Science.gov

Sample records for advanced coal beneficiation

  1. Advanced spectroscopic analysis of coal surfaces during beneficiation

    SciTech Connect

    McClelland, J.F.; Oh, J.S.

    1989-10-01

    Preliminary FTIR spectra are reported on coals undergoing flotation where enhanced recovery was achieved by ultrasonic or chemical treatments. The spectra of sonicated coals indicate that ultrasonic treatment (10 kHz Swen Sonic) reduces the surface oxidation of heavily oxidized coal. Spectra of chemically treated coal indicate that a higher mineral concentration is present on or near the surface of float coal suggesting that a slime might be present. Spectra are reported for coal-, mineral-, and crystal-derived pyrite which show a strong absorbance band at 420 cm{sup {minus}1}. Spectra of eight Argonne Premium Coal Library specimens have been examined in the 420 cm{sup {minus}1} spectral region and are found to have numerous overlapping bands. 4 figs.

  2. Process for beneficiating coal

    SciTech Connect

    Burgess, L.E.; Fox, K.M.; Herman, D.E.; McGarry, P.E.

    1982-06-01

    Mine run coal is pulverized and the extended surfaces of the coal particles are rendered hydrophobic and oilophilic by a chemical bonding and graft polymerization reaction with a water insoluble organic polymerizable monomer under peroxidation influence in a predominantly water reaction medium. The mineral ash present in the coal and particularly the iron pyrites remains hydrophilic and is separated from the polymeric organic surface bonded coal product in a water washing step wherein the washed coal floats on and is recovered from the water phase and the ash is removed with the separated wash water in a critical wash step. Excess water is removed from the beneficiated hydrophobic surface-altered coal product mechanically. The hydrophobic and oilophilic organic polymeric surface bonded coating about the coal particles is fortified by inclusion of additional unbound free fatty acids by further small additions thereof. The carboxylic acid groups present in the coal-oil product are thereafter converted to a metal soap. The beneficiated coal product can be used ''dry,'' or additional quantities of a liquid hydrocarbon fuel can be incorporated with the ''dry'' beneficiated coal product to produce a flowable fluid or liquid coal product having the rheological property of marked thixotropy. Introduction of this physically induced property into the liquid coal-oil-mixture prevents settling out of the heavier coal particles from the relatively ash-free fluid fuel composition under extended storage periods.

  3. Apparatus for beneficiating coal

    SciTech Connect

    Burgess, L.E.; Fox, K.M.; Herman, D.E.; McGarry, P.E.

    1985-08-20

    Mine run coal is pulverized and the extended surfaces of the coal particles are rendered hydrophobic and oilophilic by a chemical bonding and graft polymerization reaction with a water insoluble organic polymerizable monomer under peroxidation influence in a predominantly water reaction medium. The mineral ash present in the coal and particularly the iron pyrites remains hydrophilic and is separated from the polymeric organic surface bonded coal product in a water washing step wherein the washed coal floats on and is recovered from the water phase and the ash is removed with the separated wash water in a critical wash step. Excess water is removed from the beneficiated hydrophobic surface-altered coal product mechanically. The hydrophobic and oilophilic organic polymeric surface bonded coating about the coal particles is fortified by inclusion of additional unbound free fatty acids by further small additions thereof. The carboxylic acid groups present in the coal-oil product are thereafter converted to a metal soap. The beneficiated coal product can be used ''dry'', or additional quantities of a liquid hydrocarbon fuel can be incorporated with the ''dry'' beneficiated coal product to produce a flowable fluid or liquid coal product having the rheological property of marked thixotropy. Introduction of this physically induced property into the liquid coal-oil-mixture prevents settling out of the heavier coal particles from the relatively ash-free fluid fuel composition under extended storage periods.

  4. Coal beneficiation by gas agglomeration

    DOEpatents

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  5. Process of beneficiating coal and product

    SciTech Connect

    Burgess, L.E.; Fox, K.M.; McGarry, P.E.

    1981-12-08

    Mine run coal is pulverized and the extended surfaces of the coal particles are rendered hydrophobic and oilophilic by a chemical bonding and graft polymerization reaction with a water unsoluble organic polymerizable monomer under peroxidation influence in a predominantly water reaction medium. The mineral ash present in the coal, particularly the iron pyrites, remains hydrophilic and is separated from the polymeric organic surface bonded coal product in a water washing step wherein the washed coal floats on and is recovered from the water phase and the ash is removed with the separated wash water in a critical wash step. The hydrophobic and oilophilic organic polymeric surface bonded coating about the coal particles is fortified by inclusion of additional unbound free fatty acids by further small additions thereof. Excess water is removed from the beneficiated hydrophobic surface-altered coal product mechanically, and the carboxylic acid groups present in the coal-oil product are thereafter converted to a metal soap. The beneficiated coal product can be used ''dry'', or additional quantities of a liquid hydrocarbon fuel can be incorporated with the ''dry'' beneficiated coal product to produce a flowable fluid or liquid coal product having the rheological property of marked thixotropy. Introduction of this physically induced property into the liquid coal-oil-mixture prevents settling out of the heavier coal particles from the relatively ash-free fluid fuel composition under extended storage periods.

  6. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Levasseur, A.A.

    1995-11-01

    The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

  7. Enhancement of surface properties for coal beneficiation

    SciTech Connect

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  8. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on Combustion Characterization of Beneficiated Coal-Based Fuels.'' The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE's laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  9. Hydromechanical Advanced Coal Excavator

    NASA Technical Reports Server (NTRS)

    Estus, Jay M.; Summers, David

    1990-01-01

    Water-jet cutting reduces coal dust and its hazards. Advanced mining system utilizes full-face, hydromechanical, continuous miner. Coal excavator uses high-pressure water-jet lances, one in each of cutting heads and one in movable lance, to make cuts across top, bottom and middle height, respectively, of coal face. Wedge-shaped cutting heads advance into lower and upper cuts in turn, thereby breaking coal toward middle cut. Thrust cylinders and walking pads advance excavator toward coal face.

  10. OPTIMIZATION OF COAL BENEFICIATION PLANTS FOR SO2 EMISSIONS CONTROL

    EPA Science Inventory

    The article describes an optimization model for estimating the properties and cost of washed coal from coal beneficiation plants of varying levels of complexity. he design and technical description of the plant performance model are presented, together with cost algorithms for th...

  11. Coal surface control for advanced physical fine coal cleaning technologies

    SciTech Connect

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Bi, H.; Campbell, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.

    1991-01-01

    The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 90% pyrite sulfur rejection at an energy recovery greater than 90% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning, method for analysis of samples, development of standard beneficiation test, grinding studies, modification of particle surface, and exploratory R D and support. 5 refs., 22 figs., 34 tabs.

  12. Enhancement of surface properties for coal beneficiation. Final report

    SciTech Connect

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  13. Coal surface control for advanced physical fine coal cleaning technologies

    SciTech Connect

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  14. Predictions of boiler performance when firing beneficiated coal-based fuels

    SciTech Connect

    Hargrove, M.; Gurvich, B.; Kwasnik, A.; Liljedahl, G.; Miemiec, L.

    1994-12-31

    The development of advanced coal beneficiation and utilization technologies is being sponsored by the United States Department of Energy`s Pittsburgh Energy Technology Center, to encourage the use of our abundant coal reserves. A comprehensive program is being conducted by ABB/Combustion Engineering, Inc. (ABB/CE), regarding the use of these fuels in existing utility boilers. Physical, chemical, combustion and fireside characteristics of these beneficiated products and their parent coals are being evaluated in laboratory testing. Characterization tests provide the information required to predict the performance and economic impacts of firing Beneficiated Coal-Based Fuels (BCF) in existing coal and oil utility boilers. Two utility steam generators designed for either coal or oil firing were selected for performance evaluation. The study units were selected to be representative of a large portion of the current boiler population: a 560 MW coal-designed boiler purchased in 1973; and a 600 MW oil-designed boiler purchased in 1970. Both of these units were built by ABB/CE, but the fuel related design parameters are similar to those used by other manufacturers. An Upper Freeport medium volatile bituminous (mvb) parent coal and its respective Spherical Oil Agglomeration Product (SOAP) fuel were evaluated. This paper summarizes the results of the performance analysis and describes the economic impacts that can be expected when firing BCF`s.

  15. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOEpatents

    Viall, Arthur J.; Richards, Jeff M.

    1999-01-01

    A process for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process.

  16. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOEpatents

    Viall, A.J.; Richards, J.M.

    1999-01-26

    A process is described for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process. 3 figs.

  17. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOEpatents

    Viall, Arthur J.; Richards, Jeff M.

    2000-01-01

    A process for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process.

  18. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 8, January--March 1991

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1991-07-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the third quarter of 1991, the following technical progress was made: Calculated the kinetic characteristics of chars from the combustion of spherical oil agglomeration beneficiated products; continued drop tube devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; and started writing a summary topical report to include all results on the nine fuels tested.

  19. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 9, April--June 1991

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1991-08-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the second quarter of 1991, the following technical progress was made: completed drop tube furnace devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of samples to determine devolatilization kinetics; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; completed writing a summary topical report including all results to date on he nine fuels tested; and presented three technical papers on the project results at the 16th International Conference on Coal & Slurry Technologies.

  20. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 6, July 1990--September 1990

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  1. Hydrophobic flocculation flotation for beneficiating fine coal and minerals

    SciTech Connect

    Song, S.; Valdivieso, A.L.

    1998-06-01

    It is shown that hydrophobic flocculation flotation (HFF) is an effective process to treat finely ground ores and slimes so as to concentrate coal and mineral values at a fine size range. The process is based on first dispersing the fine particles suspension, followed by flocculation of fine mineral values or coal in the form of hydrophobic surfaces either induced by specifically adsorbed surfactants or from nature at the conditioning of the slurry with the shear field of sufficient magnitude. The flocculation is intensified by the addition of a small amount of nonpolar oil. finely ground coals, ilmenite slimes, and gold finely disseminated in a slag have been treated by this process. Results are presented indicating that cleaned coal with low ash and sulfur remaining and high Btu recovery can be obtained, and the refractory ores of ilmenite slimes and fine gold-bearing slag can be reasonably concentrated, leading to better beneficiation results than other separation techniques. In addition, the main operating parameters affecting the HFF process are discussed.

  2. Graphic values for some organic constitutents of beneficiated coal samples

    SciTech Connect

    Kohlenberger, L.B. )

    1992-01-01

    Graphic techniques exist which can accurately predict values for calorific value, organic sulfur, and possibly other constituents of the organic portion of beneficiated coal sample fractions. These techniques also permit a determination of coal rank to be made without the use of the approximations required in the standard procedure. Fractions of IBC-101 with varying ash contents were produced by froth flotation. The various fractions were analyzed by the coal analysis laboratory and the particular data type was plotted in each case vs. the individual ash content of each fraction, using Lotus 123 and Freelace software packages. Such plots for calorific value and organic sulfur have, so far, been made. These curves and the information they contain are discussed in this report. A comparison of the graphic mineral matter value with the usual one calculated from the Parr approximation has been made. Eventually, the data may lead to an effective way to estimate inorganic carbon, hydrogen, nitrogen, and other organic constitents of coal. All data will be made available to researchers.

  3. Effects of coal beneficiation and solvent quality on short contact time liquefaction of bituminous coal

    SciTech Connect

    Not Available

    1984-07-01

    A series of beneficiated coals (Illinois No. 6) from the Burning Star Mine No. 2 were evaluated in a bench scale continuous coal liquefaction unit. These included run-of-mine (22% ash), coal conventionally cleaned at the mine site preparation plant (11% ash), coal cleaned by oil agglomeration (10% ash), and deep-cleaned coal (3% ash). The oil agglomeration technique was of particular interest as it was known to preferentially leave pyrite in the cleaned coal. In short contact time liquefaction, the primary measure of reactivity is conversion to soluble material. In this study, it was found that conversion to soluble material was not correlated with iron content but rather was related to depth of cleaning. The two highest iron content coals, the run-of-mine and oil-agglomerated, exhibited the lowest conversions. Conversion was maximized with the deep-cleaned coal which had the lowest iron content. The oil-agglomerated and conventionally-cleaned coal were of similar ash content; the conventionally-cleaned coal contained less iron but showed an increased conversion compared to the oil-agglomerated coal. In contract to the conversion results, there was a strong correlation between iron in the feed coal and distillate yield. For two-stage processing, quality of the SRC is also of importance. Conversion of preasphaltenes to more soluble materials was maximized with the high iron coals and was minimized with the deep-cleaned coal. More favorable results were obtained with the Lummus solvent but differences between the two solvents were small. 27 references, 4 figures, 6 tables.

  4. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 10, July--September 1991

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1991-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the third quarter of 1991, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; completed analyses of the samples from the pilot-scale ash deposition tests of unweathered Upper Freeport fuels; completed editing of the first three quarterly reports and sent them to the publishing office; presented the project results at the Annual Contractors` Conference.

  5. Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

    DOEpatents

    Sheldon, Ray W.

    2001-01-01

    The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

  6. The influence of additives on coal-water mixtures prepared with beneficiated coal

    SciTech Connect

    Ekmann, J.M.; Wildman, D.J.

    1986-01-01

    Use of coal-water mixtures (CWM) as fuels for utility and industrial applications is currently constrained by a number of factors, including the cost of compliance with environmental quality regulations. From a utilization standpoint, limiting ash and sulfur contents to levels comparable to those for residual fuel oil produces an attractive alternate fuel provided the unit cost is equal to that for the fuel oil. Reduction in the mineral matter content of the coal has been identified as a target for continued development of CWM. Changes in coal type or in the characteristics of a single coal have been shown to affect CWM properties. It appears worthwhile to examine the impact that beneficiation might have on CWM properties.

  7. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 15, October--December 1992

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1993-03-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1992, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; re-analyzed the samples from the pilot-scale ash deposition tests of the first nine feed coals and BCFs using a modified CCSEM technique; updated the topical summary report; and prepared for upcoming tests of new BCFs being produced.

  8. Silicone glycol collectors in the beneficiation of fine coal by froth flotation

    SciTech Connect

    Owen, M.J.

    1985-07-02

    A froth flotation process for the beneficiation of fine coal is disclosed which employs as a collector a water-dispersible polyorganosiloxane or a mixture of water-dispersible polyorganosiloxanes which contain organic radicals selected from the group consisting of polyethylene oxide and polypropylene oxide radicals. The process of this invention is especially useful for the beneficiation of difficult-to-float fine coals.

  9. Heavy-liquid-beneficiation of fine coal, Phase II. Final report

    SciTech Connect

    Simmons, F.J.; Keller, D.V. Jr.

    1984-11-01

    Heavy-Liquid-Beneficiation of Fine Coal is a two-phase multitask fundamental research program directed towards the development of a basic understanding of the rheology of fine-coal/heavy-liquid slurries and the application of this understanding to the development and operation of a heavy-liquid fine-coal benefication pilot test facility using cyclone technology. (HLC)

  10. Evaluation of the effect of solvent modification and coal pretreatment and beneficiation on liquefaction: Final report

    SciTech Connect

    Garg, D.; Miller, R.N.; Hoover, D.S.; Givens, E.N.; Schweighardt, F.K.; Tarrer, A.R.; Guin, J.A.; Curtis, C.W.; Luckie, P.

    1985-03-01

    An extensive research program was conducted to ascertain ways to improve oil yields and process economics of direct coal liquefaction. The effects of removing heteroatoms from the solvent, pretreating coal by several techniques (including solvent extraction, oxidation, grinding, and ion exchange), and beneficiating coal by removing mineral species were investigated in both catalytic and noncatalytic coal liquefaction reactions. Additionally, fundamental studies were carried out to explain the role of heteroatoms in catalytic coal liquefaction. The effects of process variables, catalysts and mode of catalyst addition, solvent properties, and recycle of SRC on oil production and coal conversion were also studied. 9 refs., 12 figs., 72 tabs.

  11. Mulled coal - a beneficiation coal form for use as a fuel or fuel intermediate. Technical progress report No. 10, July 1, 1992--September 30, 1992

    SciTech Connect

    Not Available

    1993-01-01

    Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. During this reporting period the authors have: begun weathering studies on neat mull and source fuel; completed design of integrated continuous process circuit for mull formulations; extended aging studies on various mull formulations; started cost estimates on 100 tph mulling circuit.

  12. Cross flow cyclonic flotation column for coal and minerals beneficiation

    DOEpatents

    Lai, Ralph W.; Patton, Robert A.

    2000-01-01

    An apparatus and process for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophillic tailings.

  13. Coal and coal-bearing strata: recent advances

    SciTech Connect

    Scott, A.C.

    1987-01-01

    This volume contains keynote papers presented at the International Symposium on Coal and Coal-bearing Strata held at the University of London, April 1986. The authors reviewed progress in their fields over the past 15 years. Nine keynote lectures plus seven other invited contributions by experts in geology, geochemistry, sedimentology and biology are included in the volume. Coal, a major fossil fuel, is of broad interest to geologists and technological professionals alike. Topics in this volume include the formation of peat, coalification, coal geochemistry, palaeobotanical and palynological studies, sedimentology, coal exploration, oil-prone coals, and numerous coal basins. This volume is of interest not only to workers in the coal, oil, and gas industries, but also to survey geologists, lecturers, and students alike who are concerned with recent advances in the study of coal and coal-bearing strata.

  14. Electrostatic beneficiation of coal. Quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1996-07-01

    Progress reports are presented for the following: modification to the electrostatic separator; review of DOE specifications for minimum beneficiation and calculations of grinding requirements based on washability; two-pass beneficiation; analysis of different sieve fractions; measurement of charge to mass ratio as a function of height of deposition; and charging of coal against different materials.

  15. Investigation of MCHM transport mechanisms and fate: implications for coal beneficiation.

    PubMed

    He, Y Thomas; Noble, Aaron; Ziemkiewicz, Paul

    2015-05-01

    4-Methyl cyclohexane methanol (MCHM) is a flotation reagent often used in fine coal beneficiation and notably involved in the January 9, 2014 Elk River chemical spill in Charleston, WV. This study investigates the mechanisms controlling the transport and fate of MCHM in coal beneficiation plants and surrounding environments. Processes such as volatilization, sorption, and leaching were evaluated through laboratory batch and column experiments. The results indicate volatilization and sorption are important mechanisms which influence the removal of MCHM from water, with sorption being the most significant removal mechanism over short time scales (<1 h). Additionally, leaching experiments show both coal and tailings have high affinity for MCHM, and this reagent does not desorb readily. Overall, the results from these experiments indicate that MCHM is either volatilized or sorbed during coal beneficiation, and it is not likely to transport out of coal beneficiation plant. Thus, use of MCHM in coal beneficiation plant is not likely to pose threat to either surface or groundwater under normal operating conditions.

  16. Combustion characterization of beneficiated coal-based fuels

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-08-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, conbustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Sciences, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the full-scale tests. Approximately nine BCFs will be in dry ultra-fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  17. Initial study of dry ultrafine coal beneficiation utilizing triboelectric charging with subsequent electrostatic separation

    SciTech Connect

    Link, T.A.; Killmeyer, R.P.; Elstrodt, R.H.; Haden, N.H.

    1990-10-01

    A novel, dry process using electrostatics to beneficiate ultrafine coal is being developed by the Coal Preparation Division at the Pittsburgh Energy Technology Center. The historical concept of triboelectricity and its eventual use as a means of charging coal for electrostatic separation will be discussed. Test data from a first-generation and a second-generation Tribo-Electrostatic separator are presented showing the effects of feed particle size, separator voltage, solids concentration in air, and particle velocity on separation performance. 10 refs., 10 figs., 9 tabs.

  18. Electrostatic beneficiation of coal. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1995-07-01

    A chamber has been set up for exposing ground coal to controlled relative humidities. Four levels in the range of 10% to 95% are planned. The change in moisture content of the coal powders will be determined after exposure. Charge to mass ratio acquired in tribocharging and the degree of electrostatic beneficiation will be determined as a function of the relative humidity used for each of the exposures. The authors also discuss their progress in grinding of the coal; the low percentage of coal recovered after separation and the possibility that these losses were a result of holdup in the expansion cone; the design and modeling of the electric curtain; particle size measurement using image processing; and the petrographic analyses of finely and coarsely ground Illinois No. 6 coal.

  19. Mulled Coal: A beneficiated coal form for use as a fuel or fuel intermediate

    SciTech Connect

    Not Available

    1992-02-01

    This report covers activities from October 1, 1991 to December 31, 1991. During this period we have: Obtained storage and handling system design data for the granular coal; completed the 74-day aging study on various mull formulations to determine the effects of time and exposure on mull properties; demonstrated the continuous production of mulled coal from wet filter cake; demonstrated the continuous production of CWF from mull; and performed atomization studies on Mulled Coal and CWF prepared from Mulled Coal.

  20. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    SciTech Connect

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  1. Mulled coal: A beneficiated coal form for use as a fuel or fuel intermediate

    SciTech Connect

    Not Available

    1992-05-01

    Energy International is developing a technology that will create a staged formulation with the first coal form (Mulled Coal) that can be stored, transported, and pumped. Just prior to combustion, the Mulled Coal (MC) is modified to provide the properties needed for proper atomization. This concept is an alternative to the expensive and energy intensive thermal drying processing of fine coal wetcakes. The material is suitable for both direct feed use in conventional and fluid bed combustors as well as on-site conversion to combustible slurries. By maintaining the coal form relatively close to the feed wetcake, only minor processing with low additive levels and low energy blending is needed at the point of production. Its conversion to slurry or other use-feed form is made near the time of use and thus the requirements for stability, climatic control, and other storage, transport, and handling requirements are much less severe.

  2. COSTS FOR ADVANCED COAL COMBUSTION TECHNOLOGIES

    EPA Science Inventory

    The report gives results of an evaluation of the development status of advanced coal combustion technologies and discusses the preparation of performance and economic models for their application to electric utility plants. he technologies addressed were atmospheric fluidized bed...

  3. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, W.; Zou, Y.; Chen, W. ); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. )

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  4. Heavy-liquid beneficiation of fine coal. First quarterly report, September 18, 1980-December 31, 1980

    SciTech Connect

    Keller, Jr, Douglas V.; Simmons, Frederick J.

    1980-01-01

    The Heavy Liquid Beneficiation of Fine Coal is a fundamental research program directed towards developing a basic understanding of the rheology of fine coal-heavy liquid slurries, and the application of this understanding to the development of a pilot test facility. The tasks scheduled and accomplished in the first quarter were: the selection and characterization of the coal to be used; the design, construction and testing of a dynamic viscosity cell for solid-liquid slurry systems; the selection and evaluation of candidate organic liquids and the determination whether or not one candidate liquid can be taken as representative of the class of liquids; and the ongoing evaluation of the three-dimensional slurry viscosity matrix as generated by coal size fraction, coal density fraction and slurry volume percent solid. The Canterbury Coal is acceptable for the slurry evaluation phase of this program. Freon-113 can be taken as representative of this class of organic liquid and used in the three-dimensional slurry matrix evaluation. The choice of Freon-113 over Freon-11 is a matter of experimental convenience based on the higher boiling point of Freon-113. The dynamic flow viscosity cell as currently designed is capable of generating accurate viscosity data.

  5. TRW advanced slagging coal combustor utility demonstration

    SciTech Connect

    Not Available

    1990-01-01

    The TRW Advanced Entrained Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/oil unit to fire 2.5% sulfur coal. The slagging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Environmental Standards. The TRW-Utility Demonstration Unit (UDU) is responsible for the implementation of program policies and overall direction of the project. The following projects will be carried out: process and design development of clean coal technology CCT-1 the development and operation of the entrained coal combustor will enable the boiler to burn low and medium sulfur coal while meeting all the Federal/State emission requirements; demonstrate sulfur dioxide emissions control by pulverized limestone injection into the entrained coal combustor system.

  6. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Wenglarz, R.A.

    1994-08-01

    Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

  7. Advanced Coal-Based Power Generations

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1982-01-01

    Advanced power-generation systems using coal-derived fuels are evaluated in two-volume report. Report considers fuel cells, combined gas- and steam-turbine cycles, and magnetohydrodynamic (MHD) energy conversion. Presents technological status of each type of system and analyzes performance of each operating on medium-Btu fuel gas, either delivered via pipeline to powerplant or generated by coal-gasification process at plantsite.

  8. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 11, October--December 1991

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1992-03-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of beneficiated coal-based fuels (BCFs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors perform parts of the test work are the Massachusetts Institute of Technology Physical Science, Inc. Technology Company and the University of North Dakota Energy and Environmental Research Center. Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for full-scale tests. Approximately nine BCFs will be in dry ultra fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements. During the third quarter of 1991, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; completed analyses of the samples from the pilot-scale ash deposition tests of three Freeport Pittsburgh 8 fuels; conducted pilot-scale combustion and ash deposition tests of a fresh batch of Upper Freeport parent coal in the CE fireside Performance Test Facility; and completed editing of the fourth quarterly report and sent it to the publishing office.

  9. Controlling air toxics through advanced coal preparation

    SciTech Connect

    Straszheim, W.E.; Buttermore, W.H.; Pollard, J.L.

    1995-11-01

    This project involves the assessment of advanced coal preparation methods for removing trace elements from coal to reduce the potential for air toxic emissions upon combustion. Scanning electron microscopy-based automated image analysis (SEM-AIA) and advanced washability analyses are being applied with state-of-the-art analytical procedures to predict the removal of elements of concern by advanced column flotation and to confirm the effectiveness of preparation on the quality of quantity of clean coal produced. Specific objectives are to maintain an acceptable recovery of combustible product, while improving the rejection of mineral-associated trace elements. Current work has focused on determining conditions for controlling column flotation system across its operating range and on selection and analysis of samples for determining trace element cleanability.

  10. Air-dense medium fluidized bed dry beneficiation of coal: Results of 50 MTPH demonstration plant

    SciTech Connect

    Chen Qingru; Yang Yi; Liang Chuncheng; Tao Xiuxiang; Luo Zhenfu

    1993-12-31

    This paper presents the performance results of the 50 MTPH Coal Dry Beneficiation Demonstration Plant constructed in the Heilongjiang Province of northeastern China. The separating media used in this process consists of an air/dense medium (magnetite, or magnetic pearls, a remnant of coal combustion in power plants) fluidized bed controllable at specific gravities ranging from 1.3 to 2.0. That portion of the feedstock with a specific gravity less than the separating gravity floats to the top of the fluidized bed where it is recovered at one end of the vessel. That portion of the feedstock with a specific gravity higher than the separating gravity sinks and is discharged from the other end of the vessel. The process has separating efficiencies similar to a heavy media vessel or cyclone with the additional advantages of (1) can be utilized in an arid region containing insufficient water supply, (2) results in a dry product requiring no additional dewatering and coal slime treatment, and (3) as result of air flow will remove some surface moisture present in the feedstock. As a result of the magnetite used in the fluidized bed and the subsequent downstream recovery of this magnetite, the current demonstration plant utilizes a 6mm bottom size. The topsize of the feed is a function of the size of the system and the site specific ash liberation requirement. The Demonstration Plant commenced operation in September 1992. The mechanical processes of the system including coal feeding, sizing, gravity separation/beneficiation, and medium recovery, functioned as anticipated from the 10 MTPH pilot plant. Preliminary results with separating gravities in the range of 1.3--2.0 showed a probable error as low as 0.05 with magnetite losses of 0.5 kg/MT of feed.

  11. Advanced direct coal liquefaction concepts

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L. )

    1992-01-01

    During the first quarter of FY 1993, the Project proceeded close to the Project Plan. The analysis of the feed material has been completed as far as possible. Some unplanned distillation was needed to correct the boiling range of the Black Thunder solvent used during the autoclave tests. Additional distillation will be required if the same solvent is to be used for the bench unit tests. A decision on this is still outstanding. The solvent to be used with Illinois No. 6 coal has not yet been defined. As a result, the procurement of the feed and the feed analysis is somewhat behind schedule. Agglomeration tests with Black Thunder coal indicates that small agglomerates can be formed. However, the ash removal is quite low (about 10%), which is not surprising in view of the low ash content of the coal. The first series of autoclave tests with Black Thunder coal was completed as planned. Also, additional runs are in progress as repeats of previous runs or at different operating conditions based on the data obtained so far. The results are promising indicating that almost complete solubilization (close to 90%) of Black Thunder coal can be achieved in a CO/H[sub 2]O environment at our anticipated process conditions. The design of the bench unit has been completed. In contrast to the originally planned modifications, the bench unit is now designed based on a computerized control and data acquisition system. All major items of equipment have been received, and prefabrication of assemblies and control panels is proceeding on schedule. Despite a slight delay in the erection of the structural steel, it is anticipated that the bench unit will be operational at the beginning of April 1993.

  12. Moving baseline for evaluation of advanced coal-extraction systems

    SciTech Connect

    Bickerton, C.R.; Westerfield, M.D.

    1981-04-15

    This document reports results from the initial effort to establish baseline economic performance comparators for a program whose intent is to define, develop, and demonstrate advanced systems suitable for coal resource extraction beyond the year 2000. Systems used in this study were selected from contemporary coal mining technology and from conservative conjectures of year 2000 technology. The analysis was also based on a seam thickness of 6 ft. Therefore, the results are specific to the study systems and the selected seam thickness. To be more beneficial to the program, the effort should be extended to other seam thicknesses. This document is one of a series which describe systems level requirements for advanced underground coal mining equipment. Five areas of performance are discussed: production cost, miner safety, miner health, environmental impact, and recovery efficiency. The projections for cost and production capability comprise a so-called moving baseline which will be used to assess compliance with the systems requirement for production cost. Separate projections were prepared for room and pillar, longwall, and shortwall technology all operating under comparable sets of mining conditions. This work is part of an effort to define and develop innovative coal extraction systems suitable for the significant resources remaining in the year 2000.

  13. Development and scale-up of particle agglomeration processes for coal beneficiation

    NASA Astrophysics Data System (ADS)

    Shen, Meiyu

    The development of two modified agglomeration processes for coal beneficiation is presented separately in Parts I and II of this dissertation. Part I is based on research which was conducted to study the mechanism and characteristics of a gas-promoted oil agglomeration process. Part II is based on research which was carried out to develop a newer and more innovative method for agglomerating coal particles with microscopic gas bubbles in aqueous suspensions. In Part I, the development of a gas-promoted oil agglomeration process for cleaning coal was carried out with scale model mixing systems in which aqueous suspensions of ultrafine coal particles were treated with a liquid hydrocarbon and a small amount of air. The resulting agglomerates were recovered by screening. During batch agglomeration tests the progress of agglomeration was monitored by observing changes in agitator torque in the case of concentrated suspension. A key parameter turned out to be the minimum time te required to produce compact spherical agglomerates. Other important parameters included the projected area mean particle diameter of the agglomerates recovered at the end of a test as well as the ash content and yield of agglomerates. Batch agglomeration tests were conducted with geometrically similar mixing tanks which ranged in volume from 0.346 to 11.07 liters. It was shown that gas bubbles trigger the process of agglomeration and participate in a very complex mechanism involving the interaction of particles, oil droplets, and gas bubbles. The process takes place in stages involving dispersion of oil and gas, flocculation, coagulation, and agglomerate building. Numerous agglomeration tests were conducted with two kinds of coal in concentrated suspensions to determine the important characteristics of the process and to study the effects of the following operating parameters: i-octane concentration, air concentration, particle concentration, tank diameter, impeller diameter, and impeller speed

  14. Advanced clean coal utilization technologies

    SciTech Connect

    Moritomi, Hiroshi

    1993-12-31

    The most important greenhouse gas is CO{sub 2} from coal utilization. Ways of mitigating CO{sub 2} emissions include the use of alternative fuels, using renewable resources and increasing the efficiency of power generation and end use. Adding to such greenhouse gas mitigation technologies, post combustion control by removing CO{sub 2} from power station flue gases and then storing or disposing it will be available. Although the post combustion control have to be evaluated in a systematic manner relating them to whether they are presently available technology, to be available in the near future or long term prospects requiring considerable development, it is considered to be a less promising option owing to the high cost and energy penalty. By contrast, abatement technologies aimed at improving conversion efficiency or reducing energy consumption will reduce emissions while having their own commercial justification.

  15. Advanced systems for producing superclean coal

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1990-08-01

    The purpose of this project was to develop several advanced separation processes for producing superclean coal containing 0.4--2.0% ash and very little pyritic sulfur. Three physical and physico-chemical processes were studied: microbubble flotation, selective hydrophobic coagulation, and electrochemical coal cleaning. Information has been collected from bench-scale experiments in order to determine the basic mechanisms of all three processes. Additionally, because microbubble flotation has already been proven on a bench scale, preliminary scale-up models have been developed for this process. A fundamental study of the electrochemistry of coal pyrite has also been conducted in conjunction with this scale-up effort in order to provide information useful for improving sulfur rejection. The effects of additives (NaCl and kerosene) were also investigated. 94 refs., 167 figs., 25 tabs.

  16. Assessment of advanced coal gasification processes

    NASA Technical Reports Server (NTRS)

    Mccarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-01-01

    A technical assessment of the following advanced coal gasification processes is presented: high throughput gasification (HTG) process; single stage high mass flux (HMF) processes; (CS/R) hydrogasification process; and the catalytic coal gasification (CCG) process. Each process is evaluated for its potential to produce synthetic natural gas from a bituminous coal. Key similarities, differences, strengths, weaknesses, and potential improvements to each process are identified. The HTG and the HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging, and syngas as the initial raw product gas. The CS/R hydrogasifier is also SRT, but is nonslagging and produces a raw gas high in methane content. The CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier.

  17. Cultural hitchhiking on the wave of advance of beneficial technologies.

    PubMed

    Ackland, Graeme J; Signitzer, Markus; Stratford, Kevin; Cohen, Morrel H

    2007-05-22

    The wave-of-advance model was introduced to describe the spread of advantageous genes in a population. It can be adapted to model the uptake of any advantageous technology through a population, such as the arrival of neolithic farmers in Europe, the domestication of the horse, and the development of the wheel, iron tools, political organization, or advanced weaponry. Any trait that preexists alongside the advantageous one could be carried along with it, such as genetics or language, regardless of any intrinsic superiority. Decoupling of the advantageous trait from other "hitchhiking" traits depends on its adoption by the preexisting population. Here, we adopt a similar wave-of-advance model based on food production on a heterogeneous landscape with multiple populations. Two key results arise from geographic inhomogeneity: the "subsistence boundary," land so poor that the wave of advance is halted, and the temporary "diffusion boundary" where the wave cannot move into poorer areas until its gradient becomes sufficiently large. At diffusion boundaries, farming technology may pass to indigenous people already in those poorer lands, allowing their population to grow and resist encroachment by farmers. Ultimately, this adoption of technology leads to the halt in spread of the hitchhiking trait and establishment of a permanent "cultural boundary" between distinct cultures with equivalent technology. PMID:17517663

  18. Health requirements for advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Zimmerman, W. F.

    1980-01-01

    Health requirements were developed as long range goals for future advanced coal extraction systems which would be introduced into the market in the year 2000. The goal of the requirements is that underground coal miners work in an environment that is as close as possible to the working conditions of the general population, that they do not exceed mortality and morbidity rates resulting from lung diseases that are comparable to those of the general population, and that their working conditions comply as closely as possible to those of other industries as specified by OSHA regulations. A brief technique for evaluating whether proposed advanced systems meet these safety requirements is presented, as well as a discussion of the costs of respiratory disability compensation.

  19. Advanced Coal Wind Hybrid: Economic Analysis

    SciTech Connect

    Phadke, Amol; Goldman, Charles; Larson, Doug; Carr, Tom; Rath, Larry; Balash, Peter; Yih-Huei, Wan

    2008-11-28

    Growing concern over climate change is prompting new thinking about the technologies used to generate electricity. In the future, it is possible that new government policies on greenhouse gas emissions may favor electric generation technology options that release zero or low levels of carbon emissions. The Western U.S. has abundant wind and coal resources. In a world with carbon constraints, the future of coal for new electrical generation is likely to depend on the development and successful application of new clean coal technologies with near zero carbon emissions. This scoping study explores the economic and technical feasibility of combining wind farms with advanced coal generation facilities and operating them as a single generation complex in the Western US. The key questions examined are whether an advanced coal-wind hybrid (ACWH) facility provides sufficient advantages through improvements to the utilization of transmission lines and the capability to firm up variable wind generation for delivery to load centers to compete effectively with other supply-side alternatives in terms of project economics and emissions footprint. The study was conducted by an Analysis Team that consists of staff from the Lawrence Berkeley National Laboratory (LBNL), National Energy Technology Laboratory (NETL), National Renewable Energy Laboratory (NREL), and Western Interstate Energy Board (WIEB). We conducted a screening level analysis of the economic competitiveness and technical feasibility of ACWH generation options located in Wyoming that would supply electricity to load centers in California, Arizona or Nevada. Figure ES-1 is a simple stylized representation of the configuration of the ACWH options. The ACWH consists of a 3,000 MW coal gasification combined cycle power plant equipped with carbon capture and sequestration (G+CC+CCS plant), a fuel production or syngas storage facility, and a 1,500 MW wind plant. The ACWH project is connected to load centers by a 3,000 MW

  20. Coal and Coal Constituent Studies by Advanced EMR Techniques

    SciTech Connect

    Alex I. Smirnov; Mark J. Nilges; R. Linn Belford; Robert B. Clarkson

    1998-03-31

    Advanced electronic magnetic resonance (EMR) methods are used to examine properties of coals, chars, and molecular species related to constituents of coal. We have achieved substantial progress on upgrading the high field (HF) EMR (W-band, 95 GHz) spectrometers that are especially advantageous for such studies. Particularly, we have built a new second W-band instrument (Mark II) in addition to our Mark I. Briefly, Mark II features: (i) an Oxford custom-built 7 T superconducting magnet which is scannable from 0 to 7 T at up to 0.5 T/min; (ii) water-cooled coaxial solenoid with up to ±550 G scan under digital (15 bits resolution) computer control; (iii) custom-engineered precision feed-back circuit, which is used to drive this solenoid, is based on an Ultrastab 860R sensor that has linearity better than 5 ppm and resolution of 0.05 ppm; (iv) an Oxford CF 1200 cryostat for variable temperature studies from 1.8 to 340 K. During this grant period we have completed several key upgrades of both Mark I and II, particularly microwave bridge, W-band probehead, and computer interfaces. We utilize these improved instruments for HF EMR studies of spin-spin interaction and existence of different paramagnetic species in carbonaceous solids.

  1. Advanced Coal Conversion Process Demonstration Project

    SciTech Connect

    Not Available

    1992-04-01

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  2. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Ohene, F.

    1996-02-01

    The overall objective of this project is to perform experiments to understand the effect of coal beneficiation processes and high shear rheological properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the high shear rheological properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS.

  3. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Quarterly progress report, January 1--March 30, 1995

    SciTech Connect

    Ohene, F.

    1995-12-31

    The overall objective of this project is to perform experiments to understand the effect of coal beneficiation processes and high shear rheological properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the high shear rheological properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS. Results on the rheological evaluation of CWS are presented.

  4. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Quarterly progress report, May 1, 1993--July 31, 1993

    SciTech Connect

    Ohene, F.

    1994-09-01

    The overall objective of this project is to perform experiments to understand the effect of coal beneficiation processes and high shear rheological properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to-CWS. A correlation between the high shear rheological properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS.

  5. Advanced bioreactor concepts for coal processing

    SciTech Connect

    Scott, C.D.

    1988-01-01

    The development of advanced bioreactor systems for the processing of coal should follow some basic principles. Continuous operation is preferred, with maximum bioreagent concentrations and enhanced mass transfer. Although conventional stirred-tank bioreactors will be more appropriate for some processing concepts, columnar reactors with retained bioreagents could be the system of choice for most of the applications. Serious consideration must now be given to process development of some biological coal processing concepts. Process biology and biochemistry will continue to be very important, but efficient bioreactor systems will be necessary for economic feasibility. Conventional bioreactor concepts will be useful for some applications, but columnar systems represent an innovative approach to the design of continuous bioreactors with high productivity and good operational control. Fluidized and packed beds are the most promising configurations, especially where three-phase operation is required and where interphase mass transport is a likely controlling mechanism. Although the biocatalyst must be immobilized into or onto particles to be retained in the bioreactors, this also results in a very high biocatalyst concentration without washout and a significant enhancement in bioconversion rates. The multistage nature of these types of bioreactors also contributes to higher efficiencies for many types of biocatalytic processes. 25 refs.

  6. Advanced Coal-Fueled Gas Turbine Program

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  7. Graphic values for some organic constituents of beneficiated coal samples. [Final] technical report, September 1, 1991--August 31, 1992

    SciTech Connect

    Kohlenberger, L.B.; Lytle, J.M.; Kruse, C.W.; Chaven, C.

    1992-12-31

    Graphic techniques exist which can accurately predict values for calorific value, organic sulfur, and several other constituents of the organic portion of beneficiated coal sample fractions. These techniques also permit a determination of coal rank to be made without the use of approximations required in the standard procedure. In beneficiation studies, plots of the calorific value of each fraction vs its ash content invariably produce straight lines. The Y axis intercept is the mineral-matter-free Btu value used (on the moist basis) to determine coal rank, and the X axis intercept is a value we will call ``maximum ash.`` These two constants permit us to calculate all future Btu values of fractions of this coal from the ash, alone. Plots of organic sulfur vs ash sometimes produce lines which are straight and at other times curved. In any event, they can be used to read off values of organic sulfur corresponding to a particular ash value in lieu of analyses. When all values truly represent only organic sulfur, the X axis intercept must occur at the same maximum ash value obtained from the Btu/ash curve. When the line is straight, the Y axis intercept is the mineral-matter-free organic sulfur, and all future organic sulfur values may be calculated from these two constants and the ash. Fractions of IBC-101 with varying ash contents were produced by froth flotation. The various fractions were analyzed by the coal analysis laboratory and the particular data type was plotted in each case vs the individual ash content of each fraction, using Lotus 123 and Freelance software packages. These plots permit more accurate determination of mineral matter, Btu, organic sulfur, and organic and inorganic carbon, hydrogen, nitrogen, and volatile matter. This information represents a more complete knowledge of coal. In addition, the plots permit accurate estimation of these values from ash and total sulfur analyses alone and thus can save time and analytical expense.

