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Sample records for advanced open-cycle gas

  1. Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 2: Advanced energy conversion systems. Part 1: Open-cycle gas turbines

    NASA Technical Reports Server (NTRS)

    Brown, D. H.; Corman, J. C.

    1976-01-01

    Ten energy conversion systems are defined and analyzed in terms of efficiency. These include: open-cycle gas turbine recuperative; open-cycle gas turbine; closed-cycle gas turbine; supercritical CO2 cycle; advanced steam cycle; liquid metal topping cycle; open-cycle MHD; closed-cycle inert gas MHD; closed-cycle liquid metal MHD; and fuel cells. Results are presented.

  2. Open cycle gas core nuclear rockets

    NASA Technical Reports Server (NTRS)

    Ragsdale, Robert

    1991-01-01

    The open cycle gas core engine is a nuclear propulsion device. Propulsion is provided by hot hydrogen which is heated directly by thermal radiation from the nuclear fuel. Critical mass is sustained in the uranium plasma in the center. It has typically 30 to 50 kg of fuel. It is a thermal reactor in the sense that fissions are caused by absorption of thermal neutrons. The fast neutrons go out to an external moderator/reflector material and, by collision, slow down to thermal energy levels, and then come back in and cause fission. The hydrogen propellant is stored in a tank. The advantage of the concept is very high specific impulse because you can take the plasma to any temperature desired by increasing the fission level by withdrawing or turning control rods or control drums.

  3. An open cycle gas core fusion rocket for space exploration

    NASA Astrophysics Data System (ADS)

    Kammash, T.; Godfrey, T.

    A nuclear propulsion system that utilizes fusion reactions to heat a plasma in a magnetically confined device is examined as a potential rocket. It makes use of a high density plasma in a magnetic mirror geometry with a collision mean free path much shorter than its length. Under these conditions the plasma behaves like a fluid with confinement properties dictated by gasdynamic laws. Accordingly, the plasma escape from the device is analogous to the flow of a gas into vacuum from a vessel with a hole. Such a system is capable of producing a very high specific impulse albeit at modest thrust. One approach for enhancing the thrust is to use an auxiliary hydrogen propellant that could be regeneratively heated before it is introduced into the reactor chamber. As is flows past the fusion plasma it will be further heated by the radiation (bremsstrahlung and synchrotron) emanating from the plasma, and upon emergence from the nozzle it will generate the desired thrust. The system thus functions much like an open cycle gas core rocket with very attractive propulsive capabilities. In this paper we present the underlying physics principles of such a concept and assess its capability by applying the results to a round trip mission to Mars. It is shown that the propulsion parameters exceed those of a gas core fission reactor and without many of major hydrodynamic problems confronted by the latter.

  4. AFB/open cycle gas turbine conceptual design study

    NASA Technical Reports Server (NTRS)

    Dickinson, T. W.; Tashjian, R.

    1983-01-01

    Applications of coal fired atmospheric fluidized bed gas turbine systems in industrial cogeneration are identified. Based on site-specific conceptual designs, the potential benefits of the AFB/gas turbine system were compared with an atmospheric fluidized design steam boiler/steam turbine system. The application of these cogeneration systems at four industrial plant sites is reviewed. A performance and benefit analysis was made along with a study of the representativeness of the sites both in regard to their own industry and compared to industry as a whole. A site was selected for the conceptual design, which included detailed site definition, AFB/gas turbine and AFB/steam turbine cogeneration system designs, detailed cost estimates, and comparative performance and benefit analysis. Market and benefit analyses identified the potential market penetration for the cogeneration technologies and quantified the potential benefits.

  5. Open-Cycle Gas Turbine/Steam Turbine Combined Cycles with synthetic fuels from coal

    NASA Technical Reports Server (NTRS)

    Shah, R. P.; Corman, J. C.

    1977-01-01

    The Open-Cycle Gas Turbine/Steam Turbine Combined Cycle can be an effective energy conversion system for converting coal to electricity. The intermediate step in this energy conversion process is to convert the coal into a fuel acceptable to a gas turbine. This can be accomplished by producing a synthetic gas or liquid, and by removing, in the fuel conversion step, the elements in the fuel that would be harmful to the environment if combusted. In this paper, two open-cycle gas turbine combined systems are evaluated: one employing an integrated low-Btu gasifier, and one utilizing a semi-clean liquid fuel. A consistent technical/economic information base is developed for these two systems, and is compared with a reference steam plant burning coal directly in a conventional furnace.

  6. The open-cycle gas-core nuclear rocket engine - Some engineering considerations.

    NASA Technical Reports Server (NTRS)

    Taylor, M. F.; Whitmarsh, C. L., Jr.; Sirocky, P. J., Jr.; Iwanczyk, L. C.

    1971-01-01

    A preliminary design study of a conceptual 6000-MW open-cycle gas-core nuclear rocket engine system was made. The engine has a thrust of 44,200 lb and a specific impulse of 4400 sec. The nuclear fuel is uranium-235 and the propellant is hydrogen. Critical fuel mass was calculated for several reactor configurations. Major components of the reactor (reflector, pressure vessel) and the waste heat rejection system were considered conceptually and were sized.

  7. Fuel/propellant mixing in an open-cycle gas core nuclear rocket engine

    NASA Astrophysics Data System (ADS)

    Guo, Xu; Wehrmeyer, Joseph A.

    1997-01-01

    A numerical investigation of the mixing of gaseous uranium and hydrogen inside an open-cycle gas core nuclear rocket engine (spherical geometry) is presented. The gaseous uranium fuel is injected near the centerline of the spherical engine cavity at a constant mass flow rate, and the hydrogen propellant is injected around the periphery of the engine at a five degree angle to the wall, at a constant mass flow rate. The main objective is to seek ways to minimize the mixing of uranium and hydrogen by choosing a suitable injector geometry for the mixing of light and heavy gas streams. Three different uranium inlet areas are presented, and also three different turbulent models (k-ɛ model, RNG k-V model, and RSM model) are investigated. The commercial CFD code, FLUENT, is used to model the flow field. Uranium mole fraction, axial mass flux, and radial mass flux contours are obtained.

  8. Reactor moderator, pressure vessel, and heat rejection system of an open-cycle gas core nuclear rocket concept

    NASA Technical Reports Server (NTRS)

    Taylor, M. F.; Whitmarsh, C. L., Jr.; Sirocky, P. J., Jr.; Iwanczyke, L. C.

    1973-01-01

    A preliminary design study of a conceptual 6000-megawatt open-cycle gas-core nuclear rocket engine system was made. The engine has a thrust of 196,600 newtons (44,200 lb) and a specific impulse of 4400 seconds. The nuclear fuel is uranium-235 and the propellant is hydrogen. Critical fuel mass was calculated for several reactor configurations. Major components of the reactor (reflector, pressure vessel, and waste heat rejection system) were considered conceptually and were sized.

  9. Effect of buoyancy on fuel containment in an open-cycle gas-core nuclear rocket engine.

    NASA Technical Reports Server (NTRS)

    Putre, H. A.

    1971-01-01

    Analysis aimed at determining the scaling laws for the buoyancy effect on fuel containment in an open-cycle gas-core nuclear rocket engine, so conducted that experimental conditions can be related to engine conditions. The fuel volume fraction in a short coaxial flow cavity is calculated with a programmed numerical solution of the steady Navier-Stokes equations for isothermal, variable density fluid mixing. A dimensionless parameter B, called the Buoyancy number, was found to correlate the fuel volume fraction for large accelerations and various density ratios. This parameter has the value B = 0 for zero acceleration, and B = 350 for typical engine conditions.

  10. Measurements of gas sorption from seawater and the influence of gas release on open-cycle ocean thermal energy conversion (OC-OTEC) system performance

    SciTech Connect

    Penney, T R; Althof, J A

    1985-06-01

    The technical community has questioned the validity and cost-effectiveness of open-cycle ocean thermal energy conversion (OC-OTEC) systems because of the unknown effect of noncondensable gas on heat exchanger performance and the power needed to run vacuum equipment to remove this gas. To date, studies of seawater gas desorption have not been prototypical for system level analysis. This study gives preliminary gas desorption data on a vertical spout, direct contact evaporator and multiple condenser geometries. Results indicate that dissolved gas can be substantially removed before the seawater enters the heat exchange process, reducing the uncertainty and effect of inert gas on heat exchanger performance.

  11. Summary of the development of open-cycle gas turbine-steam cycles

    SciTech Connect

    Lackey, M.E.; Thompson, A.S.

    1980-09-01

    Combined-cycle plants employing gas turbine cycles superimposed on conventional steam plants are well developed. Nearly 200 units are operating in the US on clean fuels (natural gas or distillate fuel oils) and giving overall thermal efficiencies as high as 42%. Future plants will have to use coal or coal-derived fuels, and this presents problems because gas turbines are very sensitive to particulates and contaminants in the fuel such as sulfur, potassium, lead, etc. If clean liquid or high-Btu gaseous fuels are made from coal, it appears that the conversion efficiency will be no more than 67%. Thus, the overall efficiency of utilization of coal would be less than if it were burned in a conventional steam plant unless the permissible gas turbine inlet temperature can be increased to approx. 1500/sup 0/C (2732/sup 0/F). Coupling a combined-cycle power plant directly to a low-Btu coal gasifier increases the fuel conversion efficiency and permits salvaging waste heat from the gasifier for feedwater heating in the steam cycle. By using a gas turbine inlet temperature of 1315/sup 0/C (2400/sup 0/F), well above the current maximum of approx. 1040/sup 0/C (1904/sup 0/F), an overall efficiency of approx. 40% has been estimated for the integrated plant. However, as discussed in companion reports, it is doubtful that operation with gas turbine inlet temperatures above 1100/sup 0/C (2012/sup 0/F) will prove practicable in base-load plants.

  12. Open cycle thermoacoustics

    SciTech Connect

    Reid, Robert Stowers

    2000-01-01

    A new type of thermodynamic device combining a thermodynamic cycle with the externally applied steady flow of an open thermodynamic process is discussed and experimentally demonstrated. The gas flowing through this device can be heated or cooled in a series of semi-open cyclic steps. The combination of open and cyclic flows makes possible the elimination of some or all of the heat exchangers (with their associated irreversibility). Heat is directly exchanged with the process fluid as it flows through the device when operating as a refrigerator, producing a staging effect that tends to increase First Law thermodynamic efficiency. An open-flow thermoacoustic refrigerator was built to demonstrate this concept. Several approaches are presented that describe the physical characteristics of this device. Tests have been conducted on this refrigerator with good agreement with a proposed theory.

  13. Economic aspects of advanced coal-fired gas turbine locomotives

    NASA Technical Reports Server (NTRS)

    Liddle, S. G.; Bonzo, B. B.; Houser, B. C.

    1983-01-01

    Increases in the price of such conventional fuels as Diesel No. 2, as well as advancements in turbine technology, have prompted the present economic assessment of coal-fired gas turbine locomotive engines. A regenerative open cycle internal combustion gas turbine engine may be used, given the development of ceramic hot section components. Otherwise, an external combustion gas turbine engine appears attractive, since although its thermal efficiency is lower than that of a Diesel engine, its fuel is far less expensive. Attention is given to such a powerplant which will use a fluidized bed coal combustor. A life cycle cost analysis yields figures that are approximately half those typical of present locomotive engines.

  14. Advanced Gas Turbine (AGT)

    NASA Technical Reports Server (NTRS)

    1983-01-01

    The development and progress of the Advanced Gas Turbine engine program is examined. An analysis of the role of ceramics in the design and major engine components is included. Projected fuel economy, emissions and performance standards, and versatility in fuel use are also discussed.

  15. Open cycle lithium chloride cooling system

    NASA Astrophysics Data System (ADS)

    Lenz, T. G.; Loef, G. O. G.; Iyer, R.; Wenger, J.

    1983-05-01

    A lithium chloride open cycle absorption chiller has been designed, built and tested. Solution reconcentration takes place in a small counter current packed column supplied with solar heated air. Removal of noncondensable gases that enter the chiller dissolved in the strong solution and the make-up refrigerant streams is accomplished by a liquid-jet ejector and a small vacuum pump. Cooling capacities approaching 1.4 tons and COP levels of 0.58 have been achieved at non-optimum operating conditions. Test results from preliminary system operation suggest that mass transfer processes in both the packed column reconcentrator and the absorber are controlled by concentration gradients in the lithium chloride solution. Liquid phase controlled mass transfer dictates an operating strategy different from the previously assumed gas phase controlled process to obtain maximum rates of evaporation in the packed column. Determination of optimal operating conditions leading to decreased electrical power consumption and improved cooling capacity and coefficient of performance will require further analysis and testing.

  16. Open Cycle OTEC System with Fresh Water Product

    NASA Astrophysics Data System (ADS)

    Amano, Masatugu; Tanaka, Tadayosi

    An open-cycle ocean thermal energy conversion (OC-OTEC) system is one of energy conversion methods to generate electricity from ocean thermal energy. For OC-OTEC system, steam evaporated from the surface seawater due to flash evaporation drives the turbine. At that time, dissolved gas such as air is introduced into the low-pressure system (OC-OTEC system) as the non-condensable gas, which degrades the performance of condensation heat transfer. In this paper, a small scale OC-OTEC experimental unit experimentally investigates the effect of non-condensable gas on the heat transfer performance in a condenser. The experimental results are discussed in comparison with theoretical estimation by Sparrow-Lin method. It is shown that the condensation is occupied by heat and mass transfer near a condensation surface and that the condensation efficiency is affected by exhaust quantity of non-condensable gas at relative high concentration ratio of condensable gas.

  17. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect

    Unknown

    2000-01-01

    The activities of the Advanced Gas Turbine Systems Research (AGRSR) program are described in the quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education) and Research. Items worthy of note are presented in extended bullet format following the appropriate heading.

  18. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect

    Unknown

    2002-02-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for this reporting period are described in this quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education), Research and Miscellaneous Related Activity. Items worthy of note are presented in extended bullet format following the appropriate heading.

  19. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect

    Unknown

    2002-04-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for this reporting period are described in this quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education), Research and Miscellaneous Related Activity. Items worthy of note are presented in extended bullet format following the appropriate heading.

  20. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect

    E.S. Connolly; G.D. Forsythe

    1998-12-22

    Advanced, coal-based power plants will require durable and reliable hot gas filtration systems to remove particulate contaminants from the gas streams to protect downstream components such as turbine blades from erosion damage. It is expected that the filter elements in these systems will have to be made of ceramic materials to withstand goal service temperatures of 1600 F or higher. Recent demonstration projects and pilot plant tests have indicated that the current generation of ceramic hot gas filters (cross-flow and candle configurations) are failing prematurely. Two of the most promising materials that have been extensively evaluated are clay-bonded silicon carbide and alumina-mullite porous monoliths. These candidates, however, have been found to suffer progressive thermal shock fatigue damage, as a result of rapid cooling/heating cycles. Such temperature changes occur when the hot filters are back-pulsed with cooler gas to clean them, or in process upset conditions, where even larger gas temperature changes may occur quickly and unpredictably. In addition, the clay-bonded silicon carbide materials are susceptible to chemical attack of the glassy binder phase that holds the SiC particles together, resulting in softening, strength loss, creep, and eventual failure.

  1. Advanced gas turbine systems program

    SciTech Connect

    Zeh, C.M.

    1995-06-01

    The U.S. Department of Energy (DOE) is sponsoring a program to develop fuel-efficient gas turbine-based power systems with low emissions. DOE`s Office of Fossil Energy (DOE/FE) and Office of Energy Efficiency and Renewable Energy (DOE/EE) have initiated an 8-year program to develop high-efficiency, natural gas-fired advanced gas turbine power systems. The Advanced Turbine Systems (ATS) Program will support full-scale prototype demonstration of both industrial- and utility-scale systems that will provide commercial marketplace entries by the year 2000. When the program targets are met, power system emissions will be lower than from the best technology in use today. Efficiency of the utility-scale units will be greater than 60 percent on a lower heating value basis, and emissions of carbon dioxide will be reduced inversely with this increase. Industrial systems will also see an improvement of at least 15 percent in efficiency. Nitrogen oxides will be reduced by at least 10 percent, and carbon monoxide and hydrocarbon emissions will each be kept below 20 parts per million, for both utility and industrial systems.

  2. Operational analysis of open-cycle MHD

    NASA Astrophysics Data System (ADS)

    Lippert, T. E.; McCutchan, D. A.

    1980-07-01

    Open cycle magnetohydrodynamic (OCMHD) conceptual power plant designs are studied in the context of a utility system to form a better basis for understanding their design, design requirements, and market possibilities. Based on assumed or projected plant costs and performance characteristics, assumed economics and escalation factors, and one coal supply and delivery scenario, overall and regional OCMHD utility market possibilities are reviewed. Additionally, for one hypothetical utility system a generation expansion plan is developed that includes OCMHD as a baseload power generating station. The impact on generation system economics and operation of alternating selected MHD plant cost and performance characteristics is reviewed. Baseload plant availability is shown as an important plant design consideration, and a general methodology and data base is developed to assess the impact on design and cost of various reliability decisions. An overall plant availability goal is set and the required availabilities of various MHD high technology components are derived to meet the plant goal. The approach is then extended to projecting channel life goals for various plant design configurations and assumptions.

  3. Open cycle ocean thermal energy conversion system

    DOEpatents

    Wittig, J. Michael

    1980-01-01

    An improved open cycle ocean thermal energy conversion system including a flash evaporator for vaporizing relatively warm ocean surface water and an axial flow, elastic fluid turbine having a vertical shaft and axis of rotation. The warm ocean water is transmitted to the evaporator through a first prestressed concrete skirt-conduit structure circumferentially situated about the axis of rotation. The unflashed warm ocean water exits the evaporator through a second prestressed concrete skirt-conduit structure located circumferentially about and radially within the first skirt-conduit structure. The radially inner surface of the second skirt conduit structure constitutes a cylinder which functions as the turbine's outer casing and obviates the need for a conventional outer housing. The turbine includes a radially enlarged disc element attached to the shaft for supporting at least one axial row of radially directed blades through which the steam is expanded. A prestressed concrete inner casing structure of the turbine has upstream and downstream portions respectively situated upstream and downstream from the disc element. The radially outer surfaces of the inner casing portions and radially outer periphery of the axially interposed disc cooperatively form a downwardly radially inwardly tapered surface. An annular steam flowpath of increasing flow area in the downward axial direction is radially bounded by the inner and outer prestressed concrete casing structures. The inner casing portions each include a transversely situated prestressed concrete circular wall for rotatably supporting the turbine shaft and associated structure. The turbine blades are substantially radially coextensive with the steam flowpath and receive steam from the evaporator through an annular array of prestressed concrete stationary vanes which extend between the inner and outer casings to provide structural support therefor and impart a desired flow direction to the steam.

  4. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect

    E.S. Connolly; G.D. Forsythe

    2000-09-30

    DuPont Lanxide Composites, Inc. undertook a sixty-month program, under DOE Contract DEAC21-94MC31214, in order to develop hot gas candle filters from a patented material technology know as PRD-66. The goal of this program was to extend the development of this material as a filter element and fully assess the capability of this technology to meet the needs of Pressurized Fluidized Bed Combustion (PFBC) and Integrated Gasification Combined Cycle (IGCC) power generation systems at commercial scale. The principal objective of Task 3 was to build on the initial PRD-66 filter development, optimize its structure, and evaluate basic material properties relevant to the hot gas filter application. Initially, this consisted of an evaluation of an advanced filament-wound core structure that had been designed to produce an effective bulk filter underneath the barrier filter formed by the outer membrane. The basic material properties to be evaluated (as established by the DOE/METC materials working group) would include mechanical, thermal, and fracture toughness parameters for both new and used material, for the purpose of building a material database consistent with what is being done for the alternative candle filter systems. Task 3 was later expanded to include analysis of PRD-66 candle filters, which had been exposed to actual PFBC conditions, development of an improved membrane, and installation of equipment necessary for the processing of a modified composition. Task 4 would address essential technical issues involving the scale-up of PRD-66 candle filter manufacturing from prototype production to commercial scale manufacturing. The focus would be on capacity (as it affects the ability to deliver commercial order quantities), process specification (as it affects yields, quality, and costs), and manufacturing systems (e.g. QA/QC, materials handling, parts flow, and cost data acquisition). Any filters fabricated during this task would be used for product qualification tests

  5. Advancing agricultural greenhouse gas quantification*

    NASA Astrophysics Data System (ADS)

    Olander, Lydia; Wollenberg, Eva; Tubiello, Francesco; Herold, Martin

    2013-03-01

    given to methods appropriate to low-income countries, where strategies are needed for getting robust data with extremely limited resources in order to support national mitigation planning within widely accepted standards and thus provide access to essential international support, including climate funding. Managing agricultural emissions needs to occur in tandem with managing for agricultural productivity, resilience to climate change, and ecosystem impacts. Management decisions and priorities will require measures and information that identify GHG efficiencies in production and reduce inputs without reducing yields, while addressing climate resilience and maintaining other essential environmental services, such as water quality and support for pollinators. Another set of papers in this issue considers the critical synergies and tradeoffs possible between these multiple objectives of mitigation, resilience, and production efficiency to help us understand how we need to tackle these in our quantification systems. Significant capacity to quantify greenhouse gases is already built, and with some near-term strategic investment, could become an increasingly robust and useful tool for planning and development in the agricultural sector around the world. Acknowledgments The Climate Change Agriculture and Food Security Program of the Consultative Group on International Agricultural Research, the Technical Working Group on Agricultural Greenhouse Gases (T-AGG) at Duke University's Nicholas Institute for Environmental Policy Solutions, and the United Nations Food and Agriculture Organization (FAO) have come together to guide the development of this focus issue and associated activities and papers, given their common desire to improve our understanding of the state of agricultural greenhouse gas (GHG) quantification and to advance ideas for building data and methods that will help mitigation policy and programs move forward around the world. We thank the David and Lucile Packard

  6. Characterization of open-cycle coal-fired MHD generators

    NASA Astrophysics Data System (ADS)

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Bien, F.; Dvore, D.; Unkel, W.; Stewart, G.

    1980-09-01

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort is detailed. In addition, studies related to understanding arcing phenomena in the vicinity of an anode are reported.

  7. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect

    Matthew R. June; John L. Hurley; Mark W. Johnson

    1999-04-01

    Iron aluminide hot gas filters have been developed using powder metallurgy techniques to form seamless cylinders. Three alloys were short-term corrosion tested in simulated IGCC atmospheres with temperatures between 925 F and 1200 F with hydrogen sulfide concentrations ranging from 783 ppm{sub v} to 78,300 ppm{sub v}. Long-term testing was conducted for 1500 hours at 925 F with 78,300 ppm{sub v}. The FAS and FAL alloys were found to be corrosion resistant in the simulated environments. The FAS alloy has been commercialized.

  8. Advanced IGCC/Hydrogen Gas Turbine Development

    SciTech Connect

    York, William; Hughes, Michael; Berry, Jonathan; Russell, Tamara; Lau, Y. C.; Liu, Shan; Arnett, Michael; Peck, Arthur; Tralshawala, Nilesh; Weber, Joseph; Benjamin, Marc; Iduate, Michelle; Kittleson, Jacob; Garcia-Crespo, Andres; Delvaux, John; Casanova, Fernando; Lacy, Ben; Brzek, Brian; Wolfe, Chris; Palafox, Pepe; Ding, Ben; Badding, Bruce; McDuffie, Dwayne; Zemsky, Christine

    2015-07-30

    The objective of this program was to develop the technologies required for a fuel flexible (coal derived hydrogen or syngas) gas turbine for IGCC that met DOE turbine performance goals. The overall DOE Advanced Power System goal was to conduct the research and development (R&D) necessary to produce coal-based IGCC power systems with high efficiency, near-zero emissions, and competitive capital cost. To meet this goal, the DOE Fossil Energy Turbine Program had as an interim objective of 2 to 3 percentage points improvement in combined cycle (CC) efficiency. The final goal is 3 to 5 percentage points improvement in CC efficiency above the state of the art for CC turbines in IGCC applications at the time the program started. The efficiency goals were for NOx emissions of less than 2 ppm NOx (@15 % O2). As a result of the technologies developed under this program, the DOE goals were exceeded with a projected 8 point efficiency improvement. In addition, a new combustion technology was conceived of and developed to overcome the challenges of burning hydrogen and achieving the DOE’s NOx goal. This report also covers the developments under the ARRA-funded portion of the program that include gas turbine technology advancements for improvement in the efficiency, emissions, and cost performance of gas turbines for industrial applications with carbon capture and sequestration. Example applications could be cement plants, chemical plants, refineries, steel and aluminum plants, manufacturing facilities, etc. The DOE’s goal for more than 5 percentage point improvement in efficiency was met with cycle analyses performed for representative IGCC Steel Mill and IGCC Refinery applications. Technologies were developed in this program under the following areas: combustion, larger latter stage buckets, CMC and EBC, advanced materials and coatings, advanced configurations to reduce cooling, sealing and rotor purge flows, turbine aerodynamics, advanced sensors, advancements in first

  9. Combustion modeling in advanced gas turbine systems

    SciTech Connect

    Smoot, L.D.; Hedman, P.O.; Fletcher, T.H.

    1995-10-01

    The goal of the U.S. Department of Energy`s Advanced Turbine Systems (ATS) program is to help develop and commercialize ultra-high efficiency, environmentally superior, and cost competitive gas turbine systems for base-load applications in the utility, independent power producer, and industrial markets. Combustion modeling, including emission characteristics, has been identified as a needed, high-priority technology by key professionals in the gas turbine industry.

  10. Open-cycle centrifugal vapor-compression heat pump. Annual report, March 1983-February 1984

    SciTech Connect

    Iles, T.L.; Burgmeier, L.R.; Stanko, J.E.

    1984-04-01

    The objectives of this program are: (1) to develop an open-cycle high-lift centrifugal steam compressor system that can be efficiently retrofitted to existing multi-effect and high-temperature differential evaporators while maintaining the cost benefits of a single-stage centrifugal compressor and (2) to demonstrate the energy saving and cost benefits of driving the compressor with a natural-gas-fueled gas turbine engine. The turbine exhaust will be used for final drying of the product that was evaporated. This report describes the design and fabrication of the system and the test activities through February 1984.

  11. Open-cycle centrifugal vapor-compression heat pump. Annual report, March 1984-February 1985

    SciTech Connect

    Iles, T.L.; Burgmeier, L.R.; Liu, A.Y.

    1985-04-01

    The objectives of the program are to (1) develop an open-cycle high-lift centrifugal steam compressor system that can be efficiently retrofitted to existing multi-effect and high-temperature differential evaporators while maintaining the cost benefits of a single-stage centrifugal compressor and (2) demonstrate the energy saving and cost benefits of driving the compressor with a natural-gas-fueled gas turbine engine. The turbine exhaust will be used for final drying of the product that was evaporated. This report describes the design and fabrication of the system and the test activities through February 1985.

  12. Open-cycle centrifugal vapor-compression heat pump. Final report, January 1986-May 1987

    SciTech Connect

    Burgmeier, L.R.; Horner, J.E.

    1987-11-30

    The objectives of the program were (1) to develop an open-cycle, high-lift, centrifugal steam-compressor system that can be efficiently retrofitted to existing multi-effect and high-temperature differential evaporators while maintaining the cost benefits of a single-stage centrifugal compressor, and (2) to demonstrate the energy saving and cost benefits of driving the compressor with a natural-gas-fueled gas-turbine engine. The turbine exhaust was to be used for final drying of the product that was evaporated. The report describes the installation of the system and the test activities through May 1987.

  13. Center for Advanced Gas Turbine Systems Research

    SciTech Connect

    Golan, L.P.

    1992-12-31

    An unregulated conventional power station based on the Rankine Cycle typically bums pulverized coal in a boiler that exports steam for expansion through a steam turbine which ultimately drives an electric generator. The flue gases are normally cleaned of particulates by an electrostatic precipitator or bag house. A basic cycle such as this will have an efficiency of approximately 35% with 10% of the energy released through the stack and 55% to cooling water. Advanced gas turbine based combustion systems have the potential to be environmentally and commercially superior to existing conventional technology. however, to date, industry, academic, and government groups have not coordinated their effort to commercialize these technologies. The Center for Advanced Gas Turbine Systems Research will provide the medium to support effective commercialization of this technology. Several cycles or concepts for advanced gas turbine systems that could be fired on natural gas or could be adapted into coal based systems have been proposed (for examples, see Figures 4, 5, 6, and 7) (2) all with vary degrees of complexity, research needs, and system potential. Natural gas fired power systems are now available with 52% efficiency ratings; however, with a focused base technology program, it is expected that the efficiency levels can be increased to the 60% level and beyond. This increase in efficiency will significantly reduce the environmental burden and reduce the cost of power generation.

  14. Center for Advanced Gas Turbine Systems Research

    SciTech Connect

    Golan, L.P.

    1992-01-01

    An unregulated conventional power station based on the Rankine Cycle typically bums pulverized coal in a boiler that exports steam for expansion through a steam turbine which ultimately drives an electric generator. The flue gases are normally cleaned of particulates by an electrostatic precipitator or bag house. A basic cycle such as this will have an efficiency of approximately 35% with 10% of the energy released through the stack and 55% to cooling water. Advanced gas turbine based combustion systems have the potential to be environmentally and commercially superior to existing conventional technology. however, to date, industry, academic, and government groups have not coordinated their effort to commercialize these technologies. The Center for Advanced Gas Turbine Systems Research will provide the medium to support effective commercialization of this technology. Several cycles or concepts for advanced gas turbine systems that could be fired on natural gas or could be adapted into coal based systems have been proposed (for examples, see Figures 4, 5, 6, and 7) (2) all with vary degrees of complexity, research needs, and system potential. Natural gas fired power systems are now available with 52% efficiency ratings; however, with a focused base technology program, it is expected that the efficiency levels can be increased to the 60% level and beyond. This increase in efficiency will significantly reduce the environmental burden and reduce the cost of power generation.

  15. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect

    RICHARD A. WAGNER

    1998-09-04

    This report describes the fabrication and testing of continuous fiber ceramic composite (CFCC) based hot gas filters. The fabrication approach utilized a modified filament winding method that combined both continuous and chopped fibers into a novel microstructure. The work was divided into five primary tasks. In the first task, a preliminary set of compositions was fabricated in the form of open end tubes and characterized. The results of this task were used to identify the most promising compositions for sub-scale filter element fabrication and testing. In addition to laboratory measurements of permeability and strength, exposure testing in a coal combustion environment was performed to asses the thermo-chemical stability of the CFCC materials. Four candidate compositions were fabricated into sub-scale filter elements with integral flange and a closed end. Following the 250 hour exposure test in a circulating fluid bed combustor, the retained strength ranged from 70 t 145 percent of the as-fabricated strength. The post-test samples exhibited non-catastrophic failure behavior in contrast to the brittle failure exhibited by monolithic materials. Filter fabrication development continued in a filter improvement and cost reduction task that resulted in an improved fiber architecture, the production of a net shape flange, and an improved low cost bond. These modifications were incorporated into the process and used to fabricate 50 full-sized filter elements for testing in demonstration facilities in Karhula, Finland and at the Power Systems Development Facility (PSDF) in Wilsonville, AL. After 581 hours of testing in the Karhula facility, the elements retained approximately 87 percent of their as-fabricated strength. In addition, mechanical response testing at Virginia Tech provided a further demonstration of the high level of strain tolerance of the vacuum wound filter elements. Additional testing in the M. W. Kellogg unit at the PSDF has accumulated over 1800 hours of

  16. 165-kW open-cycle OTEC experiment

    NASA Astrophysics Data System (ADS)

    Shelpuk, B.

    1985-06-01

    The Solar Energy Research Institute (SERI) is developing a research experiment to establish the feasibility of producing significant amounts of net power from an open-cycle ocean thermal energy conversion (OC-OTEC) system. This experiment is sized at 165 kW sub e gross and is adequate to evaluate turbine performance and system process interactions at a scale that can be extrapolated to projected commercial market entry system sizes of 5 to 15 MW sub e.

  17. ADVANCED GAS TURBINE SYSTEMS RESEARCH PROGRAM

    SciTech Connect

    Lawrence P. Golan

    2001-01-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for this reporting period are described in this quarterly report. As this program administers research, we have included all program activity herein within the past quarter dated. More specific research progress reports are provided weekly at the request of the AGTSR COR and are being sent to NETL. As for the administration of this program, items worthy of note are presented in extended bullet format following the appropriate heading.

  18. ADVANCED GAS TURBINE SYSTEMS RESEARCH PROGRAM

    SciTech Connect

    Lawrence P. Golan

    2000-05-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program are described in the quarterly report. As this program administers research, we have included all program activity herein within the past quarter dated. More specific research progress reports are provided weekly at the request of the AGTSR COR and are being sent to NETL. As for the administration of this program, items worthy of note are presented in extended bullet format following the appropriate heading.

  19. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Wenglarz, R.A.

    1994-08-01

    Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

  20. Advanced Coal-Fueled Gas Turbine Program

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  1. Open-cycle Ocean Thermal Energy Conversion (OTEC): Status and potential

    NASA Astrophysics Data System (ADS)

    Bharathan, D.

    1984-08-01

    Tropical oceans with a 20 C or more temperature difference between surface and deep water represent a vast resource of renewable thermal energy. One of the methods of harnessing this resource is an open-cycle Ocean Thermal Energy Conversion (OTEC) system utilizing steam evaporated from the surface water for powering the turbine. In this paper, the state of the art of research and component development, as related to heat and mass transfer processes, power production, noncondensable gas handling, and seawater flow hydraulics, are described through an illustrated preliminary design study of a 1-MW facility.

  2. AGT (Advanced Gas Turbine) technology project

    NASA Technical Reports Server (NTRS)

    1988-01-01

    An overall summary documentation is provided for the Advanced Gas Turbine Technology Project conducted by the Allison Gas Turbine Division of General Motors. This advanced, high risk work was initiated in October 1979 under charter from the U.S. Congress to promote an engine for transportation that would provide an alternate to reciprocating spark ignition (SI) engines for the U.S. automotive industry and simultaneously establish the feasibility of advanced ceramic materials for hot section components to be used in an automotive gas turbine. As this program evolved, dictates of available funding, Government charter, and technical developments caused program emphases to focus on the development and demonstration of the ceramic turbine hot section and away from the development of engine and powertrain technologies and subsequent vehicular demonstrations. Program technical performance concluded in June 1987. The AGT 100 program successfully achieved project objectives with significant technology advances. Specific AGT 100 program achievements are: (1) Ceramic component feasibility for use in gas turbine engines has been demonstrated; (2) A new, 100 hp engine was designed, fabricated, and tested for 572 hour at operating temperatures to 2200 F, uncooled; (3) Statistical design methodology has been applied and correlated to experimental data acquired from over 5500 hour of rig and engine testing; (4) Ceramic component processing capability has progressed from a rudimentary level able to fabricate simple parts to a sophisticated level able to provide complex geometries such as rotors and scrolls; (5) Required improvements for monolithic and composite ceramic gas turbine components to meet automotive reliability, performance, and cost goals have been identified; (6) The combustor design demonstrated lower emissions than 1986 Federal Standards on methanol, JP-5, and diesel fuel. Thus, the potential for meeting emission standards and multifuel capability has been initiated

  3. Advanced Gas Turbine (AGT) powertrain system

    NASA Technical Reports Server (NTRS)

    Helms, H. E.; Kaufeld, J.; Kordes, R.

    1981-01-01

    A 74.5 kW(100 hp) advanced automotive gas turbine engine is described. A design iteration to improve the weight and production cost associated with the original concept is discussed. Major rig tests included 15 hours of compressor testing to 80% design speed and the results are presented. Approximately 150 hours of cold flow testing showed duct loss to be less than the design goal. Combustor test results are presented for initial checkout tests. Turbine design and rig fabrication is discussed. From a materials study of six methods to fabricate rotors, two have been selected for further effort. A discussion of all six methods is given.

  4. ADVANCED GAS TURBINE SYSTEMS RESEARCH PROGRAM

    SciTech Connect

    Lawrence P. Golan

    2003-05-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for the reporting period October 1, 2002 to December 31, 2002 are described in this quarterly report. No new membership, workshops, research projects, internships, faculty fellowships or special studies were initiated during this reporting period. Contract completion is set for June 30, 2003. During the report period, six research progress reports were received (3 final reports and 3 semi-annual reports). The University of Central Florida contract SR080 was terminated during this period, as UCF was unable to secure research facilities. AGTSR now projects that it will under spend DOE obligated funds by approximately 340-350K$.

  5. Advanced Hot-Gas Desulfurization Sorbents

    SciTech Connect

    Jothimurugesan, K.; Adeyiga, A.; Gangwal, S.K.

    1996-12-31

    The objective of this project is to develop advanced hot-gas desulfurization sorbents for relatively low temperature application that show stable and high sulfidation reactivity at 343 to 538 {degrees}C. A number of zinc-based formulations will be prepared and screened for testing in a fixed-bed reactor at high pressure (1 to 20 atm) and high temperatures using simulated coal-derived fuel gases. One of the superior formulations will be tested for long- term durability and chemical reactivity in the reactor. To prevent sulfation, catalyst additives will be investigated, which would promote a lower regeneration temperature.

  6. Study of hydraulic air compression for Ocean Thermal Energy Conversion open-cycle application

    NASA Astrophysics Data System (ADS)

    Golshani, A.; Chen, F. C.

    1983-01-01

    A hydraulic air compressor, which requires no mechanical moving parts and operates in a nearly isothermal mode, can be an alternative for the noncondensible gas disposal of an Ocean Thermal Energy Conversion (OTEC) open-cycle power system. The compressor requires only a downward flow of water to accomplish air compression. An air compressor test loop was assembled and operated to obtain test data that would lead to the design of an OTEC hydraulic air compressor. A one dimensional, hydraulic gas compressor, computer model was employed to simulate the laboratory experiments, and it was tuned to fit the test results. A sensitivity study that shows the effects of various parameters on the applied head of the hydraulic air compression is presented.

  7. Advanced Natural Gas Reciprocating Engine(s)

    SciTech Connect

    Pike, Edward

    2014-03-31

    The objective of the Cummins ARES program, in partnership with the US Department of Energy (DOE), is to develop advanced natural gas engine technologies that increase engine system efficiency at lower emissions levels while attaining lower cost of ownership. The goals of the project are to demonstrate engine system achieving 50% Brake Thermal Efficiency (BTE) in three phases, 44%, 47% and 50% (starting baseline efficiency at 36% BTE) and 0.1 g/bhp-hr NOx system out emissions (starting baseline NOx emissions at 2 – 4 g/bhp-hr NOx). Primary path towards above goals include high Brake Mean Effective Pressure (BMEP), improved closed cycle efficiency, increased air handling efficiency and optimized engine subsystems. Cummins has successfully demonstrated each of the phases of this program. All targets have been achieved through application of a combined set of advanced base engine technologies and Waste Heat Recovery from Charge Air and Exhaust streams, optimized and validated on the demonstration engine and other large engines. The following architectures were selected for each Phase: Phase 1: Lean Burn Spark Ignited (SI) Key Technologies: High Efficiency Turbocharging, Higher Efficiency Combustion System. In production on the 60/91L engines. Over 500MW of ARES Phase 1 technology has been sold. Phase 2: Lean Burn Technology with Exhaust Waste Heat Recovery (WHR) System Key Technologies: Advanced Ignition System, Combustion Improvement, Integrated Waste Heat Recovery System. Base engine technologies intended for production within 2 to 3 years Phase 3: Lean Burn Technology with Exhaust and Charge Air Waste Heat Recovery System Key Technologies: Lower Friction, New Cylinder Head Designs, Improved Integrated Waste Heat Recovery System. Intended for production within 5 to 6 years Cummins is committed to the launch of next generation of large advanced NG engines based on ARES technology to be commercialized worldwide.

  8. Bubble nucleation and growth in open-cycle OTEC subsystems

    NASA Astrophysics Data System (ADS)

    Bugby, D. C.; Wassel, A. T.; Mills, A. F.

    1983-05-01

    Bubble nucleation and growth in the evaporator, condenser, upcomers, and feedwater distribution systems of open-cycle ocean thermal energy conversion (OTEC) power plants are examined. The phenomenon that will probably have the most impact on system design is cavitation in the warm water feed near the entrance of the evaporator. The critical bubble size for cavitation is about 105 microns. Sources of bubbles in the warm water feed are those entering from the ocean, those nucleating on suspended particles, and those nucleating on the upcomer wall. Analyses of bubble growth induced by changes in hydrostatic pressure, mass transfer, and coalescence are presented. Using available information for bubble size distribution in seawater at California locations, it is shown that cavitation will probably have a significant impact on evaporator performance unless a debubbler is provided upstream of the evaporator entrance.

  9. Open cycle OTEC system with falling jet evaporator and condenser

    SciTech Connect

    Kogan, A.; Johnson, D. H.; Green, H. J.; Olson, D. A.

    1980-07-01

    A configuration for the open cycle (OC) Ocean Thermal Energy Conversion (OTEC) system is presented incorporating a countercurrent falling jet evaporator and a concurrent falling jet condenser. The parameters governing performance of the proposed configuration are discussed and the sizing of equipment for a 100-MWe net power output OC OTEC plant is performed, based on recent experimental falling jet heat and mass transfer results. The performance of an OC OTEC plant with falling jet evaporator-condenser is compared with the Westinghouse conceptual design that uses an open-channel evaporator and a surface condenser. Preliminary calculations indicate that falling jet heat and mass transfer, when applied in the proposed configuration, leads to a very simple and compact plant assembly resulting in substantial capital cost savings.

  10. ADVANCED GAS TURBINE SYSTEMS RESEARCH PROGRAM

    SciTech Connect

    Lawrence P. Golan

    2003-05-01

    The quarterly activities of the Advanced Gas Turbine Systems Research (AGTSR) program are described in this quarterly report. As this program administers research, we have included all program activity herein within the past quarter as dated. More specific research progress reports are provided weekly at the request of the AGTSR COR and are being sent to NETL As for the administration of this program, items worthy of note are presented in extended bullet format following the appropriate heading. No new memberships, workshops, research projects, internships, faculty fellowships or special studies were initiated during this reporting period. Contract completion is set for June 30, 2003. During the report period, nine subcontractor reports were received (5 final reports and 4 semi-annual reports). The report technology distribution is as follows: 3--aero-heat transfer, 2--combustion and 4--materials. AGTSR continues to project that it will under spend DOE obligated funds by approximately $329K.

  11. ADVANCED DEHYDRATOR DESIGN SAVES GAS AND REDUCES HAP EMISSIONS

    EPA Science Inventory

    Glycol dehydrators remove water from gas pipe lines. An advanced dehydrator by Engineered Concepts, Farmington, NM, saves a significant amount of gas, while reducing hazardous air pollutants, volatile organic compounds and CO2 air pollutants

  12. Advanced Gas Turbine (AGT) technology development project

    NASA Technical Reports Server (NTRS)

    1987-01-01

    This report is the final in a series of Technical Summary Reports for the Advanced Gas Turbine (AGT) Technology Development Project, authorizrd under NASA Contract DEN3-167 and sponsored by the DOE. The project was administered by NASA-Lewis Research Center of Cleveland, Ohio. Plans and progress are summarized for the period October 1979 through June 1987. This program aims to provide the US automotive industry the high risk, long range technology necessary to produce gas turbine engines for automobiles that will reduce fuel consumption and reduce environmental impact. The intent is that this technology will reach the marketplace by the 1990s. The Garrett/Ford automotive AGT was designated AGT101. The AGT101 is a 74.5 kW (100 shp) engine, capable of speeds to 100,000 rpm, and operates at turbine inlet temperatures to 1370 C (2500 F) with a specific fuel consumption level of 0.18 kg/kW-hr (0.3 lbs/hp-hr) over most of the operating range. This final report summarizes the powertrain design, power section development and component/ceramic technology development.

  13. Advanced Gas Turbine (AGT) Technology Development Project

    NASA Technical Reports Server (NTRS)

    1987-01-01

    This report is the eleventh in the series of Technical Summary reports for the Advanced Gas Turbine (AGT) Technology Development Project, authorized under NASA Contract DEN3-167, and sponsored by the Department of Energy (DOE). This report was prepared by Garrett Turbine Engine Company, A Division of the Garrett Corporation, and includes information provided by Ford Motor Company, the Standard Oil Company, and AiResearch Casting Company. This report covers plans and progress for the period July 1, 1985 through June 30, 1986. Technical progress during the reported period was highlighted by the 85-hour endurance run of an all-ceramic engine operating in the 2000 to 2250 F temperature regime. Component development continued in the areas of the combustion/fuel injection system, regenerator and seals system, and ceramic turbine rotor attachment design. Component rig testing saw further refinements. Ceramic materials showed continued improvements in required properties for gas turbine applications; however, continued development is needed before performance and reliability goals can be set.

  14. Advanced bristle seals for gas turbine engines

    NASA Astrophysics Data System (ADS)

    Cabe, Jerry L.

    1993-01-01

    A seven month proof-of-concept program was conducted for an advanced bristle seal, called a bush seal, for use in gas turbine engines. This program was performed as a Small Business Innovation Research (SBIR) Phase 1 project. Bush seal specimen and a full ring bush seal were designed, evaluated, and manufactured for testing. An analytical study of the potential of the bush seal relative to a labyrinth seal was conducted. Static and dynamic testing of the bush seal was performed to determine the behavior of the bristles under pressurization and during contact with a rotating labyrinth tooth. Stable behavior of the bristle elements was observed during static pressurization of a full ring bush seal. The dynamic testing of various configurations of bush seal against a rotating labyrinth tooth showed minimal wear of the bristles relative to a conventional labyrinth seal. The development and application of the bush seal concept to gas turbine engines has the potential of improving the engine's performance while decreasing the degradation of the seal performance over time.

  15. Seawater test results of Open-Cycle Ocean Thermal Energy Conversion (OC-OTEC) components

    NASA Astrophysics Data System (ADS)

    Zangrando, F.; Bharathan, D.; Link, H.; Panchal, C. B.

    Key components of open-cycle ocean thermal energy conversion systems- the flash evaporator, mist eliminator, passive predeaerator, two surface condenser stages, and two direct-contact condenser stages- have been tested using seawater. These components operate at lower steam pressures and higher inlet noncondensable gas concentrations than do conventional power plant heat exchangers. The rate of heat exchanged between the evaporator and the condenser is on the order of 1.25MW-thermal, requiring a warm seawater flow of about 0.1 cu m/s; the cold seawater flow is on the order of half the warm water flow. In addition to characterizing the performance of the various components, the system has produced potable water from condensation of the steam produced in the evaporator. The information obtained in these tests is being used to design a larger scale experiment in which net power production is expected to be demonstrate for the first time using OC-OTEC technology.

  16. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1992-09-01

    Westinghouse's Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO[sub x] emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO[sub x] levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  17. ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

    SciTech Connect

    Charles M. Boyer II; Ronald J. MacDonald P.G.

    2002-01-01

    As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden & Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We have continued to enhance and streamline our software, and we are testing the final stages of our new Microsoft{trademark} Access/Excel based software. We are continuing to process the information and are identifying potential candidate wells that can be used in Phase 2 to validate the new methodologies. In addition, preparation of the final technical report is underway. During this quarter, we have presented our project and discussed the software to numerous Petroleum Technology Transfer Council (PTTC) workshops located in various regions of the United States.

  18. Advanced Natural Gas Reciprocating Engine(s)

    SciTech Connect

    Kwok, Doris; Boucher, Cheryl

    2009-09-30

    Energy independence and fuel savings are hallmarks of the nation’s energy strategy. The advancement of natural gas reciprocating engine power generation technology is critical to the nation’s future. A new engine platform that meets the efficiency, emissions, fuel flexibility, cost and reliability/maintainability targets will enable American manufacturers to have highly competitive products that provide substantial environmental and economic benefits in the US and in international markets. Along with Cummins and Waukesha, Caterpillar participated in a multiyear cooperative agreement with the Department of Energy to create a 50% efficiency natural gas powered reciprocating engine system with a 95% reduction in NOx emissions by the year 2013. This platform developed under this agreement will be a significant contributor to the US energy strategy and will enable gas engine technology to remain a highly competitive choice, meeting customer cost of electricity targets, and regulatory environmental standard. Engine development under the Advanced Reciprocating Engine System (ARES) program was divided into phases, with the ultimate goal being approached in a series of incremental steps. This incremental approach would promote the commercialization of ARES technologies as soon as they emerged from development and would provide a technical and commercial foundation of later-developing technologies. Demonstrations of the Phase I and Phase II technology were completed in 2004 and 2008, respectively. Program tasks in Phase III included component and system development and testing from 2009-2012. Two advanced ignition technology evaluations were investigated under the ARES program: laser ignition and distributed ignition (DIGN). In collaboration with Colorado State University (CSU), a laser ignition system was developed to provide ignition at lean burn and high boost conditions. Much work has been performed in Caterpillar’s DIGN program under the ARES program. This work

  19. Open cycle ocean thermal energy conversion system structure

    DOEpatents

    Wittig, J. Michael

    1980-01-01

    A generally mushroom-shaped, open cycle OTEC system and distilled water producer which has a skirt-conduit structure extending from the enlarged portion of the mushroom to the ocean. The enlarged part of the mushroom houses a toroidal casing flash evaporator which produces steam which expands through a vertical rotor turbine, partially situated in the center of the blossom portion and partially situated in the mushroom's stem portion. Upon expansion through the turbine, the motive steam enters a shell and tube condenser annularly disposed about the rotor axis and axially situated beneath the turbine in the stem portion. Relatively warm ocean water is circulated up through the radially outer skirt-conduit structure entering the evaporator through a radially outer portion thereof, flashing a portion thereof into motive steam, and draining the unflashed portion from the evaporator through a radially inner skirt-conduit structure. Relatively cold cooling water enters the annular condenser through the radially inner edge and travels radially outwardly into a channel situated along the radially outer edge of the condenser. The channel is also included in the radially inner skirt-conduit structure. The cooling water is segregated from the potable, motive steam condensate which can be used for human consumption or other processes requiring high purity water. The expansion energy of the motive steam is partially converted into rotational mechanical energy of the turbine rotor when the steam is expanded through the shaft attached blades. Such mechanical energy drives a generator also included in the enlarged mushroom portion for producing electrical energy. Such power generation equipment arrangement provides a compact power system from which additional benefits may be obtained by fabricating the enclosing equipment, housings and component casings from low density materials, such as prestressed concrete, to permit those casings and housings to also function as a floating

  20. Advanced Liquid Natural Gas Onboard Storage System

    SciTech Connect

    Greg Harper; Charles Powars

    2003-10-31

    Cummins Westport Incorporated (CWI) has designed and developed a liquefied natural gas (LNG) vehicle fuel system that includes a reciprocating pump with the cold end submerged in LNG contained in a vacuum-jacketed tank. This system was tested and analyzed under the U.S. Department of Energy (DOE) Advanced LNG Onboard Storage System (ALOSS) program. The pumped LNG fuel system developed by CWI and tested under the ALOSS program is a high-pressure system designed for application on Class 8 trucks powered by CWI's ISX G engine, which employs high-pressure direct injection (HPDI) technology. A general ALOSS program objective was to demonstrate the feasibility and advantages of a pumped LNG fuel system relative to on-vehicle fuel systems that require the LNG to be ''conditioned'' to saturation pressures that exceeds the engine fuel pressure requirements. These advantages include the capability to store more fuel mass in given-size vehicle and station tanks, and simpler lower-cost LNG refueling stations that do not require conditioning equipment. Pumped LNG vehicle fuel systems are an alternative to conditioned LNG systems for spark-ignition natural gas and port-injection dual-fuel engines (which typically require about 100 psi), and they are required for HPDI engines (which require over 3,000 psi). The ALOSS program demonstrated the feasibility of a pumped LNG vehicle fuel system and the advantages of this design relative to systems that require conditioning the LNG to a saturation pressure exceeding the engine fuel pressure requirement. LNG tanks mounted on test carts and the CWI engineering truck were repeatedly filled with LNG saturated at 20 to 30 psig. More fuel mass was stored in the vehicle tanks as well as the station tank, and no conditioning equipment was required at the fueling station. The ALOSS program also demonstrated the general viability and specific performance of the CWI pumped LNG fuel system design. The system tested as part of this program is

  1. Advanced Gas Turbine (AGT) Technology Project

    NASA Technical Reports Server (NTRS)

    1984-01-01

    Technical work on the design and effort leading to the testing of a 74.5 kW (100 hp) automotive gas turbine engine is reviewed. Development of the engine compressor, gasifier turbine, power turbine, combustor, regenerator, and secondary system is discussed. Ceramic materials development and the application of such materials in the gas turbine engine components is described.

  2. Advances in gas-liquid flows 1990

    SciTech Connect

    Kim, J.M. . Nuclear Reactor Lab.); Rohatgi, U.S. ); Hashemi, A. )

    1990-01-01

    Gas-liquid two-phase flows commonly occur in nature and industrial applications. Rain, clouds, geysers, and waterfalls are examples of natural gas-liquid flow phenomena, whereas industrial applications can be found in nuclear reactors, steam generators, boilers, condensers, evaporators, fuel atomization, heat pipes, electronic equipment cooling, petroleum engineering, chemical process engineering, and many others. The household-variety phenomena such as garden sprinklers, shower, whirlpool bath, dripping faucet, boiling tea pot, and bubbling beer provide daily experience of gas-liquid flows. The papers presented in this volume reflect the variety and richness of gas-liquid two-phase flow and the increasing role it plays in modern technology. This volume contains papers dealing with some recent development in gas-liquid flow science and technology, covering basic gas-liquid flows, measurements and instrumentation, cavitation and flashing flows, countercurrent flow and flooding, flow in various components and geometries liquid metals and thermocapillary effects, heat transfer, nonlinear phenomena, instability, and other special and general topics related to gas-liquid flows.

  3. Theoretical analysis of condensation in the presence of noncondensable gases as applied to open cycle OTEC condensers

    NASA Astrophysics Data System (ADS)

    Panchal, C. B.; Bell, K. J.

    The open cycle ocean thermal energy conversion condenser was analyzed from a theoretical standpoint. Interfacial temperature profiles and gas concentrations in the axial direction were determined, and their effects on the rate of condensation studied. For the analysis, the vapor phase was modeled using diffusion equations for simultaneous heat and mass transfer processes, while the liquid phase was modeled using a falling film analysis. This analysis was then applied to a plate fin condenser, and the effect of varying the fin density along the condenser lengths was investigated. General engineering aspects of heat exchanger design are discussed for condensation of vapor mixtures in the presence of noncondensable gases.

  4. Open-cycle vapor compression heat pump. Annual progress report for 1980

    SciTech Connect

    Sakhuja, R.; Becker, F.E.

    1981-05-05

    Approximately 10 percent of U.S. energy is used by industry in the form of process steam at 100 psi or less. In many industrial plants, a portion of this steam is simply vented to the atmosphere or condensed after use in the process because it cannot be fully utilized or economically recovered. Also, a great amount of low-grade heat energy is wasted because it cannot be economically recovered. Recovery and upgrading of these low-grade steam or waste heat sources offers a great potential of energy conservation. Thermo Electron is developing an open cycle vapor compression steam heat pump to meet this objective. The system utilizes excess low-pressure steam or that produced from an industrial excess heat source with a waste heat boiler and compresses this steam to the desired pressure level for process use. The compressor is driven by a prime mover such as a gas turbine, gas engine, etc. The prime mover exhaust heat also can be recovered to generate additional process steam. The fuel consumption of this system can be as low as 30 to 50 percent in comparison to a direct-fired boiler over the expected range of process conditions. Simple payback periods as low as one year can be achieved.

  5. Advancing Greenhouse Gas Reductions through Affordable Housing

    EPA Pesticide Factsheets

    James City County, Virginia, is an EPA Climate Showcase Community. EPA’s Climate Showcase Communities Program helps local governments and tribal nations pilot innovative, cost-effective and replicable community-based greenhouse gas reduction projects.

  6. Development of materials for open-cycle magnetohydrodynamics (MHD): ceramic electrode. Final report

    SciTech Connect

    Bates, J.L.; Marchant, D.D.

    1986-09-01

    Pacific Northwest Laboratory, supported by the US Department of Energy, developed advanced materials for use in open-cycle, closed cycle magnetohydrodynamics (MHD) power generation, an advanced energy conversion system in which the flow of electrically conducting fluid interacts with an electric field to convert the energy directly into electricity. The purpose of the PNL work was to develop electrodes for the MHD channel. Such electrodes must have: (1) electrical conductivity above 0.01 (ohm-cm)/sup -1/ from near room temperature to 1900/sup 0/K, (2) resistance to both electrochemical and chemical corrosion by both slag and potassium seed, (3) resistance to erosion by high-velocity gases and particles, (4) resistance to thermal shock, (5) adequate thermal conductivity, (6) compatibility with other channel components, particularly the electrical insulators, (7) oxidation-reduction stability, and (8) adequate thermionic emission. This report describes the concept and development of high-temperature, graded ceramic composite electrode materials and their electrical and structural properties. 47 refs., 16 figs., 13 tabs.

  7. Composite turbine blade design options for Claude (open) cycle OTEC power systems

    SciTech Connect

    Penney, T R

    1985-11-01

    Small-scale turbine rotors made from composites offer several technical advantages for a Claude (open) cycle ocean thermal energy conversion (OTEC) power system. Westinghouse Electric Corporation has designed a composite turbine rotor/disk using state-of-the-art analysis methods for large-scale (100-MW/sub e/) open cycle OTEC applications. Near-term demonstrations using conventional low-pressure turbine blade shapes with composite material would achieve feasibility and modern credibility of the open cycle OTEC power system. Application of composite blades for low-pressure turbo-machinery potentially improves the reliability of conventional metal blades affected by stress corrosion.

  8. The AGT 101 advanced automotive gas turbine

    NASA Technical Reports Server (NTRS)

    Rackley, R. A.; Kidwell, J. R.

    1982-01-01

    A development program is described whose goal is the accumulation of the technology base needed by the U.S. automotive industry for the production of automotive gas turbine powertrains. Such gas turbine designs must exhibit reduced fuel consumption, a multi-fuel capability, and low exhaust emissions. The AGT101 powertrain described is a 74.6 kW, regenerated single-shaft gas turbine, operating at a maximum inlet temperature of 1644 K and coupled to a split differential gearbox and automatic overdrive transmission. The engine's single stage centrifugal compressor and single stage radial inflow turbine are mounted on a common shaft, and will operate at a maximum rotor speed of 100,000 rpm. All high temperature components, including the turbine rotor, are ceramic.

  9. Advanced Gas Storage Concepts: Technologies for the Future

    SciTech Connect

    Freeway, Katy; Rogers, R.E.; DeVries, Kerry L.; Nieland, Joel D.; Ratigan, Joe L.; Mellegard, Kirby D.

    2000-02-01

    This full text product includes: 1) A final technical report titled Advanced Underground Gas Storage Concepts, Refrigerated-Mined Cavern Storage and presentations from two technology transfer workshops held in 1998 in Houston, Texas, and Pittsburgh, Pennsylvania (both on the topic of Chilled Gas Storage in Mined Caverns); 2) A final technical report titled Natural Gas Hydrates Storage Project, Final Report 1 October 1997 - 31 May 1999; 3) A final technical report titled Natural Gas Hydrates Storage Project Phase II: Conceptual Design and Economic Study, Final Report 9 June - 10 October 1999; 4) A final technical report titled Commerical Potential of Natural Gas Storage in Lined Rock Caverns (LRC) and presentations from a DOE-sponsored workshop on Alternative Gas Storage Technologies, held Feb 17, 2000 in Pittsburgh, PA; and 5) Phase I and Phase II topical reports titled Feasibility Study for Lowering the Minimum Gas Pressure in Solution-Mined Caverns Based on Geomechanical Analyses of Creep-Induced Damage and Healing.

