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Sample records for advanced coal process

  1. Assessment of advanced coal gasification processes

    NASA Technical Reports Server (NTRS)

    Mccarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-01-01

    A technical assessment of the following advanced coal gasification processes is presented: high throughput gasification (HTG) process; single stage high mass flux (HMF) processes; (CS/R) hydrogasification process; and the catalytic coal gasification (CCG) process. Each process is evaluated for its potential to produce synthetic natural gas from a bituminous coal. Key similarities, differences, strengths, weaknesses, and potential improvements to each process are identified. The HTG and the HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging, and syngas as the initial raw product gas. The CS/R hydrogasifier is also SRT, but is nonslagging and produces a raw gas high in methane content. The CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier.

  2. Assessment of Advanced Coal Gasification Processes

    NASA Technical Reports Server (NTRS)

    McCarthy, John; Ferrall, Joseph; Charng, Thomas; Houseman, John

    1981-01-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process; Bell Single-Stage High Mass Flux (HMF) Process; Cities Service/Rockwell (CS/R) Hydrogasification Process; Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier. The report makes the following assessments: 1) while each process has significant potential as coal gasifiers, the CS/R and Exxon processes are better suited for SNG production; 2) the Exxon process is the closest to a commercial level for near-term SNG production; and 3) the SRT processes require significant development including scale-up and turndown demonstration, char processing and/or utilization demonstration, and reactor control and safety features development.

  3. Advanced Coal Conversion Process Demonstration Project

    SciTech Connect

    Not Available

    1992-04-01

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  4. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect

    B. K. Parekh; D. P. Patil

    2008-04-30

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake

  5. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    SciTech Connect

    Edwin S. Olson; Charles J. Moretti

    1999-11-01

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require

  6. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1990-01-01

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This technology is important to reduce the technical and economic risks inherent in utilizing coal, a feedstock whose variable and often unexpected behavior presents a significant challenge. This program will merge significant advances made at Advanced Fuel Research, Inc. (AFR) in measuring and quantitatively describing the mechanisms in coal conversion behavior, with technology being developed at Brigham Young University (BYU) in comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors. The foundation to describe coal-specific conversion behavior is AFR's Functional Group (FG) and Devolatilization, Vaporization, and Crosslinking (DVC) models, developed under previous and on-going METC sponsored programs. These models have demonstrated the capability to describe the time dependent evolution of individual gas species, and the amount and characteristics of tar and char. The combined FG-DVC model will be integrated with BYU's comprehensive two-dimensional reactor model, PCGC-2, which is currently the most widely used reactor simulation for combustion or gasification. Success in this program will be a major step in improving in predictive capabilities for coal conversion processes including: demonstrated accuracy and reliability and a generalized first principles'' treatment of coals based on readily obtained composition data. The progress during the fifteenth quarterly of the program is presented. 56 refs., 41 figs., 5 tabs.

  7. Advanced hot gas cleaning system for coal gasification processes

    NASA Astrophysics Data System (ADS)

    Newby, R. A.; Bannister, R. L.

    1994-04-01

    The United States electric industry is entering a period where growth and the aging of existing plants will mandate a decision on whether to repower, add capacity, or do both. The power generation cycle of choice, today, is the combined cycle that utilizes the Brayton and Rankine cycles. The combustion turbine in a combined cycle can be used in a repowering mode or in a greenfield plant installation. Today's fuel of choice for new combined cycle power generation is natural gas. However, due to a 300-year supply of coal within the United States, the fuel of the future will include coal. Westinghouse has supported the development of coal-fueled gas turbine technology over the past thirty years. Working with the U.S. Department of Energy and other organizations, Westinghouse is actively pursuing the development and commercialization of several coal-fueled processes. To protect the combustion turbine and environment from emissions generated during coal conversion (gasification/combustion) a gas cleanup system must be used. This paper reports on the status of fuel gas cleaning technology and describes the Westinghouse approach to developing an advanced hot gas cleaning system that contains component systems that remove particulate, sulfur, and alkali vapors. The basic process uses ceramic barrier filters for multiple cleaning functions.

  8. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1992-01-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO[sub x]-NO[sub x] submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  9. Advanced Coal Conversion Process Demonstration Project. Environmental Monitoring Plan

    SciTech Connect

    Not Available

    1992-04-01

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  10. Measurement and modeling of advanced coal conversion processes

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  11. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1993--December 31, 1993

    SciTech Connect

    1995-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through December 31, 1993. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low- rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  12. Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    1996-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  13. Measurement and modeling of advanced coal conversion processes, Volume III

    SciTech Connect

    Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G.

    1993-08-01

    A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

  14. Geotechnical/geochemical characterization of advanced coal process waste streams: Task 2

    SciTech Connect

    Moretti, C.J.; Olson, E.S.

    1992-09-01

    Successful disposal practices for solid wastes produced from advanced coal combustion and coal conversion processes must provide for efficient management of relatively large volumes of wastes in a cost-effective and environmentally safe manner. At present, most coal-utilization solid wastes are disposed of using various types of land-based systems, and it is probable that this disposal mode will continue to be widely used in the future for advanced process wastes. Proper design and operation of land-based disposal systems for coal combustion wastes normally require appropriate waste transfer, storage, and conditioning subsystems at the plant to prepare the waste for transport to an ultimate disposal site. Further, the overall waste management plan should include a by-product marketing program to minimize the amount of waste that will require disposal. In order to properly design and operate waste management systems for advanced coal-utilization processes, a fundamental understanding of the physical properties, chemical and mineral compositions, and leaching behaviors of the wastes is required. In order to gain information about the wastes produced by advanced coal-utilization processes, 55 waste samples from 16 different coal gasification, fluidized-bed coal combustion (FBC), and advanced flue gas scrubbing processes were collected. Thirty-four of these wastes were analyzed for their bulk chemical and mineral compositions and tested for a detailed set of disposal-related physical properties. The results of these waste characterizations are presented in this report. In addition to the waste characterization data, this report contains a discussion of potentially useful waste management practices for advanced coal utilization processes.

  15. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    SciTech Connect

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  16. [Advanced Coal Conversion Process Demonstration Project]. Technical progress report: April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1993-10-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from April 1, 1992, through June 30, 1992. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques designed to upgrade high-moisture, low-rank coals into a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/Ib), by producing a stable, upgraded coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size.

  17. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    1996-06-01

    This detailed report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project. This U.S. Department of Energy (DOE) Clean Coal Technology Project demonstrates an advanced thermal coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to high-quality, low-sulfur fuel. During this reporting period, the primary focus for the project was to expand market awareness and acceptability for the products and the technology. The use of covered hopper cars has been successful and marketing efforts have focused on this technique. Operational improvements are currently aimed at developing fines marketing systems, increasing throughput capacity, decreasing operation costs, and developing standardized continuous operator training. Testburns at industrial user sites were also conducted. A detailed process description; technical progress report including facility operations/plant production, facility testing, product testing, and testburn product; and process stability report are included. 3 figs., 8 tabs.

  18. Hydromechanical Advanced Coal Excavator

    NASA Technical Reports Server (NTRS)

    Estus, Jay M.; Summers, David

    1990-01-01

    Water-jet cutting reduces coal dust and its hazards. Advanced mining system utilizes full-face, hydromechanical, continuous miner. Coal excavator uses high-pressure water-jet lances, one in each of cutting heads and one in movable lance, to make cuts across top, bottom and middle height, respectively, of coal face. Wedge-shaped cutting heads advance into lower and upper cuts in turn, thereby breaking coal toward middle cut. Thrust cylinders and walking pads advance excavator toward coal face.

  19. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  20. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    SciTech Connect

    Speight, J.G.

    1992-01-01

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  1. Measurement and modeling of advanced coal conversion processes, Volume II

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1993-06-01

    A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

  2. Advanced coal conversion process demonstration. Technical progress report, April 1--June 30, 1996

    SciTech Connect

    1997-10-01

    This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high moisture, low rank coals to a high quality, low sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep bed stratifier cleaning process to separate the pyrite rich ash from the coal. The SynCoal process enhances low rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 Btu/lb, by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45 ton per hour unit is located adjacent to a unit train load out facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. During this report period the primary focus has been to continue the operation of the demonstration facility. Production has been going to area power plants. Modifications and maintenance work was also performed this quarter.

  3. Carbon formation and metal dusting in advanced coal gasification processes

    SciTech Connect

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  4. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    SciTech Connect

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V.

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  5. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research

    SciTech Connect

    Not Available

    1992-01-01

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  6. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    SciTech Connect

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  7. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  8. Frothing in flotation. Volume 2: Recent advances in coal processing

    SciTech Connect

    Laskowski, J.S.; Woodburn, E.T.

    1998-11-01

    This volume summarizes the achievements on various aspects of flotation froth properties and behavior, and relationship between froth appearance and flotation performance. Flotation kinetics involves a number of mass transfer processes with some of them being critically determined by the behavior of froth. Since froth is complex, and controlled experimentation is difficult, the froth phase was, until recently, either ignored or treated entirely empirically. With wide applications of flotation columns, the behavior of the froth is now often recognized as being dominant in determining flotation performance, and the research in this area is one of the most actively pursued. Contents include: Frothers and frothing; Effect of particle and bubble size on flotation kinetics; Water content and distribution in flotation froths; Mechanisms operating in flotation froths; Characterization of flotation froth; Simultaneous determination of collection zone rate constant and froth zone recovery factor; Modelling of froth dynamics with implications for feed-back control; The interrelationship between flotation variables and froth appearance; Froth image analysis in a flotation control system; Kinetic flotation modelling using froth imaging data; and Dependence of froth behavior on galvanic interactions.

  9. Field study of disposed wastes from advanced coal process. Quarterly technical progress report, May 1986--July 1986

    SciTech Connect

    1995-11-01

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Mining and Minerals Resources Research Institute (MMRRI) to monitor a limited number of field disposal tests with select advanced coal process wastes. These field tests will be monitored over a three year period to collect data on the field disposal behavior of these wastes. There has been considerable research on the characteristics and laboratory leaching behavior of coal wastes -- a lesser amount on wastes from advanced coal processes. However, very little information exists on the field disposal behavior of these wastes. Information on field disposal behavior is needed (1) as input to predictive models being developed, (2) as input to the development of rule of thumb design guidelines for the disposal of these wastes, and (3) as evidence of the behavior of these wastes in the natural environment.

  10. Coal surface control for advanced physical fine coal cleaning technologies

    SciTech Connect

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  11. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, May--July 1989

    SciTech Connect

    1989-12-31

    The Department of Energy/Morgantown Energy Technology Center (DOE/METC) has initiated research on the disposal of solid wastes from advanced coal processes. The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Mineral Research Center (EMRC) to design, construct and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. The specific objectives for the reporting period were as follows: review fourth site candidates; obtain site access for the Freeman United site; select an ash supplier for the Illinois site and initiate subcontracts for on-site work; commence construction of the Freeman United test cell; and obtain waste for the Colorado Ute test site. Accomplishments under each task are discussed.

  12. TRW advanced slagging coal combustor utility demonstration

    SciTech Connect

    Not Available

    1990-01-01

    The TRW Advanced Entrained Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/oil unit to fire 2.5% sulfur coal. The slagging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Environmental Standards. The TRW-Utility Demonstration Unit (UDU) is responsible for the implementation of program policies and overall direction of the project. The following projects will be carried out: process and design development of clean coal technology CCT-1 the development and operation of the entrained coal combustor will enable the boiler to burn low and medium sulfur coal while meeting all the Federal/State emission requirements; demonstrate sulfur dioxide emissions control by pulverized limestone injection into the entrained coal combustor system.

  13. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  14. Measurement and modeling of advanced coal conversion processes. Twenty-second quarterly report, January 2, 1992--March 31, 1992

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1992-12-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO{sub x}-NO{sub x} submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  15. Continuous coal processing method

    NASA Technical Reports Server (NTRS)

    Ryason, P. R. (Inventor)

    1980-01-01

    A coal pump is provided in which solid coal is heated in the barrel of an extruder under pressure to a temperature at which the coal assumes plastic properties. The coal is continuously extruded, without static zones, using, for example, screw extrusion preferably without venting through a reduced diameter die to form a dispersed spray. As a result, the dispersed coal may be continuously injected into vessels or combustors at any pressure up to the maximum pressure developed in the extrusion device. The coal may be premixed with other materials such as desulfurization aids or reducible metal ores so that reactions occur, during or after conversion to its plastic state. Alternatively, the coal may be processed and caused to react after extrusion, through the die, with, for example, liquid oxidizers, whereby a coal reactor is provided.

  16. Brazing as a Means of Sealing Ceramic Membranes for use in Advanced Coal Gasification Processes

    SciTech Connect

    Weil, K. Scott; Hardy, John S.; Rice, Joseph P.; Kim, Jin Yong Y.

    2006-01-02

    Coal is potentially a very inexpensive source of clean hydrogen fuel for use in fuel cells, turbines, and various process applications. To realize its potential however, efficient, low-cost gas separation systems are needed to provide high purity oxygen to enhance the coal gasification reaction and to extract hydrogen from the resulting gas product stream. Several types of inorganic membranes are being developed for hydrogen or oxygen separation, including porous alumina, transition metal oxide perovskites, and zirconia. One of the key challenges in developing solid-state membrane based gas separation systems is in hermetically joining the membrane to the metallic body of the separation device. In an effort to begin addressing this issue, a new brazing concept has been developed, referred to as reactive air brazing. This paper discusses the details of this joining technique and illustrates its use in bonding a wide variety of materials, including alumina, lanthanum strontium cobalt ferrite, and yttria stabilized zirconia.

  17. Coal liquefaction quenching process

    DOEpatents

    Thorogood, Robert M.; Yeh, Chung-Liang; Donath, Ernest E.

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  18. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous catalytic ozonation and biological process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Hou, Baolin; Zhao, Qian

    2014-08-01

    Advanced treatment of biologically pretreated coal gasification wastewater (CGW) was investigated employing heterogeneous catalytic ozonation integrated with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process. The results indicated that catalytic ozonation with the prepared catalyst (i.e. MnOx/SBAC, sewage sludge was converted into sludge based activated carbon (SBAC) which loaded manganese oxides) significantly enhanced performance of pollutants removal by generated hydroxyl radicals. The effluent of catalytic ozonation process was more biodegradable and less toxic than that in ozonation alone. Meanwhile, ANMBBR-BAF showed efficient capacity of pollutants removal in treatment of the effluent of catalytic ozonation at a shorter reaction time, allowing the discharge limits to be met. Therefore, the integrated process with efficient, economical and sustainable advantages was suitable for advanced treatment of real biologically pretreated CGW.

  19. New cleaning technologies advance coal

    SciTech Connect

    Onursal, B.

    1984-05-01

    Alternative options are discussed for reducing sulfur dioxide emissions from coal burning utility and industrial sources. Test results indicate that it may be most advantageous to use the AED Process after coal preparation or on coals that do not need much ash removal. However, the developer claims that research efforts after 1981 have led to process improvements for producing clean coals containing 1.5% to 3% ash. This paper describes the test facility where a full-scale test of the AED Process is underway.

  20. Integrated coal liquefaction process

    DOEpatents

    Effron, Edward

    1978-01-01

    In a process for the liquefaction of coal in which coal liquids containing phenols and other oxygenated compounds are produced during the liquefaction step and later hydrogenated, oxygenated compounds are removed from at least part of the coal liquids in the naphtha and gas oil boiling range prior to the hydrogenation step and employed as a feed stream for the manufacture of a synthesis gas or for other purposes.

  1. Advanced Coal-Based Power Generations

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1982-01-01

    Advanced power-generation systems using coal-derived fuels are evaluated in two-volume report. Report considers fuel cells, combined gas- and steam-turbine cycles, and magnetohydrodynamic (MHD) energy conversion. Presents technological status of each type of system and analyzes performance of each operating on medium-Btu fuel gas, either delivered via pipeline to powerplant or generated by coal-gasification process at plantsite.

  2. Coal liquefaction process

    DOEpatents

    Carr, Norman L.; Moon, William G.; Prudich, Michael E.

    1983-01-01

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  3. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Not Available

    1992-12-01

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  4. Apparatus for processing coal

    SciTech Connect

    Williams, R.M.

    1985-02-12

    Apparatus for processing coal to prevent the creation of extreme fines and to extract pyrites from the principal coal fractions in which there are two air circulating circuits having processing components which cooperate in their respective circuits to result initially in substantial extraction of fines in the first circuit while releasing principal granulated coal fractions and pyrites to the second circuit where specific gravity separation of the pyrites and principal coal fractions occur. The apparatus includes a source of drying heat added to the air moving in the circuits and delivered at the places where surface moisture drying is most effective. Furthermore, the apparatus is operated so as to reduce coal to a desired size without creating an excessive volume of extreme fines, to separate pyrites and hard to grind components by specific gravity in a region where fines are not present, and to use the extreme fines as a source of fuel to generate drying heat.

  5. Coal Liquefaction Processes.

    ERIC Educational Resources Information Center

    Yen, T. F.

    1979-01-01

    Described is a graduate level engineering course offered at the University of Southern California on coal liquefaction processes. Lecture topics and course requirements are discussed. A 64-item bibliography of papers used in place of a textbook is included. (BT)

  6. Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S.

    1991-09-25

    The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

  7. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Speight, J.G.

    1992-12-31

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  8. Coal liquefaction process

    DOEpatents

    Karr, Jr., Clarence

    1977-04-19

    An improved coal liquefaction process is provided which enables conversion of a coal-oil slurry to a synthetic crude refinable to produce larger yields of gasoline and diesel oil. The process is characterized by a two-step operation applied to the slurry prior to catalytic desulfurization and hydrogenation in which the slurry undergoes partial hydrogenation to crack and hydrogenate asphaltenes and the partially hydrogenated slurry is filtered to remove minerals prior to subsequent catalytic hydrogenation.

  9. Coal liquefaction process

    DOEpatents

    Skinner, Ronald W.; Tao, John C.; Znaimer, Samuel

    1985-01-01

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  10. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous Fenton oxidation and biological process.

    PubMed

    Xu, Peng; Han, Hongjun; Zhuang, Haifeng; Hou, Baolin; Jia, Shengyong; Xu, Chunyan; Wang, Dexin

    2015-04-01

    Laboratorial scale experiments were conducted in order to investigate a novel system integrating heterogeneous Fenton oxidation (HFO) with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process on advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that HFO with the prepared catalyst (FeOx/SBAC, sewage sludge based activated carbon (SBAC) which loaded Fe oxides) played a key role in eliminating COD and COLOR as well as in improving the biodegradability of raw wastewater. The surface reaction and hydroxyl radicals (OH) oxidation were the mechanisms for FeOx/SBAC catalytic reaction. Compared with ANMBBR-BAF process, the integrated system was more effective in abating COD, BOD5, total phenols (TPs), total nitrogen (TN) and COLOR and could shorten the retention time. Therefore, the integrated system was a promising technology for engineering applications.

  11. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    SciTech Connect

    Not Available

    1993-09-01

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  12. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    SciTech Connect

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  13. Coal liquefaction process

    DOEpatents

    Wright, Charles H.

    1986-01-01

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  14. Coal liquefaction process

    DOEpatents

    Wright, C.H.

    1986-02-11

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  15. Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Ma, Wencheng; Hou, Baolin; Jia, Shengyong; Zhao, Qian

    2015-07-01

    Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon (SBAC) with ZnCl2 as activation agent, which was used as a support for ferric oxides to form a catalyst (FeOx/SBAC) by a simple impregnation method. The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater (CGW). The results indicated that the prepared FeOx/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide pH range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1g/L of catalyst, and the treated effluent concentrations of COD, total phenols, BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated FeOx/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, FeOx/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by FeOx/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.

  16. Coal Liquefaction desulfurization process

    DOEpatents

    Givens, Edwin N.

    1983-01-01

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  17. Advanced systems for producing superclean coal

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1990-08-01

    The purpose of this project was to develop several advanced separation processes for producing superclean coal containing 0.4--2.0% ash and very little pyritic sulfur. Three physical and physico-chemical processes were studied: microbubble flotation, selective hydrophobic coagulation, and electrochemical coal cleaning. Information has been collected from bench-scale experiments in order to determine the basic mechanisms of all three processes. Additionally, because microbubble flotation has already been proven on a bench scale, preliminary scale-up models have been developed for this process. A fundamental study of the electrochemistry of coal pyrite has also been conducted in conjunction with this scale-up effort in order to provide information useful for improving sulfur rejection. The effects of additives (NaCl and kerosene) were also investigated. 94 refs., 167 figs., 25 tabs.

  18. Coal processing plants

    NASA Astrophysics Data System (ADS)

    Bitterlich, W.; Bohn, T.; Eickhoff, H. G.; Geldmacher, H.; Mengis, W.; Oomatia, H.; Stroppel, K. G.

    1980-08-01

    The efficient design of processing plants which combine various coal based technologies in order to maximize the effectiveness of coal utilization is considered. The technical, economical and ecological virtues which compound plants for coal conversion offer are assayed. Twenty-two typical processes of coal conversion and product refinement are selected and described by a standardized method of characterization. An analysis of product market and a qualitative assessment of plant design support six different compound plant propositions. The incorporation of such coal conversion schemes into future energy supply systems was simulated by model calculations. The analysis shows that byproducts and nonconverted materials from individual processes can be processed in a compound plant in a profitable manner. This leads to an improvement in efficiencies. The product spectrum can be adapted to a certain degree to demand variations. Furthermore, the integration of fluidized bed combustion can provide an efficient method of desulfurization. Compound plants are expected to become economic in the 1990's. A necessary condition to compound technologies is high reliability in the functioning of all individual processes.

  19. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Thomas Robl; John Groppo

    2009-06-30

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i.e. Florida

  20. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, July--September 1992

    SciTech Connect

    Not Available

    1992-12-31

    Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

  1. Advanced physical fine coal cleaning: Final report

    SciTech Connect

    Not Available

    1987-12-01

    The contract objective was to demonstrate Advanced Energy Dynamics, Inc., (AED) Ultrafine Coal (UFC) electrostatic physical fine coal cleaning process as capable of: producing clean coal products of no greater than 2% ash; significantly reducing the pyritic sulfur content below that achievable with state-of-the-art coal cleaning; recovering over 80% of the available energy content in the run-of-mine coal; producing product and refuse with surface moisture below 30%. Originally the demonstration was to be of a Charger/Disc System at the Electric Power Research Institute (EPRI) Coal Quality Development Center (CQDC) at Homer City, Pennsylvania. As a result of the combination of Charger/Disc System scale-up problems and parallel development of an improved Vertical-Belt Separator, DOE issued a contract modification to perform additional laboratory testing and optimization of the UFC Vertical-Belt Separator System at AED. These comparative test results, safety analyses and an economic analysis are discussed in this report. 29 refs., 25 figs., 41 tabs.

  2. Catalytic coal liquefaction process

    DOEpatents

    Garg, D.; Sunder, S.

    1986-12-02

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  3. Catalytic coal liquefaction process

    DOEpatents

    Garg, Diwakar; Sunder, Swaminathan

    1986-01-01

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  4. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    SciTech Connect

    Not Available

    1993-09-01

    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  5. Coal liquefaction process

    DOEpatents

    Maa, Peter S.

    1978-01-01

    A process for liquefying a particulate coal feed to produce useful petroleum-like liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone, or stage to the next succeeding higher temperature zone, or stage, of the series. The temperature within the initial zone, or stage, of the series is maintained about 70.degree. F and 750.degree. F and the temperature within the final zone, or stage, is maintained between about 750.degree. F and 950.degree. F. The residence time within the first zone, or stage, ranges, generally, from about 20 to about 150 minutes and residence time within each of the remaining zones, or stages, of the series ranges, generally, from about 10 minutes to about 70 minutes. Further steps of the process include: separating the product from the liquefaction zone into fractions inclusive of a liquid solvent fraction; hydrotreating said liquid solvent fraction in a hydrogenation zone; and recycling the hydrogenated liquid solvent mixture to said coal liquefaction zones.

  6. Process for hydrogenating coal and coal solvents

    DOEpatents

    Tarrer, Arthur R.; Shridharani, Ketan G.

    1983-01-01

    A novel process is described for the hydrogenation of coal by the hydrogenation of a solvent for the coal in which the hydrogenation of the coal solvent is conducted in the presence of a solvent hydrogenation catalyst of increased activity, wherein the hydrogenation catalyst is produced by reacting ferric oxide with hydrogen sulfide at a temperature range of 260.degree. C. to 315.degree. C. in an inert atmosphere to produce an iron sulfide hydrogenation catalyst for the solvent. Optimally, the reaction temperature is 275.degree. C. Alternately, the reaction can be conducted in a hydrogen atmosphere at 350.degree. C.

  7. Coal gasification cogeneration process

    SciTech Connect

    Marten, J.H.

    1990-10-16

    This patent describes a process for the coproduction of a combustible first gas stream usable as an energy source, a sulfur-dioxide-containing second gas stream usable as a source for oxidant in the gasification of coal and a sulfur-dioxide-containing third gas stream usable as a feedstock for the production of sulfuric acid. It comprises: reacting coal in a coal gasification zone in the presence of an oxidant under partial coal-gasifying conditions to produce carbonaceous char and a crude gas stream; separating sulfur-containing compounds from the crude gas stream in a sulfur recovery zone to produce a combustible first gas stream and elemental sulfur; reacting the carbonaceous char and gypsum in a reaction zone in proportions such that the non-gypsum portion of the carbonaceous char and gypsum mixture contains sufficient reducing potential to reduce sulfur in the gypsum to gaseous compounds of sulfur in a +4 or lower oxidation state under reducing conditions to produce first a sulfur-dioxide-containing second gas stream which contains weaker SO{sub 2} produced in an early stage of the reaction zone and removed from the reaction zone, and then a sulfur-dioxide-containing third gas stream which contains concentrated SO{sub 2} recovered from a later stage of the reaction zone.

  8. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    SciTech Connect

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  9. Proceedings of the fifth advanced coal gasification symposium

    SciTech Connect

    Flowers, A.; Alpert, S.; Beck, B.; Chen, C.; Dalrymple, D.; Gummel, P.; Henley, J.; Hileman, E.; Holmgren, J.; Lau, F.

    1987-01-01

    The Fifth Advanced Coal Gasification Symposium, held in Taiyuan, Shanxi, China in September 1987, was sponsored by the Shanxi Provincial Government, Shanxi Science and Technology Association, Shanxi Energy Research Association, and the Taiyuan Coal Gasification Corporation. Opening and closing speeches, summaries of the technical sessions, and lists of delegates are included. Thirteen papers presented by the international delegation of specialists discuss current coal gasification processes and research and development activities. Papers have been indexed separately.

  10. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    SciTech Connect

    Rick Honaker; Gerald Luttrell

    2007-09-30

    surface moisture of the feed coal exceeds the maximum limit. However, the content of -6mm in the feed to the FGX separator should be maintained between 10% and 20% to ensure an adequate fluidized bed. A parametric evaluation was conducted using a 3-level experimental design at each test site to identify the optimum separation performance and parameter values. The test data was used to develop empirical expressions that describe the response variables (i.e., mass yield and product ash content) as a function of the operating parameter values. From this process, it was established that table frequency and longitudinal slope are the most critical factors in controlling both mass yield and clean coal ash while the cross table slope was the least significant. Fan blower frequency is a critical parameter that controls mass yield. Although the splitter positions between product and middling streams and the middling and tailing streams were held constant during the tests, a separate evaluation indicated that performance is sensitive to splitter position within certain lengths of the table and insensitive in others. For a Utah bituminous coal, the FGX separator provided clean coal ash contents that ranged from a low of 8.57% to a high of 12.48% from a feed coal containing around 17% ash. From the 29 tests involved in the statistically designed test program, the average clean coal ash content was 10.76% while the tailings ash content averaged around 72%. One of the best separation performances achieved an ash reduction from 17.36% to 10.67% while recovering 85.9% of the total feed mass, which equated to an ash rejection value of around 47%. The total sulfur content was typically decreased from 1.61% to 1.49%. These performances were quantified by blending the middlings stream with the clean coal product. At a second Utah site, coal sources from three different bituminous coal seams were treated by the FGX deshaling unit. Three parameter values were varied based on the results

  11. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Thomas Robl; John Groppo

    2005-09-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. A mobile demonstration unit has been designed and constructed for field demonstration. The demonstration unit was hauled to the test site on trailers that were place on a test pad located adjacent to the ash pond and re-assembled. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities. Representative feed ash for the operation of the filed testing unit was excavated from a location within the lower ash pond determined from coring activities. Approximately 150 tons of ash was excavated and pre-screened to remove +3/8 inch material that could cause plugging problems during operation of the demonstration unit.

  12. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl

    2005-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. Filter media candidates were evaluated for dewatering the ultrafine ash (UFA) product. Media candidates were selected based on manufacturer recommendations and evaluated using standard batch filtration techniques. A final media was selected; 901F, a multifilament polypropylene. While this media would provide adequate solids capture and cake moisture, the use of flocculants would be necessary to enable adequate filter throughput. Several flocculant chemistries were also evaluated and it was determined that polyethylene oxide (PEO) at a dosage of 5 ppm (slurry basis) would be the most suitable in terms of both settling rate and clarity. PEO was evaluated on a continuous vacuum filter using 901F media. The optimum cycle time was found to be 1.25 minutes which provided a 305% moisture cake, 85% solids capture with a throughput of 115 lbs dry solids per hour and a dry cake rate of 25 lb/ft2/hr. Increasing cycle time not did not reduce cake moisture or increase throughput. A mobile demonstration unit has been designed and constructed for field demonstration. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities.

  13. Clean coal demonstration program: Advanced flue gas desulfurization process. Volume 1 - public design report

    SciTech Connect

    1990-03-01

    The single 100 percent absorber is a co-current grid packed tower with an integrated reaction tank at the bottom. It is designed to accomplish several process steps (quenching, absorption of SO{sub 2}, reaction with limestone, oxidation to gypsum) in a single vessel, resulting in a simple configuration of the plant. The co-current absorber is designed for higher flue gas velocities than conventional countercurrent towers, which results in a compact absorber size. The flue gas enters the top of the absorber where it contacts recirculating slurry. Quenching and absorption of SO{sub 2} occur simultaneously. This {open_quotes}wet/dry{close_quotes} interface is washed intermittently with fresh water to prevent the formation and growth of any deposits.

  14. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  15. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl

    2006-06-30

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utility's 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. A Topical Report was prepared and included all of the pertinent processing data generated during Budget Period 1 of the project as well as results of beneficiated ash product evaluations in mortar and concrete, schematic plant designs with mass and water balances for the four flowsheets tested with equipment lists, capital and installation costs, expected product outputs and equipment justifications. A proposal for continuation of the project to Budget Period 2 was also prepared and submitted, with the exception of a Letter of Commitment from Cemex. The proposal is currently under internal review with Cemex and a decision is expected by the end of September, 2006.

  16. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect

    John Groppo; Thomas Robl; Robert Rathbone

    2006-06-01

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The secondary classification testing was concluded using a continuous demonstration-scale lamella classifier that was operated at a feed rate of 0.3 to 1.5 tons/hr. Feed to the secondary classifier was generated by operating the primary classifier at the conditions shown to be effective previously. Samples were taken while the secondary classifier was operated under a variety of conditions in order to determine the range of conditions where the unit could be efficiently operated. Secondary classification was effective for producing an ultra-fine ash (UFA) product. Inclined lamella plates provided an effective settling surface for coarser ash particles and plate spacing was shown to be an important variable. Results showed that the closer the plate spacing, the finer the size distribution of the UFA product. Flotation of the secondary classifier feed provided a lower LOI UFA product (2.5% LOI vs. 4.5% LOI) and a dispersant dosage of 2 to 2.5 g/kg was adequate to provide UFA grade (3.8 to 4.4 {micro}m) and recovery (53 to 68% 5{micro}m recovery). The UFA yield without flotation was {approx}33% and lower ({approx}20%) with flotation. Demonstration plant product evaluations showed that water requirements in mortar were reduced and 100% of control strength was achieved in 28 days for the coarser products followed by further strength gain of up to 130% in 56 days. The highest strengths of 110% of control in 7 days and 140% in 56 days were achieved with the finer products. Mortar air requirements for processed products were essentially the same as those for standard mortar, suggesting that the unburned carbon remaining does not have

  17. Coal desulfurization process

    NASA Technical Reports Server (NTRS)

    Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

    1978-01-01

    A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

  18. The shell coal gasification process

    SciTech Connect

    Koenders, L.O.M.; Zuideveld, P.O.

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  19. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Diao, J.; De, A.; Sotillo, F.; Harris, G. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, Weibai; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (United

    1991-07-30

    The primary objective in the scope of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from three major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Investigation of mechanisms for the control of coal and pyrite surfaces prior to fine coal flotation is the main aspect of the project objectives. The results of this research are to be made available to ICF Kaiser Engineers who are currently working on the Engineering Development of Advanced Flotation under a separate contract with DOE under the Acid Rain Control Initiative program. A second major objective is to investigate factors involved in the progressive weathering and oxidation of coal that had been exposed to varying degrees of weathering, namely, open to the atmosphere, covered and in an argon-inerted'' atmosphere, over a period of twelve months. After regular intervals of weathering, samples of the three base coals (Illinois No. 6, Pittsburgh No. 8 and Upper Freeport PA) were collected and shipped to both the University of Pittsburgh and the University of California at Berkeley for characterization studies of the weathered material. 29 figs., 29 tabs.

  20. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Diao, J.; De, A.; Sotillo, F.; Harris, G. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, W.; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (United Stat

    1991-05-15

    The primary objective in the scope of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from three major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Investigation of mechanisms for the control of coal and pyrite surfaces prior to fine coal flotation is the main aspect of the project objectives. Research topics covered during this quarter include the characterization of the base coals, various flotation studies on optimization and pyrite rejection, and a detailed flotation kinetic study. The effect of hexanol, butanol, dodecane, and polyethylene glycol on flotation is described. A second major objective is to investigate factors involved in the progressive weathering and oxidation of coal that had been exposed to varying weathered degrees, namely, open, covered and in an argon-inerted'' atmosphere, over a period of twelve months. After regular intervals if weathering, samples of the three base coals (Illinois No. 6, Pittsburgh No. 8 and Upper Freeport PA) were collected and shipped to both the University of Pittsburgh and the University of California at Berkeley for characterization studies of the weathered material. 35 figs., 17 tabs.

  1. Coal recovery process

    DOEpatents

    Good, Robert J.; Badgujar, Mohan

    1992-01-01

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  2. Process for electrochemically gasifying coal

    DOEpatents

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  3. Iron catalyzed coal liquefaction process

    DOEpatents

    Garg, Diwakar; Givens, Edwin N.

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  4. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, W.; Zou, Y.; Chen, W. ); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. )

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  5. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  6. COSTS FOR ADVANCED COAL COMBUSTION TECHNOLOGIES

    EPA Science Inventory

    The report gives results of an evaluation of the development status of advanced coal combustion technologies and discusses the preparation of performance and economic models for their application to electric utility plants. he technologies addressed were atmospheric fluidized bed...

  7. Modelling and assessment of advanced processes for integrated environmental control of coal-fired power plants. Technical progress report

    SciTech Connect

    Barrett, J.G.; Bloyd, C.N.; McMichael, F.C.; Rubin, E.S.

