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Sample records for advanced light metals

  1. Environment assisted degradation mechanisms in advanced light metals

    NASA Technical Reports Server (NTRS)

    Gangloff, R. P.; Stoner, G. E.; Swanson, R. E.

    1989-01-01

    A multifaceted research program on the performance of advanced light metallic alloys in aggressive aerospace environments, and associated environmental failure mechanisms was initiated. The general goal is to characterize alloy behavior quantitatively and to develop predictive mechanisms for environmental failure modes. Successes in this regard will provide the basis for metallurgical optimization of alloy performance, for chemical control of aggressive environments, and for engineering life prediction with damage tolerance and long term reliability.

  2. Water cooled metal optics for the Advanced Light Source

    SciTech Connect

    McKinney, W.R.; Irick, S.C.; Lunt, D.L.J.

    1991-10-28

    The program for providing water cooled metal optics for the Advanced Light Source at Berkeley is reviewed with respect to fabrication and metrology of the surfaces. Materials choices, surface figure and smoothness specifications, and metrology systems for measuring the plated metal surfaces are discussed. Results from prototype mirrors and grating blanks will be presented, which show exceptionally low microroughness and mid-period error. We will briefly describe out improved version of the Long Trace Profiler, and its importance to out metrology program. We have completely redesigned the mechanical, optical and computational parts of the profiler system with the cooperation of Peter Takacs of Brookhaven, Continental Optical, and Baker Manufacturing. Most important is that one of our profilers is in use at the vendor to allow testing during fabrication. Metrology from the first water cooled mirror for an ALS beamline is presented as an example. The preplating processing and grinding and polishing were done by Tucson Optical. We will show significantly better surface microroughness on electroless nickel, over large areas, than has been reported previously.

  3. Advances in Thermal Spray Deposition of Billets for Particle Reinforced Light Metals

    NASA Astrophysics Data System (ADS)

    Wenzelburger, Martin; Zimmermann, Christian; Gadow, Rainer

    2007-04-01

    Forming of light-metals in semi-solid state offers some advantages like low process temperatures, improved mould durability, good flow behavior and fine, globular microstructure of the final material. By the introduction of ceramic particles, increased elastic modulus and yield strength as well as wear resistance and creep behavior can be obtained. By semi-solid forging or semi-solid casting, particle reinforced metals (PRM) can be produced with improved matrix microstructure and beneficial forming process parameters compared to conventional MMC manufacturing techniques. The production of this kind of light metal matrix composites requires the supply of dense semi-finished parts with well defined volume fractions of homogeneously distributed particulate reinforcement. A manufacturing method for cylindrical light metal billets is described that applies thermal spraying as a build-up process for simultaneous deposition of matrix and reinforcement phase with cored wires as spraying material. Thermal spraying leads to small grain sizes and prevents dendrite formation. However, long process cycle times lead to billet heating and recrystallization of the matrix microstructure. In order to preserve small grain sizes that enable semi-solid forming, the thermal spraying process was analyzed by in-flight particle analysis and thermography. As a consequence, the deposition process was optimized by adaptation of the thermal spraying parameters and by application of additional cooling, leading to lower billet temperatures and finer PRM billet microstructure.

  4. Advances in Thermal Spray Deposition of Billets for Particle Reinforced Light Metals

    SciTech Connect

    Wenzelburger, Martin; Zimmermann, Christian; Gadow, Rainer

    2007-04-07

    Forming of light-metals in semi-solid state offers some advantages like low process temperatures, improved mould durability, good flow behavior and fine, globular microstructure of the final material. By the introduction of ceramic particles, increased elastic modulus and yield strength as well as wear resistance and creep behavior can be obtained. By semi-solid forging or semi-solid casting, particle reinforced metals (PRM) can be produced with improved matrix microstructure and beneficial forming process parameters compared to conventional MMC manufacturing techniques. The production of this kind of light metal matrix composites requires the supply of dense semi-finished parts with well defined volume fractions of homogeneously distributed particulate reinforcement. A manufacturing method for cylindrical light metal billets is described that applies thermal spraying as a build-up process for simultaneous deposition of matrix and reinforcement phase with cored wires as spraying material. Thermal spraying leads to small grain sizes and prevents dendrite formation. However, long process cycle times lead to billet heating and recrystallization of the matrix microstructure. In order to preserve small grain sizes that enable semi-solid forming, the thermal spraying process was analyzed by in-flight particle analysis and thermography. As a consequence, the deposition process was optimized by adaptation of the thermal spraying parameters and by application of additional cooling, leading to lower billet temperatures and finer PRM billet microstructure.

  5. Light metals 1989

    SciTech Connect

    Campbell, P.G.

    1989-01-01

    This volume contains a cross section of the most important developments in the light metals field. The papers detail the latest solutions to problems in alumina and bauxite; carbon technology; cast shop technology; reduction technology; and reactive metals. Nearly every important company and research facility in the aluminum industry is represented. Light Metals 1989 is a reference for anyone in light metals technology.

  6. Light metal production

    DOEpatents

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  7. Light metals 1996

    SciTech Connect

    Hale, W.

    1996-10-01

    Light Metals 1996 presents the proceedings of the technical sessions of the TMS Light Metals Committee at the 125th TMS Annual Meeting held in Anaheim, California, February 4--8, 1996. Developments and innovation in the aluminum and reactive metals industries were covered including basic studies as well as their use and fabrication. The topics encompassed ore and its processing, aluminum reduction, carbon technology, casting technology, recycling, reactive metals, separation processes and waste processing. A number of papers involved mathematical modeling while others were about equipment and applications. One hundred and seventy nine papers were processed separately for inclusion on the data base.

  8. Advanced light source

    NASA Astrophysics Data System (ADS)

    Sah, R. C.

    1983-03-01

    The Advanced Light Source (ALS) is a new synchrotron radiation source which was proposed by Lawrence Berkeley Laboratory. The ALS will be a key component in a major new research facility, the National Center for Advanced Materials. The ALS will consist of an electron linear accelerator, a booster synchrotron, a 1.3-GeV electron storage ring, and a number of photon beam lines. Most of all photon beam lines will originate from wiggler and undulator magnets placed in the 12 long straight sections of the ALS. A very low electron beam emittance will provide photon beams of unsurpassed spectral brilliance from specially-designed undulators, and a high radiofrequency will produce very short pulse lengths.

  9. Advanced lighting guidelines: 1993. Final report

    SciTech Connect

    Eley, C.; Tolen, T.M.; Benya, J.R.; Rubinstein, F.; Verderber, R.

    1993-12-31

    The 1993 Advanced Lighting Guidelines document consists of twelve guidelines that provide an overview of specific lighting technologies and design application techniques utilizing energy-efficient lighting practice. Lighting Design Practice assesses energy-efficient lighting strategies, discusses lighting issues, and explains how to obtain quality lighting design and consulting services. Luminaires and Lighting Systems surveys luminaire equipment designed to take advantage of advanced technology lamp products and includes performance tables that allow for accurate estimation of luminaire light output and power input. The additional ten guidelines -- Computer-Aided Lighting Design, Energy-Efficient Fluorescent Ballasts, Full-Size Fluorescent Lamps, Compact Fluorescent Lamps, Tungsten-Halogen Lamps, Metal Halide and HPS Lamps, Daylighting and Lumen Maintenance, Occupant Sensors, Time Scheduling Systems, and Retrofit Control Technologies -- each provide a product technology overview, discuss current products on the lighting equipment market, and provide application techniques. This document is intended for use by electric utility personnel involved in lighting programs, lighting designers, electrical engineers, architects, lighting manufacturers` representatives, and other lighting professionals.

  10. Recent Advances in Lighting Science

    NASA Astrophysics Data System (ADS)

    Lapatovich, Walter P.

    2004-10-01

    Lighting is a global industry supplying a wide array of devices and systems that emit light ranging from incandescent lamps to light emitting diodes to electric discharge lamps. Electric discharge lamps are the most familiar plasma devices to most people. This work focuses on plasma light sources, some advances in this area and recent trends. Plasma light sources fall into two broad categories, namely low pressure and high pressure. The low-pressure lamps operate in the range of 40 to 500 Pa while the high-pressure lamps operate in the range of 0.1 to 15 MPa. The corresponding electron temperatures are about 1eV and 0.5 eV for the low and high-pressure lamps respectively. High-pressure lamps are treated under the assumption of local thermodynamic equilibrium wherein the gas temperature is equilibrated with the electron temperature. They are often called high intensity discharge lamps because of their intrinsically high radiance. Within these two broad categories are many subgroups, perhaps the most important being mercury and non-mercury containing lamps. An example of a low pressure, mercury-containing lamp is the ubiquitous fluorescent lamp. Attempts to improve the efficiency of these lamps center around inductive excitation techniques and two-photon phosphor development. The plasma research on mercury-free low-pressure lamps is focused on finding substitutes for a mercury-rare gas discharge. Several ultraviolet emitting candidates have been explored which emit both UV and visible. Longer wavelength UV is of interest because of the parallel development of phosphors mated with LED excitation wavelengths around 380nm. Several examples will be discussed. There have been major advances in high intensity discharge lamps with and without mercury. Mercury containing metal halide lamps are now being fabricated from translucent ceramic envelopes instead of the conventional vitreous silica. The higher temperature tolerant envelope materials permit using discharges in

  11. Advanced process characterization of a 10nm Metal 1 Logic layer using light source modulation and monitoring

    NASA Astrophysics Data System (ADS)

    Alagna, Paolo; Zurita, Omar; Timoshkov, Vadim; Wong, Patrick; Rechtsteiner, Greg; Baselmans, Jan; Mailfert, Julien; Conley, Will; Hsieh, Simon

    2015-09-01

    As ArF immersion lithography continues to be extended by adopting multi-patterning techniques, imaging requirements continue to become more stringent [1-3]. For multiple patterning based logic devices, the optimal printability is not only driven by the optimization of the optical proximity correction (OPC), but also by complex process factors, such as resist, exposure tool, and mask-related error performance levels. In addition the light source plays a crucial role; it has been widely demonstrated [4-8] how changes in the E95 bandwidth can significantly lead to changes in on wafer patterning due image contrast changes. Cymer has developed novel computational and experimental approaches to enable process characterization studies [9-11]. Using these techniques, simulations were used to assess how E95 bandwidth changes can erode the CDU budget on ≤ 20 nm logic features. Using the results of these simulations, experimental conditions were defined to study the on wafer impact of light source performance on an imec N10 Logic-type test vehicle via six different Metal 1 Logic features. The imaging metrics used to track patterning response are process window (PW), line width roughness (LWR), and local critical dimension uniformity (LCDU).

  12. Light metal explosives and propellants

    DOEpatents

    Wood, Lowell L.; Ishikawa, Muriel Y.; Nuckolls, John H.; Pagoria, Phillip F.; Viecelli, James A.

    2005-04-05

    Disclosed herein are light metal explosives, pyrotechnics and propellants (LME&Ps) comprising a light metal component such as Li, B, Be or their hydrides or intermetallic compounds and alloys containing them and an oxidizer component containing a classic explosive, such as CL-20, or a non-explosive oxidizer, such as lithium perchlorate, or combinations thereof. LME&P formulations may have light metal particles and oxidizer particles ranging in size from 0.01 .mu.m to 1000 .mu.m.

  13. Metallic fuels for advanced reactors

    NASA Astrophysics Data System (ADS)

    Carmack, W. J.; Porter, D. L.; Chang, Y. I.; Hayes, S. L.; Meyer, M. K.; Burkes, D. E.; Lee, C. B.; Mizuno, T.; Delage, F.; Somers, J.

    2009-07-01

    In the framework of the Generation IV Sodium Fast Reactor Program, the Advanced Fuel Project has conducted an evaluation of the available fuel systems supporting future sodium cooled fast reactors. This paper presents an evaluation of metallic alloy fuels. Early US fast reactor developers originally favored metal alloy fuel due to its high fissile density and compatibility with sodium. The goal of fast reactor fuel development programs is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional fast spectrum nuclear fuel while destroying recycled actinides. This will provide a mechanism for closure of the nuclear fuel cycle. Metal fuels are candidates for this application, based on documented performance of metallic fast reactor fuels and the early results of tests currently being conducted in US and international transmutation fuel development programs.

  14. Metal halide perovskite light emitters

    PubMed Central

    Kim, Young-Hoon; Cho, Himchan; Lee, Tae-Woo

    2016-01-01

    Twenty years after layer-type metal halide perovskites were successfully developed, 3D metal halide perovskites (shortly, perovskites) were recently rediscovered and are attracting multidisciplinary interest from physicists, chemists, and material engineers. Perovskites have a crystal structure composed of five atoms per unit cell (ABX3) with cation A positioned at a corner, metal cation B at the center, and halide anion X at the center of six planes and unique optoelectronic properties determined by the crystal structure. Because of very narrow spectra (full width at half-maximum ≤20 nm), which are insensitive to the crystallite/grain/particle dimension and wide wavelength range (400 nm ≤ λ ≤ 780 nm), perovskites are expected to be promising high-color purity light emitters that overcome inherent problems of conventional organic and inorganic quantum dot emitters. Within the last 2 y, perovskites have already demonstrated their great potential in light-emitting diodes by showing high electroluminescence efficiency comparable to those of organic and quantum dot light-emitting diodes. This article reviews the progress of perovskite emitters in two directions of bulk perovskite polycrystalline films and perovskite nanoparticles, describes current challenges, and suggests future research directions for researchers to encourage them to collaborate and to make a synergetic effect in this rapidly emerging multidisciplinary field. PMID:27679844

  15. Advanced Light Source elliptical wiggler

    NASA Astrophysics Data System (ADS)

    Hoyer, E.; Akre, J.; Humphries, D.; Marks, S.; Minamihara, Y.; Pipersky, P.; Plate, D.; Schlueter, R.

    1995-02-01

    A 3.5-m-long elliptical wiggler, optimized to produce elliptically polarized light in the 50 eV to 10 keV range, is currently under design and construction at the Advanced Light Source at Lawrence Berkeley Laboratory. Calculations of spectral performance show that the flux of circularly polarized photons exceeds 1013 photons/s over the 50 eV to 10 keV operating range for current of 0.4 A and 1.5 GeV electron energy. This device features vertical and horizontal magnetic structures of 14 and 141/2 periods, respectively. The period length is 20.0 cm. The vertical structure is a hybrid permanent magnet design with tapered pole tips that produce a peak field of 2.0 T. The horizontal structure is an iron core electromagnetic design, shifted longitudinally 1/4 period, that is tucked between the upper and lower vertical magnetic structure sections. A maximum peak oscillating field of 0.095 T at a frequency up to 1 Hz will be achieved by excitation of the horizontal poles with a trapezoidal current waveform. The vacuum chamber is an unconventional design that is removable from the magnetic structure, after magnetic measurements, for UHV processing. The chamber is fabricated from non-magnetic stainless steel to minimize the effects of eddy currents. Device design is presented.

  16. Metallic nano-particles for trapping light.

    PubMed

    Tang, Yongan; Vlahovic, Branislav

    2013-02-07

    We study metallic nano-particles for light trapping by investigating the optical absorption efficiency of the hydrogenated amorphous silicon thin film with and without metallic nano-particles on its top. The size and shape of these nano-particles are investigated as to their roles of light trapping: scattering light to the absorption medium and converting light to surface plasmons. The optical absorption enhancement in the red light region (e.g., 650nm) due to the light trapping of the metallic nano-particles is observed when a layer of metallic nano-particle array has certain structures. The investigation of the light with incident angles shows the importance of the coupling efficiency of light to surface plasmons in the metallic nano-particle light trapping. PACS: 73.20.Mf, 42.25.s, 88.40.hj.

  17. Advanced Light Source Activity Report 2000

    SciTech Connect

    Greiner, A.; Moxon, L.; Robinson, A.; Tamura, L.

    2001-04-01

    This is an annual report, detailing activities at the Advanced Light Source for the year 2000. It includes highlights of scientific research by users of the facility as well as information about the development of the facility itself.

  18. Advanced Light Source Activity Report 2002

    SciTech Connect

    Duque, Theresa; Greiner, Annette; Moxon, Elizabeth; Robinson, Arthur; Tamura, Lori

    2003-06-12

    This annual report of the Advanced Light Source details science highlights and facility improvements during the year. It also offers information on events sponsored by the facility, technical specifications, and staff and publication information.

  19. Shining light on metals in the environment

    SciTech Connect

    McNear, Jr., D.H.; Tappero, R.; Sparks, D.L.

    2010-07-20

    Elucidating the speciation of heavy metals in the environment is paramount to understanding their potential mobility and bioavailability. Cutting-edge synchrotron-based techniques such as microfocused X-ray absorption fine-structure (XAFS) and X-ray fluorescence (XRF) spectroscopy and microtomography have revolutionized the way metal reactions and processes in natural systems are studied. In this article, we apply these intense-light tools to decipher metal forms (species) and associations in contaminated soils and metal-hyperaccumulating plants.

  20. Advanced controls for light sources

    NASA Astrophysics Data System (ADS)

    Biedron, S. G.; Edelen, A. L.; Milton, S. V.

    2016-09-01

    We present a summary of our team's recent efforts in developing adaptive, artificial intelligence-inspired techniques specifically to address several control challenges that arise in machines/systems including those in particle accelerator systems. These techniques can readily be adapted to other systems such as lasers, beamline optics, etc… We are not at all suggesting that we create an autonomous system, but create a system with an intelligent control system, that can continually use operational data to improve itself and combines both traditional and advanced techniques. We believe that the system performance and reliability can be increased based on our findings. Another related point is that the controls sub-system of an overall system is usually not the heart of the system architecture or design process. More bluntly, often times all of the peripheral systems are considered as secondary to the main system components in the architecture design process because it is assumed that the controls system will be able to "fix" challenges found later with the sub-systems for overall system operation. We will show that this is not always the case and that it took an intelligent control application to overcome a sub-system's challenges. We will provide a recent example of such a "fix" with a standard controller and with an artificial intelligence-inspired controller. A final related point to be covered is that of system adaptation for requirements not original to a system's original design.

  1. The Advanced Light Source: Technical Design

    SciTech Connect

    Authors, Various

    1984-05-01

    The Advanced Light Source (ALS) is a synchrotron radiation source consisting of a 50-MeV linear accelerator, a 1.3-GeV 'booster' synchrotron, a 1.3-GeV electron storage ring, and a number of photon beam lines, as shown in Figure 1. As an introduction to a detailed description of the Advanced Light Source, this section provides brief discussions on the characteristics of synchrotron radiation and on the theory of storage rings. Appendix A contents: Introduction to Synchrotron-Radiation Sources; Storage Ring; Injection System; Control System; Insertion Devices; Photon Beam Lines; and References.

  2. Monitoring performance of the Advanced Light Source

    SciTech Connect

    Byrne, Warren E.; Lampo, Edward J.; Samuelson, Bruce C.

    2001-06-13

    Providing high quality light to users in a consistent and reliable manner is one of the main goals of the accelerator physics group at the Advanced Light source (ALS). To meet this goal considerable time is spent monitoring the performance of the machine. At the Group's weekly meeting the performance of the accelerator over the previous week's run is reviewed. This paper describes the parameters that are monitored to optimize the performance of the ALS.

  3. Laser light scattering instrument advanced technology development

    NASA Technical Reports Server (NTRS)

    Wallace, J. F.

    1993-01-01

    The objective of this advanced technology development (ATD) project has been to provide sturdy, miniaturized laser light scattering (LLS) instrumentation for use in microgravity experiments. To do this, we assessed user requirements, explored the capabilities of existing and prospective laser light scattering hardware, and both coordinated and participated in the hardware and software advances needed for a flight hardware instrument. We have successfully breadboarded and evaluated an engineering version of a single-angle glove-box instrument which uses solid state detectors and lasers, along with fiber optics, for beam delivery and detection. Additionally, we have provided the specifications and written verification procedures necessary for procuring a miniature multi-angle LLS instrument which will be used by the flight hardware project which resulted from this work and from this project's interaction with the laser light scattering community.

  4. Biogenic metals in advanced water treatment.

    PubMed

    Hennebel, Tom; De Gusseme, Bart; Boon, Nico; Verstraete, Willy

    2009-02-01

    Microorganisms can change the oxidation state of metals and concomitantly deposit metal oxides and zerovalent metals on or into their cells. The microbial mechanisms involved in these processes have been extensively studied in natural environments, and researchers have recently gained interest in the applications of microbe-metal interactions in biotechnology. Because of their specific characteristics, such as high specific surface areas and high catalytic reactivity, biogenic metals offer promising perspectives for the sorption and (bio)degradation of contaminants. In this review, the precipitation of biogenic manganese and iron species and the microbial reduction of precious metals, such as palladium, platinum, silver and gold, are discussed with specific attention to the application of these biogenic metals in innovative remediation technologies in advanced water treatment.

  5. Advances in Nanocarbon Metals: Process

    DTIC Science & Technology

    2015-03-01

    covetic production system was designed and built. This system addressed the 3 distinct reaction steps: 1) C dissolves in copper (Cu), where the...metal (Cu).  The applied current causes local heating where the electrodes enter the Cu melt.  C dissolves in Cu where the temperature is locally...oxygen (O). 3 4) Experimental test, using a high‐temperature microscope (laser scanning confocal microscopy), of the proposal that C dissolves from

  6. Preliminary results from an advanced lighting controlstestbed

    SciTech Connect

    Avery, Douglas; Jennings, Judity; Rubinstein, Francis

    1998-03-01

    Preliminary results from a large-scale testbed of advanced lighting control technologies at the Phillip Burton Federal Building at 450 Golden Gate Ave. in San Francisco are presented. The first year objective of this project is to determine the sustainable energy savings and cost-effectiveness of different lighting control technologies compared to a portion of the building where only minimal controls are installed. The paper presents the analyzed results from six months of tests focused on accurately characterizing the energy savings potential of one type of daylight-linked lighting controls compared to the lighting in similar open-planned areas without dimming controls. After analyzing a half year;s data, we determined that the annual energy savings for this type of daylight- linked controls was 41% and 30% for the outer rows of lights on the South and North sides of the building, respectively. The annual energy savings dropped to 22% and 16% for the second row of lights for the South and North, respectively, and was negligible for the third rows of lights.

  7. Advances in Light Microscopy for Neuroscience

    PubMed Central

    Wilt, Brian A.; Burns, Laurie D.; Ho, Eric Tatt Wei; Ghosh, Kunal K.; Mukamel, Eran A.

    2010-01-01

    Since the work of Golgi and Cajal, light microscopy has remained a key tool for neuroscientists to observe cellular properties. Ongoing advances have enabled new experimental capabilities using light to inspect the nervous system across multiple spatial scales, including ultrastructural scales finer than the optical diffraction limit. Other progress permits functional imaging at faster speeds, at greater depths in brain tissue, and over larger tissue volumes than previously possible. Portable, miniaturized fluorescence microscopes now allow brain imaging in freely behaving mice. Complementary progress on animal preparations has enabled imaging in head-restrained behaving animals, as well as time-lapse microscopy studies in the brains of live subjects. Mouse genetic approaches permit mosaic and inducible fluorescence-labeling strategies, whereas intrinsic contrast mechanisms allow in vivo imaging of animals and humans without use of exogenous markers. This review surveys such advances and highlights emerging capabilities of particular interest to neuroscientists. PMID:19555292

  8. Advances in light microscopy for neuroscience.

    PubMed

    Wilt, Brian A; Burns, Laurie D; Wei Ho, Eric Tatt; Ghosh, Kunal K; Mukamel, Eran A; Schnitzer, Mark J

    2009-01-01

    Since the work of Golgi and Cajal, light microscopy has remained a key tool for neuroscientists to observe cellular properties. Ongoing advances have enabled new experimental capabilities using light to inspect the nervous system across multiple spatial scales, including ultrastructural scales finer than the optical diffraction limit. Other progress permits functional imaging at faster speeds, at greater depths in brain tissue, and over larger tissue volumes than previously possible. Portable, miniaturized fluorescence microscopes now allow brain imaging in freely behaving mice. Complementary progress on animal preparations has enabled imaging in head-restrained behaving animals, as well as time-lapse microscopy studies in the brains of live subjects. Mouse genetic approaches permit mosaic and inducible fluorescence-labeling strategies, whereas intrinsic contrast mechanisms allow in vivo imaging of animals and humans without use of exogenous markers. This review surveys such advances and highlights emerging capabilities of particular interest to neuroscientists.

  9. The metallicity of diffuse intrahalo light

    NASA Astrophysics Data System (ADS)

    Purcell, Chris W.; Bullock, James S.; Zentner, Andrew R.

    2008-12-01

    We make predictions for the metallicity of diffuse stellar components in systems ranging from small spiral galaxies to rich galaxy clusters. We extend the formalism of Purcell, Bullock & Zentner, in which diffuse stellar mass is produced via galaxy disruption, and we convolve this result with the observed mass-metallicity relation for galaxies in order to analyse the chemical abundance of intrahalo light (IHL) in host haloes with virial mass 1010.5 <= Mhost <= 1015Msolar. We predict a steep rise of roughly 2 dex in IHL metallicity from the scales of small to large spiral galaxies. In terms of the total dynamical mass Mhost of the host systems under consideration, we predict diffuse light metallicities ranging from ZIHL <~ -2.5 for Mhost ~ 1011Msolar to ZIHL ~ -1.0 for Mhost ~ 1012Msolar. In larger systems, we predict a more shallow rise in this trend with ZIHL ~ -0.4 for Mhost ~ 1013Msolar, increasing to ZIHL ~ 0.1 for Mhost ~ 1015Msolar. This behaviour is coincident with a narrowing of the intrahalo metallicity distribution as host mass increases. The observable distinction in surface brightness between old, metal-poor IHL stars and more metal rich, dynamically younger tidal streams is of crucial importance when estimating the chemical abundance of an intrahalo population with multiple origins.

  10. LIGHT SOURCE: Conceptual design of Hefei advanced light source

    NASA Astrophysics Data System (ADS)

    Li, Wei-Min; Wang, Lin; Feng, Guang-Yao; Zhang, Shan-Cai; Wu, Cong-Feng; Xu, Hong-Liang; Liu, Zu-Ping

    2009-06-01

    The conceptual of Hefei Advanced Light Source, which is an advanced VUV and Soft X-ray source, was developed at NSRL of USTC. According to the synchrotron radiation user requirements and the trends of SR source development, some accelerator-based schemes were considered and compared; furthermore storage ring with ultra low emittance was adopted as the baseline scheme of HALS. To achieve ultra low emittance, some focusing structures were studied and optimized in the lattice design. Compromising of emittance, on-momentum and off-momentum dynamic aperture and ring scale, five bend acromat (FBA) was employed. In the preliminary design of HALS, the emittance was reduced to sub nm · rad, thus the radiation up to water window has full lateral coherence. The brilliance of undulator radiation covering several eVs to keVs range is higher than that of HLS by several orders. The HALS should be one of the most advanced synchrotron radiation light sources in the world.

  11. Buckling tests of light-metal tubes

    NASA Technical Reports Server (NTRS)

    Schroeder, August

    1929-01-01

    I will attempt to determine mathematically the buckling-strength curves of various centrally loaded light-metal tubes which exhibit conspicuous differences of behavior under compressive loads. For this purpose I will employ Von Karman's method, after adapting it to special conditions.

  12. Recent advances in the spin Hall effect of light.

    PubMed

    Ling, Xiaohui; Zhou, Xinxing; Huang, Kun; Liu, Yachao; Qiu, Cheng-Wei; Luo, Hailu; Wen, Shuangchun

    2017-03-30

    The spin Hall effect (SHE) of light, as an analogue of the SHE in electronic systems, is a promising candidate for investigating the SHE in semiconductor spintronics/valleytronics, high-energy physics and condensed matter physics, owing to their similar topological nature in the spin-orbit interaction. The SHE of light exhibits unique potential for exploring the physical properties of nanostructures, such as determining the optical thickness, and the material properties of metallic and magnetic thin films and even atomically thin two-dimensional materials. More importantly, it opens a possible pathway for controlling the spin states of photons and developing next-generation photonic spin Hall devices as a fundamental constituent of the emerging spinoptics. In this review, based on the viewpoint of the geometric phase gradient, we give a detailed presentation of the recent advances in the SHE of light and its applications in precision metrology and future spin-based photonics.

  13. Recent Advances of Light-Mediated Theranostics

    PubMed Central

    Ai, Xiangzhao; Mu, Jing; Xing, Bengang

    2016-01-01

    -triggered theranostic strategies and introduced their great advances in biomedical applications in recent years. Moreover, some other promising light-assisted techniques, such as photoacoustic and Cerenkov radiation, were also systemically discussed. Finally, the potential challenges and future perspectives for light-mediated deep-tissue diagnosis and therapeutics were proposed. PMID:27877246

  14. Visible Inelastic Light Scattering from Metals

    NASA Astrophysics Data System (ADS)

    Wilkinson, Roger Allen

    In this work we studied the spectral shape of the intense continuum of light scattered inelastically from "bare" metals used in Surface Enhanced Raman Scattering. We derived cross sections, presented their spectral properties, and experimentally sought to characterize the observable spectral shape. Three scattering cross sections are derived. The development includes exposure of assumptions and limitations in the derivation. Elucidated are: contributions due to the few angstrom drastic spatial and polarization variations of the applied electromagnetic field at jellium metal surfaces; fluctuation induced light scattering, such as, spin density, charge density (plasmon and single electron), and current density fluctuations; and the light coupling operators that arise from a choice of gauge used in photoemission rather than the customary Coulomb gauge. The result is a set of matrix elements that carry the important physics of light scattering by metallic electrons, and that is more complete than is found in the Surface Enhanced Raman literature. Using one of these matrix elements in the electric dipole approximation we have developed a quantum chemistry computer algorithm to evaluate the strength of light interaction with any metal surface which can be modeled as a cluster. The algorithm uses spd Slater-type bases and can study transition and noble metals. It was tested on some model systems. A formalism is presented for further developing the algorithm to calculate adsorbed molecular vibrational Raman cross sections in the limit of the long wavelength electric dipole approximation. We further present known continuum spectral shapes from familiar light coupling operators (a subset of those we derived) and associate them with our experimentally observed spectral shapes. In the experimental study of spectral shapes we found the mechanical disorder, due to cold working smooth metals during polishing, to correlate with the strength of the continuum. Using microscopic

  15. How Light Is Emitted by Plasmonic Metals.

    PubMed

    Mertens, Jan; Kleemann, Marie-Elena; Chikkaraddy, Rohit; Narang, Prineha; Baumberg, Jeremy J

    2017-04-12

    The mechanism by which light is emitted from plasmonic metals such as gold and silver has been contentious, particularly at photon energies below direct interband transitions. Using nanoscale plasmonic cavities, blue-pumped light emission is found to directly track dark-field scattering on individual nanoconstructs. By exploiting slow atomic-scale restructuring of the nanocavity facets to spectrally tune the dominant gap plasmons, this correlation can be measured from 600 to 900 nm in gold, silver, and mixed constructs ranging from spherical to cube nanoparticles-on-mirror. We show that prompt electronic Raman scattering is responsible and confirm that "photoluminescence", which implies phase and energy relaxation, is not the right description. Our model suggests how to maximize light emission from metals.

  16. An Upgrade for the Advanced Light Source

    SciTech Connect

    Chemla, Daniel S.; Feinberg, Benedict; Hussain, Zahid; Kirz, Janos; Krebs, Gary F.; Padmore, Howard A.; Robin, David S.; Robinson, Arthur L.; Smith, Neville V.

    2004-09-01

    One of the first third-generation synchrotron light sources, the ALS, has been operating for almost a decade at Berkeley Lab, where experimenters have been exploiting its high brightness for forefront science. However, accelerator and insertion-device technology have significantly changed since the ALS was designed. As a result, the performance of the ALS is in danger of being eclipsed by that of newer, more advanced sources. The ALS upgrade that we are planning includes full-energy, top-off injection with higher storage-ring current and the replacement of five first-generation insertion devices with nine state-of-the art insertion devices and four new application-specific beamlines now being identified in a strategic planning process. The upgrade will help keep the ALS at the forefront of soft x-ray synchrotron light sources for the next two decades.

  17. Advanced Light Source beam diagnostics systems

    SciTech Connect

    Hinkson, J.

    1993-10-01

    The Advanced Light Source (ALS), a third-generation synchrotron light source, has been recently commissioned. Beam diagnostics were very important to the success of the operation. Each diagnostic system is described in this paper along with detailed discussion of its performance. Some of the systems have been in operation for two years. Others, in the storage ring, have not yet been fully commissioned. These systems were, however, working well enough to provide the essential information needed to store beam. The devices described in this paper include wall current monitors, a beam charge monitor, a 50 ohm Faraday cup, DC current transformers, broad-hand striplines, fluorescence screens, beam collimators and scrapers, and beam position monitors. Also, the means by which waveforms are digitized and displayed in the control room is discussed.

  18. Advanced Light Source beam position monitor

    SciTech Connect

    Hinkson, J.

    1991-10-28

    The Advanced Light Source (ALS) is a synchrotron radiation facility nearing completion at LBL. As a third-generation machine, the ALS is designed to produce intense light from bend magnets, wigglers, and undulators (insertion devices). The facility will include a 50 MeV electron linear accelerator, a 1.5 GeV booster synchrotron, beam transport lines, a 1--2 GeV storage ring, insertion devices, and photon beam lines. Currently, the beam injection systems are being commissioned, and the storage ring is being installed. Electron beam position monitors (BPM) are installed throughout the accelerator and constitute the major part of accelerator beam diagnostics. The design of the BPM instruments is complete, and 50 units have been constructed for use in the injector systems. We are currently fabricating 100 additional instruments for the storage ring. In this paper I discuss engineering fabrication, testing and performance of the beam pickup electrodes and the BPM electronics.

  19. Operator scheduling at the Advanced Light Source

    SciTech Connect

    Miller, B.

    1998-06-01

    Scheduling Operations staff at the Advanced Light Source (ALS) has evolved from 5 shifts/week for commissioning operations in 1992 to the present 24 hour/day, 21 shift coverage as the ALS went to full operation for users. A number of schedules were developed and implemented in an effort to accommodate changing ALS shift coverage requirements. The present work schedule and the lessons learned, address a number of issues that are useful to any facility that is operating 24 hours/day, 7 days/week.

  20. Scientific opportunities at the advanced light source

    NASA Astrophysics Data System (ADS)

    Robinson, A. L.

    1989-04-01

    The Advanced Light Source (ALS) is a national user facility for the production of high-brightness and partially coherent X-ray and ultraviolet synchrotron radiation. Now under construction at the Lawrence Berkeley Laboratory with a projected completion date of September 1992, the ALS is based on a low-emittance electron storage ring optimized for operation at 1.5 GeV with insertion devices in eleven long straight sections. It will also have up to 48 bending-magnet ports. Scientific opportunities in materials science, surface science, chemistry, atomic and molecular physics, life science and other fields are reflected in Letters of Interest received for the establishment of beamlines.

  1. Status of the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Marx, Jay N.

    1991-01-01

    The Advanced Light Source (ALS) now under construction at the Lawrence Berkeley Laboratory will be a national user facility for the production ofhigh-brightness and partially coherent soft x-ray and ultraviolet synchrotron radiation. The ALS is based on a low-emittance electron storage ring optimized for operation at 1. 5 GeV with insertion devices in 10 long straight sections and 24 premier bend-magnet ports. High-brightness photon beams from less than 10 eV to more than 2 keY will be produced by undulators thereby providing many research opportunities in materials and surface science biology atomic physics and chemistry. Wigglers and bend magnets will provide high-flux broad-band radiation at energies to 10 keY. 2.

  2. Research opportunities at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Robinson, A. L.; Schlachter, A. S.

    1991-05-01

    The Advanced Light Source (ALS), now under construction at the Lawrence Berkeley Laboratory, is a third-generation synchrotron radiation facility based on a low-emittance, 1.5-GeV electron storage ring with ten long straight sections available for insertion devices and, initially, 24 bend-magnet ports. Undulators will provide high-brightness radiation at photon energies from below 10 eV to above 2 keV; wiggler and bend-magnet radiation will extend the spectral coverage with high fluxes to above 10 keV. Scheduled to begin operations as a US Department of Energy national user facility in the spring of 1993, the ALS will support an extensive research program in which soft X-ray and ultraviolet radiation is used to study matter in all its varied gaseous, liquid and solid forms. Participating research teams to implement the initial scientific program have been selected.

  3. Advanced Light Source: Activity report 1993

    SciTech Connect

    Not Available

    1994-11-01

    The Advanced Light Source (ALS) produces the world`s brightest light in the ultraviolet and soft x-ray regions of the spectrum. The first low-energy third-generation synchrotron source in the world, the ALS provides unprecedented opportunities for research in science and technology not possible anywhere else. This year marked the beginning of operations and the start of the user research program at the ALS, which has already produced numerous high quality results. A national user facility located at Lawrence Berkeley Laboratory of the University of California, the ALS is available to researchers from academia, industry, and government laboratories. This report contains the following: (1) director`s message; (2) operations overview; (3) user program; (4) users` executive committee; (5) industrial outreach; (6) accelerator operations; (7) beamline control system; (8) insertion devices; (9) experimental systems; (10) beamline engineering; (11) first results from user beamlines; (12) beamlines for 1994--1995; (13) special events; (14) publications; (15) advisory panels; and (16) ALS staff.

  4. An ALS (Advanced Light Source) handbook

    SciTech Connect

    Not Available

    1988-11-01

    This booklet aims to provide the prospective user of the Advanced Light Source with a concise description of the radiation a researcher might expect at his or her experimental station. The focus is therefore on the characteristics of the light that emerges from insertion devices and bending magnets and on how components of the beam lines further alter the properties of the radiation. The specifications and operating parameters of the ALS injection system and storage ring are of only peripheral interest. To this end, Sections 3 and 5 and most of Section 4 are devoted to summary presentations, by means of performance plots and tabular compilations, of radiation characteristics at the ALS--spectral brightness, flux, coherent power, resolution, time structure, etc.--assuming a representative set of four undulators and one wiggler and a corresponding set of five beam lines. As a complement to these performance summaries, Section 1 is a general introductory discussion of synchrotron radiation and the ALS, and Section 2 provides a compendious introduction to the characteristics of synchrotron radiation from bending magnets, wigglers, and undulators. In addition, Section 4 briefly introduces the theory of diffraction grating and crystal monochromators. 15 refs., 28 figs., 5 tabs.

  5. Superbend upgrade on the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Robin, D.; Krupnick, J.; Schlueter, R.; Steier, C.; Marks, S.; Wang, B.; Zbasnik, J.; Benjegerdes, R.; Biocca, A.; Bish, P.; Brown, W.; Byrne, W.; Chen, J.; Decking, W.; DeVries, J.; DeMarco, W. R.; Fahmie, M.; Geyer, A.; Harkins, J.; Henderson, T.; Hinkson, J.; Hoyer, E.; Hull, D.; Jacobson, S.; McDonald, J.; Molinari, P.; Mueller, R.; Nadolski, L.; Nishimura, H.; Nishimura, K.; Ottens, F.; Paterson, J. A.; Pipersky, P.; Portmann, G.; Ritchie, A.; Rossi, S.; Salvant, B.; Scarvie, T.; Schmidt, A.; Spring, J.; Taylor, C.; Thur, W.; Timossi, C.; Wandesforde, A.

    2005-02-01

    The Advanced Light Source (ALS) is a third generation synchrotron light source at Lawrence Berkeley National Laboratory (LBNL). There was an increasing demand for additional high brightness hard X-ray beamlines in the 7-40 keV range, so in August 2001, three 1.3 T normal conducting bending magnets were removed from the storage ring and replaced with 5 T superconducting magnets (Superbends). The radiation produced by these Superbends is an order of magnitude higher in photon brightness and flux at 12 keV, making them excellent sources of hard X-rays for protein crystallography and other hard X-ray applications. The Superbends did not compromise the performance of the facility in the VUV and soft X-ray regions of the spectrum. The Superbends will eventually feed 12 new beam lines, greatly enhancing the facility's capability and capacity in the hard X-ray region. The Superbend project is the biggest upgrade since the ALS storage ring was commissioned in 1993. In this paper we present an overview of the Superbend project, its challenges and the resulting impact on the ALS.

  6. Direct photocatalysis for organic synthesis by using plasmonic-metal nanoparticles irradiated with visible light.

    PubMed

    Xiao, Qi; Jaatinen, Esa; Zhu, Huaiyong

    2014-11-01

    Recent advances in direct-use plasmonic-metal nanoparticles (NPs) as photocatalysts to drive organic synthesis reactions under visible-light irradiation have attracted great interest. Plasmonic-metal NPs are characterized by their strong interaction with visible light through excitation of the localized surface plasmon resonance (LSPR). Herein, we review recent developments in direct photocatalysis using plasmonic-metal NPs and their applications. We focus on the role played by the LSPR of the metal NPs in catalyzing organic transformations and, more broadly, the role that light irradiation plays in catalyzing the reactions. Through this, the reaction mechanisms that these light-excited energetic electrons promote will be highlighted. This review will be of particular interest to researchers who are designing and fabricating new plasmonic-metal NP photocatalysts by identifying important reaction mechanisms that occur through light irradiation.

  7. Metallic surfaces decontamination by using laser light

    SciTech Connect

    Moggia, Fabrice; Lecardonnel, Xavier

    2013-07-01

    Metal surface cleaning appears to be one of the major priorities for industries especially for nuclear industries. The research and the development of a new technology that is able to meet the actual requirements (i.e. waste volume minimization, liquid effluents and chemicals free process...) seems to be the main commitment. Currently, a wide panel of technologies already exists (e.g. blasting, disk sander, electro-decontamination...) but for some of them, the efficiency is limited (e.g, Dry Ice blasting) and for others, the wastes production (liquid and/or solid) remains an important issue. One answer could be the use of a LASER light process. Since a couple of years, the Clean- Up Business Unit of the AREVA group investigates this decontamination technology. Many tests have been already performed in inactive (i.e. on simulants such as paints, inks, resins, metallic oxides) or active conditions (i.e. pieces covered with a thick metallic oxide layer and metallic pieces covered with grease). The paper will describe the results obtained in term of decontamination efficiency during all our validation process. Metallographic characterizations (i.e. SEM, X-ray scattering) and radiological analysis will be provided. We will also focus our paper on the future deployment of the LASER technology and its commercial use at La Hague reprocessing facility in 2013. (authors)

  8. Advanced interdisciplinary undergraduate program: light engineering

    NASA Astrophysics Data System (ADS)

    Bakholdin, Alexey; Bougrov, Vladislav; Voznesenskaya, Anna; Ezhova, Kseniia

    2016-09-01

    The undergraduate educational program "Light Engineering" of an advanced level of studies is focused on development of scientific learning outcomes and training of professionals, whose activities are in the interdisciplinary fields of Optical engineering and Technical physics. The program gives practical experience in transmission, reception, storage, processing and displaying information using opto-electronic devices, automation of optical systems design, computer image modeling, automated quality control and characterization of optical devices. The program is implemented in accordance with Educational standards of the ITMO University. The specific features of the Program is practice- and problem-based learning implemented by engaging students to perform research and projects, internships at the enterprises and in leading Russian and international research educational centers. The modular structure of the Program and a significant proportion of variable disciplines provide the concept of individual learning for each student. Learning outcomes of the program's graduates include theoretical knowledge and skills in natural science and core professional disciplines, deep knowledge of modern computer technologies, research expertise, design skills, optical and optoelectronic systems and devices.

  9. 19. DETAIL, METAL LIGHT STANDARD, AT NORTH END BLOCK OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. DETAIL, METAL LIGHT STANDARD, AT NORTH END BLOCK OF EAST PARAPET, FROM WEST, SHOWING SIMPLE ORNAMENTATION OF BASE OF STANDARD, WITH 'UNION METAL' IMPRINT - Fifth Street Viaduct, Spanning Bacon's Quarter Branch Valley on Fifth Street, Richmond, Independent City, VA

  10. Recycling light metals from end-of-life vehicle

    NASA Astrophysics Data System (ADS)

    Gesing, A.; Wolanski, R.

    2001-11-01

    The amount of aluminum used in cars and light trucks is growing steadily. However, without new developments in aluminum recycling technologies, sheet from automotive aluminum could eventually flood all current markets for recycled aluminum. This article summarizes the use of light metals and different alloys in transportation applications, the current auto recycling system, and new developments in the sorting of light metals by the metal recycling industry and by Huron Valley Steel Corporation, the world’s largest non-ferrous scrap sorter.

  11. Development of Damped Metal Matrix Composites for Advanced Structural Applications

    DTIC Science & Technology

    1990-04-01

    DTIP FiLE COPY Applied Research Laboratory (Dto 00 CD Technical Report NO DEVELOPMENT OF DAMPED METAL MATRIX COMPOSITES FOR ADVANCED STRUCTURAL...DEVELOPMENT OF DAMPED METAL MATRIX COMPOSITES FOR ADVANCED STRUCTURAL APPLICATIONS by Clark A. Updike Ram B. Bhagat Technical Report No. TR 90-004 April 1990... Metal Matrix Composites for Advanced Structural Applications 12 PERSONAL AUTHOR(S) C.A. Updike, R. Bhagat 1 3a TYPE OF REPORT 13b TIME COVERED 14. DATE

  12. Undulators at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Hoyer, E.; Akre, J.; Chin, J.; Gath, W.; Hassenzahl, W. V.; Humphries, D.; Kincaid, B.; Marks, S.; Pipersky, P.; Plate, D.; Portmann, G.; Schlueter, R.

    1995-02-01

    At Lawrence Berkeley Laboratory's Advanced Light Source, three 4.6 m long undulators have been completed, tested, and installed. A fourth is under construction. The completed undulators include two 5.0 cm period length, 89 period devices (U5.0s) which achieve a 0.85 T effective field at a 14 mm minimum gap and a 8.0 cm period length, 55 period device (U8.0) that reaches a 1.2 T effective field at a 14 mm minimum gap. The undulator under construction is a 10.0 cm period length, 43 period device (U10.0) that is designed to achieve 0.98 T at a 23 mm gap. Undulator magnetic gap variation (rms) is within 25 μm over the periodic structure length. Reproducibility of the adjustable magnetic gap has been measured to be within ±5 μm. Gap adjusting range is from 14 to 210 mm, which can be scanned in 1 min. The 5.1 m long vacuum chambers are flat in the vertical direction to within 0.74 mm and straight in the horizontal direction to within 0.08 mm over the 4.6 m magnetic structure sections. Vacuum chamber base pressures after UHV beam conditioning are in the mid-10-11 Torr range and storage ring operating pressures with full current are in the low 10-10 Torr range. Measurements show that the uncorrelated magnetic field errors are 0.23% and 0.20% for the two U5.0s and the U8.0, respectively, and that the field integrals are small over the 1 cm×6 cm beam aperture. Device description, fabrication, and measurements are presented.

  13. Advanced Solid State Lighting for Human Evaluation Project

    NASA Technical Reports Server (NTRS)

    Zeitlin, Nancy; Holbert, Eirik

    2015-01-01

    Lighting intensity and color have a significant impact on human circadian rhythms. Advanced solid state lighting was developed for the Advanced Exploration System (AES) Deep Space Habitat(DSH) concept demonstrator. The latest generation of assemblies using the latest commercially available LED lights were designed for use in the Bigelow Aerospace Environmental Control and Life Support System (ECLSS) simulator and the University of Hawaii's Hawaii Space Exploration Analog and Simulation (Hi-SEAS) habitat. Agreements with both these organizations will allow the government to receive feedback on the lights and lighting algorithms from long term human interaction.

  14. Status report on the Advanced Light Source control system

    SciTech Connect

    Magyary, S.; Chin, M.; Fahmie, M.; Lancaster, H.; Molinari, P.; Robb, A.; Timossi, C.; Young, J.

    1991-11-11

    This paper is a status report on the ADVANCED LIGHT SOURCE (ALS) control system. The current status, performance data, and future plans will be discussed. Manpower, scheduling, and costs issues are addressed.

  15. Advanced Solid State Lighting for AES Deep Space Hab Project

    NASA Technical Reports Server (NTRS)

    Holbert, Eirik

    2015-01-01

    The advanced Solid State Lighting (SSL) assemblies augmented 2nd generation modules under development for the Advanced Exploration Systems Deep Space Habitat in using color therapy to synchronize crew circadian rhythms. Current RGB LED technology does not produce sufficient brightness to adequately address general lighting in addition to color therapy. The intent is to address both through a mix of white and RGB LEDs designing for fully addressable alertness/relaxation levels as well as more dramatic circadian shifts.

  16. Advanced Lighting Program Development (BG9702800) Final Report

    SciTech Connect

    Rubinstein, Francis; Johnson, Steve

    1998-02-01

    The report presents a long-range plan for a broad-based, coordinated research, development and market transformation program for reducing the lighting energy intensities in commercial and residential buildings in California without compromising lighting quality. An effective program to advance lighting energy efficiency in California must be based on an understanding that lighting is a mature field and the lighting industry has developed many specialized products that meet a wide variety of light needs for different building types. Above all else, the lighting field is diverse and there are applications for a wide range of lighting products, systems, and strategies. Given the range of existing lighting solutions, an effective energy efficient lighting research portfolio must be broad-based and diverse to match the diversity of the lighting market itself. The belief that there is one solution--a magic bullet, such as a better lamp, for example--that will propel lighting efficiency across all uses to new heights is, in the authors' opinion, an illusion. A multi-path program is the only effective means to raising lighting efficiency across all lighting applications in all building types. This report presents a list of 27 lighting technologies and concepts (key activities) that could form the basis of a coordinated research and market transformation plan for significantly reducing lighting energy intensities in California buildings. The total 27 key activities into seven broad classes as follows: Light sources; Ballasts; Luminaires; Lighting Controls; Lighting Systems in Buildings; Human Factors and Education. Each of the above technology classes is discussed in terms of background, key activities, and the energy savings potential for the state. The report concludes that there are many possibilities for targeted research, development, and market transformation activities across all sectors of the building lighting industry. A concerted investment by the state to foster

  17. Advanced light source, User`s Handbook, Revision 1

    SciTech Connect

    1995-07-01

    The Advanced Light Source (ALS) is a national facility for scientific research and development located at the Lawrence Berkeley National Laboratory (LBNL) of the University of California. Its purpose is to generate beams of very bright light in the ultraviolet and soft x-ray regions of the spectrum. The facility is open to researchers from industry, universities, and government laboratories.

  18. Advances and prospects in visible light communications

    NASA Astrophysics Data System (ADS)

    Hongda, Chen; Chunhui, Wu; Honglei, Li; Xiongbin, Chen; Zongyu, Gao; Shigang, Cui; Qin, Wang

    2016-01-01

    Visible light communication (VLC) is an emerging technology in optical wireless communication (OWC) that has attracted worldwide research in recent years. VLC can combine communication and illumination together, which could be applied in many application scenarios such as visible light communication local area networks (VLANs), indoor localization, and intelligent lighting. In recent years, pioneering and significant work have been made in the field of VLC. In this paper, an overview of the recent progress in VLC is presented. We also demonstrate our recent experiment results including bidirectional 100 Mbit/s VLAN or Li-Fi system based on OOK modulation without blue filter. The VLC systems that we proposed are good solutions for high-speed VLC application systems with low-cost and low-complexity. VLC technology shows a bright future due to its inherent advantages, shortage of RF spectra and ever increasing popularity of white LEDs. Project supported by the National High Technology Research and Development Program of China (Nos. 2015AA033303, 2013AA013602, 2013AA013603, 2013AA03A104), the National Natural Science Foundation of China (Nos. 61178051, 61321063, 61335010, 61178048, 61275169), and the National Basic Research Program of China (Nos. 2013CB329205, 2011CBA00608).

  19. Permanent recording of light helicity on optically inactive metal surfaces.

    PubMed

    Wang, Jincheng; Guo, Chunlei

    2006-12-15

    We report on an unusual permanent recording of light helicity on optically achiral metals. Following a number of circularly polarized (CP) or elliptically polarized (EP) femtosecond laser pulses, well-defined periodic surface structures are found on metal surfaces. These surface structures show different orientation when formed by left CP/EP compared with right CP/EP light. The formation of these structures is attributed to the interference between the incident light and the excited surface plasmons. To our knowledge, this is the only phenomenon that can permanently record light helicity with an optically inactive material.

  20. 63. DETAIL VIEW OF LIGHT METAL TRUSSING SYSTEM ON PARTIALLY ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    63. DETAIL VIEW OF LIGHT METAL TRUSSING SYSTEM ON PARTIALLY DEMOLISHED GABLE END OF UNIDENTIFIED BUILDING. - Baltimore & Ohio Railroad, Mount Clare Shops, South side of Pratt Street between Carey & Poppleton Streets, Baltimore, Independent City, MD

  1. EDITORIAL: Special Issue on advanced and emerging light sources Special Issue on advanced and emerging light sources

    NASA Astrophysics Data System (ADS)

    Haverlag, Marco; Kroesen, Gerrit; Ferguson, Ian

    2011-06-01

    -based light sources. However, the progress in the last few years in LED and OLED sources has been even greater. In the editorial for the LS-11 conference by previous guest editor David Wharmby, it was stated that most LED lighting was still mostly used for signalling and decorative sources. In the three years that have passed, things have changed considerably and we now see LED light sources entering every application, ranging from street lighting and parking lots to shop lighting and even greenhouses. Currently LED prices for traditional lighting applications are high, but they are dropping rapidly. The papers published in this special issue give some indications of things to come. The paper by Jamil et al deals with the possibility of using silicon wafers as substrate material instead of the now commonly used (but more expensive) sapphire substrates. This is attractive from a cost price point of view, but leads to an increased lattice mismatch and therefore strain-induced defects. In this paper it is shown that when using intermediate matching layers it is possible to retain the same electrical and optical properties as with structures on sapphire. Another aspect that directly relates to cost is efficiency and droop in green InGaN devices, which is addressed in the paper by Lee et al. They show that by providing a flow of trymethylindium prior to the growth of the quantum wells it is possible to significantly increase the internal quantum efficiency of green LEDs. Improvement of the optical out-coupling of InGaN LEDs is discussed by Mak et al, and it is found that localized plasmon resonance of metallic nanoparticles (and especially silver) can help to increase the optical out-coupling in the wavelength region of interest. Nanoparticles in the form of ZnO nanorods are described by Willander et al as a possibility for phosphor-free wavelength conversion on polymer (O)LEDs. More advanced functions besides light emission can be achieved with OLEDs and this is demonstrated in

  2. Microwave Oven Experiments with Metals and Light Sources

    ERIC Educational Resources Information Center

    Vollmer, Michael; Mollmann, Klaus-Peter; Karstadt, Detlef

    2004-01-01

    "Don't put metal objects in the microwave" is common safety advice. But why? Here we describe demonstration experiments involving placing household metallic objects in a microwave oven. These allow a better understanding of the interaction of microwaves with materials. Light bulbs and discharge lamps can also be used in instructive demonstrations.

  3. Recent Advances in Conjugated Polymers for Light Emitting Devices

    PubMed Central

    AlSalhi, Mohamad Saleh; Alam, Javed; Dass, Lawrence Arockiasamy; Raja, Mohan

    2011-01-01

    A recent advance in the field of light emitting polymers has been the discovery of electroluminescent conjugated polymers, that is, kind of fluorescent polymers that emit light when excited by the flow of an electric current. These new generation fluorescent materials may now challenge the domination by inorganic semiconductor materials of the commercial market in light-emitting devices such as light-emitting diodes (LED) and polymer laser devices. This review provides information on unique properties of conjugated polymers and how they have been optimized to generate these properties. The review is organized in three sections focusing on the major advances in light emitting materials, recent literature survey and understanding the desirable properties as well as modern solid state lighting and displays. Recently, developed conjugated polymers are also functioning as roll-up displays for computers and mobile phones, flexible solar panels for power portable equipment as well as organic light emitting diodes in displays, in which television screens, luminous traffic, information signs, and light-emitting wallpaper in homes are also expected to broaden the use of conjugated polymers as light emitting polymers. The purpose of this review paper is to examine conjugated polymers in light emitting diodes (LEDs) in addition to organic solid state laser. Furthermore, since conjugated polymers have been approved as light-emitting organic materials similar to inorganic semiconductors, it is clear to motivate these organic light-emitting devices (OLEDs) and organic lasers for modern lighting in terms of energy saving ability. In addition, future aspects of conjugated polymers in LEDs were also highlighted in this review. PMID:21673938

  4. Advanced Metals (Industrial Arts) Curriculum Guide. Bulletin 1750.

    ERIC Educational Resources Information Center

    Louisiana State Dept. of Education, Baton Rouge. Div. of Vocational Education.

    This curriculum guide contains materials for a 13-unit course in advanced metals, the second metals course in the industrial arts curriculum for grades 10-12. It is intended for use by industrial arts teachers, supervisors, counselors, administrators, and teacher educators. A two-page course overview provides a brief course description; indicates…

  5. Environmental Science Program at the Advanced Light Source

    SciTech Connect

    Nico, Peter; A; Anastasio, Cort; Dodge, Cleveland; Fendorf, Scott; Francis, A.J.; Hubbard, Susan; Shuh, David; Tomutsa, Liviu; Tufano, Kate; Tyliszczak, Tolek; Werner, Michelle; Williams, Ken

    2006-04-05

    The Advanced Light Source (ALS) has a variety of capabilities that are applicable to very different types of environmental systems. Shown are the basic descriptions of four of the approximately 35 beam lines at the ALS. The complimentary capabilities of these four beam lines allow for investigations that range from a spatial scale of a few nanometers to several millimeters. The Environmental Science Program at the Advanced Light Source seeks to promote and assist environmental research, particularly on the four beam lines described in this report. Several short examples of the types of research conducted on these beam lines are also described.

  6. Survey, alignment, and beam stability at the Advanced Light Source

    SciTech Connect

    Krebs, G.F.

    1997-10-01

    This paper describes survey and alignment at the Lawrence Berkeley Laboratories Advanced Light Source (ALS) accelerators from 1993 to 1997. The ALS is a third generation light source requiring magnet alignment to within 150 microns. To accomplish this, a network of monuments was established and maintained. Monthly elevation surveys show the movement of the floor over time. Inclinometers have recently been employed to give real time information about magnet, vacuum tank and magnet girder motion in the ALS storage ring.

  7. How advances in light technology have shaped ENT.

    PubMed

    Mozaffari, M; Fishman, J M; Tolley, N S

    2016-02-01

    The development of light technologies, allowing anatomical visualisation of otherwise hidden structures, led to significant advances in ENT in the nineteenth and twentieth centuries. Natural light from the sun, and from candles, was initially harnessed using mirrors. Later, the invention of limelight and electricity preceded the emergence of the modern-day endoscope, which, in tandem with the discovery of coherent fibre-optics in the 1950s, significantly expanded the surgical repertoire available to otolaryngologists. This study aimed to trace the rich history of ENT through the specialty's use of light.

  8. Measurement of storage ring motion at the advanced light source

    SciTech Connect

    Krebs, G.F.

    1997-05-01

    The mechanical stability of the Advanced Light Source storage ring is examined over a period of 1.5 years from the point of view of floor motion. The storage ring beam position monitor stability is examined under various operating conditions.

  9. Advanced Light Source Activity Report 1997/1998

    SciTech Connect

    Greiner, Annette

    1999-03-01

    This Lawrence Berkeley National Laboratory, Advanced Light Source (ALS) activity report for 1997/98 discusses the following topics: Introduction and Overview; Science Highlights; Facility Report; Special Events; ALS Advisory Panels 1997/98; ALS Staff 1997/98 and Facts and Figures for the year.

  10. Thermal Applications for Advanced Metallic Materials (Preprint)

    DTIC Science & Technology

    2007-01-01

    layered metal oxides (NaCo2O4 etc.) [25], Skutterudites (CeFeCoSb, etc.) [26] and the Half - Heusler alloys e.g. MNiSn, where M = Ti, Zr, Hf [27...Thermoelectrics. 1997, IEEE: Piscataway, NJ. p. 1-11. 27. Culp, S.R., et al., Effect of substitutions on the thermoelectric figure of merit of half - Heusler

  11. [Research advances in heavy metals pollution ecology of diatom].

    PubMed

    Ding, Teng-Da; Ni, Wan-Min; Zhang, Jian-Ying

    2012-03-01

    Diatom, due to its high sensitivity to environmental change, is one of the bio-indicators of aquatic ecosystem health, and some typical diatom species have been applied to indicate the heavy metals pollution of water body. With the focus on the surface water heavy metals pollution, this paper reviewed the research advances in the toxic effect of heavy metals pollution on diatom, biosorption and bioaccumulation of heavy metals by diatom, ecological adaptation mechanisms of diatom to heavy metals pollution, and roles of diatom as bio-indicator and in ecological restoration of heavy metals pollution. The growth tendency of diatom and the morphological change of frustule under heavy metals pollution as well as the differences in heavy metals biosorption and bioaccumulation by diatom, the ecological adaptation mechanisms of diatom on heavy metals surface complexation and ion exchange, and the roles of diatom as bio-indicator and in ecological restoration of heavy metals polluted water body were also discussed. This review could provide scientific evidences for the prevention of aquatic ecosystems heavy metals pollution and related early warning techniques.

  12. Advanced Organic Ligands for Protecting Metal Nanoparticles

    NASA Astrophysics Data System (ADS)

    Yu, Jonathan Ka-Wing

    Organic monolayer protected metal nanoparticles have been utilized in many different fields such as catalysis, drug delivery, and sensor chemistry. However, these nanomaterials are prone to increase in size consequently losing its function at the nanoscale. The stability these nanoparticles have been a great interest of research. This thesis focuses on the synthesis of a novel cross-linkable ligand for the protection of metal nanoparticles. Chapter 1 reviews key concepts of nanoparticles, its usefulness in applications, some of the stabilizing strategies employed, and the scope of the thesis project. Chapter 2 describes the synthetic attempts and optimization of the novel cross-linkable ligand. In addition, its characterization data is also included. Section 2.8 also highlights another fully synthesized novel hydrophobic ligand. Chapter 3 contains the summary of the work and closing remarks. Future works is also included to describe the prospects of the synthesis of the novel ligand. Chapter 4 entails the experimental data and supplementary information.

  13. Advances in Nanocarbon Metals: Fine Structure

    DTIC Science & Technology

    2015-03-01

    SUPPLEMENTARY NOTES 14. ABSTRACT This study is an investigation of the structure and some properties of silver, copper, and aluminum alloy covetics...Covetics can incorporate large amounts of carbon (C) in a nanoscale form to alter physical and mechanical properties of the base metal or alloy ...and properties can be obtained. 15. SUBJECT TERMS covetic, nanocarbon silver, aluminum , copper 16. SECURITY CLASSIFICATION OF: 17. LIMITATION

  14. Advanced atom chips with two metal layers.

    SciTech Connect

    Stevens, James E.; Blain, Matthew Glenn; Benito, Francisco M.; Biedermann, Grant

    2010-12-01

    A design concept, device layout, and monolithic microfabrication processing sequence have been developed for a dual-metal layer atom chip for next-generation positional control of ultracold ensembles of trapped atoms. Atom chips are intriguing systems for precision metrology and quantum information that use ultracold atoms on microfabricated chips. Using magnetic fields generated by current carrying wires, atoms are confined via the Zeeman effect and controllably positioned near optical resonators. Current state-of-the-art atom chips are single-layer or hybrid-integrated multilayer devices with limited flexibility and repeatability. An attractive feature of multi-level metallization is the ability to construct more complicated conductor patterns and thereby realize the complex magnetic potentials necessary for the more precise spatial and temporal control of atoms that is required. Here, we have designed a true, monolithically integrated, planarized, multi-metal-layer atom chip for demonstrating crossed-wire conductor patterns that trap and controllably transport atoms across the chip surface to targets of interest.

  15. Advanced Metallic Thermal Protection System Development

    NASA Technical Reports Server (NTRS)

    Blosser, M. L.; Chen, R. R.; Schmidt, I. H.; Dorsey, J. T.; Poteet, C. C.; Bird, R. K.

