1988-07-15
Infrared Study of the Adsorption of Isoquinoline at a Stationary Mercury Electrode by DJ. Blackwood and S. Pons Prepared for publication in J...Secunt ClaMwfkation) An in situ Surface Fourier Transform Infrared Study of the Adsorption of Isoquinoline at a Stationary Mercury Electrode D.lc...SUBJECT TERMS (Continue on roverse if necessary and identify by block ’e’ 9ELD I GROUP I SUB-GROUP infrared spectroelectrochemistry ,adsorption, mercury I
Steerable Discrete Fourier Transform
NASA Astrophysics Data System (ADS)
Fracastoro, Giulia; Magli, Enrico
2017-03-01
Directional transforms have recently raised a lot of interest thanks to their numerous applications in signal compression and analysis. In this letter, we introduce a generalization of the discrete Fourier transform, called steerable DFT (SDFT). Since the DFT is used in numerous fields, it may be of interest in a wide range of applications. Moreover, we also show that the SDFT is highly related to other well-known transforms, such as the Fourier sine and cosine transforms and the Hilbert transforms.
Fourier Transform Mass Spectrometry.
ERIC Educational Resources Information Center
Gross, Michael L.; Rempel, Don L.
1984-01-01
Discusses the nature of Fourier transform mass spectrometry and its unique combination of high mass resolution, high upper mass limit, and multichannel advantage. Examines its operation, capabilities and limitations, applications (ion storage, ion manipulation, ion chemistry), and future applications and developments. (JN)
Carneiro, Cristine E A; de Santana, Henrique; Casado, Clara; Coronas, Joaquin; Zaia, Dimas A M
2011-06-01
Minerals adsorb more amino acids with charged R-groups than amino acids with uncharged R-groups. Thus, the peptides that form from the condensation of amino acids on the surface of minerals should be composed of amino acid residues that are more charged than uncharged. However, most of the amino acids (74%) in today's proteins have an uncharged R-group. One mechanism with which to solve this paradox is the use of organophilic minerals such as zeolites. Over the range of pH (pH 2.66-4.50) used in these experiments, the R-group of histidine (His) is positively charged and neutral for alanine (Ala), cysteine (Cys), and methionine (Met). In acidic hydrothermal environments, the pH could be even lower than those used in this study. For the pH range studied, the zeolites were negatively charged, and the overall charge of all amino acids was positive. The conditions used here approximate those of prebiotic Earth. The most important finding of this work is that the relative concentrations of each amino acid (X=His, Met, Cys) to alanine (X/Ala) are close to 1.00. This is an important result with regard to prebiotic chemistry because it could be a solution for the paradox stated above. Pore size did not affect the adsorption of Cys and Met on zeolites, and the Si/Al ratio did not affect the adsorption of Cys, His, and Met. ZSM-5 could be used for the purification of Cys from other amino acids (Student-Newman-Keuls test, p<0.05), and mordenite could be used for separation of amino acids from each other (Student-Newman-Keuls test, p<0.05). As shown by Fourier transform infrared (FT-IR) spectra, Ala interacts with zeolites through the [Formula: see text] group, and methionine-zeolite interactions involve the COO, [Formula: see text], and CH(3) groups. FT-IR spectra show that the interaction between the zeolites and His is weak. Cys showed higher adsorption on all zeolites; however, the hydrophobic Van der Waals interaction between zeolites and Cys is too weak to produce any
NASA Astrophysics Data System (ADS)
Carneiro, Cristine E. A.; de Santana, Henrique; Casado, Clara; Coronas, Joaquin; Zaia, Dimas A. M.
2011-06-01
Minerals adsorb more amino acids with charged R-groups than amino acids with uncharged R-groups. Thus, the peptides that form from the condensation of amino acids on the surface of minerals should be composed of amino acid residues that are more charged than uncharged. However, most of the amino acids (74%) in today's proteins have an uncharged R-group. One mechanism with which to solve this paradox is the use of organophilic minerals such as zeolites. Over the range of pH (pH 2.66-4.50) used in these experiments, the R-group of histidine (His) is positively charged and neutral for alanine (Ala), cysteine (Cys), and methionine (Met). In acidic hydrothermal environments, the pH could be even lower than those used in this study. For the pH range studied, the zeolites were negatively charged, and the overall charge of all amino acids was positive. The conditions used here approximate those of prebiotic Earth. The most important finding of this work is that the relative concentrations of each amino acid (X=His, Met, Cys) to alanine (X/Ala) are close to 1.00. This is an important result with regard to prebiotic chemistry because it could be a solution for the paradox stated above. Pore size did not affect the adsorption of Cys and Met on zeolites, and the Si/Al ratio did not affect the adsorption of Cys, His, and Met. ZSM-5 could be used for the purification of Cys from other amino acids (Student-Newman-Keuls test, p<0.05), and mordenite could be used for separation of amino acids from each other (Student-Newman-Keuls test, p<0.05). As shown by Fourier transform infrared (FT-IR) spectra, Ala interacts with zeolites through the group, and methionine-zeolite interactions involve the COO, , and CH3 groups. FT-IR spectra show that the interaction between the zeolites and His is weak. Cys showed higher adsorption on all zeolites; however, the hydrophobic Van der Waals interaction between zeolites and Cys is too weak to produce any structural changes in the Cys groups (amine
NASA Technical Reports Server (NTRS)
Alexandrov, Mikhail D.; Cairns, Brian; Mishchenko, Michael I.
2012-01-01
We present a novel technique for remote sensing of cloud droplet size distributions. Polarized reflectances in the scattering angle range between 135deg and 165deg exhibit a sharply defined rainbow structure, the shape of which is determined mostly by single scattering properties of cloud particles, and therefore, can be modeled using the Mie theory. Fitting the observed rainbow with such a model (computed for a parameterized family of particle size distributions) has been used for cloud droplet size retrievals. We discovered that the relationship between the rainbow structures and the corresponding particle size distributions is deeper than it had been commonly understood. In fact, the Mie theory-derived polarized reflectance as a function of reduced scattering angle (in the rainbow angular range) and the (monodisperse) particle radius appears to be a proxy to a kernel of an integral transform (similar to the sine Fourier transform on the positive semi-axis). This approach, called the rainbow Fourier transform (RFT), allows us to accurately retrieve the shape of the droplet size distribution by the application of the corresponding inverse transform to the observed polarized rainbow. While the basis functions of the proxy-transform are not exactly orthogonal in the finite angular range, this procedure needs to be complemented by a simple regression technique, which removes the retrieval artifacts. This non-parametric approach does not require any a priori knowledge of the droplet size distribution functional shape and is computationally fast (no look-up tables, no fitting, computations are the same as for the forward modeling).
Fourier Transform Spectrometer System
NASA Technical Reports Server (NTRS)
Campbell, Joel F. (Inventor)
2014-01-01
A Fourier transform spectrometer (FTS) data acquisition system includes an FTS spectrometer that receives a spectral signal and a laser signal. The system further includes a wideband detector, which is in communication with the FTS spectrometer and receives the spectral signal and laser signal from the FTS spectrometer. The wideband detector produces a composite signal comprising the laser signal and the spectral signal. The system further comprises a converter in communication with the wideband detector to receive and digitize the composite signal. The system further includes a signal processing unit that receives the composite signal from the converter. The signal processing unit further filters the laser signal and the spectral signal from the composite signal and demodulates the laser signal, to produce velocity corrected spectral data.
NASA Astrophysics Data System (ADS)
Zhang, Zhenxin; Huang, Kaijin; Yuan, Fangli; Xie, Changsheng
2014-05-01
The detection of trichloroethylene has attracted much attention because it has an important effect on human health. The sensitivity of the SnO2 flat-type coplanar gas sensor arrays to 100 ppm trichloroethylene in air was investigated. The adsorption and surface reactions of trichloroethylene were investigated at 100-200 °C by in-situ diffuse reflection Fourier transform infrared spectroscopy (DIRFTS) on SnO2 films. Molecularly adsorbed trichloroethylene, dichloroacetyl chloride (DCAC), phosgene, HCl, CO, H2O, CHCl3, Cl2 and CO2 surface species are formed during trichloroethylene adsorption at 100-200 °C. A possible mechanism of the reaction process is discussed.
Tang, Xiao-Lin; Shi, Li
2011-10-04
This work mainly involved the investigation of the adsorption of thiophene on Cu(I)-supported HY-Al(2)O(3). It demonstrated a high sulfur capacity of 10 mg sulfur/g sorbent when the HY/Al(2)O(3) mass ratio was 3, loaded with 12% copper, calcined at 550 °C, and tested at ambient temperature. In situ Fourier transform infrared (FTIR) and temperature-programmed desorption (TPD) results indicated that the adsorption mechanisms on Cu(I)/HY-Al(2)O(3) primarily were π-complexation and sulfur-adsorbent (S-M; σ) bonds. Pyridine-FTIR showed the total weak Lewis acid contribution to the Cu(I)/HY-Al(2)O(3) adsorption desulfurization performance.
Canhisares-Filho, José E; Carneiro, Cristine E A; de Santana, Henrique; Urbano, Alexandre; da Costa, Antonio C S; Zaia, Cássia T B V; Zaia, Dimas A M
2015-09-01
Minerals could have played an important role in concentration, protection, and polymerization of biomolecules. Although iron is the fourth most abundant element in Earth's crust, there are few works in the literature that describe the use of iron oxide-hydroxide in prebiotic chemistry experiments. In the present work, the interaction of adenine, thymine, and uracil with ferrihydrite was studied under conditions that resemble those of prebiotic Earth. At acidic pH, anions in artificial seawater decreased the pH at the point of zero charge (pHpzc) of ferrihydrite; and at basic pH, cations increased the pHpzc. The adsorption of nucleic acid bases onto ferrihydrite followed the order adenine > uracil > thymine. Adenine adsorption peaked at neutral pH; however, for thymine and uracil, adsorption increased with increasing pH. Electrostatic interactions did not appear to play an important role on the adsorption of nucleic acid bases onto ferrihydrite. Adenine adsorption onto ferrihydrite was higher in distilled water compared to artificial seawater. After ferrihydrite was mixed with artificial seawaters or nucleic acid bases, X-ray diffractograms and Fourier transform infrared spectra did not show any change. Surface-enhanced Raman spectroscopy showed that the interaction of adenine with ferrihydrite was not pH-dependent. In contrast, the interactions of thymine and uracil with ferrihydrite were pH-dependent such that, at basic pH, thymine and uracil lay flat on the surface of ferrihydrite, and at acidic pH, thymine and uracil were perpendicular to the surface. Ferrihydrite adsorbed much more adenine than thymine; thus adenine would have been better protected against degradation by hydrolysis or UV radiation on prebiotic Earth.
Converging beam optical Fourier transforms
NASA Astrophysics Data System (ADS)
Puang-ngern, Srisuda; Almeida, Silverio P.
1985-08-01
The classical, most often used, system for performing the optical Fourier transform is by using parallel coherent beam illumination. Lenses used in this method can become quite costly. In this paper we present results obtained using converging beam illumination which is suitable for many applications and is less expensive than the parallel beam method. The input objects for which the Fourier transforms were made are transparencies of snowflakes.
Lee, Yung Ting; Lin, Jyh Shing
2013-12-05
The reaction dynamics of ethylene adsorption onto the Si(001) surface have been studied by combining density functional theory-based molecular dynamics simulations with molecular adsorption sampling scheme for investigating all kinds of reaction pathways and corresponding populations. Based on the calculated results, three possible reaction pathways--the indirect adsorption, the direct adsorption, and the repelling reaction--have been found. First, the indirect adsorption, in which the ethylene (C2H(4(ads))) forms the π-bonded C2H(4(ads)) with the buckled-down Si atom to adsorb on the Si(001) surface and then turns into the di-σ-bonded C2H(4(ads)), is the major reaction pathway. The short-time Fourier transform analysis of structural coordinate autocorrelation function is performed to further investigate the evolution of different vibrational modes along this indirect reaction pathway. This analysis illustrates that the Infrared (IR) inactive peak of the C=C stretching mode of the π-bonded C2 H4(ads) shifts to the IR inactive peak of the C-C stretching mode of di-σ-bonded C2H(4(ads)), which is in a good agreement with the IR inactive peak of the C=C stretching mode vanished in the vibrational spectrum at 150 K (Nagao et al., J. Am. Chem. Soc. 2004, 126, 9922). Second, the direct adsorption, in which the di-σ-bonded C2H(4(ads)) is formed directly with the Si intradimer or the Si interdimer on the Si(001) surface, is the less significant reaction pathway. This reaction pathway leads to the C-C stretching mode and the C-H stretching mode of the di-σ-bonded C2H(4(ads)) appeared in the vibrational spectra at 48 and 150 K, respectively (Nagao et al., J. Am. Chem. Soc. 2004, 126, 9922). Finally, the repelling reaction, in which the C2H(4(g)) first interacts with the Si dimer and then is repelled by Si atoms, is the least important reaction pathway. Consequently, neither the π-bonded C2H(4(ads)) nor the di-σ-bonded C2H(4(ads)) is formed on the Si(001) surface.
Tantipolphan, R; Rades, T; McQuillan, A J; Medlicott, N J
2007-06-07
The adsorption of bovine serum albumin (BSA) to lecithin was investigated by ATR-FTIR spectroscopy. Lecithin films were prepared by casting aliquots of 3.2 microg lecithin in methanol onto ZnSe ATR prisms. Surface morphology and the thickness of the films were investigated by laser scanning confocal electron microscopy and scanning electron microscopy and the thickness of the films used for adsorption studies was estimated to be 40 A. The dependency of the CO peak area on the lecithin mass in the calibration curve confirms that the thickness of the film is below the penetration depth of the infrared evanescent wave. Size exclusion HPLC and fluorescence spectroscopy show that BSA conformation in up to 1M NaCl and CaCl(2) solutions is similar to that in water with no aggregation or changes in protein conformation seen over 4h. The kinetics of BSA adsorption on the lecithin film from water, NaCl and CaCl(2) solutions demonstrates that ions promote the protein adsorption. BSA bound more in the presence of NaCl compared to CaCl(2) at equivalent concentrations. The adsorption appeared greatest at a 0.1M concentration for both NaCl and CaCl(2). The results are explained in terms of absorptive reactivity of BSA and lecithin surfaces upon salt addition.
Synthetic Fourier transform light scattering.
Lee, Kyeoreh; Kim, Hyeon-Don; Kim, Kyoohyun; Kim, Youngchan; Hillman, Timothy R; Min, Bumki; Park, Yongkeun
2013-09-23
We present synthetic Fourier transform light scattering, a method for measuring extended angle-resolved light scattering (ARLS) from individual microscopic samples. By measuring the light fields scattered from the sample plane and numerically synthesizing them in Fourier space, the angle range of the ARLS patterns is extended up to twice the numerical aperture of the imaging system with unprecedented sensitivity and precision. Extended ARLS patterns of individual microscopic polystyrene beads, healthy human red blood cells (RBCs), and Plasmodium falciparum-parasitized RBCs are presented.
ERIC Educational Resources Information Center
Debnath, Lokenath
2012-01-01
This article deals with a brief biographical sketch of Joseph Fourier, his first celebrated work on analytical theory of heat, his first great discovery of Fourier series and Fourier transforms. Included is a historical development of Fourier series and Fourier transforms with their properties, importance and applications. Special emphasis is made…
Fourier-transform optical microsystems
NASA Technical Reports Server (NTRS)
Collins, S. D.; Smith, R. L.; Gonzalez, C.; Stewart, K. P.; Hagopian, J. G.; Sirota, J. M.
1999-01-01
The design, fabrication, and initial characterization of a miniature single-pass Fourier-transform spectrometer (FTS) that has an optical bench that measures 1 cm x 5 cm x 10 cm is presented. The FTS is predicated on the classic Michelson interferometer design with a moving mirror. Precision translation of the mirror is accomplished by microfabrication of dovetailed bearing surfaces along single-crystal planes in silicon. Although it is miniaturized, the FTS maintains a relatively high spectral resolution, 0.1 cm-1, with adequate optical throughput.
Fourier Transform Methods. Chapter 4
NASA Technical Reports Server (NTRS)
Kaplan, Simon G.; Quijada, Manuel A.
2015-01-01
This chapter describes the use of Fourier transform spectrometers (FTS) for accurate spectrophotometry over a wide spectral range. After a brief exposition of the basic concepts of FTS operation, we discuss instrument designs and their advantages and disadvantages relative to dispersive spectrometers. We then examine how common sources of error in spectrophotometry manifest themselves when using an FTS and ways to reduce the magnitude of these errors. Examples are given of applications to both basic and derived spectrophotometric quantities. Finally, we give recommendations for choosing the right instrument for a specific application, and how to ensure the accuracy of the measurement results..
The Fourier Transform on Quantum Euclidean Space
NASA Astrophysics Data System (ADS)
Coulembier, Kevin
2011-05-01
We study Fourier theory on quantum Euclidean space. A modified version of the general definition of the Fourier transform on a quantum space is used and its inverse is constructed. The Fourier transforms can be defined by their Bochner's relations and a new type of q-Hankel transforms using the first and second q-Bessel functions. The behavior of the Fourier transforms with respect to partial derivatives and multiplication with variables is studied. The Fourier transform acts between the two representation spaces for the harmonic oscillator on quantum Euclidean space. By using this property it is possible to define a Fourier transform on the entire Hilbert space of the harmonic oscillator, which is its own inverse and satisfies the Parseval theorem.
Fourier Analysis and Structure Determination: Part I: Fourier Transforms.
ERIC Educational Resources Information Center
Chesick, John P.
1989-01-01
Provides a brief introduction with some definitions and properties of Fourier transforms. Shows relations, ways of understanding the mathematics, and applications. Notes proofs are not included but references are given. First of three part series. (MVL)
Dual Comb Fourier Transform Spectroscopy
NASA Astrophysics Data System (ADS)
Hänsch, T. W.; Picqué, N.
2010-06-01
The advent of laser frequency combs a decade ago has already revolutionized optical frequency metrology and precision spectroscopy. Extensions of laser combs from the THz region to the extreme ultraviolet and soft x-ray frequencies are now under exploration. Such laser combs have become enabling tools for a growing tree of applications, from optical atomic clocks to attosecond science. Recently, the millions of precisely controlled laser comb lines that can be produced with a train of ultrashort laser pulses have been harnessed for highly multiplexed molecular spectroscopy. Fourier multi-heterodyne spectroscopy, dual comb spectroscopy, or asynchronous optical sampling spectroscopy with frequency combs are emerging as powerful new spectroscopic tools. Even the first proof-of-principle experiments have demonstrated a very exciting potential for ultra-rapid and ultra-sensitive recording of complex molecular spectra. Compared to conventional Fourier transform spectroscopy, recording times could be shortened from seconds to microseconds, with intriguing prospects for spectroscopy of short lived transient species. Longer recording times allow high resolution spectroscopy of molecules with extreme precision, since the absolute frequency of each laser comb line can be known with the accuracy of an atomic clock. The spectral structure of sharp lines of a laser comb can be very useful even in the recording of broadband spectra without sharp features, as they are e.g. encountered for molecular gases or in the liquid phase. A second frequency comb of different line spacing permits the generation of a comb of radio frequency beat notes, which effectively map the optical spectrum into the radio frequency regime, so that it can be recorded with a single fast photodetector, followed by digital signal analysis. In the time domain, a pulse train of a mode-locked femtosecond laser excites some molecular medium at regular time intervals. A second pulse train of different repetition
Kang, Jin; Liu, Huijuan; Zheng, Yu-Ming; Qu, Jiuhui; Chen, J Paul
2011-02-01
Extensive usage of tetracycline has resulted in its contamination in surface water and groundwater. The adsorption of tetracycline on zeolite beta was systematically investigated for the decontamination of the antibiotic polluted water in this study. Ninety percent of uptake by the zeolite beta occured in 0.25h, and the adsorption equilibrium was obtained within 3h, which was well described by an intraparticle diffusion model. The adsorption generally increased when pH was increased from 4.0 to 5.0, and then decreased significantly as the pH was further increased, which was caused by the pH-dependent speciation of tetracycline and surface charge of zeolite beta. Both Freundlich and Langmuir equations well described the adsorption isotherm. A thermodynamic analysis showed that the sorption process was spontaneous and endothermic. Aluminum atoms in the zeolite played a crucial role in the uptake; the adsorption increased with the increasing aluminum content in zeolite. The UV-Visible spectroscopy study showed that the spectra of tetracycline changed upon the interaction with zeolite beta, which could be ascribed to the formation of complexes of tetracycline and aluminum atoms in the zeolite surface. Nuclear magnetic resonance spectroscopy study further confirmed the participation of Al in the tetracycline adsorption. Fourier transform infrared spectroscopy studies showed that the amino functional groups in tetracycline were involved in the complexation with the zeolite surface.
The Geostationary Fourier Transform Spectrometer
NASA Astrophysics Data System (ADS)
Key, Richard; Sander, Stanley; Eldering, Annmarie; Blavier, Jean-Francois; Bekker, Dmitriy; Manatt, Kenneth; Rider, David; Wu, Yen-Hung (James)
2012-09-01
The Geostationary Fourier Transform Spectrometer (GeoFTS) is an imaging spectrometer designed for a geostationary orbit (GEO) earth science mission to measure key atmospheric trace gases and process tracers related to climate change and human activity. GEO allows GeoFTS to continuously stare at a region of the earth for frequent sampling to capture the variability of biogenic fluxes and anthropogenic emissions from city to continental spatial scales and temporal scales from diurnal, synoptic, seasonal to interannual. The measurement strategy provides a process based understanding of the carbon cycle from contiguous maps of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and chlorophyll fluorescence (CF) collected many times per day at high spatial resolution (~2.7km×2.7km at nadir). The CO2/CH4/CO/CF measurement suite in the near infrared spectral region provides the information needed to disentangle natural and anthropogenic contributions to atmospheric carbon concentrations and to minimize uncertainties in the flow of carbon between the atmosphere and surface. The half meter cube size GeoFTS instrument is based on a Michelson interferometer design that uses all high TRL components in a modular configuration to reduce complexity and cost. It is self-contained and as independent of the spacecraft as possible with simple spacecraft interfaces, making it ideal to be a "hosted" payload on a commercial communications satellite mission. The hosted payload approach for measuring the major carbon-containing gases in the atmosphere from the geostationary vantage point will affordably advance the scientific understating of carbon cycle processes and climate change.
The Geostationary Fourier Transform Spectrometer
NASA Technical Reports Server (NTRS)
Key, Richard; Sander, Stanley; Eldering, Annmarie; Blavier, Jean-Francois; Bekker, Dmitriy; Manatt, Ken; Rider, David; Wu, Yen-Hung
2012-01-01
The Geostationary Fourier Transform Spectrometer (GeoFTS) is an imaging spectrometer designed for a geostationary orbit (GEO) earth science mission to measure key atmospheric trace gases and process tracers related to climate change and human activity. GEO allows GeoFTS to continuously stare at a region of the earth for frequent sampling to capture the variability of biogenic fluxes and anthropogenic emissions from city to continental spatial scales and temporal scales from diurnal, synoptic, seasonal to interannual. The measurement strategy provides a process based understanding of the carbon cycle from contiguous maps of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and chlorophyll fluorescence (CF) collected many times per day at high spatial resolution (2.7kmx2.7km at nadir). The CO2/CH4/CO/CF measurement suite in the near infrared spectral region provides the information needed to disentangle natural and anthropogenic contributions to atmospheric carbon concentrations and to minimize uncertainties in the flow of carbon between the atmosphere and surface. The half meter cube size GeoFTS instrument is based on a Michelson interferometer design that uses all high TRL components in a modular configuration to reduce complexity and cost. It is self-contained and as independent of the spacecraft as possible with simple spacecraft interfaces, making it ideal to be a "hosted" payload on a commercial communications satellite mission. The hosted payload approach for measuring the major carbon-containing gases in the atmosphere from the geostationary vantage point will affordably advance the scientific understating of carbon cycle processes and climate change.
The Geostationary Fourier Transform Spectrometer
NASA Technical Reports Server (NTRS)
Key, Richard; Sander, Stanley; Eldering, Annmarie; Miller, Charles; Frankenberg, Christian; Natra, Vijay; Rider, David; Blavier, Jean-Francois; Bekker, Dmitriy; Wu, Yen-Hung
2012-01-01
The Geostationary Fourier Transform Spectrometer (GeoFTS) is an imaging spectrometer designed for an earth science mission to measure key atmospheric trace gases and process tracers related to climate change and human activity. The GeoFTS instrument is a half meter cube size instrument designed to operate in geostationary orbit as a secondary "hosted" payload on a commercial geostationary satellite mission. The advantage of GEO is the ability to continuously stare at a region of the earth, enabling frequent sampling to capture the diurnal variability of biogenic fluxes and anthropogenic emissions from city to continental scales. The science goal is to obtain a process-based understanding of the carbon cycle from simultaneous high spatial resolution measurements of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and chlorophyll fluorescence (CF) many times per day in the near infrared spectral region to capture their spatial and temporal variations on diurnal, synoptic, seasonal and interannual time scales. The GeoFTS instrument is based on a Michelson interferometer design with a number of advanced features incorporated. Two of the most important advanced features are the focal plane arrays and the optical path difference mechanism. A breadboard GeoFTS instrument has demonstrated functionality for simultaneous measurements in the visible and IR in the laboratory and subsequently in the field at the California Laboratory for Atmospheric Remote Sensing (CLARS) observatory on Mt. Wilson overlooking the Los Angeles basin. A GeoFTS engineering model instrument is being developed which will make simultaneous visible and IR measurements under space flight like environmental conditions (thermal-vacuum at 180 K). This will demonstrate critical instrument capabilities such as optical alignment stability, interferometer modulation efficiency, and high throughput FPA signal processing. This will reduce flight instrument development risk and show that the Geo
Quantum Fourier transform in computational basis
NASA Astrophysics Data System (ADS)
Zhou, S. S.; Loke, T.; Izaac, J. A.; Wang, J. B.
2017-03-01
The quantum Fourier transform, with exponential speed-up compared to the classical fast Fourier transform, has played an important role in quantum computation as a vital part of many quantum algorithms (most prominently, Shor's factoring algorithm). However, situations arise where it is not sufficient to encode the Fourier coefficients within the quantum amplitudes, for example in the implementation of control operations that depend on Fourier coefficients. In this paper, we detail a new quantum scheme to encode Fourier coefficients in the computational basis, with fidelity 1 - δ and digit accuracy ɛ for each Fourier coefficient. Its time complexity depends polynomially on log (N), where N is the problem size, and linearly on 1/δ and 1/ɛ . We also discuss an application of potential practical importance, namely the simulation of circulant Hamiltonians.
Linear and nonlinear generalized Fourier transforms.
Pelloni, Beatrice
2006-12-15
This article presents an overview of a transform method for solving linear and integrable nonlinear partial differential equations. This new transform method, proposed by Fokas, yields a generalization and unification of various fundamental mathematical techniques and, in particular, it yields an extension of the Fourier transform method.
A Short-Segment Fourier Transform Methodology
2009-03-01
defined sampling of the continuous-valued discrete-time Fourier transform, superresolution in the frequency domain and allowance of Dirac delta functions associated with pure sinusoidal input data components.
Geometric Representations for Discrete Fourier Transforms
NASA Technical Reports Server (NTRS)
Cambell, C. W.
1986-01-01
Simple geometric representations show symmetry and periodicity of discrete Fourier transforms (DFT's). Help in visualizing requirements for storing and manipulating transform value in computations. Representations useful in any number of dimensions, but particularly in one-, two-, and three-dimensional cases often encountered in practice.
Implementation of quantum and classical discrete fractional Fourier transforms.
Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N; Szameit, Alexander
2016-03-23
Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools.
Implementation of quantum and classical discrete fractional Fourier transforms
Weimann, Steffen; Perez-Leija, Armando; Lebugle, Maxime; Keil, Robert; Tichy, Malte; Gräfe, Markus; Heilmann, René; Nolte, Stefan; Moya-Cessa, Hector; Weihs, Gregor; Christodoulides, Demetrios N.; Szameit, Alexander
2016-01-01
Fourier transforms, integer and fractional, are ubiquitous mathematical tools in basic and applied science. Certainly, since the ordinary Fourier transform is merely a particular case of a continuous set of fractional Fourier domains, every property and application of the ordinary Fourier transform becomes a special case of the fractional Fourier transform. Despite the great practical importance of the discrete Fourier transform, implementation of fractional orders of the corresponding discrete operation has been elusive. Here we report classical and quantum optical realizations of the discrete fractional Fourier transform. In the context of classical optics, we implement discrete fractional Fourier transforms of exemplary wave functions and experimentally demonstrate the shift theorem. Moreover, we apply this approach in the quantum realm to Fourier transform separable and path-entangled biphoton wave functions. The proposed approach is versatile and could find applications in various fields where Fourier transforms are essential tools. PMID:27006089
Fourier transform infrared spectrometery: an undergraduate experiment
NASA Astrophysics Data System (ADS)
Lerner, L.
2016-11-01
Simple apparatus is developed, providing undergraduate students with a solid understanding of Fourier transform (FT) infrared (IR) spectroscopy in a hands on experiment. Apart from its application to measuring the mid-IR spectra of organic molecules, the experiment introduces several techniques with wide applicability in physics, including interferometry, the FT, digital data analysis, and control theory.
Fourier Transform Spectroscopy, Eleventh International Conference. Proceedings
de Haseth, J.A.
1998-05-01
These proceedings represent the papers presented at the Eleventh International Conference on Fourier Transform Spectroscopy held in August, 1997 in Athens, Georgia, USA. The Conference provided an atmosphere for people of diverse backgrounds to congregate and exchange information. The topics discussed included applications of Fourier transform spectroscopy to surface science, biological systems, atmospheric science, forensics and textiles, etc. Biochemical and biomedical studies utilizing Fourier Transform infrared spectroscopy formed a large section of the Conference Applications to semiconductor industry, namely monitoring of CVD processes and photoresists were also discussed. Most of the applications were in the near and mid infrared, with a few extending to the far infrared and visible regions of the electromagnetic spectrum. In the Keynote Address, Fourier Transform Ion Cyloctron Resonance Spectroscopy was reviewed by Professor Alan G. Marshall of the National High Magnetic Field Laboratory in Florida. Altogether 152 papers were presented at the Conference and out of these, 15 have been abstracted for the Energy, Science and Technology database. (AIP)
Discrete Fourier transforms of nonuniformly spaced data
NASA Technical Reports Server (NTRS)
Swan, P. R.
1982-01-01
Time series or spatial series of measurements taken with nonuniform spacings have failed to yield fully to analysis using the Discrete Fourier Transform (DFT). This is due to the fact that the formal DFT is the convolution of the transform of the signal with the transform of the nonuniform spacings. Two original methods are presented for deconvolving such transforms for signals containing significant noise. The first method solves a set of linear equations relating the observed data to values defined at uniform grid points, and then obtains the desired transform as the DFT of the uniform interpolates. The second method solves a set of linear equations relating the real and imaginary components of the formal DFT directly to those of the desired transform. The results of numerical experiments with noisy data are presented in order to demonstrate the capabilities and limitations of the methods.
Dispersive Fourier transformation femtosecond stimulated Raman scattering
NASA Astrophysics Data System (ADS)
Dobner, Sven; Fallnich, Carsten
2016-11-01
We present the first proof-of-principle spectroscopic measurements with purely passive dispersive Fourier transformation femtosecond stimulated Raman scattering. In femtosecond stimulated Raman scattering, the full Raman scattering spectrum is efficiently obtained, as all Raman transitions are coherently excited with the combination of a narrow-bandwidth and a broad-bandwidth (femtosecond) pulse at once. Currently, the detection speed of the spectra is limited by the read-out time of classical, comparably slow CCD-based spectrometers. We show a reduction in the acquisition time of Raman signatures by applying the dispersive Fourier transformation, a method employing wavelength-to-time transformation, in order to record the spectral composition of a single pulse with a single fast photodiode. This arrangement leads to an acquisition time of Raman signatures, scaling inversely with the repetition frequency of the applied laser system, which in our case corresponds to the order of microseconds.
Coulibaly, Lassina Sandotin; Akpo, Sylvain Kouakou; Yvon, Jacques; Coulibaly, Lacina
2016-12-01
Environmental pollution by phosphate in developing countries is growing with extensive and diffuse pollution. Solving these problem with intensive technologies is very expensive. Using natural sorbent such as laterite and sandstone could be a solution. The main objective of the study is to evaluate the P-removal efficiency of these materials under various solution properties. Laterite and sandstone used mainly contain very high levels of finely grained iron and aluminum oxy-hydroxides and diverse dioctahedral clays. Phosphate adsorption tests were carried out using crushed laterite and sandstone. Optimal doses and pH effects on phosphate adsorption were studied with a potassium hydrogeno-phosphate solution of 5 mg/L at 30 °C. The main results were that the optimal dosage is 15 and 20 mg/L respectively for laterite and sandstone. The phosphate adsorptions efficiency of laterite and sandstone are pH-dependent, they increase when the pH grows up to the Point of Zero Charge (PZC) and slowly decrease beyond. The adsorption capacities of the materials also increase proportionally with the initial phosphate concentration. The pseudo-second-order successfully described the kinetics of the phosphate adsorption on the two adsorbents. With this model, the adsorption capacity values are obtained, which give an idea of the maximum phosphate uptake that the laterite and sandstone could achieve. The changes on the FTIR spectra of raw materials and phosphate adsorbed material confirm the mechanism of chemisorptions. Considering the above, laterite and sandstone could be used as efficient and cheap adsorbent for the removal of phosphate in aqueous solution.
Electro-optic imaging Fourier transform spectrometer
NASA Technical Reports Server (NTRS)
Chao, Tien-Hsin (Inventor); Znod, Hanying (Inventor)
2009-01-01
An Electro-Optic Imaging Fourier Transform Spectrometer (EOIFTS) for Hyperspectral Imaging is described. The EOIFTS includes an input polarizer, an output polarizer, and a plurality of birefringent phase elements. The relative orientations of the polarizers and birefringent phase elements can be changed mechanically or via a controller, using ferroelectric liquid crystals, to substantially measure the spectral Fourier components of light propagating through the EIOFTS. When achromatic switches are used as an integral part of the birefringent phase elements, the EIOFTS becomes suitable for broadband applications, with over 1 micron infrared bandwidth.
Electro-optic Imaging Fourier Transform Spectrometer
NASA Technical Reports Server (NTRS)
Chao, Tien-Hsin
2005-01-01
JPL is developing an innovative compact, low mass, Electro-Optic Imaging Fourier Transform Spectrometer (E-0IFTS) for hyperspectral imaging applications. The spectral region of this spectrometer will be 1 - 2.5 pm (1000 -4000 cm-') to allow high-resolution, high-speed hyperspectral imaging applications [l-51. One application will be theremote sensing of the measurement of a large number of different atmospheric gases simultaneously in the sameairmass. Due to the use of a combination of birefiingent phase retarders and multiple achromatic phase switches toachieve phase delay, this spectrometer is capable of hyperspectral measurements similar to that of the conventionalFourier transform spectrometer but without any moving parts. In this paper, the principle of operations, systemarchitecture and recent experimental progress will be presen.
Electro-optic Imaging Fourier Transform Spectrometer
NASA Technical Reports Server (NTRS)
Chao, Tien-Hsin
2005-01-01
JPL is developing an innovative compact, low mass, Electro-Optic Imaging Fourier Transform Spectrometer (E-O IFTS) for hyperspectral imaging applications. The spectral region of this spectrometer will be 1 - 2.5 micron (1000-4000/cm) to allow high-resolution, high-speed hyperspectral imaging applications. One application will be the remote sensing of the measurement of a large number of different atmospheric gases simultaneously in the same airmass. Due to the use of a combination of birefringent phase retarders and multiple achromatic phase switches to achieve phase delay, this spectrometer is capable of hyperspectral measurements similar to that of the conventional Fourier transform spectrometer but without any moving parts. In this paper, the principle of operations, system architecture and recent experimental progress will be presented.
Fourier Transform Fabry-Perot Interferometer
NASA Technical Reports Server (NTRS)
Snell, Hilary E.; Hays, Paul B.
1992-01-01
We are developing a compact, rugged, high-resolution remote sensing instrument with wide spectral scanning capabilities. This relatively new type of instrument, which we have chosen to call the Fourier-Transform Fabry-Perot Interferometer (FT-FPI), is accomplished by mechanically scanning the etalon plates of a Fabry-Perot interferometer (FPI) through a large optical distance while examining the concomitant signal with a Fourier-transform analysis technique similar to that employed by the Michelson interferometer. The FT-FPI will be used initially as a ground-based instrument to study near-infrared atmospheric absorption lines of trace gases using the techniques of solar absorption spectroscopy. Future plans include modifications to allow for measurements of trace gases in the stratosphere using spectral lines at terahertz frequencies.
Optical Planar Discrete Fourier and Wavelet Transforms
NASA Astrophysics Data System (ADS)
Cincotti, Gabriella; Moreolo, Michela Svaluto; Neri, Alessandro
2007-10-01
We present all-optical architectures to perform discrete wavelet transform (DWT), wavelet packet (WP) decomposition and discrete Fourier transform (DFT) using planar lightwave circuits (PLC) technology. Any compact-support wavelet filter can be implemented as an optical planar two-port lattice-form device, and different subband filtering schemes are possible to denoise, or multiplex optical signals. We consider both parallel and serial input cases. We design a multiport decoder/decoder that is able to generate/process optical codes simultaneously and a flexible logarithmic wavelength multiplexer, with flat top profile and reduced crosstalk.
NASA Astrophysics Data System (ADS)
Vélez-Rábago, Rodrigo; Solorza-Calderón, Selene; Jordan-Aramburo, Adina
2016-12-01
This work presents an image pattern recognition system invariant to translation, scale and rotation. The system uses the Fourier transform to achieve the invariance to translation and the analytical Forier-Mellin transform for the invariance to scale and rotation. According with the statistical theory of box-plots, the pattern recognition system has a confidence level at least of 95.4%.
NASA Astrophysics Data System (ADS)
Debnath, Lokenath
2012-07-01
The PROSAIC Laplace and Fourier Transform
Smith, G.A.
1994-11-01
Integral Transform methods play an extremely important role in many branches of science and engineering. The ease with which many problems may be solved using these techniques is well known. In Electrical Engineering especially, Laplace and Fourier Transforms have been used for a long time as a way to change the solution of differential equations into trivial algebraic manipulations or to provide alternate representations of signals and data. These techniques, while seemingly overshadowed by today`s emphasis on digital analysis, still form an invaluable basis in the understanding of systems and circuits. A firm grasp of the practical aspects of these subjects provides valuable conceptual tools. This tutorial paper is a review of Laplace and Fourier Transforms from an applied perspective with an emphasis on engineering applications. The interrelationship of the time and frequency domains will be stressed, in an attempt to comfort those who, after living so much of their lives in the time domain, find thinking in the frequency domain disquieting.
Fourier transform infrared spectroscopy of deuterated proteins
NASA Astrophysics Data System (ADS)
Marcano O., A.; Markushin, Y.; Melikechi, N.; Connolly, D.
2008-08-01
We report on Fourier transform spectra of deuterated proteins: Bovine Serum Albumin, Leptin, Insulin-like Growth Factor II, monoclonal antibody to ovarian cancer antigen CA125 and Osteopontin. The spectra exhibit changes in the relative amplitude and spectral width of certain peaks. New peaks not present in the non-deuterated sample are also observed. Ways for improving the deuteration of proteins by varying the temperature and dilution time are discussed. We propose the use of deuterated proteins to increase the sensitivity of immunoassays aimed for early diagnostic of diseases most notably cancer.
Phase amplitude conformal symmetry in Fourier transforms
NASA Astrophysics Data System (ADS)
Kuwata, S.
2015-04-01
For the Fourier transform ℑ : L2(R) → L2(R) of a complex-valued even or odd function ψ, it is found that the amplitude invariance |ℑψ| = |ψ| leads to a phase invariance or inversion as arg(ℑψ) = ±argψ + θ (θ = constant). The converse holds unless arg ψ = constant. The condition |ψ| = |ℑψ| is required in dealing with, for example, the minimum uncertainty relation between position and momentum. Without the evenness or oddness of ψ, |ℑψ| = |ψ| does not necessarily imply arg(ℑψ) = ±argψ + θ, nor is the converse.
Analysis method for Fourier transform spectroscopy
NASA Technical Reports Server (NTRS)
Park, J. H.
1983-01-01
A fast Fourier transform technique is given for the simulation of those distortion effects in the instrument line shape of the interferometric spectrum that are due to errors in the measured interferogram. The technique is applied to analyses of atmospheric absorption spectra and laboratory spectra. It is shown that the nonlinear least squares method can retrieve the correct information from the distorted spectrum. Analyses of HF absorption spectra obtained in a laboratory and solar CO absorption spectra gathered by a balloon-borne interferometer indicate that the retrieved amount of absorbing gas is less than the correct value in most cases, if the interferogram distortion effects are not included in the analysis.
Two-dimensional fourier transform spectrometer
DeFlores, Lauren; Tokmakoff, Andrei
2016-10-25
The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.
Two-dimensional fourier transform spectrometer
DeFlores, Lauren; Tokmakoff, Andrei
2013-09-03
The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.
Fourier transform methods in local gravity modeling
NASA Technical Reports Server (NTRS)
Harrison, J. C.; Dickinson, M.
1989-01-01
New algorithms were derived for computing terrain corrections, all components of the attraction of the topography at the topographic surface and the gradients of these attractions. These algoriithms utilize fast Fourier transforms, but, in contrast to methods currently in use, all divergences of the integrals are removed during the analysis. Sequential methods employing a smooth intermediate reference surface were developed to avoid the very large transforms necessary when making computations at high resolution over a wide area. A new method for the numerical solution of Molodensky's problem was developed to mitigate the convergence difficulties that occur at short wavelengths with methods based on a Taylor series expansion. A trial field on a level surface is continued analytically to the topographic surface, and compared with that predicted from gravity observations. The difference is used to compute a correction to the trial field and the process iterated. Special techniques are employed to speed convergence and prevent oscillations. Three different spectral methods for fitting a point-mass set to a gravity field given on a regular grid at constant elevation are described. Two of the methods differ in the way that the spectrum of the point-mass set, which extends to infinite wave number, is matched to that of the gravity field which is band-limited. The third method is essentially a space-domain technique in which Fourier methods are used to solve a set of simultaneous equations.
Fourier Transforms Simplified: Computing an Infrared Spectrum from an Interferogram
ERIC Educational Resources Information Center
Hanley, Quentin S.
2012-01-01
Fourier transforms are used widely in chemistry and allied sciences. Examples include infrared, nuclear magnetic resonance, and mass spectroscopies. A thorough understanding of Fourier methods assists the understanding of microscopy, X-ray diffraction, and diffraction gratings. The theory of Fourier transforms has been presented in this "Journal",…
On-line textile quality control using optical Fourier transforms
NASA Astrophysics Data System (ADS)
Castellini, C.; Francini, F.; Longobardi, G.; Tiribilli, B.; Sansoni, P.
Fourier transformation and spatial filtering offer the possibility of detecting structural defects in a fabric. In this paper a method based on an optical Fourier transform technique during the weaving process is described. Significant variations in the Fourier pattern occurring in the presence of defective fabric are recognised with a CCD sensor joined to an electronic hardware system performing a simple algorithm.
Fourier transform spectroscopy for future planetary missions
NASA Astrophysics Data System (ADS)
Brasunas, John; Kolasinski, John; Kostiuk, Ted; Hewagama, Tilak
2017-01-01
Thermal-emission infrared spectroscopy is a powerful tool for exploring the composition, temperature structure, and dynamics of planetary atmospheres; and the temperature of solid surfaces. A host of Fourier transform spectrometers (FTS) such as Mariner IRIS, Voyager IRIS, and Cassini CIRS from NASA Goddard have made and continue to make important new discoveries throughout the solar system. Future FTS instruments will have to be more sensitive (when we concentrate on the colder, outer reaches of the solar system), and less massive and less power-hungry as we cope with decreasing resource allotments for future planetary science instruments. With this in mind, we have developed CIRS-lite, a smaller version of the CIRS FTS for future planetary missions. We discuss the roadmap for making CIRS-lite a viable candidate for future planetary missions, including the recent increased emphasis on ocean worlds (Europa, Encelatus, Titan) and also on smaller payloads such as CubeSats and SmallSats.
Fourier transform infrared spectroscopy for Mars science
NASA Astrophysics Data System (ADS)
Anderson, Mark S.; Andringa, Jason M.; Carlson, Robert W.; Conrad, Pamela; Hartford, Wayne; Shafer, Michael; Soto, Alejandro; Tsapin, Alexandre I.; Dybwad, Jens Peter; Wadsworth, Winthrop; Hand, Kevin
2005-03-01
Presented here is a Fourier transform infrared spectrometer (FTIR) for field studies that serves as a prototype for future Mars science applications. Infrared spectroscopy provides chemical information that is relevant to a number of Mars science questions. This includes mineralogical analysis, nitrogen compound recognition, truth testing of remote sensing measurements, and the ability to detect organic compounds. The challenges and scientific opportunities are given for the in situ FTIR analysis of Mars soil and rock samples. Various FTIR sampling techniques are assessed and compared to other analytical instrumentation. The prototype instrument presented is capable of providing field analysis in a Mars analog Antarctic environment. FTIR analysis of endolithic microbial communities in Antarctic rocks and a Mars meteor are given as analytical examples.
Surface Inspection using fourier transform infrared spectroscopy
Powell, G.L.; Smyrl, N.R.; Williams, D.M.; Meyers, H.M. III; Barber, T.E.; Marrero-Rivera, M.
1994-08-08
The use of reflectance Fourier transform infrared (FTIR) spectroscopy as a tool for surface inspection is described. Laboratory instruments and portable instruments can support remote sensing probes that can map chemical contaminants on surfaces. Detection limits under the best of conditions are in the subnanometer range (i.e., near absolute cleanliness), excellent performance is obtained in the submicrometer range, and useful performance may exist for films tens of microns thick. Identifying and quantifying contamination such as mineral oils and greases, vegetable oils, and silicone oils on aluminum foil, galvanized sheet steel, smooth aluminum tubing, and gritblasted 7075 aluminum alloy and D6AC steel are described. The ability to map in time and space the distribution of oil stains on metals is demonstrated. Techniques for quantitatively applying oils to metals, subsequently verifying the application, and nonlinear relationships between reflectance and the quantity of oil are discussed.
Geometric interpretations of the Discrete Fourier Transform (DFT)
NASA Technical Reports Server (NTRS)
Campbell, C. W.
1984-01-01
One, two, and three dimensional Discrete Fourier Transforms (DFT) and geometric interpretations of their periodicities are presented. These operators are examined for their relationship with the two sided, continuous Fourier transform. Discrete or continuous transforms of real functions have certain symmetry properties. The symmetries are examined for the one, two, and three dimensional cases. Extension to higher dimension is straight forward.
Geostationary Fourier Transform Spectrometer (GeoFTS)
NASA Astrophysics Data System (ADS)
Sander, S. P.; Bekker, D. L.; Blavier, J. L.; Duren, R. M.; Eldering, A.; Frankenberg, C.; Key, R.; Manatt, K.; Miller, C. E.; Natraj, V.; Rider, D. M.; Wu, Y.
2012-12-01
In order to confidently project the future evolution of climate and support efforts to mitigate the climate change, quantifying the emissions of CO2 and CH4 is a national and international priority. To accomplish this goal, new observational approaches are required that operate over spatial scales ranging from regional to global, and temporal scales from diurnal to decadal. Geostationary satellite observations of CO2, CH4 and correlative quantities such as CO and chlorophyll fluorescence provide a new measurement approach to deliver the quantity and quality of data needed for improved flux estimates and an improved understanding of the partitioning between biogenic and anthropogenic sources. GeoFTS is an exciting new concept that combines the game changing technology of imaging Fourier Transform Spectroscopy with the observational advantages of a geostationary orbit. The GeoFTS observations enable well-posed surface-atmospheric carbon exchange assessments as well as quantify the atmospheric signatures of anthropogenic CO2 and CH4 emissions. GeoFTS uses a single instrument to make measurements in the near-infrared spectral region at high spectral resolution. The imaging FTS measures atmospheric CO2, CH4, and CO to deliver high-resolution maps multiple times per day. A half-meter-sized cube, the instrument is designed to be a secondary "hosted" payload on a commercial GEO satellite. The instrument leverages recent NASA technology investments, uses a flight-proven interferometer and sensor chip assemblies, and requires no new technology development. NASA and other government agencies have adopted the hosted payload implementation approach because it substantially reduces the overall mission cost. Dense continuous mapping (4 km x 4 km pixels at 40 deg. latitude) is a transformational advance beyond, and complementary to, the capabilities of the NASA missions of record in low earth orbit, providing two to three orders of magnitude improvement in the number of
Stepwise Iterative Fourier Transform: The SIFT
NASA Technical Reports Server (NTRS)
Benignus, V. A.; Benignus, G.
1975-01-01
A program, designed specifically to study the respective effects of some common data problems on results obtained through stepwise iterative Fourier transformation of synthetic data with known waveform composition, was outlined. Included in this group were the problems of gaps in the data, different time-series lengths, periodic but nonsinusoidal waveforms, and noisy (low signal-to-noise) data. Results on sinusoidal data were also compared with results obtained on narrow band noise with similar characteristics. The findings showed that the analytic procedure under study can reliably reduce data in the nature of (1) sinusoids in noise, (2) asymmetric but periodic waves in noise, and (3) sinusoids in noise with substantial gaps in the data. The program was also able to analyze narrow-band noise well, but with increased interpretational problems. The procedure was shown to be a powerful technique for analysis of periodicities, in comparison with classical spectrum analysis techniques. However, informed use of the stepwise procedure nevertheless requires some background of knowledge concerning characteristics of the biological processes under study.
Imaging Fourier transform spectrometry of chemical plumes
NASA Astrophysics Data System (ADS)
Bradley, Kenneth C.; Gross, Kevin C.; Perram, Glen P.
2009-05-01
A midwave infrared (MWIR) imaging Fourier transform spectrometer (FTS), the Telops FIRST-MWE (Field-portable Imaging Radiometric Spectrometer Technology - Midwave Extended) has been utilized for the standoff detection and characterization of chemical plumes. Successful collection and analysis of MWIR hyperspectral imagery of jet engine exhaust has allowed us to produce spatial profiles of both temperature and chemical constituent concentrations of exhaust plumes. Successful characterization of this high temperature combustion event has led to the collection and analysis of hyperspectral imagery of lower temperature emissions from industrial smokestacks. This paper presents MWIR data from remote collection of hyperspectral imagery of methyl salicilate (MeS), a chemical warfare agent simulant, during the Chemical Biological Distributed Early Warning System (CBDEWS) test at Dugway Proving Grounds, UT in 2008. The data did not contain spectral lines associated with emission of MeS. However, a few broad spectral features were present in the background-subtracted plume spectra. Further analysis will be required to assign these features, and determine the utility of MWIR hyperspectral imagery for analysis of chemical warfare agent plumes.
Fast Fourier transform discrete dislocation dynamics
NASA Astrophysics Data System (ADS)
Graham, J. T.; Rollett, A. D.; LeSar, R.
2016-12-01
Discrete dislocation dynamics simulations have been generally limited to modeling systems described by isotropic elasticity. Effects of anisotropy on dislocation interactions, which can be quite large, have generally been ignored because of the computational expense involved when including anisotropic elasticity. We present a different formalism of dislocation dynamics in which the dislocations are represented by the deformation tensor, which is a direct measure of the slip in the lattice caused by the dislocations and can be considered as an eigenstrain. The stresses arising from the dislocations are calculated with a fast Fourier transform (FFT) method, from which the forces are determined and the equations of motion are solved. Use of the FFTs means that the stress field is only available at the grid points, which requires some adjustments/regularizations to be made to the representation of the dislocations and the calculation of the force on individual segments, as is discussed hereinafter. A notable advantage of this approach is that there is no computational penalty for including anisotropic elasticity. We review the method and apply it in a simple dislocation dynamics calculation.
VLSI Implementation Of The Fast Fourier Transform
NASA Astrophysics Data System (ADS)
Chau, Paul M.; Ku, Walter H.
1986-03-01
A VLSI implementation of a Fast Fourier Transform (FFT) processor consisting of a mesh interconnection of complex floating-point butterfly units is presented. The Cooley-Tukey radix-2 Decimation-In-Frequency (DIF) formulation of the FFT was chosen since it offered the best overall compromise between the need for fast and efficient algorithmic computation and the need for a structure amenable to VLSI layout. Thus the VLSI implementation is modular, regular, expandable to various problem sizes and has a simple systolic flow of data and control. To evaluate the FFT architecture, VLSI area-time complexity concepts are used, but are now adapted to a complex floating-point number system rather than the usual integer ring representation. We show by our construction that the Thompson area-time optimum bound for the VLSI computation of an N-point FFT, area-time2oc = ORNlogN)1+a] can be attained by an alternative number representation, and hence the theoretical bound is a tight bound regardless of number system representation.
Fourier transform spectroscopy for future planetary missions
NASA Astrophysics Data System (ADS)
Brasunas, John C.; Hewagama, Tilak; Kolasinski, John R.; Kostiuk, Theodor
2015-11-01
Thermal-emission infrared spectroscopy is a powerful tool for exploring the composition, temperature structure, and dynamics of planetary atmospheres; and the temperature of solid surfaces. A host of Fourier transform spectrometers (FTS) such as Mariner IRIS, Voyager IRIS, and Cassini CIRS from NASA Goddard have made and continue to make important new discoveries throughout the solar system.Future FTS instruments will have to be more sensitive (when we concentrate on the colder, outer reaches of the solar system), and less massive and less power-hungry as we cope with decreasing resource allotments for future planetary science instruments. With this in mind, NASA Goddard was funded via the Planetary Instrument Definition and Development Progrem (PIDDP) to develop CIRS-lite, a smaller version of the CIRS FTS for future planetary missions. Following the initial validation of CIRS-lite operation in the laboratory, we have been acquiring atmospheric data in the 8-12 micron window at the 1.2 m telescope at the Goddard Geophysical and Astronomical Observatory (GGAO) in Greenbelt, MD. Targets so far have included Earth's atmosphere (in emission, and in absorption against the moon), and Venus.We will present the roadmap for making CIRS-lite a viable candidate for future planetary missions.