    1984-07-01

    The key objective of this research is the development of a computer based model for the assessment of integrated environmental control (IEC) systems for conventional and advanced coal fired power plant designs. Efforts during the period April 1-June 30, 1984 focused on, (1) testing of a preliminary integrated model linking pre-combustion and post-combustion control options for conventional plants; (2) documentation of the analytical models of existing control technology options; (3) development and preliminary testing of a second model design for the propagation and analysis of uncertainty; and (4) development of new analytical models needed for IEC assessments. Activities and accomplishments in each of these areas are described. 4 references, 13 figures, 4 tables.

  8. Coal liquefaction process with enhanced process solvent

    DOEpatents

    Givens, Edwin N.; Kang, Dohee

    1984-01-01

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  9. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  10. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Wenglarz, R.A.

    1994-08-01

    Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

  11. Materials of construction for advanced coal conversion systems

    SciTech Connect

    Nangia, V.K.

    1982-01-01

    This book describes materials of construction, and materials problems for equipment used in advanced coal conversion systems. The need for cost effective industrial operation is always a prime concern, particularly in this age of energy consciousness. Industry is continually seeking improved materials for more efficient systems. The information presented here is intended to be of use in the design and planning of these systems. Coal conversion and utilization impose severe demands on construction materials because of high temperature, high pressure, corrosive/erosive, and other hostile environmental factors. Successful economic development of these processes can be achieved only to the extent that working materials can withstand increasingly more aggressive operating conditions. The book, which reviews present and past work on the behavior of materials in the environments of advanced coal conversion systems, is divided into three parts: atmospheric fluidized bed combustion, coal gasification and liquefaction, and advanced power systems.

  12. Coal surface control for advanced fine coal flotation

    SciTech Connect

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. ); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. ); Hu, Weibai; Zou, Y.; Chen, W. ); Choudhry, V.; Sehgal, R.; Ghosh, A. )

    1990-08-15

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  13. Process for low mercury coal

    DOEpatents

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  14. Process for low mercury coal

    DOEpatents

    Merriam, Norman W.; Grimes, R. William; Tweed, Robert E.

    1995-01-01

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  15. Technoeconomic Assessment of an Advanced Aqueous Ammonia-Based Postcombustion Capture Process Integrated with a 650-MW Coal-Fired Power Station.

    PubMed

    Li, Kangkang; Yu, Hai; Yan, Shuiping; Feron, Paul; Wardhaugh, Leigh; Tade, Moses

    2016-10-04

    Using a rigorous, rate-based model and a validated economic model, we investigated the technoeconomic performance of an aqueous NH3-based CO2 capture process integrated with a 650-MW coal-fired power station. First, the baseline NH3 process was explored with the process design of simultaneous capture of CO2 and SO2 to replace the conventional FGD unit. This reduced capital investment of the power station by US$425/kW (a 13.1% reduction). Integration of this NH3 baseline process with the power station takes the CO2-avoided cost advantage over the MEA process (US$67.3/tonne vs US$86.4/tonne). We then investigated process modifications of a two-stage absorption, rich-split configuration and interheating stripping to further advance the NH3 process. The modified process reduced energy consumption by 31.7 MW/h (20.2% reduction) and capital costs by US$55.4 million (6.7% reduction). As a result, the CO2-avoided cost fell to $53.2/tonne: a savings of $14.1 and $21.9/tonne CO2 compared with the NH3 baseline and advanced MEA process, respectively. The analysis of energy breakdown and cost distribution indicates that the technoeconomic performance of the NH3 process still has great potential to be improved.

  16. Coal cleaning process

    SciTech Connect

    Kindig, J.K.

    1994-01-11

    Fine particle coal is beneficiated in specially designed dense medium cyclones to improve particle acceleration and enhance separation efficiency. Raw coal feed is first sized to remove fine coal particles. The coarse fraction is then separated into clean coal, middlings, and refuse. Middlings are comminuted for beneficiation with the fine fraction. The fine fraction is deslimed in a countercurrent cyclone circuit and then separated as multiple fractions of different size specifications in dense medium cyclones. The dense medium contains ultra-fine magnetite particles of a narrow size distribution which aid separation and improves magnetite recovery. Magnetite is recovered from each separated fraction independently, with non-magnetic effluent water from one fraction diluting feed to a smaller-size fraction, and improving both overall coal and magnetite recovery. Magnetite recovery is in specially designed recovery units, based on particle size, with final separation in a rougher-cleaner-scavenger circuit of magnetic drum separators incorporating a high strength rare earth magnet. 12 figs.

  17. DOE/EA-1498: Environmental Assessment for the Advanced Coal Utilization Byproduct Beneficiation Processing Plant Ghent Power Station, Carroll County, Kentucky (January 2005)

    SciTech Connect

    N /A

    2005-01-01

    The Clean Coal Power Initiative (CCPI) is a cost-shared partnership between the U.S. Department of Energy (DOE) and industry to demonstrate advanced coal-based power generation technologies. Through the CCPI, candidate technologies are demonstrated at commercial-scale facilities to foster widespread application. The goals of the program are to realize environmental and economic benefits through DOE and industry partnerships, as well as to move promising, yet commercially risky, advanced coal energy systems to market. DOE proposes to provide funding, through a cooperative agreement with the University of Kentucky Research Foundation (UKRF), Center for Applied Energy Research (CAER), for the design, construction, and operation of an advanced coal ash beneficiation processing plant at Kentucky Utilities (KU) Ghent Power Station in Carroll County, Kentucky. The proposed project would contribute to CCPI program goals by demonstrating a means to reduce the net costs of particulate control technologies through the conversion of ash into salable products. DOE would provide $4,492,008, approximately 50 percent of total project cost. The proposed demonstration plant would process 200,000 tons per year of fly ash generated at the Ghent Power Station into: 156,000 tons per year of pozzolan for concrete; 16,000 tons per year of high-quality block sand; 16,000 tons per year of graded fill sand; 1,500 tons per year of high-quality polymer filler; and 8,000 tons of carbon fuel. Because the proposed project would utilize an existing waste to produce concrete and masonry materials, which could replace Portland cement, overall CO2 emissions resulting from concrete manufacturing could be reduced. Furthermore, the need for additional storage areas for fly ash would be reduced. The findings of this Environmental are that no significant impacts to human health and safety or the environment from construction and operation of the proposed demonstration plant are anticipated. Because the

  18. Controlling air toxics through advanced coal preparation

    SciTech Connect

    Straszheim, W.E.; Buttermore, W.H.; Pollard, J.L.

    1995-11-01

    This project involves the assessment of advanced coal preparation methods for removing trace elements from coal to reduce the potential for air toxic emissions upon combustion. Scanning electron microscopy-based automated image analysis (SEM-AIA) and advanced washability analyses are being applied with state-of-the-art analytical procedures to predict the removal of elements of concern by advanced column flotation and to confirm the effectiveness of preparation on the quality of quantity of clean coal produced. Specific objectives are to maintain an acceptable recovery of combustible product, while improving the rejection of mineral-associated trace elements. Current work has focused on determining conditions for controlling column flotation system across its operating range and on selection and analysis of samples for determining trace element cleanability.

  19. Process for blending coal with water immiscible liquid

    DOEpatents

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  20. Final Report of the Advanced Coal Technology Work Group

    EPA Pesticide Factsheets

    The Advanced Coal Technology workgroup reported to the Clean Air Act Advisory Committee. This page includes the final report of the Advanced Coal Technology Work Group to the Clean Air Act Advisory Committee.

  1. Advanced froth flotation techniques for fine coal cleaning

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-12-31

    Advanced column flotation cells offer many potential advantages for the treatment of fine coal. The most important of these is the ability to achieve high separation efficiencies using only a single stage of processing. Unfortunately, industrial flotation columns often suffer from poor recovery, low throughput and high maintenance requirements as compared to mechanically-agitated conventional cells. These problems can usually be attributed to poorly-designed air sparging systems. This article examines the problems of air sparging in greater detail and offers useful guidelines for designing bubble generators for industrial flotation columns. The application of these principles in the design of a successful advanced fine coal flotation circuit is also presented.

  2. Process for cleaning fine coal

    SciTech Connect

    Ennis, R.E.

    1981-08-04

    A process for the wet concentration and cleaning of fine coal is provided which comprises the steps of desliming and thickening a dilute slurry of fine coal and contaminant particles having a size of less than about 10 mm by introducing the same to a hydrocyclone separator to retain a slurry of particles having a size greater than about 0.1 mm, wet concentrating the last-named slurry and removing the heavier contaminant particles by introducing it to an autogenous dense medium separation vessel having a manifold for injecting water at an intermediate level and controlling the underflow of heavier than coal particles to maintain a fluidized bed of heavier particles and causing a slurry of the lighter coal particles to overflow, and concentrating and dewatering the overflow by means of a static or vibratory sizing screen.

  3. Low-energy process for separating hydrogen and methane in advanced coal-gasification processes. Final report, September 8, 1980-January 7, 1983

    SciTech Connect

    Yang, R.T.; Saunders, J.T.; Byers, S.G.; Wang, S.S.

    1983-01-01

    This report contains the detailed results of the following three-part study: Part I. Adsorption of H/sub 2//CH/sub 4/ from single and mixed gases on activated carbon, coals and chars; Part II. Adsorption of H/sub 2/S and its mixtures with H/sub 2//CH/sub 4/ on activated carbon, coals and chars; and Part III. Separation of H/sub 2//CH/sub 4/ and H/sub 2//CH/sub 4//H/sub 2/S mixtures by a temperature-cycling process. The original scope of the study, as indicated by the title of the report, has been expanded to include H/sub 2/S in the gas mixture. The inclusion of H/sub 2/S was to study the feasibility of combining the H/sub 2//CH/sub 4/ separation step with the H/sub 2/S removal step into a single process. The success of the feasibility study naturally leads to the possibility of separating both CO/sub 2/ and H/sub 2/S from H/sub 2/ and CH/sub 4/ in coal gasification products by the cyclic adsorption/desorption process. The results of the study are presented.

  4. Process for coal liquefaction employing selective coal feed

    DOEpatents

    Hoover, David S.; Givens, Edwin N.

    1983-01-01

    An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

  5. Advanced clean coal utilization technologies

    SciTech Connect

    Moritomi, Hiroshi

    1993-12-31

    The most important greenhouse gas is CO{sub 2} from coal utilization. Ways of mitigating CO{sub 2} emissions include the use of alternative fuels, using renewable resources and increasing the efficiency of power generation and end use. Adding to such greenhouse gas mitigation technologies, post combustion control by removing CO{sub 2} from power station flue gases and then storing or disposing it will be available. Although the post combustion control have to be evaluated in a systematic manner relating them to whether they are presently available technology, to be available in the near future or long term prospects requiring considerable development, it is considered to be a less promising option owing to the high cost and energy penalty. By contrast, abatement technologies aimed at improving conversion efficiency or reducing energy consumption will reduce emissions while having their own commercial justification.

  6. Bench-scale Development of an Advanced Solid Sorbent-based CO2 Capture Process for Coal-fired Power Plants

    SciTech Connect

    Nelson, Thomas; Kataria, Atish; Soukri, Mustapha; Farmer, Justin; Mobley, Paul; Tanthana, Jak; Wang, Dongxiang; Wang, Xiaoxing; Song, Chunshan

    2015-12-31

    It is increasingly clear that CO2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO2 capture processes – such as RTI’s Advanced Solid Sorbent CO2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO2 capture. The overall objective

  7. Granuflow and Mulled coal: Alternative processes for fine coal recovery

    SciTech Connect

    Davis, B.E.

    1999-07-01

    Granuflow and Mulled Coal were developed in parallel to enhance the ability to recover and process wet coal fines. There are some similarities in the processes; however, the end products are quite different. This paper will compare the properties of the two products prepared from the same coal and identify the unique properties of each. Criteria for selecting between the two processes, including cost, will be discussed.

  8. Technology and development requirements for advanced coal conversion systems

    NASA Technical Reports Server (NTRS)

    1981-01-01

    A compendium of coal conversion process descriptions is presented. The SRS and MC data bases were utilized to provide information paticularly in the areas of existing process designs and process evaluations. Additional information requirements were established and arrangements were made to visit process developers, pilot plants, and process development units to obtain information that was not otherwise available. Plant designs, process descriptions and operating conditions, and performance characteristics were analyzed and requirements for further development identified and evaluated to determine the impact of these requirements on the process commercialization potential from the standpoint of economics and technical feasibility. A preliminary methodology was established for the comparative technical and economic assessment of advanced processes.

  9. Health requirements for advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Zimmerman, W. F.

    1980-01-01

    Health requirements were developed as long range goals for future advanced coal extraction systems which would be introduced into the market in the year 2000. The goal of the requirements is that underground coal miners work in an environment that is as close as possible to the working conditions of the general population, that they do not exceed mortality and morbidity rates resulting from lung diseases that are comparable to those of the general population, and that their working conditions comply as closely as possible to those of other industries as specified by OSHA regulations. A brief technique for evaluating whether proposed advanced systems meet these safety requirements is presented, as well as a discussion of the costs of respiratory disability compensation.

  10. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy's program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research Development Center (Amax R D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  11. Advanced Hydrogen Transport Membrane for Coal Gasification

    SciTech Connect

    Schwartz, Joseph; Porter, Jason; Patki, Neil; Kelley, Madison; Stanislowski, Josh; Tolbert, Scott; Way, J. Douglas; Makuch, David

    2015-12-23

    A pilot-scale hydrogen transport membrane (HTM) separator was built that incorporated 98 membranes that were each 24 inches long. This separator used an advanced design to minimize the impact of concentration polarization and separated over 1000 scfh of hydrogen from a hydrogen-nitrogen feed of 5000 scfh that contained 30% hydrogen. This mixture was chosen because it was representative of the hydrogen concentration expected in coal gasification. When tested with an operating gasifier, the hydrogen concentration was lower and contaminants in the syngas adversely impacted membrane performance. All 98 membranes survived the test, but flux was lower than expected. Improved ceramic substrates were produced that have small surface pores to enable membrane production and large pores in the bulk of the substrate to allow high flux. Pd-Au was chosen as the membrane alloy because of its resistance to sulfur contamination and good flux. Processes were developed to produce a large quantity of long membranes for use in the demonstration test.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  13. Direct coal liquefaction process

    DOEpatents

    Rindt, J.R.; Hetland, M.D.

    1993-10-26

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300 C to 400 C for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  14. Direct coal liquefaction process

    DOEpatents

    Rindt, John R.; Hetland, Melanie D.

    1993-01-01

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300.degree. C. to 400.degree. C. for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  15. Advanced Coal Wind Hybrid: Economic Analysis

    SciTech Connect

    Phadke, Amol; Goldman, Charles; Larson, Doug; Carr, Tom; Rath, Larry; Balash, Peter; Yih-Huei, Wan

    2008-11-28

    Growing concern over climate change is prompting new thinking about the technologies used to generate electricity. In the future, it is possible that new government policies on greenhouse gas emissions may favor electric generation technology options that release zero or low levels of carbon emissions. The Western U.S. has abundant wind and coal resources. In a world with carbon constraints, the future of coal for new electrical generation is likely to depend on the development and successful application of new clean coal technologies with near zero carbon emissions. This scoping study explores the economic and technical feasibility of combining wind farms with advanced coal generation facilities and operating them as a single generation complex in the Western US. The key questions examined are whether an advanced coal-wind hybrid (ACWH) facility provides sufficient advantages through improvements to the utilization of transmission lines and the capability to firm up variable wind generation for delivery to load centers to compete effectively with other supply-side alternatives in terms of project economics and emissions footprint. The study was conducted by an Analysis Team that consists of staff from the Lawrence Berkeley National Laboratory (LBNL), National Energy Technology Laboratory (NETL), National Renewable Energy Laboratory (NREL), and Western Interstate Energy Board (WIEB). We conducted a screening level analysis of the economic competitiveness and technical feasibility of ACWH generation options located in Wyoming that would supply electricity to load centers in California, Arizona or Nevada. Figure ES-1 is a simple stylized representation of the configuration of the ACWH options. The ACWH consists of a 3,000 MW coal gasification combined cycle power plant equipped with carbon capture and sequestration (G+CC+CCS plant), a fuel production or syngas storage facility, and a 1,500 MW wind plant. The ACWH project is connected to load centers by a 3,000 MW

  16. Process for changing caking coals to noncaking coals

    DOEpatents

    Beeson, Justin L.

    1980-01-01

    Caking coals are treated in a slurry including alkaline earth metal hydroxides at moderate pressures and temperatures in air to form noncaking carbonaceous material. Hydroxides such as calcium hydroxide, magnesium hydroxide or barium hydroxide are contemplated for slurrying with the coal to interact with the agglomerating constituents. The slurry is subsequently dewatered and dried in air at atmospheric pressure to produce a nonagglomerating carbonaceous material that can be conveniently handled in various coal conversion and combustion processes.

  17. Advanced progress concepts for direct coal liquefaction

    SciTech Connect

    Anderson, R.; Derbyshire, F.; Givens, E.

    1995-09-01

    Given the low cost of petroleum crude, direct coal liquefaction is still not an economically viable process. The DOE objectives are to further reduce the cost of coal liquefaction to a more competitive level. In this project the primary focus is on the use of low-rank coal feedstocks. A particular strength is the use of process-derived liquids rather than model compound solvents. The original concepts are illustrated in Figure 1, where they are shown on a schematic of the Wilsonville pilot plant operation. Wilsonville operating data have been used to define a base case scenario using run {number_sign}263J, and Wilsonville process materials have been used in experimental work. The CAER has investigated: low severity CO pretreatment of coal for oxygen rejection, increasing coal reactivity and mg inhibiting the propensity for regressive reactions; the application of more active. Low-cost Fe and Mo dispersed catalysts; and the possible use of fluid coking for solids rejection and to generate an overhead product for recycle. CONSOL has investigated: oil agglomeration for coal ash rejection, for the possible rejection of ash in the recycled resid, and for catalyst addition and recovery; and distillate dewaxing to remove naphthenes and paraffins, and to generate an improved quality feed for recycle distillate hydrogenation. At Sandia, research has been concerned with the production of active hydrogen donor distillate solvent fractions produced by the hydrogenation of dewaxed distillates and by fluid coking via low severity reaction with H{sub 2}/CO/H{sub 2}O mixtures using hydrous metal oxide and other catalysts.

  18. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    SciTech Connect

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  19. The feasibility of using combined TiO2 photocatalysis oxidation and MBBR process for advanced treatment of biologically pretreated coal gasification wastewater.

    PubMed

    Xu, Peng; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng; Jia, Shengyong; Wang, Dexin; Li, Kun; Zhao, Qian

    2015-01-01

    The study examined the feasibility of using combined heterogeneous photocatalysis oxidation (HPO) and moving bed biofilm reactor (MBBR) process for advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that the TOC removal efficiency was significantly improved in HPO. Gas chromatography-mass spectrometry (GC-MS) analysis indicated that the HPO could be employed to eliminate bio-refractory and toxic compounds. Meanwhile, the BOD5/COD of the raw wastewater was increased from 0.08 to 0.49. Furthermore, in the integration of TiO2 photocatalysis oxidation and MBBR process, the effluent of COD, BOD5, TOC, NH4(+)-N and TN were 22.1 mg/L, 1.1 mg/L, 11.8 mg/L, 4.1mg/L and 13.7 mg/L, respectively, which all met class-I criteria of the Integrated Wastewater Discharge Standard (GB18918-2002, China). The total operating cost was 2.8CNY/t. Therefore, there is great potential for the combined system in engineering applications as a final treatment for biologically pretreated CGW.

  20. Process for removing ash from coal

    SciTech Connect

    Harada, K.; Nakanishi, T.; Ogino, E.; Yoshida, N.

    1983-06-21

    A process for removing ash from coal comprising the steps of pulverizing the coal to fine particles, admixing water with the finely divided coal to prepare an ash-containing slurry of finely divided coal, mixing with the slurry an oil and seeds in the form of oleophilic solid grains and serving as granulating nuclei to granulate the finely divided coal, separating the resulting granules from the mixture and washing the granules with water to remove the ash, and disintegrating the washed granules to obtain a deashed coal and recover the seeds for reuse.

  1. Advanced coal-fired glass melting development program

    SciTech Connect

    Not Available

    1991-05-01

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  2. Catalyst for coal liquefaction process

    DOEpatents

    Huibers, Derk T. A.; Kang, Chia-Chen C.

    1984-01-01

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  3. Coal and Coal Constituent Studies by Advanced EMR Techniques

    SciTech Connect

    Alex I. Smirnov; Mark J. Nilges; R. Linn Belford; Robert B. Clarkson

    1998-03-31

    Advanced electronic magnetic resonance (EMR) methods are used to examine properties of coals, chars, and molecular species related to constituents of coal. We have achieved substantial progress on upgrading the high field (HF) EMR (W-band, 95 GHz) spectrometers that are especially advantageous for such studies. Particularly, we have built a new second W-band instrument (Mark II) in addition to our Mark I. Briefly, Mark II features: (i) an Oxford custom-built 7 T superconducting magnet which is scannable from 0 to 7 T at up to 0.5 T/min; (ii) water-cooled coaxial solenoid with up to ±550 G scan under digital (15 bits resolution) computer control; (iii) custom-engineered precision feed-back circuit, which is used to drive this solenoid, is based on an Ultrastab 860R sensor that has linearity better than 5 ppm and resolution of 0.05 ppm; (iv) an Oxford CF 1200 cryostat for variable temperature studies from 1.8 to 340 K. During this grant period we have completed several key upgrades of both Mark I and II, particularly microwave bridge, W-band probehead, and computer interfaces. We utilize these improved instruments for HF EMR studies of spin-spin interaction and existence of different paramagnetic species in carbonaceous solids.

  4. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1992-09-01

    Westinghouse's Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO[sub x] emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO[sub x] levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  5. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  6. Integrated coal cleaning, liquefaction, and gasification process

    DOEpatents

    Chervenak, Michael C.

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  7. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system: Topical report, Process analysis, FY 1983

    SciTech Connect

    1987-07-31

    KRW Energy Systems, Inc., is engaged in the continuing development of a pressurized, fluidized-bed gasification process at its Waltz Mill Site in Madison, Pennsylvania. The overall objective of the program is to demonstrate the viability of the KRW process for the environmentally-acceptable production of low- and medium-Btu fuel gas from a variety of fossilized carbonaceous feedstocks and industrial fuels. This report presents process analysis of the 24 ton-per-day Process Development Unit (PDU) operations and is a continuation of the process analysis work performed in 1980 and 1981. Included is work performed on PDU process data; gasification; char-ash separation; ash agglomeration; fines carryover, recycle, and consumption; deposit formation; materials; and environmental, health, and safety issues. 63 figs., 43 tabs.

  8. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Rawls, P.

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  9. Process for selective grinding of coal

    DOEpatents

    Venkatachari, Mukund K.; Benz, August D.; Huettenhain, Horst

    1991-01-01

    A process for preparing coal for use as a fuel. Forming a coal-water slurry having solid coal particles with a particle size not exceeding about 80 microns, transferring the coal-water slurry to a solid bowl centrifuge, and operating same to classify the ground coal-water slurry to provide a centrate containing solid particles with a particle size distribution of from about 5 microns to about 20 microns and a centrifuge cake of solids having a particle size distribution of from about 10 microns to about 80 microns. The classifer cake is reground and mixed with fresh feed to the solid bowl centrifuge for additional classification.

  10. Fabrication of Pd/Pd-Alloy Films by Surfactant Induced Electroless Plating for Hydrogen Separation from Advanced Coal Gasification Processes

    SciTech Connect

    Ilias, Shamsuddin; Kumar, Dhananjay

    2012-07-31

    Dense Pd, Pd-Cu and Pd-Ag composite membranes on microporous stainless steel substrate (MPSS) were fabricated by a novel electroless plating (EP) process. In the conventional Pd-EP process, the oxidation-reduction reactions between Pd-complex and hydrazine result in an evolution of NH{sub 3} and N{sub 2} gas bubbles. When adhered to the substrate surface and in the pores, these gas bubbles hinder uniform Pd-film deposition which results in dendrite growth leading to poor film formation. This problem was addressed by introducing cationic surfactant in the electroless plating process known as surfactant induced electroless plating (SIEP). The unique features of this innovation provide control of Pd-deposition rate, and Pd-grain size distribution. The surfactant molecules play an important role in the EP process by tailoring grain size and the process of agglomeration by removing tiny gas bubbles through adsorption at the gas-liquid interface. As a result surfactant can tailor a nanocrystalline Pd, Cu and Ag deposition in the film resulting in reduced membrane film thickness. Also, it produces a uniform, agglomerated film structure. The Pd-Cu and Pd-Ag membranes on MPSS support were fabricated by sequential deposition using SIEP method. The pre- and post-annealing characterizations of these membranes (Pd, Pd-Cu and Pd-Ag on MPSS substrate) were carried out by SEM, EDX, XRD, and AFM studies. The SEM images show significant improvement of the membrane surface morphology, in terms of metal grain structures and grain agglomeration compared to the membranes fabricated by conventional EP process. The SEM images and helium gas-tightness studies indicate that dense and thinner films of Pd, Pd-Cu and Pd-Ag membranes can be produced with shorter deposition time using surfactant. H{sub 2} Flux through the membranes fabricated by SIEP shows large improvement compared to those by CEP with comparable permselectivity. Pd-MPSS composite membrane was subjected to test for long term

  11. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO[sub 2] per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO[sub 2] emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  12. Advanced Coal-Fueled Gas Turbine Program

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  13. Rocketdyne's advanced coal slurry pumping program

    NASA Technical Reports Server (NTRS)

    Davis, D. E.; Wong, G. S.; Gilman, H. H.

    1977-01-01

    The Rocketdyne Division of Rockwell International Corporation is conducting a program for the engineering, fabrication, and testing of an experimental/prototype high-capacity, high-pressure centrifugal slurry feed pump for coal liquefaction purposes. The abrasion problems in a centrifugal slurry pump are primarily due to the manner in which the hard, solid particles contained in the slurry are transported through the hydraulic flow passages within the pump. The abrasive particles can create scraping, grinding, cutting, and sandblasting effects on the various exposed parts of the pump. These critical areas involving abrasion and impact erosion wear problems in a centrifugal pump are being addressed by Rocketdyne. The mechanisms of abrasion and erosion are being studied through hydrodynamic analysis, materials evaluation, and advanced design concepts.

  14. Process for electrochemically gasifying coal using electromagnetism

    DOEpatents

    Botts, Thomas E.; Powell, James R.

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  15. Engineering design and analysis of advanced physical fine coal cleaning technologies

    SciTech Connect

    Gallier, P.W.

    1992-10-20

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies- advanced cylconing, selective agglomeration, and advanced froth flotation through the proof-of-concept. The commercially available ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology Inc. (AspenTech), its contractor, ICF Kaiser Engineers, Inc., (ICF KE) and CQ Inc., for the period of July through September 1992. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models. CQ Inc. is a subcontractor to ICF KE on Tasks I - 5 and is a contractor to AspenTech on Task 6.

  16. Pilot Plant Program for the AED Advanced Coal Cleaning System. Phase II. Interim final report

    SciTech Connect

    Not Available

    1980-08-01

    Advanced Energy Dynamics, Inc. (AED), has developed a proprietary coal cleaning process which employs a combination of ionization and electrostatic separation to remove both sulfur and ash from dry pulverized coal. The Ohio Department of Energy sponsored the first part of a program to evaluate, develop, and demonstrate the process in a continuous-flow pilot plant. Various coals used by Ohio electric utilities were characterized and classified, and sulfur reduction, ash reduction and Btu recovery were measured. Sulfur removal in various coals ranged from 33 to 68% (on a Btu basis). Ash removal ranged from 17 to 59% (on a Btu basis). Ash removal of particles greater than 53 microns ranged from 46 to 88%. Btu recovery ranged from 90 to 97%. These results, especially the large percentage removal of ash particles greater than 53 microns, suggest that the AED system can contribute materially to improved boiler performance and availability. The study indicated the following potential areas for commercial utilization of the AED process: installation between the pulverizer and boiler of conventional coal-fired power utilities; reclamation of fine coal refuse; dry coal cleaning to supplement, and, if necessary, to take the place of conventional coal cleaning; upgrading coal used in: (1) coal-oil mixtures, (2) gasification and liquefaction processes designed to handle pulverized coal; and (3) blast furnaces for making steel, as a fuel supplement to the coke. Partial cleaning of coking coal blends during preheating may also prove economically attractive. Numerous other industrial processes which use pulverized coal such as the production of activated carbon and direct reduction of iron ore may also benefit from the use of AED coal cleaning.

  17. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect

    Karekh, B K; Tao, D; Groppo, J G

    1998-08-28

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 - March 31, 1998.

  18. Process for treating moisture laden coal fines

    DOEpatents

    Davis, Burl E.; Henry, Raymond M.; Trivett, Gordon S.; Albaugh, Edgar W.

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  19. Fired heater for coal liquefaction process

    DOEpatents

    Ying, David H. S.; McDermott, Wayne T.; Givens, Edwin N.

    1985-01-01

    A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

  20. Recent advances in the perchloroethylene coal cleaning system

    SciTech Connect

    Fullerton, K.L.; Lee, S.; Kulik, C.J.

    1994-12-31

    The perchloroethylene coal desulfurization process has been shown to selectively remove both inorganic and organic sulfur as well as mineral matter from high sulfur Midwestern coals. The process consists of four stages: a wet grinding of the coal to {minus}200 mesh, an extraction stage used to remove organic sulfur, a float sink stage to remove pyritic sulfur and mineral matter, and finally, a steam stripping stage to remove residual perchloroethylene from the coal. Using this process, up to 70% of the organic sulfur and over 90% of the pyritic sulfur can be removed from the coal. Recent work has studied the effects of parameters such as type of coal, particle size, moisture content, process temperatures, etc., on the sulfur removal efficiency. In addition, a kinetic relation was established for several types of Midwestern coals and minimum extraction time was established. The kinetic study was also used to conduct simulation studies of batch, plug flow reactor, and continuous stirred tank reactor.

  1. Engineering design and analysis of advanced physical fine coal cleaning technologies

    SciTech Connect

    Gallier, P.W.

    1991-10-20

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies- heavy-liquid cylconing, selective agglomeration, and advanced froth flotation through the proof-of- concept (POC) level. The commercially available ASPEN PLUS process simulation package will be extended to handle coal applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology, Inc. (ApsenTech), its contractor, ICF Kaiser Engineers, Inc., (ICF KE) and CQ Inc., a subcontractor to ICF KE, for the seventh quarterly reporting period, April through June 1991. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models.

  2. Advanced System for Process Engineering

    SciTech Connect

    Williams, K. E.; Saus, L. S.; Regenhardt, P. A.

    1992-02-01

    ASPEN (Advanced System for Process Engineering) is a state of the art process simulator and economic evaluation package which was designed for use in engineering fossil energy conversion processes. ASPEN can represent multiphase streams including solids, and handle complex substances such as coal. The system can perform steady state material and energy balances, determine equipment size and cost, and carry out preliminary economic evaluations. It is supported by a comprehensive physical property system for computation of major properties such as enthalpy, entropy, free energy, molar volume, equilibrium ratio, fugacity coefficient, viscosity, thermal conductivity, and diffusion coefficient for specified phase conditions; vapor, liquid, or solid. The properties may be computed for pure components, mixtures, or components in a mixture, as appropriate. The ASPEN Input Language is oriented towards process engineers.

  3. EXXON donor solvent coal liquefaction process

    NASA Technical Reports Server (NTRS)

    Epperly, W. R.; Swabb, L. E., Jr.; Tauton, J. W.

    1978-01-01

    A solvent coal liquefaction process to produce low-sulfur liquid products from a wide range of coals is described. An integrated program of laboratory and engineering research and development in conjunction with operation of a 250 T/D pilot plant is discussed.

  4. Advanced liquefaction using coal swelling and catalyst dispersion techniques

    SciTech Connect

    Curtis, C.W. ); Gutterman, C. ); Chander, S. )

    1991-01-01

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Work has centered upon obtaining bulk samples of feedstocks for the project, up-dating the background literature, and preparing and testing a computer program to perform material balance calculations for the continuous flow liquefaction unit.

  5. Coal treatment process and apparatus therefor

    SciTech Connect

    Getsoian, J.A.

    1991-12-31

    This patent describes a process for obtaining product coal agglomerates. It comprises mixing an aqueous slurry of finely divided coal particles and particles of pyrites and other mineral matter with an organic, water-insoluble, steam-strippable, bridging liquid selected from the group consisting of aliphatic saturated hydrocarbons having from 5 to 9 carbon atoms and mixtures thereof, under high shear conditions effective to wet the coal particles with the bridging liquid and convert same into microagglomerates, then mixing the aqueous slurry of the microagglomerates of coal and the particles of pyrites and other mineral matters together with an organic, water-insoluble binder comprising asphalt and the bridging liquid, under low shear conditions effective to agglomerate the microagglomerates to form product coal agglomerates, then separating water and the particles of pyrites and other mineral matter from the product coal agglomerates, then heating the product coal agglomerates and thereby evaporating and removing the bridging liquid from the product coal agglomerates, and then recovering the product coal agglomerates substantially free of the bridging liquid.

  6. Testing of FMI's Coal Upgrading Process

    SciTech Connect

    Vijay Sethi

    2009-03-21

    WRI and FMI have collaborated to develop and test a novel coal upgrading technology. Proprietary coal upgrading technology is a fluidized bed-based continuous process which allows high through-puts, reducing the coal processing costs. Processing is carried out under controlled oxidizing conditions at mild enough conditions that compared to other coal upgrading technologies; the produced water is not as difficult to treat. All the energy required for coal drying and upgrading is derived from the coal itself. Under the auspices of the Jointly Sponsored Research Program, Cooperative Agreement DE-FC26-98FT40323, a nominal 400 lbs/hour PDU was constructed and operated. Over the course of this project, several low-rank coals were successfully tested in the PDU. In all cases, a higher Btu, low moisture content, stable product was produced and subsequently analyzed. Stack emissions were monitored and produced water samples were analyzed. Product stability was established by performing moisture readsorption testing. Product pyrophobicity was demonstrated by instrumenting a coal pile.

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  8. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    SciTech Connect

    K. Osseo-Asare; X. Zeng

    2002-01-01

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  9. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect

    Meyer, Howard

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy's Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  10. ADVANCED SOLIDS NMR STUDIES OF COAL STRUCTURE AND CHEMISTRY

    SciTech Connect

    1997-09-01

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utilization of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. The main activity during this granting period was a completion of a detailed comparative analysis of the suite of spectral editing techniques developed in our laboratory for this purpose. The appended report is a manuscript being submitted to the Journal of Magnetic Resonance on this subject.

  11. Advanced coal technologies in Czech heat and power systems

    SciTech Connect

    Noskievic, P.; Ochodek, T.

    1998-04-01

    Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently necessary steps in making coal utilisation more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. Preparatory steps have been taken in building an advanced combustion unit fuelled by pulverised coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper then coal) do not oblige to increase efficiency of the standing equipment applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalisation of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in near future.

  12. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F.; Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C.; Hu, W.; Zou, Y.; Chen, W.; Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R.

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  13. Advances in Process Control.

    ERIC Educational Resources Information Center

    Morrison, David L.; And Others

    1982-01-01

    Advances in electronics and computer science have enabled industries (pulp/paper, iron/steel, petroleum/chemical) to attain better control of their processes with resulting increases in quality, productivity, profitability, and compliance with government regulations. (JN)

  14. Field study for disposal of solid wastes from Advanced Coal Processes: Ohio LIMB Site Assessment. Final report, April 1986--November 1994

    SciTech Connect

    Weinberg, A.; Coel, B.J.; Butler, R.D.

