Parametric expressions for the adjusted Hargreaves coefficient in Eastern Spain
NASA Astrophysics Data System (ADS)
Martí, Pau; Zarzo, Manuel; Vanderlinden, Karl; Girona, Joan
2015-10-01
The application of simple empirical equations for estimating reference evapotranspiration (ETo) is the only alternative in many cases to robust approaches with high input requirements, especially at the local scale. In particular, temperature-based approaches present a high potential applicability, among others, because temperature might explain a high amount of ETo variability, and also because it can be measured easily and is one of the most available climatic inputs. One of the most well-known temperature-based approaches, the Hargreaves (HG) equation, requires a preliminary local calibration that is usually performed through an adjustment of the HG coefficient (AHC). Nevertheless, these calibrations are site-specific, and cannot be extrapolated to other locations. So, they become useless in many situations, because they are derived from already available benchmarks based on more robust methods, which will be applied in practice. Therefore, the development of accurate equations for estimating AHC at local scale becomes a relevant task. This paper analyses the performance of calibrated and non-calibrated HG equations at 30 stations in Eastern Spain at daily, weekly, fortnightly and monthly scales. Moreover, multiple linear regression was applied for estimating AHC based on different inputs, and the resulting equations yielded higher performance accuracy than the non-calibrated HG estimates. The approach relying on the ratio mean temperature to temperature range did not provide suitable AHC estimations, and was highly improved by splitting it into two independent predictors. Temperature-based equations were improved by incorporating geographical inputs. Finally, the model relying on temperature and geographic inputs was further improved by incorporating wind speed, even just with simple qualitative information about wind category (e.g. poorly vs. highly windy). The accuracy of the calibrated and non-calibrated HG estimates increased for longer time steps (daily
Return period adjustment for runoff coefficients based on analysis in undeveloped Texas watersheds
Dhakal, Nirajan; Fang, Xing; Asquith, William H.; Cleveland, Theodore G.; Thompson, David B.
2013-01-01
The rational method for peak discharge (Qp) estimation was introduced in the 1880s. The runoff coefficient (C) is a key parameter for the rational method that has an implicit meaning of rate proportionality, and the C has been declared a function of the annual return period by various researchers. Rate-based runoff coefficients as a function of the return period, C(T), were determined for 36 undeveloped watersheds in Texas using peak discharge frequency from previously published regional regression equations and rainfall intensity frequency for return periods T of 2, 5, 10, 25, 50, and 100 years. The C(T) values and return period adjustments C(T)/C(T=10 year) determined in this study are most applicable to undeveloped watersheds. The return period adjustments determined for the Texas watersheds in this study and those extracted from prior studies of non-Texas data exceed values from well-known literature such as design manuals and textbooks. Most importantly, the return period adjustments exceed values currently recognized in Texas Department of Transportation design guidance when T>10 years.
Determination of absorption coefficients of thin films
Lodenquai, J.F. )
1994-08-01
The equations that are usually presented as those used to determine the absorption coefficients of materials in film form based on measurements of transmission and reflection coefficients are fundamentally incorrect. These equations omit a multiplicative factor arising from the complex nature of the refractive indices of the materials. This factor enters explicitly into the relationship between the transmission and reflection coefficients for such materials and is not necessarily close to unity, although in practice this factor can be approximated by unity at least in the infrared through the optical range of wavelengths.
Molecular Diffusion Coefficients: Experimental Determination and Demonstration.
ERIC Educational Resources Information Center
Fate, Gwendolyn; Lynn, David G.
1990-01-01
Presented are laboratory methods which allow the demonstration and determination of the diffusion coefficients of compounds ranging in size from water to small proteins. Included are the procedures involving the use of a spectrometer, UV cell, triterated agar, and oxygen diffusion. Results including quantification are described. (CW)
Covariate-adjusted confidence interval for the intraclass correlation coefficient.
Shoukri, Mohamed M; Donner, Allan; El-Dali, Abdelmoneim
2013-09-01
A crucial step in designing a new study is to estimate the required sample size. For a design involving cluster sampling, the appropriate sample size depends on the so-called design effect, which is a function of the average cluster size and the intracluster correlation coefficient (ICC). It is well-known that under the framework of hierarchical and generalized linear models, a reduction in residual error may be achieved by including risk factors as covariates. In this paper we show that the covariate design, indicating whether the covariates are measured at the cluster level or at the within-cluster subject level affects the estimation of the ICC, and hence the design effect. Therefore, the distinction between these two types of covariates should be made at the design stage. In this paper we use the nested-bootstrap method to assess the accuracy of the estimated ICC for continuous and binary response variables under different covariate structures. The codes of two SAS macros are made available by the authors for interested readers to facilitate the construction of confidence intervals for the ICC. Moreover, using Monte Carlo simulations we evaluate the relative efficiency of the estimators and evaluate the accuracy of the coverage probabilities of a 95% confidence interval on the population ICC. The methodology is illustrated using a published data set of blood pressure measurements taken on family members. PMID:23871746
On the adjusting of the dynamic coefficients of tilting-pad journal bearings
NASA Astrophysics Data System (ADS)
Santos, Ilmar Ferreira
1995-07-01
This paper gives a theoretical and experimental contribution to the problem of active modification of the dynamic coefficients of tilting-pad journal bearings, aiming to increase the damping and stability of rotating systems. The theoretical studies for the calculation of the bearing coefficients are based on the fluid dynamics, specifically on the Reynolds equation, on the dynamics of multibody systems and on some concepts of the hydraulics. The experiments are carried out by means of a test rig specially designed for this investigation. The four pads of such a bearing are mounted on four flexible hydraulic chambers which are connected to a proportional valve. The chamber pressures are changed by means of the proportional value, resulting in a displacement of the pads and a modification of the bearing gap. By changing the gap, one can adjust the dynamic coefficients of the bearing. With help of an experimental procedure for identifying the bearing coefficients, theoretical and experimental results are compared and discussed. The advantages and the limitation of such hydrodynamic bearings in their controllable form are evaluated with regard to application on the high-speed machines.
Adjustment of minimum seismic shear coefficient considering site effects for long-period structures
NASA Astrophysics Data System (ADS)
Guan, Minsheng; Du, Hongbiao; Cui, Jie; Zeng, Qingli; Jiang, Haibo
2016-06-01
Minimum seismic base shear is a key factor employed in the seismic design of long-period structures, which is specified in some of the major national seismic building codes viz. ASCE7-10, NZS1170.5 and GB50011-2010. In current Chinese seismic design code GB50011-2010, however, effects of soil types on the minimum seismic shear coefficient are not considered, which causes problems for long-period structures sited in hard or rock soil to meet the minimum base shear requirement. This paper aims to modify the current minimum seismic shear coefficient by taking into account site effects. For this purpose, effective peak acceleration (EPA) is used as a representation for the ordinate value of the design response spectrum at the plateau. A large amount of earthquake records, for which EPAs are calculated, are examined through the statistical analysis by considering soil conditions as well as the seismic fortification intensities. The study indicates that soil types have a significant effect on the spectral ordinates at the plateau as well as the minimum seismic shear coefficient. Modified factors related to the current minimum seismic shear coefficient are preliminarily suggested for each site class. It is shown that the modified seismic shear coefficients are more effective to the determination of minimum seismic base shear of long-period structures.
Determination of absolute internal conversion coefficients using the SAGE spectrometer
NASA Astrophysics Data System (ADS)
Sorri, J.; Greenlees, P. T.; Papadakis, P.; Konki, J.; Cox, D. M.; Auranen, K.; Partanen, J.; Sandzelius, M.; Pakarinen, J.; Rahkila, P.; Uusitalo, J.; Herzberg, R.-D.; Smallcombe, J.; Davies, P. J.; Barton, C. J.; Jenkins, D. G.
2016-03-01
A non-reference based method to determine internal conversion coefficients using the SAGE spectrometer is carried out for transitions in the nuclei of 154Sm, 152Sm and 166Yb. The Normalised-Peak-to-Gamma method is in general an efficient tool to extract internal conversion coefficients. However, in many cases the required well-known reference transitions are not available. The data analysis steps required to determine absolute internal conversion coefficients with the SAGE spectrometer are presented. In addition, several background suppression methods are introduced and an example of how ancillary detectors can be used to select specific reaction products is given. The results obtained for ground-state band E2 transitions show that the absolute internal conversion coefficients can be extracted using the methods described with a reasonable accuracy. In some cases of less intense transitions only an upper limit for the internal conversion coefficient could be given.
Determination of Catalytic Coefficient for a First-Order Reaction
ERIC Educational Resources Information Center
Fraga, E. R.; And Others
1975-01-01
Describes an undergraduate physical chemistry experiment in which the acid catalyzed hydrolysis of sucrose is used to determine the catalytic coefficient of the hydronium ion, the catalyst in this reaction. (MLH)
Determination of thermal diffusion coefficient of nanofluid: Fullerene-toluene
NASA Astrophysics Data System (ADS)
Martin, Alain; Bou-Ali, M. Mounir
2011-05-01
Thermodiffusion coefficient at fullerene mass concentrations of 0.05%, 0.1%, 0.15%, and 0.2% was established for pure fullerene (C 60) diluted in toluene solutions. For this, the thermogravitational technique has been used in planar configuration with 4 extraction points. The determination of the concentration distribution along the column in steady state is determined by the method of analysis based on density measurements. In order to determine the thermal diffusion coefficient all thermophysical properties such as density, viscosity, thermal expansion coefficient and mass expansion coefficients were determined. All these studies coincide with the importance of the knowledge of the thermophysics and transport properties of the nanofluids to develop new applications and to optimize the existing ones.
37 CFR 1.705 - Patent term adjustment determination.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 37 Patents, Trademarks, and Copyrights 1 2011-07-01 2011-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent...
37 CFR 1.705 - Patent term adjustment determination.
Code of Federal Regulations, 2012 CFR
2012-07-01
... 37 Patents, Trademarks, and Copyrights 1 2012-07-01 2012-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent...
37 CFR 1.705 - Patent term adjustment determination.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 37 Patents, Trademarks, and Copyrights 1 2014-07-01 2014-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent...
37 CFR 1.705 - Patent term adjustment determination.
Code of Federal Regulations, 2013 CFR
2013-07-01
... 37 Patents, Trademarks, and Copyrights 1 2013-07-01 2013-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent...
37 CFR 1.705 - Patent term adjustment determination.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 37 Patents, Trademarks, and Copyrights 1 2010-07-01 2010-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent...
Fractional parentage coefficients using a restricted set of Slater determinants
NASA Astrophysics Data System (ADS)
Hill, Edward George
2014-11-01
In a previous paper a method of calculating atomic physics data, energy levels and photo- and collisional-excitation rates using a restricted set of Slater determinants was demonstrated. This paper extends that work to demonstrate the method of calculating a generalisation of coefficients of fractional parentage using a restricted, and already known, set of Slater determinants. These coefficients can be used in photoionisation, collisional ionisation and autoionisation calculations, and so allow the methods to be extended to allow all of the data required by an atomic kinetic code to be calculated using this scheme.
Experimental determination of group flux control coefficients in metabolic networks
Simpson, T.W.; Shimizu, Hiroshi; Stephanopoulos, G.
1998-04-20
Grouping of reactions around key metabolite branch points can facilitate the study of metabolic control of complex metabolic networks. This top-down Metabolic Control Analysis is exemplified through the introduction of group control coefficients whose magnitudes provide a measure of the relative impact of each reaction group on the overall network flux, as well as on the overall network stability, following enzymatic amplification. In this article, the authors demonstrate the application of previously developed theory to the determination of group flux control coefficients. Experimental data for the changes in metabolic fluxes obtained in response to the introduction of six different environmental perturbations are used to determine the group flux control coefficients for three reaction groups formed around the phosphoenolpyruvate/pyruvate branch point. The consistency of the obtained group flux control coefficient estimates is systematically analyzed to ensure that all necessary conditions are satisfied. The magnitudes of the determined control coefficients suggest that the control of lysine production flux in Corynebacterium glutamicum cells at a growth base state resides within the lysine biosynthetic pathway that begins with the PEP/PYR carboxylation anaplorotic pathway.
Determination of the Static Friction Coefficient from Circular Motion
ERIC Educational Resources Information Center
Molina-Bolívar, J. A.; Cabrerizo-Vílchez, M. A.
2014-01-01
This paper describes a physics laboratory exercise for determining the coefficient of static friction between two surfaces. The circular motion of a coin placed on the surface of a rotating turntable has been studied. For this purpose, the motion is recorded with a high-speed digital video camera recording at 240 frames s[superscript-1], and the…
Determination of the heat transfer coefficients in transient heat conduction
NASA Astrophysics Data System (ADS)
Nho Hào, Dinh; Thanh, Phan Xuan; Lesnic, D.
2013-09-01
The determination of the space- or time-dependent heat transfer coefficient which links the boundary temperature to the heat flux through a third-kind Robin boundary condition in transient heat conduction is investigated. The reconstruction uses average surface temperature measurements. In both cases of the space- or time-dependent unknown heat transfer coefficient the inverse problems are nonlinear and ill posed. Least-squares penalized variational formulations are proposed and new formulae for the gradients are derived. Numerical results obtained using the nonlinear conjugate gradient method combined with a boundary element direct solver are presented and discussed.
Determination of the First Townsend Coefficient in Pure Isobutane
NASA Astrophysics Data System (ADS)
Lima, Iara B.; Vivaldini, Túlio C.; Gonçalves, Josemary A. C.; Botelho, Suzana; Ridenti, Marco A.; Fonte, Paulo; Mangiarotti, Alessio; Pascholati, Paulo R.; Tobias, Carmen C. Bueno
2011-08-01
In this work studies of the first Townsend coefficient (α) behavior in isobutane for reduced electric fields ranging from l39Td up to 2O8Td are presented. Pure isobutane has been widely used in Resistive Plate Chambers (RPCs) and other gaseous detectors because of its excellent timing properties. Regardless of these characteristics, there is a lack of swarm parameters data in the literature for this gas. The measurements were based on the Pulsed Townsend technique. Considering the ratio between the current, measured in avalanche mode, and the primary ionization current, the first Townsend coefficient can be determined. In order to validate the technique, results for nitrogen are also presented.
NASA Astrophysics Data System (ADS)
Hirasawa, T.; Ishihara, M.; Tsujita, K.; Hirota, K.; Irisawa, K.; Kitagaki, M.; Fujita, M.; Kikuchi, M.
2012-02-01
In photo-acoustic (PA) imaging, valuable medical applications based on optical absorption spectrum such as contrast agent imaging and blood oxygen saturation measurement have been investigated. In these applications, there is an essential requirement to determine optical absorption coefficients accurately. In present, PA signal intensities have been commonly used to determine optical absorption coefficients. This method achieves practical accuracy by combining with radiative transfer analysis. However, time consumption of radiative transfer analysis and effects of signal generation efficiencies were problems of this method. In this research, we propose a new method to determine optical absorption coefficients using continuous wavelet transform (CWT). We used CWT to estimate instantaneous frequencies of PA signals which reflects optical absorption distribution. We validated the effectiveness of CWT in determination of optical absorption coefficients through an experiment. In the experiment, planar shaped samples were illuminated to generate PA signal. The PA signal was measured by our fabricated PA probe in which an optical fiber and a ring shaped P(VDFTrFE) ultrasound sensor were coaxially aligned. Optical properties of samples were adjusted by changing the concentration of dye solution. Tunable Ti:Sapphire laser (690 - 1000 nm) was used as illumination source. As a result, we confirmed strong correlation between optical absorption coefficients of samples and the instantaneous frequency of PA signal obtained by CWT. Advantages of this method were less interference of light transfer and signal generation efficiency.
Methods for determining manning's coefficients for Illinois streams
Soong, D.T.; Halfar, T.M.; Jupin, M.A.; Wobig, L.A.
2004-01-01
Determination of Manning's coefficient, n, for natural streams remains a challenge in practices. One source for determining the n-values that has received practitioners' attention is presenting the n-values determined from field data (measured discharge and water-surface slope) in combination of photographs and site descriptions (ancillary information). Further improvements in the visual approach can be made in presenting site characteristics and describing site ancillary information. In this manner, users can use the presented information for sites of interest with similar features. This approach in a current project on the subject for Illinois streams is discussed.
Theoretical and observational determinations of the ionization coefficient of meteors
NASA Astrophysics Data System (ADS)
Jones, William
1997-07-01
We examine the problem of the determination of the ionization coefficient beta from both the theoretical and observational points of view. In the past, theoretical evaluations of beta in terms of the relevant scattering cross-sections have used the Massey-Sida formula, which we show to give results which are plainly incorrect. We derive an integral equation for beta and compare the results of its application to copper and iron with laboratory simulations. Agreement for the variation of the ionization coefficient with velocity is good. The ionization coefficient has been determined observationally by Verniani & Hawkins from a comparison of radar and visual observations, employing the luminous efficiency tau also obtained observationally by Verniani. However, this determination of tau would appear to be invalidated by fragmentation. There is good evidence that the radiation of cometary meteors is dominated by that of iron in the visual range, and we have accordingly re-analysed the data of Verniani & Hawkins using the luminous efficiency of iron obtained in simulation experiments. However, it is not possible to choose an iron concentration which gives agreement between the determination of the ionization coefficient by this means and its determination from the theoretical equation in terms of either scattering coefficients or simulation methods. The observational ionization coefficients are much lower than predicted by the present theory and we provisionally explain this as a consequence of transfer of charge from the meteoric ion to a molecule of the air. It is now possible for the meteoric atom to be re-ionized, but it is also possible at sufficiently high initial line densities for significant dissociative recombination of the electrons and nitrogen or oxygen to take place. This recombination will not take place in meteor trains simulated in an ionization chamber. We thus conclude that the present theory is limited to faint radio meteors at lower velocities (v<~35
Determinants of adjustment for children of divorcing parents.
Oppenheimer, K; Prinz, R J; Bella, B S
1990-01-01
Family physicians frequently see children and parents when they are adjusting to marital separation. This study examined how well child adjustment at school could be determined from an assessment of interspousal relations, maternal functioning, and child perception variables. Teachers evaluated adaptive functioning, social withdrawal, and aggressive behavior at school for a carefully selected sample of 22 boys and 24 girls (ages 7-12) whose parents had been separated for two to 18 months. Regression analyses indicated that boys' overall school adjustment was associated with better maternal parenting skills, lower child fear of abandonment, less blaming of father for the separation, and positive parental verbal attributions toward the other parent. Girls with better overall school adjustment reported less blaming of their mothers and a higher rate of positive attributions by mother about father. These findings suggest concepts family physicians can use in working with families to minimize the effect of divorce on children. PMID:2323490
Absorption-coefficient-determination method for particulate materials.
Lindberg, J D; Douglass, R E; Garvey, D M
1994-07-01
A method is presented for determining the optical absorption coefficient, or the imaginary refractive index, of particulate material that has been collected from aerosols or hydrosols by means of filtration. The method, based on the Kubelka-Munk theory of diffuse reflectance, is nondestructive and requires no other knowledge of the sample than the amount present, the specific gravity, and an estimate of the real index of refraction. The theoretical development of the method is discussed along with an analysis of photometric and gravimetric errors. We test the method by comparing results obtained for powdered didymium glass with measurements made before the glass was crushed. An example of the method's application to the determination of the absorption coefficient of atmospheric dust at UV, visible, and near-IR wavelengths is also presented. PMID:20935789
Operation of the breeze tunnel to determine mass extinction coefficients
Sehmel, G.A.; Bonfante, R.; Catalano, E.; Rouse, W.G.; Banks, D.R.
1993-06-01
The breeze tunnel at the Edgewood Research, Development and Engineering Center (ERDEC) at Aberdeen Proving Ground, Maryland, is a unique facility for determining the efficacy of released smoke/obscurants in flowing air as a function of controlling variables. Optimum material feed characteristics and generator operating conditions can be determined. The facility allows investigation of the effects of different generator operating variables, airborne concentrations, and airborne particle sizes on mass extinction coefficients. The breeze tunnel is now available for Department of Defense (DoD) trials. During trials in the breeze tunnel, obscurants have been released from the compact-disc-generator, the IR-Log generator, and the XM56 generator. Obscurant release rates have ranged from an instantaneous puff to a continuous release of 10 lb/min. Extinction can be measured in the visual, infrared, and millimeter ranges of the electromagnetic spectrum. Experimental conditions allow calculation of mass extinction coefficients as a function of generator variables, including material release rates. Average mass extinction coefficients address attenuation from obscurants, both single primary particles and aggregates.
Determination of the static friction coefficient from circular motion
NASA Astrophysics Data System (ADS)
Molina-Bolívar, J. A.; Cabrerizo-Vílchez, M. A.
2014-07-01
This paper describes a physics laboratory exercise for determining the coefficient of static friction between two surfaces. The circular motion of a coin placed on the surface of a rotating turntable has been studied. For this purpose, the motion is recorded with a high-speed digital video camera recording at 240 frames s-1, and the videos are analyzed using Tracker video-analysis software, allowing the students to dynamically model the motion of the coin. The students have to obtain the static friction coefficient by comparing the centripetal and maximum static friction forces. The experiment only requires simple and inexpensive materials. The dynamics of circular motion and static friction forces are difficult for many students to understand. The proposed laboratory exercise addresses these topics, which are relevant to the physics curriculum.
Determining the Coefficient of Discharge for a Draining Container
NASA Astrophysics Data System (ADS)
Hicks, Ashley; Slaton, William
2014-01-01
The flow of fluids through open containers is a topic studied frequently in introductory physics classes. A fluid mechanics class delves deeper into the topic of fluid flow through open containers with holes or barriers. The flow of a fluid jet out of a sharp-edged orifice rarely has the same area as the orifice due to a fluid flow phenomenon known as the vena contracta. The area of a fluid jet out of an orifice is related to the actual area of the orifice by a value known as the coefficient of discharge, Cd. The purpose of this paper is to develop a mathematical model for a draining open container and an experimental method that will efficiently determine the coefficient of discharge for such a system. Prior work in physics education literature has developed a method for measuring the flow of a fluid out of an orifice using ultrasonic motion detectors. In this paper we present data that show our method can be used to find the coefficient of discharge within the expected literature values for sharp-edged and rounded orifices.
Determination of diffusion coefficient in disordered organic semiconductors
NASA Astrophysics Data System (ADS)
Rani, Varsha; Sharma, Akanksha; Ghosh, Subhasis
2016-05-01
Charge carrier transport in organic semiconductors is dominated by positional and energetic disorder in Gaussian density of states (GDOS) and is characterized by hopping through localized states. Due to the immobilization of charge carriers in these localized states, significant non-uniform carrier distribution exists, resulting diffusive transport. A simple, nevertheless powerful technique to determine diffusion coefficient D in disordered organic semiconductors has been presented. Diffusion coefficients of charge carriers in two technologically important organic molecular semiconductors, Pentacene and copper phthalocyanine (CuPc) have been measured from current-voltage (J-V) characteristics of Al/Pentacene/Au and Al/CuPc/Au based Schottky diodes. Ideality factor g and carrier mobility μ have been calculated from the exponential and space charge limited region respectively of J-V characteristics. Classical Einstein relation is not valid in organic semiconductors due to energetic disorders in DOS. Using generalized Einstein relation, diffusion coefficients have been obtained to be 1.31×10-6 and 1.73×10-7 cm2/s for Pentacene and CuPc respectively.
A self-adjusting flow dependent formulation for the classical Smagorinsky model coefficient
NASA Astrophysics Data System (ADS)
Ghorbaniasl, G.; Agnihotri, V.; Lacor, C.
2013-05-01
In this paper, we propose an efficient formula for estimating the model coefficient of a Smagorinsky model based subgrid scale eddy viscosity. The method allows vanishing eddy viscosity through a vanishing model coefficient in regions where the eddy viscosity should be zero. The advantage of this method is that the coefficient of the subgrid scale model is a function of the flow solution, including the translational and the rotational velocity field contributions. Furthermore, the value of model coefficient is optimized without using the dynamic procedure thereby saving significantly on computational cost. In addition, the method guarantees the model coefficient to be always positive with low fluctuation in space and time. For validation purposes, three test cases are chosen: (i) a fully developed channel flow at {mathopRenolimits} _tau = 180, 395, (ii) a fully developed flow through a rectangular duct of square cross section at {mathopRenolimits} _tau = 300, and (iii) a smooth subcritical flow past a stationary circular cylinder, at a Reynolds number of {mathopRenolimits} = 3900, where the wake is fully turbulent but the cylinder boundary layers remain laminar. A main outcome is the good behavior of the proposed model as compared to reference data. We have also applied the proposed method to a CT-based simplified human upper airway model, where the flow is transient.
Determination of Absorption Coefficient of a Solution by a Simple Experimental Setup
NASA Astrophysics Data System (ADS)
Gopalakrishnan, Deepak; Akhildev, C.; Sreenivasan, P. V.; Leelamma, K. K.; Joseph, Lyjo K.; Anila, E. I.
2011-10-01
The absorption coefficients of aqueous potassium permanganate (KMnO4) solution at 638.8 nm for various concentrations are determined using a simple experimental set up. The setup consists of He-Ne laser source (Red, 638.8 nm, 10 mW), a glass jar in which the KMnO4 sample is taken, a mirror strip inclined at 45° to direct the laser beam towards the bottom of the glass jar, a traveling microscope to adjust the position of light dependent resistor (LDR) and a digital multimeter to measure the resistance.
Determination of Joint Roughness Coefficients Using Roughness Parameters
NASA Astrophysics Data System (ADS)
Jang, Hyun-Sic; Kang, Seong-Seung; Jang, Bo-An
2014-11-01
This study used precisely digitized standard roughness profiles to determine roughness parameters such as statistical and 2D discontinuity roughness, and fractal dimensions. Our methods were based on the relationship between the joint roughness coefficient (JRC) values and roughness parameters calculated using power law equations. Statistical and 2D roughness parameters, and fractal dimensions correlated well with JRC values, and had correlation coefficients of over 0.96. However, all of these relationships have a 4th profile (JRC 6-8) that deviates by more than ±5 % from the JRC values given in the standard roughness profiles. This indicates that this profile is statistically different than the others. We suggest that fractal dimensions should be measured within the entire range of the divider, instead of merely measuring values within a suitable range. Normalized intercept values also correlated with the JRC values, similarly to the fractal dimension values discussed above. The root mean square first derivative values, roughness profile indexes, 2D roughness parameter, and fractal dimension values decreased as the sampling interval increased. However, the structure function values increased very rapidly with increasing sampling intervals. This indicates that the roughness parameters are not independent of the sampling interval, and that the different relationships between the JRC values and these roughness parameters are dependent on the sampling interval.
Determination of spin-orbit coefficients in semiconductor quantum wells
NASA Astrophysics Data System (ADS)
Faniel, S.; Matsuura, T.; Mineshige, S.; Sekine, Y.; Koga, T.
2011-03-01
We report the determination of the intrinsic spin-orbit interaction (SOI) parameters for In0.53Ga0.47As/In0.52Al0.48As quantum wells (QWs) from the analysis of the weak antilocalization effect. We show that the Dresselhaus SOI is mostly negligible in this system and that the intrinsic parameter for the Rashba effect, aSO≡α/
Experimentally Determined Heat Transfer Coefficients for Spacesuit Liquid Cooled Garments
NASA Technical Reports Server (NTRS)
Bue, Grant; Watts, Carly; Rhodes, Richard; Anchondo, Ian; Westheimer, David; Campbell, Colin; Vonau, Walt; Vogel, Matt; Conger, Bruce
2015-01-01
A Human-In-The-Loop (HITL) Portable Life Support System 2.0 (PLSS 2.0) test has been conducted at NASA Johnson Space Center in the PLSS Development Laboratory from October 27, 2014 to December 19, 2014. These closed-loop tests of the PLSS 2.0 system integrated with human subjects in the Mark III Suit at 3.7 psi to 4.3 psi above ambient pressure performing treadmill exercise at various metabolic rates from standing rest to 3000 BTU/hr (880 W). The bulk of the PLSS 2.0 was at ambient pressure but effluent water vapor from the Spacesuit Water Membrane Evaporator (SWME) and the Auxiliary Membrane Evaporator (Mini-ME), and effluent carbon dioxide from the Rapid Cycle Amine (RCA) were ported to vacuum to test performance of these components in flight-like conditions. One of the objectives of this test was to determine the heat transfer coefficient (UA) of the Liquid Cooling Garment (LCG). The UA, an important factor for modeling the heat rejection of an LCG, was determined in a variety of conditions by varying inlet water temperature, flowrate, and metabolic rate. Three LCG configurations were tested: the Extravehicular Mobility Unit (EMU) LCG, the Oceaneering Space Systems (OSS) LCG, and the OSS auxiliary LCG. Other factors influencing accurate UA determination, such as overall heat balance, LCG fit, and the skin temperature measurement, will also be discussed.
A consistent local linear estimator of the covariate adjusted correlation coefficient
Nguyen, Danh V.; Şentürk, Damla
2009-01-01
Consider the correlation between two random variables (X, Y), both not directly observed. One only observes X̃ = φ1(U)X + φ2(U) and Ỹ = ψ1(U)Y + ψ2(U), where all four functions {φl(·),ψl(·), l = 1, 2} are unknown/unspecified smooth functions of an observable covariate U. We consider consistent estimation of the correlation between the unobserved variables X and Y, adjusted for the above general dual additive and multiplicative effects of U, based on the observed data (X̃, Ỹ, U). PMID:21720454
Determination of soil–water sorption coefficients of volatile methylsiloxanes
Kozerski, Gary E; Xu, Shihe; Miller, Julie; Durham, Jeremy
2014-01-01
The sorption behaviors of 4 cyclic and linear volatile methyl siloxane (VMS) compounds between water and organic matter in 3 United Kingdom soils were studied by a batch equilibrium method using13C-enriched sorbates. Sorption and desorption kinetics and isotherms were determined for octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), octamethyltrisiloxane (L3), and decamethyltetrasiloxane (L4). Concentrations of [13C]-VMS in the soil and aqueous phases were measured directly by extraction and gas chromatography–mass spectrometry techniques. All VMS compounds were sorbed rapidly, reaching constant distributions in all soils by 24 h. Desorption kinetics were very rapid, with reattainment of equilibrium within 1 h. In the main, linear isotherms were observed for aqueous concentrations at or below 4% of the solubility limits. The average sorption organic carbon partition coefficient (log KOC) values across soils were 4.23 for D4, 5.17 for D5, 4.32 for L3, and 5.13 for L4, with standard deviations of 0.09 to 0.34. Desorption KOC values were systematically greater by 0.1 log units to 0.3 log units. The linear isotherms and low variation in KOC values across soils suggested partitioning-dominated sorption of the VMS. Compared with traditional hydrophobic organic compounds, KOC values for the VMS compounds were significantly lower than expected on the basis of their octanol–water partition coefficients. A linear free energy relationship analysis showed that these differences could be rationalized quantitatively in terms of the inherent characteristics of the VMS compounds, combined with the differences in solvation properties of organic matter and octanol. Environ Toxicol Chem 2014; 33:1937–1945. PMID:24862578
Determination of spallation neutron flux through spectral adjustment techniques
NASA Astrophysics Data System (ADS)
Mosby, M. A.; Engle, J. W.; Jackman, K. R.; Nortier, F. M.; Birnbaum, E. R.
2016-08-01
The Los Alamos Isotope Production Facility (IPF) creates medical isotopes using a proton beam impinged on a target stack. Spallation neutrons are created in the interaction of the beam with target. The use of these spallation neutrons to produce additional radionuclides has been proposed. However, the energy distribution and magnitude of the flux is not well understood. A modified SAND-II spectral adjustment routine has been used with radioactivation foils to determine the differential neutron fluence for these spallation neutrons during a standard IPF production run.
Determination of the Evaporation Coefficient of D2O
Drisdell, Walter S.; Cappa, Christopher D.; Smith, Jared D.; Saykally, Richard J.; Cohen, Ronald C.
2008-03-26
The evaporation rate of D{sub 2}O has been determined by Raman thermometry of a droplet train (12-15 {micro}m diameter) injected into vacuum ({approx}10{sup -5} torr). The cooling rate measured as a function of time in vacuum was fit to a model that accounts for temperature gradients between the surface and the core of the droplets, yielding an evaporation coefficient ({gamma}{sub e}) of 0.57 {+-} 0.06. This is nearly identical to that found for H{sub 2}O (0.62 {+-} 0.09) using the same experimental method and model, and indicates the existence of a kinetic barrier to evaporation. The application of a recently developed transition state theory (TST) model suggests that the kinetic barrier is due to librational and hindered translational motions at the liquid surface, and that the lack of an isotope effect is due to competing energetic and entropic factors. The implications of these results for cloud and aerosol particles in the atmosphere are discussed.
Wang, Qianggang; Zhou, Niancheng; Lou, Xiaoxuan; Chen, Xu
2014-01-01
Unbalanced grid faults will lead to several drawbacks in the output power quality of photovoltaic generation (PV) converters, such as power fluctuation, current amplitude swell, and a large quantity of harmonics. The aim of this paper is to propose a flexible AC current generation method by selecting coefficients to overcome these problems in an optimal way. Three coefficients are brought in to tune the output current reference within the required limits of the power quality (the current harmonic distortion, the AC current peak, the power fluctuation, and the DC voltage fluctuation). Through the optimization algorithm, the coefficients can be determined aiming to generate the minimum integrated amplitudes of the active and reactive power references with the constraints of the inverter current and DC voltage fluctuation. Dead-beat controller is utilized to track the optimal current reference in a short period. The method has been verified in PSCAD/EMTDC software. PMID:25243215
Wang, Qianggang; Zhou, Niancheng; Lou, Xiaoxuan; Chen, Xu
2014-01-01
Unbalanced grid faults will lead to several drawbacks in the output power quality of photovoltaic generation (PV) converters, such as power fluctuation, current amplitude swell, and a large quantity of harmonics. The aim of this paper is to propose a flexible AC current generation method by selecting coefficients to overcome these problems in an optimal way. Three coefficients are brought in to tune the output current reference within the required limits of the power quality (the current harmonic distortion, the AC current peak, the power fluctuation, and the DC voltage fluctuation). Through the optimization algorithm, the coefficients can be determined aiming to generate the minimum integrated amplitudes of the active and reactive power references with the constraints of the inverter current and DC voltage fluctuation. Dead-beat controller is utilized to track the optimal current reference in a short period. The method has been verified in PSCAD/EMTDC software. PMID:25243215
The determination of longitudinal dispersion coefficients in rivers.
Palancar, María C; Aragón, José M; Sánchez, Fernando; Gil, Roberto
2003-01-01
The dispersion coefficient of several sections of two Spanish rivers (Tagus and Ebro) is calculated using different methods. The aim of the study is to accurately know the effects of accidental leaks from two nuclear power plants that are placed upstream. Experimental data from tracer injections as well as data from hydraulic parameters were used to calculate the dispersion coefficient. Two methods based on tracer curves fit the experimental data well. One method is based on the time at which the tracer concentration is half the maximum concentration; the other method is based on the variance of the tracer curve distribution. An alternative method based on governmental data of velocity profiles and correlations of hydraulic parameters was also used. The results of this method are strongly sensitive to small variations in the stream flowrate. A new correlation is proposed to predict the dispersion coefficient with an error smaller than the one provided by other correlations in the literature. PMID:12934826
Determination of decay coefficients for combustors with acoustic absorbers
NASA Technical Reports Server (NTRS)
Mitchell, C. E.; Espander, W. R.; Baer, M. R.
1972-01-01
An analytical technique for the calculation of linear decay coefficients in combustors with acoustic absorbers is presented. Tuned circumferential slot acoustic absorbers were designed for the first three transverse modes of oscillation, and decay coefficients for these absorbers were found as a function of backing distance for seven different chamber configurations. The effectiveness of the absorbers for off-design values of the combustion response and acoustic mode is also investigated. Results indicate that for tuned absorbers the decay coefficient increases approximately as the cube of the backing distance. For most off-design situations the absorber still provides a damping effect. However, if an absorber designed for some higher mode of oscillation is used to damp lower mode oscillations, a driving effect is frequently found.
Determination of crop coefficients (Kc) for irrigation management of crops
Technology Transfer Automated Retrieval System (TEKTRAN)
Weighing lysimeters are used to measure crop water use during the growing season. By relating the water use of a specific crop to a well-watered reference crop such as grass, crop coefficients (Kc) can be developed to assist in predicting crop needs using meteorological data available from weather ...
Determination of the heat transfer coefficients in porous media
Kim, L.V.
1994-06-01
The process of transpiration cooling is considered. Methods are suggested for estimating the volumetric coefficient of heat transfer with the use of a two-temperature model and the surface heat transfer coefficient at entry into a porous wall. The development of new technology under conditions of increasing heat loads puts the search for effective methods of heat transfer enhancement in the forefront of theoretical investigations. One of the promising trends in the solution of this problem is the use of porous materials (PM) in the elements of power units. For thermal protection against convective or radiative heat fluxes, the method of transpiration cooling is successfully used. The mechanism operative in the thermal protection involves the injection of a coolant through a porous medium to produce a screen over the contour of a body in a flow for removing heat energy from the skeleton of the porous material.
Diaphragm cell determination of the interdiffusion coefficient for succinonitrile + water
NASA Astrophysics Data System (ADS)
Cain, J. B.; Clunie, J. C.; Baird, J. K.
1995-09-01
Using diaphragm cells, we have measured the interdiffusion coefficient for succinonitrile+water in the one-phase liquid region at a series of temperatures ranging form 25 to 60°C and compositions ranging from 34.5 to 96 mol% water. The diffusion coefficient was found to be a function of both temperature and concentration, varying from 1.66×10-6 to 16.6×10-6 cm2·s-1. Critical slowing down of diffusion was readily detected at 60°C (critical temperature, 56.17°C) over a broad range of composition on either side of the critical composition (82.7 mol% water).
Aquifer coefficients determined from multiple well effects, Fernandina Beach, Florida.
Bentley, C.B.
1979-01-01
On September 30, 1977, a large industrial plant in Fernandina Beach, Florida, shut down six artesian wells that had been pumping continuously for several weeks from the Floridan aquifer. Two wells continued pumping until November 20, 1977, at which time the shutdown wells were restarted. A transmissivity of 30 000 ft2 day-1 (2800 m2 day-1) and a storage coefficient of between 2.5 x 10-4 and 4.0 x 10-4 were computed.-from Author
On the determination of elastic coefficients from indentation experiments
NASA Astrophysics Data System (ADS)
Tardieu, N.; Constantinescu, A.
2000-06-01
The main result of this paper is the extension of the adjoint state method to variational inequalities. This is done for the Signorini contact problem (Kikuchi N and Oden J T 1988 Contact Problems in Elasticity: a Study of Variational Inequalities and Finite Element Methods (Philadelphia: SIAM)) and used for the identification of elastic coefficients from an indentation test. The result is obtained by two independent approaches based on the penalized and respectively, mixed formulations of the direct problem, a Signorini contact problem. An important and astonishing result is that the obtained adjoint problem is a linear problem with Dirichlet boundary conditions. This is expected for problems described with variational equalities (Bui H D 1993 Introduction Aux Problèmes Inverses en Mécanique des Matériaux (Paris: Eyrolles) (Engl. Transl. (Boca Raton, FL: CRC Press)), Lions J L 1968 Contrôle Optimal des Systèmes Gouvernés par des Équations aux Dérivées Partielles (Dunod)), but is a new result for problems described with variational inequalities. As an application, the elastic coefficients of an isotropic body have been identified from the knowledge of a displacement-force curve measured during an indentation test. The efficiency of the method is illustrated on numerical examples for the identification of a bimaterial and a functional gradient material.
Federal Register 2010, 2011, 2012, 2013, 2014
2011-10-20
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On determination of sign of the piezo-optic coefficients using torsion method.
Vasylkiv, Yurij; Savaryn, Viktoriya; Smaga, Ihor; Skab, Ihor; Vlokh, Rostyslav
2011-06-10
We have shown that a high-accuracy torsion method recently developed by the authors for measuring piezo-optic coefficients allows determining not only the absolute value of the coefficients but also their sign. The techniques and experimental procedures used for determination of the sign are described in detail and proven based on studies of α-BaB2O4 and LiNbO3 crystals. The piezo-optic coefficients are determined for both crystals, and a combination of the corresponding photoelastic coefficients is determined for the case of α-BaB2O4 crystals. PMID:21673752
Airflow in Gravity Sewers - Determination of Wastewater Drag Coefficient.