  10. Advanced Technologies For Stripper Gas Well Enhancement

    SciTech Connect

    Ronald J. MacDonald; Charles M. Boyer; Joseph H. Frantz Jr; Paul A. Zyglowicz

    2005-04-01

    Stripper gas and oil well operators frequently face a dilemma regarding maximizing production from low-productivity wells. With thousands of stripper wells in the United States covering extensive acreage, it is difficult to identify easily and efficiently marginal or underperforming wells. In addition, the magnitude of reviewing vast amounts of data places a strain on an operator's work force and financial resources. Schlumberger DCS, in cooperation with the National Energy Technology Laboratory (NETL) and the U.S. Department of Energy (DOE), has created software and developed in-house analysis methods to identify remediation potential in stripper wells relatively easily. This software is referred to as Stripper Well Analysis Remediation Methodology (SWARM). SWARM was beta-tested with data pertaining to two gas fields located in northwestern Pennsylvania and had notable results. Great Lakes Energy Partners, LLC (Great Lakes) and Belden & Blake Corporation (B&B) both operate wells in the first field studied. They provided data for 729 wells, and we estimated that 41 wells were candidates for remediation. However, for reasons unbeknownst to Schlumberger these wells were not budgeted for rework by the operators. The second field (Cooperstown) is located in Crawford, Venango, and Warren counties, Pa and has more than 2,200 wells operated by Great Lakes. This paper discusses in depth the successful results of a candidate recognition study of this area. We compared each well's historical production with that of its offsets and identified 339 underperformers before considering remediation costs, and 168 economically viable candidates based on restimulation costs of $50,000 per well. From this data, we prioritized a list based on the expected incremental recoverable gas and 10% discounted net present value (NPV). For this study, we calculated the incremental gas by subtracting the volumes forecasted after remediation from the production projected at its current

  11. GE power generation technology challenges for advanced gas turbines

    SciTech Connect

    Cook, C.S.; Nourse, J.G.

    1993-11-01

    The GE Utility ATS is a large gas turbine, derived from proven GEPG designs and integrated GEAE technology, that utilizes a new turbine cooling system and incorporates advanced materials. This system has the potential to achieve ATS objectives for a utility sized machine. Combined with use of advanced Thermal Barrier Coatings (TBC`s), the new cooling system will allow higher firing temperatures and improved cycle efficiency that represents a significant improvement over currently available machines. Developing advances in gas turbine efficiency and emissions is an ongoing process at GEPG. The third generation, ``F`` class, of utility gas turbines offers net combined cycle efficiencies in the 55% range, with NO{sub x} programs in place to reduce emissions to less than 10 ppM. The gas turbines have firing temperatures of 2350{degree}F, and pressure ratios of 15 to 1. The turbine components are cooled by air extracted from the cycle at various stages of the compressor. The heat recovery cycle is a three pressure steam system, with reheat. Throttle conditions are nominally 1400 psi and 1000{degree}F reheat. As part of GEPG`s ongoing advanced power generation system development program, it is expected that a gas fired advanced turbine system providing 300 MW power output greater than 58% net efficiency and < 10 ppM NO{sub x} will be defined. The new turbine cooling system developed with technology support from the ATS program will achieve system net efficiency levels in excess of 60%.

  12. Open-cycle ocean thermal energy conversion surface-condenser design analysis and computer program

    SciTech Connect

    Panchal, C.B.; Rabas, T.J.

    1991-05-01

    This report documents a computer program for designing a surface condenser that condenses low-pressure steam in an ocean thermal energy conversion (OTEC) power plant. The primary emphasis is on the open-cycle (OC) OTEC power system, although the same condenser design can be used for conventional and hybrid cycles because of their highly similar operating conditions. In an OC-OTEC system, the pressure level is very low (deep vacuums), temperature differences are small, and the inlet noncondensable gas concentrations are high. Because current condenser designs, such as the shell-and-tube, are not adequate for such conditions, a plate-fin configuration is selected. This design can be implemented in aluminum, which makes it very cost-effective when compared with other state-of-the-art vacuum steam condenser designs. Support for selecting a plate-fin heat exchanger for OC-OTEC steam condensation can be found in the sizing (geometric details) and rating (heat transfer and pressure drop) calculations presented. These calculations are then used in a computer program to obtain all the necessary thermal performance details for developing design specifications for a plate-fin steam condenser. 20 refs., 5 figs., 5 tabs.

  13. Seawater test results of open-cycle ocean thermal energy conversion (OC-OTEC) components

    SciTech Connect

    Zangrando, F.; Bharathan, D.; Link, H. ); Panchal, C.B. )

    1994-01-01

    Key components of open-cycle ocean thermal energy conversion systems--the flash evaporator, mist eliminator, passive predeaerator, two surface condenser stages, and two direct-contact condenser stages--have been tested using seawater. These components operate at lower steam pressures and higher inlet noncondensable gas concentrations than do conventional power plant heat exchangers. The rate of heat exchanged between the evaporator and the condenser is on the order of 1.25MW-thermal, requiring a warm seawater flow of about 0.1 m[sup 3]/s; the cold seawater flow is on the order of half the warm water flow. In addition to characterizing the performance of the various components, the system has produced potable water from condensation of the steam produced in the evaporator. The information obtained in these tests is being used to design a larger scale experiment in which net power production is expected to be demonstrate for the first time using OC-OTEC technology.

  14. Open-cycle ocean thermal energy conversion surface-condenser design analysis and computer program

    NASA Astrophysics Data System (ADS)

    Panchal, C. B.; Rabas, T. J.

    1991-05-01

    This report documents a computer program for designing a surface condenser that condenses low-pressure steam in an ocean thermal energy conversion (OTEC) power plant. The primary emphasis is on the open-cycle (OC) OTEC power system, although the same condenser design can be used for conventional and hybrid cycles because of their highly similar operating conditions. In an OC-OTEC system, the pressure level is very low (deep vacuums), temperature differences are small, and the inlet noncondensable gas concentrations are high. Because current condenser designs, such as the shell-and-tube, are not adequate for such conditions, a plate-fin configuration is selected. This design can be implemented in aluminum, which makes it very cost-effective when compared with other state-of-the-art vacuum steam condenser designs. Support for selecting a plate-fin heat exchanger for OC-OTEC steam condensation can be found in the sizing (geometric details) and rating (heat transfer and pressure drop) calculations presented. These calculations are then used in a computer program to obtain all the necessary thermal performance details for developing design specifications for a plate-fin steam condenser.

  15. Open-cycle vapor-compression heat pump. Annual report, April 1983-April 1984

    SciTech Connect

    Becker, F.E.; Ruggles, A.E.

    1984-05-01

    Large quantities of low-grade energy in the form of low-pressure steam and low-temperature heat are wasted by industry. The practical and economical recovery of energy from these sources is often limited by the number of applications for the use of low-temperature heat. Thermo Electron has developed an open-cycle steam-heat-pump system capable of the direct recovery and upgrading of low-grade waste steam. The system compresses low-pressure waste steam (or steam made from sources of low-temperature waste heat) to produce high-pressure steam suitable for use in industrial processes. A prototype system has been developed that is capable of recovering and recompressing up to 10,000 lb/hr of waste steam, while using only 50 percent of the fuel that would be required to produce comparable steam in a boiler. The prototype steam recompression system, using a 2200-cfm rotary screw compressor driven by a 500-hp natural-gas engine, was tested at Thermo Electron and then installed at the Monsanto Company in western Massachusetts for a yearlong field test.

  16. Open-cycle vapor compression heat pump. Final report, January 1979-January 1985

    SciTech Connect

    Becker, F.E.; Ruggles, A.E.

    1985-03-01

    Large quantities of low-grade energy in the form of low-pressure steam and low-temperature heat are often discharged to the environment by industry. The practical and economical recovery of energy from these sources is often limited by the number of applications that can directly use low-temperature heat. Thermo Electron has developed an open-cycle steam heat-pump system capable of the direct recovery and upgrading of low-grade waste energy. The system compresses low-pressure waste steam (or steam made from sources of low-temperature waste heat) to produce high-pressure steam suitable for use in industrial processes. A prototype system has been developed that is capable of recovering and recompressing up to 10,000 lb/hr of waste steam, while using only 50% of the fuel that would be required to produce comparable steam in a boiler. The prototype steam-recompression system, using a 2200-cfm rotary-screw compressor, driven by a 500-hp natural-gas engine, was tested at Thermo Electron and then installed at the Monsanto Company in western Massachusetts for a year-long field test.

  17. Mist eliminators for freshwater production from open-cycle OTEC systems

    SciTech Connect

    Bharathan, D.; Penney, T.

    1983-12-01

    For freshwater production from open-cycle OTEC systems, the suitability of commercially available mist eliminators is examined. The mist eliminators are characterized in terms of their liquid collection efficiencies, allowable vapor velocities at the onset of reentrainment, and pressure losses. Suitable design modifications can be projected to allow steam velocities of up to 35 m/s, with a corresponding parasitic power loss of less than 5% of the gross potential of an open-cycle OTEC power system.

  18. Advanced Natural Gas Reciprocating Engines(s)

    SciTech Connect

    Zurlo, James

    2012-04-05

    The ARES program was initiated in 2001 to improve the overall brake thermal efficiency of stationary, natural gas, reciprocating engines. The ARES program is a joint award that is shared by Dresser, Inc., Caterpillar and Cummins. The ARES program was divided into three phases; ARES I (achieve 44% BTE), ARES II (achieve 47% BTE) and ARES III (achieve 50% BTE). Dresser, Inc. completed ARES I in March 2005 which resulted in the commercialization of the APG1000 product line. ARES II activities were completed in September 2010 and the technology developed is currently being integrated into products. ARES III activities began in October 2010. The ARES program goal is to improve the efficiency of natural gas reciprocating engines. The ARES project is structured in three phases with higher efficiency goals in each phase. The ARES objectives are as follows: 1. Achieve 44% (ARES I), 47% (ARES II), and 50% brake thermal efficiency (BTE) as a final ARES III objective 2. Achieve 0.1 g/bhp-hr NOx emissions (with after-treatment) 3. Reduce the cost of the produced electricity by 10% 4. Improve or maintain reliability, durability and maintenance costs

  19. Collaborative Advanced Gas Turbine Program: Phase 1. Final report

    SciTech Connect

    Hollenbacher, R.; Kesser, K.; Beishon, D.

    1994-12-01

    The Collaborative Advanced Gas Turbine (CAGT) Program is an advanced gas turbine research and development program whose goal is to accelerate the commercial availability, to within the turn of the century, of high efficiency aeroderivative gas turbines for electric power generating applications. In the first project phase, research was conducted to prove or disprove the research hypothesis that advanced aeroderivative gas turbine systems can provide a promising technology alternative, offering high efficiency and good environmental performance characteristics in modular sizes, for utility applications. This $5 million, Phase 1 research effort reflects the collaborative efforts of a broad and international coalition of industries and organizations, both public and private, that have pooled their resources to assist in this research. Included in this coalition are: electric and gas utilities, the Electric Power Research Institute, the Gas Research Institute and the principal aircraft engine manufacturers. Additionally, the US Department of Energy (DOE) and the California Energy Commission have interacted with the CAGT on both technical and executive levels as observers and sources of funding. The three aircraft engine manufacturer-led research teams participating in this research include: Rolls-Royce, Inc., and Bechtel; the Turbo Power and Marine Division of United Technologies and Fluor Daniel; and General Electric Power Generation, Stewart and Stevenson, and Bechtel. Each team has investigated advanced electric power generating systems based on their high-thrust (60,000 to 100,000 pounds) aircraft engines. The ultimate goal of the CAGT program is that the community of stakeholders in the growing market for natural-gas-fueled, electric power generation can collectively provide the right combination of market-pull and technology-push to substantially accelerate the commercialization of advanced, high efficiency aeroderivative technologies.

  20. Advancement of Miniature Optic Gas Sensor (MOGS) Probe Technology

    NASA Technical Reports Server (NTRS)

    Chullen, Cinda

    2015-01-01

    Advancement of Miniature Optic Gas Sensor (MOGS) Probe Technology" project will investigate newly developed optic gas sensors delivered from a Small Business Innovative Research (SBIR) Phase II effort. A ventilation test rig will be designed and fabricated to test the sensors while integrated with a Suited Manikin Test Apparatus (SMTA). Once the sensors are integrated, a series of test points will be completed to verify that the sensors can withstand Advanced Suit Portable Life Support System (PLSS) environments and associated human metabolic profiles for changes in pressure and levels of Oxygen (ppO2), carbon dioxide (ppCO2), and humidity (ppH2O).

  1. Advanced liner-cooling techniques for gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Norgren, C. T.; Riddlebaugh, S. M.

    1985-01-01

    Component research for advanced small gas turbine engines is currently underway at the NASA Lewis Research Center. As part of this program, a basic reverse-flow combustor geometry was being maintained while different advanced liner wall cooling techniques were investigated. Performance and liner cooling effectiveness of the experimental combustor configuration featuring counter-flow film-cooled panels is presented and compared with two previously reported combustors featuring: splash film-cooled liner walls; and transpiration cooled liner walls (Lamilloy).

  2. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1991-09-01

    The combustion system discussed here incorporates a modular three- stage slagging combustor concept. Fuel-rich conditions inhibit NO{sub x} formation from fuel nitrogen in the first stage; also in the first stage, sulfur is captured with sorbent; coal ash and sulfated sorbent are removed from the combustion gases by inertial means in the second stage by the use of an impact separator and slagging cyclone separator in series. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The objective of this contract is to establish the technology required for subsequent commercial development and application by the private sector of utility-size direct coal-fueled gas turbines. Emissions from these units are to meet or be lower than the Environment Protection Agency's (EPA's) New Source Performance Standards (NSPS) for a pulverized coal-=fired steam turbine generator plant.

  3. Advanced Gas Turbine (AGT) technology development

    NASA Technical Reports Server (NTRS)

    1983-01-01

    A 74.5 kW (100 hp) automotive gas turbine was evaluated. The engine structure, bearings, oil system, and electronics were demonstrated and no shaft dynamics or other vibration problem were encountered. Areas identified during the five tests are the scroll retention features, and transient thermal deflection of turbine backplates. Modifications were designed. Seroll retention is addressed by modifying the seal arrangement in front of the gasifier turbine assembly, which will increase the pressure load on the scroll in the forward direction and thereby increase the retention forces. the backplate thermal deflection is addressed by geometric changes and thermal insulation to reduce heat input. Combustor rig proof testing of two ceramic combustor assemblies was completed. The combustor was modified to incorporate slots and reduce sharp edges, which should reduce thermal stresses. The development work focused on techniques to sinter these barrier materials onto the ceramic rotors with successes for both material systems. Silicon carbide structural parts, including engine configuration gasifier rotors (ECRs), preliminary gasifier scroll parts, and gasifier and power turbine vanes are fabricated.

  4. Advanced Water-Gas Shift Membrane Reactor

    SciTech Connect

    Sean Emerson; Thomas Vanderspurt; Susanne Opalka; Rakesh Radhakrishnan; Rhonda Willigan

    2009-01-07

    The overall objectives for this project were: (1) to identify a suitable PdCu tri-metallic alloy membrane with high stability and commercially relevant hydrogen permeation in the presence of trace amounts of carbon monoxide and sulfur; and (2) to identify and synthesize a water gas shift catalyst with a high operating life that is sulfur and chlorine tolerant at low concentrations of these impurities. This work successfully achieved the first project objective to identify a suitable PdCu tri-metallic alloy membrane composition, Pd{sub 0.47}Cu{sub 0.52}G5{sub 0.01}, that was selected based on atomistic and thermodynamic modeling alone. The second objective was partially successful in that catalysts were identified and evaluated that can withstand sulfur in high concentrations and at high pressures, but a long operating life was not achieved at the end of the project. From the limited durability testing it appears that the best catalyst, Pt-Re/Ce{sub 0.333}Zr{sub 0.333}E4{sub 0.333}O{sub 2}, is unable to maintain a long operating life at space velocities of 200,000 h{sup -1}. The reasons for the low durability do not appear to be related to the high concentrations of H{sub 2}S, but rather due to the high operating pressure and the influence the pressure has on the WGS reaction at this space velocity.

  5. Proceedings of the Department of Energy advanced gas turbine central power systems workshop

    SciTech Connect

    D'Angelo, S.

    1980-04-01

    The basic objective of the DOE Central Power Systems group is the development of technology for increasing the use of coal in central station electric power generation in an economical and environmentally acceptable manner. The two major research and development areas of this program are the Open Cycle Gas Turbine System and the Closed Cycle Gas Turbine System. Recognizing that the ultimate success of the DOE program is measured by end-user acceptance of the technology developed, the workshop was held to obtain utility industry comments and suggestions on the development of these systems and their potential use by electric power utilities. Representatives of equipment manufacturers, architect and engineering firms, and universities were also invited as participants to provide a comprehensive review of the technology development and implementation process. The 65 participants and observers examined the following topics: technical considerations of the Open Cycle and of the Closed Cycle Gas Turbine program; commercialization of both systems; and regulatory impacts on the development of both systems. Each group evaluated the existing program, indicating R and D objectives that they supported and cited recommendations for modifications and expansion of future R and D work.

  6. Brayton cycle solarized advanced gas turbine

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Described is the development of a Brayton Engine/Generator Set for solar thermal to electrical power conversion, authorized under DOE/NASA Contract DEN3-181. The objective was to design, fabricate, assemble, and test a small, hybrid, 20-kW Brayton-engine-powered generator set. The latter, called a power conversion assembly (PCA), is designed to operate with solar energy obtained from a parobolic dish concentrator, 11 meters in diameter, or with fossil energy supplied by burning fuels in a combustor, or by a combination of both (hybrid model). The CPA consists of the Brayton cycle engine, a solar collector, a belt-driven 20-kW generator, and the necessary control systems for automatic operation in solar-only, fuel-only, and hybrid modes to supply electrical power to a utility grid. The original configuration of the generator set used the GTEC Model GTP36-51 gas turbine engine for the PCA prime mover. However, subsequent development of the GTEC Model AGT101 led to its selection as the powersource for the PCA. Performance characteristics of the latter, thermally coupled to a solar collector for operation in the solar mode, are presented. The PCA was successfully demonstrated in the fuel-only mode at the GTEC Phoenix, Arizona, facilities prior to its shipment to Sandia National Laboratory in Albuquerque, New Mexico, for installation and testing on a test bed concentractor (parabolic dish). Considerations relative to Brayton-engine development using the all-ceramic AGT101 when it becomes available, which would satisfy the DOE heat engine efficiency goal of 35 to 41 percent, are also discussed in the report.

  7. Benefits of advanced technology in industrial cogeneration

    NASA Technical Reports Server (NTRS)

    Barna, G. J.; Burns, R. K.

    1979-01-01

    This broad study is aimed at identifying the most attractive advanced energy conversion systems for industrial cogeneration for the 1985 to 2000 time period and assessing the advantages of advanced technology systems compared to using today's commercially available technology. Energy conversion systems being studied include those using steam turbines, open cycle gas turbines, combined cycles, diesel engines, Stirling engines, closed cycle gas turbines, phosphoric acid and molten carbonate fuel cells and thermionics. Specific cases using today's commercially available technology are being included to serve as a baseline for assessing the advantages of advanced technology.

  8. Advanced Seal Development for Large Industrial Gas Turbines

    NASA Technical Reports Server (NTRS)

    Chupp, Raymond E.

    2006-01-01

    Efforts are in progress to develop advanced sealing for large utility industrial gas turbine engines (combustion turbines). Such seals have been under developed for some time for aero gas turbines. It is desired to transition this technology to combustion turbines. Brush seals, film riding face and circumferential seals, and other dynamic and static sealing approaches are being incorporated into gas turbines for aero applications by several engine manufacturers. These seals replace labyrinth or other seals with significantly reduced leakage rates. For utility industrial gas turbines, leakage reduction with advanced sealing can be even greater with the enormous size of the components. Challenges to transitioning technology include: extremely long operating times between overhauls; infrequent but large radial and axial excursions; difficulty in coating larger components; and maintenance, installation, and durability requirements. Advanced sealing is part of the Advanced Turbine Systems (ATS) engine development being done under a cooperative agreement between Westinghouse and the US Department of Energy, Office of Fossil Energy. Seal development focuses on various types of seals in the 501ATS engine both at dynamic and static locations. Each development includes rig testing of candidate designs and subsequent engine validation testing of prototype seals. This presentation gives an update of the ongoing ATS sealing efforts with special emphasis on brush seals.

  9. Radial inflow gas turbine engine with advanced transition duct

    DOEpatents

    Wiebe, David J

    2015-03-17

    A gas turbine engine (10), including: a turbine having radial inflow impellor blades (38); and an array of advanced transition combustor assemblies arranged circumferentially about the radial inflow impellor blades (38) and having inner surfaces (34) that are adjacent to combustion gases (40). The inner surfaces (34) of the array are configured to accelerate and orient, for delivery directly onto the radial inflow impellor blades (38), a plurality of discrete flows of the combustion gases (40). The array inner surfaces (34) define respective combustion gas flow axes (20). Each combustion gas flow axis (20) is straight from a point of ignition until no longer bound by the array inner surfaces (34), and each combustion gas flow axis (20) intersects a unique location on a circumference defined by a sweep of the radial inflow impellor blades (38).

  10. Update on DOE Advanced IGCC/H2 Gas Turbine

    NASA Technical Reports Server (NTRS)

    Chupp, Ray

    2009-01-01

    Cooling Flow Reduction: a) Focus on improving turbine hot gas path part cooling efficiency. b) Applicable to current metallic turbine components and synergistic with advanced materials. c) Address challenges of IGCC/hydrogen fuel environment (for example, possible cooling hole plugging). Leakage Flow Reduction: a) Focus on decreasing turbine parasitic leakages, i.e. between static-to-static, static-to-rotating turbine parts. b) Develop improved seal designs in a variety of important areas. Purge Flow Reduction: a) Focus on decreasing required flows to keep rotor disk cavities within temperature limits. b) Develop improved sealing at the cavity rims and modified flow geometries to minimize hot gas ingestion and aerodynamic impact.

  11. Direct-contact condensers for open-cycle OTEC applications: Model validation with fresh water experiments for structured packings

    SciTech Connect

    Bharathan, D.; Parsons, B.K.; Althof, J.A.

    1988-10-01

    The objective of the reported work was to develop analytical methods for evaluating the design and performance of advanced high-performance heat exchangers for use in open-cycle thermal energy conversion (OC-OTEC) systems. This report describes the progress made on validating a one-dimensional, steady-state analytical computer of fresh water experiments. The condenser model represents the state of the art in direct-contact heat exchange for condensation for OC-OTEC applications. This is expected to provide a basis for optimizing OC-OTEC plant configurations. Using the model, we examined two condenser geometries, a cocurrent and a countercurrent configuration. This report provides detailed validation results for important condenser parameters for cocurrent and countercurrent flows. Based on the comparisons and uncertainty overlap between the experimental data and predictions, the model is shown to predict critical condenser performance parameters with an uncertainty acceptable for general engineering design and performance evaluations. 33 refs., 69 figs., 38 tabs.

  12. Direct-contact condensers for open-cycle OTEC applications: Model validation with fresh water experiments for structured packings

    NASA Astrophysics Data System (ADS)

    Bharathan, D.; Parsons, B. K.; Althof, J. A.

    1988-10-01

    The objective of the reported work was to develop analytical methods for evaluating the design and performance of advanced high-performance heat exchangers for use in open-cycle thermal energy conversion (OC-OTEC) systems. This report describes the progress made on validating a one-dimensional, steady-state analytical computer of fresh water experiments. The condenser model represents the state of the art in direct-contact heat exchange for condensation for OC-OTEC applications. This is expected to provide a basis for optimizing OC-OTEC plant configurations. Using the model, we examined two condenser geometries, a cocurrent and a countercurrent configuration. This report provides detailed validation results for important condenser parameters for cocurrent and countercurrent flows. Based on the comparisons and uncertainty overlap between the experimental data and predictions, the model is shown to predict critical condenser performance parameters with an uncertainty acceptable for general engineering design and performance evaluations.

  13. Western tight gas sands advanced logging workshop proceedings

    SciTech Connect

    Jennings, J B; Carroll, Jr, H B

    1982-04-01

    An advanced logging research program is one major aspect of the Western Tight Sands Program. Purpose of this workshop is to help BETC define critical logging needs for tight gas sands and to allow free interchange of ideas on all aspects of the current logging research program. Sixteen papers and abstracts are included together with discussions. Separate abstracts have been prepared for the 12 papers. (DLC)

  14. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  15. An advanced oxidation process using ionized gas for wastewater treatment.

    PubMed

    Lee, Eun Ju; Chung, Paul Gene; Kwak, Dong Heui; Kim, Lee Hyung; Kim, Min Jeong

    2010-01-01

    This study on removing non-degradable materials in wastewater focused primarily on advanced oxidation methods such as ozone, ozone/UV and ozone/H2O2. Wastewater treatment using an ionized gas from plasma has been actively progressing. The ionized gas involves reactive species such as O2+, O2- cluster, O radical and OH radical. Since the ionized gas method has such outstanding characteristics as relatively simple structures, non-calorification, non-toxicity and low electricity consumption, it evidently of interest as a new process. A series of experiments were conducted to demonstrate the feasibility of ionized gas as a useful element for the diminution of nondegradable organic matters. On the other hand, a large amount of organic matters were changed to hydrophilic and the compounds containing aromatic functional group gradually decreased. The results implied that the ionized gas has been able to degrade the non-biodegradable organic matters. Therefore, the oxidation process by using an ionized gas process could be considered as an effective alternative unit in water and wastewater treatment plants.

  16. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  17. ADVANCED UNDERGROUND GAS STORAGE CONCEPTS REFRIGERATED-MINED CAVERN STORAGE

    SciTech Connect

    1998-09-01

    Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage development and PB-KBB reviewed the literature to determine if the geology of these regions was suitable for siting hard rock storage caverns. Area gas market conditions in these regions were also studied to determine the need for such storage. Based on an analysis of many factors, a possible site was determined to be in Howard and Montgomery Counties, Maryland. The area has compatible geology and a gas industry infrastructure for the nearby market populous of Baltimore and Washington D.C.. As Gas temperature is lowered, the compressibility of the gas reaches an optimum value. The compressibility of the gas, and the resultant gas density, is a function of temperature and pressure. This relationship can be used to commercial advantage by reducing the size of a storage cavern for a given working volume of natural gas. This study looks at this relationship and and the potential for commercialization of the process in a storage application. A conceptual process design, and cavern design were developed for various operating conditions. Potential site locations were considered

  18. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    1999-10-14

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3 % of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas The effort during the reporting period has been devoted to development of an advanced hot-gas process that can eliminate the problematic SO{sub 2} tail gas and yield elemental sulfur

  19. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated

  20. Advanced hot gas cleaning system for coal gasification processes

    NASA Astrophysics Data System (ADS)

    Newby, R. A.; Bannister, R. L.

    1994-04-01

    The United States electric industry is entering a period where growth and the aging of existing plants will mandate a decision on whether to repower, add capacity, or do both. The power generation cycle of choice, today, is the combined cycle that utilizes the Brayton and Rankine cycles. The combustion turbine in a combined cycle can be used in a repowering mode or in a greenfield plant installation. Today's fuel of choice for new combined cycle power generation is natural gas. However, due to a 300-year supply of coal within the United States, the fuel of the future will include coal. Westinghouse has supported the development of coal-fueled gas turbine technology over the past thirty years. Working with the U.S. Department of Energy and other organizations, Westinghouse is actively pursuing the development and commercialization of several coal-fueled processes. To protect the combustion turbine and environment from emissions generated during coal conversion (gasification/combustion) a gas cleanup system must be used. This paper reports on the status of fuel gas cleaning technology and describes the Westinghouse approach to developing an advanced hot gas cleaning system that contains component systems that remove particulate, sulfur, and alkali vapors. The basic process uses ceramic barrier filters for multiple cleaning functions.

  1. Leakage Currents and Gas Generation in Advanced Wet Tantalum Capacitors

    NASA Technical Reports Server (NTRS)

    Teverovsky, Alexander

    2015-01-01

    Currently, military grade, established reliability wet tantalum capacitors are among the most reliable parts used for space applications. This has been achieved over the years by extensive testing and improvements in design and materials. However, a rapid insertion of new types of advanced, high volumetric efficiency capacitors in space systems without proper testing and analysis of degradation mechanisms might increase risks of failures. The specifics of leakage currents in wet electrolytic capacitors is that the conduction process is associated with electrolysis of electrolyte and gas generation resulting in building up of internal gas pressure in the parts. The risk associated with excessive leakage currents and increased pressure is greater for high value advanced wet tantalum capacitors, but it has not been properly evaluated yet. In this work, in Part I, leakages currents in various types of tantalum capacitors have been analyzed in a wide range of voltages, temperatures, and time under bias. Gas generation and the level of internal pressure have been calculated in Part II for different case sizes and different hermeticity leak rates to assess maximal allowable leakage currents. Effects related to electrolyte penetration to the glass seal area have been studied and the possibility of failures analyzed in Part III. Recommendations for screening and qualification to reduce risks of failures have been suggested.

  2. Advanced Materials for Mercury 50 Gas Turbine Combustion System

    SciTech Connect

    Price, Jeffrey

    2008-09-30

    Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector

  3. Gas-turbine critical research and advanced technology support project

    NASA Technical Reports Server (NTRS)

    Clark, J. S.; Hodge, P. E.; Lowell, C. E.; Anderson, D. N.; Schultz, D. F.

    1981-01-01

    A technology data base for utility gas turbine systems capable of burning coal derived fuels was developed. The following areas are investigated: combustion; materials; and system studies. A two stage test rig is designed to study the conversion of fuel bound nitrogen to NOx. The feasibility of using heavy fuels in catalytic combustors is evaluated. A statistically designed series of hot corrosion burner rig tests was conducted to measure the corrosion rates of typical gas turbine alloys with several fuel contaminants. Fuel additives and several advanced thermal barrier coatings are tested. Thermal barrier coatings used in conjunction with low critical alloys and those used in a combined cycle system in which the stack temperature was maintained above the acid corrosion temperature are also studied.

  4. Development of advanced hot-gas desulfurization sorbents. Final report

    SciTech Connect

    Jothimurugesan, K.; Adeyiga, A.A.; Gangwal, S.K.

    1997-10-01

    The objective of this project was to develop hot-gas desulfurization sorbent formulations for relatively lower temperature application, with emphasis on the temperature range from 343--538 C. The candidate sorbents include highly dispersed mixed metal oxides of zinc, iron, copper, cobalt, nickel and molybdenum. The specific objective was to develop suitable sorbents, that would have high and stable surface area and are sufficiently reactive and regenerable at the relatively lower temperatures of interest in this work. Stability of surface area during regeneration was achieved by adding stabilizers. To prevent sulfation, catalyst additives that promote the light-off of the regeneration reaction at lower temperature was considered. Another objective of this study was to develop attrition-resistant advanced hot-gas desulfurization sorbents which show stable and high sulfidation reactivity at 343 to 538 C and regenerability at lower temperatures than leading first generation sorbents.

  5. Thermal Barrier Coatings for Advanced Gas Turbine and Diesel Engines

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1999-01-01

    Ceramic thermal barrier coatings (TBCS) have been developed for advanced gas turbine and diesel engine applications to improve engine reliability and fuel efficiency. However, durability issues of these thermal barrier coatings under high temperature cyclic conditions are still of major concern. The coating failure depends not only on the coating, but also on the ceramic sintering/creep and bond coat oxidation under the operating conditions. Novel test approaches have been established to obtain critical thermomechanical and thermophysical properties of the coating systems under near-realistic transient and steady state temperature and stress gradients encountered in advanced engine systems. This paper presents detailed experimental and modeling results describing processes occurring in the ZrO2-Y2O3 thermal barrier coating systems, thus providing a framework for developing strategies to manage ceramic coating architecture, microstructure and properties.

  6. Feasibility of magnetic bearings for advanced gas turbine engines

    NASA Technical Reports Server (NTRS)

    Hibner, David; Rosado, Lewis

    1992-01-01

    The application of active magnetic bearings to advanced gas turbine engines will provide a product with major improvements compared to current oil lubricated bearing designs. A rethinking of the engine rotating and static structure design is necessary and will provide the designer with significantly more freedom to meet the demanding goals of improved performance, increased durability, higher reliability, and increased thrust to weight ratio via engine weight reduction. The product specific technology necessary for this high speed, high temperature, dynamically complex application has been defined. The resulting benefits from this approach to aircraft engine rotor support and the complementary engine changes and improvements have been assessed.

  7. Feasibility of magnetic bearings for advanced gas turbine engines

    NASA Astrophysics Data System (ADS)

    Hibner, David; Rosado, Lewis

    1992-05-01

    The application of active magnetic bearings to advanced gas turbine engines will provide a product with major improvements compared to current oil lubricated bearing designs. A rethinking of the engine rotating and static structure design is necessary and will provide the designer with significantly more freedom to meet the demanding goals of improved performance, increased durability, higher reliability, and increased thrust to weight ratio via engine weight reduction. The product specific technology necessary for this high speed, high temperature, dynamically complex application has been defined. The resulting benefits from this approach to aircraft engine rotor support and the complementary engine changes and improvements have been assessed.

  8. Advanced Gas Turbine (AGT) Technology Development Project annual report

    NASA Technical Reports Server (NTRS)

    1986-01-01

    This report is the tenth in a series of Technical Summary reports for the Advanced Gas Turbine (AGT) Technology Development Project, authorized under NASA Contract DEN3-167, and sponsored by the Department of Energy (DOE). This report was prepared by Garrett Turbine Engine Company, A Division of the Garrett Corporation, and includes information provided by Ford Motor Company, the Carborundum Company, and AiResearch Casting Company. The Project is administered by Mr. Thomas N. Strom, Project Manager, NASA-Lewis Research Center, Cleveland, Ohio. This report covers plans and progress for the period July 1, 1984 through June 30, 1985.

  9. Advanced controls for airbreathing engines, volume 3: Allison gas turbine

    NASA Technical Reports Server (NTRS)

    Bough, R. M.

    1993-01-01

    The application of advanced control concepts to airbreathing engines may yield significant improvements in aircraft/engine performance and operability. Screening studies of advanced control concepts for airbreathing engines were conducted by three major domestic aircraft engine manufacturers to determine the potential impact of concepts on turbine engine performance and operability. The purpose of the studies was to identify concepts which offered high potential yet may incur high research and development risk. A target suite of proposed advanced control concepts was formulated and evaluated in a two-phase study to quantify each concept's impact on desired engine characteristics. To aid in the evaluation specific aircraft/engine combinations were considered: a Military High Performance Fighter mission, a High Speed Civil Transport mission, and a Civil Tiltrotor mission. Each of the advanced control concepts considered in the study are defined and described. The concept potential impact on engine performance was determined. Relevant figures of merit on which to evaluate the concepts are determined. Finally, the concepts are ranked with respect to the target aircraft/engine missions. A final report describing the screening studies was prepared by each engine manufacturer. Volume 3 of these reports describes the studies performed by the Allison Gas Turbine Division.

  10. Advanced Combustion Systems for Next Generation Gas Turbines

    SciTech Connect

    Joel Haynes; Jonathan Janssen; Craig Russell; Marcus Huffman

    2006-01-01

    Next generation turbine power plants will require high efficiency gas turbines with higher pressure ratios and turbine inlet temperatures than currently available. These increases in gas turbine cycle conditions will tend to increase NOx emissions. As the desire for higher efficiency drives pressure ratios and turbine inlet temperatures ever higher, gas turbines equipped with both lean premixed combustors and selective catalytic reduction after treatment eventually will be unable to meet the new emission goals of sub-3 ppm NOx. New gas turbine combustors are needed with lower emissions than the current state-of-the-art lean premixed combustors. In this program an advanced combustion system for the next generation of gas turbines is being developed with the goal of reducing combustor NOx emissions by 50% below the state-of-the-art. Dry Low NOx (DLN) technology is the current leader in NOx emission technology, guaranteeing 9 ppm NOx emissions for heavy duty F class gas turbines. This development program is directed at exploring advanced concepts which hold promise for meeting the low emissions targets. The trapped vortex combustor is an advanced concept in combustor design. It has been studied widely for aircraft engine applications because it has demonstrated the ability to maintain a stable flame over a wide range of fuel flow rates. Additionally, it has shown significantly lower NOx emission than a typical aircraft engine combustor and with low CO at the same time. The rapid CO burnout and low NOx production of this combustor made it a strong candidate for investigation. Incremental improvements to the DLN technology have not brought the dramatic improvements that are targeted in this program. A revolutionary combustor design is being explored because it captures many of the critical features needed to significantly reduce emissions. Experimental measurements of the combustor performance at atmospheric conditions were completed in the first phase of the program

  11. Open cycle He-3 cooling to 0.18 K for space operation

    NASA Astrophysics Data System (ADS)

    Frank, D.; Nast, T. C.

    It is pointed out that many space instruments will require very low cryogenic temperatures to perform satisfactorily. Thus, instruments for telescopes such as the Space Infrared Telescope Facility (SIRTF) will require a cooler to provide approximately 50 microwatts total cooling power at temperatures in the range from 0.1 to 0.3 K. The present paper is concerned with a long life open-cycle He-3 cooler which provides low cooling (50 microwatts) to a temperature as low as 0.18 K on the basis of a process involving the continuous evaporation of liquid He-3 and the loss of vapor through a vent tube. Attention is given to an open cycle He-3 cooler used in conjunction with a telescope which utilizes superfluid He-4, the venting characteristics, on-orbit liquid retention, and closed-cycle refrigeration below 1 K.

  12. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    1999-04-26

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3% of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas. The effort during the reporting period has been devoted to development of optimized low-cost zinc-oxide-based sorbents for Sierra-Pacific. The sorbent surface were modified to prevent

  13. SCALE-UP OF ADVANCED HOT-GAS DESULFURIZATION SORBENTS

    SciTech Connect

    K. JOTHIMURUGESAN; S.K. GANGWAL

    1998-03-01

    The objective of this study was to develop advanced regenerable sorbents for hot gas desulfurization in IGCC systems. The specific objective was to develop durable advanced sorbents that demonstrate a strong resistance to attrition and chemical deactivation, and high sulfidation activity at temperatures as low as 343 C (650 F). Twenty sorbents were synthesized in this work. Details of the preparation technique and the formulations are proprietary, pending a patent application, thus no details regarding the technique are divulged in this report. Sulfidations were conducted with a simulated gas containing (vol %) 10 H{sub 2}, 15 CO, 5 CO{sub 2}, 0.4-1 H{sub 2}S, 15 H{sub 2}O, and balance N{sub 2} in the temperature range of 343-538 C. Regenerations were conducted at temperatures in the range of 400-600 C with air-N{sub 2} mixtures. To prevent sulfation, catalyst additives were investigated that promote regeneration at lower temperatures. Characterization were performed for fresh, sulfided and regenerated sorbents.

  14. Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 8: Open-cycle MHD. [energy conversion efficiency and design analysis of electric power plants employing magnetohydrodynamics

    NASA Technical Reports Server (NTRS)

    Hoover, D. Q.

    1976-01-01

    Electric power plant costs and efficiencies are presented for three basic open-cycle MHD systems: (1) direct coal fired system, (2) a system with a separately fired air heater, and (3) a system burning low-Btu gas from an integrated gasifier. Power plant designs were developed corresponding to the basic cases with variation of major parameters for which major system components were sized and costed. Flow diagrams describing each design are presented. A discussion of the limitations of each design is made within the framework of the assumptions made.

  15. Development of advanced hot-gas desulfurization processes

    SciTech Connect

    Jothimurugesan, K.

    2000-04-17

    Advanced integrated gasification combined cycle (IGCC) power plants nearing completion, such as Sierra-Pacific, employ a circulating fluidized-bed (transport) reactor hot-gas desulfurization (HGD) process that uses 70-180 {micro}m average particle size (aps) zinc-based mixed-metal oxide sorbent for removing H{sub 2}S from coal gas down to less than 20 ppmv. The sorbent undergoes cycles of absorption (sulfidation) and air regeneration. The key barrier issues associated with a fluidized-bed HGD process are chemical degradation, physical attrition, high regeneration light-off (initiation) temperature, and high cost of the sorbent. Another inherent complication in all air-regeneration-based HGD processes is the disposal of the problematic dilute SO{sub 2} containing regeneration tail-gas. Direct Sulfur Recovery Process (DSRP), a leading first generation technology, efficiently reduces this SO{sub 2} to desirable elemental sulfur, but requires the use of 1-3 % of the coal gas, thus resulting in an energy penalty to the plant. Advanced second-generation processes are under development that can reduce this energy penalty by modifying the sorbent so that it could be directly regenerated to elemental sulfur. The objective of this research is to support the near and long term DOE efforts to commercialize the IGCC-HGD process technology. Specifically we aim to develop: optimized low-cost sorbent materials with 70-80 {micro}m average aps meeting all Sierra specs; attrition resistant sorbents with 170 {micro}m aps that allow greater flexibility in the choice of the type of fluidized-bed reactor e.g. they allow increased throughput in a bubbling-bed reactor; and modified fluidizable sorbent materials that can be regenerated to produce elemental sulfur directly with minimal or no use of coal gas. The effort during the reporting period has been devoted to testing the FHR-32 sorbent. FHR-32 sorbent was tested for 50 cycles of sulfidation in a laboratory scale reactor.

  16. DEVELOPMENT OF ADVANCED HOT-GAS DESULFURIZATION PROCESSES

    SciTech Connect

    K. Jothimurugesan; Santosh K. Gangwal

    2000-12-01

    The techniques employed in this project have successfully demonstrated the feasibility of preparing sorbents that achieve greater than 99% H{sub 2}S removal at temperatures 480 C and that retain their activity over 50 cycles. Fundamental understanding of phenomena leading to chemical deactivation and high regeneration light-off temperature has enabled us to successfully prepare and scale up a FHR-32 sorbent that showed no loss in reactivity and capacity over 50 cycles. This sorbent removed H{sub 2}S below 80 ppmv and lighted-off nicely at 480 C during regeneration. Overall the test is a success with potential for an optimized FHR-32 to be a candidate for Sierra-Pacific. An advanced attrition resistant hot-gas desulfurization sorbent that can eliminate the problematic SO{sub 2} tail gas and yield elemental sulfur directly has been developed. Attrition resistant Zn-Fe sorbent (AHI-2) formulations have been prepared that can remove H{sub 2}S to below 20 ppmv from coal gas and can be regenerated using SO{sub 2} to produce elemental sulfur.

  17. Natural Gas for Advanced Dual-Fuel Combustion Strategies

    NASA Astrophysics Data System (ADS)

    Walker, Nicholas Ryan

    Natural gas fuels represent the next evolution of low-carbon energy feedstocks powering human activity worldwide. The internal combustion engine, the energy conversion device widely used by society for more than one century, is capable of utilizing advanced combustion strategies in pursuit of ultra-high efficiency and ultra-low emissions. Yet many emerging advanced combustion strategies depend upon traditional petroleum-based fuels for their operation. In this research the use of natural gas, namely methane, is applied to both conventional and advanced dual-fuel combustion strategies. In the first part of this work both computational and experimental studies are undertaken to examine the viability of utilizing methane as the premixed low reactivity fuel in reactivity controlled compression ignition, a leading advanced dual-fuel combustion strategy. As a result, methane is shown to be capable of significantly extending the load limits for dual-fuel reactivity controlled compression ignition in both light- and heavy-duty engines. In the second part of this work heavy-duty single-cylinder engine experiments are performed to research the performance of both conventional dual-fuel (diesel pilot ignition) and advanced dual-fuel (reactivity controlled compression ignition) combustion strategies using methane as the premixed low reactivity fuel. Both strategies are strongly influenced by equivalence ratio; diesel pilot ignition offers best performance at higher equivalence ratios and higher premixed methane ratios, whereas reactivity controlled compression ignition offers superior performance at lower equivalence ratios and lower premixed methane ratios. In the third part of this work experiments are performed in order to determine the dominant mode of heat release for both dual-fuel combustion strategies. By studying the dual-fuel homogeneous charge compression ignition and single-fuel spark ignition, strategies representative of autoignition and flame propagation

  18. The coal-fired gas turbine locomotive - A new look

    NASA Technical Reports Server (NTRS)

    Liddle, S. G.; Bonzo, B. B.; Purohit, G. P.

    1983-01-01

    Advances in turbomachine technology and novel methods of coal combustion may have made possible the development of a competitive coal fired gas turbine locomotive engine. Of the combustor, thermodynamic cycle, and turbine combinations presently assessed, an external combustion closed cycle regenerative gas turbine with a fluidized bed coal combustor is judged to be the best suited for locomotive requirements. Some merit is also discerned in external combustion open cycle regenerative systems and internal combustion open cycle regenerative gas turbine systems employing a coal gasifier. The choice of an open or closed cycle depends on the selection of a working fluid and the relative advantages of loop pressurization, with air being the most attractive closed cycle working fluid on the basis of cost.

  19. Advanced Gas Turbine (AGT) power-train system development

    NASA Technical Reports Server (NTRS)

    Helms, H. E.; Johnson, R. A.; Gibson, R. K.

    1982-01-01

    Technical work on the design and component testing of a 74.5 kW (100 hp) advanced automotive gas turbine is described. Selected component ceramic component design, and procurement were tested. Compressor tests of a modified rotor showed high speed performance improvement over previous rotor designs; efficiency improved by 2.5%, corrected flow by 4.6%, and pressure ratio by 11.6% at 100% speed. The aerodynamic design is completed for both the gasifier and power turbines. Ceramic (silicon carbide) gasifier rotors were spin tested to failure. Improving strengths is indicated by burst speeds and the group of five rotors failed at speeds between 104% and 116% of engine rated speed. The emission results from combustor testing showed NOx levels to be nearly one order of magnitude lower than with previous designs. A one piece ceramic exhaust duct/regenerator seal platform is designed with acceptable low stress levels.

  20. Advancing Development and Greenhouse Gas Reductions in Vietnam's Wind Sector

    SciTech Connect

    Bilello, D.; Katz, J.; Esterly, S.; Ogonowski, M.

    2014-09-01

    Clean energy development is a key component of Vietnam's Green Growth Strategy, which establishes a target to reduce greenhouse gas (GHG) emissions from domestic energy activities by 20-30 percent by 2030 relative to a business-as-usual scenario. Vietnam has significant wind energy resources, which, if developed, could help the country reach this target while providing ancillary economic, social, and environmental benefits. Given Vietnam's ambitious clean energy goals and the relatively nascent state of wind energy development in the country, this paper seeks to fulfill two primary objectives: to distill timely and useful information to provincial-level planners, analysts, and project developers as they evaluate opportunities to develop local wind resources; and, to provide insights to policymakers on how coordinated efforts may help advance large-scale wind development, deliver near-term GHG emission reductions, and promote national objectives in the context of a low emission development framework.

  1. Environmental benefits of advanced oil and gas exploration and production technology

    SciTech Connect

    1999-10-01

    THROUGHOUT THE OIL AND GAS LIFE CYCLE, THE INDUSTRY HAS APPLIED AN ARRAY OF ADVANCED TECHNOLOGIES TO IMPROVE EFFICIENCY, PRODUCTIVITY, AND ENVIRONMENTAL PERFORMANCE. THIS REPORT FOCUSES SPECIFICALLY ON ADVANCES IN EXPLORATION AND PRODUCTION (E&P) OPERATIONS.

  2. Development of materials for open-cycle MHD. Quarterly report for the period ending March 1983

    SciTech Connect

    Marchant, D.D.; Bates, J.L.

    1983-07-01

    Pacific Northwest Laboratory (PNL) is conducting an ongoing study of channel components for open-cycle, coal-fired magnetohydrodynamic (MHD) generators. Specifically, electrodes and insulators are being developed. The electrical conductivity has been measured on several compositions based on hafnium oxide, rare earth oxides, and indium oxide. Indium oxide at present appears to be the main constituent required for high conductivity. As part of the development, materials are being corrosion tested in both Montana Rosebud coal slag and potassium sulfate (K/sub 2/SO/sub 4/). The results from three coal slag tests and one K/sub 2/SO/sub 4/ test are discussed in this document.

  3. Hot gas cleanup and gas turbine aspects of an advanced PFBC power plant

    SciTech Connect

    Robertson, A. ); Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.; Bruck, G.J.; Smeltzer, E.E. . Science and Technology Center)

    1992-01-01

    The overall objective of the second-generation PFBC development program is to advance this concept to a commercial status. Three major objectives of the current Phase 2 program activities are to: Separately test key components of the second-generation PFBC power plant at sub-scale to ascertain their performance characteristics, Revise the commercial plant performance and economic predictions where necessary, Prepare for a 1.6 MWe equivalent Phase 3 integrated subsystem test of the key components. The key components of the plant, with respect to development risk, are the carbonizer, the circulating PFBC unit, the ceramic barrier filter, and the topping combustor. This paper reports on the development and testing of one key component -- the ceramic barrier filter for the carbonizer fuel gas. The objective of the Phase 2 carbonizer ceramic barrier filter testing has been to confirm filter performance and operability in the carbonizer fuel gas environment.

  4. Experiments on oxygen desorption from surface warm seawater under Open-Cycle Ocean Thermal Energy Conversion (OC-OTEC) conditions

    NASA Astrophysics Data System (ADS)

    Pesaran, Ahmad A.

    1989-12-01

    This paper reports the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC). Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving a predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7 pct to 60 pct of dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 9 to 35 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20 pct to 60 pct. The dependence of oxygen desorption with flow rate could not be determined. The data also indicated that at typical OC-OTEC evaporator pressures when flashing occurred, 75 pct to 95 pct of dissolved oxygen was desorbed overall from the warm seawater. The uncertainty in results is larger than one would desire. These uncertainties are attributed to the uncertainties and difficulties in the dissolved oxygen measurements. Methods to improve the measurements for future gas desorption studies for warm surface and cold deep seawater under OC-OTEC conditions are recommended.

  5. Experiments on oxygen desorption from surface warm seawater under open-cycle ocean thermal energy conversion (OC-OTEC) conditions

    SciTech Connect

    Pesaran, A A

    1989-12-01

    This paper reports the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC). Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving a predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7% to 60% of dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 9 to 35 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20% to 60%. The dependence of oxygen desorption with flow rate could not be determined. The data also indicated that at typical OC-OTEC evaporator pressures when flashing occurred, 75% to 95% of dissolved oxygen was desorbed overall from the warm seawater. The uncertainty in results is larger than one would desire. These uncertainties are attributed to the uncertainties and difficulties in the dissolved oxygen measurements. Methods to improve the measurements for future gas desorption studies for warm surface and cold deep seawater under OC-OTEC conditions are recommended. 14 refs., 5 figs., 2 tabs.

  6. Innovative turbine concepts for open-cycle OTEC (Ocean Thermal Energy Conversion)

    NASA Astrophysics Data System (ADS)

    1989-12-01

    The results are summarized of preliminary studies conducted to identify and evaluate three innovative concepts for an open cycle ocean thermal energy conversion (OTEC) steam turbine that could significantly reduce the cost of OTEC electrical power plants. The three concepts are: (1) a crossflow turbine, (2) a vertical axis, axial flow turbine, and (3) a double flow, radial inflow turbine with mixed flow blading. In all cases, the innovation involves the use of lightweight, composite plastic blading and a physical geometry that facilitates efficient fluid flow to and from the other major system components and reduces the structural requirements for both the turbine or the system vacuum enclosure, or both. The performance, mechanical design, and cost of each of the concepts are developed to varying degrees but in sufficient detail to show that the potential exists for cost reductions to the goals established in the U.S. Department of Energy's planning documents. Specifically, results showed that an axial turbine operating with 33 percent higher steam throughput and 7 percent lower efficiency than the most efficient configuration provides the most cost effective open-cycle OTEC system. The vacuum enclosure can be significantly modified to reduce costs by establishing better interfaces with the system.

  7. Innovative turbine concepts for open-cycle OTEC (ocean thermal energy conversion)

    SciTech Connect

    Not Available

    1989-12-01

    This report summarizes the results of preliminary studies conducted to identify and evaluate three innovative concepts for an open-cycle ocean thermal energy conversion (OTEC) steam turbine that could significantly reduce the cost of OTEC electrical power plants. The three concepts are (1) a crossflow turbine, (2) a vertical-axis, axial-flow turbine, and (3) a double-flow, radial-inflow turbine with mixed-flow blading. In all cases, the innovation involves the use of lightweight, composite plastic blading and a physical geometry that facilitates efficient fluid flow to and from the other major system components and reduces the structural requirements for both the turbine or the system vacuum enclosure, or both. The performance, mechanical design, and cost of each of the concepts are developed to varying degrees but in sufficient detail to show that the potential exists for cost reductions to the goals established in the US Department of Energy's planning documents. Specifically, results showed that an axial turbine operating with 33% higher steam throughput and 7% lower efficiency than the most efficient configuration provides the most cost-effective open-cycle OTEC system. The vacuum enclosure can be significantly modified to reduce costs by establishing better interfaces with the system. 33 refs., 26 figs., 11 tabs.

  8. Thermodynamic systems analysis of open-cycle Ocean Thermal Energy Conversion (OTEC)

    NASA Astrophysics Data System (ADS)

    Parsons, B. K.; Bharathan, D.; Althof, J. A.

    1985-09-01

    This report describes an updated thermal-hydraulic systems analysis program called OTECSYS that studies the integrated performance of an open-cycle ocean thermal energy conversion (OTEC) plant, specifically, the effects of component performance, design parameters, and site specific resource data on the total system performance and plant size. OTECSYS can size the various open-cycle power cycle and hydraulic components. Models for the evaporator, mist eliminator, turbine-generator diffuser, direct-contact condenser, exhaust compressors, seawater pumps, and seawater piping are included, as are evaluations of the pressure drops associated with the intercomponent connections. It can also determine the required steam, cold seawater, and warm seawater flow rates. OTECSYS uses an approach similar to earlier work and integrates the most up-to-date developments in component performance and configuration. The program format allows the user to examine subsystem concepts not currently included by creating new component models. It will be useful to the OTEC plant designer who wants to quantify the design point sizing, performance, and power production using site-specific resource data. Detailed design trade-offs are easily evaluated, and several examples of these types of investigations are presented using plant size and power as criteria.

  9. [Advanced Gas Turbine Systems Research]. Technical Quarterly Progress Report

    SciTech Connect

    1998-09-30

    Major Accomplishments by Advanced Gas Turbine Systems Research (AGTSR) during this reporting period are highlighted below and amplified in later sections of this report: AGTSR distributed 50 proposals from the 98RFP to the IRB for review, evaluation and rank-ordering during the summer; AGTSR conducted a detailed program review at DOE-FETC on July 24; AGTSR organized the 1998 IRB proposal review meeting at SCIES on September 15-16; AGTSR consolidated all the IRB proposal scores and rank-orderings to facilitate the 98RFP proposal deliberations; AGTSR submitted meeting minutes and proposal short-list recommendation to the IRB and DOE for the 98RFP solicitation; AGTSR reviewed two gas turbine related proposals as part of the CU RFP State Project for renovating the central energy facility; AGTSR reviewed and cleared research papers with the IRB from the University of Pittsburgh, Wisconsin, and Minnesota; AGTSR assisted GTA in obtaining university stakeholder support of the ATS program from California, Pennsylvania, and Colorado; AGTSR assisted GTA in distributing alert notices on potential ATS budget cuts to over 150 AGTSR performing university members; AGTSR submitted proceedings booklet and organizational information pertaining to the OAI hybrid gas turbine workshop to DOE-FETC; For DOE-FETC, AGTSR updated the university consortium poster to include new members and research highlights; For DOE-FETC, the general AGTSR Fact Sheet was updated to include new awards, workshops, educational activity and select accomplishments from the research projects; For DOE-FETC, AGTSR prepared three fact sheets highlighting university research supported in combustion, aero-heat transfer, and materials; For DOE-FETC, AGTSR submitted pictures on materials research for inclusion in the ATS technology brochure; For DOE-FETC, AGTSR submitted a post-2000 roadmap showing potential technology paths AGTSR could pursue in the next decade; AGTSR distributed the ninth newsletter UPDATE to DOE, the

  10. Advanced Gas Turbine (AGT) Technology Development Project, ceramic component developments

    NASA Technical Reports Server (NTRS)

    Teneyck, M. O.; Macbeth, J. W.; Sweeting, T. B.

    1987-01-01

    The ceramic component technology development activity conducted by Standard Oil Engineered Materials Company while performing as a principal subcontractor to the Garrett Auxiliary Power Division for the Advanced Gas Turbine (AGT) Technology Development Project (NASA Contract DEN3-167) is summarized. The report covers the period October 1979 through July 1987, and includes information concerning ceramic technology work categorized as common and unique. The former pertains to ceramic development applicable to two parallel AGT projects established by NASA contracts DEN3-168 (AGT100) and DEN3-167 (AGT101), whereas the unique work solely pertains to Garrett directed activity under the latter contract. The AGT101 Technology Development Project is sponsored by DOE and administered by NASA-Lewis. Standard Oil directed its efforts toward the development of ceramic materials in the silicon-carbide family. Various shape forming and fabrication methods, and nondestructive evaluation techniques were explored to produce the static structural components for the ceramic engine. This permitted engine testing to proceed without program slippage.

  11. Advanced ceramic coating development for industrial/utility gas turbines

    NASA Technical Reports Server (NTRS)

    Vogan, J. W.; Stetson, A. R.

    1982-01-01

    A program was conducted with the objective of developing advanced thermal barrier coating (TBC) systems. Coating application was by plasma spray. Duplex, triplex and graded coatings were tested. Coating systems incorporated both NiCrAly and CoCrAly bond coats. Four ceramic overlays were tested: ZrO2.82O3; CaO.TiO2; 2CaO.SiO2; and MgO.Al2O3. The best overall results were obtained with a CaO.TiO2 coating applied to a NiCrAly bond coat. This coating was less sensitive than the ZrO2.8Y2O3 coating to process variables and part geometry. Testing with fuels contaminated with compounds containing sulfur, phosphorus and alkali metals showed the zirconia coatings were destabilized. The calcium titanate coatings were not affected by these contaminants. However, when fuels were used containing 50 ppm of vanadium and 150 ppm of magnesium, heavy deposits were formed on the test specimens and combustor components that required frequent cleaning of the test rig. During the program Mars engine first-stage turbine blades were coated and installed for an engine cyclic endurance run with the zirconia, calcium titanate, and calcium silicate coatings. Heavy spalling developed with the calcium silicate system. The zirconia and calcium titanate systems survived the full test duration. It was concluded that these two TBC's showed potential for application in gas turbines.

  12. Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment

    SciTech Connect

    National Energy Technology Laboratory

    2001-08-31

    The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

  13. Gas turbine critical research and advanced technology (CRT) support project

    NASA Technical Reports Server (NTRS)

    Furman, E. R.; Anderson, D. N.; Gedwill, M. A.; Lowell, C. E.; Schultz, D. F.

    1982-01-01

    The technical progress to provide a critical technology base for utility gas turbine systems capable of burning coal-derived fuels is summarized. Project tasks include the following: (1) combustion - to investigate the combustion of coal-derived fuels and the conversion of fuel-bound nitrogen to NOx; (2) materials - to understand and prevent the hot corrosion of turbine hot section materials; and (3) system studies - to integrate and guide the technological efforts. Technical accomplishments include: an extension of flame tube combustion testing of propane - Toluene Fuel Mixtures to vary H2 content from 9 to 18 percent by weight and the comparison of results with that predicted from a NASA Lewis General Chemical Kinetics Computer Code; the design and fabrication of combustor sector test section to test current and advanced combustor concepts; Testing of Catalytic combustors with residual and coal-derived liquid fuels; testing of high strength super alloys to evaluate their resistance to potential fuel impurities using doped clean fuels and coal-derived liquids; and the testing and evaluation of thermal barrier coatings and bond coatings on conventional turbine materials.

  14. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  15. Fracture behavior of advanced ceramic hot gas filters: Final report

    SciTech Connect

    Singh, J.P.; Majumdar, S.; Sutaria, M.; Bielke, W.

    1997-03-01

    This report presents the results of mechanical/microstructural evaluation, thermal shock/fatigue testing, and stress analyses of advanced hot-gas filters obtained from different manufacturers. These filters were fabricated from both monolithic ceramics and composites. The composite filters, made of both oxide and nonoxide materials, were in both as-fabricated and exposed conditions, whereas the monolithic filters were made only of nonoxide materials. Mechanical property measurement of composite filters included diametral compression testing with O-ring specimens and burst-testing of short filter segments with rubber plugs. In-situ strength of fibers in the composite filters was evaluated by microscopic technique. Thermal shock/fatigue resistance was estimated by measuring the strengths of filter specimens before and after thermal cycling from an air environment at elevated temperatures to a room temperature oil bath. Filter performance during mechanical and thermal shock/fatigue loadings was correlated with microstructural observations. Micromechanical models were developed to derive properties of composite filter constituents on the basis of measured mechanical properties of the filters. Subsequently, these properties were used to analytically predict the performance of composite filters during thermal shock loading.