    1994-10-01

    New air pollution regulations will require cleaner, more efficient processes for converting coal to electricity, producing solid byproducts or wastes that differ from conventional pulverized-coal combustion ash. Large scale landfill test cells containing byproducts were built at 3 sites and are to be monitored over at least 3 years. This report presents results of a 3-y field test at an ash disposal site in northern Ohio; the field test used ash from a combined lime injection-multistage burner (LIMB) retrofit at the Ohio Edison Edgewater plant. The landfill test cells used LIMB ash wetted only to control dusting in one cell, and LIMB ash wetted to optimize compaction density in the other cell. Both test cells had adequate load-bearing strength for landfill stability but had continuing dimensional instability. Heaving and expansion did not affect the landfill stability but probably contributed to greater permeability to infiltrating water. Leachate migration occurred from the base, but effects on downgradient groundwater were limited to increased chloride concentration in one well. Compressive strength of landfilled ash was adequate to support equipment, although permeability was higher and strength was lower than anticipated. Average moisture content has increased to about 90% (dry weight basis). Significant water infiltration has occurred; the model suggests that as much as 20% of the incident rainfall will pass through and exit as leachate. However, impacts on shallow ground water is minimal. Results of this field study suggest that LIMB ash from combustion of moderate to high sulfur coals will perform acceptably if engineering controls are used to condition and compact the materials, reduce water influx to the landfill, and minimize leachate production. Handling of the ash did not pose serious problems during cell construction; steaming and heat buildup were moderate.

  15. Carbon cycle in advanced coal chemical engineering.

    PubMed

    Yi, Qun; Li, Wenying; Feng, Jie; Xie, Kechang

    2015-08-07

    This review summarizes how the carbon cycle occurs and how to reduce CO2 emissions in highly efficient carbon utilization from the most abundant carbon source, coal. Nowadays, more and more attention has been paid to CO2 emissions and its myriad of sources. Much research has been undertaken on fossil energy and renewable energy and current existing problems, challenges and opportunities in controlling and reducing CO2 emission with technologies of CO2 capture, utilization, and storage. The coal chemical industry is a crucial area in the (CO2 value chain) Carbon Cycle. The realization of clean and effective conversion of coal resources, improving the utilization and efficiency of resources, whilst reducing CO2 emissions is a key area for further development and investigation by the coal chemical industry. Under a weak carbon mitigation policy, the value and price of products from coal conversion are suggested in the carbon cycle.

  16. ADVANCED SOLIDS NMR STUDIES OF COAL STRUCTURE AND CHEMISTRY

    SciTech Connect

    1997-03-01

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utilization of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. Our goals are twofold. First, we are interested in developing new methods that will enable us to measure important structural parameters in whole coals not directly accessible by other techniques. In parallel with these efforts we will apply these NMR methods in a study of the chemical differences between gas-sourcing and oil-sourcing coals. The NMR methods work will specifically focus on determination of the number and types of methylene groups, determination of the number and types of methane groups, identification of carbons adjacent to nitrogen and sites with exchangeable protons, and methods to more finely characterize the distribution of hydrogen in coals. The motivation for investigating these specific structural features of coals arises from their relevance to the chemical reactivity of coals, and their suitability for possible correlations with the oil sourcing potential of some types of coals. The coals to be studied and contrasted include oil-prone coals from Australia and Indonesia, those comprising the Argonne Premium Coal Sample bank, and other relevant samples. In this report period we have focused our work on 1 segment of the program. Our last report outlined progress in using our NMR editing methods with higher field operation where higher magic angle spinning rates are required. Significant difficulties were identified, and these have been the main subject of study during the most recent granting period.

  17. Coal Research

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Coal slurries are "clean" pulverized coal mixed with oil or water. Significant fuel savings can be realized when using coal slurries. Advanced Fuels Technology (AFT) utilized a COSMIC program, (Calculation of Complex Chemical Equilibrium Compositions), which provides specific capabilities for determining combustion products. The company has developed a cleaning process that removes much of the mineral sulphur and ash from the coals.

  18. Thermodynamic analysis of coal gasification processes

    NASA Astrophysics Data System (ADS)

    Singh, S. P.; Weil, S. A.; Babu, S. P.

    1980-09-01

    Thermodynamic analysis for evaluating and improving coal gasification process efficiency requires estimation of enthalpy, entropy, and availability transformations in various process steps. A compilation of procedures and data relevant to coal gasification processes is presented for calculating the above thermodynamic properties. Enthalpy and availability transformations are estimated for significant process steps in the HYGAS process for producing substitute natural gas from coal. The thermal efficiencies based on the first law of thermodynamics are compared with the availability efficiencies based on the second law. Work intensive process steps, such as gas compression and separation, are shown to have extremely low thermal efficiencies and fairly high availability efficiencies. Heat intensive process steps, such as steam generation, have high thermal efficiencies but generally poor availability efficiencies.

  19. Catalysts for coal liquefaction processes

    DOEpatents

    Garg, D.

    1986-10-14

    Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

  20. Catalysts for coal liquefaction processes

    DOEpatents

    Garg, Diwakar

    1986-01-01

    Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

  1. Evaluation, engineering and development of advanced cyclone processes

    SciTech Connect

    Durney, T.E.; Cook, A.; Ferris, D.D.

    1995-11-01

    This research and development project is one of three seeking to develop advanced, cost-effective, coal cleaning processes to help industry comply with 1990 Clean Air Act Regulations. The specific goal for this project is to develop a cycloning technology that will beneficiate coal to a level approaching 85% pyritic sulfur rejection while retaining 85% of the parent coal`s heating value. A clean coal ash content of less than 6% and a moisture content, for both clean coal and reject, of less than 30% are targeted. The process under development is a physical, gravimetric-based cleaning system that removes ash bearing mineral matter and pyritic sulfur. Since a large portion of the Nation`s coal reserves contain significant amounts of pyrite, physical beneficiation is viewed as a potential near-term, cost effective means of producing an environmentally acceptable fuel.

  2. Air-Sparged Hydrocyclone/Advanced Froth Flotation fine coal cleaning

    SciTech Connect

    Shirey, G.A.; Stoessner, R.D.; Pennsylvania Electric Co., Johnstown, PA )

    1988-12-30

    The objective of the project is to evaluate the Air-Sparged Hydrocyclone (ASH) and Advanced Froth Flotation (AFF) procedures for their effectiveness in cleaning fine (minus 100 mesh) coal. The two processes will be tested in a circuit capable of processing 0.124 to 0.15 tons per hour of coal at the EPRI-CQDC. Performance of the two processes will be evaluated, and the economics of fine coal cleaning by both processes will be determined. During the past quarter, efforts were concentrated on the following tasks: installation of process equipment and characterization of the test feed coal; start-up of the ASH and AFF circuits; and initialization of the AFF Test Program. 4 figs., 7 tabs.

  3. Resource targets for advanced underground coal extraction systems

    NASA Technical Reports Server (NTRS)

    Hoag, J. H.; Whipple, D. W.; Habib-Agahi, H.; Lavin, M. L.

    1982-01-01

    Resource targets appropriate for federal sponsorship of research and development of advanced underground coal mining systems are identified. A comprehensive examination of conventional and unconventional coals with particular attention to exceptionally thin and thick seams, steeply dipping beds, and multiple seam geometry was made. The results indicate that the resource of primary importance is flat lying bituminous coal of moderate thickness, under moderate cover, and located within the lower 48 states. Resources of secondary importance are the flat lying multiple seams and thin seams (especially those in Appalachia). Steeply dipping coals, abandoned pillars, and exceptionally thick western coals may be important in some regions of subregions, but the limited tonnage available places them in a position of tertiary importance.

  4. Advanced coal gasifier-fuel cell power plant systems design

    NASA Technical Reports Server (NTRS)

    Heller, M. E.

    1983-01-01

    Two advanced, high efficiency coal-fired power plants were designed, one utilizing a phosphoric acid fuel cell and one utilizing a molten carbonate fuel cell. Both incorporate a TRW Catalytic Hydrogen Process gasifier and regenerator. Both plants operate without an oxygen plant and without requiring water feed; they, instead, require makeup dolomite. Neither plant requires a shift converter; neither plant has heat exchangers operating above 1250 F. Both plants have attractive efficiencies and costs. While the molten carbonate version has a higher (52%) efficiency than the phosphoric acid version (48%), it also has a higher ($0.078/kWh versus $0.072/kWh) ten-year levelized cost of electricity. The phosphoric acid fuel cell power plant is probably feasible to build in the near term: questions about the TRW process need to be answered experimentally, such as weather it can operate on caking coals, and how effective the catalyzed carbon-dioxide acceptor will be at pilot scale, both in removing carbon dioxide and in removing sulfur from the gasifier.

  5. Respirable coal mine dust sample processing

    SciTech Connect

    Raymond, L.D.; Tomb, T.F.; Parobeck, P.S.

    1987-01-01

    The Federal Coal Mine Health and Safety Act of 1969 established mandatory dust standards for coal mines. Regulatory requirements for complying with the provisions of the Act were prescribed in Title 30, Code of Federal Regulations, Parts 70 and 71, which were published in the Federal Register on April 3, 1970, and March 28, 1972, respectively. These standard and sampling requirements of coal mine operators, along with a description of the laboratory which was established to process respirable coal mine dust samples collected in accordance with these requirements, were published in MESA Informational Report (MESA, the acronym for the Mining Enforcement and Safety Administration, was changed to MSHA, the acronym for the Mine Safety and Health Administration, in 1977). These standards and regulatory requirements continued under the Federal Mine Safety and Health Act of 1977 until November 1980, when major regulatory revisions were made in the operator's dust sampling program. This paper describes the changes in the respirable coal mine dust sampling program and the equipment and procedures used by MSHA to process respirable coal mine dust samples collected in accordance with regulatory requirements. 10 figs., 1 tab.

  6. A moving baseline for evaluation of advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Bickerton, C. R.; Westerfield, M. D.

    1981-01-01

    Results from the initial effort to establish baseline economic performance comparators for a program whose intent is to define, develop, and demonstrate advanced systems suitable for coal resource extraction beyond the year 2000 are reported. Systems used were selected from contemporary coal mining technology and from conservation conjectures of year 2000 technology. The analysis was also based on a seam thickness of 6 ft. Therefore, the results are specific to the study systems and the selected seam extended to other seam thicknesses.

  7. Coal and char studies by advanced EMR techniques

    SciTech Connect

    Belford, R.L.; Clarkson, R.B.; Odintsov, B.M.

    1999-03-31

    Advanced magnetic resonance (EMR) methods are used to examine properties of coals, chars, and molecular species related to constituents of coal. During this grant period, further progress was made on proton NMR and low-frequency dynamic nuclear polarization (DNP) to examine the interaction between fluids such as water and the surface of suspended char particles. Effects of char particle size and type on water nuclear spin relaxation, T2, were measured and modeled.

  8. Coal and char studies by advanced EMR techniques

    SciTech Connect

    Belford, R.L.; Clarkson, R.B.; Odintsov, B.M.

    1998-09-30

    Advanced magnetic resonance (EMR) methods are used to examine properties of coals, chars, and molecular species related to constituents of coal. During this grant period, further progress was made on proton NMR and low-frequency dynamic nuclear polarization (DNP) to examine the interaction between fluids such as water and the surface of suspended char particles. Effects of char particle size on water nuclear spin relaxation, T2, were measured.

  9. Advanced liquefaction using coal swelling and catalyst dispersion techniques

    SciTech Connect

    Curtis, C.W. ); Gutterman, C. ); Chander, S. )

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  10. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    SciTech Connect

    1988-02-01

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  11. Coal enhancement process and equipment

    SciTech Connect

    Nankee, R.J.; Vivan, T.A.

    1986-04-01

    This patent describes a method for treating coal by the heavy media technique wherein the float and sink solids each individually are recovered and freed of liquid then dried to remove the residual heavy media retained thereon. The improvement consists of treating each solids portion with hot water at the temperature of from the heavy medium water azeotroping point to the boiling point of water for a time sufficient to remove a substantial portion of the heavy media or until the water comes off at its boiling point and thereafter separates the solids from the water.

  12. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect

    Not Available

    1981-03-31

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  13. Overview of coal conversion process instrumentation

    SciTech Connect

    Liptak, B. G.; Leiter, C. P.

    1980-05-01

    A review of standard instrumentation used in the processing industries is given, and the applicability of this instrumentation to measurements in mixed phase media and hostile environments such as those encountered in coal conversion processes is considered. The major projects in coal conversion sponsored by the US Department of Energy are briefly reviewed with schematics to pinpoint areas where the standard instrumentation is inadequate or altogether lacking. The next report in this series will provide detailed requirements on the instruments needed for these processes, will review new instruments which have recently become commercially available but are not yet considered standard instrumentation, and report on the status of new instruments which are being developed and, in some cases, undergoing tests in coal conversion plants.

  14. Process for coal liquefaction in staged dissolvers

    DOEpatents

    Roberts, George W.; Givens, Edwin N.; Skinner, Ronald W.

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a pasting oil, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. In accordance with the improved process, the first dissolver is operated at a higher temperature than the second dissolver. This temperature sequence produces improved product selectivity and permits the incorporation of sufficient hydrogen in the solvent for adequate recycle operations.

  15. Advanced Polymer Processing Facility

    SciTech Connect

    Muenchausen, Ross E.

    2012-07-25

    Some conclusions of this presentation are: (1) Radiation-assisted nanotechnology applications will continue to grow; (2) The APPF will provide a unique focus for radiolytic processing of nanomaterials in support of DOE-DP, other DOE and advanced manufacturing initiatives; (3) {gamma}, X-ray, e-beam and ion beam processing will increasingly be applied for 'green' manufacturing of nanomaterials and nanocomposites; and (4) Biomedical science and engineering may ultimately be the biggest application area for radiation-assisted nanotechnology development.

  16. Advanced coal technologies in Czech heat and power systems

    SciTech Connect

    Noskievic, P. Ochodek, T.

    1998-07-01

    Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently, necessary steps in making coal utilization more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. preparatory steps have been taken in building an advanced combustion unit fueled by pulverized coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper than coal) do not result in an increased efficiency of the standing equipment by applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalization of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in the near future.

  17. Advanced physical fine coal cleaning spherical agglomeration. Final report

    SciTech Connect

    Not Available

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  18. Advanced direct coal liquefaction concepts. Final report, Volume 2

    SciTech Connect

    Berger, D.J.; Parker, R.J.; Simpson, P.L.

    1994-07-01

    Integration of innovative steps into new advanced processes have the potential to reduce costs for producing liquid fuels. In this program, objective is to develop a new approach to liquefaction that generates an all distillate product slate at a reduced cost of about US$25/barrel of crude oil equivalent. A Counterflow Reactor was developed in cooperation with GfK mbH, Germany. Advantages are low hydrogen recycle rates and low feed preheating requirements. Coal/heavy oil slurry is injected into the top of the reactor while the recycle gas and make up hydrogen is introduced into the bottom; hydrogenation products are withdrawn from the top. PU study resulted in distillable oil yields up to 74 wt % on feed (dry ash free) from coprocessing feed slurries containing 40 wt % Vesta subbituminous coal and 60 wt % Cold Lake heavy vacuum tower bottoms. Technologies developed separately by CED and ARC were combined. A 1-kg/hr integrated continuous flow bench scale unit was constructed at the ARC site in Devon, Alberta, based on modifications to a unit at Nisku, Alberta (the modified unit was used in the preliminary economic evaluation).

  19. Coal-to-Liquids Process Model

    SciTech Connect

    2006-01-01

    A comprehensive Aspen Plus model has been developed to rigorously model coal-to-liquids processes. This portion was developed under Laboratory Directed Research and Development (LDRD) funding. The model is built in a modular fashion to allow rapid reconfiguration for evaluation of process options. Aspen Plus is the framework in which the model is developed. The coal-to-liquids simulation package is an assemble of Aspen Hierarchy Blocks representing subsections of the plant. Each of these Blocks are considered individual components of the Copyright, which may be extracted and licensed as individual components, but which may be combined with one or more other components, to model general coal-conversion processes, including the following plant operations: (1) coal handling and preparation, (2) coal pyrolysis, combustion, or gasification, (3) syngas conditioning and cleanup, (4) sulfur recovery using Claus-SCOT unit operations, (5) Fischer-Tropsch liquid fuels synthesis, (6) hydrocracking of high molecular weight paraffin, (7) hydrotreating of low molecular weight paraffin and olefins, (8) gas separations, and (9) power generation representing integrated combined cycle technology.

  20. Coal preparation process using true-heavy-liquid separation

    SciTech Connect

    Baltich, L.K.; Malhotra, D.

    1990-12-20

    The Pittsburgh Energy Technology Center (PETC) is supporting work to develop advanced fine-coal cleaning processes including the exploitation of differences in specific gravity through the use of heavy-liquid media in hydrocyclones. The true-heavy-liquid media used for this program are solutions of sulfuric acid (H{sub 2}SO{sub 4}) and water. This concept takes advantage of the miscibility of the acid water to produce a range of heavy liquids up to a specific gravity of 1.84 for pure sulfuric acid. The main objective of this research program was to develop a true-heavy-liquid separation process to clean ultrafine coal using smelter-guide sulfuric acid. Three bituminous coals and one subbituminous coal were selected for testing. In general, single-stage true-heavy-liquid hydrocyclone process demonstrated similar performance characteristics to heavy-media separation processes under study by other investigators. True-heavy-liquid media has the advantage of allowing additional separation steps at other specific gravities for cleaning and scavenging without the introduction of another heavy liquid to the flowsheet. In addition, sulfuric acid is inorganic and can be neutralized and disposed of without the toxicity problems associated with the other type of heavy liquids under consideration. Preliminary economics analysis indicates that the cost for sulfuric acid makeup to the process may be prohibitive. 4 refs., 11 figs., 61 tabs.

  1. Advancing apparatus for coal-mining machine in underground mine

    SciTech Connect

    Schupphaus, H.

    1984-05-29

    A coal-mining machine is advanced along a face conveyor by providing a rack extending along the conveyor and a plurality of advancing units. Each advancing unit includes a hydraulic motor to rotate a drive wheel while meshing with the teeth of the gear rack. The advancing units arranged side-by-side along the mining machine have curved end faces to abut against one another. Runners are provided on the advancing units at the opposite ends of the mining machine which extend partially around the rack for guiding and maintaining the drive wheel engaged with the teeth of the rack.

  2. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    a study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This document is the eighth quarterly report prepared in accordance with the project reporting requirements covering the period from July 1,1990 to September 30, 1990. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. The data from the basic research on coal surfaces, bench scale testing and proof-of-concept scale testing will be utilized to design a final conceptual flowsheet. The economics of the flowsheet will be determined to enable industry to assess the feasibility of incorporating the advanced fine coal cleaning technology into the production of clean coal for generating electricity. 22 figs., 11 tabs.

  3. Organic coal-water fuel: Problems and advances (Review)

    NASA Astrophysics Data System (ADS)

    Glushkov, D. O.; Strizhak, P. A.; Chernetskii, M. Yu.

    2016-10-01

    The study results of ignition of organic coal-water fuel (OCWF) compositions were considered. The main problems associated with investigation of these processes were identified. Historical perspectives of the development of coal-water composite fuel technologies in Russia and worldwide are presented. The advantages of the OCWF use as a power-plant fuel in comparison with the common coal-water fuels (CWF) were emphasized. The factors (component ratio, grinding degree of solid (coal) component, limiting temperature of oxidizer, properties of liquid and solid components, procedure and time of suspension preparation, etc.) affecting inertia and stability of the ignition processes of suspensions based on the products of coaland oil processing (coals of various types and metamorphism degree, filter cakes, waste motor, transformer, and turbine oils, water-oil emulsions, fuel-oil, etc.) were analyzed. The promising directions for the development of modern notions on the OCWF ignition processes were determined. The main reasons limiting active application of the OCWF in power generation were identified. Characteristics of ignition and combustion of coal-water and organic coal-water slurry fuels were compared. The effect of water in the composite coal fuels on the energy characteristics of their ignition and combustion, as well as ecological features of these processes, were elucidated. The current problems associated with pulverization of composite coal fuels in power plants, as well as the effect of characteristics of the pulverization process on the combustion parameters of fuel, were considered. The problems hindering the development of models of ignition and combustion of OCWF were analyzed. It was established that the main one was the lack of reliable experimental data on the processes of heating, evaporation, ignition, and combustion of OCWF droplets. It was concluded that the use of high-speed video recording systems and low-inertia sensors of temperature and gas

  4. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Mitchell, G.; Davis, A. . Energy and Fuels Research Center); Burke, F.P.; Winschel, R.A.; Brandes, S.D. . Energy and Fuels Research Center)

    1991-12-01

    This study demonstrated the use of the gold tube carbonization technique and reflectance microscopy analysis for the examination of process-derived materials from direct coal liquefaction. The carbonization technique, which was applied to coal liquefaction distillation resids, yields information on the amounts of gas plus distillate, pyridine-soluble resid, and pyridine-insoluble material formed when a coal liquid sample is heated to 450{degree}C for one hour at 5000 psi in an inert atmosphere. The pyridine-insolubles then are examined by reflectance microscopy to determine the type, amount, and optical texture of isotropic and anisotropic carbon formed upon carbonization. Further development of these analytical methods as process development tools may be justified on the basis of these results.

  5. Supercritical fluid thermodynamics for coal processing

    SciTech Connect

    van Swol, F. . Dept. of Chemical Engineering); Eckert, C.A. . School of Chemical Engineering)

    1990-01-01

    Because of their unusual solvating and mass transfer properties, supercritical fluids show potential for a variety of coal processing applications. We have established a database of coal model compound equilibria; to add to this database, we have developed and are testing methods of rapidly measuring cosolvent effects on solubility. In addition, we have used fluorescence spectroscopy to study the nature of cosolvent effects on molecular level. The solubility and spectroscopic measurements are being used to guide the development of an equation of state that includes both physical and chemical interactions. The equation of state will be used to predict solubility behavior to systems can be designed for the processing of coal with supercritical fluids. 8 figs.

  6. Engineering design and analysis of advanced physical fine coal cleaning technologies

    SciTech Connect

    Gallier, P.W.

    1990-10-20

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cycloning, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level. The ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. The work plan for the froth quarter called for completion of the washability interpolation routine, gravity separation models, and dewatering models. As these items were completed, work in the areas of size reduction, classification and froth flotation were scheduled to begin. As each model was completed, testing and validation procedures were scheduled to begin. Costing models were also planned to be implemented and tested as each of the gravity separation models were completed. 1 tab.

  7. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications

    SciTech Connect

    Smit, Frank J; Schields, Gene L; Jha, Mehesh C; Moro, Nick

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel™ column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications.

  8. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  9. Process for preparing a stabilized coal-water slurry

    DOEpatents

    Givens, Edwin N.; Kang, Doohee

    1987-01-01

    A process for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases.

  10. Process for preparing a stabilized coal-water slurry

    DOEpatents

    Givens, E.N.; Kang, D.

    1987-06-23

    A process is described for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases. 2 figs.

  11. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1992-04-24

    No combustion tests for this program were conducted during this reporting period of January 1 to March 31, 1992. DOE-sponsored slogging combustor tests have been suspended since December 1991 in order to perform combustion tests on Northern States Power Company (NSP) coals. The NSP coal tests were conducted to evaluate combustor performance when burning western sub bituminous coals. The results of these tests will guide commercialization efforts, which are being promoted by NSP, Westinghouse Electric, and Textron Defense Systems. The NSP testing has been completed and preparation of the final report for that effort is underway. Although the NSP testing program has been completed, the Westinghouse/DOE program will not be resumed immediately. The reason for this is that Textron Defense Systems (TDS) has embarked on an internally funded program requiring installation of a new liquid fuel combustor system at the Haverhill site. The facility modifications for this new system are significant and it is not possible to continue the Westinghouse/DOE testing while these modifications are being made. These facility modifications are being performed during the period February 15, 1992 through May 31, 1992. The Westinghouse/DOE program can be resumed upon completion of this work.

  12. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1991-09-01

    The combustion system discussed here incorporates a modular three- stage slagging combustor concept. Fuel-rich conditions inhibit NO{sub x} formation from fuel nitrogen in the first stage; also in the first stage, sulfur is captured with sorbent; coal ash and sulfated sorbent are removed from the combustion gases by inertial means in the second stage by the use of an impact separator and slagging cyclone separator in series. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The objective of this contract is to establish the technology required for subsequent commercial development and application by the private sector of utility-size direct coal-fueled gas turbines. Emissions from these units are to meet or be lower than the Environment Protection Agency's (EPA's) New Source Performance Standards (NSPS) for a pulverized coal-=fired steam turbine generator plant.

  13. Process for separating anthracite coal from impurities

    SciTech Connect

    Stiller, D.W.; Stiller, A.H.

    1985-05-06

    A process is described for separating a first mixture including previously mined anthracite coal, klinker-type cinder ash and other refuse consisting of: a. separating the first mixture to produce a refuse portion and a second mixture consisting of anthracite and klinker-type cinder ash, b. reducing the average particle size in the second mixture to a uniform size, c. subjecting the second mixture to a separating magnetic field to produce a klinker-type cinder ash portion and an anthracite coal portion.

  14. Fired heater for coal liquefaction process

    DOEpatents

    Ying, David H. S.

    1984-01-01

    A fired heater for a coal liquefaction process is constructed with a heat transfer tube having U-bends at regular intervals along the length thereof to increase the slug frequency of the multi-phase mixture flowing therethrough to thereby improve the heat transfer efficiency.

  15. Process and apparatus for coal hydrogenation

    DOEpatents

    Ruether, John A.

    1988-01-01

    In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture of agglomerates, excess water, dissolved catalyst, and unagglomerated solids is pumped to reaction pressure and then passed through a drainage device where all but a small amount of surface water is removed from the agglomerates. Sufficient catalyst for the reaction is contained in surface water remaining on the agglomerates. The agglomerates fall into the liquefaction reactor countercurrently to a stream of hot gas which is utilized to dry and preheat the agglomerates as well as deposit catalyst on the agglomerates before they enter the reactor where they are converted to primarily liquid products under hydrogen pressure.

  16. Process and apparatus for coal hydrogenation

    DOEpatents

    Ruether, John A.; Simpson, Theodore B.

    1991-01-01

    In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture is drained of excess water and dried at atmospheric pressure leaving catalyst deposited on the agglomerates. The agglomerates then are fed to an extrusion device where they are formed into a continuous ribbon of extrudate and fed into a hydrogenation reactor at elevated pressure and temperature. The catalytic hydrogenation converts the extrudate primarily to liquid hydrocarbons in the reactor. The liquid drained in recovering the agglomerates is recycled.

  17. Controlled short residence time coal liquefaction process

    DOEpatents

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-05-04

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -455.degree. C. is an amount at least equal to that obtainable by performing the process under the same conditions except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent.

  18. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    1998-09-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean-coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 30, 1997.

  19. Advanced cases of coal workers' pneumoconiosis--two counties, Virginia, 2006.

    PubMed

    2006-08-25

    This report describes 11 newly identified cases of advanced coal workers' pneumoconiosis (CWP), including progressive massive fibrosis (PMF), in working coal miners from Lee and Wise counties in southwestern Virginia. PMF is a disabling and potentially fatal form of CWP, an occupational lung disease caused by the inhalation of coal mine dust. The continuing occurrence of advanced forms of CWP emphasizes the importance of comprehensive measures to control coal mine dust effectively and reduce the potential for inhalation exposures in coal mining.

  20. Performance and economics of advanced energy conversion systems for coal and coal-derived fuels

    NASA Technical Reports Server (NTRS)

    Corman, J. C.; Fox, G. R.

    1978-01-01

    The desire to establish an efficient Energy Conversion System to utilize the fossil fuel of the future - coal - has produced many candidate systems. A comparative technical/economic evaluation was performed on the seven most attractive advanced energy conversion systems. The evaluation maintains a cycle-to-cycle consistency in both performance and economic projections. The technical information base can be employed to make program decisions regarding the most attractive concept. A reference steam power plant was analyzed to the same detail and, under the same ground rules, was used as a comparison base. The power plants were all designed to utilize coal or coal-derived fuels and were targeted to meet an environmental standard. The systems evaluated were two advanced steam systems, a potassium topping cycle, a closed cycle helium system, two open cycle gas turbine combined cycles, and an open cycle MHD system.

  1. Prospects for advanced coal-fuelled fuel cell power plants

    NASA Astrophysics Data System (ADS)

    Jansen, D.; Vanderlaag, P. C.; Oudhuis, A. B. J.; Ribberink, J. S.

    1994-04-01

    As part of ECN's in-house R&D programs on clean energy conversion systems with high efficiencies and low emissions, system assessment studies have been carried out on coal gasification power plants integrated with high-temperature fuel cells (IGFC). The studies also included the potential to reduce CO2 emissions, and to find possible ways for CO2 extraction and sequestration. The development of this new type of clean coal technology for large-scale power generation is still far off. A significant market share is not envisaged before the year 2015. To assess the future market potential of coal-fueled fuel cell power plants, the promise of this fuel cell technology was assessed against the performance and the development of current state-of-the-art large-scale power generation systems, namely the pulverized coal-fired power plants and the integrated coal gasification combined cycle (IGCC) power plants. With the anticipated progress in gas turbine and gas clean-up technology, coal-fueled fuel cell power plants will have to face severe competition from advanced IGCC power plants, despite their higher efficiency.

  2. Regional price targets appropriate for advanced coal extraction

    NASA Technical Reports Server (NTRS)

    Terasawa, K. L.; Whipple, D. M.

    1980-01-01

    A methodology is presented for predicting coal prices in regional markets for the target time frames 1985 and 2000 that could subsequently be used to guide the development of an advanced coal extraction system. The model constructed is a supply and demand model that focuses on underground mining since the advanced technology is expected to be developed for these reserves by the target years. Coal reserve data and the cost of operating a mine are used to obtain the minimum acceptable selling price that would induce the producer to bring the mine into production. Based on this information, market supply curves can be generated. Demand by region is calculated based on an EEA methodology that emphasizes demand by electric utilities and demand by industry. The demand and supply curves are then used to obtain the price targets. The results show a growth in the size of the markets for compliance and low sulphur coal regions. A significant rise in the real price of coal is not expected even by the year 2000. The model predicts heavy reliance on mines with thick seams, larger block size and deep overburden.

  3. Advanced burner technology for low volatile coal and anthracite

    SciTech Connect

    Tigges, K.D.; Streffing, M.; Lisauskas, R.; Ake, T.

    1997-12-31

    Today China is one of the countries with the highest coal production. Approximately three quarters of the produced coal is high-volatile and medium-volatile hard coal and only about 20% is anthracite. However the actual portion of the anthracite used in power plants is even lower. The reason for this is not due to the low amount available, but to the difficulty of ensuring stable and reliable ignition and combustion of anthracite. Up to now, the so-called Downshot firing system has been used to fire difficult anthracite coals. The experience gained with this type of firing system is, however, far from satisfactory. The numerous difficulties in the plants of all manufactures have shown that attempts should be made to develop efficient burners to be able to use the simple, service-proved and reliable opposed-burner system. Deutsche Babcock started this work in the early 1980`s and developed a second generation low-NOx burner -- the DS burner -- which is also well suited for the combustion of anthracite. The development is based on state-of-the-art advanced computer simulation and full-scale combustion tests on a wide range of coals. Performance has been evaluated on coals with volatile matter content ranging from 50% down to as low as 5%. DS burners are characterized by extremely reliable and stable ignition which allows operation at low part loads even when firing difficult coal. The excellent flame stability of this burner is the reason why the complex Downshot firing system with its numerous disadvantages is no longer necessary and opposed burner system may be applied even for firing anthracite. The paper describes the development of the burner for difficult coals and explains the full scale combustion tests, the laboratory tests of the ignitability and compares these results with the computer simulation of the DS burner flame.

  4. Evaluation, engineering and development of advanced cyclone processes

    SciTech Connect

    Not Available

    1991-01-01

    Evaluation, Engineering and Development of Advanced Cyclone Processes'' is a research and development project for the reduction of pyritic sulfur in coal. Project goals are to remove 80 to 90% of the ash and pyritic sulfur while retaining 80 to 90% of the parent coal's heating value. A number of media and media separator options are to be evaluated and tested, culminating with the implementation of the preferred combination in a 1,000 lb/hr bench-scale process optimization circuit.

  5. Advanced Thermally Stable Coal-Based Jet Fuels

    DTIC Science & Technology

    2008-01-01

    electrolysis with power from the nuclear plant, reducing the carbon footprint even further by eliminating the requirement for a coal gasification unit to...following: • Substantially reduced carbon footprint, from elimination of fired process heaters and a coal gasification facility for hydrogen...of ash yield as possible. It was found that the vibratory screening system similar to the system that used in the past was effective in de- sliming

  6. Economic aspects of advanced coal-fired gas turbine locomotives

    NASA Technical Reports Server (NTRS)

    Liddle, S. G.; Bonzo, B. B.; Houser, B. C.

    1983-01-01

    Increases in the price of such conventional fuels as Diesel No. 2, as well as advancements in turbine technology, have prompted the present economic assessment of coal-fired gas turbine locomotive engines. A regenerative open cycle internal combustion gas turbine engine may be used, given the development of ceramic hot section components. Otherwise, an external combustion gas turbine engine appears attractive, since although its thermal efficiency is lower than that of a Diesel engine, its fuel is far less expensive. Attention is given to such a powerplant which will use a fluidized bed coal combustor. A life cycle cost analysis yields figures that are approximately half those typical of present locomotive engines.

  7. ENGINEERING DEVELOPMENT OF ADVANCED PHYSICAL FINE COAL CLEANING FOR PREMIUM FUEL APPLICATIONS

    SciTech Connect

    none,

    1997-06-01

    Bechtel, together with Amax Research and Development Center (Amax R&D), has prepared this study which provides conceptual cost estimates for the production of premium quality coal-water slurry fuel (CWF) in a commercial plant. Two scenarios are presented, one using column flotation technology and the other the selective agglomeration to clean the coal to the required quality specifications. This study forms part of US Department of Energy program "Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications," (Contract No. DE-AC22- 92PC92208), under Task 11, Project Final Report. The primary objective of the Department of Energy program is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to stable and highly loaded CWF. The fuels should contain less than 2 lb ash/MBtu (860 grams ash/GJ) of HHV and preferably less than 1 lb ash/MBtu (430 grams ash/GJ). The advanced fine coal cleaning technologies to be employed are advanced column froth flotation and selective agglomeration. It is further stipulated that operating conditions during the advanced cleaning process should recover not less than 80 percent of the carbon content (heating value) in the run-of-mine source coal. These goals for ultra-clean coal quality are to be met under the constraint that annualized coal production costs does not exceed $2.5 /MBtu ($ 2.37/GJ), including the mine mouth cost of the raw coal. A further objective of the program is to determine the distribution of a selected suite of eleven toxic trace elements between product CWF and the refuse stream of the cleaning processes. Laboratory, bench-scale and Process Development Unit (PDU) tests to evaluate advanced column flotation and selective agglomeration were completed earlier under this program with selected coal samples. A PDU with a capacity of 2 st/h was designed by Bechtel and installed at Amax R

  8. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Campbell, J.A.; Linehan, J.C.; Robins, W.H. )

    1992-07-01

    Under contract from the DOE , and in association with CONSOL Inc., Battelle, Pacific Northwest Laboratory (PNL) evaluated four principal and several complementary techniques for the analysis of non-distillable direct coal liquefaction materials in support of process development. Field desorption mass spectrometry (FDMS) and nuclear magnetic resonance (NMR) spectroscopic methods were examined for potential usefulness as techniques to elucidate the chemical structure of residual (nondistillable) direct coal liquefaction derived materials. Supercritical fluid extraction (SFE) and supercritical fluid chromatography/mass spectrometry (SFC/MS) were evaluated for effectiveness in compound-class separation and identification of residual materials. Liquid chromatography (including microcolumn) separation techniques, gas chromatography/mass spectrometry (GC/MS), mass spectrometry/mass spectrometry (MS/MS), and GC/Fourier transform infrared (FTIR) spectroscopy methods were applied to supercritical fluid extracts. The full report authored by the PNL researchers is presented here. The following assessment briefly highlights the major findings of the project, and evaluates the potential of the methods for application to coal liquefaction materials. These results will be incorporated by CONSOL into a general overview of the application of novel analytical techniques to coal-derived materials at the conclusion of CONSOL's contract.