    2002-01-01

    A new Adaptable, Robust, Metallic, Operable, Reusable (ARMOR) thermal protection system (TPS) concept has been designed, analyzed, and fabricated. In addition to the inherent tailorable robustness of metallic TPS, ARMOR TPS offers improved features based on lessons learned from previous metallic TPS development efforts. A specific location on a single-stage-to-orbit reusable launch vehicle was selected to develop loads and requirements needed to design prototype ARMOR TPS panels. The design loads include ascent and entry heating rate histories, pressures, acoustics, and accelerations. Additional TPS design issues were identified and discussed. An iterative sizing procedure was used to size the ARMOR TPS panels for thermal and structural loads as part of an integrated TPS/cryogenic tank structural wall. The TPS panels were sized to maintain acceptable temperatures on the underlying structure and to operate under the design structural loading. Detailed creep analyses were also performed on critical components of the ARMOR TPS panels. A lightweight, thermally compliant TPS support system (TPSS) was designed to connect the TPS to the cryogenic tank structure. Four 18-inch-square ARMOR TPS panels were fabricated. Details of the fabrication process are presented. Details of the TPSS for connecting the ARMOR TPS panels to the externally stiffened cryogenic tank structure are also described. Test plans for the fabricated hardware are presented.

  16. Metal hydride hydrogen compression: Recent advances and future prospects

    DOE PAGES

    Bowman, Jr., Robert C.; Yartys, Volodymyr A.; Lototskyy, Mykhaylo V.; ...

    2016-03-17

    Metal hydride (MH) thermal sorption compression is one of the more important applications of the metal hydrides. The present paper reviews recent advances in the field based on the analysis of the fundamental principles of this technology. The performances when boosting hydrogen pressure, along with two- and three-step compression units are analyzed. The paper includes also a theoretical modeling of a two-stage compressor aimed at both describing the performance of the experimentally studied systems, but, also, on their optimization and design of more advanced MH compressors. Business developments in the field are reviewed for the Norwegian company HYSTORSYS AS andmore » the South African Institute for Advanced Materials Chemistry. Finally, future prospects are outlined presenting the role of the metal hydride compression in the overall development of the hydrogen driven energy systems. Lastly, the work is based on the analysis of the development of the technology in Europe, USA and South Africa.« less

  17. Metal hydride hydrogen compression: Recent advances and future prospects

    SciTech Connect

    Bowman, Jr., Robert C.; Yartys, Volodymyr A.; Lototskyy, Mykhaylo V.; Linkov, Vladimir; Grant, David; Stuart, Alastair; Eriksen, Jon; Denys, Roman

    2016-03-17

    Metal hydride (MH) thermal sorption compression is one of the more important applications of the metal hydrides. The present paper reviews recent advances in the field based on the analysis of the fundamental principles of this technology. The performances when boosting hydrogen pressure, along with two- and three-step compression units are analyzed. The paper includes also a theoretical modeling of a two-stage compressor aimed at both describing the performance of the experimentally studied systems, but, also, on their optimization and design of more advanced MH compressors. Business developments in the field are reviewed for the Norwegian company HYSTORSYS AS and the South African Institute for Advanced Materials Chemistry. Finally, future prospects are outlined presenting the role of the metal hydride compression in the overall development of the hydrogen driven energy systems. Lastly, the work is based on the analysis of the development of the technology in Europe, USA and South Africa.

  18. Advanced Micro/Nanostructures for Lithium Metal Anodes

    PubMed Central

    Zhang, Rui; Li, Nian‐Wu; Cheng, Xin‐Bing; Yin, Ya‐Xia

    2017-01-01

    Owning to their very high theoretical capacity, lithium metal anodes are expected to fuel the extensive practical applications in portable electronics and electric vehicles. However, unstable solid electrolyte interphase and lithium dendrite growth during lithium plating/stripping induce poor safety, low Coulombic efficiency, and short span life of lithium metal batteries. Lately, varies of micro/nanostructured lithium metal anodes are proposed to address these issues in lithium metal batteries. With the unique surface, pore, and connecting structures of different nanomaterials, lithium plating/stripping processes have been regulated. Thus the electrochemical properties and lithium morphologies have been significantly improved. These micro/nanostructured lithium metal anodes shed new light on the future applications for lithium metal batteries. PMID:28331792

  19. Advanced Micro/Nanostructures for Lithium Metal Anodes.

    PubMed

    Zhang, Rui; Li, Nian-Wu; Cheng, Xin-Bing; Yin, Ya-Xia; Zhang, Qiang; Guo, Yu-Guo

    2017-03-01

    Owning to their very high theoretical capacity, lithium metal anodes are expected to fuel the extensive practical applications in portable electronics and electric vehicles. However, unstable solid electrolyte interphase and lithium dendrite growth during lithium plating/stripping induce poor safety, low Coulombic efficiency, and short span life of lithium metal batteries. Lately, varies of micro/nanostructured lithium metal anodes are proposed to address these issues in lithium metal batteries. With the unique surface, pore, and connecting structures of different nanomaterials, lithium plating/stripping processes have been regulated. Thus the electrochemical properties and lithium morphologies have been significantly improved. These micro/nanostructured lithium metal anodes shed new light on the future applications for lithium metal batteries.

  20. Metallic fuels: The EBR-II legacy and recent advances

    SciTech Connect

    Douglas L. Porter; Steven L. Hayes; J. Rory Kennedy

    2012-09-01

    Experimental Breeder Reactor – II (EBR-II) metallic fuel was qualified for high burnup to approximately 10 atomic per cent. Subsequently, the electrometallurgical treatment of this fuel was demonstrated. Advanced metallic fuels are now investigated for increased performance, including ultra-high burnup and actinide burning. Advances include additives to mitigate the fuel/cladding chemical interaction and uranium alloys that combine Mo, Ti and Zr to improve alloy performance. The impacts of the advances—on fabrication, waste streams, electrorefining, etc.—are found to be minimal and beneficial. Owing to extensive research literature and computational methods, only a modest effort is required to complete their development.

  1. Squeezed light for advanced gravitational wave detectors and beyond.

    PubMed

    Oelker, E; Barsotti, L; Dwyer, S; Sigg, D; Mavalvala, N

    2014-08-25

    Recent experiments have demonstrated that squeezed vacuum states can be injected into gravitational wave detectors to improve their sensitivity at detection frequencies where they are quantum noise limited. Squeezed states could be employed in the next generation of more sensitive advanced detectors currently under construction, such as Advanced LIGO, to further push the limits of the observable gravitational wave Universe. To maximize the benefit from squeezing, environmentally induced disturbances such as back scattering and angular jitter need to be mitigated. We discuss the limitations of current squeezed vacuum sources in relation to the requirements imposed by future gravitational wave detectors, and show a design for squeezed light injection which overcomes these limitations.

  2. Novel interfaces for light directed neuronal stimulation: advances and challenges

    PubMed Central

    Bareket-Keren, Lilach; Hanein, Yael

    2014-01-01

    Light activation of neurons is a growing field with applications ranging from basic investigation of neuronal systems to the development of new therapeutic methods such as artificial retina. Many recent studies currently explore novel methods for optical stimulation with temporal and spatial precision. Novel materials in particular provide an opportunity to enhance contemporary approaches. Here we review recent advances towards light directed interfaces for neuronal stimulation, focusing on state-of-the-art nanoengineered devices. In particular, we highlight challenges and prospects towards improved retinal prostheses. PMID:24872704

  3. Novel interfaces for light directed neuronal stimulation: advances and challenges.

    PubMed

    Bareket-Keren, Lilach; Hanein, Yael

    2014-01-01

    Light activation of neurons is a growing field with applications ranging from basic investigation of neuronal systems to the development of new therapeutic methods such as artificial retina. Many recent studies currently explore novel methods for optical stimulation with temporal and spatial precision. Novel materials in particular provide an opportunity to enhance contemporary approaches. Here we review recent advances towards light directed interfaces for neuronal stimulation, focusing on state-of-the-art nanoengineered devices. In particular, we highlight challenges and prospects towards improved retinal prostheses.

  4. Advanced metal-membrane technology-commercialization

    SciTech Connect

    Edlund, D.J.

    1995-06-01

    The gasification of coal offers a potentially significant source of hydrogen for use in clean power generation and as a primary chemical feedstock. However, hydrogen derived from coal continues to be more expensive than hydrogen derived from natural gas or petroleum, due in large part to the expense of separating hydrogen from the mixture of gases produced during gasification. At Bend Research, we have been developing a novel hydrogen-permeable metal membrane that promises to be economical for hydrogen separation and purification, including the purification of hydrogen derived from gasifying coal. Furthermore, the membrane is ideally suited for use at high temperatures (200{degrees} to 500{degrees}C), making it feasible to produce pure hydrogen directly from hot gas streams. Through a partnership with Teledyne Wah Chang, we are proceeding with scale-up of prototype membrane modules and field tests to demonstrate the technology to potential users. Additionally, we are working with potential customers to estimate capital savings and operating costs for integrated systems. In this paper, we present some of the operating characteristics of the metal membrane, including its use to drive equilibrium-limited reactions toward complete conversion (e.g., the water-gas-shift reaction). We also describe our activities for commercializing this technology for a variety of applications.

  5. Asymmetric light reflectance from metal nanoparticle arrays on dielectric surfaces

    NASA Astrophysics Data System (ADS)

    Huang, K.; Pan, W.; Zhu, J. F.; Li, J. C.; Gao, N.; Liu, C.; Ji, L.; Yu, E. T.; Kang, J. Y.

    2015-12-01

    Asymmetric light reflectance associated with localized surface plasmons excited in metal nanoparticles on a quartz substrate is observed and analyzed. This phenomenon is explained by the superposition of two waves, the wave reflected by the air/quartz interface and that reflected by the metal nanoparticles, and the resulting interference effects. Far field behavior investigation suggests that zero reflection can be achieved by optimizing the density of metal nanoparticles. Near field behavior investigation suggests that the coupling efficiency of localized surface plasmon can be additionally enhanced by separating the metal NPs from substrates using a thin film with refractive index smaller than the substrate. The latter behavior is confirmed via surface-enhanced Raman spectroscopy studies using metal nanoparticles on Si/SiO2 substrates.

  6. Asymmetric light reflectance from metal nanoparticle arrays on dielectric surfaces.

    PubMed

    Huang, K; Pan, W; Zhu, J F; Li, J C; Gao, N; Liu, C; Ji, L; Yu, E T; Kang, J Y

    2015-12-18

    Asymmetric light reflectance associated with localized surface plasmons excited in metal nanoparticles on a quartz substrate is observed and analyzed. This phenomenon is explained by the superposition of two waves, the wave reflected by the air/quartz interface and that reflected by the metal nanoparticles, and the resulting interference effects. Far field behavior investigation suggests that zero reflection can be achieved by optimizing the density of metal nanoparticles. Near field behavior investigation suggests that the coupling efficiency of localized surface plasmon can be additionally enhanced by separating the metal NPs from substrates using a thin film with refractive index smaller than the substrate. The latter behavior is confirmed via surface-enhanced Raman spectroscopy studies using metal nanoparticles on Si/SiO2 substrates.

  7. Nanofabrication of Metallic Nanostructures and Integration with Light Detection Devices

    NASA Astrophysics Data System (ADS)

    Huang, Liang

    Metallic nanostructures have been investigated with various applications especially for integration with light detection devices. The incident light can be manipulated by those nanostructures to enhance light absorption therefor improve device performance. However, previous studies focused on optical design. The electrical properties of these integrated light detection devices have not been fully considered. The photon generated carriers transport and collection are critical for light detection devices as well. An optimized device platform considering from both the optical and electrical aspects to fully utilize these nanostructures is highly desired for future light detection devices. This dissertation targeted on three objectives, beginning with the fabrication process development of various nanostructures on different substrates. High quality nanostructures were achieved with minimum 20nm gap and 45nm line width. The second objective was developing the metallic fishnet nanostructures integrated Schottky contact a-Si solar cell to improve both light absorption and photon generated carrier collection. The fishnet was designed as the light trapping structure and 2D connected top contact to collect carriers. The third objective was developing metallic nanostructures integrated GeSn photodetectors. The H shape nano antennas were integrated on GeSn photodetectors. Multiple resonant absorption peaks at infrared range were observed using spectroscopic ellipsometry. However, there was no obvious photoresponse value improvement of developed solar cells and H shape antennas integrated GeSn photodetectors. For further investigation, interdigitated electrodes integrated GeSn photodetectors were designed. With less carrier transit time, the responsivity value of the integrated Ge0.991Sn0.009 photodetector was 72muA/W at 1.55mum at room temperature which was 6 times higher comparing to device without integration. Meanwhile, with the increased carrier life time by decreasing

  8. Aeroheating model advancements featuring electroless metallic plating

    NASA Technical Reports Server (NTRS)

    Stalmach, C. J., Jr.; Goodrich, W. D.

    1976-01-01

    Discussed are advancements in wind tunnel model construction methods and hypersonic test data demonstrating the methods. The general objective was to develop model fabrication methods for improved heat transfer measuring capability at less model cost. A plated slab model approach was evaluated with cast models containing constantan wires that formed single-wire-to-plate surface thermocouple junctions with a seamless skin of electroless nickel alloy. The surface of a space shuttle orbiter model was selectively plated with scaled tiles to simulate, with high fidelity, the probable misalignments of the heatshield tiles on a flight vehicle. Initial, Mach 8 heating results indicated a minor effect of tile misalignment roughness on boundary layer transition, implying a possible relaxation of heatshield manufacturing tolerances. Some loss of the plated tiles was experienced when the model was tested at high heating rates.

  9. The advanced light source: America`s brightest light for science and industry

    SciTech Connect

    Cross, J.; Lawler, G.

    1994-03-01

    America`s brightest light comes from the Advanced Light Source (ALS), a national facility for scientific research, product development, and manufacturing. Completed in 1993, the ALS produces light in the ultraviolet and x-ray regions of the spectrum. Its extreme brightness provides opportunities for scientific and technical progress not possible anywhere else. Technology is poised on the brink of a major revolution - one in which vital machine components and industrial processes will be drastically miniaturized. Industrialized nations are vying for leadership in this revolution - and the huge economic rewards the leaders will reap.

  10. Advanced optical interference filters based on metal and dielectric layers.

    PubMed

    Begou, Thomas; Lemarchand, Fabien; Lumeau, Julien

    2016-09-05

    In this paper, we investigate the design and the fabrication of an advanced optical interference filter based on metal and dielectric layers. This filter respects the specifications of the 2016 OIC manufacturing problem contest. We study and present all the challenges and solutions that allowed achieving a low deviation between the fabricated prototype and the target.

  11. Advanced Materials Research with 3RD Generation Synchrotron Light

    NASA Astrophysics Data System (ADS)

    Soukiassian, P.; D'angelo, M.; Enriquez, H.; Aristov, V. Yu.

    H and D surface nanochemistry on an advanced wide band gap semiconductor, silicon carbide is investigated by synchrotron radiation-based core level and valence band photoemission, infrared absorption and scanning tunneling spectroscopy, showing the 1st example of H/D-induced semiconductor surface metallization, that also occurs on a pre-oxidized surface. These results are compared to recent state-of-the-art ab-initio total energy calculations. Most interestingly, an amazing isotopic behavior is observed with a smaller charge transfer from D atoms suggesting the role of dynamical effects. Such findings are especially exciting in semiconductor physics and in interface with biology.

  12. Advanced metallic thermal protection systems for reusable launch vehicles

    NASA Astrophysics Data System (ADS)

    Blosser, Max Leon

    2000-10-01

    Metallic thermal protection systems are a key technology that may help achieve the goal of reducing the cost of space access. A study was performed to develop an understanding of the key factors that govern the performance of metallic thermal protection systems for reusable launch vehicles. Multi-disciplinary background information was assembled and reviewed critically to provide a basis for development of improved metallic thermal protection systems. The fundamentals of aerodynamic heating were reviewed and applied to the development of thermal protection systems. General approaches to thermal protection were categorized and critiqued. The high temperature materials used for thermal protection systems (TPS), including insulations, structural materials, and coatings were reviewed. The history of metallic TPS from early pre-Shuttle concepts to current concepts for a reusable launch vehicle was reviewed for the first time. A current advanced metallic TPS concept was presented and systematically analyzed to discover the most important factors governing the thermal performance of metallic TPS. A large number of relevant factors that influence the thermal analysis and thermal performance of metallic TPS were identified and quantified. Detailed finite element computational models were developed for predicting the thermal performance of variations of the advanced metallic TPS concept mounted on a simple, unstiffened structure. The computational models were also used, in an automated iterative procedure, for sizing the metallic TPS to maintain the structure below a specified temperature limit. A statistical sensitivity analysis method, based on orthogonal matrix techniques used in robust design, was used to quantify and rank the relative importance of the various modeling and design factors considered in this study. Results from this study identify factors that have the most potential to improve metallic TPS performance. The thermal properties of the underlying vehicle

  13. Insertion devices for the Advanced Light Source at LBL

    SciTech Connect

    Hassenzahl, W.; Chin, J.; Halbach, K.; Hoyer, E.; Humphries, D.; Kincaid, B.; Savoy, R.

    1989-03-01

    The Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory will be the first of the new generation of dedicated synchrotron light sources to be put into operation. Specially designed insertion devices will be required to realize the high brightness photon beams made possible by the low emittance of the electron beam. The complement of insertion devices on the ALS will include undulators with periods as short as 3.9 cm and one or more high field wigglers. The first device to be designed is a 5 m long, 5 cm period, hybrid undulator. The goal of very high brightness and high harmonic output imposes unusually tight tolerances on the magnetic field quality and thus on the mechanical structure. The design process, using a generic structure for all undulators, is described. 5 refs., 4 figs., 1 tab.

  14. The advanced light source at the Lawrence Berkeley laboratory

    NASA Astrophysics Data System (ADS)

    Jackson, Alan

    1991-05-01

    The Advanced Light Source (ALS), a national facility currently under construction at the Lawrence Berkeley Laboratory (LBL), is a third-generation synchrotron light source designed to produce extremely bright beams of synchrotron radiation, in the energy range from a few eV to 10 keV. The design is based on a 1-1.9 GeV electron storage ring (optimized at 1.5 GeV), and utilizes special magnets, known as undulators and wigglers (collectively referred to as insertion devices), to generate the radiation. In this paper we describe the main accelerator components of the ALS, the variety of insertion devices, the radiation spectra expected from these devices, and the complement of experiments that have been approved for initial operation, starting in April 1993.

  15. Status report on the Advanced Light Source control system, 1993

    SciTech Connect

    Young, J.; Brown, W. Jr.; Cork, C.

    1993-10-01

    The Advanced Light Source (ALS), under construction for the past seven years, has become operational. The accelerator has been successfully commissioned using a control system based on hundreds of controllers of our own design and high performance personal computers which are the operator interface. The first beamlines are being commissioned using a control system based on VME hardware and the Experimental Physics and Industrial Control System (EPICS) software. The two systems are being integrated, and this paper reports on the current work being done.

  16. Slow light in metal-insulator-metal waveguide by negative Goos-Hänchen shift

    NASA Astrophysics Data System (ADS)

    Oh, Geum-Yoon; Chheang, Vuthy; Kim, Doo-Gun; Kim, Tae-Ryong; Jun, Li; Kim, Hong-Seung; Choi, Young-Wan

    2014-12-01

    We demonstrated group velocity delay using a metal-insulator-metal structure for slow light that would be very simple to fabricate. A negative Goos-Hänchen shift of the surface plasmon resonance can be caused by incident radiation while reflecting, resulting in a general group delay. Using this phenomenon, we induced a group delay of 70 fs using a very simple 20-μm-long waveguide.

  17. Advanced Nuclear Technology: Advanced Light Water Reactors Utility Requirements Document Small Modular Reactors Inclusion Summary

    SciTech Connect

    Loflin, Leonard; McRimmon, Beth

    2014-12-18

    This report summarizes a project by EPRI to include requirements for small modular light water reactors (smLWR) into the EPRI Utility Requirements Document (URD) for Advanced Light Water Reactors. The project was jointly funded by EPRI and the U.S. Department of Energy (DOE). The report covers the scope and content of the URD, the process used to revise the URD to include smLWR requirements, a summary of the major changes to the URD to include smLWR, and how to use the URD as revised to achieve value on new plant projects.

  18. Recent Advances in Transition Metal-Catalyzed Glycosylation.

    PubMed

    McKay, Matthew J; Nguyen, Hien M

    2012-08-03

    Having access to mild and operationally simple techniques for attaining carbohydrate targets will be necessary to facilitate advancement in biological, medicinal, and pharmacological research. Even with the abundance of elegant reports for generating glycosidic linkages, stereoselective construction of α- and β-oligosaccharides and glycoconjugates is by no means trivial. In an era where expanded awareness of the impact we are having on the environment drives the state-of-the-art, synthetic chemists are tasked with developing cleaner and more efficient reactions for achieving their transformations. This movement imparts the value that prevention of waste is always superior to its treatment or cleanup. This review will highlight recent advancement in this regard by examining strategies that employ transition metal catalysis in the synthesis of oligosaccharides and glycoconjugates. These methods are mild and effective for constructing glycosidic bonds with reduced levels of waste through utilization of sub-stoichiometric amounts of transition metals to promote the glycosylation.

  19. Recent Advances in Transition Metal-Catalyzed Glycosylation

    PubMed Central

    McKay, Matthew J.; Nguyen, Hien M.

    2012-01-01

    Having access to mild and operationally simple techniques for attaining carbohydrate targets will be necessary to facilitate advancement in biological, medicinal, and pharmacological research. Even with the abundance of elegant reports for generating glycosidic linkages, stereoselective construction of α- and β-oligosaccharides and glycoconjugates is by no means trivial. In an era where expanded awareness of the impact we are having on the environment drives the state-of-the-art, synthetic chemists are tasked with developing cleaner and more efficient reactions for achieving their transformations. This movement imparts the value that prevention of waste is always superior to its treatment or cleanup. This review will highlight recent advancement in this regard by examining strategies that employ transition metal catalysis in the synthesis of oligosaccharides and glycoconjugates. These methods are mild and effective for constructing glycosidic bonds with reduced levels of waste through utilization of sub-stoichiometric amounts of transition metals to promote the glycosylation. PMID:22924154

  20. LIGHT SOURCE: Conceptual design of Hefei Advanced Light Source (HALS) injection system

    NASA Astrophysics Data System (ADS)

    Zhang, Shan-Cai; Wang, Lin; Feng, Guang-Yao; Wu, Cong-Feng; Li, Wei-Min; Xu, Hong-Liang; Liu, Zu-Ping

    2009-06-01

    The Hefei Advanced Light Source(HALS) is a super low emittance storage ring and has a very short beam life time. In order to run the ring stablely, top-up injection will be necessary. The injection system will greatly affect the quality of beam. This article first gives a physics design of the injecting system. Then the injecting system is tracked under different errors. The responses of storage beam and injecting beam are given in the article.

  1. Synchrotron X-Ray Microdiffraction Studies of Electromigration in Interconnect lines at the Advanced Light Source

    SciTech Connect

    Tamura, Nobumichi; Chen, Kai; Kunz, Martin

    2009-12-01

    Synchrotron polychromatic X-ray microdiffraction is a particularly suitable technique to study in situ the effect of electromigration in metal interconnects as add spatial resolution to grain orientation and strain sensitivity. This technique has been extensively used at the Advanced Light Source to monitor changes in aluminum and copper interconnect test structures while high-density current is passed into them during accelerated tests at elevated temperature. One of the principal findings is the observation of electromigration-induced plasticity in the metal lines that appear during the very early stages of electromigration. In some of the lines, high density of geometrically necessary dislocation are formed leading to additional diffusion paths causing an enhancement of electromigration effect at test temperature.

  2. The Consortium for Advanced Simulation of Light Water Reactors

    SciTech Connect

    Ronaldo Szilard; Hongbin Zhang; Doug Kothe; Paul Turinsky

    2011-10-01

    The Consortium for Advanced Simulation of Light Water Reactors (CASL) is a DOE Energy Innovation Hub for modeling and simulation of nuclear reactors. It brings together an exceptionally capable team from national labs, industry and academia that will apply existing modeling and simulation capabilities and develop advanced capabilities to create a usable environment for predictive simulation of light water reactors (LWRs). This environment, designated as the Virtual Environment for Reactor Applications (VERA), will incorporate science-based models, state-of-the-art numerical methods, modern computational science and engineering practices, and uncertainty quantification (UQ) and validation against data from operating pressurized water reactors (PWRs). It will couple state-of-the-art fuel performance, neutronics, thermal-hydraulics (T-H), and structural models with existing tools for systems and safety analysis and will be designed for implementation on both today's leadership-class computers and the advanced architecture platforms now under development by the DOE. CASL focuses on a set of challenge problems such as CRUD induced power shift and localized corrosion, grid-to-rod fretting fuel failures, pellet clad interaction, fuel assembly distortion, etc. that encompass the key phenomena limiting the performance of PWRs. It is expected that much of the capability developed will be applicable to other types of reactors. CASL's mission is to develop and apply modeling and simulation capabilities to address three critical areas of performance for nuclear power plants: (1) reduce capital and operating costs per unit energy by enabling power uprates and plant lifetime extension, (2) reduce nuclear waste volume generated by enabling higher fuel burnup, and (3) enhance nuclear safety by enabling high-fidelity predictive capability for component performance.

  3. Highly Automated Module Production Incorporating Advanced Light Management

    SciTech Connect

    Perelli-Minetti, Michael; Roof, Kyle

    2015-08-11

    The objective was to enable a high volume, cost effective solution for increasing the amount of light captured by PV modules through utilization of an advanced Light Re-directing Film and to follow a phased approach to develop and implement this new technology in order to achieve an expected power gain of up to 12 watts per module. Full size PV modules were manufactured using a new Light Redirecting Film (LRF) material applied to two different areas of PV modules in order to increase the amount of light captured by the modules. One configuration involved applying thin strips of LRF film over the tabbing ribbon on the cells in order to redirect the light that is normally absorbed by the tabbing ribbon to the active areas of the cells. A second configuration involved applying thin strips of LRF film over the white spaces between cells within a module in order to capture some of the light that is normally reflected from the white areas back through the front glass of the modules. Significant power increases of 1.4% (3.9 watts) and 1.0% (3.2 watts), respectively, compared to standard PV modules were measured under standard test conditions. The performance of PV modules with LRF applied to the tabbing ribbon was modeled. The results showed that the power increase provided by LRF depended greatly on the angle of incident light with the optimum performance only occurring when the light was within a narrow range of being perpendicular to the solar module. The modeling showed that most of the performance gain would be lost when the angle of incident light was greater than 28 degrees off axis. This effect made the orientation of modules with LRF applied to tabbing ribbons very important as modules mounted in “portrait” mode were predicted to provide little to no power gain from LRF under real world conditions. Based on these results, modules with LRF on tabbing ribbons would have to be mounted in “landscape” mode to realize a performance advantage. In addition

  4. Metal fire implications for advanced reactors. Part 1, literature review.

    SciTech Connect

    Nowlen, Steven Patrick; Radel, Ross F.; Hewson, John C.; Olivier, Tara Jean; Blanchat, Thomas K.

    2007-10-01

    Public safety and acceptance is extremely important for the nuclear power renaissance to get started. The Advanced Burner Reactor and other potential designs utilize liquid sodium as a primary coolant which provides distinct challenges to the nuclear power industry. Fire is a dominant contributor to total nuclear plant risk events for current generation nuclear power plants. Utilizing past experience to develop suitable safety systems and procedures will minimize the chance of sodium leaks and the associated consequences in the next generation. An advanced understanding of metal fire behavior in regards to the new designs will benefit both science and industry. This report presents an extensive literature review that captures past experiences, new advanced reactor designs, and the current state-of-knowledge related to liquid sodium combustion behavior.

  5. Development of Metal Matrix Composites for NASA'S Advanced Propulsion Systems

    NASA Technical Reports Server (NTRS)

    Lee, Jonathan A.

    2000-01-01

    The state-of-the-art development of several aluminum and copper based Metal Matrix Composites (MMC) for NASA's advanced propulsion systems will be presented. The presentation's goal is to provide an overview of NASA-Marshall Space Flight Center's planned and on-going activities in MMC for advanced liquid rocket engines such as the X-33 vehicle's Aerospike and X-34 Fastrac engine. The focus will be on lightweight and environmental compatibility with oxygen and hydrogen of key MMC materials, within each NASA's new propulsion application, that will provide a high payoff for NASA's reusable launch vehicle systems and space access vehicles. Advanced MMC processing techniques such as plasma spray, centrifugal casting, pressure infiltration casting will be discussed. Development of a novel 3D printing method for low cost production of composite preform, and functional gradient MMC to enhanced rocket engine's dimensional stability will be presented.

  6. Metal hydride hydrogen compression: recent advances and future prospects

    NASA Astrophysics Data System (ADS)

    Yartys, Volodymyr A.; Lototskyy, Mykhaylo; Linkov, Vladimir; Grant, David; Stuart, Alastair; Eriksen, Jon; Denys, Roman; Bowman, Robert C.

    2016-04-01

    Metal hydride (MH) thermal sorption compression is one of the more important applications of the MHs. The present paper reviews recent advances in the field based on the analysis of the fundamental principles of this technology. The performances when boosting hydrogen pressure, along with two- and three-step compression units, are analyzed. The paper includes also a theoretical modelling of a two-stage compressor aimed at describing the performance of the experimentally studied systems, their optimization and design of more advanced MH compressors. Business developments in the field are reviewed for the Norwegian company HYSTORSYS AS and the South African Institute for Advanced Materials Chemistry. Finally, future prospects are outlined presenting the role of the MH compression in the overall development of the hydrogen-driven energy systems. The work is based on the analysis of the development of the technology in Europe, USA and South Africa.

  7. Photocatalytic Removal of Microcystin-LR by Advanced WO3-Based Nanoparticles under Simulated Solar Light

    PubMed Central

    Zhao, Chao; Li, Dawei; Feng, Chuanping; Zhang, Zhenya; Sugiura, Norio; Yang, Yingnan

    2015-01-01

    A series of advanced WO3-based photocatalysts including CuO/WO3, Pd/WO3, and Pt/WO3 were synthesized for the photocatalytic removal of microcystin-LR (MC-LR) under simulated solar light. In the present study, Pt/WO3 exhibited the best performance for the photocatalytic degradation of MC-LR. The MC-LR degradation can be described by pseudo-first-order kinetic model. Chloride ion (Cl−) with proper concentration could enhance the MC-LR degradation. The presence of metal cations (Cu2+ and Fe3+) improved the photocatalytic degradation of MC-LR. This study suggests that Pt/WO3 photocatalytic oxidation under solar light is a promising option for the purification of water containing MC-LR. PMID:25884038

  8. Advance in Photosensitizers and Light Delivery for Photodynamic Therapy

    PubMed Central

    Yoon, Il; Li, Jia Zhu

    2013-01-01

    The brief history of photodynamic therapy (PDT) research has been focused on photosensitizers (PSs) and light delivery was introduced recently. The appropriate PSs were developed from the first generation PS Photofrin (QLT) to the second (chlorins or bacteriochlorins derivatives) and third (conjugated PSs on carrier) generations PSs to overcome undesired disadvantages, and to increase selective tumor accumulation and excellent targeting. For the synthesis of new chlorin PSs chlorophyll a is isolated from natural plants or algae, and converted to methyl pheophorbide a (MPa) as an important starting material for further synthesis. MPa has various active functional groups easily modified for the preparation of different kinds of PSs, such as methyl pyropheophorbide a, purpurin-18, purpurinimide, and chlorin e6 derivatives. Combination therapy, such as chemotherapy and photothermal therapy with PDT, is shortly described here. Advanced light delivery system is shown to establish successful clinical applications of PDT. Phtodynamic efficiency of the PSs with light delivery was investigated in vitro and/or in vivo. PMID:23423543

  9. Current advances in precious metal core–shell catalyst design

    PubMed Central

    Wang, Xiaohong; He, Beibei; Hu, Zhiyu; Zeng, Zhigang; Han, Sheng

    2014-01-01

    Precious metal nanoparticles are commonly used as the main active components of various catalysts. Given their high cost, limited quantity, and easy loss of catalytic activity under severe conditions, precious metals should be used in catalysts at low volumes and be protected from damaging environments. Accordingly, reducing the amount of precious metals without compromising their catalytic performance is difficult, particularly under challenging conditions. As multifunctional materials, core–shell nanoparticles are highly important owing to their wide range of applications in chemistry, physics, biology, and environmental areas. Compared with their single-component counterparts and other composites, core–shell nanoparticles offer a new active interface and a potential synergistic effect between the core and shell, making these materials highly attractive in catalytic application. On one hand, when a precious metal is used as the shell material, the catalytic activity can be greatly improved because of the increased surface area and the closed interfacial interaction between the core and the shell. On the other hand, when a precious metal is applied as the core material, the catalytic stability can be remarkably improved because of the protection conferred by the shell material. Therefore, a reasonable design of the core–shell catalyst for target applications must be developed. We summarize the latest advances in the fabrications, properties, and applications of core–shell nanoparticles in this paper. The current research trends of these core–shell catalysts are also highlighted. PMID:27877695

  10. Current advances in precious metal core-shell catalyst design.

    PubMed

    Wang, Xiaohong; He, Beibei; Hu, Zhiyu; Zeng, Zhigang; Han, Sheng

    2014-08-01

    Precious metal nanoparticles are commonly used as the main active components of various catalysts. Given their high cost, limited quantity, and easy loss of catalytic activity under severe conditions, precious metals should be used in catalysts at low volumes and be protected from damaging environments. Accordingly, reducing the amount of precious metals without compromising their catalytic performance is difficult, particularly under challenging conditions. As multifunctional materials, core-shell nanoparticles are highly important owing to their wide range of applications in chemistry, physics, biology, and environmental areas. Compared with their single-component counterparts and other composites, core-shell nanoparticles offer a new active interface and a potential synergistic effect between the core and shell, making these materials highly attractive in catalytic application. On one hand, when a precious metal is used as the shell material, the catalytic activity can be greatly improved because of the increased surface area and the closed interfacial interaction between the core and the shell. On the other hand, when a precious metal is applied as the core material, the catalytic stability can be remarkably improved because of the protection conferred by the shell material. Therefore, a reasonable design of the core-shell catalyst for target applications must be developed. We summarize the latest advances in the fabrications, properties, and applications of core-shell nanoparticles in this paper. The current research trends of these core-shell catalysts are also highlighted.

  11. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    DOE PAGES

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; ...

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 timesmore » better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.« less

  12. Design of the Advanced Light Source timing system

    SciTech Connect

    Fahmie, M.

    1993-05-01

    The Advanced Light Source (ALS) is a third generation synchrotron radiation facility, and as such, has several unique timing requirements. Arbitrary Storage Ring filling patterns and high single bunch purity requirements demand a highly stable, low jitter timing system with the flexibility to reconfigure on a pulse-to-pulse basis. This modular system utilizes a highly linear Gauss Clock with ``on the fly`` programmable setpoints to track a free-running Booster ramping magnet and provides digitally programmable sequencing and delay for Electron Gun, Linac, Booster Ring, and Storage Ring RF, Pulsed Magnet, and Instrumentation systems. It has proven itself over the last year of accelerator operation to be reliable and rock solid.

  13. Observations of collective effects at the Advanced Light Source

    SciTech Connect

    Byrd, J.M.; Barry, W.; Corlett, J.N.; Fox, J.; Teytelman, D.

    1995-10-01

    We present a summary of measurements of single beam collective effects in the Advanced Light Source (ALS). We describe measurements of coupled-bunch instabilities, including some recent results using the newly commissioned feedback systems and the results of an initial search for the fast ion instability. Single bunch effects include bunch lengthening, energy spread increase, HOM loss measurements, head-tail damping rates, current dependent tune shifts, and transverse mode coupling instability threshold. The longitudinal measurements are consistent with a broadband impedance {vert_bar}{Zeta}{sub {parallel}}/{eta}{vert_bar}{sub eff} = 0.22{plus_minus}0.07 {Omega} and transverse measurements indicate broadband impedances of {Zeta}{sub y,eff} = 155 k{Omega}/m and Z{sub x,eff} = 58 k{Omega}/m.

  14. Applications of advanced aerodynamic technology to light aircraft.

    NASA Technical Reports Server (NTRS)

    Crane, H. L.; Mcghee, R. J.; Kohlman, D. L.

    1973-01-01

    This paper discusses a project for adapting advanced technology, much of it borrowed from the jet transport, to general aviation design practice. The NASA funded portion of the work began in 1969 at the University of Kansas and resulted in a smaller, experimental wing with spoilers and powerful flap systems for a Cessna Cardinal airplane. Some flight data and research pilot comments are presented. The project was expanded in 1972 to include a light twin-engine airplane. For the twin there was the added incentive of a potential increase in single-engine climb performance. The use of a new high-lift Whitcomb airfoil is planned for both the wing and the propellers. Preliminary data on the characteristics of the new airfoil are discussed. The configuration of an experimental wing for a Piper Seneca PA-34 and estimated airplane performance with this wing are discussed.

  15. Imaging spectroscopic analysis at the Advanced Light Source

    SciTech Connect

    MacDowell, A. A.; Warwick, T.; Anders, S.; Lamble, G.M.; Martin, M.C.; McKinney, W.R.; Padmore, H.A.

    1999-05-12

    One of the major advances at the high brightness third generation synchrotrons is the dramatic improvement of imaging capability. There is a large multi-disciplinary effort underway at the ALS to develop imaging X-ray, UV and Infra-red spectroscopic analysis on a spatial scale from. a few microns to 10nm. These developments make use of light that varies in energy from 6meV to 15KeV. Imaging and spectroscopy are finding applications in surface science, bulk materials analysis, semiconductor structures, particulate contaminants, magnetic thin films, biology and environmental science. This article is an overview and status report from the developers of some of these techniques at the ALS. The following table lists all the currently available microscopes at the. ALS. This article will describe some of the microscopes and some of the early applications.

  16. The Advanced Light Source at Lawrence Berkeley Laboratory

    NASA Astrophysics Data System (ADS)

    Robinson, A. L.; Perera, R. C. C.; Schlachter, A. S.

    1992-01-01

    The Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory (LBL), scheduled to be operational in the spring of 1993 as a U.S. Department of Energy national user facility, will be a next-generation source of soft x-ray and ultraviolet (XUV) synchrotron radiation. Undulators will provide the world's brightest synchrotron radiation at photon energies from below 10 eV to above 2 keV; wiggler and bend-magnet radiation will extend the spectral coverage with high fluxes above 10 keV. These capabilities will support an extensive research program in a broad spectrum of scientific and technological areas in which XUV radiation is used to study and manipulate matter in all its varied gaseous, liquid, and solid forms. The ALS will also serve those interested in developing the fabrication technology for microstructures and nanostructures, as well as for characterizing them.

  17. Research opportunities in atomic physics at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Schlachter, A. S.; Robinson, A. L.

    1989-09-01

    The Advanced Light Source (ALS) now under construction at the Lawrence Berkeley Laboratory is being planned as a national user facility for the production of high-brightness and partially coherent X-ray and ultraviolet synchrotron radiation. The ALS is based on a low-emittance electron storage ring optimized for operation at 1.5 GeV with insertion devices in 11 long straight sections and up to 48 bending-magnet ports. High-brightness photon beams from less than 10 eV to more than 1 keV will be produced by undulators, thereby providing many research opportunities in atomic and molecular physics and chemistry. Wigglers and bending magnets will provide high-flux broad-band radiation at energies to 10 keV.

  18. Performance of Advanced Light Source particle beam diagnostics

    SciTech Connect

    Hinkson, J.

    1993-05-01

    The Advanced Light Source (ALS), a third-generation synchrotron radiation facility, is complete. The particle beam diagnostics have been installed and tested. The beam injection systems have been running for two years. We have performance data on beam position monitors, beam intensity monitors, scintillators, beam collimators, a 50 {Omega} Faraday cup, and broad-band striplines and kickers used in the linac, transport lines, and the booster synchrotron. The single-turn monitoring capability of the booster beam position monitoring system has been particularly useful for studying beam dynamics. Beam diagnostics for the storage ring are being commissioned. In this paper we describe each instrument, show its performance, and outline how the instruments are controlled and their output data displayed.

  19. Invited Review Article: Advanced light microscopy for biological space research

    NASA Astrophysics Data System (ADS)

    De Vos, Winnok H.; Beghuin, Didier; Schwarz, Christian J.; Jones, David B.; van Loon, Jack J. W. A.; Bereiter-Hahn, Juergen; Stelzer, Ernst H. K.

    2014-10-01

    As commercial space flights have become feasible and long-term extraterrestrial missions are planned, it is imperative that the impact of space travel and the space environment on human physiology be thoroughly characterized. Scrutinizing the effects of potentially detrimental factors such as ionizing radiation and microgravity at the cellular and tissue level demands adequate visualization technology. Advanced light microscopy (ALM) is the leading tool for non-destructive structural and functional investigation of static as well as dynamic biological systems. In recent years, technological developments and advances in photochemistry and genetic engineering have boosted all aspects of resolution, readout and throughput, rendering ALM ideally suited for biological space research. While various microscopy-based studies have addressed cellular response to space-related environmental stressors, biological endpoints have typically been determined only after the mission, leaving an experimental gap that is prone to bias results. An on-board, real-time microscopical monitoring device can bridge this gap. Breadboards and even fully operational microscope setups have been conceived, but they need to be rendered more compact and versatile. Most importantly, they must allow addressing the impact of gravity, or the lack thereof, on physiologically relevant biological systems in space and in ground-based simulations. In order to delineate the essential functionalities for such a system, we have reviewed the pending questions in space science, the relevant biological model systems, and the state-of-the art in ALM. Based on a rigorous trade-off, in which we recognize the relevance of multi-cellular systems and the cellular microenvironment, we propose a compact, but flexible concept for space-related cell biological research that is based on light sheet microscopy.

  20. Invited Review Article: Advanced light microscopy for biological space research

    SciTech Connect

    De Vos, Winnok H.; Beghuin, Didier; Schwarz, Christian J.; Jones, David B.; Loon, Jack J. W. A. van

    2014-10-15

    As commercial space flights have become feasible and long-term extraterrestrial missions are planned, it is imperative that the impact of space travel and the space environment on human physiology be thoroughly characterized. Scrutinizing the effects of potentially detrimental factors such as ionizing radiation and microgravity at the cellular and tissue level demands adequate visualization technology. Advanced light microscopy (ALM) is the leading tool for non-destructive structural and functional investigation of static as well as dynamic biological systems. In recent years, technological developments and advances in photochemistry and genetic engineering have boosted all aspects of resolution, readout and throughput, rendering ALM ideally suited for biological space research. While various microscopy-based studies have addressed cellular response to space-related environmental stressors, biological endpoints have typically been determined only after the mission, leaving an experimental gap that is prone to bias results. An on-board, real-time microscopical monitoring device can bridge this gap. Breadboards and even fully operational microscope setups have been conceived, but they need to be rendered more compact and versatile. Most importantly, they must allow addressing the impact of gravity, or the lack thereof, on physiologically relevant biological systems in space and in ground-based simulations. In order to delineate the essential functionalities for such a system, we have reviewed the pending questions in space science, the relevant biological model systems, and the state-of-the art in ALM. Based on a rigorous trade-off, in which we recognize the relevance of multi-cellular systems and the cellular microenvironment, we propose a compact, but flexible concept for space-related cell biological research that is based on light sheet microscopy.

  1. Invited review article: Advanced light microscopy for biological space research.

    PubMed

    De Vos, Winnok H; Beghuin, Didier; Schwarz, Christian J; Jones, David B; van Loon, Jack J W A; Bereiter-Hahn, Juergen; Stelzer, Ernst H K

    2014-10-01

    As commercial space flights have become feasible and long-term extraterrestrial missions are planned, it is imperative that the impact of space travel and the space environment on human physiology be thoroughly characterized. Scrutinizing the effects of potentially detrimental factors such as ionizing radiation and microgravity at the cellular and tissue level demands adequate visualization technology. Advanced light microscopy (ALM) is the leading tool for non-destructive structural and functional investigation of static as well as dynamic biological systems. In recent years, technological developments and advances in photochemistry and genetic engineering have boosted all aspects of resolution, readout and throughput, rendering ALM ideally suited for biological space research. While various microscopy-based studies have addressed cellular response to space-related environmental stressors, biological endpoints have typically been determined only after the mission, leaving an experimental gap that is prone to bias results. An on-board, real-time microscopical monitoring device can bridge this gap. Breadboards and even fully operational microscope setups have been conceived, but they need to be rendered more compact and versatile. Most importantly, they must allow addressing the impact of gravity, or the lack thereof, on physiologically relevant biological systems in space and in ground-based simulations. In order to delineate the essential functionalities for such a system, we have reviewed the pending questions in space science, the relevant biological model systems, and the state-of-the art in ALM. Based on a rigorous trade-off, in which we recognize the relevance of multi-cellular systems and the cellular microenvironment, we propose a compact, but flexible concept for space-related cell biological research that is based on light sheet microscopy.

  2. Photocapacitive light sensor based on metal-YMnO3-insulator-semiconductor structures

    NASA Astrophysics Data System (ADS)

    Bogusz, A.; Choudhary, O. S.; Skorupa, I.; Bürger, D.; Lawerenz, A.; Lei, Y.; Zeng, H.; Abendroth, B.; Stöcker, H.; Schmidt, O. G.; Schmidt, H.

    2016-02-01

    Technology of light sensors, due to the wide range of applications, is a dynamically developing branch of both science and industry. This work presents concept of photodetectors based on a metal-ferroelectric-insulator-semiconductor, a structure which has not been thoroughly explored in the field of photodetectors. Functionality of the presented light sensor exploits the effects of photocapacitive phenomena, ferroelectric polarization, and charge trapping. This is accomplished by an interplay between polarization alignment, subsequent charge distribution, and charge trapping processes under given illumination condition and gate voltage. Change of capacitance serves as a read out parameter indicating the wavelength and intensity of the illuminating light. The operational principle of the proposed photocapacitive light sensor is demonstrated in terms of capacitance-voltage and capacitance-time characteristics of an Al/YMnO3/SiNx/p-Si structure exposed to green, red, and near infrared light. Obtained results are discussed in terms of optical properties of YMnO3 and SiNx layers contributing to the performance of photodetectors. Presented concept of light sensing might serve as the basis for the development of more advanced photodetectors.

  3. Summary of advanced LMR (Liquid Metal Reactor) evaluations: PRISM (Power Reactor Inherently Safe Module) and SAFR (Sodium Advanced Fast Reactor)

    SciTech Connect

    Van Tuyle, G.J.; Slovik, G.C.; Chan, B.C.; Kennett, R.J.; Cheng, H.S.; Kroeger, P.G. )

    1989-10-01

    In support of the US Nuclear Regulatory Commission (NRC), Brookhaven National Laboratory (BNL) has performed independent analyses of two advanced Liquid Metal Reactor (LMR) concepts. The designs, sponsored by the US Department of Energy (DOE), the Power Reactor Inherently Safe Module (PRISM) (Berglund, 1987) and the Sodium Advanced Fast Reactor (SAFR) (Baumeister, 1987), were developed primarily by General Electric (GE) and Rockwell International (RI), respectively. Technical support was provided to DOE, RI, and GE, by the Argonne National Laboratory (ANL), particularly with respect to the characteristics of the metal fuels. There are several examples in both PRISM and SAFR where inherent or passive systems provide for a safe response to off-normal conditions. This is in contrast to the engineered safety systems utilized on current US Light Water Reactor (LWR) designs. One important design inherency in the LMRs is the inherent shutdown'', which refers to the tendency of the reactor to transition to a much lower power level whenever temperatures rise significantly. This type of behavior was demonstrated in a series of unscrammed tests at EBR-II (NED, 1986). The second key design feature is the passive air cooling of the vessel to remove decay heat. These systems, designated RVACS in PRISM and RACS in SAFR, always operate and are believed to be able to prevent core damage in the event that no other means of heat removal is available. 27 refs., 78 figs., 3 tabs.

  4. XUV synchrotron optical components for the Advanced Light Source: Summary of the requirements and the developmental program

    SciTech Connect

    McKinney, W.; Irick, S.; Lunt, D.

    1992-07-01

    We give a brief summary of the requirements for water cooled optical components for the Advanced Light Source (ALS), a third generation synchrotron radiation source under construction at Lawrence Berkeley Laboratory (LBL). Materials choices, surface figure and smoothness specifications, and metrology systems for measuring the plated metal surfaces are discussed. Results from a finished water cooled copper alloy mirror will be used to demonstrate the state of the art in optical metrology with the Takacs Long Trace Profiler (LTP II).

  5. Transition Metal Intercalators as Anticancer Agents—Recent Advances

    PubMed Central

    Deo, Krishant M.; Pages, Benjamin J.; Ang, Dale L.; Gordon, Christopher P.; Aldrich-Wright, Janice R.

    2016-01-01

    The diverse anticancer utility of cisplatin has stimulated significant interest in the development of additional platinum-based therapies, resulting in several analogues receiving clinical approval worldwide. However, due to structural and mechanistic similarities, the effectiveness of platinum-based therapies is countered by severe side-effects, narrow spectrum of activity and the development of resistance. Nonetheless, metal complexes offer unique characteristics and exceptional versatility, with the ability to alter their pharmacology through facile modifications of geometry and coordination number. This has prompted the search for metal-based complexes with distinctly different structural motifs and non-covalent modes of binding with a primary aim of circumventing current clinical limitations. This review discusses recent advances in platinum and other transition metal-based complexes with mechanisms of action involving intercalation. This mode of DNA binding is distinct from cisplatin and its derivatives. The metals focused on in this review include Pt, Ru and Cu along with examples of Au, Ni, Zn and Fe complexes; these complexes are capable of DNA intercalation and are highly biologically active. PMID:27809241

  6. Development of Metal Matrix Composites for NASA's Advanced Propulsion Systems

    NASA Technical Reports Server (NTRS)

    Lee, J.; Elam, S.

    2001-01-01

    The state-of-the-art development of several Metal Matrix Composites (MMC) for NASA's advanced propulsion systems will be presented. The goal is to provide an overview of NASA-Marshall Space Flight Center's on-going activities in MMC components for advanced liquid rocket engines such as the X-33 vehicle's Aerospike engine and X-34's Fastrac engine. The focus will be on lightweight, low cost, and environmental compatibility with oxygen and hydrogen of key MMC materials, within each of NASA's new propulsion application, that will provide a high payoff for NASA's Reusable Launch Vehicles and space access vehicles. In order to fabricate structures from MMC, effective joining methods must be developed to join MMC to the same or to different monolithic alloys. Therefore, a qualitative assessment of MMC's welding and joining techniques will be outlined.

  7. Advanced technologies for decomtamination and conversion of scrap metal

    SciTech Connect

    Valerie MacNair; Steve Sarten; Thomas Muth; Brajendra Mishra

    1999-05-27

    The Department of Energy (DOE) faces the task of decommissioning much of the vast US weapons complex. One challenge of this effort includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for cleanup of contaminated sites and facilities. Recycling helps to offset the cost of decommissioning and saves valuable space in the waste disposal facilities. It also reduces the amount of environmental effects associated with mining new metals. Work on this project is geared toward finding decontamination and/or recycling alternatives for the RSM contained in the decommissioned gaseous diffusion plants including approximately 40,000 tons of nickel. The nickel is contaminated with Technetium-99, and is difficult to remove using traditional decontamination technologies. The project, titled ``Advanced Technologies for Decontamination and Conversion of Scrap Metal'' was proposed as a four phase project. Phase 1 and 2 are complete and Phase 3 will complete May 31, 1999. Stainless steel made from contaminated nickel barrier was successfully produced in Phase 1. An economic evaluation was performed and a market study of potential products from the recycled metal was completed. Inducto-slag refining, after extensive testing, was eliminated as an alternative to remove technetium contamination from nickel. Phase 2 included successful lab scale and pilot scale demonstrations of electrorefining to separate technetium from nickel. This effort included a survey of available technologies to detect technetium in volumetrically contaminated metals. A new process to make sanitary drums from RSM was developed and implemented. Phase 3 included a full scale demonstration of electrorefining, an evaluation of electro-refining alternatives including direct dissolution, melting of nickel into anodes, a laser cutting

  8. Rechargeable dual-metal-ion batteries for advanced energy storage.

    PubMed

    Yao, Hu-Rong; You, Ya; Yin, Ya-Xia; Wan, Li-Jun; Guo, Yu-Guo

    2016-04-14

    Energy storage devices are more important today than any time before in human history due to the increasing demand for clean and sustainable energy. Rechargeable batteries are emerging as the most efficient energy storage technology for a wide range of portable devices, grids and electronic vehicles. Future generations of batteries are required to have high gravimetric and volumetric energy, high power density, low price, long cycle life, high safety and low self-discharge properties. However, it is quite challenging to achieve the above properties simultaneously in state-of-the-art single metal ion batteries (e.g. Li-ion batteries, Na-ion batteries and Mg-ion batteries). In this contribution, hybrid-ion batteries in which various metal ions simultaneously engage to store energy are shown to provide a new perspective towards advanced energy storage: by connecting the respective advantages of different metal ion batteries they have recently attracted widespread attention due to their novel performances. The properties of hybrid-ion batteries are not simply the superposition of the performances of single ion batteries. To enable a distinct description, we only focus on dual-metal-ion batteries in this article, for which the design and the benefits are briefly discussed. We enumerate some new results about dual-metal-ion batteries and demonstrate the mechanism for improving performance based on knowledge from the literature and experiments. Although the search for hybrid-ion batteries is still at an early age, we believe that this strategy would be an excellent choice for breaking the inherent disadvantages of single ion batteries in the near future.

  9. Scientific program of the advanced light source at LBL

    NASA Astrophysics Data System (ADS)

    Robinson, A. L.; Schlachter, A. S.

    1992-08-01

    Construction of the Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory is nearing completion, with operation as a US Department of Energy national user facility scheduled to begin in the spring of 1993. Based on a low-emittance, 1.5 GeV electron storage ring with ten long straight sections available for insertion devices and, initially, 24 bend-magnet ports, the ALS will be a third-generation source of soft X-ray and ultraviolet (collectively, the XUV) synchrotron radiation. Experimental facilities (insertion devices, beamlines, and end stations) will be developed and operated by participating research teams working with the ALS staff. The ability to exploit the high spectral brightness of the ALS was the main criterion for PRT selection. In the XUV spectral regions served by the ALS, a major benefit of high brightness will be the ability to achieve spatial resolution in the neighborhood of 200 Å in X-ray microscopy and holography and in spatially resolved spectroscopy. Other beneficiaries of high brightness include very-high-resolution spectroscopy, spectroscopy of dilute species, diffraction from very small samples, and time-resolved spectroscopy and diffraction.

  10. Advanced light microscopy core facilities: Balancing service, science and career

    PubMed Central

    Hartmann, Hella; Reymann, Jürgen; Ansari, Nariman; Utz, Nadine; Fried, Hans‐Ulrich; Kukat, Christian; Peychl, Jan; Liebig, Christian; Terjung, Stefan; Laketa, Vibor; Sporbert, Anje; Weidtkamp‐Peters, Stefanie; Schauss, Astrid; Zuschratter, Werner; Avilov, Sergiy

    2016-01-01

    ABSTRACT Core Facilities (CF) for advanced light microscopy (ALM) have become indispensable support units for research in the life sciences. Their organizational structure and technical characteristics are quite diverse, although the tasks they pursue and the services they offer are similar. Therefore, throughout Europe, scientists from ALM‐CFs are forming networks to promote interactions and discuss best practice models. Here, we present recommendations for ALM‐CF operations elaborated by the workgroups of the German network of ALM‐CFs, German Bio‐Imaging (GerBI). We address technical aspects of CF planning and instrument maintainance, give advice on the organization and management of an ALM‐CF, propose a scheme for the training of CF users, and provide an overview of current resources for image processing and analysis. Further, we elaborate on the new challenges and opportunities for professional development and careers created by CFs. While some information specifically refers to the German academic system, most of the content of this article is of general interest for CFs in the life sciences. Microsc. Res. Tech. 79:463–479, 2016. © 2016 THE AUTHORS MICROSCOPY RESEARCH AND TECHNIQUE PUBLISHED BY WILEY PERIODICALS, INC. PMID:27040755

  11. The Advanced Light Source U8 beam line, 20--300 eV

    SciTech Connect

    Heimann, P.; Warwick, T.; Howells, M.; McKinney, W.; Digennaro, D.; Gee, B.; Yee, D.; Kincaid, B.

    1991-10-01

    The U8 is a beam line under construction at the Advanced Light Source (ALS). The beam line will be described along with calculations of its performance and its current status. An 8 cm period undulator is followed by two spherical collecting mirrors, an entrance slit, spherical gratings having a 15{degree} deviation angle, a moveable exit slit, and refocusing and branching mirrors. Internal water cooling is provided to the metal M1 and M2 mirrors as well as to the gratings. Calculations have been made of both the flux output and the resolution over its photon energy range of 20--300 eV. The design goal was to achieve high intensity, 10{sup 12} photons/sec, at a high resolving power of 10,000. The U8 Participating Research Team (PRT) is planning experiments involving the photoelectron spectroscopy of gaseous atoms and molecules, the spectroscopy of ions and actinide spectroscopy.

  12. Metal fires and their implications for advanced reactors.

    SciTech Connect

    Nowlen, Steven Patrick; Figueroa, Victor G.; Olivier, Tara Jean; Hewson, John C.; Blanchat, Thomas K.

    2010-10-01

    This report details the primary results of the Laboratory Directed Research and Development project (LDRD 08-0857) Metal Fires and Their Implications for Advance Reactors. Advanced reactors may employ liquid metal coolants, typically sodium, because of their many desirable qualities. This project addressed some of the significant challenges associated with the use of liquid metal coolants, primary among these being the extremely rapid oxidation (combustion) that occurs at the high operating temperatures in reactors. The project has identified a number of areas for which gaps existed in knowledge pertinent to reactor safety analyses. Experimental and analysis capabilities were developed in these areas to varying degrees. In conjunction with team participation in a DOE gap analysis panel, focus was on the oxidation of spilled sodium on thermally massive surfaces. These are spills onto surfaces that substantially cool the sodium during the oxidation process, and they are relevant because standard risk mitigation procedures seek to move spill environments into this regime through rapid draining of spilled sodium. While the spilled sodium is not quenched, the burning mode is different in that there is a transition to a smoldering mode that has not been comprehensively described previously. Prior work has described spilled sodium as a pool fire, but there is a crucial, experimentally-observed transition to a smoldering mode of oxidation. A series of experimental measurements have comprehensively described the thermal evolution of this type of sodium fire for the first time. A new physics-based model has been developed that also predicts the thermal evolution of this type of sodium fire for the first time. The model introduces smoldering oxidation through porous oxide layers to go beyond traditional pool fire analyses that have been carried out previously in order to predict experimentally observed trends. Combined, these developments add significantly to the safety

  13. Metallic halide lights and lighting systems. (Latest citations from the US Patent Bibliographic file with exemplary claims). Published Search

    SciTech Connect

    Not Available

    1994-11-01

    The bibliography contains citations of selected patents concerning the design and operation of metallic halide lights and lighting systems. High pressure, high intensity, and low wattage discharge lamps are described. Citations discuss power sources, lamp life, lamp control circuits, thermal switches, and heat reflective coatings. Applications in sport stadium lighting, vehicle headlights, and crop-lighting are included. (Contains a minimum of 170 citations and includes a subject term index and title list.)

  14. Surface-mediated light transmission in metal nanoparticle chains

    NASA Astrophysics Data System (ADS)

    Compaijen, P. Jasper; Malyshev, Victor A.; Knoester, Jasper

    2013-05-01

    We study theoretically the efficiency of the transmission of optical signals through a linear chain consisting of identical and equidistantly spaced silver metal nanoparticles. Two situations are compared: the transmission efficiency through an isolated chain and through a chain in close proximity of a reflecting substrate. The Ohmic and radiative losses in each nanoparticle strongly affect the transmission efficiency of an isolated chain and suppress it to large extent. It is shown that the presence of a reflecting interface may enhance the guiding properties of the array. The reason for this is the energy exchange between the surface plasmon polaritons (SPPs) of the array and the substrate. We focus on the dependence of the transmission efficiency on the frequency and polarization of the incoming light, as well as on the influence of the array-interface spacing. Sometimes the effect of these parameters turns out to be counterintuitive, reflecting a complicated interplay of several transmission channels.

  15. Environment assisted degradation mechanisms in advanced light metals

    NASA Technical Reports Server (NTRS)

    Gangloff, Richard P.; Stoner, Glenn E.; Swanson, Robert E.

    1988-01-01

    The general goals of the research program are to characterize alloy behavior quantitatively and to develop predictive mechanisms for environmental failure modes. Successes in this regard will provide the basis for metallurgical optimization of alloy performance, for chemical control of aggressive environments, and for engineering life prediction with damage tolerance and long term reliability.

  16. Light-scattering Characteristics of Metal Nanoparticles on a Single Bacterial Cell.

    PubMed

    Kinoshita, Takamasa; Kiso, Keita; LE, Dung Q; Shiigi, Hiroshi; Nagaoka, Tsutomu

    2016-01-01

    Metal nanoparticles express unique light-scattering characteristics based on the localized surface plasmon resonance, which depends on the metal species, particle size, and aggregation state of the nanoparticles. Therefore, we focused on the light-scattering characteristics of metal nanoparticles, such as silver, gold, and copper oxide, adsorbed on a bacterium. Monodisperse silver nanoparticles expressed the strongest scattered light among them, and showed various colors of scattered light. Although a monodisperse gold nanoparticle produced monochromatic light (green color), the color of the scattered light strongly depended on the aggregation state of the nanoparticles on a bacterium. On the other hand, copper oxide nanoparticles expressed monochromatic light (blue color), regardless of their aggregation states on a bacterium. We examined details concerning the light-scattering characteristics of metal nanoparticles, and discussed the possibility of their applications to bacterial cell imaging.

  17. Asymmetric photoredox transition-metal catalysis activated by visible light

    NASA Astrophysics Data System (ADS)

    Huo, Haohua; Shen, Xiaodong; Wang, Chuanyong; Zhang, Lilu; Röse, Philipp; Chen, Liang-An; Harms, Klaus; Marsch, Michael; Hilt, Gerhard; Meggers, Eric

    2014-11-01

    Asymmetric catalysis is seen as one of the most economical strategies to satisfy the growing demand for enantiomerically pure small molecules in the fine chemical and pharmaceutical industries. And visible light has been recognized as an environmentally friendly and sustainable form of energy for triggering chemical transformations and catalytic chemical processes. For these reasons, visible-light-driven catalytic asymmetric chemistry is a subject of enormous current interest. Photoredox catalysis provides the opportunity to generate highly reactive radical ion intermediates with often unusual or unconventional reactivities under surprisingly mild reaction conditions. In such systems, photoactivated sensitizers initiate a single electron transfer from (or to) a closed-shell organic molecule to produce radical cations or radical anions whose reactivities are then exploited for interesting or unusual chemical transformations. However, the high reactivity of photoexcited substrates, intermediate radical ions or radicals, and the low activation barriers for follow-up reactions provide significant hurdles for the development of efficient catalytic photochemical processes that work under stereochemical control and provide chiral molecules in an asymmetric fashion. Here we report a highly efficient asymmetric catalyst that uses visible light for the necessary molecular activation, thereby combining asymmetric catalysis and photocatalysis. We show that a chiral iridium complex can serve as a sensitizer for photoredox catalysis and at the same time provide very effective asymmetric induction for the enantioselective alkylation of 2-acyl imidazoles. This new asymmetric photoredox catalyst, in which the metal centre simultaneously serves as the exclusive source of chirality, the catalytically active Lewis acid centre, and the photoredox centre, offers new opportunities for the `green' synthesis of non-racemic chiral molecules.

  18. Advanced Light Source activity report 1996/97

    SciTech Connect

    1997-09-01

    Ten years ago, the Advanced Light Source (ALS) existed as a set of drawings, calculations, and ideas. Four years ago, it stored an electron beam for the first time. Today, the ALS has moved from those ideas and beginnings to a robust, third-generation synchrotron user facility, with eighteen beam lines in use, many more in planning or construction phases, and hundreds of users from around the world. Progress from concepts to realities is continuous as the scientific program, already strong in many diverse areas, moves in new directions to meet the needs of researchers into the next century. ALS staff members who develop and maintain the infrastructure for this research are similarly unwilling to rest on their laurels. As a result, the quality of the photon beams the authors deliver, as well as the support they provide to users, continues to improve. The ALS Activity Report is designed to share the results of these efforts in an accessible form for a broad audience. The Scientific Program section, while not comprehensive, shares the breadth, variety, and interest of recent research at the ALS. (The Compendium of User Abstracts and Technical Reports provides a more comprehensive and more technical view.) The Facility Report highlights progress in operations, ongoing accelerator research and development, and beamline instrumentation efforts. Although these Activity Report sections are separate, in practice the achievements of staff and users at the ALS are inseparable. User-staff collaboration is essential as they strive to meet the needs of the user community and to continue the ALS's success as a premier research facility.