Bentzen, Thomas Ruby; Østertoft, Kristian Kilsgaard; Vollertsen, Jes; Fuglsang, Emil Dietz; Nielsen, Asbjørn Haaning
2016-03-01
Several experiments have been conducted in order to improve the understanding of the wastewater drag and the wall frictional force acting on the headspace air in gravity sewers. The aim of the study is to improve the data basis for a numerical model of natural sewer ventilation. The results of the study shows that by integrating the top/side wall shear stresses the log-law models for the air velocity distribution along the unwetted perimeter resulted in a good agreement with the friction forces calculated by use of the Colebrook-White formula for hydraulic smooth pipes. Secondly, the water surface drags were found by log-law models of the velocity distribution in turbulent flows to fit velocity profiles measured from the water surface and by integrating the water surface drags along the wetted perimeter, mean water surface drags were found and a measure of the water surface drag coefficient was found. PMID:26931535
Bharate, Sonali S; Kumar, Vikas; Vishwakarma, Ram A
2016-01-01
An early prediction of physicochemical properties is highly desirable during drug discovery to find out a viable lead candidate. Although there are several methods available to determine partition coefficient (log P), distribution coefficient (log D) and ionization constant (pKa), none of them involves simple and fixed, miniaturized protocols for diverse set of compounds. Therefore, it is necessary to establish simple, uniform and medium-throughput protocols requiring small sample quantities for the determination of these physicochemical properties. Log P and log D were determined by shake flask method, wherein, the compound was partitioned between presaturated noctanol and water phase (water/PBS pH 7.4) and the concentration of compound in each phase was determined by HPLC. The pKa determination made use of UV spectrophotometric analysis in a 96-well microtiter plate containing a series of aqueous buffers ranging from pH 1.0 to 13.0. The medium-throughput miniaturized protocols described herein, for determination of log P, log D and pKa, are straightforward to set up and require very small quantities of sample (< 5 mg for all three properties). All established protocols were validated using diverse set of compounds. PMID:27137915
Determination of heat transfer coefficients during solidification of a casting in a jet crystallizer
NASA Astrophysics Data System (ADS)
Borukhov, V. T.; Zayats, G. M.; Stetsenko, V. Yu.; Konovalov, R. V.
2012-01-01
The problem of determining heat transfer coefficients in thermal processes described by nonlinear initial boundary-value problems for heat conduction equations in a cylindrical coordinate system is considered subject to axial symmetry. An algorithm is suggested and program means are created for identifying heat transfer coefficients. A computational experiment on determining heat transfer coefficients for the AK12 alloy is carried out, and recommendations for selecting numerical calculation parameters have been developed.
Determination of the hot- and cold-temperature coefficient of reactivity in the AVR core
Pohl, P.; Wimmers, M.; Kindt, T.; Feltes, W.; Schmid, U.; Jung, H.
1987-09-01
The measurements that were made in recent years to determine the hot and the cold coefficient of reactivity and the corresponding model calculations carried out by both Interatom and Hochtemperaturreaktorbau are described. The effects of the partial load of low-enriched uranium (LEU) fuel were of major interest. The cold coefficient is determined in shutdown periods by measuring the subcriticality at different core temperatures. The hot coefficient is determined under operation in connection with a change in coolant outlet temperature at constant power using a calibrated rod curve. In the case of the cold coefficient, experiment and model calculations are in perfect agreement. Calculated values for the hot coefficient are -- 20% lower than the experimental ones. However, neither experiment nor model calculation show any significant change of the hot coefficient when about one-fourth of the core content was being replaced by LEU fuel.
NASA Astrophysics Data System (ADS)
Wais, Sabah
2011-10-01
In the present work, an experimental study is performed to determine the first Townsend coefficient and Paschen curve for N2 gas chamber using a parallel plate geometrical configuration. Paschen curve coefficients are derived by exponential fitting of first Townsend coefficients data of plasma discharge. The experimental data is acquired at different working pressure and various electrode gap separations. Furthermore, the amplification process of the gas gain in non-uniform electric field is realized.
Geopotential coefficient determination and the gravimetric boundary value problem: A new approach
NASA Technical Reports Server (NTRS)
Sjoeberg, Lars E.
1989-01-01
New integral formulas to determine geopotential coefficients from terrestrial gravity and satellite altimetry data are given. The formulas are based on the integration of data over the non-spherical surface of the Earth. The effect of the topography to low degrees and orders of coefficients is estimated numerically. Formulas for the solution of the gravimetric boundary value problem are derived.
22 CFR 304.7 - Authority to adjust, determine, compromise, and settle claims.
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2014-04-01
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22 CFR 304.7 - Authority to adjust, determine, compromise, and settle claims.
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2013-04-01
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2010-04-01
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2011-04-01
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5 CFR 177.106 - Authority to adjust, determine, compromise, and settle.
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2011-01-01
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NASA Technical Reports Server (NTRS)
Molina, L. T.; Grant, W. B.
1984-01-01
The absorption spectra of three hydrazines and four of their air-oxidation products were measured in the 9-12-micron spectral region with a Fourier transform infrared (FTIR) spectrometer with a 0.05-kayser resolution to determine absorption coefficients at CO2 and tunable diode laser wavelengths. The measurements agreed well with published CO2 laser determinations for many of the absorption coefficients, except where the published values are thought to be in error. The coefficients were then used to estimate the sensitivity for remote detection of these gases using CO2 and tunable diode lasers in long-path differential absorption measurements.
NASA Technical Reports Server (NTRS)
Banan, Mohsen; Gray, Ross T.; Wilcox, William R.
1992-01-01
The heat transfer coefficient between a molten charge and its surroundings in a Bridgman furnace was experimentally determined using in-situ temperature measurement. The ampoule containing an isothermal melt was suddenly moved from a higher temperature zone to a lower temperature zone. The temperature-time history was used in a lumped-capacity cooling model to evaluate the heat transfer coefficient between the charge and the furnace. The experimentally determined heat transfer coefficient was of the same order of magnitude as the theoretical value estimated by standard heat transfer calculations.
A novel approach to determine the heat transfer coefficient in directional solidification furnaces
NASA Technical Reports Server (NTRS)
Banan, Mohsen; Gray, Ross T.; Wilcox, William R.
1990-01-01
The heat transfer coefficient between a molten charge and its surroundings in a Bridgman furnace was determined using an approach utilizing in-situ temperature measurement. The ampoule containing an isothermal melt was suddenly moved from a higher temperature zone to a lower temperature zone. The temperature-time history was used in a lumped-capacity cooling model to evaluate the heat transfer coefficient between the charge and the furnace. The experimentally determined heat transfer coefficient was of the same order of magnitude as the value estimated by standard heat transfer calculations.
NASA Astrophysics Data System (ADS)
Lubey, D.; Ko, H.; Scheeres, D.
The classical orbit determination (OD) method of dealing with unknown maneuvers is to restart the OD process with post-maneuver observations. However, it is also possible to continue the OD process through such unknown maneuvers by representing those unknown maneuvers with an appropriate event representation. It has been shown in previous work (Ko & Scheeres, JGCD 2014) that any maneuver performed by a satellite transitioning between two arbitrary orbital states can be represented as an equivalent maneuver connecting those two states using Thrust-Fourier-Coefficients (TFCs). Event representation using TFCs rigorously provides a unique control law that can generate the desired secular behavior for a given unknown maneuver. This paper presents applications of this representation approach to orbit prediction and maneuver detection problem across unknown maneuvers. The TFCs are appended to a sequential filter as an adjoint state to compensate unknown perturbing accelerations and the modified filter estimates the satellite state and thrust coefficients by processing OD across the time of an unknown maneuver. This modified sequential filter with TFCs is capable of fitting tracking data and maintaining an OD solution in the presence of unknown maneuvers. Also, the modified filter is found effective in detecting a sudden change in TFC values which indicates a maneuver. In order to illustrate that the event representation approach with TFCs is robust and sufficiently general to be easily adjustable, different types of measurement data are processed with the filter in a realistic LEO setting. Further, cases with mis-modeling of non-gravitational force are included in our study to verify the versatility and efficiency of our presented algorithm. Simulation results show that the modified sequential filter with TFCs can detect and estimate the orbit and thrust parameters in the presence of unknown maneuvers with or without measurement data during maneuvers. With no measurement
Computation of determinant expansion coefficients within the graphically contracted function method.
Gidofalvi, G.; Shepard, R.; Chemical Sciences and Engineering Division
2009-11-30
Most electronic structure methods express the wavefunction as an expansion of N-electron basis functions that are chosen to be either Slater determinants or configuration state functions. Although the expansion coefficient of a single determinant may be readily computed from configuration state function coefficients for small wavefunction expansions, traditional algorithms are impractical for systems with a large number of electrons and spatial orbitals. In this work, we describe an efficient algorithm for the evaluation of a single determinant expansion coefficient for wavefunctions expanded as a linear combination of graphically contracted functions. Each graphically contracted function has significant multiconfigurational character and depends on a relatively small number of variational parameters called arc factors. Because the graphically contracted function approach expresses the configuration state function coefficients as products of arc factors, a determinant expansion coefficient may be computed recursively more efficiently than with traditional configuration interaction methods. Although the cost of computing determinant coefficients scales exponentially with the number of spatial orbitals for traditional methods, the algorithm presented here exploits two levels of recursion and scales polynomially with system size. Hence, as demonstrated through applications to systems with hundreds of electrons and orbitals, it may readily be applied to very large systems.
Computation of determinant expansion coefficients within the graphically contracted function method.
Gidofalvi, Gergely; Shepard, Ron
2009-11-30
Most electronic structure methods express the wavefunction as an expansion of N-electron basis functions that are chosen to be either Slater determinants or configuration state functions. Although the expansion coefficient of a single determinant may be readily computed from configuration state function coefficients for small wavefunction expansions, traditional algorithms are impractical for systems with a large number of electrons and spatial orbitals. In this work, we describe an efficient algorithm for the evaluation of a single determinant expansion coefficient for wavefunctions expanded as a linear combination of graphically contracted functions. Each graphically contracted function has significant multiconfigurational character and depends on a relatively small number of variational parameters called arc factors. Because the graphically contracted function approach expresses the configuration state function coefficients as products of arc factors, a determinant expansion coefficient may be computed recursively more efficiently than with traditional configuration interaction methods. Although the cost of computing determinant coefficients scales exponentially with the number of spatial orbitals for traditional methods, the algorithm presented here exploits two levels of recursion and scales polynomially with system size. Hence, as demonstrated through applications to systems with hundreds of electrons and orbitals, it may readily be applied to very large systems. PMID:19360796
Abraham, Michael H; Gil-Lostes, Javier; Corr, Stuart; Acree, William E
2012-11-23
Gas-water partition coefficients, K(w), and gas-solvent partition coefficients, K(s), have been determined for chlorodifluoromethane and for 1,1,1,3,3,3-hexafluoropropane by headspace analysis, using a very simple experimental procedure. These partition coefficients then yield water-solvent partition coefficients, P(s). Where comparisons can be made there is excellent agreement with literature values for K(w) and P(s). The obtained values of K(s) and P(s) can be used to obtain physicochemical properties, or descriptors, for the refrigerants. Combination of these descriptors with previous equations we have developed enables partition coefficients to be obtained for a host of systems. PMID:23089519
Refinement of the aeronomically determined rate coefficient for the reaction of N2/+/ with O
NASA Technical Reports Server (NTRS)
Torr, D. G.
1979-01-01
An earlier aeronomic determination of the rate coefficient for the reaction N2(+) + O yields NO(+) + N using Atmosphere Explorer data indicated a small increase in the rate coefficient with ion temperature, contrary to laboratory observations. This was incorrectly attributed to neglect of an increase in the N2(+) recombination rate with vibrational excitation. Recent aeronomical results have shown that the rate coefficient for charge exchange of O(+)(2D) with N2 is about an order of magnitude smaller at thermal temperatures than at energies greater than 0.5 eV (i.e., energies at which laboratory measurements have been made). It is shown that the use of the smaller charge exchange rate coefficient coupled with recent results on N2 quenching of O(+)(2D) yields a temperature dependence in excellent agreement with the laboratory results for the rate coefficient.
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On the methods for determining the transverse dispersion coefficient in river mixing
NASA Astrophysics Data System (ADS)
Baek, Kyong Oh; Seo, Il Won
2016-04-01
In this study, the strengths and weaknesses of existing methods for determining the dispersion coefficient in the two-dimensional river mixing model were assessed based on hydraulic and tracer data sets acquired from experiments conducted on either laboratory channels or natural rivers. From the results of this study, it can be concluded that, when the longitudinal dispersion coefficient as well as the transverse dispersion coefficients must be determined in the transient concentration situation, the two-dimensional routing procedures, 2D RP and 2D STRP, can be employed to calculate dispersion coefficients among the observation methods. For the steady concentration situation, the STRP can be applied to calculate the transverse dispersion coefficient. When the tracer data are not available, either theoretical or empirical equations by the estimation method can be used to calculate the dispersion coefficient using the geometric and hydraulic data sets. Application of the theoretical and empirical equations to the laboratory channel showed that equations by Baek and Seo [[3], 2011] predicted reasonable values while equations by Fischer [23] and Boxwall and Guymer (2003) overestimated by factors of ten to one hundred. Among existing empirical equations, those by Jeon et al. [28] and Baek and Seo [6] gave the agreeable values of the transverse dispersion coefficient for most cases of natural rivers. Further, the theoretical equation by Baek and Seo [5] has the potential to be broadly applied to both laboratory and natural channels.
A computer program for determining truncation error coefficients for Runge-Kutta methods
NASA Technical Reports Server (NTRS)
Horn, M. K.
1980-01-01
The basic structure of a program to generate the truncation error coefficients for Runge-Kutta (RK) methods is reformulated to reduce storage requirements significantly and to accommodate variable dimensioning. This FORTRAN program, SUBROUTINE RKEQ, determines truncation error coefficients for RK algorithms for orders 1 through 10 and extends the order of coefficients through 12 with the 11th- and 12th-order terms determined following the patterns used to establish the lower order coefficients. Both subroutines (the original and RKEQ) are also written to treat RK m-fold methods which utilize m known derivatives of f to increase the order of the algorithm. Setting m = 0 gives the classical RK algorithm.
A method for determination mass absorption coefficient of gamma rays by Compton scattering.
El Abd, A
2014-12-01
A method was proposed for determination mass absorption coefficient of gamma rays for compounds, alloys and mixtures. It is based on simulating interaction processes of gamma rays with target elements having atomic numbers from Z=1 to Z=92 using the MCSHAPE software. Intensities of Compton scattered gamma rays at saturation thicknesses and at a scattering angle of 90° were calculated for incident gamma rays of different energies. The obtained results showed that the intensity of Compton scattered gamma rays at saturations and mass absorption coefficients can be described by mathematical formulas. These were used to determine mass absorption coefficients for compound, alloys and mixtures with the knowledge of their Compton scattered intensities. The method was tested by calculating mass absorption coefficients for some compounds, alloys and mixtures. There is a good agreement between obtained results and calculated ones using WinXom software. The advantages and limitations of the method were discussed. PMID:25241360
Perfetti, C.; Martin, W.; Rearden, B.; Williams, M.
2012-07-01
This study introduced two new approaches for calculating the F*(r) importance weighting function for Contributon and CLUTCH eigenvalue sensitivity coefficient calculations, and compared them in terms of accuracy and applicability. The necessary levels of F*(r) mesh refinement and mesh convergence for obtaining accurate eigenvalue sensitivity coefficients were determined for two preliminary problems through two parametric studies, and the results of these studies suggest that a sufficiently accurate F*(r) mesh for calculating eigenvalue sensitivity coefficients can be obtained for these problems with only a small increase in problem runtime. (authors)
Perfetti, Christopher M; Martin, William R; Rearden, Bradley T; Williams, Mark L
2012-01-01
This study introduced three approaches for calculating the importance weighting function for Contributon and CLUTCH eigenvalue sensitivity coefficient calculations, and compared them in terms of accuracy and applicability. The necessary levels of mesh refinement and mesh convergence for obtaining accurate eigenvalue sensitivity coefficients were determined through two parametric studies, and the results of these studies suggest that a sufficiently-accurate mesh for calculating eigenvalue sensitivity coefficients can be obtained for the Contributon and CLUTCH methods with only a small increase in problem runtime.
Yarmukhamedov, R.
2014-05-09
The basic methods of the determination of asymptotic normalization coefficient for A+a→B of astrophysical interest are briefly presented. The results of the application of the specific asymptotic normalization coefficients derived within these methods for the extrapolation of the astrophysical S factors to experimentally inaccessible energy regions (E ≤ 25 keV) for the some specific radiative capture A(a,γ)B reactions of the pp-chain and the CNO cycle are presented.
NASA Astrophysics Data System (ADS)
Egorov, A. G.; Kamalutdinov, A. M.; Paimushin, V. N.; Firsov, V. A.
2016-03-01
A method for determining the drag coefficient of a thin plate harmonically oscillating in a viscous incompressible fluid is proposed. The method is based on measuring the amplitude of deflections of cantilever-fixed thin plates exhibiting damping flexural oscillations with a frequency corresponding to the first mode and on solving an inverse problem of calculating the drag coefficient on the basis of the experimentally found logarithmic decrement of beam oscillations.
NASA Astrophysics Data System (ADS)
Taler, Dawid
2012-09-01
This paper presents a numerical method for determining heat transfer coefficients in cross-flow heat exchangers with extended heat exchange surfaces. Coefficients in the correlations defining heat transfer on the liquid- and air-side were determined using a nonlinear regression method. Correlation coefficients were determined from the condition that the sum of squared liquid and air temperature differences at the heat exchanger outlet, obtained by measurements and those calculated, achieved minimum. Minimum of the sum of the squares was found using the Levenberg-Marquardt method. The uncertainty in estimated parameters was determined using the error propagation rule by Gauss. The outlet temperature of the liquid and air leaving the heat exchanger was calculated using the analytical model of the heat exchanger.
NASA Technical Reports Server (NTRS)
Lei, Ning; Chiang, Kwo-Fu; Oudrari, Hassan; Xiong, Xiaoxiong
2011-01-01
Optical sensors aboard Earth orbiting satellites such as the next generation Visible/Infrared Imager/Radiometer Suite (VIIRS) assume that the sensors radiometric response in the Reflective Solar Bands (RSB) is described by a quadratic polynomial, in relating the aperture spectral radiance to the sensor Digital Number (DN) readout. For VIIRS Flight Unit 1, the coefficients are to be determined before launch by an attenuation method, although the linear coefficient will be further determined on-orbit through observing the Solar Diffuser. In determining the quadratic polynomial coefficients by the attenuation method, a Maximum Likelihood approach is applied in carrying out the least-squares procedure. Crucial to the Maximum Likelihood least-squares procedure is the computation of the weight. The weight not only has a contribution from the noise of the sensor s digital count, with an important contribution from digitization error, but also is affected heavily by the mathematical expression used to predict the value of the dependent variable, because both the independent and the dependent variables contain random noise. In addition, model errors have a major impact on the uncertainties of the coefficients. The Maximum Likelihood approach demonstrates the inadequacy of the attenuation method model with a quadratic polynomial for the retrieved spectral radiance. We show that using the inadequate model dramatically increases the uncertainties of the coefficients. We compute the coefficient values and their uncertainties, considering both measurement and model errors.
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-06
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Photothermal determination of optical coefficients of tissue phantoms using an optical fibre probe.
Laufer, J G; Beard, P C; Walker, S P; Mills, T N
2001-10-01
The absorption and reduced scattering coefficients of turbid tissue phantoms have been determined from photothermal measurements made using an optical fibre probe. The thermal sensor was a thin polymer film positioned at the end of a multimode optical fibre. The film was illuminated by the output of a continuous-wave diode laser and formed the cavity of a low-finesse Fabry-Perot interferometer. Low energy laser pulses, launched into the fibre and passed through the film, produced an abrupt temperature rise in the target tissue, which was placed in contact with the film. The subsequent conduction of heat into the film caused a change in its optical thickness and hence the reflected intensity. The absorption and reduced scattering coefficients of gelatine tissue phantoms of known optical properties were determined from the measurements using a numerical model of photothermal signal generation and maximum a posteriori estimation. The determined optical coefficients were in good agreement with the known values. The results showed that the probe can be used for the determination of optical coefficients provided the thermal coefficients of the target tissue are known with low uncertainty. PMID:11686272
NASA Astrophysics Data System (ADS)
Aparna, John; Satheesh, S. K.; Mahadevan Pillai, V. P.
2006-12-01
The LIDAR equation contains four unknown variables in a two-component atmosphere where the effects caused by both molecules and aerosols have to be considered. The inversion of LIDAR returns to retrieve aerosol extinction profiles, thus, calls for some functional relationship to be assumed between these two. The Klett's method, assumes a functional relationship between the extinction and backscatter. In this paper, we apply a different technique, called the optical depth solution, where we made use of the total optical depth or transmittance of the atmosphere along the LIDAR-measurement range. This method provides a stable solution to the LIDAR equation. In this study, we apply this technique to the data obtained using a micro pulse LIDAR (MPL, model 1000, Science and Engineering Services Inc) to retrieve the vertical distribution of aerosol extinction coefficient. The LIDAR is equipped with Nd-YLF laser at an operating wavelength of 523.5 nm and the data were collected over Bangalore. The LIDAR data are analyzed to get to weighted extinction coefficient profiles or the weighted sum of aerosol and molecular extinction coefficient profiles. Simultaneous measurements of aerosol column optical depth (at 500 nm) using a Microtops sun photometer were used in the retrievals. The molecular extinction coefficient is determined assuming standard atmospheric conditions. The aerosol extinction coefficient profiles are determined by subtracting the molecular part from the weighted extinction coefficient profiles. The details of the method and the results obtained are presented.
Determining the Gruneisen coefficient for liquids using the PAZ-scan technique
NASA Astrophysics Data System (ADS)
Dantiste, Olivier A.
Measurement of Gruneisen coefficient is utterly important in developing efficient molecular photoacoustic (PA) contrast agents. It is one of the two parameters that describes how efficient a molecule is in transforming optical energy into sound, the other being absorption coefficient. Using the PAZ-scan technique, the Gruneisen coefficient was obtained for various samples and the values are compared with standard techniques. In a PAZ-scan, the sample is translated through the path of a focused laser beam in small steps while the generated PA signal is recorded. The incident intensity is optimum at the focal point and decreases gradually on either side of the focus. As such, the absorption and the PA signal varies according to the sample properties. Therefore at positions away from the focal point, the incident intensities are weak and the PA signal varies linearly with intensity. A plot of the PA signal versus the intensity is used to obtain the Gruneisen coefficient. Using this technique, the Gruneisen coefficients for crystal violet in two different solvents, food coloring dyes that are dissolved in water were determined. Results show that the linear part of the PAZ-scan can be used to determine the Gruneisen coefficient for liquids.
Determination of the Peltier Coefficient of Germanium in a Vertical Bridgeman-Stockbarger Furnace
NASA Technical Reports Server (NTRS)
Weigel, Michaela E. K.; Matthiesen, David H.
1997-01-01
The Peltier effect is the fundamental mechanism that makes interface demarcation through current pulsing possible. If a method for calculating the necessary current density for effective demarcation is to be developed, it will be necessary to know the value of the Peltier coefficient. This study determined experimentally the value of the Peltier coefficient for gallium-doped germanium by comparing the change in average growth rates between current-on and current-off periods. Current-on and current-off layer thickness measurements were made using differential interference contrast microscopy and atomic force microscopy. It was found that the Joule and Thomson effects could not be neglected. Peltier coefficients calculated from the experimental data with an analysis that accounts for Joule, Thomson, and Peltier effects yielded an average value for the Peltier coefficient of 0.076 +/- 0.015 V.
NASA Astrophysics Data System (ADS)
Ray, E.; Bunton, P.; Pojman, J. A.
2007-10-01
A simple technique for determining the diffusion coefficient between two miscible liquids is presented based on observing concentration-dependent ultraviolet-excited fluorescence using a digital camera. The ultraviolet-excited visible fluorescence of corn syrup is proportional to the concentration of the syrup. The variation of fluorescence with distance from the transition zone between the fluids is fit by the Fick's law solution to the diffusion equation. By monitoring the concentration at successive times, the diffusion coefficient can be determined in otherwise transparent materials. The technique is quantitative and makes measurement of diffusion accessible in the advanced undergraduate physics laboratory.
NASA Technical Reports Server (NTRS)
Penner, Reginald M.; Vandyke, Leon S.; Martin, Charles R.
1987-01-01
The current pulse E sub oc relaxation method and its application to the determination of diffusion coefficients in electrochemically synthesized polypyrrole thin films is described. Diffusion coefficients for such films in Et4NBF4 and MeCN are determined for a series of submicron film thicknesses. Measurement of the double-layer capacitance, C sub dl, and the resistance, R sub u, of polypyrrole thin films as a function of potential obtained with the galvanostatic pulse method is reported. Measurements of the electrolyte concentration in reduced polypyrrole films are also presented to aid in the interpretation of the data.
EMPIRICAL DETERMINATION OF EINSTEIN A-COEFFICIENT RATIOS OF BRIGHT [Fe II] LINES
Giannini, T.; Antoniucci, S.; Nisini, B.; Lorenzetti, D.; Alcalá, J. M.; Bacciotti, F.; Podio, L.; Bonito, R.; Stelzer, B.
2015-01-01
The Einstein spontaneous rates (A-coefficients) of Fe{sup +} lines have been computed by several authors with results that differ from each other by up to 40%. Consequently, models for line emissivities suffer from uncertainties that in turn affect the determination of the physical conditions at the base of line excitation. We provide an empirical determination of the A-coefficient ratios of bright [Fe II] lines that would represent both a valid benchmark for theoretical computations and a reference for the physical interpretation of the observed lines. With the ESO-Very Large Telescope X-shooter instrument between 3000 Å and 24700 Å, we obtained a spectrum of the bright Herbig-Haro object HH 1. We detect around 100 [Fe II] lines, some of which with a signal-to-noise ratios ≥100. Among these latter lines, we selected those emitted by the same level, whose dereddened intensity ratios are direct functions of the Einstein A-coefficient ratios. From the same X-shooter spectrum, we got an accurate estimate of the extinction toward HH 1 through intensity ratios of atomic species, H I recombination lines and H{sub 2} ro-vibrational transitions. We provide seven reliable A-coefficient ratios between bright [Fe II] lines, which are compared with the literature determinations. In particular, the A-coefficient ratios involving the brightest near-infrared lines (λ12570/λ16440 and λ13209/λ16440) are in better agreement with the predictions by the Quinet et al. relativistic Hartree-Fock model. However, none of the theoretical models predict A-coefficient ratios in agreement with all of our determinations. We also show that literature data of near-infrared intensity ratios better agree with our determinations than with theoretical expectations.
NASA Astrophysics Data System (ADS)
Gyurko, John Harrison
Most current rotor bearing analysis utilizes lumped parameter bearing coefficients to model the static and dynamic characteristics of fluid film bearings. By treating the stiffness and damping properties of the fluid film as acting upon the axial centerline of the rotor, these models are limited in their analysis to first order lateral rotor-bearing motion. The development of numerical methods that distribute the dynamic properties of the fluid film around the bearing circumference allow for higher order analysis of the motion between the bearing and rotor. Assessment of the accuracy of the numerical method used to calculate distributed dynamic fluid film bearing coefficients is performed by developing a novel hydrodynamic journal bearing test rig and experimental testing procedure capable of obtaining measured distributed dynamic coefficients over a range of bearing operating conditions. The instrumented bearing test rig is used to measure the dynamic bearing displacement and fluid film pressure responses from application of an externally applied excitation force. Least squares solution to a system of perturbated pressure equations, populated by measured displacement and pressure responses, is used to determine the hydrodynamic stiffness and damping properties for a finite region of the bearing surface. Incremental rotation of pressure sensors embedded in the body of the test bearing allow for measurement of the fluid film circumferential pressure distribution which is used to calculate a set of experimentally determined dynamic bearing coefficients. Distributed bearing coefficients derived from experimental measurements are compared to numerically calculated distributed coefficients as well as to lumped parameter coefficients generated from experimental and numerical methods found in the literature. Overall, the numerically calculated distributed coefficients successfully model both the circumferential distribution and the operating conditions of the experimental
NASA Astrophysics Data System (ADS)
van der Wal, Wouter; Wu, Patrick; Sideris, Michael G.; Shum, C. K.
2008-10-01
Monthly geopotential spherical harmonic coefficients from the GRACE satellite mission are used to determine their usefulness and limitations for studying glacial isostatic adjustment (GIA) in North-America. Secular gravity rates are estimated by unweighted least-squares estimation using release 4 coefficients from August 2002 to August 2007 provided by the Center for Space Research (CSR), University of Texas. Smoothing is required to suppress short wavelength noise, in addition to filtering to diminish geographically correlated errors, as shown in previous studies. Optimal cut-off degrees and orders are determined for the destriping filter to maximize the signal to noise ratio. The halfwidth of the Gaussian filter is shown to significantly affect the sensitivity of the GRACE data (with respect to upper mantle viscosity and ice loading history). Therefore, the halfwidth should be selected based on the desired sensitivity. It is shown that increase in water storage in an area south west of Hudson Bay, from the summer of 2003 to the summer of 2006, contributes up to half of the maximum estimated gravity rate. Hydrology models differ in the predictions of the secular change in water storage, therefore even 4-year trend estimates are influenced by the uncertainty in water storage changes. Land ice melting in Greenland and Alaska has a non-negligible contribution, up to one-fourth of the maximum gravity rate. The estimated secular gravity rate shows two distinct peaks that can possibly be due to two domes in the former Pleistocene ice cover: west and south east of Hudson Bay. With a limited number of models, a better fit is obtained with models that use the ICE-3G model compared to the ICE-5G model. However, the uncertainty in interannual variations in hydrology models is too large to constrain the ice loading history with the current data span. For future work in which GRACE will be used to constrain ice loading history and the Earth's radial viscosity profile, it is
Morin, Roger H.; Olsen, Harold W.; Nelson, Karl R.; Gill, James D.
1989-01-01
A graphical method has been developed for determining the coefficient of consolidation from the transient phases of a flow-pump permeability test. The flow pump can be used to infuse fluid into or withdraw fluid from a laboratory sediment specimen at a constant volumetric rate in order to obtain data that can be used to calculate permeability using Darcy's law. Representative type-curve solutions to the associated forced-flow and pressure-decay models are derived. These curves provide the basis for graphically evaluating the permeability k, the coefficient of consolidation cv, and the coefficient of volume change mv. The curve-matching technique is easy and rapid. Values of k, cv and mv for a laterally confined kaolinite specimen were determined by this graphical method and appear to be in reasonably good agreement with numerically derived estimates (within 20%). Discrepancies between the two sets of results seem to be largely a function of data quality.
Thomas, S; Fell, D A
1993-06-01
A computer program (MetaCon) is described for the evaluation of flux control, concentration control and branch-point distribution control coefficients of a metabolic pathway. Requiring only the reaction scheme as input, the program produces algebraic expressions for the control coefficients in terms of elasticity coefficients, metabolite concentrations and pathway fluxes. Any of these variables can be substituted by numeric or simple algebraic expressions; the expressions will then be automatically rearranged in terms of the remaining unknown variables. When all variables have been substituted, numeric values will be obtained for the control coefficients. The program is a computerized implementation of the matrix method for the determination of control coefficients. The features of MetaCon are compared with those of other programs available to workers in Metabolic Control Analysis. Potential benefits of, and methods of using, MetaCon are discussed. The mathematical background and validity of the matrix method rules are discussed, and the algorithm used by MetaCon is described. The matrix method is shown to be a specific case of a previously described general formalism for calculating control coefficients. PMID:8503870
Rapaport, R.A.; Eisenreich, S.J.
1984-03-01
Octanol-water partition coefficients of 58 poly-chlorinated biphenyl (PCB) congeners have been determined by reverse-phase C/sub 18/ high-performance liquid chromatography (HPLC) of Aroclor 1242 and 1254 mixtures. High-resolution glass capillary gas-liquid chromatography was used for the detection of the eluted individual congeners. Some PCB congeners behaved atypically from other organics on reverse-phase HPLC, and empirically derived correction factors were used to adjust K/sub ow/ values. Congener log K/sub ow/ values for PCB's ranged from an average of 4.5 for N/sub Cl/ = 1 to 8.1 for N/sub Cl/ = 7. The environmental implications of PCB K/sub ow/ values and congener behavior on the C /sub 18/ reverse-phase column are discussed. 35 references.
Styszko, Katarzyna; Kupiec, Krzysztof
2016-10-01
In this study the diffusion coefficients of isoproturon, diuron and cybutryn in acrylate and silicone resin-based renders were determined. The diffusion coefficients were determined using measuring concentrations of biocides in the liquid phase after being in contact with renders for specific time intervals. The mathematical solution of the transient diffusion equation for an infinite plate contacted on one side with a limited volume of water was used to calculate the diffusion coefficient. The diffusion coefficients through the acrylate render were 8.10·10(-9) m(2) s(-1) for isoproturon, 1.96·10(-9) m(2) s(-1) for diuron and 1.53·10(-9) m(2) s(-1) for cybutryn. The results for the silicone render were lower by one order of magnitude. The compounds with a high diffusion coefficient for one polymer had likewise high values for the other polymer. PMID:27391050
Determination of growth-stage specific crop coefficients (Kc) of cotton and wheat
Technology Transfer Automated Retrieval System (TEKTRAN)
Development of crop coefficient (Kc), the ratio of crop evapotranspiration (ETc) to reference evapotranspiration (ETo), can enhance ETc estimates in relation to specific crop phenological development. This research was conducted to determine growth-stage-specific Kc and crop water use for cotton (Go...
NASA Astrophysics Data System (ADS)
Samatham, Ravikant; Jacques, Steven L.
2013-02-01
Different techniques have been developed to determine the optical properties of turbid media, which include collimated transmission, diffuse reflectance, adding-doubling and goniometry. While goniometry can be used to determine the anisotropy of scattering (g), other techniques are used to measure the absorption coefficient and reduced scattering coefficient (μs(1-g)). But separating scattering coefficient (μs) and anisotropy of scattering from reduced scattering coefficient has been tricky. We developed an algorithm to determine anisotropy of scattering from the depth dependent decay of reflectance-mode confocal scanning laser microscopy (rCSLM) data. This report presents the testing of the algorithm on tissue phantoms with different anisotropies (g = 0.127 to 0.868, at 488 nm wavelength). Tissue phantoms were made from polystyrene microspheres (6 sizes 0.1-0.5 μm dia.) dispersed in both aqueous solutions and agarose gels. Three dimensional images were captured. The rCSLM-signal followed an exponential decay as a function of depth of the focal volume, R(z)ρexp(-μz) where ρ (dimensionless, ρ = 1 for a mirror) is the local reflectivity and μ [cm-1] is the exponential decay constant. The theory was developed to uniquely map the experimentally determined μ and ρ into the optical scattering properties μs and g. The values of μs and g depend on the composition and microstructure of tissues, and allow characterization of a tissue.
Experimental determination of the contraction coefficient of a free jet of water
NASA Astrophysics Data System (ADS)
Njock Libii, Josué; Hartenstein, Matt; Torres, Javier D.
2001-03-01
It is shown how the diameter of the jet of water exiting a hole near the base of a cylindrical container can be determined without knowing the total drain time. The contraction coefficient can be found from two measurements of the speed of the jet - one obtained from conservation of mass and the other by using projectile motion.
Determination of growth-state specific crop coefficients (Kc) of maize and sorghum
Technology Transfer Automated Retrieval System (TEKTRAN)
A ratio of crop evapotranspiration (ETC) to reference evapotranspiration (ETO) determines a crop coefficient (Kc) value, which is related to specific crop phenological development to improve transferability of the Kc values. Development of Kc can assist in predicting crop irrigation needs using mete...
Code of Federal Regulations, 2010 CFR
2010-04-01
...-related monthly adjustment amount initial determination that is based on a more recent tax year? 418.1230... Income-Related Monthly Adjustment Amount Determinations Using A More Recent Tax Year's Modified Adjusted... initial determination that is based on a more recent tax year? (a) When you make your request prior...
NASA Astrophysics Data System (ADS)
Kurudirek, M.; Medhat, M. E.
2014-07-01
An alternative approach is used to measure normalized mass attenuation coefficients (µ/ρ) of materials with unknown thickness and density. The adopted procedure is based on the use of simultaneous emission of Kα and Kβ X-ray lines as well as gamma peaks from radioactive sources in transmission geometry. 109Cd and 60Co radioactive sources were used for the purpose of the investigation. It has been observed that using the simultaneous X- and/or gamma rays of different energy allows accurate determination of relative mass attenuation coefficients by eliminating the dependence of µ/ρ on thickness and density of the material.
NASA Astrophysics Data System (ADS)
Hahne, Susanne; Ikonomov, Julian; Sokolowski, Moritz; Maass, Philipp
2013-02-01
Methods of determining surface diffusion coefficients of molecules from signal fluctuations of a locally fixed probe are revisited and refined. Particular emphasis is put on the influence of the molecule's extent. In addition to the formerly introduced autocorrelation method and residence time method, we develop a further method based on the distribution of intervals between successive peaks in the signal. The theoretical findings are applied to scanning tunneling microscopy measurements of copper phthalocyanine (CuPc) molecules on the Ag(100) surface. We discuss advantages and disadvantages of each method and suggest a combination to obtain accurate results for diffusion coefficients.
NASA Astrophysics Data System (ADS)
Veneziani, G. R.; Corrêa, E. L.; Potiens, M. P. A.; Campos, L. L.
2016-07-01
IAEA code of practice TRS-457 states that standard phantoms should offer the same primary attenuation and scatter production as relevant body section of a representative patient. Material cost, availability and dimensional stability must also be considered. The goal of this study is to determine the attenuation coefficient of printed ABS and PLA samples in standard X-ray beams, verifying if phantoms printed with these materials could be an easier-handle substitute for PMMA, enabling the creation of different designs in an easier and cheaper way. Results show that PMMA presents higher attenuation coefficient, followed by PLA and ABS, which means that thinner PMMA layer creates higher radiation attenuation.
Kinetic models for coagulation processes: determination of rate coefficients in vivo
NASA Astrophysics Data System (ADS)
Pearce, John A.; Cheong, Wai-Fung; Pandit, Kirit; McMurray, Tom J.; Thomsen, Sharon L.
1991-06-01
Kinetic models of thermal damage in tissues can be used to describe histologic end points obtained with laser irradiation. In this study, thermographic measurements of skin surface temperature distributions during laser impingement were used to derive a temperature history for the lesion site. Lesions were evaluated at 48 h after laser irradiation to determine the radius of purpura formation. The temperature histories at the maximum radius of purpura formation (threshold temperatures) were analyzed and plotted on Arrhenius axes to estimate rate coefficients for the process. As expected, transient in vivo thermal history data yielded a noisy Arrhenius plot; however, estimates of the appropriate rate coefficients for purpura formation in vivo could be made.
40 CFR 1620.6 - Authority to adjust, determine, compromise, and settle.
Code of Federal Regulations, 2011 CFR
2011-07-01
..., compromise, and settle. 1620.6 Section 1620.6 Protection of Environment CHEMICAL SAFETY AND HAZARD..., determine, compromise, and settle. The General Counsel of CSB, or his or her designee, is delegated authority to consider, ascertain, adjust, determine, compromise and settle claims under the provision of...
40 CFR 1620.6 - Authority to adjust, determine, compromise, and settle.
Code of Federal Regulations, 2010 CFR
2010-07-01
..., compromise, and settle. 1620.6 Section 1620.6 Protection of Environment CHEMICAL SAFETY AND HAZARD..., determine, compromise, and settle. The General Counsel of CSB, or his or her designee, is delegated authority to consider, ascertain, adjust, determine, compromise and settle claims under the provision of...
Increasing Self-Determination: Teaching Students To Plan, Work, Evaluate, and Adjust.
ERIC Educational Resources Information Center
Martin, James E.; Mithaug, Dennis E.; Cox, Phil; Peterson, Lori Y.; Van Dycke, Jamie L.; Cash, Mary E.
2003-01-01
A study examined the effect of self-determination contracts for 8 students (ages 9-10) with severe emotional/behavioral problems. Students completed daily self-determination contracts to schedule their work, plan for work outcomes, evaluate progress, and adjust for the next day's activity. Pre- and post-assessment found significant academic…
Maity, S; Gorai, A K; Pal, A K
2006-06-01
This paper elucidates the basic approach of determining the path coefficients and its significance in the road traffic noise annoyance. Path model not only outline the direct effect of the traffic noise on the nearby residents but also indicate the indirect effect via other variables. In this study seven variables were considered for determining road traffic noise annoyance. However the same would be equally applicable for other situations like aircraft noise, rail noise, and industry noise with the different variables. At the outset a priori path model was designed and then on the basis of the partial regression coefficient values for the different paths, the revised path model was developed. The standardized partial regression coefficients known as path coefficients, determine the strength of the linkage among variables. Some of the paths in the model were not statistically significant. Revised path models were developed by deleting the insignificant paths whose values were found above 5% level. In the revised path model, thus the direct and indirect effect due to a particular variable causing the road traffic noise annoyance could be observed. PMID:16917695
A robust method for determining calibration coefficients for VIIRS reflective solar bands
NASA Astrophysics Data System (ADS)
Ji, Qiang; McIntire, Jeffrey; Efremova, Boryana; Schwarting, Thomas; Oudrari, Hassan; Zeng, Jinan; Xiong, Xiaoxiong
2015-09-01
This paper presents a robust method for determining the calibration coefficients in polynomial calibration equations, and discusses the corresponding calibration uncertainties. An attenuator method that takes into account all measurements with and without an attenuator screen was used to restrict the impact of the absolute calibration of the light source. The originally proposed procedure attempts to simultaneously determine all unknowns nonlinearly using polynomial curve fitting. The newly proposed method divides the task into two simpler parts. For example, in the case of a quadratic calibration equation, the first part becomes a quadratic equation solely for the transmittance of attenuator, which has an analytical solution using three or four sets of measurements. Additionally, it is straightforward to determine the median value and the standard deviation of the transmittance from the solutions using all combinations of measured data points. In conjunction, the second part becomes a linear fit, with the ratio of the zeroth-order to first-order calibration coefficients as the intercept and the ratio of the second-order to first-order calibration coefficients as the slope. These ratios are unaffected by the absolute calibration of the light source and are then used in the calibration equation to calculate the first-order calibration coefficient. How the new method works is straightforward to visualize, which makes its results easier to verify. This is demonstrated using measurements from the Joint Polar Satellite System (JPSS) J1 Visible Infrared Imaging Radiometer Suite (VIIRS) reflective solar bands (RSB) pre-launch testing.