  9. Two-stage coal liquefaction process

    DOEpatents

    Skinner, Ronald W.; Tao, John C.; Znaimer, Samuel

    1985-01-01

    An improved SRC-I two-stage coal liquefaction process which improves the product slate is provided. Substantially all of the net yield of 650.degree.-850.degree. F. heavy distillate from the LC-Finer is combined with the SRC process solvent, substantially all of the net 400.degree.-650.degree. F. middle distillate from the SRC section is combined with the hydrocracker solvent in the LC-Finer, and the initial boiling point of the SRC process solvent is increased sufficiently high to produce a net yield of 650.degree.-850.degree. F. heavy distillate of zero for the two-stage liquefaction process.

  10. Upgrading low-rank coals using the liquids from coal (LFC) process

    SciTech Connect

    Nickell, R.E.; Hoften, S.A. van

    1993-12-31

    Three unmistakable trends characterize national and international coal markets today that help to explain coal`s continuing and, in some cases, increasing share of the world`s energy mix: the downward trend in coal prices is primarily influenced by an excess of increasing supply relative to increasing demand. Associated with this trend are the availability of capital to expand coal supplies when prices become firm and the role of coal exports in international trade, especially for developing nations; the global trend toward reducing the transportation cost component relative to the market, preserves or enhances the producer`s profit margins in the face of lower prices. The strong influence of transportation costs is due to the geographic relationships between coal producers and coal users. The trend toward upgrading low grade coals, including subbituminous and lignite coals, that have favorable environmental characteristics, such as low sulfur, compensates in some measure for decreasing coal prices and helps to reduce transportation costs. The upgrading of low grade coal includes a variety of precombustion clean coal technologies, such as deep coal cleaning. Also included in this grouping are the coal drying and mild pyrolysis (or mild gasification) technologies that remove most of the moisture and a substantial portion of the volatile matter, including organic sulfur, while producing two or more saleable coproducts with considerable added value. SGI International`s Liquids From Coal (LFC) process falls into this category. In the following sections, the LFC process is described and the coproducts of the mild pyrolysis are characterized. Since the process can be applied widely to low rank coals all around the world, the characteristics of coproducts from three different regions around the Pacific Rim-the Powder River Basin of Wyoming, the Beluga Field in Alaska near the Cook Inlet, and the Bukit Asam region in south Sumatra, Indonesia - are compared.

  11. Process for removing sulfur from coal

    DOEpatents

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  12. Process for removing sulfur from coal

    DOEpatents

    Aida, Tetsuo; Squires, Thomas G.; Venier, Clifford G.

    1985-02-05

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  13. Process for detoxifying coal tars

    DOEpatents

    Longwell, John P.; Peters, William A.

    1983-01-01

    A process for treating liquid hydrocarbons to remove toxic, mutagenic and/or carcinogenic aromatic hydrocarbons comprises feeding the hydrocarbons into a reactor where vapors are thermally treated in contact with a catalyst consisting essentially of calcium oxide or a calcium oxide containing mineral. Thermally treating liquid hydrocarbons in contact with calcium oxide preferentially increases the cracking of aromatics thus producing a product having a reduced amount of aromatic compounds.

  14. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1990-01-01

    An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This is being accomplished by utilization the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. 31 figs., 22 tabs.

  15. Moving baseline for evaluation of advanced coal-extraction systems

    SciTech Connect

    Bickerton, C.R.; Westerfield, M.D.

    1981-04-15

    This document reports results from the initial effort to establish baseline economic performance comparators for a program whose intent is to define, develop, and demonstrate advanced systems suitable for coal resource extraction beyond the year 2000. Systems used in this study were selected from contemporary coal mining technology and from conservative conjectures of year 2000 technology. The analysis was also based on a seam thickness of 6 ft. Therefore, the results are specific to the study systems and the selected seam thickness. To be more beneficial to the program, the effort should be extended to other seam thicknesses. This document is one of a series which describe systems level requirements for advanced underground coal mining equipment. Five areas of performance are discussed: production cost, miner safety, miner health, environmental impact, and recovery efficiency. The projections for cost and production capability comprise a so-called moving baseline which will be used to assess compliance with the systems requirement for production cost. Separate projections were prepared for room and pillar, longwall, and shortwall technology all operating under comparable sets of mining conditions. This work is part of an effort to define and develop innovative coal extraction systems suitable for the significant resources remaining in the year 2000.

  16. Advanced powder processing

    SciTech Connect

    Janney, M.A.

    1997-04-01

    Gelcasting is an advanced powder forming process. It is most commonly used to form ceramic or metal powders into complex, near-net shapes. Turbine rotors, gears, nozzles, and crucibles have been successfully gelcast in silicon nitride, alumina, nickel-based superalloy, and several steels. Gelcasting can also be used to make blanks that can be green machined to near-net shape and then high fired. Green machining has been successfully applied to both ceramic and metal gelcast blanks. Recently, the authors have used gelcasting to make tooling for metal casting applications. Most of the work has centered on H13 tool steel. They have demonstrated an ability to gelcast and sinter H13 to near net shape for metal casting tooling. Also, blanks of H13 have been cast, green machined into complex shape, and fired. Issues associated with forming, binder burnout, and sintering are addressed.

  17. Advanced microwave processing concepts

    SciTech Connect

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.

    1995-05-01

    The purpose of this work is to explore the feasibility of several advanced microwave processing concepts to develop new energy-efficient materials and processes. The project includes two tasks: (1) commercialization of the variable-frequency microwave furnace; and (2) microwave curing of polymer composites. The variable frequency microwave furnace, whose initial conception and design was funded by the AIC Materials Program, will allow us, for the first time, to conduct microwave processing studies over a wide frequency range. This novel design uses a high-power traveling wave tube (TWT) originally developed for electronic warfare. By using this microwave source, one can not only select individual microwave frequencies for particular experiments, but also achieve uniform power densities over a large area by the superposition of many different frequencies. Microwave curing of thermoset resins will be studied because it hold the potential of in-situ curing of continuous-fiber composites for strong, lightweight components. Microwave heating can shorten curing times, provided issues of scaleup, uniformity, and thermal management can be adequately addressed.

  18. Advanced microwave processing concepts

    SciTech Connect

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.

    1997-04-01

    The purpose of this work is to explore the feasibility of several advanced microwave processing concepts to develop new energy-efficient materials and processes. The project includes two tasks: (1) commercialization of the variable-frequency microwave furnace; and (2) microwave curing of polymeric materials. The variable frequency microwave furnace, whose initial conception and design was funded by the AIM Materials Program, allows the authors, for the first time, to conduct microwave processing studies over a wide frequency range. This novel design uses a high-power traveling wave tube (TWT) originally developed for electronic warfare. By using this microwave source, one can not only select individual microwave frequencies for particular experiments, but also achieve uniform power densities over a large area by the superposition of many different frequencies. Microwave curing of various thermoset resins will be studied because it holds the potential of in-situ curing of continuous-fiber composites for strong, lightweight components or in-situ curing of adhesives, including metal-to-metal. Microwave heating can shorten curing times, provided issues of scaleup, uniformity, and thermal management can be adequately addressed.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 1, October--December 1992

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1993-01-18

    This project is a step in the Department of Energy`s program to show that ultra-clean fuel can be produced from selected coals and that the fuel will be a cost-effective replacement for oil and natural gas now fueling boilers in this country. The replacement of premium fossil fuels with coal can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the ultra-clean coal. The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term commercial integration of advanced fine coal cleaning technologies in new or existing coal preparation plants for economically and efficiently processing minus 28-mesh coal fines. A third objective is to determine the distribution of toxic trace elements between clean coal and refuse when applying the advance column flotation and selective agglomeration technologies. The project team consists of Amax Research & Development Center (Amax R&D), Amax Coal industries, Bechtel Corporation, Center for Applied Energy Research (CAER) at the University of Kentucky, and Arcanum Corporation.

  20. Development of the LICADO coal cleaning process

    SciTech Connect

    Not Available

    1990-07-31

    Development of the liquid carbon dioxide process for the cleaning of coal was performed in batch, variable volume (semi-continuous), and continuous tests. Continuous operation at feed rates up to 4.5 kg/hr (10-lb/hr) was achieved with the Continuous System. Coals tested included Upper Freeport, Pittsburgh, Illinois No. 6, and Middle Kittanning seams. Results showed that the ash and pyrite rejections agreed closely with washability data for each coal at the particle size tested (-200 mesh). A 0.91 metric ton (1-ton) per hour Proof-of-Concept Plant was conceptually designed. A 181 metric ton (200 ton) per hour and a 45 metric ton (50 ton) per hour plant were sized sufficiently to estimate costs for economic analyses. The processing costs for the 181 metric ton (200 ton) per hour and 45 metric ton (50 ton) per hour were estimated to be $18.96 per metric ton ($17.20 per ton) and $11.47 per metric ton ($10.40 per ton), respectively for these size plants. The costs for the 45 metric ton per hour plant are lower because it is assumed to be a fines recovery plant which does not require a grinding circuit of complex waste handling system.

  1. Process for producing fluid fuel from coal

    DOEpatents

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  2. Supercritical fluid thermodynamics for coal processing

    SciTech Connect

    van Swol, F. . Dept. of Chemical Engineering); Eckert, C.A. . School of Chemical Engineering)

    1988-09-15

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  3. Evaluation of ADAM/1 model for advanced coal extraction concepts

    NASA Technical Reports Server (NTRS)

    Deshpande, G. K.; Gangal, M. D.

    1982-01-01

    Several existing computer programs for estimating life cycle cost of mining systems were evaluated. A commercially available program, ADAM/1 was found to be satisfactory in relation to the needs of the advanced coal extraction project. Two test cases were run to confirm the ability of the program to handle nonconventional mining equipment and procedures. The results were satisfactory. The model, therefore, is recommended to the project team for evaluation of their conceptual designs.

  4. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation'', to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  5. Advanced turbine design for coal-fueled engines

    SciTech Connect

    Bornstein, N.S.

    1992-07-17

    The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500[degrees]F (815[degrees]C), relatively innocuous salts. In this study it is found that at 1650[degrees]F (900[degrees]C) and above, calcium sulfate becomes an aggressive corrodent.

  6. Advanced turbine design for coal-fueled engines

    NASA Astrophysics Data System (ADS)

    Bornstein, N. S.

    1992-07-01

    The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500 F (815 C), relatively innocuous salts. In this study it is found that at 1650 F (900 C) and above, calcium sulfate becomes an aggressive corrodent.

  7. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOEpatents

    Miller, Robert N.

    1986-01-01

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  8. Process for removing pyritic sulfur from bituminous coals

    DOEpatents

    Pawlak, Wanda; Janiak, Jerzy S.; Turak, Ali A.; Ignasiak, Boleslaw L.

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  9. Air-Sparged Hydrocyclone/Advanced Froth Flotation fine coal cleaning

    SciTech Connect

    Stoessner, R.D. ); Shirey, G.A.; Zawadzki, E.A. ); Welsh, C.F. ); Miller, J.D. ); Shell, W.P. )

    1990-05-27

    In May 1988, the Pennsylvania Electric Company (Penelec) and New York State Electric and Gas Corporation (NYSEG) were awarded a contract from the Department of Energy's Pittsburgh Energy and Technology Center (DOE-PETC) to evaluate the performance of a two-inch Air-Sparged Hydrocyclone (ASH) for cleaning fine minus-100-mesh coal. A 24-month study was successfully completed, optimizing the performance of the ASH for cleaning raw classified, naturally-occurring minus-100-mesh Upper Freeport coal, and comparing its performance with Advanced Froth Flotation (AFF), a procedure utilizing conventional flotation equipment operated in an advanced manner (low impeller speeds, starvation float, multiple-stage cleaning, etc.) with highly selective reagents to optimize ash and pyritic sulfur rejection. The economics of cleaning fine coal by both processes at commercial scale, for retrofit and greenfield applications were found to be comparable within the accuracy of the study. Technical performance of the two processes were also found to be essentially identical. Thus, the ASH would be the best choice for a retrofit installation into an existing plant because of requiring less space. Both processes were successful in achieving excellent separations when cleaning the Upper Freeport coal. Both the ASH and AFF circuits were able to produce a clean-coal product of yield (65--80 percent weight recovery) and quality (5--6 percent ash) equivalent to that as theoretically determined by float-sink washability analyses. Combining either of the two fine coal flotation processes with a classifying cyclone circuit resulted in pyritic sulfur rejection values of about 85 percent. 47 refs., 109 figs., 75 tabs.

  10. Coal liquefaction process research quarterly report, October-December 1979

    SciTech Connect

    Bickel, T.C.; Curlee, R.M.; Granoff, B.; Stohl, F.V.; Thomas, M.G.

    1980-03-01

    This quarterly report summarizes the activities of Sandia's continuing program in coal liquefaction process research. The overall objectives are to: (1) provide a fundamental understanding of the chemistry of coal liquefaction; (2) determine the role of catalysts in coal liquefaction; and (3) determine the mechanism(s) of catalyst deactivation. The program is composed of three major projects: short-contact-time coal liquefaction, mineral effects, and catalyst studies. These projects are interdependent and overlap significantly.

  11. Ammonia production from coal by utilization of Texaco coal gasification process

    SciTech Connect

    Watson, J.R.; McClanhan, T.S.; Weatherington, R.W.

    1983-12-01

    Operating data will be presented for the coal gasification and gas purification unit which has been retrofitted to the front end of an existing ammonia plant. The plant uses 200 tons per day of coal and produces 135 tons per day of ammonia. The plant uses the Texaco coal gasification process, Haldor-Topsoe catalyst systems, Selexol acid gas removal process, and the Holmes-Stretford sulfur recovery process.

  12. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  13. Development of an advanced high efficiency coal combustor for boiler retrofit. Summary report

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  14. Environmental studies of materials from the H-coal liquefaction process development unit

    SciTech Connect

    Cada, G.F.

    1982-12-01

    H-coal is a process for the direct liquefaction of coal to produce synthetic fuels. Its development has progressed from bench-scale testing through operation of a 2.7 Mg/d (3 ton/d) Process Development Unit. A large-scale H-Coal pilot plant is presently operating at Catlettsburg, Kentucky, and there are plans for the construction of a commercial H-Coal liquefaction facility by the end of the decade. Two of the environmental concerns of the developing direct coal liquefaction industry are accidental spills of synthetic oils and treatment/storage of solid wastes. As a means of obtaining preliminary information on the severity of these potential impacts well in advance of commercialization, samples of product oils and solid wastes were obtained from the H-Coal Process Development Unit (PDU). These samples were subjected to a battery of rapid screening tests, including chemical characterization and bioassays with a variety of aquatic and terrestrial organisms. Water-soluble fraction (WSFs) of H-Coal PDU oils had considerably higher concentrations of phenols and anilines and were commonly one to two orders of magnitude more toxic to aquatic organisms than WSFs of analogous petroleum crude oil. Whole H-Coal PDU oils were also more toxic to the cricket than petroleum-based oils, and some H-Coal samples showed evidence of teratogenicity. Leachates from H-Coal PDU solid wastes, on the other hand, had relatively low concentrations of selected elements and had essentially no acute toxicity to a variety of aquatic and terrestrial species. These studies indicate that environmental effects of product oil spills from a commercial H-Coal liquefaction plant are likely to be more severe than those of conventional petroleum spills. Product upgrading or special transportation and storage techniques may be needed to ensure environmentally sound commercialization of the H-Coal process.

  15. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Rathbone, R.F.; Hower, J.C.; Derbyshire, F.J. . Center for Applied Energy Research)

    1991-10-01

    This study demonstrated the feasibility of using fluorescence and reflectance microscopy techniques for the examination of distillation resid materials derived from direct coal liquefaction. Resid, as defined here, is the 850{degrees}F{sup +} portion of the process stream, and includes soluble organics, insoluble organics and ash. The technique can be used to determine the degree of hydrogenation and the presence of multiple phases occurring within a resid sample. It can also be used to infer resid reactivity. The technique is rapid, requiring less than one hour for sample preparation and examination, and thus has apparent usefulness for process monitoring. Additionally, the technique can distinguish differences in samples produced under various process conditions. It can, therefore, be considered a potentially useful technique for the process developer. Further development and application of this analytical method as a process development tool is justified based on these results.

  16. Process for improving soluble coal yield in a coal deashing process

    DOEpatents

    Rhodes, Donald E.

    1980-01-01

    Coal liquefaction products are contacted with a deashing solvent and introduced into a first separation zone. The first separation zone is maintained at an elevated temperature and pressure, determined to maximize the recovery of soluble coal products, to cause said coal liquefaction products to separate into a first light phase and a first heavy phase. Under these conditions the heavy phase while still fluid-like in character is substantially non-flowable. Flowability is returned to the fluid-like heavy phase by the introduction of an additional quantity of deashing solvent into the first separation zone at a location below the interface between the first light and heavy phases or into the heavy phase withdrawal conduit during withdrawal of the first heavy phase and prior to any substantial pressure reduction. The first heavy phase then is withdrawn from the first separation zone for additional downstream processing without plugging either the withdrawal conduit or the downstream apparatus. The first light phase comprising the soluble coal products is withdrawn and recovered in an increased yield to provide a more economical coal deashing process.

  17. H-Coal process and plant design

    DOEpatents

    Kydd, Paul H.; Chervenak, Michael C.; DeVaux, George R.

    1983-01-01

    A process for converting coal and other hydrocarbonaceous materials into useful and more valuable liquid products. The process comprises: feeding coal and/or other hydrocarbonaceous materials with a hydrogen-containing gas into an ebullated catalyst bed reactor; passing the reaction products from the reactor to a hot separator where the vaporous and distillate products are separated from the residuals; introducing the vaporous and distillate products from the separator directly into a hydrotreater where they are further hydrogenated; passing the residuals from the separator successively through flash vessels at reduced pressures where distillates are flashed off and combined with the vaporous and distillate products to be hydrogenated; transferring the unseparated residuals to a solids concentrating and removal means to remove a substantial portion of solids therefrom and recycling the remaining residual oil to the reactor; and passing the hydrogenated vaporous and distillate products to an atmospheric fractionator where the combined products are fractionated into separate valuable liquid products. The hydrogen-containing gas is generated from sources within the process.

  18. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Mohanty, M.K.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a run-of-mine coal sample collected from Amax Coal Company`s Delta Coal mine using column flotation and an enhanced gravity separator as separate units and in circuitry arrangements. The {minus}60 mesh run-of-mine sample having an ash content of about 22% was cleaned to 6% while achieving a very high energy recovery of about 87% and a sulfur rejection value of 53% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Packed-Column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  19. Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

    DOEpatents

    Comolli, Alfred G.; McLean, Joseph B.

    1989-01-01

    A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

  20. Continuous extrusion of coal. [plastic fluidizing process

    NASA Technical Reports Server (NTRS)

    England, C.; Kushida, R.; Daksla, C.

    1978-01-01

    A feeding method for use with bituminous coals that exhibit plasticity at elevated temperatures is described and demonstrated on a small screw extruder previously used to extrude polyethylene. A metered feed of coal heated to a temperature just below that of incipient caking (approximately 450 C) is used. Modifications to the extruder consisting of ceramic band heaters, auxiliary cooling coils on the thrust bearing and special quick opening dies are detailed. Coals successfully extruded include high volatile A bituminous coals, high volatile B bituminous coals, a high volatile C bituminous coal and a coal with high ash content. The computer program, EXTRUD, used to simulate the extruder is described. Predicted power consumption exhibits 30% scatter, which is explained by the sensitivity of the coal friction coefficient to temperature profiles. Detailed analysis reveals some discrepancies in the program that need to be resolved.

  1. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Ibrahim, M.M.; Seehra, M.S. . Dept. of Physics)

    1992-10-01

    This study demonstrated the feasibility of using temperature-programmed electron spin resonance (ESR) and thermogravimetric analysis (TGA) for the examination of tetrahydrofuran (THF)-soluble distillation resid materials derived from direct coal liquefaction. TGA is used to quantitate volatile losses in a temperature-programmed experiment. The TGA data are used to correct the free radical densities obtained by ESR as volatile material is evolved from the samples in the temperature-programmed ESR experiment. The techniques, when employed in tandem, can be used to determine the content and nature of the free radicals in the samples at temperatures approximating those used in the liquefaction process. TGA and ESR experiments were performed in flowing nitrogen and hydrogen, at ambient pressure. No significant difference was observed in the ESR spectra in the different atmospheres, except in the case of low-rank coal-derived resids. The TGA results, however, were systematically different; mass loss in an H[sub 2] atmosphere is consistently higher than that observed in an N[sub 2] atmosphere. It was shown that temperature-programmed ESR, which can pinpoint conditions at which the free radical content is the highest, has potential to be a guide for the appropriate choice of conditions for optimum resid upgrading. Further development of these combined analytical methods as process development tools appears justified based on these results.

  2. ASPEN. Advanced System for Process Engineering

    SciTech Connect

    Bajura, R.A.

    1985-10-01

    ASPEN (Advanced System for Process Engineering) is a state of the art process simulator and economic evaluation package which was designed for use in engineering fossil energy conversion processes. ASPEN can represent multiphase streams including solids, and handle complex substances such as coal. The system can perform steady state material and energy balances, determine equipment size and cost, and carry out preliminary economic evaluations. It is supported by a comprehensive physical property system for computation of major properties such as enthalpy, entropy, free energy, molar volume, equilibrium ratio, fugacity coefficient, viscosity, thermal conductivity, and diffusion coefficient for specified phase conditions; vapor, liquid, or solid. The properties may be computed for pure components, mixtures, or components in a mixture, as appropriate. The ASPEN Input Language is oriented towards process engineers.

  3. Environmental impact of solvent refined coal processes

    SciTech Connect

    Lobnitz, M.A.; Firley, J.A.; Loran, B.

    1982-08-01

    The SRC-1 process produces low sulfur and low ash solid and liquid fuels from coal which can replace corresponding petroleum products. Sources of air pollution are fuel gas combustion products, solids and liquids handling, and waste gases. The SRC-1 demonstration plant planned is projected to have very small impacts on air quality. The wastewater treatment system is designed for zero-discharge and process-derived solids are to be disposed in suitably selected land areas. Environmental unknowns in the project include operator skill in managing startup, shutdown and upset emissions; regional impact of the CO/sub 2/ released; detailed characterization of wastewater streams; and solid waste leachate kinetics. These issues are expected to be explored and possibly resolved through experience acquired during operation of the demonstration plant.

  4. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Brandes, S.D.; Lancet, M.S.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the eleventh Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: (1) The results of a study designed to determine the effects of the conditions employed at the Wilsonville slurry preheater vessel on coal conversion is described. (2) Stable carbon isotope ratios were determined and used to source the carbon of three product samples from Period 49 of UOP bench-scale coprocessing Run 37. The results from this coprocessing run agree with the general trends observed in other coprocessing runs that we have studied. (3) Microautoclave tests and chemical analyses were performed to calibrate'' the reactivity of the standard coal used for determining donor solvent quality of process oils in this contract. (4) Several aspects of Wilsonville Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) resid conversion kinetics were investigated; results are presented. Error limits associated with calculations of deactivation rate constants previously reported for Runs 258 and 261 are revised and discussed. A new procedure is described that relates the conversions of 850[degrees]F[sup +] , 1050[degrees]F[sup +], and 850 [times] 1050[degrees]F material. Resid conversions and kinetic constants previously reported for Run 260 were incorrect; corrected data and discussion are found in Appendix I of this report.

  5. Continuous process for conversion of coal

    DOEpatents

    Knudson, Curtis L.; Willson, Warrack G.; Baker, Gene G.; Sondreal, Everett A.; Farnum, Sylvia A.

    1982-01-01

    An improved process for converting coal to liquid and gaseous products wherein the liquid products predominate and wherein reactor, tubing, and valve plugging due to carbonate salt formation is reduced by reacting crushed low-rank coal containing about 12 to 30% by weight of water in a solvent at a temperature in the range of about 455.degree. to 500.degree. C., under about 2000 to 5000 psi pressure of a H.sub.2 /CO mixture for a liquid residence time of about 20 to 60 minutes. The solvent is a fraction of liquid product defined on a weight basis as being made up of about 55% of which distills at less than 250.degree. C./lmm, about 20% of which is soluble in THF, and about 25% of which is carbon polymer and indigenous inorganic matter. The solvent is further defined as containing at least about 5 weight % of partially hydrogenated aromatics and/or fully hydrogenated aromatics and little or no alkylated aromatics or higher alkanes.

  6. The high moisture western coal processing system at the UTSI-DOE Coal Fired Flow Facility. Topical report

    SciTech Connect

    Sanders, M.E.

    1996-02-01

    The original eastern coal processing system at the Department of Energy`s Coal Fired Flow Facility (CFFF), located at the University of Tennessee Space Institute in Tullahoma, Tennessee, was modified to pulverize and dry Montana Rosebud, a western coal. Significant modifications to the CFFF coal processing system were required and the equipment selection criteria are reviewed. Coal processing system performance parameters are discussed. A summary of tests conducted and significant events are included.

  7. Engineereing development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 5, October--December 1993

    SciTech Connect

    Smit, F.J.; Jha, M.C.

    1994-02-18

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. The project has three major objectives: The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  8. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    SciTech Connect

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  9. Effect of the process conditions of aerobic bioconversion on the characteristics of biologically processed brown coals

    SciTech Connect

    I.P. Ivanov

    2007-04-15

    The effect of the laboratory and pilot process conditions of the aerobic bioconversion of brown coals on the elemental composition and technical characteristics of the organic matter of the resulting biologically processed coals is reported.

  10. Development of clean coal and clean soil technologies using advanced agglomeration technologies

    SciTech Connect

    Ignasiak, B.; Pawlak, W.; Szymocha, K.; Marr, J.

    1990-04-01

    The specific objectives of the bituminous coal program were to explore and evaluate the application of advanced agglomeration technology for: (1)desulphurization of bituminous coals to sulphur content acceptable within the current EPA SO{sub 2} emission guidelines; (2) deashing of bituminous coals to ash content of less than 10 percent; and (3)increasing the calorific value of bituminous coals to above 13,000 Btu/lb. (VC)

  11. Engineering development of advance physical fine coal cleaning for premium fuel applications

    SciTech Connect

    Jha, M.C.; Smit, F.J.; Shields, G.L.

    1995-11-01

    The objective of this project is to develop the engineering design base for prototype fine coal cleaning plants based on Advanced Column Flotation and Selective Agglomeration processes for premium fuel and near-term applications. Removal of toxic trace elements is also being investigated. The scope of the project includes laboratory research and bench-scale testing of each process on six coals followed by design, construction, and operation of a 2 tons/hour process development unit (PDU). Three coals will be cleaned in tonnage quantity and provided to DOE and its contractors for combustion evaluation. Amax R&D (now a subsidiary of Cyprus Amax Mineral Company) is the prime contractor. Entech Global is managing the project and performing most of the research and development work as an on-site subcontractor. Other participants in the project are Cyprus Amax Coal Company, Arcanum, Bechtel, TIC, University of Kentucky and Virginia Tech. Drs. Keller of Syracuse and Dooher of Adelphi University are consultants.

  12. Engineering design and analysis of advanced physical fine coal cleaning technologies. Quarterly technical progress report No. 13, October--December 1992

    SciTech Connect

    Gallier, P.W.

    1993-01-20

    This project is sponsored by the United States Department of Energy (DOE) for the ``Engineering Design and Analysis of Advanced Physical Fine Coal Cleaning Technologies: The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cycloning, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level. The commercially available ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology, Inc. (AspenTech), its contractor, ICF Kaiser Engineers, Inc.,(ICF KE) and CQ Inc., a subcontractor to ICF KE, for the period of October through December 1992. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models. CQ Inc. is a subcontractor to ICF KE on Tasks 1-5.

  13. Markets for small-scale, advanced coal-combustion technologies

    SciTech Connect

    Placet, M.; Kenkeremath, L.D.; Streets, D.G.; Dials, G.E.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1988-12-01

    This report examines the potential of using US-developed advanced coal technologies (ACTs) for small combustors in foreign markets; in particular, the market potentials of the member countries of the Organization of Economic Co-operation and Development (OECD) were determined. First, the United States and those OECD countries with very low energy demands were eliminated. The remaining 15 countries were characterized on the basis of eight factors that would influence their decision to use US ACTs: energy plan and situation, dependence on oil and gas imports, experience with coal, residential/commercial energy demand, industrial energy demand, trade relationship with the United States, level of domestic competition with US ACT manufacturers, and environmental pressure to use advanced technology. Each country was rated high, medium-high, low-medium, or low on each factor, based on statistical and other data. The ratings were then used to group the countries in terms of their relative market potential (good, good but with impediments, or limited). The best potential markets appear to be Spain, Italy, turkey, Greece, and Canada. 25 refs., 1 fig., 37 tabs.

  14. Coal liquefaction process streams characterization and evaluation

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the twelfth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: Summaries of the final reports produced by Lehigh University, West Virginia University, and Vander Sande Associates under the Participants Program are presented. Analytical data produced by CONSOL are provided in Appendix I for all samples employed in the Participants Program and issued with the samples to research groups in the Participants Program. A paper was presented at the 1992 US Department of Energy Pittsburgh Energy Technology Center Liquefaction Contractors' Review Conference, held in Pittsburgh September 23--24, 1992, entitled The Chemical Nature of Coal Liquid Resids and the Implications for Process Development''. It appears as Appendix 2 in this report.

  15. Advanced Hydrogen Liquefaction Process

    SciTech Connect

    Schwartz, Joseph; Kromer, Brian; Neu, Ben; Jankowiak, Jerome; Barrett, Philip; Drnevich, Raymond

    2011-09-28

    The project identified and quantified ways to reduce the cost of hydrogen liquefaction, and reduce the cost of hydrogen distribution. The goal was to reduce the power consumption by 20% and then to reduce the capital cost. Optimizing the process, improving process equipment, and improving ortho-para conversion significantly reduced the power consumption of liquefaction, but by less than 20%. Because the efficiency improvement was less than the target, the program was stopped before the capital cost was addressed. These efficiency improvements could provide a benefit to the public to improve the design of future hydrogen liquefiers. The project increased the understanding of hydrogen liquefaction by modeling different processes and thoroughly examining ortho-para separation and conversion. The process modeling provided a benefit to the public because the project incorporated para hydrogen into the process modeling software, so liquefaction processes can be modeled more accurately than using only normal hydrogen. Adding catalyst to the first heat exchanger, a simple method to reduce liquefaction power, was identified, analyzed, and quantified. The demonstrated performance of ortho-para separation is sufficient for at least one identified process concept to show reduced power cost when compared to hydrogen liquefaction processes using conventional ortho-para conversion. The impact of improved ortho-para conversion can be significant because ortho para conversion uses about 20-25% of the total liquefaction power, but performance improvement is necessary to realize a substantial benefit. Most of the energy used in liquefaction is for gas compression. Improvements in hydrogen compression will have a significant impact on overall liquefier efficiency. Improvements to turbines, heat exchangers, and other process equipment will have less impact.

  16. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOEpatents

    Miller, R.N.

    1986-10-14

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  17. Engineering design and analysis of advanced physical fine coal cleaning technologies

    SciTech Connect

    Not Available

    1992-01-20

    This project is sponsored by the United States Department of Energy (DOE) for the Engineering Design and Analysis of Advanced Physical Fine Coal Cleaning Technologies. The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cylconing, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level.

  18. Advanced Containerless Processing Technology

    NASA Technical Reports Server (NTRS)

    Wang, T. G.

    1985-01-01

    Breadboards for high temperature containerless processing systems are to be developed, the principles of operation are to be studied, the performance is to be characterized, the limitations identified, and the influence of the acoustic field on the samples established. The subjects to be addressed are experimental and theoretical studies of: (1) acoustic positioning and manipulation capabilities in a high temperature gradient environment (from 26 C to 990 C); (2) acoustic waveforms, harmonic contents, power transfer, sample transport and stability associated with high temperature gradient system; (3) high temperature ground based levitation systems which will allow melting, processing, and solidifying samples without crucibles in the laboratory, (4) KC-135 and laboratory tests of various acoustic geometries which may have spherical applications in the Materials Processing in Space Program; and (5) provide technical information to Acoustics Containerless Experimental System (ACES) engineering team and establish the operation conditions for ACES.

  19. Advanced coal-gasification technical analyses. Appendix 2: coal fines disposal. Final report, December 1982-September 1985

    SciTech Connect

    Cover, A.E.; Hubbard, D.A.; Jain, S.K.; Shah, K.V.

    1986-01-01

    This report is a compilation of several studies conducted by KRSI under the Advanced Coal Gasification Technical Analyses contract with GRI. It addresses the issue of disposal and/or utilization of the coal fines that cannot be used as feedstock for fixed-bed (i.e. Lurgi) gasifiers. Specific items addressed are: (1) Technical, legal and economic aspects of fines burial, (2) Estimation of the premium for fines-free coal delivered to an SNG plant and resulting reduction in SNG production costs, (3) Comparison of the relative advantages and limitations of Winkler and GKT gasifiers to consuming fines, (4) Review of coal-size consist curves in the GRI Guidelines to assess the fines content of ROM coals, (5) a first-pass design and cost estimate using GKT gasifiers in tandem with Lurgi gasifiers in an North Dakota lignite-to-SNG plant to consume full range of coal-size consist, (6) Evaluation of the General Electric technology for extrusion of coal fines and testing of the extrudates in a fixed-bed gasifier, and (7) Investigation of equipment and variables involved in briquetting of coal fines, such that fines could be fed to the gasifiers along with the lump coal.

  20. Removal of mercury from coal via a microbial pretreatment process

    DOEpatents

    Borole, Abhijeet P.; Hamilton, Choo Y.

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  1. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  2. Process for heating coal-oil slurries

    DOEpatents

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  3. Process for heating coal-oil slurries

    DOEpatents

    Braunlin, Walter A.; Gorski, Alan; Jaehnig, Leo J.; Moskal, Clifford J.; Naylor, Joseph D.; Parimi, Krishnia; Ward, John V.

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  4. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  5. Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 23, April 1, 1994--June 30, 1994

    SciTech Connect

    1995-04-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  6. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 16, July 1, 1992--September 30, 1992

    SciTech Connect

    Not Available

    1992-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  7. Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 24, July 1, 1994--September 30, 1994

    SciTech Connect

    1995-04-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  8. Ultrafine coal single stage dewatering and briquetting process

    SciTech Connect

    Wilson, J.W.; Honaker, R.Q.