Laser and Fourier Transform Spectroscopy of Novel Propellant Molecules
1990-07-01
Classification) 63 Laser and Fourier Transform Spectroscopy of Novel Propellant Molecules (U) 12. PERSONAL AUTHOR(S) Bernath, Peter F. 13a. TYPE OF REPORT...Publications (Supported by F04611-87-K-0020) 1. C.R. Brazier, P.F. Bernath, J.B. Burkholder and C.J. Howard, Fourier Transform Spectroscopy of the v3
Cryogenic Scan Mechanism for Fourier Transform Spectrometer
NASA Technical Reports Server (NTRS)
Brasunas, John C.; Francis, John L.
2011-01-01
A compact and lightweight mechanism has been developed to accurately move a Fourier transform spectrometer (FTS) scan mirror (a cube corner) in a near-linear fashion with near constant speed at cryogenic temperatures. This innovation includes a slide mechanism to restrict motion to one dimension, an actuator to drive the motion, and a linear velocity transducer (LVT) to measure the speed. The cube corner mirror is double-passed in one arm of the FTS; double-passing is required to compensate for optical beam shear resulting from tilting of the moving cube corner. The slide, actuator, and LVT are off-the-shelf components that are capable of cryogenic vacuum operation. The actuator drives the slide for the required travel of 2.5 cm. The LVT measures translation speed. A proportional feedback loop compares the LVT voltage with the set voltage (speed) to derive an error signal to drive the actuator and achieve near constant speed. When the end of the scan is reached, a personal computer reverses the set voltage. The actuator and LVT have no moving parts in contact, and have magnetic properties consistent with cryogenic operation. The unlubricated slide restricts motion to linear travel, using crossed roller bearings consistent with 100-million- stroke operation. The mechanism tilts several arc seconds during transport of the FTS mirror, which would compromise optical fringe efficiency when using a flat mirror. Consequently, a cube corner mirror is used, which converts a tilt into a shear. The sheared beam strikes (at normal incidence) a flat mirror at the end of the FTS arm with the moving mechanism, thereby returning upon itself and compensating for the shear
Fourier Transform Mass Spectrometry: The Transformation of Modern Environmental Analyses
Lim, Lucy; Yan, Fangzhi; Bach, Stephen; Pihakari, Katianna; Klein, David
2016-01-01
Unknown compounds in environmental samples are difficult to identify using standard mass spectrometric methods. Fourier transform mass spectrometry (FTMS) has revolutionized how environmental analyses are performed. With its unsurpassed mass accuracy, high resolution and sensitivity, researchers now have a tool for difficult and complex environmental analyses. Two features of FTMS are responsible for changing the face of how complex analyses are accomplished. First is the ability to quickly and with high mass accuracy determine the presence of unknown chemical residues in samples. For years, the field has been limited by mass spectrometric methods that were based on knowing what compounds of interest were. Secondly, by utilizing the high resolution capabilities coupled with the low detection limits of FTMS, analysts also could dilute the sample sufficiently to minimize the ionization changes from varied matrices. PMID:26784175
Leak Location in Plates Using Spatial Fourier Transform Based Analysis
NASA Astrophysics Data System (ADS)
Roberts, R.; Holland, S.; Strei, M.; Song, J.; Chimenti, D. E.
2005-04-01
The location of air leaks in plate-like structures is examined using a spatial Fourier transform based analysis. Noise data is collected over 2-D spatial arrays at sensor locations, from which mean cross-correlations are compiled. Propagation properties, transit times, and energy distribution among modes are extracted through spatial Fourier transformation of these data. A simple algorithm to determine source location using a reduced set of transform data is demonstrated experimentally, based upon extraction of energy propagation direction.
Optical signal processing - Fourier transforms and convolution/correlation
NASA Astrophysics Data System (ADS)
Rhodes, William T.
The application of Fourier techniques and linear-systems theory to the analysis and synthesis of optical systems is described in a theoretical review, and Fourier-based optical signal-processing methods are considered. Topics examined include monochromatic wave fields and their phasor representation, wave propagation, Fourier-transform and spectrum analysis with a spherical lens, coherent and incoherent imaging and spatial filtering, and a channelized spectrum analyzer (using both spherical and cylindrical lenses) for multiple one-dimensional input signals.
Fourier transform techniques for the inference of cloud motion
NASA Technical Reports Server (NTRS)
Lo, R. C.; Rosenfeld, A.
1974-01-01
The development and evaluation are reported of phase shift techniques based on the Fourier transform for the estimation of cloud motion from geosynchronous meteorological satellite photographs. An alternative approach to cloud motion estimation, involving thresholding, was proposed and studied.
Laser ablation/Fourier transform mass spectrometry of polymers
NASA Astrophysics Data System (ADS)
Creasy, William R.; Brenna, J. T.
1989-10-01
Laser ablation/ionization followed by Fourier transform mass spectrometry is used to identify and characterize polymers. The mass spectra of several polymers are discussed, including polyimide, polyamic acid, Dupont Tefzel, and polyphenylene sulfide.
Xgremlin: Interferograms and spectra from Fourier transform spectrometers analysis
NASA Astrophysics Data System (ADS)
Nave, G.; Griesmann, U.; Brault, J. W.; Abrams, M. C.
2015-11-01
Xgremlin is a hardware and operating system independent version of the data analysis program Gremlin used for Fourier transform spectrometry. Xgremlin runs on PCs and workstations that use the X11 window system, including cygwin in Windows. It is used to Fourier transform interferograms, plot spectra, perform phase corrections, perform intensity and wavenumber calibration, and find and fit spectral lines. It can also be used to construct synthetic spectra, subtract continua, compare several different spectra, and eliminate ringing around lines.
Automatic Fourier transform and self-Fourier beams due to parabolic potential
Zhang, Yiqi; Liu, Xing; Belić, Milivoj R.; Zhong, Weiping; Petrović, Milan S.; Zhang, Yanpeng
2015-12-15
We investigate the propagation of light beams including Hermite–Gauss, Bessel–Gauss and finite energy Airy beams in a linear medium with parabolic potential. Expectedly, the beams undergo oscillation during propagation, but quite unexpectedly they also perform automatic Fourier transform, that is, periodic change from the beam to its Fourier transform and back. In addition to oscillation, the finite-energy Airy beams exhibit periodic inversion during propagation. The oscillating period of parity-asymmetric beams is twice that of the parity-symmetric beams. Based on the propagation in parabolic potential, we introduce a class of optically-interesting beams that are self-Fourier beams—that is, the beams whose Fourier transforms are the beams themselves.
ISAR Imaging Using Fourier and Wavelet Transforms
2007-12-01
5 B. SCATTERING FROM A SPHERE . . . . . . . . . . . . . . . . 7 C. IMAGING FROM WEAK-SCATTERER FAR-FIELD DATA USING FOURIER ANALYSIS ...independent of weather conditions, in day or night. With the advent of powerful digital signal processing algorithms, multidimensional signal analysis ...a very long antenna by signal analysis [Ref. 2]. The ability to view or capture a scene improves with a larger aperture (in a binocular or camera), a
Development of an Imaging Fourier Transform Spectrometer
1986-05-01
13. Smith, Warren J. Modern Optical Engineering . McGraw Hill Book Company, New York, 1966. 14. Sanderson, R. B. "Fourier Spectroscopy." Molecular...DOWNGRADIP,.G SCHEDU.E 4 PERFORMING ORGANIZATION REPORT NUMBERIS) AEDC-TR-86-17 6a. NAME OF PERFORMING ORGANIZATION ~ h Arnold Engineering L...PREFACE The work reported herein was conducted by the Arnold Engineering Development Center (AEDC), Air Force Systems Command (AFSC), from October
Fourier Transforms of Pulses Containing Exponential Leading and Trailing Profiles
Warshaw, S I
2001-07-15
In this monograph we discuss a class of pulse shapes that have exponential rise and fall profiles, and evaluate their Fourier transforms. Such pulses can be used as models for time-varying processes that produce an initial exponential rise and end with the exponential decay of a specified physical quantity. Unipolar examples of such processes include the voltage record of an increasingly rapid charge followed by a damped discharge of a capacitor bank, and the amplitude of an electromagnetic pulse produced by a nuclear explosion. Bipolar examples include acoustic N waves propagating for long distances in the atmosphere that have resulted from explosions in the air, and sonic booms generated by supersonic aircraft. These bipolar pulses have leading and trailing edges that appear to be exponential in character. To the author's knowledge the Fourier transforms of such pulses are not generally well-known or tabulated in Fourier transform compendia, and it is the purpose of this monograph to derive and present these transforms. These Fourier transforms are related to a definite integral of a ratio of exponential functions, whose evaluation we carry out in considerable detail. From this result we derive the Fourier transforms of other related functions. In all Figures showing plots of calculated curves, the actual numbers used for the function parameter values and dependent variables are arbitrary and non-dimensional, and are not identified with any particular physical phenomenon or model.
Inverse Fourier Transform in the Gamma Coordinate System
Wei, Yuchuan; Yu, Hengyong; Wang, Ge
2011-01-01
This paper provides auxiliary results for our general scheme of computed tomography. In 3D parallel-beam geometry, we first demonstrate that the inverse Fourier transform in different coordinate systems leads to different reconstruction formulas and explain why the Radon formula cannot directly work with truncated projection data. Also, we introduce a gamma coordinate system, analyze its properties, compute the Jacobian of the coordinate transform, and define weight functions for the inverse Fourier transform assuming a simple scanning model. Then, we generate Orlov's theorem and a weighted Radon formula from the inverse Fourier transform in the new system. Furthermore, we present the motion equation of the frequency plane and the conditions for sharp points of the instantaneous rotation axis. Our analysis on the motion of the frequency plane is related to the Frenet-Serret theorem in the differential geometry. PMID:21076520
Electro-Optical Imaging Fourier-Transform Spectrometer
NASA Technical Reports Server (NTRS)
Chao, Tien-Hsin; Zhou, Hanying
2006-01-01
An electro-optical (E-O) imaging Fourier-transform spectrometer (IFTS), now under development, is a prototype of improved imaging spectrometers to be used for hyperspectral imaging, especially in the infrared spectral region. Unlike both imaging and non-imaging traditional Fourier-transform spectrometers, the E-O IFTS does not contain any moving parts. Elimination of the moving parts and the associated actuator mechanisms and supporting structures would increase reliability while enabling reductions in size and mass, relative to traditional Fourier-transform spectrometers that offer equivalent capabilities. Elimination of moving parts would also eliminate the vibrations caused by the motions of those parts. Figure 1 schematically depicts a traditional Fourier-transform spectrometer, wherein a critical time delay is varied by translating one the mirrors of a Michelson interferometer. The time-dependent optical output is a periodic representation of the input spectrum. Data characterizing the input spectrum are generated through fast-Fourier-transform (FFT) post-processing of the output in conjunction with the varying time delay.
Blind digital watermarking method in the fractional Fourier transform domain
NASA Astrophysics Data System (ADS)
Lang, Jun; Zhang, Zheng-guang
2014-02-01
In this paper, we proposed a novel blind digital image watermarking algorithm based on the fractional Fourier transform (FRFT), which is a generalization of the ordinary Fourier transform and its output has the mixed time and frequency components of the signal. The original image is segmented into non-overlapping blocks for watermarking, and each block is transformed by the two dimensional fractional Fourier transform with two fractional orders. Then each pixel value of binary watermark is embedded by modifying the back-diagonal FRFT coefficients of each image block at the same location with a random array. After perform an inverse two dimensional fractional Fourier transform, we can obtain the watermarked image and the transform orders can be consider as the encryption keys in this method. A series of attacking experiments are performed on the proposed method. The experiments results show that the proposed algorithm not only is of good imperceptibility and security and is very robust to JPEG compression noise attacks and image manipulation operations, but also can provide protection even under compound attacks.
Dispersive Fourier transformation for fast continuous single-shot measurements
NASA Astrophysics Data System (ADS)
Goda, K.; Jalali, B.
2013-02-01
Dispersive Fourier transformation is an emerging measurement technique that overcomes the speed limitations of traditional optical instruments and enables fast continuous single-shot measurements in optical sensing, spectroscopy and imaging. Using chromatic dispersion, dispersive Fourier transformation maps the spectrum of an optical pulse to a temporal waveform whose intensity mimics the spectrum, thus allowing a single-pixel photodetector to capture the spectrum at a scan rate significantly beyond what is possible with conventional space-domain spectrometers. Over the past decade, this method has brought us a new class of real-time instruments that permit the capture of rare events such as optical rogue waves and rare cancer cells in blood, which would otherwise be missed using conventional instruments. In this Review, we discuss the principle of dispersive Fourier transformation and its implementation across a wide range of diverse applications.
Parallel fast Fourier transforms for non power of two data
Semeraro, B.D.
1994-09-01
This report deals with parallel algorithms for computing discrete Fourier transforms of real sequences of length N not equal to a power of two. The method described is an extension of existing power of two transforms to sequences with N a product of small primes. In particular, this implementation requires N = 2{sup p}3{sup q}5{sup r}. The communication required is the same as for a transform of length N = 2{sup p}. The algorithm presented is intended for use in the solution of partial differential equations, or in any situation in which a large number of forward and backward transforms must be performed and in which the Fourier Coefficients need not be ordered. This implementation is a one dimensional FFT but the techniques are applicable to multidimensional transforms as well. The algorithm has been implemented on a 128 node Intel Ipsc/860.
Efficient Computer Implementations of Fast Fourier Transforms.
1980-12-01
TRANSFORMS, THESIS Presented to the Faculty of the School of Engineering of the Air Force Institute of Technology Air University in Partial Fulfillment of...The Algorithm * of S. Winograd", NASA, Jet Propulsion Lab, California Ins.titute of Technology , Pasadena, CA, 15 February 79 (AS N79-19733). 1 ’ 192...M. :- E. ,._T-. OF THE A ’rY TO B E TRANFO:-:F ’. :3:’ -:f1 .QT E:-7T TE:-T FLAG3=1 IF PE :-L TRAN’-FORM :34"(1 TEST FLAG = IF IF ,OMLE. TRA;:FORM 7 T
Application of Fourier transform spectroscopy to air pollution problems
NASA Astrophysics Data System (ADS)
Shaw, J. H.; Calvert, J. G.
1980-11-01
The nature of information that can be retrieved from spectra obtained with Fourier transform spectroscopy is discussed. Nonlinear, least squares analysis of spectra is capable of retrieving information that is beyond the reach of conventional methods and has improved precision and accuracy. Fourier transform infrared spectroscopy was used to study quantitatively the kinetics and mechanisms of several chemical reactions that are of interest to atmospheric chemists and are important in the development of air pollution control strategies. The systems studied include the metastable, reactive, gaseous species, peroxynitric acid, hypochlorous acid, and dimethylnitrosamine.
Modulated Fourier Transform Raman Fiber-Optic Spectroscopy
NASA Technical Reports Server (NTRS)
Jensen, Brian J. (Inventor); Cooper, John B. (Inventor); Wise, Kent L. (Inventor)
2000-01-01
A modification to a commercial Fourier Transform (FT) Raman spectrometer is presented for the elimination of thermal backgrounds in the FT Raman spectra. The modification involves the use of a mechanical optical chopper to modulate the continuous wave laser, remote collection of the signal via fiber optics, and connection of a dual-phase digital-signal-processor (DSP) lock-in amplifier between the detector and the spectrometer's collection electronics to demodulate and filter the optical signals. The resulting Modulated Fourier Transform Raman Fiber-Optic Spectrometer is capable of completely eliminating thermal backgrounds at temperatures exceeding 300 C.
Fractional Fourier transform of Lorentz-Gauss beams.
Zhou, Guoquan
2009-02-01
Lorentz-Gauss beams are introduced to describe certain laser sources that produce highly divergent beams. The fractional Fourier transform (FRFT) is applied to treat the propagation of Lorentz-Gauss beams. Based on the definition of convolution and the convolution theorem of the Fourier transform, an analytical expression for a Lorentz-Gauss beam passing through an FRFT system has been derived. By using the derived expression, the properties of a Lorentz-Gauss beam in the FRFT plane are graphically illustrated with numerical examples.
Personal computer based Fourier transform ion cyclotron resonance mass spectrometer
NASA Astrophysics Data System (ADS)
Guan, Shenheng; Jones, Patrick R.
1988-12-01
An IBM PC AT compatible computer is used to host the interface of a Fourier transform ion cyclotron resonance mass spectrometer or FTMS. A common fast memory bank for both ion-excitation waveform and data acquisition is reserved in the computer's system memory space. All the digital electronics circuitry is assembled on an IBM PC AT extension board. Neither an external frequency synthesizer nor a waveform digitizer is needed. Ion-excitation waveforms can be generated in either frequency-sweeping or inverse-Fourier transform modes. Both excitation and data acquisition can be carried out at eight megawords per second.
Fourier-transform and global contrast interferometer alignment methods
Goldberg, Kenneth A.
2001-01-01
Interferometric methods are presented to facilitate alignment of image-plane components within an interferometer and for the magnified viewing of interferometer masks in situ. Fourier-transforms are performed on intensity patterns that are detected with the interferometer and are used to calculate pseudo-images of the electric field in the image plane of the test optic where the critical alignment of various components is being performed. Fine alignment is aided by the introduction and optimization of a global contrast parameter that is easily calculated from the Fourier-transform.
Discrete Fourier Transform in a Complex Vector Space
NASA Technical Reports Server (NTRS)
Dean, Bruce H. (Inventor)
2015-01-01
An image-based phase retrieval technique has been developed that can be used on board a space based iterative transformation system. Image-based wavefront sensing is computationally demanding due to the floating-point nature of the process. The discrete Fourier transform (DFT) calculation is presented in "diagonal" form. By diagonal we mean that a transformation of basis is introduced by an application of the similarity transform of linear algebra. The current method exploits the diagonal structure of the DFT in a special way, particularly when parts of the calculation do not have to be repeated at each iteration to converge to an acceptable solution in order to focus an image.
Discrete Fourier Transform Analysis in a Complex Vector Space
NASA Technical Reports Server (NTRS)
Dean, Bruce H.
2009-01-01
Alternative computational strategies for the Discrete Fourier Transform (DFT) have been developed using analysis of geometric manifolds. This approach provides a general framework for performing DFT calculations, and suggests a more efficient implementation of the DFT for applications using iterative transform methods, particularly phase retrieval. The DFT can thus be implemented using fewer operations when compared to the usual DFT counterpart. The software decreases the run time of the DFT in certain applications such as phase retrieval that iteratively call the DFT function. The algorithm exploits a special computational approach based on analysis of the DFT as a transformation in a complex vector space. As such, this approach has the potential to realize a DFT computation that approaches N operations versus Nlog(N) operations for the equivalent Fast Fourier Transform (FFT) calculation.
Fourier transform spectroscopy of cotton and cotton trash
Technology Transfer Automated Retrieval System (TEKTRAN)
Fourier Transform techniques have been shown to have higher signal-to-noise capabilities, higher throughput, negligible stray light, continuous spectra, and higher resolution. In addition, FT spectroscopy affords for frequencies in spectra to be measured all at once and more precise wavelength calib...
The q-Fourier transformation of q-generalized functions
Ol'shanetskii, M A; Rogov, V-B K
1999-06-30
A study is made of functions on the lattice generated by the integer powers of q{sup 2}, 0Fourier transformation is constructed based on the Jackson integral in the space of generalized functions on the lattice.
Spatial Fourier Transform Analysis of Polishing Pad Surface Topography
NASA Astrophysics Data System (ADS)
Khajornrungruang, Panart; Kimura, Keiichi; Okuzono, Takahisa; Suzuki, Keisuke; Kushida, Takashi
2012-05-01
The spatial Fourier transform analysis is proposed to quantitatively evaluate the irregular topography of the conditioned chemical mechanical polishing (CMP) pad surface. We discuss the power spectrum in the spatial wavelengths of the surface topographies corresponding to polishing time. We conclude that the spatial wavelength of less than 5 µm in the topography yielded high material removal rates.
A Sublinear Algorithm of Sparse Fourier Transform for Nonequispaced Data
2005-08-12
and discussions, I would thank my adviser Ingrid Daubechies. In addition, I thank Weinan E, Anna Gilbert, Martin Strauss for their suggestions...2002-2004. [15] S. KUNIS, D. POTTS, G. STEIDL , Fast Fourier transform at nonequispaced knots: A user’s guide to a C-library, Manual of NFFT 2.0
Discrete fourier transform (DFT) analysis for applications using iterative transform methods
NASA Technical Reports Server (NTRS)
Dean, Bruce H. (Inventor)
2012-01-01
According to various embodiments, a method is provided for determining aberration data for an optical system. The method comprises collecting a data signal, and generating a pre-transformation algorithm. The data is pre-transformed by multiplying the data with the pre-transformation algorithm. A discrete Fourier transform of the pre-transformed data is performed in an iterative loop. The method further comprises back-transforming the data to generate aberration data.
ERIC Educational Resources Information Center
Grimm, C. A.
This document contains two units that examine integral transforms and series expansions. In the first module, the user is expected to learn how to use the unified method presented to obtain Laplace transforms, Fourier transforms, complex Fourier series, real Fourier series, and half-range sine series for given piecewise continuous functions. In…
Ultrafast ranging lidar based on real-time Fourier transformation.
Xia, Haiyun; Zhang, Chunxi
2009-07-15
Real-time Fourier-transformation-based ranging lidar using a mode-locked femtosecond fiber laser is demonstrated. The object signal and the reference signal are guided from a fiber Mach-Zehnder interferometer into a dispersive element. The two optical pulses extend and overlap with each other temporally, which yields a microwave pulse on the photodetector with its frequency proportional to the time delay between the two signals. The temporal interferograms are transformed from the time domain into the frequency domain using a time-to-frequency conversion function obtained in the calibration process. The Fourier transform is used in the data processing. A range resolution of 334 nm at a sampling rate of 48.6 MHz over a distance of 16 cm is demonstrated in the laboratory.
The Discrete Fourier Transform on hexagonal remote sensing image
NASA Astrophysics Data System (ADS)
Li, Yalu; Ben, Jin; Wang, Rui; Du, Lingyu
2016-11-01
Global discrete grid system will subdivide the earth recursively to form a multi-resolution grid hierarchy with no Overlap and seamless which help build global uniform spatial reference datum and multi-source data processing mode which takes the position as the object and in the aspect of data structure supports the organization, process and analysis of the remote sensing big data. This paper adopts the base transform to realize the mutual transformation of square pixel and hexagonal pixel. This paper designs the corresponding discrete Fourier transform algorithm for any lattice. Finally, the paper show the result of the DFT of the remote sensing image of the hexagonal pixel.
A VLSI architecture for simplified arithmetic Fourier transform algorithm
NASA Technical Reports Server (NTRS)
Reed, Irving S.; Shih, Ming-Tang; Truong, T. K.; Hendon, E.; Tufts, D. W.
1992-01-01
The arithmetic Fourier transform (AFT) is a number-theoretic approach to Fourier analysis which has been shown to perform competitively with the classical FFT in terms of accuracy, complexity, and speed. Theorems developed in a previous paper for the AFT algorithm are used here to derive the original AFT algorithm which Bruns found in 1903. This is shown to yield an algorithm of less complexity and of improved performance over certain recent AFT algorithms. A VLSI architecture is suggested for this simplified AFT algorithm. This architecture uses a butterfly structure which reduces the number of additions by 25 percent of that used in the direct method.
Conformations of seven-membered rings: The Fourier transform model
NASA Astrophysics Data System (ADS)
Cano, F. H.; Foces-Foces, C.
A representation of the puckered conformations of seven-membered rings, using the Fourier Fourier Transform model and derived from the torsion angles, is presented in terms of two puckering amplitudes and their corresponding puckering phases. These four parameters are used to describe the main conformational types and to study the planarity of the rings, symmetrical forms, pseudorotation pathways and symmetrical interconversions through the puckering levels. This analysis provides a criterion for characterizing the basic conformations which have already been established by earlier work. A comparison with previous models is also given and the representation applied to some 1,4-benzodiazepine compounds.
Microholography by Numerical Wavefront Reconstruction in the Fourier Transform Geometry.
NASA Astrophysics Data System (ADS)
Haddad, Waleed Sami
New techniques for pulsed holographic microimaging with x-rays and visible light based on the Fourier transform geometry are presented. A charge-coupled device (CCD) is used to record the holographic information. Images are reconstructed numerically by fast Fourier transform (FFT) and by a novel "stigmatic" aberration-free technique. It is shown by numerical simulation that reconstruction by FFT inherently suffers from coma. An innovative design for a Fourier transform x -ray holographic microscope incorporating a metallic microsphere as the reference wave producing element is presented. The design is optimized for use with an x-ray laser source operating in the range lambda~eq43 A; nickel is found to be the best material for the reference sphere in this range. A visible light analog of the x-ray microscope was built and tested yielding an image of Ascaris larva. Two unique visible light Fourier transform holographic microscopes are also presented. The first incorporates a glycerol microdrop reference lens. This microscope was operated at N.A. ~ 0.25 with an argon ion laser at lambda = 514.5 nm. The transverse point spread function of the system was measured to be 1.40 mum, near the theoretical diffraction limit of 1.29 mu m. The second is a design based on a Mach-Zehnder interferometer. This Fourier Mach Zehnder holographic microscope (FMZHM) offers great flexibility and many advantages. The FMZHM was operated at N.A. _sp{~ }{>} 0.25 with lambda = 514.5 nm and yielded many 2-D and 3-D images of biological samples. A study of potential biological applications of visible and x-ray holographic microscopy is also presented.
Zhang, Fang; Zhu, Jing; Song, Qiang; Yue, Weirui; Liu, Jingdan; Wang, Jian; Situ, Guohai; Huang, Huijie
2015-10-20
In general, Fourier transform lenses are considered as ideal in the design algorithms of diffractive optical elements (DOEs). However, the inherent aberrations of a real Fourier transform lens disturb the far field pattern. The difference between the generated pattern and the expected design will impact the system performance. Therefore, a method for modifying the Fourier spectrum of DOEs without introducing other optical elements to reduce the aberration effect of the Fourier transform lens is proposed. By applying this method, beam shaping performance is improved markedly for the optical system with a real Fourier transform lens. The experiments carried out with a commercial Fourier transform lens give evidence for this method. The method is capable of reducing the system complexity as well as improving its performance.
Implementing quantum Fourier transform with integrated photonic devices
NASA Astrophysics Data System (ADS)
Tabia, Gelo Noel
2014-03-01
Many quantum algorithms that exhibit exponential speedup over their classical counterparts employ the quantum Fourier transform, which is used to solve interesting problems such as prime factorization. Meanwhile, nonclassical interference of single photons achieved on integrated platforms holds the promise of achieving large-scale quantum computation with multiport devices. An optical multiport device can be built to realize any quantum circuit as a sequence of unitary operations performed by beam splitters and phase shifters on path-encoded qudits. In this talk, I will present a recursive scheme for implementing quantum Fourier transform with a multimode interference photonic integrated circuit. Research at Perimeter Institute is supported by the Government of Canada through Industry Canada and by the Province of Ontario through the Ministry of Research and Innovation.
Time-frequency representation measurement based on temporal Fourier transformation
NASA Astrophysics Data System (ADS)
Suen, Yifan; Xiao, Shaoqiu; Hao, Sumin; Zhao, Xiaoxiang; Xiong, Yigao; Liu, Shenye
2016-10-01
We propose a new scheme to physically realize the short-time Fourier transform (STFT) of chirped optical pulse using time-lens array that enables us to get time-frequency representation without using FFT algorithm. The time-lens based upon the four-wave mixing is used to perform the process of temporal Fourier transformation. Pump pulse is used for both providing the quadratic phase and being the window function of STFT. The idea of STFT is physically realized in our scheme. Simulations have been done to investigate performance of the time-frequency representation scheme (TFRS) in comparison with STFT using FFT algorithm. Optimal measurement of resolution in time and frequency has been discussed.
Fourier transform digital holographic adaptive optics imaging system
Liu, Changgeng; Yu, Xiao; Kim, Myung K.
2013-01-01
A Fourier transform digital holographic adaptive optics imaging system and its basic principles are proposed. The CCD is put at the exact Fourier transform plane of the pupil of the eye lens. The spherical curvature introduced by the optics except the eye lens itself is eliminated. The CCD is also at image plane of the target. The point-spread function of the system is directly recorded, making it easier to determine the correct guide-star hologram. Also, the light signal will be stronger at the CCD, especially for phase-aberration sensing. Numerical propagation is avoided. The sensor aperture has nothing to do with the resolution and the possibility of using low coherence or incoherent illumination is opened. The system becomes more efficient and flexible. Although it is intended for ophthalmic use, it also shows potential application in microscopy. The robustness and feasibility of this compact system are demonstrated by simulations and experiments using scattering objects. PMID:23262541
An algorithm for the basis of the finite Fourier transform
NASA Technical Reports Server (NTRS)
Santhanam, Thalanayar S.
1995-01-01
The Finite Fourier Transformation matrix (F.F.T.) plays a central role in the formulation of quantum mechanics in a finite dimensional space studied by the author over the past couple of decades. An outstanding problem which still remains open is to find a complete basis for F.F.T. In this paper we suggest a simple algorithm to find the eigenvectors of F.T.T.
Visible Imaging Fourier Transform Spectrometer: Design and Calibration
Wishnow, E H; Wurtz, R; Blais-Ouellette, S; Cook, K H; Carr, D; Lewis, I; Grandmont, F; Stubbs, C W
2002-09-19
We present details of the design, operation and calibration of an astronomical visible-band imaging Fourier transform spectrometer (IFTS). This type of instrument produces a spectrum for every pixel in the field of view where the spectral resolution is flexible. The instrument is a dual-input/dual-output Michelson interferometer coupled to the 3.5 meter telescope at the Apache Point Observatory. Imaging performance and interferograms and spectra from calibration sources and standard stars are discussed.
Apparatus and methods for continuous beam fourier transform mass spectrometry
McLuckey, Scott A.; Goeringer, Douglas E.
2002-01-01
A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.
Transfer Functions for Nonlinear Systems via Fourier-Borel Transforms.
Fourier series or integral expansions of response functions of linear systems. The shuffle product which is the characteristic of the noncommutative ... noncommutative algebra on a computer in any of the currently available symbolic programming languages such as Macsyma, Reduce, PL1, and Lisp...gives the transform of the response of the nonlinear system as a Cauchy product of its transfer function which is introduced for the first time here
Spatially resolved two-dimensional Fourier transform electron spin resonance
NASA Astrophysics Data System (ADS)
Ewert, Uwe; Crepeau, Richard H.; Lee, Sanghyuk; Dunnam, Curt R.; Xu, Dajiang; Freed, Jack H.
1991-09-01
Fourier transform ESR methods have been extended to permit spatially resolved two-dimensional (2D)-ESR experiments. This is illustrated for the case of 2D-electron-electron double resonance (2D-ELDOR) spectra of nitroxides in a liquid that exhibits appreciable cross-peaks due to Heisenberg spin exchange. The use of spin-echo decays in spatially resolved FT-ESR is also demonstrated.
Fourier spectroscopy with a one-million-point transformation
NASA Technical Reports Server (NTRS)
Connes, J.; Delouis, H.; Connes, P.; Guelachvili, G.; Maillard, J.; Michel, G.
1972-01-01
A new type of interferometer for use in Fourier spectroscopy has been devised at the Aime Cotton Laboratory of the National Center for Scientific Research (CNRS), Orsay, France. With this interferometer and newly developed computational techniques, interferograms comprising as many as one million samples can now be transformed. The techniques are described, and examples of spectra of thorium and holmium, derived from one million-point interferograms, are presented.
Fast Fourier transformation results from gamma-ray burst profiles
NASA Technical Reports Server (NTRS)
Kouveliotou, Chryssa; Norris, Jay P.; Fishman, Gerald J.; Meegan, Charles A.; Wilson, Robert B.; Paciesas, W. S.
1992-01-01
Several gamma-ray bursts in the BATSE data have sufficiently long durations and complex temporal structures with pulses that appear to be spaced quasi-periodically. In order to test and quantify these periods we have applied fast Fourier transformations (FFT) to all these events. We have also performed cross spectral analyses of the FFT of the two extreme (high-low) energy bands in each case to determine the lead/lag of the pulses in different energies.
Magnetic suspension based Fourier Transform Infrared Spectrometer mechanism (FTIS)
NASA Astrophysics Data System (ADS)
Köker, Ingo; Langenbach, Harald; Schmid, Manfred; Lautier, Jean-Michel
2005-07-01
In the frame of an ESTEC technology contract the development of a Magnetically Suspended Fourier Transform Spectrometer Mechanism (FTIS) was carried out. The aim of the development is to avoid the issues found in mechanically suspended systems and to provide an active alignment and disturbance rejection capability for spectrometer applications. In the frame of FTIS an actively controlled suspension system based on the use of magnetic bearings was defined, developed and built as a demonstration model.
Wavelength-encoded tomography based on optical temporal Fourier transform
NASA Astrophysics Data System (ADS)
Zhang, Chi; Wong, Kenneth K. Y.
2014-09-01
We propose and demonstrate a technique called wavelength-encoded tomography (WET) for non-invasive optical cross-sectional imaging, particularly beneficial in biological system. The WET utilizes time-lens to perform the optical Fourier transform, and the time-to-wavelength conversion generates a wavelength-encoded image of optical scattering from internal microstructures, analogous to the interferometery-based imaging such as optical coherence tomography. Optical Fourier transform, in principle, comes with twice as good axial resolution over the electrical Fourier transform, and will greatly simplify the digital signal processing after the data acquisition. As a proof-of-principle demonstration, a 150 -μm (ideally 36 μm) resolution is achieved based on a 7.5-nm bandwidth swept-pump, using a conventional optical spectrum analyzer. This approach can potentially achieve up to 100-MHz or even higher frame rate with some proven ultrafast spectrum analyzer. We believe that this technique is innovative towards the next-generation ultrafast optical tomographic imaging application.
Mass spectral peak distortion due to Fourier transform signal processing.
Rockwood, Alan L; Erve, John C L
2014-12-01
Distortions of peaks can occur when one uses the standard method of signal processing of data from the Orbitrap and other FT-based methods of mass spectrometry. These distortions arise because the standard method of signal processing is not a linear process. If one adds two or more functions, such as time-dependent signals from a Fourier transform mass spectrometer and performs a linear operation on the sum, the result is the same as if the operation was performed on separate functions and the results added. If this relationship is not valid, the operation is non-linear and can produce unexpected and/or distorted results. Although the Fourier transform itself is a linear operator, the standard algorithm for processing spectra in Fourier transform-based methods include non-linear mathematical operators such that spectra processed by the standard algorithm may become distorted. The most serious consequence is that apparent abundances of the peaks in the spectrum may be incorrect. In light of these considerations, we performed theoretical modeling studies to illustrate several distortion effects that can be observed, including abundance distortions. In addition, we discuss experimental systems where these effects may manifest, including suggested systems for study that should demonstrate these peak distortions. Finally, we point to several examples in the literature where peak distortions may be rationalized by the phenomena presented here.
Fourier transform light scattering angular spectroscopy using digital inline holography.
Kim, Kyoohyun; Park, YongKeun
2012-10-01
A simple and practical method for measuring the angle-resolved light scattering (ARLS) from individual objects is reported. Employing the principle of inline holography and a Fourier transform light scattering technique, both the static and dynamic scattering patterns from individual micrometer-sized objects can be effectively and quantitatively obtained. First, the light scattering measurements were performed on individual polystyrene beads, from which the refractive index and diameter of each bead were retrieved. Also, the measurements of the static and dynamic light scattering from intact human red blood cells are demonstrated. Using the present method, an existing microscope can be directly transformed into a precise instrument for ARLS measurements.
Fractional Fourier transforms, symmetrical lens systems, and their cardinal planes.
Moreno, Ignacio; Sánchez-López, María M; Ferreira, Carlos; Mateos, Felipe
2007-07-01
We study the relation between optical lens systems that perform a fractional Fourier transform (FRFT) with the geometrical cardinal planes. We demonstrate that lens systems symmetrical with respect to the central plane provide an exact FRFT link between the input and output planes. Moreover, we show that the fractional order of the transform has real values between 0 and 2 when light propagation is produced between principal planes and antiprincipal planes, respectively. Finally, we use this new point of view to design an optical lens system that provides FRFTs with variable fractional order in the range (0,2) without moving the input and output planes.
Improved digital filters for evaluating Fourier and Hankel transform integrals
Anderson, Walter L.
1975-01-01
New algorithms are described for evaluating Fourier (cosine, sine) and Hankel (J0,J1) transform integrals by means of digital filters. The filters have been designed with extended lengths so that a variable convolution operation can be applied to a large class of integral transforms having the same system transfer function. A f' lagged-convolution method is also presented to significantly decrease the computation time when computing a series of like-transforms over a parameter set spaced the same as the filters. Accuracy of the new filters is comparable to Gaussian integration, provided moderate parameter ranges and well-behaved kernel functions are used. A collection of Fortran IV subprograms is included for both real and complex functions for each filter type. The algorithms have been successfully used in geophysical applications containing a wide variety of integral transforms
Discrete Fourier Transform: statistical effect size and significance of Fourier components.
NASA Astrophysics Data System (ADS)
Crockett, Robin
2016-04-01
A key analytical technique in the context of investigating cyclic/periodic features in time-series (and other sequential data) is the Discrete (Fast) Fourier Transform (DFT/FFT). However, assessment of the statistical effect-size and significance of the Fourier components in the DFT/FFT spectrum can be subjective and variable. This presentation will outline an approach and method for the statistical evaluation of the effect-size and significance of individual Fourier components from their DFT/FFT coefficients. The effect size is determined in terms of the proportions of the variance in the time-series that individual components account for. The statistical significance is determined using an hypothesis-test / p-value approach with respect to a null hypothesis that the time-series has no linear dependence on a given frequency (of a Fourier component). This approach also allows spectrograms to be presented in terms of these statistical parameters. The presentation will use sunspot cycles as an illustrative example.
Wiener amalgams and pointwise summability of Fourier transforms and Fourier series
NASA Astrophysics Data System (ADS)
Feichtinger, Hans G.; Weisz, Ferenc
2006-05-01
This paper provides a fairly general approach to summability questions for multi-dimensional Fourier transforms. It is based on the use of Wiener amalgam spaces W(L_p,ℓ_q)({mathbb R}(d)) , Herz spaces and weighted versions of Feichtinger's algebra and covers a wide range of concrete special cases (20 of them are listed at the end of the paper). It is proved that under some conditions the maximal operator of the theta-means sigma_T(theta) f can be estimated pointwise by the Hardy-Littlewood maximal function. From this it follows that sigma_T(theta) f {->} f a.e. for all fin W(L_1,ℓ_infty)({mathbb R}(d)) , hence fin L_p({mathbb R}(d)) for any 1≤ p≤ infty. Moreover, sigma_T(theta) f(x) converges to f(x) at each Lebesgue point of fin L_1({mathbb R}(d)) (resp. fin W(L_1,ℓ_infty)({mathbb R}(d)) ) if and only if the Fourier transform of theta is in a suitable Herz space. In case theta is in a Besov space or in a weighted Feichtinger's algebra or in a Sobolev-type space then the a.e. convergence is obtained. Some sufficient conditions are given for theta to be in the weighted Feichtinger's algebra. The same results are presented for multi-dimensional Fourier series.
Two-Dimensional Fourier Transform Applied to Helicopter Flyover Noise
NASA Technical Reports Server (NTRS)
Santa Maria, Odilyn L.
1999-01-01
A method to separate main rotor and tail rotor noise from a helicopter in flight is explored. Being the sum of two periodic signals of disproportionate, or incommensurate frequencies, helicopter noise is neither periodic nor stationary, but possibly harmonizable. The single Fourier transform divides signal energy into frequency bins of equal size. Incommensurate frequencies are therefore not adequately represented by any one chosen data block size. A two-dimensional Fourier analysis method is used to show helicopter noise as harmonizable. The two-dimensional spectral analysis method is first applied to simulated signals. This initial analysis gives an idea of the characteristics of the two-dimensional autocorrelations and spectra. Data from a helicopter flight test is analyzed in two dimensions. The test aircraft are a Boeing MD902 Explorer (no tail rotor) and a Sikorsky S-76 (4-bladed tail rotor). The results show that the main rotor and tail rotor signals can indeed be separated in the two-dimensional Fourier transform spectrum. The separation occurs along the diagonals associated with the frequencies of interest. These diagonals are individual spectra containing only information related to one particular frequency.
Two-Dimensional Fourier Transform Analysis of Helicopter Flyover Noise
NASA Technical Reports Server (NTRS)
SantaMaria, Odilyn L.; Farassat, F.; Morris, Philip J.
1999-01-01
A method to separate main rotor and tail rotor noise from a helicopter in flight is explored. Being the sum of two periodic signals of disproportionate, or incommensurate frequencies, helicopter noise is neither periodic nor stationary. The single Fourier transform divides signal energy into frequency bins of equal size. Incommensurate frequencies are therefore not adequately represented by any one chosen data block size. A two-dimensional Fourier analysis method is used to separate main rotor and tail rotor noise. The two-dimensional spectral analysis method is first applied to simulated signals. This initial analysis gives an idea of the characteristics of the two-dimensional autocorrelations and spectra. Data from a helicopter flight test is analyzed in two dimensions. The test aircraft are a Boeing MD902 Explorer (no tail rotor) and a Sikorsky S-76 (4-bladed tail rotor). The results show that the main rotor and tail rotor signals can indeed be separated in the two-dimensional Fourier transform spectrum. The separation occurs along the diagonals associated with the frequencies of interest. These diagonals are individual spectra containing only information related to one particular frequency.
Wavelets for approximate Fourier transform and data compression
NASA Astrophysics Data System (ADS)
Guo, Haitao
This dissertation has two parts. In the first part, we develop a wavelet-based fast approximate Fourier transform algorithm. The second part is devoted to the developments of several wavelet-based data compression techniques for image and seismic data. We propose an algorithm that uses the discrete wavelet transform (DWT) as a tool to compute the discrete Fourier transform (DFT). The classical Cooley-Tukey FFT is shown to be a special case of the proposed algorithm when the wavelets in use are trivial. The main advantage of our algorithm is that the good time and frequency localization of wavelets can be exploited to approximate the Fourier transform for many classes of signals, resulting in much less computation. Thus the new algorithm provides an efficient complexity versus accuracy tradeoff. When approximations are allowed, under certain sparsity conditions, the algorithm can achieve linear complexity, i.e. O(N). The proposed algorithm also has built-in noise reduction capability. For waveform and image compression, we propose a novel scheme using the recently developed Burrows-Wheeler transform (BWT). We show that the discrete wavelet transform (DWT) should be used before the Burrows-Wheeler transform to improve the compression performance for many natural signals and images. We demonstrate that the simple concatenation of the DWT and BWT coding performs comparably as the embedded zerotree wavelet (EZW) compression for images. Various techniques that significantly improve the performance of our compression scheme are also discussed. The phase information is crucial for seismic data processing. However, traditional compression schemes do not pay special attention to preserving the phase of the seismic data, resulting in the loss of critical information. We propose a lossy compression method that preserves the phase as much as possible. The method is based on the self-adjusting wavelet transform that adapts to the locations of the significant signal components
Partial differential equation transform - Variational formulation and Fourier analysis.
Wang, Yang; Wei, Guo-Wei; Yang, Siyang
2011-12-01
Nonlinear partial differential equation (PDE) models are established approaches for image/signal processing, data analysis and surface construction. Most previous geometric PDEs are utilized as low-pass filters which give rise to image trend information. In an earlier work, we introduced mode decomposition evolution equations (MoDEEs), which behave like high-pass filters and are able to systematically provide intrinsic mode functions (IMFs) of signals and images. Due to their tunable time-frequency localization and perfect reconstruction, the operation of MoDEEs is called a PDE transform. By appropriate selection of PDE transform parameters, we can tune IMFs into trends, edges, textures, noise etc., which can be further utilized in the secondary processing for various purposes. This work introduces the variational formulation, performs the Fourier analysis, and conducts biomedical and biological applications of the proposed PDE transform. The variational formulation offers an algorithm to incorporate two image functions and two sets of low-pass PDE operators in the total energy functional. Two low-pass PDE operators have different signs, leading to energy disparity, while a coupling term, acting as a relative fidelity of two image functions, is introduced to reduce the disparity of two energy components. We construct variational PDE transforms by using Euler-Lagrange equation and artificial time propagation. Fourier analysis of a simplified PDE transform is presented to shed light on the filter properties of high order PDE transforms. Such an analysis also offers insight on the parameter selection of the PDE transform. The proposed PDE transform algorithm is validated by numerous benchmark tests. In one selected challenging example, we illustrate the ability of PDE transform to separate two adjacent frequencies of sin(x) and sin(1.1x). Such an ability is due to PDE transform's controllable frequency localization obtained by adjusting the order of PDEs. The
A generalized Fourier transform approach to risk measures
NASA Astrophysics Data System (ADS)
Bormetti, Giacomo; Cazzola, Valentina; Livan, Giacomo; Montagna, Guido; Nicrosini, Oreste
2010-01-01
We introduce the formalism of generalized Fourier transforms in the context of risk management. We develop a general framework in which to efficiently compute the most popular risk measures, value-at-risk and expected shortfall (also known as conditional value-at-risk). The only ingredient required by our approach is the knowledge of the characteristic function describing the financial data in use. This allows us to extend risk analysis to those non-Gaussian models defined in the Fourier space, such as Lévy noise driven processes and stochastic volatility models. We test our analytical results on data sets coming from various financial indexes, finding that our predictions outperform those provided by the standard log-normal dynamics and are in remarkable agreement with those of the benchmark historical approach.
Fast Fourier transform based direct integration algorithm for the linear canonical transform
NASA Astrophysics Data System (ADS)
Wang, Dayong; Liu, Changgeng; Wang, Yunxin; Zhao, Jie
2011-03-01
The linear canonical transform(LCT) is a parameterized linear integral transform, which is the general case of many well-known transforms such as the Fourier transform(FT), the fractional Fourier transform(FRT) and the Fresnel transform(FST). These integral transforms are of great importance in wave propagation problems because they are the solutions of the wave equation under a variety of circumstances. In optics, the LCT can be used to model paraxial free space propagation and other quadratic phase systems such as lens and graded-index media. A number of algorithms have been presented to fast compute the LCT. When they are used to compute the LCT, the sampling period in the transform domain is dependent on that in the signal domain. This drawback limits their applicability in some cases such as color digital holography. In this paper, a Fast-Fourier-Transform-based Direct Integration algorithm(FFT-DI) for the LCT is presented. The FFT-DI is a fast computational method of the Direct Integration(DI) for the LCT. It removes the dependency of the sampling period in the transform domain on that in the signal domain. Simulations and experimental results are presented to validate this idea.
Fast Fourier transform based direct integration algorithm for the linear canonical transform
NASA Astrophysics Data System (ADS)
Wang, Dayong; Liu, Changgeng; Wang, Yunxin; Zhao, Jie
2010-07-01
The linear canonical transform(LCT) is a parameterized linear integral transform, which is the general case of many well-known transforms such as the Fourier transform(FT), the fractional Fourier transform(FRT) and the Fresnel transform(FST). These integral transforms are of great importance in wave propagation problems because they are the solutions of the wave equation under a variety of circumstances. In optics, the LCT can be used to model paraxial free space propagation and other quadratic phase systems such as lens and graded-index media. A number of algorithms have been presented to fast compute the LCT. When they are used to compute the LCT, the sampling period in the transform domain is dependent on that in the signal domain. This drawback limits their applicability in some cases such as color digital holography. In this paper, a Fast-Fourier-Transform-based Direct Integration algorithm(FFT-DI) for the LCT is presented. The FFT-DI is a fast computational method of the Direct Integration(DI) for the LCT. It removes the dependency of the sampling period in the transform domain on that in the signal domain. Simulations and experimental results are presented to validate this idea.
Partial differential equation transform — Variational formulation and Fourier analysis
Wang, Yang; Wei, Guo-Wei; Yang, Siyang
2011-01-01
Nonlinear partial differential equation (PDE) models are established approaches for image/signal processing, data analysis and surface construction. Most previous geometric PDEs are utilized as low-pass filters which give rise to image trend information. In an earlier work, we introduced mode decomposition evolution equations (MoDEEs), which behave like high-pass filters and are able to systematically provide intrinsic mode functions (IMFs) of signals and images. Due to their tunable time-frequency localization and perfect reconstruction, the operation of MoDEEs is called a PDE transform. By appropriate selection of PDE transform parameters, we can tune IMFs into trends, edges, textures, noise etc., which can be further utilized in the secondary processing for various purposes. This work introduces the variational formulation, performs the Fourier analysis, and conducts biomedical and biological applications of the proposed PDE transform. The variational formulation offers an algorithm to incorporate two image functions and two sets of low-pass PDE operators in the total energy functional. Two low-pass PDE operators have different signs, leading to energy disparity, while a coupling term, acting as a relative fidelity of two image functions, is introduced to reduce the disparity of two energy components. We construct variational PDE transforms by using Euler-Lagrange equation and artificial time propagation. Fourier analysis of a simplified PDE transform is presented to shed light on the filter properties of high order PDE transforms. Such an analysis also offers insight on the parameter selection of the PDE transform. The proposed PDE transform algorithm is validated by numerous benchmark tests. In one selected challenging example, we illustrate the ability of PDE transform to separate two adjacent frequencies of sin(x) and sin(1.1x). Such an ability is due to PDE transform’s controllable frequency localization obtained by adjusting the order of PDEs. The
[Using Fourier transform to analyse differential optical absorption spectrum].
Liu, Qian-Lin; Wang, Li-Shi; Huang, Xin-Jian
2008-05-01
According to the theory of differential optical absorption spectral technique, the differential optical absorption spectral monitoring equipment was designed. Aiming at two kinds of main pollutants, SO2 and NO2, in the atmosphere, this technique was used to monitor them. The present article puts forward the signal analysis method of Fourier transformation to process the above-mentioned two kinds of absorption spectra. The two approaches contain the removeal of noise and the fitting of the slow variety. On the frequency chart after the spectrum was transformed, the low frequency corresponded to the slow variety part and the high frequency corresponded to the noise part of the original spectrum, so through intercepting a certain frequency segment and using inverse Fourier transformation the slow variety part of the low frequency and the noise part of the high frequency of the absorption spectrum could be subtracted. After farther processing we can get a higher resolution differential absorption spectrum of the gas. According to the strength of the spectrum, we can calculate the concentration of the gas. After analysis and comparison with the conventional method, it is considered a new processing method of differential optical absorption spectral technique, and the method can fit the slow variety much better.
1981-02-01
using the standard Fouuier inversion method. Thep- reins concernIng the Fourier transformation of a tr-ncated and/or averaged visi- bility function are...is reviewed. Basic properties of the two-dimensional Fourier transform are reviewed, and the standard Fourier inversion method is presented. This...averaging are illustrated for a double Gaussian model source using the standard Fourier inversion method. Theorems concerning the Fourier transforma- tion
Chirped-Pulse Fourier Transform Microwave Spectroscopy of 3-VINYLBENZALDEHYDE
NASA Astrophysics Data System (ADS)
Smith, Miranda; Brown, Gordon G.
2013-06-01
The pure rotational spectrum of 3-vinylbenzaldehyde (3VBA) has been measured and assigned. Coker College's chirped-pulse Fourier transform microwave (CP-FTMW) spectrometer was used to measure the rotational spectrum of 3VBA in the 7.5 - 18.5 GHz region of the microwave spectrum. The results have been analyzed to discover the rotational constants and centrifugal distortion constants of four distinct conformations of 3VBA: cis,cis-, cis,trans-, trans,cis-, and trans,trans-3VBA. The experimental rotational constants have been compared to the results of ab initio calculations. The performance of Coker's CP-FTMW spectrometer will also be discussed.
A high-resolution Fourier-transform infrared spectrometer.
NASA Technical Reports Server (NTRS)
Johnson, H. L.; Forbes, F. F.; Thompson, R. I.; Steinmetz , D. L.; Harris, O.
1973-01-01
We have developed a Fourier-transform infrared spectrometer having a resolution of 0.5/cm over the range of wavelength from 1 to 5.5 microns. It has been used to observe the sun over this wavelength range from a Lear Jet flying at an altitude of 14 km, and to observe a number of stars from the ground, using the 229-cm telescope of the Steward Observatory and the 152-cm aluminum-mirror telescope at the Observatorio Astronomico Nacional in the Sierra de San Pedro Martir, Baja California, Mexico. The solar spectrum is given here, while the ground-based spectra are being published separately.
Hyperspectral imaging using the single-pixel Fourier transform technique
NASA Astrophysics Data System (ADS)
Jin, Senlin; Hui, Wangwei; Wang, Yunlong; Huang, Kaicheng; Shi, Qiushuai; Ying, Cuifeng; Liu, Dongqi; Ye, Qing; Zhou, Wenyuan; Tian, Jianguo
2017-03-01
Hyperspectral imaging technology is playing an increasingly important role in the fields of food analysis, medicine and biotechnology. To improve the speed of operation and increase the light throughput in a compact equipment structure, a Fourier transform hyperspectral imaging system based on a single-pixel technique is proposed in this study. Compared with current imaging spectrometry approaches, the proposed system has a wider spectral range (400–1100 nm), a better spectral resolution (1 nm) and requires fewer measurement data (a sample rate of 6.25%). The performance of this system was verified by its application to the non-destructive testing of potatoes.
Fourier-transform Raman spectroscopic study of human hair
NASA Astrophysics Data System (ADS)
Akhtar, W.; Edwards, H. G. M.; Farwell, D. W.; Nutbrown, M.
1997-07-01
Fourier-transform Raman microscopic spectra of normal, untreated and bleached hair fibres are presented. Vibrational assignments are made and differences are ascribed to the production of cysteic acid from cysteine. Changes in conformation associated with the disulphide bond in the keratotic component are noted from the ν(CSSC) vibrational modes at wave numbers near 500 cm -1. Raman spectra of hair root ends have also been investigated with a diminution in cysteine content being observed. Application of the technique to the biomedical investigation of healthy and diseased hair is proposed.