Kruk, D; Meier, R; Rachocki, A; Korpała, A; Singh, R K; Rössler, E A
2014-06-28
Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220-258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF4, 243-318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6, 258-323 K). The dispersion of (1)H spin-lattice relaxation rate R1(ω) is measured in the frequency range of 10 kHz-20 MHz, and the studies are complemented by (19)F spin-lattice relaxation measurements on BMIM-PF6 in the corresponding frequency range. From the (1)H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF4, and BMIM-PF6 are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the (1)H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R1 on square root of frequency. From the (19)F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF6. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids. PMID:24985656
NASA Astrophysics Data System (ADS)
Kruk, D.; Meier, R.; Rachocki, A.; Korpała, A.; Singh, R. K.; Rössler, E. A.
2014-06-01
Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220-258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF4, 243-318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6, 258-323 K). The dispersion of 1H spin-lattice relaxation rate R1(ω) is measured in the frequency range of 10 kHz-20 MHz, and the studies are complemented by 19F spin-lattice relaxation measurements on BMIM-PF6 in the corresponding frequency range. From the 1H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF4, and BMIM-PF6 are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the 1H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R1 on square root of frequency. From the 19F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF6. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids.
Izumi, Tatsuya; Hagiwara, Manabu; Hoshina, Takuya; Takeda, Hiroaki; Tsurumi, Takaaki
2012-08-01
We developed a possible method to determine both coefficients of piezoelectricity (d) and electrostriction (M) at the same time by a waveform analysis of current and vibration velocity in the resonance state. The waveforms of the current and vibration velocity were theoretically described using the equations of motion and piezoelectric constitutive equations, considering the dissipation effect. The dissipation factor of the d coefficient and M coefficient is dielectric loss tangent tan δ. The waveforms measured in all of the ceramics, such as Pb(Zr,Ti)O(3) (PZT), Pb(Mg,Nb)O(3) (PMN), and 0.8Pb(Mg(1/3)Nb2/3)O(3)-0.2PbTiO(3) (PMN-PT), were well fitted with the calculated waveform. This fitting produced both the d and M coefficients, which agreed with those determined via the conventional methods. Moreover, the respective contributions of both piezoelectricity and electrostriction to the d value determined in the resonance-antiresonance method were clarified. PMID:22899111
Determination of mass attenuation coefficient of low-Z dosimetric materials
NASA Astrophysics Data System (ADS)
El-Khayatt, A. M.; Ali, A. M.; Singh, Vishwanath P.; Badiger, N. M.
2014-12-01
The mass attenuation coefficients of some low-Z dosimetric materials with potential applications in dosimetry, medical and radiation protection have been investigated using the Monte Carlo simulation code Monte Carlo N-Particle (MCNP). Appreciable variations are noted for the mass attenuation coefficient by changing the photon energy. The MCNP-simulated parameters are compared with the experimental data wherever possible and theoretical values through the WinXcom program. The simulated results obtained by MCNP generally agree well with the experiment and WinXcom predictions for various low-Z dosimetric and tissue substitute materials. In addition, the mass attenuation coefficients around the k-edges for low-Z dosimetric materials estimated from the MCNP code agree very well with WinXcom prediction. Finally, the results indicate that this simulation process can be followed to determine the interaction parameters of gamma rays in such low-Z materials for which there are no satisfactory experimental values available.
NASA Astrophysics Data System (ADS)
Ohsaka, K.; Rednikov, A.; Sadhal, S. S.
2003-02-01
We present a technique that can be used to determine the thermal diffusivity coefficient of undercooled liquids, which exist at temperatures below their freezing points. The technique involves levitation of a small amount of liquid in a flattened drop shape using an acoustic levitator and heating it with a laser beam. The heated drop is then subjected to natural cooling by heat loss from the surface. Due to acoustic streaming, the heat loss mainly occurs through the equator section of the drop. The measured cooling rate in combination with a radial heat conduction model allows us to calculate the thermal diffusivity coefficient of the drop. We demonstrate the feasibility of the technique using glycerin drops as a model liquid. The technique is well suited if the thermal diffusivity coefficient of the liquid in the normal state (i.e., above the freezing point) is known or can be measured by conventional techniques.
NASA Astrophysics Data System (ADS)
Orych, A.; Walczykowski, P.; Jenerowicz, A.; Zdunek, Z.
2014-11-01
Nowadays remote sensing plays a very important role in many different study fields, i.e. environmental studies, hydrology, mineralogy, ecosystem studies, etc. One of the key areas of remote sensing applications is water quality monitoring. Understanding and monitoring of the water quality parameters and detecting different water contaminants is an important issue in water management and protection of whole environment and especially the water ecosystem. There are many remote sensing methods to monitor water quality and detect water pollutants. One of the most widely used method for substance detection with remote sensing techniques is based on usage of spectral reflectance coefficients. They are usually acquired using discrete methods such as spectrometric measurements. These however can be very time consuming, therefore image-based methods are used more and more often. In order to work out the proper methodology of obtaining spectral reflectance coefficients from hyperspectral and multispectral images, it is necessary to verify the impact of cameras radiometric resolution on the accuracy of determination of them. This paper presents laboratory experiments that were conducted using two monochromatic XEVA video sensors (400-1700 nm spectral data registration) with two different radiometric resolutions (12 and 14 bits). In view of determining spectral characteristics from images, the research team used set of interferometric filters. All data collected with multispectral digital video cameras were compared with spectral reflectance coefficients obtained with spectroradiometer. The objective of this research is to find the impact of cameras radiometric resolution on reflectance values in chosen wavelength. The main topic of this study is the analysis of accuracy of spectral coefficients from sensors with different radiometric resolution. By comparing values collected from images acquired with XEVA sensors and with the curves obtained with spectroradiometer it
NASA Astrophysics Data System (ADS)
Suzuki, S.; Itoh, H.
2016-05-01
The diffusion coefficient of the metastable excited Ne(3P2) atom in neon, the reflection coefficient of Ne(3P2) at the surface of an electrode and the rate coefficient of Ne(3P2) for collisional quenching by Ne(1S0) were determined from the gas pressure dependence of the effective lifetime of Ne(3P2). The effective lifetime of Ne(3P2) was measured from the transient current after turning off the Ultraviolet (UV) light in a Townsend discharge. The observed transient current waveform was analysed by solving the diffusion equation for the metastable excited Ne(3P2) atom using the third kind of boundary condition. The rate coefficient of Ne(3P2) for collisional quenching by Ne(1S0) and the reflection coefficient were determined by a nonspectroscopic method for the first time in neon to the best of our knowledge and were (3.2 ± 0.4) × 10‑16 cm3 s‑1 and 0.10 ± 0.04, respectively. The obtained diffusion coefficient at 1 Torr was 177 ± 17 cm2 s‑1, which is consistent with the value reported by Dixon and Grant. Moreover, the present results are compared with the results of Phelps and were found to be in good agreement. We also discuss the deexcitation rate of Ne(3P2) at pressures of up to 60 Torr in comparison with previously reported values.
NASA Astrophysics Data System (ADS)
Shvets, I. T.; Dyban, Ye. P.; Selyavin, G. F.; Stradomskiy, M. V.
1988-01-01
Following are some conclusions reached in the determination of the haydraulic resistance of apertures in rotary disks: (1) rotation of disk exerts a substantial influence on condition of course of air through apertures. In the large ratios of the velocity of the rotation of the mean flow rate in the aperture (order u/c = 2.5) the value of the coefficient of flow rate for the apertures with the sharp entering edges decreases approximately 6 times; (2) with sufficient high u/c (more than 4) effect of form of entering edges it is possible not to consider; (3) rounding of trailing edges virtually does not have effect on conditions of air flow through apertures in rotary disks; (4) coefficient of flow rate of apertures of square form investigated in work is close to coefficient of expenditure of cylindrical channels (with identical hydraulic radii); (5) relative depth of aperture in the range of relations 0.96 less than l/d less than 6.04 virtually does not have effect on dependence of value of coefficient of flow rate from rotation; (6) on the basis of analysis of experimental data in work empirical dependence of coefficients of flow rate and hydraulic resistance on parameters K and K, are obtained. The ratios indicated are valid for the disk, which rotates in the housing with the value relative to the axial clearance between the disk and the housing of more than 1.5.
Determination of macroscopic transport coefficients of a dissipative particle dynamics solvent
NASA Astrophysics Data System (ADS)
Azarnykh, Dmitrii; Litvinov, Sergey; Bian, Xin; Adams, Nikolaus A.
2016-01-01
We present an approach to determine macroscopic transport coefficients of a dissipative particle dynamics (DPD) solvent. Shear viscosity, isothermal speed of sound, and bulk viscosity result from DPD-model input parameters and can be determined only a posteriori. For this reason approximate predictions of these quantities are desirable in order to set appropriate DPD input parameters. For the purpose of deriving an improved approximate prediction we analyze the autocorrelation of shear and longitudinal modes in Fourier space of a DPD solvent for Kolmogorov flow. We propose a fitting function with nonexponential properties which gives a good approximation to these autocorrelation functions. Given this fitting function we improve significantly the capability of a priori determination of macroscopic solvent transport coefficients in comparison to previously used exponential fitting functions.
Determination of macroscopic transport coefficients of a dissipative particle dynamics solvent.
Azarnykh, Dmitrii; Litvinov, Sergey; Bian, Xin; Adams, Nikolaus A
2016-01-01
We present an approach to determine macroscopic transport coefficients of a dissipative particle dynamics (DPD) solvent. Shear viscosity, isothermal speed of sound, and bulk viscosity result from DPD-model input parameters and can be determined only a posteriori. For this reason approximate predictions of these quantities are desirable in order to set appropriate DPD input parameters. For the purpose of deriving an improved approximate prediction we analyze the autocorrelation of shear and longitudinal modes in Fourier space of a DPD solvent for Kolmogorov flow. We propose a fitting function with nonexponential properties which gives a good approximation to these autocorrelation functions. Given this fitting function we improve significantly the capability of a priori determination of macroscopic solvent transport coefficients in comparison to previously used exponential fitting functions. PMID:26871186
Byun, Jong-In; Yun, Ju-Yong
2015-08-01
It is shown that the gamma-ray linear attenuation coefficient of a sample with unknown chemical composition can be determined through a systematic calibration of the correlation between the linear attenuation coefficient, gamma-ray energy and the relative degree of attenuation. For calibration, H2O, MnO2, NaCl, Na2CO3 and (NH4)2SO4 were used as reference materials. Point-like gamma-ray sources with modest activity of approximately 37kBq, along with an HPGe detector, were used in the measurements. A semi-empirical formula was derived to calculate the linear attenuation coefficients as a function of the relative count rate and the gamma-ray energy. The method was applied to the determination of the linear attenuation coefficients for K2CrO4 and SiO2 test samples in the same setup used in calibration. The experimental result agreed well with the ones calculated by elementary data. PMID:25997111
NASA Astrophysics Data System (ADS)
Imel, Adam; Miller, Brad; Holley, Wade; Baskaran, Durairaj; Mays, Jimmy; Dadmun, Mark
2015-03-01
The diffusion properties of nanoparticles in polymer nanocomposites are largely unknown and depend intimately on the dispersion of the nanoparticles. We examine the diffusion of soft, organic nanoparticles, which disperse in a polymer matrix due to the interpenetration of polymer chains and particles and the reduction in the depletion of entropy in the system. The impact of the presence of soft nanoparticles on the diffusion coefficient of polystyrene chains has recently been determined with neutron reflectivity. This was completed by monitoring the interdiffusion of deuterated and protonated polystyrene nanocomposite bilayers with and without the soft nanoparticles dispersed throughout both layers and extracting the diffusion coefficient from the one-dimensional solution to Fick's second law of diffusion. In this work, we extend this method to bilayer systems with only the soft nanoparticles as one of the layers and a linear deuterated polystyrene as an adjacent layer. The development of this method allows us to determine the tracer diffusion coefficient of the soft polystyrene nanoparticles for the first time by analyzing the mutual diffusion coefficient from Fick's second law and the fast and slow modes theories for diffusion.
Determination of drying kinetics and convective heat transfer coefficients of ginger slices
NASA Astrophysics Data System (ADS)
Akpinar, Ebru Kavak; Toraman, Seda
2015-12-01
In the present work, the effects of some parametric values on convective heat transfer coefficients and the thin layer drying process of ginger slices were investigated. Drying was done in the laboratory by using cyclone type convective dryer. The drying air temperature was varied as 40, 50, 60 and 70 °C and the air velocity is 0.8, 1.5 and 3 m/s. All drying experiments had only falling rate period. The drying data were fitted to the twelve mathematical models and performance of these models was investigated by comparing the determination of coefficient (R 2), reduced Chi-square (χ 2) and root mean square error between the observed and predicted moisture ratios. The effective moisture diffusivity and activation energy were calculated using an infinite series solution of Fick's diffusion equation. The average effective moisture diffusivity values and activation energy values varied from 2.807 × 10-10 to 6.977 × 10-10 m2/s and 19.313-22.722 kJ/mol over the drying air temperature and velocity range, respectively. Experimental data was used to evaluate the values of constants in Nusselt number expression by using linear regression analysis and consequently, convective heat transfer coefficients were determined in forced convection mode. Convective heat transfer coefficient of ginger slices showed changes in ranges 0.33-2.11 W/m2 °C.
Random effects coefficient of determination for mixed and meta-analysis models.
Demidenko, Eugene; Sargent, James; Onega, Tracy
2012-01-01
The key feature of a mixed model is the presence of random effects. We have developed a coefficient, called the random effects coefficient of determination, [Formula: see text], that estimates the proportion of the conditional variance of the dependent variable explained by random effects. This coefficient takes values from 0 to 1 and indicates how strong the random effects are. The difference from the earlier suggested fixed effects coefficient of determination is emphasized. If [Formula: see text] is close to 0, there is weak support for random effects in the model because the reduction of the variance of the dependent variable due to random effects is small; consequently, random effects may be ignored and the model simplifies to standard linear regression. The value of [Formula: see text] apart from 0 indicates the evidence of the variance reduction in support of the mixed model. If random effects coefficient of determination is close to 1 the variance of random effects is very large and random effects turn into free fixed effects-the model can be estimated using the dummy variable approach. We derive explicit formulas for [Formula: see text] in three special cases: the random intercept model, the growth curve model, and meta-analysis model. Theoretical results are illustrated with three mixed model examples: (1) travel time to the nearest cancer center for women with breast cancer in the U.S., (2) cumulative time watching alcohol related scenes in movies among young U.S. teens, as a risk factor for early drinking onset, and (3) the classic example of the meta-analysis model for combination of 13 studies on tuberculosis vaccine. PMID:23750070
Thermal diffusivity coefficient of glycerin determined on an acoustically levitated drop.
Ohsaka, K; Rednikov, A; Sadhal, S S
2002-10-01
We present a technique that can be used to determine the thermal diffusivity coefficient of undercooled liquids that exist at temperatures below their freezing points. The technique involves levitation of a small amount of liquid in the shape of a flattened drop using an acoustic levitator and heating it with a CO2 laser. The heated drop is then allowed to cool naturally by heat loss from the surface. Due to acoustic streaming, heat loss is highly non-uniform and appears to mainly occur at the drop circumference (equatorial region). This fact allows us to relate the heat loss rate with a heat transfer model to determine the thermal diffusion coefficient. We demonstrate the feasibility of the technique using glycerin drops as a model liquid. PMID:12446319
Determining the nominal power transfer coefficient for passive surface acoustic wave devices
NASA Astrophysics Data System (ADS)
Timoshenko, A. N.; Palamarchuk, A. A.; Semenko, A. I.
1982-05-01
A method for calculating the nominal power transfer coefficient of passive SAW devices operating in a linear mode is described. Relations of practical importance are obtained, making it possible, on the basis of known characteristics of acousto-electric transducers and acoustic lines, to determine the losses incurred by devices when they are connected to radioelectronic equipment. The relations also permit an assessment of the uniformity of the amplitude-frequency characteristics of the devices.
Determination of the nonlinear optical coefficients of the BaGa(4)Se(7) crystal.
Zhang, Xin; Yao, Jiyong; Yin, Wenlong; Zhu, Yong; Wu, Yicheng; Chen, Chuangtian
2015-01-12
The second-order nonlinear optical (NLO) coefficients of the BaGa(4)Se(7) crystal were experimentally determined through the Maker Fringe Technique for the first time. The values of the two major nonlinear tensor elements d11 and d13 were 24.3 and 20.4 pm/V, respectively. These results were in agreement with the ones obtained through theoretical calculations. PMID:25835701
Zarabadi, Atefeh S; Pawliszyn, Janusz
2015-02-17
Analysis in the frequency domain is considered a powerful tool to elicit precise information from spectroscopic signals. In this study, the Fourier transformation technique is employed to determine the diffusion coefficient (D) of a number of proteins in the frequency domain. Analytical approaches are investigated for determination of D from both experimental and data treatment viewpoints. The diffusion process is modeled to calculate diffusion coefficients based on the Fourier transformation solution to Fick's law equation, and its results are compared to time domain results. The simulations characterize optimum spatial and temporal conditions and demonstrate the noise tolerance of the method. The proposed model is validated by its application for the electropherograms from the diffusion path of a set of proteins. Real-time dynamic scanning is conducted to monitor dispersion by employing whole column imaging detection technology in combination with capillary isoelectric focusing (CIEF) and the imaging plug flow (iPF) experiment. These experimental techniques provide different peak shapes, which are utilized to demonstrate the Fourier transformation ability in extracting diffusion coefficients out of irregular shape signals. Experimental results confirmed that the Fourier transformation procedure substantially enhanced the accuracy of the determined values compared to those obtained in the time domain. PMID:25607375
Determination of the crystal-melt interface kinetic coefficient from molecular dynamics simulations
NASA Astrophysics Data System (ADS)
Monk, J.; Yang, Y.; Mendelev, M. I.; Asta, M.; Hoyt, J. J.; Sun, D. Y.
2010-01-01
The generation and dissipation of latent heat at the moving solid-liquid boundary during non-equilibrium molecular dynamics (MD) simulations of crystallization can lead to significant underestimations of the interface mobility. In this work we examine the heat flow problem in detail for an embedded atom description of pure Ni and offer strategies to obtain an accurate value of the kinetic coefficient, μ. For free-solidification simulations in which the entire system is thermostated using a Nose-Hoover or velocity rescaling algorithm a non-uniform temperature profile is observed and a peak in the temperature is found at the interface position. It is shown that if the actual interface temperature, rather than the thermostat set point temperature, is used to compute the kinetic coefficient then μ is approximately a factor of 2 larger than previous estimates. In addition, we introduce a layered thermostat method in which several sub-regions, aligned normal to the crystallization direction, are indepently thermostated to a desired undercooling. We show that as the number of thermostats increases (i.e., as the width of each independently thermostated layer decreases) the kinetic coefficient converges to a value consistent with that obtained using a single thermostat and the calculated interface temperature. Also, the kinetic coefficient was determined from an analysis of the equilibrium fluctuations of the solid-liquid interface position. We demonstrate that the kinetic coefficient obtained from the relaxation times of the fluctuation spectrum is equivalent to the two values obtained from free-solidification simulations provided a simple correction is made for the contribution of heat flow controlled interface motion. Finally, a one-dimensional phase field model that captures the effect of thermostats has been developed. The mesoscale model reproduces qualitatively the results from MD simulations and thus allows for an a priori estimate of the accuracy of a kinetic
Determination of the heat transfer coefficient from IRT measurement data using the Trefftz method
NASA Astrophysics Data System (ADS)
Maciejewska, Beata; Strąk, Kinga; Piasecka, Magdalena
2016-03-01
The paper presents the method of heat transfer coefficient determination for boiling research during FC-72 flow in the minichannels, each 1.7 mm deep, 24 mm wide and 360 mm long. The heating element was the thin foil, enhanced on the side which comes into contact with fluid in the minichannels. Local values of the heat transfer coefficient were calculated from the Robin boundary condition. The foil temperature distribution and the derivative of the foil temperature were obtained by solving the two-dimensional inverse heat conduction problem, due to measurements obtained by IRT. Calculations was carried out by the method based on the approximation of the solution of the problem using a linear combination of Trefftz functions. The basic property of this functions is they satisfy the governing equation. Unknown coefficients of linear combination of Trefftz functions are calculated from the minimization of the functional that expresses the mean square error of the approximate solution on the boundary. The results presented as IR thermographs, two-phase flow structure images and the heat transfer coefficient as a function of the distance from the channel inlet, were analyzed.
NASA Astrophysics Data System (ADS)
Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal R.; Bohndiek, Sarah E.
2016-03-01
Optoacoustic Tomography is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound detection with the high contrast available from optical absorption in tissue. The spectral profile of near infrared excitation light used in optoacoustic tomography instruments is modified by absorption and scattering as it propagates deep into biological tissue. The resulting images therefore provide only qualitative insight into the distribution of tissue chromophores. Knowledge of the spectral profile of excitation light across the mouse is needed for accurate determination of the absorption coefficient in vivo. Under the conditions of constant Grueneisen parameter and accurate knowledge of the light fluence, a linear relationship should exist between the initial optoacoustic pressure amplitude and the tissue absorption coefficient. Using data from a commercial optoacoustic tomography system, we implemented an iterative optimization based on the σ-Eddington approximation to the Radiative Transfer Equation to derive a light fluence map within a given object. We segmented the images based on the positions of phantom inclusions, or mouse organs, and used known scattering coefficients for initialization. Performing the fluence correction in simple phantoms allowed the expected linear relationship between recorded and independently measured absorption coefficients to be retrieved and spectral coloring to be compensated. For in vivo data, the correction resulted in an enhancement of signal intensities in deep tissues. This improved our ability to visualize organs at depth (> 5mm). Future work will aim to perform the optimization without data normalization and explore the need for methodology that enables routine implementation for in vivo imaging.
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Kruk, D.; Meier, R.; Rössler, E. A.; Rachocki, A.; Korpała, A.; Singh, R. K.
2014-06-28
Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220–258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF{sub 4}, 243–318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF{sub 6}, 258–323 K). The dispersion of {sup 1}H spin-lattice relaxation rate R{sub 1}(ω) is measured in the frequency range of 10 kHz–20 MHz, and the studies are complemented by {sup 19}F spin-lattice relaxation measurements on BMIM-PF{sub 6} in the corresponding frequency range. From the {sup 1}H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF{sub 4}, and BMIM-PF{sub 6} are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the {sup 1}H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R{sub 1} on square root of frequency. From the {sup 19}F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF{sub 6}. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids.
Determination of piezo-optic coefficients of crystals by means of four-point bending.
Krupych, Oleg; Savaryn, Viktoriya; Krupych, Andriy; Klymiv, Ivan; Vlokh, Rostyslav
2013-06-10
A technique developed recently for determining piezo-optic coefficients (POCs) of isotropic optical media, which represents a combination of digital imaging laser interferometry and a classical four-point bending method, is generalized and applied to a single-crystalline anisotropic material. The peculiarities of measuring procedures and data processing for the case of optically uniaxial crystals are described in detail. The capabilities of the technique are tested on the example of canonical nonlinear optical crystal LiNbO3. The high precision achieved in determination of the POCs for isotropic and anisotropic materials testifies that the technique should be both versatile and reliable. PMID:23759855
Determination of PCB Elimination Coefficients in Round Goby and Tubenose Goby.
Sun, Xin; Johnson, Tim B; Drouillard, Ken G
2016-09-01
Whole-body elimination coefficients of polychlorinated biphenyls (PCBs) were determined in two Great Lakes invasive fish species, round goby (Neogobius melanostomus) and tubenose goby (Proterorhinus semilunaris). Elimination rates were determined for a set of model PCB congeners (n = 12 congeners) dosed to fish by intraperitoneal injection and allowed to depurate at a temperature of 21.4°C for 90 days. Eight PCBs (PCB 6, 21, 57, 62, 68, 89, 112 and 125) exhibited significant elimination by round goby and had corresponding half lives ranging from 13 to 39.8 days. For tubenose goby, four congeners (PCBs 21, 57, 62 and 68) exhibited significant elimination with half lives in the range from 18.8 to 48.8 days. Whole-body elimination rate coefficients were significantly higher for round gobies compared to tubenose goby. In both cases, PCB elimination rate coefficients were negatively related to chemical log KOW. PMID:27385369
NASA Astrophysics Data System (ADS)
Asadian, M.; Saeedi, H.; Yadegari, M.; Shojaee, M.
2014-06-01
In this paper, a new mathematical model has been presented to determine the equilibrium segregation (k0) and effective segregation (keff) coefficients for neodymium (Nd) in YAG crystal grown by Czochralski (CZ) method. Determination of diffusion coefficient (DL) of Nd impurity in molten YAG is also investigated. In this model, utilizing Lambert W-function is a new idea to solve the Scheil equation for calculation of effective segregation coefficient. The Nd concentration in the crystal has been measured by optical absorption method to calculate keff. The analyses show that the keff is related to the growth parameters such as crystal growth rate (ug) and crystal rotation rate (ω), ( ug/√{ω}) but it is independent of the Nd concentration in the initial melt (C0). Based on obtained keff and experimental growth data, k0 and DL of Nd in molten YAG have been calculated. For all experiments, the average value of k0=0.216 and DL=1.4×10-6 (cm2/s) are obtained. Our results are corroborated by the theoretical and experimental data from the literature.
Determination of heat transfer coefficient for an interaction of sub-cooled gas and metal
NASA Astrophysics Data System (ADS)
Zaidi Sidek, Mohd; Syahidan Kamarudin, Muhammad
2016-02-01
Heat transfer coefficient (HTC) for a hot metal surface and their surrounding is one of the need be defined parameter in hot forming process. This study has been conducted to determine the HTC for an interaction between sub-cooled gas sprayed on a hot metal surface. Both experiments and finite element have been adopted in this work. Initially, the designated experiment was conducted to obtain temperature history of spray cooling process. Then, an inverse method was adopted to calculate the HTC value before we validate in a finite element simulation model. The result shows that the heat transfer coefficient for interaction of subcooled gas and hot metal surface is 1000 W/m2K.
Determination of RW3-to-water mass-energy absorption coefficient ratio for absolute dosimetry.
Seet, Katrina Y T; Hanlon, Peta M; Charles, Paul H
2011-12-01
The measurement of absorbed dose to water in a solid-phantom may require a conversion factor because it may not be radiologically equivalent to water. One phantom developed for the use of dosimetry is a solid water, RW3 white-polystyrene material by IBA. This has a lower mass-energy absorption coefficient than water due to high bremsstrahlung yield, which affects the accuracy of absolute dosimetry measurements. In this paper, we demonstrate the calculation of mass-energy absorption coefficient ratios, relative to water, from measurements in plastic water and RW3 with an Elekta Synergy linear accelerator (6 and 10 MV photon beams) as well as Monte Carlo modeling in BEAMnrc and DOSXYZnrc. From this, the solid-phantom-to-water correction factor was determined for plastic water and RW3. PMID:21960410
Ionization constants by curve fitting: application to the determination of partition coefficients.
Clarke, F H
1984-02-01
A multiparametric curve-fitting technique for pKa calculation has been adapted for use with a programmable calculator or microcomputer. This method provides for the convenient and accurate determination of the ionization constant in aqueous solution and of the apparent ionization constant in the presence of octanol. From these parameters, partition coefficients and apparent partition coefficients are easily calculated and agree with data reported using the shaker technique or HPLC. The curve-fitting method has been applied to the differential titration technique in which the solvent curve is subtracted from the solution curve before calculations are begun. This method has been applied to the potentiometric titration of aqueous solutions of the salts of bases with a very low solubility in water. PMID:6707889
Fadeyi, Michael; Tran, Tin
2013-01-01
Primary immunodeficiency disease (PIDD) is an inherited disorder characterized by an inadequate immune system. The most common type of PIDD is antibody deficiency. Patients with this disorder lack the ability to make functional immunoglobulin G (IgG) and require lifelong IgG replacement therapy to prevent serious bacterial infections. The current standard therapy for PIDD is intravenous immunoglobulin (IVIG) infusions, but IVIG might not be appropriate for all patients. For this reason, subcutaneous immunoglobulin (SCIG) has emerged as an alternative to IVIG. A concern for physicians is the precise SCIG dose that should be prescribed, because there are pharmacokinetic differences between IVIG and SCIG. Manufacturers of SCIG 10% and 20% liquid (immune globulin subcutaneous [human]) recommend a dose-adjustment coefficient (DAC). Both strengths are currently approved by the FDA. This DAC is to be used when patients are switched from IVIG to SCIG. In this article, we propose another dosing method that uses a higher ratio of IVIG to SCIG and an incremental adjustment based on clinical status, body weight, and the presence of concurrent diseases. PMID:24391400
Gallis, Michail A.; Castaneda, Jaime N.; Rader, Daniel John; Torczynski, John Robert; Trott, Wayne Merle
2010-10-01
Thermal accommodation coefficients have been derived for a variety of gas-surface combinations using an experimental apparatus developed to measure the pressure dependence of the conductive heat flux between parallel plates at unequal temperature separated by a gas-filled gap. The heat flux is inferred from temperature-difference measurements across the plates in a configuration where the plate temperatures are set with two carefully controlled thermal baths. Temperature-controlled shrouds provide for environmental isolation of the opposing test plates. Since the measured temperature differences in these experiments are very small (typically 0.3 C or less over the entire pressure range), high-precision thermistors are used to acquire the requisite temperature data. High-precision components have also been utilized on the other control and measurement subsystems in this apparatus, including system pressure, gas flow rate, plate alignment, and plate positions. The apparatus also includes the capability for in situ plasma cleaning of the installed test plates. Measured heat-flux results are used in a formula based on Direct Simulation Monte Carlo (DSMC) code calculations to determine the thermal accommodation coefficients. Thermal accommodation coefficients have been determined for three different gases (argon, nitrogen, helium) in contact with various surfaces. Materials include metals and alloys such as aluminum, gold, platinum, and 304 stainless steel. A number of materials important to fabrication of Micro Electro Mechanical Systems (MEMS) devices have also been examined. For most surfaces, coefficient values are near 0.95, 0.85, and 0.45 for argon, nitrogen, and helium, respectively. Only slight differences in accommodation as a function of surface roughness have been seen. Surface contamination appears to have a more significant effect: argon plasma treatment has been observed to reduce thermal accommodation by as much as 0.10 for helium. Mixtures of argon and
Sundaram, P.A.; Wessel, E.; Clemens, H.; Kestler, H.; Ennis, P.J.; Quadakkers, W.J.; Singheiser, L.
2000-03-14
The diffusion coefficient of hydrogen in some gamma based titanium aluminide alloys was determined at room temperature using an electrochemical techniques. A cast Ti-48Al-2Cr alloy as well as Ti-46.5Al-4(Cr,Nb,Ta,B) sheet material with primary annealed and designed fully lamellar microstructures were subjected to cathodic hydrogen charging at room temperature in the galvanostatic mode. The potential variation with time was monitored form which data the values of the diffusion coefficient of hydrogen, D were calculated form well known error function/infinite series solutions to Fick's second law. Very good correlation was obtained with respect to theoretical calculations. The diffusion coefficients appear to be in close agreement with those for the cast alloy calculated from microhardness measurements. The value of D can be overestimated for thick specimens. Results show that neither the microstructure in terms of grain/lamellar colony size, nor the charging current density, appear to have a significant effect on the value of D. Lattice diffusion appears to be rate controlling.
NASA Astrophysics Data System (ADS)
Dag, Yusuf
Forced convection over traditional surfaces such as flat plate, cylinder and sphere have been well researched and documented. Data on forced convection over airfoil surfaces, however, remain very scanty in literature. High altitude vehicles that employ airfoils as lifting surfaces often suffer leading edge ice accretions which have tremendous negative consequences on the lifting capabilities and stability of the vehicle. One of the ways of mitigating the effect of ice accretion involves judicious leading edge convective cooling technique which in turn depends on the accuracy of convective heat transfer coefficient used in the analysis. In this study empirical investigation of convective heat transfer measurements on asymmetric airfoil is presented at different angle of attacks ranging from 0° to 20° under subsonic flow regime. The top and bottom surface temperatures are measured at given points using Senflex hot film sensors (Tao System Inc.) and used to determine heat transfer characteristics of the airfoils. The model surfaces are subjected to constant heat fluxes using KP Kapton flexible heating pads. The monitored temperature data are then utilized to determine the heat convection coefficients modelled empirically as the Nusselt Number on the surface of the airfoil. The experimental work is conducted in an open circuit-Eiffel type wind tunnel, powered by a 37 kW electrical motor that is able to generate subsonic air velocities up to around 41 m/s in the 24 square-inch test section. The heat transfer experiments have been carried out under constant heat flux supply to the asymmetric airfoil. The convective heat transfer coefficients are determined from measured surface temperature and free stream temperature and investigated in the form of Nusselt number. The variation of Nusselt number is shown with Reynolds number at various angles of attacks. It is concluded that Nusselt number increases with increasing Reynolds number and increase in angle of attack from 0
Tucker, M.D.
1995-05-01
Uranium contamination of groundwaters and surface waters near abandoned mill tailings piles is a serious concern in many areas of the western United States. Uranium usually exists in either the U(IV) or the U(VI) oxidation state. U(VI) is soluble in water and, as a result, is very mobile in the environment. U(IV), however, is generally insoluble in water and, therefore, is not subject to aqueous transport. In recent years, researchers have discovered that certain anaerobic microorganisms, such as the sulfate-reducing bacteria Desulfovibrio desulfuricans, can mediate the reduction of U(VI) to U(IV). Although the ability of this microorganism to reduce U(VI) has been studied in some detail by previous researchers, the kinetics of the reactions have not been characterized. The purpose of this research was to perform kinetic studies on Desulfovibrio desulficans bacteria during simultaneous reduction of sulfate and uranium and to determine the phase in which uranium exists after it has been reduced and precipitated from solution. The studies were conducted in a laboratory-scale chemostat under substrate-limited growth conditions with pyruvate as the substrate. Kinetic coefficients for substrate utilization and cell growth were calculated using the Monod equation. The maximum rate of substrate utilization (k) was determined to be 4.70 days{sup {minus}1} while the half-velocity constant (K{sub s}) was 140 mg/l COD. The yield coefficient (Y) was determined to be 0.17 mg cells/mg COD while the endogenous decay coefficient (k{sub d}) was calculated as 0.072 days{sup {minus}1}. After reduction, U(IV) Precipitated from solution in the uraninite (UO{sub 2}) phase. Uranium removal efficiency as high as 90% was achieved in the chemostat.
NASA Astrophysics Data System (ADS)
Zhang, Liqiang; Li, Luoxing
2013-08-01
The present work focuses on the determination of interfacial heat transfer coefficients (IHTCs) between the casting and metal chill during casting solidification. The proposed method is established based on the least-squares technique and sequential function specification method and can be applied to calculate heat fluxes and IHTCs for other alloys. The accuracy and stability of the method has been investigated by using a typical profile of heat fluxes simulating the practical conditions of casting solidification. In the test process, the effects of various calculation parameters in the inverse algorithm are also analyzed. Moreover, numerically calculated and experimental results are compared by applying the determined IHTCs into the forward heat conduction model with the same boundary conditions. The results show that the numerically calculated temperatures are in good agreement with those measured experimentally. This confirms that the proposed method is a feasible and effective tool for determination of the casting-mold IHTCs.
Determination of the gravitational coefficient of the Earth from near-Earth satellites
Ries, J.C.; Eanes, R.J.; Huang, C.; Schutz, B.E.; Shum, C.K.; Tapley. B.D.; Watkins, M.M.; Yuan, D.N. )
1989-04-01
Laser range, doppler and altimeter data collected from 14 near-Earth satellites have been combined to determine the value of the geocentric gravitational coefficient (GM) of the Earth. A long-arc solution using 3 years of laser range data to Lageos was used in a separate determination in which the effects of general relativity were investigated. The value of GM (including the mass of the atmosphere) was determined to be 398,600.4405 km{sup 3}/sec{sup 2} when all corrections for general relativity are taken into account. The uncertainty (1-{sigma}) in the value of GM is estimated to be 0.001 km{sup 3}/sec{sup 2}.
SDSS-II: Determination of shape and color parameter coefficients for SALT-II fit model
Dojcsak, L.; Marriner, J.; /Fermilab
2010-08-01
In this study we look at the SALT-II model of Type IA supernova analysis, which determines the distance moduli based on the known absolute standard candle magnitude of the Type IA supernovae. We take a look at the determination of the shape and color parameter coefficients, {alpha} and {beta} respectively, in the SALT-II model with the intrinsic error that is determined from the data. Using the SNANA software package provided for the analysis of Type IA supernovae, we use a standard Monte Carlo simulation to generate data with known parameters to use as a tool for analyzing the trends in the model based on certain assumptions about the intrinsic error. In order to find the best standard candle model, we try to minimize the residuals on the Hubble diagram by calculating the correct shape and color parameter coefficients. We can estimate the magnitude of the intrinsic errors required to obtain results with {chi}{sup 2}/degree of freedom = 1. We can use the simulation to estimate the amount of color smearing as indicated by the data for our model. We find that the color smearing model works as a general estimate of the color smearing, and that we are able to use the RMS distribution in the variables as one method of estimating the correct intrinsic errors needed by the data to obtain the correct results for {alpha} and {beta}. We then apply the resultant intrinsic error matrix to the real data and show our results.
Solid-phase microextraction to determine micropollutant-macromolecule partition coefficients.
Bridle, Helen L; Heringa, Minne B; Schäfer, Andrea I
2016-08-01
Aqueous micropollutants such as estradiol can have a large environmental impact-even at low concentrations. Part of understanding this impact involves determining the extent to which the micropollutants interact with macromolecules in water. In environmental samples, relevant macromolecules to which micropollutants bind are referred to as dissolved organic matter, and the most common examples of these in freshwater and coastal seawater are fulvic and humic acids. In living organisms, the most common macromolecules that affect bioavailability of a drug (or toxin) are proteins such as albumin. Using [2, 4, 6, 7 - (3)H]estradiol as an example compound, this protocol uses solid-phase microextraction and scintillation detection as analytical tools to quantify the amount of radiolabeled micropollutant available in solution. The measured free concentration after exposure to various concentrations of macromolecule (dissolved organic matter or protein) or micropollutant is used to determine the partition coefficient in the case of micropollutant-macromolecule interactions. The calibration and preparatory studies take at least 8 d, and the steps to determine the partition coefficient can be completed within 3 d. The protocol could be modified such that nonlabeled compounds are studied; instead of detection of activity by a liquid scintillation counter (LSC), the compounds can be quantified using gas chromatography-mass spectrometry (GC-MS) or liquid chromatography (LC)-MS(/MS). PMID:27362336
Kuss, Joachim; Holzmann, Jörg; Ludwig, Ralf
2009-05-01
Mercury is a priority pollutant as its mobility between the hydrosphere and the atmosphere threatens the biosphere globally. The air-water gas transfer of elemental mercury (Hg0) is controlled by its diffusion through the water-side boundary layer and thus by its diffusion coefficient, D(Hg), the value of which, however, has not been established. Here, the diffusion of Hg0 in water was modeled by molecular dynamics (MD) simulation and the diffusion coefficient subsequently determined. Therefore the movement of either Hg(0) or xenon and 1000 model water molecules (TIP4P-Ew) were traced for time spans of 50 ns. The modeled D(Xe) of the monatomic noble gas agreed well with measured data; thus, MD simulation was assumed to be a reliable approach to determine D(Hg) for monatomic Hg(0) as well. Accordingly, Hg(0) diffusion was then simulated for freshwater and seawater, and the data were well-described by the equation of Eyring. The activation energies for the diffusion of Hg0 in freshwater was 17.0 kJ mol(-1) and in seawater 17.8 kJ mol(-1). The newly determined D(Hg) is clearly lower than the one previously used for an oceanic mercury budget. Thus, its incorporation into the model should lead to lower estimates of global ocean mercury emissions. PMID:19534132
A new method for flight test determination of propulsive efficiency and drag coefficient
NASA Technical Reports Server (NTRS)
Bull, G.; Bridges, P. D.