    1995-12-31

    It is well known that a large portion of the pyrite particles in the coal seams of the Illinois Basin are finely disseminated within the coal matrix. In order to liberate these micron size pyrite particles, one must use a fine grinding operation. The ultrafine coal particles are difficult to dewater and create problems in coal transportation, as well as in storage and handling at utility plants. The objective of this research project is to combine the ultrafine coal dewatering and briquetting processes into a single stage operation. This will be accomplished by the use of bitumen based emulsions for dewatering and a compaction device for briquetting. During this reporting period, several types of coal samples with various particle size distributions have been tested for use in the dewatering and briquetting processes. Furthermore, various bitumen emulsions have been tested to determine the optimum dewatering reagent. These dewatering and pelletizing tests were carried out using a lab-scale ram extruder. Discharge from the dewatering and briquetting processes was tested to determine compliance with current federal and state requirements. The influence of bitumen emulsion on the sulfur content of coal pellets made were also examined. In addition, a ram extruder which can be operated continuously to simulate a rotary press operation, has been built and is currently being tested for use in the fine coal dewatering and pelletizing process.

  9. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  10. Development of advanced capitalism: a case study of retired coal miners in southern West Virginia

    SciTech Connect

    Legeay, S.P.

    1980-01-01

    This dissertation develops a critical analysis of changes in American society during the last fifty years. It is focused in particular on the southern West Virginia coal fields, and examines the changes in class structure (specifically, coal miners), the labor process, the union, class consciousness, community and leisure. The study is grounded within a theoretical perspective that is dialectical. It is concerned with the interaction between specific social categories (such as the union) and the greater whole of capitalist development. It is centrally concerned with continuing a research orientation to which the Frankfurt School gave a powerful contribution: the development of advanced capitalism in the modern epoch. The study utilizes life-history interviews with retired coal miners, almost all of whom had experience with the exploitive company towns of an earlier time. Thus, techniques for the study of oral history are instrumental in developing an analysis of social developments, inasmuch as they provide data appropriate for an analysis of the transformation from early to late capitalism. Finally, this dissertation examines a problem central to dialectical theory, that of the relation between theory and praxis, by approaching the life histories as exemplifications of collective (i.e., social) experience. It integrates the biographical experience of individual miners with the theoretical dimensions of political economy in early and late capitalism. The current crisis in the coal fields is examined, with a view to possible transformation.

  11. ADVANCED OXIDATION PROCESS

    SciTech Connect

    Dr. Colin P. Horwitz; Dr. Terrence J. Collins

    2003-11-04

    The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

  12. Advanced Sulfur Control Processing

    SciTech Connect

    Gangwal, S.K.; Portzer, J.W.; Turk, B.S.; Gupta, R.

    1996-12-31

    The primary objective of this project is to determine the feasibility of an alternate concept for the regeneration of high temperature desulfurization sorbents in which elemental sulfur, instead of SO{sub 2}, is produced. If successful, this concept will eliminate or alleviate problems caused by the highly exothermic nature of the regeneration reaction, the tendency for metal sulfate formation, and the need to treat the regeneration off-gas to prevent atmospheric SO{sub 2}, emissions. Iron and cerium-based sorbents were chosen on the basis of thermodynamic analysis to determine the feasibility of elemental sulfur production. The ability of both to remove H{sub 2}S during the sulfidation phase is less than that of zinc-based sorbents, and a two-stage desulfurization process will likely be required. Preliminary experimental work used electrobalance reactors to compare the relative rates of reaction of O{sub 2} and H{sub 2}O with FeS. More detailed studies of the regeneration of FeS as well as the sulfidation of CeO{sub 2} and regeneration of Ce{sub 2}O{sub 2}S are being carried out in a laboratory-scale fixed-bed reactor equipped with a unique analytical system which permits semi-continuous analysis of the distribution of elemental sulfur, H{sub 2}S, and SO{sub 2} in the reaction product gas.

  13. Supercritical Fluid Reactions for Coal Processing

    SciTech Connect

    Charles A. Eckert

    1997-11-01

    Exciting opportunities exist for the application of supercritical fluid (SCF) reactions for the pre-treatment of coal. Utilizing reactants which resemble the organic nitrogen containing components of coal, we developed a method to tailor chemical reactions in supercritical fluid solvents for the specific application of coal denitrogenation. The tautomeric equilibrium of a Schiff base was chosen as one model system and was investigated in supercritical ethane and cosolvent modified supercritical ethane. The Diels-Alder reaction of anthracene and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) was selected as a second model system, and it was investigated in supercritical carbon dioxide.

  14. Engineering design and analysis of advanced physical fine coal cleaning technologies. Quarterly technical progress report No. 12, July--September 1992

    SciTech Connect

    Gallier, P.W.

    1992-10-20

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies- advanced cylconing, selective agglomeration, and advanced froth flotation through the proof-of-concept. The commercially available ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology Inc. (AspenTech), its contractor, ICF Kaiser Engineers, Inc., (ICF KE) and CQ Inc., for the period of July through September 1992. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models. CQ Inc. is a subcontractor to ICF KE on Tasks I - 5 and is a contractor to AspenTech on Task 6.

  15. Advanced composite materials and processes

    NASA Technical Reports Server (NTRS)

    Baucom, Robert M.

    1991-01-01

    Composites are generally defined as two or more individual materials, which, when combined into a single material system, results in improved physical and/or mechanical properties. The freedom of choice of the starting components for composites allows the generation of materials that can be specifically tailored to meet a variety of applications. Advanced composites are described as a combination of high strength fibers and high performance polymer matrix materials. These advanced materials are required to permit future aircraft and spacecraft to perform in extended environments. Advanced composite precursor materials, processes for conversion of these materials to structures, and selected applications for composites are reviewed.

  16. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 6, January--March 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-05-03

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1- March 31, 1996.

  17. Development of the chemical and electrochemical coal cleaning (CECC) process

    SciTech Connect

    Yoon, Roe-Hoan; Basilio, C.I.

    1992-05-01

    The Chemical and Electrochemical Coal Cleaning (CECC) process developed at Virginia Polytechnic Institute and State University was studied further in this project. This process offers a new method of physically cleaning both low- and high-rank coals without requiring fine grinding. The CECC process is based on liberating mineral matter from coal by osmotic pressure. The majority of the work was conducted on Middle Wyodak, Pittsburgh No. 8 and Elkhorn No. 3 coals. The coal samples were characterized for a variety of physical and chemical properties. Parametric studies were then conducted to identify the important operating parameters and to establish the optimum conditions. In addition, fundamental mechanisms of the process were studied, including mineral matter liberation, kinetics of mineral matter and pyrite dissolution, ferric ion regeneration schemes and alternative methods of separating the cleaned coal from the liberated mineral matter. The information gathered from the parametric and fundamental studies was used in the design, construction and testing of a bench-scale continuous CECC unit. Using this unit, the ash content of a Middle Wyodak coal was reduced from 6.96 to 1.61% at a 2 lbs/hr throughput. With an Elkhorn No. 3 sample, the ash content was reduced from 9.43 to 1.8%, while the sulfur content was reduced from 1.57 to 0.9%. The mass balance and liberation studies showed that liberation played a more dominant role than the chemical dissolution in removing mineral matter and inorganic sulfur from the different bituminous coals tested. However, the opposite was found to be the case for the Wyodak coal since this coal contained a significant amount of acid-soluble minerals.

  18. Coal liquefaction process with increased naphtha yields

    DOEpatents

    Ryan, Daniel F.

    1986-01-01

    An improved process for liquefying solid carbonaceous materials wherein the solid carbonaceous material is slurried with a suitable solvent and then subjected to liquefaction at elevated temperature and pressure to produce a normally gaseous product, a normally liquid product and a normally solid product. The normally liquid product is further separated into a naphtha boiling range product, a solvent boiling range product and a vacuum gas-oil boiling range product. At least a portion of the solvent boiling-range product and the vacuum gas-oil boiling range product are then combined and passed to a hydrotreater where the mixture is hydrotreated at relatively severe hydrotreating conditions and the liquid product from the hydrotreater then passed to a catalytic cracker. In the catalytic cracker, the hydrotreater effluent is converted partially to a naphtha boiling range product and to a solvent boiling range product. The naphtha boiling range product is added to the naphtha boiling range product from coal liquefaction to thereby significantly increase the production of naphtha boiling range materials. At least a portion of the solvent boiling range product, on the other hand, is separately hydrogenated and used as solvent for the liquefaction. Use of this material as at least a portion of the solvent significantly reduces the amount of saturated materials in said solvent.

  19. Advanced physical coal cleaning to comply with potential air toxic regulations. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Honaker, R.Q.; Paul, B.C.; Wang, D.

    1995-12-31

    Studies have indicated that the potentially hazardous trace elements found in coal have a strong affinity for coal pyrite. Thus, by maximizing the rejection of pyrite, one can minimize the trace element content of a given coal while also reducing sulfur emissions. The pyrite in most Illinois Basin coals, however, is finely disseminated within the coal matrix. Therefore, to remove the pyrite using physical coal cleaning techniques, the pyrite must be liberated by grinding the coal to ultrafine particle sizes. Fortunately, the coals being fed to pulverized coal boilers (PCB) are already ground to a very fine size, i.e., 70% passing 200 mesh. Therefore, this research project will investigate the use of advanced fine coal cleaning technologies for cleaning PCB feed as a compliance strategy. Work in this quarter has focused on the processing of a PCB feed sample collected from Central Illinois Power`s Newton Power Station using column flotation and an enhanced gravity separator as separate units and in a circuitry arrangement. The PCB feed sample having a low ash content of about 12% was further cleaned to 6% while achieving a very high energy recovery of about 90% in a single stage column flotation operation. Enhanced gravity treatment is believed to be providing excellent total sulfur rejection values, although with inferior ash rejection for the {minus}400 mesh size fraction. The circuitry arrangement with the Falcon concentrator as the primary cleaner followed by the Microcel column resulted in an excellent ash rejection performance, which out performed the release analysis. Trace element analyses of the samples collected from these tests will be conducted during the next report period.

  20. Selection of feed coals for production of premium fuel using column flotation and selective agglomeration processes

    SciTech Connect

    Jha, M.C.; Smit, F.J.

    1995-10-01

    Column flotation and selective agglomeration are promising advanced physical cleaning processes that can be developed for preparing premium quality coal-water slurry fuel from coal fines. Such a fuel could either replace oil or natural gas in certain industrial and utility boilers or else could be burned in advanced combustors currently under development. These applications require coal cleaned to sulfur and ash contents below 258 g/GJ and 430--860 g/GJ (0.6 lb/million Btu and 1--2 lb/million Btu), respectively, to meet clean air emission requirements. A highly loaded slurry must be produced in order to avoid derating the boilers, and the total cost of the fuel must be below $2.37/GJ ($2.50/million Btu) in order to penetrate the market by the turn of the century. Achieving these technical and economic goals depend critically on the selection of suitable feed coals. This paper describes the identification and evaluation of 18 coals and final selection of six coals from different regions of the United States as potential feedstock for preparation of premium fuel. The work is being performed under a cost-shared DOE project.

  1. Coal gasification via the Lurgi process: Topical report: Volume 2, Production of IFG (industrial fuel gas)

    SciTech Connect

    Zahnstecher, L.W.

    1984-12-01

    A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of industrial fuel gas (IFG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based upon a plant producing 73.3 billion Btu (HHV) per day of IFG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant feed, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated facility which utilizes coal, air, and water to produce 73.3 billion Btu (HHV) per day of industrial fuel gas. The plant consists of coal handling and preparation, seven Lurgi dry bottom gasifiers, acid gas removal, sulfur recovery, phenol and ammonia recovery, as well as necessary support facilities. The plant is a grass roots facility located in the area of Minneapolis, Minnesota. The Lurgi Corporation assisted in this study, under subcontract to Foster Wheeler, by supplying the heat and material balances, flow sheets, utilities, catalysts and chemical requirements, and cost data for Lurgi designed process sections. Details of material supplied by Lurgi Corporation are presented in Appendix A. 39 refs., 33 figs., 50 tabs.

  2. Process for producing advanced ceramics

    DOEpatents

    Kwong, Kyei-Sing

    1996-01-01

    A process for the synthesis of homogeneous advanced ceramics such as SiC+AlN, SiAlON, SiC+Al.sub.2 O.sub.3, and Si.sub.3 N.sub.4 +AlN from natural clays such as kaolin, halloysite and montmorillonite by an intercalation and heat treatment method. Included are the steps of refining clays, intercalating organic compounds into the layered structure of clays, drying the intercalated mixture, firing the treated atmospheres and grinding the loosely agglomerated structure. Advanced ceramics produced by this procedure have the advantages of homogeneity, cost effectiveness, simplicity of manufacture, ease of grind and a short process time. Advanced ceramics produced by this process can be used for refractory, wear part and structure ceramics.

  3. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 26, January 1, 1995--March 31, 1995

    SciTech Connect

    1995-07-01

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  4. Performance and risks of advanced pulverized-coal plants

    SciTech Connect

    Nalbandian, H.

    2009-07-01

    This article is based on an in-depth report of the same title published by the IEA Clean Coal Centre, CCC/135 (see Coal Abstracts entry Sep 2008 00535). It discusses the commercial, developmental and future status of pulverized fuel power plants including subcritical supercritical and ultra supercritical systems of pulverized coal combustion, the most widely used technology in coal-fired power generation. 1 fig., 1 tab.

  5. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    SciTech Connect

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K.

    1994-06-01

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  6. 40 CFR 60.254 - Standards for coal processing and conveying equipment, coal storage systems, transfer and loading...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. 60.254... and Processing Plants § 60.254 Standards for coal processing and conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. (a) On and after the date on which...

  7. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    SciTech Connect

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be

  8. Process for stabilization of coal liquid fractions

    DOEpatents

    Davies, Geoffrey; El-Toukhy, Ahmed

    1987-01-01

    Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

  9. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 16, July--September, 1996

    SciTech Connect

    Shields, G.L.; Moro, N.; Smit, F.J.; Jha, M.C.

    1996-10-30

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. 28 refs., 13 figs., 19 tabs.

  10. A Characterization and Evaluation of Coal Liquefaction Process Streams

    SciTech Connect

    G. A. Robbins; R. A. Winschel; S. D. Brandes

    1998-06-09

    CONSOL characterized 38 process strea m samples from HTI Run PB- 04, in which Black Thunder Mine Coal, Hondo vacuum resid, autom obile shredder residue (ASR), and virgin plastics were used as liquefaction feedstocks with dispersed catalyst. A paper on kinetic modeling of resid reactivity was presented at the DOE Coal Lique -faction and Solid Fuels Contractors Review Conference, September 3- 4, 1997, i n Pittsburgh, PA. The paper, "The Reactivity of Direct Coal Liquefaction Resids", i s appended (Appendix 1). Three papers on characterization of samples from coal/ resid/ waste p lastics co- liquefaction were presented or submitted for presen tation at conferences. Because of their similarity, only one of the papers is appended to this report. The paper, "Characterization o f Process Samples From Co- Liquefaction of Coal and Waste Polymers", (Appendix 2) was presented at the DOE Coal Liquefaction and Solid Fuels C ontractors Review Conference, September 3- 4, 1997, in Pittsburgh, PA. The paper, "Characterization of Process Stream Samples From Bench- Scale Co -Liquefaction Runs That Utilized Waste Polymers as Feedstocks" was presented at the 214th National Meeting of the Ameri can Chemical Society, September 7- 11, 1997, in Las Vegas, NV. The paper, "Characterization of Process Oils from Coal/ Waste Co- Liquefaction" wa s submitted for presentation at the 14th Japan/ U. S. Joint Technical Meeting on Coa l Liquefaction and Materials for Coal Liquefaction on October 28, 1997, in Tokyo, Japan. A joint Burns and Roe Services Corp. and CONSOL pap er on crude oil assays of product oils from HTI Run PB- 03 was presented at the DOE Coal Liquefaction and Solid Fuel s Contractors Review Conference, September 3- 4, 1997, in Pittsburgh, PA. The paper , "Characterization of Liquid Products from All- Slurry Mode Liquefaction", is appende d (Appendix 3).

  11. Advanced direct coal liquefaction. Quarterly technical progress report No. 2, December 1983-February 1984

    SciTech Connect

    Paranjape, A.S.

    1984-04-30

    Five Bench-Scale coal liquefaction runs were completed with Wyoming subbituminous coal in a two-stage process scheme. In this process scheme, LDAR, the lighter fraction of ash-free resid, was fed to the catalytic stage prior to its recycle to the thermal stage, whereas DAR, the heavy fraction of the deashed resid, was directly recycled to the thermal stage without any intermediate processing step. The results indicate that increasing coal space rate in the dissolver resulted in lower coal conversion and reduced distillate yield in this process configuration. The coal conversions decreased from 92 wt% to 89 wt% (MAF coal) and the distillate yield was reduced from 50 wt% to less than 40 wt% (MAF coal), as the coal space velocity increased. Attempts to duplicate the yields of Run 32, at comparable process conditions in Runs 37 and 38, were unsuccessful. Several process parameters were investigated but failed to show why the yields of Run 32 could not be duplicated. Valuable process related information was gained as a result of process parameter studies completed during these runs. At comparable process conditions, coal conversions were lower by about 3 to 4 relative percent and were only in the 87 wt% (MAF coal) range. Similarly, the distillate yield was about 40 wt% (MAF coal) which is about 10 wt% lower than observed in Run 32. Although no exact cause for these results could be determined, it appeared that the H/C atomic ratio of the solvent and possibly the flow pattern (plug-flow versus back-mixed) could have affected the coal conversion and quantity of distillate product produced. A significant decrease in coal conversion of 4 to 5 wt% was observed when the disposable catalyst (iron oxide) was removed from the reaction mixture and therefore substantiates the need for a disposable catalyst in the liquefaction of Wyoming subbituminous coal.

  12. Engineering design and analysis of advanced physical fine coal cleaning technologies. Quarterly technical progress report No. 8, July--September 1991

    SciTech Connect

    Gallier, P.W.

    1991-10-20

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies- heavy-liquid cylconing, selective agglomeration, and advanced froth flotation through the proof-of- concept (POC) level. The commercially available ASPEN PLUS process simulation package will be extended to handle coal applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology, Inc. (ApsenTech), its contractor, ICF Kaiser Engineers, Inc., (ICF KE) and CQ Inc., a subcontractor to ICF KE, for the seventh quarterly reporting period, April through June 1991. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models.

  13. Process for fixed bed coal gasification

    DOEpatents

    Sadowski, Richard S.

    1992-01-01

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  14. Supercritical fluid reactions for coal processing

    SciTech Connect

    Eckert, C.A.

    1997-04-01

    Exciting opportunities exist for the application of supercritical fluid (SCF) reactions for the pre-treatment of coal. Utilizing reactants which resemble the organic nitrogen containing components of coal, we propose to develop a method to tailor chemical reactions in supercritical fluid solvents for the specific application of coal denitrogenation. The Diels-Alder reaction of anthracene and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) was chosen as the model system and was investigated in supercritical carbon dioxide. Kinetic data has been previously collected for pure CO{sub 2} at pressures between the critical pressure of CO{sub 2} (73.8 bar) and 216 bar. This data is now being used to construct mathematical forms which can model these pressure induced kinetic changes. One promising avenue of investigation involves treating the supercritical medium as a dense gas, which allows a kinetic model based on high reference pressure fugacity coefficients to be derived.

  15. Analysis of chemical coal cleaning processes. Final report

    SciTech Connect

    Not Available

    1980-06-01

    Six chemical coal cleaning processes were examined. Conceptual designs and costs were prepared for these processes and coal preparation facilities, including physical cleaning and size reduction. Transportation of fine coal in agglomerated and unagglomerated forms was also discussed. Chemical cleaning processes were: Pittsburgh Energy Technology Center, Ledgemont, Ames Laboratory, Jet Propulsion Laboratory (two versions), and Guth Process (KVB). Three of the chemical cleaning processes are similar in concept: PETC, Ledgemont, and Ames. Each of these is based on the reaction of sulfur with pressurized oxygen, with the controlling factor being the partial pressure of oxygen in the reactor. All of the processes appear technically feasible. Economic feasibility is less certain. The recovery of process chemicals is vital to the JPL and Guth processes. All of the processes consume significant amounts of energy in the form of electric power and coal. Energy recovery and increased efficiency are potential areas for study in future more detailed designs. The Guth process (formally designed KVB) appears to be the simplest of the systems evaluated. All of the processes require future engineering to better determine methods for scaling laboratory designs/results to commercial-scale operations. A major area for future engineering is to resolve problems related to handling, feeding, and flow control of the fine and often hot coal.

  16. Use of the GranuFlow Process in Coal Preparation Plants to Improve Energy Recovery and Reduce Coal Processing Wastes

    SciTech Connect

    Glenn A. Shirey; David J. Akers

    2005-12-31

    With the increasing use of screen-bowl centrifuges in today's fine coal cleaning circuits, a significant amount of low-ash, high-Btu coal can be lost during the dewatering step due to the difficulty in capturing coal of this size consist (< 100 mesh or 0.15mm). The GranuFlow{trademark} technology, developed and patented by an in-house research group at DOE-NETL, involves the addition of an emulsified mixture of high-molecular-weight hydrocarbons to a slurry of finesized coal before cleaning and/or mechanical dewatering. The binder selectively agglomerates the coal, but not the clays or other mineral matter. In practice, the binder is applied so as to contact the finest possible size fraction first (for example, froth flotation product) as agglomeration of this fraction produces the best result for a given concentration of binder. Increasing the size consist of the fine-sized coal stream reduces the loss of coal solids to the waste effluent streams from the screen bowl centrifuge circuit. In addition, the agglomerated coal dewaters better and is less dusty. The binder can also serve as a flotation conditioner and may provide freeze protection. The overall objective of the project is to generate all necessary information and data required to commercialize the GranuFlow{trademark} Technology. The technology was evaluated under full-scale operating conditions at three commercial coal preparation plants to determine operating performance and economics. The handling, storage, and combustion properties of the coal produced by this process were compared to untreated coal during a power plant combustion test.

  17. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    G.H. Luttrell; G.T. Adel

    1999-01-11

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eleventh quarter of this project, Task 7 (Operation and Testing) was nearly completed through the efforts of J.A. Herbst and Associates, Virginia Tech, and Pittston Coal Company. As a result of this work, a model-based control system has now been installed which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. The system has gone through a shake-down period, training has been carried out for plant operators, and the bulk of the control logic testing has been completed with the results of these tests awaiting analysis under Task 8 (System Evaluation). The flotation model has been shown to predict incremental ash quite successfully, implying that this approach may provide the basis for a useful ''soft sensor'' for on-line incremental ash analysis.

  18. AN ADVANCED CONTROL SYSTEM FOR FINE COAL FLOTATION

    SciTech Connect

    1998-10-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of tailings ash content. Then, based on an on-line estimate of incremental ash, the pulp level is adjusted using a model-based control algorithm to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the tenth quarter of this project, Task 6 (Equipment Procurement and Installation) was completed through the efforts of J.A. Herbst and Associates, Virginia Tech, Pittston Coal Company, and FGR Automation. As a result of this work, a model-based control system is now in place which can predict incremental ash based on tailings ash content and general plant data, and adjust pulp level accordingly to maintain a target incremental ash. Testing of this control system is expected to be carried out during the next quarter, and the results of this testing will be reported in the Eleventh Quarterly report. In addition, calibration of the video-based ash analyzer was continued and an extensive set of calibration data were obtained showing that the plant is running remarkably well under manual control. This may be a result of increased attention being paid to froth flotation as a result of this project.

  19. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1991-01-01

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no new'' reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  20. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    SciTech Connect

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  1. 76 FR 55837 - Workshops To Discuss Revisions to Federal and Indian Coal Valuation Regulations: Advance Notice...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-09

    ... Revisions to Federal and Indian Coal Valuation Regulations: Advance Notice of Proposed Rulemaking AGENCY... existing royalty valuation regulations at 30 CFR parts 1202 and 1206 for coal produced from Federal and..., Colorado 80226, telephone number (303) 231-3585. Workshop 2--Marriott St. Louis Airport, 10700 Pear...

  2. Process for forming coal compacts and product thereof

    DOEpatents

    Gunnink, Brett; Kanunar, Jayanth; Liang, Zhuoxiong

    2002-01-01

    A process for forming durable, mechanically strong compacts from coal particulates without use of a binder is disclosed. The process involves applying a compressive stress to a particulate feed comprising substantially water-saturated coal particles while the feed is heated to a final compaction temperature in excess of about 100.degree. C. The water present in the feed remains substantially in the liquid phase throughout the compact forming process. This is achieved by heating and compressing the particulate feed and cooling the formed compact at a pressure sufficient to prevent water present in the feed from boiling. The compacts produced by the process have a moisture content near their water saturation point. As a result, these compacts absorb little water and retain exceptional mechanical strength when immersed in high pressure water. The process can be used to form large, cylindrically-shaped compacts from coal particles (i.e., "coal logs") so that the coal can be transported in a hydraulic coal log pipeline.

  3. Technical, Energetics, and Economic Comparison of NRL Oxidative Coal Liquefaction Process with some Developed Coal Liquefaction Processes.

    DTIC Science & Technology

    1980-03-05

    the synthesis step becomes two processes. synthesis CO + H2 catalyst ) methanol conversion methanol catalyst > gasoline + water Wiser states that...structure illustrates the main types of linkage between ring clusters and also some of the heteroatom forms that are found in coal. 20 APPENDIX II...used more widely as petroleum and natural gas resources are depleted and hydrogen for coal liquefaction processes will be produced predominantly from

  4. Co-processing of agriculture and biomass waste with coal

    SciTech Connect

    Stiller, A.H.; Dadyburjor, D.B.; Wann, J.P.

    1995-12-01

    Biomass and bio-processed waste are potential candidates for co-liquefaction with coal. Specific materials used here include sawdust and poultry manure. Liquefaction experiments were run on each of these materials, separately and with coal, using tetralin as solvent at 350{degrees}C and 1000 psi(cold) hydrogen pressure for 1h. Total conversion was monitored, as well as conversion to asphaltenes, oils and gases. All the biomass samples are converted to oils and gases under the reaction conditions. Poultry manure seems to convert coal more completely, and to produce more oils and gases, than conventional liquefaction.

  5. Process for removal of hazardous air pollutants from coal

    DOEpatents

    Akers, David J.; Ekechukwu, Kenneth N.; Aluko, Mobolaji E.; Lebowitz, Howard E.

    2000-01-01

    An improved process for removing mercury and other trace elements from coal containing pyrite by forming a slurry of finely divided coal in a liquid solvent capable of forming ions or radicals having a tendency to react with constituents of pyrite or to attack the bond between pyrite and coal and/or to react with mercury to form mercury vapors, and heating the slurry in a closed container to a temperature of at least about 50.degree. C. to produce vapors of the solvent and withdrawing vapors including solvent and mercury-containing vapors from the closed container, then separating mercury from the vapors withdrawn.

  6. Hydrogen-donor coal liquefaction process

    DOEpatents

    Wilson, Jr., Edward L.; Mitchell, Willard N.

    1980-01-01

    Improved liquid yields are obtained during the hydrogen-donor solvent liquefaction of coal and similar carbonaceous solids by maintaining a higher concentration of material having hydrogenation catalytic activity in the downstream section of the liquefaction reactor system than in the upstream section of the system.

  7. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOEpatents

    MacArthur, James B.; McLean, Joseph B.; Comolli, Alfred G.

    1989-01-01

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  8. Method for increasing steam decomposition in a coal gasification process

    DOEpatents

    Wilson, M.W.

    1987-03-23

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  9. Method for increasing steam decomposition in a coal gasification process

    DOEpatents

    Wilson, Marvin W.

    1988-01-01

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  10. Control of pyrite addition in coal liquefaction process

    DOEpatents

    Schmid, Bruce K.; Junkin, James E.

    1982-12-21

    Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the C.sub.5 --900.degree. F. (482.degree. C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and thus reduce pyrite contribution to the slurry pumping load and disposal problems connected with pyrite produced slag.

  11. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 6, January--March 1994

    SciTech Connect

    Smit, F.J.; Rowe, R.M.; Anast, K.R.; Jha, M.C.

    1994-05-06

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effectve replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States as well as for advanced combustars currently under development. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals fbr clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 51-month program which started on September 30, 1992. This report discusses the technical progress, made during the 6th quarter of the project from January 1 to March 31, 1994. The project has three major objectives: (1) The primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) A secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics. (3) A third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  12. 40 CFR 60.254 - Standards for coal processing and conveying equipment, coal storage systems, transfer and loading...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for coal processing and conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. 60.254... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Coal...

  13. 40 CFR 60.254 - Standards for coal processing and conveying equipment, coal storage systems, transfer and loading...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for coal processing and conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. 60.254... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Coal...

  14. Advanced solids NMR studies of coal structure and chemistry. Progress report, March 1 - September 1, 1996

    SciTech Connect

    Zilm, K.W.

    1996-12-31

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utili- zation of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. Our goals are twofold. First, we are interested in developing new methods that will enable us to measure important structural parameters in whole coals not directly accessible by other techniques. In parallel with these efforts we will apply these NNM methods in a study of the chemical differences between gas-sourcing and oil-sourcing coals. The NMR methods work will specifically focus on determination of the number and types of methylene groups, determination of the number and types of methine groups, identification of carbons adjacent to nitrogen and sites with exchangeable protons, and methods to more finely characterize the distribution of hydrogen in coals. We will also develop NMR methods for probing coal macropore structure using hyperpolarized {sup 29}Xe as a probe, and study the molecular dynamics of what appear to be mobile, CH{sub 2} rich, long chain hydrocarbons. The motivation for investigating these specific structural features of coals arises from their relevance to the chemical reactivity of coals, and their suitability for possible correlations with the oil sourcing potential of some types of coals. The coals to be studied and contrasted include oil-prone coals from Australia and Indonesia, those comprising the Argonne Premium Coal Sample bank, and other relevant samples.

  15. Optimization of the process of plasma ignition of coal

    SciTech Connect

    Peregudov, V.S.

    2009-04-15

    Results are given of experimental and theoretical investigations of plasma ignition of coal as a result of its thermochemical preparation in application to the processes of firing up a boiler and stabilizing the flame combustion. The experimental test bed with a commercial-scale burner is used for determining the conditions of plasma ignition of low-reactivity high-ash anthracite depending on the concentration of coal in the air mixture and velocity of the latter. The calculations produce an equation (important from the standpoint of practical applications) for determining the energy expenditure for plasma ignition of coal depending on the basic process parameters. The tests reveal the difficulties arising in firing up a boiler with direct delivery of pulverized coal from the mill to furnace. A scheme is suggested, which enables one to reduce the energy expenditure for ignition of coal and improve the reliability of the process of firing up such a boiler. Results are given of calculation of plasma thermochemical preparation of coal under conditions of lower concentration of oxygen in the air mixture.

  16. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 15, April--June 1996

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-07-25

    Goal is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Scope includes laboratory research and bench-scale testing on 6 coals to optimize these processes, followed by design/construction/operation of a 2-t/hr PDU. During this quarter, parametric testing of the 30-in. Microcel{trademark} flotation column at the Lady Dunn plant was completed and clean coal samples submitted for briquetting. A study of a novel hydrophobic dewatering process continued at Virginia Tech. Benefits of slurry PSD (particle size distribution) modification and pH adjustment were evaluated for the Taggart and Hiawatha coals; they were found to be small. Agglomeration bench-scale test results were positive, meeting product ash specifications. PDU Flotation Module operations continued; work was performed with Taggart coal to determine scaleup similitude between the 12-in. and 6-ft Microcel{trademark} columns. Construction of the PDU selective agglomeration module continued.

  17. Engineering development of advanced physical fine coal cleaning technologies - froth flotation

    SciTech Connect

    Ferris, D.D.; Bencho, J.R.

    1995-11-01

    In 1988, ICF Kaiser Engineers was awarded DOE Contract No. DE-AC22-88PC88881 to research, develop, engineer and design a commercially acceptable advanced froth flotation coal cleaning technology. The DOE initiative is in support of the continued utilization of our most abundant energy resource. Besides the goal of commercialability, coal cleaning performance and product quality goals were established by the DOE for this and similar projects. primary among these were the goals of 85 percent energy recovery and 85 percent pyrite rejection. Three nationally important coal resources were used for this project: the Pittsburgh No. 8 coal, the Upper Freeport coal, and the Illinois No. 6 coal. Following is a summary of the key findings of this project.

  18. Coal gasification power plant and process

    DOEpatents

    Woodmansee, Donald E.

    1979-01-01

    In an integrated coal gasification power plant, a humidifier is provided for transferring as vapor, from the aqueous blowdown liquid into relatively dry air, both (I) at least a portion of the water contained in the aqueous liquid and (II) at least a portion of the volatile hydrocarbons therein. The resulting humidified air is advantageously employed as at least a portion of the hot air and water vapor included in the blast gas supplied via a boost compressor to the gasifier.

  19. Power recovery system for coal liquefaction process

    DOEpatents

    Horton, Joel R.

    1985-01-01

    Method and apparatus for minimizing energy required to inject reactant such as coal-oil slurry into a reaction vessel, using high pressure effluent from the latter to displace the reactant from a containment vessel into the reaction vessel with assistance of low pressure pump. Effluent is degassed in the containment vessel, and a heel of the degassed effluent is maintained between incoming effluent and reactant in the containment vessel.

  20. Hydrogen donor solvent coal liquefaction process

    DOEpatents

    Plumlee, Karl W.

    1978-01-01

    An indigenous hydrocarbon product stream boiling within a range of from about C.sub.1 -700.degree. F., preferably C.sub.1 -400.degree. F., is treated to produce an upgraded hydrocarbon fuel component and a component which can be recycled, with a suitable donor solvent, to a coal liquefaction zone to catalyze the reaction. In accordance therewith, a liquid hydrocarbon fraction with a high end boiling point range up to about 700.degree. F., preferably up to about 400.degree. F., is separated from a coal liquefaction zone effluent, the separated fraction is contacted with an alkaline medium to provide a hydrocarbon phase and an aqueous extract phase, the aqueous phase is neutralized, and contacted with a peroxygen compound to convert indigenous components of the aqueous phase of said hydrocarbon fraction into catalytic components, such that the aqueous stream is suitable for recycle to the coal liquefaction zone. Naturally occurring phenols and alkyl substituted phenols, found in the aqueous phase, are converted, by the addition of hydroxyl constituents to phenols, to dihydroxy benzenes which, as disclosed in copending Application Ser. Nos. 686,813 now U.S. Pat. No. 4,049,536; 686,814 now U.S. Pat. No. 4,049,537; 686,827 now U.S. Pat. No. 4,051,012 and 686,828, K. W. Plumlee et al, filed May 17, 1976, are suitable hydrogen transfer catalysts.

  1. Supercritical Fluid Reactions for Coal Processing

    SciTech Connect

    Eckert, Charles A

    1997-07-01

    Exciting opportunities exist for the application of supercritical fluid (SCF) reactions for the pre-treatment of coal. Utilizing reactants which resemble the organic nitrogen containing components of coal, we propose to develop a method to tailor chemical reactions in supercritical fluid solvents for the specific application of coal denitrogenation. The Diels-Alder reaction of anthracene and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) was chosen as the model system and was investigated in supercritical carbon dioxide. Kinetic data have been previously collected for pure CO2 at 40C and pressures between the critical pressure of CO2 (73.8 bar) and 216 bar. These data support the theory of local density enhancements suggested in the literature. Data taken at 50C and pressures ranging from 70 bar to 195 bar are currently reported; they do not exhibit the molecular clustering evident closer to the critical temperature. The data taken at 40C are now being used to construct mathematical forms which can model these pressure-induced kinetic changes. One promising avenue of investigation involves treating the supercritical medium as a dense gas, which allows a kinetic model based on high reference pressure fugacity coefficients to be derived.