  8. Advanced Coal Conversion Process Demonstration: A DOE Assessment

    SciTech Connect

    National Energy Technology Laboratory

    2005-04-01

    The objective of this project was to demonstrate a process for upgrading subbituminous coal by reducing its moisture and sulfur content and increasing its heating value using the Advanced Coal Conversion Process (ACCP) unit. The ACCP unit, with a capacity of 68.3 tons of feed coal per hour (two trains of 34 tons/hr each), was located next to a unit train loading facility at WECo's Rosebud Coal Mine near Colstrip, Montana. Most of the coal processed was Rosebud Mine coal, but several other coals were also tested. The SynCoal® produced was tested both at utilities and at several industrial sites. The demonstration unit was designed to handle about one tenth of the projected throughput of a commercial facility.

  9. Mulled coal: A beneficiated coal form for use as a fuel or fuel intermediate. Phase 2 system demonstration

    SciTech Connect

    Not Available

    1992-05-01

    Energy International is developing a technology that will create a staged formulation with the first coal form (Mulled Coal) that can be stored, transported, and pumped. Just prior to combustion, the Mulled Coal (MC) is modified to provide the properties needed for proper atomization. This concept is an alternative to the expensive and energy intensive thermal drying processing of fine coal wetcakes. The material is suitable for both direct feed use in conventional and fluid bed combustors as well as on-site conversion to combustible slurries. By maintaining the coal form relatively close to the feed wetcake, only minor processing with low additive levels and low energy blending is needed at the point of production. Its conversion to slurry or other use-feed form is made near the time of use and thus the requirements for stability, climatic control, and other storage, transport, and handling requirements are much less severe.

  10. ADVANCED SOLIDS NMR STUDIES OF COAL STRUCTURE AND CHEMISTRY

    SciTech Connect

    1998-03-01

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utilization of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. The main activity during this granting period was a detailed comparative analysis of the suite of spectral editing results obtained on the Argonne coals. We have extended our fitting procedure to include carbons of all types in the analysis.

  11. Coal surface control for advanced physical fine coal cleaning technologies

    SciTech Connect

    Morsi, B.I.; Chiang, S-H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Venkatadri, R.; Bi, H.; Campbell, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.

    1990-01-01

    Research continued on surface control of coal. This report describes Task 7 of the program. The following topics are discussed: quantitative distribution of iron species; surface functional groups; comparison of wet and dry ground samples; study of Illinois No. 6 coal wet ground using additives; study of wet grinding using tall oil; elemental distribution of coal samples wet ground without additives; elemental distribution of coal samples wet ground with tall oil; direct determination of pyrite by x-ray diffraction; electron microprobe measurements; morphology; zeta potential measurements; pyrite size distribution; statistical analysis of grinding study data; grinding using N-pentane; cyclohexane, and N-heptane; study of the effects of the grinding method and time; study of the effects of the agglomeration time; and the pentane to coal ratio. 13 refs.

  12. Advances in the shell coal gasification process

    SciTech Connect

    Doering, E.L.; Cremer, G.A.

    1995-12-31

    The Shell Coal Gasification Process (SCGP) is a dry-feed, oxygen-blown, entrained flow coal gasification process which has the capability to convert virtually any coal or petroleum coke into a clean medium Btu synthesis gas, or syngas, consisting predominantly of carbon monoxide and hydrogen. In SCGP, high pressure nitrogen or recycled syngas is used to pneumatically convey dried, pulverized coal to the gasifier. The coal enters the gasifier through diametrically opposed burners where it reacts with oxygen at temperatures in excess of 2500{degrees}F. The gasification temperature is maintained to ensure that the mineral matter in the coal is molten and will flow smoothly down the gasifier wall and out the slag tap. Gasification conditions are optimized, depending on coal properties, to achieve the highest coal to gas conversion efficiency, with minimum formation of undesirable byproducts.

  13. Graphic values for some organic constituents of beneficiated coal samples. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect

    Kohlenberber, L.B.; Lytle, J.M.; Kruse, C.W.; Chaven, C.

    1992-10-01

    Graphic techniques exist which can accurately predict values for calorific value, organic sulfur, and several other constituents of the organic portion of beneficiated coal sample fractions. These techniques also permit a determination of coal rank to be made without the use of approximations required in the standard procedure. In beneficiation studies, plots of the calorific value of each fraction vs its ash content invariably produce straight lines. The Y axis intercept is the mineral-matter-free Btu value used (on the moist basis) to determine coal rank and the X axis intercept is a value we will call ``maximum ash.`` These two constants permit us to calculate all future Btu values of fractions of this coal from the ash, alone. Plots of organic sulfur vs ash sometimes produce lines which are straight and at other times curved. In any event, they can be used to read off values of organic sulfur corresponding to a particular ash value in lieu of analyses. When all values truly represent only organic sulfur, the X axis intercept must occur at the same maximum ash value obtained from the Btu/ash curve. When the line is straight, the Y axis intercept is the mineral-matter-free organic sulfur, and all future organic sulfur values may be calculated from these 2 constants and the ash. Fractions of IBC-101 with varying ash contents were produced by froth flotation. The various fractions were analyzed by the coal analysis laboratory and the particular data type was plotted in each case vs the individual ash content of each fraction, using Lotus 123 and Freelance software packages. Such plots for calorific value and organic sulfur have, so far, been discussed in the second quarterly report. A comparison of the graphic mineral matter value with the usual one calculated from the Parr approximation was also discussed in that report. In this third quarterly report we examine the curves for volatiles, fixed carbon, total carbon, total hydrogen, and nitrogen vs ash.

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques

    SciTech Connect

    Curtis, C.W. ); Gutterman, C. ); Chander, S. )

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  15. Graphic values for some organic constitutents of beneficiated coal samples. [Quarterly] report, December 1, 1991--February 29, 1992

    SciTech Connect

    Kohlenberger, L.B.

    1992-08-01

    Graphic techniques exist which can accurately predict values for calorific value, organic sulfur, and possibly other constituents of the organic portion of beneficiated coal sample fractions. These techniques also permit a determination of coal rank to be made without the use of the approximations required in the standard procedure. Fractions of IBC-101 with varying ash contents were produced by froth flotation. The various fractions were analyzed by the coal analysis laboratory and the particular data type was plotted in each case vs. the individual ash content of each fraction, using Lotus 123 and Freelace software packages. Such plots for calorific value and organic sulfur have, so far, been made. These curves and the information they contain are discussed in this report. A comparison of the graphic mineral matter value with the usual one calculated from the Parr approximation has been made. Eventually, the data may lead to an effective way to estimate inorganic carbon, hydrogen, nitrogen, and other organic constitents of coal. All data will be made available to researchers.

  16. Advanced Hydrogen Transport Membrane for Coal Gasification

    SciTech Connect

    Schwartz, Joseph; Porter, Jason; Patki, Neil; Kelley, Madison; Stanislowski, Josh; Tolbert, Scott; Way, J. Douglas; Makuch, David

    2015-12-23

    A pilot-scale hydrogen transport membrane (HTM) separator was built that incorporated 98 membranes that were each 24 inches long. This separator used an advanced design to minimize the impact of concentration polarization and separated over 1000 scfh of hydrogen from a hydrogen-nitrogen feed of 5000 scfh that contained 30% hydrogen. This mixture was chosen because it was representative of the hydrogen concentration expected in coal gasification. When tested with an operating gasifier, the hydrogen concentration was lower and contaminants in the syngas adversely impacted membrane performance. All 98 membranes survived the test, but flux was lower than expected. Improved ceramic substrates were produced that have small surface pores to enable membrane production and large pores in the bulk of the substrate to allow high flux. Pd-Au was chosen as the membrane alloy because of its resistance to sulfur contamination and good flux. Processes were developed to produce a large quantity of long membranes for use in the demonstration test.

  17. ADVANCED SOLIDS NMR STUDIES OF COAL STRUCTURE AND CHEMISTRY

    SciTech Connect

    1997-09-01

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utilization of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. The main activity during this granting period was a completion of a detailed comparative analysis of the suite of spectral editing techniques developed in our laboratory for this purpose. The appended report is a manuscript being submitted to the Journal of Magnetic Resonance on this subject.

  18. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S. Brigham Young Univ., Provo, UT )

    1991-01-01

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This program will merge significant advances made in measuring and quantitatively describing the mechanisms in coal conversion behavior. Comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors.

  19. Advanced coal technologies in Czech heat and power systems

    SciTech Connect

    Noskievic, P.; Ochodek, T.

    1998-04-01

    Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently necessary steps in making coal utilisation more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. Preparatory steps have been taken in building an advanced combustion unit fuelled by pulverised coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper then coal) do not oblige to increase efficiency of the standing equipment applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalisation of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in near future.

  20. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Quarterly progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    Ohene, F.

    1996-10-01

    The overall objective of this project is to perform experiments to understand the effect of coal beneficiation processes and high shear rheological properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the high shear rheological properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS. The viscoelastic behavior of several concentrations of the slurries under study: Heavy Cleaned, Flotation Cleaned and Uncleaned samples were measured. The results obtained will be correlated with the atomization data. The effect of the viscoelastic property on the atomization is being investigated further, and the results will be reported in the final report.

  1. Carbon cycle in advanced coal chemical engineering.

    PubMed

    Yi, Qun; Li, Wenying; Feng, Jie; Xie, Kechang

    2015-08-01

    This review summarizes how the carbon cycle occurs and how to reduce CO2 emissions in highly efficient carbon utilization from the most abundant carbon source, coal. Nowadays, more and more attention has been paid to CO2 emissions and its myriad of sources. Much research has been undertaken on fossil energy and renewable energy and current existing problems, challenges and opportunities in controlling and reducing CO2 emission with technologies of CO2 capture, utilization, and storage. The coal chemical industry is a crucial area in the (CO2 value chain) Carbon Cycle. The realization of clean and effective conversion of coal resources, improving the utilization and efficiency of resources, whilst reducing CO2 emissions is a key area for further development and investigation by the coal chemical industry. Under a weak carbon mitigation policy, the value and price of products from coal conversion are suggested in the carbon cycle.

  2. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F.; Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C.; Hu, W.; Zou, Y.; Chen, W.; Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R.

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  3. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 5, May 1990--June 1990

    SciTech Connect

    Chow, O.K.; Nsakala, N.Y.

    1990-08-01

    The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, conbustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Sciences, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the full-scale tests. Approximately nine BCFs will be in dry ultra-fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  4. Materials of construction for advanced coal conversion systems

    SciTech Connect

    Nangia, V.K.

    1982-01-01

    This book describes materials of construction, and materials problems for equipment used in advanced coal conversion systems. The need for cost effective industrial operation is always a prime concern, particularly in this age of energy consciousness. Industry is continually seeking improved materials for more efficient systems. The information presented here is intended to be of use in the design and planning of these systems. Coal conversion and utilization impose severe demands on construction materials because of high temperature, high pressure, corrosive/erosive, and other hostile environmental factors. Successful economic development of these processes can be achieved only to the extent that working materials can withstand increasingly more aggressive operating conditions. The book, which reviews present and past work on the behavior of materials in the environments of advanced coal conversion systems, is divided into three parts: atmospheric fluidized bed combustion, coal gasification and liquefaction, and advanced power systems.

  5. Advanced coal liquefaction research: Final report

    SciTech Connect

    Gall, W.; McIlvried, H.G. III

    1988-07-01

    This study had two objectives: (1) To enhance the fundamental understanding of observed differences in the short contact time, donor solvent liquefaction of bituminous and subbituminous coals. (2) To determine if physical refining of subbituminous coals could be used to give a better feedstock for the first stage of two-stage liquefaction processes. Liquefaction studies using microautoclaves were carried out. Results are discussed. 11 refs., 25 figs., 29 tabs.

  6. A combined physical/microbial process for the beneficiation of coal

    SciTech Connect

    Andrews, G.F.; Stevens, C.J.; Noah, K.S.; McIlwain, M.E.

    1993-09-01

    A large-laboratory scale physical/microbial process was demonstrated for the removal of pyritic sulfur from coal. The process took place in an aerated-trough slurry reactor with a total slurry volume of 150 L. The reactor was divided into six sections, each of which acted as a physical separator and a bioreactor. The process objective was to physically remove the larger pyritic inclusions and to biodegrade the small inclusions (micropyrite). The process was continuously operated for 120 days, treating approximately 1 ton of Illinois {number_sign}6 coal. Ninety percent pyrite removal was achieved at a 20% slurry concentration and a reactor residence time of 5 days. Additional research should be performed to find the optimum values for reactor residence time, slurry concentration, and process hydraulic residence time (or recycle ratio). Finding these optimum values will enable a process to be developed that will maximize the amount of coal that can be processed per unit reactor volume per unit time with the desired level of pyritic sulfur removal.

  7. Resource targets for advanced underground coal extraction systems

    NASA Technical Reports Server (NTRS)

    Hoag, J. H.; Whipple, D. W.; Habib-Agahi, H.; Lavin, M. L.

    1982-01-01

    Resource targets appropriate for federal sponsorship of research and development of advanced underground coal mining systems are identified. A comprehensive examination of conventional and unconventional coals with particular attention to exceptionally thin and thick seams, steeply dipping beds, and multiple seam geometry was made. The results indicate that the resource of primary importance is flat lying bituminous coal of moderate thickness, under moderate cover, and located within the lower 48 states. Resources of secondary importance are the flat lying multiple seams and thin seams (especially those in Appalachia). Steeply dipping coals, abandoned pillars, and exceptionally thick western coals may be important in some regions of subregions, but the limited tonnage available places them in a position of tertiary importance.

  8. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect

    B. K. Parekh; D. P. Patil

    2008-04-30

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake

  9. A moving baseline for evaluation of advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Bickerton, C. R.; Westerfield, M. D.

    1981-01-01

    Results from the initial effort to establish baseline economic performance comparators for a program whose intent is to define, develop, and demonstrate advanced systems suitable for coal resource extraction beyond the year 2000 are reported. Systems used were selected from contemporary coal mining technology and from conservation conjectures of year 2000 technology. The analysis was also based on a seam thickness of 6 ft. Therefore, the results are specific to the study systems and the selected seam extended to other seam thicknesses.

  10. Genetic manipulation of acidophilic bacteria which are potentially applicable in coal beneficiation

    SciTech Connect

    Roberto, F.F.; Glenn, A.W.; Bulmer, D.; Bruhn, D.F.; Ward, T.E.

    1991-01-01

    The economic and practical aspects of a biological coal desulfurization process are the subject of increasing study. Depyritization of coal by the bacterium Thiobacillus ferrooxidans has been known for some time and pilot scale experiments are underway. A number of limitations have already been recognized for this process, foremost of which is the speed with which the microorganisms grow and attack the pyritic sulfur. Metal toxicity and mass transfer dynamics also present formidable hurdles. Removal of organic sulfur substituents poses even more difficult problems at this time, not least of which is the leak of efficient candidate organisms. Potential candidates at this time resemble members of the Psedomonadaceae, common environmental bacteria. The various limitations in the microorganisms being examined for a viable desulfurization process have led us to initiate studies on the extension of molecular genetic techniques to acidophilic bacteria, with an ultimate goal of introducing desirable characteristics for desulfurization (enhanced growth rate, metal resistance, biochemical capacity to degrade organic sulfur) either directly into T. ferrooxidans, or, alternatively, into a heterotrophic acidophile which can coexist in the same environment as T. ferrooxidans. We are focusing on members of the genus Acidiphilium, one such acidophilic heterotroph. 22 refs., 1 fig., 2 tabs.

  11. Advanced coal technologies in Czech heat and power systems

    SciTech Connect

    Noskievic, P. Ochodek, T.

    1998-07-01

    Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently, necessary steps in making coal utilization more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. preparatory steps have been taken in building an advanced combustion unit fueled by pulverized coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper than coal) do not result in an increased efficiency of the standing equipment by applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalization of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in the near future.

  12. Advanced coal liquefaction research. Quarterly technical progress report, January 1-March 31, 1983

    SciTech Connect

    Not Available

    1983-12-01

    This report describes progress on the Advanced Coal Liquefaction project by the Gulf Research and Development Company's Merriam Laboratory during the months of January through March 1983. The liquefaction behavior of Illinois No. 6 coal beneficiated in various ways was studied in both single-stage recycle (SRC II) and short contact time (SCT) modes of operation. The distillate yield increased as the iron level in the feed slurry increased in both modes of operation. In the SCT mode, the conversion increased at greater depths of cleaning. In the SRC II mode, the distillate yield and conversion were much higher with deep cleaning and add-back of pyrite than with conventional cleaning. Pyrite addition resulted in a significant increase in short contact time conversion of subbituminous Belle Ayr coal in both high and low quality solvents. Solvent quality itself, however, had little effect on conversion. With Loveridge coal, the hydrocarbon gas yield and conversion decreased as the residence time was reduced in the range of 3 to 8 minutes. The bottoms product was filterable only at residence times of 6 minutes or greater. Addition of a small amount of nickel to a molybdenum emulsion catalyst improved yields slightly with Belle Ayr coal in the SRC II mode. Higher levels of nickel resulted in the same oil yield as with none at all.

  13. Utilization of fuel cells to beneficially use coal mine methane. Final report

    SciTech Connect

    Brown, J.T.; O`Brien, D.G.; Miller, A.R.; Atkins, R.; Sanders, M.

    1996-03-01

    DOE has been given the responsibility to encourage industry to recover and use methane that is currently being released to the atmosphere. At this time the only method being employed at the Left Fork Mine to remove methane is the mine ventilation system. The methane content was measured at one one-hundredth of a percent. To prevent this methane from being vented to the atmosphere, degasification wells are proposed. To use the coal mine methane, it is proposed to use phosphoric-acid fuel cells to convert methane to electric power. These fuel cells contain (1) a steam reformer to convert the methane to hydrogen (and carbon dioxide), (2) the fuel cell stack, and (3) a power conditioner that provides 200 kW of 60 Hz alternating current output. The environmental impacts and benefits of using this technology ware summarized in the report. The study indicates the methane emission reduction that could be achieved on a national and Global level. The important point being that this technology is economically viable as is demonstrated in the report.

  14. In-situ study of beneficial utilization of coal fly ash in reactive mine tailings.

    PubMed

    Lee, Joon Kyu; Shang, Julie Q; Wang, Hongliu; Zhao, Cheng

    2014-03-15

    Oxidation of reactive mine tailings and subsequent generation of acid mine drainage (AMD) have been long recognized as the largest environmental concern for the mining industry. Laboratory studies on utilization of coal fly ash in management of reactive mine tailings have shown reducing water and oxygen infiltration into tailings matrix, thus preventing oxidation of sulphide minerals and acid generation. However, few data from field studies to evaluate the performance of co-placement of mine tailings and fly ash (CMF hereafter) are reported in the open literature. This paper documents the construction and instrumentation of three CMF systems on the Musselwhite mine located in Ontario, Canada and presents results of 3-year real time monitoring. The field data indicates that the CMFs reduced the ingress of water due to cementation generated by hydration of fly ash. It was also found that the electrical conductivity of leachate from CMFs decreased in the early stage of co-placement, compared to the control. With further study, the principle and approach demonstrated in this paper can be adopted as a sustainable technology in the mine tailings management.

  15. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  16. Regional price targets appropriate for advanced coal extraction

    NASA Technical Reports Server (NTRS)

    Terasawa, K. L.; Whipple, D. M.

    1980-01-01

    A methodology is presented for predicting coal prices in regional markets for the target time frames 1985 and 2000 that could subsequently be used to guide the development of an advanced coal extraction system. The model constructed is a supply and demand model that focuses on underground mining since the advanced technology is expected to be developed for these reserves by the target years. Coal reserve data and the cost of operating a mine are used to obtain the minimum acceptable selling price that would induce the producer to bring the mine into production. Based on this information, market supply curves can be generated. Demand by region is calculated based on an EEA methodology that emphasizes demand by electric utilities and demand by industry. The demand and supply curves are then used to obtain the price targets. The results show a growth in the size of the markets for compliance and low sulphur coal regions. A significant rise in the real price of coal is not expected even by the year 2000. The model predicts heavy reliance on mines with thick seams, larger block size and deep overburden.

  17. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Not Available

    1992-01-01

    This report presents the results of Run 260 performed at the Advanced Coal Liquefaction R D Facility in Wilsonville. The run was started on July 17, 1990 and continued until November 14, 1990, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). Both thermal/catalytic and catalytic/thermal tests were performed to determine the methods for reducing solids buildup in a subbituminous coal operation, and to improve product yields. A new, smaller interstage separator was tested to reduce solids buildup by increasing the slurry space velocity in the separator. In order to obtain improved coal and resid conversions (compared to Run 258) full-volume thermal reactor and 3/4-volume catalytic reactor were used. Shell 324 catalyst, 1/16 in. cylindrical extrudate, at a replacement rate of 3 lb/ton of MF coal was used in the catalytic stage. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run. (TNPS was the sulfiding agent.)

  18. Prospects for advanced coal-fuelled fuel cell power plants

    NASA Astrophysics Data System (ADS)

    Jansen, D.; Vanderlaag, P. C.; Oudhuis, A. B. J.; Ribberink, J. S.

    1994-04-01

    As part of ECN's in-house R&D programs on clean energy conversion systems with high efficiencies and low emissions, system assessment studies have been carried out on coal gasification power plants integrated with high-temperature fuel cells (IGFC). The studies also included the potential to reduce CO2 emissions, and to find possible ways for CO2 extraction and sequestration. The development of this new type of clean coal technology for large-scale power generation is still far off. A significant market share is not envisaged before the year 2015. To assess the future market potential of coal-fueled fuel cell power plants, the promise of this fuel cell technology was assessed against the performance and the development of current state-of-the-art large-scale power generation systems, namely the pulverized coal-fired power plants and the integrated coal gasification combined cycle (IGCC) power plants. With the anticipated progress in gas turbine and gas clean-up technology, coal-fueled fuel cell power plants will have to face severe competition from advanced IGCC power plants, despite their higher efficiency.

  19. Performance and economics of advanced energy conversion systems for coal and coal-derived fuels

    NASA Technical Reports Server (NTRS)

    Corman, J. C.; Fox, G. R.

    1978-01-01

    The desire to establish an efficient Energy Conversion System to utilize the fossil fuel of the future - coal - has produced many candidate systems. A comparative technical/economic evaluation was performed on the seven most attractive advanced energy conversion systems. The evaluation maintains a cycle-to-cycle consistency in both performance and economic projections. The technical information base can be employed to make program decisions regarding the most attractive concept. A reference steam power plant was analyzed to the same detail and, under the same ground rules, was used as a comparison base. The power plants were all designed to utilize coal or coal-derived fuels and were targeted to meet an environmental standard. The systems evaluated were two advanced steam systems, a potassium topping cycle, a closed cycle helium system, two open cycle gas turbine combined cycles, and an open cycle MHD system.

  20. Economic aspects of advanced coal-fired gas turbine locomotives

    NASA Technical Reports Server (NTRS)

    Liddle, S. G.; Bonzo, B. B.; Houser, B. C.

    1983-01-01

    Increases in the price of such conventional fuels as Diesel No. 2, as well as advancements in turbine technology, have prompted the present economic assessment of coal-fired gas turbine locomotive engines. A regenerative open cycle internal combustion gas turbine engine may be used, given the development of ceramic hot section components. Otherwise, an external combustion gas turbine engine appears attractive, since although its thermal efficiency is lower than that of a Diesel engine, its fuel is far less expensive. Attention is given to such a powerplant which will use a fluidized bed coal combustor. A life cycle cost analysis yields figures that are approximately half those typical of present locomotive engines.

  1. Advanced coal liquefaction research. Technical progress report, January 1, 1983-December 31, 1983

    SciTech Connect

    Not Available

    1984-05-01

    The most significant work this year involved two methods of improving product quality which advanced the SRC II process far beyond that envisioned for the original demonstration plant. With both bituminous and subbituminous feedstocks, all distillate product boiling above 345/sup 0/C (653/sup 0/F) was recycled to extinction without loss of total oil yield or significant increase in hydrogen consumption. In a further refinement, all of the overhead from the high temperature, high pressure separator was passed through a vapor-phase hydrotreater. This resulted in a dramatic improvement in product quality. A proportional blend of distillate product contained less than 1 ppM of nitrogen. Total oil yield was similar to the low quality product produced in the conventional SRC II process. A large number of multiple-stage liquefaction experiments were carried out to better understand each step in the process. These included 3-stage operations; dissolution, hydrogenation and hydrocracking; and several variations of 2-stage processes. Variables investigated were temperature and residence time in each stage and both slurry and fixed-bed catalyst systems. The effect of residence time on conversion in single pass experiments was found to be quite different for the subbituminous Belle Ayr Mine and bituminous Illinois No. 6 coals studied. With bituminous coal, conversion to soluble material was quite high and the limit of conversion was approached in only a few minutes. With a subbituminous coal, however, conversion was much lower and the limit of conversion was approached much more slowly. In other work, the liquefaction of Illinois No. 6 coal beneficiated in various ways was studied in both SRC II and short contact time modes of operation. Additional short contact time experiments explored the effects of solvent quality and catalysts with Belle Ayr coal and the effects of residence time with Loveridge coal. 32 figures, 8 tables.

  2. COAL AND CHAR STUDIES BY ADVANCED EMR TECHNIQUES

    SciTech Connect

    R. Linn Belford; Robert B. Clarkson; Mark J. Nilges; Boris M. Odintsov; Alex I. Smirnov

    2001-04-30

    Advanced electronic magnetic resonance (EMR) as well as nuclear magnetic resonance (NMR) methods have been used to examine properties of coals, chars, and molecular species related to constituents of coal. During the span of this grant, progress was made on construction and applications to coals and chars of two high frequency EMR systems particularly appropriate for such studies--48 GHz and 95 GHz electron magnetic resonance spectrometer, on new low-frequency dynamic nuclear polarization (DNP) experiments to examine the interaction between water and the surfaces of suspended char particulates in slurries, and on a variety of proton nuclear magnetic resonance (NMR) techniques to measure characteristics of the water directly in contact with the surfaces and pore spaces of carbonaceous particulates.

  3. Need of advanced technologies for coal ash utilization programs

    SciTech Connect

    Dube, S.K.

    1997-09-01

    National Thermal Power Corporation Ltd. (NTPC) alone produces year about 17 million tonnes of coal ash every year, out of 13 coal based stations having about 12,000 MW coal based installed capacity. The coal ash utilization program in NTPC has explored the uses of ash in the areas of raising of ash dykes, structural fills, development of low lying lands, construction of road, building materials, small brick plants, PPC, etc. In taking the studies further the Center for Power Efficiency and Environmental Protection (Cenpeep) of NTPC is evaluating the scope of employing the advanced technologies in coal ash utilization to maximize its consumption and with improved productivity. To start with it is being suggested to develop the ash ponds using more economical compacting techniques to increase the life of current ash pond. The other areas include the development of suitable grout for back filling of mine without sacrificing the productivity of mine, use of fly ash and bottom ash in the road base construction work, manufacture of clay-ash and lime ash bricks using high speed brick plants and manufacture of light weight aggregates near the consumption center. There are many other areas also where ash can find its application in large volumes.

  4. Advanced hot gas cleaning system for coal gasification processes

    NASA Astrophysics Data System (ADS)

    Newby, R. A.; Bannister, R. L.

    1994-04-01

    The United States electric industry is entering a period where growth and the aging of existing plants will mandate a decision on whether to repower, add capacity, or do both. The power generation cycle of choice, today, is the combined cycle that utilizes the Brayton and Rankine cycles. The combustion turbine in a combined cycle can be used in a repowering mode or in a greenfield plant installation. Today's fuel of choice for new combined cycle power generation is natural gas. However, due to a 300-year supply of coal within the United States, the fuel of the future will include coal. Westinghouse has supported the development of coal-fueled gas turbine technology over the past thirty years. Working with the U.S. Department of Energy and other organizations, Westinghouse is actively pursuing the development and commercialization of several coal-fueled processes. To protect the combustion turbine and environment from emissions generated during coal conversion (gasification/combustion) a gas cleanup system must be used. This paper reports on the status of fuel gas cleaning technology and describes the Westinghouse approach to developing an advanced hot gas cleaning system that contains component systems that remove particulate, sulfur, and alkali vapors. The basic process uses ceramic barrier filters for multiple cleaning functions.

  5. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    SciTech Connect

    Edwin S. Olson; Charles J. Moretti

    1999-11-01

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require

  6. Evaluation of ADAM/1 model for advanced coal extraction concepts

    NASA Technical Reports Server (NTRS)

    Deshpande, G. K.; Gangal, M. D.

    1982-01-01

    Several existing computer programs for estimating life cycle cost of mining systems were evaluated. A commercially available program, ADAM/1 was found to be satisfactory in relation to the needs of the advanced coal extraction project. Two test cases were run to confirm the ability of the program to handle nonconventional mining equipment and procedures. The results were satisfactory. The model, therefore, is recommended to the project team for evaluation of their conceptual designs.

  7. Advanced coal-fired glass melting development program

    SciTech Connect

    Not Available

    1991-05-01

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  8. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Not Available

    1992-09-01

    This report presents the results of Run 262 performed at the Advanced Coal Liquefaction R D Facility in Wilsonville, Alabama. The run started on July 10, 1991 and continued until September 30, 1991, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder Mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). A dispersed molybdenum catalyst was evaluated for its performance. The effect of the dispersed catalyst on eliminating solids buildup was also evaluated. Half volume reactors were used with supported Criterion 324 1/16'' catalyst in the second stage at a catalyst replacement rate of 3 lb/ton of MF coal. The hybrid dispersed plus supported catalyst system was tested for the effect of space velocity, second stage temperature, and molybdenum concentration. The supported catalyst was removed from the second stage for one test period to see the performance of slurry reactors. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run (dimethyl disulfide (DMDS) was used as the sulfiding agent). The close-coupled reactor unit was on-stream for 1271.2 hours for an on-stream factor of 89.8% and the ROSE-SR unit was on-feed for 1101.6 hours for an on-stream factor of 90.3% for the entire run.

  9. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1992-01-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO[sub x]-NO[sub x] submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  10. Fundamental research on surface science of coal in support of physical beneficiation of coal. Quarterly technical progress report No. 4, July 1--September 30, 1988

    SciTech Connect

    Good, R.J.

    1988-12-31

    The experimental systems required for our research have been acquired. Contact angle measurements on unoxidized Upper Freeport coal and fresh Illinois No. 6 coal show small differences in the contact angles of water under decane. Adsorption measurements on Upper Freeport coal with cyclohexanol in decane reveal adsorption behavior similar to that of octanol. This indicates that the adsorption is taking place on the pore surface of the coal and that the pores are probably greater than 2 nm diameter.

  11. Mulled Coal: A beneficiated coal form for use as a fuel or fuel intermediate. Technical progress report No. 7, October 1, 1991--December 31, 1991

    SciTech Connect

    Not Available

    1992-02-01

    This report covers activities from October 1, 1991 to December 31, 1991. During this period we have: Obtained storage and handling system design data for the granular coal; completed the 74-day aging study on various mull formulations to determine the effects of time and exposure on mull properties; demonstrated the continuous production of mulled coal from wet filter cake; demonstrated the continuous production of CWF from mull; and performed atomization studies on Mulled Coal and CWF prepared from Mulled Coal.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  13. Performance of a high efficiency advanced coal combustor

    SciTech Connect

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. )

    1989-12-01

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the primary act,'' and three further annuli for the supply of the secondary air.'' The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  14. Technology and development requirements for advanced coal conversion systems

    NASA Technical Reports Server (NTRS)

    1981-01-01

    A compendium of coal conversion process descriptions is presented. The SRS and MC data bases were utilized to provide information paticularly in the areas of existing process designs and process evaluations. Additional information requirements were established and arrangements were made to visit process developers, pilot plants, and process development units to obtain information that was not otherwise available. Plant designs, process descriptions and operating conditions, and performance characteristics were analyzed and requirements for further development identified and evaluated to determine the impact of these requirements on the process commercialization potential from the standpoint of economics and technical feasibility. A preliminary methodology was established for the comparative technical and economic assessment of advanced processes.

  15. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Not Available

    1992-09-01

    This report presents the results of Run 261 performed at the Advanced Coal Liquefaction R D Facility in Wilsonville, Alabama. The run started on January 12, 1991 and continued until May 31, 1991, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Illinois No. 6 seam bituminous coal (from Burning star No. 2 mine). In the first part of Run 261, a new bimodal catalyst, EXP-AO-60, was tested for its performance and attrition characteristics in the catalytic/catalytic mode of the CC-ITSL process. The main objective of this part of the run was to obtain good process performance in the low/high temperature mode of operation along with well-defined distillation product end boiling points. In the second part of Run 261, Criterion (Shell) 324 catalyst was tested. The objective of this test was to evaluate the operational stability and catalyst and process performance while processing the high ash Illinois No. 6 coal. Increasing viscosity and preasphaltenes made it difficult to operate at conditions similar to EXP-AO-60 catalyst operation, especially at lower catalyst replacement rates.

  16. Advanced Coal Conversion Process Demonstration Project. Environmental Monitoring Plan

    SciTech Connect

    Not Available

    1992-04-01

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  17. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy's program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research Development Center (Amax R D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  18. Advanced Coal Conversion Process Demonstration. Technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Not Available

    1994-03-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from April 1, 1993, through June 30, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  19. Advanced Coal Conversion Process Demonstration. Technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Not Available

    1994-03-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through May 31, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  20. Advanced Coal Conversion Process Demonstration. Technical progress report, July 1, 1993--September 30, 1993

    SciTech Connect

    Not Available

    1994-03-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1993, through September 30, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  1. Markets for small-scale, advanced coal-combustion technologies

    SciTech Connect

    Placet, M.; Kenkeremath, L.D.; Streets, D.G.; Dials, G.E.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1988-12-01

    This report examines the potential of using US-developed advanced coal technologies (ACTs) for small combustors in foreign markets; in particular, the market potentials of the member countries of the Organization of Economic Co-operation and Development (OECD) were determined. First, the United States and those OECD countries with very low energy demands were eliminated. The remaining 15 countries were characterized on the basis of eight factors that would influence their decision to use US ACTs: energy plan and situation, dependence on oil and gas imports, experience with coal, residential/commercial energy demand, industrial energy demand, trade relationship with the United States, level of domestic competition with US ACT manufacturers, and environmental pressure to use advanced technology. Each country was rated high, medium-high, low-medium, or low on each factor, based on statistical and other data. The ratings were then used to group the countries in terms of their relative market potential (good, good but with impediments, or limited). The best potential markets appear to be Spain, Italy, turkey, Greece, and Canada. 25 refs., 1 fig., 37 tabs.

  2. Development of clean coal and clean soil technologies using advanced agglomeration technologies

    SciTech Connect

    Ignasiak, B.; Pawlak, W.; Szymocha, K.; Marr, J.

    1990-04-01

    The specific objectives of the bituminous coal program were to explore and evaluate the application of advanced agglomeration technology for: (1)desulphurization of bituminous coals to sulphur content acceptable within the current EPA SO{sub 2} emission guidelines; (2) deashing of bituminous coals to ash content of less than 10 percent; and (3)increasing the calorific value of bituminous coals to above 13,000 Btu/lb. (VC)

  3. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    SciTech Connect

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  4. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly progress report, July--September 1993

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1993-12-31

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The primary coal of this program, Black Thunder subbituminous coal, can be effectively beneficiated to about 3.5 wt % ash using aqueous sulfurous acid pretreatment. This treated coal can be further beneficiated to about 2 wt % ash using commercially available procedures. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated subbituminous coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent. The study of bottoms processing consists of combining the ASCOT process which consists of coupling solvent deasphalting with delayed coking to maximize the production of coal-derived liquids while rejecting solids within the coke drum. The asphalt production phase has been completed; representative product has been evaluated. The solvent system for the deasphalting process has been established. Two ASCOT tests produced overall liquid yields (63.3 wt % and 61.5 wt %) that exceeded the combined liquid yields from the vacuum tower and ROSE process.

  5. Advanced direct coal liquefaction concepts. Final report, Volume 2

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L.

    1994-07-01

    Integration of innovative steps into new advanced processes have the potential to reduce costs for producing liquid fuels. In this program, objective is to develop a new approach to liquefaction that generates an all distillate product slate at a reduced cost of about US$25/barrel of crude oil equivalent. A Counterflow Reactor was developed in cooperation with GfK mbH, Germany. Advantages are low hydrogen recycle rates and low feed preheating requirements. Coal/heavy oil slurry is injected into the top of the reactor while the recycle gas and make up hydrogen is introduced into the bottom; hydrogenation products are withdrawn from the top. PU study resulted in distillable oil yields up to 74 wt % on feed (dry ash free) from coprocessing feed slurries containing 40 wt % Vesta subbituminous coal and 60 wt % Cold Lake heavy vacuum tower bottoms. Technologies developed separately by CED and ARC were combined. A 1-kg/hr integrated continuous flow bench scale unit was constructed at the ARC site in Devon, Alberta, based on modifications to a unit at Nisku, Alberta (the modified unit was used in the preliminary economic evaluation).

  6. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  7. Advanced coal gasifier-fuel cell power plant systems design

    NASA Technical Reports Server (NTRS)

    Heller, M. E.

    1983-01-01

    Two advanced, high efficiency coal-fired power plants were designed, one utilizing a phosphoric acid fuel cell and one utilizing a molten carbonate fuel cell. Both incorporate a TRW Catalytic Hydrogen Process gasifier and regenerator. Both plants operate without an oxygen plant and without requiring water feed; they, instead, require makeup dolomite. Neither plant requires a shift converter; neither plant has heat exchangers operating above 1250 F. Both plants have attractive efficiencies and costs. While the molten carbonate version has a higher (52%) efficiency than the phosphoric acid version (48%), it also has a higher ($0.078/kWh versus $0.072/kWh) ten-year levelized cost of electricity. The phosphoric acid fuel cell power plant is probably feasible to build in the near term: questions about the TRW process need to be answered experimentally, such as weather it can operate on caking coals, and how effective the catalyzed carbon-dioxide acceptor will be at pilot scale, both in removing carbon dioxide and in removing sulfur from the gasifier.

  8. Safety evaluation methodology for advanced coal extraction systems

    SciTech Connect

    Zimmerman, W.F.

    1981-07-15

    To be acceptable to the coal industry, an advanced extraction system must provide a significant improvement over conventional systems in cost, safety, environmental impact, and conservation of unmined coal. Qualitative and quantitative evaluation methodologies were developed to assist the designer in determining if a proposed extraction design will be safer than existing systems. The qualitative analysis is a process which tests the new system against regulations and hazards of existing similar systems. The analysis examines the soundness of the design, whether or not the major hazards have been eliminated or reduced, and how the reduction would be accomplished. The quantitative methodology provides the designer with a means of establishing the approximate impact of hazards on injury levels. The results are further weighted by peculiar geological elements, specialized safety training, peculiar mine environmental aspects, and reductions in labor force. The outcome is compared with injury level requirements based on similar, safer industries to get a measure of the new system's success in reducing injuries. This approach provides a more detailed and comprehensive analysis of hazards and their effects than existing safety analyses.

  9. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  10. Beneficial effects through aggressive coronary screening for type 2 diabetes patients with advanced vascular complications.

    PubMed

    Tsujimoto, Tetsuro; Sugiyama, Takehiro; Yamamoto-Honda, Ritsuko; Kishimoto, Miyako; Noto, Hiroshi; Morooka, Miyako; Kubota, Kazuo; Kamimura, Munehiro; Hara, Hisao; Kajio, Hiroshi; Kakei, Masafumi; Noda, Mitsuhiko

    2016-08-01

    Glycemic control alone does not reduce cardiovascular events in patients with type 2 diabetes (T2D), and routine screening of all T2D patients for asymptomatic coronary artery disease (CAD) is not effective for preventing acute cardiac events. We examined the effectiveness of an aggressive screening protocol for asymptomatic CAD in T2D patients with advanced vascular complications.We designed a 3-year cohort study investigating the effectiveness of the aggressive coronary screening for T2D patients with advanced vascular complications and no known coronary events using propensity score adjusted analysis at a national center in Japan. Eligibility criteria included T2D without known coronary events and with any 1 of the following 4 complications: advanced diabetic retinopathy, advanced chronic kidney disease, peripheral artery disease, or cerebrovascular disease. In the aggressive screening group (n = 122), all patients received stress single photon emission computed tomography and those exhibiting myocardial perfusion abnormalities underwent coronary angiography. In the conventional screening group (n = 108), patients were examined for CAD at the discretion of their medical providers. Primary endpoint was composite outcome of cardiovascular death and nonfatal cardiovascular events.Asymptomatic CAD with ≥70% stenosis was detected in 39.3% of patients completing aggressive screening. The proportions achieving revascularization and receiving intensive medical therapy within 90 days after the screening were significantly higher in the aggressive screening group than in the conventional screening group [19.7% vs 0% (P < 0.001) and 48.4% vs 9.3% (P < 0.001), respectively]. The cumulative rate of primary composite outcome was significantly lower in the aggressive screening group according to a propensity score adjusted Cox proportional hazards model (hazard ratio, 0.35; 95% confidence interval, 0.12-0.96; P = 0.04).Aggressive coronary screening for T2D patients

  11. Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    1996-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  12. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1993--December 31, 1993

    SciTech Connect

    1995-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through December 31, 1993. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low- rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  13. Performance and risks of advanced pulverized-coal plants

    SciTech Connect

    Nalbandian, H.

    2009-07-01

    This article is based on an in-depth report of the same title published by the IEA Clean Coal Centre, CCC/135 (see Coal Abstracts entry Sep 2008 00535). It discusses the commercial, developmental and future status of pulverized fuel power plants including subcritical supercritical and ultra supercritical systems of pulverized coal combustion, the most widely used technology in coal-fired power generation. 1 fig., 1 tab.

