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Sample records for adsorbent recycling system

  1. Molecular adsorbent recycling system (MARS): clinical results of a new membrane-based blood purification system for bioartificial liver support.

    PubMed

    Stange, J; Mitzner, S R; Risler, T; Erley, C M; Lauchart, W; Goehl, H; Klammt, S; Peszynski, P; Freytag, J; Hickstein, H; Löhr, M; Liebe, S; Schareck, W; Hopt, U T; Schmidt, R

    1999-04-01

    The use of xenogenic or genetically engineered cell types in bioartificial liver support systems requires separation methods between the patients' blood and the liver support bioreactors that guarantee the sufficient transfer of pathophysiologically relevant substances but prevent complications. The present paper describes a new membrane separation system that is nearly impermeable to proteins but enables the exchange of water soluble and protein bound toxins by a special membrane and a recycled protein containing dialysate. Because the full range of toxins in hepatic failure has still not been identified, the value of this membrane separation method was evaluated clinically. Thirteen patients suffering from life threatening hepatic failure who had not responded to state of the art therapy were treated with this device, the molecular adsorbent recycling system (MARS). The overall survival rate was 69%. All patients showed positive response to the therapy, indicating that the presented membrane separator combines therapeutic effectivity with the highest safety criteria for the patient by cutting the exchange of substances below the level of proteins. PMID:10226696

  2. An effective and recyclable adsorbent for the removal of heavy metal ions from aqueous system: Magnetic chitosan/cellulose microspheres.

    PubMed

    Luo, Xiaogang; Zeng, Jian; Liu, Shilin; Zhang, Lina

    2015-10-01

    Development of highly cost-effective, highly operation-convenient and highly efficient natural polymer-based adsorbents for their biodegradability and biocompatibility, and supply of safe drinking water are the most threatening problems in water treatment field. To tackle the challenges, a new kind of efficient recyclable magnetic chitosan/cellulose hybrid microspheres was prepared by sol-gel method. By embedding magnetic γ-Fe2O3 nanoparticles in chitosan/cellulose matrix drops in NaOH/urea aqueous solution, it combined renewability and biocompatibility of chitosan and cellulose as well as magnetic properties of γ-Fe2O3 to create a hybrid system in heavy metal ions removal. PMID:26216781

  3. Elution by Le Chatelier's principle for maximum recyclability of adsorbents: applied to polyacrylamidoxime adsorbents for extraction of uranium from seawater.

    PubMed

    Oyola, Yatsandra; Vukovic, Sinisa; Dai, Sheng

    2016-05-28

    Amidoxime-based polymer adsorbents have attracted interest within the last decade due to their high adsorption capacities for uranium and other rare earth metals from seawater. The ocean contains an approximated 4-5 billion tons of uranium and even though amidoxime-based adsorbents have demonstrated the highest uranium adsorption capacities to date, they are still economically impractical because of their limited recyclability. Typically, the adsorbed metals are eluted with a dilute acid solution that not only damages the amidoxime groups (metal adsorption sites), but is also not strong enough to remove the strongly bound vanadium, which decreases the adsorption capacity with each cycle. We resolved this challenge by incorporating Le Chatelier's principle to recycle adsorbents indefinitely. We used a solution with a high concentration of amidoxime-like chelating agents, such as hydroxylamine, to desorb nearly a 100% of adsorbed metals, including vanadium, without damaging the metal adsorption sites and preserving the high adsorption capacity. The method takes advantage of knowing the binding mode between the amidoxime ligand and the metal and mimics it with chelating agents that then in a Le Chatelier's manner removes metals by shifting to a new chemical equilibrium. For this reason the method is applicable to any ligand-metal adsorbent and it will make an impact on other extraction technologies. PMID:27117598

  4. Fuels from Recycling Systems

    ERIC Educational Resources Information Center

    Tillman, David A.

    1975-01-01

    Three systems, operating at sufficient scale, produce fuels that may be alternatives to oil and gas. These three recycling systems are: Black Clawson Fiberclaim, Franklin, Ohio; Union Carbide, South Charleston, West Virginia; and Union Electric, St. Louis, Missouri. These produce a wet fuel, a pyrolytic gas, and a dry fuel, respectively. (BT)

  5. Center-cut separation of intermediately adsorbing target component by 8-zone simulated moving bed chromatography with internal recycle.

    PubMed

    Kiwala, Dawid; Mendrella, Jadwiga; Antos, Dorota; Seidel-Morgenstern, Andreas

    2016-07-01

    An 8-zone simulated moving bed chromatography with internal recycle (8ZSMB-IR) has been designed for center-cut separation, that is, for isolating an intermediately adsorbed component out of a multicomponent mixture. The system consists of two integrated subunits and operates in a fully continuous manner. In the first subunit the feed mixture is split into two fractions containing either a single component or a binary mixture. The binary mixture is recycled through the internal raffinate or extract port into the second subunit, where the target product is isolated. Additionally, the solvent is also recycled internally. For a case study, the separation of a ternary mixture of cycloketones as a model system under weakly non-linear isotherm conditions has been investigated. A few novel configurations of the 8ZSMB-IR unit including the arrangement of the internal recycle of extract, raffinate and solvent streams between two subunits have been examined with respect to various performance indicators for the process realization. The unit performed best with the developed configuration when the internal raffinate stream was recycled and the solvent recycling loop was closed between the last and the first zone of the first subunit. That configuration has further been analyzed experimentally and numerically. On the basis of the results a strategy for determining reliable operating conditions for the 8ZSMB-IR process has been developed. The procedure exploited a model of the process dynamics, which was implemented to refine the isotherm coefficients and to quantify the mixing effect of the liquid stream inside the recycling loops. The upgraded model with the adjusted parameters has been validated based on experimental data and successfully applied for optimizing the operating conditions of the separation. PMID:27260199

  6. Removal and recycle of phosphate from treated water of sewage plants with zirconium ferrite adsorbent by high gradient magnetic separation

    NASA Astrophysics Data System (ADS)

    Ito, D.; Nishimura, K.; Miura, O.

    2009-03-01

    Zirconium ferrite particles are good adsorbent for phosphate ions. Magnetic separation characteristics for removal of phosphate from treated water of sewage plants with the adsorbent have been studied to prevent eutrophication of semi-enclosed bay, e.g. the bay of Tokyo. Based on the adsorption for the phosphate ions and ferromagnetic properties of the zirconium ferrite adsorbent, high gradient magnetic separation characteristics with using superconducting magnet was discussed. Very rapid magnetic filtration velocity, i.e. 1m/s, and regeneration properties of the adsorbent indicate that the zirconium ferrite is the excellent adsorbent for phosphorus removal and recycle from treated water of large scale sewage plants.

  7. Facile preparation of highly hydrophilic, recyclable high-performance polyimide adsorbents for the removal of heavy metal ions.

    PubMed

    Huang, Jieyang; Zheng, Yaxin; Luo, Longbo; Feng, Yan; Zhang, Chaoliang; Wang, Xu; Liu, Xiangyang

    2016-04-01

    To obtain high-performance adsorbents that combine excellent adsorption ability, thermal stability, service life and recycling ability, polyimide (PI)/silica powders were prepared via a facile one-pot coprecipitation process. A benzimidazole unit was introduced into the PI backbone as the adsorption site. The benzimidazole unit induced more hydroxyls onto the silica, which provided hydrophilic sites for access by heavy metal ions. By comprehensively analyzing the effect of hydrophilcity, agglomeration, silica polycondensation, specific surface area and PI crystallinity, 10% was demonstrated to be the most proper feed silica content. The equilibrium adsorption amount (Qe) for Cu(2+) of PI/silica adsorbents was 77 times higher than that of pure PI. Hydrogen chloride (HCl) was used as a desorbent for heavy metal ions and could be decomplexed with benzimidazole unit at around 300°C, which was lower than the glass transition temperature of PI. The complexation and decomplexation process of HCl made PI/silica adsorbents recyclable, and the adsorption ability remained steady for more than 50 recycling processes. As PI/silica adsorbents possess excellent thermal stability, chemical resistance and radiation resistance and hydrophilicity, they have potential as superior recyclable adsorbents for collecting heavy metal ions from waste water in extreme environments. PMID:26736172

  8. Unoccupied electronic states in adsorbate systems

    NASA Astrophysics Data System (ADS)

    Bertel, E.

    1991-11-01

    Experimental work on unoccupied electronic states in adsorbate systems on metallic substrates is reviewed with emphasis on recent developments. The first part is devoted to molecular adsorbates. Weakly chemisorbed hydrocarbons are briefly discussed. An exhaustive inverse photoemission (IPE) study of the CO bond to the transition metals Ni, Pb, and Pt is presented. Adsorbed NO is taken as an example to demonstrate the persisting discrepancies in the interpretation of IPE spectra. Atomic adsorbates are discussed in the second part. The quantum well state model is applied to interpret the surface states in reconstructing and non-reconstructing adsorption systems of alkali metals and hydrogen. A recent controversy on the unoccupied electronic states of the Cu(110)/O p(2×1) surface is critically reviewed. The quantum well state model is then compared to tight binding and local-density-functional calculations of the unoccupied bands and the deficiencies of the various approaches are pointed out. Finally, the relation between the surface state model and more chemically oriented models of surface bonding is briefly discussed.

  9. Orbital tomography for highly symmetric adsorbate systems

    NASA Astrophysics Data System (ADS)

    Stadtmüller, B.; Willenbockel, M.; Reinisch, E. M.; Ules, T.; Bocquet, F. C.; Soubatch, S.; Puschnig, P.; Koller, G.; Ramsey, M. G.; Tautz, F. S.; Kumpf, C.

    2012-10-01

    Orbital tomography is a new and very powerful tool to analyze the angular distribution of a photoemission spectroscopy experiment. It was successfully used for organic adsorbate systems to identify (and consequently deconvolute) the contributions of specific molecular orbitals to the photoemission data. The technique was so far limited to surfaces with low symmetry like fcc(110) oriented surfaces, owing to the small number of rotational domains that occur on such surfaces. In this letter we overcome this limitation and present an orbital tomography study of a 3,4,9,10-perylene-tetra-carboxylic-dianhydride (PTCDA) monolayer film adsorbed on Ag(111). Although this system exhibits twelve differently oriented molecules, the angular resolved photoemission data still allow a meaningful analysis of the different local density of states and reveal different electronic structures for symmetrically inequivalent molecules. We also discuss the precision of the orbital tomography technique in terms of counting statistics and linear regression fitting algorithm. Our results demonstrate that orbital tomography is not limited to low-symmetry surfaces, a finding which makes a broad field of complex adsorbate systems accessible to this powerful technique.

  10. Cost effectiveness of recycling: A systems model

    SciTech Connect

    Tonjes, David J.; Mallikarjun, Sreekanth

    2013-11-15

    Highlights: • Curbside collection of recyclables reduces overall system costs over a range of conditions. • When avoided costs for recyclables are large, even high collection costs are supported. • When avoided costs for recyclables are not great, there are reduced opportunities for savings. • For common waste compositions, maximizing curbside recyclables collection always saves money. - Abstract: Financial analytical models of waste management systems have often found that recycling costs exceed direct benefits, and in order to economically justify recycling activities, externalities such as household expenses or environmental impacts must be invoked. Certain more empirically based studies have also found that recycling is more expensive than disposal. Other work, both through models and surveys, have found differently. Here we present an empirical systems model, largely drawn from a suburban Long Island municipality. The model accounts for changes in distribution of effort as recycling tonnages displace disposal tonnages, and the seven different cases examined all show that curbside collection programs that manage up to between 31% and 37% of the waste stream should result in overall system savings. These savings accrue partially because of assumed cost differences in tip fees for recyclables and disposed wastes, and also because recycling can result in a more efficient, cost-effective collection program. These results imply that increases in recycling are justifiable due to cost-savings alone, not on more difficult to measure factors that may not impact program budgets.

  11. NiO(111) nanosheets as efficient and recyclable adsorbents for dye pollutant removal from wastewater

    NASA Astrophysics Data System (ADS)

    Song, Zhi; Chen, Lifang; Hu, Juncheng; Richards, Ryan

    2009-07-01

    Semiconductor single-crystalline polar NiO(111) nanosheets with well-defined hexagonal holes have been investigated for application in dye adsorption and combustion processes. With regard to adsorption technologies, high surface area metal oxides have an advantage over activated carbon in that the adsorbed species can be combusted and the adsorbent reused in the case of metal oxides while regeneration of activated carbon remains challenging and thus the adsorbent/adsorbate system must be disposed of. Here, three typical textile dyes, reactive brilliant red X-3B, congo red and fuchsin red, were studied for removal from wastewater with two NiO systems and activated carbon. These studies revealed that the NiO(111) nanosheets exhibited much more favorable adsorptive properties than conventionally prepared nickel oxide powder (CP-NiO) obtained from thermal decomposition of nickel nitrate. The maximum adsorption capabilities of the three dyes on NiO(111) nanosheets reached 30.4 mg g-1, 35.15 mg g-1 and 22 mg g-1 for reactive brilliant red X-3B, congo red and fuchsin acid, respectively, while the maximum adsorption capabilities of the three dyes on CP-NiO were only 8.4, 13.2 and 12 mg g-1 for reactive brilliant red X-3B, congo red and fuchsin acid. To simulate the adsorption isotherm, two commonly employed models, the Langmuir and the Freundlich isotherms, were selected to explicate the interaction of the dye and NiO(111). The isotherm evaluations revealed that the Langmuir model demonstrated better fit to experimental equilibrium data than the Freundlich model. The maximum predicted adsorption capacity was 36.1 mg g-1. In addition, adsorption kinetic data of NiO(111) followed a pseudo-second-order rate for congo red. These studies infer that NiO(111) nanosheets possess desirable properties for application in adsorption and combustion applications.

  12. Recycling

    NASA Astrophysics Data System (ADS)

    Goto, Junya; Santorelli, Michael

    Recycling systems are classified into those employing typically three methods, and the progress of each method is described. In mechanical recycling, powders of phenolic materials are recovered via a mechanical process and reused as fillers or additives in virgin materials. The effects to flowability, curability, and mechanical properties of the materials are explained. In feedstock recycling, monomers, oligomers, or oils are recovered via chemical processes and reused as feedstock. Pyrolysis, solvolysis or hydrolysis, and supercritical or subcritical fluid technology will also be introduced. When using a subcritical fluid of phenol, the recycled material maintains excellent properties similar to the virgin material, and a demonstration plant has been constructed to carry out mass production development. In energy recovery, wastes of phenolic materials are used as an alternative solid fuel to coal because they are combustible and have good calorific value. Industrial wastes of these have been in practical use in a cement plant. Finally, it is suggested that the best recycling method should be selected according to the purpose or situation, because every recycling method has both strengths and weaknesses. Therefore, quantitative and objective evaluation methods in recycling are desirable and should be established.

  13. Cost effectiveness of recycling: a systems model.

    PubMed

    Tonjes, David J; Mallikarjun, Sreekanth

    2013-11-01

    Financial analytical models of waste management systems have often found that recycling costs exceed direct benefits, and in order to economically justify recycling activities, externalities such as household expenses or environmental impacts must be invoked. Certain more empirically based studies have also found that recycling is more expensive than disposal. Other work, both through models and surveys, have found differently. Here we present an empirical systems model, largely drawn from a suburban Long Island municipality. The model accounts for changes in distribution of effort as recycling tonnages displace disposal tonnages, and the seven different cases examined all show that curbside collection programs that manage up to between 31% and 37% of the waste stream should result in overall system savings. These savings accrue partially because of assumed cost differences in tip fees for recyclables and disposed wastes, and also because recycling can result in a more efficient, cost-effective collection program. These results imply that increases in recycling are justifiable due to cost-savings alone, not on more difficult to measure factors that may not impact program budgets. PMID:23816311

  14. Recycling of spent adsorbents for oxyanions and heavy metal ions in the production of ceramics.

    PubMed

    Verbinnen, Bram; Block, Chantal; Van Caneghem, Jo; Vandecasteele, Carlo

    2015-11-01

    Spent adsorbents for oxyanion forming elements and heavy metals are classified as hazardous materials and they are typically treated by stabilization/solidification before landfilling. The use of lime or cement for stabilization/solidification entails a high environmental impact and landfilling costs are high. This paper shows that mixing spent adsorbents in the raw material for the production of ceramic materials is a valuable alternative to stabilize oxyanion forming elements and heavy metals. The produced ceramics can be used as construction material, avoiding the high economic and environmental impact of stabilization/solidification followed by landfilling. To study the stabilization of oxyanion forming elements and heavy metals during the production process, two series of experiments were performed. In the first series of experiments, the main pollutant, Mo was adsorbed onto iron-based adsorbents, which were then mixed with industrial sludge (3 w/w%) and heated at 1100°C for 30 min. Mo was chosen, as this element is easily adsorbed onto iron-based adsorbents and it is the element that is the most difficult to stabilize (i.e. the highest temperatures need to be reached before the concentrations in the leachate are reduced). Leaching concentration from the 97/3 sludge/adsorbent mixture before heating ranged between 85 and 154 mg/kg; after the heating process they were reduced to 0.42-1.48 mg/kg. Mo was actually stabilized, as the total Mo concentration after addition was not affected by the heat treatment. In the second series of experiments, the sludge was spiked with other heavy metals and oxyanion forming elements (Cr, Ni, Cu, Zn, As, Cd and Pb) in concentrations 5 times higher than the initial concentrations; after heat treatment the leachate concentrations were below the regulatory limit values. The incorporation of spent adsorbents in ceramic materials is a valuable and sustainable alternative to the existing treatment methods, saving raw materials in the

  15. Novel application of the nonmetallic fraction of the recycled printed circuit boards as a toxic heavy metal adsorbent.

    PubMed

    Hadi, Pejman; Gao, Ping; Barford, John P; McKay, Gordon

    2013-05-15

    Printed circuit boards (PCBs) constitute one of the major sources of toxicity in landfill areas throughout the world. Hence, PCB recycling and separation of its metallic and nonmetallic components has been considered a major ecological breakthrough. Many studies focus on the metallic fraction of the PCBs due to its economic benefits whereas the nonmetallic powder (NMP) has been left isolated. In this work, the feasibility of using NMP as an adsorbent to remove charged toxic heavy metal ions have been studied and its efficiency has been compared with two widely-used commercial adsorbents. The results indicated that the virgin NMP material has no adsorption capacity, while the application of an activation stage to modify the NMP process has a significant effect on its porosity and thus adsorption capacity. The Cu and Pb removal capacity of the activated sample (A-NMP) at a pH level of 4 was 3 mmol and 3.4 mmol per gram of the adsorbent, respectively, which was considerably higher than the commercial ones. PMID:23523907

  16. Recycling.

    ERIC Educational Resources Information Center

    Sinker, Barbara

    1986-01-01

    Discusses the range of benefits resulting from recycling efforts and projects. Presents information and data related to the recycling of metals, cans, paper, fans, and plastics. Suggestions for motivating and involving youth in recycling programs are also offered. (ML)

  17. Recycling of Organic Waste Sludge by Hydrothermal Dry Steam Aiming for Adsorbent

    NASA Astrophysics Data System (ADS)

    Hoshikawa, Hisahiro; Hayakawa, Tomoki; Yamasaki, Nakamichi

    2006-05-01

    Global warming becomes more serious problem today. We have to develop new technology for new energy or fixation of carbon dioxide. Biomass is considered to be one of new energies. Methane fermentation is a method to make methane from biomass, such as garbage and fecal of farm animals, by methane fermentation bacteria. It has a problem, however, that bacteria are deactivated due to ammonia, which is made by itself. And much methane fermentation residue is incinerated. Therefore recycling methane fermentation residue is important for effective use of biomass. We research hydrothermal process. Dry steam means unsaturated vapor, we call. It demands a temperature less than 400 °C. And it is expected to accelerate dehydration effect, decompose and extract the organic matter, and make porous material. Thus, we try to apply the dry steam to recycling of organic waste sludge aiming for absorbent. Experiments were conducted at 250-350 °C in nitrogen atmosphere. The carbon products are analyzed by CHNS elemental analysis, and Thermogravimetry. The extractives are analyzed by gas chromatograph.

  18. Utilization of rice husk ash as novel adsorbent: a judicious recycling of the colloidal agricultural waste.

    PubMed

    Foo, K Y; Hameed, B H

    2009-11-30

    Concern about environmental protection has aroused over the years from a global viewpoint. To date, the ever-increasing importance of biomass as the energy and material resources has lately been accounted by the rising prices for the crude petroleum oil. Rice husk ash, the most appropriate representative of the high ash biomass waste, is currently obtaining sufficient attraction, owning to its wide usefulness and potentiality in environmental conservation. Confirming the assertion, this paper presents a state of the art review of the rice milling industry, its background studies, fundamental properties and industrial applications. Moreover, the key advance on the preparation of novel adsorbents, its major challenges together with the future expectation has been highlighted and discussed. Conclusively, the expanding of rice husk ash in the field of adsorption science represents a viable and powerful tool, leading to the superior improvement of pollution control and environmental preservation. PMID:19836724

  19. Woody biomass production in waste recycling systems

    SciTech Connect

    Rockwood, D.L.; Snyder, G.H.; Sprinkle, R.R.

    1994-12-31

    Combining woody biomass production with waste recycling offers many mutual advantages, including increased tree growth and nutrient and water reclamation. Three biomass/recycling studies collectively involving Eucalyptus amplifolia, E. camaldulensis, and E. grandis, rapidly growing species potentially tolerant of high water and nutrient levels, are (1) evaluating general potential for water/nutrient recycling systems to enhance woody biomass production and to recycle water and nutrients, (2) documenting Eucalyptus growth, water use, and nutrient uptake patterns, and (3) identifying Eucalyptus superior for water and nutrient uptake in central and southern Florida. In a 1992-93 study assessing the three Eucalyptus species planted on the outside berms of sewage effluent holding ponds, position on the berms (top to bottom) and genotypes influenced tree size. The potential of the trees to reduce effluent levels in the ponds was assessed. In a stormwater holding pond planted in 1993, these Eucalyptus genotypes varied significantly for tree size but not for survival. E. camaldulensis appears generally superior when flooded with industrial stormwater. Potential sizes of ponds needed for different stormwater applications were estimated. Prolonged flooding of 4- and 5-year-old E. camaldulensis with agricultural irrigation runoff has had no observable effects on tree growth or survival. Younger E. camaldulensis, E. amplifolia, and E. grandis were assessed for water use and nutrient uptake during a Summer 1994 flooding.

  20. Water recycling system using thermopervaporation method

    NASA Technical Reports Server (NTRS)

    Nitta, K.; Ashida, A.; Mitani, K.; Ebara, K.; Yamada, A.

    1986-01-01

    A water recycling system concept for the crew of the space station is presented. A thermopervaporation method is a new key technology used for the distillation process, utilizing a hydrophobic membrane. An experimental study of thermopervaporation revealed that the permeation depends on the gap between the membrane and the cooling surface in the condensation room: the steam diffusion occurs with gaps less than 5 mm while natural convection becomes dominant with gaps more than 5 mm. A brief discussion of the system operation is also described.

  1. Dynamics and control of recycle systems. 4. Ternary systems with one or two recycle streams

    SciTech Connect

    Tyreus, B.D. ); Luyben, W.L. . Department of Chemical Engineering)

    1993-06-01

    This paper is the fourth in a series of papers that explore the challenging problems associated with the dynamics and control of recycle systems. The reactions considered in previous papers were fairly simple. Only first-order reactions were considered, so there was only one fresh feed stream. In this paper, second-order kinetics are considered with two fresh-feed makeup streams. Two cases are considered: (1) instantaneous and complete one-pass conversion of one of the two components in the reactor so there is an excess of only one component that must be recycled and (2) incomplete conversion per pass so there are two recycle streams. It is shown that the generic liquid-recycle rule proposed by Luyben applies in both of these cases: snowballing is prevented by fixing the flow rate somewhere in the recycle system. An additional generic rule is proposed: fresh feed makeup of any component cannot be fixed unless the component undergoes complete single-pass conversion. In the complete one-pass conversion case, throughput can be set by fixing the flow rate of the limiting reactant. The makeup of the other reactant should be set by level control in the reflux drum of the distillation column. In the incomplete conversion case, two workable schemes were found: (1) Both recycle flow rates are fixed and both fresh-feed makeups are brought in on level control. Throughput is controlled by changing either the reactor temperature or the recycle flow rates. (2) One fresh-feed makeup controls reactor level and the other controls the composition in the reactor. Throughput is controlled by setting reactor temperature or reactor effluent flow rate.

  2. Surface Adsorbate Fluctuations and Noise in Nanoelectromechanical Systems

    PubMed Central

    Yang, Y. T.; Callegari, C.; Feng, X. L.; Roukes, M. L.

    2013-01-01

    Physisorption on solid surfaces is important in both fundamental studies and technology. Adsorbates can also be critical for the performance of miniature electromechanical resonators and sensors. Advances in resonant nanoelectromechanical systems (NEMS), particularly mass sensitivity attaining the single-molecule level, make it possible to probe surface physics in a new regime, where a small number of adatoms cause a detectable frequency shift in a high quality factor (Q) NEMS resonator, and adsorbate fluctuations result in resonance frequency noise. Here we report measurements and analysis of the kinetics and fluctuations of physisorbed xenon (Xe) atoms on a high-Q NEMS resonator vibrating at 190.5 MHz. The measured adsorption spectrum and frequency noise, combined with analytic modeling of surface diffusion and adsorption–desorption processes, suggest that diffusion dominates the observed excess noise. This study also reveals new power laws of frequency noise induced by diffusion, which could be important in other low-dimensional nanoscale systems. PMID:21388120

  3. Precipitation Recycling in the NASA GEOS Data Assimilation System

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Schubert, Siegfried; Molod, Andrea; Takacs, Lawrence L.

    1999-01-01

    Analysis of precipitation recycling can improve the understanding of regional hydrologic anomalies, especially their evolution and maintenance. Diagnostic models of the recycling of precipitation and are applied to 15 years of the NASA Goddard Earth Observing System (GEOS) Data Assimilation System (DAS). Recycled precipitation is defined as the fraction of precipitation within a given region that originated as surface evaporation from the same region. The focus of the present work is on the interannual variability of the central United States hydrologic cycle and precipitation recycling. The extreme years of 1988 (drought) and 1993 (flood) are compared with the 15 year base period mean annual cycle. The results indicate that recycling ratio (the amount of precipitation with a local source relative to the total precipitation) is greater in 1988 than both the base period mean and the 1993 season (with 1993 recycling ratio less than the mean). On the other hand, both the summers of 1988 and 1993 show less total recycled precipitation than the mean. The results also show that precipitation recycling may have been more important in the spring of 1993, when the region was primed for flooding, than the summer, when the sever flooding occurred. The diagnostic approaches to precipitation recycling suffer from some weaknesses. Numerical simulations and assimilation using passive tracers have the potential to provide more accurate calculations of precipitation recycling and the remote sources of water. This ability is being incorporated into the latest GEOS data assimilation system, and some preliminary results will be presented.

  4. Utilization of membranes for H2O recycle system

    NASA Technical Reports Server (NTRS)

    Ohya, H.; Oguchi, M.

    1986-01-01

    Conceptual studies of closed ecological life support systems (CELSS) carried out at NAL in Japan for a water recycle system using membranes are reviewed. The system will treat water from shower room, urine, impure condensation from gas recycle system, and so on. The H2O recycle system is composed of prefilter, ultrafiltration membrane, reverse osmosis membrane, and distillator. Some results are shown for a bullet train of toilet-flushing water recycle equipment with an ultraviltration membrane module. The constant value of the permeation rate with a 4.7 square meters of module is about 70 1/h after 500th of operation. Thermovaporization with porous polytetrafluorocarbon membrane is also proposed to replce the distillator.

  5. TOTAL RECYCLE SYSTEMS FOR PETROCHEMICAL WASTE BRINES CONTAINING REFRACTORY CONTAMINANTS

    EPA Science Inventory

    Petrochemical wastewaters containing relatively high concentrations of salt and refractory organics were selected to study their feasibility for total recycle. A combination of reverse osmosis and electrodialysis was operated as a hybrid system using the pretreated wastes to prod...

  6. Systems for recycling water in poultry processing

    SciTech Connect

    Carawan, R.E.; Sheldon, B.W.

    1988-12-31

    The study was conducted to identify effective and economical water treatments, including disinfection, to meet the U.S. Department of Agriculture`s standards for the recycling of poultry chiller water. Reconditioned chiller water meeting these criteria was used to chill hot broiler carcasses, and the quality of the chilled carcasses was then evaluated.

  7. Challenges in legislation, recycling system and technical system of waste electrical and electronic equipment in China.

    PubMed

    Zhang, Shengen; Ding, Yunji; Liu, Bo; Pan, De'an; Chang, Chein-chi; Volinsky, Alex A

    2015-11-01

    Waste electrical and electronic equipment (WEEE) has been one of the fastest growing waste streams worldwide. Effective and efficient management and treatment of WEEE has become a global problem. As one of the world's largest electronic products manufacturing and consumption countries, China plays a key role in the material life cycle of electrical and electronic equipment. Over the past 20 years, China has made a great effort to improve WEEE recycling. Centered on the legal, recycling and technical systems, this paper reviews the progresses of WEEE recycling in China. An integrated recycling system is proposed to realize WEEE high recycling rate for future WEEE recycling. PMID:26059074

  8. Ferrite insertion at Recycler Flying Wire System

    SciTech Connect

    K.Y. Ng

    2004-02-27

    Ferrite rods are installed inside the flying-wire cavity of the Recycler Ring and at entrance and exit beam pipes in order to absorb high-frequency electromagnetic waves excited by the beam. However, these rods may also deteriorate the vacuum pressure of the ring. An investigation is made to analyze the necessity of the ferrite rods at the entrance and exit beam pipes.

  9. Oxygen Photochemistry on TiO2(110): Recyclable, Photoactive Oxygen Produced by Annealing Adsorbed O2

    SciTech Connect

    Petrik, Nikolay G.; Kimmel, Gregory A.

    2011-11-03

    Photon-stimulated reactions between chemisorbed and physisorbed oxygen on TiO2(110) are investigated. Experiments using O2 isotopologues show that UV irradiation results in the exchange of atoms between chemisorbed and physisorbed oxygen. Annealing chemisorbed oxygen to {approx}350 K maximizes these exchange reactions, while dissociatively adsorbing oxygen on TiO2(110) at 300 - 350 K does not lead to reactions with physisorbed O2. After annealing to 350 K, the exchange products photodesorb in the plane perpendicular to the bridge-bonded oxygen rows at an angle of 45{sup o}. In contrast, the chemisorbed O2 photodesorbs normal to the surface. Remarkably, the chemisorbed species is stable under multiple cycles of UV irradiation with physisorbed O2. The active atoms in the chemisorbed species can be changed from 18O to 16O and then back to 18O via the exchange reactions. The results show that annealing oxygen adsorbed on TiO2(110) to {approx}350 K produces a stable chemical species with interesting photochemical properties. Possible forms for the photoactive species include O2 adsorbed in a bridging oxygen vacancy or tetraoxygen.

  10. Recycling endosomes

    PubMed Central

    Goldenring, James R

    2015-01-01

    The endosomal membrane recycling system represents a dynamic conduit for sorting and re-exporting internalized membrane constituents. The recycling system is composed of multiple tubulovesicular recycling pathways that likely confer distinct trafficking pathways for individual cargoes. In addition, elements of the recycling system are responsible for assembly and maintenance of apical membrane specializations including primary cilia and apical microvilli. The existence of multiple intersecting and diverging recycling tracks likely accounts for specificity in plasma membrane recycling trafficking. PMID:26022676

  11. Recycling, Inc.

    ERIC Educational Resources Information Center

    Martin, Amy

    1992-01-01

    Suggestions for creating a successful office recycling system are enumerated from start up plans to waste reduction and paper recycling. Contact information for recycling equipment, potential buyers of recycled materials, recycled products for purchase, and ideas for promotion and education of staff are included. (MCO)

  12. Cryogenic adsorber design in a helium refrigeration system

    NASA Astrophysics Data System (ADS)

    Hu, Zhongjun; Zhang, Ning; Li, Zhengyu; Li, Q.

    2012-06-01

    The cryogenic adsorber is specially designed to eliminate impurities in gaseous helium such as O2, and N2 which is normally difficult to remove, based on the reversible cryotrapping of impurities on an activated carbon bed. The coconut shell activated carbon is adopted because of its developed micropore structure and specific surface area. This activated carbon adsorption is mostly determined by the micropore structure, and the adsorption rate of impurities is inversely proportional to the square of the particle sizes. The active carbon absorber's maximum permissible flow velocity is 0.25 m/s. When the gas flow velocity increases, the adsorption diffusion rate of the adsorbent is reduced, because an increase in the magnitude of the velocity resulted in a reduced amount of heat transfer to a unit volume of impure gas. According to the numerical simulation of N2 adsorption dynamics, the appropriate void tower link speed and the saturated adsorption capacity are determined. Then the diameter and height of the adsorber are designed. The mass transfer length should be taken into account in the adsorber height design. The pressure decrease is also calculated. The important factors that influence the adsorber pressure decrease are the void tower speed, the adsorbed layer height, and the active carbon particle shape and size.

  13. Utilization of recycled charcoal as a thermal source and adsorbent for the treatment of PCDD/Fs contaminated sediment.

    PubMed

    Zhao, Long; Hou, Hong; Iwasaki, Kanae; Terada, Akihiko; Hosomi, Masaaki

    2012-07-30

    A novel heat treatment process in which charcoal was used as both a thermal source and an adsorbent was investigated as a low-cost method for removal of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from solids. Three laboratory scale experiments involving various ratios of charcoal to contaminated sediment and air superficial velocities were performed. The results indicated that the total and toxic equivalency quantities (TEQ) concentrations of PCDD/Fs decreased significantly in the treated sediment of all runs with removal efficiencies greater than 96% and 90%, which resulted in residual concentrations below the Japanese standard limit of 0.15ng-TEQg(-1). The charcoal/contaminated sediment ratio and air superficial velocity were determinant factors controlling the PCDD/Fs concentrations and homologue profiles in effluent. As the air superficial velocity increased and charcoal/contaminated sediment ratio decreased, more PCDD/Fs were released from the sediment as fly ash, making them less likely to remain in the treated sediment. These phenomena were likely a result of the vapor pressure of PCDD/Fs, contact time with effluent gas and amount of PCDD/Fs adsorbed by charcoal. The developed process would promise an alternative to a conventional remediation process for PCDD/Fs contaminated solids. PMID:22633545

  14. The collection system for residential recyclables in communities in Haidian District, Beijing: a possible approach for China recycling.

    PubMed

    Wang, Jia; Han, Ling; Li, Shushu

    2008-01-01

    Recycling and reusing recyclables is an important way to solve the municipal solid waste (MSW) problem. As the collection of solid waste takes up the largest percentage of MSW management budgets, improving the collection of recyclables is important. Since the decline of government-run waste buying depots in the late 1980s, the collection of recyclables from households and waste deposit sites in China is done by buyers with small informal bases and waste pickers, who are usually unskilled rural people who have come to the cities. Because of this, the current system is seen to have social problems. So, the recyclable collection system has both social as well as economic significance. China is in the process of rapid industrialization and urbanization, and a new mode of community collection system is emerging. It operates by market mechanisms, with waste collection companies that are supported by the municipal government, establishing recycle service sites, and employing workers to buy recyclables door-to-door. This paper is a case study of the new system in the Haidian District, Beijing. It summarizes the system, compares it to experiences in other countries and discusses whether the new approach contributes to resources recycling in China. PMID:17967528

  15. Interface problems between material recycling systems and plants.

    PubMed

    Nitta, K; Oguchi, M; Otsubo, K

    1992-01-01

    A most important problem to creating a CELSS system to be used in space, for example, for a Lunar Base or Manned Mars mission, seems to be how to design and operate the various material recycling systems to be used on the missions. Recent studies of a Lunar Base habitat have identified examples of CELSS configurations to be used for the Plant Cultivation Module. Material recycling subsystems to be installed in the Plant Cultivation Modules are proposed to consist of various sub-systems, such as dehumidifiers, oxygen separation systems, catalytic wet oxidation systems, nitrogen adjusting systems, including tanks, and so on. The required performances of such various material recycling subsystems are determined based on precise metabolic data of derived from the various species of plants to be selected and investigated. The plant metabolic data, except that for wheat and potato, has not been fully collected at the present time. Therefore, much additional plant cultivation data is required to determine the performances of each material recycling subsystem introduced in Plant Cultivation Modules. PMID:11537056

  16. Dynamic Systems Analysis Report for Nuclear Fuel Recycle

    SciTech Connect

    Brent Dixon; Sonny Kim; David Shropshire; Steven Piet; Gretchen Matthern; Bill Halsey

    2008-12-01

    This report examines the time-dependent dynamics of transitioning from the current United States (U.S.) nuclear fuel cycle where used nuclear fuel is disposed in a repository to a closed fuel cycle where the used fuel is recycled and only fission products and waste are disposed. The report is intended to help inform policy developers, decision makers, and program managers of system-level options and constraints as they guide the formulation and implementation of advanced fuel cycle development and demonstration efforts and move toward deployment of nuclear fuel recycling infrastructure.

  17. Ammonia recycling enables sustainable operation of bioelectrochemical systems.

    PubMed

    Cheng, Ka Yu; Kaksonen, Anna H; Cord-Ruwisch, Ralf

    2013-09-01

    Ammonium (NH4(+)) migration across a cation exchange membrane is commonly observed during the operation of bioelectrochemical systems (BES). This often leads to anolyte acidification (pH <5.5) and complete inactivation of biofilm electroactivity. Without using conventional pH controls (dosage of alkali or pH buffers), the present study revealed that anodic biofilm activity (current) could be sustained if recycling of ammonia (NH3) was implemented. A simple gas-exchange apparatus was designed to enable continuous recycling of NH3 (released from the catholyte at pH >10) from the cathodic headspace to the acidified anolyte. Results indicated that current (110 mA or 688 Am(-3) net anodic chamber volume) was sustained as long as the NH3 recycling path was enabled, facilitating continuous anolyte neutralization with the recycled NH3. Since the microbial current enabled NH4(+) migration against a strong concentration gradient (~10-fold), a novel way of ammonia recovery from wastewaters could be envisaged. PMID:23774293

  18. Study on CO2 global recycling system.

    PubMed

    Takeuchi, M; Sakamoto, Y; Niwa, S

    2001-09-28

    In order to assist in finding ways to mitigate CO2 emission and to slow the depletion of fossil fuels we have established and evaluated a representative system, which consists of three technologies developed in our laboratory. These technologies were in CO2 recovery, hydrogen production and methanol synthesis and in addition we established the necessary supporting systems. Analysis of outline designs of the large scale renewable energy power generation system and this system and energy input for building plant, energy input for running plant has been conducted based on a case using this system for a 1000-MW coal fired power plant, followed by an evaluation of the material balance and energy balance. The results are as follows. Energy efficiency is 34%, the CO2 reduction rate is 41%, the balance ratio of the energy and CO2 of the system is 2.2 and 1.8, respectively, on the assumption that the primary renewable energy is solar thermal power generation, the stationary CO2 emission source is a coal-fired power plant and the generation efficiency of the methanol power plant is 60%. By adopting the system, 3.7 million tons of CO2 can be recovered, approximately 2.7 million tons of methanol can be produced, and 15.4 billion kWh of electricity can be generated per year. Compared to generating all electrical power using only coal, approximately 2.6 million tons of coal per year can be saved and approximately 2.15 million tons of CO2 emission can be reduced. Therefore, it is clearly revealed that this system would be effective to reduce CO2 emissions and to utilize renewable energy. PMID:11589395

  19. Choosing among alternative recycling systems: An economic analysis

    SciTech Connect

    Stedge, G.D. . Dept. of Agricultural and Applied Economics); Halstead, J.M. . Dept. of Resource Economics and Development)

    1994-03-01

    Due to the increasing concern over the disposal of municipal solid waste, municipalities have begun searching for ways to recycle a larger percentage to their waste stream at a reasonable cost. This report examines bag-based recycling. This system, due to its efficient collection and separation method, and its convenience, should be able to capture a larger share of the waste stream at a lower cost per metric ton than conventional recycling programs. Using a case study approach, a bag-based program is compared with a curbside-sort program and a drop-off program. Using time/motion analysis, a garbage composition study, a household survey, and the recording of set-out rates of a sample of dwelling units, the efficiency of the three programs was defined and estimated. The efficiency of the bag-based system was also estimated for three areas with distinct household densities. Although the curbside-sort program was found to divert a larger percentage of the residential waste stream than the bag-based system, the cost per metric ton of the bag-based system is so much lower that it clearly is the most efficient of the three programs. The drop-off program had a very low cost per metric ton; however, if failed to divert the minimum acceptable level of the waste stream. The bag-based system proved to be more efficient in areas with higher household densities.

  20. System and method for recycling used oil filters

    SciTech Connect

    McCarty, M.W.; Taylor, J.M.; Baillie, L.A.

    1993-08-17

    A system is described for recycling oil filters comprising: (a) means for shredding used oil filters, said filters comprising ferrous metal parts and nonmetal parts, and containing trapped oil, into smaller metal parts and nonmetal parts, and for releasing at least a portion of the trapped oil; (b) means for separating the released oil from the metal parts and nonmetal parts; (c) means for separating the metal parts from the nonmetal parts without incineration using gravitational and magnetic means; (d) means for draining oil from the separated metal parts and nonmetal parts; (e) means for separately recovering the oil, the metal parts, and the nonmetal parts; and (f) means for compacting the separated nonmetal parts. A method is also described for recycling used oil filters using this system.

  1. Palladium Nanoparticle-Loaded Cellulose Paper: A Highly Efficient, Robust, and Recyclable Self-Assembled Composite Catalytic System.

    PubMed

    Zheng, Guangchao; Kaefer, Katharina; Mourdikoudis, Stefanos; Polavarapu, Lakshminarayana; Vaz, Belén; Cartmell, Samantha E; Bouleghlimat, Azzedine; Buurma, Niklaas J; Yate, Luis; de Lera, Ángel R; Liz-Marzán, Luis M; Pastoriza-Santos, Isabel; Pérez-Juste, Jorge

    2015-01-15

    We present a novel strategy based on the immobilization of palladium nanoparticles (Pd NPs) on filter paper for development of a catalytic system with high efficiency and recyclability. Oleylamine-capped Pd nanoparticles, dispersed in an organic solvent, strongly adsorb on cellulose filter paper, which shows a great ability to wick fluids due to its microfiber structure. Strong van der Waals forces and hydrophobic interactions between the particles and the substrate lead to nanoparticle immobilization, with no desorption upon further immersion in any solvent. The prepared Pd NP-loaded paper substrates were tested for several model reactions such as the oxidative homocoupling of arylboronic acids, the Suzuki cross-coupling reaction, and nitro-to-amine reduction, and they display efficient catalytic activity and excellent recyclability and reusability. This approach of using NP-loaded paper substrates as reusable catalysts is expected to open doors for new types of catalytic support for practical applications. PMID:26263455

  2. Copper Cable Recycling System - The INEEL LSDDP Demonstration Project

    SciTech Connect

    Conner, Craig C; Meservey, Richard Harlan; Rosenberger, S.

    2001-02-01

    The United States Department of Energy (DOE) continually seeks safer and more cost-effective technologies for the deactivation and decommissioning (D&D) of nuclear facilities. The Deactivation and Decommissioning Focus Area (DDFA) and the DOE’s office of Science and Technology (OST) sponsors Large Scale Demonstration and Deployment Projects (LSDDPs). The increasing number of deactivation and decommissioning (D&D) activities at nuclear facilities can generate hundreds of tons of cables per facility consuming valuable resources such as disposal space and copper. Driven by increasing environmental concerns as well as economical pressures there is a developing need for the recycling of the uncontaminated copper. As part of the LSDDP program the NUKEM Copper Cable Recycling System (CCRS) was demonstrated November 1999 at the Idaho National Engineering and Environmental Laboratory (INEEL). This process allows recovering and recycling the uncontaminated copper contained in surface contaminated cables. The NUKEM CCRS was originally developed in Germany for the use during the D&D of commercial power plants. Up to date the CCRS has successfully processed in Germany more than 200 metric tons of contaminated cables resulting in virtually 100% free release of copper under the German standards. A total of 13.5 tons non and surrogate contaminated cables in a wide variety of sizes were successfully processed during the technology demonstration at INEEL. The assessment has demonstrated the mobility and flexibility of this new process.

  3. Carbon recycling in materially closed ecological life support systems

    NASA Technical Reports Server (NTRS)

    Obenhuber, D. C.; Folsome, C. E.

    1988-01-01

    Results of studies are presented of materially closed energetically open microbial ecosystems or 'closed ecosystems'. These are natural marine ecosystems that have been sealed in glass containers to prevent material exchange with the environment but allow energy to pass freely through them. They represent model life support systems for the future human habitation of space. The results are discussed analytically and indicate that these ecosystems, when subjected to a constant energy flux, seem to be reliable and self-sufficient systems for recycling of biologically produced carbon compounds.

  4. Gas and water recycling system for IOC vivarium experiments

    NASA Technical Reports Server (NTRS)

    Nitta, K.; Otsubo, K.

    1986-01-01

    Water and gas recycling units designed as one of the common experiment support system for the life science experiment facilities used in the Japanese Experiment Module are discussed. These units will save transportation and operation costs for the life science experiments in the space station. These units are also designed to have interfaces so simple that the connection to another life science experiment facilities such as the Research Animal Holding Facility developed by the Rockheed Missiles and Space Company can be easily done with small modification.

  5. EVALUATION OF THE MIDDAS SYSTEM FOR DESIGNING GAC ADSORBERS

    EPA Science Inventory

    The Micro-Diameter-Depth Adsorption System (MIDDAS) was evaluated for its usefulness in determining equilibrium parameters for adsorption in granular activated carbon (GAC) systems. The system employs a column configuration for determining such parameters, rather than the traditi...

  6. Binary chromatographic data and estimation of adsorbent porosities. [data for system n-heptane/n-pentane

    NASA Technical Reports Server (NTRS)

    Meisch, A. J.

    1972-01-01

    Data for the system n-pentane/n-heptane on porous Chromosorb-102 adsorbent were obtained at 150, 175, and 200 C for mixtures containing zero to 100% n-pentane by weight. Prior results showing limitations on superposition of pure component data to predict multicomponent chromatograms were verified. The thermodynamic parameter MR0 was found to be a linear function of sample composition. A nonporous adsorbent failed to separate the system because of large input sample dispersions. A proposed automated data processing scheme involving magnetic tape recording of the detector signals and processing by a minicomputer was rejected because of resolution limitations of the available a/d converters. Preliminary data on porosity and pore size distributions of the adsorbents were obtained.

  7. CELSS experiment model and design concept of gas recycle system

    NASA Technical Reports Server (NTRS)

    Nitta, K.; Oguchi, M.; Kanda, S.

    1986-01-01

    In order to prolong the duration of manned missions around the Earth and to expand the human existing region from the Earth to other planets such as a Lunar Base or a manned Mars flight mission, the controlled ecological life support system (CELSS) becomes an essential factor of the future technology to be developed through utilization of space station. The preliminary system engineering and integration efforts regarding CELSS have been carried out by the Japanese CELSS concept study group for clarifying the feasibility of hardware development for Space station experiments and for getting the time phased mission sets after FY 1992. The results of these studies are briefly summarized and the design and utilization methods of a Gas Recycle System for CELSS experiments are discussed.

  8. The development and prospects of the end-of-life vehicle recycling system in Taiwan.

    PubMed

    Chen, Kuan-chung; Huang, Shih-han; Lian, I-wei

    2010-01-01

    Automobiles usually contain toxic substances, such as lubricants, acid solutions and coolants. Therefore, inappropriate handling of end-of-life vehicles (ELVs) will result in environmental pollution. ELV parts, which include metallic and non-metallic substances, are increasingly gaining recycling value due to the recent global shortage of raw materials. Hence, the establishment of a proper recycling system for ELVs will not only reduce the impact on the environment during the recycling process, but it will also facilitate the effective reuse of recycled resources. Prior to 1994, the recycling of ELVs in Taiwan was performed by related operators in the industry. Since the publishing of the "End-of-life vehicle recycling guidelines" under the authority of the Waste Disposal Act by the Environmental Protection Administration (EPA) in 1994, the recycling of ELVs in Taiwan has gradually become systematic. Subsequently, the Recycling Fund Management Board (RFMB) of the EPA was established in 1998 to collect a Collection-Disposal-Treatment Fee (recycling fee) from responsible enterprises for recycling and related tasks. Since then, the recycling channels, processing equipment, and techniques for ELVs in Taiwan have gradually become established. This paper reviews the establishment of the ELV recycling system, analyzes the current system and its performance, and provides some recommendations for future development. The reduction of auto shredder residue (ASR) is a key factor in maximizing the resource recovery rate and recycling efficiency. The RFMB needs to provide strong economic incentives to further increase the recycling rate and to encourage the automobile industry to design and market greener cars. PMID:20382516

  9. Waste collection systems for recyclables: An environmental and economic assessment for the municipality of Aarhus (Denmark)

    SciTech Connect

    Larsen, A.W.; Merrild, H.; Moller, J.; Christensen, T.H.

    2010-05-15

    Recycling of paper and glass from household waste is an integrated part of waste management in Denmark, however, increased recycling is a legislative target. The questions are: how much more can the recycling rate be increased through improvements of collection schemes when organisational and technical limitations are respected, and what will the environmental and economic consequences be? This was investigated in a case study of a municipal waste management system. Five scenarios with alternative collection systems for recyclables (paper, glass, metal and plastic packaging) were assessed by means of a life cycle assessment and an assessment of the municipality's costs. Kerbside collection would provide the highest recycling rate, 31% compared to 25% in the baseline scenario, but bring schemes with drop-off containers would also be a reasonable solution. Collection of recyclables at recycling centres was not recommendable because the recycling rate would decrease to 20%. In general, the results showed that enhancing recycling and avoiding incineration was recommendable because the environmental performance was improved in several impact categories. The municipal costs for collection and treatment of waste were reduced with increasing recycling, mainly because the high cost for incineration was avoided. However, solutions for mitigation of air pollution caused by increased collection and transport should be sought.

  10. The consumption and recycling collection system of PET bottles: a case study of Beijing, China.

    PubMed

    Zhang, Hua; Wen, Zong-Guo

    2014-06-01

    After studying the recycling collection system of polyethylene terephthalate (PET) bottles worldwide, the authors conducted an intercept survey in Beijing. Two separate questionnaires were issued, one questionnaire to PET bottle consumers and one to PET bottle recyclers. In this study, consumers are defined as people that consume PET-bottled beverages in their daily life. Recyclers were defined as those involved in the collection and recycling of PET bottles. These include scavengers, itinerant waste buyers, small community waste-buying depots, medium/large redemption depots, and recycling companies. In total, 580 surveys were completed, including 461 by consumers and 119 by recyclers. The authors found that consumption of PET bottles in Beijing was nearly 100,000 tonnes in 2012. Age, occupation, gender, and education were identified as significant factors linked to PET-bottled beverage consumption, while income was not a significant factor. 90% Of post-consumed PET bottles were collected by informal collectors (i.e., scavengers and itinerant waste buyers). The survey also found that nearly all PET bottles were reprocessed by small factories that were not designed with pollution control equipment, which allows them to offer higher prices for waste recyclable bottles. As Beijing is trying to build a formal recycling collection system for recyclables, subsidies should be given to the formal recycling sector rather than being charged land use fees, and attention should also be given to informal recyclers that make their living from the collection of recyclables. Informal and formal sectors may work together by employing the scavengers and itinerant waste buyers for the formal sectors. In addition to the recycling of PET bottles, concern should also be allocated to reduce consumption, especially among young people, as they, compared to other groups, have a stronger demand for PET-bottled beverages and will be the main body of society. PMID:23948054

  11. A thermal energy storage system for adsorbent low-pressure natural gas storage

    SciTech Connect

    Blazek, C.F.; Jasionowski, W.J.; Kountz, K.J.; Tiller, A.J.; Gauthier, S.W.; Takagishi, S.K.

    1992-12-31

    Carbon-based adsorbents were determined to be the best enhanced storage media that would store more natural gas at low pressures than achieved with compression only. Thermal energy storage (TES) was previously demonstrated to be a potentially promising technique to mitigate heat effects associated with low-pressure carbon adsorption systems for natural gas storage. Further investigations were conducted to develop information for the design of an optimized adsorption system that incorporates TES heat management. The selection of appropriate phase-change materials and nucleating agents, encapsulant materials, and corrosion inhibitors for a TES heat management system are discussed and the results of extended thermal cyclic behavior are presented. Engineering analyses and finite element analyses are employed to calculate adsorption rates, heat generation, temperatures, and heat transfer within the adsorbent bed. The size, volume, and arrangement of components for an operational TES system designed to accommodate fast-fill within a defined time limit is presented.

  12. A thermal energy storage system for adsorbent low-pressure natural gas storage

    SciTech Connect

    Blazek, C.F.; Jasionowski, W.J.; Kountz, K.J.; Tiller, A.J. ); Gauthier, S.W.; Takagishi, S.K. )

    1992-01-01

    Carbon-based adsorbents were determined to be the best enhanced storage media that would store more natural gas at low pressures than achieved with compression only. Thermal energy storage (TES) was previously demonstrated to be a potentially promising technique to mitigate heat effects associated with low-pressure carbon adsorption systems for natural gas storage. Further investigations were conducted to develop information for the design of an optimized adsorption system that incorporates TES heat management. The selection of appropriate phase-change materials and nucleating agents, encapsulant materials, and corrosion inhibitors for a TES heat management system are discussed and the results of extended thermal cyclic behavior are presented. Engineering analyses and finite element analyses are employed to calculate adsorption rates, heat generation, temperatures, and heat transfer within the adsorbent bed. The size, volume, and arrangement of components for an operational TES system designed to accommodate fast-fill within a defined time limit is presented.

  13. Water Quality Benefits of Constructed Wetlands Integrated Within Agricultural Water Recycling Systems

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Constructed wetlands have been integrated within innovative agricultural water recycling systems, and these systems are now being evaluated at three demonstration sites located in the northwest Ohio portion of the Maumee River Basin (Defiance, Fulton, and Van Wert Counties). The water recycling syst...

  14. Recycling Frank: Spontaneous emergence of homochirality in noncatalytic systems

    PubMed Central

    Plasson, Raphaël; Bersini, Hugues; Commeyras, Auguste

    2004-01-01

    In this work, we introduce a prebiotically relevant protometabolic pattern corresponding to an engine of deracemization by using an external energy source. The spontaneous formation of a nonracemic mixture of chiral compounds can be observed in out-of-equilibrium systems via a symmetry-breaking phenomenon. This observation is possible thanks to chirally selective autocatalytic reactions (Frank's model) [Frank, F. C. (1953) Biochim. Biophys. Acta 11, 459–463]. We show that the use of a Frank-like model in a recycled system composed of reversible chemical reactions, rather than the classical irreversible system, allows for the emergence of a synergetic autoinduction from simple reactions, without any autocatalytic or even catalytic reaction. This model is described as a theoretical framework, based on the stereoselective reactivity of preexisting chiral monomeric building blocks (polymerization, epimerization, and depolymerization) maintained out of equilibrium by a continuous energy income, via an activation reaction. It permits the self-conversion of all monomeric subunits into a single chiral configuration. Real prebiotic systems of amino acid derivatives can be described on this basis. They are shown to be able to spontaneously reach a stable nonracemic state in a few centuries. In such systems, the presence of epimerization reactions is no more destructive, but in contrast is the central driving force of the unstabilization of the racemic state. PMID:15548617

  15. A double network gel as low cost and easy recycle adsorbent: Highly efficient removal of Cd(II) and Pb(II) pollutants from wastewater.

    PubMed

    Chu, Lin; Liu, Chengbin; Zhou, Guiyin; Xu, Rui; Tang, Yanhong; Zeng, Zebing; Luo, Shenglian

    2015-12-30

    A high strength of polyving alcohol/polyacrylic acid double network gel (PVA/PAA gel) adsorbent was successfully prepared by a simple two-step method in this study. The gel adsorbent possessed the advantages of low cost and high adsorptivity for heavy metals in solution. The maximum uptake capacities of PVA/PAA gel were 194.99 mg/g for Pb(II) and 115.88 mg/g for Cd(II) inferred from the Langmuir model at 303 K. At the concentration levels of Pb(II)<150 mg/L and Cd(II)<100mg/L, the Pb(II) and Cd(II) could be completely adsorbed, showing a great potential of removing heavy metals from wastewater. Simultaneously, the PVA/PAA gel adsorbent exhibited an excellent reusability. Even in the fifth cycle, the removal efficiencies of both Pb(II) and Cd(II) remained nearly 100%. Significantly, the gel adsorbent displayed a satisfactory performance of removing heavy metals in actual industrial effluent. The results reveal that the double network gel can be considered as a potential candidate for practical application. PMID:26177491

  16. Occurrence and Control of Legionella in Recycled Water Systems

    PubMed Central

    Jjemba, Patrick K.; Johnson, William; Bukhari, Zia; LeChevallier, Mark W.

    2015-01-01

    Legionella pneumophila is on the United States Environmental Protection Agency (USEPA) Candidate Contaminant list (CCL) as an important pathogen. It is commonly encountered in recycled water and is typically associated with amoeba, notably Naegleria fowleri (also on the CCL) and Acanthamoeba sp. No legionellosis outbreak has been linked to recycled water and it is important for the industry to proactively keep things that way. A review was conducted examine the occurrence of Legionella and its protozoa symbionts in recycled water with the aim of developing a risk management strategy. The review considered the intricate ecological relationships between Legionella and protozoa, methods for detecting both symbionts, and the efficacy of various disinfectants. PMID:26140674

  17. Occurrence and Control of Legionella in Recycled Water Systems.

    PubMed

    Jjemba, Patrick K; Johnson, William; Bukhari, Zia; LeChevallier, Mark W

    2015-01-01

    Legionella pneumophila is on the United States Environmental Protection Agency (USEPA) Candidate Contaminant list (CCL) as an important pathogen. It is commonly encountered in recycled water and is typically associated with amoeba, notably Naegleria fowleri (also on the CCL) and Acanthamoeba sp. No legionellosis outbreak has been linked to recycled water and it is important for the industry to proactively keep things that way. A review was conducted examine the occurrence of Legionella and its protozoa symbionts in recycled water with the aim of developing a risk management strategy. The review considered the intricate ecological relationships between Legionella and protozoa, methods for detecting both symbionts, and the efficacy of various disinfectants. PMID:26140674

  18. Assessment of Food Waste Prevention and Recycling Strategies Using a Multilayer Systems Approach.

    PubMed

    Hamilton, Helen A; Peverill, M Samantha; Müller, Daniel B; Brattebø, Helge

    2015-12-15

    Food waste (FW) generates large upstream and downstream emissions to the environment and unnecessarily consumes natural resources, potentially affecting future food security. The ecological impacts of FW can be addressed by the upstream strategies of FW prevention or by downstream strategies of FW recycling, including energy and nutrient recovery. While FW recycling is often prioritized in practice, the ecological implications of the two strategies remain poorly understood from a quantitative systems perspective. Here, we develop a multilayer systems framework and scenarios to quantify the implications of food waste strategies on national biomass, energy, and phosphorus (P) cycles, using Norway as a case study. We found that (i) avoidable food waste in Norway accounts for 17% of sold food; (ii) 10% of the avoidable food waste occurs at the consumption stage, while industry and retailers account for only 7%; (iii) the theoretical potential for systems-wide net process energy savings is 16% for FW prevention and 8% for FW recycling; (iv) the theoretical potential for systems-wide P savings is 21% for FW prevention and 9% for FW recycling; (v) while FW recycling results in exclusively domestic nutrient and energy savings, FW prevention leads to domestic and international savings due to large food imports; (vi) most effective is a combination of prevention and recycling, however, FW prevention reduces the potential for FW recycling and therefore needs to be prioritized to avoid potential overcapacities for FW recycling. PMID:26496178

  19. A financing system for battery recycling in Switzerland

    NASA Astrophysics Data System (ADS)

    Jordi, Hanspeter

    The household battery recycling procedures presently in progress in Switzerland are illustrated. Particular attention is devoted to the description of the country's organizations for providing an efficient battery disposal plan. The financial aspects of this plan are also outlined.

  20. A new optional recycled water pre-treatment system prior to use in the household laundry.

    PubMed

    Chen, Zhuo; Ngo, Huu Hao; Guo, Wenshan; Pham, Thi Thu Nga; Lim, Richard; Wang, Xiaochang C; Miechel, Clayton; Halloran, Kelly O'; Listowski, Andrzej; Corby, Nigel

    2014-04-01

    With a constantly growing population, water scarcity becomes the limiting factor for further social and economic growth. To achieve a partial reduction in current freshwater demands and lessen the environmental loadings, an increasing trend in the water market tends to adopt recycled water for household laundries as a new recycled water application. The installation of a small pre-treatment unit for water purification can not only further improve the recycled water quality, but also be viable to enhance the public confidence and acceptance level on recycled water consumption. Specifically, this paper describes column experiments conducted using a 550 mm length bed of zeolite media as a one-dimensional flow reactor. The results show that the zeolite filter system could be a simple low-cost pre-treatment option which is able to significantly reduce the total hardness level of recycled water via effective ion exchange. Additionally, depending on the quality of recycled water required by end users, a new by-pass controller using a three-level operation switching mechanism is introduced. This approach provides householders sufficient flexibility to respond to different levels of desired recycled water quality and increase the reliability of long-term system operation. These findings could be beneficial to the smooth implementation of new end uses and expansion of the potential recycled water market. The information could also offer sound suggestions for future research on sustainable water management and governance. PMID:24496024

  1. Aging assessment of nuclear air-treatment system HEPA filters and adsorbers. Volume 1, Phase 1

    SciTech Connect

    Winegardner, W.K.

    1993-08-01

    A Phase I aging assessment of high-efficiency particulate air (HEPA) filters and activated carbon gas adsorption units (adsorbers) was performed by the Pacific Northwest Laboratory (PNL) as part of the US Nuclear Regulatory Commission`s (NRC) Nuclear Plant Aging Research (NPAR) Program. Information concerning design features; failure experience; aging mechanisms, effects, and stressors; and surveillance and monitoring methods for these key air-treatment system components was compiled. Over 1100 failures, or 12 percent of the filter installations, were reported as part of a Department of Energy (DOE) survey. Investigators from other national laboratories have suggested that aging effects could have contributed to over 80 percent of these failures. Tensile strength tests on aged filter media specimens indicated a decrease in strength. Filter aging mechanisms range from those associated with particle loading to reactions that alter properties of sealants and gaskets. Low radioiodine decontamination factors associated with the Three Mile Island (TMI) accident were attributed to the premature aging of the carbon in the adsorbers. Mechanisms that can lead to impaired adsorber performance include oxidation as well as the loss of potentially available active sites as a result of the adsorption of pollutants. Stressors include heat, moisture, radiation, and airborne particles and contaminants.

  2. Polylactide-co-glycolide microparticles with surface adsorbed antigens as vaccine delivery systems.

    PubMed

    Singh, Manmohan; Kazzaz, Jina; Ugozzoli, Mildred; Malyala, Padma; Chesko, James; O'Hagan, Derek T

    2006-01-01

    Several groups have shown that vaccine antigens can be encapsulated within polymeric microparticles and can serve as potent antigen delivery systems. We have recently shown that an alternative approach involving charged polylactide co-glycolide (PLG) microparticles with surface adsorbed antigen(s) can also be used to deliver antigen into antigen presenting cell (APC). We have described the preparation of cationic and anionic PLG microparticles which have been used to adsorb a variety of agents, which include plasmid DNA, recombinant proteins and adjuvant active oligonucleotides. These PLG microparticles were prepared using a w/o/w solvent evaporation process in the presence of the anionic surfactants, including DSS (dioctyl sodium sulfosuccinate) or cationic surfactants, including CTAB (hexadecyl trimethyl ammonium bromide). Antigen binding to the charged PLG microparticles was influenced by several factors including electrostatic and hydrophobic interactions. These microparticle based formulations resulted in the induction of significantly enhanced immune responses in comparison to alum. The surface adsorbed microparticle formulation offers an alternative and novel way of delivering antigens in a vaccine formulation. PMID:16472100

  3. Phase-field modeling of epitaxial growth in stochastic systems with interacting adsorbate

    NASA Astrophysics Data System (ADS)

    Kharchenko, Dmitrii O.; Kharchenko, Vasyl O.; Lysenko, Irina O.

    2011-04-01

    We study the epitaxial growth of pyramidal patterns in stochastic systems with interacting adsorbate within the framework of the phase-field approach based on the Burton-Cabrera-Frank model. Considering the statistical criteria of pattern formation, it is shown that the system dynamics is governed by the interaction strength of adatoms and the noise intensity of the total flux fluctuations. We have shown that the noise action can crucially change the processes of pyramidal pattern formation. The scaling behavior of the height-height correlation function is discussed.

  4. Effects of welding fumes on nuclear air cleaning system carbon adsorber banks

    SciTech Connect

    Roberson, P.W.