  19. Light extraction improvement of blue light-emitting diodes with a Metal-distributed Bragg reflector current blocking layer

    NASA Astrophysics Data System (ADS)

    Liu, Na; Yi, Xiaoyan; Wang, Li; Sun, Xuejiao; Liu, Lei; Liu, Zhiqiang; Wang, Junxi; Li, Jinmin

    2015-03-01

    The p-electrode of blue light-emitting diodes (LED) chips has a low transmittance on the blue light spectrum. The blue light emitted from the quantum wells under the p-electrode will be severely absorbed by p-electrode, which cause a decrease in blue light extraction efficiency (LEE). In this study, we first designed a current blocking layer (CBL) structure with the blue light reflection through the simulation software. The simulation results show that this structure can effectively improve blue LEE, and then, this structure was verified by experiment. Electroluminescence measurement results show that LED with Metal-distributed Bragg reflector (M-DBR) CBL exhibited better optical performance than the LED with SiO2 CBL and DBR CBL. It was found that M-DBR CBL can effectively increase the blue light reflectivity and prevent the light absorption from the metal p-electrode to improve LED' blue LEE.

  20. Recent Advances in Carbon Capture with Metal-Organic Frameworks.

    PubMed

    Stylianou, Kyriakos C; Queen, Wendy L

    2015-01-01

    The escalating level of CO(2) in the atmosphere is one of the most critical environmental issues of our age. The carbon capture and storage from pilot test plants represents an option for reducing CO(2) emissions, however, the energy cost associated with post-combustion carbon capture process alone is ∼30% of the total energy generated by the power plant. Thus, the generation of carbon capture adsorbents with high uptake capacities, great separation performance and low cost is of paramount importance. Metal-organic frameworks are infinite networks of metal-containing nodes bridged by organic ligands through coordination bonds into porous extended structures and several reports have revealed that they are ideal candidates for the selective capture of CO(2). In this review we summarize recent advances related to the synthesis of porous MOFs and the latest strategies to enhance the CO(2) adsorption enthalpies and capacities at low-pressures, increase hydrolytic and mechanical stabilities, and improve the ease of regeneration. Although they show great promise for post-combustion carbon capture, there are still major challenges that must be overcome before they can be used for such a large-scale application.

  1. Advanced in aerospace lubricant and wear metal analysis

    SciTech Connect

    Saba, C.S.; Centers, P.W.

    1995-09-01

    Wear metal analysis continues to play an effective diagnostic role for condition monitoring of gas turbine engines. Since the early 1960s the United States` military services have been using spectrometric oil analysis program (SOAP) to monitor the condition of aircraft engines. The SOAP has proven to be effective in increasing reliability, fleet readiness and avoiding losses of lives and machinery. Even though historical data have demonstrated the success of the SOAP in terms of detecting imminent engine failure verified by maintenance personnel, the SOAP is not a stand-alone technique and is limited in its detection of large metallic wear debris. In response, improved laboratory, portable, in-line and on-line diagnostic techniques to perfect SOAP and oil condition monitoring have been sought. The status of research and development as well as the direction of future developmental activities in oil analysis due to technological opportunities, advanced in engine development and changes in military mission are reviewed and discussed. 54 refs.

  2. Transmission of light through slits array in a metal-insulator-metal structure

    NASA Astrophysics Data System (ADS)

    Huang, Bo; Luo, Zhi; Wu, Xia; Yang, Huidong; He, Guannan

    2017-01-01

    Light transmission through slits array in a thin dielectric core layer sandwiched between two metallic cladding (MIM) is investigated using the finite-difference time-domain (FDTD) method. The dispersion relation of surface plasmon polariton (SPP) in the MIM structure is analyzed. The results show that SPP modes on the core layer act as a resonator-coupler, which helps to couple the resonance energy in the upper slit arrays to that in the lower slit arrays, and there is an enhanced transmission peak under appropriate resonance conditions. Coupling process is verified by the field profiles of the SPP modes calculated by FDTD method. Different MIM structures are designed to control the light transmission.

  3. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  4. Artificial light at night advances avian reproductive physiology

    PubMed Central

    Dominoni, Davide; Quetting, Michael; Partecke, Jesko

    2013-01-01

    Artificial light at night is a rapidly increasing phenomenon and it is presumed to have global implications. Light at night has been associated with health problems in humans as a consequence of altered biological rhythms. Effects on wild animals have been less investigated, but light at night has often been assumed to affect seasonal cycles of urban dwellers. Using light loggers attached to free-living European blackbirds (Turdus merula), we first measured light intensity at night which forest and city birds are subjected to in the wild. Then we used these measurements to test for the effect of light at night on timing of reproductive physiology. Captive city and forest blackbirds were exposed to either dark nights or very low light intensities at night (0.3 lux). Birds exposed to light at night developed their reproductive system up to one month earlier, and also moulted earlier, than birds kept under dark nights. Furthermore, city birds responded differently than forest individuals to the light at night treatment, suggesting that urbanization can alter the physiological phenotype of songbirds. Our results emphasize the impact of human-induced lighting on the ecology of millions of animals living in cities and call for an understanding of the fitness consequences of light pollution. PMID:23407836

  5. Metallic Seal Development for Advanced Docking/Berthing System

    NASA Technical Reports Server (NTRS)

    Oswald, Jay; Daniels, Christopher; Dunlap, Patrick, Jr.; Steinetz, Bruce

    2006-01-01

    Feasibility of metal-to-metal androgenous seals has been demonstrated. Techniques to minimize surface irregularities must be examined. Two concepts investigated: 1) Flexible metal interface with elastomeric preloader; 2) Flexibility will accommodate any surface irregularities from the mating surface. Rigid metal interface with elastomeric preloader. Rigidity of the metal surface will prevent irregularities (waves) from occurring.

  6. Synchrotron X-Ray Microdiffraction Studies of Electromigration in Interconnect lines at the Advanced Light Source

    SciTech Connect

    Tamura, Nobumichi; Chen, Kai; Kunz, Martin

    2009-05-01

    Synchrotron polychromatic X-ray microdiffraction is a particularly suitable technique to study in situ the effect of electromigration in metal interconnects as add spatial resolution to grain orientation and strain sensitivity. This technique has been extensively used at the Advanced Light Source to monitor changes in aluminum and copper interconnect test structures while high-density current is passed into them during accelerated tests at elevated temperature. One of the principal findings is the observation of electromigration-induced plasticity in the metal lines that appear during the very early stages of electromigration. In some of the lines, high density of geometrically necessary dislocation are formed leading to additional diffusion paths causing an enhancement of electromigration effect at test temperature. This paper presents an overview of the principal results obtained from X-ray microdiffraction studies of electromigration effects on aluminum and copper interconnects at the ALS throughout continuous efforts that spanned over a decade (1998-2008) from approximately 40 weeks of combined beamtime.

  7. Conical reflection of light during free-space coupling into a symmetrical metal-cladding waveguide.

    PubMed

    Zheng, Yuanlin; Cao, Zhuangqi; Chen, Xianfeng

    2013-09-01

    Novel conical reflection of light by a thick three-layered metal-clad optical waveguide is observed. A symmetrical metal-cladding optical waveguide is used, which exhibits extraordinary conical reflection during free-space coupling of light to the waveguide. The phenomenon is attributed to the leakage of excited ultrahigh-order guided modes and their inter- and intramode coupling interaction.

  8. Magnetoresistance of heavy and light metal/ferromagnet bilayers

    SciTech Connect

    Avci, Can Onur; Garello, Kevin; Mendil, Johannes; Ghosh, Abhijit; Blasakis, Nicolas; Gabureac, Mihai; Trassin, Morgan; Fiebig, Manfred; Gambardella, Pietro

    2015-11-09

    We studied the magnetoresistance of normal metal (NM)/ferromagnet (FM) bilayers in the linear and nonlinear (current-dependent) regimes and compared it with the amplitude of the spin-orbit torques and thermally induced electric fields. Our experiments reveal that the magnetoresistance of the heavy NM/Co bilayers (NM = Ta, W, and Pt) is phenomenologically similar to the spin Hall magnetoresistance (SMR) of YIG/Pt, but has a much larger anisotropy of the order of 0.5%, which increases with the atomic number of the NM. This SMR-like behavior is absent in light NM/Co bilayers (NM = Ti and Cu), which present the standard anisotropic magnetoresistance expected from polycrystalline FM layers. In the Ta, W, and Pt/Co bilayers, we find an additional magnetoresistance directly proportional to the current and to the transverse component of the magnetization. This so-called unidirectional SMR, of the order of 0.005%, is largest in W and correlates with the amplitude of the antidamping spin-orbit torque. The unidirectional SMR is below the accuracy of our measurements in YIG/Pt.

  9. Hydrogen storage and generation using light metal hydrides

    SciTech Connect

    Lynch, F.; Mork, B.J.; Wilkes, J.S.

    1998-07-01

    The storage of hydrogen for use in fuel cells employed as portable electric power sources is important. For many applications pressurized gas or cryogenic liquid storage is not acceptable from weight or safety standpoints. This is particularly true for moderate power systems in the 50--200 watt range. A potentially attractive technology for providing hydrogen for moderately sized fuel cell-based electric power supplies is chemical hydrides. In general, chemical hydrides are materials that store hydrogen that may be released by chemical reactions. The authors report here the use of light metal hydrides, such as lithium aluminum tetrahydride and trilithium aluminum hexahydride to store hydrogen in a very dense form; about four times the density of liquid hydrogen. The hydrogen can be released by reaction with simple chemical reagents, such as water or ammonia, at approximately atmospheric pressure and at modest temperatures. The reaction rate may be controlled to provide hydrogen at a rate appropriate to that needed by a fuel cell operating at the power levels mentioned above. Usually hydrogen is the sole gaseous product, along with several solid products.

  10. NASA Laser Light Scattering Advanced Technology Development Workshop, 1988

    NASA Technical Reports Server (NTRS)

    Meyer, William V. (Editor)

    1989-01-01

    The major objective of the workshop was to explore the capabilities of existing and prospective laser light scattering hardware and to assess user requirements and needs for a laser light scattering instrument in a reduced gravity environment. The workshop addressed experimental needs and stressed hardware development.

  11. Backscatter tolerant squeezed light source for advanced gravitational-wave detectors.

    PubMed

    Chua, Sheon S Y; Stefszky, Michael S; Mow-Lowry, Conor M; Buchler, Ben C; Dwyer, Sheila; Shaddock, Daniel A; Lam, Ping Koy; McClelland, David E

    2011-12-01

    We report on the performance of a dual-wavelength resonant, traveling-wave optical parametric oscillator to generate squeezed light for application in advanced gravitational-wave interferometers. Shot noise suppression of 8.6±0.8 dB was measured across the detection band of interest to Advanced LIGO, and controlled squeezing measured over 5900 s. Our results also demonstrate that the traveling-wave design has excellent intracavity backscattered light suppression of 47 dB and incident backscattered light suppression of 41 dB, which is a crucial design issue for application in advanced interferometers.

  12. Toward femtosecond X-ray spectroscopy at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Chong, Henry Herng Wei

    The realization of tunable, ultrashort pulse x-ray sources promises to open new venues of science and to shed new light on long-standing problems in condensed matter physics and chemistry. Fundamentally new information can now be accessed. Used in a pump-probe spectroscopy, ultrashort x-ray pulses provide a means to monitor atomic rearrangement and changes in electronic structure in condensed-matter and chemical systems on the physically-limiting time-scales of atomic motion. This opens the way for the study of fast structural dynamics and the role they play in phase transitions, chemical reactions and the emergence of exotic properties in materials with strongly interacting degrees of freedom. The ultrashort pulse x-ray source developed at the Advanced Light Source at the Lawrence Berkeley Laboratory is based on electron slicing in storage rings, and generates ˜100 femtosecond pulses of synchrotron radiation spanning wavelengths from the far-infrared to the hard x-ray region of the electromagnetic spectrum. The tunability of the source allows for the adaptation of a broad range of static x-ray spectroscopies to useful pump-probe measurements. Initial experiments are attempted on transition metal complexes that exhibit relatively large structural changes upon photo-excitation and which have excited-state evolution determined by strongly interacting structural, electronic and magnetic degrees of freedom. Specifically, iron(II) complexes undergo a spin-crossover transition upon optical irradiation. The dynamics of the transition involve a metal-to-ligand charge transfer, a DeltaS = 2 change in magnetic moment and 10% bond dilation in the first coordination shell of the iron. Studies of the electronic dynamics are studied with time-resolved optical absorption measurements. The current progress of time-resolved structural studies to complete the picture of the spin-crossover transition is presented.

  13. Toward Femtosecond X-ray Spectroscopy at the Advanced Light Source

    SciTech Connect

    Chong, Henry Herng Wei

    2004-01-01

    The realization of tunable, ultrashort pulse x-ray sources promises to open new venues of science and to shed new light on long-standing problems in condensed matter physics and chemistry. Fundamentally new information can now be accessed. Used in a pump-probe spectroscopy, ultrashort x-ray pulses provide a means to monitor atomic rearrangement and changes in electronic structure in condensed-matter and chemical systems on the physically-limiting time-scales of atomic motion. This opens the way for the study of fast structural dynamics and the role they play in phase transitions, chemical reactions and the emergence of exotic properties in materials with strongly interacting degrees of freedom. The ultrashort pulse x-ray source developed at the Advanced Light Source at the Lawrence Berkeley Laboratory is based on electron slicing in storage rings, and generates ~100 femtosecond pulses of synchrotron radiation spanning wavelengths from the far-infrared to the hard x-ray region of the electromagnetic spectrum. The tunability of the source allows for the adaptation of a broad range of static x-ray spectroscopies to useful pump-probe measurements. Initial experiments are attempted on transition metal complexes that exhibit relatively large structural changes upon photo-excitation and which have excited-state evolution determined by strongly interacting structural, electronic and magnetic degrees of freedom. Specifically, iron(II) complexes undergo a spin-crossover transition upon optical irradiation. The dynamics of the transition involve a metal-to-ligand charge transfer, a ΔS=2 change in magnetic moment and 10% bond dilation in the first coordination shell of the iron. Studies of the electronic dynamics are studied with time-resolved optical absorption measurements. The current progress of time-resolved structural studies to complete the picture of the spin-crossover transition is presented.

  14. Theory and modeling of light interactions with metallic nanostructures.

    SciTech Connect

    Montgomery, J. M.; Lee, T.-W.; Gray, S. K.; Louisiana State Univ.

    2008-08-13

    Metallic nanostructures such as systems containing metal nanoparticles or nanostructured metal films are intriguing systems of much current interest. Surface plasmons, i.e., special electronic excitations near the metallic surfaces, can then be excited in these systems. Surface plasmons can be intense and localized, and correctly describing their behavior in complex systems can require numerically rigorous modeling techniques. The finite-difference time-domain (FDTD) method is one such technique. This review discusses results obtained mostly with the FDTD method concerning (1) local surface plasmon excitations of metal nanoparticles, (2) surface plasmon polariton propagation on layered structures, and (3) periodic hole arrays in metal films.

  15. Science at the Speed of Light: Advanced Photon Source

    SciTech Connect

    Murray Gibson

    2009-06-03

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest x-ray beams in the Western Hemisphere, and the research carried out by scientists using those x-rays.

  16. Science at the Speed of Light: Advanced Photon Source

    ScienceCinema

    Murray Gibson

    2016-07-12

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest x-ray beams in the Western Hemisphere, and the research carried out by scientists using those x-rays.

  17. Ti foil light in the ATA (Advanced Test Accelerator) beam

    SciTech Connect

    Slaughter, D.R.; Chong, Y.P.; Goosman, D.R.; Rule, D.W.; Fiorito, R.B.

    1987-09-01

    An experiment is in progress to characterize the visible light produced when a Ti foil is immersed in the ATA 2 kA, 43 MeV beam. Results obtained to date indicate that the optical condition of the foil surface is a critical determinant of these characteristics, with a very narrow angular distribution obtained when a highly polished and flat foil is used. These data are consistent with the present hypothesis that the light is produced by transition radiation. Incomplete experiments to determine the foil angle dependence of the detected light and its polarization are summarized and remaining experiments are described.

  18. Evaluation of advanced light scattering technology for microgravity experiments

    NASA Technical Reports Server (NTRS)

    Fredericks, W. J.; Rosenblum, W. M.

    1990-01-01

    The capabilities of modern light scattering equipment and the uses it might have in studying processes in microgravity are evaluated. Emphasis is on the resolution of polydisperse systems. This choice was made since a major use of light scattering was expected to be the study of crystal growth of macromolecules in low gravity environments. An evaluation of a modern photon correlation spectrometer and a Mie spectrometer is presented.

  19. 77 FR 62270 - Proposed Revision Treatment of Non-Safety Systems for Passive Advanced Light Water Reactors

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-12

    ... Non-Safety Systems for Passive Advanced Light Water Reactors AGENCY: Nuclear Regulatory Commission... Systems (RTNSS) for Passive Advanced Light Water Reactors.'' The current SRP does not contain guidance on the proposed RTNSS for Passive Advance Light Water Reactors. DATES: Submit comments by November...

  20. 78 FR 41436 - Proposed Revision to Treatment of Non-Safety Systems for Passive Advanced Light Water Reactors

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-10

    ... COMMISSION Proposed Revision to Treatment of Non-Safety Systems for Passive Advanced Light Water Reactors... Treatment of Non-Safety Systems (RTNSS) for Passive Advanced Light Water Reactors.'' The NRC seeks public...- Safety Systems (RTNSS) for Passive Advanced Light Water Reactors.'' This area includes a revised...

  1. Advances in Coupling of Kinetics and Molecular Scale Tools to Shed Light on Soil Biogeochemical Processes

    SciTech Connect

    Sparks, Donald

    2014-09-02

    Biogeochemical processes in soils such as sorption, precipitation, and redox play critical roles in the cycling and fate of nutrients, metal(loid)s and organic chemicals in soil and water environments. Advanced analytical tools enable soil scientists to track these processes in real-time and at the molecular scale. Our review focuses on recent research that has employed state-of-the-art molecular scale spectroscopy, coupled with kinetics, to elucidate the mechanisms of nutrient and metal(loid) reactivity and speciation in soils. We found that by coupling kinetics with advanced molecular and nano-scale tools major advances have been made in elucidating important soil chemical processes including sorption, precipitation, dissolution, and redox of metal(loids) and nutrients. Such advances will aid in better predicting the fate and mobility of nutrients and contaminants in soils and water and enhance environmental and agricultural sustainability.

  2. Robust cladding light stripper for high-power fiber lasers using soft metals.

    PubMed

    Babazadeh, Amin; Nasirabad, Reza Rezaei; Norouzey, Ahmad; Hejaz, Kamran; Poozesh, Reza; Heidariazar, Amir; Golshan, Ali Hamedani; Roohforouz, Ali; Jafari, S Naser Tabatabaei; Lafouti, Majid

    2014-04-20

    In this paper we present a novel method to reliably strip the unwanted cladding light in high-power fiber lasers. Soft metals are utilized to fabricate a high-power cladding light stripper (CLS). The capability of indium (In), aluminum (Al), tin (Sn), and gold (Au) in extracting unwanted cladding light is examined. The experiments show that these metals have the right features for stripping the unwanted light out of the cladding. We also find that the metal-cladding contact area is of great importance because it determines the attenuation and the thermal load on the CLS. These metals are examined in different forms to optimize the contact area to have the highest possible attenuation and avoid localized heating. The results show that sheets of indium are very effective in stripping unwanted cladding light.

  3. Light

    NASA Astrophysics Data System (ADS)

    Vernon, C. G.

    2016-09-01

    Preface; 1. Historical; 2. Waves and wave-motion; 3. The behaviour of ripples; 4. The behaviour of light; 5. Refraction through glass blocks and prisms; 6. The imprinting of curvatures; 7. Simple mathematical treatment; 8. More advanced mathematical treatment; 9. The velocity of light; 10. The spectrum and colour; 11. Geometrical optics; 12. The eye and optical instruments; 13. Sources of light; 14. Interference, diffraction and polarisation; 15. Suggestions for class experiments; Index.

  4. Laser Light Scattering, from an Advanced Technology Development Program to Experiments in a Reduced Gravity Environment

    NASA Technical Reports Server (NTRS)

    Meyer, William V.; Tscharnuter, Walther W.; Macgregor, Andrew D.; Dautet, Henri; Deschamps, Pierre; Boucher, Francois; Zuh, Jixiang; Tin, Padetha; Rogers, Richard B.; Ansari, Rafat R.

    1994-01-01

    Recent advancements in laser light scattering hardware are described. These include intelligent single card correlators; active quench/active reset avalanche photodiodes; laser diodes; and fiber optics which were used by or developed for a NASA advanced technology development program. A space shuttle experiment which will employ aspects of these hardware developments is previewed.

  5. X-ray micro-Tomography at the Advanced Light Source

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The X-ray micro-Tomography Facility at the Advanced Light Source has been in operation since 2004. The source is a superconducting bend magnet of critical energy 10.5KeV; photon energy coverage is 8-45 KeV in monochromatic mode, and a filtered white light option yields useful photons up to 50 KeV. A...

  6. Light Scattering by Polymers: Two Experiments for Advanced Undergraduates.

    ERIC Educational Resources Information Center

    Matthews, G. P.

    1984-01-01

    Background information, procedures, equipment, and results for two experiments are presented. The first involves the measurement of the mass-average and degree of coiling of polystyrene and is interpreted by the full mathematical theory of light scattering. The second is the study of transitions in gelatin. (JN)

  7. Advances in Understanding How Heavy Metal Pollution Triggers Gastric Cancer.

    PubMed

    Yuan, Wenzhen; Yang, Ning; Li, Xiangkai

    2016-01-01

    With the development of industrialization and urbanization, heavy metals contamination has become a major environmental problem. Numerous investigations have revealed an association between heavy metal exposure and the incidence and mortality of gastric cancer. The mechanisms of heavy metals (lead, cadmium, mercury, chromium, and arsenic) contamination leading to gastric cancer are concluded in this review. There are four main potential mechanisms: (1) Heavy metals disrupt the gastric mucosal barrier by decreasing mucosal thickness, mucus content, and basal acid output, thereby affecting the function of E-cadherin and inducing reactive oxygen species (ROS) damage. (2) Heavy metals directly or indirectly induce ROS generation and cause gastric mucosal and DNA lesions, which subsequently alter gene regulation, signal transduction, and cell growth, ultimately leading to carcinogenesis. Exposure to heavy metals also enhances gastric cancer cell invasion and metastasis. (3) Heavy metals inhibit DNA damage repair or cause inefficient lesion repair. (4) Heavy metals may induce other gene abnormalities. In addition, heavy metals can induce the expression of proinflammatory chemokine interleukin-8 (IL-8) and microRNAs, which promotes tumorigenesis. The present review is an effort to underline the human health problem caused by heavy metal with recent development in order to garner a broader perspective.

  8. Advances in Understanding How Heavy Metal Pollution Triggers Gastric Cancer

    PubMed Central

    Yuan, Wenzhen; Yang, Ning

    2016-01-01

    With the development of industrialization and urbanization, heavy metals contamination has become a major environmental problem. Numerous investigations have revealed an association between heavy metal exposure and the incidence and mortality of gastric cancer. The mechanisms of heavy metals (lead, cadmium, mercury, chromium, and arsenic) contamination leading to gastric cancer are concluded in this review. There are four main potential mechanisms: (1) Heavy metals disrupt the gastric mucosal barrier by decreasing mucosal thickness, mucus content, and basal acid output, thereby affecting the function of E-cadherin and inducing reactive oxygen species (ROS) damage. (2) Heavy metals directly or indirectly induce ROS generation and cause gastric mucosal and DNA lesions, which subsequently alter gene regulation, signal transduction, and cell growth, ultimately leading to carcinogenesis. Exposure to heavy metals also enhances gastric cancer cell invasion and metastasis. (3) Heavy metals inhibit DNA damage repair or cause inefficient lesion repair. (4) Heavy metals may induce other gene abnormalities. In addition, heavy metals can induce the expression of proinflammatory chemokine interleukin-8 (IL-8) and microRNAs, which promotes tumorigenesis. The present review is an effort to underline the human health problem caused by heavy metal with recent development in order to garner a broader perspective. PMID:27803929

  9. Photoacoustic imaging of clinical metal needle by a LED light source integrated transducer

    NASA Astrophysics Data System (ADS)

    Agano, Toshitaka; Sato, Naoto; Nakatsuka, Hitoshi; Kitagawa, Kazuo; Hanaoka, Takamitsu; Morisono, Koji; Shigeta, Yusuke; Tanaka, Chizuyo

    2016-03-01

    We have achieved penetration depth of 30mm by photoacoustic imaging system using LED light source integrated transducer to image a clinical metal needle inserted into a tissue mimicking phantom. We developed the transducer that integrated near-infrared LED array light source, which was connected to a photoacoustic imaging system which drove LED array light source and controlled photoacoustic data acquisition process. Conventionally solid-state laser has been used as the light source for photoacoustic imaging system. Because LED is diffused light source, laser safety glasses is not necessary, also inflexible fibers are not used to guide light close to a transducer, and we integrated LED light source inside the transducer, which became compact and practical size for conventional ultrasound equipment users. We made LED light source unit as detachable to the transducer easily, so wave-length of light can be selectable by changing the LED light source unit.

  10. Ultraviolet Light Emitting Diode Use in Advanced Oxidation Processes

    DTIC Science & Technology

    2014-03-27

    assume both the power requirements and lifetimes of UV LEDs will improve rapidly in the coming decades. LEDs turn electrical energy into light energy ... energy consumption or limiting the time the LED is powered , but do not require the highest possible rate of contamination destruction. 20 This might...as they are durable; compact; can be powered by low voltage, direct current from solar cells or batteries; and do not contain other hazardous

  11. Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry

    SciTech Connect

    none,

    2005-11-01

    The study examines current and emerging melting technologies and discusses their technical barriers to scale-up issues and research needed to advance these technologies, improving melting efficiency, lowering metal transfer heat loss, and reducing scrap.

  12. Enhanced light-harvesting capability for silicon single-nanowire solar cells coupled with metallic cavity.

    PubMed

    Gai, Feng; Zhang, Cheng; Zhan, Yaohui; Li, Xiaofeng

    2016-12-26

    Single-nanowire solar cells (SNSCs) are attracting increasing interest due to their unique optical antenna effect beneficial for achieving higher light-trapping capability. However, for conventional circular-cross-sectional SNSCs, the light-trapping performance is still far from the expectation. Here we demonstrate that integrating a silicon single nanowire into a metallic slit can dramatically enhance the absorption efficiency over almost the whole spectral band due to strengthened optical antenna effect. Especially, it is found that by using finite-size metallic blocks to form a nanoscale metallic cavity, the light-trapping performance of the SNSCs can be further improved. Through examining the detailed optical spectral response, electric field distribution, and cavity dispersion characteristics, the metallic-coupled SNSC system is optimized and the underlying physics are provided. Simulation results indicate that the photocurrent density of the SNSCs coupled with the designed metallic cavity can be enhanced by 44.4% than that of the conventional bare SNSCs.

  13. Annual meeting of the Advanced Light Source Users` Association

    SciTech Connect

    1995-02-01

    This report contains papers on the following topics: ALS Director`s Report; ALS Operations Update; Recent Results in Machine Physics; Progress in Beamline Commissioning and Overview of New Projects; The ALS Scientific Program; First Results from the SpectroMicroscopy Beamline; Soft X-ray Fluorescence Spectroscopy of Solids; Soft X-Ray Fluorescence Spectroscopy of Molecules; Microstructures and Micromachining at the ALS; High-Resolution Photoemission from Simple Atoms and Molecules; X-Ray Diffraction at the ALS; Utilizing Synchrotron Radiation in Advanced Materials Industries; Polymer Microscopy: About Balls, Rocks and Other ``Stuff``; Infrared Research and Applications; and ALS User Program.

  14. Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

    PubMed Central

    Chen, Hongjun

    2014-01-01

    Summary To better utilize the sunlight for efficient solar energy conversion, the research on visible-light active photocatalysts has recently attracted a lot of interest. The photosensitization of transition metal oxides is a promising approach for achieving effective visible-light photocatalysis. This review article primarily discusses the recent progress in the realm of a variety of nanostructured photosensitizers such as quantum dots, plasmonic metal nanostructures, and carbon nanostructures for coupling with wide-bandgap transition metal oxides to design better visible-light active photocatalysts. The underlying mechanisms of the composite photocatalysts, e.g., the light-induced charge separation and the subsequent visible-light photocatalytic reaction processes in environmental remediation and solar fuel generation fields, are also introduced. A brief outlook on the nanostructure photosensitization is also given. PMID:24991507

  15. Strong Light Confinement in Metal-Coated Si Nanopillars: Interplay of Plasmonic Effects and Geometric Resonance.

    PubMed

    Kim, Sujung; Kim, Eunah; Lee, Yeon Ui; Ko, Eunkyo; Park, Hyeong-Ho; Wu, Jeong Weon; Kim, Dong-Wook

    2017-12-01

    We investigated the influence of metal coating on the optical characteristics of Si nanopillar (NP) arrays with and without thin metal layers coated on the sample surface. The reflection dips of the metal-coated arrays were much broader and more pronounced than those of the bare arrays. The coated metal layers consisted of two parts-the metal disks on the Si NP top and the holey metal backreflectors on the Si substrate. The Mie-like geometrical resonance in the NPs, the localized surface plasmons in the metal disks, and the propagation of surface plasmon polariton along the backreflector/substrate interface could contribute to the reflection spectra. Finite-difference time-domain simulation results showed that the interplay of the plasmonic effects and the geometric resonance gave rise to significantly enhanced light confinement and consequent local absorption in the metal-Si hybrid nanostructures.

  16. Strong Light Confinement in Metal-Coated Si Nanopillars: Interplay of Plasmonic Effects and Geometric Resonance

    NASA Astrophysics Data System (ADS)

    Kim, Sujung; Kim, Eunah; Lee, Yeon Ui; Ko, Eunkyo; Park, Hyeong-Ho; Wu, Jeong Weon; Kim, Dong-Wook

    2017-02-01

    We investigated the influence of metal coating on the optical characteristics of Si nanopillar (NP) arrays with and without thin metal layers coated on the sample surface. The reflection dips of the metal-coated arrays were much broader and more pronounced than those of the bare arrays. The coated metal layers consisted of two parts—the metal disks on the Si NP top and the holey metal backreflectors on the Si substrate. The Mie-like geometrical resonance in the NPs, the localized surface plasmons in the metal disks, and the propagation of surface plasmon polariton along the backreflector/substrate interface could contribute to the reflection spectra. Finite-difference time-domain simulation results showed that the interplay of the plasmonic effects and the geometric resonance gave rise to significantly enhanced light confinement and consequent local absorption in the metal-Si hybrid nanostructures.

  17. Direct Pathway to Molecular Photodissociation on Metal Surfaces Using Visible Light.

    PubMed

    Kazuma, Emiko; Jung, Jaehoon; Ueba, Hiromu; Trenary, Michael; Kim, Yousoo

    2017-03-01

    We demonstrate molecular photodissociation on single-crystalline metal substrates, driven by visible-light irradiation. The visible-light-induced photodissociation on metal substrates has long been thought to never occur, either because visible-light energy is much smaller than the optical energy gap between the frontier electronic states of the molecule or because the molecular excited states have short lifetimes due to the strong hybridization between the adsorbate molecular orbitals (MOs) and metal substrate. The S-S bond in dimethyl disulfide adsorbed on both Cu(111) and Ag(111) surfaces was dissociated through direct electronic excitation from the HOMO-derived MO (the nonbonding lone-pair type orbitals on the S atoms (nS)) to the LUMO-derived MO (the antibonding orbital localized on the S-S bond (σ*SS)) by irradiation with visible light. A combination of scanning tunneling microscopy and density functional theory calculations revealed that visible-light-induced photodissociation becomes possible due to the interfacial electronic structures constructed by the hybridization between molecular orbitals and the metal substrate states. The molecule-metal hybridization decreases the gap between the HOMO- and LUMO-derived MOs into the visible-light energy region and forms LUMO-derived MOs that have less overlap with the metal substrate, which results in longer excited-state lifetimes.

  18. Anomalous light absorption around subwavelength apertures in metal films.

    PubMed

    Lozan, O; Perrin, M; Ea-Kim, B; Rampnoux, J M; Dilhaire, S; Lalanne, P

    2014-05-16

    In this Letter, we study the heat dissipated at metal surfaces by the electromagnetic field scattered by isolated subwavelength apertures in metal screens. In contrast to the common belief that the intensity of waves created by local sources should decrease with the distance from the sources, we reveal that the dissipated heat at the surface remains constant over a broad spatial interval. This behavior that occurs for noble metals at near infrared wavelengths is observed with nonintrusive thermoreflectance measurements and is explained with an analytical model, which underlines the intricate role played by quasicylindrical waves in the phenomenon. Additionally, we show that, by monitoring the phase of the quasicylindrical waves, the total heat dissipated at the metal surface can be rendered substantially smaller than the heat dissipated by the launched plasmon. This interesting property offers an alternative to amplification for overcoming the loss issue in miniaturized plasmonic devices.

  19. Advances in metal-induced oxidative stress and human disease.

    PubMed

    Jomova, Klaudia; Valko, Marian

    2011-05-10

    Detailed studies in the past two decades have shown that redox active metals like iron (Fe), copper (Cu), chromium (Cr), cobalt (Co) and other metals undergo redox cycling reactions and possess the ability to produce reactive radicals such as superoxide anion radical and nitric oxide in biological systems. Disruption of metal ion homeostasis may lead to oxidative stress, a state where increased formation of reactive oxygen species (ROS) overwhelms body antioxidant protection and subsequently induces DNA damage, lipid peroxidation, protein modification and other effects, all symptomatic for numerous diseases, involving cancer, cardiovascular disease, diabetes, atherosclerosis, neurological disorders (Alzheimer's disease, Parkinson's disease), chronic inflammation and others. The underlying mechanism of action for all these metals involves formation of the superoxide radical, hydroxyl radical (mainly via Fenton reaction) and other ROS, finally producing mutagenic and carcinogenic malondialdehyde (MDA), 4-hydroxynonenal (HNE) and other exocyclic DNA adducts. On the other hand, the redox inactive metals, such as cadmium (Cd), arsenic (As) and lead (Pb) show their toxic effects via bonding to sulphydryl groups of proteins and depletion of glutathione. Interestingly, for arsenic an alternative mechanism of action based on the formation of hydrogen peroxide under physiological conditions has been proposed. A special position among metals is occupied by the redox inert metal zinc (Zn). Zn is an essential component of numerous proteins involved in the defense against oxidative stress. It has been shown, that depletion of Zn may enhance DNA damage via impairments of DNA repair mechanisms. In addition, Zn has an impact on the immune system and possesses neuroprotective properties. The mechanism of metal-induced formation of free radicals is tightly influenced by the action of cellular antioxidants. Many low-molecular weight antioxidants (ascorbic acid (vitamin C), alpha

  20. Evolutionary/advanced light water reactor data report

    SciTech Connect

    1996-02-09

    The US DOE Office of Fissile Material Disposition is examining options for placing fissile materials that were produced for fabrication of weapons, and now are deemed to be surplus, into a condition that is substantially irreversible and makes its use in weapons inherently more difficult. The principal fissile materials subject to this disposition activity are plutonium and uranium containing substantial fractions of plutonium-239 uranium-235. The data in this report, prepared as technical input to the fissile material disposition Programmatic Environmental Impact Statement (PEIS) deal only with the disposition of plutonium that contains well over 80% plutonium-239. In fact, the data were developed on the basis of weapon-grade plutonium which contains, typically, 93.6% plutonium-239 and 5.9% plutonium-240 as the principal isotopes. One of the options for disposition of weapon-grade plutonium being considered is the power reactor alternative. Plutonium would be fabricated into mixed oxide (MOX) fuel and fissioned (``burned``) in a reactor to produce electric power. The MOX fuel will contain dioxides of uranium and plutonium with less than 7% weapon-grade plutonium and uranium that has about 0.2% uranium-235. The disposition mission could, for example, be carried out in existing power reactors, of which there are over 100 in the United States. Alternatively, new LWRs could be constructed especially for disposition of plutonium. These would be of the latest US design(s) incorporating numerous design simplifications and safety enhancements. These ``evolutionary`` or ``advanced`` designs would offer not only technological advances, but also flexibility in siting and the option of either government or private (e.g., utility) ownership. The new reactor designs can accommodate somewhat higher plutonium throughputs. This data report deals solely with the ``evolutionary`` LWR alternative.

  1. Advanced Light Source report. Volume 7, No. 1

    SciTech Connect

    Not Available

    1994-09-01

    The exceptional science already emerging from the user program at the ALS shows that the promises of ``unique research opportunities`` and ``experiments not possible anywhere else`` made at the inception of the ALS are indeed coming true. In less than a year of beamline operations, the ALS has produced numerous high-quality results and achieved an enviable level of performance. Since the beginning of 1994, the ALS has operated for 92% of its scheduled hours, an outstanding achievement for a new machine. The ALS` ability to deliver the brightest light in the world in the ultraviolet and soft x-ray regions of the spectrum has attracted a who`s who of synchrotron research to the experiment floor. These users have produced a variety of scientifically significant results during the ALS` first year of operation, a few of which are highlighted in this article.

  2. Advanced technologies for decontamination and conversion of scrap metal

    SciTech Connect

    Muth, T.R.; Shasteen, K.E.; Liby, A.L.

    1995-10-01

    The Department of Energy (DOE) accumulated large quantities of radioactive scrap metal (RSM) through historic maintenance activities. The Decontamination and Decommissioning (D&D) of major sites formerly engaged in production of nuclear materials and manufacture of nuclear weapons will generate additional quantities of RSM, as much as 3 million tons of such metal according to a recent study. The recycling of RSM is quickly becoming appreciated as a key strategy in DOE`s cleanup of contaminated sites and facilities. The work described here has focused on recycle of the concentrated and high-value contaminated scrap metal resource that will arise from cleanup of DOE`s gaseous diffusion plants.

  3. Advanced chemical propulsion at NASA Lewis: Metallized and high energy density propellants

    NASA Technical Reports Server (NTRS)

    Palaszewski, Bryan A.

    1991-01-01

    Two of the programs at the NASA Lewis Research Center investigating advanced systems for future space missions are the Metallized Propellant Program and the Advanced Concepts Program. Each program includes both experimental and theoretical studies of future propellants and the associated vehicle impacts and significant payload benefits for many types of space transportation. These programs are described.

  4. Advanced Strategies for Outdoor LED Lighting Applications and Technologies to Curtail Regional Light Pollution Effects

    NASA Astrophysics Data System (ADS)

    Monrad, Christian Karl; Benya, James R.

    2015-08-01

    LED lighting systems for outdoor lighting applications continue to evolve as do strategies to mitigate related effects upon regional astronomical and ecological assets. The improving availability and relative lumen-per-watt efficiencies of blue-suppressed low correlated color temperature emitters, narrow band amber, phosphor converted amber, and various combinations of broadband emitters and sub-550NM and sub-500NM filters allow for a wide palette of choices to be assessed to suit site-specific and task-specific lighting needs. In addition to static spectral content options, readily available luminaire designs also include precise geometric beam shape selections and adaptive controls to include dimming, dynamic spectral shifting, motion detection, and dynamic beam shaping to minimize total environmental lumen emissions throughout the course of the nighttime hours.Regional and international light pollution mitigation regulations will also be briefly addressed in the context of luminaire shielding and spectral content control efforts to better protect human quality of life issues as well as astronomical and ecological interests.The presentation will include numerous spectral content graphs for various luminaire options as well as project-specific case studies to document comparisons of legacy lighting systems versus high-performance LED systems with regard to total lumen emissions, skyglow contributions, energy efficiency, and end-user satisfaction with the installed LED lighting systems. Physical samples of various luminaires will also be available for hands-on assessments.

  5. Broadband light absorption enhancement in polymer photovoltaics using metal nanowall gratings as transparent electrodes

    SciTech Connect

    Ye, Zhuo; Chaudhary, Sumit; Kuang, Ping; Ho, Kai-Ming

    2012-05-15

    The authors investigate light absorption in organic solar cells in which indium tin oxide (ITO) is replaced by a new metallic architecture (grating) as a transparent electrode. Different from typical metal nanowire gratings, our gratings consist of metal nanowalls with nanoscale footprint and (sub)microscale height [Adv. Mater. 23, 2469 (2011)], thus ensuring high optical transmittance and electrical conductivity. Simulations reveal that a broadband and polarization-insensitive light absorption enhancement is achieved via two mechanisms, when such silver nanowall gratings are employed in P3HT:PCBM based solar cells. Overall absorption enhanced by ~23% compared to a reference cell with ITO electrode.

  6. Recent advances in metal hydrides for clean energy applications

    SciTech Connect

    Ronnebro, Ewa; Majzoub, Eric H.

    2013-06-01

    Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

  7. Advanced technologies for decontamination and conversion of scrap metal

    SciTech Connect

    Muth, T.R.; Shasteen, K.E.; Liby, A.L.

    1995-12-01

    The Department of Energy (DOE) accumulated large quantities of radioactive scrap metal (RSM) through historic maintenance activities. The Decontamination and Decommissioning (D&D) of major sites formerly engaged in production of nuclear materials and manufacture of nuclear weapons will generate additional quantities of RSM, as much as 3 million tons of such metal according to a recent study. The recycling of RSM is quickly becoming appreciated as a key strategy in DOE`s cleanup of contaminated sites and facilities.

  8. Single-layer mirrors for advanced research light sources

    NASA Astrophysics Data System (ADS)

    Störmer, M.; Horstmann, C.; Siewert, F.; Scholze, F.; Krumrey, M.; Hertlein, F.; Matiaske, M.; Wiesmann, J.; Gaudin, J.

    2010-06-01

    X-ray mirrors are needed for beam guidance, beam alignment and monochromatisation at third-generation synchrotron light sources (PETRA III) and forthcoming Free-Electron Lasers (LCLS, European XFEL). Amorphous carbon coatings are currently used as total reflection mirrors at FLASH to guide the photon beam to the various beamlines. These coatings were prepared by means of magnetron sputtering. The new GKSS sputtering facility for the deposition of single and multilayer mirrors with a length of up to 1500 mm and a width of up to 120 mm is in operation. In this contribution we present the results of this new deposition system. A major advantage is that it is now possible to prepare one, two or more mirrors with similar properties over the whole deposition length. The mirror properties were investigated by means of X-ray reflectometry and interference microscopy. The performance of the mirrors is analyzed, considering X-ray reflectivity, film thickness and surface roughness. The uniformity of these properties over the whole deposition length of 1500 mm is demonstrated. The results obtained will be discussed and compared with former results.

  9. Single-layer mirrors for advanced research light sources

    SciTech Connect

    Stoermer, M.; Horstmann, C.; Siewert, F.; Hertlein, F.; Matiaske, M.; Wiesmann, J.; Gaudin, J.

    2010-06-23

    X-ray mirrors are needed for beam guidance, beam alignment and monochromatisation at third-generation synchrotron light sources (PETRA III) and forthcoming Free-Electron Lasers (LCLS, European XFEL). Amorphous carbon coatings are currently used as total reflection mirrors at FLASH to guide the photon beam to the various beamlines. These coatings were prepared by means of magnetron sputtering. The new GKSS sputtering facility for the deposition of single and multilayer mirrors with a length of up to 1500 mm and a width of up to 120 mm is in operation. In this contribution we present the results of this new deposition system. A major advantage is that it is now possible to prepare one, two or more mirrors with similar properties over the whole deposition length. The mirror properties were investigated by means of X-ray reflectometry and interference microscopy. The performance of the mirrors is analyzed, considering X-ray reflectivity, film thickness and surface roughness. The uniformity of these properties over the whole deposition length of 1500 mm is demonstrated. The results obtained will be discussed and compared with former results.

  10. Vacuum system for the LBL Advanced Light Source (ALS)

    SciTech Connect

    Kennedy, K.; Henderson, T.; Meneghetti, J. )

    1989-03-01

    A 1.5 to 1.9 GeV synchrotron light source is being built at LBL. The vacuum system is designed to permit most synchrotron photons to escape the electron channel and be absorbed in an antechamber. The gas generated by the photons hitting the absorbers in the antechambers will be pumped by titanium sublimation pumps located directly under the absorbers. The electron channel and the antechamber are connected by a 10-mm-high slot that offers good electrodynamic isolation of the two chambers of frequencies affecting the store electron orbit. Twelve 10-meter-long vessels constitute the vacuum chambers for all the lattice magnets. Each chamber will be machined from two thick plates of 5083-H321 aluminum and welded at the perimeter. Machining both the inside and outside of the vacuum chamber permits the use of complex and accurate surfaces. The use of thick plates allows flanges to be machined directly into the wall of each chamber, thus avoiding much welding. 1 ref., 3 figs.

  11. Meeting Summary Advanced Light Water Reactor Fuels Industry Meeting Washington DC October 27 - 28, 2011

    SciTech Connect

    Not Listed

    2011-11-01

    The Advanced LWR Fuel Working Group first met in November of 2010 with the objective of looking 20 years ahead to the role that advanced fuels could play in improving light water reactor technology, such as waste reduction and economics. When the group met again in March 2011, the Fukushima incident was still unfolding. After the March meeting, the focus of the program changed to determining what we could do in the near term to improve fuel accident tolerance. Any discussion of fuels with enhanced accident tolerance will likely need to consider an advanced light water reactor with enhanced accident tolerance, along with the fuel. The Advanced LWR Fuel Working Group met in Washington D.C. on October 72-18, 2011 to continue discussions on this important topic.

  12. Advanced light source at Lawrence Berkeley Laboratory (invited)

    NASA Astrophysics Data System (ADS)

    Cornacchia, M.

    1989-07-01

    The 1-2-GeV synchrotron radiation source will be a national user-based facility providing photon beams of unprecedented brightness in the ultraviolet and soft x-ray region of the electromagnetic spectrum. The facility design is optimized to emphasize the use of undulators to provide high-spectral brilliance in the few electron volt to 1-keV spectral range; wigglers provide high flux up to approximately 10 keV. Beam structure of a few tens of picoseconds will be available for time-resolved experiments. The facility is designed for operational flexibility and to assure rapid commissioning. The initial complement of experimental stations consists of five insertion devices (four undulators and our wiggler) and associated beamlines, and two white light beams from bend magnets. Six other straight sections are available for additional insertion devices, and the design provides for up to 48 ports for beams from bending magnets. The storage ring is optimized for operation at 1.5 GeV with a maximum energy of 1.9 GeV. The injection system includes a 1-Hz, 1.5-GeV booster synchrotron for full energy injection at the nominal operating energy of the storage ring. Filling time for the maximum stored current of 400 mA is expected to be 2 min, and the beam half-life will be about 6 h. Attention is being given to the severe requirements for beam stability and the need to independently control photon beam alignment. We describe the important characteristics of the facility, significant aspects of the technical design of accelerator systems, insertion devices and photon beamlines, and considerations related to addressing projected user needs in the development of the project.

  13. High-speed multilevel phase/amplitude spatial light modulator advances

    NASA Astrophysics Data System (ADS)

    Bauchert, Kipp A.; Serati, Steven A.

    1999-03-01

    Recent and near-term advancements in our multi-level (analog) phase/amplitude liquid crystal spatial light modulators will be presented. These advancements include higher resolution, smaller pixel pitch, planarized pixel pads, and higher speed modulation for phase-only, amplitude-only, and phase- amplitude-coupled modulation. These devices have applications in optical processing, optical storage, holographic display, and beam steering. Design criteria and experimental data will be presented.

  14. Theory for self-consistent interplay between light and nanomaterials strongly modified by metallic nanostructures.

    PubMed

    Ishikawa, Akira; Osono, Katsuya; Nobuhiro, Atsushi; Mizumoto, Yoshihiko; Torimoto, Tsukasa; Ishihara, Hajime

    2013-03-28

    The design of the interplay between light and nanomaterials by the effect of localized-surface-plasmon resonance in metallic nanostructures is a fascinating subject, and recently, a lot of research has been carried out from both fundamental and applicational points of view. In this paper, we demonstrate the theories for describing the self-consistent interplay between the electronic states in the nanomaterials, the localized surface plasmons in the metallic nanostructures, and the light field, which provides insight into how the photoexcitation processes are modified through microscopic energy exchanges. As examples of such demonstrations, we show two cases, i.e., the interaction between a single metallic nanosphere and a quantum dot, and that between metallic nanostructures forming a nanogap and dimer molecules, where a peculiar dependence of photoexcitation processes on the distance between the metallic nanostructure and the absorbers arises depending on the respective characteristics of their interplay.

  15. Light Water Reactor Sustainability Program Advanced Seismic Soil Structure Modeling

    SciTech Connect

    Bolisetti, Chandrakanth; Coleman, Justin Leigh

    2015-06-01

    of interest. The specific nonlinear soil behavior included in the NLSSI calculation presented in this report is gapping and sliding. Other NLSSI effects are not included in the calculation. The results presented in this report document initial model runs in the linear and nonlinear analysis process. Final comparisons between traditional and advanced SPRA will be presented in the September 30th deliverable.

  16. Advanced Epi Tools for Gallium Nitride Light Emitting Diode Devices

    SciTech Connect

    Patibandla, Nag; Agrawal, Vivek

    2012-12-01

    Over the course of this program, Applied Materials, Inc., with generous support from the United States Department of Energy, developed a world-class three chamber III-Nitride epi cluster tool for low-cost, high volume GaN growth for the solid state lighting industry. One of the major achievements of the program was to design, build, and demonstrate the world’s largest wafer capacity HVPE chamber suitable for repeatable high volume III-Nitride template and device manufacturing. Applied Materials’ experience in developing deposition chambers for the silicon chip industry over many decades resulted in many orders of magnitude reductions in the price of transistors. That experience and understanding was used in developing this GaN epi deposition tool. The multi-chamber approach, which continues to be unique in the ability of the each chamber to deposit a section of the full device structure, unlike other cluster tools, allows for extreme flexibility in the manufacturing process. This robust architecture is suitable for not just the LED industry, but GaN power devices as well, both horizontal and vertical designs. The new HVPE technology developed allows GaN to be grown at a rate unheard of with MOCVD, up to 20x the typical MOCVD rates of 3{micro}m per hour, with bulk crystal quality better than the highest-quality commercial GaN films grown by MOCVD at a much cheaper overall cost. This is a unique development as the HVPE process has been known for decades, but never successfully commercially developed for high volume manufacturing. This research shows the potential of the first commercial-grade HVPE chamber, an elusive goal for III-V researchers and those wanting to capitalize on the promise of HVPE. Additionally, in the course of this program, Applied Materials built two MOCVD chambers, in addition to the HVPE chamber, and a robot that moves wafers between them. The MOCVD chambers demonstrated industry-leading wavelength yield for GaN based LED wafers and industry

  17. Nano-photonic organic solar cell architecture for advanced light management utilizing dual photonic crystals

    NASA Astrophysics Data System (ADS)

    Peer, Akshit; Biswas, Rana

    2015-09-01

    Organic solar cells have rapidly increasing efficiencies, but typically absorb less than half of the incident solar spectrum. To increase broadband light absorption, we rigorously design experimentally realizable solar cell architectures based on dual photonic crystals. Our optimized architecture consists of a polymer microlens at the air-glass interface, coupled with a photonic-plasmonic crystal at the metal cathode. The microlens focuses light on the periodic nanostructure that generates strong light diffraction. Waveguiding modes and surface plasmon modes together enhance long wavelength absorption in P3HT-PCBM. The architecture has a period of 500 nm, with absorption and photocurrent enhancement of 49% and 58%, respectively.

  18. An Advanced Semimetal-Organic Bi Spheres-g-C3N4 Nanohybrid with SPR-Enhanced Visible-Light Photocatalytic Performance for NO Purification.

    PubMed

    Dong, Fan; Zhao, Zaiwang; Sun, Yanjuan; Zhang, Yuxin; Yan, Shuai; Wu, Zhongbiao

    2015-10-20

    To achieve efficient photocatalytic air purification, we constructed an advanced semimetal-organic Bi spheres-g-C3N4 nanohybrid through the in-situ growth of Bi nanospheres on g-C3N4 nanosheets. This Bi-g-C3N4 compound exhibited an exceptionally high and stable visible-light photocatalytic performance for NO removal due to the surface plasmon resonance (SPR) endowed by Bi metal. The SPR property of Bi could conspicuously enhance the visible-light harvesting and the charge separation. The electromagnetic field distribution of Bi spheres involving SPR effect was simulated and reaches its maximum in close proximity to the Bi particle surface. When the Bi metal content was controlled at 25%, the corresponding Bi-g-C3N4 displayed outstanding photocatalytic capability and transcended those of other visible-light photocatalysts. The Bi-g-C3N4 exhibited a high structural stability under repeated photocatalytic runs. A new visible-light-induced SPR-based photocatalysis mechanism with Bi-g-C3N4 was proposed on the basis of the DMPO-ESR spin-trapping. The photoinduced electrons could transfer from g-C3N4 to the Bi metal, as revealed with time-resolved fluorescence spectra. The function of Bi semimetal as a plasmonic cocatalyst for boosting visible light photocatalysis was similar to that of noble metals, which demonstrated a great potential of utilizing the economically feasible Bi element as a substitute for noble metals for the advancement of photocatalysis efficiency.

  19. Recent advances in metathesis-derived polymers containing transition metals in the side chain

    PubMed Central

    Demonceau, Albert; Fischer, Helmut

    2015-01-01

    Summary This account critically surveys the field of side-chain transition metal-containing polymers as prepared by controlled living ring-opening metathesis polymerization (ROMP) of the respective metal-incorporating monomers. Ferrocene- and other metallocene-modified polymers, macromolecules including metal-carbonyl complexes, polymers tethering early or late transition metal complexes, etc. are herein discussed. Recent advances in the design and syntheses reported mainly during the last three years are highlighted, with special emphasis on new trends for superior applications of these hybrid materials. PMID:26877797

  20. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    SciTech Connect

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; White, W. A.; Klebanoff, L. E.; Velinsky, S. A.

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 times better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.

  1. Surface protection of light metals by one-step laser cladding with oxide ceramics

    NASA Astrophysics Data System (ADS)

    Nowotny, S.; Richter, A.; Tangermann, K.

    1999-06-01

    Today, intricate problems of surface treatment can be solved through precision cladding using advanced laser technology. Metallic and carbide coatings have been produced with high-power lasers for years, and current investigations show that laser cladding is also a promising technique for the production of dense and precisely localized ceramic layers. In the present work, powders based on Al2O3 and ZrO2 were used to clad aluminum and titanium light alloys. The compact layers are up to 1 mm thick and show a nonporous cast structure as well as a homogeneous network of vertical cracks. The high adhesive strength is due to several chemical and mechanical bonding mechanisms and can exceed that of plasmasprayed coatings. Compared to thermal spray techniques, the material deposition is strictly focused onto small functional areas of the workpiece. Thus, being a precision technique, laser cladding is not recommended for large-area coatings. Examples of applications are turbine components and filigree parts of pump casings.

  2. NAN-190 potentiates the circadian response to light and speeds re-entrainment to advanced light cycles.

    PubMed

    Kessler, E J; Sprouse, J; Harrington, M E

    2008-07-17

    Health problems can arise from de-synchrony between the external environment and the endogenous circadian rhythm, yet the circadian system is not able to quickly adjust to large, abrupt changes in the external daily cycle. In this study, we investigated the ability of NAN-190 to potentiate the circadian rhythm response to light as measured by phase of behavioral activity rhythms. NAN-190 (5 mg/kg, i.p.) was able to significantly potentiate the response to light both in dark-adapted and entrained hamsters. Furthermore, NAN-190 was effective even when administered up to 6 h after light onset. Response to a light pulse was both greater in magnitude and involved fewer unstable transient cycles. Finally, NAN-190 was able to speed re-entrainment to a 6 h advance of the light/dark cycle by an average of 6 days when compared with vehicle-treated animals. This work suggests that compounds like NAN-190 may hold great potential as a pharmaceutical treatment for jetlag, shift work, and other circadian disorders.

  3. NAN-190 potentiates the circadian response to light and speeds re-entrainment to advanced light cycles

    PubMed Central

    Kessler, Eileen J; Sprouse, Jeffrey; Harrington, Mary E

    2008-01-01

    Health problems can arise from de-synchrony between the external environment and the endogenous circadian rhythm, yet the circadian system is not able to quickly adjust to large, abrupt changes in the external daily cycle. In this study, we investigated the ability of NAN-190 to potentiate the circadian rhythm response to light as measured by phase of behavioral activity rhythms. NAN-190 (5 mg/kg, i.p.) was able to significantly potentiate the response to light both in dark-adapted and entrained hamsters. Furthermore, NAN-190 was effective even when administered up to 6 hours after light onset. Response to a light pulse was both greater in magnitude and involved fewer unstable transient cycles. Finally, NAN-190 was able to speed re-entrainment to a 6 h advance of the light: dark cycle by an average of 6 days when compared to vehicle-treated animals. This work suggests that compounds like NAN-190 may hold great potential as a pharmaceutical treatment for jetlag, shift work, and other circadian disorders. PMID:18538936

  4. Control the polarization state of light with symmetry-broken metallic metastructures

    SciTech Connect

    Xiong, Xiang Jiang, Shang-Chi; Hu, Yuan-Sheng; Hu, Yu-Hui; Wang, Zheng-Han; Peng, Ru-Wen; Wang, Mu

    2015-07-15

    Controlling the polarization state, the transmission direction, the amplitude and the phase of light in a very limited space is essential for the development of on-chip photonics. Over the past decades, numerous sub-wavelength metallic microstructures have been proposed and fabricated to fulfill these demands. In this article, we review our efforts in achieving negative refractive index, controlling the polarization state, and tuning the amplitude of light with two-dimensional (2D) and three-dimensional (3D) microstructures. We designed an assembly of stacked metallic U-shaped resonators that allow achieving negative refraction for pure magnetic and electric responses respectively at the same frequency by selecting the polarization of incident light. Based on this, we tune the permittivity and permeability of the structure, and achieve negative refractive index. Further, by control the excitation and radiation of surface electric current on a number of 2D and 3D asymmetric metallic metastructures, we are able to control the polarization state of light. It is also demonstrated that with a stereostructured metal film, the whole metal surfaces can be used to construct either polarization-sensitive or polarization-insensitive prefect absorbers, with the advantage of efficient heat dissipation and electric conductivity. Our practice shows that metamaterials, including metasurface, indeed help to master light in nanoscale, and are promising in the development of new generation of photonics.

  5. Novel recycle technology for recovering rare metals (Ga, In) from waste light-emitting diodes.

    PubMed

    Zhan, Lu; Xia, Fafa; Ye, Qiuyu; Xiang, Xishu; Xie, Bing

    2015-12-15

    This work develops a novel process of recycling rare metals (Ga, In) from waste light-emitting diodes using the combination of pyrolysis, physical disaggregation methods and vacuum metallurgy separation. Firstly, the pure chips containing InGaN/GaN are adopted to study the vacuum separation behavior of rare metals, which aims to provide the theoretical foundation for recycling gallium and indium from waste light-emitting diodes. In order to extract the rare-metal-rich particles from waste light-emitting diodes, pyrolysis and physical disaggregation methods (crushing, screening, grinding and secondly screening) are studied respectively, and the operating parameters are optimized. With low boiling points and high saturation vapor pressures under vacuum, gallium and indium are separated from rare-metal-rich particles by the process of evaporation and condensation. By reference to the separating parameters of pure chips, gallium and indium in waste light-emitting diodes are recycled with the recovery efficiencies of 93.48% and 95.67% under the conditions as follows: heating temperature of 1373 K, vacuum pressure of 0.01-0.1 Pa, and holding time of 60 min. There are no secondary hazardous materials generated in the whole processes. This work provides an efficient and environmentally friendly process for recycling rare metals from waste light-emitting diodes.

  6. Switching Thin Films of Azobenzene-Containing Metal-Organic Frameworks with Visible Light.

    PubMed

    Müller, Kai; Knebel, Alexander; Zhao, Fangli; Bléger, David; Caro, Jürgen; Heinke, Lars

    2017-04-03

    Stimuli-responsive molecules change their properties when exposed to external signals, such as light, and enable the preparation of smart materials. UV light, which often destroys organic materials, is typically required for activating the desired response of photoswitchable compounds, significantly limiting the potential applications of light-operated smart materials. Herein, we present the first metal-organic framework (MOF), which enables reversible modulation of key properties upon irradiation with visible light only. The fluorinated azobenzene side groups in the MOF structure can be reversibly switched between the trans and cis state by green and violet light, avoiding UV light. It was demonstrated that the uptake of guest molecules by these MOF films can be switched in a fully remote-controlled way. The membrane separation of hydrogen/hydrocarbon mixtures was investigated. The light-induced changes of the MOF pore size result in the switching of the permeation and of the selection factor.

  7. ITO-free large-area organic light-emitting diodes with an integrated metal grid.

    PubMed

    Choi, Seungkeun; Kim, Sung-Jin; Fuentes-Hernandez, Canek; Kippelen, Bernard

    2011-07-04

    We report on ITO-free large-area organic light-emitting diodes (OLEDs) fabricated on glass substrates comprising α-NPD as a hole transport layer (HTL) and coevaporated CBP:Ir(ppy)(3) as the emission layer. Indium-tin-oxide (ITO) was replaced with a conductive polymer electrode and an electroplated thick metal grid was used to improve the homogeneity of the potential distribution over the transparent polymer electrode. An electrical model of a metal grid integrated OLED shows the benefits of the use of metal grids in terms of improving the uniformity of the light emitted as the area of the OLED increases as well as the conductivity of the transparent electrode decreases. By integrating metal grids with polymer electrodes, the luminance increases more than 24% at 6 V and 45% at 7 V compared to the polymer electrode devices without a metal grid. This implies that a lower voltage can be applied to achieve the same luminance, hence lowering the power consumption. Furthermore, metal grid integrated OLEDs exhibited less variation in light emission compared to devices without a metal grid.

  8. Azobenzenes as light-controlled molecular electronic switches in nanoscale metal-molecule-metal junctions.

    PubMed

    Mativetsky, Jeffrey M; Pace, Giuseppina; Elbing, Mark; Rampi, Maria A; Mayor, Marcel; Samorì, Paolo

    2008-07-23

    Conductance switching associated with the photoisomerization of azobenzene-based (Azo) molecules was observed in nanoscopic metal-molecule-metal junctions. The junctions were formed by using a conducting atomic force microscope (C-AFM) approach, where a metallic AFM tip was used to electrically contact a gold-supported Azo self-assembled monolayer. The measured 30-fold increase in conductance is consistent with the expected decrease in tunneling barrier length resulting from the conformational change of the Azo molecule.

  9. Advanced Light Source First-Phase Scientific Program, 1993/1994

    SciTech Connect

    Not Available

    1992-08-01

    This composite document outlines ten different experiments planned for the beamline at the Advanced Light Source. Researchers from various parts of the country have detailed their methods and equipment to be used in experiments in biology and physics. X-ray spectroscopy and microscopy are the common topics to these experiments. (GHH)

  10. Combination of Light and Melatonin Time Cues for Phase Advancing the Human Circadian Clock

    PubMed Central

    Burke, Tina M.; Markwald, Rachel R.; Chinoy, Evan D.; Snider, Jesse A.; Bessman, Sara C.; Jung, Christopher M.; Wright, Kenneth P.

    2013-01-01

    Study Objectives: Photic and non-photic stimuli have been shown to shift the phase of the human circadian clock. We examined how photic and non-photic time cues may be combined by the human circadian system by assessing the phase advancing effects of one evening dose of exogenous melatonin, alone and in combination with one session of morning bright light exposure. Design: Randomized placebo-controlled double-blind circadian protocol. The effects of four conditions, dim light (∼1.9 lux, ∼0.6 Watts/m2)-placebo, dim light-melatonin (5 mg), bright light (∼3000 lux, ∼7 Watts/m2)-placebo, and bright light-melatonin on circadian phase was assessed by the change in the salivary dim light melatonin onset (DLMO) prior to and following treatment under constant routine conditions. Melatonin or placebo was administered 5.75 h prior to habitual bedtime and 3 h of bright light exposure started 1 h prior to habitual wake time. Setting: Sleep and chronobiology laboratory environment free of time cues. Participants: Thirty-six healthy participants (18 females) aged 22 ± 4 y (mean ± SD). Results: Morning bright light combined with early evening exogenous melatonin induced a greater phase advance of the DLMO than either treatment alone. Bright light alone and melatonin alone induced similar phase advances. Conclusion: Information from light and melatonin appear to be combined by the human circadian clock. The ability to combine circadian time cues has important implications for understanding fundamental physiological principles of the human circadian timing system. Knowledge of such principles is important for designing effective countermeasures for phase-shifting the human circadian clock to adapt to jet lag, shift work, and for designing effective treatments for circadian sleep-wakefulness disorders. Citation: Burke TM; Markwald RR; Chinoy ED; Snider JA; Bessman SC; Jung CM; Wright Jr KP. Combination of light and melatonin time cues for phase advancing the human circadian

  11. Advanced analysis of metal distributions in human hair

    SciTech Connect

    Kempson, Ivan M.; Skinner, William M.