  16. Advanced Gas Reactor (AGR)-5/6/7 Fuel Irradiation Experiments in the Advanced Test Reactor

    SciTech Connect

    A. Joseph Palmer; David A. Petti; S. Blaine Grover

    2014-04-01

    The United States Department of Energy’s Very High Temperature Reactor (VHTR) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which each consist of at least five separate capsules, are being irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gases also have on-line fission product monitoring the effluent from each capsule to track performance of the fuel during irradiation. The first two experiments (designated AGR-1 and AGR-2), have been completed. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. The design of the fuel qualification experiment, designated AGR-5/6/7, is well underway and incorporates lessons learned from the three previous experiments. Various design issues will be discussed with particular details related to selection of thermometry.

  17. Some heat pump concepts for residual heat utilization. [Absorption-cycle and open-cycle systems

    SciTech Connect

    Perez-Blanco, H.; Chen, F. C.

    1980-01-01

    Large quantities of low temperature heat in the industrial sector are rejected in the cooling water, condensate, and process water streams. While the energy rejected in these streams at temperatures between 40 and 80/sup 0/C amounts to 2.95 x 10/sup 9/ GJ/y, 2.42 x 10/sup 9/ GJ/y of process energy in the form of hot water and steam are needed in the United States. Industrial heat pumps, that recover the low temperature heat energy and upgrade it to a more usable temperature level, may improve the energy supply and demand situation. Two heat activated heat pump concepts - an absorption cycle system and an open cycle system are analyzed from the conceptual systems design and energy savings point of view. The results of the analysis and further research needs are presented.

  18. Technical support for open-cycle MHD program. Progress report, January-June 1979

    SciTech Connect

    Bomkamp, D. H.

    1980-07-01

    The support program for open-cycle MHD at the Argonne National Laboratory consists of developing the analytical tools needed for investigation of the performance of the major components in the combined-cycle MHD/steam power system. The analytical effort is centered on the primary components of the system that are unique to MHD and, also, on the integration of these analytical models into a model of the entire power-producing system. The present project activities include modeling of the combustor, generator, seed deposition, and formation and decomposition of NO. Parametric studies were performed to evaluate the performance of the U-25B generator and to support the design of the US U-25B generator. Refinements and improvements to the MHD systems code and executive program are described.

  19. GPSAP/V2 with applications to open-cycle MHD systems

    SciTech Connect

    Geyer, H. K.

    1981-01-01

    A preprocessor technique for performing lumped component system analysis is presented. By employing simple preprocessor statements, system configurations, constraints, and objective functions can easily be established and analyzed. Use is made of M.J.D. Powell's hybrid equation solver and his sequential quadratic programming method for solving constrained optimization problems. The use of recursive calling capability in both equation solver and optimizer makes possible a fast and efficient general methodology for decomposition and analysis of systems. By retaining the build-up Jacobians and Hessians of the constraints and objective functions, and effective means of reducing computing time is developed during parameter studies. Also presented is a collection of simple first-order models used in open-cycle MHD (OCMHD) applications. Examples of simple system configurations and their analysis are included.

  20. Development of materials for open-cycle MHD. Quarterly report for the period ending June 1983

    SciTech Connect

    Marchant, D.D.; Bates, J.L.

    1983-11-01

    Pacific Northwest Laboratory (PNL) is conducting an ongoing study of channel components for open-cycle, coal-fired magnetohydrodynamic (MHD) generators. Specifically, electrodes and insulators are being developed. The electrical conductivity has been measured on several compositions based on hafnium oxide, rare earth oxides, and indium oxide and on In/sub 2/O/sub 3/-SnO/sub 2/ compositions. Indium oxide at present appears to be the main constituent required for high conductivity. In the indium oxide-rare earth oxides-hafnium oxide compositions, the indium forms compounds with the other elements and is present in samples as individual grains and not as a contaminant along the grain boundary. In the In/sub 2/O/sub 3/-SnO/sub 2/ compositions, adding SnO/sub 2/ to In/sub 2/O/sub 3/ produces compositions with higher conductivity than pure In/sub 2/O/sub 3/.

  1. Development of materials for open-cycle MHD. Quarterly report ending December 1982

    SciTech Connect

    Marchant, D.D.; Bates, J.L.

    1983-03-01

    Pacific Northwest Laboratory (PNL) is conducting an ongoing study of channel components for open cycle, coal-fired magnetohydrodynamic generators. specifically, electrodes/insulators are being developed and tested. For this study, a hot-walled test channel with eight electrodes was fabricated for testing in the WESTF test facility at Westinghouse Research and Development Laboratory, Pittsburgh, Pennsylvania. The chanel is designed to operate hot on all four walls, thereby reducing the amount of condensed slag. The compositions of four of the electrodes in the test channel were based on hafnium oxide-rare earth oxides-indium oxide. The electrical conductivity has been measured on several compositions based on hafnium oxide-rare earth oxides-indium oxides. The results show that adequate conductivity may be obtained with reduced indium oxide content as long as praseodymium oxide is used as the rare earth.

  2. Technical support for open-cycle MHD program. Progress report, October-December 1979

    SciTech Connect

    Doss, E. D.

    1980-12-01

    The support program for open-cycle MHD at Argonne National Laboratory is developing the analytical tools needed to investigate the performance of the major components in the combined cycle MHD/steam power system. The analytical effort is centered on the primary components of the system that are unique to MHD and also on the integration of these analytical representations into a model of the entire power producing system. The present project activities include modeling of the combustor, MHD channel and diffuser, slag separator, radiant boiler and high-temperature air heater. In addition, these models are combined into a complete system model, which is, at present, capable of carrying out optimizations of the entire system relative to either thermodynamic efficiency or cost of electrical power. Progress is reported in detail.

  3. Potential of proposed open-cycle OTEC experiments to achieve net power

    SciTech Connect

    Link, H F; Parsons, B K

    1986-06-01

    Researchers at the Solar Energy Research Institute (SERI) conducted systems analysis studies to determine the potential of various experiments to produce net power using the Claude open-cycle ocean thermal energy conversion (OTEC) power system. The proposed experiment test site is to be the Natural Energy Laboratory of Hawaii at Keahole Point. We found that net power is unlikely to be produced in experiment sizes that use less than about 195 kg/s (3000 gpm) of cold water, and that flow rates of 420 kg/s (6500 gpm) are necessary to achieve a net-power production of at least one-half the gross-power output of the experiment.

  4. Open cycle OTEC thermal-hydraulic systems analysis and parametric studies

    NASA Astrophysics Data System (ADS)

    Patsons, B.; Bharathan, D.; Althof, J.

    1984-06-01

    An analytic thermohydraulic systems model of the power cycle an seawater supply systems for an open cycle ocean thermal energy conversion (OTEC) plant has been developed that allows ready examination of the effects of system and component operating points on plant size and parasitic power requirements. This paper presents the results of three parametric studies on the effects of system temperature distribution, plant gross electric capacity, and the allowable seawater velocity in the supply and discharge pipes. The paper also briefly discusses the assumptions and equations used in the model and the state-of-the-art component limitations. The model provides a useful tool for an OTEC plant designer to evaluate system trade-offs and define component interactions and performance.

  5. Dimensional approach on hot air turbine power plant in opened cycle for straw recycling

    NASA Astrophysics Data System (ADS)

    Bălănescu, D. T.; Homutescu, V. M.; Atanasiu, M. V.

    2016-08-01

    Currently, disposal of straw is one of the biggest problems that crop plant producers are facing. The ideal case implies not only to get rid of straw but also to recover its energetic potential. In this context, the performance of a hot air turbine power plant operating in open cycle, with straw as fuel, was analyzed in a previous study and proved to be a very interesting solution for straw disposal. As consequence, dimensional analysis of the hot air turbine power plant is required into the next step and this makes the subject of the present study. The dimensional analysis is focused on the compressed air heater - the largest component of the Power Plant, with crucial role in what concerns its entire size and mass. Once both performance and dimensional analysis performed, the final conclusions are drawn in an overall approach, by taking also into consideration the economic aspects.

  6. Study of seed reporcessing systems for open cycle coal fired MHD power plants

    SciTech Connect

    1980-07-01

    If open-cycle coal-fired MHD power generation is to be commercially competitive, a large fraction of the potassium seed must be recycled. Cost of processing the seed for recycle must not be excessive and must be less than the cost of make up seed. A preliminary evaluation of the following processes was performed: PERC; formate; aqueous carbonate; modified tampella; scrubber, with and without removal of ash from spent seed; Tomlinson - Tampella; and electrodialysis and electrodialysis - deionization. Criteria considered in the evaluation included cost, state of development, seed loss, power requirements, availability, durability, key component risk, environmental impact, safety, controllability, and impurities buildup. None of the processes is fully proven for this type recycle operation. All require some degree of development. Results are presented in detail, and recommendations are included. (WHK)

  7. Defining the needs for gas centrifuge enrichment plants advanced safeguards

    SciTech Connect

    Boyer, Brian David; Erpenbeck, Heather H; Miller, Karen A; Swinhoe, Martyn T; Ianakiev, Kiril; Marlow, Johnna B

    2010-04-05

    Current safeguards approaches used by the International Atomic Energy Agency (IAEA) at gas centrifuge enrichment plants (GCEPs) need enhancement in order to verify declared low-enriched (LEU) production, detect undeclared LEU production and detect highly enriched uranium (HEU) production with adequate detection probability using nondestructive assay (NDA) techniques. At present inspectors use attended systems, systems needing the presence of an inspector for operation, during inspections to verify the mass and {sup 235}U enrichment of declared UF{sub 6} containers used in the process of enrichment at GCEPs. In verifying declared LEU production, the inspectors also take samples for off-site destructive assay (DA) which provide accurate data, with 0.1% to 0.5% measurement uncertainty, on the enrichment of the UF{sub 6} feed, tails, and product. However, taking samples of UF{sub 6} for off-site analysis is a much more labor and resource intensive exercise for the operator and inspector. Furthermore, the operator must ship the samples off-site to the IAEA laboratory which delays the timeliness of results and interruptions to the continuity of knowledge (CofK) of the samples during their storage and transit. This paper contains an analysis of possible improvements in unattended and attended NDA systems such as process monitoring and possible on-site analysis of DA samples that could reduce the uncertainty of the inspector's measurements and provide more effective and efficient IAEA GCEPs safeguards. We also introduce examples advanced safeguards systems that could be assembled for unattended operation.

  8. Advanced sulfur control concepts for hot gas desulfurization technology

    SciTech Connect

    1998-09-01

    The objective of this project is to develop a hot-gas desulfurization process scheme for control of H{sub 2}S in HTHP coal gas that can be more simply and economically integrated with known regenerable sorbents in DOE/METC-sponsored work than current leading hot-gas desulfurization technologies. In addition to being more economical, the process scheme to be developed must yield an elemental sulfur byproduct.

  9. ADVANCED SULFUR CONTROL CONCEPTS FOR HOT GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect

    1998-09-30

    The objective of this project is to develop a hot-gas desulfurization process scheme for control of H2S in HTHP coal gas that can be more simply and economically integrated with known regenerable sorbents in DOE/METC-sponsored work than current leading hot-gas desulfurization technologies. In addition to being more economical, the process scheme to be developed must yield an elemental sulfur byproduct. The Direct Sulfur Recovery Process (DSRP), a leading process for producing an elemental sulfur byproduct in hot-gas desulfurization systems, incurs a coal gas use penalty, because coal gas is required to reduce the SO2 in regeneration off-gas to elemental sulfur. Alternative regeneration schemes, which avoid coal gas use and produce elemental sulfur, will be evaluated. These include (i) regeneration of sulfided sorbent using SO2 ; (ii) partial oxidation of sulfided sorbent in an O2 starved environment; and (iii) regeneration of sulfided sorbent using steam to produce H2S followed by direct oxidation of H2S to elemental sulfur. Known regenerable sorbents will be modified to improve the feasibility of the above alternative regeneration approaches. Performance characteristics of the modified sorbents and processes will be obtained through lab- and bench-scale testing. Technical and economic evaluation of the most promising processes concept(s) will be carried out.

  10. Advance Notice of Proposed Rule Making for Minor Source Permitting in Indian Country - Oil and Gas

    EPA Pesticide Factsheets

    Advance Notice of Proposed Rulemaking to solicit broad feedback on the most effective and efficient means of implementing the EPA's Indian Country Minor New Source Review program for sources in the oil and natural gas production segment.

  11. Experiments on oxygen desorption from surface warm seawater under open-cycle ocean thermal energy conversion

    SciTech Connect

    Pesaran, A.A. )

    1992-11-01

    This paper presents the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC) conditions. Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving the predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7 percent to 60 percent of the dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 35 to 9 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20 percent to 60 percent. The data also indicated that at typical OC-OTEC evaporator pressures, when flash evaporation in the evaporator occurred, 75 percent to 95 percent of the dissolved oxygen was desorbed overall from the warm seawater. The results were used to find the impact of a single-stage predeaeration scheme on the power to remove noncondensable gases in an OC-OTEC plant.

  12. Development of materials for open-cycle MHD. Quarterly report for the period ending March 1984

    SciTech Connect

    Marchant, D.D.; Bates, J.L.

    1984-09-01

    Pacific Northwest Laboratory (PNL) is conducting a study of channel components for open-cycle, coal-fired magnetohydrodynamic (MHD) generators. Specifically, electrodes and insulators are being developed. The electrical conductivity has been measured on several compositions based on indium oxide-tin oxide (In/sub 2/O/sub 3/-SnO/sub 2/). These compositions have been studied as additives to refractory ceramic oxides to increase the low-temperature electrical conductivity. Indium oxide appears to be the main constituent required for high conductivity. The electrical conductivity of In/sub 2/O/sub 3/-SnO/sub 2/ compositions increases with increasing In/sub 2/O/sub 3/ concentration and reaches a maximum with compositions containing about 95 mo% In/sub 2/O/sub 3/. These high In/sub 2/O/sub 3/-containing compositions behave like degenerate semiconductors; the electrical conductivity decreases with increasing temperature. Three major crystallographic phases were identified for each composition, and were tested for their relative electrical conductivity and corrosion resistance to determine which phase would be most suitable for use as an additive to refractory ceramic oxides.

  13. The performance of a solar-regenerated open-cycle desiccant bed grain cooling system

    SciTech Connect

    Ismail, M.Z.; Angus, D.E. ); Thorpe, G.R. )

    1991-01-01

    The cooling of stored food grains suppresses the growth of populations of insect pests, inhibits spoilage by fungi and helps to preserve grain quality. In temperate and subtropical climates, grains may be effectively cooled by ventilating them with ambient air. In tropical climates, the enthalpy of the air must be reduced before it can be used for cooling grain. One method of achieving this is to isothermally reduce the humidity of the air. This paper describes experiments carried out on a simple-to-build solar-regenerated open-cycle grain cooling system. The device consists of a 5.85 m{sup 2} collector coupled with two beds of silica gel. Results from a series of experiments suggest that the device may be used to cool up to 200 tons of grain. The electrical power consumption of the device is of the order of 0.3 watt per ton of grain cooled, and the total electrical energy consumption is of the order of 0.7 kWh per ton of grain stored for a six-month period. The effectiveness of the device is a function of air flow rate and the enthalpy of ambient air, and results presented in this paper suggest that the solar cooling device is particularly effective in tropical climates.

  14. Performance and economics of advanced energy conversion systems for coal and coal-derived fuels

    NASA Technical Reports Server (NTRS)

    Corman, J. C.; Fox, G. R.

    1978-01-01

    The desire to establish an efficient Energy Conversion System to utilize the fossil fuel of the future - coal - has produced many candidate systems. A comparative technical/economic evaluation was performed on the seven most attractive advanced energy conversion systems. The evaluation maintains a cycle-to-cycle consistency in both performance and economic projections. The technical information base can be employed to make program decisions regarding the most attractive concept. A reference steam power plant was analyzed to the same detail and, under the same ground rules, was used as a comparison base. The power plants were all designed to utilize coal or coal-derived fuels and were targeted to meet an environmental standard. The systems evaluated were two advanced steam systems, a potassium topping cycle, a closed cycle helium system, two open cycle gas turbine combined cycles, and an open cycle MHD system.

  15. Ambient Laboratory Coater for Advanced Gas Reactor Fuel Development

    SciTech Connect

    Duane D. Bruns; Robert M. Counce; Irma D. Lima Rojas

    2010-06-09

    this research is targeted at developing improved experimentally-based scaling relationships for the hydrodynamics of shallow, gas-spouted beds of dense particles. The work is motivated by the need to more effctively scale up shallow spouted beds used in processes such as in the coating of nuclear fuel particles where precise control of solids and gas circulation is critically important. Experimental results reported here are for a 50 mm diameter spouted bed containing two different types of bed solids (alumina and zirconia) at different static bed depths and fluidized by air and helium. Measurements of multiple local average pressures, inlet gas pressure fluctuations, and spout height were used to characterize the bed hydrodynamics for each operating condition. Follow-on studies are planned that include additional variations in bed size, particle properties, and fluidizing gas. The ultimate objective is to identify the most important non-dimensional hydrodynamic scaling groups and possible spouted-bed design correlations based on these groups.

  16. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Compressor development, turbine, combustion, regenerator system, gearbox/transmission, ceramic material and component development, foil gas bearings, bearings and seals, rotor dynamics development, and controls and accessories are discussed.

  17. [Advances in research on neuroprotective effects of inert gas].

    PubMed

    Chen, Sheng; Guo, Song-xue; Hong, Yuan; Zhang, Jian-min

    2011-01-01

    Inert gas is a group of rare gases with very low activity, their application in medical field has increasingly drawn attentions. It is known that inert gases helium, xenon and argon have protective effects on nervous system and the mechanisms are related to eradicating free radicals, anti-inflammation, suppressing apoptosis, influencing ion channels and so on. Further study on the neuroprotective effect of inert gas will shed light on a new approach to treat neurological diseases.

  18. Advances in Thermal Spray Coatings for Gas Turbines and Energy Generation: A Review

    NASA Astrophysics Data System (ADS)

    Hardwicke, Canan U.; Lau, Yuk-Chiu

    2013-06-01

    Functional coatings are widely used in energy generation equipment in industries such as renewables, oil and gas, propulsion engines, and gas turbines. Intelligent thermal spray processing is vital in many of these areas for efficient manufacturing. Advanced thermal spray coating applications include thermal management, wear, oxidation, corrosion resistance, sealing systems, vibration and sound absorbance, and component repair. This paper reviews the current status of materials, equipment, processing, and properties' aspects for key coatings in the energy industry, especially the developments in large-scale gas turbines. In addition to the most recent industrial advances in thermal spray technologies, future technical needs are also highlighted.

  19. Advanced Sorbents as a Versatile Platform for Gas Separation

    SciTech Connect

    Neil Stephenson

    2003-09-30

    The program objective was to develop materials and processes for industrial gas separations to reduce energy use and enable waste reduction. The approach chosen combined novel oxygen selective adsorbents and pressure swing adsorption (PSA) processes. Preliminary materials development and process simulation results indicated that oxygen selective adsorbents could provide a versatile platform for industrial gas separations. If fully successful, this new technology offered the potential for reducing the cost of producing nitrogen/oxygen co-products, high purity nitrogen, argon, and possibly oxygen. The potential energy savings for the gas separations are appreciable, but the end users are the main beneficiaries. Lowering the cost of industrial gases expands their use in applications that can employ them for reducing energy consumption and emissions.

  20. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1980-01-01

    Progress in the development of a gas turbine engine to improve fuel economy, reduce gaseous emissions and particulate levels, and compatible with a variety of alternate fuels is reported. The powertrain is designated AGT101 and consists of a regenerated single shaft gas turbine engine, a split differential gearbox and a Ford Automatic Overdrive production transmission. The powertrain is controlled by an electronic digital microprocessor and associated actuators, instrumentation, and sensors. Standard automotive accessories are driven by engine power provided by an accessory pad on the gearbox. Component/subsystem development progress is reported in the following areas: compressor, turbine, combustion system, regenerator, gearbox/transmission, structures, ceramic components, foil gas bearing, bearings and seals, rotor dynamics, and controls and accessories.

  1. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1982-01-01

    A gas turbine powertrain for automobiles with reduced fuel consumption and reduced environmental impact is investigated. The automotive gas turbine, when installed in an automobile (3000 pounds inertia weight), provides a CFDC fuel economy of 42.8 miles per gallon based on EPA test procedures and diesel No. 2 fuel. The AGT powered vehicle substantially gives the same overall vehicle driveability and performance as a comparable production vehicle powered by a conventional spark ignition powertrain system. The emissions are less than federal standards, and a variety of fuels can be used.

  2. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1982-01-01

    Topics covered include the AGT 101 engine test; compressor design modification; cold air turbine testing; Mod 1 alloy turbine rotor fabrication; combustion aspects; regenerator development; and thermal screening tests for ceramic materials. The foil gas bearings, rotor dynamics, and AGT controls and accessories are also considered.

  3. Designing advanced biochar products for maximizing greenhouse gas mitigation potential

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Greenhouse gas (GHG) emissions from agricultural operations continue to increase. Carbon enriched char materials like biochar have been described as a mitigation strategy. Utilization of biochar material as a soil amendment has been demonstrated to provide potentially further soil GHG suppression du...

  4. Non-Intrusive, Distributed Gas Sensing Technology for Advanced Spacesuits

    NASA Technical Reports Server (NTRS)

    Delgado, Jesus; Phillips, Straun; Rubtsov, Vladimir; Chullen, Cinda

    2015-01-01

    Chemical sensors for monitoring gas composition, including oxygen, humidity, carbon dioxide, and trace contaminants, are needed to characterize and validate spacesuit design and operating parameters. This paper reports on the first prototypes of a non-intrusive gas sensing technology based on flexible sensitive patches positioned inside spacesuit prototypes and interrogated via optical fibers routed outside the suit, taking advantage of the transparent materials of the suit prototypes. The sensitive patches are based on luminescent materials whose emission parameters vary with the partial pressure of a specific gas. Patches sensitive to carbon dioxide, humidity, and temperature have been developed, and their preliminary laboratory characterization in Mark III-like helmet parts is described. The first prototype system consists of a four-channel fiber optic luminescent detector that can be used to monitor any of the selected target gases at four locations. To switch from one gas to another we replace the (disposable) sensor patches and adjust the system settings. Repeatability among sensitive patches and of sensor performance from location to location has been confirmed, assuring that suit engineers will have flexibility in selecting multiple sensing points, fitting the sensor elements into the spacesuit, and easily repositioning the sensor elements as desired. The evaluation of the first prototype for monitoring carbon dioxide during washout studies in a spacesuit prototype is presented.

  5. Non-Intrusive, Distributed Gas Sensing Technology for Advanced Spacesuits

    NASA Technical Reports Server (NTRS)

    Delgado, Jesus; Phillips, Straun; Rubtsov, Vladimir; Chullen, Cinda

    2015-01-01

    Chemical sensors for monitoring gas composition, including oxygen, humidity, carbon dioxide, and trace contaminants are needed to characterize and validate spacesuit design and operating parameters. This paper reports on the first prototypes of a non-intrusive gas sensing technology based on flexible sensitive patches positioned inside spacesuit prototypes and interrogated by optical fibers routed outside the suit, taking advantage of the transparent materials of the suit prototypes. The sensitive patches are based on luminescent materials whose emission parameters vary with the partial pressure of a specific gas. Patches sensitive to carbon dioxide, humidity, oxygen, and ammonia have been developed, and their preliminary characterization in the laboratory using Mark III-like helmet parts is described. The first prototype system consists of a four-channel fiber optic luminescent detector that can be used to monitor any of the selected target gases at four locations. To switch from one gas to another we replace the (disposable) sensor patches and adjust the system settings. Repeatability among sensitive patches and of sensor performance from location to location has been confirmed, assuring that suit engineers will have flexibility in selecting multiple sensing points, fitting the sensor elements into the spacesuit, and easily repositioning the sensor elements as desired. The evaluation of the first prototype for monitoring carbon dioxide during washout studies in a space suit prototype is presented.

  6. Advanced Hydraulic Fracturing Technology for Unconventional Tight Gas Reservoirs

    SciTech Connect

    Stephen Holditch; A. Daniel Hill; D. Zhu

    2007-06-19

    The objectives of this project are to develop and test new techniques for creating extensive, conductive hydraulic fractures in unconventional tight gas reservoirs by statistically assessing the productivity achieved in hundreds of field treatments with a variety of current fracturing practices ranging from 'water fracs' to conventional gel fracture treatments; by laboratory measurements of the conductivity created with high rate proppant fracturing using an entirely new conductivity test - the 'dynamic fracture conductivity test'; and by developing design models to implement the optimal fracture treatments determined from the field assessment and the laboratory measurements. One of the tasks of this project is to create an 'advisor' or expert system for completion, production and stimulation of tight gas reservoirs. A central part of this study is an extensive survey of the productivity of hundreds of tight gas wells that have been hydraulically fractured. We have been doing an extensive literature search of the SPE eLibrary, DOE, Gas Technology Institute (GTI), Bureau of Economic Geology and IHS Energy, for publicly available technical reports about procedures of drilling, completion and production of the tight gas wells. We have downloaded numerous papers and read and summarized the information to build a database that will contain field treatment data, organized by geographic location, and hydraulic fracture treatment design data, organized by the treatment type. We have conducted experimental study on 'dynamic fracture conductivity' created when proppant slurries are pumped into hydraulic fractures in tight gas sands. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially; we pump proppant/frac fluid slurries into a fracture cell, dynamically placing the proppant just as it occurs in the field. From such tests, we expect to gain new insights into some of the critical issues in tight gas fracturing, in

  7. Gas Foil Bearing Technology Advancements for Closed Brayton Cycle Turbines

    NASA Technical Reports Server (NTRS)

    Howard, Samuel A.; Bruckner, Robert J.; DellaCorte, Christopher; Radil, Kevin C.

    2007-01-01

    Closed Brayton Cycle (CBC) turbine systems are under consideration for future space electric power generation. CBC turbines convert thermal energy from a nuclear reactor, or other heat source, to electrical power using a closed-loop cycle. The operating fluid in the closed-loop is commonly a high pressure inert gas mixture that cannot tolerate contamination. One source of potential contamination in a system such as this is the lubricant used in the turbomachine bearings. Gas Foil Bearings (GFB) represent a bearing technology that eliminates the possibility of contamination by using the working fluid as the lubricant. Thus, foil bearings are well suited to application in space power CBC turbine systems. NASA Glenn Research Center is actively researching GFB technology for use in these CBC power turbines. A power loss model has been developed, and the effects of a very high ambient pressure, start-up torque, and misalignment, have been observed and are reported here.

  8. Fuel economy screening study of advanced automotive gas turbine engines

    NASA Technical Reports Server (NTRS)

    Klann, J. L.

    1980-01-01

    Fuel economy potentials were calculated and compared among ten turbomachinery configurations. All gas turbine engines were evaluated with a continuously variable transmission in a 1978 compact car. A reference fuel economy was calculated for the car with its conventional spark ignition piston engine and three speed automatic transmission. Two promising engine/transmission combinations, using gasoline, had 55 to 60 percent gains over the reference fuel economy. Fuel economy sensitivities to engine design parameter changes were also calculated for these two combinations.

  9. Advances in Ammonia Removal from Hot Coal Gas

    SciTech Connect

    Jothimurugesan, K.; Gangwal, S.K.

    1996-12-31

    Nitrogen occurs in coal in the form of tightly bound organic ring compounds, typically at levels of 1 to 2 wt%. During coal gasification, this fuel bound nitrogen is released principally as ammonia (NH{sub 3}). When hot coal gas is used to generate electricity in integrated gasification combined cycle (IGCC) power plants, NH{sub 3} is converted to nitrogen oxides (NO{sub x}) which are difficult to remove and are highly undesirable as atmospheric pollutants. Similarly, while the efficiency of integrated gasification molten carbonate fuel cell (IGFC) power plants is not affected by NH{sub 3}, NO{sub x} is generated during combustion of the anode exhaust gas. Thus NH{sub 3} must be removed from hot coal gas before it can be burned in a turbine or fuel cell. The objective of this study is to develop a successful combination of an NH{sub 3} decomposition catalyst with a zinc-based mixed-metal oxide sorbent so that the sorbent-catalyst activity remains stable for NH{sub 3} decomposition in addition to H{sub 2}S removal under cycle sulfidation-regeneration conditions in the temperature range of 500 to 750{degrees}C.

  10. Progress towards the Advanced Cryogenic Gas Stopper at NSCL

    NASA Astrophysics Data System (ADS)

    Lund, Kasey; Bollen, Georg; Villiari, Antonio; Lawton, Don; Morrissey, Dave; Otterson, Jack; Ringle, Ryan; Schwarz, Stefan; Sumithrarachchi, Chandana; Yurkon, John; Advanced Cryogenic Gas Stopper Design Team

    2016-09-01

    Beam stopping is the key to performing experiments with low-energy beams of rare isotopes produced by projectile fragmentation. Linear gas stoppers filled with helium have become reliable tools to accomplish this task. Further developments are underway to maximize efficiency and beam rate capability in order to increase scientific reach. Improvements include increasing extraction efficiency, lowering decay losses due to slow transport time, reducing molecular combination of the isotope of interest with background impurity gases, and minimizing space charge effects. The ACGS under construction at NSCL is designed to increase performance by overcoming some of the more common issues. The use of a 4-phase RF wire carpet to generate an electrical traveling wave speeds up the ion transport times. Cryogenic cooling of the helium gas chamber reduces molecular ion information. A geometry that puts the RF carpet in the mid-plane of the gas stopper alleviates space charge effects. Prototype testing of important ACGS components has been completed, specifically ion transport tests of the newly designed RF wire carpets. Transport efficiencies up to 95% were demonstrated as well as transport speeds up to 100 m/s. RC104100.7301.

  11. Final report for the Advanced Natural Gas Vehicle Project

    SciTech Connect

    John Wozniak

    1999-02-16

    The project objective was to develop the technologies necessary to prototype a dedicated compressed natural gas (CNG) powered, mid-size automobile with operational capabilities comparable to gasoline automobiles. A system approach was used to design and develop the engine, gas storage system and vehicle packaging. The 2.4-liter DOHC engine was optimized for natural gas operation with high-compression pistons, hardened exhaust valves, a methane-specific catalytic converter and multi-point gaseous injection. The chassis was repackaging to increase space for fuel storage with a custom-designed, cast-aluminum, semi-trailing arm rear suspension system, a revised flat trunk sheet-metal floorpan and by equipping the car with run-flat tires. An Integrated Storage system (ISS) was developed using all-composite, small-diameter cylinders encapsulated within a high-strength fiberglass shell with impact-absorbing foam. The prototypes achieved the target goals of a city/highway driving range of 300 miles, ample trunk capacity, gasoline vehicle performance and ultra low exhaust emissions.

  12. Residual gas analysis for long-pulse, advanced tokamak operation.

    PubMed

    Klepper, C C; Hillis, D L; Bucalossi, J; Douai, D; Oddon, P; Vartanian, S; Colas, L; Manenc, L; Pégourié, B

    2010-10-01

    A shielded residual gas analyzer (RGA) system on Tore Supra can function during plasma operation and is set up to monitor the composition of the neutral gas in one of the pumping ducts of the toroidal pumped limited. This "diagnostic RGA" has been used in long-pulse (up to 6 min) discharges for continuous monitoring of up to 15 masses simultaneously. Comparison of the RGA-measured evolution of the H(2)/D(2) isotopic ratio in the exhaust gas to that measured by an energetic neutral particle analyzer in the plasma core provides a way to monitor the evolution of particle balance. RGA monitoring of corrective H(2) injection to maintain proper minority heating is providing a database for improved ion cyclotron resonance heating, potentially with RGA-base feedback control. In very long pulses (>4 min) absence of significant changes in the RGA-monitored, hydrocarbon particle pressures is an indication of proper operation of the actively cooled, carbon-based plasma facing components. Also H(2) could increase due to thermodesorption of overheated plasma facing components.

  13. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect

    Not Available

    1990-12-01

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  14. ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect

    A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

    1998-10-31

    This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500°C to 700°C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800°C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700°C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in

  15. Advanced solar energy conversion. [solar pumped gas lasers

    NASA Technical Reports Server (NTRS)

    Lee, J. H.

    1981-01-01

    An atomic iodine laser, a candidate for the direct solar pumped lasers, was successfully excited with a 4 kW beam from a xenon arc solar simulator, thus proving the feasibility of the concept. The experimental set up and the laser output as functions of operating conditions are presented. The preliminary results of the iodine laser amplifier pumped with the HCP array to which a Q switch for giant pulse production was coupled are included. Two invention disclosures - a laser driven magnetohydrodynamic generator for conversion of laser energy to electricity and solar pumped gas lasers - are also included.

  16. Advanced combustion technologies for gas turbine power plants

    SciTech Connect

    Vandsburger, U.; Roe, L.A.; Desu, S.B.

    1995-12-31

    Objectives are to develop actuators for enhancing the mixing between gas streams, increase combustion stability, and develop hgih-temperature materials for actuators and sensors in combustors. Turbulent kinetic energy maps of an excited jet with co-flow in a cavity with a partially closed exhaust end are given with and without a longitudinal or a transverse acoustic field. Dielectric constants and piezoelectric coefficients were determined for Sr{sub 2}(Nb{sub x}Ta{sub 1-x}){sub 2}O{sub 7} ceramics.

  17. Gas-turbine critical research and advanced technology support project

    NASA Technical Reports Server (NTRS)

    Clark, J. S.; Lowell, C. E.; Niedzwiecki, R. W.; Nainiger, J. J.

    1979-01-01

    The technical progress made during the first 15 months of a planned 40-month project to provide a critical-technology data base for utility gas-turbine systems capable of burning coal-derived fuels is summarized. Tasks were included in the following areas: (1) combustion, to study the combustion of coal-derived fuels and conversion of fuel-bound nitrogen to NOx; (2) materials, to understand and prevent hot corrosion; and (3) system studies, to integrate and guide the other technologies. Significant progress was made.

  18. Advanced H2-HCl Gas Dynamic Laser, Phase 2

    DTIC Science & Technology

    1976-01-01

    available in limited quantities on a special order basis, but synthesis is a straightforward and a well-known process. Three candidate propellant...oxidizers. Both oxides react significantly with HL and HC1 at high temperatures to yield H20 and other contaminants (Ca, Mg, CaOH , MgOH, CaCl, CaCl2, MgCip...quantities. However, synthesis of this compound is straight forward and results in a product of good yield and high purity. It is the best H„ gas generator

  19. Advanced Gas Sensors Using SERS-Activated Waveguides

    NASA Astrophysics Data System (ADS)

    Lascola, Robert; McWhorter, Scott; Murph, Simona Hunyadi

    2010-08-01

    This contribution describes progress towards the development and testing of a functionalized capillary that will provide detection of low-concentration gas-phase analytes through SERS. Measurement inside a waveguide allows interrogation of a large surface area, potentially overcoming the short distance dependence of the SERS effect. The possible use of Raman spectroscopy for gas detection is attractive for IR-inactive molecules or scenarios where infrared technology is inconvenient. However, the weakness of Raman scattering limits the use of the technique to situations where low detection limits are not required or large gas pressures are present. With surface-enhanced Raman spectroscopy (SERS), signal enhancements of 106 are often claimed, and higher values are seen in specific instances. However, most of the examples of SERS analysis are on liquid-phase samples, where the molecular density is high, usually combined with some sort of sample concentration at the surface. Neither of these factors is present in gas-phase samples. Because the laser is focused to a small point in the typical experimental setup, and the spatial extent of the effect above the surface is small (microns), the excitation volume is miniscule. Thus, exceptionally large enhancements are required to generate a signal comparable to that obtained by conventional Raman measurements. A reflective waveguide offers a way to increase the interaction volume of the laser with a SERS-modified surface. The use of a waveguide to enhance classical Raman measurements was recently demonstrated by S.M. Angel and coworkers, who obtained 12- to 30-fold sensitivity improvements for nonabsorbing gases (CO2, CH4) with a silvered capillary (no SERS enhancement). Shi et al.. demonstrated 10-to 100-fold enhancement of aqueous Rhodamine 6G in a capillary coated with silver nanoparticles. They observed enhancements of 10- to 100-fold compared to direct sampling, but this relied on a "double substrate", which required

  20. Sensor for performance monitoring of advanced gas turbines

    NASA Astrophysics Data System (ADS)

    Latvakoski, Harri M.; Markham, James R.; Harrington, James A.; Haan, David J.

    1999-01-01

    Advanced thermal coating materials are being developed for use in the combustor section of high performance turbine engines to allow for higher combustion temperatures. To optimize the use of these thermal barrier coatings (TBC), accurate surface temperature measurements are required to understand their response to changes in the combustion environment. Present temperature sensors, which are based on the measurement of emitted radiation, are not well studied for coated turbine blades since their operational wavelengths are not optimized for the radiative properties of the TBC. This work is concerned with developing an instrument to provide accurate, real-time measurements of the temperature of TBC blades in an advanced turbine engine. The instrument will determine the temperature form a measurement of the radiation emitted at the optimum wavelength, where the TBC radiates as a near-blackbody. The operational wavelength minimizes interference from the high temperature and pressure environment. A hollow waveguide is used to transfer the radiation from the engine cavity to a high-speed detector and data acquisition system. A prototype of this system was successfully tested at an atmospheric burner test facility, and an on-engine version is undergoing testing for installation on a high-pressure rig.

  1. Compatibility of alternative fuels with advanced automotive gas turbine and stirling engines. A literature survey

    NASA Technical Reports Server (NTRS)

    Cairelli, J.; Horvath, D.

    1981-01-01

    The application of alternative fuels in advanced automotive gas turbine and Stirling engines is discussed on the basis of a literature survey. These alternative engines are briefly described, and the aspects that will influence fuel selection are identified. Fuel properties and combustion properties are discussed, with consideration given to advanced materials and components. Alternative fuels from petroleum, coal, oil shale, alcohol, and hydrogen are discussed, and some background is given about the origin and production of these fuels. Fuel requirements for automotive gas turbine and Stirling engines are developed, and the need for certain reseach efforts is discussed. Future research efforts planned at Lewis are described.

  2. Advanced separation technology for flue gas cleanup. Topical report

    SciTech Connect

    Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S.

    1995-01-01

    The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (1) a novel method for regenerating spent SO{sub 2} scrubbing liquor and (2) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors (HFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system will be designed to remove more than 95% of the SO{sub 2} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. The process will generate only marketable by-products. Our approach is to reduce the capital cost by using high-efficiency hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. We will also introduce new process chemistry to minimize traditionally well-known problems with SO{sub 2} and NO{sub x} absorption and desorption. Our novel chemistry for scrubbing NO{sub x} will consist of water-soluble phthalocyanine compounds invented by SRI as well as polymeric forms of Fe{sup ++} complexes similar to traditional NO{sub x} scrubbing media. The final novelty of our approach is the arrangement of the absorbers in cassette (stackable) form so that the NO{sub x} absorber can be on top of the SO{sub x} absorber. This arrangement is possible only because of the high efficiency of the hollow fiber scrubbing devices, as indicated by our preliminary laboratory data. This arrangement makes it possible for the SO{sub 2} and NO{sub x} scrubbing chambers to be separate without incurring the large ducting and gas pressure drop costs necessary if a second conventional absorber vessel were used. Because we have separate scrubbers, we will have separate liquor loops and simplify the chemical complexity of simultaneous SO{sub 2}/NO{sub x} scrubbing.

  3. Analytical investigation of thermal barrier coatings on advanced power generation gas turbines

    NASA Technical Reports Server (NTRS)

    Amos, D. J.

    1977-01-01

    An analytical investigation of present and advanced gas turbine power generation cycles incorporating thermal barrier turbine component coatings was performed. Approximately 50 parametric points considering simple, recuperated, and combined cycles (including gasification) with gas turbine inlet temperatures from current levels through 1644K (2500 F) were evaluated. The results indicated that thermal barriers would be an attractive means to improve performance and reduce cost of electricity for these cycles. A recommended thermal barrier development program has been defined.

  4. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1981-01-01

    An automotive gas turbine powertrain system which, when installed in a 1985 production vehicle (3000 pounds inertia weight), is being developed with a CFDC fuel economy of 42.8 miles per gallon based on Environmental Protection Agency (EPA) test procedures and diesel No. 2 fuel. The AGT-powered vehicle shall give substantially the same overall vehicle driveability and performance as a comparable 1985 production vehicle powered by a conventional spark ignition powertrain system (baseline system). Gaseous emissions and particulate levels less than: NOx = 0.4 gm/mile, HC = 0.41 gm/mile, and CO = 3.4 gm/mile, and a total particulate of 0.2 gm/mile, using the same fuel as used for fuel economy measurements is expected, along with the ability to use a variety of alternate fuels.

  5. Advanced Gas Turbine (AGT) powertrain system initial development report

    NASA Astrophysics Data System (ADS)

    1980-08-01

    The powertrain consists of a single shaft regenerated gas turbine engine utilizing ceramic hot section components, coupled to a slit differential gearbox with an available variable stator torque converter and an available Ford intergral overdrive four-speed automatic transmission. Predicted fuel economy using gasoline fuel over the combined federal driving cycle (CFDC) is 15.3 km/1, which represents a 59% improvement over the spark-ignition-powered baseline vehicle. Using DF2 fuel, CFDC mileage estimates are 17.43 km/1. Zero to 96.6 km/hr acceleration time is 11.9 seconds with a four-second accleration distance of 21.0 m. The ceramic radial turbine rotor is discussed along with the control system for the powertrain.

  6. Swirling midframe flow for gas turbine engine having advanced transitions

    DOEpatents

    Montgomery, Matthew D.; Charron, Richard C.; Rodriguez, Jose L.; Kusters, Bernhard W.; Morrison, Jay A.; Beeck, Alexander R.

    2016-12-27

    A gas turbine engine can-annular combustion arrangement (10), including: an axial compressor (82) operable to rotate in a rotation direction (60); a diffuser (100, 110) configured to receive compressed air (16) from the axial compressor; a plenum (22) configured to receive the compressed air from the diffuser; a plurality of combustor cans (12) each having a combustor inlet (38) in fluid communication with the plenum, wherein each combustor can is tangentially oriented so that a respective combustor inlet is circumferentially offset from a respective combustor outlet in a direction opposite the rotation direction; and an airflow guiding arrangement (80) configured to impart circumferential motion to the compressed air in the plenum in the direction opposite the rotation direction.

  7. Advanced Gas Turbine (AGT) powertrain system initial development report

    NASA Technical Reports Server (NTRS)

    1980-01-01

    The powertrain consists of a single shaft regenerated gas turbine engine utilizing ceramic hot section components, coupled to a slit differential gearbox with an available variable stator torque converter and an available Ford intergral overdrive four-speed automatic transmission. Predicted fuel economy using gasoline fuel over the combined federal driving cycle (CFDC) is 15.3 km/1, which represents a 59% improvement over the spark-ignition-powered baseline vehicle. Using DF2 fuel, CFDC mileage estimates are 17.43 km/1. Zero to 96.6 km/hr acceleration time is 11.9 seconds with a four-second accleration distance of 21.0 m. The ceramic radial turbine rotor is discussed along with the control system for the powertrain.

  8. Development of advanced inert-gas ion thrusters

    NASA Technical Reports Server (NTRS)

    Poeschel, R. L.

    1983-01-01

    Inert gas ion thruster technology offers the greatest potential for providing high specific impulse, low thrust, electric propulsion on large, Earth orbital spacecraft. The development of a thruster module that can be operated on xenon or argon propellant to produce 0.2 N of thrust at a specific impulse of 3000 sec with xenon propellant and at 6000 sec with argon propellant is described. The 30 cm diameter, laboratory model thruster is considered to be scalable to produce 0.5 N thrust. A high efficiency ring cusp discharge chamber was used to achieve an overall thruster efficiency of 77% with xenon propellant and 66% with argon propellant. Measurements were performed to identify ion production and loss processes and to define critical design criteria (at least on a preliminary basis).

  9. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1984-01-01

    Rotor dynamic instability investigations were conducted. Forward ball bearing hydraulic mount configurations were tested with little effect. Trial assembly of S/N 002 ceramic engine was initiated. Impeller design activities were completed on the straight line element (SLE) blade definition to address near-net-shape powder metal die forging. Performance characteristics of the Baseline Test 2A impeller were closely preserved. The modified blading design has been released for tooling procurement. Developmental testing of the diffusion flame combustor (DFC) for initial use in the S/N 002 2100 F ceramic structures engine was completed. A natural gas slave preheater was designed and fabricated. Preliminary regenerator static seal rig testing showed a significant reduction in leakage and sensitivity to stack height. Ceramic screening tests were completed and two complete sets of ceramic static structures were qualified for engine testing. Efforts on rotor dynamics development to resolve subsynchronous motion were continued.

  10. Development of advanced hot-gas desulfurization sorbents

    SciTech Connect

    Jothimurugesan, K.; Adeyiga, A.A.; Gangwal, S.K.

    1995-11-01

    The objective of this study is to develop hot-gas cleanup sorbents for relatively lower temperature application, with emphasis on the temperature applications, with emphasis on the temperature range from 343--538 C. A number of formulations will be prepared and screened for testing in a 1/2-inch fixed bed reactor at high pressure (1 to 20 atm) and high temperatures using simulated coal-derived fuel-gases. Screening criteria will include, chemical reactivity, stability, and regenerability over the temperature range of 343 C to 538 C. Each formulation will be tested for up to 5 cycles of absorption and regeneration. To prevent sulfation, catalyst additives will be investigated, which would promote a lower ignition of the regeneration. Selected superior formulation will be tested for long term (up to at least 30 cycles) durability and chemical reactivity in the reactor. Zinc oxide based sorbents were prepared and characterized as fresh, sulfided, and regenerated sorbents. Results are presented.

  11. Advanced Gas Turbine (AGT) powertrain system development for automotive applications

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Preliminary layouts were made for the exhaust system, air induction system, and battery installation. Points of interference were identified and resolved by altering either the vehicle or engine designs. An engine general arrangement evolved to meet the vehicle engine compartment constraints while minimizing the duct pressure losses and the heat rejection. A power transfer system (between gasifier and power turbines) was developed to maintain nearly constant temperatures throughout the entire range of engine operation. An advanced four speed automatic transmission was selected to be used with the engine. Performance calculations show improvements in component efficiencies and an increase in fuel economy. A single stage centrifugal compressor design was completed and released for procurement. Gasifier turbine, power turbine, combustor, generator, secondary systems, materials, controls, and transmission development are reported.

  12. Advanced Gas Turbine (AGT) powertrain system development for automotive applications report

    NASA Technical Reports Server (NTRS)

    1984-01-01

    This report describes progress and work performed during January through June 1984 to develop technology for an Advanced Gas Turbine (AGT) engine for automotive applications. Work performed during the first eight periods initiated design and analysis, ceramic development, component testing, and test bed evaluation. Project effort conducted under this contract is part of the DOE Gas Turbine Highway Vehicle System Program. This program is oriented at providing the United States automotive industry the high-risk long-range techology necessary to produce gas turbine engines for automobiles with reduced fuel consumption and reduced environmental impact. Technology resulting from this program is intended to reach the marketplace by the early 1990s.

  13. Advanced Gas Turbine (AGT): Power-train system development

    NASA Technical Reports Server (NTRS)

    Helms, H. E.; Johnson, R. A.; Gibson, R. K.; Smith, L. B.

    1983-01-01

    Technical work on the design and effort leading to the testing of a 74.5 kW (100 hp) automotive gas turbine is described. The general effort was concentrated on building an engine for test starting in July. The buildup progressed with only routine problems and the engine was delivered to the test stand 9 July. In addition to the engine build effort, work continued in selected component areas. Ceramic turbine parts were built and tested. Burst tests of ceramic rotors show strengths are approaching that achieved in test bars; proof testing is required for acceptable strength ceramic vanes. Over 25 hours was accumulated on the combustor rig in three test modes: pilot nozzle only, start nozzle, and main nozzle operation. Satisfactory ignition was achieved for a wide range of starting speeds and the lean blowout limit was as low as 0.06 kg/b (0.14 lb/hr). Lean blowout was more a function of nozzle atomization than fuel/air ratio. A variety of cycle points were tested. Transition from start nozzle flow to main nozzle flow was done manually without difficulty. Regenerator parts were qualification tested without incident and the parts were assembled on schedule. Rig based performance matched first build requirements. Repeated failures in the harmonic drive gearbox during rig testing resulted in that concept being abandoned for an alternate scheme.

  14. Recent Advances in Water Analysis with Gas Chromatograph Mass Spectrometers

    NASA Technical Reports Server (NTRS)

    MacAskill, John A.; Tsikata, Edem

    2014-01-01

    We report on progress made in developing a water sampling system for detection and analysis of volatile organic compounds in water with a gas chromatograph mass spectrometer (GCMS). Two approaches are described herein. The first approach uses a custom water pre-concentrator for performing trap and purge of VOCs from water. The second approach uses a custom micro-volume, split-splitless injector that is compatible with air and water. These water sampling systems will enable a single GC-based instrument to analyze air and water samples for VOC content. As reduced mass, volume, and power is crucial for long-duration, manned space-exploration, these water sampling systems will demonstrate the ability of a GCMS to monitor both air and water quality of the astronaut environment, thereby reducing the amount of required instrumentation for long duration habitation. Laboratory prototypes of these water sampling systems have been constructed and tested with a quadrupole ion trap mass spectrometer as well as a thermal conductivity detector. Presented herein are details of these water sampling system with preliminary test results.

  15. Advanced Low NOx Combustors for Aircraft Gas Turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; White, D. J.; Shekleton, J. R.; Butze, H. F.

    1976-01-01

    A test rig program was conducted with the objective of evaluating and minimizing the exhaust emissions, in particular NOx, of two advanced aircraft combustor concepts at a simulated high-altitude cruise condition. The two pre-mixed, lean-reaction designs are known as the Jet Induced Circulation (JIC) combustor and the Vortex Air Blast (VAB) combustor and were rig tested in the form of reverse flow can combustors in the 0.13 ni (5.0 in. ) size range. Various configuration modifications were applied to the JIC and VAB combustor designs in an effort to reduce the emissions levels. The VAB combustor demonstrated a NOx level of 1.11 gm NO2/kg fuel with essentially 100 percent combustion efficiency at the simulated cruise combustor condition of 507 kPa (5 atm), 833 K (1500 R), inlet pressure and temperature respectively, and 1778 K (3200 R) outlet temperature on Jet-Al fuel. These configuration screening tests were carried out on essentially reaction zones only, in order to simplify the construction and modification of the combustors and to uncouple any possible effects on the emissions produced by the dilution flow. Tests were also conducted however at typical engine idle conditions on both combustors equipped with dilution ports in order to better define the problem areas involved in the operation of such concepts over a complete engine operational envelope. Versions of variable-geometry, JIC and VAB annular combustors are proposed.

  16. Life prediction of advanced materials for gas turbine application

    SciTech Connect

    Zamrik, S.Y.; Ray, A.; Koss, D.A.

    1995-10-01

    Most of the studies on the low cycle fatigue life prediction have been reported under isothermal conditions where the deformation of the material is strain dependent. In the development of gas turbines, components such as blades and vanes are exposed to temperature variations in addition to strain cycling. As a result, the deformation process becomes temperature and strain dependent. Therefore, the life of the component becomes sensitive to temperature-strain cycling which produces a process known as {open_quotes}thermomechanical fatigue, or TMF{close_quotes}. The TMF fatigue failure phenomenon has been modeled using conventional fatigue life prediction methods, which are not sufficiently accurate to quantitatively establish an allowable design procedure. To add to the complexity of TMF life prediction, blade and vane substrates are normally coated with aluminide, overlay or thermal barrier type coatings (TBC) where the durability of the component is dominated by the coating/substrate constitutive response and by the fatigue behavior of the coating. A number of issues arise from TMF depending on the type of temperature/strain phase cycle: (1) time-dependent inelastic behavior can significantly affect the stress response. For example, creep relaxation during a tensile or compressive loading at elevated temperatures leads to a progressive increase in the mean stress level under cyclic loading. (2) the mismatch in elastic and thermal expansion properties between the coating and the substrate can lead to significant deviations in the coating stress levels due to changes in the elastic modulii. (3) the {open_quotes}dry{close_quotes} corrosion resistance coatings applied to the substrate may act as primary crack initiation sites. Crack initiation in the coating is a function of the coating composition, its mechanical properties, creep relaxation behavior, thermal strain range and the strain/temperature phase relationship.

  17. Advanced gas turbine systems research. Quarterly report, October--December 1995

    SciTech Connect

    1996-01-01

    This report summarizes the major accomplishments and reports issued by Advanced Gas Turbine Systems Research (AGTSR) during October 1, 1995 to December 31, 1995, reports on changes in the AGTSR membership, describes 1993, 1994 and 1995 subcontract progress, third combustion workshop, first combustion specialty meeting, materials workshop, industrial internship, research topics highlighted, and seminar sponsorship.

  18. Advanced combustion technologies for gas turbine power plants

    SciTech Connect

    Vandsburger, U.; Desu, S.B.; Roe, L.A.

    1995-10-01

    During the second half of fiscal year 1995 progress was made in all three funded subject areas of the project as well as in a new area. Work in the area of mixing and combustion management through flow actuation was transferred into an enclosed facility. Jet mixing in a ducted co-flow was examined. The same jets were also subjected to a strong acoustic field established in the duct. Excitation of the jet with static spatial modes was shown to be effective even in the presence of co-flow and the acoustic field. Only when a wall is placed at the jet exit plane did the acoustic field dominate the jet dispersion (as expected due to reflective boundary conditions and the jet shear layer receptivity). This case is, however, not the most relevant to gas turbine combustors since it precludes co-flow. In the area of combustor testing, the design, fabrication, and assembly of a modular combustor test rig for project has been completed at the University of Arkansas. In the area of high temperature piezoceramic actuator materials development, Sr{sub 2}(Nb{sub x}Ta{sub 1-x}){sub 2}O{sub 7} powders have been synthesized, and bulk samples and thick films sintered. These materials have a curie temperature of about 1400{degrees}C compared with 300{degrees}C for the commercially available PZT. While at room temperature the new materials show a piezoelectric constant (d{sub 33}) which is a factor of 100 lower than PZT, at high temperatures they can exhibit significant action. A new area of non-linear, neural-net based, controllers for mixing and combustion control has been added during the second contract year. This work is not funded by the contract. Significant progress was made in this area. Neural nets with up to 15 neurons in the hidden layer were trained with experimental data and also with data generated using linear stability theory. System ID was performed successfully. The network was then used to predict the behavior of jets excited at other modes not used for the training.

  19. Advanced Systems development: New materials/systems for interior gas distribution. Phase 1. Advanced Systems Specifications. Final report, January 1989-May 1991

    SciTech Connect

    Peters, E.; Scocca, M.; Topping, R.

    1991-05-01

    As part of the Gas Research Institute's overall program to develop safe, low cost, semi rigid gas piping systems, their project is aimed at identifying and evaluating advanced high performance materials and components suitable for interior gas piping by the year 2000 and beyond. The report summarizes the results of Phase I - Advanced Systems Specifications Studies, which developed performance criteria, installed cost goals and a database of promising new metallic and non-metallic piping materials. Several candidate materials and systems are identified as well as the current status of gas monitoring, sensing and control technologies.

  20. Materials and structural aspects of advanced gas-turbine helicopter engines

    NASA Technical Reports Server (NTRS)

    Freche, J. C.; Acurio, J.

    1979-01-01

    The key to improved helicopter gas turbine engine performance lies in the development of advanced materials and advanced structural and design concepts. The modification of the low temperature components of helicopter engines (such as the inlet particle separator), the introduction of composites for use in the engine front frame, the development of advanced materials with increased use-temperature capability for the engine hot section, can result in improved performance and/or decreased engine maintenance cost. A major emphasis in helicopter engine design is the ability to design to meet a required lifetime. This, in turn, requires that the interrelated aspects of higher operating temperatures and pressures, cooling concepts, and environmental protection schemes be integrated into component design. The major material advances, coatings, and design life-prediction techniques pertinent to helicopter engines are reviewed; the current state-of-the-art is identified; and when appropriate, progress, problems, and future directions are assessed.

  1. Government/industry partnership: A revolutionary approach in global leadership of advanced gas turbines

    SciTech Connect

    Ali, S.A.; Zeh, C.M.

    1996-02-01

    The U.S. Department of Energy (DOE) has established a government/industry partnership program to greatly improve the capabilities of U.S. gas turbine technology. A new and challenging program named the Advanced Turbine Systems Program (ATS) has been initiated by DOE. The technical and business objectives of this initiative are to challenge the bounds of high performance capabilities of gas turbines, meet stringent environmental requirements, and produce lower cost electric power and cogeneration steam. This program will also yield greater societal benefits through continued expansion of high skilled U.S. jobs and export of U.S. products world wide. A progress report on the ATS program pertaining to program status at DOE will be presented and reviewed in this paper. A preliminary design of an industrial advanced turbine system configuration will also be outlined in the paper. The technical challenges; advanced critical technologies incorporation, analytical and experimental solutions, and test results of an advanced gas turbine meeting the DOE goals will be described and discussed.

  2. Review: gas-phase ion chemistry of the noble gases: recent advances and future perspectives.

    PubMed

    Grandinetti, Felice

    2011-01-01

    This review article surveys recent experimental and theoretical advances in the gas-phase ion chemistry of the noble gases. Covered issues include the interaction of the noble gases with metal and non-metal cations, the conceivable existence of covalent noble-gas anions, the occurrence of ion-molecule reactions involving singly-charged xenon cations, and the occurrence of bond-forming reactions involving doubly-charged cations. Research themes are also highlighted, that are expected to attract further interest in the future.

  3. A technology development summary for the AGT101 advanced gas turbine program

    NASA Technical Reports Server (NTRS)

    Boyd, Gary L.; Kidwell, James R.; Kreiner, Daniel M.

    1987-01-01

    A summary is presented of significant technology developments that have been made in the AGT101 advanced gas turbine program. The AGT101 design features are reviewed, and the power section testing and results are addressed in detail. The results of component testing and evaluation are described for the compressor, turbine, regenerator, and foil bearing. Ceramic component development is discussed, including that of the static seal, turbine shroud seal, regenerator shield planar seal, regenerator shield piston ring, stator rig, ceramic combustor, and turbine rotor. Important areas to be addressed by the Advanced Turbine Technology Applications Project now in the planning stage at DOE and NASA are briefly reviewed.

  4. Advancement and application of gas chromatography isotope ratio mass spectrometry techniques for atmospheric trace gas analysis

    NASA Astrophysics Data System (ADS)

    Giebel, Brian M.

    2011-12-01

    The use of gas chromatography isotope ratio mass spectrometry (GC-IRMS) for compound specific stable isotope analysis is an underutilized technique because of the complexity of the instrumentation and high analytical costs. However stable isotopic data, when coupled with concentration measurements, can provide additional information on a compounds production, transformation, loss, and cycling within the biosphere and atmosphere. A GC-IRMS system was developed to accurately and precisely measure delta13C values for numerous oxygenated volatile organic compounds having natural and anthropogenic sources. The OVOCs include methanol, ethanol, acetone, methyl ethyl ketone, 2-pentanone, and 3-pentanone. Guided by the requirements for analysis of trace components in air, the GC-IRMS system was developed with the goals of increasing sensitivity, reducing dead-volume and peak band broadening, optimizing combustion and water removal, and decreasing the split ratio to the IRMS. The technique relied on a two-stage preconcentration system, a low-volume capillary reactor and water trap, and a balanced reference gas delivery system. Measurements were performed on samples collected from two distinct sources (i.e. biogenic and vehicle emissions) and ambient air collected from downtown Miami and Everglades National Park. However, the instrumentation and the method have the capability to analyze a variety of source and ambient samples. The measured isotopic signatures that were obtained from source and ambient samples provide a new isotopic constraint for atmospheric chemists and can serve as a new way to evaluate their models and budgets for many OVOCs. In almost all cases, OVOCs emitted from fuel combustion were enriched in 13C when compared to the natural emissions of plants. This was particularly true for ethanol gas emitted in vehicle exhaust, which was observed to have a uniquely enriched isotopic signature that was attributed to ethanol's corn origin and use as an alternative

  5. System definition and analysis gas-fired industrial advanced turbine systems

    SciTech Connect

    Holloway, G.M.