    1997-08-01

    Standard Technical Specifications for nuclear air cleaning systems include requirements for surveillance tests following fire, painting, or chemical release in areas communicating with the affected system. To conservatively implement this requirement, many plants categorize welding as a chemical release process, and institute controls to ensure that welding fumes do not interact with carbon adsorbers in a filter system. After reviewing research data that indicated welding had a minimal impact on adsorber iodine removal efficiency, further testing was performed with the goal of establishing a welding threshold. It was anticipated that some quantity of weld electrodes could be determined that had a corresponding detrimental impact on iodine removal efficiency for the exposed adsorber. This value could be used to determine a conservative sampling schedule that would allow the station to perform laboratory testing to ensure system degradation did not occur without a full battery of surveillance tests. A series of tests was designed to demonstrate carbon efficiency versus cumulative welding fume exposure. Three series of tests were performed, one for each of three different types of commonly used weld electrodes. Carbon sampling was performed at baseline conditions, and every five pounds of electrode thereafter. Two different laboratory tests were performed for each sample; one in accordance with ASTM 3803/1989 at 95% relative humidity and 30 degrees C, and another using the less rigorous conditions of 70% relative humidity and 80 degrees C. Review of the test data for all three types of electrodes failed to show a significant correlation between carbon efficiency degradation and welding fume exposure. Accordingly, welding is no longer categorized as a `chemical release process` at McGuire Nuclear Station, and limits on welding fume interaction with ventilation systems have been eliminated. 4 refs., 3 figs., 1 tab.

  5. System for recycling char in iron oxide reducing kilns

    SciTech Connect

    Baker, A.C.; Keran, V.P.

    1983-03-08

    A method and means for improving the efficiency of the process for directly reducing ore containing iron oxide in a rotary kiln using a solid carbonaceous reducing agent, such as coal, introduced from the ore feed and discharge ends of the kiln, as both fuel and reductant, is disclosed wherein the charred coal or char found in the discharge product is recycled into the process at the discharge end of the kiln rather than the feed end as in the prior art. In particular, the recovered char, both coarse and finer particles, are transported to a recycle bin from which they are returned at a preselected rate to the kiln process by being injected along with the coal blown into the discharge end of the kiln. Alternatively, the recycle char alone may be fed without any coal at the discharge end of the kiln.

  6. Recycled Materials Affirmative Procurement Tracking System (RMAPTS). Software user`s manual

    SciTech Connect

    Not Available

    1994-07-01

    RMAPTS is designed to interact with other computer systems. This system can upload or download data from other RMAPTS systems. RMAPTS also complies with Federal Acquisition Regulations (FARs). Section 6002 of the Resource Conservation of Recovery Act (RCRA), Title 40 Part 247-25 of the Code of Federal Regulations, and Executive Order 12780 present mandates and guidelines to the Department of Energy (DOE) and its contractors for the procurement of products containing recycled materials. These regulations promote cost-effective waste reduction and recovery of reusable materials from Federally generated waste; promote environmentally sound and economically efficient waste reduction and recycling of the nation`s resources; and stimulate private sector markets through preferential procurement of designated items. On August 4, 1992, the Deputy Secretary of the Department of Energy requested DOE to show its commitment to Executive Order 12780, Federal Agency Recycling and Procurement Policy. This software was developed in response to this request. RMAPTS will allow users to track and report specific data concerning the procurement of products that contain recycled material and the quantity of recycled material contained in each product. This system provides greater detail, improved accuracy, and less time spent on year-end reporting. Users can quickly check the year-to-date status of recycled material purchases and recycled material contents of products at any time.

  7. EVALUATION OF USFILTER MEMBRALOX SILVERBACK MODEL 900 AKALINE CLEANER RECYCLING SYSTEM

    EPA Science Inventory

    The Membralox Silverback Model 900 (Silverback Unit) is a microfiltration system for recycling used alkaline cleaning solutions (cleaners). Alkaline cleaning is performed on metal parts at different times during the manufacturing process to remove oils, coolants and other metalwo...

  8. ANALYSIS AND SIMULATION OF RECYCLE SO2-LIME SLURRY IN TCA (TURBULENT CONTACT ABSORBER) SCRUBBER SYSTEM

    EPA Science Inventory

    The report gives results of an analysis of flue gas desulfurization by a turbulent contact absorber (TCA) employing lime slurry, including the development of performance equations for the scrubber-hold tank recycle system. Performance characteristics investigated include pressure...

  9. Clean Community System Multi-Material Recycling Manual.

    ERIC Educational Resources Information Center

    Keep America Beautiful, Inc., New York, NY.

    This manual is designed to assist communities in recycling the greatest possible volume of materials in ways which will: (1) benefit the local economy; (2) encourage cooperation between public and private sectors; and (3) prove valuable to municipal and county sanitation services. The manual is divided into five sections. Section 1 lays out the…

  10. Adsorbate-induced quantum Hall system probed by scanning tunneling spectroscopy combined with transport measurements

    SciTech Connect

    Masutomi, Ryuichi Okamoto, Tohru

    2015-06-22

    An adsorbate-induced quantum Hall system at the cleaved InSb surfaces is investigated in magnetic fields up to 14 T using low-temperature scanning tunneling microscopy and spectroscopy combined with transport measurements. We show that an enhanced Zeeman splitting in the Shubnikov-de Haas oscillations is explained by an exchange enhancement of spin splitting and potential disorder, both of which are obtained from the spatially averaged density of states (DOS). Moreover, the Altshuler–Aronov correlation gap is observed in the spatially averaged DOS at 0 T.

  11. Modeling and Analysis of the Electrokinetic Mass Transport and Adsorption Mechanisms of a Charged Adsorbate in Capillary Electrochromatography Systems Employing Charged Nonporous Adsorbent Particles.

    PubMed

    Grimes, B. A.; Liapis, A. I.

    2001-02-01

    Mass-transfer systems based on electrokinetic phenomena (i.e., capillary electrochromatography (CEC)) have shown practical potential for becoming powerful separation methods for the biotechnology and pharmaceutical industries. A dynamic mathematical model, consisting of the momentum balance and the Poisson equations, as well as the unsteady-state continuity expressions for the cation and anion of the background electrolyte and of a positively charged analyte (adsorbate), is constructed and solved to determine quantitatively the electroosmotic velocity, the electrostatic potential, the concentration profiles of the charged species in the double layer and in the electroneutral core region of the fluid in the interstitial channels for bulk flow in the packed chromatographic column, and the axial current density profiles as the adsorbate adsorbs onto the negatively charged fixed sites on the surface of the nonporous particles packed in the chromatographic column. The frontal analysis mode of operation is simulated in this work. The results obtained from model simulations provide significant physical insight into and understanding of the development and propagation of the dynamic profile of the concentration of the adsorbate (analyte) and indicate that sharp, highly resolved adsorption fronts and large amounts of adsorbate in the adsorbed phase for a given column length can be obtained under the following conditions: (i) The ratio, gamma(2, 0), of the electroosmotic velocity of the mobile liquid phase at the column entrance after the adsorption front has passed the column entrance to the electrophoretic velocity of the anion is very close to -1. The structure of the equations of the model and model simulations indicate that a stable adsorption front cannot develop when gamma(2, 0) is less than -1 unless the value of the mobility of the cation is less than the value of the mobility of the analyte, which may be a rare occurrence in practical CEC systems. (ii) The ratio of

  12. Methods to reduce bacterial contamination of recycling cooling systems of a CHPP

    NASA Astrophysics Data System (ADS)

    Chichirova, N. D.; Chichirov, A. A.; Vlasov, S. M.; Vlasova, A. Yu.

    2015-07-01

    Bacterial contamination of circulating and make-up water of the nonconjugated recycling cooling system with evaporative cooling towers of thermal power plants is studied. The nonconjugated recycling cooling system of Naberezhnochelninskaya CHP Plant was selected as the object of study. It was found that circulating water of recycling cooling is highly contaminated with aerobic heterotrophic bacteria. At the same time, make-up water for the cooling system from the Kama River is moderately polluted with anaerobic bacteria. Measurements of biological contamination in different parts of the recycling cooling system showed that populations of colonies of microorganisms abruptly decreases in turbine condensers, which is probably indicative of their death and deposition on the heat transfer surface of the condenser. Calculation using a special program showed that biological contamination of the recycling cooling system poses the greatest risks for clogging of the equipment (seven points on a nine-point scale), its corrosion (two points), and damage to the health of personnel (two points). Rapid development of aerobic bacteria apparently occurs under elevated temperature and intense aeration of water in the cooling tower. It is suggested to periodically monitor the recycling cooling system for biological pollution and to set a timetable for bactericidal treatment of circulating water depending on the level of its bacterial contamination.

  13. TRANSPORT PLANNING MODEL FOR WIDE AREA RECYCLING SYSTEM OF INDUSTRIAL WASTE PLASTIC

    NASA Astrophysics Data System (ADS)

    Arai, Yasuhiro; Kawamura, Hisashi; Koizumi, Akira; Mogi, Satoshi

    To date, the majority of industrial waste plastic generated in an urban city has been processed into landfill. However, it is now necessary to actively utilize that plastic as a useful resource to create a recycling society with a low environment influence. In order to construct a reasonable recycling system, it is necessary to address the "transportation problem," which means determining how much industrial waste plastic is to be transported to what location. With the goal of eliminating landfill processing, this study considers a transport planning model for industrial waste plastic applying linear programming. The results of running optimized calculations under given scenarios clarified not only the possibilities for recycle processing in the Metropolitan area, but also the validity of wide area recycling system.

  14. Modulating resonance behaviors by noise recycling in bistable systems with time delay

    SciTech Connect

    Sun, Zhongkui Xu, Wei; Yang, Xiaoli; Xiao, Yuzhu

    2014-06-01

    In this paper, the impact of noise recycling on resonance behaviors is studied theoretically and numerically in a prototypical bistable system with delayed feedback. According to the interior cooperating and interacting activity of noise recycling, a theory has been proposed by reducing the non-Markovian problem into a two-state model, wherein both the master equation and the transition rates depend on not only the current state but also the earlier two states due to the recycling lag and the feedback delay. By virtue of this theory, the formulae of the power spectrum density and the linear response function have been found analytically. And the theoretical results are well verified by numerical simulations. It has been demonstrated that both the recycling lag and the feedback delay play a crucial role in the resonance behaviors. In addition, the results also suggest an alternative scheme to modulate or control the coherence or stochastic resonance in bistable systems with time delay.

  15. Occurrence and fate of acrylamide in water-recycling systems and sludge in aggregate industries.

    PubMed

    Junqua, Guillaume; Spinelli, Sylvie; Gonzalez, Catherine

    2015-05-01

    Acrylamide is a hazardous substance having irritant and toxic properties as well as carcinogen, mutagen, and impaired fertility possible effects. Acrylamide might be found in the environment as a consequence of the use of polyacrylamides (PAMs) widely added as a flocculant for water treatment. Acrylamide is a monomer used to produce polyacrylamide (PAM) polymers. This reaction of polymerization can be incomplete, and acrylamide molecules can be present as traces in the commercial polymer. Thus, the use of PAMs may generate a release of acrylamide in the environment. In aggregate industries, PAM is widely involved in recycling process and water reuse (aggregate washing). Indeed, these industries consume large quantities of water. Thus, European and French regulations have favored loops of recycling of water in order to reduce water withdrawals. The main goal of this article is to study the occurrence and fate of acrylamide in water-recycling process as well as in the sludge produced by the flocculation treatment process in aggregate production plants. Moreover, to strengthen the relevance of this article, the objective is also to demonstrate if the recycling system leads to an accumulation effect in waters and sludge and if free acrylamide could be released by sludge during their storage. To reach this objective, water sampled at different steps of recycling water process has been analyzed as well as different sludge corresponding to various storage times. The obtained results reveal no accumulation effect in the water of the water-recycling system nor in the sludge. PMID:24840357

  16. Ventilation systems for a spent LWR fuel recycle complex

    SciTech Connect

    Not Available

    1981-01-01

    A conceptual design study has been made of a facility to recycle spent Light Water Reactor fuel. This study was based on coprocessing of plutonium and uranium where plutonium is never available as a separate material. The design of the fuel reprocessing facilities is based on remote operation and remote maintenance. The experience of many years of safe and dependable operation of government fuel processing facilities at Savannah River and Hanford was used in the design. A requirement of the study was that the facilities be licensable under Title 10 and Title 40 of the Code of Federal Regulations.

  17. Surface-adsorbed reverse micelle-loaded solid self-nanoemulsifying drug delivery system of talinolol.

    PubMed

    Shakeel, Faiyaz; Haq, Nazrul; Alanazi, Fars K; Alsarra, Ibrahim A

    2016-03-01

    The aim of present investigation was to develop surface-adsorbed reverse-micelle-loaded solid self-nanoemulsifying drug delivery system (SNEDDS) of talinolol in order to enhance its in vitro dissolution rate, which in turn enhance the bioavailability. SNEDDS were prepared using aqueous phase titration method. Thermodynamically stable formulations were characterized in terms of droplet size, viscosity, % transmittance, drug content and surface morphology. Low cost acid-treated coffee husk was used as an effective biosorbent for preparation of solid SNEDDS. Developed SNEDDS were subjected to in vitro drug release/dissolution studies. In vitro drug release studies showed 99.6% release of talinolol from optimized solid SNEDDS TS3 after 120 min of study. The results of solubility studies showed 4849.5-folds enhancement in solubility of talinolol from optimized SNEDDS as compared to its aqueous solubility. PMID:25318634

  18. Aluminosilicate-based adsorbent in equimolar and non-equimolar binary-component heavy metal removal systems.

    PubMed

    Xu, Meng; Hadi, Pejman; Ning, Chao; Barford, John; An, Kyoung Jin; McKay, Gordon

    2015-01-01

    Cadmium (Cd) and lead (Pb) are toxic heavy metals commonly used in various industries. The simultaneous presence of these metals in wastewater amplifies the toxicity of wastewater and the complexity of the treatment process. This study has investigated the selective behavior of an aluminosilicate-based mesoporous adsorbent. It has been demonstrated that when equimolar quantities of the metals are present in wastewater, the adsorbent uptakes the Pb²⁺ ions selectively. This has been attributed to the higher electronegativity value of Pb²⁺ compared to Cd²⁺ which can be more readily adsorbed on the adsorbent surface, displacing the Cd²⁺ ions. The selectivity can be advantageous when the objective is the separation and reuse of the metals besides wastewater treatment. In non-equimolar solutions, a complete selectivity can be observed up to a threshold Pb²⁺ molar ratio of 30%. Below this threshold value, the Cd²⁺ and Pb²⁺ ions are uptaken simultaneously due to the abundance of Cd²⁺ ions and the availability of adsorption sites at very low Pb²⁺ molar ratios. Moreover, the total adsorption capacities of the adsorbent for the multi-component system have been shown to be in the same range as the single-component system for each metal ion which can be of high value for industrial applications. PMID:26676004

  19. Coupling plant growth and waste recycling systems in a controlled life support system (CELSS)

    NASA Technical Reports Server (NTRS)

    Garland, Jay L.

    1992-01-01

    The development of bioregenerative systems as part of the Controlled Ecological Life Support System (CELSS) program depends, in large part, on the ability to recycle inorganic nutrients, contained in waste material, into plant growth systems. One significant waste (resource) stream is inedible plant material. This research compared wheat growth in hydroponic solutions based on inorganic salts (modified Hoagland's) with solutions based on the soluble fraction of inedible wheat biomass (leachate). Recycled nutrients in leachate solutions provided the majority of mineral nutrients for plant growth, although additions of inorganic nutrients to leachate solutions were necessary. Results indicate that plant growth and waste recyling systems can be effectively coupled within CELSS based on equivalent wheat yield in leachate and Hoagland solutions, and the rapid mineralization of waste organic material in the hydroponic systems. Selective enrichment for microbial communities able to mineralize organic material within the leachate was necessary to prevent accumulation of dissolved organic matter in leachate-based solutions. Extensive analysis of microbial abundance, growth, and activity in the hydroponic systems indicated that addition of soluble organic material from plants does not cause excessive microbial growth or 'biofouling', and helped define the microbially-mediated flux of carbon in hydroponic solutions.

  20. Hydraulic characterization of an activated sludge reactor with recycling system by tracer experiment and analytical models.

    PubMed

    Sánchez, F; Viedma, A; Kaiser, A S

    2016-09-15

    Fluid dynamic behaviour plays an important role in wastewater treatment. An efficient treatment requires the inexistence of certain hydraulic problems such as dead zones or short-circuiting flows. Residence time distribution (RTD) analysis is an excellent technique for detecting these inefficiencies. However, many wastewater treatment installations include water or sludge recycling systems, which prevent us from carrying out a conventional tracer pulse experiment to obtain the RTD curve of the installation. This paper develops an RTD analysis of an activated sludge reactor with recycling system. A tracer experiment in the reactor is carried out. Three analytical models, derived from the conventional pulse model, are proposed to obtain the RTD curve of the reactor. An analysis of the results is made, studying which model is the most suitable for each situation. This paper is useful to analyse the hydraulic efficiency of reactors with recycling systems. PMID:27288672

  1. Differences in Aquatic Communities Between Wetlands Created by an Agricultural Water Recycling System

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Establishment of an agricultural water recycling system known as the wetland reservoir subirrigation system (WRSIS) results in the creation of wetlands adjacent to agricultural fields. Each WRSIS consists of one wetland designed to process agricultural chemicals (WRSIS wetlands) and one wetland to s...

  2. Triple Recycling Processes Impact Systemic and Local Bioavailability of Orally Administered Flavonoids.

    PubMed

    Dai, Peimin; Zhu, Lijun; Luo, Feifei; Lu, Linlin; Li, Qiang; Wang, Liping; Wang, Ying; Wang, Xinchun; Hu, Ming; Liu, Zhongqiu

    2015-05-01

    Triple recycling (i.e., enterohepatic, enteric and local recycling) plays a central role in governing the disposition of phenolics such as flavonoids, resulting in low systemic bioavailability but higher gut bioavailability and longer than expected apparent half-life. The present study aims to investigate the coexistence of these recycling schemes using model bioactive flavonoid tilianin and a four-site perfused rat intestinal model in the presence or absence of a lactase phlorizin hydrolase (LPH) inhibitor gluconolactone and/or a glucuronidase inhibitor saccharolactone. The result showed that tilianin could be metabolized into tilianin glucuronide, acacetin, and acacetin glucuronide, which are excreted into the bile and luminal perfusate (highest in the duodenum and lowest in the colon). Gluconolactone (20 mM) significantly reduced the absorption of tilianin and the enteric and biliary excretion of acacetin glucuronide. Saccharolactone (0.1 mM) alone or in combination of gluconolactone also remarkably reduced the biliary and intestinal excretion of acacetin glucuronide. Acacetin glucuronides from bile or perfusate were rapidly hydrolyzed by bacterial β-glucuronidases to acacetin, enabling enterohepatic and enteric recycling. Moreover, saccharolactone-sensitive tilianin disposition and glucuronide deconjugation, which was more active in the small intestine than the colon, points to the small intestinal origin of the deconjugation enzyme and supports the presence of local recycling scheme. In conclusion, our studies have demonstrated triple recycling of a bioactive phenolic (i.e., a model flavonoid), and this recycling may have an impact on the site and duration of polyphenols pharmacokinetics in vivo. PMID:25762448

  3. Adsorbent phosphates

    NASA Technical Reports Server (NTRS)

    Watanabe, S.

    1983-01-01

    An adsorbent which uses as its primary ingredient phosphoric acid salts of zirconium or titanium is presented. Production methods are discussed and several examples are detailed. Measurements of separating characteristics of some gases using the salts are given.

  4. Effect of adsorbed films on friction of Al2O3-metal systems

    NASA Technical Reports Server (NTRS)

    Pepper, S. V.

    1976-01-01

    The kinetic friction of polycrystalline Al2O3 sliding on Cu, Ni, and Fe in ultrahigh vacuum was studied as a function of the surface chemistry of the metal. Clean metal surfaces were exposed to O2, Cl2, C2H4, and C2H3Cl, and the change in friction due to the adsorbed species was observed. Auger electron spectroscopy assessed the elemental composition of the metal surface. It was found that the systems exposed to Cl2 exhibited low friction, interpreted as the van der Waals force between the Al2O3 and metal chloride. The generation of metal oxide by oxygen exposures resulted in an increase in friction, interpreted as due to strong interfacial bonds established by reaction of metal oxide with Al2O3 to form the complex oxide (spinel). The only effect of C2H4 was to increase the friction of the Fe system, but C2H3Cl exposures decreases friction in both Ni and Fe systems, indicating the dominance of the chlorine over the ethylene complex on the surface

  5. Simulation of cutting process in the cable recycling system

    NASA Astrophysics Data System (ADS)

    Li, Yang; Luo, Zhen; Song, Kailei; Ao, Sansan; Wang, Rui

    2011-05-01

    The utilization of Waste Electrical and Electronic Equipment is a hot spot in environmental protection field presently and the resource utilization of cable wastes is an important subject. An enormous amount of electrical cable is disposed of as scrap each year. In order to recycle the valuable copper wires, cable granulator technique is used widely. However, one of the shortcomings of this technique is it has serious tool wear. In order to better understand the reason for tool wear, this paper simulates the stress and strain distribution in the cutting tool and copper during the cutting process in cable granulator by finite element method. The result shows that a tensile stress region, which is the main reason for blade tipping, appeared in the upper blade. Besides, the tensile stress in the right side of upper blade is higher than that in the left side. Therefore, in order to extend the life of cutter, we suggest using different materials in different stress zone to manufacture cutting tool. After the cutter was worn out, the right side of the blade can be renovated using material with well tensile performance through overlaying welding, as well as the left side of the blade can be renovated by material with high red hardness, high wear resistance, and high compression strength through overlaying welding. This method can reduce the consumption of precious metals and raise the utilization rate of materials.

  6. Simulation of cutting process in the cable recycling system

    NASA Astrophysics Data System (ADS)

    Li, Yang; Luo, Zhen; Song, Kailei; Ao, Sansan; Wang, Rui

    2010-12-01

    The utilization of Waste Electrical and Electronic Equipment is a hot spot in environmental protection field presently and the resource utilization of cable wastes is an important subject. An enormous amount of electrical cable is disposed of as scrap each year. In order to recycle the valuable copper wires, cable granulator technique is used widely. However, one of the shortcomings of this technique is it has serious tool wear. In order to better understand the reason for tool wear, this paper simulates the stress and strain distribution in the cutting tool and copper during the cutting process in cable granulator by finite element method. The result shows that a tensile stress region, which is the main reason for blade tipping, appeared in the upper blade. Besides, the tensile stress in the right side of upper blade is higher than that in the left side. Therefore, in order to extend the life of cutter, we suggest using different materials in different stress zone to manufacture cutting tool. After the cutter was worn out, the right side of the blade can be renovated using material with well tensile performance through overlaying welding, as well as the left side of the blade can be renovated by material with high red hardness, high wear resistance, and high compression strength through overlaying welding. This method can reduce the consumption of precious metals and raise the utilization rate of materials.

  7. Cost-Based Optimization of a Papermaking Wastewater Regeneration Recycling System

    NASA Astrophysics Data System (ADS)

    Huang, Long; Feng, Xiao; Chu, Khim H.

    2010-11-01

    Wastewater can be regenerated for recycling in an industrial process to reduce freshwater consumption and wastewater discharge. Such an environment friendly approach will also lead to cost savings that accrue due to reduced freshwater usage and wastewater discharge. However, the resulting cost savings are offset to varying degrees by the costs incurred for the regeneration of wastewater for recycling. Therefore, systematic procedures should be used to determine the true economic benefits for any water-using system involving wastewater regeneration recycling. In this paper, a total cost accounting procedure is employed to construct a comprehensive cost model for a paper mill. The resulting cost model is optimized by means of mathematical programming to determine the optimal regeneration flowrate and regeneration efficiency that will yield the minimum total cost.

  8. [MARS (Molecular Adsorbents Recirculating System). New technique of extracorporeal depuration in liver failure].

    PubMed

    Vázquez Calatayud, Mónica; Carrión Torre, María; García-Fernández, Nuria

    2005-01-01

    MARS (Molecular Adsorbent Recirculating System) is a new technique as a system of liver detoxification in patients with severe acute or acute on chronic hepatic failure. Also, it has shown its usefulness in the control of resistant pruritus in the primary biliary cirrhosis. Due to the fact that this technique is often delivered in Intensive Care Units (ICUs), we have reviewed the literature 1999 until now to describe this technique, its benefits and its mains complications. The technique was developed in Germany, where in 1999 was first used in clinical practice. It was used for the first time in Spain in 2000 and in the Clínica Universitaria of Navarra in July of 2001. Despite the short clinical experience using MARS its obvious beneficial effects such as decrease of hepatic toxins and the improvement of encephalopathy and hemodynamic situation, makes it a very useful technique in these patients. MARS has been shown to be a safe procedure, well tolerated by patients and accessible to the use by specialised nurses. Despite the encouraging clinical results, its used is still limited. Moreover its high cost precludes it widespread use and requires further studies. PMID:16022828

  9. Introduction and feasibility assessment of laundry use of recycled water in dual reticulation systems in Australia.

    PubMed

    Mainali, Bandita; Pham, Thi Thu Nga; Ngo, Huu Hao; Guo, Wenshan; Listowski, Andrzej; O'Halloran, Kelly; Miechel, Clayton; Muthukaruppan, Muthu; Johnston, Rosemary

    2014-02-01

    Laundry is a potential new end use of recycled water in dual reticulation systems. Generally, the community is willing to accept this new end use if it can meet the concerns on health issues, durability of washing machine, cloth quality and aesthetic appearance. This study addresses all these major concerns thereby assisting in the introduction and promotion of this new end use in the existing and proposed dual reticulation systems. Five representative cloth materials were selected for washing in tap water and in recycled water for up to 50 wash cycles for comparative studies. The tearing/tensile strength tests were used for the assessment of cloth durability. ANOVA one way test was applied for the significance analysis (Tukey's test p<0.05) which indicated that there is no significant change in the tensile/tearing strengths of washed cloth samples. Scanning electron microscope (SEM) images of the washed cloth samples found no distinct change in surface morphology. Textile colour analysis (CIEDE2000) analysed the variation in colour of the washed cloth samples and showed that the change in colour ∆E ranges from 0-1 revealing no visible difference in colour of cloth samples. Langelier Saturation Index (LSI) was used as the indicator for predicting corrosive/scaling potential of recycled water. The LSI values ranged from +0.5 to -0.5, indicating no corrosive or scaling potential of recycled water. The microbiological study of the cloth samples washed in recycled water indicated that there was no contamination with representative bacteria. As the recycled water has similar effects like tap water on cloth and washing machine, it is safe to use for laundry. PMID:24121662

  10. DEMONSTRATION OF A MAXIMUM RECYCLE, SIDESTREAM SOFTENING SYSTEM AT A PETROCHEMICAL PLANT AND A PETROLEUM REFINERY

    EPA Science Inventory

    New full-scale maximum recycle sidestream softening systems at USS Chemicals, Houston, Texas and TOSCO refinery, Bakersfield, California were evaluated as a technology to achieve zero wastewater discharge. Softener process efficiency was optimum at a pH control range of 10.3 to 1...

  11. Characterization of Samples from the 3H Evaporator System Including Effects of Recycle

    SciTech Connect

    Wilmarth, W.R.

    2001-05-15

    Analysis of several series of samples from the 3H Evaporator System have been completed. The goal of this work was to determine the effects of 3H operation including recycle of concentrated supernate from Tank 30H into the sludge layer of Tank 32H.

  12. Diversity of free-living amoebae in a dual distribution (potable and recycled) water system

    EPA Science Inventory

    Free-living amoebae are known to facilitate the growth of water associated pathogens. This study, for the first time, explored the diversity of free-living amoebae in a dual distribution (potable and recycled) water system in Rouse Hill NSW, Australia. Water and biofilm samples w...

  13. A fiber optics system for monitoring utilization of ZnO adsorbent beds during desulfurization for logistic fuel cell applications

    NASA Astrophysics Data System (ADS)

    Sujan, Achintya; Yang, Hongyun; Dimick, Paul; Tatarchuk, Bruce J.

    2016-05-01

    An in-situ fiber optic based technique for direct measurement of capacity utilization of ZnO adsorbent beds by monitoring bed color changes during desulfurization for fuel cell systems is presented. Adsorbents composed of bulk metal oxides (ZnO) and supported metal oxides (ZnO/SiO2 and Cusbnd ZnO/SiO2) for H2S removal at 22 °C are examined. Adsorbent bed utilization at breakthrough is determined by the optical sensor as the maximum derivative of area under UV-vis spectrum from 250 to 800 nm observed as a function of service time. Since the response time of the sensor due to bed color change is close to bed breakthrough time, a series of probes along the bed predicts utilization of the portion of bed prior to H2S breakthrough. The efficacy of the optical sensor is evaluated as a function of inlet H2S concentration, H2S flow rate and desulfurization in presence of CO, CO2 and moisture in feed. A 6 mm optical probe is employed to measure utilization of a 3/16 inch ZnO extrudate bed for H2S removal. It is envisioned that with the application of the optical sensor, desulfurization can be carried out at high adsorbent utilization and low operational costs during on-board miniaturized fuel processing for logistic fuel cell power systems.

  14. A fiber optics system for monitoring utilization of ZnO adsorbent beds during desulfurization for logistic fuel cell applications

    NASA Astrophysics Data System (ADS)

    Sujan, Achintya; Yang, Hongyun; Dimick, Paul; Tatarchuk, Bruce J.

    2016-05-01

    An in-situ fiber optic based technique for direct measurement of capacity utilization of ZnO adsorbent beds by monitoring bed color changes during desulfurization for fuel cell systems is presented. Adsorbents composed of bulk metal oxides (ZnO) and supported metal oxides (ZnO/SiO2 and Cusbnd ZnO/SiO2) for H2S removal at 22 °C are examined. Adsorbent bed utilization at breakthrough is determined by the optical sensor as the maximum derivative of area under UV-vis spectrum from 250 to 800 nm observed as a function of service time. Since the response time of the sensor due to bed color change is close to bed breakthrough time, a series of probes along the bed predicts utilization of the portion of bed prior to H2S breakthrough. The efficacy of the optical sensor is evaluated as a function of inlet H2S concentration, H2S flow rate and desulfurization in presence of CO, CO2 and moisture in feed. A 6 mm optical probe is employed to measure utilization of a 3/16 inch ZnO extrudate bed for H2S removal. It is envisioned that with the application of the optical sensor, desulfurization can be carried out at high adsorbent utilization and low operational costs during on-board miniaturized fuel processing for logistic fuel cell power systems.

  15. Extracorporeal Elimination of Piperacillin/Tazobactam during Molecular Adsorbent Recirculating System Therapy.

    PubMed

    Personett, Heather A; Larson, Scott L; Frazee, Erin N; Nyberg, Scott L; El-Zoghby, Ziad M

    2015-08-01

    Use of the Molecular Adsorbent Recirculating System (MARS) as a liver support device continues to grow worldwide. Various components of the MARS circuit remove both protein-bound and water-soluble molecules. Little is known about the extent of the enhanced clearance mechanisms used in MARS therapy on drug elimination. Of particular interest to acute care practitioners is the impact of MARS on antibiotic clearance, as suboptimal concentrations of such drugs can negatively impact patient outcomes. The properties of piperacillin/tazobactam suggest that elimination may be enhanced in the setting of MARS therapy. We describe two cases in which this was studied. Piperacillin concentrations were determined at various points within the MARS circuit, and patient serum concentrations were reported throughout the dosing interval while receiving MARS therapy. Piperacillin concentrations in both cases were in excess of the desired goal minimum inhibitory concentrations for treatment of gram-negative infections. Use of an extended-infusion strategy of piperacillin/tazobactam 3.375 or 4.5 g given every 8 hours maintained desired serum levels throughout the dosing interval. To our knowledge, this is the second published report on the use of piperacillin/tazobactam during MARS therapy. These case reports reveal successful dosing strategies for patients requiring piperacillin/tazobactam while receiving MARS therapy, as well as quantify the influence of individual MARS elements on drug extraction. PMID:26289310

  16. Meta-analysis of survival with the molecular adsorbent recirculating system for liver failure.

    PubMed

    He, Guo-Lin; Feng, Lei; Duan, Chong-Yang; Hu, Xiang; Zhou, Chen-Jie; Cheng, Yuan; Pan, Ming-Xin; Gao, Yi

    2015-01-01

    This study aims to assess the treatment effects of the molecular adsorbent recirculating system (MARS) in patients with acute and acute-on-chronic liver failure. We searched MEDLINE, EMBASE, and the Cochrane Controlled Trials Registry database between January 1966 and January 2014. We included randomized controlled trials, which compared the treatment effects of MARS with standard medical treatment. Study quality assessed according to Consolidated Standards of Reporting Trials (CONSORT) criteria. The risk ratio was used as the effect-size measure according to a fixed-effects model. The search strategy revealed 72 clinical studies, 10 of which were randomized controlled trials that met the criteria and were included. Four addressed ALF (93 patients) and six addressed AOCLF (453 patients). The mean CONSORT score was 15 (range 10-20). By meta-analysis, MARS significantly improved survival in ALF (risk ratio 0.61; 95% CI 0.38, 0.97; P = 0.04). There was no significant survival benefit in AOCLF (risk ratio 0.88; 95% CI 0.74, 1.06; P = 0.16). MARS significantly improved survival in patients with acute liver failure, however, there is no evidence that it improved survival in patients with acute-on-chronic liver failure. In conclusion, the present meta-analysis indicates that MARS therapy can improve survival in patients with ALF. It is necessary to develop MARS treatment because of the increasing demand for liver transplantation and the risk of liver failure. PMID:26770295

  17. The recycle of water and nitrogen from urine in bioregenerative life support system

    NASA Astrophysics Data System (ADS)

    Deng, Shengda; Xie, Beizhen; Liu, Hong

    2016-06-01

    The recycle of the wastewater is one of the main factors for realizing a higher closure degree of bioregenerative life support system (BLSS), among which the treatment and recovery of the crew's urine are the most difficult and critical issues. Researchers have paid a lot of attention on the desalination of urine in the previous studies, however, if the nitrogen could be recycled simultaneously while desalting the urine, the substance circulation and the closure of BLSS could be improved more significantly. In this study, two-step method was conducted to treat the urine and recycle the water and nitrogen. The urine was hydrolyzed firstly, and then the water vapor and ammonia gas were cooled and collected by using reduced pressure distillation in alkaline condition. High temperature acidification method (HTAM) and immobilized urease catalysis method (IUCM) were investigated in the hydrolysis pretreatment of urine. The treatment conditions of both methods were optimized and the hydrolysis efficiencies were compared. The results showed that the optimum treatment temperature and acidity for HTAM were 99 °C and [H+] =2 mol/L when the reaction time was 7 h, and the maximum nitrogen recycle efficiency was 39.7%. While, the optimum treatment conditions for IUCM were 60 °C, pH=7.0 and 40 min, and the maximum nitrogen recycle efficiency could reach 52.2%. Therefore, compared with HTAM, IUCM has higher hydrolysis efficiency with milder reaction temperature and pH and shorter reaction time which means it could adapt to the heavy urine treatment workload in BLSS. This investigation has provided a promising method to recycle the urine in BLSS, and all the results will contribute to the further BLSS experiments conducted in the stage II of the "Lunar Palace 1".

  18. Energetic and entropic analysis of mirror symmetry breaking processes in a recycled microreversible chemical system.

    PubMed

    Plasson, Raphaël; Bersini, Hugues

    2009-03-19

    Understanding how biological homochirality emerged remains a challenge for the researchers interested in the origin of life. During the last decades, stable nonracemic steady states of nonequilibrium chemical systems have been discussed as a possible response to this problem. In line with this framework, a description of recycled systems was provided in which stable products can be activated back to reactive compounds. The dynamical behavior of such systems relies on the presence of a source of energy, leading to the continuous maintaining of unidirectional reaction loops. A full thermodynamic study of recycled systems, composed of microreversible reactions only, is presented here, showing how the energy is transferred and distributed through the system, leading to cycle competitions and the stabilization of asymmetric states. PMID:19239210

  19. Asymmetric Rab 11 endosomes regulate delta recycling and specify cell fate in the Drosophila nervous system.

    PubMed

    Emery, Gregory; Hutterer, Andrea; Berdnik, Daniela; Mayer, Bernd; Wirtz-Peitz, Frederik; Gaitan, Marcos Gonzalez; Knoblich, Juergen A

    2005-09-01

    Drosophila sensory organ precursor (SOP) cells are a well-studied model system for asymmetric cell division. During SOP division, the determinants Numb and Neuralized segregate into the pIIb daughter cell and establish a distinct cell fate by regulating Notch/Delta signaling. Here, we describe a Numb- and Neuralized-independent mechanism that acts redundantly in cell-fate specification. We show that trafficking of the Notch ligand Delta is different in the two daughter cells. In pIIb, Delta passes through the recycling endosome which is marked by Rab 11. In pIIa, however, the recycling endosome does not form because the centrosome fails to recruit Nuclear fallout, a Rab 11 binding partner that is essential for recycling endosome formation. Using a mammalian cell culture system, we demonstrate that recycling endosomes are essential for Delta activity. Our results suggest that cells can regulate signaling pathways and influence their developmental fate by inhibiting the formation of individual endocytic compartments. PMID:16137758

  20. Reduction of dioxin-like compound emissions from a Waelz plant with adsorbent injection and a dual baghouse filter system.

    PubMed

    Chi, Kai Hsien; Chang, Shu Hao; Chang, Moo Been

    2008-03-15

    Previous study indicates that the polychlorinated dibenzo-p-dioxin and -dibenzofurans (PCDD/F) concentration measured in the stack gas of the Waelz plant investigated reached 194 ng-TEQ/(N m3) (TEQ = toxic equivalence), due to the relatively high potential of PCDD/F formation and a low PCDD/F removal efficiency (<70%) achieved with the baghouse filter (BF). In September 2006, the Taiwan government setthe PCDD/F emission limit for existing Waelz plants as 1.0 ng-I-TEQO/(N m3). The retrofit technology for reducing PCDD/F emissions from the existing Waelz plant was evaluated at the same time. Carbon-type adsorbent injection technology was adopted in early 2006 to reduce the emission of dioxin-like compounds at the Waelz plant investigated. Flue gases and ambient air samplings were conducted during the two stages of retrofit to evaluate the removal efficiency of dioxin-like compounds at the Waelz plant investigated. At stage 1, by applying adsorbent injection + single baghouse filter (SBF), the PCDD/F and polychlorinated biphenyl (PCB) concentrations measured in the stack gas at the Waelz plant were 4.62 ng-TEQ/(N m3) and 0.08 ng-TEQ(WHO)/(N m3) (TEQ(WHO) = World Health Organization TEQ), respectively, as the adsorbent injection rate was controlled at 40 kg/h (or 540 mg/ (N m3)). At stage 2, the PCDD/F and PCB concentration measured at stack gas, achieved with adsorbent injection + dual baghouse filter (DBF) system, were further reduced to 0.235 + 0.04 ng-I-TEQ/(N m3) (I-TEQ = International TEQ) and 0.004 + 0.002 ng-TEQ(WHO)/(N m3) with the adsorbent injection rate at 16 kg/h (or 215 mg/(N m3)). In the meantime, the atmospheric PCDD/F concentrations measured in the vicinity area of the Waelz plant were greatly reduced from 568-1465 to 48.9-130 fg-I-TEQ/m3. Higher removal efficiency (>99.8%) achieved at a lower adsorbent injection rate (16 kg/h) of the adsorbent injection + DBF system also significantly reduced the total PCDD/-F and PCB emission flows (per kg of

  1. Dynamics of Molecules Adsorbed in Zeolitic Systems: Neutron Scattering and MD Simulation Studies

    SciTech Connect

    Mitra, S.; Sharma, V. K.; Mukhopadhyay, R.

    2011-07-15

    Zeolites represent a class of technologically important materials because of their characteristic properties of molecular sieving and catalysis, which makes them indispensable in the petroleum industries. While the catalytic properties depend upon many factors, a major role is played by the dynamics of hydrocarbon gases. In order to be able to tailor make these materials for use in industry for catalytic and sieving purposes, it is important to understand the dynamical properties of the guest molecules adsorbed in the zeolitic materials. It is of interest to study the effects of size and shape of guest molecules and also the host zeolitic structure, governing the diffusion mechanism of the adsorbed species. Here we report the results of Quasielastic Neutron Scattering (QENS) and classical molecular dynamics (MD) simulation studies of two hydrocarbons namely acetylene and propylene adsorbed in two structurally different zeolites Na-Y and ZSM-5.

  2. Tire Recycling

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Cryopolymers, Inc. tapped NASA expertise to improve a process for recycling vehicle tires by converting shredded rubber into products that can be used in asphalt road beds, new tires, hoses, and other products. In conjunction with the Southern Technology Applications Center and Stennis Space Center, NASA expertise in cryogenic fuel-handling needed for launch vehicle and spacecraft operations was called upon to improve the recycling concept. Stennis advised Cryopolymers on the type of equipment required, as well as steps to reduce the amount of liquid nitrogen used in the process. They also guided the company to use more efficient ways to control system hardware. It is estimated that more than 300 million tires nationwide are produced per year. Cryopolymers expects to reach a production rate of 5,000 tires recycled per day.

  3. Model-Based Diagnosis and Prognosis of a Water Recycling System

    NASA Technical Reports Server (NTRS)

    Roychoudhury, Indranil; Hafiychuk, Vasyl; Goebel, Kai Frank

    2013-01-01

    A water recycling system (WRS) deployed at NASA Ames Research Center s Sustainability Base (an energy efficient office building that integrates some novel technologies developed for space applications) will serve as a testbed for long duration testing of next generation spacecraft water recycling systems for future human spaceflight missions. This system cleans graywater (waste water collected from sinks and showers) and recycles it into clean water. Like all engineered systems, the WRS is prone to standard degradation due to regular use, as well as other faults. Diagnostic and prognostic applications will be deployed on the WRS to ensure its safe, efficient, and correct operation. The diagnostic and prognostic results can be used to enable condition-based maintenance to avoid unplanned outages, and perhaps extend the useful life of the WRS. Diagnosis involves detecting when a fault occurs, isolating the root cause of the fault, and identifying the extent of damage. Prognosis involves predicting when the system will reach its end of life irrespective of whether an abnormal condition is present or not. In this paper, first, we develop a physics model of both nominal and faulty system behavior of the WRS. Then, we apply an integrated model-based diagnosis and prognosis framework to the simulation model of the WRS for several different fault scenarios to detect, isolate, and identify faults, and predict the end of life in each fault scenario, and present the experimental results.

  4. The As-Cu-Ni System: A Chemical Thermodynamic Model for Ancient Recycling

    NASA Astrophysics Data System (ADS)

    Sabatini, Benjamin J.

    2015-12-01

    This article is the first thermodynamically reasoned ancient metal system assessment intended for use by archaeologists and archaeometallurgists to aid in the interpretation of remelted/recycled copper alloys composed of arsenic and copper, and arsenic, copper, and nickel. These models are meant to fulfill two main purposes: first, to be applied toward the identification of progressive and regressive temporal changes in artifact chemistry that would have occurred due to recycling, and second, to provide thermodynamic insight into why such metal combinations existed in antiquity. Built on well-established thermodynamics, these models were created using a combination of custom-written software and published binary thermodynamic systems data adjusted to within the boundary conditions of 1200°C and 1 atm. Using these parameters, the behavior of each element and their likelihood of loss in the binaries As-Cu, As-Ni, Cu-Ni, and ternary As-Cu-Ni, systems, under assumed ancient furnace conditions, was determined.

  5. A model for simulating the grinding and classification cyclic system of waste PCBs recycling production line.

    PubMed

    Yang, Deming; Xu, Zhenming

    2011-09-15

    Crushing and separating technology is widely used in waste printed circuit boards (PCBs) recycling process. A set of automatic line without negative impact to environment for recycling waste PCBs was applied in industry scale. Crushed waste PCBs particles grinding and classification cyclic system is the most important part of the automatic production line, and it decides the efficiency of the whole production line. In this paper, a model for computing the process of the system was established, and matrix analysis method was adopted. The result showed that good agreement can be achieved between the simulation model and the actual production line, and the system is anti-jamming. This model possibly provides a basis for the automatic process control of waste PCBs production line. With this model, many engineering problems can be reduced, such as metals and nonmetals insufficient dissociation, particles over-pulverizing, incomplete comminuting, material plugging and equipment fever. PMID:21764511

  6. Ion-exchange chromatography separation applied to mineral recycle in closed systems

    NASA Technical Reports Server (NTRS)

    Ballou, E.; Spitze, L. A.; Wong, F. W.; Wydeven, T.; Johnson, C. C.

    1981-01-01

    As part of the controlled ecological life support system (CELSS) program, a study is being made of mineral separation on ion-exchange columns. The purpose of the mineral separation step is to allow minerals to be recycled from the oxidized waste products of plants, man, and animals for hydroponic food production. In the CELSS application, relatively large quantities of minerals in a broad concentration range must be recovered by the desired system, rather than the trace quantities and very low concentrations treated in analytical applications of ion-exchange chromatography. Experiments have been carried out to assess the parameters pertinent to the scale-up of ion-exchange chromatography and to determine feasibility. Preliminary conclusions are that the column scale-up is in a reasonable size range for the CELSS application. The recycling of a suitable eluent, however, remains a major challenge to the suitability of using ion exchange chromatography in closed systems.

  7. Low-temperature scanning tunneling microscopy and transport measurements on adsorbate-induced two-dimensional electron systems

    SciTech Connect

    Masutomi, Ryuichi; Triyama, Naotaka; Okamoto, Tohru

    2013-12-04

    We have performed not only magnetotransport measurements on two-dimensional electron systems (2DESs) formed at the cleaved surfaces of p-InAs but also observations of the surface morphology of the adsorbate atoms, which induced the 2DES at the surfaces of narrow band-gap semiconductors, with use of a scanning tunneling microscopy. The electron density of the 2DESs is compared to the atomic density of the isolated Ag adatoms on InAs surfaces.

  8. Molecular Adsorber Coating

    NASA Technical Reports Server (NTRS)

    Straka, Sharon; Peters, Wanda; Hasegawa, Mark; Hedgeland, Randy; Petro, John; Novo-Gradac, Kevin; Wong, Alfred; Triolo, Jack; Miller, Cory

    2011-01-01

    A document discusses a zeolite-based sprayable molecular adsorber coating that has been developed to alleviate the size and weight issues of current ceramic puck-based technology, while providing a configuration that more projects can use to protect against degradation from outgassed materials within a spacecraft, particularly contamination-sensitive instruments. This coating system demonstrates five times the adsorption capacity of previously developed adsorber coating slurries. The molecular adsorber formulation was developed and refined, and a procedure for spray application was developed. Samples were spray-coated and tested for capacity, thermal optical/radiative properties, coating adhesion, and thermal cycling. Work performed during this study indicates that the molecular adsorber formulation can be applied to aluminum, stainless steel, or other metal substrates that can accept silicate-based coatings. The coating can also function as a thermal- control coating. This adsorber will dramatically reduce the mass and volume restrictions, and is less expensive than the currently used molecular adsorber puck design.

  9. Life cycle assessment of a packaging waste recycling system in Portugal

    SciTech Connect

    Ferreira, S.; Cabral, M.; Cruz, N.F. da; Simões, P.; Marques, R.C.

    2014-09-15

    Highlights: • We modeled a real packaging waste recycling system. • The analysis was performed using the life cycle assessment methodology. • The 2010 situation was compared with scenarios where the materials were not recycled. • The “Baseline” scenario seems to be more beneficial to the environment. - Abstract: Life Cycle Assessment (LCA) has been used to assess the environmental impacts associated with an activity or product life cycle. It has also been applied to assess the environmental performance related to waste management activities. This study analyses the packaging waste management system of a local public authority in Portugal. The operations of selective and refuse collection, sorting, recycling, landfilling and incineration of packaging waste were considered. The packaging waste management system in operation in 2010, which we called “Baseline” scenario, was compared with two hypothetical scenarios where all the packaging waste that was selectively collected in 2010 would undergo the refuse collection system and would be sent directly to incineration (called “Incineration” scenario) or to landfill (“Landfill” scenario). Overall, the results show that the “Baseline” scenario is more environmentally sound than the hypothetical scenarios.

  10. Modern biofuel cells for waste recycling in life support systems

    NASA Technical Reports Server (NTRS)

    Chen, L.; Bockris, J. OM.

    1989-01-01

    Innovative ways of treating urea in waste water reprocessing for long duration space exploration are being considered. Urea is very stable and therefore there are few effective ways for its decomposition. The feasibility of the use of the enzyme urease is to catalyze the hydrolysis of urea to ammonia and carbon dioxide is discussed, including a methodology, potential problems, the capabilities and advantages of such a system.

  11. Modern biofuel cells for waste recycling in life support systems

    NASA Astrophysics Data System (ADS)

    Chen, L.; Bockris, J. Om.

    1989-09-01

    Innovative ways of treating urea in waste water reprocessing for long duration space exploration are being considered. Urea is very stable and therefore there are few effective ways for its decomposition. The feasibility of the use of the enzyme urease is to catalyze the hydrolysis of urea to ammonia and carbon dioxide is discussed, including a methodology, potential problems, the capabilities and advantages of such a system.

  12. Regenerative adsorbent heat pump

    NASA Technical Reports Server (NTRS)

    Jones, Jack A. (Inventor)

    1991-01-01

    A regenerative adsorbent heat pump process and system is provided which can regenerate a high percentage of the sensible heat of the system and at least a portion of the heat of adsorption. A series of at least four compressors containing an adsorbent is provided. A large amount of heat is transferred from compressor to compressor so that heat is regenerated. The process and system are useful for air conditioning rooms, providing room heat in the winter or for hot water heating throughout the year, and, in general, for pumping heat from a lower temperature to a higher temperature.

  13. Influence of system size on the properties of a fluid adsorbed in a nanopore: Physical manifestations and methodological consequences

    SciTech Connect

    Puibasset, Joël; Kierlik, Edouard Tarjus, Gilles

    2014-07-28

    Hysteresis and discontinuities in the isotherms of a fluid adsorbed in a nanopore in general hamper the determination of equilibrium thermodynamic properties, even in computer simulations. A way around this has been to consider both a reservoir of small size and a pore of small extent in order to restrict the fluctuations of density and approach a classical van der Waals loop. We assess this suggestion by thoroughly studying through Monte Carlo simulations and density functional theory the influence of system size on the equilibrium configurations of the adsorbed fluid and on the resulting isotherms. We stress the importance of pore-symmetry-breaking states that even for modest pore sizes lead to discontinuous isotherms and we discuss the physical relevance of these states and the methodological consequences for computing thermodynamic quantities.

  14. Biomass recycle as a means to improve the energy efficiency of CELSS algal culture systems

    NASA Technical Reports Server (NTRS)

    Radmer, R.; Cox, J.; Lieberman, D.; Behrens, P.; Arnett, K.

    1987-01-01

    Algal cultures can be very rapid and efficient means to generate biomass and regenerate the atmosphere for closed environmental life support systems. However, as in the case of most higher plants, a significant fraction of the biomass produced by most algae cannot be directly converted to a useful food product by standard food technology procedures. This waste biomass will serve as an energy drain on the overall system unless it can be efficiently recycled without a significant loss of its energy content. Experiments are reported in which cultures of the alga Scenedesmus obliquus were grown in the light and at the expense of an added carbon source, which either replaced or supplemented the actinic light. As part of these experiments, hydrolyzed waste biomass from these same algae were tested to determine whether the algae themselves could be made part of the biological recycling process. Results indicate that hydrolyzed algal (and plant) biomass can serve as carbon and energy sources for the growth of these algae, suggesting that the efficiency of the closed system could be significantly improved using this recycling process.

  15. Advanced Recyclable Media System{reg_sign}. Innovative technology summary report

    SciTech Connect

    1998-12-01

    The objective of the Large-Scale Demonstration Project (LSDP) is to select and demonstrate potentially beneficial technologies at the Argonne National Laboratory East`s (ANL) Chicago Pile-5 (CP-5) Research Reactor. The purpose of the LSDP is to demonstrate that using innovative and improved deactivation and decommissioning (D and D) technologies from various sources can result in significant benefits, such as decreased cost and increased health and safety, as compared with baseline D and D technologies. This report describes a demonstration of the Advanced Recyclable Media System{reg_sign} technology which was employed by Surface Technology Systems, Inc. to remove coatings from a concrete floor. This demonstration is part of the CP-5 LSDP sponsored by the US Department of Energy (DOE) Office of Science and Technology Deactivation and Decommissioning Focus Area (DDFA). The Advanced Recyclable Media System{reg_sign} (ARMS) technology is an open blast technology which uses a soft recyclable media. The patented ARMS Engineered Blast Media consists of a fiber-reinforced polymer matrix which can be manufactured in various grades of abrasiveness. The fiber media can be remade and/or reused up to 20 times and can clean almost any surface (e.g., metal, wood, concrete, lead) and geometry including corners and the inside of air ducts.

  16. PREFERENTIAL RECYCLING/REJECTION IN CFBC/FBC SYSTEMS USING TRIBOELECTROSTATIC SEPARATION

    SciTech Connect

    Heng Ban; John M. Stencel

    2004-12-01

    Circulating Fluidized Bed Combustion (CFBC) and Fluidized Bed Combustion (FBC) with recirculation are widely used technologies in the US for power generation. They have the advantage of fuel flexibility, and low NO{sub x} and SO{sub x} emissions. Typically, as partially combusted fuel is circulated in the system, only a split stream of this circulating stream is rejected, with the remainder recycled to the combustor. As a consequence, there is unburned carbon and partially used and valuable calcium hydroxide in the reject stream. If these useful materials in the reject stream can be recovered and sent back to the combustor, the efficiency of the system will be increased significantly and the equivalent emissions will be lower. This project studies an innovative concept to incorporate triboelectric separation into CFBC/FBC systems in order to preferentially split its recycle/reject streams based on material compositions of the particles. The objective is to answer whether useful constituents, like carbon, calcium carbonate and calcium hydroxide or oxide, can be selectively separated from combustion ash at elevated temperatures. Laboratory experimental studies are performed at temperatures from 25 C to 210 C,the data from which are presented in the form of recovery curves. These curves present quality-versus-quantity information useful for predicting the efficacy of triboelectric separation as applied to CFBC/FBC byproduct recycling and/or rejection.

  17. Inversion of type of separation system in planar chromatography of peptides, using C18 silica-based adsorbents.

    PubMed

    Gwarda, Radosław Ł; Aletańska-Kozak, Monika; Matosiuk, Dariusz; Dzido, Tadeusz H

    2016-04-01

    Our previous results show, that C18 silica-based adsorbents used in high-performance thin-layer chromatography (HPTLC), provide complex retention mechanism basing on various polar and nonpolar interactions. Here we present, that in chromatography of peptides, due to mixed-mode properties of these adsorbents, there is a simple way to obtain inversion of separation system type (from reversed-phase, RP, to normal-phase, NP, and vice versa). The results presented provide detailed information how to obtain inversion mentioned and reflect the extent (the type and concentration of organic solvent, the type and concentration of ion-pairing reagent in the mobile phase) of this phenomenon. We show, that the system type inversion results in significant change of selectivity of separation, which may be especially useful in 2D separation of complex samples of basic/amphoteric compounds such as peptides. This results from the fact, that C18 silica-based HPTLC adsorbents, may be used in hydrophilic interaction chromatography (HILIC) or RP chromatography, in dependence on mobile phase composition. PMID:26944834

  18. ECO-WALL SYSTEMS: USING RECYCLED MATERIAL IN THE DESIGN OF COMMERCIAL INTERIOR WALL SYSTEMS FOR BUILDINGS

    EPA Science Inventory

    This proposal describes an interdisciplinary project involving students from several academic departments at Miami University in the design of commercial wall systems to be manufactured from recycled materials. The goal of Phase I of the project is to develop and conduct prelimi...

  19. Advanced Non-Destructive Assay Systems and Special Instrumentation Requirements for Spent Nuclear Fuel Recycling Facilities

    SciTech Connect

    Simpson, A.P.; Clapham, M.J.; Swinson, B.

    2008-07-01

    The safe and efficient operation of the next generation of Spent Nuclear Fuel (SNF) recycling / reprocessing facilities is dependent upon the availability of high performance real time Non- Destructive Assay (NDA) systems at key in-line points. A diverse variety of such special instrument systems have been developed and commissioned at reprocessing plants worldwide over the past fifty years.. The measurement purpose, technique and plant performance for selected key systems have been reviewed. Obsolescence issues and areas for development are identified in the context of the measurements needs of future recycling facilities and their associated waste treatment plants. Areas of concern include (i) Materials Accountancy and Safeguards, (ii) Head End process control and feed envelope verification, (iii) Real-time monitoring at the Product Finishing Stages, (iv) Criticality safety and (v) Radioactive waste characterization. Common characteristics of the traditional NDA systems in historical recycling facilities are (i) In-house development of bespoke instruments resulting in equipment that if often unique to a given facility and generally not commercially available, (ii) Use of 'novel' techniques - not widely deployed in other applications, (iii) Design features that are tailored to the specific plant requirements of the facility operator, (iv) Systems and software implementation that was not always carried out to modern industry standards and (v) A tendency to be overly complex - refined by on-plant operational usage and experience. Although these systems were 'validated in use' and are generally fit for purpose, there are a number of potential problems in transferring technology that was developed ten or more years ago to the new build SNF recycling facilities of the future. These issues include (i) Obsolescence of components - particularly with respect to computer hardware and data acquisition electronics, (ii) Availability of Intellectual Property and design

  20. Aquaculture of Uranium in Seawater by a Fabric-Adsorbent Submerged System

    SciTech Connect

    Seko, Noriaki; Katakai, Akio; Hasegawa, Shin; Tamada, Masao; Kasai, Noboru; Takeda, Hayato; Sugo, Takanobu; Saito, Kyoichi

    2003-11-15

    The total amount of uranium dissolved in seawater at a uniform concentration of 3 mg U/m{sup 3} in the world's oceans is 4.5 billion tons. An adsorption method using polymeric adsorbents capable of specifically recovering uranium from seawater is reported to be economically feasible. A uranium-specific nonwoven fabric was used as the adsorbent packed in an adsorption cage 16 m{sup 2} in cross-sectional area and 16 cm in height. We submerged three adsorption cages in the Pacific Ocean at a depth of 20 m at 7 km offshore of Japan. The three adsorption cages consisted of stacks of 52 000 sheets of the uranium-specific non-woven fabric with a total mass of 350 kg. The total amount of uranium recovered by the nonwoven fabric was >1 kg in terms of yellow cake during a total submersion time of 240 days in the ocean.

  1. Systemic antibody response to nano-size calcium phospate biocompatible adjuvant adsorbed HEV-71 killed vaccine

    PubMed Central

    2015-01-01

    Purpose Since 1980s, human enterovirus-71 virus (HEV-71) is one of the common infectious disease in Asian Pacific region since late 1970s without effective commercial antiviral or protective vaccine is unavailable yet. The work examines the role of vaccine adjuvant particle size and the route of administration on postvaccination antibody response towards HEV-71 vaccine adsorbed to calcium phosphate (CaP) adjuvant. Materials and Methods First, CaP nano-particles were compared to a commercial micro-size and vaccine alone. Secondly, intradermal reduced dosage was compared to the conventional intramuscular immunization. Killed HEV-71 vaccines adsorbed to CaP nano-size (73 nm) and commercial one of micro-size (1.7 µm) were administered through intradermal, intramuscular, rabbits received vaccine alone and unvaccinated animals. Results CaP nano-particles adsorbed HEV-71 vaccine displayed higher antibody than the micro-size or unadsorbed vaccine alone, through both parenteral immunization routes. Moreover, the intradermal route (0.5 µg/mL) of 0.1-mL volume per vaccine dose induced equal IgG antibody level to 1.0-mL intramuscular route (0.5 µg/mL). Conclusion The intradermal vaccine adsorbed CaP nano-adjuvant showed safer and significant antibody response after one-tenth reduced dose quantity (0.5 µg/mL) of only 0.1-mL volume as the most suitable protective, cost effective and affordable formulation not only for HEV-71; but also for developing further effective vaccines toward other human pathogens. PMID:25649429

  2. Reuse and recycling of secondary effluents in refineries employing advanced multi-barrier systems.

    PubMed

    Lahnsteiner, J; Mittal, R

    2010-01-01

    In this paper the reclamation and reuse of municipal secondary effluents, as well as the reclamation and recycling of refinery secondary effluents, are technically and economically evaluated. It is shown that both practices are feasible and sustainable, and that the reclamation costs depend largely on specific circumstances such as legal requirements, price policy, reuse application, raw water composition, etc. The reclaimed water is reused, or respectively recycled, as boiler make-up. Therefore both reclamation plants employ advanced multi-barrier systems including ultra-filtration and reverse osmosis. The employed processes have shown excellent performance with regard to the removal of critical parameters such as silica. For example, this parameter was reduced from 13 mg/l in the raw water to 7 μg/l in the boiler make-up. PMID:20962397

  3. Solution- and Adsorbed-State Structural Ensembles Predicted for the Statherin-Hydroxyapatite System

    PubMed Central

    Masica, David L.; Gray, Jeffrey J.

    2009-01-01

    Abstract We have developed a multiscale structure prediction technique to study solution- and adsorbed-state ensembles of biomineralization proteins. The algorithm employs a Metropolis Monte Carlo-plus-minimization strategy that varies all torsional and rigid-body protein degrees of freedom. We applied the technique to fold statherin, starting from a fully extended peptide chain in solution, in the presence of hydroxyapatite (HAp) (001), (010), and (100) monoclinic crystals. Blind (unbiased) predictions capture experimentally observed macroscopic and high-resolution structural features and show minimal statherin structural change upon adsorption. The dominant structural difference between solution and adsorbed states is an experimentally observed folding event in statherin's helical binding domain. Whereas predicted statherin conformers vary slightly at three different HAp crystal faces, geometric and chemical similarities of the surfaces allow structurally promiscuous binding. Finally, we compare blind predictions with those obtained from simulation biased to satisfy all previously published solid-state NMR (ssNMR) distance and angle measurements (acquired from HAp-adsorbed statherin). Atomic clashes in these structures suggest a plausible, alternative interpretation of some ssNMR measurements as intermolecular rather than intramolecular. This work demonstrates that a combination of ssNMR and structure prediction could effectively determine high-resolution protein structures at biomineral interfaces. PMID:19383454

  4. When sink becomes source: Importance of sediment recycling in linked orogen-basin systems

    NASA Astrophysics Data System (ADS)

    Romans, Brian W.; Fosdick, Julie C.; Hubbards, Stephen M.; Fildani, Andrea

    2013-04-01

    Much of the recent research on sedimentary system dynamics has focused on extant systems where the linkage of sediment production from eroding highlands can be directly linked to deposition in lowlands and/or offshore basins. Studies of such systems, typically late Pleistocene to Holocene in age, are especially valuable for quantitative constraints such as system morphometrics (e.g., longitudinal profiles, basin volumes, etc.) and rates of processes (e.g., erosion/denudation, sediment accumulation, etc.), which can be measured directly or estimated with relatively high certainty. Moreover, information about climate and tectonic forcings that are independent to the system is explicitly known for extant systems. However, an understanding of longer-term (>105 yr) evolution can only be gained through the investigation of ancient systems. Such systems are either buried in the subsurface, which requires geophysical remote sensing and/or drilling, or exposed at the Earth's surface as outcrops as the result of uplift and exhumation. The dynamic linkage of mountain belt and adjacent basin makes foreland basin systems ideal natural laboratories to address long-term sedimentary system evolution. In this presentation, we highlight important issues and challenges that sedimentary systems research is currently facing, with an emphasis on sediment recycling during progressive stages of basin development. In this context, we focus on sedimentary systems in which multiple episodes of uplift and erosion of the primary depocenter led to a history whereby basin material was repeatedly recycled. The spatial and temporal aspects of sediment recycling have implications for how provenance signals (based on composition, crystallization or metamorphic age information, thermal history, etc.) are used. Additionally, improved constraints regarding the timescales and magnitude of sediment recycling have implications for system-scale modeling. Key parameters such as total sediment volumes and

  5. Application of portable fluorescence spectrophotometry for integrity testing of recycled water dual distribution systems.

    PubMed

    Hambly, Adam C; Henderson, Rita K; Baker, Andy; Stuetz, Richard M; Khan, Stuart J

    2015-01-01

    Water utilities supplying recycled water to households via a "third-pipe" or "dual reticulation" system have a need for a rapid, portable method to detect cross-connections within potable water reticulation networks. This study evaluates portable fluorimetry as a technique for cross-connection detection in the field. For the first time, an investigation of a full-scale dual reticulation water-recycling network has been carried out to identify cross-connections using a portable fluorimeter. We determined that this can be carried out with a 3 mL water sample, and unlike methods that are currently in use for cross-connection detection, can be achieved quickly without disruption to water flow or availability within the network. It was also revealed that fluorescence trigger values could be established with high levels of confidence by sampling less than 2.5% of the network. Fluorescence analysis was also able to uncover a single, real cross-connection event. As such, this paper is a fundamental demonstration of fluorescence as a reliable, highly portable technique for cross-connection detection within dual reticulation water recycling networks and further establishes the abilities of fluorescence devices as valuable field instruments for water quality monitoring. PMID:25506735

  6. Evaluation of concrete recycling system efficiency for ready-mix concrete plants.

    PubMed

    Vieira, Luiz de Brito Prado; Figueiredo, Antonio Domingues de

    2016-10-01

    The volume of waste generated annually in concrete plants is quite large and has important environmental and economic consequences. The use of fresh concrete recyclers is an interesting way for the reuse of aggregates and water in new concrete production. This paper presents a study carried out for over one year by one of the largest ready-mix concrete producers in Brazil. This study focused on the evaluation of two recyclers with distinct material separation systems, herein referred to as drum-type and rotary sieve-type equipment. They were evaluated through characterization and monitoring test programs to verify the behaviour of recovered materials (aggregates, water, and slurry). The applicability of the recovered materials (water and aggregates) was also evaluated in the laboratory and at an industrial scale. The results obtained with the two types of recyclers used were equivalent and showed no significant differences. The only exception was in terms of workability. The drum-type recycler generated fewer cases that required increased pumping pressure. The analysis concluded that the use of untreated slurry is unfeasible because of its intense negative effects on the strength and workability of concrete. The reclaimed water, pre-treated to ensure that its density is less than 1.03g/cm(3), can be used on an industrial scale without causing any harm to the concrete. The use of recovered aggregates consequently induces an increase in water demand and cement consumption to ensure the workability conditions of concrete that is proportional to the concrete strength level. Therefore, the viability of their use is restricted to concretes with characteristic strengths lower than 25MPa. PMID:27478022

  7. Microwave Schottky diagnostic systems for the Fermilab Tevatron, Recycler, and CERN LHC

    SciTech Connect

    Pasquinelli, Ralph J.; Jansson, Andreas; /ESS, Lund

    2011-02-01

    A means for non-invasive measurement of transverse and longitudinal characteristics of bunched beams in synchrotrons has been developed based on high sensitivity slotted waveguide pickups. The pickups allow for bandwidths exceeding hundreds of MHz while maintaining good beam sensitivity characteristics. Wide bandwidth is essential to allow bunch-by-bunch measurements by means of a fast gating system. The Schottky detector system is installed and successfully commissioned in the Fermilab Tevatron and Recycler and CERN LHC synchrotrons. Measurement capabilities include tune, chromaticity, and momentum spread of single or multiple beam bunches in any combination. With appropriate calibrations, emittance can also be measured by integrating the area under the incoherent tune sidebands.

