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Sample records for advance column flotation

  1. Column flotation '88

    SciTech Connect

    Sastry, K.V.S.

    1988-01-01

    This book contains 34 selections. Some of the titles are: Column flotation of ultrafine coal: experience at BHP-Utah Coal Limited's Riverside mine; Measurement of rate data in flotation columns; Factors influencing the structure of a 3-phase coal flotation froth; and Microbubble flotation of fine coal.

  2. Recovery of fine coal from waste streams using advanced column flotation

    SciTech Connect

    Groppo, J.G.

    1991-01-01

    The advanced flotation techniques, namely column flotation, have shown potential in obtaining a low ash, low pyritic sulfur fine size clean coal. The overall objective of this program is to evaluate applicability of an advanced flotation technique, 'Ken-Flote' column to recover clean coal with minimum mineral matter content at greater than 90 percent combustible recovery from two Illinois preparation plant waste streams. Column flotations tests were conducted on the flotation feed obtained from the Kerr-McGee Galatia and Ziegler No. 26 plants using three different bubble-generating devices: sparger, gas saver and foam jet. Each of these devices was tested with three different frothers and various column-operating variable to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. For the Galatia slurry, the column provided a clean coal containing 5 percent ash, 0.48 percent pyritic sulfur at combustible recovery averaging 90 percent. In other words, about 90 percent ash and about 75 percent pyritic sulfur rejection were attained for the Galatia slurry. Pilot plant studies on this slurry basically obtained results similar to the laboratory studies. For the Ziegler No. 26, slurry column flotation provided a clean coal containing about 5 percent ash, 0.44 percent pyritic sulfur at more than 90 percent combustible recovery. The ash and pyrite sulfur rejection was about 85 percent and 65 percent, respectively.

  3. Recovery of fine coal from waste streams using advanced column flotation

    SciTech Connect

    Groppo, J.G.; Parekh, B.K. . Center for Applied Energy Research)

    1991-01-01

    The overall objective of this program is to evaluate the application of an advanced physical separation technique, namely Ken-Flote'' column flotation to recover clean coal with minimum sulfur and ash content at greater than 90 percent combustible recovery from two Illinois coal preparation plant fine waste streams. The project will optimize various operating parameters with particular emphasis on fine bubble generating devices and reagent packages to enhance the rejection of liberated ash and pyritic sulfur. During this contract period, column flotation testing was completed on the flotation feed slurry obtained from the Kerr-McGee Galatia Preparation Plant. The column flotation tests were conducted using three different bubble generating devices: Static, gas saver and foam jet spargers. Each of these devices was tested with three different frothers and various column operating variables to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. In general, the column flotation provided a clean coal containing about 4--6 percent ash at combustible recovery ranging from 88 to 92 percent while pyrite rejection was 70 to 75 percent. Flotation tests were also conducted on a slurry sample obtained from The Ziegler {number sign}26 Preparation Plant in Sesse, Illinois. Base-line flotation testing was completed using batch flotation to identify optimum reagent addition. Column flotation of the Ziegler slurry provided a clean coal containing 4--6 percent ash with a combustible recovery of 90--95 percent and pyrite rejection of 60--67 percent. Efforts are in progress in installing a 6-inc. I.D. pilot column at the Ziegler {number sign}26. 9 figs.

  4. Modeling of column flotation

    SciTech Connect

    Luttrell, G.H.; Adel, G.T.; Yoon, R.H.

    1987-01-01

    Many investigators believe that column flotation cells offer significant advantages over standard mechanical machines for the flotation of fine particles. However, because of their unique design and operation, conventional techniques for flotation cell scale-up and design cannot be applied to columns. In an attempt to help alleviate this problem, a population balance model based on first principles has been developed for fine particle flotation in a column. Two different terms have been considered in the model, i.e., transport and rate. Transport terms, incorporating fluid flow and buoyancy, are used to describe the movement of air bubbles, unattached particles and bubble-particle aggregates along the length of the column. Rate terms, which describe the bubble-particle attachment process, have been derived from first principle considerations. Because the model is based on first principles, it can be useful for the design, control, optimization and scale-up of column flotation cells. 9 refs., 12 figs.

  5. Recovery of fine coal from waste streams using advanced column flotation

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1991-01-01

    The overall objective of this program is to evaluate the application of an advanced physical separation technique, namely Ken-Flote'' column flotation to recover clean coal with minimum sulfur and ash content at greater than 90 percent combustible recovery from two Illinois coal preparation plant fine waste streams. This project will optimize various operating parameters with particular emphasis on fine bubble generating devices and reagent packages to enhance to rejection of liberated ash and pyritic sulfur. During this contract period, column flotation testing was conducted on the flotation feed slurry obtained from the Kerr-McGee Galatia Preparation Plant. The column flotation tests were conducted using three different bubble generating devices: static, gas saver and foam jet spargers. Each of these devices was tested with three different frothers and various column operating variables to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. In general, the column flotation provided a clean coal containing about 4--6 percent ash at combustible recovery ranging from 88 to 92 percent. 10 figs.

  6. Recovery of fine coal from waste streams using advanced column flotation

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1990-01-01

    The overall objective of this program is to evaluate the application of an advanced physical separation technique, namely Ken-Flote column flotation to maximize BTU recovery with minimum product sulfur and ash content from two Illinois coal preparation plant fine waste streams. The project will optimize various operating parameters with particular emphasis on fine bubble generating devices and reagent packages to enhance the rejection of liberated ash and pyrite. During this contract period, samples were obtained from the Kerr-McGee Galatia Preparation Plant and characterized. Analysis of the flotation feed slurry indicate that a significant amount of pyrite is present in the 5 microns size range as free particles. The coal is hydrophobic in nature and optimum reagent addition is 0.75 lb/ton frother and 1.5 lb/ton fuel oil. The best flotation results were obtained near pH 6 for all frothers tested. Two ash depressants tested showed no significant improvement in ash rejection. A pyrite depressant was also tested which indicated improved pyrite rejection from 28 to 37 percent at a dosage of 5 lb/ton. Efforts are in progress to design a test matrix to determine optimum operating conditions for column flotation testing with this substrate. The test matrixes will be designed to investigate three different bubble generating mechanisms. The objective is to identify column operating variables that will provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. 10 figs., 1 tab.

  7. Recovery of fine coal from waste streams using advanced column flotation. Annual report, September 1, 1990--August 31, 1991

    SciTech Connect

    Groppo, J.G.

    1991-12-31

    The advanced flotation techniques, namely column flotation, have shown potential in obtaining a low ash, low pyritic sulfur fine size clean coal. The overall objective of this program is to evaluate applicability of an advanced flotation technique, `Ken-Flote` column to recover clean coal with minimum mineral matter content at greater than 90 percent combustible recovery from two Illinois preparation plant waste streams. Column flotations tests were conducted on the flotation feed obtained from the Kerr-McGee Galatia and Ziegler No. 26 plants using three different bubble-generating devices: sparger, gas saver and foam jet. Each of these devices was tested with three different frothers and various column-operating variable to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. For the Galatia slurry, the column provided a clean coal containing 5 percent ash, 0.48 percent pyritic sulfur at combustible recovery averaging 90 percent. In other words, about 90 percent ash and about 75 percent pyritic sulfur rejection were attained for the Galatia slurry. Pilot plant studies on this slurry basically obtained results similar to the laboratory studies. For the Ziegler No. 26, slurry column flotation provided a clean coal containing about 5 percent ash, 0.44 percent pyritic sulfur at more than 90 percent combustible recovery. The ash and pyrite sulfur rejection was about 85 percent and 65 percent, respectively.

  8. Comparison of column flotation cells

    SciTech Connect

    Honaker, R.Q.; Mohanty, M.K.; Ho, K.

    1995-08-01

    Six commercial column flotation technologies, i.e., Canadian, Flotaire, Jameson, Microcel, Packed-Column, and Turbo-air, were tested for the treatment of Illinois Basin fine coal and the results from each column compared based on separation performance and throughout capacity. The separation performance achieved by each cell approached and, in some cases, exceeded the ultimate performance predicted by release analysis. A comparison of the test results indicates differences in the selectivity obtained by each flotation column on the basis of both ash and sulfur rejection. This finding may be due to variations in cell hydrodynamics and the ability to support a deep froth phase among the different column cells. In addition, throughput capacity of each cell was found to differ, apparently due to the differences in the bubble-particle attachment environment, bubble size, and bubble population. Variations in the operating characteristics, such as reagent additions, aeration rate and wash water rate, were also noted and summarized in this publication.

  9. The jet flotation column control system

    SciTech Connect

    Xu Zhiqiang; Ming Shangzhi; Liu Lijian; Huangfu Jinghua; Huo Sen; Zhang Rongzeng; Yang Hongjun

    1998-12-31

    Compared with the conventional mechanical flotation column, the jet flotation column has the advantages of high selectivity of separation, low investment and production cost, low floor space requirement, low dosage of reagent, easy control; it is more suitable to process fine particles. Recently, many new types of flotation columns have been developed with new methods. Mineral Processing Dept., China University of Mining and Technology (Beijing) designed an aerated, double-jet flotation column in the lab and the industrial trial will be put into operation. One of the significant characteristics of the new type of flotation column is high selectivity of separation, fast bubble mineralization speed. As it is sensitive to various factors, a control system for flotation column has been developed to stabilize the working condition, and this set of control system has been operated in the lab experiment.

  10. A parametric study of fine coal cleaning using column flotation

    SciTech Connect

    Parekh, B.K.; Groppo, J.G.; Bland, A.E.

    1986-01-01

    Recovery of fine coal is becoming an important and integral part of coal cleaning plants. Conventional froth flotation, which is commonly used in the coal industry, is inefficient at cleaning fine coal which contains large amounts of ultrafine ash or clays. The Kentucky Center for Energy Research Laboratory (KCERL) has been investigating an alternative method, counter-current column flotation, which is widely used in the mineral industry. Through an advanced cell design and counter-current wash of the froth, column flotation can produce a low-ash, clean coal product without sacrificing combustible recovery. An experimental program was conducted using a 2-inch internal diameter Canadian column flotation cell to examine the effect of various operating parameters on clean coal recovery and quality. The study investigated six operational parameters: feed rate, frother concentration, air flow rate, column height, pulp density and wash water rate.

  11. Column flotation of coal with fluorosurfactants

    SciTech Connect

    Not Available

    1989-10-01

    Laboratory tests were carried out by the US Bureau of Mines, Salt Lake City Research Center to evaluate the potential of column flotation technology, coupled with novel fluorosurfactant collectors, for the selective flotation of fine coal from pyritic sulfur and mineral matter. The results on flotation feeds of both {minus}100 and {minus}400 mesh Middle Kittaning seam coal samples are presented. 4 refs., 23 figs., 9 tabs.

  12. The flotation column as a froth separator

    SciTech Connect

    Schultz, C.W.; Mehta, R.K.; Bates, J.B. )

    1991-12-01

    The Mineral Resources Institute, The University of Alabama, has for the past three years been engaged in a program to develop a beneficiation system for eastern (Devonian) oil shales. One objective of that program was to evaluate advanced technologies for effecting a kerogen-mineral matter separation. Column flotation was among the advanced technologies selected for evaluation. One observation made in the course of optimization testing was that introducing the feed into the froth (above the pulp- froth interface) resulted in an improved combination of concentrate grade and kerogen recovery. This observation was reported in a previous paper. Because the practice of maintaining the pulp froth interface below the feed point is contrary to conventional practice, it was decided to subject the observation to a systematic series of tests. This paper describes a recent series of tests and the results that were obtained.

  13. Plant practices in fine coal column flotation

    SciTech Connect

    Davis, V.L. Jr.; Bethell, P.J.; Stanley, F.L.; Luttrell, G.H.

    1995-10-01

    Five 3 m (10 ft) diameter Microcel{trademark} flotation columns were installed at Clinchfield Coal Company`s Middle Fork preparation facility in order to reduce product ash and increase recovery and plant capacity. The Middle Fork facility is utilized for the recovery of fine coal from a feed stream that consists primarily of 1.5 mm x 0 material. The columns replaced conventional flotation cells for the treatment of the minus 150 {micro}m fraction while spirals are used to upgrade the plus 150 {micro}m material in the plant feed. The addition of the column flotation circuit resulted in an increase in plant capacity in excess of 20 percent while reducing the flotation product ash content by approximately 7 percentage points. Flotation circuit combustible recovery wa increased by 17 percentage points. This paper discusses circuit design, commissioning, and sparging system design. Circuit instrumentation, level control, reagent system control, performance comparisons with conventional flotation, and general operating procedures are also discussed.

  14. Advanced froth flotation techniques for fine coal cleaning

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-12-31

    Advanced column flotation cells offer many potential advantages for the treatment of fine coal. The most important of these is the ability to achieve high separation efficiencies using only a single stage of processing. Unfortunately, industrial flotation columns often suffer from poor recovery, low throughput and high maintenance requirements as compared to mechanically-agitated conventional cells. These problems can usually be attributed to poorly-designed air sparging systems. This article examines the problems of air sparging in greater detail and offers useful guidelines for designing bubble generators for industrial flotation columns. The application of these principles in the design of a successful advanced fine coal flotation circuit is also presented.

  15. Desulfurization of coal by microbial column flotation.

    PubMed

    Ohmura, N; Saiki, H

    1994-06-05

    Twenty-three strains capable of oxidizing iron were isolated from coal and ore storage sites as well as coal and ore mines, volcanic areas, and hot spring. Four strains were found to have high iron-oxidizing activity. One strain (T-4) was selected for this experiment since the strain showed the fastest leaching rate of iron and sulfate from pyrite among the four strains. The T-4 strain was assigned for Thiobacillus ferrooxidans from its cultural and morphological characteristics.Bacterial treatment was applied to column flotation. An increase of cell density in the microbial column flotation resulted in the increase of pyrite removal from a coal-pyrite mixture (high sulfur imitated coal) with corresponding decrease of coal recovery. The addition of kerosene into the microbial column flotation increased the recovery of the imitated coal from 55% (without kerosene) to 81% (with 50 microL/L kerosene) with the reduction of pyrite sulfur content from 11% (feed coal) to 3.9% (product coal). The kerosene addition could reduce the pyritic sulfur content by collecting the coal in the recovery. However, the addition could not enhance separation of pyrite from the coal-pyrite mixture, since pyrite rejection was not affected by the increase of the kerosene addition. An excellent separation was obtained by the microbial flotation using a long column which had a length-diameter (L/D) ratio of 12.7. The long column flotation reduced the pyritic sulfur content from 11% (feed coal) to 1.8% (product coal) when 80% of the feed coal was recovered without the kerosene addition. The long column flotation not only attained an excellent separation but also reduced the amount of cells for desulfurization to as little as one-tenth of the reported amount.

  16. Desulfurization of coal by microbial column flotation

    SciTech Connect

    Ohmura, Naoya; Saiki, Hiroshi . Dept. of Biotechnology)

    1994-06-05

    Twenty-three strains capable of oxidizing iron were isolated from coal and ore storage sites as well as coal and ore mines, volcanic areas, and hot spring. Four strains were found to have high iron-oxidizing activity. One strain (T-4) was selected for this experiment since the strain showed the fastest leaching rate of iron and sulfate from pyrite among the four strains. The T-4 strain was assigned for Thiobacillus ferrooxidans from its cultural and morphological characteristics. Bacterial treatment was applied to column flotation. An increase of cell density in the microbial column flotation resulted in the increase of pyrite removal from a coal-pyrite mixture with corresponding decrease of coal recovery. The addition of kerosene into the microbial column flotation increased the recovery of the imitated coal from 55% (without kerosene) to 81% (with 50 [mu]L/L kerosene) with the reduction of pyrite sulfur content from11% (feed coal) to 3.9% (product coal). An excellent separation was obtained by the microbial flotation using a long column which had a length-diameter (L/D) ratio of 12.7.

  17. In-plant testing of microbubble column flotation

    SciTech Connect

    Luttrell, G.H.; Mankosa, M.J.; Adel, G.T.; Yoon, R.H.

    1990-01-01

    This report describes progress in two areas: advanced instrumentation and column installation. The project is working with both 30-inch and 8-foot columns for coal flotation. The paper describes installation of the instrument package, the control loops, and the data acquisition system. Under the second area of study, a test plan was developed for a parametric study of the 8-foot column operating conditions (feed flow rate, gas flow rate, wash water flow rate, and froth addition) that were determined to influence separation efficiency on the 30-inch column. Results to date are discussed. 7 refs., 4 tabs. (CK)

  18. Advances in flotation technology

    SciTech Connect

    Parekh, B.K.; Miller, J.D.

    1999-07-01

    The ability to selectively separate fine and coarse particles by flotation is the heart of most mineral processing operations. Significant developments in flotation technology are reflected in this proceedings including: equipment design and development, instrumentation and control, sulfides and precious metals, nonsulfide minerals, coal cleaning, and fundamentals.

  19. The industrial practice and development of flotation column in China

    SciTech Connect

    Liu Jiongtian; Zhang Shuangquan

    1997-12-31

    This paper reviewed the developing course of the flotation column since the 1960`s in China. Based on the practical data from several coal preparation plants, two types of flotation columns (the pressure aerated column and the jetting-cyclone column) were compared by their operation, performance and the reasons why they succeeded in the coal industry in China. The paper points out that the flotation column has come into commercial use and has good application prospects in China.

  20. Dispersion characteristics in column flotation of fine coal

    SciTech Connect

    Peng, F.F.; Lili, L.

    1995-10-01

    The dispersion model of nonideal flow was applied to describe the hydrodynamic state within the flotation column. Residence time distribution (RTD) data of a laboratory flotation column were measured to determine the parameters of the model. The effects of operating variables and column geometry on the Peclet number which reflects the extent of axial dispersion were investigated and a semi-empirical expression of Pe was formulated. The dispersion model was validated for the column flotation of ultrafines coal. Under the conditions of sufficient aeration rate and frother addition, a good agreement between the measured recoveries and predicted data was obtained. The dispersion model with first-order flotation rate process of the flotation column developed in this study is useful in predicting the collection zone recovery of fine coal, and for the flotation column scale-up.

  1. Commercialization of the Microcel{trademark} column flotation technology

    SciTech Connect

    Luttrell, G.H.; Yoon, R.H.

    1994-12-31

    Hydrodynamic analyses suggest that the recovery of fine particles by flotation can be improved through the use of smaller air bubbles. Unfortunately, many of the commercial methods for generating small air bubbles are difficult to scale-up and maintain. To overcome these problems, a novel flotation system known as Microcel{trademark} column flotation was developed at Virginia Tech. In this process, compressed air is injected into flotation pulp that is circulated through a parallel set of static in-line mixers. This arrangement provides a means of creating high energy dissipation, which is essential for producing small bubbles, without creating serious wear and maintenance problems. This article reviews some of the fundamental principles involved m the development of the Microcel{trademark} technology and provides guidelines for designing an effective fine coal flotation system. An example of a commercial installation of the Microcel{trademark} technology is also presented along with the economic benefits of using this advanced fine coal cleaning technique.

  2. Cross flow cyclonic flotation column for coal and minerals beneficiation

    SciTech Connect

    Lai, R.W.; Patton, R.A.

    2000-05-02

    An apparatus and process are disclosed for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophilic tailings.

  3. Cross flow flotation column for coal and minerals beneficiation

    SciTech Connect

    Lai, Ralph W.; Patton, Robert A.

    1997-12-01

    An apparatus and process are disclosed for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophilic tailings.

  4. Cross flow cyclonic flotation column for coal and minerals beneficiation

    DOEpatents

    Lai, Ralph W.; Patton, Robert A.

    2000-01-01

    An apparatus and process for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophillic tailings.

  5. In-plant testing of microbubble column flotation

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1989-01-01

    A project to evaluate the performance of the Virginia Tech Microbubble Column Flotation (MCF) process in an operating coal preparation plant was initiated during this past quarter. The project is concerned with the collection of process operating data using a 30-inch diameter column, and using this data to scale-up to a prototype, full-scale plant column. The work is being carried out at the Marrowbone Preparation Plant owned by the Shell Mining Corporation. Work has primarily concentrated on finalizing the project work plan (Task 2.1 -- Project Planning), instrumenting the 30-inch diameter column (Task 2.2 -- Advanced Instrumentation) and conducting a preliminary parametric study to evaluate the performance of the column (Task 2.3 -- Detailed Testing). To date, the column has been consistently capable of producing a 9.5% ash product at a 61% combustible recovery from a -150 mesh classifying cyclone overflow containing 55--60% ash at 3--5% solids. Tests conducted over an extended period of time indicate that the column consistently maintains grade in spite of fluctuations in the feed characteristics. 12 figs.

  6. Enhanced column flotation of fine and ultrafine coal

    SciTech Connect

    Slomka, B.J.; Buttermore, W.H.; Birlingmair, D.H.; Dawson, M.R.; Pollard, J.L.; Enustun, B.V.

    1992-12-01

    A 2-inch diameter, twenty-foot tall, glass laboratory flotation column was modified to incorporate digital control of critical operating parameters. Different column control strategies were explored including location of the froth interface, and manipulation of volumetric flow ratios. Column flotation tests were performed with both fine (-250{mu}m) and ultrafine (-5{mu}m) Pittsburgh seam coal. Both moisture- and ash-free (MAF) recovery, and ash rejection were improved when the partition of the column`s liquid content into froth and tailings was directly controlled. MAF recovery and ash rejection were also enhanced by brief exposure of the coarser feed to pulsed sonic energy.

  7. A comparison study of commercially-available column flotation technologies

    SciTech Connect

    Honaker, R.Q.; Mohanty, M.K.; Paul, B.C.; Ho, K.

    1994-12-31

    A direct comparison of three commercially-available column flotation technologies, i.e., Jameson Cell, Microcel, and Packed-Column, has been conducted using a {minus}100 mesh Illinois No. 5 flotation feed coal sample. The separation performance of each flotation technology was optimized and their performance levels compared on the basis of both ash rejection, sulfur rejection, and throughput capacities. A parametric study using a statistically-designed experimental program was conducted to optimize the critical operating parameter values of each column. The ultimate performance curves for each column were generated by conducting additional tests using the optimized operating parameter values. The throughput capacity of each flotation cell was determined by conducting tests over a range of feed rates at the maximum superficial gas rate while maintaining the other parameters at their optimum values. The separation performance achieved by each of the three flotation cells was found to be comparable to the idealistic flotation performance predicted by release analysis. However, the fraction of wash water reporting to tailings (bias factor) was found to be critical in achieving the near idealistic performance. The bias factor required for the Packed-Column was found to be less than that required by the other two flotation cells. The sulfur rejection achieved by the Microcel and the Packed-Column were found to be greater than that achieved by the Jameson Cell and all three produced sulfur rejections exceeding the values obtained from release analysis. The throughput capacity, on the other hand, differed among the three flotation columns. The Jameson Cell and the Microcel were found to have comparable throughput capacities while the Packed-Column was found to have a lower capacity.

  8. Column flotation: Processes, designs and practices. Process engineering for the chemical, metals and minerals industry, Volume 2

    SciTech Connect

    Rubinstein, J.B. . Flotation Equipment and Process Engineering Dept.)

    1994-01-01

    Practically all mined ores of non-ferrous and rare metals and an increasing share of industrial minerals and coal are processed through flotation. This book presents the analysis of a wide range of problems in the process theory of flotation columns, including the first published analysis of models of flotation froths. The experience of pilot tests and commercial applications of column flotation for mineral processing and in waste water treatment circuits are also considered. This is the first book to consider column flotation design and operation experience and to present data on column parameters. Topics include: design of flotation columns; aerators in flotation columns; experimental methods of column aerohydrodynamics investigation; aerohydrodynamic characteristics of flotation columns; experimental investigation of the flotation process in columns; kinetics aspects of column flotation; scaling-up methods for flotation columns; structure and mass transfer in flotation froths; column flotation practice; and column flotation control.

  9. Column flotation shows higher recovery with less ash

    SciTech Connect

    Groppo, J.

    1986-08-01

    Why column flotation. It can effectively clean fines and yield a saleable low-ash coal from what would otherwise be the waste stream. Not only does the coal recovery improve, but the waste tonnage is reduced, thereby prolonging the life of waste storage facilities. Although regular froth flotation has proven to be an effective method for recovering fine coal (-28 mesh), flotation efficiency often drops for the finest fractions, particularly when an excessive amount of fine clays are present. Because of their small mass and momentum, these fine particles wind up in the froth and get physically entrained with particles that float. Countercurrent column flotation solves this problem by providing a stream of wash water flowing against the bubble/particle aggregates. This action allows the sticky ash to be washed from the bubble as well as from the froth. Column flotation is not new to the mining industry; it has been used to separate fine graphite from clay, and such sulfide mineral separations as molybdenum and copper. The big advantage provided by countercurrent column flotation was it required only a single step to do what cleaner flotation did in several stages.

  10. Enhanced column flotation of fine and ultrafine coal

    SciTech Connect

    Slomka, B.J.; Buttermore, W.H.; Birlingmair, D.H.; Dawson, M.R.; Pollard, J.L.; Enustun, B.V.

    1992-01-01

    A 2-inch diameter, twenty-foot tall, glass laboratory flotation column was modified to incorporate digital control of critical operating parameters. Different column control strategies were explored including location of the froth interface, and manipulation of volumetric flow ratios. Column flotation tests were performed with both fine (-250[mu]m) and ultrafine (-5[mu]m) Pittsburgh seam coal. Both moisture- and ash-free (MAF) recovery, and ash rejection were improved when the partition of the column's liquid content into froth and tailings was directly controlled. MAF recovery and ash rejection were also enhanced by brief exposure of the coarser feed to pulsed sonic energy.

  11. Coal desulfurization by bacterial treatment and column flotation. Final report

    SciTech Connect

    Kawatra, S.K.

    1994-06-01

    A review of the literature showed that bacterial leaching, using the microorganism Thiobacillus ferrooxidans, was a very effective technique for removing pyrite from coal, as it could dissolve even the finest pyrite particles without the need for expensive reagents or extreme processing conditions. Unfortunately, bacterial leaching is also rather slow, and so the initial goal of this research was to decrease the leaching time as much as possible. However, this still left the bacteria needing approximately a week to remove half of the pyritic sulfur, and so a faster technique was sought. Since it had been reported in the literature that T. ferrooxidans could be used to depress the flotation of pyrite during froth flotation of coal, this was investigated further. By studying the recovery mechanisms of coal-pyrite in froth flotation, it was found that pyrite was being recovered by entrainment and by locking to coal particles, not by true flotation of hydrophobic pyrite. Therefore, no pyrite depressant could be of any significant benefit for keeping pyrite out of the coal froth product, and it was much more important to prevent entrainment from occurring. Countercurrent flotation columns were invented to essentially eliminate entrainment effects, by washing the froth and reducing mixing of the froth and tailings products. Existing flotation columns tend to be quite simple, and in order to give reasonable product quality they must be very tall (typically 30--45 feet). As a result, they have difficulty in handling the high froth volumes which occur in coal flotation, and are awkward to install in existing plants. The bulk of this project therefore concentrated on developing an improved coal flotation column, and testing it under actual plant conditions.

  12. New aspects in the theory and practice of column flotation

    SciTech Connect

    Rubinstein, J.; Badenicov, V.

    1995-12-31

    The high efficiency of column flotation allows a reduction in process time, a decrease in the number of cleaner stages and in the volume of the circulating load in the flotation circuit, and, as a result of this, an increase in consistency and reliability of operations. Unique multisectional column flotation apparatuses were developed. To attain that aim particular hydrodynamics and aeration regime is established in each section of the column, operational variables being adjusted according to the floatability of the material. Therefore in multisectional column machines, the material-apparatus feedback can be established, and process variables optimized depending on the characteristics of the floated materials. Successful operation was reported of the new generation of columns with cell volumes of 10 to 80 m{sup 3} and the height of 4--6 m in copper, molybdenum, antimony, tungsten and nickel ores and coal slurry processing at different plants. Operational experience of these cells showed their considerable design and operational advantages and verified the proposed options and relationships. The new apparatus is provided with a pneumohydraulic aerator allowing to control bubble size distribution, the service life of the aerator is not less than two years. A multilevel flotation model was developed and used to work out a technique of column design and process parameters calculation. A method of the apparatus design parameters calculation based on laboratory test results (scaling up) was worked out.

  13. In-plant testing of microbubble column flotation

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.; Mankosa, M.J.

    1990-01-01

    During the past year, a joint project between the US Department of Energy (DOE), the Virginia Center for Coal and Minerals Processing (VCCMP) and the Shell Mining Corporation (SMC) was initiated to implement the testing of a full-scale microbubble flotation column. The work is being carried out at the Marrowbone Preparation Plant, located near Naugatuck in southwestern West Virginia. The primary objective of this effort was to determine the feasibility of using microbubble column flotation for the recovery of coal fines from a classifying cyclone overflow stream that is presently being discarded as refuse.

  14. Column flotation results at Powell Mountain Coal Company

    SciTech Connect

    Peters, W.J. Parekh, B.K. )

    1992-01-01

    In 1989 a column flotation process was developed at the CAER, which enabled the economical recovery of coal fines from high-ash fine refuse. The laboratory design was expanded to commercial scale and installed at the Mayflower Coal Preparation Plant of Powell Mountain Coal Company in December, 1989. It has been in continuous operation there since that time. This article is a summary of the past two years' experiences with this applied technology, applicable dewatering tests and flotation tests results from the plant.

  15. Column flotation research at United Coal looks to pay off

    SciTech Connect

    Merritt, P.

    1988-07-01

    Column flotation technology, designed to recover coal fines, has been the focus of research in private, university, and government laboratories for several years. While the potential of this technology continues to be scrutinized by scientists, the first commercial-size units have also been quietly placed on-line in two eastern preparation plants. The recently installed cells at both plants have gone through debugging procedures and are now achieving substantial recoveries of fine coal formerly lost to waste. For Tanoma that added production is 10.4 tph of fine coal; for United Coal, fine coal recovery exceeds 15 tph, an amount expected to rise to perhaps as much as 25 tph. The author describes how column flotation works and the systems at Tanoma Mining and United Coal.

  16. Strategy for adaptive process control for a column flotation unit

    SciTech Connect

    Karr, C.L.; Ferguson, C.R.

    1994-12-31

    Researchers at the U.S. Bureau of Mines (USBM) have developed adaptive process control systems in which genetic algorithms (GAs) are used to augment fuzzy logic controllers (FLCs). Together, GAs and FLCs possess the capabilities necessary to produce powerful, efficient, and robust adaptive control systems. To perform efficiently, such control systems require a control element to manipulate the problem environment, an analysis element to recognize changes in the problem environment, and a learning element to adjust to the changes in the problem environment. In this paper, the details of an ongoing research effort to develop and implement an adaptive process control system for a column flotation unit are discussed. Column flotation units are used extensively in the mineral processing industry to recover valuable minerals from their ores.

  17. In-plant testing of microbubble column flotation

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1990-01-01

    During the past year, a joint project between the US Department of Energy (DOE), the Virginia Center for Coal and Minerals Processing (VCCMP) and the Shell Mining Corporation (SMC) was initiated to implement the testing of a full-scale microbubble flotation column. The work is being carried out at the Marrowbone Preparation Plant, located near Naugatuck in southwestern West Virginia. The primary objective of this effort was to determine the feasibility of using microbubble column flotation for the recovery of coal fines from a classifying cyclone overflow stream that is presently being discarded as refuse. During the past quarter, results obtained using a 30-inch diameter test unit were reviewed, flowsheet layouts and preliminary scale-up projections were generated and design, engineering, fabrication and installation of the full-scale test unit was completed. Preliminary results were also obtained with the full-scale test unit and are presented in this report. 5 figs., 7 tabs.

  18. In-plant testing of microbubble column flotation

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.; Mankosa, M.J.

    1991-07-31

    Microbubble column flotation (MCF) was developed at the Virginia Center for Coal and Minerals Processing (VCCMP) for the selective recovery of fine particles. Bench-scale test work conducted at VCCMP, largely under the sponsorship of the U.S. Department of Energy (DOE), showed that the technology worked well for both coal and mineral applications. For the technology to be commercially successful, however, a full-scale demonstration of the MCF technology was deemed necessary. This report summarizes the results of work performed under the DOE project entitled In-plant Testing of Microbubble Column Flotation.'' The objectives of this research and development effort were to duplicate the bench-scale performance of the MCF process in a full-scale unit, to verify the scale-up procedure developed in an earlier project, and to demonstrate the applicability of the MCF technology to the coal industry.

  19. In-plant testing of microbubble column flotation. Final report

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.; Mankosa, M.J.

    1991-07-31

    Microbubble column flotation (MCF) was developed at the Virginia Center for Coal and Minerals Processing (VCCMP) for the selective recovery of fine particles. Bench-scale test work conducted at VCCMP, largely under the sponsorship of the U.S. Department of Energy (DOE), showed that the technology worked well for both coal and mineral applications. For the technology to be commercially successful, however, a full-scale demonstration of the MCF technology was deemed necessary. This report summarizes the results of work performed under the DOE project entitled ``In-plant Testing of Microbubble Column Flotation.`` The objectives of this research and development effort were to duplicate the bench-scale performance of the MCF process in a full-scale unit, to verify the scale-up procedure developed in an earlier project, and to demonstrate the applicability of the MCF technology to the coal industry.

  20. Initial testing of a dynamic column for fine coal flotation

    SciTech Connect

    Lai, R.W.; Patton, R.A.; He, D.X.; Joyce, T.; Chiang, S.H.

    1995-12-31

    This paper describes the design and initial performance of a dynamic column for fine coal column flotation. A dynamic column is a modified conventional column with the insertion of a series of draft tubes that provide individual mixing stages. The mixing is beneficial in generating small and uniform bubbles over a wide range of frother dosages. It is also beneficial in the control of flotation where the fluctuation of froth volume should be minimized. In the modified design, a vortex-inducing plate is attached to the top of each draft tube to create an artificial vortex. In theory the vortex action is desirable for collecting the light clean coal froth within the inner mixing zone, and for passing it upward to the next draft tube stage. The mineral laden slurry, particularly the pyrite, is accelerated outside the vortex zone by centrifugal force to reach the wall where it is carried downward to the bottom of the column. The draft tubes are arranged in a series to accomplish multistage cleaning. The experimental results showed that this dynamic column has the potential advantage of higher throughput and better product recovery as well as improved product quality.

  1. In-plant testing of microbubble column flotation

    SciTech Connect

    Luttrell, G.H.; Mankosa, M.J.; Adel, G.T.; Yoon, R.H.

    1991-01-01

    Testing of micro-bubble column flotation continued. Work during this time frame was concentrated on completion of the automated control and data acquisition system and the factorial test plan for evaluating the performance of the 8-foot column (Tasks 2.5 and 3.3). Preliminary results obtained from the factorial test program indicate that higher frother addition and aeration rates result in a higher separation efficiency. Furthermore, an increase in collector dosage results in higher column yields under most conditions. The Allen-Bradley PLC has been installed and program development completed for control of the 8-foot column. A completely automated start-up and shut-down sequence has been developed. This sequence can be initiated by the operator from a plant floor industrial interface. Instrumentation of the 30-inch column has also been completed. Testing of this instrumentation is currently underway. 11 figs., 5 tabs.

  2. Final report on agglomerate column flotation for cleaning and desulfurization of Ohio coal fines

    SciTech Connect

    Attia, Y.A.; El Zeky, M.; Yu, Mulong . Dept. of Materials Science and Engineering)

    1990-08-30

    The objective of this research program was investigate the feasibility of cleaning and desulfurization of Ohio coal by an agglomerate column flotation process, which integrates selective flocculation with conventional column flotation. It was concluded earlier on in the program that the conventional design of flotation column was not particularly efficient for pyrite rejection. A novel design for flotation column system was conceived and a prototype unit was manufactured and tested in the laboratory. Several design and operational parameters for the column and the agglomerate flotation process were briefly investigated to define proper design and working conditions for a satisfactory performance. The novel design was compared with conventional design of flotation column through laboratory tests and through published results. The role of selective flocculation of coal including selective depression of pyrite has been identified and tested with both novel and conventional design of flotation columns. The results of these brief investigations, which are summarized in this report, suggest that: (1) excellent performance ca n be obtained with agglomerate column flotation using the new design. For example, a raw coal containing 3.16% total sulfur, 2.11% pyritic sulfur, and 17% ash can be cleaned to 1.91 % ash, 0.42% pyritic sulfur, 1.32% total sulfur, while maintaining a projected Btu/coal recovery of 86% (mmmf basis). This is equivalent to 89% ash removal and 81% pyritic sulfur (58% total sulfur) rejection. (2) The novel design of flotation column is superior to conventional design particularly for pyrite rejection.

  3. Hybrid first-principles/neural networks model for column flotation

    SciTech Connect

    Gupta, S.; Liu, P.H.; Svoronos, S.A.; Sharma, R.; Abdel-Khalek, N.A.; Cheng, Y.; El-Shall, H.

    1999-03-01

    A new model for phosphate column flotation is presented which for the first time relates the effects of operating variables such as frother concentration on column performance. This is a hybrid model that combines a first-principles model with artificial neural networks. The first-principles model is obtained from material balances on both phosphate particles and gangue (undesired material containing mostly silica). First-order rates of net attachment are assumed for both. Artificial neural networks relate the attachment rate constants to the operating variables. Experiments were conducted in a 6-in.-dia. (152-mm-dia.) laboratory column to provide data for neural network training and model validation. The model successfully predicts the effects of frother concentration, particle size, air flow rate and bubble diameter on grade and recovery.

  4. Improving the performance of conventional and column froth flotation cells

    SciTech Connect

    Arnold, B.J.

    1995-11-01

    Many existing mining operations hover on the brink of producing competitively priced fuel with marginally acceptable sulfur levels. To remain competitive, these operations need to improve the yield of their coal processing facilities, lower the sulfur content of their clean coal, or lower the ash content of their clean coal. Fine coal cleaning processes offer the best opportunity for coal producers to increase their yield of high quality product. Over 200 coal processing plants in the U.S. already employ some type of conventional or column flotation device to clean fines. an increase in efficiency in these existing circuits could be the margin required to make these coal producers competitive.

  5. Frothing in flotation. Volume 2: Recent advances in coal processing

    SciTech Connect

    Laskowski, J.S.; Woodburn, E.T.

    1998-11-01

    This volume summarizes the achievements on various aspects of flotation froth properties and behavior, and relationship between froth appearance and flotation performance. Flotation kinetics involves a number of mass transfer processes with some of them being critically determined by the behavior of froth. Since froth is complex, and controlled experimentation is difficult, the froth phase was, until recently, either ignored or treated entirely empirically. With wide applications of flotation columns, the behavior of the froth is now often recognized as being dominant in determining flotation performance, and the research in this area is one of the most actively pursued. Contents include: Frothers and frothing; Effect of particle and bubble size on flotation kinetics; Water content and distribution in flotation froths; Mechanisms operating in flotation froths; Characterization of flotation froth; Simultaneous determination of collection zone rate constant and froth zone recovery factor; Modelling of froth dynamics with implications for feed-back control; The interrelationship between flotation variables and froth appearance; Froth image analysis in a flotation control system; Kinetic flotation modelling using froth imaging data; and Dependence of froth behavior on galvanic interactions.

  6. Column flotation to produce ultra-clean coal

    SciTech Connect

    Parekh, B.K.; Groppo, J.G.; Smit, F.; Jha, M.C.; Feeley, T.

    1994-12-31

    Recovery of ultra-fine (minus 200 mesh) coal can be achieved using surface chemical based techniques such as froth flotation and oil agglomeration. Column flotation technique has shown potential to produce ultra-fine clean coal with low ash at high HHV recovery. The objective of this ongoing US DOE sponsored study is to evaluate various column configuration six different types of coal to produce premium quality coal containing less than 0.6 lb/mm Btu sulfur and less than 1 lb/mm Btu ash. The other goal of the study is to produce this ultra-clean coal at a cost of about $2.50/mm Btu. Amax Research and Development Center, prime contractor on this project, and other team members selected six different coals which are low in organic sulfur and have shown potential of cleaning to low ash level. The Center for Applied Energy Research (CAER) has evaluated two different types of bubble generating systems on six different coals to produce low ash clean coal at high ({approximately}90 percent) HHV recovery.

  7. Study on the application of FCMC-1500 cyclonic microbubble flotation column for coal preparation

    SciTech Connect

    Xie Guangyuan; Ou Zeshen; Ge Mi; Wang Yongtian; Liu Jiongtian

    1997-12-31

    In this paper the cyclonic microbubble flotation column is introduced. Its structure and the principle of operation along with some results in a commercial plant are also presented. The test results have demonstrated the cyclonic microbubble flotation column to be highly selective and extremely efficient in ash rejection from fine coals, oil consumption, and energy conservation. It has a great future for commercialization.

  8. In-plant testing of microbubble column flotation

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1990-01-01

    A project to evaluate the performance of the Virginia Tech Microbubble Column Flotation (MCF) process in an operating coal preparation plant was continued during this past quarter. The project is concerned with the collection of process operating data using a 30-inch diameter column, and using these data to scale-up to a prototype, full-scale plant column. The work is being carried out at the Marrowbone Preparation Plant owned by the Shell Mining Corporation. Work during the past reported period primarily concentrated on the completion of a parametric study to evaluate the performance of the 30-inch diameter column. The preliminary results obtained from the parametric study suggest that higher gas flow rates and frother additions appear to have a beneficial effect on separation efficiency. However, under these conditions, a larger wash water flow rate was necessary to offset the increased flow of feed water to the product stream. The parametric testing results indicated that the height of the stabilized froth zone had only a limited impact on the separation efficiency, except under conditions of high feed rates. A more detailed analysis of the response surface data is currently under way. Work in other areas (Task 2.5 - Control systems and Task 3.3 - Column Testing) is continuing, but has progressed at a slower pace than originally anticipated. The appendix contains data on energy recovery, product ash content, sulfur rejection, and separation efficiency. 32 figs., 5 tabs.

  9. Method for enhancing selectivity and recovery in the fractional flotation of particles in a flotation column

    DOEpatents

    Klunder, Edgar B.

    2011-08-09

    The method relates to particle separation from a feed stream. The feed stream is injected directly into the froth zone of a vertical flotation column in the presence of a counter-current reflux stream. A froth breaker generates a reflux stream and a concentrate stream, and the reflux stream is injected into the froth zone to mix with the interstitial liquid between bubbles in the froth zone. Counter-current flow between the plurality of bubbles and the interstitial liquid facilitates the attachment of higher hydrophobicity particles to bubble surfaces as lower hydrophobicity particles detach. The height of the feed stream injection and the reflux ratio may be varied in order to optimize the concentrate or tailing stream recoveries desired based on existing operating conditions.

  10. A comparison study of column flotation technologies for cleaning Illinois coal. Final technical report, September 1, 1993--November 30, 1994

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.

    1994-12-31

    Six commercially-available column technologies were compared on the basis of their separation performance, throughput capacity and operational characteristics for treating Illinois Basin coal fines. The flotation column technologies included in this study were the Jameson Cell, Flotaire, Turboair, Packed-Column, Microcel and the Canadian Column. The coal samples treated in this study were a {minus}100 mesh flotation feed slurry, a {minus}40 mesh coal, and a refuse pond coal sample. This investigation found that the Packed Column, Jameson Cell, and Microcel are the best flotation columns for cleaning the Illinois Basin coals treated in this study. The Packed-Column was found to provide superior selectivity, although requiring the highest amount of air and frother concentration. The superior performance is believed to be related to the extensive reflux action and selective detachment mechanism that are more prevalent in the Packed-Column due to its unique ability to support a full froth column. Among the conventional open columns, the Microcel provided the best selectivity, most likely due to its lower aeration requirement which results in a more plug-flow environment within the cell. Both the Packed-Column and the Microcel appeared to have nearly equal throughput capacities. The Jameson Cell, which also has a relatively high throughput capacity, was found to require the least amount of frother while supplying a self-inducing air system. Another important finding of this investigation is that the traditional release analysis procedure is inadequate for predicting the optimum performance of advanced froth flotation processes and, thus, requires further investigation.

  11. Evaluation of column flotation for fine coal cleaning at the Lady Dunn Preparation Plant

    SciTech Connect

    Jha, M.C.; Smit, F.J.; Fish, L.; Toney, T.A.; Phillips, D.I.; Feeley, T.J. III

    1996-12-31

    In 1992, Pittsburgh Energy Technology Center (PETC) of the Department of Energy (DOE) awarded a cost-sharing contract to a team headed by Amax R&D Inc. The contract was to develop advanced cleaning technologies for production of low-ash, premium fuel from coal. Entech Global of Golden, Colorado, now manages this contract for Amex R&D, and Cyprus Amex Coal Company, Arcanum, Bechtel, University of Kentucky and Virginia Tech are among the team members. Two advanced technologies were selected for development, column flotation and selective agglomeration. Even though production of premium fuel is the primary goal of the project, the DOE asked that near-term applications of these advanced technologies be investigated as well in order to learn how they might be used to recover coal now being discarded from existing preparation plants as fine refuse The resulting investigation of near-term applications began with an engineering analysis or paper study of potential applications at Amax Coal operations. The project continued with further laboratory and bench-scale process development and culminated with the installation of a pilot-scale advanced flotation column at the Lady Dunn Preparation Plant. The results of this cooperation between the Department of Energy and the coal industry are described in this presentation.

  12. Hydrocarbon-oil encapsulated bubble flotation of fine coal using 3-in. ID flotation column. Technical progress report for the eleventh quarter, April 1--June 30, 1993

    SciTech Connect

    Peng, F.F.

    1996-05-01

    There are four modes of the collector dispersion techniques. They are (1) direct liquid additions and stirring, (2) ultrasonic energy collector dispersion, (3) atomized collector dispersion, and (4) gasified collector transported in air stream. Among those collector dispersion techniques, the technique using the gasified collector transported in air phase can be used to enhance the flotation performance with substantial reduction in collector usage and selectivity, compared to the flotation using direct liquid addition (and mechanical agitation) technique. In this phase of study, two modes of collector addition techniques including gasified collector transported in gas phase and direct collector addition techniques were applied in the column flotation to demonstrate the selectivity of utilizing the hydrocarbon-oil encapsulated air bubbles in the fine coal flotation process. The 1-in. ID flotation column was used to scale-up to 3-in. ID flotation column. The initial starting point to operate the 3-in ID flotation column were determined using both 1-in. and 3-in. flotation columns based on the three phases of work plans and experiment design. A 3-in. flotation column was used to evaluate two modes of collector dispersion and addition techniques on the recovery and grade of fine coals using various ranks of coal.

  13. Method and apparatus for column flotation of mineral matter

    SciTech Connect

    Trigg, R.D.

    1990-10-30

    This patent describes a method for the separation of the components of a slurry of ore by froth flotation in a vertically aligned, elongated zone having an upper section, an intermediate section and a lower section. Also described is an apparatus for the separation of components of a slurry of ore by froth flotation.