Hyperspectral imaging using the single-pixel Fourier transform technique
Jin, Senlin; Hui, Wangwei; Wang, Yunlong; Huang, Kaicheng; Shi, Qiushuai; Ying, Cuifeng; Liu, Dongqi; Ye, Qing; Zhou, Wenyuan; Tian, Jianguo
2017-01-01
Hyperspectral imaging technology is playing an increasingly important role in the fields of food analysis, medicine and biotechnology. To improve the speed of operation and increase the light throughput in a compact equipment structure, a Fourier transform hyperspectral imaging system based on a single-pixel technique is proposed in this study. Compared with current imaging spectrometry approaches, the proposed system has a wider spectral range (400–1100 nm), a better spectral resolution (1 nm) and requires fewer measurement data (a sample rate of 6.25%). The performance of this system was verified by its application to the non-destructive testing of potatoes. PMID:28338100
Two-dimensional Fourier transform of scaled Dirac delta curves
NASA Astrophysics Data System (ADS)
Guizar-Sicairos, Manuel; Gutiérrez-Vega, Julio C.
2004-09-01
We obtain a Fourier transform scaling relation to find analytically, numerically, or experimentally the spectrum of an arbitrary scaled two-dimensional Dirac delta curve from the spectrum of the nonscaled curve. An amplitude factor is derived and given explicitly in terms of the scaling factors and the angle of the forward tangent at each point of the curve about the positive x axis. With the scaling relation we determine the spectrum of an elliptic curve by a circular geometry instead of an elliptical one. The generalization to N-dimensional Dirac delta curves is also included.
Transfer Function Identification Using Orthogonal Fourier Transform Modeling Functions
NASA Technical Reports Server (NTRS)
Morelli, Eugene A.
2013-01-01
A method for transfer function identification, including both model structure determination and parameter estimation, was developed and demonstrated. The approach uses orthogonal modeling functions generated from frequency domain data obtained by Fourier transformation of time series data. The method was applied to simulation data to identify continuous-time transfer function models and unsteady aerodynamic models. Model fit error, estimated model parameters, and the associated uncertainties were used to show the effectiveness of the method for identifying accurate transfer function models from noisy data.
Double passing the Kitt Peak 1-m Fourier transform spectrometer
NASA Technical Reports Server (NTRS)
Jennings, D. E.; Hubbard, R.; Brault, J. W.
1985-01-01
Attention is given to a simple technique for performing the conversion of the Kitt Peak 1-m Fourier transform spectrometer's dual input/output optical configuration to a double pass configuration that improves spectral resolution by a factor of 2. The modification is made by placing a flat mirror in the output beam from each cat's eye, retroreflecting the beams back through the cat's eyes to the first beam splitter. A single detector is placed at the second input port, which then becomes the instrument's output.
Atomic transition probabilities of Ce I from Fourier transform spectra
NASA Astrophysics Data System (ADS)
Nitz, D. E.; Lawler, J. E.; Chisholm, J.; Wood, M. P.; Sobeck, J.; den Hartog, E. A.
2010-03-01
We report transition probabilities for 2874 lines of CeI in the wavelength range 360 -- 1500 nm. These are derived from new branching fraction measurements on Fourier transform spectra normalized with recently-reported radiative lifetimes (Den Hartog et al., J. Phys. B 42, 085006 (2009)). We have analyzed the decay branches for 153 upper levels in 14 different spectra recorded under a variety of discharge lamp conditions. Comparison of results with previous less extensive investigations shows good agreement for lines studied in common. Accurate Ce I transition probabilities are needed for applications in astrophysics and in lighting research, particularly for the development of improved metal halide high-intensity discharge lamps.
Atomic transition probabilities of Ce I from Fourier transform spectra
NASA Astrophysics Data System (ADS)
Lawler, J. E.; Chisholm, J.; Nitz, D. E.; Wood, M. P.; Sobeck, J.; Den Hartog, E. A.
2010-04-01
Atomic transition probabilities for 2874 lines of the first spectrum of cerium (Ce I) are reported. These data are from new branching fraction measurements on Fourier transform spectra normalized with previously reported radiative lifetimes from time-resolved laser-induced-fluorescence measurements (Den Hartog et al 2009 J. Phys. B: At. Mol. Opt. Phys. 42 085006). The wavelength range of the data set is from 360 to 1500 nm. Comparisons are made to previous investigations which are less extensive. Accurate Ce i transition probabilities are needed for lighting research and development on metal halide high-intensity discharge lamps.
Quantum control in two-dimensional Fourier-transform spectroscopy
Lim, Jongseok; Lee, Han-gyeol; Lee, Sangkyung; Ahn, Jaewook
2011-07-15
We present a method that harnesses coherent control capability to two-dimensional Fourier-transform optical spectroscopy. For this, three ultrashort laser pulses are individually shaped to prepare and control the quantum interference involved in two-photon interexcited-state transitions of a V-type quantum system. In experiments performed with atomic rubidium, quantum control for the enhancement and reduction of the 5P{sub 1/2}{yields} 5P{sub 3/2} transition was successfully tested in which the engineered transitions were distinguishably extracted in the presence of dominant one-photon transitions.
Fiber-optic thermometer using Fourier transform spectroscopy
NASA Technical Reports Server (NTRS)
Beheim, Glenn; Sotomayor, Jorge L.; Flatico, Joseph M.; Azar, Massood T.
1991-01-01
An integrated-optic Mach-Zender interferometer is used as a Fourier transform spectrometer to analyze the input and output spectra of a temperature-sensing thin-film etalon. This configuration provides a high degree of immunity to the effects of changes in the source spectrum, and it readily permits the interrogation of a number of different sensors using a single spectrometer. In addition, this system has a potentially low cost because it uses optical communications hardware that may in the future be manufactured in large quantities.
Fourier transform vibrational circular dichroism of small pharmaceutical molecules
NASA Astrophysics Data System (ADS)
Long, Fujin; Freedman, Teresa B.; Nafie, Laurence A.
1998-06-01
Fourier transform vibrational circular dichroism (FT-VCD) spectra of the small pharmaceutical molecules propanolol, ibuprofen and naproxen have been measured in the hydrogen stretching and mid-infrared regions to obtain information on solution conformation and to identify markers for absolute configuration determination. Ab initio molecular orbital calculations of low energy conformations, vibrational frequencies and VCD intensities for fragments of the drugs were utilized in interpreting the spectra. Features characteristic of five conformers of propranolol were identified. The weak positive CH stretching VCD signal in ibuprofen and naproxen is characteristic of the S-configuration of the chiral center common to these two analgesics.
Tests of a compact static Fourier-transform imaging spectropolarimeter.
Li, Jie; Gao, Bo; Qi, Chun; Zhu, Jingping; Hou, Xun
2014-06-02
A compact Fourier-transform imaging spectropolarimeter covering a 450-1000 nm spectral range is presented. The sensor, which is based on two birefringent retarders and a Wollaston interferometer, offers significant advantages over previous implementations. Specifically, with no internal moving parts, electrically controllable or micro polarization components, the full wavelength-dependent state of polarization, spectral and spatial information of a scene can be acquired simultaneously. Outdoor measurements of several cars and plants demonstrate the sensor's potential for color measurement, target identification, and agriculture monitoring applications.
SCUBA-2 Fourier transform spectrometer (FTS-2) commissioning results
NASA Astrophysics Data System (ADS)
Gom, Brad G.; Naylor, David A.; Friberg, Per; Bell, Graham S.; Bintley, Daniel; Abdelazim, Sherif; Sherwood, Matt
2014-07-01
We present the latest commissioning results and instrument performance for the SCUBA-2 imaging Fourier Transform Spectrometer (FTS-2) installed at the James Clerk Maxwell Telescope (JCMT). This ancillary instrument provides intermediate spectral resolution (R ~10 to 5000) across both the 450 and 850 μm atmospheric transmission windows with a FOV of ~5 arcmin2. The superconducting TES sensors and SQUID readout of SCUBA-2 present unique challenges for operation of an FTS; the sensitivity requirements demand high detector linearity and stability in addition to control of systematic atmospheric and optical spillover effects. We discuss the challenges encountered during commissioning and ongoing efforts to mitigate their effects.
Optical fiber interferometer array for scanless Fourier-transform spectroscopy.
Velasco, Aitor V; Cheben, Pavel; Florjańczyk, Mirosław; Schmid, Jens H; Bock, Przemek J; Lapointe, Jean; Delâge, André; Janz, Siegfried; Vachon, Martin; Calvo, María L; Xu, Dan-Xia; Civiš, Svatopluk
2013-07-01
We report a spatial heterodyne Fourier-transform spectrometer implemented with an array of optical fiber interferometers. This configuration generates a wavelength-dependent stationary interferogram from which the input spectrum is retrieved in a single shot without scanning elements. Furthermore, fabrication and experimental deviations from the ideal behavior of the device are corrected by spectral inversion algorithms. The spectral resolution of our system can be readily scaled up by incorporating longer optical fiber delays, providing a pathway toward surpassing current spectroscopy resolution limits.
Particle field holography data reduction by Fourier transform analysis
NASA Technical Reports Server (NTRS)
Hess, Cecil F.; Trolinger, James D.
1987-01-01
The size distribution of a particle field hologram is obtained with a Fourier transformation of the Fraunhofer diffraction pattern of the reconstructed hologram. Off-axis absorption holograms of particle fields with known characteristics were obtained and analyzed with a commercially available instrument. The mean particle size of the reconstructed hologram was measured with an error of + or - 5 percent, while the distribution broadening was estimated within + or - 15 percent. Small sections of a pulsed laser hologram of a synthetic fuel spray were analyzed with this method thus yielding a spatially resolved size distribution. The method yields fast and accurate automated analysis of particle field holograms.
Ordered fast fourier transforms on a massively parallel hypercube multiprocessor
NASA Technical Reports Server (NTRS)
Tong, Charles; Swarztrauber, Paul N.
1989-01-01
Design alternatives for ordered Fast Fourier Transformation (FFT) algorithms were examined on massively parallel hypercube multiprocessors such as the Connection Machine. Particular emphasis is placed on reducing communication which is known to dominate the overall computing time. To this end, the order and computational phases of the FFT were combined, and the sequence to processor maps that reduce communication were used. The class of ordered transforms is expanded to include any FFT in which the order of the transform is the same as that of the input sequence. Two such orderings are examined, namely, standard-order and A-order which can be implemented with equal ease on the Connection Machine where orderings are determined by geometries and priorities. If the sequence has N = 2 exp r elements and the hypercube has P = 2 exp d processors, then a standard-order FFT can be implemented with d + r/2 + 1 parallel transmissions. An A-order sequence can be transformed with 2d - r/2 parallel transmissions which is r - d + 1 fewer than the standard order. A parallel method for computing the trigonometric coefficients is presented that does not use trigonometric functions or interprocessor communication. A performance of 0.9 GFLOPS was obtained for an A-order transform on the Connection Machine.
Voigt line infrared atmospheric transmittance calculations by Fourier transform
NASA Astrophysics Data System (ADS)
Neuendorffer, A. C.
1980-04-01
The absorption coefficient space of an IR atmospheric path contains the linear superposition of many Voigt spectral lines. This paper discusses the practical application of Karp's method to the simulation of satellite transmittance and radiance observations by using fast Fourier transforms on the recursively generated Voigt transforms. Although the procedure is physically straightforward, it is nonetheless computationally demanding and suited primarily to narrow isolated Q-branch regions. Performing the calculation on a 2.4/cm wide 15-micron CO2 Q-branch region demonstrates that 4% of the total absorption takes place above 0.1 mb. This absorption is in the cold mesopause and results in a 1-2% radiation deficit with its inclusion in a satellite radiation calculation.
2D discrete Fourier transform on sliding windows.
Park, Chun-Su
2015-03-01
Discrete Fourier transform (DFT) is the most widely used method for determining the frequency spectra of digital signals. In this paper, a 2D sliding DFT (2D SDFT) algorithm is proposed for fast implementation of the DFT on 2D sliding windows. The proposed 2D SDFT algorithm directly computes the DFT bins of the current window using the precalculated bins of the previous window. Since the proposed algorithm is designed to accelerate the sliding transform process of a 2D input signal, it can be directly applied to computer vision and image processing applications. The theoretical analysis shows that the computational requirement of the proposed 2D SDFT algorithm is the lowest among existing 2D DFT algorithms. Moreover, the output of the 2D SDFT is mathematically equivalent to that of the traditional DFT at all pixel positions.
Fast Fourier Transform Co-Processor (FFTC)- Towards Embedded GFLOPs
NASA Astrophysics Data System (ADS)
Kuehl, Christopher; Liebstueckel, Uwe; Tejerina, Isaac; Uemminghaus, Michael; Wite, Felix; Kolb, Michael; Suess, Martin; Weigand, Roland
2012-08-01
Many signal processing applications and algorithms perform their operations on the data in the transform domain to gain efficiency. The Fourier Transform Co- Processor has been developed with the aim to offload General Purpose Processors from performing these transformations and therefore to boast the overall performance of a processing module. The IP of the commercial PowerFFT processor has been selected and adapted to meet the constraints of the space environment.In frame of the ESA activity “Fast Fourier Transform DSP Co-processor (FFTC)” (ESTEC/Contract No. 15314/07/NL/LvH/ma) the objectives were the following:Production of prototypes of a space qualified version of the commercial PowerFFT chip called FFTC based on the PowerFFT IP.The development of a stand-alone FFTC Accelerator Board (FTAB) based on the FFTC including the Controller FPGA and SpaceWire Interfaces to verify the FFTC function and performance.The FFTC chip performs its calculations with floating point precision. Stand alone it is capable computing FFTs of up to 1K complex samples in length in only 10μsec. This corresponds to an equivalent processing performance of 4.7 GFlops. In this mode the maximum sustained data throughput reaches 6.4Gbit/s. When connected to up to 4 EDAC protected SDRAM memory banks the FFTC can perform long FFTs with up to 1M complex samples in length or multidimensional FFT- based processing tasks.A Controller FPGA on the FTAB takes care of the SDRAM addressing. The instructions commanded via the Controller FPGA are used to set up the data flow and generate the memory addresses.The presentation will give and overview on the project, including the results of the validation of the FFTC ASIC prototypes.
Fast Fourier Transform Co-processor (FFTC), towards embedded GFLOPs
NASA Astrophysics Data System (ADS)
Kuehl, Christopher; Liebstueckel, Uwe; Tejerina, Isaac; Uemminghaus, Michael; Witte, Felix; Kolb, Michael; Suess, Martin; Weigand, Roland; Kopp, Nicholas
2012-10-01
Many signal processing applications and algorithms perform their operations on the data in the transform domain to gain efficiency. The Fourier Transform Co-Processor has been developed with the aim to offload General Purpose Processors from performing these transformations and therefore to boast the overall performance of a processing module. The IP of the commercial PowerFFT processor has been selected and adapted to meet the constraints of the space environment. In frame of the ESA activity "Fast Fourier Transform DSP Co-processor (FFTC)" (ESTEC/Contract No. 15314/07/NL/LvH/ma) the objectives were the following: • Production of prototypes of a space qualified version of the commercial PowerFFT chip called FFTC based on the PowerFFT IP. • The development of a stand-alone FFTC Accelerator Board (FTAB) based on the FFTC including the Controller FPGA and SpaceWire Interfaces to verify the FFTC function and performance. The FFTC chip performs its calculations with floating point precision. Stand alone it is capable computing FFTs of up to 1K complex samples in length in only 10μsec. This corresponds to an equivalent processing performance of 4.7 GFlops. In this mode the maximum sustained data throughput reaches 6.4Gbit/s. When connected to up to 4 EDAC protected SDRAM memory banks the FFTC can perform long FFTs with up to 1M complex samples in length or multidimensional FFT-based processing tasks. A Controller FPGA on the FTAB takes care of the SDRAM addressing. The instructions commanded via the Controller FPGA are used to set up the data flow and generate the memory addresses. The paper will give an overview on the project, including the results of the validation of the FFTC ASIC prototypes.
Progress report of a static Fourier transform spectrometer breadboard
NASA Astrophysics Data System (ADS)
Rosak, A.; Tintó, F.
2004-06-01
MOLI instrument - for MOtionLess Interferometer - takes advantage of the new concept of static Fourier transform spectrometer. It is a high-resolution spectrometer working over a narrow bandwidth, which is adapted to a wide range of atmospheric sounding missions and compatible with micro-satellite platform. The core of this instrument is an echelette cube. Mirrors on the classical design are replaced by stepped mirrors - integrated into that interference cube - thus suppressing any moving part. The steps' directions being set over a perpendicular axis, the overlap of both stepped mirrors creates a cluster of so-called "echelettes", each one corresponding to a different optical path difference (OPD). Hence the Fourier transform of the incoming radiance is directly imaged on a CCD array in a single acquisition. The frequency domain of the measurements is selected by an interferential filter disposed on the incoming optical path. A rotating wheel equipped with several filters allows the successive measurement of spectra around some bands of interest, i.e. O2, CO2 and CO absorption bands.
Soft x-ray microscope using Fourier transform holography
McNulty, I.; Kirz, J.; Jacobsen, C.; Anderson, E.; Howells, M.R.; Rarback, H. . Dept. of Physics; Lawrence Berkeley Lab., CA; Brookhaven National Lab., Upton, NY )
1989-01-01
A Fourier transform holographic microscope with an anticipated resolution of better than 100 nm has been built. Extensive testing of the apparatus has begun. Preliminary results include the recording of interference fringes using 3.6 nm x-rays. The microscope employs a charge-coupled device (CCD) detector array of 576 {times} 384 elements. The system is illuminated by soft x-rays from a high brightness undulator. The reference point source is formed by a Fresnel zone plate with a finest outer zone width of 50 nm. Sufficient temporal coherence for hologram formation is obtained by a spherical grating monochromator. The x-ray hologram intensities at the recording plane are to be collected, digitized and reconstructed by computer. Data acquisition is under CAMAC control, while image display and off-line processing takes place on a VAX graphics workstation. Computational models of Fourier transform hologram synthesis, and reconstruction in the presence of noise, have demonstrated the feasibility of numerical methods in two dimensions, and that three-dimensional information is potentially recoverable. 13 refs., 3 figs.
The Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS): noise performance
NASA Astrophysics Data System (ADS)
Taylor, Joe K.; Revercomb, Henry E.; Tobin, David C.; Best, Fred A.; Knuteson, Robert O.; Elwell, John D.; Cantwell, Gregory W.; Scott, Deron K.; Bingham, Gail E.; Smith, William L.; Zhou, Daniel K.; Reisse, Robert A.
2006-12-01
The NASA New Millennium Program (NMP) Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) instrument was designed to demonstrate new and emerging technologies and provide immense improvements in satellite based remote sensing of the atmosphere from a geostationary orbit [1]. Combining a Fourier Transform Spectrometer (FTS) and Large Area Focal Plane Arrays, GIFTS measures incident infrared radiance with an extraordinary combination of spectral, temporal, and spatial resolution and coverage. Thermal vacuum testing of the GIFTS Engineering Development Unit (EDU) was performed at the Space Dynamics Laboratory and completed in May 2006 [2,3]. The GIFTS noise performance measured during EDU thermal vacuum testing indicates that threshold performance has been realized, and that goal performance (or better) has been achieved over much of both the Longwave Infrared (LWIR) and Short/Midwave Infrared (SMWIR) detector bands. An organizational structure for the division of the noise sources and effects for the GIFTS instrument is presented. To comprehensively characterize and predict the effects of measurement noise on expected instrument performance, the noise sources are categorically divided and a method of combining the independent effects is defined. Within this architecture, the total noise is principally decomposed into spectrally correlated noise and random (spectrally uncorrelated) noise. The characterization of the spectrally correlated noise sources specified within the structure is presented in detail.
Chiral Analysis of Isopulegol by Fourier Transform Molecular Rotational Spectroscopy
NASA Astrophysics Data System (ADS)
Evangelisti, Luca; Seifert, Nathan A.; Spada, Lorenzo; Pate, Brooks
2016-06-01
Chiral analysis on molecules with multiple chiral centers can be performed using pulsed-jet Fourier transform rotational spectroscopy. This analysis includes quantitative measurement of diastereomer products and, with the three wave mixing methods developed by Patterson, Schnell, and Doyle (Nature 497, 475-477 (2013)), quantitative determination of the enantiomeric excess of each diastereomer. The high resolution features enable to perform the analysis directly on complex samples without the need for chromatographic separation. Isopulegol has been chosen to show the capabilities of Fourier transform rotational spectroscopy for chiral analysis. Broadband rotational spectroscopy produces spectra with signal-to-noise ratio exceeding 1000:1. The ability to identify low-abundance (0.1-1%) diastereomers in the sample will be described. Methods to rapidly identify rotational spectra from isotopologues at natural abundance will be shown and the molecular structures obtained from this analysis will be compared to theory. The role that quantum chemistry calculations play in identifying structural minima and estimating their spectroscopic properties to aid spectral analysis will be described. Finally, the implementation of three wave mixing techniques to measure the enantiomeric excess of each diastereomer and determine the absolute configuration of the enantiomer in excess will be described.
Fourier-Transform Ghost Imaging with Hard X Rays
NASA Astrophysics Data System (ADS)
Yu, Hong; Lu, Ronghua; Han, Shensheng; Xie, Honglan; Du, Guohao; Xiao, Tiqiao; Zhu, Daming
2016-09-01
Knowledge gained through x-ray crystallography fostered structural determination of materials and greatly facilitated the development of modern science and technology in the past century. However, it is only applied to crystalline structures and cannot resolve noncrystalline materials. Here we demonstrate a novel lensless Fourier-transform ghost imaging method with pseudothermal hard x rays that extends x-ray crystallography to noncrystalline samples. By measuring the second-order intensity correlation function of the light, Fourier-transform diffraction pattern of a complex amplitude sample is achieved at the Fresnel region in our experiment and the amplitude and phase distributions of the sample in the spatial domain are retrieved successfully. For the first time, ghost imaging is experimentally realized with x rays. Since a highly coherent x-ray source is not required, the method can be implemented with laboratory x-ray sources and it also provides a potential solution for lensless diffraction imaging with fermions, such as neutrons and electrons where intensive coherent sources usually are not available.
Versatile and Sensitive Dual Comb Fourier Transform Spectroscopy
NASA Astrophysics Data System (ADS)
Jacquey, M.; Jacquet, P.; Mandon, J.; Thon, R.; Guelachvili, G.; Hänsch, T. W.; Picqué, N.
2010-06-01
Fourier transform spectroscopy based on time-domain interferences between two slightly detuned frequency comb sources holds much promise for the real-time diagnostic of gaseous, liquid or solid-state samples. In one very recent example, cavity-enhanced absorption spectroscopy with two infrared frequency combs has demonstrated a dramatically enhanced sensitivity, compared to conventional Fourier spectroscopy, with intriguing implications for instantaneous trace gas analysis. It however remains challenging to match continuously the comb and cavity modes across a broad spectral bandwidth during the time of a measurement. An obvious alternative for reaching a long interaction path is a conventional multipass cell. Additionally, differential detection schemes may be devised to increase the dynamic range of the interferometric measurements, thus providing enhanced signal to noise ratio. Experimental demonstrations will be given in the 1.5 μm region with a dual comb set-up based on two Er-doped fiber femtosecond lasers. The versatility and performances of these solutions will be compared to the cavity-enhanced dual comb technique and other state-of-the-art alternatives. P. Jacquet, J. Mandon, B. Bernhardt, R. Holzwarth, G. Guelachvili, T. W. Hänsch, N. Picqué, Frequency Comb Fourier Transform Spectroscopy with kHz Optical Resolution, The Optical Society of America, Washington, DC 2009, paper FMB2 (2009). B. Bernhardt, A. Ozawa, P. Jacquet, M. Jacquey, Y. Kobayashi, T. Udem, R. Holzwarth, G. Guelachvili, T.W. Hänsch, N. Picqué, Cavity-enhanced dual-comb spectroscopy, Nature Photonics 4, 55-57 (2010),
Dai, Guang-Ming
2006-02-15
The set of Fourier series is discussed following some discussion of Zernike polynomials. Fourier transforms of Zernike polynomials are derived that allow for relating Fourier series expansion coefficients to Zernike polynomial expansion coefficients. With iterative Fourier reconstruction, Zernike representations of wavefront aberrations can easily be obtained from wavefront derivative measurements.
Andrianov, Alexey; Szabo, Aron; Sergeev, Alexander; Kim, Arkady; Chvykov, Vladimir; Kalashnikov, Mikhail
2016-11-14
We developed an improved approach to calculate the Fourier transform of signals with arbitrary large quadratic phase which can be efficiently implemented in numerical simulations utilizing Fast Fourier transform. The proposed algorithm significantly reduces the computational cost of Fourier transform of a highly chirped and stretched pulse by splitting it into two separate transforms of almost transform limited pulses, thereby reducing the required grid size roughly by a factor of the pulse stretching. The application of our improved Fourier transform algorithm in the split-step method for numerical modeling of CPA and OPCPA shows excellent agreement with standard algorithms.
Gas emission analysis based on Fourier transformed infrared spectroscopy
NASA Astrophysics Data System (ADS)
Shu, Xiaowen; Zhang, Xiaofu; Lian, Xu; Jin, Hui
2014-12-01
Solar occultation flux (SOF), a new optical technology to detect the gas based on the traditional Fourier transformed infrared spectroscopy (FTIR) developed quickly recently. In this paper, the system and the data analysis is investigated. First a multilayer transmission model of solar radiation is simulated. Then the retrieval process is illustrated. In the proceeding of the data analysis, the Levenberg-Marquardt non-linear square fitting is used to obtain the gas column concentration and the related emission ratio. After the theory certification, the built up system is conducted in a fertilizer plant in Hefei city .The results show SOF is available in the practice and the retrieved gas column concentration can give important information about the pollution emission and dispersion
Wide-Field Detected Fourier Transform CARS Microscopy
Duarte, Alex Soares; Schnedermann, Christoph; Kukura, Philipp
2016-01-01
We present a wide-field imaging implementation of Fourier transform coherent anti-Stokes Raman scattering (wide-field detected FT-CARS) microscopy capable of acquiring high-contrast label-free but chemically specific images over the full vibrational ‘fingerprint’ region, suitable for a large field of view. Rapid resonant mechanical scanning of the illumination beam coupled with highly sensitive, camera-based detection of the CARS signal allows for fast and direct hyperspectral wide-field image acquisition, while minimizing sample damage. Intrinsic to FT-CARS microscopy, the ability to control the range of time-delays between pump and probe pulses allows for fine tuning of spectral resolution, bandwidth and imaging speed while maintaining full duty cycle. We outline the basic principles of wide-field detected FT-CARS microscopy and demonstrate how it can be used as a sensitive optical probe for chemically specific Raman imaging. PMID:27881844
Sound resonance in pipes with discrete Fourier transform
NASA Astrophysics Data System (ADS)
Aljalal, Abdulaziz M.
2015-09-01
Sound resonance in pipes is investigated using a readily available setup consisting of a pipe, loudspeaker, microphone, and laptop. Discrete Fourier transform is used to extract the amplitude and phase spectra from the recorded sound enabling determination of locations and shapes of resonance peaks accurately. Either white noise signal or sharp pulse signal is used as an excited input sound signal. Both have broad frequency spectra and the difference between them is explored. The shapes of the amplitude and phase spectra are found to be well fitted to the predicted shapes. The pipe is either closed at both ends, closed at only one end, or open at both ends. The speed of sound and the effective location of reflection at the open end are in excellent agreement with theory.
Process control using fiber optics and Fourier transform infrared spectroscopy
NASA Astrophysics Data System (ADS)
Kemsley, E. K.; Wilson, Reginald H.
1992-03-01
A process control system has been constructed using optical fibers interfaced to a Fourier transform infrared (FT-IR) spectrometer, to achieve remote spectroscopic analysis of food samples during processing. The multichannel interface accommodates six fibers, allowing the sequential observation of up to six samples. Novel fiber-optic sampling cells have been constructed, including transmission and attenuated total reflectance (ATR) designs. Different fiber types have been evaluated; in particular, plastic clad silica (PCS) and zirconium fluoride fibers. Processes investigated have included the dilution of fruit juice concentrate, and the addition of alcohol to fruit syrup. Suitable algorithms have been written which use the results of spectroscopic measurements to control and monitor the course of each process, by actuating devices such as valves and switches.
A rheumatoid arthritis study by Fourier transform infrared spectroscopy
NASA Astrophysics Data System (ADS)
Carvalho, Carolina S.; Silva, Ana Carla A.; Santos, Tatiano J. P. S.; Martin, Airton A.; dos Santos Fernandes, Ana Célia; Andrade, Luís E.; Raniero, Leandro
2012-01-01
Rheumatoid arthritis is a systemic inflammatory disease of unknown causes and a new methods to identify it in early stages are needed. The main purpose of this work is the biochemical differentiation of sera between normal and RA patients, through the establishment of a statistical method that can be appropriately used for serological analysis. The human sera from 39 healthy donors and 39 rheumatics donors were collected and analyzed by Fourier Transform Infrared Spectroscopy. The results show significant spectral variations with p<0.05 in regions corresponding to protein, lipids and immunoglobulins. The technique of latex particles, coated with human IgG and monoclonal anti-CRP by indirect agglutination known as FR and CRP, was performed to confirm possible false-negative results within the groups, facilitating the statistical interpretation and validation of the technique.
Calibration of the Geostationary Imaging Fourier Transform Spectrometer (GIFTS)
NASA Technical Reports Server (NTRS)
Best, F. A.; Revercomb, H. E.; Bingham, G. E.; Knuteson, R. O.; Tobin, D. C.; LaPorte, D. D.; Smith, W. L.
2001-01-01
The NASA New Millennium Program's Geostationary Imaging Fourier Transform Spectrometer (GIFTS) requires highly accurate radiometric and spectral calibration in order to carry out its mission to provide water vapor, wind, temperature, and trace gas profiling from geostationary orbit. A calibration concept has been developed for the GIFTS Phase A instrument design. The in-flight calibration is performed using views of two on-board blackbody sources along with cold space. A radiometric calibration uncertainty analysis has been developed and used to show that the expected performance for GIFTS exceeds its top level requirement to measure brightness temperature to better than 1 K. For the Phase A GIFTS design, the spectral calibration is established by the highly stable diode laser used as the reference for interferogram sampling, and verified with comparisons to atmospheric calculations.
Microscope system with on axis programmable Fourier transform filtering
NASA Astrophysics Data System (ADS)
Martínez, José Luis; García-Martínez, Pascuala; Moreno, Ignacio
2017-02-01
We propose an on-axis microscope optical system to implement programmable optical Fourier transform image processing operations, taking advantage of phase and polarization modulation of a liquid crystal on silicon (LCOS) display. We use a Hamamatsu spatial light modulator (SLM), free of flickering, which therefore can be tuned to fully eliminate the zero order component of the encoded diffractive filter. This allows the realization of filtering operation on axis (as opposed to other systems in the literature that require operating off axis), therefore making use of the full space bandwidth provided by the SLM. The system is first demonstrated by implementing different optical processing operations based on phase-only blazed gratings such as phase contrast, band-pass filtering, or additive and substractive imaging. Then, a simple Differential interference contrast (DIC) imaging is obtained changing to a polarization modulation scheme, achieved simply by selecting a different incident state of polarization on the incident beam.
Generation of Fourier-transform-limited heralded single photons
U'Ren, Alfred B.; Jeronimo-Moreno, Yasser; Garcia-Gracia, Hipolito
2007-02-15
In this paper we study the spectral (temporal) properties of heralded single photon wave packets, triggered by the detection of an idler photon in the process of parametric down conversion. The generated single photons are studied within the framework of the chronocyclic Wigner function, from which the single photon spectral width and temporal duration can be computed. We derive specific conditions on the two-photon joint spectral amplitude which result in both pure and Fourier-transform-limited heralded single photons. Likewise, we present specific source geometries which lead to the fulfillment of these conditions and show that one of these geometries leads, for a given pump bandwidth, to the temporally shortest possible heralded single photon wave packets.
Multifunctional metasurface lens for imaging and Fourier transform
Wen, Dandan; Yue, Fuyong; Ardron, Marcus; Chen, Xianzhong
2016-01-01
A metasurface can manipulate light in a desirable manner by imparting local and space-variant abrupt phase change. Benefiting from such an unprecedented capability, the conventional concept of what constitutes an optical lens continues to evolve. Ultrathin optical metasurface lenses have been demonstrated based on various nanoantennas such as V-shape structures, nanorods and nanoslits. A single device that can integrate two different types of lenses and polarities is desirable for system integration and device miniaturization. We experimentally demonstrate such an ultrathin metasurface lens that can function either as a spherical lens or a cylindrical lens, depending on the helicity of the incident light. Helicity-controllable focal line and focal point in the real focal plane, as well as imaging and 1D/2D Fourier transforms, are observed on the same lens. Our work provides a unique tool for polarization imaging, image processing and particle trapping. PMID:27272601
Betti numbers of holomorphic symplectic quotients via arithmetic Fourier transform
Hausel, Tamás
2006-01-01
A Fourier transform technique is introduced for counting the number of solutions of holomorphic moment map equations over a finite field. This technique in turn gives information on Betti numbers of holomorphic symplectic quotients. As a consequence, simple unified proofs are obtained for formulas of Poincaré polynomials of toric hyperkähler varieties (recovering results of Bielawski–Dancer and Hausel–Sturmfels), Poincaré polynomials of Hilbert schemes of points and twisted Atiyah–Drinfeld–Hitchin–Manin (ADHM) spaces of instantons on ℂ2 (recovering results of Nakajima–Yoshioka), and Poincaré polynomials of all Nakajima quiver varieties. As an application, a proof of a conjecture of Kac on the number of absolutely indecomposable representations of a quiver is announced. PMID:16606857
Identification of Amanita mushrooms by fourier transform infrared spectroscopy
NASA Astrophysics Data System (ADS)
Zhao, Dezhang; Liu, Gang; Song, Dingshan; Liu, Jian-hong; Zhou, Yilan; Ou, Jiaming; Sun, Shizhong
2006-09-01
Amanita is one of cosmopolitan genera of basidiomycetes. This genus contains some of the most poisonous toadstools, as well as several species of the most favorite edible mushrooms. In this paper, Fourier transform infrared spectroscopy was used for obtaining vibrational spectra of the fruiting bodies of wild growing Amanita mushrooms. The results show that the mushrooms exhibit characteristic spectra, whose strong absorption bands appear at about 1655, 1076, and 1040 cm -1. The vibrational spectra indicate that the main compositions of the Amanita mushrooms are proteins and polysaccharides. The observed spectral differences might be used to discriminate different species of Amanita. It is showed that FTIR spectroscopic method is a valuable tool for rapid and nondestructive identification of Amanita mushrooms.
Analysis of far-infrared emission Fourier transform spectra
NASA Technical Reports Server (NTRS)
Park, J. H.; Carli, B.
1986-01-01
An analysis method that uses the nonlinear least-squares fit technique has been developed for emission spectra obtained with a Fourier transform spectrometer. This method is used for the analysis of submillimeter-region atmospheric emission spectra obtained with a balloon-borne FT spectrometer that was carried out as a correlative measurement for the Limb IR Monitor of the Stratosphere (LIMS) satellite experiment. The retrieved mixing ratios of H2O and O3 in the stratosphere from four spectral intervals have standard deviations of about 10 percent, and the average values agree to within 10 percent of corresponding results from the LIMS satellite experiment which used a broadband emission radiometer in the IR region.
Development of galvanostatic Fourier transform electrochemical impedance spectroscopy.
Nam, Kwang-Mo; Shin, Dong-Hyup; Jung, Namchul; Joo, Moon G; Jeon, Sangmin; Park, Su-Moon; Chang, Byoung-Yong
2013-02-19
Here, we report development of the galvanostatic Fourier transform electrochemical impedance spectroscopy (FTEIS), which monitors impedance of electrochemical reactions activated by current steps. We first derive relevant relations for potential change upon application of a step current, obtain impedances theoretically from the relations by simulation, and verify them with experimental results. The validity of the galvanostatic FTEIS technique is demonstrated by measuring impedances of a semiconductive silicon wafer using the conventional frequency response analysis (FRA), the potentiostatic FTEIS, and the galvanostatic FTEIS methods, and the results are in excellent agreement with each other. This work is significant in that the galvanostatic FTEIS would allow one to record impedance changes during charge/discharge cycles of secondary batteries and fuel cells as well as electrochemically irreversible systems which may produce noise level chronoamperometric currents by potentiostatic techniques.
Eliminating the picket fence effect of the fast Fourier transform
NASA Astrophysics Data System (ADS)
Li, Yan Feng; Chen, Kui Fu
2008-04-01
The canonical fast Fourier transform (FFT) is afflicted by the picket fence effect (PFE). This can be ascribed to the simplification caused by viewing non-parametrically. For a periodic signal composed of frequency well-separated tones, a complex formula for retrieving a tone's frequency can be derived in light of the parametric relationship among the FFT spectral lines around each tone's main-lobe. Compared to the modulus-based interpolated FFT, this complex spectrum-based approach is less sensitive to spectral leakage. The frequency, amplitude and phase retrieving formulas are presented for the generalized Hamming window, which is used frequently in physics but seldom mentioned in the interpolated FFT literature. Numerical simulation shows that the FPE can be eliminated efficiently by this approach.
Indirect Fourier transform in the context of statistical inference.
Muthig, Michael; Prévost, Sylvain; Orglmeister, Reinhold; Gradzielski, Michael
2016-09-01
Inferring structural information from the intensity of a small-angle scattering (SAS) experiment is an ill-posed inverse problem. Thus, the determination of a solution is in general non-trivial. In this work, the indirect Fourier transform (IFT), which determines the pair distance distribution function from the intensity and hence yields structural information, is discussed within two different statistical inference approaches, namely a frequentist one and a Bayesian one, in order to determine a solution objectively From the frequentist approach the cross-validation method is obtained as a good practical objective function for selecting an IFT solution. Moreover, modern machine learning methods are employed to suppress oscillatory behaviour of the solution, hence extracting only meaningful features of the solution. By comparing the results yielded by the different methods presented here, the reliability of the outcome can be improved and thus the approach should enable more reliable information to be deduced from SAS experiments.
On the abstracted dataflow complexity of Fast Fourier Transforms
Boehm, A.P.W.; Hiromoto, R.E.; Kelly, K.A.; Ashley, J.M.
1992-05-01
In this paper we develop and analyze the simulated performance of codes for the Fast Fourier Transform written in If and targeted for execution on Motorola`s dataflow machine Monsoon. The FFT application is of interest because of its computational parallelism, its requirement for global communications, and its array element data dependences. We use the parallel profiling simulator Id World to study the dataflow performance of various implementations. Our approach is comparative. We study two approaches, a recursive and an iterative one, and in each version we examine the effect of a variety of implementations. We contend that only through such comparative evaluations can significant insight be gained in understanding the computational and structural details of functional algorithms.
[Identification of gastrodia elata blume by Fourier transform infrared spectroscopy].
Liu, Gang; Dong, Qin; Yu, Fan; Liu, Jian-hong; Sun, Shi-zhong
2004-03-01
In this paper, a method of rapid and undamaged identification of wild and cultivated Gastrodia elata Blume, and one of its fakes by Fourier transform infrared spectroscopy (FTIR) is reported. The results show that Gastrodia elata Blume and its fake have different characteristic infrared spectra, by which Gastrodia elata Blume can be identified from its fake. Wild winter, wild spring, and cultivated Gastrodia elata Blume can be discriminated by FTIR, according to the differences of their spectral peaks and absorbance ratios. By the differences of absorbance ratios of several peaks, different grade of Gastrodia elata Blume may be classified. FTIR has proved to be a rapid, simple and nondestructive method for the identification of Gastrodia elata Blume.
A direct digital synthesis chirped pulse Fourier transform microwave spectrometer.
Finneran, Ian A; Holland, Daniel B; Carroll, P Brandon; Blake, Geoffrey A
2013-08-01
Chirped pulse Fourier transform microwave (CP-FTMW) spectrometers have become the instrument of choice for acquiring rotational spectra, due to their high sensitivity, fast acquisition rate, and large bandwidth. Here we present the design and capabilities of a recently constructed CP-FTMW spectrometer using direct digital synthesis (DDS) as a new method for chirped pulse generation, through both a suite of extensive microwave characterizations and deep averaging of the 10-14 GHz spectrum of jet-cooled acetone. The use of DDS is more suited for in situ applications of CP-FTMW spectroscopy, as it reduces the size, weight, and power consumption of the chirp generation segment of the spectrometer all by more than an order of magnitude, while matching the performance of traditional designs. The performance of the instrument was further improved by the use of a high speed digitizer with dedicated signal averaging electronics, which facilitates a data acquisition rate of 2.1 kHz.
Collision-induced dissociation with Fourier transform mass spectrometry
Cody, R.B.; Burnier, R.C.; Freiser, B.S.
1982-01-01
Collision-induced dissociations (CID) is demonstrated on a number of primary and secondary ions using a Nicolet prototype Fourier transform mass spectrometer (FT-MS). Like the triple quadrupole technique, CID using FT-MS is a relatively low energy and efficient process. The ability to study a wide range of ion-molecule reaction products is exemplified by results on proton-bound dimers and transition metal containing ionic species. Variation of collision energy by varying the RF irradiation level can provide information about product distributions as a function of energy as well as yield ion structural information. Like the triple quadrupole technique, no slits are employed and virtually all of the fragment ions formed by the CID process may be detected. Unlike all previous mass spectrometric techniques for studying CID, a tandem instrument is not required, and different experiments are performed by making software modifications rather than hardware modifications.
Wide-Field Detected Fourier Transform CARS Microscopy
NASA Astrophysics Data System (ADS)
Duarte, Alex Soares; Schnedermann, Christoph; Kukura, Philipp
2016-11-01
We present a wide-field imaging implementation of Fourier transform coherent anti-Stokes Raman scattering (wide-field detected FT-CARS) microscopy capable of acquiring high-contrast label-free but chemically specific images over the full vibrational ‘fingerprint’ region, suitable for a large field of view. Rapid resonant mechanical scanning of the illumination beam coupled with highly sensitive, camera-based detection of the CARS signal allows for fast and direct hyperspectral wide-field image acquisition, while minimizing sample damage. Intrinsic to FT-CARS microscopy, the ability to control the range of time-delays between pump and probe pulses allows for fine tuning of spectral resolution, bandwidth and imaging speed while maintaining full duty cycle. We outline the basic principles of wide-field detected FT-CARS microscopy and demonstrate how it can be used as a sensitive optical probe for chemically specific Raman imaging.
Structural Characterization of Carbohydrates by Fourier Transform Tandem Mass Spectrometry
Zhou, Wen; Håkansson, Kristina
2012-01-01
Fourier transform tandem mass spectrometry (MS/MS) provides high mass accuracy, high sensitivity, and analytical versatility and has therefore emerged as an indispensable tool for structural elucidation of biomolecules. Glycosylation is one of the most common posttranslational modifications, occurring in ~50% of proteins. However, due to the structural diversity of carbohydrates, arising from non-template driven biosynthesis, achievement of detailed structural insight is highly challenging. This review briefly discusses carbohydrate sample preparation and ionization methods, and highlights recent developments in alternative high-resolution MS/MS strategies, including infrared multiphoton dissociation (IRMPD), electron capture dissociation (ECD), and electron detachment dissociation (EDD), for carbohydrates with a focus on glycans and proteoglycans from mammalian glycoproteins. PMID:22389641
Motion saliency detection using a temporal fourier transform
NASA Astrophysics Data System (ADS)
Chen, Zhe; Wang, Xin; Sun, Zhen; Wang, Zhijian
2016-06-01
Motion saliency detection aims at detecting the dynamic semantic regions in a video sequence. It is very important for many vision tasks. This paper proposes a new type of motion saliency detection method, Temporal Fourier Transform, for fast motion saliency detection. Different from conventional motion saliency detection methods that use complex mathematical models or features, variations in the phase spectrum of consecutive frames are identified and extracted as the key to obtaining the location of salient motion. As all the calculation is made on the temporal frequency spectrum, our model is independent of features, background models, or other forms of prior knowledge about scenes. The benefits of the proposed approach are evaluated for various videos where the number of moving objects, illumination, and background are all different. Compared with some the state of the art methods, our method achieves both good accuracy and fast computation.
Betti numbers of holomorphic symplectic quotients via arithmetic Fourier transform
NASA Astrophysics Data System (ADS)
Hausel, Tamás
2006-04-01
A Fourier transform technique is introduced for counting the number of solutions of holomorphic moment map equations over a finite field. This technique in turn gives information on Betti numbers of holomorphic symplectic quotients. As a consequence, simple unified proofs are obtained for formulas of Poincaré polynomials of toric hyperkähler varieties (recovering results of Bielawski-Dancer and Hausel-Sturmfels), Poincaré polynomials of Hilbert schemes of points and twisted Atiyah-Drinfeld-Hitchin-Manin (ADHM) spaces of instantons on 2 (recovering results of Nakajima-Yoshioka), and Poincaré polynomials of all Nakajima quiver varieties. As an application, a proof of a conjecture of Kac on the number of absolutely indecomposable representations of a quiver is announced. quiver varieties | Weyl-Kac character formula
How to tickle spins with a fourier transform NMR spectrometer.
Segawa, Takuya F; Carnevale, Diego; Bodenhausen, Geoffrey
2013-02-04
In the long bygone days of continuous-wave nuclear magnetic resonance (NMR) spectroscopy, a selected transition within a multiplet of a high-resolution spectrum could be irradiated by a highly selective continuous-wave (CW) radio-frequency (rf) field with a very weak amplitude ω(2)/(2π)≤J. This causes splittings of connected transitions, allowing one to map the connectivities of all transitions within the energy-level diagram of the spin system. Such "tickling" experiments stimulated the invention of two-dimensional spectroscopy, but seem to have been forgotten for nearly 50 years. We show that tickling can readily be achieved in homonuclear systems with Fourier transform spectrometers by applying short pulses in the intervals between the sampling points. Extensions to heteronuclear systems are even more straightforward since they can be carried out using very weak CW rf fields.
Száraz, Ildikó; Forsling, Willis
2003-06-01
The interaction between y-aluminum oxide and an ethylene glycol (EG) based capacitor electrolyte was investigated by Fourier transform infrared (FT-IR) spectroscopy. It was found that only a few ingredients of the electrolyte react with the oxide (azelaic acid, poly(1-vinyl-2-pyrrolidone) (PVP), and phosphoric acid); the others act as pH or conductivity buffers (boric acid, ammonia, and water). The adsorption of azelaic acid and PVP from the electrolyte was studied as a function of temperature, pH, and time, and the result was compared to the adsorption from model solutions of simpler composition. The influence of other components such as phosphoric acid both in the electrolyte and on the aluminum oxide was also investigated, as was the presence of water. At low pH and high temperature (T > or = 105 degrees C) the acid formed an ester with EG and this product adsorbed on the oxide surface. The PVP was attached to the adsorbed azelaic acid by hydrophobic interaction, which is pH independent. Ester formation was found to be catalyzed by other electrolyte ingredients like boric acid. At high pH, surface adsorption of azelaic acid occurs through a deprotonated species, which is mainly coordinated through outer-sphere complexation. At high temperature or after a long equilibration time, the surface of the alumina changed, resulting in less adsorption of the organic substances, independent of pH. This change is due to a selective adsorption of phosphate species from the electrolyte, which block active surface sites.
Fourier domain target transformation analysis in the thermal infrared
NASA Technical Reports Server (NTRS)
Anderson, D. L.
1993-01-01
Remote sensing uses of principal component analysis (PCA) of multispectral images include band selection and optimal color selection for display of information content. PCA has also been used for quantitative determination of mineral types and abundances given end member spectra. The preliminary results of the investigation of target transformation PCA (TTPCA) in the fourier domain to both identify end member spectra in an unknown spectrum, and to then calculate the relative concentrations of these selected end members are presented. Identification of endmember spectra in an unknown sample has previously been performed through bandmatching, expert systems, and binary classifiers. Both bandmatching and expert system techniques require the analyst to select bands or combinations of bands unique to each endmember. Thermal infrared mineral spectra have broad spectral features which vary subtly with composition. This makes identification of unique features difficult. Alternatively, whole spectra can be used in the classification process, in which case there is not need for an expert to identify unique spectra. Use of binary classifiers on whole spectra to identify endmember components has met with some success. These techniques can be used, along with a least squares fit approach on the endmembers identified, to derive compositional information. An alternative to the approach outlined above usese target transformation in conjunction with PCA to both identify and quantify the composition of unknown spectra. Preprocessing of the library and unknown spectra into the fourier domain, and using only a specific number of the components, allows for significant data volume reduction while maintaining a linear relationship in a Beer's Law sense. The approach taken here is to iteratively calculate concentrations, reducing the number of endmember components until only non-negative concentrations remain.
NASA Astrophysics Data System (ADS)
Vilardy, Juan M.; Torres, Yezid; Millán, María S.; Pérez-Cabré, Elisabet
2014-12-01
We propose a generalization of the encryption system based on double random phase encoding (DRPE) and a joint transform correlator (JTC), from the Fourier domain to the fractional Fourier domain (FrFD) by using the fractional Fourier operators, such as the fractional Fourier transform (FrFT), fractional traslation, fractional convolution and fractional correlation. Image encryption systems based on a JTC architecture in the FrFD usually produce low quality decrypted images. In this work, we present two approaches to improve the quality of the decrypted images, which are based on nonlinear processing applied to the encrypted function (that contains the joint fractional power spectrum, JFPS) and the nonzero-order JTC in the FrFD. When the two approaches are combined, the quality of the decrypted image is higher. In addition to the advantages introduced by the implementation of the DRPE using a JTC, we demonstrate that the proposed encryption system in the FrFD preserves the shift-invariance property of the JTC-based encryption system in the Fourier domain, with respect to the lateral displacement of both the key random mask in the decryption process and the retrieval of the primary image. The feasibility of this encryption system is verified and analyzed by computer simulations.
A method to perform a fast fourier transform with primitive image transformations.
Sheridan, Phil
2007-05-01
The Fourier transform is one of the most important transformations in image processing. A major component of this influence comes from the ability to implement it efficiently on a digital computer. This paper describes a new methodology to perform a fast Fourier transform (FFT). This methodology emerges from considerations of the natural physical constraints imposed by image capture devices (camera/eye). The novel aspects of the specific FFT method described include: 1) a bit-wise reversal re-grouping operation of the conventional FFT is replaced by the use of lossless image rotation and scaling and 2) the usual arithmetic operations of complex multiplication are replaced with integer addition. The significance of the FFT presented in this paper is introduced by extending a discrete and finite image algebra, named Spiral Honeycomb Image Algebra (SHIA), to a continuous version, named SHIAC.
Application of the Fractional Fourier Transform and S-Method in Doppler Radar Tomography
2010-08-01
Tomography CPI - Coherent Processing Interval CW - Continuous Wave FFT - Fast Fourier Transform FrFT - Fractional Fourier Transform FT - Fourier Transform ISAR ...range profile of a rotating target from radar with a high sampling rate, which may be the case for radars with an ISAR capability. Alternatively, it may...modulated (LFM) audio signals from bats by Capus et al. in [11]. It has also been applied to the SAR and ISAR imaging problems of moving and
2014-09-18
DEVELOPMENT OF IMAGING FOURIER- TRANSFORM SPECTROSCOPY FOR THE CHARACTERIZATION OF TURBULENT JET FLAMES DISSERTATION Jacob L. Harley, Captain, USAF...work of the U.S. Government and is not subject to copyright protection in the United States. AFIT-ENP-DS-14-S-13 DEVELOPMENT OF IMAGING FOURIER- TRANSFORM ...DISTRIBUTION UNLIMITED AFIT-ENP-DS-14-S-13 DEVELOPMENT OF IMAGING FOURIER- TRANSFORM SPECTROSCOPY FOR THE CHARACTERIZATION OF TURBULENT JET FLAMES Jacob L
Fourier transform infrared and Raman spectroscopy studies on magnetite/Ag/antibiotic nanocomposites
NASA Astrophysics Data System (ADS)
Ivashchenko, Olena; Jurga-Stopa, Justyna; Coy, Emerson; Peplinska, Barbara; Pietralik, Zuzanna; Jurga, Stefan
2016-02-01
This article presents a study on the detection of antibiotics in magnetite/Ag/antibiotic nanocomposites using Fourier transform infrared (FTIR) and Raman spectroscopy. Antibiotics with different spectra of antimicrobial activities, including rifampicin, doxycycline, cefotaxime, and ceftriaxone, were studied. Mechanical mixtures of antibiotics and magnetite/Ag nanocomposites, as well as antibiotics and magnetite nanopowder, were investigated in order to identify the origin of FTIR bands. FTIR spectroscopy was found to be an appropriate technique for this task. The spectra of the magnetite/Ag/antibiotic nanocomposites exhibited very weak (for doxycycline, cefotaxime, and ceftriaxone) or even no (for rifampicin) antibiotic bands. This FTIR "invisibility" of antibiotics is ascribed to their adsorbed state. FTIR and Raman measurements show altered Csbnd O, Cdbnd O, and Csbnd S bonds, indicating adsorption of the antibiotic molecules on the magnetite/Ag nanocomposite structure. In addition, a potential mechanism through which antibiotic molecules interact with magnetite/Ag nanoparticle surfaces is proposed.
Non-rigid registration of tomographic images with Fourier transforms
NASA Astrophysics Data System (ADS)
Osorio, Ar; Isoardi, Ra; Mato, G.
2007-11-01
Spatial image registration of deformable body parts such as thorax and abdomen has important medical applications, but at the same time, it represents an important computational challenge. In this work we propose an automatic algorithm to perform non-rigid registration of tomographic images using a non-rigid model based on Fourier transforms. As a measure of similarity, we use the correlation coefficient, finding that the optimal order of the transformation is n = 3 (36 parameters). We apply this method to a digital phantom and to 7 pairs of patient images corresponding to clinical CT scans. The preliminary results indicate a fairly good agreement according to medical experts, with an average registration error of 2 mm for the case of clinical images. For 2D images (dimensions 512×512), the average running time for the algorithm is 15 seconds using a standard personal computer. Summarizing, we find that intra-modality registration of the abdomen can be achieved with acceptable accuracy for slight deformations and can be extended to 3D with a reasonable execution time.