  8. Recycling decision support system: Design and development of a Web-based DSS. Master thesis

    SciTech Connect

    Tettelbach, C.G.

    1997-03-01

    The explosive growth of the World Wide Web creates new opportunities for the development and deployment of Decision Support Systems. No longer restricted by machine-specific limitations, Web-based Decision Support Systems (DSS) provide global access to widely diversified and geographically dispersed users through sharing of data, models, algorithms, and modeling environments. This thesis examines the design and development processes involved in the creation of a Web-based DSS. The Recycling Decision Support System utilizes a rapid prototype and refinement process to create a Web-based system focusing on supporting ordinary people and industrial users in making good decisions for recycling and disposal of household and industrial waste. Through abstraction of details from the specific Web-based DSS design, a generalized framework for supporting decision-making via the WWW is built which supports functionality in education, queries, and analysis of complex problems. An important aspect of this research is the development of a new architecture which conforms to the complexities specific to Web-based Decision Support Systems. Prompted by the additional interactions required for WWW connectivity, this architecture incorporates agents for negotiating transactions between the functional components of a standard DSS.

  9. Influence of carboxylic ion-pairing reagents on retention of peptides in thin-layer chromatography systems with C18 silica-based adsorbents.

    PubMed

    Gwarda, Radosław Ł; Aletańska-Kozak, Monika; Klimek-Turek, Anna; Ziajko-Jankowska, Agnieszka; Matosiuk, Dariusz; Dzido, Tadeusz H

    2016-04-01

    One of the main problems related to chromatography of peptides concerns adverse interactions of their strong basic groups with free silanol groups of the silica based stationary phase. Influence of type and concentration of ion-pairing regents on peptide retention in reversed-phase high-performance liquid chromatography (RP-HPLC) systems has been discussed before. Here we present influence of these mobile phase additives on retention of some peptide standards in high-performance thin-layer chromatography (HPTLC) systems with C18 silica-based adsorbents. We prove, that due to different characteristic of adsorbents used in both techniques (RP HPLC and HPTLC), influence of ion-pairing reagents on retention of basic and/or amphoteric compounds also may be quite different. C18 silica-based HPTLC adsorbents provide more complex mechanism of retention and should be rather considered as mixed-mode adsorbents. PMID:26944833

  10. Mechatronic Design and Control of a Waste Paper Sorting System for Efficient Recycling

    SciTech Connect

    Venditti, R. A.; Ramasubramanian, M. K.

    2007-11-13

    Sorting of paper into compatible grades is a necessary step prior to recycling. Current method of manually sorting is tedious, slow, and expensive. Hence, significant part of the waste paper stream is sent to the landfill. High speed automation of the sorting process will improve the cost efficiency and increase the amount of paper recycled significantly. There have been recent developments in automation of this process. Mechanisms for the distribution of the papers from a bale onto a moving conveyor and the pneumatic actuation to deflect papers into different streams are well established. Correct identification of the sample in real-time before the sample reaches the actuation station still remains a challenge since different types of paper and board samples are mixed in a waste stream, and has a lot of variation in terms of color, chemical composition, coating, and prints in black and white and color to different degrees. This is primarily due to the lack of satisfactory sensors and sensor fusion algorithms for sample identification in real-time. In this report, we identify key parameters that must be measured (lignin, stiffness, color gloss), sensor design, and integration of the output from sensors to interpret the type of sample using a fuzzy inference system. Results show that the sensor system proposed is capable of identifying the samples at 90% accuracy. The sensor system can be integrated onto a conveyor and actuation system for automated sorting.

  11. Beam manipulation and compression using broadband rf systems in the Fermilab Main Injector and Recycler

    SciTech Connect

    G William Foster et al.

    2004-07-09

    A novel method for beam manipulation, compression, and stacking using a broad band RF system in circular accelerators is described. The method uses a series of linear voltage ramps in combination with moving barrier pulses to azimuthally compress, expand, or cog the beam. Beam manipulations can be accomplished rapidly and, in principle, without emittance growth. The general principle of the method is discussed using beam dynamics simulations. Beam experiments in the Fermilab Recycler Ring convincingly validate the concept. Preliminary experiments in the Fermilab Main Injector to investigate its potential for merging two ''booster batches'' to produce high intensity proton beams for neutrino and antiproton production are described.

  12. Feed-forward control of a solid oxide fuel cell system with anode offgas recycle

    NASA Astrophysics Data System (ADS)

    Carré, Maxime; Brandenburger, Ralf; Friede, Wolfgang; Lapicque, François; Limbeck, Uwe; da Silva, Pedro

    2015-05-01

    In this work a combined heat and power unit (CHP unit) based on the solid oxide fuel cell (SOFC) technology is analysed. This unit has a special feature: the anode offgas is partially recycled to the anode inlet. Thus it is possible to increase the electrical efficiency and the system can be operated without external water feeding. A feed-forward control concept which allows secure operating conditions of the CHP unit as well as a maximization of its electrical efficiency is introduced and validated experimentally. The control algorithm requires a limited number of measurement values and few deterministic relations for its description.

  13. Highly Efficient and Facile Photocatalytic Recycling System Suitable for ICAR ATRP of Hydrophilic Monomers.

    PubMed

    Jiang, Xiaowu; Zhang, Lifen; Cheng, Zhenping; Zhu, Xiulin

    2016-08-01

    Photoinduced initiators for continuous activator regeneration atom transfer radical polymerization (ATRP) of hydrophilic monomers in heptane/ethanol latent-biphasic system for copper catalyst separation and recycling have been realized for the first time at room temperature with different wavelengths of visible light LED (green, blue, purple, and white LED) as external stimulus, using 2-bromophenylacetate as the ATRP initiator and camphorquinone/triethylamine as the photoinitiator. In this system, hybrid catalyst complex (HCc) is synthesized as a novel nonpolar catalyst, which is preferentially dissolved in heptane. The hydrophilic polymers obtained catalyzed by HCc in heptane/ethanol mixture solvent show typical "living" features, for example, the values of Mn,GPC increase linearly with monomer conversion up to quantitative level (>96%) and the molecular weight distributions were kept narrow (Mw /Mn < 1.20) throughout the polymerization process. It should be noted that the excellent controllability of this novel polymerization system can be achieved even after 5 catalyst recycling experiments under LED irradiation. PMID:27296245

  14. Recycling of Na in advanced life support: strategies based on crop production systems.

    PubMed

    Guntur, S V; Mackowiak, C; Wheeler, R M

    1999-01-01

    Sodium is an essential dietary requirement in human nutrition, but seldom holds much importance as a nutritional element for crop plants. In Advanced Life Support (ALS) systems, recycling of gases, nutrients, and water loops is required to improve system closure. If plants are to play a significant role in recycling of human wastes, Na will need to accumulate in edible tissues for return to the crew diet. If crops fail to accumulate the incoming Na into edible tissues, Na could become a threat to the hydroponic food production system by increasing the nutrient solution salinity. Vegetable crops of Chenopodiaceae such as spinach, table beet, and chard may have a high potential to supply Na to the human diet, as Na can substitute for K to a large extent in metabolic processes of these crops. Various strategies are outlined that include both genetic and environmental management aspects to optimize the Na recovery from waste streams and their resupply through the human diet in ALS. PMID:11542242

  15. STUDY ON THE RECYCLING SYSTEM OF WASTE PLASTICS AND MIXED PAPER FROM A LONG-TERM PERSPECTIVE

    NASA Astrophysics Data System (ADS)

    Fujii, Minoru; Fujita, Tsuyoshi; Chen, Xudong; Ohnishi, Satoshi; Osako, Masahiro; Moriguchi, Yuichi; Yamaguchi, Naohisa

    Plastics and mixed paper in municipal solid waste are valuable resources with high calorific value. However, the recycling cost to utilize them tends to be expensive. In addition, recycling system has to be consistent with the reduce of wastes on which should be put higher-priority to lower carbon emission and save resources in the long term. In this paper, we proposed a recycling system (smart recycling system) which consists of a local center an d existing facilities in arterial industries. In the local center, collected waste plastics and mixed paper from household are processed on the same line into a form suitable for transportation and handling in a facility of arterial in dustry which can utilize those wastes effectively. At the same time, a part of plastics with high quality is processed into a recycled resin in the center. It was suggested that, by utilizing existing facilities in arterial industries which have enough and flexible capacity to accept those wastes, the system can be a robust system even if the amount of wastes generation fluctuates widely. The effect of CO2 reduction and cost by installing the system were calculated and it was estimated that 3.5 million ton of additional annual CO2 reduction could be brought in Tokyo and surrounding three prefectures without co nsiderable increase in cost.

  16. Type of adsorbent and column height in adsorption process of used cooking oil

    NASA Astrophysics Data System (ADS)

    Hasnelly, Hervelly, Taufik, Yusman; Melany, Ivo Nila

    2015-12-01

    The purpose of this research was to find out the best adsorbent and column height that can adsorb color and soluble impurities substances in used cooking oil. This research was meant for knowledge development of refined cooking oil technology. The used of this research was giving out information on the recycling process of used cooking oil. Research design used 2 × 2 factorial pattern in randomized group design with 6 repetitions. The first factor is adsorbent type (J) that consist of activated carbon (J1) and Zeolit (J2). The second factor is column height (K) with variations of 15 cm (k1) and 20 cm (k2). Chemical analysis parameter are free fatty acid, water content and saponification value. Physical parameter measurement was done on color with Hunter Lab system analysis and viscosity using viscometer method. Chemical analysis result of preliminary research on used cooking oil showed water content of 1,9%, free fatty acid 1,58%, saponification value 130,79 mg KOH/g oil, viscosity 0,6 d Pas and color with L value of -27,60, a value 1,04 and b value 1,54. Result on main research showed that adsorbent type only gave effect on water content whereas column height and its interaction was not gave significant effect on water content. Interaction between adsorbent type (J) and column height (K) gave significant effect to free fatty acid, saponification value, viscosity and color for L, a and b value of recycled cooking oil.

  17. Apparatus and method for removing solvent from carbon dioxide in resin recycling system

    DOEpatents

    Bohnert, George W.; Hand, Thomas E.; DeLaurentiis, Gary M.

    2009-01-06

    A two-step resin recycling system and method solvent that produces essentially contaminant-free synthetic resin material. The system and method includes one or more solvent wash vessels to expose resin particles to a solvent, the solvent contacting the resin particles in the one or more solvent wash vessels to substantially remove contaminants on the resin particles. A separator is provided to separate the solvent from the resin particles after removal from the one or more solvent wash vessels. The resin particles are next exposed to carbon dioxide in a closed loop carbon dioxide system. The closed loop system includes a carbon dioxide vessel where the carbon dioxide is exposed to the resin, substantially removing any residual solvent remaining on the resin particles after separation. A separation vessel is also provided to separate the solvent from the solvent laden carbon dioxide. Both the carbon dioxide and the solvent are reused after separation in the separation vessel.

  18. Transverse digital damper system for the Fermilab anti-proton recycler

    SciTech Connect

    Eddy, N.; Crisp, J.; /Fermilab

    2006-05-01

    A transverse damping system is used in the Recycler at Fermilab to damp beam instabilities which arise from large beam intensities with electron cooling. Initial tests of electron cooling demonstrated beam loss due to transverse beam motion when the beam was cooled past the beam density threshold. The transverse damper system consists of two horizontal and two vertical pickups whose signals are amplified and passed into an analog hybrid to generate a difference signal from each pickup. The difference signals are input to a custom digital damper board which digitizes the analog signals at 212mhz, performs digital processing of the signals inside a large Altera Stratix II FPGA, then provides analog output at 212mhz via digital to analog converters. The digital damper output is sent to amplifiers which drive one horizontal and one vertical kicker. An initial prototype digital damper board has been successfully used in the Recycler for over six months. Currently, work is underway to replace the prototype board with an upgraded VME version.

  19. Transverse Digital Damper System for the Fermilab Anti-Proton Recycler

    SciTech Connect

    Eddy, N.; Crisp, J.; Hu, M.

    2006-11-20

    A transverse damping system is used in the Recycler at Fermilab to damp beam instabilities which arise from large beam intensities with electron cooling. Initial tests of electron cooling demonstrated beam loss due to transverse beam motion when the beam was cooled past the beam density threshold. The transverse damper system consists of two horizontal and two vertical pickups whose signals are amplified and passed into an analog hybrid to generate a difference signal from each pickup. The difference signals are input to a custom digital damper board which digitizes the analog signals at 212MHz, performs digital processing of the signals inside a large Altera Stratix II FPGA, then provides analog output at 212MHz via digital to analog converters. The digital damper output is sent to amplifiers which drive one horizontal and one vertical kicker. An initial prototype digital damper board has been successfully used in the Recycler for over six months. Currently, work is underway to replace the prototype board with an upgraded VME version.

  20. Gold coast seaway smartrelease decision support system: optimising recycled water release in a sub tropical estuarine environment.

    PubMed

    Stuart, G; Hollingsworth, A; Thomsen, F; Szylkarski, S; Khan, S; Tomlinson, R; Kirkpatrick, S; Catterall, K; Capati, B

    2009-01-01

    Gold Coast Water is responsible for the management of the water, recycled water and wastewater assets of the City of the Gold Coast on Australia's east coast. Excess treated recycled water is released at the Gold Coast Seaway, a man-made channel connecting the Broadwater Estuary with the Pacific Ocean, on an outgoing tide in order for the recycled water to be dispersed before the tide changes and re-enters the Broadwater estuary. Rapid population growth has placed increasing demands on the city's recycled water release system and an investigation of the capacity of the Broadwater to assimilate a greater volume of recycled water over a longer release period was undertaken in 2007. As an outcome, Gold Coast Water was granted an extension of the existing release licence from 10.5 hours per day to 13.3 hours per day from the Coombabah wastewater treatment plant (WWTP). The Seaway SmartRelease Project has been designed to optimise the release of the recycled water from the Coombabah WWTP in order to minimise the impact to the receiving estuarine water quality and maximise the cost efficiency of pumping. In order achieve this; an optimisation study that involves intensive hydrodynamic and water quality monitoring, numerical modelling and a web-based decision support system is underway. An intensive monitoring campaign provided information on water levels, currents, winds, waves, nutrients and bacterial levels within the Broadwater. This data was then used to calibrate and verify numerical models using the MIKE by DHI suite of software. The Decision Support System will then collect continually measured data such as water levels, interact with the WWTP SCADA system, run the numerical models and provide the optimal time window to release the required amount of recycled water from the WWTP within the licence specifications. PMID:19844054

  1. Plasma exchange-based plasma recycling dialysis system as a potential platform for artificial liver support.

    PubMed

    Nishimura, Akimasa; Umehara, Yutaka; Umehara, Minoru; Hakamada, Kenichi; Narumi, Shunji; Toyoki, Yoshikazu; Yoshihara, Shuichi; Sasaki, Mutsuo

    2006-08-01

    We developed a plasma recycling dialysis (PRD) system based on plasma exchange (PE). In this system, rapid reduction of toxic substances and restitution of deficient essential substances are performed by PE, and subsequent blood purification is performed by dialysis between separated plasma recycled over a purification device and the patient's blood across the membrane of the plasma separator. This study was performed to demonstrate the safety and efficacy of this system. Hyperbilirubinemia was induced by ligating the bile duct in pigs, and 7 days later, only PE for 2 h (group PE) or PE for 2 h followed by PRD for 6 h (group PE + PRD) was performed. The separated plasma was recycled over anion-exchange resin through the extra fiber space of the plasma separator. The safety and efficacy of this system were evaluated based on the values of hemodynamic and laboratory parameters. Transfer from PE to PRD was completed in a few minutes. The hemodynamic status and blood cells counts were stable and hemolysis was not observed during the procedure. In the PE + PRD group, the concentrations of total bile acids continuously decreased (pretreatment, 155.5 +/- 40.6 microM; 2 h [end of PE], 76.1 +/- 14.4 microM; 8 h [end of PRD], 25.8 +/- 9.1 microM) and the value was significantly lower than in the PE group after 6 h. The total bilirubin also continuously decreased during PRD (pretreatment, 55.3 +/- 11.5 microM; 2 h [end of PE], 33.8 +/- 8.4 microM; 8 h [end of PRD], 18.6 +/- 7.7 microM) and was significantly lower than in the PE group after 4 h. No significant change was observed in other laboratory values. This PE-based PRD system allowed a swift transfer from PE to sorbent-based blood purification. The safety of this system was demonstrated and the removal of toxic substances was significant. This study confirmed the clinical utility of this system as a platform for artificial liver support. PMID:16911318

  2. Beneficial uses of recycled asphalt-stabilized products as landfill cover and capping systems

    SciTech Connect

    Camougis, G.

    1996-12-31

    The American Reclamation Corporation (AMREC{reg_sign}) has played a major role in the development of new programs for the recycling of discarded materials from construction, demolition, remediation and manufacturing operations. Excavated petroleum-contaminated soils (oily soils), asphalt paving, concrete rubble, and discarded asphalt roofing shingles have been processed and recycled into beneficially useful construction products. AMREC uses a cold-mix, asphalt-emulsion technology to process many of the recyclables received at its recycling facility in Charlton, MA. Recyclable materials are processed and blended to produce recycled, asphalt-stabilized products. In addition, recycled, asphalt-stabilized products are being investigated and tested for other beneficial uses. This includes their uses as capping materials and as containment materials.

  3. Life cycle assessment of a packaging waste recycling system in Portugal.

    PubMed

    Ferreira, S; Cabral, M; da Cruz, N F; Simões, P; Marques, R C

    2014-09-01

    Life Cycle Assessment (LCA) has been used to assess the environmental impacts associated with an activity or product life cycle. It has also been applied to assess the environmental performance related to waste management activities. This study analyses the packaging waste management system of a local public authority in Portugal. The operations of selective and refuse collection, sorting, recycling, landfilling and incineration of packaging waste were considered. The packaging waste management system in operation in 2010, which we called "Baseline" scenario, was compared with two hypothetical scenarios where all the packaging waste that was selectively collected in 2010 would undergo the refuse collection system and would be sent directly to incineration (called "Incineration" scenario) or to landfill ("Landfill" scenario). Overall, the results show that the "Baseline" scenario is more environmentally sound than the hypothetical scenarios. PMID:24910140

  4. In situ combined chemical and biological assessment of estrogenic pollution in a water recycling system.

    PubMed

    Chi, Yulang; Huang, Qiansheng; Zhang, Huanteng; Chen, Yajie; Dong, Sijun

    2016-05-01

    Estrogenic pollution and its control in aquatic systems have drawn substantial attention around the world. The chemical and biological assessment approaches currently utilized in the laboratory or field cannot give an integrated assessment of the pollution when used separately. In this study, in situ chemical and biological methods were combined to detect pollution in a water recycling system. Data for the water quality index (WQI) demonstrated that the water treatment resulted in the decline of pollution from upstream to downstream. Wild male Nile tilapia, Oreochromis niloticus, was sampled in June and September. The concentrations of four common endocrine disrupting chemicals (EDCs) were determined in the tilapia liver by chromatographic analysis methods. The level of 17β-estradiol (E2) declined from upstream to downstream in both months. In contrast, the levels of bisphenol A (BPA), di-(2-ethylhcxyl) phthalate (DEHP), and perfluorooctane sulfonate (PFOS) did not display this declining tendency. The highest relative expression of vitellogenin 1 (VTG1) was observed in tilapia from upstream, then the level significantly decreased along the water system. The relative expression levels of CYP1A1 in the water system were also significantly higher than that of the control. However, no declining trend could be observed along the water system. The change of VTG1 expression corresponded well with that of E2 levels in the tilapia liver. Overall, our study assessed the pollution by endocrine disruptors using chemical and biological data with good correspondence. This study also demonstrated the effectiveness of the water recycling system in eliminating estrogen pollution in municipal sewage. PMID:27155427

  5. Hanford recycling

    SciTech Connect

    Leonard, I.M.

    1996-09-01

    This paper is a study of the past and present recycling efforts on the Hanford site and options for future improvements in the recycling program. Until 1996, recycling goals were voluntarily set by the waste generators: this year, DOE has imposed goals for all its sites to accomplish by 1999. Hanford is presently meeting the voluntary site goals, but may not be able to meet all the new DOE goals without changes to the program. Most of these new DOE goals are recycling goals: * Reduce the generation of radioactive (low-level) waste from routine operations 50 percent through source reduction and recycling. * Reduce the generation of low-level mixed waste from routine operations 50 percent through source reduction and recycling. * Reduce the generation of hazardous waste from routine operations 50 percent through source reduction and recycling. * Recycle 33 percent of the sanitary waste from all operations. * Increase affirmative procurement of EPA-designated recycled items to 100 percent. The Hanford recycling program has made great strides-there has been a 98 percent increase in the amount of paper recycled since its inception in 1990. Hanford recycles paper, chemicals cardboard, tires, oil, batteries, rags, lead weights, fluorescent tubes, aerosol products, concrete, office furniture, computer software, drums, toner cartridges, and scrap metal. Many other items are recycled or reused by individual groups on a one time basis without a formal contract. Several contracts are closed-loop contracts which involve all parts of the recycle loop. Considerable savings are generated from recycling, and much more is possible with increased attention and improvements to this program. General methods for improving the recycling program to ensure that the new goals can be met are: a Contract and financial changes 0 Tracking database and methods improvements 0 Expanded recycling efforts. Specifically, the Hanford recycling program would be improved by: 0 Establishing one overall

  6. Plasma exchange-based plasma recycling dialysis system as an artificial liver support.

    PubMed

    Takahashi, Kentaro; Umehara, Yutaka; Umehara, Minoru; Nishimura, Akimasa; Narumi, Shunji; Toyoki, Yoshikazu; Hakamada, Kenichi; Yoshihara, Syuichi; Sasaki, Mutsuo

    2008-08-01

    We developed a plasma recycling dialysis (PRD) system based on plasma exchange (PE). In this system, rapid reduction of toxic substances and restitution of deficient essential substances are performed by PE and subsequent blood purification is performed by dialysis between separated plasma recycled over a purification device and the patient's blood across the membrane of a plasma separator. To demonstrate the safety and efficacy of this system, we used a pig model of fulminant hepatic failure (FHF) and anion exchange resin, activated charcoal and hemodialysis for the purification device. FHF was induced by intraportal administration of alpha-amanitine (0.1 mg/kg) and lipopolysaccharides (1 microg/kg) in pigs. Three groups of animals were studied: group 1, diseased controls (N = 4); group 2, PE group (N = 4), 16 h after drug infusion the pigs underwent PE of approximately 1.2 L for 2 h; and group 3, PE + PRD group (N = 4), the pigs underwent PE followed by PRD for 6 h. The hemodynamic status of all animals was stable during the procedure. In group 3, the values of ammonia, total bile acid and total bilirubin continuously decreased and were significantly lower than those of the animals in group 2 24 h after the induction of FHF. The Fischer ratio was significantly higher than in group 2 after 24 h. Group 3 pigs maintained a higher level of consciousness and survived longer than group 2 pigs. Safety of this PE-based PRD system was demonstrated and the removal of toxic substances was significant. This study confirmed the clinical utility of this system as an artificial liver support. PMID:18789112

  7. Nutrients recycling strategy for microalgae-based CO2 mitigation system

    NASA Astrophysics Data System (ADS)

    E, Xinyi

    Coal-fired electricity production is the major emitter of CO2 and other greenhouse gases including NOx and SO x. Microalgae-based CO2 mitigation systems have been proposed to reduce the net CO2 emission from coal-fired power plants. This study focused on developing an optimum culture media and exploring the possibilities for recycling nutrients, which were added as commercial mineralized chemicals at the beginning of cultivation. In order to release the nutrients embedded in the cells so that they can be used as a nutrient source for new cells, Scenedesmus biomass was digested by anaerobic bacteria. Results showed that thermal pretreatment enhanced the methane production rate for the first 7 days of digestion. Three operational factors were tested: heating temperature, heating duration and NaOH dosage. The combination of 10 min heating with 3˜6% NaOH at 50 °C gave the highest cell wall destruction for all samples except oven-dried algae. The anaerobic digestate, rich in mineralized nutrients including ammonium and phosphate, potassium and magnesium ions, was tested as a possible nutrient source for the algae cultivation. To cope with the high solid content of the digestates, the dosage of the digestates was reduced or the solid particles were removed prior to addition to the microalgae. Both approaches worked well in terms of providing nutrients with minimal effect on light penetration. Using digestates without any sterilization did not cause contamination or other deleterious effects on the Scenedesmus growth rate. Harvesting microalgae cells was critical to ensure a continuous and robust growth rate. The used media could be recycled at least four times without altering the algae growth. Nutrient replenishment was the key for a healthy culture when used media was incorporated. The combination of used media and digestates can sustain a normal algae growth. Life cycle assessment was conducted on the system including the photobioreactor, the anaerobic digester, the

  8. Differences in Fish, Amphibian, and Reptile Communities Within Wetlands Created by an Agricultural Water Recycling System in Northwestern Ohio

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Establishment of a water recycling system known as the wetland-reservoir subirrigation system (WRSIS) results in the creation of wetlands adjacent to agricultural fields. Each WRSIS consists of one wetland designed to process agricultural chemicals (WRSIS wetlands) and one wetland to store subirriga...

  9. Field test results for nitrogen removal by the constructed wetland component of an agricultural water recycling system

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Wetland Reservoir Subirrigation Systems (WRSIS) are innovative agricultural water recycling systems that can provide economic and environmental benefits. A constructed wetland is a main component of WRSIS, and an important function of this constructed wetland is drainage water treatment of nitrog...

  10. Recycled roads

    SciTech Connect

    Tarricone, P.

    1993-04-01

    This article examines the efforts of various states in the USA to recycle waste materials in highway construction as fill and pavements. The topics of the article include recycling used tires whole, ground, and shredded, cost of recycling, wood fiber chips as fill material in embankments, and mining wastes used to construct embankments and as coarse aggregates in asphalt pavement.

  11. The effect of aeration and effluent recycling on domestic wastewater treatment in a pilot-plant system of duckweed ponds.

    PubMed

    Ben-shalom, Miriam; Shandalov, Semion; Brenner, Asher; Oron, Gideon

    2014-01-01

    Three pilot-scale duckweed pond (DP) wastewater treatment systems were designed and operated to examine the effect of aeration and effluent recycling on treatment efficiency. Each system consisted of two DPs in series fed by pre-settled domestic sewage. The first system (duckweed+ conventional treatment) was 'natural' and included only duckweed plants. The second system (duckweed aeration) included aeration in the second pond. The third system (duckweed+ aeration+ circulation) included aeration in the second pond and effluent recycling from the second to the first pond. All three systems demonstrated similarly efficient removal of organic matter and nutrients. Supplemental aeration had no effect on either dissolved oxygen levels or on pollutant removal efficiencies. Although recycling had almost no influence on nutrient removal efficiencies, it had a positive impact on chemical oxygen demand and total suspended solids removals due to equalization of load and pH, which suppressed algae growth. Recycling also improved the appearance and growth rate of the duckweed plants, especially during heavy wastewater loads. PMID:24473305

  12. Human subjects concerns in ground based ECLSS testing - Managing uncertainty in closely recycled systems

    NASA Technical Reports Server (NTRS)

    Crump, William J.; Janik, Daniel S.; Thomas, L. Dale

    1990-01-01

    U.S. space missions have to this point used water either made on board or carried from earth and discarded after use. For Space Station Freedom, long duration life support will include air and water recycling using a series of physical-chemical subsystems. The Environmental Control and Life Support System (ECLSS) designed for this application must be tested extensively at all stages of hardware maturity. Human test subjects are required to conduct some of these tests, and the risks associated with the use of development hardware must be addressed. Federal guidelines for protection of human subjects require careful consideration of risks and potential benefits by an Institutional Review Board (IRB) before and during testing. This paper reviews the ethical principles guiding this consideration, details the problems and uncertainties inherent in current hardware testing, and presents an incremental approach to risk assessment for ECLSS testing.

  13. A novel reverse-osmosis wash water recycle system for manned space stations

    NASA Technical Reports Server (NTRS)

    Ray, R. J.; Babcock, W. C.; Barss, R. P.; Andrews, T. A.; Lachapelle, E. D.

    1984-01-01

    The preliminary development of a wash water recycle system utilizing an inside-skinned hollow-fiber membrane is described. This module configuration is based on tube-side feed and is highly resistant to fouling with a minimum of pretreatment. During an ongoing research program for NASA, these modules were operated on actual wash waters with no significant fouling for a period of 40 days. Due to the tube-side-feed flow in these hollow-fiber membranes, the fibers themselves become the pressure vessels, allowing the development of extremely lightweight membrane modules. During the NASA research program, a pre-prototype membrane module capable of processing 6 gallons per day of wash water at 97 percent recovery was developed that can be dry-stored and that weighs 120 g.

  14. Antioxidant defenses in caterpillars: role of the ascorbate-recycling system in the midgut lumen.

    PubMed

    Barbehenn, R V; Bumgarner, S L; Roosen, E F; Martin, M M

    2001-04-01

    This study demonstrates that an ascorbate-recycling system in the midgut lumen can act as an effective antioxidant defense in caterpillars that feed on prooxidant-rich foods. In tannin-sensitive larvae of the forest tent caterpillar, Malacosoma disstria (Lasiocampidae), ingested tannic acid is oxidized in the midgut lumen, generating significant quantities of peroxides, including hydrogen peroxide, which readily diffuses across cell membranes and is a powerful cytotoxin. By contrast, in the tannin-tolerant larvae of the white-marked tussock moth, Orgyia leucostigma (Lymantriidae), tannic acid oxidation and the generation of peroxides are suppressed. The superior defense of O. leucostigma against oxidative stress imposed by the oxidation of ingested polyphenols can be explained by the presence of higher concentrations of ascorbate and glutathione in the midgut lumen. In O. leucostigma at least 50% of the ingested ascorbate present in the anterior midgut is still present in the posterior midgut, whereas in M. disstria, only 10% of the ascorbate is present in the posterior half of the midgut. We propose that the maintenance of higher levels of ascorbate in the midgut lumen of O. leucostigma than in M. disstria is explained by the secretion of glutathione into the midgut lumen by O. leucostigma, thereby forming a complete ascorbate-recycling system. The concentration of glutathione in the midgut lumen of O. leucostigma is 3.5-fold higher than in M. disstria and more than double the concentration in the diet. Our results emphasize the importance of a defensive strategy in herbivorous insects based on the maintenance of conditions in the gut lumen that reduce or eliminate the potential prooxidant behavior of ingested phenols. PMID:11166299

  15. Dishwashing water recycling system and related water quality standards for military use.

    PubMed

    Church, Jared; Verbyla, Matthew E; Lee, Woo Hyoung; Randall, Andrew A; Amundsen, Ted J; Zastrow, Dustin J

    2015-10-01

    As the demand for reliable and safe water supplies increases, both water quality and available quantity are being challenged by population growth and climate change. Greywater reuse is becoming a common practice worldwide; however, in remote locations of limited water supply, such as those encountered in military installations, it is desirable to expand its classification to include dishwashing water to maximize the conservation of fresh water. Given that no standards for dishwashing greywater reuse by the military are currently available, the current study determined a specific set of water quality standards for dishwater recycling systems for U.S. military field operations. A tentative water reuse standard for dishwashing water was developed based on federal and state regulations and guidelines for non-potable water, and the developed standard was cross-evaluated by monitoring water quality data from a full-scale dishwashing water recycling system using an innovative electrocoagulation and ultrafiltration process. Quantitative microbial risk assessment (QMRA) was also performed based on exposure scenarios derived from literature data. As a result, a specific set of dishwashing water reuse standards for field analysis (simple, but accurate) was finalized as follows: turbidity (<1 NTU), Escherichia coli (<50 cfu mL(-1)), and pH (6-9). UV254 was recommended as a surrogate for organic contaminants (e.g., BOD5), but requires further calibration steps for validation. The developed specific water standard is the first for dishwashing water reuse and will be expected to ensure that water quality is safe for field operations, but not so stringent that design complexity, cost, and operational and maintenance requirements will not be feasible for field use. In addition the parameters can be monitored using simple equipment in a field setting with only modest training requirements and real-time or rapid sample turn-around. This standard may prove useful in future development

  16. Direct recycling of human hygiene water into hydroponic plant growth systems.

    PubMed

    Loader, C A; Garland, J L; Levine, L H; Cook, K L; Mackowiak, C L; Vivenzio, H R

    1999-01-01

    Direct recycling of gray water (human hygiene water) through plant production systems would reduce the need for additional space, mass, and energy for water reclamation in Advanced Life Support (ALS) systems. A plant production system designed to produce 25% of crew food needs could theoretically purify enough water through transpiration for 100% of crew water requirements. This scenario was tested through additions of shower and laundry water to recirculating hydroponic systems containing either wheat or soybean. Surfactant (Igepon TC-42) did not accumulate in the systems, and both the rate of surfactant disappearance and the proportion of Igepon-degrading microorganisms on the plant roots increased with time. A mechanism of surfactant degradation via the microbially ally mediated hydrolysis of the amide linkage and subsequent breakdown of fatty acid components is proposed. Fecal coliforms present in the human gray water were not detectable on the plant roots, indicating that human-associated microorganisms do not grow in the system. Overall plant growth was unaffected by gray water additions, although preliminary evidence suggests that reproduction may be inhibited. PMID:11542241

  17. Recycle as an alternative to algal TSS and BOD removal from an industrial waste stabilization pond system

    SciTech Connect

    Davis, E.M.; Downs, T.D.; Shi, Y.; Ajgaonkar, A.A.

    1996-11-01

    Reuse of wastewater is acquiring a more important role in the overall concept of water conservation management. Information on industrial waste stabilization pond (WSP) effluent recycling or reuse for cooling water purposes is virtually nonexistent. This paper presents data from investigations that were conducted to determine the feasibility of recycling a WSP series effluent back within the system for BOD and total suspended solids (TSS) reduction, which were algal in origin, and separately, to evaluate whether recycling the final WSP effluent to the industry`s cooling water ponds would show corrosion compatibility. The second part of this paper contains data developed form analyses of the settling characteristics of the algal standing crop in the industrial WSPs in question to determine the extent to which autosedimentation could occur.

  18. Multi-Material Recycling Manual. The Keep America Beautiful System. Revised Edition.

    ERIC Educational Resources Information Center

    1987

    Solid waste management ranks third after schools and roads in most municipal budgets in the United States. Maximizing the separation of recyclable materials that can be reused may offer the highest priority and best use of our waste and should receive high priority in a solid waste management plan. This manual deals with the recycling of material…

  19. Stormwater harvesting for irrigation purposes: an investigation of chemical quality of water recycled in pervious pavement system.

    PubMed

    Nnadi, Ernest O; Newman, Alan P; Coupe, Stephen J; Mbanaso, Fredrick U

    2015-01-01

    Most available water resources in the world are used for agricultural irrigation. Whilst this level of water use is expected to increase due to rising world population and land use, available water resources are expected to become limited due to climate change and uneven rainfall distribution. Recycled stormwater has the potential to be used as an alternative source of irrigation water and part of sustainable water management strategy. This paper reports on a study to investigate whether a sustainable urban drainage system (SUDS) technique, known as the pervious pavements system (PPS) has the capability to recycle water that meets irrigation water quality standard. Furthermore, the experiment provided information on the impact of hydrocarbon (which was applied to simulate oil dripping from parked vehicles onto PPS), leaching of nutrients from different layers of the PPS and effects of nutrients (applied to enhance bioremediation) on the stormwater recycling efficiency of the PPS. A weekly dose of 6.23 × 10(-3) L of lubricating oil and single dose of 17.06 g of polymer coated controlled-release fertilizer granules were applied to the series of 710 mm × 360 mm model pervious pavement structure except the controls. Rainfall intensity of 7.4 mm/h was applied to the test models at the rate of 3 events per week. Analysis of the recycled water showed that PPS has the capability to recycle stormwater to a quality that meets the chemical standards for use in agricultural irrigation irrespective of the type of sub-base used. There is a potential benefit of nutrient availability in recycled water for plants, but care should be taken not to dispose of this water in natural water courses as it might result in eutrophication problems. PMID:25256837

  20. Reverse logistics system and recycling potential at a landfill: A case study from Kampala City

    SciTech Connect

    Kinobe, J.R.; Gebresenbet, G.; Niwagaba, C.B.; Vinnerås, B.

    2015-08-15

    Highlights: • Quantifies the different waste streams delivered at the landfill. • Evaluates the amount of potential waste products that enters into the reverse cycle. • Drawing out the reverse logistics activities from Kampala City to Kiteezi landfill. • Identify the storage, collection and transportation mechanisms of products to the various destinations; and finally. • The study suggests efficient measures to improve reverse logistics system. - Abstract: The rapid growing population and high urbanisation rates in Sub-Saharan Africa has caused enormous pressure on collection services of the generated waste in the urban areas. This has put a burden on landfilling, which is the major waste disposal method. Waste reduction, re-use and recycling opportunities exist but are not fully utilized. The common items that are re-used and re-cycled are plastics, paper, aluminum, glass, steel, cardboard, and yard waste. This paper develops an overview of reverse logistics at Kiteezi landfill, the only officially recognised waste disposal facility for Kampala City. The paper analyses, in details the collection, re-processing, re-distribution and final markets of these products into a reversed supply chain network. Only 14% of the products at Kiteezi landfill are channeled into the reverse chain while 63% could be included in the distribution chain but are left out and disposed of while the remaining 23% is buried. This is because of the low processing power available, lack of market value, lack of knowledge and limited value addition activities to the products. This paper proposes possible strategies of efficient and effective reverse logistics development, applicable to Kampala City and other similar cities.

  1. A new 68Ge/68Ga generator system using an organic polymer containing N-methylglucamine groups as adsorbent for 68Ge.

    PubMed

    Nakayama, M; Haratake, M; Ono, M; Koiso, T; Harada, K; Nakayama, H; Yahara, S; Ohmomo, Y; Arano, Y

    2003-01-01

    A macroporous styrene-divinylbenzene copolymer containing N-methylglucamine groups was selected for a new 68Ge/68Ga generator system. This resin packed into a column effectively adsorbed the parent nuclide 68Ge. The daughter 68Ga was eluted from the resin with a solution of a low-affinity gallium chelating ligand such as citric or phosphoric acid. The 68Ge leakage was less than 0.0004% of the 68Ge adsorbed on the resin. By simple mixing of transferrin and desferoxamine conjugated HSA and IgG with the eluate from the column, 68Ga-labeling was completed in high yield. PMID:12485657

  2. PFC concentration and recycle

    SciTech Connect

    Tom, G.M.; McManus, J.; Knolle, W.; Stoll, I.

    1994-12-31

    The semiconductor industry uses PFC gases such as CF{sub 4} and C{sub 2}F{sub 6} as etchant and cleaning gases during plasma processes. The gases do not fully react within the reactor chamber. The unused gases enter the atmosphere through the process effluent. These gases have long persistence in the atmosphere and absorb infrared radiation. The PFC gases are, therefore, potential global warming gases. A method is described that will recover and recycle PFC gases. The method that the authors have employed to trap and concentrate the PFC gases is based on a dual bed adsorber. The adsorption material is activated carbon.

  3. Stationary patterns for an adsorbate-induced phase transition model: II. Shadow system

    NASA Astrophysics Data System (ADS)

    Kuto, Kousuke; Tsujikawa, Tohru

    2013-05-01

    This paper is concerned with stationary solutions of a reaction-diffusion-advection system arising in surface chemistry. Hildebrand et al (2003 New J. Phys. 5 61) have constructed stationary stripe (or spot) solutions of the system in the singular perturbation case and shown a numerical result that the set of stripe (or spot) solutions forms a saddle-node bifurcation curve with respect to a diffusion coefficient. In this paper, we introduce a shadow system in the limiting case that another diffusion and an advection coefficient tend to infinity. Furthermore we obtain the bifurcation structure of stationary solutions of the shadow systems in the one-dimensional case. This structure involves saddle-node bifurcation curves which support the above numerical result in Hildebrand et al (2003 New J. Phys. 5 61, figure 9). Our proof is based on the combination of the bifurcation, the singular perturbation and a level set analysis.

  4. Time-resolved spectroscopy at surfaces and adsorbate dynamics: Insights from a model-system approach

    NASA Astrophysics Data System (ADS)

    Boström, Emil; Mikkelsen, Anders; Verdozzi, Claudio

    2016-05-01

    We introduce a model description of femtosecond laser induced desorption at surfaces. The substrate part of the system is taken into account as a (possibly semi-infinite) linear chain. Here, being especially interested in the early stages of dissociation, we consider a finite-size implementation of the model (i.e., a finite substrate), for which an exact numerical solution is possible. By time-evolving the many-body wave function, and also using results from a time-dependent density functional theory description for electron-nuclear systems, we analyze the competition between several surface-response mechanisms and electronic correlations in the transient and longer time dynamics under the influence of dipole-coupled fields. Our model allows us to explore how coherent multiple-pulse protocols can impact desorption in a variety of prototypical experiments.

  5. Adsorbate-Induced Segregation in a PdAg Membrane Model System: Pd3Ag(1 1 1)

    SciTech Connect

    Svenum, I. H.; Herron, Jeffrey A.; Mavrikakis, Manos; Venvik, H. J.

    2012-10-15

    Thin PdAg alloy membranes with 20–25% Ag are being developed for hydrogen separation technology. Despite many investigations on such membranes as well as representative experimental and theoretical model systems, unresolved issues remain concerning the effect of the alloy surface structure and composition on adsorption and vice versa. Therefore, the interaction between hydrogen, carbon monoxide or oxygen with the surface of a PdAg model alloy was studied using periodic self-consistent density functional theory (DFT-GGA) calculations. In particular, the adsorption structure, coverage dependence and possible adsorption-induced segregation phenomena were addressed using Pd3Ag(1 1 1) model surfaces with varying degrees of surface segregation. In agreement with previous experimental and theoretical investigations, we predict Ag surface termination to be energetically favorable in vacuum. The segregation of Ag is then reversed upon adsorption of H, CO or O. For these adsorbates, the binding is strongest on Pd three-fold hollow sites, and hence complete Pd termination is favored at high coverage of H or CO, while 25% Ag may remain under oxygen because of the lower O-saturation coverage. CO adsorption provides a somewhat stronger driving force for Pd segregation when compared to H, and this may have implications with respect to permeation properties of PdAg alloy surfaces. Our predictions for high coverage are particularly relevant in underlining the importance of segregation phenomena to the hydrogen transport properties of thin PdAg alloy membranes.

  6. Experience of Treatments of Amanita phalloides-Induced Fulminant Liver Failure with Molecular Adsorbent Recirculating System and Therapeutic Plasma Exchange.

    PubMed

    Zhang, Jicheng; Zhang, Ying; Peng, Zhiyong; Maberry, Donald; Feng, Xueqiang; Bian, Pengfei; Ma, Wenjuan; Wang, Chunting; Qin, Chengyong

    2014-01-01

    Ingestion of the mushroom containing Amanita phalloides can induce fulminant liver failure and death. There are no specific antidotes. Blood purifications, such as molecular adsorbent recirculating system (MARS) and therapeutic plasma exchange (TPE), are potential therapies. However, the extent to which these technologies avert the deleterious effects of amatoxins remains controversial; the optimal intensity, duration, and initiation criteria have not been determined yet. This study aimed to retrospectively observe the effects of MARS and TPE on nine patients with A. phalloides-induced fulminant liver failure. The survival rate for the nine patients was 66.7%. Both TPE and MARS might remove toxins and improve liver functions. However, a single session of TPE produced immediately greater improvements in alanine aminotransferase (-60% vs. -16.3%), aspartate aminotransferase (-47.6% vs. -15.4%), and total bilirubin (-37.3% vs. -17.1%) (compared with the values of pretreatment, all p < 0.05) than MARS compared with MARS. Early intervention may be more effective than delayed therapy. Additionally, the presence of severe liver failure and renal failure indicated worse outcome. Although these findings are promising, additional case-controlled, randomized studies are required to confirm our results. PMID:24727538

  7. Improvement of vitamin B(12) fermentation by reducing the inhibitory metabolites by cell recycle system and a mixed culture.

    PubMed

    Miyano; Ye; Shimizu

    2000-12-01

    The major problem in vitamin B(12) production using Propionibacterium is the growth inhibition of the cell due to the accumulation of inhibitory metabolites such as propionic acid and acetic acid. In the present paper, we considered several approaches of controlling the propionic acid concentration at low level. Namely: (1) the periodic cultivation of Propionibacterium where dissolved oxygen (DO) concentration was alternatively changed between 0 and 1ppm; (2) cell recycle system using hollow fiber module; and (3) mixed culture using Propionibacterium and Ralstonia eutropha where the latter microorganism assimilates the propionic acid produced by the former. It was found that the productivity of vitamin B(12) was the highest for the cell recycle system, while if the performance was evaluated based on the amount of vitamin B(12) produced per medium used, the mixed culture system gave the far highest value. PMID:11080651

  8. Recycled pulsars

    NASA Astrophysics Data System (ADS)

    Jacoby, Bryan Anthony

    2005-11-01

    In a survey of ~4,150 square degrees, we discovered 26 previously unknown pulsars, including 7 "recycled" millisecond or binary pulsars. The most significant discovery of this survey is PSR J1909-3744, a 2.95 ms pulsar in an extremely circular 1.5 d orbit with a low-mass white dwarf companion. Though this system is a fairly typical low-mass binary pulsar (LMBP) system, it has several exceptional qualities: an extremely narrow pulse profile and stable rotation have enabled the most precise long-term timing ever reported, and a nearly edge-on orbit gives rise to a strong Shapiro delay which has allowed the most precise measurement of the mass of a millisecond pulsar: m p = (1.438 +/- 0.024) [Special characters omitted.] . Our accurate parallax distance measurement, d p = ([Special characters omitted.] ) kpc, combined with the mass of the optically-detected companion, m c = (0.2038 +/- 0.022) [Special characters omitted.] , will provide an important calibration for white dwarf models relevant to other LMBP companions. We have detected optical counterparts for two intermediate mass binary pulsar (IMBP) systems; taken together with optical detections and non-detections of several similar systems, our results indicate that the characteristic age t = c P /2 P consistently overestimates the time since the end of mass accretion in these recycled systems. We have measured orbital decay in the double neutron star system PSR B2127+11C in the globular cluster M15. This has allowed an improved measurement of the mass of the pulsar, m p = (1.3584 +/- 0.0097) [Special characters omitted.] , and companion, m c = (1.3544 +/- 0.0097) [Special characters omitted.] , as well as a test of general relativity at the 3% level. We find that the proper motions of this pulsar as well as PSR B2127+11A and PSR B2127+11B are consistent with each other and with one published measurement of the cluster proper motion. We have discovered three binary millisecond pulsars in the globular cluster M62

  9. Chemical activation in view of MSWI bottom ash recycling in cement-based systems.

    PubMed

    Polettini, A; Pomi, R; Fortuna, E

    2009-03-15

    In the present study, the feasibility of recycling incinerator bottom ash in cementitious systems by means of chemical activation was investigated. Different Na-, K- and Ca-based hydroxides and salts were selected for the experiments on the basis of their recognized effects on activation of typical pozzolanic materials. The evolution of mechanical properties of bottom ash/Portland cement mixtures and the leaching of trace metals from the materials were a matter of major concern. The experiments were arranged according to a full factorial design, which also allowed to derive a predictive model for unconfined compressive strength as affected by bottom ash content as well as activator type and dosage. Among the activators tested, calcium chloride was found to affect mechanical strength far more positively than the other species used, at the same time ensuring low metal release from the material. On the other hand, the use of potassium sulfate was observed to cause a significant increase in metal leaching at pH<12, which was probably associated to the release of contaminants initially immobilized within the structure of ettringite as soon as it converted into monosulfate over time. PMID:18632208

  10. Comparative study of wastewater treatment and nutrient recycle via activated sludge, microalgae and combination systems.

    PubMed

    Wang, Liang; Liu, Jinli; Zhao, Quanyu; Wei, Wei; Sun, Yuhan

    2016-07-01

    Algal-bacterial synergistic cultivation could be an optional wastewater treatment technology in temperate areas. In this study, a locally screened vigorous Chlorella strain was characterized and then it was used in a comparative study of wastewater treatment and nutrient recycle assessment via activated sludge (AS), microalgae and their combination systems. Chlorella sp. cultured with AS in light showed the best performance, in which case the removal efficiencies of COD, NH3-N and TP were 87.3%, 99.2% and 83.9%, respectively, within a short period of 1day. Algal-bacterial combination in light had the best settleability. Chlorella sp. contained biomass, could be processed to feed, fertilizer or fuel due to the improved quality (higher C/H/N) compared with sludge. PCR-DGGE analysis shows that two types of rhizobacteria, namely, Pseudomonas putida and Flavobacterium hauense were enriched in sludge when cultured with algae in light, serving as the basics for artificial consortium construction for improved wastewater treatment. PMID:26995615

  11. Detoxification of phytotoxic compounds by TiO2 photocatalysis in a recycling hydroponic cultivation system of asparagus.

    PubMed

    Sunada, Kayano; Ding, Xin Geng; Utami, Melia Sandya; Kawashima, Yoko; Miyama, Yoko; Hashimoto, Kazuhito

    2008-06-25

    TiO 2 photocatalytic decomposition and detoxification of phytotoxic compounds released by the roots of asparagus ( Asparagus officinalis L.) were investigated from the viewpoint of conservation-oriented cultivation. The phytotoxically active fraction was extracted either from dried asparagus roots or from the recycled nutrient solution of an asparagus hydroponic cultivation system. We found that the phytotoxic activity gradually decreased in the fraction with TiO 2 powder under irradiation with ultraviolet (UV) light at an intensity of 1.0 mW/cm (2). The growth of asparagus plants under actual cultivation conditions was also investigated by comparing asparagus grown in a hydroponic system where recycled waste nutrient solution was photocatalytically treated with solar light and a system with untreated recycled waste nutrient solution. The results showed, as measured by growth indices such as stem length and stem thickness, that asparagus growth in the photocatalytically treated system was superior to the untreated one. Furthermore, the yield of asparagus spears was 1.6-fold greater in the photocatalytically treated system, demonstrating the detoxification effect on the phytotoxic compounds and also the killing effect on pathogenic microorganisms. PMID:18500814

  12. A global, comprehensive review of literature related to paper recycling: A pressing need for a uniform system of terms and definitions.

    PubMed

    Ervasti, Ilpo; Miranda, Ruben; Kauranen, Ilkka

    2016-02-01

    A global, comprehensive review of terms and definitions related to paper recycling was conducted in this article. Terms and definitions related to paper recycling have varied in the course of time. Different terms and different definitions for the same thing are being used in different geographical regions and by different organizations. Definitions are different based on varying conceptions of waste paper as a raw material. Definitions of how to make various calculations related to paper recycling activity are inconsistent. Even such fundamental basic definitions like how to calculate recycling rate and paper consumption are not uniform. It could be concluded that there is no uniform system of terms and definitions related to paper recycling and the implications of this deficiency are profound. For example, it is difficult to reliably compare with each other statistics from different times and from different geographical regions. It is not possible to measure if targets for recycling activities are met if the terms describing the targets are not uniformly defined. In cases of reporting data for recycling targets, the lack of uniform terminology can, for example, impede the necessary transparency between different stakeholders and may allow for deception. The authors conclude there is a pressing need to develop a uniform system of terms and definition for terms related to paper recycling. PMID:26619933

  13. Plant growth and mineral recycle trade-offs in different scenarios for a CELSS. [Closed Ecological Life Support System

    NASA Technical Reports Server (NTRS)

    Ballou, E. V.; Wydeven, T.; Spitze, L. A.

    1982-01-01

    Data for hydroponic plant growth in a manned system test is combined with nutritional recommendations to suport trade-off calculations for closed and partially closed life support system scenarios. Published data are used as guidelines for the masses of mineral nutrients needed for higher plant production. The results of calculations based on various scenarios are presented for various combinations of plant growth chamber utilization and fraction of mineral recycle. Estimates are made of the masses of material needed to meet human nutritional requirements in the various scenarios. It appears that food production from a plant growth chamber with mineral recycle is favorable to reduction of the total launch weight in missions exceeding 3 years.

  14. Hydrogen Purification and Recycling for an Integrated Oxygen Recovery System Architecture

    NASA Technical Reports Server (NTRS)

    Abney, Morgan B.; Greenwood, Zachary; Wall, Terry; Miller, Lee; Wheeler, Ray

    2016-01-01

    The United States Atmosphere Revitalization life support system on the International Space Station (ISS) performs several services for the crew including oxygen generation, trace contaminant control, carbon dioxide (CO2) removal, and oxygen recovery. Oxygen recovery is performed using a Sabatier reactor developed by Hamilton Sundstrand, wherein CO2 is reduced with hydrogen in a catalytic reactor to produce methane and water. The water product is purified in the Water Purification Assembly and recycled to the Oxygen Generation Assembly (OGA) to provide O2 to the crew. This architecture results in a theoretical maximum oxygen recovery from CO2 of approximately 54% due to the loss of reactant hydrogen in Sabatier-produced methane that is currently vented outside of ISS. Plasma Methane Pyrolysis technology (PPA), developed by Umpqua Research Company, provides the capability to further close the Atmosphere Revitalization oxygen loop by recovering hydrogen from Sabatier-produced methane. A key aspect of this technology approach is to purify the hydrogen from the PPA product stream which includes acetylene, unreacted methane and byproduct water and carbon monoxide. In 2015, four sub-scale hydrogen separation systems were delivered to NASA for evaluation. These included two electrolysis single-cell hydrogen purification cell stacks developed by Sustainable Innovations, LLC, a sorbent-based hydrogen purification unit using microwave power for sorbent regeneration developed by Umpqua Research Company, and a LaNi4.6Sn0.4 metal hydride produced by Hydrogen Consultants, Inc. Here we report the results of these evaluations, discuss potential architecture options, and propose future work.

  15. Hydrogen Purification and Recycling for an Integrated Oxygen Recovery System Architecture

    NASA Technical Reports Server (NTRS)

    Abney, Morgan B.; Greenwood, Zachary; Wall, Terry; Nur, Mononita; Wheeler, Richard R., Jr.; Preston, Joshua; Molter, Trent

    2016-01-01

    The United States Atmosphere Revitalization life support system on the International Space Station (ISS) performs several services for the crew including oxygen generation, trace contaminant control, carbon dioxide (CO2) removal, and oxygen recovery. Oxygen recovery is performed using a Sabatier reactor developed by Hamilton Sundstrand, wherein CO2 is reduced with hydrogen in a catalytic reactor to produce methane and water. The water product is purified in the Water Purification Assembly and recycled to the Oxygen Generation Assembly (OGA) to provide O2 to the crew. This architecture results in a theoretical maximum oxygen recovery from CO2 of approx.54% due to the loss of reactant hydrogen in Sabatier-produced methane that is currently vented outside of ISS. Plasma Pyrolysis Assembly (PPA) technology, developed by Umpqua Research Company, provides the capability to further close the Atmosphere Revitalization oxygen loop by recovering hydrogen from Sabatier-produced methane. A key aspect of this technology approach is the need to purify the hydrogen from the PPA product stream which includes acetylene, unreacted methane and byproduct water and carbon monoxide. In 2015, four sub-scale hydrogen separation systems were delivered to NASA for evaluation. These included two electrolysis single-cell hydrogen purification cell stacks developed by Sustainable Innovations, LLC, a sorbent-based hydrogen purification unit using microwave power for sorbent regeneration developed by Umpqua Research Company, and a LaNi4.6Sn0.4 metal hydride produced by Hydrogen Consultants, Inc. Here we report the results of these evaluations to-date, discuss potential architecture options, and propose future work.

  16. Cold in-place recycling characterization framework for single or multiple component binder systems

    NASA Astrophysics Data System (ADS)

    Cox, Benjamin C.

    Cold in-place recycling (CIR) is a pavement rehabilitation technique which has gained momentum in recent years. This momentum is due partly to its economic and sustainability characteristics, which has led to CIR market expansion. When pavement network deterioration is considered alongside increasing material costs, it is not beyond reason to expect demands on CIR to continue to increase. Historically, single component binder (SCB) systems, those with one stabilization binder (or two if the secondary binder dosage is 1% or less), have dominated the CIR market and could be considered the general state of practice. Common stabilization binders are either bituminous or cementitious. Two example SCB systems would be: 1) 3% portland cement, or 2) 3% asphalt emulsion with 1% hydrated lime. While traditional SCB systems have demonstrated positive economic and sustainability impacts, this dissertation focuses on multiple component binder (MCB) systems (bituminous and cementitious combined) which exhibit the potential to provide better overall economics and performance. Use of MCBs has the potential to alleviate SCB issues to some extent (e.g. cracking with cementitious SCBs, rutting with bituminous SCBs). Furthermore, to fairly represent both binders in an MCB system a universal design method which can accommodate multiple binder types is needed. The main objectives of this dissertation are to develop a universal CIR design framework and, using this framework, characterize multiple SCB and MCB systems. Approximately 1500 CIR specimens were tested herein along with approximately 300 asphalt concrete specimens which serve as a reference data set for CIR characterization. A case study of a high-traffic Mississippi CIR project which included cement SCB and emulsion SCB sections is also presented to support laboratory efforts. Individual components needed to comprise a universal design framework, such as curing protocols, were developed. SCB and MCB characterization indicated

  17. Experience with molecular adsorbent recirculating system treatment in 20 children listed for high-urgency liver transplantation.

    PubMed

    Lexmond, Willem S; Van Dael, Carin M L; Scheenstra, René; Goorhuis, Joanne F; Sieders, Egbert; Verkade, Henkjan J; Van Rheenen, Patrick F; Kömhoff, Martin

    2015-03-01

    For more than 10 years, children at our national center for pediatric liver transplantation (LT) have been treated with Molecular Adsorbent Recirculating System (MARS) liver dialysis as a bridging therapy to high-urgency LT. Treatment was reserved for 20 patients with the highest degrees of hepatic encephalopathy (HE; median grade = 3.5). Death from neurological sequelae was considered imminent for these patients, and this was further reflected in significantly higher international normalized ratios and ammonia levels and worse prognostic liver indices (Model for End-Stage Liver Disease/Pediatric End-Stage Liver Disease scores and liver injury units) in comparison with 32 wait-listed patients who did not receive MARS dialysis. MARS therapy was generally well tolerated, with a reduction in thrombocytes and hemorrhaging as the most common side effects. HE improvement was documented in 30% of the treated patients, but progression to grade IV encephalopathy occurred in 45% of the patients despite the treatment. Serum ammonia, bilirubin, bile acid, and creatinine levels significantly decreased during treatment. Eighty percent of MARS-treated patients survived to undergo LT, and their survival was equivalent to that of non-MARS-treated patients with severe liver failure (69%, P = 0.52). The heterogeneity between MARS-treated patients and non-MARS-treated patients in our cohort precluded a statistical evaluation of a benefit from MARS for patient survival. Our data demonstrate the safety of MARS even in the most severely ill patients awaiting LT, but strategies that promote the more rapid and widespread availability of high-quality donor organs remain of critical importance for improving patient survival in cases of severe acute liver failure. PMID:25366362

  18. Unique Inflammatory Mediators and Specific IgE Levels Distinguish Local from Systemic Reactions after Anthrax Vaccine Adsorbed Vaccination.

    PubMed

    Garman, Lori; Smith, Kenneth; Muns, Emily E; Velte, Cathy A; Spooner, Christina E; Munroe, Melissa E; Farris, A Darise; Nelson, Michael R; Engler, Renata J M; James, Judith A

    2016-08-01

    Although the U.S. National Academy of Sciences concluded that anthrax vaccine adsorbed (AVA) has an adverse event (AE) profile similar to those of other adult vaccines, 30 to 70% of queried AVA vaccinees report AEs. AEs appear to be correlated with certain demographic factors, but the underlying immunologic pathways are poorly understood. We evaluated a cohort of 2,421 AVA vaccinees and found 153 (6.3%) reported an AE. Females were more likely to experience AEs (odds ratio [OR] = 6.0 [95% confidence interval {CI} = 4.2 to 8.7]; P < 0.0001). Individuals 18 to 29 years of age were less likely to report an AE than individuals aged 30 years or older (OR = 0.31 [95% CI = 0.22 to 0.43]; P < 0.0001). No significant effects were observed for African, European, Hispanic, American Indian, or Asian ancestry after correcting for age and sex. Additionally, 103 AEs were large local reactions (LLRs), whereas 53 AEs were systemic reactions (SRs). In a subset of our cohort vaccinated 2 to 12 months prior to plasma sample collection (n = 75), individuals with LLRs (n = 33) had higher protective-antigen (PA)-specific IgE levels than matched, unaffected vaccinated individuals (n = 50; P < 0.01). Anti-PA IgE was not associated with total plasma IgE, hepatitis B-specific IgE, or anti-PA IgG in individuals who reported an AE or in matched, unaffected AVA-vaccinated individuals. IP-10 was also elevated in sera of individuals who developed LLRs (P < 0.05). Individuals reporting SRs had higher levels of systemic inflammation as measured from C-reactive protein (P < 0.01). Thus, LLRs and SRs are mediated by distinct pathways. LLRs are associated with a vaccine-specific IgE response and IP-10, whereas SRs demonstrate increased systemic inflammation without a skewed cytokine profile. PMID:27280620

  19. Solid earth as a recycling systems and the lateral growth of Precambrian North America

    NASA Technical Reports Server (NTRS)

    Veizer, Jan

    1988-01-01

    If plotted on mass vs time diagrams, geologic entities (for example, continental and oceanic crust, sediments, and mineral resources) display an exponential (power law) relationship, with entity per unit time increasing toward the present. This relationship is consistent with the concept of recycling and can be simulated mathematically. The approach is based on the plate tectonic theory and considers area-age or mass-age distributions of crystalline basement and sediments for major global tectonic realms. Each tectonic realm is characterized by a specific lifespan, which is an inverse function of its recycling rate. The estimated average half-area of half-mass ages are given. The corresponding parameters for continental crust are 690 Ma for K/Ar, and approximately 1200 Ma for Rb/St and U-Th/Pb dating pairs. Tectonic diversity preserved in the geologic record is therefore a function of time, with oceanic tectonic realms, because of their rapid recycling, underrepresented in the rocks older than approximately 300 Ma. The Sm/Nd isotopic systematic of sediments suggest that, for a near steady-state post-Archean sedimentary mass, recycling is approximately 90 + or - 5 percent cannibalistic. This yields an estimated upper limit on crust-mantle exchange via sediment subduction of approximately 1.1 + or - 0.5 x 10 g a(sup -1) considerably less than demanded by isotopic constraints. The discrepancy may indicate the existence of additional loci, such as orogenic belts, for significant crust-mantle interaction.

  20. ETV REPORT: AND STATEMENT: HYDROMATIX 786E ION EXCHANGE RINSEWATER RECYCLING SYSTEM

    EPA Science Inventory

    RPA's ETV Program, through the NRMRL, has partnered with the California Dept. of Toxic Substances Contol (DTSCO) under an ETV Pilot to verify pollution prevention, recycling, and waste treatment technologies. This report provides a verification of performance results for the Hydr...

  1. SURVEY OF FOULING, FOAM, CORROSION, AND SCALING CONTROL IN IRON AND STEEL INDUSTRY RECYCLE SYSTEMS

    EPA Science Inventory

    The report gives results of a review of the state-of-the-art for fouling, foaming, corrosion, and scaling control in the treatment and recycle of process waters of integrated iron and steel mills. Areas examined were: (1) the character of the wastewaters generated in the differen...

  2. P3 DESIGN OF A NATIONAL ELECTRONICS PRODUCT REUSE AND RECYCLING SYSTEM

    EPA Science Inventory

    Material and resource conservation are critical to sustainability; and, the ability to efficiently and effectively recover old products for reuse and recycle is an essential element in these conservation efforts. In California alone, it has been estimated that 10,000 computers a...

  3. A visible-light harvesting system for CO2 reduction using a Ru(II) -Re(I) photocatalyst adsorbed in mesoporous organosilica.