    1997-05-01

    The objective is to define and analyze an engine system based on the gas fuel Advanced Turbine from Task 3. Using the cycle results of Task 3, a technical effort was started for Task 6 which would establish the definition of the engine flowpath and the key engine component systems. The key engine systems are: gas turbine engine overall flowpath; booster (low pressure compressor); intercooler; high pressure compressor; combustor; high pressure turbine; low pressure turbine and materials; engine system packaging; and power plant configurations. The design objective is to use the GE90 engine as the platform for the GE Industrial Advanced Turbine System. This objective sets the bounds for the engine flowpath and component systems.

  6. Energy and cost saving results for advanced technology systems from the Cogeneration Technology Alternatives Study (CTAS)

    NASA Technical Reports Server (NTRS)

    Sagerman, G. D.; Barna, G. J.; Burns, R. K.

    1979-01-01

    An overview of the organization and methodology of the Cogeneration Technology Alternatives Study is presented. The objectives of the study were to identify the most attractive advanced energy conversion systems for industrial cogeneration applications in the future and to assess the advantages of advanced technology systems compared to those systems commercially available today. Advanced systems studied include steam turbines, open and closed cycle gas turbines, combined cycles, diesel engines, Stirling engines, phosphoric acid and molten carbonate fuel cells and thermionics. Steam turbines, open cycle gas turbines, combined cycles, and diesel engines were also analyzed in versions typical of today's commercially available technology to provide a base against which to measure the advanced systems. Cogeneration applications in the major energy consuming manufacturing industries were considered. Results of the study in terms of plant level energy savings, annual energy cost savings and economic attractiveness are presented for the various energy conversion systems considered.

  7. Advanced gas turbine systems research. Quarterly report, January--March, 1994

    SciTech Connect

    Not Available

    1994-04-01

    The Department of Energy is sponsoring a series of studies related to advanced gas turbine systems. Ten universities participated in the first round studies, and an additional 13 studies have been funded this year. The five areas being covered are heat transfer, aerodynamics, materials, combustion, and dynamics. Summaries are given for the 6-month progress on the 1993 subcontract studies and on the planned research for the new subcontract studies.

  8. Infrared spectroscopy study of electrochromic nanocrystalline tungsten oxide films made by reactive advanced gas deposition

    NASA Astrophysics Data System (ADS)

    Solis, J. L.; Hoel, A.; Lantto, V.; Granqvist, C. G.

    2001-03-01

    Nanocrystalline W oxide films were produced by advanced reactive gas deposition. The material consisted of ˜6 nm diameter tetragonal crystallites, as found from x-ray diffraction and electron microscopy. Optoelectrochemical measurements demonstrated electrochromism upon Li+ intercalation/deintercalation, and infrared absorption spectroscopy gave clear evidence for longitudinal and transversal optical modes being modified following the lithiation. Our data were consistent with ionic transport predominantly in disordered grain boundaries and intercrystalline regions and with electrochromism being associated with small polaron formation.

  9. High performance fibers for structurally reliable metal and ceramic composites. [advanced gas turbine engine materials

    NASA Technical Reports Server (NTRS)

    Dicarlo, J. A.

    1984-01-01

    Very few of the commercially available high performance fibers with low densities, high Young's moduli, and high tensile strengths possess all the necessary property requirements for providing either metal matrix composites (MMC) or ceramic matrix composites (CMC) with high structural reliability. These requirements are discussed in general and examples are presented of how these property guidelines are influencing fiber evaluation and improvement studies at NASA aimed at developing structurally reliable MMC and CMC for advanced gas turbine engines.

  10. THERMODYNAMIC ANALYSIS OF OPEN-CYCLE MULTISHAFT POWER SYSTEM WITH MULTIPLE REHEAT AND INTERCOOL

    NASA Technical Reports Server (NTRS)

    Glassman, A. J.

    1994-01-01

    This program computes the specific power output, specific fuel consumption, and cycle efficiency functions of turbine-inlet temperature, compressor pressure ratio, and component performance factors for power systems having any number of shafts up to a maximum of five. On each shaft there can be any number of compressors and turbines up to a maximum of five each, along with any specified number of intervening intercoolers and reheaters. A recuperator can be included in the system and turbine coolant flow can be accounted for. The combustion-gas thermodynamic properties are valid for any fuel consisting of hydrogen and/or carbon only. The program should be used with maximum temperatures no higher than about 2000 K (3140 degrees Fahrenheit) because molecular dissociation is not included in the stoichiometry. Improvements in cycle performance resulting from the use of intercooling, reheating, and recuperation can also be determined. This program has been implemented on the IBM 7094.

  11. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  12. A thermodynamic approach for advanced fuels of gas-cooled reactors

    NASA Astrophysics Data System (ADS)

    Guéneau, C.; Chatain, S.; Gossé, S.; Rado, C.; Rapaud, O.; Lechelle, J.; Dumas, J. C.; Chatillon, C.

    2005-09-01

    For both high temperature reactor (HTR) and gas cooled fast reactor (GFR) systems, the high operating temperature in normal and accidental conditions necessitates the assessment of the thermodynamic data and associated phase diagrams for the complex system constituted of the fuel kernel, the inert materials and the fission products. A classical CALPHAD approach, coupling experiments and thermodynamic calculations, is proposed. Some examples of studies are presented leading with the CO and CO 2 gas formation during the chemical interaction of [UO 2± x/C] in the HTR particle, and the chemical compatibility of the couples [UN/SiC], [(U, Pu)N/SiC], [(U, Pu)N/TiN] for the GFR system. A project of constitution of a thermodynamic database for advanced fuels of gas-cooled reactors is proposed.

  13. Completion of the first NGNP Advanced Gas Reactor Fuel Irradiation Experiment, AGR-1, in the Advanced Test Reactor

    SciTech Connect

    Blaine Grover; John Maki; David Petti

    2010-10-01

    The United States Department of Energy’s Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The ATR has a long history of irradiation testing in support of reactor development and the INL has been designated as the United States Department of Energy’s lead laboratory for nuclear energy development. The ATR is one of the world’s premiere test reactors for performing long term, high flux, and/or large volume irradiation test programs. These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and completed a very successful irradiation in early November 2009. The design of AGR-1 test train and support systems used to monitor and control the experiment during

  14. Investigation of austenitic alloys for advanced heat recovery and hot gas cleanup systems

    SciTech Connect

    Swindeman, R.W.; Ren, W.

    1996-06-01

    The objective of the research is to provide databases and design criteria to assist in the selection of optimum alloys for construction of components needed to contain process streams in advanced heat recovery and hot-gas cleanup systems. Typical components include: steam line piping and superheater tubing for low emission boilers (600 to 700{degrees}C), heat exchanger tubing for advanced steam cycles and topping cycle systems (650 to 800{degrees}C), foil materials for recuperators, on advanced turbine systems (700 to 750{degrees}C), and tubesheets for barrier filters, liners for piping, cyclones, and blowback system tubing for hot-gas cleanup systems (850 to 1000{degrees}C). The materials being examined fall into several classes, depending on which of the advanced heat recovery concepts is of concern. These classes include martensitic steels for service to 650{degrees}C, lean stainless steels and modified 25Cr-30Ni steels for service to 700{degrees}C, modified 25Cr-20Ni steels for service to 900{degrees}C, and high Ni-Cr-Fe or Ni-Cr-Co-Fe alloys for service to 1000{degrees}C.

  15. Do open-cycle hatcheries relying on tourism conserve sea turtles? Sri Lankan developments and economic-ecological considerations.

    PubMed

    Tisdell, Clem; Wilson, Clevo

    2005-04-01

    By combining economic analysis of markets with ecological parameters, this article considers the role that tourism-based sea turtle hatcheries (of an open-cycle type) can play in conserving populations of sea turtles. Background is provided on the nature and development of such hatcheries in Sri Lanka. The modeling facilitates the assessment of the impacts of turtle hatcheries on the conservation of sea turtles and enables the economic and ecological consequences of tourism, based on such hatcheries, to be better appreciated. The results demonstrate that sea turtle hatcheries serving tourists can make a positive contribution to sea turtle conservation, but that their conservation effectiveness depends on the way they are managed. Possible negative effects are also identified. Economic market models are combined with turtle population survival relationships to predict the conservation impact of turtle hatcheries and their consequence for the total economic value obtained from sea turtle populations.

  16. Advances in Inhalation Gas Dosimetry for Derivation of a Reference Concentration (RfC) and Use in Risk Assessment

    EPA Science Inventory

    This status report provides a review of advances in the state of the science for interspecies inhalation gas dosimetry related to extrathoracic (ET) or upper respiratory tract (URT), tracheobronchial (TB), pulmonary (PU), and extrarespiratory (systemic, SYS) effects.

  17. Integration of magnetic bearings in the design of advanced gas turbine engines

    SciTech Connect

    Storace, A.F.; Sood, D.; Lyons, J.P.; Preston, M.A.

    1995-10-01

    Active magnetic bearings provide revolutionary advantages for gas turbine engine rotor support. These advantages include tremendously improved vibration and stability characteristics, reduced power loss, improved reliability, fault tolerance, and greatly extended bearing service life. The marriage of these advantages with innovative structural network design and advanced materials utilization will permit major increases in thrust-to-weight performance and structural efficiency for future gas turbine engines. However, obtaining the maximum payoff requires two key ingredients. The first is the use of modern magnetic bearing technologies such as innovative digital control techniques, high-density power electronics, high-density magnetic actuators, fault-tolerant system architecture, and electronic (sensorless) position estimation. This paper describes these technologies and the test hardware currently in place for verifying the performance of advanced magnetic actuators, power electronics, and digital controls. The second key ingredient is to go beyond the simple replacement of rolling element bearings with magnetic bearings by incorporating magnetic bearings as an integral part of the overall engine design. This is analogous to the proper approach to designing with composites, whereby the designer tailors the geometry and load-carrying function of the structural system or component for the composite instead of simply substituting composites in a design originally intended for metal material. This paper describes methodologies for the design integration of magnetic bearings in gas turbine engines.

  18. Melt Infiltrated Ceramic Matrix Composites for Shrouds and Combustor Liners of Advanced Industrial Gas Turbines

    SciTech Connect

    Gregory Corman; Krishan Luthra; Jill Jonkowski; Joseph Mavec; Paul Bakke; Debbie Haught; Merrill Smith

    2011-01-07

    This report covers work performed under the Advanced Materials for Advanced Industrial Gas Turbines (AMAIGT) program by GE Global Research and its collaborators from 2000 through 2010. A first stage shroud for a 7FA-class gas turbine engine utilizing HiPerComp{reg_sign}* ceramic matrix composite (CMC) material was developed. The design, fabrication, rig testing and engine testing of this shroud system are described. Through two field engine tests, the latter of which is still in progress at a Jacksonville Electric Authority generating station, the robustness of the CMC material and the shroud system in general were demonstrated, with shrouds having accumulated nearly 7,000 hours of field engine testing at the conclusion of the program. During the latter test the engine performance benefits from utilizing CMC shrouds were verified. Similar development of a CMC combustor liner design for a 7FA-class engine is also described. The feasibility of using the HiPerComp{reg_sign} CMC material for combustor liner applications was demonstrated in a Solar Turbines Ceramic Stationary Gas Turbine (CSGT) engine test where the liner performed without incident for 12,822 hours. The deposition processes for applying environmental barrier coatings to the CMC components were also developed, and the performance of the coatings in the rig and engine tests is described.

  19. Measurement of gas bremsstrahlung from the insertion device beamlines of the advanced photon source

    SciTech Connect

    Pisharody, M.; Job, P.K.; Magill, S.

    1997-03-01

    High energy electron storage rings generate energetic bremsstrahlung photons through radiative interaction of the electrons (or positrons) with the residual gas molecules inside the storage ring. The resulting radiation exits at an average emittance angle of (m{sub 0}c{sub 2}/E) radian with respect to the electron beam path, where m{sub 0}c{sup 2} is the rest mass of E the electron and E its kinetic energy. Thus, at straight sections of the storage rings, moving electrons will produce a narrow and intense monodirectional photon beam. At synchrotron radiation facilities, where beamlines are channeled out of the storage ring, a continuous gas bremsstrahlung spectrum, with a maximum energy of the electron beam, will be present. There are a number of compelling reasons that a measurement of the bremsstrahlung characteristics be conducted at the Advanced Photon Source (APS) storage ring. Although the number of residual gas molecules present in the storage ring at typical nTorr vacuum is low, because of the long straight paths of the electrons in the storage ring at APS, significant production of bremsstrahlung will be produced. This may pose a radiation hazard. It is then imperative that personnel be shielded from dose rates due to this radiation. There are not many measurements available for gas bremsstrahlung, especially for higher electron beam energies. The quantitative estimates of gas bremsstrahlung from storage rings as evaluated by Monte Carlo codes also have several uncertainties. They are in general calculated for air at atmospheric pressure, the results of which are then extrapolated to typical storage ring vacuum values (of the order of 10{sup -9} Torr). Realistically, the actual pressure profile can vary inside the narrow vacuum chamber. Also, the actual chemical composition of the residual gas inside the storage ring is generally different from that of air.

  20. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    SciTech Connect

    Wang, M. Q.

    1998-12-16

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  1. Gas-phase advanced oxidation for effective, efficient in situ control of pollution.

    PubMed

    Johnson, Matthew S; Nilsson, Elna J K; Svensson, Erik A; Langer, Sarka

    2014-01-01

    In this article, gas-phase advanced oxidation, a new method for pollution control building on the photo-oxidation and particle formation chemistry occurring in the atmosphere, is introduced and characterized. The process uses ozone and UV-C light to produce in situ radicals to oxidize pollution, generating particles that are removed by a filter; ozone is removed using a MnO2 honeycomb catalyst. This combination of in situ processes removes a wide range of pollutants with a comparatively low specific energy input. Two proof-of-concept devices were built to test and optimize the process. The laboratory prototype was built of standard ventilation duct and could treat up to 850 m(3)/h. A portable continuous-flow prototype built in an aluminum flight case was able to treat 46 m(3)/h. Removal efficiencies of >95% were observed for propane, cyclohexane, benzene, isoprene, aerosol particle mass, and ozone for concentrations in the range of 0.4-6 ppm and exposure times up to 0.5 min. The laboratory prototype generated a OH(•) concentration derived from propane reaction of (2.5 ± 0.3) × 10(10) cm(-3) at a specific energy input of 3 kJ/m(3), and the portable device generated (4.6 ± 0.4) × 10(9) cm(-3) at 10 kJ/m(3). Based on these results, in situ gas-phase advanced oxidation is a viable control strategy for most volatile organic compounds, specifically those with a OH(•) reaction rate higher than ca. 5 × 10(-13) cm(3)/s. Gas-phase advanced oxidation is able to remove compounds that react with OH and to control ozone and total particulate mass. Secondary pollution including formaldehyde and ultrafine particles might be generated, depending on the composition of the primary pollution.

  2. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  3. Applications of Gas Imaging Micro-Well Detectors to an Advanced Compton Telescope

    NASA Technical Reports Server (NTRS)

    Bloser, P. F.; Hunter, S. D.; Ryan, J. M.; McConnell, M. L.; Miller, R. S.; Jackson, T. N.; Bai, B.; Jung, S.

    2003-01-01

    We present a concept for an Advanced Compton Telescope (ACT) based on the use of pixelized gas micro-well detectors to form a three-dimensional electron track imager. A micro-well detector consists of an array of individual micro-patterned proportional counters opposite a planar drift electrode. When combined with thin film transistor array readouts, large gas volumes may be imaged with very good spatial and energy resolution at reasonable cost. The third dimension is determined by timing the drift of the ionization electrons. The primary advantage of this approach is the excellent tracking of the Compton recoil electron that is possible in a gas volume. Such good electron tracking allows us to reduce the point spread function of a single incident photon dramatically, greatly improving the imaging capability and sensitivity. The polarization sensitivity, which relies on events with large Compton scattering angles, is particularly enhanced. We describe a possible ACT implementation of this technique, in which the gas tracking volume is surrounded by a CsI calorimeter, and present our plans to build and test a small prototype over the next three years.

  4. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  5. Characterization of open-cycle coal-fired MHD generators. 14th/15th quarterly technical progress report, February 1-July 31, 1980

    SciTech Connect

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Bien, F.; Dvore, D.; Unkel, W.; Stewart, G.

    1980-09-01

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort as detailed. In addition, studies related to understanding arcing phenomena in the vicinity of an anode are reported.

  6. Characterization of open-cycle coal-fired MHD generators. 16th quarterly technical progress report, December 16, 1980-March 31, 1981

    SciTech Connect

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Dvore, D.; Freedman, A.; Stanton, A.; Stewart, G.

    1981-05-01

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort is reported. In addition, studies related to understanding arcing and corrosion phenomena in the vicinity of an anode are reported.

  7. Performance evaluation of single-glazed and double glazed collectors/regenerators for an open cycle absorption solar cooling system

    SciTech Connect

    Yang, R.; Wang, P.L.

    1998-07-01

    Feasibility for an open-cycle absorption solar cooling system operated in Kaohsiung, Taiwan is studied via a computer simulation program using previous obtained experimental correlations for the collector/regenerator (C/R) performance and the TMY data of Kaohsiung, Taiwan. Three C/R models are considered in this study. They are the natural and the forced convection single-glazed Cs/Rs and the forced convection double-glazed C/R. The effects of the C/R area, the C/R solution flow rate, the solution storage, the chilled water temperature and the daily cooling demand on the system performance in terms of seasonal solar fraction are studied and discussed. The results show that the solar C/R is the key component of the cooling system and the open-cycle absorption system is a sound solar cooling system. It is shown that the double glazed forced convection C/R gives a better system performance. The simulation study is to evaluate the seasonal solar fraction, which is defined as F=(solar cooling load)/(total cooling load) Firstly, all three C/R models are simulated under the base case conditions. The seasonal averaged solar fraction for three models are found to be 0.7, 0.75 and 0.79, respectively, while the corresponding seasonal averaged C/R efficiencies are 15.7%, 18.4% and 20.6%. The double-glazed forced convection system performs better than the other two systems. This is consistent with the results of previous experimental studies for the C/R. A nearly linear relationship between the C/R efficiency and the solar fraction is shown. The solar fraction increases slightly with the solution storage volume for the natural convection case, but it is much more sensitive to the solution storage for the forced convection system. The solar fraction is relatively insensitive to the C/R area after a critical value is reached. A similar dependence is also found in other solar absorption air conditioning system alternatives.

  8. The Next Generation Nuclear Plant/Advanced Gas Reactor Fuel Irradiation Experiments in the Advanced Test Reactor

    SciTech Connect

    S. Blaine Grover

    2009-09-01

    The United States Department of Energy’s Next Generation Nuclear Plant (NGNP) Program will be irradiating eight separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The ATR has a long history of irradiation testing in support of reactor development and the INL has been designated as the new United States Department of Energy’s lead laboratory for nuclear energy development. The ATR is one of the world’s premiere test reactors for performing long term, high flux, and/or large volume irradiation test programs. These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next ten years to demonstrate and qualify new particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006, and the second experiment (AGR-2) is currently in the design phase. The design of test trains, as well as the support systems and fission product monitoring system that will monitor and control the experiment during irradiation will be discussed. In

  9. Advanced Underground Gas Storage Concepts: Refrigerated-Mined Cavern Storage, Final Report

    SciTech Connect

    1998-09-30

    Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. Competing methods include LNG facilities and remote underground storage combined with pipeline transportation to the area. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. DOE has identified five regions, that have not had favorable geological conditions for underground storage development: New England, Mid-Atlantic (NY/NJ), South Atlantic (DL/MD/VA), South Atlantic (NC/SC/GA), and the Pacific Northwest (WA/OR). PB-KBB reviewed published literature and in-house databases of the geology of these regions to determine suitability of hard rock formations for siting storage

  10. Investigation of advanced propulsion technologies: The RAM accelerator and the flowing gas radiation heater

    NASA Technical Reports Server (NTRS)

    Bruckner, A. P.; Knowlen, C.; Mattick, A. T.; Hertzberg, A.

    1992-01-01

    The two principal areas of advanced propulsion investigated are the ram accelerator and the flowing gas radiation heater. The concept of the ram accelerator is presented as a hypervelocity launcher for large-scale aeroballistic range applications in hypersonics and aerothermodynamics research. The ram accelerator is an in-bore ramjet device in which a projectile shaped like the centerbody of a supersonic ramjet is propelled in a stationary tube filled with a tailored combustible gas mixture. Combustion on and behind the projectile generates thrust which accelerates it to very high velocities. The acceleration can be tailored for the 'soft launch' of instrumented models. The distinctive reacting flow phenomena that have been observed in the ram accelerator are relevant to the aerothermodynamic processes in airbreathing hypersonic propulsion systems and are useful for validating sophisticated CFD codes. The recently demonstrated scalability of the device and the ability to control the rate of acceleration offer unique opportunities for the use of the ram accelerator as a large-scale hypersonic ground test facility. The flowing gas radiation receiver is a novel concept for using solar energy to heat a working fluid for space power or propulsion. Focused solar radiation is absorbed directly in a working gas, rather than by heat transfer through a solid surface. Previous theoretical analysis had demonstrated that radiation trapping reduces energy loss compared to that of blackbody receivers, and enables higher efficiencies and higher peak temperatures. An experiment was carried out to measure the temperature profile of an infrared-active gas and demonstrate the effect of radiation trapping. The success of this effort validates analytical models of heat transfer in this receiver, and confirms the potential of this approach for achieving high efficiency space power and propulsion.

  11. Advanced onboard storage concepts for natural gas-fueled automotive vehicles

    NASA Technical Reports Server (NTRS)

    Remick, R. J.; Elkins, R. H.; Camara, E. H.; Bulicz, T.

    1984-01-01

    The evaluation of several advanced concepts for storing natural gas at reduced pressure is presented. The advanced concepts include adsorption on high surface area carbon, adsorption in high porosity zeolite, storage in clathration compounds, and storage by dissolution in liquid solvents. High surface area carbons with high packing density are the best low pressure storage mediums. A simple mathematical model is used to compare adsorption storage on a state of the art carbon with compression storage. The model indicates that a vehicle using adsorption storage of natural gas at 3.6 MPa will have 36 percent of the range, on the EPA city cycle, of a vehicle operating on a compression storage system having the same physical size and a peak storage pressure of 21 MPa. Preliminary experiments and current literature suggest that the storage capacity of state of the art carbons could be improved by as much as 50 percent, and that adsorption systems having a capacity equal to compression storage at 14 MPa are possible without exceeding a maximum pressure of 3.6 MPa.

  12. Advanced High Temperature Polymer Matrix Composites for Gas Turbine Engines Program Expansion

    NASA Technical Reports Server (NTRS)

    Hanley, David; Carella, John

    1999-01-01

    This document, submitted by AlliedSignal Engines (AE), a division of AlliedSignal Aerospace Company, presents the program final report for the Advanced High Temperature Polymer Matrix Composites for Gas Turbine Engines Program Expansion in compliance with data requirements in the statement of work, Contract No. NAS3-97003. This document includes: 1 -Technical Summary: a) Component Design, b) Manufacturing Process Selection, c) Vendor Selection, and d) Testing Validation: 2-Program Conclusion and Perspective. Also, see the Appendix at the back of this report. This report covers the program accomplishments from December 1, 1996, to August 24, 1998. The Advanced High Temperature PMC's for Gas Turbine Engines Program Expansion was a one year long, five task technical effort aimed at designing, fabricating and testing a turbine engine component using NASA's high temperature resin system AMB-21. The fiber material chosen was graphite T650-35, 3K, 8HS with UC-309 sizing. The first four tasks included component design and manufacturing, process selection, vendor selection, component fabrication and validation testing. The final task involved monthly financial and technical reports.

  13. Assessment of research opportunities for advanced gas-fired systems in agriculture. Final report Feb 82-Jun 83

    SciTech Connect

    Lowry, J.F.; Brady, J.A.

    1982-06-01

    An investigation of energy consumption in the U. S. agricultural sector reveals that natural gas is used on farms for a variety of purposes wherever a supply system is in place. However, only a small fraction of U. S. farms have access to gas, thus severely limiting the market for advanced natural gas-fired systems. While there is room for energy efficiency improvements in many equipment types, there is little justification for initiating a major RandD effort aimed exclusively at agricultural applications. Advanced equipment systems such as gas-fired dairy refrigeration equipment and gas-fired mobile apparatus have potential on-farm markets, but economic and technological constraints limit their potential in the near future.

  14. Techical findings document for generic issue 51: Improving the reliability of open-cycle service-water systems

    SciTech Connect

    Neitzel, D.A.; Johnson, K.I.

    1988-08-01

    This report summarizes information needed to prepare a fouling surveillance and control program for a nuclear power plant. The safety significance of bivalve and other fouling is reviewed. Many safety-related systems are cooled either directly by the open-cycle water system or indirectly through intermediate cooling loops. Residual heat-removal heat exchangers, containment cooling units, diesel-generator coolers, fire-protection systems, and safety-related equipment coolers have been fouled by bivalves, sediment, or corrosion. The biological characteristics of bivalves enhance their ability to foul service-water systems. The design of the service-water system provides areas where sediments can accumulate and where bivalves can settle and grow. Surveillance and control systems are available to reduce the occurrence of bivalve, sediment, and corrosion fouling. No one technique seems to provide the best answer. A workable surveillance and control program requires using several surveillance and control alternatives. Utility experience has shown that continuous low-level chlorination of the service-water system is one of the most effective means of minimizing the safety significance of macrofouling.

  15. Conceptual design of an open-cycle ocean thermal energy conversion net power-producing experiment (OC-OTEC NPPE)

    SciTech Connect

    Bharathan, D.; Green, H.J.; Link, H.F.; Parsons, B.K.; Parsons, J.M.; Zangrando, F.

    1990-07-01

    This report describes the conceptual design of an experiment to investigate heat and mass transfer and to assess the viability of open-cycle ocean thermal energy conversion (OC-OTEC). The experiment will be developed in two stages, the Heat- and Mass-Transfer Experimental Apparatus (HMTEA) and the Net Power-Producing Experiment (NPPE). The goal for the HMTEA is to test heat exchangers. The goal for the NPPE is to experimentally verify OC-OTEC's feasibility by installing a turbine and testing the power-generating system. The design effort met the goals of both the HMTEA and the NPPE, and duplication of hardware was minimal. The choices made for the design resource water flow rates are consistent with the availability of cold and warm seawater as a result of the seawater systems upgrade carried out by the US Department of Energy (DOE), the state of Hawaii, and the Pacific International Center for High Technology Research. The choices regarding configuration of the system were made based on projected performance, degree of technical risk, schedule, and cost. The cost for the future phase of the design and the development of the HMTEA/NPPE is consistent with the projected future program funding levels. The HMTEA and NPPE were designed cooperatively by PICHTR, Argonne National Laboratory, and Solar Energy Research Institute under the guidance of DOE. The experiment will be located at the DOE's Seacoast Test Facility at the Natural Energy Laboratory of Hawaii, Kailua-Kona, Hawaii. 71 refs., 41 figs., 34 tabs.

  16. Results of scoping tests for open-cycle OTEC (Ocean Thermal Energy Conversion) components operating with seawater

    NASA Astrophysics Data System (ADS)

    Zangrando, F.; Bharathan, D.; Green, H. J.; Link, H. F.; Parsons, B. K.; Parsons, J. M.; Pesaran, A. A.; Panchal, C. B.

    1990-09-01

    This report presents comprehensive documentation of the experimental research conducted on open-cycle ocean thermal energy conversion (OC-OTEC) components operating with seawater as a working fluid. The results of this research are presented in the context of previous analysis and fresh-water testing; they provide a basis for understanding and predicting with confidence the performance of all components of an OC-OTEC system except the turbine. Seawater tests have confirmed the results that were obtained in fresh-water tests and predicted by the analytical models of the components. A sound technical basis has been established for the design of larger systems in which net power will be produced for the first time from OC-OTEC technology. Design and operation of a complete OC-OTEC system that produces power will provide sufficient confidence to warrant complete transfer of OC-OTEC technology to the private sector. Each components performance is described in a separate chapter written by the principal investigator responsible for technical aspects of the specific tests. Chapters have been indexed separately for inclusion on the data base.

  17. Conceptual design of an Open-Cycle Ocean Thermal Energy Conversion Net Power-Producing Experiment (OC-OTEC NPPE)

    NASA Astrophysics Data System (ADS)

    Bharathan, D.; Green, H. J.; Link, H. F.; Parsons, B. K.; Parsons, J. M.; Zangrando, F.

    1990-07-01

    This report describes the conceptual design of an experiment to investigate heat and mass transfer and to assess the viability of open-cycle ocean thermal energy conversion (OC-OTEC). The experiment will be developed in two stages, the Heat- and Mass-Transfer Experimental Apparatus (HMTEA) and the Net Power-Producing Experiment (NPPE). The goal for the HMTEA is to test heat exchangers. The goal for the NPPE is to experimentally verify OC-OTEC's feasibility by installing a turbine and testing the power-generating system. The design effort met the goals of both the HMTEA and the NPPE, and duplication of hardware was minimal. The choices made for the design resource water flow rates are consistent with the availability of cold and warm seawater as a result of the seawater systems upgrade carried out by the U.S. Department of Energy (DOE), the state of Hawaii, and the Pacific International Center for High Technology Research. The choices regarding configuration of the system were made based on projected performance, degree of technical risk, schedule, and cost. The cost for the future phase of the design and the development of the HMTEA/NPPE is consistent with the projected future program funding levels. The HMTEA and NPPE were designed cooperatively by PICHTR, Argonne National Laboratory, and Solar Energy Research Institute under the guidance of DOE. The experiment will be located at the DOE's Seacoast Test Facility at the Natural Energy Laboratory of Hawaii, Kailua-Kona, Hawaii.

  18. Results of scoping tests for open-cycle OTEC (ocean thermal energy conversion) components operating with seawater

    SciTech Connect

    Zangrando, F; Bharathan, D; Green, H J; Link, H F; Parsons, B K; Parsons, J M; Pesaran, A A; Panchal, C B

    1990-09-01

    This report presents comprehensive documentation of the experimental research conducted on open-cycle ocean thermal energy conversion (OC-OTEC) components operating with seawater as a working fluid. The results of this research are presented in the context of previous analysis and fresh-water testing; they provide a basis for understanding and predicting with confidence the performance of all components of an OC-OTEC system except the turbine. Seawater tests have confirmed the results that were obtained in fresh-water tests and predicted by the analytical models of the components. A sound technical basis has been established for the design of larger systems in which net power will be produced for the first time from OC-OTEC technology. Design and operation of a complete OC-OTEC system that produces power will provide sufficient confidence to warrant complete transfer of OC-OTEC technology to the private sector. Each components performance is described in a separate chapter written by the principal investigator responsible for technical aspects of the specific tests. Chapters have been indexed separately for inclusion on the data base.

  19. The DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification Program

    SciTech Connect

    David Petti; Hans Gougar; Gary Bell

    2005-05-01

    The Department of Energy has established the Advanced Gas Reactor Fuel Development and Qualification Program to address the following overall goals: Provide a baseline fuel qualification data set in support of the licensing and operation of the Next Generation Nuclear Plant (NGNP). Gas-reactor fuel performance demonstration and qualification comprise the longest duration research and development (R&D) task for the NGNP feasibility. The baseline fuel form is to be demonstrated and qualified for a peak fuel centerline temperature of 1250°C. Support near-term deployment of an NGNP by reducing market entry risks posed by technical uncertainties associated with fuel production and qualification. Utilize international collaboration mechanisms to extend the value of DOE resources. The Advanced Gas Reactor Fuel Development and Qualification Program consists of five elements: fuel manufacture, fuel and materials irradiations, postirradiation examination (PIE) and safety testing, fuel performance modeling, and fission product transport and source term evaluation. An underlying theme for the fuel development work is the need to develop a more complete fundamental understanding of the relationship between the fuel fabrication process, key fuel properties, the irradiation performance of the fuel, and the release and transport of fission products in the NGNP primary coolant system. Fuel performance modeling and analysis of the fission product behavior in the primary circuit are important aspects of this work. The performance models are considered essential for several reasons, including guidance for the plant designer in establishing the core design and operating limits, and demonstration to the licensing authority that the applicant has a thorough understanding of the in-service behavior of the fuel system. The fission product behavior task will also provide primary source term data needed for licensing. An overview of the program and recent progress will be presented.

  20. Thermal barrier coatings issues in advanced land-based gas turbines

    NASA Technical Reports Server (NTRS)

    Parks, W. P.; Lee, W. Y.; Wright, I. G.

    1995-01-01

    The Department of Energy's Advanced Turbine System (ATS) program is aimed at forecasting the development of a new generation of land-based gas turbine systems with overall efficiencies significantly beyond those of current state-of-the-art machines, as well as greatly increased times between inspection and refurbishment, improved environmental impact, and decreased cost. The proposed duty cycle of ATS turbines will require the use of different criteria in the design of the materials for the critical hot gas path components. In particular, thermal barrier coatings will be an essential feature of the hot gas path components in these machines. While such coatings are routinely used in high-performance aircraft engines and are becoming established in land-based turbines, the requirements of the ATS turbine application are sufficiently different that significant improvements in thermal barrier coating technology will be necessary. In particular, it appears that thermal barrier coatings will have to function on all airfoil sections of the first stage vanes and blades to provide the significant temperature reduction required. In contrast, such coatings applied to the blades and vances of advanced aircraft engines are intended primarily to reduce air cooling requirements and extend component lifetime; failure of those coatings can be tolerated without jeopardizing mechanical or corrosion performance. A major difference is that in ATS turbines these components will be totally reliant on thermal barrier coatings which will, therefore, need to be highly reliable even over the leading edges of first stage blades. Obviously, the ATS program provides a very challenging opportunity for TBC's, and involves some significant opportunities to extend this technology.

  1. Optical Breath Gas Extravehicular Activity Sensor for the Advanced Portable Life Support System

    NASA Technical Reports Server (NTRS)

    Wood, William R.; Casias, Miguel E.; Pilgrim, Jeffrey S.; Chullen, Cinda; Campbell, Colin

    2016-01-01

    The function of the infrared gas transducer used during extravehicular activity (EVA) in the current space suit is to measure and report the concentration of carbon dioxide (CO2) in the ventilation loop. The next generation portable life support system (PLSS) requires highly accurate CO2 sensing technology with performance beyond that presently in use on the International Space Station extravehicular mobility unit (EMU). Further, that accuracy needs to be provided over the full operating pressure range of the suit (3 to 25 psia). Accommodation within space suits demands that optical sensors meet stringent size, weight, and power requirements. A laser diode (LD) sensor based on infrared absorption spectroscopy is being developed for this purpose by Vista Photonics, Inc. Version 1.0 prototype devices were delivered to NASA Johnson Space Center (JSC) in September 2011. The prototypes were upgraded with more sophisticated communications and faster response times to version 2.0 and delivered to JSC in July 2012. The sensors incorporate a laser diode based CO2 channel that also includes an incidental water vapor (humidity) measurement. The prototypes are controlled digitally with an field-programmable gate array microcontroller architecture. Based on the results of the iterative instrument development, further prototype development and testing of instruments were performed leveraging the lessons learned where feasible. The present development extends and upgrades the earlier hardware for the advanced PLSS 2.5 prototypes for testing at JSC. The prototypes provide significantly enhanced accuracy for water vapor measurement and eliminate wavelength drift affecting the earlier versions. Various improvements to the electronics and gas sampling are currently being advanced including the companion development of engineering development units that will ultimately be capable of radiation tolerance. The combination of low power electronics with the performance of a long wavelength

  2. Exploring Advanced Technology Gas Turbine Engine Design and Performance for the Large Civil Tiltrotor (LCTR)

    NASA Technical Reports Server (NTRS)

    Snyder, Christopher A.

    2014-01-01

    A Large Civil Tiltrotor (LCTR) conceptual design was developed as part of the NASA Heavy Lift Rotorcraft Systems Investigation in order to establish a consistent basis for evaluating the benefits of advanced technology for large tiltrotors. The concept has since evolved into the second-generation LCTR2, designed to carry 90 passengers for 1,000 nautical miles at 300 knots, with vertical takeoff and landing capability. This paper explores gas turbine component performance and cycle parameters to quantify performance gains possible for additional improvements in component and material performance beyond those identified in previous LCTR2 propulsion studies and to identify additional research areas. The vehicle-level characteristics from this advanced technology generation 2 propulsion architecture will help set performance levels as additional propulsion and power systems are conceived to meet ever-increasing requirements for mobility and comfort, while reducing energy use, cost, noise and emissions. The Large Civil Tiltrotor vehicle and mission will be discussed as a starting point for this effort. A few, relevant engine and component technology studies, including previous LCTR2 engine study results will be summarized to help orient the reader on gas turbine engine architecture, performance and limitations. Study assumptions and methodology used to explore engine design and performance, as well as assess vehicle sizing and mission performance will then be discussed. Individual performance for present and advanced engines, as well as engine performance effects on overall vehicle size and mission fuel usage, will be given. All results will be summarized to facilitate understanding the importance and interaction of various component and system performance on overall vehicle characteristics.

  3. Integration of magnetic bearings in the design of advanced gas turbine engines

    NASA Technical Reports Server (NTRS)

    Storace, Albert F.; Sood, Devendra K.; Lyons, James P.; Preston, Mark A.

    1994-01-01

    Active magnetic bearings provide revolutionary advantages for gas turbine engine rotor support. These advantages include tremendously improved vibration and stability characteristics, reduced power loss, improved reliability, fault-tolerance, and greatly extended bearing service life. The marriage of these advantages with innovative structural network design and advanced materials utilization will permit major increases in thrust to weight performance and structural efficiency for future gas turbine engines. However, obtaining the maximum payoff requires two key ingredients. The first key ingredient is the use of modern magnetic bearing technologies such as innovative digital control techniques, high-density power electronics, high-density magnetic actuators, fault-tolerant system architecture, and electronic (sensorless) position estimation. This paper describes these technologies. The second key ingredient is to go beyond the simple replacement of rolling element bearings with magnetic bearings by incorporating magnetic bearings as an integral part of the overall engine design. This is analogous to the proper approach to designing with composites, whereby the designer tailors the geometry and load carrying function of the structural system or component for the composite instead of simply substituting composites in a design originally intended for metal material. This paper describes methodologies for the design integration of magnetic bearings in gas turbine engines.

  4. Integration of magnetic bearings in the design of advanced gas turbine engines

    NASA Astrophysics Data System (ADS)

    Storace, Albert F.; Sood, Devendra K.; Lyons, James P.; Preston, Mark A.

    1994-05-01

    Active magnetic bearings provide revolutionary advantages for gas turbine engine rotor support. These advantages include tremendously improved vibration and stability characteristics, reduced power loss, improved reliability, fault-tolerance, and greatly extended bearing service life. The marriage of these advantages with innovative structural network design and advanced materials utilization will permit major increases in thrust to weight performance and structural efficiency for future gas turbine engines. However, obtaining the maximum payoff requires two key ingredients. The first key ingredient is the use of modern magnetic bearing technologies such as innovative digital control techniques, high-density power electronics, high-density magnetic actuators, fault-tolerant system architecture, and electronic (sensorless) position estimation. This paper describes these technologies. The second key ingredient is to go beyond the simple replacement of rolling element bearings with magnetic bearings by incorporating magnetic bearings as an integral part of the overall engine design. This is analogous to the proper approach to designing with composites, whereby the designer tailors the geometry and load carrying function of the structural system or component for the composite instead of simply substituting composites in a design originally intended for metal material. This paper describes methodologies for the design integration of magnetic bearings in gas turbine engines.

  5. Design of a Gas Test Loop Facility for the Advanced Test Reactor

    SciTech Connect

    C. A. Wemple

    2005-09-01

    The Office of Nuclear Energy within the U.S. Department of Energy (DOE-NE) has identified the need for irradiation testing of nuclear fuels and materials, primarily in support of the Generation IV (Gen-IV) and Advanced Fuel Cycle Initiative (AFCI) programs. These fuel development programs require a unique environment to test and qualify potential reactor fuel forms. This environment should combine a high fast neutron flux with a hard neutron spectrum and high irradiation temperature. An effort is presently underway at the Idaho National Laboratory (INL) to modify a large flux trap in the Advanced Test Reactor (ATR) to accommodate such a test facility [1,2]. The Gas Test Loop (GTL) Project Conceptual Design was initiated to determine basic feasibility of designing, constructing, and installing in a host irradiation facility, an experimental vehicle that can replicate with reasonable fidelity the fast-flux test environment needed for fuels and materials irradiation testing for advanced reactor concepts. Such a capability will be needed if programs such as the AFCI, Gen-IV, the Next Generation Nuclear Plant (NGNP), and space nuclear propulsion are to meet development objectives and schedules. These programs are beginning some irradiations now, but many call for fast flux testing within this decade.

  6. Degradation of TBC Systems in Environments Relevant to Advanced Gas Turbines for IGCC Systems

    SciTech Connect

    Gleeson, Brian

    2014-09-30

    Air plasma sprayed (APS) thermal barrier coatings (TBCs) are used to provide thermal insulation for the hottest components in gas turbines. Zirconia stabilized with 7wt% yttria (7YSZ) is the most common ceramic top coat used for turbine blades. The 7YSZ coating can be degraded from the buildup of fly-ash deposits created in the power-generation process. Fly ash from an integrated gasification combined cycle (IGCC) system can result from coal-based syngas. TBCs are also exposed to harsh gas environments containing CO2, SO2, and steam. Degradation from the combined effects of fly ash and harsh gas atmospheres has the potential to severely limit TBC lifetimes. The main objective of this study was to use lab-scale testing to systematically elucidate the interplay between prototypical deposit chemistries (i.e., ash and its constituents, K2SO4, and FeS) and environmental oxidants (i.e., O2, H2O and CO2) on the degradation behavior of advanced TBC systems. Several mechanisms of early TBC failure were identified, as were the specific fly-ash constituents responsible for degradation. The reactivity of MCrAlY bondcoats used in TBC systems was also investigated. The specific roles of oxide and sulfate components were assessed, together with the complex interplay between gas composition, deposit chemistry and alloy reactivity. Bondcoat composition design strategies to mitigate corrosion were established, particularly with regard to controlling phase constitution and the amount of reactive elements the bondcoat contains in order to achieve optimal corrosion resistance.

  7. Anisotropic mechanical behaviour of sedimentary basins inferred by advanced radar interferometry above gas storage fields

    NASA Astrophysics Data System (ADS)

    Teatini, P.; Gambolati, G.; Ferretti, A.

    2010-12-01

    Natural gas is commonly stored underground in depleted oil and gas fields to provide safe storage capacity and deliverability to market areas where production is limited, or to take advantage of seasonal price swings. In response to summer gas injection and winter gas withdrawal the reservoir expands and contracts with the overlying land that moves accordingly. Depending on the field burial depth, a few kilometres of the upper lithosphere are subject to local three-dimensional deformations with the related cyclic motion of the ground surface being both vertical and horizontal. Advanced Persistent Scatterer Interferometry (PSI) data, obtained by combining ascending and descending RADARSAT-1 images acquired from 2003 to 2008 above gas storage fields located in the sedimentary basin of the Po river plain, Italy, provide reliable measurement of these seasonal vertical ups and downs as well as horizontal displacements to and from the injection/withdrawal wells. Combination of the land surface movements together with an accurate reconstruction of the subsurface geology made available by three-dimensional seismic surveys and long-time records of fluid pore pressure within the 1000-1500 m deep reservoirs has allowed for the development of an accurate 3D poro-mechanical finite-element model of the gas injection/removal occurrence. Model calibration based on the observed cyclic motions, which are on the range of 10-15 mm and 5-10 mm in the vertical and horizontal west-east directions, respectively, helps characterize the nonlinear hysteretic geomechanical properties of the basin. First, using a basin-scale relationship between the oedometric rock compressibility cM in virgin loading conditions versus the effective intergranular stress derived from previous experimental studies, the modeling results show that the ratio s between loading and unloading-reloading cM is about 4, consistent with in-situ expansions measured by the radioactive marker technique in similar reservoirs

  8. Functionally gradient materials for thermal barrier coatings in advanced gas turbine systems

    SciTech Connect

    Banovic, S.W.; Barmak, K.; Chan, H.M.

    1995-10-01

    New designs for advanced gas turbine engines for power production are required to have higher operating temperatures in order to increase efficiency. However, elevated temperatures will increase the magnitude and severity of environmental degradation of critical turbine components (e.g. combustor parts, turbine blades, etc{hor_ellipsis}). To offset this problem, the usage of thermal barrier coatings (TBCs) has become popular by allowing an increase in maximum inlet temperatures for an operating engine. Although thermal barrier technology is over thirty years old, the principle failure mechanism is the spallation of the ceramic coating at or near the ceramic/bond coat interface. Therefore, it is desirable to develop a coating that combines the thermal barrier qualities of the ceramic layer and the corrosion protection by the metallic bond coat without the detrimental effects associated with the localization of the ceramic/metal interface to a single plane.

  9. Investigation of austenitic alloys for advanced heat recovery and hot gas cleanup systems

    SciTech Connect

    Swindeman, R.W.; Ren, W.

    1996-08-01

    Materials properties were collected for the design and construction of structural components for use in advanced heat recovery and hot gas cleanup systems. Alloys systems included 9Cr-1Mo-V steel, modified 316 stainless steel, modified type 310 stainless steel, modified 20Cr-25Ni-Nb stainless steel, modified alloy 800, and two sulfidation resistant alloys: HR160 and HR120. Experimental work was undertaken to expand the databases for potentially useful alloys. Types of testing included creep, stress-rupture, creep-crack growth, fatigue, and post-exposure short-time tensile tests. Because of the interest in relatively inexpensive alloys for service at 700{degrees}C and higher, research emphasis was placed on a modified type 310 stainless steel and a modified 20Cr-25Ni-Nb stainless steel. Both steels were found to have useful strength to 925{degrees}C with good weldability and ductility.

  10. Investigation of austenitic alloys for advanced heat recovery and hot gas cleanup systems

    SciTech Connect

    Swindeman, R.W.; Ren, W.

    1995-08-01

    Alloys for design and construction of structural components needed to contain process streams and provide internal structures in advanced heat recovery and hot gas cleanup systems were examined. Emphasis was placed on high-strength, corrosion-resistant alloys for service at temperatures above 1000 {degrees}F (540{degrees}C). Data were collected that related to fabrication, joining, corrosion protection, and failure criteria. Alloys systems include modified type 310 and 20Cr-25Ni-Nb steels and sulfidation-resistance alloys HR120 and HR160. Types of testing include creep, stress-rupture, creep crack growth, fatigue, and post-exposure short-time tensile. Because of the interest in relatively inexpensive alloys for high temperature service, a modified type 310 stainless steel was developed with a target strength of twice that for standard type 310 stainless steel.

  11. Investigation of austenitic alloys for advanced heat recovery and hot-gas cleanup systems

    SciTech Connect

    Swindeman, R.W.

    1997-12-01

    Materials properties were collected for the design and construction of structural components for use in advanced heat recovery and hot gas cleanup systems. Alloys systems included 9Cr-1Mo-V steel, modified 316 stainless steel, modified type 310 stainless steel, modified 20Cr-25Ni-Nb stainless steel, and modified alloy 800. Experimental work was undertaken to expand the databases for potentially useful alloys. Types of testing included creep, stress-rupture, creep-crack growth, fatigue, and post-exposure short-time tensile tests. Because of the interest in relatively inexpensive alloys for service at 700 C and higher, research emphasis was placed on a modified type 310 stainless steel and a modified 20Cr-25Ni-Nb stainless steel. Both steels were found to have useful strength to 925 C with good weldability and ductility.

  12. Optical Fuel Injector Patternation Measurements in Advanced Liquid-Fueled, High Pressure, Gas Turbine Combustors

    NASA Technical Reports Server (NTRS)

    Locke, R. J.; Hicks, Y. R.; Anderson, R. C.; Zaller, M. M.

    1998-01-01

    Planar laser-induced fluorescence (PLIF) imaging and planar Mie scattering are used to examine the fuel distribution pattern (patternation) for advanced fuel injector concepts in kerosene burning, high pressure gas turbine combustors. Three fuel injector concepts for aerospace applications were investigated under a broad range of operating conditions. Fuel PLIF patternation results are contrasted with those obtained by planar Mie scattering. For one injector, further comparison is also made with data obtained through phase Doppler measurements. Differences in spray patterns for diverse conditions and fuel injector configurations are readily discernible. An examination of the data has shown that a direct determination of the fuel spray angle at realistic conditions is also possible. The results obtained in this study demonstrate the applicability and usefulness of these nonintrusive optical techniques for investigating fuel spray patternation under actual combustor conditions.

  13. Thermal barrier coatings issues in advanced land-based gas turbines

    SciTech Connect

    Parks, W.P.; Lee, W.Y.; Wright, I.G.

    1995-06-01

    The Department of Energy`s Advanced Turbine Systems (ATS) program is aimed at fostering the development of a new generation of land-based gas turbine systems with overall efficiencies significantly beyond those of current state-of-the-art machines, as well as greatly increased times between inspection and refurbishment, improved environmental impact, and decreased cost. The proposed duty cycle of ATS machines will emphasize different criteria in the selection of materials for the critical components. In particular, thermal barrier coatings (TBCS) will be an essential feature of the hot gas path components in these machines. In fact, the goals of the ATS will require significant improvements in TBC technology, since these turbines will be totally reliant on TBCs, which will be required to function on critical components such as the first stage vanes and blades for times considerably in excess of those experienced in current applications. Issues that assume increased importance are the mechanical and chemical stability of the ceramic layer and of the metallic bond coat; the thermal expansion characteristics and compliance of the ceramic layer; and the thermal conductivity across the thickness of the ceramic layer. Obviously, the ATS program provides a very challenging opportunity for TBCs, and involves some significant opportunities to extend this technology. A significant TBC development effort is planned in the ATS program which will address these key issues.

  14. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect

    Not Available

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  15. Thermal barrier coatings issues in advanced land-based gas turbines

    NASA Technical Reports Server (NTRS)

    Parks, William P.; Hoffman, Eugene E.; Lee, Woo Y.; Wright, Ian G.

    1995-01-01

    The Department of Energy's Advanced Turbine Systems (ATS) program is aimed at fostering the development of a new generation of land-based gas turbine systems with overall efficiencies significantly beyond those of current state-of-the-art machines, as well as greatly increased times between inspection and refurbishment, improved environmental impact, and decreased cost. The proposed duty cycle of ATS machines will emphasize different criteria in the selection of materials for the critical components. In particular, thermal barrier coatings (TBC's) will be an essential feature of the hot gas path components in these machines. In fact, the goals of the ATS will require significant improvements in TBC technology, since these turbines will be totally reliant on TBC's, which will be required to function on critical components such as the first stage vanes and blades for times considerably in excess of those experienced in current applications. Issues that assume increased importance are the mechanical and chemical stability of the ceramic layer and of the metallic bond coat; the thermal expansion characteristics and compliance of the ceramic layer; and the thermal conductivity across the thickness of the ceramic layer. Obviously, the ATS program provides a very challenging opportunity for TBC's, and involves some significant opportunities to extend this technology. A significant TBC development effort is planned in the ATS program which will address these key issues.

  16. Apparent dynamic contact angle of an advancing gas--liquid meniscus

    SciTech Connect

    Kalliadasis, S.; Chang, H. )

    1994-01-01

    The steady motion of an advancing meniscus in a gas-filled capillary tube involves a delicate balance of capillary, viscous, and intermolecular forces. The limit of small capillary numbers Ca (dimensionless speeds) is analyzed here with a matched asymptotic analysis that links the outer capillary region to the precursor film in front of the meniscus through a lubricating film. The meniscus shape in the outer region is constructed and the apparent dynamic contact angle [Theta] that the meniscus forms with the solid surface is derived as a function of the capillary number, the capillary radius, and the Hamaker's constant for intermolecular forces, under conditions of weak gas--solid interaction, which lead to fast spreading of the precursor film and weak intermolecular forces relative to viscous forces within the lubricating film. The dependence on intermolecular forces is very weak and the contact angle expression has a tight upper bound tan [Theta]=7.48 Ca[sup 1/3] for thick films, which is independent of the Hamaker constant. This upper bound is in very good agreement with existing experimental data for wetting fluids in any capillary and for partially wetting fluids in a prewetted capillary. Significant correction to the Ca[sup 1/3] dependence occurs only at very low Ca, where the intermolecular forces become more important and tan [Theta] diverges slightly from the above asymptotic behavior toward lower values.

  17. Selection of an industrial natural-gas-fired advanced turbine system - Task 3A

    SciTech Connect

    Holloway, G.M.

    1997-05-01

    TASK OBJECTIVES: Identify a gas-fueled turbine and steam system which will meet the program goals for efficiency - and emissions. TECHNICAL GOALS AND REQUIREMENTS: Goals for the Advanced Turbine System Program (ATS) where outlined in the statement of work for five basic categories: Cycle Efficiency - System heat rate to have a 15% improvement over 1991 vintage systems being offered to the market. Environmental No post-combustion devices while meeting the following parameter targets: (1) Nitrous Oxide (NO{sub x}) emissions to equal 8 parts per million dry (ppmd) with 15% oxygen. (2) Carbon monoxide (CO) and unburned hydrocarbon (UHC) emissions to equal 20 parts per million(ppmd) each. Cost of electricity to be 10 percent less when compared to similar 1991 systems. Fuel Flexibility Have to ability to burn coal or coal derived fuels without extensive redesign. Reliability, Availability, Maintainability Reliability, availability and maintainability must be comparable to modern advanced power generation systems. For all cycle and system studies, analyses were done for the following engine system ambient conditions: Temperature - 59F; Altitude - Sea Level; Humidity - 60%. For the 1991 reference system, GE Aircraft Engines used its LM6OOO engine product offering for comparison of the Industrial System parameters developed under this program.

  18. Three-dimensional unsteady flow calculations in an advanced gas generator turbine

    NASA Technical Reports Server (NTRS)

    Rangwalla, Akil A.

    1993-01-01

    This paper deals with the application of a three-dimensional, unsteady Navier-Stokes code for predicting the unsteady flow in a single stage of an advanced gas generator turbine. The numerical method solves the three-dimensional thin-layer Navier-Stokes equations, using a system of overlaid grids, which allow for relative motion between the rotor and stator airfoils. Results in the form of time averaged pressures and pressure amplitudes on the airfoil surfaces will be shown. In addition, instantaneous contours of pressure, Mach number, etc. will be presented in order to provide a greater understanding of the inviscid as well as the viscous aspects of the flowfield. Also, relevant secondary flow features such as cross-plane velocity vectors and total pressure contours will be presented. Prior work in two-dimensions has indicated that for the advanced designs, the unsteady interactions can play a significant role in turbine performance. These interactions affect not only the stage efficiency but can substantially alter the time-averaged features of the flow. This work is a natural extension of the work done in two-dimensions and hopes to address some of the issues raised by the two-dimensional calculations. These calculations are being performed as an integral part of an actual design process and demonstrate the value of unsteady rotor-stator interaction calculations in the design of turbomachines.

  19. Noble gas and hydrocarbon tracers in multiphase unconventional hydrocarbon systems: Toward integrated advanced reservoir simulators

    NASA Astrophysics Data System (ADS)

    Darrah, T.; Moortgat, J.; Poreda, R. J.; Muehlenbachs, K.; Whyte, C. J.

    2015-12-01

    Although hydrocarbon production from unconventional energy resources has increased dramatically in the last decade, total unconventional oil and gas recovery from black shales is still less than 25% and 9% of the totals in place, respectively. Further, the majority of increased hydrocarbon production results from increasing the lengths of laterals, the number of hydraulic fracturing stages, and the volume of consumptive water usage. These strategies all reduce the economic efficiency of hydrocarbon extraction. The poor recovery statistics result from an insufficient understanding of some of the key physical processes in complex, organic-rich, low porosity formations (e.g., phase behavior, fluid-rock interactions, and flow mechanisms at nano-scale confinement and the role of natural fractures and faults as conduits for flow). Noble gases and other hydrocarbon tracers are capably of recording subsurface fluid-rock interactions on a variety of geological scales (micro-, meso-, to macro-scale) and provide analogs for the movement of hydrocarbons in the subsurface. As such geochemical data enrich the input for the numerical modeling of multi-phase (e.g., oil, gas, and brine) fluid flow in highly heterogeneous, low permeability formations Herein we will present a combination of noble gas (He, Ne, Ar, Kr, and Xe abundances and isotope ratios) and molecular and isotopic hydrocarbon data from a geographically and geologically diverse set of unconventional hydrocarbon reservoirs in North America. Specifically, we will include data from the Marcellus, Utica, Barnett, Eagle Ford, formations and the Illinois basin. Our presentation will include geochemical and geological interpretation and our perspective on the first steps toward building an advanced reservoir simulator for tracer transport in multicomponent multiphase compositional flow (presented separately, in Moortgat et al., 2015).

  20. An Advanced Analytical Chemistry Experiment Using Gas Chromatography-Mass Spectrometry, MATLAB, and Chemometrics to Predict Biodiesel Blend Percent Composition

    ERIC Educational Resources Information Center

    Pierce, Karisa M.; Schale, Stephen P.; Le, Trang M.; Larson, Joel C.

    2011-01-01

    We present a laboratory experiment for an advanced analytical chemistry course where we first focus on the chemometric technique partial least-squares (PLS) analysis applied to one-dimensional (1D) total-ion-current gas chromatography-mass spectrometry (GC-TIC) separations of biodiesel blends. Then, we focus on n-way PLS (n-PLS) applied to…

  1. Fission Product Monitoring and Release Data for the Advanced Gas Reactor -1 Experiment

    SciTech Connect

    Dawn M. Scates; John B. Walter; Jason M. Harp; Mark W. Drigert; Edward L. Reber

    2010-10-01

    The AGR-1 experiment is a fueled multiple-capsule irradiation experiment that was irradiated in the Advanced Test Reactor (ATR) from December 26, 2006 until November 6, 2009 in support of the Very High Temperature Reactor (VHTR) Technology Development Office (TDO) Fuel Development and Qualification program. An important measure of the fuel performance is the quantification of the fission product releases over the duration of the experiment. To provide this data for the inert fission gasses(Kr and Xe), a fission product monitoring system (FPMS) was developed and implemented to monitor the individual capsule effluents for the radioactive species. The FPMS continuously measured the concentrations of various krypton and xenon isotopes in the sweep gas from each AGR-1 capsule to provide an indicator of fuel irradiation performance. Spectrometer systems quantified the concentrations of Kr-85m, Kr-87, Kr-88, Kr-89, Kr-90, Xe-131m, Xe-133, Xe 135, Xe 135m, Xe-137, Xe-138, and Xe-139 accumulated over repeated eight hour counting intervals.-. To determine initial fuel quality and fuel performance, release activity for each isotope of interest was derived from FPMS measurements and paired with a calculation of the corresponding isotopic production or birthrate. The release activities and birthrates were combined to determine Release-to-Birth ratios for the selected nuclides. R/B values provide indicators of initial fuel quality and fuel performance during irradiation. This paper presents a brief summary of the FPMS, the release to birth ratio data for the AGR-1 experiment and preliminary comparisons of AGR-1 experimental fuels data to fission gas release models.