1983-01-01
A flight test method is described from which propulsive efficiency as well as parasite and induced drag coefficients can be directly determined using relatively simple instrumentation and analysis techniques. The method uses information contained in the transient response in airspeed for a small power change in level flight in addition to the usual measurement of power required for level flight. Measurements of pitch angle and longitudinal and normal acceleration are eliminated. The theoretical basis for the method, the analytical techniques used, and the results of application of the method to flight test data are presented.
NASA Technical Reports Server (NTRS)
Elbanna, Hesham M.; Carlson, Leland A.
1992-01-01
The quasi-analytical approach is applied to the three-dimensional full potential equation to compute wing aerodynamic sensitivity coefficients in the transonic regime. Symbolic manipulation is used to reduce the effort associated with obtaining the sensitivity equations, and the large sensitivity system is solved using 'state of the art' routines. Results are compared to those obtained by the direct finite difference approach and both methods are evaluated to determine their computational accuracy and efficiency. The quasi-analytical approach is shown to be accurate and efficient for large aerodynamic systems.
Determining electro-optic coefficients for lithium tantalate using an electro-optic scanning device
Casson, J. L.; Gahagan, K. T.; Robinson, J. M.; Scrymgeour, D. A.; Jain, R.
2001-01-01
We demonstrate a ferroelectric optical device based on single crystal LiTaO{sub 3} that can scan a laser beam from the visible to the infrared. It utilizes the electro-optic effect in the ferroelectric that has potentially high intrinsic response times of GHz. There are many applications to such scanning devices in the infrared such as optical switching, spectrometry, microscopy, and sensing. Lithium tantalate has two ferroelectric polarization states that are antiparallel (180{sup o}) to each other. The domain states can be reversed by applying an electric field of {approx}21 kV/mm at room temperature. By reversing the domain structure in the crystal, we can create domains in the crystal of almost any desired shape. By creating prism-shaped domain, we can create a ferroelectric deflector or scanner by applying either static or sweeping voltages across the crystal. This scanner is capable of scanning wavelengths from 0.4-5 {micro}m. The scanning performance varied from a total deflection angle of 13.38{sup o} at 1558 nm to 16.18{sup o} at 632.8 nm. Since the amount of deflection of the incoming light is determined by the applied voltage, the electro-optic coefficient and other fixed quantities, by measuring the deflection angle as a function of wavelength, the dispersion of the electro-optic coefficient in lithium tantalate can be determined. In these experiments, the scanner was characterized from the visible (632.8 nm) to midinfrared (1558 nm). Both extraordinary and the ordinary polarizations of light were used, in order to determine the electro-optic coefficients, r{sup 33} and r{sup 31}. Except for the values at 632.8 nm, these values of the electro-optic coefficients have not been previously reported. For lithium tantalate, r{sup 33} at 632.8 nm is reported in the literature as 30.2 pm/V. We found that this decreases to 27.1 pm/V at 1558 nm. For the extraordinary polarization, r{sup 13} varied from 7.55 pm/V (632.8 nm) to 6.84 pm/V (1558 nm).
A new in-situ method to determine the apparent gas diffusion coefficient of soils
NASA Astrophysics Data System (ADS)
Laemmel, Thomas; Paulus, Sinikka; Schack-Kirchner, Helmer; Maier, Martin
2015-04-01
Soil aeration is an important factor for the biological activity in the soil and soil respiration. Generally, gas exchange between soil and atmosphere is assumed to be governed by diffusion and Fick's Law is used to describe the fluxes in the soil. The "apparent soil gas diffusion coefficient" represents the proportional factor between the flux and the gas concentration gradient in the soil and reflects the ability of the soil to "transport passively" gases through the soil. One common way to determine this coefficient is to take core samples in the field and determine it in the lab. Unfortunately this method is destructive and needs laborious field work and can only reflect a small fraction of the whole soil. As a consequence insecurity about the resulting effective diffusivity on the profile scale must remain. We developed a new in-situ method using new gas sampling device, tracer gas and inverse soil gas modelling. The gas sampling device contains several sampling depths and can be easily installed into vertical holes of an auger, which allows for fast installation of the system. At the lower end of the device inert tracer gas is injected continuously. The tracer gas diffuses into the surrounding soil. The resulting distribution of the tracer gas concentrations is used to deduce the diffusivity profile of the soil. For Finite Element Modeling of the gas sampling device/soil system the program COMSOL is used. We will present the results of a field campaign comparing the new in-situ method with lab measurements on soil cores. The new sampling pole has several interesting advantages: it can be used in-situ and over a long time; so it allows following modifications of diffusion coefficients in interaction with rain but also vegetation cycle and wind.
NASA Technical Reports Server (NTRS)
Nelson, Clayton C.; Nguyen, Dung T.
1987-01-01
The rotordynamic coefficients of an incompressible-flow annular pressure seal were determined using a bulk-flow model in conjunction with two different friction factor relationships. The first, Hirs' equation, assumes the friction factor is a function of Reynolds number only. The second, Moody's equation, approximates Moody's diagram and assumes the friction factor is a function of both Reynolds number and relative roughness. For each value of relative roughness, Hirs' constants were determined so that both equations gave the same magnitude and slope of the friction factor. For smooth seals, both relationships give the same results. For rough seals (e/2 H sub 0 = 0.05) Moody's equation predicts 44% greater direct stiffness, 35% greater cross-coupled stiffness, 19% smaller cross-coupled damping, 59% smaller cross-coupled inertia, and nominally the same direct damping and direct inertia.
Rate Coefficient Determinations for H + NO2 → OH + NO from High Pressure Flow Reactor Measurements.
Haas, Francis M; Dryer, Frederick L
2015-07-16
Rate coefficients for the reaction H + NO2 → OH + NO (R1) have been determined over the nominal temperature and pressure ranges of 737-882 K and 10-20 atm, respectively, from measurements in two different flow reactor facilities: one laminar and one turbulent. Considering the existing database of experimental k1 measurements, the present conditions add measurements of k1 at previously unconsidered temperatures between ∼820-880 K, as well as at pressures that exceed existing measurements by over an order of magnitude. Experimental measurements of NOx-perturbed H2 oxidation have been interpreted by a quasi-steady state NOx plateau (QSSP) method. At the QSSP conditions considered here, overall reactivity is sensitive only to the rates of R1 and H + O2 + M → HO2 + M (R2.M). Consequently, the ratio of k1 to k2.M may be extracted as a simple algebraic function of measured NO2, O2, and total gas concentrations with only minimal complication (within measurement uncertainty) due to treatment of overall gas composition M that differs slightly from pure bath gas B. Absolute values of k1 have been determined with reference to the relatively well-known, pressure-dependent rate coefficients of R2.B for B = Ar and N2. Rate coefficients for the title reaction determined from present experimental interpretation of both laminar and turbulent flow reactor results appear to be in very good agreement around a representative value of 1.05 × 10(14) cm(3) mol(-1) s(-1) (1.74 × 10(-10) cm(3) molecule(-1) s(-1)). Further, the results of this study agree both with existing low pressure flash photolysis k1 determinations of Ko and Fontijn (J. Phys. Chem. 95 3984) near 760 K as well as a present fit to the theoretical expression of Su et al. (J. Phys. Chem. A 106 8261). These results indicate that, over the temperature range considered in this study and up to at least 20 atm, net chemistry due to stabilization of the H-NO2 reaction intermediate to form isomers of HNO2 may proceed at
NASA Astrophysics Data System (ADS)
Szyszkiewicz-Warzecha, Krzysztof; Jasielec, Jerzy J.; Fausek, Janusz; Filipek, Robert
2016-06-01
Transport properties of ions have significant impact on the possibility of rebars corrosion thus the knowledge of a diffusion coefficient is important for reinforced concrete durability. Numerous tests for the determination of diffusion coefficients have been proposed but analysis of some of these tests show that they are too simplistic or even not valid. Hence, more rigorous models to calculate the coefficients should be employed. Here we propose the Nernst-Planck and Poisson equations, which take into account the concentration and electric potential field. Based on this model a special inverse method is presented for determination of a chloride diffusion coefficient. It requires the measurement of concentration profiles or flux on the boundary and solution of the NPP model to define the goal function. Finding the global minimum is equivalent to the determination of diffusion coefficients. Typical examples of the application of the presented method are given.
NASA Astrophysics Data System (ADS)
Odziomek, K.; Gajewicz, A.; Haranczyk, M.; Puzyn, T.
2013-07-01
Air-water partition coefficient (KAW) is one of the key parameters determining environmental behavior of Persistent Organic Pollutants (POPs). Experimentally measured values of KAW are still unavailable for majority of POPs, thus alternative methods of supplying data, including Quantitative Structure-Property Relationships (QSPR) modeling, are often in use. In this paper, applicability of two QSPR methods of predicting KAW were compared with each other in the context of further application of the predicted data in environmental transport and fate studies. According to the first (indirect) method, KAW is calculated from previously predicted values of octanol-water (KOW) and octanol-air (KOA) partition coefficients. In the second (direct) approach, KAW is calculated, based on the estimated value of Henry's law constant (KH) and then adjusted to ensure its consistency with the other two partition coefficients (KOW and KOA). Although the indirect method carries theoretically twice as much error as the direct method, when the predicted values of KAW are then utilized as an input to the environmental fate model The OECD POV and LRTP Screening Tool, ver. 2.2, the indirect method elicits much higher and therefore much more restrictive values of overall persistence (POV) and transfer efficiency (TE) than its equivalent (direct method). High uncertainties related to the application of the direct method result mainly from the necessary adjustment procedure.
Sadler, M.; Charlson, R.J.; Rosen, H.; Novakov, T.
1980-07-01
The absorption coefficients determined by the integrating plate method and the laser transmission method are found to be comparable and highly correlated. Furthermore, a high correlation is found between these absorption coefficients and the carbon content of the aerosol in urbanized regions.
Determination of the coefficient of thermal expansion with embedded long-gauge fiber optic sensors
NASA Astrophysics Data System (ADS)
Feng, Xin; Sun, Changsen; Zhang, Xiaotan; Ansari, Farhad
2010-06-01
A novel methodology for the determination of the coefficient of thermal expansion (CTE) is proposed by using long-gauge fiber optic sensors. Current approaches either neglect the shear-lag effects or do not compensate for the thermo-optic effects in optical fibers leading to precision errors. The embedded long-gauge sensor measures not only the thermo-optic effect due to temperature fluctuations, but also the strain-optic effect created by thermal stresses. However, it is difficult to directly separate these two effects in the measurements. Given that only the strain-optic effect correlates to the CTE of a host material, it is necessary to compensate for the thermo-optic effect. An additional error is attributed to the fact that the shear-lag effect is ignored, i.e. assumption is made that the strain distribution in the optical fiber is the same as that in the host material. This study reports on the development of a methodology for the computation of the coefficient of thermal expansion in structural materials using long-gauge fiber optic sensors. The proposed formulations account for both the shear-lag and thermo-optic effects.
NASA Astrophysics Data System (ADS)
Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel
2016-04-01
Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (klN) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show klN for benzene varied from 0.022 to 0.60 d- 1. Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties.
Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel
2016-04-01
Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (kl(N)) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show kl(N) for benzene varied from 0.022 to 0.60d(-1). Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties. PMID:26855386
Grant, Sharon; Schacht, Veronika J; Escher, Beate I; Hawker, Darryl W; Gaus, Caroline
2016-03-15
Freely dissolved aqueous concentration and chemical activity are important determinants of contaminant transport, fate, and toxic potential. Both parameters are commonly quantified using Solid Phase Micro-Extraction (SPME) based on a sorptive polymer such as polydimethylsiloxane (PDMS). This method requires the PDMS-water partition constants, KPDMSw, or activity coefficient to be known. For superhydrophobic contaminants (log KOW >6), application of existing methods to measure these parameters is challenging, and independent measures to validate KPDMSw values would be beneficial. We developed a simple, rapid method to directly measure PDMS solubilities of solid contaminants, SPDMS(S), which together with literature thermodynamic properties was then used to estimate KPDMSw and activity coefficients in PDMS. PDMS solubility for the test compounds (log KOW 7.2-8.3) ranged over 3 orders of magnitude (4.1-5700 μM), and was dependent on compound class. For polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins (PCDDs), solubility-derived KPDMSw increased linearly with hydrophobicity, consistent with trends previously reported for less chlorinated congeners. In contrast, subcooled liquid PDMS solubilities, SPDMS(L), were approximately constant within a compound class. SPDMS(S) and KPDMSw can therefore be predicted for a compound class with reasonable robustness based solely on the class-specific SPDMS(L) and a particular congener's entropy of fusion, melting point, and aqueous solubility. PMID:26881312
Use of the quartz crystal microbalance to determine the monomeric friction coefficient of polyimides
NASA Technical Reports Server (NTRS)
Bechtold, Mary M.
1995-01-01
obtained when using this oscillating circuit are highly variable. This circuit requires further modification to stabilize frequency readings before its use in studies to determine the diffusion coefficient of penetrant molecules into a polymer film coated on a QCM.
Determination of polyoxymethylene (POM)--water partition coefficients for oxy-PAHs and PAHs.
Josefsson, Sarah; Arp, Hans Peter H; Kleja, Dan Berggren; Enell, Anja; Lundstedt, Staffan
2015-01-01
Oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) are a class of ubiquitously occurring pollutants of which little is known. They can be co-emitted with PAHs or formed from PAHs in the environment. The environmental fate and risk of oxy-PAHs are difficult to assess due to a lack of methods to quantify their pore water concentrations. One sampler that can be used to determine freely dissolved concentrations of organic contaminants is polyoxymethylene (POM). In this study, POM - water partition coefficients (KPOM) were determined for 11 oxy-PAHs. KPOM values of 8 PAHs with similar hydrophobicities as the oxy-PAHs were determined for comparison. Results showed that logKPOM values ranged from 2.64 to 4.82 for the PAHs (2-4 rings), similar to previously determined values. LogKPOM values for investigated oxy-PAHs ranged from 0.96 to 5.36. The addition of carbonylic oxygen on a parent PAH generally lowered KPOM by 0.5 to 1.0 log units, which is attributable to the presence of carbonylic oxygens increasing water solubility. The KPOM values presented here will facilitate simultaneous assessments of freely dissolved water concentrations of oxy-PAHs and PAHs in environmental media. PMID:25460771
NASA Astrophysics Data System (ADS)
Han, I.; Demir, L.; Şahin, M.
2009-09-01
The total mass attenuation coefficients ( μ m) for SiO 2 {Quartz (1 1 0 1), Quartz (1 1 0 0) and Quartz (0 0 0 1)}, KAlSi 3O 8 {Orthoclase (0 1 0), Orthoclase (1 0 0)}, CaSO 4·2H 2O (gypsum), FeS 2 (pyrite) and Mg 2Si 2O 6 (pyroxene) natural minerals were measured at 22.1, 25.0, 59.5 and 88.0 keV photon energies. The γ- and X-rays were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. Atomic and electronic cross sections ( σ t and σ e), the effective atomic and electron numbers or electron densities ( Z eff and N eff) were determined using the obtained μ m values for investigated samples.
NASA Astrophysics Data System (ADS)
Çevik, Ugˇur; Baltaş, Hasan; Çelik, Ahmet; Bacaksız, Emin
2006-06-01
The X-rays attenuation coefficients for Cu, In and Se in elemental state and the semiconductor CuInSe2 were measured at 15 different energies from 11.9 to 37.3 keV by using the secondary excitation method. Monochromatic photons were obtained using the following secondary targets: Br, Sr, Mo, Cd, Te and Ba. 59.5 keV gamma rays emitted from an annular 241Am radioactive source were used to excite secondary target and X-rays emitted from secondary target were counted by a Si(Li) detector with a resolution of 0.16 keV at 5.9 keV. A method to determine the thickness of thin film with XRF is described. Additionally, the effect of absorption edges on effective atomic numbers and their variation with photon energy in composite semiconductor sample was discussed. Obtained values were compared with calculated values.
Determination of partition coefficient of spin probe between different lipid membrane phases.
Arsov, Zoran; Strancar, Janez
2005-01-01
Model lipid membranes made from binary mixtures of dimyristoylphosphatidylcholine/dipalmitoylphosphatidylcholine (DMPC/DPPC) and dimyristoylphosphatidylcholine/cholesterol (DMPC/Chol) exhibit coexistence of diverse lipid phases at appropriate temperature and composition. Since lipids in different phases show different structural and motional properties, it is expected that the corresponding spin probe electron paramagnetic resonance (EPR) spectra will be superposition of several spectral components. From comparison of proportions of spectral components of the EPR spectrum with the fractions of the corresponding lipid phases obtained from known phase diagrams the partition coefficient of spin probe methyl ester of 5-doxyl palmitate between different lipid phases was determined. The results indicate that the used spin probe partitions approximately equally between different phases. PMID:16309270
Worth, H; Nüsse, W; Piiper, J
1978-01-01
In order to provide data required for quantitative analysis of gas diffusion in lung airways, diffusion of He, CO, O2, CO2 and SF6 in various gases used in respiratory physiology was studied in vitro at 37 degrees C and 25 degrees C. The gases were allowed to mix by diffusion in a closed cylindrical tube (length 2 m, internal diameter 1 cm), one half of which was initially filled with 1% test gas in a second gas and the other half of which was filled with the second gas only. Kinetics of diffusional equilibration was determined by withdrawal of spot samples analyzed by gas chromatography. The binary (mutual) diffusion coefficients (D) computed there from were in most cases in good agreement with values calculated on the basis of the Chapman-Enskog theory. PMID:625611
Experimental determination and prediction of the gas-liquid n-hexadecane partition coefficients.
Mutelet, F; Rogalski, M
2001-07-20
Experimental methods based on gas-phase chromatography were tested with a view to determine the gas-liquid n-hexadecane partition coefficients, log L16 of non-volatile compounds at 298.2 K. It was demonstrated that reliable values of log L16 of compounds more volatile than n-docosane can be obtained using either capillary, or packed columns. The main limitation of both methods is the column stability at high temperatures. Here we propose a new method based on the temperature gradient mode, to obtain log L16 of high-boiling compounds. A group contribution model is also presented in view to predicting log L16 values of non-volatile compounds. PMID:11510537
Determination of collisional quenching rate coefficient of N2(A^3σu^+ )
NASA Astrophysics Data System (ADS)
Koizumi, Yuusuke; Suzuki, Susumu; Itoh, Haruo
2012-10-01
We have previously determined the collisional quenching rate coefficient of N2(A^3σu^+ ) by an air pollutant gas [1-4]. In this paper we report the collisional quenching rate coefficient k' of N2(A^3σu^+ ) by p-xylene (C8H10), which was determined to be (6.5±0.9)x10-9 cm^3/s. In addition, through repeated experiments it was found that by-products of p-xylene were deposited on the cathode, similarly to the cases of m-xylene and o-xylene previously reported [4], and then the current-voltage curves consistently shifed to a higher-E/p0 region. To clarify the reason for this behavior, we confirmed by Auger electron spectroscopy (AES) and Fourier transform infrared spectroscopy (FTIR) that these changes in the current-voltage curves were caused by the deposition of a thin film of by-product of decomposed xylene on the cathode surface. According to the results of AES, C atoms were detected in a sample exposed to an electrical discharge, and we confirmed that the deposit of C was thickest in the case of electrical discharge in p-xylene. According to the results of FTIR, it was found that CH2 and CH were obtained from the deposition of p-xylene. [4pt] [1] S. Suzuki, H. Itoh, H. Sekizawa and N. Ikuta, J. Phys. Soc. Jpn., 62, No.8, 2692-2697 (1993)[0pt] [2] S. Suzuki, H. Itoh, H. Sekizawa and N. Ikuta, Jpn. J. Appl. Phys., 36, 4744-4746 (1997)[0pt] [3] S. Suzuki, T. Suzuki and H. Itoh, Cont. of HAKONE X Saga, Japan, 132-135 (2006)[0pt] [4] S. Suzuki, H. Itoh, Proc. of 30th ICPIG (Belfast, UK), A1-12 (2011)
Gonzaga, Carla Castiglia; Cesar, Paulo Francisco; Miranda, Walter Gomes; Yoshimura, Humberto Naoyuki
2011-11-01
This study compared three methods for the determination of the slow crack growth susceptibility coefficient (n) of two veneering ceramics (VM7 and d.Sign), two glass-ceramics (Empress and Empress 2) and a glass-infiltrated alumina composite (In-Ceram Alumina). Discs (n = 10) were prepared according to manufacturers' recommendations and polished. The constant stress-rate test was performed at five constant stress rates to calculate n(d) . For the indentation fracture test to determine n(IF) , Vickers indentations were performed and the crack lengths were measured under an optical microscope. For the constant stress test (performed only for d.Sign for the determination of n(s) ) four constant stresses were applied and held constant until the specimens' fracture and the time to failure was recorded. All tests were performed in artificial saliva at 37°C. The n(d) values were 17.2 for Empress 2, followed by d.Sign (20.5), VM7 (26.5), Empress (30.2), and In-Ceram Alumina (31.1). In-Ceram Alumina and Empress 2 showed the highest n(IF) values, 66.0 and 40.2, respectively. The n(IF) values determined for Empress (25.2), d.Sign (25.6), and VM7 (20.1) were similar. The n(s) value determined for d.Sign was 31.4. It can be concluded that the n values determined for the dental ceramics evaluated were significantly influenced by the test method used. PMID:21714087
ERIC Educational Resources Information Center
Quinino, Roberto C.; Reis, Edna A.; Bessegato, Lupercio F.
2013-01-01
This article proposes the use of the coefficient of determination as a statistic for hypothesis testing in multiple linear regression based on distributions acquired by beta sampling. (Contains 3 figures.)
NASA Astrophysics Data System (ADS)
Dzyubenko, B. V.
1981-05-01
The dependence of the structure coefficient of a stream flowing in a bundle of helically curved tubes of oval profile on the determining parameters is established, along with the features of this system.
Pace, M.N.; Rosentreter, J.J.; Bartholomay, R.C.
2001-01-01
Idaho State University and the US Geological Survey, in cooperation with the US Department of Energy, conducted a study to determine and evaluate strontium distribution coefficients (Kds) of subsurface materials at the Idaho National Engineering and Environmental Laboratory (INEEL). The Kds were determined to aid in assessing the variability of strontium Kds and their effects on chemical transport of strontium-90 in the Snake River Plain aquifer system. Data from batch experiments done to determine strontium Kds of five sediment-infill samples and six standard reference material samples were analyzed by using multiple linear regression analysis and the stepwise variable-selection method in the statistical program, Statistical Product and Service Solutions, to derive an equation of variables that can be used to predict strontium Kds of sediment-infill samples. The sediment-infill samples were from basalt vesicles and fractures from a selected core at the INEEL; strontium Kds ranged from ???201 to 356 ml g-1. The standard material samples consisted of clay minerals and calcite. The statistical analyses of the batch-experiment results showed that the amount of strontium in the initial solution, the amount of manganese oxide in the sample material, and the amount of potassium in the initial solution are the most important variables in predicting strontium Kds of sediment-infill samples.
NASA Technical Reports Server (NTRS)
Weiser, P.; Nordmann, R.
1991-01-01
In today's rotordynamic calculations, the input parameters for a finite element analysis (FEA) determine very much the reliability of eigenvalue and eigenmode predictions. While modeling of an elastic structure by means of beam elements etc. is relatively straightforward to perform and the input data for journal bearings are usually known exactly enough, the determination of stiffness and damping for labyrinth seals is still the subject of many investigations. Therefore, the rotordynamic influence of labyrinths is often not included in FEA for rotating machinery because of a lack of computer programs to calculate these parameters. This circumstance can give rise to severe vibration problems especially for high performance turbines or compressors, resulting in remarkable economic losses. The forces generated in labyrinths can be described for small motions around the seal center with a linearized force-motion relationship. Several years ago, we started with the development of computer codes for the determination of rotordynamic seal coefficients. Our different approaches to evaluate the dynamic fluid forces generated by turbulent, compressible seal flow are introduced.
Experimentally Determined Overall Heat Transfer Coefficients for Spacesuit Liquid Cooled Garments
NASA Technical Reports Server (NTRS)
Bue, Grant; Rhodes, Richard; Anchondo, Ian; Westheimer, David; Campbell, Colin; Vogel, Matt; Vonaue, Walt; Conger, Bruce; Stein, James
2015-01-01
A Human-In-The-Loop (HITL) Portable Life Support System 2.0 (PLSS 2.0) test has been conducted at NASA Johnson Space Center in the PLSS Development Laboratory from October 27, 2014 to December 19, 2014. These closed-loop tests of the PLSS 2.0 system integrated with human subjects in the Mark III Suit at 3.7 psi to 4.3 psi above ambient pressure performing treadmill exercise at various metabolic rates from standing rest to 3000 BTU/hr (880 W). The bulk of the PLSS 2.0 was at ambient pressure but effluent water vapor from the Spacesuit Water Membrane Evaporator (SWME) and the Auxiliary Membrane Evaporator (Mini-ME), and effluent carbon dioxide from the Rapid Cycle Amine (RCA) were ported to vacuum to test performance of these components in flight-like conditions. One of the objectives of this test was to determine the overall heat transfer coefficient (UA) of the Liquid Cooling Garment (LCG). The UA, an important factor for modeling the heat rejection of an LCG, was determined in a variety of conditions by varying inlet water temperature, flow rate, and metabolic rate. Three LCG configurations were tested: the Extravehicular Mobility Unit (EMU) LCG, the Oceaneering Space Systems (OSS) LCG, and the OSS auxiliary LCG. Other factors influencing accurate UA determination, such as overall heat balance, LCG fit, and the skin temperature measurement, will also be discussed.
Mandal, A.B.; Nair, B.U. )
1991-10-31
Critical micelle concentrations (cmc) of cetyltrimethylammonium bromide (CTAB) and cetylpyridinium chloride (CPC) surfactants in aqueous solution have been determined by using the cyclic voltammetric technique. (Co(en){sub 3})(ClO{sub 4}){sub 3} has been used as the redox-active electrochemical probe. The cmc values so obtained for the surfactants were found to be in good agreement with the literature values. The partition coefficient, K, of the electrochemical probe between water and surfactants in nonmicellar and micellar states was estimated using the peak current, i{sub p} and half-wave potential, E{sub 1/2} values. The self-diffusion coefficient, D{sub m}, interaction parameter, k{sub f}, and hydrodynamic radius of the micelles were also estimated. The results suggest that the probe is sensitive to the nature of surfactant as well as surfactant concentration.
NASA Astrophysics Data System (ADS)
Ko, H.; Scheeres, D.
2014-09-01
Representing spacecraft orbit anomalies between two separate states is a challenging but an important problem in achieving space situational awareness for an active spacecraft. Incorporation of such a capability could play an essential role in analyzing satellite behaviors as well as trajectory estimation of the space object. A general way to deal with the anomaly problem is to add an estimated perturbing acceleration such as dynamic model compensation (DMC) into an orbit determination process based on pre- and post-anomaly tracking data. It is a time-consuming numerical process to find valid coefficients to compensate for unknown dynamics for the anomaly. Even if the orbit determination filter with DMC can crudely estimate an unknown acceleration, this approach does not consider any fundamental element of the unknown dynamics for a given anomaly. In this paper, a new way of representing a spacecraft anomaly using an interpolation technique with the Thrust-Fourier-Coefficients (TFCs) is introduced and several anomaly cases are studied using this interpolation method. It provides a very efficient way of reconstructing the fundamental elements of the dynamics for a given spacecraft anomaly. Any maneuver performed by a satellite transitioning between two arbitrary orbital states can be represented as an equivalent maneuver using an interpolation technique with the TFCs. Given unconnected orbit states between two epochs due to a spacecraft anomaly, it is possible to obtain a unique control law using the TFCs that is able to generate the desired secular behavior for the given orbital changes. This interpolation technique can capture the fundamental elements of combined unmodeled anomaly events. The interpolated orbit trajectory, using the TFCs compensating for a given anomaly, can be used to improve the quality of orbit fits through the anomaly period and therefore help to obtain a good orbit determination solution after the anomaly. Orbit Determination Toolbox (ODTBX
Liang, Yuzhen; Kuo, Dave T F; Allen, Herbert E; Di Toro, Dominic M
2016-10-01
There is concern about the environmental fate and effects of munition constituents (MCs). Polyparameter linear free energy relationships (pp-LFERs) that employ Abraham solute parameters can aid in evaluating the risk of MCs to the environment. However, poor predictions using pp-LFERs and ABSOLV estimated Abraham solute parameters are found for some key physico-chemical properties. In this work, the Abraham solute parameters are determined using experimental partition coefficients in various solvent-water systems. The compounds investigated include hexahydro-1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX), hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine (MNX), hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX), hexahydro-1,3-dinitroso-5- nitro-1,3,5-triazine (DNX), 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitrobenzene (TNB), and 4-nitroanisole. The solvents in the solvent-water systems are hexane, dichloromethane, trichloromethane, octanol, and toluene. The only available reported solvent-water partition coefficients are for octanol-water for some of the investigated compounds and they are in good agreement with the experimental measurements from this study. Solvent-water partition coefficients fitted using experimentally derived solute parameters from this study have significantly smaller root mean square errors (RMSE = 0.38) than predictions using ABSOLV estimated solute parameters (RMSE = 3.56) for the investigated compounds. Additionally, the predictions for various physico-chemical properties using the experimentally derived solute parameters agree with available literature reported values with prediction errors within 0.79 log units except for water solubility of RDX and HMX with errors of 1.48 and 2.16 log units respectively. However, predictions using ABSOLV estimated solute parameters have larger prediction errors of up to 7.68 log units. This large discrepancy is probably due to the missing R2NNO2
Hoche, S; Hussein, M A; Becker, T
2015-03-01
The accuracy of density, reflection coefficient, and acoustic impedance determination via multiple reflection method was validated experimentally. The ternary system water-maltose-ethanol was used to execute a systematic, temperature dependent study over a wide range of densities and viscosities aiming an application as inline sensor in beverage industries. The validation results of the presented method and setup show root mean square errors of: 1.201E-3 g cm(-3) (±0.12%) density, 0.515E-3 (0.15%) reflection coefficient and 1.851E+3 kg s(-1) m(-2) (0.12%) specific acoustic impedance. The results of the diffraction corrected absorption showed an average standard deviation of only 0.12%. It was found that the absorption change shows a good correlation to concentration variations and may be useful for laboratory analysis of sufficiently pure liquids. The main part of the observed errors can be explained by the observed noise, temperature variation and the low signal resolution of 50 MHz. In particular, the poor signal-to-noise ratio of the second reflector echo was found to be a main accuracy limitation. Concerning the investigation of liquids the unstable properties of the reference material PMMA, due to hygroscopicity, were identified to be an additional, unpredictable source of uncertainty. While dimensional changes can be considered by adequate methodology, the impact of the time and temperature dependent water absorption on relevant reference properties like the buffer's sound velocity and density could not be considered and may explain part of the observed deviations. PMID:25465962
Determination of absorption coefficient based on laser beam thermal blooming in gas-filled tube.
Hafizi, B; Peñano, J; Fischer, R; DiComo, G; Ting, A
2014-08-01
Thermal blooming of a laser beam propagating in a gas-filled tube is investigated both analytically and experimentally. A self-consistent formulation taking into account heating of the gas and the resultant laser beam spreading (including diffraction) is presented. The heat equation is used to determine the temperature variation while the paraxial wave equation is solved in the eikonal approximation to determine the temporal and spatial variation of the Gaussian laser spot radius, Gouy phase (longitudinal phase delay), and wavefront curvature. The analysis is benchmarked against a thermal blooming experiment in the literature using a CO₂ laser beam propagating in a tube filled with air and propane. New experimental results are presented in which a CW fiber laser (1 μm) propagates in a tube filled with nitrogen and water vapor. By matching laboratory and theoretical results, the absorption coefficient of water vapor is found to agree with calculations using MODTRAN (the MODerate-resolution atmospheric TRANsmission molecular absorption database) and HITRAN (the HIgh-resolution atmospheric TRANsmission molecular absorption database). PMID:25090334
Pomiès, M; Choubert, J M; Wisniewski, C; Miège, C; Budzinski, H; Coquery, M
2015-03-01
The nitrifying/denitrifying activated sludge process removes several micropollutants from wastewater by sorption onto sludge and/or biodegradation. The objective of this paper is to propose and evaluate a lab-scale experimental strategy for the determination of partition coefficient and biodegradation constant for micropollutant with an objective of modelling their removal. Four pharmaceutical compounds (ibuprofen, atenolol, diclofenac and fluoxetine) covering a wide hydrophobicity range (log Kow from 0.16 to 4.51) were chosen. Dissolved and particulate concentrations were monitored for 4 days, inside two reactors working under aerobic and anoxic conditions, and under different substrate feed conditions (biodegradable carbon and nitrogen). We determined the mechanisms responsible for the removal of the target compounds: (i) ibuprofen was biodegraded, mainly under aerobic conditions by cometabolism with biodegradable carbon, whereas anoxic conditions suppressed biodegradation; (ii) atenolol was biodegraded under both aerobic and anoxic conditions (with a higher biodegradation rate under aerobic conditions), and cometabolism with biodegradable carbon was the main mechanism; (iii) diclofenac and fluoxetine were removed by sorption only. Finally, the abilities of our strategy were evaluated by testing the suitability of the parameters for simulating effluent concentrations and removal efficiency at a full-scale plant. PMID:25300180
NASA Astrophysics Data System (ADS)
Vacca, Santiago; Martorano, Marcelo A.; Heringer, Romulo; Boccalini, Mário
2015-05-01
The heat transfer coefficient at the metal-mold interface ( h MM) has been determined for the first time during the centrifugal casting of a Fe-C alloy tube using the inverse solution method. To apply this method, a centrifugal casting experiment was carried out to measure cooling curves within the tube wall under a mold rotation speed of 900 rpm, imposing a centrifugal force 106 times as large as the gravity force (106 G). As part of the solution method, a comprehensive heat transfer model of the centrifugal casting was also developed and coupled to an optimization algorithm. Finally, the evolution of h MM with time that gives the minimum squared error between measured and calculated cooling curves was obtained. The determined h MM is approximately 870 W m-2 K-1 immediately after melt pouring, decreasing to about 50 W m-2 K-1 when the average temperature of the tube is ~973 K (700 °C), after the end of solidification. Despite the existence of a centrifugal force that could enhance the metal-mold contact, these values are lower than those generally reported for static molds with or without an insulating coating at the mold inner surface. The implemented model shows that the heat loss by radiation is dominant over that by convection at the tube inner surface, causing the formation of a solidification front that meets another front coming from the outer surface of the tube.
NASA Astrophysics Data System (ADS)
Clark, Christopher J. R.; Schofield, Simon P.; Gomez, Haley L.; Davies, Jonathan I.
2016-06-01
We use the published photometry and spectroscopy of 22 galaxies in the Herschel Reference Survey to determine that the value of the dust mass absorption coefficient κd at a wavelength of 500 μm is kappa _{500} = 0.051^{+0.070}_{-0.026} m^{2 kg^{-1}}. We do so by taking advantage of the fact that the dust-to-metals ratio in the interstellar medium of galaxies appears to be constant. We argue that our value for κd supersedes that of James et al. - who pioneered this approach for determining κd - because we take advantage of superior data, and account for a number of significant systematic effects that they did not consider. We comprehensively incorporate all methodological and observational contributions to establish the uncertainty on our value, which represents a marked improvement on the oft-quoted `order-of-magnitude' uncertainty on κd. We find no evidence that the value of κd differs significantly between galaxies, or that it correlates with any other measured or derived galaxy properties. We note, however, that the availability of data limits our sample to relatively massive (109.7 < M⋆ < 1011.0 M⊙), high metallicity (8.61 < [ 12 + log_{10} fracOH ] < 8.86) galaxies; future work will allow us to investigate a wider range of systems.
Determination of Rashba and Dresslhaus coefficient in InGaAs quantum wells
NASA Astrophysics Data System (ADS)
Faniel, Sébastien; Matsuura, Toru; Mineshige, Shunsuke; Sekine, Yoshiaki; Koga, Takaaki
2012-02-01
We report the determination of the intrinsic spin-orbit interaction (SOI) parameters for In0.53Ga0.47As/In0.52Al0.48As quantum wells (QWs) from the analysis of the weak antilocalization effect measured at dilution temperature [1]. We found that the Dresselhaus SOI is mostly negligible relative to the Rashba SOI in this system. The intrinsic parameter for the Rashba effect, aSO≡α/
NASA Astrophysics Data System (ADS)
Kuznetsov, S. A.; Hayashi, H.; Minato, K.; Gaune-Escard, M.
2005-09-01
The main step in the pyrometallurgical process of spent nuclear fuel recycling is a molten salt electrorefining. The knowledge of separation coefficients of actinides (U, Np, Pu and Am) and rare-earth metals (Y, La, Ce, Nd and Gd) is very important for this step. Usually the separation coefficients are evaluated from the formal standard potentials of metals in melts containing their own ions, values obtained by potentiometric method. Electrochemical experiments were carried out at 723-823 K in order to estimate separation coefficients in LiCl-KCl eutectic melt containing uranium and lanthanum trichlorides. It was shown that for the calculation of uranium and lanthanum separation coefficients it is necessary to determine the voltammetric peak potentials of U(III) and La(III), their concentration in the melt and the kinetic parameters relating to U(III) discharge such as transfer and diffusion coefficients, and standard rate constants of charge transfer.
NASA Astrophysics Data System (ADS)
Tang, Hongwu; Tian, Zhijun; Yan, Jing; Yuan, Saiyu
2014-07-01
Vegetation is a key aspect of water resources and ecology in natural rivers, floodplains and irrigation channels. The hydraulic resistance of the water flow is greatly changed when submerged vegetation is present. Three kinds of drag coefficients, i.e., the drag coefficient for an isolated cylinder, the bulk drag coefficient of an array of cylinders and the vertically distributed or local drag coefficient, have been commonly used as parameters to represent the vegetation drag force. In this paper, a comprehensive experimental study of submerged stems in an open channel flow is presented. Empirical formulae for the three drag coefficients were obtained based on our experimental results and on data from previous studies. A two-layer model was developed to solve the mean momentum equation, which was used to evaluate the vertical mean velocity profile with each of the drag coefficients. By comparing the velocity distribution model predictions and the measurement results, we found that the model with the drag coefficient for an isolated cylinder and the local drag coefficient was good fit. In addition, the model with the bulk drag coefficient gave much larger velocity values than measurements, but it could be improved by adding the bed friction effect and making choice of the depth-averaged velocity within the canopy layer.
NASA Astrophysics Data System (ADS)
Ochoa-Martínez, Efraín; Gabás, Mercedes; Barrutia, Laura; Pesquera, Amaia; Centeno, Alba; Palanco, Santiago; Zurutuza, Amaia; Algora, Carlos
2015-01-01
The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical properties of the stacked structure is noticeable both in the visible and the ultraviolet spectral regions, thus masking the graphene optical response. Finally, the use of heat treatment under a nitrogen atmosphere of the graphene-based stacked structures, as a method to reduce the water content of the sample, and its effect on the optical response of both graphene and the residual debris layer are presented. The Lorentz-Drude model proposed for the optical response of graphene fits fairly well the experimental ellipsometric data for all the analysed graphene-based stacked structures.The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical
Determination of phosphorus source coefficients for organic phosphorus sources: laboratory studies.
Leytem, A B; Sims, J T; Coale, F J
2004-01-01
Phosphorus losses in runoff from application of manures and biosolids to agricultural land are implicated in the degradation of water quality in the Chesapeake and Delaware Inland Bays. We conducted an incubation study to determine the relative P solubility and bioavailability, referred to as P source coefficients (PSCs), for organic P sources, which are typically land-applied in the Mid-Atlantic USA. Nine organic and one inorganic (KH2PO4) P amendments were applied to an Evesboro loamy sand (mesic, coated Typic Quartzipsamments) at a rate of 60 mg P kg(-1) and incubated for 8 wk with subsamples analyzed at 2 and 8 wk. There was an increase in Mehlich-3 P (M3-P), water-soluble P (WS-P), iron-oxide strip extractable P (FeO-P), and Mehlich-3 P saturation ratio (M3-PSR) with P additions, which varied by P source. The trend of relative extractable WS-P, FeO-P, and M3-P generally followed the pattern: inorganic P > liquid and deep pit manures > manures and biosolids treated with metal salts or composted. We found significant differences in the availability of P from varying organic P sources. The use of PSCs may be beneficial when determining the risk of P losses from land application of manures and other organic P sources and could be used in risk assessments such as a P site index. These PSCs may also be useful for determining P application rates when organic P sources are applied to P deficient soils for use as a fertilizer source. PMID:14964394
Tillis, G.M.; Swain, E.D.