[Biological Process Oriented Online Fourier Transform Infrared Spectrometer].
Xie, Fei; Wu, Qiong-shui; Zeng, Li-bo
2015-08-01
An online Fourier Transform Infrared Spectrometer and an ATR (Attenuated Total Reflection) probe, specifically at the application of real time measurement of the reaction substrate concentration in biological processes, were designed. (1) The spectrometer combined the theories of double cube-corner reflectors and flat mirror, which created a kind of high performance interferometer system. The light path folding way was utilized to makes the interferometer compact structure. Adopting double cube-corner reflectors, greatly reduces the influence of factors in the process of moving mirror movement such as rotation, tilt, etc. The parallelogram oscillation flexible support device was utilized to support the moving mirror moves. It cancelled the friction and vibration during mirror moving, and ensures the smooth operation. The ZnSe splitter significantly improved the hardware reliability in high moisture environment. The method of 60° entrance to light splitter improves the luminous flux. (2) An ATR in situ measuring probe with simple structure, large-flux, economical and practical character was designed in this article. The transmission of incident light and the light output utilized the infrared pipe with large diameter and innerplanted-high plating membrane, which conducted for the infrared transmission media of ATR probe. It greatly reduced the energy loss of infrared light after multiple reflection on the inner wall of the light pipe. Therefore, the ATR probe obtained high flux, improved the signal strength, which make the signal detected easily. Finally, the high sensitivity of MCT (Mercury Cadmium Telluride) detector was utilized to realize infrared interference signal collection, and improved the data quality of detection. The test results showed that the system yields the advantages of perfect moisture-proof performance, luminous flux, online measurement, etc. The designed online Fourier infrared spectrometer can real-time measured common reactant substrates
Adsorption properties and gaseous mercury transformation rate of natural biofilm.
Cheng, Jinping; Zhao, Wenchang; Liu, Yuanyuan; Wu, Cheng; Liu, Caie; Wang, Wenhua
2008-11-01
Biofilms were developed on glass microscope slides in a natural aquatic environment and their mercury adsorption properties were evaluated. Results demonstrated that the biofilms contained a large number of bacterial cells and associated extracellular polymers. Mercury forms detected in the biofilms were mainly bound to residual matter and organic acids. The adsorption processes could be described by a Langmuir isotherm. The optimum conditions for adsorption of mercury to natural biofilm were an ionic strength of 0.1 mol/L, pH 6 and an optimum adsorption time of 40 min. The transformation rate was 0.79 microg gaseous mercury per gram of biofilm.
Gas Analysis by Fourier Transform Mm-Wave Spectroscopy
NASA Astrophysics Data System (ADS)
Harris, Brent J.; Steber, Amanda L.; Lehmann, Kevin K.; Pate, Brooks H.
2013-06-01
Molecular rotational spectroscopy of low pressure, room temperature gases offers high chemical selectivity and sensitivity with the potential for a wide range of applications in gas analysis. A strength of the technique is the potential to identify molecules that have not been previously studied by rotational spectroscopy by comparing experimental results to predictions of the spectroscopic parameters from quantum chemistry -6 so called library-free detection. The development of Fourier transform mm-wave spectrometers using high peak power (30 mW) active multiplier chain mm-wave sources brings new measurement capabilities to the analysis of complex gas mixtures. Strategies for gas analysis based on high-throughput mm-wave spectroscopy and arbitrary waveform generator driven mm-wave sources are described. Several new measurement capabilities come from the intrinsic time-domain measurement technique. High-sensitivity double-resonance measurements can be performed to speed the analysis of a complex gas sample containing several species. This technique uses a "pi-pulse" to selectively invert the population of two selected rotational energy levels and the effect of this excitation pulse on all other transitions in the spectrometer operating range is monitored using segmented chirped-pulse Fourier transform spectroscopy. This method can lead to automated determination of the molecular rotational constants. Rapid pulse duration scan experiments can be used to estimate the magnitude and direction of the dipole moment of the molecule from an unknown spectrum. Coherent pulse echo experiments, using the traditional Hahn sequence or two-color population recovery methods, can be used to determine the collisional relaxation rate of the unknown molecule. This rate determination improves the ability to estimate the mass of the unknown molecule from the determination of the Doppler dephasing rate. By performing a suite of automated, high-throughput measurements, there is the
Fourier transform infrared spectroscopic analysis of cell differentiation
NASA Astrophysics Data System (ADS)
Ishii, Katsunori; Kimura, Akinori; Kushibiki, Toshihiro; Awazu, Kunio
2007-02-01
Stem cells and its differentiations have got a lot of attentions in regenerative medicine. The process of differentiations, the formation of tissues, has become better understood by the study using a lot of cell types progressively. These studies of cells and tissue dynamics at molecular levels are carried out through various approaches like histochemical methods, application of molecular biology and immunology. However, in case of using regenerative sources (cells, tissues and biomaterials etc.) clinically, they are measured and quality-controlled by non-invasive methods from the view point of safety. Recently, the use of Fourier Transform Infrared spectroscopy (FT-IR) has been used to monitor biochemical changes in cells, and has gained considerable importance. The objective of this study is to establish the infrared spectroscopy of cell differentiation as a quality control of cell sources for regenerative medicine. In the present study, as a basic study, we examined the adipose differentiation kinetics of preadipocyte (3T3-L1) and the osteoblast differentiation kinetics of bone marrow mesenchymal stem cells (Kusa-A1) to analyze the infrared absorption spectra. As a result, we achieved to analyze the adipose differentiation kinetics using the infrared absorption peak at 1739 cm-1 derived from ester bonds of triglyceride and osteoblast differentiation kinetics using the infrared absorption peak at 1030 cm-1 derived from phosphate groups of calcium phosphate.
Liquid chromatography/Fourier transform IR spectrometry interface flow cell
Johnson, C.C.; Taylor, L.T.
1985-01-04
A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.
Fourier-Transform Microwave Spectroscopy of HCCNSi and NCNSi
NASA Astrophysics Data System (ADS)
Thorwirth, S.; Kaiser, R. I.; McCarthy, M. C.; Crabtree, K. N.; Martinez, O., Jr.
2013-06-01
By means of Fourier transform microwave spectroscopy of a supersonic jet, the pure rotational spectra of the silicon-bearing chain molecules silaisocyanoacetylene, HCCNSi, and cyanosilaisocyanide, NCNSi, have been studied for the first time. The molecules were observed in low-current dc discharges through appropriate gas mixtures comprising CH_3CN/SiH_4 and cyanogen/SiH_4 heavily diluted in neon. Spectroscopic searches and identification were based on predictions from high-level quantum-chemical calculations at the CCSD(T) level of theory in combination with large basis sets. Excellent agreement between experimental and calculated molecular parameters is found. In addition to the parent isotopic species, rotational lines of rare isotopologs were also observed. Because of the close relationship of these two species to known astronomical molecules and due to their sizable dipole moments of μ=1.4 D (HCCNSi) and μ=5.4 D (NCNSi) both are plausible targets for future astronomical searches using large radio telescopes.
Fourier transform optical profilometry using fiber optic Lloyd's mirrors.
Kart, Türkay; Kösoğlu, Gülşen; Yüksel, Heba; İnci, Mehmet Naci
2014-12-10
A fiber optic Lloyd's mirror assembly is used to obtain various optical interference patterns for the detection of 3D rigid body shapes. Two types of fiber optic Lloyd's systems are used in this work. The first consists of a single-mode optical fiber and a highly reflecting flat mirror to produce bright and dark strips. The second is constructed by locating a single-mode optical fiber in a v-groove, which is formed by two orthogonal flat mirrors to allow the generation of square-type interference patterns for the desired applications. The structured light patterns formed by these two fiber Lloyd's techniques are projected onto 3D objects. Fringe patterns are deformed due to the object's surface topography, which are captured by a digital CCD camera and processed with a Fourier transform technique to accomplish 3D surface topography of the object. It is demonstrated that the fiber-optic Lloyd's technique proposed in this work is more compact, more stable, and easier to configure than other existing surface profilometry systems, since it does not include any high-cost optical tools such as aligners, couplers, or 3D stages. The fringe patterns are observed to be more robust against environmental disturbances such as ambient temperature and vibrations.
Spin Glass Field Theory with Replica Fourier Transforms
NASA Astrophysics Data System (ADS)
Pimentel, Iveta R.; De Dominicis, Cirano
We develop a field theory for spin glasses using Replica Fourier Transforms (RFT). We present the formalism for the case of replica symmetry and the case of replica symmetry breaking on an ultrametric tree, with the number of replicas n and the number of replica symmetry breaking steps R generic integers. We show how the RFT applied to the two-replica fields allows to construct a new basis which block-diagonalizes the four-replica mass-matrix, into the replicon, anomalous and longitudinal modes. The eigenvalues are given in terms of the mass RFT and the propagators in the RFT space are obtained by inversion of the block-diagonal matrix. The formalism allows to express any i-replica vertex in the new RFT basis and hence enables to perform a standard perturbation expansion. We apply the formalism to calculate the contribution of the Gaussian fluctuations around the Parisi's solution for the free-energy of an Ising spin glass.
Spin glass field theory with replica Fourier transforms
NASA Astrophysics Data System (ADS)
Pimentel, I. R.; De Dominicis, C.
2014-11-01
We develop a field theory for spin glasses using replica Fourier transforms (RFT). We present the formalism for the case of replica symmetry and the case of replica symmetry breaking on an ultrametric tree, with the number of replicas n and the number of replica symmetry breaking steps R generic integers. We show how the RFT applied to the two-replica fields allows one to construct a new basis which block-diagonalizes the four-replica mass-matrix, into the replicon, anomalous and longitudinal modes. The eigenvalues are given in terms of the mass RFT and the propagators in the RFT space are obtained by inversion of the block-diagonal matrix. The formalism allows one to express any i-replica vertex in the new RFT basis and hence enables one to perform a standard perturbation expansion. We apply the formalism to calculate the contribution of the Gaussian fluctuations around the Parisi solution for the free-energy of an Ising spin glass.
Continued Development of a Planetary Imaging Fourier Transform Spectrometer (PIFTS)
NASA Technical Reports Server (NTRS)
Sromovsky, L. A.
2002-01-01
This report describes continued efforts to evaluate a breadboard of a Planetary Imaging Fourier Transform Spectrometer (PIFTS). The PIFTS breadboard was developed under prior PIDDP funding. That effort is described in the final report for NASA Grant NAG5-6248 and in two conference papers (Sromovsky et al. 2000; Revercomb et al. 2000). The PIFTS breadboard was designed for near-IR (1-5.2 micrometer imaging of planetary targets with spectral resolving powers of several hundred to several thousand, using an InSb detector array providing at least 64x64 pixels imaging detail. The major focus of the development effort was to combine existing technologies to produce a small and low power design compatible with a very low mass flyable instrument. The objective of this grant (NAG5-10729) was further characterization of the breadboard performance, including intercomparisons with the highly accurate non-imaging Advanced Emitted Radiance Interferometer (AERI) (Revercomb et al. 1994; Best et al. 1997).
Picolinic and isonicotinic acids: a Fourier transform microwave spectroscopy study.
Peña, Isabel; Varela, Marcelino; Franco, Vanina G; López, Juan C; Cabezas, Carlos; Alonso, José L
2014-12-04
The rotational spectra of laser ablated picolinic and isonicotinic acids have been studied using broadband chirped pulse (CP-FTMW) and narrowband molecular beam (MB-FTMW) Fourier transform microwave spectroscopies. Two conformers of picolinic acid, s-cis-I and s-cis-II, and one conformer of isonicotinic acid have been identified through the analysis of their rotational spectra. The values of the inertial defect and the quadrupole coupling constants obtained for the most stable s-cis-I conformer of picolinic acid, evidence the formation of an O-H···N hydrogen bond between the acid group and the endocyclic N atom. The stabilization provided by this hydrogen bond compensates the destabilization energy due to the adoption of a -COOH trans configuration in this conformer. Its rs structure has been derived from the rotational spectra of several (13)C, (15)N, and (18)O species observed in their natural abundances. Mesomeric effects have been revealed by comparing the experimental values of the (14)N nuclear quadrupole coupling constants in the isomeric series of picolinic, isonicotinic, and nicotinic acids.
Fourier Transform Infrared Spectroscopy and Photoacoustic Spectroscopy for Saliva Analysis.
Mikkonen, Jopi J W; Raittila, Jussi; Rieppo, Lassi; Lappalainen, Reijo; Kullaa, Arja M; Myllymaa, Sami
2016-09-01
Saliva provides a valuable tool for assessing oral and systemic diseases, but concentrations of salivary components are very small, calling the need for precise analysis methods. In this work, Fourier transform infrared (FT-IR) spectroscopy using transmission and photoacoustic (PA) modes were compared for quantitative analysis of saliva. The performance of these techniques was compared with a calibration series. The linearity of spectrum output was verified by using albumin-thiocyanate (SCN(-)) solution at different SCN(-) concentrations. Saliva samples used as a comparison were obtained from healthy subjects. Saliva droplets of 15 µL were applied on the silicon sample substrate, 6 drops for each specimen, and dried at 37 ℃ overnight. The measurements were carried out using an FT-IR spectrometer in conjunction with an accessory unit for PA measurements. The findings with both transmission and PA modes mirror each other. The major bands presented were 1500-1750 cm(-1) for proteins and 1050-1200 cm(-1) for carbohydrates. In addition, the distinct spectral band at 2050 cm(-1) derives from SCN(-) anions, which is converted by salivary peroxidases to hypothiocyanate (OSCN(-)). The correlation between the spectroscopic data with SCN(-) concentration (r > 0.990 for transmission and r = 0.967 for PA mode) was found to be significant (P < 0.01), thus promising to be utilized in future applications.
Fourier Transform Microwave and Infrared Spectroscopic Investigation of Propiolactone
NASA Astrophysics Data System (ADS)
Chen, Ziqiu; van Wijngaarden, Jennifer
2009-06-01
The pure rotational spectrum of the four-membered ester ring propiolactone (C{_3}H{_4}O{_2}) has been measured in a supersonic jet between 7 and 22 GHz using Fourier transform microwave (FTMW) spectroscopy. For the normal isotopologue, a total of 19 a- and b-type transitions have been recorded. Fifteen transitions due to three different ^{13}C isotopologues have also been observed. The microwave spectrum was analyzed to obtain an improved set of ground state rotational constants in comparison to earlier microwave experiments. The new set of rotational parameters was used to predict the rovibrational band structure of the lowest frequency modes of propiolactone. A total of 12 vibrational band origins have been observed between 400 and 1500 cm^{-1} using the far infrared beamline of the Canadian Light Source coupled to a Bruker IFS125HR spectrometer. The spectra were recorded with a resolution of 0.000969 cm^{-1} and although the intensities of the bands vary, 9 bands are of sufficient quality for complete rovibrational assignment. The progress of the assignment of this rich spectrum will be discussed. D. W. Boone, C O. Britt and J. E. Boggs J. Chem. Phys. 43 (1190), 1965.
Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS): Imaging and Tracking Capability
NASA Technical Reports Server (NTRS)
Zhou, D. K.; Larar, A. M.; Liu, Xu; Reisse, R. A.; Smith, W. L.; Revercomb, H. E.; Bingham, G. E.; Zollinger, L. J.; Tansock, J. J.; Huppi, Ronald J.
2007-01-01
The geosynchronous-imaging Fourier transform spectrometer (GIFTS) engineering demonstration unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. It measures the infrared spectrum in two spectral bands (14.6 to 8.8 microns, 6.0 to 4.4 microns) using two 128 128 detector arrays with a spectral resolution of 0.57/cm with a scan duration of approx. 11 seconds. From a geosynchronous orbit, the instrument will have the capability of taking successive measurements of such data to scan desired regions of the globe, from which atmospheric status, cloud parameters, wind field profiles, and other derived products can be retrieved. The GIFTS EDU provides a flexible and accurate testbed for the new challenges of the emerging hyperspectral era. The EDU ground-based measurement experiment, held in Logan, Utah during September 2006, demonstrated its extensive capabilities and potential for geosynchronous and other applications (e.g., Earth observing environmental measurements). This paper addresses the experiment objectives and overall performance of the sensor system with a focus on the GIFTS EDU imaging capability and proof of the GIFTS measurement concept.
Fourier transform infrared and physicochemical analyses of roasted coffee.
Wang, Niya; Lim, Loong-Tak
2012-05-30
In this study, Brazilian coffee beans processed to different stages of roast at 210, 220, 230, and 240 °C were analyzed for pH value, titratable acidity, moisture content, and color lightness. Fourier transform infrared (FTIR) spectroscopy, in conjunction with principal component analysis, was conducted to study the effects of process time and temperature on the IR-active components of the acetyl acetate extract of the roasted coffee. The results showed that high-temperature-short-time resulted in higher moisture content, higher pH value, and higher titratable acidity when the beans were roasted beyond the start-of-second-crack stage, as compare to low-temperature-long-time process (LTLT). The LTLT process also resulted in greater IR absorbance for aldehydes, ketones, aliphatic acids, aromatic acids, and caffeine carbonyl bands on the FTIR spectra. Clusters for principal component score plots were well separated, indicating that the changes IR-active components in the coffee extracts, due to the different roasting treatments, can be discriminated by the FTIR technique. On the basis of the loading plots of principal components, changes of IR-active compounds in the coffee extract at various stages of roasting were discussed.
High-resolution wide-band fast Fourier transform spectrometers
NASA Astrophysics Data System (ADS)
Klein, B.; Hochgürtel, S.; Krämer, I.; Bell, A.; Meyer, K.; Güsten, R.
2012-06-01
We describe the performance of our latest generations of sensitive wide-band high-resolution digital fast Fourier transform spectrometer (FFTS). Their design, optimized for a wide range of radio astronomical applications, is presented. Developed for operation with the GREAT far infrared heterodyne spectrometer on-board SOFIA, the eXtended bandwidth FFTS (XFFTS) offers a high instantaneous bandwidth of 2.5 GHz with 88.5 kHz spectral resolution and has been in routine operation during SOFIA's Basic Science since July 2011. We discuss the advanced field programmable gate array (FPGA) signal processing pipeline, with an optimized multi-tap polyphase filter bank algorithm that provides a nearly loss-less time-to-frequency data conversion with significantly reduced frequency scallop and fast sidelobe fall-off. Our digital spectrometers have been proven to be extremely reliable and robust, even under the harsh environmental conditions of an airborne observatory, with Allan-variance stability times of several 1000 s. An enhancement of the present 2.5 GHz XFFTS will duplicate the number of spectral channels (64k), offering spectroscopy with even better resolution during Cycle 1 observations.
Two-dimensional chirped-pulse Fourier transform microwave spectroscopy.
Wilcox, David S; Hotopp, Kelly M; Dian, Brian C
2011-08-18
Two-dimensional (2D) correlation techniques are developed for chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy. The broadband nature of the spectrometer coupled with fast digital electronics permits the generation of arbitrary pulse sequences and simultaneous detection of the 8-18 GHz region of the microwave spectrum. This significantly increases the number of rotation transitions that can be simultaneously probed, as well as the bandwidth in both frequency dimensions. We theoretically and experimentally evaluate coherence transfer of three- and four-level systems to relate the method with previous studies. We then extend the principles of single-quantum and autocorrelation to incorporate broadband excitation and detection. Global connectivity of the rotational energy level structure is demonstrated through the transfer of multiple coherences in a single 2D experiment. Additionally, open-system effects are observed from irradiating many-level systems. Quadrature detection in the indirectly measured frequency dimension and phase cycling are also adapted for 2D CP-FTMW spectroscopy.
Large Molecule Structures by Broadband Fourier Transform Molecular Rotational Spectroscopy
NASA Astrophysics Data System (ADS)
Evangelisti, Luca; Seifert, Nathan A.; Spada, Lorenzo; Pate, Brooks
2016-06-01
Fourier transform molecular rotational resonance spectroscopy (FT-MRR) using pulsed jet molecular beam sources is a high-resolution spectroscopy technique that can be used for chiral analysis of molecules with multiple chiral centers. The sensitivity of the molecular rotational spectrum pattern to small changes in the three dimensional structure makes it possible to identify diastereomers without prior chemical separation. For larger molecules, there is the additional challenge that different conformations of each diastereomer may be present and these need to be differentiated from the diastereomers in the spectral analysis. Broadband rotational spectra of several larger molecules have been measured using a chirped-pulse FT-MRR spectrometer. Measurements of nootkatone (C15H22O), cedrol (C15H26O), ambroxide (C16H28O) and sclareolide (C16H26O2) are presented. These spectra are measured with high sensitivity (signal-to-noise ratio near 1,000:1) and permit structure determination of the most populated isomers using isotopic analysis of the 13C and 18O isotopologues in natural abundance. The accuracy of quantum chemistry calculations to identify diastereomers and conformers and to predict the dipole moment properties needed for three wave mixing measurements is examined.
Liquid chromatography/Fourier transform IR spectrometry interface flow cell
Johnson, Charles C.; Taylor, Larry T.
1986-01-01
A zero dead volume (ZDV) microbore high performance liquid chromatography (.mu.HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a .mu.HPLC column end fitting to minimize the transfer volume of the effluents exiting the .mu.HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF.sub.2), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.
Two-dimensional Fourier transform ESR correlation spectroscopy
NASA Astrophysics Data System (ADS)
Gorcester, Jeff; Freed, Jack H.
1988-04-01
We describe our pulsed two-dimensional Fourier transform ESR experiment and demonstrate its applicabilty for the double resonance of motionally narrowed nitroxides. Multiple pulse irradiation of the entire nitroxide spectrum enables the correlation of two precessional periods, allowing observation of cross correlations between hyperfine lines introduced by magnetization transfer in the case of a three-pulse experiment (2D ELDOR), or coherence transfer in the case of a two-pulse experiment (COSY). Cross correlations are revealed by the presence of cross peaks which connect the autocorrelation lines appearing along the diagonal ω1=ω2. The amplitudes of these cross peaks are determined by the rates of magnetization transfer in the 2D ELDOR experiment. The density operator theory for the experiment is outlined and applied to the determination of Heisenberg exchange (HE) rates in 2,2,6,6-tetramethyl-4-piperidone-N-oxyl-d15 (PD-tempone) dissolved in toluene-d8. The quantitative accuracy of this experiment is established by comparison with the HE rate measured from the dependence of the spin echo T2 on nitroxide concentration.
Applications of the VUV Fourier Transform Spectrometer at Synchrotron Soleil
NASA Astrophysics Data System (ADS)
de Oliveira, Nelson; Joyeux, Denis; Ito, Kenji; Gans, Berenger; Nahon, Laurent
2015-06-01
Fourier transform spectrometers (FTS) are usually based upon amplitude division interferometers through beamsplitters (BS) as in the Michelson interferometer geometry. However, the manufacture of broadband BS is difficult and even impossible in the far VUV (below λ = 140 nm). We therefore conceived an instrument based upon an original design involving only reflective plane surfaces, giving access to the whole VUV range without the restrictions associated with BS. The VUV- FTS is a permanent endstation connected to one of the three experimental branches of the DESIRS beamline and devoted to high resolution photoabsorption in the UV-VUV spectral range, typically between λ = 300 and 40 nm Since 2008, a large international community of users interested in laboratory measurements with applications in astrophysics, molecular physics or planetary atmospheres has been attracted by the VUV - FTS capabilities including its efficiency in terms of signal to noise ratio, even when high spectral resolution was not an issue. A large number of dedicated gas phase sample environments have been developed including a windowless cell that can be cooled down, a heated windowless cell, a free molecular jet set-up and various windowed cells. Besides, a new discharge gas cell for production and study of transient species gave recently its first results. As an illustration, the VUV absorption spectrum of the CH_3 radical down to 140 nm will be shown in this presentation. Nahon et al., J. Synchrotron Radiat., 19, 508(2012) De Oliveira et al., Nat. Photonics, 5, 149(2011)
External Second Gate-Fourier Transform Ion Mobility Spectrometry.
Tarver, Edward E., III
2005-01-01
Ion mobility spectrometry (IMS) is recognized as one of the most sensitive and versatile techniques for the detection of trace levels of organic vapors. IMS is widely used for detecting contraband narcotics, explosives, toxic industrial compounds and chemical warfare agents. Increasing threat of terrorist attacks, the proliferation of narcotics, Chemical Weapons Convention treaty verification as well as humanitarian de-mining efforts has mandated that equal importance be placed on the analysis time as well as the quality of the analytical data. (1) IMS is unrivaled when both speed of response and sensitivity has to be considered. (2) With conventional (signal averaging) IMS systems the number of available ions contributing to the measured signal to less than 1%. Furthermore, the signal averaging process incorporates scan-to-scan variations decreasing resolution. With external second gate Fourier Transform ion mobility spectrometry (FT-IMS), the entrance gate frequency is variable and can be altered in conjunction with other data acquisition parameters to increase the spectral resolution. The FT-IMS entrance gate operates with a 50% duty cycle and so affords a 7 to 10-fold increase in sensitivity. Recent data on high explosives are presented to demonstrate the parametric optimization in sensitivity and resolution of our system.
Cryogenic Fourier transform infrared spectrometer from 4 to 20 micrometers
NASA Astrophysics Data System (ADS)
Kaplan, Simon G.; Woods, Solomon I.; Jung, Timothy M.; Carter, Adriaan C.
2010-07-01
We describe the design and performance of a cryogenic Fourier transform spectrometer (Cryo-FTS) operating at a temperature of approximately 15 K. The instrument is based on a porch-swing scanning mirror design with active alignment stabilization using a fiber-optic coupled diode laser and voice-coil actuator mechanism. It has a KBr beamsplitter and has been integrated into an infrared radiometer containing a calibrated Si:As blocked impurity band (BIB) detector. Due to its low operating temperature, the spectrometer exhibits very small thermal background signal and low drift. Data from tests of basic spectrometer function, such as modulation efficiency, scan jitter, spectral range, and spectral resolution are presented. We also present results from measurements of faint point-like sources in a low background environment, including background, signal offset and gain, and spectral noise equivalent power, and discuss the possible use of the instrument for spectral characterization of ground-based infrared astronomy calibration sources. The Cryo-FTS is presently limited to wavelengths below 25 micrometers but can be in principle extended to longer wavelengths with changes in beamsplitter and detector.
Fourier transform spectrometer for Greenhouse Gases Observing Satellite (GOSAT)
NASA Astrophysics Data System (ADS)
Hamazaki, Takashi; Kaneko, Yutaka; Kuze, Akihiko; Kondo, Kayoko
2005-01-01
Global warming has become a very serious issue for human beings. In 1997, the Kyoto Protocol was adopted at the Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change (COP3), making it mandatory for developed nations to reduce carbon dioxide emissions by six (6) to eight (8) per cent of their total emissions in 1990, and to meet this goal sometime between 2008 and 2012. The Greenhouse gases Observing SATellite (GOSAT) is designed to monitor the global distribution of carbon dioxide (CO2) from the space. GOSAT is a joint project of Japan Aerospace Exploration Agency (JAXA), the Ministry of Environment (MOE), and the National Institute for Environmental Studies (NIES). JAXA is responsible for the satellite and instrument development, MOE is involved in the instrument development, and NIES is responsible for the satellite data retrieval. The satellite is scheduled to be launched in 2008. In order to detect the CO2 variation of boundary layers, both the technique to measure the column density and the retrieval algorithm to remove cloud and aerosol contamination are investigated. Main mission sensor of the GOSAT is a Fourier Transform Spectrometer with high optical throughput, spectral resolution and wide spectral coverage, and a cloud-aerosol detecting imager attached to the satellite. The paper presents the mission sensor system of the GOSAT together with the results of performance demonstration with proto-type instrument aboard an aircraft.
NASA Astrophysics Data System (ADS)
Xia, Xiang-Gen; Wang, Genyuan; Chen, Victor C.
2001-03-01
This paper first reviews some basic properties of the discrete chirp-Fourier transform and then present an adaptive chirp- Fourier transform, a generalization of the amplitude and phase estimation of sinusoids (APES) algorithm proposed by Li and Stoica for sinusoidal signals. We finally applied it to the ISAR imaging of maneuvering targets.
Optimal Padding for the Two-Dimensional Fast Fourier Transform
NASA Technical Reports Server (NTRS)
Dean, Bruce H.; Aronstein, David L.; Smith, Jeffrey S.
2011-01-01
One-dimensional Fast Fourier Transform (FFT) operations work fastest on grids whose size is divisible by a power of two. Because of this, padding grids (that are not already sized to a power of two) so that their size is the next highest power of two can speed up operations. While this works well for one-dimensional grids, it does not work well for two-dimensional grids. For a two-dimensional grid, there are certain pad sizes that work better than others. Therefore, the need exists to generalize a strategy for determining optimal pad sizes. There are three steps in the FFT algorithm. The first is to perform a one-dimensional transform on each row in the grid. The second step is to transpose the resulting matrix. The third step is to perform a one-dimensional transform on each row in the resulting grid. Steps one and three both benefit from padding the row to the next highest power of two, but the second step needs a novel approach. An algorithm was developed that struck a balance between optimizing the grid pad size with prime factors that are small (which are optimal for one-dimensional operations), and with prime factors that are large (which are optimal for two-dimensional operations). This algorithm optimizes based on average run times, and is not fine-tuned for any specific application. It increases the amount of times that processor-requested data is found in the set-associative processor cache. Cache retrievals are 4-10 times faster than conventional memory retrievals. The tested implementation of the algorithm resulted in faster execution times on all platforms tested, but with varying sized grids. This is because various computer architectures process commands differently. The test grid was 512 512. Using a 540 540 grid on a Pentium V processor, the code ran 30 percent faster. On a PowerPC, a 256x256 grid worked best. A Core2Duo computer preferred either a 1040x1040 (15 percent faster) or a 1008x1008 (30 percent faster) grid. There are many industries that
NASA Astrophysics Data System (ADS)
Kubicki, J. D.; Schroeter, L. M.; Itoh, M. J.; Nguyen, B. N.; Apitz, S. E.
1999-09-01
A suite of naturally-occurring carboxylic acids (acetic, oxalic, citric, benzoic, salicylic and phthalic) and their corresponding sodium salts were adsorbed onto a set of common mineral substrates (quartz, albite, illite, kaolinite and montmorillonite) in batch slurry experiments. Solution pH's of approximately 3 and 6 were used to examine the effects of pH on sorption mechanisms. Attenuated total reflectance Fourier-transform infrared (ATR FTIR) spectroscopy was employed to obtain vibrational frequencies of the organic ligands on the mineral surfaces and in solution. UV/visible spectroscopy on supernatant solutions was also employed to confirm that adsorption from solution had taken place for benzoic, salicylic and phthalic acids. Molecular orbital calculations were used to model possible surface complexes and interpret the experimental spectra. In general, the tectosilicates, quartz and albite feldspar, did not chemisorb (i.e., strong, inner-sphere adsorption) the carboxylate anions in sufficient amounts to produce infrared spectra of the organics after rinsing in distilled water. The clays (illite, kaolinite and montmorillonite) each exhibited similar ATR FTIR spectra. However, the illite sample used in this study reacted to form strong surface and aqueous complexes with salicylic acid before being treated to remove free Fe-hydroxides. Chemisorption of carboxylic acids onto clays is shown to be limited without the presence of Fe-hydroxides within the clay matrix.
Ogawa, Takahiro; Haseyama, Miki
2013-03-01
A missing texture reconstruction method based on an error reduction (ER) algorithm, including a novel estimation scheme of Fourier transform magnitudes is presented in this brief. In our method, Fourier transform magnitude is estimated for a target patch including missing areas, and the missing intensities are estimated by retrieving its phase based on the ER algorithm. Specifically, by monitoring errors converged in the ER algorithm, known patches whose Fourier transform magnitudes are similar to that of the target patch are selected from the target image. In the second approach, the Fourier transform magnitude of the target patch is estimated from those of the selected known patches and their corresponding errors. Consequently, by using the ER algorithm, we can estimate both the Fourier transform magnitudes and phases to reconstruct the missing areas.
Precise and fast spatial-frequency analysis using the iterative local Fourier transform.
Lee, Sukmock; Choi, Heejoo; Kim, Dae Wook
2016-09-19
The use of the discrete Fourier transform has decreased since the introduction of the fast Fourier transform (fFT), which is a numerically efficient computing process. This paper presents the iterative local Fourier transform (ilFT), a set of new processing algorithms that iteratively apply the discrete Fourier transform within a local and optimal frequency domain. The new technique achieves 2^{10} times higher frequency resolution than the fFT within a comparable computation time. The method's superb computing efficiency, high resolution, spectrum zoom-in capability, and overall performance are evaluated and compared to other advanced high-resolution Fourier transform techniques, such as the fFT combined with several fitting methods. The effectiveness of the ilFT is demonstrated through the data analysis of a set of Talbot self-images (1280 × 1024 pixels) obtained with an experimental setup using grating in a diverging beam produced by a coherent point source.
Libyan Desert Glass: New field and Fourier transform infrared data
NASA Astrophysics Data System (ADS)
Fröhlich, F.; Poupeau, G.; Badou, A.; Le Bourdonnec, F. X.; Sacquin, Y.; Dubernet, S.; Bardintzeff, J. M.; Véran, M.; Smith, D. C.; Diemer, E.
2013-12-01
Results are presented of new geological observations and laboratory analyses on Libyan Desert Glass (LDG), a unique kind of impact glass found in Egypt, probably 28.5-29.4 million years in age. A new LDG occurrence has been discovered some 50 km southward of the main LDG occurrences in the Great Sand Sea. From Fourier transform infrared (FTIR) analysis, the molecular structure of LDG is refined and significant differences are shown between LDG specimens and other pure silica glasses (fulgurite, industrial fused quartz, and amorphous biogenic silica) that are related to differences in their structures. The slight variations observed here for the mean Si-O-Si angle between the different glasses are attributed to their thermal histories. With regard to the other glasses analyzed, the LDG infrared spectral parameters point to a higher ratio of discontinuities and defects in the tetrahedral (SiO4) network. The quantitative mineralogical constitutions of sandstones and quartzites from the LDG geological setting were analyzed by FTIR. Cretaceous sandstones have a specific composition (about 90 wt% quartz, 10% dickite), clearly different from the Paleozoic ones (about 90 wt% quartz, but ≥7% kaolinite). It is shown that the reddish silts bearing the LDG are constituted mainly of microquartz enriched with dickite, whose particle size distribution is characteristic of fluvio-lacustrine deposits, probably Oligocene to Miocene in age. The target rocks, most probably quartz sand, resulted from the weathering (loss of the cementing microquartz) of the Cretaceous sandstones from the Gilf Khebir Plateau with deposition in a high-energy environment.
Fourier Transform Spectrometer measurements of Atmospheric Carbon Dioxide and Methane
NASA Astrophysics Data System (ADS)
Kivi, Rigel; Heikkinen, Pauli; Chen, Huilin; Hatakka, Juha; Laurila, Tuomas
2016-04-01
Ground based remote sensing measurements of column CO2 and CH4 using Fourier Transform Spectrometers (FTS) within the Total Carbon Column Observing Network (TCCON) are known for high precision and accuracy. These measurements are performed at various locations globally and they have been widely used in carbon cycle studies and validation of space born measurements. The relevant satellite missions include the Orbiting Carbon Observatory-2 (OCO-2) by the National Aeronautics and Space Administration (NASA); the SCanning Imaging Absorption SpectroMeter for Atmospheric CHartographY (SCIAMACHY) by the European Space Agency (ESA); the Greenhouse gases Observing SATellite (GOSAT) by the Japan Aerospace Exploration Agency (JAXA) and the upcoming Sentinel-5 Precursor mission, which is an ESA mission and scheduled for launch in 2016. Results of the column CO2 and CH4 measurements at Sodankylä in northern Finland (at 67.4° N, 26.6° E) are reported in this study. The measurements have been performed on regular basis since the beginning of the program in early 2009. We also present evaluation of the data quality of the ground based measurements and comparisons with the available satellite based retrievals. In case of comparisons between the GOSAT and ground based retrievals of CO2 and CH4 no significant biases were found. Sodankylä is one of the northernmost stations in the TCCON network. However, the data coverage has been relatively good thanks to the progress towards automation of the FTS measurement system. At Sodankylä the retrievals have been also compared with the balloon borne AirCore measurements at the site. AirCore sampling system is directly related to the World Meteorological Organization in situ trace gas measurement scales. The balloon platform allows sampling in both stratosphere and troposphere, which is a benefit, compared to the aircraft in situ measurements.
Fourier transform infrared spectroscopy for molecular analysis of microbial cells.
Ojeda, Jesús J; Dittrich, Maria
2012-01-01
A rapid and inexpensive method to characterise chemical cell properties and identify the functional groups present in the cell wall is Fourier transform infrared spectroscopy (FTIR). Infrared spectroscopy is a well-established technique to identify functional groups in organic molecules based on their vibration modes at different infrared wave numbers. The presence or absence of functional groups, their protonation states, or any changes due to new interactions can be monitored by analysing the position and intensity of the different infrared absorption bands. Additionally, infrared spectroscopy is non-destructive and can be used to monitor the chemistry of living cells. Despite the complexity of the spectra, the elucidation of functional groups on Gram-negative and Gram-positive bacteria has been already well documented in the literature. Recent advances in detector sensitivity have allowed the use of micro-FTIR spectroscopy as an important analytical tool to analyse biofilm samples without the need of previous treatment. Using FTIR spectroscopy, the infrared bands corresponding to proteins, lipids, polysaccharides, polyphosphate groups, and other carbohydrate functional groups on the bacterial cells can now be identified and compared along different conditions. Despite some differences in FTIR spectra among bacterial strains, experimental conditions, or changes in microbiological parameters, the IR absorption bands between approximately 4,000 and 400 cm(-1) are mainly due to fundamental vibrational modes and can often be assigned to the same particular functional groups. In this chapter, an overview covering the different sample preparation protocols for infrared analysis of bacterial cells is given, alongside the basic principles of the technique, the procedures for calculating vibrational frequencies based on simple harmonic motion, and the advantages and disadvantages of FTIR spectroscopy for the analysis of microorganisms.
Modeling and Simulation of a Signal Processor Implementing the Winograd Fourier Transform.
1985-12-01
description of how the device / transforms inputs to outputs (a body in the syntax). Related type declarations, func- tions, and procedures can be grouped...SIGNAL PROCESSOR IMPLEMENTING THE WINOGRAD FOURIER TRANSFORM THESIS Presented to the Faculty of the School of Engineering *of the Air Force Institute...2.3.1 Good-Thomas Prime Factor Algorithm ............................................. 12 2.3.2 Winograd Fast Fourier Transform
Far-field radiation patterns of aperture antennas by the Winograd Fourier transform algorithm
NASA Technical Reports Server (NTRS)
Heisler, R.
1978-01-01
A more time-efficient algorithm for computing the discrete Fourier transform, the Winograd Fourier transform (WFT), is described. The WFT algorithm is compared with other transform algorithms. Results indicate that the WFT algorithm in antenna analysis appears to be a very successful application. Significant savings in cpu time will improve the computer turn around time and circumvent the need to resort to weekend runs.
NASA Astrophysics Data System (ADS)
Wang, Tong-Tong; Fan, Hong-Yi
2012-03-01
Using the Weyl quantization scheme and based on the Fourier slice transformation (FST) of the Wigner operator, we construct a new expansion formula of the density operator ρ, with the expansion coefficient being the FST of ρ's classical Weyl correspondence, and the latter the Fourier transformation of ρ's quantum tomogram. The coordinate-momentum intermediate representation is used as the Radon transformation of the Wigner operator.
Pisani, Marco; Zucco, Massimo
2009-05-11
An imaging spectrometer based on a Fabry-Perot interferometer is presented. The Fabry-Perot interferometer scans the mirror distance up to contact and the intensity modulated light signal is transformed using a Fourier Transform based algorithm, as the Michelson based Fourier Transform Spectrometers does. The resulting instrument has the advantage of a compact, high numerical aperture, high luminosity hyperspectral imaging device. Theory of operation is described along with one experimental realization and preliminary results.
Adsorption and transformation of tetracycline antibiotics with aluminum oxide.
Chen, Wan-Ru; Huang, Ching-Hua
2010-05-01
Tetracycline antibiotics (TCs) including tetracycline (TTC), chlorotetracycline (CTC) and oxytetracycline (OTC) adsorb strongly to aluminum oxide (Al(2)O(3)), and the surface interaction promotes structural transformation of TCs. The latter phenomenon was not widely recognized previously. Typically, rapid adsorption of TCs to Al(2)O(3) occurs in the first 3h ([TC]=40microM, [Al(2)O(3)]=1.78gL(-1), pH=5, and T=22 degrees C), followed by continuous first-order decay of the parent compound (k(obs)=15+/-1.0, 18+/-1.0 and 6.2+/-0.9x10(-3)h(-1) for TTC, CTC and OTC, respectively) and product formation. The transformation reaction rate of TCs strongly correlates with adsorption to Al(2)O(3) surfaces. Both adsorption and transformation occur at the highest rate at around neutral pH conditions. Product evaluation indicates that Al(2)O(3) promotes dehydration of TTC to yield anhydrotetracycline (AHTTC), epimerization of TTC, and formation of Al-TTC complexes. Al(2)O(3) promotes predominantly the transformation of CTC to iso-CTC. The surface-bound Al(+III) acts as a Lewis acid site to promote the above transformation of TCs. Formation of AHTTC is of special concern because of its higher cytotoxicity. Results of this study indicate that aluminum oxide will likely affect the fate of TC antibiotics in the aquatic environment via both adsorption and transformation.
A Synthetic Quadrature Phase Detector/Demodulator for Fourier Transform Transform Spectrometers
NASA Technical Reports Server (NTRS)
Campbell, Joel
2008-01-01
A method is developed to demodulate (velocity correct) Fourier transform spectrometer (FTS) data that is taken with an analog to digital converter that digitizes equally spaced in time. This method makes it possible to use simple low cost, high resolution audio digitizers to record high quality data without the need for an event timer or quadrature laser hardware, and makes it possible to use a metrology laser of any wavelength. The reduced parts count and simplicity implementation makes it an attractive alternative in space based applications when compared to previous methods such as the Brault algorithm.
NASA Technical Reports Server (NTRS)
Ma, Q.; Tipping, R. H.; Lavrentieva, N. N.
2012-01-01
By adopting a concept from signal processing, instead of starting from the correlation functions which are even, one considers the causal correlation functions whose Fourier transforms become complex. Their real and imaginary parts multiplied by 2 are the Fourier transforms of the original correlations and the subsequent Hilbert transforms, respectively. Thus, by taking this step one can complete the two previously needed transforms. However, to obviate performing the Cauchy principal integrations required in the Hilbert transforms is the greatest advantage. Meanwhile, because the causal correlations are well-bounded within the time domain and band limited in the frequency domain, one can replace their Fourier transforms by the discrete Fourier transforms and the latter can be carried out with the FFT algorithm. This replacement is justified by sampling theory because the Fourier transforms can be derived from the discrete Fourier transforms with the Nyquis rate without any distortions. We apply this method in calculating pressure induced shifts of H2O lines and obtain more reliable values. By comparing the calculated shifts with those in HITRAN 2008 and by screening both of them with the pair identity and the smooth variation rules, one can conclude many of shift values in HITRAN are not correct.
Broadband Mid-Infrared Comb-Resolved Fourier Transform Spectroscopy
NASA Astrophysics Data System (ADS)
Lee, Kevin; Mills, Andrew; Mohr, Christian; Jiang, Jie; Fermann, Martin; Maslowski, Piotr
2014-06-01
We report on a comb-resolved, broadband, direct-comb spectroscopy system in the mid-IR and its application to the detection of trace gases and molecular line shape analysis. By coupling an optical parametric oscillator (OPO), a 100 m multipass cell, and a high-resolution Fourier transform spectrometer (FTS), sensitive, comb-resolved broadband spectroscopy of dilute gases is possible. The OPO has radiation output at 3.1-3.7 and 4.5-5.5 μm. The laser repetition rate is scanned to arbitrary values with 1 Hz accuracy around 417 MHz. The comb-resolved spectrum is produced with an absolute frequency axis depending only on the RF reference (in this case a GPS disciplined oscillator), stable to 1 part in 10^9. The minimum detectable absorption is 1.6x10-6 wn Hz-1/2. The operating range of the experimental setup enables access to strong fundamental transitions of numerous molecular species for applications based on trace gas detection such as environmental monitoring, industrial gas calibration or medical application of human breath analysis. In addition to these capabilities, we show the application for careful line shape analysis of argon-broadened CO band spectra around 4.7 μm. Fits of the obtained spectra clearly illustrate the discrepancy between the measured spectra and the Voigt profile (VP), indicating the need to include effects such as Dicke narrowing and the speed-dependence of the collisional width and shift in the line shape model, as was shown in previous cw-laser studies. In contrast to cw-laser based experiments, in this case the entire spectrum (˜ 250 wn) covering the whole P and R branches can be measured in 16 s with 417 MHz resolution, decreasing the acquisition time by orders of magnitude. The parallel acquisition allows collection of multiple lines simultaneously, removing the correlation of possible temperature and pressure drifts. While cw-systems are capable of measuring spectra with higher precision, this demonstration opens the door for fast
Midwave infrared imaging Fourier transform spectrometry of combustion plumes
NASA Astrophysics Data System (ADS)
Bradley, Kenneth C.
A midwave infrared (MWIR) imaging Fourier transform spectrometer (IFTS) was used to successfully capture and analyze hyperspectral imagery of combustion plumes. Jet engine exhaust data from a small turbojet engine burning diesel fuel at a low rate of 300 cm3/min was collected at 1 cm -1 resolution from a side-plume vantage point on a 200x64 pixel window at a range of 11.2 meters. Spectral features of H2O, CO, and CO2 were present, and showed spatial variability within the plume structure. An array of thermocouple probes was positioned within the plume to aid in temperature analysis. A single-temperature plume model was implemented to obtain spatially-varying temperatures and plume concentrations. Model-fitted temperatures of 811 +/- 1.5 K and 543 +/- 1.6 K were obtained from plume regions in close proximity to thermocouple probes measuring temperatures of 719 K and 522 K, respectively. Industrial smokestack plume data from a coal-burning stack collected at 0.25 cm-1 resolution at a range of 600 meters featured strong emission from NO, CO, CO2, SO 2, and HCl in the spectral region 1800-3000 cm-1. A simplified radiative transfer model was employed to derive temperature and concentrations for clustered regions of the 128x64 pixel scene, with corresponding statistical error bounds. The hottest region (closest to stack centerline) was 401 +/- 0.36 K, compared to an in-stack measurement of 406 K, and model-derived concentration values of NO, CO2, and SO2 were 140 +/- 1 ppmV, 110,400 +/- 950 ppmV, and 382 +/- 4 ppmV compared to in-stack measurements of 120 ppmV (NOx), 94,000 ppmV, and 382 ppmV, respectively. In-stack measurements of CO and HCl were not provided by the stack operator, but model-derived values of 19 +/- 0.2 ppmV and 111 +/- 1 ppmV are reported near stack centerline. A deployment to Dugway Proving Grounds, UT to collect hyperspectral imagery of chemical and biological threat agent simulants resulted in weak spectral signatures from several species. Plume
Yang, Jiao-lan; Luo, Tian
2002-08-01
This paper expatriated the applications for Fourier transform infrared spectrum analysis technique in preventive medicine field from four aspects of environmental pollution, life science, and the latest infrared analysis methods and near infrared analysis technique. In the environmental pollution field, it mainly described the advantages, the limitations and the solutions of the combined applications for gas chromatograph and Fourier transform infrared spectrum. In the life science field, it described the application for Fourier transform infrared spectrum analysis technique on protein secondary structure, membrane protein, phospholipid, nucleic acid, cell, tissue. In addition, it also introduced a few latest infrared analysis methods and the applications for near infrared spectrum analysis technique in food, cosmetic, drug.
The Sharper Image: Implementing a Fast Fourier Transform (FFT) to Enhance a Video-Captured Image.
1994-01-01
mathematical system to quantitatively analyze and compare complex wave forms. In 1307, Baron Jean - Baptiste - Joseph Fourier proved that any periodic wave can be...HOVEY ROAD, PENSACOLA, FL 32508-1046 NAMRL Special Report 94-1 THE SHARPER IMAGE: 16 IMPLEMENTING A FAST FOURIER TRANSFORM (FFT) TO ENHANCE A VIDEO...most visually impaired persons fail to discern the higher spatial frequencies present in an image. Based on the Fourier analysis of vision, Peli et al
NASA Technical Reports Server (NTRS)
Cageao, R.; Sander, S.; Blavier, J.; Jiang, Y.; Nemtchinov, V.
2000-01-01
A compact, high resolution Fourier-transform spectrometer for atmospheric near ultraviolet spectroscopy has been installed at the Jet Propulsion Laboratory's Table Mountain Facility (34.4N, 117.7 W, elevation 2290m).
Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR.
ERIC Educational Resources Information Center
Perkins, W. D.
1987-01-01
This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)
Fourier transform of delayed fluorescence as an indicator of herbicide concentration.
Guo, Ya; Tan, Jinglu
2014-12-21
It is well known that delayed fluorescence (DF) from Photosystem II (PSII) of plant leaves can be potentially used to sense herbicide pollution and evaluate the effect of herbicides on plant leaves. The research of using DF as a measure of herbicides in the literature was mainly conducted in time domain and qualitative correlation was often obtained. Fourier transform is often used to analyze signals. Viewing DF signal in frequency domain through Fourier transform may allow separation of signal components and provide a quantitative method for sensing herbicides. However, there is a lack of an attempt to use Fourier transform of DF as an indicator of herbicide. In this work, the relationship between the Fourier transform of DF and herbicide concentration was theoretically modelled and analyzed, which immediately yielded a quantitative method to measure herbicide concentration in frequency domain. Experiments were performed to validate the developed method.
Entanglement of periodic states, the quantum Fourier transform, and Shor's factoring algorithm
Most, Yonatan; Biham, Ofer; Shimoni, Yishai
2010-05-15
The preprocessing stage of Shor's algorithm generates a class of quantum states referred to as periodic states, on which the quantum Fourier transform is applied. Such states also play an important role in other quantum algorithms that rely on the quantum Fourier transform. Since entanglement is believed to be a necessary resource for quantum computational speedup, we analyze the entanglement of periodic states and the way it is affected by the quantum Fourier transform. To this end, we derive a formula that evaluates the Groverian entanglement measure for periodic states. Using this formula, we explain the surprising result that the Groverian entanglement of the periodic states built up during the preprocessing stage is only slightly affected by the quantum Fourier transform.
The Fourier Transform in Chemistry. Part 1. Nuclear Magnetic Resonance: Introduction.
ERIC Educational Resources Information Center
King, Roy W.; Williams, Kathryn R.
1989-01-01
Using fourier transformation methods in nuclear magnetic resonance has made possible increased sensitivity in chemical analysis. This article describes these methods as they relate to magnetization, the RF magnetic field, nuclear relaxation, the RF pulse, and free induction decay. (CW)
Infrared (IR) spectroscopy has been widely used for the structural investigation of humic substances. Although Fourier Transform Infrared (FTIR) instrumentation has been available for sometime, relatively little work with these instruments has been reported for humic substances,...
Effect of coherence and polarization on frequency resolution in optical Fourier transforming system.
Ostrovsky, Andrey S; Olvera-Santamaría, Miguel Á; Romero-Soría, Paulo C
2011-12-01
Using an example of vector Gaussian Schell-model beam, we demonstrate and analyze the dependence of the spatial frequency resolution in optical Fourier transforming system on the intrinsic coherence-polarization structure of illumination.
NASA Technical Reports Server (NTRS)
Bowman, K.; Worden, H.; Beer, R.
1999-01-01
Spectra measured by off-axis detectors in a high-resolution Fourier transform spectrometer (FTS) are characterized by frequency scaling, asymmetry and broadening of their line shape, and self-apodization in the corresponding interferogram.
Computational chemistry, in conjunction with gas chromatography/mass spectrometry/Fourier transform infrared spectrometry (GC/MS/FT-IR), was used to tentatively identify seven tetrachlorobutadiene (TCBD) isomers detected in an environmental sample. Computation of the TCBD infrare...
[Studies on normal and mildewy Auricularia auricular by Fourier transform infrared spectroscopy].
Shi, You-ming; Liu, Gang; Sun, Yan-lin; Wei, Sheng-xian; Yan, Cui-qiong
2011-03-01
In order to verify the capability of Fourier transform infrared spectroscopy in food safety, Fourier transform infrared spectroscopy (FTIR) was used to obtain the spectra of normal and mildewy auricularia auricula, The result showed the frequency of hydroxyl and aliphatic absorption band in their spectra had evident differentia, with the dispersion being 23.31 and 13.41 cm(-1) respectively. The curve-fitting analysis was used for the fold peaks of hydroxyl and amido, and it presented that the content of hydroxyl and amido had evident change. The substances in the auricularia auricula generated chemical change, and Fourier transform infrared spectroscopy could show the differentia easily. The results show that Fourier transform infrared spectroscopy can provide valuable information about the auricularia auricula. It could be used as a reference method for identification of the normal and mildewy auricularia auricula.
Signal Coherence Recovery Using Acousto-Optic Fourier Transform Architectures
1990-06-14
processing of data in ground- and space-based applications. We have implemented a prototype one-dimensional time-integrating acousto - optic (AO) Fourier...theory of optimum coherence recovery (CR) applicable in computation-limited environments. We have demonstrated direct acousto - optic implementation of CR
Acousto-Optically Addressed Fourier Transform Matched Filters.
1984-08-01
ACOUSTO - OPTIC DEFLECTOR .............................. II. THE EXPERIMENT............................................. 2 FV XPERIMENTAl. RESULTS...tcohniqtie1 arc addressed using an acousto - optic beam deflector with good correlation signals resulting. Th is method may be used to address arrays of matched...essentially the standard Vander Lugt method for making matched filters, except for the addition of the acousto - optic deflector between the Fourier
Building a symbolic computer algebra toolbox to compute 2D Fourier transforms in polar coordinates.