  2. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  3. LOW-ENGINE-FRICTION TECHNOLOGY FOR ADVANCED NATURAL-GAS RECIPROCATING ENGINES

    SciTech Connect

    Victor W. Wong; Tian Tian; Grant Smedley; Jeffrey Jocsak

    2004-09-30

    This program aims at improving the efficiency of advanced natural-gas reciprocating engines (ANGRE) by reducing piston/ring assembly friction without major adverse effects on engine performance, such as increased oil consumption and emissions. An iterative process of simulation, experimentation and analysis, are being followed towards achieving the goal of demonstrating a complete optimized low-friction engine system. To date, a detailed set of piston/ring dynamic and friction models have been developed and applied that illustrated the fundamental relationships between design parameters and friction losses. Various low-friction strategies and ring-design concepts have been explored, and engine experiments have been done on a full-scale Waukesha VGF F18 in-line 6 cylinder power generation engine rated at 370 kW at 1800 rpm. Current accomplishments include designing and testing ring-packs using a subtle top-compression-ring profile (skewed barrel design), lowering the tension of the oil-control ring, employing a negative twist to the scraper ring to control oil consumption. Initial test data indicate that piston ring-pack friction was reduced by 35% by lowering the oil-control ring tension alone, which corresponds to a 1.5% improvement in fuel efficiency. Although small in magnitude, this improvement represents a first step towards anticipated aggregate improvements from other strategies. Other ring-pack design strategies to lower friction have been identified, including reduced axial distance between the top two rings, tilted top-ring groove. Some of these configurations have been tested and some await further evaluation. Colorado State University performed the tests and Waukesha Engine Dresser, Inc. provided technical support. Key elements of the continuing work include optimizing the engine piston design, application of surface and material developments in conjunction with improved lubricant properties, system modeling and analysis, and continued technology

  4. Fission Product Monitoring of TRISO Coated Fuel For The Advanced Gas Reactor -1 Experiment

    SciTech Connect

    Dawn M. Scates; John K. Hartwell; John b. Walter

    2010-10-01

    The US Department of Energy has embarked on a series of tests of TRISO-coated particle reactor fuel intended for use in the Very High Temperature Reactor (VHTR) as part of the Advanced Gas Reactor (AGR) program. The AGR-1 TRISO fuel experiment, currently underway, is the first in a series of eight fuel tests planned for irradiation in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The AGR-1 experiment reached a peak compact averaged burn up of 9% FIMA with no known TRISO fuel particle failures in March 2008. The burnup goal for the majority of the fuel compacts is to have a compact averaged burnup greater than 18% FIMA and a minimum compact averaged burnup of 14% FIMA. At the INL the TRISO fuel in the AGR-1 experiment is closely monitored while it is being irradiated in the ATR. The effluent monitoring system used for the AGR-1 fuel is the Fission Product Monitoring System (FPMS). The FPMS is a valuable tool that provides near real-time data indicative of the AGR-1 test fuel performance and incorporates both high-purity germanium (HPGe) gamma-ray spectrometers and sodium iodide [NaI(Tl)] scintillation detector-based gross radiation monitors. To quantify the fuel performance, release-to-birth ratios (R/B’s) of radioactive fission gases are computed. The gamma-ray spectra acquired by the AGR-1 FPMS are analyzed and used to determine the released activities of specific fission gases, while a dedicated detector provides near-real time count rate information. Isotopic build up and depletion calculations provide the associated isotopic birth rates. This paper highlights the features of the FPMS, encompassing the equipment, methods and measures that enable the calculation of the release-to-birth ratios. Some preliminary results from the AGR-1 experiment are also presented.

  5. Fission Product Monitoring of TRISO Coated Fuel For The Advanced Gas Reactor -1 Experiment

    SciTech Connect

    Dawn M. Scates; John K Hartwell; John B. Walter

    2008-09-01

    The US Department of Energy has embarked on a series of tests of TRISO-coated particle reactor fuel intended for use in the Very High Temperature Reactor (VHTR) as part of the Advanced Gas Reactor (AGR) program. The AGR-1 TRISO fuel experiment, currently underway, is the first in a series of eight fuel tests planned for irradiation in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The AGR-1 experiment reached a peak compact averaged burn up of 9% FIMA with no known TRISO fuel particle failures in March 2008. The burnup goal for the majority of the fuel compacts is to have a compact averaged burnup greater than 18% FIMA and a minimum compact averaged burnup of 14% FIMA. At the INL the TRISO fuel in the AGR-1 experiment is closely monitored while it is being irradiated in the ATR. The effluent monitoring system used for the AGR-1 fuel is the Fission Product Monitoring System (FPMS). The FPMS is a valuable tool that provides near real-time data indicative of the AGR-1 test fuel performance and incorporates both high-purity germanium (HPGe) gamma-ray spectrometers and sodium iodide [NaI(Tl)] scintillation detector-based gross radiation monitors. To quantify the fuel performance, release-to-birth ratios (R/B’s) of radioactive fission gases are computed. The gamma-ray spectra acquired by the AGR-1 FPMS are analyzed and used to determine the released activities of specific fission gases, while a dedicated detector provides near-real time count rate information. Isotopic build up and depletion calculations provide the associated isotopic birth rates. This paper highlights the features of the FPMS, encompassing the equipment, methods and measures that enable the calculation of the release-to-birth ratios. Some preliminary results from the AGR-1 experiment are also presented.

  6. UNCERTAINTY QUANTIFICATION OF CALCULATED TEMPERATURES FOR ADVANCED GAS REACTOR FUEL IRRADIATION EXPERIMENTS

    SciTech Connect

    Pham, Binh Thi-Cam; Hawkes, Grant Lynn; Einerson, Jeffrey James

    2015-08-01

    This paper presents the quantification of uncertainty of the calculated temperature data for the Advanced Gas Reactor (AGR) fuel irradiation experiments conducted in the Advanced Test Reactor at Idaho National Laboratory in support of the Advanced Reactor Technology Research and Development program. Recognizing uncertainties inherent in physics and thermal simulations of the AGR tests, the results of the numerical simulations are used in combination with statistical analysis methods to improve qualification of measured data. The temperature simulation data for AGR tests are also used for validation of the fission product transport and fuel performance simulation models. These crucial roles of the calculated fuel temperatures in ensuring achievement of the AGR experimental program objectives require accurate determination of the model temperature uncertainties. To quantify the uncertainty of AGR calculated temperatures, this study identifies and analyzes ABAQUS model parameters of potential importance to the AGR predicted fuel temperatures. The selection of input parameters for uncertainty quantification of the AGR calculated temperatures is based on the ranking of their influences on variation of temperature predictions. Thus, selected input parameters include those with high sensitivity and those with large uncertainty. Propagation of model parameter uncertainty and sensitivity is then used to quantify the overall uncertainty of AGR calculated temperatures. Expert judgment is used as the basis to specify the uncertainty range for selected input parameters. The input uncertainties are dynamic accounting for the effect of unplanned events and changes in thermal properties of capsule components over extended exposure to high temperature and fast neutron irradiation. The sensitivity analysis performed in this work went beyond the traditional local sensitivity. Using experimental design, analysis of pairwise interactions of model parameters was performed to establish

  7. Advanced coal-fueled gas turbine systems. Annual report, July 1991--June 1992

    SciTech Connect

    Not Available

    1992-09-01

    Westinghouse`s Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO{sub x} emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO{sub x} levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  8. LOW-ENGINE-FRICTION TECHNOLOGY FOR ADVANCED NATURAL-GAS RECIPROCATING ENGINES

    SciTech Connect

    Victor W. Wong; Tian Tian; Grant Smedley

    2003-08-28

    This program aims at improving the efficiency of advanced natural-gas reciprocating engines (ANGRE) by reducing piston/ring assembly friction without major adverse effects on engine performance, such as increased oil consumption and emissions. A detailed set of piston/ring dynamic and friction models have been developed and applied that illustrated the fundamental relationships between design parameters and friction losses. Various low-friction strategies and concepts have been explored, and engine experiments will validate these concepts. An iterative process of experimentation, simulation and analysis, will be followed with the goal of demonstrating a complete optimized low-friction engine system. As planned, MIT has developed guidelines for an initial set of low-friction piston-ring-pack designs. Current recommendations focus on subtle top-piston-ring and oil-control-ring characteristics. A full-scale Waukesha F18 engine has been installed at Colorado State University and testing of the baseline configuration is in progress. Components for the first design iteration are being procured. Subsequent work includes examining the friction and engine performance data and extending the analyses to other areas to evaluate opportunities for further friction improvement and the impact on oil consumption/emission and wear, towards demonstrating an optimized reduced-friction engine system.

  9. Gas centrifuge enrichment plants inspection frequency and remote monitoring issues for advanced safeguards implementation

    SciTech Connect

    Boyer, Brian David; Erpenbeck, Heather H; Miller, Karen A; Ianakiev, Kiril D; Reimold, Benjamin A; Ward, Steven L; Howell, John

    2010-09-13

    Current safeguards approaches used by the IAEA at gas centrifuge enrichment plants (GCEPs) need enhancement in order to verify declared low enriched uranium (LEU) production, detect undeclared LEU production and detect high enriched uranium (BEU) production with adequate probability using non destructive assay (NDA) techniques. At present inspectors use attended systems, systems needing the presence of an inspector for operation, during inspections to verify the mass and {sup 235}U enrichment of declared cylinders of uranium hexafluoride that are used in the process of enrichment at GCEPs. This paper contains an analysis of how possible improvements in unattended and attended NDA systems including process monitoring and possible on-site destructive analysis (DA) of samples could reduce the uncertainty of the inspector's measurements providing more effective and efficient IAEA GCEPs safeguards. We have also studied a few advanced safeguards systems that could be assembled for unattended operation and the level of performance needed from these systems to provide more effective safeguards. The analysis also considers how short notice random inspections, unannounced inspections (UIs), and the concept of information-driven inspections can affect probability of detection of the diversion of nuclear material when coupled to new GCEPs safeguards regimes augmented with unattended systems. We also explore the effects of system failures and operator tampering on meeting safeguards goals for quantity and timeliness and the measures needed to recover from such failures and anomalies.

  10. Advanced coal-fueled industrial cogeneration gas turbine system: Hot End Simulation Rig

    SciTech Connect

    Galica, M.A.

    1994-02-01

    This Hot End Simulation Rig (HESR) was an integral part of the overall Solar/METC program chartered to prove the technical, economic, an environmental feasibility of a coal-fueled gas turbine, for cogeneration applications. The program was to culminate in a test of a Solar Centaur Type H engine system operated on coal slurry fuel throughput the engine design operating range. This particular activity was designed to verify the performance of the Centaur Type H engine hot section materials in a coal-fired environment varying the amounts of alkali, ash, and sulfur in the coal to assess the material corrosion. Success in the program was dependent upon the satisfactory resolution of several key issues. Included was the control of hot end corrosion and erosion, necessary to ensure adequate operating life. The Hot End Simulation Rig addressed this important issue by exposing currently used hot section turbine alloys, alternate alloys, and commercially available advanced protective coating systems to a representative coal-fueled environment at turbine inlet temperatures typical of Solar`s Centaur Type H. Turbine hot end components which would experience material degradation include the transition duct from the combustor outlet to the turbine inlet, the shroud, nozzles, and blades. A ceramic candle filter vessel was included in the system as the particulate removal device for the HESR. In addition to turbine material testing, the candle material was exposed and evaluated. Long-term testing was intended to sufficiently characterize the performance of these materials for the turbine.

  11. Analysis of the effectiveness of gas centrifuge enrichment plants advanced safeguards

    SciTech Connect

    Boyer, Brian David; Erpenbeck, Heather H; Miller, Karen A; Swinjoe, Martyn T; Ianakiev, Kiril D; Marlow, Johnna B

    2010-01-01

    Current safeguards approaches used by the International Atomic Energy Agency (IAEA) at gas centrifuge enrichment plants (GCEPs) need enhancement in order to verify declared low-enriched uranium (LEU) production, detect undeclared LEU production and detect highly enriched uranium (HEU) production with adequate detection probability using non destructive assay (NDA) techniques. At present inspectors use attended systems, systems needing the presence of an inspector for operation, during inspections to verify the mass and 235U enrichment of declared UF6 containers used in the process of enrichment at GCEPs. This paper contains an analysis of possible improvements in unattended and attended NDA systems including process monitoring and possible on-site destructive assay (DA) of samples that could reduce the uncertainty of the inspector's measurements. These improvements could reduce the difference between the operator's and inspector's measurements providing more effective and efficient IAEA GCEPs safeguards. We also explore how a few advanced safeguards systems could be assembled for unattended operation. The analysis will focus on how unannounced inspections (UIs), and the concept of information-driven inspections (IDS) can affect probability of detection of the diversion of nuclear materials when coupled to new GCEPs safeguards regimes augmented with unattended systems.

  12. Current advances of integrated processes combining chemical absorption and biological reduction for NO x removal from flue gas.

    PubMed

    Zhang, Shihan; Chen, Han; Xia, Yinfeng; Liu, Nan; Lu, Bi-Hong; Li, Wei

    2014-10-01

    Anthropogenic nitrogen oxides (NO x ) emitted from the fossil-fuel-fired power plants cause adverse environmental issues such as acid rain, urban ozone smoke, and photochemical smog. A novel chemical absorption-biological reduction (CABR) integrated process under development is regarded as a promising alternative to the conventional selective catalytic reduction processes for NO x removal from the flue gas because it is economic and environmentally friendly. CABR process employs ferrous ethylenediaminetetraacetate [Fe(II)EDTA] as a solvent to absorb the NO x following microbial denitrification of NO x to harmless nitrogen gas. Meanwhile, the absorbent Fe(II)EDTA is biologically regenerated to sustain the adequate NO x removal. Compared with conventional denitrification process, CABR not only enhances the mass transfer of NO from gas to liquid phase but also minimize the impact of oxygen on the microorganisms. This review provides the current advances of the development of the CABR process for NO x removal from the flue gas.

  13. An advanced passive diffusion sampler for the determination of dissolved gas concentrations

    NASA Astrophysics Data System (ADS)

    Gardner, P.; Solomon, D. K.

    2009-06-01

    We have designed and tested a passive headspace sampler for the collection of noble gases that allows for the precise calculation of dissolved gas concentrations from measured gas mixing ratios. Gas permeable silicon tubing allows for gas exchange between the headspace in the sampler volume and the dissolved gases in the adjacent water. After reaching equilibrium, the aqueous-phase concentration is related to the headspace concentration by Henry's law. Gas exchange between the water and headspace can be shut off in situ, preserving the total dissolved gas pressure upon retrieval. Gas samples are then sealed in an all metal container, retaining even highly mobile helium. Dissolved noble gas concentrations measured in these diffusion samplers are in good agreement with traditional copper tube aqueous-phase samples. These significantly reduce the laboratory labor in extracting the gases from a water sample and provide a simple and robust method for collecting dissolved gas concentrations in a variety of aqueous environments.

  14. Process Modeling Phase I Summary Report for the Advanced Gas Reactor Fuel Development and Qualification Program

    SciTech Connect

    Pannala, Sreekanth; Daw, C Stuart; Boyalakuntla, Dhanunjay S; FINNEY, Charles E A

    2006-09-01

    This report summarizes the results of preliminary work at Oak Ridge National Laboratory (ORNL) to demonstrate application of computational fluid dynamics modeling to the scale-up of a Fluidized Bed Chemical Vapor Deposition (FBCVD) process for nuclear fuels coating. Specifically, this work, referred to as Modeling Scale-Up Phase I, was conducted between January 1, 2006 and March 31, 2006 in support of the Advanced Gas Reactor (AGR) Program. The objective was to develop, demonstrate and "freeze" a version of ORNL's computational model of the TRI ISOtropic (TRISO) fuel-particle coating process that can be specifically used to assist coater scale-up activities as part of the production of AGR-2 fuel. The results in this report are intended to serve as input for making decisions about initiating additional FBCVD modeling work (referred to as Modeling Scale-Up Phase II) in support of AGR-2. The main computational tool used to implement the model is the general-purpose multiphase fluid-dynamics computer code known as MFIX (Multiphase Flow with Interphase eXchanges), which is documented in detail on the DOE-sponsored website http://www.mfix.org. Additional computational tools are also being developed by ORNL for post-processing MFIX output to efficiently summarize the important information generated by the coater simulations. The summarized information includes quantitative spatial and temporal measures (referred to as discriminating characteristics, or DCs) by which different coater designs and operating conditions can be compared and correlated with trends in product quality. The ORNL FBCVD modeling work is being conducted in conjunction with experimental coater studies at ORNL with natural uranium CO (NUCO) and surrogate fuel kernels. Data are also being obtained from ambient-temperature, spouted-bed characterization experiments at the University of Tennessee and theoretical studies of carbon and silicon carbide chemical vapor deposition kinetics at Iowa State

  15. Advanced fuel gas desulfurization (AFGD) demonstration project. Technical progress report No. 19, July 1, 1994--September 30, 1994

    SciTech Connect

    1995-12-01

    The {open_quotes}Advanced Flue Gas Desulfurization (AFGD) Demonstration Project{close_quotes} is a $150.5 million cooperative effort between the U.S. Department of Energy and Pure Air, a general partnership of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc. The AFGD process is one of several alternatives to conventional flue gas desulfurization (FGD) being demonstrated under the Department of Energy`s Clean Coal Technology Demonstration Program. The AFGD demonstration project is located at the Northern Indiana Public Service Company`s Bailly Generating Station, about 12 miles northeast of Gary, Indiana.

  16. Recent advances of packed column technology for gas dehydration and absorbent regeneration in arctic and off-shore gas production

    SciTech Connect

    Chen, G.K.

    1987-01-01

    In-depth revamp of dehydration and regeneration trayed columns with proprietary structured packings in arctic gas production will be presented in terms of throughput increase and mass transfer efficiency improvement achieved. Mathematical expressions that relate the column performance to operating variables such as absorbent temperature and concentration, ratio of absorbent to gas, degree of dehydration/regeneration and number of transfer units available are described. Equipment specification and performance between conventional tray design and packed column for off-shore application are also included. Initial capital investment versus subsequent net savings of numerous commercial installations are discussed.

  17. Fabrication and Comparison of Fuels for Advanced Gas Reactor Irradiation Tests

    SciTech Connect

    Jeffrey Phillips; Charles Barnes; John Hunn

    2010-10-01

    As part of the program to demonstrate TRISO-coated fuel for the Next Generation Nuclear Plant, a series of irradiation tests of Advanced Gas Reactor (AGR) fuel are being performed in the Advanced Test Reactor (ATR) at the Idaho National Laboratory. In the first test, called “AGR-1,” graphite compacts containing approximately 300,000 coated particles were irradiated from December 2006 until November 2009. Development of AGR-1 fuel sought to replicate the properties of German TRISO-coated particles. No particle failures were seen in the nearly 3-year irradiation to a burn up of 19%. The AGR-1 particles were coated in a two-inch diameter coater. Following fabrication of AGR-1 fuel, process improvements and changes were made in each of the fabrication processes. Changes in the kernel fabrication process included replacing the carbon black powder feed with a surface-modified carbon slurry and shortening the sintering schedule. AGR-2 TRISO particles were produced in a six-inch diameter coater using a change size about twenty-one times that of the two-inch diameter coater used to coat AGR-1 particles. Changes were also made in the compacting process, including increasing the temperature and pressure of pressing and using a different type of press. Irradiation of AGR-2 fuel began in late spring 2010. Properties of AGR-2 fuel compare favorably with AGR-1 and historic German fuel. Kernels are more homogeneous in shape, chemistry and density. TRISO-particle sphericity, layer thickness standard deviations, and defect fractions are also comparable. In a sample of 317,000 particles from deconsolidated AGR-2 compacts, 3 exposed kernels were found in a leach test. No SiC defects were found in a sample of 250,000 deconsolidated particles, and no IPyC defects in a sample of 64,000 particles. The primary difference in properties between AGR-1 and AGR-2 compacts is that AGR-2 compacts have a higher matrix density, 1.6 g/cm3 compared to about 1.3 g/cm3 for AGR-1 compacts. Based on

  18. FABRICATION PROCESS AND PRODUCT QUALITY IMPROVEMENTS IN ADVANCED GAS REACTOR UCO KERNELS

    SciTech Connect

    Charles M Barnes

    2008-09-01

    A major element of the Advanced Gas Reactor (AGR) program is developing fuel fabrication processes to produce high quality uranium-containing kernels, TRISO-coated particles and fuel compacts needed for planned irradiation tests. The goals of the AGR program also include developing the fabrication technology to mass produce this fuel at low cost. Kernels for the first AGR test (“AGR-1) consisted of uranium oxycarbide (UCO) microspheres that werre produced by an internal gelation process followed by high temperature steps tot convert the UO3 + C “green” microspheres to first UO2 + C and then UO2 + UCx. The high temperature steps also densified the kernels. Babcock and Wilcox (B&W) fabricated UCO kernels for the AGR-1 irradiation experiment, which went into the Advance Test Reactor (ATR) at Idaho National Laboratory in December 2006. An evaluation of the kernel process following AGR-1 kernel production led to several recommendations to improve the fabrication process. These recommendations included testing alternative methods of dispersing carbon during broth preparation, evaluating the method of broth mixing, optimizing the broth chemistry, optimizing sintering conditions, and demonstrating fabrication of larger diameter UCO kernels needed for the second AGR irradiation test. Based on these recommendations and requirements, a test program was defined and performed. Certain portions of the test program were performed by Oak Ridge National Laboratory (ORNL), while tests at larger scale were performed by B&W. The tests at B&W have demonstrated improvements in both kernel properties and process operation. Changes in the form of carbon black used and the method of mixing the carbon prior to forming kernels led to improvements in the phase distribution in the sintered kernels, greater consistency in kernel properties, a reduction in forming run time, and simplifications to the forming process. Process parameter variation tests in both forming and sintering steps led

  19. LOW-ENGINE-FRICTION TECHNOLOGY FOR ADVANCED NATURAL-GAS RECIPROCATING ENGINES

    SciTech Connect

    Victor Wong; Tian Tian; Luke Moughon; Rosalind Takata; Jeffrey Jocsak

    2005-09-30

    This program aims at improving the efficiency of advanced natural-gas reciprocating engines (ANGRE) by reducing piston and piston ring assembly friction without major adverse effects on engine performance, such as increased oil consumption and wear. An iterative process of simulation, experimentation and analysis is being followed towards achieving the goal of demonstrating a complete optimized low-friction engine system. To date, a detailed set of piston and piston-ring dynamic and friction models have been developed and applied that illustrate the fundamental relationships between design parameters and friction losses. Low friction ring designs have already been recommended in a previous phase, with full-scale engine validation partially completed. Current accomplishments include the addition of several additional power cylinder design areas to the overall system analysis. These include analyses of lubricant and cylinder surface finish and a parametric study of piston design. The Waukesha engine was found to be already well optimized in the areas of lubricant, surface skewness and honing cross-hatch angle, where friction reductions of 12% for lubricant, and 5% for surface characteristics, are projected. For the piston, a friction reduction of up to 50% may be possible by controlling waviness alone, while additional friction reductions are expected when other parameters are optimized. A total power cylinder friction reduction of 30-50% is expected, translating to an engine efficiency increase of two percentage points from its current baseline towards the goal of 50% efficiency. Key elements of the continuing work include further analysis and optimization of the engine piston design, in-engine testing of recommended lubricant and surface designs, design iteration and optimization of previously recommended technologies, and full-engine testing of a complete, optimized, low-friction power cylinder system.

  20. Overview of advanced Stirling and gas turbine engine development programs and implications for solar thermal electrical applications

    SciTech Connect

    Alger, D.

    1984-03-01

    The DOE automotive advanced engine development projects managed by the NASA Lewis Research Center were described. These included one Stirling cycle engine development and two air Brayton cycle development. Other engine research activities included: (1) an air Brayton engine development sponsored by the Gas Research Institute, and (2) plans for development of a Stirling cycle engine for space use. Current and potential use of these various engines with solar parabolic dishes were discussed.

  1. Overview of Advanced Stirling and Gas Turbine Engine Development Programs and Implications for Solar Thermal Electrical Applications

    NASA Technical Reports Server (NTRS)

    Alger, D.

    1984-01-01

    The DOE automotive advanced engine development projects managed by the NASA Lewis Research Center were described. These included one Stirling cycle engine development and two air Brayton cycle development. Other engine research activities included: (1) an air Brayton engine development sponsored by the Gas Research Institute, and (2) plans for development of a Stirling cycle engine for space use. Current and potential use of these various engines with solar parabolic dishes were discussed.

  2. Coal-fired open-cycle liquid-metal magnetohydrodynamic topping cycle for retrofit of steam power plants. [Two-phase working fluid composed of coal combustion products and liquid copper

    SciTech Connect

    Pierson, E. S.; Herman, H.; Petrick, M.; Boom, R. W.; Carlson, L.; Cohen, D.; Dubey, G.; Grammel, S. J.; Schreiner, F.; Snyder, B. K.; Zinneman, T.

    1980-12-01

    The application of the new, coal-fired open-cycle liquid-metal MHD (OC-LMMHD) energy-conversion system to the retrofit of an existing, oil- or gas-fired conventional steam power plant is evaluated. The criteria used to evaluate the retrofit are the new plant efficiency and the cost benefit relative to other options, i.e., continuing to burn oil, a conventional retrofit to burn coal (if possible), and an over-the-fence gasifier for boilers that cannot burn coal directly. The OC-LMMHD cycle and the existing steam plant used in the study are discussed, and a detailed description of the retrofit plant is presented. The latter includes plant drawings, description of the coupling of the OC-LMMHD topping cycle and the steam boiler, drawings and descriptions of the major components in the retrofit plant, and costs. The unique capability of the OC-LMMHD cycle to control the pollutants normally associated with burning coal is discussed. The net plant output powers and efficiencies are calculated, with allowances for the required auxiliary powers and component inefficiencies, and a plant lifetime economic analysis performed by an architect/engineer. The efficiency and cost results are compared with the values for the other options.

  3. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Unknown

    2002-03-31

    The objectives of this report period were to complete the development of the Gas Generator design, which was done; fabricate and test of the non-polluting unique power turbine drive gas Gas Generator, which has been postponed. Focus during this report period has been to complete the brazing and bonding necessary to fabricate the Gas Generator hardware, continue making preparations for fabricating and testing the Gas Generator, and continuing the fabrication of the Gas Generator hardware and ancillary hardware in preparation for the test program. Fabrication is more than 95% complete and is expected to conclude in early May 2002. the test schedule was affected by relocation of the testing to another test supplier. The target test date for hot fire testing is now not earlier than June 15, 2002.

  4. LOW-ENGINE-FRICTION TECHNOLOGY FOR ADVANCED NATURAL-GAS RECIPROCATING ENGINES

    SciTech Connect

    Victor Wong; Tian Tian; Luke Moughon; Rosalind Takata; Jeffrey Jocsak

    2006-03-31

    This program aims at improving the efficiency of advanced natural-gas reciprocating engines (ANGRE) by reducing piston and piston ring assembly friction without major adverse effects on engine performance, such as increased oil consumption and wear. An iterative process of simulation, experimentation and analysis is being followed towards achieving the goal of demonstrating a complete optimized low-friction engine system. To date, a detailed set of piston and piston-ring dynamic and friction models have been developed and applied that illustrate the fundamental relationships among mechanical, surface/material and lubricant design parameters and friction losses. Demonstration of low-friction ring-pack designs in the Waukesha VGF 18GL engine confirmed total engine FEMP (friction mean effective pressure) reduction of 7-10% from the baseline configuration without significantly increasing oil consumption or blow-by flow. This represents a substantial (30-40%) reduction of the ringpack friction alone. The measured FMEP reductions were in good agreement with the model predictions. Further improvements via piston, lubricant, and surface designs offer additional opportunities. Tests of low-friction lubricants are in progress and preliminary results are very promising. The combined analysis of lubricant and surface design indicates that low-viscosity lubricants can be very effective in reducing friction, subject to component wear for extremely thin oils, which can be mitigated with further lubricant formulation and/or engineered surfaces. Hence a combined approach of lubricant design and appropriate wear reduction offers improved potential for minimum engine friction loss. Piston friction studies indicate that a flatter piston with a more flexible skirt, together with optimizing the waviness and film thickness on the piston skirt offer significant friction reduction. Combined with low-friction ring-pack, material and lubricant parameters, a total power cylinder friction

  5. Advanced SiC/SiC Ceramic Composites For Gas-Turbine Engine Components

    NASA Technical Reports Server (NTRS)

    Yun, H. M.; DiCarlo, J. A.; Easler, T. E.

    2004-01-01

    NASA Glenn Research Center (GRC) is developing a variety of advanced SiC/SiC ceramic composite (ASC) systems that allow these materials to operate for hundreds of hours under stress in air at temperatures approaching 2700 F. These SiC/SiC composite systems are lightweight (approximately 30% metal density) and, in comparison to monolithic ceramics and carbon fiber-reinforced ceramic composites, are able to reliably retain their structural properties for long times under aggressive gas-turbine engine environments. The key for the ASC systems is related first to the NASA development of the Sylramic-iBN Sic fiber, which displays higher thermal stability than any other SiC- based ceramic fibers and possesses an in-situ grown BN surface layer for higher environmental durability. This fiber is simply derived from Sylramic Sic fiber type that is currently produced at ATK COI Ceramics (COIC). Further capability is then derived by using chemical vapor infiltration (CVI) and/or polymer infiltration and pyrolysis (PIP) to form a Sic-based matrix with high creep and rupture resistance as well as high thermal conductivity. The objectives of this study were (1) to optimize the constituents and processing parameters for a Sylramic-iBN fiber reinforced ceramic composite system in which the Sic-based matrix is formed at COIC almost entirely by PIP (full PIP approach), (2) to evaluate the properties of this system in comparison to other 2700 F Sylramic-iBN systems in which the matrix is formed by full CVI and CVI + PIP, and (3) to examine the pros and cons of the full PIP approach for fabricating hot-section engine components. A key goal is the development of a composite system with low porosity, thereby providing high modulus, high matrix cracking strength, high interlaminar strength, and high thermal conductivity, a major property requirement for engine components that will experience high thermal gradients during service. Other key composite property goals are demonstration at

  6. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Unknown

    2001-10-30

    The objectives of this report period were to continue the development of the Gas Generator design, to complete the hardware and ancillary hardware fabrication, and commence the Test Preparations for the testing of the non-polluting unique power turbine drive gas generator. Focus during this report period has been on testing the Gas Generator. Because of unacceptable delays encountered in a previously competitively selected test site, CES initiated a re-competition of our testing program and selected an alternate test site. Following that selection, CES used all available resources to make preparations for testing the 10 Mw Gas Generator at the new testing site facilities of NTS at Saugus, CA. A substantial portion of this report period was devoted to Testing Preparations, i.e. test facility development, cold- flow testing, calibration testing, performing igniter ignition testing, and then commencement of the completely assembled Gas Generator Assembly Testing, in process at this writing.

  7. Advancing New 3D Seismic Interpretation Methods for Exploration and Development of Fractured Tight Gas Reservoirs

    SciTech Connect

    James Reeves

    2005-01-31

    In a study funded by the U.S. Department of Energy and GeoSpectrum, Inc., new P-wave 3D seismic interpretation methods to characterize fractured gas reservoirs are developed. A data driven exploratory approach is used to determine empirical relationships for reservoir properties. Fractures are predicted using seismic lineament mapping through a series of horizon and time slices in the reservoir zone. A seismic lineament is a linear feature seen in a slice through the seismic volume that has negligible vertical offset. We interpret that in regions of high seismic lineament density there is a greater likelihood of fractured reservoir. Seismic AVO attributes are developed to map brittle reservoir rock (low clay) and gas content. Brittle rocks are interpreted to be more fractured when seismic lineaments are present. The most important attribute developed in this study is the gas sensitive phase gradient (a new AVO attribute), as reservoir fractures may provide a plumbing system for both water and gas. Success is obtained when economic gas and oil discoveries are found. In a gas field previously plagued with poor drilling results, four new wells were spotted using the new methodology and recently drilled. The wells have estimated best of 12-months production indicators of 2106, 1652, 941, and 227 MCFGPD. The latter well was drilled in a region of swarming seismic lineaments but has poor gas sensitive phase gradient (AVO) and clay volume attributes. GeoSpectrum advised the unit operators that this location did not appear to have significant Lower Dakota gas before the well was drilled. The other three wells are considered good wells in this part of the basin and among the best wells in the area. These new drilling results have nearly doubled the gas production and the value of the field. The interpretation method is ready for commercialization and gas exploration and development. The new technology is adaptable to conventional lower cost 3D seismic surveys.

  8. Advanced turbine systems program conceptual design and product development task 5 -- market study of the gas fired ATS. Topical report

    SciTech Connect

    1995-05-01

    Solar Turbines Incorporated (Solar), in partnership with the Department of Energy, will develop a family of advanced gas turbine-based power systems (ATS) for widespread commercialization within the domestic and international industrial marketplace, and to the rapidly changing electric power generation industry. The objective of the jointly-funded Program is to introduce an ATS with high efficiency, and markedly reduced emissions levels, in high numbers as rapidly as possible following introduction. This Topical Report is submitted in response to the requirements outlined in Task 5 of the Department of Energy METC Contract on Advanced Combustion Systems, Contract No, DE AC21-93MC30246 (Contract), for a Market Study of the Gas Fired Advanced Turbine System. It presents a market study for the ATS proposed by Solar, and will examine both the economic and siting constraints of the ATS compared with competing systems in the various candidate markets. Also contained within this report is an examination and analysis of Solar`s ATS and its ability to compete in future utility and industrial markets, as well as factors affecting the marketability of the ATS.

  9. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Unknown

    2002-01-31

    The objective of this report period was to continue the development of the Gas Generator design, fabrication and test of the non-polluting unique power turbine drive Gas Generator. Focus during this past report period has been to continue completion the Gas Generator design, completing the brazing and bonding experiments to determine the best method and materials necessary to fabricate the Gas Generator hardware, continuing to making preparations for fabricating and testing this Gas Generator and commencing with the fabrication of the Gas Generator hardware and ancillary hardware. Designs have been completed sufficiently such that Long Lead Items [LLI] have been ordered and upon arrival will be readied for the fabrication process. The keys to this design are the platelet construction of the injectors that precisely measures/meters the flow of the propellants and water all throughout the steam generating process and the CES patented gas generating cycle. The Igniter Assembly injector platelets fabrication process has been completed and bonded to the Igniter Assembly and final machined. The Igniter Assembly is in final assembly and is being readied for testing in the October 2001 time frame. Test Plan dated August 2001, was revised and finalized, replacing Test Plan dated May 2001.

  10. Advanced technology cogeneration system conceptual design study: Closed cycle gas turbines

    NASA Technical Reports Server (NTRS)

    Mock, E. A. T.; Daudet, H. C.

    1983-01-01

    The results of a three task study performed for the Department of Energy under the direction of the NASA Lewis Research Center are documented. The thermal and electrical energy requirements of three specific industrial plants were surveyed and cost records for the energies consumed were compiled. Preliminary coal fired atmospheric fluidized bed heated closed cycle gas turbine and steam turbine cogeneration system designs were developed for each industrial plant. Preliminary cost and return-on-equity values were calculated and the results compared. The best of the three sites was selected for more detailed design and evaluation of both closed cycle gas turbine and steam turbine cogeneration systems during Task II. Task III involved characterizing the industrial sector electrical and thermal loads for the 48 contiguous states, applying a family of closed cycle gas turbine and steam turbine cogeneration systems to these loads, and conducting a market penetration analysis of the closed cycle gas turbine cogeneration system.

  11. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    E.W. Baxter

    2002-06-30

    The objective of this report period was to continue the development of the Gas Generator design, completion of the hardware and ancillary hardware fabrication and commence the Test Preparations for the testing of the non-polluting unique power turbine driven Gas Generator. Focus during this report period has been on completing the Gas Generator fabrication of hardware and ancillary hardware, and completion of unit closeout brazing and bonding. Because of unacceptable delays encountered in a previously competitively selected test site, CES initiated a re-competition of our testing program and selected an alternate test site. Following that selection, CES used all available resources to make preparations for testing the 10 Mw Gas Generator at the new testing site facilities of NTS at Saugus, CA.

  12. TiO2 Nanotubes: Recent Advances in Synthesis and Gas Sensing Properties

    PubMed Central

    Galstyan, Vardan; Comini, Elisabetta; Faglia, Guido; Sberveglieri, Giorgio

    2013-01-01

    Synthesis—particularly by electrochemical anodization-, growth mechanism and chemical sensing properties of pure, doped and mixed titania tubular arrays are reviewed. The first part deals on how anodization parameters affect the size, shape and morphology of titania nanotubes. In the second part fabrication of sensing devices based on titania nanotubes is presented, together with their most notable gas sensing performances. Doping largely improves conductivity and enhances gas sensing performances of TiO2 nanotubes. PMID:24184919

  13. FABRICATE AND TEST AN ADVANCED NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Eugene Baxter; Roger E. Anderson; Stephen E. Doyle

    2003-06-01

    In September 2000 the Department of Energy's National Energy Technology Laboratory (DOE/NETL) contracted with Clean Energy Systems, Inc. (CES) of Sacramento, California to design, fabricate, and test a 20 MW{sub t} (10 MW{sub e}) gas generator. Program goals were to demonstrate a non-polluting gas generator at temperatures up to 3000 F at 1500 psi, and to demonstrate resulting drive gas composition, comprising steam and carbon dioxide substantially free of pollutants. Following hardware design and fabrication, testing, originally planned to begin in the summer of 2001, was delayed by unavailability of the contracted test facility. CES designed, fabricated, and tested the proposed gas generator as originally agreed. The CES process for producing near-zero-emissions power from fossil fuels is based on the near-stoichiometric combustion of a clean gaseous fuel with oxygen in the presence of recycled water, to produce a high-temperature, high-pressure turbine drive fluid comprising steam and carbon dioxide. Tests demonstrated igniter operation over the prescribed ranges of pressure and mixture ratios. Ignition was repeatable and reliable through more than 100 ignitions. Injector design ''A'' was operated successfully at both low power ({approx}20% of rated power) and at rated power ({approx}20 MW{sub t}) in more than 95 tests. The uncooled gas generator configuration (no diluent injectors or cooldown chambers installed) produced drive gases at temperatures approaching 3000 F and at pressures greater than 1550 psia. The fully cooled gas generator configuration, with cooldown chambers and injector ''A'', operated consistently at pressures from 1100 to 1540 psia and produced high pressure, steam-rich turbine drive gases at temperatures ranging from {approx}3000 to as low as 600 F. This report includes description of the intended next steps in the gas generator technology demonstration and traces the anticipated pathway to commercialization for the gas generator technology

  14. Final Assembly and Initial Irradiation of the First Advanced Gas Reactor Fuel Development and Qualification Experiment in the Advanced Test Reactor

    SciTech Connect

    S. B. Grover

    2007-05-01

    The United States Department of Energy’s Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating eight separate low enriched uranium (LEU) oxycarbide (UCO) tri-isotropic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The ATR has a long history of irradiation testing in support of reactor development and the INL has been designated as the new United States Department of Energy’s lead laboratory for nuclear energy development. The ATR is one of the world’s premiere test reactors for performing long term, high flux, and/or large volume irradiation test programs. These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The AGR fuel experiments will be irradiated over the next ten years to demonstrate and qualify new particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing.1,2 The experiments, which will each consist of six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The final design phase for the first experiment was completed in 2005, and the fabrication and assembly of the first experiment test train (designated AGR-1) as well as the support systems and fission product monitoring system that will monitor and control the experiment

  15. Results from the DOE Advanced Gas Reactor Fuel Development and Qualification Program

    SciTech Connect

    David Petti

    2014-06-01

    Modular HTGR designs were developed to provide natural safety, which prevents core damage under all design basis accidents and presently envisioned severe accidents. The principle that guides their design concepts is to passively maintain core temperatures below fission product release thresholds under all accident scenarios. This level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude and allows potential elimination of the need for evacuation and sheltering beyond a small exclusion area. This level, however, is predicated on exceptionally high fuel fabrication quality and performance under normal operation and accident conditions. Germany produced and demonstrated high quality fuel for their pebble bed HTGRs in the 1980s, but no U.S. manufactured fuel had exhibited equivalent performance prior to the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. The design goal of the modular HTGRs is to allow elimination of an exclusion zone and an emergency planning zone outside the plant boundary fence, typically interpreted as being about 400 meters from the reactor. To achieve this, the reactor design concepts require a level of fuel integrity that is better than that claimed for all prior US manufactured TRISO fuel, by a few orders of magnitude. The improved performance level is about a factor of three better than qualified for German TRISO fuel in the 1980’s. At the start of the AGR program, without a reactor design concept selected, the AGR fuel program selected to qualify fuel to an operating envelope that would bound both pebble bed and prismatic options. This resulted in needing a fuel form that could survive at peak fuel temperatures of 1250°C on a time-averaged basis and high burnups in the range of 150 to 200 GWd/MTHM (metric tons of heavy metal) or 16.4 to 21.8% fissions per initial metal atom (FIMA). Although Germany has demonstrated excellent performance of TRISO-coated UO

  16. Low-Engine-Friction Technology for Advanced Natural-Gas Reciprocating Engines

    SciTech Connect

    Victor Wong; Tian Tian; G. Smedley; L. Moughon; Rosalind Takata; J. Jocsak

    2006-11-30

    This program aims at improving the efficiency of advanced natural-gas reciprocating engines (ANGRE) by reducing piston and piston ring assembly friction without major adverse effects on engine performance, such as increased oil consumption and wear. An iterative process of simulation, experimentation and analysis has been followed towards achieving the goal of demonstrating a complete optimized low-friction engine system. In this program, a detailed set of piston and piston-ring dynamic and friction models have been adapted and applied that illustrate the fundamental relationships among mechanical, surface/material and lubricant design parameters and friction losses. Demonstration of low-friction ring-pack designs in the Waukesha VGF 18GL engine confirmed ring-pack friction reduction of 30-40%, which translates to total engine FEMP (friction mean effective pressure) reduction of 7-10% from the baseline configuration without significantly increasing oil consumption or blow-by flow. The study on surface textures, including roughness characteristics, cross hatch patterns, dimples and grooves have shown that even relatively small-scale changes can have a large effect on ring/liner friction, in some cases reducing FMEP by as much as 30% from a smooth surface case. The measured FMEP reductions were in good agreement with the model predictions. The combined analysis of lubricant and surface design indicates that low-viscosity lubricants can be very effective in reducing friction, subject to component wear for extremely thin oils, which can be mitigated with further lubricant formulation and/or engineered surfaces. Hence a combined approach of lubricant design and appropriate wear reduction offers improved potential for minimum engine friction loss. Testing of low-friction lubricants showed that total engine FMEP reduced by up to {approx}16.5% from the commercial reference oil without significantly increasing oil consumption or blow-by flow. Piston friction studies

  17. Advanced industrial gas turbine technology readiness demonstration program. Phase II. Final report: compressor rig fabrication assembly and test

    SciTech Connect

    Schweitzer, J. K.; Smith, J. D.

    1981-03-01

    The results of a component technology demonstration program to fabricate, assemble and test an advanced axial/centrifugal compressor are presented. This work was conducted to demonstrate the utilization of advanced aircraft gas turbine cooling and high pressure compressor technology to improve the performance and reliability of future industrial gas turbines. Specific objectives of the compressor component testing were to demonstrate 18:1 pressure ratio on a single spool at 90% polytropic efficiency with 80% fewer airfoils as compared to current industrial gas turbine compressors. The compressor design configuration utilizes low aspect ratio/highly-loaded axial compressor blading combined with a centrifugal backend stage to achieve the 18:1 design pressure ratio in only 7 stages and 281 axial compressor airfoils. Initial testing of the compressor test rig was conducted with a vaneless centrifugal stage diffuser to allow documentation of the axial compressor performance. Peak design speed axial compressor performance demonstrated was 91.8% polytropic efficiency at 6.5:1 pressure ratio. Subsequent documentation of the combined axial/centrifugal performance with a centrifugal stage pipe diffuser resulted in the demonstration of 91.5% polytropic efficiency and 14% stall margin at the 18:1 overall compressor design pressure ratio. The demonstrated performance not only exceeded the contract performance goals, but also represents the highest known demonstrated compressor performance in this pressure ratio and flow class. The performance demonstrated is particularly significant in that it was accomplished at airfoil loading levels approximately 15% higher than that of current production engine compressor designs. The test results provide conclusive verification of the advanced low aspect ratio axial compressor and centrifugal stage technologies utilized.

  18. Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program. Progress report, January 1, 1980-March 31, 1980

    SciTech Connect

    Not Available

    1980-06-25

    Results are presented of work performed on the Advanced Gas-Cooled Nuclear Reactor Materials Evaluation and Development Program. The objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Nuclear Process Heat (NPH) and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (helium containing small amounts of various other gases), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Included are the activities associated with the status of the simulated reactor helium supply system, testing equipment and gas chemistry analysis instrumentation and equipment. The progress in the screening test program is described, including screening creep results and metallographic analysis for materials thermally exposed or tested at 750, 850, and 950/sup 0/C.

  19. Advanced Gas-Cooled Nuclear Reactor Materials Evaluation and Development Program. Progress report, July 1, 1979-September 30, 1979

    SciTech Connect

    Not Available

    1980-03-07

    The results of work performed from July 1, 1979 through September 30, 1979 on the Advanced Gas-Cooled Nuclear Reactor Materials Evaluation and Development Program are presented. The objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Nuclear Process Heat (NPH) and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (helium containing small amounts of various other gases), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Work covered in this report includes the activities associated with the status of the simulated reactor helium supply system, testing equipment, and gas chemistry analysis instrumentation and equipment. The status of the data management system is presented. In addition, the progress in the screening test program is described.

  20. Development of a high-temperature durable catalyst for use in catalytic combustors for advanced automotive gas turbine engines

    NASA Technical Reports Server (NTRS)

    Tong, H.; Snow, G. C.; Chu, E. K.; Chang, R. L. S.; Angwin, M. J.; Pessagno, S. L.

    1981-01-01

    Durable catalytic reactors for advanced gas turbine engines were developed. Objectives were: to evaluate furnace aging as a cost effective catalytic reactor screening test, measure reactor degradation as a function of furnace aging, demonstrate 1,000 hours of combustion durability, and define a catalytic reactor system with a high probability of successful integration into an automotive gas turbine engine. Fourteen different catalytic reactor concepts were evaluated, leading to the selection of one for a durability combustion test with diesel fuel for combustion conditions. Eight additional catalytic reactors were evaluated and one of these was successfully combustion tested on propane fuel. This durability reactor used graded cell honeycombs and a combination of noble metal and metal oxide catalysts. The reactor was catalytically active and structurally sound at the end of the durability test.

  1. Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems

    SciTech Connect

    Pickrell, Gary; Scott, Brian

    2014-06-30

    This report covers the technical progress on the program “Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems”, funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed by the Materials Science & Engineering and Electrical & Computer Engineering Departments at Virginia Tech, and summarizes technical progress from July 1st, 2005 –June 30th, 2014. The objective of this program was to develop novel fiber materials for high temperature gas sensors based on evanescent wave absorption in optical fibers. This project focused on two primary areas: the study of a sapphire photonic crystal fiber (SPCF) for operation at high temperature and long wavelengths, and a porous glass based fiber optic sensor for gas detection. The sapphire component of the project focused on the development of a sapphire photonic crystal fiber, modeling of the new structures, fabrication of the optimal structure, development of a long wavelength interrogation system, testing of the optical properties, and gas and temperature testing of the final sensor. The fabrication of the 6 rod SPCF gap bundle (diameter of 70μm) with a hollow core was successfully constructed with lead-in and lead-out 50μm diameter fiber along with transmission and gas detection testing. Testing of the sapphire photonic crystal fiber sensor capabilities with the developed long wavelength optical system showed the ability to detect CO2 at or below 1000ppm at temperatures up to 1000°C. Work on the porous glass sensor focused on the development of a porous clad solid core optical fiber, a hollow core waveguide, gas detection capabilities at room and high temperature, simultaneous gas species detection, suitable joining technologies for the lead-in and lead-out fibers and the porous sensor, sensor system sensitivity improvement, signal processing improvement, relationship between pore structure and fiber

  2. Proof-of concept testing of the advanced NOXSO flue gas cleanup process. Final report

    SciTech Connect

    Not Available

    1993-04-01

    The NOXSO Process uses a regenerable sorbent that removes SO{sub 2} and NO{sub x} simultaneously from flue gas. The sorbent is a stabilized {gamma}-alumina bed impregnated with sodium carbonate. The process was successfully tested at three different scales, equivalent to 0.017, 0.06 and 0.75 MW of flue gas generated from a coal-fired power plant. The Proof-of-Concept (POC) Test is the last test prior to a full-scale demonstration. A slip stream of flue gas equivalent to a 5 MW coal-fired power plant was used for the POC test. This paper summarizes the NOXSO POC plant and its test results.

  3. Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream

    DOEpatents

    Kromer, Brian R.; Litwin, Michael M.; Kelly, Sean M.

    2016-09-27

    A method and system for generating electrical power in which a high pressure synthesis gas stream generated in a gasifier is partially oxidized in an oxygen transport membrane based reactor, expanded and thereafter, is combusted in an oxygen transport membrane based boiler. A low pressure synthesis gas slip stream is split off downstream of the expanders and used as the source of fuel in the oxygen transport membrane based partial oxidation reactors to allow the oxygen transport membrane to operate at low fuel pressures with high fuel utilization. The combustion within the boiler generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

  4. Oil and gas resources of the Fergana basin (Uzbekistan, Tadzhikistan, and Kyrgyzstan). Advance summary

    SciTech Connect

    Not Available

    1993-12-07

    The Energy Information Administration (EIA), in cooperation with the US Geological Survey (USGS), has assessed 13 major petroleum producing regions outside of the United States. This series of assessments has been performed under EIA`s Foreign Energy Supply Assessment Program (FESAP). The basic approach used in these assessments was to combine historical drilling, discovery, and production data with EIA reserve estimates and USGS undiscovered resource estimates. Field-level data for discovered oil were used for these previous assessments. In FESAP, supply projections through depletion were typically formulated for the country or major producing region. Until now, EIA has not prepared an assessment of oil and gas provinces in the former Soviet Union (FSU). Before breakup of the Soviet Union in 1991, the Fergana basin was selected for a trial assessment of its discovered and undiscovered oil and gas. The object was to see if enough data could be collected and estimated to perform reasonable field-level estimates of oil and gas in this basin. If so, then assessments of other basins in the FSU could be considered. The objective was met and assessments of other basins can be considered. Collected data for this assessment cover discoveries through 1987. Compared to most other oil and gas provinces in the FSU, the Fergana basin is relatively small in geographic size, and in number and size of most of its oil and gas fields. However, with recent emphasis given to the central graben as a result of the relatively large Mingbulak field, the basin`s oil and gas potential has significantly increased. At least 7 additional fields to the 53 fields analyzed are known and are assumed to have been discovered after 1987.

  5. Advanced gas turbine systems research. Technical quarterly progress report, October 1--December 31, 1997

    SciTech Connect

    1997-12-31

    Major accomplishments by AGTSR during this reporting period are highlighted and then amplified in later sections of this report. Main areas of research are combustion, heat transfer, and materials. Gas turbines are used for power generation by utilities and industry and for propulsion.

  6. Advanced gas turbine systems research. Technical quarterly progress report, January 1--March 31, 1998

    SciTech Connect

    1998-08-01

    Major accomplishments by AGTSR during this reporting period are highlighted and then amplified in later sections of this report. Main areas of research are combustion, heat transfer, and materials. Gas turbines are used for power generation by utilities and industry and for propulsion.

  7. Advanced gas turbine systems research. Quarterly technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect

    Not Available

    1994-07-01

    A cooperative development of gas turbines for electric power generation in USA is underway. Since the first AGTSR program manager has retired, a search for a new manager has begun. Reports during this period include membership, combustion instability white paper, and a summary paper for the ASME IGTI conference.

  8. Flight Testing of an Advanced Airborne Natural Gas Leak Detection System

    SciTech Connect

    Dawn Lenz; Raymond T. Lines; Darryl Murdock; Jeffrey Owen; Steven Stearns; Michael Stoogenke

    2005-10-01

    ITT Industries Space Systems Division (Space Systems) has developed an airborne natural gas leak detection system designed to detect, image, quantify, and precisely locate leaks from natural gas transmission pipelines. This system is called the Airborne Natural Gas Emission Lidar (ANGEL) system. The ANGEL system uses a highly sensitive differential absorption Lidar technology to remotely detect pipeline leaks. The ANGEL System is operated from a fixed wing aircraft and includes automatic scanning, pointing system, and pilot guidance systems. During a pipeline inspection, the ANGEL system aircraft flies at an elevation of 1000 feet above the ground at speeds of between 100 and 150 mph. Under this contract with DOE/NETL, Space Systems was funded to integrate the ANGEL sensor into a test aircraft and conduct a series of flight tests over a variety of test targets including simulated natural gas pipeline leaks. Following early tests in upstate New York in the summer of 2004, the ANGEL system was deployed to Casper, Wyoming to participate in a set of DOE-sponsored field tests at the Rocky Mountain Oilfield Testing Center (RMOTC). At RMOTC the Space Systems team completed integration of the system and flew an operational system for the first time. The ANGEL system flew 2 missions/day for the duration for the 5-day test. Over the course of the week the ANGEL System detected leaks ranging from 100 to 5,000 scfh.

  9. Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges.

    PubMed

    Abbatt, J P D; Lee, A K Y; Thornton, J A

    2012-10-07

    The interactions of trace gases with tropospheric aerosol can have significant effects on both gas phase and aerosol composition. In turn, this may affect the atmospheric oxidizing capacity, aerosol hygroscopicity and optical properties, and the lifetimes of trace aerosol species. Through the detailed description of specific reaction systems, this review article illustrates how detailed experimental studies of gas-particle interactions lead to both a comprehensive understanding of the underlying physical chemistry as well as accurate parameterizations for atmospheric modeling. The reaction systems studied illustrate the complexity in the field: (i) N(2)O(5) uptake, presented as a benchmark multiphase system, can lead to both NO(x) loss and halogen activation, (ii) loss of HO(2) on aqueous particles is surprisingly poorly studied given its potential importance for HO(x) loss, (iii) uptake of HNO(3) by marine aerosol and heterogeneous oxidation of organic-bearing particles are examples of how gas-particle interactions can lead to substantial alteration of aerosol composition, and (iv) the uptake of glyoxal to ammonium sulfate aerosol leads to highly complex particle-phase chemistry. In addition, for the first time, this article presents the challenges that must be addressed in the design and interpretation of atmospheric gas-to-particle uptake experiments.

  10. Advanced control improves MHC-VGO unit operation. [Mild HydroCracking-Vacuum Gas Oil

    SciTech Connect

    Richard, L.; Watson, D. ); Danzinger, F.; Tuppinger, D.; Schuster, R.; Wilmsen, W. )

    1995-03-01

    Constraint and multivariable predictive (MPC) controllers were implemented on an FCC preheater (MHC-VGO unit), which runs in mild hydrocracking (MHC) mode. In only a few weeks following commissioning, better control provided an average reduction in steam use of 38%, an average reduction of 22% in DEA use and a 5 to 10% reduction in fuel consumption. OMV's refinery in Schwechat was commissioned in 1960 and is now one of the largest and most complex inland-refineries in Europe with an annual crude oil processing capacity of 10 million metric tons. Every product stream is desulfurized by hydrodesulfurization (HDS) units. As part of a refinery-wide advanced control (ADVC) project which includes 27 units implemented on four process computers and two DCSs, advanced controls were installed on the MHC-VGO unit. The entire project was executed over a period of two and a half years. The paper describes the process, advanced control, the weighted average bed temperature controller, feed maximization control, stripper feed temperature control, stripping steam/feed ratio controller, stripper pressure minimization, H[sub 2]/oil controller, recycle/DEA ratio controller, stripper bottoms level controller, and advanced control benefits.

  11. Development of a high-temperature durable catalyst for use in catalytic combustors for advanced automotive gas turbine engines

    SciTech Connect

    Tong, H; Snow, G C; Chu, E K :; Chang, R L.S.; Angwin, M J; Pessagno, S L

    1981-09-01

    An experimental program was performed to develop durable catalytic reactors for advanced gas turbine engines. This program was performed as part of DOE's Gas Turbine Highway Vehicle Systems Project. Objectives of this program were to evaluate furnace aging as a cost-effective catalytic reactor screening test, measure reactor degradation as a function of furnace aging, demonstrate 1000 h of combustion durability, and define a catalytic reactor system with a high probability of successfful integration into an automotive gas turbine engine. In the first phase of this program, 14 different catalytic reactor concepts were evaluated, leading to the selection of one for a durability combustion test with diesel fuel at 1700 K combustion coditions. The durability reactor, a proprietary UOP noble metal catalyst, failed structurally after about 136 h and the catalyst was essentially inactive after about 226 h. In Phase II, eight additional catalytic reactors were evalated and one of these was sucessfully combustion-tested for 1000 h at 1700 K on propane fuel. This durability reactor used graded-cell honeycombs and a combination of noble metal and metal oxide catalysts. The reactor was catalytically active and structurally sound at the end of the durability test.

  12. Optical fiber evanescent wave adsorption sensors for high-temperature gas sensing in advanced coal-fired power plants

    SciTech Connect

    Buric, M.; Ohodnicky, P.; Duy, J.

    2012-01-01

    Modern advanced energy systems such as coal-fired power plants, gasifiers, or similar infrastructure present some of the most challenging harsh environments for sensors. The power industry would benefit from new, ultra-high temperature devices capable of surviving in hot and corrosive environments for embedded sensing at the highest value locations. For these applications, we are currently exploring optical fiber evanescent wave absorption spectroscopy (EWAS) based sensors consisting of high temperature core materials integrated with novel high temperature gas sensitive cladding materials. Mathematical simulations can be used to assist in sensor development efforts, and we describe a simulation code that assumes a single thick cladding layer with gas sensitive optical constants. Recent work has demonstrated that Au nanoparticle-incorporated metal oxides show a potentially useful response for high temperature optical gas sensing applications through the sensitivity of the localized surface plasmon resonance absorption peak to ambient atmospheric conditions. Hence, the simulation code has been applied to understand how such a response can be exploited in an optical fiber based EWAS sensor configuration. We demonstrate that interrogation can be used to optimize the sensing response in such materials.

  13. ADVANCED FRACTURING TECHNOLOGY FOR TIGHT GAS: AN EAST TEXAS FIELD DEMONSTRATION

    SciTech Connect

    Mukul M. Sharma

    2005-03-01

    The primary objective of this research was to improve completion and fracturing practices in gas reservoirs in marginal plays in the continental United States. The Bossier Play in East Texas, a very active tight gas play, was chosen as the site to develop and test the new strategies for completion and fracturing. Figure 1 provides a general location map for the Dowdy Ranch Field, where the wells involved in this study are located. The Bossier and other tight gas formations in the continental Unites States are marginal plays in that they become uneconomical at gas prices below $2.00 MCF. It was, therefore, imperative that completion and fracturing practices be optimized so that these gas wells remain economically attractive. The economic viability of this play is strongly dependent on the cost and effectiveness of the hydraulic fracturing used in its well completions. Water-fracs consisting of proppant pumped with un-gelled fluid is the type of stimulation used in many low permeability reservoirs in East Texas and throughout the United States. The use of low viscosity Newtonian fluids allows the creation of long narrow fractures in the reservoir, without the excessive height growth that is often seen with cross-linked fluids. These low viscosity fluids have poor proppant transport properties. Pressure transient tests run on several wells that have been water-fractured indicate a long effective fracture length with very low fracture conductivity even when large amounts of proppant are placed in the formation. A modification to the water-frac stimulation design was needed to transport proppant farther out into the fracture. This requires suspending the proppant until the fracture closes without generating excessive fracture height. A review of fracture diagnostic data collected from various wells in different areas (for conventional gel and water-fracs) suggests that effective propped lengths for the fracture treatments are sometimes significantly shorter than those

  14. Proof of concept testing of the advanced NOXSO flue gas cleanup process

    SciTech Connect

    Gilbert, R.L.

    1990-01-01

    The objective of this project is to demonstrate the potential for application of the NOXSO Flue Gas Treatment (FGT) technology to coal-fired utility boilers in the 1990s. To accomplish this, the NOXSO team will design, construct, operate, and test a proof-of-concept scale NOXSO test facility at Ohio Edison's Toronto Station. The goal of the proof-of-concept test is to obtain the engineering data required to prepare a cost-effective design of a commercial scale NOXSO process module at an acceptable level of technical risk. A secondary goal of the test program is to optimize process performance, i.e., achieve 90% removal of SO{sub 2} and NO{sub x} from the flue gas at the lowest possible cost, while maintaining the high level of system reliability dictated by the utility market. Progress is reported. 5 figs.

  15. Advanced low-NO(x) combustors for supersonic high-altitude gas turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.

    1977-01-01

    The impact of gas-turbine-engine-powered aircraft on worldwide pollution was defined within two major areas of contribution. First, the contribution of aircraft to the local air pollution of metropolitan areas and, second, the long-term effects on the chemical balance of the stratosphere of pollutants emitted from future generations of high-altitude, supersonic commercial and military aircraft. Preliminary findings indicate that stratospheric oxides of nitrogen (NOx) emissions may have to be limited to very low levels if, for example, ozone depletion with concomitant increases in sea-level radiation, are to be avoided. Theoretical considerations suggest that (NOx) levels as low as 1.0 gram per kilogram of fuel and less should be attainable from a idealized premixed type of combustor. Experimental rig studies were intended to explore new combustor concepts designed to minimize the formation of (NOx) in aircraft gas turbines and to define their major operational problems and limitations.