  14. Assessment of Feasibility of the Beneficial Use of Waste Heat from the Advanced Test Reactor

    SciTech Connect

    Donna P. Guillen

    2012-07-01

    This report investigates the feasibility of using waste heat from the Advanced Test Reactor (ATR). A proposed glycol waste heat recovery system was assessed for technical and economic feasibility. The system under consideration would use waste heat from the ATR secondary coolant system to preheat air for space heating of TRA-670. A tertiary coolant stream would be extracted from the secondary coolant system loop and pumped to a new plate and frame heat exchanger, where heat would be transferred to a glycol loop for preheating outdoor air in the heating and ventilation system. Historical data from Advanced Test Reactor operations over the past 10 years indicates that heat from the reactor coolant was available (when needed for heating) for 43.5% of the year on average. Potential energy cost savings by using the waste heat to preheat intake air is $242K/yr. Technical, safety, and logistics considerations of the glycol waste heat recovery system are outlined. Other opportunities for using waste heat and reducing water usage at ATR are considered.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO[sub 2] per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO[sub 2] emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  16. Advanced Coal-Extraction-Systems Project: report of activities for fiscal year 1980-1981. [By coal field and basin

    SciTech Connect

    Dutzi, E.J.

    1982-03-15

    The Advanced Coal Extraction Systems Project completed several major accomplishments in the definition of target resources, definition of conceptual design requirements for Central Appalachia coals, and initiation of the conceptual design effort. Geologically and economically significant resources were characterized, resulting in recommendations for additional target resources; conceptual design requirements for Central Appalachia coals in the areas of production cost, safety, health, environmental impact, and coal conservation were formulated; and strategies for internal and external design efforts were defined. In addition, an in-depth health and safety evaluation of a modified tunnel borer design for coal mining was completed. At the end of fiscal year 1980-1981, the project was prepared to begin evolution and evaluation of conceptual designs for advanced coal mining systems. The selection of Central Appalachia as the target region automatically imposes certain restrictions and constraints, pertinent to the geology, geography, and other aspects of the operating environment. Requirements imposed by the target resource are summarized. Figure 2-1 presents an overview of the relationship between the conceptual design requirements and the constraints imposed by the Central Appalachian target resource.

  17. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Rawls, P.

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  18. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    SciTech Connect

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  19. Low-rank coal research

    SciTech Connect

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  20. Coal for the future. Proceedings of the 33rd international technical conference on coal utilization and fuel systems

    SciTech Connect

    Sakkestad, B.A.

    2008-07-01

    Topics covered include oxy-fuel technology, modelling and simulations, low NOx technology, gasification technology, pre-utilization beneficiation of coal, advanced energy conversion systems, mercury emissions control, improving power plant efficiency and reducing emissions, biomass and wastes, coal to liquids, post-combustion CO{sub 2} capture, multi emission controls, advanced materials, advanced controls, and international highlights.

  1. 76 FR 55837 - Workshops To Discuss Revisions to Federal and Indian Coal Valuation Regulations: Advance Notice...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-09

    ... Revisions to Federal and Indian Coal Valuation Regulations: Advance Notice of Proposed Rulemaking AGENCY...-2225, e- mail hyla.hurst@onrr.gov . SUPPLEMENTARY INFORMATION: The comment period for the Advance... without advance registration; however, attendance may be limited to the space available at each venue....

  2. Advanced turbine design for coal-fueled engines

    SciTech Connect

    Bornstein, N.S.

    1992-07-17

    The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500[degrees]F (815[degrees]C), relatively innocuous salts. In this study it is found that at 1650[degrees]F (900[degrees]C) and above, calcium sulfate becomes an aggressive corrodent.

  3. Advanced turbine design for coal-fueled engines

    NASA Astrophysics Data System (ADS)

    Bornstein, N. S.

    1992-07-01

    The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500 F (815 C), relatively innocuous salts. In this study it is found that at 1650 F (900 C) and above, calcium sulfate becomes an aggressive corrodent.

  4. Advanced physical fine coal cleaning spherical agglomeration. Final report

    SciTech Connect

    Not Available

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  5. Measurement and modeling of advanced coal conversion processes. Annual report, October 1990--September 1991

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S. |

    1991-12-31

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This program will merge significant advances made in measuring and quantitatively describing the mechanisms in coal conversion behavior. Comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors.

  6. Geotechnical/geochemical characterization of advanced coal process waste streams: Task 2

    SciTech Connect

    Moretti, C.J.; Olson, E.S.

    1992-09-01

    Successful disposal practices for solid wastes produced from advanced coal combustion and coal conversion processes must provide for efficient management of relatively large volumes of wastes in a cost-effective and environmentally safe manner. At present, most coal-utilization solid wastes are disposed of using various types of land-based systems, and it is probable that this disposal mode will continue to be widely used in the future for advanced process wastes. Proper design and operation of land-based disposal systems for coal combustion wastes normally require appropriate waste transfer, storage, and conditioning subsystems at the plant to prepare the waste for transport to an ultimate disposal site. Further, the overall waste management plan should include a by-product marketing program to minimize the amount of waste that will require disposal. In order to properly design and operate waste management systems for advanced coal-utilization processes, a fundamental understanding of the physical properties, chemical and mineral compositions, and leaching behaviors of the wastes is required. In order to gain information about the wastes produced by advanced coal-utilization processes, 55 waste samples from 16 different coal gasification, fluidized-bed coal combustion (FBC), and advanced flue gas scrubbing processes were collected. Thirty-four of these wastes were analyzed for their bulk chemical and mineral compositions and tested for a detailed set of disposal-related physical properties. The results of these waste characterizations are presented in this report. In addition to the waste characterization data, this report contains a discussion of potentially useful waste management practices for advanced coal utilization processes.

  7. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Run 260 with Black Thunder Mine subbituminous coal: Technical progress report

    SciTech Connect

    Not Available

    1992-01-01

    This report presents the results of Run 260 performed at the Advanced Coal Liquefaction R&D Facility in Wilsonville. The run was started on July 17, 1990 and continued until November 14, 1990, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). Both thermal/catalytic and catalytic/thermal tests were performed to determine the methods for reducing solids buildup in a subbituminous coal operation, and to improve product yields. A new, smaller interstage separator was tested to reduce solids buildup by increasing the slurry space velocity in the separator. In order to obtain improved coal and resid conversions (compared to Run 258) full-volume thermal reactor and 3/4-volume catalytic reactor were used. Shell 324 catalyst, 1/16 in. cylindrical extrudate, at a replacement rate of 3 lb/ton of MF coal was used in the catalytic stage. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run. (TNPS was the sulfiding agent.)

  8. Engineering development of advanced physical fine coal cleaning technologies - froth flotation

    SciTech Connect

    Ferris, D.D.; Bencho, J.R.

    1995-11-01

    In 1988, ICF Kaiser Engineers was awarded DOE Contract No. DE-AC22-88PC88881 to research, develop, engineer and design a commercially acceptable advanced froth flotation coal cleaning technology. The DOE initiative is in support of the continued utilization of our most abundant energy resource. Besides the goal of commercialability, coal cleaning performance and product quality goals were established by the DOE for this and similar projects. primary among these were the goals of 85 percent energy recovery and 85 percent pyrite rejection. Three nationally important coal resources were used for this project: the Pittsburgh No. 8 coal, the Upper Freeport coal, and the Illinois No. 6 coal. Following is a summary of the key findings of this project.

  9. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect

    Karekh, B K; Tao, D; Groppo, J G

    1998-08-28

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 - March 31, 1998.

  10. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  11. An evaluation of disposal and utilization options for advanced coal utilization wastes

    SciTech Connect

    Moretti, C.J.

    1996-05-01

    If the US is to continue to effectively use its substantial coal reserves, new clean coal technologies must be developed to improve power production efficiency and reduce emissions from power plants. In order to gain information about wastes produced by advanced coal utilization processes, a research project is being conducted to characterize the geotechnical and geochemical properties of advanced coal process wastes. The University of North Dakota Energy and Environmental Research Center (EERC) analyzed 34 of these wastes for their bulk chemical and mineral compositions and for the disposal-related physical properties listed in a table. This paper discusses potentially useful waste management practices for eight bulk waste samples obtained from four different clean coal processes: gas reburning with sorbent injection (GRSI); pressurized fluidized-bed combustion (PFBC); SO{sub x}, NO{sub x}, RO{sub x}, BOX (SNRB); and coal reburning (CR). All four processes have been demonstrated at either full-scale or pilot-scale facilities in the US. Since the properties of advanced process wastes are different from conventional coal combustion wastes, an analysis was performed to identify any potential problems that could occur when standard, off-the-shelf waste management technologies are used for handling and disposal of advanced process wastes. When potential problems were identified, possible alternative technologies were evaluated.

  12. Systems Analysis Of Advanced Coal-Based Power Plants

    NASA Technical Reports Server (NTRS)

    Ferrall, Joseph F.; Jennings, Charles N.; Pappano, Alfred W.

    1988-01-01

    Report presents appraisal of integrated coal-gasification/fuel-cell power plants. Based on study comparing fuel-cell technologies with each other and with coal-based alternatives and recommends most promising ones for research and development. Evaluates capital cost, cost of electricity, fuel consumption, and conformance with environmental standards. Analyzes sensitivity of cost of electricity to changes in fuel cost, to economic assumptions, and to level of technology. Recommends further evaluation of integrated coal-gasification/fuel-cell integrated coal-gasification/combined-cycle, and pulverized-coal-fired plants. Concludes with appendixes detailing plant-performance models, subsystem-performance parameters, performance goals, cost bases, plant-cost data sheets, and plant sensitivity to fuel-cell performance.

  13. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    SciTech Connect

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  14. Field study of disposed solid wastes from advanced coal processes

    SciTech Connect

    Not Available

    1992-01-01

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells.

  15. Organic coal-water fuel: Problems and advances (Review)

    NASA Astrophysics Data System (ADS)

    Glushkov, D. O.; Strizhak, P. A.; Chernetskii, M. Yu.

    2016-10-01

    The study results of ignition of organic coal-water fuel (OCWF) compositions were considered. The main problems associated with investigation of these processes were identified. Historical perspectives of the development of coal-water composite fuel technologies in Russia and worldwide are presented. The advantages of the OCWF use as a power-plant fuel in comparison with the common coal-water fuels (CWF) were emphasized. The factors (component ratio, grinding degree of solid (coal) component, limiting temperature of oxidizer, properties of liquid and solid components, procedure and time of suspension preparation, etc.) affecting inertia and stability of the ignition processes of suspensions based on the products of coaland oil processing (coals of various types and metamorphism degree, filter cakes, waste motor, transformer, and turbine oils, water-oil emulsions, fuel-oil, etc.) were analyzed. The promising directions for the development of modern notions on the OCWF ignition processes were determined. The main reasons limiting active application of the OCWF in power generation were identified. Characteristics of ignition and combustion of coal-water and organic coal-water slurry fuels were compared. The effect of water in the composite coal fuels on the energy characteristics of their ignition and combustion, as well as ecological features of these processes, were elucidated. The current problems associated with pulverization of composite coal fuels in power plants, as well as the effect of characteristics of the pulverization process on the combustion parameters of fuel, were considered. The problems hindering the development of models of ignition and combustion of OCWF were analyzed. It was established that the main one was the lack of reliable experimental data on the processes of heating, evaporation, ignition, and combustion of OCWF droplets. It was concluded that the use of high-speed video recording systems and low-inertia sensors of temperature and gas

  16. Measurement and modeling of advanced coal conversion processes, Volume II

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1993-06-01

    A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

  17. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Technical progress report, Run 243 with Illinois 6 coal

    SciTech Connect

    Not Available

    1984-02-01

    This report presents the operating results for Run 243 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary objective was to demonstrate the effect of a dissolver on the ITSL product slate, especially on the net C/sub 1/-C/sub 5/ gas production and hydrogen consumption. Run 243 began on 3 February 1983 and continued through 28 June 1983. During this period, 349.8 tons of coal was fed in 2947 hours of operation. Thirteen special product workup material balances were defined, and the results are presented herein. 29 figures, 19 tables.

  18. Advanced coal-fueled gas turbine systems. Final report

    SciTech Connect

    Not Available

    1993-08-01

    The configuration of the subscale combustor has evolved during the six years of this program from a system using only an impact separator to remove particulates to a system which also included a slagging cyclone separator before the lean-quench combustor. The system also now includes active slag tapping after the impact separator rather than a bucket to collect the slag. The subscale 12 MM Btu/hr (higher heating value, HHV) slagging combustor has demonstrated excellent coal-fired operation at 6 atm. The combustor has fired both coal-water mixtures (CWM) and pulverized coal (PC). Three Wyoming subbituminous coals and two bituminous coals have been successfully fired in the TVC. As a result of this active testing, the following conclusions may be drawn: (1) it was possible to achieve the full design thermal capacity of 12 MM Btu/hr with the subscale slagging combustor, while burning 100% pulverized coal and operating at the design pressure of 6 atm; (2) because of the separate-chamber, rich-lean design of the subscale slagging combustor, NO{sub x} emissions that easily meet the New Source Performance Standards (NSPS) limits were achieved; (3) carbon burnout efficiency was in excess of 99% when 100% coal-fired; (4) ninety percent of the ash can be separated as slag in the impact separator, and a total 98 to 99% removed with the addition of the slagging cyclone separator; (5) Objectives for third-stage exit temperature (1850{degrees}F), and exit temperature pattern factor (14%) were readily achieved; (6) overall pressure loss is currently an acceptable 5 to 6% without cyclone separator and 7 to 9% with the cyclone; and (7) feeding pulverized coal or sorbent into the combustor against 6 atm pressure is achievable.

  19. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1990-07-01

    The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. This quarter, work was centered on design, fabrication, and testing of the combustor, cleanup, fuel specifications, and hot end simulation rig. 2 refs., 59 figs., 29 tabs.

  20. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    SciTech Connect

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V.

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  1. Advanced NMR approaches in the characterization of coal

    SciTech Connect

    Maciel, G.E.

    1992-01-01

    The paper submitted earlier on the use of (bicyclo[3.2.1]4pyrrolidino-N-methyl-octan-8-one triflate) ([sup 13]CO-123) as a [sup 13]C intensity standard was accepted for publication. Subsequently, [sup 13]CO-321 was used in this manner for quantitative [sup 13]C CP-MAS NMR analysis (including spin counting) of Argonne Premium coals. The cross-polarization time constants, T[sub CH], and the rotating-frame proton spin-lattice relaxation times, T[sub 1p][sup H], were determined for each major peak of each coal via a combination of variable contact-time and variable spin-lock (T[sub 1p][sup H]) experiments. Two or three components of rotating-frame [sup 1]H relaxation decay and two or three components of T[sub CH] behavior were observed for each major [sup 13]C peak of each coal. These data were used to determine the number of carbon atoms detected in each coal; these values are in the range between 77% and 87% of the amount of carbon known to be in each coal from elemental analysis data, except for Pocahontas No. 3, for which only 50% of the carbon was detected. In an attempt to use [sup 1]H CRAMPS to elucidate chemical functionality in coal, pyridine-saturated samples of the Argonne Premium coals were examined in detail in terms of their [sup 1]H CRAMPS NMR spectra. These spectra were deconvoluted to yield relative concentrations for individual peaks.

  2. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    1996-06-01

    This detailed report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project. This U.S. Department of Energy (DOE) Clean Coal Technology Project demonstrates an advanced thermal coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to high-quality, low-sulfur fuel. During this reporting period, the primary focus for the project was to expand market awareness and acceptability for the products and the technology. The use of covered hopper cars has been successful and marketing efforts have focused on this technique. Operational improvements are currently aimed at developing fines marketing systems, increasing throughput capacity, decreasing operation costs, and developing standardized continuous operator training. Testburns at industrial user sites were also conducted. A detailed process description; technical progress report including facility operations/plant production, facility testing, product testing, and testburn product; and process stability report are included. 3 figs., 8 tabs.

  3. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    a study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This document is the eighth quarterly report prepared in accordance with the project reporting requirements covering the period from July 1,1990 to September 30, 1990. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. The data from the basic research on coal surfaces, bench scale testing and proof-of-concept scale testing will be utilized to design a final conceptual flowsheet. The economics of the flowsheet will be determined to enable industry to assess the feasibility of incorporating the advanced fine coal cleaning technology into the production of clean coal for generating electricity. 22 figs., 11 tabs.

  4. Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

    NASA Astrophysics Data System (ADS)

    Robson, F. L.

    1981-03-01

    Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

  5. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect

    Not Available

    1981-03-31

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  6. Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

  7. Measurement and modeling of advanced coal conversion processes, Volume III

    SciTech Connect

    Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G.

    1993-08-01

    A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

  8. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications

    SciTech Connect

    Smit, Frank J; Schields, Gene L; Jha, Mehesh C; Moro, Nick

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel™ column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications.

  9. Effectiveness of beneficial plant-microbe interactions under hypobaric and hypoxic conditions in an advanced life support system

    NASA Astrophysics Data System (ADS)

    MacIntyre, Olathe; Stasiak, Michael; Cottenie, Karl; Trevors, Jack; Dixon, Mike

    An assembled microbial community in the hydroponics solution of an advanced life support system may improve plant performance and productivity in three ways: (1) exclusion of plant pathogens from the initial community, (2) resistance to infection, and (3) plant-growth promotion. However, the plant production area is likely to have a hypobaric (low pressure) and hypoxic (low oxygen) atmosphere to reduce structural mass and atmosphere leakage, and these conditions may alter plant-microbe interactions. Plant performance and productivity of radish (Raphanus sativus L. cv. Cherry Bomb II) grown under hypobaric and hypoxic conditions were investigated at the University of Guelph's Controlled Environment Systems Research Facility. Changes in the microbial communities that routinely colonized the re-circulated nutrient solution, roots, and leaves of radishes in these experiments were quantified in terms of similarity in community composition, abundance of bacteria, and community diversity before and after exposure to hypobaric and hypoxic conditions relative to communities maintained at ambient growth conditions. The microbial succession was affected by extreme hypoxia (2 kPa oxygen partial pressure) while hypobaria as low as 10 kPa total pressure had little effect on microbial ecology. There were no correlations found between the physiological profile of these unintentional microbial communities and radish growth. The effects of hypobaric and hypoxic conditions on specific plant-microbe interactions need to be determined before beneficial gnotobiotic communities can be developed for use in space. The bacterial strains Tal 629 of Bradyrhizobium japonicum and WCS417 of Pseudomonas fluorescens, and the plant pathogen Fusarium oxysporum f. sp. raphani will be used in future experiments. B. japonicum Tal 629 promotes radish growth in hydroponics systems and P. fluorescens WCS417 induces systemic resistance to fusarium wilt (F. oxysporum f. sp. raphani) in radish under ambient

  10. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, January--March 1993

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1993-09-01

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The primary coal of this program, Black Thunder subbituminous coal, can be effectively beneficiated to about 4 wt% ash using aqueous sulfurous acid pretreatment. This treated coal can be further beneficiated to about 2 wt% ash using commercially available procedures. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. In addition, a synergistic effect has been demonstrated, in which solvent blends are more effective for coal swelling than the pure solvents alone. Therefore, it will be necessary to use only low levels of swelling agents and yet promote the impregnation of catalyst precursors. The rate of the impregnation of catalyst precursors into swollen coal increases greatly as the effectiveness of the solvent to swell the coal increases.

  11. Overall requirements for an advanced underground coal extraction system

    SciTech Connect

    Goldsmith, M.; Lavin, M.L.

    1980-10-15

    This report presents overall requirements on underground mining systems suitable for coal seams exploitable in the year 2000, with particular relevance to the resources of Central Appalachia. These requirements may be summarized as follows: (1) Production Cost: demonstrate a return on incremental investment of 1.5 to 2.5 times the value required by a low-risk capital project. (2) Miner Safety: achieve at least a 50% reduction in deaths and disabling injuries per million man-hours. (3) Miner Health: meet the intent of all applicable regulations, with particular attention to coal dust, carcinogens, and mutagens; and with continued emphasis on acceptable levels of noise and vibration, lighting, humidity and temperature, and adequate work space. (4) Environmental Impact: maintain the value of mined and adjacent lands at the pre-mining value following reclamation; mitigation of off-site impacts should not cost more than the procedures used in contemporary mining. (5) Coal Conservation: the recovery of coal from the seam being mined should be at least as good as the best available contemporary technology operating in comparable conditions. No significant trade-offs between production cost and other performance indices were found.

  12. Advances in Ammonia Removal from Hot Coal Gas

    SciTech Connect

    Jothimurugesan, K.; Gangwal, S.K.

    1996-12-31

    Nitrogen occurs in coal in the form of tightly bound organic ring compounds, typically at levels of 1 to 2 wt%. During coal gasification, this fuel bound nitrogen is released principally as ammonia (NH{sub 3}). When hot coal gas is used to generate electricity in integrated gasification combined cycle (IGCC) power plants, NH{sub 3} is converted to nitrogen oxides (NO{sub x}) which are difficult to remove and are highly undesirable as atmospheric pollutants. Similarly, while the efficiency of integrated gasification molten carbonate fuel cell (IGFC) power plants is not affected by NH{sub 3}, NO{sub x} is generated during combustion of the anode exhaust gas. Thus NH{sub 3} must be removed from hot coal gas before it can be burned in a turbine or fuel cell. The objective of this study is to develop a successful combination of an NH{sub 3} decomposition catalyst with a zinc-based mixed-metal oxide sorbent so that the sorbent-catalyst activity remains stable for NH{sub 3} decomposition in addition to H{sub 2}S removal under cycle sulfidation-regeneration conditions in the temperature range of 500 to 750{degrees}C.

  13. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  14. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Run 262 with Black Thunder subbituminous coal: Technical progress report

    SciTech Connect

    Not Available

    1992-09-01

    This report presents the results of Run 262 performed at the Advanced Coal Liquefaction R&D Facility in Wilsonville, Alabama. The run started on July 10, 1991 and continued until September 30, 1991, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder Mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). A dispersed molybdenum catalyst was evaluated for its performance. The effect of the dispersed catalyst on eliminating solids buildup was also evaluated. Half volume reactors were used with supported Criterion 324 1/16`` catalyst in the second stage at a catalyst replacement rate of 3 lb/ton of MF coal. The hybrid dispersed plus supported catalyst system was tested for the effect of space velocity, second stage temperature, and molybdenum concentration. The supported catalyst was removed from the second stage for one test period to see the performance of slurry reactors. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run (dimethyl disulfide (DMDS) was used as the sulfiding agent). The close-coupled reactor unit was on-stream for 1271.2 hours for an on-stream factor of 89.8% and the ROSE-SR unit was on-feed for 1101.6 hours for an on-stream factor of 90.3% for the entire run.

  15. A commitment to coal

    SciTech Connect

    Shea, Q.

    2006-07-15

    Quin Shea explores the need for power generated with coal and the advanced technologies that will generate that power more efficiently and cleanly in the future. The article considers the air and waste challenges of using coal, including progress toward reducing emissions of SO{sub 2}, NOx, and mercury; efforts to address CO{sub 2}, including voluntary programs like the Climate Challenge, Power Partners, and the Asia-Pacific Partnership on Clean Development and Climate; and the regulation and beneficial use of coal-combustion byproducts (e.g., fly ash, bottom ash, flue gas desulfurization materials, boiler slag). 17 refs.

  16. Advanced concepts in coal liquefaction: Optimization of reactor configuration in coal liquefaction. Final report

    SciTech Connect

    Pradhan, V.R.; Comolli, A.G.; Lee, L.K.

    1994-11-01

    The overall objective of this Project was to find the ways to effectively reduce the cost of coal liquids to about dollar 25 per barrel of crude oil equivalent. The work described herein is primarily concerned with the testing at the laboratory scale of three reactor configuration concepts, namely (1) a fixed-bed plug-flow reactor as a ``finishing reactor`` in coal liquefaction, (2) three-stage well-mixed reactors in series, and (3) interstage stream concentration/product separation. The three reactor configurations listed above were tested during this project using a 20 cc tubing microreactor, a fixed-bed plug flow reactor, and a two-stage modified Robinson-Mahoney reactor system. The reactor schemes were first evaluated based on theoretical modelling studies, then experimentally evaluated at the microautoclave level and laboratory scale continuous operations. The fixed-bed ``finishing reactor`` concept was evaluated in both the upflow and the downflow modes of operation using a partially converted coal-solvent slurry as feed. For most of the testing of concepts at the microautoclave level, simulated coal, recycle oil, and slurry feedstocks were either specially prepared (to represent a specific state of coal/resid conversion) and/or obtained from HRI`s other ongoing bench-scale and PDU scale coal liquefaction experiments. The three-stage continuous stirred tank reactors (CSTR) and interstage product stream separation/concentration concepts were tested using a simulated three-stage CSTR system by employing a laboratory-scale ebullated-bed system and a modified version of the HRI`s existing Robinson-Mahoney fixed catalyst basket reactor system. This testing was conducted as a fourteen day long continuous run, divided into four Conditions to allow for a comparison of the new three-stage CSTR and interstage product concentration concepts with a two-stage CSTR baseline configuration.

  17. Advanced coal conversion process demonstration. Technical progress report, April 1--June 30, 1996

    SciTech Connect

    1997-10-01

    This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high moisture, low rank coals to a high quality, low sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep bed stratifier cleaning process to separate the pyrite rich ash from the coal. The SynCoal process enhances low rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 Btu/lb, by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45 ton per hour unit is located adjacent to a unit train load out facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. During this report period the primary focus has been to continue the operation of the demonstration facility. Production has been going to area power plants. Modifications and maintenance work was also performed this quarter.

  18. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  19. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  20. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  1. Engineering development of advanced coal-fired low-emission boiler system

    SciTech Connect

    Not Available

    1993-02-26

    The Pittsburgh Energy Technology Center of the US Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems'' Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: NO[sub x] emissions not greater than one-third NSPS; SO[sub x] emissions not greater than one-third NSPS; and particulate emissions not greater than one-half NSPS. The specific secondary objectives are: Improved ash disposability and reduced waste generation; reduced air toxics emissions; increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

  2. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    1998-09-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean-coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 30, 1997.

  3. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    SciTech Connect

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  4. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect

    Alvin, M.A.

    2002-09-19

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  5. 78 FR 49061 - Valuation of Federal Coal for Advance Royalty Purposes and Information Collection Applicable to...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-12

    ... Applicable to All Solid Minerals Leases; Proposed Rule #0;#0;Federal Register / Vol. 78, No. 155 / Monday... Purposes and Information Collection Applicable to All Solid Minerals Leases AGENCY: Office of Natural... solid minerals leases and also are necessary to implement the EPAct Federal coal advance...

  6. Evaluation of air toxic emissions from advanced and conventional coal-fired power plants

    SciTech Connect

    Chu, P.; Epstein, M.; Gould, L.; Botros, P.

    1995-12-31

    This paper evaluates the air toxics measurements at three advanced power systems and a base case conventional fossil fuel power plant. The four plants tested include a pressurized fluidized bed combustor, integrated gasification combined cycle, circulating fluidized bed combustor, and a conventional coal-fired plant.

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  8. The fate of alkali species in advanced coal conversion systems

    SciTech Connect

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  9. Safety evaluation methodology for advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Zimmerman, W. F.

    1981-01-01

    Qualitative and quantitative evaluation methods for coal extraction systems were developed. The analysis examines the soundness of the design, whether or not the major hazards have been eliminated or reduced, and how the reduction would be accomplished. The quantitative methodology establishes the approximate impact of hazards on injury levels. The results are weighted by peculiar geological elements, specialized safety training, peculiar mine environmental aspects, and reductions in labor force. The outcome is compared with injury level requirements based on similar, safer industries to get a measure of the new system's success in reducing injuries. This approach provides a more detailed and comprehensive analysis of hazards and their effects than existing safety analyses.

  10. Advanced NMR approaches in the characterization of coal

    SciTech Connect

    Maciel, G.E.

    1992-01-01

    A considerable effort in this project during the past few months has been focussed on the development of [sup 1]H and [sup 13]C NMR imaging techniques to yield spatially-resolved chemical shift (structure) information on coal. In order to yield the chemical shift information, a solid-state NMR imaging technique must include magic-angle spinning, so rotating gradient capabilities are indicated. A [sup 13]C MAS imaging probe and a [sup 1]H MAS imaging probe and the circuitry necessary for rotating gradients have been designed and constructed. The [sup 1]H system has already produced promising preliminary results, which are briefly described in this report.

  11. ENGINEERING DEVELOPMENT OF ADVANCED PHYSICAL FINE COAL CLEANING FOR PREMIUM FUEL APPLICATIONS

    SciTech Connect

    none,

    1997-06-01

    Bechtel, together with Amax Research and Development Center (Amax R&D), has prepared this study which provides conceptual cost estimates for the production of premium quality coal-water slurry fuel (CWF) in a commercial plant. Two scenarios are presented, one using column flotation technology and the other the selective agglomeration to clean the coal to the required quality specifications. This study forms part of US Department of Energy program "Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications," (Contract No. DE-AC22- 92PC92208), under Task 11, Project Final Report. The primary objective of the Department of Energy program is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to stable and highly loaded CWF. The fuels should contain less than 2 lb ash/MBtu (860 grams ash/GJ) of HHV and preferably less than 1 lb ash/MBtu (430 grams ash/GJ). The advanced fine coal cleaning technologies to be employed are advanced column froth flotation and selective agglomeration. It is further stipulated that operating conditions during the advanced cleaning process should recover not less than 80 percent of the carbon content (heating value) in the run-of-mine source coal. These goals for ultra-clean coal quality are to be met under the constraint that annualized coal production costs does not exceed $2.5 /MBtu ($ 2.37/GJ), including the mine mouth cost of the raw coal. A further objective of the program is to determine the distribution of a selected suite of eleven toxic trace elements between product CWF and the refuse stream of the cleaning processes. Laboratory, bench-scale and Process Development Unit (PDU) tests to evaluate advanced column flotation and selective agglomeration were completed earlier under this program with selected coal samples. A PDU with a capacity of 2 st/h was designed by Bechtel and installed at Amax R

  12. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect

    Curtis, C.W.; Chander, S.; Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  13. Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Run 261 with Illinois No. 6 Burning Star Mine coal

    SciTech Connect

    Not Available

    1992-09-01

    This report presents the results of Run 261 performed at the Advanced Coal Liquefaction R & D Facility in Wilsonville, Alabama. The run started on January 12, 1991 and continued until May 31, 1991, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Illinois No. 6 seam bituminous coal (from Burning star No. 2 mine). In the first part of Run 261, a new bimodal catalyst, EXP-AO-60, was tested for its performance and attrition characteristics in the catalytic/catalytic mode of the CC-ITSL process. The main objective of this part of the run was to obtain good process performance in the low/high temperature mode of operation along with well-defined distillation product end boiling points. In the second part of Run 261, Criterion (Shell) 324 catalyst was tested. The objective of this test was to evaluate the operational stability and catalyst and process performance while processing the high ash Illinois No. 6 coal. Increasing viscosity and preasphaltenes made it difficult to operate at conditions similar to EXP-AO-60 catalyst operation, especially at lower catalyst replacement rates.

  14. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    G.H. Luttrell; G.T. Adel

    1999-01-11

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eleventh quarter of this project, Task 7 (Operation and Testing) was nearly completed through the efforts of J.A. Herbst and Associates, Virginia Tech, and Pittston Coal Company. As a result of this work, a model-based control system has now been installed which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. The system has gone through a shake-down period, training has been carried out for plant operators, and the bulk of the control logic testing has been completed with the results of these tests awaiting analysis under Task 8 (System Evaluation). The flotation model has been shown to predict incremental ash quite successfully, implying that this approach may provide the basis for a useful ''soft sensor'' for on-line incremental ash analysis.

  15. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    1998-10-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the tenth quarter of this project, Task 6 (Equipment Procurement and Installation) was completed through the efforts of J.A. Herbst and Associates, Virginia Tech, Pittston Coal Company, and FGR Automation. As a result of this work, a model-based control system is now in place which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. Testing of this control system is expected to be carried out during the next quarter, and the results of this testing will be reported in the Eleventh Quarterly report. In addition, calibration of the video-based ash analyzer was continued and an extensive set of calibration data were obtained showing that the plant is running remarkably well under manual control. This may be a result of increased attention being paid to froth flotation as a result of this project.

  16. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This is being accomplished by utilization the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. 31 figs., 22 tabs.

  17. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Not Available

    1990-05-01

    The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star Mine coal Wyodak Clovis Point Mine coal were processed. Cobalt-molybdenum and disposable iron-oxide catalysts were used to improve coal liquefaction reactions and nickel-molybdenum catalysts were used in the hydrotreater. 28 refs., 31 figs., 13 tabs.

  18. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect

    1994-10-01

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  19. An analysis of cost effective incentives for initial commercial deployment of advanced clean coal technologies

    SciTech Connect

    Spencer, D.F.

    1997-12-31

    This analysis evaluates the incentives necessary to introduce commercial scale Advanced Clean Coal Technologies, specifically Integrated Coal Gasification Combined Cycle (ICGCC) and Pressurized Fluidized Bed Combustion (PFBC) powerplants. The incentives required to support the initial introduction of these systems are based on competitive busbar electricity costs with natural gas fired combined cycle powerplants, in baseload service. A federal government price guarantee program for up to 10 Advanced Clean Coal Technology powerplants, 5 each ICGCC and PFBC systems is recommended in order to establish the commercial viability of these systems by 2010. By utilizing a decreasing incentives approach as the technologies mature (plants 1--5 of each type), and considering the additional federal government benefits of these plants versus natural gas fired combined cycle powerplants, federal government net financial exposure is minimized. Annual net incentive outlays of approximately 150 million annually over a 20 year period could be necessary. Based on increased demand for Advanced Clean Coal Technologies beyond 2010, the federal government would be revenue neutral within 10 years of the incentives program completion.

  20. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  1. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation'', to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  2. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  3. Advanced turbine design for coal-fueled engines

    SciTech Connect

    Wagner, J.H.; Johnson, B.V.

    1993-04-01

    The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

  4. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  5. Advanced coal-liquefaction research. Technical progress report, August 1, 1982-December 31, 1982

    SciTech Connect

    Not Available

    1983-07-01

    This report describes progress on the Advanced Coal-Liquefaction Project by the Gulf Research and Development Company's Merriam Laboratory. It was demonstrated that all oil products from the SRC II Processing of Powhatan No. 3 (Pittsburgh seam), Elkol-Sorensen or Belle Ayr coals boiling above 270/sup 0/C (518/sup 0/F) can be recycled to extinction. There was no loss in liquid yield, no increase in gas make and no significant change in hydrogen requirement. It has also been demonstrated that the net C/sub 5/-270/sup 0/C (518/sup 0/F) product is inactive in the Ames test and presumably poses substantially less threat than the conventional product as a potential carcinogen. The potential impact of coal cleaning and pyrite addition on liquefaction were determined with a high-reactivity Pittsburgh seam coal from the Ireland Mine. The results indicate that deep cleaning (to 6-8 wt % ash) by heavy media separation with add back of pyrite would give a better yield structure than the normal cleaning (to 12 wt % ash) envisioned for liquefaction plants. Screening of feedstocks for liquefaction processes was extended to the low-ash (5 wt % MF basis), subbituminous Elkol-Sorensen coal. Although the low ash content allowed increased recycle of bottoms product, the relatively low reactivity of the organic matrix resulted in a lower oil yield than with subbituminous Belle Ayr coal. A simulation of staged liquefaction was carried out by preparing filtrate in the SRC I mode and then studying the production of gas and distillate at lower temperature (420/sup 0/C, 788/sup 0/F) using a molybdenum emulsion catalyst. Distillate yields were low (29 wt %, based on MF coal) compared to single-stage, high temperature runs. Multiple-pass operations indicated no mechanistic barriers to high distillate yields although reaction rates were unacceptably low at the conditions employed in these preliminary experiments.

  6. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect

    Not Available

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  7. Advanced coal-fueled industrial cogeneration gas turbine system: Hot End Simulation Rig

    SciTech Connect

    Galica, M.A.

    1994-02-01

    This Hot End Simulation Rig (HESR) was an integral part of the overall Solar/METC program chartered to prove the technical, economic, an environmental feasibility of a coal-fueled gas turbine, for cogeneration applications. The program was to culminate in a test of a Solar Centaur Type H engine system operated on coal slurry fuel throughput the engine design operating range. This particular activity was designed to verify the performance of the Centaur Type H engine hot section materials in a coal-fired environment varying the amounts of alkali, ash, and sulfur in the coal to assess the material corrosion. Success in the program was dependent upon the satisfactory resolution of several key issues. Included was the control of hot end corrosion and erosion, necessary to ensure adequate operating life. The Hot End Simulation Rig addressed this important issue by exposing currently used hot section turbine alloys, alternate alloys, and commercially available advanced protective coating systems to a representative coal-fueled environment at turbine inlet temperatures typical of Solar`s Centaur Type H. Turbine hot end components which would experience material degradation include the transition duct from the combustor outlet to the turbine inlet, the shroud, nozzles, and blades. A ceramic candle filter vessel was included in the system as the particulate removal device for the HESR. In addition to turbine material testing, the candle material was exposed and evaluated. Long-term testing was intended to sufficiently characterize the performance of these materials for the turbine.

  8. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

    SciTech Connect

    Zauderer, B.; Fleming, E.S.

    1991-08-30

    This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

  9. Regional price targets appropriate for advanced coal extraction. [Forecasting to 1985 and 2000; USA; Regional analysis

    SciTech Connect

    Terasawa, K.L.; Whipple, D.W.

    1980-12-01

    The object of the study is to provide a methodology for predicting coal prices in regional markets for the target time frames 1985 and 2000 that could subsequently be used to guide the development of an advanced coal extraction system. The model constructed for the study is a supply and demand model that focuses on underground mining, since the advanced technology is expected to be developed for these reserves by the target years. The supply side of the model is based on coal reserve data generated by Energy and Environmental Analysis, Inc. (EEA). Given this data and the cost of operating a mine (data from US Department of Energy and Bureau of Mines), the Minimum Acceptable Selling Price (MASP) is obtained. The MASP is defined as the smallest price that would induce the producer to bring the mine into production, and is sensitive to the current technology and to assumptions concerning miner productivity. Based on this information, market supply curves can then be generated. On the demand side of the model, demand by region is calculated based on an EEA methodology that emphasizes demand by electric utilities and demand by industry. The demand and supply curves are then used to obtain the price targets. This last step is accomplished by allocating the demands among the suppliers so that the combined cost of producing and transporting coal is minimized.

  10. Carbon formation and metal dusting in advanced coal gasification processes

    SciTech Connect

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  11. An Advanced Control System for Fine Coal Floatation

    SciTech Connect

    Luttrell, G H; Adel, G T

    1998-06-01

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eighth quarter of this project, the analysis of data collected during Task 2 (Sampling and Data Analysis) was completed, and significant progress was made on Task 3 (Model Building and Computer Simulation). Previously, a plant sampling campaign had been conducted at Pittston's Moss No. 3 preparation plant to provide data for the development of a mathematical process model and a model-based control system. During this campaign, a one-half factorial design experiment, blocked into low and high feed rates, was conducted to investigate the effects of collector, frother, and pulp level on model parameters. In addition, samples were collected during the transient period following each change in the manipulated variables to provide data for confirmation of the dynamic process simulator. A residence time distribution (RTD) test was also conducted to estimate the mean residence time. This is a critical piece of information since no feed flowrate measurement is available, and the mean residence time can be used to estimate the feed flowrate. Feed samples were taken at timed intervals and floated in a laboratory flotation cell to investigate the magnitude of feed property disturbances and their duration.

  12. An Advanced Control System For Fine Coal Flotation

    SciTech Connect

    G. H. Luttrell; G. T. Adel

    1998-08-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the ninth quarter of this project, Task 3 (Model Building and Computer Simulation) and Task 4 (Sensor Testing) were nearly completed, and Task 6 (Equipment Procurement and Installation) was initiated. Previously, data collected from the plant sampling campaign (Task 2) were used to construct a population balance model to describe the steady-state and dynamic behavior of the flotation circuit. The details of this model were presented in the Eighth Quarterly Technical Progress Report. During the past quarter, a flotation circuit simulator was designed and used to evaluate control strategies. As a result of this work, a model-based control strategy has been conceived which will allow manipulated variables to be adjusted in response to disturbances to achieve a target incremental ash value in the last cell of the bank. This will, in effect, maximize yield at an acceptable product quality. During this same period, a video-based ash analyzer was installed on the flotation tailings stream at the Moss No. 3 preparation plant. A preliminary calibration curve was established, and data are continuing to be collected in order to improve the calibration of the analyzer.

  13. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development's facility near Beverly, Ohio. OCDO's facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  14. Evaluation of ADAM/1 model for advanced coal-extraction concepts

    SciTech Connect

    Deshpande, G. K.; Gangal, M. D.

    1982-01-15

    The Advanced Coal Extraction Project is sponsored by the Department of Energy at the Jet Propulsion Laboratory to define and develop advanced underground coal extraction systems which: (1) are suitable for significant remaining resources after the year 2000, and (2) promise a significant improvement in production cost and miner safety, with no degradation in miner health, environmental quality and resource recovery. System requirements in the five performance areas have been defined by Goldsmith and Lavin (1980). Several existing computer programs for estimating life-cycle cost of mining systems have been evaluated. A commercially available program ADAM/1 was found to be satisfactory in relation to the needs of the Advanced Coal Extraction Project. Two test cases were run to confirm the ability of the program to handle non-conventional mining equipment and procedures. The results were satisfactory. The model, therefore, is recommended to the project team for evaluation of their conceptual designs. Since the model is commercially available, data preparation instructions are not reproduced in this document; instead the reader is referred to the original documents for this information.