Dovlo, Edem; Baddour, Natalie
2015-01-01
The development of a symbolic computer algebra toolbox for the computation of two dimensional (2D) Fourier transforms in polar coordinates is presented. Multidimensional Fourier transforms are widely used in image processing, tomographic reconstructions and in fact any application that requires a multidimensional convolution. By examining a function in the frequency domain, additional information and insights may be obtained. The advantages of our method include: •The implementation of the 2D Fourier transform in polar coordinates within the toolbox via the combination of two significantly simpler transforms.•The modular approach along with the idea of lookup tables implemented help avoid the issue of indeterminate results which may occur when attempting to directly evaluate the transform.•The concept also helps prevent unnecessary computation of already known transforms thereby saving memory and processing time.
Fourier-Transform Raman Spectroscopy Of Biological Assemblies
NASA Astrophysics Data System (ADS)
Levin, Ira W.; Lewis, E. Neil
1989-12-01
Although the successful coupling of Raman scattered near-infrared radiation to a Michelson interferometer has recently created an outburst of intense interest in Fourier-transform (FT) Raman spectrometry," extended applications of the technique to macromolecular assemblies of biochemical and biophysical relevance have not progressed as rapidly as studies directed primarily at more conventional chemical characterizations. Since biological materials sampled with visible laser excitation sources typically emit a dominant fluorescence signal originating either from the intrinsic fluorescence of the molecular scatterer or from unrelenting contaminants, the use of near-infrared Nd:YAG laser excitation offers a convenient approach for avoiding this frequently overwhelming effect. In addition, the FT-Raman instrumentation provides a means of eliminating the deleterious resonance and decomposition effects often observed with the more accessible green and blue laser emissions. However, in choosing the incident near-infrared wavelength at, for example, 1064nm, the Raman scattered intensity decreases by factors of eighteen to forty from the Raman emissions induced by the shorter, visible excitations. Depending upon the experiment, this disadvantage is offset by the throughput and multiplex advantages afforded by the interferometric design. Thus, for most chemical systems, near-infrared FT-Raman spectroscopy, clearly provides a means for obtaining vibrational Raman spectra from samples intractable to the use of visible laser sources. In particular, for neat liquids, dilute solutions or polycrystalline materials, the ability to achieve high quality, reproducible spectra is, with moderate experience and perhaps relatively high laser powers, as straightforward as the conventional methods used to obtain Raman spectra with visible excitation and dispersive monochromators. In using near-infrared FT techniques to determine the Raman spectra of biological samples, one encounters new
Analysis and application of Fourier transform spectroscopy in atmospheric remote sensing
NASA Technical Reports Server (NTRS)
Park, J. H.
1984-01-01
An analysis method for Fourier transform spectroscopy is summarized with applications to various types of distortion in atmospheric absorption spectra. This analysis method includes the fast Fourier transform method for simulating the interferometric spectrum and the nonlinear least-squares method for retrieving the information from a measured spectrum. It is shown that spectral distortions can be simulated quite well and that the correct information can be retrieved from a distorted spectrum by this analysis technique.
Application of the Fractional Fourier Transform in the Detection of Accelerating Targets in Clutter
2011-04-01
Warfare and Radar Division Defence Science and Technology Organisation DSTO–RR–0365 ABSTRACT We demonstrate that the Fractional Fourier transform is a...may fail. APPROVED FOR PUBLIC RELEASE UNCLASSIFIED DSTO–RR–0365 UNCLASSIFIED Published by DSTO Defence Science and Technology Organisation PO Box...Transform LFM: Linear Frequency Modulated (signal) PDF : Probability distribution function SCR: Signal-to-Clutter Ratio STFT: Short-Time Fourier
Baddour, Natalie
2010-10-01
For functions that are best described with spherical coordinates, the three-dimensional Fourier transform can be written in spherical coordinates as a combination of spherical Hankel transforms and spherical harmonic series. However, to be as useful as its Cartesian counterpart, a spherical version of the Fourier operational toolset is required for the standard operations of shift, multiplication, convolution, etc. This paper derives the spherical version of the standard Fourier operation toolset. In particular, convolution in various forms is discussed in detail as this has important consequences for filtering. It is shown that standard multiplication and convolution rules do apply as long as the correct definition of convolution is applied.
Zheng, Y. |; Shirley, D.A.
1995-02-01
The authors show by Fourier analyses of experimental data, with no further treatment, that the positions of all the strong peaks in Fourier transforms of angle-resolved photoemission extended fine structure (ARPEFS) from adsorbed surfaces can be explicitly predicted from a trial structure with an accuracy of about {+-} 0.3 {angstrom} based on a single-scattering cluster model together with the concept of a strong backscattering cone, and without any additional analysis. This characteristic of ARPEFS Fourier transforms can be developed as a simple method for determining the structures of adsorbed surfaces to an accuracy of about {+-} 0.1 {angstrom}.
NASA Astrophysics Data System (ADS)
Parker, R. W.; Frost, R. L.
1998-06-01
This paper describes how Diffuse Reflectance Fourier Transform Infrared (DRIFT) spectroscopy was used to monitor the sorption behavior of a short chain fatty acid, propanoic acid, on the clay mineral, montmorillonite. Organic acids bind to montmorillonite in two ways, either by dipole interaction with the oxygens in the interlayer space, or by bonding of the carboxylate anions to exposed aluminum ions. The DRIFT spectra of propanoic acid-montmorillonite complexes have bands at 1728 and 1554 cm-1, which are attributed to the symmetric, and antisymmetric stretching vibrations, respectively, of the C=O, ν(C=O)s, and O-C-O, ν(O-C-O)a, bonds of the carboxylic acid group. Each band represents one of the two different binding modes. These bands can be used to monitor the physical and chemical adsorption of the acid by the montmorillonite. When the peak area of each vibration is plotted against increasing acid concentration, both increase to a maximum. However the peak area for the ν(O-C-O)a vibration reaches a maximum at a much lower acid concentration than the ν(O=O)s vibration. The former maximum corresponds to saturation of the available binding sites on the edge surface aluminum ions. This concentration can be used to calculate the number of binding sites on the clay crystal. Where propanoic acid is allowed to diffuse from the clay, the bound fraction remains on the montmorillonite reducing the available acid that can be desorbed or leached from the clay.
Application Of Moire Analysis Of Strain Using Fourier Transform
NASA Astrophysics Data System (ADS)
Morimoto, Yoshiharu; Seguchi, Yasuyuki; Higashi, Toshihiko
1988-08-01
By shifting the discrete Fourier spectrum of the image of a deformed grating, we obtain the "complex moire pattern," from which strain distribution is given as the derivatives of the phases of the complex moire fringes. The analysis is completely automated by digital image processing. All of the laborious and subjective procedures required in the conventional analysis such as fringe sign determination, fringe ordering, and fringe interpolation are thus eliminated, permitting objective, fast, and accurate analysis. Some applications for rubber plates are shown.
Luo, David; Kudenov, Michael W
2016-05-16
Systematic phase errors in Fourier transform spectroscopy can severely degrade the calculated spectra. Compensation of these errors is typically accomplished using post-processing techniques, such as Fourier deconvolution, linear unmixing, or iterative solvers. This results in increased computational complexity when reconstructing and calibrating many parallel interference patterns. In this paper, we describe a new method of calibrating a Fourier transform spectrometer based on the use of artificial neural networks (ANNs). In this way, it is demonstrated that a simpler and more straightforward reconstruction process can be achieved at the cost of additional calibration equipment. To this end, we provide a theoretical model for general systematic phase errors in a polarization birefringent interferometer. This is followed by a discussion of our experimental setup and a demonstration of our technique, as applied to data with and without phase error. The technique's utility is then supported by comparison to alternative reconstruction techniques using fast Fourier transforms (FFTs) and linear unmixing.
Application Of Moire Analysis Of Strain Using Fourier Transform
NASA Astrophysics Data System (ADS)
Morimoto, Yoshiharu; Seguchi, Yasuyuki; Higashi, Toshihiko
1987-02-01
By shifting the discrete Fourier spectrum of the image of a deformed grating, we can obtain "the complex moire pattern", from which strain distribution is given as the derivatives of the phases of the complex moire fringes. The analysis is completely automatized by introducing the digital image processing. All of the laborious and subjective procedures required in the conventional analysis such as fringe sign determination, fringe ordering, fringe interpolation are so eliminated that objective, fast and accurate analysis can be made. Some applications for rubber plates are shown.
High Accuracy Evaluation of the Finite Fourier Transform Using Sampled Data
NASA Technical Reports Server (NTRS)
Morelli, Eugene A.
1997-01-01
Many system identification and signal processing procedures can be done advantageously in the frequency domain. A required preliminary step for this approach is the transformation of sampled time domain data into the frequency domain. The analytical tool used for this transformation is the finite Fourier transform. Inaccuracy in the transformation can degrade system identification and signal processing results. This work presents a method for evaluating the finite Fourier transform using cubic interpolation of sampled time domain data for high accuracy, and the chirp Zeta-transform for arbitrary frequency resolution. The accuracy of the technique is demonstrated in example cases where the transformation can be evaluated analytically. Arbitrary frequency resolution is shown to be important for capturing details of the data in the frequency domain. The technique is demonstrated using flight test data from a longitudinal maneuver of the F-18 High Alpha Research Vehicle.
Biological Applications Of Fourier Transform Infrared (FTIR) Or Bloody FTIR
NASA Astrophysics Data System (ADS)
Jakobsen, R. J.; Winters, S.; Gendreau, R. M.
1981-10-01
An ex vivo FT-IR/ATR experiment for studying blood protein adsorption at the molecular level is described. This experiment involves the use of live dogs pumping the blood through a arterial-veinal shunt to the ATR cell and back into the animal. The results from these live dog experiments are compared to results obtained using donated whole blood. These experiments demonstrate that FT-IR can be used to study aqueous, physiological, flowing solutions in real time with the sensitivity necessary to detect minor changes.
A Graphical Presentation to Teach the Concept of the Fourier Transform
ERIC Educational Resources Information Center
Besalu, E.
2006-01-01
A study was conducted to visualize the reason why the Fourier transform technique is useful to detect the originating frequencies of a complicated superposition of waves. The findings reveal that students respond well when instructors adapt pictorial presentation to show how the time-domain function is transformed into the frequency domain.
Development of out-of-core fast Fourier transform software for the connection machine. Final report
Sweet, R.; Wilson, J.
1995-10-01
This report describes the algorithm and implementation of an out-of-core Fast Fourier Transform routine for the Thinking Machines Corp. CM-5 parallel computer. The software has the capability of transforming multi-dimensional arrays that are both real and complex.
Adaptive motion mapping in pancreatic SBRT patients using Fourier transforms
Jones, Bernard L.; Schefter, Tracey; Miften, Moyed
2015-01-01
Background and Purpose Recent studies suggest that 4DCT is unable to accurately measure respiratory-induced pancreatic tumor motion. In this work, we assessed the daily motion of pancreatic tumors treated with SBRT, and developed adaptive strategies to predict and account for this motion. Materials and Methods The daily motion trajectory of pancreatic tumors during CBCT acquisition was calculated using a model which reconstructs the instantaneous 3D position in each 2D CBCT projection image. We developed a metric (termed “Spectral Coherence,” SC) based on the Fourier frequency spectrum of motion in the SI direction, and analyzed the ability of SC to predict motion-based errors and classify patients according to motion characteristics. Results The amplitude of daily motion exceeded the predictions of pre-treatment 4DCT imaging by an average of 3.0 mm, 2.3 mm, and 3.5 mm in the AP/LR/SI directions. SC was correlated with daily motion differences and tumor dose coverage. In a simulated adaptive protocol, target margins were adjusted based on SC, resulting in significant increases in mean target D95, D99, and minimum dose. Conclusions Our Fourier-based approach differentiates between consistent and inconsistent motion characteristics of respiration and correlates with daily motion deviations from pre-treatment 4DCT. The feasibility of an SC-based adaptive protocol was demonstrated, and this patient-specific respiratory information was used to improve target dosimetry by expanding coverage in inconsistent breathers while shrinking treatment volumes in consistent breathers. PMID:25890573
Large quantum Fourier transforms are never exactly realized by braiding conformal blocks
Freedman, Michael H.; Wang, Zhenghan
2007-03-15
Fourier transform is an essential ingredient in Shor's factoring algorithm. In the standard quantum circuit model with the gate set {l_brace}U(2), controlled-NOT{r_brace}, the discrete Fourier transforms F{sub N}=({omega}{sup ij}){sub NxN}, i,j=0,1,...,N-1, {omega}=e{sup 2{pi}}{sup i} at {sup {approx}}{sup sol{approx}} at {sup N}, can be realized exactly by quantum circuits of size O(n{sup 2}), n=ln N, and so can the discrete sine or cosine transforms. In topological quantum computing, the simplest universal topological quantum computer is based on the Fibonacci (2+1)-topological quantum field theory (TQFT), where the standard quantum circuits are replaced by unitary transformations realized by braiding conformal blocks. We report here that the large Fourier transforms F{sub N} and the discrete sine or cosine transforms can never be realized exactly by braiding conformal blocks for a fixed TQFT. It follows that an approximation is unavoidable in the implementation of Fourier transforms by braiding conformal blocks.
Operational and convolution properties of two-dimensional Fourier transforms in polar coordinates.
Baddour, Natalie
2009-08-01
For functions that are best described in terms of polar coordinates, the two-dimensional Fourier transform can be written in terms of polar coordinates as a combination of Hankel transforms and Fourier series-even if the function does not possess circular symmetry. However, to be as useful as its Cartesian counterpart, a polar version of the Fourier operational toolset is required for the standard operations of shift, multiplication, convolution, etc. This paper derives the requisite polar version of the standard Fourier operations. In particular, convolution-two dimensional, circular, and radial one dimensional-is discussed in detail. It is shown that standard multiplication/convolution rules do apply as long as the correct definition of convolution is applied.
Locke, Jonathan; White, Paul R
2011-10-01
The analysis of cetacean vocalizations is considered using Fourier-based techniques that employ chirp functions in their decomposition. In particular, the paper considers a short-time methods based on the fractional Fourier transform for detecting frequency modulated narrow-band signals, such as dolphin whistles, and compares this to the classical short-time Fourier methods. The fractional Fourier technique explored computes transforms associated with a range of chirp rates and automatically selects the rate for the final analysis. This avoids the need for prior knowledge of signal's chirp rate. An analysis is presented that details the performance of both methods as signal detectors and allows one to determine their detection thresholds. These thresholds are then used to measure the detectability of synthetic signals. This principle is then extended to measure performance on a set of recordings of narrow-band vocalizations from a range of cetacean species.
Spatial Fourier transform method for evaluating SQUID gradiometers
Ribeiro, P.C.; Bruno, A.C.; Paulsen, C.C.; Symko, O.G.
1987-08-01
A simple method of measuring the spatial transfer function of a gradiometer, consisting of a flux transformer coupled to a SQUID, is presented and it is compared with theoretical predictions. Based, on this approach, a new method of reporting a gradiometer's performance is proposed; the rejection factor is expressed in decibels obtained directly from the transfer function plot.
Products of multiple Fourier series with application to the multiblade transformation
NASA Technical Reports Server (NTRS)
Kunz, D. L.
1981-01-01
A relatively simple and systematic method for forming the products of multiple Fourier series using tensor like operations is demonstrated. This symbolic multiplication can be performed for any arbitrary number of series, and the coefficients of a set of linear differential equations with periodic coefficients from a rotating coordinate system to a nonrotating system is also demonstrated. It is shown that using Fourier operations to perform this transformation make it easily understood, simple to apply, and generally applicable.
2011-03-01
IMAGING FOURIER-TRANSFORM SPECTROSCOPY I. Introduction The passive optical remote sensing of chemical plumes is a well established field, and Fourier...increasing portability of the tech- nology this technique could eventually be applied to examine plumes of interest to the Department of Defense. Research ...forward using the technique. 2 Document structure Chapter II of this document presents a review of research critical to this work. Various remote
Fractional Fourier transform-based optical encryption with treble random phase-encoding
NASA Astrophysics Data System (ADS)
Xin, Yi; Tao, Ran; Wang, Yue
2008-03-01
We propose a new architecture of optical encryption technique using the fractional Fourier transform with three statistically independent random phase masks. Compared with the existing double-phase encoding method in the fractional Fourier-domain, the proposed extra phase mask in the last fractional Fourier domain makes the architecture symmetrical, and additive processing to the encrypted image can be turned into complex stationary white noise after decryption, and enlarge the key space without any degradation of its robustness to blind decryption. This property can be utilized to improve the quality of the recover image. Simulation results have verified the validity.
NASA Astrophysics Data System (ADS)
Cross, William Murray
The adsorption of surfactants at mineral oxide surfaces was investigated by in situ Fourier transform infrared internal reflection spectroscopy (FT-IR/IRS), and contact angle goniometry. FT-IR/IRS was used to determine both adsorption isotherms and the enthalpy of adsorption. Furthermore, the conformation and orientation of the hydrocarbon chain of SDS adsorbed at a sapphire internal reflection element (IRE) were determined. Contact angle goniometry was used to measure the effect of the surface phase of the surfactant on the hydrophobic character of sapphire surfaces in aqueous solutions. For SDS adsorbed by sapphire, in situ FT-IR/IRS experiments indicate that a surface phase transition occurs at an adsorption density of 2 to 3 x 10-10 mol/cm2 for both pD 2.9 and 6.9. This transition is characterized by a two to four wavenumber shift in the position of the asymmetric -CH2 stretching band. Based on solution spectroscopy studies, the surface phase was found to be similar to solution phase micelles and liquid crystals for adsorption densities less than the adsorption density of the surface phase transition. Whereas for adsorption densities in excess of the adsorption density of the surface phase transition, the surface phase resembled a solution phase coagel species. It was also found that the contact angle of an air bubble at the sapphire surface exhibited a sharp decrease at the adsorption density corresponding to the surface phase transition The effect of temperature on adsorption and phase behavior of SDS at the sapphire IRE surface was also determined. It was shown that a surface phase transition similar to that discussed occurred at approximately 298 K. The adsorption reaction was found to be exothermic, with a heat of adsorption of --1.3 kcal/mole for adsorption densities less than the adsorption density of the surface phase transition at 298 K and --4.1 kcal/mole for adsorption densities greater than the adsorption density of the surface phase transition
Mesh-based phase contrast Fourier transform imaging
NASA Astrophysics Data System (ADS)
Tahir, Sajjad; Bashir, Sajid; MacDonald, C. A.; Petruccelli, Jonathan C.
2017-04-01
Traditional x-ray radiography is limited by low attenuation contrast in materials of low electron density. Phase contrast imaging offers the potential to improve the contrast between such materials, but due to the requirements on the spatial coherence of the x-ray beam, practical implementation of such systems with tabletop (i.e. non-synchrotron) sources has been limited. One phase imaging technique employs multiple fine-pitched gratings. However, the strict manufacturing tolerances and precise alignment requirements have limited the widespread adoption of grating-based techniques. In this work, we have investigated a recently developed technique that utilizes a single grid of much coarser pitch. Our system consisted of a low power 100 μm spot Mo source, a CCD with 22 μm pixel pitch, and either a focused mammography linear grid or a stainless steel woven mesh. Phase is extracted from a single image by windowing and comparing data localized about harmonics of the mesh in the Fourier domain. The effects on the diffraction phase contrast and scattering amplitude images of varying grid types and periods, and of varying the width of the window function used to separate the harmonics were investigated. Using the wire mesh, derivatives of the phase along two orthogonal directions were obtained and combined to form improved phase contrast images.
Grid-Based Fourier Transform Phase Contrast Imaging
NASA Astrophysics Data System (ADS)
Tahir, Sajjad
Low contrast in x-ray attenuation imaging between different materials of low electron density is a limitation of traditional x-ray radiography. Phase contrast imaging offers the potential to improve the contrast between such materials, but due to the requirements on the spatial coherence of the x-ray beam, practical implementation of such systems with tabletop (i.e. non-synchrotron) sources has been limited. One recently developed phase imaging technique employs multiple fine-pitched gratings. However, the strict manufacturing tolerances and precise alignment requirements have limited the widespread adoption of grating-based techniques. In this work, we have investigated a technique recently demonstrated by Bennett et al. that utilizes a single grid of much coarser pitch. Our system consisted of a low power 100 microm spot Mo source, a CCD with 22 microm pixel pitch, and either a focused mammography linear grid or a stainless steel woven mesh. Phase is extracted from a single image by windowing and comparing data localized about harmonics of the grid in the Fourier domain. A Matlab code was written to perform the image processing. For the first time, the effects on the diffraction phase contrast and scattering amplitude images of varying grid types and periods, and of varying the window function type used to separate the harmonics, and the window widths, were investigated. Using the wire mesh, derivatives of the phase along two orthogonal directions were obtained and new methods investigated to form improved phase contrast images.
Fourier transform demodulation of pixelated phase-masked interferograms.
Servin, M; Estrada, J C; Medina, O
2010-07-19
Recently a new type of spatial phase shifting interferometer was proposed that uses a phase-mask over the camera's pixels. This new interferometer allows one to phase modulate each pixel independently by setting the angle of a linear polarizer built in contact over the camera's CCD. In this way neighbor pixels may have any desired (however fixed) phase shift without cross taking. The standard manufacturing of these interferometers uses a 2x2 array with phase-shifts of 0, pi/2, pi, and 3 pi/2 radians. This 2x2 array is tiled all over the video camera's CCD. In this paper we propose a new way to phase demodulate these phase-masked interferograms using the squeezing phase-shifting technique. A notable advantage of this squeezing technique is that it allows one the use of Fourier interferometry wiping out the detuning error that most phase shifting algorithms suffers. Finally we suggest the use of an alternative phase-mask to phase modulate the camera's pixels using a linear spatial carrier along a given axis.
van Agthoven, Maria A; Barrow, Mark P; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B
2015-12-01
Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules. Graphical Abstract ᅟ.
NASA Astrophysics Data System (ADS)
van Agthoven, Maria A.; Barrow, Mark P.; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A.; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B.
2015-12-01
Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules.
[Research on key technologies of all fiber optic Fourier transform spectrometer].
Wang, An; Zhu, Ling; Zhang, Long; Liu, Yong; Zhu, Zhen; Li, Zhi-Gang; Wu, Jian-Dong; Fan, Yan-Ping
2009-07-01
A noval all fiber optic Fourier transform spectrometer based on single mode fiber Mach-Zehnder interferometer is reported. The authors designed a piezoelectric optical phase modulator with two centimeter scan scale, which was used to replace the moving mirror of traditonal Fourier transform spectrometer. The 1 310 nm DFB laser was used as reference light source to make equal interval sampling of test light source's interferogram, and to eliminate errors of nonlinear modulation. Through making the inverse Fourier transform to test light source's interferogram, the authors obtained the spectrum of test source. The spectrum of ASE broadband light source was measured by FFTS system, and the experiment result agrees with that tested by grating spectrometer. Finally, the authors utilized fiber grating as sample to measure the resolution of FFTS system, and the spectral resolution is 0.78 cm(-1).
Periodic artifact reduction in Fourier transforms of full field atomic resolution images.
Hovden, Robert; Jiang, Yi; Xin, Huolin L; Kourkoutis, Lena F
2015-04-01
The discrete Fourier transform is among the most routine tools used in high-resolution scanning/transmission electron microscopy (S/TEM). However, when calculating a Fourier transform, periodic boundary conditions are imposed and sharp discontinuities between the edges of an image cause a cross patterned artifact along the reciprocal space axes. This artifact can interfere with the analysis of reciprocal lattice peaks of an atomic resolution image. Here we demonstrate that the recently developed Periodic Plus Smooth Decomposition technique provides a simple, efficient method for reliable removal of artifacts caused by edge discontinuities. In this method, edge artifacts are reduced by subtracting a smooth background that solves Poisson's equation with boundary conditions set by the image's edges. Unlike the traditional windowed Fourier transforms, Periodic Plus Smooth Decomposition maintains sharp reciprocal lattice peaks from the image's entire field of view.
Reduction and coding of synthetic aperture radar data with Fourier transforms
NASA Technical Reports Server (NTRS)
Tilley, David G.
1995-01-01
Recently, aboard the Space Radar Laboratory (SRL), the two roles of Fourier Transforms for ocean image synthesis and surface wave analysis have been implemented with a dedicated radar processor to significantly reduce Synthetic Aperture Radar (SAR) ocean data before transmission to the ground. The object was to archive the SAR image spectrum, rather than the SAR image itself, to reduce data volume and capture the essential descriptors of the surface wave field. SAR signal data are usually sampled and coded in the time domain for transmission to the ground where Fourier Transforms are applied both to individual radar pulses and to long sequences of radar pulses to form two-dimensional images. High resolution images of the ocean often contain no striking features and subtle image modulations by wind generated surface waves are only apparent when large ocean regions are studied, with Fourier transforms, to reveal periodic patterns created by wind stress over the surface wave field. Major ocean currents and atmospheric instability in coastal environments are apparent as large scale modulations of SAR imagery. This paper explores the possibility of computing complex Fourier spectrum codes representing SAR images, transmitting the coded spectra to Earth for data archives and creating scenes of surface wave signatures and air-sea interactions via inverse Fourier transformations with ground station processors.
Security of image encryption scheme based on multi-parameter fractional Fourier transform
NASA Astrophysics Data System (ADS)
Zhao, Tieyu; Ran, Qiwen; Yuan, Lin; Chi, Yingying; Ma, Jing
2016-10-01
Recently, multi-parameter fractional Fourier transform (MPFRFT) has been widely applied in the optics cryptosystem, which has attracted more and more researchers' attention. However, in further study we find a serious security problem on the MPFRFT which is the multi-choice of decryption key corresponding to an encryption key. The existence of multi-decryption-key hinders the application of this algorithm. We present a new generalized fractional Fourier transform, which can overcome the problem and enlarge the key space. The simulation results show that the proposed algorithm has higher security and key sensitivity.
Linear and Nonlinear Crosstalk Evaluation in DWDM Networks Using Optical Fourier Transformers
NASA Astrophysics Data System (ADS)
Llorente, R.; Clavero, R.; Ramos, F.; Marti, J.
2005-12-01
A novel DWDM channel monitoring technique based on the conversion from wavelength domain to time domain by performing a real-time optical Fourier transform over the whole DWDM system bandwidth is proposed and experimentally demonstrated. The use of chromatic dispersion-based optical Fourier transformers has been validated in the case of a spectrum comprising light from different uncorrelated sources. Linear and nonlinear crosstalks between the DWDM channels appear as amplitude noise at specific time positions. The correspondence of this amplitude noise with the crosstalk spectral distribution is evaluated theoretically and experimentally.
Fast 3D shape measurement using Fourier transform profilometry without phase unwrapping
NASA Astrophysics Data System (ADS)
Song, Kechen; Hu, Shaopeng; Wen, Xin; Yan, Yunhui
2016-09-01
This paper presents a novel, simple, yet fast 3D shape measurement method using Fourier transform profilometry. Different from the conventional Fourier transform profilometry, this proposed method introduces the binocular stereo vision and employs two image pairs (i.e., original image pairs and fringe image pairs) to restructure 3D shape. In this proposed method, instead of phase unwrapping algorithm, a coarse disparity map is adopted as a constraint condition to realize phase matching using wrapped phase. Since the local phase matching and sub-pixel disparity refinement are proposed to obtain high measuring accuracy, high-quality phase is not required. The validity of the proposed method is verified by experiments.
Ordered fast Fourier transforms on a massively parallel hypercube multiprocessor
NASA Technical Reports Server (NTRS)
Tong, Charles; Swarztrauber, Paul N.
1991-01-01
The present evaluation of alternative, massively parallel hypercube processor-applicable designs for ordered radix-2 decimation-in-frequency FFT algorithms gives attention to the reduction of computation time-dominating communication. A combination of the order and computational phases of the FFT is accordingly employed, in conjunction with sequence-to-processor maps which reduce communication. Two orderings, 'standard' and 'cyclic', in which the order of the transform is the same as that of the input sequence, can be implemented with ease on the Connection Machine (where orderings are determined by geometries and priorities. A parallel method for trigonometric coefficient computation is presented which does not employ trigonometric functions or interprocessor communication.
Multi-modal Color Medical Image Fusion Using Quaternion Discrete Fourier Transform
NASA Astrophysics Data System (ADS)
Nawaz, Qamar; Xiao, Bin; Hamid, Isma; Jiao, Du
2016-12-01
Multimodal image fusion is a process of combining multiple images, generated by identical or diverse imaging modalities, to get precise inside information about the same body organ. In recent years, various multimodal image fusion algorithms have been proposed to fuse medical image. However, most of them focus on fusing grayscale images. This paper proposes a novel algorithm for the fusion of multimodal color medical images. The proposed algorithm divides source images into blocks, converts each RGB block into quaternion representation and transforms them from special domain to frequency domain by applying quaternion discrete Fourier transform. The fused coefficients are obtained by calculating and comparing contrast values of corresponding coefficients in transformed blocks. The resultant fused image is reconstructed by merging all the blocks after applying inverse quaternion discrete Fourier transform on each block. Experimental evaluation demonstrates that the proposed algorithm qualitatively outperforms many existing state-of-the-art multimodal image fusion algorithms.
Gear Fault Signal Detection based on an Adaptive Fractional Fourier Transform Filter
NASA Astrophysics Data System (ADS)
Zhou, Xiaojun; Shao, Yimin; Zhen, Dong; Gu, Fengshou; Ball, Andrew
2011-07-01
Vibration-based fault diagnosis is widely used for gearbox monitoring. However, it often needs considerable effort to extract effective diagnostic feature signal from noisy vibration signals because of rich signal components contained in a complex gear transmission system. In this paper, an adaptive fractional Fourier transform filter is proposed to suppress noise in gear vibration signals and hence to highlight signal components originated from gear fault dynamic characteristics. The approach relies on the use of adaptive filters in the fractional Fourier transform domain with the optimised fractional transform order and the filter parameters, while the transform orders are selected when the signal have the highest energy gathering and the filter parameters are determined by evolutionary rules. The results from the simulation and experiments have verified the performance of the proposed algorithm in extracting the gear failure signal components from the noisy signals based on a multistage gearbox system.
Fourier transforms on Cantor sets: A study in non-Diophantine arithmetic and calculus
NASA Astrophysics Data System (ADS)
Aerts, Diederik; Czachor, Marek; Kuna, Maciej
2016-10-01
Fractals equipped with intrinsic arithmetic lead to a natural definition of differentiation, integration and complex numbers. Applying the formalism to the problem of a Fourier transform on fractals we show that the resulting transform has all the expected basic properties. As an example we discuss a sawtooth signal on the ternary middle-third Cantor set. The formalism works also for fractals that are not self-similar.
1984-04-01
RECONSTRUCTION OF PARTIALLY KNOWN, BAND - LIMITED FOURIER TRANSFORM PAIRS FROM NOISY DATA 0 Richard Baraka - Contractor: RGB Associates, Inc. Contract Number...is the archetypical linear problem in transform reconstruction. A number of algorithms have been proposed for its solution, either by iterative means ...Gerschberg and Saxton 11], Papoulis 121, Youla [3] or by direct means : Cadzow [4], Sabri and Steenaart [5]. Exampte 2, The Phone PAobZem. Given a
Waveguide Chirped-Pulse Fourier Transform Microwave Spectroscopy of 2-ETHOXYETHANOL
NASA Astrophysics Data System (ADS)
Phillips, Maria A.; Shipman, Steven T.
2013-06-01
The pure rotational spectrum of 2-ethoxyethanol was recorded from 8.7 to 26.5 GHz at 250 K with a waveguide chirped-pulse Fourier transform microwave spectrometer. The full spectrum contains contributions from multiple vibrational states. Preliminary assignments have been made with a combination of ab initio calculations and an automated spectral fitting program that accelerates the initial fitting process.
Measuring residual stress of anisotropic thin film by fast Fourier transform.
Tien, Chuen-Lin; Zeng, Hung-Da
2010-08-02
A new method for the measurement of anisotropic stress in thin films based on 2-D fast Fourier transform (FFT) is presented. A modified Twyman-Green interferometer was used for surface topography measurement. A fringe normalization technique was also used to improve the phase extraction technique efficiently. The measurement of anisotropic stress in obliquely deposited MgF(2) thin film was demonstrated.
PARTICULATE MATTER MEASUREMENTS USING OPEN-PATH FOURIER TRANSFORM INFRARED SPECTROSCOPY
Open-path Fourier transform infrared (OP-FT1R) spectroscopy is an accepted technology for measuring gaseous air contaminants. OP-FT1R absorbance spectra acquired during changing aerosols conditions reveal related changes in very broad baseline features. Usually, this shearing of ...
Technology Transfer Automated Retrieval System (TEKTRAN)
A new chemometric method based on absorbance ratios from Fourier transform infrared spectra was devised to analyze multicomponent biodegradable plastics. The method uses the BeerLambert law to directly compute individual component concentrations and weight losses before and after biodegradation of c...
Nikolay I. Agladz, John Klopf, Gwyn Williams, Albert J. Sievers
2010-06-01
By use of coherent terahertz synchrotron radiation, we experimentally tested a holographic Fourier transform spectrometer coupled to an array detector to determine its viability as a spectral device. Somewhat surprisingly, the overall performance strongly depends on the absorptivity of the birefringent lithium tantalate pixels in the array detector.
Technology Transfer Automated Retrieval System (TEKTRAN)
The automated quantification of three greenhouse gases, ammonia, methane and nitrous oxide, in the vicinity of a large dairy farm by open-path Fourier transform infrared (OP/FT-IR) spectrometry at intervals of 5 minutes is demonstrated. Spectral pretreatment, including the detection and correction ...
Nonuniform fast Fourier transform method for numerical diffraction simulation on tilted planes.
Xiao, Yu; Tang, Xiahui; Qin, Yingxiong; Peng, Hao; Wang, Wei; Zhong, Lijing
2016-10-01
The method, based on the rotation of the angular spectrum in the frequency domain, is generally used for the diffraction simulation between the tilted planes. Due to the rotation of the angular spectrum, the interval between the sampling points in the Fourier domain is not even. For the conventional fast Fourier transform (FFT)-based methods, a spectrum interpolation is needed to get the approximate sampling value on the equidistant sampling points. However, due to the numerical error caused by the spectrum interpolation, the calculation accuracy degrades very quickly as the rotation angle increases. Here, the diffraction propagation between the tilted planes is transformed into a problem about the discrete Fourier transform on the uneven sampling points, which can be evaluated effectively and precisely through the nonuniform fast Fourier transform method (NUFFT). The most important advantage of this method is that the conventional spectrum interpolation is avoided and the high calculation accuracy can be guaranteed for different rotation angles, even when the rotation angle is close to π/2. Also, its calculation efficiency is comparable with that of the conventional FFT-based methods. Numerical examples as well as a discussion about the calculation accuracy and the sampling method are presented.
Technology Transfer Automated Retrieval System (TEKTRAN)
Our presentation will focus on continuing efforts to examine secondary cell wall development in cotton fibers using infrared Spectroscopy. Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-...
Teaching Stable Two-Mirror Resonators through the Fractional Fourier Transform
ERIC Educational Resources Information Center
Moreno, Ignacio; Garcia-Martinez, Pascuala; Ferreira, Carlos
2010-01-01
We analyse two-mirror resonators in terms of their fractional Fourier transform (FRFT) properties. We use the basic ABCD ray transfer matrix method to show how the resonator can be regarded as the cascade of two propagation-lens-propagation FRFT systems. Then, we present a connection between the geometric properties of the resonator (the g…
All optical discrete Fourier transform processor for 100 Gbps OFDM transmission.
Lee, Kyusang; Thai, Chan T D; Rhee, June-Koo Kevin
2008-03-17
Optical orthogonal frequency division multiplex (OFDM) symbol generation by all-optical discrete Fourier transform (DFT) is proposed and investigated for 100-Gbps transmission performance. We discuss a design example for a 4x25Gbps OFDM transmission system and its performance comparison with that for a 100-Gbps single-channel return-to-zero data transmission in an optically amplified system.
NASA Astrophysics Data System (ADS)
Luc, Paul
1995-07-01
This paper gives the main results obtained at Laboratoire Aimé Cotton, using Fourier transform spectroscopy (FTS) in the visible and UV ranges. After a rapid historical survey, a description of the fourth generation interferometer, which is specially designed to record visible and UV light will be given. Typical results in emission and absorption spectroscopy, including the metrological applications, will follow.
The Kinetics of Mo(Co)6 Substitution Monitored by Fourier Transform Infrared Spectrophotometry.
ERIC Educational Resources Information Center
Suslick, Kenneth S.; And Others
1987-01-01
Describes a physical chemistry experiment that uses Fourier transform (FTIR) spectrometers and microcomputers as a way of introducing students to the spectral storage and manipulation techniques associated with digitized data. It can be used to illustrate FTIR spectroscopy, simple kinetics, inorganic mechanisms, and Beer's Law. (TW)
ERIC Educational Resources Information Center
Perkins, W. D.
1986-01-01
Discusses: (1) the design of the Fourier Transform-Infrared Spectroscopy (FT-IR) spectrometer; (2) the computation of the spectrum from the interferogram; and (3) the use of apodization. (Part II will discuss advantages of FT-IR over dispersive techniques and show applications of FT-IR to difficult spectroscopic measurements.) (JN)
Regenerative Fourier transformation for dual-quadrature regeneration of multilevel rectangular QAM.
Sorokina, Mariia; Sygletos, Stylianos; Ellis, Andrew; Turitsyn, Sergei
2015-07-01
We propose a new nonlinear optical loop mirror based configuration capable of regenerating regular rectangular quadrature amplitude modulated (QAM) signals. The scheme achieves suppression of noise distortion on both signal quadratures through the realization of two orthogonal regenerative Fourier transformations. Numerical simulations show the performance of the scheme for high constellation complexities (including 256-QAM formats).
Technology Transfer Automated Retrieval System (TEKTRAN)
Soil science research is increasingly applying Fourier transform infrared (FTIR) spectroscopy for analysis of soil organic matter (SOM). However, the compositional complexity of soils and the dominance of the mineral component can limit spectroscopic resolution of SOM and other minor components. The...
System tolerance of all-optical sampling OFDM using AWG discrete Fourier transform.
Lim, Seong-Jin; Rhee, June-Koo Kevin
2011-07-04
The fundamental-mode arrayed waveguide grating (AWG) for all-optical discrete Fourier transformer (DFT) shows significant feasibility in the system tolerance of all-optical sampling orthogonal frequency division multiplexing (AOS-OFDM) systems. We discuss the system tolerance of AWG-based DFT designs for 100/160Gbps OFDM transmission system in comparison with coupler-based DFT designs.
Two-dimensional ultrafast fourier transform spectroscopy in the deep ultraviolet.
Tseng, Chien-hung; Matsika, Spiridoula; Weinacht, Thomas C
2009-10-12
We demonstrate two-dimensional ultrafast fourier transform spectroscopy in the deep ultraviolet (approximately 260 nm) using an acousto-optic modulator based pulse shaper. The use of a pulse shaper in the ultraviolet allows for rapid scanning, high phase (time) stability (approximately 0.017 rad) and phase cycling. We present measurements on the DNA nucleobase Adenine.
Applications of Fourier transform infrared spectroscopy to quality control of the epoxy matrix
NASA Technical Reports Server (NTRS)
Antoon, M. K.; Starkey, K. M.; Koenig, J. L.
1979-01-01
The object of the paper is to demonstrate the utility of Fourier transform infrared (FT-IR) difference spectra for investigating the composition of a neat epoxy resin, hardener, and catalysts. The composition and degree of cross-linking of the cured matrix is also considered.
NASA Astrophysics Data System (ADS)
Baril, Marc R.; Grandmont, Frédéric J.; Mandar, Julie; Drissen, Laurent; Martin, Thomas; Rousseau-Nepton, Laurie; Thibault, Simon; Brousseau, Denis; Levesque, Steve R.; Thomas, Jim; Malo, Lison; Morrison, Glenn; le Gal, Maëlle; Jones, Windell; Barrick, Gregory; Benedict, Tom; Salmon, Derrick; Prunet, Simon; Devost, Daniel
2016-08-01
The SITELLE Imaging Fourier Transform Spectrometer was successfully commissioned at the Canada France Hawaii Telescope starting in July 2015. Here we discuss the commissioning process, the outcome of the early tests on-sky as well as the ensuing work to optimize the modulation efficiency at large optical path difference and the image quality of the instrument.
NASA Astrophysics Data System (ADS)
Gundreddy, Rohith Reddy; Tan, Maxine; Qui, Yuchen; Zheng, Bin
2015-03-01
The purpose of this study is to develop and test a new content-based image retrieval (CBIR) scheme that enables to achieve higher reproducibility when it is implemented in an interactive computer-aided diagnosis (CAD) system without significantly reducing lesion classification performance. This is a new Fourier transform based CBIR algorithm that determines image similarity of two regions of interest (ROI) based on the difference of average regional image pixel value distribution in two Fourier transform mapped images under comparison. A reference image database involving 227 ROIs depicting the verified soft-tissue breast lesions was used. For each testing ROI, the queried lesion center was systematically shifted from 10 to 50 pixels to simulate inter-user variation of querying suspicious lesion center when using an interactive CAD system. The lesion classification performance and reproducibility as the queried lesion center shift were assessed and compared among the three CBIR schemes based on Fourier transform, mutual information and Pearson correlation. Each CBIR scheme retrieved 10 most similar reference ROIs and computed a likelihood score of the queried ROI depicting a malignant lesion. The experimental results shown that three CBIR schemes yielded very comparable lesion classification performance as measured by the areas under ROC curves with the p-value greater than 0.498. However, the CBIR scheme using Fourier transform yielded the highest invariance to both queried lesion center shift and lesion size change. This study demonstrated the feasibility of improving robustness of the interactive CAD systems by adding a new Fourier transform based image feature to CBIR schemes.
The Fractional Fourier Transform and Its Application to Energy Localization Problems
NASA Astrophysics Data System (ADS)
Oonincx, Patrick J.; ter Morsche, Hennie G.
2003-12-01
Applying the fractional Fourier transform (FRFT) and the Wigner distribution on a signal in a cascade fashion is equivalent to a rotation of the time and frequency parameters of the Wigner distribution. We presented in ter Morsche and Oonincx, 2002, an integral representation formula that yields affine transformations on the spatial and frequency parameters of the[InlineEquation not available: see fulltext.]-dimensional Wigner distribution if it is applied on a signal with the Wigner distribution as for the FRFT. In this paper, we show how this representation formula can be used to solve certain energy localization problems in phase space. Examples of such problems are given by means of some classical results. Although the results on localization problems are classical, the application of generalized Fourier transform enlarges the class of problems that can be solved with traditional techniques.
Park, G Barratt; Field, Robert W
2016-05-28
Since its invention in 2006, the broadband chirped pulse Fourier transform spectrometer has transformed the field of microwave spectroscopy. The technique enables the collection of a ≥10 GHz bandwidth spectrum in a single shot of the spectrometer, which allows broadband, high-resolution microwave spectra to be acquired several orders of magnitude faster than what was previously possible. We discuss the advantages and challenges associated with the technique and look back on the first ten years of chirped pulse Fourier transform spectroscopy. In addition to enabling faster-than-ever structure determination of increasingly complex species, the technique has given rise to an assortment of entirely new classes of experiments, ranging from chiral sensing by three-wave mixing to microwave detection of multichannel reaction kinetics. However, this is only the beginning. Future generations of microwave experiments will make increasingly creative use of frequency-agile pulse sequences for the coherent manipulation and interrogation of molecular dynamics.
Detecting of copy-move forgery in digital images using fractional Fourier transform
NASA Astrophysics Data System (ADS)
Yang, Renqing; Bai, Zhengyao; Yin, Liguo; Gao, Hao
2015-07-01
Copy-move forgery is one of the most simple and commonly used forging methods, where a part of image itself is copied and pasted on another part of the same image. This paper presents a new approach for copy-move forgery detection where fractional Fourier transform (FRFT) is used. First, the 1-level discrete wavelet transform (DWT) of the forged image is to reduce its dimension. Next, the low frequency the sub-band is divided into overlapped blocks of equal size. The fractional Fourier transform of each block is calculated and the vector of the coefficients is constructed. All feature vectors are sorted using lexicographical order. Finally, the difference of adjacent feature vectors is evaluated and employed to locate the duplicated regions which have the same feature vectors. Experimental results show that the proposed method is effective in detection of the copy-move forgery regions.
Use of the fast Fourier transform method for analyzing linear and equispaced Fizeau fringes.
Lai, G; Yatagai, T
1994-09-01
The Fourier transform method is applied to analyze the initial phase of linear and equispaced Fizeau fringes. We develop an algorithm for high-precision phase measurement by using the Fourier coefficient that corresponds to the spatial frequency of the Fizeau fringes, and we describe methods for determining the fringe carrier frequency. Errors caused by carrier frequency fluctuation and data truncation are studied theoretically and by computer simulation. To demonstrate the method we apply it to the real-time calibration of a piezoelectric transducer mirror in a Twyman-Green interferometer.
Double-resolution electron holography with simple Fourier transform of fringe-shifted holograms.
Volkov, V V; Han, M G; Zhu, Y
2013-11-01
We propose a fringe-shifting holographic method with an appropriate image wave recovery algorithm leading to exact solution of holographic equations. With this new method the complex object image wave recovered from holograms appears to have much less traditional artifacts caused by the autocorrelation band present practically in all Fourier transformed holograms. The new analytical solutions make possible a double-resolution electron holography free from autocorrelation band artifacts and thus push the limits for phase resolution. The new image wave recovery algorithm uses a popular Fourier solution of the side band-pass filter technique, while the fringe-shifting holographic method is simple to implement in practice.
A fast partial Fourier transform (FPFT) for data compression and filtering.
Smith, Mark William
2010-07-01
A discrete Fourier transform (DFT) or the closely related discrete cosine transform (DCT) is often employed as part of a data compression scheme. This paper presents a fast partial Fourier transform (FPFT) algorithm that is useful for calculating a subset of M Fourier transform coefficients for a data set comprised of N points (M < N). This algorithm reduces to the standard DFT when M = 1 and it reduces to the radix-2, decimation-in-time FFT when M = N and N is a power of 2. The DFT requires on the order of MN complex floating point multiplications to calculate M coefficients for N data points, a complete FFT requires on the order of (N/2)log{sub 2}N multiplications independent of M, and the new FPFT algorithm requires on the order of (N/2)log{sub 2}M + N multiplications. The FPFT algorithm introduced in this paper could be readily adapted to parallel processing. In addition to data compression, the FPFT algorithm described in this paper might be useful for very narrow band filter operations that pass only a small number of non-zero frequency coefficients such that M << N.
Lu, Wenlong; Xie, Junwei; Wang, Heming; Sheng, Chuan
2016-01-01
Inspired by track-before-detection technology in radar, a novel time-frequency transform, namely polynomial chirping Fourier transform (PCFT), is exploited to extract components from noisy multicomponent signal. The PCFT combines advantages of Fourier transform and polynomial chirplet transform to accumulate component energy along a polynomial chirping curve in the time-frequency plane. The particle swarm optimization algorithm is employed to search optimal polynomial parameters with which the PCFT will achieve a most concentrated energy ridge in the time-frequency plane for the target component. The component can be well separated in the polynomial chirping Fourier domain with a narrow-band filter and then reconstructed by inverse PCFT. Furthermore, an iterative procedure, involving parameter estimation, PCFT, filtering and recovery, is introduced to extract components from a noisy multicomponent signal successively. The Simulations and experiments show that the proposed method has better performance in component extraction from noisy multicomponent signal as well as provides more time-frequency details about the analyzed signal than conventional methods.
A Study of Derivative Filters Using the Discrete Fourier Transform. Final Report M. S. Thesis
NASA Technical Reports Server (NTRS)
Ioup, G. E.
1980-01-01
Important properties of derivative (difference) filters using the discrete Fourier transform are investigated. The filters are designed using the derivative theorem of Fourier analysis. Because physical data are generally degraded by noise, the derivative filter is modified to diminish the effects of the noise, especially the noise amplification which normally occurs while differencing. The basis for these modifications is the reduction of those Fourier components for which the noise most dominates the data. The various filters are tested by applying them to find differences of two-dimensional data to which various amounts of signal dependent noise, as measured by a root mean square value, have been added. The modifications, circular and square ideal low-pass filters and a cut-off pyramid filter, are all found to reduce noise in the derivative without significantly degrading the result.
Program for the analysis of time series. [by means of fast Fourier transform algorithm
NASA Technical Reports Server (NTRS)
Brown, T. J.; Brown, C. G.; Hardin, J. C.
1974-01-01
A digital computer program for the Fourier analysis of discrete time data is described. The program was designed to handle multiple channels of digitized data on general purpose computer systems. It is written, primarily, in a version of FORTRAN 2 currently in use on CDC 6000 series computers. Some small portions are written in CDC COMPASS, an assembler level code. However, functional descriptions of these portions are provided so that the program may be adapted for use on any facility possessing a FORTRAN compiler and random-access capability. Properly formatted digital data are windowed and analyzed by means of a fast Fourier transform algorithm to generate the following functions: (1) auto and/or cross power spectra, (2) autocorrelations and/or cross correlations, (3) Fourier coefficients, (4) coherence functions, (5) transfer functions, and (6) histograms.
Tropical Forest Biomass Estimation from Vertical Fourier Transforms of Lidar and InSAR Profiles
NASA Astrophysics Data System (ADS)
Treuhaft, R. N.; Goncalves, F.; Drake, J.; Hensley, S.; Chapman, B. D.; Michel, T.; Dos Santos, J. R.; Dutra, L.; Graca, P. A.
2010-12-01
Structural forest biomass estimation from lidar or interferometric SAR (InSAR) has demonstrated better performance than radar-power-based approaches for the higher biomasses (>150 Mg/ha) found in tropical forests. Structural biomass estimation frequently regresses field biomass to some function of forest height. With airborne, 25-m footprint lidar data and fixed-baseline C-band InSAR data over tropical wet forests of La Selva Biological Station, Costa Rica, we compare the use of Fourier transforms of vertical profiles at a few frequencies to the intrinsically low-frequency “average height”. RMS scatters of Fourier-estimated biomass about field-measured biomass improved by 40% and 20% over estimates base on average height from lidar and fixed-baseline InSAR, respectively. Vertical wavelengths between 14 and 100 m were found to best estimate biomass. The same airborne data acquisition over La Selva was used to generate many 10’s of repeat-track L-band InSAR baselines with time delays of 1-72 hours, and vertical wavelengths of 5-100 m. We will estimate biomass from the Fourier transforms of L-band radar power profiles (InSAR complex coherence). The effects of temporal decorrelation will be modeled in the Fourier domain to try to model and reduce their impact. Using L-band polarimetric interferometry, average heights will be estimated as well and biomass regression performance compared to the Fourier transform approach. The more traditional approach of using L-band radar polarimetry will also be compared to structural biomass estimation.
NASA Astrophysics Data System (ADS)
Krovi, Hari; Russell, Alexander
2015-03-01
Knot and link invariants naturally arise from any braided Hopf algebra. We consider the computational complexity of the invariants arising from an elementary family of finite-dimensional Hopf algebras: quantum doubles of finite groups [denoted , for a group G]. These induce a rich family of knot invariants and, additionally, are directly related to topological quantum computation. Regarding algorithms for these invariants, we develop quantum circuits for the quantum Fourier transform over ; in general, we show that when one can uniformly and efficiently carry out the quantum Fourier transform over the centralizers Z( g) of the elements of G, one can efficiently carry out the quantum Fourier transform over . We apply these results to the symmetric groups to yield efficient circuits for the quantum Fourier transform over . With such a Fourier transform, it is straightforward to obtain additive approximation algorithms for the related link invariant. As for hardness results, first we note that in contrast to those concerning the Jones polynomial—where the images of the braid group representations are dense in the unitary group—the images of the representations arising from are finite. This important difference appears to be directly reflected in the complexity of these invariants. While additively approximating "dense" invariants is -complete and multiplicatively approximating them is -complete, we show that certain invariants (such as invariants) are -hard to additively approximate, -hard to multiplicatively approximate, and -hard to exactly evaluate. To show this, we prove that, for groups (such as A n ) which satisfy certain properties, the probability of success of any randomized computation can be approximated to within any by the plat closure. Finally, we make partial progress on the question of simulating anyonic computation in groups uniformly as a function of the group size. In this direction, we provide efficient quantum circuits for the Clebsch
A Discussion of the Discrete Fourier Transform Execution on a Typical Desktop PC
NASA Technical Reports Server (NTRS)
White, Michael J.
2006-01-01
This paper will discuss and compare the execution times of three examples of the Discrete Fourier Transform (DFT). The first two examples will demonstrate the direct implementation of the algorithm. In the first example, the Fourier coefficients are generated at the execution of the DFT. In the second example, the coefficients are generated prior to execution and the DFT coefficients are indexed at execution. The last example will demonstrate the Cooley- Tukey algorithm, better known as the Fast Fourier Transform. All examples were written in C executed on a PC using a Pentium 4 running at 1.7 Ghz. As a function of N, the total complex data size, the direct implementation DFT executes, as expected at order of N2 and the FFT executes at order of N log2 N. At N=16K, there is an increase in processing time beyond what is expected. This is not caused by implementation but is a consequence of the effect that machine architecture and memory hierarchy has on implementation. This paper will include a brief overview of digital signal processing, along with a discussion of contemporary work with discrete Fourier processing.
Fast large scale structure perturbation theory using one-dimensional fast Fourier transforms
NASA Astrophysics Data System (ADS)
Schmittfull, Marcel; Vlah, Zvonimir; McDonald, Patrick
2016-05-01
The usual fluid equations describing the large-scale evolution of mass density in the universe can be written as local in the density, velocity divergence, and velocity potential fields. As a result, the perturbative expansion in small density fluctuations, usually written in terms of convolutions in Fourier space, can be written as a series of products of these fields evaluated at the same location in configuration space. Based on this, we establish a new method to numerically evaluate the 1-loop power spectrum (i.e., Fourier transform of the 2-point correlation function) with one-dimensional fast Fourier transforms. This is exact and a few orders of magnitude faster than previously used numerical approaches. Numerical results of the new method are in excellent agreement with the standard quadrature integration method. This fast model evaluation can in principle be extended to higher loop order where existing codes become painfully slow. Our approach follows by writing higher order corrections to the 2-point correlation function as, e.g., the correlation between two second-order fields or the correlation between a linear and a third-order field. These are then decomposed into products of correlations of linear fields and derivatives of linear fields. The method can also be viewed as evaluating three-dimensional Fourier space convolutions using products in configuration space, which may also be useful in other contexts where similar integrals appear.