    2008-06-09

    A variety of techniques (secondary electron microscopy with energy dispersive X-ray analysis, time-of-flight-secondary ion mass spectrometry, and synchrotron X-ray fluorescence) were utilized to distinguish metal contamination occurring in hair arising from endogenous uptake from an individual exposed to a polluted environment, in this case a lead smelter. Evidence was sought for elements less affected by contamination and potentially indicative of biogenic activity. The unique combination of surface sensitivity, spatial resolution, and detection limits used here has provided new insight regarding hair analysis. Metals such as Ca, Fe, and Pb appeared to have little representative value of endogenous uptake and were mainly due to contamination. Cu and Zn, however, demonstrate behaviors worthy of further investigation into relating hair concentrations to endogenous function.

  12. Application of metallic nanoparticle suspensions in advanced cooling systems

    SciTech Connect

    Lee, S.; Choi, S.U.S.

    1996-12-31

    In the development of energy-efficient heat transfer fluids that are required in many cooling applications, low thermal conductivity is a primary limitation. However, it is well known that at room temperature, metals in solid form have orders-of-magnitude higher thermal conductivities than those of fluids. Therefore, the thermal conductivities of fluids that contain suspended solid metallic particles are expected to be significantly enhanced over those of conventional heat transfer fluids. In fact, numerous theoretical and experimental studies of the effective thermal conductivity of dispersions that contain solid particles have been conducted since Maxwell`s theoretical was published more than 100 years ago. However, all of the studies on thermal conductivity of suspensions have been confined to millimeter- or micrometer-sized particles.

  13. Bright morning light advances the human circadian system without affecting NREM sleep homeostasis.

    PubMed

    Dijk, D J; Beersma, D G; Daan, S; Lewy, A J

    1989-01-01

    Eight male subjects were exposed to either bright light or dim light between 0600 and 0900 h for 3 consecutive days each. Relative to the dim light condition, the bright light treatment advanced the evening rise in plasma melatonin and the time of sleep termination (sleep onset was held constant) for an average approximately 1 h. The magnitude of the advance of the plasma melatonin rise was dependent on its phase in dim light. The reduction in sleep duration was at the expense of rapid-eye-movement (REM) sleep. Spectral analysis of the sleep electroencephalogram (EEG) revealed that the advance of the circadian pacemaker did not affect EEG power densities between 0.25 and 15.0 Hz during either non-REM or REM sleep. The data show that shifting the human circadian pacemaker by 1 h does not affect non-REM sleep homeostasis. These findings are in accordance with the predictions of the two-process model of sleep regulation.

  14. Carbon formation and metal dusting in advanced coal gasification processes

    SciTech Connect

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  15. LATEST LASER AND LIGHT-BASED ADVANCES FOR ETHNIC SKIN REJUVENATION

    PubMed Central

    Elsaie, Mohamed Lotfy; Lloyd, Heather Woolery

    2008-01-01

    Background: Advances in nonablative skin rejuvenation technologies have sparked a renewed interest in the cosmetic treatment of aging skin. More options exist now than ever before to reverse cutaneous changes caused by long-term exposure to sunlight. Although Caucasian skin is more prone to ultraviolet light injury, ethnic skin (typically classified as types IV to VI) also exhibits characteristic photoaging changes. Widespread belief that inevitable or irreversible textural changes or dyspigmentation occurs following laser- or light-based treatments, has been challenged in recent years by new classes of devices capable of protecting the epidermis from injury during treatment. Objective: The purpose of this article is to review recent clinical advances in the treatment of photoaging changes in ethnic skin. This article provides a basis for the classification of current advances in nonablative management of ethnic skin. PMID:19881986

  16. Advanced technologies for decontamination and conversion of scrap metal

    SciTech Connect

    MacNair, V.; Muth, T.; Shasteen, K.; Liby, A.; Hradil, G.; Mishra, B.

    1996-12-31

    In October 1993, Manufacturing Sciences Corporation was awarded DOE contract DE-AC21-93MC30170 to develop and test recycling of radioactive scrap metal (RSM) to high value and intermediate and final product forms. This work was conducted to help solve the problems associated with decontamination and reuse of the diffusion plant barrier nickel and other radioactively contaminated scrap metals present in the diffusion plants. Options available for disposition of the nickel include decontamination and subsequent release or recycled product manufacture for restricted end use. Both of these options are evaluated during the course of this research effort. work during phase I of this project successfully demonstrated the ability to make stainless steel from barrier nickel feed. This paved the way for restricted end use products made from stainless steel. Also, after repeated trials and studies, the inducto-slag nickel decontamination process was eliminated as a suitable alternative. Electro-refining appeared to be a promising technology for decontamination of the diffusion plant barrier material. Goals for phase II included conducting experiments to facilitate the development of an electro-refining process to separate technetium from nickel. In parallel with those activities, phase II efforts were to include the development of the necessary processes to make useful products from radioactive scrap metal. Nickel from the diffusion plants as well as stainless steel and carbon steel could be used as feed material for these products.

  17. Advanced technologies for decontamination and conversion of scrap metals

    SciTech Connect

    Muth, T.R.; Moore, J.; Olson, D.; Mishra, B.

    1994-12-31

    Recycle of radioactive scrap metals (RSM) from decommissioning of DOE uranium enrichment and nuclear weapons manufacturing facilities is mandatory to recapture the value of these metals and avoid the high cost of disposal by burial. The scrap metals conversion project detailed below focuses on the contaminated nickel associated with the gaseous diffusion plants. Stainless steel can be produced in MSC`s vacuum induction melting process (VIM) to the S30400 specification using nickel as an alloy constituent. Further the case alloy can be rolled in MSC`s rolling mill to the mechanical property specification for S30400 demonstrating the capability to manufacture the contaminated nickel into valuable end products at a facility licensed to handle radioactive materials. Bulk removal of Technetium from scrap nickel is theoretically possible in a reasonable length of time with the high calcium fluoride flux, however the need for the high temperature creates a practical problem due to flux volatility. Bulk decontamination is possible and perhaps more desirable if nickel is alloyed with copper to lower the melting point of the alloy allowing the use of the high calcium fluoride flux. Slag decontamination processes have been suggested which have been proven technically viable at the Colorado School of Mines.

  18. Elliptical polarization of near-resonant linearly polarized probe light in optically pumped alkali metal vapor

    NASA Astrophysics Data System (ADS)

    Li, Yingying; Wang, Zhiguo; Jin, Shilong; Yuan, Jie; Luo, Hui

    2017-02-01

    Optically pumped alkali metal atoms currently provide a sensitive solution for magnetic microscopic measurements. As the most practicable plan, Faraday rotation of linearly polarized light is extensively used in spin polarization measurements of alkali metal atoms. In some cases, near-resonant Faraday rotation is applied to improve the sensitivity. However, the near-resonant linearly polarized probe light is elliptically polarized after passing through optically pumped alkali metal vapor. The ellipticity of transmitted near-resonant probe light is numerically calculated and experimentally measured. In addition, we also analyze the negative impact of elliptical polarization on Faraday rotation measurements. From our theoretical estimate and experimental results, the elliptical polarization forms an inevitable error in spin polarization measurements.

  19. Elliptical polarization of near-resonant linearly polarized probe light in optically pumped alkali metal vapor

    PubMed Central

    Li, Yingying; Wang, Zhiguo; Jin, Shilong; Yuan, Jie; Luo, Hui

    2017-01-01

    Optically pumped alkali metal atoms currently provide a sensitive solution for magnetic microscopic measurements. As the most practicable plan, Faraday rotation of linearly polarized light is extensively used in spin polarization measurements of alkali metal atoms. In some cases, near-resonant Faraday rotation is applied to improve the sensitivity. However, the near-resonant linearly polarized probe light is elliptically polarized after passing through optically pumped alkali metal vapor. The ellipticity of transmitted near-resonant probe light is numerically calculated and experimentally measured. In addition, we also analyze the negative impact of elliptical polarization on Faraday rotation measurements. From our theoretical estimate and experimental results, the elliptical polarization forms an inevitable error in spin polarization measurements. PMID:28216649

  20. Interaction of light with a metal wedge: the role of diffraction in shaping energy flow.

    PubMed

    Xi, Yonggang; Jung, Yun Suk; Kim, Hong Koo

    2010-02-01

    When a light wave hits a metal wedge structure, the metal surfaces respond to the incident light by generating both free-space and surface-bound waves. Here we present a physical model that elucidates electromagnetic interactions of an incoming planar wave with a simple semi-infinite 90 degrees metal wedge. We show that a metal wedge structure possesses an intrinsic capability of directing the incident power around the corner into the forward direction. Interplay of the boundary diffraction wave and the incident and reflection waves in the near field region of a metal corner is found to form a basis of the funneling phenomena that are commonly observed in metal nanoslit structures. Theory and experiment reveal that the incident wave propagating parallel to the sidewall destructively interferes with the boundary diffraction wave forming a depleted-energy-flow region along the glancing angle direction. A physical understanding of various electromagnetic phenomena associated with a metal wedge structure confirms rich potential of the simple structure as an elemental building block of complex metal nanostructures.

  1. Extraordinary Light-Induced Local Angular Momentum near Metallic Nanoparticles.

    PubMed

    Alabastri, Alessandro; Yang, Xiao; Manjavacas, Alejandro; Everitt, Henry O; Nordlander, Peter

    2016-04-26

    The intense local field induced near metallic nanostructures provides strong enhancements for surface-enhanced spectroscopies, a major focus of plasmonics research over the past decade. Here we consider that plasmonic nanoparticles can also induce remarkably large electromagnetic field gradients near their surfaces. Sizeable field gradients can excite dipole-forbidden transitions in nearby atoms or molecules and provide unique spectroscopic fingerprinting for chemical and bimolecular sensing. Specifically, we investigate how the local field gradients near metallic nanostructures depend on geometry, polarization, and wavelength. We introduce the concept of the local angular momentum (LAM) vector as a useful figure of merit for the design of nanostructures that provide large field gradients. This quantity, based on integrated fields rather than field gradients, is particularly well-suited for optimization using numerical grid-based full wave electromagnetic simulations. The LAM vector has a more compact structure than the gradient matrix and can be straightforwardly associated with the angular momentum of the electromagnetic field incident on the plasmonic structures.

  2. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect

    Musich, Mark; Swanson, Michael; Dunham, Grant; Stanislowski, Joshua

    2010-10-05

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-μg/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-μg/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most

  3. ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS

    SciTech Connect

    Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski

    2010-07-31

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-μg/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-μg/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine

  4. Light scattering by surface acoustic waves on corrugated metal surfaces

    SciTech Connect

    Robertson, W.M.; Grimsditch, M. ); Moretti, A.L.; Kaufman, R.G.; Hulse, G.R. ); Fullerton, E.; Schuller, I.K. )

    1990-03-15

    We report the results of a Brillouin-scattering study of corrugated Ag surfaces. The corrugation plays a dramatic role in the wave-vector--selection rules governing coupling to surface phonons, and this effect is substantially different when the effective wave vector of the surface corrugation is collinear or perpendicular to the scattering plane. In processes that involve the grating wave vector, we show that the coupling mechanism between light and phonons is governed by surface plasmons which introduce a new scattering interaction with unusual polarization features in the Brillouin-scattering process.

  5. Metal-nitride-oxide-semiconductor light-emitting devices for general lighting.

    PubMed

    Berencén, Y; Carreras, Josep; Jambois, O; Ramírez, J M; Rodríguez, J A; Domínguez, C; Hunt, Charles E; Garrido, B

    2011-05-09

    The potential for application of silicon nitride-based light sources to general lighting is reported. The mechanism of current injection and transport in silicon nitride layers and silicon oxide tunnel layers is determined by electro-optical characterization of both bi- and tri-layers. It is shown that red luminescence is due to bipolar injection by direct tunneling, whereas Poole-Frenkel ionization is responsible for blue-green emission. The emission appears warm white to the eye, and the technology has potential for large-area lighting devices. A photometric study, including color rendering, color quality and luminous efficacy of radiation, measured under various AC excitation conditions, is given for a spectrum deemed promising for lighting. A correlated color temperature of 4800K was obtained using a 35% duty cycle of the AC excitation signal. Under these conditions, values for general color rendering index of 93 and luminous efficacy of radiation of 112 lm/W are demonstrated. This proof of concept demonstrates that mature silicon technology, which is extendable to low-cost, large-area lamps, can be used for general lighting purposes. Once the external quantum efficiency is improved to exceed 10%, this technique could be competitive with other energy-efficient solid-state lighting options.

  6. Asymmetric transport of light in linearly arrayed metallic nano-particles

    NASA Astrophysics Data System (ADS)

    Horchani, R.

    2016-02-01

    A strong asymmetric light transport in a linear chain of spherical and equidistantly spaced silver metal nano-particles (MNPs) located near a substrate is reported. The contrast ratio of the proposed structure is above 0.95. We have studied the propagation of light in the array with respect to the metal and the size of the last nano-particle of the chain and the nature of the substrate. It is shown also that the presence of a copper or gold substrate enhance the guiding properties of the array. This structure opens the possibility to design various optical devices such as broadband antennae and optical diodes.

  7. Asymmetric transport of light in linearly arrayed metallic nano-particles

    NASA Astrophysics Data System (ADS)

    Aroua, W.; Horchani, R.; AbdelMalek, F.; Haxha, S.; Kamli, Ali A.

    2016-09-01

    A strong asymmetric light transport in a linear chain of spherical and equidistantly spaced silver metal nano-particles (MNPs) located near a substrate is reported. The contrast ratio of the proposed structure is above 0.95. We have studied the propagation of light in the array with respect to the metal and the size of the last nano-particle of the chain and the nature of the substrate. It is shown also that the presence of a copper or gold substrate enhance the guiding properties of the array. This structure opens the possibility to design various optical devices such as broadband antennae and optical diodes.

  8. Image processing of metal surface with structured light

    NASA Astrophysics Data System (ADS)

    Luo, Cong; Feng, Chang; Wang, Congzheng

    2014-09-01

    In structured light vision measurement system, the ideal image of structured light strip, in addition to black background , contains only the gray information of the position of the stripe. However, the actual image contains image noise, complex background and so on, which does not belong to the stripe, and it will cause interference to useful information. To extract the stripe center of mental surface accurately, a new processing method was presented. Through adaptive median filtering, the noise can be preliminary removed, and the noise which introduced by CCD camera and measured environment can be further removed with difference image method. To highlight fine details and enhance the blurred regions between the stripe and noise, the sharping algorithm is used which combine the best features of Laplacian operator and Sobel operator. Morphological opening operation and closing operation are used to compensate the loss of information.Experimental results show that this method is effective in the image processing, not only to restrain the information but also heighten contrast. It is beneficial for the following processing.

  9. Advanced refractory metals and composites for extraterrestrial power systems

    NASA Technical Reports Server (NTRS)

    Titran, R. H.; Grobstein, Toni L.

    1990-01-01

    Concepts for future space power systems include nuclear and focused solar heat sources coupled to static and dynamic power-conversion devices; such systems must be designed for service lives as long as 30 years, despite service temperatures of the order of 1600 K. Materials are a critical technology-development factor in such aspects of these systems as reactor fuel containment, environmental protection, power management, and thermal management. Attention is given to the prospective performance of such refractory metals as Nb, W, and Mo alloys, W fiber-reinforced Nb-matrix composites, and HfC precipitate-strengthened W-Re alloys.

  10. Shielded Metal Arc Welding Consumables for Advanced High Strength Steels

    DTIC Science & Technology

    1992-02-01

    100 ksi) depends on the availability of adequate welding consumables. In the case of shielded metal arc welding, the electrodes must provide...associated with the potassium silicate binder (K2 SiO3 .nH2 0). The fluxes were then crushed and sized to 14# Tyler mesh (1.7 mm screen aperture) to...determined that the hydrated potassium silicate binder (K2 SiO3 .nH20) used in this investi- gation was 50 wt. pct. potassium silicate (K 2SiO 3 ) and

  11. Simultaneous generation and focus of radially polarized light with metal-dielectric grating metasurface

    NASA Astrophysics Data System (ADS)

    Luo, Jun; Zhang, Zuojun; Song, Maowen; He, Anguo; Yu, Honglin

    2017-01-01

    Simultaneous manipulation of light polarization and phase possesses great significance for modern optical technologies. Here we propose metal-dielectric gratings capable of tailoring the polarization and phase of light based on polarization filtering with the polarization extinction ratio exceeding 10 dB and the transmittance higher than 65%. The standard radially polarized (RP) light with axially symmetric polarization distribution can be generated by using arrayed grating with gradient phase under the illumination of circularly polarized (CP) light. Besides, a RP metasurface lens with high numerical aperture is presented, which can convert the CP light into the focused radially polarized light at wavelength of 632.8 nm. This compact and efficient approach would have potential applications in beam manipulation, super-resolution imaging and integrated optics system.

  12. Dual catalysis sees the light: combining photoredox with organo-, acid, and transition-metal catalysis.

    PubMed

    Hopkinson, Matthew N; Sahoo, Basudev; Li, Jun-Long; Glorius, Frank

    2014-04-01

    The photoredox activation of organic substrates with visible light is a powerful methodology that generates reactive radical species under very mild conditions. When combined with another catalytic process in a dual catalytic system, novel, visible-light-promoted transformations have been realized that do not proceed using either catalyst in isolation. In this minireview, the state of the art in organic reactions mediated by dual catalytic systems merging photoredox activation with organo-, acid or metal catalysis is discussed.

  13. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect

    Alvin, M.A.

    2002-09-19

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  14. Light-Induced In Situ Transformation of Metal Clusters to Metal Nanocrystals for Photocatalysis.

    PubMed

    Xiao, Fang-Xing; Zeng, Zhiping; Hsu, Shao-Hui; Hung, Sung-Fu; Chen, Hao Ming; Liu, Bin

    2015-12-30

    In situ transformation of glutathione-capped gold (Aux) clusters to gold (Au) nanocrystals under simulated solar light irradiation was achieved and utilized as a facile synthetic approach to rationally fabricate Aux/Au/TiO2 ternary and Au/TiO2 binary heterostructures. Synergistic interaction of Aux clusters and Au nanocrystals contributes to enhanced visible-light-driven photocatalysis.

  15. Extremely tight focusing of light at the nanoapex of a metal microtip

    SciTech Connect

    Petrin, A B

    2016-02-28

    We study the focusing of an optical electromagnetic wave into a nanoscale spatial region in the vicinity of the nanoapex of a metal microtip, arising due to a convergent surface plasmon wave. The metal boundary near the nanoapex is approximated by a paraboloid of revolution. It is proved that an increase in the metal absorption in approaching the nanoapex, associated with an increase in the frequency of collisions of electrons with the surface, is an essential but not limiting factor for this method of light nanofocusing. It is shown that the minimum possible size of the focusing region can be about of 1 nm. (nanooptics)

  16. Light-induced structural phase behaviour of metal nanoparticle materials

    NASA Astrophysics Data System (ADS)

    Plech, A.; Kotaidis, V.; Wulff, M.; Dahmen, C.; von Plessen, G.

    2005-01-01

    We have investigated the structural dynamics of gold nanoparticles induced by femtosecond light excitation. Structure evolution in both embedded particles (glass matrix or liquid water suspension) and quasi-free particles adsorbed on a solid surface is analyzed. By use of stroboscopic laser pump- x-ray probe techniques the structural relaxations have been resolved on the 100 ps time scale at the European Synchrotron Radiation Facility. Several methods including powder scattering, liquid scattering and small angle scattering serve to resolve microscopic and mesoscopic length scales of the composite system. The thermal response includes the heating, lattice melting, explosive solvent evaporation and solvent cooling subsequent to the laser flash excitation. Nonthermal effects are observed with femtosecond excitation. They are attributed to ablation from the particle and particle explosion at strong nonequilibrium conditions. The observations can form a complete picture of the energy dissipation and phase transitions involved in nanoscale composites.

  17. Advanced methods for light trapping in optically thin silicon solar cells

    NASA Astrophysics Data System (ADS)

    Nagel, James Richard

    2011-12-01

    The field of light trapping is the study of how best to absorb light in a thin film of material when most light either reflects away at the surface or transmits straight through to the other side. This has tremendous application to the field of photovoltaics where thin silicon films can be manufactured cheaply, but also fail to capture all of the available photons in the solar spectrum. Advancements in light trapping therefore bring us closer to the day when photovoltaic devices may reach grid parity with traditional fossil fuels on the electrical energy market. This dissertation advances our understanding of light trapping by first modeling the effects of loss in planar dielectric waveguides. The mathematical framework developed here can be used to model any arbitrary three-layer structure with mixed gain or loss and then extract the total field solution for the guided modes. It is found that lossy waveguides possess a greater number of eigenmodes than their lossless counterparts, and that these "loss guided" modes attenuate much more rapidly than conventional modes. Another contribution from this dissertation is the exploration of light trapping through the use of dielectric nanospheres embedded directly within the active layer of a thin silicon film. The primary benefit to this approach is that the device can utilize a surface nitride layer serving as an antireflective coating while still retaining the benefits of light trapping within the film. The end result is that light trapping and light injection are effectively decoupled from each other and may be independently optimized within a single photovoltaic device. The final contribution from this work is a direct numerical comparison between multiple light trapping schemes. This allows us to quantify the relative performances of various design techniques against one another and objectively determine which ideas tend to capture the most light. Using numerical simulation, this work directly compares the absorption

  18. Modeling light-induced charge transfer dynamics across a metal-molecule-metal junction: bridging classical electrodynamics and quantum dynamics.

    PubMed

    Hu, Zixuan; Ratner, Mark A; Seideman, Tamar

    2014-12-14

    We develop a numerical approach for simulating light-induced charge transport dynamics across a metal-molecule-metal conductance junction. The finite-difference time-domain method is used to simulate the plasmonic response of the metal structures. The Huygens subgridding technique, as adapted to Lorentz media, is used to bridge the vastly disparate length scales of the plasmonic metal electrodes and the molecular system, maintaining accuracy. The charge and current densities calculated with classical electrodynamics are transformed to an electronic wavefunction, which is then propagated through the molecular linker via the Heisenberg equations of motion. We focus mainly on development of the theory and exemplify our approach by a numerical illustration of a simple system consisting of two silver cylinders bridged by a three-site molecular linker. The electronic subsystem exhibits fascinating light driven dynamics, wherein the charge density oscillates at the driving optical frequency, exhibiting also the natural system timescales, and a resonance phenomenon leads to strong conductance enhancement.

  19. Modeling light-induced charge transfer dynamics across a metal-molecule-metal junction: Bridging classical electrodynamics and quantum dynamics

    SciTech Connect

    Hu, Zixuan; Ratner, Mark A.; Seideman, Tamar

    2014-12-14

    We develop a numerical approach for simulating light-induced charge transport dynamics across a metal-molecule-metal conductance junction. The finite-difference time-domain method is used to simulate the plasmonic response of the metal structures. The Huygens subgridding technique, as adapted to Lorentz media, is used to bridge the vastly disparate length scales of the plasmonic metal electrodes and the molecular system, maintaining accuracy. The charge and current densities calculated with classical electrodynamics are transformed to an electronic wavefunction, which is then propagated through the molecular linker via the Heisenberg equations of motion. We focus mainly on development of the theory and exemplify our approach by a numerical illustration of a simple system consisting of two silver cylinders bridged by a three-site molecular linker. The electronic subsystem exhibits fascinating light driven dynamics, wherein the charge density oscillates at the driving optical frequency, exhibiting also the natural system timescales, and a resonance phenomenon leads to strong conductance enhancement.

  20. Analytical and experimental evaluation of joining silicon nitride to metal and silicon carbide to metal for advanced heat engine applications

    SciTech Connect

    Kang, S.; Selverian, J.H.; Kim, H.; O'Niel, D.; Kim, K. )

    1990-04-01

    This report summarizes the results of Phase I of Analytical and Experimental Evaluation of Joining Silicon Nitride to Metal and Silicon Carbide to Metal and Silicon Carbide to Metal for Advanced Heat Engine Applications. A general methodology was developed to optimize the joint geometry and material systems for 650 and 950{degree}C applications. Failure criteria were derived to predict the fracture of the braze and ceramic. Extensive finite element analyses (FEA), using ABAQUS code, were performed to examine various joint geometries and to evaluate the affect of different interlayers on the residual stress state. Also, material systems composed of coating materials, interlayers, and braze alloys were developed for the program based on the chemical stability and strength of the joints during processing and service. Finally, the FEA results were compared with experiments using an idealized strength relationship. The results showed that the measured strength of the joint reached 30--90% of the strength by predicted by FEA. Overall results demonstrated that FEA is an effective tool for designing the geometries of ceramic-metal joints and that joining by brazing is a relevant method for advanced heat engine applications. 33 refs., 54 figs., 36 tabs.

  1. Closeout of Advanced Boron and Metal Loaded High Porosity Carbons.

    SciTech Connect

    Peter C. Eklund; T. C. Mike Chung; Henry C. Foley; Vincent H. Crespi

    2011-05-01

    The Penn State effort explored the development of new high-surface-area materials for hydrogen storage, materials that could offer enhancement in the hydrogen binding energy through a direct chemical modification of the framework in high specific-surface-area platforms. The team chemically substituted boron into the hexagonal sp2 carbon framework, dispersed metal atoms bound to the boro-carbon structure, and generated the theory of novel nanoscale geometries that can enhance storage through chemical frustration, sheet curvature, electron deficiency, large local fields and mixed hybridization states. New boro-carbon materials were synthesized by high temperature plasma, pyrolysis of boron-carbon precursor molecules, and post-synthesis modification of carbons. Hydrogen uptake has been assessed, and several promising leads have been identified, with the requirement to simultaneously optimize total surface area while maintaining the enhanced hydrogen binding energies already demonstrated.

  2. [Heavy metal pollution ecology of macro-fungi: research advances and expectation].

    PubMed

    Zhou, Qi-xing; An, Xin-long; Wei, Shu-he

    2008-08-01

    Macro-fungi are the main component of biosphere and one of the ecological resources, and play very important roles in matter cycling and in maintaining ecological balances. This paper summarized and reviewed the research advances in the eco-toxicological effects of heavy metals on macro-fungi, the bioaccumulation function of macro-fungi on heavy metals, the ecological adaptation mechanisms of macro-fungi to heavy metal pollution, the role of macro-fungi as a bio-indicator of heavy metal pollution, and the potential of macro-fungi in the ecological remediation of contaminated environment. To strengthen the researches on the heavy metal pollution ecology of macro-fungi would be of practical significance in the reasonable utilization of macro-fungi resources and in the ecological remediation of contaminated environment.

  3. Development of Advanced High Uranium Density Fuels for Light Water Reactors

    SciTech Connect

    Blanchard, James; Butt, Darryl; Meyer, Mitchell; Xu, Peng

    2016-02-15

    This work conducts basic materials research (fabrication, radiation resistance, thermal conductivity, and corrosion response) on U3Si2 and UN, two high uranium density fuel forms that have a high potential for success as advanced light water reactor (LWR) fuels. The outcome of this proposed work will serve as the basis for the development of advance LWR fuels, and utilization of such fuel forms can lead to the optimization of the fuel performance related plant operating limits such as power density, power ramp rate and cycle length.

  4. Effect of plasmonic losses on light emission enhancement in quantum-wells coupled to metallic gratings

    NASA Astrophysics Data System (ADS)

    Sadi, Toufik; Oksanen, Jani; Tulkki, Jukka

    2013-12-01

    Recent experimental work has shown significant luminescence enhancement from near-surface quantum-well (QW) structures using metallic grating to convert surface plasmon (SP) modes into radiative modes. This work introduces a detailed theoretical study of plasmonic losses and the role of SPs in improving light extraction from grated light-emitting QW structures, using the fluctuational electrodynamics method. The method explains experimental results demonstrating emission enhancement, light scattering, and plasmonic coupling in the structures. We study these effects in angle-resolved reflectometry and luminescence setups in InGaN QW structures with silver grating. In contrast to experiments, our model allows direct calculation of the optical losses. The model predicts that the plasmonic coupling and scattering increases light emission by a factor of up to three compared to a flat semiconductor structure. This corresponds to reducing the absorption losses from approximately 93% in the ungrated metallic structure to 75% in the grated structure. Lower losses are associated with a significant emission enhancement enabled by the SPs of silver/GaN interfaces, which are present in the blue/green wavelength range, and can be optimized by carefully nanostructuring the metal layer and by the positioning of the QW. In general, the enhancement results from the interplay of mode scattering, conversion of SP energy directly into light, and losses in the metallic grating. The reported losses are very high when compared to the losses present in modern light-emitting diodes (LEDs). Albeit, our work provides tools needed for further optimization of plasmonic light extraction, eventually leading to highly efficient LEDs.

  5. Effect of plasmonic losses on light emission enhancement in quantum-wells coupled to metallic gratings

    SciTech Connect

    Sadi, Toufik; Oksanen, Jani; Tulkki, Jukka

    2013-12-14

    Recent experimental work has shown significant luminescence enhancement from near-surface quantum-well (QW) structures using metallic grating to convert surface plasmon (SP) modes into radiative modes. This work introduces a detailed theoretical study of plasmonic losses and the role of SPs in improving light extraction from grated light-emitting QW structures, using the fluctuational electrodynamics method. The method explains experimental results demonstrating emission enhancement, light scattering, and plasmonic coupling in the structures. We study these effects in angle-resolved reflectometry and luminescence setups in InGaN QW structures with silver grating. In contrast to experiments, our model allows direct calculation of the optical losses. The model predicts that the plasmonic coupling and scattering increases light emission by a factor of up to three compared to a flat semiconductor structure. This corresponds to reducing the absorption losses from approximately 93% in the ungrated metallic structure to 75% in the grated structure. Lower losses are associated with a significant emission enhancement enabled by the SPs of silver/GaN interfaces, which are present in the blue/green wavelength range, and can be optimized by carefully nanostructuring the metal layer and by the positioning of the QW. In general, the enhancement results from the interplay of mode scattering, conversion of SP energy directly into light, and losses in the metallic grating. The reported losses are very high when compared to the losses present in modern light-emitting diodes (LEDs). Albeit, our work provides tools needed for further optimization of plasmonic light extraction, eventually leading to highly efficient LEDs.

  6. High-resolution VUV spectroscopy: New results from the Advanced Light Source

    SciTech Connect

    Schlachter, F.; Bozek, J.

    1996-06-01

    Third-generation synchrotron light sources are providing photon beams of unprecedented brightness for researchers in atomic and molecular physics. Beamline 9.0.1, an undulator beamline at the Advanced Light Source (ALS), produces a beam in the vacuum-ultraviolet (VUV) region of the spectrum with exceptional flux and spectral resolution. Exciting new results from experiments in atomic and molecular VUV spectroscopy of doubly excited autoionizing states of helium, hollow lithium, and photoelectron spectroscopy of small molecules using Beamline 9.0.1 at the ALS are reported.

  7. On the origin of third harmonic light from hybrid metal-dielectric nanoantennas

    NASA Astrophysics Data System (ADS)

    de Ceglia, Domenico; Vincenti, Maria Antonietta; Scalora, Michael

    2016-11-01

    Near field amplification of electric fields magnifies the nonlinear optical signals generated in the metal volume of plasmonic nanoantennas, as well as in the surrounding media. We investigate the third harmonic light emitted by a hybrid nanoantenna composed of two metallic rods separated by a small gap filled with a dielectric. Despite the large cubic nonlinear susceptibility of metals, the presence of a hot spot in the antenna’s gap may easily transform weaker dielectric nonlinearities into the dominant source of third harmonic light. This has led to diverse and sometimes opposite interpretations of the nature of the nonlinear response, which are further complicated by the limited knowledge of the intrinsic nonlinear susceptibilities of the constituent materials. Here, a quantitative description of third harmonic generation is provided as a function of the ratio between the dielectric and the metal nonlinear susceptibilities in a hybrid metal-dielectric nanoantenna. We find a spectral discriminator that allows us to determine the origin of third harmonic light unambiguously.

  8. Transition metal-modified zinc oxides for UV and visible light photocatalysis.

    PubMed

    Bloh, J Z; Dillert, R; Bahnemann, D W

    2012-11-01

    In order to use photocatalysis with solar light, finding more active and especially visible light active photocatalysts is a very important challenge. Also, studies of these photocatalysts should employ a standardized test procedure so that their results can be accurately compared and evaluated with one another. A systematic study of transition metal-modified zinc oxide was conducted to determine whether they are suitable as visible light photocatalysts. The photocatalytic activity of ZnO modified with eight different transition metals (Cu, Co, Fe, Mn, Ni, Ru, Ti, Zr) in three different concentrations (0.01, 0.1, and 1 at.%) was investigated under irradiation with UV as well as with visible light. The employed activity test is the gas-phase degradation of acetaldehyde as described by the ISO standard 22197-2. The results suggest that the UV activity can be improved with almost any modification element and that there exists an optimal modification ratio at about 0.1 at.%. Additionally, Mn- and Ru-modified ZnO display visible light activity. Especially the Ru-modified ZnO is highly active and surpasses the visible light activity of all studied titania standards. These findings suggest that modified zinc oxides may be a viable alternative to titanium dioxide-based catalysts for visible light photocatalysis. Eventually, possible underlying mechanisms are proposed and discussed.

  9. ADVANCED REACTIVITY MEASUREMENT FACILITY, TRA660, INTERIOR. REACTOR INSIDE TANK. METAL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    ADVANCED REACTIVITY MEASUREMENT FACILITY, TRA-660, INTERIOR. REACTOR INSIDE TANK. METAL WORK PLATFORM ABOVE. THE REACTOR WAS IN A SMALL WATER-FILLED POOL. INL NEGATIVE NO. 66-6373. Unknown Photographer, ca. 1966 - Idaho National Engineering Laboratory, Test Reactor Area, Materials & Engineering Test Reactors, Scoville, Butte County, ID

  10. Laboratory Demonstrations for PDE and Metals Combustion at NASA MSFC's Advanced Propulsion Laboratory

    NASA Technical Reports Server (NTRS)

    2000-01-01

    Report provides status reporting on activities under order no. H-30549 for the period December 1 through December 31, 1999. Details the activities of the contract in the coordination of planned conduct of experiments at the MSFC Advanced Propulsion Laboratory in pulse detonation MHD power production and metals combustion.

  11. Topological phases in oxide heterostructures with light and heavy transition metal ions (invited)

    SciTech Connect

    Fiete, Gregory A.; Rüegg, Andreas

    2015-05-07

    Using a combination of density functional theory, tight-binding models, and Hartree-Fock theory, we predict topological phases with and without time-reversal symmetry breaking in oxide heterostructures. We consider both heterostructures containing light transition metal ions and those containing heavy transition metal ions. We find that the (111) growth direction naturally leads to favorable conditions for topological phases in both perovskite structures and pyrochlore structures. For the case of light transition metal elements, Hartree-Fock theory predicts the spin-orbit coupling is effectively enhanced by on-site multiple-orbital interactions and may drive the system through a topological phase transition, while heavy elements with intrinsically large spin-orbit coupling require much weaker or even vanishing electron interactions to bring about a topological phase.

  12. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect

    Michael L. Swanson; Grant E. Dunham; Mark A. Musich

    2007-02-01

    Three potential additives for controlling mercury emissions from syngas at temperatures ranging from 350 to 500 F (177 to 260 C) were developed. Current efforts are being directed at increasing the effective working temperature for these sorbents and also being able to either eliminate any potential mercury desorption or trying to engineer a trace metal removal system that can utilize the observed desorption process to repeatedly regenerate the same sorbent monolith for extended use. Project results also indicate that one of these same sorbents can also successfully be utilized for arsenic removal. Capture of the hydrogen selenide in the passivated tubing at elevated temperatures has resulted in limited results on the effective control of hydrogen selenide with these current sorbents, although lower-temperature results are promising. Preliminary economic analysis suggests that these Corning monoliths potentially could be more cost-effective than the conventional cold-gas (presulfided activated carbon beds) technology currently being utilized. Recent Hg-loading results might suggest that the annualized costs might be as high as 2.5 times the cost of the conventional technology. However, this annualized cost does not take into account the significantly improved thermal efficiency of any plant utilizing the warm-gas monolith technology currently being developed.

  13. Enhancement of light absorption in polyazomethines due to plasmon excitation on randomly distributed metal nanoparticles

    NASA Astrophysics Data System (ADS)

    Wróbel, P.; Antosiewicz, T. J.; Stefaniuk, T.; Ciesielski, A.; Iwan, A.; Wronkowska, A. A.; Wronkowski, A.; Szoplik, T.

    2015-05-01

    In photovoltaic devices, metal nanoparticles embedded in a semiconductor layer allow the enhancement of solar-toelectric energy conversion efficiency due to enhanced light absorption via a prolonged optical path, enhanced electric fields near the metallic inclusions, direct injection of hot electrons, or local heating. Here we pursue the first two avenues. In the first, light scattered at an angle beyond the critical angle for reflection is coupled into the semiconductor layer and confined within such planar waveguide up to possible exciton generation. In the second, light is trapped by the excitation of localized surface plasmons on metal nanoparticles leading to enhanced near-field plasmon-exciton coupling at the peak of the plasmon resonance. We report on results of a numerical experiment on light absorption in polymer- (fullerene derivative) blends, using the 3D FDTD method, where exact optical parameters of the materials involved are taken from our recent measurements. In simulations we investigate light absorption in randomly distributed metal nanoparticles dispersed in polyazomethine-(fullerene derivative) blends, which serve as active layers in bulkheterojunction polymer solar cells. In the study Ag and Al nanoparticles of different diameters and fill factors are diffused in two air-stable aromatic polyazomethines with different chemical structures (abbreviated S9POF and S15POF) mixed with phenyl-C61-butyric acid methyl ester (PCBM) or [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). The mixtures are spin coated on a 100 nm thick Al layer deposited on a fused silica substrate. Optical constants of the active layers are taken from spectroscopic ellipsometry and reflectance measurements using a rotating analyzer type ellipsometer with auto-retarder performed in the wavelength range from 225 nm to 2200 nm. The permittivities of Ag and Al particles of diameters from 20 to 60 nm are assumed to be equal to those measured on 100 to 200 nm thick metal films.

  14. First commissioning results for the elliptically polarizing undulator beamline at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Young, A. T.; Feng, J.; Arenholz, E.; Padmore, H. A.; Henderson, T.; Marks, S.; Hoyer, E.; Schlueter, R.; Kortright, J. B.; Martynov, V.; Steier, C.; Portmann, G.

    2001-07-01

    A new facility at the Advanced Light Source, Lawrence Berkeley National Laboratory, for high resolution magnetic spectroscopy is described. Beamline 4.0.2 has an elliptically polarizing undulator (EPU) and a high resolution monochromator, covering the energy range from 90 to 1800 eV. In this paper, we present the first commissioning results from this beamline, including measurements of the spectral resolution, photon flux and polarization of the x-rays.

  15. Advanced Light Water Reactor Program: Program management and staff review methodology

    SciTech Connect

    Moran, D.H.

    1986-12-01

    This report summarizes the NRC/EPRI coordinated effort to develop design requirements for a standardized advanced light water reactor (ALWR) and the procedures for screening and applying new generic safety issues to this program. The end-product will be an NRC-approved ALWR Requirements Document for use by the nuclear industry in generating designs of LWRs to be constructed for operation in the 1990s and beyond.

  16. Visible light focusing flat lenses based on hybrid dielectric-metal metasurface reflector-arrays.

    PubMed

    Fan, Qingbin; Huo, Pengcheng; Wang, Daopeng; Liang, Yuzhang; Yan, Feng; Xu, Ting

    2017-03-23

    Conventional metasurface reflector-arrays based on metallic resonant nanoantenna to control the wavefront of light for focusing always suffer from strong ohmic loss at optical frequencies. Here, we overcome this challenge by constructing a non-resonant, hybrid dielectric-metal configuration consisting of TiO2 nanofins associated with an Ag reflector substrate that provides a broadband response and high polarization conversion efficiency in the visible range. A reflective flat lens based on this configuration shows an excellent focusing performance with the spot size close to the diffraction limit. Furthermore, by employing the superimposed phase distribution design to manipulate the wavefront of the reflected light, various functionalities, such as multifocal and achromatic focusing, are demonstrated for the flat lenses. Such a reflective flat lens will find various applications in visible light imaging and sensing systems.

  17. Visible light focusing flat lenses based on hybrid dielectric-metal metasurface reflector-arrays

    PubMed Central

    Fan, Qingbin; Huo, Pengcheng; Wang, Daopeng; Liang, Yuzhang; Yan, Feng; Xu, Ting

    2017-01-01

    Conventional metasurface reflector-arrays based on metallic resonant nanoantenna to control the wavefront of light for focusing always suffer from strong ohmic loss at optical frequencies. Here, we overcome this challenge by constructing a non-resonant, hybrid dielectric-metal configuration consisting of TiO2 nanofins associated with an Ag reflector substrate that provides a broadband response and high polarization conversion efficiency in the visible range. A reflective flat lens based on this configuration shows an excellent focusing performance with the spot size close to the diffraction limit. Furthermore, by employing the superimposed phase distribution design to manipulate the wavefront of the reflected light, various functionalities, such as multifocal and achromatic focusing, are demonstrated for the flat lenses. Such a reflective flat lens will find various applications in visible light imaging and sensing systems. PMID:28332611

  18. Visible light focusing flat lenses based on hybrid dielectric-metal metasurface reflector-arrays

    NASA Astrophysics Data System (ADS)

    Fan, Qingbin; Huo, Pengcheng; Wang, Daopeng; Liang, Yuzhang; Yan, Feng; Xu, Ting

    2017-03-01

    Conventional metasurface reflector-arrays based on metallic resonant nanoantenna to control the wavefront of light for focusing always suffer from strong ohmic loss at optical frequencies. Here, we overcome this challenge by constructing a non-resonant, hybrid dielectric-metal configuration consisting of TiO2 nanofins associated with an Ag reflector substrate that provides a broadband response and high polarization conversion efficiency in the visible range. A reflective flat lens based on this configuration shows an excellent focusing performance with the spot size close to the diffraction limit. Furthermore, by employing the superimposed phase distribution design to manipulate the wavefront of the reflected light, various functionalities, such as multifocal and achromatic focusing, are demonstrated for the flat lenses. Such a reflective flat lens will find various applications in visible light imaging and sensing systems.

  19. Spectral light separator based on deep-subwavelength resonant apertures in a metallic film

    SciTech Connect

    Büyükalp, Yasin; Catrysse, Peter B. Shin, Wonseok; Fan, Shanhui

    2014-07-07

    We propose to funnel, select, and collect light spectrally by exploiting the unique properties of deep-subwavelength resonant apertures in a metallic film. In our approach, each aperture has an electromagnetic cross section that is much larger than its physical size while the frequency of the collected light is controlled by its height through the Fabry-Pérot resonance mechanism. The electromagnetic crosstalk between apertures remains low despite physical separations in the deep-subwavelength range. The resulting device enables an extremely efficient, subwavelength way to decompose light into its spectral components without the loss of photons and spatial coregistration errors. As a specific example, we show a subwavelength-size structure with three deep-subwavelength slits in a metallic film designed to operate in the mid-wave infrared range between 3 and 5.5 μm.

  20. Guidance for Developing Principal Design Criteria for Advanced (Non-Light Water) Reactors

    SciTech Connect

    Holbrook, Mark; Kinsey, Jim

    2015-03-01

    In July 2013, the US Department of Energy (DOE) and US Nuclear Regulatory Commission (NRC) established a joint initiative to address a key portion of the licensing framework essential to advanced (non-light water) reactor technologies. The initiative addressed the “General Design Criteria for Nuclear Power Plants,” Appendix A to10 Code of Federal Regulations (CFR) 50, which were developed primarily for light water reactors (LWRs), specific to the needs of advanced reactor design and licensing. The need for General Design Criteria (GDC) clarifications in non-LWR applications has been consistently identified as a concern by the industry and varied stakeholders and was acknowledged by the NRC staff in their 2012 Report to Congress1 as an area for enhancement. The initiative to adapt GDC requirements for non-light water advanced reactor applications is being accomplished in two phases. Phase 1, managed by DOE, consisted of reviews, analyses and evaluations resulting in recommendations and deliverables to NRC as input for NRC staff development of regulatory guidance. Idaho National Laboratory (INL) developed this technical report using technical and reactor technology stakeholder inputs coupled with analysis and evaluations provided by a team of knowledgeable DOE national laboratory personnel with input from individual industry licensing consultants. The DOE national laboratory team reviewed six different classes of emerging commercial reactor technologies against 10 CFR 50 Appendix A GDC requirements and proposed guidance for their adapted use in non-LWR applications. The results of the Phase 1 analysis are contained in this report. A set of draft Advanced Reactor Design Criteria (ARDC) has been proposed for consideration by the NRC in the establishment of guidance for use by non-LWR designers and NRC staff. The proposed criteria were developed to preserve the underlying safety bases expressed by the original GDC, and recognizing that advanced reactors may take

  1. Altered Circadian Rhythm and Metabolic Gene Profile in Rats Subjected to Advanced Light Phase Shifts

    PubMed Central

    Herrero, Laura; Valcarcel, Lorea; da Silva, Crhistiane Andressa; Albert, Nerea; Diez-Noguera, Antoni; Cambras, Trinitat; Serra, Dolors

    2015-01-01

    The circadian clock regulates metabolic homeostasis and its disruption predisposes to obesity and other metabolic diseases. However, the effect of phase shifts on metabolism is not completely understood. We examined whether alterations in the circadian rhythm caused by phase shifts induce metabolic changes in crucial genes that would predispose to obesity. Three-month-old rats were maintained on a standard diet under lighting conditions with chronic phase shifts consisting of advances, delays or advances plus delays. Serum leptin, insulin and glucose levels decreased only in rats subjected to advances. The expression of the clock gene Bmal 1 increased in the hypothalamus, white adipose tissue (WAT), brown adipose tissue (BAT) and liver of the advanced group compared to control rats. The advanced group showed an increase in hypothalamic AgRP and NPY mRNA, and their lipid metabolism gene profile was altered in liver, WAT and BAT. WAT showed an increase in inflammation and ER stress and brown adipocytes suffered a brown-to-white transformation and decreased UCP-1 expression. Our results indicate that chronic phase advances lead to significant changes in neuropeptides, lipid metabolism, inflammation and ER stress gene profile in metabolically relevant tissues such as the hypothalamus, liver, WAT and BAT. This highlights a link between alteration of the circadian rhythm and metabolism at the transcriptional level. PMID:25837425

  2. van der Waals Metal-Organic Framework as an Excitonic Material for Advanced Photonics.

    PubMed

    Milichko, Valentin A; Makarov, Sergey V; Yulin, Alexey V; Vinogradov, Alexandr V; Krasilin, Andrei A; Ushakova, Elena; Dzyuba, Vladimir P; Hey-Hawkins, Evamarie; Pidko, Evgeny A; Belov, Pavel A

    2017-01-23

    Synergistic combination of organic and inorganic nature in van der Waals metal-organic frameworks supports different types of robust excitons that can be effectively and independently manipulated by light at room temperature, and opens new concepts for all-optical data processing and storage.

  3. Phase advancing human circadian rhythms with morning bright light, afternoon melatonin, and gradually shifted sleep: can we reduce morning bright light duration?

    PubMed Central

    Crowley, Stephanie J.; Eastman, Charmane I.

    2015-01-01

    OBJECTIVE Efficient treatments to phase advance human circadian rhythms are needed to attenuate circadian misalignment and the associated negative health outcomes that accompany early morning shift work, early school start times, jet lag, and delayed sleep phase disorder. This study compared three morning bright light exposure patterns from a single light box (to mimic home treatment) in combination with afternoon melatonin. METHODS Fifty adults (27 males) aged 25.9±5.1 years participated. Sleep/dark was advanced 1 hour/day for 3 treatment days. Participants took 0.5 mg melatonin 5 hours before baseline bedtime on treatment day 1, and an hour earlier each treatment day. They were exposed to one of three bright light (~5000 lux) patterns upon waking each morning: four 30-minute exposures separated by 30 minutes of room light (2 h group); four 15-minute exposures separated by 45 minutes of room light (1 h group), and one 30-minute exposure (0.5 h group). Dim light melatonin onsets (DLMOs) before and after treatment determined the phase advance. RESULTS Compared to the 2 h group (phase shift=2.4±0.8 h), smaller phase advance shifts were seen in the 1 h (1.7±0.7 h) and 0.5 h (1.8±0.8 h) groups. The 2-hour pattern produced the largest phase advance; however, the single 30-minute bright light exposure was as effective as 1 hour of bright light spread over 3.25 h, and produced 75% of the phase shift observed with 2 hours of bright light. CONCLUSIONS A 30-minute morning bright light exposure with afternoon melatonin is an efficient treatment to phase advance human circadian rhythms. PMID:25620199

  4. Thermophysical properties of saturated light and heavy water for Advanced Neutron Source applications

    SciTech Connect

    Crabtree, A.; Siman-Tov, M.

    1993-05-01

    The Advanced Neutron Source is an experimental facility being developed by Oak Ridge National Laboratory. As a new nuclear fission research reactor of unprecedented flux, the Advanced Neutron Source Reactor will provide the most intense steady-state beams of neutrons in the world. The high heat fluxes generated in the reactor [303 MW(t) with an average power density of 4.5 MW/L] will be accommodated by a flow of heavy water through the core at high velocities. In support of this experimental and analytical effort, a reliable, highly accurate, and uniform source of thermodynamic and transport property correlations for saturated light and heavy water were developed. In order to attain high accuracy in the correlations, the range of these correlations was limited to the proposed Advanced Neutron Source Reactor`s nominal operating conditions. The temperature and corresponding saturation pressure ranges used for light water were 20--300{degrees}C and 0.0025--8.5 MPa, respectively, while those for heavy water were 50--250{degrees}C and 0.012--3.9 MPa. Deviations between the correlation predictions and data from the various sources did not exceed 1.0%. Light water vapor density was the only exception, with an error of 1.76%. The physical property package consists of analytical correlations, SAS codes, and FORTRAN subroutines incorporating these correlations, as well as an interactive, easy-to-use program entitled QuikProp.

  5. Thermophysical properties of saturated light and heavy water for advanced neutron source applications

    SciTech Connect

    Crabtree, A.; Siman-Tov, M.

    1993-05-01

    The Advanced Neutron Source is an experimental facility being developed by Oak Ridge National Laboratory. As a new nuclear fission research reactor of unprecedented flux, the Advanced Neutron Source Reactor will provide the most intense steady-state beams of neutrons in the world. The high heat fluxes generated in the reactor [303 MW(t) with an average power density of 4.5 MW/L] will be accommodated by a flow of heavy water through the core at high velocities. In support of this experimental and analytical effort, a reliable, highly accurate, and uniform source of thermodynamic and transport property correlations for saturated light and heavy water were developed. In order to attain high accuracy in the correlations, the range of these correlations was limited to the proposed Advanced Neutron Source Reactor's nominal operating conditions. The temperature and corresponding saturation pressure ranges used for light water were 20--300[degrees]C and 0.0025--8.5 MPa, respectively, while those for heavy water were 50--250[degrees]C and 0.012--3.9 MPa. Deviations between the correlation predictions and data from the various sources did not exceed 1.0%. Light water vapor density was the only exception, with an error of 1.76%. The physical property package consists of analytical correlations, SAS codes, and FORTRAN subroutines incorporating these correlations, as well as an interactive, easy-to-use program entitled QuikProp.

  6. Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries.

    PubMed

    Wu, Hao Bin; Chen, Jun Song; Hng, Huey Hoon; Lou, Xiong Wen David

    2012-04-21

    The search for new electrode materials for lithium-ion batteries (LIBs) has been an important way to satisfy the ever-growing demands for better performance with higher energy/power densities, improved safety and longer cycle life. Nanostructured metal oxides exhibit good electrochemical properties, and they are regarded as promising anode materials for high-performance LIBs. In this feature article, we will focus on three different categories of metal oxides with distinct lithium storage mechanisms: tin dioxide (SnO(2)), which utilizes alloying/dealloying processes to reversibly store/release lithium ions during charge/discharge; titanium dioxide (TiO(2)), where lithium ions are inserted/deinserted into/out of the TiO(2) crystal framework; and transition metal oxides including iron oxide and cobalt oxide, which react with lithium ions via an unusual conversion reaction. For all three systems, we will emphasize that creating nanomaterials with unique structures could effectively improve the lithium storage properties of these metal oxides. We will also highlight that the lithium storage capability can be further enhanced through designing advanced nanocomposite materials containing metal oxides and other carbonaceous supports. By providing such a rather systematic survey, we aim to stress the importance of proper nanostructuring and advanced compositing that would result in improved physicochemical properties of metal oxides, thus making them promising negative electrodes for next-generation LIBs.

  7. Recent Advances in Atomic Metal Doping of Carbon-based Nanomaterials for Energy Conversion.

    PubMed

    Bayatsarmadi, Bita; Zheng, Yao; Vasileff, Anthony; Qiao, Shi-Zhang

    2017-04-12

    Nanostructured metal-contained catalysts are one of the most widely used types of catalysts applied to facilitate some of sluggish electrochemical reactions. However, the high activity of these catalysts cannot be sustained over a variety of pH ranges. In an effort to develop highly active and stable metal-contained catalysts, various approaches have been pursued with an emphasis on metal particle size reduction and doping on carbon-based supports. These techniques enhances the metal-support interactions, originating from the chemical bonding effect between the metal dopants and carbon support and the associated interface, as well as the charge transfer between the atomic metal species and carbon framework. This provides an opportunity to tune the well-defined metal active centers and optimize their activity, selectivity and stability of this type of (electro)catalyst. Herein, recent advances in synthesis strategies, characterization and catalytic performance of single atom metal dopants on carbon-based nanomaterials are highlighted with attempts to understand the electronic structure and spatial arrangement of individual atoms as well as their interaction with the supports. Applications of these new materials in a wide range of potential electrocatalytic processes in renewable energy conversion systems are also discussed with emphasis on future directions in this active field of research.

  8. Investigation of novel electrolyte systems for advanced metal/air batteries and fuel cells

    NASA Astrophysics Data System (ADS)

    Ye, Hui

    It is a worldwide challenge to develop advanced green power sources for modern portable devices, transportation and stationary power generation. Metal/air batteries and fuel cells clearly stand out in view of their high specific energy, high energy efficiency and environment-friendliness. Advanced metal/air batteries based on metal ion conductors and proton exchange membrane (PEM) fuel cells operated at elevated temperatures (>120°C) can circumvent the limitations of current technologies and bring considerable advantages. The key is to develop suitable electrolytes to enable these new technologies. In this thesis research, investigation of novel electrolytes systems for advanced metal/air batteries and PEM fuel cells is conducted. Novel polymer gel electrolyte systems, [metal salt/ionic liquid/polymer] and [metal salt/liquid polyether/polymer] are prepared. Such systems contain no volatile solvents, conduct metal ions (Li+ or Zn 2+) with high ionic conductivity, possess wide electrochemical stability windows, and exhibit wide operating temperature ranges. They promise to enable non-aqueous, all-solid-state, thin-film Li/air batteries and Zn/air batteries. They are advantageous for application in other battery systems as well, such as rechargeable lithium and lithium ion batteries. In the case of proton exchange membranes, polymer gel electrolyte systems [acid/ionic liquid/polymer] are prepared. Especially, H3PO4/PMIH2PO 4/PBI is demonstrated as prospective proton exchange membranes for PEM fuel cells operating at elevated temperatures. Comprehensive electrochemical characterization, thermal analysis (TGA and DSC) and spectroscopy analysis (NMR and FTIR) are carried out to investigate these novel electrolyte systems and their ion transport mechanisms. The design and synthesis of novel ionic liquids and electrolyte systems based on them for advantageous application in various electrochemical power sources are highlighted in this work.

  9. White organic light-emitting diodes with 4 nm metal electrode

    SciTech Connect

    Lenk, Simone; Schwab, Tobias; Schubert, Sylvio; Müller-Meskamp, Lars; Leo, Karl; Reineke, Sebastian; Gather, Malte C.

    2015-10-19

    We investigate metal layers with a thickness of only a few nanometers as anode replacement for indium tin oxide (ITO) in white organic light-emitting diodes (OLEDs). The ultrathin metal electrodes prove to be an excellent alternative that can, with regard to the angular dependence and efficiency of the OLED devices, outperform the ITO reference. Furthermore, unlike ITO, the thin composite metal electrodes are readily compatible with demanding architectures (e.g., top-emission or transparent OLEDs, device unit stacking, etc.) and flexible substrates. Here, we compare the sheet resistance of both types of electrodes on polyethylene terephthalate for different bending radii. The electrical performance of ITO breaks down at a radius of 10 mm, while the metal electrode remains intact even at radii smaller than 1 mm.

  10. High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Qiao, Ruimin; Li, Qinghao; Zhuo, Zengqing; Sallis, Shawn; Fuchs, Oliver; Blum, Monika; Weinhardt, Lothar; Heske, Clemens; Pepper, John; Jones, Michael; Brown, Adam; Spucces, Adrian; Chow, Ken; Smith, Brian; Glans, Per-Anders; Chen, Yanxue; Yan, Shishen; Pan, Feng; Piper, Louis F. J.; Denlinger, Jonathan; Guo, Jinghua; Hussain, Zahid; Chuang, Yi-De; Yang, Wanli

    2017-03-01

    An endstation with two high-efficiency soft x-ray spectrographs was developed at Beamline 8.0.1 of the Advanced Light Source, Lawrence Berkeley National Laboratory. The endstation is capable of performing soft x-ray absorption spectroscopy, emission spectroscopy, and, in particular, resonant inelastic soft x-ray scattering (RIXS). Two slit-less variable line-spacing grating spectrographs are installed at different detection geometries. The endstation covers the photon energy range from 80 to 1500 eV. For studying transition-metal oxides, the large detection energy window allows a simultaneous collection of x-ray emission spectra with energies ranging from the O K-edge to the Ni L-edge without moving any mechanical components. The record-high efficiency enables the recording of comprehensive two-dimensional RIXS maps with good statistics within a short acquisition time. By virtue of the large energy window and high throughput of the spectrographs, partial fluorescence yield and inverse partial fluorescence yield signals could be obtained for all transition metal L-edges including Mn. Moreover, the different geometries of these two spectrographs (parallel and perpendicular to the horizontal polarization of the beamline) provide contrasts in RIXS features with two different momentum transfers.

  11. ATYPICAL MACULOPATHY IN A PATIENT WITH LIGHT CHAIN DEPOSITION DISEASE MIMICKING ADVANCED GEOGRAPHIC ATROPHY

    PubMed Central

    Oshry, Lauren J.; Reichel, Elias

    2017-01-01

    Purpose: To report a previously unreported presentation of advanced geographic atrophy of the macula mimicking nonneovascular (dry) age-related macular degeneration in a patient with light chain deposition disease. Methods: Ocular examination included dilated fundus examination, fundus autofluorescence, full-field electroretinography, and spectral domain optical coherence tomography. Patients: Single-patient case report. Results: Dilated fundus examination demonstrated diffuse loss of the retinal pigment epithelium in a geographic atrophy pattern in the macula and drusenlike deposits localized to the outer retina and retinal pigment epithelium. There were no signs of choroidal neovascularization or retinal pigment epithelium detachments. Fundus autofluorescence demonstrated wide areas of retinal pigment epithelium loss. Full-field electroretinography was normal. Spectral domain optical coherence tomography displayed atrophy of the outer retinal layers. Discussion: This is the first documented case of drusenlike deposits and maculopathy in a patient with light chain deposition disease that mimics advanced geographic atrophy that is typically observed in nonneovascular age-related macular degeneration. Physicians should be aware of the macular changes that can be associated with light chain deposition disease, and patients with light chain deposition disease should be regularly evaluated for associated macular disease. PMID:26934302

  12. Development of a microsecond X-ray protein footprinting facility at the Advanced Light Source

    PubMed Central

    Gupta, Sayan; Celestre, Richard; Petzold, Christopher J.; Chance, Mark R.; Ralston, Corie

    2014-01-01

    X-ray footprinting (XF) is an important structural biology tool used to determine macromolecular conformations and dynamics of both nucleic acids and proteins in solution on a wide range of timescales. With the impending shut-down of the National Synchrotron Light Source, it is ever more important that this tool continues to be developed at other synchrotron facilities to accommodate XF users. Toward this end, a collaborative XF program has been initiated at the Advanced Light Source using the white-light bending-magnet beamlines 5.3.1 and 3.2.1. Accessibility of the microsecond time regime for protein footprinting is demonstrated at beamline 5.3.1 using the high flux density provided by a focusing mirror in combination with a micro-capillary flow cell. It is further reported that, by saturating samples with nitrous oxide, the radiolytic labeling efficiency is increased and the imprints of bound versus bulk water can be distinguished. These results both demonstrate the suitability of the Advanced Light Source as a second home for the XF experiment, and pave the way for obtaining high-quality structural data on complex protein samples and dynamics information on the microsecond timescale. PMID:24971962

  13. RECENT BEAM MEASUREMENTS AND NEW INSTRUMENTATION AT THE ADVANCED LIGHT SOURCE

    SciTech Connect

    Sannibale, Fernando; Baptiste, Kenneth; Barry, Walter; Chin, Michael; Filippetto, Daniele; Jaegerhofer, Lukas; Julian, James; Kwiatkowski, Slawomir; Low, Raymond; Plate, David; Portmann, Gregory; Robin, David; Scarvie, Tomas; Stupakov, Gennady; Weber, Jonah; Zolotorev, Max

    2008-05-05

    The Advanced Light Source (ALS) in Berkeley was the first of the soft x-ray third generation light source ever built, and since 1993 has been in continuous and successful operation serving a large community of users in the VUV and soft x-ray community. During these years the storage ring underwent through several important upgrades that allowed maintaining the performance of this veteran facility at the forefront. The ALS beam diagnostics and instrumentation have followed a similar path of innovation and upgrade and nowadays include most of the modem and last generation devices and technologies that are commercially available and used in the recently constructed third generation light sources. In this paper we will not focus on such already widely known systems, but we will concentrate our effort in the description of some measurements techniques, instrumentation and diagnostic systems specifically developed at the ALS and used during the last few years.

  14. Recent Beam Measurements and New Instrumentation at the Advanced Light Source

    SciTech Connect

    Sannibale, F.; Baptiste, K.; Barry, W.; Chin, M.; Filippetto, D.; Jaegerhofer, L.; Julian, J.; Kwiatkowski, S.; Low, R.; Plate, D.; Portmann, G.; Robin, D.; Scarvie, T.; Stupakov, G.; Weber, J.; Zolotorev, M.; /LBL, Berkeley

    2012-04-11

    The Advanced Light Source (ALS) in Berkeley was the first of the soft x-ray third generation light source ever built, and since 1993 has been in continuous and successful operation serving a large community of users in the VUV and soft x-ray community. During these years the storage ring underwent through several important upgrades that allowed maintaining the performance of this veteran facility at the forefront. The ALS beam diagnostics and instrumentation have followed a similar path of innovation and upgrade and nowadays include most of the modem and last generation devices and technologies that are commercially available and used in the recently constructed third generation light sources. In this paper we will not focus on such already widely known systems, but we will concentrate our effort in the description of some measurements techniques, instrumentation and diagnostic systems specifically developed at the ALS and used during the last few years.