  15. Advanced coal liquefaction research. Technical progress report, January 1-April 30, 1984

    SciTech Connect

    Not Available

    1984-07-01

    The significant improvement in product quality reported last year for bituminous and subbituminous coals has been demonstrated with lignite. As discussed previously, use of a vapor-phase hydrotreater and recycle of all heavy distillate advances the SRC II process far beyond that envisioned for the original demonstration plant. As with the other coal ranks, all net distillate product from the lignite boils below 345/sup 0/C (653/sup 0/F) and has a nitrogen concentration on the order of 1 ppM. It was also confirmed that the Texas Big Brown lignite can be processed successfully in this mode without added catalyst. Both subbituminous Belle Ayr and bituminous Illinois No. 6 coals were processed in an integrated two-stage mode, without depressurization or solids separation between stages. Operation was relatively smooth with a fixed-bed second stage employing a high-void-volume (star-shaped) catalyst support, which was operated upflow. There was no evidence that H/sub 2/S addition improved yields with Belle Ayr coal and added pyrite or that H/sub 2/S could be used in place of pyrite to catalyze the reaction. 84 figures, 6 tables.

  16. Development of advanced capitalism: a case study of retired coal miners in southern West Virginia

    SciTech Connect

    Legeay, S.P.

    1980-01-01

    This dissertation develops a critical analysis of changes in American society during the last fifty years. It is focused in particular on the southern West Virginia coal fields, and examines the changes in class structure (specifically, coal miners), the labor process, the union, class consciousness, community and leisure. The study is grounded within a theoretical perspective that is dialectical. It is concerned with the interaction between specific social categories (such as the union) and the greater whole of capitalist development. It is centrally concerned with continuing a research orientation to which the Frankfurt School gave a powerful contribution: the development of advanced capitalism in the modern epoch. The study utilizes life-history interviews with retired coal miners, almost all of whom had experience with the exploitive company towns of an earlier time. Thus, techniques for the study of oral history are instrumental in developing an analysis of social developments, inasmuch as they provide data appropriate for an analysis of the transformation from early to late capitalism. Finally, this dissertation examines a problem central to dialectical theory, that of the relation between theory and praxis, by approaching the life histories as exemplifications of collective (i.e., social) experience. It integrates the biographical experience of individual miners with the theoretical dimensions of political economy in early and late capitalism. The current crisis in the coal fields is examined, with a view to possible transformation.

  17. Engineering development of advance physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Jha, M.C.; Smit, F.J.; Shields, G.L.

    1995-11-01

    The objective of this project is to develop the engineering design base for prototype fine coal cleaning plants based on Advanced Column Flotation and Selective Agglomeration processes for premium fuel and near-term applications. Removal of toxic trace elements is also being investigated. The scope of the project includes laboratory research and bench-scale testing of each process on six coals followed by design, construction, and operation of a 2 tons/hour process development unit (PDU). Three coals will be cleaned in tonnage quantity and provided to DOE and its contractors for combustion evaluation. Amax R&D (now a subsidiary of Cyprus Amax Mineral Company) is the prime contractor. Entech Global is managing the project and performing most of the research and development work as an on-site subcontractor. Other participants in the project are Cyprus Amax Coal Company, Arcanum, Bechtel, TIC, University of Kentucky and Virginia Tech. Drs. Keller of Syracuse and Dooher of Adelphi University are consultants.

  18. Requirements for the conceptual design of advanced underground coal-extraction systems

    SciTech Connect

    Gangal, M.D.; Lavin, M.L.

    1981-12-15

    This document presents conceptual design requirements for underground coal mining systems having substantially improved performance in the areas of production cost and miner safety. Mandatory performance levels are also set for miner health, environmental impact, and coal recovery. In addition to mandatory design goals and constraints, the document identifies a number of desirable system characteristics which must be assessed in terms of their impact on production cost and their compatibility with other system elements. Although developed for the flat-lying, moderately thick seams of Central Appalachia, these requirements are designed to be easily adaptable to other coals. This document results from the initial phase of a program to define, develop, and demonstrate advanced equipment suitable for the resources remaining beyond the year 2000. The requirements developed are meant to implement the broad systems performance goals formulated by Goldsmith and Lavin (1980) by providing a rational point of departure for the design of underground mining systems with emphasis on Central Appalachian coals. Because no one has yet attempted to design to these requirements, they may contain some inconsistencies and need clarification in some areas. Accordingly, the authors would very much appreciate commments and suggestions from those who have used or critically reviewed these requirements.

  19. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    SciTech Connect

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  20. Seal evaluation and confinement screening criteria for beneficial carbon dioxide storage with enhanced coal bed methane recovery in the Pocahontas Basin, Virginia

    USGS Publications Warehouse

    Grimm, R.P.; Eriksson, K.A.; Ripepi, N.; Eble, C.; Greb, S.F.

    2012-01-01

    The geological storage of carbon dioxide in Appalachian basin coal seams is one possible sink for sequestration of greenhouse gases, with the added benefit of enhanced-coal bed methane (ECBM) recovery. The Pocahontas Basin (part of the central Appalachian Basin) of southwestern Virginia is a major coal bed methane (CBM) province with production mostly from coal beds in the Lower Pennsylvanian Pocahontas and New River formations. As part of the Southeast Regional Carbon Sequestration Partnership's Phase II research program, a CO 2-injection demonstration well was installed into Lower Pennsylvanian coal bed-methane producing strata in southwest Virginia. Samples of siliciclastic lithologies above coal beds in this Oakwood Field well, and from several other cores in the Nora Field were taken to establish a baseline of the basic confinement properties of overlying strata to test seal competency at local and regional scales.Strata above CBM-producing coal beds in the Pocahontas and New River formations consist of dark-gray shales; silty gray shales; heterolithic siltstones, sandstones, and shales; lithic sandstones, and quartzose sandstones. Standard measurements of porosity, permeability and petrography were used to evaluate potential leakage hazards and any possible secondary storage potential for typical lithologies. Both lithic- and quartz-rich sandstones exhibit only minor porosity, with generally low permeability (<0.042mD). Interconnected porosity and permeability are strongly impacted by diverse cementation types and compaction. Analyzed siliciclastic lithologies are considered tight, with limited primary matrix permeability risks for leakage, providing an ensemble of redundant CO 2-ECBM traps.One of the most promising confining intervals above the major coal bed-methane producing interval is the Hensley Shale Member. Analyses of 1500 geophysical logs in southwest Virginia indicate that this unit is moderately thick (>50ft, 15m), laterally continuous (>3000km 2

  1. Advanced solids NMR studies of coal structure and chemistry. Progress report, September 1, 1995--February 28, 1996

    SciTech Connect

    Zilm, K.W.

    1996-09-01

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utilization of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. Our goals are twofold. First, we are interested in developing new methods that will enable us to measure important structural parameters in whole coals not directly accessible by other techniques. In parallel with these efforts we will apply these NMR methods in a study of the chemical differences between gas-sourcing and oil-sourcing coals. The NMR methods work will specifically focus on determination of the number and types of methylene groups, determination of the number and types of methine groups, identification of carbons adjacent to nitrogen and sites with exchangeable protons, and methods to more finely characterize the distribution of hydrogen in coals. We will also develop NMR methods for probing coal macropore structure using hyperpolarized {sup 129}Xe as a probe, and study the molecular dynamics of what appear to be mobile, CH{sub 2} rich, long chain hydrocarbons. The motivation for investigating these specific structural features of coals arises from their relevance to the chemical reactivity of some types of coals. The coals to be studied and contrasted include oil-prone coals from Australia and Indonesia, those comprising the Argonne Premium Coal Sample bank, and other relevant samples.

  2. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Mohanty, M.K.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a run-of-mine coal sample collected from Amax Coal Company`s Delta Coal mine using column flotation and an enhanced gravity separator as separate units and in circuitry arrangements. The {minus}60 mesh run-of-mine sample having an ash content of about 22% was cleaned to 6% while achieving a very high energy recovery of about 87% and a sulfur rejection value of 53% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Packed-Column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  3. Performance of a high efficiency advanced coal combustor. Task 2, Pilot scale combustion tests: Final report

    SciTech Connect

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M.

    1989-12-01

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R&D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the ``primary act,`` and three further annuli for the supply of the ``secondary air.`` The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  4. Advanced NMR approaches in the characterization of coal. Final technical report, September 1, 1990--August 31, 1993

    SciTech Connect

    Maciel, G.E.

    1993-09-30

    This project addressed two main goals and one much smaller one. The main goals were (1) to improve the significance, reliability and information content in high-resolution NMR (nuclear magnetic resonance) characterization of coal samples and (2) to develop chemically informative NMR imaging techniques for coal. The minor goal was to explore advanced features of dynamic nuclear polarization (DNP) as a technique for coal characterization; this included the development of two DNP probes and the examination of DNP characteristics of various carbonaceous samples, including coals. {sup 13}C NMR advances for coal depended on large-sample MAS devices, employing either cross-polarization (CP) or direct polarization (DP) approaches. CP and DP spin dynamics and their relationships to quantitation and spin counting were elucidated. {sup 1}H NMR studies, based on CRAMPS, dipolar dephasing and saturation with perdeuteropyridine, led to a {sup 1}H NMR-based elucidation of chemical functionality in coal. {sup 1}H and {sup 13}C NMR imaging techniques, based on magic-angle spinning and rotating magnetic field gradients, were developed for introducing chemical shift information (hence, chemical detail) into the spatial imaging of coal. The TREV multiple-pulse sequence was found to be useful in the {sup 1}H CRAMPS imaging of samples like coal.

  5. Coal Research

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Coal slurries are "clean" pulverized coal mixed with oil or water. Significant fuel savings can be realized when using coal slurries. Advanced Fuels Technology (AFT) utilized a COSMIC program, (Calculation of Complex Chemical Equilibrium Compositions), which provides specific capabilities for determining combustion products. The company has developed a cleaning process that removes much of the mineral sulphur and ash from the coals.

  6. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    SciTech Connect

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  7. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-06-01

    This sixteenth quarterly report describes work done during the sixteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, and making and responding to several outside contacts.

  8. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-04-28

    This thirteenth quarterly report describes work done during the thirteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to a number of outside contacts.

  9. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  10. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-01-01

    This seventeenth quarterly report describes work done during the seventeenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, submitting a manuscript and making and responding to one outside contact.

  11. Monolithic solid oxide fuel cell technology advancement for coal- based power generation. Quarterly report, December 1991

    SciTech Connect

    Not Available

    1992-01-15

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  12. Monolithic solid oxide fuel cell technology advancement for coal- based power generation

    SciTech Connect

    Not Available

    1992-01-15

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  13. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-11

    This fifteenth quarterly report describes work done during the fifteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to several outside contacts.

  14. Treatment of metal-laden hazardous wastes with advanced Clean Coal Technology by-products

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-04-12

    This twelfth quarterly report describes work done during the twelfth three-month period of the University of Pittsburgh's project on the ``Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to a number of outside contacts.

  15. Treatment of metal-laden hazardous wastes with advanced Clean Coal Technology by-products

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini; Wiles Elder

    1999-04-05

    This eleventh quarterly report describes work done during the eleventh three-month period of the University of Pittsburgh's project on the ``Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to two outside contacts.

  16. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    SciTech Connect

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  17. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, X.H.; Leonard, J.W.; Parekh, B.K.; Jiang, C.L.

    1992-01-01

    This is the 9th quarterly technical progress report for the project entitled Pyrite surface characterization and control for advanced fine coal desulfurization technologies'', DE-FG22-90PC90295. The work presented in this report was performed from September 1, 1992 to November 31, 1992. The objective of the project is to conduct extensive fundamental studies on the surface chemistry of pyrite oxidation and flotation and to understand how the alteration of the coal-pyrite surface affects the efficiency of pyrite rejection in coal flotation. During this reporting period, the surface oxidation of pyrite in various electrolytes was investigated. It has been demonstrated, for the first time, that borate, a pH buffer and electrolyte used by many previous investigators in studying sulfide mineral oxidation, actively participates in the surface oxidation of pyrite. In borate solutions, the surface oxidation of pyrite is tronly enhanced. The anodic oxidation potential of pyrite is lowered by more than 0.4 volts. The initial reaction of the borate enhanced pyrite oxidation can be described by:FeS[sub 2] + B(OH)[sub 4][sup =] ------> [S[sub 2]Fe-B(OH)[sub 4

  18. Recent advances in large-eddy simulation of spray and coal combustion

    NASA Astrophysics Data System (ADS)

    Zhou, L. X.

    2013-07-01

    Large-eddy simulation (LES) is under its rapid development and is recognized as a possible second generation of CFD methods used in engineering. Spray and coal combustion is widely used in power, transportation, chemical and metallurgical, iron and steel making, aeronautical and astronautical engineering, hence LES of spray and coal two-phase combustion is particularly important for engineering application. LES of two-phase combustion attracts more and more attention; since it can give the detailed instantaneous flow and flame structures and more exact statistical results than those given by the Reynolds averaged modeling (RANS modeling). One of the key problems in LES is to develop sub-grid scale (SGS) models, including SGS stress models and combustion models. Different investigators proposed or adopted various SGS models. In this paper the present author attempts to review the advances in studies on LES of spray and coal combustion, including the studies done by the present author and his colleagues. Different SGS models adopted by different investigators are described, some of their main results are summarized, and finally some research needs are discussed.

  19. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1991-01-01

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no new'' reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1991-01-01

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  1. Measurement and modeling of advanced coal conversion processes, Volume I, Part 1. Final report, September 1986--September 1993

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1995-09-01

    The objective of this program was the development of a predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. The foundation to describe coal specific conversion behavior was AFR`s Functional Group and Devolatilization, Vaporization and Crosslinking (DVC) models, which had been previously developed. The combined FG-DVC model was integrated with BYU`s comprehensive two-dimensional reactor model for combustion and coal gasification, PCGC-2, and a one-dimensional model for fixed-bed gasifiers, FBED-1. Progress utilizing these models is described.

  2. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 1, October--December 1992

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy`s program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research & Development Center (Amax R&D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  3. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  4. Overall requirements for an advanced underground coal extraction system. [environment effects, miner health and safety, production cost, and coal conservation

    NASA Technical Reports Server (NTRS)

    Goldsmith, M.; Lavin, M. L.

    1980-01-01

    Underground mining systems suitable for coal seams expoitable in the year 2000 are examined with particular relevance to the resources of Central Appalachia. Requirements for such systems may be summarized as follows: (1) production cost; (2)miner safety; (3) miner health; (4) environmental impact; and (5) coal conservation. No significant trade offs between production cost and other performance indices were found.

  5. The Mulled Coal process: An advanced fine coal preparation technology used to improve the handling characteristics of fine wet coal products

    SciTech Connect

    Jamison, P.R.

    1996-12-31

    The Mulled Coal process is a simple low cost method of improving the handling characteristics of the fine wet coal. The process involves the addition of a specifically formulated reagent to fine wet coal by mixing the two together in a pug mill. The converted material (Mulled Coal) retains some of its original surface moisture, but it handles, stores and transports like dry coal. It does not cause any of the sticking, fouling, bridging and freezing problems normally associated with fine wet coal, and, unlike thermally dried fine coal, it will not rewet and it is not dusty. In the process, large (baseball size) loosely bound sticky masses of fine wet coal particles are broken down into granules which are fairly uniform in the 28 Mesh x 0 size range. Due to the unique combination of the mixing action of the pug mill, the surface chemistry of the fine coal particles and the properties of the reagent; the individual granules are tightly bound, and they become completely enveloped by a very thin film of reagent. The reagent envelope will allow moisture out in the vapor stage, but it will not allow moisture back into the agglomerated granule. The envelope also prevents individual granules from adhering to or freezing to one another. The end result is a fine coal product which is free flowing, which is not dusty, and which will not rewet.

  6. Measurement and modeling of advanced coal conversion processes. Twenty-seventh quarterly report, April 1, 1993--June 30, 1993

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1993-09-01

    Significant advances have been made at Brigham Young University (BYU) in comprehensive two-dimensional computer codes for mechanistic modeling of entrained-bed gasification and pulverized coal combustion. During the same time period, significant advances have been made at Advanced Fuel Research, Inc. (AFR) in the mechanisms and kinetics of coal pyrolysis and secondary reactions of pyrolysis products. This program presents a unique opportunity to merge the technology developed by each organization to provide detailed predictive capability for advanced coal characterization techniques in conjunction with comprehensive computer models to provide accurate process simulations. The program will streamline submodels existing or under development for coal pyrolysis chemistry, volatile secondary reactions, tar formation, soot formation, char reactivity, and SO{sub x}-NO{sub x} pollutant formation. Submodels for coal viscosity, agglomeration, tar/char secondary reactions, sulfur capture, and ash physics and chemistry will be developed or adapted. The submodels will first be incorporated into the BYU entrained-bed gasification code and subsequently, into a fixed-bed gasification code (to be selected and adapted). These codes will be validated by comparison with small scale laboratory and PDU-scale experiments. Progress is described.

  7. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report: April--June 1993

    SciTech Connect

    Not Available

    1993-12-31

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. There has been considerable research on the characteristics and laboratory leaching behavior of coal wastes -- a lesser amount on wastes from advanced coal processes. However, very little information exists on the field disposal behavior of these wastes. Information on field disposal behavior is needed (a) as input to predictive models being developed, (b) as input to the development of rule of thumb design guidelines for the disposal of these wastes, and (c) as evidence of the behavior of these wastes in the natural environment.

  8. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a PCB feed sample collected from Central Illinois Power`s Newton Power Station using column flotation and an enhanced gravity separator as separate units and in a circuitry arrangement. The PCB feed sample having a low ash content of about 12% was further cleaned to 6% while achieving a very high energy recovery of about 90% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Microcel column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  9. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    SciTech Connect

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  10. Applications study of advanced power generation systems utilizing coal-derived fuels. Volume 1: Executive summary

    NASA Astrophysics Data System (ADS)

    Robson, F. L.

    1981-03-01

    The technology status of phosphoric acid and molten carbon fuel cells, combined gas and steam turbine cycles, and magnetohydrodynamic energy conversion systems was assessed and the power performance of these systems when operating with medium-Btu fuel gas whether delivered by pipeline to the power plant or in an integrated mode in which the coal gasification process and power system are closely coupled as an overall power plant was evaluated. Commercially available combined-cycle gas turbine systems can reach projected required performance levels for advanced systems using currently available technology. The phosphoric acid fuel cell appears to be the next most likely candidate for commercialization. On pipeline delivery, the systems efficiency ranges from 40.9% for the phosphoric acid fuel cell to 63% for the molten carbonate fuel cell system. The efficiencies of the integrated power plants vary from approximately 39-40% for the combined cycle to 46-47% for the molden carbonate fuel cell systems. Conventional coal-fired steam stations with flue-gas desulfurization have only 33-35% efficiency.

  11. Applications study of advanced power generation systems utilizing coal-derived fuels. Volume 1: Executive summary

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    The technology status of phosphoric acid and molten carbon fuel cells, combined gas and steam turbine cycles, and magnetohydrodynamic energy conversion systems was assessed and the power performance of these systems when operating with medium-Btu fuel gas whether delivered by pipeline to the power plant or in an integrated mode in which the coal gasification process and power system are closely coupled as an overall power plant was evaluated. Commercially available combined-cycle gas turbine systems can reach projected required performance levels for advanced systems using currently available technology. The phosphoric acid fuel cell appears to be the next most likely candidate for commercialization. On pipeline delivery, the systems efficiency ranges from 40.9% for the phosphoric acid fuel cell to 63% for the molten carbonate fuel cell system. The efficiencies of the integrated power plants vary from approximately 39-40% for the combined cycle to 46-47% for the molden carbonate fuel cell systems. Conventional coal-fired steam stations with flue-gas desulfurization have only 33-35% efficiency.

  12. Advanced coal liquefaction research. Quarterly technical progress report, April 1-June 30, 1983

    SciTech Connect

    Not Available

    1984-04-01

    Two methods of improving product quality were examined which advance the SRC II process far beyond that envisioned for the original demonstration plant. All distillate product boiling above 310/sup 0/C (590/sup 0/F) was recycled to extinction without loss of total oil yield or significant increase in hydrogen consumption. This product has substantially reduced potential for genetic damage and is more amenable to upgrading. In a further refinement, all of the overhead from the high temperature, high pressure separator was passed through a vapor-phase hydrotreater. This resulted in a dramatic improvement in product quality. A proportional blend of distillate product contained less than 1 ppM of nitrogen. Total oil yield was similar to the low quality product produced in the conventional SRC II process. Coal liquefaction was carried out in three stages to better understand how the variables affect dissolution, hydrogenation and hydrocracking steps. Short contact time dissolution of Illinois No. 6 coal was conducted with minimal hydrocarbon gas yield and hydrogen consumption and high conversion to toluene and pyridine soluble products. In the hydrogenation step, liquid yield increased as temperature was increased to 412/sup 0/C (774/sup 0/F) from 356/sup 0/C (673/sup 0/F). The hydrogen level in the products went through a maximum in the range of 380 to 400/sup 0/C (716 to 752/sup 0/F), however. Very little distillate was made in the subsequent hydrocracking step at a variety of conditions. 33 figures, 10 tables.

  13. Development of advanced NO[sub x] control concepts for coal-fired utility boilers

    SciTech Connect

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-03-04

    The complete CombiNO[sub x], process has now been demonstrated at a level that is believed to be representative of a full-scale boiler in terms of mixing capabilities. A summary of the results is displayedin Figure 5-1. While firing Illinois Coal on the Reburn Tower, Advanced Reburning was capable of reducing NO[sub x], by 83 percent. The injection of methanol oxidized 50--58 percent of the existing NO to N0[sub 2]. Assuming that 85 percent of the newly formed N0[sub 2] can be scrubbed in a liquor modified wet-limestone scrubber, the CombiNO[sub x], process has been shown capable of reducing NO[sub 2], by 90--91 percent in a large pilot-scale coal-fired furnace. There is still uncertainty regarding the fate of the N0[sub 2] formed with methanol injection. Tests should be conducted to determine whether the reconversion is thermodynamic or catalytic, and what steps can be taken (such as quench rate) to prevent it from happening.

  14. Update of progress for Phase II of B&W`s advanced coal-fired low-emission boiler system

    SciTech Connect

    McDonald, D.K.; Madden, D.A.; Rodgers, L.W.

    1995-11-01

    Over the past five years, advances in emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements in steam turbine and cycle design have significantly altered the governing criteria by which advanced technologies have been compared. With these advances, it is clear that pulverized coal technology will continue to be competitive in both cost and performance with other advanced technologies such as Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBC) technologies for at least the next decade. In the early 1990`s it appeared that if IGCC and PFBC could achieve costs comparable to conventional pulverized coal plants, their significantly reduced NO{sub x} and SO{sub 2} emissions would make them more attractive. A comparison of current emission control capabilities shows that all three technologies can already achieve similarly low emissions levels.

  15. Engineereing development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 5, October--December 1993

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1994-02-18

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. The project has three major objectives: The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  16. Engineering development of advanced coal-fired low-emissions boiler systems. Quarterly report, April 1--June 30, 1997

    SciTech Connect

    1997-12-31

    This progress report is on the project by Babcock and Wilcox Company to develop an advanced coal-fired low-emissions boiler system. The topics of the report include project management, the NO{sub x} subsystem, the SO{sub 2}/particulate/air toxics/solid by-product subsystem, boiler subsystem, balance of plant subsystem, and controls and sensors subsystems.

  17. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect

    Shen, Chen

    2014-04-01

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

  18. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect

    Not Available

    1990-08-01

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  19. The Coal-Seq III Consortium. Advancing the Science of CO2 Sequestration in Coal Seam and Gas Shale Reservoirs

    SciTech Connect

    Koperna, George

    2014-03-14

    The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3 expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was applied to

  20. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Jiang, Chengliang; Raichur, A.M.

    1992-07-14

    The objective of this project is to conduct extensive studies on the surface reactivity and surface hydrophobicity of coal-pyrites using various surface characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The flotation characteristics of coal-pyrites under various conditions was studied and compared with ore-pyrite and coal to determine the causes of pyrite rejection difficulties in coal flotation. Both the native and induced floatabilities of pyrites were investigated. It was found that both coal- and ore-pyrites, ff prepared by dry-grinding, show little or no floatability in the absence of any chemical reagents. After ultrasonic pretreatment, ore-pyrite floats effectively in the acidic to neutral pH range. Kentucky No. 9 coal-pyrite (KYPY) shows significant flotation in the pH range 7--10. With ethyl xanthate as collector, ore-pyrite floats well up to pH = 10; while coal-pyrite reveals no flotation above pH = 6. For the first time, the effect of coal collector on the floatability of coal-pyrite has been studied. It was shown that in the presence of fuel oil--a widely used collector for promoting coal flotation, coal-pyrite, particularly for the fine sizes, shows good flotation below pH = 11, whereas ore-pyrite has no or little floatability. These studies demonstrate that one of the main causes of the coal-pyrite flotation in coal separation is the oil-induced floatability due to adsorption/attachment of oil droplets on the coal-pyrite surfaces, the native'' or self-induced'' floatability of pyrite is no as profound as the oil-induced flotation.

  1. Evaluation, engineering and development of advanced cyclone processes

    SciTech Connect

    Durney, T.E.; Cook, A.; Ferris, D.D.

    1995-11-01

    This research and development project is one of three seeking to develop advanced, cost-effective, coal cleaning processes to help industry comply with 1990 Clean Air Act Regulations. The specific goal for this project is to develop a cycloning technology that will beneficiate coal to a level approaching 85% pyritic sulfur rejection while retaining 85% of the parent coal`s heating value. A clean coal ash content of less than 6% and a moisture content, for both clean coal and reject, of less than 30% are targeted. The process under development is a physical, gravimetric-based cleaning system that removes ash bearing mineral matter and pyritic sulfur. Since a large portion of the Nation`s coal reserves contain significant amounts of pyrite, physical beneficiation is viewed as a potential near-term, cost effective means of producing an environmentally acceptable fuel.

  2. Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 23, April 1, 1994--June 30, 1994

    SciTech Connect

    1995-04-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  3. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 16, July 1, 1992--September 30, 1992

    SciTech Connect

    Not Available

    1992-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  4. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  5. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, X.H.; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Jiang, C.L.

    1992-01-01

    The objective of the project is to conduct extensive fundamental studies on the surface reactivity and surface hydrophobicity of coal-pyrites using various surface characterization techniques and to understand how the alteration of the coal-pyrite surface affects the efficiency of pyrite rejection in coal flotation. During this reporting period, the influence of the impurity content, particularly coal/carbon content, on the electrochemical oxidation of pyrite surfaces was investigated. The studies demonstrate that the coal/carbon content in coal-pyrite has a determining effect on the surface reactivity of pyrite. The oxidation behavior of high carbon-content coal-pyrite is completely different from that of purer coal-pyrite and ore-pyrite. The effects of flotation gases on the flotation behavior of coal and the surface hydrophobicity of various coal-pyrite were investigated. It was found from the lab-scale column flotation studies that among the various gases studied (air, oxygen, argon, nitrogen and carbon dioxide), carbon dioxide produced the best results with a combustible recovery of 90% and ash-content of less than 9 percent. Finally, the surface energetic studies revealed that the surfaces of pyrites and coals produced by wet grinding is more heterogenous than that prepared by dry grinding.

  6. Recent advances in the use of synchrotron radiation for the analysis of coal combustion products

    SciTech Connect

    Manowitz, B.

    1995-11-01

    Two major coal combustion problems are the formation and build-up of slag deposits on heat transfer surfaces and the production and control of toxic species in coal combustion emissions. The use of synchrotron radiation for the analysis of coal combustion products can play a role in the better understanding of both these phenomena. An understanding of the chemical composition of such slags under boiler operating conditions and as a function of the mineral composition of various coals is one ultimate goal of this program. The principal constituents in the ash of many coals are the oxides of Si, Al, Fe, Ca, K, S, and Na. The analytical method required must be able to determine the functional forms of all these elements both in coal and in coal ash at elevated temperatures. One unique way of conducting these analyses is by x-ray spectroscopy.

  7. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    B.K. PAREKH; D. TAO; J.G. GROPPO

    1998-02-03

    The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

  8. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, 2 June 1992--1 June 1993

    SciTech Connect

    LeCren, L.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1993-06-01

    This program was initiated in June of 1986 because advances in coal-fueled gas turbine technology over the previous few years, together with DOE-METC sponsored studies, served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine could ultimately be the preferred system in appropriate market application sectors. In early 1991 it became evident that a combination of low natural gas prices, stringent emission limits of the Clean Air Act and concerns for CO{sub 2} emissions made the direct coal-fueled gas turbine less attractive. In late 1991 it was decided not to complete this program as planned. The objective of the Solar/METC program was to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. Component development of the coal-fueled combustor island and cleanup system while not complete indicated that the planned engine test was feasible. Preliminary designs of the engine hardware and installation were partially completed. A successful conclusion to the program would have initiated a continuation of the commercialization plan through extended field demonstration runs. After notification of the intent not to complete the program a replan was carried out to finish the program in an orderly fashion within the framework of the contract. A contract modification added the first phase of the Advanced Turbine Study whose objective is to develop high efficiency, natural gas fueled gas turbine technology.

  9. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Thomas Robl; John Groppo

    2009-06-30

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i.e. Florida

  10. Advanced direct coal liquefaction. Quarterly technical progress report No. 2, December 1983-February 1984

    SciTech Connect

    Paranjape, A.S.

    1984-04-30

    Five Bench-Scale coal liquefaction runs were completed with Wyoming subbituminous coal in a two-stage process scheme. In this process scheme, LDAR, the lighter fraction of ash-free resid, was fed to the catalytic stage prior to its recycle to the thermal stage, whereas DAR, the heavy fraction of the deashed resid, was directly recycled to the thermal stage without any intermediate processing step. The results indicate that increasing coal space rate in the dissolver resulted in lower coal conversion and reduced distillate yield in this process configuration. The coal conversions decreased from 92 wt% to 89 wt% (MAF coal) and the distillate yield was reduced from 50 wt% to less than 40 wt% (MAF coal), as the coal space velocity increased. Attempts to duplicate the yields of Run 32, at comparable process conditions in Runs 37 and 38, were unsuccessful. Several process parameters were investigated but failed to show why the yields of Run 32 could not be duplicated. Valuable process related information was gained as a result of process parameter studies completed during these runs. At comparable process conditions, coal conversions were lower by about 3 to 4 relative percent and were only in the 87 wt% (MAF coal) range. Similarly, the distillate yield was about 40 wt% (MAF coal) which is about 10 wt% lower than observed in Run 32. Although no exact cause for these results could be determined, it appeared that the H/C atomic ratio of the solvent and possibly the flow pattern (plug-flow versus back-mixed) could have affected the coal conversion and quantity of distillate product produced. A significant decrease in coal conversion of 4 to 5 wt% was observed when the disposable catalyst (iron oxide) was removed from the reaction mixture and therefore substantiates the need for a disposable catalyst in the liquefaction of Wyoming subbituminous coal.

  11. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 26, January 1, 1995--March 31, 1995

    SciTech Connect

    1995-07-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  12. Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems

    SciTech Connect

    Wang, Anbo; Pickrell, Gary

    2012-03-31

    This report summarizes technical progress on the program Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed jointly by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering and the Department of Materials Science and Engineering at Virginia Tech. This three-year project started on October 1, 2008. In the project, a fiber optical sensing system based on intrinsic Fabry-Perot Interferometer (IFPI) was developed for strain and temperature measurements for Ultra Supercritical boiler condition assessment. Investigations were focused on sensor design, fabrication, attachment techniques and novel materials for high temperature and strain measurements. At the start of the project, the technical requirements for the sensing technology were determined together with our industrial partner Alstom Power. As is demonstrated in Chapter 4, all the technical requirements are successfully met. The success of the technology extended beyond laboratory test; its capability was further validated through the field test at DOE NETL, in which the sensors yielded distributed temperature mapping of a testing coupon installed in the turbine test rig. The measurement results agreed well with prior results generated with thermocouples. In this project, significant improvements were made to the IFPI sensor technology by splicing condition optimization, transmission loss reduction, sensor signal demodulation and sensor system design.

  13. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.

    2003-09-12

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  14. Development of advanced NO sub x control concepts for coal-fired utility boilers

    SciTech Connect

    Evans, A.; Newhall, J.; England, G.; Seeker, W.R.

    1992-06-23

    CombiNO{sub x} is a NO{sub x} reduction process which incorporates three different NO{sub x} control technologies: reburning, selective non-catalytic reduction (SNCR), and methanol injection. Gas reburning is a widely used technology that has been proven to reduce NO{sub x} up to 60% on full-scale applications. The specific goals of the CombiNO{sub x} project are: 70% NO{sub x} reduction at 20% of the cost of selective catalytic reduction; NO{sub x} levels at the stack of 60 ppm for ozone non-attainment areas; Demonstrate coal reburning; Identify all undesirable by-products of the process and their controlling parameters; Demonstrate 95% N0{sub 2} removal in a wet scrubber. Before integrating all three of CombiNO{sub x}'s technologies into a combined process, it is imperative that the chemistry of each individual process is well understood. Pilot-scale SNCR tests and the corresponding computer modeling were studied in detail and discussed in the previous quarterly report. This quarterly report will present the results obtained during the pilot-scale advanced reburning tests performed on EER's Boiler Simulation Facility (BSF). Since methanol injection is a relatively new NO{sub x} control technology, laboratory-scale tests were performed to better understand the conditions at which methanol is most effective. The experimental set-up and results from these tests will be discussed.

  15. Hydrogeologic investigation of the Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Gardner, F.G.; Kearl, P.M.; Mumby, M.E.; Rogers, S.

    1996-09-01

    This document describes the geology and hydrogeology at the former Advanced Coal Liquefaction Research and Development (ACLR&D) facility in Wilsonville, Alabama. The work was conducted by personnel from the Oak Ridge National Laboratory Grand Junction office (ORNL/GJ) for the U.S. Department of Energy (DOE) Pittsburgh Energy Technology Center (PETC). Characterization information was requested by PETC to provide baseline environmental information for use in evaluating needs and in subsequent decision-making for further actions associated with the closeout of facility operations. The hydrogeologic conceptual model presented in this report provides significant insight regarding the potential for contaminant migration from the ACLR&D facility and may be useful during other characterization work in the region. The ACLR&D facility is no longer operational and has been dismantled. The site was characterized in three phases: the first two phases were an environmental assessment study and a sod sampling study (APCO 1991) and the third phase the hydraulic assessment. Currently, a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remedial investigation (RI) to address the presence of contaminants on the site is underway and will be documented in an RI report. This technical memorandum addresses the hydrogeologic model only.

  16. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 6, January--March 1994

    SciTech Connect

    Smit, F.J.; Rowe, R.M.; Anast, K.R.; Jha, M.C.

    1994-05-06

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effectve replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States as well as for advanced combustars currently under development. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals fbr clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 51-month program which started on September 30, 1992. This report discusses the technical progress, made during the 6th quarter of the project from January 1 to March 31, 1994. The project has three major objectives: (1) The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. (3) A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  17. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  18. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, January to April 1994

    SciTech Connect

    Not Available

    1994-06-01

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal solid processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. Information on field disposal behavior is needed (a) as input to predictive models being developed, (b) as input to the development of rule of thumb design guidelines for the disposal of these wastes, and (c) as evidence of the behavior of these wastes in the natural environment.This study is organized into four major Tasks. Task 1 and 2 were devoted to planning the Task 3 field study. Task 4 uses the results of the field testing to produce an Engineering Design Manual for the utilities and industrial users who manage wastes from advanced coal combustion technologies.

  19. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, May--July 1989

    SciTech Connect

    1989-12-31

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Mineral Research Center (EMRC) to design, construct and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. The specific objectives for the reporting period were as follows: review fourth site candidates; obtain site access for the Freeman United site; select an ash supplier for the Illinois site and initiate subcontracts for on-site work; commence construction of the Freeman United test cell; and obtain waste for the Colorado Ute test site. Accomplishments under each task are discussed.

  20. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri,; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-11-30

    This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grinding and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.

  1. Pelletizing/reslurrying as a means of distributing and firing clean coal

    SciTech Connect

    Conkle, H.N.

    1992-03-17

    The objective of this study is to develop technology that permits the practical and economic preparation, storage, handling, and transportation of coal pellets, which can be reslurried into Coal water fuels (CWF) suitable for firing in small- and medium-size commercial and industrial boilers, furnaces, and engines. The project includes preparing coal pellets and capsules from wet filter cake that can be economically stored, handled, transported, and reslurried into a CWF that can be suitably atomized and fired at the user site. The wet cakes studied were prepared from ultra-fine (95% -325 mesh) coal beneficiated by advanced froth-flotation techniques. The coals studied included two eastern bituminous coals, one from Virginia (Elkhorn) and one from Illinois (Illinois No. 6) and one western bituminous coal from Utah (Sky Line coal).

  2. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly progress report, July - September 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-10-01

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale. The study which is in progress is being conducted at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter laboratory dewatering studies were conducted using a 4-in diameter laboratory chemical centrifuge. The baseline data provided a filter cake with about 32% moisture. Addition of 0.3 kg/t of a cationic surfactant lowered the moisture to 29%. Addition of anionic and non-ionic surfactant was not effective in reducing the filter cake moisture content. In the pilot scale studies, a comparison was conducted between the high pressure and vacuum dewatering techniques. The base line data with high pressure and vacuum filtration provided filter cakes with 23.6% and 27.8% moisture, respectively. Addition of 20 g/t of cationic flocculent provided 21% filter cake moisture using the high pressure filter. A 15% moisture filter cake was obtained using 1.5 kg/t of non-ionic surfactant. Vacuum filter provided about 23% to 25% moisture product with additional reagents. The high pressure filter processed about 3 to 4 times more solids compared to vacuum filter.

  3. Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Malhotra, V.M.; Wright, M.A.

    1995-12-31

    The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first two quarters of the project, the thrust of the work directed towards characterizing the various coal combustion residues and FGD residue, i.e., scrubber sludge. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADK unit l-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM, unit l-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}.0.5H{sub 2}O) phase. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disk,- from coal combustion residues. This has been achieved. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites. Also, these results along with mechanical behavior of the fabricated disks lead us to believe that the combination of surface altered PCC fly ash and scrubber sludge particles, together ed ash particles are ideal for our composite materials.

  4. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 6, January--March 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-05-03

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1- March 31, 1996.

  5. Advanced technology applications for second and third generation coal gasification systems. Appendix

    NASA Technical Reports Server (NTRS)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    Sixteen coal conversion processes are described and their projected goals listed. Tables show the reactants used, products derived, typical operating data, and properties of the feed coal. A history of the development of each process is included along with a drawing of the chemical reactor used.

  6. Beneficial uses of radiation

    SciTech Connect

    Fox, M.R.

    1991-10-01

    An overall decline in technical literacy within the American public has come at a time when technological advances are accelerating in the United States and around the world. This had led to a large communication gulf between the general public and the technologists. Nowhere is this more evident then with the topic of radiation. Regrettably, too few people know about sources of radiation, the pervasiveness, amounts, and variabilities, and do not have a true understanding of the environment in which we live. Nor do many people know that radiation has been used in beneficial ways for decades around the world. While the general public does not know of the scientific applications to which radiation has been deployed, it nevertheless had benefited tremendously from these efforts. Thanks to the well know properties of radiation, scientific ingenuity has found many uses of radiation in chemical and agricultural research, biomedical research, in the diagnoses and treatment of hundreds of types of diseases, in industrial applications, food irradiation, and many others. This paper provides a sample of the types of uses to which radiation has been used to help advance the betterment of humankind.

  7. Advanced treatment of biologically pretreated coal gasification wastewater using a novel anoxic moving bed biofilm reactor (ANMBBR)-biological aerated filter (BAF) system.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Zhao, Qian; Hou, Baolin

    2014-04-01

    A novel system integrating anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) with short-cut biological nitrogen removal (SBNR) process was investigated as advanced treatment of real biologically pretreated coal gasification wastewater (CGW). The results showed the system had efficient capacity of degradation of pollutants especially nitrogen removal. The best performance was obtained at hydraulic residence times of 12h and nitrite recycling ratios of 200%. The removal efficiencies of COD, total organic carbon, NH4(+)-N, total phenols and total nitrogen (TN) were 74.6%, 70.0%, 85.0%, 92.7% and 72.3%, the corresponding effluent concentrations were 35.1, 18.0, 4.8, 2.2 and 13.6mg/L, respectively. Compared with traditional A(2)/O process, the system had high performance of NH4(+)-N and TN removal, especially under the high toxic loading. Moreover, ANMBBR played a key role in eliminating toxicity and degrading refractory compounds, which was beneficial to improve biodegradability of raw wastewater for SBNR process.

  8. Coal recovery process

    DOEpatents

    Good, Robert J.; Badgujar, Mohan

    1992-01-01

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  9. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, Xiang-Huai.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  10. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Jiang, Chengliang.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof will lead to identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  11. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, Xiang-Huai.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surfaces reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of the pyrite rejection in coal flotation. The product as well as their structure, the mechanism and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc., are directed at identifying the cause and possible solutions of the pyrite rejection problems in coal cleaning.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 3, April--June 1993

    SciTech Connect

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-07-28

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the quarter from April 1 to June 30, 1993. The project has three major objectives: (1) the primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) a secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics; and (3) a third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  13. Measurement and modeling of advanced coal conversion processes. Twenty-second quarterly report, January 2, 1992--March 31, 1992

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1992-12-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO{sub x}-NO{sub x} submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  14. Advanced direct coal liquefaction concepts. Quarterly report, April 1, 1993--June 30, 1993

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L. |

    1993-11-01

    Construction and commissioning of the bench unit for operation of the first stage of the process was completed. Solubilization of Black Thunder coal using carbon monoxide and steam was successfully demonstrated in the counterflow reactor system. The results were comparable with those obtained in the autoclave with the exception that coal solubilization at the same nominal residence times was slightly lower. The bench unit has now been modified for two stage operation. The Wilsonville process derived solvent for Black Thunder coal (V-1074) was found to be essentially as stable as the previous solvent used in the autoclave runs (V-178 + 320) at reactor conditions. This solvent (V-1074) is, therefore, being used in the bench unit tests. Carbon monoxide may be replaced by synthesis gas for the coal solubilization step in the process. However, in autoclave tests, coal conversion was found to be dependent on the amount of carbon monoxide present in the synthesis gas. Coal conversions ranged from 88% for pure carbon monoxide to 67% for a 25:75 carbon monoxide/hydrogen mixture at equivalent conditions. Two stage liquefaction tests were completed in the autoclave using a disposable catalyst (FeS) and hydrogen in the second stage. Increased coal conversion, higher gas and oil and lower asphaltene and preasphaltene yields were observed as expected. However, no hydrogen consumption was observed in the second stage. Other conditions, in particular, alternate catalyst systems will be explored.