NASA Astrophysics Data System (ADS)
Dong, Bing; Qin, Shun; Hu, Xinqi
2013-09-01
Large-aperture segmented primary mirror will be widely used in next-generation space-based and ground-based telescopes. The effects of intersegment gaps, obstructions, position and figure errors of segments, which are all involved in the pupil plane, on the image quality metric should be analyzed using diffractive imaging theory. Traditional Fast Fourier Transform (FFT) method is very time-consuming and costs a lot of memory especially in dealing with large pupil-sampling matrix. A Partial Fourier Transform (PFT) method is first proposed to substantially speed up the computation and reduce memory usage for diffractive imaging analysis. Diffraction effects of a 6-meter segmented mirror including 18 hexagonal segments are simulated and analyzed using PFT method. The influence of intersegment gaps and position errors of segments on Strehl ratio is quantitatively analyzed by computing the Point Spread Function (PSF). By comparing simulation results with theoretical results, the correctness and feasibility of PFT method is confirmed.
Suppression law of quantum states in a 3D photonic fast Fourier transform chip
NASA Astrophysics Data System (ADS)
Crespi, Andrea; Osellame, Roberto; Ramponi, Roberta; Bentivegna, Marco; Flamini, Fulvio; Spagnolo, Nicolò; Viggianiello, Niko; Innocenti, Luca; Mataloni, Paolo; Sciarrino, Fabio
2016-02-01
The identification of phenomena able to pinpoint quantum interference is attracting large interest. Indeed, a generalization of the Hong-Ou-Mandel effect valid for any number of photons and optical modes would represent an important leap ahead both from a fundamental perspective and for practical applications, such as certification of photonic quantum devices, whose computational speedup is expected to depend critically on multi-particle interference. Quantum distinctive features have been predicted for many particles injected into multimode interferometers implementing the Fourier transform over the optical modes. Here we develop a scalable approach for the implementation of the fast Fourier transform algorithm using three-dimensional photonic integrated interferometers, fabricated via femtosecond laser writing technique. We observe the suppression law for a large number of output states with four- and eight-mode optical circuits: the experimental results demonstrate genuine quantum interference between the injected photons, thus offering a powerful tool for diagnostic of photonic platforms.
Simulation of micromechanical behavior of polycrystals: finite elements vs. fast Fourier transforms
Lebensohn, Ricardo A; Prakash, Arun
2009-01-01
In this work, we compare finite element and fast Fourier transform approaches for the prediction of micromechanical behavior of polycrystals. Both approaches are full-field approaches and use the same visco-plastic single crystal constitutive law. We investigate the texture and the heterogeneity of the inter- and intragranular, stress and strain fields obtained from the two models. Additionally, we also look into their computational performance. Two cases - rolling of aluminium and wire drawing of tungsten - are used to evaluate the predictions of the two mode1s. Results from both the models are similar, when large grain distortions do not occur in the polycrystal. The finite element simulations were found to be highly computationally intensive, in comparison to the fast Fourier transform simulations.
Suppression law of quantum states in a 3D photonic fast Fourier transform chip
Crespi, Andrea; Osellame, Roberto; Ramponi, Roberta; Bentivegna, Marco; Flamini, Fulvio; Spagnolo, Nicolò; Viggianiello, Niko; Innocenti, Luca; Mataloni, Paolo; Sciarrino, Fabio
2016-01-01
The identification of phenomena able to pinpoint quantum interference is attracting large interest. Indeed, a generalization of the Hong–Ou–Mandel effect valid for any number of photons and optical modes would represent an important leap ahead both from a fundamental perspective and for practical applications, such as certification of photonic quantum devices, whose computational speedup is expected to depend critically on multi-particle interference. Quantum distinctive features have been predicted for many particles injected into multimode interferometers implementing the Fourier transform over the optical modes. Here we develop a scalable approach for the implementation of the fast Fourier transform algorithm using three-dimensional photonic integrated interferometers, fabricated via femtosecond laser writing technique. We observe the suppression law for a large number of output states with four- and eight-mode optical circuits: the experimental results demonstrate genuine quantum interference between the injected photons, thus offering a powerful tool for diagnostic of photonic platforms. PMID:26843135
Fourier Transform Ultrasound Spectroscopy for the determination of wave propagation parameters.
Pal, Barnana
2017-01-01
The reported results for ultrasonic wave attenuation constant (α) in pure water show noticeable inconsistency in magnitude. A "Propagating-Wave" model analysis of the most popular pulse-echo technique indicates that this is a consequence of the inherent wave propagation characteristics in a bounded medium. In the present work Fourier Transform Ultrasound Spectroscopy (FTUS) is adopted to determine ultrasonic wave propagation parameters, the wave number (k) and attenuation constant (α) at 1MHz frequency in tri-distilled water at room temperature (25°C). Pulse-echo signals obtained under same experimental conditions regarding the exciting input signal and reflecting boundary wall of the water container for various lengths of water columns are captured. The Fast Fourier Transform (FFT) components of the echo signals are taken to compute k, α and r, the reflection constant at the boundary, using Oak Ridge and Oxford method. The results are compared with existing literature values.
Barnett, Patrick D; Strange, K Alicia; Angel, S Michael
2016-12-12
This work describes a method of applying the Fourier transform to the two-dimensional Fizeau fringe patterns generated by the spatial heterodyne Raman spectrometer (SHRS), a dispersive interferometer, to correct the effects of certain types of optical alignment errors. In the SHRS, certain types of optical misalignments result in wavelength-dependent and wavelength-independent rotations of the fringe pattern on the detector. We describe here a simple correction technique that can be used in post-processing, by applying the Fourier transform in a row-by-row manner. This allows the user to be more forgiving of fringe alignment and allows for a reduction in the mechanical complexity of the SHRS.
Multiple-image encryption based on phase mask multiplexing in fractional Fourier transform domain.
Liansheng, Sui; Meiting, Xin; Ailing, Tian
2013-06-01
A multiple-image encryption scheme is proposed based on the phase retrieval process and phase mask multiplexing in the fractional Fourier transform domain. First, each original gray-scale image is encoded into a phase only function by using the proposed phase retrieval process. Second, all the obtained phase functions are modulated into an interim, which is encrypted into the final ciphertext by using the fractional Fourier transform. From a plaintext image, a group of phase masks is generated in the encryption process. The corresponding decrypted image can be recovered from the ciphertext only with the correct phase mask group in the decryption process. Simulation results show that the proposed phase retrieval process has high convergence speed, and the encryption algorithm can avoid cross-talk; in addition, its encrypted capacity is considerably enhanced.
NASA Astrophysics Data System (ADS)
Sun, Zhiwei; Zhi, Ya'nan; Liu, Liren; Sun, Jianfeng; Zhou, Yu; Hou, Peipei
2013-09-01
The synthetic aperture imaging ladar (SAIL) systems typically generate large amounts of data difficult to compress with digital method. This paper presents an optical SAIL processor based on compensation of quadratic phase of echo in azimuth direction and two dimensional Fourier transform. The optical processor mainly consists of one phase-only liquid crystal spatial modulator(LCSLM) to load the phase data of target echo and one cylindrical lens to compensate the quadratic phase and one spherical lens to fulfill the task of two dimensional Fourier transform. We show the imaging processing result of practical target echo obtained by a synthetic aperture imaging ladar demonstrator. The optical processor is compact and lightweight and could provide inherent parallel and the speed-of-light computing capability, it has a promising application future especially in onboard and satellite borne SAIL systems.
Seismology with a Fourier-transform spectrometer: applications to giant planets and stars.
Maillard, J P
1996-06-01
A method to detect the acoustic oscillation spectrum of giant planets and stars exploits the multiplex properties of a Fourier-transform spectrometer (FTS). It is based on measurement of the small Doppler shift related to the oscillation of the atmosphere measured from all the lines in a portion of the planetary or the stellar spectrum directly from the interferogram. The resulting amplitude modulation of the output signal is recorded continuously over several consecutive nights at a fixed path difference selected from criteria of optimum efficiency. Hence the Fourier transform of this signal yields the pressure-mode spectrum of the object. Applications to Jupiter, Saturn, and Procyon, observed in this mode with the step-scan FTS installed in the Canada-France-Hawaii Telescope, are presented. Future projects are discussed.
Fast Fourier transform for Voigt profile: Comparison with some other algorithms
NASA Astrophysics Data System (ADS)
Abousahl, S.; Gourma, M.; Bickel, M.
1997-02-01
There are different algorithms describing the Voigt profile. This profile is encountered in many areas of physics which could be limited by the resolution of the instrumentation used to measure it and by other phenomena like the interaction between the emitted waves and matter. In nuclear measurement field, the codes used to characterise radionucleides rely on algorithms resolving the Voigt profile equation. The Fast Fourier Transform (FFT) algorithm allows the validation of some algorithms.
Using single buffers and data reorganization to implement a multi-megasample fast Fourier transform
NASA Technical Reports Server (NTRS)
Brown, R. D.
1992-01-01
Data ordering in large fast Fourier transforms (FFT's) is both conceptually and implementationally difficult. Discribed here is a method of visualizing data orderings as vectors of address bits, which enables the engineer to use more efficient data orderings and reduce double-buffer memory designs. Also detailed are the difficulties and algorithmic solutions involved in FFT lengths up to 4 megasamples (Msamples) and sample rates up to 80 MHz.
Fourier-transform microwave spectroscopy of dimethyl-substituted Criegee intermediate (CH3)2COO.
Nakajima, Masakazu; Endo, Yasuki
2016-12-28
Pure rotational transitions of the dimethyl-substituted Criegee intermediate (dimethyl carbonyl oxide, acetone oxide), (CH3)2COO, were observed in the discharge plasma of a C(CH3)2I2/O2 gas mixture by Fourier-transform microwave spectroscopy. The observed spectra show small splittings due to the internal rotations of the two methyl groups. Precise rotational constants of the molecule and the barrier heights of the methyl internal rotations were experimentally determined.
Estimating Granger causality from fourier and wavelet transforms of time series data.
Dhamala, Mukeshwar; Rangarajan, Govindan; Ding, Mingzhou
2008-01-11
Experiments in many fields of science and engineering yield data in the form of time series. The Fourier and wavelet transform-based nonparametric methods are used widely to study the spectral characteristics of these time series data. Here, we extend the framework of nonparametric spectral methods to include the estimation of Granger causality spectra for assessing directional influences. We illustrate the utility of the proposed methods using synthetic data from network models consisting of interacting dynamical systems.
Magnetic imaging by Fourier transform holography using linearly polarized x-rays.
Sacchi, Maurizio; Popescu, Horia; Jaouen, Nicolas; Tortarolo, Marina; Fortuna, Franck; Delaunay, Renaud; Spezzani, Carlo
2012-04-23
We present a method for imaging magnetic domains via x-ray Fourier transform holography at linearly polarized sources. Our approach is based on the separation of holographic mask and sample and on the Faraday rotation induced on the reference wave. We compare images of perpendicular magnetic domains obtained with either linearly or circularly polarized x-rays and discuss the relevance of this method to future experiments at free-electron laser and high-harmonic-generation sources.
Second-Generation Discrete Fourier Transform Signal Processor for Laser Velocimetry
1986-12-01
AEDC-TR-86-33 C.7- eAR 0 0 1987 Second- Generation Discrete Fourier Transform Signal Processor for Laser Velocimetry Thomas Chris Layne Calspan...available to the general public, including foreign nations. APPROVAL STATEMENT This report has been reviewed and approved. ROBERT W. SMITH...IFIFI) SECURITY CLASSIFICATION OF THIS PAGE UNCLASSIFIED SECURITY C L ~ S I F I C A T I O N OF THIS PAGE 11. TITLE Second- Generation Discrete
Study of supermolecular structure by optical fourier transforms of scattered-light patterns
Gudkov, V.A.
1992-02-01
A method for decoding of the supermolecular structure of condensed media (polymers, liquid crystals, solids, etc.) is described that consists of optical Fourier transforms of scattered-light patterns by Fraunhofer diffraction. It is shown by the example of polyethylene films that the method makes it possible to determine macrostructure elements and the nature of their mutual arrangement, which allows it to be used in a production technology for materials with specified properties. 7 refs., 4 figs.
Metabolic fingerprinting of lichen Usnea baileyi by Fourier transform infrared spectroscopy
NASA Astrophysics Data System (ADS)
Bakar, Siti Zaharah Abu; Latip, Jalifah; bin Din, Laily; Samsuddin, Mohd Wahid
2014-09-01
The lichen Usnea baileyi collected from different environments was characterised using Fourier transform infrared spectroscopy. This preliminary study was done to determine the effects of different environment populations on U. baileyi chemical composition. Results showed that the absorbance peaks of Golf Course 2 (GCU2) are more intense compared to Taman Awana (TA), Jalan Awana (JA) and Jalan Gohtong (JG). U. baileyi contains of dibenzofurans, depsides, depsidones, xanthones and terpenoids.
NASA Technical Reports Server (NTRS)
Lyubashevskiy, G. S.
1973-01-01
Fourier processing of automatic signals transforms direct current voltage into a numerical form through bandpass filtration in time-pulse multiplying devices. It is shown that the ratio of the interference energy to the useful signal energy is inversely proportional to the square of the product of the depth of the width modulation and the ratio of the time constant averaging to the cross-multiplied signals.
A Fast Fourier transform stochastic analysis of the contaminant transport problem
Deng, F.W.; Cushman, J.H.; Delleur, J.W.
1993-01-01
A three-dimensional stochastic analysis of the contaminant transport problem is developed in the spirit of Naff (1990). The new derivation is more general and simpler than previous analysis. The fast Fourier transformation is used extensively to obtain numerical estimates of the mean concentration and various spatial moments. Data from both the Borden and Cape Cod experiments are used to test the methodology. Results are comparable to results obtained by other methods, and to the experiments themselves.
Ozaktas, Haldun M; Arık, Sercan Ö; Coşkun, Türker
2011-07-01
Fresnel integrals corresponding to different distances can be interpreted as scaled fractional Fourier transformations observed on spherical reference surfaces. We show that by judiciously choosing sample points on these curved reference surfaces, it is possible to represent the diffracted signals in a nonredundant manner. The change in sample spacing with distance reflects the structure of Fresnel diffraction. This sampling grid also provides a simple and robust basis for accurate and efficient computation, which naturally handles the challenges of sampling chirplike kernels.
Toney, M.L.
1999-07-01
The purpose of this testing program is to obtain uncontrolled and controlled hydrogen chloride (HCl) and speciated hydrocarbon Hazardous Air Pollutants (HAPs) emissions data from lime production plants to support a national emission standard for hazardous air pollutants (NESHAP). This report presents data from the Fourier Transform Infrared Spectroscopy (FTIR) measurements. FTIR source testing was conducted for the following purposes: Quantify HCl emission levels; and Gather screening (i.e., qualitative) data on other HAP emissions.
Jing, Juan-Juan; Zhou, Jin-Song; Xiangli, Bin; Lü, Qun-Bo; Wei, Ru-Yi
2010-06-01
The principle of reflecting rotating Fourier transform spectrometer was introduced in the present paper. The nonlinear problem of optical path difference (OPD) of rotating Fourier transform spectrometer universally exists, produced by the rotation of rotating mirror. The nonlinear OPD will lead to fictitious recovery spectrum, so it is necessary to compensate the nonlinear OPD. Three methods of correction for the nonlinear OPD were described and compared in this paper, namely NUFFT method, OPD replace method and interferograms fitting method. The result indicates that NUFFT was the best method for the compensation of nonlinear OPD, OPD replace method was better, its precision was almost the same as NUFFT method, and their relative error are superior to 0.13%, but the computation efficiency of OPD replace method is slower than NUFFT method, while the precision and computation efficiency of interferograms fitting method are not so satisfied, because the interferograms are rapid fluctuant especially around the zero optical path difference, so it is unsuitable for polynomial fitting, and because this method needs piecewise fitting, its computation efficiency is the slowest, thus the NUFFT method is the most suited method for the nonlinear OPD compensation of reflecting rotating Fourier transform spectrometer.
The parallel implementation of the one-dimensional Fourier transformed Vlasov Poisson system
NASA Astrophysics Data System (ADS)
Eliasson, Bengt
2005-08-01
A parallel implementation of an algorithm for solving the one-dimensional, Fourier transformed Vlasov-Poisson system of equations is documented, together with the code structure, file formats and settings to run the code. The properties of the Fourier transformed Vlasov-Poisson system is discussed in connection with the numerical solution of the system. The Fourier method in velocity space is used to treat numerical problems arising due the filamentation of the solution in velocity space. Outflow boundary conditions in the Fourier transformed velocity space removes the highest oscillations in velocity space. A fourth-order compact Padé scheme is used to calculate derivatives in the Fourier transformed velocity space, and spatial derivatives are calculated with a pseudo-spectral method. The parallel algorithms used are described in more detail, in particular the parallel solver of the tri-diagonal systems occurring in the Padé scheme. Program summaryTitle of program:vlasov Catalogue identifier:ADVQ Program summary URL:http://cpc.cs.qub.ac.uk/summaries/ADVQ Program obtainable from: CPC Program Library, Queen's University of Belfast, N. Ireland Operating system under which the program has been tested: Sun Solaris; HP-UX; Read Hat Linux Programming language used: FORTRAN 90 with Message Passing Interface (MPI) Computers: Sun Ultra Sparc; HP 9000/785; HP IPF (Itanium Processor Family) ia64 Cluster; PCs cluster Number of lines in distributed program, including test data, etc.:3737 Number of bytes in distributed program, including test data, etc.:18 772 Distribution format: tar.gz Nature of physical problem: Kinetic simulations of collisionless electron-ion plasmas. Method of solution: A Fourier method in velocity space, a pseudo-spectral method in space and a fourth-order Runge-Kutta scheme in time. Memory required to execute with typical data: Uses typically of the order 10 5-10 6 double precision numbers. Restriction on the complexity of the problem: The program uses
NASA Astrophysics Data System (ADS)
Carlysle, Felicity; Nic Daeid, Niamh; Normand, Erwan; McCulloch, Michael
2012-10-01
Fourier Transform infrared spectroscopy (FTIR) is regularly used in forensic analysis, however the application of high resolution Fourier Transform infrared spectroscopy for the detection of explosive materials and explosive precursors has not been fully explored. This project aimed to develop systematically a protocol for the analysis of explosives and precursors using Fourier Transform infrared spectroscopy and basic data analysis to enable the further development of a quantum cascade laser (QCL) based airport detection system. This paper details the development of the protocol and results of the initial analysis of compounds of interest.
A Fourier transform method for Vsin i estimations under nonlinear Limb-Darkening laws
Levenhagen, R. S.
2014-12-10
Star rotation offers us a large horizon for the study of many important physical issues pertaining to stellar evolution. Currently, four methods are widely used to infer rotation velocities, namely those related to line width calibrations, on the fitting of synthetic spectra, interferometry, and on Fourier transforms (FTs) of line profiles. Almost all of the estimations of stellar projected rotation velocities using the Fourier method in the literature have been addressed with the use of linear limb-darkening (LD) approximations during the evaluation of rotation profiles and their cosine FTs, which in certain cases, lead to discrepant velocity estimates. In this work, we introduce new mathematical expressions of rotation profiles and their Fourier cosine transforms assuming three nonlinear LD laws—quadratic, square-root, and logarithmic—and study their applications with and without gravity-darkening (GD) and geometrical flattening (GF) effects. Through an analysis of He I models in the visible range accounting for both limb and GD, we find out that, for classical models without rotationally driven effects, all the Vsin i values are too close to each other. On the other hand, taking into account GD and GF, the Vsin i obtained with the linear law result in Vsin i values that are systematically smaller than those obtained with the other laws. As a rule of thumb, we apply these expressions to the FT method to evaluate the projected rotation velocity of the emission B-type star Achernar (α Eri).
A Fourier Transform Method for Vsin i Estimations under Nonlinear Limb-darkening Laws
NASA Astrophysics Data System (ADS)
Levenhagen, R. S.
2014-12-01
Star rotation offers us a large horizon for the study of many important physical issues pertaining to stellar evolution. Currently, four methods are widely used to infer rotation velocities, namely those related to line width calibrations, on the fitting of synthetic spectra, interferometry, and on Fourier transforms (FTs) of line profiles. Almost all of the estimations of stellar projected rotation velocities using the Fourier method in the literature have been addressed with the use of linear limb-darkening (LD) approximations during the evaluation of rotation profiles and their cosine FTs, which in certain cases, lead to discrepant velocity estimates. In this work, we introduce new mathematical expressions of rotation profiles and their Fourier cosine transforms assuming three nonlinear LD laws—quadratic, square-root, and logarithmic—and study their applications with and without gravity-darkening (GD) and geometrical flattening (GF) effects. Through an analysis of He I models in the visible range accounting for both limb and GD, we find out that, for classical models without rotationally driven effects, all the Vsin i values are too close to each other. On the other hand, taking into account GD and GF, the Vsin i obtained with the linear law result in Vsin i values that are systematically smaller than those obtained with the other laws. As a rule of thumb, we apply these expressions to the FT method to evaluate the projected rotation velocity of the emission B-type star Achernar (α Eri).
Subpixel shift with Fourier transform to achieve efficient and high-quality image interpolation
NASA Astrophysics Data System (ADS)
Chen, Qin-Sheng; Weinhous, Martin S.
1999-05-01
A new approach to image interpolation is proposed. Different from the conventional scheme, the interpolation of a digital image is achieved with a sub-unity coordinate shift technique. In the approach, the original image is first shifted by sub-unity distances matching the locations where the image values need to be restored. The original and the shifted images are then interspersed together, yielding an interpolated image. High quality sub-unity image shift which is crucial to the approach is accomplished by implementing the shift theorem of Fourier transformation. It is well known that under the Nyquist sampling criterion, the most accurate image interpolation can be achieved with the interpolating function (sinc function). A major drawback is its computation efficiency. The present approach can achieve an interpolation quality as good as that with the sinc function since the sub-unity shift in Fourier domain is equivalent to shifting the sinc function in spatial domain, while the efficiency, thanks to the fast Fourier transform, is very much improved. In comparison to the conventional interpolation techniques such as linear or cubic B-spline interpolation, the interpolation accuracy is significantly enhanced. In order to compensate for the under-sampling effects in the interpolation of 3D medical images owing to a larger inter-slice distance, proper window functions were recommended. The application of the approach to 2- and 3-D CT and MRI images produced satisfactory interpolation results.
Suzuki, M.; Isogami, S.; Tsunoda, M.; Takahashi, S.; Ishio, S.
2011-09-09
We present a fabrication method for a reference source that is efficient when used for lensless Fourier transform holography. This method produces a reference source that yields high spatial resolution and enhanced signal-to-noise ratio in a Fourier-transformed real-space image, and is particularly useful for Fourier transform holography experiments in the hard x-ray region.
Digital watermarking algorithm research of color images based on quaternion Fourier transform
NASA Astrophysics Data System (ADS)
An, Mali; Wang, Weijiang; Zhao, Zhen
2013-10-01
A watermarking algorithm of color images based on the quaternion Fourier Transform (QFFT) and improved quantization index algorithm (QIM) is proposed in this paper. The original image is transformed by QFFT, the watermark image is processed by compression and quantization coding, and then the processed watermark image is embedded into the components of the transformed original image. It achieves embedding and blind extraction of the watermark image. The experimental results show that the watermarking algorithm based on the improved QIM algorithm with distortion compensation achieves a good tradeoff between invisibility and robustness, and better robustness for the attacks of Gaussian noises, salt and pepper noises, JPEG compression, cropping, filtering and image enhancement than the traditional QIM algorithm.
Zarnowiec, Paulina; Lechowicz, Łukasz; Czerwonka, Grzegorz; Kaca, Wiesław
2015-01-01
Methods of human bacterial pathogen identification need to be fast, reliable, inexpensive, and time efficient. These requirements may be met by vibrational spectroscopic techniques. The method that is most often used for bacterial detection and identification is Fourier transform infrared spectroscopy (FTIR). It enables biochemical scans of whole bacterial cells or parts thereof at infrared frequencies (4,000-600 cm(-1)). The recorded spectra must be subsequently transformed in order to minimize data variability and to amplify the chemically-based spectral differences in order to facilitate spectra interpretation and analysis. In the next step, the transformed spectra are analyzed by data reduction tools, regression techniques, and classification methods. Chemometric analysis of FTIR spectra is a basic technique for discriminating between bacteria at the genus, species, and clonal levels. Examples of bacterial pathogen identification and methods of differentiation up to the clonal level, based on infrared spectroscopy, are presented below.
A new iterative Fourier transform algorithm for optimal design in holographic optical tweezers
NASA Astrophysics Data System (ADS)
Memmolo, P.; Miccio, L.; Merola, F.; Ferraro, P.; Netti, P. A.
2012-06-01
We propose a new Iterative Fourier Transform Algorithm (IFTA) capable to suppress ghost traps and noise in Holographic Optical Tweezers (HOT), maintaining a high diffraction efficiency in a computational time comparable with the others iterative algorithms. The process consists in the planning of the suitable ideal target of optical tweezers as input of classical IFTA and we show we are able to design up to 4 real traps, in the field of view imaged by the microscope objective, using an IFTA built on fictitious phasors, located in strategic positions in the Fourier plane. The effectiveness of the proposed algorithm is evaluated both for numerical and optical reconstructions and compared with the other techniques known in literature.
Asymmetric multiple-image encryption based on the cascaded fractional Fourier transform
NASA Astrophysics Data System (ADS)
Li, Yanbin; Zhang, Feng; Li, Yuanchao; Tao, Ran
2015-09-01
A multiple-image cryptosystem is proposed based on the cascaded fractional Fourier transform. During an encryption procedure, each of the original images is directly separated into two phase masks. A portion of the masks is subsequently modulated into an interim mask, which is encrypted into the ciphertext image; the others are used as the encryption keys. Using phase truncation in the fractional Fourier domain, one can use an asymmetric cryptosystem to produce a real-valued noise-like ciphertext, while a legal user can reconstruct all of the original images using a different group of phase masks. The encryption key is an indivisible part of the corresponding original image and is still useful during decryption. The proposed system has high resistance to various potential attacks, including the chosen-plaintext attack. Numerical simulations also demonstrate the security and feasibility of the proposed scheme.
Precise measurement of the resolution in light microscopy using Fourier transform
Vainrub, Arnold
2008-04-15
The resolution power of light microscope has been accurately measured ({+-}5%) by Fourier transform of various object images and further evaluation of the highest spatial frequency in Fourier spectrum. Any unknown shape plane object with a shape feature's size smaller than the resolution to be measured was shown to provide a reliable resolution test. This simple method gives a direct measurement of the resolution power as defined by Abbe [Archiv. F. Mikroskopische Anat. 9, 413 (1873)]. The results have been justified by comparison to a standard resolution measurement by using calibrated periodic line patterns. Notably, the approach is applicable in super-resolution light microscopy (transmission, reflection, and fluorescence), where calibrated resolution targets do not occur. It was conveniently implemented by using a compact disk as a test object and free IMAGEJ imaging software.
Compact standing-wave Fourier-transform interferometer with harmonic spectral analysis
NASA Astrophysics Data System (ADS)
Fu, Junxian; Yu, Xiaojun; Zhang, Bingyang; Harris, James S., Jr.
2006-02-01
A new technique utilizing harmonic Fourier spectra created by the non-linear properties of a compact Fourier transform infrared interferometer (FTIR) was proposed and realized to improve the system resolution. The compact standing wave FTIR (SWFTIR) system consists of a partial transparent hetero-junction bipolar phototransistor (HPT) and a free scanning highly reflective mirror. The overall size of the system is less than 5×5×5cm 3, and the resolution at 1.5μm is better than 37.5cm -1 at the 5 th harmonic spectral component. The SWFTIR array system has theoretical resolution of better than 1cm -1 covering the whole near-infrared region with potential compact portable applications.
Strain analysis by mismatch moire method and grid method using Fourier transform
NASA Astrophysics Data System (ADS)
Morimoto, Y.; Seguchi, Y.; Higashi, T.
1990-01-01
We have formerly presented a new method of the moire analysis of strain using the Fourier transform. It uses the phase information of the moire fringe brightness. By shifting the Fourier spectrum of the image of deformed grating lines, we obtain the “complex moire pattern”. Strain distribution is given as the derivatives of the phases of the complex moire fringes. The analysis is completely automated by digital image processing. All of the laborious and subjective procedures required in the conventional analysis such as fringe sign determination, fringe ordering and fringe interpolation are thus eliminated, and objective, fast and accurate analysis can be made. In this paper, we develop the method to a mismatch method and a grid method. We show some applications for analyzing strain distribution by using this method.
A portable Fourier transform infrared gas analyzer with a photoacoustic detector performed reliably during pollution prevention research at two industrial facilities. It exhibited good agreement (within approximately 6%) with other analytical instruments (dispersive infrared and ...
NASA Astrophysics Data System (ADS)
Nourazar, S. S.; Nazari-Golshan, A.
2015-01-01
A hybrid of Fourier transform and new modified homotopy perturbation method based on the Adomian method is developed to solve linear and nonlinear partial differential equations. The Taylor series expansion is used to expand nonlinear term of partial differential equation and the Adomian polynomial incorporated into homotopy perturbation method combined with Fourier transform, is used to solve partial differential equations. Three case study problems, partial differential equations, are handled using homotopy perturbation method and Fourier transform modified homotopy perturbation method (FTMHPM). Results obtained are compared with exact solution. The comparison reveals that for same components of recursive sequences, errors associated with Fourier transform modified method are much less than the other and are valid for a large range of x-axis coordinates.
Technology Transfer Automated Retrieval System (TEKTRAN)
Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...
Rice, S.B.; Freund, H.; Huang, W.L.; Clouse, J.A.; Isaacs, C.M.
1995-10-02
An important goal in silica diagenesis research is to understand the kinetics of opal transformation from noncrystalline opal-A to the disordered silica polymorph opal-CT. Because the conventional technique for monitoring the transformation, powder X-ray diffraction (XRD), is applicable only to phases with long-range order, the authors used Fourier transform infrared spectroscopy (FTIR) to monitor the transformation. They applied this technique, combined with XRD and TEM, to experimental run products and natural opals from the Monterey Formation and from siliceous deposits in the western Pacific Ocean. Using a ratio of two infrared absorption intensities ({omega} = I{sub 472 cm{sup {minus}1}}/I{sub 500 cm{sup {minus}1}}), the relative proportions of opal-A and opal-CT can be determined. The progress of the transformation is marked by changes in slope of {omega} vs. depth or time when a sufficient stratigraphic profile is available. There are three stages in the opal-A to opal-CT reaction: (1) opal-A dissolution; (2) opal-CT precipitation, whose end point is marked by completion of opal-A dissolution; and (3) opal-CT ordering, during which tridymite stacking is eliminated in favor of crystobalite stacking.
Content measurement of textile mixture by Fourier transform near infrared spectroscopy
NASA Astrophysics Data System (ADS)
Liu, Li; Yan, Li; Xie, Yaocheng; Li, Songzhang; Xia, Ge; Zhou, Libin
2009-11-01
A new method for accurate measurement of content of textile mixture based on Fourier transform near infrared spectroscopy is put forward. The near infrared spectra of 56 samples with different cotton and polyester contents were obtained, in which 41 samples, 10 samples and 5 samples were used for the calibration set, validation set and prediction set respectively. The wavelet transform (WT) was utilized for the spectra data compression. From the linear and nonlinear perspective, multivariable linear regression (MLR) model based on the Lambert - Beer's law and back propagation (BP) neural network model based on WT were developed. It indicates that the prediction accuracy of WT-ca3-BP network model is 2% for calibration sample and 4% for validation sample, which is much higher than the MLR model and is suitable for the prediction of unknown samples. On the basis of not changing the structure of the WT-ca3-BP network model, calibration and validation samples were utilized fully to be re-set to new calibration samples, which upgraded this model. The upgraded WT-ca3-BP network model was applied to predict unknown samples. Experimental results show that this approach based on Fourier transform Near Infrared Spectroscopy can be used to quantitative analysis for textile fiber.
[The meteorological satellite spectral image registration based on Fourier-Mellin transform].
Wang, Liang; Liu, Rong; Zhang, Li; Duan, Fu-Qing; Lü, Ke
2013-03-01
The meteorological satellite spectral image is an effective tool for researches on meteorological science and environmental remote sensing science. Image registration is the basis for the application of the meteorological satellite spectral image data. In order to realize the registration of the satellite image and the template image, a new registration method based on the Fourier-Mellin transform is presented in this paper. Firstly, we use the global coastline vector map data to build a landmark template, which is a reference for the meteorological satellite spectral image registration. Secondly, we choose infrared sub-image of no cloud according to the cloud channel data, and extract the edges of the infrared image by Sobel operator. Finally, the affine transform model parameters between the landmark template and the satellite image are determined by the Fourier-Mellin transform, and thus the registration is realized. The proposed method is based on the curve matching in essence. It needs no feature point extraction, and can greatly simplify the process of registration. The experimental results using the infrared spectral data of the FY-2D meteorological satellite show that the method is robust and can reach a high speed and high accuracy.
Kamalian, Morteza; Prilepsky, Jaroslaw E; Le, Son Thai; Turitsyn, Sergei K
2016-08-08
In this work, we introduce the periodic nonlinear Fourier transform (PNFT) method as an alternative and efficacious tool for compensation of the nonlinear transmission effects in optical fiber links. In the Part I, we introduce the algorithmic platform of the technique, describing in details the direct and inverse PNFT operations, also known as the inverse scattering transform for periodic (in time variable) nonlinear Schrödinger equation (NLSE). We pay a special attention to explaining the potential advantages of the PNFT-based processing over the previously studied nonlinear Fourier transform (NFT) based methods. Further, we elucidate the issue of the numerical PNFT computation: we compare the performance of four known numerical methods applicable for the calculation of nonlinear spectral data (the direct PNFT), in particular, taking the main spectrum (utilized further in Part II for the modulation and transmission) associated with some simple example waveforms as the quality indicator for each method. We show that the Ablowitz-Ladik discretization approach for the direct PNFT provides the best performance in terms of the accuracy and computational time consumption.
NASA Astrophysics Data System (ADS)
Zhang, Leihong; Liang, Dong; Li, Bei; Kang, Yi; Pan, Zilan; Zhang, Dawei; Gao, Xiumin; Ma, Xiuhua
2016-07-01
On the basis of analyzing the cosine light field with determined analytic expression and the pseudo-inverse method, the object is illuminated by a presetting light field with a determined discrete Fourier transform measurement matrix, and the object image is reconstructed by the pseudo-inverse method. The analytic expression of the algorithm of computational ghost imaging based on discrete Fourier transform measurement matrix is deduced theoretically, and compared with the algorithm of compressive computational ghost imaging based on random measurement matrix. The reconstruction process and the reconstruction error are analyzed. On this basis, the simulation is done to verify the theoretical analysis. When the sampling measurement number is similar to the number of object pixel, the rank of discrete Fourier transform matrix is the same as the one of the random measurement matrix, the PSNR of the reconstruction image of FGI algorithm and PGI algorithm are similar, the reconstruction error of the traditional CGI algorithm is lower than that of reconstruction image based on FGI algorithm and PGI algorithm. As the decreasing of the number of sampling measurement, the PSNR of reconstruction image based on FGI algorithm decreases slowly, and the PSNR of reconstruction image based on PGI algorithm and CGI algorithm decreases sharply. The reconstruction time of FGI algorithm is lower than that of other algorithms and is not affected by the number of sampling measurement. The FGI algorithm can effectively filter out the random white noise through a low-pass filter and realize the reconstruction denoising which has a higher denoising capability than that of the CGI algorithm. The FGI algorithm can improve the reconstruction accuracy and the reconstruction speed of computational ghost imaging.
Slit Function Measurement of An Imaging Spectrograph Using Fourier Transform Techniques
NASA Technical Reports Server (NTRS)
Park, Hongwoo; Swimyard, Bruce; Jakobsen, Peter; Moseley, Harvey; Greenhouse, Matthew
2004-01-01
Knowledge of a spectrograph slit function is necessary to interpret the unresolved lines in an observed spectrum. A theoretical slit function can be calculated from the sizes of the entrance slit, the detector aperture when it functions as an exit slit, the dispersion characteristic of the disperser, and the point spread function of the spectrograph. A measured slit function is preferred to the theoretical one for the correct interpretation of the spectral data. In a scanning spectrometer with a single exit slit, the slit function is easily measured. In a fixed grating/or disperser spectrograph, illuminating the entrance slit with a near monochromatic light from a pre-monochrmator or a tunable laser and varying the wavelength of the incident light can measure the slit function. Even though the latter technique had been used successfully for the slit function measurements, it had been very laborious and it would be prohibitive to an imaging spectrograph or a multi-object spectrograph that has a large field of view. We explore an alternative technique that is manageable for the measurements. In the proposed technique, the imaging spectrograph is used as a detector of a Fourier transform spectrometer. This method can be applied not only to an IR spectrograph but also has a potential to a visible/UV spectrograph including a wedge filter spectrograph. This technique will require a blackbody source of known temperature and a bolometer to characterize the interferometer part of the Fourier Transform spectrometer. This pa?er will describe the alternative slit function measurement technique using a Fourier transform spectrometer.
Parameter estimation of optical fringes with quadratic phase using the fractional Fourier transform
NASA Astrophysics Data System (ADS)
Lu, Ming-Feng; Zhang, Feng; Tao, Ran; Ni, Guo-Qiang; Bai, Ting-Zhu; Yang, Wen-Ming
2015-11-01
Optical fringes with a quadratic phase are often encountered in optical metrology. Parameter estimation of such fringes plays an important role in interferometric measurements. A novel method is proposed for accurate and direct parameter estimation using the fractional Fourier transform (FRFT), even in the presence of noise and obstacles. We take Newton's rings fringe patterns and electronic speckle pattern interferometry (ESPI) interferograms as classic examples of optical fringes that have a quadratic phase and present simulation and experimental results demonstrating the performance of the proposed method.
NASA Astrophysics Data System (ADS)
Shen, Fabin; Wang, Anbo
2006-02-01
The numerical calculation of the Rayleigh-Sommerfeld diffraction integral is investigated. The implementation of a fast-Fourier-transform (FFT) based direct integration (FFT-DI) method is presented, and Simpson's rule is used to improve the calculation accuracy. The sampling interval, the size of the computation window, and their influence on numerical accuracy and on computational complexity are discussed for the FFT-DI and the FFT-based angular spectrum (FFT-AS) methods. The performance of the FFT-DI method is verified by numerical simulation and compared with that of the FFT-AS method.
Radar cross-section reduction based on an iterative fast Fourier transform optimized metasurface
NASA Astrophysics Data System (ADS)
Song, Yi-Chuan; Ding, Jun; Guo, Chen-Jiang; Ren, Yu-Hui; Zhang, Jia-Kai
2016-07-01
A novel polarization insensitive metasurface with over 25 dB monostatic radar cross-section (RCS) reduction is introduced. The proposed metasurface is comprised of carefully arranged unit cells with spatially varied dimension, which enables approximate uniform diffusion of incoming electromagnetic (EM) energy and reduces the threat from bistatic radar system. An iterative fast Fourier transform (FFT) method for conventional antenna array pattern synthesis is innovatively applied to find the best unit cell geometry parameter arrangement. Finally, a metasurface sample is fabricated and tested to validate RCS reduction behavior predicted by full wave simulation software Ansys HFSSTM and marvelous agreement is observed.
Fourier transform C-13 NMR analysis of some free and potassium-ion complexed antibiotics.
NASA Technical Reports Server (NTRS)
Ohnishi, M.; Fedarko, M.-C.; Baldeschwieler, J. D.; Johnson, L. F.
1972-01-01
Fourier transforms of the noise-decoupled, natural abundance C-13 NMR free induction decays of the cyclic antibiotic valinomycin and its potassium-ion complex have been obtained at 25.2 MHz. Comparisons are made with C-13 NMR spectra taken at 22.6 MHz of the cyclic antibiotic nonactin and the synthetic polyether dicyclohexyl-18-crown-6 and their potassium complexes. The results obtained suggest that conformational rearrangements of the molecule as a whole can compete with direct interactions between carbons and the potassium ion in determining C-13 chemical shift differences between the free and complexed species.
Waveguide Chirped-Pulse Fourier Transform Microwave Spectroscopy of 1-PROPANETHIOL
NASA Astrophysics Data System (ADS)
Gordon, Brittany P.; Shipman, Steven T.
2013-06-01
The rotational spectrum of 1-propanethiol was measured from 8.7 to 26.5 GHz at 250 K with a waveguide chirped-pulse Fourier transform microwave spectrometer. This thiol has a dense spectrum containing contributions from multiple conformers, excited vibrational states, and singly-substituted isotopomers (^{34}S and ^{13}C) in natural abundance. Further, the spectrum shows complications due to the presence of internal rotation. Despite this complexity, some progress has been made, and preliminary work on this molecule will be presented.
Chirped-Pulse Fourier Transform Microwave Spectroscopy of Meta-Chlorobenzaldehyde
NASA Astrophysics Data System (ADS)
Arnold, Sean T.; Garrett, Jessica A.; Brown, Gordon G.
2013-06-01
The pure rotational spectrum of meta-chlorobenzaldehyde (m-ClBA) has been measured from 8 - 18.5 GHz by chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy. The spectrum has been analyzed to discover the presence of two conformations of m-ClBA in the free jet expansion. For each conformation the rotational constants, the centrifugal distortion constants, and the nuclear quadrupole coupling constants have been found for both the ^{35}Cl and the ^{37}Cl isotopologue. The rotational constants and the nuclear quadrupole coupling constants have been compared to ab initio calculations performed using the Gaussian 03W software package.
NASA Technical Reports Server (NTRS)
Smillie, D. G.; Pickering, J. C.; Blackwell-Whitehead, R. J.; Smith, Peter L.; Nave, G.
2006-01-01
We report new measurements of doubly ionized iron group element spectra, important in the analysis of B-type (hot) stars whose spectra they dominate. These measurements include Co III and Cr III taken with the Imperial College VUV Fourier transform (FT) spectrometer and measurements of Co III taken with the normal incidence vacuum spectrograph at NIST, below 135 nm. We report new Fe III grating spectra measurements to complement our FT spectra. Work towards transition wavelengths, energy levels and branching ratios (which, combined with lifetimes, produce oscillator strengths) for these ions is underway.
Li, Jianxin; Bai, Caixun; Shen, Yan; Xu, Donglei
2016-11-15
We present an optical path squeezing interferometer dedicated to high-spectral-resolution Fourier transform imaging spectrometry. By incorporating a pair of gratings into a Sagnac interferometer, the short-wavelength light has a larger optical path difference (OPD) than the long-wavelength light. Interference fringes with different OPDs are squeezed into the same sampling window in data acquisition. As a result, the spectral resolution is greatly enhanced without large OPD scanning. The experimental results demonstrate that the proposed method is a promising technology for high-resolution spectral imaging.
NASA Astrophysics Data System (ADS)
Guangzhao, Zhang; Guangqun, Zhou
1989-02-01
The Marple algorthm for the autoregressive spectral estimates has been applied to the SMMW Fourier transform spectrum analysis. The experimental results have shown that this method yields AR spectra with three times higher resolution than the FFT method does. The improvements obtained from the Marple algorithm over the maximum entropy algorithm include higher resolution, less bias in the spectral peak frequency estimation and absence of observed spectral line splitting. The effects of the structure of the spectral lines and the noise on the resolution are discussed.
Fourier-transform microwave spectroscopy of a halogen substituted Criegee intermediate ClCHOO
NASA Astrophysics Data System (ADS)
Cabezas, Carlos; Guillemin, Jean-Claude; Endo, Yasuki
2016-11-01
Pure rotational spectra of the chloro-substituted Criegee intermediate (ClCHOO) were observed by Fourier-transform microwave spectroscopy. Two conformers (syn and anti) of the isolated molecule were identified from the rotational spectra of the parent and 37Cl and 13C isotopologues detected in natural abundance. Rotational constants, centrifugal distortion constants, and all components of the nuclear quadrupole coupling tensor were determined for both conformers. Structural features of the molecule have been rationalized with supporting ab initio calculations and the natural bond orbital analysis, which suggest that the conformational preferences are driven by hyperconjugative effects.
Fourier-transform microwave spectroscopy of a halogen substituted Criegee intermediate ClCHOO.
Cabezas, Carlos; Guillemin, Jean-Claude; Endo, Yasuki
2016-11-14
Pure rotational spectra of the chloro-substituted Criegee intermediate (ClCHOO) were observed by Fourier-transform microwave spectroscopy. Two conformers (syn and anti) of the isolated molecule were identified from the rotational spectra of the parent and (37)Cl and (13)C isotopologues detected in natural abundance. Rotational constants, centrifugal distortion constants, and all components of the nuclear quadrupole coupling tensor were determined for both conformers. Structural features of the molecule have been rationalized with supporting ab initio calculations and the natural bond orbital analysis, which suggest that the conformational preferences are driven by hyperconjugative effects.
Fourier-transform microwave spectroscopy of an alkyl substituted Criegee intermediate anti-CH3CHOO
NASA Astrophysics Data System (ADS)
Nakajima, Masakazu; Yue, Qiang; Endo, Yasuki
2015-04-01
Pure rotational transitions of the anti-form of the simplest alkyl-substituted Criegee intermediate, anti-CH3CHOO, were observed by Fourier-transform microwave spectroscopy. The observed transition frequencies in the A and E levels of the ground vibrational state were analyzed together, and molecular constants including parameters which characterize the internal rotation of the methyl rotor were determined. The experimentally determined barrier height of the three-fold potential for the methyl internal rotation is 399.1 cm-1, less than a half of that of the other conformer, syn-CH3CHOO (Nakajima and Endo, 2014).
NASA Technical Reports Server (NTRS)
Beecken, Brian P.; Kleinman, Randall R.
2004-01-01
New developments in infrared sensor technology have potentially made possible a new space-based system which can measure far-infrared radiation at lower costs (mass, power and expense). The Stationary Imaging Fourier Transform Spectrometer (SIFTS) proposed by NASA Langley Research Center, makes use of new detector array technology. A mathematical model which simulates resolution and spectral range relationships has been developed for analyzing the utility of such a radically new approach to spectroscopy. Calculations with this forward model emulate the effects of a detector array on the ability to retrieve accurate spectral features. Initial computations indicate significant attenuation at high wavenumbers.
Schoonover, J R; Steckle, Jr., W P; Elliot, N; Ebey, P S; Nobile, A; Nikroo, A; Cook, R C; Letts, S A
2005-06-16
Planar samples of varying thicknesses of both CH and CD glow discharge polymer have been measured with Fourier transform infrared (FTIR) spectroscopy before and after exposure to deuterium-tritium (DT) gas at elevated temperature and pressure. Planar samples of polyimide films made from both hydrogenated and deuterated precursors have also been examined by FTIR before and after DT exposure. The post-exposure FTIR spectra demonstrated no measurable exchange of hydrogen with deuterium or tritium for either polymer. Evidence for oxidation of the glow discharge polymer due to atmospheric oxygen was the only chemical change indicated by the FTIR data.
Ince-Gaussian series representation of the two-dimensional fractional Fourier transform.
Bandres, Miguel A; Gutiérrez-Vega, Julio C
2005-03-01
We introduce the Ince-Gaussian series representation of the two-dimensional fractional Fourier transform in elliptical coordinates. A physical interpretation is provided in terms of field propagation in quadratic graded-index media whose eigenmodes in elliptical coordinates are derived for the first time to our knowledge. The kernel of the new series representation is expressed in terms of Ince-Gaussian functions. The equivalence among the Hermite-Gaussian, Laguerre-Gaussian, and Ince-Gaussian series representations is verified by establishing the relation among the three definitions.
NASA Astrophysics Data System (ADS)
Azour, Halima; Derouault, Jean; Lauroua, Pierre; Vezon, Gérard
2000-07-01
In order to remedy the limitations of state-of-the-art methods for red blood cells grouping and antibody screening we have tried to develop a new type of immunosensors based upon a metallic substrate. The first two steps of the manufacturing of such a sensor consist in the anodization and in the silanization of the metal surface. Fourier transform infrared spectroscopy (FTIR) has been used to investigate aluminum samples treated with the above process. FTIR analysis allows the accurate determination of the grafted species, and thus to perform the optimization of the experimental parameters.
Rheo-Optical Fourier-Transform Infrared Spectroscopy Of Polyamide Elastomers
NASA Astrophysics Data System (ADS)
Dekiert, S.; Siesler, H. W.; Lohmar, J.
1989-12-01
The potential of rhea-optical Fourier-Transform infrared (FTIR) spectroscopy is demonstrated with reference to the characterization of segmental orientation during cyclic elongation-recovery procedures of poly(ether-ester)amides based on chain-extended polyamide 12 (hard segments) and oligotetrahydrofuran (soft segments). The rheo-optical data show that the soft and hard segments deform by different orientation mechanisms. Thus, the soft segments exhibit positive chain alignment during loading and desorientation upon unloading. The deformation of the hard segments is characterized by an initial transverse orientation with a subsequent reorganization of their morphology.
Application of the two-dimensional Fourier transform scaling theorem to Dirac delta curves
NASA Astrophysics Data System (ADS)
Guizar-Sicairos, Manuel; Gutierrez-Vega, Julio C.
2005-08-01
We propose a Fourier transform scaling relation to find analytically, numerically and experimentally the spatial frequency spectrum of a two-dimensional Dirac delta curve from the spectrum of the non-scaled curve, after an arbitrary coordinate scaling. An amplitude factor is derived and given explicitly in terms of the scaling factors and the angle of the forward tangent at each point of the curve about the positive x axis. With this formulation we experimentally obtain the spectrum of an elliptic contour in a circular geometry, thus acquiring non-diffracting beam characteristics. Additionally we include the generalization to N-dimensional Dirac delta curves.
Planetary infrared astronomy using a cryogenic postdisperser on Fourier transform spectrometers
NASA Technical Reports Server (NTRS)
Jennings, D. E.; Kunde, V. G.; Hanel, R. A.; Maguire, W. C.; Lamb, G. M.
1986-01-01
High resolution infrared spectra of planets from ground-based observatories were analyzed and instrumentation to improve sensitivity was developed. A cryogenic postdisperser (a narrow bandpass spectral filter) for use with Fourier transform spectrometers (FTS's) at facility observatories was constructed. This instrument has improved the sensitivity of FTS observations at 8 to 20 microns by about an order of magnitude. Spectra of Jupiter, Saturn and Comet Halley were obtained using the postdisperser with FTS facilities at the Kitt Peak 4-meter and McMath telescopes. Spectral resolution as high as 0.01/cm was achieved.
Vehicle Classification Using the Discrete Fourier Transform with Traffic Inductive Sensors
Lamas-Seco, José J.; Castro, Paula M.; Dapena, Adriana; Vazquez-Araujo, Francisco J.
2015-01-01
Inductive Loop Detectors (ILDs) are the most commonly used sensors in traffic management systems. This paper shows that some spectral features extracted from the Fourier Transform (FT) of inductive signatures do not depend on the vehicle speed. Such a property is used to propose a novel method for vehicle classification based on only one signature acquired from a sensor single-loop, in contrast to standard methods using two sensor loops. Our proposal will be evaluated by means of real inductive signatures captured with our hardware prototype. PMID:26516855
Set-up for broadband Fourier-transform multidimensional electronic spectroscopy.
Al Haddad, A; Chauvet, A; Ojeda, J; Arrell, C; van Mourik, F; Auböck, G; Chergui, M
2015-02-01
We present a compact passively phase-stabilized ultra-broadband 2D Fourier transform setup. A gas (argon)-filled hollow core fiber pumped by an amplified Ti:Al2O3 laser is used as a light source providing spectral range spanning from 420 to 900 nm. Sub-10-fs pulses were obtained using a deformable mirror-based pulse shaper. We probe the nonlinear response of Rhodamine 101 using 90 nm bandwidth and resolve vibrational coherences of 150 fs period in the ground state.
NASA Technical Reports Server (NTRS)
Parsons, C. L.; Gerlach, J. C.; Whitehurst, M.
1982-01-01
The development of a prototype, ground-based, Sun-pointed Michelson interferometric spectrometer is described. Its intended use is to measure the atmospheric amount of various gases which absorb in the near-infrared, visible, and near-ultraviolet portions of the electromagnetic spectrum. Preliminary spectra which contain the alpha, 0.8 micrometer, and rho sigma tau water vapor absorption bands in the near-infrared are presented to indicate the present capability of the system. Ultimately, the spectrometer can be used to explore the feasible applications of Fourier transform spectroscopy in the ultraviolet where grating spectrometers were used exclusively.
Taylor, Samuel E.; Cao, Tuoxin; Talauliker, Pooja M.; Lifshitz, Jonathan
2016-01-01
Quantification of immunohistochemistry (IHC) and immunofluorescence (IF) using image intensity depends on a number of variables. These variables add a subjective complexity in keeping a standard within and between laboratories. Fast Fourier Transformation (FFT) algorithms, however, allow for a rapid and objective quantification (via statistical analysis) using cell morphologies when the microscopic structures are oriented or aligned. Quantification of alignment is given in terms of a ratio of FFT intensity to the intensity of an orthogonal angle, giving a numerical value of the alignment of the microscopic structures. This allows for a more objective analysis than alternative approaches, which rely upon relative intensities. PMID:27134700
Kim, Hwi; Yang, Byungchoon; Lee, Byoungho
2004-12-01
There is a trade-off between uniformity and diffraction efficiency in the design of diffractive optical elements. It is caused by the inherent ill-posedness of the design problem itself. For the optimal design, the optimum trade-off needs to be obtained. The trade-off between uniformity and diffraction efficiency in the design of diffractive optical elements is theoretically investigated based on the Tikhonov regularization theory. A novel scheme of an iterative Fourier transform algorithm with regularization to obtain the optimum trade-off is proposed.
NASA Astrophysics Data System (ADS)
Hettich, Robert L.; Jin, Changming; Compton, Robert N.; Buseck, Peter R.; Tsipursky, Semeon J.