  15. Study of Pu consumption in Advanced Light Water Reactors. Evaluation of GE Advanced Boiling Water Reactor plants

    SciTech Connect

    Not Available

    1993-05-13

    Timely disposal of the weapons plutonium is of paramount importance to permanently safeguarding this material. GE`s 1300 MWe Advanced Boiling Water Reactor (ABWR) has been designed to utilize fill] core loading of mixed uranium-plutonium oxide fuel. Because of its large core size, a single ABWR reactor is capable of disposing 100 metric tons of plutonium within 15 years of project inception in the spiking mode. The same amount of material could be disposed of in 25 years after the start of the project as spent fuel, again using a single reactor, while operating at 75 percent capacity factor. In either case, the design permits reuse of the stored spent fuel assemblies for electrical energy generation for the remaining life of the plant for another 40 years. Up to 40 percent of the initial plutonium can also be completely destroyed using ABWRS, without reprocessing, either by utilizing six ABWRs over 25 years or by expanding the disposition time to 60 years, the design life of the plants and using two ABWRS. More complete destruction would require the development and testing of a plutonium-base fuel with a non-fertile matrix for an ABWR or use of an Advanced Liquid Metal Reactor (ALMR). The ABWR, in addition, is fully capable of meeting the tritium target production goals with already developed target technology.

  16. Recent advances in DNA-based electrochemical biosensors for heavy metal ion detection: A review.

    PubMed

    Saidur, M R; Aziz, A R Abdul; Basirun, W J

    2017-04-15

    The presence of heavy metal in food chains due to the rapid industrialization poses a serious threat on the environment. Therefore, detection and monitoring of heavy metals contamination are gaining more attention nowadays. However, the current analytical methods (based on spectroscopy) for the detection of heavy metal contamination are often very expensive, tedious and can only be handled by trained personnel. DNA biosensors, which are based on electrochemical transduction, is a sensitive but inexpensive method of detection. The principles, sensitivity, selectivity and challenges of electrochemical biosensors are discussed in this review. This review also highlights the major advances of DNA-based electrochemical biosensors for the detection of heavy metal ions such as Hg(2+), Ag(+), Cu(2+) and Pb(2+).

  17. Advances in sensor adaptation to changes in ambient light: a bio-inspired solution - biomed 2010.

    PubMed

    Dean, Brian; Wright, Cameron H G; Barrett, Stephen F

    2010-01-01

    Fly-inspired sensors have been shown to have many interesting qualities such as hyperacuity (or an ability to achieve movement resolution beyond the theoretical limit), extreme sensitivity to motion, and (through software simulation) image edge extraction, motion detection, and orientation and location of a line. Many of these qualities are beyond the ability of traditional computer vision sensors such as charge-coupled device (CCD) arrays. To obtain these characteristics, a prototype fly-inspired sensor has been built and tested in a laboratory environment and shows promise. Any sophisticated visual system, whether man made or natural, must adequately adapt to lighting conditions; therefore, light adaptation is a vital milestone in getting the fly eye vision sensor prototype working in real-world conditions. A design based on the common house fly, Musca domestica, was suggested in a paper presented to RMBS 2009 and showed an ability to remove 72-86% of effects due to ambient light changes. In this paper, a more advanced version of this design is discussed. This new design is able to remove 97-99% of the effects due to changes in ambient light, by more accurately approximating the light adaptation process used by the common house fly.

  18. Metal Organic Vapor Phase Epitaxy of Monolithic Two-Color Light-Emitting Diodes Using an InGaN-Based Light Converter

    NASA Astrophysics Data System (ADS)

    Damilano, Benjamin; Kim-Chauveau, Hyonju; Frayssinet, Eric; Brault, Julien; Hussain, Sakhawat; Lekhal, Kaddour; Vennéguès, Philippe; De Mierry, Philippe; Massies, Jean

    2013-09-01

    Monolithic InGaN-based light-emitting diodes (LEDs) using a light converter fully grown by metal organic vapor phase epitaxy are demonstrated. The light converter, consisting of 10-40 InGaN/GaN quantum wells, is grown first, followed by a violet pump LED. The structure and growth conditions of the pump LED are specifically adapted to avoid thermal degradation of the light converter. Electroluminescence analysis shows that part of the pump light is absorbed by the light converter and reemitted at longer wavelength. Depending on the emission wavelength of the light converter, different LED colors are achieved. In particular, for red-emitting light converters, a color temperature of 2100 K corresponding to a tint between warm white and candle light is demonstrated.

  19. Highly Active TiO2-Based Visible-Light Photocatalyst with Nonmetal Doping and Plasmonic Metal Decoration

    SciTech Connect

    Zhang, Qiao; Lima, Diana Q.; Chi, Miaofang; Yin, Yadong

    2011-01-01

    A sandwich-structured photocatalyst shows an excellent performance in degradation reactions of a number of organic compounds under UV, visible light, and direct sunlight (see picture). The catalyst was synthesized by a combination of nonmetal doping and plasmonic metal decoration of TiO2 nanocrystals, which improves visible-light activity and enhances light harvesting and charge separation, respectively.

  20. Advancements in sensing and perception using structured lighting techniques :an LDRD final report.

    SciTech Connect

    Novick, David Keith; Padilla, Denise D.; Davidson, Patrick A. Jr.; Carlson, Jeffrey J.

    2005-09-01

    This report summarizes the analytical and experimental efforts for the Laboratory Directed Research and Development (LDRD) project entitled ''Advancements in Sensing and Perception using Structured Lighting Techniques''. There is an ever-increasing need for robust, autonomous ground vehicles for counterterrorism and defense missions. Although there has been nearly 30 years of government-sponsored research, it is undisputed that significant advancements in sensing and perception are necessary. We developed an innovative, advanced sensing technology for national security missions serving the Department of Energy, the Department of Defense, and other government agencies. The principal goal of this project was to develop an eye-safe, robust, low-cost, lightweight, 3D structured lighting sensor for use in broad daylight outdoor applications. The market for this technology is wide open due to the unavailability of such a sensor. Currently available laser scanners are slow, bulky and heavy, expensive, fragile, short-range, sensitive to vibration (highly problematic for moving platforms), and unreliable for outdoor use in bright sunlight conditions. Eye-safety issues are a primary concern for currently available laser-based sensors. Passive, stereo-imaging sensors are available for 3D sensing but suffer from several limitations : computationally intensive, require a lighted environment (natural or man-made light source), and don't work for many scenes or regions lacking texture or with ambiguous texture. Our approach leveraged from the advanced capabilities of modern CCD camera technology and Center 6600's expertise in 3D world modeling, mapping, and analysis, using structured lighting. We have a diverse customer base for indoor mapping applications and this research extends our current technology's lifecycle and opens a new market base for outdoor 3D mapping. Applications include precision mapping, autonomous navigation, dexterous manipulation, surveillance and

  1. Overview of the Consortium for the Advanced Simulation of Light Water Reactors (CASL)

    NASA Astrophysics Data System (ADS)

    Kulesza, Joel A.; Franceschini, Fausto; Evans, Thomas M.; Gehin, Jess C.

    2016-02-01

    The Consortium for Advanced Simulation of Light Water Reactors (CASL) was established in July 2010 for the purpose of providing advanced modeling and simulation solutions for commercial nuclear reactors. The primary goal is to provide coupled, higher-fidelity, usable modeling and simulation capabilities than are currently available. These are needed to address light water reactor (LWR) operational and safety performance-defining phenomena that are not yet able to be fully modeled taking a first-principles approach. In order to pursue these goals, CASL has participation from laboratory, academic, and industry partners. These partners are pursuing the solution of ten major "Challenge Problems" in order to advance the state-of-the-art in reactor design and analysis to permit power uprates, higher burnup, life extension, and increased safety. At present, the problems being addressed by CASL are primarily reactor physics-oriented; however, this paper is intended to introduce CASL to the reactor dosimetry community because of the importance of reactor physics modelling and nuclear data to define the source term for that community and the applicability and extensibility of the transport methods being developed.

  2. Control of light absorption in organic solar cells using semi-transparent metal electrodes

    NASA Astrophysics Data System (ADS)

    Neutzner, Stefanie; van de Groep, Jorik; Bakulin, Artem A.; Bakker, Huib J.

    2013-09-01

    In this contribution we combine optical modeling and device fabrication/characterization techniques to demonstrate that semitransparent metal electrodes can improve light harvesting in organic photovoltaic (OPV) devices. We show that inverted P3HT:PCBM solar cells using a thin ~8 nm silver film as a front electrode outperform the ITO-based devices, despite the lower transmittance of silver films in comparison to ITO. The variation of silver thickness allows tailoring the field distribution inside the cell, which leads to a broad resonance window where the absorption is enhanced. Thereby the short-circuit current was increased by 84% and the solar-cell efficiency was doubled. These results show that semitransparent metal electrodes can be efficiently used for light trapping and also form a very promising alternative to ITO in OPV devices. The stacked silver electrodes used in this work are flexible and can be easily produced on a large scale, including printing techniques.

  3. Plasmonic effects for light concentration in organic photovoltaic thin films induced by hexagonal periodic metallic nanospheres

    NASA Astrophysics Data System (ADS)

    Zhu, Jinfeng; Xue, Mei; Shen, Huajun; Wu, Zhe; Kim, Seongku; Ho, Jyh-Jier; Hassani-Afshar, Aram; Zeng, Baoqing; Wang, Kang L.

    2011-04-01

    We present a plasmonic nanostructure design by embedding a layer of hexagonal periodic metallic nanospheres between the active layer and transparent anode for bulk heterojunction organic solar cells. The hybrid structure shows broadband optical absorption enhancement from localized surface plasmon resonance with a weak dependence on polarization of incident light. We also theoretically study the optimization of the design to enhance the absorption up to 1.90 times for a typical hybrid active layer based on a low band gap material.

  4. Polymer, metal, and ceramic matrix composites for advanced aircraft engine applications

    SciTech Connect

    Mc Daniels, D.L.; Serafini, T.T.; Di Carlo, J.A.

    1986-06-01

    Advanced aircraft engine research within NASA Lewis focuses on propulsion systems for subsonic, supersonic, and hypersonic aircraft. Each of these flight regimes requires different types of engines, but all require advanced materials to meet their goals of performance, thrust-to-weight ratio, and fuel efficiency. The high strength/weight and stiffness/weight properties of resin, metal, and ceramic matrix composites will play an increasingly key role in meeting these performance requirements. At NASA Lewis, research is ongoing to apply graphite/polyimide composites to engine components and to develop polymer matrices with higher operating temperature capabilities. Metal matrix composites, using magnesium, aluminum, titanium, and superalloy matrices, are being developed for application to static and rotating engine components, as well as for space applications, over a broad temperature range. Ceramic matrix composites are also being examined to increase the toughness and reliability of ceramics for application to high-temperature engine structures and components.

  5. Reference site selection report for the advanced liquid metal reactor at the Idaho National Engineering Laboratory

    SciTech Connect

    Sivill, R.L.

    1990-03-01

    This Reference Site Selection Report was prepared by EG G, Idaho Inc., for General Electric (GE) to provide information for use by the Department of Energy (DOE) in selecting a Safety Test Site for an Advanced Liquid Metal Reactor. Similar Evaluation studies are planned to be conducted at other potential DOE sites. The Power Reactor Innovative Small Module (PRISM) Concept was developed for ALMR by GE. A ALMR Safety Test is planned to be performed on a DOE site to demonstrate features and meet Nuclear Regulatory Commission Requirements. This study considered possible locations at the Idaho National Engineering Laboratory that met the ALMR Prototype Site Selection Methodology and Criteria. Four sites were identified, after further evaluation one site was eliminated. Each of the remaining three sites satisfied the criteria and was graded. The results were relatively close. Thus concluding that the Idaho National Engineering Laboratory is a suitable location for an Advanced Liquid Metal Reactor Safety Test. 23 refs., 13 figs., 9 tabs.

  6. Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor

    SciTech Connect

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.

    1990-11-01

    The conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design has been performed. As a first step, an intensive literature survey was completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins were designed and analyzed using the SIEX computer code. The analysis predicted that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors. 13 refs., 10 figs., 2 tabs.

  7. Low-loss light transmission in a rectangular-shaped hybrid metal trench at 1550 nm.

    PubMed

    Yang, Pengfei; Di, Zhigang; Xu, Hongxing

    2013-07-15

    A hybrid plasmonic waveguide consisting of a high-index dielectric core embedded inside a rectangular-shaped metallic trench is proposed and its guiding properties are investigated at the wavelength of 1550 nm. Numerical simulations based on the finite element method have demonstrated that the introduced dielectric core could greatly reduce the modal loss of the metal trench while maintaining strong confinement of light. The effects of dielectric core size, material of the cladding and the dielectric core on the modal properties have been systematically investigated. The proposed hybrid plasmonic structure can be realized employing fabrication techniques of the traditional metal trench waveguides and could be leveraged as important elements for highly-integrated photonic circuits.

  8. Direct Imaging of Single Plasmonic Metal Nanoparticles in Capillary with Laser Light-Sheet Scattering Imaging.

    PubMed

    Cao, Xuan; Feng, Jingjing; Pan, Qi; Xiong, Bin; He, Yan; Yeung, Edward S

    2017-03-07

    Understanding the heterogeneous distribution of the physical and chemical properties of plasmonic metal nanoparticles is fundamentally important to their basic and applied research. Traditionally, they are obtained either indirectly via bulk spectroscopic measurements plus electron microscopic characterizations or through single molecule/particle imaging of nanoparticles immobilized on planar substrates. In this study, by using light-sheet scattering microscopy with a supercontinuum white laser, highly sensitive imaging of individual metal nanoparticles (MNPs) flowing inside a capillary, driven by either pressure or electric field, was achieved for the first time. We demonstrate that single plasmonic nanoparticles with different size or chemical modification could be differentiated through their electrophoretic mobility in a few minutes. This technique could potentially be applied to high throughput characterization and evaluation of single metal nanoparticles as well as their dynamic interactions with various local environments.

  9. Waveguide-coupled nanopillar metal-cavity light-emitting diodes on silicon

    PubMed Central

    Dolores-Calzadilla, V.; Romeira, B.; Pagliano, F.; Birindelli, S.; Higuera-Rodriguez, A.; van Veldhoven, P. J.; Smit, M. K.; Fiore, A.; Heiss, D.

    2017-01-01

    Nanoscale light sources using metal cavities have been proposed to enable high integration density, efficient operation at low energy per bit and ultra-fast modulation, which would make them attractive for future low-power optical interconnects. For this application, such devices are required to be efficient, waveguide-coupled and integrated on a silicon substrate. We demonstrate a metal-cavity light-emitting diode coupled to a waveguide on silicon. The cavity consists of a metal-coated III–V semiconductor nanopillar which funnels a large fraction of spontaneous emission into the fundamental mode of an InP waveguide bonded to a silicon wafer showing full compatibility with membrane-on-Si photonic integration platforms. The device was characterized through a grating coupler and shows on-chip external quantum efficiency in the 10−4–10−2 range at tens of microamp current injection levels, which greatly exceeds the performance of any waveguide-coupled nanoscale light source integrated on silicon in this current range. Furthermore, direct modulation experiments reveal sub-nanosecond electro-optical response with the potential for multi gigabit per second modulation speeds. PMID:28148954

  10. Waveguide-coupled nanopillar metal-cavity light-emitting diodes on silicon

    NASA Astrophysics Data System (ADS)

    Dolores-Calzadilla, V.; Romeira, B.; Pagliano, F.; Birindelli, S.; Higuera-Rodriguez, A.; van Veldhoven, P. J.; Smit, M. K.; Fiore, A.; Heiss, D.

    2017-02-01

    Nanoscale light sources using metal cavities have been proposed to enable high integration density, efficient operation at low energy per bit and ultra-fast modulation, which would make them attractive for future low-power optical interconnects. For this application, such devices are required to be efficient, waveguide-coupled and integrated on a silicon substrate. We demonstrate a metal-cavity light-emitting diode coupled to a waveguide on silicon. The cavity consists of a metal-coated III-V semiconductor nanopillar which funnels a large fraction of spontaneous emission into the fundamental mode of an InP waveguide bonded to a silicon wafer showing full compatibility with membrane-on-Si photonic integration platforms. The device was characterized through a grating coupler and shows on-chip external quantum efficiency in the 10-4-10-2 range at tens of microamp current injection levels, which greatly exceeds the performance of any waveguide-coupled nanoscale light source integrated on silicon in this current range. Furthermore, direct modulation experiments reveal sub-nanosecond electro-optical response with the potential for multi gigabit per second modulation speeds.

  11. Waveguide-coupled nanopillar metal-cavity light-emitting diodes on silicon.

    PubMed

    Dolores-Calzadilla, V; Romeira, B; Pagliano, F; Birindelli, S; Higuera-Rodriguez, A; van Veldhoven, P J; Smit, M K; Fiore, A; Heiss, D

    2017-02-02

    Nanoscale light sources using metal cavities have been proposed to enable high integration density, efficient operation at low energy per bit and ultra-fast modulation, which would make them attractive for future low-power optical interconnects. For this application, such devices are required to be efficient, waveguide-coupled and integrated on a silicon substrate. We demonstrate a metal-cavity light-emitting diode coupled to a waveguide on silicon. The cavity consists of a metal-coated III-V semiconductor nanopillar which funnels a large fraction of spontaneous emission into the fundamental mode of an InP waveguide bonded to a silicon wafer showing full compatibility with membrane-on-Si photonic integration platforms. The device was characterized through a grating coupler and shows on-chip external quantum efficiency in the 10(-4)-10(-2) range at tens of microamp current injection levels, which greatly exceeds the performance of any waveguide-coupled nanoscale light source integrated on silicon in this current range. Furthermore, direct modulation experiments reveal sub-nanosecond electro-optical response with the potential for multi gigabit per second modulation speeds.

  12. High performance fibers for structurally reliable metal and ceramic composites. [advanced gas turbine engine materials

    NASA Technical Reports Server (NTRS)

    Dicarlo, J. A.

    1984-01-01

    Very few of the commercially available high performance fibers with low densities, high Young's moduli, and high tensile strengths possess all the necessary property requirements for providing either metal matrix composites (MMC) or ceramic matrix composites (CMC) with high structural reliability. These requirements are discussed in general and examples are presented of how these property guidelines are influencing fiber evaluation and improvement studies at NASA aimed at developing structurally reliable MMC and CMC for advanced gas turbine engines.

  13. Involvement of Programmed Cell Death in Neurotoxicity of Metallic Nanoparticles: Recent Advances and Future Perspectives

    NASA Astrophysics Data System (ADS)

    Song, Bin; Zhou, Ting; Liu, Jia; Shao, LongQuan

    2016-11-01

    The widespread application of metallic nanoparticles (NPs) or NP-based products has increased the risk of exposure to NPs in humans. The brain is an important organ that is more susceptible to exogenous stimuli. Moreover, any impairment to the brain is irreversible. Recently, several in vivo studies have found that metallic NPs can be absorbed into the animal body and then translocated into the brain, mainly through the blood-brain barrier and olfactory pathway after systemic administration. Furthermore, metallic NPs can cross the placental barrier to accumulate in the fetal brain, causing developmental neurotoxicity on exposure during pregnancy. Therefore, metallic NPs become a big threat to the brain. However, the mechanisms underlying the neurotoxicity of metallic NPs remain unclear. Programmed cell death (PCD), which is different from necrosis, is defined as active cell death and is regulated by certain genes. PCD can be mainly classified into apoptosis, autophagy, necroptosis, and pyroptosis. It is involved in brain development, neurodegenerative disorders, psychiatric disorders, and brain injury. Given the pivotal role of PCD in neurological functions, we reviewed relevant articles and tried to summarize the recent advances and future perspectives of PCD involvement in the neurotoxicity of metallic NPs, with the purpose of comprehensively understanding the neurotoxic mechanisms of NPs.

  14. Advances in atmospheric light scattering theory and remote-sensing techniques

    NASA Astrophysics Data System (ADS)

    Videen, Gorden; Sun, Wenbo; Gong, Wei

    2017-02-01

    This issue focuses especially on characterizing particles in the Earth-atmosphere system. The significant role of aerosol particles in this system was recognized in the mid-1970s [1]. Since that time, our appreciation for the role they play has only increased. It has been and continues to be one of the greatest unknown factors in the Earth-atmosphere system as evidenced by the most recent Intergovernmental Panel on Climate Change (IPCC) assessments [2]. With increased computational capabilities, in terms of both advanced algorithms and in brute-force computational power, more researchers have the tools available to address different aspects of the role of aerosols in the atmosphere. In this issue, we focus on recent advances in this topical area, especially the role of light scattering and remote sensing. This issue follows on the heels of four previous topical issues on this subject matter that have graced the pages of this journal [3-6].

  15. Theory of transmission of light by sub-wavelength cylindrical holes in metallic films.

    PubMed

    García, N; Bai, Ming

    2006-10-16

    This paper presents theory and finite-difference time-domain (FDTD) calculations for a single and arrays of sub-wavelength cylindrical holes in metallic films presenting large transmission. These calculations are in excellent agreement with experimental measurements. This effect has to be understood in terms of the properties exhibited by the dielectric constant of metals which cannot be treated as ideal metals for the purpose of transmission and diffraction of light. We discuss the cases of well-differentiated metals silver and tungsten. It is found that the effect of surface plasmons or other surface wave excitations due to a periodical set of holes or other roughness at the surface is marginal. The effect can enhance but also can depress the transmission of the arrays as shown by theory and experiments. The peak structure observed in experiments is a consequence of the interference of the wavefronts transmitted by each hole and is determined by the surface array period independently of the material. Without large transmission through a single hole there is no large transmission through the array. We found that in the case of Ag which at the discussed frequencies is a metal there are cylindrical plasmons at the wall of the hole, as reported by Economu et al 30 years ago, that enhanced the transmission. But it turns out, as will be explained, that for the case of W which behaves as a dielectric, there is also a large transmission when compared with that of an ideal metal waveguide at large wavelengths. To deal with this problem one has to use the measured dielectric function of the metals. We discuss thoroughly all these cases and compare with the data. We notice that to discuss these data, for a single hole's transmission, in terms of the Bethe approximation of ideal metals is misleading. Therefore, the extraordinary enhancement of the transmission for the holes arrays versus the single hole does not exist.

  16. Analysis of insertion device magnet measurements for the Advanced Light Source

    SciTech Connect

    Marks, S.; Humphries, D.; Kincaid, B.M.; Schlueter, R.; Wang, C.

    1993-07-01

    The Advanced Light Source (ALS), which is currently being commissioned at Lawrence Berkeley Laboratory, is a third generation light source designed to produce XUV radiation of unprecedented brightness. To meet the high brightness goal the storage ring has been designed for very small electron beam emittance and the undulators installed in the ALS are built to a high degree of precision. The allowable magnetic field errors are driven by electron beam and radiation requirements. Detailed magnetic measurements and adjustments are performed on each undulator to qualify it for installation in the ALS. The first two ALS undulators, IDA and IDB, have been installed. This paper describes the program of measurements, data analysis, and adjustments carried out for these two devices. Calculations of the radiation spectrum, based upon magnetic measurements, are included. Final field integral distributions are also shown. Good field integral uniformity has been achieved using a novel correction scheme, which is also described.

  17. Analysis of insertion device magnet measurements for the advanced light source

    NASA Astrophysics Data System (ADS)

    Marks, Steve; Humphries, David E.; Kincaid, Brian M.; Schlueter, Ross D.; Wang, Chunxi

    1993-11-01

    The Advanced Light Source (ALS), which is currently being commissioned at Lawrence Berkeley Laboratory, is a third generation light source designed to produce XUV radiation of unprecedented brightness. To meet the high brightness goal the storage ring has been designed for very small electron beam emittance and the undulators installed in the ALS are built to a high degree of precision. The allowable magnetic field errors are driven by electron beam and radiation requirements. Detailed magnetic measurements and adjustments are performed on each undulator to qualify it for installation in the ALS. The first two ALS undulators, IDA and IDB, have been installed. This paper describes the program of measurements, data analysis, and adjustments carried out for these two devices. Calculations of the radiation spectrum, based upon magnetic measurements, are included. Final field integral distributions are also shown. Good field integral uniformity has been achieved using a novel correction scheme, which is also described.

  18. The Advanced Light Source at the Lawrence Berkeley Laboratory (ALS, LBL)

    SciTech Connect

    Jackson, A.

    1990-08-01

    The Advanced Light Source (ALS), a national facility currently under construction at the Lawrence Berkeley Laboratory (LBL), is a third-generation synchrotron light source designed to produce extremely bright beams of synchrotron radiation, in the energy range from a few eV to 10 keV. The design is based on a 1-1.9 GeV electron storage ring (optimized at 1.5 GeV), and utilizes special magnets, known as undulators and wigglers (collectively referred to as insertion devices), to generate the radiation. In this paper we describe the main accelerator components of the ALS, the variety of insertion devices, the radiation spectra expected from these devices, and the complement of experiments that have been approved for initial operation, starting in April 1993.

  19. Hybrid nuclear light bulb-nuclear-pumped laser propulsion for advanced missions

    NASA Astrophysics Data System (ADS)

    Miley, G. H.

    1999-01-01

    A hybrid ``nuclear light bulb'' gaseous core reactor that can radiantly transfer energy to a propellant or alternately activate laser action is proposed for advanced space missions. The propellant mode would be employed in the phases of the mission requiring a higher thrust. However, for the bulk of the travel, the propellant would be turned off and the ultrahigh specific impulse laser mode of operation would be employed. The concept is reviewed, research and development issues are identified, and steps necessary for a feasibility demonstration are discussed.

  20. Advanced Light Source Compendium of User Abstracts andTechnical Reports 1997

    SciTech Connect

    Cross, J.; Devereaux, M.K.; Dixon, D.J.; Greiner, A.; editors

    1998-07-01

    The Advanced Light Source (ALS), a national user facility located at Ernest Orlando Lawrence Berkeley National Laboratory of the University of California is available to researchers from academia, industry, and government laboratories. Operation of the ALS is funded by the Department of Energy's Office of Basic Energy Sciences. This Compendium contains abstracts written by users summarizing research completed or in progress during 1997, ALS technical reports describing ongoing efforts related to improvement in machine operations and research and development projects, and information on ALS beamlines planned through 1998.

  1. Design developments for advanced general aviation aircraft. [using Fly By Light Control

    NASA Technical Reports Server (NTRS)

    Roskam, Jan; Gomer, Charles

    1991-01-01

    Design study results are presented for two advanced general-aviation aircraft incorporating fly-by-light/fly-by-wire controls and digital avionics and cockpit displays. The design exercise proceeded from a database of information derived from a market survey for the 4-10 passenger aircraft range. Pusher and tractor propeller configurations were treated, and attention was given to the maximization of passenger comfort. 'Outside-in' tooling methods were assumed for the primary structures of both configurations, in order to achieve surface tolerances which maximize the rearward extent of laminar flow.

  2. Fabrication and test of prototype ring magnets for the ALS (Advanced Light Source)

    SciTech Connect

    Tanabe, J.; Avery, R.; Caylor, R.; Green, M.I.; Hoyer, E.; Halbach, K.; Hernandez, S.; Humphries, D.; Kajiyama, Y.; Keller, R.; Low, W.; Marks, S.; Milburn, J.; Yee, D.

    1989-03-01

    Prototype Models for the Advanced Light Source (ALS) Booster Dipole, Quadrupole and Sextupole and the Storage Ring Gradient Magnet, Quadrupole and Sextupole have been constructed. The Booster Magnet Prototypes have been tested. The Storage Ring Magnets are presently undergoing tests and magnetic measurements. This paper reviews the designs and parameters for these magnets, briefly describes features of the magnet designs which respond to the special constraints imposed by the requirements for both accelerator rings, and reviews some of the results of magnet measurements for the prototype. 13 refs., 7 figs., 1 tab.

  3. The Advanced Light Source: A new tool for research in atomic and molecular physics

    NASA Astrophysics Data System (ADS)

    Schlachter, F.; Robinson, A.

    1991-04-01

    The Advanced Light Source at the Lawrence Berkeley Laboratory will be the world's brightest synchrotron radiation source in the extreme ultraviolet and soft x-ray regions of the spectrum when it begins operation in 1993. It will be available as a national user facility to researchers in a broad range of disciplines, including materials science, atomic and molecular physics, chemistry, biology, imaging, and technology. The high brightness of the ALS will be particularly well suited to high-resolution studies of tenuous targets, such as excited atoms, ions, and clusters.

  4. A directly cooled grating substrate for ALS (Advanced Light Source) undulator beam lines

    SciTech Connect

    DiGennaro, R.; Swain, T.

    1989-08-01

    Design analyses using finite element methods are presented for thermal distortion of water-cooled diffraction grating substrates for a potential application at the LBL Advanced Light Source, demonstrating that refinements in cooling channel configuration and heat flux distribution can significantly reduce optical surface distortion with high heat loads. Using an existing grating substrate design, sensitivity of tangential slope errors due to thermal distortion is evaluated for a variety of thermal boundary conditions, including coolant flow rate and heat transfer film coefficients, surface illumination area and heat distribution profile, and location of the convection cooling surfaces adjacent to the heated region. 1 ref., 5 figs., 2 tabs.

  5. Utility leadership in reopening the nuclear option with advanced light water reactors

    SciTech Connect

    Marston, T.U.; Layman, W.H. )

    1992-01-01

    Since 1981, the Electric Power Research Institute (EPRI) has been pursing the development of the advanced light water reactor (ALWR). The ALWR Program is comprised of five phases and are described in the paper. In order to meet the anticipated baseline power generation requirements in the US, the Nuclear Power Oversight Committee (NPOC) has developed a strategic plan for ALWR implementation in order to regain the nuclear option in the United States. The paper also covers the policies behind the utility requirements, the status of ALWR developments in the United States, the electricity demands during the period 1990-2010, and some of the innovative features of the passive plants presently under design.

  6. Successful Completion of the Top-off Upgrade of the Advanced Light Source

    SciTech Connect

    Steier, C.; Bailey, B.; Baptiste, K.; Barry, W.; Biocca, A.; Byrne, W.; Casey, P.; Chin, M.; Donahue, R.; Duarte, R.; Fahmie, M.; Gath, B.; Jacobson, S.; Julian, J.; Jung, J. Y.; Kritscher, M.; Kwiatkowski, S.; Marks, S.; McKean, P.; Mueller, R.

    2010-06-23

    An upgrade of the Advanced Light Source (ALS) to enable top-off operation has been completed during the last four years. The final work centered around radiation safety aspects, culminating in a systematic proof that top-off operation is equally safe as decaying beam operation. Commissioning and transition to full user operations happened in late 2008 and early 2009. Top-off operation at the ALS provides a very large increase in time-averaged brightness (by about a factor of 10) as well as improvements in beam stability. The following sections provide an overview of the radiation safety rationale, commissioning results, as well as experience in user operations.

  7. The Advanced Light Source: A third-generation Synchrotron Radiation Source

    SciTech Connect

    Robinson, Arthur L.

    2002-08-14

    The Advanced Light Source (ALS) at the E.O. Lawrence Berkeley National Laboratory (Berkeley Lab) of the University of California is a ''third-generation'' synchrotron radiation source optimized for highest brightness at ultraviolet and soft x-ray photon energies. It also provides world-class performance at hard x-ray photon energies. Berkeley Lab operates the ALS for the United States Department of Energy as a national user facility that is available 24 hours/day around the year for research by scientists from industrial, academic, and government laboratories primarily from the United States but also from abroad.

  8. Realizing the benefits of restored periodicity in the advanced light source

    NASA Astrophysics Data System (ADS)

    Robin, D.; Safranek, J.; Decking, W.

    1999-04-01

    An essential feature of third generation storage ring based light sources is the magnetic lattice is designed with a high degree of periodicity. Tracking simulations show that if the periodicity is perturbed (by focusing errors, for example), nonlinear resonances become excited, which causes a reduction in the dynamic aperture. Therefore it is important to have a method to measure and correct perturbed periodicity. In this paper we study the effect of broken and restored periodicity at an actual third generation light source: the Advanced Light Source at Lawrence Berkeley National Laboratory. First, we show that it is possible to accurately determine the storage ring optic and thus the perturbation of the periodicity by fitting measured orbit response matrices. This method allows us to determine individual field gradient errors in quadrupoles and closed orbit errors in sextupoles. By varying individual quadrupole field strengths it is possible to correct the optic, largely restoring the lattice periodicity. A comparison is made of the performance of the storage ring before and after the optic is corrected. Measurements of the electron beam tails and the synchrotron light image reveal a large suppression in resonance excitation after the optic is corrected. Correcting the optic also improves the injection efficiency.

  9. Enhanced Performance of the Advanced Light Source through Periodicity Restoration of the Linear Lattice

    NASA Astrophysics Data System (ADS)

    Robin, D.; Steier, C.; Safranek, J.; Decking, W.

    2002-01-01

    An essential feature of third generation storage ring based light sources is the magnetic lattice is designed with a high degree of periodicity. Tracking simulations show that if the periodicity is perturbed (by focusing errors for example), non-linear resonances become excited, which causes a reduction in the dynamic aperture. Therefore it is important to have a method to measure and correct perturbed periodicity. In this paper we study the effect of broken and restored periodicity at an actual third generation light source: the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory. First we show that it is possible to accurately determine the storage ring optic and thus the perturbation of the periodicity by fitting measured orbit response matrices. This method allows us to determine individual field gradient errors in quadrupoles and closed orbit errors in sextupoles. By varying individual quadrupole field strengths it is possible to correct the optic, largely restoring the lattice periodicity. A comparison is made of the performance of the ALS before and after the optic is corrected. Measurements of the electron beam tails and the synchrotron light image reveal a large suppression in resonance excitation after the optic is corrected. Correcting the optic also improves the injection efficiency and lifetime.

  10. Efficient nanorod-based amorphous silicon solar cells with advanced light trapping

    NASA Astrophysics Data System (ADS)

    Kuang, Y.; van Lare, M. C.; Veldhuizen, L. W.; Polman, A.; Rath, J. K.; Schropp, R. E. I.

    2015-11-01

    We present a simple, low-cost, and scalable approach for the fabrication of efficient nanorod-based solar cells. Templates with arrays of self-assembled ZnO nanorods with tunable morphology are synthesized by chemical bath deposition using a low process temperature at 80 °C. The nanorod templates are conformally coated with hydrogenated amorphous silicon light absorber layers of 100 nm and 200 nm thickness. An initial efficiency of up to 9.0% is achieved for the optimized design. External quantum efficiency measurements on the nanorod cells show a substantial photocurrent enhancement both in the red and the blue parts of the solar spectrum. Key insights in the light trapping mechanisms in these arrays are obtained via a combination of three-dimensional finite-difference time-domain simulations, optical absorption, and external quantum efficiency measurements. Front surface patterns enhance the light incoupling in the blue, while rear side patterns lead to enhanced light trapping in the red. The red response in the nanorod cells is limited by absorption in the patterned Ag back contact. With these findings, we develop and experimentally realize a further advanced design with patterned front and back sides while keeping the Ag reflector flat, showing significantly enhanced scattering from the back reflector with reduced parasitic absorption in the Ag and thus higher photocurrent generation. Many of the findings in this work can serve to provide insights for further optimization of nanostructures for thin-film solar cells in a broad range of materials.

  11. Tunable white light emission in Parallel Tandem OLEDs made with silver metal as interlayer

    NASA Astrophysics Data System (ADS)

    Oliva, Jorge; Papadimitratos, Alexios; Zakhidov, Anvar; UT Dallas Team

    Parallel tandem organic light emitting diodes (OLEDs) which consisted in a top and bottom subunits, and joined with a thin layer of silver (interlayer) were fabricated. In this parallel tandem architecture the Ag metal is an active common anode, which permitted to inject holes into top and bottom subunits. Both subunits of the tandem can thus be connected functionally in a new geometry and addressed separately. Those Tandems had a yellow emitter (a mixture of MEH-PPV and TFB polymers) in the bottom subunit and a blue emitting molecule in the top subunit. The simultaneous combination of the emitted yellow and blue light when both subunits are operating produced white light. We could tune the white light from cool (CIE: 0.33, 0.25) to warm (CIE: 0.38, 0.39) by changing the intensity of the yellow light, that in turn depends on the ratio of MEH-PPV/TFB mixture used to make the emitting layer in the bottom subunit. We also compared the performance of the parallel tandem with these in series and we found additional advantages of the parallel architecture over the configuration for the series tandems such as: tunable chromaticity, lower turn on voltage (4V compared to 7V in the in-series tandem) and higher brightness. The best CIE coordinate we obtained for white light was (0.35, 0.35) which is near the ideal coordinate of (0.33,0.33).

  12. Managing light polarization via plasmon-molecule interactions within an asymmetric metal nanoparticle trimer

    SciTech Connect

    Shegai, Timur; Li, Zhipeng; Zhang, Zhenyu; Xu, Hongxing; Haran, Gilad

    2008-01-01

    The interaction of light with metal nanoparticles leads to novel phenomena mediated by surface plasmon excitations. In this paper we use single molecules to characterize the interaction of surface plasmons with light, and show that such interaction can strongly modulate the polarization of the emitted light. The simplest nanostructures that enable such polarization modulation are asymmetric silver nanocrystal trimers, where individual Raman scattering molecules are located in the gap between two of the nanoparticles. The third particle breaks the dipolar symmetry of the two-particle junction, generating a wavelength-dependent polarization pattern. Indeed, the scattered light becomes elliptically polarized and its intensity pattern is rotated in the presence of the third particle. We use a combination of spectroscopic observations on single molecules, scanning electron microscope imaging, and generalized Mie theory calculations to provide a full picture of the effect of particles on the polarization of the emitted light. Furthermore, our theoretical analysis allows us to show that the observed phenomenon is very sensitive to the size of the trimer particles and their relative position, suggesting future means for precise control of light polarization on the nanoscale.

  13. Chromatic aberration of light focusing in hyperbolic anisotropic metamaterial made of metallic slit array.

    PubMed

    Guo, Kai; Liu, Jianlong; Zhang, Yan; Liu, Shutian

    2012-12-17

    The dispersion of a hyperbolic anisotropic metamaterial (HAM) and the chromatic aberration of light focusing in this kind of HAM are studied. The HAM is formed by alternately stacking metal and dielectric layers. The rules of materials and filling factors affecting the optical property of HAM are given. The chromatic aberration of light focusing is demonstrated both theoretically and numerically. By comparing the theory with the simulation results, the factors influencing the focal length, including the heat loss of material and low spatial frequency modes, are discussed. The investigation emphasizes the anomalous properties, such as chromatic aberration and low spatial frequency modes influencing focus position, of HAM compared with that in conventional lens. Based on the analysis, the possibility of using HAM to focus light with two different wavelengths at the same point is studied.

  14. Measurement of the Radiation Incident on NbFeB Insertion Devices at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Krebs, Gary; Holmes, Michael

    1997-05-01

    The Lawrence Berkeley National Laboratories Advanced Light Source is a third generation light source containing NdFeB permanent magnet insertion devices.The lifetime of the permanent magnets in a radiation environment is of paramount importance. Measurements of the radiation incident on the insertion device magnets under various operating conditions are presented.

  15. Light-triggered self-construction of supramolecular organic nanowires as metallic interconnects

    NASA Astrophysics Data System (ADS)

    Faramarzi, Vina; Niess, Frédéric; Moulin, Emilie; Maaloum, Mounir; Dayen, Jean-François; Beaufrand, Jean-Baptiste; Zanettini, Silvia; Doudin, Bernard; Giuseppone, Nicolas

    2012-06-01

    The construction of soft and processable organic material able to display metallic conduction properties—a large density of freely moving charges—is a major challenge for electronics. Films of doped conjugated polymers are widely used as semiconductor devices, but metallic-type transport in the bulk of such materials remains extremely rare. On the other hand, single-walled carbon nanotubes can exhibit remarkably low contact resistances with related large currents, but are intrinsically very difficult to isolate and process. Here, we describe the self-assembly of supramolecular organic nanowires between two metallic electrodes, from a solution of triarylamine derivative, under the simultaneous action of light and electric field triggers. They exhibit a combination of large conductivity values (>5 × 103 S m-1) and a low interface resistance (<2 × 10-4 Ω m). Moreover, the resistance of nanowires in series with metal interfaces systematically decreases when the temperature is lowered to 1.5 K, revealing an intrinsic metallic behaviour.

  16. Light-triggered self-construction of supramolecular organic nanowires as metallic interconnects.

    PubMed

    Faramarzi, Vina; Niess, Frédéric; Moulin, Emilie; Maaloum, Mounir; Dayen, Jean-François; Beaufrand, Jean-Baptiste; Zanettini, Silvia; Doudin, Bernard; Giuseppone, Nicolas

    2012-04-22

    The construction of soft and processable organic material able to display metallic conduction properties-a large density of freely moving charges-is a major challenge for electronics. Films of doped conjugated polymers are widely used as semiconductor devices, but metallic-type transport in the bulk of such materials remains extremely rare. On the other hand, single-walled carbon nanotubes can exhibit remarkably low contact resistances with related large currents, but are intrinsically very difficult to isolate and process. Here, we describe the self-assembly of supramolecular organic nanowires between two metallic electrodes, from a solution of triarylamine derivative, under the simultaneous action of light and electric field triggers. They exhibit a combination of large conductivity values (>5 × 10(3) S m(-1)) and a low interface resistance (<2 × 10(-4) Ω m). Moreover, the resistance of nanowires in series with metal interfaces systematically decreases when the temperature is lowered to 1.5 K, revealing an intrinsic metallic behaviour.

  17. The use of visible light and metal oxide nano particles for pathogen inactivation

    NASA Astrophysics Data System (ADS)

    Lubart, R.; Lipovski, A.; Gedanken, A.

    2012-09-01

    Since the effectiveness of antibiotic treatment is decreasing due to the development of resistant strains, alternative approaches for destroying microorganisms are needed. In this review we summarize new technologies that might be effective for pathogen inactivation. In the past we found that intense blue light could be used for bacterial eradication. The phototoxic effect correlated with the amount of reactive oxygen species (ROS) generated by the bacteria due to illumination. Recently it has been shown that the effect of light can be enhanced by introducing metal oxide nanoparticles (nps) to the bacteria prior to irradiation. This led us to suggest combining nanoparticles with visible light irradiation for pathogen eradication. We have shown that combination of illumination with the nanoparticles (ZnO or TiO2) resulted in a marked increase in the reduction of bacterial viability to a mean reduction of 80-90% for both nanoaprticles. As a matter of fact metal oxide nps alone can be used for bacteria destruction. The advantage of our approach is the use of lower concentrations of nps, combined with reduced light intensity that is less toxic to the host tissue. To further avoid the toxicity of metal oxides nps on healthy tissue it is possible to coat their surfaces with various substrates including ceramics and polymers. Recently Zinc oxide nanoparticles have been synthesized and deposited on the surface of cotton fabrics using ultrasound irradiation. Thus in the future we will try to treat infected wounds with transparent bandages coated with ZnO that will be applied to the wounds prior to irradiation.

  18. Influence of Light Conditions and Light Sources on Clinical Measurement of Natural Teeth Color using VITA Easyshade Advance 4,0® Spectrophotometer. Pilot Study.

    PubMed Central

    Posavec, Ivona; Prpić, Vladimir

    2016-01-01

    Objectives The purpose of this study was to evaluate and compare lightness (L), chroma (C) and hue (h), green-red (a) and blue-yellow (b) character of the color of maxillary right central incisors in different light conditions and light sources. Materials and methods Two examiners who were well trained in digital color evaluation participated in the research. Intraclass correlation coefficients (ICCs) were used to analyze intra- and interobserver reliability. The LCh and L*a*b* values were determined at 08.15 and at 10.00 in the morning under three different light conditions. Tooth color was assessed in 10 subjects using intraoral spectrophotometer VITA Easyshade Advance 4.0® set at the central region of the vestibular surface of the measured tooth. Results Intra- and interobserver ICC values were high for both examiners and ranged from 0.57 to 0.99. Statistically significant differences in LCh and L*a*b* values measured in different time of the day and certain light condition were not found (p>0.05). Statistically significant differences in LCh and L*a*b* values measured under three different light conditions were not found, too (p>0.05). Conclusions VITA Easyshade Advance 4.0® is reliable enough for daily clinical work in order to assess tooth color during the fabrication of esthtic appliances because it is not dependent on light conditions and light sources. PMID:28275281

  19. Recent advances in visible-light-responsive photocatalysts for hydrogen production and solar energy conversion--from semiconducting TiO2 to MOF/PCP photocatalysts.

    PubMed

    Horiuchi, Yu; Toyao, Takashi; Takeuchi, Masato; Matsuoka, Masaya; Anpo, Masakazu

    2013-08-28

    The present perspective describes recent advances in visible-light-responsive photocatalysts intended to develop novel and efficient solar energy conversion technologies, including water splitting and photofuel cells. Water splitting is recognized as one of the most promising techniques to convert solar energy as a clean and abundant energy resource into chemical energy in the form of hydrogen. In recent years, increasing concern is directed to not only the development of new photocatalytic materials but also the importance of technologies to produce hydrogen and oxygen separately. Photofuel cells can convert solar energy into electrical energy by decomposing bio-related compounds and livestock waste as fuels. The advances of photocatalysts enabling these solar energy conversion technologies have been going on since the discovery of semiconducting titanium dioxide materials and have extended to organic-inorganic hybrid materials, such as metal-organic frameworks and porous coordination polymers (MOF/PCP).

  20. Effect of etching time and light source on the bond strength of metallic brackets to ceramic.

    PubMed

    Gonçalves, Paulo Roberto Amaral; Moraes, Rafael Ratto de; Costa, Ana Rosa; Correr, Américo Bortolazzo; Nouer, Paulo Roberto Aranha; Sinhoreti, Mário Alexandre Coelho; Correr-Sobrinho, Lourenço

    2011-01-01

    This study evaluated the bond strength of brackets to ceramic testing different etching times and light sources for photo-activation of the bonding agent. Cylinders of feldspathic ceramic were etched with 10% hydrofluoric acid for 20 or 60 s. After application of silane on the ceramic surface, metallic brackets were bonded to the cylinders using Transbond XT (3M Unitek). The specimens for each etching time were assigned to 4 groups (n=15), according to the light source: XL2500 halogen light, UltraLume 5 LED, AccuCure 3000 argon laser, and Apollo 95E plasma arc. Light-activation was carried out with total exposure times of 40, 40, 20 and 12 s, respectively. Shear strength testing was carried out after 24 h. The adhesive remnant index (ARI) was evaluated under magnification. Data were subjected to two-way ANOVA and Tukey's test (α=0.05). Specimens etched for 20 s presented significantly lower bond strength (p<0.05) compared with those etched for 60 s. No significant differences (p>0.05) were detected among the light sources. The ARI showed a predominance of scores 0 in all groups, with an increase in scores 1, 2 and 3 for the 60 s time. In conclusion, only the etching time had significant influence on the bond strength of brackets to ceramic.

  1. Structural Effects in Visible-Light-Responsive Metal-Organic Frameworks Incorporating ortho-Fluoroazobenzenes.

    PubMed

    Castellanos, Sonia; Goulet-Hanssens, Alexis; Zhao, Fangli; Dikhtiarenko, Alla; Pustovarenko, Alexey; Hecht, Stefan; Gascon, Jorge; Kapteijn, Freek; Bléger, David

    2016-01-11

    The ability to control the interplay of materials with low-energy photons is important as visible light offers several appealing features compared to ultraviolet radiation (less damaging, more selective, predominant in the solar spectrum, possibility to increase the penetration depth). Two different metal-organic frameworks (MOFs) were synthesized from the same linker bearing all-visible ortho-fluoroazobenzene photoswitches as pendant groups. The MOFs exhibit different architectures that strongly influence the ability of the azobenzenes to isomerize inside the voids. The framework built with Al-based nodes has congested 1D channels that preclude efficient isomerization. As a result, local light-heat conversion can be used to alter the CO2 adsorption capacity of the material on exposure to green light. The second framework, built with Zr nodes, provides enough room for the photoswitches to isomerize, which leads to a unique bistable photochromic MOF that readily responds to blue and green light. The superiority of green over UV irradiation was additionally demonstrated by reflectance spectroscopy and analysis of digested samples. This material offers promising perspectives for liquid-phase applications such as light-controlled catalysis and adsorptive separation.

  2. Electrically Driven White Light Emission from Intrinsic Metal-Organic Framework.

    PubMed

    Haider, Golam; Usman, Muhammad; Chen, Tzu-Pei; Perumal, Packiyaraj; Lu, Kuang-Lieh; Chen, Yang-Fang

    2016-09-27

    Light-emitting diodes (LEDs) have drawn tremendous potential as a replacement of traditional lighting due to its low-power consumption and longer lifetime. Nowadays, the practical white LEDs (WLED) are contingent on the photon down-conversion of phosphors containing rare-earth elements, which limits its utility, energy, and cost efficiency. In order to resolve the energy crisis and to address the environmental concerns, designing a direct WLED is highly desirable and remains a challenging issue. To circumvent the existing difficulties, in this report, we have designed and demonstrated a direct WLED consisting of a strontium-based metal-organic framework (MOF), {[Sr(ntca)(H2O)2]·H2O}n (1), graphene, and inorganic semiconductors, which can generate a bright white light emission. In addition to the suitable design of a MOF structure, the demonstration of electrically driven white light emission based on a MOF is made possible by the combination of several factors including the unique properties of graphene and the appropriate band alignment between the MOF and semiconductor layer. Because electroluminescence using a MOF as an active material is very rare and intriguing and a direct WLED is also not commonly seen, our work here therefore represents a major discovery which should be very useful and timely for the development of solid-state lighting.

  3. Thermodynamic limit to photonic-plasmonic light-trapping in thin films on metals

    NASA Astrophysics Data System (ADS)

    Schiff, E. A.

    2011-11-01

    We calculate the maximum optical absorptance enhancements in thin semiconductor films on metals due to structures that diffuse light and couple it to surface plasmon polaritons. The calculations can be used to estimate plasmonic effects on light-trapping in solar cells. The calculations are based on the statistical distribution of energy in the electromagnetic modes of the structure, which include surface plasmon polariton modes at the metal interface as well as the trapped waveguide modes in the film. The enhancement has the form 4n2+nλ/h (n - film refractive index, λ - optical wavelength, h - film thickness), which is an increase beyond the non-plasmonic "classical" enhancement 4n2. Larger resonant enhancements occur for wavelengths near the surface plasmon frequency; these add up to 2 mA/cm2 to the photocurrent of a solar cell based on a 500 nm film of crystalline silicon. We also calculated the effects of plasmon dissipation in the metal. Dissipation rates typical of silver reverse the resonant enhancement effect for silicon, but a non-resonant enhancement remains.

  4. Diversity of Abundance Patterns of Light Neutron-capture Elements in Very-metal-poor Stars

    NASA Astrophysics Data System (ADS)

    Aoki, Misa; Ishimaru, Yuhri; Aoki, Wako; Wanajo, Shinya

    2017-03-01

    We determine the abundances of neutron-capture elements from Sr to Eu for five very-metal-poor stars (-3 < [{Fe}/{{H}}] < -2) in the Milky Way halo to reveal the origin of light neutron-capture elements. Previous spectroscopic studies have shown evidence of at least two components in the r-process; one referred to as the “main r-process” and the other as the “weak r-process,” which is mainly responsible for producing heavy and light neutron-capture elements, respectively. Observational studies of metal-poor stars suggest that there is a universal pattern in the main r-process, similar to the abundance pattern of the r-process component of solar-system material. Still, it is uncertain whether the abundance pattern of the weak r-process shows universality or diversity, due to the sparseness of measured light neutron-capture elements. We have detected the key elements, Mo, Ru, and Pd, in five target stars to give an answer to this question. The abundance patterns of light neutron-capture elements from Sr to Pd suggest a diversity in the weak r-process. In particular, scatter in the abundance ratio between Ru and Pd is significant when the abundance patterns are normalized at Zr. Our results are compared with the elemental abundances predicted by nucleosynthesis models of supernovae with parameters such as electron fraction or proto-neutron-star mass, to investigate sources of such diversity in the abundance patterns of light neutron-capture elements. This paper presents that the variation in the abundances of observed stars can be explained with a small range of parameters, which can serve as constraints on future modeling of supernova models. Study based on data collected with the Subaru Telescope, operated by the National Astronomical Observatory of Japan.

  5. Metal-enhanced fluorescence of chlorophylls in light-harvesting complexes coupled to silver nanowires.

    PubMed

    Kowalska, Dorota; Krajnik, Bartosz; Olejnik, Maria; Twardowska, Magdalena; Czechowski, Nikodem; Hofmann, Eckhard; Mackowski, Sebastian

    2013-01-01

    We investigate metal-enhanced fluorescence of peridinin-chlorophyll protein coupled to silver nanowires using optical microscopy combined with spectrally and time-resolved fluorescence techniques. In particular we study two different sample geometries: first, in which the light-harvesting complexes are deposited onto silver nanowires, and second, where solution of both nanostructures are mixed prior deposition on a substrate. The results indicate that for the peridinin-chlorophyll complexes placed in the vicinity of the silver nanowires we observe higher intensities of fluorescence emission as compared to the reference sample, where no nanowires are present. Enhancement factors estimated for the sample where the light-harvesting complexes are mixed together with the silver nanowires prior deposition on a substrate are generally larger in comparison to the other geometry of a hybrid nanostructure. While fluorescence spectra are identical both in terms of overall shape and maximum wavelength for peridinin-chlorophyll-protein complexes both isolated and coupled to metallic nanostructures, we conclude that interaction with plasmon excitations in the latter remains neutral to the functionality of the biological system. Fluorescence transients measured for the PCP complexes coupled to the silver nanowires indicate shortening of the fluorescence lifetime pointing towards modifications of radiative rate due to plasmonic interactions. Our results can be applied for developing ways to plasmonically control the light-harvesting capability of photosynthetic complexes.

  6. Metal-clad waveguide characterization for contact-based light transmission into tissue

    NASA Astrophysics Data System (ADS)

    Chininis, Jeffrey; Whiteside, Paul; Hunt, Heather K.

    2016-02-01

    As contemporary laser dermatology procedures, like tattoo removal and skin resurfacing, become more popular, the complications of their operation are also becoming more prevalent. Frequent incidences of over-exposure, ocular injury, and excessive thermal damage represent mounting concerns for those seeking such procedures; moreover, each of these problems is a direct consequence of the standard, free-space method of laser transmission predominantly used in clinical settings. Therefore, an alternative method of light transmission is needed to minimize these problems. Here, we demonstrate and characterize an alternative method that uses planar waveguides to deliver light into sample tissue via direct contact. To do this, slab substrates made from glass were clad in layers of titanium and silver, constraining the light within the waveguide along the waveguide's length. By creating active areas on the waveguide surface, the propagating light could then optically tunnel into the tissue sample, when the waveguide was brought into contact with the tissue. SEM and EDS were used to characterize the metal film thickness and deposition rates onto the glass substrates. Laser light from a Q-switched Nd:YAG source operating at 532nm was coupled into the waveguide and transmitted into samples of pig skin. The amount of light transmitted was measured using photoacoustics techniques, in conjunction with a photodiode and integrating sphere. Transmitting light into tissue in this manner effectively resolves or circumvents the complications caused by free-space propagation methods as it reduces the operating distance to 0, which prevents hazardous back-reflections and allows for the ready incorporation of contact cooling technologies.

  7. Advanced Electrochemistry of Individual Metal Clusters Electrodeposited Atom by Atom to Nanometer by Nanometer.

    PubMed

    Kim, Jiyeon; Dick, Jeffrey E; Bard, Allen J

    2016-11-15

    Metal clusters are very important as building blocks for nanoparticles (NPs) for electrocatalysis and electroanalysis in both fundamental and applied electrochemistry. Attention has been given to understanding of traditional nucleation and growth of metal clusters and to their catalytic activities for various electrochemical applications in energy harvesting as well as analytical sensing. Importantly, understanding the properties of these clusters, primarily the relationship between catalysis and morphology, is required to optimize catalytic function. This has been difficult due to the heterogeneities in the size, shape, and surface properties. Thus, methods that address these issues are necessary to begin understanding the reactivity of individual catalytic centers as opposed to ensemble measurements, where the effect of size and morphology on the catalysis is averaged out in the measurement. This Account introduces our advanced electrochemical approaches to focus on each isolated metal cluster, where we electrochemically fabricated clusters or NPs atom by atom to nanometer by nanometer and explored their electrochemistry for their kinetic and catalytic behavior. Such approaches expand the dimensions of analysis, to include the electrochemistry of (1) a discrete atomic cluster, (2) solely a single NP, or (3) individual NPs in the ensemble sample. Specifically, we studied the electrocatalysis of atomic metal clusters as a nascent electrocatalyst via direct electrodeposition on carbon ultramicroelectrode (C UME) in a femtomolar metal ion precursor. In addition, we developed tunneling ultramicroelectrodes (TUMEs) to study electron transfer (ET) kinetics of a redox probe at a single metal NP electrodeposited on this TUME. Owing to the small dimension of a NP as an active area of a TUME, extremely high mass transfer conditions yielded a remarkably high standard ET rate constant, k(0), of 36 cm/s for outer-sphere ET reaction. Most recently, we advanced nanoscale

  8. METALLICITY AS A SOURCE OF DISPERSION IN THE SNIa BOLOMETRIC LIGHT CURVE LUMINOSITY-WIDTH RELATIONSHIP

    SciTech Connect

    Bravo, E.; DomInguez, I.; Badenes, C.; Piersanti, L.; Straniero, O. E-mail: inma@ugr.es

    2010-03-10

    The recognition that the metallicity of Type Ia supernova (SNIa) progenitors might bias their use for cosmological applications has led to an increasing interest in its role in shaping SNIa light curves. We explore the sensitivity of the synthesized mass of {sup 56}Ni, M({sup 56}Ni), to the progenitor metallicity starting from pre-main-sequence models with masses M {sub 0} = 2-7 M {sub sun} and metallicities Z = 10{sup -5}-0.10. The interplay between convective mixing and carbon burning during the simmering phase eventually raises the neutron excess, {eta}, and leads to a smaller {sup 56}Ni yield, but does not change substantially the dependence of M({sup 56}Ni) on Z. Uncertain attributes of the progenitor white dwarf, like the central density, have a minor effect on M({sup 56}Ni). Our main results are: (1) a sizeable amount of {sup 56}Ni is synthesized during incomplete Si-burning, which leads to a stronger dependence of M({sup 56}Ni) on Z than obtained by assuming that {sup 56}Ni is produced in material that burns fully to nuclear statistical equilibrium; (2) in one-dimensional delayed detonation simulations a composition dependence of the deflagration-to-detonation transition (DDT) density gives a nonlinear relationship between M({sup 56}Ni) and Z and predicts a luminosity larger than previously thought at low metallicities (however, the progenitor metallicity alone cannot explain the whole observational scatter of SNIa luminosities); and (3) an accurate measurement of the slope of the Hubble residuals versus metallicity for a large enough data set of SNIa might give clues to the physics of DDT in thermonuclear explosions.

  9. Metallicity as a Source of Dispersion in the SNIa Bolometric Light Curve Luminosity-Width Relationship

    NASA Astrophysics Data System (ADS)

    Bravo, E.; Domínguez, I.; Badenes, C.; Piersanti, L.; Straniero, O.

    2010-03-01

    The recognition that the metallicity of Type Ia supernova (SNIa) progenitors might bias their use for cosmological applications has led to an increasing interest in its role in shaping SNIa light curves. We explore the sensitivity of the synthesized mass of 56Ni, M(56Ni), to the progenitor metallicity starting from pre-main-sequence models with masses M 0 = 2-7 M sun and metallicities Z = 10-5-0.10. The interplay between convective mixing and carbon burning during the simmering phase eventually raises the neutron excess, η, and leads to a smaller 56Ni yield, but does not change substantially the dependence of M(56Ni) on Z. Uncertain attributes of the progenitor white dwarf, like the central density, have a minor effect on M(56Ni). Our main results are: (1) a sizeable amount of 56Ni is synthesized during incomplete Si-burning, which leads to a stronger dependence of M(56Ni) on Z than obtained by assuming that 56Ni is produced in material that burns fully to nuclear statistical equilibrium; (2) in one-dimensional delayed detonation simulations a composition dependence of the deflagration-to-detonation transition (DDT) density gives a nonlinear relationship between M(56Ni) and Z and predicts a luminosity larger than previously thought at low metallicities (however, the progenitor metallicity alone cannot explain the whole observational scatter of SNIa luminosities); and (3) an accurate measurement of the slope of the Hubble residuals versus metallicity for a large enough data set of SNIa might give clues to the physics of DDT in thermonuclear explosions.

  10. Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants

    PubMed Central

    2016-01-01

    Conspectus The development of efficient catalytic systems for direct aromatic C–H bond functionalization is a long-desired goal of chemists, because these protocols provide environmental friendly and waste-reducing alternatives to classical methodologies for C–C and C–heteroatom bond formation. A key challenge for these transformations is the reoxidation of the in situ generated metal hydride or low-valent metal complexes of the primary catalytic bond forming cycle. To complete the catalytic cycle and to regenerate the C–H activation catalyst, (super)stoichiometric amounts of Cu(II) or Ag(I) salts have often been applied. Recently, “greener” approaches have been developed by applying molecular oxygen in combination with Cu(II) salts, internal oxidants that are cleaved during the reaction, or solvents or additives enabling the metal hydride reoxidation. All these approaches improved the environmental friendliness but have not overcome the obstacles associated with the overall limited functional group and substrate tolerance. Hence, catalytic processes that do not feature the unfavorable aspects described above and provide products in a streamlined as well as economically and ecologically advantageous manner would be desirable. In this context, we decided to examine visible light photoredox catalysis as a new alternative to conventionally applied regeneration/oxidation procedures. This Account summarizes our recent advances in this expanding area and will highlight the new concept of merging distinct redox catalytic processes for C–H functionalizations through the application of visible light photoredox catalysis. Photoredox catalysis can be considered as catalytic electron-donating or -accepting processes, making use of visible-light absorbing homogeneous and heterogeneous metal-based catalysts, as well as organic dye sensitizers or polymers. As a consequence, photoredox catalysis is, in principle, an ideal tool for the recycling of any given metal

  11. Enhanced Endosomal Escape by Light-Fueled Liquid-Metal Transformer.

    PubMed

    Lu, Yue; Lin, Yiliang; Chen, Zhaowei; Hu, Quanyin; Liu, Yang; Yu, Shuangjiang; Gao, Wei; Dickey, Michael D; Gu, Zhen

    2017-03-22

    Effective endosomal escape remains as the "holy grail" for endocytosis-based intracellular drug delivery. To date, most of the endosomal escape strategies rely on small molecules, cationic polymers, or pore-forming proteins, which are often limited by the systemic toxicity and lack of specificity. We describe here a light-fueled liquid-metal transformer for effective endosomal escape-facilitated cargo delivery via a chemical-mechanical process. The nanoscale transformer can be prepared by a simple approach of sonicating a low-toxicity liquid-metal. When coated with graphene quantum dots (GQDs), the resulting nanospheres demonstrate the ability to absorb and convert photoenergy to drive the simultaneous phase separation and morphological transformation of the inner liquid-metal core. The morphological transformation from nanospheres to hollow nanorods with a remarkable change of aspect ratio can physically disrupt the endosomal membrane to promote endosomal escape of payloads. This metal-based nanotransformer equipped with GQDs provides a new strategy for facilitating effective endosomal escape to achieve spatiotemporally controlled drug delivery with enhanced efficacy.

  12. Helium plasma implantation on metals: Nanostructure formation and visible-light photocatalytic response

    SciTech Connect

    Kajita, Shin; Yoshida, Tomoko; Kitaoka, Daiki; Etoh, Reo; Yajima, Miyuki; Ohno, Noriyasu; Yoshida, Hisao; Yoshida, Naoaki; Terao, Yoshitaka

    2013-04-07

    It has been found recently that low-energy helium (He) plasma irradiation to tungsten (W) leads to the growth of W nanostructures on the surface. The process to grow the nanostructure is identified as a self-growth process of He bubbles and has a potential to open up a new plasma processing method. Here, we show that the metallic nanostructure formation process by the exposure to He plasma can occur in various metals such as, titanium, nickel, iron, and so on. When the irradiation conditions alter, the metallic cone arrays including nanobubbles inside are formed on the surface. Different from W cases, other processes than growth of fiberform structure, i.e., physical sputtering and the growth of large He bubbles, can be dominant on other metals during irradiation; various surface morphology changes can occur. The nanostructured W, part of which was oxidized, has revealed a significant photocatalytic activity under visible light (wavelength >700 nm) in decolorization of methylene blue without any co-catalyst.