  15. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Munirathinam, M.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. Four high quality coal pyrite samples from the Illinois No. 6, Kentucky No. 9, Pittsburgh No. 8 and Upper Freeport coal seams, and several high purity mineral pyrite samples were acquired. Synthetic single pyrite crystals (5 mm in size) and microcrystalline pyrite particles (averaging 6 {mu}m in size) were carefully obtained. Surface hydrophobicities of coal- and ore-pyrites have been studied by contact angle titration and film flotation methods. The oxidation and reduction behavior of coal-pyrites, ore-pyrites and synthetic pyrite single crystals have been studied suing electrochemical methods, including cyclic voltammetry, rotating-disc electrode technique, open-circuit potential measurements and steady-polarization measurements. 7 refs., 14 figs.

  16. Requirements for the conceptual design of advanced underground coal extraction systems

    NASA Astrophysics Data System (ADS)

    Gangal, M. D.; Lavin, M. L.

    1981-12-01

    Conceptual design requirements are presented for underground coal mining systems having substantially improved performance in the areas of production cost and miner safety. Mandatory performance levels are also set for miner health, environmental impact, and coal recovery. In addition to mandatory design goals and constraints, a number of desirable system characteristics are identified which must be assessed in terms of their impact on production cost and their compatibility with other system elements. Although developed for the flat lying, moderately thick seams of Central Appalachia, these requirements are designed to be easily adaptable to other coals.

  17. Requirements for the conceptual design of advanced underground coal extraction systems

    NASA Technical Reports Server (NTRS)

    Gangal, M. D.; Lavin, M. L.

    1981-01-01

    Conceptual design requirements are presented for underground coal mining systems having substantially improved performance in the areas of production cost and miner safety. Mandatory performance levels are also set for miner health, environmental impact, and coal recovery. In addition to mandatory design goals and constraints, a number of desirable system characteristics are identified which must be assessed in terms of their impact on production cost and their compatibility with other system elements. Although developed for the flat lying, moderately thick seams of Central Appalachia, these requirements are designed to be easily adaptable to other coals.

  18. Advanced pulverized coal combustor for control of NO/sub x/ emissions. First quarterly report, September 24-December 24, 1980

    SciTech Connect

    Pam, R.; Chu, E. K.; Kelly, J. T.

    1981-01-30

    The first quarter results under the Advanced Pulverized Coal Combustor for Control of NO/sub x/ Emissions Program (DOE Contract DE-AC22-80PC30296) are reported. A preliminary gas phase reaction model for predicting fuel NO/sub x/ formation during combustion of methane fuel has been constructed. Predictions of NO/sub x/ formation under stirred reactor conditions agree with existing experimental data. Thermal NO/sub x/ and coal reaction data will be developed and verified during the next reporting period. Progress has been made in formulating the changes necessary to upgrade the Acurex PROF code for use as the comprehensive data analysis tool in this program. The radiation modeling and the incorporation of the needed modifications into the PROF code will occur during the next reporting period. The idealized combustor was designed, and requests for bids to fabricate the combustor were submitted. Combustor fabrication will be completed during the next reporting period.

  19. Coal combustion science

    SciTech Connect

    Hardesty, D.R.; Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  20. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    SciTech Connect

    Not Available

    1989-12-31

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  1. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 18, January 1, 1993--March 31, 1993

    SciTech Connect

    Not Available

    1993-07-01

    This task is the actual demonstration of the advanced froth flotation technology. All previous work has led to this task. ICF KE technicians and process engineers from the team will operate the plant over a 10 month period to demonstrate the capability of the technology to remove 85% of the pyritic sulfur from three different test coals while recovering at least 85% of the as-mined coal`s energy content. Six major subtasks have been included to better define the overall work scope for this task. The ICF KE team will test the Pittsburgh No. 8 seam, the Illinois No. 6 seam and the Upper Freeport seam; the team will operate the circuit in a continuous run; the team will analyze all samples generated in those runs and will develop a plan to store and dispose of the coal and refuse products. All laboratory data generated will be accessible to all team members and the DOE. The test program for the Pittsburgh No. 8 coal began during March 1, 1993. An arrangement has been made between ICF Kaiser Engineers (ICF KE) and American Electric Power (AEP), who is the host for the DOE POC facility. The arrangement calls for AEP to purchase the raw coal and use the clean coal generated by the DOE POC facility. This arrangement permits the processing of raw coal at a very minimal cost of purchasing the raw coal.

  2. Advanced direct coal liquefaction concepts. Quarterly report, January 1, 1993--March 31, 1993

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L.

    1993-07-01

    Five barrels of a Wilsonville process derived solvent (V-1074) from Black Thunder coal were obtained. This material boils within the preferred gas oil range, is more aromatic than previous solvents, and will therefore be used for the bench unit studies. Several repeat runs were performed in the autoclave to confirm the results of the matrix study. In addition, runs were carried out with different catalysts, with agglomerates and with the V-1074 solvent. The results of the autoclave runs were analyzed with respect to coal conversion, CO conversion, oil yield, hydrogen consumption and oxygen removal. It was concluded that the best operating conditions for the first stage operation was a temperature of at least 390{degrees}C, residence time of at least 30 minutes, cold CO pressure of at least 600 psig and potassium carbonate catalyst (2% wt on total feed). The data also indicated however, that the coal conversion goes through a maximum, and too high a severity leads to retrograde reaction and lower coal solubilization. The scope for increasing temperature and time is therefore limited. Petrographic examination of the THF insoluble resids from the autoclave program indicated a maximum coal conversion of about 90% for Black Thunder coal. The bench unit construction was also essentially completed and the bench unit program to be carded out in the next twelve months was defined.

  3. Recovery of ultra fine bituminous coal from screen-bowl centrifuge effluent: A possible feedstock for coal-water slurry fuels?

    SciTech Connect

    Morrison, J.L.; Miller, B.G.; Battista, J.J.

    1998-04-01

    Coal fines have historically been viewed as a size fraction which are difficult to handle and expensive to clean and dewater. Consequently, many coal suppliers in the past have chosen to discard their coal fines in slurry impoundments rather than beneficiating them. These disposal costs are then passed onto the end user. Today, with the advent of advanced fine coal cleaning technologies, more stringent environmental policies, and increased pressure by coal-fired utilities to reduce their operating costs, the industry is taking a more progressive look at fine coal recovery options. This paper discusses a fine coal recovery project which is currently being conducted at the Homer City Coal Cleaning Plant (HCCCP) located in western Pennsylvania. The HCCCP utilizes heavy media cyclone, spiral, and conventional froth flotation circuits to clean approximately 4.3 million tons of low to medium volatile bituminous coal annually for the adjacent 1,884 net MW{sub e} Homer City Generating Station. The project focuses on recovering minus 325 mesh coal fines from the effluent of screen-bowl centrifuges. The HCCCP screen-bowl effluent contains approximately 3 to 5 wt.% of suspended coal fines. Approximately 100,000 tons of coal fines are estimated to be lost per year. These coal fines represent a Btu loss, require flocculent prior to the static thickeners and belt presses, contribute excess moisture to the plant refuse which leads to handling and compaction problems during refuse disposal, and contribute to the premature filling of the refuse site.

  4. Recovery of ultra fine bituminous coal from screen-bowl centrifuge effluent: A possible feedstock for coal-water slurry fuels?

    SciTech Connect

    Morrison, J.L.; Miller, B.G.; Battista, J.J.

    1998-07-01

    Coal fines have historically been viewed as a size fraction which are difficult to handle and expensive to clean and dewater. Consequently, many coal suppliers in the past have chosen to discard their coal fines in slurry impoundments rather than beneficiating them. These disposal costs are then passed onto the end user. Today, with the advent of advanced fine coal cleaning technologies, more stringent environmental policies, and increased pressure by coal-fired utilities to reduce their operating costs, the industry is taking a more progressive look at fine coal recovery options. This paper discusses a fine coal recovery project which is currently being conducted at the Homer City Coal Cleaning Plant (HCCCP) located in western Pennsylvania. The HCCCP utilizes heavy media cyclone, spiral, and conventional froth flotation circuits to clean approximately 4.3 million tons of low to medium volatile bituminous coal annually for the adjacent 1,884 net MW{sub e} Homer City Generating Station. The project focuses on recovering minus 325 mesh coal fines from the effluent of screen-bowl centrifuges. The HCCCP screen-bowl effluent contains approximately 3 to 5 wt.% of suspended coal fines. Approximately 100,000 tons of coal fines are estimated to be lost per year. These coal fines represent a Btu loss, require flocculant prior to the static thickeners and belt presses, contribute excess moisture to the plant refuse which leads to handling and compaction problems during refuse disposal, and contribute to the premature filling of the refuse site.

  5. Advanced NMR approaches in the characterization of coal. [Quarterly] report No. 8

    SciTech Connect

    Maciel, G.E.

    1992-12-31

    The paper submitted earlier on the use of (bicyclo[3.2.1]4pyrrolidino-N-methyl-octan-8-one triflate) ({sup 13}CO-123) as a {sup 13}C intensity standard was accepted for publication. Subsequently, {sup 13}CO-321 was used in this manner for quantitative {sup 13}C CP-MAS NMR analysis (including spin counting) of Argonne Premium coals. The cross-polarization time constants, T{sub CH}, and the rotating-frame proton spin-lattice relaxation times, T{sub 1p}{sup H}, were determined for each major peak of each coal via a combination of variable contact-time and variable spin-lock (T{sub 1p}{sup H}) experiments. Two or three components of rotating-frame {sup 1}H relaxation decay and two or three components of T{sub CH} behavior were observed for each major {sup 13}C peak of each coal. These data were used to determine the number of carbon atoms detected in each coal; these values are in the range between 77% and 87% of the amount of carbon known to be in each coal from elemental analysis data, except for Pocahontas No. 3, for which only 50% of the carbon was detected. In an attempt to use {sup 1}H CRAMPS to elucidate chemical functionality in coal, pyridine-saturated samples of the Argonne Premium coals were examined in detail in terms of their {sup 1}H CRAMPS NMR spectra. These spectra were deconvoluted to yield relative concentrations for individual peaks.

  6. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 15, April--June 1996

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-07-25

    Goal is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Scope includes laboratory research and bench-scale testing on 6 coals to optimize these processes, followed by design/construction/operation of a 2-t/hr PDU. During this quarter, parametric testing of the 30-in. Microcel{trademark} flotation column at the Lady Dunn plant was completed and clean coal samples submitted for briquetting. A study of a novel hydrophobic dewatering process continued at Virginia Tech. Benefits of slurry PSD (particle size distribution) modification and pH adjustment were evaluated for the Taggart and Hiawatha coals; they were found to be small. Agglomeration bench-scale test results were positive, meeting product ash specifications. PDU Flotation Module operations continued; work was performed with Taggart coal to determine scaleup similitude between the 12-in. and 6-ft Microcel{trademark} columns. Construction of the PDU selective agglomeration module continued.

  7. Microstructural evolution in advanced boiler materials for ultra-supercritical coal power plants

    NASA Astrophysics Data System (ADS)

    Wu, Quanyan

    The goal of improving the efficiency of pulverized coal powerplants has been pursued for decades. The need for greater efficiency and reduced environmental impact is pushing utilities to ultra supercritical conditions (USC), i.e. steam temperatures approaching 760°C under a stress of 35 MPa. The long-term creep strength and environmental resistance requirements imposed by these conditions are clearly beyond the capacity of the currently used ferritic steels and other conventional alloys. As part of a large DOE-funded consortium, new and existing materials based on advanced austenitic stainless steels and nickel base superalloys are being evaluated for these very demanding applications. In the present work, the nickel base superalloys of Inconel 617, CCA617, Haynes 230 and Inconel 740, and austenitic alloys Super 304H and HR6W, were evaluated on their microstructural properties over elevated temperature ageing and creep rupture conditions. The materials were aged for different lengths of time at temperatures relevant to USC applications, i.e., in the range from 700 to 800°C. The precipitation behaviors, namely of the gamma', carbides and eta phase in some conditions in nickel base superalloys, carbides in Haynes 230, Cu-rich precipitates in Super 304H and Laves phase particles in HR6W, were studied in detail using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and related analytical techniques. Particular attention has been given on the structure, morphology and compositional distinctiveness of various phases (including gamma, gamma', carbides, secondary phase precipitates, and other types of particles) and their nature, dislocation structures and other types of defects. The results were presented and discussed in light of associated changes in microhardness in the cases of aged samples, and in close reference to mechanical testing (including tensile and creep rupture tests) wherever available. Several mechanical strengthening

  8. Advanced direct coal liquefaction concepts. Quarterly report, October 1, 1993--December 31, 1993

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L.

    1993-12-31

    Six runs on the bench unit were successfully completed this quarter. The runs covered twenty five different operating conditions and yield periods, and involved 336 hours of operation. In the bench unit, increased temperature of first stage operation (410{degree}C) and direct addition of the powdered solid sodium aluminate to the feed as first stage catalyst improved both coal and carbon monoxide conversion. To achieve 90%+ overall coal conversion, temperatures of 430{degree}C+ were required in the second stage. Oil yields (pentane soluble liquid product) in excess of 65 wt % based on MAF Black Thunder coal, were achieved both with iron oxide/dimethyl disulfide and ammonium molybdate/carbon disulfide second stage catalysts. C{sub l}-C{sub 3} hydrogen gas yields were modest, generally 7-8 wt % on MAF coal, and overall hydrogen consumption (including first stage shift hydrogen) was in the order of 7-8 wt % on MAF coal. The ammonium molybdate catalyst system appeared to give slightly higher oil yields and hydrogen consumption, as was expected, but the differences may not be significant.

  9. World market: A survey of opportunities for advanced coal-fired systems

    SciTech Connect

    Holt, N.A.H.

    1995-06-01

    Although there is a wide range of forecasts for the future of World energy demand and consumption over the next 25 years, all forecasts show marked increases being required for all forms of fossil fuels even when optimistic projections are made for the future adoption of Nuclear and Renewable energy. It is also generally expected that coal usage will in this period experience its greatest growth (a doubling) in the Asia-Pacific region dominated demographically by China and India. In this paper, energy projections and the extent and nature of the coal reserves available worldwide are examined. While most coal technologies can handle a variety of feedstocks, there are often economic factors that will determine the preferred selection. The matching of technology to coal type and other factors is examined with particular reference to the Asia Pacific region. Oil usage is similarly forecast to experience a comparable growth in this region. Over 70% of the World`s oil reserves are heavy oils and refinery crudes are increasing in gravity and sulfur content. The clean coal technologies of gasification and fluid bed combustion can also use low value petroleum residuals as feedstocks. There is therefore a nearer term market opportunity to incorporate such technologies into cogeneration and coproduction schemes adjacent to refineries resulting in extremely efficient use of these resources.

  10. Advanced coal liquefaction research: Technical progress report, October 1, 1986-December 31, 1986

    SciTech Connect

    Gall, W.; McIlvried, H.G. III

    1988-03-01

    This report describes studies made during the fourth quarter of 1986 using the revised microautoclave experimental technique. Studies were made of the effect of reaction time on conversion using Kemmerer coal. Results that, at least during the first 30 minutes, conversion is a monotonically increasing function of reaction time and temperature. A study was also made of the effect of temperature on conversion. In general, conversion increased with temperature. The reactivity of coal appears to be unaffected by exposure to Certigrav fluid, if the exposed coal is subjected to two acetone washings under a nitrogen blanket. Work was started on using SCR-II process solvent in place of tetralin. Results indicate that SRC-II process solvent is a satisfactory solvent donor for high reactivity, high ash bituminous coals, but slightly less effective for low ash, subbituminous coals. Some tests were made to examine the effect of operating the Soxlett extraction equipment at higher temperatures. In general, higher temperature operations gave product yields 2--4 wt% higher than the uninsulated columns. 2 refs., 8 figs., 39 tabs.

  11. Advanced coal liquefaction research: Technical progress report, January 1, 1987-March 31, 1987

    SciTech Connect

    Gall, W.; McIlvried, H.G. III

    1987-05-01

    This report describes the work performed by Energy International during the first quarter of 1987. Most of this work involved using a larger microautoclave reactor. Studies were made of the effect of the size of the coal charge on conversion and product yield reproducibility using Powhatan No. 6 Mine and Illinois No. 6 coals. Good coal conversion and product yield reproducibility for duplicate runs were obtained after minor modifications were made to the product workup technique. The experimental program using 50/sup 0/F distillate fractions of process solvent obtained from the GR and DC P-99 SRC-II PDU has been completed. Initial results indicate that all six distillates are essentially equal as hydrogen donor solvents. A sample of Wilsonville SRC deashed oil was received and distilled into two distillate fractions: 650 to 850/sup 0/F. A 3 x 3 factorial design of experiments with replicates of the corner and center points (14 runs total) will be made with the 850 to 1005/sup 0/F distillate cut using Illinois No. 6 coal. EI will perform the coal liquefaction runs in its 105 ml microautoclave reactor. 2 refs., 6 figs., 24 tabs.

  12. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  13. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 16, July--September, 1996

    SciTech Connect

    Shields, G.L.; Moro, N.; Smit, F.J.; Jha, M.C.

    1996-10-30

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. 28 refs., 13 figs., 19 tabs.

  14. Engineering Development of Advanced Physical Fine Coal Cleaning Technologies: Froth flotation. Quarterly technical progress report No. 21, October 1, 1993--December 31, 1993

    SciTech Connect

    Not Available

    1993-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate.

  15. Report of activities of the advanced coal extraction systems definition project, 1979 - 1980

    NASA Technical Reports Server (NTRS)

    Lavin, M. L.; Isenberg, L.

    1981-01-01

    During this period effort was devoted to: formulation of system performance goals in the areas of production cost, miner safety, miner health, environmental impact, and coal conservation, survey and in depth assessment of promising technology, and characterization of potential resource targets. Primary system performance goals are to achieve a return on incremental investment of 150% of the value required for a low risk capital improvement project and to reduce deaths and disability injuries per million man-hour by 50%. Although these performance goals were developed to be immediately applicable to the Central Appalachian coal resources, they were also designed to be readily adaptable to other coals by appending a geological description of the new resource. The work done on technology assessment was concerned with the performance of the slurry haulage system.

  16. Advanced technology applications for second and third general coal gasification systems

    NASA Technical Reports Server (NTRS)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    The historical background of coal conversion is reviewed and the programmatic status (operational, construction, design, proposed) of coal gasification processes is tabulated for both commercial and demonstration projects as well as for large and small pilot plants. Both second and third generation processes typically operate at higher temperatures and pressures than first generation methods. Much of the equipment that has been tested has failed. The most difficult problems are in process control. The mechanics of three-phase flow are not fully understood. Companies participating in coal conversion projects are ordering duplicates of failure prone units. No real solutions to any of the significant problems in technology development have been developed in recent years.

  17. Advanced NMR-based techniques for pore structure analysis of coal

    SciTech Connect

    Smith, D.M.

    1991-01-01

    One of the main problems in coal utilization is the inability to properly characterize its complex pore structure. We propose to investigate the dependence of the common NMR parameters such as chemical shifts and relaxation times of several different nuclei and compounds on the pore structure of model microporous solids, carbons, and coals. In particular, we will study the interaction between several small molecules ({sup 129}Xe, {sup 3}He, {sup 2}H{sub 2}, {sup 14}N{sub 2}, {sup 14}NH{sub 3}, {sup 15}N{sub 2}, {sup 13}CH{sub 4}, {sup 13}CO{sub 2}) and the pore surfaces in coals. These molecules have been selected for their chemical and physical properties.

  18. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL FIRED PROCESSES

    SciTech Connect

    Leon Glicksman; Hesham Younis; Richard Hing-Fung Tan; Michel Louge; Elizabeth Griffith; Vincent Bricout

    1998-04-30

    Pressurized fluidization is a promising new technology for the clean and efficient combustion of coal. Its principle is to operate a coal combustor at high inlet gas velocity to increase the flow of reactants, at an elevated pressure to raise the overall efficiency of the process. Unfortunately, commercialization of large pressurized fluidized beds is inhibited by uncertainties in scaling up units from the current pilot plant levels. In this context, our objective is to conduct a study of the fluid dynamics and solid capture of a large pressurized coal-fired unit. The idea is to employ dimensional similitude to simulate in a cold laboratory model the flow in a Pressurized Circulating Fluid Bed ''Pyrolyzer,'' which is part of a High Performance Power System (HIPPS) developed by Foster Wheeler Development Corporation (FWDC) under the DOE's Combustion 2000 program.

  19. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  20. Advanced NMR-based techniques for pore structure analysis of coal

    SciTech Connect

    Smith, D.M.

    1992-01-01

    One of the main problems in coal utilization is the inability to properly characterize its complex pore structure. Coals typically have micro/ultra-micro pores but they also exhibit meso and macroporosity. Conventional pore size techniques (adsorption/condensation, mercury porosimetry) are limited because of this broad pore size range, microporosity, reactive nature of coal, samples must be completely dried, and network/percolation effects. Small angle scattering is limited because it probes both open and closed pores. Although one would not expect any single technique to provide a satisfactory description of a coal's structure, it is apparent that better techniques are necessary. We believe that measurement of the NMR parameters of various gas phase and adsorbed phase NMR active probes can provide the resolution to this problem. We will investigate the dependence of the common NMR parameters such as chemical shifts and relaxation times of several different nuclei and compounds on the pore structure of model microporous solids, carbons, and coals. In particular, we will study the interaction between several small molecules and the pore surfaces in coals. These molecules have been selected for their chemical and physical properties. A special NMR probe will be constructed which will allow the concurrent measurement of NMR properties and adsorption uptake at a variety of temperatures. All samples will be subjected to a suite of conventional'' pore structure analyses. These include nitrogen adsorption at 77 K with BET analysis, CO[sub 2] and CH[sub 4] adsorption at 273 K with D-R (Dubinin-Radushkevich) analysis, helium pycnometry, and small angle X-ray scattering as well as gas diffusion measurements.

  1. An Advanced Control System for Fine Coal Flotation. Sixth quarter, technical progress report, July 1-September 30, 1997

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-10-27

    Over the past thirty years, process control has spread from the chemical industry into the fields of mineral and coal processing. Today, process control computers, combined with improved instrumentation, are capable of effective control in many modem flotation circuits. Unfortunately, the classical methods used in most control strategies have severe limitations when used in froth flotation. For example, the nonlinear nature of the flotation process can cause single-input, single-output lines to battle each other in attempts to achieve a given objective. Other problems experienced in classical control schemes include noisy signals from sensors and the inability to measure certain process variables. For example, factors related to ore type or water chemistry, such as liberation, froth stability, and floatability, cannot be measured by conventional means. The purpose of this project is to demonstrate an advanced control system for fine coal flotation. The demonstration is being carried out at an existing coal preparation plant by a team consisting of Virginia Polytechnic Institute and State University (VPI&SU) as the prime contractor and J.A. Herbst and Associates as a subcontractor. The objectives of this work are: (1) to identify through sampling, analysis, and simulation those variables which can be manipulated to maintain grades, recoveries, and throughput rates at levels set by management; (2) to develop and implement a model-based computer control strategy that continuously adjusts those variables to maximize revenue subject to various metallurgical, economic, and environmental constraints; and (3) to employ a video-based optical analyzer for on-line analysis of ash content in fine coal slurries.

  2. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, November 1991--January 1992

    SciTech Connect

    Not Available

    1992-08-01

    The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. Accomplishments for this past quarter are as follows: The 9th quarterly measurements at the Colorado site took place in December, 1991. Permeability and neutron absorption moisture content measurements were made and on site data was collected from the data logger; The 9th quarterly sampling at the Ohio site took place in November 1991. Permeability and moisture content measurements were made, and water samples were collected from the wells and lysimeters; The second quarterly core and water samples from the first Illinois test case were collected in mid November, and field data were collected from the data logger; Chemical analysis of all core and water samples continued; all chemical analyses except for some tests on Illinois second quarter cores are now complete.

  3. Advanced NMR-based techniques for pore structure analysis of coal

    SciTech Connect

    Smith, D.M.

    1992-01-01

    One of the main problems in coal utilization is the inability to properly characterize its complex pore structure. Coals typically have micro/ultra-micro pores but they also exhibit meso and macroporosity. Conventional pore size techniques (adsorption/condensation, mercury porosimetry) are limited because of this broad pore size range, microporosity, reactive nature of coal, samples must be completely dried, and network/percolation effects. Small angle scattering is limited because it probes both open and closed pores. Although one would not expect any single technique to provide a satisfactory description of a coal's structure, it is apparent that better techniques are necessary. We believe that measurement of the NMR parameters of various gas phase and adsorbed phase NMR active probes can provide the resolution to this problem. We now have two suites of well-characterized microporous materials including oxides (zeolites and silica gel) and activated carbons from our industrial partner, Air Products in Allentown, PA. Our current work may be divided into three areas: small-angle X-ray scattering (SAXS), adsorption, and NMR.

  4. Advanced technology for ancillary coal cleaning operations. Technical progress report, January 1988--March 1988

    SciTech Connect

    Not Available

    1994-09-01

    The work under contract number DE-AC22-87PC97881 is devoted to experimental research and development to investigate the feasibility of novel ancillary coal-cleaning technologies that offer a potential for reduced capital and operating costs. The ancilliary operations that are specifically addressed in this work include pulse enhanced drying, fines reconstitution by extrusion, and hydraulic wave comminution.

  5. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Not Available

    1992-12-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  6. Advanced coal liquefaction research. Quarterly technical progress report, July 1, 1983-September 30, 1983

    SciTech Connect

    1984-04-01

    Work this quarter focused on staged liquefaction. The effect of residence time on conversion in single pass experiments was found to be quite different for the subbituminous Belle Ayr Mine and bituminous Illinois No. 6 coals studied. With bituminous coal, conversion to soluble material is quite high and the limit of conversion is approached in only a few minutes. With a subbituminous coal, however, conversion is much lower and the limit of conversion is approached much more slowly. Short contact time (SCT) dissolution of Belle Ayr coal was studied as a possible first stage in a two-stage process. Conversion, hydrocarbon gas yield and hydrogen consumption were increased as residence time or temperature were increased. Conversion was also significantly increased by partial slurry recycle. Pyrite was found to be the most effective slurry catalyst for increasing conversion, followed by ammonium molybdate emulsion and finally nickel-molybdenum on alumina. Illinois No. 6 coal was liquefied in two stages. Conditions in the first stage dissolution were varied to determine the effect on upgradability in the second stage. An SCT (6 minute) coal dissolution stage is preferred over one at 30 minutes because hydrocarbon gas yield was much lower while overall oil yields for the combined dissolution and upgrading stages were nearly the same. Use of a NiMo/Al/sub 2/O/sub 3/ catalyst in a trickle-bed second stage resulted in a higher oil yield and lower product heteroatom content than use of the same catalyst in the slurry phase. The total oil yield was lower with a pyrite slurry catalyst than with a NiMo/Al/sub 2/O/sub 3/ slurry catalyst. With Belle Ayr coal and added pyrite, there was no change in total oil yield, conversion or product quality brought about by adding an 8-minute first stage at 450/sup 0/C (842/sup 0/F) to a 2-hour second stage operated at 420/sup 0/C (788/sup 0/F). 39 figures, 12 tables.

  7. POC-scale testing of an advanced fine coal dewatering equipment/technique: Quarterly technical progress report No. 9, October 1996--December 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1997-01-21

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter in the laboratory dewatering studies were conducted using copper and aluminum ions showed that for the low sulfur clean coal slurry addition of 0.1 Kg/t of copper ions was effective in lowering the filter cake moisture from 29 percent to 26.3 percent. Addition of 0.3 Kg/t of aluminum ions provided filter cake with 28 percent moisture. For the high sulfur clean coal slurry 0.5 Kg/t of copper and 0.1 Kg/t of aluminum ions reduced cake moisture from 30.5 percent to 28 percent respectively. Combined addition of anionic (10 g/t) and cationic (10 g/t) flocculants was effective in providing a filter cake with 29.8 percent moisture. Addition of flocculants was not effective in centrifuge dewatering. In pilot scale screen bowl centrifuge dewatering studies it was found that the clean coal slurry feed rate of 30 gpm was optimum to the centrifuge, which provided 65 percent solids capture. Addition of anionic or cationic flocculants was not effective in lowering of filter cake moisture, which remained close to 30 percent for both clean coal slurries.

  8. Advanced direct coal liquefaction concepts. Quarterly report, October 1, 1992--December 31, 1992

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L.

    1992-12-31

    During the first quarter of FY 1993, the Project proceeded close to the Project Plan. The analysis of the feed material has been completed as far as possible. Some unplanned distillation was needed to correct the boiling range of the Black Thunder solvent used during the autoclave tests. Additional distillation will be required if the same solvent is to be used for the bench unit tests. A decision on this is still outstanding. The solvent to be used with Illinois No. 6 coal has not yet been defined. As a result, the procurement of the feed and the feed analysis is somewhat behind schedule. Agglomeration tests with Black Thunder coal indicates that small agglomerates can be formed. However, the ash removal is quite low (about 10%), which is not surprising in view of the low ash content of the coal. The first series of autoclave tests with Black Thunder coal was completed as planned. Also, additional runs are in progress as repeats of previous runs or at different operating conditions based on the data obtained so far. The results are promising indicating that almost complete solubilization (close to 90%) of Black Thunder coal can be achieved in a CO/H{sub 2}O environment at our anticipated process conditions. The design of the bench unit has been completed. In contrast to the originally planned modifications, the bench unit is now designed based on a computerized control and data acquisition system. All major items of equipment have been received, and prefabrication of assemblies and control panels is proceeding on schedule. Despite a slight delay in the erection of the structural steel, it is anticipated that the bench unit will be operational at the beginning of April 1993.

  9. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications: Task 9 - Selective agglomeration Module Testing and Evaluation.

    SciTech Connect

    Moro, N.` Jha, M.C.

    1997-09-29

    The primary goal of this project was the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing of both processes on six coals to optimize the processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report summarizes the findings of all the selective agglomeration (SA) test work performed with emphasis on the results of the PDU SA Module testing. Two light hydrocarbons, heptane and pentane, were tested as agglomerants in the laboratory research program which investigated two reactor design concepts: a conventional two-stage agglomeration circuit and a unitized reactor that combined the high- and low-shear operations in one vessel. The results were used to design and build a 25 lb/hr bench-scale unit with two-stage agglomeration. The unit also included a steam stripping and condensation circuit for recovery and recycle of heptane. It was tested on six coals to determine the optimum grind and other process conditions that resulted in the recovery of about 99% of the energy while producing low ash (1-2 lb/MBtu) products. The fineness of the grind was the most important variable with the D80 (80% passing size) varying in the 12 to 68 micron range. All the clean coals could be formulated into coal-water-slurry-fuels with acceptable properties. The bench-scale results were used for the conceptual and detailed design of the PDU SA Module which was integrated with the existing grinding and dewatering circuits. The PDU was operated for about 9 months. During the first three months, the shakedown testing was performed to fine tune the operation and control of various equipment. This was followed by parametric testing, optimization/confirmatory testing, and finally a

  10. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl

    2006-09-30

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station.

  11. Advanced coal technology by-products: Long-term results from landfill test cells and their implications for reuse or disposal applications

    SciTech Connect

    Weinberg, A.; Harness, J.L.

    1994-06-01

    New air pollution regulations under the 1991 Clean Air Act and other legislation are motivating continued development and implementation, of cleaner, more efficient processes for converting coal to electrical power. These clean coal processes produce solid by-products which differ in important respects from conventional pulverized coal combustion ash. Clean coal by-products` contain both residual sorbent and captured SO{sub 2} control products, as well as the mineral component of the coal. The Department of Energy/Morgantown Energy Technology Center has contracted Radian Corporation to construct and monitor landfill test cells with a several different advanced coal combustion by-products at three locations around the US; data from these sites provide a unique picture of the long-term field behavior of clean coal combustion by-products. The field testing sites were located in western Colorado, northern Ohio, and central Illinois. Fluidized bed combustion and lime injection residues are characterized by high lime and calcium sulfate contents` contributed by reacted and unreacted sorbent materials, and produce an leachate, when wetted. Compared with conventional coal fly ash, the clean coal technology ashes have been noted for potential difficulties when wetted, including corrosivity, heat generation, cementation, and swelling on hydration. On the other hand, the high lime content and chemical reactivity of clean coal residues offer potential benefits in reuse as a cementitious material.The results of three years of data collection suggest a fairly consistent pattern of behavior for the calcium-based dry sorbent systems involved in the project, despite differences in the initial of the by-products, differences in the methods of placement, and differences in climate at the test sites.

  12. Development of advanced, dry, SO{sub x}/NO{sub x} emission control technologies for high-sulfur coal. Final report, April 1, 1993--December 31, 1994

    SciTech Connect

    Amrhein, G.T.

    1994-12-23

    Dry Scrubbing is a common commercial process that has been limited to low- and medium-sulfur coal applications because high-sulfur coal requires more reagent than can be efficiently injected into the process. Babcock & Wilcox has made several advances that extend dry scrubbing technologies to higher sulfur coals by allowing deposit-free operation at low scrubber exit temperatures. This not only increases the amount of reagent that can be injected into the scrubber, but also increases SO{sub 2} removal efficiency and sorbent utilization. The objectives of this project were to demonstrate, at pilot scale, that advanced, dry-scrubbing-based technologies can attain the performance levels specified by the 1990 Clean Air Act Amendments for SO{sub 2} and NO{sub x} emissions while burning high-sulfur coal, and that these technologies are economically competitive with wet scrubber systems. The use of these technologies by utilities in and around Ohio, on new or retrofit applications, will ensure the future of markets for high-sulfur coal by creating cost effective options to coal switching.

  13. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 25, October 1, 1994--December 31, 1994

    SciTech Connect

    1994-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  14. Engineering design and analysis of advanced physical fine coal cleaning technologies. Final report

    SciTech Connect

    1994-08-01

    This report describes the gravity separation equipment models available in the Coal Cleaning Simulator developed by Aspen Technology, Inc. This flowsheet simulator was developed in collaboration with ICF Kaiser Engineers, a subcontractor to Aspen Technology, Inc., and CQ Inc., a subcontractor to ICF Kaiser Engineers. The algorithms and FORTRAN programs for modeling gravity separation, which include calculations for predicting process performance, and calculations for equipment sizing and costing, were developed by ICF Kaiser Engineers. Aspen Technology integrated these and other models into the ASPEN PLUS system to provide a simulator specifically tailored for modeling coal cleaning plants. ICF Kaiser Engineers also provided basic documentation for these models; Aspen Technology, Inc. has incorporated the information into this topical report. The report documents both the use and the design bases for the models, and provides to the user a good understanding of their range of applicability and limitations.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1993-02-12

    Work completed produced the criteria for additional engineering analysis, computation and detailed experimental benchscale testing for areas of uncertainty. The engineering analysis, computation, bench-scale testing and component development was formulated to produce necessary design information to define a commercially operating system. In order to produce the required information by means of bench-scale testing and component development, a uniform coal sample was procured. After agreement with DOE, a selected sample of coal from those previously listed was secured. The test plan was developed in two parts. The first part listed procedures for engineering and computational analyses of those deficiencies previously identified that could be solved without bench scale testing. Likewise, the second part prepared procedures for bench-scale testing and component development for those deficiencies previously identified in Task 3.

  16. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  17. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  18. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  19. Effect of conventional and advanced coal conversion by-products on the pulmonary system

    SciTech Connect

    Aranyi, C.; Bradof, J.

    1981-04-01

    To evaluate the environmental impact of different energy technologies, fly ash samples collected from a coal-fired and from an oil-fired electric power plant were used in aerosol inhalation exposures of mice. The effects of multiple 3-h exposures to the fly ash particles at 2 and 1 mg/cu m aerosol mass concentration and <0.5 micrometer MMAD were evaluated in male and female mice by examining the changes in their pulmonary free cells, in their susceptibility to streptococcus infection, and in the bactericidal activity in their lungs to inhaled Klebsiella pneumoniae. Generally, no consistent differences could be discovered in the effects of the exposures between the two sexes. However, in a combined evaluation of both sexes, more and greater significant changes relative to controls were observed in the experimental parameters after inhalation of the oil power plant fly ash than after exposure to the coal fly ash. Thus, the overall results of the study indicate that the pulmonary defense system of mice was more adversely affected by the oil-fired power plant fly ash, a true stack emission effluent, than by the coal fly ash collected by electrostatic precipitator, an in-plant control device.

  20. Resource targets for advanced underground coal-extraction systems. [Identification of location and geology of deposit for which greatest savings can be realized by advanced mining systems in 2000

    SciTech Connect

    Hoag, J.H.; Whipple, D.W.; Habib-Agahi, H.; Lavin, M.L.

    1982-08-01

    This report identifies resource targets appropriate for federal sponsorship of research and development of advanced underground coal mining systems. In contrast to previous research, which focused on a particular resource type, this study made a comprehensive examination of both conventional and unconventional coals, with particular attention to exceptionally thin and thick seams, steeply dipping beds, and multiple seam geometry. The major thrust of the targeting analysis was forecasting which coals would be of clear commercial significance at the beginning of the 21st century under three widely different scenarios for coal demand. The primary measure of commercial importance was an estimate of the aggregate dollar savings realized by consumers if advanced technology were available to mine coal at prices at or below the price projected for conventional technology in the year 2000. Both deterministic and probabilistic savings estimates were prepared for each demand scenario. The results indicate that the resource of primary importance is flat-lying bituminous coal of moderate thickness, under moderate cover, and located within the lower 48 states. Resources of secondary importance are the flat-lying multiple seams and thin seams (especially those in Appalachia). The rather substantial deposits of bituminous coal in North Alaska and the deeply buried lignites of the Gulf Coast present transportation and ground control problems which appear to postpone their commercial importance well beyond 2000. Steeply dipping coals, abandoned pillars, and exceptionally thick western coals may be important in some regions or sub-regions, but the limited tonnage available places them in a position of tertiary importance.

  1. Pelletizing/reslurrying as a means of distributing and firing clean coal. Final quarterly technical progress report No. 6, October 1, 1991--December 31, 1991

    SciTech Connect

    Conkle, H.N.

    1992-03-17

    The objective of this study is to develop technology that permits the practical and economic preparation, storage, handling, and transportation of coal pellets, which can be reslurried into Coal water fuels (CWF) suitable for firing in small- and medium-size commercial and industrial boilers, furnaces, and engines. The project includes preparing coal pellets and capsules from wet filter cake that can be economically stored, handled, transported, and reslurried into a CWF that can be suitably atomized and fired at the user site. The wet cakes studied were prepared from ultra-fine (95% -325 mesh) coal beneficiated by advanced froth-flotation techniques. The coals studied included two eastern bituminous coals, one from Virginia (Elkhorn) and one from Illinois (Illinois No. 6) and one western bituminous coal from Utah (Sky Line coal).

  2. The Oxnard advanced water purification facility: combining indirect potable reuse with reverse osmosis concentrate beneficial use to ensure a California community's water sustainability and provide coastal wetlands restoration.

    PubMed

    Lozier, Jim; Ortega, Ken

    2010-01-01

    The City of Oxnard in California is implementing a strategic water resources program known as the Groundwater Recovery Enhancement and Treatment (GREAT) program, which includes an Advanced Water Purification Facility (AWPF) that will use a major portion of the secondary effluent from the City's existing Water Pollution Control Facility to produce high-quality treated water to be used for irrigation of edible food crops, landscape irrigation, injection into the groundwater basin to form a barrier to seawater intrusion, and other industrial uses. The AWPF, currently under design by CH2M HILL, will employ a multiple-barrier treatment train consisting of microfiltration, reverse osmosis, and ultravioletlightbased advanced oxidation processes to purify the secondary effluent to conform to California Department of Public Health Title 22 Recycled Water Criteria for groundwater recharge. The AWPF, which will have initial and build-out capacities of ca. 24,000 and ca 95,000 m(3)/day, respectively, was limited to a 1.8-hectare site, with 0.4 hectares dedicated to a Visitor's Center and administration building. Further, the depth below grade and height of the AWPF's structures were constrained because of the high groundwater table at the site, the high cost of excavation and dewatering, and local codes. To accommodate these various restrictions, an innovative design approach has been developed. This paper summarizes the design constraints and innovative solutions for the design of the AWPF.

  3. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  4. Engineering development of advanced coal-fired low-emission boiler system. Technical progress report No. 1, August--December 1992

    SciTech Connect

    Not Available

    1993-02-26

    The Pittsburgh Energy Technology Center of the US Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the ``Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems`` Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: NO{sub x} emissions not greater than one-third NSPS; SO{sub x} emissions not greater than one-third NSPS; and particulate emissions not greater than one-half NSPS. The specific secondary objectives are: Improved ash disposability and reduced waste generation; reduced air toxics emissions; increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

  5. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, April 1996--June 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-07-31

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from April 1 - June 30, 1996.

  6. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide emissions from coal-fired boilers

    SciTech Connect

    Sorge, J.N.; Larrimore, C.L.; Slatsky, M.D.; Menzies, W.R.; Smouse, S.M.; Stallings, J.W.

    1997-12-31

    This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The primary objectives of the demonstration is to determine the long-term NOx reduction performance of advanced overfire air (AOFA), low NOx burners (LNB), and advanced digital control optimization methodologies applied in a stepwise fashion to a 500 MW boiler. The focus of this paper is to report (1) on the installation of three on-line carbon-in-ash monitors and (2) the design and results to date from the advanced digital control/optimization phase of the project.

  7. Modelling and assessment of advanced processes for integrated environmental control of coal-fired power plants. Technical progress report

    SciTech Connect

    Barrett, J.G.; Bloyd, C.N.; McMichael, F.C.; Rubin, E.S.