  16. Clean coal demonstration program: Advanced flue gas desulfurization process. Volume 1 - public design report

    SciTech Connect

    1990-03-01

    The single 100 percent absorber is a co-current grid packed tower with an integrated reaction tank at the bottom. It is designed to accomplish several process steps (quenching, absorption of SO{sub 2}, reaction with limestone, oxidation to gypsum) in a single vessel, resulting in a simple configuration of the plant. The co-current absorber is designed for higher flue gas velocities than conventional countercurrent towers, which results in a compact absorber size. The flue gas enters the top of the absorber where it contacts recirculating slurry. Quenching and absorption of SO{sub 2} occur simultaneously. This {open_quotes}wet/dry{close_quotes} interface is washed intermittently with fresh water to prevent the formation and growth of any deposits.

  17. Advanced Exploration Systems Logistics Reduction and Repurposing Trash-to-Gas and Heat Melt Compactor KSC

    NASA Technical Reports Server (NTRS)

    Caraccio, Anne J.; Layne, Andrew; Hummerick, Mary

    2013-01-01

    Topics covered: 1. Project Structure 2. "Trash to Gas" 3. "Smashing Trash! The Heat Melt Compactor" 4. "Heat Melt Compaction as an Effective Treatment for Eliminating Microorganisms from Solid Waste" Thermal degradation of trash reduces volume while creating water, carbon dioxide and ash. CO2 can be fed to Sabatier reactor for CH4 production to fuel LOX/LCH4 ascent vehicle. Optimal performance: HFWS, full temperature ramp to 500-600 C. Tar challenges exist. Catalysis: Dolomag did eliminate allene byproducts from the product stream. 2nd Gen Reactor Studies. Targeting power, mass, time efficiency. Gas separation, Catalysis to reduce tar formation. Microgravity effects. Downselect in August will determine where we should spend time optimizing the technology.

  18. Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment

    SciTech Connect

    Nick Soelberg

    2005-09-01

    Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

  19. High temperature corrosion of advanced ceramic materials for hot gas filters and heat exchangers. Final report

    SciTech Connect

    Kupp, E.R.; Trubelja, K.E.; Spear, K.E.; Tressler, R.E.

    1995-08-01

    Experimental corrosion studies of hot gas filter materials and heat exchanger materials in oxidizing combustion environments have been initiated. Filter materials from 3M Co. and DuPont Lanxide Composites Inc. are being tested over a range of temperatures, times and gas flows. It has been demonstrated that morphological and phase changes due to corrosive effects occur after exposure of these materials to a simulated coal combustion environment for relatively short periods of time (10-50 hours). Heat exchanger tubes from DuPont Lanxide Composite Inc. were cut and infiltrated with Cr by heating in a Cr{sub 2}O{sub 3} powder bed. This resulted in continuous Cr-rich layers with thicknesses ranging from 20 to 250 {mu}m. The Cr-free and the Cr-infiltrated specimens were reacted with the molten Illinois No. 6 slag for 2 and 20 h at 1260{degrees}C, and the reaction layers examined with SEM and EDX. In the Cr-free specimens, the segregation of Fe and the precipitation of Fe{sub 2}O{sub 3} were detected near the liquid/gas interface, but no evidence of corrosion was present. In the Cr-infiltrate specimens, corrosion was evident, since a rearrangement and segregation of the Cr-rich grains occurred toward the surface of the molten slag. In addition, evidence of the diffusion of major quantities of Fe was observed from the liquid slag into the Cr-rich layer formed by infiltration.

  20. Processing of Advanced Ceramics Which Have Potential for Use in Gas Turbine Aero Engines

    DTIC Science & Technology

    1989-02-01

    and Materials Laboratory/ G.F. Marsters Laboratofre de structures et materiaux Director/directeur ABSTRACT Si 3N4 and SiC based advanced ceramics that...Alumina, for example, maintains good corrosion resistance , good stiffness, and good strength at high temperatures, but exhibits very poor thermal shock... resistance ; an important property to be considered in the steep temperature gradients and with the rapid -2- temperature fluctuations that are developed

  1. Advanced thermal barrier coatings for operation in high hydrogen content fueled gas turbines.

    SciTech Connect

    Sampath, Sanjay

    2015-04-02

    The Center for Thermal Spray Research (CTSR) at Stony Brook University in partnership with its industrial Consortium for Thermal Spray Technology is investigating science and technology related to advanced metallic alloy bond coats and ceramic thermal barrier coatings for applications in the hot section of gasified coal-based high hydrogen turbine power systems. In conjunction with our OEM partners (GE and Siemens) and through strategic partnership with Oak Ridge National Laboratory (ORNL) (materials degradation group and high temperature materials laboratory), a systems approach, considering all components of the TBC (multilayer ceramic top coat, metallic bond coat & superalloy substrate) is being taken during multi-layered coating design, process development and subsequent environmental testing. Recent advances in process science and advanced in situ thermal spray coating property measurement enabled within CTSR has been incorporated for full-field enhancement of coating and process reliability. The development of bond coat processing during this program explored various aspects of processing and microstructure and linked them to performance. The determination of the bond coat material was carried out during the initial stages of the program. Based on tests conducted both at Stony Brook University as well as those carried out at ORNL it was determined that the NiCoCrAlYHfSi (Amdry) bond coats had considerable benefits over NiCoCrAlY bond coats. Since the studies were also conducted at different cycling frequencies, thereby addressing an associated need for performance under different loading conditions, the Amdry bond coat was selected as the material of choice going forward in the program. With initial investigations focused on the fabrication of HVOF bond coats and the performance of TBC under furnace cycle tests , several processing strategies were developed. Two-layered HVOF bond coats were developed to render optimal balance of density and surface roughness

  2. Recent advancements in the gas-phase MicroChemLab

    NASA Astrophysics Data System (ADS)

    Manginell, Ronald P.; Lewis, Patrick R.; Adkins, Douglas R.; Kottenstette, Richard J.; Wheeler, David; Sokolowski, Sara; Trudell, Dan; Byrnes, Joy; Okandan, Murat; Bauer, Joseph M.; Manley, Robert G.

    2004-12-01

    Sandia's hand-held MicroChemLabTM system uses a micromachined preconcentrator (PC), a gas chromatography channel (GC) and a quartz surface acoustic wave array (SAW) detector for sensitive/selective detection of gas-phase chemical analytes. Requisite system size, performance, power budget and time response mandate microfabrication of the key analytical system components. In the fielded system hybrid integration has been employed, permitting optimization of the individual components. Recent improvements in the hybrid-integrated system, using plastic, metal or silicon/glass manifolds, is described, as is system performance against semivolatile compounds and toxic industrial chemicals. The design and performance of a new three-dimensional micropreconcentrator is also introduced. To further reduce system dead volume, eliminate unheated transfer lines and simplify assembly, there is an effort to monolithically integrate the silicon PC and GC with a suitable silicon-based detector, such as a magnetically-actuated flexural plate wave sensor (magFPW) or a magnetically-actuated pivot plate resonator (PPR).

  3. Advanced separation technology for flue gas cleanup. Final report, February 1998

    SciTech Connect

    Bhown, A.S.; Alvarado, D.; Pakala, N.; Tagg, T.; Riggs, T.; Ventura, S.; Sirkar, K.K.; Majumdar, S.; Bhaumick, D.

    1998-06-01

    The objective of this work by SRI International was to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (1) a novel method for regenerating spent SO{sub 2} scrubbing liquor and (2) novel chemistry for reversible absorption of NO{sub x}. High efficiency, hollow fiber contactors (HFCs) were proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system would be designed to remove more than 95% of the SO{sub 2} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. In addition, the process would generate only marketable by-products, if any (no waste streams are anticipated). The major cost item in existing technology is capital investment. Therefore, the approach was to reduce the capital cost by using high-efficiency, hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. The authors also introduced new process chemistry to minimize traditionally well-known problems with SO{sub 2} and NO{sub x} absorption and desorption. The process and progress in its development are described.

  4. High temperature corrosion of advanced ceramic materials for hot-gas filters and heat exchangers

    SciTech Connect

    Kupp, E.R.; Trubelja, M.F.; Spear, K.E.; Tressler, R.E.

    1995-08-01

    Experimental corrosion studies of hot gas filter materials and heat exchanger materials in oxidizing combustion environments have been initiated. Filter materials from 3M Co. and DuPont Lanxide Composites Inc. are being tested over a range of temperatures, times and gas flows. It has been demonstrated that morphological and phase changes due to corrosive effects occur after exposure of the 3M material to a combustion environment for as little as 25 hours at 800{degrees}C. The study of heat exchanger materials has focused on enhancing the corrosion resistance of DuPont Lanxide Dimox{trademark} composite tubes by adding chromium to its surfaces by (1) heat treatments in a Cr{sub 2}O{sub 3} powder bed, or (2) infiltrating surface porosity with molten chromium nitrate. Each process is followed by a surface homogenization at 1500{degrees}C. The powder bed method has been most successful, producing continuous Cr-rich layers with thicknesses ranging from 20 to 250 {mu}m. As-received and Cr-modified DuPont Lanxide Dimox{trademark} samples will be reacted with commonly encountered coal-ash slags to determine the Cr effects on corrosion resistance.

  5. INVESTIGATION OF FUNDAMENTAL THERMAL-HYDRAULIC PHENOMENA IN ADVANCED GAS-COOLED REACTORS

    SciTech Connect

    INVESTIGATION OF FUNDAMENTAL THERMAL-HYDRAULIC PHE

    2006-09-01

    INL LDRD funded research was conducted at MIT to experimentally characterize mixed convection heat transfer in gas-cooled fast reactor (GFR) core channels in collaboration with INL personnel. The GFR for Generation IV has generated considerable interest and is under development in the U.S., France, and Japan. One of the key candidates is a block-core configuration first proposed by MIT, has the potential to operate in Deteriorated Turbulent Heat Transfer (DTHT) regime or in the transition between the DTHT and normal forced or laminar convection regime during post-loss-of-coolant accident (LOCA) conditions. This is contrary to most industrial applications where operation is in a well-defined and well-known turbulent forced convection regime. As a result, important new need emerged to develop heat transfer correlations that make possible rigorous and accurate predictions of Decay Heat Removal (DHR) during post LOCA in these regimes. Extensive literature review on these regimes was performed and a number of the available correlations was collected in: (1) forced laminar, (2) forced turbulent, (3) mixed convection laminar, (4) buoyancy driven DTHT and (5) acceleration driven DTHT regimes. Preliminary analysis on the GFR DHR system was performed and using the literature review results and GFR conditions. It confirmed that the GFR block type core has a potential to operate in the DTHT regime. Further, a newly proposed approach proved that gas, liquid and super critical fluids all behave differently in single channel under DTHT regime conditions, thus making it questionable to extrapolate liquid or supercritical fluid data to gas flow heat transfer. Experimental data were collected with three different gases (nitrogen, helium and carbon dioxide) in various heat transfer regimes. Each gas unveiled different physical phenomena. All data basically covered the forced turbulent heat transfer regime, nitrogen data covered the acceleration driven DTHT and buoyancy driven DTHT

  6. ORIGEN-ARP Cross-Section Libraries for Magnox, Advanced Gas-Cooled, and VVER Reactor Designs

    SciTech Connect

    Murphy, BD

    2004-03-10

    Cross-section libraries for the ORIGEN-ARP system were extended to include four non-U.S. reactor types: the Magnox reactor, the Advanced Gas-Cooled Reactor, the VVER-440, and the VVER-1000. Typical design and operational parameters for these four reactor types were determined by an examination of a variety of published information sources. Burnup simulation models of the reactors were then developed using the SAS2H sequence from the Oak Ridge National Laboratory SCALE code system. In turn, these models were used to prepare the burnup-dependent cross-section libraries suitable for use with ORIGEN-ARP. The reactor designs together with the development of the SAS2H models are described, and a small number of validation results using spent-fuel assay data are reported.

  7. Gas and liquid chromatography with inductively coupled plasma mass spectrometry detection for environmental speciation analysis — advances and limitations

    NASA Astrophysics Data System (ADS)

    Szpunar, Joanna; McSheehy, Shona; Połeć, Kasia; Vacchina, Véronique; Mounicou, Sandra; Rodriguez, Isaac; Łobiński, Ryszard

    2000-07-01

    Recent advances in the coupling of gas chromatography (GC) and high performance liquid chromatography (HPLC) with inductively coupled plasma mass spectrometry (ICP MS) and their role in trace element speciation analysis of environmental materials are presented. The discussion is illustrated with three research examples concerning the following topics: (i) development and coupling of multicapillary microcolumn GC with ICP MS for speciation of organotin in sediment and biological tissue samples; (ii) speciation of arsenic in marine algae by size-exclusion-anion-exchange HPLC-ICP MS; and (iii) speciation of cadmium in plant cell cultures by size-exclusion HPLC-ICP MS. Particular attention is paid to the problem of signal identification in ICP MS chromatograms; the potential of electrospray MS/MS for this purpose is highlighted.

  8. Advances in Hydrogen, Carbon Dioxide, and Hydrocarbon Gas Sensor Technology Using GaN and ZnO-Based Devices

    PubMed Central

    Anderson, Travis; Ren, Fan; Pearton, Stephen; Kang, Byoung Sam; Wang, Hung-Ta; Chang, Chih-Yang; Lin, Jenshan

    2009-01-01

    In this paper, we review our recent results in developing gas sensors for hydrogen using various device structures, including ZnO nanowires and GaN High Electron Mobility Transistors (HEMTs). ZnO nanowires are particularly interesting because they have a large surface area to volume ratio, which will improve sensitivity, and because they operate at low current levels, will have low power requirements in a sensor module. GaN-based devices offer the advantage of the HEMT structure, high temperature operation, and simple integration with existing fabrication technology and sensing systems. Improvements in sensitivity, recoverability, and reliability are presented. Also reported are demonstrations of detection of other gases, including CO2 and C2H4 using functionalized GaN HEMTs. This is critical for the development of lab-on-a-chip type systems and can provide a significant advance towards a market-ready sensor application. PMID:22408548

  9. Fuel Injector Patternation Evaluation in Advanced Liquid-Fueled, High Pressure, Gas Turbine Combustors, Using Nonintrusive Optical Diagnostic Techniques

    NASA Technical Reports Server (NTRS)

    Locke, R. J.; Hicks, Y. R.; Anderson, R. C.; Zaller, M. M.

    1998-01-01

    Planar laser-induced fluorescence (PLIF) imaging and planar Mie scattering are used to examine the fuel distribution pattern (patternation) for advanced fuel injector concepts in kerosene burning, high pressure gas turbine combustors. Three diverse fuel injector concepts for aerospace applications were investigated under a broad range of operating conditions. Fuel PLIF patternation results are contrasted with those obtained by planar Mie scattering. Further comparison is also made for one injector with data obtained through phase Doppler measurements. Differences in spray patterns for diverse conditions and fuel injector configurations are readily discernible. An examination of the data has shown that a direct determination of the fuel spray angle at realistic conditions is also possible. The results obtained in this study demonstrate the applicability and usefulness of these nonintrusive optical techniques for investigating fuel spray patternation under actual combustor conditions.

  10. Optical Thin Films for Gas Sensing in Advanced Coal Fired Power Plants

    SciTech Connect

    Ohodnicki, Paul; Brown, Thomas; Baltrus John; Chorpening, Benjamin

    2012-08-09

    Even for existing coal based plants, the opportunity for sensors and controls to improve efficiency is great. A wide range of gas species are of interest for relevant applications. Functional sensor layers for embedded sensing must be compatible with extreme conditions (temperature, pressure, corrosive). Au incorporated metal oxides have been looked at by a number of other authors previously for gas sensing, but have often focused on temperatures below 500{degree}C. Au nanoparticle incorporated metal oxide thin films have shown enhanced gas sensing response. In prior work, we have demonstrated that material systems such as Au nanoparticle incorporated TiO{sub 2} films exhibit a potentially useful optical response to changing gas atmospheres at temperatures up to ~800-850{degree}C. Current work is focused on sputter-deposited Au/TiO{sub 2} films. Au and Ti are multi-layered sputter deposited, followed by a 950{degree}C oxidation step. Increasing Au layer thickness yields larger particles. Interband electronic transitions significantly modify the optical constants of Au as compared to the damped free electron theory. A high temperature oxidation (20%O{sub 2}/N{sub 2}) treatment was performed at 700{degree}C followed by a reduction (4%H{sub 2}/N{sub 2}) treatment to illustrate the shift in both absorption and scattering with exposure to reducing gases. Shift of localized surface plasmon resonance (LSPR) absorption peak in changing gas atmospheres is well documented, but shift in the peak associated with diffuse scattering is a new observation. Increasing Au layer-thickness results in an increase in LSPR absorption and a shift to longer wavelengths. Diffuse scattering associated with the LSPR resonance of Au shows a similar trend with increasing Au thickness. To model the temperature dependence of LSPR, the modification to the plasmon frequency, the damping frequency, and the dielectric constant of the oxide matrix must be accounted for. Thermal expansion of Au causes

  11. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally

  12. Advanced separation technology for flue gas cleanup. Quarterly technical report No. 15

    SciTech Connect

    Bhown, A.S.; Pakala, N.; Riggs, T.; Tagg, T.

    1996-02-01

    The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (1) a novel method for regeneration of spent SO{sub 2} scrubbing liquor and (2) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors (HFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system will be designed to remove more than 95% of the SO{sub x} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. In addition, the process will make only marketable byproducts, if any (no waste streams). Our approach is to reduce the capital cost by using high efficiency hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. We will also introduce new process chemistry to minimize traditionally well-known problems with SO{sub 2} and NO{sub x} absorption and desorption. For example, we will extract the SO{sub 2} from the aqueous scrubbing liquor into an oligomer of dimethylaniline to avoid the problem of organic liquid losses in the regeneration of the organic liquid. Our novel chemistry for scrubbing NO{sub x} will consist of water soluble phthalocyanine compounds invented by SRI and also of polymeric forms of Fe{sup ++} complexes similar to traditional NO{sub x} scrubbing media. Finally, the arrangement of the absorbers is in cassette (stackable) form so that the NO{sub x} absorber can be on top of the SO{sub x} absorber. This cassette (stacked) arrangement makes it possible for the SO{sub 2} and NO{sub x} scrubbing chambers to be separate without incurring the large ducting and gas pressure drop costs necessary if a second conventional absorber vessel were used.

  13. Advanced separation technology for flue gas cleanup: Quarterly technical report No. 16, January 1996--March 1996

    SciTech Connect

    Bhown, A.S.; Bahman, A.; Sirkar, K.K.; Majumdar, S.; Bhaumick, D.

    1996-06-01

    The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (a) a novel method for regeneration of spent SO{sub 2} scrubbing liquor and (b) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors (BFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system will be designed to remove more than 95% of the SO{sub x} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. In addition, the process will make only marketable byproducts, if any (no waste streams). The major cost item in existing technology is capital investment. Therefore, our approach is to reduce the capital cost by using high efficiency hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. We will also introduce new process chemistry to minimize traditionally well-known problems with SO{sub 2} and NO{sub x} absorption and desorption. For example, we will extract the SO{sub 2} from the aqueous scrubbing liquor into an oligomer of dimethylaniline to avoid the problem of organic liquid losses in the regeneration of the organic liquid. Our novel chemistry for scrubbing NO{sub x} will consist of water soluble plithalocyanine compounds invented by SRI and also of polymeric forms of Fe{sup ++} complexes similar to traditional NO{sub x} scrubbing media described in the open literature. Our past work with the phthalocyanine compounds, used as sensors for NO and NO{sub 2} in flue gases, shows that these compounds bind NO and NO{sub 2} reversibly and with no interference from O{sub 2}, CO{sub 2}, SO{sub 2}, or other components of flue gas.

  14. Wide range operation of advanced low NOx aircraft gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; Fiorito, R. J.; Butze, H. F.

    1978-01-01

    The paper summarizes the results of an experimental test rig program designed to define and demonstrates techniques which would allow the jet-induced circulation and vortex air blast combustors to operate stably with acceptable emissions at simulated engine idle without compromise to the low NOx emissions under the high-altitude supersonic cruise condition. The discussion focuses on the test results of the key combustor modifications for both the simulated engine idle and cruise conditions. Several range-augmentation techniques are demonstrated that allow the lean-reaction premixed aircraft gas turbine combustor to operate with low NOx emissons at engine cruise and acceptable CO and UHC levels at engine idle. These techniques involve several combinations, including variable geometry and fuel switching designs.

  15. Durability testing at 5 atmospheres of advanced catalysts and catalyst supports for gas turbine engine combustors

    NASA Technical Reports Server (NTRS)

    Olson, B. A.; Lee, H. C.; Osgerby, I. T.; Heck, R. M.; Hess, H.

    1980-01-01

    The durability of CATCOM catalysts and catalyst supports was experimentally demonstrated in a combustion environment under simulated gas turbine engine combustor operating conditions. A test of 1000 hours duration was completed with one catalyst using no. 2 diesel fuel and operating at catalytically-supported thermal combustion conditions. The performance of the catalyst was determined by monitoring emissions throughout the test, and by examining the physical condition of the catalyst core at the conclusion of the test. Tests were performed periodically to determine changes in catalytic activity of the catalyst core. Detailed parametric studies were also run at the beginning and end of the durability test, using no. 2 fuel oil. Initial and final emissions for the 1000 hours test respectively were: unburned hydrocarbons (C3 vppm):0, 146, carbon monoxide (vppm):30, 2420; nitrogen oxides (vppm):5.7, 5.6.

  16. R and D advances in corrosion and crack monitoring for oil and gas lines

    SciTech Connect

    Atherton, D.L.; Czura, W.; Krause, T.W.; Laursen, P.; Mergelas, B.; Hauge, C.

    1996-12-31

    Magnetic Flux Leakage (MFL) inspection techniques for in-line corrosion monitoring of pipelines continue to evolve rapidly. Current R and D is aimed at improving the accuracy and reliability of defect sizing. Major issues are the variability and consequent need to characterize the magnetic properties of the pipes and the effects of line pressure, residual and bending stresses on MFL signals. Magnetic Barkhausen Noise (MBN) measurements are being used to study the stress-induced changes in magnetic anisotropy. Remote Field Eddy Current (RFEC) techniques are being investigated for detection and measurement of stress corrosion cracking in gas pipelines. Anomalous defect source models have improved the detailed explanation of crack defect interactions greatly.

  17. Recent advances in gas and chemical detection by Vernier effect-based photonic sensors.

    PubMed

    La Notte, Mario; Troia, Benedetto; Muciaccia, Tommaso; Campanella, Carlo Edoardo; De Leonardis, Francesco; Passaro, Vittorio M N

    2014-03-10

    Recently, the Vernier effect has been proved to be very efficient for significantly improving the sensitivity and the limit of detection (LOD) of chemical, biochemical and gas photonic sensors. In this paper a review of compact and efficient photonic sensors based on the Vernier effect is presented. The most relevant results of several theoretical and experimental works are reported, and the theoretical model of the typical Vernier effect-based sensor is discussed as well. In particular, sensitivity up to 460 μm/RIU has been experimentally reported, while ultra-high sensitivity of 2,500 μm/RIU and ultra-low LOD of 8.79 × 10(-8) RIU have been theoretically demonstrated, employing a Mach-Zehnder Interferometer (MZI) as sensing device instead of an add drop ring resonator.

  18. Recent Advances in Gas and Chemical Detection by Vernier Effect-Based Photonic Sensors

    PubMed Central

    La Notte, Mario; Troia, Benedetto; Muciaccia, Tommaso; Campanella, Carlo Edoardo; De Leonardis, Francesco; Passaro, Vittorio M. N.

    2014-01-01

    Recently, the Vernier effect has been proved to be very efficient for significantly improving the sensitivity and the limit of detection (LOD) of chemical, biochemical and gas photonic sensors. In this paper a review of compact and efficient photonic sensors based on the Vernier effect is presented. The most relevant results of several theoretical and experimental works are reported, and the theoretical model of the typical Vernier effect-based sensor is discussed as well. In particular, sensitivity up to 460 μm/RIU has been experimentally reported, while ultra-high sensitivity of 2,500 μm/RIU and ultra-low LOD of 8.79 × 10−8 RIU have been theoretically demonstrated, employing a Mach-Zehnder Interferometer (MZI) as sensing device instead of an add drop ring resonator. PMID:24618728

  19. Advanced Acid Gas Separation Technology for Clean Power and Syngas Applications

    SciTech Connect

    Amy, Fabrice; Hufton, Jeffrey; Bhadra, Shubhra; Weist, Edward; Lau, Garret; Jonas, Gordon

    2015-06-30

    Air Products has developed an acid gas removal technology based on adsorption (Sour PSA) that favorably compares with incumbent AGR technologies. During this DOE-sponsored study, Air Products has been able to increase the Sour PSA technology readiness level by successfully operating a two-bed test system on coal-derived sour syngas at the NCCC, validating the lifetime and performance of the adsorbent material. Both proprietary simulation and data obtained during the testing at NCCC were used to further refine the estimate of the performance of the Sour PSA technology when expanded to a commercial scale. In-house experiments on sweet syngas combined with simulation work allowed Air Products to develop new PSA cycles that allowed for further reduction in capital expenditure. Finally our techno economic analysis of the use the Sour PSA technology for both IGCC and coal-to-methanol applications suggests significant improvement of the unit cost of electricity and methanol compared to incumbent AGR technologies.

  20. Gas chromatography: Possible application of advanced instrumentation developed for solar system exploration to space station cabin atmospheres

    NASA Technical Reports Server (NTRS)

    Carle, G. C.

    1985-01-01

    Gas chromatography (GC) technology was developed for flight experiments in solar system exploration. The GC is a powerful analytical technique with simple devices separating individual components from complex mixtures to make very sensitive quantitative and qualitative measurements. It monitors samples containing mixtures of fixed gases and volatile organic molecules. The GC was used on the Viking mission in support of life detection experiments and on the Pioneer Venus Large Probe to determine the composition of the venusian atmosphere. A flight GC is under development to study the progress and extent of STS astronaut denitrogenation prior to extravehicular activity. Advanced flight GC concepts and systems for future solar system exploration are also studied. Studies include miniature ionization detectors and associated control systems capable of detecting from ppb up to 100% concentration levels. Further miniaturization is investigated using photolithography and controlled chemical etching in silicon wafers. Novel concepts such as ion mobility drift spectroscopy and multiplex gas chromatography are also developed for future flight experiments. These powerful analytical concepts and associated hardware are ideal for the monitoring of cabin atmospheres containing potentially dangerous volatile compounds.

  1. Advanced coal-fueled industrial cogeneration gas turbine system -- combustion development

    SciTech Connect

    LeCren, R.T.

    1994-06-01

    This topical report summarizes the combustor development work accomplished under the subject contract. The objective was to develop a combustion system for the Solar 4MW Type H Centaur gas turbine generator set which was to be used to demonstrate the economic, technical and environmental feasibility of a direct coal-fueled gas turbine in a 100 hour proof-of-concept test. This program started with a design configuration derived during the CSC program. The design went through the following evolution: CSC design which had some known shortcomings, redesigned CSC now designated as the Two Stage Slagging Combustor (TSSC), improved TSSC with the PRIS evaluated in the IBSTF, and full scale design. Supporting and complimentary activities included computer modelling, flow visualization, slag removal, SO{sub x} removal, fuel injector development and fuel properties evaluation. Three combustor rigs were utilized: the TSSC, the IBSTF and the full scale rig at Peoria. The TSSC rig, which was 1/10th scale of the proposed system, consisted of a primary and secondary zone and was used to develop the primary zone performance and to evaluate SO{sub x} and slag removal and fuel properties variations. The IBSTF rig which included all the components of the proposed system was also 1/10th scale except for the particulate removal system which was about 1/30th scale. This rig was used to verify combustor performance data obtained on the TSSC and to develop the PRIS and the particulate removal system. The full scale rig initially included the primary and secondary zones and was later modified to incorporate the PRIS. The purpose of the full scale testing was to verify the scale up calculations and to provide a combustion system for the proof-of-concept engine test that was initially planned in the program.

  2. High temperature corrosion of advanced ceramic materials for hot gas filters and heat exchangers

    SciTech Connect

    Crossland, C.E.; Shelleman, D.L.; Spear, K.E.

    1996-08-01

    A vertical flow-through furnace has been built to study the effect of corrosion on the morphology and mechanical properties of ceramic hot gas filters. Sections of 3M Type 203 and DuPont Lanxide SiC-SiC filter tubes were sealed at one end and suspended in the furnace while being subjected to a simulated coal combustion environment at 870{degrees}C. X-ray diffraction and electron microscopy is used to identify phase and morphology changes due to corrosion while burst testing determines the loss of mechanical strength after exposure to the combustion gases. Additionally, a thermodynamic database of gaseous silicon compounds is currently being established so that calculations can be made to predict important products of the reaction of the environment with the ceramics. These thermodynamic calculations provide useful information concerning the regimes where the ceramic may be degraded by material vaporization. To verify the durability and predict lifetime performance of ceramic heat exchangers in coal combustion environments, long-term exposure testing of stressed (internally pressurized) tubes must be performed in actual coal combustion environments. The authors have designed a system that will internally pressurize 2 inch OD by 48 inch long ceramic heat exchanger tubes to a maximum pressure of 200 psi while exposing the outer surface of the tubes to coal combustion gas at the Combustion and Environmental Research Facility (CERF) at the Pittsburgh Energy and Technology Center. Water-cooled, internal o-ring pressure seals were designed to accommodate the existing 6 inch by 6 inch access panels of the CERF. Tubes will be exposed for up to a maximum of 500 hours at temperatures of 2500 and 2600{degrees}F with an internal pressure of 200 psi. If the tubes survive, their retained strength will be measured using the high temperature tube burst test facility at Penn State University. Fractographic analysis will be performed to identify the failure source(s) for the tubes.

  3. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  4. Advanced sulfur control concepts for hot gas desulfurization technology. Quarterly report, January 1--March 31, 1997

    SciTech Connect

    1997-08-01

    Favorable results were achieved in the sulfidation of CeO{sub 2} by H{sub 2}S and the regeneration of Ce{sub 2}O{sub 2}S by SO{sub 2}. Successful removal of approximately 99% of the H{sub 2}S from the sulfidation gas to levels of about 100 ppmv (or lower), and the production of approximately 12% elemental sulfur (as S{sub 2}) in the regeneration product gas were highlights. Final effort in the preliminary phase included a ten-cycle test at standard sulfidation and regeneration conditions with little or no sorbent deterioration. In the initial test of the detailed experimental phase of the program, the authors investigated the effect of temperature on the regeneration reaction. Results of preliminary tests showed that the Ce{sub 2}O{sub 2}S-SO{sub 2} reaction did not occur at 350 C, and all subsequent regeneration tests were at 600 C where the reaction was rapid. Significant progress has been made on the process analysis effort during the quarter. Detailed process flow diagrams along with material and energy balance calculations for six design case studies were completed in the previous quarter. Two of the cases involved two-stage desulfurization with steam regeneration, three used two-stage desulfurization with SO{sub 2} regeneration, and the sixth was based on single-stage desulfurization with elemental sulfur recovery using the DSRP concept. In the present quarter, major process equipment was sized for each of the six cases. Preliminary annual operating and levelized total cost estimates were then completed for two design cases--one involving two-stage desulfurization with SO{sub 2} regeneration and the second based on single-stage desulfurization with DSRP.

  5. Results of Two-Stage Light-Gas Gun Development Efforts and Hypervelocity Impact Tests of Advanced Thermal Protection Materials

    NASA Technical Reports Server (NTRS)

    Cornelison, C. J.; Watts, Eric T.

    1998-01-01

    Gun development efforts to increase the launching capabilities of the NASA Ames 0.5-inch two-stage light-gas gun have been investigated. A gun performance simulation code was used to guide initial parametric variations and hardware modifications, in order to increase the projectile impact velocity capability to 8 km/s, while maintaining acceptable levels of gun barrel erosion and gun component stresses. Concurrent with this facility development effort, a hypervelocity impact testing series in support of the X-33/RLV program was performed in collaboration with Rockwell International. Specifically, advanced thermal protection system materials were impacted with aluminum spheres to simulate impacts with on-orbit space debris. Materials tested included AETB-8, AETB-12, AETB-20, and SIRCA-25 tiles, tailorable advanced blanket insulation (TABI), and high temperature AFRSI (HTA). The ballistic limit for several Thermal Protection System (TPS) configurations was investigated to determine particle sizes which cause threshold TPS/structure penetration. Crater depth in tiles was measured as a function of impact particle size. The relationship between coating type and crater morphology was also explored. Data obtained during this test series was used to perform a preliminary analysis of the risks to a typical orbital vehicle from the meteoroid and space debris environment.

  6. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect

    Not Available

    1991-09-01

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  7. Status of Technological Advancements for Reducing Aircraft Gas Turbine Engine Pollutant Emissions

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1975-01-01

    Combustor test rig results indicate that substantial reductions from current emission levels of carbon monoxide (CO), total unburned hydrocarbons (THC), oxides of nitrogen (NOx), and smoke are achievable by employing varying degrees of technological advancements in combustion systems. Minor to moderate modifications to existing conventional combustors produced significant reductions in CO and THC emissions at engine low power (idle/taxi) operating conditions but did not effectively reduce NOx at engine full power (takeoff) operating conditions. Staged combusiton techniques were needed to simultaneously reduce the levels of all the emissions over the entire engine operating range (from idle to takeoff). Emission levels that approached or were below the requirements of the 1979 EPA standards were achieved with the staged combustion systems and in some cases with the minor to moderate modifications to existing conventional combustion systems. Results from research programs indicate that an entire new generation of combustor technology with extremely low emission levels may be possible in the future.

  8. Computer Aided Design of Advanced Turbine Airfoil Alloys for Industrial Gas Turbines in Coal Fired Environments

    SciTech Connect

    G.E. Fuchs

    2007-12-31

    Recent initiatives for fuel flexibility, increased efficiency and decreased emissions in power generating industrial gas turbines (IGT's), have highlighted the need for the development of techniques to produce large single crystal or columnar grained, directionally solidified Ni-base superalloy turbine blades and vanes. In order to address the technical difficulties of producing large single crystal components, a program has been initiated to, using computational materials science, better understand how alloy composition in potential IGT alloys and solidification conditions during processing, effect castability, defect formation and environmental resistance. This program will help to identify potential routes for the development of high strength, corrosion resistant airfoil/vane alloys, which would be a benefit to all IGT's, including small IGT's and even aerospace gas turbines. During the first year, collaboration with Siemens Power Corporation (SPC), Rolls-Royce, Howmet and Solar Turbines has identified and evaluated about 50 alloy compositions that are of interest for this potential application. In addition, alloy modifications to an existing alloy (CMSX-4) were also evaluated. Collaborating with SPC and using computational software at SPC to evaluate about 50 alloy compositions identified 5 candidate alloys for experimental evaluation. The results obtained from the experimentally determined phase transformation temperatures did not compare well to the calculated values in many cases. The effects of small additions of boundary strengtheners (i.e., C, B and N) to CMSX-4 were also examined. The calculated phase transformation temperatures were somewhat closer to the experimentally determined values than for the 5 candidate alloys, discussed above. The calculated partitioning coefficients were similar for all of the CMSX-4 alloys, similar to the experimentally determined segregation behavior. In general, it appears that computational materials science has become a

  9. Advanced natural gas-fired turbine system utilizing thermochemical recuperation and/or partial oxidation for electricity generation, greenfield and repowering applications

    SciTech Connect

    1997-03-01

    The performance, economics and technical feasibility of heavy duty combustion turbine power systems incorporating two advanced power generation schemes have been estimated to assess the potential merits of these advanced technologies. The advanced technologies considered were: Thermochemical Recuperation (TCR), and Partial Oxidation (PO). The performance and economics of these advanced cycles are compared to conventional combustion turbine Simple-Cycles and Combined-Cycles. The objectives of the Westinghouse evaluation were to: (1) simulate TCR and PO power plant cycles, (2) evaluate TCR and PO cycle options and assess their performance potential and cost potential compared to conventional technologies, (3) identify the required modifications to the combustion turbine and the conventional power cycle components to utilize the TCR and PO technologies, (4) assess the technical feasibility of the TCR and PO cycles, (5) identify what development activities are required to bring the TCR and PO technologies to commercial readiness. Both advanced technologies involve the preprocessing of the turbine fuel to generate a low-thermal-value fuel gas, and neither technology requires advances in basic turbine technologies (e.g., combustion, airfoil materials, airfoil cooling). In TCR, the turbine fuel is reformed to a hydrogen-rich fuel gas by catalytic contact with steam, or with flue gas (steam and carbon dioxide), and the turbine exhaust gas provides the indirect energy required to conduct the endothermic reforming reactions. This reforming process improves the recuperative energy recovery of the cycle, and the delivery of the low-thermal-value fuel gas to the combustors potentially reduces the NO{sub x} emission and increases the combustor stability.

  10. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  11. Advanced coal-fueled gas turbine systems. Annual report, July 1990--June 1991

    SciTech Connect

    Not Available

    1991-09-01

    The combustion system discussed here incorporates a modular three- stage slagging combustor concept. Fuel-rich conditions inhibit NO{sub x} formation from fuel nitrogen in the first stage; also in the first stage, sulfur is captured with sorbent; coal ash and sulfated sorbent are removed from the combustion gases by inertial means in the second stage by the use of an impact separator and slagging cyclone separator in series. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The objective of this contract is to establish the technology required for subsequent commercial development and application by the private sector of utility-size direct coal-fueled gas turbines. Emissions from these units are to meet or be lower than the Environment Protection Agency`s (EPA`s) New Source Performance Standards (NSPS) for a pulverized coal-=fired steam turbine generator plant.

  12. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  13. Advanced Laser-Based Techniques for Gas-Phase Diagnostics in Combustion and Aerospace Engineering.

    PubMed

    Ehn, Andreas; Zhu, Jiajian; Li, Xuesong; Kiefer, Johannes

    2017-03-01

    Gaining information of species, temperature, and velocity distributions in turbulent combustion and high-speed reactive flows is challenging, particularly for conducting measurements without influencing the experimental object itself. The use of optical and spectroscopic techniques, and in particular laser-based diagnostics, has shown outstanding abilities for performing non-intrusive in situ diagnostics. The development of instrumentation, such as robust lasers with high pulse energy, ultra-short pulse duration, and high repetition rate along with digitized cameras exhibiting high sensitivity, large dynamic range, and frame rates on the order of MHz, has opened up for temporally and spatially resolved volumetric measurements of extreme dynamics and complexities. The aim of this article is to present selected important laser-based techniques for gas-phase diagnostics focusing on their applications in combustion and aerospace engineering. Applicable laser-based techniques for investigations of turbulent flows and combustion such as planar laser-induced fluorescence, Raman and Rayleigh scattering, coherent anti-Stokes Raman scattering, laser-induced grating scattering, particle image velocimetry, laser Doppler anemometry, and tomographic imaging are reviewed and described with some background physics. In addition, demands on instrumentation are further discussed to give insight in the possibilities that are offered by laser flow diagnostics.

  14. Advanced instrumentation for local measurement of gas-solid suspension flows

    NASA Astrophysics Data System (ADS)

    Ling, S. C.; Pao, H. P.

    The study of gas-solid suspension flow is being conducted in two parts: the lifting of heavy particles from the flow boundary by micro-hairpin vortices and the design of an optical instrument to investigate the characteristics of turbulent flows has particle-size concentrations. The study of micro-hairpin vortices is based on the observation of these vortices in a cavitation water-tunnel. The micro-vortices exist within the laminar and intermediate sublayer of the turbulent flow field where the velocity gradient is most intense. These vortices are believed to be the major production source of turbulence which are also responsible for the picking up of heavy solid particles from the flow boundary at the bottom of the pipe. However, this important transport mechanism near the bottom boundary was not taken into account in all previous theories of solid transport. It is hoped that this work will provide a more basic understanding on the mechanics of solid transport. Our major research effort in this quarter has been concentrated on the construction of the experimental test-setup and the development of an optical particle-size and concentration detector. The optical detector also provides the information on flow characteristics.

  15. Advanced wet flue gas desulfurization and denitrification process, Miami Fort station. Volume 2: Final report

    SciTech Connect

    Not Available

    1991-11-01

    Two hundred and sixty-one coal-fired electric utility generating units in the United States are affected by Phase 1 the 1990 Clean Air Act revisions. The total MW of generating capacity affected is 87,261. Dravo Lime projects that 24,400 MW will be retrofitted with wet FGD for Phase 1; in Phase 2, another 6,600 MW will be retrofitted. Forty-one of the affected units, with a total capacity of 14,343 MW, are located Ohio. Figure A1 shows the location and approximate size of these units. Table Al lists the units and itemizes the allowable emissions. It is likely that several of the larger units in Ohio and elsewhere will be retrofitted by 1995--1997 with magnesium-enhanced lime based wet FGD, and the improvements found in the testing program could be included as part of these installations. Smaller diameter absorbers built for higher flue gas velocities would be easier to fabricate off-site and to ship by barge on the Ohio River to the plant site, as was done for the absorbers installed at the Zimmer station. Much smaller thickeners would be easier to fit onto cramped sites in retrofits.

  16. Advanced system experimental facility: solid waste to methane gas. Background and process description

    SciTech Connect

    Isaacson, R.; Pfeffer, J.

    1981-03-01

    The Refuse Conversion to Methane Facility in Pompano Beach, Florida, a 100-ton/day experimental plant to convert municipal solid waste (MSW) to methane for fuel, has been built and is being tested. The facility has been designed to assess the technical merit of anaerobic digestion of the MSW process. Approximately 40 ton/day of volatile solids are fed to the digesters; of this, about 25 ton/day will be converted to gases. For each pound of volatile solids destroyed, 6.6 std. ft/sup 3/ of methane gas and 6.6 std. ft/sup 3/ of CO/sub 2/ will be produced. Thus, the plant will yield approximately 330,000 std. ft/sup 3//day each of methane and CO/sub 2/. This project provides a critical test of the most important process variables, thus allowing judgments to be made on scale-up considerations. The successful operation of this facility will yield information with a significant impact on potential commercial-scale plant developments. The background and theory involved in applying this technology to MSW, as well as details of the specific process line, are presented.

  17. Modeling prismatic HTGRs with U.S. N.R.C advanced gas reactor evaluator (AGREE)

    SciTech Connect

    Seker, V.; Drzewiecki, T.; Downar, T.; Kelly, J. M.

    2012-07-01

    A core fluids and heat transfer model has been developed for the prismatic high temperature gas reactor in support of the US NRC Next Generation Nuclear Plant (NGNP) evaluation model. The core fluids modeling relies on a subchannel approach in which the primary coolant flow path through the core region and vertical in-core and ex-core gaps can be modeled as individual subchannels. These subchannels are connected together to represent a three dimensional reactor. An initial validation calculation for the core fluids model has been performed using data available in literature for bypass flow. The predicted bypass flow was within 2.6% of the value reported in the literature. The core level heat transfer model is based on a triangular finite volume method, where the base triangle is one sixth of the prismatic block. In order to improve the spatial accuracy at this level, a triangular refinement method was also implemented. The fuel compact temperature is calculated by a cylindrical conduction model which is implicitly coupled to the triangular core level model. The preliminary verification of the model was performed by comparing AGREE to a finite element code COMSOL by analyzing the MHTGR core heat transfer. Further verification and validation is currently an ongoing effort. (authors)

  18. Advanced diagnostics for impact-flash spectroscopy on light-gas guns.

    SciTech Connect

    Breiland, William George; Reinhart, William Dodd; Miller, Paul Albert; Brown, Justin L.; Thornhill, Tom Finley, III; Mangan, Michael A.; Shaner, Eric Arthur; Chhabildas, Lalit Chandra; Grine, Albert D.; Wanke, Michael Clement; Alexander, C. Scott

    2007-03-01

    This study is best characterized as new technology development for implementing new sensors to investigate the optical characteristics of a rapidly expanding debris cloud resulting from hypervelocity impact regimes of 7 to 11 km/s. Our gas guns constitute a unique test bed that match operational conditions relevant to hypervelocity impact encountered in space engagements. We have demonstrated the use of (1) terahertz sensors, (2) silicon diodes for visible regimes, (3) germanium and InGaAs sensors for the near infrared regimes, and (4) the Sandia lightning detectors which are similar to the silicon diodes described in 2. The combination and complementary use of all these techniques has the strong potential of ''thermally'' characterizing the time dependent behavior of the radiating debris cloud. Complementary spectroscopic measurements provide temperature estimates of the impact generated debris by fitting its spectrum to a blackbody radiation function. This debris is time-dependent as its transport/expansion behavior is changing with time. The rapid expansion behavior of the debris cools the cloud rapidly, changing its thermal/temperature characteristics with time. A variety of sensors that span over a wide spectrum, varying from visible regime to THz frequencies, now gives us the potential to cover the impact over a broader temporal regime starting from high pressures (Mbar) high-temperatures (eV) to low pressures (mbar) low temperatures (less than room temperature) as the debris expands and cools.

  19. Impact of supplemental firing of tire-derived fuel (TDF) on mercury species and mercury capture with the advanced hybrid filter in a western subbituminous coal flue gas

    SciTech Connect

    Ye Zhuang; Stanley J. Miller

    2006-05-15

    Pilot-scale experimental studies were carried out to evaluate the impacts of cofiring tire-derived fuel and a western subbituminous coal on mercury species in flue gas. Mercury samples were collected at the inlet and outlet of the Advanced Hybrid filter to determine mercury concentrations in the flue gas with and without TDF cofiring, respectively. Cofiring of TDF with a subbituminous coal had a significant effect on mercury speciation in the flue gas. With 100% coal firing, there was only 16.8% oxidized mercury in the flue gas compared to 47.7% when 5% TDF (mass basis) was fired and 84.8% when 10% TDF was cofired. The significantly enhanced mercury oxidation may be the result of additional homogeneous gas reactions between Hg{sup 0} and the reactive chlorine generated in the TDF-cofiring flue gas and the in situ improved reactivity of unburned carbon in ash by the reactive chlorine species. Although the cofiring of TDF demonstrated limited improvement on mercury-emission control with the Advanced Hybrid filter, it proved to be a very cost-effective mercury control approach for power plants equipped with wet or dry flue gas desulfurization (FGD) systems because of the enhanced mercury oxidation. 15 refs., 4 figs., 4 tabs.

  20. Summary of Thermocouple Performance During Advanced Gas Reactor Fuel Irradiation Experiments in the Advanced Test Reactor and Out-of-Pile Thermocouple Testing in Support of Such Experiments

    SciTech Connect

    A. J. Palmer; DC Haggard; J. W. Herter; M. Scervini; W. D. Swank; D. L. Knudson; R. S. Cherry

    2011-07-01

    High temperature gas reactor experiments create unique challenges for thermocouple based temperature measurements. As a result of the interaction with neutrons, the thermoelements of the thermocouples undergo transmutation, which produces a time dependent change in composition and, as a consequence, a time dependent drift of the thermocouple signal. This drift is particularly severe for high temperature platinum-rhodium thermocouples (Types S, R, and B); and tungsten-rhenium thermocouples (Types C and W). For lower temperature applications, previous experiences with type K thermocouples in nuclear reactors have shown that they are affected by neutron irradiation only to a limited extent. Similarly type N thermocouples are expected to be only slightly affected by neutron fluxes. Currently the use of these Nickel based thermocouples is limited when the temperature exceeds 1000°C due to drift related to phenomena other than nuclear irradiation. High rates of open-circuit failure are also typical. Over the past ten years, three long-term Advanced Gas Reactor (AGR) experiments have been conducted with measured temperatures ranging from 700oC – 1200oC. A variety of standard Type N and specialty thermocouple designs have been used in these experiments with mixed results. A brief summary of thermocouple performance in these experiments is provided. Most recently, out of pile testing has been conducted on a variety of Type N thermocouple designs at the following (nominal) temperatures and durations: 1150oC and 1200oC for 2000 hours at each temperature, followed by 200 hours at 1250oC, and 200 hours at 1300oC. The standard Type N design utilizes high purity crushed MgO insulation and an Inconel 600 sheath. Several variations on the standard Type N design were tested, including Haynes 214 alloy sheath, spinel (MgAl2O4) insulation instead of MgO, a customized sheath developed at the University of Cambridge, and finally a loose assembly thermocouple with hard fired alumina

  1. Summary of thermocouple performance during advanced gas reactor fuel irradiation experiments in the advanced test reactor and out-of-pile thermocouple testing in support of such experiments

    SciTech Connect

    Palmer, A. J.; Haggard, DC; Herter, J. W.; Swank, W. D.; Knudson, D. L.; Cherry, R. S.; Scervini, M.

    2015-07-01

    High temperature gas reactor experiments create unique challenges for thermocouple-based temperature measurements. As a result of the interaction with neutrons, the thermoelements of the thermocouples undergo transmutation, which produces a time-dependent change in composition and, as a consequence, a time-dependent drift of the thermocouple signal. This drift is particularly severe for high temperature platinum-rhodium thermocouples (Types S, R, and B) and tungsten-rhenium thermocouples (Type C). For lower temperature applications, previous experiences with Type K thermocouples in nuclear reactors have shown that they are affected by neutron irradiation only to a limited extent. Similarly, Type N thermocouples are expected to be only slightly affected by neutron fluence. Currently, the use of these nickel-based thermocouples is limited when the temperature exceeds 1000 deg. C due to drift related to phenomena other than nuclear irradiation. High rates of open-circuit failure are also typical. Over the past 10 years, three long-term Advanced Gas Reactor experiments have been conducted with measured temperatures ranging from 700 deg. C - 1200 deg. C. A variety of standard Type N and specialty thermocouple designs have been used in these experiments with mixed results. A brief summary of thermocouple performance in these experiments is provided. Most recently, out-of-pile testing has been conducted on a variety of Type N thermocouple designs at the following (nominal) temperatures and durations: 1150 deg. C and 1200 deg. C for 2,000 hours at each temperature, followed by 200 hours at 1250 deg. C and 200 hours at 1300 deg. C. The standard Type N design utilizes high purity, crushed MgO insulation and an Inconel 600 sheath. Several variations on the standard Type N design were tested, including a Haynes 214 alloy sheath, spinel (MgAl{sub 2}O{sub 4}) insulation instead of MgO, a customized sheath developed at the University of Cambridge, and finally a loose assembly

  2. Advanced Low-Emissions Catalytic-Combustor Program, phase 1. [aircraft gas turbine engines

    NASA Technical Reports Server (NTRS)

    Sturgess, G. J.

    1981-01-01

    Six catalytic combustor concepts were defined, analyzed, and evaluated. Major design considerations included low emissions, performance, safety, durability, installations, operations and development. On the basis of these considerations the two most promising concepts were selected. Refined analysis and preliminary design work was conducted on these two concepts. The selected concepts were required to fit within the combustor chamber dimensions of the reference engine. This is achieved by using a dump diffuser discharging into a plenum chamber between the compressor discharge and the turbine inlet, with the combustors overlaying the prediffuser and the rear of the compressor. To enhance maintainability, the outer combustor case for each concept is designed to translate forward for accessibility to the catalytic reactor, liners and high pressure turbine area. The catalytic reactor is self-contained with air-cooled canning on a resilient mounting. Both selected concepts employed integrated engine-starting approaches to raise the catalytic reactor up to operating conditions. Advanced liner schemes are used to minimize required cooling air. The two selected concepts respectively employ fuel-rich initial thermal reaction followed by rapid quench and subsequent fuel-lean catalytic reaction of carbon monoxide, and, fuel-lean thermal reaction of some fuel in a continuously operating pilot combustor with fuel-lean catalytic reaction of remaining fuel in a radially-staged main combustor.

  3. Advanced low NO/x/ combustors for supersonic high-altitude aircraft gas turbines

    NASA Technical Reports Server (NTRS)

    Roberts, P. B.; Shekleton, J. R.; White, D. J.; Butze, H. F.

    1976-01-01

    A test rig program was conducted with the objective of evaluating and minimizing the exhaust emissions, in particular NO(x), of two advanced aircraft combustor concepts at a simulated, high-altitude cruise condition. The two combustor designs, both members of the lean-reaction, pre-mixed family, are known as the Jet Induced Circulation (JIC) combustor and the Vortex Air Blast (VAB) combustor and were rig tested in the form of reverse flow can combustors in the 0.127-m size range. Various configuration modifications were applied to each of the initial JIC and VAB combustor model designs in an effort to reduce the emissions levels. The VAB combustor demonstrated a NO(x) level of 1.1 gm NO2/kg fuel with essentially 100 percent combustion efficiency at the simulated cruise combustor condition of 507 kPa, 833 K inlet pressure and temperature, respectively and 1778 K outlet temperature on Jet-A1 fuel. In addition, emissions data were obtained at low combustor inlet pressure and temperatures that indicate the potential performance at engine off-design conditions.

  4. Advanced hot-gas filter development. Topical report, September 30, 1994--May 31, 1996

    SciTech Connect

    Lane, J.E.; LeCostaouec, J.F.; Painter, C.J.; Sue, W.A.; Radford, K.C.

    1996-12-31

    The application of high-performance, high-temperature particulate control devices is considered to be beneficial to advanced fossil fuel processing technology, to selected high-temperature industrial processes, and to waste incineration concepts. Ceramic rigid filters represent the most attractive technology for these applications due to their capability to withstand high-temperature corrosive environments. However, current generation monolithic filters have demonstrated poor resistance to crack propagation and can experience catastrophic failure during use. To address this problem, ceramic fiber-reinforced ceramic matrix composite (CMC) filter materials are needed for reliable damage tolerant candle filters. This program is focused on the development of an oxide-fiber reinforced oxide material composite filter material that is cost competitive with prototype next generation filters. This goal would be achieved through the development of a low cost sol-gel fabrication process and a three-dimensional fiber architecture optimized for high volume filter manufacturing. The 3D continuous fiber reinforcement provides a damage tolerant structure which is not subject to delamination-type failures. This report documents the Phase 1, Filter Material Development and Evaluation, results. Section 2 provides a program summary. Technical results, including experimental procedures, are presented and discussed in Section 3. Section 4 and 5 provide the Phase 1 conclusions and recommendations, respectively. The remaining sections cover acknowledgements and references.

  5. Ceramics for the advanced automotive gas turbine engine: A look at a single shaft design

    NASA Technical Reports Server (NTRS)

    Nosek, S. M.

    1977-01-01

    The results of a preliminary analysis of a single shaft regenerative design with a single stage radial turbine are presented to show the fuel economy that can be achieved at high turbine inlet temperatures, with this particular advanced design, if the turbine tip speed and regenerator inlet temperature are not limited. The engine size was 100 hp for application to a 3500 lb auto. The fuel economy was analyzed by coupling the engine to the auto through a continuously variable speed-ratio transmission and operating the system at constant turbine inlet temperature over the Composite Driving Cycle. The fuel was gasoline and the analysis was for a 85 F day. With a turbine inlet temperature of 2500 F the fuel economy was 26.2 mpg, an improvement of 18 percent over that of 22.3 mpg with a turbine inlet temperature of 1900 F. The turbine tip speed needed for best economy with the 2500 F engine was 2530 ft/sec. The regenerator temperature was approximately 2200 F at idle. Disk stresses were estimated for one single stage radial turbine and two two-stage radial-axial turbines and compared with maximum allowable stress curves estimated for a current ceramic material. Results show a need for higher Weibull Modulus, higher strength ceramics.

  6. Advanced online monitoring of cell culture off-gas using proton transfer reaction mass spectrometry.

    PubMed

    Schmidberger, Timo; Gutmann, Rene; Bayer, Karl; Kronthaler, Jennifer; Huber, Robert

    2014-01-01

    Mass spectrometry has been frequently applied to monitor the O₂ and CO₂ content in the off-gas of animal cell culture fermentations. In contrast to classical mass spectrometry the proton transfer reaction mass spectrometry (PTR-MS) provides additional information of volatile organic compounds by application of a soft ionization technology. Hence, the spectra show less fragments and can more accurately assigned to particular compounds. In order to discriminate between compounds of non-metabolic and metabolic origin cell free experiments and fed-batch cultivations with a recombinant CHO cell line were conducted. As a result, in total eight volatiles showing high relevance to individual cultivation or cultivation conditions could be identified. Among the detected compounds methanethiol, with a mass-to-charge ratio of 49, qualifies as a key candidate in process monitoring due to its strong connectivity to lactate formation. Moreover, the versatile and complex data sets acquired by PTR MS provide a valuable resource for statistical modeling to predict non direct measurable parameters. Hence, partial least square regression was applied to the complete spectra of volatiles measured and important cell culture parameters such as viable cell density estimated (R²  = 0.86). As a whole, the results of this study clearly show that PTR-MS provides a powerful tool to improve bioprocess-monitoring for mammalian cell culture. Thus, specific volatiles emitted by cells and measured online by the PTR-MS and complex variables gained through statistical modeling will contribute to a deeper process understanding in the future and open promising perspectives to bioprocess control.

  7. Hot-Electron Gallium Nitride Two Dimensional Electron Gas Nano-bolometers For Advanced THz Spectroscopy

    NASA Astrophysics Data System (ADS)

    Ramaswamy, Rahul

    Two-dimensional electron gas (2DEG) in semiconductor heterostructures was identified as a promising medium for hot-electron bolometers (HEB) in the early 90s. Up until now all research based on 2DEG HEBs is done using high mobility AlGaAs/GaAs heterostructures. These systems have demonstrated very good performance, but only in the sub terahertz (THz) range. However, above ˜0.5 THz the performance of AlGaAs/GaAs detectors drastically deteriorates. It is currently understood, that detectors fabricated from standard AlGaAs/GaAs heterostructures do not allow for reasonable coupling to THz radiation while maintaining high conversion efficiency. In this work we have developed 2DEG HEBs based on disordered Gallium Nitride (GaN) semiconductor, that operate at frequencies beyond 1THz at room temperature. We observe strong free carrier absorption at THz frequencies in our disordered 2DEG film due to Drude absorption. We show the design and fabrication procedures of novel micro-bolometers having ultra-low heat capacities. In this work the mechanism of 2DEG response to THz radiation is clearly identified as bolometric effect through our direct detection measurements. With optimal doping and detector geometry, impedances of 10--100 O have been achieved, which allow integration of these devices with standard THz antennas. We also demonstrate performance of the antennas used in this work in effectively coupling THz radiation to the micro-bolometers through polarization dependence and far field measurements. Finally heterodyne mixing due to hot electrons in the 2DEG micro-bolometer has been performed at sub terahertz frequencies and a mixing bandwidth greater than 3GHz has been achieved. This indicates that the characteristic cooling time in our detectors is fast, less than 50ps. Due to the ultra-low heat capacity; these detectors can be used in a heterodyne system with a quantum cascade laser (QCL) as a local oscillator (LO) which typically provides output powers in the micro

  8. Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas

    SciTech Connect

    Cafferty, Kara G.; Searcy, Erin M.; Nguyen, Long; Spatari, Sabrina

    2014-11-01

    To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels and access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver on-spec biomass feedstocks at preprocessing “depots”, which densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The harvesting, preprocessing, and logistics (HPL) of biomass commodity supply chains thus could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logisticsHPL within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. Monte Carlo simulation was used to estimate the spatial uncertainty in the HPL gate-to-gate sequence. The results show that the transport of densified biomass introduces the highest variability and contribution to the carbon footprint of the logistics HPL supply chain (0.2-13 g CO2e/MJ). Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics HPL processes can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 to 41 g CO2e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this

  9. Recent Advances in the Development and Application of Power Plate Transducers in Dense Gas Extraction and Aerosol Agglomeration Processes

    NASA Astrophysics Data System (ADS)

    Riera, E.; Cardoni, A.; Gallego-Juárez, J. A.; Acosta, V. M.; Blanco, A.; Rodríguez, G.; Blasco, M.; Herranz, L. E.