  2. Plasma Processing of Advanced Materials

    SciTech Connect

    Heberlein, Joachim, V.R.; Pfender, Emil; Kortshagen, Uwe

    2005-02-28

    Plasma Processing of Advanced Materials The project had the overall objective of improving our understanding of the influences of process parameters on the properties of advanced superhard materials. The focus was on high rate deposition processes using thermal plasmas and atmospheric pressure glow discharges, and the emphasis on superhard materials was chosen because of the potential impact of such materials on industrial energy use and on the environment. In addition, the development of suitable diagnostic techniques was pursued. The project was divided into four tasks: (1) Deposition of superhard boron containing films using a supersonic plasma jet reactor (SPJR), and the characterization of the deposition process. (2) Deposition of superhard nanocomposite films in the silicon-nitrogen-carbon system using the triple torch plasma reactor (TTPR), and the characterization of the deposition process. (3) Deposition of films consisting of carbon nanotubes using an atmospheric pressure glow discharge reactor. (4) Adapting the Thomson scattering method for characterization of atmospheric pressure non-uniform plasmas with steep spatial gradients and temporal fluctuations. This report summarizes the results.

  3. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly progress report, July--September 1993

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1993-12-31

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The primary coal of this program, Black Thunder subbituminous coal, can be effectively beneficiated to about 3.5 wt % ash using aqueous sulfurous acid pretreatment. This treated coal can be further beneficiated to about 2 wt % ash using commercially available procedures. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated subbituminous coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent. The study of bottoms processing consists of combining the ASCOT process which consists of coupling solvent deasphalting with delayed coking to maximize the production of coal-derived liquids while rejecting solids within the coke drum. The asphalt production phase has been completed; representative product has been evaluated. The solvent system for the deasphalting process has been established. Two ASCOT tests produced overall liquid yields (63.3 wt % and 61.5 wt %) that exceeded the combined liquid yields from the vacuum tower and ROSE process.

  4. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    SciTech Connect

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  5. Systems Analysis Of Advanced Coal-Based Power Plants

    NASA Technical Reports Server (NTRS)

    Ferrall, Joseph F.; Jennings, Charles N.; Pappano, Alfred W.

    1988-01-01

    Report presents appraisal of integrated coal-gasification/fuel-cell power plants. Based on study comparing fuel-cell technologies with each other and with coal-based alternatives and recommends most promising ones for research and development. Evaluates capital cost, cost of electricity, fuel consumption, and conformance with environmental standards. Analyzes sensitivity of cost of electricity to changes in fuel cost, to economic assumptions, and to level of technology. Recommends further evaluation of integrated coal-gasification/fuel-cell integrated coal-gasification/combined-cycle, and pulverized-coal-fired plants. Concludes with appendixes detailing plant-performance models, subsystem-performance parameters, performance goals, cost bases, plant-cost data sheets, and plant sensitivity to fuel-cell performance.

  6. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    B.K. PAREKH; D. TAO; J.G. GROPPO

    1998-02-03

    The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

  7. 30 CFR 784.25 - Return of coal processing waste to abandoned underground workings.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Return of coal processing waste to abandoned... ENFORCEMENT, DEPARTMENT OF THE INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL... RECLAMATION AND OPERATION PLAN § 784.25 Return of coal processing waste to abandoned underground workings....

  8. Thermodynamic analysis of the process of formation of sulfur compounds in oxygen gasification of coal

    SciTech Connect

    G.Ya. Gerasimov; T.M. Bogacheva

    2001-05-15

    A thermodynamic approach to the description of the behavior of the system fuel-oxidizer in oxygen gasification of coal is used to reveal the main mechanisms of the process of capture of sulfur by the mineral part of the coal and to determine the fundamental possibility of the process for coals from different coal fields.

  9. 30 CFR 784.25 - Return of coal processing waste to abandoned underground workings.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Return of coal processing waste to abandoned... ENFORCEMENT, DEPARTMENT OF THE INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL... RECLAMATION AND OPERATION PLAN § 784.25 Return of coal processing waste to abandoned underground workings....

  10. 30 CFR 784.25 - Return of coal processing waste to abandoned underground workings.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Return of coal processing waste to abandoned... ENFORCEMENT, DEPARTMENT OF THE INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL... RECLAMATION AND OPERATION PLAN § 784.25 Return of coal processing waste to abandoned underground workings....

  11. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 3, April--June 1993

    SciTech Connect

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-07-28

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the quarter from April 1 to June 30, 1993. The project has three major objectives: (1) the primary objective is to develop the design base for prototype commercial advanced fine coal cleaning facilities capable of producing ultra-clean coals suitable for conversion to coal-water slurry fuel for premium fuel applications. The fine coal cleaning technologies are advanced column flotation and selective agglomeration. (2) a secondary objective is to develop the design base for near-term application of these advanced fine coal cleaning technologies in new or existing coal preparation plants for efficiently processing minus 28-mesh coal fines and converting this to marketable products in current market economics; and (3) a third objective is to determine the removal of toxic trace elements from coal by advance column flotation and selective agglomeration technologies.

  12. Fluidized bed catalytic coal gasification process

    DOEpatents

    Euker, Jr., Charles A.; Wesselhoft, Robert D.; Dunkleman, John J.; Aquino, Dolores C.; Gouker, Toby R.

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  13. Process for reducing sulfur in coal char

    DOEpatents

    Gasior, Stanley J.; Forney, Albert J.; Haynes, William P.; Kenny, Richard F.

    1976-07-20

    Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

  14. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Technical progress report, Run 243 with Illinois 6 coal

    SciTech Connect

    Not Available

    1984-02-01

    This report presents the operating results for Run 243 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary objective was to demonstrate the effect of a dissolver on the ITSL product slate, especially on the net C/sub 1/-C/sub 5/ gas production and hydrogen consumption. Run 243 began on 3 February 1983 and continued through 28 June 1983. During this period, 349.8 tons of coal was fed in 2947 hours of operation. Thirteen special product workup material balances were defined, and the results are presented herein. 29 figures, 19 tables.

  15. Design Fuels Corporation (DFC)-Apache, Inc. coal reclamation system for the plant of the future for processing clean coal

    SciTech Connect

    Hoppe, J.; Karsnak, G.

    1998-12-31

    The mechanical washing processing and drying portion of the DFC process offers an efficient method for cleaning of pyritic sulfur bearing compounds which represents 25% sulfur reduction from original run-of-mine coal quality. This reduction can be augmented with the use of calcium and sodium based compounds to reduce the sulfur in many coals to produce compliance quality coal. The use of mechanical/physical methods for the removal of the pyritic material found in coal is used by the DFC process as a first step to the final application of a complete coal refuse clean-up technology based on site specific conditions of the parent coal. The paper discusses the use of the DFC process to remediate slurry ponds and tailings piles and to improve coal cleaning by gravity separation methods, flotation, hydrocyclones and spiral separators, dense media separation, water only cyclones, and oil/solvent agglomeration. A typical DFC Project is the Rosa Coal Reclamation Project which involves the development of a bituminous coal waste impoundment reclamation and washery system. The plant would be located adjacent to a coal fines pond or tailings pond and refuse pile or gob pile at a former coal strip mine in Oneonta, Alabama. Design Fuels would provide a development program by which coal waste at the Rosa Mine could be reclaimed, cleaned and sold profitably. This feedstock could be furnished from recovered coal for direct use in blast furnaces, or as feedstock for coke ovens at 250,000 tons per year at an attractive price on a 10-year contract basis. The site has an old coal washing facility on the property that will be dismantled. Some equipment salvage has been considered; and removal of the existing plant would be the responsibility of Design Fuels. The paper briefly discusses the market potential of the process.

  16. Advanced Information Processing System (AIPS)

    NASA Technical Reports Server (NTRS)

    Pitts, Felix L.

    1993-01-01

    Advanced Information Processing System (AIPS) is a computer systems philosophy, a set of validated hardware building blocks, and a set of validated services as embodied in system software. The goal of AIPS is to provide the knowledgebase which will allow achievement of validated fault-tolerant distributed computer system architectures, suitable for a broad range of applications, having failure probability requirements of 10E-9 at 10 hours. A background and description is given followed by program accomplishments, the current focus, applications, technology transfer, FY92 accomplishments, and funding.

  17. Advances in natural language processing.

    PubMed

    Hirschberg, Julia; Manning, Christopher D

    2015-07-17

    Natural language processing employs computational techniques for the purpose of learning, understanding, and producing human language content. Early computational approaches to language research focused on automating the analysis of the linguistic structure of language and developing basic technologies such as machine translation, speech recognition, and speech synthesis. Today's researchers refine and make use of such tools in real-world applications, creating spoken dialogue systems and speech-to-speech translation engines, mining social media for information about health or finance, and identifying sentiment and emotion toward products and services. We describe successes and challenges in this rapidly advancing area.

  18. Advanced technology applications for second and third generation coal gasification systems. Appendix

    NASA Technical Reports Server (NTRS)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    Sixteen coal conversion processes are described and their projected goals listed. Tables show the reactants used, products derived, typical operating data, and properties of the feed coal. A history of the development of each process is included along with a drawing of the chemical reactor used.

  19. A coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Phase III development contract DE-AC22-91PC91161 for a Coal-Fired Combustion System for Industrial Process Heating Applications'' is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec's Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  20. U-GAS process for production of hydrogen from coal

    SciTech Connect

    Dihu, R.J.; Patel, J.G.

    1982-01-01

    Today, hydrogen is produced mainly from natural gas and petroleum fractions. Tomorrow, because reserves of natural gas and oil are declining while demand continues to increase, they cannot be considered available for long-term, large-scale production of hydrogen. Hydrogen obtained from coal is expected to be the lowest cost, large-scale source of hydrogen in the future. The U-GAS coal gasification process and its potential application to the manufacture of hydrogen is discussed. Pilot plant results, the current status of the process, and economic projections for the cost of hydrogen manufactured are presented.

  1. A synoptic description of coal basins via image processing

    NASA Technical Reports Server (NTRS)

    Farrell, K. W., Jr.; Wherry, D. B.

    1978-01-01

    An existing image processing system is adapted to describe the geologic attributes of a regional coal basin. This scheme handles a map as if it were a matrix, in contrast to more conventional approaches which represent map information in terms of linked polygons. The utility of the image processing approach is demonstrated by a multiattribute analysis of the Herrin No. 6 coal seam in Illinois. Findings include the location of a resource and estimation of tonnage corresponding to constraints on seam thickness, overburden, and Btu value, which are illustrative of the need for new mining technology.

  2. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 8, July 1994--September 1994

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1994-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2 t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 8 (July - September, 1994), work on the formulation of coal water slurries from flotation concentrates was completed. Parametric and optimization tests were performed on the Indiana VII coal using a 12-inch MicrocelT{sup M} flotation column. Laboratory research on selective agglomeration was completed with limited testing of the Dietz coal and alternate agglomerants. Initial planning has started for the bench-scale agglomeration unit which will utilize heptane as the bridging liquid in a conventional two-stage system, and steam stripping for heptane recovery and recycle. A project review meeting was held at Bechtel to discuss the detailed design of the PDU, which is being designed to process Indiana VII, Sunnyside, and Taggart coals. Process flow, piping and instrument, and equipment layout diagrams are being revised to reflect the process improvements resulting from bench-scale testing. Material Requisition activity has commenced, and will continue next quarter along with the selection of a construction subcontractor.

  3. Advanced coal-fueled gas turbine systems. Final report

    SciTech Connect

    Not Available

    1993-08-01

    The configuration of the subscale combustor has evolved during the six years of this program from a system using only an impact separator to remove particulates to a system which also included a slagging cyclone separator before the lean-quench combustor. The system also now includes active slag tapping after the impact separator rather than a bucket to collect the slag. The subscale 12 MM Btu/hr (higher heating value, HHV) slagging combustor has demonstrated excellent coal-fired operation at 6 atm. The combustor has fired both coal-water mixtures (CWM) and pulverized coal (PC). Three Wyoming subbituminous coals and two bituminous coals have been successfully fired in the TVC. As a result of this active testing, the following conclusions may be drawn: (1) it was possible to achieve the full design thermal capacity of 12 MM Btu/hr with the subscale slagging combustor, while burning 100% pulverized coal and operating at the design pressure of 6 atm; (2) because of the separate-chamber, rich-lean design of the subscale slagging combustor, NO{sub x} emissions that easily meet the New Source Performance Standards (NSPS) limits were achieved; (3) carbon burnout efficiency was in excess of 99% when 100% coal-fired; (4) ninety percent of the ash can be separated as slag in the impact separator, and a total 98 to 99% removed with the addition of the slagging cyclone separator; (5) Objectives for third-stage exit temperature (1850{degrees}F), and exit temperature pattern factor (14%) were readily achieved; (6) overall pressure loss is currently an acceptable 5 to 6% without cyclone separator and 7 to 9% with the cyclone; and (7) feeding pulverized coal or sorbent into the combustor against 6 atm pressure is achievable.

  4. The development of a coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  5. An Advanced Control System for Fine Coal Floatation

    SciTech Connect

    Luttrell, G H; Adel, G T

    1998-06-01

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the eighth quarter of this project, the analysis of data collected during Task 2 (Sampling and Data Analysis) was completed, and significant progress was made on Task 3 (Model Building and Computer Simulation). Previously, a plant sampling campaign had been conducted at Pittston's Moss No. 3 preparation plant to provide data for the development of a mathematical process model and a model-based control system. During this campaign, a one-half factorial design experiment, blocked into low and high feed rates, was conducted to investigate the effects of collector, frother, and pulp level on model parameters. In addition, samples were collected during the transient period following each change in the manipulated variables to provide data for confirmation of the dynamic process simulator. A residence time distribution (RTD) test was also conducted to estimate the mean residence time. This is a critical piece of information since no feed flowrate measurement is available, and the mean residence time can be used to estimate the feed flowrate. Feed samples were taken at timed intervals and floated in a laboratory flotation cell to investigate the magnitude of feed property disturbances and their duration.

  6. Process and catalyst for the hydrogenation of coal

    SciTech Connect

    Wernicke, H.J.; Zimmerman, H.

    1985-05-07

    Blast furnace flue dust is used as a catalyst in a process for the hydrogenation of coal. A flowable mixture of finely divided coal particles and liquid hydrocarbons is brought to high pressure and to reaction temperature. The mixture is hydrogenated with hydrogen in the presence of blast furnace dust as a hydrogenation catalyst. The cost-effective hydrogenation catalyst is reused profitably subsequent to application in the coal hydrogenation process. Gaseous products are separated from liquid and solid reaction products. Liquid products are vaporized and are fractionated under atmospheric pressure and under vacuum. Hydrogen for use in the hydrogenation is produced by partial oxidation of the residue, and the catalyst is deposited as slag, which is returned to the blast furnace.

  7. Upgraded Coal Interest Group

    SciTech Connect

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  8. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect

    Not Available

    1991-09-01

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  9. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.

    1989-10-01

    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, Cold Flow Burner Development''. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  10. Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

    DOEpatents

    Sheldon, Ray W.

    2001-01-01

    The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

  11. Application studies of RFID technology in the process of coal logistics transport

    NASA Astrophysics Data System (ADS)

    Qiao, Bingqin; Chang, Xiaoming; Hao, Meiyan; Kong, Dejin

    2012-04-01

    For quality control problems in coal transport, RFID technology has been proposed to be applied to coal transportation process. The whole process RFID traceability system from coal production to consumption has been designed and coal supply chain logistics tracking system integration platform has been built, to form the coal supply chain traceability and transport tracking system and providing more and more transparent tracking and monitoring of coal quality information for consumers of coal. Currently direct transport and combined transport are the main forms of coal transportation in China. The means of transport are cars, trains and ships. In the booming networking environment of RFID technology, the RFID technology will be applied to coal logistics and provide opportunity for the coal transportation tracking in the process transportation.

  12. Development of advanced NO[sub x] control concepts for coal-fired utility boilers

    SciTech Connect

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-03-04

    The complete CombiNO[sub x], process has now been demonstrated at a level that is believed to be representative of a full-scale boiler in terms of mixing capabilities. A summary of the results is displayedin Figure 5-1. While firing Illinois Coal on the Reburn Tower, Advanced Reburning was capable of reducing NO[sub x], by 83 percent. The injection of methanol oxidized 50--58 percent of the existing NO to N0[sub 2]. Assuming that 85 percent of the newly formed N0[sub 2] can be scrubbed in a liquor modified wet-limestone scrubber, the CombiNO[sub x], process has been shown capable of reducing NO[sub 2], by 90--91 percent in a large pilot-scale coal-fired furnace. There is still uncertainty regarding the fate of the N0[sub 2] formed with methanol injection. Tests should be conducted to determine whether the reconversion is thermodynamic or catalytic, and what steps can be taken (such as quench rate) to prevent it from happening.

  13. Coal gasification via the Lurgi process: Topical report: Volume 1, Production of SNG (substitute material gas)

    SciTech Connect

    Zahnstecher, L.W.

    1984-09-01

    A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of substitute natural gas (SNG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based on a mine mouth plant producing 250 billion Btu (HHV) per day of SNG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant food, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated facility which utilizes coal, air, and water to produce 250 billion Btu (HHV) per day of SNG. The plant consists of coal handling and preparation, twenty-six Lurgi dry bottom gasifiers, shift conversion, acid gas removal, methanation, compression and drying of product gas, sulfur recovery, phenol and ammonia recovery, as well as necessary support facilities. The plant is a grass roots, mine mouth facility located in a Western location similar to the town of Colstrip in Rosebud County, Montana. The Lurgi Corporation assisted in this study, under subcontract to Foster Wheeler, by supplying the heat and material balances, flow sheets, utilities, catalysts and chemical requirements, and cost data for Lurgi designed process sections. Details of material supplied by Lurgi Corporation are presented in Appendix A. 52 refs., 36 figs., 64 tabs.

  14. Advanced NMR approaches in the characterization of coal

    SciTech Connect

    Maciel, G.E.

    1992-01-01

    The paper submitted earlier on the use of (bicyclo[3.2.1]4pyrrolidino-N-methyl-octan-8-one triflate) ([sup 13]CO-123) as a [sup 13]C intensity standard was accepted for publication. Subsequently, [sup 13]CO-321 was used in this manner for quantitative [sup 13]C CP-MAS NMR analysis (including spin counting) of Argonne Premium coals. The cross-polarization time constants, T[sub CH], and the rotating-frame proton spin-lattice relaxation times, T[sub 1p][sup H], were determined for each major peak of each coal via a combination of variable contact-time and variable spin-lock (T[sub 1p][sup H]) experiments. Two or three components of rotating-frame [sup 1]H relaxation decay and two or three components of T[sub CH] behavior were observed for each major [sup 13]C peak of each coal. These data were used to determine the number of carbon atoms detected in each coal; these values are in the range between 77% and 87% of the amount of carbon known to be in each coal from elemental analysis data, except for Pocahontas No. 3, for which only 50% of the carbon was detected. In an attempt to use [sup 1]H CRAMPS to elucidate chemical functionality in coal, pyridine-saturated samples of the Argonne Premium coals were examined in detail in terms of their [sup 1]H CRAMPS NMR spectra. These spectra were deconvoluted to yield relative concentrations for individual peaks.

  15. Subtask 3.9 - Direct Coal Liquefaction Process Development

    SciTech Connect

    Aulich, Ted; Sharma, Ramesh

    2012-07-01

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  16. Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

  17. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect

    Not Available

    1990-05-01

    This reports presents the operating results for Run 252 at the Advanced Coal Liquefaction R D Facility in Wilsonville, Alabama. This run operated in the Close-Coupled Integrated Two-Stage Liquefaction mode (CC-ITSL) using Illinois No. 6 bituminous coal. The primary run objective was demonstration of unit and system operability in the CC-ITSL mode with catalytic-catalytic reactors and with ash recycle. Run 252 began on 26 November 1986 and continued through 3 February 1987. During this period 214.4 MF tons of Illinois No. 6 coal were fed in 1250 hours of operation. 3 refs., 29 figs., 18 tabs.

  18. Short residence time coal liquefaction process including catalytic hydrogenation

    DOEpatents

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -454.degree. C. is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance.

  19. Short residence time coal liquefaction process including catalytic hydrogenation

    DOEpatents

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone, the hydrogen pressure in the preheating-reaction zone being at least 1,500 psig (105 kg/cm[sup 2]), reacting the slurry in the preheating-reaction zone at a temperature in the range of between about 455 and about 500 C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid to substantially immediately reduce the temperature of the reaction effluent to below 425 C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C[sub 5]-454 C is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent. The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. 6 figs.

  20. Process for hydroliquefying coal or like carbonaceous solid materials

    DOEpatents

    Malek, John Michael

    1977-01-01

    In this process the products of the dissolution-hydrogenation of coal or the like material in a hydrocarbon rich solvent are subjected in their slurryform fraction to an asphaltenes decomposing action of an alkali, like caustic soda or, being admixed after the gasiform fraction of the hydrogenation products has been taken off the slurryform fraction of the hydrogenation products now including the admixed alkali is subjected to a rehydrogenation by a hydrogen rich gas which after its rehydrogenating use is preferably applied, as source of hydrogen, to said dissolution-hydrogenation of coal. Optionally the admixed alkali includes minor amounts of a carboxylic acid salt of calcium.

  1. Co-processing of agricultural and biomass waste with coal

    SciTech Connect

    Stiller, A.H.; Dadyburjor, D.B.; Wann, Ji-Perng

    1995-12-31

    A major thrust of our research program is the use of waste materials as co-liquefaction agents for the first-stage conversion of coal to liquid fuels. By fulfilling one or more of the roles of an expensive solvent in the direct coal liquefaction (DCL) process, the waste material is disposed off ex-landfill, and may improve the overall economics of DCL. Work in our group has concentrated on co-liquefaction with waste rubber tires, some results from which are presented elsewhere in these Preprints. In this paper, we report on preliminary results with agricultural and biomass-type waste as co-liquefaction agents.

  2. Liquid products derived from brown coal in BCL process

    SciTech Connect

    Okuma, O.; Yanai, S.; Komatsu, N.

    1999-07-01

    The BCL (Brown Coal Liquefaction) process developed for Victorian brown coal is a two-stage liquefaction process which consists of 4 unit sections: dewatering, primary hydrogenation (PH), solvent de-ashing (DA) and secondary hydrogenation (SH). The liquid products produced in the PH and SH sections are distillates with b.p. < 420 C and with b.p. < 240 C, respectively, and their properties are different due to differences in the hydrogenation conditions and activities of catalysts used. The former contains much aromatic and hetero-atom-containing compounds than the latter. This paper reveals the yields and properties of the liquid products derived from the brown coal in the BCL process, and the compounds in these products that were analyzed by GC/MC and capillary GC. This paper discusses the change in the compounds in the solvent fraction during recycling and the effects of PH conditions on the naphtha. In addition, the results of hydrogenation of the vaporized fraction in gas-liquid separator of the PH section are also discussed to simplify the BCL process. These results are useful as basic data for production of chemicals from the coal-derived liquids.

  3. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect

    Calderon, A.; Madison, E.; Probert, P.

    1992-01-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H[sub 2] mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO[sub x] (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  4. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect

    Calderon, A.; Madison, E.; Probert, P.

    1992-11-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H{sub 2} mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO{sub x} (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  5. Main trends in the biotechnological processing of coals: a review

    SciTech Connect

    I.P. Ivanov

    2007-02-15

    A review of the literature concerning the studies of the biotechnological processing of coal in Russia and abroad is presented. This environmentally safe technology is demonstrated to be promising for the conversion of solid fossil fuels into valuable fuel and chemical products. 73 refs.

  6. Co-processing of residual oil and coal

    SciTech Connect

    Audeh, C.A.

    1983-04-05

    Visbreaking a mixture of petroleum residuum, coal and catalytic cracking catalyst under conditions severe enough to effect conversion but not so severe as to produce substantial quantities of coke produces a range of products including gaseous olefins and gasoline distillate. The solids recovered from the visbreaking operation can be processed to produce a synthesis gas of carbon monoxide and hydrogen.

  7. Coal Gasification Processes for Retrofitting Military Central Heating Plants: Overview

    DTIC Science & Technology

    1992-11-01

    the product gas and convened to elemental sulfur by the Claus or wet oxidation processes. It is easier to remove sulfur in the form of H2S rather than...The wet oxidation process is generally more economical than the Claus process because of the low H2S content (usually less than 5 percent) in the cold...is carried out with the product gases. The fluidized-bed gasifier generally cannot handle highly caking coals without an oxidative pretreatment step

  8. Distribution and leaching ability of some heavy metals in products of flotation processing of fine-grained coal slurries

    SciTech Connect

    Klika, Z.; Weiss, Z.; Lach, K.

    1994-12-31

    Coal from the Ostrava-Karvina mines is processed in 19 coal preparation plants, 6 of which are not equipped with flotation technology. Generally, all fine-grained coal is transported into sedimentary coal slurry ponds. Depending on processing technology, coal slurries contain from 5 to 95% coal matter. Sedimentary coal slurry ponds occupy large areas, deteriorate the landscape, and ar great sources of dust in a dry summer. Moreover, some components from coal slurries scan be leached and can penetrate into underground water. This research project sampled 13 coal slurry ponds to determine the composition of coal slurries, the distribution of some heavy metals in the flotation process, and leaching behavior.

  9. Electrochromic Windows: Advanced Processing Technology

    SciTech Connect

    SAGE Electrochromics, Inc

    2006-12-13

    This project addresses the development of advanced fabrication capabilities for energy saving electrochromic (EC) windows. SAGE EC windows consist of an inorganic stack of thin films deposited onto a glass substrate. The window tint can be reversibly changed by the application of a low power dc voltage. This property can be used to modulate the amount of light and heat entering buildings (or vehicles) through the glazings. By judicious management of this so-called solar heat gain, it is possible to derive significant energy savings due to reductions in heating lighting, and air conditioning (HVAC). Several areas of SAGE’s production were targeted during this project to allow significant improvements to processing throughput, yield and overall quality of the processing, in an effort to reduce the cost and thereby improve the market penetration. First, the overall thin film process was optimized to allow a more robust set of operating points to be used, thereby maximizing the yield due to the thin film deposition themselves. Other significant efforts aimed at improving yield were relating to implementing new procedures and processes for the manufacturing process, to improve the quality of the substrate preparation, and the quality of the IGU fabrication. Furthermore, methods for reworking defective devices were developed, to enable devices which would otherwise be scrapped to be made into useful product. This involved the in-house development of some customized equipment. Finally, the improvements made during this project were validated to ensure that they did not impact the exceptional durability of the SageGlass® products. Given conservative estimates for cost and market penetration, energy savings due to EC windows in residences in the US are calculated to be of the order 0.026 quad (0.026×1015BTU/yr) by the year 2017.

  10. An Advanced Control System For Fine Coal Flotation

    SciTech Connect

    G. H. Luttrell; G. T. Adel

    1998-08-25

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as collector dosage, frother dosage, and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the ninth quarter of this project, Task 3 (Model Building and Computer Simulation) and Task 4 (Sensor Testing) were nearly completed, and Task 6 (Equipment Procurement and Installation) was initiated. Previously, data collected from the plant sampling campaign (Task 2) were used to construct a population balance model to describe the steady-state and dynamic behavior of the flotation circuit. The details of this model were presented in the Eighth Quarterly Technical Progress Report. During the past quarter, a flotation circuit simulator was designed and used to evaluate control strategies. As a result of this work, a model-based control strategy has been conceived which will allow manipulated variables to be adjusted in response to disturbances to achieve a target incremental ash value in the last cell of the bank. This will, in effect, maximize yield at an acceptable product quality. During this same period, a video-based ash analyzer was installed on the flotation tailings stream at the Moss No. 3 preparation plant. A preliminary calibration curve was established, and data are continuing to be collected in order to improve the calibration of the analyzer.

  11. Process for recovering fine coal particles from slurry of finely divided coal

    SciTech Connect

    Harada, K.; Ogino, E.; Yoshii, N.

    1982-08-24

    Fine coal particles are recovered from a slurry of finely divided coal by mixing coarsely divided coal and a binder together to cause the binder to adhere to the surfaces of the coarsely divided coal pieces, mixing the slurry with the coal pieces having the binder adhered thereto to cause fine coal particles to adhere to the binder over the surfaces of the coal pieces serving as nuclei and thereby form agglomerates, and separating the agglomerates from the remaining slurry portion to recover the fine coal particles along with the coarsely divided coal and the binder.

  12. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOEpatents

    Scott, Charles D.; Strandberg, Gerald W.

    1989-01-01

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  13. Applications study of advanced power generation systems utilizing coal-derived fuels. Volume 1: Executive summary

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    The technology status of phosphoric acid and molten carbon fuel cells, combined gas and steam turbine cycles, and magnetohydrodynamic energy conversion systems was assessed and the power performance of these systems when operating with medium-Btu fuel gas whether delivered by pipeline to the power plant or in an integrated mode in which the coal gasification process and power system are closely coupled as an overall power plant was evaluated. Commercially available combined-cycle gas turbine systems can reach projected required performance levels for advanced systems using currently available technology. The phosphoric acid fuel cell appears to be the next most likely candidate for commercialization. On pipeline delivery, the systems efficiency ranges from 40.9% for the phosphoric acid fuel cell to 63% for the molten carbonate fuel cell system. The efficiencies of the integrated power plants vary from approximately 39-40% for the combined cycle to 46-47% for the molden carbonate fuel cell systems. Conventional coal-fired steam stations with flue-gas desulfurization have only 33-35% efficiency.

  14. Advances in cardiac processing software.

    PubMed

    Gordon DePuey, Ernest

    2014-07-01

    New software methods that incorporate iterative reconstruction, resolution recovery, and noise compensation now provide the ability to maintain or improve myocardial perfusion SPECT image quality with conventional sodium iodide cameras. Despite lower image counting statistics associated with significantly decreased injected radiopharmaceutical doses or shortened acquisition times or both, image quality is preserved or even improved compared with conventional processing methods. The ability to prescribe a desired myocardial count density by preselecting a SPECT acquisition time now avoids additional patient radiation exposure associated with "weight-based" dosing. More recent advancements, including temporal correlation among the gated perfusion frames and higher resolution SPECT acquisitions, hold promise to further improve image quality and diagnostic accuracy. Phase analysis of gated perfusion SPECT provides the ability to assess cardiac dyssynchrony and to select those patients who will most benefit from resynchronization therapy. In combination with the higher counting statistics afforded by the new solid-state dedicated cardiac cameras, these software advancements allow for even further decreased patient radiation doses or acquisition times or both. List-mode software allows for refinement of myocardial perfusion SPECT by interrogating particular data from selected cardiac cycles. Rejection of frames degraded by arrhythmic cardiac cycles or excessive extracardiac uptake can be excluded for reconstruction. Respiratory gating, which diminishes cardiac motion and potentially decreases diaphragmatic attenuation, has been demonstrated to improve diagnostic specificity. With high-count first-pass list-mode acquisitions at rest and during pharmacologic vasodilatation, it may be possible to measure global and regional myocardial perfusion reserve to more accurately diagnose coronary artery disease and avoid false-negative studies owing to balanced ischemia.

  15. A Course in Coal Science and Technology.

    ERIC Educational Resources Information Center

    Wheelock, T. D.

    1978-01-01

    This course introduces graduate students and advanced undergraduates to coal science and technology. Topics include: (1) the nature and occurrence of coal, (2) its chemical and physical characteristics, (3) methods of cleaning and preparing coal, and (4) processes for converting coal into clean solid, liquid, and gaseous fuels, as well as coke.…

  16. Advances in Ammonia Removal from Hot Coal Gas

    SciTech Connect

    Jothimurugesan, K.; Gangwal, S.K.

    1996-12-31

    Nitrogen occurs in coal in the form of tightly bound organic ring compounds, typically at levels of 1 to 2 wt%. During coal gasification, this fuel bound nitrogen is released principally as ammonia (NH{sub 3}). When hot coal gas is used to generate electricity in integrated gasification combined cycle (IGCC) power plants, NH{sub 3} is converted to nitrogen oxides (NO{sub x}) which are difficult to remove and are highly undesirable as atmospheric pollutants. Similarly, while the efficiency of integrated gasification molten carbonate fuel cell (IGFC) power plants is not affected by NH{sub 3}, NO{sub x} is generated during combustion of the anode exhaust gas. Thus NH{sub 3} must be removed from hot coal gas before it can be burned in a turbine or fuel cell. The objective of this study is to develop a successful combination of an NH{sub 3} decomposition catalyst with a zinc-based mixed-metal oxide sorbent so that the sorbent-catalyst activity remains stable for NH{sub 3} decomposition in addition to H{sub 2}S removal under cycle sulfidation-regeneration conditions in the temperature range of 500 to 750{degrees}C.

  17. Overall requirements for an advanced underground coal extraction system

    SciTech Connect

    Goldsmith, M.; Lavin, M.L.

    1980-10-15

    This report presents overall requirements on underground mining systems suitable for coal seams exploitable in the year 2000, with particular relevance to the resources of Central Appalachia. These requirements may be summarized as follows: (1) Production Cost: demonstrate a return on incremental investment of 1.5 to 2.5 times the value required by a low-risk capital project. (2) Miner Safety: achieve at least a 50% reduction in deaths and disabling injuries per million man-hours. (3) Miner Health: meet the intent of all applicable regulations, with particular attention to coal dust, carcinogens, and mutagens; and with continued emphasis on acceptable levels of noise and vibration, lighting, humidity and temperature, and adequate work space. (4) Environmental Impact: maintain the value of mined and adjacent lands at the pre-mining value following reclamation; mitigation of off-site impacts should not cost more than the procedures used in contemporary mining. (5) Coal Conservation: the recovery of coal from the seam being mined should be at least as good as the best available contemporary technology operating in comparable conditions. No significant trade-offs between production cost and other performance indices were found.

  18. Coal-gasification-process concepts. [Dependence on gasifier pressure

    SciTech Connect

    Miller, C.L.; Tarman, P.B.

    1982-01-01

    First Generation coal gasification continues to grow with the expansion of Lurgi process to make gasoline in South Africa and SNG in the United States. This moving-bed gasifier is no doubt the leading commercial application of coal gasification. This can probably be attributed to its operation at the elevated pressure that simultaneously increases coal throughput and broadens the utility of the raw Syngas product by lowering its coal. Other Second Generation processes also strive to achieve high pressure operation: Ruhrgas 100 to improve moving-bed gasification at 100 bars; Texaco, Shell, Koppers, and Saarberg-Otto to improve entrained-bed gasification at 20 to 40 bars; and U-GAS and Westinghouse and the pressurized Winkler to improve fluidized-bed operation at 10 to 40 bars. Operation at 20 to 40 bars greatly improves gasifier productivity and significantly broadens the use of the raw Syngas produced by all types of gasifiers. Future commercial trends will include the entrained- and fluidized-bed concepts at 20 to 40 bars while even higher operating pressures will be used for the Lurgi moving-bed concept.

  19. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.; Potas, Todd A.; DeWall, Raymond A.; Musich, Mark A.

    1992-01-01

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  20. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  1. Advanced concepts in coal liquefaction: Optimization of reactor configuration in coal liquefaction. Final report

    SciTech Connect

    Pradhan, V.R.; Comolli, A.G.; Lee, L.K.