    1984-07-01

    The key objective of this research is the development of a computer based model for the assessment of integrated environmental control (IEC) systems for conventional and advanced coal fired power plant designs. Efforts during the period April 1-June 30, 1984 focused on, (1) testing of a preliminary integrated model linking pre-combustion and post-combustion control options for conventional plants; (2) documentation of the analytical models of existing control technology options; (3) development and preliminary testing of a second model design for the propagation and analysis of uncertainty; and (4) development of new analytical models needed for IEC assessments. Activities and accomplishments in each of these areas are described. 4 references, 13 figures, 4 tables.

  8. [Engineering development of advanced coal-fired low-emission boiler systems]. Technical progress report, October--December 1995

    SciTech Connect

    Wesnor, J.D.; Bakke, E.; Bender, D.J.; Kaminski, R.S.

    1995-12-31

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emisssion boiler systems. The primary objectives are: NO{sub x} emissions, lb/million Btu; SO{sub 2} emissions, lb/million Btu; particulate emissions, lb/million Btu; and net plant efficiency, not less than 42%. The secondary objectives are: improved ash disposability; reduced waste generation; and reduced air toxics emissions. Accomplishments to date are summarized for the following tasks: task 1, project planning and management; task 7, component development and optimization; task 8, preliminary POC test facility design; task 9, subsystem test design and plan; task 10, subsystem test unit construction; and task 11, subsystem test operation and evaluation.

  9. Short-Term Oxidation Studies on Nicrofer- 6025HT in Air at Elevated Temperatures for Advanced Coal Based Power Plants

    SciTech Connect

    Joshi, Vineet V.; Meier, Alan; Darsell, Jens T.; Nachimuthu, Ponnusamy; Bowden, Mark E.; Weil, K. Scott

    2013-04-01

    Several advanced air separation unit (ASU) designs being considered for use in coal gasification rely on the use of solid state mixed ionic and electronic conductors. Nicrofer-6025HT, a nickel-based alloy, has been identified as a potential manifold material to transport the hot gases into the ASUs. In the current study, isothermal oxidation tests were conducted on Nicrofer-6025HT in the temperature range of 700–900 °C for up to 24 h. The evolution of oxide scale was evaluated using SEM, XRD, and XPS. The composite surface oxide layer that formed consisted of an outer chromia-rich scale and an inner alumina scale. For the longer times at the higher temperatures evaluated, a NiCr2O4 spinel phase was located at the interface between the alumina and chromia. Based on the experimental results a four-step oxidation model was proposed.

  10. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect

    Geiling, D.W.

    1993-08-01

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  11. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    SciTech Connect

    Not Available

    1993-09-01

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  12. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  13. Advanced technological components enhance the performance of coal and oil gasification plants

    SciTech Connect

    Keller, H.J.; Buxel, M.; Kaiser, V.; Jass, K.H.; Liu, C.; Hanke, H.; Poloszyk, K.

    1997-12-31

    The gasification of coal has been carried out on an industrial scale for a long time. During the past two decades, gasification processes of the so-called second generation were developed to produce synthesis gas or fuel gas from solid and viscous feedstocks at an elevated pressure. These processes offer a wide variety of applications. The preferred feedstocks are coal of different types and heavy hydrocarbons including heavy fuel oil and heavy residues from oil refining as well as natural bitumen. The main components of the crude gas are CO and H{sub 2} in a molar ratio between 1 and 2, depending on the type of feedstock and the gasification principle applied. In downstream facilities, the crude gas is conditioned so as to meet the requirements of the final products: pure hydrogen, the group of synthesis products and fuel gas for power and heat generation, preferably by the combined cycle principle (IGCC). The second-generation gasification processes have furnished proof of their technical feasibility, but have to compete against alternative gas generation technologies such as steam reforming using natural gas as the feedstock. In view of this situation, operational aspects such as plant reliability, efficient energy utilization and optimum reduction of emission levels are gaining increasing importance. Based on practical experience, several key components have been developed, continuously improved and optimized for coal and oil gasification units, with the result of a very positive plant performance. The technical background and the results of this development work will be explained in more detail. Process configuration and special process elements of the Texaco Gasification process are described.

  14. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  15. Development of advanced NO sub x control concepts for coal-fired utility boilers

    SciTech Connect

    Newhall, J.; England, G.; Seeker, W.R.

    1992-01-16

    Hybrid technologies for reduction of NO{sub x} emissions from coal fired utility boilers may offer greater levels of NO{sub x} control than the sum of the individual technologies, leading to more cost effective emissions control strategies. CombiNO{sub x} is an integration of modified reburning, promoted selective non-catalytic reduction (SNCR) and methanol injection to reduce NO{sub x} emissions from coal fired flue gas. The first two steps, modified reburning and promoted SNCR are linked. It was shown previously that oxidation of CO in the presence of a SNCR agent enhances the NO reduction performance. Less reburning than is typically done is required to generate the optimum amount of CO to promote the SNCR agent. If the reburn fuel is natural gas this may result in a significant cost savings over typical reburning. Injection of methanol into the flue gas has been shown at laboratory scale to convert NO to NO{sub 2} which may subsequently be removed in a wet scrubber. The overall objective of this program is to demonstrate the effectiveness of the CombiNOx process at a large enough scale and over a sufficiently broad range of conditions to provide all of the information needed to conduct a full-scale demonstration in a coal fired utility boiler. The specific technical goals of this program are: 70% NO{sub x} reduction at 20% of the cost of selective catalytic reduction; NO{sub x} levels at the stack of 60 ppm for ozone non-attainment areas; demonstrate coal reburning; identify all undesirable by-products of the process and their controlling parameters; demonstrate 95% NO{sub 2} removal in a wet scrubber. During this reporting period, experimental work was initiated at both the laboratory and pilot scale in the Fundamental Studies phase of the program. The laboratory scale work focused on determining whether or not the NO{sub 2} formed by the methanol injection step can be removed in an SO{sub 2} scrubber.

  16. Advanced NMR approaches in the characterization of coal. [Quarterly] report No. 9

    SciTech Connect

    Maciel, G.E.

    1992-12-31

    A considerable effort in this project during the past few months has been focussed on the development of {sup 1}H and {sup 13}C NMR imaging techniques to yield spatially-resolved chemical shift (structure) information on coal. In order to yield the chemical shift information, a solid-state NMR imaging technique must include magic-angle spinning, so rotating gradient capabilities are indicated. A {sup 13}C MAS imaging probe and a {sup 1}H MAS imaging probe and the circuitry necessary for rotating gradients have been designed and constructed. The {sup 1}H system has already produced promising preliminary results, which are briefly described in this report.

  17. Evaluating risks to wildlife from coal fly ash incorporating recent advances in metals and metalloids risk assessment.

    PubMed

    Meyer, Carolyn B; Schlekat, Tamar H; Walls, Suzanne J; Iannuzzi, Jacqueline; Souza, Marcy J

    2015-01-01

    Current scientific advances in metal and metalloid risk assessment were applied to evaluate risk to aquatic and riparian wildlife species potentially impacted by residual coal fly ash after cleanup of an unprecedented large ash release into an aquatic environment-the first assessment of its kind. Risk was evaluated using multiple lines of evidence (LOE), including 1) tissue-based risk assessment of inorganic concentrations in piscivorous and insectivorous bird eggs and raccoon organs, 2) deterministic and probabilistic diet-based risk estimates for 10 receptors species, 3) raccoon health metrics, and 4) tree swallow nest productivity measures. Innovative approaches included use of tissue-based toxicity reference values (TRVs), adjustment of bioavailability in the dietary uptake models (using sequential metal extractions in sediment), partitioning chemical species into uptake compartments (e.g., prey gut, nongut, sediment), incorporating uncertainty in both modeled dose and dietary TRVs, matching TRVs to chemical forms of constituents, and pairing these LOEs with reproductive success or health status of sensitive receptor species. The weight of evidence revealed that risk to wildlife from residual ash was low and that risk, though low, was most pronounced for insectivorous birds from exposure to Se and As. This information contributes to the debate surrounding coal combustion residue regulations prompted by this ash release. Because of the responsible party's proactive approach of applying state-of-the-art methods to assess risk using several LOEs that produced consistent results, and because of their inclusion of the regulating agencies in decisions at every step of the process, the risk assessment results were accepted, and an effective approach toward cleanup protective of the environment was quickly implemented. This study highlights the value of using multiple LOEs and the latest scientific advances to assist in timely decision making to obtain an effective

  18. Advances in measurements and simulation of gas-particle flows and coal combustion in burners/combustors

    NASA Astrophysics Data System (ADS)

    Zhou, L. X.

    2009-02-01

    Innovative coal combustors were developed, and measurement and simulation of gas-particle flows and coal combustion in such combustors were done in the Department of Engineering Mechanics, Tsinghua University. LDV/PDPA measurements are made to understand the behavior of turbulent gas-particle flows in coal combustors. Coal combustion test was done for the non-slagging cyclone coal combustor. The full two-fluid model developed by the present author was used to simulate turbulent gas-particle flows, coal combustion and NOx formation. It is found by measurements and simulation that the optimum design can give large-size recirculation zones for improving the combustion performance for all the combustors. The combustion test shows that the nonslagging coal combustor can burn 3-5mm coal particles with good combustion efficiency and low NO emission. Simulation in comparison with experiments indicates that the swirl number can significantly affect the NO formation in the swirl coal combustor.

  19. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL-FIRED POWER PROCESSES

    SciTech Connect

    Leon R. Glicksman; Michael Louge; Hesham F. Younis; Richard Tan; Mathew Hyre; Mark Torpey

    2003-11-24

    This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor an agency thereof, nor any of the their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, A combined-cycle High Performance Power System (HIPPS) capable of overall cycle efficiencies approaching 50% has been proposed and designed by Foster Wheeler Development Corporation (FWDC). A pyrolyzer in the first stage of the HIPPS process converts a coal feedstock into fuel gas and char at an elevated pressure of 1.4 Map. (206 psia) and elevated temperature of 930 C (1700 F). The generated char serves as the feedstock for a Pulverized Coal (PC) boiler operating at atmospheric pressure, and the fuel gas is directly fired in a gas turbine. The hydrodynamic behavior of the pyrolyzer strongly influences the quality of both the fuel gas and the generated char, the energy split between the gas turbine and the steam turbine, and hence the overall efficiency of the system. By utilizing a simplified set of scaling parameters (Glicksman et al.,1993), a 4/7th labscale cold model of the pyrolyzer operating at ambient temperature and pressure was constructed and tested. The scaling parameters matched include solid to gas density ratio, Froude number, length to diameter ratio; dimensionless superficial gas velocity and solid recycle rate, particle sphericity and particle size distribution (PSD).

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 2, January--March 1993

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-04-26

    The main purpose of this project is engineering development of advanced column flotation and selective agglomeration technologies for cleaning coal. Development of these technologies is an important step in the Department of Energy program to show that ultra-clean fuel can be produced from selected United States coals and that this fuel will be a cost-effective replacement for a portion of the premium fuels (oil and natural gas) burned by electric utility and industrial boilers in this country. Capturing a relatively small fraction of the total utility and industrial oil-fired boiler fuel market would have a significant impact on domestic coal production and reduce national dependence on petroleum fuels. Significant potential export markets also exist in Europe and the Pacific Rim for cost-effective premium fuels prepared from ultra-clean coal. The replacement of premium fossil fuels with coal can only be realized if retrofit costs, and boiler derating are kept to a minimum. Also, retrofit boiler emissions must be compatible with national goals for clean air. These concerns establish the specifications for the ash and sulfur levels and combustion properties of ultra-clean coal discussed below. The cost-shared contract effort is for 48 months beginning September 30, 1992, and ending September 30, 1996. This report discusses the technical progress made during the second 3 months of the project, January 1 to March 31, 1993.

  1. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Thomas Robl; John Groppo

    2005-09-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. A mobile demonstration unit has been designed and constructed for field demonstration. The demonstration unit was hauled to the test site on trailers that were place on a test pad located adjacent to the ash pond and re-assembled. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities. Representative feed ash for the operation of the filed testing unit was excavated from a location within the lower ash pond determined from coring activities. Approximately 150 tons of ash was excavated and pre-screened to remove +3/8 inch material that could cause plugging problems during operation of the demonstration unit.

  2. The Beneficiation of Education

    ERIC Educational Resources Information Center

    Senger, April J.

    2014-01-01

    When the challenge of adapting curriculum to meet the requirements of the Common Core State Standards were presented, this author immediately sought out the assistance of experts in another field: the school library staff. It was apparent that staff needed to practice the beneficiation of the current curriculum to meet the CCSS requirements.…

  3. Predictions of boiler performance when firing fine grind coal fuels

    SciTech Connect

    Hargrove, M.J.; Liljedahl, G.N.; Miemiec, L.S.

    1996-12-31

    The development of advanced coal beneficiation and utilization technologies is being sponsored by the US Department of Energy`s Pittsburgh Energy Technology Center, to encourage the use of the abundant coal reserves. A comprehensive program is being conducted by Combustion Engineering, Inc. (ABB CE), regarding the use of these fuels in existing utility boilers. The preparation process can change the original fuel particle size distribution and hence can affect the combustion and ash deposition behaviors. To evaluate the effects of fine particles independent of the beneficiation process, a Pittsburgh No. 8 coal at three degrees of fineness was selected. Physical, chemical, combustion and fireside characteristics of these fuels were evaluated in laboratory testing. Characterization tests provide the information required to predict the performance and economic impacts of firing these fuels in existing coal and oil-designed utility boilers. Two utility steam generators designed for either coal or oil-firing were selected for performance evaluation. The study units were selected to be representative of a large portion of the current boiler population: a 560 MW coal-designed boiler purchased in 1973; and a 600 MW oil-designed boiler purchased in 1970. Each of these units was previously studied in the DOE Beneficiated Coal Fuels (BCF) evaluation of Spherical Oil Agglomeration Products (SOAP). Both of these units were built by ABB CE, but the fuel related design parameters are similar to those used by other manufacturers. This paper summarizes the results of the performance analysis and describes the economic impacts that can be expected when firing this coal ground to different fineness levels in two utility steam generators.

  4. Studies of in-situ calcium-based sorbents in advanced pressurized coal conversion systems

    SciTech Connect

    Katta, S.; Shires, P.J.; O'Donnell, J.J.

    1992-01-01

    The overall objective of the project is to obtain experimental data on the reactions of calcium-based sorbents in gasification systems and to evaluate or develop kinetic models applicable to the commercial design of such systems. Both air-blown coal gasification systems and second generation fluid bed combustion systems (partial gasification) will be investigated, as well as subsequent stabilization of the solid wastes (calcium sulfide/ash) produced. More specifically, the objectives are to: Develop data on kinetics of in-situ desulfurization reactions; study the effect of calcium on the kinetics of carbon conversion rate; study kinetics of oxidation of CaS to CaSO[sup 4]; Develop and identify viable techniques to stabilize CaS; and, carry out further development work on most promising method and determine its commercial economics.

  5. Studies of in-situ calcium-based sorbents in advanced pressurized coal conversion systems

    SciTech Connect

    Katta, S.; Shires, P.J.; O`Donnell, J.J.

    1992-11-01

    The overall objective of the project is to obtain experimental data on the reactions of calcium-based sorbents in gasification systems and to evaluate or develop kinetic models applicable to the commercial design of such systems. Both air-blown coal gasification systems and second generation fluid bed combustion systems (partial gasification) will be investigated, as well as subsequent stabilization of the solid wastes (calcium sulfide/ash) produced. More specifically, the objectives are to: Develop data on kinetics of in-situ desulfurization reactions; study the effect of calcium on the kinetics of carbon conversion rate; study kinetics of oxidation of CaS to CaSO{sup 4}; Develop and identify viable techniques to stabilize CaS; and, carry out further development work on most promising method and determine its commercial economics.

  6. Development of advanced NO sub x control concepts for coal-fired utility boilers

    SciTech Connect

    Evans, A.; Newhall, J.; England, G.; Seeker, W.R.

    1992-05-27

    CombiNO{sub x} is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO{sub x}, emission reduction from coal fired power plants equipped with SO{sub 2} scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that, performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent, although lower levels of reburning are needed than are traditionally applied in the reburning process. If the reburn fuel is natural gas, the combination of reburning and SNCR may result in a significant cost savings over conventional reburning. The third step, injection of methanol into the flue gas, is used to convert NO to NO{sub 2} which may subsequently be removed in a wet scrubber.

  7. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect

    Gregory J. McCarthy; Dean G. Grier

    1998-09-01

    The goals of the project are two-fold: (1) to upgrade semi-quantitative X-ray diffraction (QXRD) methods presently used in analyzing complex coal combustion by-product (CCB) systems, with the quantitative Rietveld method, and (2) to apply this method to a set of by-product materials that have been disposed or utilized for a long period (5 years or more) in contact with the natural environment, to further study the nature of CCB diagenesis. The project is organized into three tasks to accomplish these two goals: (1) thorough characterization of a set of previously analyzed disposed by-product materials, (2) development of a set of CCB-specific protocols for Rietveld QXRD, and (3) characterization of an additional set of disposed CCB materials, including application of the protocols for Rietveld QXRD developed in Task 2.

  8. Advanced NMR-based techniques for pore structure analysis of coal. Final project report

    SciTech Connect

    Smith, D.M.; Hua, D.W.

    1996-02-01

    During the 3 year term of the project, new methods have been developed for characterizing the pore structure of porous materials such as coals, carbons, and amorphous silica gels. In general, these techniques revolve around; (1) combining multiple techniques such as small-angle x-ray scattering (SAXS) and adsorption of contrast-matched adsorbates or {sup 129}Xe NMR and thermoporometry (the change in freezing point with pore size), (2) combining adsorption isotherms over several pressure ranges to obtain a more complete description of pore filling, or (3) applying NMR ({sup 129}Xe, {sup 14}N{sub 2}, {sup 15}N{sub 2}) techniques with well-defined porous solids with pores in the large micropore size range (>1 nm).

  9. Development of advanced NO[sub x] control concepts for coal-fired utility boiler

    SciTech Connect

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-02-11

    Hybrid technologies for the reduction of NO[sub x] emissions from coal-fired utility boilers have shown the potential to offer greater levels of NO[sub x] control than the sum of the individual technologies, leading to more cost effective emissions control strategies. Energy and Environmental Research Corporation (EER) has developed a hybrid NO[sub x] control strategy involving two proprietary concepts which has the potential to meet the US Department of Energy's NO[sub x] reduction goal at a significant reduction in cost compared to existing technology. The process has been named CombiNO[sub x]. CombiNO[sub x] is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO[sub x] emission reduction from coal-fired power plants equipped with S0[sub x] scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent. Approximately 10 percent reburning is required, this represents half of that required for conventional reburning. If the reburn fuel is natural gas, the combination of reburning and SNCR may result in a significant cost savings over conventional reburning. The third step, injection of methanol into the flue gas, is used to oxidize NO to N0[sub 2] which may subsequently be removed in a wet scrubber. Pilot-scale tests performed at EER's 1 MMBtu/hr Boiler Simulation Facility (BSF) have demonstrated NO[sub x] reductions up to 92%. The program's next phase entails process scale-up to a 10 MMBtu/hr furnace also located at EER's Santa Anna test site.

  10. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, July--September 1992

    SciTech Connect

    Not Available

    1992-12-31

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  11. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 4, July--September 1993

    SciTech Connect

    Not Available

    1993-12-29

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: NOx emissions not greater than one-third NSPS; SOx emissions not greater than one-third NSPS; and particulate emissions not greater than one-half NSPS. The specific secondary objectives are: improved ash disposability and reduced waste generation; reduced air toxics emissions; and increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

  12. Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Final report, September 1989--March 1994

    SciTech Connect

    Not Available

    1994-05-01

    This project has successfully advanced the technology for MSOFCs for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-cm{sup 2} per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  13. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-12-31

    The evaluation of various catalyst pre or pyrene coal conversion continued. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate. A technique to measure the effect of coal swelling and catalyst impregnation upon coal liquefaction has been developed, and experimentation is under way. Reactivity tests have been performed using S0{sub 2}-treated and untreated swelled Black Thunder Coal. Thermal reactions with swelled coals yielded much less coal conversion and pyrene conversion than did the swelled coal reactions with Molyvan-L. The study of bottoms processing consists of coupling solvent deasphalting with delayed coking to maximize the production of coal-derived liquids while rejecting solids within the coke drum. The batch deasphalting screening tests have been completed. While n-butane/pentane solvent blends initially appeared best, pentane alone at 380{degree}F provided an oil yield (63.6 wt%) that was desired for subsequent tests. The production of asphalt for the transport tests is underway. The target deasphalted oil yields are 40, 50 and 60 wt% of feed. This would produce asphalt with ash levels ranging from 20 to 30 wt% with which to run the transport tests.

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report No. 7, April 1993--June 1993

    SciTech Connect

    Curtis, C.W.; Chander, S.; Gutterman, C.

    1994-09-01

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. In addition, a synergistic effect has been demonstrated, in which solvent blends are more effective for coal swelling than the pure solvents alone. Therefore, it will be necessary to use only low levels of swelling agents and yet promote the impregnation of catalyst precursors. The rate of the impregnation of catalyst precursors into swollen coal increases greatly as the effectiveness of the solvent to swell the coal increases. This effect is also demonstrated by improved catalyst precursor impregnation with increased contact temperature. Laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent.

  15. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl

    2005-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. Filter media candidates were evaluated for dewatering the ultrafine ash (UFA) product. Media candidates were selected based on manufacturer recommendations and evaluated using standard batch filtration techniques. A final media was selected; 901F, a multifilament polypropylene. While this media would provide adequate solids capture and cake moisture, the use of flocculants would be necessary to enable adequate filter throughput. Several flocculant chemistries were also evaluated and it was determined that polyethylene oxide (PEO) at a dosage of 5 ppm (slurry basis) would be the most suitable in terms of both settling rate and clarity. PEO was evaluated on a continuous vacuum filter using 901F media. The optimum cycle time was found to be 1.25 minutes which provided a 305% moisture cake, 85% solids capture with a throughput of 115 lbs dry solids per hour and a dry cake rate of 25 lb/ft2/hr. Increasing cycle time not did not reduce cake moisture or increase throughput. A mobile demonstration unit has been designed and constructed for field demonstration. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities.

  16. Advanced CO{sub 2} Capture Technology for Low Rank Coal IGCC System

    SciTech Connect

    Alptekin, Gokhan

    2013-09-30

    The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in bituminous coal the net plant efficiency is about 2.4 percentage points higher than an Integrated Gasification Combined Cycle (IGCC) plant equipped with SelexolTM to capture CO{sub 2}. We also previously completed two successful field demonstrations: one at the National Carbon Capture Center (Southern- Wilsonville, AL) in 2011, and a second demonstration in fall of 2012 at the Wabash River IGCC plant (Terra Haute, IN). In this project, we first optimized the sorbent to catalyst ratio used in the combined WGS and CO{sub 2} capture

  17. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  18. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 15, April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  19. Upgraded Coal Interest Group

    SciTech Connect

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  20. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect

    Not Available

    1990-12-01

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  1. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    The construction of the DOE POC at the OCDO facility continued through this entire quarter. By the end of the quarter approximately 90% of all of the construction had been completed. All equipment has beeninstalled, checked for mechanical and installation and operated from a local pushbutton. During this quarter a review of items to be completed for start-up was compiled. This information was then presented to the construction subcontractors and agreement was concluded that all items will be completed and operational for processing coal by February 1, 1993. There are still several items that were not on site for installation during this quarter. These items are the flocculant controls supplied by Westec Engineering, Inc., and the discharge valve for the hyperbaric filter supplied by KHD. Neither of these items will prevent start-up. The flocculants can be manually controlled and provisions are all ready provided to bypass the hyperbaric filter to the Sharpels high-G centrifuge. Both of these items are scheduled for delivery in mid-January.

  2. Assessment of instrumentation needs for advanced coal power plant applications: Final report

    SciTech Connect

    Nelson, E.T.; Fischer, W.H.; Lipka, J.V.; Rutkowski, M.D.; Zaharchuk, R.

    1987-10-01

    The purpose of this study was to identify contaminants, identify instrumentation needs, assess available instrumentation and identify instruments that should be developed for controlling and monitoring gas streams encountered in the following power plants: Integrated Gasification Combined Cycle, Pressurized Fluidized Bed Combustion, and Gasification Molten Carbonate Fuel Cell. Emphasis was placed on hot gas cleanup system gas stream analysis, and included process control, research and environmental monitoring needs. Commercial process analyzers, typical of those currently used for process control purposes, were reviewed for the purpose of indicating commercial status. No instrument selection guidelines were found which were capable of replacing user interaction with the process analyzer vendors. This study leads to the following conclusions: available process analyzers for coal-derived gas cleanup applications satisfy current power system process control and regulatory requirements, but they are troublesome to maintain; commercial gas conditioning systems and in situ analyzers continue to be unavailable for hot gas cleanup applications; many research-oriented gas stream characterization and toxicity assessment needs can not be met by commercially available process analyzers; and greater emphasis should be placed on instrumentation and control system planning for future power plant applications. Analyzers for specific compounds are not recommended other than those needed for current process control purposes. Instead, some generally useful on-line laser-based and inductively coupled plasma methods are recommended for further development because of their potential for use in present hot gas cleanup research and future optimization, component protection and regulation compliance activities. 48 refs., 21 figs., 26 tabs.

  3. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 13, October--December, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-01-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit. During Quarter 13 (October--December 1995), testing of the GranuFlow dewatering process indicated a 3--4% reduction in cake moisture for screen-bowl and solid-bowl centrifuge products. The Orimulsion additions were also found to reduce the potential dustiness of the fine coal, as well as improve solids recovery in the screen-bowl centrifuge. Based on these results, Lady Dunn management now plans to use a screen bowl centrifuge to dewater their Microcel{trademark} column froth product. Subtask 3.3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter. Continuing Subtask 6.4 work, investigating coal-water-slurry formulation, indicated that selective agglomeration products can be formulated into slurries with lower viscosities than advanced flotation products. Subtask 6.5 agglomeration bench-scale testing results indicate that a very fine grind is required to meet the 2 lb ash/MBtu product specification for the Winifrede coal, while the Hiawatha coal requires a grind in the 100- to 150-mesh topsize range. Detailed design work remaining involves the preparation and issuing of the final task report. Utilizing this detailed design, a construction bid package was prepared and submitted to three Colorado based contractors for quotes as part of Task 9.

  4. In-plant testing of a novel coal cleaning circuit using advanced technologies. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect

    Honaker, R.Q.; Reed, S.; Mohanty, M.K.

    1997-05-01

    A circuit comprised of advanced fine coal cleaning technologies was evaluated in an operating preparation plant to determine circuit performance and to compare the performance with current technologies used to treat -16 mesh fine coal. The circuit integrated a Floatex hydrosizer, a Falcon enhanced gravity concentrator and a Jameson flotation cell. A Packed-Column was used to provide additional reductions in the pyritic sulfur and ash contents by treatment of the Floatex-Falcon-Jameson circuit product. For a low sulfur Illinois No. 5 coal, the pyritic sulfur content was reduced from 0.67% to 0.34% at a combustible recovery of 93.2%. The ash content was decreased from 27.6% to 5.84%, which equates to an organic efficiency of 95% according to gravity-based washability data. The separation performance achieved on a high sulfur Illinois No. 5 coal resulted in the rejection of 72.7% of the pyritic sulfur and 82.3% of the ash-forming material at a recovery of 8 1 %. Subsequent pulverization of the cleaned product and retreatment in a Falcon concentrator and Packed-Column resulted in overall circuit ash and pyritic sulfur rejections of 89% and 93%, respectively, which yielded a pyritic sulfur content reduction from 2.43% to 0.30%. This separation reduced the sulfur dioxide emission rating of an Illinois No. 5 coal from 6.21 to 1.75 lbs SO{sub 2}/MBTU, which is Phase I compliance coal. A comparison of the results obtained from the Floatex-Falcon-Jameson circuit with those of the existing circuit revealed that the novel fine coal circuit provides 10% to 20% improvement in mass yield to the concentrate while rejecting greater amounts of ash and pyritic sulfur.

  5. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  6. Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Ma, Wencheng; Hou, Baolin; Jia, Shengyong; Zhao, Qian

    2015-07-01

    Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon (SBAC) with ZnCl2 as activation agent, which was used as a support for ferric oxides to form a catalyst (FeOx/SBAC) by a simple impregnation method. The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater (CGW). The results indicated that the prepared FeOx/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide pH range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1g/L of catalyst, and the treated effluent concentrations of COD, total phenols, BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated FeOx/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, FeOx/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by FeOx/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.

  7. Advanced coal liquefaction. Quarterly report, January 1, 1994--March 31, 1994

    SciTech Connect

    1995-03-01

    This project investigated the use of ceramic membranes to improve liquefaction processes to meet both economical and environmental requirements. The separation of model compounds with a series of modified membranes were complete for Yr. I. The experimental system is presently under modification for performing the catalytic membrane reaction. In this quarter, the authors summarized the Yr.I experimental result as quarterly to satisfy the contractual reporting requirement. A series of 1{double_prime} and 10{double_prime} long membranes were modified through the CVD method to reduce the pore size. These tubes were characterized by He and N{sub 2} permeation as well as He/SF{sub 6} separation. The He and N{sub 2} permeances decreased with reducing pore size and porosity. The coronene and compound No. 11 mixture separation were performed in 10-inch long membranes. The model compound chosen for the catalytic membrane reaction was NBBM (naphthyl-bibenzyl-methane). The hydrogenolysis of this compound will generate toluene which can be selectively removed by the modified membrane. The NBBM/toluene separation was performed in 1{double_prime} long modified membranes. The GC calibration of NBBM, coronene, compound No. 11 and toluene were established and gave good accurate analysis. The results were accurate and reproducible using wide board capillary column with appropriate GC conditions. The coal-liquid separation through microporous ceramic membranes could be described by an ultrafiltration model. Two transport phenomenons, molecular diffusion and convection, were the most important mechanisms. The hindrance factors were necessary of these mechanisms to evaluate the separation performance of membrane and to design the catalytic membrane reactor. The hindrance factors can be calculated from that rejection and permeate flux based on the simplified Niemi-Palosaari method.

  8. Intelligent Control via Wireless Sensor Networks for Advanced Coal Combustion Systems

    SciTech Connect

    Aman Behal; Sunil Kumar; Goodarz Ahmadi

    2007-08-05

    Numerical Modeling of Solid Gas Flow, System Identification for purposes of modeling and control, and Wireless Sensor and Actor Network design were pursued as part of this project. Time series input-output data was obtained from NETL's Morgantown CFB facility courtesy of Dr. Lawrence Shadle. It was run through a nonlinear kernel estimator and nonparametric models were obtained for the system. Linear and first-order nonlinear kernels were then utilized to obtain a state-space description of the system. Neural networks were trained that performed better at capturing the plant dynamics. It is possible to use these networks to find a plant model and the inversion of this model can be used to control the system. These models allow one to compare with physics based models whose parameters can then be determined by comparing them against the available data based model. On a parallel track, Dr. Kumar designed an energy-efficient and reliable transport protocol for wireless sensor and actor networks, where the sensors could be different types of wireless sensors used in CFB based coal combustion systems and actors are more powerful wireless nodes to set up a communication network while avoiding the data congestion. Dr. Ahmadi's group studied gas solid flow in a duct. It was seen that particle concentration clearly shows a preferential distribution. The particles strongly interact with the turbulence eddies and are concentrated in narrow bands that are evolving with time. It is believed that observed preferential concentration is due to the fact that these particles are flung out of eddies by centrifugal force.

  9. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, July--September 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-12-31

    The experimental study of coal swelling ratios have been determined with a wide variety of solvents. Only marginal levels of coal swelling were observed for the hydrocarbon solvents, but high levels were found with solvents having heteroatom functionality. Blends were superior to pure solvents. The activity of various catalyst precursors for pyrene hydrogenation and coal conversion was measured. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively. Bottoms processing consists of a combination of the ASCOT process coupling solvent deasphalting with delayed coking. Initial results indicate that a blend of butane and pentane used near the critical temperature of butane is the best solvent blend for producing a yield/temperature relationship of proper sensitivity and yet retaining an asphalt phase of reasonable viscosity. The literature concerning coal swelling, both alone and in combination with coal liquefaction, and the use of dispersed or unsupported catalysts in coal liquefaction has been updated.

  10. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 14, January 1, 1992--March 31, 1992

    SciTech Connect

    Not Available

    1992-12-31

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development`s facility near Beverly, Ohio. OCDO`s facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  11. Engineering development of advanced coal-fired low-emission boiler systems. Quarterly technical progress report No. 17, October 1, 1996--December 31, 1996

    SciTech Connect

    Regan, J.W.; Bender, D.J.; Clark, J.P.; Wesnor, J.D.

    1997-01-01

    This report describes the work performed between October 1 and December 31, 1996 by the ABB team on U.S. Department of Energy project ``Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems`` (LEBS), which is part of the DOE`s Combustion 2000 Program. The overall objective of the LEBS Project is to dramatically improve environmental performance of future coal-fired power plants without adversely impacting efficiency or the cost of electricity. Near-term technologies, i.e., advanced technologies that are partially developed, will be used to reduce NO{sub x} and SO{sub 2} emission to one-sixth current NSPS limits and particulates to one- third current NSPS limits.

  12. Clean coal technologies market potential

    SciTech Connect

    Drazga, B.

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  13. An analysis of markets for small-scale, advanced coal-combustion technology in Spain, Italy, and Turkey

    SciTech Connect

    Placet, M.; Gerry, P.A.; Kenski, D.M.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1989-09-01

    This report discusses the examination of potential overseas markets for using small-scale, US-developed, advanced coal-combustion technologies (ACTs). In previous work, member countries of the Organization for Economic Cooperation and Development (OECD) were rated on their potential for using ACTs through a comprehensive screening methodology. The three most promising OECD markets were found to be Spain, Italy, and Turkey. This report provides in-depth analyses of these three selected countries. First, it addresses changes in the European Community with particular reference to the 1992 restructuring and its potential effect on the energy situation in Europe, specifically in the three subject countries. It presents individual country studies that examine demographics, economics, building infrastructures, and energy-related factors. Potential niches for ACTs are explored for each country through regional analyses. Marketing channels, strategies, and the trading environments in each country are also discussed. The information gathered indicates that Turkey is a most promising market, Spain is a fairly promising market, and Italy appears to be a somewhat limited market for US ACTs. 76 refs., 16 figs., 14 tabs.

  14. Advanced turbine design for coal-fueled engines. Topical report, Task 1.6, Task 1.7

    SciTech Connect

    Bornstein, N.S.

    1992-07-17

    The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500{degrees}F (815{degrees}C), relatively innocuous salts. In this study it is found that at 1650{degrees}F (900{degrees}C) and above, calcium sulfate becomes an aggressive corrodent.

  15. An advanced anaerobic biofilter with effluent recirculation for phenol removal and methane production in treatment of coal gasification wastewater.

    PubMed

    Li, Yajie; Tabassum, Salma; Zhang, Zhenjia

    2016-09-01

    An advanced anaerobic biofilter (AF) was introduced for the treatment of coal gasification wastewater (CGW), and effluent recirculation was adopted to enhance phenol removal and methane production. The results indicated that AF was reliable in treating diluted CGW, while its efficiency and stability were seriously reduced when directly treating raw CGW. However, its performance could be greatly enhanced by effluent recirculation. Under optimal effluent recirculation of 0.5 to the influent, concentrations of chemical oxygen demand (COD) and total phenol in the effluent could reach as low as 234.0 and 14.2mg/L, respectively. Also, the rate of methane production reached 169.0mLCH4/L/day. Though CGW seemed to restrain the growth of anaerobic microorganisms, especially methanogens, the inhibition was temporary and reversible, and anaerobic bacteria presented strong tolerance. The activities of methanogens cultivated in CGW could quickly recover on feeding with glucose wastewater (GW). However, the adaptability of anaerobic bacteria to the CGW was very poor and the activity of methanogens could not be improved by long-term domestication. By analysis using the Haldane model, it was further confirmed that high effluent recirculation could result in high activity for hydrolytic bacteria and substrate affinity for toxic matters, but only suitable effluent recirculation could result in high methanogenic activity. PMID:27593269

  16. Optical fiber evanescent wave adsorption sensors for high-temperature gas sensing in advanced coal-fired power plants

    SciTech Connect

    Buric, M.; Ohodnicky, P.; Duy, J.

    2012-01-01

    Modern advanced energy systems such as coal-fired power plants, gasifiers, or similar infrastructure present some of the most challenging harsh environments for sensors. The power industry would benefit from new, ultra-high temperature devices capable of surviving in hot and corrosive environments for embedded sensing at the highest value locations. For these applications, we are currently exploring optical fiber evanescent wave absorption spectroscopy (EWAS) based sensors consisting of high temperature core materials integrated with novel high temperature gas sensitive cladding materials. Mathematical simulations can be used to assist in sensor development efforts, and we describe a simulation code that assumes a single thick cladding layer with gas sensitive optical constants. Recent work has demonstrated that Au nanoparticle-incorporated metal oxides show a potentially useful response for high temperature optical gas sensing applications through the sensitivity of the localized surface plasmon resonance absorption peak to ambient atmospheric conditions. Hence, the simulation code has been applied to understand how such a response can be exploited in an optical fiber based EWAS sensor configuration. We demonstrate that interrogation can be used to optimize the sensing response in such materials.

  17. An advanced anaerobic biofilter with effluent recirculation for phenol removal and methane production in treatment of coal gasification wastewater.

    PubMed

    Li, Yajie; Tabassum, Salma; Zhang, Zhenjia

    2016-09-01

    An advanced anaerobic biofilter (AF) was introduced for the treatment of coal gasification wastewater (CGW), and effluent recirculation was adopted to enhance phenol removal and methane production. The results indicated that AF was reliable in treating diluted CGW, while its efficiency and stability were seriously reduced when directly treating raw CGW. However, its performance could be greatly enhanced by effluent recirculation. Under optimal effluent recirculation of 0.5 to the influent, concentrations of chemical oxygen demand (COD) and total phenol in the effluent could reach as low as 234.0 and 14.2mg/L, respectively. Also, the rate of methane production reached 169.0mLCH4/L/day. Though CGW seemed to restrain the growth of anaerobic microorganisms, especially methanogens, the inhibition was temporary and reversible, and anaerobic bacteria presented strong tolerance. The activities of methanogens cultivated in CGW could quickly recover on feeding with glucose wastewater (GW). However, the adaptability of anaerobic bacteria to the CGW was very poor and the activity of methanogens could not be improved by long-term domestication. By analysis using the Haldane model, it was further confirmed that high effluent recirculation could result in high activity for hydrolytic bacteria and substrate affinity for toxic matters, but only suitable effluent recirculation could result in high methanogenic activity.

  18. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 15, April 15 1996--June 1996

    SciTech Connect

    1996-08-19

    The Pittsburgh Energy Technology center of the US Department of Energy (DOE) has contracted with Combustion Engineering; Inc. (ABB CE) to perform work on the {open_quotes}Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems{close_quote} Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis and Phases II and III on a cost-share basis.

  19. Engineering development of advanced coal-fired low-emissions boiler systems. Fourth quarterly report, 1996

    SciTech Connect

    1997-02-01

    The goal of the NO{sub x} Subsystem is to achieve continuous operation of the Low Emissions Boiler System (LEBS) at NO{sub x} emissions at or below 0. 20 lb/MBtu through combustion techniques only, with a further target of 0.1 lb NO{sub x}/MBtu using supplementary advanced flue gas cleanup technologies if necessary. These goals places practical constraints that must be considered on the NO{sub x} Subsystem design. Not only must the boiler be designed to achieve time temperature mixing histories that minimize NO{sub x}, but it must also be designed to operate that way throughout its working lifetime. Therefore, NO{sub x} minimization strategies must be integrated into the control systems for every boiler component from the pulverizers to the stack. Furthermore, these goals must be met without increases in carbon loss and CO emissions from the levels achieved with current low-NO{sub x} combustion systems. Therefore, the NO{sub x} Subsystem requires not only sound mechanical designs of burners, furnace surface, and staging air/fuel injectors, but also sensors and software to allow control of their operation. Through engineering analysis, experimental testing, and numerical modeling in Phase 2, an advanced low NO{sub x} control system is being developed. The progress of these activities is presented in this report.

  20. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    SciTech Connect

    Not Available

    1993-09-01

    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  1. Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

    SciTech Connect

    Oguejiofor, G.C.

    2008-07-01

    Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

  2. The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995

    SciTech Connect

    Miller, B.G.; Bartley, D.A.; Hatcher, P.

    1996-10-15

    This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.

  3. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  4. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect

    Gregory J. McCarthy; Dean G. Grier

    2001-01-01

    Prior to the initiation of this study, understanding of the long-term behavior of environmentally-exposed Coal Combustion By-Products (CCBs) was lacking in (among others) two primary areas addressed in this work. First, no method had been successfully applied to achieve full quantitative analysis of the partitioning of chemical constituents into reactive or passive crystalline or noncrystalline compounds. Rather, only semi-quantitative methods were available, with large associated errors. Second, our understanding of the long-term behavior of various CCBs in contact with the natural environment was based on a relatively limited set of study materials. This study addressed these areas with two objectives, producing (1) a set of protocols for fully quantitative phase analysis using the Rietveld Quantitative X-ray Diffraction (RQXRD) method and (2) greater understanding of the hydrologic and geochemical nature of the long-term behavior of disposed and utilized CCBs. The RQXRD technique was initially tested using (1) mixtures of National Institute of Standards and Technology (NIST) crystalline standards, and (2) mixtures of synthetic reagents simulating various CCBs, to determine accuracy and precision of the method, and to determine the most favorable protocols to follow in order to efficiently quantify multi-phase mixtures. Four sets of borehole samples of disposed or utilized CCBs were retrieved and analyzed by RQXRD according to the protocols developed under the first objective. The first set of samples, from a Class F ash settling pond in Kentucky disposed for up to 20 years, showed little mineralogical alteration, as expected. The second set of samples, from an embankment in Indiana containing a mixture of chain-grate (stoker) furnace ash and fluidized bed combustion (FBC) residues, showed formation of the mineral thaumasite, as observed in previously studied exposed FBC materials. Two high-calcium CCBs studied, including a dry-process flue gas desulfurization

  5. Fever: is it beneficial?

    PubMed

    Blatteis, C M

    1986-01-01

    Data obtained in lizards infected with live bacteria suggest that fever may be beneficial to their survival. An adaptive value of fever has also been inferred in mammals, but the results are equivocal. Findings that certain leukocyte functions are enhanced in vitro at high temperatures have provided a possible explanation for the alleged benefits of fever. However, serious questions exist as to whether results from experiments in ectotherms and in vitro can properly be extrapolated to in vivo endothermic conditions. Indeed, various studies have yielded results inconsistent with the survival benefits attributed to fever, and fever is not an obligatory feature of all infections under all conditions. Certainly, the widespread use of antipyretics, without apparent adverse effects on the course of disease, argues against fever having great benefit to the host. In sum, although fever is a cardinal manifestation of infection, conclusive evidence that it has survival value in mammals is still lacking.