  13. Helium plasma implantation on metals: Nanostructure formation and visible-light photocatalytic response

    NASA Astrophysics Data System (ADS)

    Kajita, Shin; Yoshida, Tomoko; Kitaoka, Daiki; Etoh, Reo; Yajima, Miyuki; Ohno, Noriyasu; Yoshida, Hisao; Yoshida, Naoaki; Terao, Yoshitaka

    2013-04-01

    It has been found recently that low-energy helium (He) plasma irradiation to tungsten (W) leads to the growth of W nanostructures on the surface. The process to grow the nanostructure is identified as a self-growth process of He bubbles and has a potential to open up a new plasma processing method. Here, we show that the metallic nanostructure formation process by the exposure to He plasma can occur in various metals such as, titanium, nickel, iron, and so on. When the irradiation conditions alter, the metallic cone arrays including nanobubbles inside are formed on the surface. Different from W cases, other processes than growth of fiberform structure, i.e., physical sputtering and the growth of large He bubbles, can be dominant on other metals during irradiation; various surface morphology changes can occur. The nanostructured W, part of which was oxidized, has revealed a significant photocatalytic activity under visible light (wavelength >700 nm) in decolorization of methylene blue without any co-catalyst.

  14. Efficient nanorod-based amorphous silicon solar cells with advanced light trapping

    SciTech Connect

    Kuang, Y.; Lare, M. C. van; Polman, A.; Veldhuizen, L. W.; Schropp, R. E. I.; Rath, J. K.

    2015-11-14

    We present a simple, low-cost, and scalable approach for the fabrication of efficient nanorod-based solar cells. Templates with arrays of self-assembled ZnO nanorods with tunable morphology are synthesized by chemical bath deposition using a low process temperature at 80 °C. The nanorod templates are conformally coated with hydrogenated amorphous silicon light absorber layers of 100 nm and 200 nm thickness. An initial efficiency of up to 9.0% is achieved for the optimized design. External quantum efficiency measurements on the nanorod cells show a substantial photocurrent enhancement both in the red and the blue parts of the solar spectrum. Key insights in the light trapping mechanisms in these arrays are obtained via a combination of three-dimensional finite-difference time-domain simulations, optical absorption, and external quantum efficiency measurements. Front surface patterns enhance the light incoupling in the blue, while rear side patterns lead to enhanced light trapping in the red. The red response in the nanorod cells is limited by absorption in the patterned Ag back contact. With these findings, we develop and experimentally realize a further advanced design with patterned front and back sides while keeping the Ag reflector flat, showing significantly enhanced scattering from the back reflector with reduced parasitic absorption in the Ag and thus higher photocurrent generation. Many of the findings in this work can serve to provide insights for further optimization of nanostructures for thin-film solar cells in a broad range of materials.

  15. Anomalous refraction of light through slanted-nanoaperture arrays on metal surface

    SciTech Connect

    Kim, Myungji; Jung, Yun Suk; Xi, Yonggang; Kim, Hong Koo

    2015-09-07

    We report a nanoapertured metal surface that demonstrates anomalous refraction of light for a wide range of incident angles. A nanoslit aperture is designed to serve as a tilted vertical-dipole whose radiation pattern orients to a glancing angle direction to substrate. An array of such slanted nanoslits formed in a metal film redirects an incident beam into the direction of negative refraction angle: the aperture-transmitted wave makes a far-field propagation to the tilt-oriented direction of radiation pattern. The thus-designed nanoaperture array demonstrates the −1st order diffraction (i.e., to the negative refraction-angle direction) with well-suppressed background transmission (the zero-order direct transmission and other higher-order diffractions). Engineering the radiation pattern of nanoaperture offers an approach to overcoming the limits of conventional diffractive/refractive optics and complementing metasurface-based nano-optics.

  16. The Effect of Continuous Weathering on Light Metal Alloys Used in Aircraft

    NASA Technical Reports Server (NTRS)

    Mutchler, Willard

    1939-01-01

    An investigation of the corrosion of light metal alloys used in aircraft was begun at the National Bureau of Standards in 1925 and has for its purpose causes of corrosion in aluminum-rich and magnesium-rich alloys together with the development of methods for its prevention. The results, obtained in an extensive series of laboratory and weather-exposure tests, reveal the relative durability of a number of commercially available materials and the extent to which the application of various surface coatings of oxide alone and with paint coatings afforded additional protection. The paper may be considered as a supplement to NACA report 490.

  17. Interaction of electrons with light metal hydrides in the transmission electron microscope.

    PubMed

    Wang, Yongming; Wakasugi, Takenobu; Isobe, Shigehito; Hashimoto, Naoyuki; Ohnuki, Somei

    2014-12-01

    Transmission electron microscope (TEM) observation of light metal hydrides is complicated by the instability of these materials under electron irradiation. In this study, the electron kinetic energy dependences of the interactions of incident electrons with lithium, sodium and magnesium hydrides, as well as the constituting element effect on the interactions, were theoretically discussed, and electron irradiation damage to these hydrides was examined using in situ TEM. The results indicate that high incident electron kinetic energy helps alleviate the irradiation damage resulting from inelastic or elastic scattering of the incident electrons in the TEM. Therefore, observations and characterizations of these materials would benefit from increased, instead decreased, TEM operating voltage.

  18. Metal-halide perovskites for photovoltaic and light-emitting devices.

    PubMed

    Stranks, Samuel D; Snaith, Henry J

    2015-05-01

    Metal-halide perovskites are crystalline materials originally developed out of scientific curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival the leading photovoltaic technologies. Power conversion efficiencies have jumped from 3% to over 20% in just four years of academic research. Here, we review the rapid progress in perovskite solar cells, as well as their promising use in light-emitting devices. In particular, we describe the broad tunability and fabrication methods of these materials, the current understanding of the operation of state-of-the-art solar cells and we highlight the properties that have delivered light-emitting diodes and lasers. We discuss key thermal and operational stability challenges facing perovskites, and give an outlook of future research avenues that might bring perovskite technology to commercialization.

  19. Light-induced metal-like surface of silicon photonic waveguides.

    PubMed

    Grillanda, Stefano; Morichetti, Francesco

    2015-09-11

    The surface of a material may exhibit physical phenomena that do not occur in the bulk of the material itself. For this reason, the behaviour of nanoscale devices is expected to be conditioned, or even dominated, by the nature of their surface. Here, we show that in silicon photonic nanowaveguides, massive surface carrier generation is induced by light travelling in the waveguide, because of natural surface-state absorption at the core/cladding interface. At the typical light intensity used in linear applications, this effect makes the surface of the waveguide behave as a metal-like frame. A twofold impact is observed on the waveguide performance: the surface electric conductivity dominates over that of bulk silicon and an additional optical absorption mechanism arises, that we named surface free-carrier absorption. These results, applying to generic semiconductor photonic technologies, unveil the real picture of optical nanowaveguides that needs to be considered in the design of any integrated optoelectronic device.

  20. Significant light absorption enhancement in silicon thin film tandem solar cells with metallic nanoparticles.

    PubMed

    Cai, Boyuan; Li, Xiangping; Zhang, Yinan; Jia, Baohua

    2016-05-13

    Enhancing the light absorption in microcrystalline silicon bottom cell of a silicon-based tandem solar cell for photocurrent matching holds the key to achieving the overall solar cell performance breakthroughs. Here, we present a concept for significantly improving the absorption of both subcells simultaneously by simply applying tailored metallic nanoparticles both on the top and at the rear surfaces of the solar cells. Significant light absorption enhancement as large as 56% has been achieved in the bottom subcells. More importantly the thickness of the microcrystalline layer can be reduced by 57% without compromising the optical performance of the tandem solar cell, providing a cost-effective strategy for high performance tandem solar cells.

  1. Metal-halide perovskites for photovoltaic and light-emitting devices

    NASA Astrophysics Data System (ADS)

    Stranks, Samuel D.; Snaith, Henry J.

    2015-05-01

    Metal-halide perovskites are crystalline materials originally developed out of scientific curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival the leading photovoltaic technologies. Power conversion efficiencies have jumped from 3% to over 20% in just four years of academic research. Here, we review the rapid progress in perovskite solar cells, as well as their promising use in light-emitting devices. In particular, we describe the broad tunability and fabrication methods of these materials, the current understanding of the operation of state-of-the-art solar cells and we highlight the properties that have delivered light-emitting diodes and lasers. We discuss key thermal and operational stability challenges facing perovskites, and give an outlook of future research avenues that might bring perovskite technology to commercialization.

  2. Passivation of impurities in semiconductors by hydrogen and light metal ions

    NASA Astrophysics Data System (ADS)

    Gislason, Hafliði P.

    1997-01-01

    Books as well as numerous articles have been written about hydrogen passivation in classical semiconductors such as Si and GaAs. The subject has gained a renewed interest recently since hydrogen is widely considered to saturate the hole conductivity of the wide bandgap semiconductors GaN and ZnSe which are currently most promising for blue light emitting devices. Other group-I impurities are capable of compensating the electrical conductivity of semiconductors both through directly neutralising (passivating) the impurity or providing space charge of polarity opposite to that of the dominating one. The paper reviews the similarities and differences between hydrogen and its light metallic neighbour in the periodic table, lithium. Also we provide a comparison with the heavier interstitial copper which is known for its ability to passivate shallow acceptors. Finally fundamental differences between shallow-level and deep level passivation will be addressed.

  3. Light-induced metal-like surface of silicon photonic waveguides

    PubMed Central

    Grillanda, Stefano; Morichetti, Francesco

    2015-01-01

    The surface of a material may exhibit physical phenomena that do not occur in the bulk of the material itself. For this reason, the behaviour of nanoscale devices is expected to be conditioned, or even dominated, by the nature of their surface. Here, we show that in silicon photonic nanowaveguides, massive surface carrier generation is induced by light travelling in the waveguide, because of natural surface-state absorption at the core/cladding interface. At the typical light intensity used in linear applications, this effect makes the surface of the waveguide behave as a metal-like frame. A twofold impact is observed on the waveguide performance: the surface electric conductivity dominates over that of bulk silicon and an additional optical absorption mechanism arises, that we named surface free-carrier absorption. These results, applying to generic semiconductor photonic technologies, unveil the real picture of optical nanowaveguides that needs to be considered in the design of any integrated optoelectronic device. PMID:26359202

  4. Orthogonal Metal Cutting Simulation Using Advanced Constitutive Equations with Damage and Fully Adaptive Numerical Procedure

    NASA Astrophysics Data System (ADS)

    Saanouni, Kkemais; Labergère, Carl; Issa, Mazen; Rassineux, Alain

    2010-06-01

    This work proposes a complete adaptive numerical methodology which uses `advanced' elastoplastic constitutive equations coupling: thermal effects, large elasto-viscoplasticity with mixed non linear hardening, ductile damage and contact with friction, for 2D machining simulation. Fully coupled (strong coupling) thermo-elasto-visco-plastic-damage constitutive equations based on the state variables under large plastic deformation developed for metal forming simulation are presented. The relevant numerical aspects concerning the local integration scheme as well as the global resolution strategy and the adaptive remeshing facility are briefly discussed. Applications are made to the orthogonal metal cutting by chip formation and segmentation under high velocity. The interactions between hardening, plasticity, ductile damage and thermal effects and their effects on the adiabatic shear band formation including the formation of cracks are investigated.

  5. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.

    2003-09-12

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  6. Robust Joining and Integration Technologies for Advanced Metallic, Ceramic, and Composite Systems

    NASA Technical Reports Server (NTRS)

    Singh, M.; Shpargel, Tarah; Morscher, Gregory N.; Halbig, Michael H.; Asthana, Rajiv

    2006-01-01

    Robust integration and assembly technologies are critical for the successful implementation of advanced metallic, ceramic, carbon-carbon, and ceramic matrix composite components in a wide variety of aerospace, space exploration, and ground based systems. Typically, the operating temperature of these components varies from few hundred to few thousand Kelvin with different working times (few minutes to years). The wide ranging system performance requirements necessitate the use of different integration technologies which includes adhesive bonding, low temperature soldering, active metal brazing, diffusion bonding, ARCJoinT, and ultra high temperature joining technologies. In this presentation, a number of joining examples and test results will be provided related to the adhesive bonding and active metal brazing of titanium to C/C composites, diffusion bonding of silicon carbide to silicon carbide using titanium interlayer, titanium and hastelloy brazing to silicon carbide matrix composites, and ARCJoinT joining of SiC ceramics and SiC matrix composites. Various issues in the joining of metal-ceramic systems including thermal expansion mismatch and resulting residual stresses generated during joining will be discussed. In addition, joint design and testing issues for a wide variety of joints will be presented.

  7. Near-field light focusing by a slit array in a planar metal film with nonuniform slit dielectric material

    NASA Astrophysics Data System (ADS)

    David Wellems, L.; Huang, Danhong

    2012-02-01

    We study the interference of evanescent electromagnetic waves generated from multi-slits in a metal film and demonstrate the anomalous bending of light at infrared frequencies due to negative refraction. We also calculate the diffraction of an incident plane electromagnetic waves by a metallic film with an arbitrary linear array of slits, slit separation, and slit dielectric material. In contrast to a double-convex shaped quartz lens, we show that a planar metallic film with a one-dimensional slit array can also focus polarized light in the near-field region when either the slit width or the slit dielectric material becomes spatially nonuniform.

  8. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-11

    This fifteenth quarterly report describes work done during the fifteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to several outside contacts.

  9. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-01-01

    This seventeenth quarterly report describes work done during the seventeenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, submitting a manuscript and making and responding to one outside contact.

  10. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-06-01

    This sixteenth quarterly report describes work done during the sixteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, and making and responding to several outside contacts.

  11. Treatment of metal-laden hazardous wastes with advanced Clean Coal Technology by-products

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-04-12

    This twelfth quarterly report describes work done during the twelfth three-month period of the University of Pittsburgh's project on the ``Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to a number of outside contacts.

  12. Advanced Numerical methods for F. E. Simulation of Metal Forming Processes

    NASA Astrophysics Data System (ADS)

    Chenot, Jean-Loup; Bernacki, Marc; Fourment, Lionel; Ducloux, Richard

    2010-06-01

    The classical scientific basis for finite element modeling of metal forming processes is first recalled. Several developments in advanced topics are summarized: adaptive and anisotropic remeshing, parallel solving, multi material deformation. More recent researches in numerical analysis are outlined, including multi grid and multi mesh methods, mainly devoted to decrease computation time, automatic optimization method for faster and more effective design of forming processes. The link of forming simulation and structural computations is considered with emphasis on the necessity to predict the final mechanical properties. Finally a brief account of computation at the micro scale level is given.

  13. Safety aspects of the US advanced LMR (liquid metal reactor) design

    SciTech Connect

    Pedersen, D.R.; Gyorey, G.L.; Marchaterre, J.F.; Rosen, S.; General Electric Co., San Jose, CA; Argonne National Lab., IL; USDOE Assistant Secretary for Nuclear Energy, Washington, DC )

    1989-01-01

    The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the US program is to produce a standard, commercial ALMR, including the associated fuel cycle. This paper discusses the US regulatory framework for design of an ALMR, safety aspects of the IFR program at ANL, the IFR fuel cycle and actinide recycle, and the ALMR plant design program at GE. 6 refs., 5 figs.

  14. Treatment of metal-laden hazardous wastes with advanced Clean Coal Technology by-products

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini; Wiles Elder

    1999-04-05

    This eleventh quarterly report describes work done during the eleventh three-month period of the University of Pittsburgh's project on the ``Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing and giving presentations, and making and responding to two outside contacts.

  15. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  16. Microtextured metals for stray-light suppression in the Clementine startracker

    NASA Technical Reports Server (NTRS)

    Johnson, E. A.

    1993-01-01

    Anodized blacks for suppressing stray light in optical systems can now be replaced by microscopically textured metal surfaces. An application of these black surfaces to the Clementine star-tracker navigational system, which will be launched in early 1994 to examine the Moon, en route to intercept an asteroid, is detailed. Rugged black surfaces with Lambertian BRDF less than 10(exp -2) srad(sup -1) are critical for suppressing stray light in the star-tracker optical train. Previously available materials spall under launch vibrations to contaminate mirrors and lenses. Microtextured aluminum is nearly as dark, but much less fragile. It is made by differential ion beam sputtering, which generates light-trapping pores and cones slightly smaller than the wavelength to be absorbed. This leaves a sturdy but light-absorbing surface that can survive challenging conditions without generating debris or contaminants. Both seeded ion beams and plasma immersion (from ECR plasmas) extraction can produce these microscopic textures without fragile interfaces. Process parameters control feature size, spacing, and optical effects (THR, BRDF). Both broad and narrow absorption bands can be engineered with tuning for specific wavelengths and applications. Examples are presented characterized by FTIR in reflection librators (0.95 normal emissivity), heat rejection, and enhanced nucleate boiling.

  17. Flight evaluation of an advanced technology light twin-engine airplane (ATLIT)

    NASA Technical Reports Server (NTRS)

    Holmes, B. J.

    1977-01-01

    Project organization and execution, airplane description and performance predictions, and the results of the flight evaluation of an advanced technology light twin engine airplane (ATLIT) are presented. The ATLIT is a Piper PA-34-200 Seneca I modified by the installation of new wings incorporating the GA(W)-1 (Whitcomb) airfoil, reduced wing area, roll control spoilers, and full span Fowler flaps. The conclusions for the ATLIT evaluation are based on complete stall and roll flight test results and partial performance test results. The Stalling and rolling characteristics met design expectations. Climb performance was penalized by extensive flow separation in the region of the wing body juncture. Cruise performance was found to be penalized by a large value of zero lift drag. Calculations showed that, with proper attention to construction details, the improvements in span efficiency and zero lift drag would permit the realization of the predicted increases in cruising and maximum rate of climb performance.

  18. Photometric Calibration of an EUV Flat Field Spectrometer at the Advanced Light Source

    SciTech Connect

    May, M; Lepson, J; Beiersdorfer, P; Thorn, D; Chen, H; Hey, D; Smith, A

    2002-07-03

    The photometric calibration of ail extreme ultraviolet flat field spectrometer has been done at the Advanced Light Source at LBNL. This spectrometer is used to record spectrum for atomic physics research from highly charged ions in plasmas created in the Livermore electron beam ion traps EBIT-I and SUPEREBIT. Two calibrations were done each with a different gold-coated grating, a 1200 {ell}/mm and a 2400 {ell}/mm, that covered 75-300{angstrom} and 15-160{angstrom}, respectively. The detector for this calibration was a back thinned CCD. The relative calibration was determined for several different incident angles for both gratings. Within the scatter of the data, the calibration was roughly insensitive to the incidence angle for the range of angles investigated.

  19. Special issue on the "Consortium for Advanced Simulation of Light Water Reactors Research and Development Progress"

    NASA Astrophysics Data System (ADS)

    Turinsky, Paul J.; Martin, William R.

    2017-04-01

    In this special issue of the Journal of Computational Physics, the research and development completed at the time of manuscript submission by the Consortium for Advanced Simulation of Light Water Reactors (CASL) is presented. CASL is the first of several Energy Innovation Hubs that have been created by the Department of Energy. The Hubs are modeled after the strong scientific management characteristics of the Manhattan Project and AT&T Bell Laboratories, and function as integrated research centers that combine basic and applied research with engineering to accelerate scientific discovery that addresses critical energy issues. Lifetime of a Hub is expected to be five or ten years depending upon performance, with CASL being granted a ten year lifetime.

  20. Estimation of 1D proximity budget impacts due to light source for advanced node design

    NASA Astrophysics Data System (ADS)

    Peng, R. C.; Wu, Tony; Liu, H. H.

    2014-03-01

    The laser impacts on the proximity error are well known in many previous studies and papers. The proximity budget control is more and more important for advanced node design. The goal of this paper is to describe the laser spectral bandwidth and wavelength stability contributions to the proximity budget by considering general line/space and trench pattern design. We performed experiments and modeled the photolithography response using Panoramic Technology HyperLith simulation over a range of laser bandwidth and wavelength stability conditions to quantify the long term and short term stability contributions on wafer-to-wafer and field-to-field proximity variation. Finally, we determine the requirements for current system performance to meet patterning requirements and minimize the laser contribution on proximity error and within 4% of target CD Critical Dimension Uniformity (CDU) budget process requirement [2]. This paper also discusses how the wafer lithography drivers are enabled by ArFi light source technologies.

  1. The advanced light source — a new tool for research in atomic physics

    NASA Astrophysics Data System (ADS)

    Schlachter, A. S.

    1991-03-01

    The Advanced Light Source, a third-generation national synchrotron-radiation facility now under construction at the Lawrence Berkeley Laboratory in Berkeley, California, is scheduled to begin serving qualified users across a broad spectrum of research areas in the spring of 1993. Undulators will generate high-brightness, partially coherent, plane polarized, soft x-ray and ultraviolet (XUV) radiation from below 10 eV to above 2 keV. Wigglers and bend magnets will generate high fluxes of x-rays to photon energies above 10 keV. The ALS will have an extensive research program in which XUV radiation is used to study matter in all its varied gaseous, liquid, and solid forms.

  2. The advanced light source: A new tool for research in atomic physics

    NASA Astrophysics Data System (ADS)

    Schlachter, A. S.

    1990-09-01

    The Advanced Light Source, a third-generation national synchrotron-radiation facility now under construction at the Lawrence Berkeley Laboratory in Berkeley, California, is scheduled to begin serving qualified users across a broad spectrum of research areas in the spring of 1993. Undulators will generate high-brightness, partially coherent, plane polarized, soft-x-ray and ultraviolet (XUV) radiation from below 10 eV to above 2 keV. Wigglers and bend magnets will generate high fluxes of x-rays to photon energies above 10 keV. The ALS will have an extensive research program in which XUV radiation is used to study matter in all its varied gaseous, liquid, and solid forms.

  3. Advanced Oxidation of Tartrazine and Brilliant Blue with Pulsed Ultraviolet Light Emitting Diodes.

    PubMed

    Scott, Robert; Mudimbi, Patrick; Miller, Michael E; Magnuson, Matthew; Willison, Stuart; Phillips, Rebecca; Harper, Willie F

    2017-01-01

      This study investigated the effect of ultraviolet light-emitting diodes (UVLEDs) coupled with hydrogen peroxide as an advanced oxidation process (AOP) for the degradation of two test chemicals. Brilliant Blue FCF consistently exhibited greater degradation than tartrazine, with 83% degradation after 300 minutes at the 100% duty cycle compared with only 17% degradation of tartrazine under the same conditions. These differences are attributable to the structural properties of the compounds. Duty cycle was positively correlated with the first-order rate constants (k) for both chemicals but, interestingly, negatively correlated with the normalized first-order rate constants (k/duty cycle). Synergistic effects of both hydraulic mixing and LED duty cycle were manifested as novel oscillations in the effluent contaminant concentration. Further, LED output and efficiency were dependent upon duty cycle and less efficient over time perhaps due to heating effects on semiconductor performance.

  4. Calibration of a microchannel plate based extreme ultraviolet grazing incident spectrometer at the Advanced Light Source.

    PubMed

    Bakeman, M S; van Tilborg, J; Sokollik, T; Baum, D; Ybarrolaza, N; Duarte, R; Toth, C; Leemans, W P

    2010-10-01

    We present the design and calibration of a microchannel plate based extreme ultraviolet spectrometer. Calibration was performed at the Advance Light Source (ALS) at the Lawrence Berkeley National Laboratory (LBNL). This spectrometer will be used to record the single shot spectrum of radiation emitted by the tapered hybrid undulator (THUNDER) undulator installed at the LOASIS GeV-class laser-plasma-accelerator. The spectrometer uses an aberration-corrected concave grating with 1200 lines/mm covering 11-62 nm and a microchannel plate detector with a CsI coated photocathode for increased quantum efficiency in the extreme ultraviolet. A touch screen interface controls the grating angle, aperture size, and placement of the detector in vacuum, allowing for high-resolution measurements over the entire spectral range.

  5. An aberration corrected photoemission electron microscope at the advanced light source

    SciTech Connect

    Feng, J.; MacDowell, A.A.; Duarte, R.; Doran, A.; Forest, E.; Kelez, N.; Marcus, M.; Munson, D.; Padmore, H.; Petermann, K.; Raoux, S.; Robin, D.; Scholl, A.; Schlueter, R.; Schmid, P.; Stohr, J.; Wan, W.; Wei, D.H.; Wu, Y.

    2003-11-01

    Design of a new aberration corrected Photoemission electron microscope PEEM3 at the Advanced Light Source is outlined. PEEM3 will be installed on an elliptically polarized undulator beamline and will be used for the study of complex materials at high spatial and spectral resolution. The critical components of PEEM3 are the electron mirror aberration corrector and aberration-free magnetic beam separator. The models to calculate the optical properties of the electron mirror are discussed. The goal of the PEEM3 project is to achieve the highest possible transmission of the system at resolutions comparable to our present PEEM2 system (50 nm) and to enable significantly higher resolution, albeit at the sacrifice of intensity. We have left open the possibility to add an energy filter at a later date, if it becomes necessary driven by scientific need to improve the resolution further.

  6. High Energy Laboratory Astrophysics Experiments using electron beam ion traps and advanced light sources

    NASA Astrophysics Data System (ADS)

    Brown, Gregory V.; Beiersdorfer, Peter; Bernitt, Sven; Eberle, Sita; Hell, Natalie; Kilbourne, Caroline; Kelley, Rich; Leutenegger, Maurice; Porter, F. Scott; Rudolph, Jan; Steinbrugge, Rene; Traebert, Elmar; Crespo-Lopez-Urritia, Jose R.

    2015-08-01

    We have used the Lawrence Livermore National Laboratory's EBIT-I electron beam ion trap coupled with a NASA/GSFC microcalorimeter spectrometer instrument to systematically address problems found in the analysis of high resolution X-ray spectra from celestial sources, and to benchmark atomic physics codes employed by high resolution spectral modeling packages. Our results include laboratory measurements of transition energies, absolute and relative electron impact excitation cross sections, charge exchange cross sections, and dielectronic recombination resonance strengths. More recently, we have coupled to the Max-Plank Institute for Nuclear Physics-Heidelberg's FLASH-EBIT electron beam ion trap to third and fourth generation advanced light sources to measure photoexcitation and photoionization cross sections, as well as, natural line widths of X-ray transitions in highly charged iron ions. Selected results will be presented.

  7. Calibration of a microchannel plate based extreme ultraviolet grazing incident spectrometer at the Advanced Light Source

    SciTech Connect

    Bakeman, M. S.; Tilborg, J. van; Sokollik, T.; Baum, D.; Ybarrolaza, N.; Duarte, R.; Toth, C.; Leemans, W. P.

    2010-10-15

    We present the design and calibration of a microchannel plate based extreme ultraviolet spectrometer. Calibration was performed at the Advance Light Source (ALS) at the Lawrence Berkeley National Laboratory (LBNL). This spectrometer will be used to record the single shot spectrum of radiation emitted by the tapered hybrid undulator (THUNDER) undulator installed at the LOASIS GeV-class laser-plasma-accelerator. The spectrometer uses an aberration-corrected concave grating with 1200 lines/mm covering 11-62 nm and a microchannel plate detector with a CsI coated photocathode for increased quantum efficiency in the extreme ultraviolet. A touch screen interface controls the grating angle, aperture size, and placement of the detector in vacuum, allowing for high-resolution measurements over the entire spectral range.

  8. A flammability and combustion model for integrated accident analysis. [Advanced light water reactors

    SciTech Connect

    Plys, M.G.; Astleford, R.D.; Epstein, M. )

    1988-01-01

    A model for flammability characteristics and combustion of hydrogen and carbon monoxide mixtures is presented for application to severe accident analysis of Advanced Light Water Reactors (ALWR's). Flammability of general mixtures for thermodynamic conditions anticipated during a severe accident is quantified with a new correlation technique applied to data for several fuel and inertant mixtures and using accepted methods for combining these data. Combustion behavior is quantified by a mechanistic model consisting of a continuity and momentum balance for the burned gases, and considering an uncertainty parameter to match the idealized process to experiment. Benchmarks against experiment demonstrate the validity of this approach for a single recommended value of the flame flux multiplier parameter. The models presented here are equally applicable to analysis of current LWR's. 21 refs., 16 figs., 6 tabs.

  9. A new synchrotron light source at Louisiana State University's Center for Advanced Microstructures and Devices

    NASA Astrophysics Data System (ADS)

    Stockbauer, Roger L.; Ajmera, Pratul; Poliakoff, Erwin D.; Craft, Ben C.; Saile, Volker

    1990-05-01

    A 1.2-GeV synchrotron light source is being constructed at the Center for Advanced Microstructures and Devices (CAMD) at Louisiana State University. The expressed purpose of the center, which has been funded by a grant from the US Department of Energy, is to develop X-ray lithography techniques for manufacturing microcircuits, although basic science programs are also being established. The storage ring will be optimized for the soft-X-ray region and will be the first commercially manufactured electron storage ring in the United States. The magnetic lattice is based on a design developed by Chasman and Green and will allow up to three insertion devices to be installed for higher-energy and higher-intensity radiation. In addition to the lithography effort, experimental programs are being established in physics, chemistry, and related areas.

  10. Magnetic design of trim excitations for the advanced light source storage ring sextupole

    SciTech Connect

    Marks, S.

    1995-06-01

    The Advanced Light Source (ALS) storage ring sextupole is a unique multi-purpose magnet. It is designed to operate as a sextupole with three auxiliary trim modes: horizontal steering, vertical steering, and skew quadrupole. A perturbation theory for iron-dominated magnets developed by Klaus Halbach provides the basis for this design. The three trim excitations are produced by violating sextupole symmetry and are thus perturbations of the normal sextupole excitation. The magnet was designed such that all four modes are decoupled and can be excited independently. This paper discusses the use of Halbach`s perturbation theory to design the trim functions and to evaluate the primary asymmetry in the sextupole mode, namely, a gap in the return yoke to accommodate the vacuum chamber.

  11. Magnetic design of trim excitations for the Advanced Light Source storage ring sextupole

    SciTech Connect

    Marks, S.

    1996-07-01

    The Advanced Light Source (ALS) storage ring sextupole is a unique multi-purpose magnet. It is designed to operate as a sextupole with three auxiliary trim modes: horizontal steering, vertical steering, and skew quadrupole. A perturbation theory for iron-dominated magnets developed by Klaus Halbach provides the basis for this design. The three trim excitations are produced by violating sextupole symmetry and are thus perturbations of the normal sextupole excitation. The magnet was designed such that all four modes are decoupled and can be excited independently. This paper discusses the use of Halbach`s perturbation theory to design the trim functions and to evaluate the primary asymmetry in the sextupole mode, namely, a gap in the return yoke to accommodate the vacuum chamber.

  12. A Superbend X-Ray Microdiffraction Beamline at the Advanced Light Source

    SciTech Connect

    Tamura, N.; Kunz, M.; Chen, K.; Celestre, R.S.; MacDowell, A.A.; Warwick, T.

    2009-03-10

    Beamline 12.3.2 at the Advanced Light Source is a newly commissioned beamline dedicated to x-ray microdiffraction. It operates in both monochromatic and polychromatic radiation mode. The facility uses a superconducting bending magnet source to deliver an X-ray spectrum ranging from 5 to 22 keV. The beam is focused down to {approx} 1 um size at the sample position using a pair of elliptically bent Kirkpatrick-Baez mirrors enclosed in a vacuum box. The sample placed on high precision stages can be raster-scanned under the microbeam while a diffraction pattern is taken at each step. The arrays of diffraction patterns are then analyzed to derive distribution maps of phases, strain/stress and/or plastic deformation inside the sample.

  13. Soft x-ray spectromicroscopy development for materials science at the Advanced Light Source

    SciTech Connect

    Warwick, T.; Padmore, H.; Ade, H.; Hitchcock, A.P.; Rightor, E.G.; Tonner, B.P.

    1996-08-01

    Several third generation synchrotron radiation facilities are now operational and the high brightness of these photon sources offers new opportunities for x-ray microscopy. Well developed synchrotron radiation spectroscopy techniques are being applied in new instruments capable of imaging the surface of a material with a spatial resolution smaller than one micron. There are two aspects to this. One is to further the field of surface science by exploring the effects of spatial variations across a surface on a scale not previously accessible to x-ray measurements. The other is to open up new analytical techniques in materials science using x-rays, on a spatial scale comparable to that of the processes or devices to be studied. The development of the spectromicroscopy program at the Advanced Light Source will employ a variety of instruments, some are already operational. Their development and use will be discussed, and recent results will be presented to illustrate their capabilities.

  14. Magnetic properties of the ALS (Advanced Light Source) booster synchrotron engineering model magnets

    SciTech Connect

    Keller, R.; Green, M.I.; Hoyer, E.; Koo, Y.M.; Luchini, K.; Marks, S.; Milburn, J.; Nelson, D.H.

    1989-03-01

    The Advanced Light Source (ALS) at Lawrence Berkeley Laboratory is designed to be a third-generation electron storage ring producing high-brightness VUV and X-ray radiation from wiggler and undulator insertion devices. Engineering models of all lattice magnets that are to be installed in the storage ring and its booster synchrotron have been built and are being tested to verify their performance. This paper is concerned with the magnets that form the booster lattice: dipoles, quadrupoles, sextupoles, and corrector dipoles (steerers). After a brief outline of measurement techniques and equipment, the major design parameters of these magnets are listed. Measured effective lengths and multipole field errors are then given for each type. All engineering models meet the specifications, and tracking studies including the measured systematic field errors show acceptable performance of the booster synchrotron; hence the designs are qualified for production. 3 refs., 7 figs., 4 tabs.

  15. Metal oxide core shell nanostructures as building blocks for efficient light emission (SISGR)

    SciTech Connect

    Chang, Jane P; Dorman, James; Cheung, Cyrus

    2016-01-12

    The objective of this research is to synthesize core-shell nano-structured metal oxide materials and investigate their structural, electronic and optical properties to understand the microscopic pathways governing the energy conversion process, thereby controlling and improving their efficiency. Specifically, the goal is to use a single metal oxide core-shell nanostructure and a single excitation source to generate photons with long emission lifetime over the entire visible spectrum and when controlled at the right ratio, generating white light. In order to achieve this goal, we need to control the energy transfer between light emitting elements, which dictates the control of their interatomic spacing and spatial distribution. We developed an economical wet chemical process to form the nanostructured core and to control the thickness and composition of the shell layers. With the help from using DOE funded synchrotron radiation facility, we delineated the growth mechanism of the nano-structured core and the shell layers, thereby enhancing our understanding of structure-property relation in these materials. Using the upconversion luminescence and the lifetime measurements as effective feedback to materials sysnthes is and integration, we demonstrated improved luminescence lifetimes of the core-shell nano-structures and quantified the optimal core-multi-shell structure with optimum shell thickness and composition. We developed a rare-earths co-doped LaPO4 core-multishell structure in order to produce a single white light source. It was decided that the mutli-shell method would produce the largest increase in luminescence efficiency while limiting any energy transfer that may occur between the dopant ions. All samples resulted in emission spectra within the accepted range of white light generation based on the converted CIE color coordinates. The white light obtained varied between warm and cool white depending on the layering architecture, allowing for the

  16. Intra-beam Scattering and Minimum Achievable Emittance in the Advanced Light Source

    SciTech Connect

    Bane, Karl LF

    2002-08-13

    Intra-beam scattering (IBS) potentially limits the minimum emittance of low-energy storage rings, and this effect strongly influences the choice of energy of damping rings for linear colliders. The Advanced Light Source (ALS) is the third-generation synchrotron light source operating in high-intensity, low-emittance beams at energies up to 2 GeV. It can operate with an emittance coupling of below 1%. We present measurements of the beam growth in three dimensions as a function of current, for normalized natural horizontal emittances approximately 1-10 mm-mrad at energies of 0.7-1.5 GeV, values comparable to the parameters in an NLC damping ring [1]. Using a dedicated diagnostic beamline with an x-ray scintillator imaging system, measurements of the transverse beamsize are made, simultaneously with bunch length measurements using an optical streak camera. The bunch volume growth as a function of bunch current is compared with theoretical estimates, for a parameter space of IBS, where very little experimental data exists so far.

  17. Recent advances in the science and engineering of organic light-emitting diodes (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Kippelen, Bernard; Gaj, Michael P.; Zhang, Xiaoqing; Choi, Sangmoo; Fuentes-Hernandez, Canek; Zhang, Yadong; Barlow, Stephen; Marder, Seth R.; Voit, Walter E.; Wei, Andrew

    2016-09-01

    In this talk, we will discuss recent advances in the science and engineering of organic light-emitting diodes (OLEDs). First, we will focus on materials in which light emission involves the process of thermally activated delayed fluorescence (TADF). In these materials, triplet excited states can convert into optically emissive singlet excited states by reverse intersystem crossing, allowing for nearly 100% internal quantum efficiency. This process can be used to design a new class of materials that are all organic, offering a lower cost alternative to conventional electrophosphorescent materials that contain heavy and expensive elements such as Pt and Ir. We will discuss molecular design strategies and present examples of materials that can be used as emitters or hosts in the emissive layer. In a second part of this talk, we will review recent progress in fabricating OLEDs on shape memory polymer substrates (SMPs). SMPs are mechanically active, smart materials that can exhibit a significant drop in modulus once an external stimulus such as temperature is applied. In their rubbery state upon heating, the SMP can be easily deformed by external stresses into a temporary geometric configuration that can be retained even after the stress is removed by cooling the SMP to below the glass transition temperature. Reheating the SMP causes strain relaxation within the polymer network and induces recovery of its original shape. We will discuss how these unique mechanical properties can also be extended to a new class of OLEDs.

  18. High security chaotic multiple access scheme for visible light communication systems with advanced encryption standard interleaving

    NASA Astrophysics Data System (ADS)

    Qiu, Junchao; Zhang, Lin; Li, Diyang; Liu, Xingcheng

    2016-06-01

    Chaotic sequences can be applied to realize multiple user access and improve the system security for a visible light communication (VLC) system. However, since the map patterns of chaotic sequences are usually well known, eavesdroppers can possibly derive the key parameters of chaotic sequences and subsequently retrieve the information. We design an advanced encryption standard (AES) interleaving aided multiple user access scheme to enhance the security of a chaotic code division multiple access-based visible light communication (C-CDMA-VLC) system. We propose to spread the information with chaotic sequences, and then the spread information is interleaved by an AES algorithm and transmitted over VLC channels. Since the computation complexity of performing inverse operations to deinterleave the information is high, the eavesdroppers in a high speed VLC system cannot retrieve the information in real time; thus, the system security will be enhanced. Moreover, we build a mathematical model for the AES-aided VLC system and derive the theoretical information leakage to analyze the system security. The simulations are performed over VLC channels, and the results demonstrate the effectiveness and high security of our presented AES interleaving aided chaotic CDMA-VLC system.

  19. An ALS handbook: A summary of the capabilities and characteristics of the advanced light source

    SciTech Connect

    Not Available

    1989-04-01

    This booklet aims to provide the prospective user of the Advanced Light Source with a concise description of the radiation a researcher might expect at his or her experimental station. The focus is therefore on the characteristics of the light that emerges from insertion devices and bending magnets and on how components of the beam lines further alter the properties of the radiation. The few specifications and operating parameters of the ALS storage ring that are of interest are those that directly determine the radiation characteristics. Sections 4 through 5 are primarily devoted to summary presentations, by means of performance plots and tabular compilations, of radiation characteristics at the ALS--spectral brightness, flux, coherent power, resolution, etc.--assuming a representative set of three undulators and one wiggler and a corresponding set of four beam lines. As a complement to these performance summaries, Section 1 is a general introductory discussion of synchrotron radiation and the ALS, and Section 2 discusses the properties of the stored electron beam that affect the radiation. Section 3 then provides an introduction to the characteristics of synchrotron radiation from bending magnets, wigglers, and undulators. In addition, Section 5 briefly introduces the theory of diffraction-grating and crystal monochromators. As compared with previous editions of this booklet, the performance plots and tabular compilations of the ALS radiation characteristics are now based on conservative engineering designs rather than preliminary physics designs.

  20. Measurements of Intra-Beam Scattering at Low Emittance in the Advanced Light Source

    SciTech Connect

    Byrd, J.; Corlett, J.; Nishimura, H.; Robin, D.; De Santis, S.; Steier, C.; Wolski, A.; Wu, Y.; Bane, K.; Raubenheimer, T.; Ross, M.; Sheppard, J.; Smith, T.; /SLAC

    2006-03-13

    The beam emittance at the interaction point of linear colliders is expected to be strongly influenced by the emittance of the beams extracted from the damping rings. Intra-beam scattering (IBS) potentially limits the minimum emittance of low-energy storage rings, and this effect strongly influences the choice of energy of damping rings [1]. Theoretical analysis suggests that the NLC damping rings will experience modest emittance growth at 1.98 GeV, however there is little experimental data of IBS effects for very low-emittance machines in the energy regime of interest. The Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory is a third-generation synchrotron light source operating with high-intensity, low-emittance beams at energies of approximately 1-2 GeV, and with emittance coupling capability of 1% or less. We present measurements of the beam growth in three dimensions as a function of current, for normalized natural horizontal emittance of approximately 1-10 mm-mrad at energies of 0.7-1.5 GeV, values comparable to the parameters in an NLC damping ring. Using a dedicated diagnostic beamline with an x-ray scintillator imaging system, measurements of the transverse beamsize are made, and bunch length measurements are made using an optical streak camera. Emittance growth as a function of bunch current is determined, and compared with preliminary calculation estimates.

  1. Development of new generation of perovskite based noble metal/semiconductor photocatalysts for visible-light-driven hydrogen production

    NASA Astrophysics Data System (ADS)

    Shen, Peichuan

    In recent decades, semiconductor photocatalysis has attracted a growing attention as a possible alternative to existing methods of hydrogen production, hydrocarbon conversion and organic compound oxidation. Many types of photocatalysts have been developed and tested for photocatalytic applications. However, most of them do not have notable activity in visible light region, which limits their practical applications. Development of photocatalysts, which can be activated by visible light provides a promising way forward to utilize both UV and visible portions of solar spectrum. In this thesis, two main methods to advance visible light driven photocatalysis, such as bandgap modification through doping and co-catalyst development, are investigated. The photocatalysts studied in this thesis included CdS and SrTiO3, which were extensively investigated and characterized. Rhodium doped strontium titanate was synthesized through different preparation methods. The synthesized samples have been investigated by various characterization techniques including XRD, TEM, STEM, XPS and UV-Vis spectroscopy. The effect of preparation conditions, such as doping concentration, calcination temperature and pH have been investigated and optimized. In addition, the photocatalytic activities for hydrogen production of the samples synthesized by different preparation methods were also studied. Among the preparation methods, polymerizable complex (PC) method was found to be the most effective synthesis method for SrTiO3: Rh. The samples prepared by PC method had higher photocatalytic activity as compared to that of samples synthesized by solid state reaction method and hydrothermal method. The reasons might be attributed to more effective doping and higher surface area. The results of this work suggest that PC method can also be applied to develop other perovskite materials for photocatalytic applications. Co-catalyst development for enhancement of photocatalytic hydrogen production is also

  2. Advanced use of high-performance liquid chromatography for synthesis of controlled metal clusters

    NASA Astrophysics Data System (ADS)

    Niihori, Yoshiki; Matsuzaki, Miku; Uchida, Chihiro; Negishi, Yuichi

    2014-06-01

    Because the synthesis of metal clusters with multiple ligand types results in a distribution of ligands, high-resolution separation of each unique cluster from the mixture is required for precise control of the ligand composition. Reverse-phase high-performance liquid chromatography combined with appropriate transitioning of the mobile phase composition is an extremely effective means of separating ligand combinations when working with metal clusters protected by two different types of thiolates. We report herein advanced use of this method. The studies involving Au24Pd(SR1)18-x(SR2)x and Au24Pd(SR1)18-x(SeR2)x (SR1, SR2 = thiolate, SeR2 = selenolate) revealed the following. (1) In general, an increase in the difference between the polarities of the functional groups incorporated in the two types of ligands improves the separation resolution. A suitable ligand combination for separation can be predicted from the retention times of Au24Pd(SR1)18 and Au24Pd(SR2)18, which cause the terminal peaks in a series of peaks. (2) The use of a step-gradient program during the mobile phase substitution results in improved resolution compared to that achievable with the linear gradients applied in prior work. (3) This technique is also useful for the evaluation of the chemical compositions of metal clusters protected by two different types of ligands with similar molecular weights. These findings will provide clear design guidelines for the functionalization of metal clusters via control of the ligand composition, and will also improve our understanding of the high-resolution isolation of metal clusters.Because the synthesis of metal clusters with multiple ligand types results in a distribution of ligands, high-resolution separation of each unique cluster from the mixture is required for precise control of the ligand composition. Reverse-phase high-performance liquid chromatography combined with appropriate transitioning of the mobile phase composition is an extremely effective

  3. Electromagnetically induced transparency of a plasmonic metamaterial light absorber based on multilayered metallic nanoparticle sheets

    PubMed Central

    Okamoto, Koichi; Tanaka, Daisuke; Degawa, Ryo; Li, Xinheng; Wang, Pangpang; Ryuzaki, Sou; Tamada, Kaoru

    2016-01-01

    In this study, we observed the peak splitting of absorption spectra for two-dimensional sheets of silver nanoparticles due to the electromagnetically induced transparency (EIT) effect. This unique optical phenomenon was observed for the multilayered nanosheets up to 20 layers on a metal substrate, while this phenomenon was not observed on a transparent substrate. The wavelength and intensities of the split peaks depend on the number of layers, and the experimental results were well reproduced by the calculation of the Transfer-Matrix method by employing the effective medium approximation. The Ag nanosheets used in this study can act as a plasmonic metamaterial light absorber, which has a such large oscillator strength. This phenomenon is a fundamental optical property of a thin film on a metal substrate but has never been observed because native materials do not have a large oscillator strength. This new type of EIT effect using a plasmonic metamaterial light absorber presents the potential for the development of future optic and photonic technologies. PMID:27824071

  4. Electromagnetically induced transparency of a plasmonic metamaterial light absorber based on multilayered metallic nanoparticle sheets.

    PubMed

    Okamoto, Koichi; Tanaka, Daisuke; Degawa, Ryo; Li, Xinheng; Wang, Pangpang; Ryuzaki, Sou; Tamada, Kaoru

    2016-11-08

    In this study, we observed the peak splitting of absorption spectra for two-dimensional sheets of silver nanoparticles due to the electromagnetically induced transparency (EIT) effect. This unique optical phenomenon was observed for the multilayered nanosheets up to 20 layers on a metal substrate, while this phenomenon was not observed on a transparent substrate. The wavelength and intensities of the split peaks depend on the number of layers, and the experimental results were well reproduced by the calculation of the Transfer-Matrix method by employing the effective medium approximation. The Ag nanosheets used in this study can act as a plasmonic metamaterial light absorber, which has a such large oscillator strength. This phenomenon is a fundamental optical property of a thin film on a metal substrate but has never been observed because native materials do not have a large oscillator strength. This new type of EIT effect using a plasmonic metamaterial light absorber presents the potential for the development of future optic and photonic technologies.

  5. Bacterial killing by light-triggered release of silver from biomimetic metal nanorods.

    PubMed

    Black, Kvar C L; Sileika, Tadas S; Yi, Ji; Zhang, Ran; Rivera, José G; Messersmith, Phillip B

    2014-01-15

    Illumination of noble metal nanoparticles at the plasmon resonance causes substantial heat generation, and the transient and highly localized temperature increases that result from this energy conversion can be exploited for photothermal therapy by plasmonically heating gold nanorods (NRs) bound to cell surfaces. Here, plasmonic heating is used for the first time to locally release silver from gold core/silver shell (Au@Ag) NRs targeted to bacterial cell walls. A novel biomimetic method of preparing Au@Ag core-shell NRs is employed, involving deposition of a thin organic polydopamine (PD) primer onto Au NR surfaces, followed by spontaneous electroless silver metallization, and conjugation of antibacterial antibodies and passivating polymers for targeting to gram-negative and gram-positive bacteria. Dramatic cytotoxicity of S. epidermidis and E. coli cells targeted with Au@Ag NRs is observed upon exposure to light as a result of the combined antibacterial effects of plasmonic heating and silver release. The antibacterial effect is much greater than with either plasmonic heating or silver alone, implying a strong therapeutic synergy between cell-targeted plasmonic heating and the associated silver release upon irradiation. The findings suggest a potential antibacterial use of Au@Ag NRs when coupled with light irradiation, which has not been previously described.

  6. Bacterial Killing by Light-Triggered Release of Silver from Biomimetic Metal Nanorods

    PubMed Central

    Yi, Ji; Zhang, Ran; Rivera, José G.; Messersmith, Phillip B.

    2014-01-01

    Illumination of noble metal nanoparticles at the plasmon resonance causes substantial heat generation, and the transient and highly localized temperature increases that result from this energy conversion can be exploited for photothermal therapy by plasmonically heating gold nanorods (NRs) bound to cell surfaces. Here, we report the first use of plasmonic heating to locally release silver from gold core/silver shell (Au@Ag) NRs targeted to bacterial cell walls. A novel biomimetic method of preparing Au@Ag core-shell NRs was employed, involving deposition of a thin organic polydopamine (PD) primer onto Au NR surfaces, followed by spontaneous electroless silver metallization, and conjugation of antibacterial antibodies and passivating polymers for targeting to gram-negative and gram-positive bacteria. Dramatic cytotoxicity of S. epidermidis and E. coli cells targeted with Au@Ag NRs was observed upon exposure to light as a result of the combined antibacterial effects of plasmonic heating and silver release. The antibacterial effect was much greater than with either plasmonic heating or silver alone, implying a strong therapeutic synergy between cell-targeted plasmonic heating and the associated silver release upon irradiation. Our findings suggest a potential antibacterial use of Au@Ag NRs when coupled with light irradiation, which was not previously described. PMID:23847147

  7. Electromagnetically induced transparency of a plasmonic metamaterial light absorber based on multilayered metallic nanoparticle sheets

    NASA Astrophysics Data System (ADS)

    Okamoto, Koichi; Tanaka, Daisuke; Degawa, Ryo; Li, Xinheng; Wang, Pangpang; Ryuzaki, Sou; Tamada, Kaoru

    2016-11-01

    In this study, we observed the peak splitting of absorption spectra for two-dimensional sheets of silver nanoparticles due to the electromagnetically induced transparency (EIT) effect. This unique optical phenomenon was observed for the multilayered nanosheets up to 20 layers on a metal substrate, while this phenomenon was not observed on a transparent substrate. The wavelength and intensities of the split peaks depend on the number of layers, and the experimental results were well reproduced by the calculation of the Transfer-Matrix method by employing the effective medium approximation. The Ag nanosheets used in this study can act as a plasmonic metamaterial light absorber, which has a such large oscillator strength. This phenomenon is a fundamental optical property of a thin film on a metal substrate but has never been observed because native materials do not have a large oscillator strength. This new type of EIT effect using a plasmonic metamaterial light absorber presents the potential for the development of future optic and photonic technologies.

  8. Advanced use of high-performance liquid chromatography for synthesis of controlled metal clusters.

    PubMed

    Niihori, Yoshiki; Matsuzaki, Miku; Uchida, Chihiro; Negishi, Yuichi

    2014-07-21

    Because the synthesis of metal clusters with multiple ligand types results in a distribution of ligands, high-resolution separation of each unique cluster from the mixture is required for precise control of the ligand composition. Reverse-phase high-performance liquid chromatography combined with appropriate transitioning of the mobile phase composition is an extremely effective means of separating ligand combinations when working with metal clusters protected by two different types of thiolates. We report herein advanced use of this method. The studies involving Au₂₄Pd(SR₁)₁₈-x(SR₂)x and Au₂₄Pd(SR₁)₁₈-x(SeR₂)x (SR₁, SR₂ = thiolate, SeR₂ = selenolate) revealed the following. (1) In general, an increase in the difference between the polarities of the functional groups incorporated in the two types of ligands improves the separation resolution. A suitable ligand combination for separation can be predicted from the retention times of Au₂₄Pd(SR₁)₁₈ and Au₂₄Pd(SR₂)₁₈, which cause the terminal peaks in a series of peaks. (2) The use of a step-gradient program during the mobile phase substitution results in improved resolution compared to that achievable with the linear gradients applied in prior work. (3) This technique is also useful for the evaluation of the chemical compositions of metal clusters protected by two different types of ligands with similar molecular weights. These findings will provide clear design guidelines for the functionalization of metal clusters via control of the ligand composition, and will also improve our understanding of the high-resolution isolation of metal clusters.

  9. Selection of the reference steam generator for the advanced liquid metal reactor

    SciTech Connect

    Loewen, Eric P.; Boardman, Chuck

    2007-07-01

    In February 2006 President Bush announced the Advanced Energy Initiative, which included the Department of Energy's (DOE) Global Nuclear Energy Partnership (GNEP). GNEP has seven broad goals; one of the major elements being to develop and deploy advanced nuclear fuel recycling technology that includes consuming spent nuclear fuel in an Advanced Recycling Reactor (ARR). DOE is contemplating accelerating the deployment of these technologies to achieve the construction of a commercial scale application of these technologies. DOE now defines this approach as 'two simultaneous tracks: (1) deployment of commercial scale facilities for which advanced technologies are available now or in the near future, and (2) further research and development of transmutation fuels technologies'. GEHitachi Nuclear Energy Americas LLC (GHNEA) believes an integrated technical solution is achievable in the near term to accelerate the commercial demonstration of GNEP infrastructure. The GHNEA ARR concept involves a single integrated recycling facility sized to service a single reactor module ARR capable of destroying light water and fast reactor sourced actinides. This paper describes the bases and rationale behind the selection of the helical coil steam generator (HCSG) as the reference steam generator concept for the ALMR and S-PRISM reactor concepts. (authors)

  10. A micromachined thermo-optical light modulator based on semiconductor-to-metal phase transition

    NASA Astrophysics Data System (ADS)

    Jiang, Lijun

    In this research, a micromachined thermo-optical light modulator was realized based on the semiconductor-to-metal phase transition of vanadium dioxide (VO2) thin film. VO2 undergoes a reversible phase transition at approximately 68°C, which is accompanied with drastic changes in its electrical and optical properties. The sharp electrical resistivity change can be as great as five orders. Optically, VO2 film will switch from a transparent semiconductor phase to a reflective metal phase upon the phase transition. The light modulator in this research exploits this phase transition related optical switching by using surface micromachined low-thermal-mass pixels to achieve good thermal isolations, which ensures that each pixel can be individually switched without cross talking. In operation, the pixel temperature was controlled by integrated resistor on each pixel or spatially addressed thermal radiation sources. Active VO2 thin film was synthesized by thermal oxidation of e-beam evaporated vanadium metal film. The oxidized film exhibits a phase transition at ˜65°C with a hysteresis of about 15°C. A transmittance switching from ˜90% to ˜30% in the near infrared and a reflectance switching from ˜50% to ˜15% in the visible have been achieved. The surface microstructure was studied and correlated to its optical properties. A study on the hysteresis loop reveals that the VO2 can be repetitively switched between the "on" and "off" states. The micromachined thermal isolation pixel was a bridge-like silicon dioxide platform suspended with narrow supporting legs. The pixel design was optimized with both thermal and optical simulations. The VO2 light modulator was fabricated by surface micromachining based on dry processing. Silicon dioxide was deposited on a polyimide sacrificial layer by PECVD and patterned to form the structural pixel. Vanadium film was e-beam evaporated and patterned with lift-off process. It was thermally oxidized into VO2 at 390°C. The thermal

  11. Stabilization of Heavy Metal Containing Hazardous Wastes with Byproducts from Advanced Clean Coal Technology Systems.

    PubMed

    Pritts, Jesse W; Neufeld, Ronald D; Cobb, James T

    1999-10-01

    The purpose of this investigation was to evaluate the success of residues from advanced Clean Coal Technology (CCT) systems as stabilization agents for heavy metal containing hazardous wastes. In the context examined here, stabilization refers to techniques that reduce the toxicity of a waste by converting the hazardous constituents to a less soluble, mobile, or toxic form.(1) Three advanced CCT byproducts were used: coal waste-fired circulating fluidized bed combustor residue, pressurized fluidized bed combustor residue, and spray drier residue. Seven metal-laden hazardous wastes were treated: three contaminated soils, two air pollution control dusts, wastewater treatment plant sludge, and sandblast waste. Each of the seven hazardous wastes was treated with each of the three CCT byproducts at dosages of 10, 30, and 50% by weight (byproduct:waste). The treatment effectiveness of each mixture was evaluated by the Toxicity Characteristic Leaching Procedure. Of the 63 mixtures evaluated, 21 produced non-hazardous residues. Treatment effectiveness can likely be attributed to mechanisms such as precipitation and encapsulation due to the formation of hydrated calcium silicates and calcium sulfo-alu-minates. Results indicate that these residues have potential beneficial uses to the hazardous waste treatment community, possibly substituting for costly treatment chemicals.

  12. Effect of metal halide light source on hardness, water sorption and solubility of indirect composite material.

    PubMed

    Koizumi, Hiroyasu; Satsukawa, Hidetada; Tanoue, Naomi; Ogino, Tomohisa; Nishiyama, Minoru; Matsumura, Hideo

    2005-12-01

    This study evaluates the effects of a metal halide light source on the post-polymerization properties of the Sinfony indirect composite material. Two polymerization systems were employed: the Hyper LII system, comprising a metal halide polymerization unit, and the Visio system, comprising two proprietary units designed for polymerizing the Sinfony composite. The composite material was polymerized for 60, 120 or 180 s with the LII system. As a control, the composite was polymerized for 15 min with the Visio system. Knoop hardness, water sorption and solubility were determined. The results were analyzed by Dunnett's T3 multiple comparison test (P<0.05). Knoop hardness was greater for polymerization with the LII unit than for that with the Visio system. Water sorption was greater for polymerization with the Visio system than that with the LII unit. For polymerization with the LII unit for 180 s, solubility was significantly reduced as compared with the Visio system. Within the limitations of the current experiment, it can be concluded that the metal halide unit exhibited better polymerizing performance for the composite material than the proprietary units.

  13. Visible-light driven degradation of ibuprofen using abundant metal-loaded BiVO₄ photocatalysts.

    PubMed

    Bian, Zhao-Yong; Zhu, Ya-Qi; Zhang, Jun-Xiao; Ding, Ai-Zhong; Wang, Hui

    2014-12-01

    An efficient method for the degradation of ibuprofen as an aqueous contaminant was developed under visible-light irradiation with as-prepared bismuth vanadate (BiVO4) catalysts. The metal-loaded catalysts Cu-BiVO4 and Ag-BiVO4 were synthesized using a hydrothermal process and then a wet-impregnation method. All of the materials were fully characterized by X-ray diffraction, scanning electron microscopy, UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy and BET surface area. The results indicated that all of the prepared samples had monoclinic scheelite structures. In the metal-loaded catalysts, silver existed as a mixture of Ag and Ag2O on the surface of the catalysts. However, copper existed as Cu2O and CuO. Additionally, the band gap values of BiVO4, Ag-BiVO4, and Cu-BiVO4 were 2.38, 2.31, and 2.30eV, respectively. Compared to the BiVO4 catalyst, the metal-loaded BiVO4 catalysts showed superior photocatalytic properties for the degradation of ibuprofen.

  14. Nonlocal response of metallic nanospheres probed by light, electrons, and atoms.

    PubMed

    Christensen, Thomas; Yan, Wei; Raza, Søren; Jauho, Antti-Pekka; Mortensen, N Asger; Wubs, Martijn

    2014-02-25

    Inspired by recent measurements on individual metallic nanospheres that cannot be explained with traditional classical electrodynamics, we theoretically investigate the effects of nonlocal response by metallic nanospheres in three distinct settings: atomic spontaneous emission, electron energy loss spectroscopy, and light scattering. These constitute two near-field and one far-field measurements, with zero-, one-, and two-dimensional excitation sources, respectively. We search for the clearest signatures of hydrodynamic pressure waves in nanospheres. We employ a linearized hydrodynamic model, and Mie-Lorenz theory is applied for each case. Nonlocal response shows its mark in all three configurations, but for the two near-field measurements, we predict especially pronounced nonlocal effects that are not exhibited in far-field measurements. Associated with every multipole order is not only a single blueshifted surface plasmon but also an infinite series of bulk plasmons that have no counterpart in a local-response approximation. We show that these increasingly blueshifted multipole plasmons become spectrally more prominent at shorter probe-to-surface separations and for decreasing nanosphere radii. For selected metals, we predict hydrodynamic multipolar plasmons to be measurable on single nanospheres.

  15. Insights for aging management of light water reactor components: Metal containments. Volume 5

    SciTech Connect

    Shah, V.N.; Sinha, U.P.; Smith, S.K.

    1994-03-01

    This report evaluates the available technical information and field experience related to management of aging damage to light water reactor metal containments. A generic aging management approach is suggested for the effective and comprehensive aging management of metal containments to ensure their safe operation. The major concern is corrosion of the embedded portion of the containment vessel and detection of this damage. The electromagnetic acoustic transducer and half-cell potential measurement are potential techniques to detect corrosion damage in the embedded portion of the containment vessel. Other corrosion-related concerns include inspection of corrosion damage on the inaccessible side of BWR Mark I and Mark II containment vessels and corrosion of the BWR Mark I torus and emergency core cooling system piping that penetrates the torus, and transgranular stress corrosion cracking of the penetration bellows. Fatigue-related concerns include reduction in the fatigue life (a) of a vessel caused by roughness of the corroded vessel surface and (b) of bellows because of any physical damage. Maintenance of surface coatings and sealant at the metal-concrete interface is the best protection against corrosion of the vessel.

  16. Guiding light by plasmonic resonant solitons in metallic nanosuspensions (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Kelly, Trevor S.; Samadi, Akbar; Bezryadina, Anna; Chen, Zhigang

    2015-09-01

    In typical colloidal suspensions, the corresponding optical polarizability is positive, and thus enhanced scattering takes place as optical beams tend to catastrophically collapse during propagation. Recently, light penetration deep inside scattering suspensions has been realized by engineering dielectric or plasmonic nanoparticle polarizibilities. In particular, we have previously demonstrated two types of soft-matter systems with tunable optical nonlinearities - the dielectric and metallic colloidal suspensions, in which the effects of diffraction and scattering were overcome, hence achieving deep penetration of a light needle through the suspension. In this work, we show that waveguides can be established in soft matter systems such as metallic nanosuspensions through the formation of plasmonic resonant solitons. First, we show that, due to plasmonic resonance, a 1064nm laser beam (probe) would not experience appreciable nonlinear self-action while propagating through 4cm cuvette containing the metallic nanosuspension of gold spheres (40nm), whereas a 532nm laser beam (pump) can readily form a spatial soliton due to nonlinear self-trapping. Second, we demonstrate effective guidance of the probe beam, which would otherwise diffract significantly through the nanosuspensions, due to the soliton-induced waveguide from the pump beam. Such guidance was observed when the power of the probe beam was varied from 20mW to 500mW at constant pump beam power, with more pronounced guidance realized from lower to higher probe beam power. Interestingly, due to the presence of the probe beam, the pump beam undergoes self-trapping at an even lower power. These results may bring about the possibility of engineering plasmonic soliton-based waveguides for many applications.

  17. Modeling Constituent Redistribution in U-Pu-Zr Metallic Fuel Using the Advanced Fuel Performance Code BISON

    SciTech Connect

    Douglas Porter; Steve Hayes; Various

    2014-06-01

    The Advanced Fuels Campaign (AFC) metallic fuels currently being tested have higher zirconium and plutonium concentrations than those tested in the past in EBR reactors. Current metal fuel performance codes have limitations and deficiencies in predicting AFC fuel performance, particularly in the modeling of constituent distribution. No fully validated code exists due to sparse data and unknown modeling parameters. Our primary objective is to develop an initial analysis tool by incorporating state-of-the-art knowledge, constitutive models and properties of AFC metal fuels into the MOOSE/BISON (1) framework in order to analyze AFC metallic fuel tests.

  18. A new type of DNA "light-switch": a dual photochemical sensor and metalating agent for duplex and G-quadruplex DNA.

    PubMed

    Wachter, Erin; Howerton, Brock S; Hall, Emily C; Parkin, Sean; Glazer, Edith C

    2014-01-11

    Ru(bpy)2dppz, a well studied "light-switch" metal complex, transforms into a photochemical "light-switch" and DNA damaging agent by incorporating structural strain. This distorted compound is photoreactive and ejects a ligand upon binding duplex and G-quadruplex DNA, producing a reactive metal center that metalates the DNA.

  19. Light quanta modulated characteristics of Ni uptake by Brassica juncea seedlings: the interdependence of plant metal concentration and biomass.