    PubMed

    Ueda, Yutaro; Takeda, Hiroyuki; Yui, Tatsuto; Koike, Kazuhide; Goto, Yasutomo; Inagaki, Shinji; Ishitani, Osamu

    2015-02-01

    A photocatalytic system for CO2 reduction exhibiting visible-light harvesting was developed by preparing a hybrid consisting of a supramolecular metal complex as photocatalyst and periodic mesoporous organosilica (PMO) as light harvester. A Ru(II) Re(I) binuclear complex (RuRe) with methylphosphonic acid anchor groups was adsorbed on acridone or methylacridone embedded in the walls of PMO mesochannels to yield the hybrid structure. The embedded organic groups absorbed visible light, and the excitation energy was funneled to the Ru units. The energy accumulation was followed by electron transfer and catalytic reduction of CO2 to CO on the Re unit. The light harvesting of these hybrids enhanced the photocatalytic CO evolution rate by a factor of up to ten compared with that of RuRe adsorbed on mesoporous silica without a light harvester. PMID:25524162

  4. Effects of acoustic hood on noise, CFC-11, and particulate matter in a recycling system for waste refrigerator cabinet.

    PubMed

    Guo, Jie; Fang, Wenxiong; Yang, Yichen; Xu, Zhenming

    2014-11-01

    The mechanical-physical process was proven to be technologically feasible for waste refrigerator recycling and has been widely used in the typical e-waste recycling factories in China. In this study, effects of the acoustic hood on the reduction of noise level, CFC-11, and heavy metals (Cr, Ni, Cu, Cd, and Pb) in particulate matter (PM) were evaluated. For noise pollution, the noise level inside and outside the acoustic hood was 96.4 and 78.9 dB, respectively. Meanwhile, it had a significant effect on A-weighted sound level with a reduction from 98.3 to 63.6 dB. For CFC-11 exposure, abundant CFC-11 (255 mg/m(3)) was detected in the acoustic hood. However, the mean concentration of CFC-11 at the outline of polyurethane foam collection was obviously diminished to 14 mg/m(3), and no CFC-11 was monitored around the acoustic hood. The concentrations of PM and heavy metals in PM outside the acoustic hood were lower than those inside the acoustic hood due to the physical barriers of the acoustic hood. Based on the risk assessment, only adverse health effect caused by Pb might likely appear. All the results can provide the basic data for pollution control and risk assessment in waste refrigerator recycling system. PMID:24965005

  5. Comparison of aerobically-treated and untreated crop residue as a source of recycled nutrients in a recirculating hydroponic system

    NASA Technical Reports Server (NTRS)

    Mackowiak, C. L.; Garland, J. L.; Strayer, R. F.; Finger, B. W.; Wheeler, R. M.

    1996-01-01

    This study compared the growth of potato plants on nutrients recycled from inedible potato biomass. Plants were grown for 105 days in recirculating, thin-film hydroponic systems containing four separate nutrient solution treatments: (1) modified half-strength Hoagland's (control), 2) liquid effluent from a bioreactor containing inedible potato biomass, 3) filtered (0.2 micrometer) effluent, and 4) the water soluble fraction of inedible potato biomass (leachate). Approximately 50% of the total nutrient requirement in treatments 2-4 were provided (recycled) from the potato biomass. Leachate had an inhibitory effect on leaf conductance, photosynthetic rate, and growth (50% reduction in plant height and 60% reduction in tuber yield). Plants grown on bioreactor effluent (filtered or unfiltered) were similar to the control plants. These results indicated that rapidly degraded, water soluble organic material contained in the inedible biomass, i.e., material in leachate, brought about phytotoxicity in the hydroponic culture of potato. Recalcitrant, water soluble organic material accumulated in all nutrient recycling treatments (650% increase after 105 days), but no increase in rhizosphere microbial numbers was observed.

  6. Comparison of aerobically-treated and untreated crop residue as a source of recycled nutrients in a recirculating hydroponic system

    NASA Astrophysics Data System (ADS)

    Mackowiak, C. L.; Garland, J. L.; Strayer, R. F.; Finger, B. W.; Wheeler, R. M.

    1996-01-01

    This study compared the growth of potato plants on nutrients recycled from inedible potato biomass. Plants were grown for 105 days in recirculating, thin-film hydroponic systems containing four separate nutrient solution treatments: 1) modified half-strength Hoagland's (control), 2) liquid effluent from a bioreactor containing inedible potato biomass, 3) filtered (0.2 μm) effluent, and 4) the water soluble fraction of inedible potato biomass (leachate). Approximately 50% of the total nutrient requirement in treatments 2 - 4 were provided (recycled) from the potato biomass. Leachate had an inhibitory effect on leaf conductance, photosynthetic rate, and growth (50% reduction in plant height and 60% reduction in tuber yield). Plants grown on bioreactor effluent (filtered or unfiltered) were similar to the control plants. These results indicated that rapidly degraded, water soluble organic material contained in the inedible biomass, i.e., material in leachate, brought about phytotoxicity in the hydroponic culture of potato. Recalcitrant, water soluble organic material accumulated in all nutrient recycling treatments (650% increase after 105 days), but no increase in rhizosphere microbial numbers was observed.

  7. Textile recycling

    SciTech Connect

    Jablonowski, E. ); Carlton, J.

    1995-01-01

    The most common household textiles include clothing, linens, draperies, carpets, shoes, handbags, and rugs. Old clothing, of course, is the most readily reused and/or recycled residentially generated textile category. State and/or local mandates to recycle a percentage of the waste stream are providing the impetus to add new materials to existing collection programs. Concurrently, the textile industry is aggressively trying to increase its throughput by seeking new sources of material to meet increased world demand for product. As experienced with drop-off programs for traditional materials, a majority of residents will not recycle materials unless the collection programs are convenient, i.e., curbside collection. The tonnage of marketable textiles currently being landfilled provide evidence of this. It is the authors' contention that if textile recycling is made convenient and accessible to every household in a municipality or region, then the waste stream disposed may be reduced in a similar fashion as when traditional recyclables are included in curbside programs.

  8. TOMATO CLEANING AND WATER RECYCLE

    EPA Science Inventory

    A full-scale dump tank water recycle system was developed and demonstrated. A false bottom-ejector transport system removed soil from the water. Clarified water was either recycled back to the dump tank or discharged to the sewer. A vacuum belt was developed for dewatering the mu...

  9. A non-contact energy transferring system for an electric vehicle-charging system based on recycled products

    NASA Astrophysics Data System (ADS)

    Matsuda, Y.; Sakamoto, H.; Shibuya, H.; Murata, S.

    2006-04-01

    A non-contact automatic charging system for electric vehicle application is presented. The principle is the same as that of the transformer where the primary and the secondary circuits are separable but coupled with each other without using the hand coupler. In this paper, we present a possibility of removing the core of the secondary coil on the body for reducing the weight of the car. In our experiments, the primary core, which is placed on the earth floor, is made of Mn-Zn ferrite with square shape as 1 m×1 m×10 mm for a large cross-sectional area. The steel floor of the car assists to pass the magnetic flux. An efficiency rate over 90% with the test device of 2 kW is obtained without the conventional secondary core. The leakage inductance is well compensated by a resonance capacitor inserted in the secondary coil. In this experiment, the distance between the primary and the secondary coil is 100 mm and the switching frequency is 100 kHz. In addition, we developed a pavement method for the system. The method utilizes plates made from the waste of expanded polystyrene and rubber mats made from used tire. The plates are set up on the rubber mats and these mats are arranged over the non-contact charging system. The pavements can be replaced easily when the system is exchanged. Therefore, this pavement method is not only practical for the non-contact charging system but is also useful for recycling of resources and reduction of waste matters.

  10. Decision-making support system based on LCA for aseptic packaging recycling.

    PubMed

    Varžinskas, Visvaldas; Staniškis, Jurgis K; Knašyte, Milda

    2012-09-01

    In Europe post-consumer beverage carton packages are treated in three ways: dumped in a landfill, incinerated for energy recovery, and recycled. In recent years new technologies for beverage carton recycling have been developed and tested. At the same time in Europe the collection of second-hand raw materials is becoming more efficient. In order to facilitate and justify the decision-making process, different possibilities of poly-aluminium handling were analysed. For this reason, the objective of this study was to compare carbon footprints in the whole life cycle of selected technologies and to provide decision-making with data for beverage carton recycling. The paper is based on some of the results of the project 'Sustainable Production through Innovations in small- and medium-sized enterprises (SPIN)'. The SPIN project is providing small- and medium-sized enterprises with a whole set of instruments that put entrepreneurs in a position to innovate their production processes and products leading to improved business and public benefits. PMID:22778144

  11. System Design Description and Requirements for Modeling the Off-Gas Systems for Fuel Recycling Facilities

    SciTech Connect

    Daryl R. Haefner; Jack D. Law; Troy J. Tranter

    2010-08-01

    This document provides descriptions of the off-gases evolved during spent nuclear fuel processing and the systems used to capture the gases of concern. Two reprocessing techniques are discussed, namely aqueous separations and electrochemical (pyrochemical) processing. The unit operations associated with each process are described in enough detail so that computer models to mimic their behavior can be developed. The document also lists the general requirements for the desired computer models.

  12. Helium-Recycling Plant

    NASA Technical Reports Server (NTRS)

    Cook, Joseph

    1996-01-01

    Proposed system recovers and stores helium gas for reuse. Maintains helium at 99.99-percent purity, preventing water vapor from atmosphere or lubricating oil from pumps from contaminating gas. System takes in gas at nearly constant low back pressure near atmospheric pressure; introduces little or no back pressure into source of helium. Concept also extended to recycling of other gases.

  13. What can Recycling in Thermal Reactors Accomplish?

    SciTech Connect

    Steven Piet; Gretchen E. Matthern; Jacob J. Jacobson

    2007-09-01

    Thermal recycle provides several potential benefits when used as stop-gap, mixed, or backup recycling to recycling in fast reactors. These three roles involve a mixture of thermal and fast recycling; fast reactors are required to some degree at some time. Stop-gap uses thermal reactors only until fast reactors are adequately deployed and until any thermal-recycle-only facilities have met their economic lifetime. Mixed uses thermal and fast reactors symbiotically for an extended period of time. Backup uses thermal reactors only if problems later develop in the fast reactor portion of a recycling system. Thermal recycle can also provide benefits when used as pure thermal recycling, with no intention to use fast reactors. However, long term, the pure thermal recycling approach is inadequate to meet several objectives.

  14. Integrated system for temperature-controlled fast protein liquid chromatography comprising improved copolymer modified beaded agarose adsorbents and a travelling cooling zone reactor arrangement.

    PubMed

    Müller, Tobias K H; Cao, Ping; Ewert, Stephanie; Wohlgemuth, Jonas; Liu, Haiyang; Willett, Thomas C; Theodosiou, Eirini; Thomas, Owen R T; Franzreb, Matthias

    2013-04-12

    An integrated approach to temperature-controlled chromatography, involving copolymer modified agarose adsorbents and a novel travelling cooling zone reactor (TCZR) arrangement, is described. Sepharose CL6B was transformed into a thermoresponsive cation exchange adsorbent (thermoCEX) in four synthetic steps: (i) epichlorohydrin activation; (ii) amine capping; (iii) 4,4'-azobis(4-cyanovaleric acid) immobilization; and 'graft from' polymerization of poly(N-isopropylacrylamide-co-N-tert-butylacrylamide-co-acrylic acid-co-N,N'-methylenebisacrylamide). FT-IR, (1)H NMR, gravimetry and chemical assays allowed precise determination of the adsorbent's copolymer composition and loading, and identified the initial epoxy activation step as a critical determinant of 'on-support' copolymer loading, and in turn, protein binding performance. In batch binding studies with lactoferrin, thermoCEX's binding affinity and maximum adsorption capacity rose smoothly with temperature increase from 20 to 50 °C. In temperature shifting chromatography experiments employing thermoCEX in thermally jacketed columns, 44-51% of the lactoferrin adsorbed at 42 °C could be desorbed under binding conditions by cooling the column to 22 °C, but the elution peaks exhibited strong tailing. To more fully exploit the potential of thermoresponsive chromatography adsorbents, a new column arrangement, the TCZR, was developed. In TCZR chromatography, a narrow discrete cooling zone (special assembly of copper blocks and Peltier elements) is moved along a bespoke fixed-bed separation columnfilled with stationary phase. In tests with thermoCEX, it was possible to recover 65% of the lactoferrin bound at 35 °C using 8 successive movements of the cooling zone at a velocity of 0.1mm/s; over half of the recovered protein was eluted in the first peak in more concentrated form than in the feed. Intra-particle diffusion of desorbed protein out of the support pores, and the ratio between the velocities of the cooling

  15. Radioactive tracer test to develop a recycling system for operating reactor scrap metal

    SciTech Connect

    Umemura, A.; Kimura, K.; Takahashi, K.; Sakurai, D.; Yamamoto, M.; Abe, S.

    1995-12-31

    A demonstration test using radio-isotope (RI) tracers during the manufacturing of inner drum shielding material from the recycling of operating reactor scrap metal was completed and the following results were obtained. The behavior of five radionuclides (Mn-54, Co-60, Zn-65, Sr-85 and Cs-137) was established. The time-dependent behaviors of the radionuclides in molten steel and in slag were investigated. The radioactivity distributions in metal products were homogeneous. Dose equivalent rates in the working area were below background levels and radioactive dust concentrations in the air were below detection limits.

  16. Reverse logistics system planning for recycling computers hardware: A case study

    NASA Astrophysics Data System (ADS)

    Januri, Siti Sarah; Zulkipli, Faridah; Zahari, Siti Meriam; Shamsuri, Siti Hajar

    2014-09-01

    This paper describes modeling and simulation of reverse logistics networks for collection of used computers in one of the company in Selangor. The study focuses on design of reverse logistics network for used computers recycling operation. Simulation modeling, presented in this work allows the user to analyze the future performance of the network and to understand the complex relationship between the parties involved. The findings from the simulation suggest that the model calculates processing time and resource utilization in a predictable manner. In this study, the simulation model was developed by using Arena simulation package.

  17. The Dynamic Earth: Recycling Naturally!

    ERIC Educational Resources Information Center

    Goldston, M. Jenice; Allison, Elizabeth; Fowler, Lisa; Glaze, Amanda

    2013-01-01

    This article begins with a thought-provoking question: What do you think of when you hear the term "recycle?" Many think about paper, glass, aluminum cans, landfills, and reducing waste by reusing some of these materials. How many of us ever consider the way the systems of Earth dynamically recycle its materials? In the following…

  18. Reverse logistics system and recycling potential at a landfill: A case study from Kampala City.

    PubMed

    Kinobe, J R; Gebresenbet, G; Niwagaba, C B; Vinnerås, B

    2015-08-01

    The rapid growing population and high urbanisation rates in Sub-Saharan Africa has caused enormous pressure on collection services of the generated waste in the urban areas. This has put a burden on landfilling, which is the major waste disposal method. Waste reduction, re-use and recycling opportunities exist but are not fully utilized. The common items that are re-used and re-cycled are plastics, paper, aluminum, glass, steel, cardboard, and yard waste. This paper develops an overview of reverse logistics at Kiteezi landfill, the only officially recognised waste disposal facility for Kampala City. The paper analyses, in details the collection, re-processing, re-distribution and final markets of these products into a reversed supply chain network. Only 14% of the products at Kiteezi landfill are channeled into the reverse chain while 63% could be included in the distribution chain but are left out and disposed of while the remaining 23% is buried. This is because of the low processing power available, lack of market value, lack of knowledge and limited value addition activities to the products. This paper proposes possible strategies of efficient and effective reverse logistics development, applicable to Kampala City and other similar cities. PMID:25936554

  19. Precipitation Recycling

    NASA Technical Reports Server (NTRS)

    Eltahir, Elfatih A. B.; Bras, Rafael L.

    1996-01-01

    The water cycle regulates and reflects natural variability in climate at the regional and global scales. Large-scale human activities that involve changes in land cover, such as tropical deforestation, are likely to modify climate through changes in the water cycle. In order to understand, and hopefully be able to predict, the extent of these potential global and regional changes, we need first to understand how the water cycle works. In the past, most of the research in hydrology focused on the land branch of the water cycle, with little attention given to the atmospheric branch. The study of precipitation recycling which is defined as the contribution of local evaporation to local precipitation, aims at understanding hydrologic processes in the atmospheric branch of the water cycle. Simply stated, any study on precipitation recycling is about how the atmospheric branch of the water cycle works, namely, what happens to water vapor molecules after they evaporate from the surface, and where will they precipitate?

  20. The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies

    DOE PAGESBeta

    Gill, Gary A.; Kuo, Li -Jung; Janke, Christopher James; Park, Jiyeon; Jeters, Robert T.; Bonheyo, George T.; Pan, Horng -Bin; Wai, Chien; Khangaonkar, Tarang P.; Bianucci, Laura; et al

    2016-02-07

    The Pacific Northwest National Laboratory's (PNNL) Marine Science Laboratory (MSL) located along the coast of Washington State is evaluating the performance of uranium adsorption materials being developed for seawater extraction under realistic marine conditions with natural seawater. Two types of exposure systems were employed in this program: flow-through columns for testing of fixed beds of individual fibers and pellets and a recirculating water flume for testing of braided adsorbent material. Testing consists of measurements of the adsorption of uranium and other elements from seawater as a function of time, typically 42 to 56 day exposures, to determine the adsorbent capacitymore » and adsorption rate (kinetics). Analysis of uranium and other trace elements collected by the adsorbents was conducted following strong acid digestion of the adsorbent with 50% aqua regia using either Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) or Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The ORNL 38H adsorbent had a 56 day adsorption capacity of 3.30 ± 0.68 g U/ kg adsorbent (normalized to a salinity of 35 psu), a saturation adsorption capacity of 4.89 ± 0.83 g U/kg of adsorbent material (normalized to a salinity of 35 psu) and a half-saturation time of 28 10 days. The AF1 adsorbent material had a 56 day adsorption capacity of 3.9 ± 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu), a saturation capacity of 5.4 ± 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu) and a half saturation time of 23 2 days. The ORNL amidoxime-based adsorbent materials are not specific for uranium, but also adsorb other elements from seawater. The major doubly charged cations in seawater (Ca and Mg) account for a majority of the cations adsorbed (61% by mass and 74% by molar percent). For the ORNL AF1 adsorbent material, U is the 4th most abundant element adsorbed by mass and 7th most abundant by molar percentage. Marine testing

  1. The Uranium from Seawater Program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies

    SciTech Connect

    Gill, Gary; Kuo, Li-Jung; Janke, Christopher James; Park, Jiyeon; Jeters, Robert T; Bonheyo, George; Pan, Horng-Bin; Wai, Chien; Khangaonkar, Tarang P; Bianucci, Laura; Wood, Jordana; Warner, Marvin G; Peterson, Sonja; Abrecht, David; Mayes, Richard T; Tsouris, Costas; Oyola, Yatsandra; Strivens, Jonathan E.; Schlafer, Nicholas; Addleman, Shane R; Chouyyok, Wilaiwan; Das, Sadananda; Kim, Jungseung; Buesseler, Dr. Ken; Breier, Crystalline; D'Alessandro, Dr. Evan

    2016-01-01

    The Pacific Northwest National Laboratory s (PNNL) Marine Science Laboratory (MSL) located along the coast of Washington State is evaluating the performance of uranium adsorption materials being developed for seawater extraction under realistic marine conditions with natural seawater. Two types of exposure systems were employed in this program: flow-through columns for testing of fixed beds of individual fibers and pellets and a recirculating water flume for testing of braided adsorbent material. Testing consists of measurements of the adsorption of uranium and other elements from seawater as a function of time, typically 42 to 56 day exposures, to determine the adsorbent capacity and adsorption rate (kinetics). Analysis of uranium and other trace elements collected by the adsorbents was conducted following strong acid digestion of the adsorbent with 50% aqua regia using either Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) or Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The ORNL 38H adsorbent had a 56 day adsorption capacity of 3.30 0.68 g U/ kg adsorbent (normalized to a salinity of 35 psu), a saturation adsorption capacity of 4.89 0.83 g U/kg of adsorbent material (normalized to a salinity of 35 psu) and a half-saturation time of 28 10 days. The AF1 adsorbent material had a 56 day adsorption capacity of 3.9 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu), a saturation capacity of 5.4 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu) and a half saturation time of 23 2 days. The ORNL amidoxime-based adsorbent materials are not specific for uranium, but also adsorb other elements from seawater. The major doubly charged cations in seawater (Ca and Mg) account for a majority of the cations adsorbed (61% by mass and 74% by molar percent). For the ORNL AF1 adsorbent material, U is the 4th most abundant element adsorbed by mass and 7th most abundant by molar percentage. Marine testing at Woods Hole

  2. Foulant Characteristics Comparison in Recycling Cooling Water System Makeup by Municipal Reclaimed Water and Surface Water in Power Plant

    PubMed Central

    Ping, Xu; Jing, Wang; Yajun, Zhang; Jie, Wang; Shuai, Si

    2015-01-01

    Due to water shortage, municipal reclaimed water rather than surface water was replenished into recycling cooling water system in power plants in some cities in China. In order to understand the effects of the measure on carbon steel corrosion, characteristics of two kinds of foulant produced in different systems were studied in the paper. Differences between municipal reclaimed water and surface water were analyzed firstly. Then, the weight and the morphology of two kinds of foulant were compared. Moreover, other characteristics including the total number of bacteria, sulfate reducing bacteria, iron bacteria, extracellular polymeric substance (EPS), protein (PN), and polysaccharide (PS) in foulant were analyzed. Based on results, it could be concluded that microbial and corrosive risk would be increased when the system replenished by municipal reclaimed water instead of surface water. PMID:25893132

  3. Foulant characteristics comparison in recycling cooling water system makeup by municipal reclaimed water and surface water in power plant.

    PubMed

    Ping, Xu; Jing, Wang; Yajun, Zhang; Jie, Wang; Shuai, Si

    2015-01-01

    Due to water shortage, municipal reclaimed water rather than surface water was replenished into recycling cooling water system in power plants in some cities in China. In order to understand the effects of the measure on carbon steel corrosion, characteristics of two kinds of foulant produced in different systems were studied in the paper. Differences between municipal reclaimed water and surface water were analyzed firstly. Then, the weight and the morphology of two kinds of foulant were compared. Moreover, other characteristics including the total number of bacteria, sulfate reducing bacteria, iron bacteria, extracellular polymeric substance (EPS), protein (PN), and polysaccharide (PS) in foulant were analyzed. Based on results, it could be concluded that microbial and corrosive risk would be increased when the system replenished by municipal reclaimed water instead of surface water. PMID:25893132

  4. RECYCLABILITY INDEX FOR AUTOMOBILES

    EPA Science Inventory

    The project's purpose is to create a rating system for the ecological impacts of vehicles at the end of their life based on recyclability, toxic material content, and ultimate disposal. Each year, 10-11 million vehicles are retired from service in the United States. The vehi...

  5. Quantitative sustainability and qualitative concerns in an irrigations system using recycled water to supplement limited groundwater supply

    NASA Astrophysics Data System (ADS)

    Gowing, John; Alataway, Abed

    2013-04-01

    Sustainability of irrigation in a country facing water scarcity depends upon adoption of best management practices to deliver 'more crop per drop' together with use of recycled waste-water from urban sewage systems. Saudi Arabia is a country facing extreme water scarcity and in this paper we report on research conducted at an extensive irrigation system where a concerted effort over several years has been devoted to achieving a high level of water productivity. Al-Ahsa oasis is located about 60 km inland from the Persian Gulf and has been inhabited since prehistoric times, due to the abundance of water in an otherwise arid region. It is one of the largest oases in the world with 12,000 hectares of irrigated land and more than 2 million palm trees. Historically the oasis was watered by over 60 artesian springs, but water is now pumped from the aquifer. To supplement this groundwater source, treated waste-water reuse has been practiced since 1992 and now comprises 30% of total supply. In addition, a comparable amount of agricultural drainage water is collected and recycled, so that the 'first-use' water represents only 40% of total irrigation supply. While this re-use system permits sustained irrigation with greatly reduced groundwater abstraction, there is a potential down-side in that fertilizers and contaminants applied with irrigation water move through the soil and return to the irrigation supply enhancing the risk for human and animal health. We investigated this problem using E coli and helminth eggs as indicators of human health risk. We sampled each of the three sources which are delivered separately to the head of the main irrigation canal where they are blended. The groundwater was free from E coli and helminths and the treated wastewater source was generally within designated quality standards. The recycled drainage water was delivered untreated into the canal system and was found to be contaminated with both E coli and helminths above acceptable

  6. Bromocriptine tablet of self-microemulsifying system adsorbed onto porous carrier to stimulate lipoproteins secretion for brain cellular uptake.

    PubMed

    Thongrangsalit, Sirigul; Phaechamud, Thawatchai; Lipipun, Vimolmas; Ritthidej, Garnpimol C

    2015-07-01

    Both low solubility and high hepatic metabolism cause low oral bioavailability of bromocriptine mesylate (BM) leading to very low drug amount in brain. Self-microemulsion (SME) tablets were developed to improve solubility, stimulate lipoprotein synthesis to promote lymphatic transport, avoid hepatic metabolism and target drug to brain. SME liquid containing castor oil, Tween(®) 80 and Cremophor(®) EL was prepared and then adsorbed onto solid carries, Aerosil(®)200, Aeroperl(®)300 or NeusilinUS2(®), yielding SME powders. The optimal ratios of SME liquid to carriers determined from flowability and scanning electron photomicrographs before tableting were 1.5:1, 2:1 and 2.5:1 for Aerosil(®)200, Aeroperl(®)300 and NeusilinUS2(®), respectively. Only Aeroperl(®)300 SME tablet had comparable dissolution to BM commercial tablet. From in vitro study in Caco-2 cells, fluorescein loaded SME tablet showed higher uptake than fluorescein loaded in either oil or surfactant. Although significantly lower amount of drug was permeated from SME tablet than from commercial tablet, higher drug uptake was obviously observed (P<0.05). In addition, higher lipoprotein synthesis expressing as content of apolipoprotein B (apo-B) found in secreted chylomicron resulted in higher drug uptake in co-culture of brain endothelial cells (bEnd.3) and astrocytes (CTX TNA2) from drug loaded SME tablet when compared to commercial tablet (P<0.05) due to binding of apo-B to LDL receptors expressed on the surface of endothelial cells. Therefore, tablet of SME adsorbed onto porous carrier potentially delivered BM to brain via lymphatic transport by increasing the lipoprotein synthesis. PMID:25988280

  7. Use of halophytic plants for recycling NaCl in human liquid waste in a bioregenerative life support system

    NASA Astrophysics Data System (ADS)

    Balnokin, Yurii; Nikolai, Myasoedov; Larisa, Popova; Alexander, Tikhomirov; Sofya, Ushakova; Christophe, Lasseur; Jean-Bernard, Gros

    2010-09-01

    The purpose of this work was to develop technology for recycling NaCl containing in human liquid waste as intrasystem matter in a bioregenerative life support system (BLSS). The circulation of Na + and Cl - excreted in urine is achieved by inclusion of halophytes, i.e. plants that naturally inhabit salt-rich soils and accumulate NaCl in their organs. A model of Na + and Cl - recycling in a BLSS was designed, based on the NaCl turnover in the human-urine-nutrient solution-halophytic plant-human cycle. The study consisted of (i) selecting a halophyte suitable for inclusion in a BLSS, and (ii) determining growth conditions supporting maximal Na + and Cl - accumulation in the shoots of the halophyte growing in a nutrient solution simulating mineralized urine. For the selected halophytic plant, Salicornia europaea, growth rate under optimal conditions, biomass production and quantities of Na + and Cl - absorbed were determined. Characteristics of a plant production conveyor consisting of S.europaea at various ages, and allowing continuity of Na + and Cl - turnover, were estimated. It was shown that closure of the NaCl cycle in a BLSS can be attained if the daily ration of fresh Salicornia biomass for a BLSS inhabitant is approximately 360 g.

  8. NADPH recycling systems in oxidative stressed pea nodules: a key role for the NADP+ -dependent isocitrate dehydrogenase.

    PubMed

    Marino, Daniel; González, Esther M; Frendo, Pierre; Puppo, Alain; Arrese-Igor, Cesar

    2007-01-01

    The symbiosis between legumes and rhizobia is characterised by the formation of dinitrogen-fixing root nodules. In natural conditions, nitrogen fixation is strongly impaired by abiotic stresses which generate over-production of reactive oxygen species. Since one of the nodule main antioxidant systems is the ascorbate-glutathione cycle, NADPH recycling that is involved in glutathione reduction is of great relevance under stress conditions. NADPH is mainly produced by glucose 6-phosphate dehydrogenase (G6PDH; EC 1.1.1.49) and 6-phosphogluconate dehydrogenase (6PGDH; EC 1.1.1.44) from the oxidative pentose phosphate pathway, and also by NADP(+)-dependent isocitrate dehydrogenase (ICDH; EC 1.1.1.42). In this work, 10 microM paraquat (PQ) was applied to pea roots in order to determine the in vivo relationship between oxidative stress and the activity of the NADPH-generating enzymes in nodules. Whereas G6PDH and 6PGDH activities remained unchanged, a remarkable induction of ICDH gene expression and a dramatic increase of the ICDH activity was observed during the PQ treatment. These results support that ICDH has a key role in NADPH recycling under oxidative stress conditions in pea root nodules. PMID:16896792

  9. Hydrophobic Porous Material Adsorbs Small Organic Molecules

    NASA Technical Reports Server (NTRS)

    Sharma, Pramod K.; Hickey, Gregory S.

    1994-01-01

    Composite molecular-sieve material has pore structure designed specifically for preferential adsorption of organic molecules for sizes ranging from 3 to 6 angstrom. Design based on principle that contaminant molecules become strongly bound to surface of adsorbent when size of contaminant molecules is nearly same as that of pores in adsorbent. Material used to remove small organic contaminant molecules from vacuum systems or from enclosed gaseous environments like closed-loop life-support systems.

  10. Recycling Flight Hardware Components and Systems to Reduce Next Generation Research Costs

    NASA Technical Reports Server (NTRS)

    Turner, Wlat

    2011-01-01

    With the recent 'new direction' put forth by President Obama identifying NASA's new focus in research rather than continuing on a path to return to the Moon and Mars, the focus of work at Kennedy Space Center (KSC) may be changing dramatically. Research opportunities within the micro-gravity community potentially stands at the threshold of resurgence when the new direction of the agency takes hold for the next generation of experimenters. This presentation defines a strategy for recycling flight experiment components or part numbers, in order to reduce research project costs, not just in component selection and fabrication, but in expediting qualification of hardware for flight. A key component of the strategy is effective communication of relevant flight hardware information and available flight hardware components to researchers, with the goal of 'short circuiting' the design process for flight experiments

  11. Recycling plant, human and animal wastes to plant nutrients in a closed ecological system

    NASA Technical Reports Server (NTRS)

    Meissner, H. P.; Modell, M.

    1979-01-01

    The essential minerals for plant growth are nitrogen, phosphorous, potassium (macronutrients), calcium, magnesium, sulfur (secondary nutrients), iron, manganese, boron, copper, zinc, chlorine, sodium, and molybdenum (micronutrients). The first step in recycling wastes will undoubtedly be oxidation of carbon and hydrogen to CO2 and H2O. Transformation of minerals to plant nutrients depends upon the mode of oxidation to define the state of the nutrients. For the purpose of illustrating the type of processing required, ash and off-gas compositions of an incineration process were assumed and subsequent processing requirements were identified. Several processing schemes are described for separating out sodium chloride from the ash, leading to reformulation of a nutrient solution which should be acceptable to plants.

  12. Extensive Treatment System For Recycling Water For Flushing Fresh Manure And Recovering Nutrients

    NASA Astrophysics Data System (ADS)

    Morand, Philippe; Robin, Paul; Escande, Aurélie; Picot, Bernadette; Pourcher, Anne-Marie; Jiangping, Qiu; Yinsheng, Li; Hamon, Gwenn; Amblard, Charlotte; Luth, Fievet, Sébastien; Oudart, Didier; Le Quéré, Camille Pain; Cluzeau, Daniel; Landrain, Brigitte

    2010-11-01

    From preliminary researches on a pilot scale, a complete demonstration plant was built to treat the effluents of a 30 pregnant sow's piggery. It includes a screen, a vermifilter, a macrophyte lagooning, and a complementary water storage pond; the recycled water is used for flushing, and rainfall is collected to compensate for evapotranspiration. After functioning in 2008 and 2009, it was showed that, during the warm season, the whole plant produced an effluent suitable for flushing, where the concentration decrease was over 70% for the phosphorus and potassium, 95% for the COD and nitrogen, 99.8% for endocrine disruptors (estrogenic activity), and 99.99% for pathogenic micro-organisms. During the cold season, the dilution by the rain water and the treatment effect of the constructed wetlands lead to similar results. Nevertheless, for this season, suitable floating macrophytes that will cover the lagoons remain to be settled.

  13. Fermilab Recycler Stochastic Cooling for Luminosity Production

    SciTech Connect

    Broemmelsiek, D.; Gattuso, C.

    2006-03-20

    The Fermilab Recycler began regularly delivering antiprotons for Tevatron luminosity operations in 2005. Methods for tuning the Recycler stochastic cooling system are presented. The unique conditions and resulting procedures for minimizing the longitudinal phase space density of the Recycler antiproton beam are outlined.

  14. Adsorbed Water Illustration

    NASA Technical Reports Server (NTRS)

    2008-01-01

    The Thermal and Electrical Conductivity Probe on NASA's Phoenix Mars Lander detected small and variable amounts of water in the Martian soil.

    In this schematic illustration, water molecules are represented in red and white; soil minerals are represented in green and blue. The water, neither liquid, vapor, nor solid, adheres in very thin films of molecules to the surfaces of soil minerals. The left half illustrates an interpretation of less water being adsorbed onto the soil-particle surface during a period when the tilt, or obliquity, of Mars' rotation axis is small, as it is in the present. The right half illustrates a thicker film of water during a time when the obliquity is greater, as it is during cycles on time scales of hundreds of thousands of years. As the humidity of the atmosphere increases, more water accumulates on mineral surfaces. Thicker films behave increasingly like liquid water.

    The Phoenix Mission is led by the University of Arizona, Tucson, on behalf of NASA. Project management of the mission is by NASA's Jet Propulsion Laboratory, Pasadena, Calif. Spacecraft development is by Lockheed Martin Space Systems, Denver.

  15. Recycling of quartz-poor/lithic-rich foreland-basin sediments in arid climate (Euphrates-Tigris-Karun river system)

    NASA Astrophysics Data System (ADS)

    Garzanti, Eduardo; Juboury, Ali Ismail Al; Zoleikhaei, Yousef; Vermeesch, Pieter; Hamzah Abdulhussein Jotheri, Jaafar; Akkoca, Dicle Bal; Allen, Mark; Andò, Sergio; Limonta, Mara; Padoan, Marta; Resentini, Alberto; Vezzoli, Giovanni

    2016-04-01

    In this detailed petrological analysis of a large source-to-sink sediment-routing system (catchment area > 1 million km2) we document its several peculiarities, and illustrate a rich petrographic and heavy-mineral dataset integrated by bulk-sediment geochemistry and detrital-zircon U-Pb geochronological data that widens the spectrum of compositions generally assumed as paradigmatic for orogenic settings. We test traditional versus upgraded sedimentary-petrology models in the endeavor to derive a more refined conceptual model of reference, in order to enhance the power of provenance analysis but also to define its limitations and understand which secret of nature is likely to remain beyond reach in our efforts to reconstruct orogenic landscapes of the past. Sands derived from the Zagros-Southeast Anatolian fold-thrust belt contain an abundance of lithic grains derived not only first-cycle from carbonates, cherts, mudrocks, arc volcanics, and obducted mantle serpentinites representing the exposed shallow structural level of the orogen, but also recycled from Neogene molassic strata exposed in the foothills. Quartz, K-feldspar and mica are equally scarce in first-cycle and recycled sediments. This quartz-poor petrographic signature, characterizing the broad undissected tectonic domain of the Anatolia-Iranian plateau, is markedly distinct from that of sands shed by highly elevated and dissected collision orogens of the same mountain system such as the Himalaya or the Alps. Arid climate in the region allows full preservation of chemically unstable grains including carbonate and mafic/ultramafic rock fragments even through more than a single sedimentary cycle. Also, it reduces transport capacity of fluvial systems, which dump most of their load in Mesopotamian marshlands upstream of the Arabian/Persian Gulf allochemical carbonate factory. Quartz-poor orogenic sediments from the Zagros-Southeast Anatolian range mix with quartz-rich recycled sands ultimately derived from

  16. Recycling Lesson Plans.

    ERIC Educational Resources Information Center

    Pennsylvania State Dept. of Environmental Resources, Harrisburg.

    This document contains lesson plans about recycling for teachers in grades K-12. Titles include: (1) "Waste--Where Does It Come From? Where Does It Go?" (2) "Litter Detectives," (3) "Classroom Paper Recycling," (4) "Recycling Survey," (5) "Disposal and Recycling Costs," (6) "Composting Project," (7) Used Motor Oil Recycling," (8) "Unwrapping…

  17. Update on performance tests from the COBRA Process, a combined SO{sub 2} and NO{sub x} removal system[Copper Oxide Bed Regenerable Adsorber

    SciTech Connect

    Breault, R.W.; Litka, T.

    1999-07-01

    The Low Emission Boiler System (LEBS) Program of the US Department of Energy (DOE) is developing advanced power systems to accelerate the commercialization of affordable, highly efficient, and low-emission pulverized coal-fueled electric generating technologies. DB Riley Inc.'s concept for LEBS includes a dry, regenerable flue gas desulfurization and denitrification process. The COBRA (Copper Oxide Bed Regenerable Adsorber) Process can efficiently remove sulfur dioxide (SO{sub 2}) and sulfur trioxide (SO{sub 3}) and reduce nitrogen oxides (NO{sub x}) from flue gas with no solid or liquid byproducts and at a competitive cost. The sulfur laden flue gas is contacted with copper oxide impregnated alumina substrate in a cross flow moving bed reactor operating at 700 F. Sulfur dioxide reacts with the copper to form copper sulfate and the copper oxide/copper sulfate bed acts as a selective catalyst for NO{sub x} reduction. The sulfated sorbent is transported from the bottom of the moving bed reactors to the regenerator vessels where methane is used to reduce the copper sulfate to copper and SO{sub 2}. The concentrated SO{sub 2} stream resulting from regeneration may be oxidized to SO{sub 3} and condensed to sulfuric acid or can be converted to elemental sulfur in a Claus Plant or scrubbed with ammonia to form an ammonium sulfate. This paper will present the results of performance testing conducted on a 1 MW Pilot Scale Facility located at the Illinois Coal Development Park. This facility was designed and built to demonstrate at a reasonable scale the component configurations to be utilized in a full-scale system and to verify and optimize the operation of the integrated system. The ability of laboratory tests, when combined with a model of the moving bed adsorber, to predict the performance of the pilot system will be shown.

  18. Electron Transfer Reactivity Patterns at Chemically Modified Electrodes: Fundamentals and Application to the Optimization of Redox Recycling Amplification Systems

    SciTech Connect

    Adam Johan Bergren

    2006-05-01

    Electroanalytical chemistry is often utilized in chemical analysis and Fundamental studies. Important advances have been made in these areas since the advent of chemically modified electrodes: the coating of an electrode with a chemical film in order to impart desirable, and ideally, predictable properties. These procedures enable the exploitation of unique reactivity patterns. This dissertation presents studies that investigate novel reaction mechanisms at self-assembled monolayers on gold. In particular, a unique electrochemical current amplification scheme is detailed that relies on a selective electrode to enable a reactivity pattern that results in regeneration of the analyte (redox recycling). This regenerating reaction can occur up to 250 times for each analyte molecule, leading to a notable enhancement in the observed current. The requirements of electrode selectivity and the resulting amplification and detection limit improvements are described with respect to the heterogeneous and homogeneous electron transfer rates that characterize the system. These studies revealed that the heterogeneous electrolysis of the analyte should ideally be electrochemically reversible, while that for the regenerating agent should be held to a low level. Moreover, the homogeneous reaction that recycles the analyte should occur at a rapid rate. The physical selectivity mechanism is also detailed with respect to the properties of the electrode and redox probes utilized. It is shown that partitioning of the analyte into/onto the adlayer leads to the extraordinary selectivity of the alkanethiolate monolayer modified electrode. Collectively, these studies enable a thorough understanding of the complex electrode mechanism required for successful redox recycling amplification systems, Finally, in a separate (but related) study, the effect of the akyl chain length on the heterogeneous electron transfer behavior of solution-based redox probes is reported, where an odd-even oscillation

  19. Effect of tungsten concentration on growth of acetobacter xylinum as a promising agent for eco-friendly recycling system

    NASA Astrophysics Data System (ADS)

    Nandiyanto, A. B. D.; Halimatul, H. S.; Rosyid, N. H.; Effendi, D. B.

    2016-04-01

    Effect of tungsten (W) concentration on Acetobacter xylinum growth was studied. In the experimental procedure, concentration of W in the bacterial growth medium containing pineapple peels waste was varied from 0.5 to 50 ppm. To confirm the influence of W, the bacterial incubation process was carried out for 72 hours. Spectrophotometer analysis showed that the growth rate of Acetobacter xylinum decreased with increasing concentration of W. The result from fourier transform infra red analysis showed a slightly change on the absorption peak intensities and informing the interaction of W ion and bacteria cell. The result confirmed that Acetobacter xylinum was able to uptake W concentration up to 15 ppm, indicating that Acetobacter xylinum might act as a promising agent for eco-friendly recycling system.

  20. Band structure and charge doping effects of the potassium-adsorbed FeSe /SrTiO3 system

    NASA Astrophysics Data System (ADS)

    Zheng, Fawei; Wang, Li-Li; Xue, Qi-Kun; Zhang, Ping

    2016-02-01

    We theoretically study, through combining the density functional theory and an unfolding technique, the electronic band structure and the charge doping effects for the deposition of potassium on multilayer FeSe films grown on SrTiO3 (001) surface. These results form a theoretical baseline for further detailed studies of low-temperature electronic properties and their multiway quantum engineering of FeSe thin films. We explain the Fermi-surface topology observed in experiment and formulate the amount of doped electrons as a function of atomic K coverage. We show that the atomic K deposition efficiently dopes electrons to the top layer of FeSe. Both checkerboard- and pair-checkerboard-antiferromagnetic (AFM) FeSe layers show electron pockets at the M point and no Fermi pocket at the Γ point with moderate atomic K coverage. The electron transfer from the K adsorbate to the FeSe film introduces a strong electric field, which leads to a double-Weyl-cone structure at the M point in the Brillouin zone of checkerboard-AFM FeSe. We demonstrate that with experimentally accessible heavy-electron doping, an electronlike Fermi pocket will emerge at the Γ point, which should manifest itself in modulating the high-temperature superconductivity of FeSe thin films.

  1. Removal of PCP-Na from aqueous systems using monodispersed pompon-like magnetic nanoparticles as adsorbents.

    PubMed

    Liu, Yu; Yu, Hongbing; Zhan, Sihui; Li, Shengjun; Yang, Hui; Liu, Bo

    2013-01-01

    Novel monodispersed pompon-like magnetite/chitosan (Fe3O4/CS) composite nanoparticles were synthesized by a solvothermal method and used as adsorbents for the removal of toxic sodium pentachlorophenate (PCP-Na) from aqueous media. The adsorption behavior of PCP-Na on Fe3O4/CS obeyed the Langmuir isotherm and fitted the pseudo-second-order kinetics model. Thermodynamic parameters showed that the adsorption process was exothermic and spontaneous. Moreover, the adsorption was strongly pH-dependent. The results of XPS, thermodynamics, pH-dependent and desorption studies suggested that electrostatic attraction, hydrogen bonding and π-π interactions were all believed to play a role in PCP-Na adsorption on Fe3O4/CS. Having a saturation magnetization of 22.2 emu · g(-1), the Fe3O4/CS can be easily separated from water with magnets within 2 min. The adsorption equilibrium was achieved quite rapidly (within 30 min) and the maximum removal of PCP-Na (91.5%) was obtained at 25 °C and pH 6.5. The Fe3O4/CS investigated can be used to remove PCP-Na and other contaminants from wastewater. PMID:24355861

  2. Biosorption and recycling of gold using various microorganisms.

    PubMed

    Tsuruta, Takehiko

    2004-08-01

    In order to obtain basic information on the biosorption and recycling of gold from aqueous systems using microbial cells, the biosorption of gold by various microorganisms was investigated. Of 75 strains of microorganisms tested (25 bacteria, 19 actinomycetes, 17 fungi and 14 yeasts), high abilities of gold biosorption from a solution containing hydrogen tetrachloroaurate (III) were found in some gram-negative bacterial strains, such as Acinetobacter calcoaceticus, Erwinia herbicola, Pseudomonas aeruginosa, and P. maltophilia. Most of the gram-positive bacteria, actinomycetes, fungi and yeasts had a lower ability for gold biosorption than gram-negative bacteria. On the other hand, all of the microorganisms tested adsorbed far smaller amounts of gold from a solution containing gold dicyanoaurate (I). The biosorption of gold from a solution containing hydrogen tetrachloroaurate (III) using P. maltophilia having a high adsorbing ability for gold was very rapid and was affected by the pH of the solution, external gold concentration, and cell amounts. P. maltophilia cells immobilized with polyacrylamide gel also have a high ability for gold biosorption. The gold adsorbed on the immobilized cells is easily desorbed with 0.1 M thiourea solution. The immobilized P. maltophilia cells can be used repeatedly in biosorption-desorption cycles. PMID:15754248

  3. Strategies for regeneration of nicotinamide coenzymes emphasizing self-sufficient closed-loop recycling systems.

    PubMed

    Hummel, Werner; Gröger, Harald

    2014-12-10

    Biocatalytic reduction reactions depending on nicotinamide coenzymes require an additional reaction to regenerate the consumed cofactor. For preparative application the preferred method is the simultaneous coupling of an in situ regeneration reaction. There are different strategically advantageous routes to achieve this goal. The standard method uses a second enzyme and a second co-substrate, for example formate and formate dehydrogenase or glucose and glucose dehydrogenase. Alternatively, a second substrate is employed which is converted by the same enzyme used for the primary reaction. For example, alcohol dehydrogenase catalyzed reactions are often coupled with excess 2-propanol which is oxidized to acetone during the regeneration of NAD(P)H. A third method utilizes a reaction-internal sequence by the direct coupling of an oxidizing and a reducing enzyme reaction. Neither an additional substrate nor a further regenerating enzyme are required for the recycling reaction. This kind of "closed-loop" or "self-sufficient" redox process for cofactor regeneration has been used rarely so far. Its most intriguing advantage is that even redox reactions with unstable precursors can be realized provided that this compound is produced in situ by an opposite redox reaction. This elegant method is applicable in special cases only but increasing numbers of examples have been published during the last years. PMID:25102236

  4. Comparison of the efficiencies of attached- versus suspended-growth SBR systems in the treatment of recycled paper mill wastewater.

    PubMed

    Muhamad, Mohd Hafizuddin; Sheikh Abdullah, Siti Rozaimah; Abu Hasan, Hassimi; Abd Rahim, Reehan Adnee

    2015-11-01

    The complexity of residual toxic organics from biologically treated effluents of pulp and paper mills is a serious concern. To date, it has been difficult to choose the best treatment technique because each of the available options has advantages and drawbacks. In this study, two different treatment techniques using laboratory-scale aerobic sequencing batch reactors (SBRs) were tested with the same real recycled paper mill effluent to evaluate their treatment efficiencies. Two attached-growth SBRs using granular activated carbon (GAC) with and without additional biomass and a suspended-growth SBR were used in the treatment of real recycled paper mill effluent at a chemical oxygen demand (COD) level in the range of 800-1300 mg/L, a fixed hydraulic retention time of 24 h and a COD:N:P ratio of approximately 100:5:1. The efficiency of this biological treatment process was studied over a 300-day period. The six most important wastewater quality parameters, namely, chemical oxygen demand (COD), turbidity, ammonia (expressed as NH3-N), phosphorus (expressed as PO4(3)-P), colour, and suspended solids (SS), were measured to compare the different treatment techniques. It was determined that these processes were able to almost completely and simultaneously eliminate COD (99%) and turbidity (99%); the removals of NH3-N (90-100%), PO4(3)-P (66-78%), colour (63-91%), and SS (97-99%) were also sufficient. The overall performance results confirmed that an attached-growth SBR system using additional biomass on GAC is a promising configuration for wastewater treatment in terms of performance efficiency and process stability under fluctuations of organic load. Hence, this hybrid system is recommended for the treatment of pulp and paper mill effluents. PMID:26311084

  5. Mesoporous Silica: A Suitable Adsorbent for Amines

    PubMed Central

    2009-01-01

    Mesoporous silica with KIT-6 structure was investigated as a preconcentrating material in chromatographic systems for ammonia and trimethylamine. Its adsorption capacity was compared to that of existing commercial materials, showing its increased adsorption power. In addition, KIT-6 mesoporous silica efficiently adsorbs both gases, while none of the employed commercial adsorbents did. This means that KIT-6 Mesoporous silica may be a good choice for integrated chromatography/gas sensing micro-devices. PMID:20628459

  6. A highly efficient ADH-coupled NADH-recycling system for the asymmetric bioreduction of carbon-carbon double bonds using enoate reductases.

    PubMed

    Tauber, Katharina; Hall, Melanie; Kroutil, Wolfgang; Fabian, Walter M F; Faber, Kurt; Glueck, Silvia M

    2011-06-01

    The asymmetric bioreduction of activated alkenes catalyzed by flavin-dependent enoate reductases from the OYE-family represents a powerful method for the production of optically active compounds. For its preparative-scale application, efficient and economic NADH-recycling is crucial. A novel enzyme-coupled NADH-recycling system is proposed based on the concurrent oxidation of a sacrificial sec-alcohol catalyzed by an alcohol dehydrogenase (ADH-A). Due to the highly favorable position of the equilibrium of ene-reduction versus alcohol-oxidation, the cosubstrate is only required in slight excess. PMID:21328323

  7. Recyclability information for electronic equipment: A case study of a PC monitor and a system unit. Report for 1 June 1996--31 January 1998

    SciTech Connect

    Dammert, T.; Kuuva, M.

    1997-12-31

    This project was a part of a larger cooperation project (RecyTech) to develop prehandling technologies for recycling household appliances and electronics equipment. The project was based on two case products from companies participating in the RecyTech-project: a personal computer system unit by Fujitsu ICL Computers and a monitor by Nokia Display Products.

  8. IR investigations of surfaces and adsorbates

    SciTech Connect

    Gwyn Williams

    2001-12-10

    Synchrotron infrared reflection-absorption measurements on single crystal metal surfaces with adsorbates have led to the determination of many key parameters related to the bonding vibrational modes and the dynamics of adsorbates. In particular, energy couplings between electrons and adsorbate motion have been shown to be a dominant mechanism on metal surfaces. Excellent agreement has been obtained with calculations for many of the observations, and the synergy between theory and experiment has led to a deeper understanding of the roles of electrons and phonons in determining the properties of interfaces and their roles in phenomena as diverse as friction, lubrication, catalysis and adhesion. Nonetheless, as the experiments are pushed harder, to describe such effects as co-adsorbed systems, disagreements continue to challenge the theory and our comprehension also is still evolving.

  9. Coal liquefaction with preasphaltene recycle

    DOEpatents

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  10. Thiophilic adsorbents for RIA and ELISA procedures.

    PubMed

    Oscarsson, S; Chaga, G; Porath, J

    1991-10-25

    Three types of agarose derivatives have been prepared and investigated as adsorbents for radioimmunoassay and ELISA analysis. The analytical systems were evaluated using beta 2 microglobulin as a model. After a competitive reaction between the immunocomponents in solution, the formed immune complexes were adsorbed onto the adsorbent in the presence of 0.5 M potassium sulfate in 0.1 M Tris, pH 7.5. The binding constant between the interaction site on human IgG and the adsorbent 3-(2-pyridylthio)-2-hydroxypropylagarose (Py-S-gel) was determined to be 1.5 x 10(7) M-1 and the binding capacity was 20 mg/ml gel. The immune complex was desorbed by deleting potassium sulfate from the buffer, and only 0.5% of the total applied protein remained after washing the adsorbent with 0.5 M NaOH. The same adsorbent can be used repetitively with different systems. PMID:1940385

  11. Adsorbent and adsorbent bed for materials capture and separation processes

    SciTech Connect

    Liu, Wei

    2011-01-25

    A method device and material for performing adsorption wherein a fluid mixture is passed through a channel in a structured adsorbent bed having a solid adsorbent comprised of adsorbent particles having a general diameter less than 100 um, loaded in a porous support matrix defining at least one straight flow channel. The adsorbent bed is configured to allow passage of a fluid through said channel and diffusion of a target material into said adsorbent under a pressure gradient driving force. The targeted molecular species in the fluid mixture diffuses across the porous support retaining layer, contacts the adsorbent, and adsorbs on the adsorbent, while the remaining species in the fluid mixture flows out of the channel.

  12. H. R. 1593: A Bill to protect the used oil recycling system, conserve a valuable resource, establish used oil management standards, and for other purposes. Introduced in the House of Representatives, One Hundred First Congress, First Session, March 23, 1989

    SciTech Connect

    Not Available

    1989-01-01

    This bill would protect the used oil recycling system, conserve a valuable resource, and establish used oil management standards. The act distinguishes between recycled oil and non-recycled oil as a hazardous waste. If an oil has been recycled, will be recycled, and has been stored for less than 12 months, it will not be listed as a hazardous material. Management standards will be proposed to protect human health and the environment from the hazards associated with improper handling of used oil. Also covered is record keeping and reporting, prohibition on mixing with hazardous wastes, inspections, and enforcement. Other sections deal with used oil recycling education, appropriations, and the procurement of used oil fuel by Federal agencies.

  13. The biogeochemical cycle of the adsorbed template. II - Selective adsorption of mononucleotides on adsorbed polynucleotide templates

    NASA Technical Reports Server (NTRS)

    Lazard, Daniel; Lahav, Noam; Orenberg, James B.

    1988-01-01

    Experimental results are presented for the verification of the specific interaction step of the 'adsorbed template' biogeochemical cycle, a simple model for a primitive prebiotic replication system. The experimental system consisted of gypsum as the mineral to which an oligonucleotide template attaches (Poly-C or Poly-U) and (5-prime)-AMP, (5-prime)-GMP, (5-prime)-CMP and (5-prime)-UMP as the interacting biomonomers. When Poly-C or Poly-U were used as adsorbed templates, (5-prime)-GMP and (5-prime)-AMP, respectively, were observed to be the most strongly adsorbed species.

  14. Photochemistry of Nitrate Adsorbed on Mineral Dust

    NASA Astrophysics Data System (ADS)

    Gankanda, A.; Grassian, V. H.

    2013-12-01

    Mineral dust particles in the atmosphere are often associated with adsorbed nitrate from heterogeneous reactions with nitrogen oxides including HNO3 and NO2. Although nitrate ion is a well-studied chromophore in natural waters, the photochemistry of adsorbed nitrate on mineral dust particles is yet to be fully explored. In this study, wavelength dependence of the photochemistry of adsorbed nitrate on different model components of mineral dust aerosol has been investigated using transmission FTIR spectroscopy. Al2O3, TiO2 and NaY zeolite were used as model systems to represent non-photoactive oxides, photoactive semiconductor oxides and porous materials respectively, present in mineral dust aerosol. In this study, adsorbed nitrate is irradiated with 254 nm, 310 nm and 350 nm narrow band light. In the irradiation with narrow band light, NO2 is the only detectable gas-phase product formed from nitrate adsorbed on Al2O3 and TiO2. The NO2 yield is highest at 310 nm for both Al2O3 and TiO2. Unlike Al2O3 and TiO2, in zeolite, adsorbed nitrate photolysis to nitrite is observed only at 310 nm during narrow band irradiation. Moreover gas phase products were not detected during nitrate photolysis in zeolite at all three wavelengths. The significance of these differences as related to nitrate photochemistry on different mineral dust components will be highlighted.

  15. Plastics recycling: challenges and opportunities

    PubMed Central

    Hopewell, Jefferson; Dvorak, Robert; Kosior, Edward

    2009-01-01

    Plastics are inexpensive, lightweight and durable materials, which can readily be moulded into a variety of products that find use in a wide range of applications. As a consequence, the production of plastics has increased markedly over the last 60 years. However, current levels of their usage and disposal generate several environmental problems. Around 4 per cent of world oil and gas production, a non-renewable resource, is used as feedstock for plastics and a further 3–4% is expended to provide energy for their manufacture. A major portion of plastic produced each year is used to make disposable items of packaging or other short-lived products that are discarded within a year of manufacture. These two observations alone indicate that our current use of plastics is not sustainable. In addition, because of the durability of the polymers involved, substantial quantities of discarded end-of-life plastics are accumulating as debris in landfills and in natural habitats worldwide. Recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today. Recycling provides opportunities to reduce oil usage, carbon dioxide emissions and the quantities of waste requiring disposal. Here, we briefly set recycling into context against other waste-reduction strategies, namely reduction in material use through downgauging or product reuse, the use of alternative biodegradable materials and energy recovery as fuel. While plastics have been recycled since the 1970s, the quantities that are recycled vary geographically, according to plastic type and application. Recycling of packaging materials has seen rapid expansion over the last decades in a number of countries. Advances in technologies and systems for the collection, sorting and reprocessing of recyclable plastics are creating new opportunities for recycling, and with the combined actions of the public, industry and governments it

  16. Plastics recycling: challenges and opportunities.

    PubMed

    Hopewell, Jefferson; Dvorak, Robert; Kosior, Edward

    2009-07-27

    Plastics are inexpensive, lightweight and durable materials, which can readily be moulded into a variety of products that find use in a wide range of applications. As a consequence, the production of plastics has increased markedly over the last 60 years. However, current levels of their usage and disposal generate several environmental problems. Around 4 per cent of world oil and gas production, a non-renewable resource, is used as feedstock for plastics and a further 3-4% is expended to provide energy for their manufacture. A major portion of plastic produced each year is used to make disposable items of packaging or other short-lived products that are discarded within a year of manufacture. These two observations alone indicate that our current use of plastics is not sustainable. In addition, because of the durability of the polymers involved, substantial quantities of discarded end-of-life plastics are accumulating as debris in landfills and in natural habitats worldwide. Recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today. Recycling provides opportunities to reduce oil usage, carbon dioxide emissions and the quantities of waste requiring disposal. Here, we briefly set recycling into context against other waste-reduction strategies, namely reduction in material use through downgauging or product reuse, the use of alternative biodegradable materials and energy recovery as fuel. While plastics have been recycled since the 1970s, the quantities that are recycled vary geographically, according to plastic type and application. Recycling of packaging materials has seen rapid expansion over the last decades in a number of countries. Advances in technologies and systems for the collection, sorting and reprocessing of recyclable plastics are creating new opportunities for recycling, and with the combined actions of the public, industry and governments it

  17. Rab11-family interacting proteins define spatially and temporally distinct regions within the dynamic Rab11a-dependent recycling system

    PubMed Central

    Baetz, Nicholas W.; Goldenring, James R.

    2013-01-01

    The Rab11-family interacting proteins (Rab11-FIPs) facilitate Rab11-dependent vesicle recycling. We hypothesized that Rab11-FIPs define discrete subdomains and carry out temporally distinct roles within the recycling system. We used live-cell deconvolution microscopy of HeLa cells expressing chimeric fluorescent Rab11-FIPs to examine Rab11-FIP localization, transferrin passage through Rab11-FIP–containing compartments, and overlap among Rab11-FIPs within the recycling system. FIP1A, FIP2, and FIP5 occupy widely distributed mobile tubules and vesicles, whereas FIP1B, FIP1C, and FIP3 localize to perinuclear tubules. Internalized transferrin entered Rab11-FIP–containing compartments within 5 min, reaching maximum colocalization with FIP1B and FIP2 early in the time course, whereas localization with FIP1A, FIP1C, FIP3, and FIP5 was delayed until 10 min or later. Whereas direct interactions with FIP1A were only observed for FIP1B and FIP1C, FIP1A also associated with membranes containing FIP3. Live-cell dual-expression studies of Rab11-FIPs revealed the tubular dynamics of Rab11-FIP–containing compartments and demonstrated a series of selective associations among Rab11-FIPs in real time. These findings suggest that Rab11-FIP1 proteins participate in spatially and temporally distinct steps of the recycling process along a complex and dynamic tubular network in which Rab11-FIPs occupy discrete domains. PMID:23283983

  18. Extending the life and recycle capability of earth storable propellant systems.

    NASA Technical Reports Server (NTRS)

    Schweickert, T. F.

    1972-01-01

    Rocket propulsion systems for reusable vehicles will be required to operate reliably for a large number of missions with a minimum of maintenance and a fast turnaround. For the space shuttle reaction control system to meet these requirements, current and prior related system failures were examined for their impact on reuse and, where warranted, component design and/or system configuration changes were defined for improving system service life. It was found necessary to change the pressurization component arrangement used on many single-use applications in order to eliminate a prevalent check valve failure mode and to incorporate redundant expulsion capability in propellant tank designs to achieve the necessary system reliability. Material flaws in pressurant and propellant tanks were noted to have a significant effect on tank cycle life. Finally, maintenance considerations dictated a modularized systems approach, allowing the system to be removed from the vehicle for service and repair at a remote site.

  19. Data report. The fate of human enteric viruses in a natural sewage recycling system

    SciTech Connect

    Vaughn, J.M.; Landry, E.F.

    1980-09-01

    A two-year study was conducted to determine the virus-removing capacity of two man-made ecosystems designed for the treatment of raw domestic wastewater. The first treatment system consisted of two meadows followed by a marsh-pond unit (M/M/P). The second system contained individual marsh and pond units (M/P). All systems demonstrated moderate virus removal, with the marsh/pond system yielding the most consistent removal rates. Within this system, the greater potential for virus removal appeared to occur in the marsh unit. In addition to the production of system-oriented data, improved techniques for the concentration and enumeration of human viruses from sewage-polluted aquatic systems were developed.

  20. Green Science: Revisiting Recycling

    ERIC Educational Resources Information Center

    Palliser, Janna

    2011-01-01

    Recycling has been around for a long time--people have reused materials and refashioned them into needed items for thousands of years. More recently, war efforts encouraged conservation and reuse of materials, and in the 1970s recycling got its official start when recycling centers were created. Now, curbside recycling programs and recycling…

  1. Solvent cleaning system and method for removing contaminants from solvent used in resin recycling

    DOEpatents

    Bohnert, George W.; Hand, Thomas E.; DeLaurentiis, Gary M.

    2009-01-06

    A two step solvent and carbon dioxide based system that produces essentially contaminant-free synthetic resin material and which further includes a solvent cleaning system for periodically removing the contaminants from the solvent so that the solvent can be reused and the contaminants can be collected and safely discarded in an environmentally safe manner.

  2. Atmosphere stabilization and element recycle in an experimental mouse-algal system

    NASA Technical Reports Server (NTRS)

    Smernoff, David T.

    1986-01-01

    Life support systems based on bioregeneration rely on the control and manipulation of organisms. Experiments conducted with a gas-closed mouse-algal system designed to investigate principles of photosynthetic gas exchange focus primarily on observing gas exchange phenomena under varying algal environmental conditions and secondarily on studying element cycling through compartments of the experimental system. Inherent instabilities exit between the uptake and release of carbon dioxide CO2 and oxygen O2 by the mouse and algae. Variations in light intensity and cell density alter the photosynthetic rate of the algae and enable maintenance of physiologic concentrations of CO2 and O2. Different nitrogen sources (urea and nitrate) result in different algal assimilatory quotients (AQ). Combinations of photosynthetic rate and AQ ratio manipulations have been examined for their potential in stabilizing atmospheric gas concentrations in the gas-closed algal-mouse system. Elemental mass balances through the experimental systems compartments are being studied with the concurrent development of a mathematical simulation model. Element cycling experiments include quantification of elemental flows through system compartments and wet oxidation of system waste materials for use as an algal nutrient source. Oxidized waste products demonstrate inhibitory properties although dilution has been shown to allow normal growth.

  3. Volatiles and subduction-recycled lithologies in the petrogenesis of Cenozoic alkaline magmatism in the West Antarctic Rift System

    NASA Astrophysics Data System (ADS)

    Aviado, K.; Rilling-Hall, S.; Mukasa, S. B.; Bryce, J. G.; Fahnestock, M. F.

    2015-12-01

    In the West Antarctic Rift System (WARS), the failure of both passive and active models of decompression melting to explain unusually voluminous Cenozoic volcanism has prompted debate about the roles of thermal plume-related melting and ancient subduction-related flux melting. The latter is supported by ~500 Ma of subduction along the paleo-Pacific margin of Gondwana[1], a process capable of generating easily fusible, volatile-rich lithologies and producing the broad seismic low-velocity anomaly imaged beneath the Southern Ocean[2]. We present new geochemical information from submarine lavas in the Ross Sea and subaerial lavas from Franklin Island, Beaufort Island, and Mt. Melbourne in Northern Victoria Land (NVL) supportive of an evolving fluxed mantle source. Lavas exhibit ocean island basalt (OIB)-like trace element signatures and isotopic affinities for the C/FOZO mantle endmember consistent with subduction processing of recycled ocean lithosphere. Lava major-oxide compositions suggest multiple recycled source components, including pyroxenite (associated with older lavas), amphibole-rich metasomes, and volatilized peridotite (associated with the youngest lavas). In-situ analyses of olivine-hosted melt inclusions (MIs) from a subset of host lavas confirm high H2O and CO2 ranging up to 2.94 wt % and 4657 ppm, respectively. MIs exhibit OIB-like trace element compositions and Ba/Rb and Rb/Sr consistent with melting in the presence of hydrated, amphibole-bearing lithosphere[3,4]. We interpret these observations as evidence that ongoing tectonomagmatic activity in the WARS is facilitated by melting of subduction-modified mantle generated by 550 - 100 Ma Gondwana subduction. Following radiogenic ingrowth in high-µ (U/Pb) domains, Cenozoic extension triggered decompression melting of easily fusible, hydrated metasomes and volatilized mantle. This multistage magma model attempts to reconcile geochemical observations with increasing geophysical evidence that the seismic

  4. Recycle Waste Collection Tank (RWCT) simulant testing in the PVTD feed preparation system

    SciTech Connect

    Abrigo, G.P.; Daume, J.T.; Halstead, S.D.; Myers, R.L.; Beckette, M.R.; Freeman, C.J.; Hatchell, B.K.