  6. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl; Robert Rathbone

    2006-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. Secondary classification was effective for producing an ultra-fine ash (UFA) product. Inclined lamella plates provided an effective settling surface for coarser ash particles and plate spacing was shown to be an important variable. Results showed that the closer the plate spacing, the finer the size distribution of the UFA product. Flotation of the secondary classifier feed provided a lower LOI UFA product (2.5% LOI vs. 4.5% LOI) and a dispersant dosage of 2 to 2.5 g/kg was adequate to provide UFA grade (3.8 to 4.4 {micro}m) and recovery (53 to 68% 5{micro}m recovery). The UFA yield without flotation was {approx}33% and lower ({approx}20%) with flotation. Demonstration plant product evaluations showed that water requirements in mortar were reduced and 100% of control strength was achieved in 28 days for the coarser products followed by further strength gain of up to 130% in 56 days. The highest strengths of 110% of control in 7 days and 140% in 56 days were achieved with the finer products. Mortar air requirements for processed products were essentially the same as those for standard mortar, suggesting that the unburned carbon remaining does not have

  7. A methodology for the environmental assessment of advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Sullivan, P. J.; Hutchinson, C. F.; Makihara, J.; Evensizer, J.

    1980-01-01

    Procedures developed to identify and assess potential environment impacts of advanced mining technology as it moves from a generic concept to a more systems definition are described. Two levels of assessment are defined in terms of the design stage of the technology being evaluated. The first level of analysis is appropriate to a conceptual design. At this level it is assumed that each mining process has known and potential environmental impacts that are generic to each mining activity. By using this assumption, potential environmental impacts can be identified for new mining systems. When two or more systems have been assessed, they can be evaluated comparing potential environmental impacts. At the preliminary stage of design, a systems performance can be assessed again with more precision. At this level of systems definition, potential environmental impacts can be analyzed and their significane determined in a manner to facilitate comparisons between systems. At each level of analysis, suggestions calculated to help the designer mitigate potentially harmful impacts are provided.

  8. Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  9. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly progress report No. 10, January--March 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-04-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and benchscale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by June, 1997. During Quarter 10 (January--March, 1995), preliminary work continued for the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant. Towards this end, laboratory flotation testing and refurbishing of the column have been started. The final version of the Subtask 4.2 Advanced Flotation Process Optimization Research topical report was issued, as was a draft version of the Subtask 4.3 report discussing the formulation of coal-water slurry fuels (CWF) from advanced flotation products. A number of product samples from Subtask 4.4 testing were sent to both Combustion Engineering and Penn State for combustion testing. The evaluation of toxic trace element analyses of column flotation products also continued. The detailed design of the 2 t/hr PDU was essentially completed with the approval of various process flow, plant layout, electrical, and vendor equipment drawings. The final version of the Subtask 6.5 -- Selective Agglomeration Bench-Scale Design and Test Plan Report was issued during this reporting quarter. Design and construction of this 25 lb/hr selective agglomeration test unit was completed and preliminary testing started. Construction of the 2 t/hr PDU began following the selection of TIC. The Industrial Company as the construction subcontractor.

  10. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. First annual report, September 1, 1990--August 30, 1991

    SciTech Connect

    Wang, Xiang-Huai

    1991-12-31

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  11. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    SciTech Connect

    Karmis, Michael; Luttrell, Gerald; Ripepi, Nino; Bratton, Robert; Dohm, Erich

    2014-09-30

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NOx, CO2, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  12. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    SciTech Connect

    Dennis, R.A.

    1997-05-01

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

  13. Removal of ash, sulfur, and trace elements of environmental concern from eight selected Illinois coals

    USGS Publications Warehouse

    Demir, I.

    1998-01-01

    Release analysis (RA) and float-sink (F-S) data were generated to assess the beneficiation potential of washed coals from selected Illinois coal preparation plants through the use of advanced physical cleaning at -60 mesh size. Generally, the F-S process removed greater amounts of ash, sulfur, and trace elements of environmental concern from the coals than the RA process, indicating that the cleanability of Illinois coals by advanced methods can be estimated best by F-S testing. At an 80%-combustibles recovery, the ash yield in the clean F-S products decreased by 47-75%, relative to the parent coals. Average decreases for the elements As(67%), Cd(78%), Hg(73%), Mn(71%), and P(66%) exceeded the average decrease for ash yield (55%). Average decreases for other elements were: Co(31%), Cr(27%), F(39%), Ni(25%), Pb(50%), S(28%), Sb(20%), Se(39), Th(32%), and U(8%). Only Be was enriched (up to 120%) in the clean products relative to the parent coals. These results suggested that the concentration of elements with relatively high atmospheric mobilities (As, Cd, F, Hg, Pb, and Se) during coal combustion can be reduced substantially in Illinois coals through the use of advanced physical cleaning. Advanced physical cleaning can be effective also for the removal of inorganic S. Environmental risks from the emission of other elements with enrichment or relatively low cleanabilities could be small because these elements generally have very low concentrations in Illinois coals or are largely retained in solid residues during coal combustion. ?? 1998 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint.

  14. Field study of disposed solid wastes from advanced coal processes. Annual technical progress report, October 1991--September 1992

    SciTech Connect

    Not Available

    1992-12-31

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute`s fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison`s limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United`s mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells.

  15. Beneficial Properties of Probiotics

    PubMed Central

    Shi, Lye Huey; Balakrishnan, Kunasundari; Thiagarajah, Kokila; Mohd Ismail, Nor Ismaliza; Yin, Ooi Shao

    2016-01-01

    Probiotics are live microorganisms that can be found in fermented foods and cultured milk, and are widely used for the preparation of infant food. They are well-known as “health friendly bacteria”, which exhibit various health beneficial properties such as prevention of bowel diseases, improving the immune system, for lactose intolerance and intestinal microbial balance, exhibiting antihypercholesterolemic and antihypertensive effects, alleviation of postmenopausal disorders, and reducing traveller’s diarrhoea. Recent studies have also been focused on their uses in treating skin and oral diseases. In addition to that, modulation of the gut-brain by probiotics has been suggested as a novel therapeutic solution for anxiety and depression. Thus, this review discusses on the current probiotics-based products in Malaysia, criteria for selection of probiotics, and evidences obtained from past studies on how probiotics have been used in preventing intestinal disorders via improving the immune system, acting as an antihypercholesterolemic factor, improving oral and dermal health, and performing as anti-anxiety and anti-depressive agents.

  16. Beneficial bacteria inhibit cachexia

    PubMed Central

    Varian, Bernard J.; Goureshetti, Sravya; Poutahidis, Theofilos; Lakritz, Jessica R.; Levkovich, Tatiana; Kwok, Caitlin; Teliousis, Konstantinos; Ibrahim, Yassin M.; Mirabal, Sheyla; Erdman, Susan E.

    2016-01-01

    Muscle wasting, known as cachexia, is a debilitating condition associated with chronic inflammation such as during cancer. Beneficial microbes have been shown to optimize systemic inflammatory tone during good health; however, interactions between microbes and host immunity in the context of cachexia are incompletely understood. Here we use mouse models to test roles for bacteria in muscle wasting syndromes. We find that feeding of a human commensal microbe, Lactobacillus reuteri, to mice is sufficient to lower systemic indices of inflammation and inhibit cachexia. Further, the microbial muscle-building phenomenon extends to normal aging as wild type animals exhibited increased growth hormone levels and up-regulation of transcription factor Forkhead Box N1 [FoxN1] associated with thymus gland retention and longevity. Interestingly, mice with a defective FoxN1 gene (athymic nude) fail to inhibit sarcopenia after L. reuteri therapy, indicating a FoxN1-mediated mechanism. In conclusion, symbiotic bacteria may serve to stimulate FoxN1 and thymic functions that regulate inflammation, offering possible alternatives for cachexia prevention and novel insights into roles for microbiota in mammalian ontogeny and phylogeny. PMID:26933816

  17. Beneficial bacteria inhibit cachexia.

    PubMed

    Varian, Bernard J; Goureshetti, Sravya; Poutahidis, Theofilos; Lakritz, Jessica R; Levkovich, Tatiana; Kwok, Caitlin; Teliousis, Konstantinos; Ibrahim, Yassin M; Mirabal, Sheyla; Erdman, Susan E

    2016-03-15

    Muscle wasting, known as cachexia, is a debilitating condition associated with chronic inflammation such as during cancer. Beneficial microbes have been shown to optimize systemic inflammatory tone during good health; however, interactions between microbes and host immunity in the context of cachexia are incompletely understood. Here we use mouse models to test roles for bacteria in muscle wasting syndromes. We find that feeding of a human commensal microbe, Lactobacillus reuteri, to mice is sufficient to lower systemic indices of inflammation and inhibit cachexia. Further, the microbial muscle-building phenomenon extends to normal aging as wild type animals exhibited increased growth hormone levels and up-regulation of transcription factor Forkhead Box N1 [FoxN1] associated with thymus gland retention and longevity. Interestingly, mice with a defective FoxN1 gene (athymic nude) fail to inhibit sarcopenia after L. reuteri therapy, indicating a FoxN1-mediated mechanism. In conclusion, symbiotic bacteria may serve to stimulate FoxN1 and thymic functions that regulate inflammation, offering possible alternatives for cachexia prevention and novel insights into roles for microbiota in mammalian ontogeny and phylogeny. PMID:26933816

  18. Beneficial Properties of Probiotics

    PubMed Central

    Shi, Lye Huey; Balakrishnan, Kunasundari; Thiagarajah, Kokila; Mohd Ismail, Nor Ismaliza; Yin, Ooi Shao

    2016-01-01

    Probiotics are live microorganisms that can be found in fermented foods and cultured milk, and are widely used for the preparation of infant food. They are well-known as “health friendly bacteria”, which exhibit various health beneficial properties such as prevention of bowel diseases, improving the immune system, for lactose intolerance and intestinal microbial balance, exhibiting antihypercholesterolemic and antihypertensive effects, alleviation of postmenopausal disorders, and reducing traveller’s diarrhoea. Recent studies have also been focused on their uses in treating skin and oral diseases. In addition to that, modulation of the gut-brain by probiotics has been suggested as a novel therapeutic solution for anxiety and depression. Thus, this review discusses on the current probiotics-based products in Malaysia, criteria for selection of probiotics, and evidences obtained from past studies on how probiotics have been used in preventing intestinal disorders via improving the immune system, acting as an antihypercholesterolemic factor, improving oral and dermal health, and performing as anti-anxiety and anti-depressive agents. PMID:27688852

  19. Beneficial Properties of Probiotics.

    PubMed

    Shi, Lye Huey; Balakrishnan, Kunasundari; Thiagarajah, Kokila; Mohd Ismail, Nor Ismaliza; Yin, Ooi Shao

    2016-08-01

    Probiotics are live microorganisms that can be found in fermented foods and cultured milk, and are widely used for the preparation of infant food. They are well-known as "health friendly bacteria", which exhibit various health beneficial properties such as prevention of bowel diseases, improving the immune system, for lactose intolerance and intestinal microbial balance, exhibiting antihypercholesterolemic and antihypertensive effects, alleviation of postmenopausal disorders, and reducing traveller's diarrhoea. Recent studies have also been focused on their uses in treating skin and oral diseases. In addition to that, modulation of the gut-brain by probiotics has been suggested as a novel therapeutic solution for anxiety and depression. Thus, this review discusses on the current probiotics-based products in Malaysia, criteria for selection of probiotics, and evidences obtained from past studies on how probiotics have been used in preventing intestinal disorders via improving the immune system, acting as an antihypercholesterolemic factor, improving oral and dermal health, and performing as anti-anxiety and anti-depressive agents. PMID:27688852

  20. Beneficial Properties of Probiotics.

    PubMed

    Shi, Lye Huey; Balakrishnan, Kunasundari; Thiagarajah, Kokila; Mohd Ismail, Nor Ismaliza; Yin, Ooi Shao

    2016-08-01

    Probiotics are live microorganisms that can be found in fermented foods and cultured milk, and are widely used for the preparation of infant food. They are well-known as "health friendly bacteria", which exhibit various health beneficial properties such as prevention of bowel diseases, improving the immune system, for lactose intolerance and intestinal microbial balance, exhibiting antihypercholesterolemic and antihypertensive effects, alleviation of postmenopausal disorders, and reducing traveller's diarrhoea. Recent studies have also been focused on their uses in treating skin and oral diseases. In addition to that, modulation of the gut-brain by probiotics has been suggested as a novel therapeutic solution for anxiety and depression. Thus, this review discusses on the current probiotics-based products in Malaysia, criteria for selection of probiotics, and evidences obtained from past studies on how probiotics have been used in preventing intestinal disorders via improving the immune system, acting as an antihypercholesterolemic factor, improving oral and dermal health, and performing as anti-anxiety and anti-depressive agents.

  1. Coal Combustion Science

    SciTech Connect

    Hardesty, D.R.; Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. )

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  2. Impact of supplemental firing of tire-derived fuel (TDF) on mercury species and mercury capture with the advanced hybrid filter in a western subbituminous coal flue gas

    SciTech Connect

    Ye Zhuang; Stanley J. Miller

    2006-05-15

    Pilot-scale experimental studies were carried out to evaluate the impacts of cofiring tire-derived fuel and a western subbituminous coal on mercury species in flue gas. Mercury samples were collected at the inlet and outlet of the Advanced Hybrid filter to determine mercury concentrations in the flue gas with and without TDF cofiring, respectively. Cofiring of TDF with a subbituminous coal had a significant effect on mercury speciation in the flue gas. With 100% coal firing, there was only 16.8% oxidized mercury in the flue gas compared to 47.7% when 5% TDF (mass basis) was fired and 84.8% when 10% TDF was cofired. The significantly enhanced mercury oxidation may be the result of additional homogeneous gas reactions between Hg{sup 0} and the reactive chlorine generated in the TDF-cofiring flue gas and the in situ improved reactivity of unburned carbon in ash by the reactive chlorine species. Although the cofiring of TDF demonstrated limited improvement on mercury-emission control with the Advanced Hybrid filter, it proved to be a very cost-effective mercury control approach for power plants equipped with wet or dry flue gas desulfurization (FGD) systems because of the enhanced mercury oxidation. 15 refs., 4 figs., 4 tabs.

  3. Fundamental bioprocessing research for coal applications

    SciTech Connect

    Kaufman, E.N.; Scott, T.C.

    1995-06-01

    The purpose of this program is to gain a fundamental understanding and sound scientific and technical basis for evaluating the potential roles of innovative bioprocessing concepts for the utilization and conversion of coal. The aim is to explore the numerous ways in which advanced biological processes and techniques can open new opportunities for coal utilization or can replace more conventional techniques by using milder conditions with less energy consumption or loss. There are several roles where biotechnology is likely to be important in coal utilization and conversion. These include potential bioprocessing systems such as conversion of coal to liquids or gases; biocatalytic beneficiation of coal-derived liquids and conversion to useful chemical feedstocks; biocatalytic removal of SO{sub x} and NO{sub x} from coal combustion off-gas; environmental control technology for the removal or destruction of hazardous materials in process effluents and/or solid residues; and the removal and utilization of CO{sub 2} from combustion off-gas. Effective bioprocesses for such applications will require detailed knowledge of the biological process mechanisms and advanced bioreactor technology than can be optimized for high productivity, as well as supporting upstream and downstream processes that will allow an effective integrated bioprocess. Of particular interest is the development of predictive models that can be used for process design and scaleup. In this program, a generic approach is taken so that there will be utility over a broad range of applications. In conjunction with the generic approach, model experimental systems that address real-world problems are used to verify the results.

  4. Low-rank coal research, Task 5.1. Topical report, April 1986--December 1992

    SciTech Connect

    Not Available

    1993-02-01

    This document is a topical progress report for Low-Rank Coal Research performed April 1986 - December 1992. Control Technology and Coal Preparation Research is described for Flue Gas Cleanup, Waste Management, Regional Energy Policy Program for the Northern Great Plains, and Hot-Gas Cleanup. Advanced Research and Technology Development was conducted on Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Combustion Research is described for Atmospheric Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Fuels (completed 10/31/90), Diesel Utilization of Low-Rank Coals (completed 12/31/90), Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications (completed 10/31/90), Nitrous Oxide Emission, and Pressurized Fluidized-Bed Combustion. Liquefaction Research in Low-Rank Coal Direct Liquefaction is discussed. Gasification Research was conducted in Production of Hydrogen and By-Products from Coals and in Sulfur Forms in Coal.

  5. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Quarterly technical progress report No. 11, April 1, 1994--June 30, 1994

    SciTech Connect

    Patel, R.; Borio, R.; Scaroni, A.W.; Miller, B.G.; McGowan, J.G.

    1994-09-23

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the tenth quarter of the program. The four hundred hours ``Proof-of-Concept System Test`` under Task 3 was completed during this quarter. The primary objectives were to obtain steady state operation consistently on coal only and increase carbon conversion efficiency from {approximately}95% to the project goal of 98%. This was to be obtained without increasing NO{sub x} emission above the project goal level of 0.6 lbs/MBtu ({approximately}425 ppM). The testing was also designed to show that consistent, reliable operation could be achieved as another prerequisite to the demonstration. The data were gathered and analyzed for both economic and technical analysis prior to committing to the long term demonstration. The Economic Evaluation was completed and work started on commercialization plan. During this reporting period, activities included sample analysis, data reduction and interpretation from all the testing during March and April. Following preliminary conclusions are drawn based on results evaluated: coal handling/preparation system can be designed to meet technical requirements for retrofitting microfine coal combustion; boiler thermal performance met requirement; NO{sub x} Emission can meet target of 0.6 lb/MBtu; combustion efficiencies of 95% could be met on a daily average basis, somewhat below target of 98%; economic playback very sensitive to fuel differential cost, unit size, and annual operating hours; and continuous long term demonstration needed to quantify ash effect and how to best handle.

  6. Structural features of a bituminous coal and their changes during low-temperature oxidation and loss of volatiles investigated by advanced solid-state NMR spectroscopy

    USGS Publications Warehouse

    Mao, J.-D.; Schimmelmann, A.; Mastalerz, Maria; Hatcher, P.G.; Li, Y.

    2010-01-01

    Quantitative and advanced 13C solid-state NMR techniques were employed to investigate (i) the chemical structure of a high volatile bituminous coal, as well as (ii) chemical structural changes of this coal after evacuation of adsorbed gases, (iii) during oxidative air exposure at room temperature, and (iv) after oxidative heating in air at 75 ??C. The solid-state NMR techniques employed in this study included quantitative direct polarization/magic angle spinning (DP/MAS) at a high spinning speed of 14 kHz, cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CH, CH2, and CHn selection, 13C chemical shift anisotropy (CSA) filtering, two-dimensional (2D) 1H-13C heteronuclear correlation NMR (HETCOR), and 2D HETCOR with 1H spin diffusion. With spectral editing techniques, we identified methyl CCH 3, rigid and mobile methylene CCH2C, methine CCH, quaternary Cq, aromatic CH, aromatic carbons bonded to alkyls, small-sized condensed aromatic moieties, and aromatic C-O groups. With direct polarization combined with spectral-editing techniques, we quantified 11 different types of functional groups. 1H-13C 2D HETCOR NMR experiments indicated spatial proximity of aromatic and alkyl moieties in cross-linked structures. The proton spin diffusion experiments indicated that the magnetization was not equilibrated at a 1H spin diffusion time of 5 ms. Therefore, the heterogeneity in spatial distribution of different functional groups should be above 2 nm. Recoupled C-H long-range dipolar dephasing showed that the fraction of large charcoal-like clusters of polycondensed aromatic rings was relatively small. The exposure of this coal to atmospheric oxygen at room temperature for 6 months did not result in obvious chemical structural changes of the coal, whereas heating at 75 ??C in air for 10 days led to oxidation of coal and generated some COO groups. Evacuation removed most volatiles and caused a significant reduction in aliphatic signals in its DP

  7. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect

    Not Available

    1992-08-24

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No[sub x]) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO[sub x] combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  8. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Second quarter 1992

    SciTech Connect

    Not Available

    1992-08-24

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  9. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  10. Separation and Purification of Mineral Salts from Spacecraft Wastewater Processing via Electrostatic Beneficiation

    NASA Technical Reports Server (NTRS)

    Miles, John D., II; Lunn, Griffin

    2013-01-01

    Electrostatic separation is a class of material processing technologies commonly used for the sorting of coarse mixtures by means of electrical forces acting on charged or polarized particles. Most if not all of the existing tribo-electrostatic separators had been initially developed for mineral ores beneficiation. It is a well-known process that has been successfully used to separate coal from minerals. Potash (potassium) enrichment where underground salt mines containing large amounts of sodium is another use of this techno logy. Through modification this technology can be used for spacecraft wastewater brine beneficiation. This will add in closing the gap beeen traveling around Earth's Gravity well and long-term space explorations. Food has been brought on all man missions, which is why plant growth for food crops continues to be of interest to NASA. For long-term mission considerations food productions is one of the top priorities. Nutrient recovery is essential for surviving in or past low earth orbit. In our advance bio-regenerative process instead of nitrogen gas produced; soluble nitrate salts that can be recovered for plant fertilizer would be produced instead. The only part missing is the beneficiation of brine to separate the potassium from the sodium. The use of electrostatic beneficiation in this experiment utilizes the electrical charge differences between aluminum and dried brine by surface contact. The helixes within the aluminum tribocharger allows for more surface contact when being agitated. When two materials are in contact, the material with the highest affinity for electrons becomes negatively charged, while the other becomes positively charged. This contact exchange of charge may cause the particles to agglomerate depending on their residence time within the tribocharger, compromising the efficiency of separation. The aim of this experiment is to further the development in electrostatic beneficiation by optimizing the separation of ersatz and

  11. Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China

    SciTech Connect

    Yang, C.; Zeng, G.; Li, G.; Qiu, J.

    1999-07-01

    Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

  12. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    SciTech Connect

    Rick Honaker; Gerald Luttrell

    2007-09-30

    The concept of using a dry, density-based separator to achieve efficient, near-face rock removal, commonly referred to as deshaling, was evaluated in several applications across the U.S.. Varying amounts of high-density rock exist in most run-of-mine feed. In the central Appalachian coalfields, a rock content exceeding 50% in the feed to a preparation plant is commonplace due to high amounts of out-of-seam dilution made necessary by extracting coal from thin seams. In the western U.S, an increase in out-of-seam dilution and environmental regulations associated with combustion emissions have resulted in a need to clean low rank coals and dry cleaning may be the only option. A 5 ton/hr mobile deshaling unit incorporating a density-based, air-table technology commercially known as the FGX Separator has been evaluated at mine sites located within the states of Utah, Wyoming, Texas, West Virginia, Virginia, Pennsylvania and Kentucky. The FGX technology utilizes table riffling principles with air as the medium. Air enters through the table and creates a fluidized bed of particles comprised of mostly fine, high density particles. The high density particle bed lifts the low-density coal particles to the top of the bed. The low-density coal moves toward the front of the table due to mass action and the downward slope of the table. The high-density particles settle through the fluidized particle bed and, upon making contact with the table, moves toward the back of the table with the assistance of table vibration. As a result, the low-density coal particles exit the front of the table closest to the feed whereas the high-density, high-ash content particles leave on the side and front of the table located at the farthest from the feed entry. At each test site, the run-of-mine feed was either directly fed to the FGX unit or pre-screened to remove the majority of the -6mm material. The surface moisture of the feed must be maintained below 9%. Pre-screening is required when the

  13. Report of activities of the advanced coal extraction systems definition project for the period 1979-1980

    SciTech Connect

    Lavin, M.L.; Isenberg, L.

    1981-08-01

    The primary focus of the Project during 1979-1980 was formulation of system level performance goals and the translation of these goals into conceptual design requirements. The overall performance goals, although presented as specific to the Central Appalachian resource, are general in all areas except mine size and regional geology. Five system performance areas were covered: production cost, miner safety and health, environmental impact, and coal conservation. During the latter portion of 1980, project attention turned to transformation into conceptual design requirements the previously identified opportunities to meet the systems requirements. The Central Appalachian coals were chosen as the focus of the early system definition work on the basis of a brief analysis. Preliminary estimates indicated substantial deposits of coal in the Gulf Coast and the Brooks Range region of Alaska. At the close of 1980, this resource study was in the midst of an in-depth analysis of substantial coal deposits within the five major coal provinces - Appalachia, the Interior, the Rocky Mountains, the Gulf Coast, and Alaska. Finally, the project launched a brief conceptual design activity in early 1979, and performed a broad survey of current R and D in underground mining technology. Subsequent work in the area of technology assessment focused on underground slurry transport.

  14. Feasibility study for an advanced coal fired heat exchanger/gas turbine topping cycle for a high efficiency power plant. Final report

    SciTech Connect

    Solomon, P.R.; Zhao, Y.; Pines, D.; Buggeln, R.C.; Shamroth, S.J.

    1993-11-01

    Significant improvements in efficiency for the conversion of coal into electricity can be achieved by cycles which employ a high temperature gas turbine topping cycle. The objective of this project is the development of an externally fired gas turbine system. The project computationally tested a new concept for a High Temperature Advanced Furnace (HITAF) and high temperature heat exchanger with a proprietary design to reduce the problems associated with the harsh coal environment. The program addressed two key technology issues: (1) the HITAF/heat exchanger heat transfer through a 2-D computer analysis of the HITAF configuration; (2) 3-D Computational Fluid Dynamics (CFD) model application to simulate the exclusion of particles and corrosive gases from the heat exchanger surface. The basic concept of this new combustor design was verified through the 2D and 3D modeling. It demonstrated that the corrosion and erosion of the exchanger material caused by coal and ash particles can be largely reduced by employing a specially designed firing scheme. It also suggested that a proper combustion geometry design is necessary to maximize the cleaning effect.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 12, July 1, 1991--September 30, 1991

    SciTech Connect

    Not Available

    1991-12-31

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no ``new`` reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality? The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  16. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 11, April 1, 1991--June 30, 1991

    SciTech Connect

    Not Available

    1991-12-31

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  17. Cooperative research program in coal liquefaction

    SciTech Connect

    Huffman, G.P.; Sendlein, L.V.A.

    1990-01-01

    Cooperative research in coal liquefaction is presented. Topics include: Sulfate-promoted metal oxides as direct coal liquefaction catalysts; low temperature depolymerization and liquefaction of premium US coal samples; construction of continuous flow-through gas reactor for liquefaction investigations; examination of ferric sulfide as a liquefaction catalyst; generic structural characterization and liquefaction research; spectroscopic studies of coal macerals depolymerization catalyzed by iron chloride; characterization of catalysts used in coal hydrogenation systems; coal structure/liquefaction yield correlation by means of advanced NMR techniques; mass spectrometry of coal derived liquids: determination of molecular weight distributions; catalyst cracking, hydrogenation and liquefaction of coals under milder conditions; ENDOR investigations of coal liquefaction under mild conditions; direct determination of hydroaromatic structures in coal and coal conversion products by catalytic dehydrogenation; surface characterization of APCSB coals by XPS; computation chemistry of model compounds and molecular fragments of relevance to coal liquefaction; chemical characterization and hydrogenation reactions of single coal particles; the role of hydrogen during liquefaction using donor and non-donor solvents; solvent sorption and FTIR studies on the effect of catalytic depolymerization reactions in coal; bioprocessing of coal; chemical routes to breaking bonds: new approaches to low-temperature liquefaction; an investigation into the reactivity of isotetralin and tetralin using molecular orbital calculations; coal liquefaction modification for enhanced reactivity; catalytic hydropyrolysis and energized extraction of coals; gallium catalyst in mild coal liquefaction -- potential of temperature microscope in coal liquefaction; evaluation of nitride catalysts for hydrotreatment and coal liquefaction; and improved catalysts for coal liquefaction and coprocessing.

  18. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  19. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    SciTech Connect

    1998-01-01

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  20. Studies of in-situ calcium based sorbents in advanced pressurized coal conversion systems. Final report, June 1991--October 1994

    SciTech Connect

    Katta, S.; Shires, P.J.; Campbell, W.M.; Henningsen, G.

    1994-10-01

    The overall objective of this project was to obtain experimental data on the reactions of calcium-based sorbents in both air-blown coal gasification systems and second generation fluid bed coal combustion systems (partial gasification) as well as stabilization of the spent sorbent produced. The project consisted of six tasks: Tasks 1 and 2 dealt mostly with project-related activities and preparation of test equipment, Task 3 -- study on sulfidation of calcium-based sorbents, Task 4 -- kinetic studies on calcium-catalyzed carbon gasification reactions, and Task 5 -- oxidation of CaS present in LASHs and DASHs (mixtures of coal ash and limestone or dolomite respectively) to CaSO{sub 4} and absorption of SO{sub 2} on various solids, and Task 6 -- economic evaluation of the most promising CaS oxidation method developed under this program. Experimental studies were conducted primarily to address Task 5 issues, and are discussed in this report.

  1. Advanced coal gasification system for electric power generation. Third quarterly progress report, April 1-June 30, 1980

    SciTech Connect

    1980-07-25

    The operation, maintenance and modifications to the Westinghouse gasification process development unit during the quarter are reviewed. The tests of the gasifier-agglomerator included direct coal feed as well as oxygen-blown gasification of a char or coal bed. Then the whole system was tested in single and double stage operation. Laboratory support involved fluidized bed test facilities at ambient temperature and at design temperature for devolatilization and gasification studies. Other laboratory systems were related to thermal analysis and pressurized high temperature studies of gasification and gas cleaning. (LTN)

  2. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 11, April 1995--June 1995

    SciTech Connect

    1995-08-30

    The Pittsburgh Energy Technology Center of the U.S. Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the {open_quotes}Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems{close_quotes} Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis and Phases II and III on a cost-share basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: (1) NO{sub x} emissions not greater than one-third NSPS. (2) SO{sub x} emissions not greater than one-third NSPS. (3) Particulate emissions not greater than one-half NSPS. The specific secondary objectives are: (1) Improved ash disposability and reduced waste generation. (2) Reduced air toxics emissions. (3) Increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a Commercial Generation Unit. The work in Phase I covered a 24-month period and included system analysis, RD&T Plan formulation, component definition, and preliminary Commercial Generating Unit (CGU) design. Phase II will cover a 15-month period and will include preliminary Proof-of-Concept Test Facility (POCTF) design and subsystem testing. Phase III will cover a 9-month period and will produce a revised CGU design and a revised POCTF design, cost estimate and a test plan. Phase IV, the final Phase, will cover a 36-month period and will include POCTF detailed design, construction, testing, and evaluation.

  3. Engineering development of advanced coal-fired low-emission boiler systems: Technical progress report No. 16, July-September 1996

    SciTech Connect

    Barcikowski, G.F.; Borio, R.W.; Bozzuto, C.R.; Burr, D.H.; Cellilli, L.; Fox, J.D.; Gibbons, T.B.; Hargrove, M.J.; Jukkola, G.D.; King, A.M.

    1996-11-27

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The Project is under budget and generally on schedule. The current status is shown in the Milestone Schedule Status Report included as Appendix A. Under Task 7--Component development and optimization, the CeraMem filter testing was completed. Due to an unacceptably high flue gas draft loss, which will not be resolved in the POCTF timeframe, a decision was made to change the design of the flue gas cleaning system from Hot SNO{sub x}{sup {trademark}} to an advanced dry scrubber called New Integrated Desulfurization (NID). However, it is recognized that the CeraMem filter still has the potential to be viable in pulverized coal systems. In Task 8-- Preliminary POCTF design, integrating and optimizing the performance and design of the boiler, turbine/generator and heat exchangers of the Kalina cycle as well as the balance of plant design were completed. Licensing activities continued. A NID system was substituted for the SNO{sub x} Hot Process.

  4. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Final report

    SciTech Connect

    Patel, R.L.; Thornock, D.E.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1998-03-01

    Economics and/or political intervention may one day dictate the conversion from oil or natural gas to coal in boilers that were originally designed to burn oil or gas. In recognition of this future possibility the US Department of Energy, Federal Energy Technical Center (DOE-FETC) supported a program led by ABB Power Plant Laboratories with support from the Energy and Fuels Research Center of Penn State University with the goal of demonstrating the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of the overall goal the following specific objectives were targeted: develop a coal handling/preparation system that can meet the technical and operational requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; maintain boiler thermal performance in accordance with specifications when burning oil or natural gas; maintain NOx emissions at or below 0.6 lb NO{sub 2} per million Btu; achieve combustion efficiencies of 98% or higher; and determine economic payback periods as a function of key variables.

  5. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  6. N sub 2 O formation from advanced NO sub x control processes (selective non-catalytic reduction and coal reburning)

    SciTech Connect

    Montgomery, T.A.; Martz, T.D.; Quartucy, G.C.; Muzio, L.J. ); Sheldon, M.S.; Cole, J.A.; Kramlich, J.C. ); Samuelsen, G.S.; Reddy, V. )

    1991-04-01

    The current work addressed the potential of N{sub 2}O production from two NO{sub x} reduction techniques: selective non-catalytic NO{sub x} reduction (SNCR processes) and reburning with pulverized coal. The effects of SNCR processes (utilizing ammonia, urea, and cyanuric acid injection) and reburning processes (with bituminous and lignite coals) upon NO{sub x} and N{sub 2}O levels were evaluated. Pilot scale testing and chemical kinetic modeling were used to characterize the N{sub 2} production from SNCR processes over a range of process parameters. The data show that the evaluated SNCR processes (ammonia, urea, and cyanuric acid injection) produced some N{sub 2}O as a by-product. Ammonia injection produced the lowest levels of N{sub 2}O; less than 4% of the reduced NO{sub x} was converted to N{sub 2}O. Cyanuric acid injection produced the highest levels; N{sub 2}O increases ranged between 12--40% of the reduced NO{sub x}. The conversion of NO{sub x} to N{sub 2}O with urea injection ranged from 7--25%. Pilot scale testing was used to characterize the N{sub 2}O production from reburning processes with coal over a range of process parameters. Parameters included: coal type, firing rate, initial NO level, and reburn zone stoichiometry. Data show that N{sub 2}O is not a major product during coal reburning processes for NO{sub x} reduction. 56 figs., 13 tabs.

  7. Advanced direct liquefaction concepts for PETC generic units. [Mainly, the effect of preteatment of coal with carbon monoxide and steam

    SciTech Connect

    Not Available

    1992-08-01

    CAER/UK: Detail coal and starting solvents from Wilsonville were analyzed to develop the data necessary to conduct process studies in the CO Pretreatment and Catalyst Evaluation segment of this program. A comparison of the solvent separation analysis with the distillation/separation used at Wilsonville showed that the residual solvent components contained a large amount of residual pentane soluble products. The ashy resid contained 3% iron and 400 ppM molybdenum. Although the iron content in the distillate and deashed resid was much less, namely about 200 ppM., the molybdenum concentrations in these fractions were not significantly reduced over the concentration in the ashy resid, i.e., 200 ppM in each. The pretreatment of coal with CO/H{sub 2}O in the presence of NaOH and Na{sub 2}CO{sub 3} has been shown to give a product which is lower in oxygen content and higher in hydrogen content compared to the raw coal. The atomic H/C ratios of the H{sub 2}O-insolubles, THF insolubles and the PA+A fractions of the products-together with the hydrogen consumption data suggested that the raw coal has been substantially depolymerized and hydrogenated via the WGS reaction during the pretreatment process. The extensive amount of molecular reconstruction that has occurred in the solid product was evident from the ease of solubilization of the product into pyridine. The result of the pretreatment process is a product which is highly reactive under hydroliquefaction conditions at 400{degrees}C. Reaction rates seem to be much faster than the raw coal, especially at shorter reaction times, providing the opportunity for major reductions in plant vessel sizes, and preliminary data has led us to believe that better efficiency in hydrogen utilization is achieved.

  8. A Course in Coal Science and Technology.

    ERIC Educational Resources Information Center

    Wheelock, T. D.

    1978-01-01

    This course introduces graduate students and advanced undergraduates to coal science and technology. Topics include: (1) the nature and occurrence of coal, (2) its chemical and physical characteristics, (3) methods of cleaning and preparing coal, and (4) processes for converting coal into clean solid, liquid, and gaseous fuels, as well as coke.…

  9. Demonstration of advanced combustion NO{sub X} control techniques for a wall-fired boiler. Project performance summary, Clean Coal Technology Demonstration Program

    SciTech Connect

    2001-01-01

    The project represents a landmark assessment of the potential of low-NO{sub x} burners, advanced overtire air, and neural-network control systems to reduce NO{sub x} emissions within the bounds of acceptable dry-bottom, wall-fired boiler performance. Such boilers were targeted under the Clean Air Act Amendments of 1990 (CAAA). Testing provided valuable input to the Environmental Protection Agency ruling issued in March 1994, which set NO{sub x} emission limits for ''Group 1'' wall-fired boilers at 0.5 lb/10{sup 6} Btu to be met by January 1996. The resultant comprehensive database served to assist utilities in effectively implementing CAAA compliance. The project is part of the U.S. Department of Energy's Clean Coal Technology Demonstration Program established to address energy and environmental concerns related to coal use. Five nationally competed solicitations sought cost-shared partnerships with industry to accelerate commercialization of the most advanced coal-based power generation and pollution control technologies. The Program, valued at over $5 billion, has leveraged federal funding twofold through the resultant partnerships encompassing utilities, technology developers, state governments, and research organizations. This project was one of 16 selected in May 1988 from 55 proposals submitted in response to the Program's second solicitation. Southern Company Services, Inc. (SCS) conducted a comprehensive evaluation of the effects of Foster Wheeler Energy Corporation's (FWEC) advanced overfire air (AOFA), low-NO{sub x} burners (LNB), and LNB/AOFA on wall-fired boiler NO{sub x} emissions and other combustion parameters. SCS also evaluated the effectiveness of an advanced on-line optimization system, the Generic NO{sub x} Control Intelligent System (GNOCIS). Over a six-year period, SCS carried out testing at Georgia Power Company's 500-MWe Plant Hammond Unit 4 in Coosa, Georgia. Tests proceeded in a logical sequence using rigorous statistical analyses to

  10. Cooperative research program in coal liquefaction

    SciTech Connect

    Huffman, G.P.; Sendlein, L.V.A.

    1991-01-01

    This report is a coordinated effort of the Consortium for Fossil Fuel Liquefaction Science. The topics concerning coal liquefaction discussed are: sulfate promoted metal oxides as direct coal liquefaction catalysts; low temperature depolymerization and liquefaction of premium R.S. coal samples; construction of continuous flow-through gas reactor for liquefaction investigations; generic structural characterization and liquefaction research; macerals, model compounds and iron catalyst dispersion; coal structure/liquefaction yield correlation by means of advanced NMR techniques; GC/MS of model compound mixtures; catalytic cracking, hydrogenation and liquefaction of coals under milder conditions; ENDOR investigations of coal liquefaction under mild conditions; catalytic dehydrogenation of model compounds in relation to direct coal liquefaction; surface characterization of catalyst added coal samples; computational chemistry of model compounds and molecular fragments of relevance to coal liquefaction; chemical characterization and hydrogenation reactions of single coal particles; thermolytic cleavage of selected coal-related linkages at mild temperatures; solvent sorption and FTIR studies on the effect of catalytic depolymerization reactions in coal; bioprocessing of coal; chemical routes to breaking bonds; novel liquefaction concepts cyclic olefins: novel new donors for coal liquefaction; better hydrogen transfer in coal liquefaction; catalytic hydropyrolysis and energized extraction of coals; gallium catalyst in mild coal liquefaction; potential of temperature microscope in coal liquefaction; evaluation of nitride catalysts for hydrotreatment and coal liquefaction; coprocessing and coal liquefaction with novel catalysts.

  11. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 4

    SciTech Connect

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-11-04

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the 4th quarter of the project from July 1 to September 30, 1993.

  12. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

  13. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  14. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. Ninth quarterly technical progress report, September 1, 1992-- December 31, 1992

    SciTech Connect

    Wang, X.H.; Leonard, J.W.; Parekh, B.K.; Jiang, C.L.

    1992-12-31

    This is the 9th quarterly technical progress report for the project entitled ``Pyrite surface characterization and control for advanced fine coal desulfurization technologies``, DE-FG22-90PC90295. The work presented in this report was performed from September 1, 1992 to November 31, 1992. The objective of the project is to conduct extensive fundamental studies on the surface chemistry of pyrite oxidation and flotation and to understand how the alteration of the coal-pyrite surface affects the efficiency of pyrite rejection in coal flotation. During this reporting period, the surface oxidation of pyrite in various electrolytes was investigated. It has been demonstrated, for the first time, that borate, a pH buffer and electrolyte used by many previous investigators in studying sulfide mineral oxidation, actively participates in the surface oxidation of pyrite. In borate solutions, the surface oxidation of pyrite is tronly enhanced. The anodic oxidation potential of pyrite is lowered by more than 0.4 volts. The initial reaction of the borate enhanced pyrite oxidation can be described by:FeS{sub 2} + B(OH){sub 4}{sup =} ------> [S{sub 2}Fe-B(OH){sub 4}]{sub surf} + e. This reaction is irreversible and is controlled by the mass-transfer of borate species from the solution to the surface. It has been shown that the above reaction inhibits the adsorption of xanthate on pyrite. Comparative studies have been made with other sulfide minerals. The solution chemistry of the iron-borate systems have been studied to understand the electrochemical results.