1993-10-01
Fourier transform mass spectrometry (FTMS) employing both laser desorption/ionization and thermal desorption/electron ionization is useful for the detection and structural characterization of fullerenes and chemically-modified fullerenes. Examination of a carbon-rich shungite rock sample from Russia by transmission electron microscopy and FTMS provided evidence of naturally-occurring fullerenes. Ion-molecule reactions can be studied with FTMS to investigate the electron affinities of modified fullerenes. By monitoring charge exchange reactions, the electron affinities of C60Fx (x=44,46) and C70Fy (y=52,54) were found to be substantially higher than the values for the parent fullerenes.
Mao, Haidan; Du, Xinyue; Chen, Linfei; Zhao, Daomu
2011-06-01
On the basis of the fact that a hard-edged aperture function can be expressed as finite matrices with different weighting coefficients, we obtain the analytical formula for the propagation of the broadband gaussian Schell-model (BGSM) beam through the apertured fractional Fourier transformation (AFrFT) system. It is shown by numerical examples that the intensity distribution in the plane of a small fractional order is obviously influenced by the bandwidth when the BGSM beams propagate through the AFrFT system. Further extensions are also pointed out.
Niece, Krista L.
2015-01-01
Colistin use has increased in response to the advent of infections caused by multidrug-resistant organisms. It is administered parenterally as an inactive prodrug, colistin methanesulfonate (CMS). Various formulations of CMS and labeling conventions can lead to confusion about colistin dosing, and questions remain about the pharmacokinetics of CMS. Since CMS does not have strong UV absorbance, current methods employ a laborious process of chemical conversion to colistin followed by precolumn derivatization to detect formed colistin by high-performance liquid chromatography. Here, we report a method for direct quantification of colistin methanesulfonate by attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR). PMID:26124160
Noguchi, T; Mitsuka, T; Inoue, Y
1994-12-19
A Fourier-transform infrared (FTIR) spectrum of the radical cation of beta-carotene photoinduced in photosystem II (PSII) membranes was obtained at 80K under oxidizing conditions, by utilizing the light-induced FTIR difference technique. Formation of the beta-carotene cation was monitored with the electronic absorption band at 993 nm. An FTIR spectrum of a chemically-generated beta-carotene cation in chloroform was also measured and compared with the spectrum of PSII. Since the FTIR bands of carotenoid cation have characteristic features with strong intensities, they can be useful markers in studying the reaction of carotenoid in PSII.
Taylor, Samuel E; Cao, Tuoxin; Talauliker, Pooja M; Lifshitz, Jonathan
Quantification of immunohistochemistry (IHC) and immunofluorescence (IF) using image intensity depends on a number of variables. These variables add a subjective complexity in keeping a standard within and between laboratories. Fast Fourier Transformation (FFT) algorithms, however, allow for a rapid and objective quantification (via statistical analysis) using cell morphologies when the microscopic structures are oriented or aligned. Quantification of alignment is given in terms of a ratio of FFT intensity to the intensity of an orthogonal angle, giving a numerical value of the alignment of the microscopic structures. This allows for a more objective analysis than alternative approaches, which rely upon relative intensities.
Range-invariant anomaly detection applied to imaging Fourier transform spectrometry data
NASA Astrophysics Data System (ADS)
Borel, Christoph; Rosario, Dalton; Romano, Joao
2012-09-01
This paper describes the end-to-end processing of image Fourier transform spectrometry data taken of surrogate tank targets at Picatinny Arsenal in New Jersey with the long-wave hyper-spectral camera HyperCam from Telops. The first part of the paper discusses the processing from raw data to calibrated radiance and emissivity data. The second part discusses the application of a range-invariant anomaly detection approach to calibrated radiance, emissivity and brightness temperature data for different spatial resolutions and compares it to the Reed-Xiaoli detector.
Fourier transform Raman spectroscopic studies of a novel wood pulp bleaching system
NASA Astrophysics Data System (ADS)
Weinstock, Ira A.; Atalla, Rajai H.; Agarwal, Umesh P.; Minor, James L.; Petty, Chris
1993-06-01
The use of near-infrared (NIR) Fourier transform (FT) Raman spectroscopy for the study of lignocellulosic materials is discussed. An application utilizing NIR FT-Raman spectroscopy to study a novel chlorine-free process for the bleaching of wood pulps is presented in detail. The new process, still under development, entails the oxidation of residual lignin in wood pulps by vanadium-substituted polyoxometalates, and reoxidation of the reduced polyoxometalates by chlorine-free oxidants such as air, dioxygen, peroxides or ozone. Results from FT-Raman measurements of polyoxometalate-treated pulps are compared with those from chemical, spectroscopic and optical techniques commonly used in the pulp and paper industry.
Application of numerical Fourier transformation on measurements made on board rotating spacecraft
NASA Astrophysics Data System (ADS)
Grabowski, R.; Boesch, B.; Wolf, H.
Use of a Fast Fourier Transform algorithm to perform digital evaluation of signals from spacecraft featuring spin modulation and nutational effects is described. The case of a rotating spacecraft without nutation is modeled, with account taken of demodulation performed simultaneously with respect to amplitude and phase. Applying the demodulation technique twice removes the nutational effects. Assumptions are made that the spectral functions do not vary as fast as the spin modulation, and the signal variance independent of spacecraft rotation occurs at a rate significantly less than the spin rate. A demodulation example is given for a signal received from a probe on the Porcupine 2 rocket.
NASA Astrophysics Data System (ADS)
Townley-Smith, Keeley; Nave, Gillian; Pickering, Juliet C.; Blackwell-Whitehead, Richard J.
2016-09-01
We expand on the comprehensive study of hyperfine structure (HFS) in Mn II conducted by Holt et al. (1999) by verifying hyperfine magnetic dipole constants (A) for 20 levels previously measured by Holt et al. (1999) and deriving A constants for 47 previously unstudied levels. The HFS patterns were measured in archival spectra from Fourier transform (FT) spectrometers at Imperial College London and the National Institute of Standards and Technology. Analysis of the FT spectra was carried out in XGREMLIN. Our A constant for the ground level has a lower uncertainty by a factor of 6 than that of Blackwell-Whitehead et al.
NASA Astrophysics Data System (ADS)
Anh, P. K.; Castro, L. P.; Thao, P. T.; Tuan, N. M.
2017-01-01
This paper presents new convolutions for the fractional Fourier transform which are somehow associated with the Hermite functions. Consequent inequalities and properties are derived for these convolutions, among which we emphasize two new types of Young's convolution inequalities. The results guarantee a general framework where the present convolutions are well-defined, allowing larger possibilities than the known ones for other convolutions. Furthermore, we exemplify the use of our convolutions by providing explicit solutions of some classes of integral equations which appear in engineering problems.
Characterization of essential oils from lamiaceae species by fourier transform Raman spectroscopy.
Daferera, Dimitra J; Tarantilis, Petros A; Polissiou, Moschos G
2002-09-25
The Fourier transform Raman (FT-Raman) spectra of pure terpenes and essential oils obtained by hydrodistillation of some Lamiaceae species, are presented. This study shows that principal components of an essential oil can be recognized by FT-Raman. Components predicted by FT-Raman spectrum of an essential oil correlate well with those found as major constituents by GC-MS. In this way the basic chemical character of an essential oil can be recognized. The results demonstrate that certain Raman intensities can be correlated to specific terpenes and therefore FT-Raman can discriminate between the essential oils of which main components belong to different classes of compounds.
Application of the partial-Fourier-transform approach for tunnel ionization of molecules
NASA Astrophysics Data System (ADS)
Liu, Mingming; Liu, Yunquan
2016-04-01
Combining the partial-Fourier-transform approach with Wenzel-Kramers-Brillouin approximation, we theoretically study the strong-field tunneling ionization of diatomic and polyatomic molecules. First we obtain the analytical expression of momentum distribution at the tunnel exit of diatomic molecules, and then we calculate the alignment-dependent ionization rate at different laser intensities and internuclear distances. We show that the internuclear distance has a significant effect on the alignment dependence of the ionization rate. Using this approach, we can also separate the contributions of each atomic center and show the interference effect between them. Finally, we extend this method to a polyatomic molecule, benzene, as an example.
A program for 2D modeling (cross) correlogram tables using fast Fourier transform
NASA Astrophysics Data System (ADS)
Ma, Xianlin; Yao, Tingting
2001-08-01
An alternative to the traditional fitting of analytical correlogram models or of a linear model of coregionalization has been recently proposed, whereby the conditions for permissibility of a set of (cross) correlogram tables are imposed on their Fourier transforms, that is on the corresponding set of (cross) spectrum tables. The resulting model is entirely non-parametric and consists of a set of permissible (cross) correlogram tables from which gridded correlogram values can be read directly. This paper gives the suite of GSLIB-type programs to implement this correlogram modeling approach. Presentation of the program is backed by a case study using actual petroleum reservoir data (porosity and seismic reflection energy).
A highly linear superconducting bolometer for quantitative THz Fourier transform spectroscopy.
Kehrt, Mathias; Monte, Christian; Beyer, Jörn; Hollandt, Jörg
2015-05-04
A superconducting transition edge sensor (TES) bolometer operating in the spectral range from 0.1 THz to 3 THz was designed. It is especially intended for Fourier transform spectroscopy and features a higher dynamic range and a highly linear response at a similar response compared to commercially available silicon composite bolometers. The design is based on a thin film metal mesh absorber, a superconducting thermistor and Si3N4 membrane technology. A prototype was set up, characterized and successfully used in first applications.
HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF Nb i IN THE NEAR-INFRARED
Er, A.; Güzelçimen, F.; Başar, Gö.; Öztürk, I. K.; Tamanis, M.; Ferber, R.; Kröger, S. E-mail: sophie.kroeger@htw-berlin.de
2015-11-15
In this study, a Fourier Transform spectrum of Niobium (Nb) is investigated in the near-infrared spectral range from 6000 to 12,000 cm{sup −1} (830–1660 nm). The Nb spectrum is produced using a hollow cathode discharge lamp in an argon atmosphere. Both Nb and Ar spectral lines are visible in the spectrum. A total of 110 spectral lines are assigned to the element Nb. Of these lines, 90 could be classified as transitions between known levels of atomic Nb. From these classified Nb i transitions, 27 have not been listed in literature previously. Additionally, 8 lines are classified for the first time.
Kiyokura, Takanori; Ito, Takahiro; Sawada, Renshi
2004-12-01
This paper describes a Fourier transform (FT) near-infrared spectrometer that uses an integrated prism scanning interferometer whose optical paths are stabilized by corner cubes. A combination of corner cubes and a retroreflection mirror, which is sometimes used in the conventional interferometer for FT spectrometers, is adopted and adapted to the integrated prism scanning interferometer through a special design. Without any degradation of spectroscopic properties, the optical path in the interferometer is highly stabilized and the moving distance of the stage is halved. These advantages provide a robust and portable FT spectrometer for field use.
Pure rotational spectrum of cyclopropane observed by microwave Fourier transform spectroscopy
NASA Astrophysics Data System (ADS)
Brupbacher, Th.; Styger, Ch.; Vogelsanger, B.; Ozier, I.; Bauder, A.
1989-11-01
Pure rotational transitions of cyclopropane in the ground vibrational state have been measured between 12 and 24 GHz. The extremely weak transitions have been observed with a pulsed microwave Fourier transform spectrometer. P-, Q-, and R-branch transitions following the (Δ k = ±3) selection rule have been assigned for J ranging between 10 and 38. A total of 40 measured transition frequencies have been combined in a least-squares fit of the molecular constants B, ( C- B), DJ, DJK, DK, HJ, HJK, HKJ, and HK.
A High Precision Scanning Control System For A VUV Fourier Transform Spectrometer
De Oliveira, N.; Nahon, L.; Polack, F.; Joyeux, D.; Phalippou, D.; Rodier, J. C.; Vervloeet, M.
2007-01-19
A VUV Fourier transform spectrometer based on a wavefront division interferometer has been built. Our ultimate goal is to provide a high resolution absorption spectrometer in the 140 - 40 nm range using the new third generation French synchrotron source Soleil as the background continuum. Here, we present the design and latest performance of the instrument scanning control system. It is based on multiple reflections of a monomode, frequency-stabilized HeNe laser between two plane mirrors allowing the required sensitivity on the displacement of the interferometer mobile arm. The experimental results on the sampling precision show an rms error below 5 nm for a travel length of 7.5 mm.
Gao, Jianhua; Liang, Zhongzhu; Liang, Jingqiu; Wang, Weibiao; Lü, Jinguang; Qin, Yuxin
2016-11-23
Based on the basic configuration and interference principle of a static step-mirror-based Fourier transform spectrometer, an image segmentation method is proposed to obtain a one-dimensional interferogram. The direct current component of the interferogram is fit using the least squares (LS) method and is subsequently removed. An empirical-mode decomposition-method-based high-pass filter is constructed to denoise the spectrum and enhance the spectral resolution simultaneously. Several experiments were performed and the spectrum is reconstructed based on these methods. The spectrum resolution is 81 cm(-1) at 2254 cm(-1).
Enobio, Eli Christopher I.; Ohtani, Keita; Ohno, Yuzo; Ohno, Hideo
2013-12-02
We demonstrate the use of a Fourier Transform Infrared microscope system to detect and measure electroreflectance (ER) from mid-infrared quantum cascade laser (QCL) device. To characterize intersubband transition (ISBT) energies in a functioning QCL device, a microscope is used to focus the probe on the QCL cleaved mirror. The measured ER spectra exhibit resonance features associated to ISBTs under applied electric field in agreement with the numerical calculations and comparable to observed photocurrent, and emission peaks. The method demonstrates the potential as a characterization tool for QCL devices.
Solouki, T; Russell, D H
1992-01-01
Matrix-assisted laser desorption ionization is used to obtain Fourier-transform ion cyclotron resonance mass spectra of model peptides (e.g., gramicidin S, angiotensin I, renin substrate, melittin, and bovine insulin). Matrix-assisted laser desorption ionization yields ions having appreciable kinetic energies. Two methods for trapping the high kinetic energy ions are described: (i) the ion signal for [M+H]+ ions is shown to increase with increasing trapping voltages, and (ii) collisional relaxation is used for the detection of [M+H]+ ions of bovine insulin. Images PMID:1378614
Imaging the in-plane magnetization in a Co microstructure by Fourier transform holography.
Tieg, C; Frömter, R; Stickler, D; Hankemeier, S; Kobs, A; Streit-Nierobisch, S; Gutt, C; Grübel, G; Oepen, H P
2010-12-20
We report on experiments using Fourier transform holography to image the in-plane magnetization of a magnetic microstructure. Magnetic sensitivity is achieved via the x-ray magnetic circular dichroism effect by recording holograms in transmission at off-normal incidence. The reference beam is defined by a narrow hole milled at an inclined angle into the opaque mask. We present magnetic domain images of an in-plane magnetized cobalt element with a size of 2 μm × 2 μm× 20 nm. The domain pattern shows a multi-vortex state that deviates from the simple Landau ground state.
Real-time optical reflectometry enabled by amplified dispersive Fourier transformation
NASA Astrophysics Data System (ADS)
Goda, Keisuke; Solli, Daniel R.; Jalali, Bahram
2008-07-01
The axial scan rate of optical frequency-domain reflectometry and optical coherence tomography can be increased to megahertz frequencies by dispersive Fourier transformation. However, the fundamental connection between dispersion and loss creates a trade-off between detection sensitivity and acquisition speed. Here we circumvent this predicament by using distributed Raman postamplification of the reflection from the sample. The Raman amplification enables measurement of weak signals, which are otherwise buried in detector noise. It extends the depth range without sacrificing the acquisition speed. Single-shot imaging with improved sensitivity at an axial scan rate of 36.6MHz is demonstrated.
Laboratory detection of HC9N using a Fourier transform microwave spectrometer
NASA Astrophysics Data System (ADS)
Iida, Minoru; Ohshima, Yasuhiro; Endo, Yasuki
1991-04-01
The laboratory microwave spectrum of a linear carbon chain molecule, HC9N (cyano-octatetra-yne), has been observed for the first time by discharging a mixture of vinyl-cyanide and acetylene diluted in argon. The absorption spectrum was observed in a supersonic beam, using a pulsed-nozzle Fabry-Perot-type Fourier transform microwave spectrometer. Frequencies of 11 rotational transitions have been combined with the previously reported astronomical data, yielding accurate ground state parameters, B0 = 290.518322(57) MHz and D0 = 0.874(78) Hz.
NASA Astrophysics Data System (ADS)
Hanafi, Abdelmalek; Gharbi, Tijani; Cornu, Jean-Yves
2005-07-01
We explore the potential use of the Fourier-transform profilometry technique in in vivo studies of muscular contractions through the variation of muscle-group cross sections. Thanks to a tensorial analysis of the technique, a general expression of its sensitivity vector is established. It allows derivation of the expression of the resolution and the limit condition imposed by the spatial sampling of the fringe pattern. Key parameters that maximize the sensitivity are then simulated. A measurement system is accordingly built up and characterized. It is then successfully applied to the evaluation of the deformation of the forearm muscles during grasping exertions.
Predictive analog-to-digital converter for Fourier-transform spectrometers.
Deschênes, Jean-Daniel; Potvin, Simon; Ash, Jean-Simon; Genest, Jérôme
2010-09-10
This paper proposes the use of predictive analog-to-digital converters (ADC) to handle dynamic range issues in Fourier-transform spectrometers. Several predictive approaches are proposed, and one is implemented experimentally to show that the technique works. A system was implemented with 16 bit (13 bits effective) ADCs and digital-to-analog converters (DACs) operated at 8 bits to provide a comparison basis. Measurements of a blackbody at 900 °C performed using the setup show a 13 bit effective performance, limited by the input noise of the data acquisition card.
NASA Astrophysics Data System (ADS)
Green, Martina; Seiber, James N.; Biermann, Heinz W.
1993-03-01
A Fourier transform infrared (FTIR) spectrometer interfaced to a 2.5 m base path, open multi- pass cell was used to monitor indoor air in post-fumigation dwellings. The residual chemicals studied were the fumigant, methyl bromide and its odor additive, chloropicrin (Cl3CNO2). Indoor measurements with a time resolution of 15 minutes were performed for two houses of different age. Our results indicate that the newer dwelling, which contained insulation materials, appeared to retain substantial amounts of the fumigant. The highest concentration measured for methyl bromide was 24 ppm, close to five times the allowed TLV (Threshold Limit Value) of 5 ppm. For chloropicrin, we also observed a surprising level of close to 0.4 ppm, four times the TLV of 0.1 ppm. It was noted that the concentrations were very susceptible to any air movement such as that due to door opening. Analyses utilizing the conventional adsorption-desorption/GC technique were performed simultaneously by the Worker Health and Safety Branch of the California EPA. Although the vast difference in time resolution of the two methods precludes direct comparison of the data, averaging our measurements over the same integration time indicated that the FTIR methods gives significantly higher values than those obtained by the conventional method, especially when the pollutant concentrations are low.
Blackford, Jennifer Urbano; Salomon, Ronald M.; Waller, Niels G.
2009-01-01
Treatment-related changes in neurobiological rhythms are of increasing interest to psychologists, psychiatrists, and biological rhythms researchers. New methods for analyzing change in rhythms are needed, as most common methods disregard the rich complexity of biological processes. Large time series data sets reflect the intricacies of underlying neurobiological processes, but can be difficult to analyze. We propose the use of Fourier methods with multivariate permutation test (MPT) methods for analyzing change in rhythms from time series data. To validate the use of MPT for Fourier-transformed data, we performed Monte Carlo simulations and compared statistical power and family-wise error for MPT to Bonferroni-corrected and uncorrected methods. Results show that MPT provides greater statistical power than Bonferroni-corrected tests, while appropriately controlling family-wise error. We applied this method to human, pre-and post-treatment, serially-sampled neurotransmitter data to confirm the utility of this method using real data. Together, Fourier with MPT methods provides a statistically powerful approach for detecting change in biological rhythms from time series data. PMID:19212840
Long-distance super-resolution imaging assisted by enhanced spatial Fourier transform.
Tang, Heng-He; Liu, Pu-Kun
2015-09-07
A new gradient-index (GRIN) lens that can realize enhanced spatial Fourier transform (FT) over optically long distances is demonstrated. By using an anisotropic GRIN metamaterial with hyperbolic dispersion, evanescent wave in free space can be transformed into propagating wave in the metamaterial and then focused outside due to negative-refraction. Both the results based on the ray tracing and the finite element simulation show that the spatial frequency bandwidth of the spatial FT can be extended to 2.7k(0) (k(0) is the wave vector in free space). Furthermore, assisted by the enhanced spatial FT, a new long-distance (in the optical far-field region) super-resolution imaging scheme is also proposed and the super resolved capability of λ/5 (λ is the wavelength in free space) is verified. The work may provide technical support for designing new-type high-speed microscopes with long working distances.
High-resolution Fourier-transform spectrometer chip with microphotonic silicon spiral waveguides.
Velasco, Aitor V; Cheben, Pavel; Bock, Przemek J; Delâge, André; Schmid, Jens H; Lapointe, Jean; Janz, Siegfried; Calvo, María L; Xu, Dan-Xia; Florjańczyk, Mirosław; Vachon, Martin
2013-03-01
We report a stationary Fourier-transform spectrometer chip implemented in silicon microphotonic waveguides. The device comprises an array of 32 Mach-Zehnder interferometers (MZIs) with linearly increasing optical path delays between the MZI arms across the array. The optical delays are achieved by using Si-wire waveguides arranged in tightly coiled spirals with a compact device footprint of 12 mm2. Spectral retrieval is demonstrated in a single measurement of the stationary spatial interferogram formed at the output waveguides of the array, with a wavelength resolution of 40 pm within a free spectral range of 0.75 nm. The phase and amplitude errors arising from fabrication imperfections are compensated using a transformation matrix spectral retrieval algorithm.
[A phase error correction method for the new Fourier transforms spectrometer].
Wang, Ning; Gong, Tian-Cheng; Chen, Jian-Jun; Li, Yang; Yang, Yi-Ning; Zhu, Yong; Zhang, Jie; Chen, Wei-Min
2014-11-01
To decrease the distortion of the recovered spectrum, improve the quantity of the recovered spectrum and decrease the influence of the phase error of the new spectrum detection system based on MEMS (micro-electro-mechanical systems) micro-mirrors, a new phase error correction method for this system is proposed in the present paper. The source of phase error of the spectrum detection system based on MEMS micro-mirrors is analyzed firstly. The analyzed result indicated that the phase error of the new spectral Fourier transform detection system is the zero drift of the optical path difference, and the phase error can be corrected by Zero-crossing sampling which is realized by improving the structure of the interferometer system and Mertz product The spectrum detection system is set up and the phase error correction method is verified by this system. The experiment result is show that the quantity of the recovered spectrum of the spectrum detection is improved obviously by using the improved interferometer system and Mertz product, and the recovered spectrum has no negative peaks and the side lobes is suppressed markedly. This correction method can reduce the influence caused by phase error to the system performance well and improve the spectral detection performance effectively. In this paper, the origin of the system phase error based on the new MEMS micromirror Fourier transform spectroscopy detection system is analyzed, and the phase error correction method is proposed. This method can improve the performance of the spectrum detection system.
Dziuba, B
2013-01-01
Fourier transform infrared spectroscopy (FTIR) and artificial neural networks (ANN's) were used to identify species of Propionibacteria strains. The aim of the study was to improve the methodology to identify species of Propionibacteria strains, in which the differentiation index D, calculated based on Pearson's correlation and cluster analyses were used to describe the correlation between the Fourier transform infrared spectra and bacteria as molecular systems brought unsatisfactory results. More advanced statistical methods of identification of the FTIR spectra with application of artificial neural networks (ANN's) were used. In this experiment, the FTIR spectra of Propionibacteria strains stored in the library were used to develop artificial neural networks for their identification. Several multilayer perceptrons (MLP) and probabilistic neural networks (PNN) were tested. The practical value of selected artificial neural networks was assessed based on identification results of spectra of 9 reference strains and 28 isolates. To verify results of isolates identification, the PCR based method with the pairs of species-specific primers was used. The use of artificial neural networks in FTIR spectral analyses as the most advanced chemometric method supported correct identification of 93% bacteria of the genus Propionibacterium to the species level.
Ground-based high resolution Fourier transform spectrometer and its application in Beijing
NASA Astrophysics Data System (ADS)
Fan, Dongdong
2013-10-01
The B3M-FTS instrument, inherited from ACE-FTS and PARIS, is built by Canadian ABB and Beijing Vision Sky Aerospace Co., Ltd. The B3M is a complete stand-alone spectrometer designed to operate from the ground in moderate environment. It can acquire atmospheric spectra with the Sun as back illumination. This instrument is an adapted version of the classical Michelson interferometer using an optimized optical layout, and it is a high-resolution infrared Fourier transform spectrometer operating in the 750 to 4100cm-1 spectral range. In this paper, the instrument concept of a compact, portable, high-resolution Fourier transform spectrometer is introduced. Some test results of the instrument such as ILS and SNR are presented, and the spectral resolution of 0.028cm-1 @ 750cm-1 and SNR over 100:1 are achieved. Sample atmospheric absorption spectra and corresponding retrieval results measured by the FTS are given. The B3M-FTS, with its high performance, provides the capability to monitor the atmospheric composition changes by measuring the atmospheric absorption spectra of solar radiance. Lots of measurements have been acquired at the Olympics atmospheric observation super-station. Up to now, the VMRs of near 10 trace gases have been retrieved. The success of atmospheric composition profile retrieval using the FTS measurements makes the further application of FTS type payload possible in China.
Identification of Earthquake Induced Damage Areas Using Fourier Transform and SPOT HRVIR Pan Images
Sertel, Elif
2009-01-01
A devastating earthquake with a magnitude of Mw 7.4 occurred on the North Anatolian Fault Zone (NAFZ) of Turkey on August 17, 1999 at 00:01:39 UTC (3:01 a.m. local time). The aim of this study is to propose a new approach to automatically identify earthquake induced damage areas which can provide valuable information to support emergency response and recovery assessment procedures. This research was conducted in the Adapazari inner city, covering a 3 × 3 km area, where 11,373 buildings collapsed as a result of the earthquake. SPOT high resolution visible infrared (HRVIR) Pan images obtained before (25 June 1999) and after (4 October 1999) the earthquake were used in the study. Five steps were employed to conduct the research and these are: (i) geometric and radiometric correction of satellite images, (ii) Fast Fourier Transform (FFT) of pre- and post-earthquake images and filtering the images in frequency domain, (iii) generating difference image using Inverse Fast Fourier Transform (IFFT) pre- and post- earthquake images, (iv) application of level slicing to difference image to identify the earthquake-induced damages, (v) accuracy assessment of the method using ground truth obtained from a 1/5,000 scale damage map. The total accuracy obtained in the research is 80.19 %, illustrating that the proposed method can be successfully used to automatically identify earthquake-induced damage areas. PMID:22573966
Algorithm, applications and evaluation for protein comparison by Ramanujan Fourier transform.
Zhao, Jian; Wang, Jiasong; Hua, Wei; Ouyang, Pingkai
2015-12-01
The amino acid sequence of a protein determines its chemical properties, chain conformation and biological functions. Protein sequence comparison is of great importance to identify similarities of protein structures and infer their functions. Many properties of a protein correspond to the low-frequency signals within the sequence. Low frequency modes in protein sequences are linked to the secondary structures, membrane protein types, and sub-cellular localizations of the proteins. In this paper, we present Ramanujan Fourier transform (RFT) with a fast algorithm to analyze the low-frequency signals of protein sequences. The RFT method is applied to similarity analysis of protein sequences with the Resonant Recognition Model (RRM). The results show that the proposed fast RFT method on protein comparison is more efficient than commonly used discrete Fourier transform (DFT). RFT can detect common frequencies as significant feature for specific protein families, and the RFT spectrum heat-map of protein sequences demonstrates the information conservation in the sequence comparison. The proposed method offers a new tool for pattern recognition, feature extraction and structural analysis on protein sequences.
Identification of Earthquake Induced Damage Areas Using Fourier Transform and SPOT HRVIR Pan Images.
Sertel, Elif
2009-01-01
A devastating earthquake with a magnitude of Mw 7.4 occurred on the North Anatolian Fault Zone (NAFZ) of Turkey on August 17, 1999 at 00:01:39 UTC (3:01 a.m. local time). The aim of this study is to propose a new approach to automatically identify earthquake induced damage areas which can provide valuable information to support emergency response and recovery assessment procedures. This research was conducted in the Adapazari inner city, covering a 3 × 3 km area, where 11,373 buildings collapsed as a result of the earthquake. SPOT high resolution visible infrared (HRVIR) Pan images obtained before (25 June 1999) and after (4 October 1999) the earthquake were used in the study. Five steps were employed to conduct the research and these are: (i) geometric and radiometric correction of satellite images, (ii) Fast Fourier Transform (FFT) of pre- and post-earthquake images and filtering the images in frequency domain, (iii) generating difference image using Inverse Fast Fourier Transform (IFFT) pre- and post- earthquake images, (iv) application of level slicing to difference image to identify the earthquake-induced damages, (v) accuracy assessment of the method using ground truth obtained from a 1/5,000 scale damage map. The total accuracy obtained in the research is 80.19 %, illustrating that the proposed method can be successfully used to automatically identify earthquake-induced damage areas.
An Intelligent Dynamic Alignment System for Interferometer of Fourier Transform Spectrometer
NASA Astrophysics Data System (ADS)
Yang, Kun; Zeng, Libo
An intelligent dynamic alignment system for a Michelson interferometer which is applied to a Mid-infrared band Fourier transform spectrometer (FTS) is presented. Three photodiodes are used to detect the tilt of moving mirror opposite to fixed mirror with the assistance of the interfered signal of a reference He-Ne laser. This technique is based on detecting the phase difference of laser signal between every two diodes in two perpendicular directions. And four magnetic actuators behind the mounting brace of fixed mirror are used to change the pose of fixed mirror. The system is controlled by a digital signal processor (DSP) in real-time. A feedback algorithm is used to tilt fixed mirror following the action of moving mirror so as to keep both mirror planes in perpendicular. Experiment result shows that the relative tilt between two reflecting mirrors can be restricted in a range no more than ±1.5×10-6rad. This system is effective and reliable to be applied to scanning interferometer of Fourier transform spectrometer.
NASA Technical Reports Server (NTRS)
Hewagama, TIlak; Aslam, Shahid; Talabac, Stephen; Allen, John E., Jr.; Annen, John N.; Jennings, Donald E.
2011-01-01
Fourier transform spectrometers have a venerable heritage as flight instruments. However, obtaining an accurate spectrum exacts a penalty in instrument mass and power requirements. Recent advances in a broad class of non-scanning Fourier transform spectrometer (FTS) devices, generally called spatial heterodyne spectrometers, offer distinct advantages as flight optimized systems. We are developing a miniaturized system that employs photonics lightwave circuit principles and functions as an FTS operating in the 7-14 micrometer spectral region. The inteferogram is constructed from an ensemble of Mach-Zehnder interferometers with path length differences calibrated to mimic scan mirror sample positions of a classic Michelson type FTS. One potential long-term application of this technology in low cost planetary missions is the concept of a self-contained sensor system. We are developing a systems architecture concept for wide area in situ and remote monitoring of characteristic properties that are of scientific interest. The system will be based on wavelength- and resolution-independent spectroscopic sensors for studying atmospheric and surface chemistry, physics, and mineralogy. The self-contained sensor network is based on our concept of an Addressable Photonics Cube (APC) which has real-time flexibility and broad science applications. It is envisaged that a spatially distributed autonomous sensor web concept that integrates multiple APCs will be reactive and dynamically driven. The network is designed to respond in an event- or model-driven manner or reconfigured as needed.
Iterative Fourier transform algorithm: different approaches to diffractive optical element design
NASA Astrophysics Data System (ADS)
Skeren, Marek; Richter, Ivan; Fiala, Pavel
2002-10-01
This contribution focuses on the study and comparison of different design approaches for designing phase-only diffractive optical elements (PDOEs) for different possible applications in laser beam shaping. Especially, new results and approaches, concerning the iterative Fourier transform algorithm, are analyzed, implemented, and compared. Namely, various approaches within the iterative Fourier transform algorithm (IFTA) are analyzed for the case of phase-only diffractive optical elements with quantizied phase levels (either binary or multilevel structures). First, the general scheme of the IFTA iterative approach with partial quantization is briefly presented and discussed. Then, the special assortment of the general IFTA scheme is given with respect to quantization constraint strategies. Based on such a special classification, the three practically interesting approaches are chosen, further-analyzed, and compared to eachother. The performance of these algorithms is compared in detail in terms of the signal-to-noise ratio characteristic developments with respect to the numberof iterations, for various input diffusive-type objects chose. Also, the performance is documented on the complex spectra developments for typical computer reconstruction results. The advantages and drawbacks of all approaches are discussed, and a brief guide on the choice of a particular approach for typical design tasks is given. Finally, the two ways of amplitude elimination within the design procedure are considered, namely the direct elimination and partial elimination of the amplitude of the complex hologram function.
The design of ROM-type holographic memory with iterative Fourier transform algorithm
NASA Astrophysics Data System (ADS)
Akamatsu, Hideki; Yamada, Kai; Unno, Noriyuki; Yoshida, Shuhei; Taniguchi, Jun; Yamamoto, Manabu
2013-03-01
The research and development of the holographic data storage (HDS) is advanced, as one of the high-speed, mass storage systems of the next generation. Recently, along the development of the write-once system that uses photopolymer media, large capacity ROM type HDS which can replace conventional optical discs becomes important. In this study, we develop the ROM type HDS using a diffractive optical element (DOE), and verify the effectiveness of our approach. In order to design DOE, iterative Fourier transform algorithm was adopted, and DOE is fabricated with electron beam (EB) cutting and nanoimprint lithography. We optimize the phase distribution of the hologram by iterative Fourier transform algorithm known as Gerchberg-Saxton (GS) algorithm with the angular spectrum method. In the fabrication process, the phase distribution of the hologram is implicated as the concavity and convexity structure by the EB cutting and transcribed with nanoimprint lithography. At this time, the mold is formed as multiple-stage concavity and convexity. The purpose of multiple-stage concavity and convexity is to obtain high diffraction efficiency and signal-to-noise ratio (SNR). Fabricated trial model DOE is evaluated by the experiment.
SITELLE: a wide-field imaging Fourier transform spectrometer for the Canada-France-Hawaii Telescope
NASA Astrophysics Data System (ADS)
Drissen, L.; Bernier, A.-P.; Rousseau-Nepton, L.; Alarie, A.; Robert, C.; Joncas, G.; Thibault, S.; Grandmont, F.
2010-07-01
We describe the concept of a new instrument for the Canada-France-Hawaii telescope (CFHT), SITELLE (Spectromètre Imageur à Transformée de Fourier pour l'Etude en Long et en Large de raies d'Emission), as well as a science case and a technical study of its preliminary design. SITELLE will be an imaging Fourier transform spectrometer capable of obtaining the visible (350 nm - 950 nm) spectrum of every source of light in a field of view of 15 arcminutes, with 100% spatial coverage and a spectral resolution ranging from R = 1 (deep panchromatic image) to R = 104 (for gas dynamics). SITELLE will cover a field of view 100 to 1000 times larger than traditional integral field spectrographs, such as GMOS-IFU on Gemini or the future MUSE on the VLT. It is a legacy from BEAR, the first imaging FTS installed on the CFHT and the direct successor of SpIOMM, a similar instrument attached to the 1.6-m telescope of the Observatoire du Mont-Mégantic in Québec. SITELLE will be used to study the structure and kinematics of HII regions and ejecta around evolved stars in the Milky Way, emission-line stars in clusters, abundances in nearby gas-rich galaxies, and the star formation rate in distant galaxies.
Quantization maps, algebra representation, and non-commutative Fourier transform for Lie groups
Guedes, Carlos; Oriti, Daniele; Raasakka, Matti
2013-08-15
The phase space given by the cotangent bundle of a Lie group appears in the context of several models for physical systems. A representation for the quantum system in terms of non-commutative functions on the (dual) Lie algebra, and a generalized notion of (non-commutative) Fourier transform, different from standard harmonic analysis, has been recently developed, and found several applications, especially in the quantum gravity literature. We show that this algebra representation can be defined on the sole basis of a quantization map of the classical Poisson algebra, and identify the conditions for its existence. In particular, the corresponding non-commutative star-product carried by this representation is obtained directly from the quantization map via deformation quantization. We then clarify under which conditions a unitary intertwiner between such algebra representation and the usual group representation can be constructed giving rise to the non-commutative plane waves and consequently, the non-commutative Fourier transform. The compact groups U(1) and SU(2) are considered for different choices of quantization maps, such as the symmetric and the Duflo map, and we exhibit the corresponding star-products, algebra representations, and non-commutative plane waves.
NASA Astrophysics Data System (ADS)
Rossbach, P. C.
1985-12-01
The calculation of the Discrete Fourier Transform has long been a significant bottleneck in many Digital Signal Processing applications. With the arrival of Very Large Scale Integration and new DFT algorithms, system architectures that significantly reduce the DFT bottleneck are possible. This thesis addresses the design, simulation, implementation, and testing of the control circuitry for a high speed, VLSI Winograd Fourier Transform (WFT) processor. Three WFT processors are combined into a pipelined architecture that is capable of computing a 4080-point DFT on complex input data approximately every 120 microseconds when operating with 70 MHz clock signals. The chip control architecture features a special Programmable Logic Array (PLA) to control the on-chip arithmetic circuitry, and a dense, 54K ROM to generate data addresses for the external RAM. The PLA controller was fabricated in 3 micron CMOS and functioned properly for clock rates of over 60 MHz. The address generator ROM was designed and submitted for fabrication in 3 micron CMOS, and SPICE simulations predict an access time of 60 nanoseconds. Software that automatically generates a ROM layout description from a data file was developed to ensure the correctness of the final design. The transistor minimization procedure i s based on a graph partitioning heuristic, and the drain removal procedure is based on an algorithm that near-optimally solves the Traveling Salesman Problem.
A fractional Fourier transform analysis of the scattering of ultrasonic waves
Tant, Katherine M.M.; Mulholland, Anthony J.; Langer, Matthias; Gachagan, Anthony
2015-01-01
Many safety critical structures, such as those found in nuclear plants, oil pipelines and in the aerospace industry, rely on key components that are constructed from heterogeneous materials. Ultrasonic non-destructive testing (NDT) uses high-frequency mechanical waves to inspect these parts, ensuring they operate reliably without compromising their integrity. It is possible to employ mathematical models to develop a deeper understanding of the acquired ultrasonic data and enhance defect imaging algorithms. In this paper, a model for the scattering of ultrasonic waves by a crack is derived in the time–frequency domain. The fractional Fourier transform (FrFT) is applied to an inhomogeneous wave equation where the forcing function is prescribed as a linear chirp, modulated by a Gaussian envelope. The homogeneous solution is found via the Born approximation which encapsulates information regarding the flaw geometry. The inhomogeneous solution is obtained via the inverse Fourier transform of a Gaussian-windowed linear chirp excitation. It is observed that, although the scattering profile of the flaw does not change, it is amplified. Thus, the theory demonstrates the enhanced signal-to-noise ratio permitted by the use of coded excitation, as well as establishing a time–frequency domain framework to assist in flaw identification and classification. PMID:25792967
Zhang, Y G; Gu, Y; Wang, K; Fang, X; Li, A Z; Liu, K H
2012-05-01
An improved Fourier transform infrared spectroscopy approach adapting to photoluminescence and electroluminescence measurements in mid-infrared has been developed, in which diode-pumped solid-state excitation lasers were adopted for photoluminescence excitation. In this approach, three different Fourier transform infrared modes of rapid scan, double modulation, and step scan were software switchable without changing the hardware or connections. The advantages and limitations of each mode were analyzed in detail. Using this approach a group of III-V and II-VI samples from near-infrared extending to mid-infrared with photoluminescence intensities in a wider range have been characterized at room temperature to demonstrate the validity and overall performances of the system. The weaker electroluminescence of quantum cascade lasers in mid-infrared band was also surveyed at different resolutions. Results show that for samples with relatively strong photoluminescence or electroluminescence out off the background, rapid scan mode is the most preferable. For weaker photoluminescence or electroluminescence overlapped with background, double modulation is the most effective mode. To get a better signal noise ratio when weaker photoluminescence or electroluminescence signal has been observed in double modulation mode, switching to step scan mode should be an advisable option despite the long data acquiring time and limited resolution.
A fractional Fourier transform analysis of the scattering of ultrasonic waves.
Tant, Katherine M M; Mulholland, Anthony J; Langer, Matthias; Gachagan, Anthony
2015-03-08
Many safety critical structures, such as those found in nuclear plants, oil pipelines and in the aerospace industry, rely on key components that are constructed from heterogeneous materials. Ultrasonic non-destructive testing (NDT) uses high-frequency mechanical waves to inspect these parts, ensuring they operate reliably without compromising their integrity. It is possible to employ mathematical models to develop a deeper understanding of the acquired ultrasonic data and enhance defect imaging algorithms. In this paper, a model for the scattering of ultrasonic waves by a crack is derived in the time-frequency domain. The fractional Fourier transform (FrFT) is applied to an inhomogeneous wave equation where the forcing function is prescribed as a linear chirp, modulated by a Gaussian envelope. The homogeneous solution is found via the Born approximation which encapsulates information regarding the flaw geometry. The inhomogeneous solution is obtained via the inverse Fourier transform of a Gaussian-windowed linear chirp excitation. It is observed that, although the scattering profile of the flaw does not change, it is amplified. Thus, the theory demonstrates the enhanced signal-to-noise ratio permitted by the use of coded excitation, as well as establishing a time-frequency domain framework to assist in flaw identification and classification.
Estimation of ultrasound attenuation and dispersion using short time Fourier transform.
Zhao, B; Basir, O A; Mittal, G S
2005-03-01
Determination of the acoustic attenuation and dispersion has important applications in ultrasound tissue characterization and non-destructive material testing. Current signal processing methods Fourier transform of ultrasound signals to get the spectra of amplitude and phase to estimate respectively the attenuation and dispersion of a given medium. These methods are frequency domain method and obsessed with ambiguity issue in the phase unwrapping calculation. Conventional ultrasound velocity measuring method detects the time of arrival of a pulse (or echo) signal, which is a time domain method to compute group velocity (not phase velocity). This paper presents a novel approach based on the short time Fourier transform (STFT)--a time-frequency analysis, to estimate the ultrasonic dispersion and attenuation. Only the amplitude information of the pulse-signal spectra is used. Based on the time-frequency presentation, the attenuation coefficient of the signal is obtained by computing the amplitude decay of pulse spectrum in time domain, while phase velocities are obtained based on the "time-of-flight" (TOF) of the mono frequency component of the pulse signals. As a result, we eliminate the ambiguity issue in phase angle calculation. Furthermore, the proposed method makes the phase velocity pedagogically intuitive for novice users. The paper presents experiments to evaluate demonstrate the performance of the proposed method.
A prototype stationary Fourier transform spectrometer for near-infrared absorption spectroscopy.
Li, Jinyang; Lu, Dan-feng; Qi, Zhi-mei
2015-09-01
A prototype stationary Fourier transform spectrometer (FTS) was constructed with a fiber-coupled lithium niobate (LiNbO3) waveguide Mach-Zehnder interferometer (MZI) for the purpose of rapid on-site spectroscopy of biological and chemical measurands. The MZI contains push-pull electrodes for electro-optic modulation, and its interferogram as a plot of intensity against voltage was obtained by scanning the modulating voltage from -60 to +60 V in 50 ms. The power spectrum of input signal was retrieved by Fourier transform processing of the interferogram combined with the wavelength dispersion of half-wave voltage determined for the MZI used. The prototype FTS operates in the single-mode wavelength range from 1200 to 1700 nm and allows for reproducible spectroscopy. A linear concentration dependence of the absorbance at λmax = 1451 nm for water in ethanolic solution was obtained using the prototype FTS. The near-infrared spectroscopy of solid samples was also implemented, and the different spectra obtained with different materials evidenced the chemical recognition capability of the prototype FTS. To make this prototype FTS practically applicable, work on improving its spectral resolution by increasing the maximum optical path length difference is in progress.
Fresnel diffraction effects in Fourier-transform arrayed waveguide grating spectrometer.
Rodrigo, J A; Cheben, P; Alieva, T; Calvo, M L; Florjanczyk, M; Janz, S; Scott, A; Solheim, B; Xu, D X; Deláge, A
2007-12-10
We present an analysis of Fourier-transform arrayed waveguide gratings in the Fresnel diffraction regime. We report a distinct spatial modulation of the interference pattern referred to as the Moiré-Talbot effect. The effect and its influence in a FT AWG device is explained by deriving an original analytical expression for the modulated field, and is also confirmed by numerical simulations using the angular spectrum method to solve the Fresnel diffraction integral. We illustrate the retrieval of spectral information in a waveguide Fourier-transform spectrometer in the presence of the Moiré-Talbot effect. The simulated device comprises two interleaved waveguide arrays each with 180 waveguides and the interference order of 40. It is designed with a Rayleigh spectral resolution of 0.1 nm and 8 nm bandwidth at wavelength lambda approximately 1.5 mum. We also demonstrate by numerical simulations that the spectrometer crosstalk is reduced from -20 dB to -40 dB by Gaussian apodization.
Calculation of Fresnel diffraction from 1D phase step by discrete Fourier transform
NASA Astrophysics Data System (ADS)
Aalipour, Rasoul
2017-01-01
When a part of an optical wave-front experiences a sharp change in its phase, Fresnel diffraction becomes appreciable. Sharp change in phase occurs as a wave-front strikes with a phase step. The intensity distributions of diffraction patterns of the phase step is formulated by applying Fresnel-Kirchhoff integral. For while the incident light on the step is coherent, the Fresnel-Kirchhoff integral can be solved by using familiar Fresnel integrals. But, when the incident light is partially coherent, one can not express the diffraction integral as the Fresnel integrals and the problem is summarized in solving some unusual integrals. In this report, we propose Fourier transform method for solving the Fresnel-Kirchhoff integral. In this regard we use discrete Fourier transform method and calculate Fresnel diffraction from the 1D phase step by FFT-based algorithms. This method does not have any restriction on the coherence and profile shape of the incident light. We show that the method have appropriate solutions for coherent and partially coherent lights. For the case of the coherent light illumination of the step, the obtained results are in good agreement with the calculated results by using the Fresnel integrals in reported literatures.
[Application of Fourier transform infrared spectroscopy in identification of wine spoilage].
Zhao, Xian-De; Dong, Da-Ming; Zheng, Wen-Gang; Jiao, Lei-Zi; Lang, Yun
2014-10-01
In the present work, fresh and spoiled wine samples from three wines produced by different companies were studied u- sing Fourier transform infrared (FTIR) spectroscopy. We analyzed the physicochemical property change in the process of spoil- age, and then, gave out the attribution of some main FTIR absorption peaks. A novel determination method was explored based on the comparisons of some absorbance ratios at different wavebands although the absorbance ratios in this method were relative. Through the compare of the wine spectra before and after spoiled, the authors found that they were informative at the bands of 3,020~2,790, 1,760~1,620 and 1,550~800 cm(-1). In order to find the relation between these informative spectral bands and the wine deterioration and achieve the discriminant analysis, chemometrics methods were introduced. Principal compounds analysis (PCA) and soft independent modeling of class analogy (SIMCA) were used for classifying different-quality wines. And partial least squares discriminant analysis (PLS-DA) was applied to identify spoiled wines and good wines. Results showed that FTIR technique combined with chemometrics methods could effectively distinguish spoiled wines from fresh samples. The effect of classification at the wave band of 1 550-800 cm(-1) was the best. The recognition rate of SIMCA and PLSDA were respectively 94% and 100%. This study demonstrates that Fourier transform infrared spectroscopy is an effective tool for monitoring red wine's spoilage and provides theoretical support for developing early-warning equipments.
Use of Fourier transform infrared spectrometry to characterize composites and polymers
Lerner, B.D.
1992-01-01
Carbon fiber reinforced composites (CFRCs) combine the high tensile strength of carbon fibers with a highly crosslinked polymer matrix. Typically the carbon fibers are in the form of a cloth which is preimpregnated with a mixture of either unreacted monomers or partially reacted oligomers that are polymerized at high temperatures and pressures. For the product to have the desired mechanical properties, the prepreg must undergo the expected crosslinking reaction and this process is susceptible to small changes in the composition of the reactants that can occur on atmospheric exposure. In this dissertation the use of diffuse reflectance Fourier transform infrared (FT-IR) spectrometry as a means of characterizing small compositional changes occurring in epoxy and polyimide prepregs was evaluated. Prepregs were aged under similar conditions of temperature and humidity. Several methods of analyzing the spectra were investigated, ranging from the simple measurement of the ratio of two bands in the spectra to the combined use of Fourier self-deconvolution (FSD) and curve-fitting. Useful data on the epoxy polymers was obtained using each of these techniques, with the most linear plots of the spectral changes with time being obtained using combined FSD and curve-fitting. The development of several different types of step-scanning FT-IR spectrometers is described. Installation of a piezoelectric transducer (PZT) behind the movable mirror of the interferometer allows positional control to an accuracy of [+-]1.5 nm. Three coarse positioning drives, based on a dc motor, an Inchworm PZT drive, and a microstepper motor, were evaluated. Each permitted the desired level of positional accuracy, but none permitted the optical element to be stepped to the next sampling point in less than 0.5 s. The use of Fourier transforms to demodulate the sinusoidal signal from a phase-modulated interferogram was demonstrated.
Real-time 2D floating-point fast Fourier transforms for seeker simulation
NASA Astrophysics Data System (ADS)
Chamberlain, Richard; Lord, Eric; Shand, David J.
2002-07-01
The floating point Fast Fourier Transform (FFT) is one of the most useful basic functions available to the image and signal processing engineer allowing many complex and detailed special functions to be implemented more simply in the frequency domain. In the Hardware-in-the-Loop field an image transformed using FFT would allow the designer to think about accurate frequency based simulation of seeker lens effects, motion blur, detector transfer functions and much more. Unfortunately, the transform requires many hundreds of thousands or millions of floating point operations on a single modest sized image making it impractical for realtime Hardware-in-the-Loop systems. .until now. This paper outlines the development, by Nallatech, of an FPGA based IEEE floating point core. It traces the subsequent use of this core to develop a full 256 X 256 FFT and filter process implemented on COTS hardware at frame rates up to 150Hz. This transform can be demonstrated to model optical transfer functions at a far greater accuracy than the current spatial models. Other applications and extensions of this technique will be discussed such as filtering for image tracking algorithms and in the simulation of radar processing in the frequency domain.
NASA Technical Reports Server (NTRS)
Klimas, A. J.
1983-01-01
A numerical method is presented for studying one-dimensional electron plasma evolution under typical interplanetary conditions. The method applies the Fourier-Fourier transform approach to a plasma model that is a generalization of the electrostatic Vlasov-Poisson system of equations. Conservation laws that are modified to include the plasma model generalization and also the boundary effects of nonperiodic solutions are given. A new conservation law for entropy in the transformed space is then introduced. These conservation laws are used to verify the numerical solutions. A discretization error analysis is presented. Two numerical instabilities and the methods used for their suppression are treated. It is shown that in interplanetary plasma conditions, the bump-on-tail instability produces significant excitation of plasma oscillations at the Bohm-Gross frequency and its second harmonic. An explanation of the second harmonic excitation is given in terms of wave-wave coupling during the growth phase of the instability.
NASA Astrophysics Data System (ADS)
Graf, Robert N.; Chen, Xiaoxin; Brown, William; Wax, Adam
2008-02-01
Fourier Domain Low Coherence Interferometry (fLCI) is a promising technique which combines the depth resolution of low coherence interferometry with the sensitivity of light scattering spectroscopy for probing the health of epithelial tissue layers. Our new fLCI system configuration utilizes a white light Xe arc lamp source and a 4-f interferometer which re-images light scattered from the sample onto the detection plane. The system employs an imaging spectrometer at the detection plane to acquire depth resolved profiles from 252 adjacent spatial points without the need for any scanning. The limited spatial coherence of the light source requires the resolution of adjacent spatial points for the generation of depth information. Depth-resolved spectral information is recovered by performing a short-time Fourier transform on the detected spectra, similar to spectroscopic optical coherence tomography. Wavelength dependent variations in scattering intensity are analyzed as a function of depth to obtain information about the neoplastic transformation of the probed cells. Previous studies have demonstrated fLCI as an excellent technique for probing the scatterer morphology of simple phantoms and of in vitro cancer cell monolayers. We now seek to assess the ability of the new fLCI system to measure the health of subsurface tissue layers using the hamster cheek pouch model. Seven hamsters will have one cheek pouch treated with the known carcinogen DMBA. At the conclusion of the 24 week treatment period the animals will be anesthetized and the cheek pouches will be extracted. We will use the fLCI optical system to measure the neoplastic transformation of the in situ subsurface tissue layers in both the normal and DMBA-treated cheek pouches. Traditional histological analysis will be used to verify the fLCI measurements. We expect our results to establish the feasibility of fLCI to distinguish between healthy and dysplastic epithelial tissues in the hamster cheek pouch.
Zhang, Mingjing; Wen, Ming; Zhang, Zhi-Min; Lu, Hongmei; Liang, Yizeng; Zhan, Dejian
2015-03-01
Retention time shift is one of the most challenging problems during the preprocessing of massive chromatographic datasets. Here, an improved version of the moving window fast Fourier transform cross-correlation algorithm is presented to perform nonlinear and robust alignment of chromatograms by analyzing the shifts matrix generated by moving window procedure. The shifts matrix in retention time can be estimated by fast Fourier transform cross-correlation with a moving window procedure. The refined shift of each scan point can be obtained by calculating the mode of corresponding column of the shifts matrix. This version is simple, but more effective and robust than the previously published moving window fast Fourier transform cross-correlation method. It can handle nonlinear retention time shift robustly if proper window size has been selected. The window size is the only one parameter needed to adjust and optimize. The properties of the proposed method are investigated by comparison with the previous moving window fast Fourier transform cross-correlation and recursive alignment by fast Fourier transform using chromatographic datasets. The pattern recognition results of a gas chromatography mass spectrometry dataset of metabolic syndrome can be improved significantly after preprocessing by this method. Furthermore, the proposed method is available as an open source package at https://github.com/zmzhang/MWFFT2.