    1996-03-01

    (This is part of the radwaste vitrification program at Hanford.) RWCT was to routinely receive final canister decontamination sand blast frit and rinse water, Decontamination Waste Treatment Tank bottoms, and melter off-gas Submerged Bed Scrubber filter cake. In order to address the design needs of the RWCT system to meet performance levels, the PNL Vitrification Technology (PVTD) program used the Feed Preparation Test System (FPTS) to evaluate its equipment and performance for a simulant of RWCT slurry. (FPTS is an adaptation of the Defense Waste Processing Facility feed preparation system and represents the initially proposed Hanford Waste Vitrification Plant feed preparation system designed by Fluor-Daniel, Inc.) The following were determined: mixing performance, pump priming, pump performance, simulant flow characterization, evaporator and condenser performance, and ammonia dispersion. The RWCT test had two runs, one with and one without tank baffles.

  5. Advanced Petroleum-Based Fuels - Diesel Emissions Project (APBF-DEC): 2,000-Hour Performance of a NOx Adsorber Catalyst and Diesel Particle Filter System for a Medium-Duty, Pick-Up Diesel Engine Platform; Final Report

    SciTech Connect

    Not Available

    2007-03-01

    Presents the results of a 2,000-hour test of an emissions control system consisting of a nitrogen oxides adsorber catalyst in combination with a diesel particle filter, advanced fuels, and advanced engine controls in an SUV/pick-up truck vehicle platform.

  6. Observations on gas exchange and element recycle within a gas-closed algal-mouse system

    NASA Technical Reports Server (NTRS)

    Smernoff, D. T.; Wharton, R. A., Jr.; Averner, M. M.

    1986-01-01

    Life support systems based on bioregeneration rely on the control and manipulation of organisms. Algae are potentially useful for a variety of Closed Ecological Life Support System (CELSS) functions including the revitalization of atmospheres, production of food and for nitrogen fixation. The results of experiments conducted with a gas-closed algal-mouse system designed to investigate gas exchange phenomena under varying algal environmental conditions, and the ability of algae to utilize oxidized mouse solid waste are reported. Inherent instabilities exist between the uptake and release of carbon dioxide (CO2) and oxygen (O2) by the mouse and algae in a gas-closed system. Variations in light intensity and cell density alter the photosynthetic rate of the algae and enable short-term steady-state concentrations of atmospheric CO2 and O2. Different nitrogen sources (urea and nitrate) result in different algal assimilatory quotients (AQ). Combinations of photosynthetic rate and AQ ratio manipulations were examined for their potential in stabilizing atmospheric gas concentrations in the gas-closed algal-mouse system.

  7. Assessment of polycarbonate filter in a molecular analytical system for the microbiological quality monitoring of recycled waters onboard ISS.

    PubMed

    Bechy-Loizeau, Anne-Laure; Flandrois, Jean-Pierre; Abaibou, Hafid

    2015-07-01

    On the ISS, as on Earth, water is an essential element for life and its quality control on a regular basis allows to ensure the health of the crew and the integrity of equipment. Currently, microbial water analysis onboard ISS still relies on the traditional culture-based microbiology methods. Molecular methods based on the amplification of nucleic acids for microbiological analysis of water quality show enormous potential and are considered as the best alternative to culture-based methods. For this reason, the Midass, a fully integrated and automated prototype was designed conjointly by ESA and bioMérieux for a rapid monitoring of the microbiological quality of air. The prototype allows air sampling, sample processing and the amplification/detection of nucleic acids. We describe herein the proof of principle of an analytical approach based on molecular biology that could fulfill the ESA's need for a rapid monitoring of the microbiological quality of recycled water onboard ISS. Both concentration and recovery of microorganisms are the main critical steps when the microfiltration technology is used for water analysis. Among filters recommended standards for monitoring the microbiological quality of the water, the polycarbonate filter was fully in line with the requirements of the ISO 7704-1985 standard in terms of efficacy of capture and recovery of bacteria. Moreover, this filter does not retain nucleic acids on the surface and has no inhibitory effect on their downstream processing steps such as purification and amplification/detection. Although the Midass system was designed for the treatment of air samples, the first results on the integration of PC filters were encouraging. Nevertheless, system modifications are needed to better adapt the Midass system for the monitoring of the microbiological water quality. PMID:26256625

  8. Assessment of polycarbonate filter in a molecular analytical system for the microbiological quality monitoring of recycled waters onboard ISS

    NASA Astrophysics Data System (ADS)

    Bechy-Loizeau, Anne-Laure; Flandrois, Jean-Pierre; Abaibou, Hafid

    2015-07-01

    On the ISS, as on Earth, water is an essential element for life and its quality control on a regular basis allows to ensure the health of the crew and the integrity of equipment. Currently, microbial water analysis onboard ISS still relies on the traditional culture-based microbiology methods. Molecular methods based on the amplification of nucleic acids for microbiological analysis of water quality show enormous potential and are considered as the best alternative to culture-based methods. For this reason, the Midass, a fully integrated and automated prototype was designed conjointly by ESA and bioMérieux for a rapid monitoring of the microbiological quality of air. The prototype allows air sampling, sample processing and the amplification/detection of nucleic acids. We describe herein the proof of principle of an analytical approach based on molecular biology that could fulfill the ESA's need for a rapid monitoring of the microbiological quality of recycled water onboard ISS. Both concentration and recovery of microorganisms are the main critical steps when the microfiltration technology is used for water analysis. Among filters recommended standards for monitoring the microbiological quality of the water, the polycarbonate filter was fully in line with the requirements of the ISO 7704-1985 standard in terms of efficacy of capture and recovery of bacteria. Moreover, this filter does not retain nucleic acids on the surface and has no inhibitory effect on their downstream processing steps such as purification and amplification/detection. Although the Midass system was designed for the treatment of air samples, the first results on the integration of PC filters were encouraging. Nevertheless, system modifications are needed to better adapt the Midass system for the monitoring of the microbiological water quality.

  9. Evaluation of regional bioenergy recovery by local methane fermentation thermal recycling systems.

    PubMed

    Wong, Looi-Fang; Fujita, Tsuyoshi; Xu, Kaiqin

    2008-11-01

    This paper evaluates the potential for regional bioenergy recovery as electricity and heat by small-scale methane fermentation systems from organic waste matter generated from urban, industrial, and agricultural sectors. Biogas production functions of high-strength organic wastes are derived from data of implemented methane fermentation systems. The distributions of organic wastes from sewage, household, wholesale/retail, manufacturing, farming, and livestock activities in the Tokyo Bay region are calibrated into a disaggregated spatial database by compiling general activity statistics and emission intensity parameters using Geographic Information System (GIS). Three scenarios of organic matter circulation by co-digestion in sewage treatment plants (STPs) are designed and assessed. Surplus electricity and heat from methane fermentation systems are used for STP operations and household demand. The spatial database allows a preliminary examination for the suitability of locations for technology implementation from the aspects of bioenergy supply and balance. The results show that an additional 368,000-1,328,000 MW of electricity would be generated, and 1300-3600 TJ of heat could be used by households, reducing the annual emissions of CO2 from fossil fuels by 307,000-798,000 t. PMID:18166448

  10. DESIGN AND APPLICATION OF A SPRAY RINSING SYSTEM FOR RECYCLE OF PROCESS WATERS

    EPA Science Inventory

    This research demonstrates the effectiveness of an innovative application of a multiple spray rinsing system in an electroplating process. A joint study was conducted by NCR and the U.S. EPA at NCR's printed circuit board facility in Cambridge, Ohio. Engineering evaluations were ...

  11. Mineral separation and recycle in a Controlled Ecological Life Support System (CELSS)

    NASA Technical Reports Server (NTRS)

    Ballou, E. V.

    1982-01-01

    The background of the mineral nutrition needs of plants are examined along with the applicability of mineral control and separation to a controlled ecological life support system (CELSS). Steps that may be taken in a program to analytically define and experimentally test key mineral control concepts in the nutritional and waste processing loops of a CELSS are delineated.

  12. Recycler barrier RF buckets

    SciTech Connect

    Bhat, C.M.; /Fermilab

    2011-03-01

    The Recycler Ring at Fermilab uses a barrier rf systems for all of its rf manipulations. In this paper, I will give an overview of historical perspective on barrier rf system, the longitudinal beam dynamics issues, aspects of rf linearization to produce long flat bunches and methods used for emittance measurements of the beam in the RR barrier rf buckets. Current rf manipulation schemes used for antiproton beam stacking and longitudinal momentum mining of the RR beam for the Tevatron collider operation are explained along with their importance in spectacular success of the Tevatron luminosity performance.

  13. Recycled Art: Create Puppets Using Recycled Objects.

    ERIC Educational Resources Information Center

    Clearing, 2003

    2003-01-01

    Presents an activity from "Healthy Foods from Healthy Soils" for making puppets using recycled food packaging materials. Includes background information, materials, instructions, literature links, resources, and benchmarks. (NB)

  14. Recycle Used Oil on America Recycles Day.

    ERIC Educational Resources Information Center

    White, Boyd W.

    2000-01-01

    Explains that motor oils can be reused and recycled. Educates students about environmental hazards and oil management and includes classroom activities. Addresses the National Science Education Standards. (YDS)

  15. A plant culture system for producing food and recycling materials with sweetpotato in space

    NASA Astrophysics Data System (ADS)

    Kitaya, Yoshiaki; Yano, Sachiko; Hirai, Hiroaki

    2016-07-01

    The long term human life support in space is greatly dependent on the amounts of food, atmospheric O2 and clean water produced by plants. Therefore, the bio-regenerative life support system such as space farming with scheduling of crop production, obtaining high yields with a rapid turnover rate, converting atmospheric CO2 to O2 and purifying water should be established with employing suitable plant species and varieties and precisely controlling environmental variables around plants grown at a high density in a limited space. We are developing a sweetpotato culture system for producing tuberous roots as a high-calorie food and fresh edible leaves and stems as a nutritive functional vegetable food in space. In this study, we investigated the ability of food production, CO2 to O2 conversion through photosynthesis, and clean water production through transpiration in the sweetpotato production system. The biomass of edible parts in the whole plant was almost 100%. The proportion of the top (leaves and stems) and tuberous roots was strongly affected by environmental variables even when the total biomass production was mostly the same. The production of biomass and clean water was controllable especially by light, atmospheric CO2 and moisture and gas regimes in the root zone. It was confirmed that sweetpotato can be utilized for the vegetable crop as well as the root crop allowing a little waste and is a promising functional crop for supporting long-duration human activity in space.

  16. Ab initio study of Ga-GaN system: Transition from adsorbed metal atoms to a metal–semiconductor junction

    SciTech Connect

    Witczak, Przemysław; Kempisty, Pawel; Strak, Pawel

    2015-11-15

    Ab initio studies of a GaN(0001)-Ga system with various thicknesses of a metallic Ga layer were undertaken. The studied systems extend from a GaN(0001) surface with a fractional coverage of gallium atoms to a Ga-GaN metal–semiconductor (m–s) contact. Electronic properties of the system are simulated using density functional theory calculations for different doping of the bulk semiconductor. It is shown that during transition from a bare GaN(0001) surface to a m–s heterostructure, the Fermi level stays pinned at a Ga-broken bond highly dispersive surface state to Ga–Ga states at the m–s interface. Adsorption of gallium leads to an energy gain of about 4 eV for a clean GaN(0001) surface and the energy decreases to 3.2 eV for a thickly Ga-covered surface. The transition to the m–s interface is observed. For a thick Ga overlayer such interface corresponds to a Schottky contact with a barrier equal to 0.9 and 0.6 eV for n- and p-type, respectively. Bond polarization-related dipole layer occurring due to an electron transfer to the metal leads to a potential energy jump of 1.5 eV, independent on the semiconductor doping. Additionally high electron density in the Ga–Ga bond region leads to an energy barrier about 1.2 eV high and 4 Å wide. This feature may adversely affect the conductivity of the n-type m–s system.

  17. Response of graywater recycling systems based on hydroponic plant growth to three classes of surfactants

    NASA Technical Reports Server (NTRS)

    Garland, J. L.; Levine, L. H.; Yorio, N. C.; Hummerick, M. E.

    2004-01-01

    Anionic (sodium laureth sulfate, SLES), amphoteric (cocamidopropyl betaine, CAPB) and nonionic (alcohol polyethoxylate, AE) surfactants were added to separate nutrient film technique (NFT) hydroponic systems containing dwarf wheat (Triticum aestivum cv. USU Apogee) in a series of 21 day trials. Surfactant was added either in a (1). temporally dynamic mode (1-3 g surfactant m(-2) growing area d(-1)) as effected by automatic addition of a 300 ppm surfactant solution to meet plant water demand, or (2). continuous mode (2 g surfactant m(-2) growing area d(-1)) as effected by slow addition (10 mLh(-1)) of a 2000 ppm surfactant solution beginning at 4d after planting. SLES showed rapid primary degradation in both experiments, with no accumulation 24 h after initial addition. CAPB and AE were degraded less rapidly, with 30-50% remaining 24 h after initial addition, but CAPB and AE levels were below detection limit for the remainder of the study. No reductions in vegetative growth of wheat were observed in response to SLES, but biomass was reduced 20-25% with CAPB and AE. Microbial communities associated with both the plant roots and wetted hardware surfaces actively degraded the surfactants, as determined by monitoring surfactant levels following pulse additions at day 20 (with plants) and day 21 (after plant removal). In order to test whether the biofilm communities could ameliorate phytotoxicity by providing a microbial community acclimated for CAPB and AE decay, the continuous exposure systems were planted with wheat seeds after crop removal at day 21. Acclimation resulted in faster primary degradation (>90% within 24h) and reduced phytotoxicity. Overall, the studies indicate that relatively small areas (3-5m(2)) of hydroponic plant systems can process per capita production of mixed surfactants (5-10 g x person(-1)d(-1)) with minimal effects on plant growth.

  18. Response of graywater recycling systems based on hydroponic plant growth to three classes of surfactants.

    PubMed

    Garland, J L; Levine, L H; Yorio, N C; Hummerick, M E

    2004-04-01

    Anionic (sodium laureth sulfate, SLES), amphoteric (cocamidopropyl betaine, CAPB) and nonionic (alcohol polyethoxylate, AE) surfactants were added to separate nutrient film technique (NFT) hydroponic systems containing dwarf wheat (Triticum aestivum cv. USU Apogee) in a series of 21 day trials. Surfactant was added either in a (1). temporally dynamic mode (1-3 g surfactant m(-2) growing area d(-1)) as effected by automatic addition of a 300 ppm surfactant solution to meet plant water demand, or (2). continuous mode (2 g surfactant m(-2) growing area d(-1)) as effected by slow addition (10 mLh(-1)) of a 2000 ppm surfactant solution beginning at 4d after planting. SLES showed rapid primary degradation in both experiments, with no accumulation 24 h after initial addition. CAPB and AE were degraded less rapidly, with 30-50% remaining 24 h after initial addition, but CAPB and AE levels were below detection limit for the remainder of the study. No reductions in vegetative growth of wheat were observed in response to SLES, but biomass was reduced 20-25% with CAPB and AE. Microbial communities associated with both the plant roots and wetted hardware surfaces actively degraded the surfactants, as determined by monitoring surfactant levels following pulse additions at day 20 (with plants) and day 21 (after plant removal). In order to test whether the biofilm communities could ameliorate phytotoxicity by providing a microbial community acclimated for CAPB and AE decay, the continuous exposure systems were planted with wheat seeds after crop removal at day 21. Acclimation resulted in faster primary degradation (>90% within 24h) and reduced phytotoxicity. Overall, the studies indicate that relatively small areas (3-5m(2)) of hydroponic plant systems can process per capita production of mixed surfactants (5-10 g x person(-1)d(-1)) with minimal effects on plant growth. PMID:15087176

  19. Stress Corrosion Evaluation of Various Metallic Materials for the International Space Station Water Recycling System

    NASA Technical Reports Server (NTRS)

    Torres, P. D.

    2015-01-01

    A stress corrosion evaluation was performed on Inconel 625, Hastelloy C276, titanium commercially pure (TiCP), Ti-6Al-4V, Ti-6Al-4V extra low interstitial, and Cronidur 30 steel as a consequence of a change in formulation of the pretreatment for processing the urine in the International Space Station Environmental Control and Life Support System Urine Processing Assembly from a sulfuric acid-based to a phosphoric acid-based solution. The first five listed were found resistant to stress corrosion in the pretreatment and brine. However, some of the Cronidur 30 specimens experienced reduction in load-carrying ability.

  20. Environmental monitoring of selected pesticides and organic chemicals in urban stormwater recycling systems using passive sampling techniques

    NASA Astrophysics Data System (ADS)

    Page, Declan; Miotliński, Konrad; Gonzalez, Dennis; Barry, Karen; Dillon, Peter; Gallen, Christie

    2014-03-01

    Water recycling via aquifers has become a valuable tool to augment urban water supplies in many countries. This study reports the first use of passive samplers for monitoring of organic micropollutants in Managed Aquifer Recharge (MAR). Five different configurations of passive samplers were deployed in a stormwater treatment wetland, groundwater monitoring wells and a recovery tank to capture a range of polar and non-polar micropollutants present in the system. The passive samplers were analysed for a suite of pesticides, polycyclic aromatic hydrocarbons (PAHs) and other chemicals. As a result, 17 pesticides and pesticide degradation products, 5 PAHs and 8 other organic chemicals including flame retardants and fragrances were detected in urban stormwater recharging Aquifer Storage and Recovery (ASR) and an Aquifer Storage Transfer and Recovery (ASTR) system. Of the pesticides detected, diuron, metolachlor and chlorpyrifos were generally detected at the highest concentrations in one or more passive samplers, whereas chlorpyrifos, diuron, metolachlor, simazine, galaxolide and triallate were detected in multiple samplers. Fluorene was the PAH detected at the highest concentration and the flame retardant Tris(1-chloro-2-propyl)phosphate was the chemical detected in the greatest abundance at all sites. The passive samplers showed different efficiencies for capture of micropollutants with the Empore disc samplers giving the most reliable results. The results indicate generally low levels of organic micropollutants in the stormwater, as the contaminants detected were present at very low ng/L levels, generally two to four orders of magnitude below the drinking water guidelines (NHMRC, 2011). The efficiency of attenuation of these organic micropollutants during MAR was difficult to determine due to variations in the source water concentrations. Comparisons were made between different samplers, to give a field-based calibration where existing lab-based calibrations were

  1. Environmental monitoring of selected pesticides and organic chemicals in urban stormwater recycling systems using passive sampling techniques.

    PubMed

    Page, Declan; Miotliński, Konrad; Gonzalez, Dennis; Barry, Karen; Dillon, Peter; Gallen, Christie

    2014-03-01

    Water recycling via aquifers has become a valuable tool to augment urban water supplies in many countries. This study reports the first use of passive samplers for monitoring of organic micropollutants in Managed Aquifer Recharge (MAR). Five different configurations of passive samplers were deployed in a stormwater treatment wetland, groundwater monitoring wells and a recovery tank to capture a range of polar and non-polar micropollutants present in the system. The passive samplers were analysed for a suite of pesticides, polycyclic aromatic hydrocarbons (PAHs) and other chemicals. As a result, 17 pesticides and pesticide degradation products, 5 PAHs and 8 other organic chemicals including flame retardants and fragrances were detected in urban stormwater recharging Aquifer Storage and Recovery (ASR) and an Aquifer Storage Transfer and Recovery (ASTR) system. Of the pesticides detected, diuron, metolachlor and chlorpyrifos were generally detected at the highest concentrations in one or more passive samplers, whereas chlorpyrifos, diuron, metolachlor, simazine, galaxolide and triallate were detected in multiple samplers. Fluorene was the PAH detected at the highest concentration and the flame retardant Tris(1-chloro-2-propyl)phosphate was the chemical detected in the greatest abundance at all sites. The passive samplers showed different efficiencies for capture of micropollutants with the Empore disc samplers giving the most reliable results. The results indicate generally low levels of organic micropollutants in the stormwater, as the contaminants detected were present at very low ng/L levels, generally two to four orders of magnitude below the drinking water guidelines (NHMRC, 2011). The efficiency of attenuation of these organic micropollutants during MAR was difficult to determine due to variations in the source water concentrations. Comparisons were made between different samplers, to give a field-based calibration where existing lab-based calibrations were

  2. Catalyst recycling via specific non-covalent adsorption on modified silicas.

    PubMed

    Kluwer, Alexander M; Simons, Chretien; Knijnenburg, Quinten; van der Vlugt, Jarl Ivar; de Bruin, Bas; Reek, Joost N H

    2013-03-14

    This article describes a new strategy for the recycling of a homogeneous hydroformylation catalyst, by selective adsorption of the catalyst to tailor-made supports after a batchwise reaction. The separation of the catalyst from the product mixture is based on selective non-covalent supramolecular interactions between a ligand and the support. Changing the solvent releases the active catalyst back into the reactor and allows a subsequent batch reaction with the recycled active catalyst. For this purpose, the bidentate NixantPhos ligand has been equipped with a pyridine group. The corresponding rhodium pre-catalyst [Rh(Nix-py)(acac)] (acac = acetylacetonate) forms a very selective, active and highly stable catalyst, and able to reach a turnover number (TON) of 170 000 in a single run (reaction performed in nearly neat 1-octene, S/C ratio of 200 000, at 140 °C, 20 bars syngas pressure). Various commercially available supports have been explored in binding studies and recycling experiments. The end-capped silica-alumina performs the best so far with respect to ligand-adsorbing properties for the current purpose. Although this system has not been fully optimized, four recycling runs could be performed successfully. PMID:23292126

  3. Expansion Hamiltonian model for a diatomic molecule adsorbed on a surface: Vibrational states of the CO/Cu(100) system including surface vibrations

    NASA Astrophysics Data System (ADS)

    Meng, Qingyong; Meyer, Hans-Dieter

    2015-10-01

    Molecular-surface studies are often done by assuming a corrugated, static (i.e., rigid) surface. To be able to investigate the effects that vibrations of surface atoms may have on spectra and cross sections, an expansion Hamiltonian model is proposed on the basis of the recently reported [R. Marquardt et al., J. Chem. Phys. 132, 074108 (2010)] SAP potential energy surface (PES), which was built for the CO/Cu(100) system with a rigid surface. In contrast to other molecule-surface coupling models, such as the modified surface oscillator model, the coupling between the adsorbed molecule and the surface atoms is already included in the present expansion SAP-PES model, in which a Taylor expansion around the equilibrium positions of the surface atoms is performed. To test the quality of the Taylor expansion, a direct model, that is avoiding the expansion, is also studied. The latter, however, requests that there is only one movable surface atom included. On the basis of the present expansion and direct models, the effects of a moving top copper atom (the one to which CO is bound) on the energy levels of a bound CO/Cu(100) system are studied. For this purpose, the multiconfiguration time-dependent Hartree calculations are carried out to obtain the vibrational fundamentals and overtones of the CO/Cu(100) system including a movable top copper atom. In order to interpret the results, a simple model consisting of two coupled harmonic oscillators is introduced. From these calculations, the vibrational levels of the CO/Cu(100) system as function of the frequency of the top copper atom are discussed.

  4. Expansion Hamiltonian model for a diatomic molecule adsorbed on a surface: Vibrational states of the CO/Cu(100) system including surface vibrations

    SciTech Connect

    Meng, Qingyong; Meyer, Hans-Dieter

    2015-10-28

    Molecular-surface studies are often done by assuming a corrugated, static (i.e., rigid) surface. To be able to investigate the effects that vibrations of surface atoms may have on spectra and cross sections, an expansion Hamiltonian model is proposed on the basis of the recently reported [R. Marquardt et al., J. Chem. Phys. 132, 074108 (2010)] SAP potential energy surface (PES), which was built for the CO/Cu(100) system with a rigid surface. In contrast to other molecule-surface coupling models, such as the modified surface oscillator model, the coupling between the adsorbed molecule and the surface atoms is already included in the present expansion SAP-PES model, in which a Taylor expansion around the equilibrium positions of the surface atoms is performed. To test the quality of the Taylor expansion, a direct model, that is avoiding the expansion, is also studied. The latter, however, requests that there is only one movable surface atom included. On the basis of the present expansion and direct models, the effects of a moving top copper atom (the one to which CO is bound) on the energy levels of a bound CO/Cu(100) system are studied. For this purpose, the multiconfiguration time-dependent Hartree calculations are carried out to obtain the vibrational fundamentals and overtones of the CO/Cu(100) system including a movable top copper atom. In order to interpret the results, a simple model consisting of two coupled harmonic oscillators is introduced. From these calculations, the vibrational levels of the CO/Cu(100) system as function of the frequency of the top copper atom are discussed.

  5. Black Molecular Adsorber Coatings for Spaceflight Applications

    NASA Technical Reports Server (NTRS)

    Abraham, Nithin Susan; Hasegawa, Mark Makoto; Straka, Sharon A.

    2014-01-01

    The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

  6. Cerebral blood flow velocity increases during a single treatment with the molecular adsorbents recirculating system in patients with acute on chronic liver failure.

    PubMed

    Schmidt, L E; Svendsen, L B; Sørensen, V R; Hansen, B A; Larsen, F S

    2001-08-01

    The aim of this uncontrolled pilot study is to determine the effect of treatment with the molecular adsorbents recirculating system (MARS) on cerebral perfusion in patients with acute on chronic liver failure (AOCLF). In 8 patients (median age, 44 years; range, 35 to 52 years) admitted with AOCLF, a single 10-hour MARS treatment was performed. Hepatic encephalopathy (HE) was graded according to the Fogarty criteria. Changes in cerebral perfusion were determined by transcranial Doppler as mean flow velocity (V(mean)) in the middle cerebral artery. Arterial ammonia and bilirubin levels were monitored as a measure of the capability of the MARS to remove water-soluble and protein-bound toxins. During MARS treatment, HE grade improved in 3 patients and remained unchanged in 5 patients (P =.11). V(mean) increased from 42 cm/sec (range, 26 to 59 cm/sec) to 72 cm/sec (range, 52 to 106 cm/sec; P <.05), whereas arterial ammonia level decreased from 88 micromol/L (range, 45 to 117 micromol/L) to 71 micromol/L (range, 26 to 98 micromol/L; P <.05) and bilirubin level from 537 micromol/L (range, 324 to 877 micromol/L) to 351 micromol/L (range, 228 to 512 micromol/L; P <.05). In conclusion, cerebral perfusion is increased and levels of ammonia and bilirubin are reduced during MARS treatment in patients with AOCLF. PMID:11510016

  7. Phosphorus depletion in forest soils shapes bacterial communities towards phosphorus recycling systems.

    PubMed

    Bergkemper, Fabian; Schöler, Anne; Engel, Marion; Lang, Friederike; Krüger, Jaane; Schloter, Michael; Schulz, Stefanie

    2016-06-01

    Phosphorus (P) is an important macronutrient for all biota on earth but similarly a finite resource. Microorganisms play on both sides of the fence as they effectively mineralize organic and solubilize precipitated forms of soil phosphorus but conversely also take up and immobilize P. Therefore, we analysed the role of microbes in two beech forest soils with high and low P content by direct sequencing of metagenomic deoxyribonucleic acid. For inorganic P solubilization, a significantly higher microbial potential was detected in the P-rich soil. This trait especially referred to Candidatus Solibacter usiatus, likewise one of the dominating species in the data sets. A higher microbial potential for efficient phosphate uptake systems (pstSCAB) was detected in the P-depleted soil. Genes involved in P starvation response regulation (phoB, phoR) were prevalent in both soils. This underlines the importance of effective phosphate (Pho) regulon control for microorganisms to use alternative P sources during phosphate limitation. Predicted genes were primarily harboured by Rhizobiales, Actinomycetales and Acidobacteriales. PMID:26690731

  8. Separation of Rebaudiana A from Steviol glycoside using a polymeric adsorbent with multi-hydrogen bonding in a non-aqueous system.

    PubMed

    Ba, Jing; Zhang, Na; Yao, Lijuan; Ma, Ning; Wang, Chunhong

    2014-11-15

    Rebaudioside A (RA) and stevioside (SS) are the primary effective glycoside components in Stevia Rebaudiana. The RA glycoside is sweeter, and it tastes similarly to sucrose. Because extracts with a high RA content can be used as natural sweeteners for food additives approved by the FAO and FDA, RA should generate high market demand. In this study, an efficient method for separating RA was established based on the synergistic multi-hydrogen bonding interaction between a polymeric adsorbent and the RA glycoside. To overcome the destruction of the hydrophobic affinity required for the selective adsorption of RA, an innovative non-aqueous environment was established for adsorption and separation. To this end, an initial polymeric adsorbent composed of a glycidyl methacrylate and trimethylolpropane trimethacrylate (GMA-co-TMPTMA) copolymer matrix was synthesized, and polyethylene polyamine was employed as a functional reagent designed to react with the epoxy group on GME-co-TMPTMA to form a highly selective macroporous adsorbent. The effects of the different functional reagents and the solvent polarity on the adsorption selectivity for RA and SS, respectively, were investigated. Matching the structure of the polyethylene polyamine and sugar ligand on the glycoside molecule was essential in ensuring that the maximum synergistic interaction between adsorbent and adsorbate would be achieved. Moreover, the hydrogen-bonding force was observed to increase when the polarity of the adsorption solvent decreased. Therefore, among the synthesized macroporous polymeric adsorbents, the GTN4 adsorbent-bonding tetraethylenepentamine functional group provided the best separation in an n-butyl alcohol solution. Under the optimized gradient elution conditions, RA and SS can be effectively separated, and the contents of RA and SS increased from 33.5% and 51.5% in the initial crude extract to 95.4% and 78.2% after separation, respectively. Compared to conventional methods, the adsorption

  9. Pathways and mechanisms of endocytic recycling

    PubMed Central

    Grant, Barth D.; Donaldson, Julie G.

    2011-01-01

    Endocytic recycling is coordinated with endocytic uptake to control the composition of the plasma membrane. Although much of our understanding of endocytic recycling has come from studies on the transferrin receptor, a protein internalized through clathrin-dependent endocytosis, increased interest in clathrin-independent endocytosis has led to the discovery of new endocytic recycling systems. Recent insights into the regulatory mechanisms that control endocytic recycling have focused on recycling through tubular carriers and the return to the cell surface of cargo that enters cells through clathrin-independent mechanisms. Recent work emphasizes the importance of regulated recycling in such diverse processes as cytokinesis, cell adhesion and morphogenesis, cell fusion, and learning and memory. PMID:19696797

  10. A dehydrogenase-mediated recycling system of NADPH in plant peroxisomes.

    PubMed Central

    Corpas, F J; Barroso, J B; Sandalio, L M; Distefano, S; Palma, J M; Lupiáñez, J A; Del Río, L A

    1998-01-01

    The presence of the two NADP-dependent dehydrogenases of the pentose phosphate pathway has been investigated in plant peroxisomes from pea (Pisum sativum L.) leaves. Both enzymes, glucose-6-phosphate dehydrogenase (G6PDH; EC 1.1.1.49) and 6-phosphogluconate dehydrogenase (6PGDH; EC 1.1.1.44), were present in the matrix of leaf peroxisomes, and their kinetic properties were studied. G6PDH and 6PGDH showed a typical Michaelis-Menten kinetic saturation curve, and had specific activities of 12.4 and 29.6 mU/mg protein, respectively. The Km values of G6PDH and 6PGDH for glucose 6-phosphate and for 6-phosphogluconate were 107.3 and 10.2 microM, respectively. Dithiothreitol did not inhibit G6PDH activity. By isoelectric focusing of peroxisomal matrices, the G6PDH activity was resolved into three isoforms with isoelectric points of 5.55, 5.30 and 4.85. The isoelectric point of peroxisomal 6PGDH was 5.10. Immunoblot analyses of peroxisomal matrix with an antibody against yeast G6PDH revealed a single cross-reactive band of 56 kDa. Post-embedment, EM immunogold labelling of G6PDH confirmed that this enzyme was localized in the peroxisomal matrices, the thylakoid membrane and matrix of chloroplasts, and the cytosol. The presence of the two oxidative enzymes of the pentose phosphate pathway in plant peroxisomes implies that these organelles have the capacity to reduce NADP+ to NADPH for its re-utilization in the peroxisomal metabolism. NADPH is particularly required for the ascorbate-glutathione cycle, which has been recently demonstrated in plant peroxisomes [Jiménez, Hernández, del Río and Sevilla (1997) Plant Physiol. 114, 275-284] and represents an important antioxidant protection system against H2O2 generated in peroxisomes. PMID:9480890

  11. Titanium-incorporated organic–inorganic hybrid adsorbent for improved CO{sub 2} adsorption performance

    SciTech Connect

    Zhang, Xiaoyun; Qin, Hongyan; Zhang, Sisi; Wu, Wei

    2015-02-15

    Highlights: • Titanium-incorporated organic–inorganic hybrid adsorbent was prepared. • The incorporation of Ti to the adsorbent showed significant effect. • The sorbent shows high CO{sub 2} capture capacity both in pure and diluted CO{sub 2} at RT. • The sorbent exhibits a high recycling stability after 15 cycling runs. - Abstract: The CO{sub 2} adsorption performance of acrylonitrile (AN)–tetraethylenepentamine (TEPA) adduct (hereafter referred to as TN) impregnated adsorbent was greatly enhanced by introduction of Titanium atom into the silica matrix. The adsorbents were characterized by X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), transmission electron microscopy (TEM), N{sub 2} adsorption/desorption, UV–vis spectroscopy, Fourier transform infrared (FTIR) spectroscopy. The adsorption experiments together with the physicochemical characterization demonstrated that these adsorbents containing an optimal amount of Titanium (Ti/Si ≈ 0.1) remarkably reinforced the CO{sub 2} adsorption capacity and recycling stability. The highest CO{sub 2} uptakes reached 4.65 and 1.80 mmol CO{sub 2}/g adsorbent at 25 °C under 90% CO{sub 2} (CO{sub 2}/N{sub 2}, 90:10 V/V) and 1% CO{sub 2} (CO{sub 2}/N{sub 2}, 1:99 V/V) conditions for sample Ti(0.1)-DMS-TN, respectively. Repeated adsorption/desorption cycles revealed that the Ti-incorporated adsorbent showed only a tiny decrease in adsorption capacity (1.778 mmol CO{sub 2}/g adsorbent after 15 cycles, decreased by 0.95%), significantly enhanced the adsorbent recycling stability.

  12. Fermilab recycler stochastic cooling commissioning and performance

    SciTech Connect

    D. Broemmelsiek; Ralph Pasquinelli

    2003-06-04

    The Fermilab Recycler is a fixed 8 GeV kinetic energy storage ring located in the Fermilab Main Injector tunnel near the ceiling. The Recycler has two roles in Run II. First, to store antiprotons from the Fermilab Antiproton Accumulator so that the antiproton production rate is no longer compromised by large numbers of antiprotons stored in the Accumulator. Second, to receive antiprotons from the Fermilab Tevatron at the end of luminosity periods. To perform each of these roles, stochastic cooling in the Recycler is needed to preserve and cool antiprotons in preparation for transfer to the Tevatron. The commissioning and performance of the Recycler stochastic cooling systems will be reviewed.

  13. Recycling overview in Sweden

    SciTech Connect

    Not Available

    1989-07-01

    This article discusses the recycling programs currently in use in Sweden. Recycling of newspapers, batteries, plastics are all mentioned in this report by the Swedish Association of Public Cleansing and Solid Waste Management.

  14. Recycling Research. Tracking Trash.

    ERIC Educational Resources Information Center

    DeLago, Louise Furia

    1991-01-01

    An activity in which students research the effectiveness of recycling is presented. Students compare the types and amount of litter both before and after recycling is implemented. Directions for the activity and a sample data sheet are included. (KR)

  15. Integrated system for temperature-controlled fast protein liquid chromatography. II. Optimized adsorbents and 'single column continuous operation'.

    PubMed

    Cao, Ping; Müller, Tobias K H; Ketterer, Benedikt; Ewert, Stephanie; Theodosiou, Eirini; Thomas, Owen R T; Franzreb, Matthias

    2015-07-17

    Continued advance of a new temperature-controlled chromatography system, comprising a column filled with thermoresponsive stationary phase and a travelling cooling zone reactor (TCZR), is described. Nine copolymer grafted thermoresponsive cation exchangers (thermoCEX) with different balances of thermoresponsive (N-isopropylacrylamide), hydrophobic (N-tert-butylacrylamide) and negatively charged (acrylic acid) units were fashioned from three cross-linked agarose media differing in particle size and pore dimensions. Marked differences in grafted copolymer composition on finished supports were sourced to base matrix hydrophobicity. In batch binding tests with lactoferrin, maximum binding capacity (qmax) increased strongly as a function of charge introduced, but became increasingly independent of temperature, as the ability of the tethered copolymer networks to switch between extended and collapsed states was lost. ThermoCEX formed from Sepharose CL-6B (A2), Superose 6 Prep Grade (B2) and Superose 12 Prep Grade (C1) under identical conditions displayed the best combination of thermoresponsiveness (qmax,50°C/qmax,10°C ratios of 3.3, 2.2 and 2.8 for supports 'A2', 'B2' and 'C1' respectively) and lactoferrin binding capacity (qmax,50°C∼56, 29 and 45mg/g for supports 'A2', 'B2' and 'C1' respectively), and were selected for TCZR chromatography. With the cooling zone in its parked position, thermoCEX filled columns were saturated with lactoferrin at a binding temperature of 35°C, washed with equilibration buffer, before initiating the first of 8 or 12 consecutive movements of the cooling zone along the column at 0.1mm/s. A reduction in particle diameter (A2→B2) enhanced lactoferrin desorption, while one in pore diameter (B2→C1) had the opposite effect. In subsequent TCZR experiments conducted with thermoCEX 'B2' columns continuously fed with lactoferrin or 'lactoferrin+bovine serum albumin' whilst simultaneously moving the cooling zone, lactoferrin was

  16. Recycling and the automobile

    SciTech Connect

    Holt, D.J.

    1993-10-01

    This article examines the current status of automobile recycling and contains a summary of a survey which points out the major drivers and their impacts on automotive recycling. The topics of the article include computerized dismantling, polyurethane, sheet molding compound, polyester, thermoplastic polyester, recycling salvaged parts, vinyl and automotive shredder residue.

  17. The Sustainability of Recycling.

    ERIC Educational Resources Information Center

    Juniper, Christopher

    1993-01-01

    Describes the need for closing the business cycle in the recycling process. Discusses whether the government should mandate or the free market create uses for recycled products. Presents challenges associated with marketing recycled materials including what has been and what needs to be done to stimulate markets, encourage business, and balance…

  18. Rethink, Rework, Recycle.

    ERIC Educational Resources Information Center

    Wrhen, Linda; DiSpezio, Michael A.

    1991-01-01

    Information about the recycling and reuse of plastics, aluminum, steel, glass, and newspapers is presented. The phases of recycling are described. An activity that allows students to separate recyclable materials is included. The objectives, a list of needed materials, and procedure are provided. (KR)

  19. RECYCLING OF WATER IN POULTRY PROCESSING PLANTS

    EPA Science Inventory

    Studies were conducted on recycling chiller water in a poultry processing plant. The recycling system must be provided with the capability of removing solids and controlling the microbial population. UV was used to control the microbial population. For this control to be effectiv...

  20. Recyclable heparin and chitosan conjugated magnetic nanocomposites for selective removal of low-density lipoprotein from plasma.

    PubMed

    Li, Jinghua; Hou, Yanhua; Chen, Xiuyong; Ding, Xingwei; Liu, Yun; Shen, Xinkun; Cai, Kaiyong

    2014-04-01

    A new fabrication protocol is described to obtain heparin and chitosan conjugated magnetic nanocomposite as a blood purification material for removal of low-density lipoprotein (LDL) from blood plasma. The adsorbent could be easily separated with an external magnet for recyclable use since it had a magnetic core. The LDL level of plasma decreased by 67.3 % after hemoperfusion for 2 h. Moreover, the adsorbent could be recycled simply washing with NaCl solution. After eight cycles, the removal efficiency of the adsorbent was still above 50 %. The recyclable magnetic adsorbent had good blood compatibility due to the conjugation of heparin to the chitosan-coated magnetic nanocomposites. The fabricated magnetic adsorbent could be applied for LDL apheresis without side effects. PMID:24394982

  1. A 3-year experience with Molecular Adsorbent Recirculating System (MARS): our results on 63 patients with hepatic failure and color Doppler US evaluation of cerebral perfusion.

    PubMed

    Novelli, Gilnardo; Rossi, Massimo; Pretagostini, Renzo; Novelli, Luigi; Poli, Luca; Ferretti, Giancarlo; Iappelli, Massimo; Berloco, Pasquale; Cortesini, Raffaello

    2003-01-01

    In our 3-year experience, we treated 63 patients with Molecular Adsorbent Recirculating System (MARS). The patients were divided as follows: 10 primary non-function (PNF) 16%, 10 delayed non-function (DNF) 16%, 16 Fulminant hepatitis (FH) 24%, 23 acute decompensation of chronic liver disease (ACLF) 38%, and 4 hepatic resection 6%. All patients who underwent MARS treatment had bilirubin >15 mg/dL, Glasgow Coma Score between 9 and 11, ammonium >160 microg/dL and non-coagulability. The determining factors taken into consideration for the continuation of MARS treatment were: an improvement in Glasgow Coma Score, and a decrease in ammonium and bilirubin. We also monitored hemodynamic parameters, acid-base equilibrium, and blood gas analysis before and after each treatment. In order to determine patients' neurological conditions, we not only took into account the Glasgow Coma Score, which does not give mathematically precise results but also took into account the fact that patients with hepatic coma had lower cerebral mean velocity in the cerebral arteries than patients without encephalopathy. For this reason, in the last 22 patients we monitored cerebral perfusion, determined by mean flow velocity (Vmean) in the middle cerebral artery. Our results were expressed as mean +/- SD and we analyzed the differences between mean values for each variable, before and after treatment by means of Student's t-test. At the end of treatment, we obtained significant P-values for bilirubin, ammonium, Glasgow Coma Score and creatinine. In 16/20 patients, we could demonstrate a clear correlation between the improvement in clinical conditions (especially neurological status) and improvement in cerebral perfusion, measured by color Doppler US. PMID:12950955

  2. Process to recycle shredder residue

    DOEpatents

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  3. Performance evaluation of a granular activated carbon-sequencing batch biofilm reactor pilot plant system used in treating real wastewater from recycled paper industry.

    PubMed

    Muhamad, Mohd Hafizuddin; Sheikh Abdullah, Siti Rozaimah; Mohamad, Abu Bakar; Rahman, Rakmi Abdul; Kadhum, Abdul Amir Hasan

    2012-01-01

    A pilot scale granular activated carbon-sequencing batch biofilm reactor with a capacity of 2.2 m3 was operated for over three months to evaluate its performance treating real recycled paper industry wastewater under different operational conditions. In this study, dissolved air floatation (DAF) and clarifier effluents were used as influent sources of the pilot plant. During the course of the study, the reactor was able to biodegrade the contaminants in the incoming recycled paper mill wastewater in terms of chemical oxygen demand (COD), adsorbable organic halides (AOX; specifically 2,4-dichlorophenol (2,4-DCP)) and ammoniacal nitrogen (NH3-N) removal efficiencies at varying hydraulic retention times (HRTs) of 1-3 days, aeration rates (ARs) of 2.1-3.4 m3/min and influent feed concentration of 40-950 mg COD/l. Percentages of COD, 2,4-DCP and NH3-N removals increased with increasing HRT, resulting in more than 90% COD, 2,4-DCP and NH3-N removals at HRT values above two days. Degradation of COD, 2,4-DCP and NH3-N were seriously affected by variation of ARs, which resulted in significant decrease of COD, 2,4-DCP and NH3-N removals by decreasing ARs from 3.4 m3/min to 2.1 m3/min, varying in the ranges of 24-80%, 6-96% and 5-42%, respectively. In comparison to the clarifier effluent, the treatment performance of DAF effluent, containing high COD concentration, resulted in a higher COD removal of 82%. The use of diluted DAF effluent did not improve significantly the COD removal. Higher NH3-N removal efficiency of almost 100% was observed during operation after maintenance shutdown compared to normal operation, even at the same HRT of one day due to the higher dissolved oxygen concentrations (1-7 mg/l), while no significant difference in COD removal efficiency was observed. PMID:22720416

  4. Recycled Water Poses Disinfectant Problem

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1973

    1973-01-01

    Discusses the possible health hazards resulting from released nucleic acid of inactivated viruses, chlorinated nonliving organic molecules, and overestimated reliability of waste treatment standards. Suggests the recycle system use a dual disinfectant such as chlorine and ozone in water treatment. (CC)

  5. An analytical framework and tool ('InteRa') for integrating the informal recycling sector in waste and resource management systems in developing countries.

    PubMed

    Velis, Costas A; Wilson, David C; Rocca, Ondina; Smith, Stephen R; Mavropoulos, Antonis; Cheeseman, Chris R

    2012-09-01

    In low- and middle-income developing countries, the informal (collection and) recycling sector (here abbreviated IRS) is an important, but often unrecognised, part of a city's solid waste and resources management system. Recent evidence shows recycling rates of 20-30% achieved by IRS systems, reducing collection and disposal costs. They play a vital role in the value chain by reprocessing waste into secondary raw materials, providing a livelihood to around 0.5% of urban populations. However, persisting factual and perceived problems are associated with IRS (waste-picking): occupational and public health and safety (H&S), child labour, uncontrolled pollution, untaxed activities, crime and political collusion. Increasingly, incorporating IRS as a legitimate stakeholder and functional part of solid waste management (SWM) is attempted, further building recycling rates in an affordable way while also addressing the negatives. Based on a literature review and a practitioner's workshop, here we develop a systematic framework--or typology--for classifying and analysing possible interventions to promote the integration of IRS in a city's SWM system. Three primary interfaces are identified: between the IRS and the SWM system, the materials and value chain, and society as a whole; underlain by a fourth, which is focused on organisation and empowerment. To maximise the potential for success, IRS integration/inclusion/formalisation initiatives should consider all four categories in a balanced way and pay increased attention to their interdependencies, which are central to success, including specific actions, such as the IRS having access to source separated waste. A novel rapid evaluation and visualisation tool is presented--integration radar (diagram) or InterRa--aimed at illustrating the degree to which a planned or existing intervention considers each of the four categories. The tool is further demonstrated by application to 10 cases around the world, including a step

  6. CO2 Sequestration and Recycle by Photosynthesis

    SciTech Connect

    Steven S.C. Chuang

    2004-02-01

    Visible light-photocatalysis could provide a cost-effective route to recycle CO2 to useful chemicals or fuels. Research is planned to study the reactivity of adsorbates, their role in the photosynthesis reaction, and their relation to the nature of surface sites during photosynthesis of methanol and hydrocarbons from CO{sub 2}/H{sub 2}O. The year two research focus catalyst screening and IR studies. Key research results show Pd/TiO2 exhibits the highest activity for hydrocarbon synthesis from photocatalytic reactions. The in situ IR could successfully monitor the adsorbate hydrocarbon species on Cu/TiO2. Year III research will focus on developing a better understanding of the key factors which control the catalyst activity.

  7. Development and Testing of Molecular Adsorber Coatings

    NASA Technical Reports Server (NTRS)

    Abraham, Nithin; Hasegawa, Mark; Straka, Sharon

    2012-01-01

    The effect of on-orbit molecular contamination has the potential to degrade the performance of spaceflight hardware and diminish the lifetime of the spacecraft. For example, sensitive surfaces, such as optical surfaces, electronics, detectors, and thermal control surfaces, are vulnerable to the damaging effects of contamination from outgassed materials. The current solution to protect these surfaces is through the use of zeolite coated ceramic adsorber pucks. However, these pucks and its additional complex mounting hardware requirements result in several disadvantages, such as size, weight, and cost related concerns, that impact the spacecraft design and the integration and test schedule. As a result, a new innovative molecular adsorber coating was developed as a sprayable alternative to mitigate the risk of on-orbit molecular contamination. In this study, the formulation for molecular adsorber coatings was optimized using various binders, pigment treatment methods, binder to pigment ratios, thicknesses, and spray application techniques. The formulations that passed coating adhesion and vacuum thermal cycling tests were further tested for its adsorptive capacity. Accelerated molecular capacitance tests were performed in an innovatively designed multi-unit system containing idealized contaminant sources. This novel system significantly increased the productivity of the testing phase for the various formulations that were developed. Work performed during the development and testing phases has demonstrated successful application of molecular adsorber coatings onto metallic substrates, as well as, very promising results for the adhesion performance and the molecular capacitance of the coating. Continued testing will assist in the qualification of molecular adsorber coatings for use on future contamination sensitive spaceflight missions.

  8. Recycling light metals from end-of-life vehicle

    NASA Astrophysics Data System (ADS)

    Gesing, A.; Wolanski, R.

    2001-11-01

    The amount of aluminum used in cars and light trucks is growing steadily. However, without new developments in aluminum recycling technologies, sheet from automotive aluminum could eventually flood all current markets for recycled aluminum. This article summarizes the use of light metals and different alloys in transportation applications, the current auto recycling system, and new developments in the sorting of light metals by the metal recycling industry and by Huron Valley Steel Corporation, the world’s largest non-ferrous scrap sorter.

  9. CO2 Sequestration and Recycle by Photosynthesis

    SciTech Connect

    Steven S.C. Chuang

    2003-02-01

    Visible light-photocatalysis could provide a cost-effective route to recycle CO{sub 2} to useful chemicals or fuels. Research is planned to study the reactivity of adsorbates, their role in the photosynthesis reaction, and their relation to the nature of surface sites during photosynthesis of methanol and hydrocarbons from CO{sub 2}/H{sub 2}O over four types of MCM-41/Al{sub 2}O{sub 3}-supported TiO{sub 2} and CdS catalysts: (1) ion-exchanged metal cations, (2) highly dispersed cations, (3) monolayer sites, and (4) modified monolayer catalysts. TiO{sub 2} was selected since it has exhibited higher activity than other oxide catalysts; CdS was selected for its photocatalytic activity in the visible light region. Al{sub 2}O{sub 3} provides excellent hydrothermal stability. MCM-41 offers high surface area (more than 800 m{sup 2}/g), providing a platform for preparing and depositing a large number of active sites per gram catalyst. The unique structure of these ion exchange cations, highly dispersed cations, and monolayer sites provides an opportunity to tailor their chemical/coordination environments for enhancing visible-light photocatalytic activity and deactivation resistance. The year one research tasks include (1) setting up experimental system, (2) preparing ion-exchanged metal cations, highly dispersed cations, monolayer sites of TiO{sub 2} and CdS, and (3) determination of the dependence of methanol activity/selectivity on the catalyst preparation techniques and their relation to adsorbate reactivity. During the first quarter, we have purchased a Gas Chromatography and all the necessary components for building 3 reactor systems, set up the light source apparatus, and calibrated the light intensity. In addition, monolayer TiO{sub 2}/MCM-41 and TiO{sub 2}/Al{sub 2}O{sub 3} catalyst were prepared. TiO{sub 2}/Al{sub 2}O{sub 3} was found to exhibit high activity for methanol synthesis. Repeated runs was planned to insure the reproducibility of the data.

  10. pH recycling aqueous two-phase systems applied in extraction of Maitake β-Glucan and mechanism analysis using low-field nuclear magnetic resonance.

    PubMed

    Hou, Huiyun; Cao, Xuejun

    2015-07-31

    In this paper, a recycling aqueous two-phase systems (ATPS) based on two pH-response copolymers PADB and PMDM were used in purification of β-Glucan from Grifola frondosa. The main parameters, such as polymer concentration, type and concentration of salt, extraction temperature and pH, were investigated to optimize partition conditions. The results demonstrated that β-Glucan was extracted into PADB-rich phase, while impurities were extracted into PMDM-rich phase. In this 2.5% PADB/2.5% PMDM ATPS, 7.489 partition coefficient and 96.92% extraction recovery for β-Glucan were obtained in the presence of 30mmol/L KBr, at pH 8.20, 30°C. The phase-forming copolymers could be recycled by adjusting pH, with recoveries of over 96.0%. Furthermore, the partition mechanism of Maitake β-Glucan in PADB/PMDM aqueous two-phase systems was studied. Fourier transform infrared spectra, ForteBio Octet system and low-field nuclear magnetic resonance (LF-NMR) were introduced for elucidating the partition mechanism of β-Glucan. Especially, LF-NMR was firstly used in the mechanism analysis in partition of aqueous two-phase systems. The change of transverse relaxation time (T2) in ATPS could reflect the interaction between polymers and β-Glucan. PMID:26094138

  11. Efficiency gain of solid oxide fuel cell systems by using anode offgas recycle - Results for a small scale propane driven unit

    NASA Astrophysics Data System (ADS)

    Dietrich, Ralph-Uwe; Oelze, Jana; Lindermeir, Andreas; Spitta, Christian; Steffen, Michael; Küster, Torben; Chen, Shaofei; Schlitzberger, Christian; Leithner, Reinhard

    The transfer of high electrical efficiencies of solid oxide fuel cells (SOFC) into praxis requires appropriate system concepts. One option is the anode-offgas recycling (AOGR) approach, which is based on the integration of waste heat using the principle of a chemical heat pump. The AOGR concept allows a combined steam- and dry-reforming of hydrocarbon fuel using the fuel cell products steam and carbon dioxide. SOFC fuel gas of higher quantity and quality results. In combination with internal reuse of waste heat the system efficiency increases compared to the usual path of partial oxidation (POX). The demonstration of the AOGR concept with a 300 Wel-SOFC stack running on propane required: a combined reformer/burner-reactor operating in POX (start-up) and AOGR modus; a hotgas-injector for anode-offgas recycling to the reformer; a dynamic process model; a multi-variable process controller; full system operation for experimental proof of the efficiency gain. Experimental results proof an efficiency gain of 18 percentage points (η·POX = 23%, η·AOGR = 41%) under idealized lab conditions. Nevertheless, further improvements of injector performance, stack fuel utilization and additional reduction of reformer reformer O/C ratio and system pressure drop are required to bring this approach into self-sustaining operation.

  12. Iron nanotube-silica composite (ZVI-S-PCAT modified silica composite) preparation, characterization and application as a recyclable catalytic system for 5-membered ring organic transformations.

    PubMed

    Kour, Gurpreet; Gupta, Monika; Vishwanathan, B; Thirunavukkarasu, K

    2015-09-01

    Iron nanotube silica composite have been synthesized and studied through particle-size analysis, FTIR, SEM-EDX, TEM, XRD, UV, VSM, TGA-DTA and XPS techniques. The application of nanoframeworks as sustainable recyclable catalytic systems has been observed for azole cyclic ring organic transformations. The good reaction yields and characterization through (1)H NMR, (13)C NMR and mass analysis support the performance of the nanoframeworks. We also present here the synthesis of two novel compounds. Also the prepared nanoframework has been observed to show soft magnetism which provides a scope to be used in sensing devices. PMID:26228908

  13. Computer simulations of adsorbed liquid crystal films

    NASA Astrophysics Data System (ADS)

    Wall, Greg D.; Cleaver, Douglas J.

    2003-01-01

    The structures adopted by adsorbed thin films of Gay-Berne particles in the presence of a coexisting vapour phase are investigated by molecular dynamics simulation. The films are adsorbed at a flat substrate which favours planar anchoring, whereas the nematic-vapour interface favours normal alignment. On cooling, a system with a high molecule-substrate interaction strength exhibits substrate-induced planar orientational ordering and considerable stratification is observed in the density profiles. In contrast, a system with weak molecule-substrate coupling adopts a director orientation orthogonal to the substrate plane, owing to the increased influence of the nematic-vapour interface. There are significant differences between the structures adopted at the two interfaces, in contrast with the predictions of density functional treatments of such systems.

  14. Antiproton Cooling in the Fermilab Recycler Ring

    SciTech Connect

    Nagaitsev, S.; Broemmelsiek, D.; Burov, A.; Carlson, K.; Gattuso, C.; Hu, M.; Kramper, B.; Kroc, T.; Leibfritz, J.; Prost, L.; Pruss, S.; Saewert, G.; Schmidt, C. W.; Shemyakin, A.; Sutherland, M.; Tupikov, V.; Warner, A.; Bolshakov, A.; Zenkevich, P.; Kazakevich, G.

    2006-03-20

    The 8.9-GeV/c Recycler antiproton storage ring is equipped with both stochastic and electron cooling systems. These cooling systems are designed to assist accumulation of antiprotons for the Tevatron collider operations. In this paper we report on an experimental demonstration of electron cooling of high-energy antiprotons. At the time of writing this report, the Recycler electron cooling system is routinely used in collider operations. It has helped to set recent peak luminosity records.

  15. Antiproton cooling in the Fermilab Recycler Ring

    SciTech Connect

    Nagaitsev, S.; Bolshakov, A.; Broemmelsiek, D.; Burov, Alexey V.; Carlson, K.; Gattuso, C.; Hu, M.; Kazakevich, G.; Kramper, B.; Kroc, T.; Leibfritz, J.; Prost, L.; Pruss, S.; Saewert, G; Schmidt, C.W.; Seletskiy, S.; Shemyakin, A.; Sutherland, M.; Tupikov, V.; Warner, A.; Zenkevich, P.; /Fermilab /Moscow, ITEP /Novosibirsk, IYF /Rochester U.

    2005-12-01

    The 8.9-GeV/c Recycler antiproton storage ring is equipped with both stochastic and electron cooling systems. These cooling systems are designed to assist accumulation of antiprotons for the Tevatron collider operations. In this paper we report on an experimental demonstration of electron cooling of high-energy antiprotons. At the time of writing this report, the Recycler electron cooling system is routinely used in collider operations. It has helped to set recent peak luminosity records.

  16. Solid waste recycling programs at Rocky Flats

    SciTech Connect

    Millette, R.L.; Blackman, T.E.; Shepard, M.D.

    1994-12-31

    The Rocky Flats (RFP) recycling programs for solid waste materials have been in place for over ten years. Within the last three years, the programs were centralized under the direction of the Rocky Flats Waste Minimization department, with the assistance of various plant organizations (e.g., Trucking, Building Services, Regulated Waste Operations, property Utilization and Disposal and Security). Waste Minimization designs collection and transportation systems for recyclable materials and evaluates recycling markets for opportunities to add new commodities to the existing programs. The Waste Minimization department also promotes employee participation in the Rocky Flats Recycling Programs, and collects all recycling data for publication. A description of the program status as of January 1994 is given.

  17. Benchmarking survey for recycling.

    SciTech Connect

    Marley, Margie Charlotte; Mizner, Jack Harry

    2005-06-01

    This report describes the methodology, analysis and conclusions of a comparison survey of recycling programs at ten Department of Energy sites including Sandia National Laboratories/New Mexico (SNL/NM). The goal of the survey was to compare SNL/NM's recycling performance with that of other federal facilities, and to identify activities and programs that could be implemented at SNL/NM to improve recycling performance.

  18. A hybrid froth flotation-filtration system as a pretreatment for oil sands tailings pond recycle water management: Bench- and pilot-scale studies.

    PubMed

    Loganathan, Kavithaa; Bromley, David; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed

    2015-09-15

    Through sustainable water management, oil sands companies are working to reduce their reliance on fresh water by minimizing the amount of water required for their operations and by recycling water from tailings ponds. This study was the first pilot-scale testing of a hybrid technology consisting of froth flotation combined with filtration through precoated submerged stainless steel membranes used to treat recycle water from an oil sands facility. The results indicated that the most important factor affecting the performance of the hybrid system was the influent water quality. Any rise in the levels of suspended solids or total organic carbon of the feed water resulted in changes of chemical consumption rates, flux rates, and operating cycle durations. The selections of chemical type and dosing rates were critical in achieving optimal performance. In particular, the froth application rate heavily affected the overall recovery of the hybrid system as well as the performance of the flotation process. Optimum surfactant usage to generate froth (per liter of treated water) was 0.25 mL/L at approximately 2000 NTU of influent turbidity and 0.015 mL/L at approximately 200 NTU of influent turbidity. At the tested conditions, the optimal coagulant dose was 80 mg/L (as Al) at approximately 2000 NTU of influent turbidity and <40 mg/L (as Al) at approximately 200 NTU of influent turbidity. Precoat loading per unit membrane surface area tested during the pilot study was approximately 30 g/m(2). The results of this study indicated that this hybrid technology can potentially be considered as a pre-treatment step for reverse osmosis treatment of recycle water. PMID:26164269

  19. Some observations on the development of superior photocatalytic systems for application to water purification by the "adsorb and shuttle" or the interphase charge transfer mechanisms.

    PubMed

    Langford, Cooper; Izadifard, Maryam; Radwan, Emad; Achari, Gopal

    2014-01-01

    Adsorb and shuttle (A/S) and interfacial charge transfer are the two major strategies for overcoming recombination in photocatalysis in this era of nanoparticle composites. Their relationships are considered here. A review of key literature is accompanied by a presentation of three new experiments within the overall aim of assessing the relation of these strategies. The cases presented include: A/S by a high silica zeolite/TiO2 composite, charge transfer (CT) between phases in a TiO2/WO3 composite and both A/S and CT by composites of TiO2 with powered activated carbon (AC) and single-walled carbon nanotubes (SWCNT). The opportunities presented by the two strategies for moving toward photocatalysts that could support applications for the removal of contaminants from drinking water or that lead to a practical adsorbent for organics that could be regenerated photocatalytically link this discussion to ongoing research here. PMID:25432008

  20. Aluminum recycling in the United States in 2000

    USGS Publications Warehouse

    Plunkert, Patricia A.

    2006-01-01

    As one of a series of reports on metals recycling, this report discusses the flow of aluminum from production through its uses with particular emphasis on the recycling of industrial scrap (new scrap) and used products (old scrap) in 2000. This materials flow study includes a description of aluminum supply and demand factors for the United States to illustrate the extent of aluminum recycling and to identify recycling trends. Understanding the system of materials flow from source to ultimate disposition can assist in improving the management of natural resources in a manner that is compatible with sound environmental practices. In 2000, the old scrap recycling efficiency for aluminum was estimated to be 42 percent. Almost 60 percent of the aluminum that was recycled in 2000 came from new scrap, and the recycling rate was estimated to be 36 percent. The principal source of old scrap was recycled aluminum beverage cans.

  1. Extracorporeal detoxification for hepatic failure using molecular adsorbent recirculating system: depurative efficiency and clinical results in a long-term follow-up.

    PubMed

    Donati, Gabriele; La Manna, Gaetano; Cianciolo, Giuseppe; Grandinetti, Valeria; Carretta, Elisa; Cappuccilli, Maria; Panicali, Laura; Iorio, Mario; Piscaglia, Fabio; Bolondi, Luigi; Colì, Luigi; Stefoni, Sergio

    2014-02-01

    Acute liver failure and acute-on-chronic liver failure still show a poor prognosis. The molecular adsorbent recirculating system (MARS) has been extensively used as the most promising detoxifying therapy for patients with these conditions. Sixty-four patients with life-threatening liver failure were selected, and 269 MARS treatments were carried out as a bridge for orthotopic liver transplantation (OLT) or for liver function recovery. All patients were grouped according to the aim of MARS therapy. Group A consisted of 47 patients treated for liver function recovery (median age 59 years, range 23-82). Group B consisted of 11 patients on the waiting list who underwent OLT (median age 47 years, range 32-62). Group C consisted of 6 patients on the waiting list who did not undergo OLT (median age 45.5 years, range 36-54, P = 0.001). MARS depurative efficiency in terms of liver toxins, cytokines, and growth factors was assessed together with the clinical outcome of the patients during a 1-year follow-up. Total bilirubin reduction rate per session (RRs) for each MARS session was 23% (range 17-29); direct bilirubin RRs was 28% (21-35), and indirect bilirubin RRs was 8% (3-21). Ammonia RRs was 34% (12-86). Conjugated cholic acid RRs was 58% (48-61); chenodeoxycholic acid RRs was 34% (18-48). No differences were found between groups. Hepatocyte growth factor (HGF) values on starting MARS were 4.1 ng/mL (1.9-7.9) versus 7.9 ng/mL (3.2-14.1) at MARS end (P < 0.01). Cox regression analysis to determine the risk factors predicting patient outcomes showed that age, male gender, and Sequential Organ Failure Assessment score (but not Model for End-stage Liver Disease score) were factors predicting death, whereas the number of MARS sessions and the ΔHGF proved protective factors. Kaplan-Meier survival analysis was also used; after 12 months, 21.3% of patients in Group A survived, while 90.9% were alive in Group B and 16.7% in Group C (log rank = 0.002). In

  2. Utility of Recycled Bedding for Laboratory Rodents

    PubMed Central

    Miyamoto, Toru; Li, Zhixia; Kibushi, Tomomi; Okano, Shinya; Yamasaki, Nakamichi; Kasai, Noriyuki

    2009-01-01

    Animal facilities generate a large amount of used bedding containing excrement as medical waste. We developed a recycling system for used bedding that involves soft hydrothermal processing. In this study, we examined the effects of bedding type on growth, hematologic and serum biochemical values, and organ weights of female and male mice reared on either recycled or fresh bedding from 3 to 33 wk of age. Neither growth nor physiology differed between mice housed on recycled bedding compared with fresh bedding. When 14-wk-old mice were bred, litter size and total number of weaned pups showed no significant differences between animals raised on recycled or fresh bedding. Because bedding type influences the environment within cages and animal rooms, we evaluated particulate and ammonia data from cages and animal rooms. Values were significantly lower from cages and rooms that used recycled bedding than from those using fresh bedding, thus indicating that recycled bedding has the potential to improve the environment within both cages and animal rooms. Overall, this study revealed that recycled bedding is an excellent material for use in housing laboratory rodents. Specifically, recycled bedding may reduce medical waste and maintain healthy environments within cages and animal rooms. PMID:19653951

  3. Design of an integrated piggery system with recycled water, biomass production and water purification by vermiculture, macrophyte ponds and constructed wetlands.