  15. Chemical structures of coal lithotypes before and after CO2 adsorption as investigated by advanced solid-state 13C nuclear magnetic resonance spectroscopy

    USGS Publications Warehouse

    Cao, X.; Mastalerz, Maria; Chappell, M.A.; Miller, L.F.; Li, Y.; Mao, J.

    2011-01-01

    Four lithotypes (vitrain, bright clarain, clarain, and fusain) of a high volatile bituminous Springfield Coal from the Illinois Basin were characterized using advanced solid-state 13C nuclear magnetic resonance (NMR) spectroscopy. The NMR techniques included quantitative direct polarization/magic angle spinning (DP/MAS), cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CHn selection, and recoupled C-H long-range dipolar dephasing techniques. The lithotypes that experienced high-pressure CO2 adsorption isotherm analysis were also analyzed to determine possible changes in coal structure as a result of CO2 saturation at high pressure and subsequent evacuation. The main carbon functionalities present in original vitrain, bright clarain, clarain and fusain were aromatic carbons (65.9%-86.1%), nonpolar alkyl groups (9.0%-28.9%), and aromatic C-O carbons (4.1%-9.5%). Among these lithotypes, aromaticity increased in the order of clarain, bright clarain, vitrain, and fusain, whereas the fraction of alkyl carbons decreased in the same order. Fusain was distinct from other three lithotypes in respect to its highest aromatic composition (86.1%) and remarkably small fraction of alkyl carbons (11.0%). The aromatic cluster size in fusain was larger than that in bright clarain. The lithotypes studied responded differently to high pressure CO2 saturation. After exposure to high pressure CO2, vitrain and fusain showed a decrease in aromaticity but an increase in the fraction of alkyl carbons, whereas bright clarain and clarain displayed an increase in aromaticity but a decrease in the fraction of alkyl carbons. Aromatic fused-rings were larger for bright clarain but smaller for fusain in the post-CO2 adsorption samples compared to the original lithotypes. These observations suggested chemical CO2-coal interactions at high pressure and the selectivity of lithotypes in response to CO2 adsorption. ?? 2011 Elsevier B.V.

  16. Development of advanced NO{sub x} control concepts for coal-fired utility boilers. Quarterly technical progress report No. 8, July 1, 1992--September 30, 1992

    SciTech Connect

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-03-04

    The complete CombiNO{sub x}, process has now been demonstrated at a level that is believed to be representative of a full-scale boiler in terms of mixing capabilities. A summary of the results is displayed in Figure 5-1. While firing Illinois Coal on the Reburn Tower, Advanced Reburning was capable of reducing NO{sub x}, by 83 percent. The injection of methanol oxidized 50--58 percent of the existing NO to N0{sub 2}. Assuming that 85 percent of the newly formed N0{sub 2} can be scrubbed in a liquor modified wet-limestone scrubber, the CombiNO{sub x}, process has been shown capable of reducing NO{sub 2}, by 90--91 percent in a large pilot-scale coal-fired furnace. There is still uncertainty regarding the fate of the N0{sub 2} formed with methanol injection. Tests should be conducted to determine whether the reconversion is thermodynamic or catalytic, and what steps can be taken (such as quench rate) to prevent it from happening.

  17. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 12, July--September 1995

    SciTech Connect

    1995-11-27

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The goals for emissions and plant efficiency are: NO{sub x} emissions not greater than 0.1 lb/million Btu; SO{sub x} emissions not greater than 0.1 lb/million Btu; particulate emissions not greater than 0.01 lb/million Btu; and net plant efficiency (HHV basis) not less than 42%. Other goals include: improved ash disposability and reduced waste generation; and reduced air toxics emissions. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives, and a preliminary design of a Commercial Generation Unit. The work in Phase I covered a 24- month period and included system analysis, RD&T Plan formulation, component definition, and preliminary Commercial Generating Unit (CGU) design. Phase II will cover a 15-month period and will include preliminary Proof-of-Concept Test Facility (POCTF) design and subsystem testing. Phase III will cover a 9-month period and will produce a revised CGU design and a revised POCTF design, cost estimate and a test plan. Phase IV, the final Phase, will cover a 36- month period and will include POCTF detailed design, construction, testing, and evaluation.

  18. Development of a Coal Quality Expert

    SciTech Connect

    1998-06-20

    ABB Power Plant Laboratories Combustion Engineering, Inc., (ABB CE) and CQ Inc. completed a broad, comprehensive program to demonstrate the economic and environmental benefits of using higher quality U.S. coals for electrical power generation and developed state-of-the-art user-friendly software--Coal Quality Expert (CQE)-to reliably predict/estimate these benefits in a consistent manner. The program was an essential extension and integration of R and D projects performed in the past under U.S. DOE and EPRI sponsorship and it expanded the available database of coal quality and power plant performance information. This software will permit utilities to purchase the lowest cost clean coals tailored to their specific requirements. Based on common interest and mutual benefit, the subject program was cosponsored by the U.S. DOE, EPRI, and eight U.S. coal-burning utilities. In addition to cosponsoring this program, EPN contributed its background research, data, and computer models, and managed some other supporting contracts under the terms of a project agreement established between CQ Inc. and EPRI. The essential work of the proposed project was performed under separate contracts to CQ Inc. by Electric Power Technologies (El?'T), Black and Veatch (B and V), ABB Combustion Engineering, Babcock and Wilcox (B and W), and Decision Focus, Inc. Although a significant quantity of the coals tied in the United States are now cleaned to some degree before firing, for many of these coals the residual sulfur content requires users to install expensive sulfur removal systems and the residual ash causes boilers to operate inefficiently and to require frequent maintenance. Disposal of the large quantities of slag and ash at utility plant sites can also be problematic and expensive. Improved and advanced coal cleaning processes can reduce the sulfur content of many coals to levels conforming to environmental standards without requiring post-combustion desulfurization systems. Also

  19. Coal cleaning process

    SciTech Connect

    Kindig, J.K.

    1994-01-11

    Fine particle coal is beneficiated in specially designed dense medium cyclones to improve particle acceleration and enhance separation efficiency. Raw coal feed is first sized to remove fine coal particles. The coarse fraction is then separated into clean coal, middlings, and refuse. Middlings are comminuted for beneficiation with the fine fraction. The fine fraction is deslimed in a countercurrent cyclone circuit and then separated as multiple fractions of different size specifications in dense medium cyclones. The dense medium contains ultra-fine magnetite particles of a narrow size distribution which aid separation and improves magnetite recovery. Magnetite is recovered from each separated fraction independently, with non-magnetic effluent water from one fraction diluting feed to a smaller-size fraction, and improving both overall coal and magnetite recovery. Magnetite recovery is in specially designed recovery units, based on particle size, with final separation in a rougher-cleaner-scavenger circuit of magnetic drum separators incorporating a high strength rare earth magnet. 12 figs.

  20. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect

    1994-12-01

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  1. Distribution of chlorine in coal

    SciTech Connect

    Zhao Fenghua; Ren Deyi; Zhang Shuangquan; Zhang Wang

    1998-12-31

    The current advance of study on chlorine in coal is reviewed. The concentrations of chlorine in 45 Chinese coal samples are determined on whole coal basis using instrumental neutron activation analysis (INAA). The sequential chemical extraction method is put forward to determine the occurrence modes of chlorine in coal. The research shows that Chinese coals are not chlorine-rich ones compared with those from other countries. In coal from Pingshuo Antaibao Opencast Mine, 46.70%--91.78% of chlorine is in a water-soluble state, 5.20%--48.38% of it is organic chlorine bonded to coal molecules, and only 4.92%--18.78% is an organic one in an ion-exchange state; the proportions of organic chlorine increase with the decrease in ash of coal.

  2. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2002-05-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  3. Advanced turbine design for coal-fueled engines. Quarterly technical report, [July 1, 1989--September 30, 1989

    SciTech Connect

    Not Available

    1989-12-31

    Coal-fueled gas turbines require the development of a number of new technologies which are being identified by METC and its Heat Engines Contractors. Three significant problems, that were Identified early in the development of coal-fueled engines, are the rapid wear of the turbine airfoils due to particulate erosion, the accumulation of deposits on portions of the airfoil surfaces due to slag deposition and the rapid corrosion of airfoils after the breakdown of surface coatings. The technology development study contained in this program is focused on improving the durability of the turbine through the development of erosion and deposition resistant airfoils and turbine operating conditions. The baseline turbine meanline design vas modified to prevent a local shock on the suction side of the rotor airfoil. New particle dimensionless parameters to be varied were determined. Three first-stage turbine meanline designs have been completed. The design of nev turbine airfoil shapes has been initiated. The calculation of particle trajectories has been completed for the baseline turbine vane and blade airfoils. The erosion model described in the previous technical report vas incorporated in the Post Processing Trajectory Analysis Code.

  4. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect

    DeLallo, M.R.; Zaharchuk, R.; Reuther, R.B.; Bonk, D.L.

    1996-09-01

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  5. Bioaccumulation and effects of metals and trace elements from aquatic disposal of coal combustion residues: recent advances and recommendations for further study.

    PubMed

    Rowe, Christopher L

    2014-07-01

    Advances have been made recently in assessing accumulation and effects of coal combustion residues (CCR). I provide a brief review of recent advancements, provide a tabulated summary of results of recent work, and put forth recommendations for future studies. One advancement is that mercury accumulation has begun to receive (limited) attention, whereas it had rarely been considered in the past. Additionally, some constituents of CCR have been shown to be accumulated by adults and transferred to offspring, sometimes compromising offspring health. Studies have demonstrated that amphibians, possessing complex life cycles, may accumulate and transfer some contaminants to terrestrial systems. Some study has been given to molecular and cellular effects of CCR exposure, although these studies have been limited to invertebrates. Population models have also been applied to CCR affected systems and have shown that CCR may affect animal populations under some conditions. In light of these advancements, there are several topics that require further assessment. First, more attention to Hg and its dynamics in CCR affected systems is warranted. Hg can be highly accumulative and toxic under some conditions and may interact with other components of CCR (notably Se), perhaps altering accumulation and effects of the contaminant mixtures. Second, further investigation of maternal transfer and effects of CCR contaminants need to be conducted. These studies could benefit from incorporation of quantitative models to project impacts on populations. Finally, more attention to the organic constituents of CCR (PAHs) is required, as a focus on inorganic compounds only may restrict our knowledge of contaminant dynamics and effects as a whole. While further studies will shed light on some chemical and biological nuances of exposure and effect, information available to date from numerous study sites implicates CCR as a bulk effluent that presents risks of bioaccumulation and effects on organisms

  6. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-10-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, progress was made in obtaining an industry partner for a long-term demonstration and in technology transfer activities. Engineering and equipment procurement activities related to the long-term demonstration were also completed.

  7. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Public design report (preliminary and final)

    SciTech Connect

    1996-07-01

    This Public Design Report presents the design criteria of a DOE Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of NO{sub x} emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 (500 MW) near Rome, Georgia. The technologies being demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NO{sub x} burner. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NO{sub x} burners, advanced overfire systems, and digital control system.

  8. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. Seventh quarterly technical progress report, March 1, 1992--May 31, 1992

    SciTech Connect

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Jiang, Chengliang; Raichur, A.M.

    1992-07-14

    The objective of this project is to conduct extensive studies on the surface reactivity and surface hydrophobicity of coal-pyrites using various surface characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The flotation characteristics of coal-pyrites under various conditions was studied and compared with ore-pyrite and coal to determine the causes of pyrite rejection difficulties in coal flotation. Both the native and induced floatabilities of pyrites were investigated. It was found that both coal- and ore-pyrites, ff prepared by dry-grinding, show little or no floatability in the absence of any chemical reagents. After ultrasonic pretreatment, ore-pyrite floats effectively in the acidic to neutral pH range. Kentucky No. 9 coal-pyrite (KYPY) shows significant flotation in the pH range 7--10. With ethyl xanthate as collector, ore-pyrite floats well up to pH = 10; while coal-pyrite reveals no flotation above pH = 6. For the first time, the effect of coal collector on the floatability of coal-pyrite has been studied. It was shown that in the presence of fuel oil--a widely used collector for promoting coal flotation, coal-pyrite, particularly for the fine sizes, shows good flotation below pH = 11, whereas ore-pyrite has no or little floatability. These studies demonstrate that one of the main causes of the coal-pyrite flotation in coal separation is the oil-induced floatability due to adsorption/attachment of oil droplets on the coal-pyrite surfaces, the ``native`` or ``self-induced`` floatability of pyrite is no as profound as the oil-induced flotation.

  9. Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a 500 MW Coal-Fired Power Station.

    PubMed

    Li, Kangkang; Yu, Hai; Feron, Paul; Tade, Moses; Wardhaugh, Leigh

    2015-08-18

    Using a rate-based model, we assessed the technical feasibility and energy performance of an advanced aqueous-ammonia-based postcombustion capture process integrated with a coal-fired power station. The capture process consists of three identical process trains in parallel, each containing a CO2 capture unit, an NH3 recycling unit, a water separation unit, and a CO2 compressor. A sensitivity study of important parameters, such as NH3 concentration, lean CO2 loading, and stripper pressure, was performed to minimize the energy consumption involved in the CO2 capture process. Process modifications of the rich-split process and the interheating process were investigated to further reduce the solvent regeneration energy. The integrated capture system was then evaluated in terms of the mass balance and the energy consumption of each unit. The results show that our advanced ammonia process is technically feasible and energy-competitive, with a low net power-plant efficiency penalty of 7.7%. PMID:26208135

  10. Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a 500 MW Coal-Fired Power Station.

    PubMed

    Li, Kangkang; Yu, Hai; Feron, Paul; Tade, Moses; Wardhaugh, Leigh

    2015-08-18

    Using a rate-based model, we assessed the technical feasibility and energy performance of an advanced aqueous-ammonia-based postcombustion capture process integrated with a coal-fired power station. The capture process consists of three identical process trains in parallel, each containing a CO2 capture unit, an NH3 recycling unit, a water separation unit, and a CO2 compressor. A sensitivity study of important parameters, such as NH3 concentration, lean CO2 loading, and stripper pressure, was performed to minimize the energy consumption involved in the CO2 capture process. Process modifications of the rich-split process and the interheating process were investigated to further reduce the solvent regeneration energy. The integrated capture system was then evaluated in terms of the mass balance and the energy consumption of each unit. The results show that our advanced ammonia process is technically feasible and energy-competitive, with a low net power-plant efficiency penalty of 7.7%.

  11. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report: First quarter 1993

    SciTech Connect

    Not Available

    1993-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, long-term testing of the LNB + AOFA configuration continued and no parametric testing was performed. Further full-load optimization of the LNB + AOFA system began on March 30, 1993. Following completion of this optimization, comprehensive testing in this configuration will be performed including diagnostic, performance, verification, long-term, and chemical emissions testing. These tests are scheduled to start in May 1993 and continue through August 1993. Preliminary engineering and procurement are progressing on the Advanced Low NOx Digital Controls scope addition to the wall-fired project. The primary activities during this quarter include (1) refinement of the input/output lists, (2) procurement of the distributed digital control system, (3) configuration training, and (4) revision of schedule to accommodate project approval cycle and change in unit outage dates.

  12. The Development of Power Technologies for Low-Grade Coal

    NASA Astrophysics Data System (ADS)

    Basu, K.

    Beneficiation of Indian coal and operation of power plants with imported coal will improve the efficiency of power generation to some extent but they will not satisfy overall future requirements of pollution control and conservation of energy. Therefore, there is a need to adopt new clean coal technologies.

  13. Managing urban biosolids: Beneficial uses

    SciTech Connect

    Forste, J.B.

    1998-07-01

    Biosolids (the primarily organic product produced by wastewater treatment processes that can be beneficially recycled) are becoming a significant challenge for operators of both small and large urban wastewater facilities. More stringent water quality standards, coupled with increasingly sensitive environmental and public health considerations, have made the treatment and use/disposal of solids from treatment processes a growing and complex field of environmental management.

  14. Beneficial Uses of Depleted Uranium

    SciTech Connect

    Brown, C.; Croff, A.G.; Haire, M. J.

    1997-08-01

    Naturally occurring uranium contains 0.71 wt% {sup 235}U. In order for the uranium to be useful in most fission reactors, it must be enriched the concentration of the fissile isotope {sup 235}U must be increased. Depleted uranium (DU) is a co-product of the processing of natural uranium to produce enriched uranium, and DU has a {sup 235}U concentration of less than 0.71 wt%. In the United States, essentially all of the DU inventory is in the chemical form of uranium hexafluoride (UF{sub 6}) and is stored in large cylinders above ground. If this co-product material were to be declared surplus, converted to a stable oxide form, and disposed, the costs are estimated to be several billion dollars. Only small amounts of DU have at this time been beneficially reused. The U.S. Department of Energy (DOE) has begun the Beneficial Uses of DU Project to identify large-scale uses of DU and encourage its reuse for the primary purpose of potentially reducing the cost and expediting the disposition of the DU inventory. This paper discusses the inventory of DU and its rate of increase; DU disposition options; beneficial use options; a preliminary cost analysis; and major technical, institutional, and regulatory issues to be resolved.

  15. LIBS Analysis for Coal

    NASA Astrophysics Data System (ADS)

    E. Romero, Carlos; De Saro, Robert

    Coal is a non-uniform material with large inherent variability in composition, and other important properties, such as calorific value and ash fusion temperature. This quality variability is very important when coal is used as fuel in steam generators, since it affects boiler operation and control, maintenance and availability, and the extent and treatment of environmental pollution associated with coal combustion. On-line/in situ monitoring of coal before is fed into a boiler is a necessity. A very few analytical techniques like X-ray fluorescence and prompt gamma neutron activation analysis are available commercially with enough speed and sophistication of data collection for continuous coal monitoring. However, there is still a need for a better on-line/in situ technique that has higher selectivity, sensitivity, accuracy and precision, and that is safer and has a lower installation and operating costs than the other options. Laser induced breakdown spectroscopy (LIBS) is ideal for coal monitoring in boiler applications as it need no sample preparation, it is accurate and precise it is fast, and it can detect all of the elements of concern to the coal-fired boiler industry. LIBS data can also be adapted with advanced data processing techniques to provide real-time information required by boiler operators nowadays. This chapter summarizes development of LIBS for on-line/in situ coal applications in utility boilers.

  16. Bench-scale Development of an Advanced Solid Sorbent-based CO2 Capture Process for Coal-fired Power Plants

    SciTech Connect

    Nelson, Thomas; Kataria, Atish; Soukri, Mustapha; Farmer, Justin; Mobley, Paul; Tanthana, Jak; Wang, Dongxiang; Wang, Xiaoxing; Song, Chunshan

    2015-12-31

    It is increasingly clear that CO2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO2 capture processes – such as RTI’s Advanced Solid Sorbent CO2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO2 capture. The overall objective

  17. Method of continuously producing compression molded coal

    SciTech Connect

    Yoshida, H.; Ishihara, N.; Kuwashima, S.

    1986-08-19

    This patent describes a method of producing a continuous cake of compression molded coal for chamber type coke ovens comprising steps of charging raw material coking coal into a molding box, and pressurizing the raw material coking coal with a pressing plate to obtain compression molded coal and to push the compression molded coal out of the molding box through an outlet. The improvement described here includes: the coking coal having a water content of more than 8.5% is charged into a chamber of the molding box at a side opposite the outlet, the pressing plate in the chamber is so advanced in the molding box to compression mold the coking coal into the preceding compression molded coal at a pressure no more than about 100 Kg/cm/sup 2/ so that the molded coal has a bulk density of at least 1.0 wet ton/m/sup 3/, and to push the molded coal in the molding box toward the outlet, the molded coal pressurized by the pressing plate partly remains in the molding box for supporting the coking coal freshly charged for the following cycle of the operation, and the freshly charged coal is pressed by the pressing plate so that the subsequent molded coal is combined with the preceding compression molded coal and the preceding molded coal is pushed out of the molding box whereby by repeating the serial steps of the operation, continuous cake of compression molded coal is produced.

  18. Flotation and flocculation chemistry of coal and oxidized coals

    SciTech Connect

    Somasundaran, P.

    1990-01-01

    The objective of this research project is to understand the fundamentals involved in the flotation and flocculation of coal and oxidized coals and elucidate mechanisms by which surface interactions between coal and various reagents enhance coal beneficiation. An understanding of the nature of the heterogeneity of coal surfaces arising from the intrinsic distribution of chemical moieties is fundamental to the elucidation of mechanism of coal surface modification and its role in interfacial processes such as flotation, flocculation and agglomeration. A new approach for determining the distribution in surface properties of coal particles was developed in this study and various techniques capable of providing such information were identified. Distributions in surface energy, contact angle and wettability were obtained using novel techniques such as centrifugal immersion and film flotation. Changes in these distributions upon oxidation and surface modifications were monitored and discussed. An approach to the modelling of coal surface site distributions based on thermodynamic information obtained from gas adsorption and immersion calorimetry is proposed. Polyacrylamide and dodecane was used to alter the coal surface. Methanol adsorption was also studied. 62 figs.

  19. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. Eighth quarterly technical progress report, June 1, 1992--August 31, 1992

    SciTech Connect

    Wang, X.H.; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Jiang, C.L.

    1992-12-01

    The objective of the project is to conduct extensive fundamental studies on the surface reactivity and surface hydrophobicity of coal-pyrites using various surface characterization techniques and to understand how the alteration of the coal-pyrite surface affects the efficiency of pyrite rejection in coal flotation. During this reporting period, the influence of the impurity content, particularly coal/carbon content, on the electrochemical oxidation of pyrite surfaces was investigated. The studies demonstrate that the coal/carbon content in coal-pyrite has a determining effect on the surface reactivity of pyrite. The oxidation behavior of high carbon-content coal-pyrite is completely different from that of purer coal-pyrite and ore-pyrite. The effects of flotation gases on the flotation behavior of coal and the surface hydrophobicity of various coal-pyrite were investigated. It was found from the lab-scale column flotation studies that among the various gases studied (air, oxygen, argon, nitrogen and carbon dioxide), carbon dioxide produced the best results with a combustible recovery of 90% and ash-content of less than 9 percent. Finally, the surface energetic studies revealed that the surfaces of pyrites and coals produced by wet grinding is more heterogenous than that prepared by dry grinding.

  20. Coal: the cornerstone of America's energy future

    SciTech Connect

    Beck, R.A.

    2006-06-15

    In April 2005, US Secretary of Energy Samuel W. Bodman asked the National Coal Council to develop a 'report identifying the challenges and opportunities of more fully exploring our domestic coal resources to meet the nation's future energy needs'. The Council has responded with eight specific recommendations for developing and implementing advanced coal processing and combustion technologies to satisfy our unquenchable thirst for energy. These are: Use coal-to-liquids technologies to produce 2.6 million barrels/day; Use coal-to-natural gas technologies to produce 4 trillion ft{sup 3}/yr; Build 100 GW of clean coal plants by 2025; Produce ethanol from coal; Develop coal-to-hydrogen technologies; Use CO{sub 2} to enhance recovery of oil and coal-bed methane; Increase the capacity of US coal mines and railroads; and Invest in technology development and implementation. 1 ref.; 4 figs.; 1 tab.

  1. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-05-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the fourth reporting quarter, laboratory-screening tests of more than 20 potential additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of flyash cohesivity. Resistivity was measured for each screening test with a new multi-cell laboratory flyash resistivity furnace constructed for this project. An initial field trial of three additive formulations was also conducted at the City of Ames, Iowa Municipal Power Plant.

  2. Evaluation of advanced combustion concepts for dry NO sub x suppression with coal-derived, gaseous fuels

    NASA Astrophysics Data System (ADS)

    Beebe, K. W.; Symonds, R. A.; Notardonato, J. J.

    The emissions performance of a rich lean combustor (developed for liquid fuels) was determined for combustion of simulated coal gases ranging in heating value from 167 to 244 Btu/scf (7.0 to 10.3 MJ/NCM). The 244 Btu/scf gas is typical of the product gas from an oxygen blown gasifier, while the 167 Btu/scf gas is similar to that from an air blown gasifier. NOx performance of the rich lean combustor did not meet program goals with the 244 Btu/scf gas because of high thermal NOx, similar to levels expected from conventional lean burning combustors. The NOx emissions are attributed to inadequate fuel air mixing in the rich stage resulting from the design of the large central fuel nozzle delivering 71% of the total gas flow. NOx yield from ammonia injected into the fuel gas decreased rapidly with increasing ammonia level, and is projected to be less than 10% at NH3 levels of 0.5% or higher. NOx generation from NH3 is significant at ammonia concentrations significantly less than 0.5%. These levels may occur depending on fuel gas cleanup system design. CO emissions, combustion efficiency, smoke and other operational performance parameters were satisfactory. A test was completed with a catalytic combustor concept with petroleum distillate fuel. Reactor stage NOx emissions were low (1.4g NOx/kg fuel). CO emissions and combustion efficiency were satisfactory. Airflow split instabilities occurred which eventually led to test termination.

  3. Evaluation of advanced combustion concepts for dry NO sub x suppression with coal-derived, gaseous fuels

    NASA Technical Reports Server (NTRS)

    Beebe, K. W.; Symonds, R. A.; Notardonato, J. J.

    1982-01-01

    The emissions performance of a rich lean combustor (developed for liquid fuels) was determined for combustion of simulated coal gases ranging in heating value from 167 to 244 Btu/scf (7.0 to 10.3 MJ/NCM). The 244 Btu/scf gas is typical of the product gas from an oxygen blown gasifier, while the 167 Btu/scf gas is similar to that from an air blown gasifier. NOx performance of the rich lean combustor did not meet program goals with the 244 Btu/scf gas because of high thermal NOx, similar to levels expected from conventional lean burning combustors. The NOx emissions are attributed to inadequate fuel air mixing in the rich stage resulting from the design of the large central fuel nozzle delivering 71% of the total gas flow. NOx yield from ammonia injected into the fuel gas decreased rapidly with increasing ammonia level, and is projected to be less than 10% at NH3 levels of 0.5% or higher. NOx generation from NH3 is significant at ammonia concentrations significantly less than 0.5%. These levels may occur depending on fuel gas cleanup system design. CO emissions, combustion efficiency, smoke and other operational performance parameters were satisfactory. A test was completed with a catalytic combustor concept with petroleum distillate fuel. Reactor stage NOx emissions were low (1.4g NOx/kg fuel). CO emissions and combustion efficiency were satisfactory. Airflow split instabilities occurred which eventually led to test termination.

  4. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-09-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  5. Development of advanced NO{sub x} control concepts for coal-fired utility boilers. Final report

    SciTech Connect

    Evans, A.; Pont, J.; England, G.

    1993-09-01

    Control of emissions of nitrogen oxides (NO{sub x}) from fossil-fuel fired combustion systems has become increasingly important over the past twenty years due to their role in the formation of acid rain and photochemical oxidant or smog. High levels of NO{sub x} from coal-fired utility boilers are typically only achievable with expensive post-combustion technologies employing catalyst beds. Energy and Environmental Research has developed a hybrid technology capable of achieving high levels of NO{sub x}, reduction at costs significantly below those of catalytic technologies. This process has been named CombiNO{sub x}. The CombiNO{sub x} process consists of three NO{sub x} control technologies-reburning, Selective Non-Catalytic Reduction (SNCR), and NO{sub 2} Scrubbing-which have been integrated and optimized in a manner which takes advantage of the chemical reactions involved in each process to achieve overall NO{sub x} reductions greater than 90 percent. The specific goal is to demonstrate 70 percent NO{sub x} reduction at 20 percent of the cost of Selective Catalytic Reduction (SCR). A secondary goal was to achieve stack emissions comparable to those downstream of an SCR system at 50 percent of the cost of SCR. In addition, sufficient process information was to be gathered to minimize the risk associated with a full-scale demonstration.

  6. Advanced turbine design for coal-fueled engines. Phase 1, Erosion of turbine hot gas path blading: Final report

    SciTech Connect

    Wagner, J.H.; Johnson, B.V.

    1993-04-01

    The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

  7. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers

    SciTech Connect

    Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1996-05-01

    Research is presently being initiated to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituents` size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. During the last quarter, model Ni-Al{sub 2}O{sub 3} powder cermet composites were produced at Idaho National Engineering Laboratory by the Hot Isostatic Pressing (HIP) technique. The composite samples contained 0, 21, 27, 37, and 45 volume percent of Al{sub 2}O{sub 2} in a nickel matrix with an average size of alumina particles of 12 micrometers. The increase in volume fraction of alumina in the nickel matrix from 0 to 45% led to an increase in hardness of these composites from 85 to 180 HV{sub 1000}. The experimental procedure and preliminary microstructural characterization of Ni-Al{sub 2}O{sub 3} composites are presented in this progress report along with plans for the research in coming year. 3 figs.

  8. Electrostatic Beneficiation of Lunar Simulant

    NASA Technical Reports Server (NTRS)

    Trigwell, Steve; Captain, James; Captain, Janine; Arens, Ellen; Quinn, Jacqueline; Calle, Carlos

    2006-01-01

    Electrostatic beneficiation of lunar regolith is a method allowing refinement of specific minerals in the material for processing on the moon. The use of tribocharging the regolith prior to separation was investigated on the lunar simulant MLS-I by passing the dust through static mixers constructed from different materials; aluminum, copper, stainless steel, and polytetrafluoroethylene (PTFE). The amount of charge acquired by the simulant was dependent upon the difference in the work function of the dust and the charging material. XPS and SEM were used to characterize the simulant after it was sieved into five size fractions (> 100 pm, 75-100 pm, 50- 75 pm, 50-25 pm, and < 25 pm), where very little difference in surface composition was observed between the sizes. Samples of the smallest (< 25 pm) and largest (> 100 pm) size fractions were beneficiated through a charge separator using the aluminum (charged the simulant negatively) and PTFE (charged positively) mixers. The mass fractions of the separated simulant revealed that for the larger particle size, significant unipolar charging was observed for both mixers, whereas for the smaller particle sizes, more bipolar charging was observed, probably due to the finer simulant adhering to the inside of the mixers shielding the dust from the charging material. Subsequent XPS analysis of the beneficiated fractions showed the larger particle size fraction having some species differentiation, but very little difference for the smaller.size. Although MLS-1 was made to have similar chemistry to actual lunar dust, its mineralogy is quite different. On-going experiments are using NASA JSC-1 lunar simulant. A vacuum chamber has been constructed, and future experiments are planned in a simulated lunar environment.

  9. Conditioning of carbonaceous material prior to physical beneficiation

    DOEpatents

    Warzinski, Robert P.; Ruether, John A.

    1987-01-01

    A carbonaceous material such as coal is conditioned by contact with a supercritical fluid prior to physical beneficiation. The solid feed material is contacted with an organic supercritical fluid such as cyclohexane or methanol at temperatures slightly above the critical temperature and pressures of 1 to 4 times the critical pressure. A minor solute fraction is extracted into critical phase and separated from the solid residuum. The residuum is then processed by physical separation such as by froth flotation or specific gravity separation to recover a substantial fraction thereof with reduced ash content. The solute in supercritical phase can be released by pressure reduction and recombined with the low-ash, carbonaceous material.

  10. Advanced turbine design for coal-fueled engines. Phase 2, Corrosion of turbine hot gas path blading: Final report, December 1988--February 1993

    SciTech Connect

    Bornstein, N.

    1993-06-01

    The environment within the advanced industrial gas turbine is highly oxidizing and contains the compounds, salts and oxides that accelerate the rate of oxidation of structural materials. Protective coatings which differ from each other and the superalloys in composition and phase morphology, enhance the oxidation and corrosion resistance of the superalloys. As temperatures increase, the relativity stability and long term effectiveness of the coatings is of concern. The interdiffusion of coating and alloy constituents can affect chemical and mechanical properties. Long term studies are appropriate. Thermal barrier coatings, introduced at the inception of the current program will further improve the thermal efficiency of industrial gas turbine engines. The interaction between state-of-the-art thermal barrier coatings (TBC) and oxidation and corrosion in the coal fired environment is of concern and should be critically examined. The superior performance of the overlay coating is related to thickness rather than chemistry. With respect to sodium sulfate corrosion, the life of the overlay coating is 2.7 times longer than that of the platinum aluminide which in turn is 2.2 times longer than that of the simple aluminide. The ranking of the coatings is unchanged with respect to eutectic soft corrosion, however the salt is more aggressive. The life of the overlay coating is 1.4 times longer than that of the platinum aluminide which is 1.9 times longer than that of the simple aluminide.

  11. The feasibility of using combined TiO2 photocatalysis oxidation and MBBR process for advanced treatment of biologically pretreated coal gasification wastewater.

    PubMed

    Xu, Peng; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng; Jia, Shengyong; Wang, Dexin; Li, Kun; Zhao, Qian

    2015-01-01

    The study examined the feasibility of using combined heterogeneous photocatalysis oxidation (HPO) and moving bed biofilm reactor (MBBR) process for advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that the TOC removal efficiency was significantly improved in HPO. Gas chromatography-mass spectrometry (GC-MS) analysis indicated that the HPO could be employed to eliminate bio-refractory and toxic compounds. Meanwhile, the BOD5/COD of the raw wastewater was increased from 0.08 to 0.49. Furthermore, in the integration of TiO2 photocatalysis oxidation and MBBR process, the effluent of COD, BOD5, TOC, NH4(+)-N and TN were 22.1 mg/L, 1.1 mg/L, 11.8 mg/L, 4.1mg/L and 13.7 mg/L, respectively, which all met class-I criteria of the Integrated Wastewater Discharge Standard (GB18918-2002, China). The total operating cost was 2.8CNY/t. Therefore, there is great potential for the combined system in engineering applications as a final treatment for biologically pretreated CGW.

  12. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, November 1994--February 1995

    SciTech Connect

    1995-03-01

    This second quarterly report describes work during the second three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSI) and the Center for Hazardous Materials Research (CHMR). The report describes the activities of the project team during the reporting period. The principal work has focussed upon the acquisition of by-product samples and their initial analysis. Other efforts during the second quarter have been directed toward identifying the first hazardous waste samples and preparing for their treatment and analysis. Relatively little data has yet been collected. Major presentation of technical details and data will appear for the first time in the third quarterly report. The activity on the project during the second quarter of Phase One, as presented in the following sections, has fallen into seven areas: (1) Acquiring by-products, (2) Analyzing by-products, (3) Identifying, analyzing and treating suitable hazardous wastes, (4) Carrying out the quality assurance/quality control program, (5) Developing background, and (6) Initiating public relations

  13. Development of advanced NO{sub x} control concepts for coal-fired utility boilers. Quarterly technical progress report No. 4, July 1, 1991--September 30, 1991

    SciTech Connect

    Evans, A.; Newhall, J.; England, G.; Seeker, W.R.

    1992-06-23

    CombiNO{sub x} is a NO{sub x} reduction process which incorporates three different NO{sub x} control technologies: reburning, selective non-catalytic reduction (SNCR), and methanol injection. Gas reburning is a widely used technology that has been proven to reduce NO{sub x} up to 60% on full-scale applications. The specific goals of the CombiNO{sub x} project are: 70% NO{sub x} reduction at 20% of the cost of selective catalytic reduction; NO{sub x} levels at the stack of 60 ppm for ozone non-attainment areas; Demonstrate coal reburning; Identify all undesirable by-products of the process and their controlling parameters; Demonstrate 95% N0{sub 2} removal in a wet scrubber. Before integrating all three of CombiNO{sub x}`s technologies into a combined process, it is imperative that the chemistry of each individual process is well understood. Pilot-scale SNCR tests and the corresponding computer modeling were studied in detail and discussed in the previous quarterly report. This quarterly report will present the results obtained during the pilot-scale advanced reburning tests performed on EER`s Boiler Simulation Facility (BSF). Since methanol injection is a relatively new NO{sub x} control technology, laboratory-scale tests were performed to better understand the conditions at which methanol is most effective. The experimental set-up and results from these tests will be discussed.

  14. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, May 1995--August 1995

    SciTech Connect

    1995-11-01

    This fourth quarterly report describes work done during the fourth three-month period of the University of Pittsburgh`s project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quote} Participating with the university on this project are Dravo Lime Company, Mill Service, Inc., and the Center for Hazardous Materials Research. This report describes the activities of the project team during the reporting period. The principal work has focussed upon the production of six sets of samples with high water content for solidification testing and the mixing of five dry samples for solidification testing by the Proctor method. Twenty-eight day compressive strengths are reported for five of the six sets of samples with high water content. The report also discusses completion of the format of the database and the inclusion in it of all data collected to date. Special reports presented during the quarter include the Continuation Application, a News Release, and modification to the Test Plan. Work is progressing on the NEPA report and the Topical Report. The activity on the project during the fourth quarter of Phase one, as presented in the following sections, has fallen into six major areas: (1) Completion of by-product evaluations, (2) Completion of analyses of six wastes, (3) Initiation of eleven solidification tests, (4) Continued extraction and extract analysis of solidified samples, (5) Development of the database, and (6) Production of reports.

  15. A novel integration of three-dimensional electro-Fenton and biological activated carbon and its application in the advanced treatment of biologically pretreated Lurgi coal gasification wastewater.

    PubMed

    Hou, Baolin; Han, Hongjun; Zhuang, Haifeng; Xu, Peng; Jia, Shengyong; Li, Kun

    2015-11-01

    A novel integrated process with three-dimensional electro-Fenton (3D EF) and biological activated carbon (BAC) was employed in advanced treatment of biologically pretreated Lurgi coal gasification wastewater. SAC-Fe (sludge deserved activated carbon from sewage and iron sludge) and SAC (sludge deserved activated carbon) were used in 3D EF as catalytic particle electrodes (CPEs) and in BAC as carriers respectively. Results indicated that 3D EF with SAC-Fe as CPEs represented excellent pollutants and COLOR removals as well as biodegradability improvement. The efficiency enhancement attributed to generating more H2O2 and OH. The integrated process exhibited efficient performance of COD, BOD5, total phenols, TOC, TN and COLOR removals at a much shorter retention time, with the corresponding concentrations in effluent of 31.18, 6.69, 4.29, 17.82, 13.88mg/L and <20 times, allowing discharge criteria to be met. The integrated system was efficient, cost-effective and ecological sustainable and could be a promising technology for engineering applications.

  16. Application of Pulsed Electrical Fields for Advanced Cooling and Water Recovery in Coal-Fired Power Plant

    SciTech Connect

    Young Cho; Alexander Fridman

    2009-04-02

    The overall objective of the present work was to develop technologies to reduce freshwater consumption in a cooling tower of coal-based power plant so that one could significantly reduce the need of make-up water. The specific goal was to develop a scale prevention technology based an integrated system of physical water treatment (PWT) and a novel filtration method so that one could reduce the need for the water blowdown, which accounts approximately 30% of water loss in a cooling tower. The present study investigated if a pulsed spark discharge in water could be used to remove deposits from the filter membrane. The test setup included a circulating water loop and a pulsed power system. The present experiments used artificially hardened water with hardness of 1,000 mg/L of CaCO{sub 3} made from a mixture of calcium chloride (CaCl{sub 2}) and sodium carbonate (Na{sub 2}CO{sub 3}) in order to produce calcium carbonate deposits on the filter membrane. Spark discharge in water was found to produce strong shockwaves in water, and the efficiency of the spark discharge in cleaning filter surface was evaluated by measuring the pressure drop across the filter over time. Results showed that the pressure drop could be reduced to the value corresponding to the initial clean state and after that the filter could be maintained at the initial state almost indefinitely, confirming the validity of the present concept of pulsed spark discharge in water to clean dirty filter. The present study also investigated the effect of a plasma-assisted self-cleaning filter on the performance of physical water treatment (PWT) solenoid coil for the mitigation of mineral fouling in a concentric counterflow heat exchanger. The self-cleaning filter utilized shockwaves produced by pulse-spark discharges in water to continuously remove scale deposits from the surface of the filter, thus keeping the pressure drop across the filter at a relatively low value. Artificial hard water was used in the

  17. Wastewater privatization: A beneficial alternative

    SciTech Connect

    Wakeman, R.F.; Drewry, W.A.

    1999-07-01

    Municipalities with wastewater operations face increasing requirements to maximize efficiency, implement capital improvements, and ensure environmental compliance. Privatization is a relatively unused alternative offering benefits in the areas of cost-effective operations, flexible financing, technology access, and compliance assurance. Recent executive direction and tax code changes have opened new doors for mutually beneficial public-private partnerships. Wastewater privatization has historically consisted of short-term contract agreements for treatment operations, but looming infrastructure recapitalization and development requirements have catalyzed an exploration of non-traditional alternatives that include private sector financing, development, and operation of entire wastewater systems, The purpose of this paper is to show why privatization must be considered, evaluate the different levels available, and generate an analytical aid for communities taking their first look at privatization opportunities.

  18. Biosolubilization of coal by Candida in glucose limited cultures

    SciTech Connect

    Mitter, J.; Guillory, L.; Bose, N.K.; Misra, A. )

    1990-01-01

    Coal biodegradation is attracting the attention of many workers because of its significance for efficient bioconversion of coal into useful chemicals. The authors work is based upon the beneficiation of a fungus (candida) on subbituminous coal. Candida was grown on both solid and liquid sabouraud medium and the coal solubilizing activity was studied at varying glucose concentration and temperature. Lower glucose concentration and higher temperature enhanced coal solubilizing activity by this fungus. Preliminary work has begun on analyzing organic extractions (alumina chromatography) of the liquid produced after microbial solubilization, including elemental analysis, solubility, molecular weights and chemical structure. This preliminary work suggests that the candida could metabolize naturally occurring coal as substrate.

  19. Coal pump

    DOEpatents

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  20. 7 CFR 1434.6 - Beneficial interest.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ..., title and control of the honey and beneficial interest in the honey, as specified in 7 CFR 1434.6, must... REGULATIONS FOR HONEY § 1434.6 Beneficial interest. (a) To be eligible to receive marketing assistance loans under this part a producer must have the beneficial interest in the honey that is tendered to CCC for...