1998-01-01
Discharges through 10 selected coastal control structures in Broward and Palm Beach Counties, Florida, are presently computed using the theoretical discharge-coefficient ratings developed from scale modeling, theoretical discharge coefficients, and some field calibrations whose accuracies for specific sites are unknown. To achieve more accurate discharge-coefficient ratings for the coastal control structures, field discharge measurements were taken with an Acoustic Doppler Current Profiler at the coastal control structures under a variety of flow conditions. These measurements were used to determine computed discharge-coefficient ratings for the coastal control structures under different flow regimes: submerged orifice flow, submerged weir flow, free orifice flow, and free weir flow. Theoretical and computed discharge-coefficient ratings for submerged orifice and weir flows were determined at seven coastal control structures, and discharge ratings for free orifice and weir flows were determined at three coastal control structures. The difference between the theoretical and computed discharge-coefficient ratings varied from structure to structure. The theoretical and computed dischargecoefficient ratings for submerged orifice flow were within 10 percent at four of seven coastal control structures; however, differences greater than 20 percent were found at two of the seven structures. The theoretical and computed discharge-coefficient ratings for submerged weir flow were within 10 percent at three of seven coastal control structures; however, differences greater than 20 percent were found at four of the seven coastal control structures. The difference between theoretical and computed discharge-coefficient ratings for free orifice and free weir flows ranged from 5 to 32 percent. Some differences between the theoretical and computed discharge-coefficient ratings could be better defined with more data collected over a greater distribution of measuring conditions.
Determination of discount functions in rats with an adjusting-amount procedure.
Richards, J B; Mitchell, S H; de Wit, H; Seiden, L S
1997-01-01
An adjusting-amount procedure was used to measure discounting of reinforcer value by delay. Eight rats chose between a varying amount of immediate water and a fixed amount of water given after a delay. The amount of immediate water was systematically adjusted as a function of the rats' previous choices. This procedure was used to determine the indifference point at which each rat chose the immediate amount and the delayed amount with equal frequency. The amount of immediate water at this indifference point was used to estimate the value of the delayed amount of water. In Experiment 1, the effects of daily changes in the delay to the fixed reinforcer (100 microliters of water delivered after 0, 2, 4, 8, or 16 s) were tested. Under these conditions, the rats reached indifference points within the first 30 trials of each 60-trial session. In Experiment 2, the effects of water deprivation level on discounting of value by delay were assessed. Altering water deprivation level affected the speed of responding but did not affect delay discounting. In Experiment 3, the effects of varying the magnitude of the delayed water (100, 150, and 200 microliters) were tested. There was some tendency for the discounting function to be steeper for larger than for smaller reinforcers, although this difference did not reach statistical significance. In all three experiments, the obtained discount functions were well described by a hyperbolic function. These experiments demonstrate that the adjusting-amount procedure provides a useful tool for measuring the discounting of reinforcer value by delay. PMID:9163939
Determining the Drag Coefficient of Rotational Symmetric Objects Falling through Liquids
ERIC Educational Resources Information Center
Houari, Ahmed
2012-01-01
I will propose here a kinematic approach for measuring the drag coefficient of rotational symmetric objects falling through liquids. For this, I will show that one can obtain a measurement of the drag coefficient of a rotational symmetric object by numerically solving the equation of motion describing its fall through a known liquid contained in a…
Sterling, Sarah M.; Allgeyer, Edward S.; Fick, Jörg; Prudovsky, Igor; Mason, Michael D.; Neivandt, David J.
2013-01-01
Model cellular membranes enable the study of biological processes in a controlled environment and reduce the traditional challenges associated with live or fixed cell studies. However, model membrane systems based on the air/water or oil/solution interface do not allow for incorporation of transmembrane proteins, or for the study of protein transport mechanisms. Conversely, a phospholipid bilayer deposited via the Langmuir-Blodgett/Langmuir Schaefer method on a hydrogel layer is potentially an effective mimic of the cross-section of a biological membrane, and facilitates both protein incorporation and transport studies. Prior to application, however, such membranes must be fully characterized, particularly with respect to the phospholipid bilayer phase transition temperature. Here we present a detailed characterization of the phase transition temperature of the inner and outer leaflets of a chitosan supported model membrane system. Specifically, the lateral diffusion coefficient of each individual leaflet has been determined as a function of temperature. Measurements were performed utilizing z-scan fluorescence correlation spectroscopy (FCS), a technique that yields calibration-free diffusion information. Analysis via the method of Wawrezinieck and coworkers, revealed that phospholipid diffusion changes from raft-like to free diffusion as the temperature is increased; an insight into the dynamic behavior of hydrogel supported membranes not previously reported. PMID:23705855
High-throughput microplate assay for the determination of drug partition coefficients.
Magalhães, Luís M; Nunes, Cláudia; Lúcio, Marlene; Segundo, Marcela A; Reis, Salette; Lima, José L F C
2010-11-01
Partition coefficients (K(p)) of drugs between the phospholipid bilayer and the aqueous phase provide useful information in quantitative structure-activity relationship studies. Hexadecylphosphocholine (HePC) micelles, composed of a zwitterionic hydrophilic surface and a hydrophobic core, mimic the biomembranes and have several advantages over other lipid structures to assess K(p) values. Their preparation is easy, fast and avoids the use of toxic organic solvents, and the output has fewer spectroscopic interferences. Here, we describe a high-throughput microplate protocol for assessing the K(p) of drugs using HePC micelles as membrane models and derivative spectrophotometry as the detection technique. Moreover, the time-consuming data treatment to assess K(p) values is easily performed by a dedicated Excel routine developed here and described in detail. The K(p) values of nonsteroidal anti-inflammatory drugs (acemetacin, clonixin, diclofenac and indomethacin) were determined to show the simplicity of the method and to validate this protocol, which provides K(p) values (n = 3) of two drugs in ∼ 2 h. PMID:21030957
Satomura, Hironori; Adachi, Kohei
2013-07-01
To facilitate the interpretation of canonical correlation analysis (CCA) solutions, procedures have been proposed in which CCA solutions are orthogonally rotated to a simple structure. In this paper, we consider oblique rotation for CCA to provide solutions that are much easier to interpret, though only orthogonal rotation is allowed in the existing formulations of CCA. Our task is thus to reformulate CCA so that its solutions have the freedom of oblique rotation. Such a task can be achieved using Yanai's (Jpn. J. Behaviormetrics 1:46-54, 1974; J. Jpn. Stat. Soc. 11:43-53, 1981) generalized coefficient of determination for the objective function to be maximized in CCA. The resulting solutions are proved to include the existing orthogonal ones as special cases and to be rotated obliquely without affecting the objective function value, where ten Berge's (Psychometrika 48:519-523, 1983) theorems on suborthonormal matrices are used. A real data example demonstrates that the proposed oblique rotation can provide simple, easily interpreted CCA solutions. PMID:25106398
Orbit determination across unknown maneuvers using the essential Thrust-Fourier-Coefficients
NASA Astrophysics Data System (ADS)
Ko, Hyun Chul; Scheeres, Daniel J.
2016-01-01
Any maneuver performed by a satellite transitioning between two arbitrary orbital states can be represented as an equivalent maneuver involving Thrust-Fourier-Coefficients (TFCs). With a selected TFC set as a basis, a thrust acceleration can be constructed to interpolate two unconnected states across an unknown maneuver. This representation technique with TFCs enables us to facilitate the analytical propagation of uncertainties of the satellite state. This approach allows for the usage of existing pre-maneuver orbit estimation to compute the orbit solution after the unknown maneuver. In this paper, we applied this approach to orbit determination (OD) problems across unknown maneuvers by appending different combinations of TFCs to the state vector in the batch filter. The aim is to investigate how different maneuver representations with different TFC sets affect the OD solution across unknown maneuvers. Simulation results show that each TFC set provides different representations of the unknown perturbing acceleration, which yields varying magnitudes of delta velocity for a given maneuver. However, OD solutions across unknown maneuvers using different TFC sets display equivalent performance over the post-maneuver arc as long as those TFC sets are capable of generating the apparent secular motion caused by a given unknown maneuver.
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Determination of the reaction rate coefficient of sulphide mine tailings deposited under water.
Awoh, Akué Sylvette; Mbonimpa, Mamert; Bussière, Bruno
2013-10-15
The efficiency of a water cover to limit dissolved oxygen (DO) availability to underlying acid-generating mine tailings can be assessed by calculating the DO flux at the tailings-water interface. Fick's equations, which are generally used to calculate this flux, require knowing the effective DO diffusion coefficient (Dw) and the reaction (consumption) rate coefficient (Kr) of the tailings, or the DO concentration profile. Whereas Dw can be accurately estimated, few studies have measured the parameter Kr for submerged sulphide tailings. The objective of this study was to determine Kr for underwater sulphide tailings in a laboratory experiment. Samples of sulphide mine tailings (an approximately 6 cm layer) were placed in a cell under a water cover (approximately 2 cm) maintained at constant DO concentration. Two tailings were studied: TA1 with high sulphide content (83% pyrite) and TA2 with low sulphide content (2.8% pyrite). DO concentration was measured with a microelectrode at various depths above and below the tailings-water interface at 1 mm intervals. Results indicate that steady-state condition was rapidly attained. As expected, a diffusive boundary layer (DBL) was observed in all cases. An iterative back-calculation process using the numerical code POLLUTEv6 and taking the DBL into account provided the Kr values used to match calculated and experimental concentration profiles. Kr obtained for tailings TA1 and TA2 was about 80 d(-1) and 6.5 d(-1), respectively. For comparison purposes, Kr obtained from cell tests on tailings TA1 was lower than Kr calculated from the sulphate production rate obtained from shake-flask tests. Steady-state DO flux at the water-tailings interface was then calculated with POLLUTEv6 using tailings characteristics Dw and Kr. For the tested conditions, DO flux ranged from 608 to 758 mg O2/m(2)/d for tailings TA1 and from 177 to 221 mg O2/m(2)/d for tailings TA2. The impact of placing a protective layer of inert material over
Impurity Diffusion Coefficients of Al and Zn in Mg Determined from Solid-to-Solid Diffusion Couples
Kammerer, Catherine; Kulkarni, Nagraj S; Warmack, Robert J Bruce; Perry, Kelly A; Belova, Irina; Murch, Prof. Graeme; Sohn, Yong Ho
2013-08-01
Increasing use and development of lightweight Mgalloys have led to the desire for more fundamental research in and understanding of Mg-based systems. As property enhancing components, Al and Zn are two of the most important and common alloying elements for Mg-alloys. We have investigated the concentration dependent interdiffusion of Al and Zn in Mg using diffusion couples of pure polycrystalline Mg mated to Mg solid solutions containing either <9 at.% Al or <3 at.% Zn. Concentration profiles were determined by electron micro-probe microanalysis of the diffusion zone. The interdiffusion coefficients were determined by the classical Boltzmann-Matano method within the Mg solid solution. As the concentration of Al or Zn approaches the dilute ends, we employ an analytical approach based on the Hall method to estimate the impurity diffusion coefficients. Results of Al and Zn impurity diffusion in Mg are reported and compared to published impurity diffusion coefficients typically determined by thin film techniques.
Takeda, M.; Hiratsuka, T.; Ito, K.; Finsterle, S.
2011-02-01
Diffusion anisotropy is a critical property in predicting migration of substances in sedimentary formations with very low permeability. The diffusion anisotropy of sedimentary rocks has been evaluated mainly from laboratory diffusion experiments, in which the directional diffusivities are separately estimated by through-diffusion experiments using different rock samples, or concurrently by in-diffusion experiments in which only the tracer profile in a rock block is measured. To estimate the diffusion anisotropy from a single rock sample, this study proposes an axisymmetric diffusion test, in which tracer diffuses between a cylindrical rock sample and a surrounding solution reservoir. The tracer diffusion between the sample and reservoir can be monitored from the reservoir tracer concentrations, and the tracer profile could also be obtained after dismantling the sample. Semi-analytical solutions are derived for tracer concentrations in both the reservoir and sample, accounting for an anisotropic diffusion tensor of rank two as well as the dilution effects from sampling and replacement of reservoir solution. The transient and steady-state analyses were examined experimentally and numerically for different experimental configurations, but without the need for tracer profiling. These experimental configurations are tested for in- and out-diffusion experiments using Koetoi and Wakkanai mudstones and Shirahama sandstone, and are scrutinized by a numerical approach to identify favorable conditions for parameter estimation. The analysis reveals the difficulty in estimating diffusion anisotropy; test configurations are proposed for enhanced identifiability of diffusion anisotropy. Moreover, it is demonstrated that the axisymmetric diffusion test is efficient in obtaining the sorption parameter from both steady-state and transient data, and in determining the effective diffusion coefficient if isotropic diffusion is assumed. Moreover, measuring reservoir concentrations in an
Takeda, M; Hiratsuka, T; Ito, K; Finsterle, S
2011-04-25
Diffusion anisotropy is a critical property in predicting migration of substances in sedimentary formations with very low permeability. The diffusion anisotropy of sedimentary rocks has been evaluated mainly from laboratory diffusion experiments, in which the directional diffusivities are separately estimated by through-diffusion experiments using different rock samples, or concurrently by in-diffusion experiments in which only the tracer profile in a rock block is measured. To estimate the diffusion anisotropy from a single rock sample, this study proposes an axisymmetric diffusion test, in which tracer diffuses between a cylindrical rock sample and a surrounding solution reservoir. The tracer diffusion between the sample and reservoir can be monitored from the reservoir tracer concentrations, and the tracer profile could also be obtained after dismantling the sample. Semi-analytical solutions are derived for tracer concentrations in both the reservoir and sample, accounting for an anisotropic diffusion tensor of rank two as well as the dilution effects from sampling and replacement of reservoir solution. The transient and steady-state analyses were examined experimentally and numerically for different experimental configurations, but without the need for tracer profiling. These experimental configurations are tested for in- and out-diffusion experiments using Koetoi and Wakkanai mudstones and Shirahama sandstone, and are scrutinized by a numerical approach to identify favorable conditions for parameter estimation. The analysis reveals the difficulty in estimating diffusion anisotropy; test configurations are proposed for enhanced identifiability of diffusion anisotropy. Moreover, it is demonstrated that the axisymmetric diffusion test is efficient in obtaining the sorption parameter from both steady-state and transient data, and in determining the effective diffusion coefficient if isotropic diffusion is assumed. Moreover, measuring reservoir concentrations in an
Park, Seongjun; Rittmann, Bruce E; Bae, Wookeun
2010-04-01
A differential elimination method (DEM) is developed to determine the kinetic coefficients for substrate self-inhibition. Finite differentiation of the equation eliminates either K(I) or K(S), which enables the equation to be linearized so that q, K(S), and K(I) can be estimated without using nonlinear least square regression (NLSR). The DEM options that eliminate K(I) or K(S) computed the parameter values exactly when the data did not contain any errors. If one-point or random errors were not too large, both DEM options worked as well as NLSR when data were acquired with geometric intervals for substrate concentration. The DEM was more accurate for fitting the data for the smallest and largest values of S, but relatively weaker in estimating the observed maximum substrate utilization rate, q(max). The estimates for S(max), the concentration at which the maximum specific substrate utilization rate is observed, were relatively invariant among the methods, even when K(S) and K(I) differed. When the intervals were arithmetic (i.e., equal intervals of substrate concentration) and the data contained errors, the DEM and NLSR estimated the parameters poorly, indicating that collecting data with an arithmetic interval greatly increases the risk of poor parameter estimation. Parameter estimates by DEM fit very well experimental data from nitrification or photosynthesis, which were taken with geometric intervals of substrate concentration or light intensity, but fit poorly phenol-degradation data, which were obtained with arithmetic substrate intervals. Besides providing a reasonable substitute for NLSR, the DEM also can be used as a tool to diagnose the quality of experimental data by comparing its estimates between the DEM options, or, more rigorously, to those from NLSR. PMID:19768559
NASA Technical Reports Server (NTRS)
Donegan, James J; Pearson, Henry A
1952-01-01
A matrix method is presented for determining the longitudinal-stability coefficients and frequency response of an aircraft from arbitrary maneuvers. The method is devised so that it can be applied to time-history measurements of combinations of such simple quantities as angle of attack, pitching velocity, load factor, elevator angle, and hinge moment to obtain the over-all coefficients. Although the method has been devised primarily for the evaluation of stability coefficients which are of primary interest in most aircraft loads and stability studies, it can be used also, with a simple additional computation, to determine the frequency-response characteristics. The entire procedure can be applied or extended to other problems which can be expressed by linear differential equations.
Zhang, Xiaomin; Xie, Xiangdong; Qu, Decheng; Ning, Jing; Zhou, Hongmei; Pan, Jie; Yang, Guoshan
2016-01-01
A set of fluence-to-dose conversion coefficients has been calculated for neutrons with energies <20 MeV using a developed voxel mouse model and Monte Carlo N-particle code (MCNP), for the purpose of neutron radiation effect evaluation. The calculation used 37 monodirectional monoenergetic neutron beams in the energy range 10−9 MeV to 20 MeV, under five different source irradiation configurations: left lateral, right lateral, dorsal–ventral, ventral–dorsal, and isotropic. Neutron fluence-to-dose conversion coefficients for selected organs of the body were presented in the paper, and the effect of irradiation geometry conditions, neutron energy and the organ location on the organ dose was discussed. The results indicated that neutron dose conversion coefficients clearly show sensitivity to irradiation geometry at neutron energy below 1 MeV. PMID:26661852
Zhang, Xiaomin; Xie, Xiangdong; Qu, Decheng; Ning, Jing; Zhou, Hongmei; Pan, Jie; Yang, Guoshan
2016-03-01
A set of fluence-to-dose conversion coefficients has been calculated for neutrons with energies <20 MeV using a developed voxel mouse model and Monte Carlo N-particle code (MCNP), for the purpose of neutron radiation effect evaluation. The calculation used 37 monodirectional monoenergetic neutron beams in the energy range 10(-9) MeV to 20 MeV, under five different source irradiation configurations: left lateral, right lateral, dorsal-ventral, ventral-dorsal, and isotropic. Neutron fluence-to-dose conversion coefficients for selected organs of the body were presented in the paper, and the effect of irradiation geometry conditions, neutron energy and the organ location on the organ dose was discussed. The results indicated that neutron dose conversion coefficients clearly show sensitivity to irradiation geometry at neutron energy below 1 MeV. PMID:26661852
A reverberation room round robin on the determination of absorption coefficients
NASA Astrophysics Data System (ADS)
Kath, U.
In ten reverberation rooms with very different volumes and different room shapes, the absorption coefficients for mineral fiber mat were measured. The particular feature of this round robin was that the absorption material was much thicker than in other similar experiments and that it was measured not only with an area of 12 sq m on the floor, but also as a complete surface covering of a small wall in order to avoid the edge effect. The decay curves were evaluated in at least two institutions and the absorption coefficients were calculated using the Eyring equation. The absorption coefficients were quite dispersed from one room to another and also from one-third octave band to the adjacent ones. Errors due to change are small, thus one is dealing with systematic errors.
Determination of the zincate diffusion coefficient and its application to alkaline battery problems
NASA Technical Reports Server (NTRS)
May, C. E.; Kautz, Harold E.
1978-01-01
The diffusion coefficient for the zincate ion at 24 C was found to be 9.9 X 10 to the minus 7th power squared cm per sec + or - 30 percent in 45 percent potassium hydroxide and 1.4 x 10 to the minus 7 squared cm per sec + or - 25 percent in 40 percent sodium hydroxide. Comparison of these values with literature values at different potassium hydroxide concentrations show that the Stokes-Einstein equation is obeyed. The diffusion coefficient is characteristic of the zincate ion (not the cation) and independent of its concentration. Calculations with the measured value of the diffusion coefficient show that the zinc concentration in an alkaline zincate half cell becomes uniform throughout in tens of hours by diffusion alone. Diffusion equations are derived which are applicable to finite size chambers. Details and discussion of the experimental method are also given.
Determination of the zincate diffusion coefficient and its application to alkaline battery problems
NASA Technical Reports Server (NTRS)
May, C. E.; Kautz, H. E.
1978-01-01
The diffusion coefficient for the zincate ion at 24 C was found to be 9.9 x 10 to the -7th power sq cm/sec + or - 30% in 45% potassium hydroxide and 1.4 x 10 to the -7th power sq cm/sec + or - 25% in 40% sodium hydroxide. Comparison of these values with literature values at different potassium hydroxide concentrations show that the Stokes-Einstein equation is obeyed. The diffusion coefficient is characteristic of the zincate ion (not the cation) and independent of its concentration. Calculations with the measured value of the diffusion coefficient show that the zinc concentration in an alkaline zincate half-cell becomes uniform throughout in tens of hours by diffusion alone. Diffusion equations are derived which are applicable to finite-size chambers. Details and discussion of the experimental method are also given.
NASA Astrophysics Data System (ADS)
Kallman, Joshua Benjamin
Recycled particle flux can be a significant contributor to tokamak edge plasma density, and lead to reductions in edge temperature. Previous measurements have shown that solid evaporated lithium coatings can lead to lowered edge recycling, corresponding decreases in edge plasma density, and a radial broadening of the electron temperature profile. During the 2010 run campaign, The National Spherical Torus Experiment operated with both solid and liquid lithium coatings on its plasma-facing components. A section of graphite outer divertor tiles was replaced with a substrate designed to hold liquid lithium coatings. While the lithium coatings on the graphite remain solid, the plates can be heated to render the lithium into a liquid state. In preparation for this campaign, a 99-tip dense Langmuir probe array was installed in the outboard divertor to measure scrape-off layer density and temperature. The probe array was located so as to radially span these two different divertor surfaces and measure their respective effects on the temperature and density. A dual-band fast IR camera was also installed to provide surface temperature and heat flux measurements. The use of two-color IR thermography allows for an assessment of effects due to the uncertain, phase- and purity-dependent emissivity of the lithium coatings. The present study compares the derived heat fluxes from these diagnostics to determine an effective classical sheath heat transmission coefficient gamma, a measure of the heat flow reaching the device surfaces as a function of plasma parameters, namely the edge temperature and density - quantities which should be modified by lithium coatings. The sheath heat transmission is of great interest to future devices, which can expect to see large steady-state and transient heat fluxes to material surfaces. The value of gamma was measured to be 2.49 +/- 0.04, a factor of ˜3 smaller than the expected classical result of ˜7. The implications of this measurement and the
NASA Technical Reports Server (NTRS)
Blanchard, R. C.; Walberg, G. D.
1980-01-01
Results of an investigation to determine the full scale drag coefficient in the high speed, low density regime of the Viking lander capsule 1 entry vehicle are presented. The principal flight data used in the study were from onboard pressure, mass spectrometer, and accelerometer instrumentation. The hypersonic continuum flow drag coefficient was unambiguously obtained from pressure and accelerometer data; the free molecule flow drag coefficient was indirectly estimated from accelerometer and mass spectrometer data; the slip flow drag coefficient variation was obtained from an appropriate scaling of existing experimental sphere data. Comparison of the flight derived drag hypersonic continuum flow regime except for Reynolds numbers from 1000 to 100,000, for which an unaccountable difference between flight and ground test data of about 8% existed. The flight derived drag coefficients in the free molecule flow regime were considerably larger than those previously calculated with classical theory. The general character of the previously determined temperature profile was not changed appreciably by the results of this investigation; however, a slightly more symmetrical temperature variation at the highest altitudes was obtained.
NASA Technical Reports Server (NTRS)
Brown, W Byron; Esgar, Jack B
1950-01-01
Analytical methods are presented for the determination of local values of outside and inside heat-transfer coefficients and effective gas temperatures by use of turbine-blade-temperature measurements. The methods are derived for a number of configurations that can be applied to typical cooled-turbine-blade shapes as well as to other types of heat-transfer apparatus.
Determination of the thermal expansion and thermo-optic coefficients of a bacteriorhodopsin film
NASA Astrophysics Data System (ADS)
Wang Song, Q.; Zhang, Chunping; Ku, Chin-Yu; Huang, Ming-Chieh; Gross, Richard B.; Birge, Robert R.
1995-02-01
The linear expansion and thermo-optic coefficients of a bacteriorhodopsin film were measured by using an interferometric method. The experimental results confirm the previous suspicions that the large refractive nonlinearity which occurs at high illumination intensities arises form a thermal effect. The results also suggest a possible way to increase the usable thermal nonlinearity by four times.
De Mezquia, D Alonso; Bou-Ali, M Mounir; Larrañaga, M; Madariaga, J A; Santamaría, C
2012-03-01
In this work we have measured the molecular diffusion coefficient of the n-alkane binary series nC(i)-nC(6), nC(i)-nC(10), and nC(i)-nC(12) at 298 K and 1 atm and a mass fraction of 0.5 by using the so-called sliding symmetric tubes technique. The results show that the diffusion coefficient at this concentration is proportional to the inverse viscosity of the mixture. In addition, we have also measured the diffusion coefficient of the systems nC(12)-nC(6), nC(12)-nC(7), and nC(12)-nC(8) as a function of concentration. From the data obtained, it is shown that the diffusion coefficient of the n-alkane binary mixtures at any concentration can be calculated from the molecular weight of the components and the dynamic viscosity of the corresponding mixture at 50% mass fraction. PMID:22263833
Experiment to Determine the Absorption Coefficient of Gamma Rays as a Function of Energy.
ERIC Educational Resources Information Center
Ouseph, P. J.; And Others
1982-01-01
Simpler than x-ray diffractometer experiments, the experiment described illustrates certain concepts regarding the interaction of electromagnetic rays with matter such as the exponential decrease in the intensity with absorber thickness, variation of the coefficient of absorption with energy, and the effect of the K-absorption edge on the…
Yotsukura, Nobuhiro; Steadfast, D.A.; Jirka, G.H.
1984-01-01
A test was conducted in a meandering 9.6-km reach of the Chenango River, New York, to assess the feasibility of a two-dimensional steady-state propane-gas tracer method as a means of estimating in situ reaeration coefficients. It is concluded that the method, which combines an instantaneous release of dye tracer with a long duration release of propane gas tracer, is very feasible for determining gas-desorption coefficients and wind effects in a wide river. However, the method does not appear to be ready for immediate operational applications. (USGS)
Schenzel, Judith; Goss, Kai-Uwe; Schwarzenbach, René P; Bucheli, Thomas D; Droge, Steven T J
2012-06-01
Although natural toxins, such as mycotoxins or phytoestrogens are widely studied and were recently identified as micropollutants in the environment, many of their environmentally relevant physicochemical properties have not yet been determined. Here, the sorption affinity to Pahokee peat, a model sorbent for soil organic matter, was investigated for 29 mycotoxins and two phytoestrogens. Sorption coefficients (K(oc)) were determined with a dynamic HPLC-based column method using a fully aqueous mobile phase with 5 mM CaCl(2) at pH 4.5. Sorption coefficients varied from less than 10(0.7) L/kg(oc) (e.g., all type B trichothecenes) to 10(4.0) L/kg(oc) (positively charged ergot alkaloids). For the neutral compounds the experimental sorption data set was compared with predicted sorption coefficients using various models, based on molecular fragment approaches (EPISuite's KOCWIN or SPARC), poly parameter linear free energy relationship (pp-LFER) in combination with predicted descriptors, and quantum-chemical based software (COSMOtherm)). None of the available models was able to adequately predict absolute K(oc) numbers and relative differences in sorption affinity for the whole set of neutral toxins, largely because mycotoxins exhibit highly complex structures. Hence, at present, for such compounds fast and consistent experimental techniques for determining sorption coefficients, as the one used in this study, are required. PMID:22540838
Guo, Yugao; Ma, Shuo; Guan, Shan; Zhang, Yan; Pan, Jie
2015-09-01
A method of high-throughput determination, which is based on ultrasound-assisted liquid-phase microextraction, was developed to measure directly the partition coefficients of n-octanol-water. In ultrasound-assisted liquid-phase microextraction, ultrasonic energy can facilitate the mass transfer process of six or more microextractors simultaneously. Therefore, high-throughput determination of n-octanol-water partition coefficients can be performed favorably, and the equilibrium time of each microextractor can be decreased effectively. Several experimental parameters including ultrasonic power and frequency, centrifugation conditions, extractant volume and sample concentration were analyzed and optimized at 25°C. Under the optimum conditions, it only takes 2 min to reach extraction equilibrium, and the solutions of sample can be separated by centrifugation in 4 min. After centrifugation, the concentrations in n-octanol phases are analyzed with gas chromatography. The method was further evaluated with eight reference compounds and the findings demonstrated that this method is suitable to determine the partition coefficients of organic compounds accurately and quickly. Next, the method was exploited to measure the partition coefficients of n-octanol-water containing 20 organic compounds, which cover the [Formula: see text] values from 0.05 to 4.36, with comparatively low relative standard deviation (RSD) directly. The results of this study illustrated that the RSD (n = 6) was under 3%. PMID:25583971
NASA Astrophysics Data System (ADS)
Cao, Yongyou; Guo, Zhipeng; Xiong, Shoumei
2012-07-01
High-pressure die cast B390 alloy was prepared on a 350 ton cold chamber die casting machine. The metal/die interfacial heat transfer coefficient of the alloy was investigated. Considering the filling process, a "finger"-shaped casting was designed for the experiments. This casting consisted of five plates with different thicknesses (0.05 inch or 1.27 mm to 0.25 inch or 6.35 mm) as well as individual ingates and overflows. Experiments under various operation conditions were conducted, and temperatures were measured at various specific locations inside the die. Based on the results, the interfacial heat transfer coefficient and heat flux were determined by solving the inverse heat transfer problem. The influence of the mold-filling sequence, sensor locations, as well as processing parameters including the casting pressure, die temperature, and fast/slow shot speeds on the heat transfer coefficient were discussed.
NASA Technical Reports Server (NTRS)
Donegan, James J; Robinson, Samuel W , Jr; Gates, Ordway, B , jr
1955-01-01
A method is presented for determining the lateral-stability derivatives, transfer-function coefficients, and the modes for lateral motion from frequency-response data for a rigid aircraft. The method is based on the application of the vector technique to the equations of lateral motion, so that the three equations of lateral motion can be separated into six equations. The method of least squares is then applied to the data for each of these equations to yield the coefficients of the equations of lateral motion from which the lateral-stability derivatives and lateral transfer-function coefficients are computed. Two numerical examples are given to demonstrate the use of the method.
Yang, X; Wood, L T; Miller, J H
2001-11-01
We discuss a method for measuring electro-optic coefficients by measuring diffraction from a tunable grating. The method involves measuring the changes in the diffraction pattern of a reflection grating, where applied electric fields of alternating direction induce changes in the index of refraction through the electro-optic effect. For certain geometries, these applied fields cause period-doubling effects that produce new peaks in the diffraction pattern. Numerically calculated diffraction patterns are presented for the assumptions of both homogeneous and inhomogeneous fields. Peak splitting, as a function of both the number of slits illuminated and the induced change in the index of refraction, is observed and discussed. Finally, the usefulness of our method for the measurement of electro-optic coefficients is discussed. PMID:18364844
A Monte Carlo model for determination of binary diffusion coefficients in gases
NASA Astrophysics Data System (ADS)
Panarese, A.; Bruno, D.; Colonna, G.; Diomede, P.; Laricchiuta, A.; Longo, S.; Capitelli, M.
2011-06-01
A Monte Carlo method has been developed for the calculation of binary diffusion coefficients in gas mixtures. The method is based on the stochastic solution of the linear Boltzmann equation obtained for the transport of one component in a thermal bath of the second one. Anisotropic scattering is included by calculating the classical deflection angle in binary collisions under isotropic potential. Model results are compared to accurate solutions of the Chapman-Enskog equation in the first and higher orders. We have selected two different cases, H 2 in H 2 and O in O 2, assuming rigid spheres or using a model phenomenological potential. Diffusion coefficients, calculated in the proposed approach, are found in close agreement with Chapman-Enskog results in all the cases considered, the deviations being reduced using higher order approximations.
A Monte Carlo model for determination of binary diffusion coefficients in gases
Panarese, A.; Bruno, D.; Colonna, G.; Diomede, P.; Laricchiuta, A.; Longo, S.; Capitelli, M.
2011-06-20
A Monte Carlo method has been developed for the calculation of binary diffusion coefficients in gas mixtures. The method is based on the stochastic solution of the linear Boltzmann equation obtained for the transport of one component in a thermal bath of the second one. Anisotropic scattering is included by calculating the classical deflection angle in binary collisions under isotropic potential. Model results are compared to accurate solutions of the Chapman-Enskog equation in the first and higher orders. We have selected two different cases, H{sub 2} in H{sub 2} and O in O{sub 2}, assuming rigid spheres or using a model phenomenological potential. Diffusion coefficients, calculated in the proposed approach, are found in close agreement with Chapman-Enskog results in all the cases considered, the deviations being reduced using higher order approximations.
Grigorian, G. M.; Dyatko, N. A.; Kochetov, I. V.
2015-05-15
Radial profiles of the density of metastable atoms Ar({sup 3}P{sub 2}) in the positive column of a dc glow discharge in argon were measured. Gas-discharge glass tubes with clean inner surfaces and surfaces covered with a carbonitride or carbon film were utilized. The parameters of the discharge plasma under experimental conditions were calculated in the framework of a one-dimensional (along the tube radius) discharge model. The coefficient K of reflection of Ar({sup 3}P{sub 2}) atoms from the tube wall was estimated by comparing the measured and calculated density profiles. It is found that, for a clean tube wall, the coefficient of reflection is K = 0.4 ± 0.2, whereas for a wall covered with a carbonitride or carbon film, it is K < 0.2.
Determination of the Solute Diffusion Coefficient by the Droplet Migration Method
Shan Liu; Jing Teng; Jeongyun Choi
2007-07-01
Further analysis of droplet migration in a temperature gradient field indicates that different terms can be used to evaluate the solute diffusion coefficient in liquid (D{sub L}) and that there exists a characteristic curve that can describe the motion of all the droplets for a given composition and temperature gradient. Critical experiments are subsequently conducted in succinonitrile (SCN)-salol and SCN-camphor transparent alloys in order to observe dynamic migration processes of a number of droplets. The derived diffusion coefficients from different terms are the same within experimental error. For SCN-salol alloys, D{sub L} = (0.69 {+-} 0.05) x 10{sup -3} mm{sup 2}/s, and for SCN-camphor alloys, D{sub L} = (0.24 {+-} 0.02) x 10{sup -3} mm{sup 2}/s.
NASA Astrophysics Data System (ADS)
Kugler, T.; Rausch, M. H.; Fröba, A. P.
2015-11-01
The paper reports on binary diffusion coefficient data for the gaseous systems argon-neon, krypton-helium, ammonia-helium, nitrous oxide-nitrogen, and propane-helium measured using a Loschmidt cell combined with holographic interferometry between (293.15 and 353.15) K as well as between (1 and 10) bar. The investigations on the noble gas systems aimed to validate the measurement apparatus by comparing the binary diffusion coefficients measured as a function of temperature and pressure with theoretical data. In previous studies, it was already shown that the raw concentration-dependent data measured with the applied setup are affected by systematic effects if pure gases are used prior to the diffusion process. Hence, the concentration-dependent measurement data were processed to obtain averaged binary diffusion coefficients at a mean mole fraction of 0.5. The data for the molecular gas systems complete literature data on little investigated systems of technical interest and point out the capabilities of the applied measurement apparatus. Further experimental data are reported for the systems argon-helium, krypton-argon, krypton-neon, xenon-helium, xenon-krypton, nitrous oxide-carbon dioxide, and propane-carbon dioxide at 293.15 K, 2 bar, and a mean mole fraction of 0.5.
Annunziata, Onofrio; Vergara, Alessandro; Paduano, Luigi; Sartorio, Roberto; Miller, Donald G; Albright, John G
2009-10-01
We have experimentally investigated multicomponent diffusion in a protein-polymer-salt-water quaternary system. Specifically, we have measured the nine multicomponent diffusion coefficients, D(ij), for the lysozyme-poly(ethylene glycol)-NaCl-water system at pH 4.5 and 25 degrees C using precision Rayleigh interferometry. Lysozyme is a model protein for protein-crystallization and enzymology studies. We find that the protein diffusion coefficient, D(11), decreases as polymer concentration increases at a given salt concentration. This behavior can be quantitatively related to the corresponding increase in fluid viscosity only at low polymer concentration. However, at high polymer concentration (250 g/L), protein diffusion is enhanced compared to the corresponding viscosity prediction. We also find that a protein concentration gradient induces salt diffusion from high to low protein concentration. This effect increases in the presence of poly(ethylene glycol). Finally, we have evaluated systematic errors associated with measurements of protein diffusion coefficients by dynamic light scattering. This work overall helps characterize protein diffusion in crowded environments and may provide guidance for further theoretical developments in the field of protein crystallization and protein diffusion in such crowded systems, such as the cytoplasm of living cells. PMID:19746957
NASA Astrophysics Data System (ADS)
Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal; Bohndiek, Sarah E.
2015-07-01
MultiSpectral Optoacoustic Tomography (MSOT) is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound with the excellent contrast from optical imaging of tissue. Absorption and scattering of the near infrared excitation light modulates the spectral profile of light as it propagates deep into biological tissue, meaning the images obtained provide only qualitative insight into the distribution of tissue chromophores. The goal of this work is to accurately recover the spectral profile of excitation light by modelling light fluence in the data reconstruction, to enable quantitative imaging. We worked with a commercial small animal MSOT scanner and developed our light fluence correction for its' cylindrical geometry. Optoacoustic image reconstruction pinpoints the sources of acoustic waves detected by the transducers and returns the initial pressure amplitude at these points. This pressure is the product of the dimensionless Grüneisen parameter, the absorption coefficient and the light fluence. Under the condition of constant Grüneisen parameter and well modelled light fluence, there is a linear relationship between the initial pressure amplitude measured in the optoacoustic image and the absorption coefficient. We were able to reproduce this linear relationship in different physical regions of an agarose gel phantom containing targets of known optical absorption coefficient, demonstrating that our light fluence model was working. We also demonstrate promising results of light fluence correction effects on in vivo data.
Li, L; Kleinman, K; Gillman, M W
2014-12-01
We implemented six confounding adjustment methods: (1) covariate-adjusted regression, (2) propensity score (PS) regression, (3) PS stratification, (4) PS matching with two calipers, (5) inverse probability weighting and (6) doubly robust estimation to examine the associations between the body mass index (BMI) z-score at 3 years and two separate dichotomous exposure measures: exclusive breastfeeding v. formula only (n=437) and cesarean section v. vaginal delivery (n=1236). Data were drawn from a prospective pre-birth cohort study, Project Viva. The goal is to demonstrate the necessity and usefulness, and approaches for multiple confounding adjustment methods to analyze observational data. Unadjusted (univariate) and covariate-adjusted linear regression associations of breastfeeding with BMI z-score were -0.33 (95% CI -0.53, -0.13) and -0.24 (-0.46, -0.02), respectively. The other approaches resulted in smaller n (204-276) because of poor overlap of covariates, but CIs were of similar width except for inverse probability weighting (75% wider) and PS matching with a wider caliper (76% wider). Point estimates ranged widely, however, from -0.01 to -0.38. For cesarean section, because of better covariate overlap, the covariate-adjusted regression estimate (0.20) was remarkably robust to all adjustment methods, and the widths of the 95% CIs differed less than in the breastfeeding example. Choice of covariate adjustment method can matter. Lack of overlap in covariate structure between exposed and unexposed participants in observational studies can lead to erroneous covariate-adjusted estimates and confidence intervals. We recommend inspecting covariate overlap and using multiple confounding adjustment methods. Similar results bring reassurance. Contradictory results suggest issues with either the data or the analytic method. PMID:25171142
Kleinman, Ken; Gillman, Matthew W.
2014-01-01
We implemented 6 confounding adjustment methods: 1) covariate-adjusted regression, 2) propensity score (PS) regression, 3) PS stratification, 4) PS matching with two calipers, 5) inverse-probability-weighting, and 6) doubly-robust estimation to examine the associations between the BMI z-score at 3 years and two separate dichotomous exposure measures: exclusive breastfeeding versus formula only (N = 437) and cesarean section versus vaginal delivery (N = 1236). Data were drawn from a prospective pre-birth cohort study, Project Viva. The goal is to demonstrate the necessity and usefulness, and approaches for multiple confounding adjustment methods to analyze observational data. Unadjusted (univariate) and covariate-adjusted linear regression associations of breastfeeding with BMI z-score were −0.33 (95% CI −0.53, −0.13) and −0.24 (−0.46, −0.02), respectively. The other approaches resulted in smaller N (204 to 276) because of poor overlap of covariates, but CIs were of similar width except for inverse-probability-weighting (75% wider) and PS matching with a wider caliper (76% wider). Point estimates ranged widely, however, from −0.01 to −0.38. For cesarean section, because of better covariate overlap, the covariate-adjusted regression estimate (0.20) was remarkably robust to all adjustment methods, and the widths of the 95% CIs differed less than in the breastfeeding example. Choice of covariate adjustment method can matter. Lack of overlap in covariate structure between exposed and unexposed participants in observational studies can lead to erroneous covariate-adjusted estimates and confidence intervals. We recommend inspecting covariate overlap and using multiple confounding adjustment methods. Similar results bring reassurance. Contradictory results suggest issues with either the data or the analytic method. PMID:25171142
NASA Astrophysics Data System (ADS)
Thoo, K. K.; Chin, W. M.; Heikal, M. R.