  14. Implementation of Microcel{trademark} column flotation for processing fine coal

    SciTech Connect

    Davis, V.L. Jr.

    1993-12-31

    Laboratory and pilot-scale test programs have been conducted in order to evaluate the performance of column and conventional flotation circuits for the processing of fine coal. The tests were conducted on-site at several operating coal preparation facilities by utilization of Pilot-scale conventional and column flotation cells. The feed to the test equipment in each case was classifying cyclone overflow material that was high in ash content (40%--50%) with solids content values in the 5%--10% range. The test results indicated that column flotation Provided superior metallurgical performance (approaching that attained by release analysis techniques) as compared to single pass and rougher/cleaner conventional flotation. The results of this study eventually led to the installation of 5--10 foot diameter column flotation cells at the Middle Fork pond reclaim facility. It was determined that the installation of the flotation columns at the Middle Fork facility led to a reduction in concentrate ash of approximately 7 percentage points and an increase in combustible recovery in excess of 15 percentage points.

  15. Separation of algal cells from water by column flotation

    SciTech Connect

    Liu, J.C.; Chen, Y.M.; Ju, Y.H.

    1999-08-01

    The dispersed air flotation (DiAF) process was utilized to separate algal cells (Chlorella sp.) from water. Two types of collector, cationic N-cetyl-N,N,N-trimethylammonium bromide (CTAB) and anionic sodium dodecylsulfate (SDS), were used. It was observed that 20% of cell removal was achieved in the presence of 40 mg/L of SDS, and ca. 86% of the cells were removed at 40 mg/L of CTAB. Upon the addition of 10 mg/L of chitosan, over 90% of the cells were removed when SDS (20 mg/L) was used as the collector. Air flow rate affected cell flotation slightly. Optimum pH values for cell flotation were from 4.0 to 5.0. Flotation efficiency decreased at high ionic strength. The electrostatic interaction between collector and cell surface plays a critical role in the separation processes.

  16. A modified release analysis procedure using advanced froth flotation mechanisms. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect

    Honaker, R.Q.; Mohanty, M.K.

    1997-05-01

    Recent studies indicate that the optimum separation performances achieved by multiple stage cleaning using various column flotation technologies and single stage cleaning using a Packed-Flotation Column are superior to the performance achieved by the traditional release procedure, especially in terms of pyritic sulfur rejection. This superior performance is believed to be the result of the advanced flotation mechanisms provided by column flotation technologies. Thus, the objective of this study was to develop a suitable process utilizing the advanced froth flotation mechanisms to characterize the true flotation response of a coal sample. This investigation resulted in the development of a modified coal flotation characterization procedure, termed as the Advanced Flotation Washability (AFW) technique. The apparatus used for this procedure is a batch operated Packed-Column device which provides enhanced selectivity due to a plug-flow environment and a deep froth zone. The separation performance achieved by the AFW procedure was found to be superior to those produced by the conventional tree and release procedures for three nominally -100 mesh coal samples and two micronized samples. The largest difference in separation performance was obtained on the basis of product pyritic sulfur content. A comparison conducted between the AFW and the release procedures at an 80% recovery value showed that the AFW technique provided a 19% improvement in the reduction of pyritic sulfur. For an Illinois No. 5 coal sample, this improvement corresponded to a reduction in pyritic sulfur content from 1.38% to 0.70% or a total rejection of 66%. Micronization of the sample improved the pyritic sulfur rejection to 85% while rejecting 92% of the ash-bearing material. In addition, the separation performance provided by the AFW procedure was superior to that obtained from multiple cleaning stages using a continuous Packed-Column under both kinetic and carrying-capacity limiting conditions.

  17. Deinking of recycled pulps using column flotation: Energy and environmental benefits

    SciTech Connect

    Chaiarrekij, S.; Dhingra, H.; Ramarao, B.V.

    1999-07-01

    Deinking of recycled pulps is an important operation intended to provide pulps appropriate for making paper and paperboard products from recycled wastepaper. Conventionally, deinking of recycled pulp is conducted in a flotation cell equipped with an agitator. The authors have investigated the applicability of a new flotation cell based on a column without an agitator present to accomplish the deinking of typical wastepaper feedstocks and also a feedstock consisting of rejects from a conventional deinking cell. Experimental results on the deinking operation indicate that it is possible to achieve deinking of a mixture of photocopier and laserprinted paper in the column flotation cell. The performance of the column as measured by the resultant pulp's brightness and ink particle size distributions is comparable to that of a conventional laboratory cell which incorporates severe agitation regimens. Thus, it is found that the agitator can be eliminated by using the column flotation design which could yield significant electrical energy savings in addition to savings in capital costs and other operational and maintenance costs. A series of deinking experiments were also performed on a feedstock consisting of rejected waste obtained from a conventional cell in a pilot plant. The authors found that de-inking of the rejected waste could yield significant usable fiber. This indicates the potential of the column flotation technique in enhancing the reuse of a waste component thus reducing the volume of deinking waste rejected into the environment.

  18. A modified release analysis procedure using advanced froth flotation mechanisms: Technical report, March 1, 1996-May 31, 1996

    SciTech Connect

    Honaker, R.Q., Mohanty, M.K.

    1997-04-01

    Recent studies indicate that the optimum separation performances achieved by multiple stage cleaning using various column flotation technologies and single stage cleaning using a Packed-Flotation Column are superior to the performance achieved by the traditional release procedure, especially in terms of pyritic sulfur rejection. This superior performance is believed to be the result of the advanced flotation mechanisms provided by column flotation technologies. Thus, the objective of this study is to develop a suitable process utilizing the advanced froth flotation mechanisms to characterize the true flotation response of a coal sample. Work in this reporting period concentrated on developing a modified coal flotation characterization procedure, termed as Advanced Flotation Washability (AFW) technique. The new apparatus used for this procedure is essentially a batch operated packed-column device equipped with a controlled wash water system. Several experiments were conducted using the AFW technique on a relatively high sulfur, -100 mesh Illinois No. 5 run-of-mine coal sample collected from a local coal preparation plant. Similar coal characterization experiments were also conducted using the traditional release and tree analysis procedures. The best performance curve generated using the AFW technique was found to be superior to the optimum curve produced by the traditional procedures. For example, at a combustible recovery of 80%, a 19% improvement in the reduction of the pyritic sulfur content was achieved by the AFW method while the ash reduction was also enhanced by 4%. Several tests are on-going to solidify the AFW procedure and verify the above finding by conducting Anova analyses to evaluate the repeatability of the AFW method and the statistical significance of the difference in the performance achieved from the traditional and modified coal characterization procedures.

  19. Use of hydrocyclone and flotation column for reducing the volume of contaminated dredged material.

    PubMed

    Park, K H; Lee, J H; Bae, B H; Kim, Y H; Choung, Y K

    2006-01-01

    As sediment contamination problems have recently been raised in Korea, the need for technologies to clean contaminants in sediments has increased. Although the recalcitrant organic matters and heavy metals in the contaminated sediments are of primary concern, large amounts of sediment makes the removal of the contaminants in them more difficult. In this study, the performance of hydrocyclone and flotation column was tested to reduce the volume of contaminated dredged materials (CDMs) prior to treating recalcitrant matters, such as various organic chemicals and heavy metals, in an integrated treatment system. When hydrocyclone was operated with 10% (w/v) solids concentration of the feed slurry, the total solids of upflow products were 4 to 7% (w/v) when the inlet pressure was changed from 1.0 to 2.0 kg/cm2. The volume reduction ratio of CDMs by hydrocyclone was approximately 90% (v/v). When the upflow products in hydrocyclone was then spiked with automobile transmission oil and fed to the flotation colum to see the performance of the column flotation on the volume reduction and the TPH removal, 44% of the TPHs in feed were removed at the tails and the volume reduction ratio of CDMs by column flotation was 18% at 200 L/min of wash water. The flotation column could be proposed as a potential preliminary treatment process of CDMs prior to subsequent biological treatments.

  20. An experimental study on desulfurization of high-sulfur coal slime with free jet flotation column

    SciTech Connect

    Xie Hua; Huang Bo; Xia Qing

    1998-12-31

    A free jet flotation column gives good selectivity and high separation efficiency in treating fine and ultra-fine coal. This paper reports test results of coal desulfurization with a free jet flotation column. Test results showed that when the coal sample from Zhong Liang Shan was processed its pyritic sulfur content was reduced from 3.08% to 0.84%, with 72.22% recovery of combustible matter in clean coal. The concept of Desulfurization Efficiency Index E(ds) for a comprehensive evaluation of desulfurization process is proposed, which is defined as the product of the ratio of sulfur content reduction and the recovery of combustible matters in clean coal.

  1. A modified release analysis procedure using advanced froth flotation mechanisms. Technical report, September 1--November 30, 1995

    SciTech Connect

    Honaker, R.Q.; Mohanty, M.K.

    1995-12-31

    The objective of this study is to reinvestigate the release analysis procedure, which is traditionally conducted using a laboratory Denver cell, and to develop a modified process that can be used for all froth flotation technologies. Recent studies have found that the separation performance achieved by multiple stage cleaning and, in some cases, single stage cleaning using column flotation is superior to the performance achieved by the traditional release procedure. These findings are a result of the advanced flotation mechanisms provided by column flotation, which will be incorporated into a modified release analysis procedure developed in this study. A fundamental model of an open column has been developed which incorporates the effects of system hydrodynamics, froth drop-back, selective and non-selective detachment, operating parameters, feed solids content, and feed component flotation kinetics. Simulation results obtained during this reporting period indicate that the ultimate separation that can be achieved by a column flotation process can only be obtained in a single cleaning stage if the detachment mechanism in the froth phase is highly selective, which does not appear to occur in practice based on experimental results. Two to three cleaning stages were found to be required to obtain the ultimate performance if non-selective detachment or kinetic limiting conditions are assumed. this simulated finding agrees well with the experimental results obtained from the multiple stage cleaning of an Illinois No. 5 seam coal using the Packed-Column. Simulated results also indicate that the separation performance achieved by column flotation improves with increasing feed solids content after carrying-capacity limiting conditions are realized. These findings will be utilized in the next reporting period to modify the traditional release analysis procedure.

  2. Engineering development of advanced physical fine coal cleaning technolgies: Froth flotation

    SciTech Connect

    Not Available

    1991-01-01

    The Task 6 effort involves three main elements including column cell development, flotation circuit testing and flotation cell modeling. The work outlined is to research column designs and operation parameters in developing an optimized column flotation cell (OCFC) to meet the overall program objectives. Any design parameters that were not evaluated as part of the optimized column development work will be reviewed and tested so as to incorporate all possible scenarios in presenting DOE with the best available flotation process for use in the 2 to 3 ton per hour POC. Following development of the OCFC, various flotation circuit configurations will be evaluated determine the best'' circuit design for the 2 to 3 ton per hour POC. Single and multiple stage flotation, grab and run, rougher/scavenger/cleaner, etc., test circuits will be tested as part of this effort. Upon completion of this test work, the best'' possible flotation cell will have been tested in a number of possible flotation circuit designs to possibly provide the best'' flotation approach in meeting the design criteria. In conjunction with the flotation test effort, model development work will be conducted to provide a tool in evaluating the various flotation circuit configurations and in predicting flotation performance. The model will be useful in selecting operating conditions in the POC and in evaluating the performance of the POC.

  3. Removal of unburned carbon from municipal solid waste fly ash by column flotation.

    PubMed

    Huang, Ying; Takaoka, Masaki; Takeda, Nobuo

    2003-01-01

    Unburned carbon (UC) is the major source of organic contaminants in municipal solid waste (MSW) fly ash. So most organic contaminants can be removed by the removal of the UC from the MSW fly ash. In this paper, we first used a technique of column flotation to remove UC from MSW fly ash. The influences of column flotation parameters on the recovery efficiency of UC were systematically studied. It was found that the UC recovery efficiency was greatly influenced by the gas flow rate, pH value, collector kerosene's concentration and the types of fly ash. By optimizing the above parameters, we have successfully removed 61.2% of the UC from MSW fly ash having 5.24% UC content. The removal mechanism was well accounted for the kinetic theory of column flotation and surface-chemistry theory. The results indicate that the column flotation technique is effective in removing the UC from MSW fly ash, and show that there is a strong possibility for practical application of this technique in removing the organic contaminants from MSW fly ash.

  4. Column flotation monitoring based on electrical capacitance volume tomography: A preliminary study

    NASA Astrophysics Data System (ADS)

    Haryono, Didied; Harjanto, Sri; Nugraha, Harisma; Huda, Mahfudz Al; Taruno, Warsito Purwo

    2017-01-01

    A preliminary study of column flotation monitoring process using electrical capacitance volume tomography (ECVT) was conducted. ECVT was one of the monitoring systems which based on the capacitance measurement. It was used to understand the phenomenon that occurs inside the column in a three-dimensional (3-D) image. A linear back projection (LBP) algorithm technique was used to reconstruct the 3-D ECVT images from all measurement data obtained in this study. As a preliminary study, the effect of gas injection in the two-phase (liquid and gas) system was conducted. This study is conducted to assess the possibility of ECVT system in the monitoring of column flotation process. The experiments were conducted by using column flotation with 5 cm diameter and 150 cm height in which a sparger was installed at the bottom of column to inject air inside the column. 32-CH rectangular ECVT sensor was installed at 13 cm above the sparger and placed around the column. The gas injection variations used were 2-7 l/min with interval 1 l/min and all experiments were conducted at room temperature. Based on the signal and image analysis, the signals and 3-D ECVT images showed differences when the gas injection was varied. An increase in gas injection will decrease the fluctuation of signal intensity which correlates to the 3-D ECVT images. Average signals obtained by ECVT when given gas injection variations were in the range of 440.09 to 453.62 mV from high to low gas injection. Based on these results, ECVT has a prospect as an imaging tool to monitor the column flotation process. And also, hopefully, based on the analysis of 3-D images generated by ECVT system, the metallurgical performance would be analyzed in the further researches.

  5. Engineering development of advanced froth flotation. Volume 2, Final report

    SciTech Connect

    Ferris, D.D.; Bencho, J.R.; Torak, E.R.

    1995-03-01

    This report is an account of findings related to the Engineering and Development of Advanced Froth Flotation project. The results from benchscale and proof-of-concept (POC) level testing are presented and the important results from this testing are used to refine a conceptual design and cost estimate for a 20 TPH Semi-Works Facility incorporating the final proposed technology.

  6. Foam flotation

    SciTech Connect

    Clarke, A.N.; Wilson, D.J.

    1983-01-01

    This book is a review of precipitate and absorbing colloid flotation and mathemataical analyses of physical models regarding foam flotation phenomena. Over 800 literature references are cited. Contents include some fluid mechanical aspects of particle flotation, theoretical aspects of particulate flotation, column design considerations, solvent sublation, the future and appendices.

  7. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Diao, J.; De, A.; Sotillo, F.; Harris, G. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, W.; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (United Stat

    1991-05-15

    The primary objective in the scope of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from three major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Investigation of mechanisms for the control of coal and pyrite surfaces prior to fine coal flotation is the main aspect of the project objectives. Research topics covered during this quarter include the characterization of the base coals, various flotation studies on optimization and pyrite rejection, and a detailed flotation kinetic study. The effect of hexanol, butanol, dodecane, and polyethylene glycol on flotation is described. A second major objective is to investigate factors involved in the progressive weathering and oxidation of coal that had been exposed to varying weathered degrees, namely, open, covered and in an argon-inerted'' atmosphere, over a period of twelve months. After regular intervals if weathering, samples of the three base coals (Illinois No. 6, Pittsburgh No. 8 and Upper Freeport PA) were collected and shipped to both the University of Pittsburgh and the University of California at Berkeley for characterization studies of the weathered material. 35 figs., 17 tabs.

  8. Selection of feed coals for production of premium fuel using column flotation and selective agglomeration processes

    SciTech Connect

    Jha, M.C.; Smit, F.J.

    1995-10-01

    Column flotation and selective agglomeration are promising advanced physical cleaning processes that can be developed for preparing premium quality coal-water slurry fuel from coal fines. Such a fuel could either replace oil or natural gas in certain industrial and utility boilers or else could be burned in advanced combustors currently under development. These applications require coal cleaned to sulfur and ash contents below 258 g/GJ and 430--860 g/GJ (0.6 lb/million Btu and 1--2 lb/million Btu), respectively, to meet clean air emission requirements. A highly loaded slurry must be produced in order to avoid derating the boilers, and the total cost of the fuel must be below $2.37/GJ ($2.50/million Btu) in order to penetrate the market by the turn of the century. Achieving these technical and economic goals depend critically on the selection of suitable feed coals. This paper describes the identification and evaluation of 18 coals and final selection of six coals from different regions of the United States as potential feedstock for preparation of premium fuel. The work is being performed under a cost-shared DOE project.

  9. Comparing the effect of biosurfactant and chemical surfactant on bubble hydrodynamics in a flotation column.

    PubMed

    Wang, Huanran; Yang, Jingjing; Lei, Shaomin; Wang, Xinbing

    2013-01-01

    Bubble hydrodynamics is fundamental to the performance of the flotation process widely used in the separation industry. To compare the effect of biosurfactants and chemical synthetic surfactants on bubble hydrodynamics in the flotation process, the motion of a single bubble and the size distribution of bubble swarms in various surfactants (rhamnolipid, tea saponin and Triton X-100) solutions were observed directly using a high-speed video camera in a laboratory scale flotation column. Bubble trajectory, dimensions, velocity and size distribution were then determined through image analysis. The results indicated that the addition of biosurfactants had the same significant effects on bubble motion and size distribution as chemosynthetic surfactants. The biosurfactant effect on bubble behavior was also found to depend on their type and concentration. In general, the effect of tea saponin was stronger than another biosurfactant (rhamnolipid) used in the present study. The present findings implied that some biosurfactants like tea saponin can replace chemosynthetic surfactants in controlling bubble behavior in flotation operation. This will contribute to promoting the use of green environmentally friendly flotation agents in the separation industry.

  10. Experimental and modeling evaluation of upward and downward velocities in the coaxial flotation column.

    PubMed

    Park, K; Cho, J M; Oh, J; Chung, K

    2001-01-01

    This study was conducted to show the influence of upward velocity in the inner column and downward velocity in the outer column of the coaxial cylinder-type flotation column on the solids removal efficiency, solids concentration in the treated water, and so on. The SIMPLE (Semi-Implicit Method for Pressure Linked Equation) solution was applied to the coaxial flotation column to simulate the velocity vectors of the elements of water flowing in the column. The effects of solids loading and residence time in the agglomerate separation zone on the solids removal efficiency were also tested. In the pilot scale coaxial DAF column experiments with solids concentration of 1,000-2,000 mg of SS per liter and solids loading less than 350 kg/m2/day, approximately 90% of the solids removal efficiencies were obtained using the upward velocity of up to 110 cm/min in the contact zone of the inner column and the downward velocity of up to 30 cm/min in the outer column. In the simulation, similar results were observed as in the experiments. The solids loading in the excess of 350 kg/m2/day caused the instability of the sludge float layer and aggravated the quality of the treated water.

  11. Continuous pilot-scale testing of column flotation for recovery of fine coal

    SciTech Connect

    Groppo, J.G.; Parekh, B.K. . Center for Applied Energy Research)

    1990-10-01

    A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150{mu}m (100 mesh) {times} 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

  12. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, Weibai; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. )

    1990-08-15

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  13. Effect of bubble generating devices on recovery of clean coal from refuse using column flotation

    SciTech Connect

    Parekh, B.K.; Groppo, J.G.

    1994-12-31

    Column flotation testing was conducted on the flotation feed slurry obtained from a preparation plant located in the southern Illinois coal basin using three different bubble generating devices, static sparger, gas saver and foam jet. Each of these devices were tested with three different types of frother and various column operating variables to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. Alcohol frothers were most effective for use with the static sparger, somewhat less effective for the foam jet and ineffective for the gas saver. Glycol frothers were effective for all three bubble generating systems, providing high combustible recovery (>90 percent), low clean coal ash (4-6 percent ash) and high pyrite rejection (70-80 percent).

  14. Gas holdup in cyclone-static micro-bubble flotation column.

    PubMed

    Li, Xiaobing; Zhu, Wei; Liu, Jiongtian; Zhang, Jian; Xu, Hongxiang; Deng, Xiaowei

    2016-01-01

    The present work has been carried out to investigate the effect of process variables on gas holdup and develop an empirical equation and a neural network model for online process control of the gas holdup based on the operating variables. In this study, the effect of process variables (nozzle diameter, circulation pressure, aeration rate, and frother dosage) on gas holdup in a cyclone-static micro-bubble flotation column of an air/oily wastewater system was investigated. Gas holdup was estimated using a pressure difference method and an empirical equation was proposed to predict gas holdup. A general regression neural network (GRNN) model was also introduced to predict gas holdup for the cyclone-static micro-bubble flotation column. The predictions from the empirical equation and the GRNN are in good agreement with the experiment data for gas holdup, while the GRNN provides higher accuracy and stability compared with that of the empirical equation.

  15. Comparison of coagulants and coagulation aids for treatment of meat processing wastewater by column flotation.

    PubMed

    de Sena, Rênnio F; Moreira, Regina F P M; José, Humberto J

    2008-11-01

    The physicochemical treatment of the wastewater from a meat processing industry was studied using three ferric salts as coagulants in conjunction with four different polymers as coagulation aids by batch column flotation. The effluent was characterized in terms of pH (6.5-6.7), turbidity (1000-12000 NTU), total solids (TS) (2300-7000mgl(-1)), oils and greases (OG) (820-1050mgl(-1)), and biochemical and chemical oxygen demands (BOD(5) and COD) (1200-1760 and 2800-3230mgl(-1)), respectively. The treatments achieved typical organic load reductions of oils and greases, and total solids (up to 85%), as well as biochemical and chemical oxygen demands (between 62.0-78.8% and 74.6-79.5%, respectively). The research also found that the utilization of a column flotation achieved high efficiency of organic matter removal and its operation as a primary treatment showed no significant dependence of pollutant removal and air flow rate.

  16. Verification of a model for foam flotation column operation

    SciTech Connect

    Kiefer, J.E.; Rodriguez, J.; McIntyre, G.; Thackston, E.L.; Wilson, D.J.

    1982-01-01

    We report experimental data testing the validity of a mathematical model for the time-dependent operation of a continuous-flow foam floating column.Sodium lauryl sulfate was the surfactant being removed. The responses of the column in steady-state operation and under the influence of rectangular pulses in sodium lauryl sulfates concentration and in hydraulic loading rate were investigated and compared with the results of computer simulation.Effluent surfactant concentrations were well simulated under all conditions. It was found that the fraction of liquid in the Plateau borders varies somewhat with the hydraulic loading rate, which causes some discrepancy between calculated and observed collapsed foamate flow rates.

  17. Fine coal flotation plant waste comparison--column vs. sub-a cells

    SciTech Connect

    Ehrlinger, H.P. III.

    1991-01-01

    The objective of this project was to compare results from a small commercially sized Deister Flotaire column flotation cell with the subaeration cells at Kerr-McGee's Galatia plant during side by side testing of feed splits from the same sources. Typical cell criteria for both cells are included in the appendix. The project involved the activities of three organizations: the Kerr-McGee Coal Corporation, the Deister Concentrator Company, and the Illinois State Geological Survey. Their roles were as follows: Kerr-McGee installed the Deister column with sample splitter and tailings volume measuring cell in the Galatia Coal Preparation Plant to treat a representative split of their flotation feed; Deister provided a 30 inch diameter {times} 35{prime} high Deister Flotaire Column Flotation Cell capable of treating nominally one ton per hour or slightly over 1% of the plant feed. Deister additionally provided the sample splitter and the tailings volume measuring cell. ISGS personnel worked with both companies on the installation, conducted laboratory tests to direct the early plant test reagent practice, attended all of the plant runs cutting representative samples of feed, measuring slurry and reagent flows, preparing samples and writing reports.

  18. A comparison study of column flotation technologies for cleaning Illinois coal. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.

    1994-06-01

    The objectives of this research project are to optimize the performance of six commercially available column technologies for the treatment of Illinois Basin coal fines and to compare their performance on the basis of the recovery-grade curve and column throughput capacity. A statistically-designed, experimental program will be conducted to optimize the critical operating performance values of each flotation column. During the previous reporting period, construction and installation of the six flotation columns were completed. The flotation feed sample that will be used for the tests in this investigation was collected from a coal preparation plant treating the Illinois No. 5 seam coal. During this reporting period, the flotation feed sample was characterized on a size-by-size basis for its ash, total sulfur, and BTU content. A release analysis was also conducted to obtain the best possible recovery versus product grade curve that can be achieved by a froth flotation process for the treatment of the Illinois No. 5 flotation feed sample. Experiments were initiated on the Jameson Cell. The preliminary results indicate that the Jameson Cell achieves a separation performance that is close to the release data. The experimental program on the Jameson Cell and the other flotation technologies will be performed during the next reporting period.

  19. Combined column and cell flotation process for the treatment of PAH contaminated hazardous wastes produced by an aluminium production plant.

    PubMed

    Dhenain, Aurélie; Mercier, Guy; Blais, Jean-François; Chartier, Myriam

    2009-06-15

    The aluminium electrolytic plants generate PAH and fluoride contaminated wastes which are usually classified as hazardous material. These residues are generally disposed in secure landfill sites. A flotation cell process was previously developed to remove PAH from these aluminium industry wastes. The tests were done on composite samples made of particle size fractions under 50mm. The efficiency of the flotation cell process was demonstrated but the high quantity of concentrate produced (14.0%) during the air injection period, because of the solid entrainment, raised the treatment cost. The aim of this study was to reduce the entrainment of fine particles in order to obtain an efficient and economic technology. The process initially developed was modified: the smallest particle size fraction (<0.5mm) of the composite sample was treated in a flotation column, whereas the other particle size fractions (0.5-50mm) were treated in a flotation cell. The separated treatment allowed to reduce the entrainment during the air injection period of the flotation cell step from 14.0% to 10.1%. The optimum total solids of the pulp and cocamidopropylhydroxysultaine (CAS) concentration were 3.33% and 0.50% (ww(-1)) for the flotation column, and 15% and 0.25% (ww(-1)) for the flotation cell. This combined flotation process minimized the total entrainment which allowed a 23.6% abatement of the concentrate quantity initially produced, and reduced the PAH concentrations of the wastes under the authorized limit of 1000 mg kg(-1).

  20. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Diao, J.; De, A.; Sotillo, F.; Harris, G. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, Weibai; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (United

    1991-07-30

    The primary objective in the scope of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from three major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Investigation of mechanisms for the control of coal and pyrite surfaces prior to fine coal flotation is the main aspect of the project objectives. The results of this research are to be made available to ICF Kaiser Engineers who are currently working on the Engineering Development of Advanced Flotation under a separate contract with DOE under the Acid Rain Control Initiative program. A second major objective is to investigate factors involved in the progressive weathering and oxidation of coal that had been exposed to varying degrees of weathering, namely, open to the atmosphere, covered and in an argon-inerted'' atmosphere, over a period of twelve months. After regular intervals of weathering, samples of the three base coals (Illinois No. 6, Pittsburgh No. 8 and Upper Freeport PA) were collected and shipped to both the University of Pittsburgh and the University of California at Berkeley for characterization studies of the weathered material. 29 figs., 29 tabs.

  1. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    The Task 6 effort involves three main elements including column cell development, flotation circuit testing and flotation cell modeling. The work outlined is to research column designs and operation parameters in developing an optimized column flotation cell (OCFC) to meet the overall program objectives. The test results obtained through this effort will be evaluated against the results obtained from the round-robin test program in Task 5. Any design parameters or operating conditions that are unique with the round-robin test winner that were not evaluated as part of the optimized column developments work will be reviewed and tested so as to incorporate all possible scenarios in presenting DOE with the best available flotation process for use in the 2 to 3 ton per hour POC. Following development of the OCFC, various flotation circuit configurations will be evaluated determine the best'' circuit design for the 2 to 3 ton per hour POC. Single and multiple stage flotation, grab and run,rougher/scavenger/cleaner, etc., test circuits will be tested as part of this effort. Upon completion of this test work, the best'' possible flotation cell will have been tested in a number of possible flotation circuit designs to possibly provide the best'' flotation approach in meeting the design criteria. In conjunction with the flotation test effort, model development work will be conducted to provide a tool in evaluating the various flotation circuit configurations and in predicting flotation performance. The model will be useful in selecting operating conditions in the POC and in evaluating the performance of the POC.

  2. Recovery of fine coal using column flotation at Powell Mountain Coal Company

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Peters, W.J.

    1994-12-31

    A joint project was initiated in 1989 between the University of Kentucky Center for Applied Energy Research (CAER) and the Powell Mountain Coal Company (PMCC) to evaluate the applicability of column flotation for recovery of fine coal from classifying cyclone refuse at PMCC`s Mayflower Preparation Plant. Laboratory and extensive pilot plant studies were conducted on each of the seams processed by the plant evaluating various column operating parameters. These results were used to design a larger 8-ft. diameter x 22-ft. tall column capable of recovering fine coal from the dilute classifying cyclone overflow with a feed capacity of 1,000 gpm. In order to effectively treat the entire plant classifying cyclone overflow stream, a total of four columns operating in parallel were installed in December 1989. This paper outlines four years of operating experience and results obtained with this fine coal recovery circuit.

  3. Three years of column flotation operating experience at Powell Mountain Coal Company

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Peters, W.J.; Kennedy, D.L.

    1993-12-31

    A joint project was initiated in 1989 between the University of Kentucky Center for Applied Energy Research (CAER) and the Powell Mountain Coal Company (PMCC) to evaluated the applicability of column flotation for recovery of fine coal from classifying cyclone refuse at PMCC`s Mayflower Preparation Plant. Laboratory and extensive pilot plant studies were conducted on each of the seams processed by the plant evaluating various column operating parameters. These results were used to design a larger 8-ft. diameter {times} 22-ft. tall column capable of recovering fine coal from the dilute classifying cyclone overflow with a feed capacity of 1,000 gpm. In order to effectively treat the entire plant classifying cyclone overflow stream, a total of four columns operating in parallel were installed in December 1989. This paper outlines three years of operating experience and results obtained with this fine coal recovery circuit.

  4. Separating mixed waste plastics in a flotation column

    SciTech Connect

    Biddulph, M.W.; Chow, P.S.; Cloke, M.

    1996-12-31

    This paper describes efforts to develop a continuous separation technique for mixed waste plastics to facilitate subsequent recycling. Selective wetting of the surfaces is used as the separating criterion, and Critical Surface Tension values for various commercial plastic materials have been determined. This has demonstrated the feasibility of the technique. Although the technique has been applied using solvent systems, the method investigated here is the use of surface active agents. Previously batch systems have been reported, but the development of a continuous process requires a much better understanding of dynamic surface tension effects. Detailed studies of the effects of air bubble size and particle size have been made using very high speed video techniques. From these observations, the collision behavior of a bubble against the plastic surface was found to be markedly affected by bubble size, impact velocity, roughness of surface and the surface tension of the surfactant solution, and permanent adhesion to the surface required a contact time for film thinning, rupturing and forming the contact angle. The experiments demonstrated the desirability of small bubbles and low impact velocities. Recovery was influenced significantly by particle size. Actual separations have been achieved in a bench top apparatus, and extended to a water elutriator 4.3 metres in height and 15 cm diameter. A mathematical model has been fitted to the behavior of particles in the column, and the effective axial diffusivity is quite similar to the {open_quotes}free stream{close_quotes} single fluid values. 10 refs., 7 figs.

  5. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, W.; Zou, Y.; Chen, W. ); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. )

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  6. Chlorobenzenes removal from municipal solid waste incineration fly ash by surfactant-assisted column flotation.

    PubMed

    Huang, Ying; Takaoka, Masaki; Takeda, Nobuo

    2003-07-01

    The organic contaminants in municipal solid waste incineration (MSWI) fly ash, including chlorinated aromatic compounds and polycyclic aromatic hydrocarbons, have high toxicity and a potential negative impact on the environment. An effective and low energy consumption technique to remove the organic contaminants from MSWI fly ash is required urgently. Organic contaminants, such as chlorobenzenes (CBzs), in MSWI fly ash are known to become enriched in the unburnt carbon (UC) fraction. It is proposed that removal of UC from fly ash will result in the effective removal of most organic micropollutants. In this research, we use a technique of surfactant-assisted column flotation to decontaminate MSWI fly ash by removal of the CBzs-enriched UC from MSWI fly ash. We find that 39.8% of CBzs can be removed from fresh MSWI fly ash with 61.7% UC removal efficiency, whereas only 33.2% of CBzs can be removed from weathered MSWI fly ash with a low UC removal efficiency of 33.7%. By adding a mixture of two kinds of surfactants: sorbitan mono-oleate and polyoxyethylene (20) sorbitan mono-oleate to the weathered fly ash, 47.0% of CBzs were removed at the hydrophile lipophile balance value of 13.5, while the UC removal efficiency increased to 49.0%. The results show that surfactants can enhance CBzs and UC removal efficiencies during the column flotation process. Higher CBzs and UC removal efficiencies can be expected by further optimizing the conditions of surfactant-assisted column flotation.

  7. Removal of carbon constituents from hospital solid waste incinerator fly ash by column flotation.

    PubMed

    Liu, Hanqiao; Wei, Guoxia; Zhang, Rui

    2013-01-01

    Hospital solid waste incinerator (HSWI) fly ash contains a large number of carbon constituents including powder activated carbon and unburned carbon, which are the major source of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in fly ash. Therefore, the removal of carbon constituents could reduce PCDD/Fs in fly ash greatly. In this study, the effects of the main flotation parameters on the removal of carbon constituents were investigated, and the characteristics of the final product were evaluated. The results showed that loss on ignition (LOI) of fly ash increased from 11.1% to 31.6% during conditioning process. By optimizing the flotation parameters at slurry concentration 0.05 kg/l, kerosene dosage 12 kg/t, frother dosage 3 kg/t and air flow rate 0.06 m(3)/h, 92.7% of the carbon constituents were removed from the raw fly ash. Under these conditions, the froth product has LOI of 56.35% and calorific values of 12.5 MJ/kg, LOI in the tailings was below 5%, and the total toxic equivalent (TEQ) of PCDD/Fs decreased from 5.61 ng-TEQ/g in the raw fly ash to 1.47 ng-TEQ/g in the tailings. The results show that column flotation is a potential technology for simultaneous separation of carbon constituents and PCDD/Fs from HSWI fly ash.

  8. A comparison study of column flotation technologies for cleaning Illinois coal. Technical report, September 1--November 30, 1993

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.

    1993-12-31

    The objectives of this research project are to optimize the performance of six commercially available column technologies for the treatment of Illinois Basin coal fines and to compare their performance on the basis of the recovery-grade curve and column throughput capacity. A statistically-designed experimental program will be conducted to optimize the critical operating performance values of each flotation column. The operating values suggested by the vendor will be used as the center point of the design. The ultimate recovery-grade curve and-the maximum throughput capacity for each column will be determined by conducting further tests using the optimum operating parameter values. During this reporting period, the flotation columns that were not already present were purchased and received. Installation of all the flotation columns was completed with the exception of the Packed-Column which is presently being mounted. A total of 25 fifty-five gallon drums of Illinois No. 5 flotation feed coal ({minus}100 mesh) was collected at a local preparation plant to be used as the feed for the comparison tests. A complete characterization of this coal sample will be conducted during the next reporting period.

  9. A fine coal circuitry study using column flotation and gravity separation. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect

    Honaker, R.Q.; Reed, S.

    1995-12-31

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. During this reporting period, an extensive separation performance comparison between a pilot-scale Floatex Density Separator (18{times}18-inch) and an existing spiral circuit has been conducted at Kerf-McGee Coal Preparation plan for the treatment of nominally {minus}16 mesh coal. The results indicate that the Floatex is a more efficient separation device (E{sub p}=0.12) than a conventional coal spiral (E{sub p}=0.18) for Illinois seam coals. In addition, the treatment of {minus}100 mesh Illinois No. 5 fine coal from the same plant using Falcon concentrator, column flotation (Packed-Column) and their different combinations was also evaluated. For a single operation, both Falcon concentrator and column flotation can produce a clean coal product with 90% combustible recovery and 5% ash content. In the case of the combined circuit, column flotation followed by the Falcon achieved a higher combustible recovery value (about 75%) than that obtained by the individual units while maintaining an ash content less than 3%.

  10. Coal pond fines cleaning with classifying cyclones, spirals, and column flotation

    SciTech Connect

    Carson, W.R.; Arnold, B.J.; Raleigh, C.E. Jr.; Parekh, B.K.

    1997-07-01

    Large reserves of coal pond fines arc found in the Illinois Basin--over 40 million tons in Western Kentucky, over 65 million tons in Southern Illinois, and over 35 million tons in Southern Indiana. If these fines are used to produce coal-water slurry (CWS), fuel costs, NO{sub x} emissions, and pond closure costs can be reduced. Coal fines from this region that are used to produce CWS for co-fire or re-burn may require processing, however, to attain proper particle size distribution and fuel quality. To evaluate the effectiveness of using coal cleaning technologies to control these CWS quality parameters, a simple flowsheet for recovering and processing coal pond fines was designed and tested. Coal fines processing consisted of using classifying cyclones to size at nominal minus 200 mesh, cleaning the classifying cyclone underflow using spirals, and cleaning the overflow using column froth flotation. Ash content of the dean coal from the spiral was reduced to about 10 percent, winch is satisfactory to use for CWS co-firing in a cyclone-fired boiler. The clean coal from column flotation may be used for re-burn in a cydone-fired boiler or as co-fire fuel in a wall-fired or tangentially-fired boiler Heating value recovery during laboratory scale, pilot-scale, and commercial-scale coal cleaning testing was about 80 percent.

  11. In-plant testing of microbubble column flotation. Third quarter technical progress report, April 1, 1990--June 30, 1990

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.; Mankosa, M.J.

    1990-12-31

    During the past year, a joint project between the US Department of Energy (DOE), the Virginia Center for Coal and Minerals Processing (VCCMP) and the Shell Mining Corporation (SMC) was initiated to implement the testing of a full-scale microbubble flotation column. The work is being carried out at the Marrowbone Preparation Plant, located near Naugatuck in southwestern West Virginia. The primary objective of this effort was to determine the feasibility of using microbubble column flotation for the recovery of coal fines from a classifying cyclone overflow stream that is presently being discarded as refuse.

  12. A comparison study of column flotation technologies for cleaning Illinois coal. Technical report, March 1, 1994--May 31, 1994

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.

    1994-09-01

    The objectives of this research project are to optimize the performance of six commercially available column technologies for the treatment of Illinois Basin coal fines and to compare their performance on the basis of the recovery-grade curve and column throughput capacity. During the previous reporting period, characterization of an Illinois No. S flotation feed sample was completed and tests on the Jameson Cell were initiated. During this reporting period, parametric studies using a Box-Behnken test design were conducted on the Jameson Cell, Packed-Column, and the Microcel. The results obtained from all three flotation technologies compared well with release analysis data. Excellent ash rejections of more than 85% were achieved by each flotation technology. However, for the test conditions used in this investigation, relatively low combustible recovery values were obtained from the Jameson Cell and the Packed-Column due to carrying capacity limitations. During the next reporting period, lower feed rates will be tested for these two technologies in an effort to improve recovery. Empirical models developed from the parametric studies will be used to predict the optimum operating parameter values. These optimum values will be used to obtain the best possible separation efficiency and maximum throughput for each flotation technology.

  13. On-line testing of a horizontally-baffled flotation column in an operating coal-cleaning plant

    SciTech Connect

    Eisele, T.C.; Kawatra, S.K.

    1995-10-01

    A horizontal-baffle arrangement has been developed to prevent excessive axial mixing in flotation columns. These baffles have been shown in previous work to improve the grade/recovery performance of both a laboratory-scale column and a pilot-scale column. In this paper, results are given for continuous on-line operation of the pilot-scale baffled column in a commercial coal-cleaning plant. These results show its ability to operate for extended periods without plugging, to produce a consistent-quality product even while the feed quality was fluctuating, and to remove much of the pyritic sulfur from the coal.

  14. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1992-12-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  15. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1998-09-29

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  16. Apparatus for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, Roe-Hoan; Adel, Gregory T.; Luttrell, Gerald H.

    1995-01-01

    An apparatus is disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal, and minerals so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  17. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, Roe-Hoan; Adel, Gregory T.; Luttrell, Gerald H.

    1992-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  18. Apparatus for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1995-03-14

    An apparatus is disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal, and minerals so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  19. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, Roe-Hoan; Adel, Gregory T.; Luttrell, Gerald H.

    1998-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  20. A fine coal circuitry study using column flotation and gravity separation. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Honaker, R.Q.; Reed, S.

    1995-12-31

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. During this reporting period, an in-plant Box-Behnken test program of the Floatex hydrosizer has been conducted at Kerr-McGee`s Galatia preparation plant. The results have shown that the Floatex hydrosizer can be successfully used to reject most of coarser ({plus}100 mesh) pyrite and mineral matter in the coal stream to the plant. With a single operation, ash rejection of 63% and total sulfur rejection of 43% have been achieved while maintaining a combustible recovery as high as 90.5%. A long term duration test under the optimum operating conditions determined from Box-Behnken test results has also been conducted. The feed samples for the following enhanced gravity - column flotation studies, which will be carried out in the next reporting period, have been collected.

  1. Separation of astaxanthin from cells of Phaffia rhodozyma using colloidal gas aphrons in a flotation column.

    PubMed

    Dermiki, Maria; Bourquin, Anne Lise; Jauregi, Paula

    2010-01-01

    The aim of this study is to investigate the separation of astaxanthin from the cells of Phaffia rhodozyma using colloidal gas aphrons (CGA), which are surfactant stabilized microbubbles, in a flotation column. It was reported in previous studies that optimum recoveries are achieved at conditions that favor electrostatic interactions. Therefore, in this study, CGA generated from the cationic surfactant hexadecyl trimethyl ammonium bromide (CTAB) were applied to suspensions of cells pretreated with NaOH. The different operation modes (batch or continuous) and the effect of volumetric ratio of CGA to feed, initial concentration of feed, operating height, and flow rate of CGA on the separation of astaxanthin were investigated. The volumetric ratio was found to have a significant effect on the separation of astaxanthin for both batch and continuous experiments. Additionally, the effect of homogenization of the cells on the purity of the recovered fractions was investigated, showing that the homogenization resulted in increased purity. Moreover, different concentrations of surfactant were used for the generation of CGA for the recovery of astaxanthin on batch mode; it was found that recoveries up to 98% could be achieved using CGA generated from a CTAB solution 0.8 mM, which is below the CTAB critical micellar concentration (CMC). These results offer important information for the scale-up of the separation of astaxanthin from the cells of P. rhodozyma using CGA.

  2. A fine coal circuitry study using column flotation and gravity separation. Technical report, September 1--November 30, 1994

    SciTech Connect

    Honaker, R.Q.; Reed, S.

    1994-12-31

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. The gravity/flotation circuits will be compared based on their optimum separation performance which will consider ash and total sulfur rejection and energy recovery as well as the probable error (E{sub p}) value obtained from washability analyses. During this reporting period, multi-stage treatment using the Falcon concentrator was conducted on a refuse pond ({minus}100 mesh) coal sample and a {minus}28 mesh run-of-mine coal sample. The results suggest that the Falcon concentrator can make an ideal separation for either sample in a single process. Recleaning was found to improve product grade, however, recovery was reduced sharply. In addition, the groups involved with the in-plant testing of the Floatex Hydrosizer met and organized the test plan which will be conducted at Kerr-McGee`s Galatia preparation plant during the next reporting period. Coal samples for the circuitry tests will be collected during, this time period.

  3. Evaluation of column flotation in the downstream processing of fermentation products: recovery of a genetically engineered alpha-amylase.

    PubMed

    Miranda, E A; Berglund, K A

    1993-01-01

    Flotation is a simple, inexpensive, and versatile unit operation with a largely unexplored potential in biotechnology. There is a general lack of research concerning biotechnological applications in this area, especially in the recovery of fermentation products. Moreover, the few reports in the literature do not consider the modern concept of column flotation as practiced in the mineral industry. We report herein the application of column flotation for the recovery of a Bacillus stearothermophilus alpha-amylase expressed in Escherichia coli by the use of a food-grade polymer, (hydroxypropyl)methylcellulose (HPMC), and ammonium sulfate. First, the enzyme was removed from the liquid phase by partition to a salted-out HPMC phase. The enzyme-containing polymer flocs were then floated from the liquid. Recovery of active enzyme was as high as 90%, with throughput as high as 94 m3/(h.m2). The floatability of the enzyme from a periplasmic extract was higher than extracellular enzyme in the broth due to the presence of depressors of molecular weight lower than 10,000 in the broth.

  4. An Advanced Control System For Fine Coal Flotation

    SciTech Connect

    G. H. Luttrell; G. T. Adel

    1998-08-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the ninth quarter of this project, Task 3 (Model Building and Computer Simulation) and Task 4 (Sensor Testing) were nearly completed, and Task 6 (Equipment Procurement and Installation) was initiated. Previously, data collected from the plant sampling campaign (Task 2) were used to construct a population balance model to describe the steady-state and dynamic behavior of the flotation circuit. The details of this model were presented in the Eighth Quarterly Technical Progress Report. During the past quarter, a flotation circuit simulator was designed and used to evaluate control strategies. As a result of this work, a model-based control strategy has been conceived which will allow manipulated variables to be adjusted in response to disturbances to achieve a target incremental ash value in the last cell of the bank. This will, in effect, maximize yield at an acceptable product quality. During this same period, a video-based ash analyzer was installed on the flotation tailings stream at the Moss No. 3 preparation plant. A preliminary calibration curve was established, and data are continuing to be collected in order to improve the calibration of the analyzer.

  5. Bench-scale testing of on-line control of column flotation using a novel analyzer

    SciTech Connect

    Not Available

    1992-01-22

    This document contains the first quarterly technical progress report for PTI's Bench-Scale Testing Project of a circuit integrating PTI's KEN-FLOTETM Column Flotation Technology and PTI's On-Line Quality Monitor Control System. The twelve-month project will involve installation of a 300 lb/hr. bench-scale testing circuit at PETC's Coal Preparation Process Research Facility (CPPRF) and testing of two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan as well as the approach to completing the major tasks within the twelvemonth project. The project is broken down into three phases, which include: Phase I - Preparation: The preparation phase was performed principally at PTI's Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing. Phase II - ET Circuit Installation and Testing: This installation and testing phase of the project will be performed at PETC's CPPRF from January through May, 1993, and will be the major focus of the project. It will involve testing of the continuous 300 lb/hr. circuit. Phase II - Project Finalization: The project finalization phase will occur from June through September, 1993, at PTI's Calumet offices and will involve finalizing analytical work and data evaluation, as well as final project reporting. This quarterly progress report principally summarizes the results from the Phase I preparation work and the plan for the early portions of the Phase 11 installation and commissioning, which will occur in January and the first week of February, 1993.