    1994-11-01

    The overall objective of this Project was to find the ways to effectively reduce the cost of coal liquids to about dollar 25 per barrel of crude oil equivalent. The work described herein is primarily concerned with the testing at the laboratory scale of three reactor configuration concepts, namely (1) a fixed-bed plug-flow reactor as a ``finishing reactor`` in coal liquefaction, (2) three-stage well-mixed reactors in series, and (3) interstage stream concentration/product separation. The three reactor configurations listed above were tested during this project using a 20 cc tubing microreactor, a fixed-bed plug flow reactor, and a two-stage modified Robinson-Mahoney reactor system. The reactor schemes were first evaluated based on theoretical modelling studies, then experimentally evaluated at the microautoclave level and laboratory scale continuous operations. The fixed-bed ``finishing reactor`` concept was evaluated in both the upflow and the downflow modes of operation using a partially converted coal-solvent slurry as feed. For most of the testing of concepts at the microautoclave level, simulated coal, recycle oil, and slurry feedstocks were either specially prepared (to represent a specific state of coal/resid conversion) and/or obtained from HRI`s other ongoing bench-scale and PDU scale coal liquefaction experiments. The three-stage continuous stirred tank reactors (CSTR) and interstage product stream separation/concentration concepts were tested using a simulated three-stage CSTR system by employing a laboratory-scale ebullated-bed system and a modified version of the HRI`s existing Robinson-Mahoney fixed catalyst basket reactor system. This testing was conducted as a fourteen day long continuous run, divided into four Conditions to allow for a comparison of the new three-stage CSTR and interstage product concentration concepts with a two-stage CSTR baseline configuration.

  2. Geochemical Proxies for Enhanced Process Control of Underground Coal Gasification

    NASA Astrophysics Data System (ADS)

    Kronimus, A.; Koenen, M.; David, P.; Veld, H.; van Dijk, A.; van Bergen, F.

    2009-04-01

    Underground coal gasification (UCG) represents a strategy targeting at syngas production for fuel or power generation from in-situ coal seams. It is a promising technique for exploiting coal deposits as an energy source at locations not allowing conventional mining under economic conditions. Although the underlying concept has already been suggested in 1868 and has been later on implemented in a number of field trials and even at a commercial scale, UCG is still facing technological barriers, impeding its widespread application. Field UCG operations rely on injection wells enabling the ignition of the target seam and the supply with oxidants (air, O2) inducing combustion (oxidative conditions). The combustion process delivers the enthalpy required for endothermic hydrogen production under reduction prone conditions in some distance to the injection point. The produced hydrogen - usually accompanied by organic and inorganic carbon species, e.g. CH4, CO, and CO2 - can then be retrieved through a production well. In contrast to gasification of mined coal in furnaces, it is difficult to measure the combustion temperature directly during UCG operations. It is already known that geochemical parameters such as the relative production gas composition as well as its stable isotope signature are related to the combustion temperature and, consequently, can be used as temperature proxies. However, so far the general applicability of such relations has not been proven. In order to get corresponding insights with respect to coals of significantly different rank and origin, four powdered coal samples covering maturities ranging from Ro= 0.43% (lignite) to Ro= 3.39% (anthracite) have been gasified in laboratory experiments. The combustion temperature has been varied between 350 and 900 ˚ C, respectively. During gasification, the generated gas has been captured in a cryo-trap, dried and the carbon containing gas components have been catalytically oxidized to CO2. Thereafter, the

  3. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  4. Coal gasification process wastewater reusability: separation of organics by membranes

    SciTech Connect

    Bhattacharyya, D.; Kermode, R.I.; Dickinson, R.L.

    1983-02-01

    The developing coal-gasification technologies generate gaseous process streams laden with water-soluble species such as H/sub 2/S, NH/sub 3/, HCN, phenols, cresols etc. The primary raw gas clean-up (gas quenching) results in large volumes of highly contaminated wastewaters. The development of a membrane separation process for the removal of selected organics, salts, and scale-forming compounds from stripped coal-conversion process wastewaters, will minimise surface-water pollution and decrease water consumption by permeate recycling. The recent industrial development of non-cellulosic thin-film composite membranes has provided membranes with high salt and low molecular weight organic separation characteristics and insignificant compaction problems. The low pressure membranes (used for brackish water) have definite advantages in terms of energy saving and lower capital cost. The composite membranes perform better than cellulose-acetate membranes. 24 references.

  5. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOEpatents

    Ignasiak, Teresa; Strausz, Otto; Ignasiak, Boleslaw; Janiak, Jerzy; Pawlak, Wanda; Szymocha, Kazimierz; Turak, Ali A.

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  6. Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

    SciTech Connect

    Baldwin, R.M.; Miller, R.L.

    1991-12-01

    The findings in the first phase were as follows: 1. Both reductive (non-selective) alkylation and selective oxygen alkylation brought about an increase in liquefaction reactivity for both coals. 2. Selective oxygen alkylation is more effective in enhancing the reactivity of low rank coals. In the second phase of studies, the major findings were as follows: 1. Liquefaction reactivity increases with increasing level of alkylation for both hydroliquefaction and co-processing reaction conditions. 2. the increase in reactivity found for O-alkylated Wyodak subbituminous coal is caused by chemical changes at phenolic and carboxylic functional sites. 3. O-methylation of Wyodak subbituminous coal reduced the apparent activation energy for liquefaction of this coal.

  7. Cofiring of coal and biomass in advanced fluidized bed gasifiers

    SciTech Connect

    Hoppe, J.A.

    1998-12-31

    The cofiring of coal and biomass is now being considered by the scientific community and as a viable option to the sustained year round operation of biomass based plants which are currently limited in duration due to the biomass growing season dependency. There are many industrial applications which would also accommodate the use of waste residuals including biomass resources for production of cogenerated electricity, steam and syn-gas based chemicals and fuels (methanol, ethanol, ammonia, etc.). A good example of this is the bagasse-based biomass project NREL is currently supporting using the IGT U-Gas gasifier technology which is under way in a pilot plant operation located in Maui, Hawaii in the sugar cane fields accessible to a nearby seaport which could accommodate other alternate fuel handling facilities. In addition the use of bagasse types of biomass wastes can support the environmental clean-up and disposal of these and other types of wastes such as wood wastes from pulp and paper mills, and vegetation and floral wastes in tropical regions such as South Asia. Using cofiring of coal fines and biomass can be economically attractive in areas where high and low grade coal is mined and can add to the electrification and district heating of these remotely located villages and hamlets. Large scale facilities can be envisioned, but there is a need for testing and proving these options in areas where there is no existing infrastructure for providing local electric and district heat. Industrial scale coal-based IGCC facilities are economically operated in many places in China and in urban industrial complexes such as the Shanghai Coke and Chemical Plant Group (SCCPG) in the southern region of Shanghai (SCCPG has a license for the U-Gas gasification technology in China).

  8. Testing of advanced liquefaction concepts in HTI Run ALC-1: Coal cleaning and recycle solvent treatment

    SciTech Connect

    Robbins, G.A.; Winschel, R.A.; Burke, F.P.; Derbyshire, F.L.; Givens, E.N.; Hu, J.; Lee, T.L.K.; Miller, J.E.; Stephens, H.P.; Peluso, M.

    1996-09-01

    In 1991, the Department of Energy initiated the Advanced Liquefaction Concepts Program to promote the development of new and emerging technology that has potential to reduce the cost of producing liquid fuels by direct coal liquefaction. Laboratory research performed by researchers at CAER, CONSOL, Sandia, and LDP Associates in Phase I is being developed further and tested at the bench scale at HTI. HTI Run ALC-1, conducted in the spring of 1996, was the first of four planned tests. In Run ALC-1, feed coal ash reduction (coal cleaning) by oil agglomeration, and recycle solvent quality improvement through dewaxing and hydrotreatment of the recycle distillate were evaluated. HTI`s bench liquefaction Run ALC-1 consisted of 25 days of operation. Major accomplishments were: 1) oil agglomeration reduced the ash content of Black Thunder Mine coal by 40%, from 5.5% to 3.3%; 2) excellent coal conversion of 98% was obtained with oil agglomerated coal, about 3% higher than the raw Black Thunder Mine coal, increasing the potential product yield by 2-3% on an MAF coal basis; 3) agglomerates were liquefied with no handling problems; 4) fresh catalyst make-up rate was decreased by 30%, with no apparent detrimental operating characteristics, both when agglomerates were fed and when raw coal was fed (with solvent dewaxing and hydrotreating); 5) recycle solvent treatment by dewaxing and hydrotreating was demonstrated, but steady-state operation was not achieved; and 6) there was some success in achieving extinction recycle of the heaviest liquid products. Performance data have not been finalized; they will be available for full evaluation in the new future.

  9. Coal.

    ERIC Educational Resources Information Center

    Brant, Russell A.; Glass, Gary B.

    1983-01-01

    Principle work of 23 state geological surveys is summarized. Work includes mapping/estimating coal resources, centralizing data in National Coal Resources Data System through cooperative programs, exploration drilling, and others. Comments on U.S. Geological Survey activities, coal-related conferences/meetings, and industry research activities are…

  10. Engineering development of advanced coal-fired low-emission boiler system

    SciTech Connect

    Not Available

    1993-02-26

    The Pittsburgh Energy Technology Center of the US Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems'' Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: NO[sub x] emissions not greater than one-third NSPS; SO[sub x] emissions not greater than one-third NSPS; and particulate emissions not greater than one-half NSPS. The specific secondary objectives are: Improved ash disposability and reduced waste generation; reduced air toxics emissions; increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

  11. The Texaco coal gasification process for manufacture of medium BTU gas

    NASA Technical Reports Server (NTRS)

    Schlinger, W. G.

    1978-01-01

    The development of the Texaco coal gasification process is discussed with particular emphasis on its close relationship to the fully commercialized Texaco synthesis gas generation process for residual oil gasification. The end uses of the product gas are covered, with special attention to electric power generation via combined cycle technology. Control of SO2, NOx, and particulate emissions in the power generating mode is also covered. The application of this technology in a proposed Texaco-Southern California Edison demonstration project is mentioned. Investment information released for a 1000-megawatt advanced combined cycle gasification facility, is also reviewed.

  12. Brine disposal process for Morcinek coal mine

    SciTech Connect

    Tait, J.H.

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  14. A Characterization and Evaluation of Coal Liquefaction Process Streams

    SciTech Connect

    G. A. Robbins; R. A. Winschel

    1998-07-01

    This is the Technical Progress Report for the fourteenth quatier of activities under DOE Contract No. DE-AC22-94PC93054. It covers the period October 1 through December 31, 1997'. Described in this report is the following activity: o CONSOL characterized 34 process stream samples from HTI Run PB-06, in which Black Thunder Mine coal, virgin plastics, plasticiderived pyrolysis oil, and Hondo vacuum resid were used as liquefaction feedstocks with dispersed catalyst.

  15. Evaluation of air toxic emissions from advanced and conventional coal-fired power plants

    SciTech Connect

    Chu, P.; Epstein, M.; Gould, L.; Botros, P.

    1995-12-31

    This paper evaluates the air toxics measurements at three advanced power systems and a base case conventional fossil fuel power plant. The four plants tested include a pressurized fluidized bed combustor, integrated gasification combined cycle, circulating fluidized bed combustor, and a conventional coal-fired plant.

  16. 78 FR 49061 - Valuation of Federal Coal for Advance Royalty Purposes and Information Collection Applicable to...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-12

    ...ONRR proposes new regulations to implement the provisions of the Energy Policy Act of 2005 (EPAct) governing the payment of advance royalty on coal resources produced from Federal leases. The EPAct provisions amend the Mineral Leasing Act of 1920 (MLA). ONRR also proposes to add information collection requirements that are applicable to all solid minerals leases and also are necessary to......

  17. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, April 1996--June 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-07-31

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from April 1 - June 30, 1996.

  18. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, No. 4, July 1995--September 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1995-11-06

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 29, 1995.

  19. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 2, January 1995--March 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1995-05-05

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 to March 31, 1995.

  20. A Technique for Decreasing Reactivity of Coal Material to Suppress the Oxygen Absorption Process

    NASA Astrophysics Data System (ADS)

    Timofeeva, S. S.; Lugovtsova, N. Yu; Gubanova, A. R.

    2016-08-01

    The paper describes the mechanisms of self-ignition formation in coal liable to spontaneous combustion, on the basis of experimental works performed to analyze heat and mass transfer in the coal-air system. A new approach was developed to the coal self-heating suppression and thermodynamic control of the oxidation process. The influence of coal moisture content and thermal behaviour of air in the cooling process was studied during moisture evaporation.

  1. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect

    Alvin, M.A.

    2002-09-19

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  2. RESEARCH ON CARBON PRODUCTS FROM COAL USING AN EXTRACTIVE PROCESS

    SciTech Connect

    Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo; Chong Chen; Brian Bland; David Fenton

    2002-03-31

    This report presents the results of a one-year effort directed at the exploration of the use of coal as a feedstock for a variety of industrially-relevant carbon products. The work was basically divided into three focus areas. The first area dealt with the acquisition of laboratory equipment to aid in the analysis and characterization of both the raw coal and the coal-derived feedstocks. Improvements were also made on the coal-extraction pilot plant which will now allow larger quantities of feedstock to be produced. Mass and energy balances were also performed on the pilot plant in an attempt to evaluate the scale-up potential of the process. The second focus area dealt with exploring hydrogenation conditions specifically aimed at testing several less-expensive candidate hydrogen-donor solvents. Through a process of filtration and vacuum distillation, viable pitch products were produced and evaluated. Moreover, a recycle solvent was also isolated so that the overall solvent balance in the system could be maintained. The effect of variables such as gas pressure and gas atmosphere were evaluated. The pitch product was analyzed and showed low ash content, reasonable yield, good coking value and a coke with anisotropic optical texture. A unique plot of coke yield vs. pitch softening point was discovered to be independent of reaction conditions or hydrogen-donor solvent. The third area of research centered on the investigation of alternate extraction solvents and processing conditions for the solvent extraction step. A wide variety of solvents, co-solvents and enhancement additives were tested with varying degrees of success. For the extraction of raw coal, the efficacy of the alternate solvents when compared to the benchmark solvent, N-methyl pyrrolidone, was not good. However when the same coal was partially hydrogenated prior to solvent extraction, all solvents showed excellent results even for extractions performed at room temperature. Standard analyses of the

  3. Process development for production of coal/sorbent agglomerates

    SciTech Connect

    Rapp, D.M.

    1991-01-01

    The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of hardening iron ore pellets (Imperato, 1966). Two potential combustion options are being considered for the coal/calcium hydroxide pellets: fluidized bed combustors and industrial stoker boilers.

  4. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Task 6 -- Selective agglomeration laboratory research and engineering development for premium fuels

    SciTech Connect

    Moro, N.; Jha, M.C.

    1997-06-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and benchscale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report represents the findings of Subtask 6.5 Selective Agglomeration Bench-Scale Testing and Process Scale-up. During this work, six project coals, namely Winifrede, Elkhorn No. 3, Sunnyside, Taggart, Indiana VII, and Hiawatha were processed in a 25 lb/hr continuous selective agglomeration bench-scale test unit.

  5. Process for coal liquefaction using electrodeposited catalyst

    DOEpatents

    Moore, Raymond H.

    1978-01-01

    A process for the liquefaction of solid hydrocarbonaceous materials is disclosed. Particles of such materials are electroplated with a metal catalyst and are then suspended in a hydrocarbon oil and subjected to hydrogenolysis to liquefy the solid hydrocarbonaceous material. A liquid product oil is separated from residue solid material containing char and the catalyst metal. The catalyst is recovered from the solid material by electrolysis for reuse. A portion of the product oil can be employed as the hydrocarbon oil for suspending additional particles of catalyst coated solid carbonaceous material for hydrogenolysis.

  6. State of the art of biological processes for coal gasification wastewater treatment.

    PubMed

    Zhao, Qian; Liu, Yu

    2016-01-01

    The treatment of coal gasification wastewater (CGW) poses a serious challenge on the sustainable development of the global coal industry. The CGW contains a broad spectrum of high-strength recalcitrant substances, including phenolic, monocyclic and polycyclic aromatic hydrocarbons, heterocyclic nitrogenous compounds and long chain aliphatic hydrocarbon. So far, biological treatment of CGW has been considered as an environment-friendly and cost-effective method compared to physiochemical approaches. Thus, this reviews aims to provide a comprehensive picture of state of the art of biological processes for treating CGW wastewater, while the possible biodegradation mechanisms of toxic and refractory organic substances were also elaborated together with microbial community involved. Discussion was further extended to advanced bioprocesses to tackle high-concentration ammonia and possible options towards in-plant zero liquid discharge.

  7. Safety evaluation methodology for advanced coal extraction systems

    NASA Technical Reports Server (NTRS)

    Zimmerman, W. F.

    1981-01-01

    Qualitative and quantitative evaluation methods for coal extraction systems were developed. The analysis examines the soundness of the design, whether or not the major hazards have been eliminated or reduced, and how the reduction would be accomplished. The quantitative methodology establishes the approximate impact of hazards on injury levels. The results are weighted by peculiar geological elements, specialized safety training, peculiar mine environmental aspects, and reductions in labor force. The outcome is compared with injury level requirements based on similar, safer industries to get a measure of the new system's success in reducing injuries. This approach provides a more detailed and comprehensive analysis of hazards and their effects than existing safety analyses.

  8. The fate of alkali species in advanced coal conversion systems

    SciTech Connect

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  9. Coal liquefaction process streams characterization and evaluation. Novel analytical techniques for coal liquefaction: Fluorescence microscopy

    SciTech Connect

    Rathbone, R.F.; Hower, J.C.; Derbyshire, F.J.

    1991-10-01

    This study demonstrated the feasibility of using fluorescence and reflectance microscopy techniques for the examination of distillation resid materials derived from direct coal liquefaction. Resid, as defined here, is the 850{degrees}F{sup +} portion of the process stream, and includes soluble organics, insoluble organics and ash. The technique can be used to determine the degree of hydrogenation and the presence of multiple phases occurring within a resid sample. It can also be used to infer resid reactivity. The technique is rapid, requiring less than one hour for sample preparation and examination, and thus has apparent usefulness for process monitoring. Additionally, the technique can distinguish differences in samples produced under various process conditions. It can, therefore, be considered a potentially useful technique for the process developer. Further development and application of this analytical method as a process development tool is justified based on these results.

  10. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    NASA Astrophysics Data System (ADS)

    1994-05-01

    This project has successfully advanced the technology for MSOFC's for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-sq cm per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  11. Coal Combustion Science

    SciTech Connect

    Hardesty, D.R.; Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. )

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  12. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 25, October 1, 1994--December 31, 1994

    SciTech Connect

    1994-12-31

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This progress report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  13. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    1999-04-26

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3% of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas. The effort during the reporting period has been devoted to development of optimized low-cost zinc-oxide-based sorbents for Sierra-Pacific. The sorbent surface were modified to prevent

  14. Advances in the development of wire mesh reactor for coal gasification studies.

    PubMed

    Zeng, Cai; Chen, Lei; Liu, Gang; Li, Wenhua; Huang, Baoming; Zhu, Hongdong; Zhang, Bing; Zamansky, Vladimir

    2008-08-01

    In an effort to further understand the coal gasification behavior in entrained-flow gasifiers, a high pressure and high temperature wire mesh reactor with new features was recently built. An advanced LABVIEW-based temperature measurement and control system were adapted. Molybdenum wire mesh with aperture smaller than 70 mum and type D thermocouple were used to enable high carbon conversion (>90%) at temperatures >1000 degrees C. Gaseous species from wire mesh reactor were quantified using a high sensitivity gas chromatography. The material balance of coal pyrolysis in wire mesh reactor was demonstrated for the first time by improving the volatile's quantification techniques.

  15. Advances in the development of wire mesh reactor for coal gasification studies - article no. 084102

    SciTech Connect

    Zeng, C.; Chen, L.; Liu, G.; Li, W.H.; Huang, B.M.; Zhu, H.D.; Zhang, B.; Zamansky, V.

    2008-08-15

    In an effort to further understand the coal gasification behavior in entrained-flow gasifiers, a high pressure and high temperature wire mesh reactor with new features was recently built. An advanced LABVIEW-based temperature measurement and control system were adapted. Molybdenum wire mesh with aperture smaller than 70 {mu} m and type D thermocouple were used to enable high carbon conversion ({gt}90%) at temperatures {gt}1000 {sup o}C. Gaseous species from wire mesh reactor were quantified using a high sensitivity gas chromatography. The material balance of coal pyrolysis in wire mesh reactor was demonstrated for the first time by improving the volatile's quantification techniques.

  16. An analysis of cost effective incentives for initial commercial deployment of advanced clean coal technologies

    SciTech Connect

    Spencer, D.F.

    1997-12-31

    This analysis evaluates the incentives necessary to introduce commercial scale Advanced Clean Coal Technologies, specifically Integrated Coal Gasification Combined Cycle (ICGCC) and Pressurized Fluidized Bed Combustion (PFBC) powerplants. The incentives required to support the initial introduction of these systems are based on competitive busbar electricity costs with natural gas fired combined cycle powerplants, in baseload service. A federal government price guarantee program for up to 10 Advanced Clean Coal Technology powerplants, 5 each ICGCC and PFBC systems is recommended in order to establish the commercial viability of these systems by 2010. By utilizing a decreasing incentives approach as the technologies mature (plants 1--5 of each type), and considering the additional federal government benefits of these plants versus natural gas fired combined cycle powerplants, federal government net financial exposure is minimized. Annual net incentive outlays of approximately 150 million annually over a 20 year period could be necessary. Based on increased demand for Advanced Clean Coal Technologies beyond 2010, the federal government would be revenue neutral within 10 years of the incentives program completion.

  17. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect

    1994-10-01

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  18. An Advanced Control System for Fine Coal Flotation. Sixth quarter, technical progress report, July 1-September 30, 1997

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-10-27

    Over the past thirty years, process control has spread from the chemical industry into the fields of mineral and coal processing. Today, process control computers, combined with improved instrumentation, are capable of effective control in many modem flotation circuits. Unfortunately, the classical methods used in most control strategies have severe limitations when used in froth flotation. For example, the nonlinear nature of the flotation process can cause single-input, single-output lines to battle each other in attempts to achieve a given objective. Other problems experienced in classical control schemes include noisy signals from sensors and the inability to measure certain process variables. For example, factors related to ore type or water chemistry, such as liberation, froth stability, and floatability, cannot be measured by conventional means. The purpose of this project is to demonstrate an advanced control system for fine coal flotation. The demonstration is being carried out at an existing coal preparation plant by a team consisting of Virginia Polytechnic Institute and State University (VPI&SU) as the prime contractor and J.A. Herbst and Associates as a subcontractor. The objectives of this work are: (1) to identify through sampling, analysis, and simulation those variables which can be manipulated to maintain grades, recoveries, and throughput rates at levels set by management; (2) to develop and implement a model-based computer control strategy that continuously adjusts those variables to maximize revenue subject to various metallurgical, economic, and environmental constraints; and (3) to employ a video-based optical analyzer for on-line analysis of ash content in fine coal slurries.

  19. Process for producing high-concentration slurry of coal

    SciTech Connect

    Nakaoji, K.; Itoh, H.; Kamao, M.; Takao, Sh.; Tatsumi, Sh.

    1985-02-19

    High concentrated coal-water slurry is produced by coarsely crushing coal, thereafter pulverizing the coarsely crushed coal, together with water and a slurry dispersant, according to necessity, in a wet-type ball mill, and feeding back one portion of the finely pulverized coal slurry thus obtained into the inlet of the wet-type ball mill.

  20. A Course in Fundamentals of Coal Utilization and Conversion Processes.

    ERIC Educational Resources Information Center

    Radovic, Ljubisa R.

    1985-01-01

    Describes the content, objectives, and requirements for a one-semester (30 20-hour sessions) graduate engineering course at the University of Concepcion, Chile. Major course topics include: structure and properties of coal; coal pyrolysis and carbonization; coal liquefaction; coal combustion and gasification; and economic and environmental…

  1. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING... Coal Mining Operations, pertaining to petitioning, initial processing, hearing requirements, decisions... surface coal mining and reclamation operations beginning one year after the effective date of this program....

  2. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary...

  3. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary...

  4. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING... Coal Mining Operations, pertaining to petitioning, initial processing, hearing requirements, decisions... surface coal mining and reclamation operations beginning one year after the effective date of this program....

  5. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary...

  6. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING... Coal Mining Operations, pertaining to petitioning, initial processing, hearing requirements, decisions... surface coal mining and reclamation operations beginning one year after the effective date of this program....

  7. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary...

  8. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary...

  9. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING... Coal Mining Operations, pertaining to petitioning, initial processing, hearing requirements, decisions... surface coal mining and reclamation operations beginning one year after the effective date of this program....

  10. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING... Coal Mining Operations, pertaining to petitioning, initial processing, hearing requirements, decisions... surface coal mining and reclamation operations beginning one year after the effective date of this program....

  11. Applications of polymer extrusion technology to coal processing

    NASA Technical Reports Server (NTRS)

    Lewis, D. W.

    1981-01-01

    Upon heating, many of the middle-aged bituminous coals exhibit a plasticity very similar to polyethylene for a few minutes. Plastic coal can be extruded, pelletized or molded using common plastics technology and equipment. Investigations concerning the plastic state of coals are conducted with the objective to develop techniques which will make useful commercial applications of this property possible. Experiments which show the characteristics of plastic-state coal are discussed, and problems related to a continuous extrusion of coal are considered. Probably the most significant difference between the continuous extrusion of coal and the extrusion of a thermoplastic polymer is that volatiles are continuously being released from the coal. Attention is given to aspects of dragflow, solids feeding, and melt pumping. Application potentials for plastic coal extrusion might be related to coal gasification, direct liquefaction, and coal combustion.

  12. A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS

    SciTech Connect

    G.A. Robbins; S.D. Brandes; D.J. Pazuchanics; D.G. Nichols; R.A. Winschel

    1999-02-01

    This is the Technical Progress Report for the sixteenth quarter of activities under DOE Contract No. DE-AC22-94PC93054. It covers the period April 1 through June 30, 1998. Described in this report are the following activities: (1) CONSOL characterized nine process stream samples received from Exxon Recycle Coal Liquefaction Unit (RCLU) operations conducted in 1994 with Rawhide Mine Wyoming subbituminous coal and all-dispersed Fe and Mo catalysts. (2) The University of Delaware subcontract related to resid reactivity was completed with issuance of the Topical Report covering work performed by Delaware. (3) Computational studies of the coal liquefaction resid models developed at the University of Delaware were continued at CONSOL R and D. The two reaction models, consisting of the reaction optimization and reaction once-through programs, were the focus of these studies. The updated resid structure data and results were used in the reaction models to predict percent conversion values that were compared with the experimentally-measured values from the University of Delaware. (4) Small samples of high-sulfur Hondo resid and anthracene oil were shipped to John Verkade of Iowa State University at his request. Verkade is testing a desulfurization method.

  13. A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS

    SciTech Connect

    G.A. Robbins; S.D. Brandes; D.J. Pazuchanics; D.G. Nichols; R.A. Winschel

    1998-12-01

    This is the Technical Progress Report for the fifteenth quarter of activities under DOE Contract No. DE-AC22-94PC93054. It covers the period January 1 through March 31, 1998. Described in this report are the following activities: (1) CONSOL characterized 41 process stream samples obtained from HTI Run PB-01 (227-90), in which Black Thunder Mine coal, Hondo VTB resid, municipal solid waste (MSW) plastics, and virgin plastics were co-liquefaction feedstocks with all-dispersed Fe and Mo catalysts. (2) A request was made for samples from the Nippon Coal Oil NEDOL pilot plant in Kashima, Japan. (3) Phenols were extracted from two samples of separator overhead oil from HTI Run PB-03 Periods 10A and 10B. The phenols were converted to ethylphenyl ethers, and the ethers were distilled to produce a sample within the diesel fuel boiling range. The ethers were mixed with diesel fuel to make 1%, 5%, 10%, and 20% solutions. The four mixtures and a control sample (0% ether) were tested for diesel fuel properties by Intertek Testing Services, Caleb Brett. (4) Computational studies related to the University of Delaware's resid conversion model were continued on the Hewlett Packard Apollo HP-735 RISC workstation at CONSOL R and D. The Structure Optimization Program and the Structure Once-Through Program were used to generate physicochemical properties and structure models for the 15 coal resid samples which have been under study.

  14. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    1999-10-14

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3 % of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas The effort during the reporting period has been devoted to development of an advanced hot-gas process that can eliminate the problematic SO{sub 2} tail gas and yield elemental sulfur

  15. Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Annual report, October 1991--September 1992

    SciTech Connect

    Not Available

    1993-05-01

    The program is being conducted by a team consisting of AlliedSignal Aerospace Systems & Equipment (ASE) (formerly AiResearch Los Angeles Division) and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  16. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

    SciTech Connect

    Zauderer, B.; Fleming, E.S.

    1991-08-30

    This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

  17. Advanced methods for processing ceramics

    SciTech Connect

    Carter, W.B.

    1995-05-01

    Combustion chemical vapor deposition (CCVD) is a flame assisted, open air chemical vapor deposition (CVD) process. The process is capable of producing textured, epitaxial coatings on single crystal substrates using low cost reagents. Combustion chemical vapor deposition is a relatively inexpensive, alternative thin film deposition process with potential to replace conventional coating technologies for certain applications. The goals of this project are to develop the CCVD process to the point that potential industrial applications can be identified and reliably assessed.

  18. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 14, January--March 1996

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-04-30

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by June 1997. During Quarter 14 (January--March 1996), parametric testing of the 30-inch Microcel{trademark} flotation column at the Lady Dunn Plant continued under Subtask 3.2. Subtask 3. 3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter with parametric testing of the batch dewatering unit. Coal product moistures of 3 to 12 percent were achieved, with higher percent solids slurry feeds resulting in lower product moistures. For a given percent solids feed, the product moisture decreased with increasing butane to dry coal ratios. Stirring time, stirring rate, and settling time were all found to have little effect on the final moisture content. Continuing Subtask 6.4 work, investigating coal-water-fuel slurry formulation for coals cleaned by selective agglomeration, indicated that pH adjustment to 10 resulted in marginally better (lower viscosity) slurries for one of the two coals tested. Subtask 6.5 agglomeration bench-scale testing results indicate that the new Taggart coal requires a grind with a d{sub 80} of approximately 33 microns to achieve the 1 lb ash/MBtu product quality specification. Also under Subtask 6.5, reductions in the various trace element concentrations accomplished during selective agglomeration were determined. Work was essentially completed on the detailed design of the PDU selective agglomeration module under Task 7 with the issuing of a draft report.

  20. DFC coal reclamation system for the plant of the future for processing clean coal

    SciTech Connect

    Karsnak, G.; Hoppe, J.

    1993-12-31

    The coal resources of the United States are vast and provide a sound uninterruptable source of energy for both domestic use and international export which will continue to be available for hundreds of years in the future. It has been estimated that the vast U.S. Coal resources can be used as an economic way of producing power for another 300-400 years as predicted by both federal and industrial energy analysis sources. The {open_quotes}proven coal reserves{close_quotes} of the country or demonstrated reserve base (DRB) was estimated to be 467 billion short tons in 1987 based on DOE/EIA estimates of the coal that can be economically removed from the ground by state-of-the-art coal mining technology currently used by industry. These estimates are based on {open_quotes}state level{close_quotes} data that were collected by the DOE/EIA in recent studies attempting to quantify the economically usable coal reserves of the U.S. and provide estimates of the total available reserve base. The estimation of the U.S. coal resource base often leads to a misunderstanding of the actual coal reserves available as a carbon based fuel. Coal resources are defined as the amount of coal in the ground which may be made available for end-use in energy production while the quantifying of coal reserves is based on the amount of recoverable coal which can be economically extracted from the ground through conventional mining methods. What is customarily ignored in these estimates is the coal waste generated during coal beneficiation and which accumulates as a result of coal cleaning plants associated with most coal utilization applications.

  1. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  2. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.

    2003-09-12

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  3. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  4. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect

    Not Available

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  5. Advanced coal-fueled industrial cogeneration gas turbine system: Hot End Simulation Rig

    SciTech Connect

    Galica, M.A.

    1994-02-01

    This Hot End Simulation Rig (HESR) was an integral part of the overall Solar/METC program chartered to prove the technical, economic, an environmental feasibility of a coal-fueled gas turbine, for cogeneration applications. The program was to culminate in a test of a Solar Centaur Type H engine system operated on coal slurry fuel throughput the engine design operating range. This particular activity was designed to verify the performance of the Centaur Type H engine hot section materials in a coal-fired environment varying the amounts of alkali, ash, and sulfur in the coal to assess the material corrosion. Success in the program was dependent upon the satisfactory resolution of several key issues. Included was the control of hot end corrosion and erosion, necessary to ensure adequate operating life. The Hot End Simulation Rig addressed this important issue by exposing currently used hot section turbine alloys, alternate alloys, and commercially available advanced protective coating systems to a representative coal-fueled environment at turbine inlet temperatures typical of Solar`s Centaur Type H. Turbine hot end components which would experience material degradation include the transition duct from the combustor outlet to the turbine inlet, the shroud, nozzles, and blades. A ceramic candle filter vessel was included in the system as the particulate removal device for the HESR. In addition to turbine material testing, the candle material was exposed and evaluated. Long-term testing was intended to sufficiently characterize the performance of these materials for the turbine.

  6. Coal conversion systems design and process modeling. Volume 1: Application of MPPR and Aspen computer models

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The development of a coal gasification system design and mass and energy balance simulation program for the TVA and other similar facilities is described. The materials-process-product model (MPPM) and the advanced system for process engineering (ASPEN) computer program were selected from available steady state and dynamic models. The MPPM was selected to serve as the basis for development of system level design model structure because it provided the capability for process block material and energy balance and high-level systems sizing and costing. The ASPEN simulation serves as the basis for assessing detailed component models for the system design modeling program. The ASPEN components were analyzed to identify particular process blocks and data packages (physical properties) which could be extracted and used in the system design modeling program. While ASPEN physical properties calculation routines are capable of generating physical properties required for process simulation, not all required physical property data are available, and must be user-entered.

  7. Recovery of fine coal from waste streams using advanced column flotation

    SciTech Connect

    Groppo, J.G.

    1991-01-01

    The advanced flotation techniques, namely column flotation, have shown potential in obtaining a low ash, low pyritic sulfur fine size clean coal. The overall objective of this program is to evaluate applicability of an advanced flotation technique, 'Ken-Flote' column to recover clean coal with minimum mineral matter content at greater than 90 percent combustible recovery from two Illinois preparation plant waste streams. Column flotations tests were conducted on the flotation feed obtained from the Kerr-McGee Galatia and Ziegler No. 26 plants using three different bubble-generating devices: sparger, gas saver and foam jet. Each of these devices was tested with three different frothers and various column-operating variable to provide maximum combustible recovery, minimum product ash and maximum pyrite rejection. For the Galatia slurry, the column provided a clean coal containing 5 percent ash, 0.48 percent pyritic sulfur at combustible recovery averaging 90 percent. In other words, about 90 percent ash and about 75 percent pyritic sulfur rejection were attained for the Galatia slurry. Pilot plant studies on this slurry basically obtained results similar to the laboratory studies. For the Ziegler No. 26, slurry column flotation provided a clean coal containing about 5 percent ash, 0.44 percent pyritic sulfur at more than 90 percent combustible recovery. The ash and pyrite sulfur rejection was about 85 percent and 65 percent, respectively.