    Power ultrasound (PU) is an emerging, innovative, energy saving and environmental friendly technology that is generating a great interest in sectors such as food and pharmaceutical industries, green chemistry, environmental pollution, and other processes, where sustainable and energy efficient methods are required to improve and/or produce specific effects. Two typical effects of PU are the enhancement of mass transfer in gases and liquids, and the induction of particle agglomeration in aerosols. These effects are activated by a variety of mechanisms associated to the nonlinear propagation of high amplitude ultrasonic waves such as diffusion, agitation, entrainment, turbulence, etc. During the last years a great effort has been jointly made by the Spanish National Research Council (CSIC) and the company Pusonics towards introducing novel processes into the market based on airborne ultrasonic plate transducers. This technology was specifically developed for the treatment of gas and multiphasic media characterized by low specific acoustic impedance and high acoustic absorption. Different strategies have been developed to mitigate the effects of the nonlinear dynamic behavior of such ultrasonic piezoelectric transducers in order to enhance and stabilize their response at operational power conditions. This work deals with the latter advances in the mitigation of nonlinear problems found in power transducers; besides it describes two applications assisted by ultrasound developed at semi-industrial and laboratory scales and consisting in extraction via dense gases and particle agglomeration. Dense Gas Extraction (DGE) assisted by PU is a new process with a potential to enhance the extraction kinetics with supercritical CO2. Acoustic agglomeration of fine aerosol particles has a great potential for the treatment of air pollution problems generated by particulate materials. Experimental and numerical results in both processes will be shown and discussed.

  10. Advancements in Ti Alloy Powder Production by Close-Coupled Gas Atomization

    SciTech Connect

    Heidloff, Andy; Rieken, Joel; Anderson, Iver; Byrd, David

    2011-04-01

    As the technology for titanium metal injection molding (Ti-MIM) becomes more readily available, efficient Ti alloy fine powder production methods are required. An update on a novel close-coupled gas atomization system has been given. Unique features of the melting apparatus are shown to have measurable effects on the efficiency and ability to fully melt within the induction skull melting system (ISM). The means to initiate the melt flow were also found to be dependent on melt apparatus. Starting oxygen contents of atomization feedstock are suggested based on oxygen pick up during the atomization and MIM processes and compared to a new ASTM specification. Forming of titanium by metal injection molding (Ti-MIM) has been extensively studied with regards to binders, particle shape, and size distribution and suitable de-binding methods have been discovered. As a result, the visibility of Ti-MIM has steadily increased as reviews of technology, acceptability, and availability have been released. In addition, new ASTM specification ASTM F2885-11 for Ti-MIM for biomedical implants was released in early 2011. As the general acceptance of Ti-MIM as a viable fabrication route increases, demand for economical production of high quality Ti alloy powder for the preparation of Ti-MIM feedstock correspondingly increases. The production of spherical powders from the liquid state has required extensive pre-processing into different shapes thereby increasing costs. This has prompted examination of Ti-MIM with non-spherical particle shape. These particles are produced by the hydride/de-hydride process and are equi-axed but fragmented and angular which is less than ideal. Current prices for MIM quality titanium powder range from $40-$220/kg. While it is ideal for the MIM process to utilize spherical powders within the size range of 0.5-20 {mu}m, titanium's high affinity for oxygen to date has prohibited the use of this powder size range. In order to meet oxygen requirements the top size

  11. Implications of Results from the Advanced Gas Reactor Fuel Development and Qualification Program on Licensing of Modular HTGRs

    SciTech Connect

    David Petti

    2001-10-01

    The high level of safety of modular high temperature gas-cooled reactor (HTGR) designs is achieved by passively maintaining core temperatures below fission product release thresholds under all envisioned accident scenarios. This level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude relative to other reactor types but is predicated on exceptionally high coated-particle fuel fabrication quality and excellent fuel performance under normal operation and accident conditions. The Advanced Gas Reactor Fuel Development and Qualification (AGR) Program decided to qualify for uranium oxide/uranium carbide (UCO) TRISO coated-particle fuel in an operating envelope that would bound both pebble bed and prismatic modular HTGR options. By using a mixture of uranium oxide and uranium carbide, the kernel composition is engineered to minimize CO formation and fuel kernel migration, which is key to maintain to fuel integrity at the higher burnups, temperatures, and temperature gradients anticipated in prismatic HTGRs. Fuel fabrication conducted at both laboratory and engineering scale has demonstrated the ability to fabricate high quality UCO TRISO fuel with very low defects. The first irradiation (AGR 1) exposed about 300,000 TRISO fuel particles to a peak burnup of 19.6% FIMA, a peak fast-neutron fluence of about 4.3 × 1025 n/m2, and a maximum time-averaged fuel temperature of about 1,200°C without a single particle failure. The very low release of key metallic fission products (except silver) measured in post-irradiation examination (PIE) confirms the excellent performance measured under irradiation. Very low releases have been measured in accident simulation heatup testing (''safety testing'') after hundreds of hours at 1600 and 1700°C and no particle failures (no noble gas release measured) have been observed. Even after hundreds of hours at 1800°C, the releases are still very low

  12. Greenhouse gas accounting of the proposed landfill extension and advanced incineration facility for municipal solid waste management in Hong Kong.

    PubMed

    Woon, K S; Lo, Irene M C

    2013-08-01

    The burgeoning of municipal solid waste (MSW) disposal issue and climate change have drawn massive attention from people. On the one hand, Hong Kong is facing a controversial debate over the implementation of proposed landfill extension (LFE) and advanced incineration facility (AIF) to curb the MSW disposal issue. On the other hand, the Hong Kong Special Administrative Region Government is taking concerted efforts to reduce the carbon intensity in this region. This paper discusses the greenhouse gas (GHG) emissions from four proposed waste disposal scenarios, covering the proposed LFE and AIF within a defined system boundary. On the basis of the data collected, assumptions made, and system boundary defined in this study, the results indicate that AIF releases less GHG emissions than LFE. The GHG emissions from LFE are highly contributed by the landfill methane (CH4) emissions but offset by biogenic carbon storage, while the GHG emissions from AIF are mostly due to the stack discharge system but offset by the energy recovery system. Furthermore, parametric sensitivity analyses show that GHG emissions are strongly dependent on the landfill CH4 recovery rate, types of electricity displaced by energy recovery systems, and the heating value of MSW, altering the order of preferred waste disposal scenarios. This evaluation provides valuable insights into the applicability of a policy framework for MSW management practices in reducing GHG emissions.

  13. Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I

    SciTech Connect

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  14. Advancing strategic environmental assessment in the offshore oil and gas sector: Lessons from Norway, Canada, and the United Kingdom

    SciTech Connect

    Fidler, Courtney; Noble, Bram

    2012-04-15

    Abstract: Strategic environmental assessment (SEA) for offshore oil and gas planning and development is utilized in select international jurisdictions, but the sector has received limited attention in the SEA literature. While the potential benefits of and rationale for SEA are well argued, there have been few empirical studies of SEA processes for the offshore sector. Hence, little is known about the efficacy of SEA offshore, in particular its influence on planning and development decisions. This paper examines SEA practice and influence in three international offshore systems: Norway, Atlantic Canada and the United Kingdom, with the intent to identify the challenges, lessons and opportunities for advancing SEA in offshore planning and impact assessment. Results demonstrate that SEA can help inform and improve the efficacy and efficiency of project-based assessment in the offshore sector, however weak coordination between higher and lower tiers limit SEA's ability to influence planning and development decisions in a broad regional environmental and socioeconomic context. - Highlights: Black-Right-Pointing-Pointer SEA can inform and improve the efficacy and efficiency of project EA offshore Black-Right-Pointing-Pointer Scope and deliverables of SEA offshore often differ from stakeholder expectations Black-Right-Pointing-Pointer Considerable variability in influence of SEA output beyond licensing decisions Black-Right-Pointing-Pointer Sector-based SEA offshore is often too restrictive to generate expected benefits.

  15. Development of Advanced Eco-hydrologic and Biogeochemical Coupling Model to Re-evaluate Greenhouse Gas Budget of Biosphere

    NASA Astrophysics Data System (ADS)

    Nakayama, T.; Maksyutov, S. S.

    2015-12-01

    Inland waters including rivers, lakes, and groundwater are suggested to act as a transport pathway for water and dissolved substances, and play some role in continental biogeochemical cycling (Cole et al., 2007; Battin et al., 2009). The authors have developed process-based National Integrated Catchment-based Eco-hydrology (NICE) model (2014, 2015, etc.), which includes feedback between hydrologic-geomorphic-ecological processes. In this study, NICE was further developed to couple with various biogeochemical cycle models in biosphere, those for water quality in aquatic ecosystems, and those for carbon weathering. The NICE-biogeochemical coupling model incorporates connectivity of the biogeochemical cycle accompanied by hydrologic cycle between surface water and groundwater, hillslopes and river networks, and other intermediate regions. The model also includes reaction between inorganic and organic carbons, and its relation to nitrogen and phosphorus in terrestrial-aquatic continuum. The coupled model showed to improve the accuracy of inundation stress mechanism such as photosynthesis and primary production, which attributes to improvement of CH4 flux in wetland sensitive to fluctuations of shallow groundwater. The model also simulated CO2 evasion from inland water in global scale, and was relatively in good agreement in empirical relation (Aufdenkampe et al., 2011) which has relatively an uncertainty in the calculated flux because of pCO2 data missing in some region and effect of small tributaries, etc. Further, the model evaluated how the expected CO2 evasion might change as inland waters become polluted with nutrients and eutrophication increases from agriculture and urban areas (Pacheco et al., 2013). This advanced eco-hydrologic and biogeochemical coupling model would play important role to re-evaluate greenhouse gas budget of the biosphere, and to bridge gap between top-down and bottom-up approaches (Battin et al., 2009; Regnier et al., 2013).

  16. Advanced design nuclear power plants: Competitive, economical electricity. An analysis of the cost of electricity from coal, gas and nuclear power plants

    SciTech Connect

    Not Available

    1992-06-01

    This report presents an updated analysis of the projected cost of electricity from new baseload power plants beginning operation around the year 2000. Included in the study are: (1) advanced-design, standardized nuclear power plants; (2) low emissions coal-fired power plants; (3) gasified coal-fired power plants; and (4) natural gas-fired power plants. This analysis shows that electricity from advanced-design, standardized nuclear power plants will be economically competitive with all other baseload electric generating system alternatives. This does not mean that any one source of electric power is always preferable to another. Rather, what this analysis indicates is that, as utilities and others begin planning for future baseload power plants, advanced-design nuclear plants should be considered an economically viable option to be included in their detailed studies of alternatives. Even with aggressive and successful conservation, efficiency and demand-side management programs, some new baseload electric supply will be needed during the 1990s and into the future. The baseload generating plants required in the 1990s are currently being designed and constructed. For those required shortly after 2000, the planning and alternatives assessment process must start now. It takes up to ten years to plan, design, license and construct a new coal-fired or nuclear fueled baseload electric generating plant and about six years for a natural gas-fired plant. This study indicates that for 600-megawatt blocks of capacity, advanced-design nuclear plants could supply electricity at an average of 4.5 cents per kilowatt-hour versus 4.8 cents per kilowatt-hour for an advanced pulverized-coal plant, 5.0 cents per kilowatt-hour for a gasified-coal combined cycle plant, and 4.3 cents per kilowatt-hour for a gas-fired combined cycle combustion turbine plant.

  17. Low drift type N thermocouples in out-of-pile advanced gas reactor mock-up test: metallurgical analysis

    SciTech Connect

    Scervini, M.; Palmer, J.; Haggard, D.C.; Swank, W.D.

    2015-07-01

    Thermocouples are the most commonly used sensors for temperature measurement in nuclear reactors. They are crucial for the control of current nuclear reactors and for the development of GEN IV reactors. In nuclear applications thermocouples are strongly affected by intense neutron fluxes. As a result of the interaction with neutrons, the thermoelements of the thermocouples undergo transmutation, which produces a time dependent change in composition and, as a consequence, a time dependent drift of the thermocouple signal. Thermocouple drift can be very significant for in-pile temperature measurements and may render the temperature sensors unreliable after exposure to nuclear radiation for relatively short times compared to the life required for temperature sensors in nuclear applications. Previous experiences with type K thermocouples in nuclear reactors have shown that they are affected by neutron irradiation only to a limited extent. Similarly type N thermocouples are expected to be only slightly affected by neutron fluxes. Currently the use of Nickel based thermocouples is limited to temperatures lower than 1000 deg. C due to drift related to phenomena other than nuclear irradiation. As part of a collaboration between Idaho National Laboratory (INL) and the University of Cambridge a variety of Type N thermocouples have been exposed at INL in an Advanced Gas Reactor mock-up test at 1150 deg. C for 2000 h, 1200 deg. C for 2000 h, 125 deg. C for 200 h and 1300 deg. C for 200 h, and later analysed metallurgically at the University of Cambridge. The use of electron microscopy allows to identify the metallurgical changes occurring in the thermocouples during high temperature exposure and correlate the time dependent thermocouple drift with the microscopic changes experienced by the thermoelements of different thermocouple designs. In this paper conventional Inconel 600 sheathed type N thermocouples and a type N using a customized sheath developed at the University of

  18. 46 CFR 13.607 - Requirements to qualify for an STCW endorsement for advanced liquefied gas tanker cargo operations.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... operations must: (1) Qualify for a national endorsement as tankerman-PIC liquefied gas; (2) Meet the... tankerman-PIC (barge) liquefied gas; (2) Provide evidence of meeting the standards of competence identified... loading and three discharge operations. (e) Grandfathering. Seafarers holding valid...

  19. Proposed Rule and Related Materials for Proposed Finding That Greenhouse Gas Emissions From Aircraft Cause or Contribute to Air Pollution That May Reasonably Be Anticipated To Endanger Public Health and Welfare and Advance Notice of Proposed Rulemaking

    EPA Pesticide Factsheets

    Proposed Rule and Related Materials for Proposed Finding That Greenhouse Gas Emissions From Aircraft Cause or Contribute to Air Pollution That May Reasonably Be Anticipated To Endanger Public Health and Welfare and Advance Notice of Proposed Rulemaking

  20. Clostridial abdominal gas gangrene masquerading as a bowel perforation in an advanced-stage ovarian cancer patient.

    PubMed

    Abaid, L N; Thomas, R H; Epstein, H D; Goldstein, B H

    2013-08-01

    The coexistence of clostridial gas gangrene and a gynecologic malignancy is extremely rare, with very few cases involving ovarian cancer. A patient originally presented to our gynecologic oncology service with stage IV ovarian cancer; she underwent a diagnostic laparoscopy and neoadjuvant chemotherapy. On postoperative day 6, the patient developed severe abdominal pain, nausea, and emesis, suggestive of a bowel perforation. Further evaluation confirmed that her symptoms were attributed to Clostridium perfringens-related gas gangrene. Despite immediate surgical intervention, the patient succumbed to her disease. Clostridial gas gangrene is associated with an extremely high mortality rate. Therefore, accurate detection and prompt management are indispensable to ensuring a favorable patient outcome.

  1. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    SciTech Connect

    2009-02-01

    Gas Technology Institute will collaborate with Integrated CHP Systems Corporation, West Virginia University, Vronay Engineering Services, KAR Engineering Associates, Pioneer Air Systems, and Energy Concepts Company to recover waste heat from reciprocating engines. The project will integrate waste heat recovery along with gas clean-up technology system improvements. This will address fuel quality issues that have hampered expanded use of opportunity fuels such as landfill gas, digester biogas, and coal mine methane. This will enable increased application of CHP using renewable and domestically derived opportunity fuels.

  2. USAF advanced terrestrial energy study. Volume 1: Project summary

    NASA Astrophysics Data System (ADS)

    Daniels, E. J.; Yudow, B. D.; Donakowski, T. D.

    1983-04-01

    The objective of this project was to develop a data base of technical and economic performance parameters of selected energy conversion and energy storage devices. The data base includes not only the state-of-the-art (1980) values of performance parameters, but also the expected values of performance parameters in 1985, 1990, and 2000. For energy conversion technologies, performance parameters were developed over a power output from 1.5 to 5000.0 kW. For energy storage technologies, performance parameters were developed over an energy output range equivalent to the power output at continuous annual operation. The following energy conversion technologies were characterized in this data base: Gas turbines -- Closed cycle and Open cycle, (recuperative and nonrecuperative); Diesels -- Turbocompounded, Turbocharged and Adiabatic; Stirlings -- Free piston and Kinematic; Organic Rankine Cycles; Fuel cells -Phosphoric acid, Solid polymer electrolyte and Molten carbonate; Photovoltaics -- Flat plate, Actively cooled and Photochemical; and Wind turbines -- Vertical and horizontal axes. The following energy storage technologies were characterized: Batteries -- Zn/Cl2, Zn/Br2, Ni/Fe, Li-Al/FeS2, Na/S, Advanced sealed lead/acids and Redox Cr-Fe; and Thermal energy storage devices -- CaCl26H2O, Na2SO410H2O, Na2S2O35H2O, Olivine and Magnesite ceramic brick, and Form-stable polyethylene.

  3. Development of Metal-impregnated Single Walled Carbon Nanotubes for Toxic Gas Contaminant Control in Advanced Life Support Systems

    NASA Technical Reports Server (NTRS)

    Pisharody, Suresh A.; Fisher, John W.; Wignarajah, K.

    2002-01-01

    The success of physico-chemical waste processing and resource recovery technologies for life support application depends partly on the ability of gas clean-up systems to efficiently remove trace contaminants generated during the process with minimal use of expendables. Carbon nanotubes promise superior performance over conventional approaches to gas clean-up due to their ability to direct the selective uptake of gaseous species based on their controlled pore size, high surface area, ordered chemical structure that allows functionalization and their effectiveness also as catalyst support materials for toxic gas conversion. We present results and findings from a preliminary study on the effectiveness of metal impregnated single walled nanotubes as catalyst/catalyst support materials for toxic gas contaminate control. The study included the purification of single walled nanotubes, the catalyst impregnation of the purified nanotubes, the experimental characterization of the surface properties of purified single walled nanotubes and the characterization of physisorption and chemisorption of uptake molecules.

  4. ENVIRONMENTAL RESEARCH BRIEF: DEVELOPMENT OF GAS CLEANING TECHNOLOGY: DEMONSTRATION OF ADVANCED ELECTROSTATIC PRECIPITATOR TECHNOLOGY (INDIA ESP TRAINING)

    EPA Science Inventory

    The Brief discusses a demonstration of advanced electrostatic precipitator (ESP) diagnostics and technologies in India. Six Indian ESP specialists were selected by Southern Research Institute and their consultants, with the concurrence of EPA's project officer, to attend a course...

  5. Toward improved durability in advanced aircraft engine hot sections; Proceedings of the Thirty-third ASME International Gas Turbine and Aeroengine Congress and Exposition, Amsterdam, Netherlands, June 5-9, 1988

    NASA Technical Reports Server (NTRS)

    Sokolowski, Daniel E. (Editor)

    1988-01-01

    The present conference on durability improvement methods for advanced aircraft gas turbine hot-section components discusses NASA's 'HOST' project, advanced high-temperature instrumentation for hot-section research, the development and application of combustor aerothermal models, and the evaluation of a data base and numerical model for turbine heat transfer. Also discussed are structural analysis methods for gas turbine hot section components, fatigue life-prediction modeling for turbine hot section materials, and the service life modeling of thermal barrier coatings for aircraft gas turbine engines.

  6. Advanced gas atomization production of oxide dispersion strengthened (ODS) Ni-base superalloys through process and solidification control

    NASA Astrophysics Data System (ADS)

    Meyer, John Louis Lamb

    A novel gas atomization reaction synthesis (GARS) method was utilized to produce precursor Ni-Cr-Y-Ti powder with a surface oxide and an internal rare earth (RE)-containing intermetallic. Although Al is necessary for industrial superalloy production, the Ni-Cr base alloy system was selected as a simplified system more amenable to characterization. This was done in an effort to better study the effects of processing parameters. Consolidation and heat-treatment were performed to promote the exchange of oxygen from the surface oxide to the RE intermetallic to form nanometric oxide dispersoids. Alloy selection was aided by an internal oxidation and serial grinding experiment that found that Hf-containing alloys may form more stable dispersoids than Ti-containing alloys, but the Hf-containing system exhibited five different oxide phases and two different intermetallics compared to the two oxide phases and one intermetallic in the Ti-containing alloys. Since the simpler Ti-containing system was easier to characterize, and make observations on the effects of processing parameters, the Ti-containing system was used for experimental atomization trials. An internal oxidation model was used to predict the heat treatment times necessary for dispersoid formation as a function of powder size and temperature. A new high-pressure gas atomization (HPGA) nozzle was developed with the aim of promoting fine powder production at scales similar to that of the high gas-flow and melt-flow of industrial atomizers. The atomization nozzle was characterized using schlieren imaging and aspiration pressure testing to determine the optimum melt delivery tip geometry and atomization pressure to promote enhanced secondary atomization mechanisms. Six atomization trials were performed to investigate the effects of gas atomization pressure and reactive-gas concentration on the particle size distribution (PSD). Also, the effect on the rapidly solidified microstructure (as a function of powder size

  7. Preliminary Results of an On-Line, Multi-Spectrometer Fission Product Monitoring System to Support Advanced Gas Reactor Fuel Testing and Qualification in the Advanced Test Reactor at the Idaho National Laboratory

    SciTech Connect

    Dawn M. Scates; John K. Hartwell; John B. Walter; Mark W. Drigert

    2007-10-01

    The Advanced Gas Reactor -1 (AGR-1) experiment is the first experiment in a series of eight separate low enriched uranium (LEU) oxycarbide (UCO) tri-isotropic (TRISO) particle fuel (in compact form) experiments scheduled for placement in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The experiment began irradiation in the ATR with a cycle that reached full power on December 26, 2006 and will continue irradiation for about 2.5 years. During this time six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The goals of the irradiation experiment is to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. This paper presents the preliminary test details of the fuel performance, as measured by the control and acquisition software.

  8. Recent Advances in Gas Barrier Thin Films via Layer-by-Layer Assembly of Polymers and Platelets.

    PubMed

    Priolo, Morgan A; Holder, Kevin M; Guin, Tyler; Grunlan, Jaime C

    2015-05-01

    Layer-by-layer (LbL) assembly has emerged as the leading non-vacuum technology for the fabrication of transparent, super gas barrier films. The super gas barrier performance of LbL deposited films has been demonstrated in numerous studies, with a variety of polyelectrolytes, to rival that of metal and metal oxide-based barrier films. This Feature Article is a mini-review of LbL-based multilayer thin films with a 'nanobrick wall' microstructure comprising polymeric mortar and nano-platelet bricks that impart high gas barrier to otherwise permeable polymer substrates. These transparent, water-based thin films exhibit oxygen transmission rates below 5 × 10(-3) cm(3) m(-2) day(-1) atm(-1) and lower permeability than any other barrier material reported. In an effort to put this technology in the proper context, incumbent technologies such as metallized plastics, metal oxides, and flake-filled polymers are briefly reviewed.

  9. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2000-09-01

    The U.S. Department of Energy and ADA Environmental Solutions have begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the second reporting quarter for this project, design and development is continuing on an electrostatic tensiometer to measure cohesion of flyash layers. A dedicated test fixture to automate flyash electrical resistivity testing is also underway. Ancillary instrumentation to control gas humidification within these test fixtures is also under construction.

  10. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

  11. Performance evaluation of an advanced air-fuel ratio controller on a stationary, rich-burn natural gas engine

    NASA Astrophysics Data System (ADS)

    Kochuparampil, Roshan Joseph

    The advent of an era of abundant natural gas is making it an increasingly economical fuel source against incumbents such as crude oil and coal, in end-use sectors such as power generation, transportation and industrial chemical production, while also offering significant environmental benefits over these incumbents. Equipment manufacturers, in turn, are responding to widespread demand for power plants optimized for operation with natural gas. In several applications such as distributed power generation, gas transmission, and water pumping, stationary, spark-ignited, natural gas fueled internal combustion engines (ICEs) are the power plant of choice (over turbines) owing to their lower equipment and operational costs, higher thermal efficiencies across a wide load range, and the flexibility afforded to end-users when building fine-resolution horsepower topologies: modular size increments ranging from 100 kW -- 2 MW per ICE power plant compared to 2 -- 5 MW per turbine power plant. Under the U.S. Environment Protection Agency's (EPA) New Source Performance Standards (NSPS) and Reciprocating Internal Combustion Engine National Emission Standards for Hazardous Air Pollutants (RICE NESHAP) air quality regulations, these natural gas power plants are required to comply with stringent emission limits, with several states mandating even stricter emissions norms. In the case of rich-burn or stoichiometric natural gas ICEs, very high levels of sustained emissions reduction can be achieved through exhaust after-treatment that utilizes Non Selective Catalyst Reduction (NSCR) systems. The primary operational constraint with these systems is the tight air-fuel ratio (AFR) window of operation that needs to be maintained if the NSCR system is to achieve simultaneous reduction of carbon monoxide (CO), nitrogen oxides (NOx), total hydrocarbons (THC), volatile organic compounds (VOCs), and formaldehyde (CH 2O). Most commercially available AFR controllers utilizing lambda (oxygen

  12. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2002-07-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was completed at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. The product was effective as a flue gas conditioner. However, ongoing problems with in-duct deposition resulting from the flue gas conditioning were not entirely resolved. Primarily these problems were the result of difficulties encountered with retrofit of an existing spray humidification system. Eventually it proved necessary to replace all of the original injection lances and to manually bypass the PLC-based air/liquid feed control. This yielded substantial improvement in spray atomization and system reliability. However, the plant opted not to install a permanent system. Also in this quarter, preparations continued for a test of the cohesivity additives at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  13. Review of status and potential of tungsten-wire: Superalloy composites for advanced gas turbine engine blades

    NASA Technical Reports Server (NTRS)

    Signorelli, R. A.

    1972-01-01

    The current status of development of refractory-wire-superalloy composites and the potential for their application to turbine blades in land-based power generation and advanced aircraft engines are reviewed. The data indicate that refractory-wire-superalloy composites have application as turbine blades at temperatures of 2200 F and above.

  14. ASSESSING AND FORECASTING, BY PLAY, NATURAL GAS ULTIMATE RECOVERY GROWTH AND QUANTIFYING THE ROLE OF TECHNOLOGY ADVANCEMENTS IN THE TEXAS GULF COAST BASIN AND EAST TEXAS

    SciTech Connect

    William L. Fisher; Eugene M. Kim

    2000-12-01

    A detailed natural gas ultimate recovery growth (URG) analysis of the Texas Gulf Coast Basin and East Texas has been undertaken. The key to such analysis was determined to be the disaggregation of the resource base to the play level. A play is defined as a conceptual geologic unit having one or more reservoirs that can be genetically related on the basis of depositional origin of the reservoir, structural or trap style, source rocks and hydrocarbon generation, migration mechanism, seals for entrapment, and type of hydrocarbon produced. Plays are the geologically homogeneous subdivision of the universe of petroleum pools within a basin. Therefore, individual plays have unique geological features that can be used as a conceptual model that incorporates geologic processes and depositional environments to explain the distribution of petroleum. Play disaggregation revealed important URG trends for the major natural gas fields in the Texas Gulf Coast Basin and East Texas. Although significant growth and future potential were observed for the major fields, important URG trends were masked by total, aggregated analysis based on a broad geological province. When disaggregated by plays, significant growth and future potential were displayed for plays that were associated with relatively recently discovered fields, deeper reservoir depths, high structural complexities due to fault compartmentalization, reservoirs designated as tight gas/low-permeability, and high initial reservoir pressures. Continued technology applications and advancements are crucial in achieving URG potential in these plays.

  15. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  16. Advanced Flue Gas Desulfurization (AFGD) Demonstration Project. Technical progress report No. 15, July 1, 1993--September 30, 1993

    SciTech Connect

    Not Available

    1994-08-01

    The goal of this project is to demonstrate that, by combining state-of-the-art technology, highly efficient plant operation and maintenance capabilities and by-product gypsum sales, significant reductions of SO{sub 2} emissions can be achieved at approximately one-half the life cycle cost of a conventional Flue Gas Desulfurization (FGD) system. Further, this emission reduction is achieved without generating solid waste and while minimizing liquid wastewater effluent. Basically, this project entails the design, construction and operation of a nominal 600 MWe AFGD facility to remove SO{sub 2} from coal-fired power plant flue gas at the Northern Indiana Public Service Company`s Bailly Generating Station.

  17. Development of Metal-impregnated Single Walled Carbon Nanotubes for Toxic Gas Contaminant Control in Advanced Life Support Systems

    NASA Technical Reports Server (NTRS)

    Cinke, Martin; Li, Jing; Chen, Bin; Wignarajah, Kanapathipillai; Pisharody, Suresh A.; Fisher, John W.; Delzeit, Lance; Meyyappan, Meyya; Partridge, Harry; Clark, Kimberlee

    2003-01-01

    The success of physico-chemical waste processing and resource recovery technologies for life support application depends partly on the ability of gas clean-up systems to efficiently remove trace contaminants generated during the process with minimal use of expendables. Highly purified metal-impregnated carbon nanotubes promise superior performance over conventional approaches to gas clean-up due to their ability to direct the selective uptake gaseous species based both on the nanotube s controlled pore size, high surface area, and ordered chemical structure that allows functionalization and on the nanotube s effectiveness as a catalyst support material for toxic contaminants removal. We present results on the purification of single walled carbon nanotubes (SWCNT) and efforts at metal impregnation of the SWCNT's.

  18. Advanced separation technology for flue gas cleanup. Revised quarterly technical report No. 17, April--June 1996

    SciTech Connect

    Bhown, A.S.; Riggs, T.; Bahman, A.

    1996-10-01

    The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (a) a novel method for regeneration of spent SO{sub 2} scrubbing liquor and (b) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors, (HFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system will be designed to remove more than 95% of the SO{sub x} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. In addition, the process will make only marketable byproducts, if any (no waste streams).

  19. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-05-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of flyash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory flyash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  20. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-01-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the third reporting quarter, the electrostatic tensiometer for laboratory determination of flyash cohesivity was completed. Modifications were made to this method to improve repeatability. In addition, a new multi-cell laboratory flyash resistivity furnace was completed. Also during this quarter an agreement was reached for the initial field trial of the new additives at the City of Ames, Iowa Municipal Power Plant.

  1. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-10-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, progress was made in obtaining an industry partner for a long-term demonstration and in technology transfer activities. Engineering and equipment procurement activities related to the long-term demonstration were also completed.

  2. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-07-30

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

  3. Lurgi's MPG gasification plus Rectisol{reg_sign} gas purification - advanced process combination for reliable syngas production

    SciTech Connect

    2005-07-01

    Lurgi's Multi Purpose Gasification Process (MPG) is the reliable partial oxidation process to convert hydrocarbon liquids, slurries and natural gas into valuable syngas. The MPG burner has once again proven its capabilities in an ammonia plant based on asphalt gasification. Lurgi is operating the HP-POX demonstration plant together with the University of Freiberg, Germany. Gasification tests at pressures of up to 100 bar have shown that syngas for high pressure synthesis such as methanol and ammonia can be produced more economically. The Rectisol{reg_sign} gas purification process yields ultra clean synthesis gas which is required to avoid problems in the downstream synthesis. Pure carbon dioxide is produced as a separate stream and is readily available for sequestration, enhanced oil recovery or other uses. The reliability of the Rectisol{reg_sign} process and the confidence of plant operators in this process are acknowledged by the fact that more than 75% of the syngas produced world wide by coal, oil and waste gasification is purified in Rectisol{reg_sign} units. Virtually all coal gasification plants currently under construction rely on Rectisol{reg_sign}. The new, large GTL plants and hydrogen production facilities require effective CO{sub 2} removal. New developments make Rectisol{reg_sign} attractive for this task. 10 figs., 3 tabs., 2 photos.

  4. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2002-01-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

  5. Advances in Methane Isotope Measurements via Direct Absorption Spectroscopy with Applications to Oil and Gas Source Characterization

    NASA Astrophysics Data System (ADS)

    Yacovitch, T. I.; Herndon, S. C.; Roscioli, J. R.; Petron, G.; Shorter, J. H.; Jervis, D.; McManus, J. B.; Nelson, D. D.; Zahniser, M. S.; Kolb, C. E., Jr.

    2015-12-01

    Instrumental developments in the measurement of multiple isotopes of methane (12CH4, 13CH4 and 12CH3D) are presented. A first generation 8-micron instrument quantifies 12CH4 and 13CH4 at a 1-second rate via tunable infrared direct absorption spectroscopy (TILDAS). A second generation instrument uses two 3-micron intraband cascade lasers in an Aerodyne dual laser chassis for simultaneous measurement of 12CH4, 13CH4 and 12CH3D. Sensitivity and noise performance improvements are examined. The isotopic signature of methane provides valuable information for emission source identification of this greenhouse gas. A first generation spectrometer has been deployed in the field on a mobile laboratory along with a sophisticated 4-tank calibration system. Calibrations are done on an agressive schedule, allowing for the correction of measured isotope ratios to an absolute isotope scale. Distinct isotopic signatures are found for a number of emission sources in the Denver-Julesburg Basin: oil and gas gathering stations, compressor stations and processing plants; a municipal landfill, and dairy/cattle operations. The isotopic signatures are compared with measured ethane/methane ratios. These direct absorption measurements have larger uncertainties than samples measured via gas chromatography-mass spectrometry, but have several advantages over canister sampling methods: individual sources of short duration are easier to isolate; calibrated isotope ratio results are available immediately; replicate measurements on a single source are easily performed; and the number of sources sampled is not limited by canister availability and processing time.

  6. Aerodynamic performance of conventional and advanced design labyrinth seals with solid-smooth abradable, and honeycomb lands. [gas turbine engines

    NASA Technical Reports Server (NTRS)

    Stocker, H. L.; Cox, D. M.; Holle, G. F.

    1977-01-01

    Labyrinth air seal static and dynamic performance was evaluated using solid, abradable, and honeycomb lands with standard and advanced seal designs. The effects on leakage of land surface roughness, abradable land porosity, rub grooves in abradable lands, and honeycomb land cell size and depth were studied using a standard labyrinth seal. The effects of rotation on the optimum seal knife pitch were also investigated. Selected geometric and aerodynamic parameters for an advanced seal design were evaluated to derive an optimized performance configuration. The rotational energy requirements were also measured to determine the inherent friction and pumping energy absorbed by the various seal knife and land configurations tested in order to properly assess the net seal system performance level. Results indicate that: (1) seal leakage can be significantly affected with honeycomb or abradable lands; (2) rotational energy absorption does not vary significantly with the use of a solid-smooth, an abradable, or a honeycomb land; and (3) optimization of an advanced lab seal design produced a configuration that had leakage 25% below a conventional stepped seal.

  7. Thermo-fluid dynamic design study of single and double-inflow radial and single-stage axial steam turbines for open-cycle thermal energy conversion net power-producing experiment facility in Hawaii

    SciTech Connect

    Schlbeiri, T. . Dept. of Mechanical Engineering)

    1990-03-01

    The results of the study of the optimum thermo-fluid dynamic design concept are presented for turbine units operating within the open-cycle ocean thermal energy conversion (OC-OTEC) systems. The concept is applied to the first OC-OTEC net power producing experiment (NPPE) facility to be installed at Hawaii's natural energy laboratory. Detailed efficiency and performance calculations were performed for the radial turbine design concept with single and double-inflow arrangements. To complete the study, the calculation results for a single-stage axial steam turbine design are also presented. In contrast to the axial flow design with a relatively low unit efficiency, higher efficiency was achieved for single-inflow turbines. Highest efficiency was calculated for a double-inflow radial design, which opens new perspectives for energy generation from OC-OTEC systems.

  8. A Study of Advanced Materials for Gas Turbine Coatings at Elevated Temperatures Using Selected Microstructures and Characteristic Environments for Syngas Combustion

    SciTech Connect

    Ravinder Diwan; Patrick Mensah; Guoqiang Li; Nalini Uppu; Strphen Akwaboa; Monica Silva; Ebubekir Beyazoglu; Ogad Agu; Naresh Polasa; Lawrence Bazille; Douglas Wolfe; Purush Sahoo

    2011-02-10

    Thermal barrier coatings (TBCs) that can be suitable for use in industrial gas turbine engines have been processed and compared with electron beam physical vapor deposition (EBPVD) microstructures for applications in advanced gas turbines that use coal-derived synthesis gas. Thermo-physical properties have been evaluated of the processed air plasma sprayed TBCs with standard APS-STD and vertically cracked APS-VC coatings samples up to 1300 C. Porosity of these selected coatings with related microstructural effects have been analyzed in this study. Wet and dry thermal cycling studies at 1125 C and spalling resistance thermal cycling studies to 1200 C have also been carried out. Type I and Type II hot corrosion tests were carried out to investigate the effects of microstructure variations and additions of alumina in YSZ top coats in multi-layered TBC structures. The thermal modeling of turbine blade has also been carried out that gives the capability to predict in-service performance temperature gradients. In addition to isothermal high temperature oxidation kinetics analysis in YSZ thermal barrier coatings of NiCoCrAlY bond coats with 0.25% Hf. This can affect the failure behavior depending on the control of the thermally grown oxide (TGO) growth at the interface. The TGO growth kinetics is seen to be parabolic and the activation energies correspond to interfacial growth kinetics that is controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. The difference between oxidation behavior of the VC and STD structures are attributed to the effects of microstructure morphology and porosity on oxygen ingression into the zirconia and TGO layers. The isothermal oxidation resistance of the STD and VC microstructures is similar at temperatures up to 1200 C. However, the generally thicker TGO layer thicknesses and the slightly faster oxidation rates in the VC microstructures are attributed to the increased ingression of oxygen through the grain boundaries of the vertically

  9. Advanced gas cooled nuclear reactor materials evaluation and development program. Progress report, October 1, 1979-December 31, 1979

    SciTech Connect

    Not Available

    1980-04-18

    This report presents the results of work performed from October 1, 1979 through December 31, 1979. Work covered in this report includes the activities associated with the status of the simulated reactor helium supply system, testing equipment and gas chemistry analysis instrumentation and equipment. The progress in the screening test program is described. This includes: screening creep results, weight gain and post-exposure mechanical properties for materials thermally exposed at 750/sup 0/ and 850/sup 0/C (1382/sup 0/ and 1562/sup 0/F). In addition, the status of the data management system is described.

  10. Gas Research Institute advanced stimulation technology: A short course. Held in Calgary, Canada on April 28-29, 1997

    SciTech Connect

    1997-05-01

    This volume includes presentation materials prepared for a short course covering fundamental and practical information needed to understand and apply Advanced Stimulation Technology (AST). AST Deployment Program was designed to overcome barriers to the application of AST in today`s challenging economic environment. In addition to course materials, this workbook includes the short course agenda; a brief overview of AST methodology; a list of presenters with brief survey of their professional credentials and AST experience; concise information on the companies sponsoring the program; and some information on the technology transfer vehicles, i.e., information centers, publications, GRI/Net, and Regional Technology Transfer Agent program.

  11. Energy Savings and Economics of Advanced Control Strategies for Packaged Air-Conditioning Units with Gas Heat

    SciTech Connect

    Wang, Weimin; Katipamula, Srinivas; Huang, Yunzhi; Brambley, Michael R.

    2011-12-31

    Pacific Northwest National Laboratory (PNNL) with funding from the U.S. Department of Energy's Building Technologies Program (BTP) evaluated a number of control strategies that can be implemented in a controller, to improve the operational efficiency of the packaged air conditioning units. The two primary objectives of this research project are: (1) determine the magnitude of energy savings achievable by retrofitting existing packaged air conditioning units with advanced control strategies not ordinarily used for packaged units and (2) estimating what the installed cost of a replacement control with the desired features should be in various regions of the U.S. This document reports results of the study.

  12. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2003-02-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, two cohesivity-specific additive formulations, ADA-44C and ADA-51, were evaluated in a full-scale trial at the American Electric Power Conesville plant. Ammonia conditioning was also evaluated for comparison. ADA-51 and ammonia conditioning significantly reduced rapping and non-rapped particulate re-entrainment based on stack opacity monitor data. Based on the successful tests to date, ADA-51 will be evaluated in a long-term test.

  13. Development of advanced material composites for use as internal insulation for LH2 tanks (gas layer concept)

    NASA Technical Reports Server (NTRS)

    Gille, J. P.

    1972-01-01

    A program is described that was conducted to develop an internal insulation system for potential application to the liquid hydrogen tanks of a reusable booster, where the tanks would be subjected to repeated high temperatures. The design of the internal insulation is based on a unique gas layer concept, in which capillary or surface tension effects are used to maintain a stable gas layer, within a cellular core structure, between the tank wall and the contained liquid hydrogen. Specific objectives were to select materials for insulation systems that would be compatible with wall temperatures of 350 F and 650 F during reentry into the earth's atmosphere, and to fabricate and test insulation systems under conditions simulating the operating environment. A materials test program was conducted to evaluate the properties of candidate materials at elevated temperatures and at the temperature of liquid hydrogen, and to determine the compatibility of the materials with a hydrogen atmosphere at the appropriate elevated temperature. The materials that were finally selected included Kapton polyimide films, silicone adhesives, fiber glass batting, and in the case of the 350 F system, Teflon film.

  14. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-05-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During the fourth reporting quarter, laboratory-screening tests of more than 20 potential additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of flyash cohesivity. Resistivity was measured for each screening test with a new multi-cell laboratory flyash resistivity furnace constructed for this project. An initial field trial of three additive formulations was also conducted at the City of Ames, Iowa Municipal Power Plant.

  15. Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, April 1--June 30, 1998

    SciTech Connect

    Harrison, D.P.

    1998-09-01

    Twenty-five reduction/sulfidation tests plus one sulfidation/regeneration test were completed during the quarter. The reduction/sulfidation tests examined the behavior of six cerium oxide sorbents from different sources with reaction variables of temperature, pressure, gas composition and flow rate. Most significantly, steam was added to the sulfidation feed gas for the first time. Tests using pre-reduced sorbents and tests in which reduction and sulfidation occurred simultaneously were performed. Prebreakthrough H{sub 2}S concentrations less than 10 ppmv were obtained over a range of reaction conditions with prebreakthrough concentrations as low as 1 ppmv achieved at the most favorable conditions. The general response to reaction variables was as expected except when feed rate was varied. In some of these cases the FPD breakthrough time did not correspond to expectation. The single regeneration run was conducted at 600 C and 2 atm using 12% SO{sub 2} in N{sub 2} at a feet rate of 400 sccm. This was the first regeneration test at other than 1 atm pressure; favorable results were obtained. The only experimental objective remaining is additional high pressure regeneration testing.

  16. Advanced turbine design for coal-fueled engines. Phase 1, Erosion of turbine hot gas path blading: Final report

    SciTech Connect

    Wagner, J.H.; Johnson, B.V.

    1993-04-01

    The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

  17. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    Kenneth E. Baldrey

    2001-09-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  18. Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly technical progress report, July--September 1995

    SciTech Connect

    Harrison, D.P.

    1995-10-01

    Both the Antek total sulfur analyzer and the modifications to the Shimadzu GC-14A gas chromatograph to be used for analysis for SO{sub 2} and H{sub 2}S were delivered during the quarter. Problems were faced during the installation and calibration phases of both instruments. By the end of the quarter we believe that the GC problems have been solved, but problems remain with the Antek analyzer. It appears that too much sulfur (as SO{sub 2}) reaches the UV detector and causes it to become saturated. This shows up as a maximum in the instrument calibration curve. At 200 psia, the capillary flow restrictor allows a total flow rate of about 180 sccm, and the maximum occurs at about 1 % H{sub 2}S in the calibration gas. Reducing the pressure so that the total flow is reduced to about 25 sccm shifts the calibration curve maximum to about 5.7% H{sub 2}S. It appears that we must reduce the total flow rate to the detector or provide additional dilution. This may be accomplished by increasing the resistance of the capillary restrictor, by diverting a portion of the flow leaving the pyrotube to vent, or adding an inert such as N{sub 2} to the gases exiting the pyrotube. We are in contact with Antek representatives about the problem. Both the atmospheric pressure and high pressure electrobalances were used during the quarter to study the regeneration of FeS in atmospheres of O{sub 2}/N{sub 2} or H{sub 2}O/N{sub 2}. In the atmospheric pressure unit the effects of temperature (600 - 800{degrees}C), flow rate (130 - 500 sccm), and reactive gas mol fraction (0.005 to 0.03 O{sub 2} and 0.1 to 0.5 H{sub 2}O) are being studied. Regeneration tests completed to date in the high pressure unit have utilized only O{sub 2}/N. and the parameters studied include temperature (600 - 800{degrees}C), flow rate (500 - 1000 sccm), pressure (1 - 15 atm) ad O{sub 2} mol fraction (0.005 - 0.03).

  19. Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report 14, July--October 1997

    SciTech Connect

    Harrison, D.P.

    1997-10-01

    Experimental work during the quarter was limited to a series of CeO{sub 2} reduction tests using an atmospheric pressure electrobalance reactor. Both Rhonc-Poulenc and Molycorp CeO{sub 2} were tested over a temperature range of 600 to 1000{degrees}C in various reducing gas compositions. Experimental results are in reasonable agreement with equilibrium calculations of the oxygen partial pressure from CHEMQ coupled with earlier experimental results from Bevan and Kordis. Weight loss corresponding to the reduction of CeO{sub 2} to CeO{sub 1.86} was observed at 1000{degrees} in an atmosphere of 40% H{sub 2}, 3.5% CO{sub 2}, balance He. Helium was used as the carrier gas instead of nitrogen to reduce aerodynamic noise, and the H{sub 2} and CO{sub 2} concentrations were chosen since this mixture results in oxygen partial pressure similar to those expected in Shell gas. The experimental value of CeO{sub 1.86} compares quite favorably to the predicted value of CeO{sub 1.83}. One unexpected results was a weight loss of about 9% from Rhone-Poulenc CeO{sub 2} in an inert atmosphere at 600{degrees}C. BET surface area measurements of nine samples were performed consisting of as-received CeO{sub 2} (both Rhone Poulenc and Molycorp), as-received Al{sub 2}O{sub 3}, both CeO{sub 2} samples with Al{sub 2}O{sub 3} as initially charged to the reactor, and both CeO{sub 2}-Al{sub 2}O{sub 3} mixtures after multicycle sulfidation-regeneration tests. The BET surface area of the Rhone-Poulenc CeO{sub 2} was about 20 times larger than the surface area of Molycorp CeO{sub 2} which explains differences in sulfidation performance reported earlier. Finally a more complete search of the literature for thermodynamic data for cerium compounds was carried out. It appears that the free energy of formation of CeO{sub 2} as a function of temperature is well defined.

  20. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect

    C. Jean Bustard

    2003-12-01

    ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

  1. Evaluation of advanced gas processing concepts for fluidized-bed gasification. Topical report, November 1985-December 1987

    SciTech Connect

    Smelser, S.C.; Ravikumar, R.H.; Mako, P.F.; Tu, H.S.; Wong, P.S.

    1989-01-01

    First-pass plant designs and cost estimates were prepared to evaluate the CNG H/sub 2/S removal process, the CNG CO/sub 2/ removal process, and GRI's direct methanation process in the context of plants that convert western coal to 125 MMM Btu day of pipeline gas using KRW gasifiers. Four different plant designs, one prepared earlier and three developed in the study, are compared. The results of the evaluations indicate: CNG H/sub 2/S removal technology is competitive with Selexol H/sub 2/S removal technology, provided the process matures without significant increase in the capital costs; the concept for CNG CO/sub 2/ removal technology is noncompetitive with Selexol CO/sub 2/ removal technology; and direct methanation is quite attractive compared to conventional methanation.

  2. Advanced turbine design for coal-fueled engines. Phase 2, Corrosion of turbine hot gas path blading: Final report, December 1988--February 1993

    SciTech Connect

    Bornstein, N.

    1993-06-01

    The environment within the advanced industrial gas turbine is highly oxidizing and contains the compounds, salts and oxides that accelerate the rate of oxidation of structural materials. Protective coatings which differ from each other and the superalloys in composition and phase morphology, enhance the oxidation and corrosion resistance of the superalloys. As temperatures increase, the relativity stability and long term effectiveness of the coatings is of concern. The interdiffusion of coating and alloy constituents can affect chemical and mechanical properties. Long term studies are appropriate. Thermal barrier coatings, introduced at the inception of the current program will further improve the thermal efficiency of industrial gas turbine engines. The interaction between state-of-the-art thermal barrier coatings (TBC) and oxidation and corrosion in the coal fired environment is of concern and should be critically examined. The superior performance of the overlay coating is related to thickness rather than chemistry. With respect to sodium sulfate corrosion, the life of the overlay coating is 2.7 times longer than that of the platinum aluminide which in turn is 2.2 times longer than that of the simple aluminide. The ranking of the coatings is unchanged with respect to eutectic soft corrosion, however the salt is more aggressive. The life of the overlay coating is 1.4 times longer than that of the platinum aluminide which is 1.9 times longer than that of the simple aluminide.

  3. Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China

    SciTech Connect

    Yang, C.; Zeng, G.; Li, G.; Qiu, J.

    1999-07-01

    Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

  4. OTEC gas-desorption studies

    SciTech Connect

    Chen, F.C.; Golshani, A.

    1981-01-01

    OTEC gas desorption studies were initiated with the goal of mitigating these effects and were carried out in four areas: (1) vacuum deaeration in a packed column, (2) deaeration in a barometric water intake system, (3) noncondensibles disposal through hydraulic air compression, and (4) OTEC deaeration subsystems' analysis. Laboratory experiments to date have completed the vacuum deaeration test of three different kinds of packings, barometric intake deaeration experiments, and a series of hydraulic air compression tests. Preliminary analyses based on the experimental data have shown that, as compared to the previous baseline study, reduction both in deaerator cost and pumping power can be realized with a combination of barometric intake and packed column deaeration. The design and operation of the gas desorption test loop, experimental and computer simulation results obtained, and an analysis of OTEC deaeration subsystem design based on the test results and their implication on OTEC open-cycle power systems are presented.

  5. An advanced CFD model to study the effect of non-condensable gas on cavitation in positive displacement pumps

    NASA Astrophysics Data System (ADS)

    Iannetti, Aldo; Stickland, Matthew T.; Dempster, William M.

    2015-09-01

    An advanced transient CFD model of a positive displacement reciprocating pump was created to study its behavior and performance in cavitating condition during the inlet stroke. The "full" cavitation model developed by Singhal et al. was utilized, and a sensitivity analysis test on two air mass fraction amounts (1.5 and 15 parts per million) was carried out to study the influence of the dissolved air content in water on the cavitation phenomenon. The model was equipped with user defined functions to introduce the liquid compressibility, which stabilizes the simulation, and to handle the two-way coupling between the pressure field and the inlet valve lift history. Estimation of the performance is also presented in both cases.

  6. Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program. Progress report, July 1, 1980-September 30, 1980

    SciTech Connect

    Not Available

    1980-12-12

    Objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Nuclear Process Heat (NPH) and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (helium containing small amounts of various other gases), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Work covered in this report includes the activities associated with the status of the simulated reactor helium supply system, testing equipment and gas chemistry analysis instrumentation and equipment. The progress in the screening test program is described: screening creep results and metallographic analysis for materials thermally exposed or tested at 750, 850, 950 and 1050/sup 0/C. Initiation of controlled purity helium creep-rupture testing in the intensive screening test program is discussed. In addition, the results of 1000-hour exposures at 750 and 850/sup 0/C on several experimental alloys are discussed.

  7. Recent advances in combustion flow-field imaging measurements in high-pressure liquid-fueled gas turbine combustor concepts

    NASA Astrophysics Data System (ADS)

    Locke, Randy J.; Hicks, Yolanda R.; Zaller, Michelle M.; Anderson, Robert C.

    1999-12-01

    Future gas turbine combustor designs for aerospace applications will be required to meet severe restrictions on environmentally harmful emissions. To meet the target emission reduction goals, these combustors will operate at temperatures and pressures greatly exceeding those of present day aero-powerplants. New diagnostic methods are required to provide insight into understanding the complex physical and chemical processes extant at these conditions because traditional diagnostic methods are either insufficient or incapable of providing this knowledge. At NASA Glenn Research Center (GRC), several optically accessible combustor rigs have been built which allow the implementation of a suite of optical diagnostic techniques that are capable of providing just this type of crucial information. The techniques employed in the GRC combustion research laboratory include planar laser-induced fluorescence and planar Mie scattering. Research efforts have been quite successful probing both non-reacting and reacting flowfields of many kerosene-fueled combustor and combustor subcomponent design at pressures approaching 2.0 MPa, and temperatures near 2100 K. Images that map out combustion intermediate species such as OH distribution, fuel spray patternation, and fuel to air ratio contour mapping have been obtained for many different fuel injector designs and configurations. A novel combination of multiple planar images and computational analysis allows a 3D capability that greatly enhances the evaluation of the combustion processes and flowfields examined in this study.

  8. Development of advanced combustion technology for medium- and high-speed natural gas engines. Final report, January 1985-February 1989

    SciTech Connect

    Snyder, W.E.

    1989-07-01

    The project investigated the several variables which influence the performance of pre-chamber equipped, lean-burn natural gas engines in general, and of the pre-chamber in particular. The effort was divided into four closely inter-related phases: Theoretical Analysis, Constant Volume Combustion (CVC) Rig Tests, Single Cylinder Engine Tests and Multi-Cylinder Engine Tests. The Theoretical Analysis was directed toward development of a computer program, called COGEN, which was then used to predict output performance trends resulting from changes to input parameters. The CVC Rig Test program was directed towards an improved understanding of the pre-chamber combustion process using high speed photography and simultaneous measurement of instantaneous pressures. Variations of pre-chamber size, throat design and air-fuel ratio were studied to guide the later engine test programs. The Single Cylinder Engine Tests were directed towards bridging the gap between the CVC Test Rig and the performance to be expected from a commercial multi-cylinder engine. Variations in pre-chamber design as well as engine compression ratio, Intake Manifold Temperature and load were investigated.

  9. Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program. Progress report, April 1, 1980-June 30, 1980

    SciTech Connect

    Not Available

    1980-11-14

    Objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Nuclear Process Heat (NPH) and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (helium containing small amounts of various other gases), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Work covered in this report includes the activities associated with the status of the simulated reactor helium supply system, testing equipment and gas chemistry analysis instrumentation and equipment. The progress in the screening test program is described; this includes: screening creep results and metallographic analysis for materials thermally exposed or tested at 750, 850 and 950/sup 0/C. The initiation of air creep-rupture testing in the intensive screening test program is discussed. In addition, the status of the data management system is described.

  10. Active Combustion Control for Aircraft Gas-Turbine Engines-Experimental Results for an Advanced, Low-Emissions Combustor Prototype

    NASA Technical Reports Server (NTRS)

    DeLaat, John C.; Kopasakis, George; Saus, Joseph R.; Chang, Clarence T.; Wey, Changlie

    2012-01-01

    Lean combustion concepts for aircraft engine combustors are prone to combustion instabilities. Mitigation of instabilities is an enabling technology for these low-emissions combustors. NASA Glenn Research Center s prior activity has demonstrated active control to suppress a high-frequency combustion instability in a combustor rig designed to emulate an actual aircraft engine instability experience with a conventional, rich-front-end combustor. The current effort is developing further understanding of the problem specifically as applied to future lean-burning, very low-emissions combustors. A prototype advanced, low-emissions aircraft engine combustor with a combustion instability has been identified and previous work has characterized the dynamic behavior of that combustor prototype. The combustor exhibits thermoacoustic instabilities that are related to increasing fuel flow and that potentially prevent full-power operation. A simplified, non-linear oscillator model and a more physics-based sectored 1-D dynamic model have been developed to capture the combustor prototype s instability behavior. Utilizing these models, the NASA Adaptive Sliding Phasor Average Control (ASPAC) instability control method has been updated for the low-emissions combustor prototype. Active combustion instability suppression using the ASPAC control method has been demonstrated experimentally with this combustor prototype in a NASA combustion test cell operating at engine pressures, temperatures, and flows. A high-frequency fuel valve was utilized to perturb the combustor fuel flow. Successful instability suppression was shown using a dynamic pressure sensor in the combustor for controller feedback. Instability control was also shown with a pressure feedback sensor in the lower temperature region upstream of the combustor. It was also demonstrated that the controller can prevent the instability from occurring while combustor operation was transitioning from a stable, low-power condition to

  11. Advances in the metabolic profiling of acidic compounds in children's urines achieved by comprehensive two-dimensional gas chromatography.

    PubMed

    Vasquez, N Pérez; Crosnier de Bellaistre-Bonose, M; Lévêque, N; Thioulouse, E; Doummar, D; Billette de Villemeur, T; Rodriguez, D; Couderc, R; Robin, S; Courderot-Masuyer, C; Moussa, F

    2015-10-01

    The main objective of this work was to evaluate a comprehensive two-dimensional gas chromatographic (GCxGC) coupled to quadrupole mass spectrometry (qMS) method in the field of biomarker candidates' discovery. To this purpose we developed a GCxGC-qMS method suitable for the separation of organic acids and other classes of compounds with silylable polar hydrogen such as sugars, amino-acids, and vitamins. As compared to those obtained by a widely used 1D-GC method, the urinary chromatographic profiles performed by the proposed 2D-GC method exhibit higher resolution and sensitivity, leading to the detection of up to 92 additional compounds in some urine samples including some well-known biomarkers. In order to validate the proposed method we focused on three metabolites of interest with various functional groups and polarities including CH3-malonic acid (MMA: biomarker of methylmalonic acidemia), 3-hydroxy-3-methyl-glutaric acid (3-OHMGA: biomarker of 3-hydroxy-3-methylglutaric acidemia), and phenylpiruvic acid (PhPA: marker of phenylketonuria). While these three metabolites can be considered as representative of organic acids classically determined by 1D-GC, they cannot be representative of new detected metabolites. Thus, we also focused on quinolic acid (QUIN), taken as an example of biomarker not detected at basal levels with the classical 1D GC-qMS method. In order to obtain sufficient recoveries for all tested compounds, we developed a sample preparation protocol including a step of urea removal followed by two extraction steps using two solvents of different polarity and selectivity. Recoveries with the proposed method reached more than 80% for all targeted compounds and the linearity was satisfactory up to 50μmol/L. The CVs of the within-run and within-laboratory precisions were less than 8% for all tested compounds. The limits of quantification (LOQs) were 0.6μmol/L for MMA, 0.4μmol/L for 3-OHMGA, 0.7μmol/L for PhPA, and 1μmol/L for QUIN. The LOQs of

  12. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel

  13. Recent advances in experimental techniques to probe fast excited-state dynamics in biological molecules in the gas phase: dynamics in nucleotides, amino acids and beyond

    PubMed Central

    Staniforth, Michael; Stavros, Vasilios G.

    2013-01-01

    In many chemical reactions, an activation barrier must be overcome before a chemical transformation can occur. As such, understanding the behaviour of molecules in energetically excited states is critical to understanding the chemical changes that these molecules undergo. Among the most prominent reactions for mankind to understand are chemical changes that occur in our own biological molecules. A notable example is the focus towards understanding the interaction of DNA with ultraviolet radiation and the subsequent chemical changes. However, the interaction of radiation with large biological structures is highly complex, and thus the photochemistry of these systems as a whole is poorly understood. Studying the gas-phase spectroscopy and ultrafast dynamics of the building blocks of these more complex biomolecules offers the tantalizing prospect of providing a scientifically intuitive bottom-up approach, beginning with the study of the subunits of large polymeric biomolecules and monitoring the evolution in photochemistry as the complexity of the molecules is increased. While highly attractive, one of the main challenges of this approach is in transferring large, and in many cases, thermally labile molecules into vacuum. This review discusses the recent advances in cutting-edge experimental methodologies, emerging as excellent candidates for progressing this bottom-up approach. PMID:24204191

  14. Gas gun shock experiments with single-pulse x-ray phase contrast imaging and diffraction at the Advanced Photon Source

    NASA Astrophysics Data System (ADS)

    Luo, S. N.; Jensen, B. J.; Hooks, D. E.; Fezzaa, K.; Ramos, K. J.; Yeager, J. D.; Kwiatkowski, K.; Shimada, T.