  6. Engineering development of advanced physical fine coal cleaning technolgies: Froth flotation. Quarterly technical progress report No. 10, January 1, 1991--March 31, 1991

    SciTech Connect

    Not Available

    1991-12-31

    The Task 6 effort involves three main elements including column cell development, flotation circuit testing and flotation cell modeling. The work outlined is to research column designs and operation parameters in developing an optimized column flotation cell (OCFC) to meet the overall program objectives. Any design parameters that were not evaluated as part of the optimized column development work will be reviewed and tested so as to incorporate all possible scenarios in presenting DOE with the best available flotation process for use in the 2 to 3 ton per hour POC. Following development of the OCFC, various flotation circuit configurations will be evaluated determine the ``best`` circuit design for the 2 to 3 ton per hour POC. Single and multiple stage flotation, grab and run, rougher/scavenger/cleaner, etc., test circuits will be tested as part of this effort. Upon completion of this test work, the ``best`` possible flotation cell will have been tested in a number of possible flotation circuit designs to possibly provide the ``best`` flotation approach in meeting the design criteria. In conjunction with the flotation test effort, model development work will be conducted to provide a tool in evaluating the various flotation circuit configurations and in predicting flotation performance. The model will be useful in selecting operating conditions in the POC and in evaluating the performance of the POC.

  7. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    G.H. Luttrell; G.T. Adel

    1999-01-11

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eleventh quarter of this project, Task 7 (Operation and Testing) was nearly completed through the efforts of J.A. Herbst and Associates, Virginia Tech, and Pittston Coal Company. As a result of this work, a model-based control system has now been installed which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. The system has gone through a shake-down period, training has been carried out for plant operators, and the bulk of the control logic testing has been completed with the results of these tests awaiting analysis under Task 8 (System Evaluation). The flotation model has been shown to predict incremental ash quite successfully, implying that this approach may provide the basis for a useful ''soft sensor'' for on-line incremental ash analysis.

  8. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    1998-10-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the tenth quarter of this project, Task 6 (Equipment Procurement and Installation) was completed through the efforts of J.A. Herbst and Associates, Virginia Tech, Pittston Coal Company, and FGR Automation. As a result of this work, a model-based control system is now in place which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. Testing of this control system is expected to be carried out during the next quarter, and the results of this testing will be reported in the Eleventh Quarterly report. In addition, calibration of the video-based ash analyzer was continued and an extensive set of calibration data were obtained showing that the plant is running remarkably well under manual control. This may be a result of increased attention being paid to froth flotation as a result of this project.

  9. Polychlorinated biphenyls removal from weathered municipal solid waste incineration fly ash by collector-assisted column flotation.

    PubMed

    Huang, Ying; Takaoka, Masaki; Takeda, Nobuo; Oshita, Kazuyuki

    2003-06-27

    Polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) are highly toxic micropollutants emitted from municipal solid waste incineration (MSWI), in particular, concentrated in the unburned carbon (UC) of MSWI fly ash. Because of concerns over their adverse health effects, a number of countries have classified MSWI fly ash as hazardous material and required further treatment before its final disposal in landfills. The technologies for removing the toxic chlorinated micropollutants in the MSWI fly ash have been studied, however, until now no mature technique has been obtained in this purpose. In this research, we used a technique of collector-assisted column flotation to remove PCBs-enriched UC from MSWI fly ash. We found that 36.9% PCBs could be removed from fresh MSWI fly ash with 61.7% UC removal efficiency, whereas only 21.7% PCBs could be removed from weathered MSWI fly ash with a low UC removal efficiency of 33.7%. By adding a mixture of two kinds of surfactants: sorbitan mono-oleate and polyoxyethylene (20) sorbitan mono-oleate to the weathered fly ash slurry as the collector assistant, 39.3% PCBs was removed at the hydrophile-lipophile balance (HLB) value of 13.5, while the UC removal efficiency increased to 49.0%. The results showed that the collector assistant could enhance PCBs and UC removal efficiencies during the column flotation process, and the mechanism has been discussed in detail. Higher PCBs and UC removal efficiencies could be expected by further optimizing the conditions of collector-assisted column flotation.

  10. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1991-01-01

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no new'' reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  11. Partial removal of PCDD/Fs, coplanar PCBS, and PCBS from municipal solid waste incineration fly ash by a column flotation process.

    PubMed

    Huang, Ying; Takaoka, Masaki; Takeda, Nobuo; Oshita, Kazuyuki

    2007-01-01

    Municipal solid waste incineration (MSWI) fly ash has recently attracted much attention because of its large quantity and enrichment of high toxic combustion generating organohalogen contaminants such as polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), coplanar polychlorinated biphenyls (coplanar PCBs), and polychlorinated biphenyls (PCBs). Since the organohalogen contaminants in MSWI fly ash are known to be enriched in the unburnt carbon (UC) fraction, the organohalogen contaminants can therefore be removed by the removal of UC. In this research, we used a modified column flotation technique to remove the organic contaminants from MSWI fly ash. UC was removed for 27.7% under the flotation condition without chemical flotation aids. The removal efficiencies of UC, PCDD/Fs, coplanar PCBs, and PCBs are further improved by adding flotation aids during the flotation process. UC was removed for 49.0% by adding a collector assistant with a HLB value of 13.5 and a concentration in the kerosene of 3% during the flotation process. In addition,the UC removal efficiencies are increased with the decrease of the diameter of the micropores in the gas spargers. By optimizing the flotation condition, 41.9% total PCDD/Fs, 40.8% coplanar PCBs, and 44.1% PCBs with 64.0% UC have been successfully removed from MSWI fly ash. The total toxic equivalent (TEQ) of the fly ash was decreased from 6.2 ng/g to 4.2 ng/g in the residue.

  12. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development's facility near Beverly, Ohio. OCDO's facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  13. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 9, October 1, 1990--December 31, 1990

    SciTech Connect

    Not Available

    1992-12-31

    The Task 6 effort involves three main elements including column cell development, flotation circuit testing and flotation cell modeling. The work outlined is to research column designs and operation parameters in developing an optimized column flotation cell (OCFC) to meet the overall program objectives. The test results obtained through this effort will be evaluated against the results obtained from the round-robin test program in Task 5. Any design parameters or operating conditions that are unique with the round-robin test winner that were not evaluated as part of the optimized column developments work will be reviewed and tested so as to incorporate all possible scenarios in presenting DOE with the best available flotation process for use in the 2 to 3 ton per hour POC. Following development of the OCFC, various flotation circuit configurations will be evaluated determine the ``best`` circuit design for the 2 to 3 ton per hour POC. Single and multiple stage flotation, grab and run,rougher/scavenger/cleaner, etc., test circuits will be tested as part of this effort. Upon completion of this test work, the ``best`` possible flotation cell will have been tested in a number of possible flotation circuit designs to possibly provide the ``best`` flotation approach in meeting the design criteria. In conjunction with the flotation test effort, model development work will be conducted to provide a tool in evaluating the various flotation circuit configurations and in predicting flotation performance. The model will be useful in selecting operating conditions in the POC and in evaluating the performance of the POC.

  14. Enhanced phosphorus removal in the DAF process by flotation scum recycling for advanced treatment of municipal wastewater.

    PubMed

    Kwak, Dong-Heui; Lee, Ki-Cheol

    2015-01-01

    To remove phosphorus (P) from municipal wastewater, various types of advanced treatment processes are being actively applied. However, there is commonly a space limit in municipal wastewater treatment plants (MWTPs). For that reason, the dissolved air flotation (DAF), which is well known for small space and flexible application process, is preferred as an additive process to enhance the removal of P. A series of experiments were conducted to investigate the feasibility of flotation scum recycling for effective P removal from a MWTP using a DAF pilot plant over 1 year. The average increases in the removal efficiencies due to flotation scum recycling were 22.6% for total phosphorus (T-P) and 18.3% for PO4-P. A higher removal efficiency of T-P was induced by recycling the flotation scum because a significant amount of Al components remained in the flotation scum. The increase in T-P removal efficiency, due to the recycling of flotation scum, shifted from the boundary of the stoichiometric precipitate to the equilibrium control region. Flotation scum recycling may contribute to improving the quality of treated water and reducing treatment costs by minimizing the coagulant dosage required.

  15. Ethylene/propylene oxide block copolymer interfacial phenomena in relation to coal cleaning by advanced flotation methods

    SciTech Connect

    McCloy, J.L.; Chander, S.

    1995-12-01

    Surface tension of aqueous ethylene/propylene oxide (EO/PO) block copolymer reagents were measured to understand their role in advanced coal flotation. Coal flotation is one of the most promising methods for separating the combustible matter in coal from ash forming minerals. The use of EO/PO block copolymer reagents enhances the rejection of ash minerals during coal flotation procedures. Since the mechanism whereby this enhancement is achieved is not known very well, an investigation of the surface tension characteristics of EO/PO block copolymer reagents was performed at various concentrations. Data obtained were used to compute adsorption densities at the liquid/gas interface. The adsorption characteristics of nine different EO/PO block copolymers were determined to examine the effect of percent ethylene oxide and formula weight. These studies predict that flotation experiments are most efficient when surfactants with low ethylene oxide percentages are utilized.

  16. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F.; Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C.; Hu, W.; Zou, Y.; Chen, W.; Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R.

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  17. Fine coal flotation plant waste comparison--column vs. sub-a cells. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect

    Ehrlinger, H.P. III

    1991-12-31

    The objective of this project was to compare results from a small commercially sized Deister Flotaire column flotation cell with the subaeration cells at Kerr-McGee`s Galatia plant during side by side testing of feed splits from the same sources. Typical cell criteria for both cells are included in the appendix. The project involved the activities of three organizations: the Kerr-McGee Coal Corporation, the Deister Concentrator Company, and the Illinois State Geological Survey. Their roles were as follows: Kerr-McGee installed the Deister column with sample splitter and tailings volume measuring cell in the Galatia Coal Preparation Plant to treat a representative split of their flotation feed; Deister provided a 30 inch diameter {times} 35{prime} high Deister Flotaire Column Flotation Cell capable of treating nominally one ton per hour or slightly over 1% of the plant feed. Deister additionally provided the sample splitter and the tailings volume measuring cell. ISGS personnel worked with both companies on the installation, conducted laboratory tests to direct the early plant test reagent practice, attended all of the plant runs cutting representative samples of feed, measuring slurry and reagent flows, preparing samples and writing reports.

  18. Air-Sparged Hydrocyclone/Advanced Froth Flotation fine coal cleaning

    SciTech Connect

    Stoessner, R.D. ); Shirey, G.A.; Zawadzki, E.A. ); Welsh, C.F. ); Miller, J.D. ); Shell, W.P. )

    1990-05-27

    In May 1988, the Pennsylvania Electric Company (Penelec) and New York State Electric and Gas Corporation (NYSEG) were awarded a contract from the Department of Energy's Pittsburgh Energy and Technology Center (DOE-PETC) to evaluate the performance of a two-inch Air-Sparged Hydrocyclone (ASH) for cleaning fine minus-100-mesh coal. A 24-month study was successfully completed, optimizing the performance of the ASH for cleaning raw classified, naturally-occurring minus-100-mesh Upper Freeport coal, and comparing its performance with Advanced Froth Flotation (AFF), a procedure utilizing conventional flotation equipment operated in an advanced manner (low impeller speeds, starvation float, multiple-stage cleaning, etc.) with highly selective reagents to optimize ash and pyritic sulfur rejection. The economics of cleaning fine coal by both processes at commercial scale, for retrofit and greenfield applications were found to be comparable within the accuracy of the study. Technical performance of the two processes were also found to be essentially identical. Thus, the ASH would be the best choice for a retrofit installation into an existing plant because of requiring less space. Both processes were successful in achieving excellent separations when cleaning the Upper Freeport coal. Both the ASH and AFF circuits were able to produce a clean-coal product of yield (65--80 percent weight recovery) and quality (5--6 percent ash) equivalent to that as theoretically determined by float-sink washability analyses. Combining either of the two fine coal flotation processes with a classifying cyclone circuit resulted in pyritic sulfur rejection values of about 85 percent. 47 refs., 109 figs., 75 tabs.

  19. Comparison of cutting-oil emulsion treatment by electrocoagulation-flotation in bubble column and airlift reactors.

    PubMed

    Chawaloesphonsiya, Nattawin; Prommajun, Chayanin; Wongwailikhit, Kritchart; Painmanakul, Pisut

    2016-09-01

    Separation of nanoscale oil droplets in the cutting-oil emulsion by electrocoagulation-flotation (ECF) was carried out in a bubble column reactor (BCR) and an external-loop airlift reactor (ALR). Under the batch operation, aluminium electrode provided the highest efficiency of 99% and required the shortest separating time compared to iron and graphite electrodes. The separation performance was also affected by the electrode gap and current density due to the amount of produced aluminium ions and turbulence by bubble motions. Additionally, the ECF efficiency obtained from the ALR was similar to that of the BCR. However, the ALR was preferable owing to its lower energy consumption, less electrode sacrifice, and less sludge production. Similar results were acquired under the continuous mode; nevertheless, the highest efficiency of only 85% was achieved from both reactors. It was found that the efficiency declined with increasing flow rates. According to the results suggested by the residence time distribution (RTD), the ALR was more effective at higher flow rates since the plug flow condition can be retained. On the other hand, an increase in flow rate also provoked the bypass flow to the down-comer of the ALR, resulting in the presence of a dead zone and reduction in the treatment efficiency.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This is being accomplished by utilization the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. 31 figs., 22 tabs.

  1. Advanced treatment of oilfield production wastewater by an integration of coagulation/flotation, catalytic ozonation and biological processes.

    PubMed

    Chen, Ke-Yong; Zhang, Xiao-Bing; Li, Jun

    2016-10-01

    In this study, advanced treatment of heavily polluted oilfield production wastewater (OPW) was investigated employing the combination of coagulation/dissolved air flotation, heterogeneous catalytic ozonation and sequencing batch reactor (SBR) processes. Two SBR reactors were separately set up before and after the ozonation unit. The results show that microbubble flotation was more efficient than macrobubble flotation in pollutant removal. Catalytic ozonation with the prepared Fe/activated carbon catalyst significantly enhanced pollutant removal in the second SBR by improving wastewater biodegradability and reducing wastewater microtoxicity. The treatment technique decreased oil, chemical oxygen demand and NH3-N by about 97%, 88% and 91%, respectively, allowing the discharge limits to be met. Therefore, the integrated process with efficient, economical and sustainable advantages was suitable for advanced treatment of real OPW.

  2. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO[sub 2] per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO[sub 2] emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  3. Air-Sparged Hydrocyclone/Advanced Froth Flotation fine coal cleaning

    SciTech Connect

    Shirey, G.A.; Stoessner, R.D.; Pennsylvania Electric Co., Johnstown, PA )

    1988-12-30

    The objective of the project is to evaluate the Air-Sparged Hydrocyclone (ASH) and Advanced Froth Flotation (AFF) procedures for their effectiveness in cleaning fine (minus 100 mesh) coal. The two processes will be tested in a circuit capable of processing 0.124 to 0.15 tons per hour of coal at the EPRI-CQDC. Performance of the two processes will be evaluated, and the economics of fine coal cleaning by both processes will be determined. During the past quarter, efforts were concentrated on the following tasks: installation of process equipment and characterization of the test feed coal; start-up of the ASH and AFF circuits; and initialization of the AFF Test Program. 4 figs., 7 tabs.

  4. Engineering development of advanced physical fine coal cleaning technologies - froth flotation

    SciTech Connect

    Ferris, D.D.; Bencho, J.R.

    1995-11-01

    In 1988, ICF Kaiser Engineers was awarded DOE Contract No. DE-AC22-88PC88881 to research, develop, engineer and design a commercially acceptable advanced froth flotation coal cleaning technology. The DOE initiative is in support of the continued utilization of our most abundant energy resource. Besides the goal of commercialability, coal cleaning performance and product quality goals were established by the DOE for this and similar projects. primary among these were the goals of 85 percent energy recovery and 85 percent pyrite rejection. Three nationally important coal resources were used for this project: the Pittsburgh No. 8 coal, the Upper Freeport coal, and the Illinois No. 6 coal. Following is a summary of the key findings of this project.

  5. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation'', to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  6. Intensification of the separation of CuO nanoparticles from their highly diluted suspension using a foam flotation column with S type internal

    NASA Astrophysics Data System (ADS)

    Hu, Nan; Li, Rui; Wu, Zhao-liang; Huang, Di; Li, Hong Zhen

    2015-10-01

    Foam flotation is a promising technique for recovering nanoparticles from their highly diluted suspensions. In this work, a novel S type internal was developed to intensify the foam flotation of CuO nanoparticles (357.6 nm in average particle size) from their suspension of 6.2 × 10-2 mmol/L. By enhancing foam drainage, the S type internal increased the enrichment ratio of CuO nanoparticles by 139.3 ± 12.5 % without significantly affecting their recovery percentage. Under the optimal conditions of Cetyl trimethyl ammonium bromide (CTAB) concentration 0.45 mmol/L, superficial airflow rate 2.6 mm/s, and volumetric feed rate 1.0 mL/min, the enrichment ratio and recovery percentage of CuO nanoparticles reached 81.6 ± 4.1 and 95.4 ± 4.9 %, respectively, using the foam flotation column with the S type internal. Furthermore, about 95 % CTAB could be recycled by recovering CTAB from the foamate and the residual solution. The recovered CuO nanoparticles were associated with CTAB molecules, so they had better dispersity and dispersion stability than the starting CuO nanoparticles. Therefore, they would have good reusability.

  7. The development of new Microcel{trademark} column flotation circuit for BHP Australia coal`s peak downs coal preparation plant

    SciTech Connect

    Brake, I.R.; Eldridge, G.

    1996-12-31

    In Australia`s Bowen Basin coal preparation plants, twenty-five years of development work on conventional sub-eration flotation machines have resulted in optimized circuit design, the application of customized reagents, optimal conditioning practice, increased mechanical reliability and enhanced control systems. In recent years, world-wide research has shown the potential for a quantum leap above existing flotation performance through new technology. The 2,000 tph Peak Downs Coal Preparation Plant, managed by BHP Australia Coal, is Australia`s largest. The plant produces prime coking coal through dense medium cyclones and froth flotation. The paper describes on-line pilot scale testing of three different novel flotation devices. After extensive pilot testing, the Microcel{trademark} Column supplied by Bulk Materials (Coal Handling) Pty Ltd (BMCH) was chosen by Peak Downs Mine for full scale plant trials over a nine-month period. The Microcel{trademark} demonstrated dramatically improved product quality through very effective froth washing, improved product yields, and the ability to recover 500 micron x 0 coal efficiently in one machine in a single pass. Performance was predictable, reproducible and controllable in that changing frothier dose alone moved the separation along an ash/yield curve which equaled release analysis results. The research program led to the design and construction of a full plant installation which was commissioned in September, 1995. Commissioning a breakthrough design treating minus 50 micron coal was not without its difficulties, and the practical problems of implementing such new technology into a full scale-circuit is discussed.

  8. Integrated processes for produced water polishing: Enhanced flotation/sedimentation combined with advanced oxidation processes.

    PubMed

    Jiménez, Silvia; Micó, María M; Arnaldos, Marina; Ferrero, Enrique; Malfeito, Jorge J; Medina, Francisco; Contreras, Sandra

    2017-02-01

    In this study, bench scale dissolved air flotation (DAF) and settling processes have been studied and compared to a novel flotation technology based on the use of glass microspheres of limited buoyancy and its combination with conventional DAF, (Enhanced DAF or E-DAF). They were evaluated as pretreatments for advanced oxidation processes (AOPs) to polish produced water (PW) for reuse purposes. Settling and E-DAF without air injection showed adequate turbidity and oil and grease (O&G) removals, with eliminations higher than 87% and 90% respectively, employing 70 mg L(-1) of FeCl3 and 83 min of settling time, and 57.9 mg L(-1) of FeCl3, 300 mg L(-1) of microspheres and a flocculation rate of 40 rpm in the E-DAF process. A linear correlation was observed between final O&G concentration and turbidity after E-DAF. In order to polish the O&G content of the effluent even further, to remove soluble compounds as phenol and to take advantage of residual iron after these treatments, Fenton and photo-Fenton reactions were essayed. After 6 h of the Fenton reaction at pH 3, the addition of 1660 mg L(-1) of H2O2 and 133 mg L(-1) of iron showed a maximum O&G elimination of 57.6% and a phenol removal up to 80%. Photo-Fenton process showed better results after 3 h, adding 600 mg L(-1) of H2O2 and 300 mg L(-1) of iron, at pH 3, with a higher fraction of elimination of the O&G content (73.7%) and phenol (95%) compared to the conventional Fenton process.

  9. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    a study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This document is the eighth quarterly report prepared in accordance with the project reporting requirements covering the period from July 1,1990 to September 30, 1990. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. The data from the basic research on coal surfaces, bench scale testing and proof-of-concept scale testing will be utilized to design a final conceptual flowsheet. The economics of the flowsheet will be determined to enable industry to assess the feasibility of incorporating the advanced fine coal cleaning technology into the production of clean coal for generating electricity. 22 figs., 11 tabs.

  10. Bench-scale testing of on-line control of column flotation using a novel analyzer. Revised final report, [October 1992--October 1993]: Volume 1

    SciTech Connect

    Not Available

    1993-10-27

    The main advantage of the project is that it allowed PTI to gain knowledge and experience about the proper approach, methods and hardware required to properly optimize and control column flotation performance. Many operational problems were incurred during the project, some of that PTI was able to solve during the project and other that must be overcome as the technology is further developed and commercialized. The key operating problems experienced with the KEN-FLOTE{sup TM} Column that must be further researched and overcome include: (1)The low concentrate solids content which limited the throughput capacity of the column, due to high froth washing requirements. The low concentrate solids content also lead to difficulty obtaining accurate On-Line Monitor measurements, due to the poor measurement sensitivity obtained with low solids content samples (particularly less than 5.0 wt %). (2) The higher-than-anticipated reagent dosages that undoubtedly contributed to the low solids content listed above, and also caused foaming problems within PTI`s On-Line Monitor. A defoaming reagent addition (Nalco 7810) was required to provide consistent sample size and reproducible On-Line Monitor counts for the concentrate samples collected within the circuit. PTI and UK`s CAER staff will continue to research alternative column design, particularly alternative air bubble generation and air distribution systems, to try to maximize column concentrate solids content while reducing reagent dosage requirements. In addition to the KEN-FLOTE{sup TM} Column operation there were also a number of hardware problems with PTI`s On-Line Quality Monitor that must be remedied for future commercial installations.

  11. Bench-scale testing of on-line control of column flotation using a novel analyzer. Second quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Not Available

    1993-04-16

    This document contains the second quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTE{trademark} Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale testing circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). The project schedule timeline by task series for the twelve month project, as it was laid out in the initial Project Work Plan. At the present time, all tasks are progressing according to schedule with the exception of the Task 800 Circuit Testing and Sample Prep and Task 1000 Circuit Decommissioning, which have slipped approximately five weeks due to delays incurred within in the project.

  12. An Advanced Control System for Fine Coal Flotation. Sixth quarter, technical progress report, July 1-September 30, 1997

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-10-27

    Over the past thirty years, process control has spread from the chemical industry into the fields of mineral and coal processing. Today, process control computers, combined with improved instrumentation, are capable of effective control in many modem flotation circuits. Unfortunately, the classical methods used in most control strategies have severe limitations when used in froth flotation. For example, the nonlinear nature of the flotation process can cause single-input, single-output lines to battle each other in attempts to achieve a given objective. Other problems experienced in classical control schemes include noisy signals from sensors and the inability to measure certain process variables. For example, factors related to ore type or water chemistry, such as liberation, froth stability, and floatability, cannot be measured by conventional means. The purpose of this project is to demonstrate an advanced control system for fine coal flotation. The demonstration is being carried out at an existing coal preparation plant by a team consisting of Virginia Polytechnic Institute and State University (VPI&SU) as the prime contractor and J.A. Herbst and Associates as a subcontractor. The objectives of this work are: (1) to identify through sampling, analysis, and simulation those variables which can be manipulated to maintain grades, recoveries, and throughput rates at levels set by management; (2) to develop and implement a model-based computer control strategy that continuously adjusts those variables to maximize revenue subject to various metallurgical, economic, and environmental constraints; and (3) to employ a video-based optical analyzer for on-line analysis of ash content in fine coal slurries.

  13. Bench-scale testing of on-line control of column flotation using a novel analyzer. Third quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Not Available

    1993-08-24

    This document contains the third quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale flotation circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan, as well as the approach to completing the major tasks within the twelve-month project schedule. The project is broken down into three phases, which include: Phase I -- Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing; Phase II -- ET Circuit Installation and Testing: This installation and testing phase of the project was performed at PETC`s CPPRF from January through June, 1993, and was the major focus of the project. It involved testing of the continuous 200--300 lb/hr. circuit; and Phase III -- Project Finalization: The project finalization phase is occurring from July through September, 1993, at PTI`s Calumet offices and involves finalizing analytical work and data evaluation, as well as final project reporting. This Third Quarterly Technical Progress Report principally summarizes the results from the benchscale testing with the second coal (Pittsburgh No. 8 Seam Coal), which occurred in April through June, 1993. It also contains preliminary economic evaluations that will go into the Final Report, as well as the plan for the final reporting task.

  14. Picobubble enhanced fine coal flotation

    SciTech Connect

    Tao, Y.J.; Liu, J.T.; Yu, S.; Tao, D.

    2006-07-01

    Froth flotation is widely used in the coal industry to clean -28 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range beyond which the flotation efficiency drops drastically. It is now known that the low flotation recovery of particles in the finest size fractions is mainly due to a low probability of bubble-particle collision while the main reason for poor coarse particle flotation recovery is the high probability of detachment. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles in a wide range of size by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. They are characterized by a size distribution that is mostly below 1 {mu}m and adhere preferentially to the hydrophobic surfaces. The presence of picobubbles increases the probability of collision and attachment and decreases the probability of detachment, thus enhancing flotation recovery. Experimental results with the Coalberg seam coal in West Virginia, U.S.A. have shown that the use of picobubbles in a 2 in. column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 12, July 1, 1991--September 30, 1991

    SciTech Connect

    Not Available

    1991-12-31

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no ``new`` reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality? The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  16. Advanced water recycling through electrochemical treatment of effluent from dissolved air flotation unit of food processing industry.

    PubMed

    Yoo, Sukjoon; Hsieh, Jeffery S

    2010-01-01

    This study elucidates the feasibility of electrochemical treatment as a water recycling process in the dissolved air flotation (DAF) unit in the food industry. Effects of operation parameters such as current density, electrolysis time, initial pH of effluent, and mixing process were investigated on the removal of COD, TSS, and TDS of the DAF pretreated effluent. An increase of current density enhances the removal rates and reduces the electrolysis time to reach the maximum performance. The initial pH less than 7 and the addition of mixing process were proven to increase the efficiency of EC treatment. About 80% of COD, 100% of TSS, and 60% of TDS were successfully removed at 500 mA current for 1 hour of electrolysis. The final treated effluent was found to meet the discharge standard from the US Environmental Protection Agency. It was concluded that EC process could be effective as an advanced water resourcing technology in the food industry.

  17. Bench-scale testing of on-line control of column flotation using a novel analyzer. Quarterly technical progress report, September 21, 1992--December 31, 1992

    SciTech Connect

    Not Available

    1992-01-22

    This document contains the first quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor Control System. The twelve-month project will involve installation of a 300 lb/hr. bench-scale testing circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) and testing of two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan as well as the approach to completing the major tasks within the twelvemonth project. The project is broken down into three phases, which include: Phase I - Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing. Phase II - ET Circuit Installation and Testing: This installation and testing phase of the project will be performed at PETC`s CPPRF from January through May, 1993, and will be the major focus of the project. It will involve testing of the continuous 300 lb/hr. circuit. Phase II - Project Finalization: The project finalization phase will occur from June through September, 1993, at PTI`s Calumet offices and will involve finalizing analytical work and data evaluation, as well as final project reporting. This quarterly progress report principally summarizes the results from the Phase I preparation work and the plan for the early portions of the Phase 11 installation and commissioning, which will occur in January and the first week of February, 1993.

  18. Flotation machine

    SciTech Connect

    Zlobin, M.N.; Permyakov, G.P.; Nemarov, A.A.; Metsik, V.M.; Medetsky, J.V.; Taraban, N.T.

    1993-08-10

    A flotation machine is described for beneficiating minerals comprising: a vertical cylindrical chamber for circulating a flotation pulp; a downwardly tapered bottom connected to said vertical cylindrical chamber; feed pipe means for feeding the flotation pulp carrying mineral particles of fine fraction, particles of the useful ingredient of the fine fraction being capable of floating up from the volume of said aerated pulp; discharge pipe means connected to the tapered bottom near its lowest point for discharging gangue; an annular trough for collecting froth concentrate at the top of said chamber; a group of frustoconical shells each having bases of different diameters and a tapered surface secured axially in said chamber and spaced equidistantly from one another height wise of said chamber; aerator means for aerating the flotation pulp secured to the walls of said chamber and communicating therewith to provide aerated water into said chamber; means for feeding mineral particles of coarse fraction, particles of the useful ingredient of the coarse fraction being capable of floating in the froth layer of the flotation pulp, in the form of a hydrocyclone having a cylindrical casing positioned axially over said chamber and a downwardly tapering outlet directed downwardly to feed the coarse particles to said chamber; feed pipe means for feeding the flotation pulp carrying mineral particles of coarse fraction positioned tangentially at said cylindrical casing of the hydrocyclone; and evacuation means for evacuating the liquid phase of the flotation pulp positioned tangentially at said casing of the hydrocyclone over said feed pipe means and connected to said feed pipe means for feeding the flotation pulp carrying mineral particles of the fine fraction.

  19. Advanced IMCW Lidar Techniques for ASCENDS CO2 Column Measurements

    NASA Astrophysics Data System (ADS)

    Campbell, Joel; lin, bing; nehrir, amin; harrison, fenton; obland, michael

    2015-04-01

    Global atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity-Modulated Continuous-Wave (IM-CW) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud contamination. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of optically thin clouds, thereby eliminating the need to correct for sidelobe bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper. These results are extended to include Richardson-Lucy deconvolution techniques to extend the resolution of the lidar beyond that implied by limit of the bandwidth of the modulation.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 14, January 1, 1992--March 31, 1992

    SciTech Connect

    Not Available

    1992-12-31

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development`s facility near Beverly, Ohio. OCDO`s facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  1. Controlled comparison of advanced froth flotation process technology and economic evaluations for maximizing BTU recovery and pyritic sulfur rejection

    SciTech Connect

    Harrison, K.E.; Ferris, D.D. ); Kosky, R.M. ); Warchol, J.J.; Musiol, W.F.; Shiao, S.Y. ); Luttrell, G.H.; Adel, G.T.; Yoon, R.H. )

    1990-01-01

    The overall objective of this round robin project was to select the most efficient, as determined by the efficiency index, cost effective, as determined by the annual cost per ton of SO{sub 2} removed, advanced flotation device available. This machine was to process ultra fine coal, maximize Btu recovery and maximize pyritic sulfur rejection. The device will first be installed as a one hundred pound per hour capacity unit and, subject to the outcome of Task 6 of the Engineering Development Contract, increased to a 3 ton per hour capacity unit for installation into a proof-of-concept preparation plant. All of the technical and economic results were submitted to the TST for consideration. The TST members evaluated the data and determined to rank each of the participants 50% on technical merit and 50% on economic merit. The technical merit was to be the efficiency index. The economical merit was to be the annual dollars per ton of clean coal corrected for carrying capacity and frother concentration and the results of Test No. 4. This factor does not penalize a particular technology for not meeting a 90% pyritic sulfur rejection and therefore leaves something to be desired as the only economic basis for decision. A second economic evaluation criteria was required that considered the $/ton of sulfur dioxide removed. The technical and economic factors were calculated and added together for the final evaluation ranking. The technical factor was calculated by multiplying the efficiency index for each participant by 0.5. The two economic factors were calculated by dividing 1000 by the $/ton of clean coal and multiplying by 0.5 and by dividing 10,000 by the $/ton of sulfur dioxide removed and multiply by 0.5. The 1000 and 10,000 are numbers selected such that when divided by their economic factors, respective numbers resulted in a two digit number. The results of these calculations are discussed. 4 refs., 18 figs., 27 tabs.

  2. Comparative study of flotation techniques for the treatment of liquid effluents.

    PubMed

    Puget, F P; Melo, M V; Massarani, G

    2004-01-01

    This work aimed to study the performance of three different induced air flotation units (flotation column, flotation tank and centrifugal flotation in hydrocyclone) for the treatment of a synthetic dairy effluent. Under continuous operation, it was possible to achieve removal efficiencies of milky material in suspension up to 90%, both for the flotation column and the flotation tank units. Using the centrifugal flotation unit in hydrocyclone, it was possible to decrease up to 45% of all suspended material in the effluent, with a clarified flow rate approximately three times greater than those found for the previous flotation units. In the centrifugal flotation unit, better results were obtained for air flow rate-feed flow rate ratios (Q(air)/Q(L)) greater than 0.15, and for underflow-overflow ratios (Qu/Qo) lower than 1.0.

  3. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 26, January 1, 1995--March 31, 1995

    SciTech Connect

    1995-07-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  4. Pilot-scale testing of microbubble flotation

    SciTech Connect

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1991-01-01

    Fundamental investigations into the effect of bubble size on coal flotation have established that the use of microbubbles can improve the recovery of fine coal during flotation while, at the same time, increasing the rejection of ash-forming mineral matter. When used in conjunction with the quiescent conditions provided by a column, the microbubble flotation process has been demonstrated on a laboratory scale to be capable of producing superclean coal containing less than 1 or 2% ash and very little pyritic sulfur. The main objective of this project is to demonstrate the microbubble column flotation process on a pilot-scale. A 500 lb/hr pilot plant is being constructed for the purpose of: 910 demonstrating the feasibility of the microbubble flotation process for producing superclean coal, (2) collecting scale-up data for designing commercial-scale microbubble flotation columns, and (3) collecting cost data for an economic evaluation of the process. In addition to micronized coal, the process is also being tested on coarse coal and refuse pond material. 20 figs.

  5. An advanced control system for fine coal flotation. Final technical progress report, October 1, 1995--June 30, 1996

    SciTech Connect

    1996-11-26

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, air addition rate, pulp density and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in video-based sensor technology are being applied for on-line determination of slurry ash content. During the third quarter of this project, work continued on the testing and calibration of the video-based ash analyzer, and a plant sampling campaign was conducted to provide data for the development of a mathematical process model and the model-based control algorithms.

  6. An advanced control system for fine coal flotation. Fifth quarterly technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-03-04

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on- line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, pulp density and pulp level are adjusted using model-base control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the fifth quarter of this project, all work was on hold pending the final novation of the contract to Virginia Polytechnic Institute and State University.

  7. An advanced control system for fine coal flotation. Fourth quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-03-04

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, pulp density and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the fourth quarter of this project, a final attempt was made to calibrate a video-based ash analyzer for use in this application. It was concluded that the low ash content and the coarse particle size of the flotation tailings slurry at the Maple Meadow plant site made the video-based system unsuitable for this application. Plans are now underway to lease a nuclear-based analyzer as the primary sensor for this project.

  8. Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 23, April 1, 1994--June 30, 1994

    SciTech Connect

    1995-04-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  9. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 16, July 1, 1992--September 30, 1992

    SciTech Connect

    Not Available

    1992-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  10. Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 24, July 1, 1994--September 30, 1994

    SciTech Connect

    1995-04-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  11. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 15, April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  12. Static column and its industrial application in China

    SciTech Connect

    Lu, M.; Wang, F.; Liu, W.; Xu, E.; Xu, Q.

    1999-07-01

    The column, as an advanced fine coal cleaning equipment, has been developed for more than 20 years. The Microcel, Jameson cell and other types of columns have been used in the coal industry. Since 1990, the cyclonic micro-bubble flotation column has been developed. The test of 1.5 M packed column is underway in the Shitai coal preparation plant. Chinese fine coal is quite difficult to separate. Its native ash content is high and the floatability is difficult. There is not compressed air available in the small coal mine. The high cost for waste-water treatment limited the usage of wash water. It is necessary to study the column under Chinese conditions. Laboratory tests have been done for five coals. Conventional flotation tests were also done in a one-liter flotation cell in order to compare with the results of static column. Compared with a conventional flotation cell, lower ash content and higher combustion recovery are obtained from the static column. In addition, the static column can produce super-low-ash clean coal and treat very fine and high ash content slurry, which is difficult for conventional flotation cell to separate. Test results also show that the construction of the bubble generator and the aeration rate are important for the performance of the static column. An one-meter diameter by six-meter high FXZ-1 static column has been used in four coal preparation plants for more than one year. The results are satisfactory. An additional three columns with the diameter of 1 M and 1.25 M in another 3 coal mines have been fabricated and will be put into use soon. The three-meter column has been designed for MaTou coal preparation plant and is in the course of fabrication now. The static column does not need any high-pressure air and usually does not use wash-water. The power consumption is very low and manual operation is easy. The investment and operating cost is low. In addition, the separation results are quite satisfactory. It has been recommended to be

  13. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 25, October 1, 1994--December 31, 1994

    SciTech Connect

    1994-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  14. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 11, April 1, 1991--June 30, 1991

    SciTech Connect

    Not Available

    1991-12-31

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  15. The Bateman Flotation Machine

    SciTech Connect

    Bezuidenhout, G.

    1995-12-31

    The newly developed Bateman Flotation Machine has proven its versatility in roughing and cleaning flotation circuits. This mechanical flotation machine has the dual performance capability of suspending solids and dispersing air at relatively low power inputs without compromising these two important fundamentals. This new development has been successfully marketed to a wide cross section of concentrator mineral processes. The mechanical design of the flotation mechanism has been optimized to reduce operational costs and to lower manufacturing costs. Production process environments were utilized for verification of the scale-up of each cell volume size rated mechanism. These thorough investigations produced performance data which could be accurately quoted. This paper is a historical account of the Batement Flotation Machine. Technical details of the development are covered with descriptions of the operational applications.

  16. Oil removal from produced water by conjugation of flotation and photo-Fenton processes.

    PubMed

    da Silva, Syllos Santos; Chiavone-Filho, Osvaldo; de Barros Neto, Eduardo Lins; Foletto, Edson Luiz

    2015-01-01

    The present work investigates the conjugation of flotation and photo-Fenton techniques on oil removal performance from oilfield produced water. The experiments were conducted in a column flotation and annular lamp reactor for induced air flotation and photodegradation steps, respectively. A nonionic surfactant was used as a flotation agent. The flotation experimental data were analyzed in terms of a first-order kinetic rate model. Two experimental designs were employed to evaluate the oil removal efficiency: fractional experimental design and central composite rotational design (CCRD). Overall oil removal of 99% was reached in the optimum experimental condition after 10 min of flotation followed by 45 min of photo-Fenton. The results of the conjugation of induced air flotation and photo-Fenton processes allowed meeting the wastewater limits established by the legislations for disposal.

  17. Advances in the management of spinal cord and spinal column injuries.

    PubMed

    Taghva, Alexander; Hoh, Daniel J; Lauryssen, Carl L

    2012-01-01

    Spinal cord injury (SCI) is a significant public problem, with recent data suggesting that over 1 million people in the U.S.A. alone are affected by paralysis resulting from SCI. Recent advances in prehospital care have improved survival as well as reduced incidence and severity of SCI following spine trauma. Furthermore, increased understanding of the secondary mechanisms of injury following SCI has provided improvements in critical care and acute management in patients suffering from SCI, thus limiting morbidity following injury. In addition, improved technology and biomechanical understanding of the mechanisms of spine trauma have allowed further advances in available techniques for spinal decompression and stabilization. In this chapter we review the most recent data and salient literature regarding SCI and address current controversies, including the use of pharmacological adjuncts in the setting of acute SCI. We will also attempt to provide a reader with basic understanding of the classifications of SCI and spinal column injury. Finally, we review advances in spinal column stabilization including improvements in instrumented fusion and minimally invasive surgery.

  18. Advanced Intensity-Modulation Continuous-Wave Lidar Techniques for Column CO2 Measurements

    NASA Astrophysics Data System (ADS)

    Campbell, J. F.; Lin, B.; Nehrir, A. R.; Harrison, F. W.; Obland, M. D.; Ismail, S.; Meadows, B.; Browell, E. V.

    2014-12-01

    Global atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity-Modulated Continuous-Wave (IM-CW) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud contamination. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of optically thin clouds, thereby eliminating the need to correct for sidelobe bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper.

  19. The theory of flotation

    NASA Technical Reports Server (NTRS)

    Ostwald, Wolfgang

    1988-01-01

    A brief summary of the fundamentals of the Linear theory of flotation is given. The theory by no means contradicts the previous Laminar theory or even the thermodynamics (Wark-Siedler), rather it is a refinement of the known Hardy-Langmuir-Harkin conceptions for the case when there are not two phases and phase boundaries, but rather three phases and corresponding phase boundary edges. The appearance of such three-phase boundaries (ore, water, air) is characteristic for modern flotation methods.

  20. Hydrocarbon-oil encapsulated bubble flotation of fine coal. Technical progress report for the ninth quarter, October 1, 1992--December 31, 1992

    SciTech Connect

    Peng, F.F.

    1995-01-01

    A main portion of this reporting period has been consumed in the following tasks to establish the base line for hydrocarbon oil encapsulated bubble flotation: (1) to measure the residence time distribution and formulate the axial dispersion model of 1-in. I.D. flotation column, (2) to obtain the optimum operating conditions using three phase experiment design approach followed the fractional factorial design, (3) to develop the column scale-up procedure and formulate recovery predicting model for flotation column, (4) to apply the models developed to design a 3-in. ID flotation column and predicting the cleaning results, (5) to test the collector gasification system installed on the 3-in. I.D. flotation column for hydrocarbon-oil capsulated bubble flotation of fine coal. Column flotation of minus 47 {mu}m (-400 US sieve) Pittsburgh No. 8 seam coal was carried out to study the column scale-up procedure using one-inch column. The dispersion model of nonideal flow was applied to describe the hydrodynamic state within the column. This model may be used to predict the collection zone recovery of column flotation in scale-up procedure if the column flotation is a first-order rate process. Residence Time Distribution (RTD) data of the column flotation were measured to determine the parameters of the model. It was found that an empirical distribution, logarithmic normal distribution can describe the RTD curve well. The effects of operating variables and column geometry on the Peclet number, Pe, which measure the extent of axial dispersion were studied and an empirical expression of Pe was obtained. Using the dispersion model, the column flotation of fine coal recovery can be predicted.

  1. An evaluation of fine coal flotation at the Chaili Coal Washery

    SciTech Connect

    Zhang, R.Z.; Jiang, S.X.; Yu, Z.D.; Phillips, D.I.; Gebhardt, J.E.

    1995-12-31

    The potential application of flotation for the treatment and processing of a fine-particle coal stream was investigated for the Chaili Coal Washery of the Zaozhuang Coal Mine Administration, Shandong Province, China. A goal of the test work was to evaluate the application of the Microcel{trademark} flotation column and compare its performance to conventional flotation. Small-scale flotation tests were performed in the laboratory and on-site with fine coal slurry samples from the plant thickener underflow, i.e., the washing plant`s undersized reject material. Flotation tests were conducted on-site with a 7.6-cm diameter Microcel{trademark} column and with small-scale conventional cells. Column flotation tests were performed to determine a recovery-grade relationship for the fine coal feed, which contained about 24% ash, and to obtain sufficient data to enable scale-up to a large-diameter unit. A primary objective was to establish the maximum throughput capacity of a Microcel flotation column while operating to produce a clean coal product with ash content of 7.5--7.8%. Results of the test work indicate that this product quality could be achieved at feed rates of 15--19 tph to a 3-m diameter Microcel flotation column. Lower ash products, i.e. 5--7% ash, were obtained but at lower column throughput capacities. Comparative flotation tests, conducted with conventional flotation cells, indicated that a product ash of only 8% or greater was achieved in a single-stage test.

  2. Flotation techniques for oily water treatment.

    PubMed

    Melo, M V; Sant'anna, G L; Massarani, G

    2003-07-01

    The aim of this work is to develop alternative techniques for the treatment of waters heavily contaminated by oil. Furthermore, the treatment system should achieve high removal efficiencies even under unfavorable conditions, when oil is finely dispersed in the water phase and oil droplet sizes range from 5-30 mm and concentrations are between 100 and 300 mg l(-1). The first experiments were carried out in an induced air flotation system where a flotation column performance was evaluated in batch and continuous operation. The second system investigated in this work focused on the association of centrifugal separation in a hydrocyclone and the flotation operation. The considered system is characterized by the association of these two processes, resulting the set-up in a compact unit (centrifugal flotation system). The bubbles generation and the droplet-bubble contact are performed through a gas-liquid ejector, while the separation of the phase rich in oil (froth phase) is promoted by a hydrocyclone. In both systems, it was possible to reduce the chemical demand of oxygen by more than 85% and the oil concentration of an emulsion containing droplets with sizes between 10 and 20 mm, using Polyacrilamide as destabilizing agent.

  3. SURFACTANT SPRAY: A NOVEL TECHNOLOGY TO IMPROVE FLOTATION DEINKING PERFORMANCE

    SciTech Connect

    Yulin Deng; Junyong Zhu

    2004-01-31

    Based on the fundamental understanding of ink removal and fiber loss mechanism in flotation deinking process, we developed this innovative technology using surfactant spray to improve the ink removal efficiency, reduce the water and fiber loss, reduce the chemical consumption and carry over in the flotation deinking. The innovative flotation deinking process uses a spray to deliver the frothing agent during flotation deinking to control several key process variables. The spray can control the foam stability and structure and modify the fluid dynamics to reduce the fibers entrapped in the froth layer. The froth formed at the top part of the flotation column will act as a physical filter to prevent the penetration of frothing agent into the pulp suspension to eliminate fiber contamination and unfavorable deinking surface chemistry modification due to surfactant adsorption on the fiber surface. Because of the filter effect, frothing agents will be better utilized. Under the sponsorships of the US Dept. of Energy (DOE) and the member companies of the Institute of Paper Science and Technology, we studied the chem-mechanical mechanism of surfactant spray for flotation deinking using different furnishes, chemicals, and flotation devices in the past four years. In the final year of the project, we successfully conducted mill trials at Abitibi-Consolidated, Inc., Snowflake paper recycling operation of 100% mixture of ONP/OMG. Results from laboratory, pilot-plant and mill trials indicated that surfactant spray technology can significantly reduce fiber loss in flotation deinking. It can be concluded that paper industry can profit greatly when this technology is commercialized in flotation deinking mills.