Bangalore, Arjun S.; Demirgian, Jack C.; Boparai, Amrit S.; Small, Gary W.
1999-11-01
The Fourier transform infrared (FT-IR) spectral data of two nerve agent simulants, diisopropyl methyl phosphonate (DIMP) and dimethyl methyl phosphonate (DMMP), are used as test cases to determine the spectral resolution that gives optimal pattern recognition performance. DIMP is used as the target analyte for detection, while DMMP is used to test the ability of the automated pattern recognition methodology to detect the analyte selectively. Interferogram data are collected by using a Midac passive FT-IR instrument. The methodology is based on the application of pattern recognition techniques to short segments of single-beam spectra obtained by Fourier processing the collected interferogram data. The work described in this article evaluates the effect of varying spectral resolution on the pattern recognition results. The objective is to determine the optimal spectral resolution to be used for data collection. The results of this study indicate that the data with a nominal spectral resolution of 16 cm{sup -1} provide sufficient selectivity to give pattern recognition results comparable to that obtained by using higher resolution data. We found that, while higher resolution does not increase selectivity sufficiently to provide better pattern recognition results, lower resolution decreases selectivity and degrades the pattern recognition results. These results can be used as guidelines to maximize detection sensitivity, to minimize the time needed for data collection, and to reduce data storage requirements. (c) 2000 Society for Applied Spectroscopy.
Analytical model and spectral correction of vibration effects on Fourier transform spectrometer
NASA Astrophysics Data System (ADS)
Shatalina, Irina; Schmidt, Frederic; Saggin, Bortolino; Gac, Nicolas; Kowalski, Matthieu; Giuranna, Marco
2013-10-01
Sensitivity to mechanical vibrations of Fourier Transform Spectrometers (FTS) is a well-known phenomenon. It is especially critical for FTS devoted to atmospheric studies (like the Planetary Fourier Spectrometer (PFS) onboard Mars Express 2003), as absorption bands for the gases of low concentration are comparable with the generated instrument spectral noise. The adopted techniques for the vibration sensitivity reduction suffer of limitations in practical implementation, leaving residual modulations of the interferogram and the so-called ghosts in the spectra. Moreover as it is often impossible to measure the vibrations during the FTS measurement, the position and magnitude of these ghosts cannot be evaluated. Up to now the adopted ghost reduction techniques are mostly based on the averaging of spectra, because the disturbance phase is randomly distributed. This paper presents an innovative data treatment technique which allows single spectrum correction from distortions of unknown nature. Such a technique would increase the spatial resolution of the mapping process and becomes crucial when the desired information is linked to a particular mapping area associated to an individual spectrum. The full study consists in the explicit analysis of the ghost formation and the post-processing algorithm based on the semiblind deconvolution method - an iterative numerical algorithm of the series of consecutive deconvolutions. The technique was tested on the data from the PFS and the algorithm proved to be consistent according to the selected efficiency criteria (coming from the available general information about the signal spectral shape).
Propagation of a general-type beam through a truncated fractional Fourier transform optical system.
Zhao, Chengliang; Cai, Yangjian
2010-03-01
Paraxial propagation of a general-type beam through a truncated fractional Fourier transform (FRT) optical system is investigated. Analytical formulas for the electric field and effective beam width of a general-type beam in the FRT plane are derived based on the Collins formula. Our formulas can be used to study the propagation of a variety of laser beams--such as Gaussian, cos-Gaussian, cosh-Gaussian, sine-Gaussian, sinh-Gaussian, flat-topped, Hermite-cosh-Gaussian, Hermite-sine-Gaussian, higher-order annular Gaussian, Hermite-sinh-Gaussian and Hermite-cos-Gaussian beams--through a FRT optical system with or without truncation. The propagation properties of a Hermite-cos-Gaussian beam passing through a rectangularly truncated FRT optical system are studied as a numerical example. Our results clearly show that the truncated FRT optical system provides a convenient way for laser beam shaping.
NASA Astrophysics Data System (ADS)
Zhang, Xiaoxing; Liu, Heng; Ren, Jiangbo; Li, Jian; Li, Xin
2015-02-01
Gas-insulated switchgear (GIS) internal SF6 gas produces specific decomposition components under partial discharge (PD). By detecting these characteristic decomposition components, such information as the type and level of GIS internal insulation deterioration can be obtained effectively, and the status of GIS internal insulation can be evaluated. SF6 was selected as the background gas for Fourier transform infrared spectroscopy (FTIR) detection in this study. SOF2, SO2F2, SO2, and CO were selected as the characteristic decomposition components for system analysis. The standard infrared absorption spectroscopy of the four characteristic components was measured, the optimal absorption peaks were recorded and the corresponding absorption coefficient was calculated. Quantitative detection experiments on the four characteristic components were conducted. The volume fraction variation trend of four characteristic components at different PD time were analyzed. And under five different PD quantity, the quantitative relationships among gas production rate, PD time, and PD quantity were studied.
Fourier-transform infrared spectroscopy (FTIR) analysis of triclinic and hexagonal birnessites.
Ling, Florence T; Post, Jeffrey E; Heaney, Peter J; Kubicki, James D; Santelli, Cara M
2017-05-05
The characterization of birnessite structures is particularly challenging for poorly crystalline materials of biogenic origin, and a determination of the relative concentrations of triclinic and hexagonal birnessite in a mixed assemblage has typically required synchrotron-based spectroscopy and diffraction approaches. In this study, Fourier-transform infrared spectroscopy (FTIR) is demonstrated to be capable of differentiating synthetic triclinic Na-birnessite and synthetic hexagonal H-birnessite. Furthermore, IR spectral deconvolution of peaks resulting from MnO lattice vibrations between 400 and 750cm(-1) yield results comparable to those obtained by linear combination fitting of synchrotron X-ray absorption fine structure (EXAFS) data when applied to known mixtures of triclinic and hexagonal birnessites. Density functional theory (DFT) calculations suggest that an infrared absorbance peak at ~1628cm(-1) may be related to OH vibrations near vacancy sites. The integrated intensity of this peak may show sensitivity to vacancy concentrations in the Mn octahedral sheet for different birnessites.
NASA Astrophysics Data System (ADS)
Watanabe, Hiroyuki
In this research, an iterative learning type courseware was made, the distribution of time scores in the courseware is gotten by the learning management system. It is a proposed method by which the distribution of time scores is changed to frequency and to power spectrum using Fourier Transform. The learning process continues until students get the passing scores and are classified by using these values, which are related to average time and the average of scores‧ square. Furthermore, the cross-correlation coefficients between the standard student and students are calculated, and delay times are analyzed. Finally, the transfer functions of some students are calculated, and the characteristics of the learning processes are analyzed.
NASA Astrophysics Data System (ADS)
Nagler, Peter C.; Fixsen, Dale J.; Kogut, Alan; Tucker, Gregory S.
2015-11-01
The detection of the primordial B-mode polarization signal of the cosmic microwave background (CMB) would provide evidence for inflation. Yet as has become increasingly clear, the detection of a such a faint signal requires an instrument with both wide frequency coverage to reject foregrounds and excellent control over instrumental systematic effects. Using a polarizing Fourier transform spectrometer (FTS) for CMB observations meets both of these requirements. In this work, we present an analysis of instrumental systematic effects in polarizing FTSs, using the Primordial Inflation Explorer (PIXIE) as a worked example. We analytically solve for the most important systematic effects inherent to the FTS—emissive optical components, misaligned optical components, sampling and phase errors, and spin synchronous effects—and demonstrate that residual systematic error terms after corrections will all be at the sub-nK level, well below the predicted 100 nK B-mode signal.
Supercontinuum Fourier transform spectrometry with balanced detection on a single photodiode.
Goncharov, Vasily V; Hall, Gregory E
2016-08-28
We demonstrate a method of combining a supercontinuum light source with a commercial Fourier transform spectrometer, using a novel approach to dual-beam balanced detection, implemented with phase-sensitive detection on a single light detector. A 40 dB reduction in the relative intensity noise is achieved for broadband light, analogous to conventional balanced detection methods using two matched photodetectors. Unlike conventional balanced detection, however, this method exploits the time structure of the broadband source to interleave signal and reference pulse trains in the time domain, recording the broadband differential signal at the fundamental pulse repetition frequency of the supercontinuum. The method is capable of real-time correction for instability in the supercontinuum spectral structure over a broad range of wavelengths and is compatible with commercially designed spectrometers. A proof-of-principle experimental setup is demonstrated for weak absorption in the 1500-1600 nm region.
Unraveling quantum pathways using optical 3D Fourier-transform spectroscopy
Li, Hebin; Bristow, Alan D.; Siemens, Mark E.; Moody, Galan; Cundiff, Steven T.
2013-01-01
Predicting and controlling quantum mechanical phenomena require knowledge of the system Hamiltonian. A detailed understanding of the quantum pathways used to construct the Hamiltonian is essential for deterministic control and improved performance of coherent control schemes. In complex systems, parameters characterizing the pathways, especially those associated with inter-particle interactions and coupling to the environment, can only be identified experimentally. Quantitative insight can be obtained provided the quantum pathways are isolated and independently analysed. Here we demonstrate this possibility in an atomic vapour using optical three-dimensional Fourier-transform spectroscopy. By unfolding the system’s nonlinear response onto three frequency dimensions, three-dimensional spectra unambiguously reveal transition energies, relaxation rates and dipole moments of each pathway. The results demonstrate the unique capacity of this technique as a powerful tool for resolving the complex nature of quantum systems. This experiment is a critical step in the pursuit of complete experimental characterization of a system’s Hamiltonian. PMID:23340430
A general purpose subroutine for fast fourier transform on a distributed memory parallel machine
NASA Technical Reports Server (NTRS)
Dubey, A.; Zubair, M.; Grosch, C. E.
1992-01-01
One issue which is central in developing a general purpose Fast Fourier Transform (FFT) subroutine on a distributed memory parallel machine is the data distribution. It is possible that different users would like to use the FFT routine with different data distributions. Thus, there is a need to design FFT schemes on distributed memory parallel machines which can support a variety of data distributions. An FFT implementation on a distributed memory parallel machine which works for a number of data distributions commonly encountered in scientific applications is presented. The problem of rearranging the data after computing the FFT is also addressed. The performance of the implementation on a distributed memory parallel machine Intel iPSC/860 is evaluated.
Davis, Benjamin L.; Berrier, Joel C.; Shields, Douglas W.; Kennefick, Julia; Kennefick, Daniel; Seigar, Marc S.; Lacy, Claud H. S.; Puerari, Ivanio
2012-04-01
A logarithmic spiral is a prominent feature appearing in a majority of observed galaxies. This feature has long been associated with the traditional Hubble classification scheme, but historical quotes of pitch angle of spiral galaxies have been almost exclusively qualitative. We have developed a methodology, utilizing two-dimensional fast Fourier transformations of images of spiral galaxies, in order to isolate and measure the pitch angles of their spiral arms. Our technique provides a quantitative way to measure this morphological feature. This will allow comparison of spiral galaxy pitch angle to other galactic parameters and test spiral arm genesis theories. In this work, we detail our image processing and analysis of spiral galaxy images and discuss the robustness of our analysis techniques.
The Fourier Transform Microwave/millimeter Spectrum of ScO (X^2Σ^+)
NASA Astrophysics Data System (ADS)
Halfen, D. T.; Min, J.; Ziurys, L. M.
2013-06-01
The pure rotational spectra of ScO (X^2Σ^+) have been recorded in the 4 - 90 GHz range using Fourier transform microwave/millimeter (FTM/mmW) techniques. This species was created in a supersonic jet expansion of laser-ablated scandium vapor and N_2O gas, diluted in argon. The N = 1 → 0 and 2 → 1 rotational transitions in both v = 0 and 1 have been measured near 30 and 61 GHz, respectively. The data over 60 GHz were obtained using a new E-band (60 - 90 GHz) FTmmW spectrometer system. The data have been analyzed, and rotational, fine, and hyperfine constants have been determined, which are in good agreement with those from past optical studies. ScO is a potential circumstellar molecule in giant/supergiant stars, where it is produced in oxygen-burning nucleosynthesis.
NASA Astrophysics Data System (ADS)
Adande, Gilles; Ziurys, L. M.
2013-06-01
The pure rotational spectrum of VS (X^{4}Σ^{-} ) has been measured with Fourier transform microwave (FTMW) and millimeter-wave direct absorption methods in the frequency range of 5-40 GHz and 210-315 GHz. Discharge assisted laser ablation (DALAS) of a vanadium rod in presence of H_{2}S gas was used to synthesize the radical in the microwave region. In the millimeter-wave range, the species was produced from the mixture of CS_{2} and VCl_{4} vapor in a DC discharge. The hyperfine structure was resolved and accurate fine and hyperfine parameters were obtained. Insights into the bonding character can be gleamed from the hyperfine constants, and an estimate of the position of two low-lying interacting electronic states can be obtain from the fine structure parameters. Details of these results will be discussed.
NASA Technical Reports Server (NTRS)
Jennings, Donald E.
1990-01-01
Modern observations of infrared molecular lines in planets are performed at spectral resolutions which are as high as those available in the laboratory. Analysis of such data requires laboratory measurements at the highest possible resolution, which also yield accurate line positions and intensities. For planetary purposes the spectrometer must be coupled to sample cells which can be reduced in temperature and varied in pressure. An approach which produces the full range of required molecular line parameters uses a combination of tunable diode lasers and Fourier transform spectrometers (FTS). The FTS provides board spectral coverage and good calibration accuracy, while the diode laser can be used to study those regions which are not resolved by the FTS.
NASA Astrophysics Data System (ADS)
Hotopp, Kelly M.; Wilcox, David S.; Shirar, Amanda J.; Dian, Brian C.
2010-06-01
Two-dimensional chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy has been used to study rotational energy level connectivity of 1,3-difluoroacetone and m-methylbenzaldehyde. In this series of experiments, non-selective polarizing pulse sequences were used to probe both progressively and regressively connected systems through coherences of coupled rotational energy levels. Coherence propagation among shared energy levels will be demonstrated on 1,3-difluoroacetone. Ab initio calculations predict that the methyl rotor barrier of m-methylbenzaldehyde is less than 35 cm-1 therefore giving rise to large A-E splitting. Furthermore there are two conformers of m-methylbenzaldehyde making the assignment of the rotational spectrum extremely difficult. We will show how coherence propagation demonstrated by 1,3-difluoroacetone can be applied in a general way to assign complex ground state rotational spectra such as m-methylbenzaldehyde.
NASA Astrophysics Data System (ADS)
Kamnev, Alexander A.; Calce, Enrica; Tarantilis, Petros A.; Tugarova, Anna V.; De Luca, Stefania
2015-01-01
Chemically modified pectin derivatives obtained by partial esterification of its hydroxyl moieties with fatty acids (FA; oleic, linoleic and palmitic acids), as well as the initial apple peel pectin were comparatively characterised using diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. Characteristic changes observed in DRIFT spectra in going from pectin to its FA esters are related to the corresponding chemical modifications. Comparing the DRIFT spectra with some reported data on FTIR spectra of the same materials measured in KBr or NaCl matrices has revealed noticeable shifts of several polar functional groups both in pectin and in its FA-esterified products induced by the halide salts. The results obtained have implications for careful structural analyses of biopolymers with hydrophilic functional groups by means of different FTIR spectroscopic methodologies.
Photoacoustic detection of blood in dental pulp by using short-time Fourier transform
NASA Astrophysics Data System (ADS)
Yamada, Azusa; Kakino, Satoko; Matsuura, Yuji
2016-03-01
A method based on photoacoustic analysis is proposed to diagnose dental pulp vitality. Photoacoustic analysis enables to get signal from deeper tissues than other optical analyses and therefore, signal detection from root canal of thick dental tissues such as molar teeth is expected. As a light source for excitation of photoacoustic waves, a microchip Q-switched YAG laser with a wavelength of 1064 nm was used and owing to large penetration depth of the near infrared laser, photoacoustic signals from dental root were successfully obtained. It was found that the photoacoustic signals from the teeth containing hemoglobin solution in the pulp cavity provide vibration in high frequency region. It was also shown that the intensities of the high frequency component have correlation with the hemoglobin concentration of solution. We applied short-time Fourier transform for evaluation of photoacoustic signals and this analysis clearly showed photoacoustic signals from dental root.
An Archive of Spectra from the Mayall Fourier Transform Spectrometer at Kitt Peak
NASA Astrophysics Data System (ADS)
Pilachowski, C. A.; Hinkle, K. H.; Young, M. D.; Dennis, H. B.; Gopu, A.; Henschel, R.; Hayashi, S.
2017-02-01
We describe the SpArc science gateway for spectral data obtained using the Fourier Transform Spectrometer (FTS) in operation at the Mayall 4-m telescope at the Kitt Peak National Observatory during the period from 1975 through 1995. SpArc is hosted by Indiana University Bloomington and is available for public access. The archive includes nearly 10,000 individual spectra of more than 800 different astronomical sources including stars, nebulae, galaxies, and solar system objects. We briefly describe the FTS instrument itself and summarize the conversion of the original interferograms into spectral data and the process for recovering the data into FITS files. The architecture of the archive is discussed and the process for retrieving data from the archive is introduced. Sample use cases showing typical FTS spectra are presented.
Nagler, Peter C.; Tucker, Gregory S.; Fixsen, Dale J.; Kogut, Alan
2015-11-15
The detection of the primordial B-mode polarization signal of the cosmic microwave background (CMB) would provide evidence for inflation. Yet as has become increasingly clear, the detection of a such a faint signal requires an instrument with both wide frequency coverage to reject foregrounds and excellent control over instrumental systematic effects. Using a polarizing Fourier transform spectrometer (FTS) for CMB observations meets both of these requirements. In this work, we present an analysis of instrumental systematic effects in polarizing FTSs, using the Primordial Inflation Explorer (PIXIE) as a worked example. We analytically solve for the most important systematic effects inherent to the FTS—emissive optical components, misaligned optical components, sampling and phase errors, and spin synchronous effects—and demonstrate that residual systematic error terms after corrections will all be at the sub-nK level, well below the predicted 100 nK B-mode signal.
NASA Astrophysics Data System (ADS)
Tan, Ru-Chao; Lei, Tong; Zhao, Qing-Min; Gong, Li-Hua; Zhou, Zhi-Hong
2016-12-01
To improve the slow processing speed of the classical image encryption algorithms and enhance the security of the private color images, a new quantum color image encryption algorithm based on a hyper-chaotic system is proposed, in which the sequences generated by the Chen's hyper-chaotic system are scrambled and diffused with three components of the original color image. Sequentially, the quantum Fourier transform is exploited to fulfill the encryption. Numerical simulations show that the presented quantum color image encryption algorithm possesses large key space to resist illegal attacks, sensitive dependence on initial keys, uniform distribution of gray values for the encrypted image and weak correlation between two adjacent pixels in the cipher-image.
An automatic frequency control loop using overlapping DFTs (Discrete Fourier Transforms)
NASA Technical Reports Server (NTRS)
Aguirre, S.
1988-01-01
An automatic frequency control (AFC) loop is introduced and analyzed in detail. The new scheme is a generalization of the well known Cross Product AFC loop that uses running overlapping discrete Fourier transforms (DFTs) to create a discriminator curve. Linear analysis is included and supported with computer simulations. The algorithm is tested in a low carrier to noise ratio (CNR) dynamic environment, and the probability of loss of lock is estimated via computer simulations. The algorithm discussed is a suboptimum tracking scheme with a larger frequency error variance compared to an optimum strategy, but offers simplicity of implementation and a very low operating threshold CNR. This technique can be applied during the carrier acquisition and re-acquisition process in the Advanced Receiver.
A Novel Application of Fourier Transform Spectroscopy with HEMT Amplifiers at Microwave Frequencies
NASA Technical Reports Server (NTRS)
Wilkinson, David T.; Page, Lyman
1995-01-01
The goal was to develop cryogenic high-electron-mobility transistor (HEMT) based radiometers and use them to measure the anisotropy in the cosmic microwave background (CMB). In particular, a novel Fourier transform spectrometer (FTS) built entirely of waveguide components would be developed. A dual-polarization Ka-band HEMT radiometer and a similar Q-band radiometer were built. In a series of measurements spanning three years made from a ground-based site in Saskatoon, SK, the amplitude, frequency spectrum, and spatial frequency spectrum of the anisotropy were measured. A prototype Ka-band FTS was built and tested, and a simplified version is proposed for the MAP satellite mission. The 1/f characteristics of HEMT amplifiers were quantified using correlation techniques.
Samiee, Kaveh; Kovács, Petér; Gabbouj, Moncef
2015-02-01
A system for epileptic seizure detection in electroencephalography (EEG) is described in this paper. One of the challenges is to distinguish rhythmic discharges from nonstationary patterns occurring during seizures. The proposed approach is based on an adaptive and localized time-frequency representation of EEG signals by means of rational functions. The corresponding rational discrete short-time Fourier transform (DSTFT) is a novel feature extraction technique for epileptic EEG data. A multilayer perceptron classifier is fed by the coefficients of the rational DSTFT in order to separate seizure epochs from seizure-free epochs. The effectiveness of the proposed method is compared with several state-of-art feature extraction algorithms used in offline epileptic seizure detection. The results of the comparative evaluations show that the proposed method outperforms competing techniques in terms of classification accuracy. In addition, it provides a compact representation of EEG time-series.
Hettich, R.L.; Jin, C.; Compton, R.N. ); Buseck, P.R.; Tsipursky, S.J. )
1993-10-10
Fourier transform mass spectrometry (FTMS) employing both laser desorption/ionization and thermal desorption/electron ionization is useful for the detection and structural characterization of fullerenes and chemically-modified fullerenes. Examination of a carbon-rich shungite rock sample from Russia by transmission electron microscopy and FTMS provided evidence of naturally-occurring fullerenes. Ion-molecule reactions can be studied with FTMS to investigate the electron affinities of modified fullerenes. By monitoring charge exchange reactions, the electron affinities of C[sub 60]F[sub x] (x=44,46) and C[sub 70]F[sub y] (y=52,54) were found to be substantially higher than the values for the parent fullerenes.
Determining the Critical Point of a Sigmoidal Curve via its Fourier Transform
NASA Astrophysics Data System (ADS)
Humeyra Bilge, Ayse; Ozdemir, Yunus
2016-08-01
A sigmoidal curve y(t) is a monotone increasing curve such that all derivatives vanish at infinity. Let tn be the point where the nth derivative of y(t) reaches its global extremum. In the previous work on sol-gel transition modelled by the Susceptible-Infected- Recovered (SIR) system, we observed that the sequence {tn } seemed to converge to a point that agrees qualitatively with the location of the gel point [2]. In the present work we outline a proof that for sigmoidal curves satisfying fairly general assumptions on their Fourier transform, the sequence {tn } is convergent and we call it “the critical point of the sigmoidal curve”. In the context of phase transitions, the limit point is interpreted as a junction point of two different regimes where all derivatives undergo their highest rate of change.
NASA Astrophysics Data System (ADS)
Choudhury, Debesh; Takeda, Mitsuo
2003-11-01
We propose a new technique for three-dimensional (3D) target recognition using the phase information from a Fourier transform profilometer (FTP). Instead of cross-correlating the 3D target/nontargets-induced distorted grating patterns or the associated phase differences directly, the phase information are rather utilized to synthesize two complex harmonic functions, spatial frequency distributions of which are proportional to the computed profilometric phase maps of the target and the nontargets and hence to respective shape information. These complex harmonic functions due to the target and the nontargets are cross-correlated to produce highest correlation peak at the target location and almost no correlation peak for others. The feasibility of the technique is demonstrated by detailed simulations and experiments showing an excellent discrimination capability for 3D target recognition.
Kluger, Robert; Smith, Brian L; Park, Hyungjun; Dailey, Daniel J
2016-11-01
Recent technological advances have made it both feasible and practical to identify unsafe driving behaviors using second-by-second trajectory data. Presented in this paper is a unique approach to detecting safety-critical events using vehicles' longitudinal accelerations. A Discrete Fourier Transform is used in combination with K-means clustering to flag patterns in the vehicles' accelerations in time-series that are likely to be crashes or near-crashes. The algorithm was able to detect roughly 78% of crasjavascript:void(0)hes and near-crashes (71 out of 91 validated events in the Naturalistic Driving Study data used), while generating about 1 false positive every 2.7h. In addition to presenting the promising results, an implementation strategy is discussed and further research topics that can improve this method are suggested in the paper.
Reference Ultraviolet Wavelengths of Cr III Measured by Fourier Transform Spectrometry
NASA Technical Reports Server (NTRS)
Smillie, D.G.; Pickering, J.C.; Smith, P.L.
2008-01-01
We report Cr III ultraviolet (UV) transition wavelengths measured using a high-resolution Fourier transform spectrometer (FTS), for the first time, available for use as wavelength standards. The doubly ionized iron group element spectra dominate the observed opacity of hot B stars in the UV, and improved, accurate, wavelengths are required for the analysis of astronomical spectra. The spectrum was excited using a chromium-neon Penning discharge lamp and measured with the Imperial College vacuum ultraviolet FTS. 140 classified 3d(exp 3)4s- 3d(exp 3)4p Cr III transition lines, in the spectral range 38,000 to 49,000 cm(exp -1) (2632 to 2041 A), the strongest having wavelength uncertainties less than one part in 10(exp 7), are presented.
Huck-Pezzei, V A; Pallua, J D; Pezzei, C; Bittner, L K; Schönbichler, S A; Abel, G; Popp, M; Bonn, G K; Huck, C W
2012-10-01
In the present study, Fourier transform infrared (FTIR) imaging and data analysis methods were combined to study morphological and molecular patterns of St. John's wort (Hypericum perforatum) in detail. For interpretation, FTIR imaging results were correlated with histological information gained from light microscopy (LM). Additionally, we tested several evaluation processes and optimized the methodology for use of complex FTIR microscopic images to monitor molecular patterns. It is demonstrated that the combination of the used spectroscopic method with LM enables a more distinct picture, concerning morphology and distribution of active ingredients, to be gained. We were able to obtain high-quality FTIR microscopic imaging results and to distinguish different tissue types with their chemical ingredients.
Titus, Jitto; Viennois, Emilie; Merlin, Didier; Unil Perera, A G
2017-03-01
This article describes a rapid, simple and cost-effective technique that could lead to a screening method for colitis without the need for biopsies or in vivo measurements. This screening technique includes the testing of serum using Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy for the colitis-induced increased presence of mannose. Chronic (Interleukin 10 knockout) and acute (Dextran Sodium Sulphate-induced) models for colitis are tested using the ATR-FTIR technique. Arthritis (Collagen Antibody Induced Arthritis) and metabolic syndrome (Toll like receptor 5 knockout) models are also tested as controls. The marker identified as mannose uniquely screens and distinguishes the colitic from the non-colitic samples and the controls. The reference or the baseline spectrum could be the pooled and averaged spectra of non-colitic samples or the subject's previous sample spectrum. This shows the potential of having individualized route maps of disease status, leading to personalized diagnosis and drug management.
Ikeda, Tatsuhiko; Kanaya, Shigehiko; Yonetani, Tsutomu; Kobayashi, Akio; Fukusaki, Eiichiro
2007-11-28
A rapid and easy determination method of green tea's quality was developed by using Fourier transform near-infrared (FT-NIR) reflectance spectroscopy and metabolomics techniques. The method is applied to an online measurement and an online prediction of green tea's quality. FT-NIR was employed to measure green tea metabolites' alteration affected by green tea varieties and manufacturing processes. A set of ranked green tea samples from a Japanese commercial tea contest was analyzed to create a reliable quality-prediction model. As multivariate analyses, principal component analysis (PCA) and partial least-squares projections to latent structures (PLS) were used. It was indicated that the wavenumber region from 5500 to 5200 cm(-1) had high correlation with the quality of the tea. In this study, a reliable quality-prediction model of green tea has been achieved.
Vesicle sizing by static light scattering: a Fourier cosine transform approach
NASA Astrophysics Data System (ADS)
Wang, Jianhong; Hallett, F. Ross
1995-08-01
A Fourier cosine transform method, based on the Rayleigh-Gans-Debye thin-shell approximation, was developed to retrieve vesicle size distribution directly from the angular dependence of scattered light intensity. Its feasibility for real vesicles was partially tested on scattering data generated by the exact Mie solutions for isotropic vesicles. The noise tolerance of the method in recovering unimodal and biomodal distributions was studied with the simulated data. Applicability of this approach to vesicles with weak anisotropy was examined using Mie theory for anisotropic hollow spheres. A primitive theory about the first four moments of the radius distribution about the origin, excluding the mean radius, was obtained as an alternative to the direct retrieval of size distributions.
Multiple-image encryption scheme based on cascaded fractional Fourier transform.
Kong, Dezhao; Shen, Xueju; Xu, Qinzu; Xin, Wang; Guo, Haiqiong
2013-04-20
A multiple-image encryption scheme based on cascaded fractional Fourier transform is proposed. In the scheme, images are successively coded into the amplitude and phase of the input by cascading stages, which ends up with an encrypted image and a series of keys. The scheme takes full advantage of multikeys and the cascaded relationships of all stages, and it not only realizes image encryption but also achieves higher safety and more diverse applications. So multiuser authentication and hierarchical encryption are achieved. Numerical simulation verifies the feasibility of the method and demonstrates the security of the scheme and decryption characteristics. Finally, flexibility and variability of the scheme in application are discussed, and the simple photoelectric mixed devices to realize the scheme are proposed.
NASA Astrophysics Data System (ADS)
Mitchel, W. C.; Brown, Gail J.; Rea, Laura S.; Smith, S. R.
1992-01-01
Deep levels between 0.1 and 1.0 eV in semi-insulating and high resistivity undoped horizontal Bridgman GaAs have been studied by temperature-dependent Hall effect (TDH) and Fourier transform photoconductivity (FTPC). Activation energies at 0.77, 0.426, and 0.15 eV have been observed by TDH. Photoionization thresholds at 1.0, 0.8, 0.56, 0.44, and 0.25 are reported. The photoconductivity thresholds at 0.56 and 0.25 eV are reported for the first time. New features in the 0.44 eV threshold suggest that the defect responsible for this level has a small lattice relaxation and Frank-Condon shift. Possible associations of the FTPC and TDH energies with the deep-level transient spectroscopy levels EL2, EL3, and EL6 are presented.
High-definition Fourier transform infrared spectroscopic imaging of prostate tissue
NASA Astrophysics Data System (ADS)
Wrobel, Tomasz P.; Kwak, Jin Tae; Kadjacsy-Balla, Andre; Bhargava, Rohit
2016-03-01
Histopathology forms the gold standard for cancer diagnosis and therapy, and generally relies on manual examination of microscopic structural morphology within tissue. Fourier-Transform Infrared (FT-IR) imaging is an emerging vibrational spectroscopic imaging technique, especially in a High-Definition (HD) format, that provides the spatial specificity of microscopy at magnifications used in diagnostic surgical pathology. While it has been shown for standard imaging that IR absorption by tissue creates a strong signal where the spectrum at each pixel is a quantitative "fingerprint" of the molecular composition of the sample, here we show that this fingerprint also enables direct digital pathology without the need for stains or dyes for HD imaging. An assessment of the potential of HD imaging to improve diagnostic pathology accuracy is presented.
High-definition Fourier transform infrared spectroscopic imaging of breast tissue
NASA Astrophysics Data System (ADS)
Leslie, L. Suzanne; Kadjacsy-Balla, Andre; Bhargava, Rohit
2015-03-01
Breast cancer diagnosis relies on staining serial sections of a biopsy in a process that can be time intensive and costly. Fourier transform infrared imaging (FT-IR) is a non-destructive, label-free chemical imaging technique that uses the vibrational structure of the biological molecules of the sample to provide contrast for images at any absorption peak in the mid-infrared. The full potential of spectroscopic imaging has been limited by the spatial resolution provided by most commercial instruments. By increasing the magnification and numerical aperture of the microscope, image pixel sizes on the order of 1.1 micron can be achieved, allowing HD FT-IR spectroscopic imaging to provide high quality images that could aid in histopathology, diagnosis, and studies of breast cancer progression.
NASA Astrophysics Data System (ADS)
Yi, Wei-song; Cui, Dian-sheng; Li, Zhi; Wu, Lan-lan; Shen, Ai-guo; Hu, Ji-ming
2013-01-01
The manuscript has investigated the application of near-infrared (NIR) spectroscopy for differentiation gastric cancer. The 90 spectra from cancerous and normal tissues were collected from a total of 30 surgical specimens using Fourier transform near-infrared spectroscopy (FT-NIR) equipped with a fiber-optic probe. Major spectral differences were observed in the CH-stretching second overtone (9000-7000 cm-1), CH-stretching first overtone (6000-5200 cm-1), and CH-stretching combination (4500-4000 cm-1) regions. By use of unsupervised pattern recognition, such as principal component analysis (PCA) and cluster analysis (CA), all spectra were classified into cancerous and normal tissue groups with accuracy up to 81.1%. The sensitivity and specificity was 100% and 68.2%, respectively. These present results indicate that CH-stretching first, combination band and second overtone regions can serve as diagnostic markers for gastric cancer.
NASA Astrophysics Data System (ADS)
Jusman, Yessi; Mat Isa, Nor Ashidi; Ng, Siew-Cheok; Hasikin, Khairunnisa; Abu Osman, Noor Azuan
2016-07-01
Fourier transform infrared (FTIR) spectroscopy technique can detect the abnormality of a cervical cell that occurs before the morphological change could be observed under the light microscope as employed in conventional techniques. This paper presents developed features extraction for an automated screening system for cervical precancerous cell based on the FTIR spectroscopy as a second opinion to pathologists. The automated system generally consists of the developed features extraction and classification stages. Signal processing techniques are used in the features extraction stage. Then, discriminant analysis and principal component analysis are employed to select dominant features for the classification process. The datasets of the cervical precancerous cells obtained from the feature selection process are classified using a hybrid multilayered perceptron network. The proposed system achieved 92% accuracy.
Ong, Eng Teo; Lee, Heow Pueh; Lim, Kian Meng
2004-09-01
This article presents a fast algorithm for the efficient solution of the Helmholtz equation. The method is based on the translation theory of the multipole expansions. Here, the speedup comes from the convolution nature of the translation operators, which can be evaluated rapidly using fast Fourier transform algorithms. Also, the computations of the translation operators are accelerated by using the recursive formulas developed recently by Gumerov and Duraiswami [SIAM J. Sci. Comput. 25, 1344-1381(2003)]. It is demonstrated that the algorithm can produce good accuracy with a relatively low order of expansion. Efficiency analyses of the algorithm reveal that it has computational complexities of O(Na), where a ranges from 1.05 to 1.24. However, this method requires substantially more memory to store the translation operators as compared to the fast multipole method. Hence, despite its simplicity in implementation, this memory requirement issue may limit the application of this algorithm to solving very large-scale problems.
Rohman, A; Man, Yb Che; Sismindari
2009-10-01
Today, virgin coconut oil (VCO) is becoming valuable oil and is receiving an attractive topic for researchers because of its several biological activities. In cosmetics industry, VCO is excellent material which functions as a skin moisturizer and softener. Therefore, it is important to develop a quantitative analytical method offering a fast and reliable technique. Fourier transform infrared (FTIR) spectroscopy with sample handling technique of attenuated total reflectance (ATR) can be successfully used to analyze VCO quantitatively in cream cosmetic preparations. A multivariate analysis using calibration of partial least square (PLS) model revealed the good relationship between actual value and FTIR-predicted value of VCO with coefficient of determination (R2) of 0.998.
Skliros, Aris; Park, Wooram; Chirikjian, Gregory S.
2010-01-01
This paper presents an efficient group-theoretic approach for computing the statistics of non-reversal random walks (NRRW) on lattices. These framed walks evolve on proper crystallographic space groups. In a previous paper we introduced a convolution method for computing the statistics of NRRWs in which the convolution product is defined relative to the space-group operation. Here we use the corresponding concept of the fast Fourier transform for functions on crystallographic space groups together with a non-Abelian version of the convolution theorem. We develop the theory behind this technique and present numerical results for two-dimensional and three-dimensional lattices (square, cubic and diamond). In order to verify our results, the statistics of the end-to-end distance and the probability of ring closure are calculated and compared with results obtained in the literature for the random walks for which closed-form expressions exist. PMID:21037950
Chang, Byoung-Yong; Hong, Sung-Young; Yoo, Jung-Suk; Park, Su-Moon
2006-10-05
A new attempt to obtain electron transfer kinetic parameters at an electrified electrode/electrolyte interface using Fourier transform electrochemical impedance spectroscopic (FTEIS) analyses of small potential step chronoamperometric currents is presented. The kinetic parameters thus obtained allowed mass transport free voltammograms to be constructed in an overpotential region, where the diffusion limits the electron transfer reaction, using the Butler-Volmer (B-V) relation. The B-V voltammograms clearly distinguish electrode reactions that are not much different in their electron transfer kinetic parameters, thus showing very similar normal linear sweep voltammetric (SCV) behaviors. Electrochemical reduction of p-benzoquinone, which displays nearly the same SCV responses at a gold electrode regardless whether the electrode is covered by a thiolated beta-cyclodextrin self-assembled monolayer, was taken as an example for the demonstration. The results show that the two voltametrically similar systems display very different electron transfer characteristics.
Application of Fourier transform ion cyclotron resonance mass spectrometry to oligosaccharides.
Park, Youmie; Lebrilla, Carlito B
2005-01-01
The application of Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) to the structural elucidation of oligosaccharides is described. This review covers the analyses of oligosaccharides in the context of the unique features of FTICR MS and the improvements in instrumentation that make it possible to study this class of compounds. It consists of work performed initially to understand the fundamental aspects of oligosaccharide ionization and unimolecular fragmentation. More recent investigation includes the application of the technique to samples of direct biological origin. Chemical and enzymatic degradation methods in conjunction with mass spectrometry (MS) and the use front-end methods with FTICR MS are also discussed. The current applications including the characterization of bacterial lipooligosaccharides and phosporylated carbohydrates are described.
Label-free identification of individual bacteria using Fourier transform light scattering.
Jo, YoungJu; Jung, JaeHwang; Kim, Min-Hyeok; Park, HyunJoo; Kang, Suk-Jo; Park, YongKeun
2015-06-15
Rapid identification of bacterial species is crucial in medicine and food hygiene. In order to achieve rapid and label-free identification of bacterial species at the single bacterium level, we propose and experimentally demonstrate an optical method based on Fourier transform light scattering (FTLS) measurements and statistical classification. For individual rod-shaped bacteria belonging to four bacterial species (Listeria monocytogenes, Escherichia coli, Lactobacillus casei, and Bacillus subtilis), two-dimensional angle-resolved light scattering maps are precisely measured using FTLS technique. The scattering maps are then systematically analyzed, employing statistical classification in order to extract the unique fingerprint patterns for each species, so that a new unidentified bacterium can be identified by a single light scattering measurement. The single-bacterial and label-free nature of our method suggests wide applicability for rapid point-of-care bacterial diagnosis.
Nam, Yun Sik; Park, Jin Sook; Kim, Nak-Kyoon; Lee, Yeonhee; Lee, Kang-Bong
2014-07-01
Seals are traditionally used in the Far East Asia to stamp an impression on a document in place of a signature. In this study, an accuser claimed that a personal contract regarding mining development rights acquired by a defendant was devolved to the accuser because the defendant stamped the devolvement contract in the presence of the accuser and a witness. The accuser further stated that the seal ink stamped on the devolvement contract was the same as that stamped on the development rights application document. To verify this, the seals used in two documents were analyzed using micro-attenuated total reflectance Fourier transform infrared spectroscopy and infrared spectra. The findings revealed that the seals originated from different manufacturers. Thus, the accuser's claim on the existence of a devolvement contract was proved to be false.
Park, Jinsoo; Kim, Wooil; Han, David K; Ko, Hanseok
2014-01-01
A new voice activity detector for noisy environments is proposed. In conventional algorithms, the endpoint of speech is found by applying an edge detection filter that finds the abrupt changing point in a feature domain. However, since the frame energy feature is unstable in noisy environments, it is difficult to accurately find the endpoint of speech. Therefore, a novel feature extraction algorithm based on the double-combined Fourier transform and envelope line fitting is proposed. It is combined with an edge detection filter for effective detection of endpoints. Effectiveness of the proposed algorithm is evaluated and compared to other VAD algorithms using two different databases, which are AURORA 2.0 database and SITEC database. Experimental results show that the proposed algorithm performs well under a variety of noisy conditions.
NASA Technical Reports Server (NTRS)
Zimmerman, G. A.; Gulkis, S.
1991-01-01
The sensitivity of a matched filter-detection system to a finite-duration continuous wave (CW) tone is compared with the sensitivities of a windowed discrete Fourier transform (DFT) system and an ideal bandpass filter-bank system. These comparisons are made in the context of the NASA Search for Extraterrestrial Intelligence (SETI) microwave observing project (MOP) sky survey. A review of the theory of polyphase-DFT filter banks and its relationship to the well-known windowed-DFT process is presented. The polyphase-DFT system approximates the ideal bandpass filter bank by using as few as eight filter taps per polyphase branch. An improvement in sensitivity of approx. 3 dB over a windowed-DFT system can be obtained by using the polyphase-DFT approach. Sidelobe rejection of the polyphase-DFT system is vastly superior to the windowed-DFT system, thereby improving its performance in the presence of radio frequency interference (RFI).
A Discussion of Using a Reconfigurable Processor to Implement the Discrete Fourier Transform
NASA Technical Reports Server (NTRS)
White, Michael J.
2004-01-01
This paper presents the design and implementation of the Discrete Fourier Transform (DFT) algorithm on a reconfigurable processor system. While highly applicable to many engineering problems, the DFT is an extremely computationally intensive algorithm. Consequently, the eventual goal of this work is to enhance the execution of a floating-point precision DFT algorithm by off loading the algorithm from the computing system. This computing system, within the context of this research, is a typical high performance desktop computer with an may of field programmable gate arrays (FPGAs). FPGAs are hardware devices that are configured by software to execute an algorithm. If it is desired to change the algorithm, the software is changed to reflect the modification, then download to the FPGA, which is then itself modified. This paper will discuss methodology for developing the DFT algorithm to be implemented on the FPGA. We will discuss the algorithm, the FPGA code effort, and the results to date.
NASA Astrophysics Data System (ADS)
Irudayaraj, Joseph; Yang, Hong; Sakhamuri, Sivakesava
2002-03-01
Fourier transform infrared photoacoustic spectroscopy (FTIR-PAS) was used to differentiate and identify microorganisms on a food (apple) surface. Microorganisms considered include bacteria ( Lactobacillus casei, Bacillus cereus, and Escherichia coli), yeast ( Saccharomyces cerevisiae), and fungi ( Aspergillus niger and Fusarium verticilliodes). Discriminant analysis was used to differentiate apples contaminated with the different microorganisms from uncontaminated apple. Mahalanobis distances were calculated to quantify the differences. The higher the value of the Mahalanobis distance metric between different microorganisms, the greater is their difference. Additionally, pathogenic (O157:H7) E. coli was successfully differentiated from non-pathogenic strains. Results demonstrate that FTIR-PAS spectroscopy has the potential to become a non-destructive analysis tool in food safety related research.
NASA Astrophysics Data System (ADS)
Yang, Hong; Irudayaraj, Joseph
2003-02-01
Fourier transform (FT) Raman spectroscopy was used for non-destructive characterization and differentiation of six different microorganisms including the pathogen Escherichia coli O157:H7 on whole apples. Mahalanobis distance metric was used to evaluate and quantify the statistical differences between the spectra of six different microorganisms. The same procedure was extended to discriminate six different strains of E. coli. The FT-Raman procedure was not only successful in discriminating the different E. coli strain but also accurately differentiated the pathogen from non-pathogens. Results demonstrate that FT-Raman spectroscopy can be an excellent tool for rapid examination of food surfaces for microorganism contamination and for the classification of microbial cultures.
Raman spectroscopy of gases with a Fourier transform spectrometer: the spectrum of D2
Jennings, D.E.; Weber, A.; Brault, J.W.
1986-01-15
A high-resolution Fourier transform spectrometer (FTS) has been used to record spontaneous incoherent laser Raman spectra of gases. The resolution, sensitivity, calibration accuracy, and spectral coverage achieved in these spectra demonstrate the viability of the FTS for Raman spectroscopy. Measurements from a spectrum of D2 containing both v = 0-0 and v = 1-0 transitions were fitted to the Dunham expansion of the vibration--rotation energy levels. The coefficients are (in cm ) Y10 = 2993.6060(67), Y01 = 30.4401 (89), Y11 = -1.0538(17), Y02 = -0.011590(41), Y12 = 2.02(80) x 10 U, and Y03 = 5.83(11) x 10 W. Errors in parentheses are one standard deviation.
Amirfattahi, Rassoul
2013-10-01
Owing to its simplicity radix-2 is a popular algorithm to implement fast fourier transform. Radix-2(p) algorithms have the same order of computational complexity as higher radices algorithms, but still retain the simplicity of radix-2. By defining a new concept, twiddle factor template, in this paper, we propose a method for exact calculation of multiplicative complexity for radix-2(p) algorithms. The methodology is described for radix-2, radix-2 (2) and radix-2 (3) algorithms. Results show that radix-2 (2) and radix-2 (3) have significantly less computational complexity compared with radix-2. Another interesting result is that while the number of complex multiplications in radix-2 (3) algorithm is slightly more than radix-2 (2), the number of real multiplications for radix-2 (3) is less than radix-2 (2). This is because of the twiddle factors in the form of which need less number of real multiplications and are more frequent in radix-2 (3) algorithm.
Phase cycling for optical two-dimensional Fourier-transform spectroscopy
NASA Astrophysics Data System (ADS)
Autry, Travis; Moody, Galan; Li, Hebin; Siemens, Mark; Cundiff, Steven
2011-03-01
Phase-cycling has been implemented in optical two-dimensional Fourier-transform spectroscopy to extract signals from quantum wells and quantum dots and to eliminate noise such as pump scatter co-propagating with the four-wave mixing signal. Experiments using actively phase-stabilized interferometers to cycle the excitation pulse optical phases suffer from partial noise cancellation because excitation and phase-control laser wavelengths are incommensurate. To obtain full noise elimination, we have incorporated liquid crystal variable retarders capable of imposing a π phase shift for wavelengths 650-950 nm. We present non-rephasing spectra of potassium vapor contained in a ~ 20 μ m transmission cell and show that this phase cycling method removes all noise from pump scatter while drastically reducing the data acquisition time compared to mechanical phase-delay techniques. This work was supported by an NSF-REU grant at the University of Colorado- Boulder.
Waveguide Chirped-Pulse Fourier Transform Microwave Spectroscopy of Allyl Bromide
NASA Astrophysics Data System (ADS)
McCabe, Morgan N.; Shipman, Steven
2014-06-01
The rotational spectrum of allyl bromide was recorded from 8.7 to 26.5 GHz at -20 °C with a waveguide chirped-pulse Fourier transform microwave spectrometer. The rotational spectrum of allyl bromide has been previously studied by Niide and coworkers. However, previous assignments of this spectrum only extended to J = 12 and K_a = 1. Newly acquired data from our spectrometer has allowed us to extend the previous work to higher values of J and K_a, leading to significant improvements in the distortion constants in particular. Comparisons between the spectra and conformational preferences of the allyl halides will also be discussed. Y. Niide, M, Takano,T. Satoh, and Y. Sasada J. Mol. Spectrosc., 63, 108(1976) Niide, Yuzuru, J. Sci. Hiroshima Univ., Ser. A, 48, 1(1984)
He, Jiayuan; Zhang, Dingguo; Sheng, Xinjun; Meng, Jianjun; Zhu, Xiangyang
2013-01-01
An improved discrete Fourier transform (iDFT) is presented in this study as a novel feature for surface electromyogram (sEMG) pattern classification. It employs the principle that the spectrum of sEMG signals changes regarding different motions. iDFT feature focuses on global information of local bands to increase the inter-class distance. The experiment results showed that iDFT feature had a better separability than two other spectral features, auto regression (AR) and Power spectral density (PSD), both on experienced and inexperienced subjects. The optimal bandwidth is between 30 and 50 Hz and influence of division methods is not significant. With the low computation cost and property of insensitivity to sampling frequency, our proposed method provides a competitive choice for prosthetic control.
Laremore, Tatiana N; Leach, Franklin E; Amster, I Jonathan; Linhardt, Robert J
2011-08-15
A mixture of glycosaminoglycan (GAG) chains from a plasma proteoglycan bikunin was fractionated using native, continuous-elution polyacrylamide gel electrophoresis, and the resulting fractions were analyzed by electrospray ionization Fourier transform mass spectrometry (ESI FTMS). Molecular mass analysis of the intact GAG afforded information about the length and composition of GAG chains in the mixture. Ambiguity in the interpretation of the intact GAG mass spectra was eliminated by conducting an additional experiment in which the GAG chains of known molecular mass were treated with a GAG-degrading enzyme, chondroitinase ABC, and the digestion products were analyzed by ESI FTMS. The plasma bikunin GAG chains consisted predominantly of odd number of saccharides, although few chains consisting of even number of saccharides were also detected. Majority of the analyzed chains were tetrasulfated or pentasulfated and comprised by 29 to 41 monosaccharides.
a Study of 4,4-DIMETHYLAMINOBEZONITRILE by Chirped-Pulsed Fourier Transform Microwave Spectroscopy
NASA Astrophysics Data System (ADS)
Bird, Ryan G.; Alstadt, Valerie J.; Pratt, David W.; Neill, Justin L.; Pate, Brooks H.
2010-06-01
The ground state rotational spectrum of 4,4-dimethylaminobenzonitrile (DMABN) was studied using chirped-pulsed Fourier transform microwave spectroscopy (CP-FTMW). The rotational spectrum from 6.5 to 18 GHz was collected using a compilation of 250 MHz chirped pulses and pieced together. DMABN is widely known as an important model for excited state twisted intramolecular charge transfer dynamics. It has been previously studied in our group using high resolution electronic spectroscopy, in which a strong coupling between methyl group internal rotation and overall rotation was discovered. We have recently determined that these couplings are not present in the ground state spectrum. The ground state structure and nuclear quadrupole coupling terms will also be discussed.
NASA Astrophysics Data System (ADS)
Li, Chao; Yang, Sheng-Chao; Guo, Qiao-Sheng; Zheng, Kai-Yan; Wang, Ping-Li; Meng, Zhen-Gui
2016-01-01
A combination of Fourier transform infrared spectroscopy with chemometrics tools provided an approach for studying Marsdenia tenacissima according to its geographical origin. A total of 128 M. tenacissima samples from four provinces in China were analyzed with FTIR spectroscopy. Six pattern recognition methods were used to construct the discrimination models: support vector machine-genetic algorithms, support vector machine-particle swarm optimization, K-nearest neighbors, radial basis function neural network, random forest and support vector machine-grid search. Experimental results showed that K-nearest neighbors was superior to other mathematical algorithms after data were preprocessed with wavelet de-noising, with a discrimination rate of 100% in both the training and prediction sets. This study demonstrated that FTIR spectroscopy coupled with K-nearest neighbors could be successfully applied to determine the geographical origins of M. tenacissima samples, thereby providing reliable authentication in a rapid, cheap and noninvasive way.
Supercontinuum Fourier transform spectrometry with balanced detection on a single photodiode
Goncharov, Vasily; Hall, Gregory
2016-08-25
Here, we have developed phase-sensitive signal detection and processing algorithms for Fourier transform spectrometers fitted with supercontinuum sources for applications requiring ultimate sensitivity. Similar to well-established approach of source noise cancellation through balanced detection of monochromatic light, our method is capable of reducing the relative intensity noise of polychromatic light by 40 dB. Unlike conventional balanced detection, which relies on differential absorption measured with a well matched pair of photo-detectors, our algorithm utilizes phase-sensitive differential detection on a single photodiode and is capable of the real-time correction for instabilities in supercontinuum spectral structure over a broad range of wavelengths. Inmore » the resulting method is universal in terms of applicable wavelengths and compatible with commercial spectrometers. We present a proof-of-principle experimental« less
Laser Mode Behavior of the Cassini CIRS Fourier Transform Spectrometer at Saturn
NASA Technical Reports Server (NTRS)
Brasunas, John C.
2012-01-01
The CIRS Fourier transform spectrometer aboard the NASA/ESA/ASI Cassini orbiter has been acquiring spectra of the Saturnian system since 2004. The CIRS reference interferometer employs a laser diode to trigger the interferogram sampling. Although the control of laser diode drive current and operating temperature are stringent enough to restrict laser wavelength variation to a small fraction of CIRS finest resolution element, the CIRS instrument does need to be restarted every year or two, at which time it may start in a new laser mode. By monitoring the Mylar absorption features in uncalibrated spectra due to the beam splitter Mylar substrate, it can be shown that these jumps are to adjacent modes and that most of the eight-year operation so far is restricted to three adjacent modes. For a given mode, the wavelength stability appears consistent with the stability of the laser diode drive curren.t and operating temperature.
Thompson, Sandra E.; Foster, Nancy S.; Johnson, Timothy J.; Valentine, Nancy B.; Amonette, James E.
2003-08-28
Fourier Transform Infrared Photoacoustic Spectroscopy (FTIR-PAS) has been applied for the first time to the identification and speciation of bacterial spores. With minimal preparation the spores were deposited into the photoacoustic sample cup and their spectra recorded. A total of 40 different samples of 5 different strains of Bacillus spores were analyzed: Bacillus subtilis ATCC 49760, Bacillus atrophaeus ATCC 49337, Bacillus subtilis 6051, Bacillus thuringiensis ssp. kurstaki, and Bacillus globigii Dugway. The statistical methods used included principal-component analysis (PCA), classification and regression trees (CART), and Mahalanobis-distance calculations. Internal cross-validation studies successfully classify the spores according to their bacterial strain in 38 of 40 cases (95%) and 36 of 40 (90%) in cross-validation. Analysis of fifteen blind samples, which included library and other spores, and nonbacterial materials, resulted in correct strain classification the blind samples that were members of the library and correct rejection of the nonbacterial samples.