    PubMed

    Morand, Philippe; Robin, Paul; Pourcher, Anne-Marie; Oudart, Didier; Fievet, Sebastien; Luth, Daniel; Cluzeau, Daniel; Picot, Bernadette; Landrain, Brigitte

    2011-01-01

    Since 2001 the swine experimental station of Guernévez has studied biological treatment plants for nutrient recovery and water recycling, suited to the fresh liquid manure coming out of flushing systems. An integrated system with continuous recycling was set up in 2007, associated with a piggery of 30 pregnant sows. It includes a screen, a vermifilter, and macrophyte ponds alternating with constructed wetlands. The screen and the vermifilter had a lower removal efficiency than in previous studies on finishing pigs. A settling tank was then added between the vermifilter and the first lagoon to collect the worm casts. A second vermifilter was added to recover this particulate organic matter. A storage lagoon was added to compensate for evaporative losses and complete pollution abatement, with goldfish as a bioindicator of water quality. The removal efficiency of the whole system was over 90% for COD and nitrogen, over 70% for phosphorus and potassium, and more than 4 logarithmic units for pathogens (E. coli, enterococci, C perfringens). Plant production was about 20 T DM ha(-1) y(-1). Floating macrophytes (Azolla caroliniana, Eichhornia crassipes, Hydrocotyle vulgaris) were more concentrated in nutrients than helophytes (Phragmites australis, Glyceria aquatica,…). Azolla caroliniana was successfully added to feed finishing pigs. PMID:21436573

  4. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  5. Poorly crystalline hydroxyapatite: A novel adsorbent for enhanced fulvic acid removal from aqueous solution

    NASA Astrophysics Data System (ADS)

    Wei, Wei; Yang, Lei; Zhong, Wenhui; Cui, Jing; Wei, Zhenggui

    2015-03-01

    In this study, poorly crystalline hydroxyapatite (HAP) was developed as an efficient adsorbent for the removal of fulvic acid (FA) from aqueous solution. Surface functionality, crystallinity, and morphology of the synthetic adsorbent were studied by Fourier-transformation infrared (FT-IR) spectroscopy, powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). The effects of various parameters such as crystallinity of adsorbent, contact time, adsorbent dosage, pH, initial adsorbate concentration, temperature, ionic strength and the presence of alkaline earth metal ions on FA adsorption were investigated. Results indicated that the nanosized HAP calcined at lower temperature was poorly crystalline (Xc = 0.23) and had better adsorption capacity for FA than those (Xc = 0.52, 0.86) calcined at higher temperature. FA removal was increased with increases of adsorbent dosage, temperature, ionic strength and the presence of alkali earth metal ions, but decreased as the pH increased. Kinetic studies showed that pseudo-second-order kinetic model better described the adsorption process. Equilibrium data were best described by Sips models, and the estimated maximum adsorption capacity of poorly crystalline HAP was 90.20 mg/g at 318 K, displaying higher efficiency for FA removal than previously reported adsorbents. FT-IR results revealed that FA adsorption over the adsorbent could be attributed to the surface complexation between the oxygen atom of functional groups of FA and calcium ions of HAP. Regeneration studies indicated that HAP could be recyclable for a long term. Findings of the present work highlight the potential for using poorly crystalline HAP nanoparticles as an effective and recyclable adsorbent for FA removal from aqueous solution.

  6. Volcanic arc magmas: implications of a melting-mixing model for element recycling in the crust-upper mantle system

    SciTech Connect

    Kay, R.W.

    1980-09-01

    In a model tested by mass balance calculations, residual periodotite (partly depleted in a basalt fraction) in a subducted lithospheric plate thermally equilibrates with the surrounding hotter mantle at depth beneath island arcs, and being less dense, rises as kilometer size diapires. The diapirs are modified by addiion of small proportions of melt or saline suprcritical fluid from the denser oceanic basalt (eclogite) and sediment. The diapire serves as a source for arc basalts. Mass balance calculations show that large proportions of the K, Rb, Pb, Ba and to a lesser extent Sr and light REE in island arc tholeiites are recycled continental crust material. Proportions are less for high-alumina basalts and shoshonites. High La/Sm basalts from volcanic arcs may be quite similar to their oceanic and intraplate counterparts. High La/Sm basalts are distinctly different. The model does not apply to magmas tha have been chemically modified during migration through the crust (e.g., some Andean andesites). Mass and element recycling rates can be calculated from the volcanic arc model, which gives the relative contributions of the melting components, and the magmatic production rates of arcs. Mantle-derived magmatism is forming new continental crust at arcs at a rate exceeding subduction of crustally-derived sediment at arcs. Thus, the crust appears to be growing, but at a rate that is perhaps half of the mean past rate. The K content of newly added continental crust, when corrected for recycling, is very much lower than the mean K content of the crust. Thus the dominant present mechanisms of crustal formation appears to yield a very different composition than past mechanisms which were responsible for formation of the bulk of the crust.

  7. DWPF recycle minimization: Brainstorming session

    SciTech Connect

    Jacobs, R.A.; Poirier, M.R.

    1993-10-12

    The recycle stream from the DWPF constitutes a major source of water addition to the High Level Waste evaporator system. As now designed, the entire flow of 3.5 to 6.5 gal/min (@ 25% and 75% attainment, respectively), or 2 gal/min during idling, flow to the 2H evaporator system (Tank 43). Substantial improvement in the HLW water balance and tank volume management is expected if the DWPF recycle to the HLW evaporator system can be significantly reduced. A task team has been appointed to study alternatives for reducing the flow to the HLW evaporator system and make recommendations for implementation and/or further study and evaluation. The brainstorming session detailed in this report was designed to produce the first cut options for the task team to further evaluate.

  8. Recycle with Heating: A Laboratory Experiment.

    ERIC Educational Resources Information Center

    Foord, A.; Mason, G.

    1985-01-01

    Describes an apparatus (built from domestic plumbing pipes and fittings) that uses only water and electricity (as consumables) to investigate basic mass and heat balances in a system with recycle. Also describes experiments using the apparatus. (JN)

  9. 40 CFR 141.76 - Recycle provisions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) NATIONAL PRIMARY DRINKING WATER REGULATIONS Filtration and Disinfection § 141.76 Recycle provisions. (a... completed no later than June 8, 2006. (d) Recordkeeping. The system must collect and retain on file...

  10. Recycling behaviour in healthcare: waste handling at work.

    PubMed

    Vogt, Joachim; Nunes, Katia R A

    2014-01-01

    This article reviews the motivational factors for environmental behaviour in general, presenting a case study on recycling disposable plastics in hospitals. Results show that 90% of over 600 employees from six analysed hospitals in Germany reported that the recycling of disposable plastics on the wards makes sense from an environmental and economic point of view. The case study reports an assessment of recycling attitudes and problems of hospital staff, mainly nurses. Employees in eco-certified hospitals were much more satisfied and reported fewer problems with the recycling system. The gender effect was significant only for saving energy, while age correlated with nearly all reported pro-environmental behaviour at home. At work, the mere introduction of a recycling system was insufficient to achieve good recycling results. Based on the study findings, recommendations are given aimed at improving the safety and sustainability of the recycling system. PMID:24617848

  11. Hollow-fiber-based adsorbers for gas separation by pressure-swing adsorption

    SciTech Connect

    Feng, X.; Pan, C.Y.; McMinis, C.W.; Ivory, J.; Ghosh, D.

    1998-07-01

    Hollow-fiber-based adsorbers for gas separation by pressure-swing adsorption (PSA) was studied experimentally. The high efficiency of hollow-fiber-based adsorbers for gas separation was illustrated by hydrogen separation using fine-powder-activated carbon and molecular sieve as adsorbents. The adsorption equilibrium and dynamics of the hollow-fiber adsorbers were determined. The pressure drop of the gas flowing through the adsorbers was also examined. The adsorbers were tested for hydrogen separation from nitrogen, carbon dioxide, and a multicomponent gas mixture simulating ammonia synthesis purge gas. The PSA systems using the hollow-fiber adsorbers were very effective for hydrogen purification. The high separation efficiency is derived from the fast mass-transfer rate and low pressure drop, two key features of hollow-fiber-based adsorbers.

  12. Application of the Saccharomyces cerevisiae FLP/FRT recombination system in filamentous fungi for marker recycling and construction of knockout strains devoid of heterologous genes.

    PubMed

    Kopke, Katarina; Hoff, Birgit; Kück, Ulrich

    2010-07-01

    To overcome the limited availability of antibiotic resistance markers in filamentous fungi, we adapted the FLP/FRT recombination system from the yeast Saccharomyces cerevisiae for marker recycling. We tested this system in the penicillin producer Penicillium chrysogenum using different experimental approaches. In a two-step application, we first integrated ectopically a nourseothricin resistance cassette flanked by the FRT sequences in direct repeat orientation (FRT-nat1 cassette) into a P. chrysogenum recipient. In the second step, the gene for the native yeast FLP recombinase, and in parallel, a codon-optimized P. chrysogenum flp (Pcflp) recombinase gene, were transferred into the P. chrysogenum strain carrying the FRT-nat1 cassette. The corresponding transformants were analyzed by PCR, growth tests, and sequencing to verify successful recombination events. Our analysis of several single- and multicopy transformants showed that only when the codon-optimized recombinase was present could a fully functional recombination system be generated in P. chrysogenum. As a proof of application of this system, we constructed a DeltaPcku70 knockout strain devoid of any heterologous genes. To further improve the FLP/FRT system, we produced a flipper cassette carrying the FRT sites as well as the Pcflp gene together with a resistance marker. This cassette allows the controlled expression of the recombinase gene for one-step marker excision. Moreover, the applicability of the optimized FLP/FRT recombination system in other fungi was further demonstrated by marker recycling in the ascomycete Sordaria macrospora. Here, we discuss the application of the optimized FLP/FRT recombination system as a molecular tool for the genetic manipulation of filamentous fungi. PMID:20472720

  13. Is Municipal Solid Waste Recycling Economically Efficient?

    NASA Astrophysics Data System (ADS)

    Lavee, Doron

    2007-12-01

    It has traditionally been argued that recycling municipal solid waste (MSW) is usually not economically viable and that only when externalities, long-term dynamic considerations, and/or the entire product life cycle are taken into account, recycling becomes worthwhile from a social point of view. This article explores the results of a wide study conducted in Israel in the years 2000 2004. Our results reveal that recycling is optimal more often than usually claimed, even when externality considerations are ignored. The study is unique in the tools it uses to explore the efficiency of recycling: a computer-based simulation applied to an extensive database. We developed a simulation for assessing the costs of handling and treating MSW under different waste-management systems and used this simulation to explore possible cost reductions obtained by designating some of the waste (otherwise sent to landfill) to recycling. We ran the simulation on data from 79 municipalities in Israel that produce over 60% of MSW in Israel. For each municipality, we were able to arrive at an optimal method of waste management and compare the costs associated with 100% landfilling to the costs born by the municipality when some of the waste is recycled. Our results indicate that for 51% of the municipalities, it would be efficient to adopt recycling, even without accounting for externality costs. We found that by adopting recycling, municipalities would be able to reduce direct costs by an average of 11%. Through interviews conducted with representatives of municipalities, we were also able to identify obstacles to the utilization of recycling, answering in part the question of why actual recycling levels in Israel are lower than our model predicts they should be.

  14. Recycling MgOH2 nanoadsorbent during treating the low concentration of CrVI.

    PubMed

    Liu, Weizhen; Huang, Feng; Wang, Yongjing; Zou, Ting; Zheng, Jinsheng; Lin, Zhang

    2011-03-01

    Investigations about how to recycle the deactivated nanomaterials are well-needed. This work was designed to explore the recycling strategy of Mg(OH)(2) nanoadsorbent during treating low concentration of Cr(VI) solution as an example. It was demonstrated that a reversible route between Cr-adsorbed nano-Mg(OH)(2) and Cr-desorbed bulk-MgCO(3) · 3H(2)O can be established by using CO(2) as a phase transformation medium. In each adsorption-desorption cycle, Cr(VI) solution with initial concentration of 10 mg · L(-1) could be enriched over 40 times. An aggregation-induced rapid phase transformation mechanism from nano-Mg(OH)(2) to bulk-MgCO(3) · 3H(2)O was discovered, which was one of the critical factors to ensure the disposing efficiency of this environmental-friendly Cr(VI) disposal system. A pilot-scale experiment was conducted with this strategy to deal with 50 L Cr(VI)-containing simulated industrial wastewater. The enrichment of Cr(VI) and the recycle of nano-Mg(OH)(2) can be successfully achieved simultaneously. PMID:21291274

  15. AIRCRAFT INDUSTRY WASTEWATER RECYCLING

    EPA Science Inventory

    The feasibility of recycling certain categories of water used in the manufacture of airplanes was demonstrated. Water in four categories was continuously recycled in 380-liter (100-gallon) treatment plants; chemical process rinse water, dye-penetrant crack-detection rinse water, ...

  16. Wee Recyclers Resources.

    ERIC Educational Resources Information Center

    Wisconsin State Dept. of Natural Resources, Madison.

    Hands-on activities in this guide are designed to help preschool children (ages 3-5) understand that reducing, reusing, and recycling preserves natural resources and prolongs the life of landfills. Children sort, match and compare recyclable items and learn to separate some items by number and color. The 29 activities are divided into units that…

  17. The Fermilab recycler ring

    SciTech Connect

    Martin Hu

    2001-07-24

    The Fermilab Recycler is a permanent magnet storage ring for the accumulation of antiprotons from the Antiproton Source, and the recovery and cooling of the antiprotons remaining at the end of a Tevatron store. It is an integral part of the Fermilab III luminosity upgrade. The following paper describes the design features, operational and commissioning status of the Recycler Ring.

  18. Carbon dioxide recycling

    EPA Science Inventory

    The recycling of carbon dioxide to methanol and dimethyl ether is seen to offer a substantial route to renewable and environmentally carbon neutral fuels. One of the authors has championed the “Methanol Economy" in articles and a book. By recycling ambient CO2, the authors argue ...

  19. Design for aluminum recycling

    SciTech Connect

    Not Available

    1993-10-01

    This article describes the increasing use of aluminum in automobiles and the need to recycle to benefit further growth of aluminum applications by assuring an economical, high-quality source of metal. The article emphasizes that coordination of material specifications among designers can raise aluminum scrap value and facilitate recycling. Applications of aluminum in automobile construction are discussed.

  20. Reuse, Reduce, Recycle.

    ERIC Educational Resources Information Center

    Briscoe, Georgia

    1991-01-01

    Discussion of recycling paper in law libraries is also applicable to other types of libraries. Results of surveys of law libraries that investigated recycling practices in 1987 and again in 1990 are reported, and suggestions for reducing the amount of paper used and reusing as much as possible are offered. (LRW)

  1. Recycling at Camp.

    ERIC Educational Resources Information Center

    Cummins, William M.

    1988-01-01

    Outlines a Michigan summer camp's efforts to reduce solid waste disposal by recycling cardboard, tin, glass, aluminum, and plastic milk containers. Points out variables affecting the success of such efforts. Discusses Michigan state funding for the development of recycling programs. (SV)

  2. Alkylammonium montmorillonites as adsorbents for organic vapors from air

    SciTech Connect

    Harper, M.; Purnell, C.J. )

    1990-01-01

    Montmorillonite clays may be modified by the exchange of the inorganic interlayer cations with alkylammonium ions, resulting in a fixed internal porosity. The pore size and shape depend on the nature of the alkylammonium ion. A number of different ions were used to prepare adsorbents with varying properties, and these were examined for their potential application to sampling organic vapors in air. Characterization involved determination of nitrogen and water contents, surface area, interlayer spacing, thermal stability, and breakthrough volumes of organic vapors. The adsorbent that showed the most promise (tetramethylammonium montmorillonite (TMA)) was further evaluated for use as an adsorbent in both thermal- and solvent-desorable sampling systems.

  3. Technology development for lunar base water recycling

    NASA Technical Reports Server (NTRS)

    Schultz, John R.; Sauer, Richard L.

    1992-01-01

    This paper will review previous and ongoing work in aerospace water recycling and identify research activities required to support development of a lunar base. The development of a water recycle system for use in the life support systems envisioned for a lunar base will require considerable research work. A review of previous work on aerospace water recycle systems indicates that more efficient physical and chemical processes are needed to reduce expendable and power requirements. Development work on biological processes that can be applied to microgravity and lunar environments also needs to be initiated. Biological processes are inherently more efficient than physical and chemical processes and may be used to minimize resupply and waste disposal requirements. Processes for recovering and recycling nutrients such as nitrogen, phosphorus, and sulfur also need to be developed to support plant growth units. The development of efficient water quality monitors to be used for process control and environmental monitoring also needs to be initiated.

  4. Evaluation of Recycle Grinding Performance in Flour Milling

    NASA Astrophysics Data System (ADS)

    Mazlina Mustapa Kamal, Siti; Webb, Colin

    A typical flour milling process is a very linear operation that is almost entirely void of recycled streams where separate fractions from each operation go ahead as new streams to the next operation. In some cases, there are opportunities for combining some streams, for recycling particles that have been insufficiently broken to go back to the same roller mill. This study introduces this recycle concept in flour milling process at second break system. The recycle grinding assessment was made using a Satake STR-100 test roller mill. The recycle process was started after the second break system and the number of recycle grinding was up to 7 regrinds. The particle size distribution and ash analysis were produced to describe the behaviour of the recycle grinding performance. The material release was sifted on a range of sieves and the ash content was analysed using a laboratory furnace. The performance for each recycle stage was investigated. It was determined that it is possible for some coarse particles that contain only bran to keep being recycled in the recycle circuit. A purging operation was recommended to be included in the recycle system, to separate the unwanted particles.

  5. Analysis of Adsorbed Natural Gas Tank Technology

    NASA Astrophysics Data System (ADS)

    Knight, Ernest; Schultz, Conrad; Rash, Tyler; Dohnke, Elmar; Stalla, David; Gillespie, Andrew; Sweany, Mark; Seydel, Florian; Pfeifer, Peter

    With gasoline being an ever decreasing finite resource and with the desire to reduce humanity's carbon footprint, there has been an increasing focus on innovation of alternative fuel sources. Natural gas burns cleaner, is more abundant, and conforms to modern engines. However, storing compressed natural gas (CNG) requires large, heavy gas cylinders, which limits space and fuel efficiency. Adsorbed natural gas (ANG) technology allows for much greater fuel storage capacity and the ability to store the gas at a much lower pressure. Thus, ANG tanks are much more flexible in terms of their size, shape, and weight. Our ANG tank employs monolithic nanoporous activated carbon as its adsorbent material. Several different configurations of this Flat Panel Tank Assembly (FPTA) along with a Fuel Extraction System (FES) were examined to compare with the mass flow rate demands of an engine.

  6. Advances in plastic recycling. Volume 1: Recycling of polyurethanes

    SciTech Connect

    Frisch, K.C.; Klempner, D.; Prentice, G.

    1999-07-01

    ``Recycling of Polyurethanes'', the first volume in the Advances in Plastics Recycling series, is focused on the physical and chemical recycling of polyurethanes, with attention given to energy conversion. A compilation of the present ongoing studies on recycling of urethane and, in general, isocyanate-based polymers, the focus is on thermosetting urethane polymers. Contents include: Recycling of Polyurethane Plastics in the European Automotive Industry; Present State of Polyurethane Recycling in Europe; Processing Overview of Bonded Polyurethane Foam; Mechanical Recycling of Polyurethane Scrap; Ecostream{trademark}--A Technology Beyond Recycling; Recycling of Flexible polyurethane Foam; General purpose Adhesives Prepared from Chemically Recycled Waste Rigid Polyurethane Foams; and Utilization of Isocyanate Binders in Recycling of Scrap Automotive Headliners.

  7. Potential of salt-accumulating and salt-secreting halophytic plants for recycling sodium chloride in human urine in bioregenerative life support systems

    NASA Astrophysics Data System (ADS)

    Tikhomirova, N. A.; Ushakova, S. A.; Kudenko, Yu. A.; Gribovskaya, I. V.; Shklavtsova, E. S.; Balnokin, Yu. V.; Popova, L. G.; Myasoedov, N. A.; Gros, J.-B.; Lasseur, Ch.

    2011-07-01

    This study addresses the possibility of growing different halophytic plants on mineralized human urine as a way to recycle NaCl from human wastes in a bioregenerative life support system (BLSS). Two halophytic plant species were studied: the salt-accumulating Salicornia europaea and the salt-secreting Limonium gmelinii. During the first two weeks, plants were grown on Knop's solution, then an average daily amount of urine produced by one human, which had been preliminarily mineralized, was gradually added to the experimental solutions. Nutrient solutions simulating urine mineral composition were gradually added to control solutions. NaCl concentrations in the stock solutions added to the experimental and control solutions were 9 g/L in the first treatment and 20 g/L in the second treatment. The mineralized human urine showed some inhibitory effects on S. europaea and L. gmelinii. The biomass yield of experimental plants was lower than that of control ones. If calculated for the same time period (120 d) and area (1 m 2), the amount of sodium chloride taken up by S. europaea plants would be 11.7 times larger than the amount taken up by L. gmelinii plants (486 g/m 2 vs. 41 g/m 2). Thus, S. europaea is the better choice of halophyte for recycling sodium chloride from human wastes in BLSS.

  8. A Novel Aqueous Two Phase System Composed of Surfactant and Xylitol for the Purification of Lipase from Pumpkin (Cucurbita moschata) Seeds and Recycling of Phase Components.

    PubMed

    Amid, Mehrnoush; Manap, Mohd Yazid; Hussin, Muhaini; Mustafa, Shuhaimi

    2015-01-01

    Lipase is one of the more important enzymes used in various industries such as the food, detergent, pharmaceutical, textile, and pulp and paper sectors. A novel aqueous two-phase system composed of surfactant and xylitol was employed for the first time to purify lipase from Cucurbita moschata. The influence of different parameters such as type and concentration of surfactants, and the composition of the surfactant/xylitol mixtures on the partitioning behavior and recovery of lipase was investigated. Moreover, the effect of system pH and crude load on the degree of purification and yield of the purified lipase were studied. The results indicated that the lipase was partitioned into the top surfactant rich phase while the impurities partitioned into the bottom xylitol-rich phase using an aqueous two phase system composed of 24% (w/w) Triton X-100 and 20% (w/w) xylitol, at 56.2% of tie line length (TLL), (TTL is one of the important parameters in this study and it is determined from a bimodal curve in which the tie-line connects two nodes on the bimodal, that represent concentration of phase components in the top and bottom phases) and a crude load of 25% (w/w) at pH 8.0. Recovery and recycling of components was also measured in each successive step process. The enzyme was successfully recovered by the proposed method with a high purification factor of 16.4 and yield of 97.4% while over 97% of the phase components were also recovered and recycled. This study demonstrated that the proposed novel aqueous two phase system method is more efficient and economical than the traditional aqueous two phase system method for the purification and recovery of the valuable enzyme lipase. PMID:26091076

  9. Recycling rubber wastes. (Latest citations from the Rubber and Plastics Research Association database). Published Search

    SciTech Connect

    1995-02-01

    The bibliography contains citations concerning research and innovations in the recycling of rubber wastes. Recycling methods and equipment, applications of recycled rubber, and energy recovery systems and performance are among the topics discussed. Recycling methods compared and contrasted with various rubber waste disposal techniques are also included. (Contains a minimum of 96 citations and includes a subject term index and title list.)

  10. Recycling rubber wastes. (Latest citations from the rubber and plastics research association database). Published Search

    SciTech Connect

    Not Available

    1994-05-01

    The bibliography contains citations concerning research and innovations in the recycling of rubber wastes. Recycling methods and equipment, applications of recycled rubber, and energy recovery systems and performance are among the topics discussed. Recycling methods compared and contrasted with various rubber waste disposal techniques are also included. (Contains a minimum of 89 citations and includes a subject term index and title list.)

  11. Recycling efficiencies of C,H,O,N,S, and P elements in a biological life support system based on micro-organisms and higher plants

    NASA Astrophysics Data System (ADS)

    Gros, J. B.; Poughon, L.; Lasseur, C.; Tikhomirov, A. A.

    MELiSSA is a microorganism based artificial ecosystem conceived as a tool for understanding the behavior of ecosystems and developing the technology for future Manned Space Missions. MELiSSA is composed of four compartments colonized by the microorganisms required by the function of this ecosystem : breakdown of waste produced by men, regeneration of atmosphere and biosynthesis of edible biomass. This paper reports the mass balance description of a Biological Life Support System composed of the MELiSSA loop and of a Higher Plant Compartment working in parallel with the photosynthetic Spirulina compartment producing edible biomass. The recycling efficiencies of the system are determined and compared for various working conditions of the MELiSSA loop with or without the HPC.

  12. Electronic structure of benzene adsorbed on Ni and Cu surfaces

    SciTech Connect

    Weinelt, M.; Nilsson, A.; Wassdahl, N.

    1997-04-01

    Benzene has for a long time served as a prototype adsorption system of large molecules. It adsorbs with the molecular plane parallel to the surface. The bonding of benzene to a transition metal is typically viewed to involve the {pi} system. Benzene adsorbs weakly on Cu and strongly on Ni. It is interesting to study how the adsorption strength is reflected in the electronic structure of the adsorbate-substrate complex. The authors have used X-ray Emission (XE) and X-ray Absorption (XA) spectroscopies to selectively study the electronic states localized on the adsorbed benzene molecule. Using XES the occupied states can be studies and with XAS the unoccupied states. The authors have used beamline 8.0 and the Swedish endstation equipped with a grazing incidence x-ray spectrometer and a partial yield absorption detector. The resolution in the XES and XAS were 0.5 eV and 0.05 eV, respectively.

  13. 3He Bilayer Film Adsorbed on Graphite Plated with a Bilayer of 4He: a New Frustrated 2D Magnetic System

    NASA Astrophysics Data System (ADS)

    Neumann, Michael; Nyéki, Ján; Cowan, Brian; Saunders, John

    2006-09-01

    The heat capacity and NMR response of a 3He bilayer adsorbed on graphite plated with a bilayer of 4He have been measured over the temperature range 1-80 mK. We find that the first 3He layer requires the presence of a 3He fluid overlayer before it solidifies. Solidification is completed at a total coverage close to 9.85 nm-2, On further increasing the coverage the heat capacity maximum grows from `antiferromagnetic-like' (AFM-like) to `ferromagnetic-like' (FM-like). On the other hand, when the 3He layer first solidifies, it has a low temperature saturation magnetisation corresponding to a significant fraction of full polarisation, and this increases with increasing coverage. Furthermore the effective exchange constant inferred from the high temperature magnetisation data is always ferromagnetic. The effective exchange constants inferred from the heat capacity and magnetisation are significantly larger than those observed in the second layer of pure 3He films adsorbed on bare graphite. Otherwise there are strong similarities in the coverage dependence of the heat capacity and magnetisation, providing fresh insights into how the magnetic ground state of such 2D magnets evolves as the frustration is tuned with increasing coverage.

  14. Crustal recycling and the aleutian arc

    SciTech Connect

    Kay, R.W.; Kay, S.M. )

    1988-06-01

    Two types of crustal recycling transfer continental crust back into its mantle source. The first of these, upper crustal recycling, involves elements that have been fractionated by the hydrosphere-sediment system, and are subducted as a part of the oceanic crust. The subduction process (S-process) then fractionates these elements, and those not removed at shallow tectonic levels and as excess components of arc magmas are returned to the mantle. Newly determined trace element composition of Pacific oceanic sedimants are variable and mixing is necessary during the S-process, if sediment is to provide excess element in the ratios observed in Aleutian arc magmas. Only a small fraction of the total sediment subducted at the Aleutian trench is required to furnish the excess elements in Aleutian arc magmas. Ba and {sub 10}Be data indicate that this small fraction includes a contribution from the youngest subducted sediment. The second type of recycling, lower crustal recycling, involves crystal cumulates of both arc and oceanic crustal origin, and residues from crustal melting within arc crust. Unlike the silicic sediments, recycled lower crust is mafic to ultramafic in composition. Trace element analyses of xenoliths representing Aleutian arc lower crust are presented. Recycling by delamination of lower crust and attached mantle lithosphere may occur following basalt eclogite phase transformations that are facilitated by terrane suturing events that weld oceanic island arcs to the continents. The relative importance of upper and lower crustal recycling exerts a primary control on continental crustal composition.

  15. Cell phone recycling experiences in the United States and potential recycling options in Brazil.

    PubMed

    Silveira, Geraldo T R; Chang, Shoou-Yuh

    2010-11-01

    This paper presents an overview of cell phone recycling programs currently available in the United States. At the same time, it also provides analyses of the current recycling situation and possible recycling alternatives for Brazil. Although there are several recycling options in the United States, collection rates are still only 10% of all potential devices because customers are not aware of these possibilities. The whole system is financially based on reselling refurbished cell phones and recycled materials to developing countries which represent an effective and strong market. Several recyclers offer funds to collection partners who are either charities or who work with charities while obtaining the materials that they need in order to run their operations. A mobile phone recycling system for Brazil considering the United States experience and the Extended Producer Responsibility (EPR) principle is suggested. A deposit/refund/advance-recycling fee is proposed which might be implemented as a voluntary industrial initiative managed by PRO Brazil, a producer responsibility organization. One widespread public-private agreement will integrate all mobile phone stakeholders, and environmental education actions and promotional events will promote citizen's participation. PMID:20554440

  16. Conformational changes of adsorbed proteins

    NASA Astrophysics Data System (ADS)

    Allen, Scott

    2005-03-01

    The adsorption of bovine serum albumin (BSA) and pepsin to gold surfaces has been studied using surface plasmon resonance (SPR). Proteins are adsorbed from solution onto a gold surface and changes in the conformation of the adsorbed proteins are induced by changing the buffer solution. We selected pH and ionic strength values for the buffer solutions that are known from our circular dichroism measurements to cause conformational changes of the proteins in bulk solution. We find that for both BSA and pepsin the changes in conformation are impeded by the interaction of the protein with the gold surface.

  17. Solvent recycle/recovery

    SciTech Connect

    Paffhausen, M.W.; Smith, D.L.; Ugaki, S.N.

    1990-09-01

    This report describes Phase I of the Solvent Recycle/Recovery Task of the DOE Chlorinated Solvent Substitution Program for the US Air Force by the Idaho National Engineering Laboratory, EG G Idaho, Inc., through the US Department of Energy, Idaho Operations Office. The purpose of the task is to identify and test recovery and recycling technologies for proposed substitution solvents identified by the Biodegradable Solvent Substitution Program and the Alternative Solvents/Technologies for Paint Stripping Program with the overall objective of minimizing hazardous wastes. A literature search to identify recycle/recovery technologies and initial distillation studies has been conducted. 4 refs.

  18. Electric Field Cancellation on Quartz by Rb Adsorbate-Induced Negative Electron Affinity

    NASA Astrophysics Data System (ADS)

    Sedlacek, J. A.; Kim, E.; Rittenhouse, S. T.; Weck, P. F.; Sadeghpour, H. R.; Shaffer, J. P.

    2016-04-01

    We investigate the (0001) surface of single crystal quartz with a submonolayer of Rb adsorbates. Using Rydberg atom electromagnetically induced transparency, we investigate the electric fields resulting from Rb adsorbed on the quartz surface, and measure the activation energy of the Rb adsorbates. We show that the adsorbed Rb induces negative electron affinity (NEA) on the quartz surface. The NEA surface allows low energy electrons to bind to the surface and cancel the electric field from the Rb adsorbates. Our results will be important for integrating Rydberg atoms into hybrid quantum systems, as fundamental probes of atom-surface interactions, and for studies of 2D electron gases bound to surfaces.

  19. Electric Field Cancellation on Quartz by Rb Adsorbate-Induced Negative Electron Affinity.

    PubMed

    Sedlacek, J A; Kim, E; Rittenhouse, S T; Weck, P F; Sadeghpour, H R; Shaffer, J P

    2016-04-01

    We investigate the (0001) surface of single crystal quartz with a submonolayer of Rb adsorbates. Using Rydberg atom electromagnetically induced transparency, we investigate the electric fields resulting from Rb adsorbed on the quartz surface, and measure the activation energy of the Rb adsorbates. We show that the adsorbed Rb induces negative electron affinity (NEA) on the quartz surface. The NEA surface allows low energy electrons to bind to the surface and cancel the electric field from the Rb adsorbates. Our results will be important for integrating Rydberg atoms into hybrid quantum systems, as fundamental probes of atom-surface interactions, and for studies of 2D electron gases bound to surfaces. PMID:27081976

  20. Carbon dioxide adsorbent study

    NASA Technical Reports Server (NTRS)

    Onischak, M.; Baker, B. S.

    1973-01-01

    A study was initiated on the feasibility of using the alkali metal carbonate - bi-carbonate solid-gas reaction to remove carbon dioxide from the atmosphere of an EVA life support system. The program successfully demonstrates that carbon dioxide concentrations could be maintained below 0.1 mole per cent using this chemistry. Further a practical method for distributing the carbonates in a coherent sheet form capable of repeated regeneration (50 cycles) at modest temperatures (423 K), without loss in activity was also demonstrated. Sufficiently high reaction rates were shown to be possible with the carbonate - bi-carbonate system such that EVA hardware could be readily designed. Experimental and design data were presented on the basis of which two practical units were designed. In addition to conventional thermally regenerative systems very compact units using ambient temperature cyclic vacuum regeneration may also be feasible. For a one man - 8 hour EVA unit regenerated thermally at the base ship a system volume of 14 liters is estimated.

  1. Equilibrium molecular theory of two-dimensional adsorbate drops on surfaces of heterogeneous adsorbents

    NASA Astrophysics Data System (ADS)

    Tovbin, Yu. K.

    2016-08-01

    A molecular statistical theory for calculating the linear tension of small multicomponent droplets in two-dimensional adsorption systems is developed. The theory describes discrete distributions of molecules in space (on a scale comparable to molecular size) and continuous distributions of molecules (at short distances inside cells) in their translational and vibrational motions. Pair intermolecular interaction potentials (the Mie type potential) in several coordination spheres are considered. For simplicity, it is assumed that distinctions in the sizes of mixture components are slight and comparable to the sizes of adsorbent adsorption centers. Expressions for the pressure tensor components inside small droplets on the heterogeneous surface of an adsorbent are obtained, allowing calculations of the thermodynamic characteristics of a vapor-fluid interface, including linear tension. Problems in refining the molecular theory are discussed: describing the properties of small droplets using a coordination model of their structure, considering the effect an adsorbate has on the state of a near-surface adsorbent region, and the surface heterogeneity factor in the conditions for the formation of droplets.

  2. Quality requirements for reclaimed/recycled water

    NASA Technical Reports Server (NTRS)

    Janik, Daniel S.; Sauer, Richard L.; Pierson, Duane L.; Thorstenson, Yvonne R.

    1987-01-01

    Water used during current and previous space missions has been either carried or made aloft. Future human space endeavors will require some form of water reclamation and recycling. There is little experience in the U.S. space program with this technology. Water reclamation and recycling constitute engineering challenges of the broadest nature that will require an intensive research and development effort if this technology is to mature in time for practical use on the proposed U.S. Space Station. In order for this to happen, reclaimed/recycled water specifications will need to be devised to guide engineering development. Present NASA Potable Water Specifications are not applicable to reclaimed or recycled water. Adequate specifications for ensuring the quality of the reclaimed or recycled potable water system is reviewed, limitations of present water specifications are examined, world experience with potable water reclamation/recycling systems and systems analogs is reviewed, and an approach to developing pertinent biomedical water specifications for spacecraft is presented. Space Station water specifications should be designed to ensure the health of all likely spacecraft inhabitants including man, animals, and plants.

  3. The Totem Pole Recycled.

    ERIC Educational Resources Information Center

    Sewall, Susan Breyer

    1991-01-01

    Presents an activity that integrates science, environmental education, art, and social studies. Students identify and research an endangered species and construct a totem pole depicting the species using a recyclable material. (MDH)

  4. A Practical Recycling Project . . .

    ERIC Educational Resources Information Center

    Durant, Raymond H.; Mikuska, James M.

    1973-01-01

    Descirbes a school district's recycling program of aluminum lunch trays that are collected after their use. The trays are used as scrap metal in industrial education workshop and used for sand castings. (PS)

  5. Recycle plastics into feedstocks

    SciTech Connect

    Kastner, H.; Kaminsky, W.

    1995-05-01

    Thermal cracking of mixed-plastics wastes with a fluidized-bed reactor can be a viable and cost-effective means to meet mandatory recycling laws. Strict worldwide environmental statutes require the hydrocarbon processing industry (HPI) to develop and implement product applications and technologies that reuse post-consumer mixed-plastics waste. Recycling or reuse of plastics waste has a broad definition. Recycling entails more than mechanical regranulation and remelting of polymers for film and molding applications. A European consortium of academia and refiners have investigated if it is possible and profitable to thermally crack plastics into feedstocks for refining and petrochemical applications. Development and demonstration of pyrolysis methods show promising possibilities of converting landfill garbage into valuable feedstocks such as ethylene, propylene, BTX, etc. Fluidized-bed reactor technologies offer HPI operators a possible avenue to meet recycling laws, conserve raw materials and yield a profit. The paper describes thermal cracking for feedstocks and pyrolysis of polyolefins.

  6. Recycling of nonmetallics

    USGS Publications Warehouse

    Amey, E.B.; Kelly, T.D.

    1996-01-01

    The first factor determining recyclability is the composition of the material itself. Metals, for example, can be reused with little or no loss in quality. Paper and rubber, by this criterion, are less recyclable. Each time paper is recycled, some cellulose fibers are broken. Shorter fibers can mean weaker paper of perceived lower quality and value. Vulcanizing is an irreversible chemical process that precludes recycling rubber in its original form. Both materials may be reused in other applications often of lower value than the original one. To be recyclable, the discarded material must have a collection infrastructure at the source of waste generation, at a central collection site, or at curbside. The recovered material must also have a market. If it is priced noncompetitively or no market exists, if it does not meet specifications, or if it requires special technology investments which cannot be recovered through future sales, the recovered material may be stockpiled or discarded rather than recycled. ?? 1996 International Association for Mathematical Geology.

  7. Plastics waste trashes German recycling scheme

    SciTech Connect

    Chynoweth, E.

    1993-06-30

    Plastics waste is causing a major headache for Duales System Deutschland (DSD: Bonn), one of Europe`s groundbreaking national packaging recycling programs. Five of Germany`s states have threatened to withdraw from the plan mainly because of the lack of plastics recycling capacity, says a DSD spokeswoman. {open_quotes}The pace of establishing recycling capacity does not meet the zeal in collection.{close_quotes} she notes. In addition, the organization has been crippled by a lack of funds. It claims that up to half the subscribers to the scheme - who pay a fee to display a green dot on packaging - are either irregular payers or not paying fees in proportion to their use of the green dot. The cost of setting up and paying for plastics recycling - not originally part of DSD`s responsibility - is also hurting the organization.

  8. Perspectives on recycling centres and future developments.

    PubMed

    Engkvist, I-L; Eklund, J; Krook, J; Björkman, M; Sundin, E

    2016-11-01

    The overall aim of this paper is to draw combined, all-embracing conclusions based on a long-term multidisciplinary research programme on recycling centres in Sweden, focussing on working conditions, environment and system performance. A second aim is to give recommendations for their development of new and existing recycling centres and to discuss implications for the future design and organisation. Several opportunities for improvement of recycling centres were identified, such as design, layout, ease with which users could sort their waste, the work environment, conflicting needs and goals within the industry, and industrialisation. Combining all results from the research, which consisted of different disciplinary aspects, made it possible to analyse and elucidate their interrelations. Waste sorting quality was recognized as the most prominent improvement field in the recycling centre system. The research identified the importance of involving stakeholders with different perspectives when planning a recycling centre in order to get functionality and high performance. Practical proposals of how to plan and build recycling centres are given in a detailed checklist. PMID:26826952

  9. Adsorbents as antiendotoxin agents in experimental colitis.

    PubMed Central

    Gardiner, K R; Anderson, N H; McCaigue, M D; Erwin, P J; Halliday, M I; Rowlands, B J

    1993-01-01

    The intestinal mucosa protects the body from a large reservoir of intraluminal pathogenic bacteria and endotoxins. This mucosal barrier is disrupted by the inflammation and ulceration of inflammatory bowel disease and may permit the absorption of toxic bacterial products. Systemic endotoxaemia has been demonstrated in ulcerative colitis and Crohn's disease and correlates with the extent and activity of disease. In this study the efficacy of absorbents as antiendotoxin agents in a hapten induced rat model of colitis is investigated. Induction of colitis was associated with systemic endotoxaemia. Enteral administration of terra fullonica and kaolin, but not of charcoal, significantly reduced systemic endotoxaemia (terra fullonica 4.2 (1.40) pg/ml; kaolin 5.29 (1.86) pg/ml; charcoal 32.7 (16.6) pg/ml; water 39.8 (12.6) pg/ml). Data expressed as mean (SE). With increasing severity of colitis, there was a decreasing ability of adsorbent therapy (terra fullonica) to control systemic endotoxaemia. Enteral administration of adsorbents controls gut derived systemic endotoxaemia in experimental colitis in animals and may be a useful antiendotoxin treatment in patients with inflammatory bowel disease. PMID:8432452

  10. Halophytic plants as a component of a bioregenerative life support system for recycling of NaCl contained in human liquid waste.

    NASA Astrophysics Data System (ADS)

    Balnokin, Yurii; Balnokin, Yurii; Myasoedov, Nikolay; Popova, Larissa; Tikhomirov, Alexander A.; Ushakova, Sofya; Tikhomirova, Natalia; Lasseur, Christophe; Gros, Jean-Bernard

    Currently, the closure of matter turnover is one of the urgent problems of bioregenerative life support system (BLSS) designing. The important aspect of the problem is involving of substances contained in liquid and solid exometabolites of humans inhabiting BLSS into intrasystem matter turnover. Recycling of Na+ and Cl- contained in human liquid exometabolites, i.e. urine is acknowledged to be among the main tasks of the matter turnover in BLSS. The ions excreted with urine may be returned to human organism with food. A way to allow this is including edible halophytic plants into the phototrophic compartment of BLSS. Halophytes are defined as plants which can grow on saline soils and produce high biomass under these conditions. Some halophytes can take up high quantities of Na+ and Cl- and accumulate the ions in the shoots or extrude them to leaf surface by means of salt glands. To allow Na+ and Cl- recycling through halophyte utilization, the following principal steps should be accomplished: (i) mineralization of the exometabolites by physicochemical methods; (ii) oxidation of ammonia formed during the exometabolite mineralization to nitrate by nitrifying bacteria, (iii) growing the halophyte on the nutrient solution prepared on the basis of the mineralized exometabolites, (iv) introducing the halophyte green biomass into human food. The present work is devoted to the following problems: (i) selection of a salt-accumulating/extruding halophytic plant suitable for Na+ and Cl- recycling in BLSS and (ii) parameter evaluation of a plant conveyor containing the halophytic plants at various ages. Halophytic plants selected for BLSS should meet the following criteria: (i) ability to grow under 24-hour-illumination, (ii) high productivity, (iii) ability to accumulate Na+ and Cl- in high quantities in shoots or to excrete salts to leaf surface, (iv) edibility, and (v) high nutritive value of the biomass. Relying on these criteria, salt-accumulating halophyte Salicornia

  11. An economic and technical assessment of black-dross and salt-cake-recycling systems for application in the secondary aluminum industry

    SciTech Connect

    Karvelas, D.; Daniels, E.; Jody, B.; Bonsignore, P.

    1991-12-01

    The secondary aluminum industry annually disposes of large amounts of dross residues and salt cake, which are by-products from the processing of scrap aluminum for reuse. These wastes contain as much as 50% salts and are presently disposed of in conventional landfills. As the costs of landfill space increase and the availability of landfill space decreases, disposal of the residues will increasingly compromise the economics of recycling aluminum. Alternative processes exist by which the major constituents of the various drosses and salt cakes can be recovered for recycling. In this study, we review available recycling technologies and processes relevant to the recycling of black dross and salt cake and discuss new concepts that have the potential to improve the cost-effectiveness of recycling technologies.

  12. Gold recovery from low concentrations using nanoporous silica adsorbent

    NASA Astrophysics Data System (ADS)

    Aledresse, Adil

    The development of high capacity adsorbents with uniform porosity denoted 5%MP-HMS (5% Mercaptopropyl-Hexagonal Mesoporous Structure) to extract gold from noncyanide solutions is presented. The preliminary studies from laboratory simulated noncyanide gold solutions show that the adsorption capacities of these materials are among the highest reported. The high adsorption saturation level of these materials, up to 1.9 mmol/g (37% of the adsorbent weight) from gold chloride solutions (potassium tetrachloroaurate) and 2.9 mmol/g (57% of the adsorbent weight) from gold bromide solutions (potassium tetrabromoaurate) at pH = 2, is a noteworthy feature of these materials. This gold loading from [AuC4]- and [AuBr4 ]- solutions corresponds to a relative Au:S molar ratio of 2.5:1 and 3.8:1, respectively. These rates are significantly higher than the usual 1:1 (Au:S) ratio expected for metal ion binding with the material. The additional gold ions loaded have been spontaneously reduced to metallic gold in the mesoporous material. Experimental studies indicated high maximum adsorptions of gold as high as 99.9% recovery. Another promising attribute of these materials is their favourable adsorption kinetics. The MP-HMS reaches equilibrium (saturation) in less than 1 minute of exposure in gold bromide and less than 10 minutes in gold chloride. The MP-HMS materials adsorption is significantly improved by agitation and the adsorption capacity of Au (III) ions increases with the decrease in pH. The recovery of adsorbed gold and the regeneration of spent adsorbent were investigated for MP-HMS adsorbent. The regenerated adsorbent (MP-HMS) maintained its adsorption capacity even after repeated use and all the gold was successfully recovered from the spent adsorbent. For the fist time, a promising adsorbent system has been found that is capable of effectively concentrating gold thiosulphate complexes, whereas conventional carbon-inpulp (CIP) and carbon-in-leach (CIL) systems fail. The

  13. Application of Silver Impregnated Iodine Adsorbent to Nuclear Facilities

    NASA Astrophysics Data System (ADS)

    Fukasawa, Tetsuo; Nakamura, Tomotaka; Kondo, Yoshikazu; Funabashi, Kiyomi

    Radioactive iodine is one of the most important nuclides to be prevented for release from nuclear facilities and many facilities have off-gas treatment systems to minimize the volatile nuclides dispersion to the environment. Silver impregnated inorganic adsorbents were known as inflammable and stable fixing materials for iodine and the authors started to develop 25 years ago a kind of inorganic adsorbent that has better capability compared with conventional ones. Aluminum oxide (Alumina) was selected as a carrier material and silver nitrate as an impregnated one. Pore diameters were optimized to avoid the influence of impurities such as humidity in the off-gas stream at lower temperatures. Experiments and improvements were alternately conducted for the new adsorbent. The tests were carried out in various conditions to confirm the performance of the developed adsorbent, which clarified its good ability to remove iodine. Silver nitrate impregnated alumina adsorbent (AgA) has about twice the capacity for iodine adsorption and higher iodine removal efficiency at relatively high humidity than conventional ones. The AgA chemically and stably fixes radioactive iodine and fits the storage and disposal of used adsorbent. AgA is now and will be applied to nuclear power plants, reprocessing plants, and research facilities.

  14. Lead removal with adsorbing colloid flotation

    SciTech Connect

    Thackston, E.L.; Wilson, D.J.; Hanson, J.S.; Miller, D.L. Jr.

    1980-02-01

    A process that removes lead from industrial waste by adsorbing colloid foam flotation has been designed and demonstrated. A system of ferric chloride and sodium lauryl sulfate, both relatively inexpensive chemicals, gave good performance with optimum dosages of sodium lauryl sulfate at 40 mg/l and trivalent iron at 150 mg/l. With optimum chemical and hydraulic conditions, the pilot plant was able to produce effluents with lead concentrations of less than 0.5 mg/l. The process may be especially attractive where space for heavy metals removal equipment is extremely limited.

  15. Integrated Recycling Test Fuel Fabrication

    SciTech Connect

    R.S. Fielding; K.H. Kim; B. Grover; J. Smith; J. King; K. Wendt; D. Chapman; L. Zirker

    2013-03-01

    The Integrated Recycling Test is a collaborative irradiation test that will electrochemically recycle used light water reactor fuel into metallic fuel feedstock. The feedstock will be fabricated into a metallic fast reactor type fuel that will be irradiation tested in a drop in capsule test in the Advanced Test Reactor on the Idaho National Laboratory site. This paper will summarize the fuel fabrication activities and design efforts. Casting development will include developing a casting process and system. The closure welding system will be based on the gas tungsten arc burst welding process. The settler/bonder system has been designed to be a simple system which provides heating and controllable impact energy to ensure wetting between the fuel and cladding. The final major pieces of equipment to be designed are the weld and sodium bond inspection system. Both x-radiography and ultrasonic inspection techniques have been examine experimentally and found to be feasible, however the final remote system has not been designed. Conceptual designs for radiography and an ultrasonic system have been made.

  16. Modeling of a thermally integrated 10 kWe planar solid oxide fuel cell system with anode offgas recycling and internal reforming by discretization in flow direction

    NASA Astrophysics Data System (ADS)

    Wahl, Stefanie; Segarra, Ana Gallet; Horstmann, Peter; Carré, Maxime; Bessler, Wolfgang G.; Lapicque, François; Friedrich, K. Andreas

    2015-04-01

    Combined heat and power production (CHP) based on solid oxide fuel cells (SOFC) is a very promising technology to achieve high electrical efficiency to cover power demand by decentralized production. This paper presents a dynamic quasi 2D model of an SOFC system which consists of stack and balance of plant and includes thermal coupling between the single components. The model is implemented in Modelica® and validated with experimental data for the stack UI-characteristic and the thermal behavior. The good agreement between experimental and simulation results demonstrates the validity of the model. Different operating conditions and system configurations are tested, increasing the net electrical efficiency to 57% by implementing an anode offgas recycle rate of 65%. A sensitivity analysis of characteristic values of the system like fuel utilization, oxygen-to-carbon ratio and electrical efficiency for different natural gas compositions is carried out. The result shows that a control strategy adapted to variable natural gas composition and its energy content should be developed in order to optimize the operation of the system.

  17. New approaches for MOX multi-recycling

    SciTech Connect

    Gain, T.; Bouvier, E.; Grosman, R.; Senentz, G.H.; Lelievre, F.; Bailly, F.; Brueziere, J.; Murray, P.

    2013-07-01

    Due to its low fissile content after irradiation, Pu from used MOX fuel is considered by some as not recyclable in LWR (Light Water Reactors). The point of this paper is hence to go back to those statements and provide a new analysis based on AREVA extended experience in the fields of fissile and fertile material management and optimized waste management. This is done using the current US fuel inventory as a case study. MOX Multi-recycling in LWRs is a closed cycle scenario where U and Pu management through reprocessing and recycling leads to a significant reduction of the used assemblies to be stored. The recycling of Pu in MOX fuel is moreover a way to maintain the self-protection of the Pu-bearing assemblies. With this scenario, Pu content is also reduced repetitively via a multi-recycling of MOX in LWRs. Simultaneously, {sup 238}Pu content decreases. All along this scenario, HLW (High-Level Radioactive Waste) vitrified canisters are produced and planned for deep geological disposal. Contrary to used fuel, HLW vitrified canisters do not contain proliferation materials. Moreover, the reprocessing of used fuel limits the space needed on current interim storage. With MOX multi-recycling in LWR, Pu isotopy needs to be managed carefully all along the scenario. The early introduction of a limited number of SFRs (Sodium Fast Reactors) can therefore be a real asset for the overall system. A few SFRs would be enough to improve the Pu isotopy from used LWR MOX fuel and provide a Pu-isotopy that could be mixed back with multi-recycled Pu from LWRs, hence increasing the Pu multi-recycling potential in LWRs.

  18. Recycling of Reinforced Plastics

    NASA Astrophysics Data System (ADS)

    Adams, R. D.; Collins, Andrew; Cooper, Duncan; Wingfield-Digby, Mark; Watts-Farmer, Archibald; Laurence, Anna; Patel, Kayur; Stevens, Mark; Watkins, Rhodri

    2014-02-01

    This work has shown is that it is possible to recycle continuous and short fibre reinforced thermosetting resins while keeping almost the whole of the original material, both fibres and matrix, within the recyclate. By splitting, crushing hot or cold, and hot forming, it is possible to create a recyclable material, which we designate a Remat, which can then be used to remanufacture other shapes, examples of plates and tubes being demonstrated. Not only can remanufacturing be done, but it has been shown that over 50 % of the original mechanical properties, such as the E modulus, tensile strength, and interlaminar shear strength, can be retained. Four different forms of composite were investigated, a random mat Glass Fibre Reinforced Plastic (GFRP) bathroom component and boat hull, woven glass and carbon fibre cloth impregnated with an epoxy resin, and unidirectional carbon fibre pre-preg. One of the main factors found to affect composite recyclability was the type of resin matrix used in the composite. Thermoset resins tested were shown to have a temperature range around the Glass Transition Temperature (Tg) where they exhibit ductile behaviour, hence aiding reforming of the material. The high-grade carbon fibre prepreg was found to be less easy to recycle than the woven of random fibre laminates. One method of remanufacturing was by heating the Remat to above its glass transition temperature, bending it to shape, and then cooling it. However, unless precautions are taken, the geometric form may revert. This does not happen with the crushed material.

  19. Supercritical fluid regeneration of adsorbents

    NASA Astrophysics Data System (ADS)

    Defilippi, R. P.; Robey, R. J.

    1983-05-01

    The results of a program to perform studies supercritical (fluid) carbon dioxide (SCF CO2) regeneration of adsorbents, using samples of industrial wastewaters from manufacturing pesticides and synthetic solution, and to estimate the economics of the specific wastewater treatment regenerations, based on test data are given. Processing costs for regenerating granular activated carbon GAC) for treating industrial wastewaters depend on stream properties and regeneration throughput.

  20. An improved high intensity recycling helium-3 beam source

    SciTech Connect

    Hedgeland, H.; Kole, P. R.; Allison, W.; Ellis, J.; Jardine, A. P.

    2009-07-15

    We describe an improved high intensity, recycling, supersonic atomic beam source. Changes address several issues previously limiting performance and reliability of the apparatus, including the use of newly available vacuum pumps and modifications to the recycling system. We achieve a source intensity of 2.5x10{sup 19} atoms/s/sr, almost twice that previously achievable during recycling. Current limits on intensity are discussed.

  1. An improved high intensity recycling helium-3 beam source.

    PubMed

    Hedgeland, H; Kole, P R; Allison, W; Ellis, J; Jardine, A P

    2009-07-01

    We describe an improved high intensity, recycling, supersonic atomic beam source. Changes address several issues previously limiting performance and reliability of the apparatus, including the use of newly available vacuum pumps and modifications to the recycling system. We achieve a source intensity of 2.5 x 10(19) atoms/s/sr, almost twice that previously achievable during recycling. Current limits on intensity are discussed. PMID:19655995

  2. Who owns the recyclables

    SciTech Connect

    Parker, B.

    1994-05-01

    On March 31, the California Supreme Court decided the much awaited Rancho Mirage'' case (Waste Management of the Desert, Inc., and the City of Rancho Mirage v. Palm Springs Recycling Center, Inc.), and held that the California Integrated Waste Management Act of 1989 does not allow an exclusive franchise for the collection of recyclables not discarded by their owner.'' This ends a three-year slugfest between secondary materials processors in the state and municipalities and their franchised garbage haulers who also collect and process recyclables as part of their exclusive arrangement. Central to this nationally-watched litigation is a most fundamental question in waste management: at what point in time do articles in the solid waste stream become actual or potentially valuable secondary materials

  3. Scrap tire recycling

    SciTech Connect

    Lula, J.W.; Bohnert, G.W.

    1997-03-01

    As the automobile tire technology has grown and met the need for safer and more durable tires, stronger reinforcement and more chemically resistant rubber compounds have made recycling tires more difficult. In an effort to resolve this problem, techniques and equipment were developed to grind tires into small pieces, and new markets were sought to utilize the crumb rubber product streams from ground tires. Industrial combustion processes were modified to accept scrap tires as fuel. These efforts have been beneficial, steadily increasing the percentage of scrap tires recycled to about 10% in 1985, and reaching 72% in 1995. By the end of 1997, fully 100% of tires generated in the U.S. are expected to be recycled.

  4. Phosphorylated cellulose triacetate-silica composite adsorbent for recovery of heavy metal ion.

    PubMed

    Srivastava, Niharika; Thakur, Amit K; Shahi, Vinod K

    2016-01-20

    Phosphorylated cellulose triacetate (CTA)/silica composite adsorbent was prepared by acid catalyzed sol-gel method using an inorganic precursor (3-aminopropyl triethoxysilane (APTEOS)). Reported composite adsorbent showed comparatively high adsorption capacity for Ni(II) in compare with different heavy metal ions (Cu(2+), Ni(2+), Cd(2+) and Pb(2+)). For Ni(II) adsorption, effect of time, temperature, pH, adsorbent dose and adsorbate concentration were investigated; different kinetic models were also evaluated. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were also estimated and equilibrium adsorption obeyed Langmuir and Freundlich isotherms. Developed adsorbent exhibited about 78.8% Ni(II) adsorption at pH: 6 and a suitable candidate for the removal of Ni(II) ions from wastewater. Further, about 65.5% recovery of adsorbed Ni(II) using EDTA solution was demonstrated, which suggested effective recycling of the functionalized beads would enable it to be used in the treatment of contaminated water in industry. PMID:26572476

  5. Compact, Lightweight Adsorber and Sabatier Reactor for CO2 Capture and Reduction for Consumable and Propellant Production

    NASA Technical Reports Server (NTRS)

    Junaedi, Christian; Hawley, Kyle; Walsh, Dennis; Roychoudhury, Subir; Busby, Stacy A.; Abney, Morgan B.; Perry, Jay L.; Knox, James C.

    2012-01-01

    The utilization of CO2 to produce (or recycle) life support consumables, such as O2 and H2O, and to generate propellant fuels is an important aspect of NASA's concept for future, long duration planetary exploration. One potential approach is to capture and use CO2 from the Martian atmosphere to generate the consumables and propellant fuels. Precision Combustion, Inc. (PCI), with support from NASA, continues to develop its regenerable adsorber technology for capturing CO2 from gaseous atmospheres (for cabin atmosphere revitalization and in-situ resource utilization applications) and its Sabatier reactor for converting CO2 to methane and water. Both technologies are based on PCI's Microlith(R) substrates and have been demonstrated to reduce size, weight, and power consumption during CO2 capture and methanation process. For adsorber applications, the Microlith substrates offer a unique resistive heating capability that shows potential for short regeneration time and reduced power requirements compared to conventional systems. For the Sabatier applications, the combination of the Microlith substrates and durable catalyst coating permits efficient CO2 methanation that favors high reactant conversion, high selectivity, and durability. Results from performance testing at various operating conditions will be presented. An effort to optimize the Sabatier reactor and to develop a bench-top Sabatier Development Unit (SDU) will be discussed.

  6. Vibrational Studies of Adsorbate-Induced Reconstruction on Molybdenum Surfaces.

    NASA Astrophysics Data System (ADS)

    Lopinski, Gregory Peter

    Adsorbate-induced rearrangement of the substrate structure strongly modifies the adsorbate-substrate and adsorbate-adsorbate interactions, leading to the complex behavior observed in many chemisorption systems. In this thesis the H/Mo(211), O/Mo(211) and Na/Mo(100) systems have been studied using high resolution electron energy loss spectroscopy (HREELS) to observe vibrations of the adsorbed atoms. The vibrational data is correlated with observations of the long-range order probed by LEED as well as the work function changes induced by adsorption. Adsorbate -induced substrate reconstruction plays an important role in all three of these systems. Studies of the coadsorption systems O+H/Mo(211) and Na+O/Mo(100) indicate how these effects can influence interactions between adsorbates. For H/Mo(211), above 1ML a (1 x 1) to (1 x 2) transition is observed and attributed to modification of the substrate periodicity. Below 1ML, H atoms are bridge bonded and induce local distortions of the substrate. The transition to the (1 x 2) phase involves the ordering of these displacements and occupation of three-fold sites partially populated by conversion of the bridge bonded species. This conversion accounts for the sawtooth-like coverage dependence of the work function. The structural model proposed for this system is also supported by the desorption parameters and partial molar entropy extracted from adsorption isobars. Oxygen adsorption on Mo(211) involves the occupation of multiple binding sites, with both the long-range order and the local geometry of the adsorbate phases strongly temperature dependent. Coadsorption of low coverages of oxygen and hydrogen leads to segregation of the two adsorbates which can be understood in terms of a substrate-mediated repulsive interaction between O and H. For Na/Mo(100), the frequency of the Na-Mo symmetric stretch mode does not shift with coverage although the mode intensity is strongly coverage dependent. The absence of a frequency shift

  7. Method And Apparatus For Regenerating Nox Adsorbers

    DOEpatents

    Driscoll, J. Joshua; Endicott, Dennis L.; Faulkner, Stephen A.; Verkiel, Maarten

    2006-03-28

    Methods and apparatuses for regenerating a NOx adsorber coupled with an exhaust of an engine. An actuator drives a throttle valve to a first position when regeneration of the NOx adsorber is desired. The first position is a position that causes the regeneration of the NOx adsorber. An actuator drives the throttle valve to a second position while regeneration of the NOx adsorber is still desired. The second position being a position that is more open than the first position and operable to regenerate a NOx adsorber.

  8. Adsorption of thorium(IV) from simulated radioactive solutions using a novel electrospun PVA/TiO2/ZnO nanofiber adsorbent functionalized with mercapto groups: Study in single and multi-component systems

    NASA Astrophysics Data System (ADS)

    Alipour, Dariush; Keshtkar, Ali Reza; Moosavian, Mohammad Ali

    2016-03-01

    The novel polyvinyl alcohol/titanium oxide/zinc oxide (PVA/TiO2/ZnO) nanofiber adsorbent functionalized with 3-mercaptopropyltrimethoxysilane (TMPTMS) was prepared by electrospinning method and its potential was investigated for the adsorption of thorium from single and multi-metal aqueous solutions. The prepared adsorbent was characterized by FTIR, SEM and BET analysis. The influences of different operational parameters such as pH, ionic strength, equilibrium time, initial concentration and temperature were studied in batch mode. Investigation of ionic strength effect showed that the addition of NaNO3 to metal solution has a slight effect on the thorium adsorption, whereas pH value has a serious effect on the thorium adsorption at pH values lower than 4. The double-exponential model described the adsorption of Th(IV) ions much better than other kinetic models within both the single and multi-component systems. Among various isotherm models used, the equilibrium data of Th(IV) conformed the Langmuir isotherm in the single system, while those were best fitted by Dubinin-Radushkevich (D-R) isotherm in multi-component system. Thermodynamic parameters such as ΔH°, ΔS°, and ΔG° indicated that the nature of adsorption process was spontaneous, endothermic and thermodynamically favored. The inhibitory effect of other metal ions on the adsorption capacity of Th(IV) was in order of Al(III) > Cu(II) > Cd(II) > Ni(II) > U(VI) > Fe(II).

  9. The development of recycle-friendly automotive aluminum alloys

    NASA Astrophysics Data System (ADS)

    Das, Subodh K.; Green, J. A. S.; Kaufman, J. Gilbert

    2007-11-01

    The continuing growth of aluminum alloy usage in transportation applications, notably passenger automobiles and minivans, and the demonstrated economic benefits of recycling aluminum-rich vehicles increase the need to seriously consider the desirability of designing recycling-friendly alloys. This article focuses on that aspect of the recycling process for passenger vehicles. The goals are to illustrate the opportunities afforded by identifying and taking full advantage of potential metal streams in guiding the development of new alloys that use those streams. In speculating on several possible aluminum recovery practices and systems that might be used in recycling passenger vehicles, likely compositions are identified and preliminary assessments of their usefulness for direct recycling are made. Specific compositions for possible new recycle-friendly alloys are suggested. In addition, recommendations on how the aluminum enterprise, including industry, academia, and government, can work together to achieve the aggressive but important goals described here are discussed.

  10. A novel aqueous micellar two-phase system composed of surfactant and sorbitol for purification of pectinase enzyme from Psidium guajava and recycling phase components.