2013-12-01
In this study, the air side heat transfer coefficient of an aluminium mini-channel heat exchanger was investigated for single-phase flow in the mini-channel, with water in the tubes and air on the outside. Research methods included hydraulic tests on a single mini-channel tube, Wilson Plot experiments and experiment validation. Results obtained from the hydraulic test showed that turbulent flow occurred in the tube at a Reynolds number of 830. Wilson Plot experiments were conducted to determine air side heat transfer coefficient of the heat exchanger. The tube side Reynolds number was maintained above 1000 to ensure turbulent flow and tube side heat transfer coefficient was calculated using Gnielinski equation for turbulent flow. The air side heat transfer coefficients obtained from the Wilson Plot experiments were in good agreement with known correlations. The outcome of this study is to use the air side heat transfer coefficient to calculate the performance of refrigerant condensers for different tube pass ratios and flow pass configurations.
NASA Astrophysics Data System (ADS)
Abdessalem, K. B.; Sahtout, W.; Flaud, P.; Gazah, H.; Fakhfakh, Z.
2007-11-01
Literature shows a lack of works based on non-invasive methods for computing the propagation coefficient γ, a complex number related to dynamic vascular properties. Its imaginary part is inversely related to the wave speed C through the relationship C=ω/Im(γ), while its real part a, called attenuation, represents loss of pulse energy per unit of length. In this work an expression is derived giving the propagation coefficient when assuming a pulsatile flow through a viscoelastic vessel. The effects of physical and geometrical parameters of the tube are then studied. In particular, the effects of increasing the reflection coefficient, on the determination of the propagation coefficient are investigated in a first step. In a second step, we simulate a variation of tube length under physiological conditions. The method developed here is based on the knowledge of instantaneous velocity and radius values at only two sites. It takes into account the presence of a reflection site of unknown reflection coefficient, localised in the distal end of the vessel. The values of wave speed and attenuation obtained with this method are in a good agreement with the theory. This method has the advantage to be usable for small portions of the arterial tree.
NASA Astrophysics Data System (ADS)
Esmaielpour, Hamidreza; Tang, Jinfeng; Whiteside, Vincent R.; Vijeyaragunathan, Sangeetha; Mishima, Tetsuya D.; Santos, Michael B.; Sellers, Ian R.
2015-03-01
We present an investigation of hot carriers in InAs/AlAsSb quantum wells as a practical candidate for a hot carrier solar cell absorber. The thermalization coefficient (Q) of the sample is investigated using continuous wave photoluminescence (PL). The Q is accurately determined through transfer matrix calculations of the absorption, analysis of the power density, penetration depth, diffusion, and recombination rates using a combination of simulation and empirical methods. A precise measurement of laser spot size is important in order to determine the absorbed power density. Simulations were performed based on our PL geometry in order to calculate the excitation spot size, which was compared with experiment by measurements using variable diameter pinholes to determine beam radius. Here, these techniques are described, in addition to, the temperature dependent hot carrier dynamics and phonon mediated thermalization coefficient for the InAs/AlAsSb quantum well structure.
2015-01-01
Drug release from liposomal formulations is governed by a complex interplay of kinetic (i.e., drug permeability) and thermodynamic factors (i.e., drug partitioning to the bilayer surface). Release studies under sink conditions that attempt to mimic physiological conditions are insufficient to decipher these separate contributions. The present study explores release studies performed under nonsink conditions coupled with appropriate mathematical models to describe both the release kinetics and the conditions in which equilibrium is established. Liposomal release profiles for a model anticancer agent, topotecan, under nonsink conditions provided values for both the first-order rate constant for drug release and the bilayer/water partition coefficient. These findings were validated by conducting release studies under sink conditions via dynamic dialysis at the same temperature and buffer pH. A nearly identical rate constant for drug release could be obtained from dynamic dialysis data when appropriate volume corrections were applied and a mechanism-based mathematical model was employed to account for lipid bilayer binding and dialysis membrane transport. The usefulness of the nonsink method combined with mathematical modeling was further explored by demonstrating the effects of topotecan dimerization and bilayer surface charge potential on the bilayer/water partition coefficient at varying suspension concentrations of lipid and drug. PMID:24628304
Spectroscopic method for determination of the absorption coefficient in brain tissue
NASA Astrophysics Data System (ADS)
Johansson, Johannes D.
2010-09-01
I use Monte Carlo simulations and phantom measurements to characterize a probe with adjacent optical fibres for diffuse reflectance spectroscopy during stereotactic surgery in the brain. Simulations and measurements have been fitted to a modified Beer-Lambert model for light transport in order to be able to quantify chromophore content based on clinically measured spectra in brain tissue. It was found that it is important to take the impact of the light absorption into account when calculating the apparent optical path length, lp, for the photons in order to get good estimates of the absorption coefficient, μa. The optical path length was found to be well fitted to the equation lp=a+b ln(Is)+c ln(μa)+d ln(Is)ln(μa), where Is is the reflected light intensity for scattering alone (i.e., zero absorption). Although coefficients a-d calculated in this study are specific to the probe used here, the general form of the equation should be applicable to similar probes.
A simple method for the determination of ionic diffusion coefficients in flooded soils
NASA Astrophysics Data System (ADS)
Gardner, P. J.; Flynn, N.; Maltby, E.
2001-02-01
Soil cores from river marginal wetlands from the Torridge and Severn catchments in the UK were collected to study rates of soil denitrification at different sites and at two stations (levee and backplain depression) at the river margin. Half the cores were sterilized prior to flooding to destroy the denitrifying bacteria. After flooding and equilibration, monitoring the concentration of amended nitrate in the supernatant of the sterile cores over a period of 7 days provided a simple procedure for the estimation of the diffusion coefficient of the nitrate ion in the flooded soils. An expression was developed that permitted this diffusion coefficient to be extracted from the slope of a plot of supernatant concentration versus (time)1/2. The values obtained, at 15 °C, varied from 2·4 to 6·8 × 10-10m2s-1. Sterile cores are usually treated as controls in denitrification experiments; this work develops a procedure whereby they may yield useful soil process information.
NASA Technical Reports Server (NTRS)
King, C.; Righter, K.; Danielson, L.; Pando, K.; Lee, C.
2010-01-01
Currently there are several hypotheses for the thermal state of the early Earth. Some hypothesize a shallow magma ocean, or deep magma ocean, or heterogeneous accretion which requires no magma ocean at all. Previous models are unable to account for Ge depletion in Earth's mantle relative to CI chondrites. In this study, the element Ge is used to observe the way siderophile elements partition into the metallic core. The purpose of this research is to provide new data for Ge and to further test these models for Earth's early stages. The partition coefficients (D(sub Ge) = c(sub metal)/c(sub silicate), where D = partition coefficient of Ge and c = concentration of Ge in the metal and silicate, respectively) of siderophile elements were studied by performing series of high pressure, high temperature experiments. They are also dependent on oxygen fugacity, and metal and silicate composition. Ge is a moderately siderophile element found in both the mantle and core, and has yet to be studied systematically at high temperatures. Moreover, previous work has been limited by the low solubility of Ge in silicate melts (less than 100 ppm and close to detection limits for electron microprobe analysis). Reported here are results from 14 experiments studying the partitioning of Ge between silicate and metallic liquids. The Ge concentrations were then analyzed using Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) which is sensitive enough to detect ppm levels of Ge in the silicate melt.
NASA Astrophysics Data System (ADS)
Zhang, Liqiang; Tan, Wenfang; Hu, Hao
2016-06-01
For modeling solidification process of casting accurately, a reliable heat transfer boundary condition data is required. In this paper, an inverse conduction model was established to determine the heat flux and heat transfer coefficient at the metal-sand mold interface for cylindrical casting in the lost foam process. The numerically calculated temperature was compared with analytic solution and simulation solution obtained by commercial software ProCAST to investigate the accuracy of heat conduction model. The instantaneous cast and sand mold temperatures were measured experimentally and these values were used to determine the interfacial heat transfer coefficient (IHTC). The IHTC values during lost foam casting were shown to vary from 20 to 800 W m-2 K-1. Additionally, the characteristics of the time-varying IHTC have also been discussed in this study.
NASA Astrophysics Data System (ADS)
Raymundo-Ortiz, A. I.; Ramos-Ramirez, E. G.; Cruz-Orea, A.; Salazar-Montoya, J. A.
2013-09-01
The main objective of this work is to determine the effect of different sodium alginate concentrations in hydrogels on their water-vapor diffusion coefficient (WVDC) and thermal effusivity (. These physical parameters were measured by photoacoustic and pyroelectric techniques, respectively. The results indicate that the higher values for the WVDC are presented at a concentration of 2 % sodium alginate. At lower concentrations of sodium alginate, the sample thermal effusivity increases, with a value close to the water thermal effusivity.
NASA Technical Reports Server (NTRS)
Theodorsen, Theodore
1944-01-01
Values of the circulation function have been obtained for dual-rotating propellers. Numerical values are given for four, eight, and twelve-blade dual-rotating propellers and for advance ratios from 2 to about 6. In addition, the circulation function has been determine for single-rotating propellers for the higher values of the advance ratio. The mass coefficient, another quantity of significance in propeller theory, has been introduced.
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Determination of the transmission coefficients for quantum structures using FDTD method.
Peng, Yangyang; Wang, Xiaoying; Sui, Wenquan
2011-12-01
The purpose of this work is to develop a simple method to incorporate quantum effect in traditional finite-difference time-domain (FDTD) simulators. Witch could make it possible to co-simulate systems include quantum structures and traditional components. In this paper, tunneling transmission coefficient is calculated by solving time-domain Schrödinger equation with a developed FDTD technique, called FDTD-S method. To validate the feasibility of the method, a simple resonant tunneling diode (RTD) structure model has been simulated using the proposed method. The good agreement between the numerical and analytical results proves its accuracy. The effectness and accuracy of this approach makes it a potential method for analysis and design of hybrid systems includes quantum structures and traditional components. PMID:22409063
NASA Astrophysics Data System (ADS)
Xu, Zuli; Miao, Jianying; Wang, Ning; Sheng, Ping
2011-03-01
Electroosmosis (EO) and streaming potential (SP) are two complementary electrokinetic processes related by the Onsager relation. In particular, electroosmotic pump (EOP) is potentially useful for a variety of engineering and bio-related applications. By fabricating samples consisting of dry-etched cylindrical pores (50 μ m in length and 3.5 μ m in diameter) on silicon wafers, we demonstrate that the use of digital control via voltage pulses can resolve the flow regulation and stability issues associated with the EOP, so that the intrinsic characteristics of the porous sample medium may be revealed. Through the consistency of the measured electroosmosis and the streaming potential coefficients as required by the Onsager relation, we deduce the zeta potential and the surface conductivity, both physical parameters pertaining to the liquid-solid interface.
NASA Astrophysics Data System (ADS)
Xu, Zuli; Miao, Jianying; Wang, Ning; Wen, Weijia; Sheng, Ping
2011-03-01
Electroosmosis and streaming potential are two complementary electrokinetic processes related by the Onsager relation. In particular, an electroosmotic pump (EOP) is potentially useful for a variety of engineering and bio-related applications. By fabricating samples consisting of dry-etched cylindrical pores (50 μm in length and 3.5 μm in diameter) on silicon wafers, we demonstrate that the use of digital control via voltage pulses can resolve the flow regulation and stability issues associated with the EOP, so that the intrinsic characteristics of the porous sample medium may be revealed. Through the consistency of the measured electroosmosis (EO) and the streaming potential (SP) coefficients as required by the Onsager relation, we deduce the zeta potential and the surface conductivity, both physical parameters pertaining to the liquid-solid interface.
Determination of the global recombination rate coefficient for the ISX-B Tokamak
Langley, R.A.; Howe, H.C.
1983-01-01
The global recombination rate coefficient for hydrogen has been measured for the ISX-B tokamak vacuum vessel for various surface conditions. The measurements were performed by observing the rate of decrease of gas pressure in the vessel during a glow discharge. The parameters of the glow discharge and the complete experimental method are described. Previously published analytic and numerical models are used for data analysis. The effects of surface contamination on the results are described. For ''unclean'' wall conditions sigmak/sub r/ = 1.8 x 10/sup -28/ cm/sup 4//atom.s at 296 K and increases to sigmak/sub r/ = 4.4 x 10/sup -28/ cm/sup 4//atoms.s for ''clean'' conditions and remains constant until subsequent exposure to air.
NASA Technical Reports Server (NTRS)
Muravyov, Alexander A.
1999-01-01
In this paper, a method for obtaining nonlinear stiffness coefficients in modal coordinates for geometrically nonlinear finite-element models is developed. The method requires application of a finite-element program with a geometrically non- linear static capability. The MSC/NASTRAN code is employed for this purpose. The equations of motion of a MDOF system are formulated in modal coordinates. A set of linear eigenvectors is used to approximate the solution of the nonlinear problem. The random vibration problem of the MDOF nonlinear system is then considered. The solutions obtained by application of two different versions of a stochastic linearization technique are compared with linear and exact (analytical) solutions in terms of root-mean-square (RMS) displacements and strains for a beam structure.
Varga, Agnes; Gyetvai, Gergely; Nagy, Lívia; Nagy, Géza
2009-08-01
The diffusion coefficient of glucose in different media is an important parameter in life sciences, as well as in biotechnology and microbiology. In this work a simple, fast method is proposed that is based on the electrochemical time of flight principle. In most of the earlier time of flight experiments performed, a constant flight distance was applied. In the present work a scanning electrochemical microscope (SECM) was applied as a measuring tool. With use of the SECM, the flying distance could be changed with high precision, making measurements with several flight distances more accurate and reliable values could be obtained for solutions as well as for gels. The conventional voltammetric methods are not applicable for glucose detection. In our work electrocatalytic copper oxide coated copper microelectrodes and micro-sized amperometric enzyme sensors were used as detectors, while microdroplet-ejecting pneumatically driven micropipettes were used as a source. PMID:19517100
Yasuda, Isamu; Hikita, Tomoji . Fundamental Technology Research Lab.)
1994-05-01
Chemical relaxation experiments were conducted on sintered samples of calcium-doped lanthanum chromites by abruptly changing the oxygen partial pressure in the atmosphere and following the time change of conductivity. The re-equilibration kinetics was analyzed by fitting the relaxation data to the solutions of Fick's second law for appropriate boundary conditions. The diffusion equation ignoring the effect of surface reaction failed to describe the transient behavior especially for the initial stage, while that taking the surface effect into account gave a satisfactory interpretation of the overall relaxation process and allowed a precise determination of the two kinetic parameters: oxygen chemical diffusion coefficient and surface reaction rate constant. The chemical diffusion coefficients increased with a decrease of the oxygen partial pressure due to the corresponding change in the concentration of the moving species. The activation energy was similar to that of oxygen vacancy diffusion coefficients in other monocrystalline perovskites, suggesting that the measured diffusion coefficients were attributable to lattice diffusion. The surface reaction rate constant increased with a decrease of the oxygen partial pressure similarly to the reported oxygen nonstoichiometry, which implies that the presence of oxygen vacancies plays an important role in the surface reaction kinetics.
AllamehZadeh, Mostafa
2011-12-15
A Quadratic Neural Networks (QNNs) model has been developed for identifying seismic source classification problem at regional distances using ARMA coefficients determination by Artificial Neural Networks (ANNs). We have devised a supervised neural system to discriminate between earthquakes and chemical explosions with filter coefficients obtained by windowed P-wave phase spectra (15 s). First, we preprocess the recording's signals to cancel out instrumental and attenuation site effects and obtain a compact representation of seismic records. Second, we use a QNNs system to obtain ARMA coefficients for feature extraction in the discrimination problem. The derived coefficients are then applied to the neural system to train and classification. In this study, we explore the possibility of using single station three-component (3C) covariance matrix traces from a priori-known explosion sites (learning) for automatically recognizing subsequent explosions from the same site. The results have shown that this feature extraction gives the best classifier for seismic signals and performs significantly better than other classification methods. The events have been tested, which include 36 chemical explosions at the Semipalatinsk test site in Kazakhstan and 61 earthquakes (mb = 5.0-6.5) recorded by the Iranian National Seismic Network (INSN). The 100% correct decisions were obtained between site explosions and some of non-site events. The above approach to event discrimination is very flexible as we can combine several 3C stations.
NASA Astrophysics Data System (ADS)
Santos, Jane Meri; Kreim, Virginie; Guillot, Jean-Michel; Reis, Neyval Costa; de Sá, Leandro Melo; Horan, Nigel John
2012-12-01
This study has investigated overall mass transfer coefficients of hydrogen sulphide from quiescent liquid surfaces under simulated laboratory conditions. Wind flow (friction velocity) has been correlated with the overall mass transfer coefficient (KL) of hydrogen sulphide in the liquid phase using a wind tunnel study. The experimental values for this coefficient have been compared with predicted KL values obtained from three different emission models that are widely used to determine volatilization rates from the quiescent surfaces of wastewater treatment unit processes. Friction velocity (in a range of 0.11 and 0.27 m s-1) was found to have a negligible influence on the overall mass transfer coefficients for hydrogen sulphide but by contrast two of the models predicted a stronger influence of friction velocity and overestimate the KL values by up to a factor of 12.5, thus risking unnecessary expenditure on odour control measures. However, at low wind speeds or friction velocities, when more odour complaints might be expected due to poor atmospheric dispersion, a better agreement of emission rates with experimental data was found for all the models.
NASA Astrophysics Data System (ADS)
Chou, F. N.-F.; Wu, C.-W.
2014-05-01
This paper presents a method to establish the objective function of a network flow programming model for simulating river-reservoir system operations and associated water allocation, with an emphasis on situations when the links other than demand or storage have to be assigned with nonzero cost coefficients. The method preserves the priorities defined by rule curves of reservoir, operational preferences for conveying water, allocation of storage among multiple reservoirs, and transbasin water diversions. Path enumeration analysis transforms these water allocation rules into linear constraints that can be solved to determine link cost coefficients. An approach to prune the original system into a reduced network is proposed to establish the precise constraints of nonzero cost coefficients, which can then be efficiently solved. The cost coefficients for the water allocation in the Feitsui and Shihmen reservoirs' joint operating system of northern Taiwan was adequately assigned by the proposed method. This case study demonstrates how practitioners can correctly utilize network-flow-based models to allocate water supply throughout complex systems that are subject to strict operating rules.
NASA Astrophysics Data System (ADS)
Chou, F. N.-F.; Wu, C.-W.
2013-12-01
This paper presents a method to establish the objective function of a network flow programming model for simulating river/reservoir system operations and associated water allocation, with an emphasis on situations when the links other than demand or storage have to be assigned with nonzero cost coefficients. The method preserves the priorities defined by rule curves of reservoir, operational preferences for conveying water, allocation of storage among multiple reservoirs, and trans-basin water diversions. Path enumeration analysis transforms these water allocation rules into linear constraints that can be solved to determine link cost coefficients. An approach to prune the original system into a reduced network is proposed to establish the precise constraints of nonzero cost coefficients which can then be efficiently solved. The cost coefficients for the water allocation in the Feitsui and Shihmen Reservoirs joint operating system of northern Taiwan was adequately assigned by the proposed method. This case study demonstrates how practitioners can correctly utilize network-flow-based models to allocate water supply throughout complex systems that are subject to strict operating rules.
NASA Technical Reports Server (NTRS)
Hawkins, Richard; Penland, Jim A.
1997-01-01
Observations have been made and reported that the experimental normal force coefficients at a constant angle of attack were constant with a variation of more than 2 orders of magnitude of Reynolds number at a free-stream Mach number M(sub infinity) of 8.00 and more than 1 order of magnitude variation at M(sub infinity) = 6.00 on the same body-wing hypersonic cruise configuration. These data were recorded under laminar, transitional, and turbulent boundary layer conditions with both hot-wall and cold-wall models. This report presents experimental data on 25 configurations of 17 models of both simple and complex geometry taken at M(sub infinity) = 6.00, 6.86, and 8.00 in 4 different hypersonic facilities. Aerodynamic calculations were made by computational fluid dynamics (CID) and engineering methods to analyze these data. The conclusions were that the normal force coefficients at a given altitude are constant with Reynolds numbers at hypersonic speeds and that the axial force coefficients recorded under laminar boundary-layer conditions at several Reynolds numbers may be plotted against the laminar parameter (the reciprocal of the Reynolds number to the one-half power) and extrapolated to the ordinate axis to determine the inviscid-wave-drag coefficient at the intercept.
Hindasageri, V; Vedula, R P; Prabhu, S V
2013-02-01
Temperature measurement by thermocouples is prone to errors due to conduction and radiation losses and therefore has to be corrected for precise measurement. The temperature dependent emissivity of the thermocouple wires is measured by the use of thermal infrared camera. The measured emissivities are found to be 20%-40% lower than the theoretical values predicted from theory of electromagnetism. A transient technique is employed for finding the heat transfer coefficients for the lead wire and the bead of the thermocouple. This method does not require the data of thermal properties and velocity of the burnt gases. The heat transfer coefficients obtained from the present method have an average deviation of 20% from the available heat transfer correlations in literature for non-reacting convective flow over cylinders and spheres. The parametric study of thermocouple error using the numerical code confirmed the existence of a minimum wire length beyond which the conduction loss is a constant minimal. Temperature of premixed methane-air flames stabilised on 16 mm diameter tube burner is measured by three B-type thermocouples of wire diameters: 0.15 mm, 0.30 mm, and 0.60 mm. The measurements are made at three distances from the burner tip (thermocouple tip to burner tip/burner diameter = 2, 4, and 6) at an equivalence ratio of 1 for the tube Reynolds number varying from 1000 to 2200. These measured flame temperatures are corrected by the present numerical procedure, the multi-element method, and the extrapolation method. The flame temperatures estimated by the two-element method and extrapolation method deviate from numerical results within 2.5% and 4%, respectively. PMID:23464237
NASA Astrophysics Data System (ADS)
Hindasageri, V.; Vedula, R. P.; Prabhu, S. V.
2013-02-01
Temperature measurement by thermocouples is prone to errors due to conduction and radiation losses and therefore has to be corrected for precise measurement. The temperature dependent emissivity of the thermocouple wires is measured by the use of thermal infrared camera. The measured emissivities are found to be 20%-40% lower than the theoretical values predicted from theory of electromagnetism. A transient technique is employed for finding the heat transfer coefficients for the lead wire and the bead of the thermocouple. This method does not require the data of thermal properties and velocity of the burnt gases. The heat transfer coefficients obtained from the present method have an average deviation of 20% from the available heat transfer correlations in literature for non-reacting convective flow over cylinders and spheres. The parametric study of thermocouple error using the numerical code confirmed the existence of a minimum wire length beyond which the conduction loss is a constant minimal. Temperature of premixed methane-air flames stabilised on 16 mm diameter tube burner is measured by three B-type thermocouples of wire diameters: 0.15 mm, 0.30 mm, and 0.60 mm. The measurements are made at three distances from the burner tip (thermocouple tip to burner tip/burner diameter = 2, 4, and 6) at an equivalence ratio of 1 for the tube Reynolds number varying from 1000 to 2200. These measured flame temperatures are corrected by the present numerical procedure, the multi-element method, and the extrapolation method. The flame temperatures estimated by the two-element method and extrapolation method deviate from numerical results within 2.5% and 4%, respectively.
NASA Astrophysics Data System (ADS)
Wassenburg, Jasper A.; Scholz, Denis; Jochum, Klaus Peter; Cheng, Hai; Oster, Jessica; Immenhauser, Adrian; Richter, Detlev K.; Haeger, Tobias; Hoffmann, Dirk; Breitenbach, Sebastian F. M.
2016-04-01
Speleothem trace element variability has often been linked to environmental changes. While research has focused on element incorporation into speleothem calcite, our current knowledge of trace element variability in speleothem aragonite is limited to a few studies only. Here we present, to our knowledge, for the first time quantitative estimates of distribution coefficients for speleothem aragonite (DMg, DBa, DSr, and DU). These were derived from ten calcite-to-aragonite transitions from seven speleothems from Morocco, Germany, Spain, France and India. Our calculations indicate the following distribution coefficients: DMg = 1.01E-04 ± 9.0E-05, DBa(Ar) = 0.91 ± 0.53, DSr(Ar) = 1.38 ± 0.53, and DU(Ar) = 6.26 ± 4.53. These results are discussed in the context of speleothem growth rates, Rayleigh distillation effects, temperature, drip water elemental composition and drip water pH. We conclude that speleothem aragonite DMg(Ar) is below one, DSr(Ar) is close to unity, and DU(Ar) is above one. For DBa(Ar), such a conclusion is difficult. Speleothem growth rate may affect aragonite DSr in samples forming at a growth rate lower than 20 μm/a. Our results also indicate that calcite DSr and calcite DBa are affected by the Mg content of calcite. This has important implications for studies attempting to quantify processes like prior calcite precipitation. In particular, DSr and DBa cannot be transferred from caves developed within a limestone host rock to caves developed within a dolostone host rock.
Determining Spectral Reflectance Coefficients from Hyperspectral Images Obtained from Low Altitudes
NASA Astrophysics Data System (ADS)
Walczykowski, P.; Jenerowicz, A.; Orych, A.; Siok, K.
2016-06-01
Remote Sensing plays very important role in many different study fields, like hydrology, crop management, environmental and ecosystem studies. For all mentioned areas of interest different remote sensing and image processing techniques, such as: image classification (object and pixel- based), object identification, change detection, etc. can be applied. Most of this techniques use spectral reflectance coefficients as the basis for the identification and distinction of different objects and materials, e.g. monitoring of vegetation stress, identification of water pollutants, yield identification, etc. Spectral characteristics are usually acquired using discrete methods such as spectrometric measurements in both laboratory and field conditions. Such measurements however can be very time consuming, which has led many international researchers to investigate the reliability and accuracy of using image-based methods. According to published and ongoing studies, in order to acquire these spectral characteristics from images, it is necessary to have hyperspectral data. The presented article describes a series of experiments conducted using the push-broom Headwall MicroHyperspec A-series VNIR. This hyperspectral scanner allows for registration of images with more than 300 spectral channels with a 1.9 nm spectral bandwidth in the 380- 1000 nm range. The aim of these experiments was to establish a methodology for acquiring spectral reflectance characteristics of different forms of land cover using such sensor. All research work was conducted in controlled conditions from low altitudes. Hyperspectral images obtained with this specific type of sensor requires a unique approach in terms of post-processing, especially radiometric correction. Large amounts of acquired imagery data allowed the authors to establish a new post- processing approach. The developed methodology allowed the authors to obtain spectral reflectance coefficients from a hyperspectral sensor mounted on an
Experimental determination of drag coefficients in low-density polyurethane foam
Adams, M L
2006-04-18
We describe several experiments performed at the LLNL Site 300 firing range and on the LLNL 1/3 scale gun to investigate the deceleration of small projectiles (l {approx} 3-5 [mm]) in low-density foam ({rho} {approx} 0.08-0.32 [g/cm{sup 3}]). The experiments at the firing range researched a passive velocity diagnostic based on Faraday's law of induction, while experiments on the 1/3 scale gun investigated the effects of varying projectile surface area, projectile shape, and foam density on the drag coefficient c{sub d}. Analysis shows that the velocity diagnostic has an uncertainty on the order of 1 percent for projectiles with velocity v {approx} 0.8-1.2 [km/s]. The 1/3 scale gun experiments, dubbed the Krispy Kreme series, included nine shots considering the combinations of 3 projectile surface areas with 3 target densities. The experiments used Tantalum square surface area block projectiles (with an initial velocity v{sub 0} {approx} 1.2 [km/s], a common thickness T = 2.67 [mm], and square side lengths of 3, 4, and 5 [mm]) decelerating in polyurethane foams (with densities {rho}{sub f} of 0.08, 0.16 and 0.32 [g/cm{sup 3}]). Standard fluid models of the Krispy Kreme experiments predict Reynolds numbers Re {approx} 10{sup 5} - 10{sup 6}, Mach numbers Ma {approx} 0.5-2.0, and drag coefficients c{sub d} {approx} 2-3. However, the data indicate that c{sub d} = 1.1-1.2 (c{sub d} = 1.7) for all three block projectiles in the 0.08 and 0.16 [g/cm{sup 3}] targets (0.32 [g/cm{sup 3}] target). First, we conclude that the drag force on projectiles in solid polyurethane foam is less than in fluids with equivalent dimensionless parameters. This result is also supported by an additional Krispy Kreme experiment that used a disk projectile (with diameter d = 4.51 [mm] and thickness T = 2.67 [mm]) penetrating a target with density {rho} = 0.16 [g/cm{sup 3}], i.e., the fluid-like c{sub d} = 1.15 while the measured c{sub d} = 0.63. Second, we conclude that the measured drag
Federal Register 2010, 2011, 2012, 2013, 2014
2013-07-05
... trade adjustment assistance for workers by (TA-W) number issued during the period of June 17, 2013... period beginning on the date on which-- (A) a summary of the report submitted to the President by the... workers have become totally or partially separated from the workers' firm within-- (A) the 1-year...
Chen, Junning; Suenaga, Hanako; Hogg, Michael; Li, Wei; Swain, Michael; Li, Qing
2016-01-01
Despite their considerable importance to biomechanics, there are no existing methods available to directly measure apparent Poisson's ratio and friction coefficient of oral mucosa. This study aimed to develop an inverse procedure to determine these two biomechanical parameters by utilizing in vivo experiment of contact pressure between partial denture and beneath mucosa through nonlinear finite element (FE) analysis and surrogate response surface (RS) modelling technique. First, the in vivo denture-mucosa contact pressure was measured by a tactile electronic sensing sheet. Second, a 3D FE model was constructed based on the patient CT images. Third, a range of apparent Poisson's ratios and the coefficients of friction from literature was considered as the design variables in a series of FE runs for constructing a RS surrogate model. Finally, the discrepancy between computed in silico and measured in vivo results was minimized to identify the best matching Poisson's ratio and coefficient of friction. The established non-invasive methodology was demonstrated effective to identify such biomechanical parameters of oral mucosa and can be potentially used for determining the biomaterial properties of other soft biological tissues. PMID:26024011
NASA Technical Reports Server (NTRS)
Yuan, F. G.
1998-01-01
Determination of all the coefficients in the crack tip field expansion for monoclinic materials under two-dimensional deformation is presented in this report. For monoclinic materials with a plane of material symmetry at x(sub 3) = 0, the in-plane deformation is decoupled from the anti-plane deformation. In the case of in-plane deformation, utilizing conservation laws of elasticity and Betti's reciprocal theorem, together with selected auxiliary fields, T-stress and third-order stress coefficients near the crack tip are evaluated first from path-independent line integrals. To determine the T-stress terms using the J-integral and Betti's reciprocal work theorem, auxiliary fields under a concentrated force and moment acting at the crack tip are used respectively. Through the use of Stroh formalism in anisotropic elasticity, analytical expressions for all the coefficients including the stress intensity factors are derived in a compact form that has surprisingly simple structure in terms of the Barnett-Lothe tensors, L. The solution forms for degenerated materials, orthotropic, and isotropic materials are presented.
Deen, William M.; Troy, Julia L.; Robertson, Channing R.; Brenner, Barry M.
1973-01-01
Pressures and flow rates were measured in accessible surface glomeruli of mutant Wistar rats under conditions deliberately designed to prevent achievement of filtration pressure equilibrium, that is, the equalization of transcapillary hydrostatic and oncotic pressures by the efferent end of the glomerulus as typically observed in the normal hydropenic rat. Disequilibrium was obtained at elevated levels of glomerular plasma flow (GPF) brought about by acute expansion of plasma volume with a volume of rat plasma equal to 5% of body weight. Glomerular hydrostatic and oncotic pressures measured at high GPF were used to calculate the ultrafiltration coefficient, Kf, the product of effective hydraulic permeability and surface area. GPF was then either lowered (by aortic constriction) or raised (by carotid occlusion) in order to examine the dependence of Kf on GPF. The value of Kf per glomerulus, 0.08 nl/(s·mm Hg), was found not to vary over an approximately twofold range of GPF. This finding, taken together with data from previous studies from this laboratory, leads us to conclude that plasma-flow dependence of glomerular filtration rate (GFR) results primarily from flow-induced changes in mean ultrafiltration pressure, rather than large changes in Kf. PMID:4703234
Brown, T D; Singerman, R J
1986-01-01
The mechanical properties of the cartilaginous regions of the proximal femoral epiphysis are an important factor in load transmission through the hip joint of young children. Cylindrical test specimens excised from the chondroepiphysis of human stillborn femoral heads were subjected to uniaxial loading in peripherally-unconfined compression, using a ramp/plateau input strain history. The corresponding load vs time curves were analyzed in terms of a recent analytical solution for a linear biphasic material (the well-known KLM model), allowing calculation of that model's three fundamental constitutive coefficients (permeability, equilibrium modulus and solid-phase Poisson ratio) for this material. The numerical algorithm developed to evaluate the biphasic solution yielded very precise replication of previously published KLM parametric plots. When fitted to experimental load histories, however, the model provided only a rather loose approximation of specimen behavior, due apparently to a substantial underestimation of the transient response component associated with interstitial fluid transport. Averaged over the series, the best-fit values for permeability (2.51 X 10(-15) m4 Ns-1) and equilibrium modulus (0.699 MPa) were in the range of values accepted for human adult articular cartilage. A consequence of the coarseness of the analytical curve fits was that a solid-phase Poisson ratio of 0.0 was inferred for all specimens. The permeability vs equilibrium modulus exhibited a nearly linear (r = 0.74) inverse relationship similar to that reported for adult articular cartilage. PMID:3771582
Wavelet coefficient analysis for the quantitative determination of damage in tendons and cables
NASA Astrophysics Data System (ADS)
Rizzo, Piervincenzo; Lanza di Scalea, Francesco
2005-05-01
Wires, bars, multi-wire strands made of steel or composite materials are widely used in civil infrastructures as tensioning members in cable-stayed bridges, suspension bridges and prestressed concrete. The health monitoring of these components is a long-standing challenge in the NDE community. In the last few years, the authors have been conducting a study on the application of ultrasonic guided waves for the structural health monitoring of bars and multi-wire strands. This paper presents an application of a signal processing technique based on the Discrete Wavelet Transform (DWT) for the detection and the quantification of damage (in the form of small notches) in loaded seven-wire steel strands. The DWT is applied to ultrasonic signals generated and detected via magnetostrictive transducers. The detection and the quantification of damage in the strands are accomplished by constructing and computing a damage index based on the variance and the root mean square of the wavelet coefficient vector of the ultrasonic damage signatures. It is shown that the logarithmic value of the damage index is linearly dependent on the damage size. In the last portion of the paper an eight-dimensional damage index is constructed and it is fed to an artificial neural network that classifies the size and the location of the notch.
Determination of the Accommodation Coefficient Using Vapor/gas Bubble Dynamics in an Acoustic Field
NASA Technical Reports Server (NTRS)
Gumerov, Nail A.; Hsiao, Chao-Tsung; Goumilevski, Alexei G.; Allen, Jeff (Technical Monitor)
2001-01-01
Nonequilibrium liquid/vapor phase transformations can occur in superheated or subcooled liquids in fast processes such as in evaporation in a vacuum. The rate at which such a phase transformation occurs depends on the "condensation" or "accommodation" coefficient, Beta, which is a property of the interface. Existing measurement techniques for Beta are complex and expensive. The development of a relatively inexpensive and reliable technique for measurement of Beta for a wide range of substances and temperatures is of great practical importance. The dynamics of a bubble in an acoustic field strongly depends on the value of Beta. It is known that near the saturation temperature, small vapor bubbles grow under the action of an acoustic field due to "rectified heat transfer." This finding can be used as the basis for an effective measurement technique of Beta. We developed a theory of vapor bubble behavior in an isotropic acoustic wave and in a plane standing acoustic wave. A numerical code was developed which enables simulation of a variety of experimental situations and accurately takes into account slowly evolving temperature. A parametric study showed that the measurement of Beta can be made over a broad range of frequencies and bubble sizes. We found several interesting regimes and conditions which can be efficiently used for measurements of Beta. Measurements of Beta can be performed in both reduced and normal gravity environments.
Determination of the diffusion length and the optical self absorption coefficient using EBIC model
NASA Astrophysics Data System (ADS)
Guermazi, S.; Guermazi, H.; Mlik, Y.; El Jani, B.; Grill, C.; Toureille, A.
2001-10-01
We have developed a model of calculation of the induced current due to an electron beam. The expression for the electron beam induced current (EBIC) with an extended generation profile is obtained via the resolution of a steady state continuity equation by the Green function method, satisfying appropriated boundary conditions to the physical model. The generation profile takes into account the lateral diffusion, the effect of defects, dislocations and recombination surfaces besides the number of absorbed electrons and that of diffuse electrons as a function of the depth. In the case of a Schottky diode Au/GaAs obtained by metalorganic vapour phase epitaxy (MOVPE) method, the theoretical induced current profile is compared to the experimental one and to theoretical profiles whose analytical expressions are given by van Roosbroeck and Bresse. The minority carriers diffusion length L_n = 2 μm and the optical self-absorption coefficient a=0.034 μm^{-1} can be deduced from the experimental current profile, measured by scanning electron microscopy. The theoretical curve, obtained from the proposed model is in a good agreement with the experimental one for surface recombination velocity 10^6 cm s^{-1} except for distances far from the depletion layer (x_0 > 2.3 μm) where the photocurrent produced by the multiple process of the reabsorbed recombination radiation is preponderant. Our results are in agreement with those obtained by other experimental techniques on the same samples.
NASA Astrophysics Data System (ADS)
Errifaiy, Meriem; Naasse, Smail; Chahine, Chakib
2016-07-01
Our work presents an analytical study of the determination of the reflection coefficient during the interaction between the regular wave current and a horizontal plate. This study was done using the linearized potential flow theory with the evanescent modes model, while searching for complex solutions to the dispersion equation that are neither real pure nor imaginary pure. To validate the established model, it has been confronted with the experimental results of V. Rey and J. Touboul, in a first phase, and then compared to those of the numerical study by H.-X. Lin et al. Then, this model was used to study the effect of current on the reflection coefficient. xml:lang="fr"
NASA Technical Reports Server (NTRS)
Whitesides, R. Harold; Majumdar, Alok K.; Jenkins, Susan L.; Bacchus, David L.
1990-01-01
A series of cold flow heat transfer tests was conducted with a 7.5-percent scale model of the Space Shuttle Rocket Motor (SRM) to measure the heat transfer coefficients in the separated flow region around the nose of the submerged nozzle. Modifications were made to an existing 7.5 percent scale model of the internal geometry of the aft end of the SRM, including the gimballed nozzle in order to accomplish the measurements. The model nozzle nose was fitted with a stainless steel shell with numerous thermocouples welded to the backside of the thin wall. A transient 'thin skin' experimental technique was used to measure the local heat transfer coefficients. The effects of Reynolds number, nozzle gimbal angle, and model location were correlated with a Stanton number versus Reynolds number correlation which may be used to determine the convective heating rates for the full scale Space Shuttle Solid Rocket Motor nozzle.
Nogueira, Bruno L; Pérez, Julio; van Loosdrecht, Mark C M; Secchi, Argimiro R; Dezotti, Márcia; Biscaia, Evaristo C
2015-09-01
In moving bed biofilm reactors (MBBR), the removal of pollutants from wastewater is due to the substrate consumption by bacteria attached on suspended carriers. As a biofilm process, the substrates are transported from the bulk phase to the biofilm passing through a mass transfer resistance layer. This study proposes a methodology to determine the external mass transfer coefficient and identify the influence of the mixing intensity on the conversion process in-situ in MBBR systems. The method allows the determination of the external mass transfer coefficient in the reactor, which is a major advantage when compared to the previous methods that require mimicking hydrodynamics of the reactor in a flow chamber or in a separate vessel. The proposed methodology was evaluated in an aerobic lab-scale system operating with COD removal and nitrification. The impact of the mixing intensity on the conversion rates for ammonium and COD was tested individually. When comparing the effect of mixing intensity on the removal rates of COD and ammonium, a higher apparent external mass transfer resistance was found for ammonium. For the used aeration intensities, the external mass transfer coefficient for ammonium oxidation was ranging from 0.68 to 13.50 m d(-1) and for COD removal 2.9 to 22.4 m d(-1). The lower coefficient range for ammonium oxidation is likely related to the location of nitrifiers deeper in the biofilm. The measurement of external mass transfer rates in MBBR will help in better design and evaluation of MBBR system-based technologies. PMID:25996756
NASA Technical Reports Server (NTRS)
Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.
2009-01-01
The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."
Hodge, S.A.
1980-08-01
The friction factor and Stanton number for flow past a roughened surface are determined by the parameters A and R(h/sup +/) of the universal law of friction and A/sub H/ and G(h/sup +/) of the universal law of heat transfer. The methods to be used for determination of these parameters for the particular roughness to be used in the Core Flow Test Loop (CFTL) are presented. Examples are given concerning the application of these methods to both transitional and fully rough flow using experimental results taken from the literature.
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2012-10-01
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Use of NMR Imaging to Determine the Diffusion Coefficient of Water in Bio-based Hydrogels
Technology Transfer Automated Retrieval System (TEKTRAN)
The diffusion of liquid in a hydrogel material is a fundamental property which must be controlled in order to create effective delivery systems for the agricultural and pharmaceutical industries. NMR spectroscopy has been used to determine the diffusion of water and deuterium oxide in a bio-based h...