  4. Advanced Intensity-Modulation Continuous-Wave Lidar Techniques for ASCENDS O2 Column Measurements

    NASA Technical Reports Server (NTRS)

    Campbell, Joel F.; Lin, Bing; Nehrir, Amin R.; Harrison, F. Wallace; Obland, Michael D.; Meadows, Byron

    2015-01-01

    Global atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity- Modulated Continuous-Wave (IM-CW) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud contamination. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of optically thin clouds, thereby eliminating the need to correct for sidelobe bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper. These results are extended to include Richardson-Lucy deconvolution techniques to extend the resolution of the lidar beyond that implied by limit of the bandwidth of the modulation, where it is shown useful for making tree canopy measurements.

  5. Advanced Intensity-Modulation Continuous-Wave Lidar Techniques for Column CO2 Measurements

    NASA Astrophysics Data System (ADS)

    Campbell, J. F.; Lin, B.; Nehrir, A. R.; Obland, M. D.; Liu, Z.; Browell, E. V.; Chen, S.; Kooi, S. A.; Fan, T. F.

    2015-12-01

    Global and regional atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission and Atmospheric Carbon and Transport (ACT) - America airborne investigation are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity-Modulated Continuous-Wave (IM-CW) lidar techniques are being investigated as a means of facilitating CO2 measurements from space and airborne platforms to meet the mission science measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud returns. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of intervening optically thin clouds, thereby minimizing bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the Earth's surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques and provides very high (at sub-meter level) range resolution. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper. These techniques are used in a new data processing architecture to support the ASCENDS CarbonHawk Experiment Simulator (ACES) and ACT-America programs.

  6. Advanced intensity-modulation continuous-wave lidar techniques for ASCENDS CO2 column measurements

    NASA Astrophysics Data System (ADS)

    Campbell, Joel F.; Lin, Bing; Nehrir, Amin R.; Harrison, F. W.; Obland, Michael D.; Meadows, Byron

    2015-10-01

    Global atmospheric carbon dioxide (CO2) measurements for the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) space mission are critical for improving our understanding of global CO2 sources and sinks. Advanced Intensity- Modulated Continuous-Wave (IM-CW) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS measurement requirements. In recent numerical, laboratory and flight experiments we have successfully used the Binary Phase Shift Keying (BPSK) modulation technique to uniquely discriminate surface lidar returns from intermediate aerosol and cloud contamination. We demonstrate the utility of BPSK to eliminate sidelobes in the range profile as a means of making Integrated Path Differential Absorption (IPDA) column CO2 measurements in the presence of optically thin clouds, thereby eliminating the need to correct for sidelobe bias errors caused by the clouds. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate cloud layers, which is a requirement for the inversion of column CO2 number density measurements to column CO2 mixing ratios, has been demonstrated using new hyperfine interpolation techniques that takes advantage of the periodicity of the modulation waveforms. This approach works well for both BPSK and linear swept-frequency modulation techniques. The BPSK technique under investigation has excellent auto-correlation properties while possessing a finite bandwidth. A comparison of BPSK and linear swept-frequency is also discussed in this paper. These results are extended to include Richardson-Lucy deconvolution techniques to extend the resolution of the lidar beyond that implied by limit of the bandwidth of the modulation, where it is shown useful for making tree canopy measurements.

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  8. Controlling air toxics through advanced coal preparation

    SciTech Connect

    Straszheim, W.E.; Buttermore, W.H.; Pollard, J.L.

    1995-11-01

    This project involves the assessment of advanced coal preparation methods for removing trace elements from coal to reduce the potential for air toxic emissions upon combustion. Scanning electron microscopy-based automated image analysis (SEM-AIA) and advanced washability analyses are being applied with state-of-the-art analytical procedures to predict the removal of elements of concern by advanced column flotation and to confirm the effectiveness of preparation on the quality of quantity of clean coal produced. Specific objectives are to maintain an acceptable recovery of combustible product, while improving the rejection of mineral-associated trace elements. Current work has focused on determining conditions for controlling column flotation system across its operating range and on selection and analysis of samples for determining trace element cleanability.

  9. Low energy ballasted flotation.

    PubMed

    Jarvis, P; Buckingham, P; Holden, B; Jefferson, B

    2009-08-01

    A novel process which involves the replacement or supplementation of bubbles in the dissolved air flotation process with low density beads is presented. The work comprised a series of bench-scale flotation trials treating three commonly encountered algal species (Microcystis, Melosira and Chlorella) that were removed in a flotation cell configured as either: conventional dissolved air flotation (DAF); ballasted flotation using low density 70 microm glass beads with a density of 100 kg m(-3); or a hybrid process of ballasted flotation combined with conventional DAF. Results indicated that the bead only system was capable of achieving better residual turbidity than standard DAF at bead concentrations of 500 mg L(-1). Addition of beads in combination with standard DAF reduced turbidity further to even lower residual turbidity levels. Algae removal was improved when glass beads were dosed, but removal was dependent on algal species. Microcystis was removed by 97% for bead only systems and this removal did not change significantly with the addition of air bubbles. Melosira was the next best removed algae with bead only dosed systems giving similar removals to that achieved by standard DAF using a 10% air recycle ratio (81 and 76% removal respectively). Chlorella was the least well removed algae by bead only systems (63% removal). However, removal was rapidly improved to 86% by the addition of air bubbles using only a 2% recycle ratio. Energy estimations suggested that at least a 50% energy reduction could be achieved using the process offering a potential route for future development of low energy separation processes for algae removal.

  10. Advancing IM-CW Lidar Modulation Techniques for ASCENDS CO2 Column Measurements from Space

    NASA Astrophysics Data System (ADS)

    Campbell, J. F.; Lin, B.; Nehrir, A. R.; Harrison, F. W.; Chen, S.; Obland, M. D.

    2013-12-01

    Global atmospheric carbon dioxide (CO2) measurements through the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) decadal survey recommended space mission are critical for improving our understanding of CO2 sources and sinks. IM-CW (Intensity Modulated Continuous Wave) lidar techniques are investigated as a means of facilitating CO2 measurements from space to meet the ASCENDS science requirements. In previous laboratory and flight experiments we have successfully used linear swept frequency modulation to discriminate surface lidar returns from intermediate aerosol and cloud contamination. Furthermore, high accuracy and precision ranging to the surface as well as to the top of intermediate clouds, which is a requirement for the inversion of the CO2 column mixing ratio from the instrument optical depth measurements, has been demonstrated with the linear swept frequency modulation technique. We are concurrently investigating advanced techniques to help improve the auto-correlation properties of the transmitted waveform implemented through physical hardware to make cloud rejection more robust in special restricted scenarios. Several different modulation techniques are compared including orthogonal linear swept, orthogonal non-linear swept, time shifted PN, sine wave modulated PN, and sine wave pulsed PN. Different PN code techniques are presented that are appropriate for different types of lidar hardware, including our current ASCENDS IM-CW concept space hardware. These techniques have excellent auto-correlation properties without sidelobes while possessing a finite bandwidth (by way of a new cyclic digital filter), which will reduce bias error in the presence of multiple scatterers. Our analyses show that the studied modulation techniques can increase the accuracy of CO2 column measurements from space.

  11. Froth flotation of xenotime

    NASA Astrophysics Data System (ADS)

    Zhang, Yicheng

    Froth flotation as a fundamental method for processing complex minerals is commonly applied to the surface chemistry and beneficiation of rare-earth-bearing minerals. This is due to the fact that it is possible to process a wide range of fine particle sizes and the process can be tailored to the unique mineralogy of a given deposit. Flotation effectiveness is primarily controlled by the surface-chemical properties of the minerals and related adsorption phenomena at the liquid--solid interface. This research program was designed to investigate the principles of surface chemistry and froth flotation of xenotime and selected gangue minerals. This led to a better understanding of the factors affecting flotation performance and separation of xenotime from associated gangue minerals in an efficient way. This investigation includes MLA analysis, surface area measurement, zeta potential tests, and adsorption tests of xenotime, ilmenite, zircon, schorl, and staurolite under conditions of various reagent additions and different temperatures. Octano-hydroxamic acid, sodium oleate, sodium silicates, and ammonium lignosulfonate were used in microflotation behavior evaluation. Efforts were made to evaluate the effects of temperature, pH, concentration, addition order, and depressants in the microflotation of minerals with anionic collectors such as octano-hydroxamic acid and sodium oleate. Other factors, such as bubble surface tension and bubble particle size, are also discussed based on the literature review and lab observations.

  12. Towards high throughput screening of nanoparticle flotation collectors.

    PubMed

    Abarca, Carla; Yang, Songtao; Pelton, Robert H

    2015-12-15

    To function as flotation collectors for mineral processing, polymeric nanoparticles require a delicate balance of surface properties to give mineral-specific deposition and colloidal stability in high ionic strength alkaline media, while remaining sufficiently hydrophobic to promote flotation. Combinatorial nanoparticle surface modification, in conjunction with high throughput screening, is a promising approach for nanoparticle development. However, efficient automated screening assays are required to reject ineffective particles without having to undergo time consuming flotation testing. Herein we demonstrate that determining critical coagulation concentrations of sodium carbonate in combination with measuring the advancing water contact angle of nanoparticle-saturated glass surfaces can be used to screen ineffective nanoparticles. Finally, none of our first nanoparticle library based on poly(ethylene glycol) methyl ether methacrylate (PEG-methacrylate) were effective flotation collectors because the nanoparticles were too hydrophilic.

  13. An overview of oil-water separation using gas flotation systems.

    PubMed

    Saththasivam, Jayaprakash; Loganathan, Kavithaa; Sarp, Sarper

    2016-02-01

    Oil concentration levels in municipal waste water effluent streams are stringently regulated in most parts of the world. Apart from municipal waste, stricter oil/grease discharge limits are also enforced in oil and gas sectors as large volumes of produced water is being discharged to open ocean. One of the feasible, practical and established methods to remove oil substances from waste water sources is by gas flotation. In this overview, gas flotation technologies, namely dissolved and induced flotation systems, are discussed. Physico-chemical interaction between oil-water-gas during flotation is also summarized. In addition to a brief review on design advancements in flotation systems, enhancement of flotation efficiency by using pre-treatment methods, particularly coagulation-flocculation, is also presented.

  14. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 15, April--June 1996

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-07-25

    Goal is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Scope includes laboratory research and bench-scale testing on 6 coals to optimize these processes, followed by design/construction/operation of a 2-t/hr PDU. During this quarter, parametric testing of the 30-in. Microcel{trademark} flotation column at the Lady Dunn plant was completed and clean coal samples submitted for briquetting. A study of a novel hydrophobic dewatering process continued at Virginia Tech. Benefits of slurry PSD (particle size distribution) modification and pH adjustment were evaluated for the Taggart and Hiawatha coals; they were found to be small. Agglomeration bench-scale test results were positive, meeting product ash specifications. PDU Flotation Module operations continued; work was performed with Taggart coal to determine scaleup similitude between the 12-in. and 6-ft Microcel{trademark} columns. Construction of the PDU selective agglomeration module continued.

  15. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  16. Removal of cadmium (II) from simulated wastewater by ion flotation technique.

    PubMed

    Salmani, Mohammad Hossein; Davoodi, Mojtaba; Ehrampoush, Mohammad Hassan; Ghaneian, Mohammad Taghi; Fallahzadah, Mohammad Hossein

    2013-01-01

    A separation technique which has recently received a sharp increase in research activities is "ion flotation". This technique has four important advantages for treating wastewaters: low energy consumption, small space requirements, small volume of sludge and acting selectively. The present study aims to optimize parameters of ion flotation for cadmium removal in simulated wastewater at laboratory scale. It was obtained on the reaction between Cd(2+) and sodium dodecylesulfate (SDS) collector followed by flotation with ethanol as frother. Test solution was prepared by combining the required amount of cadmium ion, SDS and necessary frother or sodium sulfate solution. All experiments were carried out in a flotation column at laboratory temperature (27°C), adjusted pH = 4 and 120 minutes. The different parameters (namely: flow rate, cadmium, SDS and frother concentrations and ionic strength) influencing the flotation process were examined. The best removal efficiency obtained at a collector-metal ratio of 3:1 in 60 min with flow rate of 150 mL/min was 84%. The maximum cadmium removal was 92.1% where ethanol was introduced at a concentration 0.4% to flotation column with above conditions. The obtained results were promising, as both cadmium and collector were effectively removed from wastewater. Hence, the application of ion flotation for metal ions removal from effluents seems to be efficient.

  17. 33 CFR 183.322 - Flotation materials.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Flotation materials. 183.322...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.322 Flotation materials. (a) Flotation materials must meet...

  18. 33 CFR 183.322 - Flotation materials.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation materials. 183.322...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.322 Flotation materials. (a) Flotation materials must meet...

  19. Nanoparticle flotation collectors II: the role of nanoparticle hydrophobicity.

    PubMed

    Yang, Songtao; Pelton, Robert

    2011-09-20

    The ability of polystyrene nanoparticles to facilitate the froth flotation of glass beads was correlated to the hydrophobicity of the nanoparticles. Contact angle measurements were used to probe the hydrophobicity of hydrophilic glass surfaces decorated with hydrophobic nanoparticles. Both sessile water drop advancing angles, θ(a), and attached air bubble receding angle measurements, θ(r), were performed. For glass surfaces saturated with adsorbed nanoparticles, flotation recovery, a measure of flotation efficiency, increased with increasing values of each type of contact angle. As expected, the advancing water contact angle on nanoparticle-decorated, dry glass surfaces increased with surface coverage, the area fraction of glass covered with nanoparticles. However, the nanoparticles were far more effective at raising the contact angle than the Cassie-Baxter prediction, suggesting that with higher nanoparticle coverages the water did not completely wet the glass surfaces between the nanoparticles. A series of polystyrene nanoparticles was prepared to cover a range of surface energies. Water contact angle measurements, θ(np), on smooth polymer films formed from organic solutions of dissolved nanoparticles were used to rank the nanoparticles in terms of hydrophobicity. Glass spheres were saturated with adsorbed nanoparticles and were isolated by flotation. The minimum nanoparticle water contact angle to give high flotation recovery was in the range of 51° < θ(np(min)) ≤ 85°.

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly progress report No. 10, January--March 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-04-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and benchscale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by June, 1997. During Quarter 10 (January--March, 1995), preliminary work continued for the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant. Towards this end, laboratory flotation testing and refurbishing of the column have been started. The final version of the Subtask 4.2 Advanced Flotation Process Optimization Research topical report was issued, as was a draft version of the Subtask 4.3 report discussing the formulation of coal-water slurry fuels (CWF) from advanced flotation products. A number of product samples from Subtask 4.4 testing were sent to both Combustion Engineering and Penn State for combustion testing. The evaluation of toxic trace element analyses of column flotation products also continued. The detailed design of the 2 t/hr PDU was essentially completed with the approval of various process flow, plant layout, electrical, and vendor equipment drawings. The final version of the Subtask 6.5 -- Selective Agglomeration Bench-Scale Design and Test Plan Report was issued during this reporting quarter. Design and construction of this 25 lb/hr selective agglomeration test unit was completed and preliminary testing started. Construction of the 2 t/hr PDU began following the selection of TIC. The Industrial Company as the construction subcontractor.

  1. ADVANCED DIAGNOSTIC TECHNIQUES FOR THREE-PHASE SLURRY BUBBLE COLUMN REACTORS(SBCR)

    SciTech Connect

    M.H. Al-Dahhan; L.S. Fan; M.P. Dudukovic

    2002-07-25

    This report summarizes the accomplishment made during the third year of this cooperative research effort between Washington University, Ohio State University and Air Products and Chemicals. Data processing of the performed Computer Automated Radioactive Particle Tracking (CARPT) experiments in 6 inch column using air-water-glass beads (150 {micro}m) system has been completed. Experimental investigation of time averaged three phases distribution in air-Therminol LT-glass beads (150 {micro}m) system in 6 inch column has been executed. Data processing and analysis of all the performed Computed Tomography (CT) experiments have been completed, using the newly proposed CT/Overall gas holdup methodology. The hydrodynamics of air-Norpar 15-glass beads (150 {micro}m) have been investigated in 2 inch slurry bubble column using Dynamic Gas Disengagement (DGD), Pressure Drop fluctuations, and Fiber Optic Probe. To improve the design and scale-up of bubble column reactors, a correlation for overall gas holdup has been proposed based on Artificial Neural Network and Dimensional Analysis.

  2. ADVANCED DIAGNOSTIC TECHNIQUES FOR THREE-PHASE SLURRY BUBBLE COLUMN REACTORS (SBCR)

    SciTech Connect

    M.H. Al-Dahhan; M.P. Dudukovic; L.S. Fan

    2001-07-25

    This report summarizes the accomplishment made during the second year of this cooperative research effort between Washington University, Ohio State University and Air Products and Chemicals. The technical difficulties that were encountered in implementing Computer Automated Radioactive Particle Tracking (CARPT) in high pressure SBCR have been successfully resolved. New strategies for data acquisition and calibration procedure have been implemented. These have been performed as a part of other projects supported by Industrial Consortium and DOE via contract DE-2295PC95051 which are executed in parallel with this grant. CARPT and Computed Tomography (CT) experiments have been performed using air-water-glass beads in 6 inch high pressure stainless steel slurry bubble column reactor at selected conditions. Data processing of this work is in progress. The overall gas holdup and the hydrodynamic parameters are measured by Laser Doppler Anemometry (LDA) in 2 inch slurry bubble column using Norpar 15 that mimic at room temperature the Fischer Tropsch wax at FT reaction conditions of high pressure and temperature. To improve the design and scale-up of bubble column, new correlations have been developed to predict the radial gas holdup and the time averaged axial liquid recirculation velocity profiles in bubble columns.

  3. Dolomite flotation of high magnesium phosphate ores using fatty acid soap collectors

    NASA Astrophysics Data System (ADS)

    Gu, Zhengxing

    The separation of dolomite from apatite has been recognized as one of the most difficult subjects in mineral processing due to the similarities in their physiochemical properties. In this study, selective surfactants were used with a fatty acid soap collector to improve the flotation performance of separating dolomite from high magnesium phosphate ores. Three surfactants, diethyl phthalate (DP), Tween-80 (TW) and derivative of sulfonate salt (DSS1) were used. Hallimond cell flotation was conducted using pure dolomite sample to determine the effects of various factors including dosages, particle size, Ca2+ ions and slimes on the dolomite flotation recovery. The results showed that the surfactants can significantly improve dolomite flotation performance by increasing collecting ability and tolerating the effect of calcium ions and slime contents. The stirrer-tank cell batch flotation tests were carried out using two natural high magnesium phosphate ore samples containing 3.3% and 1.5% MgO. The test results showed that the surfactant DP could improve dolomite flotation at low dosages, and DSS1 could enhance the separation of dolomite from phosphate by improving both collecting ability and flotation selectivity. When 10% of DSS1 was used with the fatty acid soap as collector, at least 10% more dolomite can be removed with less P2O5 loss. The effectiveness of the surfactant DSS1 in enhancing dolomite flotation was further demonstrated in modified packed column flotation with natural dolomitic phosphate ore sample. The addition of the surfactant DSS1 into fatty acid soap collector could improve its frothability and froth stability, and reduce the bubble size. It has been found that the dolomite flotation performance has a close relationship with the frothability and froth stability of the collector.

  4. Selective flotation of fossil resin from Western coal. Final report, July 1, 1990--May 25, 1992

    SciTech Connect

    Jensen, G.F.; Miller, J.D.

    1992-05-25

    The proof-of-concept test program was designed to clarify a number of concerns that have been raised by coal companies who own the valuable resin resource. First, from laboratory bench-scale flotation experiments, a froth product from cleaner flotation containing more than 80% hexane-extractable resin at higher than 80% recovery can be produced. Pilot-plant testing was initiated to demonstrate the selective flotation of fossil resin and to establish a better confidence level in the new technology. Second, pilot-plant testing was designed to evaluate the effect and impact of random variation in slurry solids concentration and feed grade on this new selective fossil resin flotation technology. The flotation performance obtained under these industrial conditions is more realistic for process evaluation. Third, more accurate operating cost data was to be obtained for economic analysis. Fourth, sufficient quantities of the fossil resin concentrate were to be produced from the test program for evaluation by potential industrial users. Fifth, and finally, optimum levels for the operating variables were to be established. Such information was required for eventual scale-up and design of a fossil resin flotation plant. The pilot-plant proof-of-concept testing of selective resinate flotation has demonstrated that: (1) technically, the new flotation technologies discovered at the University of Utah and then improved upon by Advanced Processing Technologies, Inc. provide a highly efficient means to selectively recover fossil resin from coal. The proof-of-concept continuous flotation circuit (about 0.1 tph) resulted in fossil resin recovery with the same separation efficiency as was obtained from laboratory bench-scale testing (more than 80% recovery at about 80% concentrate grade); and (2) economically, the selective flotation process has been shown to be sufficiently profitable to justify the development of a fossil resin industry based on this new flotation process.

  5. Final Report - Advanced Hydraulic and Mass Transfer Models for Distillation Column Optimization and Design

    SciTech Connect

    Eldridge, Robert, B.

    2005-10-13

    The project successfully developed a computational fluid dynamics (CFD) based simulation of the hydrodynamics of flow in a commercial structured packing element. This result fulfilled the prime objective of the research program. The simulation utilized commercial CFD code marketed by Fluent Inc. in combination with a novel graphical interface developed by Oak Ridge National Lab. The end product will allow the design of next generation column internals without the need for extensive experimental validation and will expand the fundamental understanding of the vapor-liquid contacting process.

  6. Semi-industrial experimental study on bauxite separation using a cell-column integration process

    NASA Astrophysics Data System (ADS)

    Zhang, Ning-ning; Zhou, Chang-chun; Cong, Long-fei; Cao, Wen-long; Zhou, You

    2016-01-01

    The cyclonic-static micro-bubble flotation column (FCSMC) is a highly efficient mineral processing equipment. In this study, a cell-column (FCSMC) integration process was investigated for the separation of bauxite and its feasibility was analyzed on a theoretical basis. The properties of low-grade bauxite ore from Henan Province, China were analyzed. Parameters such as reagent dosage, scraping bubble time, and pressure of the circulating pump during the sorting process were investigated and optimized to improve the flotation efficiency. On the basis of these parameters, continuous separation experiments were conducted. Bauxite concentrate with an aluminum-to-silicon (A/S) mass ratio of 6.37 and a 77.63wt% recovery rate were achieved via a flow sheet consisting of "fast flotation using a flotation cell, one roughing flotation and one cleaning flotation using flotation columns". Compared with the full-flotation-cells process, the cell-column integration process resulted in an increase of the A/S ratio by 0.41 and the recovery rate by 17.58wt%. Cell-column integration separation technology represents a new approach for the separation of middle-to-low-grade bauxite ore.

  7. 33 CFR 183.302 - Flotation requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Flotation requirements. 183.302...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.302 Flotation requirements. Each boat to which this...

  8. 33 CFR 183.302 - Flotation requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation requirements. 183.302...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.302 Flotation requirements. Each boat to which this...

  9. 33 CFR 183.302 - Flotation requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Flotation requirements. 183.302...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.302 Flotation requirements. Each boat to which this...

  10. 33 CFR 183.302 - Flotation requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Flotation requirements. 183.302...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.302 Flotation requirements. Each boat to which this...

  11. Selective flotation of inorganic sulfides from coal

    DOEpatents

    Miller, K.J.; Wen, Wu-Wey

    1988-05-31

    Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow. 1 fig., 2 tabs.

  12. 76 FR 56294 - Inflatable Personal Flotation Devices

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-13

    ... SECURITY Coast Guard 46 CFR Part 160 RIN 1625-AB60 Inflatable Personal Flotation Devices AGENCY: Coast... flotation devices (PFDs) with current voluntary industry consensus standards, and to slightly modify... rule entitled ``Inflatable Personal Flotation Devices'' in the Federal Register (76 FR 17561)....

  13. 33 CFR 183.302 - Flotation requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Flotation requirements. 183.302...) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less General § 183.302 Flotation requirements. Each boat to which this...

  14. 33 CFR 183.322 - Flotation materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Flotation materials. 183.322 Section 183.322 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... of 2 Horsepower or Less General § 183.322 Flotation materials. (a) Flotation materials must meet...

  15. 33 CFR 183.322 - Flotation materials.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Flotation materials. 183.322 Section 183.322 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... of 2 Horsepower or Less General § 183.322 Flotation materials. (a) Flotation materials must meet...

  16. 33 CFR 183.322 - Flotation materials.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Flotation materials. 183.322 Section 183.322 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED... of 2 Horsepower or Less General § 183.322 Flotation materials. (a) Flotation materials must meet...

  17. Selective flotation of inorganic sulfides from coal

    DOEpatents

    Miller, Kenneth J.; Wen, Wu-Wey

    1989-01-01

    Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

  18. Advances in the development of organic polymer monolithic columns and their applications in food analysis--a review.

    PubMed

    Jandera, Pavel

    2013-10-25

    Monolithic continuous separation media are gradually finding their way to sample pre-treatment, isolation, enrichment and final analytical separations of a plethora of compounds, occurring as food components, additives or contaminants, including pharmaceuticals, pesticides and toxins, which have traditionally been the domain of particulate chromatographic materials. In the present review, recent advances in the technology of monolithic columns and the applications in food analysis are addressed. Silica-based monoliths are excellent substitutes to conventional particle-packed columns, improving the speed of analysis for low-molecular weight compounds, due to their excellent efficiency and high permeability. These properties have been recently appreciated in two-dimensional HPLC, where the performance in the second dimension is of crucial importance. Organic-polymer monoliths in various formats provide excellent separations of biopolymers. Thin monolithic disks or rod columns are widely employed in isolation, purification and pre-treatment of sample containing proteins, peptides or nucleic acid fragments. Monolithic capillaries were originally intended for use in electrochromatography, but are becoming more frequently used for capillary and micro-HPLC. Monoliths are ideal highly porous support media for immobilization or imprinting template molecules, to provide sorbents for shape-selective isolation of target molecules from various matrices occurring in food analysis. The separation efficiency of organic polymer monoliths for small molecules can be significantly improved by optimization of polymerization approach, or by post-polymerization modification. This will enable full utilization of a large variety of available monomers to prepare monoliths with chemistry matching the needs of selectivity of separations of various food samples containing even very polar or ionized compounds.

  19. Hydrocarbon-oil encapsulated air bubble flotation of fine coal. 1st Quarterly report, October 1, 1990--December 31, 1990

    SciTech Connect

    Peng, F.F.

    1995-01-01

    In the froth flotation process, whether accomplished In a conventional stirred tank flotation cell, in a column flotation cell, in an air sparged cyclone flotation or in a static-tube cell by using microbubbles, it requires the addition of large quantity of surfactants such as frother and/or collector (or promoter). In coarse coal flotation, special reagents are used such as high molecular weight frothers, the collector with a non-ionic, low foam emulsifier, Sherex Shur Coal 159 or Sherex Shur Coal 168 blended with fuel oil No. 2. These reagents in liquid forms are directly added into the coal pulp in the flotation cell. Frequently, a conditioning tank is required to achieve the dispersion of the reagents. The dispersion of the collector such as hydrocarbon-oil (insoluble or partially soluble) by a mechanical mixer in the coal pulp is often inadequate. In this work, in order to demonstrate the effectiveness of collector droplet size and dispersion on froth flotation processes, a unique gasified collector dispersion and oil-coated bubble generation system was used. The hydrocarbon oil collector was gasified at a temperature approximately 40 degrees C above the fractionation temperature of the collector to avoid pyrolysis. Gasified collector is first mixed in the air stream and transported to the air diffusion hood in the flotation cell. The oil-coated air bubbles were then generated and diffused into solid-water phases.

  20. Removal of pyrite and trace elements from waste coal by dissolved-CO{sub 2} flotation and chelating agents. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect

    Shiao, S.Y.

    1994-08-01

    In dissolved-CO{sub 2} flotation, ultrafine -bubbles are generated by CO{sub 2} dissolved in water. The ultrafine bubbles have the potential to improve the separation efficiency in fine coal cleaning. Chemicals will be used prior to or during dissolved-CO{sub 2} flotation to improve the separation efficiency-CO{sub 2} of pyrite and other minerals including trace metals from coal. Chelating agent will be applied to clean coal to further reduce the trace metals from coal. During this period, a 3 in. diameter packed column has been purchased and installed. This column was then modified for use in dissolved-CO{sub 2} flotation. Coal samples of Illinois No. 6 coal are being prepared for flotation. Preliminary flotation tests were performed on Illinois No. 6 waste coal.

  1. Process and apparatus for separating fine particles by microbubble flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1991-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine particles, especially coal, so as to produce a high purity and large recovery efficiently. This is accomplished through the use of a high aspect ratio flotation column, microbubbles, and a countercurrent use of wash water to gently wash the froth. Also, disclosed are unique processes and apparatus for generating microbubbles for flotation in a high efficient and inexpensive manner using either a porous tube or an in-line static generator. 23 figures.

  2. Process and apparatus for separating fine particles by microbubble flotation together with a process and apparatus for generation of microbubbles

    DOEpatents

    Yoon, Roe-Hoan; Adel, Gregory T.; Luttrell, Gerald H.

    1991-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine particles, especially coal, so as to produce a high purity and large recovery efficiently. This is accomplished through the use of a high aspect ratio flotation column, microbubbles, and a countercurrent use of wash water to gently wash the froth. Also, disclosed are unique processes and apparatus for generating microbubbles for flotation in a high efficient and inexpensive manner using either a porous tube or an in-line static generator.

  3. Removal of pyrite and trace elements from waste coal by dissolved-CO{sub 2} flotation and chelating agents. Final technical report, September 1, 1993--August 31, 1994

    SciTech Connect

    Shiao, S.Y.; Ho, K.

    1994-12-31

    The overall objective of this project was to use ultrafine bubbles generated by dissolved C0{sub 2} to recover useable fuel, and reject pyrite and other minerals from a waste coal in flotation. In addition, a chelating agent was used to remove trace metals from the froth products. Illinois No. 6 waste coal obtained from a refuse thickener of a coal cleaning circuit was used as the feed in flotation. The as-received waste coal had a top size of 2400 microns. The waste coal was ground to {minus}75 microns ({minus}200 mesh) and {minus}44 microns ({minus}325 mesh). The as-received and the ground waste coal samples were subjected to flotation. Dissolved-CO{sub 2} flotation tests were performed mainly in a 3-inch diameter by 8 feet high packed column under various test conditions. Some tests were also performed in a 2-inch diameter microbubble column for comparison. The flotation performance of the waste coal in the microbubble column was higher than that for the packed column. The packing in the packed column hindered the coal flotation. The separation efficiency of the ground coal was less than that for the asreceived coal. Flotation of the waste coal was also performed in the packed column using coarser bubbles generated by dispersed C0{sub 2} and air. The separation efficiency of the ground waste coal of 44 microns top size was higher than that for dissolved-CO{sub 2} flotation. Additives were used to modify the waste coal surfaces. Triton-X 100, a nonionic surfactant and EDTA, a chelating agent, increased the separation efficiency of the waste coal.Most of the trace metals in coal were reduced in different degrees by flotation. Triton X-100 or EDTA enhanced removal of chromium, nickel, and selenium. Applying EDTA to the froth products further removed lead significantly.

  4. Advanced landfill leachate treatment using iron-carbon microelectrolysis- Fenton process: Process optimization and column experiments.

    PubMed

    Wang, Liqun; Yang, Qi; Wang, Dongbo; Li, Xiaoming; Zeng, Guangming; Li, Zhijun; Deng, Yongchao; Liu, Jun; Yi, Kaixin

    2016-11-15

    A novel hydrogen peroxide-enhanced iron-carbon (Fe-C) microelectrolysis reactor was proposed for the pretreatment of mature landfill leachate. This reactor, combining microelectrolysis with Fenton process, revealed high treatment efficiency. The operating variables, including Fe-C dosage, H2O2 concentration and initial pH, were optimized by the response surface methodology (RSM), regarding the chemical oxygen demand (COD) removal efficiency and biochemical oxygen demand: chemical oxygen demand (BOD5/COD) as the responses. The highest COD removal (74.59%) and BOD5/COD (0.50) was obtained at optimal conditions of Fe-C dosage 55.72g/L, H2O2 concentration 12.32mL/L and initial pH 3.12. Three-dimensional excitation and emission matrix (3D-EEM) fluorescence spectroscopy and molecular weight (MW) distribution demonstrated that high molecular weight fractions such as refractory fulvic-like substances in leachate were effectively destroyed during the combined processes, which should be attributed to the combination oxidative effect of microelectrolysis and Fenton. The fixed-bed column experiments were performed and the breakthrough curves at different flow rates were evaluated to determine the practical applicability of the combined process. All these results show that the hydrogen peroxide-enhanced iron-carbon (Fe-C) microelectrolysis reactor is a promising and efficient technology for the treatment of mature landfill leachate.

  5. Flotation classification of ultrafine particles -- A novel classification approach

    SciTech Connect

    Qiu Guanzhou; Luo Lin; Hu Yuehua; Xu Jin; Wang Dianzuo

    1995-12-31

    This paper introduces a novel classification approach named the flotation classification approach which works by controlling interactions between particles. It differs considerably from the conventional classification processes operating on mechanical forces. In the present test, the micro-bubble flotation technology is grafted onto hydro-classification. Selective aggregation and dispersion of ultrafine particles are achieved through governing the interactions in the classification process. A series of laboratory classification tests for {minus}44 gm kaolin have been conducted on a classification column. As a result, about 92% recovery for minus 2 {micro}m size fraction Kaolin in the final product is obtained. In addition, two criteria for the classification are set up. Finally, a principle of classifying and controlling the interactions between particles is discussed in terms of surface thermodynamics and hydrodynamics.

  6. Distillation Column Modeling Tools

    SciTech Connect

    2001-09-01

    Advanced Computational and Experimental Techniques will Optimize Distillation Column Operation. Distillation is a low thermal efficiency unit operation that currently consumes 4.8 quadrillion BTUs of energy...

  7. The use of ion flotation for detoxification of metal-contaminated waters and process effluents

    SciTech Connect

    Doyle, F.M.; Duyvesteyn, S.; Sreenivasarao, K.

    1995-12-31

    Toxic metals entering surface or ground water from sources such as metal finishing shop spills and abandoned mines can pose a significant threat to public health and the environment. Ion flotation and similar foam separation techniques show great promise for treating dilute, metal-contaminated solutions, and could also be used to treat effluents from many minerals and metallurgical processing operations prior to discharge. In ion flotation, an appropriate collector is added to the solution to form hydrophobic complexes with the metal ions. These metal-bearing species are then removed by flotation, usually with trace addition of a frother to stabilize the foam. In an effort to better understand the underlying scientific and engineering principles that determine the performance of ion flotation, the removal of Cu(II), Pb(II), Cd(II), Cr(III) and Cr(VI) has been studied using laboratory scale flotation columns in batch mode. The effects of the superficial air velocity, solution and froth height, nature of the collector, collector:metal-ion ratio, ionic strength and several frothers at low concentrations on the flotation kinetics are reported. Finally, results are presented on methods that might allow regeneration of collector and recovery of by-product metal from the foam product.

  8. Selective flotation of fossil resin from western coal

    SciTech Connect

    Jensen, G.F.; Miller, J.D.

    1992-03-20

    The test program has demonstrated that: (1) technically, the new flotation technologies discovered at the University of Utah and then improved upon by Advanced Processing Technologies, Inc. provide a highly efficient means to selectively recover fossil resin from coal. The proof-of-concept continuous flotation circuit resulted in fossil resin recovery with the same separation efficiency as was obtained from laboratory bench-scale testing (more than 80% recovery at about 80% concentrate grade); and (2) economically, the selective flotation process has been shown to be sufficiently profitable to justify the development of a fossil resin industry based on this new flotation process. The proof-of-concept testing has resulted in significant interest from several coal mining companies and has sparked the desire of local and state government to establish a fossil resin industry in the Wasatch Plateau coal field. In this view, the results from the current proof-of-concept testing program have been successful. This special report provides theoretical and analytical data on some surface chemistry work pertinent to fossil resin characterization, and other efforts carried out during the past months.

  9. Bubble injected hydrocyclone flotation cell

    SciTech Connect

    Stanley, D.A.; Jordon, C.E.

    1990-11-20

    This patent describes an apparatus for selective separation of a mixture of hydrophobic and hydrophilic mineral particles. It comprises: a bubble-injected hydrocyclone flotation cell and a bubble slurry. The cell comprises an enclosed body section; a mineral pulp feed port; a bubble slurry feed port; and a vortex finder.

  10. Hydrocarbon-oil encapsulate bubble flotation of fine coal. Technical progress report for the thirteenth quarter, October 1--December 30, 1993

    SciTech Connect

    Peng, F.F.

    1993-12-31

    Gasified collector and liquid collector addition techniques were applied in the column flotation to demonstrate the selectivity of utilizing the hydrocarbon-oil encapsulated air bubbles in the fine coal flotation process. A 3-in. flotation column was used to evaluate two modes of collector dispersion and addition techniques on the recovery and grade of fine coals using various ranks of coal. Five different coal samples were used in the column flotation test program. They are Mammoth, Lower Kittanning, Upper Freeport, Pittsburgh No. 8, and Illinois No. 6 seam coals, which correspond to anthracite-, low volatile-, medium volatile-, and high volatile-seam coals, respectively. In this quarterly report, the test results for the Illinois No. 6 seam coal are reported.

  11. Hydrocarbon-oil encapsulate bubble flotation of fine coal. Technical progress report for the twelfth quarter, July 1--September 30, 1993

    SciTech Connect

    Peng, F.F.

    1993-12-31

    Two modes of collector addition techniques including gasified collector transported in gas phase and direct collector addition techniques were applied in the column flotation to demonstrate the selectivity of utilizing the hydrocarbon-oil encapsulated air bubbles in the fine coal flotation process. A 3-in. flotation column was used to evaluate two modes of collector dispersion and addition techniques on the recovery and grade of fine coals using various ranks of coal. Five different coal samples were used in the column flotation test program. They are Mammoth, Lower Kittanning, Upper Freeport, Pittsburgh No. 8, and Illinois No. 6 seam coals, which correspond to anthracite-, low volatile-, medium volatile-, and high volatile-seam coals, respectively. In this quarterly report, the test results for the Upper Freeport seam coal and Pittsburgh No. 8 seam coal are reported.

  12. Hydrocarbon-oil encapsulated air bubble flotation of fine coal. Technical progress report for the third quarter, April 1, 1991--June 30, 1991

    SciTech Connect

    Peng, F.F.

    1995-01-01

    This report is concerned with the progress made during the third period of the two year project. A significant portion of this reporting period has been consumed in measurement of induction time of oil-free and oil-coated bubbles, modification of collector gasifier, hydrocarbon oil encapsulated flotation tests and float and sink analyses of various rank of coal samples, building a 1-inch column cell, as well as building the ultrasound collector emulsification apparatus. Induction time has been measured using an Electronic Induction Timer. The results indicate that alteration of chemical properties of air bubble by applying hydrocarbon oil or reagent can drastically improve the rate of flotation process. Various techniques have been employed in hydrocarbon oil encapsulated flotation processes to further enhance the selectivity of the process, which include: (1) gasified collector flotation with addition of gasified collector into the air stream in the initial stage; (2) two-stage (rougher-cleaner) gasified collector flotation; and (3) starvation gasified collector flotation by addition of gasified collector at various flotation times. Among these, three techniques used in hydrocarbon oil encapsulated flotation process, the starvation flotation technique provides the best selectivity.

  13. Hydrocarbon-oil encapsulate bubble flotation of fine coal. Technical progress report for the eighth quarter, July 1, 1992--September 30, 1992

    SciTech Connect

    Peng, F.F.

    1995-01-01

    A portion of this reporting period has been consumed in the following tasks: (1) development of air-water-frother sparging system using an assemble of two sets of atomizers; (2) conducting the column flotation tests followed 2{sup 6} {times} 1/4 fractional factorial design; (3) to develop a collector gasifier system for formation of hydrocarbon-oil encapsulated bubbles. To effectively remove sulfur and mineral matters from coal, the coal particles must be ground to minus 75 {mu}m (minus 200 U.S. sieve) or less to liberate the pyrite and mineral matters from the coal matrix. As reported in a previous report (Fifth Quarterly report), in order to effectively reduce ash content in fine clean coal products using a 3-in. flotation column, the height of the column must be increased to increase the depth of the frother and the residence time of coal particles in the flotation column. In this study, a series of column flotation tests were conducted on freshly ground minus 75 {mu}m Upper Freeport seam coal. The flotation column is equipped with froth washing device as well as two sets of atomizers for sparging the air-water and frother mixture. The operation of column flotation involves the multiplicity of control variables. Thus, three phases of work plan were used to minimize the number of tests. In this report, the results of column flotation tests obtained in the third phase of the experiment work are reported. The column flotation is capable of achieving 90 percent or more of combustible recovery and 70 percent or more of ash rejection from the raw coal contained 20 percent or greater ash content. The main objectives of this reporting period are: (1) to establish a test procedure, and to determine the optimal height of flotation column and operating conditions for cleaning minus 75 {mu}m Upper Freeport seam coal, and (2) to extend the test procedure and the operating conditions established to clean various seam coals using a hydrocarbon-oil encapsulated bubble flotation.

  14. Burdach's column.

    PubMed

    Pearce, J M S

    2006-01-01

    After the Greek physicians Herophilus and Galen, the major anatomical advances in the anatomy of the spinal cord were made possible by the microtome devised by Benedikt Stilling in January 1842. This enabled him to cut the frozen, thin sections and examine them, unstained,with the microscope. The technique founded future investigation of the cord's anatomy. Brown-Séquard, Türck, Clarke, Lissauer, Goll, and Flechsig all contributed. An important result of these progressing anatomical experiments was the identification of the posterior columns. In 1826, the German physiologist Karl Friedrich Burdach (1776-1847) described, from macroscopic study, the fasciculus cuneatus, known as the tract of Burdach: the lateral portion of the posterior columns of the cord that terminate in the nucleus cuneatus of the medulla.

  15. A dynamics model for fine coal flotation

    SciTech Connect

    Youjun, T.; Maixi, L.

    1999-07-01

    Through a large amount of experiments, this article studied the effect of the entrapment of water flow on the fine coal flotation during the flotation, and also investigated the relation between the constant of water flotation rate and different operation variables, and resulted in its equation. The water-recycling model is determined, and finally, the dynamics model on relation between the recovery of fine particle and the water recovery in concentration is established. The equation about ash of fine clean coal in any flotation time is derived by introduction of de-ashed coefficient.

  16. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 12, July--September 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction and operation of a 2-t/hr process development unit. The project began in October, 1992, and is scheduled for completion by June, 1997. During Quarter 12 (July--September 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at Lady Dunn. Under Subtask 4.4, additional toxic trace element analysis of column flotation samples finalized the data set. Data analysis indicates that reasonably good mass balances were achieved for most elements. The final Subtask 6.3 Selective Agglomeration Process Optimization topical report was issued this quarter. Preliminary Subtask 6.4 work investigating coal-water-fuel slurry formulation indicated that selective agglomeration products formulate slurries with lower viscosities than advanced flotation products. Work continued on Subtask 6.5 agglomeration bench-scale testing. Results indicate that a 2 lb ash/MBtu product could be produced at a 100-mesh topsize with the Elkhorn No. 3 coal. The detailed design of the 2 t/hr selective agglomeration module neared completion this quarter with the completion of additional revisions of both the process flow, and the process piping and instrument diagrams. Construction of the 2 t/hr PDU and advanced flotation module was completed this quarter and startup and shakedown testing began.

  17. Sewage treatment-flotation apparatus

    SciTech Connect

    Hines, D.A.; Jones, R.T.; Roesler, F.C.

    1981-03-03

    Solids-liquid separation, wherein a solids-liquid mixture containing dissolved oxygen-containing gas is circulated around a circulatory system comprising a downcomer and a riser, part of the mixture in the riser being introduced into a flotation chamber in which the hydrostatic pressure gradually decreases as the mixture flows upwards, with consequent release from solution of gas bubbles which carry solid particles to the top of the mixture.

  18. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 16, July--September, 1996

    SciTech Connect

    Shields, G.L.; Moro, N.; Smit, F.J.; Jha, M.C.

    1996-10-30

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. 28 refs., 13 figs., 19 tabs.

  19. 21 CFR 890.3175 - Flotation cushion.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Flotation cushion. 890.3175 Section 890.3175 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Prosthetic Devices § 890.3175 Flotation cushion....

  20. 21 CFR 890.3175 - Flotation cushion.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Flotation cushion. 890.3175 Section 890.3175 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Prosthetic Devices § 890.3175 Flotation cushion....

  1. 21 CFR 890.3175 - Flotation cushion.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Flotation cushion. 890.3175 Section 890.3175 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Prosthetic Devices § 890.3175 Flotation cushion....

  2. 21 CFR 890.3175 - Flotation cushion.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Flotation cushion. 890.3175 Section 890.3175 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Prosthetic Devices § 890.3175 Flotation cushion....

  3. 21 CFR 890.3175 - Flotation cushion.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Flotation cushion. 890.3175 Section 890.3175 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Prosthetic Devices § 890.3175 Flotation cushion....

  4. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  5. Recent advances of packed column technology for gas dehydration and absorbent regeneration in arctic and off-shore gas production

    SciTech Connect

    Chen, G.K.

    1987-01-01

    In-depth revamp of dehydration and regeneration trayed columns with proprietary structured packings in arctic gas production will be presented in terms of throughput increase and mass transfer efficiency improvement achieved. Mathematical expressions that relate the column performance to operating variables such as absorbent temperature and concentration, ratio of absorbent to gas, degree of dehydration/regeneration and number of transfer units available are described. Equipment specification and performance between conventional tray design and packed column for off-shore application are also included. Initial capital investment versus subsequent net savings of numerous commercial installations are discussed.

  6. Dispersed ozone flotation of Chlorella vulgaris.

    PubMed

    Cheng, Ya-Ling; Juang, Yu-Chuan; Liao, Guan-Yu; Ho, Shih-Hsin; Yeh, Kuei-Ling; Chen, Chun-Yen; Chang, Jo-Shu; Liu, Jhy-Chern; Lee, Duu-Jong

    2010-12-01

    Flotation separation of Chlorella vulgaris, a species with excellent potential for CO(2) capture and lipid production, was studied using dispersed ozone gas. Pure oxygen aeration did not yield flotation. Conversely, applying ozone effectively separation algae from broth through flotation. The ozone dose applied for sufficient algal flotation is <0.05 mg/g biomass, much lower than those used in practical drinking waterworks (0.1-0.3 mg/g suspended solids). Main products, lipid C16:0, was effectively collected in the flotage phase. The algae removal rate, surface charge, and hydrophobicity of algal cells, and proteins and polysaccharides contents of algogenic organic matter (AOM) were determined. Certain quantities of proteins were present in the cultivated algal suspension, hence, minimal quantity of ozone was required to release intracellular proteins as surfactants to lead to effective flotation.