    PubMed

    Amid, Mehrnoush; Murshid, Fara Syazana; Manap, Mohd Yazid; Hussin, Muhaini

    2015-01-01

    A novel aqueous two-phase system composed of a surfactant and sorbitol was employed for the first time to purify pectinase from Psidium guajava. The influences of different parameters, including the type and concentration of the surfactant and the concentration and composition of the surfactant/sorbitol ratio, on the partitioning behavior and recovery of pectinase were investigated. Moreover, the effects of system pH and the crude load on purification fold and the yield of purified pectinase were studied. The experimental results indicated that the pectinase was partitioned into surfactant-rich top phase, and the impurities were partitioned into the sorbitol-rich bottom phase with the novel method involving an ATPS composed of 26% (w/w) Triton X-100 and 23% (w/w) sorbitol at 54.2% of the TLL crude load of 20% (w/w) at pH 6.0. The enzyme was successfully recovered by this method with a high purification factor of 15.2 and a yield of 98.3%, whereas the phase components were also recovered and recycled at rates above 96%. This study demonstrated that this novel ATPS method can be used as an efficient and economical alternative to the traditional ATPS for the purification and recovery of the valuable enzyme. PMID:25756051

  11. A Novel Aqueous Micellar Two-Phase System Composed of Surfactant and Sorbitol for Purification of Pectinase Enzyme from Psidium guajava and Recycling Phase Components

    PubMed Central

    Murshid, Fara Syazana; Manap, Mohd Yazid; Hussin, Muhaini

    2015-01-01

    A novel aqueous two-phase system composed of a surfactant and sorbitol was employed for the first time to purify pectinase from Psidium guajava. The influences of different parameters, including the type and concentration of the surfactant and the concentration and composition of the surfactant/sorbitol ratio, on the partitioning behavior and recovery of pectinase were investigated. Moreover, the effects of system pH and the crude load on purification fold and the yield of purified pectinase were studied. The experimental results indicated that the pectinase was partitioned into surfactant-rich top phase, and the impurities were partitioned into the sorbitol-rich bottom phase with the novel method involving an ATPS composed of 26% (w/w) Triton X-100 and 23% (w/w) sorbitol at 54.2% of the TLL crude load of 20% (w/w) at pH 6.0. The enzyme was successfully recovered by this method with a high purification factor of 15.2 and a yield of 98.3%, whereas the phase components were also recovered and recycled at rates above 96%. This study demonstrated that this novel ATPS method can be used as an efficient and economical alternative to the traditional ATPS for the purification and recovery of the valuable enzyme. PMID:25756051

  12. DWPF RECYCLE EVAPORATOR FLOWSHEET EVALUATION (U)

    SciTech Connect

    Stone, M

    2005-04-30

    The Defense Waste Processing Facility (DWPF) converts the high level waste slurries stored at the Savannah River Site into borosilicate glass for long-term storage. The vitrification process results in the generation of approximately five gallons of dilute recycle streams for each gallon of waste slurry vitrified. This dilute recycle stream is currently transferred to the H-area Tank Farm and amounts to approximately 1,400,000 gallons of effluent per year. Process changes to incorporate salt waste could increase the amount of effluent to approximately 2,900,000 gallons per year. The recycle consists of two major streams and four smaller streams. The first major recycle stream is condensate from the Chemical Process Cell (CPC), and is collected in the Slurry Mix Evaporator Condensate Tank (SMECT). The second major recycle stream is the melter offgas which is collected in the Off Gas Condensate Tank (OGCT). The four smaller streams are the sample flushes, sump flushes, decon solution, and High Efficiency Mist Eliminator (HEME) dissolution solution. These streams are collected in the Decontamination Waste Treatment Tank (DWTT) or the Recycle Collection Tank (RCT). All recycle streams are currently combined in the RCT and treated with sodium nitrite and sodium hydroxide prior to transfer to the tank farm. Tank Farm space limitations and previous outages in the 2H Evaporator system due to deposition of sodium alumino-silicates have led to evaluation of alternative methods of dealing with the DWPF recycle. One option identified for processing the recycle was a dedicated evaporator to concentrate the recycle stream to allow the solids to be recycled to the DWPF Sludge Receipt and Adjustment Tank (SRAT) and the condensate from this evaporation process to be sent and treated in the Effluent Treatment Plant (ETP). In order to meet process objectives, the recycle stream must be concentrated to 1/30th of the feed volume during the evaporation process. The concentrated stream

  13. Selective solid-phase extraction of alpha-tocopherol by functionalized ionic liquid-modified mesoporous SBA-15 adsorbent.

    PubMed

    Li, Min; Pham, Patrisha J; Pittman, Charles U; Li, Tingyu

    2008-10-01

    Ordered mesoporous adsorbents were prepared by physically grafting functionalized ionic liquids onto SBA-15 (a mesoporous siliceous substrate) using incipient wetness immersion method. These adsorbents were successfully applied to the selective extraction and separation of alpha-tocopherol (an isomer of vitamin E) from a model mixture of soybean oil deodorizer distillate. Various parameters affecting adsorption process such as adsorption time, the structures and loadings of ionic liquids, the adsorption isotherm, and the reusability of adsorbent were investigated using liquid-solid extraction. As high as 211 mg/g adsorbent of the adsorption capacity for alpha-tocopherol was obtained through the adsorption isotherm tests using [emim][Gly]/SBA-15 (functionalized ionic liquid 1-ethyl-3-methylimidazolium glycine which was physically coated on SBA-15) as the adsorbent, in which the functionalized ionic liquids contained the amino acid glycine as the anion. The adsorbent [emim][Gly]/SBA-15 also exhibited a very high adsorption selectivity for alpha-tocopherol. The extraction selectivity or the ratio of distribution coefficients between alpha-tocopherol and the major interference component glyceryl triundecanoate (K(d(alpha-tocopherol))/K(d(triglyceride))) was 10.5. The concentration of alpha-tocopherol was significantly increased from 15.6% in original feedstock solution that contained fatty acid methyl ester, triglyceride and alpha-tocopherol to 73.0% after stripping by diethyl ether. Five adsorbent recycle tests showed good reusability of the functionalized ionic liquid-modified mesoporous adsorbent. PMID:18845881

  14. Recycling and computerized garbage tracking cut city's costs

    SciTech Connect

    Norris, J.L. )

    1994-02-01

    This article describes Athens, Ohio efforts to encourage recycling and minimizing of landfilled garbage by a sliding rate system for garbage collection that accommodates the highly transient nature of this college community. Residential waste going to the landfill has been reduced by as much as 50 percent. Recycling is scheduled the same day as garbage collection. Recycling crews sort all items and package them for sale. Yard wastes are also recycled and are co-mingled with digested municipal sludge generated at the waste-water treatment plant and applied on agricultural fields as a soil conditioner.

  15. Recycling Decisions and Green Design.

    ERIC Educational Resources Information Center

    Lave, Lester B.; And Others

    1994-01-01

    Explores the facts and perceptions regarding recycling, what can be done to make products more environmentally compatible, and how to think about recycling decisions in a more helpful way. (Contains 39 references.) (MDH)

  16. Recycled Insect Models

    ERIC Educational Resources Information Center

    Rule, Audrey C.; Meyer, Mary Ann

    2007-01-01

    This article presents an engaging activity in which high school students use a dichotomous key to guide the creation and classification of model insects from recycled plastic lids and containers. Besides teaching the use of a dichotomous key and the effect of evolutionary descent upon groupings of organisms, this activity focuses on an…

  17. Recycling Study Guide.

    ERIC Educational Resources Information Center

    Hallowell, Anne; And Others

    This study guide was designed to help teachers and students understand the problems surrounding solid wastes. It includes an overview of solid waste and recycling, a glossary, suggested activities and a list of resource publications, audiovisual materials and organizations. There are 19 activity suggestions included in this guide designed for use…

  18. The Recycle Team.

    ERIC Educational Resources Information Center

    Scott, Roger; And Others

    This guide provides lessons that enable students to learn how important it is for each of us to take care of the environment by minimizing the problems caused by too much trash. In the 10 lessons included here, students and their families learn how they can be part of the solution by practicing source reduction and by reusing, recycling, and…

  19. Deep Recycling of Carbon

    NASA Astrophysics Data System (ADS)

    Schmidt, M. W.

    2012-12-01

    While most of the subducted H2O is recycled at shallow and subarc depths, carbon is less readily mobilized and susceptive to complex redox processes involving CO2 in solids, fluids and melts, elemental carbon, Fe- and Si- carbides, and methane. Here I review the various ways of recycling carbon during subduction and present a spectrum of possible reaction products in the mantle. Metamorphic reactions liberate <20% of the subducted CO2 to the subarc region (Connolly 2005, EPSL). Larger amounts might be mobilized through (sediment) melting. Although the wet pelite solidus is only shifted by 30-50 oC (at 3 GPa) with carbonates, the latter remain stable with melts that are saturated in a H2O+CO2-fluid. Complete dissolution of carbonates requires temperatures above any predicted subduction geotherm. Carbonated sediments yield CO2-rich phonolites to 5 GPa but carbonatites at higher pressures. The silicate melts become increasingly potassic with pressure, while the alkali-rich carbonatites have their highest K/Na at 8 GPa, slightly decreasing to 13 GPa and become sodic with the disappearance of residual cpx at ~16 GPa. What may happen when carbonated pelite derived melts migrate into the mantle is illustrated in Central Italy: in this case, it can be experimentally demonstrated that hybridization of ultrapotassic phonolitic melts with ~2 wt% H2O and ~6 wt% CO2 in the mantle results in the primitive parents of the ultrapotassic kamafugite suites which have ~43 wt% SiO2. Hence, despite a crustal isotopic signature of C, O, and Sr in these rocks, the CO2 of the Italian magmatism does not stem from assimilation in the crust but from melts derived from subducted marine carbonates mixed with pelagic clays and then reacted in the mantle. The migration of CO2-bearing fluids and melts into the mantle may lead to a redox-shock. Where high liquid/mantle ratios prevail, carbonatites rest in their oxidized form and may only freeze in relatively cold lithospheric keels where they form

  20. Enhanced Control of PWR Primary Coolant Water Chemistry Using Selective Separation Systems for Recovery and Recycle of Enriched Boric Acid

    SciTech Connect

    Ken Czerwinski; Charels Yeamans; Don Olander; Kenneth Raymond; Norman Schroeder; Thomas Robison; Bryan Carlson; Barbara Smit; Pat Robinson

    2006-02-28

    The objective of this project is to develop systems that will allow for increased nuclear energy production through the use of enriched fuels. The developed systems will allow for the efficient and selective recover of selected isotopes that are additives to power water reactors' primary coolant chemistry for suppression of corrosion attack on reactor materials.

  1. RECYCLING OF RUNOFF AND SUBSURFACE DRAINAGE WATER IN THE MIDWEST U.S. (WETLAND RESERVOIR SUBIRRIGATION SYSTEMS -WRSIS)

    Technology Transfer Automated Retrieval System (TEKTRAN)

    An innovative agricultural water management system has been developed and is now being tested to determine efficacy for reduction of nonpoint source pollution of surface water streams. Widespread utilization of this system could substantially reduce many of the Midwest's agriculturally related envi...

  2. Adsorption of Magnesium Sulfate from Desulfurization Industrial Wastewater by Nano-Cerium Loaded Recycled Aggregates.

    PubMed

    Yoon, Hyung-Sun; Bak, Somi; Seo, Seong-Gyu; Choi, Jeongdong; Kim, Eun-Sik

    2016-02-01

    In this research, the recycled aggregates (RAs) from blast furnace were solidified with nano-cerium (Ce), and applied to reduce the ionic species (e.g., magnesium sulfate) in the desulfurization industrial wastewater. Static batch experiments were performed based on different loading of recycled aggregates. Sulfate sorption isotherm studies were performed by Langmuir adsorption model. The physical morphologies were determined using scanning electron microscope. The results presented that the partial ions were captured with the different loading of the recycled aggregates during the batch tests. It was observed that 8 hr batch reaction equilibrated the electrical conductivity reduction, and 13% mass loading was estimated an optimal dosage of adsorbent. This study showed the nano-Ce loaded RAs could reduce ionic species in wastewater, and expected to be an economical adsorbent for wastewater treatment process. PMID:27433701

  3. Recycling Behavior: A Multidimensional Approach

    ERIC Educational Resources Information Center

    Meneses, Gonzalo Diaz; Palacio, Asuncion Beerli

    2005-01-01

    This work centers on the study of consumer recycling roles to examine the sociodemographic and psychographic profile of the distribution of recycling tasks and roles within the household. With this aim in mind, an empirical work was carried out, the results of which suggest that recycling behavior is multidimensional and comprises the undertaking…

  4. Recycling of the #5 polymer.

    PubMed

    Xanthos, Marino

    2012-08-10

    Polypropylene (PP) is a widely used plastic with consumer applications ranging from food packaging to automotive parts, including car battery casings. To differentiate it from other recyclable plastics, it is designated as #5. Here, the factors contributing to PP recycling rates are briefly reviewed. Considerations include collection and separation efficiency, processing chemistry, and market dynamics for the products derived from recyclates. PMID:22879510

  5. Entropy, recycling and macroeconomics of water resources

    NASA Astrophysics Data System (ADS)

    Karakatsanis, Georgios; Mamassis, Nikos; Koutsoyiannis, Demetris

    2014-05-01

    We propose a macroeconomic model for water quantity and quality supply multipliers derived by water recycling (Karakatsanis et al. 2013). Macroeconomic models that incorporate natural resource conservation have become increasingly important (European Commission et al. 2012). In addition, as an estimated 80% of globally used freshwater is not reused (United Nations 2012), under increasing population trends, water recycling becomes a solution of high priority. Recycling of water resources creates two major conservation effects: (1) conservation of water in reservoirs and aquifers and (2) conservation of ecosystem carrying capacity due to wastewater flux reduction. Statistical distribution properties of the recycling efficiencies -on both water quantity and quality- for each sector are of vital economic importance. Uncertainty and complexity of water reuse in sectors are statistically quantified by entropy. High entropy of recycling efficiency values signifies greater efficiency dispersion; which -in turn- may indicate the need for additional infrastructure for the statistical distribution's both shifting and concentration towards higher efficiencies that lead to higher supply multipliers. Keywords: Entropy, water recycling, water supply multipliers, conservation, recycling efficiencies, macroeconomics References 1. European Commission (EC), Food and Agriculture Organization (FAO), International Monetary Fund (IMF), Organization of Economic Cooperation and Development (OECD), United Nations (UN) and World Bank (2012), System of Environmental and Economic Accounting (SEEA) Central Framework (White cover publication), United Nations Statistics Division 2. Karakatsanis, G., N. Mamassis, D. Koutsoyiannis and A. Efstratiades (2013), Entropy and reliability of water use via a statistical approach of scarcity, 5th EGU Leonardo Conference - Hydrofractals 2013 - STAHY '13, Kos Island, Greece, European Geosciences Union, International Association of Hydrological Sciences

  6. Flows of engineered nanomaterials through the recycling process in Switzerland

    SciTech Connect

    Caballero-Guzman, Alejandro; Sun, Tianyin; Nowack, Bernd

    2015-02-15

    Highlights: • Recycling is one of the likely end-of-life fates of nanoproducts. • We assessed the material flows of four nanomaterials in the Swiss recycling system. • After recycling, most nanomaterials will flow to landfills or incineration plants. • Recycled construction waste, plastics and textiles may contain nanomaterials. - Abstract: The use of engineered nanomaterials (ENMs) in diverse applications has increased during the last years and this will likely continue in the near future. As the number of applications increase, more and more waste with nanomaterials will be generated. A portion of this waste will enter the recycling system, for example, in electronic products, textiles and construction materials. The fate of these materials during and after the waste management and recycling operations is poorly understood. The aim of this work is to model the flows of nano-TiO{sub 2}, nano-ZnO, nano-Ag and CNT in the recycling system in Switzerland. The basis for this study is published information on the ENMs flows on the Swiss system. We developed a method to assess their flow after recycling. To incorporate the uncertainties inherent to the limited information available, we applied a probabilistic material flow analysis approach. The results show that the recycling processes does not result in significant further propagation of nanomaterials into new products. Instead, the largest proportion will flow as waste that can subsequently be properly handled in incineration plants or landfills. Smaller fractions of ENMs will be eliminated or end up in materials that are sent abroad to undergo further recovery processes. Only a reduced amount of ENMs will flow back to the productive process of the economy in a limited number of sectors. Overall, the results suggest that risk assessment during recycling should focus on occupational exposure, release of ENMs in landfills and incineration plants, and toxicity assessment in a small number of recycled inputs.

  7. Nitric oxide releasing material adsorbs more fibrinogen.

    PubMed

    Lantvit, Sarah M; Barrett, Brittany J; Reynolds, Melissa M

    2013-11-01

    One mechanism of the failure of blood-contacting devices is clotting. Nitric oxide (NO) releasing materials are seen as a viable solution to the mediation of surface clotting by preventing platelet activation; however, NO's involvement in preventing clot formation extends beyond controlling platelet function. In this study, we evaluate NO's effect on factor XII (fibrinogen) adsorption and activation, which causes the initiation of the intrinsic arm of the coagulation cascade. This is done by utilizing a model plasticized poly(vinyl) chloride (PVC), N-diazeniumdiolate system and looking at the adsorption of fibrinogen, an important clotting protein, to these surfaces. The materials have been prepared in such a way to eliminate changes in surface properties between the control (plasticized PVC) and composite (NO-releasing) materials. This allows us to isolate NO release and determine the effect on the adsorption of fibrinogen, to the material surface. Surprisingly, it was found that an NO releasing material with a surface flux of 17.4 ± 0.5 × 10(-10) mol NO cm(-2) min(-1) showed a significant increase in the amount of fibrinogen adsorbed to the material surface compared to one with a flux of 13.0 ± 1.6 × 10(-10) mol NO cm(-2) min(-1) and the control (2334 ± 496, 226 ± 99, and 103 ±31% fibrinogen adsorbed of control, respectively). This study suggests that NO's role in controlling clotting is extended beyond platelet activation. PMID:23554300

  8. A tale of five cities: Using recycling frameworks to analyse inclusive recycling performance.

    PubMed

    Scheinberg, Anne; Simpson, Michael

    2015-11-01

    'Recycling' is a source of much confusion, particularly when comparing solid waste systems in high-income countries with those in low- and middle-income countries. Few analysts can explain why the performance and structure of recycling appears to be so different in rich countries from poor ones, nor why well-meaning efforts to implement recycling so often fail. The analysis of policy drivers, and the Integrated Sustainable Waste Management (ISWM) framework, come close to an explanation.This article builds on these earlier works, focusing in on five cities profiled in the 2010 UN-Habitat publication (Scheinberg A, Wilson DC and Rodic L (2010) Solid Waste Management in the World's Cities. UN-Habitat's Third Global Report on the State of Water and Sanitation in the World's Cities. Newcastle-on-Tyne, UK: Earthscan Publications). Data from these cities and others provides the basis for developing a new tool to analyse inclusive recycling performance. The points of departure are the institutional and economic relationships between the service chain, the public obligation to remove waste, pollution, and other forms of disvalue, and the value chain, a system of private enterprises trading valuable materials and providing markets for recyclables. The methodological innovation is to use flows of materials and money as indicators of institutional relationships, and is an extension of process flow diagramming.The authors are using the term 'recycling framework analysis' to describe this new form of institutional analysis. The diagrams increase our understanding of the factors that contribute to high-performance inclusive recycling. By focusing on institutional relationships, the article seeks to improve analysis, planning, and ultimately, outcomes, of recycling interventions. PMID:26416850

  9. Recycling of electric-arc-furnace dust

    SciTech Connect

    Sresty, G.C.

    1990-05-01

    Electric arc furnace (EAF) dust is one of the largest solid waste streams produced by steel mills, and is classified as a waste under the Resource Conservation and Recovery Act (RCRA) by the U.S. Environmental Protection Agency (EPA). Successful recycle of the valuable metals (iron, zinc, and lead) present in the dust will result in resource conservation while simultaneously reducing the disposal problems. Technical feasibility of a novel recycling method based on using hydrogen as the reductant was established under this project through laboratory experiments. Sponge iron produced was low in zinc, cadmium, and lead to permit its recycle, and nontoxic to permit its safe disposal as an alternative to recycling. Zinc oxide was analyzed to contain 50% to 58% zinc by weight, and can be marketed for recovering zinc and lead. A prototype system was designed to process 2.5 tons per day (600 tons/year) of EAF dust, and a preliminary economic analysis was conducted. The cost of processing dust by this recycling method was estimated to be comparable to or lower than existing methods, even at such low capacities.

  10. Adsorption of lead ions on composite biopolymer adsorbent

    SciTech Connect

    Seki, Hideshi; Suzuki, Akira

    1996-04-01

    A fundamental study about the application of biopolymers to the recovery of lead from dilute solution was carried out. A membranous composite biopolymer adsorbent containing two kind of biopolymers, alginic acid (AA) and humic acid (HA), was prepared. HA, which has high solubility in water, was almost completely immobilized in the adsorbent by a combination of calcium alginate gel and activated carbon powder. A general model for complexation between divalent metal ions and acidic sites on biopolymers was applied to explain the adsorption mechanism of lead on the adsorbent (HA-M). The results showed that the complexation constants and the complexation capacities of lead-AA and lead-HA systems were scarcely influenced by immobilization.

  11. Activated carbon adsorbents from waste tires for air quality control

    SciTech Connect

    Lehmann, C.M.B.; Rostam-Abadi, M.; Rood, M.J.; Hsi, H.C.

    1999-07-01

    This study evaluates methodologies for utilizing waste tire rubber to produce carbonaceous adsorbents for use in air quality control operations. Such an approach provides a two-fold environmental and economic benefit. A recycling path is developed for waste tire rubber and new adsorbents are produced from a low cost feedstock for use in environmentally-related operations. Bench-scale and pilot-scale quantities of tire-derived activated carbon (TDAC) were produced from waste tire rubber. Raw tire rubber samples and devolatilized tire char were obtained from several US vendors. The raw samples were analyzed using proximate, ultimate, and elemental analyses. Batches of activated carbon samples were prepared using a bench-scale fixed-tubular reactor to prepare {approximately}10 g samples and a fluidized-bed reactor to prepare {approximately}100 g quantities. About 25 kg of activated carbon was also produced at a pilot-scale commercial facility. The resulting TDACs were then characterized by nitrogen adsorption at 77K. The sample surface areas were determined by the BET method, and the pore size distribution (PSD) was evaluated using the BJH model, and a 3-D PSD model. Performance of the TDACs was evaluated in their ability to remove gaseous mercury species from simulated power-plant flue-gas streams, and for the removal of organic compounds (e.g., acetone and 1,1,1-trichloroethane) from flowing gas streams.

  12. Processing solid propellants for recycling

    SciTech Connect

    Whinnery, L.L.; Griffiths, S.K.; Handrock, J.L.; Lipkin, J.

    1994-05-01

    Rapid evolution in the structure of military forces worldwide is resulting in the retirement of numerous weapon systems. Many of these systems include rocket motors containing highly energetic propellants based on hazardous nitrocellulose/nitroglycerin (NC/NG) mixtures. Even as the surplus quantities of such material increases, however, current disposal methods -- principally open burning and open detonation (OB/OD) -- are coming under close scrutiny from environmental regulators. Environmentally conscious alternatives to disposal of propellant and explosives are thus receiving renewed interest. Recycle and reuse alternatives to OB/OD appear particularly attractive because some of the energetic materials in the inventories of surplus weapon systems represent potentially valuable resources to the commercial explosives and chemical industries. The ability to reclaim such resources is therefore likely to be a key requirement of any successful technology of the future in rocket motor demilitarization. This document consists of view graphs from the poster session.

  13. Scrap uranium recycling via electron beam melting

    SciTech Connect

    McKoon, R.

    1993-11-01

    A program is underway at the Lawrence Livermore National Laboratory (LLNL) to recycle scrap uranium metal. Currently, much of the material from forging and machining processes is considered radioactive waste and is disposed of by oxidation and encapsulation at significant cost. In the recycling process, uranium and uranium alloys in various forms will be processed by electron beam melting and continuously cast into ingots meeting applicable specifications for virgin material. Existing vacuum processing facilities at LLNL are in compliance with all current federal and state environmental, safety and health regulations for the electron beam melting and vaporization of uranium metal. One of these facilities has been retrofitted with an auxiliary electron beam gun system, water-cooled hearth, crucible and ingot puller to create an electron beam melt furnace. In this furnace, basic process R&D on uranium recycling will be performed with the goal of eventual transfer of this technology to a production facility.

  14. A novel fiber-based adsorbent technology

    SciTech Connect

    Reynolds, T.A.

    1997-10-01

    In this Phase I Small Business Innovation Research program, Chemica Technologies, Inc. is developing an economical, robust, fiber-based adsorbent technology for removal of heavy metals from contaminated water. The key innovation is the development of regenerable adsorbent fibers and adsorbent fiber cloths that have high capacity and selectivity for heavy metals and are chemically robust. The process has the potential for widespread use at DOE facilities, mining operations, and the chemical process industry.

  15. COPPER CABLE RECYCLING TECHNOLOGY

    SciTech Connect

    Chelsea Hubbard

    2001-05-01

    The United States Department of Energy (DOE) continually seeks safer and more cost-effective technologies for use in deactivation and decommissioning (D&D) of nuclear facilities. The Deactivation and Decommissioning Focus Area (DDFA) of the DOE's Office of Science and Technology (OST) sponsors large-scale demonstration and deployment projects (LSDDPs). At these LSDDPs, developers and vendors of improved or innovative technologies showcase products that are potentially beneficial to the DOE's projects and to others in the D&D community. Benefits sought include decreased health and safety risks to personnel and the environment, increased productivity, and decreased costs of operation. The Idaho National Engineering and Environmental Laboratory (INEEL) generated a list of statements defining specific needs and problems where improved technology could be incorporated into ongoing D&D tasks. One such need is to reduce the volume of waste copper wire and cable generated by D&D. Deactivation and decommissioning activities of nuclear facilities generates hundreds of tons of contaminated copper cable, which are sent to radioactive waste disposal sites. The Copper Cable Recycling Technology separates the clean copper from contaminated insulation and dust materials in these cables. The recovered copper can then be reclaimed and, more importantly, landfill disposal volumes can be reduced. The existing baseline technology for disposing radioactively contaminated cables is to package the cables in wooden storage boxes and dispose of the cables in radioactive waste disposal sites. The Copper Cable Recycling Technology is applicable to facility decommissioning projects at many Department of Energy (DOE) nuclear facilities and commercial nuclear power plants undergoing decommissioning activities. The INEEL Copper Cable Recycling Technology Demonstration investigated the effectiveness and efficiency to recycle 13.5 tons of copper cable. To determine the effectiveness of separating

  16. Quasiparticle excitations of adsorbates on doped graphene

    NASA Astrophysics Data System (ADS)

    Lischner, Johannes; Wickenburg, Sebastian; Wong, Dillon; Karrasch, Christoph; Wang, Yang; Lu, Jiong; Omrani, Arash A.; Brar, Victor; Tsai, Hsin-Zon; Wu, Qiong; Corsetti, Fabiano; Mostofi, Arash; Kawakami, Roland K.; Moore, Joel; Zettl, Alex; Louie, Steven G.; Crommie, Mike

    Adsorbed atoms and molecules can modify the electronic structure of graphene, but in turn it is also possible to control the properties of adsorbates via the graphene substrate. In my talk, I will discuss the electronic structure of F4-TCNQ molecules on doped graphene and present a first-principles based theory of quasiparticle excitations that captures the interplay of doping-dependent image charge interactions between substrate and adsorbate and electron-electron interaction effects on the molecule. The resulting doping-dependent quasiparticle energies will be compared to experimental scanning tunnelling spectra. Finally, I will also discuss the effects of charged adsorbates on the electronic structure of doped graphene.

  17. Optimization of electron cooling in the Recycler

    SciTech Connect

    Shemyakin, A.; Burov, A.; Carlson, K.; Prost, L.R.; Sutherland, M.; Warner, A.; /Fermilab

    2009-04-01

    Antiprotons in Fermilab's Recycler ring are cooled by a 4.3 MeV, 0.1A DC electron beam (as well as by a stochastic cooling system). The paper describes electron cooling improvements recently implemented: adjustments of electron beam line quadrupoles to decrease the electron angles in the cooling section and better stabilization and control of the electron energy.

  18. Process design and solvent recycle for the supercritical Fischer-Tropsch synthesis

    SciTech Connect

    Wensheng Linghu; Xiaohong Li; Kenji Asami; Kaoru Fujimoto

    2006-02-01

    A recycle reactor system for supercritical Fischer-Tropsch synthesis was successfully designed and tested. The new reactor system has these characteristics: (1) integration of supercritical Fischer-Tropsch reactions, natural separation of produced wax from liquid phase, and recycle of the solvent and (2) natural recycle of solvent driven by self-gravity. A 20% Co/SiO{sub 2} catalyst and n-hexane were used as a catalyst and supercritical fluid, respectively. The results show that the average CO conversion at the steady state was 45% with recycle and 58% without recycle. The lumped hydrocarbon products distribution did not have any obvious difference between with and without recycle operation; however, {alpha}-olefin content of products with recycle was lower than that without recycle. The XRD result indicates that most of the reduced cobalt remains in the metallic state during the Fischer-Tropsch reactions for both cases. 22 refs., 3 figs., 1 tab.

  19. Solid waste characterization and recycling potential for a university campus

    SciTech Connect

    Armijo de Vega, Carolina Ojeda Benitez, Sara; Ramirez Barreto, Ma. Elizabeth

    2008-07-01

    Integrated waste management systems are one of the greatest challenges for sustainable development. For these systems to be successful, the first step is to carry out waste characterization studies. In this paper are reported the results of a waste characterization study performed in the Campus Mexicali I of the Autonomous University of Baja California (UABC). The aim of this study was to set the basis for implementation of a recovery, reduction and recycling waste management program at the campus. It was found that the campus Mexicali I produces 1 ton of solid wastes per day; more than 65% of these wastes are recyclable or potentially recyclable. These results showed that a program for segregation and recycling is feasible on a University Campus. The study also showed that the local market for recyclable waste, under present conditions - number of recycling companies and amounts of recyclables accepted - can absorb all of these wastes. Some alternatives for the potentially recyclables wastes are discussed. Finally some strategies that could be used to reduce waste at the source are discussed as well.

  20. Municipal solid waste recycling issues

    SciTech Connect

    Lave, L.B.; Hendrickson, C.T.; Conway-Schempf, N.M.; McMichael, F.C.

    1999-10-01

    Municipal solid waste (MSW) recycling targets have been set nationally and in many states. Unfortunately, the definitions of recycling, rates of recycling, and the appropriate components of MSW vary. MSW recycling has been found to be costly for most municipalities compared to landfill disposal. MSW recycling policy should be determined by the cost to the community and to society more generally. In particular, recycling is a good policy only if environmental impacts and the resources used to collect, sort, and recycle a material are less than the environmental impacts and resources needed to provide equivalent virgin material plus the resources needed to dispose of the postconsumer material safely. From a review of the existing economic experience with recycling and an analysis of the environmental benefits (including estimation of external social costs), the authors find that, for most communities, curbside recycling is only justifiable for some postconsumer waste, such as aluminum and other metals. They argue that alternatives to curbside recycling collection should be explored, including product takeback for products with a toxic content (such as batteries) or product redesign to permit more effective product remanufacture.

  1. Hydroponic Crop Production using Recycled Nutrients from Inedible Crop Residues

    NASA Technical Reports Server (NTRS)

    Garland, Jay L.; Mackowiak, Cheryl L.; Sager, John C.

    1993-01-01

    The coupling of plant growth and waste recycling systems is an important step toward the development of bioregenerative life support systems. This research examined the effectiveness of two alternative methods for recycling nutrients from the inedible fraction (residue) of candidate crops in a bioregenerative system as follows: (1) extraction in water, or leaching, and (2) combustion at 550 C, with subsequent reconstitution of the ash in acid. The effectiveness of the different methods was evaluated by (1) comparing the percent recovery of nutrients, and (2) measuring short- and long-term plant growth in hydroponic solutions, based on recycled nutrients.

  2. Recycling rubber wastes. (Latest citations from the Rubber and Plastics Research Association database). Published Search

    SciTech Connect

    1996-04-01

    The bibliography contains citations concerning research and innovations in the recycling of rubber wastes. Recycling methods and equipment, applications of recycled rubber, and energy recovery systems and performance are among the topics discussed. Recycling methods compared and contrasted with various rubber waste disposal techniques are also included. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. Recycling of 3He from lung magnetic resonance imaging.

    PubMed

    Salhi, Z; Grossmann, T; Gueldner, M; Heil, W; Karpuk, S; Otten, E W; Rudersdorf, D; Surkau, R; Wolf, U

    2012-06-01

    We have developed the means to recycle (3) He exhaled by patients after imaging the lungs using magnetic resonance of hyperpolarized (3) He. The exhaled gas is collected in a helium leak proof bag and further compressed into a steel bottle. The collected gas contains about 1-2% of (3) He, depending on the amount administered and the number of breaths collected to wash out the (3) He gas from the lungs. (3) He is separated from the exhaled air using zeolite molecular sieve adsorbent at 77 K followed by a cold head at 8 K. Residual gaseous impurities are finally absorbed by a commercial nonevaporative getter. The recycled (3) He gas features high purity, which is required for repolarization by metastability exchange optical pumping. At present, we achieve a collection efficiency of 80-84% for exhaled gas from healthy volunteers and cryogenic separation efficiency of 95%. PMID:22135249

  4. Experimental characterization of adsorbed protein orientation, conformation, and bioactivity.

    PubMed

    Thyparambil, Aby A; Wei, Yang; Latour, Robert A

    2015-01-01

    Protein adsorption on material surfaces is a common phenomenon that is of critical importance in many biotechnological applications. The structure and function of adsorbed proteins are tightly interrelated and play a key role in the communication and interaction of the adsorbed proteins with the surrounding environment. Because the bioactive state of a protein on a surface is a function of the orientation, conformation, and accessibility of its bioactive site(s), the isolated determination of just one or two of these factors will typically not be sufficient to understand the structure-function relationships of the adsorbed layer. Rather a combination of methods is needed to address each of these factors in a synergistic manner to provide a complementary dataset to characterize and understand the bioactive state of adsorbed protein. Over the past several years, the authors have focused on the development of such a set of complementary methods to address this need. These methods include adsorbed-state circular dichroism spectropolarimetry to determine adsorption-induced changes in protein secondary structure, amino-acid labeling/mass spectrometry to assess adsorbed protein orientation and tertiary structure by monitoring adsorption-induced changes in residue solvent accessibility, and bioactivity assays to assess adsorption-induced changes in protein bioactivity. In this paper, the authors describe the methods that they have developed and/or adapted for each of these assays. The authors then provide an example of their application to characterize how adsorption-induced changes in protein structure influence the enzymatic activity of hen egg-white lysozyme on fused silica glass, high density polyethylene, and poly(methyl-methacrylate) as a set of model systems. PMID:25708632

  5. Experimental characterization of adsorbed protein orientation, conformation, and bioactivity

    PubMed Central

    Thyparambil, Aby A.; Wei, Yang; Latour, Robert A.

    2015-01-01

    Protein adsorption on material surfaces is a common phenomenon that is of critical importance in many biotechnological applications. The structure and function of adsorbed proteins are tightly interrelated and play a key role in the communication and interaction of the adsorbed proteins with the surrounding environment. Because the bioactive state of a protein on a surface is a function of the orientation, conformation, and accessibility of its bioactive site(s), the isolated determination of just one or two of these factors will typically not be sufficient to understand the structure–function relationships of the adsorbed layer. Rather a combination of methods is needed to address each of these factors in a synergistic manner to provide a complementary dataset to characterize and understand the bioactive state of adsorbed protein. Over the past several years, the authors have focused on the development of such a set of complementary methods to address this need. These methods include adsorbed-state circular dichroism spectropolarimetry to determine adsorption-induced changes in protein secondary structure, amino-acid labeling/mass spectrometry to assess adsorbed protein orientation and tertiary structure by monitoring adsorption-induced changes in residue solvent accessibility, and bioactivity assays to assess adsorption-induced changes in protein bioactivity. In this paper, the authors describe the methods that they have developed and/or adapted for each of these assays. The authors then provide an example of their application to characterize how adsorption-induced changes in protein structure influence the enzymatic activity of hen egg-white lysozyme on fused silica glass, high density polyethylene, and poly(methyl-methacrylate) as a set of model systems. PMID:25708632

  6. Ultrasensitive, Specific, Recyclable, and Reproducible Detection of Lead Ions in Real Systems through a Polyadenine-Assisted, Surface-Enhanced Raman Scattering Silicon Chip.

    PubMed

    Shi, Yu; Wang, Houyu; Jiang, Xiangxu; Sun, Bin; Song, Bin; Su, Yuanyuan; He, Yao

    2016-04-01

    It is of great significance to accurately and reliably detect trace lead(II) (Pb(2+)) ions, preferably at sub-nM level due to the possible long-term accumulation of Pb(2+) in the human body, which may cause serious threats to human health. However, a suitable Pb(2+) sensor meeting the demands is still scanty. Herein, we develop a polyadenine-assisted, surface-enhanced Raman scattering (SERS) silicon chip (0.5 cm × 0.5 cm) composed of core (Ag)-satellite (Au) nanoparticles (Ag-Au NPs)-decorated silicon wafers (Ag-Au NPs@Si) for high-performance Pb(2+) detection. Typically, strong SERS signals could be measured when DNAzyme conjugated on the SERS silicon chip is specifically activated by Pb(2+), cleaving the substrate strand into two free DNA strands. A good linearity exists between the normalized Raman intensities and the logarithmic concentrations of Pb(2+) ranging from 10 pM to 1 μM with a good correlation coefficient, R(2) of 0.997. Remarkably, Pb(2+) ions with a low concentration of 8.9 × 10(-12) M can be readily determined via the SERS silicon chip ascribed to its superior SERS enhancement, much lower than those (∼nM) reported by other SERS sensors. Additionally, the developed chip features good selectivity and recyclability (e.g., ∼11.1% loss of Raman intensity after three cycles). More importantly, the as-prepared chip can be used for accurate and reliable determination of unknown Pb(2+) ions in real systems including lake water, tap water and industrial wastewater, with the RSD value less than 12%. PMID:26923545

  7. A novel approach to recycle bacterial culture waste for fermentation reuse via a microbial fuel cell-membrane bioreactor system.

    PubMed

    Li, Jian; Zhu, Yuan; Zhuang, Liangpeng; Otsuka, Yuichiro; Nakamura, Masaya; Goodell, Barry; Sonoki, Tomonori; He, Zhen

    2015-09-01

    Biochemical production processes require water and nutrient resources for culture media preparation, but aqueous waste is generated after the target products are extracted. In this study, culture waste (including cells) produced from a lab-scale fermenter was fed into a microbial fuel cell-membrane bioreactor (MFC-MBR) system. Electrical energy was generated via the interaction between the microbial consortia and the solid electrode in the MFC. The treated wastewater was reclaimed in this process which was reused as a solvent and a nutrient source in subsequent fermentation. Polarization testing showed that the MFC produced a maximum current density of 37.53 A m(-3) with a maximum power density of 5.49 W m(-3). The MFC was able to generate 0.04 kWh of energy per cubic meter of culture waste treated. The lab-scale fermenters containing pure cultures of an engineered Pseudomonas spp. were used to generate 2-pyrone-4,6-dicarboxylic acid (PDC), a high value platform chemical. When the MFC-MBR-treated wastewater was used for the fermenter culture medium, a specific bacterial growth rate of 1.00 ± 0.05 h(-1) was obtained with a PDC production rate of 708.11 ± 64.70 mg PDC L(-1) h(-1). Comparable values for controls using pure water were 0.95 ± 0.06 h(-1) and 621.01 ± 22.09 mg PDC L(-1) h(-1) (P > 0.05), respectively. The results provide insight on a new approach for more sustainable bio-material production while at the same time generating energy, and suggest that the treated wastewater can be used as a solvent and a nutrient source for the fermentation production of high value platform chemicals. PMID:26013992

  8. Complete braided adsorbent for marine testing to demonstrate 3g-U/kg-adsorbent

    SciTech Connect

    Janke, Chris; Yatsandra, Oyola; Mayes, Richard; none,; Gill, Gary; Li-Jung, Kuo; Wood, Jordana; Sadananda, Das

    2014-04-30

    ORNL has manufactured four braided adsorbents that successfully demonstrated uranium adsorption capacities ranging from 3.0-3.6 g-U/kg-adsorbent in marine testing at PNNL. Four new braided and leno woven fabric adsorbents have also been prepared by ORNL and are currently undergoing marine testing at PNNL.

  9. Understanding recycling behavior in Kentucky: Who recycles and why

    NASA Astrophysics Data System (ADS)

    Morgan, Fred W.; Hughes, Margaret V.

    2006-08-01

    Recycling behavior and the motivations behind recycling are being analyzed in a collaborative study between the Sloan Industry Center for a Sustainable Aluminum Industry, the Center for Aluminum Technology, Secat, and the Gatton College of Business and Economics at the University of Kentucky in Lexington. The goals of this study are to determine why people recycle and to find ways to motivate people to recycle more, using Fayette County, Kentucky, as a sample study. It is hoped that the information gathered through educational and motivational efforts in this county can be used on a larger scale in communities throughout the United States.

  10. Why recycle? A comparison of recycling motivations in four communities

    NASA Astrophysics Data System (ADS)

    Vining, Joanne; Linn, Nancy; Burdge, Rabel J.

    1992-11-01

    Four Illinois communities with different sociode-mographic compositions and at various stages of planning for solid waste management were surveyed to determine the influence of sociodemographic variables and planning stages on the factors that motivate recycling behavior. A factor analysis of importance ratings of reasons for recycling and for not recycling yielded five factors interpreted as altruism, personal inconvenience, social influences, economic incentives, and household storage. The four communities were shown to be significantly different in multivariate analyses of the five motivational factors. However, attempts to explain these community differences with regression analyses, which predicted the motivational factors with dummy codes for planning stages, a measure of self-reported recycling behavior, and sociodemographic measures were unsatisfactory. Contrary to expectation, the solid waste management planning stages of the cities (curbside pickup, recycling dropoff center, and planning in progress) contributed only very slightly to the prediction of motivational factors for recycling. Community differences were better explained by different underlying motivational structures among the four communities. Altruistic reasons for recycling (e.g., conserving resources) composed the only factor which was similar across the four communities. This factor was also perceived to be the most important reason for recycling by respondents from all four communities. The results of the study supported the notion that convenient, voluntary recycling programs that rely on environmental concern and conscience for motivation are useful approaches to reducing waste.

  11. Current organic waste recycling and the potential for local recycling through urban agriculture in Metro Manila.

    PubMed

    Hara, Yuji; Furutani, Takashi; Murakami, Akinobu; Palijon, Armando M; Yokohari, Makoto

    2011-11-01

    Using the solid waste management programmes of three barangays (the smallest unit of local government in the Philippines) in Quezon City, Metro Manila, as a case study, this research aimed to further the development of efficient organic waste recycling systems through the promotion of urban agricultural activities on green and vacant spaces. First, the quantity of organic waste and compost produced through ongoing barangay projects was measured. The amount of compost that could potentially be utilized on farmland and vacant land within the barangays was then identified to determine the possibility of a local recycling system. The results indicate that, at present, securing buyers for compost is difficult and, therefore, most compost is distributed to large neighbouring farm villages. However, the present analysis of potential compost use within the barangay demonstrates that a more local compost recycling system is indeed feasible. PMID:20952443

  12. Waste recycling issues in bioregenerative life support

    NASA Technical Reports Server (NTRS)

    Macelroy, R. D.; Wang, D.

    1989-01-01

    Research and technology development issues centering on the recycling of materials within a bioregenerative life support system are reviewed. The importance of recovering waste materials for subsequent use is emphasized. Such material reclamation will substantially decrease the energy penalty paid for bioregenerative life support systems, and can potentially decrease the size of the system and its power demands by a significant amount. Reclamation of fixed nitrogen and the sugars in cellulosic materials is discussed.

  13. Conveyor Cultivation of the Halophytic Plant Salicornia europaea for the Recycling of NaCl from Human Liquid Waste in a Biological Life Support System.

    NASA Astrophysics Data System (ADS)

    Balnokin, Yurii; Myasoedov, Nikolay; Popova, Larissa; Tikhomirov, Alexander A.; Ushakova, Sofya; Tikhomirova, Natalia; Lasseur, Christophe; Gros, Jean-Bernard

    One problem in designing bioregenerative life support systems (BLSS) is developing technolo-gies to include human liquid and solid waste in intrasystem recycling. A specific task is recycling of NaCl excreted in urine by humans. We showed recently that this could be achieved through inclusion of the salt accumulating halophyte Salicornia europaea in the autotrophic compart-ment of the BLSS (Balnokin et al., ASR, 2010, in press). A model of NaCl circulation in BLSS with inclusion of S. europaea was based on the NaCl turnover in the human -urine -nutrient solution -S. europaea -human cycle. Mineralized urine was used as a basis for preparation of a nutrient solution for the halophyte cultivation. The shoots of the halophyte cultivated in the mineralized urine and containing NaCl could to be used by the BLSS inhabitants in their diets. In this report we describe cultivation of S. europaea which allows turnover of NaCl and produces daily shoot biomass containing Na+ and Cl- in quantities approximately equal to those excreted in daily human urine. The plants were grown in water culture in a climatic chamber under controlled conditions. A solution simulating mineralized urine (SSMU) was used as a basis for preparation of a nutri-ent solution for S. europaea cultivation. For continuous biomass production, seedlings of S. europaea, germinated preliminary in moist sand, were being transferred to the nutrient solu-tion at regular intervals (every two days). Duration of the conveyor operation was 112 days. During the first 56 days, the seedlings were being planted in SSMU diluted by a factor of 1.5 (2/3 SSMU). The same solution was introduced into the growth vessels as volumes of growth medium decreased due to plant transpiration. Starting from the 56th day as conveyor operation was initiated, the plants were being harvested every two days; the solutions from the discharged vessels were mixed with the fresh SSMU and the mixture was introduced into all other growth vessels of

  14. Establishing components of community satisfaction with recycled water use through a structural equation model.

    PubMed

    Hurlimann, Anna; Hemphill, Elizabeth; McKay, Jennifer; Geursen, Gus

    2008-09-01

    The use of recycled water is being promoted through policy in many parts of the world with the aim of achieving sustainable water management. However there are some major barriers to the success of recycled water use policies and their instruments, in particular for potable reuse schemes. One of these barriers can be a lack of community support. Despite the critical nature of community attitudes to recycled water to the success of projects, they are often little understood. Further information is required to ensure the successful implementation of recycled water policy and to ensure sustainable management of water resources is achieved. The aim of this paper is to establish the key components of community satisfaction with recycled water. This was investigated through a case study of the Mawson Lakes population in South Australia, where recycled water is used for non-potable purposes through a dual water supply system (the 'recycled water system'). This paper reports results from a survey of 162 Mawson Lakes residents. A structural equation model (SEM) was developed and tested to explain and predict components of community satisfaction with recycled water use (for non-potable use) through the dual water supply system. Results indicate the components of satisfaction with recycled water use were an individual's positive perception of: the Water Authority's communication, trust in the Water Authority, fairness in the recycled water system's implementation, quality of the recycled water, financial value of the recycled water system, and risk associated with recycled water use (negative relationship). The results of this study have positive implications for the future management and implementation of recycled water projects in particular through dual water supply systems. The results indicate to water authorities and water policy developers guiding principles for community consultation with regards to the management of recycled water projects. PMID:17662519

  15. Lead recycling in the United States in 1998

    USGS Publications Warehouse

    Smith, Gerald R.

    2001-01-01

    This materials flow study includes a description of lead supply and demand factors for the United States to illustrate the extent of lead recycling and to identify recycling trends. Understanding the system of materials flow from source to ultimate disposition can assist in improving the management of the use of natural resources in a manner that is compatible with sound environmental practices. The quantity of lead recycled in 1998, as a percentage of apparent lead supply, was estimated to be about 63%, and recycling efficiency, to be 95%. Of the total lead consumed in products for the U.S. market in 1998, an estimated 10% was consumed in products in which the lead was not readily recyclable.

  16. Lead recycling in the United States in 1998

    USGS Publications Warehouse

    Smith, Gerald R.

    2002-01-01

    This materials flow study includes a description of lead supply and demand factors for the United States to illustrate the extent of lead recycling and to identify recycling trends. Understanding the system of materials flow from source to ultimate disposition can assist in improving the management of the use of natural resources in a manner that is compatible with sound environmental practices. The quantity of lead recycled in 1998, as a percentage of apparent lead supply, was estimated to be about 63 percent, and recycling efficiency, to be 95 percent. Of the total lead consumed in products for the U.S. market in 1998, an estimated 10 percent was consumed in products in which the lead was not readily recyclable.

  17. Fluorescence dynamics of microsphere-adsorbed sunscreens

    NASA Astrophysics Data System (ADS)

    Krishnan, R.

    2005-03-01

    Sunscreens are generally oily substances which are prepared in organic solvents, emulsions or dispersions with micro- or nanoparticles. These molecules adsorb to and integrate into skin cells. In order to understand the photophysical properties of the sunscreen, we compare steady-state and time-resolved fluorescence in organic solvent of varying dielectric constant ɛ and adsorbed to polystyrene microspheres and dispersed in water. Steady-state fluorescence is highest and average fluorescence lifetime longest in toluene, the solvent of lowest ɛ. However, there is no uniform dependence on ɛ. Sunscreens PABA and padimate-O show complex emission spectra. Microsphere-adsorbed sunscreens exhibit highly non-exponential decay, illustrative of multiple environments of the adsorbed molecule. The heterogeneous fluorescence dynamics likely characterizes sunscreen adsorbed to cells.

  18. Nanovalved Adsorbents for CH4 Storage.

    PubMed

    Song, Zhuonan; Nambo, Apolo; Tate, Kirby L; Bao, Ainan; Zhu, Minqi; Jasinski, Jacek B; Zhou, Shaojun J; Meyer, Howard S; Carreon, Moises A; Li, Shiguang; Yu, Miao

    2016-05-11

    A novel concept of utilizing nanoporous coatings as effective nanovalves on microporous adsorbents was developed for high capacity natural gas storage at low storage pressure. The work reported here for the first time presents the concept of nanovalved adsorbents capable of sealing high pressure CH4 inside the adsorbents and storing it at low pressure. Traditional natural gas storage tanks are thick and heavy, which makes them expensive to manufacture and highly energy-consuming to carry around. Our design uses unique adsorbent pellets with nanoscale pores surrounded by a coating that functions as a valve to help manage the pressure of the gas and facilitate more efficient storage and transportation. We expect this new concept will result in a lighter, more affordable product with increased storage capacity. The nanovalved adsorbent concept demonstrated here can be potentially extended for the storage of other important gas molecules targeted for diverse relevant functional applications. PMID:27124722

  19. NOx adsorber and method of regenerating same

    SciTech Connect

    Endicott, Dennis L.; Verkiel, Maarten; Driscoll, James J.

    2007-01-30

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  20. Structural characterization of adsorbed helical and beta-sheet peptides

    NASA Astrophysics Data System (ADS)

    Samuel, Newton Thangadurai

    Adsorbed peptides on surfaces have potential applications in the fields of biomaterials, tissue engineering, peptide microarrays and nanobiotechnology. The surface region, the "biomolecular interface" between a material and the biological environment, plays a crucial role in these applications. As a result, characterization of adsorbed peptide structure, especially with respect to identity, concentration, spatial distribution, conformation and orientation, is important. The present research employs NEXAFS (near-edge X-ray absorption fine structure spectroscopy) and SFG (sum frequency generation spectroscopy) to provide information about the adsorbed peptide structure. Soft X-ray NEXAFS is a synchrotron-based technique which typically utilizes polarized X-rays to interrogate surfaces under ultra-high vacuum conditions. SFG is a non-linear optical technique which utilizes a combination of a fixed visible and a tunable infrared laser beams to generate a surface-vibrational spectrum of surface species. SFG has the added advantage of being able to directly analyze the surface-structure at the solid-liquid interface. The main goals of the present research were twofold: characterize the structure of adsorbed peptides (1) ex situ using soft X-ray NEXAFS, and (2) in situ using non-linear laser spectroscopy (SFG). Achieving the former goal involved first developing a comprehensive characterization of the carbon, nitrogen and oxygen k-edge NEXAFS spectra for amino acids, and then using a series of helical and beta-sheet peptides to demonstrate the sensitivity of polarization-dependent NEXAFS to secondary structure of adsorbed peptides. Characterizing the structure of adsorbed peptides in situ using SFG involved developing a model system to probe the solid-liquid interface in situ; demonstrating the ability to probe the molecular interactions and adsorbed secondary structure; following the time-dependent ordering of the adsorbed peptides; and establishing the ability to obtain

  1. Emulsified industrial oils recycling

    SciTech Connect

    Gabris, T.

    1982-04-01

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  2. Recent trends in automobile recycling: An energy and economic assessment

    SciTech Connect

    Curlee, T.R.; Das, S.; Rizy, C.G.; Schexanyder, S.M.

    1994-03-01

    Recent and anticipated trends in the material composition of domestic and imported automobiles and the increasing cost of landfilling the non-recyclable portion of automobiles (automobile shredder residue or ASR) pose questions about the future of automobile recycling. This report documents the findings of a study sponsored by the US Department of Energy`s Office of Environmental Analysis to examine the impacts of these and other relevant trends on the life-cycle energy consumption of automobiles and on the economic viability of the domestic automobile recycling industry. More specifically, the study (1) reviewed the status of the automobile recycling industry in the United States, including the current technologies used to process scrapped automobiles and the challenges facing the automobile recycling industry; (2) examined the current status and future trends of automobile recycling in Europe and Japan, with the objectives of identifying ``lessons learned`` and pinpointing differences between those areas and the United States; (3) developed estimates of the energy system impacts of the recycling status quo and projections of the probable energy impacts of alternative technical and institutional approaches to recycling; and (4) identified the key policy questions that will determine the future economic viability of automobile shredder facilities in the United States.

  3. REGULATIONS ON PHOTOVOLTAIC MODULE DISPOSAL AND RECYCLING.

    SciTech Connect

    FTHENAKIS,V.

    2001-01-29

    Environmental regulations can have a significant impact on product use, disposal, and recycling. This report summarizes the basic aspects of current federal, state and international regulations which apply to end-of-life photovoltaic (PV) modules and PV manufacturing scrap destined for disposal or recycling. It also discusses proposed regulations for electronics that may set the ground of what is to be expected in this area in the near future. In the US, several states have started programs to support the recycling of electronic equipment, and materials destined for recycling often are excepted from solid waste regulations during the collection, transfer, storage and processing stages. California regulations are described separately because they are different from those of most other states. International agreements on the movement of waste between different countries may pose barriers to cross-border shipments. Currently waste moves freely among country members of the Organization of Economic Cooperation and Development (OECD), and between the US and the four countries with which the US has bilateral agreements. However, it is expected, that the US will adopt the rules of the Basel Convention (an agreement which currently applies to 128 countries but not the US) and that the Convection's waste classification system will influence the current OECD waste-handling system. Some countries adopting the Basel Convention consider end-of-life electronics to be hazardous waste, whereas the OECD countries consider them to be non-hazardous. Also, waste management regulations potentially affecting electronics in Germany and Japan are mentioned in this report.

  4. Recycled rubber roads

    SciTech Connect

    Not Available

    1989-02-01

    The paper describes several innovative approaches for recycling old tires in the construction of roads. In one, 18 inches of shredded tire chips (2 X 2 inches) were used on top of 6-8 inches of small stone to construct a road across a sanitary landfill. No compacting or linders were needed. In another application, sidewall mats linked together with steel strapping were used as a sub-base for a road across a swampy area. A third application uses 1/2 inch bits of groundup rubber tires as a replacement for aggregate in an asphalt road base.

  5. Separation of the attractive and repulsive contributions to the adsorbate-adsorbate interactions of polar adsorbates on Si(100)

    NASA Astrophysics Data System (ADS)

    Lin, Ying-Hsiu; Jeng, Horng-Tay; Lin, Deng-Sung

    2015-11-01

    Dissociative adsorption of H2O, NH3, CH3OH and CH3NH2 polar molecules on the Si(100) surface results in a 1:1 mixture of two adsorbates (H and multi-atomic fragment A = OH, NH2, CH3O, CH3NH, respectively) on the surface. By using density functional theory (DFT) calculations, the adsorption geometry, the total energies and the charge densities for various possible ordered structures of the mixed adsorbate layer have been found. Analyzing the systematic trends in the total energies unveils concurrently the nearest-neighbor interactions ENN and the next nearest-neighbor interactions ENNN between two polar adsorbates A. In going from small to large polar adsorbates, ENN's exhibit an attractive-to-repulsive crossover behavior, indicating that they include competing attractive and repulsive contributions. Exploration of the charge density distributions allows the estimation of the degree of charge overlapping between immediately neighboring A's, the resulting contribution of the steric repulsions, and that of the attractive interactions to the corresponding ENN's. The attractive contributions to nearest neighboring adsorbate-adsorbate interactions between the polar adsorbates under study are shown to result from hydrogen bonds or dipole-dipole interactions.

  6. Adsorbate-metal bond effect on empirical determination of surface plasmon penetration depth.

    PubMed

    Kegel, Laurel L; Menegazzo, Nicola; Booksh, Karl S

    2013-05-21

    The penetration depth of surface plasmons is commonly determined empirically from the observed response for adsorbate loading on gold surface plasmon resonance (SPR) substrates. However, changes in the SPR spectrum may originate from both changes in the effective refractive index near the metal surface and changes in the metal permittivity following covalent binding of the adsorbate layer. Herein, the significance of incorporating an additional adsorbate-metal bonding effect in the calculation is demonstrated in theory and in practice. The bonding effect is determined from the nonzero intercept of a SPR shift versus adsorbate thickness calibration and incorporated into the calculation of penetration depth at various excitation wavelengths. Determinations of plasmon penetration depth with and without the bonding response for alkanethiolate-gold are compared and are shown to be significantly different for a thiol monolayer adsorbate system. Additionally, plasmon penetration depth evaluated with bonding effect compensation shows greater consistency over different adsorbate thicknesses and better agreement with theory derived from Maxwell's equation, particularly for adsorbate thicknesses that are much smaller (<5%) than the plasmon penetration depth. The method is also extended to a more practically applicable polyelectrolyte multilayer adsorbate system. PMID:23566015

  7. γ-Fe2O3 nanocrystals-anchored macro/meso-porous graphene as a highly efficient adsorbent toward removal of methylene blue.

    PubMed

    Zhang, Lian Ying; Zhang, Wenlin; Zhou, Zhiqin; Li, Chang Ming

    2016-08-15

    An adsorbent, γ-Fe2O3 nanocrystals-anchored macro/meso-porous graphene was synthesized by metal etching approach toward removal of methylene blue, exhibiting rapid adsorption rate, high adsorption capacity and good recyclability, thus holding a great promise for treatment of methylene blue in wastewater. PMID:27218808

  8. Analysis of Adsorbate-Adsorbate and Adsorbate-Adsorbent Interactions to Decode Isosteric Heats of Gas Adsorption.

    PubMed

    Madani, S Hadi; Sedghi, Saeid; Biggs, Mark J; Pendleton, Phillip

    2015-12-21

    A qualitative interpretation is proposed to interpret isosteric heats of adsorption by considering contributions from three general classes of interaction energy: fluid-fluid heat, fluid-solid heat, and fluid-high-energy site (HES) heat. Multiple temperature adsorption isotherms are defined for nitrogen, T=(75, 77, 79) K, argon at T=(85, 87, 89) K, and for water and methanol at T=(278, 288, 298) K on a well-characterized polymer-based, activated carbon. Nitrogen and argon are subjected to isosteric heat analyses; their zero filling isosteric heats of adsorption are consistent with slit-pore, adsorption energy enhancement modelling. Water adsorbs entirely via specific interactions, offering decreasing isosteric heat at low pore filling followed by a constant heat slightly in excess of water condensation enthalpy, demonstrating the effects of micropores. Methanol offers both specific adsorption via the alcohol group and non-specific interactions via its methyl group; the isosteric heat increases at low pore filling, indicating the predominance of non-specific interactions. PMID:26538339

  9. Inorganic chemically active adsorbents (ICAAs)

    SciTech Connect

    Ally, M.R.; Tavlarides, L.

    1997-10-01

    Oak Ridge National Laboratory (ORNL) researchers are developing a technology that combines metal chelation extraction technology and synthesis chemistry. They begin with a ceramic substrate such as alumina, titanium oxide or silica gel because they provide high surface area, high mechanical strength, and radiolytic stability. One preparation method involves silylation to hydrophobize the surface, followed by chemisorption of a suitable chelation agent using vapor deposition. Another route attaches newly designed chelating agents through covalent bonding by the use of coupling agents. These approaches provide stable and selective, inorganic chemically active adsorbents (ICAAs) tailored for removal of metals. The technology has the following advantages over ion exchange: (1) higher mechanical strength, (2) higher resistance to radiation fields, (3) higher selectivity for the desired metal ion, (4) no cation exchange, (5) reduced or no interference from accompanying anions, (6) faster kinetics, and (7) easy and selective regeneration. Target waste streams include metal-containing groundwater/process wastewater at ORNL`s Y-12 Plant (multiple metals), Savannah River Site (SRS), Rocky Flats (multiple metals), and Hanford; aqueous mixed wastes at Idaho National Engineering Laboratory (INEL); and scrubber water generated at SRS and INEL. Focus Areas that will benefit from this research include Mixed Waste, and Subsurface Contaminants.

  10. Prevalence and transmission of antimicrobial resistance among Aeromonas populations from a duckweed aquaculture based hospital sewage water recycling system in Bangladesh.

    PubMed

    Rahman, Mokhlasur; Huys, Geert; Kühn, Inger; Rahman, Motiur; Möllby, Roland

    2009-10-01

    In order to investigate the influence of a duckweed aquaculture based hospital sewage water recycling plant on the prevalence and dissemination of antibiotic resistance, we made use of an existing collection of 1,315 Aeromonas isolates that were previously typed by the biochemical fingerprinting PhP-AE system. In these treatment plant, hospital raw sewage water is first collected in a settlement pond (referred to as sewage water in this study) and is then transferred to a lagoon, where the duckweed (Lemnaceae) is grown (referred to as lagoon). The duckweed is harvested and used as feed for the fish in a separate pond (referred to as fish pond). From this collection, representatives of 288 PhP types were subjected to antibiotic susceptibility testing for eight antimicrobials by broth microdilution method. The overall resistance rates among Aeromonas isolates from the treatment plant were highest for ampicillin (87%) and erythromycin (79%) followed by cephalothin (58%), nalidixic acid (52%), streptomycin (51%), tetracycline (31%), chloramphenicol (13%) and gentamicin (8%). A significantly lower prevalence of antibiotic resistance was found in Aeromonas from environmental control water, patient stool samples, duckweed and fish compared to sewage water isolates. The prevalence of resistance in the sewage water was not significantly reduced compared to the lagoon water and fish pond. Throughout the treatment system, the frequencies of resistant strains were found to diminish during the sewage water purification process, i.e. in the lagoon where sewage water is used to grow the duckweed. However, the frequency of resistant strains again increased in the fish pond where sewage grown duckweed is used for aquaculture. Among the selected isolates, two multiresistant clonal groups of Aeromonas caviae HG4 were identified that exhibited indistinguishable PhP and amplified fragment length polymorphism fingerprints and shared a common plasmid of approximately 5 kb

  11. The Life Cycle Cost (LCC) of Life Support Recycling and Resupply

    NASA Technical Reports Server (NTRS)

    Jones, Harry W.

    2015-01-01

    Brief human space missions supply all the crew's water and oxygen from Earth. The multiyear International Space Station (ISS) program instead uses physicochemical life support systems to recycle water and oxygen. This paper compares the Life Cycle Cost (LCC) of recycling to the LCC of resupply for potential future long duration human space missions. Recycling systems have high initial development costs but relatively low durationdependent support costs. This means that recycling is more cost effective for longer missions. Resupplying all the water and oxygen requires little initial development cost but has a much higher launch mass and launch cost. The cost of resupply increases as the mission duration increases. Resupply is therefore more cost effective than recycling for shorter missions. A recycling system pays for itself when the resupply LCC grows greater over time than the recycling LCC. The time when this occurs is called the recycling breakeven date. Recycling will cost very much less than resupply for long duration missions within the Earth-Moon system, such as a future space station or Moon base. But recycling would cost about the same as resupply for long duration deep space missions, such as a Mars trip. Because it is not possible to provide emergency supplies or quick return options on the way to Mars, more expensive redundant recycling systems will be needed.

  12. Behaviour of Recycled Coarse Aggregate Concrete: Age and Successive Recycling

    NASA Astrophysics Data System (ADS)

    Sahoo, Kirtikanta; Pathappilly, Robin Davis; Sarkar, Pradip

    2016-05-01

    Recycled Coarse Aggregate (RCA) concrete construction technique can be called as `green concrete', as it minimizes the environmental hazard of the concrete waste disposal. Indian standard recommends target mean compressive strength of the conventional concrete in terms of water cement ratio (w/c). The present work is an attempt to study the behaviour of RCA concrete from two samples of parent concrete having different age group with regard to the relationship of compressive strength with water cement ratios. Number of recycling may influence the mechanical properties of RCA concrete. The influence of age and successive recycling on the properties such as capillary water absorption, drying shrinkage strain, air content, flexural strength and tensile splitting strength of the RCA concrete are examined. The relationship between compressive strength at different w/c ratios obtained experimentally is investigated for the two parameters such as age of parent concrete and successive recycling. The recycled concrete using older recycled aggregate shows poor quality. While the compressive strength reduces with successive recycling gradually, the capillary water absorption increases abruptly, which leads to the conclusion that further recycling may not be advisable.