Higaki, M.; Otsuka, T.; Hashizume, K.; Tokunaga, K.; Ezato, K.; Suzuki, S.; Enoeda, M.; Akiba, M.
2015-03-15
Hydrogen diffusion coefficients in a reduced activation ferritic/martensitic steel (F82H) and an oxide dispersion strengthened F82H (ODS-F82H) have been determined from depth profiles of plasma-loaded hydrogen with a tritium imaging plate technique (TIPT) in the temperature range from 298 K to 523 K. Data on hydrogen diffusion coefficients, D, in F82H, are summarized as D [m{sup 2}*s{sup -1}] =1.1*10{sup -7}exp(-16[kJ mol{sup -1}]/RT). The present data indicate almost no trapping effect on hydrogen diffusion due to an excess entry of energetic hydrogen by the plasma loading, which results in saturation of the trapping sites at the surface and even in the bulk. In the case of ODS-F82H, data of hydrogen diffusion coefficients are summarized as D [m{sup 2}*s{sup -1}] =2.2*10{sup -7}exp(-30[kJ mol{sup -1}]/RT) indicating a remarkable trapping effect on hydrogen diffusion caused by tiny oxide particles (Y{sub 2}O{sub 3}) in the bulk of F82H. Such oxide particles introduced in the bulk may play an effective role not only on enhancement of mechanical strength but also on suppression of hydrogen penetration by plasma loading.
Determination of the manning coefficient from measured bed roughness in natural channels
Limerinos, John Thomas
1970-01-01
This report presents the results of a study to test the hypothesis that basic values of the Manning roughness coefficient of stream channels may be related to (1) some characteristic size of the streambed particles and to (2) the distribution of particle size. These two elements involving particle size can be combined into a single element by weighting characteristic particle sizes. The investigation was confined to channels with coarse bed material to avoid the complication of bed-form roughness that is associated with alluvial channels composed of fine bed material. Fifty current-meter measurements of discharge and appropriate field surveys were made at 11 sites on California streams for the purpose of computing the roughness coefficient, n, by the Manning formula. The test sites were selected to give a wide range in average size of bed material, and the discharge measurements and surveys were made at such times as to provide data covering a suitable range in stream depth. The sites selected were relatively free of the extraneous flow-retarding effects associated with irregular channel conformation and streambank vegetation. The characteristic bed-particle sizes used in the analyses were the 16,- 50,- and 84-percentile sizes as obtained from a cumulative frequency distribution of the diameters of randomly sampled surficial bed material. Separate distributions were computed for the minimum and intermediate values of the three diameters of a particle. The minimum diameters of the streambed particles were used in the study because a particle at rest on the bed invariably has its minimum diameter in the vertical position; this diameter is, therefore, the most representative measure of roughness height. The intermediate diameter was also studied because this is the diameter most easily measurable-either by sieve analysis or by photographic techniques--and--because it is the diameter that had been used in previous studies by other investigators. No significant
Flight-determined stability and control coefficients of the F-111A airplane
NASA Technical Reports Server (NTRS)
Iliff, K. W.; Maine, R. E.; Steers, S. T.
1978-01-01
A complete set of linear stability and control derivatives of the F-111A airplane was determined with a modified maximum likelihood estimator. The derivatives were determined at wing sweep angles of 26 deg, 35 deg, and 58 deg. The flight conditions included a Mach number range of 0.63 to 1.43 and an angle of attack range of 2 deg to 15 deg. Maneuvers were performed at normal accelerations from 0.9g to 3.8g during steady turns to assess the aeroelastic effects on the stability and control characteristics. The derivatives generally showed consistent trends and reasonable agreement with the wind tunnel estimates. Significant Mach effects were observed for Mach numbers as low as 0.82. No large effects attributable to aeroelasticity were noted.
NASA Technical Reports Server (NTRS)
Messina, Michael D.
1995-01-01
The method described in this report is intended to present an overview of a process developed to extract the forebody aerodynamic increments from flight tests. The process to determine the aerodynamic increments (rolling pitching, and yawing moments, Cl, Cm, Cn, respectively) for the forebody strake controllers added to the F/A - 18 High Alpha Research Vehicle (HARV) aircraft was developed to validate the forebody strake aerodynamic model used in simulation.
NASA Astrophysics Data System (ADS)
Tobajas, M.; García-Calvo, E.
Mass transfer in bioreactors has been examined. In the present work, dynamic methods are used for the determination of KLa values for water, model media and a fermentation broth (Candida utilis) in an airlift reactor. The conventional dynamic method is applied at the end of the microbial process in order to avoid an alteration in the metabolism of the microorganisms. New dynamic methods are used to determine KLa in an airlift reactor during the microbial growth of Candida utilis on glucose. One of the methods is based on the continuous measurement of carbon dioxide production while the other method is based on the relationship between the oxygen transfer and biomass growth rates. These methods of determining KLa does not interfere with the microorganisms action. A theoretical mass transfer model has been used for KLa estimation for the systems described above. Some differences between calculated and measured values are found for fermentation processes due to the model is developed for two-phase air-water systems. Nevertheless, the average deviation between the predicted values and those obtained from the relationship between oxygen transfer and biomass production rates are lower than 25% in any case.
NASA Technical Reports Server (NTRS)
James, W. P.
1971-01-01
A simplified procedure is presented for determining water current velocities and diffusion coefficients. Dye drops which form dye patches in the receiving water are made from an aircraft. The changes in position and size of the patches are recorded from two flights over the area. The simplified data processing procedure requires only that the ground coordinates about the dye patches be determined at the time of each flight. With an automatic recording coordinatograph for measuring coordinates and a computer for processing the data, this technique provides a practical method of determining circulation patterns and mixing characteristics of large aquatic systems. This information is useful in assessing the environmental impact of waste water discharges and for industrial plant siting.
Jonker, Michiel T O
2016-06-01
Octanol-water partition coefficients (KOW ) are widely used in fate and effects modeling of chemicals. Still, high-quality experimental KOW data are scarce, in particular for very hydrophobic chemicals. This hampers reliable assessments of several fate and effect parameters and the development and validation of new models. One reason for the limited availability of experimental values may relate to the challenging nature of KOW measurements. In the present study, KOW values for 13 polycyclic aromatic hydrocarbons were determined with the gold standard "slow-stirring" method (log KOW 4.6-7.2). These values were then used as reference data for the development of an alternative method for measuring KOW . This approach combined slow stirring and equilibrium sampling of the extremely low aqueous concentrations with polydimethylsiloxane-coated solid-phase microextraction fibers, applying experimentally determined fiber-water partition coefficients. It resulted in KOW values matching the slow-stirring data very well. Therefore, the method was subsequently applied to a series of 17 moderately to extremely hydrophobic petrochemical compounds. The obtained KOW values spanned almost 6 orders of magnitude, with the highest value measuring 10(10.6) . The present study demonstrates that the hydrophobicity domain within which experimental KOW measurements are possible can be extended with the help of solid-phase microextraction and that experimentally determined KOW values can exceed the proposed upper limit of 10(9) . Environ Toxicol Chem 2016;35:1371-1377. © 2015 SETAC. PMID:26550770
NASA Astrophysics Data System (ADS)
Cicenaite, Aurelija; Huckins, James N.; Alvarez, David A.; Cranor, Walter L.; Gale, Robert W.; Kauneliene, Violeta; Bergqvist, Per-Anders
Semipermeable membrane devices (SPMDs) are a widely used passive sampling methodology for both waterborne and airborne hydrophobic organic contaminants. The exchange kinetics and partition coefficients of an analyte in a SPMD are mediated by its physicochemical properties and certain environmental conditions. Controlled laboratory experiments are used for determining the SPMD-air ( Ksa's) partition coefficients and the exchange kinetics of organic vapors. This study focused on determining a simple approach for measuring equilibrium Ksa's for naphthalene (Naph), o-chlorophenol ( o-CPh) and p-dichlorobenzene ( p-DCB) over a wide range of temperatures. SPMDs were exposed to test chemical vapors in small, gas-tight chambers at four different temperatures (-16, -4, 22 and 40 °C). The exposure times ranged from 6 h to 28 d depending on test temperature. Ksa's or non-equilibrium concentrations in SPMDs were determined for all compounds, temperatures and exposure periods with the exception of Naph, which could not be quantified in SPMDs until 4 weeks at the -16 °C temperature. To perform this study the assumption of constant and saturated atmospheric concentrations in test chambers was made. It could influence the results, which suggest that flow through experimental system and performance reference compounds should be used for SPMD calibration.
Cicenaite, Aurelija; Huckins, James N.; Alvarez, David A.; Cranor, Walter L.; Gale, Robert W.; Kauneliene, Violeta; Bergqvist, Per-Anders
2007-01-01
Semipermeable membrane devices (SPMDs) are a widely used passive sampling methodology for both waterborne and airborne hydrophobic organic contaminants. The exchange kinetics and partition coefficients of an analyte in a SPMD are mediated by its physicochemical properties and certain environmental conditions. Controlled laboratory experiments are used for determining the SPMD–air (Ksa's) partition coefficients and the exchange kinetics of organic vapors. This study focused on determining a simple approach for measuring equilibrium Ksa's for naphthalene (Naph), o-chlorophenol (o-CPh) and p-dichlorobenzene (p-DCB) over a wide range of temperatures. SPMDs were exposed to test chemical vapors in small, gas-tight chambers at four different temperatures (−16, −4, 22 and 40 °C). The exposure times ranged from 6 h to 28 d depending on test temperature. Ksa's or non-equilibrium concentrations in SPMDs were determined for all compounds, temperatures and exposure periods with the exception of Naph, which could not be quantified in SPMDs until 4 weeks at the −16 °C temperature. To perform this study the assumption of constant and saturated atmospheric concentrations in test chambers was made. It could influence the results, which suggest that flow through experimental system and performance reference compounds should be used for SPMD calibration.
Cicenaite, A.; Huckins, J.N.; Alvarez, D.A.; Cranor, W.L.; Gale, R.W.; Kauneliene, V.; Bergqvist, P.-A.
2007-01-01
Semipermeable membrane devices (SPMDs) are a widely used passive sampling methodology for both waterborne and airborne hydrophobic organic contaminants. The exchange kinetics and partition coefficients of an analyte in a SPMD are mediated by its physicochemical properties and certain environmental conditions. Controlled laboratory experiments are used for determining the SPMD-air (Ksa's) partition coefficients and the exchange kinetics of organic vapors. This study focused on determining a simple approach for measuring equilibrium Ksa's for naphthalene (Naph), o-chlorophenol (o-CPh) and p-dichlorobenzene (p-DCB) over a wide range of temperatures. SPMDs were exposed to test chemical vapors in small, gas-tight chambers at four different temperatures (-16, -4, 22 and 40 ??C). The exposure times ranged from 6 h to 28 d depending on test temperature. Ksa's or non-equilibrium concentrations in SPMDs were determined for all compounds, temperatures and exposure periods with the exception of Naph, which could not be quantified in SPMDs until 4 weeks at the -16 ??C temperature. To perform this study the assumption of constant and saturated atmospheric concentrations in test chambers was made. It could influence the results, which suggest that flow through experimental system and performance reference compounds should be used for SPMD calibration. ?? 2006 Elsevier Ltd. All rights reserved.
Dupont-Leclercq, Laurence; Giroux, Sébastien; Henry, Bernard; Rubini, Patrice
2007-10-01
The solubilization of octylamidotartaric acid (C8T) and octanoic acid (C8C) in Triton X-100 and Brij 58 nonionic micelles has been studied by pHmetric and 1H NMR self-diffusion experiments. As both C8C and C8T exhibit acid-base properties, a distinction between the partition of the neutral acidic form, in terms of the partition coefficient KPH, and the partition of the charged basic form, in terms of the partition coefficient KP-, has been made. The acidity constants, Ka, of C8T and C8C in the presence of micelles have been evaluated from pHmetric experiments. For both solutes, an increase in the pKa is observed in micellar media due to the difference in the partition of acidic and basic forms of the solutes. A model has been developed to determine KPH and KP- from the pKa shifts observed. The values obtained by this pKa shift modeling method and those from self-diffusion coefficient measurements are in good agreement. The acidic form of C8C is incorporated to a larger extent into the Brij 58 micelles than the acidic form of C8T, whereas the opposite trend is observed for the basic forms. Both the acidic and basic forms of C8T are more easily incorporated into Brij 58 micelles than into Triton X-100 micelles. The influence of the structure of the polar head on the solubilization properties is demonstrated. Moreover, evidence for the localization of the solutes in the micelles is obtained from the comparison of the partition coefficients and from 1H NMR data. PMID:17850105
NASA Astrophysics Data System (ADS)
Skoczylas, Norbert
2015-08-01
In this paper the conception of a low-cost device to determine the coefficient of permeability was presented. In the apparatus a non-typical source of gas and gas flow meter has been used. A used flow meter allows us to measure very low gas flow rates. The upper measurement range limit of the constructed device was about 20 cm3 min-1, whereas the lower measurement range limit was estimated to be approximately 0.01 cm3 min-1.
Miller, James A; Klippenstein, Stephen J
2013-04-01
In this article we discuss at length the determination of phenomenological rate coefficients from the solution to a time-dependent, multiple-well master equation. Both conservative and non-conservative formulations are considered. The emphasis is placed on how to handle the situation when a CSE (chemically significant eigenvalue of the transition matrix) merges with the quasi-continuum of IEREs (internal energy relaxation eigenvalues), indicating that one or more chemical reactions begin to take place on vibrational-rotational relaxation time scales. The methodology is illustrated with four examples. PMID:23435763
NASA Astrophysics Data System (ADS)
Vivacqua, Marco; Espinosa, Daniel; Martins Figueiredo Neto, Antônio
2012-06-01
We investigate the occurrence of the optical Kerr effect and two-photon absorption when an oil-based magnetic Fe3O4 nanoparticles colloidal suspension is illuminated with high intensity femtosecond laser pulses. The frequency of the pulses is controlled and the Z-scan technique is employed in our measurements of the nonlinear optical Kerr coefficient (n2) and two-photon absorption coefficient (β). From these values it was possible to calculate the real and imaginary parts of the third-order susceptibility. We observed that increasing the pulse frequency, additional physical processes take place, increasing artificially the absolute values of n2 and β. The experimental conditions are discussed to assure the obtention of reliable values of these nonlinear optical parameters, which may be useful in all-optical switching and optical power limiting applications.
Coefficients of an analytical aerosol forcing equation determined with a Monte-Carlo radiation model
NASA Astrophysics Data System (ADS)
Hassan, Taufiq; Moosmüller, H.; Chung, Chul E.
2015-10-01
Simple analytical equations for global-average direct aerosol radiative forcing are useful to quickly estimate aerosol forcing changes as function of key atmosphere, surface and aerosol parameters. The surface and atmosphere parameters in these analytical equations are the globally uniform atmospheric transmittance and surface albedo, and have so far been estimated from simplified observations under untested assumptions. In the present study, we take the state-of-the-art analytical equation and write the aerosol forcing as a linear function of the single scattering albedo (SSA) and replace the average upscatter fraction with the asymmetry parameter (ASY). Then we determine the surface and atmosphere parameter values of this equation using the output from the global MACR (Monte-Carlo Aerosol Cloud Radiation) model, as well as testing the validity of the equation. The MACR model incorporated spatio-temporally varying observations for surface albedo, cloud optical depth, water vapor, stratosphere column ozone, etc., instead of assuming as in the analytical equation that the atmosphere and surface parameters are globally uniform, and should thus be viewed as providing realistic radiation simulations. The modified analytical equation needs globally uniform aerosol parameters that consist of AOD (Aerosol Optical Depth), SSA, and ASY. The MACR model is run here with the same globally uniform aerosol parameters. The MACR model is also run without cloud to test the cloud effect. In both cloudy and cloud-free runs, the equation fits in the model output well whether SSA or ASY varies. This means the equation is an excellent approximation for the atmospheric radiation. On the other hand, the determined parameter values are somewhat realistic for the cloud-free runs but unrealistic for the cloudy runs. The global atmospheric transmittance, one of the determined parameters, is found to be around 0.74 in case of the cloud-free conditions and around 1.03 with cloud. The surface
Drevelegas, Konstantinos; Nikiforaki, Katerina; Constantinides, Manolis; Papanikolaou, Nickolas; Papalavrentios, Lavrentios; Stoikou, Ioanna; Zarogoulidis, Paul; Pitsiou, Georgia; Pataka, Athanasia; Organtzis, John; Papadaki, Eleni; Porpodis, Konstantinos; Kougioumtzi, Ioanna; Kioumis, Ioannis; Kouskouras, Constantinos; Akriviadis, Evaggelos; Drevelegas, Antonios
2016-01-01
Purpose: Diffusion Weighted Imaging is an established diagnostic tool for accurate differential diagnosis between benign and malignant liver lesions. The aim of our study was to evaluate the role of Histogram Analysis of ADC quantification in determining the histological diagnosis as well as the grade of malignant liver tumours. To our knowledge, there is no study evaluating the role of Histogram Analysis of ADC quantification in determining the histological diagnosis as well as the grade of malignant liver tumours. Methods: During five years, 115 patients with known liver lesions underwent Diffusion Weighted Imaging in 3Tesla MR scanner prior to core needle biopsy. Histogram analyses of ADC in regions of interest were drawn and were correlated with biopsy histological diagnosis and grading. Results: Histogram analysis of ADC values shows that 5th and 30th percentile parameters have statistically significant potency of discrimination between primary and secondary lesions groups (p values 0.0036 and 0.0125 respectively). Skewness of the histogram can help discriminate between good and poor differentiated (p value 0.17). Discrimination between primary malignancy site in metastases failed for the present number of patients in each subgroup. Conclusion: Statistical parameters reflecting the shape of the left side of the ADC histogram can be useful for discriminating between primary and secondary lesions and also between well differentiated versus moderate or poor. For the secondary malignancies, they failed to predict the original site of tumour. PMID:27076855
New Method for Determination of Adjustment Corrections for Crane Rail Axes
NASA Astrophysics Data System (ADS)
Kamiński, Waldemar
2013-10-01
Electronic tacheometers are currently a standard instrument used in geodetic work, including also geodetic engineering measurements. One of the many applications of tacheometers in engineering geodesy are 3D control measurements of crane rail axes. This paper proposes a new method of computing adjustment corrections for crane rail axes based on 3D polar measurements performed with an electronic tacheometer. The intermediary method with conditions on parameters was used in the solution of the problem. The theoretical discussion was complemented with an example application on simulated results of observations. The obtained results confirmed the theoretical assumptions and encourage the verification of the presented proposal on practical examples.
NASA Astrophysics Data System (ADS)
Yılmaz, Demet; Boydaş, Elif; Cömert, Esra
2016-08-01
In this study, we aimed to determine mass attenuation coefficient (μm) and effective atomic number (Zeff) for some compounds of the 3d transition elements such as CoO, CoF2, CoF3, Cr2O3, CrF2, CrF3, FeO, Fe2O3, MnO2, TiO2, V2O3, VF3, V2O5, VF4 and ZnO at 19.63 and 22.10 keV photon energies by using an HPGe detector with a resolution of 182 eV at 5.9 keV. The experimental results of μm are compared with the theoretical results. Also, effective atomic numbers of compounds of the 3d transition elements have been determined by using experimental and theoretical mass attenuation coefficients. The agreement of measured values of effective atomic numbers with theoretical calculations is quite satisfactory.
NASA Astrophysics Data System (ADS)
Tohmyoh, Hironori; Sakamoto, Yuhei
2015-11-01
This paper reports on a technique to measure the acoustic properties of a thin polymer film utilizing the frequency dependence of the reflection coefficient of ultrasound reflected back from a system comprising a reflection plate, the film, and a material that covers the film. The frequency components of the echo reflected from the back of the plate, where the film is attached, take their minimum values at the resonant frequency, and from these frequency characteristics, the acoustic impedance, sound velocity, and the density of the film can be determined. We applied this technique to characterize an ion exchange membrane, which has high water absorbability, and successfully determined the acoustic properties of the membrane without getting it wet.
NASA Technical Reports Server (NTRS)
Powell, W. B.
1973-01-01
A methodology is described for the analysis of a transient temperature measurement made in a flat or curved plate subjected to convective heat transfer, such that the surface heat flux, the hot-gas temperture, and the gas heat transfer coefficient can be determined. It is shown that if the transient temperature measurement is made at a particular point located nearly midway in the thickness of the plate there is an important simplification in the data analysis process, in that the factor relating the surface heat flux to the measured rate of rise of temperature becomes invariant for a Fourier Number above 0.60 and for all values of the Biot Number. Parameters are derived, tabulated, and plotted which enable straightforward determination of the surface heat flux, the hot-gas temperature, of the plate, the rate of rise of temperature, the plate thickness and curvature, and the mean thermal properties of the plate material at the test temperature.
Gas-film coefficients for streams
Rathbun, R.E.; Tai, D.Y.
1983-01-01
Equations for predicting the gas-film coefficient for the volatilization of organic solutes from streams are developed. The film coefficient is a function of windspeed and water temperature. The dependence of the coefficient on windspeed is determined from published information on the evaporation of water from a canal. The dependence of the coefficient on temperature is determined from laboratory studies on the evaporation of water. Procedures for adjusting the coefficients for different organic solutes are based on the molecular diffusion coefficient and the molecular weight. The molecular weight procedure is easiest to use because of the availability of molecular weights. However, the theoretical basis of the procedure is questionable. The diffusion coefficient procedure is supported by considerable data. Questions, however, remain regarding the exact dependence of the film coefficint on the diffusion coefficient. It is suggested that the diffusion coefficient procedure with a 0.68-power dependence be used when precise estimate of the gas-film coefficient are needed and that the molecular weight procedure be used when only approximate estimates are needed.
Lu, Yan; Li, Mingzhong
2016-01-01
The solubility and diffusion coefficient are two of the most important physicochemical properties of a drug compound. In practice, both have been measured separately, which is time consuming. This work utilizes a novel technique of UV imaging to determine the solubility and diffusion coefficients of poorly water-soluble drugs simultaneously. A 2-step optimal method is proposed to determine the solubility and diffusion coefficients of a poorly water-soluble pharmaceutical substance based on the Fick's second law of diffusion and UV imaging measurements. Experimental results demonstrate that the proposed method can be used to determine the solubility and diffusion coefficients of a drug with reasonable accuracy, indicating that UV imaging may provide a new opportunity to accurately measure the solubility and diffusion coefficients of a poorly water-soluble drug simultaneously and rapidly. PMID:26852848
NASA Astrophysics Data System (ADS)
Han, I.; Demir, L.
2009-01-01
The total mass attenuation coefficients ( μ m), for Cr, Fe, Ni and Fe xNi 1-x ( x = 0.8, 0.7, 0.6, 0.5, 0.4, 0.3 and 0.2), Fe xCr yNi 1-(x+y) ( x = 0.7, y = 0.1; x = 0.5, y = 0.2; x = 0.4, y = 0.3; x = 0.3, y = 0.3; x = 0.2, y = 0.2 and x = 0.1, y = 0.2) and Ni xCr 1-x ( x = 0.8, 0.6, 0.5, 0.4 and 0.2) alloys were measured at 22.1, 25.0, 59.5 and 88.0 keV photon energies. The samples were irradiated with 10 mCi Cd-109 and 100 mCi Am-241 radioactive point source using transmission arrangement. The γ- and X-rays were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. Total atomic and electronic cross-sections ( σ t and σ e), effective atomic and electron numbers ( Z eff and N eff) were determined experimentally and theoretically using the obtained mass attenuation coefficients for investigated 3d alloys. The theoretical mass attenuation coefficients of each alloy were estimated using mixture rule. The experimental values were compared with the calculated values for all samples.
NASA Astrophysics Data System (ADS)
Wijbrans, C. H.; Klemme, S.; Berndt, J.; Vollmer, C.
2015-04-01
We present new experimentally determined trace element partition coefficients between spinel and silicate melt. The experiments were performed at atmospheric pressure and at temperatures between 1220 and 1450 °C. To study the effect of redox conditions on trace element partitioning, we performed experiments under different redox conditions, with fO2 ranging from log -12 to log -0.7. The effect of different spinel compositions is also investigated. Our results show that spinel of all compositions readily incorporates the transition metals Ni, Co and Ga and the corresponding partition coefficients are >1. D Ni,Co,Ga are not significantly affected by changing melt composition, crystal composition or redox conditions. However, the multivalent trace elements V and Mo show a strong effect of redox conditions on their partitioning behavior with D V and D Mo highest at very reducing conditions and considerably lower at more oxidizing conditions. Partition coefficients for the high field strength elements Ti, Zr, Hf, Nb, and Ta and the elements Sc and Lu strongly depend on crystal composition, with D Ti and D Sc >1 for very Fe3+- or Cr-rich (and Al-poor) spinels, but one to two orders of magnitude lower in systems with Al-rich spinels. We present some examples on how our data may be used to reconstruct redox conditions of spinel formation. We also present some results on the partitioning of Pt and Rh between spinel and melt. D Rh depends strongly on redox conditions, while D Pt is not significantly affected.
Vereecken, H; Vanderborght, J; Kasteel, R; Spiteller, M; Schäffer, A; Close, M
2011-01-01
In this study, we analyzed sorption parameters for pesticides that were derived from batch and column or batch and field experiments. The batch experiments analyzed in this study were run with the same pesticide and soil as in the column and field experiments. We analyzed the relationship between the pore water velocity of the column and field experiments, solute residence times, and sorption parameters, such as the organic carbon normalized distribution coefficient ( ) and the mass exchange coefficient in kinetic models, as well as the predictability of sorption parameters from basic soil properties. The batch/column analysis included 38 studies with a total of 139 observations. The batch/field analysis included five studies, resulting in a dataset of 24 observations. For the batch/column data, power law relationships between pore water velocity, residence time, and sorption constants were derived. The unexplained variability in these equations was reduced, taking into account the saturation status and the packing status (disturbed-undisturbed) of the soil sample. A new regression equation was derived that allows estimating the values derived from column experiments using organic matter and bulk density with an value of 0.56. Regression analysis of the batch/column data showed that the relationship between batch- and column-derived values depends on the saturation status and packing of the soil column. Analysis of the batch/field data showed that as the batch-derived value becomes larger, field-derived values tend to be lower than the corresponding batch-derived values, and vice versa. The present dataset also showed that the variability in the ratio of batch- to column-derived value increases with increasing pore water velocity, with a maximum value approaching 3.5. PMID:21546674
Sokolov, V I; Marusin, N V; Panchenko, V Ya; Savelyev, A G; Seminogov, V N; Khaydukov, E V
2013-12-31
We propose a method for measuring simultaneously the refractive index n{sub f}, extinction coefficient m{sub f} and thickness H{sub f} of thin films. The method is based on the resonant excitation of waveguide modes in the film by a TE- or a TM-polarised laser beam in the geometry of frustrated total internal reflection. The values of n{sub f}, m{sub f} and H{sub f} are found by minimising the functional φ = [N{sup -1}Σ{sup N}{sub i=1}(R{sub exp}(θ{sub i}) – R{sub thr}(θ{sub i})){sup 2}]{sup 1/2}, where R{sub exp}(θ{sub i}) and R{sub thr}(θ{sub i}) are the experimental and theoretical coefficients of reflection of the light beam from the interface between the measuring prism and the film at an angle of incidence θ{sub i}. The errors in determining n{sub f}, m{sub f} and H{sub f} by this method are ±2 × 10{sup -4}, ±1 × 10{sup -3} and ±0.5%, respectively. (fiber and integrated optics)
NASA Astrophysics Data System (ADS)
Haberkorn, Christoph; Bloßfeld, Mathis; Bouman, Johannes; Fuchs, Martin; McMillan, Malcolm
2015-04-01
series for C20 from Center for Space Research (CSR), USA and DGFI, where both institutes use satellite laser ranging (SLR) to obtain the coefficient, as SLR is a highly suitable technique for C20 determination. In this study, we analyse different scenarios of C20 replacement to detect the effect of C20 on ice mass loss. The focus will be on the one hand Antarctica, where glaciers in the western part and the Antarctic Peninsula experience large ice mass loss and on the other hand Greenland.
Ramos, E.U.; Meijer, S.N.; Vaes, W.H.J.; Verhaar, H.J.M.; Hermens, J.L.M.
1998-11-01
In the current study, the suitability of negligible depletion solid-phase microextraction (nd-SPME) to determine free fractions of chemicals in aquatic environments was explored. The potential interferences of the dissolved matrix (i.e., humic acids) with the SPME measurements were tested. Results show that nd-SPME measures only the freely dissolved fraction and that the measurements are not disturbed by the humic acids. In addition, nd-SPME was used to determine partition coefficients between dissolved organic carbon and water for four hydrophobic chemicals. Obtained values are in excellent agreement with previously reported data. Finally, the bioaccumulation of hexachlorobenzene and PCB 77 to Daphnia magna was determined in the presence and absence of humic acids. The bioconcentration factors (BCF) were calculated based on total as well as on free concentration. Lower BCF values are obtained in the presence of humic acids using total concentrations, whereas equal BCFs are found using free concentrations measured with nd-SPME. Therefore, the authors can conclude that negligible depletion SPME is a good technique to determine bioavailable concentrations of hydrophobic chemicals in aquatic environments.
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Aguilar-Mendez, M A; Martin-Martinez, E San; Morales, J E; Cruz-Orea, A; Jaime-Fonseca, M R
2007-04-01
Water vapor diffusion coefficient (WVDC) and thermal diffusivity (alpha) were determined in gelatin-starch films through photothermal techniques. The effect of different variables in the elaboration of these films, such as starch and glycerol concentrations and pH, were evaluated through the response surface methodology. The results indicated that an increase in the glycerol concentration and pH favored the WVDC of the films. On the other hand, alpha was influenced principally by the starch content and pH of the film-forming solution. The minimum alpha value was 4.5 x 10(-4) cm2/s, which is compared with alpha values reported for commercial synthetic polymers. PMID:17420552
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NASA Astrophysics Data System (ADS)
Fukutomi, D.; Ishii, K.; Awazu, K.
2015-12-01
Anisotropy factor g, one of the optical properties of biological tissues, is the most important parameter to accurately determine scattering coefficient μs in the inverse Monte Carlo (iMC) simulation. It has been reported that g has wavelength and absorption dependence, however, there are few attempts in order to calculate μs of biological tissue considering the wavelength and absorption dependence of g. In this study, the scattering angular distributions of biological tissue phantoms were measured in order to determine g by using goniometric measurements with three polarization conditions at strongly and weakly absorbing wavelengths of hemoglobin. Then, optical properties, especially, μs were measured by integrating sphere measurements and iMC simulation in order to confirm the influence of measured g on optical properties in comparison of with general value of g (0.9) for soft biological tissue. Consequently, it was found that μs was overestimated at strongly absorbing wavelength, however, μs was underestimated at weakly absorbing wavelength if the g was not considered its wavelength and absorption dependence.
Guérin, Nicolas; Langevin, Marc-Antoine; Nadeau, Kenny; Labrecque, Charles; Gagné, Alexandre; Larivière, Dominic
2010-12-01
Neptunium(V) ions are unstable in acid media, which limits their extraction on chromatographic resins. We developed a novel analytical method to measure Np by either α-spectrometry or inductively coupled plasma mass spectrometry (ICP-MS) after extraction chromatography as Np(VI). We investigated the reactivity of various oxidizing reagents, and determined the retention capacity of Np(IV, V, and VI) on various extraction chromatographic supports. A simple method using two UTEVA resins was used to rapidly detect Np in soil and sediment samples. PMID:20630769
Hirasawa, Kazunori; Shoji, Nobuyuki; Yoshii, Yukako; Haraguchi, Shota
2014-01-01
Purpose To determine the axial length requiring adjustment of measured circumpapillary retinal nerve fiber layer (cpRNFL) thickness to account for ocular magnification during spectral-domain optical coherence tomography (SD-OCT). Methods In this prospective study, 148 eyes of 148 healthy student volunteers were imaged by two examiners using three-dimensional SD-OCT. In 54 randomly selected eyes, total cpRNFL thickness was measured with and without adjustment for ocular magnification to establish intra-examiner and inter-examiner measurement error. The 148 eyes were then divided into three groups according to the error values: control group (difference in the corrected and uncorrected total cpRNFL thickness was within the measurement error range), thinner group (the corrected total cpRNFL thickness was less than the uncorrected one), and thicker group (the corrected total cpRNFL thickness was more than the uncorrected one). The cutoff values of axial length between the control and the other groups were calculated by receiver operating characteristic analysis. Results Measurement error ranged from 4.2 to 5.3 µm; the threshold value was defined as 5.3 µm. The cutoff values of axial length between the thinner and the control groups and between the control and the thicker groups were 23.60 (area under the curve [AUC] = 0.959) and 25.55 (AUC = 0.944) mm, respectively. Conclusions Axial lengths shorter than 23.60 mm and longer than 25.55 mm require adjustment of measured cpRNFL thickness to account for ocular magnification during SD-OCT. Clinical Trial Registration UMIN Clinical Trials Registry (http://www.umin.ac.jp/) under unique trial number UMIN000013248 (date of registration: 02/24/2014) PMID:25215521
NASA Astrophysics Data System (ADS)
Mamedov, Bahtiyar A.; Somuncu, Elif; Askerov, Iskender M.
2016-08-01
In this work, a new theoretical approach is proposed for calculating fourth virial coefficient with Leonard-Jones potential. The established algorithm can be used to evaluate the thermodynamics properties and the intermolecular interaction potentials of liquids and gases with an improved accuracy. Note that the evaluation of the high-order virial coefficients is very valuable for accurate calculation of thermodynamic parameters. By using the suggested method, the fourth virial coefficient of CH4, Ar,C2H6 and SF6 molecules are evaluated. The calculation results are useful for accurate interpretation of the experimental data and of the determination of related physical properties.
Xu, Jing; Zhang, Jianshun S; Liu, Xiaoyu; Gao, Zhi
2012-06-01
The partition and effective diffusion coefficients of formaldehyde were measured for three materials (conventional gypsum wallboard, "green" gypsum wallboard, and "green" carpet) under three relative humidity (RH) conditions (20%, 50%, and 70% RH). The "green" materials contained recycled materials and were friendly to environment. A dynamic dual-chamber test method was used. Results showed that a higher relative humidity led to a larger effective diffusion coefficient for two kinds of wallboards and carpet. The carpet was also found to be very permeable resulting in an effective diffusion coefficient at the same order of magnitude with the formaldehyde diffusion coefficient in air. The partition coefficient (K(ma)) of formaldehyde in conventional wallboard was 1.52 times larger at 50% RH than at 20% RH, whereas it decreased slightly from 50% to 70% RH, presumably due to the combined effects of water solubility of formaldehyde and micro-pore blocking by condensed moisture at the high RH level. The partition coefficient of formaldehyde increased slightly with the increase of relative humidity in "green" wallboard and "green" carpet. At the same relative humidity level, the "green" wallboard had larger partition coefficient and effective diffusion coefficient than the conventional wallboard, presumably due to the micro-pore structure differences between the two materials. The data generated could be used to assess the sorption effects of formaldehyde on building materials and to evaluate its impact on the formaldehyde concentration in buildings. PMID:22788105
NASA Astrophysics Data System (ADS)
Dyadkin, A. A.; Khatuntseva, O. N.
2014-12-01
Analysis of experimental data shows that the nature of the oscillating motion of an aircraft does not depend uniquely on the value of the coefficients of aerodynamic damping derivatives. The present work makes an attempt to explain this phenomenon and develops a methodology to adequately characterize the oscillating motion of aircraft based on the analysis of the coefficients of aerodynamic damping derivatives.
Kockler, Katrin B; Haehnel, Alexander P; Junkers, Thomas; Barner-Kowollik, Christopher
2016-01-01
Detailed knowledge of the polymerization mechanisms and kinetics of academically and industrially relevant monomers is mandatory for the precision synthesis of tailor-made polymers. The IUPAC-recommended pulsed-laser polymerization-size exclusion chromatography (PLP-SEC) approach is the method of choice for the determination of propagation rate coefficients and the associated Arrhenius parameters for free radical polymerization processes. With regard to specific monomer classes-such as acrylate-type monomers, which are very important from a materials point of view-high laser frequencies of up to 500 Hz are mandatory to prevent the formation of mid-chain radicals and the occurrence of chain-breaking events by chain transfer, if industrially relevant temperatures are to be reached and wide temperature ranges are to be explored (up to 70 °C). Herein the progress and state-of-the-art of high-frequency PLP-SEC with pulse repetition rates of 500 Hz is reported, with a critical collection of to-date investigated 500 Hz data as well as future perspectives for the field. PMID:26479174
NASA Astrophysics Data System (ADS)
Maydanyuk, Sergei P.
In the paper the closed Friedmann-Robertson-Walker model with quantization in the presence of the positive cosmological constant and radiation is studied. For analysis of tunneling probability for birth of an asymptotically de Sitter, inflationary universe as a function of the radiation energy, a new definition of a "free" wave propagating inside strong fields is proposed. On such a basis, tunneling boundary condition is corrected, penetrability and reflection relative to the barrier are calculated in fully quantum stationary approach. For the first time nonzero interference between the incident and reflected waves has been taken into account which turns out to play important role inside cosmological potentials and could be explained by non-locality of barriers in quantum mechanics. Inside the whole region of radiation energy the tunneling probability for the birth of the inflationary universe is found to be close to its value obtained in the semiclassical approach. The reflection from the barrier is determined for the first time (which differs essentially on 1 at the energy of radiation close to the barrier height). The proposed method could be easily generalized on the cosmological models with barriers of arbitrary shape, as demonstrated for the FRW model with included Chaplygin gas. The result is stable for variations of the studied barriers, accuracy is found to be 11-18 digits for all coefficients and energies below the barrier height.
Delakowitz, B; Meinrath, G
1998-01-01
Assessment of radiological risks in strategies for decommissioning of nuclear installations have to consider not only technical concepts such as cutting and decontamination techniques but, even more important, requirements for input of reliable information on the hydrological situation and retardation capabilities of relevant radionuclides specific to the respective decommissioning operation. In this paper we describe appropriate methods for obtaining site-specific sorption data and present results achieved from a case study performed as a commercial contractual work preliminary to the planned decommissioning of a nuclear power plant. A detailed mineralogical study of the sediment used in our sorption experiment highlights the necessity of a thorough sample homogenization and characterization. Batch experiments using radiotracer techniques for the determination of site-specific sorption coefficients show significant retardation for Co-60 and Cs-137 after only 2 h of equilibration between the preconditioned groundwater and sediment. Sorption is more effective in the groundwater of a deeper aquifer containing a higher amount of colloidal clay (illite) particles < 0.63 micron. The Co-60 radiotracer is more completely sorbed than the Cs-137 radiotracer. Equilibration of radionuclide distribution is slow, particularly for Co-60. Presence of EDTA reduces sorption of Co-60 efficiently while Cs-137 sorption remains unaffected. PMID:10089594
Determining aerodynamic coefficients from high speed video of a free-flying model in a shock tunnel
NASA Astrophysics Data System (ADS)
Neely, Andrew J.; West, Ivan; Hruschka, Robert; Park, Gisu; Mudford, Neil R.
2008-11-01
This paper describes the application of the free flight technique to determine the aerodynamic coefficients of a model for the flow conditions produced in a shock tunnel. Sting-based force measurement techniques either lack the required temporal response or are restricted to large complex models. Additionally the free flight technique removes the flow interference produced by the sting that is present for these other techniques. Shock tunnel test flows present two major challenges to the practical implementation of the free flight technique. These are the millisecond-order duration of the test flows and the spatial and temporal nonuniformity of these flows. These challenges are overcome by the combination of an ultra-high speed digital video camera to record the trajectory, with spatial and temporal mapping of the test flow conditions. Use of a lightweight model ensures sufficient motion during the test time. The technique is demonstrated using the simple case of drag measurement on a spherical model, free flown in a Mach 10 shock tunnel condition.
Østergaard, Jesper; Hansen, Steen Honoré; Larsen, Claus; Schou, Christian; Heegaard, Niels H H
2003-03-01
Microemulsion electrokinetic chromatography (MEEKC) was assessed as a tool for determination of octanol-water partition coefficients using 34 solutes encompassing 8 carbonate esters. It was confirmed that microemulsions containing 1.44-2.88% w/w SDS, 6.49% w/w 1-butanol, and 0.82% w/w n-heptane constitute a good model of octanol-water partitioning in the pH range of 1.4-7.4. Use of the migration index concept led to improved repeatability of the MEEKC method compared to the use of retention factors. Using a dynamical coating, a high electroosmotic flow at pH 1.4 and 4.75 was achieved expanding the practical pH working range of the MEEKC system. The correlation obtained between the migration index and log P was unaffected by pH indicating that the properties of the microemulsion droplets and, thus, partitioning are independent of pH. No evidence for congeneric behavior was found for the sample set comprising solutes with different hydrogen bonding properties suggesting that simple reference compounds can be used as calibrators. Lipophilicity estimates for the series of carbonate esters were obtained. The increase in lipophilicity with chain length was smaller than expected from the Hansch substituent constant, pi. PMID:12658693
Hall Coefficient Determination and Electrical Properties of Chemical Bath-Deposited n-WO3 Thin Films
NASA Astrophysics Data System (ADS)
Amaechi, Ifeanyichukwu C.; Nwanya, Assumpta C.; Asogwa, Paul U.; Osuji, Rose U.; Maaza, Malik; Ezema, Fabian I.