  7. 46 CFR 179.240 - Foam flotation material.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Foam flotation material. 179.240 Section 179.240... Requirements § 179.240 Foam flotation material. (a) Foam may only be installed as flotation material on a vessel when approved by the cognizant OCMI. (b) If foam is installed as flotation material on a...

  8. 33 CFR 183.114 - Test of flotation materials.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Test of flotation materials. 183.../Outdrive Boats, and Airboats § 183.114 Test of flotation materials. (a) Vapor test. The flotation material... gasoline test. The flotation material must not reduce in buoyant force more than 5 percent after...

  9. 33 CFR 183.114 - Test of flotation materials.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Test of flotation materials. 183.../Outdrive Boats, and Airboats § 183.114 Test of flotation materials. (a) Vapor test. The flotation material... gasoline test. The flotation material must not reduce in buoyant force more than 5 percent after...

  10. 33 CFR 183.114 - Test of flotation materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Test of flotation materials. 183.../Outdrive Boats, and Airboats § 183.114 Test of flotation materials. (a) Vapor test. The flotation material... gasoline test. The flotation material must not reduce in buoyant force more than 5 percent after...

  11. 33 CFR 183.114 - Test of flotation materials.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Test of flotation materials. 183.../Outdrive Boats, and Airboats § 183.114 Test of flotation materials. (a) Vapor test. The flotation material... gasoline test. The flotation material must not reduce in buoyant force more than 5 percent after...

  12. 33 CFR 183.114 - Test of flotation materials.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Test of flotation materials. 183.../Outdrive Boats, and Airboats § 183.114 Test of flotation materials. (a) Vapor test. The flotation material... gasoline test. The flotation material must not reduce in buoyant force more than 5 percent after...

  13. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications

    SciTech Connect

    Smit, Frank J; Schields, Gene L; Jha, Mehesh C; Moro, Nick

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel™ column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications.

  14. Advanced dress-up chiral columns: New removable chiral stationary phases for enantioseparation of chiral carboxylic acids.

    PubMed

    Todoroki, Kenichiro; Ishii, Yasuhiro; Ide, Takafumi; Min, Jun Zhe; Inoue, Koichi; Huang, Xin; Zhang, Wei; Hamashima, Yoshitaka; Toyo'oka, Toshimasa

    2015-07-02

    This paper describes the preparation of new dress-up columns featuring reproducibly removable and replaceable chiral stationary phases. After synthesizing perfluroalkylated quinine and quinidine derivatives as chiral stationary phase compounds (F-CSPs), we adsorbed them reversibly onto a fluorous LC column through pumping of their solutions. Using this dress-up chiral column and fluorophobic elution of aqueous ammonium formate/MeOH mixtures, we could enantioseparate four racemic N-acetyl amino acids, dichlorprop, and sixteen fluorescent 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate (AQC)-derivatized amino acids. Dressing and undressing of the coated F-CSPs could be controlled by varying the fluorophilicity and fluorophobicity of the eluent. The relative standard deviations of the retention times, the retention factors, the number of theoretical plates, the enantioseparation factors, and the resolutions of each of four preparations of such dress-up columns were all less than or equal to 5.26% (from 20 repeated analyses); the reproducibilities from four different preparations were all less than or equal to 10.6%. These columns also facilitated highly sensitive and selective analyses of AQC-amino acids when detected using LC-MS/MS.

  15. Physical cleaning of waste coal by dissolved-CO{sub 2} flotation. Final technical report, September 1, 1992--August 31, 1993

    SciTech Connect

    Shiao, S.Y.

    1993-12-31

    The coal wastes generated from coal mining operations and coal cleaning processes contain fine and ultrafine coals. Recovery of the fine/ultrafine coal from the coal wastes reduces the loss of useable fuels and the environmental impact. The objective of this project was to use dissolved-CO{sub 2} technology to generate ultrafine bubbles to separate fine/ultrafine coal from pyrite and other mineral matter in the coal wastes. The Illinois No. 6 coal waste used in the project was the underflow from a refuse thickener. The concentrations of the major trace metals are much higher than those found in Illinois Basin Coal database for Illinois No. 6 coals. Bench-scale conventional flotation tests of the waste coal were performed under various conditions using a 4-liter Wemco flotation cell. The tests were performed to determine the chemical dosages and flotation conditions used in dissolved-CO{sub 2} column flotation. The waste coal samples were subjected to dissolved-CO{sub 2} flotation in a 2-inch diameter microbubble column under various test conditions. The flotation performance as affected by each test variable was compared. For most of the tests, the Btu recovery was above 80%, the pyrite rejection was about 60%, and the ash rejection varied from about 45% to 76%. Dissolved air was used in one test for comparison. The waste coal samples were also subjected to typical microbubble flotation. As compared to microbubble flotation, the dissolved-CO{sub 2} had higher yield, higher Btu recovery, less pyrite rejection, and less ash rejection. Almost all of the major trace metals had a substantial reduction in concentration by dissolved-CO{sub 2} flotation, particularly for cadmium, chromium, nickel, and lead.

  16. Isolation and characterization of lost copper and molybdenum particles in the flotation tailings of Kennecott copper porphyry ores

    NASA Astrophysics Data System (ADS)

    Tserendavga, Tsend-Ayush

    The importance of flotation separation has long been, and continues to be, an important technology for the mining industry, especially to metallurgical engineers. However, the flotation process is quite complex and expensive, in addition to being influenced by many variables. Understanding the variables affecting flotation efficiency and how valuable minerals are lost to the tailings gives metallurgists an advantage in their attempts to increase efficiency by designing operations to target the areas of greatest potential value. A successful, accurate evaluation of lost minerals in the tailings and appropriate solutions to improve flotation efficiency can save millions of dollars in the effective utilization of our mineral resources. In this dissertation research, an attempt has been made to understand the reasons for the loss of valuable mineral particles in the tailings from Kennecott Utah Copper ores. Possibilities include liberation, particle aggregation (slime coating) and surface chemistry issues associated with the flotation separation. This research generally consisted of three main aspects. The first part involved laboratory flotation experiments and factors, which affect the flotation efficiency. Results of flotation testing are reported that several factors such as mineral exposure/liberation and slime coating and surface oxidation strongly affect the flotation efficiency. The second part of this dissertation research was to develop a rapid scan dual energy (DE) methodology using 2D radiography to identify, isolate, and prepare lost sulfide mineral particles with the advantages of simple sample preparation, short analysis time, statistically reliable accuracy and confident identification. The third part of this dissertation research was concerned with detailed characterization of lost particles including such factors as liberation, slime coating, and surface chemistry characteristics using advanced analytical techniques and instruments. Based on the

  17. Hydrocarbon-oil encapsulated bubble flotation of fine coal. Technical progress report for the fourth quarter, July 1, 1991--September 30, 1991

    SciTech Connect

    Peng, F.F.

    1995-01-01

    This report is concerned with the progress made during the fourth period of the research Project, Grant no. DE-FG22-90-PC90314. A main portion of this reporting period has been consumed in the following tasks: (i) induction time measurement for the coal particles prepared by using various modes of collector addition techniques; (ii) ultrasonic energy dispersed collector flotation tests; (iii) natural floatability measurement using Hallimond tube flotation cell; (iv) preparation and operation of 3-inch column cell, and (v) preparation of wettability measurement using film flotation method. The coal samples used in this period of work are four ranks of coal samples from Mammoth (Anthracite), Lower Kittanning, Upper Freeport and Pittsburgh No. 8 seam coals. The results showed that a drastic improvement in the flotation rate and yield were achieved by using the ultrasonic energy dispersed collector flotation compared to that of conventional flotation. The techniques of direct liquid addition and addition of ultrasonic energy dispersed collector are mainly for alteration of the hydrophobicity distribution of coal particle surfaces. On the contrary, the gasified collector addition to the gas phase technique is for alteration of the chemical properties of bubble surfaces. Among these techniques, however, the results showed that the hydrocarbon oil encapsulated bubble flotation is more selective than either ultrasonic energy dispersed collector flotation process or conventional flotation process. Induction time measurement was continued and extended to the coal samples received in this period of work, using oil free air bubble and oil-coated air bubbles. Induction time for oil-coated bubbles is significantly shorter than that of oil-free bubbles for all the coal samples used. A good agreement between flotation responses and induction time were obtained for all the coal samples under the conditions of various modes of collector dispersion.

  18. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  19. Testing of pyrite flotation techniques on selected Ohio coals: Final report

    SciTech Connect

    Arnold, B.J.; Torak, E.R.

    1989-05-01

    The project was conceived to demonstrate the combining of conventional physical coal cleaning with emerging advanced physical coal cleaning technologies in a cost-effective manner. The objectives of the program were to demonstrate that conventional coal cleaning followed by advanced coal cleaning of a crushed mid-gravity portion of the run-of-mine coal would produce a clean coal, suitable for use as a thermal coal, having a lower ash content and a lower sulfur dioxide emission potential than a coal cleaned only be current conventional cleaning technologies. As part of this program a number of advanced flotation techniques were tested to determine the feasibility of including them in the design of their Advanced Coal Preparation Facility. The program consisted of testing the Pittsburgh seam, the Middle Kittanning seam, and the Meigs Creek seam coals in the pilot flotation circuit at EPRI's Coal Quality Development Center (CQDC) in Homer City, Pennsylvania. This report contains all the data from OCDO's pilot flotation test program at the CQDC and the test data from the Middle Kittanning and Meigs Creek reverse flotation tests. 13 figs., 40 tabs.

  20. Foam flotation as a separation process

    NASA Technical Reports Server (NTRS)

    Currin, B. L.

    1986-01-01

    The basic principles of foam separation techniques are discussed. A review of the research concerning bubble-particle interaction and its role in the kinetics of the flotation process is given. Most of the research in this area deals with the use of theoretical models to predict the effects of bubble and particle sizes, of liquid flow, and of various forces on the aperture and retention of particles by bubbles. A discussion of fluid mechanical aspects of particle flotation is given.

  1. Flotation separation of waste plastics for recycling-A review.

    PubMed

    Wang, Chong-qing; Wang, Hui; Fu, Jian-gang; Liu, You-nian

    2015-07-01

    The sharp increase of plastic wastes results in great social and environmental pressures, and recycling, as an effective way currently available to reduce the negative impacts of plastic wastes, represents one of the most dynamic areas in the plastics industry today. Froth flotation is a promising method to solve the key problem of recycling process, namely separation of plastic mixtures. This review surveys recent literature on plastics flotation, focusing on specific features compared to ores flotation, strategies, methods and principles, flotation equipments, and current challenges. In terms of separation methods, plastics flotation is divided into gamma flotation, adsorption of reagents, surface modification and physical regulation.

  2. [PAH removal from black sludge from aluminium industry by flotation using non-ionic surfactants].

    PubMed

    Dhenain, A; Mercier, G; Blais, J F; Bergeron, M

    2006-09-01

    The valorization of black sludge is an environmental problem of the aluminium industry because of Polycyclic Aromatic Hydrocarbon (PAH), fluoride and alumina contents. A soil washing operated in a cell flotation with non-ionic surfactants (Brij 35, Igepal CA-720, Triton X-100, Tween 80) at different concentrations has been tested in order to remove the PAH (benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(j)fluoranthene, benzo(k)fluoranthene, fluoranthene) detected in black sludge. The Tween 80 at 0.5% gave the best results with PAH removal rates between 35 and 50%. These percentages remain low due to the presence in large quantity of fine solid particles (45%) in the PAH concentrate produced by the flotation process. The substitution of the cell flotation by a column flotation allowed the reduction of this problem. Thus, the PAH removal rates reached 60%. This removal yield has been obtained with the lowest wash water flow-rate (150 ml min(-1)) and pulp total solids (10% p p(-1)) tested.

  3. 33 CFR 183.112 - Flotation material and air chambers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.112 Flotation material and air chambers. (a)...

  4. 33 CFR 183.112 - Flotation material and air chambers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.112 Flotation material and air chambers. (a)...

  5. 33 CFR 183.112 - Flotation material and air chambers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.112 Flotation material and air chambers. (a)...

  6. A review of factors that affect contact angle and implications for flotation practice.

    PubMed

    Chau, T T; Bruckard, W J; Koh, P T L; Nguyen, A V

    2009-09-30

    . Other advanced techniques and measures complementary to contact angle will be essential to establish the link between research and practice in flotation.

  7. Vitrification of copper flotation waste.

    PubMed

    Karamanov, Alexander; Aloisi, Mirko; Pelino, Mario

    2007-02-09

    The vitrification of an hazardous iron-rich waste (W), arising from slag flotation of copper production, was studied. Two glasses, containing 30wt% W were melted for 30min at 1400 degrees C. The first batch, labeled WSZ, was obtained by mixing W, blast furnace slag (S) and zeolite tuff (Z), whereas the second, labeled WG, was prepared by mixing W, glass cullet (G), sand and limestone. The glass frits showed high chemical durability, measured by the TCLP test. The crystallization of the glasses was evaluated by DTA. The crystal phases formed were identified by XRD resulting to be pyroxene and wollastonite solid solutions, magnetite and hematite. The morphology of the glass-ceramics was observed by optical and scanning electron microscopy. WSZ composition showed a high rate of bulk crystallization and resulted to be suitable for producing glass-ceramics by a short crystallization heat-treatment. WG composition showed a low crystallization rate and good sinterability; glass-ceramics were obtained by sinter-crystallization of the glass frit.

  8. Hydrocarbon-oil encapsulated air bubble flotation of fine coal. Technical progress report for the fifth quarter, October 1, 1991--December 30, 1991

    SciTech Connect

    Peng, F.F.

    1995-01-01

    A main portion of this reporting period has been consumed in the following tasks: (i) Contact angle measurement using gasified collector encapsulated bubble; (ii) wettability measurement using film flotation method; (iii) induction time measurement; (iv) conducting atomized collector flotation tests in a stirred tank cell; (v) developing the experimental design and conducting a column flotation test. The coal samples used in this period of work are five ranks of coal samples from Mammoth, Lower Kittanning, Upper Freeport, Pittsburgh No. 8 and Wyodak seam coals. To better understand the fundamental steps involved in the modes of collector addition techniques in the froth flotation, contact angle, wettability and induction time were measurement. It was found increasing in the contact angles and decreasing in the induction time for a hydrocarbon-oil encapsulated air bubble compared to those for an oil-free bubble for all the coal samples measured. These observations may account for the improved flotation kinetics and, hence, the recovery with the hydrocarbon-oil encapsulated bubbles. Two level fractional factorial experimental design were developed for conducting the column flotation tests to obtain the optimal operating conditions. In the first series of the tests, seven operating parameters were considered with 16 runs. Based on those results, subsequently, the second experimental design was developed for six operating parameters with 16 runs. The third experiment design was formulated with three most significant operating parameters with 8 runs. A high combustible recovery was obtained for -200 mesh Upper Freeport coal sample. However, the results indicated that for further reduction of the ash content of the froth product, the height of column flotation cell needed to be increased.

  9. 46 CFR 25.25-13 - Personal flotation device lights.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 1 2012-10-01 2012-10-01 false Personal flotation device lights. 25.25-13 Section 25.25... Preservers and Other Lifesaving Equipment § 25.25-13 Personal flotation device lights. (a) This section... device intended to be worn, and each buoyant vest must have a personal flotation device light that...

  10. 46 CFR 25.25-13 - Personal flotation device lights.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 1 2011-10-01 2011-10-01 false Personal flotation device lights. 25.25-13 Section 25.25... Preservers and Other Lifesaving Equipment § 25.25-13 Personal flotation device lights. (a) This section... device intended to be worn, and each buoyant vest must have a personal flotation device light that...

  11. 46 CFR 25.25-13 - Personal flotation device lights.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 1 2014-10-01 2014-10-01 false Personal flotation device lights. 25.25-13 Section 25.25... Preservers and Other Lifesaving Equipment § 25.25-13 Personal flotation device lights. (a) This section... device intended to be worn, and each buoyant vest must have a personal flotation device light that...

  12. 46 CFR 25.25-13 - Personal flotation device lights.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 1 2013-10-01 2013-10-01 false Personal flotation device lights. 25.25-13 Section 25.25... Preservers and Other Lifesaving Equipment § 25.25-13 Personal flotation device lights. (a) This section... device intended to be worn, and each buoyant vest must have a personal flotation device light that...

  13. 21 CFR 880.5550 - Alternating pressure air flotation mattress.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Alternating pressure air flotation mattress. 880... Personal Use Therapeutic Devices § 880.5550 Alternating pressure air flotation mattress. (a) Identification. An alternating pressure air flotation mattress is a device intended for medical purposes...

  14. 33 CFR 183.222 - Flotation material and air chambers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.222 Flotation material and air...

  15. 33 CFR 183.222 - Flotation material and air chambers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.222 Flotation material and air...

  16. 14 CFR 121.340 - Emergency flotation means.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 3 2012-01-01 2012-01-01 false Emergency flotation means. 121.340 Section... Emergency flotation means. (a) Except as provided in paragraph (b) of this section, no person may operate an...(a)(1) or with an approved flotation means for each occupant. This means must be within easy reach...

  17. 33 CFR 183.222 - Flotation material and air chambers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.222 Flotation material and air...

  18. 21 CFR 880.5550 - Alternating pressure air flotation mattress.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Alternating pressure air flotation mattress. 880... Personal Use Therapeutic Devices § 880.5550 Alternating pressure air flotation mattress. (a) Identification. An alternating pressure air flotation mattress is a device intended for medical purposes...

  19. 33 CFR 175.15 - Personal flotation devices required.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Personal flotation devices... SECURITY (CONTINUED) BOATING SAFETY EQUIPMENT REQUIREMENTS Personal Flotation Devices § 175.15 Personal flotation devices required. Except as provided in § 175.17 and 175.25: (a) No person may use a...

  20. 33 CFR 175.15 - Personal flotation devices required.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Personal flotation devices... SECURITY (CONTINUED) BOATING SAFETY EQUIPMENT REQUIREMENTS Personal Flotation Devices § 175.15 Personal flotation devices required. Except as provided in § 175.17 and 175.25: (a) No person may use a...

  1. 33 CFR 183.202 - Flotation and certification requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Flotation and certification... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.202 Flotation and...

  2. 33 CFR 175.15 - Personal flotation devices required.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Personal flotation devices... SECURITY (CONTINUED) BOATING SAFETY EQUIPMENT REQUIREMENTS Personal Flotation Devices § 175.15 Personal flotation devices required. Except as provided in § 175.17 and 175.25: (a) No person may use a...

  3. Froth flotation for fine-coal cleaning. Final report

    SciTech Connect

    Olson, T.J.

    1985-12-01

    Froth flotation of fine coal was investigated with the objectives of improving flotation at existing coal-cleaning plants and providing design guidance for future plants. Using hydrodynamically scaled-down laboratory and pilot flotation cells, and the Klimpel flotation model, a methodology was developed to relate laboratory-scale flotation results to full-scale flotation circuits. Froth Factor, the percent of froth over the froth lip, was determined to be the key element of this scale-up methodology. Results showed that simple, inexpensive changes in flotation parameters such as air rate and reagent dosages can significantly improve full-scale flotation product recovery and grade, and that more complex flotation circuitry can produce better recovery levels of high-grade coal than more commonly used rougher-only flotation circuits. In particular, cleaning rougher product can effectively reduce pyritic sulfur content. Results also demonstrated interaction between different size fractions of coal. Flotation rates were shown to depend on feed size consist, and it was found that separations based on differences in flotation rates are more advantageously performed on fine topsizes. Ultimate recoveries appear unaffected by size consist. 6 refs.

  4. 14 CFR 121.340 - Emergency flotation means.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 3 2011-01-01 2011-01-01 false Emergency flotation means. 121.340 Section... Emergency flotation means. (a) Except as provided in paragraph (b) of this section, no person may operate an...(a)(1) or with an approved flotation means for each occupant. This means must be within easy reach...

  5. 33 CFR 175.15 - Personal flotation devices required.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Personal flotation devices... SECURITY (CONTINUED) BOATING SAFETY EQUIPMENT REQUIREMENTS Personal Flotation Devices § 175.15 Personal flotation devices required. Except as provided in § 175.17 and 175.25: (a) No person may use a...

  6. 33 CFR 183.112 - Flotation material and air chambers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.112 Flotation material and air chambers. (a)...

  7. 14 CFR 121.340 - Emergency flotation means.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 3 2013-01-01 2013-01-01 false Emergency flotation means. 121.340 Section... Emergency flotation means. (a) Except as provided in paragraph (b) of this section, no person may operate an...(a)(1) or with an approved flotation means for each occupant. This means must be within easy reach...

  8. 33 CFR 183.105 - Quantity of flotation required.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Quantity of flotation required... (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.105 Quantity of flotation required. (a) Each boat must have...

  9. 33 CFR 183.202 - Flotation and certification requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation and certification... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.202 Flotation and...

  10. 14 CFR 121.340 - Emergency flotation means.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 3 2014-01-01 2014-01-01 false Emergency flotation means. 121.340 Section... Emergency flotation means. (a) Except as provided in paragraph (b) of this section, no person may operate an...(a)(1) or with an approved flotation means for each occupant. This means must be within easy reach...

  11. 21 CFR 880.5550 - Alternating pressure air flotation mattress.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Alternating pressure air flotation mattress. 880... Personal Use Therapeutic Devices § 880.5550 Alternating pressure air flotation mattress. (a) Identification. An alternating pressure air flotation mattress is a device intended for medical purposes...

  12. Physically absorbable reagents-collectors in elementary flotation

    SciTech Connect

    S.A. Kondrat'ev; I.G. Bochkarev

    2007-09-15

    Based on the reviewed researches held at the Institute of Mining, Siberian Branch, Russian Academy of Sciences, the effect of physically absorbable reagents-collectors on formation of a flotation complex and its stability in turbulent pulp flows in flotation machines of basic types is considered. The basic requirements for physically absorbable reagents-collectors at different flotation stages are established.

  13. 46 CFR 25.25-13 - Personal flotation device lights.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Personal flotation device lights. 25.25-13 Section 25.25... Preservers and Other Lifesaving Equipment § 25.25-13 Personal flotation device lights. (a) This section... device intended to be worn, and each buoyant vest must have a personal flotation device light that...

  14. 33 CFR 183.222 - Flotation material and air chambers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.222 Flotation material and air...

  15. 33 CFR 183.202 - Flotation and certification requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Flotation and certification... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.202 Flotation and...

  16. 33 CFR 175.15 - Personal flotation devices required.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Personal flotation devices... SECURITY (CONTINUED) BOATING SAFETY EQUIPMENT REQUIREMENTS Personal Flotation Devices § 175.15 Personal flotation devices required. Except as provided in § 175.17 and 175.25: (a) No person may use a...

  17. 14 CFR 121.340 - Emergency flotation means.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Emergency flotation means. 121.340 Section... Emergency flotation means. (a) Except as provided in paragraph (b) of this section, no person may operate an...(a)(1) or with an approved flotation means for each occupant. This means must be within easy reach...

  18. 33 CFR 183.112 - Flotation material and air chambers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Flotation material and air... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.112 Flotation material and air chambers. (a)...

  19. 33 CFR 183.105 - Quantity of flotation required.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Quantity of flotation required... (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Inboard Boats, Inboard/Outdrive Boats, and Airboats § 183.105 Quantity of flotation required. (a) Each boat must have...

  20. 21 CFR 880.5150 - Nonpowered flotation therapy mattress.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Nonpowered flotation therapy mattress. 880.5150... Therapeutic Devices § 880.5150 Nonpowered flotation therapy mattress. (a) Identification. A nonpowered flotation therapy mattress is a mattress intended for medical purposes which contains air, fluid, or...

  1. 21 CFR 880.5150 - Nonpowered flotation therapy mattress.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Nonpowered flotation therapy mattress. 880.5150... Therapeutic Devices § 880.5150 Nonpowered flotation therapy mattress. (a) Identification. A nonpowered flotation therapy mattress is a mattress intended for medical purposes which contains air, fluid, or...

  2. Dissolved mineral species precipitation during coal flotation

    SciTech Connect

    Somasundaran, P.; Liu, D.

    1995-12-31

    Beneficiation by froth flotation, which exploits the difference in surface properties of minerals, has been a promising method for coal cleaning.However, dissolved mineral species present in coal flotation systems can interact with particles and other species leading to drastic effects on flotation. Particularly, precipitation or adsorption of such species on the particles can alter their surface properties and thus influence the efficiency of coal cleaning. In this work, the bulk and surface precipitation of the dissolved mineral species present in Pittsburgh No. 8 coal was investigated under controlled experimental conditions. Changes in the surface properties of coal due to the precipitation were monitored by following zeta potential. Solution potential data were used to elucidate the mechanism of the precipitation. The effect of the precipitation of the dissolved species on the floatability of coal was found to be marked.

  3. Flotation of cadmium-loaded biomass

    SciTech Connect

    Matis, K.A.; Zouboulis, A.I. . Chemical Technology Div.)

    1994-07-01

    Biosorption of heavy metal ions such as Cd[sup 2+] by dead biomass has been recognized as a potential alternative to existing removal technologies applied to wastewater treatment. Two bacterial strains were studied in the laboratory, Streptomyces griseus and S. clavuligerus, an industrial by-product. Both washed and unwashed samples were examined. Foam flotation is proposed in this work as the separation stage following biosorption. Effective biomass separation was conducted in the presence of a frother, ethanol. The pH of the solution was a crucial parameter for flotation and also for metal binding. Other basic parameters of flotation examined were the initial cadmium concentration in the dilute aqueous solution and the quantity of biomass used. A study of [zeta]-potential measurements of the actinomycetes was carried out under the conditions used in the separation; surface tension was also measured. These provided useful information on the process.

  4. Removal of pyrite and trace elements from waste coal by dissolved- CO{sub 2} flotation and chelating agents. Technical report, September 1, 1993--November 30, 1993

    SciTech Connect

    Shiao, S.Y.

    1993-12-31

    In dissolved-CO{sub 2} flotation, ultrafine bubbles are generated by CO{sub 2} dissolved in water. The ultrafine bubbles have the potential to improve the separation efficiency in fine coal cleaning. Chemicals will be used prior to or during dissolved-CO{sub 2} flotation to improve the separation efficiency of pyrite and other minerals including trace metals from coal. Chelating agents will be applied to clean coal to further reduce the trace metals from coal. During this period, the project planning has begun. A 3in.-diameter packed column has been ordered. This column will be modified for use in dissolved-CO{sub 2} flotation. Clean and waste coal samples of Illinois No. 6 coal have been scheduled to be picked up from Ohio Coal Testing and Development (OCTAD) facility.

  5. Distillation Column Flooding Predictor

    SciTech Connect

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  6. Effect of microwave radiation on coal flotation

    SciTech Connect

    Ozbayoglu, G.; Depci, T.; Ataman, N.

    2009-07-01

    Most low-rank coals are high in moisture and acid functional groups, therefore showing poor floatability. Drying, which removes the water molecules trapped in the pores and adsorbed at the surface of coal, decreases the hydrophilic character and improves the floatability. Microwave heating, whose simplest application is drying, was applied at 0.9 kW power level for 60 sec exposure time in the experiments to decrease the moisture content of coal in order to enhance the hydrophobicity. The flotation tests of microwave-treated coal by using heptanol and octanol lead to a higher flotation yield and ash removal than original coal.

  7. A Multi-Objective Advanced Design Methodology of Composite Beam-to-Column Joints Subjected to Seismic and Fire Loads

    NASA Astrophysics Data System (ADS)

    Pucinotti, Raffaele; Ferrario, Fabio; Bursi, Oreste S.

    2008-07-01

    A multi-objective advanced design methodology dealing with seismic actions followed by fire on steel-concrete composite full strength joints with concrete filled tubes is proposed in this paper. The specimens were designed in detail in order to exhibit a suitable fire behaviour after a severe earthquake. The major aspects of the cyclic behaviour of composite joints are presented and commented upon. The data obtained from monotonic and cyclic experimental tests have been used to calibrate a model of the joint in order to perform seismic simulations on several moment resisting frames. A hysteretic law was used to take into account the seismic degradation of the joints. Finally, fire tests were conducted with the objective to evaluate fire resistance of the connection already damaged by an earthquake. The experimental activity together with FE simulation demonstrated the adequacy of the advanced design methodology.

  8. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy's program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research Development Center (Amax R D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  9. Removal of molybdate and arsenate from aqueous solutions by flotation

    SciTech Connect

    Zhao, Y.; Zouboulis, A.I.; Matis, K.A.

    1996-03-01

    Ion flotation and adsorbing colloid flotation have been studied in this paper for the effective removal of molybdenum(VI) and arsenic(V) from dilute aqueous solutions. These different flotation methods were also compared. Ion flotation using a cationic surfactant (dodecylamine) as collector, as well as adsorbing colloid flotation using ferric hydroxide as coprecipitant (or sorbent) and an anionic surfactant (sodium dodecyl sulfate) as collector were examined. Laboratory-scale experiments were conducted in order to assess the effects of the following parameters of the efficiency of the process: pH value, dosages of chemical reagents, initial concentrations of arsenic and molybdenum, and the presence of foreign anions, such as Cl{sup -} and SO{sup 2}{sub 4}{sup -}. In practical applications, ion flotation or adsorbing colloid flotation may be selected according to the concentration of arsenic, molybdenum, and also the initial [Mo]/[As] molar ratios in solution.

  10. A novel multistage kinetic modeling of flotation for wastewater treatment.

    PubMed

    Ksenofontov, B S; Ivanov, M V

    2013-01-01

    This study develops a new model for description of flotation kinetics. It defines flotation as a process that consists of several stages: separated air bubbles and particles, air bubbles and particles forming an aggregate, aggregate rising to the froth layer. This description significantly differs from known models, which are much simplified. The multistage model gives a novel in-depth description and considers different aspects of flotation, i.e. aggregate formation, which is critically important for flotation to take place. Experimental approval of the new model resulted in its accuracy. The model is to be used for a description of kinetics of all flotation processes in wastewater treatment. It helps in accurate design of flotation treatment plants and may be used for further research of the flotation process.

  11. Axial flow reversal and its significance in air-sparged hydrocyclone (ASH) flotation

    SciTech Connect

    Miller, J.D.; Das, A.; Yin, D.

    1995-12-31

    In recent years the potential of air-sparged hydrocyclone (ASH) flotation for fine coal cleaning has been demonstrated both in pilot plant testing and in a plant-site demonstration program. Further improvements in the ASH technology will depend, to some extent, on improved understanding of the complex multiphase fluid flow. Froth transport plays a very important role in determining the efficiency of fine coal cleaning by ASH flotation. It should be noted that the surface of zero axial velocity is of particular significance in froth transport because the location of this surface actually accounts for the amount of froth being transported to the overflow. In this regard, the axial flow reversal has been examined based on specially designed tracer experiments. On the basis of these experimental results, modeling efforts were made to characterize the flow pattern in the ASH. The theoretical predictions based on turbulent fluid dynamic considerations were found to describe experimental observations regarding the surface of zero axial velocity. These results that define the surface of zero axial velocity together with froth phase features established from X-ray CT measurements provide an excellent description of the flow characteristics in ASH flotation and explain the effect of various process variables, such as dimensionless area (A*), dimensionless flowrate (Q*), inlet pressure, percent solids, etc., on flotation recovery. On this basis it is expected that further advances in the design and operation of the ASH system can be made, leading to more efficient use of the ASH technology for fine coal cleaning.

  12. Benzene stripping in a flotation unit

    SciTech Connect

    Hillquist, D.; Litchfield, J.; Willet, S.; Whiteford, R.

    1994-12-31

    An induced gas flotation unit is used as a combination stripping/flotation vessel with fuel gas as the stripping/flotation medium. The gas bubbles simultaneously float the oils and solids, and strip out and recover the benzene and other volatile components from wastewater and from the floated oils and solids. The effluent stripping gas is then either used as fuel gas, or recycled to the process for product recovery. The induced gas flotation stripper, IGFS, is self-cleaning and normally experiences no sludge build up or fouling. The unit requires a minimum of operator attention and maintenance. It is sealed to eliminate emissions, has a high stripping efficiency, and has a significantly wider operating range than conventional strippers. The unit does not experience the biological fouling and disposal problems of air strippers, or the fouling and higher capital and operating costs of steam strippers. The IGFS unit was installed at the BF Goodrich ethylene plant in Calvert City in 1991. The unit was designed to treat a combined stream consisting of quench water, neutralized spent caustic, and a number of intermittent smaller oily water streams. The unit is operating effectively in stripping the benzene to levels below the NESHAP requirements. The average benzene removal efficiency is above 97%. Operating data indicate that the benzene removal efficiency can be further enhanced by increasing temperature, increasing stripping flow, reducing oil emulsions in the influent and eliminating dilution from recycled water. This paper presents performance and operating experience of the IGFS unit.

  13. Plagioclase flotation and lunar crust formation

    NASA Technical Reports Server (NTRS)

    Walker, D.; Hays, J. F.

    1977-01-01

    Anorthitic plagioclase floats in liquids parental to the lunar highlands crust. The plagioclase enrichment that is characteristic of lunar highlands rocks can be the result of plagioclase flotation. Such rocks would form a gravitationally stable upper crust on their parental magma.

  14. Commercial applications of the packed column froth separator

    SciTech Connect

    Yang, D.C.; Mengxiong Guo; Xusin Shao; Zexue Du

    1993-12-31

    The packed column flotation technology is commercially proven in processing a variety of coal and mineral fines. It incorporates the packing design to overcome most of the problems encountered by conventional columns or open vessel type cells. The packing elements break up air bubbles through small tortuous passages and support an unlimited froth depth inside the column where nearly all separation takes place. Thus, the packed column is actually a froth separator. The first commercial packed column for coal application was installed at the Pingdingshan Mine, China in 1989. This unit (1.5 m ID {times} 7 m tall) has been used to recover clean coal ({approximately}6% ash) from the black water (10--15% ash) with 82--88% coal yield. The capacity of the unit is 10--12 TPH. Some modifications of the column are being considered to improve product quality and to simplify control strategy.

  15. Effects of surfactant on bubble hydrodynamic behavior under flotation-related conditions in wastewater.

    PubMed

    Li, Yanpeng; Zhu, Tingting; Liu, Yanyan; Tian, Ye; Wang, Huanran

    2012-01-01

    Bubble behavior is fundamental to the performance of froth flotation operations used in wastewater treatment processes. To fully understand and characterize bubble behavior under flotation-related conditions in wastewater, the high-speed photographic method has been employed to examine the motion of single bubbles and size distribution of bubble swarms with intermediate sizes ranging from 1 to 4 mm in the presence of surfactants in a laboratory scale flotation column. Both distilled water and synthetic municipal wastewater have been used to make solutions as well as two types of common surfactants. The instantaneous bubble motion has been recorded by a high speed camera. Subsequently, bubble trajectory, dimensions, velocity and distribution have been determined from the recorded frames using the image analysis software. The experimental results show that the addition of surfactant into wastewater has similar effects on bubble hydrodynamic behavior as in pure water (e.g., improving trajectory stabilization, dampening bubble deformation, slowing down terminal velocity, reducing bubble size and increasing the specific surface area of bubble swarm) due to the Marangoni effect. However, it is interesting to note that surfactant effects on single bubble hydrodynamics in wastewater are slightly stronger than those in pure water while surfactant effects on size parameters of bubble swarms in wastewater are significantly stronger than those in pure water. This finding suggests that besides surfactant, inorganic salts present in synthetic wastewater have an important influence on bubble dispersion.

  16. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 8, July 1994--September 1994

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1994-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2 t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 8 (July - September, 1994), work on the formulation of coal water slurries from flotation concentrates was completed. Parametric and optimization tests were performed on the Indiana VII coal using a 12-inch MicrocelT{sup M} flotation column. Laboratory research on selective agglomeration was completed with limited testing of the Dietz coal and alternate agglomerants. Initial planning has started for the bench-scale agglomeration unit which will utilize heptane as the bridging liquid in a conventional two-stage system, and steam stripping for heptane recovery and recycle. A project review meeting was held at Bechtel to discuss the detailed design of the PDU, which is being designed to process Indiana VII, Sunnyside, and Taggart coals. Process flow, piping and instrument, and equipment layout diagrams are being revised to reflect the process improvements resulting from bench-scale testing. Material Requisition activity has commenced, and will continue next quarter along with the selection of a construction subcontractor.

  17. Enhanced pyrite rejection in coal flotation

    SciTech Connect

    Tao, D.P.; Lu, M.X.; Richardson, P.E.; Luttrell, G.H.; Adel, G.T.; Yoon, R.H.

    1994-12-31

    Difficulties in rejecting pyrite from coal by flotation primarily result from two mechanisms of particle recovery: attachment and middlings. Attachment of pyrite is the consequence of surface hydrophobicity induced by superficial oxidation; middlings that can float readily are caused by incomplete liberation of pyrite from coal. New flotation schemes have been developed to enhance pyrite rejection. They are referred to as Electrochemically-Enhanced Sulfur Rejection (EESR) and Polymer-Enhanced Sulfur Rejection (PESR) processes. In the EESR process, the formation of hydrophobic products is prevented by electrochemical techniques in which active metals are used as sacrificial anodes to cathodically protect pyrite from oxidation; in the PESR process, hydrophilic polymers is used to mask coal in middlings by specific adsorption on pyrite, and thus depress coal-pyrite middlings.

  18. Flotation machine and process for removing impurities from coals

    DOEpatents

    Szymocha, Kazimierz; Ignasiak, Boleslaw; Pawlak, Wanda; Kulik, Conrad; Lebowitz, Howard E.

    1995-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  19. Flotation machine and process for removing impurities from coals

    DOEpatents

    Szymocha, Kazimierz; Ignasiak, Boleslaw; Pawlak, Wanda; Kulik, Conrad; Lebowitz, Howard E.

    1997-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  20. The behavior of each species in coal flotation

    SciTech Connect

    Liu, W.; Lu, M.; Ren, S.; Kou, C.

    1999-07-01

    The work presented in this paper mainly focused on the study into the flotation behavior of each species at different levels of collector dosage, frother dosage, and air volumetric flow rate. Examination of the flotation response of the discrete particle size fraction reveals that the flotation behavior of each size fraction does not follow the first order model. The flotation rate constant decreases with the increase of flotation time. The recovery of minus 74 micron fraction has a good relationship with the amount of floated water. The relationship between water flotation rate, Kw, and frother dosage, collector dosage and air volumetric flow rate is also discussed. By this relationship, the amount of floated water can be predicted according to the addition rate of frother, collector and air volumetric flow rate during the flotation procedure, and further the recovery of minus 74 micron coal can also be predicted. Examination of the flotation behavior of each discrete density fraction shows that it also does not follow the first order model. A further investigation of each density fraction within the same size fraction is also conducted. It is found that the behavior of the narrower species fits the first order model well. By statistical analysis, the models, which represent the relationship between the flotation rate constant of each narrower species and the manipulated variables (frother, collector and air flow rate), have been built. On these models built above, the product quantity and quality can be predicted on-line.

  1. Flotation machine and process for removing impurities from coals

    DOEpatents

    Szymocha, K.; Ignasiak, B.; Pawlak, W.; Kulik, C.; Lebowitz, H.E.

    1997-02-11

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal. 4 figs.

  2. Flotation machine and process for removing impurities from coals

    DOEpatents

    Szymocha, K.; Ignasiak, B.; Pawlak, W.; Kulik, C.; Lebowitz, H.E.

    1995-12-05

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other mineral particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal. 4 figs.

  3. [Assessment of schemes for sewage purification from petroleum products, by using various flotation methods].

    PubMed

    Zabuga, G A; Filippova, T M; Sivkov, A A

    2010-01-01

    Petroleum products are the most common pollutants in petroleum refinery wastewater and are freed from the latter by flotation that is one of the most frequently applied physicochemical methods. The existing petroleum refinery OAO "Angara Petroleum Company" scheme for sewage purification from petroleum products, by using pressure flotation and proposed as a competitive purification scheme by applying electrical and impeller flotations underwent a comparative ecologoeconomic analysis. The use of electrical flotation instead of pressure flotation and that of an impeller flotation-electrical flotation system instead of a mechanical purification-pressure flotation one can considerably lower the concentration of petroleum products at the wastewater outlet into the Angara river.

  4. Elk Valley coal implements smartcell flotation technology

    SciTech Connect

    Stirling, J.C.

    2008-06-15

    In anticipation of future raw coal containing higher fines content, Elk Valley Coal Corp.'s Greenhills Operations upgraded their fines circuit to include Wemco SmartCells in March 2007. Positive results were immediately achieved increasing the average flotation tailings ash by 16%. With this increase in yield the SmartCells project paid for itself in less than eight months. 2 figs., 1 tab., 1 photo.

  5. ENGINEERING DEVELOPMENT OF ADVANCED PHYSICAL FINE COAL CLEANING FOR PREMIUM FUEL APPLICATIONS

    SciTech Connect

    none,

    1997-06-01

    Bechtel, together with Amax Research and Development Center (Amax R&D), has prepared this study which provides conceptual cost estimates for the production of premium quality coal-water slurry fuel (CWF) in a commercial plant. Two scenarios are presented, one using column flotation technology and the other the selective agglomeration to clean the coal to the required quality specifications. This study forms part of US Department of Energy program "Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications," (Contract No. DE-AC22- 92PC92208), under Task 11, Project Final Report. The primary objective of the Department of Energy program is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to stable and highly loaded CWF. The fuels should contain less than 2 lb ash/MBtu (860 grams ash/GJ) of HHV and preferably less than 1 lb ash/MBtu (430 grams ash/GJ). The advanced fine coal cleaning technologies to be employed are advanced column froth flotation and selective agglomeration. It is further stipulated that operating conditions during the advanced cleaning process should recover not less than 80 percent of the carbon content (heating value) in the run-of-mine source coal. These goals for ultra-clean coal quality are to be met under the constraint that annualized coal production costs does not exceed $2.5 /MBtu ($ 2.37/GJ), including the mine mouth cost of the raw coal. A further objective of the program is to determine the distribution of a selected suite of eleven toxic trace elements between product CWF and the refuse stream of the cleaning processes. Laboratory, bench-scale and Process Development Unit (PDU) tests to evaluate advanced column flotation and selective agglomeration were completed earlier under this program with selected coal samples. A PDU with a capacity of 2 st/h was designed by Bechtel and installed at Amax R

  6. A theoretical model of flotation deinking efficiency

    SciTech Connect

    Bloom, F.; Heindel, T.J.

    1997-06-01

    The associated probabilities of each microprocess occurring in flotation deinking are employed in the development of a kinetic or population balance-type model of the overall flotation process. The overall model contains two kinetic constants: The first, k{sub 1}, governs the overall probability of a free ink particle successfully being intercepted by and adhering to an air bubble; the second, k{sub 2}, is a measure of the probability that a particle/bubble aggregate pair will become unstable and split to yield a new free ink particle. The solution to the kinetic model is presented in terms of k{sub 1} and k{sub 2}, which are themselves functions of system parameters such as bubble and particle physical properties (e.g., diameter, density) and fluid properties (e.g., viscosity, surface tension). From this solution, a definition of theoretical flotation efficiency is presented, as well as definitions of other system performance parameters, and selected predictions are displayed.

  7. Hydrocarbon-oil encapsulated air bubble flotation of fine coal. Technical progress report for the second quarter, January 1, 1991--March 31, 1991

    SciTech Connect

    Peng, F.F.

    1995-01-01

    The objective of the present work is to have a good understanding on the fundamentals of modes of reagent/collector dispersion and adsorbing collector on the bubbles to improve the selectivity and recovery of fine coal flotation. A portion of this reporting period has been consumed in building experimental apparatus and equipment. These include an automated flotation machine, a computer-based induction time apparatus, a bubble charge measuring apparatus, continuous flotation column, etc. An automated flotation machine was constructed for Denver model D-12 with 2- and 4-liter cells. The standard test procedure was established for using the machine with improved pulp level control and constant frother removal to minimize the human error. The flotation results of Upper Freeport coal sample showed a good reproducibility for using the improved automatic flotation machine/cell. The reagentless flotation was conducted in a Hallimond tube to determine the hydrophobicity of coal particles. Upper Freeport coal samples were used for all of the tests including -30 mesh, -200 mesh and -400 mesh U.S. sieves coal samples. High floatability was obtained for Upper Freeport coal samples. The significant entrainment of fine particles were observed for coal samples with -200 mesh and -400 mesh U.S. Sieve samples. The electrokinetic properties of coal particles from Upper Freeport seam was determined as the function of pH, frother or collector concentrations. The IEP of -200 mesh coal particle was at pHaw.53. The zeta potential of the coal particles with or without addition of MIBC or kerosene were exhibited negative values for pH greater than 3 and decreased with increasing pH values. The coal particles with kerosene has the higher zeta-potential value than that of particles with MIBC or free of frother/collector. The negative zeta-potential of coal sample was also observed regardless of MIBC concentration employed.

  8. Eruption column physics

    SciTech Connect

    Valentine, G.A.

    1997-03-01

    In this paper the author focuses on the fluid dynamics of large-scale eruption columns. The dynamics of these columns are rooted in multiphase flow phenomena, so a major part of the paper sets up a foundation on that topic that allows one to quickly assess the inherent assumptions made in various theoretical and experimental approaches. The first part is centered on a set of complex differential equations that describe eruption columns, but the focus is on a general understanding of important physical processes rather than on the mathematics. The author discusses briefly the relative merits and weaknesses of different approaches, emphasizing that the largest advances in understanding are made by combining them. He then focuses on dynamics of steady eruption columns and then on transient phenomena. Finally he briefly reviews the effects of varying behavior of the ambient medium through which an eruption column moves. These final sections will emphasize concepts and a qualitative understanding of eruption dynamics. This paper relies on principles of continuum mechanics and transport processes but does not go into detail on the development of those principles. 36 refs., 36 figs., 3 tabs.

  9. Engineereing development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 5, October--December 1993

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1994-02-18

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. The project has three major objectives: The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  10. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 1, October--December 1992

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy`s program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research & Development Center (Amax R&D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  11. 21 CFR 880.5550 - Alternating pressure air flotation mattress.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... body pressure. The device is used to prevent and treat decubitus ulcers (bed sores). (b) Classification... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Alternating pressure air flotation mattress. 880... Personal Use Therapeutic Devices § 880.5550 Alternating pressure air flotation mattress. (a)...

  12. 33 CFR 142.45 - Personal flotation devices.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Personal flotation devices. 142.45 Section 142.45 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... § 142.45 Personal flotation devices. Personnel, when working in a location such that, in the event of...