    PubMed

    Dasgupta-Schubert, N; Whelan, T; Reyes, M A; Lloren, C; Brandt, T T; Persans, M W

    2007-01-01

    The relationships between the concentration of metal in the growth medium, Cs, the concentration of metal absorbed by the plant, Cp, and the total biomass achieved, M, all of which are factors relevant to the efficiency of metal uptake and tolerance by the plant, have been investigated via the physiological response of Brassica juncea seedlings to Ni stress. The factorial growth experiments treated the Ni concentration in agar medium and the diurnal light quanta as independently variable parameters. Observations included the evidence of light enhancement of Ni toxicity in the root, as well as at the whole-plant level. The shoot mass index possibly is an indicator of the amount of shoot metal sequestration in B. juncea, as are the logarithmic variation of Cp with Cs and the power-law dependence of M on Cp. The sum total of these observations indicates that, for the Ni accumulating plant B. juncea, the overall metabolic allocation to either growth or metal tolerance of the plant is important. Neither a rapid biomass increase nor a high metal absorbed concentration favored the removal of high metal mass from the medium. Rather, the plants with a moderate rate of biomass growth and a moderate absorbed metal concentration demonstrated the ability to remove the maximum mass of metal from the medium. The implication of these results as related to the extant model of phyoextraction efficiency is discussed.

  20. The advances of Chinese non-ferrous metal mineral industry and its environmental management

    SciTech Connect

    Miao Zewei; Gao Lin; Zhou Xiaoyuan

    1998-12-31

    With the steady growth of Chinese economy, the nonferrous metal industry of China was also developed quickly. The gross output of ten main nonferrous metals 4.25 million tons in 1995 so that China ranks the fourth in the world. However, a series of environmental problems also occurred, which relate to characteristics of mineral resources, techniques for mining, dressing, smelting and processing, equipment and their management level. The major pollutants include sulphur dioxide, industrial powder-dust and smoke-dust, water containing heavy metal ions as well as solid wastes. Air, water body, soil, vegetation and people`s health were polluted and damaged to different extent due to the above pollutants. For the purpose of environmental management and pollution control, some measures must be taken: (1) to strengthen environmental planning, accelerate and perfect environmental laws and related regulations as well as spread the consciousness of environmental protection energetically; (2) to extend cleaner production and adopt advanced technologies so as to reduce environmental pollution; (3) to turn the concept of the end-of-pipe management to the whole-process control; (4) to recovery or reuse the wastes fully. In addition, general situation and policies on reclamation of mining land as well as theory, methods and techniques of restoration of waste land were also stated in the paper.

  1. Recent Progress in Self‐Supported Metal Oxide Nanoarray Electrodes for Advanced Lithium‐Ion Batteries

    PubMed Central

    Zhang, Feng

    2016-01-01

    The rational design and fabrication of electrode materials with desirable architectures and optimized properties has been demonstrated to be an effective approach towards high‐performance lithium‐ion batteries (LIBs). Although nanostructured metal oxide electrodes with high specific capacity have been regarded as the most promising alternatives for replacing commercial electrodes in LIBs, their further developments are still faced with several challenges such as poor cycling stability and unsatisfying rate performance. As a new class of binder‐free electrodes for LIBs, self‐supported metal oxide nanoarray electrodes have many advantageous features in terms of high specific surface area, fast electron transport, improved charge transfer efficiency, and free space for alleviating volume expansion and preventing severe aggregation, holding great potential to solve the mentioned problems. This review highlights the recent progress in the utilization of self‐supported metal oxide nanoarrays grown on 2D planar and 3D porous substrates, such as 1D and 2D nanostructure arrays, hierarchical nanostructure arrays, and heterostructured nanoarrays, as anodes and cathodes for advanced LIBs. Furthermore, the potential applications of these binder‐free nanoarray electrodes for practical LIBs in full‐cell configuration are outlined. Finally, the future prospects of these self‐supported nanoarray electrodes are discussed. PMID:27711259

  2. Joining and Integration of Advanced Carbon-Carbon Composites to Metallic Systems for Thermal Management Applications

    NASA Technical Reports Server (NTRS)

    Singh, M.; Asthana, R.

    2008-01-01

    Recent research and development activities in joining and integration of carbon-carbon (C/C) composites to metals such as Ti and Cu-clad-Mo for thermal management applications are presented with focus on advanced brazing techniques. A wide variety of carbon-carbon composites with CVI and resin-derived matrices were joined to Ti and Cu-clad Mo using a number of active braze alloys. The brazed joints revealed good interfacial bonding, preferential precipitation of active elements (e.g., Ti) at the composite/braze interface. Extensive braze penetration of the inter-fiber channels in the CVI C/C composites was observed. The chemical and thermomechanical compatibility between C/C and metals at elevated temperatures is assessed. The role of residual stresses and thermal conduction in brazed C/C joints is discussed. Theoretical predictions of the effective thermal resistance suggest that composite-to-metal brazed joints may be promising for lightweight thermal management applications.

  3. Recent Progress in Self-Supported Metal Oxide Nanoarray Electrodes for Advanced Lithium-Ion Batteries.

    PubMed

    Zhang, Feng; Qi, Limin

    2016-09-01

    The rational design and fabrication of electrode materials with desirable architectures and optimized properties has been demonstrated to be an effective approach towards high-performance lithium-ion batteries (LIBs). Although nanostructured metal oxide electrodes with high specific capacity have been regarded as the most promising alternatives for replacing commercial electrodes in LIBs, their further developments are still faced with several challenges such as poor cycling stability and unsatisfying rate performance. As a new class of binder-free electrodes for LIBs, self-supported metal oxide nanoarray electrodes have many advantageous features in terms of high specific surface area, fast electron transport, improved charge transfer efficiency, and free space for alleviating volume expansion and preventing severe aggregation, holding great potential to solve the mentioned problems. This review highlights the recent progress in the utilization of self-supported metal oxide nanoarrays grown on 2D planar and 3D porous substrates, such as 1D and 2D nanostructure arrays, hierarchical nanostructure arrays, and heterostructured nanoarrays, as anodes and cathodes for advanced LIBs. Furthermore, the potential applications of these binder-free nanoarray electrodes for practical LIBs in full-cell configuration are outlined. Finally, the future prospects of these self-supported nanoarray electrodes are discussed.

  4. Parametric Weight Comparison of Advanced Metallic, Ceramic Tile, and Ceramic Blanket Thermal Protection Systems

    NASA Technical Reports Server (NTRS)

    Myers, David E.; Martin, Carl J.; Blosser, Max L.

    2000-01-01

    A parametric weight assessment of advanced metallic panel, ceramic blanket, and ceramic tile thermal protection systems (TPS) was conducted using an implicit, one-dimensional (I-D) finite element sizing code. This sizing code contained models to account for coatings fasteners, adhesives, and strain isolation pads. Atmospheric entry heating profiles for two vehicles, the Access to Space (ATS) vehicle and a proposed Reusable Launch Vehicle (RLV), were used to ensure that the trends were not unique to a certain trajectory. Ten TPS concepts were compared for a range of applied heat loads and substructural heat capacities to identify general trends. This study found the blanket TPS concepts have the lightest weights over the majority of their applicable ranges, and current technology ceramic tiles and metallic TPS concepts have similar weights. A proposed, state-of-the-art metallic system which uses a higher temperature alloy and efficient multilayer insulation was predicted to be significantly lighter than the ceramic tile stems and approaches blanket TPS weights for higher integrated heat loads.

  5. Visible-light-induced instability in amorphous metal-oxide based TFTs for transparent electronics

    SciTech Connect

    Ha, Tae-Jun

    2014-10-15

    We investigate the origin of visible-light-induced instability in amorphous metal-oxide based thin film transistors (oxide-TFTs) for transparent electronics by exploring the shift in threshold voltage (V{sub th}). A large hysteresis window in amorphous indium-gallium-zinc-oxide (a-IGZO) TFTs possessing large optical band-gap (≈3 eV) was observed in a visible-light illuminated condition whereas no hysteresis window was shown in a dark measuring condition. We also report the instability caused by photo irradiation and prolonged gate bias stress in oxide-TFTs. Larger V{sub th} shift was observed after photo-induced stress combined with a negative gate bias than the sum of that after only illumination stress and only negative gate bias stress. Such results can be explained by trapped charges at the interface of semiconductor/dielectric and/or in the gate dielectric which play a role in a screen effect on the electric field applied by gate voltage, for which we propose that the localized-states-assisted transitions by visible-light absorption can be responsible.

  6. Improving the carrier balance of light-emitting electrochemical cells based on ionic transition metal complexes.

    PubMed

    Su, Hai-Ching; Hsu, Jia-Hong

    2015-05-14

    Recently, solid-state light-emitting electrochemical cells (LECs) based on ionic transition metal complexes (iTMCs) have attracted much research interest since they have the advantages of a simple device structure, a low operation voltage and compatibility with air-stable electrodes. These properties enable LECs to be cost-effective, versatile and power-efficient organic light-emitting sources. However, it is generally not easy to modify the molecular structure to achieve balanced carrier mobilities without altering the photoluminescence quantum yield of the iTMC. Furthermore, the carrier balance and the consequent device efficiency of single-layered LECs would not be easy to optimize since no carrier injection and transport layers can be used. In this perspective, some reported techniques to improve carrier balance of LECs based on iTMCs are described and reviewed. The importance and impact of these studies are highlighted. The effects on device lifetime and turn-on time because of employing these techniques to improve the carrier balance are also discussed. This perspective concludes that even with electrochemically doped layers, improving the carrier balance of LECs would be required for realizing efficient electroluminescent emission from simple-structure organic light-emitting sources.

  7. Active modulation of visible light with graphene-loaded ultrathin metal plasmonic antennas

    PubMed Central

    Yu, Renwen; Pruneri, Valerio; García de Abajo, F. Javier

    2016-01-01

    Electro-optical modulation of visible and near-infrared light is important for a wide variety of applications, ranging from communications to sensing and smart windows. However, currently available approaches result in rather bulky devices, suffer from low integrability, and can hardly operate at the low power consumption levels and fast switching rates required by microelectronic drivers. Here we show that planar nanostructures patterned in ultrathin metal-graphene hybrid films sustain highly tunable plasmons in the visible and near-infrared spectral regions. Strong variations in the reflection and absorption of incident light take place when the plasmons are tuned on- and off-resonance with respect to externally incident light. As a result, a remarkable modulation depth (i.e., the maximum relative variation with/without graphene doping) exceeding 90% in transmission and even more dramatic in reflection (>600%) is predicted for graphene-loaded silver films of 1–5 nm thickness and currently attainable lateral dimensions. These new structures hold great potential for fast low-power electro-optical modulation. PMID:27561789

  8. Active modulation of visible light with graphene-loaded ultrathin metal plasmonic antennas

    NASA Astrophysics Data System (ADS)

    Yu, Renwen; Pruneri, Valerio; García de Abajo, F. Javier

    2016-08-01

    Electro-optical modulation of visible and near-infrared light is important for a wide variety of applications, ranging from communications to sensing and smart windows. However, currently available approaches result in rather bulky devices, suffer from low integrability, and can hardly operate at the low power consumption levels and fast switching rates required by microelectronic drivers. Here we show that planar nanostructures patterned in ultrathin metal-graphene hybrid films sustain highly tunable plasmons in the visible and near-infrared spectral regions. Strong variations in the reflection and absorption of incident light take place when the plasmons are tuned on- and off-resonance with respect to externally incident light. As a result, a remarkable modulation depth (i.e., the maximum relative variation with/without graphene doping) exceeding 90% in transmission and even more dramatic in reflection (>600%) is predicted for graphene-loaded silver films of 1–5 nm thickness and currently attainable lateral dimensions. These new structures hold great potential for fast low-power electro-optical modulation.

  9. Efficient vacuum-free-processed quantum dot light-emitting diodes with printable liquid metal cathodes.

    PubMed

    Peng, Huiren; Jiang, Yibin; Chen, Shuming

    2016-10-20

    Colloidal quantum dot light-emitting diodes (QLEDs) are recognized as promising candidates for next generation displays. QLEDs can be fabricated by low-cost solution processing except for the metal electrodes, which, in general, are deposited by costly vacuum evaporation. To be fully compatible with the low-cost solution process, we herein demonstrate vacuum-free and solvent-free fabrication of electrodes using a printable liquid metal. With eutectic gallium-indium (EGaIn) based liquid metal cathodes, vacuum-free-processed QLEDs are demonstrated with superior external quantum efficiencies of 11.51%, 12.85% and 5.03% for red, green and blue devices, respectively, which are about 2-, 1.5- and 1.1-fold higher than those of the devices with thermally evaporated Al cathodes. The improved performance is attributable to the reduction of electron injection by the native oxide of EGaIn, which serves as an electron-blocking layer for the devices and thus improves the balance of carrier injection. Also, the T50 half-lifetime of the vacuum-free-processed QLEDs is about 2-fold longer than that of the devices with Al cathodes. Our results demonstrate that EGaIn-based solvent-free liquid metals are promising printable electrodes for realizing efficient, low-cost and vacuum-free-processed QLEDs. The elimination of vacuum and high-temperature processes significantly reduces the production cost and paves the way for industrial roll-to-roll manufacturing of large area displays.

  10. Surface plasmon excitations in metal spheres: Direct comparison of light scattering and electron energy-loss spectroscopy by modal decomposition

    NASA Astrophysics Data System (ADS)

    Collins, Sean M.; Midgley, Paul A.

    2013-06-01

    In previous publications, qualitative agreement between studies of surface plasmon excitations in nanoparticles by near-field light scattering and electron energy-loss spectroscopy (EELS) has been found for experiments and simulations. Here, we present a quantitative method for the comparison of light scattering and EELS for surface plasmons in metal spheres. Defining the Fourier transform of the modal component of the scattered electric field along the equivalent electron trajectory enables a direct evaluation of the relative weighting factor for light- and electron-excited surface plasmon modes. This common quantity for light scattering and EELS is examined for size, composition, and trajectory dependencies, facilitating the analysis of key differences between light and electron excitation. A single functional dependence on Drude model plasmon energies is identified to explain the relative modal weighting factors for light scattering and EELS. This method represents an important step toward the complete spectral and spatial reconstruction of EELS maps from near-field light scattering calculations.

  11. Advances in Fatigue and Fracture Mechanics Analyses for Metallic Aircraft Structures

    NASA Technical Reports Server (NTRS)

    Newman, J. C., Jr.

    2000-01-01

    This paper reviews some of the advances that have been made in stress analyses of cracked aircraft components, in the understanding of the fatigue and fatigue-crack growth process, and in the prediction of residual strength of complex aircraft structures with widespread fatigue damage. Finite-element analyses of cracked metallic structures are now used to determine accurate stress-intensity factors for cracks at structural details. Observations of small-crack behavior at open and rivet-loaded holes and the development of small-crack theory has lead to the prediction of stress-life behavior for components with stress concentrations under aircraft spectrum loading. Fatigue-crack growth under simulated aircraft spectra can now be predicted with the crack-closure concept. Residual strength of cracked panels with severe out-of-plane deformations (buckling) in the presence of stiffeners and multiple-site damage can be predicted with advanced elastic-plastic finite-element analyses and the critical crack-tip-opening angle (CTOA) fracture criterion. These advances are helping to assure continued safety of aircraft structures.

  12. Enhancing light emission efficiency without color change in post-transition metal chalcogenides

    NASA Astrophysics Data System (ADS)

    Wang, Cong; Yang, Shengxue; Cai, Hui; Ataca, Can; Chen, Hui; Zhang, Xinzheng; Xu, Jingjun; Chen, Bin; Wu, Kedi; Zhang, Haoran; Liu, Luqi; Li, Jingbo; Grossman, Jeffrey C.; Tongay, Sefaattin; Liu, Qian

    2016-03-01

    Two-dimensional (2D) materials can take a large amount of mechanical deformation before reaching the fracture limit due to their high Young's modulus, and this in return, provides a way to tune the properties of 2D materials by strain engineering. Previous works have shown that the optical band gap of transition metal chalcogenides (TMDs) can be modulated by strain, resulting in a drift of the photoluminescence (PL) peak position and a decrease (or little change) in PL intensity. Here, we report a member of the post-transition metal chalcogenides (PTMCs), 2D-GaSe sheets, displaying vastly different phenomena under strain. Strained 2D-GaSe emits photons at almost the same wavelength as unstrained material but appears an order of magnitude brighter. In contrast to TMDs, optical spectroscopy measurements reveal that changes in the optical properties are mostly related to the colossal optical absorption anisotropy of GaSe, instead of commonly accepted strain-induced band renormalization. Results suggest that the light-matter interaction and the optical properties of 2D-GaSe can be controlled at will by manipulating the optical absorption.Two-dimensional (2D) materials can take a large amount of mechanical deformation before reaching the fracture limit due to their high Young's modulus, and this in return, provides a way to tune the properties of 2D materials by strain engineering. Previous works have shown that the optical band gap of transition metal chalcogenides (TMDs) can be modulated by strain, resulting in a drift of the photoluminescence (PL) peak position and a decrease (or little change) in PL intensity. Here, we report a member of the post-transition metal chalcogenides (PTMCs), 2D-GaSe sheets, displaying vastly different phenomena under strain. Strained 2D-GaSe emits photons at almost the same wavelength as unstrained material but appears an order of magnitude brighter. In contrast to TMDs, optical spectroscopy measurements reveal that changes in the optical

  13. Modeling and simulation challenges pursued by the Consortium for Advanced Simulation of Light Water Reactors (CASL)

    SciTech Connect

    Turinsky, Paul J.; Kothe, Douglas B.

    2016-05-15

    The Consortium for the Advanced Simulation of Light Water Reactors (CASL), the first Energy Innovation Hub of the Department of Energy, was established in 2010 with the goal of providing modeling and simulation (M&S) capabilities that support and accelerate the improvement of nuclear energy's economic competitiveness and the reduction of spent nuclear fuel volume per unit energy, and all while assuring nuclear safety. To accomplish this requires advances in M&S capabilities in radiation transport, thermal-hydraulics, fuel performance and corrosion chemistry. To focus CASL's R&D, industry challenge problems have been defined, which equate with long standing issues of the nuclear power industry that M&S can assist in addressing. To date CASL has developed a multi-physics “core simulator” based upon pin-resolved radiation transport and subchannel (within fuel assembly) thermal-hydraulics, capitalizing on the capabilities of high performance computing. CASL's fuel performance M&S capability can also be optionally integrated into the core simulator, yielding a coupled multi-physics capability with untapped predictive potential. Material models have been developed to enhance predictive capabilities of fuel clad creep and growth, along with deeper understanding of zirconium alloy clad oxidation and hydrogen pickup. Understanding of corrosion chemistry (e.g., CRUD formation) has evolved at all scales: micro, meso and macro. CFD R&D has focused on improvement in closure models for subcooled boiling and bubbly flow, and the formulation of robust numerical solution algorithms. For multiphysics integration, several iterative acceleration methods have been assessed, illuminating areas where further research is needed. Finally, uncertainty quantification and data assimilation techniques, based upon sampling approaches, have been made more feasible for practicing nuclear engineers via R&D on dimensional reduction and biased sampling. Industry adoption of CASL's evolving M

  14. Modeling and simulation challenges pursued by the Consortium for Advanced Simulation of Light Water Reactors (CASL)

    NASA Astrophysics Data System (ADS)

    Turinsky, Paul J.; Kothe, Douglas B.

    2016-05-01

    The Consortium for the Advanced Simulation of Light Water Reactors (CASL), the first Energy Innovation Hub of the Department of Energy, was established in 2010 with the goal of providing modeling and simulation (M&S) capabilities that support and accelerate the improvement of nuclear energy's economic competitiveness and the reduction of spent nuclear fuel volume per unit energy, and all while assuring nuclear safety. To accomplish this requires advances in M&S capabilities in radiation transport, thermal-hydraulics, fuel performance and corrosion chemistry. To focus CASL's R&D, industry challenge problems have been defined, which equate with long standing issues of the nuclear power industry that M&S can assist in addressing. To date CASL has developed a multi-physics ;core simulator; based upon pin-resolved radiation transport and subchannel (within fuel assembly) thermal-hydraulics, capitalizing on the capabilities of high performance computing. CASL's fuel performance M&S capability can also be optionally integrated into the core simulator, yielding a coupled multi-physics capability with untapped predictive potential. Material models have been developed to enhance predictive capabilities of fuel clad creep and growth, along with deeper understanding of zirconium alloy clad oxidation and hydrogen pickup. Understanding of corrosion chemistry (e.g., CRUD formation) has evolved at all scales: micro, meso and macro. CFD R&D has focused on improvement in closure models for subcooled boiling and bubbly flow, and the formulation of robust numerical solution algorithms. For multiphysics integration, several iterative acceleration methods have been assessed, illuminating areas where further research is needed. Finally, uncertainty quantification and data assimilation techniques, based upon sampling approaches, have been made more feasible for practicing nuclear engineers via R&D on dimensional reduction and biased sampling. Industry adoption of CASL's evolving M

  15. Advanced Fuels Campaign Light Water Reactor Accident Tolerant Fuel Performance Metrics

    SciTech Connect

    Brad Merrill; Melissa Teague; Robert Youngblood; Larry Ott; Kevin Robb; Michael Todosow; Chris Stanek; Mitchell Farmer; Michael Billone; Robert Montgomery; Nicholas Brown; Shannon Bragg-Sitton

    2014-02-01

    The safe, reliable and economic operation of the nation’s nuclear power reactor fleet has always been a top priority for the United States’ nuclear industry. As a result, continual improvement of technology, including advanced materials and nuclear fuels, remains central to industry’s success. Decades of research combined with continual operation have produced steady advancements in technology and yielded an extensive base of data, experience, and knowledge on light water reactor (LWR) fuel performance under both normal and accident conditions. In 2011, following the Great East Japan Earthquake, resulting tsunami, and subsequent damage to the Fukushima Daiichi nuclear power plant complex, enhancing the accident tolerance of LWRs became a topic of serious discussion. As a result of direction from the U.S. Congress, the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) initiated an Accident Tolerant Fuel (ATF) Development program. The complex multiphysics behavior of LWR nuclear fuel makes defining specific material or design improvements difficult; as such, establishing qualitative attributes is critical to guide the design and development of fuels and cladding with enhanced accident tolerance. This report summarizes a common set of technical evaluation metrics to aid in the optimization and down selection of candidate designs. As used herein, “metrics” describe a set of technical bases by which multiple concepts can be fairly evaluated against a common baseline and against one another. Furthermore, this report describes a proposed technical evaluation methodology that can be applied to assess the ability of each concept to meet performance and safety goals relative to the current UO2 – zirconium alloy system and relative to one another. The resultant ranked evaluation can then inform concept down-selection, such that the most promising accident tolerant fuel design option(s) can continue to be developed for lead test rod or lead test assembly

  16. Nuclear Systems Enhanced Performance Program, Maintenance Cycle Extension in Advanced Light Water Reactor Design

    SciTech Connect

    Professor Neill Todreas

    2001-10-01

    A renewed interest in new nuclear power generation in the US has spurred interest in developing advanced reactors with features which will address the public's concerns regarding nuclear generation. However, it is economic performance which will dictate whether any new orders for these plants will materialize. Economic performance is, to a great extent, improved by maximizing the time that the plant is on-line generating electricity relative to the time spent off-line conducting maintenance and refueling. Indeed, the strategy for the advanced light water reactor plant IRIS (International Reactor, Innovative and Secure) is to utilize an eight year operating cycle. This report describes a formalized strategy to address, during the design phase, the maintenance-related barriers to an extended operating cycle. The top-level objective of this investigation was to develop a methodology for injecting component and system maintainability issues into the reactor plant design process to overcome these barriers. A primary goal was to demonstrate the applicability and utility of the methodology in the context of the IRIS design. The first step in meeting the top-level objective was to determine the types of operating cycle length barriers that the IRIS design team is likely to face. Evaluation of previously identified regulatory and investment protection surveillance program barriers preventing a candidate operating PWR from achieving an extended (48 month) cycle was conducted in the context of the IRIS design. From this analysis, 54 known IRIS operating cycle length barriers were identified. The resolution methodology was applied to each of these barriers to generate design solution alternatives for consideration in the IRIS design. The methodology developed has been demonstrated to narrow the design space to feasible design solutions which enable a desired operating cycle length, yet is general enough to have broad applicability. Feedback from the IRIS design team indicates

  17. Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems

    SciTech Connect

    D. E. Shropshire

    2009-01-01

    The Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems, prepared to support the U.S. Advanced Fuel Cycle Initiative (AFCI) systems analysis, provides a technology-oriented baseline system cost comparison between the open fuel cycle and closed fuel cycle systems. The intent is to understand their overall cost trends, cost sensitivities, and trade-offs. This analysis also improves the AFCI Program’s understanding of the cost drivers that will determine nuclear power’s cost competitiveness vis-a-vis other baseload generation systems. The common reactor-related costs consist of capital, operating, and decontamination and decommissioning costs. Fuel cycle costs include front-end (pre-irradiation) and back-end (post-iradiation) costs, as well as costs specifically associated with fuel recycling. This analysis reveals that there are large cost uncertainties associated with all the fuel cycle strategies, and that overall systems (reactor plus fuel cycle) using a closed fuel cycle are about 10% more expensive in terms of electricity generation cost than open cycle systems. The study concludes that further U.S. and joint international-based design studies are needed to reduce the cost uncertainties with respect to fast reactor, fuel separation and fabrication, and waste disposition. The results of this work can help provide insight to the cost-related factors and conditions needed to keep nuclear energy (including closed fuel cycles) economically competitive in the U.S. and worldwide. These results may be updated over time based on new cost information, revised assumptions, and feedback received from additional reviews.

  18. Applications of the Advanced Light Source to problems in the earth, soil, and environmental sciences report of the workshop

    SciTech Connect

    Not Available

    1992-10-01

    This report discusses the following topics: ALS status and research opportunities; advanced light source applications to geological materials; applications in the soil and environmental sciences; x-ray microprobe analysis; potential applications of the ALS in soil and environmental sciences; and x-ray spectroscopy using soft x-rays: applications to earth materials.

  19. A single dose of alcohol does not meaningfully alter circadian phase advances and phase delays to light in humans.

    PubMed

    Burgess, Helen J; Rizvydeen, Muneer; Fogg, Louis F; Keshavarzian, Ali

    2016-04-15

    Central circadian timing influences mental and physical health. Research in nocturnal rodents has demonstrated that when alcohol is consumed, it reaches the central hypothalamic circadian pacemaker (suprachiasmatic nuclei) and can directly alter circadian phase shifts to light. In two separate studies, we examined, for the first time, the effects of a single dose of alcohol on circadian phase advances and phase delays to light in humans. Two 23-day within-subjects placebo-controlled counterbalanced design studies were conducted. Both studies consisted of 6 days of fixed baseline sleep to stabilize circadian timing, a 2-day laboratory session, a 6-day break, and a repeat of 6 days of fixed sleep and a 2-day laboratory session. In the phase advance study (n= 10 light drinkers, 24-45 yr), the laboratory sessions consisted of a baseline dim light phase assessment, sleep episode, alcohol (0.6 g/kg) or placebo, 2-h morning bright light pulse, and final phase assessment. In the phase-delay study (n= 14 light drinkers, 22-44 yr), the laboratory sessions consisted of a baseline phase assessment, alcohol (0.8 g/kg) or placebo, 2-h late night bright light pulse, sleep episode, and final phase assessment. In both studies, alcohol either increased or decreased the observed phase shifts to light (interaction P≥ 0.46), but the effect of alcohol vs. placebo on phase shifts to light was always on average smaller than 30 min. Thus, no meaningful effects of a single dose of alcohol vs. placebo on circadian phase shifts to light in humans were observed.

  20. Theory of light scattering in subwavelength metallic slot antenna array fabricated on subwavelength thin film

    NASA Astrophysics Data System (ADS)

    Choi, S. B.; Park, D. J.

    2015-10-01

    We demonstrate an analytic model that describes the near-field electromagnetic field profile near a subwavelength-sized metallic slot antenna fabricated on a thin dielectric substrate having a subwavelength thickness reaching λ/1000 in the terahertz frequency region. We found two-dimensional light diffraction induced by the two-dimensional nature of the slot antenna, and back-reflected waves interfered with each other in a complicated manner, resulting in a coupling of the Fourierdecomposed field amplitudes between the diffraction orders along the x and the y directions. We applied these findings to our model by modifying a previously developed model [D. J. Park et al., J. Korean Phys. Soc. 65, 1390 (2014)], and we monitor the effect on far-field transmission. This coupling effect was found to contribute to removal of physically-meaningless spikes or divergences in the transmission spectra, especially for relatively thick substrates.

  1. Si nanowire metal-insulator-semiconductor photodetectors as efficient light harvesters.

    PubMed

    Bae, Joonho; Kim, Hyunjin; Zhang, Xiao-Mei; Dang, Cuong H; Zhang, Yue; Choi, Young Jin; Nurmikko, Arto; Wang, Zhong Lin

    2010-03-05

    Novel ITO-Si nanowire (NW) metal-insulator-semiconductor (MIS) photodetectors were fabricated by using n-type Si NWs as detection units and ITO films as top gate electrodes. Measurements on the Si NW based device reveal a significant photoresponse, including photocurrent generation with an external quantum efficiency (EQE) of approximately 35% at a peak wavelength of 600 nm at zero external bias, and with an EQE of 70% at a peak wavelength of 800 nm at - 0.5 V bias. The NW device shows a flat and low reflectance and almost constant EQE up to a 60 degrees incident angle of illumination, demonstrating efficient visible-light harvesting by the Si NW antenna.

  2. Coupling mid-infrared light from a photonic crystal waveguide to metallic transmission lines

    SciTech Connect

    Blanco-Redondo, Andrea E-mail: r.hillenbrand@nanogune.eu; Garcia-Adeva, Angel; Zubia, Joseba

    2014-01-06

    We propose and theoretically study a hybrid structure consisting of a photonic crystal waveguide (PhC-wg) and a two-wire metallic transmission line (TL), engineered for efficient transfer of mid-infrared (mid-IR) light between them. An efficiency of 32% is obtained for the coupling from the transverse magnetic (TM) photonic mode to the symmetric mode of the TL, with a predicted intensity enhancement factor of 53 at the transmission line surface. The strong coupling is explained by the small phase velocity mismatch and sufficient spatial overlapping between the modes. This hybrid structure could find applications in highly integrated mid-IR photonic-plasmonic devices for biological and gas sensing, among others.

  3. Light scattering by epitaxial VO{sub 2} films near the metal-insulator transition point

    SciTech Connect

    Lysenko, Sergiy Fernández, Felix; Rúa, Armando; Figueroa, Jose; Vargas, Kevin; Cordero, Joseph; Aparicio, Joaquin; Sepúlveda, Nelson

    2015-05-14

    Experimental observation of metal-insulator transition in epitaxial films of vanadium dioxide is reported. Hemispherical angle-resolved light scattering technique is applied for statistical analysis of the phase transition processes on mesoscale. It is shown that the thermal hysteresis strongly depends on spatial frequency of surface irregularities. The transformation of scattering indicatrix depends on sample morphology and is principally different for the thin films with higher internal elastic strain and for the thicker films where this strain is suppressed by introduction of misfit dislocations. The evolution of scattering indicatrix, fractal dimension, surface power spectral density, and surface autocorrelation function demonstrates distinctive behavior which elucidates the influence of structural defects and strain on thermal hysteresis, twinning of microcrystallites, and domain formation during the phase transition.

  4. Diffusion of light gases in advanced nanoporous membranes and catalysts via NMR diffusometry

    NASA Astrophysics Data System (ADS)

    Mueller, Robert A.

    Diffusion in nanoporous gas separation membranes and catalysts plays an important role in their selectivity and performance. As a result, there is an intense effort towards development of novel membranes and catalysts with microstructures tailored for improved transport properties. Fundamental understanding and prediction of the mass transport properties of these materials can be obtained by studies of mass transport on a broad range of microscopic length scales. In this dissertation, a novel NMR diffusometry technique is employed to study the influence of the pore network properties on light gas diffusion for several nanoporous systems, which represent promising advanced gas separation membranes and catalysts. The following systems were investigated: (i) carbon molecular sieve membranes, (ii) mixed-matrix membranes and (iii) rare-earth aerogel catalysts. For carbon molecular sieve membranes, the self-diffusion properties of several light gases of industrial importance are characterized by investigating the dependences of the self diffusivity on displacement length scale, temperature, sorbate loading and composition. Analysis of these dependences and comparison of the measured microscopic transport data with the corresponding results of membrane permeation enabled the determination of membrane structural properties which lead to the remarkable diffusion selectivity of these membranes. For mixed-matrix membranes, detailed measurements of light gas sorbate diffusion over a broad range of microscopic length scales enables resolution of the different modes of sorbate self-diffusion inside mixed-matrix membranes. Finally for samaria-aerogel catalyst, the influence of catalyst packing is explored based on detailed microscopic diffusion measurements over a broad range of sorbate loading pressures and detailed data analysis. These studies were enabled by application of a novel pulsed-field gradient nuclear magnetic resonance technique, developed in part by this work

  5. Advanced transition metal phosphide materials from single-source molecular precursors

    NASA Astrophysics Data System (ADS)

    Colson, Adam Caleb

    In this thesis, the feasibility of employing organometallic single-source precursors in the preparation of advanced transition metal pnictide materials such as colloidal nanoparticles and films has been investigated. In particular, the ternary FeMnP phase was targeted as a model for preparing advanced heterobimetallic phosphide materials, and the iron-rich Fe3P phase was targeted due to its favorable ferromagnetic properties as well as the fact that the preparation of advanced Fe3P materials has been elusive by commonly used methods. Progress towards the synthesis of advanced Fe2--xMn xP nanomaterials and films was facilitated by the synthesis of the novel heterobimetallic complexes FeMn(CO)8(mu-PR1R 2) (R1 = H, R2 = H or R1 = H, R2 = Ph), which contain the relatively rare mu-PH2 and mu-PPhH functionalities. Iron rich Fe2--xMnxP nanoparticles were obtained by thermal decomposition of FeMn(CO)8(mu-PH 2) using solution-based synthetic methods, and empirical evidence suggested that oleic acid was responsible for manganese depletion. Films containing Fe, Mn, and P with the desired stoichiometric ratio of 1:1:1 were prepared using FeMn(CO)8(mu-PH2) in a simple low-pressure metal-organic chemical vapor deposition (MOCVD) apparatus. Although the elemental composition of the precursor was conserved in the deposited film material, spectroscopic evidence indicated that the films were not composed of pure-phase FeMnP, but were actually mixtures of crystalline FeMnP and amorphous FeP and Mn xOy. A new method for the preparation of phase-pure ferromagnetic Fe 3P films on quartz substrates has also been developed. This approach involved the thermal decomposition of the single-source precursors H 2Fe3(CO)9PR (R = tBu or Ph) at 400 °C. The films were deposited using a simple home-built MOCVD apparatus and were characterized using a variety of analytical methods. The films exhibited excellent phase purity, as evidenced by X-ray diffraction, X-ray photoelectron spectroscopy, and

  6. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Light Metals Permanent Mold Casting

    SciTech Connect

    Fasoyinu, Yemi

    2014-03-31

    Current vehicles use mostly ferrous components for structural applications. It is possible to reduce the weight of the vehicle by substituting these parts with those made from light metals such as aluminum and magnesium. Many alloys and manufacturing processes can be used to produce these light metal components and casting is known to be most economical. One of the high integrity casting processes is permanent mold casting which is the focus of this research report. Many aluminum alloy castings used in automotive applications are produced by the sand casting process. Also, aluminum-silicon (Al-Si) alloys are the most widely used alloy systems for automotive applications. It is possible that by using high strength aluminum alloys based on an aluminum-copper (Al-Cu) system and permanent mold casting, the performance of these components can be enhanced significantly. This will also help to further reduce the weight. However, many technological obstacles need to be overcome before using these alloys in automotive applications in an economical way. There is very limited information in the open literature on gravity and low-pressure permanent mold casting of high strength aluminum alloys. This report summarizes the results and issues encountered during the casting trials of high strength aluminum alloy 206.0 (Al-Cu alloy) and moderate strength alloy 535.0 (Al-Mg alloy). Five engineering components were cast by gravity tilt-pour or low pressure permanent mold casting processes at CanmetMATERIALS (CMAT) and two production foundries. The results of the casting trials show that high integrity engineering components can be produced successfully from both alloys if specific processing parameters are used. It was shown that a combination of melt processing and mold temperature is necessary for the elimination of hot tears in both alloys.

  7. Construction of stable Ta3N5/g-C3N4 metal/non-metal nitride hybrids with enhanced visible-light photocatalysis

    NASA Astrophysics Data System (ADS)

    Jiang, Yinhua; Liu, Peipei; Chen, YeCheng; Zhou, Zhengzhong; Yang, Haijian; Hong, Yuanzhi; Li, Fan; Ni, Liang; Yan, Yongsheng; Gregory, Duncan H.

    2017-01-01

    In this paper, a novel Ta3N5/g-C3N4 metal/non-metal nitride hybrid was successfully synthesized by a facile impregnation method. The photocatalytic activity of Ta3N5/g-C3N4 hybrid nitrides was evaluated by the degradation of organic dye rhodamine B (RhB) under visible light irradiation, and the result indicated that all Ta3N5/g-C3N4 samples exhibited distinctly enhanced photocatalytic activities for the degradation of RhB than pure g-C3N4. The optimal Ta3N5/g-C3N4 composite sample, with Ta3N5 mass ratio of 2%, demonstrated the highest photocatalytic activity, and its degradation rate constant was 2.71 times as high as that of pure g-C3N4. The enhanced photocatalytic activity of this Ta3N5/g-C3N4 metal/metal-free nitride was predominantly attributed to the synergistic effect which increased visible-light absorption and facilitated the efficient separation of photoinduced electrons and holes. The Ta3N5/g-C3N4 hybrid nitride exhibited excellent photostability and reusability. The possible mechanism for improved photocatalytic performance was proposed. Overall, this work may provide a facile way to synthesize the highly efficient metal/metal-free hybrid nitride photocatalysts with promising applications in environmental purification and energy conversion.

  8. Identification and partial characterization of a low affinity metal-binding site in the light chain of tetanus toxin.

    PubMed

    Wright, J F; Pernollet, M; Reboul, A; Aude, C; Colomb, M G

    1992-05-05

    Tetanus toxin was shown to contain a metal-binding site for zinc and copper. Equilibrium dialysis binding experiments using 65Zn indicated an association constant of 9-15 microM, with one zinc-binding site/toxin molecule. The zinc-binding site was localized to the toxin light chain as determined by binding of 65Zn to the light chain but not to the heavy chain after separation by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and transfer to Immobilon membranes. Copper was an efficient inhibitor of 65Zn binding to tetanus toxin and caused two peptide bond cleavages in the toxin light chain in the presence of ascorbate. These metal-catalyzed oxidative cleavages were inhibited by the presence of zinc. Partial characterization of metal-catalyzed oxidative modifications of a peptide based on a putative metal-binding site (HELIH) in the toxin light chain was used to map the metal-binding site in the protein.

  9. The U5.0 undulator design for the advanced light source at LBL

    NASA Astrophysics Data System (ADS)

    Hoyer, E.; Chin, J.; Halbach, K.; Hassenzahl, W.; Humphries, D.; Kincaid, B.; Lancaster, H.; Plate, D.; Savoy, R.

    1990-05-01

    The U5.0 undulator, currently under design, is the first in a series of insertion devices planned for the Advanced Light Source at LBL. U5.0 parameters include a 5-cm period and a 5-m length with an 0.837-T maximum field at a 14-mm gap. A hybrid configuration utilizing NdFeB permanent magnet material and vanadium permendur poles is used for the magnetic structure. Construction is modular with many pole assemblies attached to a pole mount, which in turn is fastened onto one of the backing beams. Vertical field integral correction at the ends is accomplished with permanent magnet rotators. The support structure features a four-post configuration, a rigid base with three kinematic floor supports, and two rigid 5-m long backing beams that fit within the 2.4-m-high accelerator enclosure. The drive system is computer-controlled using a stepper motor and shaft encoder coupled to a roller-screw/nut and chain drive train. Vacuum chamber design is a rigid configuration with a 10 mm vertical by 218 mm horizontal aperture of 5.5 m length. Chamber fabrication features a two-piece welded chamber of 5083 H321 aluminum. Pumping is with ion and titanium sublimation pumps.

  10. The advanced light source at Lawrence Berkeley laboratory: a new tool for research in atomic physics

    NASA Astrophysics Data System (ADS)

    Schlachter, Alfred S.; Robinson, Arthur L.

    1991-04-01

    The Advanced Light Source, a third-generation national synchrotron-radiation facility now under construction at the Lawrence Berkeley Laboratory, is scheduled to begin serving qualified users across a broad spectrum of research areas in the spring of 1993. Based on a low-emittance electron storage ring optimized to operate at 1.5 GeV, the ALS will have 10 long straight sections available for insertion devices (undulators and wigglers) and 24 high-quality bend-magnet ports. The short pulse width (30-50 ps) will be ideal for time-resolved measurements. Undulators will generate high-brightness partially coherent soft X-ray and ultraviolet (XUV) radiation from below 10 eV to above 2 keV; this radiation is plane polarized. Wigglers and bend magnets will extend the spectrum by generating high fluxes of X-rays to photon energies above 10 keV. The ALS will have an extensive research program in which XUV radiation is used to study matter in all its varied gaseous, liquid, and solid forms. The high brightness will open new areas of research in the materials sciences, such as spatially resolved spectroscopy (spectromicroscopy), and in biology, such as X-ray microscopy with element-specific sensitivity; the high flux will allow measurements in atomic physics and chemistry to be made with tenuous gas-phase targets. Technological applications could include lithography and nano-fabrication.

  11. Passive ALWR requirements to prevent containment failure. [Advanced light water reactors

    SciTech Connect

    Additon, S.L.; Blanchard, D.P.; Leaver, D.E.; Persinko, D. TENERA, L.P., Bethesda, MD )

    1991-12-01

    The purpose of this report is to document a systematic evaluation of the Passive Advanced Light Water Reactor (ALWR) design requirements which address severe accident mitigation. This evaluation was performed concurrent with completion of the ALWR Requirements Document to assure the adequacy of these mitigation requirements. The passive plant approach to containment integrity assurance reflects an expansion of the approach established earlier for evolutionary ALWRs. The report identifies containment challenges that might occur coincident with or result from a core damage event, compiles the set of passive ALWR design requirements which addresses each challenge, and evaluates each set of requirements on an integrated basis to confirm that the requirements provide substantial assurance that coincident core damage and containment failure are precluded. Based on past PRAs, a review of pertinent safety functions, severe accident analyses, current regulatory requirements, and reviews by ALWR design personnel, twenty-three (23) potential containment challenges were identified. The report concludes that the relevant ALWR requirements severe to limit the likelihood and magnitude of the challenges, and to assure the capability of the containment to accommodate all challenges which remain potentially risk-significant.

  12. Advanced Fuels Campaign Light Water Reactor Accident Tolerant Fuel Performance Metrics Executive Summary

    SciTech Connect

    Shannon Bragg-Sitton

    2014-02-01

    Research and development (R&D) activities on advanced, higher performance Light Water Reactor (LWR) fuels have been ongoing for the last few years. Following the unfortunate March 2011 events at the Fukushima Nuclear Power Plant in Japan, the R&D shifted toward enhancing the accident tolerance of LWRs. Qualitative attributes for fuels with enhanced accident tolerance, such as improved reaction kinetics with steam resulting in slower hydrogen generation rate, provide guidance for the design and development of fuels and cladding with enhanced accident tolerance. A common set of technical metrics should be established to aid in the optimization and down selection of candidate designs on a more quantitative basis. “Metrics” describe a set of technical bases by which multiple concepts can be fairly evaluated against a common baseline and against one another. This report describes a proposed technical evaluation methodology that can be applied to evaluate the ability of each concept to meet performance and safety goals relative to the current UO2 – zirconium alloy system and relative to one another. The resultant ranked evaluation can then inform concept down-selection, such that the most promising accident tolerant fuel design option(s) can continue to be developed toward qualification.

  13. Maintenance Cycle Extension in the IRIS Advanced Light Water Reactor Plant Design

    SciTech Connect

    Galvin, Mark R.; Todreas, Neil E.; Conway, Larry E.

    2003-09-15

    New nuclear power generation in the United States will be realized only if the economic performance can be made competitive with other methods of electrical power generation. The economic performance of a nuclear power plant can be significantly improved by increasing the time spent on-line generating electricity relative to the time spent off-line conducting maintenance and refueling. Maintenance includes planned actions (surveillances) and unplanned actions (corrective maintenance) to respond to component degradation or failure. A methodology is described that can be used to resolve, in the design phase, maintenance-related operating cycle length barriers. A primary goal was to demonstrate the applicability and utility of the methodology in the context of the International Reactor, Innovative and Secure (IRIS) design. IRIS is an advanced light water nuclear power plant that is being designed to maximize this on-line generating time by increasing the operating cycle length. This is consequently a maintenance strategy paper using the IRIS plant as the example.Potential IRIS operating cycle length maintenance-related barriers, determined by modification of an earlier operating pressurized water reactor (PWR) plant cycle length analysis to account for differences between the design of IRIS and this operating PWR, are presented. The proposed methodology to resolve these maintenance-related barriers by the design process is described. The results of applying the methodology to two potential IRIS cycle length barriers, relief valve testing and emergency heat removal system testing, are presented.

  14. Effects of light on quantum phases and topological properties of two-dimensional Metal-organic frameworks

    PubMed Central

    Wang, Yunhua; Liu, Yulan; Wang, Biao

    2017-01-01

    Periodically driven nontrivial quantum states open another door to engineer topological phases in solid systems by light. Here we show, based on the Floquet-Bloch theory, that the on-resonant linearly and circularly polarized infrared light brings in the exotic Floquet quantum spin Hall state and half-metal in two-dimensional Metal-organic frameworks (2D MOFs) because of the unbroken and broken time-reversal symmetry, respectively. We also observe that the off-resonant light triggers topological quantum phase transitions and induces semimetals with pseudospin-1 Dirac-Weyl fermions via the photon-dressed topological band structures of 2D MOFs. This work paves a way to design light-controlled spintronics and optoelectronics based on 2D MOFs. PMID:28134315

  15. Effects of light on quantum phases and topological properties of two-dimensional Metal-organic frameworks

    NASA Astrophysics Data System (ADS)

    Wang, Yunhua; Liu, Yulan; Wang, Biao

    2017-01-01

    Periodically driven nontrivial quantum states open another door to engineer topological phases in solid systems by light. Here we show, based on the Floquet-Bloch theory, that the on-resonant linearly and circularly polarized infrared light brings in the exotic Floquet quantum spin Hall state and half-metal in two-dimensional Metal-organic frameworks (2D MOFs) because of the unbroken and broken time-reversal symmetry, respectively. We also observe that the off-resonant light triggers topological quantum phase transitions and induces semimetals with pseudospin-1 Dirac-Weyl fermions via the photon-dressed topological band structures of 2D MOFs. This work paves a way to design light-controlled spintronics and optoelectronics based on 2D MOFs.

  16. Effects of light on quantum phases and topological properties of two-dimensional Metal-organic frameworks.

    PubMed

    Wang, Yunhua; Liu, Yulan; Wang, Biao

    2017-01-30

    Periodically driven nontrivial quantum states open another door to engineer topological phases in solid systems by light. Here we show, based on the Floquet-Bloch theory, that the on-resonant linearly and circularly polarized infrared light brings in the exotic Floquet quantum spin Hall state and half-metal in two-dimensional Metal-organic frameworks (2D MOFs) because of the unbroken and broken time-reversal symmetry, respectively. We also observe that the off-resonant light triggers topological quantum phase transitions and induces semimetals with pseudospin-1 Dirac-Weyl fermions via the photon-dressed topological band structures of 2D MOFs. This work paves a way to design light-controlled spintronics and optoelectronics based on 2D MOFs.

  17. Development of a metal-clad advanced composite shear web design concept

    NASA Technical Reports Server (NTRS)

    Laakso, J. H.

    1974-01-01

    An advanced composite web concept was developed for potential application to the Space Shuttle Orbiter main engine thrust structure. The program consisted of design synthesis, analysis, detail design, element testing, and large scale component testing. A concept was sought that offered significant weight saving by the use of Boron/Epoxy (B/E) reinforced titanium plate structure. The desired concept was one that was practical and that utilized metal to efficiently improve structural reliability. The resulting development of a unique titanium-clad B/E shear web design concept is described. Three large scale components were fabricated and tested to demonstrate the performance of the concept: a titanium-clad plus or minus 45 deg B/E web laminate stiffened with vertical B/E reinforced aluminum stiffeners.

  18. Advanced composite structures. [metal matrix composites - structural design criteria for spacecraft construction materials

    NASA Technical Reports Server (NTRS)

    1974-01-01

    A monograph is presented which establishes structural design criteria and recommends practices to ensure the design of sound composite structures, including composite-reinforced metal structures. (It does not discuss design criteria for fiber-glass composites and such advanced composite materials as beryllium wire or sapphire whiskers in a matrix material.) Although the criteria were developed for aircraft applications, they are general enough to be applicable to space vehicles and missiles as well. The monograph covers four broad areas: (1) materials, (2) design, (3) fracture control, and (4) design verification. The materials portion deals with such subjects as material system design, material design levels, and material characterization. The design portion includes panel, shell, and joint design, applied loads, internal loads, design factors, reliability, and maintainability. Fracture control includes such items as stress concentrations, service-life philosophy, and the management plan for control of fracture-related aspects of structural design using composite materials. Design verification discusses ways to prove flightworthiness.

  19. Final report to USAMP on the use of EBPVD in the light metal die casting industry

    SciTech Connect

    Heestand, G.M.

    1996-02-02

    This is the final report to the United States Automotive Materials Partnership (USAMP) on the use of Electron Beam Physical Vapor Deposition (EBPVD) to make rapid tooling for functional prototyping of metal mold processes. Historically this process has been successfully applied to the production of mold inserts for the plastics injection mold industry. Our approach for this project was to use the same technique to produce dies which could be used to make a few thousand light metal (aluminum and magnesium) prototype parts. The difficulty encountered in this project was that the requirements for the die casting industry, both in size and material requirements, were considerably more stringent than those encountered in the plastics injection industry. Consequently our technique, within the allotted time and budget constraints, was not able to meet the requirements set forth by USAMP. The remainder of this report is organized into five sections. The first discusses the technique in some detail while the second discusses a successful application. The third section discusses issues with this process while the fourth specifically discusses the work done in this project. The last is a short summary and conclusion section.

  20. Tunable color parallel tandem organic light emitting devices with carbon nanotube and metallic sheet interlayers

    SciTech Connect

    Oliva, Jorge; Desirena, Haggeo; De la Rosa, Elder; Papadimitratos, Alexios; Zakhidov, Anvar A.

    2015-11-21

    Parallel tandem organic light emitting devices (OLEDs) were fabricated with transparent multiwall carbon nanotube sheets (MWCNT) and thin metal films (Al, Ag) as interlayers. In parallel monolithic tandem architecture, the MWCNT (or metallic films) interlayers are an active electrode which injects similar charges into subunits. In the case of parallel tandems with common anode (C.A.) of this study, holes are injected into top and bottom subunits from the common interlayer electrode; whereas in the configuration of common cathode (C.C.), electrons are injected into the top and bottom subunits. Both subunits of the tandem can thus be monolithically connected functionally in an active structure in which each subunit can be electrically addressed separately. Our tandem OLEDs have a polymer as emitter in the bottom subunit and a small molecule emitter in the top subunit. We also compared the performance of the parallel tandem with that of in series and the additional advantages of the parallel architecture over the in-series were: tunable chromaticity, lower voltage operation, and higher brightness. Finally, we demonstrate that processing of the MWCNT sheets as a common anode in parallel tandems is an easy and low cost process, since their integration as electrodes in OLEDs is achieved by simple dry lamination process.

  1. Performance Enhancement of Organic Light-Emitting Diodes Using Electron-Injection Materials of Metal Carbonates

    NASA Astrophysics Data System (ADS)

    Shin, Jong-Yeol; Kim, Tae Wan; Kim, Gwi-Yeol; Lee, Su-Min; Shrestha, Bhanu; Hong, Jin-Woong

    2016-05-01

    Performance of organic light-emitting diodes was investigated depending on the electron-injection materials of metal carbonates (Li2CO3 and Cs2CO3 ); and number of layers. In order to improve the device efficiency, two types of devices were manufactured by using the hole-injection material (Teflon-amorphous fluoropolymer -AF) and electron-injection materials; one is a two-layer reference device ( ITO/Teflon-AF/Alq3/Al ) and the other is a three-layer device (ITO/Teflon-AF/Alq3/metal carbonate/Al). From the results of the efficiency for the devices with hole-injection layer and electron-injection layer, it was found that the electron-injection layer affects the electrical properties of the device more than the hole-injection layer. The external-quantum efficiency for the three-layer device with Li2CO3 and Cs2CO3 layer is improved by approximately six and eight times, respectively, compared with that of the two-layer reference device. It is thought that a use of electron-injection layer increases recombination rate of charge carriers by the active injection of electrons and the blocking of holes.

  2. Photoactive chiral metal-organic frameworks for light-driven asymmetric α-alkylation of aldehydes.

    PubMed

    Wu, Pengyan; He, Cheng; Wang, Jian; Peng, Xiaojun; Li, Xuezhao; An, Yonglin; Duan, Chunying

    2012-09-12

    Chiral metal-organic frameworks (MOFs) with porous and tunable nature show promise as heterogeneous asymmetric catalysts. Through incorporating the stereoselective organocatalyst L- or D-pyrrolidin-2-ylimidazole (PYI) and a triphenylamine photoredox group into a single framework, we have developed two enantiomeric MOFs, Zn-PYI1 and Zn-PYI2, to prompt the asymmetric α-alkylation of aliphatic aldehydes in a heterogeneous manner. The strong reductive excited state of the triphenylamaine moiety within these MOFs initiated a photoinduced electron transfer, rendering an active intermediate for the α-alkylation. The chiral PYI moieties acted as cooperative organocatalytic active sites to drive the asymmetric catalysis with significant stereoselectivity. Control experiments using the lanthanide-based metal-organic frameworks Ho-TCA and MOF-150, assembled from 4,4',4"-nitrilotribenzoic acid, as catalysts suggested that both the photosensitizer triphenylamine moiety and the chiral organocatalyst D-/L-PYI moiety were necessary for the light-driven α-alkylation reactions. Further investigations demonstrated that the integration of both photocatalyst and asymmetric organocatalyst into a single MOF makes the enantioselection superior to that of simply mixing the corresponding MOFs with the chiral adduct. The easy availability, excellent stereoselectivity, great separability, and individual components fixed with their well-defined porous and repeating structures make the MOF a versatile platform for a new type of tandem catalyst and cooperative catalyst.

  3. Understanding the superior photocatalytic activity of noble metals modified titania under UV and visible light irradiation.

    PubMed

    Bumajdad, Ali; Madkour, Metwally

    2014-04-28

    Although TiO2 is one of the most efficient photocatalysts, with the highest stability and the lowest cost, there are drawbacks that hinder its practical applications like its wide band gap and high recombination rate of the charge carriers. Consequently, many efforts were directed toward enhancing the photocatalytic activity of TiO2 and extending its response to the visible region. To head off these attempts, modification of TiO2 with noble metal nanoparticles (NMNPs) received considerable attention due to their role in accelerating the transfer of photoexcited electrons from TiO2 and also due to the surface plasmon resonance which induces the photocatalytic activity of TiO2 under visible light irradiation. This insightful perspective is devoted to the vital role of TiO2 photocatalysis and its drawbacks that urged researchers to find solutions such as modification with NMNPs. In a coherent context, we discussed here the characteristics which qualify NMNPs to possess a great enhancement effect for TiO2 photocatalysis. Also we tried to understand the reasons behind this effect by means of photoluminescence (PL) and electron paramagnetic resonance (EPR) spectra, and Density Functional Theory (DFT) calculations. Then the mechanism of action of NMNPs upon deposition on TiO2 is presented. Finally we introduced a survey of the behaviour of these noble metal NPs on TiO2 based on the particle size and the loading amount.

  4. Control method for transition metal oxides as a hole-injection layer for organic light-emitting devices

    NASA Astrophysics Data System (ADS)

    Zhang, Wejiang; Zhang, Jie

    2013-12-01

    The mechanism of transition metal oxide, molybdenum oxide (MoOx), used as interlayers in organic light-emitting devices (OLEDs) are investigated. The electronic structures and interfacial chemical reactions are investigated with ultraviolet and x-ray photoelectron spectroscopy. The influence of evaporation temperatures on the electronic structures of MoOx films and the electrical properties of organic light emitting diodes are investigated.

  5. Light-harvesting and ultrafast energy migration in porphyrin-based metal-organic frameworks.

    PubMed

    Son, Ho-Jin; Jin, Shengye; Patwardhan, Sameer; Wezenberg, Sander J; Jeong, Nak Cheon; So, Monica; Wilmer, Christopher E; Sarjeant, Amy A; Schatz, George C; Snurr, Randall Q; Farha, Omar K; Wiederrecht, Gary P; Hupp, Joseph T

    2013-01-16

    Given that energy (exciton) migration in natural photosynthesis primarily occurs in highly ordered porphyrin-like pigments (chlorophylls), equally highly ordered porphyrin-based metal-organic frameworks (MOFs) might be expected to exhibit similar behavior, thereby facilitating antenna-like light-harvesting and positioning such materials for use in solar energy conversion schemes. Herein, we report the first example of directional, long-distance energy migration within a MOF. Two MOFs, namely F-MOF and DA-MOF that are composed of two Zn(II) porphyrin struts [5,15-dipyridyl-10,20-bis(pentafluorophenyl)porphinato]zinc(II) and [5,15-bis[4-(pyridyl)ethynyl]-10,20-diphenylporphinato]zinc(II), respectively, were investigated. From fluorescence quenching experiments and theoretical calculations, we find that the photogenerated exciton migrates over a net distance of up to ~45 porphyrin struts within its lifetime in DA-MOF (but only ~3 in F-MOF), with a high anisotropy along a specific direction. The remarkably efficient exciton migration in DA-MOF is attributed to enhanced π-conjugation through the addition of two acetylene moieties in the porphyrin molecule, which leads to greater Q-band absorption intensity and much faster exciton-hopping (energy transfer between adjacent porphyrin struts). The long distance and directional energy migration in DA-MOF suggests promising applications of this compound or related compounds in solar energy conversion schemes as an efficient light-harvesting and energy-transport component.

  6. Strengthening TiN diffusion barriers for Cu metallization by lightly doping Al

    NASA Astrophysics Data System (ADS)

    Yang, L. C.; Hsu, C. S.; Chen, G. S.; Fu, C. C.; Zuo, J. M.; Lee, B. Q.

    2005-09-01

    Thin films of Ti1-xAlxN were deposited on (100) Si by ultrahigh-vacuum dual-target reactive sputtering, and the impact of lightly doping Al of x as small as 0.09 on altering the films's microstructure upon thermal annealing, and hence the performance of the films (40nm thick) as diffusion barriers for Cu metallization was evaluated. The results of transmission electron microscopy, Rutherford backscattering spectroscopy, and grazing-incidence x-ray diffraction show that the TiN barrier layer gives the commonly observed voided, columnar grains composed of 5nm sized subgrains. Upon annealing, the subgrains tend to coalesce into 20nm sized equiaxed grains full of crystalline defects, initiating an inward penetration of Cu and a partial dissociation of TiN, transforming themselves, respectively, into pyramidal (or columnar) Cu3Si precipitates and a dendritic Ti5Si3 layer just after 550°C, 10min annealing. However, the lightly doped Al not only overrides the tendency to form intercolumnar voids inherent in sputter deposition by self-shadowing and statistical roughening, but also substantially enhances the microstructural and thermochemical stability, hence significantly improving barrier property, as evidenced from an annealing test at an elevated temperature (600°C) for a prolonged period of 30min.

  7. Advances in Molten Oxide Electrolysis for the Production of Oxygen and Metals from Lunar Regolith

    NASA Technical Reports Server (NTRS)

    Sadoway, Donald R.; Sirk, Aislinn; Sibille, Laurent; Melendez, Orlando; Lueck, Dale; Curreri, Peter; Dominquez, Jesus; Whitlow, Jonathan

    2008-01-01

    As part of an In-Situ Resource Utilization infrastructure to sustain long term-human presence on the lunar surface, the production of oxygen and metals by electrolysis of lunar regolith has been the subject of major scrutiny. There is a reasonably large body of literature characterizing the candidate solvent electrolytes, including ionic liquids, molten salts, fluxed oxides, and pure molten regolith itself. In the light of this information and in consideration of available electrolytic technologies, the authors have determined that direct molten oxide electrolysis at temperatures of approx 1600 C is the most promising avenue for further development. Results from ongoing studies as well as those of previous workers will be presented. Topics include materials selection and testing, electrode stability, gas capture and analysis, and cell operation during feeding and tapping.

  8. Final LDRD report : design and fabrication of advanced device structures for ultra high efficiency solid state lighting.

    SciTech Connect

    Koleske, Daniel David; Bogart, Katherine Huderle Andersen; Shul, Randy John; Wendt, Joel Robert; Crawford, Mary Hagerott; Allerman, Andrew Alan; Fischer, Arthur Joseph

    2005-04-01

    The goal of this one year LDRD was to improve the overall efficiency of InGaN LEDs by improving the extraction of light from the semiconductor chip. InGaN LEDs are currently the most promising technology for producing high efficiency blue and green semiconductor light emitters. Improving the efficiency of InGaN LEDs will enable a more rapid adoption of semiconductor based lighting. In this LDRD, we proposed to develop photonic structures to improve light extraction from nitride-based light emitting diodes (LEDs). While many advanced device geometries were considered for this work, we focused on the use of a photonic crystal for improved light extraction. Although resonant cavity LEDs and other advanced structures certainly have the potential to improve light extraction, the photonic crystal approach showed the most promise in the early stages of this short program. The photonic crystal (PX)-LED developed here incorporates a two dimensional photonic crystal, or photonic lattice, into a nitride-based LED. The dimensions of the photonic crystal are selected such that there are very few or no optical modes in the plane of the LED ('lateral' modes). This will reduce or eliminate any radiation in the lateral direction so that the majority of the LED radiation will be in vertical modes that escape the semiconductor, which will improve the light-extraction efficiency. PX-LEDs were fabricated using a range of hole diameters and lattice constants and compared to control LEDs without a photonic crystal. The far field patterns from the PX-LEDs were dramatically modified by the presence of the photonic crystal. An increase in LED brightness of 1.75X was observed for light measured into a 40 degree emission cone with a total increase in power of 1.5X for an unencapsulated LED.

  9. Robotics application for in-service inspection of the ALMR. [Advanced Liquid Metal Reactor (ALMR)

    SciTech Connect

    Kwant, W.; Ramsour, N.L. . Nuclear Energy Div.); Sweeney, F.J. )

    1993-01-01

    The US Advanced Liquid Metal Reactor (ALMR) Program is developing and licensing a reactor system that is compact for factory fabrication and modular construction. The design includes provisions for in-service inspection to verify performance and safety capabilities throughout the life of the plant. A DOE sponsored robotics team, comprised of members from the universities of Florida, Michigan, Tennessee, Texas and from Oak Ridge National Laboratory, is developing advanced inspection equipment using robotics for nuclear application. This equipment is compact and remotely operated and particularly suited for inspection of the ALMR. Extensive 3D simulations are used to refine and demonstrate the inspection methods. This paper focuses on inspection methods for the reactor vessel and the reactor vessel auxiliary cooling system (RVACS). Inspection capabilities are included for visual inspection of the reactor vessel outer surface and volumetric inspection of the welds. The robotics team is devising a compact crawler design with the capabilities to perform these inspections. Similarly, various robot concepts are being evaluated for accomplishing the RVACS visual inspection and cleaning procedures.