    2012-07-01

    The highly transient nature of shock loading and pronounced microstructure effects on dynamic materials response call for in situ, temporally and spatially resolved, x-ray-based diagnostics. Third-generation synchrotron x-ray sources are advantageous for x-ray phase contrast imaging (PCI) and diffraction under dynamic loading, due to their high photon fluxes, high coherency, and high pulse repetition rates. The feasibility of bulk-scale gas gun shock experiments with dynamic x-ray PCI and diffraction measurements was investigated at the beamline 32ID-B of the Advanced Photon Source. The x-ray beam characteristics, experimental setup, x-ray diagnostics, and static and dynamic test results are described. We demonstrate ultrafast, multiframe, single-pulse PCI measurements with unprecedented temporal (<100 ps) and spatial (˜2 μm) resolutions for bulk-scale shock experiments, as well as single-pulse dynamic Laue diffraction. The results not only substantiate the potential of synchrotron-based experiments for addressing a variety of shock physics problems, but also allow us to identify the technical challenges related to image detection, x-ray source, and dynamic loading.

  15. Gas gun shock experiments with single-pulse x-ray phase contrast imaging and diffraction at the Advanced Photon Source.

    PubMed

    Luo, S N; Jensen, B J; Hooks, D E; Fezzaa, K; Ramos, K J; Yeager, J D; Kwiatkowski, K; Shimada, T

    2012-07-01

    The highly transient nature of shock loading and pronounced microstructure effects on dynamic materials response call for in situ, temporally and spatially resolved, x-ray-based diagnostics. Third-generation synchrotron x-ray sources are advantageous for x-ray phase contrast imaging (PCI) and diffraction under dynamic loading, due to their high photon fluxes, high coherency, and high pulse repetition rates. The feasibility of bulk-scale gas gun shock experiments with dynamic x-ray PCI and diffraction measurements was investigated at the beamline 32ID-B of the Advanced Photon Source. The x-ray beam characteristics, experimental setup, x-ray diagnostics, and static and dynamic test results are described. We demonstrate ultrafast, multiframe, single-pulse PCI measurements with unprecedented temporal (<100 ps) and spatial (∼2 μm) resolutions for bulk-scale shock experiments, as well as single-pulse dynamic Laue diffraction. The results not only substantiate the potential of synchrotron-based experiments for addressing a variety of shock physics problems, but also allow us to identify the technical challenges related to image detection, x-ray source, and dynamic loading.

  16. Characterizing the effects of elevated temperature on the air void pore structure of advanced gas-cooled reactor pressure vessel concrete using x-ray computed tomography

    NASA Astrophysics Data System (ADS)

    Stein, R. C.; Petkovski, M.; Engelberg, D. L.; Leonard, F.; Withers, P. J.

    2013-07-01

    X-ray computed tomography (X-ray CT) has been applied to nondestructively characterise changes in the microstructure of a concrete used in the pressure vessel structure of Advanced Gas-cooled Reactors (AGR) in the UK. Concrete specimens were conditioned at temperatures of 105 °C and 250 °C, to simulate the maximum thermal load expected to occur during a loss of coolant accident (LOCA). Following thermal treatment, these specimens along with an unconditioned control sample were characterised using micro-focus X-ray CT with a spatial resolution of 14.6 microns. The results indicate that the air void pore structure of the specimens experienced significant volume changes as a result of the increasing temperature. The increase in the porous volume was more prevalent at 250 °C. Alterations in air void size distributions were characterized with respect to the unconditioned control specimen. These findings appear to correlate with changes in the uni-axial compressive strength of the conditioned concrete.

  17. Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 4: Open recuperated and bottomed gas turbine cycles. [performance prediction and energy conversion efficiency of gas turbines in electric power plants (thermodynamic cycles)

    NASA Technical Reports Server (NTRS)

    Amos, D. J.; Grube, J. E.

    1976-01-01

    Open-cycle recuperated gas turbine plant with inlet temperatures of 1255 to 1644 K (1800 to 2500 F) and recuperators with effectiveness values of 0, 70, 80 and 90% are considered. A 1644 K (2500 F) gas turbine would have a 33.5% plant efficiency in a simple cycle, 37.6% in a recuperated cycle and 47.6% when combined with a sulfur dioxide bottomer. The distillate burning recuperated plant was calculated to produce electricity at a cost of 8.19 mills/MJ (29.5 mills/kWh). Due to their low capital cost $170 to 200 $/kW, the open cycle gas turbine plant should see duty for peaking and intermediate load duty.

  18. The Coal-Seq III Consortium. Advancing the Science of CO2 Sequestration in Coal Seam and Gas Shale Reservoirs

    SciTech Connect

    Koperna, George

    2014-03-14

    The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3 expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was applied to

  19. Testimony of Fred R. Mynatt before the Energy Research and Development Subcommittee of the Committee on Science, Space, and Technology, US House of Representatives. [Advanced fuel technology, gas-cooled reactor technology, and liquid metal-cooled reactor technology programs

    SciTech Connect

    Mynatt, F.R.

    1987-03-18

    This report provides a description of the statements submitted for the record to the committee on Science, Space, and Technology of the United States House of Representatives. These statements describe three principal areas of activity of the Advanced Reactor Technology Program of the Department of Energy (DOE). These areas are advanced fuel cycle technology, modular high-temperature gas-cooled reactor technology, and liquid metal-cooled reactor. The areas of automated reactor control systems, robotics, materials and structural design shielding and international cooperation were included in these statements describing the Oak Ridge National Laboratory's efforts in these areas. (FI)

  20. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect

    Unknown

    1999-10-01

    The activities of the AGTSR Program during this reporting period are described in this quarterly report. The report text is divided into discussions on Membership, Administration, Technology Transfer (Workshop/Education) and Research. Items worthy of note are highlighted below with additional detail following in the text of the report.

  1. The Windscale Advanced Gas Cooled Reactor (WAGR) Decommissioning Project A Close Out Report for WAGR Decommissioning Campaigns 1 to 10 - 12474

    SciTech Connect

    Halliwell, Chris

    2012-07-01

    The reactor core of the Windscale Advanced Gas-Cooled Reactor (WAGR) has been dismantled as part of an ongoing decommissioning project. The WAGR operated until 1981 as a development reactor for the British Commercial Advanced Gas cooled Reactor (CAGR) power programme. Decommissioning began in 1982 with the removal of fuel from the reactor core which was completed in 1983. Subsequently, a significant amount of engineering work was carried out, including removal of equipment external to the reactor and initial manual dismantling operations at the top of the reactor, in preparation for the removal of the reactor core itself. Modification of the facility structure and construction of the waste packaging plant served to provide a waste route for the reactor components. The reactor core was dismantled on a 'top-down' basis in a series of 'campaigns' related to discrete reactor components. This report describes the facility, the modifications undertaken to facilitate its decommissioning and the strategies employed to recognise the successful decommissioning of the reactor. Early decommissioning tasks at the top of the reactor were undertaken manually but the main of the decommissioning tasks were carried remotely, with deployment systems comprising of little more than crane like devices, intelligently interfaced into the existing structure. The tooling deployed from the 3 tonne capacity (3te) hoist consisted either purely mechanical devices or those being electrically controlled from a 'push-button' panel positioned at the operator control stations, there was no degree of autonomy in the 3te hoist or any of the tools deployed from it. Whilst the ATC was able to provide some tele-robotic capabilities these were very limited and required a good degree of driver input which due to the operating philosophy at WAGR was not utilised. The WAGR box proved a successful waste package, adaptable through the use of waste box furniture specific to the waste-forms generated throughout

  2. Regolith and Environment Science and Oxygen and Lunar Volatile Extraction (RESOLVE): Lunar Advanced Volatile Analysis (LAVA) Capillary Fluid Dynamic Restriction Effects on Gas Chromatography

    NASA Technical Reports Server (NTRS)

    Gonzalez, Marianne; Quinn, Jacqueline; Captain, Janine; Santiago-Bond, Josephine; Starr, Stanley

    2015-01-01

    The Resource Prospector (RP) mission with the Regolith and Environment Science and Oxygen Lunar Volatile Extraction (RESOLVE) payload aims to show the presence of water in lunar regolith, and establish a proving ground for NASAs mission to Mars. One of the analysis is performed by the Lunar Advanced Volatiles Analysis (LAVA) subsystem, which consists of a fluid network that facilitates the transport of volatile samples to a gas chromatograph and mass spectrometer (GC-MS) instrument. The understanding of fluid dynamics directed from the GC to the MS is important due to the influence of flow rates and pressures that affect the accuracy of and prevent the damage to the overall GC-MS instrument. The micro-scale capillary fluid network within the GC alone has various lengths and inner-diameters; therefore, determination of pressure differentials and flow rates are difficult to model computationally, with additional complexity from the vacuum conditions in space and lack of a lunar atmosphere. A series of tests were performed on an experimental set-up of the system where the inner diameters of the GC transfer line connecting to the MS were varied. The effect on chromatography readings were also studied by applying these lines onto a GC instrument. It was found that a smaller inner diameter transfer line resulted in a lower flow rate, as well as a lower pressure differential across the thermal conductivity detector (TCD) unit of the GC and a negligible pressure drop across the mock-up capillary column. The chromatography was affected with longer retention times and broader peak integrations. It was concluded that a 0.050 mm inner diameter line still proved most suitable for the systems flow rate preferences. In addition, it was evident that this small transfer line portrayed some expense to GC signal characteristics and the wait time for steady-state operation.

  3. Advanced bioreactor concepts for gaseous substrates: Conversion of synthesis gas to liquid fuels and removal of SO{sub x} and NO{sub x} from coal combustion gases. CRADA final report

    SciTech Connect

    Kaufman, E.N.; Selvaraj, P.T.

    1997-10-01

    The purpose of the proposed research program was the development and demonstration of a new generation of gaseous substrate-based bioreactors for the production of liquid fuels from coal synthesis gas and the removal of NO{sub x} and SO{sub x} species from coal combustion flue gas. This study addressed the further investigation of optimal bacterial strains, growth media and kinetics for the biocatalytic conversion of coal synthesis gas to liquid fuel such as ethanol and the reduction of gaseous flue gas constituents. The primary emphasis was on the development of advanced bioreactor systems coupled with innovative biocatalytic systems that will provide increased productivity under controlled conditions. It was hoped that this would result in bioprocessing options that have both technical and economic feasibility, thus, ensuring early industrial use. Predictive mathematical models were formulated to accommodate hydrodynamics, mass transport, and conversion kinetics, and provide the data base for design and scale-up. The program was separated into four tasks: (1) Optimization of Biocatalytic Kinetics; (2) Development of Well-mixed and Columnar Reactors; (3) Development of Predictive Mathematical Models; and (4) Industrial Demonstration. Research activities addressing both synthesis gas conversion and flue gas removal were conducted in parallel by BRI and ORNL respectively.

  4. Fuel containment and stability in the gas core nuclear rocket. Final report, April 15, 1993--April 14, 1994

    SciTech Connect

    Kammash, T.

    1996-02-01

    One of the most promising approaches to advanced propulsion that could meet the objectives of the Space Exploration Initiative (SEI) is the open cycle gas core nuclear rocket (GCR). The energy in this device is generated by a fissioning uranium plasma which heats, through radiation, a propellant that flows around the core and exits through a nozzle, thereby converting thermal energy into thrust. Although such a scheme can produce very attractive propulsion parameters in the form of high specific impulse and high thrust, it does suffer from serious physics and engineering problems that must be addressed if it is to become a viable propulsion system. Among the major problems that must be solved are the confinement of the uranium plasma, potential instabilities and control problems associated with the dynamics of the uranium core, and the question of startup and fueling of such a reactor. In this paper, the authors focus their attention on the problems of equilibria and stability of the uranium care, and examine the potential use of an externally applied magnetic field for these purposes. They find that steady state operation of the reactor is possible only for certain care profiles that may not be compatible with the radiative aspect of the system. The authors also find that the system is susceptible to hydrodynamic and acoustic instabilities that could deplete the uranium fuel in a short time if not properly suppressed.

  5. Modeling RP-1 fuel advanced distillation data using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry and partial least squares analysis.

    PubMed

    Kehimkar, Benjamin; Parsons, Brendon A; Hoggard, Jamin C; Billingsley, Matthew C; Bruno, Thomas J; Synovec, Robert E

    2015-01-01

    Recent efforts in predicting rocket propulsion (RP-1) fuel performance through modeling put greater emphasis on obtaining detailed and accurate fuel properties, as well as elucidating the relationships between fuel compositions and their properties. Herein, we study multidimensional chromatographic data obtained by comprehensive two-dimensional gas chromatography combined with time-of-flight mass spectrometry (GC × GC-TOFMS) to analyze RP-1 fuels. For GC × GC separations, RTX-Wax (polar stationary phase) and RTX-1 (non-polar stationary phase) columns were implemented for the primary and secondary dimensions, respectively, to separate the chemical compound classes (alkanes, cycloalkanes, aromatics, etc.), providing a significant level of chemical compositional information. The GC × GC-TOFMS data were analyzed using partial least squares regression (PLS) chemometric analysis to model and predict advanced distillation curve (ADC) data for ten RP-1 fuels that were previously analyzed using the ADC method. The PLS modeling provides insight into the chemical species that impact the ADC data. The PLS modeling correlates compositional information found in the GC × GC-TOFMS chromatograms of each RP-1 fuel, and their respective ADC, and allows prediction of the ADC for each RP-1 fuel with good precision and accuracy. The root-mean-square error of calibration (RMSEC) ranged from 0.1 to 0.5 °C, and was typically below ∼0.2 °C, for the PLS calibration of the ADC modeling with GC × GC-TOFMS data, indicating a good fit of the model to the calibration data. Likewise, the predictive power of the overall method via PLS modeling was assessed using leave-one-out cross-validation (LOOCV) yielding root-mean-square error of cross-validation (RMSECV) ranging from 1.4 to 2.6 °C, and was typically below ∼2.0 °C, at each % distilled measurement point during the ADC analysis.

  6. Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 1: Introduction and summary and general assumptions. [energy conversion systems for electric power plants using coal - feasibility

    NASA Technical Reports Server (NTRS)

    Beecher, D. T.

    1976-01-01

    Nine advanced energy conversion concepts using coal or coal-derived fuels are summarized. They are; (1) open-cycle gas turbines, (2) combined gas-steam turbine cycles, (3) closed-cycle gas turbines, (4) metal vapor Rankine topping, (5) open-cycle MHD; (6) closed-cycle MHD; (7) liquid-metal MHD; (8) advanced steam; and (9) fuel cell systems. The economics, natural resource requirements, and performance criteria for the nine concepts are discussed.

  7. PIGC™ - A low cost fugitive emissions and methane detection system using advanced gas filter correlation techniques for local and wide area monitoring

    NASA Astrophysics Data System (ADS)

    Lachance, R. L.; Gordley, L. L.; Marshall, B. T.; Fisher, J.; Paxton, G.; Gubeli, J. F.

    2015-12-01

    Currently there is no efficient and affordable way to monitor gas releases over small to large areas. We have demonstrated the ability to accurately measure key greenhouse and pollutant gasses with low cost solar observations using the breakthrough sensor technology called the "Pupil Imaging Gas Correlation", PIGC™, which provides size and complexity reduction while providing exceptional resolution and coverage for various gas sensing applications. It is a practical implementation of the well-known Gas Filter Correlation Radiometry (GFCR) technique used for the HALOE and MOPITT satellite instruments that were flown on successful NASA missions in the early 2000s. This strong space heritage brings performance and reliability to the ground instrument design. A methane (CH4) abundance sensitivity of 0.5% or better of ambient column with uncooled microbolometers has been demonstrated with 1 second direct solar observations. These under $10 k sensors can be deployed in precisely balanced autonomous grids to monitor the flow of chosen gasses, and infer their source locations. Measureable gases include CH4, 13CO2, N2O, NO, NH3, CO, H2S, HCN, HCl, HF, HDO and others. A single instrument operates in a dual operation mode, at no additional cost, for continuous (real-time 24/7) local area perimeter monitoring for the detection of leaks for safety & security needs, looking at an artificial light source (for example a simple 60 W light bulb placed 100 m away), while simultaneously allowing solar observation for quasi-continuous wide area total atmospheric column scanning (3-D) for environmental monitoring (fixed and mobile configurations). The second mode of operation continuously quantifies the concentration and flux of specific gases over different ground locations, determined the amount of targeted gas being released from the area or getting into the area from outside locations, allowing better tracking of plumes and identification of sources. This paper reviews the

  8. Stress trajectory and advanced hydraulic-fracture simulations for the Eastern Gas Shales Project. Final report, April 30, 1981-July 30, 1983

    SciTech Connect

    Advani, S.H.; Lee, J.K.

    1983-01-01

    A summary review of hydraulic fracture modeling is given. Advanced hydraulic fracture model formulations and simulation, using the finite element method, are presented. The numerical examples include the determination of fracture width, height, length, and stress intensity factors with the effects of frac fluid properties, layered strata, in situ stresses, and joints. Future model extensions are also recommended. 66 references, 23 figures.

  9. Recent advancements in the "water-window" microscopy with laser-plasma SXR source based on a double stream gas-puff target

    NASA Astrophysics Data System (ADS)

    Wachulak, P. W.

    2016-09-01

    An overview of our recent developments, regarding "water-window" soft X-ray (SXR) microscopy based on a laser-plasma double stream gas puff target sources is presented. The work, presented herein, describes two approaches to SXR microscopy. The first one is a low spatial resolution, achromatic SXR microscopy, employing Wolter type-I objective. The second one is a nanometer spatial resolution SXR microscopy, with the use of a Fresnel zone plate objective, for imaging various objects with quasimonochromatic light, emitted from a double stream gas puff target based short wavelength source. The developments regarding both systems are presented, as well as the possible applications, for which the SXR microscope was already employed. Such compact, table-top size, laboratory type microscopy setups may be employed in the near future for complementary-like studies to other, often used, microscopy techniques.

  10. Staged field experiment No. 4: Application of advanced technologies in tight gas sandstones. Frontier formation, Chimney Buttes Field, Sublette County, Wyoming. Topical report

    SciTech Connect

    Not Available

    1992-09-01

    The Gas Research Institute has sponsored research directed towards improving the recovery efficiency and reducing the cost of producing gas from tight reservoirs. In support of the goal, the Staged Field Experiment (SFE) project was implemented. The document provides the results of the research work performed on the SFE No. 4 well. Following an extensive site selection effort, the Frontier Formation along the Moxa Arch was selected as the target formation for SFE No. 4 research. Cooperative well data acquisition and analysis led to the selection of the SFE No. 4 site in the Chimney Buttes Field located in Section 24, T28N R113W. The open-hole and data acquisition programs designed and implemented on the SFE No. 4 well supported the goal of determining the most effective combination of formation evaluation (geological, petrophysical and engineering), fracture diagnostics, hydraulic fracturing and fracture modeling techniques to reduce the cost of producing gas from tight formations such as the Frontier. Analyses of these data, presented in detail in the report, determined that the target Second Bench of the Second Frontier was found to have a thin (approximately 10 ft), tight (ranging from 0.004 to 0.008 md) reservoir unit which had pre-frac flow rates measured at 9 MCFD. Higher than expected stress gradients were measured in in-situ stress tests. Several fluid-only mini-frac injections were attempted but aborted when pressure limitations of surface equipment were reached.

  11. PFB coal fired combined cycle development program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume B. Developmental cyclone evaluation

    SciTech Connect

    Not Available

    1980-02-01

    This report summarizes the results of cold flow model testing of a conventional reverse-flow cyclone containing several developmental features designed to improve its separative performance. The four advanced features evaluated were: Outlet Scroll Skimming - to remove particles from the high dust concentration region at the periphery of the outlet dust; Base Purge - to reduce reentrainment of dust from the disengagement hopper; Increased Outlet Duct Engagement - to reduce short-circuiting of the inlet dust into the outlet; and Vortex Shield - to stabilize the point of vortex attachment at the cyclone base and thus reduce base pickup. A schematic of the advanced cyclone, showing the various developmental features, is provided. The results of the cold flow experiments showed that substantial improvement (approximately 30% reduction in exhaust emission) could be obtained from outlet skimming or from increased engagement of the exhaust dust. Furthermore, the effects of these features are additive so that about 60% overall reduction in emissions could be achieved by incorporating both of these elements. On the other hand, the vortex shield and the base purge had little effect on the separative performance. Almost all of the experimental results exhibited strong electrostatic influence. At high flowrates, the separative performance of the cyclone decreased as the flowrate was reduced, as expected from cyclone theory. Although the improvements obtained with the developmental cyclone are significant, further improvements appear possible with the Air Shield cyclone and the Electrocyclone. Consequently, subsequent efforts under the CFCC program were focused on these concepts.

  12. Automotive Gas Turbine Power System-Performance Analysis Code

    NASA Technical Reports Server (NTRS)

    Juhasz, Albert J.

    1997-01-01

    An open cycle gas turbine numerical modelling code suitable for thermodynamic performance analysis (i.e. thermal efficiency, specific fuel consumption, cycle state points, working fluid flowrates etc.) of automotive and aircraft powerplant applications has been generated at the NASA Lewis Research Center's Power Technology Division. The use this code can be made available to automotive gas turbine preliminary design efforts, either in its present version, or, assuming that resources can be obtained to incorporate empirical models for component weight and packaging volume, in later version that includes the weight-volume estimator feature. The paper contains a brief discussion of the capabilities of the presently operational version of the code, including a listing of input and output parameters and actual sample output listings.

  13. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery: Mattoon Oil Field, Illinois. Fourth quarterly report, [October 1, 1993--December 31, 1993

    SciTech Connect

    Baroni, M.

    1994-01-25

    The objectives of this project are to continue reservoir characterization of the Cypress Sandstone; to identify and map fades-defined waterflood units (FDWS); and to design and Implement water-alternating-gas (WAG) oil recovery utilizing carbon dioxide (CO{sub 2}). The producibility problems are permeability variation and poor sweep efficiency. Phase 1 of the project focuses on the development of computer-generated geological and reservoir simulation models that will be used to select sites for the demonstration and implementation of CO{sub 2} displacement programs in Phase 2. Included in Phase 1 is the site selection and drilling of an infill well, coring of the Cypress interval, and injectivity testing to gather information used to update the reservoir simulation model. Phase 2 involves field implementation of WAG. Technology Transfer includes outreach activity such as seminars, workshops, and field trips. Technical progress for this quarter is described.

  14. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery: Mattoon Oil Field, Illinois. Third quarterly report, [July--September 1993

    SciTech Connect

    Baroni, M.R.

    1993-12-21

    The objectives of this project are to continue reservoir characterization of the Cypress Sandstone; to identify and map facies-defined waterflood units (FDWS); and to design and implement water-alternating-gas (WAG) oil recovery utilizing carbon dioxide (CO{sub 2}) The producibility problems are permeability variation and poor sweep efficiency. Part 1 of the project focuses on the development of computer-generated geological and reservoir simulation models that will be used to select sites for the demonstration and implementation of CO{sub 2} displacement programs in Part 2. Included in Part 1 is the site selection and drilling of an infill well, coring of the Cypress interval, and injectivity testing to gather information used to update the reservoir simulation model. Part 2 involves field implementation of WAG. Technology Transfer includes outreach activity such as seminars, workshops, and field trips.

  15. Applications of advanced petroleum production technology and water alternating gas injection for enhanced oil recovery - Mattoon Oil Field, Illinois. Final report

    SciTech Connect

    Baroni, M.

    1995-09-01

    Phase I results of a C0{sub 2}-assisted oil recovery demonstration project in selected Cypress Sandstone reservoirs at Mattoon Field, Illinois are reported. The design and scope of this project included C0{sub 2} injectvity testing in the Pinnell and Sawyer units, well stimulaton treatments with C0{sub 2} in the Strong unit and infill well drilling, completion and oil production. The field activities were supported by extensive C0{sub 2}-oil-water coreflood experiments, CO{sub 2} oil-phase interaction experiments, and integrated geologic modeling and reservoir simulations. The progress of the project was made public through presentations at an industry meeting and a DOEs contractors` symposium, through quarterly reports and one-to-one consultations with interested operators. Phase II of this project was not implemented. It would have been a water-alternating-gas (WAG) project of longer duration.

  16. Means and method for the destruction of particles entrained in a gas stream

    DOEpatents

    Botts, Thomas E.; Powell, James R.

    1980-01-01

    An apparatus and method for the destruction of particles entrained in a gas stream are disclosed. Destruction in the context of the subject invention means the fragmentation and/or vaporization of particles above a certain size limit. The subject invention contemplates destroying such particles by exposing them to intense bursts of laser light, such light having a frequency approximately equal to or less than the mean size of such particles. This invention is particularly adopted to the protection of turbine blades in open cycle coal-fired turbine systems. Means for introducing various chemical species and activating them by exposure to laser light are also disclosed.

  17. Evaluation of residential and commercial solar/gas heating and cooling technologies, volume 2

    NASA Astrophysics Data System (ADS)

    Hirshberg, A. S.; Haas, S. A.; Jacobsen, A. S.

    1980-12-01

    The economics of the most cost-effective solar/gas hybrid systems against a range of advanced gas-fired space conditioning equipment, including both conventional gas furnaces and pulse combustion gas furnaces were analyzed. In addition, the economic comparison considered improvements in performance and cost reduction for both solar/gas systems and advanced gas-fired equipment.

  18. The LandCarbon Web Application: Advanced Geospatial Data Delivery and Visualization Tools for Communication about Ecosystem Carbon Sequestration and Greenhouse Gas Fluxes

    NASA Astrophysics Data System (ADS)

    Thomas, N.; Galey, B.; Zhu, Z.; Sleeter, B. M.; Lehmer, E.

    2015-12-01

    The LandCarbon web application (http://landcarbon.org) is a collaboration between the U.S. Geological Survey and U.C. Berkeley's Geospatial Innovation Facility (GIF). The LandCarbon project is a national assessment focused on improved understanding of carbon sequestration and greenhouse gas fluxes in and out of ecosystems related to land use, using scientific capabilities from USGS and other organizations. The national assessment is conducted at a regional scale, covers all 50 states, and incorporates data from remote sensing, land change studies, aquatic and wetland data, hydrological and biogeochemical modeling, and wildfire mapping to estimate baseline and future potential carbon storage and greenhouse gas fluxes. The LandCarbon web application is a geospatial portal that allows for a sophisticated data delivery system as well as a suite of engaging tools that showcase the LandCarbon data using interactive web based maps and charts. The web application was designed to be flexible and accessible to meet the needs of a variety of users. Casual users can explore the input data and results of the assessment for a particular area of interest in an intuitive and interactive map, without the need for specialized software. Users can view and interact with maps, charts, and statistics that summarize the baseline and future potential carbon storage and fluxes for U.S. Level 2 Ecoregions for 3 IPCC emissions scenarios. The application allows users to access the primary data sources and assessment results for viewing and download, and also to learn more about the assessment's objectives, methods, and uncertainties through published reports and documentation. The LandCarbon web application is built on free and open source libraries including Django and D3. The GIF has developed the Django-Spillway package, which facilitates interactive visualization and serialization of complex geospatial raster data. The underlying LandCarbon data is available through an open application

  19. Advanced ceramic component development for high temperature indirect gas-fired heating systems. Final report, February 1988-September 1991 and annual report, June 1990-September 1991

    SciTech Connect

    Kirk, R.S.

    1992-10-01

    The CVD silicon carbide process was developed to a point where it can reproducibly deposit material within, around and along the length of tubes, either individually or in multiples. Two methods for sealing the tubes were worked out: one procedure involved a modification of the CVD process, while the other used a sealant coating after the CVD of the silicon carbide. Twenty-three radiant burner tubes 3 inch diameter and 62-1/2 inch long for the Caterpillar field test were made one at a time. The permeabilities of the tubes met the requirements of the furnace at Caterpillar. After eighteen months of operation in the field test of Nextel(TM) 312 Siconex, three tubes failed through the degradation of silicon carbide and one was broken in handling. (A total of 17 tubes were tested.) Installing the Siconex(TM) Corebusters reduced the energy usage by 22 to 25%. A total of six full-sized (8 inch x 94 inch) radiant burner tubes incoorporating the high temperature fiber, Nextel(TM) 440, were coated with silicon carbide. One full-sized 440 tube was painted with a refractory coating and tested at Columbia Gas. Aside from the painted coating flaking off, the tube was able to take the worst that Columbia could give it. Two more full-sized tubes utilizing Nextel(TM) 440 were sealed in the CVD coating process and installed in the pusher forge at SIFCO.

  20. Gas and Gas Pains

    MedlinePlus

    ... your gas and bloating occur mainly after eating dairy products, it may be because your body isn' ... able to break down the sugar (lactose) in dairy foods. Other food intolerances, especially to gluten — a ...

  1. SECONDARY NATURAL GAS RECOVERY IN THE APPALACHIAN BASIN: APPLICATION OF ADVANCED TECHNOLOGIES IN A FIELD DEMONSTRATION SITE, HENDERSON DOME, WESTERN PENNSYLVANIA

    SciTech Connect

    BOB A. HARDAGE; ELOISE DOHERTY; STEPHEN E. LAUBACH; TUCKER F. HENTZ

    1998-08-14

    The principal objectives of this project were to test and evaluate technologies that would result in improved characterization of fractured natural-gas reservoirs in the Appalachian Basin. The Bureau of Economic Geology (Bureau) worked jointly with industry partner Atlas Resources, Inc. to design, execute, and evaluate several experimental tests toward this end. The experimental tests were of two types: (1) tests leading to a low-cost methodology whereby small-scale microfractures observed in matrix grains of sidewall cores can be used to deduce critical properties of large-scale fractures that control natural-gas production and (2) tests that verify methods whereby robust seismic shear (S) waves can be generated to detect and map fractured reservoir facies. The grain-scale microfracture approach to characterizing rock facies was developed in an ongoing Bureau research program that started before this Appalachian Basin study began. However, the method had not been tested in a wide variety of fracture systems, and the tectonic setting of rocks in the Appalachian Basin composed an ideal laboratory for perfecting the methodology. As a result of this Appalachian study, a low-cost commercial procedure now exists that will allow Appalachian operators to use scanning electron microscope (SEM) images of thin sections extracted from oriented sidewall cores to infer the spatial orientation, relative geologic timing, and population density of large-scale fracture systems in reservoir sandstones. These attributes are difficult to assess using conventional techniques. In the Henderson Dome area, large quartz-lined regional fractures having N20E strikes, and a subsidiary set of fractures having N70W strikes, are prevalent. An innovative method was also developed for obtaining the stratigraphic and geographic tops of sidewall cores. With currently deployed sidewall coring devices, no markings from which top orientation can be obtained are made on the sidewall core itself during

  2. Advanced sulfur control concepts in hot-gas desulfurization technology: Phase 1, Feasibility of the direct production of elemental sulfur during the regeneration of high temperature desulfurization sorbents

    SciTech Connect

    Lopez, A.; White, J.; Groves, F.R.; Harrison, D.P.

    1994-10-01

    This topical report de-scribes the results of Phase 1 research performed during the first six months of a three-year contract to study the feasibility of the direct production of elemental sulfur during the regeneration of high temperature desulfurization sorbents. Much effort has gone into the development of a high-temperature meal oxide sorbent process for removal of H{sub 2}S from the coal gas. A number of sorbents based upon metals such as zinc, iron, manganese and others have been studied. In order for high temperature desulfurization to be economical it is necessary that the sorbents be regenerated to permit multicycle operation. Current methods of sorbent regeneration involve oxidation of the metal sulfide to reform the metal oxide and free the sulfur as SO{sub 2}. An alternate regeneration process in which the sulfur is liberated in elemental form is preferable. The overall objective of the current research is to study simpler and economically superior processing of known sorbents capable of producing elemental sulfur during regeneration. This topical report summarizes the first steps of this effort. A literature search has been completed to identify possible regeneration concepts and to collect relevant thermodynamic, kinetic, and process data. Three concepts involving reaction with SO{sub 2}, partial oxidation using an O{sub 2} {minus} H{sub 2}O mixture, and steam regeneration have been identified. The first two concepts result in the direct production of elemental sulfur while H{sub 2}S is the product of steam regeneration. This concept is of potential interest, however, since existing Claus technology can be used to convert H{sub 2}S to elemental sulfur. Following the literature search, a thermodynamic analysis, based upon free-energy minimization was carried out to evaluate candidate sorbents for possible use with the three regeneration concepts.

  3. Production of Depleted UO2Kernels for the Advanced Gas-Cooled Reactor Program for Use in TRISO Coating Development

    SciTech Connect

    Collins, J.L.

    2004-12-02

    The main objective of the Depleted UO{sub 2} Kernels Production Task at Oak Ridge National Laboratory (ORNL) was to conduct two small-scale production campaigns to produce 2 kg of UO{sub 2} kernels with diameters of 500 {+-} 20 {micro}m and 3.5 kg of UO{sub 2} kernels with diameters of 350 {+-} 10 {micro}m for the U.S. Department of Energy Advanced Fuel Cycle Initiative Program. The final acceptance requirements for the UO{sub 2} kernels are provided in the first section of this report. The kernels were prepared for use by the ORNL Metals and Ceramics Division in a development study to perfect the triisotropic (TRISO) coating process. It was important that the kernels be strong and near theoretical density, with excellent sphericity, minimal surface roughness, and no cracking. This report gives a detailed description of the production efforts and results as well as an in-depth description of the internal gelation process and its chemistry. It describes the laboratory-scale gel-forming apparatus, optimum broth formulation and operating conditions, preparation of the acid-deficient uranyl nitrate stock solution, the system used to provide uniform broth droplet formation and control, and the process of calcining and sintering UO{sub 3} {center_dot} 2H{sub 2}O microspheres to form dense UO{sub 2} kernels. The report also describes improvements and best past practices for uranium kernel formation via the internal gelation process, which utilizes hexamethylenetetramine and urea. Improvements were made in broth formulation and broth droplet formation and control that made it possible in many of the runs in the campaign to produce the desired 350 {+-} 10-{micro}m-diameter kernels, and to obtain very high yields.

  4. Natural Gas Multi-Year Program Plan

    SciTech Connect

    1997-12-01

    This document comprises the Department of Energy (DOE) Natural Gas Multi-Year Program Plan, and is a follow-up to the `Natural Gas Strategic Plan and Program Crosscut Plans,` dated July 1995. DOE`s natural gas programs are aimed at simultaneously meeting our national energy needs, reducing oil imports, protecting our environment, and improving our economy. The Natural Gas Multi-Year Program Plan represents a Department-wide effort on expanded development and use of natural gas and defines Federal government and US industry roles in partnering to accomplish defined strategic goals. The four overarching goals of the Natural Gas Program are to: (1) foster development of advanced natural gas technologies, (2) encourage adoption of advanced natural gas technologies in new and existing markets, (3) support removal of policy impediments to natural gas use in new and existing markets, and (4) foster technologies and policies to maximize environmental benefits of natural gas use.

  5. Advanced Fuels Campaign FY 2010 Accomplishments Report

    SciTech Connect

    Lori Braase

    2010-12-01

    The Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) Accomplishment Report documents the high-level research and development results achieved in fiscal year 2010. The AFC program has been given responsibility to develop advanced fuel technologies for the Department of Energy (DOE) using a science-based approach focusing on developing a microstructural understanding of nuclear fuels and materials. The science-based approach combines theory, experiments, and multi-scale modeling and simulation aimed at a fundamental understanding of the fuel fabrication processes and fuel and clad performance under irradiation. The scope of the AFC includes evaluation and development of multiple fuel forms to support the three fuel cycle options described in the Sustainable Fuel Cycle Implementation Plan4: Once-Through Cycle, Modified-Open Cycle, and Continuous Recycle. The word “fuel” is used generically to include fuels, targets, and their associated cladding materials. This document includes a brief overview of the management and integration activities; but is primarily focused on the technical accomplishments for FY-10. Each technical section provides a high level overview of the activity, results, technical points of contact, and applicable references.

  6. Advanced turbine systems program

    SciTech Connect

    Wilkes, C.; Mukavetz, D.W.; Knickerbocker, T.K.; Ali, S.A.

    1992-12-31

    In accordance with the goals of the DOE program, improvements in the gas turbine are the primary focus of Allison activity during Phase I. To this end Allison conducted a survey of potentially applicable gas turbine cycles and selected the advanced combined cycle as reference system. Extensive analysis of two versions of the advanced combined cycle was performed against the requirement for a 60% thermal efficiency (LHV) utility-sized, natural gas fired system. This analysis resulted in technology requirements for this system. Additional analysis determined emissions potential for the system, established a coal-fueled derivative system and a commercialization plan. This report deals with the technical requirements for a system that meets the thermal efficiency goal. Allison initially investigated four basic thermodynamic cycles: Humid air turbine, intercalate-recuperated systems, advanced combined cycle, chemically recuperated cycle. Our survey and cycle analysis indicated that au had the potential of reaching 60% thermal efficiency. We also concluded that engine hot section technology would be a critical technology regardless of which cycle was chosen. Based on this result Allison chose to concentrate on the advanced combined cycle. This cycle is well known and understood by the utility turbine user community and is therefore likely to be acceptable to users.

  7. Advanced turbine systems program

    SciTech Connect

    Wilkes, C.; Mukavetz, D.W.; Knickerbocker, T.K.; Ali, S.A.

    1992-01-01

    In accordance with the goals of the DOE program, improvements in the gas turbine are the primary focus of Allison activity during Phase I. To this end Allison conducted a survey of potentially applicable gas turbine cycles and selected the advanced combined cycle as reference system. Extensive analysis of two versions of the advanced combined cycle was performed against the requirement for a 60% thermal efficiency (LHV) utility-sized, natural gas fired system. This analysis resulted in technology requirements for this system. Additional analysis determined emissions potential for the system, established a coal-fueled derivative system and a commercialization plan. This report deals with the technical requirements for a system that meets the thermal efficiency goal. Allison initially investigated four basic thermodynamic cycles: Humid air turbine, intercalate-recuperated systems, advanced combined cycle, chemically recuperated cycle. Our survey and cycle analysis indicated that au had the potential of reaching 60% thermal efficiency. We also concluded that engine hot section technology would be a critical technology regardless of which cycle was chosen. Based on this result Allison chose to concentrate on the advanced combined cycle. This cycle is well known and understood by the utility turbine user community and is therefore likely to be acceptable to users.

  8. Advances in Strapdown Sensors

    DTIC Science & Technology

    1984-04-01

    axis laser gyro sensor assembly (1, 24) in a single Zerodur structure using interleaved laser paths to reduce net size/weight. If advances in mirror ...laser gyros, special design considerations - associated with mechanically dithered laaer gyros, the state-of-the-art in magnetic mirror and...from the lasing action of a helium-noon gas discharge within the optical cavity. The reflecting surfaces are die- lectric mirrors designed to

  9. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  10. Gas stream cleanup

    SciTech Connect

    Bossart, S.J.; Cicero, D.C.; Zeh, C.M.; Bedick, R.C.

    1990-08-01

    This report describes the current status and recent accomplishments of gas stream cleanup (GSCU) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Gas Stream Cleanup Program is to develop contaminant control strategies that meet environmental regulations and protect equipment in advanced coal conversion systems. Contaminant control systems are being developed for integration into seven advanced coal conversion processes: Pressurized fludized-bed combustion (PFBC), Direct coal-fueled turbine (DCFT), Intergrated gasification combined-cycle (IGCC), Gasification/molten carbonate fuel cell (MCFC), Gasification/solid oxide fuel cell (SOFC), Coal-fueled diesel (CFD), and Mild gasification (MG). These advanced coal conversion systems present a significant challenge for development of contaminant control systems because they generate multi-contaminant gas streams at high-pressures and high temperatures. Each of the seven advanced coal conversion systems incorporates distinct contaminant control strategies because each has different contaminant tolerance limits and operating conditions. 59 refs., 17 figs., 5 tabs.

  11. Advanced FT-IR Gas Analysis

    DTIC Science & Technology

    2005-12-01

    octene CH4 ppm o-xylene p-xylene†† 1-pentene CO % Propane Toluene†† 1-pentyne CO ppm SO3 Ethylene Glycol†† 2-hexene CO2 % Oxygen * Acrolein... Ethylene and Propylene are not shown because these gases are quantified using absorbance bands located around 1100 cm -1 , but do absorb within...region of (a) is expanded in (b). 28 Figure 18. Sample absorbance spectrum (blue) compared to ethylene glycol (red) positively identifying the

  12. Advanced Gas Turbine (AGT) technology report

    NASA Technical Reports Server (NTRS)

    1985-01-01

    Engine testing, ceramic component fabrication and evaluation, component performance rig testing, and producibility experiments at Pontiac comprised AGT 100 activities of this period, January to December 1984. Two experimental engines were available and allowed the evaluation of eight experimental assemblies. Operating time accumulated was 115 hr of burning and 156 hr total. Total cumulative engine operating time is now 225 hr. Build number 11 and 12 of engine S/N 1 totaled 28 burning hours and constituted a single assembly of the engine core--the compressor, both turbines, and the gearbox. Build number 11 of engine S/N 1 included a 1:07 hr continuous test at 100% gasifier speed (86,000 rpm). Build number 8 of engine S/N 2 was the first engine test with a ceramic turbine rotor. A mechanical loss test of an engine assembly revealed the actual losses to be near the original design allowance. Component development activity included rig testing of the compressor, combustor, and regenerator. Compressor testing was initiated on a rig modified to control the transfer of heat between flow path, lubricating oil, and structure. Results show successful thermal decoupling of the rig and lubricating/cooling oil. Rig evaluation of a reduced-friction compressor was initiated. Combustor testing covered qualification of ceramic parts for engine use, mapping of operating range limits, and evaluation of a relocated igniter plug. Several seal refinements were tested on the hot regenerator rig. An alternate regenerator disk, extruded MAS, was examined and found to be currently inadequate for the AGT 100 application. Also, a new technique for measuring leakage was explored on the regenerator rig. Ceramic component activity has focused on the development of state-of-the-art material strength characteristics in full-scale hardware. Injection-molded sintered alpha-SiC rotors were produced at Carborundum in an extensive process and tool optimization study.

  13. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Not Available

    1992-04-24

    No combustion tests for this program were conducted during this reporting period of January 1 to March 31, 1992. DOE-sponsored slogging combustor tests have been suspended since December 1991 in order to perform combustion tests on Northern States Power Company (NSP) coals. The NSP coal tests were conducted to evaluate combustor performance when burning western sub bituminous coals. The results of these tests will guide commercialization efforts, which are being promoted by NSP, Westinghouse Electric, and Textron Defense Systems. The NSP testing has been completed and preparation of the final report for that effort is underway. Although the NSP testing program has been completed, the Westinghouse/DOE program will not be resumed immediately. The reason for this is that Textron Defense Systems (TDS) has embarked on an internally funded program requiring installation of a new liquid fuel combustor system at the Haverhill site. The facility modifications for this new system are significant and it is not possible to continue the Westinghouse/DOE testing while these modifications are being made. These facility modifications are being performed during the period February 15, 1992 through May 31, 1992. The Westinghouse/DOE program can be resumed upon completion of this work.

  14. Advanced Bristle Seals for Gas Turbine Engines

    DTIC Science & Technology

    1993-01-28

    test sequence I retained the .003 inch shim and added a positive seal between the shim stock and the housing using Room Temperature Vulcanizing (RTV...113.4 200 6 1.131 1.040 175.142 0.219 * STANDARD CUBIC FOOT PER MINUTE u FLOW(cfm) OF AIR 2 70F/14.7psil TABLE C-8. TESI SEQUENCE H DATA "H. STATIC

  15. Advanced Gas Turbine (AGT) Technology Project

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Engine testing, ceramic component fabrication and evaluation, component performance rig testing, and analytical studies comprised AGT 100 activities during the 1985 year. Ten experimental assemblies (builds) were evaluated using two engines. Accrued operating time was 120 hr of burning and 170 hr total, bringing cumulative total operating time to 395 hr, all devoid of major failures. Tests identified the generator seals as the primary working fluid leakage sources. Power transfer clutch operation was demonstrated. An alpha SiC gasifier rotor engine test resulted in blade tip failures. Recurring case vibration and shaft whip have limited gasifier shaft speeds to 84%. Ceramic components successfully engine tested now include the SiC scroll assembly, Si3N3 turbine rotor, combustor assembly, regenerator disk bulkhead, turbine vanes, piston rings, and couplings. A compressor shroud design change to reduce heat recirculation back to the inlet was executed. Ceramic components activity continues to focus on the development of state-of-the-art material strength characteristics in full-scale engine hardware. Fiber reinforced glass-ceramic composite turbine (inner) backplates were fabricated by Corning Glass Works. The BMAS/III material performed well in engine testing. Backplates of MAS material have not been engine tested.

  16. Evaluation of the ECAS open cycle MHD power plant design

    NASA Technical Reports Server (NTRS)

    Seikel, G. R.; Staiger, P. J.; Pian, C. C. P.

    1978-01-01

    The Energy Conversion Alternatives Study (ECAS) MHD/steam power plant is described. The NASA critical evaluation of the design is summarized. Performance of the MHD plant is compared to that of the other type ECAS plant designs on the basis of efficiency and the 30-year levelized cost of electricity. Techniques to improve the plant design and the potential performance of lower technology plants requiring shorter development time and lower development cost are then discussed.

  17. Advanced ramjet concepts program

    NASA Technical Reports Server (NTRS)

    Leingang, J. L.

    1992-01-01

    Uniquely advantageous features, on both the performance and weight sides of the ledger, can be achieved through synergistic design integration of airbreathing and rocket technologies in the development of advanced orbital space transport propulsion systems of the combined cycle type. In the context of well understood advanced airbreathing and liquid rocket propulsion principles and practices, this precept of synergism is advanced mainly through six rather specific examples. These range from the detailed component level to the overall vehicle system level as follows: using jet compression; achieving a high area ratio rocket nozzle; ameliorating gas generator cycle rocket system deficiencies; using the in-duct special rocket thrust chamber assembly as the principal scramjet fuel injection operation; using the unstowed, covered fan as a duct closure for effecting high area ratio rocket mode operation; and creating a unique airbreathing rocket system via the onboard, cryogenic hydrogen induced air liquefaction process.

  18. Advanced Hydrogen Turbine Development

    SciTech Connect

    Marra, John

    2015-09-30

    Under the sponsorship of the U.S. Department of Energy (DOE) National Energy Technology Laboratories, Siemens has completed the Advanced Hydrogen Turbine Development Program to develop an advanced gas turbine for incorporation into future coal-based Integrated Gasification Combined Cycle (IGCC) plants. All the scheduled DOE Milestones were completed and significant technical progress was made in the development of new technologies and concepts. Advanced computer simulations and modeling, as well as subscale, full scale laboratory, rig and engine testing were utilized to evaluate and select concepts for further development. Program Requirements of: A 3 to 5 percentage point improvement in overall plant combined cycle efficiency when compared to the reference baseline plant; 20 to 30 percent reduction in overall plant capital cost when compared to the reference baseline plant; and NOx emissions of 2 PPM out of the stack. were all met. The program was completed on schedule and within the allotted budget

  19. Therapeutic Antioxidant Medical Gas

    PubMed Central

    Nakao, Atsunori; Sugimoto, Ryujiro; Billiar, Timothy R; McCurry, Kenneth R

    2009-01-01

    Medical gases are pharmaceutical gaseous molecules which offer solutions to medical needs and include traditional gases, such as oxygen and nitrous oxide, as well as gases with recently discovered roles as biological messenger molecules, such as carbon monoxide, nitric oxide and hydrogen sulphide. Medical gas therapy is a relatively unexplored field of medicine; however, a recent increasing in the number of publications on medical gas therapies clearly indicate that there are significant opportunities for use of gases as therapeutic tools for a variety of disease conditions. In this article, we review the recent advances in research on medical gases with antioxidant properties and discuss their clinical applications and therapeutic properties. PMID:19177183

  20. Gas Chromatic Mass Spectrometer

    NASA Technical Reports Server (NTRS)

    Wey, Chowen

    1995-01-01

    Gas chromatograph/mass spectrometer (GC/MS) used to measure and identify combustion species present in trace concentration. Advanced extractive diagnostic method measures to parts per billion (PPB), as well as differentiates between different types of hydrocarbons. Applicable for petrochemical, waste incinerator, diesel transporation, and electric utility companies in accurately monitoring types of hydrocarbon emissions generated by fuel combustion, in order to meet stricter environmental requirements. Other potential applications include manufacturing processes requiring precise detection of toxic gaseous chemicals, biomedical applications requiring precise identification of accumulative gaseous species, and gas utility operations requiring high-sensitivity leak detection.

  1. Gas separating

    DOEpatents

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  2. Gas separating

    DOEpatents

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  3. Advanced Science.

    ERIC Educational Resources Information Center

    Coles, Mike; Nelms, Rick

    1996-01-01

    Describes a study that explores the depth and breadth of scientific facts, principles, and procedures which are required in the Advanced General National Vocational Qualifications (GNVQ) science through comparison with GCE Advanced level. The final report takes account of the updated 1996 version of GNVQ science. (DDR)

  4. ADVANCED TURBINE SYSTEMS PROGRAM

    SciTech Connect

    Gregory Gaul

    2004-04-21

    Natural gas combustion turbines are rapidly becoming the primary technology of choice for generating electricity. At least half of the new generating capacity added in the US over the next twenty years will be combustion turbine systems. The Department of Energy has cosponsored with Siemens Westinghouse, a program to maintain the technology lead in gas turbine systems. The very ambitious eight year program was designed to demonstrate a highly efficient and commercially acceptable power plant, with the ability to fire a wide range of fuels. The main goal of the Advanced Turbine Systems (ATS) Program was to develop ultra-high efficiency, environmentally superior and cost effective competitive gas turbine systems for base load application in utility, independent power producer and industrial markets. Performance targets were focused on natural gas as a fuel and included: System efficiency that exceeds 60% (lower heating value basis); Less than 10 ppmv NO{sub x} emissions without the use of post combustion controls; Busbar electricity that are less than 10% of state of the art systems; Reliability-Availability-Maintainability (RAM) equivalent to current systems; Water consumption minimized to levels consistent with cost and efficiency goals; and Commercial systems by the year 2000. In a parallel effort, the program was to focus on adapting the ATS engine to coal-derived or biomass fuels. In Phase 1 of the ATS Program, preliminary investigators on different gas turbine cycles demonstrated that net plant LHV based efficiency greater than 60% was achievable. In Phase 2 the more promising cycles were evaluated in greater detail and the closed-loop steam-cooled combined cycle was selected for development because it offered the best solution with least risk for achieving the ATS Program goals for plant efficiency, emissions, cost of electricity and RAM. Phase 2 also involved conceptual ATS engine and plant design and technology developments in aerodynamics, sealing

  5. The Cummins advanced turbocompound diesel engine evaluation

    NASA Technical Reports Server (NTRS)

    Hoehne, J. L.; Werner, J. R.

    1982-01-01

    An advanced turbocompound diesel engine program was initiated to improve the tank mileage of the turbocompound engine by 5% over the vehicle test engines. Engine improvements could be realized by increasing the available energy of the exhaust gas at the turbine inlet, incorporating gas turbine techniques into improving the turbomachinery efficiencies, and through refined engine system optimization. The individual and cumulative performance gains achieved with the advanced turbocompound engine improvements are presented.

  6. Role of natural gas in meeting an electric sector emissions reduction strategy and effects on greenhouse gas emissions

    EPA Science Inventory

    With advances in natural gas extraction technologies, there is an increase in availability of domestic natural gas, and natural gas is gaining a larger share of use as a fuel in electricity production. At the power plant, natural gas is a cleaner burning fuel than coal, but unce...

  7. Advanced Microsensors

    NASA Technical Reports Server (NTRS)

    1991-01-01

    This video looks at a spinoff application of the technology from advanced microsensors -- those that monitor and determine conditions of spacecraft like the Space Shuttle. The application featured is concerned with the monitoring of the health of premature babies.

  8. GAS BEARING

    DOEpatents

    Skarstrom, C.W.

    1960-09-01

    A gas lubricated bearing for a rotating shaft is described. The assembly comprises a stationary collar having an annular member resiliently supported thereon. The collar and annular member are provided with cooperating gas passages arranged for admission of pressurized gas which supports and lubricates a bearing block fixed to the rotatable shaft. The resilient means for the annular member support the latter against movement away from the bearing block when the assembly is in operation.

  9. Gas vesicles.

    PubMed Central

    Walsby, A E

    1994-01-01

    The gas vesicle is a hollow structure made of protein. It usually has the form of a cylindrical tube closed by conical end caps. Gas vesicles occur in five phyla of the Bacteria and two groups of the Archaea, but they are mostly restricted to planktonic microorganisms, in which they provide buoyancy. By regulating their relative gas vesicle content aquatic microbes are able to perform vertical migrations. In slowly growing organisms such movements are made more efficiently than by swimming with flagella. The gas vesicle is impermeable to liquid water, but it is highly permeable to gases and is normally filled with air. It is a rigid structure of low compressibility, but it collapses flat under a certain critical pressure and buoyancy is then lost. Gas vesicles in different organisms vary in width, from 45 to > 200 nm; in accordance with engineering principles the narrower ones are stronger (have higher critical pressures) than wide ones, but they contain less gas space per wall volume and are therefore less efficient at providing buoyancy. A survey of gas-vacuolate cyanobacteria reveals that there has been natural selection for gas vesicles of the maximum width permitted by the pressure encountered in the natural environment, which is mainly determined by cell turgor pressure and water depth. Gas vesicle width is genetically determined, perhaps through the amino acid sequence of one of the constituent proteins. Up to 14 genes have been implicated in gas vesicle production, but so far the products of only two have been shown to be present in the gas vesicle: GvpA makes the ribs that form the structure, and GvpC binds to the outside of the ribs and stiffens the structure against collapse. The evolution of the gas vesicle is discussed in relation to the homologies of these proteins. Images PMID:8177173

  10. Gas separating

    DOEpatents

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  11. Gas Chromatograph.

    DTIC Science & Technology

    Patents, * Gas chromotography , *Hydrocarbons, *Carbon monoxide, *Carbon dioxide, *Water, Field equipment, Portable equipment, Sensitivity, Halogenated hydrocarbons, Test methods, Gases, Liquids, Purity

  12. Gas magnetometer

    SciTech Connect

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2016-05-03

    Measurement of a precessional rate of a gas, such as an alkali gas, in a magnetic field is made by promoting a non-uniform precession of the gas in which substantially no net magnetic field affects the gas during a majority of the precession cycle. This allows sensitive gases that would be subject to spin-exchange collision de-phasing to be effectively used for extremely sensitive measurements in the presence of an environmental magnetic field such as the Earth's magnetic field.

  13. Gas separating

    DOEpatents

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  14. Ultrafast gas switching experiments

    SciTech Connect

    Frost, C.A.; Martin, T.H.; Patterson, P.E.; Rinehart, L.F.; Rohwein, G.J.; Roose, L.D.; Aurand, J.F.; Buttram, M.T.

    1993-08-01

    We describe recent experiments which studied the physics of ultrafast gas breakdown under the extreme overvoltages which occur when a high pressure gas switch is pulse charged to hundreds of kV in 1 ns or less. The highly overvolted peaking gaps produce powerful electromagnetic pulses with risetimes < 100 ps which can be used for ultrawideband radar systems, particle accelerators, laser drivers, bioelectromagnetic studies, electromagnetic effects testing, and for basic studies of gas breakdown physics. We have produced and accurately measured pulses with 50 to 100 ps risetimes to peak levels of 75 to 160 kV at pulse repetition frequencies (PRF) to 1 kHz. A unique gas switch was developed to hold off hundreds of kV with parasitic inductance less than 1 nH. An advanced diagnostic system using Fourier compensation was developed to measure single-shot risetimes below 35 ps. The complete apparatus is described and waveforms are presented. The measured data are compared with a theoretical model which predicts key features including dependence on gas species and technology to practical systems antennas and bounded wave developed a thyristor/pulse transformer based system using a highly overvolted cable switch. This pulser driving a Sandia-designed TEM cell, provides an ultra wideband impulse with < 200 ps risetime to the test object at a PRF > Khz at > 100 kV/m E field.

  15. Ultrafast gas switching experiments

    SciTech Connect

    Frost, C.A.; Martin, T.H.; Patterson, P.E.; Rinehart, L.F.; Rohwein, G.J.; Roose, L.D.; Aurand, J.F.; Buttram, M.T.

    1996-11-01

    We describe recent experiments which studied the physics of ultrafast gas breakdown under the extreme overvoltages which occur when a high pressure gas switch is pulse charged to hundreds of kV in 1 ns or less. The highly overvolted peaking gaps produce powerful electromagnetic pulses with risetimes < 100 ps which can be used for ultrawideband radar systems, particle accelerators, laser drivers, bioelectromagnetic studies, electromagnetic effects testing, and for basic studies of gas breakdown physics. We have produced and accurately measured pulses with 50 to 100 ps risetimes to peak levels of 75 to 160 kV at pulse repetition frequencies (PRF) to I kHz. A unique gas switch was developed to hold off hundreds of kV with parasitic inductance less than I nH. An advanced diagnostic system using Fourier compensation was developed to measure single-shot risetimes below 35 ps. The complete apparatus is described and wave forms are presented. The measured data are compared with a theoretical model which predicts key features including dependence on gas species and pressure. We have applied this technology to practical systems driving ultrawideband radiating antennas and bounded wave simulators. For example, we have developed a thyristor/pulse transformer based system using a highly overvolted cable switch. This pulser driving a Sandia- designed TEM cell, provides an ultra wideband impulse with < 200 ps risetime to the test object at a PRF > 1 kHz at > 100 kV/m E field.

  16. Ultrafast gas switching experiments

    NASA Astrophysics Data System (ADS)

    Frost, C. A.; Martin, T. H.; Patterson, P. E.; Rinehart, L. F.; Rohwein, G. J.; Roose, L. D.; Aurand, J. F.; Buttram, M. T.

    1993-06-01

    Recent experiments which studied the physics of ultrafast gas breakdown under the extreme overvoltages which occur when a high pressure gas switch is pulse charged to hundreds of kV in 1 ns or less are described. The highly overvolted peaking gaps produce powerful electromagnetic pulses with risetimes less than 100 ps which can be used for ultrawideband radar systems, particle accelerators, laser drivers, bioelectromagnetic studies, electromagnetic effects testing, and for basic studies of gas breakdown physics. Pulses with 50 to 100 ps risetimes to peak levels of 75 to 160 kV at pulse repetition frequencies (PRF) to 1 kHz were produced and accurately measured. A unique gas switch was developed to hold off hundreds of kV with parasitic inductance less than 1 nH. An advanced diagnostic system using Fourier compensation was developed to measure single-shot risetimes below 35 ps. The complete apparatus is described and waveforms are presented. The measured data are compared with a theoretical model which predicts key features including dependence on gas species and pressure. This technology was applied to practical systems driving ultrawideband radiating antennas and bounded wave simulators. A thyristor/pulse transformer based system using a highly overvolted cable switch was developed. This pulser driving a Sandia-designed TEM cell, provides an ultra wideband impulse with less than 200 ps risetime to the test object at a PRF greater than 1 kHz at grater tha n 100 kV/m E field.

  17. F-1 Engine Gas Generator Testing

    NASA Video Gallery

    The gas generator from an F-1 engine is test-fired at the Marshall Space Flight Center in Huntsville, Ala., on Jan. 24, 2013. Data from the 30 second test will be used in the development of advance...

  18. Progress in Evaluating Quantitative Optical Gas Imaging

    EPA Science Inventory

    Development of advanced fugitive emission detection and assessment technologies that facilitate cost effective leak and malfunction mitigation strategies is an ongoing goal shared by industry, regulators, and environmental groups. Optical gas imaging (OGI) represents an importan...

  19. Spacecraft cryogenic gas storage systems

    NASA Technical Reports Server (NTRS)

    Rysavy, G.

    1971-01-01

    Cryogenic gas storage systems were developed for the liquid storage of oxygen, hydrogen, nitrogen, and helium. Cryogenic storage is attractive because of the high liquid density and low storage pressure of cryogens. This situation results in smaller container sizes, reduced container-strength levels, and lower tankage weights. The Gemini and Apollo spacecraft used cryogenic gas storage systems as standard spacecraft equipment. In addition to the Gemini and Apollo cryogenic gas storage systems, other systems were developed and tested in the course of advancing the state of the art. All of the cryogenic storage systems used, developed, and tested to date for manned-spacecraft applications are described.

  20. Gas Chromatography.

    ERIC Educational Resources Information Center

    Karasek, Francis W.; And Others

    1984-01-01

    This review covers fundamental developments in gas chromatography during 1982 and 1983. Literature is considered under these headings: columns; liguid phases; solid supports; sorption processes and solvents; open tubular column gas chromatography; instrumentation; high-resolution columns and applications; other techniques; qualitative and…