  13. 33 CFR 142.45 - Personal flotation devices.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Personal flotation devices. 142.45 Section 142.45 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... § 142.45 Personal flotation devices. Personnel, when working in a location such that, in the event of...

  14. 33 CFR 142.45 - Personal flotation devices.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Personal flotation devices. 142.45 Section 142.45 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... § 142.45 Personal flotation devices. Personnel, when working in a location such that, in the event of...

  15. 33 CFR 142.45 - Personal flotation devices.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Personal flotation devices. 142.45 Section 142.45 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... § 142.45 Personal flotation devices. Personnel, when working in a location such that, in the event of...

  16. 33 CFR 183.202 - Flotation and certification requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.202 Flotation and certification requirements. Each boat to which this subpart applies must be manufactured, constructed, or assembled to...

  17. 33 CFR 183.202 - Flotation and certification requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower General § 183.202 Flotation and certification requirements. Each boat to which this subpart applies must be manufactured, constructed, or assembled to...

  18. Beneficiation of borax by reverse flotation in boron saturated brine.

    PubMed

    Cafer Cilek, Emin; Uresin, Hasan

    2005-10-15

    Flotation is one of the plausible methods for recovering borax fines discharged as fine waste to the tailings dam in the Kirka borax processing plant. A literature review dealing with the flotation behavior of boron minerals reveals that clay minerals in the boron ores coat boron minerals and thus deteriorate the quality of boron concentrates produced by direct flotation. The main objective of this study is therefore to recover borax fines from the tailings of the concentrator by reverse flotation. A three-level-factor experimental design was used to determine the main and interaction effects of variables selected on the metallurgical performance of reverse flotation. An analysis of variance for experimental results indicates that interaction effects of the variables for concentrate quality and recovery of B2O3 is nonsignificant and the most important variable for grade of concentrate and recovery is the collector dosage. It is shown that a concentrate assaying 11.25% B2O3 with 89.90% B2O3 recovery could be produced by means of single-stage (rougher) reverse flotation. Additionally, in order to produce a sufficient-quality concentrate, a multistage reverse flotation scheme involving rougher, scavenger, and two cleaners was devised. A final concentrate containing 23.47% B2O3 with 81.78% B2O3 recovery was obtained from these tests. The reverse flotation method can be thus considered as an important option for the beneficiation of borax fines.

  19. 46 CFR 170.245 - Foam flotation material.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Foam flotation material. 170.245 Section 170.245... REQUIREMENTS FOR ALL INSPECTED VESSELS Special Installations § 170.245 Foam flotation material. (a... strength to withstand a hydrostatic head equivalent to that which would be imposed if the vessel...

  20. 33 CFR 183.225 - Flotation test for persons capacity.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation test for persons capacity. 183.225 Section 183.225 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Boats Rated for Engines of More Than 2 Horsepower Tests § 183.225 Flotation test for persons...

  1. 33 CFR 183.325 - Flotation test for persons capacity.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Flotation test for persons capacity. 183.325 Section 183.325 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Boats Rated for Engines of 2 Horsepower or Less Tests § 183.325 Flotation test for persons...

  2. 33 CFR 183.222 - Flotation material and air chambers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Flotation material and air chambers. 183.222 Section 183.222 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND... Boats Rated for Engines of More Than 2 Horsepower General § 183.222 Flotation material and air...

  3. Additive-free harvesting of oleaginous phagotrophic microalga by oil and air flotation.

    PubMed

    Hosseini, Majid; Starvaggi, Haley A; Ju, Lu-Kwang

    2016-07-01

    A unique oleaginous phagotrophic microalga Ochromonas danica is poised for effective lipid production from waste. Cell harvesting and dewatering are major costs in making algae-based products. In this work an effective additive-free harvesting method was developed, taking advantage of O. danica's comparatively more hydrophobic surface and larger size. The algal cells' partitioning to oil/water interface was evaluated. Recovery by flotation with waste cooking oil was optimized using an L-9 Taguchi orthogonal-array design. Further, additive-free cell collection and concentrating by air flotation was studied for the effects of both physical factors (column dimension, air-stone pore size, sample-to-column volume ratio) and culture properties (pH, culture growth stage, cell concentration, and pure versus impure cultures). The optimized process consistently achieved >90 % recovery in a single stage. 98+ % recovery could be achieved when starting concentrations were >10(8) cells/ml, or potentially using a two- or multi-stage process for diluter cultures.

  4. Pressure flotation of nitrocellulose fines: Hydrodynamics and interfacial chemistry

    SciTech Connect

    Grasso, D.; Hu, H.L.; LaFrance, P.; Kim, B.J.

    1996-11-01

    The production of nitrocellulose (NC) creates large quantities of waste NC fines in wash water streams. Current processing techniques attempt to remove these fines by cross-flow microfiltration, pressure flotation, settling, centrifugation, and lime precipitation. Pressure flotation, or dissolved air flotation (DAF), is a solid/liquid separation process first developed in the ore processing industry. DAF has since found many applications in the environmental engineering field including: drinking water clarification, sludge thickening, and the clarification of wastewater from a variety of industrial and municipal processes. The work presented herein is part of a larger effort to explore techniques to recover and reuse nitrocellulose (NC) fines resulting from propellant manufacturing processes. Previous papers investigated NC particle stability and interfacial thermodynamics and developed a flotation trajectory model. This paper builds on that work and presents a sensitivity analysis of the flotation trajectory model. The sensitivity analysis explores both operational and parameter estimation uncertainty.

  5. A study of multistage/multifunction column for fine particle separation. Quarterly technical progress report, January 1, 1995-- March 31, 1995

    SciTech Connect

    Chiang, Shiao-Hung; Lai, R.W.

    1995-04-20

    The overall objective of the proposed research program is to explore the potential application of a new invention involving a multistage column equipped with vortex-inducing loopflow contactors (hereafter referred to as the multistage flotation column) for flotation process. The research work will identify the design parameters and their effects on the performance of the separation process. The results of this study will provide a basis for further development of this technology. In the last quarter, we completed equipment design and started to construct the new column for hydrodynamic tests. In this quarter, Task 2 (Equipment Design and Construction) was completed, and the experimental work mainly focused on gas holdup measurement.

  6. The sensitivity of direct faecal examination, direct faecal flotation, modified centrifugal faecal flotation and centrifugal sedimentation/flotation in the diagnosis of canine spirocercosis.

    PubMed

    Christie, J; Schwan, E V; Bodenstein, L L; Sommerville, J E M; van der Merwe, L L

    2011-06-01

    Several faecal examination techniques have shown variable sensitivity in demonstrating Spirocerca lupi (S. lupi) eggs. The objective of this study was to determine which faecal examination technique, including a novel modified centrifugal flotation technique, was most sensitive to diagnose spirocercosis. Ten coproscopic examinations were performed on faeces collected from 33 dogs confirmed endoscopically to have spirocercosis. The tests included a direct faecal examination, a faecal sedimentation/flotation test, 4 direct faecal flotations and 4 modified faecal centrifugal flotations. These latter 2 flotation tests utilised 4 different faecal flotation solutions: NaNO3 (SG 1.22), MgSO4 (SG 1.29), ZnSO4 (SG 1.30) and sugar (SG 1.27). The sensitivity of the tests ranged between 42% and 67%, with the NaNO3 solution showing the highest sensitivity in both the direct and modified-centrifugal flotations. The modified NaNO3 centrifugal method ranked 1st with the highest mean egg count (45.24 +/- 83), and was superior (i.e. higher egg count) and significantly different (P < 0.05) compared with the routine saturated sugar, ZnSO4 and MgSO4 flotation methods. The routine NaNO3 flotation method was also superior and significantly different (P < 0.05) compared with the routine ZnSO4 and MgSO4 flotation methods. Fifteen per cent (n = 5) of dogs had neoplastic oesophageal nodules and a further 18% (n = 6) had both neoplastic and non-neoplastic nodules. S. lupi eggs were demonstrated in 40% of dogs with neoplastic nodules only and 72.9% of the dogs with non-neoplastic nodules. The mean egg count in the non-neoplastic group (61) was statistically greater (P = 0.02) than that of the neoplastic group (1). The results show that faecal examination using a NaNO3 solution is the most sensitive in the diagnosis of spirocercosis. The modified centrifugal flotation faecal method using this solution has the highest egg count. The study also found that dogs with neoplastic nodules shed

  7. Particle-bubble aggregate stability on static bubble generated by single nozzle on flotation process

    NASA Astrophysics Data System (ADS)

    Warjito, Harinaldi, Setyantono, Manus; Siregar, Sahala D.

    2016-06-01

    There are three sub-processes on flotation. These processes are intervening liquid film into critical thickness, rupture of liquid film forming three phase contact line, and expansion three phase contact line forming aggregate stability. Aggregate stability factor contribute to determine flotation efficiency. Aggregate stability has some important factors such as reagent and particle geometry. This research focussed on to understand effect of particle geometry to aggregate stability. Experimental setup consists of 9 x 9 x26 cm flotation column made of glass, bubble generator, particle feeding system, and high speed video camera. Bubble generator made from single nozzle with 0.3 mm diameter attached to programmable syringe pump. Particle feeding system made of pipette. Particle used in this research is taken from open pit Grasberg in Timika, Papua. Particle has sub-angular geometry and its size varies from 38 to 300 µm. Bubble-particle interaction are recorded using high speed video camera. Recordings from high speed video camera analyzed using image processing software. Experiment result shows that aggregate particle-bubble and induction time depends on particle size. Small particle (38-106 µm) has long induction time and able to rupture liquid film and also forming three phase contact line. Big particle (150-300 µm) has short induction time, so it unable to attach with bubble easily. This phenomenon is caused by apparent gravity work on particle-bubble interaction. Apparent gravity worked during particle sliding on bubble surface experience increase and reached its maximum magnitude at bubble equator. After particle passed bubble equator, apparent gravity force experience decrease. In conclusion particle size from 38-300 µm can form stable aggregate if particle attached with bubble in certain condition.

  8. Swimming kinematic and flotation analysis of conscious and sedated dogs using 3 canine flotation devices.

    PubMed

    Corum, China Prentice; Wichtowski, Maja; Hetts, Suzanne; Estep, Dan; Bertone, Joseph J

    2014-12-01

    Canine flotation devices (CFDs) are very popular; however, their efficacy is still under debate. There is no oversight to standardize device testing, certification, or qualification for use. We set out to assess the biomechanical and behavioral effects of 3 CFDs on swim and flotation characteristics of dogs. High-speed video recordings were used to measure behavior, range of motion (ROM), maximum flexion angle, and cycles of motion per minute while swimming and roll, yaw, and fear or panic scoring while floating. Predictably, swimming with no CFD yielded the largest ROM and flexion angles. CFDINF was associated with the least ROM. During flotation, CFDAB and CFDRW caused significant rolling and fear, whereas CFDINF was the most stable. CFDAB was associated with cranial downpitch in 2 dogs. Interpretation of the kinematics for CFDAB and CFDRW suggests that decreased stability in the water leads to a greater forced ROM when the position of the dog was conducive to swimming. When positioning forced the dog into a downward pitch, ROM was decreased because of the increased effort for the dogs to keep their head above water. CFDINF was most stable overall owing to a decreased swim effort, with most dogs showing the lowest fear scores and absolute relaxation. CFDAB and CFDRW caused the dogs significant rolling, fear, and distress, with obvious fighting of sedation. We hope to disseminate these results to dog owners in the hopes of providing a valid assessment of these devices.

  9. Development and demonstration of a static tube flotation system for producing superclean coal: 10th quarterly technical progress report ending March 31, 1988

    SciTech Connect

    Yang, D.C.

    1988-04-14

    Research continued during the quarter to study the two-stage flotation circuit in various configurations at the laboratory scale and to prepare for the pilot plant scale-up tests with large packed columns (2 ft square x 20 ft high). All the research activities were designed to demonstrate the potential application of the static tube flotation technology for economic production of superclean coal (0.4-1.0% ASH) from the domestic sources. Preparatory work for PDU (Process Development Unit) testing has just been completed including the setup of the two columns and the auxiliary equipment. The first of the two bulk coal samples (25 tons of Lower Kittanning seam coal) was crushed to less than one hald inch to be used as the feed to the PDU circuit. A small portion of it representative of the bulk sample was further crushed to pass 28 mesh for testing with the laboratory unit to determine its flotation response. We have found that a stronger frother, such as pine oil, can be used to improve fine coal recovery in the packed column because of its water down-washing capability. This reagent scheme will be adopted in the PDU trial. According to the revised schedule, the project completion date will now move slightly to the end of July 1988. 1 tab.

  10. Effect and mechanism of siderite on reverse flotation of hematite

    NASA Astrophysics Data System (ADS)

    Yin, Wan-zhong; Li, Dong; Luo, Xi-mei; Yao, Jin; Sun, Qian-yu

    2016-04-01

    The effects of siderite on reverse flotation of hematite were investigated using micro flotation, adsorption tests, and Fourier transform infrared spectroscopy. The flotation results show that interactions between siderite and quartz are the main reasons that siderite significantly influences the floatability. The interactions are attributed to dissolved siderite species and fine siderite particles. The interaction due to the dissolved species is, however, dominant. Derjaguin-Landau-Verwey-Overbeek (DLVO) theoretical calculations reveal that adhesion on quartz increases when the siderite particle size decreases and that fine particles partly influence quartz floatability. Chemical solution calculations indicate that the dissolved species of siderite might convert the surface of active quartz to CaCO3 precipitates that can be depressed by starch. The theoretical calculations are in good agreement with the results of adsorption tests and FTIR spectroscopy and explain the reasons why siderite significantly influences reverse flotation of hematite.

  11. FLOTATION ROOM, LOOKING SOUTHWEST, WITH LEAD ROUGHER CELLS AT RIGHT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    FLOTATION ROOM, LOOKING SOUTHWEST, WITH LEAD ROUGHER CELLS AT RIGHT AND LEAD CLEANER CELLS AT LEFT. NOTE SUNNYSIDE GOLD CORP. "SG" LOGO ON ROUGHER CELL LAUNDER. - Shenandoah-Dives Mill, 135 County Road 2, Silverton, San Juan County, CO

  12. Flotation kinetics: Methods for estimating distribution of rate constants

    SciTech Connect

    Chander, S.; Polat, M.

    1995-12-31

    Many models have been suggested in the past to obtain a satisfactory fit to flotation data. Of these, first-order kinetics models with a distribution of flotation rate constants are most common. A serious limitation of these models is that type of the distribution must be pre-supposed. Methods to overcome this limitation are discussed and a procedure is suggested for estimating the actual distribution of flotation rate constants. It is demonstrated that the classical first-order model fits the data well when applied to coal flotation in narrow size-specific gravity intervals. When applied to material which is fractionated on the basis of size alone, the use of three parameter models, which were modified from their two parameter analogs such as rectangular, sinusoidal, and triangular, gave most reliable results.

  13. Colloidal titanium dioxide separation from water by foam flotation

    SciTech Connect

    Shen, Y.H.

    1998-12-01

    Colloidal titanium dioxide (TiO{sub 2}) was separated from an aqueous suspension (1,000 ppm) by foam flotation using cationic or anionic surfactants. The effects of surfactant dosage, suspension pH value, suspension ionic strength, and gas flow rate on the dispersed-air flotation of colloidal TiO{sub 2} were investigated. TiO{sub 2} separation was almost complete in optimum conditions. It was found that the coulombic interaction between charged TiO{sub 2} particle surfaces and ionic collectors plays a dominant role in this system. Both flotation rate and foamate volume are dependent upon the gas flow rate. Foam flotation may find application in the separation of submicron TiO{sub 2} particles in suspend-photocatalyst systems.

  14. Harvesting of Scenedesmus obliquus FSP-3 using dispersed ozone flotation.

    PubMed

    Cheng, Ya-Ling; Juang, Yu-Chuan; Liao, Guan-Yu; Tsai, Pei-Wen; Ho, Shih-Hsin; Yeh, Kuei-Ling; Chen, Chun-Yen; Chang, Jo-Shu; Liu, Jhy-Chern; Chen, Wen-Ming; Lee, Duu-Jong

    2011-01-01

    The Scenedesmus obliquus FSP-3, a species with excellent potential for CO(2) capture and lipid production, was harvested using dispersed ozone flotation. While air aeration does not, ozone produces effective solid-liquid separation through flotation. Ozone dose applied for sufficient algal flotation is similar to those used in practical drinking waterworks. The algae removal rate, surface charge, and hydrophobicity of algal cells, and fluorescence characteristics and proteins and polysaccharides contents of algogenic organic matter (AOM) were determined during ozonation. Proteins released from tightly bound AOM are essential to modifying the hydrophobicity of bubble surfaces for easy cell attachment and to forming a top froth layer for collecting floating cells. Humic substances in the suspension scavenge dosed ozone that adversely affects ozone flotation efficiency of algal cells.

  15. Zircon-rutile-ilmenite froth flotation process

    SciTech Connect

    Schmidt, R.; Denham, D.L. Jr.

    1992-04-21

    This patent describes a method for separating a mixture of minerals comprising at least zircon, ilmenite and rutile. It comprises adding an acid solution to the mixture to acidify to a pH of between about 2.0 and 6.0; adding starch to the mixture to depress the ilmenite and the rutile; adding a source of fluoride ions to the mixture to provide a negative surface charge on the zircon surface to activate the zircon; adding an amine cationic collector to the mixture to float the activated zircon; subjecting the mixture containing the added acid solution, the fluoride ions, the starch and the cationic collector, to froth flotation; and withdrawing a float product comprising the zircon and a sink product comprising the ilmenite and rutile.

  16. Investigation of foam flotation and phase partitioning techniques

    NASA Technical Reports Server (NTRS)

    Currin, B. L.

    1985-01-01

    The present status of foam flotation as a separation process is evaluated and limitations for cells and proteins are determined. Possible applications of foam flotation to separations in microgravity are discussed. Application of the fluid mechanical aspects of foam separation techniques is made to phase partitioning in order to investigate the viscous drag forces that may effect the partitioning of cells in a two phase poly(ethylene glycol) and dextran system.

  17. Remediation of metal-contaminated urban soil using flotation technique.

    PubMed

    Dermont, G; Bergeron, M; Richer-Laflèche, M; Mercier, G

    2010-02-01

    A soil washing process using froth flotation technique was evaluated for the removal of arsenic, cadmium, copper, lead, and zinc from a highly contaminated urban soil (brownfield) after crushing of the particle-size fractions >250microm. The metal contaminants were in particulate forms and distributed in all the particle-size fractions. The particle-by-particle study with SEM-EDS showed that Zn was mainly present as sphalerite (ZnS), whereas Cu and Pb were mainly speciated as various oxide/carbonate compounds. The influence of surfactant collector type (non-ionic and anionic), collector dosage, pulp pH, a chemical activation step (sulfidization), particle size, and process time on metal removal efficiency and flotation selectivity was studied. Satisfactory results in metal recovery (42-52%), flotation selectivity (concentration factor>2.5), and volume reduction (>80%) were obtained with anionic collector (potassium amyl xanthate). The transportation mechanisms involved in the separation process (i.e., the true flotation and the mechanical entrainment) were evaluated by the pulp chemistry, the metal speciation, the metal distribution in the particle-size fractions, and the separation selectivity indices of Zn/Ca and Zn/Fe. The investigations showed that a great proportion of metal-containing particles were recovered in the froth layer by entrainment mechanism rather than by true flotation process. The non-selective entrainment mechanism of the fine particles (<20 microm) caused a flotation selectivity drop, especially with a long flotation time (>5 min) and when a high collector dose is used. The intermediate particle-size fraction (20-125 microm) showed the best flotation selectivity.

  18. A review of zinc oxide mineral beneficiation using flotation method.

    PubMed

    Ejtemaei, Majid; Gharabaghi, Mahdi; Irannajad, Mehdi

    2014-04-01

    In recent years, extraction of zinc from low-grade mining tailings of oxidized zinc has been a matter of discussion. This is a material which can be processed by flotation and acid-leaching methods. Owing to the similarities in the physicochemical and surface chemistry of the constituent minerals, separation of zinc oxide minerals from their gangues by flotation is an extremely complex process. It appears that selective leaching is a promising method for the beneficiation of this type of ore. However, with the high consumption of leaching acid, the treatment of low-grade oxidized zinc ores by hydrometallurgical methods is expensive and complex. Hence, it is best to pre-concentrate low-grade oxidized zinc by flotation and then to employ hydrometallurgical methods. This paper presents a critical review on the zinc oxide mineral flotation technique. In this paper, the various flotation methods of zinc oxide minerals which have been proposed in the literature have been detailed with the aim of identifying the important factors involved in the flotation process. The various aspects of recovery of zinc from these minerals are also dealt with here. The literature indicates that the collector type, sulfidizing agent, pH regulator, depressants and dispersants types, temperature, solid pulp concentration, and desliming are important parameters in the process. The range and optimum values of these parameters, as also the adsorption mechanism, together with the resultant flotation of the zinc oxide minerals reported in the literature are summarized and highlighted in the paper. This review presents a comprehensive scientific guide to the effectiveness of flotation strategy.

  19. Application of electrochemical investigation methods in high sulfur coal flotation

    SciTech Connect

    Zhu Hong; Ou Zeshen; Shi Xiuping; Shen Yanchun

    1997-12-31

    More and more attention has been paid to sulfur dioxide pollution caused by coal burning. It is important that sulfur in coal should be reduced before combustion. Flotation is an important method for the removal of pyrite from high sulfur coal. Many chemicals have been tested as a pyrite depressant. In recent years many tests have been done in the laboratory on the flotation behavior of pyrite, and the results have confirmed that the hydrophobicity of the pyrite surface is dependent on the redox potential of the pulp. The mechanism and the reaction products on the pyrite surface are discussed under various conditions. And pyrite depression in coal flotation by electrochemical control are further studied on the basis of what has been achieved. There are two methods in electrochemical control: chemical reagent and control potential by electrochemical instrument (``control potential`` for short). This paper studies pyrite depression in coal flotation by electrochemical control. The influence of sulfur removal in coal flotation has been probed by chemical reagent and control potential. Experiment shows that at low pulp potential the pyrite flotation is generally suppressed. This is new, efficient and simple method of pyrite depression without environmental pollution. The following main conclusions can be drawn from this study: (1) The control of pulp potential can regulate and lead to electrochemical reaction of the hydrophobicity or hydrophilicity on the pyrite surface; and (2) The characteristics of electrochemical methods are normal atmospheric temperature, simple technological process and strong selection.

  20. Boiling treatment of ABS and PS plastics for flotation separation.

    PubMed

    Wang, Chong-qing; Wang, Hui; Wu, Bao-xin; Liu, Qun

    2014-07-01

    A new physical method, namely boiling treatment, was developed to aid flotation separation of acrylonitrile-butadiene-styrene (ABS) and polystyrene (PS) plastics. Boiling treatment was shown to be effective in producing a hydrophilic surface on ABS plastic. Fourier Transform Infrared analysis was conducted to investigate the mechanism of boiling treatment of ABS. Surface rearrangement of polymer may be responsible for surface change of boiling treated ABS, and the selective influence of boiling treatment on the floatability of boiling treated plastics may be attributed to the difference in the molecular mobility of polymer chains. The effects of flotation time, frother concentration and particle size on flotation behavior of simple plastic were investigated. Based on flotation behavior of simple plastic, flotation separation of boiling treatment ABS and PS with different particle sizes was achieved efficiently. The purity of ABS and PS was up to 99.78% and 95.80%, respectively; the recovery of ABS and PS was up to 95.81% and 99.82%, respectively. Boiling treatment promotes the industrial application of plastics flotation and facilitates plastic recycling.

  1. Selective flotation of fossil resins from Northeast China coal

    SciTech Connect

    Hua, X.; Bo, H.; Qing, X.; Lijian, L.; Rong-Zeng, Z.

    1999-07-01

    For a feed which came from Northeast China containing 11.4 per cent fossil resin, by conventional single stage flotation, the fossil resin concentrate gained had a low grade. Adjusting the pH of the feed slurry with HCl or CaO before flotation or treating the feed with H{sub 2}O{sub 2} solution before flotation did not improve the selectivity of flotation. In order to improve the selectivity of flotation for fossil resin, the authors treated the feed slurry of flotation with several surfactants. Although most of them did not work very well, one surfactant was able to increase the grade of concentrate to over 80% as the recovery rate was higher than 82%. The result of mechanism research into the performance of the best surfactant indicated that the selective adsorption of the hydrophobic side of the surfactant onto the surface of coal particle made it more hydrophilic, so that the difference between the hydrophobicity of the coal particle's surface and that of the fossil resin's surface was enlarged.

  2. Interfacial interactions between plastic particles in plastics flotation.

    PubMed

    Wang, Chong-qing; Wang, Hui; Gu, Guo-hua; Fu, Jian-gang; Lin, Qing-quan; Liu, You-nian

    2015-12-01

    Plastics flotation used for recycling of plastic wastes receives increasing attention for its industrial application. In order to study the mechanism of plastics flotation, the interfacial interactions between plastic particles in flotation system were investigated through calculation of Lifshitz-van der Waals (LW) function, Lewis acid-base (AB) Gibbs function, and the extended Derjaguin-Landau-Verwey-Overbeek potential energy profiles. The results showed that van der Waals force between plastic particles is attraction force in flotation system. The large hydrophobic attraction, caused by the AB Gibbs function, is the dominant interparticle force. Wetting agents present significant effects on the interfacial interactions between plastic particles. It is found that adsorption of wetting agents promotes dispersion of plastic particles and decreases the floatability. Pneumatic flotation may improve the recovery and purity of separated plastics through selective adsorption of wetting agents on plastic surface. The relationships between hydrophobic attraction and surface properties were also examined. It is revealed that there exists a three-order polynomial relationship between the AB Gibbs function and Lewis base component. Our finding provides some insights into mechanism of plastics flotation.

  3. Modelling Of Flotation Processes By Classical Mathematical Methods - A Review

    NASA Astrophysics Data System (ADS)

    Jovanović, Ivana; Miljanović, Igor

    2015-12-01

    Flotation process modelling is not a simple task, mostly because of the process complexity, i.e. the presence of a large number of variables that (to a lesser or a greater extent) affect the final outcome of the mineral particles separation based on the differences in their surface properties. The attempts toward the development of the quantitative predictive model that would fully describe the operation of an industrial flotation plant started in the middle of past century and it lasts to this day. This paper gives a review of published research activities directed toward the development of flotation models based on the classical mathematical rules. The description and systematization of classical flotation models were performed according to the available references, with emphasize exclusively given to the flotation process modelling, regardless of the model application in a certain control system. In accordance with the contemporary considerations, models were classified as the empirical, probabilistic, kinetic and population balance types. Each model type is presented through the aspects of flotation modelling at the macro and micro process levels.

  4. Removal of Wax and Stickies from OCC by Flotation

    SciTech Connect

    M. R. Doshi; J. Dyer

    2000-01-31

    Laboratory research indicates that wax is amenable to removal by froth flotation provided it is free or detached from the fiber. The only effective means, at this time, of maximizing detachment of wax is through the use of low consistency pulping at temperatures above the melting point of wax. Wax removal from WCC through washing, flotation, or a combination of both was approximately 90% in these laboratory studies, indicating that not all of the wax is detached from fibers. These results were summarized in Annual Report 1, December 1, 1997 to November 30, 1998. Pilot trials were conducted in which the authors simulated a conventional OCC repulping process with and without flotation. Additional aggressive washing and water clarification were also examined during the study. The inclusion of flotation in the OCC stock preparation system significantly improved the removal of wax spots and extractable material from the furnish. Based on this study, the authors predict that a compact flotation system with 2 lb surfactant/ton of fiber would improve the OCC pulp quality with regard to wax spots by 60% and would not negatively affect strength properties. Flotation losses would be in the 2-5% range. Two mill trials were conducted during the last quarter of the project. One trial was carried out at Green Bay Packaging, Green Bay, WI, and a second trial was conducted at Menasha Corporation, Otsego, MI. A 250-liter Voith Sulzer Ecocell was used to evaluate the removal of wax and stickies from the OCC processing systems at these two mills. The inclusion of flotation in the OCC stock preparation system significantly improved the removal of wax spots from the furnish. The data indicate that flotation was more effective in removing wax and stickies than reverse cleaners. The mill trials have demonstrated that flotation can be substituted for or replace existing reverse cleaning systems and, in some cases, can replace dispersion systems. In this manner, the use of flotation can

  5. The effect of asphaltene particle size and distribution on the temporal advancement of the asphaltene deposition profile in the well column

    NASA Astrophysics Data System (ADS)

    Zeinali Hasanvand, Mahdi; Mosayebi Behbahani, Reza; Feyzi, Farzaneh; Ali Mousavi Dehghani, Seyed

    2016-05-01

    Asphaltene deposition in oil wells is an inconvenient production problem. Generating a precise deposition model for the well column is essential for optimal well design and prevention/reduction of deposition-associated difficulties. The goal of this study is to determine the effects of various parameters on the deposition process. These parameters include oil viscosity, temperature, flow velocity, well diameter and asphaltene particle size and particle size distribution. The first five parameters are analyzed using Escobedo and Mansoori (2010), Cleaver and Yates (1975) and Friedlander and Johnstone (1957) asphaltene deposition models. The last parameter (asphaltene particle size distribution) is not directly included in the asphaltene deposition models. Therefore, a dynamic well column model is generated by combining transport phenomena (mass, heat and momentum transfer) equations with thermodynamic models. The model is fine-tuned and verified based on field data from an Iranian producing oil well with frequent asphaltene deposition problem and subsequently used for predicting the time-dependent development of the asphaltene deposition profile in the well column for a series of asphaltene particle size distributions. The results show the effect of the said parameters depends on how the buffer layer and Brownian motion are defined. The Escobedo and Mansoori (2010) model is found to make better predictions of deposited asphaltene in the studied well.

  6. Some physicochemical aspects of water-soluble mineral flotation.

    PubMed

    Wu, Zhijian; Wang, Xuming; Liu, Haining; Zhang, Huifang; Miller, Jan D

    2016-09-01

    Some physicochemical aspects of water-soluble mineral flotation including hydration phenomena, associations and interactions between collectors, air bubbles, and water-soluble mineral particles are presented. Flotation carried out in saturated salt solutions, and a wide range of collector concentrations for effective flotation of different salts are two basic aspects of water-soluble mineral flotation. Hydration of salt ions, mineral particle surfaces, collector molecules or ions, and collector aggregates play an important role in water-soluble mineral flotation. The adsorption of collectors onto bubble surfaces is suggested to be the precondition for the association of mineral particles with bubbles. The association of collectors with water-soluble minerals is a complicated process, which may include the adsorption of collector molecules or ions onto such surfaces, and/or the attachment of collector precipitates or crystals onto the mineral surfaces. The interactions between the collectors and the minerals include electrostatic and hydrophobic interactions, hydrogen bonding, and specific interactions, with electrostatic and hydrophobic interactions being the common mechanisms. For the association of ionic collectors with minerals with an opposite charge, electrostatic and hydrophobic interactions could have a synergistic effect, with the hydrophobic interactions between the hydrophobic groups of the previously associated collectors and the hydrophobic groups of oncoming collectors being an important attractive force. Association between solid particles and air bubbles is the key to froth flotation, which is affected by hydrophobicity of the mineral particle surfaces, surface charges of mineral particles and bubbles, mineral particle size and shape, temperature, bubble size, etc. The use of a collector together with a frother and the use of mixed surfactants as collectors are suggested to improve flotation.

  7. Role of the collecting agent sorption forms in the elementary act of flotation

    SciTech Connect

    Abramov, A.A.

    2005-02-01

    A new hypothesis of flotation is substantiated based on the well-known hypotheses, theoretical analysis of the elementary act, and experimental results. The hypothesis presented allows the processes of flotation activation, depression, and intensification to be explained and optimized.

  8. High intensity conditioning to improve flotation of gold fine particles

    SciTech Connect

    Valderrama, L.; Perez, C.; Rubio, J.

    1995-12-31

    This work describes the effect of the degree of energy transferred to the pulp, during the conditioning stage, on gold flotation fines recovery, grade and kinetics, with three types of frother (Dowfroth 250, pine oil and MIBC) and amyl xanthate as collector. Best results show an increase in 24% recovery and 50% in concentrate grade, depending on the intensity of conditioning and type of frother (better with Dowfroth 250). For low or intermediate energies (0.5--1.5 kWh/m3 pulp), the fine particles adhere to larger ones, increasing the recovery due to a mixture of carrier (pyrite, in this case) and autogeneous carrier flotation and at higher shear (2--3 kWh/m3 pulp), gold fine particles aggregate themselves. These phenomena are demonstrated by measurements of flotation rate, true flotation (flotation by actual particle-bubble adhesion), and by the amount of entrained particles. Alternatives for this type of pulp conditioning and mechanisms involved are discussed.

  9. 46 CFR 180.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Personal flotation devices carried in addition to life... Jackets § 180.72 Personal flotation devices carried in addition to life jackets. (a) Equipment carried... flotation devices (PFD) approved in accordance with § 160.077 of this chapter, or other standard...

  10. 46 CFR 28.110 - Life preservers or other personal flotation devices.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 1 2013-10-01 2013-10-01 false Life preservers or other personal flotation devices. 28... other personal flotation devices. (a) Except as provided by § 28.305 of this chapter, each vessel must be equipped with at least one immersion suit, exposure suit, or wearable personal flotation device...

  11. 46 CFR 180.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Personal flotation devices carried in addition to life... Jackets § 180.72 Personal flotation devices carried in addition to life jackets. (a) Equipment carried... flotation devices (PFD) approved in accordance with § 160.077 of this chapter, or other standard...

  12. 33 CFR 183.335 - Level flotation test without weights for persons capacity.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Level flotation test without..., DEPARTMENT OF HOMELAND SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of 2 Horsepower or Less Tests § 183.335 Level flotation...

  13. 46 CFR 169.741 - Personal flotation devices and ring life buoys.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 7 2011-10-01 2011-10-01 false Personal flotation devices and ring life buoys. 169.741... SCHOOL VESSELS Vessel Control, Miscellaneous Systems, and Equipment Markings § 169.741 Personal flotation devices and ring life buoys. Each personal flotation device and ring life buoy must be marked with...

  14. 33 CFR 175.25 - Enforcement of State requirements for children to wear personal flotation devices.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Enforcement of State requirements for children to wear personal flotation devices. 175.25 Section 175.25 Navigation and Navigable Waters... Flotation Devices § 175.25 Enforcement of State requirements for children to wear personal flotation...

  15. 33 CFR 175.25 - Enforcement of State requirements for children to wear personal flotation devices.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Enforcement of State requirements for children to wear personal flotation devices. 175.25 Section 175.25 Navigation and Navigable Waters... Flotation Devices § 175.25 Enforcement of State requirements for children to wear personal flotation...

  16. 46 CFR 28.110 - Life preservers or other personal flotation devices.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 1 2014-10-01 2014-10-01 false Life preservers or other personal flotation devices. 28... other personal flotation devices. (a) Except as provided by § 28.305 of this chapter, each vessel must be equipped with at least one immersion suit, exposure suit, or wearable personal flotation device...

  17. 46 CFR 117.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Personal flotation devices carried in addition to life... PASSENGERS LIFESAVING EQUIPMENT AND ARRANGEMENTS Ring Life Buoys and Life Jackets § 117.72 Personal flotation... persons working near or over the water. (d) Commercial hybrid personal flotation devices (PFD) approved...

  18. 33 CFR 175.25 - Enforcement of State requirements for children to wear personal flotation devices.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Enforcement of State requirements for children to wear personal flotation devices. 175.25 Section 175.25 Navigation and Navigable Waters... Flotation Devices § 175.25 Enforcement of State requirements for children to wear personal flotation...

  19. 46 CFR 180.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Personal flotation devices carried in addition to life... Jackets § 180.72 Personal flotation devices carried in addition to life jackets. (a) Equipment carried... flotation devices (PFD) approved in accordance with § 160.077 of this chapter, or other standard...

  20. 46 CFR 169.741 - Personal flotation devices and ring life buoys.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Personal flotation devices and ring life buoys. 169.741... SCHOOL VESSELS Vessel Control, Miscellaneous Systems, and Equipment Markings § 169.741 Personal flotation devices and ring life buoys. Each personal flotation device and ring life buoy must be marked with...

  1. 33 CFR 175.25 - Enforcement of State requirements for children to wear personal flotation devices.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Enforcement of State requirements for children to wear personal flotation devices. 175.25 Section 175.25 Navigation and Navigable Waters... Flotation Devices § 175.25 Enforcement of State requirements for children to wear personal flotation...

  2. Where we are in flotation chemistry after 70 years of research

    SciTech Connect

    Fuerstenau, D.W.

    1995-12-31

    The success of industrial flotation separations has been the design of specific chemical schemes for regulating the bulk and the surface chemistry of the system. Highlights of fundamental research on the nature of flotation reagents and their mode of action in flotation, which has been carried on for about the past 65 years, is briefly reviewed.

  3. 46 CFR 169.741 - Personal flotation devices and ring life buoys.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 7 2012-10-01 2012-10-01 false Personal flotation devices and ring life buoys. 169.741... SCHOOL VESSELS Vessel Control, Miscellaneous Systems, and Equipment Markings § 169.741 Personal flotation devices and ring life buoys. Each personal flotation device and ring life buoy must be marked with...

  4. 46 CFR 180.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Personal flotation devices carried in addition to life... Jackets § 180.72 Personal flotation devices carried in addition to life jackets. (a) Equipment carried... flotation devices (PFD) approved in accordance with § 160.077 of this chapter, or other standard...

  5. 18 CFR 1304.400 - Flotation devices and material, all floating structures.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., shall be of materials commercially manufactured for marine use. Flotation materials shall be fabricated... materials shall be resistant to puncture, penetration, damage by animals, and fire. Any flotation within 40... manufactured flotation device or material specifically designed for marine applications (for example,...

  6. 18 CFR 1304.400 - Flotation devices and material, all floating structures.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ..., shall be of materials commercially manufactured for marine use. Flotation materials shall be fabricated... materials shall be resistant to puncture, penetration, damage by animals, and fire. Any flotation within 40... manufactured flotation device or material specifically designed for marine applications (for example,...

  7. 33 CFR 149.331 - What are the requirements for hybrid personal flotation devices?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... hybrid personal flotation devices? 149.331 Section 149.331 Navigation and Navigable Waters COAST GUARD... hybrid personal flotation devices? (a) The operator must ensure that the use and stowage of all commercial hybrid personal flotation devices (PFDs) used as work vests comply with the procedures...

  8. 33 CFR 149.331 - What are the requirements for hybrid personal flotation devices?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... hybrid personal flotation devices? 149.331 Section 149.331 Navigation and Navigable Waters COAST GUARD... hybrid personal flotation devices? (a) The operator must ensure that the use and stowage of all commercial hybrid personal flotation devices (PFDs) used as work vests comply with the procedures...

  9. 33 CFR 149.331 - What are the requirements for hybrid personal flotation devices?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... hybrid personal flotation devices? 149.331 Section 149.331 Navigation and Navigable Waters COAST GUARD... hybrid personal flotation devices? (a) The operator must ensure that the use and stowage of all commercial hybrid personal flotation devices (PFDs) used as work vests comply with the procedures...

  10. 33 CFR 149.331 - What are the requirements for hybrid personal flotation devices?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... hybrid personal flotation devices? 149.331 Section 149.331 Navigation and Navigable Waters COAST GUARD... hybrid personal flotation devices? (a) The operator must ensure that the use and stowage of all commercial hybrid personal flotation devices (PFDs) used as work vests comply with the procedures...

  11. 46 CFR 180.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Personal flotation devices carried in addition to life... Jackets § 180.72 Personal flotation devices carried in addition to life jackets. (a) Equipment carried... flotation devices (PFD) approved in accordance with § 160.077 of this chapter, or other standard...

  12. 46 CFR 169.741 - Personal flotation devices and ring life buoys.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Personal flotation devices and ring life buoys. 169.741... SCHOOL VESSELS Vessel Control, Miscellaneous Systems, and Equipment Markings § 169.741 Personal flotation devices and ring life buoys. Each personal flotation device and ring life buoy must be marked with...

  13. 33 CFR 175.25 - Enforcement of State requirements for children to wear personal flotation devices.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Enforcement of State requirements for children to wear personal flotation devices. 175.25 Section 175.25 Navigation and Navigable Waters... Flotation Devices § 175.25 Enforcement of State requirements for children to wear personal flotation...

  14. 33 CFR 149.331 - What are the requirements for hybrid personal flotation devices?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... hybrid personal flotation devices? 149.331 Section 149.331 Navigation and Navigable Waters COAST GUARD... hybrid personal flotation devices? (a) The operator must ensure that the use and stowage of all commercial hybrid personal flotation devices (PFDs) used as work vests comply with the procedures...

  15. 46 CFR 117.72 - Personal flotation devices carried in addition to life jackets.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Personal flotation devices carried in addition to life... PASSENGERS LIFESAVING EQUIPMENT AND ARRANGEMENTS Ring Life Buoys and Life Jackets § 117.72 Personal flotation... persons working near or over the water. (d) Commercial hybrid personal flotation devices (PFD) approved...

  16. FRACTIONATING COLUMN PRODUCT COLLECTOR CONTROL

    DOEpatents

    Paxson, G.D. Jr.

    1964-03-10

    Means for detecting minute fluid products from a chemical separation column and for advancing a collector tube rack in order to automatically separate and collect successive fractionated products are described. A charge is imposed on the forming drops at the column orifice to create an electric field as the drop falls in the vicinity of a sensing plate. The field is detected by an electrometer tube coupled to the plate causing an output signal to actuate rotation of a collector turntable rack, thereby positioning new collectors under the orifice. The invention provides reliable automatic collection independent of drop size, rate of fall, or chemical composition. (AEC)

  17. Selective flotation of PVC using gelatin and lignin alkali.

    PubMed

    Yenial, Unzile; Kangal, Olgaç; Güney, Ali

    2013-06-01

    Recycling has become one of the most important issues as a result of increasing waste mass in present day. This is especially important for polymer wastes as they are hard to degenerate in nature. Today, most of the practical methods used for the recycling of waste mass, such as hand sorting, gravity separation, etc., cannot be performed successfully owing to close densities of polymers. Froth flotation can be used successfully and economically for this purpose. The main objective of this study was to investigate the effect of plasticizer reagents and the success of froth flotation at plastic recycling. In this study, lignin alkali and gelatin were used as plasticizer reagents. The effect of these reagents was searched with the parameters of pH, concentration, conditioning and flotation time. In the case of post-consumed polyethylene terephthalate and polyvinyl chloride (PVC), 98.9% purity of PVC was obtained at optimum conditions.

  18. Selective flotation of fossil resin from western coal

    SciTech Connect

    Jensen, G.F.; Miller, J.D.

    1992-03-30

    Economic analysis of this fossil resin project mainly focused on the flotation plant which is intended to be designed with data obtained from the current proof-of-concept flotation test program. It is believed that the analysis of this step is fairly accurate. The other two economic aspects of fossil in resin recovery/utilization are refining and marketing. Cost data used for refining were from an estimated base and are believed to have a large variance. Marketing data used were obtained from two independent marketing studies which were made available on confidentiality basis. Nevertheless, the data used are believed to be fairly accurate with respect to the market potential.

  19. Chemical and colloidal aspects of collectorless flotation behavior of sulfide and non-sulfide minerals.

    PubMed

    Aghazadeh, Sajjad; Mousavinezhad, Seyed Kamal; Gharabaghi, Mahdi

    2015-11-01

    Flotation has been widely used for separation of valuable minerals from gangues based on their surface characterizations and differences in hydrophobicity on mineral surfaces. As hydrophobicity of minerals widely differs from each other, their separation by flotation will become easier. Collectors are chemical materials which are supposed to make selectively valuable minerals hydrophobic. In addition, there are some minerals which based on their surface and structural features are intrinsically hydrophobic. However, their hydrophobicities are not strong enough to be floatable in the flotation cell without collectors such as sulfide minerals, coal, stibnite, and so forth. To float these minerals in a flotation cell, their hydrophobicity should be increased in specific conditions. Various parameters including pH, Eh, size distribution, mill types, mineral types, ore characterization, and type of reaction in flotation cells affect the hydrophobicity of minerals. Surface analysis results show that when sulfide minerals experience specific flotation conditions, the reactions on the surface of these minerals increase the amount of sulfur on the surface. These phenomenons improve the hydrophobicity of these minerals due to strong hydrophobic feature of sulfurs. Collectorless flotation reduces chemical material consumption amount, increases flotation selectivity (grade increases), and affects the equipment quantities; however, it can also have negative effects. Some minerals with poor surface floatability can be increased by adding some ions to the flotation system. Depressing undesirable minerals in flotation is another application of collectorless flotation.

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 9, October 1, 1994--December 31, 1994

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-01-25

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 9 (October--December, 1995), parametric and optimization testing was completed for the Taggart, Sunnyside, and Indiana VII coal using a 12-inch Microcel{trademark} flotation column. The detailed design of the 2-t/hr PDU grinding, flotation, and dewatering circuits neared completion with the specification of the major pieces of capital equipment to be purchased for these areas. Selective agglomeration test work investigated the properties of various industrial grades of heptane for use during bench- and PDU-scale testing. It was decided to use a hydrotreated grade of commercial heptane due to its low cost and low concentration of aromatic compounds. The final Subtask 6.4 CWF Formulation Studies Test Plan was issued. A draft version of the Subtask 6.5 Preliminary Design and Test Plan Report was also issued, discussing the progress made in the design of the bench-scale selective agglomeration unit. PDU construction work moved forward through the issuing of 26 request for quotations and 21 award packages for capital equipment.

  1. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 6, January--March 1994

    SciTech Connect

    Smit, F.J.; Rowe, R.M.; Anast, K.R.; Jha, M.C.

    1994-05-06

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effectve replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States as well as for advanced combustars currently under development. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals fbr clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 51-month program which started on September 30, 1992. This report discusses the technical progress, made during the 6th quarter of the project from January 1 to March 31, 1994. The project has three major objectives: (1) The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. (3) A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  2. 21 CFR 880.5150 - Nonpowered flotation therapy mattress.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Nonpowered flotation therapy mattress. 880.5150 Section 880.5150 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... materials that have the functionally equivalent effect of supporting a patient and avoiding excess...

  3. 21 CFR 880.5150 - Nonpowered flotation therapy mattress.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Nonpowered flotation therapy mattress. 880.5150 Section 880.5150 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... materials that have the functionally equivalent effect of supporting a patient and avoiding excess...

  4. Flotation of fine coal with different volatility in China

    SciTech Connect

    Guo, M.X.; Hui, W.D.; An, Z.; Ren, Z.M.; Wang, Q.F.; Dai, Z.; Xiao, Z.Q.; Cui, Y.B.; Zhang, X.J.