  13. Behaviour of Recycled Coarse Aggregate Concrete: Age and Successive Recycling

    NASA Astrophysics Data System (ADS)

    Sahoo, Kirtikanta; Pathappilly, Robin Davis; Sarkar, Pradip

    2016-06-01

    Recycled Coarse Aggregate (RCA) concrete construction technique can be called as `green concrete', as it minimizes the environmental hazard of the concrete waste disposal. Indian standard recommends target mean compressive strength of the conventional concrete in terms of water cement ratio ( w/ c). The present work is an attempt to study the behaviour of RCA concrete from two samples of parent concrete having different age group with regard to the relationship of compressive strength with water cement ratios. Number of recycling may influence the mechanical properties of RCA concrete. The influence of age and successive recycling on the properties such as capillary water absorption, drying shrinkage strain, air content, flexural strength and tensile splitting strength of the RCA concrete are examined. The relationship between compressive strength at different w/ c ratios obtained experimentally is investigated for the two parameters such as age of parent concrete and successive recycling. The recycled concrete using older recycled aggregate shows poor quality. While the compressive strength reduces with successive recycling gradually, the capillary water absorption increases abruptly, which leads to the conclusion that further recycling may not be advisable.

  14. Adsorption characteristics of water vapor on gear-pellet and honeycomb-pellet types of adsorbents containing A-type zeolite

    SciTech Connect

    Nakamura, A.; Munakata, K.; Hara, K.; Narita, S.; Sugiyama, T.; Kotoh, K.; Tanaka, M.; Uda, T.

    2015-03-15

    It is necessary to recover or process tritiated species that are extensively coexistent in nuclear fusion installations. A conventional way to recover tritium release to atmosphere is catalytic oxidation of tritiated species and adsorption of tritiated water vapor on adsorbents with high surface areas. Therefore, new adsorbents with low pressure loss and high surface areas need to be developed and utilized for such large-scale adsorption systems. In this study, attention was focused on new adsorbents, which are gear-type pellet MS5A adsorbent, gear-type pellet MS4A adsorbent and honeycomb-type pellet MS5A adsorbent. The adsorption characteristics of the new adsorbent were comparatively studied with conventional type of adsorbents (pellet-type MS5A adsorbent and pebble-type MS5A adsorbent), in terms of adsorption capacity, pressure loss and adsorption rate. It was found that the adsorption capacity of water vapor on the gear-type adsorbents is higher than that on a honeycomb-type adsorbent. The experimental breakthrough curves indicate that the adsorption rates of water vapor on gear-type and honeycomb-type adsorbents are smaller than that on conventional type adsorbents. Various adsorption models were also tested to correlate the experimental isotherms. It was found that the Langmuir-Freundlich model could properly correlate the experimental adsorption isotherms.

  15. Cellulase stability, adsorption/desorption profiles and recycling during successive cycles of hydrolysis and fermentation of wheat straw.

    PubMed

    Rodrigues, Ana Cristina; Felby, Claus; Gama, Miguel

    2014-03-01

    The potential of enzymes recycling after hydrolysis and fermentation of wheat straw under a variety of conditions was investigated, monitoring the activity of the enzymes in the solid and liquid fractions, using low molecular weight substrates. A significant amount of active enzymes could be recovered by recycling the liquid phase. In the early stage of the process, enzyme adsorb to the substrate, then gradually returning to the solution as the saccharification proceeds. At 50°C, normally regarded as an acceptable operational temperature for saccharification, the enzymes (Celluclast) significantly undergo thermal deactivation. The hydrolysis yield and enzyme recycling efficiency in consecutive recycling rounds can be increased by using high enzyme loadings and moderate temperatures. Indeed, the amount of enzymes in the liquid phase increased with its thermostability and hydrolytic efficiency. This study contributes towards developing effective enzymes recycling strategies and helping to reduce the enzyme costs on bioethanol production. PMID:24502914

  16. Site blocking effects on adsorbed polyacrylamide conformation

    NASA Astrophysics Data System (ADS)

    Brotherson, Brett A.

    The use of polymers as flocculating additives is a common practice in many manufacturing environments. However, exactly how these polymers interact with surfaces is relatively unknown. One specific topic which is thought to be very important to flocculation is an adsorbed polymer's conformation. Substantial amounts of previous work, mainly using simulations, have been performed to elucidate the theory surrounding adsorbed polymer conformations. Yet, there is little experimental work which directly verifies current theory. In order to optimize the use of polymer flocculants in industrial applications, a better understanding of an adsorbed polymer's conformation on a surface beyond theoretical simulations is necessary. This work looks specifically at site blocking, which has a broad impact on flocculation, adsorption, and surface modification, and investigated its effects on the resulting adsorbed polymer conformation. Experimental methods which would allow direct determination of adsorbed polymer conformational details and be comparable with previous experimental results were first determined or developed. Characterization of an adsorbed polymer's conformation was then evaluated using dynamic light scattering, a currently accepted experimental technique to examine this. This commonly used technique was performed to allow the comparison of this works results with past literature. Next, a new technique using atomic force microscopy was developed, building on previous experimental techniques, to allow the direct determination of an adsorbed polymer's loop lengths. This method also was able to quantify changes in the length of adsorbed polymer tails. Finally, mesoscopic simulation was attempted using dissipative particle dynamics. In order to determine more information about an adsorbed polymer's conformation, three different environmental factors were analyzed: an adsorbed polymer on a surface in water, an adsorbed polymer on a surface in aqueous solutions of varying

  17. Complexation of trace metals by adsorbed natural organic matter

    USGS Publications Warehouse

    Davis, J.A.

    1984-01-01

    The adsorption behavior and solution speciation of Cu(II) and Cd(II) were studied in model systems containing colloidal alumina particles and dissolved natural organic matter. At equilibrium a significant fraction of the alumina surface was covered by adsorbed organic matter. Cu(II) was partitioned primarily between the surface-bound organic matter and dissolved Cu-organic complexes in the aqueous phase. Complexation of Cu2+ with the functional groups of adsorbed organic matter was stronger than complexation with uncovered alumina surface hydroxyls. It is shown that the complexation of Cu(II) by adsorbed organic matter can be described by an apparent stability constant approximately equal to the value found for solution phase equilibria. In contrast, Cd(II) adsorption was not significantly affected by the presence of organic matter at the surface, due to weak complex formation with the organic ligands. The results demonstrate that general models of trace element partitioning in natural waters must consider the presence of adsorbed organic matter. ?? 1984.

  18. Pulling adsorbed self-avoiding walks from a surface

    NASA Astrophysics Data System (ADS)

    Guttmann, Anthony J.; Jensen, I.; Whittington, S. G.

    2014-01-01

    We consider a self-avoiding walk model of polymer adsorption where the adsorbed polymer can be desorbed by the application of a force, concentrating on the case of the square lattice. Using series analysis methods we investigate the behaviour of the free energy of the system when there is an attractive potential ɛ with the surface and a force f applied at the last vertex, normal to the surface, and extract the phase boundary between the ballistic and adsorbed phases. We believe this to be exact to graphical accuracy. We give precise estimates of the location of the transition from the free phase to the ballistic phase, which we find to be at yc = exp (f/kBTc) = 1, and from the free phase to the adsorbed phase, which we estimate to be at ac = exp ( - ɛ/kBTc) = 1.775 615 ± 0.000 005. In addition we prove that the phase transition from the ballistic to the adsorbed phase is first order.

  19. Photochemistry of adsorbed nitrate on aluminum oxide particle surfaces.

    PubMed

    Rubasinghege, Gayan; Grassian, Vicki H

    2009-07-01

    Nitrogen oxides, including nitrogen dioxide and nitric acid, react with mineral dust particles in the atmosphere to yield adsorbed nitrate. Although nitrate ion is a well-known chromophore in natural waters, little is known about the surface photochemistry of nitrate adsorbed on mineral particles. In this study, nitrate adsorbed on aluminum oxide, a model system for mineral dust aerosol, is irradiated with broadband light (lambda > 300 nm) as a function of relative humidity (RH) in the presence of molecular oxygen. Upon irradiation, the nitrate ion readily undergoes photolysis to yield nitrogen-containing gas-phase products including NO(2), NO, and N(2)O, with NO being the major product. The relative ratio and product yields of these gas-phase products change with RH, with N(2)O production being highest at the higher relative humidities. Furthermore, an efficient dark reaction readily converts the major NO product into NO(2) during post-irradiation. Photochemical processes on mineral dust aerosol surfaces have the potential to impact the chemical balance of the atmosphere, yet little is known about these processes. In this study, the impact that adsorbed nitrate photochemistry may have on the renoxification of the atmosphere is discussed. PMID:19534452

  20. Recycling the office - Walls and all

    SciTech Connect

    Tilsner, J.

    1993-04-26

    As the keeper of any office-supply closet can tell you, the work-place is a very wasteful environment but now, as America prepares to celebrate the 23rd Earth Day, on April 22, businesses are discovering that the three R's - recycling, reusing, and reducing - apply to a lot more than copy paper and cans from the vending machine. Today, offices use items that couldn't be recycled a few years ago. Take toner cartridges for laser printers and copiers. Even in this electronic age, paper copies are a must, so most offices go through boxloads of cartridges, which cost $100 to $130 each. But you can prevent those spent cartridges from clogging landfills and cut costs. The trick to substantially reducing waste in your office may be expanding your notion of what recycling means. For example, several companies refit, repaint, and repair old chairs, cubicles, panels, and partitions. The resulting products cost 30% to 50% less than equivalent new equipment. Obsolete computers, telephones, and other equipment that you no longer need can still be recycled. There's also a brisk secondary market for old telephone systems.

  1. A fragment method for systematic improvement of anharmonic adsorbate vibrational frequencies: Acetylene on Cu(001)

    SciTech Connect

    Chulkov, Sergey K. Benoit, David M.

    2013-12-07

    We suggest a novel method for systematic improvement of anharmonic adsorbate frequencies based on a fragment approach. The calculations are carried out by considering the adsorbed molecule separately and computing an energy correction using high-level ab initio method in addition to a standard calculation of the whole adsorbed system using quantum mechanical techniques with periodic boundary conditions. We demonstrate its reliability for a C{sub 2}H{sub 2} molecule chemisorbed on a Cu(001) surface. We also show that the accuracy of the presented approach with a suitable description of the periodic surface depends mainly on the accuracy of the high-level ab initio method used to describe the adsorbate molecule. Moreover, our technique potentially allows to predict adsorbate vibrational spectra with spectroscopic accuracy.

  2. Electric field cancellation on quartz by Rb adsorbate-induced negative electron affinity

    NASA Astrophysics Data System (ADS)

    Shaffer, James

    2016-05-01

    We investigate the (0001) surface of single crystal quartz with a submonolayer of Rb adsorbates. Using Rydberg atom electromagnetically induced transparency, we investigate the electric fields resulting from Rb adsorbed on the quartz surface, and measure the activation energy of the Rb adsorbates. We show that the adsorbed Rb induces a negative electron affinity (NEA) on the quartz surface. The NEA surface allows low energy electrons to bind to the surface and cancel the electric field from the Rb adsorbates. Our results are important for integrating Rydberg atoms into hybrid quantum systems and the fundamental study of atom-surface interactions, as well as applications for electrons bound to a 2D surface. This work was supported by the DARPA Quasar program by a Grant through ARO (60181-PH-DRP) and the AFOSR (FA9550-12-1-0282),.

  3. Adsorbed natural gas storage with activated carbon

    SciTech Connect

    Sun, Jian; Brady, T.A.; Rood, M.J.

    1996-12-31

    Despite technical advances to reduce air pollution emissions, motor vehicles still account for 30 to 70% emissions of all urban air pollutants. The Clean Air Act Amendments of 1990 require 100 cities in the United States to reduce the amount of their smog within 5 to 15 years. Hence, auto emissions, the major cause of smog, must be reduced 30 to 60% by 1998. Natural gas con be combusted with less pollutant emissions. Adsorbed natural gas (ANG) uses adsorbents and operates with a low storage pressure which results in lower capital costs and maintenance. This paper describes the production of an activated carbon adsorbent produced from an Illinois coal for ANG.

  4. States of water adsorbed on perindopril crystals

    NASA Astrophysics Data System (ADS)

    Stepanov, V. A.; Khmelevskaya, V. S.; Bogdanov, N. Yu.; Gorchakov, K. A.

    2011-10-01

    The relationship between the structural state of adsorbed water, the crystal structure of the substances, and the solubility of the perindopril salt C19H32N2O5 · C4H11N in water was studied by IR spectroscopy and X-ray diffractometry. The high-frequency shift of the stretching vibrations of adsorbed water and the solubility depend on the crystal structure of the drug substance. A reversible chemical reaction occurred between the adsorbed water and the perindopril salt.

  5. Garbage project on recycling behavior

    SciTech Connect

    McGuire, R.H.; Hughes, W.W.; Rathje, W.L.

    1982-02-01

    Results are presented of a study undertaken to determine the factors which are most effective in motivating different socio-economic groups to change their recycling behaviors and participate in recycling programs. Four types of data were collected and analyzed in Tucson: (1) purchase data from local recyclers, (2) traditional interview-survey data on recycling behavior, (3) long-term and short-term household refuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are tuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are the same across census tracts with significantly different socio-economic characteristics. Further, analysis of interview and garbage data matched by household reaffirm that what people say about recycling and how they dispose of recyclable materials are two different things. Thus, interview reports of newspaper recycling correlate with higher income informants, but their interview reports do not correlate with what is thrown into their garbage cans. Money is concluded to be the most powerful incentive toward recycling.

  6. Information Sources on Rural Recycling.

    ERIC Educational Resources Information Center

    Notess, Greg; Kuske, Jodee

    1992-01-01

    Provides resources for rural recycling operations with the principle aim of assisting rural government officials, planners, residents, and educators to encourage recycling as an integral part of an individual's or community's solid waste management plan. Sources range from bibliographies, directories, and government documents to case studies. (49…

  7. American Art of Conspicuous Recycling.

    ERIC Educational Resources Information Center

    Gomez, Aurelia

    1999-01-01

    Characterizes the use of recycling "junk" as a means for creating art by exploring various recycling traditions that are present in the United States. Demonstrates to students that "junk" can be fashioned into beautiful works of art. Offers four works of art and provides discussion questions and project ideas for each artwork. (CMK)

  8. Recycling Study Guide [Resource Packet].

    ERIC Educational Resources Information Center

    Wisconsin State Dept. of Natural Resources, Madison.

    This resource packet contains six documents developed by the Wisconsin Department of Natural Resources in order to help teachers infuse the environmental education topics of recycling and solid waste into social studies, art, English, health, mathematics, science, and environmental education classes. "Recycling Study Guide" contains 19 activities…

  9. Recycling Solid Waste in Chattanooga

    ERIC Educational Resources Information Center

    Vredeveld, Ruth; Martin, Robin

    1973-01-01

    Students undertook a group project in collaboration with city officials to study garbage types in the community and possibilities of recycling solid wastes. Data collected from various sources revealed that public attitude was favorable for recycling efforts and that it was feasible economically. (PS)

  10. Training Governments to Buy Recycled.

    ERIC Educational Resources Information Center

    Keller, Richard

    1995-01-01

    Describes a program developed by the Northeast Maryland Waste Disposal Authority to teach government buyers how to buy recycled materials. The program consists of a hands-on training seminar and a manual that offers step-by-step instructions for setting up a buy-recycled purchasing program. (LZ)

  11. Evidence That p-Cresol and IL-6 Are Adsorbed by the HFR Cartridge: Towards a New Strategy to Decrease Systemic Inflammation in Dialyzed Patients?

    PubMed Central

    Riccio, Eleonora; Cataldi, Mauro; Minco, Maristella; Argentino, Gennaro; Russo, Roberta; Brancaccio, Stefania; Memoli, Andrea; Grumetto, Lucia; Postiglione, Loredana; Guida, Bruna; Memoli, Bruno

    2014-01-01

    Introduction Hemodialysis (HD) and hemodiafiltration clear only with a low efficiency the plasma from interleukin-6 and p-cresol, two protein-bound uremic toxins associated with high cardiovascular risk in end stage renal disease. HFR Supra is a double-chamber hemodiafiltration system in which the ultrafiltrate returns to the patient after its regeneration through a resin cartridge that binds hydrophobic and protein-bound solutes. In the present study, we evaluated whether the HFR cartridge can also bind total p-cresol and IL-6 and remove them from the ultrafiltrate. Methods We compared the levels of IL-6 and p-cresol in ultrafiltrate samples collected at the inlet (UFin) and at the outlet (UFout) of the cartridge at the start or at the end of a 240 min HFR session in 12 inflamed chronic HD patients. The pro-inflammatory activity of the ultrafiltrate samples was also determined by evaluating the changes that they induced in IL-6 mRNA expression and protein release in peripheral blood mononuclear cells from 12 healthy volunteers. IL-6 and p-cresol circulating levels were also assessed in peripheral plasma blood samples collected before and after HFR and, for comparison, a control HD. Results p-Cresol and IL-6 were lower in UFout than in UFin both at the start and at the end of the HFR session, suggesting that they were retained by the cartridge. IL-6 mRNA expression and release were lower in PBMC incubated with UFout collected at the end than with UFin collected at the start of HFR, suggesting that passage through the cartridge reduced UF pro-inflammatory activity. Plasma total p-cresol decreased by about 53% after HFR, and 37% after HD. IL-6 circulating values were unmodified by either these dialysis procedures. Conclusions This study shows that the HFR-Supra cartridge retains total p-cresol and IL-6 in the ultrafiltrate and lowers plasma total p cresol but not IL-6 levels. Trial Registration ClinicalTrials.gov NCT01865773 PMID:24755610

  12. Volumetric Interpretation of Protein Adsorption: Capacity Scaling with Adsorbate Molecular Weight and Adsorbent Surface Energy

    PubMed Central

    Parhi, Purnendu; Golas, Avantika; Barnthip, Naris; Noh, Hyeran; Vogler, Erwin A.

    2009-01-01

    Silanized-glass-particle adsorbent capacities are extracted from adsorption isotherms of human serum albumin (HSA, 66 kDa), immunoglobulin G (IgG, 160 kDa), fibrinogen (Fib, 341 kDa), and immunoglobulin M (IgM, 1000 kDa) for adsorbent surface energies sampling the observable range of water wettability. Adsorbent capacity expressed as either mass-or-moles per-unit-adsorbent-area increases with protein molecular weight (MW) in a manner that is quantitatively inconsistent with the idea that proteins adsorb as a monolayer at the solution-material interface in any physically-realizable configuration or state of denaturation. Capacity decreases monotonically with increasing adsorbent hydrophilicity to the limit-of-detection (LOD) near τo = 30 dyne/cm (θ~65o) for all protein/surface combinations studied (where τo≡γlvocosθ is the water adhesion tension, γlvo is the interfacial tension of pure-buffer solution, and θ is the buffer advancing contact angle). Experimental evidence thus shows that adsorbent capacity depends on both adsorbent surface energy and adsorbate size. Comparison of theory to experiment implies that proteins do not adsorb onto a two-dimensional (2D) interfacial plane as frequently depicted in the literature but rather partition from solution into a three-dimensional (3D) interphase region that separates the physical surface from bulk solution. This interphase has a finite volume related to the dimensions of hydrated protein in the adsorbed state (defining “layer” thickness). The interphase can be comprised of a number of adsorbed-protein layers depending on the solution concentration in which adsorbent is immersed, molecular volume of the adsorbing protein (proportional to MW), and adsorbent hydrophilicity. Multilayer adsorption accounts for adsorbent capacity over-and-above monolayer and is inconsistent with the idea that protein adsorbs to surfaces primarily through protein/surface interactions because proteins within second (or higher

  13. OsO(4) in ionic liquid [Bmim]PF(6): a recyclable and reusable catalyst system for olefin dihydroxylation. remarkable effect of DMAP.

    PubMed

    Yao, Qingwei

    2002-06-27

    [reaction: see text] The combination of the ionic liquid [bmim]PF(6) and DMAP provides a most simple and practical approach to the immobilization of OsO(4) as catalyst for olefin dihydroxylation. Both the catalyst and the ionic liquid can be repeatedly recycled and reused in the dihydroxylation of a variety of olefins with only a very slight drop in catalyst activity. PMID:12074666

  14. Is recycling worth the trouble

    SciTech Connect

    Boltz, C.M.

    1995-03-01

    A panel of waste industry experts met recently at a Washington, DC, conference to discuss and debate the costs, benefits, and economics of recycling solid waste. The nearly unanimous conclusion from some of the speakers--that recycling, as it is implemented today, has costs that far outweigh its benefits--is evidence of a growing backlash among solid waste officials against a recycling movement they feel has been grossly over-inflated by environmental groups as a solution to a non-existent problem known as the garbage crisis. The public should not place such a strong emphasis on recycling as a cure-all for environmental problems, according to the panel of four waste management policy analysts at The State of Garbage'' session held in mid-January at the 1995 US/Canadian Federation Solid Waste Management Conference. Moreover, some panel members said, recycling should take place only if it makes economic sense.

  15. Heterogeneous Recycling in Fast Reactors

    SciTech Connect

    Forget, Benoit; Pope, Michael; Piet, Steven J.; Driscoll, Michael

    2012-07-30

    Current sodium fast reactor (SFR) designs have avoided the use of depleted uranium blankets over concerns of creating weapons grade plutonium. While reducing proliferation risks, this restrains the reactor design space considerably. This project will analyze various blanket and transmutation target configurations that could broaden the design space while still addressing the non-proliferation issues. The blanket designs will be assessed based on the transmutation efficiency of key minor actinide (MA) isotopes and also on mitigation of associated proliferation risks. This study will also evaluate SFR core performance under different scenarios in which depleted uranium blankets are modified to include minor actinides with or without moderators (e.g. BeO, MgO, B4C, and hydrides). This will be done in an effort to increase the sustainability of the reactor and increase its power density while still offering a proliferation resistant design with the capability of burning MA waste produced from light water reactors (LWRs). Researchers will also analyze the use of recycled (as opposed to depleted) uranium in the blankets. The various designs will compare MA transmutation efficiency, plutonium breeding characteristics, proliferation risk, shutdown margins and reactivity coefficients with a current reference sodium fast reactor design employing homogeneous recycling. The team will also evaluate the out-of-core accumulation and/or burn-down rates of MAs and plutonium isotopes on a cycle-by-cycle basis. This cycle-by-cycle information will be produced in a format readily usable by the fuel cycle systems analysis code, VISION, for assessment of the sustainability of the deployment scenarios.

  16. Preparation of sodium humate/{alpha}-aluminum oxide adsorbents for flue gas desulfurization

    SciTech Connect

    Sun, Z.G.; Gao, H.Y.; Hu, G.X.; Li, Y.H.

    2009-06-15

    A new composite adsorbent of sodium humate (HNa)=alpha-aluminium oxide ({alpha}-Al{sub 2}O{sub 3}) for flue gas desulfurization (FGD) was prepared using the impregnation method. Both the adsorbent of {alpha}-Al{sub 2}O{sub 3} and HNa={alpha}-Al{sub 2}O{sub 3} were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), and scanning electron microscope (SEM). Desulfurization activity of the adsorbent impregnated with ammonia (NH{sub 4}OH) was investigated in a fixed-bed quartz reactor. Experimental results indicate that HNa, which coats the {alpha}-Al{sub 2}O{sub 3} fibers impregnated with HNa solution, improved the property of {alpha}-Al{sub 2}O{sub 3} support for FGD. On the other hand, the HNa-coating on the adsorbent of HNa/{alpha}-Al{sub 2}O{sub 3} impregnated with NH{sub 4}OH played an important role in enhancing the desulfurization property of the {alpha}-Al{sub 2}O{sub 3}. Due to the strong adsorption capability of HNa, more NH{sub 4}OH was adsorbed in the adsorbent of HNa/{alpha}-Al{sub 2}O{sub 3} the longer a high sulfur dioxide (SO{sub 2}) conversation rate was maintained. In addition, because the desulfurization product was a compound fertilizer consisting of ammonium sulfate ((NH{sub 4}){sub 2}SO{sub 4}), ammonium humate (HNH{sub 4}), and HNa, the recycling use of {alpha}-Al{sub 2}O{sub 3} was also easily achieved. Thus, this study can provide a new cost-effective way to remove SO{sub 2} from flue gas.

  17. Recyclable Waste Paper Sorting Using Template Matching

    NASA Astrophysics Data System (ADS)

    Osiur Rahman, Mohammad; Hussain, Aini; Scavino, Edgar; Hannan, M. A.; Basri, Hassan

    This paper explores the application of image processing techniques in recyclable waste paper sorting. In recycling, waste papers are segregated into various grades as they are subjected to different recycling processes. Highly sorted paper streams will facilitate high quality end products, and save processing chemicals and energy. Since 1932 to 2009, different mechanical and optical paper sorting methods have been developed to fill the demand of paper sorting. Still, in many countries including Malaysia, waste papers are sorted into different grades using manual sorting system. Due to inadequate throughput and some major drawbacks of mechanical paper sorting systems, the popularity of optical paper sorting systems is increased. Automated paper sorting systems offer significant advantages over human inspection in terms of fatigue, throughput, speed, and accuracy. This research attempts to develop a smart vision sensing system that able to separate the different grades of paper using Template Matching. For constructing template database, the RGB components of the pixel values are used to construct RGBString for template images. Finally, paper object grade is identified based on the maximum occurrence of a specific template image in the search image. The outcomes from the experiment in classification for White Paper, Old Newsprint Paper and Old Corrugated Cardboard are 96%, 92% and 96%, respectively. The remarkable achievement obtained with the method is the accurate identification and dynamic sorting of all grades of papers using simple image processing techniques.

  18. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  19. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  20. PERVAPORATION USING ADSORBENT-FILLED MEMBRANES

    EPA Science Inventory

    Membranes containing selective fillers, such as zeolites and activated carbon, can improve the separation by pervaporation. Applications of adsorbent-filled membranes in pervaporation have been demonstrated by a number of studies. These applications include removal of organic co...

  1. Examining Adsorbed Polymer Conformations with Fluorescence Imaging

    NASA Astrophysics Data System (ADS)

    Parkes, Maria; Chennaoui, Mourad; Wong, Janet; Tribology Group, Dept. of Mechanical Engineering Team

    2011-03-01

    The conformation of adsorbed polymers can have significant impact on their properties such as dynamics and elasticity as well as their ability to take part in reactions with other molecules. Experimental research to determine adsorbed polymer conformation has relied mainly on atomic force microscopy (AFM) studies. During an AFM scan, the contact between the scanning probe and the polymer could affect the polymer conformation, particularly where parts of the polymer might have formed projected loops and tails. In this work, conformations of model polymers are examined with total internal reflection fluorescence microscopy (TIRFM). The advantage of TIRFM over AFM is that TIRFM is a non contact technique. Lambda DNA labelled along its length with fluorescent probes was adsorbed in a projected 2D -- 3D state. With TIRFM, the relationship between intensity and depth was used as a basis to determine how the conformation of the adsorbed polymers evolved with time using our custom algorithm.

  2. Detection and Recovery of Palladium, Gold and Cobalt Metals from the Urban Mine Using Novel Sensors/Adsorbents Designated with Nanoscale Wagon-wheel-shaped Pores.

    PubMed

    El-Safty, Sherif A; Shenashen, Mohamed A; Sakai, Masaru; Elshehy, Emad; Halada, Kohmei

    2015-01-01

    Developing low-cost, efficient processes for recovering and recycling palladium, gold and cobalt metals from urban mine remains a significant challenge in industrialized countries. Here, the development of optical mesosensors/adsorbents (MSAs) for efficient recognition and selective recovery of Pd(II), Au(III), and Co(II) from urban mine was achieved. A simple, general method for preparing MSAs based on using high-order mesoporous monolithic scaffolds was described. Hierarchical cubic Ia3d wagon-wheel-shaped MSAs were fabricated by anchoring chelating agents (colorants) into three-dimensional pores and micrometric particle surfaces of the mesoporous monolithic scaffolds. Findings show, for the first time, evidence of controlled optical recognition of Pd(II), Au(III), and Co(II) ions and a highly selective system for recovery of Pd(II) ions (up to ~95%) in ores and industrial wastes. Furthermore, the controlled assessment processes described herein involve evaluation of intrinsic properties (e.g., visual signal change, long-term stability, adsorption efficiency, extraordinary sensitivity, selectivity, and reusability); thus, expensive, sophisticated instruments are not required. Results show evidence that MSAs will attract worldwide attention as a promising technological means of recovering and recycling palladium, gold and cobalt metals. PMID:26709467

  3. Detection and Recovery of Palladium, Gold and Cobalt Metals from the Urban Mine Using Novel Sensors/Adsorbents Designated with Nanoscale Wagon-wheel-shaped Pores

    PubMed Central

    El-Safty, Sherif A.; Shenashen, Mohamed A.; Sakai, Masaru; Elshehy, Emad; Halada, Kohmei

    2015-01-01

    Developing low-cost, efficient processes for recovering and recycling palladium, gold and cobalt metals from urban mine remains a significant challenge in industrialized countries. Here, the development of optical mesosensors/adsorbents (MSAs) for efficient recognition and selective recovery of Pd(II), Au(III), and Co(II) from urban mine was achieved. A simple, general method for preparing MSAs based on using high-order mesoporous monolithic scaffolds was described. Hierarchical cubic Ia3d wagon-wheel-shaped MSAs were fabricated by anchoring chelating agents (colorants) into three-dimensional pores and micrometric particle surfaces of the mesoporous monolithic scaffolds. Findings show, for the first time, evidence of controlled optical recognition of Pd(II), Au(III), and Co(II) ions and a highly selective system for recovery of Pd(II) ions (up to ~95%) in ores and industrial wastes. Furthermore, the controlled assessment processes described herein involve evaluation of intrinsic properties (e.g., visual signal change, long-term stability, adsorption efficiency, extraordinary sensitivity, selectivity, and reusability); thus, expensive, sophisticated instruments are not required. Results show evidence that MSAs will attract worldwide attention as a promising technological means of recovering and recycling palladium, gold and cobaltmetals. PMID:26709467

  4. Dispersed-phase adsorbents for biotechnology applications

    SciTech Connect

    Scott, C.D.

    1987-01-01

    A new type of adsorbent material has been developed in which very small adsorbent particles are entrapped in a hydrocolloidal gel matrix that is formed into small, monodisperse spherical beads. Examples of applications of this type of material include dispersed, hydrous transition metal oxides that can be used for the retention of biocatalysts, such as enzymes, and certain microorganisms or microbial fragments that can be dispersed into the gel matrix to accumulate and isolate various dissolved metals. 7 refs., 2 figs., 2 tabs.

  5. Regenerable activated bauxite adsorbent alkali monitor probe

    DOEpatents

    Lee, Sheldon H. D.

    1992-01-01

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases.

  6. Regenerable activated bauxite adsorbent alkali monitor probe

    DOEpatents

    Lee, S.H.D.

    1992-12-22

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

  7. A multifunctional azobenzene-based polymeric adsorbent for effective water remediation

    NASA Astrophysics Data System (ADS)

    Wan, Decheng; Chen, Feng; Geng, Qingrui; Lu, Hang; Willcock, Helen; Liu, Qiuming; Wang, Fangyingkai; Zou, Kaidian; Jin, Ming; Pu, Hongting; Du, Jianzhong

    2014-12-01

    The efficient removal of trace carcinogenic organic pollutants, such as polycyclic aromatic hydrocarbons (PAHs) and ionic dyes, from water is an important technical challenge. We report a highly effective recyclable multifunctional azobenzene (AZ)-based silica-supported polymeric adsorbent which can simultaneously remove both PAHs and anionic dyes from water to below parts per billion (ppb) level based on multiple interactions such as the hydrophobic effect, π-π stacking and electrostatic interactions, thus providing a new strategy for designer water remediation materials.

  8. A multifunctional azobenzene-based polymeric adsorbent for effective water remediation

    PubMed Central

    Wan, Decheng; Chen, Feng; Geng, Qingrui; Lu, Hang; Willcock, Helen; Liu, Qiuming; Wang, Fangyingkai; Zou, Kaidian; Jin, Ming; Pu, Hongting; Du, Jianzhong

    2014-01-01

    The efficient removal of trace carcinogenic organic pollutants, such as polycyclic aromatic hydrocarbons (PAHs) and ionic dyes, from water is an important technical challenge. We report a highly effective recyclable multifunctional azobenzene (AZ)-based silica-supported polymeric adsorbent which can simultaneously remove both PAHs and anionic dyes from water to below parts per billion (ppb) level based on multiple interactions such as the hydrophobic effect, π–π stacking and electrostatic interactions, thus providing a new strategy for designer water remediation materials. PMID:25465671

  9. Water recycling at the Millennium Dome.

    PubMed

    Hills, S; Smith, A; Hardy, P; Birks, R

    2001-01-01

    Thames Water is working with the New Millennium Experience Company to provide a water recycling system for the Millennium Dome which will supply 500 m3/d of reclaimed water for WC and urinal flushing. The system will treat water from three sources: rainwater--from the Dome roof greywater--from handbasins in the toilet blocks groundwater--from beneath the Dome site The treatment technologies will range from "natural" reedbeds for the rainwater, to more sophisticated options, including biological aerated filters and membranes for the greywater and groundwater. Pilot scale trials were used to design the optimum configuration. In addition to the recycling system, water efficient devices will be installed in three of the core toilet blocks as part of a programme of research into the effectiveness of conservation measures. Data on water usage and customer behaviour will be collected via a comprehensive metering system. Information from the Dome project on the economics and efficiency of on-site recycling at large scale and data on water efficient devices, customer perception and behaviour will be of great value to the water industry. For Thames Water, the project provides vital input to the development of future water resource strategies. PMID:11436793

  10. Precipitation Recycling in India during South West Monsoon

    NASA Astrophysics Data System (ADS)

    Pathak, A.; Ghosh, S.; Kumar, P.

    2012-12-01

    The summer monsoon (June to September, JJAS) rainfall over India is dominated by oceanic forcing but the land surface hydrology may also have significant role in generation of precipitation over the Indian subcontinent. The present study aims to investigate the role of land surface processes in rainfall through evapotranspiration. As monsoon progresses in Indian subcontinent, the rainfall enhances the soil moisture and vegetation cover. Though the humidity is high during monsoon; very high wind speed, large availability of water surface area, and vegetation cover intensifies the evapotranspiration process. The evapotranspiration over a region in the summer monsoon months supplies the moisture to the atmosphere which may also lead to precipitation other than oceanic sources. However, it is the interaction between land surface and atmosphere that determines the fate of evapotranspirated water molecule. The fraction of precipitation generated because of local evapotranspiration is known as recycled precipitation and this phenomenon is known as precipitation recycling. The precipitation recycling is quantified by recycling ratio which is equal to ratio of recycled precipitation to total precipitation. The estimates of precipitation recycling provide a clear picture of interactions between land and atmosphere for any region and may help in understanding the mechanism behind precipitation. The objective of this work is to study the impact of precipitation recycling on Indian southwest monsoon rainfall. In the present work, daily dataset from National Centers for Environmental Prediction (NCEP) and Climate Forecast System Reanalysis (CFSR), for the period of 1980 to 2001, at a spatial resolution of 0.5o x 0.5o, is used. In order to study the impact of recycling process on monsoon rainfall, dynamic recycling model is used and the regional recycling ratio values for entire Indian sub-continental land region are estimated. It is observed that precipitation recycling is

  11. Effects of fuel cell anode recycle on catalytic fuel reforming

    SciTech Connect

    shekhawat, D.; Berry, D.; Gardner, T.; Haynes, D.; Spivey, J.

    2007-01-01

    The presence of steam in the reactant gas of a catalytic fuel reformer decreases the formation of carbon, minimizing catalyst deactivation. However, the operation of the reformer without supplemental water reduces the size, weight, cost, and overall complexity of the system. The work presented here examines experimentally two options for adding steam to the reformer inlet: (I) recycle of a simulated fuel cell anode exit gas (comprised of mainly CO2, H2O, and N2 and some H2 and CO) and (II) recycle of the reformate from the reformer exit back to the reformer inlet (mainly comprised of H2, CO, and N2 and some H2O and CO2). As expected, anode gas recycle reduced the carbon formation and increased the hydrogen concentration in the reformate. However, reformer recycle was not as effective due principally to the lower water content in the reformate compared to the anode gas. In fact, reformate recycle showed slightly increased carbon formation compared to no recycle. In an attempt to understand the effects of individual gases in these recycle streams (H2, CO, CO2, N2, and H2O), individual gas species were independently introduced to the reformer feed. Published by Elsevier B.V.

  12. Effects of Fuel Cell Anode Recycle on Catalytic Fuel Reforming

    SciTech Connect

    Shekhawat, Dushyant; Berry, D.A.; Gardner, T.H.; Haynes, D.J.; Spivey, J.J.

    2007-06-01

    The presence of steam in the reactant gas of a catalytic fuel reformer decreases the formation of carbon, minimizing catalyst deactivation. However, the operation of the reformer without supplemental water reduces the size, weight, cost, and overall complexity of the system. The work presented here examines experimentally two options for adding steam to the reformer inlet: (I) recycle of a simulated fuel cell anode exit gas (comprised of mainly CO2, H2O, and N2 and some H2 and CO) and (II) recycle of the reformate from the reformer exit back to the reformer inlet (mainly comprised of H2, CO, and N2 and some H2O and CO2). As expected, anode gas recycle reduced the carbon formation and increased the hydrogen concentration in the reformate. However, reformer recycle was not as effective due principally to the lower water content in the reformate compared to the anode gas. In fact, reformate recycle showed slightly increased carbon formation compared to no recycle. In an attempt to understand the effects of individual gases in these recycle streams (H2, CO, CO2, N2, and H2O), individual gas species were independently introduced to the reformer feed.

  13. Technological, Economic, and Environmental Optimization of Aluminum Recycling

    NASA Astrophysics Data System (ADS)

    Ioana, Adrian; Semenescu, Augustin

    2013-08-01

    The four strategic directions (referring to the entire life cycle of aluminum) are as follows: production, primary use, recycling, and reuse. Thus, in this work, the following are analyzed and optimized: reducing greenhouse gas emissions from aluminum production, increasing energy efficiency in aluminum production, maximizing used-product collection, recycling, and reusing. According to the energetic balance at the gaseous environment level, the conductive transfer model is also analyzed through the finished elements method. Several principles of modeling and optimization are presented and analyzed: the principle of analogy, the principle of concepts, and the principle of hierarchization. Based on these principles, an original diagram model is designed together with the corresponding logic diagram. This article also presents and analyzes the main benefits of aluminum recycling and reuse. Recycling and reuse of aluminum have the main advantage that it requires only about 5% of energy consumed to produce it from bauxite. The aluminum recycling and production process causes the emission of pollutants such as dioxides and furans, hydrogen chloride, and particulate matter. To control these emissions, aluminum recyclers are required to comply with the National Emission Standards for Hazardous Air Pollutants for Secondary Aluminum Production. The results of technological, economic, and ecological optimization of aluminum recycling are based on the criteria function's evaluation in the modeling system.

  14. Model institutional infrastructures for recycling of photovoltaic modules

    SciTech Connect

    Moscowitz, P.D.; Reaven, J.; Fthenakis, V.M.

    1996-07-01

    This paper describes model approaches to designing an institutional infrastructure for the recycling of decommissioned photovoltaic modules; more detailed discussion of the information presented in this paper is contained in Reaven et al., (1996)[1]. The alternative approaches are based on experiences in other industries, with other products and materials. In the aluminum, scrap iron, and container glass industries, where recycling is a long-standing, even venerable practice, predominantly private, fully articulated institutional infrastructures exist. Nevertheless, even in these industries, arrangements are constantly evolving in response to regulatory changes, competition, and new technological developments. Institutional infrastructures are less settled for younger large- scale recycling industries that target components of the municipal solid waste (MSW) stream, such as cardboard and newspaper, polyethylene terephthalate (PET) and high-density polyethylene (HDPE) plastics, and textiles. In these industries the economics, markets, and technologies are rapidly changing. Finally, many other industries are developing projects to ensure that their products are recycled (and recyclable) e.g., computers, non-automotive batteries, communications equipment, motor and lubrication oil and oil filters, fluorescent lighting fixtures, automotive plastics and shredder residues, and bulk industrial chemical wastes. The lack of an an adequate recycling infrastructure, attractive end-markets, and clear the economic incentives, can be formidable impediments to a self- sustaining recycling system.

  15. Recycling and Life Cycle Issues

    SciTech Connect

    Das, Sujit

    2010-01-01

    This chapter addresses recycling and life cycle considerations related to the growing use of lightweight materials in vehicles. The chapter first addresses the benefit of a life cycle perspective in materials choice, and the role that recycling plays in reducing energy inputs and environmental impacts in a vehicle s life cycle. Some limitations of life cycle analysis and results of several vehicle- and fleet-level assessments are drawn from published studies. With emphasis on lightweight materials such as aluminum, magnesium, and polymer composites, the status of the existing recycling infrastructure and technological challenges being faced by the industry also are discussed.

  16. Condensate Recycling in Closed Plant Growth Chambers

    NASA Technical Reports Server (NTRS)

    Bledsoe, J. O.; Sager, J. C.; Fortson, R. E.

    1994-01-01

    Water used in the the Controlled Ecological Life Support System (CELSS) Breadboard Project at the Kennedy Space Center is being recycled. Condensation is collected in the air ducts, filtered and deionized, and resupplied to the system for nutrient solutions, supplemental humidification, solvents and diluents. While the system functions well from a process control standpoint, precise and accurate tracking of water movement through the system to answer plant physiological questions is not consistent. Possible causes include hardware errors, undetected vapor loss from chamber leakage, and unmeasured changes in water volume in the plant growth trays.

  17. Computer simulation of the pneumatic separator in the pneumatic-electrostatic separation system for recycling waste printed circuit boards with electronic components.

    PubMed

    Xue, Mianqiang; Xu, Zhenming

    2013-05-01

    Technologies could be integrated in different ways into automatic recycling lines for a certain kind of electronic waste according to practical requirements. In this study, a new kind of pneumatic separator with openings at the dust hooper was applied combing with electrostatic separation for recycling waste printed circuit boards. However, the flow pattern and the particles' movement behavior could not be obtained by experimental methods. To better control the separation quantity and the material size distribution, computational fluid dynamics was used to model the new pneumatic separator giving a detailed understanding of the mechanisms. Simulated results showed that the tangential velocity direction reversed with a relatively small value. Axial velocity exhibited two sharp decreases at the x axis. It is indicated that the bottom openings at the dust hopper resulted in an enormous change in the velocity profile. A new phenomenon that was named dusting was observed, which would mitigate the effect of particles with small diameter on the following electrostatic separation and avoid materials plugging caused by the waste printed circuit boards special properties effectively. The trapped materials were divided into seven grades. Experimental results showed that the mass fraction of grade 5, grade 6, and grade 7 materials were 27.54%, 15.23%, and 17.38%, respectively. Grade 1 particles' mass fraction was reduced by 80.30% compared with a traditional separator. Furthermore, the monocrystalline silicon content in silicon element in particles with a diameter of -0.091 mm was 18.9%, higher than that in the mixed materials. This study could serve as guidance for the future material flow control, automation control, waste recycling, and semiconductor storage medium destruction. PMID:23560940

  18. Insight into the adsorption of PPCPs by porous adsorbents: Effect of the properties of adsorbents and adsorbates.

    PubMed

    Zhu, Zengyin; Xie, Jiawen; Zhang, Mancheng; Zhou, Qing; Liu, Fuqiang

    2016-07-01

    Adsorption is an efficient method for removal of pharmaceuticals and personal care products (PPCPs). Magnetic resins are efficient adsorbents for water treatment and exhibit potential for PPCP removal. In this study, the magnetic hypercrosslinked resin Q100 was used for adsorption of PPCPs. The adsorption behavior of this resin was compared with those of two activated carbons, namely, Norit and F400D. Norit exhibited the fastest adsorption kinetics, followed by Q100. Norit featured a honeycomb shape and long-range ordered pore channels, which facilitated the diffusion of PPCPs. Moreover, the large average pore size of Q100 reduced diffusion resistance. The adsorbed amounts of 11 PPCPs on the three adsorbents increased with increasing adsorbate hydrophobicity. For Q100, a significant linear correlation was observed between the adsorption performance for PPCPs and hydrophobicity (logD value) of adsorbates (R(2) = 0.8951); as such, PPCPs with high logD values (>1.69) could be efficiently removed. Compared with those of Norit and F400D, the adsorption performance of Q100 was less affected by humic acid because of the dominant hydrophobic interaction. Furthermore, Q100 showed improved regeneration performance, which renders it promising for PPCP removal in practical applications. PMID:27131811

  19. Natural selection for costly nutrient recycling in simulated microbial metacommunities.

    PubMed

    Boyle, Richard A; Williams, Hywel T P; Lenton, Timothy M

    2012-11-01

    Recycling of essential nutrients occurs at scales from microbial communities to global biogeochemical cycles, often in association with ecological interactions in which two or more species utilise each others' metabolic by-products. However, recycling loops may be unstable; sequences of reactions leading to net recycling may be parasitised by side-reactions causing nutrient loss, while some reactions in any closed recycling loop are likely to be costly to participants. Here we examine the stability of nutrient recycling loops in an individual-based ecosystem model based on microbial functional types that differ in their metabolism. A supplied nutrient is utilised by a "source" functional type, generating a secondary nutrient that is subsequently used by two other types-a "mutualist" that regenerates the initial nutrient at a growth rate cost, and a "parasite" that produces a refractory waste product but does not incur any additional cost. The three functional types are distributed across a metacommunity in which separate patches are linked by a stochastic diffusive migration process. Regions of high mutualist abundance feature high levels of nutrient recycling and increased local population density leading to greater export of individuals, allowing the source-mutualist recycling loop to spread across the system. Individual-level selection favouring parasites is balanced by patch-level selection for high productivity, indirectly favouring mutualists due to the synergistic productivity benefits of the recycling loop they support. This suggests that multi-level selection may promote nutrient cycling and thereby help to explain the apparent ubiquity and stability of nutrient recycling in nature. PMID:22842011

  20. Current Status and Tasks in Development of Cable Recycling Technology

    NASA Astrophysics Data System (ADS)

    Ezure, Takashi; Goto, Kazuhiko

    This paper shows current status and tasks in development of cable recycling technology and it’s items to be solved. Electric cable recycle system has been activated especially for copper conductor recycle in Japan. Previously removed cable coverings materials were mainly land filled. But landfill capacity is decreased and limited in recent years, at the same time, recycle technology was highly developed. A cable recycle technology has 4 tasks. (1) Applying new high efficiency separation system instead of electrostatic and gravity methods to classify mixed various kind of plastics materials including recently developed ecological material (ex PE, PVC, Rubber), (2) Removing heavy metal, especially lead from PVC material, (3) Treatment of optical glass fiber core, which has possibility going to be harmful micro particles, and (4) Establishment of social recycle system for electric wire and cable. Taking action for these tasks shall be proceeded under environmentally sensitive technology together with local government, user, manufacturer, and waste-disposal company on cost performance basis.

  1. Coal liquefaction with preasphaltene recycle

    SciTech Connect

    Weimer, R.F.; Miller, R.N.

    1986-09-02

    A process is described for solvent refining coal to yield an asphaltene-rich product stream by forming a slurry of finely divided coal and a process solvent therefor, which process comprises the steps of: (1) contacting the slurry with a hydrogen-rich gas; (2) heating the slurry in the presence of the hydrogen-rich gas. (3) permitting the heated slurry to react and to dissolve at least some of the coal. (4) adding fresh hydrogen as required to form a liquefied coal slurry; (5) passing the liquefied coal slurry to a separator in which a vapor product stream and a condensed product stream are separated; (6) passing the condensed product stream to a vacuum distillation still; (7) removing from the vacuum distillation still a residual bottoms product, wherein the residual bottoms product from the still is mixed with a suitable extractions solvent and is passed to supercritical extraction system to separate an asphaltene-rich stream comprised of pentane solubles and benzene solubles from a preasphaltene-rich stream which includes solids residue material, the preasphaltene-rich stream comprised of benzene insolubles, pyridine solubles, pyridine insolubles and ash; (8) recycling at least a portion of the preasphaltene-rich stream together with the solid residue material as process solvent, with less than 10 percent of the process solvent comprising asphaltenes; (9) withdrawing the asphaltene-rich stream and passing the asphaltene-rich stream to a solvent recovery system to yield an asphaltene-rich product stream and an extraction solvent stream.

  2. Progress reported in PET recycling

    SciTech Connect

    Not Available

    1989-06-01

    The Goodyear Polyester Division has demonstrated its ability to break down polyethylene terephthalate (PET) from recycled plastic soft drink bottles and remanufacture the material into PET suitable for containers. Most people are familiar with PET in the form of lightweight, shatter resistant beverage bottles. About 20 percent of these beverage containers currently are being recycled. The recycled PET is currently used in many applications such as carpeting, pillow stuffing, sleeping bag filling, insulation for water heaters and non-food containers. This is the first step of Goodyear's increased efforts to recycle PET from containers into a material suitable for food packing. The project is extremely complex, involving sophisticated understanding of the chemical reactions involved, PET production and the technology testing protocols necessary to design a process that addresses all the technical, safety, and regulatory concerns. The research conducted so far indicated that additional processing beyond simply cleaning the shredded material, called flake, will be required to assure a quality polymer.

  3. New approaches to recycling tires

    SciTech Connect

    Spencer, R.

    1991-03-01

    Steel-belted radial tires are potentially one of the most recyclable products created by modern industry, although the potential has been barely tapped. Discarded tires pile up at an astonishing rate each year - 234 million in the US and 26 million passenger tire equivalents in Canada. They represent a mother lode of raw material waiting for modern day miners to transform them into recycled rubber, steel, fiber and energy. The tremendous increase in use of steel belted radials since the early 1970s has complicated their recyclability compared to the bias ply tire, but it has also accomplished waste reduction by tripling tire service life. Part one of this report describes processes being developed to convert tires to crumb rubber, as well as some potential uses of recycled rubber. Part two, to appear next month, will examine such uses as rubberized athletic tracks and highway asphalt.

  4. Operating A Recycling Program: A Citizen's Guide.

    ERIC Educational Resources Information Center

    Mulligan, Kevin; Powell, Jerry

    Presented are recycling program alternatives, procedures for handling and marketing recyclable materials, and suggestions for financing and publicizing a recycling operation. This publication offers a general overview of the possibilities and potential pitfalls of recycling efforts, thereby serving as a catalyst and guide for organizations wishing…

  5. You're a "What"? Recycling Coordinator

    ERIC Educational Resources Information Center

    Torpey, Elka Maria

    2011-01-01

    Recycling coordinators supervise curbside and dropoff recycling programs for municipal governments or private firms. Today, recycling is mandatory in many communities. And advancements in collection and processing methods have helped to increase the quantity of materials for which the recycling coordinator is responsible. In some communities,…

  6. The Three Rs: Reduce, Reuse, Recycle.

    ERIC Educational Resources Information Center

    Science Activities, 1991

    1991-01-01

    A student hand-out for a recycling unit defines the terms reduce, recycle, and reuse as they relate to solid waste management. Presents the characteristics of recyclable items such as yard wastes, metals, glass, and paper. Lists organizations through which more information about recycling can be obtained. (MCO)

  7. Informal electronic waste recycling: A sector review with special focus on China

    SciTech Connect

    Chi Xinwen; Streicher-Porte, Martin; Wang, Mark Y.L.; Reuter, Markus A.

    2011-04-15

    Informal recycling is a new and expanding low cost recycling practice in managing Waste Electrical and Electronic Equipment (WEEE or e-waste). It occurs in many developing countries, including China, where current gaps in environmental management, high demand for second-hand electronic appliances and the norm of selling e-waste to individual collectors encourage the growth of a strong informal recycling sector. This paper gathers information on informal e-waste management, takes a look at its particular manifestations in China and identifies some of the main difficulties of the current Chinese approach. Informal e-waste recycling is not only associated with serious environmental and health impacts, but also the supply deficiency of formal recyclers and the safety problems of remanufactured electronic products. Experiences already show that simply prohibiting or competing with the informal collectors and informal recyclers is not an effective solution. New formal e-waste recycling systems should take existing informal sectors into account, and more policies need to be made to improve recycling rates, working conditions and the efficiency of involved informal players. A key issue for China's e-waste management is how to set up incentives for informal recyclers so as to reduce improper recycling activities and to divert more e-waste flow into the formal recycling sector.

  8. Qualitative and quantitative analysis of endocytic recycling.

    PubMed

    Reineke, James B; Xie, Shuwei; Naslavsky, Naava; Caplan, Steve

    2015-01-01

    Endocytosis, which encompasses the internalization and sorting of plasma membrane (PM) lipids and proteins to distinct membrane-bound intracellular compartments, is a highly regulated and fundamental cellular process by which eukaryotic cells dynamically regulate their PM composition. Indeed, endocytosis is implicated in crucial cellular processes that include proliferation, migration, and cell division as well as maintenance of tissue homeostasis such as apical-basal polarity. Once PM constituents have been taken up into the cell, either via clathrin-dependent endocytosis (CDE) or clathrin-independent endocytosis (CIE), they typically have two fates: degradation through the late-endosomal/lysosomal pathway or returning to the PM via endocytic recycling pathways. In this review, we will detail experimental procedures that allow for both qualitative and quantitative assessment of endocytic recycling of transmembrane proteins internalized by CDE and CIE, using the HeLa cervical cancer cell line as a model system. PMID:26360033

  9. Probe for contamination detection in recyclable materials

    DOEpatents

    Taleyarkhan, Rusi

    2003-08-05

    A neutron detection system for detection of contaminants contained within a bulk material during recycling includes at least one neutron generator for neutron bombardment of the bulk material, and at least one gamma ray detector for detection of gamma rays emitted by contaminants within the bulk material. A structure for analyzing gamma ray data is communicably connected to the gamma ray detector, the structure for analyzing gamma ray data adapted. The identity and concentration of contaminants in a bulk material can also be determined. By scanning the neutron beam, discrete locations within the bulk material having contaminants can be identified. A method for recycling bulk material having unknown levels of contaminants includes the steps of providing at least one neutron generator, at least one gamma ray detector, and structure for analyzing gamma ray data, irradiating the bulk material with neutrons, and then determining the presence of at least one contaminant in the bulk material from gamma rays emitted from the bulk material.

  10. Fluorescent lamp recycling initiatives in the United States and a recycling proposal based on extended producer responsibility and product stewardship concepts.

    PubMed

    Silveira, Geraldo Tr; Chang, Shoou-Yuh

    2011-06-01

    This paper presents an overview of mercury-containing lamp (MCL) recycling initiatives currently available in the world, especially in the United States. The majority of MCLs contain mercury which is a neurotoxin, a persistent pollutant in the environment, and can bioaccumulate in the food chain. Although there are some recycling options in the United States, collection rates are still at 23% of all potential used MCLs. This shows that citizens are either indifferent to or unaware of the recycling alternatives. On the other hand, MCL recycling seems not to be a cost-effective process and, for this reason, in the United States, take-back programmes are still sponsored only by consumers or municipalities. A few retailers have recently initiated limited take-back alternatives and manufacturers have not yet supported financially any consistent recycling alternative in the country. Considering successful experiences, this paper makes a suggestion for an MCL recycling system based on the concepts of extended producer responsibility and product stewardship. A manufacturer-importer advance recycling fee is proposed to finance the collection and recycling system while a MCL-energy recycling fee supported by the energy sector creates a lamp refund process. 'PRO Lamp', a producer responsibility organization, will manage the entire system through a widespread public-private agreement. PMID:20837557

  11. Reflectivity studies on adsorbed block copolymers under shear

    SciTech Connect

    Smith, G.S.; Wages, S.; Baker, S.M.; Toprakcioglu, C.; Hadziioannou, G.

    1994-12-01

    The authors report neutron reflectivity data on (poly)styrene-(poly)ethylene oxide (PS-PEO) diblock copolymers adsorbed onto quartz from the selective solvent cyclohexane (a non-solvent for PEO and a poor solvent for PS). The PEO ``anchor block`` adsorbs strongly to form a thin layer on the quartz substrate, while the deuterated PS chains dangle into the solvent. They find that under static conditions the density profile of the PS block in a poor solvent can be well described by a Schultz function which is indicative of a polymer ``mushroom.`` Furthermore, they have studied the same system under shear at shear rates from 0--400s{sup {minus}1}. They find that there is a dramatic increase in the thickness of the PS layer under shear in cyclohexane and that the relaxation time from the shear-on profile back to the static profile is on the order of several days.

  12. Adsorbate-induced curvature and stiffening of graphene.

    PubMed

    Svatek, Simon A; Scott, Oliver R; Rivett, Jasmine P H; Wright, Katherine; Baldoni, Matteo; Bichoutskaia, Elena; Taniguchi, Takashi; Watanabe, Kenji; Marsden, Alexander J; Wilson, Neil R; Beton, Peter H

    2015-01-14

    The adsorption of the alkane tetratetracontane (TTC, C44H90) on graphene induces the formation of a curved surface stabilized by a gain in adsorption energy. This effect arises from a curvature-dependent variation of a moiré pattern due to the mismatch of the carbon-carbon separation in the adsorbed molecule and the period of graphene. The effect is observed when graphene is transferred onto a deformable substrate, which in our case is the interface between water layers adsorbed on mica and an organic solvent, but is not observed on more rigid substrates such as boron nitride. Our results show that molecular adsorption can be influenced by substrate curvature, provide an example of two-dimensional molecular self-assembly on a soft, responsive interface, and demonstrate that the mechanical properties of graphene may be modified by molecular adsorption, which is of relevance to nanomechanical systems, electronics, and membrane technology. PMID:25469625

  13. Microbiological test results of the environmental control and life support systems vapors compression distillation subsystem recycle tank components following various pretreatment protocols

    NASA Technical Reports Server (NTRS)

    Huff, Tim

    1993-01-01

    Microbiological samples were collected from the recycle tank of the vapor compression distillation (VCD) subsystem of the water recovery test at NASA MSFC following a 68-day run. The recycle tank collects rejected urine brine that was pretreated with a commercially available oxidant (Oxone) and sulfuric acid and pumps it back to the processing component of the VCD. Samples collected included a water sample and two swab samples, one from the particulate filter surface and a second from material floating on the surface of the water. No bacteria were recovered from the water sample. Both swab samples contained a spore-forming bacterium, Bacillus insolitus. A filamentous fungus was isolated from the floating material. Approximately 1 month after the pretreatment chemicals were changed to sodium hypochlorite and sulfuric acid, a swab of the particulate filter was again analyzed for microbial content. One fungus was isolated, and spore-forming bacteria were observed. These results indicate the inability of these pretreatments to inhibit surface attachment. The implications of the presence of these organisms are discussed.

  14. Size selective hydrophobic adsorbent for organic molecules

    NASA Technical Reports Server (NTRS)

    Sharma, Pramod K. (Inventor); Hickey, Gregory S. (Inventor)

    1997-01-01

    The present invention relates to an adsorbent formed by the pyrolysis of a hydrophobic silica with a pore size greater than 5 .ANG., such as SILICALITE.TM., with a molecular sieving polymer precursor such as polyfurfuryl alcohol, polyacrylonitrile, polyvinylidene chloride, phenol-formaldehyde resin, polyvinylidene difluoride and mixtures thereof. Polyfurfuryl alcohol is the most preferred. The adsorbent produced by the pyrolysis has a silicon to carbon mole ratio of between about 10:1 and 1:3, and preferably about 2:1 to 1:2, most preferably 1:1. The pyrolysis is performed as a ramped temperature program between about 100.degree. and 800.degree. C., and preferably between about 100.degree. and 600.degree. C. The present invention also relates to a method for selectively adsorbing organic molecules having a molecular size (mean molecular diameter) of between about 3 and 6 .ANG. comprising contacting a vapor containing the small organic molecules to be adsorbed with the adsorbent composition of the present invention.

  15. Recycling of aluminum cans. (Latest citations from the Aluminum Industry Abstracts database). Published Search

    SciTech Connect

    Not Available

    1994-06-01

    The bibliography contains citations concerning systems used for aluminum can recycling. Current developments, recycling markets, and projections from the United States, Europe, and Asia are covered. New separation systems and equipment are reviewed as well as the use of paper in the manufacture of cans to make them more recyclable. (Contains a minimum of 193 citations and includes a subject term index and title list.)

  16. Corporate America urges consumers to buy recycled

    SciTech Connect

    Rabasca, L.

    1995-04-01

    The National Recycling Coalition`s (NRC, Washington, DC) buy Recycled Business Alliance (BRBA), the US EPA`s WasteWi$e program, and the US Conference of Mayors` (Washington, DC) buy-recycled program are just a few of the national groups that have formed since 1990 to encourage the purchase of products made from recyclables. Indeed, corporate America and governments are buying recycled. More than $1 billion worth of recycled-content products have been bought by McDonald`s Corp. since 1990. The nearly 950 members of the BRBA reported spending $9.1 billion on recycled-content products in 1993. State governments reported in 1993 that they had spent more than $600 million on recycled products. Several states, cities, and counties have adopted buy-recycled executive orders. Now, many of these companies and government officials are urging consumers to use their own purchasing power to spur markets for recyclables.

  17. Recycling microbial lipid production wastes to cultivate oleaginous yeasts.

    PubMed

    Yang, Xiaobing; Jin, Guojie; Gong, Zhiwei; Shen, Hongwei; Bai, Fengwu; Zhao, Zongbao Kent

    2015-01-01

    To reduce wastes and the costs of microbial lipid production, it is imperative to recycle resources, including spent cell mass, mineral nutrients and water. In the present study, lipid production by the oleaginous yeast Rhodosporidium toruloides was used as a model system to demonstrate resources recycling. It was found that the hydrolysates of spent cell mass were good media to support cell growth of various oleaginous yeasts. When serial repitching experiments were performed using 70g/L glucose and the hydrolysates alone as nutrients, it produced 16.6, 14.6 and 12.9g/L lipids, for three successive cycles, while lipid titre remained almost constant when spent water was also recycled. The cell mass hydrolysates could be used as equivalents to the mixture of yeast extract and peptone to support lipid production from corn stalk hydrolysates. Our results showed efficient recycling of lipid production wastes and should be helpful to advance microbial lipid technology. PMID:25459808

  18. Physical/chemical closed-loop water-recycling

    NASA Technical Reports Server (NTRS)

    Herrmann, Cal C.; Wydeven, Theodore

    1991-01-01

    Water needs, water sources, and means for recycling water are examined in terms appropriate to the water quality requirements of a small crew and spacecraft intended for long duration exploration missions. Inorganic, organic, and biological hazards are estimated for waste water sources. Sensitivities to these hazards for human uses are estimated. The water recycling processes considered are humidity condensation, carbon dioxide reduction, waste oxidation, distillation, reverse osmosis, pervaporation, electrodialysis, ion exchange, carbon sorption, and electrochemical oxidation. Limitations and applications of these processes are evaluated in terms of water quality objectives. Computerized simulation of some of these chemical processes is examined. Recommendations are made for development of new water recycling technology and improvement of existing technology for near term application to life support systems for humans in space. The technological developments are equally applicable to water needs on Earth, in regions where extensive water recycling is needed or where advanced water treatment is essential to meet EPA health standards.

  19. Recyclable organic solar cells on substrates comprising cellulose nanocrystals (CNC)

    DOEpatents

    Kippelen, Bernard; Fuentes-Hernandez, Canek; Zhou, Yinhua; Moon, Robert; Youngblood, Jeffrey P

    2015-12-01

    Recyclable organic solar cells are disclosed herein. Systems and methods are further disclosed for producing, improving performance, and for recycling the solar cells. In certain example embodiments, the recyclable organic solar cells disclosed herein include: a first electrode; a second electrode; a photoactive layer disposed between the first electrode and the second electrode; an interlayer comprising a Lewis basic oligomer or polymer disposed between the photoactive layer and at least a portion of the first electrode or the second electrode; and a substrate disposed adjacent to the first electrode or the second electrode. The interlayer reduces the work function associated with the first or second electrode. In certain example embodiments, the substrate comprises cellulose nanocrystals that can be recycled. In certain example embodiments, one or more of the first electrode, the photoactive layer, and the second electrode may be applied by a film transfer lamination method.

  20. Selective Gas Capture Ability of Gas-Adsorbent-Incorporated Cellulose Nanofiber Films.

    PubMed

    Shah, Kinjal J; Imae, Toyoko

    2016-05-01

    The 2,2,6,6-tetramethylpiperidine-1-oxyl radical-oxidized cellulose nanofibers (TOCNF) were hybridized with cation and anion-exchange organoclays, where poly(amido amine) dendrimers were loaded to enhance the functionality of gas adsorption, since dendrimers have the high adsorbability and the enough selectivity on the gas adsorption. The thin films were prepared from the organoclay-TOCNF hybrids and supplied to the gas adsorption. The adsorption of CO2 and NH3 gases increased with an increasing amount of organoclays in TOCNF films, but the behavior of the increase depended on gases, clays, and dendrimers. The hydrotalcite organoclay-TOCNF films displayed the highest adsorption of both gases, but the desorption of CO2 gas from hydrotalcite organoclay-TOCNF films was drastically high in comparison with the other systems. While the CO2 gas is adsorbed and remained on cationic dendrimer sites in cation-exchange organoclay-TOCNF films, the CO2 gas is adsorbed on cationic clay sites in anion exchange organoclay-TOCNF films, and it is easily desorbed from the films. The NH3 adsorption is inversive to the CO2 adsorption. Then the CO2 molecules adsorbed on the cationic dendrimers and the NH3 molecules adsorbed on the anionic dendrimers are preferably captured in these adsorbents. The present research incorporated dendrimers will be contributing to the development of gas-specialized adsorbents, which are selectively storable only in particular gases. PMID:27035217