  10. Preparation and characterization of B4C coatings for advanced research light sources

    PubMed Central

    Störmer, Michael; Siewert, Frank; Sinn, Harald

    2016-01-01

    X-ray optical elements are required for beam transport at the current and upcoming free-electron lasers and synchrotron sources. An X-ray mirror is a combination of a substrate and a coating. The demand for large mirrors with single layers consisting of light or heavy elements has increased during the last few decades; surface finishing technology is currently able to process mirror lengths up to 1 m with microroughness at the sub-nanometre level. Additionally, thin-film fabrication is able to deposit a suitable single-layer material, such as boron carbide (B4C), some tens of nanometres thick. After deposition, the mirror should provide excellent X-ray optical properties with respect to coating thickness errors, microroughness values and slope errors; thereby enabling the mirror to transport the X-ray beam with high reflectivity, high beam flux and an undistorted wavefront to an experimental station. At the European XFEL, the technical specifications of the future mirrors are extraordinarily challenging. The acceptable shape error of the mirrors is below 2 nm along the whole length of 1 m. At the Helmholtz-Zentrum Geesthacht (HZG), amorphous layers of boron carbide with thicknesses in the range 30–60 nm were fabricated using the HZG sputtering facility, which is able to cover areas up to 1500 mm long by 120 mm wide in one step using rectangular B4C sputtering targets. The available deposition area is suitable for the specified X-ray mirror dimensions of upcoming advanced research light sources such as the European XFEL. The coatings produced were investigated by means of X-ray reflectometry and interference microscopy. The experimental results for the B4C layers are discussed according to thickness uniformity, density, microroughness and thermal stability. The variation of layer thickness in the tangential and sagittal directions was investigated in order to estimate the achieved level of uniformity over the whole deposition area, which is

  11. Preparation and characterization of B4C coatings for advanced research light sources.

    PubMed

    Störmer, Michael; Siewert, Frank; Sinn, Harald

    2016-01-01

    X-ray optical elements are required for beam transport at the current and upcoming free-electron lasers and synchrotron sources. An X-ray mirror is a combination of a substrate and a coating. The demand for large mirrors with single layers consisting of light or heavy elements has increased during the last few decades; surface finishing technology is currently able to process mirror lengths up to 1 m with microroughness at the sub-nanometre level. Additionally, thin-film fabrication is able to deposit a suitable single-layer material, such as boron carbide (B4C), some tens of nanometres thick. After deposition, the mirror should provide excellent X-ray optical properties with respect to coating thickness errors, microroughness values and slope errors; thereby enabling the mirror to transport the X-ray beam with high reflectivity, high beam flux and an undistorted wavefront to an experimental station. At the European XFEL, the technical specifications of the future mirrors are extraordinarily challenging. The acceptable shape error of the mirrors is below 2 nm along the whole length of 1 m. At the Helmholtz-Zentrum Geesthacht (HZG), amorphous layers of boron carbide with thicknesses in the range 30-60 nm were fabricated using the HZG sputtering facility, which is able to cover areas up to 1500 mm long by 120 mm wide in one step using rectangular B4C sputtering targets. The available deposition area is suitable for the specified X-ray mirror dimensions of upcoming advanced research light sources such as the European XFEL. The coatings produced were investigated by means of X-ray reflectometry and interference microscopy. The experimental results for the B4C layers are discussed according to thickness uniformity, density, microroughness and thermal stability. The variation of layer thickness in the tangential and sagittal directions was investigated in order to estimate the achieved level of uniformity over the whole deposition area, which is considerably

  12. The U5.0 Undulator for the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Hoyer, E.; Chin, J.; Halbach, K.; Hassenzahl, W. V.; Humphries, D.; Kincaid, B.; Lancaster, H.; Plate, D.

    1992-01-01

    The U5.0 Undulator, an 89 period, 5 cm period length, 4.6 m long insertion device has been designed, is being fabricated, and is scheduled for completion in early 1992. This undulator will be the first high brightness source, in the 50 to 1,500 eV range, for the Advanced Light Source at the Lawrence Berkeley Laboratory. A hybrid magnetic configuration using Nd-Fe-B permanent magnet material and vanadium permendur poles has been selected to achieve the field quality needed to meet performance requirements. The magnetic structure is modular with each half consisting of five assembly sections, which provide the periodic structure, and end structures, for entrance and exit correction, mounted on a steel backing beam. Each assembly section consists of 35 half-period pole assemblies bolted to a mount. The required 0.837 T effective peak field at a 1.4 cm gap has been verified with model measurements. Vertical field integral correction is accomplished with the end structures, each having an arrangement of permanent magnet rotors which will be adjusted to minimize electron beam missteering over the undulator operating field range. To reduce the effect of environmental fields, the steel backing beams are connected through parallel, low-reluctance, Ni-Fe hinges. The magnetic structure is connected through four rollernuts to the drive system that provides gap adjustment with an arrangement of roller screws, chain drives, a gear reduction unit, and a stepper motor driven by a closed loop control system. Magnetic structure and drive system support are from a 2.4 m high structure which includes a support base with four vertical supports. The vacuum chamber design is a two-piece machined and welded 5083-H321 aluminum construction of 5.1 m length. Pumping is with a combination of ion, titanium sublimation pump and nonevaporable getter pumps. Magnetic design, subsystem design, and fabrication progress are presented.

  13. Soft x-ray optics for spectromicroscopy at the Advanced Light Source

    SciTech Connect

    Padmore, H.A.

    1996-09-01

    A variety of systems for performing spectromicroscopy, spatially resolved spectroscopy, are in operation or under construction at the Advanced Light Source (ALS). For example, part of the program is centered around the surface analysis problems of local semiconductor industries, and this has required the construction of a microscope with wafer handling, fiducialization, optical microscopy, coordinated ion beam etching, and X-ray Photoelectron Spectroscopy (XPS) integrated in this case with Kirkpatrick-Baez (K-B) grazing incidence micro-focusing optics. The microscope is to be used in conjunction with a highly efficient entrance slitless Spherical Grating Monochromator (SGM). The design and expected performance of this instrument will be described, with emphasis on the production of the elliptically curved surfaces of the K-B mirrors by elastic bending of flat mirror substrates. For higher resolution, zone-plate (Z-P) focusing optics are used and one instrument, a Scanning Transmission X-ray Microscope (STXM) is in routine operation on undulator beamline 7.0. A second Z-P based system is being commissioned on the same beamline, and differs from the STXM in that it will operate at Ultra-High Vacuum (UHV) and will be able to perform XPS at 0.1 {micro}m spatial resolution. Spatially resolved X-ray Absorption Spectroscopy (XAS) can be performed by imaging electrons photoemitted from a material with a Photo-Emission Electron Microscope (PEEM). The optical requirements of a beamline designed for PEEM are very different to those of micro-focus systems and they give examples of bending magnet and undulator based instruments.

  14. Chemical characterization of emissions from advanced technology light-duty vehicles

    NASA Astrophysics Data System (ADS)

    Graham, Lisa

    Results of detailed emissions measurements of seven 2000 model year advanced technology vehicles are reported. Six of the seven vehicles were imported from Europe and Japan and are not yet available for sale in Canada. Three of the vehicles were with direct injection diesel (DDI) technology, three with gasoline direct injection (GDI) technology and one vehicle was a gasoline-electric hybrid. It is expected that vehicles with these technologies will be forming a larger fraction of the Canadian light-duty vehicle fleet in the coming years in response to requirements to reduce greenhouse gas emissions from the transportation sector in support of Canada's ratification of the Kyoto Protocol; and as a result of improving fuel quality (most notably reducing the sulphur content of both diesel and gasoline). It is therefore important to understand the potential impacts on air quality of such changes in the composition of the vehicle fleet. The emissions from these vehicles were characterized over four test cycles representing different driving conditions. Samples of the exhaust were collected for determining methane, non-methane hydrocarbons and carbonyl compounds for the purposes of comparing ozone-forming potential of the emissions. Although these vehicles were not certified to Canadian emissions standards as tested, all vehicles met the then current Tier 1 emission standards, except for one diesel vehicle which did not meet the particulate matter (PM) standard. The DDI vehicles had the highest NO X emissions, the highest specific reactivity and the highest ozone-forming potential of the vehicles tested. When compared to conventional gasoline vehicles, the ozone-forming potential was equivalent. The GDI vehicles had lower NO X emissions, lower specific reactivity and lower ozone-forming potential than the conventional gasoline vehicles. Both the diesel and GDI vehicles had higher PM emissions than the conventional gasoline vehicles. The gasoline-electric hybrid vehicle

  15. Advanced light source vacuum policy and vacuum guidelines for beamlines and experiment endstations

    SciTech Connect

    Hussain, Z.

    1995-08-01

    The purpose of this document is to: (1) Explain the ALS vacuum policy and specifications for beamlines and experiment endstations. (2) Provide guidelines related to ALS vacuum policy to assist in designing beamlines which are in accordance with ALS vacuum policy. This document supersedes LSBL-116. The Advanced Light Source is a third generation synchrotron radiation source whose beam lifetime depends on the quality of the vacuum in the storage ring and the connecting beamlines. The storage ring and most of the beamlines share a common vacuum and are operated under ultra-high-vacuum (UHV) conditions. All endstations and beamline equipment must be operated so as to avoid contamination of beamline components, and must include proper safeguards to protect the storage ring vacuum from an accidental break in the beamline or endstation vacuum systems. The primary gas load during operation is due to thermal desorption and electron/photon induced desorption of contaminants from the interior of the vacuum vessel and its components. The desorption rates are considerably higher for hydrocarbon contamination, thus considerable emphasis is placed on eliminating these sources of contaminants. All vacuum components in a beamline and endstation must meet the ALS vacuum specifications. The vacuum design of both beamlines and endstations must be approved by the ALS Beamline Review Committee (BRC) before vacuum connections to the storage ring are made. The vacuum design is first checked during the Beamline Design Review (BDR) held before construction of the beamline equipment begins. Any deviation from the ALS vacuum specifications must be approved by the BRC prior to installation of the equipment on the ALS floor. Any modification that is incorporated into a vacuum assembly without the written approval of the BRC is done at the user`s risk and may lead to rejection of the whole assembly.

  16. First-principles simulation of light propagation and exciton dynamics in metal cluster nanostructures

    NASA Astrophysics Data System (ADS)

    Lisinetskaya, Polina G.; Röhr, Merle I. S.; Mitrić, Roland

    2016-06-01

    We present a theoretical approach for the simulation of the electric field and exciton propagation in ordered arrays constructed of molecular-sized noble metal clusters bound to organic polymer templates. In order to describe the electronic coupling between individual constituents of the nanostructure we use the ab initio parameterized transition charge method which is more accurate than the usual dipole-dipole coupling. The electronic population dynamics in the nanostructure under an external laser pulse excitation is simulated by numerical integration of the time-dependent Schrödinger equation employing the fully coupled Hamiltonian. The solution of the TDSE gives rise to time-dependent partial point charges for each subunit of the nanostructure, and the spatio-temporal electric field distribution is evaluated by means of classical electrodynamics methods. The time-dependent partial charges are determined based on the stationary partial and transition charges obtained in the framework of the TDDFT. In order to treat large plasmonic nanostructures constructed of many constituents, the approximate self-consistent iterative approach presented in (Lisinetskaya and Mitrić in Phys Rev B 89:035433, 2014) is modified to include the transition-charge-based interaction. The developed methods are used to study the optical response and exciton dynamics of Ag3+ and porphyrin-Ag4 dimers. Subsequently, the spatio-temporal electric field distribution in a ring constructed of ten porphyrin-Ag4 subunits under the action of circularly polarized laser pulse is simulated. The presented methodology provides a theoretical basis for the investigation of coupled light-exciton propagation in nanoarchitectures built from molecular size metal nanoclusters in which quantum confinement effects are important.

  17. Novel MoSe2 hierarchical microspheres for applications in visible-light-driven advanced oxidation processes

    NASA Astrophysics Data System (ADS)

    Dai, Chu; Qing, Enping; Li, Yong; Zhou, Zhaoxin; Yang, Chao; Tian, Xike; Wang, Yanxin

    2015-11-01

    Advanced oxidation processes as a green technology have been adopted by combining the semiconductor catalyst MoSe2 with H2O2 under visible radiation. And novel three-dimensional self-assembled molybdenum diselenide (MoSe2) hierarchical microspheres from nanosheets were produced by using organic, selenium cyanoacetic acid sodium (NCSeCH2COONa) as the source of Se. The obtained products possess good crystallinity and present hierarchical structures with the average diameter of 1 μm. The band gap of MoSe2 microspheres is 1.68 eV and they present excellent photocatalytic activity under visible light irradiation in the MoSe2-H2O2 system. This effective photocatalytic mechanism was investigated in this study and can be attributed to visible-light-driven advanced oxidation processes.

  18. Novel MoSe2 hierarchical microspheres for applications in visible-light-driven advanced oxidation processes.

    PubMed

    Dai, Chu; Qing, Enping; Li, Yong; Zhou, Zhaoxin; Yang, Chao; Tian, Xike; Wang, Yanxin

    2015-12-21

    Advanced oxidation processes as a green technology have been adopted by combining the semiconductor catalyst MoSe2 with H2O2 under visible radiation. And novel three-dimensional self-assembled molybdenum diselenide (MoSe2) hierarchical microspheres from nanosheets were produced by using organic, selenium cyanoacetic acid sodium (NCSeCH2COONa) as the source of Se. The obtained products possess good crystallinity and present hierarchical structures with the average diameter of 1 μm. The band gap of MoSe2 microspheres is 1.68 eV and they present excellent photocatalytic activity under visible light irradiation in the MoSe2-H2O2 system. This effective photocatalytic mechanism was investigated in this study and can be attributed to visible-light-driven advanced oxidation processes.

  19. Ultra-broadband near perfect absorption of visible light based on one-dimensional metal-dielectric-metal grating for TM polarization

    NASA Astrophysics Data System (ADS)

    Luo, Minghui; Zhou, Yun; Chen, Linsen; Ye, Yan; Shen, Su; Wu, Shangliang

    2016-10-01

    We numerically and analytically report an ultra-broadband near perfect absorber based on one-dimensional metal-dielectric-metal grating at visible light for TM polarization. A unit cell of this design is composed of metal-dielectric-metal grating, where the bottom metallic layer and the upper metallic coating are separated from each other by the intermediate dielectric grating. The absorber exhibits an average absorption of over 90% in the range 400-700nm. Moreover, they remain very high over a wide range of incident angle up to 45°.The electromagnetic field distributions are investigated, which reveals that this broadband absorption behavior is ascribed to the combination of surface plasmon resonance and cavity resonance. Furthermore, impedance calculations were carried out to explain the absorption behavior. The ultra-broadband near-perfect angle-robust absorber can be a good candidate for many fascinating applications, including solar-energy harvesting as well as producing artificial colors on a large scale substrate.

  20. ADVANCES IN BIOTREATMENT OF ACID MINE DRAINAGE AND BIORECOVERY OF METALS: 1. METAL PRECIPITATION FOR RECOVERY AND RECYCLE

    EPA Science Inventory

    Acid-mine drainage (AMD) is a severe pollution problem attributed to past mining activities. AMD is an acidic, metal-bearing wastewater generated by the oxidation of metal sulfides to sulfates by Thiobacillus bacteria in both active and abandoned mining operations. The wastewater...

  1. Focusing of light at the nanoapex of a metal microtip located above the plane of a dielectric or metal

    NASA Astrophysics Data System (ADS)

    Petrin, A. B.

    2016-09-01

    We study the focusing of the optical electromagnetic radiation energy into a nanoscale spatial region in the vicinity of the nanoapex of a metal microtip located near a dielectric or metal plane. Focusing arises from a symmetric convergence of a surface plasmon TM wave at the nanoapex. The metal boundary near the nanoapex is approximated by a paraboloid of revolution. A numerical model, based on the method of moments, is developed to find the electric field near the tip apex. Calculation results show that, compared to a single tip, the presence of a plane leads to an additional concentration of the electric field near the nanoapex.

  2. Amorphous mixed-metal hydroxide nanostructures for advanced water oxidation catalysts

    NASA Astrophysics Data System (ADS)

    Gao, Y. Q.; Liu, X. Y.; Yang, G. W.

    2016-02-01

    The design of highly efficient, durable, and earth-abundant catalysts for the oxygen evolution reaction (OER) is crucial in order to promote energy conversion and storage processes. Here, we synthesize amorphous mixed-metal (Ni-Fe) hydroxide nanostructures with a homogeneous distribution of Ni/Fe as well as a tunable Ni/Fe ratio by a simple, facile, green and low-cost electrochemical technique, and we demonstrate that the synthesized amorphous nanomaterials possess ultrahigh activity and super long-term cycle stability in the OER process. The amorphous Ni0.71Fe0.29(OH)x nanostructure affords a current density of 10 mA cm-2 at an overpotential of a mere 0.296 V and a small Tafel slope of 58 mV dec-1, while no deactivation is detected in the CV testing even up to 30 000 cycles, which suggests the promising application of these amorphous nanomaterials in electrochemical oxidation. Meanwhile, the distinct catalytic activities among these amorphous Ni-Fe hydroxide nanostructures prompts us to take notice of the composition of the alloy hydroxides/oxides when studying their catalytic properties, which opens an avenue for the rational design and controllable preparation of such amorphous nanomaterials as advanced OER electrocatalysts.The design of highly efficient, durable, and earth-abundant catalysts for the oxygen evolution reaction (OER) is crucial in order to promote energy conversion and storage processes. Here, we synthesize amorphous mixed-metal (Ni-Fe) hydroxide nanostructures with a homogeneous distribution of Ni/Fe as well as a tunable Ni/Fe ratio by a simple, facile, green and low-cost electrochemical technique, and we demonstrate that the synthesized amorphous nanomaterials possess ultrahigh activity and super long-term cycle stability in the OER process. The amorphous Ni0.71Fe0.29(OH)x nanostructure affords a current density of 10 mA cm-2 at an overpotential of a mere 0.296 V and a small Tafel slope of 58 mV dec-1, while no deactivation is detected in the CV

  3. High-resolution imaging of hypervelocity metal jets using advanced high-speed photographic techniques

    SciTech Connect

    Shaw, L.L.; Muelder, S.A.

    1995-08-29

    It is now possible to obtain high resolution sequential photographs of the initial formation and evolution of hypervelocity metal jets formed by shaped charge devices fired in air. Researchers have been frustrated by the high velocity of the jet material and the luminous sheath of hot gases cloaking the jet that made detailed observation of the jet body extremely difficult. The camera system that provides the photographs is a large format multi-frame electro-optic camera, referred to as an IC camera (IC stands for image converter), that utilizes electro-optic shuttering, monochromatic pulsed laser illumination and bandpass filtering to provide sequential pictures (in 3D if desired) with minimal degradation due to luminous air shocks or motion blur. The large format (75mm image plane), short exposure (15 ns minimum), ruby laser illumination and bandpass filtering (monochromatic illumination while excluding extraneous light) produces clear, sharp, images of the detailed surface structure of a metal shaped charge jet during early jet formation, elongation of the jet body, jet tip evolution and subsequent particulation (breakup) of the jet body. By utilizing the new camera system in conjunction with the more traditional rotating mirror high speed cameras, pulsed radiography, and electrical sensors, a maximum amount of, often unique, data can be extracted from a single experiment. This paper was intended primarily as an oral presentation. For purposes of continuity and simplicity in these proceedings, the authors have chosen to concentrate on the development of the IC camera system and its impact on the photography of high speed shaped chargejets.

  4. Metamaterial-based theoretical description of light scattering by metallic nano-hole array structures

    SciTech Connect

    Singh, Mahi R.; Najiminaini, Mohamadreza; Carson, Jeffrey J. L.; Balakrishnan, Shankar

    2015-05-14

    We have experimentally and theoretically investigated the light-matter interaction in metallic nano-hole array structures. The scattering cross section spectrum was measured for three samples each having a unique nano-hole array radius and periodicity. Each measured spectrum had several peaks due to surface plasmon polaritons. The dispersion relation and the effective dielectric constant of the structure were calculated using transmission line theory and Bloch's theorem. Using the effective dielectric constant and the transfer matrix method, the surface plasmon polariton energies were calculated and found to be quantized. Using these quantized energies, a Hamiltonian for the surface plasmon polaritons was written in the second quantized form. Working with the Hamiltonian, a theory of scattering cross section was developed based on the quantum scattering theory and Green's function method. For both theory and experiment, the location of the surface plasmon polariton spectral peaks was dependant on the array periodicity and radii of the nano-holes. Good agreement was observed between the experimental and theoretical results. It is proposed that the newly developed theory can be used to facilitate optimization of nanosensors for medical and engineering applications.

  5. Thermally sprayed prepregs for thixoforging of UD fiber reinforced light metal MMCs

    SciTech Connect

    Silber, Martin; Wenzelburger, Martin; Gadow, Rainer

    2007-04-07

    Low density and good mechanical properties are the basic requirements for lightweight structures in automotive and aerospace applications. With their high specific strength and strain to failure values, aluminum alloys could be used for such applications. Only the insufficient stiffness and thermal and fatigue strength prevented their usage in high-end applications. One possibility to solve this problem is to reinforce the light metal with unidirectional fibers. The UD fiber allows tailoring of the reinforcement to meet the direction of the component's load. In this study, the production of thermally sprayed prepregs for the manufacturing of continuous fiber reinforced MMC by thixoforging is analysed. The main aim is to optimize the winding procedure, which determines the fiber strand position and tension during the coating process. A method to wind and to coat the continuous fibers with an easy-to-use handling technique for the whole manufacturing process is presented. The prepregs were manufactured by producing arc wire sprayed AlSi6 coatings on fibers bundles. First results of bending experiments showed appropriate mechanical properties.

  6. Metamaterial-based theoretical description of light scattering by metallic nano-hole array structures

    NASA Astrophysics Data System (ADS)

    Singh, Mahi R.; Najiminaini, Mohamadreza; Balakrishnan, Shankar; Carson, Jeffrey J. L.

    2015-05-01

    We have experimentally and theoretically investigated the light-matter interaction in metallic nano-hole array structures. The scattering cross section spectrum was measured for three samples each having a unique nano-hole array radius and periodicity. Each measured spectrum had several peaks due to surface plasmon polaritons. The dispersion relation and the effective dielectric constant of the structure were calculated using transmission line theory and Bloch's theorem. Using the effective dielectric constant and the transfer matrix method, the surface plasmon polariton energies were calculated and found to be quantized. Using these quantized energies, a Hamiltonian for the surface plasmon polaritons was written in the second quantized form. Working with the Hamiltonian, a theory of scattering cross section was developed based on the quantum scattering theory and Green's function method. For both theory and experiment, the location of the surface plasmon polariton spectral peaks was dependant on the array periodicity and radii of the nano-holes. Good agreement was observed between the experimental and theoretical results. It is proposed that the newly developed theory can be used to facilitate optimization of nanosensors for medical and engineering applications.

  7. An advanced field experimental design to assess plant tolerance to heavy metal pollution

    NASA Astrophysics Data System (ADS)

    Łopata, Barbara; Szarek-Łukaszewska, Grażyna; Babst-Kostecka, Alicja

    2016-04-01

    Only a limited number of vascular plant species can survive and reproduce in toxic metalliferous environments. Among these species, pseudometallophytes are particularly interesting, as their metallicolous (M) populations on metalliferous soils and non-metallicolous (NM) populations on non-metalliferous soils show very pronounced ecological differences. Pseudometallophytes thus provide excellent opportunities for multidisciplinary research to improve phytoremediation and phytomining. Numerous methods have been developed to investigate plant adaptation to metal pollution, the majority of which has been conducted under controlled laboratory conditions. Although these efforts have significantly advanced our understanding of mechanisms underlying metal tolerance in plants, populations must be reciprocally transplanted to clearly identify natural selection. Only then is it possible to test, whether the fitness of native plants is higher than that of nonnative populations and thereby prove local adaptation. Here, we present an enhanced field experimental design aimed at verification of local adaptation to habitats with different levels of heavy metal soil contamination. At two M and two NM sites, we established a total of 12 plots (4 sites x 3 plots each), removed the existing local vegetation, and collected soil samples for chemical analyses (5 samples per plot). Plant collection (N= 480) from all four selected populations was established under laboratory conditions prior to the transplant experiment. Genotypes were randomly distributed within each plot (240 x 270 cm) and planted along a regulary spaced grid (30x30cm cell size) in spring 2015. Measurements will start in spring 2016, by which time plants are expected to have acclimatized to the local conditions. For the two subsiquent years, growth, survival, fitness, life cycle and herbivory consumption will be monitored for each transplant. On a weekly basis, we will record: 1) pictures of each transplant to determine

  8. Transition-metal-catalyzed Suzuki-Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts.

    PubMed

    Han, Fu-She

    2013-06-21

    In the transition-metal-catalyzed cross-coupling reactions, the use of the first row transition metals as catalysts is much more appealing than the precious metals owing to the apparent advantages such as cheapness and earth abundance. Within the last two decades, particularly the last five years, explosive interests have been focused on the nickel-catalyzed Suzuki-Miyaura reactions. This has greatly advanced the chemistry of transition-metal-catalyzed cross-coupling reactions. Most notably, a broad range of aryl electrophiles such as phenols, aryl ethers, esters, carbonates, carbamates, sulfamates, phosphates, phosphoramides, phosphonium salts, and fluorides, as well as various alkyl electrophiles, which are conventionally challenging, by applying palladium catalysts can now be coupled efficiently with boron reagents in the presence of nickel catalysts. In this review, we would like to summarize the progress in this reaction.

  9. Flame Experiments at the Advanced Light Source: New Insights into Soot Formation Processes

    PubMed Central

    Hansen, Nils; Skeen, Scott A.; Michelsen, Hope A.; Wilson, Kevin R.; Kohse-Höinghaus, Katharina

    2014-01-01

    The following experimental protocols and the accompanying video are concerned with the flame experiments that are performed at the Chemical Dynamics Beamline of the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory1-4. This video demonstrates how the complex chemical structures of laboratory-based model flames are analyzed using flame-sampling mass spectrometry with tunable synchrotron-generated vacuum-ultraviolet (VUV) radiation. This experimental approach combines isomer-resolving capabilities with high sensitivity and a large dynamic range5,6. The first part of the video describes experiments involving burner-stabilized, reduced-pressure (20-80 mbar) laminar premixed flames. A small hydrocarbon fuel was used for the selected flame to demonstrate the general experimental approach. It is shown how species’ profiles are acquired as a function of distance from the burner surface and how the tunability of the VUV photon energy is used advantageously to identify many combustion intermediates based on their ionization energies. For example, this technique has been used to study gas-phase aspects of the soot-formation processes, and the video shows how the resonance-stabilized radicals, such as C3H3, C3H5, and i-C4H5, are identified as important intermediates7. The work has been focused on soot formation processes, and, from the chemical point of view, this process is very intriguing because chemical structures containing millions of carbon atoms are assembled from a fuel molecule possessing only a few carbon atoms in just milliseconds. The second part of the video highlights a new experiment, in which an opposed-flow diffusion flame and synchrotron-based aerosol mass spectrometry are used to study the chemical composition of the combustion-generated soot particles4. The experimental results indicate that the widely accepted H-abstraction-C2H2-addition (HACA) mechanism is not the sole molecular growth process responsible for the formation of the

  10. Flame experiments at the advanced light source: new insights into soot formation processes.

    PubMed

    Hansen, Nils; Skeen, Scott A; Michelsen, Hope A; Wilson, Kevin R; Kohse-Höinghaus, Katharina

    2014-05-26

    The following experimental protocols and the accompanying video are concerned with the flame experiments that are performed at the Chemical Dynamics Beamline of the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory(1-4). This video demonstrates how the complex chemical structures of laboratory-based model flames are analyzed using flame-sampling mass spectrometry with tunable synchrotron-generated vacuum-ultraviolet (VUV) radiation. This experimental approach combines isomer-resolving capabilities with high sensitivity and a large dynamic range(5,6). The first part of the video describes experiments involving burner-stabilized, reduced-pressure (20-80 mbar) laminar premixed flames. A small hydrocarbon fuel was used for the selected flame to demonstrate the general experimental approach. It is shown how species' profiles are acquired as a function of distance from the burner surface and how the tunability of the VUV photon energy is used advantageously to identify many combustion intermediates based on their ionization energies. For example, this technique has been used to study gas-phase aspects of the soot-formation processes, and the video shows how the resonance-stabilized radicals, such as C3H3, C3H5, and i-C4H5, are identified as important intermediates(7). The work has been focused on soot formation processes, and, from the chemical point of view, this process is very intriguing because chemical structures containing millions of carbon atoms are assembled from a fuel molecule possessing only a few carbon atoms in just milliseconds. The second part of the video highlights a new experiment, in which an opposed-flow diffusion flame and synchrotron-based aerosol mass spectrometry are used to study the chemical composition of the combustion-generated soot particles(4). The experimental results indicate that the widely accepted H-abstraction-C2H2-addition (HACA) mechanism is not the sole molecular growth process responsible for the formation

  11. TCO/metal hybrid structures for surface plasmon enhanced light emitting in the near infrared range (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Fang, Xu; Zhang, Shiyu; Xia, Liang; Ye, Hui

    2015-09-01

    Transparent conductive oxides (TCOs, such as Sn:In2O3, Al:ZnO, Ga: ZnO et al) have re-drawn people's attention as alternative candidates of noble metals (particularly Ag or Au) in the field of plasmonic for the reasons of property tunable and low losses et al. However even for Sn:In2O3 (ITO, reported highest conductivity), the metallic property lies in the near infrared (NIR) range exhibiting the real part permittivity ɛ' was around -3 at communication wavelength of 1.55μm. Under this circumstance, surface plasma polaritons (SPPs) was hard to be exited on the interface between ITO and surrounded dielectric materials with large permittivity. Hence, in order to explore the potential use of TCOs in the applications of silicon photonics (for permittivity of silicon and germanium are 11.6 and 16 at 300K, respectively), we design a hybrid structure of ITO/metal or ITO/metal/ITO as surface plasmonic materials in NIR. The electrical and optical property of hybrid structure was manipulated accordingly by changing the portion of the introduced metal while maintaining a lower loss than bare metals. The highest carrier concentration of the hybrid structure reached 3×10^22cm^-3, definitely the same magnitude of noble metals. Magnetron sputtering and atomic layer deposition (ALD) can be used to deposit the hybrid ITO/metal structure, in which metal represents gold (Au), and iridium (Ir). The normalized radiative decay rate of light emitted by germanium quantum dots reaches a maximum enhancement of ~8-fold with the assistance of ITO/metal hybrid structure according to the finite difference time domain (FDTD) simulation.

  12. Yellow/orange emissive heavy-metal complexes as phosphors in monochromatic and white organic light-emitting devices.

    PubMed

    Fan, Cong; Yang, Chuluo

    2014-09-07

    Owing to the electron spin-orbit coupling (SOC) and fast intersystem crossing (ISC), heavy-metal complexes (such as iridium(III), platinum(II) and osmium(II) complexes, etc.) are phosphorescent emitters at room temperature. Since 1998, heavy-metal complexes as phosphors have received considerable academic and industrial attention in the field of organic light-emitting diodes (OLEDs), because they can harvest both the singlet (25%) and triplet (75%) excitons for emission during the electro-generated processes. Among all the visible colors (blue, green, yellow, orange and red), the yellow/orange heavy-metal complexes play an important role for realizing full-color OLEDs as well as high-efficiency white OLEDs, and thus the development of highly efficient yellow/orange heavy-metal complexes is a pressing concern. In this article, we will review the progress on yellow/orange heavy-metal complexes as phosphors in OLEDs. The general principles and useful tactics for designing the yellow/orange heavy-metal complexes will be systematically summarized. The structure-property relationship and electrophosphorescence performance of the yellow/orange heavy-metal complexes in monochromatic phosphorescent OLEDs (PhOLEDs) and white OLEDs (WOLEDs) will be comprehensively surveyed and discussed.

  13. The emerging multiple metal nanostructures for enhancing the light trapping of thin film organic photovoltaic cells.

    PubMed

    Choy, Wallace C H

    2014-10-18

    Recently, various metal nanostructures have been introduced into organic solar cells (OSCs) for performance enhancement. Here, we review the recent progress in OSCs incorporated with multiple metal nanostructures including various metal nanopatterns and metal nanomaterials. Multiple physical effects arise from these incorporated nanostructures, which require careful distinction. Changes induced by the metal nanostructures are examined in detail from the optical and electrical aspects. With the comprehensive understanding of the physical mechanisms for various metal nanostructures, further improvement in device performance and emerging applications can be expected for the new class of nanostructure-incorporated OSCs.

  14. Amorphous mixed-metal hydroxide nanostructures for advanced water oxidation catalysts.

    PubMed

    Gao, Y Q; Liu, X Y; Yang, G W

    2016-03-07

    The design of highly efficient, durable, and earth-abundant catalysts for the oxygen evolution reaction (OER) is crucial in order to promote energy conversion and storage processes. Here, we synthesize amorphous mixed-metal (Ni-Fe) hydroxide nanostructures with a homogeneous distribution of Ni/Fe as well as a tunable Ni/Fe ratio by a simple, facile, green and low-cost electrochemical technique, and we demonstrate that the synthesized amorphous nanomaterials possess ultrahigh activity and super long-term cycle stability in the OER process. The amorphous Ni0.71Fe0.29(OH)x nanostructure affords a current density of 10 mA cm(-2) at an overpotential of a mere 0.296 V and a small Tafel slope of 58 mV dec(-1), while no deactivation is detected in the CV testing even up to 30 000 cycles, which suggests the promising application of these amorphous nanomaterials in electrochemical oxidation. Meanwhile, the distinct catalytic activities among these amorphous Ni-Fe hydroxide nanostructures prompts us to take notice of the composition of the alloy hydroxides/oxides when studying their catalytic properties, which opens an avenue for the rational design and controllable preparation of such amorphous nanomaterials as advanced OER electrocatalysts.

  15. Analysis of hot forming of a sheet metal component made of advanced high strength steel

    NASA Astrophysics Data System (ADS)

    Demirkaya, Sinem; Darendeliler, Haluk; Gökler, Mustafa İlhan; Ayhaner, Murat

    2013-05-01

    To provide reduction in weight while maintaining crashworthiness and to decrease the fuel consumption of vehicles, thinner components made of Advanced High Strength Steels (AHSS) are being increasingly used in automotive industry. However, AHSS cannot be formed easily at the room temperature (i.e. cold forming). The alternative process involves heating, hot forming and subsequent quenching. A-pillar upper reinforcement of a vehicle is currently being produced by cold forming of DP600 steel sheet with a thickness of 1.8 mm. In this study, the possible decrease in the thickness of this particular part by using 22MnB5 as appropriate AHSS material and applying this alternative process has been studied. The proposed process involves deep drawing, trimming, heating, sizing, cooling and piercing operations. Both the current production process and the proposed process are analyzed by the finite element method. The die geometry, blank holding forces and the design of the cooling channels for the cooling process are determined numerically. It is shown that the particular part made of 22MnB5 steel sheet with a thickness of 1.2 mm can be successfully produced by applying the proposed process sequence and can be used without sacrificing the crashworthiness. With the use of the 22MnB5 steel with a thickness of 1.2 mm instead of DP600 sheet metal with a thickness of 1.8 mm, the weight is reduced by approximately 33%.

  16. The effect of advanced treatment on chlorine decay in metallic pipes.

    PubMed

    Rossman, Lewis A

    2006-07-01

    Experiments were run to measure what effect advanced treatment might have on the kinetics of chlorine and chloramine decay in metallic pipes that comprise many drinking water distribution systems. A recirculating loop of 6-in diameter unlined ductile iron pipe was used to simulate turbulent flow conditions in a pipe with significant corrosion and tubercle buildup. Conventionally treated test water was subjected to either ozonation, carbon adsorption (GAC), reverse osmosis (RO) or no further treatment before being chlorinated and introduced into the pipeline simulator. Results showed that overall chlorine decay in the simulator was consistently dominated by wall reactions whose first-order rate constants were an order of magnitude higher than those for the bulk water. With free chlorine, the wall rate constants for ozonated and GAC-treated water were about twice those of conventional or RO-treated water. This behavior is believed due to the effect that changes in the organic content of water have on its ability to complex iron and the effect that changes in water conductivity have on pipe wall corrosion. Tests run with chloraminated water showed no statistically significant effect of treatment type and had wall rate constants that were only 40 to 70% as high as those using free chlorine.

  17. Hydrometallurgical recovery of heavy metals from low grade automobile shredder residue (ASR): An application of advanced Fenton process (AFP).

    PubMed

    Singh, Jiwan; Lee, Byeong-Kyu

    2015-09-15

    To investigate the leaching and recovery of heavy metals from low-grade automobile shredder residue (ASR), the effects of nitric acid (HNO3) and hydrogen peroxide (H2O2) concentrations, liquid/solid (L/S) ratio, leaching temperature and ASR particle size fractions on the heavy metal leaching rate were determined. The heavy metals were recovered by fractional precipitation and advanced Fenton process (AFP) at different pHs. The toxicity characteristic leaching procedure (TCLP) test was also performed in the residue remaining after heavy metal leaching to evaluate the potential toxicity of ASR. The heavy metal leaching efficiency was increased with increasing HNO3 and H2O2 concentrations, L/S ratio and temperature. The heavy metal leaching efficiencies were maximized in the lowest ASR size fraction at 303 K and L/S ratio of 100 mL/g. The kinetic study showed that the metal leaching was best represented by a second-order reaction model, with a value of R(2) > 0.99 for all selected heavy metals. The determined activation energy (kJ/mol) was 21.61, 17.10, 12.15, 34.50, 13.07 and 11.45 for Zn, Fe, Ni, Pb, Cd and Cr, respectively. In the final residue, the concentrations of Cd, Cr and Pb were under their threshold limits in all ASR size fractions. Hydrometallurgical metal recovery was greatly increased by AFP up to 99.96% for Zn, 99.97% for Fe, 95.62% for Ni, 99.62% for Pb, 94.11% for Cd and 96.79% for Cr. AFP is highly recommended for the recovery of leached metals from solution even at low concentrations.

  18. Phenyl Benzo[b]phenothiazine as a Visible Light Photoredox Catalyst for Metal-Free Atom Transfer Radical Polymerization.

    PubMed

    Dadashi-Silab, Sajjad; Pan, Xiangcheng; Matyjaszewski, Krzysztof

    2016-12-23

    This paper reports use of phenyl benzo[b]phenothiazine (Ph-benzoPTZ) as a visible light-induced metal-free atom transfer radical polymerization (ATRP) photoredox catalyst. Well-controlled polymerizations of various methacrylate monomers were conducted under a 392 nm visible light LED using Ph-benzoPTZ to activate different alkyl halides. The use of the photocatalyst enabled temporal control over the growth of polymer chains during intermittent on/off periods. The polymerization was initiated and progressed only under stimulation by light and completely stopped in the absence of light. Block copolymers were synthesized to demonstrate high retention of chain end fidelity in the polymers and livingness of the process.

  19. Efficient stray-light suppression for resonance fluorescence in quantum dot micropillars using self-aligned metal apertures

    NASA Astrophysics Data System (ADS)

    Hopfmann, Caspar; Musiał, Anna; Maier, Sebastian; Emmerling, Monika; Schneider, Christian; Höfling, Sven; Kamp, Martin; Reitzenstein, Stephan

    2016-09-01

    Within this work we propose and demonstrate a technological approach to efficiently suppress excitation laser stray-light in resonance fluorescence experiments on quantum dot micropillars. To ensure efficient stray-light suppression, their fabrication process includes a planarization step and subsequent covering with a titanium mask to fabricate self-aligned apertures at the micropillar positions. These apertures aim to limit laser stray-light in the side-excitation vertical-detection configuration, while enabling detection of the optical signal through the top facet of the micropillars. The beneficial effects of these apertures are proven and quantitatively evaluated within a statistical study in which we determine and compare the stray-light suppression of 48 micropillars with and without metal apertures. Actual resonance fluorescence experiments on single quantum dots coupled to the cavity mode prove the relevance of the proposed approach and demonstrate that it will foster further studies on cavity quantum electrodynamics phenomena under coherent optical excitation.

  20. Advances in biotreatment of acid mine drainage and biorecovery of metals: 1. Metal precipitation for recovery and recycle.

    PubMed

    Tabak, Henry H; Scharp, Richard; Burckle, John; Kawahara, Fred K; Govind, Rakesh

    2003-12-01

    Acid mine drainage (AMD), an acidic metal-bearing wastewater, poses a severe pollution problem attributed to post mining activities. The metals usually encountered in AMD and considered of concern for risk assessment are arsenic, cadmium, iron, lead, manganese, zinc, copper and sulfate. The pollution generated by abandoned mining activities in the area of Butte, Montana has resulted in the designation of the Silver Bow Creek-Butte Area as the largest Superfund (National Priorities List) site in the U.S. This paper reports the results of bench-scale studies conducted to develop a resource recovery based remediation process for the clean up of the Berkeley Pit. The process utilizes selective, sequential precipitation (SSP) of metals as hydroxides and sulfides, such as copper, zinc, aluminum, iron and manganese, from the Berkeley Pit AMD for their removal from the water in a form suitable for additional processing into marketable precipitates and pigments. The metal biorecovery and recycle process is based on complete separation of the biological sulfate reduction step and the metal precipitation step. Hydrogen sulfide produced in the SRB bioreactor systems is used in the precipitation step to form insoluble metal sulfides. The average metal recoveries using the SSP process were as follows: aluminum (as hydroxide) 99.8%, cadmium (as sulfide) 99.7%, cobalt (as sulfide) 99.1% copper (as sulfide) 99.8%, ferrous iron (sulfide) 97.1%, manganese (as sulfide) 87.4%, nickel (as sulfide) 47.8%, and zinc (as sulfide) 100%. The average precipitate purity for metals, copper sulfide, ferric hydroxide, zinc sulfide, aluminum hydroxide and manganese sulfide were: 92.4, 81.5, 97.8, 95.6, 92.1 and 75.0%, respectively. The final produced water contained only calcium and magnesium and both sulfate and sulfide concentrations were below usable water limits. Water quality of this agriculturally usable water met the EPA's gold standard criterion.

  1. Experiments on the Interaction of Light and Sound for the Advanced Laboratory

    ERIC Educational Resources Information Center

    Pierce, D. T.; Byer, R. L.

    1973-01-01

    An experiment in which both Raman-Nath and Bragg diffraction of light by acoustic waves in water are observed in the sound frequency range from 5 to 45 MHz. The apparatus consists of a laser, light detector, rf power source, quartz transducer, and homemade water cell. (Author/DF)

  2. NEUROSCIENCE. Natural light-gated anion channels: A family of microbial rhodopsins for advanced optogenetics.

    PubMed

    Govorunova, Elena G; Sineshchekov, Oleg A; Janz, Roger; Liu, Xiaoqin; Spudich, John L

    2015-08-07

    Light-gated rhodopsin cation channels from chlorophyte algae have transformed neuroscience research through their use as membrane-depolarizing optogenetic tools for targeted photoactivation of neuron firing. Photosuppression of neuronal action potentials has been limited by the lack of equally efficient tools for membrane hyperpolarization. We describe anion channel rhodopsins (ACRs), a family of light-gated anion channels from cryptophyte algae that provide highly sensitive and efficient membrane hyperpolarization and neuronal silencing through light-gated chloride conduction. ACRs strictly conducted anions, completely excluding protons and larger cations, and hyperpolarized the membrane of cultured animal cells with much faster kinetics at less than one-thousandth of the light intensity required by the most efficient currently available optogenetic proteins. Natural ACRs provide optogenetic inhibition tools with unprecedented light sensitivity and temporal precision.

  3. Identification and characterization of passive safety system and inherent safety feature building blocks for advanced light-water reactors

    SciTech Connect

    Forsberg, C.W.

    1989-01-01

    Oak Ridge National Laboratory (ORNL) is investigating passive and inherent safety options for Advanced Light-Water Reactors (ALWRs). A major activity in 1989 includes identification and characterization of passive safety system and inherent safety feature building blocks, both existing and proposed, for ALWRs. Preliminary results of this work are reported herein. This activity is part of a larger effort by the US Department of Energy, reactor vendors, utilities, and others in the United States to develop improved LWRs. The Advanced Boiling Water Reactor (ABWR) program and the Advanced Pressurized Water Reactor (APWR) program have as goals improved, commercially available LWRs in the early 1990s. The Advanced Simplified Boiling Water Reactor (ASBWR) program and the AP-600 program are developing more advanced reactors with increased use of passive safety systems. It is planned that these reactors will become commercially available in the mid 1990s. The ORNL program is an exploratory research program for LWRs beyond the year 2000. Desired long-term goals for such reactors include: (1) use of only passive and inherent safety, (2) foolproof against operator errors, (3) malevolence resistance against internal sabotage and external assault and (4) walkaway safety. The acronym ''PRIME'' (Passive safety, Resilient operation, Inherent safety, Malevolence resistance, and Extended (walkaway) safety) is used to summarize these desired characteristics. Existing passive and inherent safety options are discussed in this document.

  4. Fabrication of Metal-Deposited Indium Tin Oxides: Its Applications to 385 nm Light-Emitting Diodes.

    PubMed

    Kim, Min Ju; Kim, Tae Geun

    2016-03-02

    We report performance improvements in near-ultraviolet (NUV) light-emitting diodes (LEDs) using various metal-doped indium tin oxide (ITO/metals). Metals with an orbital energy gap greater than that of an In atom (e.g., Ti, Ga, Ge, and Al) are deposited on ITO, and subsequent annealing is performed to improve optical transmittance of ITO due to effective bandgap increase via the linear combination of atomic orbitals, as well as electrical conductivity; thus, current spreading via metal-doping effect at the surface of ITO. As a result, the ITO/metals (annealed at 550 °C, 1 min) exhibit 90.5-94.7% transmittance at 385 nm and a specific contact resistance of 2.1-3.0 × 10(-3) Ω cm(2), whereas the reference ITOs exhibit 76.5-89.5% and 3.2-4.5 × 10(-3) Ω cm(2), respectively. Compared to NUV LEDs using conventional ITO (60 nm), the InGaN/AlGaInN NUV LED using ITO (110 nm)/metal (3 nm) on average exhibits a 70% increase in light output power at 100 mA and a 2% decrease in forward voltage at 20 mA, with more uniform and brighter emission images. We also identified the origin for the improvement by analyzing the surface of ITO/metals using X-ray photoelectron spectroscopy and Auger electron spectroscopy. This approach could offer a simple, effective way to enhance the overall efficiency of conventional NUV LEDs using ITO.

  5. Metal Optics Based nanoLEDs: In Search of a Fast, Efficient, Nanoscale Light Emitter

    NASA Astrophysics Data System (ADS)

    Eggleston, Michael Scott

    Since the invention of the laser, stimulated emission has been the de facto king of optical communication. Lasers can be directly modulated at rates as high as 50GHz, much faster than a typical solid state light-emitting diode (LED) that is limited by spontaneous emission to <1GHz. Unfortunately, lasers have a severe scaling problem; they require large cavities operated at high power to achieve efficient lasing. A properly designed LED can be made arbitrarily small and still operate with high-efficiency. On-chip interconnects is an area that is in desperate need of a high-speed, low-power optical emitter that can enable on-chip links to replace current high-loss metal wires. In this work, I will show that by utilizing proper antenna design, a nanoLED can be created that is faster than a laser while still operating at >50% efficiency. I start by formulating an optical antenna circuit model whose elements are based completely off of antenna geometry. This allows for intuitive antenna design and suggests that rate enhancements up to ~3,000x are possible while keeping antenna efficiency >50%. Such a massive speed-up in spontaneous emission would enable an LED that can be directly modulated at 100's of GHz, much faster than any laser. I then use the circuit model to design an arch-dipole antenna, a dipole antenna with an inductive arch across the feedgap. I experimentally demonstrate a free-standing arch-dipole based nanoLED with rate enhancement of 115x and 66% antenna efficiency. Because the emitter is InGaAsP, a common III-V material, I experimentally show that this device can be easily and efficiently coupled into an InP waveguide. Experimental coupling efficiencies up to 70% are demonstrated and directional antennas are employed that offer front to back emission ratios of 3:1. Finally, I show that a nanoLED can still have high quantum yield by using a transition metal dichalcogenide, WSe2, as the emitter material. By coupling a monolayer of WSe2 to a cavity

  6. The impacts of new street light technologies: experimentally testing the effects on bats of changing from low-pressure sodium to white metal halide.

    PubMed

    Stone, Emma Louise; Wakefield, Andrew; Harris, Stephen; Jones, Gareth

    2015-05-05

    Artificial light at night is a major feature of anthropogenic global change and is increasingly recognized as affecting biodiversity, often negatively. On a global scale, newer technology white lights are replacing orange sodium lights to reduce energy waste. In 2009, Cornwall County Council (UK) commenced replacement of existing low-pressure sodium (LPS) high intensity discharge (HID) street lights with new Phillips CosmoPolis white ceramic metal halide street lights to reduce energy wastage. This changeover provided a unique collaborative opportunity to implement a before-after-control-impact field experiment to investigate the ecological effects of newly installed broad spectrum light technologies. Activity of the bat species Pipistrellus pipistrellus, P. pygmaeus and Nyctalus/Eptesicus spp. was significantly higher at metal halide than LPS lights, as found in other studies of bat activity at old technology (i.e. mercury vapour) white light types. No significant difference was found in feeding attempts per bat pass between light types, though more passes overall were recorded at metal halide lights. Species-specific attraction of bats to the metal halide lights could have cascading effects at lower trophic levels. We highlight the need for further research on possible ecosystem-level effects of light technologies before they are installed on a wide scale.

  7. Research on the exploitation of advanced composite materials to lightly loaded structures

    NASA Technical Reports Server (NTRS)

    Mar, J. W.

    1976-01-01

    The objective was to create a sailplane which could fly in weaker thermals than present day sailplanes (by being lighter) and to fly in stronger thermals than present sailplanes (by carrying more water ballast). The research was to tackle the interaction of advanced composites and the aerodynamic performance, the interaction of fabrication procedures and the advanced composites, and the interaction of advanced composites and the design process. Many pieces of the overall system were investigated but none were carried to the resolution required for engineering application. Nonetheless, interesting and useful results were obtained and are here reported.

  8. Sensitive determination of the spin polarization of optically pumped alkali-metal atoms using near-resonant light

    PubMed Central

    Ding, Zhichao; Long, Xingwu; Yuan, Jie; Fan, Zhenfang; Luo, Hui

    2016-01-01

    A new method to measure the spin polarization of optically pumped alkali-metal atoms is demonstrated. Unlike the conventional method using far-detuned probe light, the near-resonant light with two specific frequencies was chosen. Because the Faraday rotation angle of this approach can be two orders of magnitude greater than that with the conventional method, this approach is more sensitive to the spin polarization. Based on the results of the experimental scheme, the spin polarization measurements are found to be in good agreement with the theoretical predictions, thereby demonstrating the feasibility of this approach. PMID:27595707

  9. Sensitive determination of the spin polarization of optically pumped alkali-metal atoms using near-resonant light.

    PubMed

    Ding, Zhichao; Long, Xingwu; Yuan, Jie; Fan, Zhenfang; Luo, Hui

    2016-09-06

    A new method to measure the spin polarization of optically pumped alkali-metal atoms is demonstrated. Unlike the conventional method using far-detuned probe light, the near-resonant light with two specific frequencies was chosen. Because the Faraday rotation angle of this approach can be two orders of magnitude greater than that with the conventional method, this approach is more sensitive to the spin polarization. Based on the results of the experimental scheme, the spin polarization measurements are found to be in good agreement with the theoretical predictions, thereby demonstrating the feasibility of this approach.

  10. Sensitive determination of the spin polarization of optically pumped alkali-metal atoms using near-resonant light

    NASA Astrophysics Data System (ADS)

    Ding, Zhichao; Long, Xingwu; Yuan, Jie; Fan, Zhenfang; Luo, Hui

    2016-09-01

    A new method to measure the spin polarization of optically pumped alkali-metal atoms is demonstrated. Unlike the conventional method using far-detuned probe light, the near-resonant light with two specific frequencies was chosen. Because the Faraday rotation angle of this approach can be two orders of magnitude greater than that with the conventional method, this approach is more sensitive to the spin polarization. Based on the results of the experimental scheme, the spin polarization measurements are found to be in good agreement with the theoretical predictions, thereby demonstrating the feasibility of this approach.

  11. Vertically integrated metal-clad/silicon dioxide-shell microtube arrays for high-spatial-resolution light stimuli in saline

    NASA Astrophysics Data System (ADS)

    Sakata, M.; Nakamura, T.; Matsuo, T.; Goryu, A.; Ishida, M.; Kawano, T.

    2014-04-01

    Microdevices composed of integrated microscale light source arrays are powerful tools in optogenetic applications. Herein, we prepared vertically aligned 3-μm inner diameter silicon dioxide (SiO2) tube-based optical light waveguide arrays. To increase the locality of the light stimuli through the tube, we also fabricated metal-cladded SiO2 tubes using iridium (Ir). After filling the tube with a saline solution, the saline-core/Ir-clad/SiO2-shell waveguide exhibited light stimuli without spreading. With a 532-nm wavelength, the half-power width of the light intensity measured 10 μm above the tube tip was 3 μm, while that of the saline/SiO2-shell waveguide was 9.6 μm, which was more than three times wider. Such high-spatial-resolution optical light stimuli will offer a new class of optogenetic applications, including light stimuli for specific regions of a neuron (e.g., axons or dendrites).

  12. Potential environmental impacts of light-emitting diodes (LEDs): metallic resources, toxicity, and hazardous waste classification.

    PubMed

    Lim, Seong-Rin; Kang, Daniel; Ogunseitan, Oladele A; Schoenung, Julie M

    2011-01-01

    Light-emitting diodes (LEDs) are advertised as environmentally friendly because they are energy efficient and mercury-free. This study aimed to determine if LEDs engender other forms of environmental and human health impacts, and to characterize variation across different LEDs based on color and intensity. The objectives are as follows: (i) to use standardized leachability tests to examine whether LEDs are to be categorized as hazardous waste under existing United States federal and California state regulations; and (ii) to use material life cycle impact and hazard assessment methods to evaluate resource depletion and toxicity potentials of LEDs based on their metallic constituents. According to federal standards, LEDs are not hazardous except for low-intensity red LEDs, which leached Pb at levels exceeding regulatory limits (186 mg/L; regulatory limit: 5). However, according to California regulations, excessive levels of copper (up to 3892 mg/kg; limit: 2500), Pb (up to 8103 mg/kg; limit: 1000), nickel (up to 4797 mg/kg; limit: 2000), or silver (up to 721 mg/kg; limit: 500) render all except low-intensity yellow LEDs hazardous. The environmental burden associated with resource depletion potentials derives primarily from gold and silver, whereas the burden from toxicity potentials is associated primarily with arsenic, copper, nickel, lead, iron, and silver. Establishing benchmark levels of these substances can help manufacturers implement design for environment through informed materials substitution, can motivate recyclers and waste management teams to recognize resource value and occupational hazards, and can inform policymakers who establish waste management policies for LEDs.

  13. Improving the room-temperature confinement of light by miniaturizing mode sizes into a deep subwavelength scale using dielectric spheres in metal cavities.

    PubMed

    Liu, Ken; Luo, Zhang; Ye, Wei Min; Yuan, Xiao Dong; Zhu, Zhi Hong; Zeng, Chun

    2012-10-01

    The confinement of light within nanometer-scale regions may result in the significant enhancement of light-matter interactions. However, light confinement to nanometers is hindered by the diffraction limit of a dielectric material. For a dielectric cavity, if the material loss is negligible, reducing the cavity size usually causes a significantly increase in radiation loss. Surface plasmons show great promise for potential subwavelength light confinement. However, in most circumstances, light confinement by dissipative metallic materials can cause ohmic losses at optical frequencies. In such cases, the realization of light confinement with deep subwavelength mode sizes results in great losses and thus has low quality factors. In the present study, a three-dimensional light confinement with deep subwavelength mode sizes is achieved using dielectric spheres in metal cavities. Contrary to other mechanisms for subwavelength light confinement that are based on the use of dielectric or metal cavities, the nanometer-scale regions ensure that most of the light energy is confined away from the metal-dielectric interfaces, thereby decreasing light absorption in the metal cavity. In turn, the metal cavity decreases the radiation loss of light. Thus, high quality factors ranging from 2×10(2) to 6×10(2) can be obtained at room temperature. An effective electrical mode volume ranging from 7×10(-5)λ(0)(3) to 2×10(-4)λ(0)(3) (where λ(0) is the resonant wavelength in a vacuum) can be achieved. Therefore, this method of three-dimensional light confinement with deep subwavelength mode sizes using dielectric spheres in metal cavities may have potential applications in the design of nanolasers, nanophoton detectors, nonlinear optical switches, and so on.

  14. Improving on-wafer CD correlation analysis using advanced diagnostics and across-wafer light-source monitoring

    NASA Astrophysics Data System (ADS)

    Alagna, Paolo; Zurita, Omar; Rechtsteiner, Gregory; Lalovic, Ivan; Bekaert, Joost

    2014-04-01

    With the implementation of multi-patterning ArF-immersion for sub 20nm integrated circuits (IC), advances in equipment monitoring and control are needed to support on-wafer yield performance. These in-situ equipment monitoring improvements, along with advanced litho-cell corrections based on on-wafer measurements, enable meeting stringent overlay and CD control requirements for advanced lithography patterning. The importance of light-source performance on lithography pattering (CD and overlay) has been discussed in previous publications.[1-3] Recent developments of Cymer ArF light-source metrology and on-board monitoring enable end-users to detect, for each exposed wafer, changes in the near-field and far-field spatial profiles and polarization performance, [4-6] in addition to the key `optical' scalar parameters, such as bandwidth, wavelength and energy. The major advantage of this capability is that the key performance metrics are sampled at rates matched to wafer performance, e.g. every exposure field across the wafer, which is critical for direct correlation with on-wafer performance for process control and excursion detection.

  15. Comparison of Bond Strength of Metal and Ceramic Brackets Bonded with Conventional and High-Power LED Light Curing Units

    PubMed Central

    Chalipa, Javad; Jalali, Yasamin Farajzadeh; Gorjizadeh, Fatemeh; Baghaeian, Pedram; Hoseini, Mohammad Hashem

    2016-01-01

    Objectives: The aim of this study was to evaluate the effect of conventional and high-power light emitting diode (LED) light curing units on shear bond strength (SBS) of metal and ceramic brackets to tooth surface. Materials and Methods: Forty sound bovine maxillary central incisors were used for the study. The teeth were divided into four groups (n=10). Teeth surfaces were etched with 37% phosphoric acid for 20 seconds. After applying a uniform layer of adhesive primer on the etched enamel, composite was placed on the base of brackets. The samples were light cured according to the manufacturer’s instructions and thermocycled. The SBS was measured. The failure mode was scored using the adhesive remnant index (ARI). Results: The mean SBS of samples in groups A (high-power LED, metal bracket), B (high-power LED, ceramic bracket), C (conventional LED, metal bracket) and D (conventional LED, ceramic bracket) was 23.1±3.69, 10.7±2.06, 24.92±6.37 and 10.74±3.18MPa, respectively. The interaction effect of type of LED unit (high-power/conventional) and bracket type on SBS was not statistically significant (P=0.483). In general, type of LED unit did not affect SBS. Type of bracket significantly affected SBS (P<0.001). The ARI score was not significantly influenced by the interaction between the type of LED unit and bracket. Conclusions: The obtained SBS is the same for both bracket types by use of high-power and conventional LED light curing units. Regardless of the type of LED unit, SBS of ceramic brackets was significantly lower than that of metal brackets. PMID:28243304

  16. Measurement and Verification of Energy Savings and Performance from Advanced Lighting Controls

    SciTech Connect

    PNNL

    2016-02-21

    This document provides a framework for measurement and verification (M&V) of energy savings, performance, and user satisfaction from lighting retrofit projects involving occupancy-sensor-based, daylighting, and/or other types of automatic lighting. It was developed to provide site owners, contractors, and other involved organizations with the essential elements of a robust M&V plan for retrofit projects and to assist in developing specific project M&V plans.

  17. Revisited design optimization of metallic gratings for plasmonic light-trapping enhancement in thin organic solar cells

    NASA Astrophysics Data System (ADS)

    Toan Dang, Phuc; Nguyen, Truong Khang; Le, Khai Q.

    2017-01-01

    We revisit previous studies of metallic gratings for optical absorption enhancement in an organic solar cell with a thin active layer. Our device geometry is designed for a real solar cell with full of functional layers. Various metallic gratings calibrated to generate periodic scatterers and low reflectors for broadband light account for increases in short circuit current density of up to 47% when compared to its flat counterpart. We found that the tapered grating has greater performance than the regular rectangular grating for transverse magnetic (TM) polarization while the latter shows better performance for transverse electric (TE) polarization. The overall metallic grating induced absorption enhancement was found at all angles of incidence. The best configuration was realized for the tapered grating-based solar cell at 25° of inclination.

  18. Enhanced adsorption of acidic gases (CO2, NO2 and SO2) on light metal decorated graphene oxide.

    PubMed

    Chen, Chi; Xu, Kui; Ji, Xiao; Miao, Ling; Jiang, Jianjun

    2014-06-14

    The adsorption of several acidic gases (CO2, NO2 and SO2) on light metal (Li, Al) decorated graphene oxide (GO) is theoretically studied, based on the first-principles calculations. Configuration relaxation, binding energy and charge transfer are carried out to discuss the acidic gas adsorption ability of light metal decorated GO. It is found out that Li, Al could be anchored stably by hydroxyl and epoxy groups on GO, and then a strong adsorption of CO2, NO2 and SO2 will occur above these light metals. In contrast to Ti, Li decorated GO exhibits a comparable adsorption ability of acidic gases, but a much smaller interaction with O2 about 2.85-3.98 eV lower in binding energy; and Al decorated GO displays much higher binding energy of all acidic gases with an enhancement of about 0.59-2.29 eV. The results of enhanced acidic gas adsorption ability and a reduced interference by O2 imply that Li, Al decorated GO may be useful and promising for collection and filtration of exhaust gases.

  19. Development of Advanced LED Phosphors by Spray-based Processes for Solid State Lighting

    SciTech Connect

    Cabot Corporation

    2007-09-30

    The overarching goal of the project was to develop luminescent materials using aerosol processes for making improved LED devices for solid state lighting. In essence this means improving white light emitting phosphor based LEDs by improvement of the phosphor and phosphor layer. The structure of these types of light sources, displayed in Figure 1, comprises of a blue or UV LED under a phosphor layer that converts the blue or UV light to a broad visible (white) light. Traditionally, this is done with a blue emitting diode combined with a blue absorbing, broadly yellow emitting phosphor such as Y{sub 3}Al{sub 5}O{sub 12}:Ce (YAG). A similar result may be achieved by combining a UV emitting diode and at least three different UV absorbing phosphors: red, green, and blue emitting. These emitted colors mix to make white light. The efficiency of these LEDs is based on the combined efficiency of the LED, phosphor, and the interaction between the two. The Cabot SSL project attempted to improve the over all efficiency of the LED light source be improving the efficiency of the phosphor and the interaction between the LED light and the phosphor. Cabot's spray based process for producing phosphor powders is able to improve the brightness of the powder itself by increasing the activator (the species that emits the light) concentration without adverse quenching effects compared to conventional synthesis. This will allow less phosphor powder to be used, and will decrease the cost of the light source; thus lowering the barrier of entry to the lighting market. Cabot's process also allows for chemical flexibility of the phosphor particles, which may result in tunable emission spectra and so light sources with improved color rendering. Another benefit of Cabot's process is the resulting spherical morphology of the particles. Less light scattering results when spherical particles are used in the phosphor layer (Figure 1) compared to when conventional, irregular shaped phosphor particles

  20. Study on the interactional behaviour of transition metal ions with myoglobin: A detailed calorimetric, spectroscopic and light scattering analysis

    NASA Astrophysics Data System (ADS)

    Kaur, Amandeep; Banipal, Parampaul K.; Banipal, Tarlok S.

    2017-03-01

    The energetics and the impact on the conformation of heme containing protein myoglobin (Mb) due to the binding of three transition metal ions (Zn2 +, Ni2 +, and Mn2 +) have been investigated using isothermal titration calorimetry (ITC), dynamic light scattering (DLS), UV-vis, and circular dichroism (CD) spectroscopy under physiological conditions. The binding affinity of the order of 104 M- 1 has been observed for all metal ions from calorimetry as well as from absorption spectroscopy. The binding of these metal ions with Mb is a spontaneous process that exposes the hydrophobic groups away from the protein core as exhibited by the negative Gibbs free energy change (ΔG) and positive heat capacity change (ΔCp) values. Both light scattering and CD results demonstrates that the binding of Zn2 + and Mn2 + ions with Mb results in the folding whereas Ni2 + ion results in the unfolding of the protein. No direct interactions among the transition metal ions and heme moiety of Mb has been observed from absorption study. The results of these studies reveals that Mn2 + ion influences the biological functions of Mb to a larger extent in spite of its lowest affinity followed by Zn2 + and Ni2 + ions.