    1997-12-31

    This paper contains three parts. The first part interprets the surface hydrophobicity and theoretical floatability of different rank coals from the organic molecular component point of view. The theoretical floatability between bituminous and anthracite is solved by the molecular theory. The second part describes a study of the interactive energy between hydrocarbon oil and coal particle using DLVO theory showing that the controlling factor in determining the repulsive energy barrier preventing oil from wetting and spreading on the coal surface is the same sign charge and Zeta potential. Some surfactants to promote the interaction of hydrocarbon oil and coal surface were investigated. The batch tests show a new flotation promoter having a higher efficiency and performance. A discussion is centered on the relationship between the floatabilities of coals with different volatile matter and the character of the new reagent. A molecular theory for the explanation of the interaction mechanism of the flotation reagent on coal surface was summarized. A survey of four coal preparation plants (Xiqu, Malan, Taiyuan and Tianzhuang) in Shanxi and Henan provinces was introduced. The flotation performance of coal with different volatility using commercial flotation cells in the above mentioned plants was tested.

  5. 21 CFR 890.5170 - Powered flotation therapy bed.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Powered flotation therapy bed. 890.5170 Section 890.5170 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Therapeutic Devices §...

  6. 21 CFR 890.5170 - Powered flotation therapy bed.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Powered flotation therapy bed. 890.5170 Section 890.5170 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Therapeutic Devices §...

  7. 21 CFR 890.5170 - Powered flotation therapy bed.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Powered flotation therapy bed. 890.5170 Section 890.5170 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Therapeutic Devices §...

  8. 33 CFR 183.325 - Flotation test for persons capacity.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Boats Rated for Engines of 2 Horsepower or Less Tests § 183.325 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  9. 33 CFR 183.225 - Flotation test for persons capacity.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Boats Rated for Engines of More Than 2 Horsepower Tests § 183.225 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  10. 21 CFR 890.5170 - Powered flotation therapy bed.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Powered flotation therapy bed. 890.5170 Section 890.5170 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Therapeutic Devices §...

  11. 21 CFR 890.5170 - Powered flotation therapy bed.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Powered flotation therapy bed. 890.5170 Section 890.5170 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES PHYSICAL MEDICINE DEVICES Physical Medicine Therapeutic Devices §...

  12. Micro-agglomerate flotation for deep cleaning of coal

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-04-01

    We are investigating the use of a hybrid process, Micro-agglomerate flotation, which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 [mu]m in size) rather than individual coal particles (1--10 [mu]m) the problems of froth overload and water/mineral carryover should be significantly alleviated.Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  13. Micro-agglomerate flotation for deep cleaning of coal

    SciTech Connect

    Chander, S.; Hogg, R.

    1993-01-01

    We are investigating the use of a hybrid process - Micro-agglomerate flotation - which is a combination of oil-agglomeration and froth flotation. The basic concept is to use small quantities of oil to promote the formation of dense micro-agglomerates with minimal entrapment of water and mineral particles, and to use froth flotation to extract these micro-agglomerates from the water/dispersed-mineral phase. Since the floating units are agglomerates (about 30--50 [mu]m in size) rather than individual coal particles (1--10 [mu]m) the problems of froth overload and water/mineral carryover should be significantly alleviated. Micro-agglomerate flotation has considerable potential for the practical deep cleaning of coal on a commercial scale. In principle, it should be possible to achieve both high selectivity and high yield at reasonable cost. The process requires only conventional, off-the-shelf equipment and reagent usage (oil, surfactants, etc.) should be small. There are, however, complications. The process involves at least five phases: two or more solids (coal and mineral), two liquids (oil and water) and one gas (air). It is necessary to maintain precise control over the chemistry of the liquid phases in order to promote the interfacial reactions and interactions between phases necessary to ensure selectivity. Kinetics as well as thermodynamic factors may be critical in determining overall system response.

  14. Surface chemistry control for selective fossil resin flotation

    DOEpatents

    Miller, J.D.; Yi, Y.; Yu, Q.

    1994-06-07

    A froth flotation method is disclosed for separating fine particles of fossil resin by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method. 12 figs.

  15. Surface chemistry control for selective fossil resin flotation

    DOEpatents

    Miller, Jan D.; Yi, Ye; Yu, Qiang

    1994-01-01

    A froth flotation method is disclosed for separating fine particles of fossil resin from by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method.

  16. 21 CFR 880.5550 - Alternating pressure air flotation mattress.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Alternating pressure air flotation mattress. 880.5550 Section 880.5550 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES GENERAL HOSPITAL AND PERSONAL USE DEVICES General Hospital...

  17. Zeta potentials in the flotation of oxide and silicate minerals.

    PubMed

    Fuerstenau, D W; Pradip

    2005-06-30

    Adsorption of collectors and modifying reagents in the flotation of oxide and silicate minerals is controlled by the electrical double layer at the mineral-water interface. In systems where the collector is physically adsorbed, flotation with anionic or cationic collectors depends on the mineral surface being charged oppositely. Adjusting the pH of the system can enhance or prevent the flotation of a mineral. Thus, the point of zero charge (PZC) of the mineral is the most important property of a mineral in such systems. The length of the hydrocarbon chain of the collector is important because of chain-chain association enhances the adsorption once the surfactant ions aggregate to form hemimicelles at the surface. Strongly chemisorbing collectors are able to induce flotation even when collector and the mineral surface are charged similarly, but raising the pH sufficiently above the PZC can repel chemisorbing collectors from the mineral surface. Zeta potentials can be used to delineate interfacial phenomena in these various systems.

  18. 33 CFR 142.45 - Personal flotation devices.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Personal flotation devices. 142.45 Section 142.45 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) OUTER CONTINENTAL SHELF ACTIVITIES WORKPLACE SAFETY AND HEALTH Personal Protective...

  19. Frogmen on Apollo command module boilerplate flotation collar during recovery

    NASA Technical Reports Server (NTRS)

    1966-01-01

    Apollo command module boilerplate floats in the Atlantic Ocean during a practice recovery exercise. Frogmen in a liferaft and on the flotation collar secure the command module boilerplate for hoisting onto a nearby recovery ship. The exercise was conducted in preparation for the forthcoming Apollo-Saturn 201 (AS-201) mission.

  20. Navy frogmen attach flotation collar to Apollo 7 command module

    NASA Technical Reports Server (NTRS)

    1968-01-01

    U.S. Navy frogmen attach a flotation collar to the Apollo 7 command module during recovery operations in the Atlantic. The Apollo 7 spacecraft splashed down at 7:11 a.m., October 22, 1968, approximately 200 nautical miles south-southwest of Bermuda.

  1. 33 CFR 183.225 - Flotation test for persons capacity.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Boats Rated for Engines of More Than 2 Horsepower Tests § 183.225 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  2. 33 CFR 183.325 - Flotation test for persons capacity.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Boats Rated for Engines of 2 Horsepower or Less Tests § 183.325 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  3. 33 CFR 183.225 - Flotation test for persons capacity.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Boats Rated for Engines of More Than 2 Horsepower Tests § 183.225 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  4. 33 CFR 183.325 - Flotation test for persons capacity.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Boats Rated for Engines of 2 Horsepower or Less Tests § 183.325 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  5. 33 CFR 183.325 - Flotation test for persons capacity.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Boats Rated for Engines of 2 Horsepower or Less Tests § 183.325 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  6. 33 CFR 183.225 - Flotation test for persons capacity.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Boats Rated for Engines of More Than 2 Horsepower Tests § 183.225 Flotation test for persons capacity... water as follows: (a) The angle of heel does not exceed 10 degrees from the horizontal. (b) Any point on either the forward or aft reference area is above the surface of the water. (c) The reference depth...

  7. Removal of arsenopyrite from complex sulfide minerals by froth flotation

    NASA Astrophysics Data System (ADS)

    Choi, Jin-young; Kim, Yang-soo; Kim, Dong-gyu; Han, Oh-hyung; Park, Chul-hyun

    2016-04-01

    Arsenic (As) is one of hazardous materials and a penalty element in metal concentrates and so metal concentrates containing arsenic of over 0.5% has been currently restricted in import and export trade. It also corrodes a smelting furnace as well as shortens its life cycle. In korea, Janggun mine that produces galena (PbS) /sphalerite (ZnS) concentrate containing arsenic of 1.78% charges a penalty of US 2/ton to LS-Nikko smelter. Hence in this work, flotation tests for removal of arsenopyrite (FeAsS) from sulfide mineral concentrates were carried out using lab scale flotation cell, which maintain grade and recovery of PbS and ZnS in comparison to flotation plant. Particularly, this study was focused on investigating the combination of several chemical reagents (depressant, collector, activator and etc.) that affect flotation performance. In the straight differential flotation for PbS, a PbS grade of 75.80% and a recovery of 90.12% could be obtained with FeAsS removal of 84.1% (0.2% As) under the conditions of 20% feed solids concentration, pH 8.5, 50g/t frother (AF65), 40g/t collector (AP242) and 800g/t As depressant (NaHSO3) and 600g/t Zn depressant (ZnSO4). In the ZnS flotation, the maximum separation achievable for ZnS using froth flotation has been shown to be a grade of 72.57% and a recovery of 95.43%. At this time, FeAsS removal of 87.8% (0.16% As) could be successfully accomplished under pH 11, and 800g/t Zn activator (CuSO4), 75g/t frother (AF65), 60g/t collector (AP211) and 600g/t As depressant (NaHSO3). Acknowledgments This work was supported by the Energy and Resources Engineering Program Grant funded by the Ministry of Trade, Industry and Energy, Korea

  8. Column Liquid Chromatography.

    ERIC Educational Resources Information Center

    Majors, Ronald E.; And Others

    1984-01-01

    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  9. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 3, April--June 1993

    SciTech Connect

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-07-28

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the quarter from April 1 to June 30, 1993. The project has three major objectives: (1) the primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) a secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics; and (3) a third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  10. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect

    B. K. Parekh; D. P. Patil

    2008-04-30

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake

  11. Removal of methylene blue from its aqueous solution by froth flotation: hydrophobic silica nanoparticle as a collector

    NASA Astrophysics Data System (ADS)

    Hu, Nan; Liu, Wei; Ding, Linlin; Wu, Zhaoliang; Yin, Hao; Huang, Di; Li, Hongzhen; Jin, Lixue; Zheng, Huijie

    2017-02-01

    Dye pollution has been a severe problem faced by worldwide environmentalists. The use of nanoparticles as adsorbents has attracted widespread interests for effectively removing dyes, while the separation of them from an aqueous solution is a difficult and important subject. For achieving the simultaneous removal of methylene blue (MB) and nanoadsorbents, this work utilized a commercial hydrophobic silica nanoparticle (SNP) (200.0 ± 10.0 nm in average particle size) as a collector and then developed a novel froth flotation technology without using any surfactants. Under the suitable conditions of anhydrous ethanol dosage of 8 mL, pH of 9.0, SNP concentration of 600 mg/L, and flotation column height of 600 mm, the removal efficiencies of MB and SNPs and the volume ratio reached 91.1 ± 4.6%, 93.9 ± 4.7%, and 10.5 ± 0.5, respectively. Subsequently, the recovered MB-adsorbed SNPs in the foamate were separated by free setting due to their high concentration and massive agglomeration. After free setting, MB could be effectively separated from the recovered MB-adsorbed SNPs by using ethanol at pH 2.0 and repeating five cycles of washing-centrifugation. Additionally, the regenerated SNPs could be reused for removing MB up to five times. Overall, this work had a significant meaning for the treatment of dye-contaminated wastewaters.

  12. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Mohanty, M.K.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a run-of-mine coal sample collected from Amax Coal Company`s Delta Coal mine using column flotation and an enhanced gravity separator as separate units and in circuitry arrangements. The {minus}60 mesh run-of-mine sample having an ash content of about 22% was cleaned to 6% while achieving a very high energy recovery of about 87% and a sulfur rejection value of 53% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Packed-Column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  13. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a PCB feed sample collected from Central Illinois Power`s Newton Power Station using column flotation and an enhanced gravity separator as separate units and in a circuitry arrangement. The PCB feed sample having a low ash content of about 12% was further cleaned to 6% while achieving a very high energy recovery of about 90% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Microcel column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  14. Flotation rate and residence time distribution in continuous coal froth flotation circuits and an evaluation of reagents and circuit variations for pyritic sulfur removal

    SciTech Connect

    Arnold, B.J.

    1989-01-01

    This thesis gives the results of research conducted on several aspects of coal froth flotation. The effect of operating variables on the residence time distribution in coal froth flotation cells is discussed, and a model of the residence time distribution is presented for use with flotation rate models in scaling up from laboratory to plant scale. Flotation rate models are also investigated in detail for continuous coal froth flotation circuits. Changes in operating variables were found to affect the mean residence time in cells, but they did not have much effect on the mixing behavior. The use of a time lag was found to be an important part of rate models for continuous froth flotation cells. An important aspect of the use of such rate and residence time equations is their application to the flotation of gangue constituents, which often enter the froth by water carry-over in addition to natural flotation or flotation as slime coatings. As such, water carry-over is also investigated in this thesis for the laboratory and the plant and for both ash-forming minerals and pyrite. Maintaining a constant froth factor, the percentage of froth above the weir, in both laboratory and plant tests is believed to be a critical factor in predicting plant results using a kinetic factor ratio documented in the literature. Removing the pyrite and ash-forming minerals from coal that may be recovered by the water carry-over or other mechanisms is an important goal in coal froth flotation. This thesis also contains the results of tests with pyrite depressants and circuit variations for removal of pyritic sulfur.

  15. Improved flotation performance of hematite fines using citric acid as a dispersant

    NASA Astrophysics Data System (ADS)

    Luo, Xi-mei; Yin, Wan-zhong; Sun, Chuan-yao; Wang, Nai-ling; Ma, Ying-qiang; Wang, Yun-fan

    2016-10-01

    In this study, citric acid was used as a dispersant to improve the flotation performance of hematite fines. The effect and mechanism of citric acid on the reverse flotation of hematite fines were investigated by flotation tests, sedimentation experiments, scanning electron microscopy (SEM), zeta-potential measurements, and X-ray photoelectron spectroscopy (XPS). The results of SEM analysis and flotation tests reveal that a strong heterocoagulation in the form of slime coating or coagulation in hematite fine slurry affects the beneficiation of hematite ores by froth flotation. The addition of a small amount of citric acid (less than 300 g/t) favorably affects the reverse flotation of hematite fines by improving particle dispersion. The results of sedimentation experiments, zeta-potential measurements, and XPS measurements demonstrate that citric acid adsorbs onto hematite and quartz surfaces via hydrogen bonding, thereby reducing the zeta potentials of mineral surfaces, strengthening the electrical double-layer repulsion between mineral particles, and dispersing the pulp particles.

  16. The influence of reagent dosage on the floatability of pyrite during coal flotation

    SciTech Connect

    Bonner, C.M.; Aplan, F.F.

    1993-01-01

    In general, as the quantity of frother and/or coal collector is increased, so too, does the flotation of the undesired pyrite. The problem is particularly serious with oil reagents. For some coals, however, a collector, such as fuel oil, is required to achieve a high coal recovery. This requires a compromise between the competing desires of a high coal recovery and a high pyrite rejection. This study gives the quantitative effect of reagent dosage on coal and pyrite floatability and details several means of minimizing pyrite floatability during coal flotation. The effect of fuel oil on coal flotation is especially interesting in that the flotation process changes from froth flotation to emulsion or agglomerative flotation as the amount of oil is increased. This phenomenon provides an additional method of rejecting pyritic sulfur.

  17. Flotation separation of coal concentrates. 1976-1981 (citations from the Energy Data Base). Report for Jan 76-Dec 81

    SciTech Connect

    Not Available

    1981-12-01

    Reports are cited which discuss flotation separation of mineral particles using the different surface chemical properties to cause the selected particles to float. Coal-washery flotation circuits are emphasized. Sorting and separating using compressed air jets into the mineral concentration, flotation reagent effects on coal concentrate quality, and economy of flotation separation of coal concentrates are included in this bibliography. Froth flotation, foam separation, and foam flotation processes are included with respect to oil and water mixtures, ore concentrates, and minerals, as well as coal concentrates. (Contains 213 citations fully indexed and including a title list.)

  18. Dorsal column stimulator applications

    PubMed Central

    Yampolsky, Claudio; Hem, Santiago; Bendersky, Damián

    2012-01-01

    Background: Spinal cord stimulation (SCS) has been used to treat neuropathic pain since 1967. Following that, technological progress, among other advances, helped SCS become an effective tool to reduce pain. Methods: This article is a non-systematic review of the mechanism of action, indications, results, programming parameters, complications, and cost-effectiveness of SCS. Results: In spite of the existence of several studies that try to prove the mechanism of action of SCS, it still remains unknown. The mechanism of action of SCS would be based on the antidromic activation of the dorsal column fibers, which activate the inhibitory interneurons within the dorsal horn. At present, the indications of SCS are being revised constantly, while new applications are being proposed and researched worldwide. Failed back surgery syndrome (FBSS) is the most common indication for SCS, whereas, the complex regional pain syndrome (CRPS) is the second one. Also, this technique is useful in patients with refractory angina and critical limb ischemia, in whom surgical or endovascular treatment cannot be performed. Further indications may be phantom limb pain, chronic intractable pain located in the head, face, neck, or upper extremities, spinal lumbar stenosis in patients who are not surgical candidates, and others. Conclusion: Spinal cord stimulation is a useful tool for neuromodulation, if an accurate patient selection is carried out prior, which should include a trial period. Undoubtedly, this proper selection and a better knowledge of its underlying mechanisms of action, will allow this cutting edge technique to be more acceptable among pain physicians. PMID:23230533

  19. On the Methodology of Nematode Extraction from Field Samples: Density Flotation Techniques

    PubMed Central

    Viglierchio, David R.; Yamashita, Tom T.

    1983-01-01

    Density flotation has been frequently used for the extraction of nematodes from field samples. Density flotation curves for four nematode species and five solutes have been prepared. The curves confirm that flotation was governed by several factors: solute density, solute osmotic activity, and physiological properties of the nematode species. Nematode viability and function can be adversely affected by improper selection of solute for density extraction of nematodes; nevertheless, some nematode species can be enriched from mixtures by density and solute selection. PMID:19295831

  20. Microalgae harvesting by flotation using natural saponin and chitosan.

    PubMed

    Kurniawati, H Agnes; Ismadji, Suryadi; Liu, J C

    2014-08-01

    This study aims to investigate the harvesting of microalgae by dispersed air flotation (DiAF) using natural biosurfactant saponin as the collector and chitosan as the flocculant. Two types of microalgae, Chlorella vulgaris and Scenedesmus obliquus, were used in this study. It was observed that saponin was a good frother, but not an effective collector when used alone for flotation separation of algae. However, with the pre-flocculation of 5 mg/L of chitosan, separation efficiency of >93% microalgae cells was found at 20 mg/L of saponin. Removal efficiency of >54.4% and >73.0% was found for polysaccharide and protein, respectively at 20 mg/L of saponin and chitosan each. Experimental results show that DiAF using saponin and chitosan is effective for separation of microalgae, and algogenic organic matter (AOM). It can potentially be applied in the integrated microalgae-based biorefinery.

  1. An investigation of pyrite depression in coal flotation by electrochemical pyrite surface control

    SciTech Connect

    Zhu Hong; Ou Zeshen; Shi Xiuping; Shen Yanchun

    1995-12-31

    This paper introduces a new potential method of pyrite depression in the flotation of high sulfur coal based on the electrochemical pyrite surface control. Experimental date show that the natural hydrophobicity of pyrite depends on the oxidation-reduction potential of the pulp. The mechanism and products of electrochemical reaction on the pyrite surface are also discussed under various conditions. The pyrite flotation is generally suppressed under low pulp potentials. Therefore, the sulfur removal in the flotation of high sulfur coal could be improved by the pulp redox potential control, while the coal flotation is materially not affected.

  2. Using alternative chemicals in the flotation of heavy metals from lead mill tailings

    SciTech Connect

    Benn, F.W.

    1995-04-01

    The U.S. Bureau of Mines (USBM) investigated alternative chemicals for the flotation of heavy metal values from southeast Missouri lead mill tailings. The objectives of the study were to lower the Pb remaining in the reprocessed tailings to <500 ppm, concentrate the metal values, and lower the overall toxicity of the flotation reagent scheme. Due to the high toxicity of classic flotation chemicals, collectorless flotation, as well as nontoxic or less-toxic chemicals, was studied for use in the flotation process. The investigation centered on the National tailings pile in Flat River, MO. Advantages to using alternative chemicals for the flotation process are presented. Novel reagent schemes are discussed for the treatment of the tailings. Various nontoxic or less-toxic oils were tested, and a substitute for sodium sulfide was investigated. Using a food additive oil, soda ash, and a frother as the reagent scheme, froth flotation recovered 89% of the Pb values. Further scavenging lowered the Pb remaining in the reprocessed tailings to <500 ppm. A less-toxic substitute for sodium cyanide was also studied for use in the cleaner flotation stages. Preliminary results indicate that the food additive oil, canola oil, to be as effective as classic sulfide flotation reagents.

  3. Flotation: A promising microalgae harvesting and dewatering technology for biofuels production.

    PubMed

    Ndikubwimana, Theoneste; Chang, Jingyu; Xiao, Zongyuan; Shao, Wenyao; Zeng, Xianhai; Ng, I-Son; Lu, Yinghua

    2016-03-01

    Microalgal biomass as renewable energy source is believed to be of great potential for reliable and sustainable biofuels production. However, microalgal biomass production is pinned by harvesting and dewatering stage thus hindering the developing and growing microalgae biotechnology industries. Flotation technology applied in mineral industry could be potentially applied in microalgae harvesting and dewatering, however substantial knowledge on different flotation units is essential. This paper presents an overview on different flotation units as promising cost-effective technologies for microalgae harvesting thus bestowing for further research in development and commercialization of microalgae based biofuels. Dispersed air flotation was found to be less energy consuming. Moreover, Jameson cell flotation and dispersed ozone flotation are believed to be energy efficient microalgae flotation approaches. Microalgae harvesting and dewatering by flotation is still at embryonic stage, therefore extended studies with the focus on life cycle assessment, sustainability of the flotation unit, optimization of the operating parameters using different algal species is imperative. Though there are a number of challenges in microalgae harvesting and dewatering, with well designed and developed cultivation, harvesting/dewatering, extraction and conversion technologies, progressively, microalgae technology will be of great potential for biological carbon sequestration, biofuels and biochemicals production.

  4. Inelastic column behavior

    NASA Technical Reports Server (NTRS)

    Duberg, John E; Wilder, Thomas W , III

    1952-01-01

    The significant findings of a theoretical study of column behavior in the plastic stress range are presented. When the behavior of a straight column is regarded as the limiting behavior of an imperfect column as the initial imperfection (lack of straightness) approaches zero, the departure from the straight configuration occurs at the tangent-modulus load. Without such a concept of the behavior of a straight column, one is led to the unrealistic conclusion that lateral deflection of the column can begin at any load between the tangent-modulus value and the Euler load, based on the original elastic modulus. A family of curves showing load against lateral deflection is presented for idealized h-section columns of various lengths and of various materials that have a systematic variation of their stress-strain curves.

  5. Personal Flotation Devices Research. Volume 2. Research Report.

    DTIC Science & Technology

    1978-01-01

    statistical techniques , inc l uding factor analysis, canonical correlation analysis , and multiple linear regression were used to develop indices of PFD...of inflatable PFDs subjected to this test plan showed that an Accelerated Testing Technique - is feasible for testing inflatable PFDs , that latent...tool, with related techniques and procedures that organize and summarize accident data so that the role of personal flotation devices in saving lives

  6. SYNTHESIS AND EVALUATION OF NEW AND IMPROVED GYRO FLOTATION FLUIDS.

    DTIC Science & Technology

    on a proprietary fluid. The synthesis of heavy metal alkanethiolates was investigated and two compounds were isolated and characterized. Both are...viscous, high boiling liquids. Methods of preparing fluoroalkanethiols were explored as a means of providing starting materials for the synthesis of heavy metal fluoroalkanethiolates. (Author)...The purpose of this research program is to produce liquids which have densities between 2.5 and 3.0 g./cc. for use as gyro flotation fluids. Heavy

  7. Characterisation of flotation froth colour and structure by machine vision

    NASA Astrophysics Data System (ADS)

    Bonifazi, Giuseppe; Serranti, Silvia; Volpe, Fabio; Zuco, Riccardo

    2001-11-01

    It is well known and well recognised that flotation is a process that is complex to monitor and study if a classical approach based on the evaluation of the signals resulting from sensors is adopted. Sensors are usually strategically positioned in the bank cells and detect global process variables such as pH, reagent addition, froth level, on-stream chemical analysis, particle size distribution, etc. In the last ten years several studies have been carried out with the main goal to utilise imaging techniques to detect froth bubbles characteristics and to evaluate the flotation process performance. In this paper an approach of this type is described. More specifically, image processing techniques to automatically measure the colour and the structure of the froth bubbles are presented and the results are discussed. All the investigations are carried out on digital sample images collected in an industrial flotation plant operating in steady-state conditions. The colour analysis is performed on the whole surface of the froth images considering different colour reference systems (RGB, HSV, HSI); the morphological measurements are obtained after the application of selected enhancement and segmentation techniques, necessary to consider the bubbles as separate domains. The multiple correlation analysis performed between froth mineral concentrations (Cu, MgO, Zn and Pb content) and the extracted colour and structure parameters are good in most situations.

  8. Estimated water requirements for the conventional flotation of copper ores

    USGS Publications Warehouse

    Bleiwas, Donald I.

    2012-01-01

    This report provides a perspective on the amount of water used by a conventional copper flotation plant. Water is required for many activities at a mine-mill site, including ore production and beneficiation, dust and fire suppression, drinking and sanitation, and minesite reclamation. The water required to operate a flotation plant may outweigh all of the other uses of water at a mine site, [however,] and the need to maintain a water balance is critical for the plant to operate efficiently. Process water may be irretrievably lost or not immediately available for reuse in the beneficiation plant because it has been used in the production of backfill slurry from tailings to provide underground mine support; because it has been entrapped in the tailings stored in the TSF, evaporated from the TSF, or leaked from pipes and (or) the TSF; and because it has been retained as moisture in the concentrate. Water retained in the interstices of the tailings and the evaporation of water from the surface of the TSF are the two most significant contributors to water loss at a conventional flotation circuit facility.

  9. Flotation and flocculation chemistry of coal and oxidized coals

    SciTech Connect

    Somasundaran, P.

    1990-01-01

    The objective of this research project is to understand the fundamentals involved in the flotation and flocculation of coal and oxidized coals and elucidate mechanisms by which surface interactions between coal and various reagents enhance coal beneficiation. An understanding of the nature of the heterogeneity of coal surfaces arising from the intrinsic distribution of chemical moieties is fundamental to the elucidation of mechanism of coal surface modification and its role in interfacial processes such as flotation, flocculation and agglomeration. A new approach for determining the distribution in surface properties of coal particles was developed in this study and various techniques capable of providing such information were identified. Distributions in surface energy, contact angle and wettability were obtained using novel techniques such as centrifugal immersion and film flotation. Changes in these distributions upon oxidation and surface modifications were monitored and discussed. An approach to the modelling of coal surface site distributions based on thermodynamic information obtained from gas adsorption and immersion calorimetry is proposed. Polyacrylamide and dodecane was used to alter the coal surface. Methanol adsorption was also studied. 62 figs.

  10. Beneficiation of flotation tailing from Polish copper sulfide ores

    SciTech Connect

    Luszczkiewicz, A.; Sztaba, K.S.

    1995-12-31

    Flotation tailing of Polish copper sulfide ores represents more than 90% of the mass of run-of-mine ore. The tailing contains mainly quartz, dolomite, clay minerals, traces of sulfides, and some accessory minerals. Almost all minerals of the tailing are well liberated and, therefore, any further beneficiation process applied to the tailing is expected to be inexpensive. In this work, results of investigations on utilization of flotation tailing using classification and gravity concentration are presented. It is shown that due to classification of flotation tailing in hydrocyclones, the coarse fraction becomes suitable material for gravity separation providing backfill material for underground mines as well as heavy minerals, a source of valuable rare elements. It was also found that heavy minerals separated by gravity methods contain a significant amount of rare elements such as zirconium, titanium, silver, rare earth metals, and uranium. The light fraction of the gravity separation contains well deslimed quartz particles and meets strict requirements for hydraulic filling material used for structural support in underground mines. Evaluation of the cost of the proposed technology indicated that investment to implement the method would provide a return within 2--4 years.

  11. Effect of reverse flotation on magnetic separation concentrates

    NASA Astrophysics Data System (ADS)

    Bada, S. O.; Afolabi, A. S.; Makhula, M. J.

    2012-08-01

    Reverse flotation studies on magnetite samples have revealed that the use of starch as a depressant of Fe-oxides has a hydrophilic effect on the surface of Fe-bearing silicates and significantly decreases Fe in the silica-rich stream when used in combination with an amine (Lilaflot D817M). In this study, the effect of reverse flotation on the optimization of products obtained from magnetic separation was investigated. Two different magnetic samples, zones 1 and 2, were milled to <75 μm and then subjected to low intensity magnetic separation (LIMS). The LIMS test conducted on the <75 μm shown an upgrade of 46.40wt% Fe, 28.40wt% SiO2 and 2.61wt% MnO for zone 1 and 47.60wt% Fe, 29.17wt% SiO2 and 0.50wt% MnO for zone 2. Further milling of the ore to <25 μm resulted in a higher magnetic-rich product after magnetic separation. Reverse flotation tests were conducted on the agitated magnetic concentrate feed, and the result shows a significant upgrade of Fe compared to that obtained from the non-agitated feed. Iron concentrations greater than 69%, and SiO2 concentrations less than 2% with overall magnetite recoveries greater than 67% and 71% were obtained for zones 1 and 2, respectively.

  12. A study of multistage/multifunction column for fine particle separation. Quarterly technical progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    Chiang, Shiao-Hung

    1995-02-10

    The overall objective of the proposed research program is to explore the potential application of a new a multistage column equipped with vortex-inducing loop-flow contactors (hereafter referred to as the multistage flotation column) for flotation processes using gaseous-CO{sub 2}. The research work will identify the design parameters and their effect on the performance of the separation process. The results of this study will provide a basis for further development of this technology. In the last quarter, the authors completed Task 1 (Project Planning) and performed equipment design. In this quarter, the authors have started to construct the new column for hydrodynamic tests and expect to complete the installation work in the next quarter. The shake-down test is scheduled for March 1995.

  13. Inflatable Column Structure

    NASA Technical Reports Server (NTRS)

    Hedgepeth, J. M.

    1985-01-01

    Lightweight structural member easy to store. Billowing between circumferential loops of fiber inflated column becomes series of cells. Each fiber subjected to same tension along entire length (though tension is different in different fibers). Member is called "isotensoid" column. Serves as jack for automobiles or structures during repairs. Also used as support for temporary bleachers or swimming pools.

  14. Glass-silicon column

    DOEpatents

    Yu, Conrad M.

    2003-12-30

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  15. JCE Feature Columns

    NASA Astrophysics Data System (ADS)

    Holmes, Jon L.

    1999-05-01

    The Features area of JCE Online is now readily accessible through a single click from our home page. In the Features area each column is linked to its own home page. These column home pages also have links to them from the online Journal Table of Contents pages or from any article published as part of that feature column. Using these links you can easily find abstracts of additional articles that are related by topic. Of course, JCE Online+ subscribers are then just one click away from the entire article. Finding related articles is easy because each feature column "site" contains links to the online abstracts of all the articles that have appeared in the column. In addition, you can find the mission statement for the column and the email link to the column editor that I mentioned above. At the discretion of its editor, a feature column site may contain additional resources. As an example, the Chemical Information Instructor column edited by Arleen Somerville will have a periodically updated bibliography of resources for teaching and using chemical information. Due to the increase in the number of these resources available on the WWW, it only makes sense to publish this information online so that you can get to these resources with a simple click of the mouse. We expect that there will soon be additional information and resources at several other feature column sites. Following in the footsteps of the Chemical Information Instructor, up-to-date bibliographies and links to related online resources can be made available. We hope to extend the online component of our feature columns with moderated online discussion forums. If you have a suggestion for an online resource you would like to see included, let the feature editor or JCE Online (jceonline@chem.wisc.edu) know about it. JCE Internet Features JCE Internet also has several feature columns: Chemical Education Resource Shelf, Conceptual Questions and Challenge Problems, Equipment Buyers Guide, Hal's Picks, Mathcad

  16. 18 CFR 1304.400 - Flotation devices and material, all floating structures.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 18 Conservation of Power and Water Resources 2 2012-04-01 2012-04-01 false Flotation devices and material, all floating structures. 1304.400 Section 1304.400 Conservation of Power and Water Resources... structures. (a) All flotation for docks, boat mooring buoys, and other water-use structures and...

  17. 46 CFR 25.25-15 - Retroreflective material for personal flotation devices.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 1 2012-10-01 2012-10-01 false Retroreflective material for personal flotation devices. 25.25-15 Section 25.25-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY UNINSPECTED VESSELS... flotation devices. (a) Each life preserver, each marine buoyant device intended to be worn, and each...

  18. 46 CFR 25.25-15 - Retroreflective material for personal flotation devices.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 1 2014-10-01 2014-10-01 false Retroreflective material for personal flotation devices. 25.25-15 Section 25.25-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY UNINSPECTED VESSELS... flotation devices. (a) Each life preserver, each marine buoyant device intended to be worn, and each...

  19. 46 CFR 25.25-15 - Retroreflective material for personal flotation devices.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 1 2013-10-01 2013-10-01 false Retroreflective material for personal flotation devices. 25.25-15 Section 25.25-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY UNINSPECTED VESSELS... flotation devices. (a) Each life preserver, each marine buoyant device intended to be worn, and each...

  20. 46 CFR 25.25-15 - Retroreflective material for personal flotation devices.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 1 2011-10-01 2011-10-01 false Retroreflective material for personal flotation devices. 25.25-15 Section 25.25-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY UNINSPECTED VESSELS... flotation devices. (a) Each life preserver, each marine buoyant device intended to be worn, and each...

  1. 33 CFR 183.235 - Level flotation test without weights for persons capacity.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Level flotation test without..., DEPARTMENT OF HOMELAND SECURITY (CONTINUED) BOATING SAFETY BOATS AND ASSOCIATED EQUIPMENT Flotation Requirements for Outboard Boats Rated for Engines of More Than 2 Horsepower Tests § 183.235 Level...

  2. 46 CFR 169.741 - Personal flotation devices and ring life buoys.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 7 2014-10-01 2014-10-01 false Personal flotation devices and ring life buoys. 169.741 Section 169.741 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL SCHOOLS SAILING... devices and ring life buoys. Each personal flotation device and ring life buoy must be marked with...

  3. 18 CFR 1304.400 - Flotation devices and material, all floating structures.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... STRUCTURES AND OTHER ALTERATIONS Miscellaneous § 1304.400 Flotation devices and material, all floating... 18 Conservation of Power and Water Resources 2 2011-04-01 2011-04-01 false Flotation devices and material, all floating structures. 1304.400 Section 1304.400 Conservation of Power and Water...

  4. 18 CFR 1304.400 - Flotation devices and material, all floating structures.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... STRUCTURES AND OTHER ALTERATIONS Miscellaneous § 1304.400 Flotation devices and material, all floating... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Flotation devices and material, all floating structures. 1304.400 Section 1304.400 Conservation of Power and Water...

  5. 46 CFR 25.25-15 - Retroreflective material for personal flotation devices.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Retroreflective material for personal flotation devices. 25.25-15 Section 25.25-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY UNINSPECTED VESSELS... flotation devices. (a) Each life preserver, each marine buoyant device intended to be worn, and each...

  6. Nuclear reactor control column

    DOEpatents

    Bachovchin, Dennis M.

    1982-01-01

    The nuclear reactor control column comprises a column disposed within the nuclear reactor core having a variable cross-section hollow channel and containing balls whose vertical location is determined by the flow of the reactor coolant through the column. The control column is divided into three basic sections wherein each of the sections has a different cross-sectional area. The uppermost section of the control column has the greatest cross-sectional area, the intermediate section of the control column has the smallest cross-sectional area, and the lowermost section of the control column has the intermediate cross-sectional area. In this manner, the area of the uppermost section can be established such that when the reactor coolant is flowing under normal conditions therethrough, the absorber balls will be lifted and suspended in a fluidized bed manner in the upper section. However, when the reactor coolant flow falls below a predetermined value, the absorber balls will fall through the intermediate section and into the lowermost section, thereby reducing the reactivity of the reactor core and shutting down the reactor.

  7. Column continuous transition functions

    NASA Astrophysics Data System (ADS)

    Li, Yangrong

    2007-04-01

    A column continuous transition function is by definition a standard transition function P(t) whose every column is continuous for t[greater-or-equal, slanted]0 in the norm topology of bounded sequence space l[infinity]. We will prove that it has a stable q-matrix and that there exists a one-to-one relationship between column continuous transition functions and increasing integrated semigroups on l[infinity]. Using the theory of integrated semigroups, we give some necessary and sufficient conditions under which the minimal q-function is column continuous, in terms of its generator (of the Markov semigroup) as well as its q-matrix. Furthermore, we will construct all column continuous Q-functions for a conservative, single-exit and column bounded q-matrix Q. As applications, we find that many interesting continuous-time Markov chains (CTMCs), say Feller-Reuter-Riley processes, monotone processes, birth-death processes and branching processes, etc., have column continuity.

  8. Gas Chromatograph Method Optimization Trade Study for RESOLVE: 20-meter Column v. 8-meter Column

    NASA Technical Reports Server (NTRS)

    Huz, Kateryna

    2014-01-01

    detection via good peak separation with a longer run time is a better asset than moderate peak separation with a shorter run time. Even given that RESOLVE is highly interested in water and that mission timeline is of significant importance given the short seven-to-ten-day mission timeline, worse detection with an 8m column may lead to overlooking other substances existing on the moon that could advance planetary science. Thus, I recommend the 20m column. However, if mission timeline and water separation are deemed the highest priority, the 8m column should be selected due to its ability to separate water within a shorter run time than the 20m column.

  9. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Task 6 -- Selective agglomeration laboratory research and engineering development for premium fuels

    SciTech Connect

    Moro, N.; Jha, M.C.

    1997-06-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and benchscale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report represents the findings of Subtask 6.5 Selective Agglomeration Bench-Scale Testing and Process Scale-up. During this work, six project coals, namely Winifrede, Elkhorn No. 3, Sunnyside, Taggart, Indiana VII, and Hiawatha were processed in a 25 lb/hr continuous selective agglomeration bench-scale test unit.

  10. Effective harvesting of low surface-hydrophobicity microalgae by froth flotation.

    PubMed

    Garg, Sourabh; Wang, Liguang; Schenk, Peer M

    2014-05-01

    Microalgae harvesting by air flotation is a promising technology for large-scale production of biofuel, feed and nutraceuticals from algae. With an adherence-to-hydrocarbon method and two different types of flotation cells (mechanically agitated cell and Jameson cell), microalgal surface hydrophobicity and bubble size were identified to be critical for effective froth flotation of microalgae. Freshwater alga Chlorella sp. BR2 showed naturally a high hydrophobicity and an ideal response to flotation. However, many marine microalgae possess a low surface hydrophobicity and are thus difficult to harvest. This paper shows that a step-wise optimization approach can substantially improve the flotation of a low surface hydrophobicity marine microalga, Tetraselmis sp. M8, to near full recovery with an enrichment ratio of 11.4.

  11. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 13, October--December, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-01-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit. During Quarter 13 (October--December 1995), testing of the GranuFlow dewatering process indicated a 3--4% reduction in cake moisture for screen-bowl and solid-bowl centrifuge products. The Orimulsion additions were also found to reduce the potential dustiness of the fine coal, as well as improve solids recovery in the screen-bowl centrifuge. Based on these results, Lady Dunn management now plans to use a screen bowl centrifuge to dewater their Microcel{trademark} column froth product. Subtask 3.3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter. Continuing Subtask 6.4 work, investigating coal-water-slurry formulation, indicated that selective agglomeration products can be formulated into slurries with lower viscosities than advanced flotation products. Subtask 6.5 agglomeration bench-scale testing results indicate that a very fine grind is required to meet the 2 lb ash/MBtu product specification for the Winifrede coal, while the Hiawatha coal requires a grind in the 100- to 150-mesh topsize range. Detailed design work remaining involves the preparation and issuing of the final task report. Utilizing this detailed design, a construction bid package was prepared and submitted to three Colorado based contractors for quotes as part of Task 9.

  13. The kinetics of fossil resin extraction from a flotation concentrate

    SciTech Connect

    Li, L.; Yu, Q.; Miller, J.D.

    1995-11-01

    The kinetics of fossil resin extraction from a flotation concentrate by heptane were investigated as a function of process variables using monosize particles. Experimental results provide for a better understanding of the refining process and the basis for subsequent design and construction of a continuous resin refining circuit. Based on the effect of process variables (particle size, stirring speed, and temperature) the resin extraction rate appears to be controlled by surface solvation phenomena. The initial extraction rate was found to be inversely proportional to the initial particle size and a kinetic model is being developed to describe the experimental results.

  14. Equity flotation cost adjustments in utilities' cost of service

    SciTech Connect

    Bierman, H. Jr.; Hass, J.E.

    1984-03-01

    Recovery of the unavoidable costs of issuing new shares of stock is generally agreed to be appropriate in determining utility revenue requirements. This article suggests that the methods by which that is usually accomplished are of questionable accuracy. The conventional practice of adjusting the allowed rate of return on common equity is examined, and an improved adjustment formulation is presented. Acknowledging that application of the formula remains subject to considerable error, however, the authors propose yet another solution. Capitalization of flotation costs as intangible assets is suggested as a way of more accurately factoring such expenses into tariff determinations. 6 references.

  15. Enhanced desulfurizing flotation of coal using sonoelectrochemical method.

    PubMed

    Zhang, Hong-Xi; Hou, Xiao-Yang; Xu, Shi-Xun; Li, Zhi-Long; Yu, Hai-Feng; Shen, Xue-Hua

    2013-09-01

    Enhanced desulfurizing flotation of low sulfur coal was investigated using sonoelectrochemical method. The supporting electrolyte used in this process was sodium chloride and the additive was anhydrous ethanol. The effects of treatment conditions on desulfurization were studied by a single-factor method. The conditions include anhydrous ethanol concentration, sodium chloride concentration, sonoelectrolytic voltage, sonoelectrolytic temperature, sonoelectrolytic time and coal sample granulometry. The optimal experimental conditions achieved for anhydrous ethanol concentration, sodium chloride concentration, sonoelectrolytic voltage, sonoelectrolytic temperature and sonoelectrolytic time are 1.7 mol L(-1), 5.1×10(-3) mol L(-1), 10 V, 70 °C, 50 min achieved for a -0.18 mm coal sample. Optimal conditions cause a sulfur reduction of up to 69.4%. The raw and treated coals were analyzed by infrared spectroscopy and a chemical method. Pyritic sulfur, organic sulfur, ash as well as moisture are partially removed. The combination of high sulfur reduction, high yield, as well as high ash reduction was obtained in the newly developed method of enhanced flotation by sonoelectrochemistry. Ultrasound irradiation promotes electron transfer efficiency and increases clean coal yield.

  16. Inclusion flotation-driven channel segregation in solidifying steels

    PubMed Central

    Li, Dianzhong; Chen, Xing-Qiu; Fu, Paixian; Ma, Xiaoping; Liu, Hongwei; Chen, Yun; Cao, Yanfei; Luan, Yikun; Li, Yiyi

    2014-01-01

    Channel segregation, which is featured by the strip-like shape with compositional variation in cast materials due to density contrast-induced flow during solidification, frequently causes the severe destruction of homogeneity and some fatal damage. An investigation of its mechanism sheds light on the understanding and control of the channel segregation formation in solidifying metals, such as steels. Until now, it still remains controversial what composes the density contrasts and, to what extent, how it affects channel segregation. Here we discover a new force of inclusion flotation that drives the occurrence of channel segregation. It originates from oxide-based inclusions (Al2O3/MnS) and their sufficient volume fraction-driven flotation becomes stronger than the traditionally recognized inter-dendritic thermosolutal buoyancy, inducing the destabilization of the mushy zone and dominating the formation of channels. This study uncovers the mystery of oxygen in steels, extends the classical macro-segregation theory and highlights a significant technological breakthrough to control macrosegregation. PMID:25422943

  17. A Novel Mineral Flotation Process Using Thiobacillus ferrooxidans

    PubMed Central

    Nagaoka, Toru; Ohmura, Naoya; Saiki, Hiroshi

    1999-01-01

    Oxidative leaching of metals by Thiobacillus ferrooxidans has proven useful in mineral processing. Here, we report on a new use for T. ferrooxidans, in which bacterial adhesion is used to remove pyrite from mixtures of sulfide minerals during flotation. Under control conditions, the floatabilities of five sulfide minerals tested (pyrite, chalcocite, molybdenite, millerite, and galena) ranged from 90 to 99%. Upon addition of T. ferrooxidans, the floatability of pyrite was significantly suppressed to less than 20%. In contrast, addition of the bacterium had little effect on the floatabilities of the other minerals, even when they were present in relatively large quantities: their floatabilities remained in the range of 81 to 98%. T. ferrooxidans thus appears to selectively suppress pyrite floatability. As a consequence, 77 to 95% of pyrite was removed from mineral mixtures while 72 to 100% of nonpyrite sulfide minerals was recovered. The suppression of pyrite floatability was caused by bacterial adhesion to pyrite surfaces. When normalized to the mineral surface area, the number of cells adhering to pyrite was significantly larger than the number adhering to other minerals. These results suggest that flotation with T. ferrooxidans may provide a novel approach to mineral processing in which the biological functions involved in cell adhesion play a key role in the separation of minerals. PMID:10427053

  18. Selective flotation of fossil resin from western coal. A special report comprising: Monthly report for December 1991--April 1992 and Quarterly reports for December 1, 1991--February 29, 1992

    SciTech Connect

    Jensen, G.F.; Miller, J.D.

    1992-03-20

    The test program has demonstrated that: (1) technically, the new flotation technologies discovered at the University of Utah and then improved upon by Advanced Processing Technologies, Inc. provide a highly efficient means to selectively recover fossil resin from coal. The proof-of-concept continuous flotation circuit resulted in fossil resin recovery with the same separation efficiency as was obtained from laboratory bench-scale testing (more than 80% recovery at about 80% concentrate grade); and (2) economically, the selective flotation process has been shown to be sufficiently profitable to justify the development of a fossil resin industry based on this new flotation process. The proof-of-concept testing has resulted in significant interest from several coal mining companies and has sparked the desire of local and state government to establish a fossil resin industry in the Wasatch Plateau coal field. In this view, the results from the current proof-of-concept testing program have been successful. This special report provides theoretical and analytical data on some surface chemistry work pertinent to fossil resin characterization, and other efforts carried out during the past months.