  8. Slag processing system for direct coal-fired gas turbines

    DOEpatents

    Pillsbury, Paul W.

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  9. Application of Modern Coal Technologies to Military Facilities. Volume I. Summary of findings.

    DTIC Science & Technology

    1978-05-01

    military facilities. Technologies considered are: conventional and advanced direct combustion of coal, coal gasification , and coal liquefaction. The impacts...direct combustion by 1982. Current- to near-term coal gasification prospects are the Lurgi and Koppers-Totzek low-Btu processes and the Lurgi high-Btu...process. A long-term coal gasification prospect is the CO2-Acceptor high-Btu process. No coal liquefaction processes currently appear to be economically

  10. Advanced turbine design for coal-fueled engines

    SciTech Connect

    Wagner, J.H.; Johnson, B.V.

    1993-04-01

    The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

  11. Advanced methods for processing ceramics

    SciTech Connect

    Carter, W.B.

    1997-04-01

    Combustion chemical vapor deposition (combustion CVD) is being developed for the deposition of high temperature oxide coatings. The process is being evaluated as an alternative to more capital intensive conventional coating processes. The thrusts during this reporting period were the development of the combustion CVD process for depositing lanthanum monazite, the determination of the influence of aerosol size on coating morphology, the incorporation of combustion CVD coatings into thermal barrier coatings (TBCs) and related oxidation research, and continued work on the deposition of zirconia-yttria coatings.

  12. Advanced direct coal liquefaction. Quarterly technical progress report No. 1, September-November 1983

    SciTech Connect

    Paranjape, A.S.

    1984-02-07

    Wyoming subbituminous coal was liquefied using three different two-stage process configurations in bench-scale tests. These process configurations differed in the type of fractionated deashing resid being recycled to the individual stages. The objective of these runs was to determine whether, by recycle of specific resid streams to the thermal stage, the second stage catalyst life could be improved without detrimentally affecting distillate yield or hydrogen consumption. The results indicate that the two-stage process configuration consisting of hydrotreating the Light Deashed Resid and direct recycle of heavy Deashed Resid to the thermal stage produced the best results. This process configuration resulted in a distillate yield of 54 wt % (MAF coal basis) and overall coal conversion in the 93 to 95% range, as measured by pyridine-soluble analytical test while operating in a total distillate mode. These results are very encouraging from the lower rank Wyoming subbituminous coal. Among the three two-stage process configurations tested, the particular process configuration of hydrotreating Light Deashed Resid resulted in the least amount of catalyst deactivation. As a part of this research effort, a test procedure for quick evaluation of various resids and catalysts in terms of coke precursors was also developed. This procedure utilizing as-produced oxide-form extrudates of catalyst is able to simulate closely in a batch reactor test the performance of a presulfided and extrudate form of catalyst in a continuous reactor. The CSD unit, being able to not only deash but also fractionate the resid, greatly increased the flexibility of options for coal liquefaction. New process concepts evolved incorporating reside fractionation and selective resid recycle in coal liquefaction. 17 figures, 28 tables.

  13. Advanced technology applications for second and third general coal gasification systems

    NASA Technical Reports Server (NTRS)

    Bradford, R.; Hyde, J. D.; Mead, C. W.

    1980-01-01

    The historical background of coal conversion is reviewed and the programmatic status (operational, construction, design, proposed) of coal gasification processes is tabulated for both commercial and demonstration projects as well as for large and small pilot plants. Both second and third generation processes typically operate at higher temperatures and pressures than first generation methods. Much of the equipment that has been tested has failed. The most difficult problems are in process control. The mechanics of three-phase flow are not fully understood. Companies participating in coal conversion projects are ordering duplicates of failure prone units. No real solutions to any of the significant problems in technology development have been developed in recent years.

  14. Process for clean-burning fuel from low-rank coal

    DOEpatents

    Merriam, Norman W.; Sethi, Vijay; Brecher, Lee E.

    1994-01-01

    A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect

    Not Available

    1992-01-01

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development's facility near Beverly, Ohio. OCDO's facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  16. Development of an advanced continuous mild gasification process for the production of coproducts

    SciTech Connect

    Merriam, N.W.; Jha, M.C.

    1991-11-01

    This report is a final brief summary of development of a mild-gasification and char conversion process. Morgantown Energy Technology Center developed a concept called mild gasification. In this concept, devolatilization of coal under nonoxidizing and relatively mild temperature and pressure conditions can yield three marketable products: (1) a high-heating-value gas, (2) a high-aromatic coal liquid, and (3) a high-carbon char. The objective of this program is to develop an advanced, continuous, mild-gasification process to produce products that will make the concept economically and environmentally viable. (VC)

  17. Development of an advanced continuous mild gasification process for the production of coproducts. Final report

    SciTech Connect

    Merriam, N.W.; Jha, M.C.

    1991-11-01

    This report is a final brief summary of development of a mild-gasification and char conversion process. Morgantown Energy Technology Center developed a concept called mild gasification. In this concept, devolatilization of coal under nonoxidizing and relatively mild temperature and pressure conditions can yield three marketable products: (1) a high-heating-value gas, (2) a high-aromatic coal liquid, and (3) a high-carbon char. The objective of this program is to develop an advanced, continuous, mild-gasification process to produce products that will make the concept economically and environmentally viable. (VC)

  18. Advanced digital SAR processing study

    NASA Technical Reports Server (NTRS)

    Martinson, L. W.; Gaffney, B. P.; Liu, B.; Perry, R. P.; Ruvin, A.

    1982-01-01

    A highly programmable, land based, real time synthetic aperture radar (SAR) processor requiring a processed pixel rate of 2.75 MHz or more in a four look system was designed. Variations in range and azimuth compression, number of looks, range swath, range migration and SR mode were specified. Alternative range and azimuth processing algorithms were examined in conjunction with projected integrated circuit, digital architecture, and software technologies. The advaced digital SAR processor (ADSP) employs an FFT convolver algorithm for both range and azimuth processing in a parallel architecture configuration. Algorithm performace comparisons, design system design, implementation tradeoffs and the results of a supporting survey of integrated circuit and digital architecture technologies are reported. Cost tradeoffs and projections with alternate implementation plans are presented.

  19. High temperature electrochemical polishingof H{sub 2}S from coal gasificatioon process streams: Quarterly report, January 1-March 31, 1997

    SciTech Connect

    Winnick, J.

    1997-12-31

    An advanced process for the separation of hydrogen sulfide from coal gasification product streams through electrochemical membrane is being developed. H2S is removed from the syngas stream, split into hydrogen, with the existing syngas, and sulfur. Past experiments dealt with removal of 1-2% H2S from gases containing only H2S, nitrogen, and simulated coal gas. The most recent experiments evaluated the polishing application using Electrochemical Membrane Separator. Removal efficiencies of over 90% were achieved.

  20. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 13, October--December, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-01-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit. During Quarter 13 (October--December 1995), testing of the GranuFlow dewatering process indicated a 3--4% reduction in cake moisture for screen-bowl and solid-bowl centrifuge products. The Orimulsion additions were also found to reduce the potential dustiness of the fine coal, as well as improve solids recovery in the screen-bowl centrifuge. Based on these results, Lady Dunn management now plans to use a screen bowl centrifuge to dewater their Microcel{trademark} column froth product. Subtask 3.3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter. Continuing Subtask 6.4 work, investigating coal-water-slurry formulation, indicated that selective agglomeration products can be formulated into slurries with lower viscosities than advanced flotation products. Subtask 6.5 agglomeration bench-scale testing results indicate that a very fine grind is required to meet the 2 lb ash/MBtu product specification for the Winifrede coal, while the Hiawatha coal requires a grind in the 100- to 150-mesh topsize range. Detailed design work remaining involves the preparation and issuing of the final task report. Utilizing this detailed design, a construction bid package was prepared and submitted to three Colorado based contractors for quotes as part of Task 9.

  1. Characteristics of process oils from HTI coal/plastics co-liquefaction runs

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.

    1995-12-31

    The objective of this project is to provide timely analytical support to DOE`s liquefaction development effort. Specific objectives of the work reported here are presented. During a few operating periods of Run POC-2, HTI co-liquefied mixed plastics with coal, and tire rubber with coal. Although steady-state operation was not achieved during these brief tests periods, the results indicated that a liquefaction plant could operate with these waste materials as feedstocks. CONSOL analyzed 65 process stream samples from coal-only and coal/waste portions of the run. Some results obtained from characterization of samples from Run POC-2 coal/plastics operation are presented.

  2. POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING

    SciTech Connect

    1998-01-01

    This report covers the technical progress achieved from July 01, 1997 to September 30, 1997 on the POC-Scale Testing Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental procedures and test data for recovery of fine coal from coal fines streams generated at a commercial coal preparation plant are described. Two coal fines streams, namely Sieve Bend Effluent and Cyclone Overflow were investigated. The test results showed that ash was reduced by more than 50% at combustible matter recovery levels exceeding 95%.

  3. Experience in feeding coal into a liquefaction process development unit

    NASA Technical Reports Server (NTRS)

    Akhtar, S.; Friedman, S.; Mazzocco, N. J.; Yavorsky, P. M.

    1977-01-01

    A system for preparing coal slurry and feeding it into a high pressure liquefaction plant is described. The system was developed to provide supporting research and development for the Bureau of Mines coal liquefaction pilot plant. Operating experiences are included.

  4. Process to upgrade coal liquids by extraction prior to hydrodenitrogenation

    DOEpatents

    Schneider, Abraham; Hollstein, Elmer J.; Janoski, Edward J.; Scheibel, Edward G.

    1982-01-01

    Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

  5. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  6. Processing - Property Relationship in Advanced Intermetallics

    DTIC Science & Technology

    1994-07-01

    AD-A285 262 - IlE I !!III Illl iIII c.,. Processing- Property Relationship I in Advanced Intermetallics Final Report For Period March 4,1991 through...through 03-03-94 4. TITLE AND SUBTITLE 5. FUNDING NUMBERS Processing- Property Relationship in Advanced Intermetallics; 4. AUTHOR(S) D.A. Hardwick and P.L...2 M echanical Properties ......................................................................... 9 3 C

  7. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 15, April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1993-02-12

    The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  8. A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS

    SciTech Connect

    G.A. Robbins; R.A. Winschel; S.D. Brandes

    1999-05-01

    This is the first Annual Technical Report of activities under DOE Contract No. DE-AC22-94PC93054. Activities from the first three quarters of the fiscal 1998 year were reported previously as Quarterly Technical Progress Reports (DOE/PC93054-57, DOE/PC93054-61, and DOE/PC93054-66). Activities for the period July 1 through September 30, 1998, are reported here. This report describes CONSOL's characterization of process-derived samples obtained from HTI Run PB-08. These samples were derived from operations with Black Thunder Mine Wyoming subbituminous coal, simulated mixed waste plastics, and pyrolysis oils derived from waste plastics and waste tires. Comparison of characteristics among the PB-08 samples was made to ascertain the effects of feed composition changes. A comparison also was made to samples from a previous test (Run PB-06) made in the same processing unit, with Black Thunder Mine coal, and in one run condition with co-fed mixed plastics.

  9. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report No. 7, April 1993--June 1993

    SciTech Connect

    Curtis, C.W.; Chander, S.; Gutterman, C.

    1994-09-01

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. In addition, a synergistic effect has been demonstrated, in which solvent blends are more effective for coal swelling than the pure solvents alone. Therefore, it will be necessary to use only low levels of swelling agents and yet promote the impregnation of catalyst precursors. The rate of the impregnation of catalyst precursors into swollen coal increases greatly as the effectiveness of the solvent to swell the coal increases. This effect is also demonstrated by improved catalyst precursor impregnation with increased contact temperature. Laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent.

  10. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-12-31

    The evaluation of various catalyst pre or pyrene coal conversion continued. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate. A technique to measure the effect of coal swelling and catalyst impregnation upon coal liquefaction has been developed, and experimentation is under way. Reactivity tests have been performed using S0{sub 2}-treated and untreated swelled Black Thunder Coal. Thermal reactions with swelled coals yielded much less coal conversion and pyrene conversion than did the swelled coal reactions with Molyvan-L. The study of bottoms processing consists of coupling solvent deasphalting with delayed coking to maximize the production of coal-derived liquids while rejecting solids within the coke drum. The batch deasphalting screening tests have been completed. While n-butane/pentane solvent blends initially appeared best, pentane alone at 380{degree}F provided an oil yield (63.6 wt%) that was desired for subsequent tests. The production of asphalt for the transport tests is underway. The target deasphalted oil yields are 40, 50 and 60 wt% of feed. This would produce asphalt with ash levels ranging from 20 to 30 wt% with which to run the transport tests.

  11. Process for converting coal into liquid fuel and metallurgical coke

    DOEpatents

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  12. Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report

    SciTech Connect

    Prausnitz, J.M.

    1980-05-01

    This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

  13. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    2000-04-17

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3 % of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas. The effort during the reporting period has been devoted to testing the FHR-32 sorbent. FHR-32 sorbent was tested for 50 cycles of sulfidation in a laboratory scale reactor.

  14. Evaluation, engineering and development of advanced cyclone processes. Quarterly technical progress report No. 4, July 1, 1991--September 30, 1991

    SciTech Connect

    Not Available

    1991-12-31

    ``Evaluation, Engineering and Development of Advanced Cyclone Processes`` is a research and development project for the reduction of pyritic sulfur in coal. Project goals are to remove 80 to 90% of the ash and pyritic sulfur while retaining 80 to 90% of the parent coal`s heating value. A number of media and media separator options are to be evaluated and tested, culminating with the implementation of the preferred combination in a 1,000 lb/hr bench-scale process optimization circuit.

  15. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications: Task 9 - Selective agglomeration Module Testing and Evaluation.

    SciTech Connect

    Moro, N.` Jha, M.C.

    1997-09-29

    The primary goal of this project was the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing of both processes on six coals to optimize the processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report summarizes the findings of all the selective agglomeration (SA) test work performed with emphasis on the results of the PDU SA Module testing. Two light hydrocarbons, heptane and pentane, were tested as agglomerants in the laboratory research program which investigated two reactor design concepts: a conventional two-stage agglomeration circuit and a unitized reactor that combined the high- and low-shear operations in one vessel. The results were used to design and build a 25 lb/hr bench-scale unit with two-stage agglomeration. The unit also included a steam stripping and condensation circuit for recovery and recycle of heptane. It was tested on six coals to determine the optimum grind and other process conditions that resulted in the recovery of about 99% of the energy while producing low ash (1-2 lb/MBtu) products. The fineness of the grind was the most important variable with the D80 (80% passing size) varying in the 12 to 68 micron range. All the clean coals could be formulated into coal-water-slurry-fuels with acceptable properties. The bench-scale results were used for the conceptual and detailed design of the PDU SA Module which was integrated with the existing grinding and dewatering circuits. The PDU was operated for about 9 months. During the first three months, the shakedown testing was performed to fine tune the operation and control of various equipment. This was followed by parametric testing, optimization/confirmatory testing, and finally a

  16. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    SciTech Connect

    K. Osseo-Asare; X. Zeng

    2001-06-30

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. The partitioning behaviors of hematite in the dextran (Dex)/Triton X-100 (TX100) and polyethylene glycol (PEG)/dextran systems were investigated and the effects of some ionic surfactants on solid partition were studied. In both biphase systems, the particles stayed in the bottom dextran-rich phase under all pH conditions. This behavior is attributable to the fact that the hydrophilic oxide particles prefer the more hydrophilic bottom phase. Also, the strong favorable interaction between dextran and ferric oxide facilitates the dispersion of the solids in the polysaccharide-rich phase. In the Dex/TX100 system, addition of sodium dodecylsulfate (SDS) or potassium oleate had no effect on the solid partition; on the other hand, addition of dodecyltrimethylammonium bromide (DTAB) transferred the particles to the top phase or interface at high pH values. In the PEG/Dex system, the preferred location of hematite remained the bottom phase in the presence of either SDS or DTAB. The effects of anionic surfactants on the partition behavior are attributable to the fact that they are not able to replace the strongly adsorbed polysaccharide layer on the ferric oxide surface. The results with the cationic surfactant are due to electrostatic interaction between the cationic surfactant and the charged surface of the solid particles. The difference in solids partitioning in the two systems is the result of the different distribution of DTAB in these systems. In the Dex/TX100 system, DTAB prefers the top surfactant-rich phase, while it concentrates in the bottom phase in the PEG/dextran system.

  17. Research on the evolvement of morphology of coking coal during the coking process.

    PubMed

    Zhong, Xiangyun; Wu, Shiyong; Liu, Yang; Zhao, Zhenning; Zhang, Yaru; Bai, Jinfeng; Xu, Jun; Xi, Bai

    2013-12-01

    The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising.

  18. Development of a method for characterizing changes in coal and mineral surfaces resulting from beneficiation processes

    SciTech Connect

    Slomka, B.J.; Seward, K.J.; Dawson, M.R.; Buttermore, W.H.

    1989-01-01

    A novel method was developed for characterizing changes in coal and mineral surfaces resulting from sonication and other cleaning processes. This method employs a unique flow-cell to permit the dynamic measurement of dye adsorption on coal and mineral particle surfaces. The rates and extents of adsorption of ionic dyes on Illinois No. 6 coal were found to be dependent on mineral content and particle size of ground coal samples. A significant correlation was observed between the adsorbed quantity of dye and the total mineral content of coal. In preliminary experiments with methylene blue dye, clay was found to absorb significantly more of the dye than quartz, pyrite, calcite, or clean coal'' surfaces. By using dyes of differing adsorption selectivity, it is demonstrated that sonication reduces the apparent mineral content on the surface of coal. 9 refs., 7 fig., 3 tabs.

  19. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    SciTech Connect

    Not Available

    1980-11-01

    This report discusses the effects on SRC yields of seven process variables (reactor temperature, SRT, hydrogen partial pressure, recycle ash and coal concentrations, gas velocity and coal type) predicted by second-order regression models developed from a data base containing pilot plant data with both Kentucky and Powhatan coals. The only effect of coal type in the model is a shift in each yield by a constant factor. Although some differences were found between the models developed from the Kentucky data base (1) (which we call Kentucky models) and the pooled coal models, the general conclusions of the previous report are confirmed by the new models and the assumption of similar behavior of the two coals appears to be justified. In some respects the dependence of the yields (MAF coal basis) on variables such as pressure and temperature are clearer than in the previous models. The principal trends which emerge are discussed.

  20. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  1. Advanced design nuclear power plants: Competitive, economical electricity. An analysis of the cost of electricity from coal, gas and nuclear power plants

    SciTech Connect

    Not Available

    1992-06-01

    This report presents an updated analysis of the projected cost of electricity from new baseload power plants beginning operation around the year 2000. Included in the study are: (1) advanced-design, standardized nuclear power plants; (2) low emissions coal-fired power plants; (3) gasified coal-fired power plants; and (4) natural gas-fired power plants. This analysis shows that electricity from advanced-design, standardized nuclear power plants will be economically competitive with all other baseload electric generating system alternatives. This does not mean that any one source of electric power is always preferable to another. Rather, what this analysis indicates is that, as utilities and others begin planning for future baseload power plants, advanced-design nuclear plants should be considered an economically viable option to be included in their detailed studies of alternatives. Even with aggressive and successful conservation, efficiency and demand-side management programs, some new baseload electric supply will be needed during the 1990s and into the future. The baseload generating plants required in the 1990s are currently being designed and constructed. For those required shortly after 2000, the planning and alternatives assessment process must start now. It takes up to ten years to plan, design, license and construct a new coal-fired or nuclear fueled baseload electric generating plant and about six years for a natural gas-fired plant. This study indicates that for 600-megawatt blocks of capacity, advanced-design nuclear plants could supply electricity at an average of 4.5 cents per kilowatt-hour versus 4.8 cents per kilowatt-hour for an advanced pulverized-coal plant, 5.0 cents per kilowatt-hour for a gasified-coal combined cycle plant, and 4.3 cents per kilowatt-hour for a gas-fired combined cycle combustion turbine plant.

  2. Phase equilibrium in coal liquefaction processes. Final report

    SciTech Connect

    Chao, K.C.

    1984-08-01

    Gas-liquid equilibrium data have been determined in simulation of coal liquefaction process conditions in mixtures of light gases + heavy hydrocarbons to add to the accumulated data previously reported in EPRI AP-1593. The mixture systems newly investigated are: methane + 9,10 dihydrophenanthrene; hydrogen + methane + 1-methylnaphthalene; hydrogen + carbon dioxide + tetralin; hydrogen + carbon dioxide + 1-methynaphthalene; hydrogen + carbon dioxide + quinoline; nitrogen + tetralin, + n-hexadecane, + 1-methylnaphthalene, + quinoline, and + m-cresol. Correlations for the solubilities of methane and carbon dioxide have been developed from the data based on the use of solubility parameter. The solubility of hydrogen was correlated in EPRI AP-1593. Two equations of state are developed for the description of both the gas solubility and the vaporization of the heavy oil. The Chain-of-Rotators (COR) equation of state explicitly accounts for the rotational molecular motion contribution to the pressure of a fluid. The Cubic-Chain-of-Rotators (CCOR) equation is obtained upon simplifying the COR equation. Interaction constants in the CCOR equation have been determined for the light gases with the heavy hydrocarbons based on data from this project, and the constants are correlated. Equilibrium flash vaporization has been experimentally determined for three coal liquids and for their mixtures with hydrogen. The data are correlated with the CCOR equation of state. 74 figures, 46 tables.

  3. Novel use of residue from direct coal liquefaction process

    SciTech Connect

    Jianli Yang; Zhaixia Wang; Zhenyu Liu; Yuzhen Zhang

    2009-09-15

    Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA), a superior commercial modifier. Asphalts modified by two DCLRs meet the specifications of ASTM D5710 and BSI BS-3690 designated for the TLA-modified asphalts. The required addition amount for the DCLRs tested is less than that for TLA due possibly to the high content of asphaltene in DCLRs. Different compatibility was observed for the asphalts with the same penetration grade but from the different origin. Different components in the DCLR play different roles in the modification. Positive synergetic effects among the fractions were observed, which may due to the formation of the stable colloid structure. Unlike polymer-type modifier, the structure of asphalt-type modifier has a similarity with petroleum asphalts which favors the formation of a stable dispersed polar fluid (DPF) colloid structure and improves the performance of pavement asphalt. 12 refs., 1 fig., 6 tabs.

  4. Separation of products from mild coal gasification processes

    SciTech Connect

    Wallman, P.H.

    1991-09-11

    The primary mild coal gasification product mixture containing noncondensible gas, high-boiling hydrocarbon vapors and entrained fines is difficult to process into the desired pure products: gas, liquids, and dry solids. This challenge for mild coal gasification process development has been studied by surveying the technical literature for suitable separations processes and for similar issues in related processes. The choice for a first-stage solids separation step is standard cyclones, arranged in parallel trains for large-volume applications in order to take advantage of the higher separation efficiency of smaller cyclones. However, mild gasification pilot-plant data show entrainment of ultrafine particles for which standard cyclones have poor separation efficiency. A hot secondary solids separation step is needed for the ultrafine entrainment in order to protect the liquid product from excessive amounts of contaminating solids. The secondary solids separation step is similar to many high-temperature flue-gas applications with an important complicating condition: Mild gasifier vapors form coke on surfaces in contact with the vapors. Plugging of the filter medium by coke deposition is concluded to be the main product separation problem for mild gasification. Three approaches to solution of this problem are discussed in the order of preference: (1) a barrier filter medium made of a perforated foil that is easy to regenerate, (2) a high-efficiency cyclone coupled with recycle of a solids-containing tar fraction for coking/cracking in the gasifier, and (3) a granular moving bed filter with regeneration of the bed material. The condensation of oil vapors diluted by noncondensible gas is analyzed thermodynamically, and the conclusion is that existing commercial oil fractionator designs are adequate as long as the vapor stream does not contain excessive amounts of solids. 34 refs., 4 figs.

  5. Advanced planning for ISS payload ground processing

    NASA Astrophysics Data System (ADS)

    Page, Kimberly A.

    2000-01-01

    Ground processing at John F. Kennedy Space Center (KSC) is the concluding phase of the payload/flight hardware development process and is the final opportunity to ensure safe and successful recognition of mission objectives. Planning for the ground processing of on-orbit flight hardware elements and payloads for the International Space Station is a responsibility taken seriously at KSC. Realizing that entering into this operational environment can be an enormous undertaking for a payload customer, KSC continually works to improve this process by instituting new/improved services for payload developer/owner, applying state-of-the-art technologies to the advanced planning process, and incorporating lessons learned for payload ground processing planning to ensure complete customer satisfaction. This paper will present an overview of the KSC advanced planning activities for ISS hardware/payload ground processing. It will focus on when and how KSC begins to interact with the payload developer/owner, how that interaction changes (and grows) throughout the planning process, and how KSC ensures that advanced planning is successfully implemented at the launch site. It will also briefly consider the type of advance planning conducted by the launch site that is transparent to the payload user but essential to the successful processing of the payload (i.e. resource allocation, executing documentation, etc.) .

  6. Advanced Materials and Processing 2010

    NASA Astrophysics Data System (ADS)

    Zhang, Yunfeng; Su, Chun Wei; Xia, Hui; Xiao, Pengfei

    2011-06-01

    Strain sensors made from MWNT/polymer nanocomposites / Gang Yin, Ning Hu and Yuan Li -- Shear band evolution and nanostructure formation in titanium by cold rolling / Dengke Yang, Peter D. Hodgson and Cuie Wen -- Biodegradable Mg-Zr-Ca alloys for bone implant materials / Yuncang Li ... [et al.] -- Hydroxyapatite synthesized from nanosized calcium carbonate via hydrothermal method / Yu-Shiang Wu, Wen-Ku Chang and Min Jou -- Modeling of the magnetization process and orthogonal fluxgate sensitivity of ferromagnetic micro-wire arrays / Fan Jie ... [et al.] -- Fabrication of silicon oxide nanowires on Ni coated silicon substrate by simple heating process / Bo Peng and Kwon-Koo Cho -- Deposition of TiOxNy thin films with various nitrogen flow rate: growth behavior and structural properties / S.-J. Cho ... [et al.] -- Observation on photoluminescence evolution in 300 KeV self-ion implanted and annealed silicon / Yu Yang ... [et al.] -- Facile synthesis of lithium niobate from a novel precursor H[symbol] / Meinan Liu ... [et al.] -- Effects of the buffer layers on the adhesion and antimicrobial properties of the amorphous ZrAlNiCuSi films / Pai-Tsung Chiang ... [et al.] -- Fabrication of ZnO nanorods by electrochemical deposition process and its photovoltaic properties / Jin-Hwa Kim ... [et al.] -- Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys / Xiao Yang and Yong Zhang -- Modeling of centrifugal force field and the effect on filling and solidification in centrifugal casting / Wenbin Sheng, Chunxue Ma and Wanli Gu -- Electrochemical properties of TiO[symbol] nanotube arrays film prepared by anodic oxidation / Young-Jin Choi ... [et al.] -- Effect of Ce additions on high temperature properties of Mg-5Sn-3Al-1Zn alloy / Byoung Soo Kang ... [et al.] -- Sono-electroless plating of Ni-Mo-P film / Atsushi Chiba, Masato Kanou and Wen-Chang Wu -- Diameter dependence of giant magneto-impedance effect in co-based melt extracted amorphous

  7. Inhibition of retrogressive reactions in coal/petroleum co-processing. Final technical report

    SciTech Connect

    Schobert, H.H.; Tomic, J.

    1993-05-25

    The objective of this study was to examine the processes in coal/petroleum coprocessing systems which led to coke formation. Specifically, the interactions between the petroleum residue and coal, leading to retrogressive products, were investigated. Five coals were reacted with five model compounds in order to investigate the coal conversions in a variety of solvents and to determine the role of the solvent in promoting or inhibiting coal conversion. The selected model compounds range from paraffinic to fully aromatic and were chosen as representative of types of compounds that are found in petroleum residua. Coprocessing experiments were conducted using the five coals and three petroleum residua. The effect of temperature on coal conversions was crucial. The coal conversions at 350 and 400{degree}C seem to be governed by the nature of the coal and to a lesser extent by the petroleum residua. Negative coal conversions were observed above 400{degree}C indicating that retrogressive processes had occurred. At temperatures higher than 400{degree}C, the petroleum residua undergo physical and chemical transformations and the influence of the petroleum residua on coal conversions is significant. The structural features of the residues indicated that the residues were predominately coal-derived. An overall increase in aromaticity was observed with increasing temperature which was also accompanied by loss of oxygen functional groups. The retrogressive reactions with non-caking coals involve carbonyl and carboxyl group leading to a final solid characterized by a cross-linked structure. In the case of caking coal, these reactions are governed by loss of aromatic oxygen groups and loss of alkyl groups.

  8. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  9. Advanced Digital Signal Processing for Hybrid Lidar

    DTIC Science & Technology

    2013-09-30

    Advanced Digital Signal Processing for Hybrid Lidar William D. Jemison Clarkson University [Technical Section Technical Objectives The technical...objective of this project is the development and evaluation of various digital signal processing (DSP) algorithms that will enhance hybrid lidar ...algorithm as shown in Figure 1. Hardware Platform for Algorithm Implementation + Underwater Channel Characteristics ^ Lidar DSP Algorithm Figure

  10. Process for modifying the properties of a swelling coal, an installation for carrying out the process and a chamber for treatment of coal by fluidization and crushing

    SciTech Connect

    Delessard, S.L.; Kita, J.; Puff, R.M.

    1983-05-10

    The present invention relates to a process for modifying the properties of a swelling coal, to an installation for carrying out the process and to a chamber for treatment by fluidization and crushing. A percussion-type crusher is installed in a fluidization chamber at about 1 meter above the zone of connection between a duct for conveying coal by pneumatic transport and the chamber. A combustion chamber produces gases for transport and fluidization, having an oxygen content of at least 10%.

  11. Advanced NMR approaches in the characterization of coal. Final technical report, September 1, 1990--August 31, 1993

    SciTech Connect

    Maciel, G.E.

    1993-09-30

    This project addressed two main goals and one much smaller one. The main goals were (1) to improve the significance, reliability and information content in high-resolution NMR (nuclear magnetic resonance) characterization of coal samples and (2) to develop chemically informative NMR imaging techniques for coal. The minor goal was to explore advanced features of dynamic nuclear polarization (DNP) as a technique for coal characterization; this included the development of two DNP probes and the examination of DNP characteristics of various carbonaceous samples, including coals. {sup 13}C NMR advances for coal depended on large-sample MAS devices, employing either cross-polarization (CP) or direct polarization (DP) approaches. CP and DP spin dynamics and their relationships to quantitation and spin counting were elucidated. {sup 1}H NMR studies, based on CRAMPS, dipolar dephasing and saturation with perdeuteropyridine, led to a {sup 1}H NMR-based elucidation of chemical functionality in coal. {sup 1}H and {sup 13}C NMR imaging techniques, based on magic-angle spinning and rotating magnetic field gradients, were developed for introducing chemical shift information (hence, chemical detail) into the spatial imaging of coal. The TREV multiple-pulse sequence was found to be useful in the {sup 1}H CRAMPS imaging of samples like coal.

  12. Coal desulfurization by a microwave process. Technical progress report

    SciTech Connect

    Zavitsanos, P.D.; Golden, J.A.; Bleiler, K.W.

    1982-01-01

    Desulfurization experiments have been carried out using the moving bed flow reactor to examine the following: (1) hardgrove grindability index of microwave treated coal compared with raw coal; (2) washability of microwave treated coal compared with raw coal; (3) the extent of sulfur and ash removal from alkali/coal treated samples. In the washability experiments, the following treatment sequence was carried out: expose raw coal (1-2'' size) to microwaves (2 kW power level, 120 to 240 sec exposure); crush (30 to 200 mesh); float/sink (1.6 S.G.). Sulfur, ash and CV measurements were made on the float fractions for comparison with similar measurements on raw coal float samples prepared in the same way as microwave treated samples. Table 2 is a summary of the sulfur, ash and calorific value analyses comparing washed with raw coal samples. These data were used to calculate percent energy recovery as shown in the table. It is not possible to conclude from the data taken to date whether there is beneficiation from microwave treated-washed coal since two coals showed increased energy recovery and two did not. Additional washability data will be taken to pursue this question.

  13. Advanced research and technology: Direct utilization recovery of minerals from coal fly ash. Fossil energy program

    NASA Astrophysics Data System (ADS)

    Burnet, G.; Murtha, M. J.; Adelman, D. J.

    1980-12-01

    Methods for utilizing coal fly ash through processes for the extraction of alumina and titania, and for the separation and use of an iron-rich fraction are described. Research of the HiChlor process for the extraction of alumina and titania by high temperature chlorination of a fly ash reductant mixture is described. An engineering cost evaluation is presented for a centralized HiChlor processing facility to process the fly ash of several large coal fueled power stations. Investigations for a high temperature lime soda process for extraction of alumina from fly ash included the use of several types of quarry limestones and waste materials to replace the limestone and/or soda ash.

  14. 30 CFR 910.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 910.764 Section 910.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE GEORGIA § 910.764 Process for designating areas unsuitable for surface coal mining operations. Part 764 of this chapter, State Processes for Designating Areas Unsuitable for Surface...

  15. 30 CFR 903.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 903.764 Section 903.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE ARIZONA § 903.764 Process for designating areas unsuitable for surface coal mining operations. Part 764 of this chapter, State Processes for Designating Areas Unsuitable for Surface...

  16. 30 CFR 905.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 905.764 Section 905.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE CALIFORNIA § 905.764 Process for designating areas unsuitable for surface coal mining operations. Part 764 of this chapter, State Processes for Designating Areas Unsuitable for Surface...

  17. 30 CFR 912.764 - Process for designating areas unsuitable for surface coal mining operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... surface coal mining operations. 912.764 Section 912.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE IDAHO § 912.764 Process for designating areas unsuitable for surface coal mining operations. Part 764 of this chapter, State Processes for Designating Areas Unsuitable for Surface...

  18. Process for control of pollutants generated during coal gasification

    DOEpatents

    Frumerman, Robert; Hooper, Harold M.

    1979-01-01

    The present invention is directed to an improvement in the coal gasification process that effectively eliminates substantially all of the environmental pollutants contained in the producer gas. The raw producer gas is passed through a two-stage water scrubbing arrangement with the tars being condensed essentially water-free in the first stage and lower boiling condensables, including pollutant laden water, being removed in the second stage. The pollutant-laden water is introduced into an evaporator in which about 95 percent of the water is vaporized and introduced as steam into the gas producer. The condensed tars are combusted and the resulting products of combustion are admixed with the pollutant-containing water residue from the evaporator and introduced into the gas producer.

  19. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, July--September 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-12-31

    The experimental study of coal swelling ratios have been determined with a wide variety of solvents. Only marginal levels of coal swelling were observed for the hydrocarbon solvents, but high levels were found with solvents having heteroatom functionality. Blends were superior to pure solvents. The activity of various catalyst precursors for pyrene hydrogenation and coal conversion was measured. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively. Bottoms processing consists of a combination of the ASCOT process coupling solvent deasphalting with delayed coking. Initial results indicate that a blend of butane and pentane used near the critical temperature of butane is the best solvent blend for producing a yield/temperature relationship of proper sensitivity and yet retaining an asphalt phase of reasonable viscosity. The literature concerning coal swelling, both alone and in combination with coal liquefaction, and the use of dispersed or unsupported catalysts in coal liquefaction has been updated.

  20. Enhancement of surface properties for coal beneficiation

    SciTech Connect

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.