2015-04-01
Nanocrystalline and porous chemical bath-deposited n-WO3 thin films at low temperature (318 K) are reported. The high-quality and well-reproducible films have been fabricated by acidic hydrolysis of tungstate ion followed by thermal annealing at 573 K for 1 h. X-ray diffraction analyses of the deposited WO3 films revealed that they were amorphous. However, an amorphous-to-crystalline transition with monoclinic phase was observed. Atomic force microscopy (AFM) analyses revealed a homogenous but irregular cluster of faceted spherically-shaped grains with pores. Scanning electron microscopy corroborated the AFM results. The optical absorption analysis of WO3 film showed that direct optical transition exists in the photon energy range 3.00-4.00 eV with bandgap of 3.70 eV. The refractive index developed peak at 315 nm in the dispersion region while the high frequency dielectric constant ɛ ∞, and the carrier concentration to effective mass ratio, N/m*, were found to be 1.37 and 1.45 × 1039 cm-3, respectively. The temperature dependence of the electrical resistivity of the deposited films follows the semiconductor behavior with thermal activation energy of 2.0 meV, while the Hall coefficient R H was determined to be 0.17 cm3/A s.
NASA Astrophysics Data System (ADS)
Haberer, C. M.; Grathwohl, P.
2009-12-01
Mass transfer from the unsaturated to the saturated zone across the capillary fringe is a common mechanism for groundwater contamination by volatile compounds (McCarthy and Johnson 1993) but also for oxygen supply. Oxygen plays an important role for microbial processes in groundwater - either by influencing the redox conditions directly or by replenishing electron acceptors needed for microbial growth and respiration. Hydrodynamic transverse dispersion was found to be essential for the mass transfer of vapor phase compounds across the capillary fringe (Klenk and Grathwohl 2002). Thus the objective of this work was to determine transverse vertical dispersion coefficients in this transition zone and a non-invasive method was developed to measure oxygen gradients across the saturated/unsaturated interface at grain scale resolution. Bench-scale 2D-flow through experiments have been conducted and different horizontal flow velocities, grain sizes, water table fluctuation amplitudes and frequencies have been applied. Vertical oxygen concentration profiles across the capillary fringe were subsequently measured at distinct positions in flow direction and evaluated with regard to mass transfer of oxygen from the unsaturated to the saturated zone. To the authors knowledge this is the first time where the fibre optical sensor technique to measure oxygen concentrations is applied to this transition zone. Transverse dispersion coefficients were calculated for steady state flow conditions. Under transient conditions, i.e. having changed the position of the water table, the measured concentration profiles are different with regard to the process of imbibition or drainage. Whereas drainage does not produce a significant change in concentration profiles compared to the stationary case, increasing water tables result in entrapment of air bubbles, and thus also a flatter gradient in oxygen concentrations. The gradual dissolution of entrapped oxygen into the bypassing oxygen
The partition and effective diffusion coefficients of formaldehyde were measured for three materials (conventional gypsum wallboard, "green" gypsum wallboard, and "green" carpet) under three relative humidity (RH) conditions (20%, 50% and 70% RH). A dynamic dual-chamber test meth...
The partition and effective diffusion coefficients of formaldehyde were measured for three materials (conventional gypsum wallboard, "green" gypsum wallboard, and "green" carpet) under three relative humidity (RH) conditions (20%, 50% and 70% RH). A dynamic dual-chamber test meth...
Heilig, Andrej; Sonne, Alina; Schieberle, Peter; Hinrichs, Jörg
2016-06-01
The partition of aroma compounds between a matrix and a gas phase describes an individual compound's specific affinity toward the matrix constituents affecting orthonasal sensory perception. The static headspace phase ratio variation (PRV) method has been increasingly applied by various authors to determine the equilibrium partition coefficient K in aqueous, polysaccharide, and dairy matrices. However, reported partition coefficients are difficult to relate and compare due to different experimental conditions, e.g., aroma compound selection, matrix composition, equilibration temperature. Due to its specific advantages, the PRV method is supposed to find more frequent application in the future, this Review aims to summarize, evaluate, compare, and relate the currently available data on PRV-determined partition coefficients. This process was designed to specify the potentials and the limitations as well as the consistency of the PRV method, and to identify open fields of research in aroma compound partitioning in food-related, especially dairy matrices. PMID:27182770
NASA Astrophysics Data System (ADS)
Kim, J. G.; Liu, H.
2007-10-01
Near-infrared spectroscopy or imaging has been extensively applied to various biomedical applications since it can detect the concentrations of oxyhaemoglobin (HbO2), deoxyhaemoglobin (Hb) and total haemoglobin (Hbtotal) from deep tissues. To quantify concentrations of these haemoglobin derivatives, the extinction coefficient values of HbO2 and Hb have to be employed. However, it was not well recognized among researchers that small differences in extinction coefficients could cause significant errors in quantifying the concentrations of haemoglobin derivatives. In this study, we derived equations to estimate errors of haemoglobin derivatives caused by the variation of haemoglobin extinction coefficients. To prove our error analysis, we performed experiments using liquid-tissue phantoms containing 1% Intralipid in a phosphate-buffered saline solution. The gas intervention of pure oxygen was given in the solution to examine the oxygenation changes in the phantom, and 3 mL of human blood was added twice to show the changes in [Hbtotal]. The error calculation has shown that even a small variation (0.01 cm-1 mM-1) in extinction coefficients can produce appreciable relative errors in quantification of Δ[HbO2], Δ[Hb] and Δ[Hbtotal]. We have also observed that the error of Δ[Hbtotal] is not always larger than those of Δ[HbO2] and Δ[Hb]. This study concludes that we need to be aware of any variation in haemoglobin extinction coefficients, which could result from changes in temperature, and to utilize corresponding animal's haemoglobin extinction coefficients for the animal experiments, in order to obtain more accurate values of Δ[HbO2], Δ[Hb] and Δ[Hbtotal] from in vivo tissue measurements.
NASA Astrophysics Data System (ADS)
Thomas, S.; Koch-Mueller, M.; Reichart, P.; Rhede, D.; Thomas, R.
2007-12-01
Conventionally applied Infrared (IR) calibrations [1, 2] for quantitative water analyses in solids are established on hydrous minerals and glasses with several wt% water. These calibrations are based on a negative correlation between the IR molar absorption coefficient (ɛ) for water and the mean wavenumber of the corresponding OH pattern. The correlation reflects the dependence of the OH band position on the appropriate O- H...O distances and thereby the magnitude of the dipole momentum which is proportional to the band intensity. However, it has been observed that these calibrations can not be adopted to nominally anhydrous minerals (NAMs) [3].To study the potential dependence of ɛ on structure and chemistry in NAMs we synthesized olivine and SiO2 polymorphs with specific isolated hydroxyl point defects, e.g. quartz, coesite and stishovite with B3++H+=Si4+ and/or Al3++H+=Si4+ substitutions. Experiments were performed with water in excess in piston cylinder and multi-anvil presses. Single crystal IR spectra demonstrate that we successfully managed to seperate generally complex OH patterns as e.g. observed in natural quartz and synthetic coesite. We quantified sample water contents of both natural samples and our run products by applying proton-proton-scattering [4], confocal microRaman spectroscopy [5] and Secondary Ion mass spectrometry. Resulting water concentrations were used to calculate new mineral specific ɛs. For olivine with the mean wavenumber of 3517 cm-1 we determined an ɛ value of 41,000±5,000 lmol-1H2Ocm-2. Quantification of olivine with the mean wavenumber of 3550 cm-1 in contrast resulted in an ɛ value of 47,000±1,000 lmol-1H2Ocm-2. Taking into account previous studies [6, 7] there is evidence to suggest a linear wavenumber dependent correlation for olivine, where ɛ increases with decreasing wavenumber. In case of the SiO2 system it turns out that the magnitude of ɛ within one structure type is independent of the liable OH point defect and
ERIC Educational Resources Information Center
Liebkind, Karmela; Jasinskaja-Lahti, Inga; Solheim, Erling
2004-01-01
This study focuses on factors predicting school adjustment of immigrant adolescents. One hundred seventy-five immigrant adolescents of Vietnamese origin in Finland (ages 13 to 18) were compared with a sample of host national Finnish youth (N = 337). The immigrant adolescents were better adjusted to school than were their host national peers. In…
ERIC Educational Resources Information Center
Coskuntuncel, Orkun
2013-01-01
The purpose of this study is two-fold; the first aim being to show the effect of outliers on the widely used least squares regression estimator in social sciences. The second aim is to compare the classical method of least squares with the robust M-estimator using the "determination of coefficient" (R[superscript 2]). For this purpose,…
Thomas, B.L.
1984-07-01
Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.
NASA Astrophysics Data System (ADS)
Shang, L.; Chou, I.; Lu, W.; Burruss, R. C.
2008-12-01
The oxygen buffer technique is routinely used in experimental studies of redox sensitive geochemical reactions at elevated pressures (P) and temperatures (T). However, this technique is limited to T above about 400°C due to the low permeability of sample containers (Pt or Ag-Pd alloys) to hydrogen at lower T. Preliminary results of Chou et al. (Geochim. Cosmochim. Acta, 2008, doi:10.1016/j.gca.2008.07.030) indicate that the use of fused silica capillary (FSC) container may extend this technique to lower T. In this study, hydrogen diffusion coefficients (D) in FSC were determined from 23 to 250°C by measuring the loss of hydrogen from the FSC containers (0.3 mm OD, 0.1 mm ID, and ~10 mm long) with Raman spectroscopy using CO2 as an internal standard. First, CO2 was loaded cryogenically in a FSC capsule (Chou et al., ibid.). The capsule was then inserted in a protective ceramic tube, sealed in a gold capsule containing Fe powder and water, and heated at 300°C under 100 MPa of Ar external P in a cold-seal pressure vessel for several days allowing H2 to diffuse into the capsule. After quench, the Raman spectra were collected and the initial relative concentration of hydrogen in the silica capsule was derived from the peak height ratios between H2 (near 587 cm-1) and CO2 (near 1387 cm- 1). The sample capsule was then heated at a fixed T at one atmosphere to let H2 diffuse out of the capsule, and the changes of hydrogen concentration were monitored by Raman spectroscopy after quench. This process was repeated with different heating durations at 23 (room T), 50, 102, 157, 200, and 250°C. The values of D (in cm2s-1) in FSC were obtained by fitting the observed changes of hydrogen concentration to an equation based on Fick's second law. Our results can be represented by: Ln D (±0.14) = (-39810/RT) - 9.5491 (r2 = 0.9985) where R is the gas constant, and T in Kelvin. The slope corresponds to an activation energy of 39.81 kJ/mol. Our D values are about a half order of
Wittenberg, P; Sever, K; Knoth, S; Sahin, N; Bondarenko, J
2013-01-01
Due to substantial progress made in road safety in the last ten years, the European Union (EU) renewed the ambitious agreement of halving the number of persons killed on the roads within the next decade. In this paper we develop a method that aims at finding an optimal target for each nation, in terms of being as achievable as possible, and with the cumulative EU target being reached. Targets as an important component in road safety policy are given as reduction rate or as absolute number of road traffic deaths. Determination of these quantitative road safety targets (QRST) is done by a top-down approach, formalized in a multi-stage adjustment procedure. Different QRST are derived under consideration of recent research. The paper presents a method to break the national target further down to regional targets in case of the German Federal States. Generalized linear models are fitted to data in the period 1991-2010. Our model selection procedure chooses various models for the EU and solely log-linear models for the German Federal States. If the proposed targets for the EU Member States are attained, the sum of fatalities should not exceed the total value of 15,465 per year by 2020. Both, the mean level and the range of mortality rates within the EU could be lowered from 28-113 in 2010 to 17-41 per million inhabitants in 2020. This study provides an alternative to the determination of safety targets by political commitments only, taking the history of road fatalities trends and population into consideration. PMID:22770816
NASA Astrophysics Data System (ADS)
Chan, T. L.
This paper presents the effect of viewing-angle variations on the accuracy of transient and heated-coating liquid-crystal methods for determining the local heat transfer coefficients on a curved surface. A developed liquid-crystal calibration technique using a true-color image processing system has been used to alleviate the effect of viewing angle on oblique/curved surfaces. The accuracy of heat transfer coefficients improved significantly with careful correction of the viewing-angle effect on the surface geometry. It is crucial to ensure the implementation of the suggested calibration technique to be used in wideband thermochromic liquid-crystal applications on the non-orthogonal surface.
NASA Technical Reports Server (NTRS)
Torr, D. G.; Orsini, N.
1978-01-01
The Atmosphere Explorer (AE) data are reexamined in the light of new laboratory measurements of the N2(+) recombination rate coefficient alpha. The new measurements support earlier measurements which yielded values of alpha significantly lower than the AE values. It is found that the values for alpha determined from the satellite data can be reconciled with the laboratory measurements, if the charge exchange rate coefficient for O(+)(2D) with N2 is less than one-quarter of that derived in the laboratory by Rutherford and Vroom (1971).
Determination of Mass Attenuation Coefficients for CuInSe2 and CuGaSe2 Semiconductors
NASA Astrophysics Data System (ADS)
Çelik, Ahmet; Çevik, Uǧur; Baltaş, Hasan; Bacaksiz, Emin
2007-04-01
This work presents mass attenuation coefficients values of CuInSe2 and CuGaSe2 semiconductor thin films commonly used in photovoltaic devices. The mass attenuation coefficients were measured at different energies from 11.9 to 37.3 keV by using the secondary excitation method. Monochromatic photons were obtained using the Br, Sr, Mo, Cd, Te, Ba and Nd secondary targets. 59.5 keV gamma rays emitted from an annular Am-241 radioactive source were used to excite secondary targets. Characteristic X-rays emitted from secondary target were counted by a Si(Li) detector with a resolution of 0.16 keV at 5.9 keV. The measured values were compared with theoretical values calculated using WinXCOM program.
Determination of Mass Attenuation Coefficients for CuInSe2 and CuGaSe2 Semiconductors
Celik, Ahmet; Cevik, Ugur; Baltas, Hasan; Bacaksiz, Emin
2007-04-23
This work presents mass attenuation coefficients values of CuInSe2 and CuGaSe2 semiconductor thin films commonly used in photovoltaic devices. The mass attenuation coefficients were measured at different energies from 11.9 to 37.3 keV by using the secondary excitation method. Monochromatic photons were obtained using the Br, Sr, Mo, Cd, Te, Ba and Nd secondary targets. 59.5 keV gamma rays emitted from an annular Am-241 radioactive source were used to excite secondary targets. Characteristic X-rays emitted from secondary target were counted by a Si(Li) detector with a resolution of 0.16 keV at 5.9 keV. The measured values were compared with theoretical values calculated using WinXCOM program.
2016-01-01
Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeated full-thickness human nails more deeply than luliconazole. Amorolfine and terbinafine did not show any detectable permeation. The free-drug concentration of efinaconazole in a 5% human nail keratin suspension was 24.9%, which was significantly higher than those of the other drugs (1.1–3.9%). Additionally, efinaconazole was released from human nail keratin at a greater proportion than the other drugs. The MICs of the five drugs for Trichophyton rubrum were determined at various concentrations of keratin (0–20%) in RPMI 1640 medium. The MICs of ciclopirox were not affected by keratin, whereas those of efinaconazole were slightly increased and those of luliconazole and terbinafine were markedly increased in the presence of 20% keratin. Efficacy coefficients were calculated using the nail permeation flux and MIC in media without or with keratin. Efinaconazole showed the highest efficacy coefficient, which was determined using MIC in media with keratin. The order of efficacy coefficients determined using MIC in keratin-containing media rather than keratin-free media was consistent with that of complete cure rates in previously reported clinical trials. The present study revealed that efficacy coefficients determined using MIC in keratin-containing media are useful for predicting the clinical efficacies of topical drugs. In order to be more effective, topical drugs have to possess higher efficacy coefficients. PMID:27441843
Matsuda, Yoshiki; Sugiura, Keita; Hashimoto, Takashi; Ueda, Akane; Konno, Yoshihiro; Tatsumi, Yoshiyuki
2016-01-01
Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeated full-thickness human nails more deeply than luliconazole. Amorolfine and terbinafine did not show any detectable permeation. The free-drug concentration of efinaconazole in a 5% human nail keratin suspension was 24.9%, which was significantly higher than those of the other drugs (1.1-3.9%). Additionally, efinaconazole was released from human nail keratin at a greater proportion than the other drugs. The MICs of the five drugs for Trichophyton rubrum were determined at various concentrations of keratin (0-20%) in RPMI 1640 medium. The MICs of ciclopirox were not affected by keratin, whereas those of efinaconazole were slightly increased and those of luliconazole and terbinafine were markedly increased in the presence of 20% keratin. Efficacy coefficients were calculated using the nail permeation flux and MIC in media without or with keratin. Efinaconazole showed the highest efficacy coefficient, which was determined using MIC in media with keratin. The order of efficacy coefficients determined using MIC in keratin-containing media rather than keratin-free media was consistent with that of complete cure rates in previously reported clinical trials. The present study revealed that efficacy coefficients determined using MIC in keratin-containing media are useful for predicting the clinical efficacies of topical drugs. In order to be more effective, topical drugs have to possess higher efficacy coefficients. PMID:27441843
NASA Astrophysics Data System (ADS)
Franco, Ediguer E.; Adamowski, Julio C.; Buiochi, Flávio
2012-05-01
This work implements the ultrasonic shear-wave reflectance method for viscosity measurements. A modeconversion device was used for the dynamic viscosity measurement of mineral oil, SAE 40 automotive oil and glycerin samples at room temperature and 1 MHz. A novel signals processing technique that calculates the reflection coefficient magnitude in a frequency band, instead of a single frequency, was employed, showing an important improvement on the measurement accuracy.
Determination of the loss coefficient of elbows in the flow of low-density spherical capsule train
Ulusarslan, Deniz
2007-11-15
Design parameters of a pipelines capsule flow can be calculated if dependence of pressure drops on flow velocity and capsule concentration of such pipelines are known. For this purpose, loss coefficients of elbows were studied experimentally in pipeline loop of I.D. 0.1 m. Elbows with central angles of 90 and 45 made of PVC were used for low-density spherical capsule train flow. The outer diameter and relative density of the capsules were 0.08 m and 0.87, respectively; the pressure drops were measured at Reynolds number range 2 x 10{sup 4} < Re < 1 x 10{sup 5} and for a transport concentration from 5% to 25%. Increments of the pressure gradient become larger at higher velocities and solid phase concentrations. The pressure gradients that occurred at the 90 elbow were higher than that occurred at the 45 elbow. Loss coefficient of the 90 elbow for the same flow velocity and capsule concentration in the capsules-water mixture flow is from 3 to 2 times higher than the loss coefficient at the 45 elbow. (author)
NASA Astrophysics Data System (ADS)
Yan, Yangqian; Blume, D.
2016-06-01
The unitary equal-mass Fermi gas with zero-range interactions constitutes a paradigmatic model system that is relevant to atomic, condensed matter, nuclear, particle, and astrophysics. This work determines the fourth-order virial coefficient b4 of such a strongly interacting Fermi gas using a customized ab initio path-integral Monte Carlo (PIMC) algorithm. In contrast to earlier theoretical results, which disagreed on the sign and magnitude of b4 , our b4 agrees within error bars with the experimentally determined value, thereby resolving an ongoing literature debate. Utilizing a trap regulator, our PIMC approach determines the fourth-order virial coefficient by directly sampling the partition function. An on-the-fly antisymmetrization avoids the Thomas collapse and, combined with the use of the exact two-body zero-range propagator, establishes an efficient general means to treat small Fermi systems with zero-range interactions.
Yan, Yangqian; Blume, D
2016-06-10
The unitary equal-mass Fermi gas with zero-range interactions constitutes a paradigmatic model system that is relevant to atomic, condensed matter, nuclear, particle, and astrophysics. This work determines the fourth-order virial coefficient b_{4} of such a strongly interacting Fermi gas using a customized ab initio path-integral Monte Carlo (PIMC) algorithm. In contrast to earlier theoretical results, which disagreed on the sign and magnitude of b_{4}, our b_{4} agrees within error bars with the experimentally determined value, thereby resolving an ongoing literature debate. Utilizing a trap regulator, our PIMC approach determines the fourth-order virial coefficient by directly sampling the partition function. An on-the-fly antisymmetrization avoids the Thomas collapse and, combined with the use of the exact two-body zero-range propagator, establishes an efficient general means to treat small Fermi systems with zero-range interactions. PMID:27341213
NASA Astrophysics Data System (ADS)
Yan, Yangqian; Blume, D.
2016-05-01
The unitary equal-mass Fermi gas with zero-range interactions constitutes a paradigmatic model system that is relevant to atomic, condensed matter, nuclear, particle, and astro physics. This work determines the fourth-order virial coefficient b4 of such a strongly-interacting Fermi gas using a customized ab inito path integral Monte Carlo (PIMC) algorithm. In contrast to earlier theoretical results, which disagreed on the sign and magnitude of b4, our b4 agrees with the experimentally determined value, thereby resolving an ongoing literature debate. Utilizing a trap regulator, our PIMC approach determines the fourth-order virial coefficient by directly sampling the partition function. An on-the-fly anti-symmetrization avoids the Thomas collapse and, combined with the use of the exact two-body zero-range propagator, establishes an efficient general means to treat small Fermi systems with zero-range interactions. We gratefully acknowledge support by the NSF.
NASA Astrophysics Data System (ADS)
Ménesguen, Y.; Gerlach, M.; Pollakowski, B.; Unterumsberger, R.; Haschke, M.; Beckhoff, B.; Lépy, M.-C.
2016-02-01
The knowledge of atomic fundamental parameters such as mass attenuation coefficients with low uncertainties, is of decisive importance in elemental quantification using x-ray fluorescence analysis techniques. Several databases are accessible and frequently used within a large community of users. These compilations are most often in good agreement for photon energies in the hard x-ray ranges. However, they significantly differ for low photon energies and around the absorption edges of any element. In a joint cooperation of the metrology institutes of France and Germany, mass attenuation coefficients of copper and zinc were determined experimentally in the photon energy range from 100 eV to 30 keV by independent approaches using monochromatized synchrotron radiation at SOLEIL (France) and BESSY II (Germany), respectively. The application of high-accuracy experimental techniques resulted in mass attenuation coefficient datasets determined with low uncertainties that are directly compared to existing databases. The novel datasets are expected to enhance the reliability of mass attenuation coefficients.
Krakow, K.I.; Lin, S.; Zeng, Z.S.
1995-08-01
A linearized analysis of temperature and relative humidity control using proportional-integral-differential (PID) controls to vary compressor motor speed and evaporator fan speed enables analytical determination of suitable PID coefficients. The PID coefficients are related to refrigeration system performance parameters and the volume of the conditioned space. Analytical determination of coefficients may eliminate or supplement trial-and-error methods. System response characteristics--damping ratios and periods--are related to PID coefficients, sampling intervals, performance parameters of a refrigeration system, and the volume of a conditioned space. Two control strategies are possible in order to control space temperature and relative humidity simultaneously. One strategy controls temperature by varying compressor speed and controls relative humidity by varying evaporator fan speed. The other strategy controls temperature by varying evaporator fan speed and controls relative humidity by varying compressor fan speed The first strategy was successfully implemented experimentally as well as by simulation. The second strategy was not successfully implemented due to an adverse interaction between the two control systems.
Pintado-Herrera, Marina G; Lara-Martín, Pablo A; González-Mazo, Eduardo; Allan, Ian J
2016-09-01
There is a growing interest in assessing the concentration and distribution of new nonregulated organic compounds (emerging contaminants) in the environment. The measurement of freely dissolved concentrations using conventional approaches is challenging because of the low concentrations that may be encountered and their temporally variable emissions. Absorption-based passive sampling enables the estimation of freely dissolved concentrations of hydrophobic contaminants of emerging concern in water. In the present study, calibration was undertaken for 2 polymers, low-density polyethylene (LDPE) and silicone rubber for 11 fragrances, 5 endocrine-disrupting compounds, 7 ultraviolet (UV) filters, and 8 organophosphate flame retardant compounds. Batch experiments were performed to estimate contaminant diffusion coefficients in the polymers (Dp ), which in general decreased with increasing molecular weight. The values for fragrances, endocrine-disrupting compounds, and UV filters were in ranges similar to those previously reported for polycyclic aromatic hydrocarbons, but were 1 order of magnitude lower for organophosphate flame retardant compounds. Silicone rubber had higher Dp values than LDPE and was therefore selected for further experiments to calculate polymer/water partition coefficients (KPW ). The authors observed a positive correlation between log KPW and log octanol/water partition coefficient values. Field testing of silicone rubber passive samplers was undertaken though exposure in the River Alna (Norway) for an exposure time of 21 d to estimate freely dissolved concentration. Some fragrances and UV filters were predominant over other emerging and regulated contaminants, at levels up to 1600 ng L(-1) for galaxolide and 448 ng L(-1) for octocrylene. Environ Toxicol Chem 2016;35:2162-2172. © 2016 SETAC. PMID:26833936
Berthod, Laurence; Roberts, Gary; Whitley, David C; Sharpe, Alan; Mills, Graham A
2014-12-15
The partitioning of pharmaceuticals in the environment can be assessed by measuring their adsorption coefficients (Kd) between aqueous and solid phases. Measuring this coefficient in sewage sludge gives an indication of their partitioning behaviour in a wastewater treatment plant and hence contributes to an understanding of their subsequent fate. The regulatory approved method for measuring Kd in sewage sludge is the US Environmental Protection Agency's Office of Prevention, Pesticides and Toxic Substances (OPPTS) guideline 835.1110, which is labour intensive and time consuming. We describe an alternative method for measuring the Kd of pharmaceuticals in sewage sludge using a modified solid-phase extraction (SPE) technique. SPE cartridges were packed at different sludge/PTFE ratios (0.4, 6.0, 24.0 and 40.0% w/w sludge) and eluted with phosphate buffer at pH 7.4. The approach was tested initially using three pharmaceuticals (clofibric acid, diclofenac and oxytetracycline) that covered a range of Kd values. Subsequently, the sorption behaviour of ten further pharmaceuticals with varying physico-chemical properties was evaluated. Results from the SPE method were comparable to those of the OPPTS test, with a correlation coefficient of 0.93 between the two approaches. SPE cartridges packed with sludge and PTFE were stable for up to one year; use within one month reduced variability in measurements (to a maximum of 0.6 log units). The SPE method is low-cost, easy to use and enables the rapid measurement of Kd values for a large number of chemicals. It can be used as an alternative to the more laborious full OPPTS test in environmental fate studies and risk assessments. PMID:25299795
Berthod, Laurence; Roberts, Gary; Whitley, David C.; Sharpe, Alan; Mills, Graham A.
2014-01-01
The partitioning of pharmaceuticals in the environment can be assessed by measuring their adsorption coefficients (Kd) between aqueous and solid phases. Measuring this coefficient in sewage sludge gives an indication of their partitioning behaviour in a wastewater treatment plant and hence contributes to an understanding of their subsequent fate. The regulatory approved method for measuring Kd in sewage sludge is the US Environmental Protection Agency's Office of Prevention, Pesticides and Toxic Substances (OPPTS) guideline 835.1110, which is labour intensive and time consuming. We describe an alternative method for measuring the Kd of pharmaceuticals in sewage sludge using a modified solid-phase extraction (SPE) technique. SPE cartridges were packed at different sludge/PTFE ratios (0.4, 6.0, 24.0 and 40.0% w/w sludge) and eluted with phosphate buffer at pH 7.4. The approach was tested initially using three pharmaceuticals (clofibric acid, diclofenac and oxytetracycline) that covered a range of Kd values. Subsequently, the sorption behaviour of ten further pharmaceuticals with varying physico-chemical properties was evaluated. Results from the SPE method were comparable to those of the OPPTS test, with a correlation coefficient of 0.93 between the two approaches. SPE cartridges packed with sludge and PTFE were stable for up to one year; use within one month reduced variability in measurements (to a maximum of 0.6 log units). The SPE method is low-cost, easy to use and enables the rapid measurement of Kd values for a large number of chemicals. It can be used as an alternative to the more laborious full OPPTS test in environmental fate studies and risk assessments. PMID:25299795
Quinn, John G
2012-02-15
In label-free biomolecular interaction analysis, a standard injection provides an injection of uniform analyte concentration. An alternative approach exploiting Taylor dispersion produces a continuous analyte titration allowing a full analyte dose response to be recorded in a single injection. The enhanced biophysical characterization that is possible with this new technique is demonstrated using a commercially available surface plasmon resonance-based biosensor. A kinetic interaction model was fitted locally to Taylor dispersion curves for estimation of the analyte diffusion coefficient in addition to affinity/kinetic constants. Statistical confidence in the measured parameters from a single Taylor dispersion injection was comparable to that obtained for global analysis of multiple standard injections. The affinity constants for multisite interactions were resolved with acceptable confidence limits. Importantly, a single analyte injection could be treated as a high-resolution real-time affinity isotherm and was demonstrated using the complex two-site interaction of warfarin with human serum albumin. In all three model interactions tested, the kinetic/affinity constants compared favorably with those obtained from standard kinetic analysis and the estimates of analyte diffusion coefficients were in good agreement with the expected values. PMID:22197422
NASA Astrophysics Data System (ADS)
Bolton, J. S.; Gold, E.
1986-10-01
The authors have previously outlined a transient free field technique, based on cepstral analysis, for the measurement of acoustic reflection coefficients. In this paper are described laboratory acoustical measurements of the normal incidence reflection coefficient of an absorbent material: emphasis is placed on practical aspects of the technique. Specifically, the origin of extraction noise, which distorts the reflector impulse response as it appears in the power cepstrum, is discussed and means of reducing it are described and implemented. Secondly, a means of identifying and removing the time delay introduced when the reflector impulse response is copied from the cepstrum is described; this procedure eliminates the need for highly accurate measurements of path length difference. The absorbent material tested was a commercial partially reticulated polyurethane foam. Bonded to one side of the foam was an impermeable polyurethane membrane, and the foam was measured in two configurations: first with its film covered face uppermost, then with its uncovered face uppermost. The broad frequency range of the measurements made possible by the cepstral technique has given a good picture of the properties of this material. These results will be considered in detail in a subsequent publication.
Demir, D; Un, A; Ozgül, M; Sahin, Y
2008-12-01
Gamma-ray transmission methods have been used accurately for the study of the properties of soil in the agricultural purposes. In this study, photon attenuation coefficient, porosity and field capacity of soil are determined by using gamma-ray transmission method. To this end, the soil sample was collected from Erzurum and a 2 x 2 in NaI (Tl) scintillation detector measured the attenuation of strongly collimated monoenergetic gamma beam through soil sample. The radioactive sources used in the experiment were (241)Am, (133)Ba and (137)Cs. The mass attenuation coefficients of dry soil samples were calculated from the transmission measurements. The soil samples were irrigated by adding known quantities of water and the soil-water properties were examined. It was observed that gamma-ray transmission method for determination of the soil parameters has advantages such as practical, inexpensive, non-destructive and fast analysis. PMID:18554919
NASA Astrophysics Data System (ADS)
Degrelle, D.; Mavon, C.; Groetz, J.-E.
2016-04-01
This study presents a numerical method in order to determine the mass attenuation coefficient of a sample with an unknown chemical composition at low energy. It is compared with two experimental methods: a graphic method and a transmission method. The method proposes to realise a numerical absorption calibration curve to process experimental results. Demineralised water with known mass attenuation coefficient (0.2066cm2g-1 at 59.54 keV) is chosen to confirm the method. 0.1964 ± 0.0350cm2g-1 is the average value determined by the numerical method, that is to say less than 5% relative deviation compared to more than 47% for the experimental methods.
NASA Astrophysics Data System (ADS)
Zhu, Xi-Ming; Cheng, Zhi-Wen; Carbone, Emile; Pu, Yi-Kang; Czarnetzki, Uwe
2016-08-01
Electron-impact excitation processes play an important role in low-temperature plasma physics. Cross section and rate coefficient data for electron-impact processes from the ground state to excited states or between two excited states are required for both diagnostics and modeling works. However, the collisional processes between excited states are much less investigated than the ones involving the ground state due to various experimental challenges. Recently, a method for determining electron excitation rate coefficients between Ar excited states in afterglow plasmas was successfully implemented and further developed to obtain large sets of collisional data. This method combines diagnostics for electron temperature, electron density, and excited species densities and kinetic modeling of excited species, from which the electron excitation rate coefficients from one of the 1s states to the other 1s states or to one of 2p or 3p states are determined (states are in Paschen’s notation). This paper reviews the above method—namely the combined diagnostics and modeling in afterglow plasmas. The results from other important approaches, including electron-beam measurement of cross sections, laser pump-probe technique for measuring rate coefficients, and theoretical calculations by R-matrix and distorted-wave models are also discussed. From a comparative study of these results, a fitted mathematical expression of excitation rate coefficients is obtained for the electron temperature range of 1–5 eV, which can be used for the collisional-radiative modeling of low-temperature Ar plasmas. At last, we report the limitations in the present dataset and give some suggestions for future work in this area.
NASA Astrophysics Data System (ADS)
Howell, D.; Davids, B.; Greene, J. P.; Kanungo, R.; Mythili, S.; Ruiz, C.; Ruprecht, G.; Thompson, I. J.
2013-08-01
We report here a determination of the asymptotic normalization coefficient of the valence neutron in 8Li from a measurement of the angular distribution of the 7Li(8Li,7Li)8Li reaction at 11 MeV. Using isospin symmetry the 8B ANC has also been calculated and used to infer a value for S17(0) of 20.2 ± 4.4 eV b.
2014-03-01
This final rule adopts, without change, the interim final rule with request for comments we published in the Federal Register on September 18, 2013. The interim final rule modified our rules regarding Medicare Part B income-related monthly adjustment amounts to conform to changes made to the Social Security Act (Act) and Internal Revenue Code by the Affordable Care Act. We also removed provisions that phased in income-related monthly adjustment amounts between 2007 and 2009 and updated a citation to reflect the transfer of authority for hearing appeals under title XVIII of the Act from the Social Security Administration to the Department of Health and Human Services. PMID:24611211
Determination of the Rate Coefficients of the SO2 plus O plus M yields SO3 plus M Reaction
NASA Technical Reports Server (NTRS)
Hwang, S. M.; Cooke, J. A.; De Witt, K. J.; Rabinowitz, M. J.
2010-01-01
Rate coefficients of the title reaction R(sub 31) (SO2 +O+M yields SO3 +M) and R(sub 56) (SO2 + HO2 yields SO3 +OH), important in the conversion of S(IV) to S(VI),were obtained at T =970-1150 K and rho (sub ave) = 16.2 micro mol/cubic cm behind reflected shock waves by a perturbation method. Shock-heated H2/ O2/Ar mixtures were perturbed by adding small amounts of SO2 (1%, 2%, and 3%) and the OH temporal profiles were then measured using laser absorption spectroscopy. Reaction rate coefficients were elucidated by matching the characteristic reaction times acquired from the individual experimental absorption profiles via simultaneous optimization of k(sub 31) and k(sub 56) values in the reaction modeling (for satisfactory matches to the observed characteristic times, it was necessary to take into account R(sub 56)). In the experimental conditions of this study, R(sub 31) is in the low-pressure limit. The rate coefficient expressions fitted using the combined data of this study and the previous experimental results are k(sub 31,0)/[Ar] = 2.9 10(exp 35) T(exp ?6.0) exp(?4780 K/T ) + 6.1 10(exp 24) T(exp ?3.0) exp(?1980 K/T ) cm(sup 6) mol(exp ?2)/ s at T = 300-2500 K; k(sub 56) = 1.36 10(exp 11) exp(?3420 K/T ) cm(exp 3)/mol/s at T = 970-1150 K. Computer simulations of typical aircraft engine environments, using the reaction mechanism with the above k(sub 31,0) and k(sub 56) expressions, gave the maximum S(IV) to S(VI) conversion yield of ca. 3.5% and 2.5% for the constant density and constant pressure flow condition, respectively. Moreover, maximum conversions occur at rather higher temperatures (?1200 K) than that where the maximum k(sub 31,0) value is located (approximately 800 K). This is because the conversion yield is dependent upon not only the k(sup 31,0) and k(sup 56) values (production flux) but also the availability of H, O, and HO2 in the system (consumption flux).
Michael F. Gray; Peter Zalupski; Mikael Nilsson
2013-08-01
Effective models for solvent extraction require accurate characterization of the nonideality effects for each component, including the extractants. In this study, the nonideal behavior of the industrial extractant di(2-ethylhexyl) phosphoric acid has been investigated using vapor pressure osmometry (VPO). From the osmometry data, activity coefficients for the HDEHP dimer were obtained based on a formulation of the regular solution theory of Scatchard and Hildebrand, and the Margules two- and three-suffix equations. The results show similarity with a slope-analysis based relation from previous literature, although important differences are highlighted. The work points towards VPO as a useful technique for this type of study, but care must be taken with the choice of standard and method of analysis.
Byrne, J.
2005-01-01
The coefficient a0 has been derived from a measurement of the integral spectrum of recoil protons stored in a quasi-Penning trap with inhomogeneous magnetic field and adiabatic focusing onto an electro-static mirror of potential variable in 10 V steps between 0 V and 850 V. Correction for incomplete transfer of energy from transverse to longitudinal degrees of freedom, and the violation of the adiabatic conditions on reflection at the mirror, is carried out by alternately measuring the spectrum at trapping times of 1 ms and 2 ms. The results a0 = −0.1054 ± 0.0055 and |λ | = 1.271 ± 0.018 are comparable in precision with existing measurements of a0. PMID:27308156
Byrne, J
2005-01-01
The coefficient a 0 has been derived from a measurement of the integral spectrum of recoil protons stored in a quasi-Penning trap with inhomogeneous magnetic field and adiabatic focusing onto an electro-static mirror of potential variable in 10 V steps between 0 V and 850 V. Correction for incomplete transfer of energy from transverse to longitudinal degrees of freedom, and the violation of the adiabatic conditions on reflection at the mirror, is carried out by alternately measuring the spectrum at trapping times of 1 ms and 2 ms. The results a 0 = -0.1054 ± 0.0055 and |λ | = 1.271 ± 0.018 are comparable in precision with existing measurements of a 0. PMID:27308156
NASA Technical Reports Server (NTRS)
Liebert, Curt H.; Ehlers, Robert C.
1961-01-01
Local experimental heat-transfer coefficients were measured in the chamber and throat of a 2400-pound-thrust ammonia-oxygen rocket engine with a nominal chamber pressure of 600 pounds per square inch absolute. Three injector configurations were used. The rocket engine was run over a range of oxidant-fuel ratio and chamber pressure. The injector that achieved the best performance also produced the highest rates of heat flux at design conditions. The heat-transfer data from the best-performing injector agreed well with the simplified equation developed by Bartz at the throat region. A large spread of data was observed for the chamber. This spread was attributed generally to the variations of combustion processes. The spread was least evident, however, with the best-performing injector.
NASA Astrophysics Data System (ADS)
Bekstein, A.; de Urquijo, J.; Ducasse, O.; Rodríguez-Luna, J. C.; Juárez, A. M.
2012-06-01
We present in this paper the interpretation and analysis of transient pulses from a pulsed Townsend experiment by solving the continuity equations of the charged carriers (electrons and ions) involved in the avalanche. The set of second order partial differential equations is solved by SIMAV, a simulator designed specifically for the pulsed Townsend avalanche. Complex situations involving processes such as electron detachment, ion-molecule reactions, Penning ionization and secondary electron emission from ion impact at the cathode, virtually impossible to solve analytically, are discussed here to illustrate the capability of the simulator to help explain the various reaction processes involved in the avalanche, and also to derive some of the transport and reaction coefficients.
Tseng, Y.J.; Huang, S.-C.; Chu, W.C.
2005-04-01
A least-squares error minimization approach was adopted to assess ferric ion diffusion coefficient of Fricke-agarose gels. Ferric ion diffusion process was modeled as a Gaussian-shaped degradation kernel operating on an initial concentration distribution. Diffusion coefficient was iteratively determined by minimizing the error function defined as the difference between the theoretically calculated and the experimentally measured dose distributions. A rapid MR image-based differential gel dosimetry technique that time resolves the evolution of the ferric ion diffusion process minimizes smearing of the dose distribution. Our results showed that for a Fricke-agarose gel contained 1 mM ammonium ferrous sulfate, 1% agarose, 1 mM sodium chloride, and 50 mM sulfuric acid, its ferric ion diffusion coefficient is (1.59{+-}0.28)x10{sup -2} cm{sup 2} h{sup -1} at room temperature. This value falls within the 1.00-2.00x10{sup -2} cm{sup 2} h{sup -1} range previously reported under varying gelling ingredients and concentrations. This method allows a quick, nondestructive evaluation of the ferric ion diffusion coefficient that can be used in conjunction with the in situ gel dosimetry experiment to provide a practical diffusion characterization of the dosimeter gel.