  19. Egg flotation estimates nest age for Pacific and Red-throated Loons

    USGS Publications Warehouse

    Rizzolo, Daniel; Schmutz, Joel A.

    2007-01-01

    We used Pacific Loon (Gavia pacifica) and Red-throated Loon (G. stellata) nests with known ages to gauge the efficacy of egg flotation for determining nest age in coastal Alaska. Egg flotation accurately estimated nest age for both species; the mean ± 1SD difference between known age and age determined with egg flotation was - 0.05 ± 2.00 d and -0.02 ± 1.63 d for Pacific and Red-throated Loons, respectively. Day of nest initiation did not influence the relationship between known nest age and nest age estimated with egg flotation, indicating incubation period was not shortened in nests initiated later in the season. Additionally, we found no difference in the ability of egg flotation to estimate nest age between two widely dispersed study sites for Pacific Loons, and only a small difference between two of three widely dispersed study sites for Red-throated Loons. Thus, our described relationships between egg flotation categories and nest age should be broadly applicable for these holarctic species. We conclude that for Pacific and Red-throated Loons, egg flotation is a useful technique for determining nest age in the field to better monitor nest fate, and to quantify nest age effects on nest daily survival rate.

  20. Leaching behaviour and mechanical properties of copper flotation waste in stabilized/solidified products.

    PubMed

    Mesci, Başak; Coruh, Semra; Ergun, Osman Nuri

    2009-02-01

    This research describes the investigation of a cement-based solidification/stabilization process for the safe disposal of copper flotation waste and the effect on cement properties of the addition of copper flotation waste (CW) and clinoptilolite (C). In addition to the reference mixture, 17 different mixtures were prepared using different proportions of CW and C. Physical properties such as setting time, specific surface area and compressive strength were determined and compared to a reference mixture and Turkish standards (TS). Different mixtures with the copper flotation waste portion ranging from 2.5 to 12.5% by weight of the mixture were tested for copper leachability. The results show that as cement replacement materials especially clinoptilolite had clear effects on the mechanical properties. Substitution of 5% copper flotation waste for Portland cement gave a similar strength performance to the reference mixture. Higher copper flotation waste addition such as 12.5% replacement yielded lower strength values. As a result, copper flotation waste and clinoptilolite can be used as cementitious materials, and copper flotation waste also can be safely stabilized/solidified in a cement-based solidification/stabilization system.

  1. Application of dissolved air flotation on separation of waste plastics ABS and PS.

    PubMed

    Wang, Hui; Chen, Xiao-Lei; Bai, Yang; Guo, Chao; Zhang, Li

    2012-07-01

    The aim of this research was to separate waste plastics acrylonitrile butadiene styrene (ABS) and polystyrene (PS) by dissolved air flotation in a self-designed dissolved air flotation apparatus. The effects of wetting agents, frother, conditioning time and flotation time on flotation behavior of waste plastics ABS (w-ABS) and PS (w-PS) were investigated and the optimized separation conditions were obtained. The results showed that when using 25 mgL(-1) tannic acid, 5 mgL(-1) terpineol, 15 min conditioning time and 15 min flotation time, mixtures of w-ABS and w-PS were separated successfully by dissolved air flotation in two stages, the results revealed that the purity and recovery rate of w-PS in the floated products were 90.12% and 97.45%, respectively, and the purity and recovery rate of w-ABS in the depressed products were 97.24% and 89.38%, respectively. Based on the studies of wetting mechanism of plastic flotation, it is found that the electrostatic force and hydrophobic attraction cannot be the main factor of the interaction between wetting agent molecules and plastic particles, which can be completed through water molecules as a mesophase, and a hydrogen bonding adsorption model with hydration shell as a mesophase was proposed.

  2. Kinetic model for conventional flotation of coal. Report of investigations/1995

    SciTech Connect

    Susko, F.J.; Stanley, D.A.

    1995-12-31

    The U.S. Bureau of Mines has developed a computer model to describe a flotation process. Coal data from conventional flotation has been converted to a simple two-parameter kinetic model developed by Reuter and van Deventer. Each set of coal data was represented by two constants, alpha and beta, and an average flotation rate. The success of the model was demonstrated when the calculated and experimental recoveries showed good correlation. The two-parameter model allows complex data to be defined much more efficiently than traditional knowledge-based models.

  3. Hydrophobic Agglomeration of Mineral Fines in Aqueous Suspensions and its Application in Flotation: a Review

    NASA Astrophysics Data System (ADS)

    Yang, Bingqiao; Song, Shaoxian

    2014-05-01

    Hydrophobic agglomeration is originated from the hydrophobic attraction between particles, which is essentially different from electrolyte coagulation and polymer flocculation. It is applied to mineral processing in floc-flotation process to improve the recovery of mineral fines. In this paper, the applications of this phenomenon in mineral fines were summarized, including the origin of hydrophobic agglomeration, the main factors affect hydrophobic agglomeration (particle hydrophobicity, shear rate and duration, nonpolar oil and tank geometry), as well as hydrophobic agglomeration based separation processes (carrier flotation and floc-flotation).

  4. A novel process for separation of polycarbonate, polyvinyl chloride and polymethyl methacrylate waste plastics by froth flotation.

    PubMed

    Wang, Chong-Qing; Wang, Hui; Huang, Luo-Luo

    2017-04-08

    A novel process was proposed for separation of ternary waste plastics by froth flotation. Pretreatment of plastics with potassium permanganate (KMnO4) solution was conducted to aid flotation separation of polycarbonate (PC), polyvinyl chloride (PVC) and polymethyl methacrylate (PMMA) plastics. The effect of pretreatment parameters including KMnO4 concentration, treatment time, temperature and stirring rate on flotation recovery were investigated by single factor experiments. Surface treatment with KMnO4 changes selectively the flotation behavior of PC, PVC and PMMA, enabling separation of the plastics by froth flotation. Mechanism of surface treatment was studied by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray photoelectron spectrum (XPS). Effect of frother concentration and flotation time on flotation behavior of plastic mixtures was further studied for flotation separation. The optimized conditions for separation of PC are KMnO4 concentration 2mmolL(-1), treatment time 10min, temperature 60°C, stirring rate 300rpm, flotation time 1min and frother concentration 17.5mgL(-1). Under optimum conditions, PVC and PMMA mixtures are also separated efficiently by froth flotation associated with KMnO4 treatment. The purity of PC, PVC and PMMA is up to 100%, 98.41% and 98.68%, while the recovery reaches 96.82%, 98.71% and 98.38%, respectively. Economic analysis manifests remarkable profits of the developed process. Reusing KMnO4 solution is feasible, enabling the process greener.

  5. Columns in Clay

    ERIC Educational Resources Information Center

    Leenhouts, Robin

    2010-01-01

    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  6. Optimization of Fenton's reagent coupled to Dissolved Air Flotation to remove cyanobacterial odorous metabolites and suspended solids from raw surface water.

    PubMed

    Elías-Maxil, Jorge A; Rigas, Fotis; Orta de Velásquez, María Teresa; Ramírez-Zamora, Rosa-María

    2011-01-01

    Ferrous salts are commonly used as coagulants in Water Treatment Plants (WTPs). When these salts are combined with hydrogen peroxide in acidic conditions - besides coagulation - an additional Advanced Oxidation Process (Fenton's reagent) can take place. Using a response surface methodology, this paper presents the optimization of a novel treatment system constituted by Fenton's reagent (FE) and Dissolved Air Flotation (DAF) for removing 2-Methylisoborneol (MIB), geosmin and Total Suspended Solids (TSS) from raw water. FE was proven able to remove completely both micro pollutants found in the influent of a drinking water treatment plant. Moreover, higher clarification rate was achieved by coupling FE-DAF with respect FE-Sedimentation.

  7. Foaming and cell flotation in suspended plant cell cultures and the effect of chemical antifoams.

    PubMed

    Wongsamuth, R; Doran, P M

    1994-08-05

    Foam development and stability in Atropa belladonna suspensions were investigated as a function of culture conditions. Foaming was due mainly to properties of the cell-free broth and was correlated with protein content; effects due to presence of cells increased towards the end of batch culture. Highest foam levels were measured 11 days after inoculation. Air flow rate was of major importance in determining foam volume; foam volume and stability were also strongly dependent on pH. Foam flotation of plant cells was very effective. After 30 min foaming, ca. 55% of cells were found in the foam; this increased to ca. 75% after 90 min. Polypropylene glycol 1025 and 2025, Pluronic PE 6100, and Antifoam-C emulsion were tested as chemical antifoams. Polypropylene glycol 1025 and Antifoam C at concentrations up to 600 ppm had no adverse effect on growth in shake flasks; Pluronic PE 6100 has an inhibitory effect at all levels tested. Concentrations of polypropylene glycol 2025 and Pluronic PE 6100 as low as 20 ppm reduced foam volumes by a factor of ca. 10. Addition of antifoam reduced k(L)a values in bubble-column and stirred-tank bioreactors. After operation of a stirred reactor for 2 days using Antifoam C for foam control, cell production was limited by oxygen due to the effect of antifoam on mass transfer. Theoretical analysis showed that maximum cell concentrations and biomass levels decline with increasing reactors working volume due to greater consumption of antifoam to prevent foam overflow. The results indicate that when chemical foam control is used in plant cell cultures, head-space volume and tolerable foam levels must be considered to optimize biomass production. (c) 1994 John Wiley & Sons, Inc.

  8. Achieved slime flotation in centrifugal force field by float-hydrocyclone

    SciTech Connect

    Guode Xuzhanxian; Gaozhenshen Songzhiwei

    1997-12-31

    Based on the theory of intensifying flotation in a centrifugal force field, float-hydrocyclone (FH) is developed, which is a new type of equipment for slime flotation and consists of an air bubble generator and the cylindrical section of a hydrocyclone. The combination of pulp and air bubbles is fed into the FH tangentially at a high speed to effect the separation of slime in the centrifugal force field. It offers many advantages over mechanically agitated flotation cells. Commercial test results show that slime, especially fine slime, can be perfectly floated in the FH with rapid flotation and fine froth size. The quality and quantity of concentrate and tailings can be adjusted conveniently within a certain range according to different requirements.

  9. Rule-based characterization of industrial flotation processes with inductive techniques and genetic algorithms

    SciTech Connect

    Gouws, F.S.; Aldrich, C.

    1996-11-01

    By making use of machine learning techniques, the features of flotation froths and other plant variables can be used as a basis for the development of knowledge-based systems for plant monitoring and control. probabilistic induction and genetic algorithms were used to classify different froth structures from industrial copper and platinum flotation plants, as well as recoveries from a phosphate flotation plant. Both algorithms were equally capable of classifying the different froths at least as well as a human expert. The genetic algorithm performed significantly better than the inductive algorithm but required more tuning before optimum results could be obtained. The classification rules produced by both algorithms can easily be incorporated into a supervisory expert system shell or decision support system for plant operators and could consequently make a significant impact on the way flotation plants are currently being controlled.

  10. Statistical Evaluation and Optimization of Factors Affecting the Leaching Performance of Copper Flotation Waste

    PubMed Central

    Çoruh, Semra; Elevli, Sermin; Geyikçi, Feza

    2012-01-01

    Copper flotation waste is an industrial by-product material produced from the process of manufacturing copper. The main concern with respect to landfilling of copper flotation waste is the release of elements (e.g., salts and heavy metals) when in contact with water, that is, leaching. Copper flotation waste generally contains a significant amount of Cu together with trace elements of other toxic metals, such as Zn, Co, and Pb. The release of heavy metals into the environment has resulted in a number of environmental problems. The aim of this study is to investigate the leaching characteristics of copper flotation waste by use of the Box-Behnken experimental design approach. In order to obtain the optimized condition of leachability, a second-order model was examined. The best leaching conditions achieved were as follows: pH = 9, stirring time = 5 min, and temperature = 41.5°C. PMID:22629194

  11. Adsorption of Crystal Violet on Activated Carbon Prepared from Coal Flotation Concentrate

    NASA Astrophysics Data System (ADS)

    Aydogmus, Ramazan; Depci, Tolga; Sarikaya, Musa; Riza Kul, Ali; Onal, Yunus

    2016-10-01

    The objective of this study is firstly to investigate the floatability properties of Zilan- Van coal after microwave irradiation and secondly to produce activated carbon from flotation concentrate in order to remove Crystal Violet (CV) from waste water. The flotation experiments showed that microwave heating at 0.9 kW power level for 60 sec exposure time enhanced the hydrophobicity and increased the flotation yield. The activated carbon with remarkable surface area (696 m2/g) was produced from the flotation concentrate and used to adsorb CV from aqueous solution in a batch reactor at different temperature. The adsorption properties of CV onto the activated carbon are discussed in terms of the adsorption isotherms (Langmuir and Freundlich) and found that the experimental results best fitted by the Langmuir model.

  12. Froth flotation of oil-bearing metal sulfide wastes

    SciTech Connect

    Miller, R.L.; Atwood, R.L.; Ye, Yi

    1991-12-01

    An industrial wastewater, including plating wastes, is treated with sodium sulfide and ferrous sulfate to form a sulfide-oxide precipitate containing chromium and other toxic metals. Hydrocarbons, in the water, coat the sulfide-oxide particles, impeding metal recovery. Froth flotation, without reagent addition, was found to recover 93.9% of the solids from the sludge with simultaneous rejection of 89% of the water. Methyl isobutyl carbinol (MIBC) improved recovery and potassium amyl xanthate improved both recovery and grade. The process design has wastewater feed (without MIBC) to the rougher circuit. The rougher concentrate is conditioned with MIBC and fed to a cleaner circuit to achieve a high grade concentrate. About 95% of the water is recirculated to the waste treatment plant. 3 refs., 3 figs., 4 tabs.

  13. Froth flotation of oil-bearing metal sulfide wastes

    SciTech Connect

    Miller, R.L. ); Atwood, R.L.; Ye, Yi )

    1991-01-01

    An industrial wastewater, including plating wastes, is treated with sodium sulfide and ferrous sulfate to form a sulfide-oxide precipitate containing chromium and other toxic metals. Hydrocarbons, in the water, coat the sulfide-oxide particles, impeding metal recovery. Froth flotation, without reagent addition, was found to recover 93.9% of the solids from the sludge with simultaneous rejection of 89% of the water. Methyl isobutyl carbinol (MIBC) improved recovery and potassium amyl xanthate improved both recovery and grade. The process design has wastewater feed (without MIBC) to the rougher circuit. The rougher concentrate is conditioned with MIBC and fed to a cleaner circuit to achieve a high grade concentrate. About 95% of the water is recirculated to the waste treatment plant. 3 refs., 3 figs., 4 tabs.

  14. An Investigation of Variables in a Fecal Flotation Technique

    PubMed Central

    O'Grady, M. R.; Slocombe, J. O. D.

    1980-01-01

    Several variables in a standard vial fecal gravitational flotation technique were investigated. These were the specific gravity of the sodium nitrate flotation solution, duration of flotation and mesh sizes of strainers. The number of eggs which floated and adhered to a coverslip were counted and estimates of the number of eggs remaining in the strained fecal suspension and in the feces trapped on the strainer were made. Eggs from hookworms, Trichuris vulpis and Toxocara canis in feces from dogs, Nematodirus spp. from sheep and Parascaris equorum from horses floated equally well in solutions with specific gravities (SpGr) ranging from 1.22-1.38. Taenia spp. from dogs had a slightly narrower range (SpGr 1.27-1.38) for best recovery. Eggs from Haemonchus contortus from sheep appeared to float best between SpGr 1.22- 1.32. Strongyles from one horse floated best with SpGr 1.27-1.32 and from another with SpGr 1.11-1.38. Coccidial oocysts from sheep floated best in a narrow range of SpGr from 1.22-1.27. However, as the SpGr of the solution was increased the recognition of eggs under the coverslip was increasingly difficult and especially so at SpGr 1.38 with sheep feces. This was due to the increasing amount of debris and the more rapid formation of crystals with evaporation with solutions of higher SpGr. It appeared, therefore, that solutions with SpGr of 1.22-1.35 would be best for routine laboratory use. At specific gravity 1.27, there appeared to be no difference in the number of eggs recovered for a four, eight and 12 min flotation period. Only 3-7% of the eggs in 4 g of feces were counted under the coverslip. This poor efficacy resulted first because approximately 50% of the eggs were trapped in the feces and retained on the strainer. Secondly, only one half of the strained fecal suspension, containing approximately 25% of the eggs, was placed in the vial for examination. Thirdly, of those eggs in the vial only 16-29% were counted under the coverslip. When the

  15. Molecular Loops in the Galactic Center: Evidence for Magnetic Flotation

    NASA Astrophysics Data System (ADS)

    Fukui, Yasuo; Yamamoto, Hiroaki; Fujishita, Motosuji; Kudo, Natsuko; Torii, Kazufumi; Nozawa, Satoshi; Takahashi, Kunio; Matsumoto, Ryoji; Machida, Mami; Kawamura, Akiko; Yonekura, Yoshinori; Mizuno, Norikazu; Onishi, Toshikazu; Mizuno, Akira

    2006-10-01

    The central few hundred parsecs of the Milky Way host a massive black hole and exhibit very violent gas motion and high temperatures in molecular gas. The origin of these properties has been a mystery for the past four decades. Wide-field imaging of the 12CO (rotational quantum number J = 1 to 0) 2.6-millimeter spectrum has revealed huge loops of dense molecular gas with strong velocity dispersions in the galactic center. We present a magnetic flotation model to explain that the formation of the loops is due to magnetic buoyancy caused by the Parker instability. The model has the potential to offer a coherent explanation for the origin of the violent motion and extensive heating of the molecular gas in the galactic center.

  16. Selective flotation of phosphate minerals with hydroxamate collectors

    DOEpatents

    Miller, Jan D.; Wang, Xuming; Li, Minhua

    2002-01-01

    A method is disclosed for separating phosphate minerals from a mineral mixture, particularly from high-dolomite containing phosphate ores. The method involves conditioning the mineral mixture by contacting in an aqueous in environment with a collector in an amount sufficient for promoting flotation of phosphate minerals. The collector is a hydroxamate compound of the formula; ##STR1## wherein R is generally hydrophobic and chosen such that the collector has solubility or dispersion properties it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms. M is a cation, typically hydrogen, an alkali metal or an alkaline earth metal. Preferably, the collector also comprises an alcohol of the formula, R'--OH wherein R' is generally hydrophobic and chosen such that the collector has solubility or dispersion properties so that it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms.

  17. Heavy metals in the products of deinking flotation of digital offset prints.

    PubMed

    Barbaric-Mikocevic, Zeljka; Orescanin, Visnja; Bolanca, Zdenka; Lulic, Stipe; Rozic, Mirela

    2004-01-01

    This study was undertaken to investigate the suitability of applying the conventional method of chemical deinking flotation of digital offset prints and ecological implications of the disposal of digital offset prints, with special emphasis on the content of heavy metal cations. The EDXRF method was used to determine the concentrations of Pb, Zr, Sr, As, Co, Zn, Cu, Ni, Fe, Mn, Cr, V, Ti, Ca, and K cations in handsheet ashes after flotation as well as in ashes of foams separated from cellulose suspension in the flotation phase. The same method was applied to determine the concentrations of Pb, Cr, Mn, Fe, Ni, Cu, Zn, and Co in process water filtrates obtained from the cellulose suspension after flotation and in foam filtrates. Centrifuging and coagulation previously treated flotation process water, while foam filtrates were centrifuged. Concentrations of Pb, As, Sr, Zr, K, Ca, Ti, V, Cr, Mn, Fe, Cu, and Zn were determined in the sediments obtained by centrifuging process water. The trials were done with unprinted substrates without deinking chemicals, with unprinted substrates in the presence of deinking chemicals and with printed substrates in the presence of deinking chemicals. Cation analysis revealed that deinking chemicals facilitate release of cations from the substrate and their transition into process water. Concentrations of most cations in the flotation process water, in foam water as well as in the sediment of the process water of printed substrate flotation deinking were lower than those obtained by flotation of unprinted substrate suspension. Polymer particles of ElectroInk incompletely separated from cellulose fibers prevent release of cations from cellulose fibers into process water. Deinking chemicals do not affect release of cations from ElectroInk particles, so the substrate is the main source of increased concentration of cations in the water of digital offset print deinking. The major part of cations in process water is bound to the colloid

  18. Pioneering studies on the flotation of corundum from a Montana gneiss

    SciTech Connect

    Smith, C.W.; Llewellyn, T.O.

    1987-01-01

    Bureau of Mines conducted laboratory-scale beneficiation tests on a sample of corundum gneiss from Montana to devise a method for beneficiating corundum for use as a substitute for refractory-grade bauxite. A flotation process utilizing petroleum sulfonate as the collector in an acid circuit was devised. Results showed that two flotation schemes each produced a concentrate exceeding the national stockpile specifications for calcined bauxite.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 14, January--March 1996

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-04-30

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by June 1997. During Quarter 14 (January--March 1996), parametric testing of the 30-inch Microcel{trademark} flotation column at the Lady Dunn Plant continued under Subtask 3.2. Subtask 3. 3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter with parametric testing of the batch dewatering unit. Coal product moistures of 3 to 12 percent were achieved, with higher percent solids slurry feeds resulting in lower product moistures. For a given percent solids feed, the product moisture decreased with increasing butane to dry coal ratios. Stirring time, stirring rate, and settling time were all found to have little effect on the final moisture content. Continuing Subtask 6.4 work, investigating coal-water-fuel slurry formulation for coals cleaned by selective agglomeration, indicated that pH adjustment to 10 resulted in marginally better (lower viscosity) slurries for one of the two coals tested. Subtask 6.5 agglomeration bench-scale testing results indicate that the new Taggart coal requires a grind with a d{sub 80} of approximately 33 microns to achieve the 1 lb ash/MBtu product quality specification. Also under Subtask 6.5, reductions in the various trace element concentrations accomplished during selective agglomeration were determined. Work was essentially completed on the detailed design of the PDU selective agglomeration module under Task 7 with the issuing of a draft report.

  20. Sorbent flotation in trace metal analysis: Preconcentration of uranium traces on hydrophobized hyphan-cellulose

    SciTech Connect

    Braun, T.; Galsan, V.; Toelgyessy, J.

    1994-01-01

    The use of flotation in analytical chemistry has established itself as a reliable technique for the separation and preconcentration of trace elements. In most of the applications in situ generated inorganic and organic precipitates were used as trace element gatherers and floated to the surface of large volumes of solution with the aid of a rising stream of gas bubbles and well selected collector surfactants. This procedure of {open_quotes}precipitate flotation{close_quotes} has been well studied and applied to many problems of preconcentration chemistry. As far as the present authors are aware of solid preformed sorbents have not yet been separated from large volumes of solution by flotation after batch type sorption of trace elements on them. That is why the authors considered it worthwhile to explore the analytical potentialities of the separation of commercial and non-commercial solid sorbents by flotation. The new procedure the authors like to call {open_quotes}sorbent flotation{close_quotes} refers to the separation of preformed solid sorbents from large volumes of solution and can be viewed as an extension to the already known flotation of in situ formed inorganic and organic precipitates.

  1. Separation of polyethylene terephthalate from municipal waste plastics by froth flotation for recycling industry

    SciTech Connect

    Wang, Chong-Qing; Wang, Hui Liu, You-Nian

    2015-01-15

    Highlights: • Factors of NaOH treatment were studied by orthogonal and single factor experiments. • Mechanism of alkaline treatment for facilitating flotation was manifested. • Flotation separation of PET was achieved with high purity and efficiency. • A flow sheet of purification PET from MWP was designed. - Abstract: Recycling is an effective way to manage plastic wastes and receives considerable attention. Since plastic mixtures are difficult to recycle because of their intrinsic characteristics, separation of mixed plastics is the key problem for recycling. Separation of polyethylene terephthalate (PET) from municipal waste plastics (MWP) by froth flotation combined with alkaline pretreatment was investigated for recycling industry. The effect of process variables was estimated by L{sub 9} (3{sup 4}) orthogonal array of experiments and single factor experiments. The optimum conditions of alkaline pretreatment are 10 wt% sodium hydroxide, 20 min and 70 °C. After alkaline pretreatment under optimum conditions, flotation separation PET from acrylonitrile–butadiene–styrene, polystyrene, polycarbonate or polyvinyl chloride was achieved with high purity and efficiency. The purity of PET is up to 98.46% and the recovery is above 92.47%. A flow sheet of separation PET from MWP by a combination of froth flotation and sink float separation was designed. This study facilitates industrial application of plastics flotation and provides technical insights into recycling of waste plastics.

  2. Separation of plastics: The importance of kinetics knowledge in the evaluation of froth flotation.

    PubMed

    Censori, Matteo; La Marca, Floriana; Carvalho, M Teresa

    2016-08-01

    Froth flotation is a promising technique to separate polymers of similar density. The present paper shows the need for performing kinetic tests to evaluate and optimize the process. In the experimental study, batch flotation tests were performed on samples of ABS and PS. The floated product was collected at increasing flotation time. Two variables were selected for modification: the concentration of the depressor (tannic acid) and airflow rate. The former is associated with the chemistry of the process and the latter with the transport of particles. It was shown that, like mineral flotation, plastics flotation can be adequately assumed as a first order rate process. The results of the kinetic tests showed that the kinetic parameters change with the operating conditions. When the depressing action is weak and the airflow rate is low, the kinetic is fast. Otherwise, the kinetic is slow and a variable percentage of the plastics never floats. Concomitantly, the time at which the maximum difference in the recovery of the plastics in the floated product is attained changes with the operating conditions. The prediction of flotation results, process evaluation and comparisons should be done considering the process kinetics.

  3. Flotation separation of polyvinyl chloride and polyethylene terephthalate plastics combined with surface modification for recycling.

    PubMed

    Wang, Chongqing; Wang, Hui; Fu, Jiangang; Zhang, Lingling; Luo, Chengcheng; Liu, Younian

    2015-11-01

    Surface modification with potassium permanganate (KMnO4) solution was developed for separation of polyvinyl chloride (PVC) and polyethylene terephthalate (PET) waste plastics. The floatability of PVC decreases with increasing of KMnO4 concentration, treatment time, temperature and stirring rate, while that of PET is unaffected. Fourier transform infrared (FT-IR) analysis confirms that mechanism of surface modification may be due to oxidization reactions occurred on PVC surface. The optimum conditions are KMnO4 concentration 1.25 mM/L, treatment time 50 min, temperature 60°C, stirring rate 300 r/min, frother concentration 17.5 g/L and flotation time 1 min. PVC and PET with different particle sizes were separated efficiently through two-stage flotation. Additionally, after ultrasonic assisted surface modification, separation of PVC and PET with different mass ratios was obtained efficiently through one-stage flotation. The purity and the recovery of the obtained products after flotation separation are up to 99.30% and 99.73%, respectively. A flotation process was designed for flotation separation of PVC and PET plastics combined with surface modification. This study provides technical insights into physical separation of plastic wastes for recycling industry.

  4. Ammonia modification for flotation separation of polycarbonate and polystyrene waste plastics.

    PubMed

    Wang, Chong-qing; Wang, Hui; Gu, Guo-hua; Lin, Qing-quan; Zhang, Ling-ling; Huang, Luo-luo; Zhao, Jun-yao

    2016-05-01

    A promising method, ammonia modification, was developed for flotation separation of polycarbonate (PC) and polystyrene (PS) waste plastics. Ammonia modification has little effect on flotation behavior of PS, while it changes significantly that of PC. The PC recovery in the floated product drops from 100% to 3.17% when modification time is 13min and then rises to 100% after longer modification. The mechanism of ammonia modification was studied by contact angle, and Fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS) measurements. Contact angle of PC indicates the decline of PC recovery in the floated product is ascribed to an increase in surface wettability. FT-IR and XPS spectra suggest that ammonia modification causes chemical reactions occurred on PC surface. Flotation behavior of ammonia-modified PC and PS was investigated with respect to flotation time, frother concentration and particle sizes. Flotation separation of PC and PS waste plastics was conducted based on the flotation behavior of single plastic. PC and PS mixtures with different particle sizes are separated efficiently, implying that the technology possesses superior applicability to particle sizes of plastics. The purity of PS and PC is up to 99.53% and 98.21%, respectively, and the recovery of PS and PC is larger than 92.06%. A reliable, cheap and effective process is proposed for separation of PC and PS waste plastics.

  5. Effect of three typical sulfide mineral flotation collectors on soil microbial activity.

    PubMed

    Guo, Zunwei; Yao, Jun; Wang, Fei; Yuan, Zhimin; Bararunyeretse, P; Zhao, Yue

    2016-04-01

    The sulfide mineral flotation collectors are wildly used in China, whereas their toxic effect on soil microbial activity remains largely unexplored. In this study, isothermal microcalorimetric technique and soil enzyme assay techniques were employed to investigate the toxic effect of typical sulfide mineral flotation collectors on soil microbial activity. Soil samples were treated with different concentrations (0-100 μg•g - 1 soil) of butyl xanthate, butyl dithiophosphate, and sodium diethyldithiocarbamate. Results showed a significant adverse effect of butyl xanthate (p < 0.05), butyl dithiophosphate, and sodium diethyldithiocarbamate (p < 0.01) on soil microbial activity. The growth rate constants k decreased along with the increase of flotation collectors concentration from 20.0 to 100.0 μg•g(-1). However, the adverse effects of these three floatation collectors showed significant difference. The IC 20 of the investigated flotation reagents followed such an order: IC 20 (butyl xanthate) > IC 20 (sodium diethyldithiocarbamate) > IC 20 (butyl dithiophosphate) with their respective inhibitory concentration as 47.03, 38.36, and 33.34 μg•g(-1). Besides, soil enzyme activities revealed that these three flotation collectors had an obvious effect on fluorescein diacetate hydrolysis (FDA) enzyme and catalase (CAT) enzyme. The proposed methods can provide meaningful toxicological information of flotation reagents to soil microbes in the view of metabolism and biochemistry, which are consistent and correlated to each other.

  6. Slurry bubble column hydrodynamics

    NASA Astrophysics Data System (ADS)

    Rados, Novica

    Slurry bubble column reactors are presently used for a wide range of reactions in both chemical and biochemical industry. The successful design and scale up of slurry bubble column reactors require a complete understanding of multiphase fluid dynamics, i.e. phase mixing, heat and mass transport characteristics. The primary objective of this thesis is to improve presently limited understanding of the gas-liquid-solid slurry bubble column hydrodynamics. The effect of superficial gas velocity (8 to 45 cm/s), pressure (0.1 to 1.0 MPa) and solids loading (20 and 35 wt.%) on the time-averaged solids velocity and turbulent parameter profiles has been studied using Computer Automated Radioactive Particle Tracking (CARPT). To accomplish this, CARPT technique has been significantly improved for the measurements in highly attenuating systems, such as high pressure, high solids loading stainless steel slurry bubble column. At a similar set of operational conditions time-averaged gas and solids holdup profiles have been evaluated using the developed Computed Tomography (CT)/Overall gas holdup procedure. This procedure is based on the combination of the CT scans and the overall gas holdup measurements. The procedure assumes constant solids loading in the radial direction and axially invariant cross-sectionally averaged gas holdup. The obtained experimental holdup, velocity and turbulent parameters data are correlated and compared with the existing low superficial gas velocities and atmospheric pressure CARPT/CT gas-liquid and gas-liquid-solid slurry data. The obtained solids axial velocity radial profiles are compared with the predictions of the one dimensional (1-D) liquid/slurry recirculation phenomenological model. The obtained solids loading axial profiles are compared with the predictions of the Sedimentation and Dispersion Model (SDM). The overall gas holdup values, gas holdup radial profiles, solids loading axial profiles, solids axial velocity radial profiles and solids

  7. Micro-agglomerate flotation for deep cleaning of coal. Quarterly progress report, October 1--December 30, 1995

    SciTech Connect

    Chandler, S.; Hogg, R.

    1996-04-01

    Goals are to demonstrate the technical and economic feasibility of a micro-agglomerate flotation process (combination of oil-agglomeration and froth flotation) and to establish the essential criteria for reagent selection and system design and operation. The research program was organized into the following tasks: interfacial studies, emulsification, agglomerate growth and structure, and agglomerate flotation. Work on the first two tasks has been completed.

  8. Flotation Analysis for Boat Docks on U.S. Army Corps of Engineers Projects. Recreation Management Support Program

    DTIC Science & Technology

    2009-06-01

    blocks of EPS are commonly collected, particularly after a storm season. In Georgia , a Lake Hartwell Association newsletter referred to these as...flotation products being used at boat docks on U.S. Army Corps of Engineers lakes , best practices and policies for dock flotation of various water...TR-09-5 1 1 Introduction This report documents a survey of flotation products being used at boat docks on U.S. Army Corps of Engineers lakes , best

  9. Technically Speaking: Columns from the Monthly Magazine, "The Source," 1987-88. Trace Reprint Series.

    ERIC Educational Resources Information Center

    Borden, Peter A.; And Others

    The "Technically Speaking" columns from several isues of "The Source" magazine are reprinted. The columns were written by Gregg Vanderheiden, Peter Borden, Roger Smith, Jane Berliss, and Charles Lee. Titles of the columns included are: "Technological Advances: A Boon or a Barrier to Persons with Disabilities?";…

  10. A study of multi-stage/multi-function column for fine particle separation. Quarterly technical progress report, July 8, 1994--September 30, 1994

    SciTech Connect

    Chiang, Shiao-Hung

    1995-01-20

    The overall objective of the proposed research program is to explore the potential application of a new invention involving a multi-stage column equipped with vortex-inducing loop-flow contactors (hereafter referred to as the multi-stage flotation column) for fine coal cleaning and other solid-solid separations. The research work will identify the design parameters and their effect on the performance of the separation process. The results of this research will provide a basis for further development of the technology. In the past three months, the efforts focused on project planning and design of test equipment. A description of technical progress is presented.

  11. Nonambulatory cows: Duration of recumbency and quality of nursing care affect outcome of flotation therapy.

    PubMed

    Stojkov, J; Weary, D M; von Keyserlingk, M A G

    2016-03-01

    Cows that are unable or unwilling to stand and remain recumbent for ≥ 12 h are defined as nonambulatory. Care and management of nonambulatory cattle is considered a major animal welfare concern facing the livestock industry, particularly the dairy sector. Flotation therapy has gained interest as a means to promote recovery in nonambulatory cows and is based on the concept that by floating the cow in warm water, secondary pressure damage to muscles and nerves will be reduced. The objective of this study was to assess the physiological responses to stress related to the flotation therapy and to evaluate the effect of recumbency duration and nursing care on the outcome of the flotation therapy. The outcomes of 34 nonambulatory Holstein dairy cows were analyzed after they were subjected to flotation therapy. The duration of recumbency and quality of nursing care provided before initiation of the flotation treatment were assessed based on producer responses to survey questions, and from on-site observations by the researchers. A veterinarian examined all cows before flotation therapy began. The treatment was divided into 5 phases: baseline (before filling), manipulation (placing the cow into the tank), filling (the tank was filled with water), flotation (the cow was confined in the filled tank), and draining (water was removed from the tank). Stress responses to the procedure, excluding the manipulation portion, were assessed using heart rate variability. The high-frequency component (HF normalized units) decreased during the filling and draining phases (2.8 ± 0.2 and 3.1 ± 0.4, respectively) compared with the baseline and floating phase (5.1 ± 0.6 and 4.9 ± 0.3, [corrected] respectively). These results indicate that the stress related to the flotation therapy is greatest during the filling and draining phases of the treatment, when cows likely have to exert increased effort to transition to a standing position. The flotation therapy was less likely to be

  12. Final Report, Distillation Column Flooding Predictor

    SciTech Connect

    George E. Dzyacky

    2003-05-31

    The Flooding Predictor is an advanced process control strategy comprising a patented pattern-recognition methodology that identifies pre-flood patterns discovered to precede flooding events in distillation columns. The grantee holds a U.S. patent on the modeling system. The technology was validated at the Separations Research Program, The University of Texas at Austin under a grant from the U. S. Department of Energy, Inventions & Innovation Program. Distillation tower flooding occurs at abnormally high vapor and/or liquid rates. The loss in tray efficiencies is attributed to unusual behavior of liquid inventories inside the column leading to conditions of flooding of the space in between trays with liquid. Depending on the severity of the flood condition, consequences range from off spec products to equipment damage and tower shutdown. This non-intrusive pattern recognition methodology, processes signal data obtained from existing column instrumentation. Once the pattern is identified empirically, it is modeled and coded into the plant's distributed control system. The control system is programmed to briefly "unload" the tower each time the pattern appears. The unloading takes the form of a momentary reduction in column severity, e.g., decrease bottom temperature, reflux or tower throughput. Unloading the tower briefly at the pre-flood state causes long-term column operation to become significantly more stable - allowing an increase in throughput and/or product purity. The technology provides a wide range of value between optimization and flooding. When a distillation column is not running at capacity, it should be run in such a way ("pushed") that optimal product purity is achieved. Additional benefits include low implementation and maintenance costs, and a high level of console operator acceptance. The previous commercial applications experienced 98% uptime over a four-year period. Further, the technology is unique in its ability to distinguish between different

  13. Accuracy of egg flotation throughout incubation to determine embryo age and incubation day in waterbird nests

    USGS Publications Warehouse

    Ackerman, Joshua T.; Eagles-Smith, Collin A.

    2010-01-01

    Floating bird eggs to estimate their age is a widely used technique, but few studies have examined its accuracy throughout incubation. We assessed egg flotation for estimating hatch date, day of incubation, and the embryo's developmental age in eggs of the American Avocet (Recurvirostra americana), Black-necked Stilt (Himantopus mexicanus), and Forster's Tern (Sterna forsteri). Predicted hatch dates based on egg flotation during our first visit to a nest were highly correlated with actual hatch dates (r = 0.99) and accurate within 2.3 ± 1.7 (SD) days. Age estimates based on flotation were correlated with both day of incubation (r = 0.96) and the embryo's developmental age (r = 0.86) and accurate within 1.3 ± 1.6 days and 1.9 ± 1.6 days, respectively. However, the technique's accuracy varied substantially throughout incubation. Flotation overestimated the embryo's developmental age between 3 and 9 days, underestimated age between 12 and 21 days, and was most accurate between 0 and 3 days and 9 and 12 days. Age estimates based on egg flotation were generally accurate within 3 days until day 15 but later in incubation were biased progressively lower. Egg flotation was inaccurate and overestimated embryo age in abandoned nests (mean error: 7.5 ± 6.0 days). The embryo's developmental age and day of incubation were highly correlated (r = 0.94), differed by 2.1 ± 1.6 days, and resulted in similar assessments of the egg-flotation technique. Floating every egg in the clutch and refloating eggs at subsequent visits to a nest can refine age estimates.

  14. Halo columns: new generation technology for high speed liquid chromatography.

    PubMed

    Ali, Imran; Gaitonde, Vinay D; Grahn, Anders

    2010-01-01

    Fast speed and high sample loading and the pressing demands of industries and researchers are compelling scientists and manufacturers to explore the new horizons in column technology. Recently, superficially porous silica particle columns are manufactured with some salient features such as super fast speed, sharp peaks, good sample loading, and low backpressure. The commercially available columns are Halo (Advanced Material Technology, Wilmington, DE), Express (Supelco, Bellefonte, PA), and Proshell 120 (Agilent, Santa Clara, CA). Halo columns are of C(8), C(18), RP Amide, and HILIC types with 2.7 microm over all diameters, 0.5 microm porous thick layers containing 90 A as pore diameter, and 150 m(2)/g surface area. These columns have been used for fast separation of low molecular weight compounds with some exception for large molecules such as protein, peptides, and DNA. The present article describes the importance of these state-of-the-art superficially porous silica particles based columns with special emphasis on Halo columns. The different aspects of these columns such as structures, mechanism of separations, applications, and comparison, with conventional columns have been discussed.

  15. Industrial use of technologies potentially applicable to the cleaning of slurry pond fines

    SciTech Connect

    Schimmoller, B.K.; Jacobsen, P.S.; Hucko, R.E.

    1994-12-31

    Several advanced technologies have been developed in the past decade that are particularly applicable to the processing of fine-coal streams. The Microcel{trademark} flotation column, the Static Tube flotation column, the Ken-Flote flotation column, the Jameson froth flotation cell, the Deister Flotaire{reg_sign} column flotation cell, the AFT spray flotation process, the Allflot flotation cell, the air-sparged hydrocyclone, and micronized-magnetite beneficiation have all advanced past the experimental stage and await widespread commercial application. One of the principal application opportunities for these technologies may be in the remediation of fine-coal slurry ponds, where millions of tons of fine coal and refuse are discarded annually. This paper discusses the status of development and commercial application of these technologies.

  16. Removal of hydrocarbons from petrochemical wastewater by dissolved air flotation.

    PubMed

    Galil, N I; Wolf, D

    2001-01-01

    The dissolved air flotation (DAF) method has an important role in the removal of hydrocarbons, as well as in the protection of the biological treatment, which usually follows the DAF. The aims of this study were to evaluate the removal efficiencies of suspended solids, general organic matter, hydrocarbons and phenols by DAF, as influenced by the flocculant type, aluminum sulfate (alum) or a cationic polyelectrolyte. Laboratory batch experiments included chemical flocculation followed by DAF, controlling the flocculant dose and the air to solids ratio. The characterization of the influent and effluent was based on general analysis of organic matter (COD), suspended solids, hydrocarbons and phenols. The influent to all experiments was supplied daily from the outlet of a full scale oil-water gravitational separation unit at a petrochemical complex in Haifa, Israel. The influent contained hydrocarbons in the range of 20 to 77 mg/L. Usually less than 10% were found in "free" form, 70 to 80% were emulsified and 10 to 20% were dissolved. The DAF process enabled us to reduce the general hydrocarbon content by 50 to 90%. The effluent was characterized by stable and uniform levels of suspended solids, and oil, almost without depending on the influent concentrations. The results indicate that the chemical flocculation followed by DAF removed efficiently the emulsified phase, which could be aggregated and separated to the surface. However, it was found that the process could also remove substantial amounts of dissolved organic matter. This mechanism could be explained by the hydrophobic characteristics of some of the substances, which could bind to the solid surfaces. It was found that aggregates created by the flocculation with the cationic polyelectrolite (C-577) could remove up to 40% from the dissolved hydrocarbon. Alum flocs also indicated removal of soluble materials, mainly phenols. The results obtained in this study indicated the possibility to improve the protection

  17. Comparison of passive fecal flotation run by veterinary students to zinc-sulfate centrifugation flotation run in a diagnostic parasitology laboratory.

    PubMed

    Gates, Maureen C; Nolan, Thomas J

    2009-10-01

    The sensitivity of fecal examination methods can be influenced by both technician error and methodology. In this analysis, we compared the results of 335 passive fecal flotation examinations performed on the feces of stray dogs by 3rd-yr veterinary students at the University of Pennsylvania, School of Veterinary Medicine, to the results obtained through zinc-sulfate centrifugation performed by the diagnostic parasitology laboratory on the same fecal samples. The students' passive flotation results agreed with the laboratory zinc-sulfate centrifugation for only 62.4% of samples. Students were able to diagnose 75.0% of Ancylostoma caninum cases, 71.4% of Toxocara canis cases, 54.2% of Trichuris vulpis cases, 26.7% of Cystoisospora spp. (C. ohioensis-like and C. canis) cases, and 14.7% of Giardia lamblia cases. There were also 70 instances where students reported the presence of parasites in the sample that were not diagnosed by zinc-sulfate centrifugation. Based on the overall study findings, passive fecal flotation examinations run in private practice could be missing up to 50.5% of infected dogs, due to either technician error or inherent limitations to the passive fecal flotation technique.

  18. REMOVAL OF NONVOLATILE HYDROPHOBIC ORGANIC COMPOUNDS FROM ARTIFICIALLY AND NATURALLY CONTAMINATED SOILS BY COLUMN FLOTATION. (R825511C049)

    EPA Science Inventory

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  19. The lateral column lengthening and medial column stabilization procedures.

    PubMed

    Chi, T D; Toolan, B C; Sangeorzan, B J; Hansen, S T

    1999-08-01

    The results of medial column stabilization, lateral column lengthening, and combined medial and lateral procedures were reviewed in the treatment of adult acquired flatfoot secondary to posterior tibialis tendon insufficiency. All bony procedures were accompanied by transfer of the flexor digitorum longus tendon to the medial cuneiform or stump of the posterior tibialis tendon and tendoachilles lengthening or gastrocnemius recession. Medial column fusion was performed for naviculocuneiform and cuneiform first metatarsal sag; lateral column lengthening was performed for calcaneovalgus deformity with a flat pitch angle; and combined procedures were performed for complex combined deformities. At 1 to 4 year followup of 65 feet, 88% of the feet that had lateral column lengthening, 80% that had medial column stabilization, and 88% of the feet that had medial and lateral procedures had a decrease in pain or were pain free. The lateral talar first metatarsal angle improved by 16 degrees in the patients in the lateral column lengthening group, 20 degrees in the patients in the medial column stabilization group, and 24 degrees in the patients in the combined medial and lateral procedures group. The anteroposterior talonavicular coverage angle improved by 14 degrees in the patients in the lateral column lengthening group, 10 degrees in the patients in the medial column stabilization group, and 14 degrees in the patients in the combined medial and lateral procedures group. These techniques effectively correct deformity without disrupting the essential joints of the hindfoot and midfoot.

  20. Electro-coagulation-flotation process for algae removal.

    PubMed

    Gao, Shanshan; Yang, Jixian; Tian, Jiayu; Ma, Fang; Tu, Gang; Du, Maoan

    2010-05-15

    Algae in surface water have been a long-term issue all over the world, due to their adverse influence on drinking water treatment process as well as drinking water quality. The algae removal by electro-coagulation-flotation (ECF) technology was investigated in this paper. The results indicated that aluminum was an excellent electrode material for algae removal as compared with iron. The optimal parameters determined were: current density=1 mA/cm(2), pH=4-7, water temperature=18-36 degrees C, algae density=0.55 x 10(9)-1.55 x 10(9) cells/L. Under the optimal conditions, 100% of algae removal was achieved with the energy consumption as low as 0.4 kWh/m(3). The ECF performed well in acid and neutral conditions. At low initial pH of 4-7, the cell density of algae was effectively removed in the ECF, mainly through the charge neutralization mechanism; while the algae removal worsened when the pH increased (7-10), and the main mechanism shifted to sweeping flocculation and enmeshment. The mechanisms for algae removal at different pH were also confirmed by atomic force microscopy (AFM) analysis. Furthermore, initial cell density and water temperature could also influence the algae removal. Overall, the results indicated that the ECF technology was effective for algae removal, from both the technical and economical points of view.