Efficient mass transport by optical advection
NASA Astrophysics Data System (ADS)
Kajorndejnukul, Veerachart; Sukhov, Sergey; Dogariu, Aristide
2015-10-01
Advection is critical for efficient mass transport. For instance, bare diffusion cannot explain the spatial and temporal scales of some of the cellular processes. The regulation of intracellular functions is strongly influenced by the transport of mass at low Reynolds numbers where viscous drag dominates inertia. Mimicking the efficacy and specificity of the cellular machinery has been a long time pursuit and, due to inherent flexibility, optical manipulation is of particular interest. However, optical forces are relatively small and cannot significantly modify diffusion properties. Here we show that the effectiveness of microparticle transport can be dramatically enhanced by recycling the optical energy through an effective optical advection process. We demonstrate theoretically and experimentally that this new advection mechanism permits an efficient control of collective and directional mass transport in colloidal systems. The cooperative long-range interaction between large numbers of particles can be optically manipulated to create complex flow patterns, enabling efficient and tunable transport in microfluidic lab-on-chip platforms.
Efficient mass transport by optical advection
Kajorndejnukul, Veerachart; Sukhov, Sergey; Dogariu, Aristide
2015-01-01
Advection is critical for efficient mass transport. For instance, bare diffusion cannot explain the spatial and temporal scales of some of the cellular processes. The regulation of intracellular functions is strongly influenced by the transport of mass at low Reynolds numbers where viscous drag dominates inertia. Mimicking the efficacy and specificity of the cellular machinery has been a long time pursuit and, due to inherent flexibility, optical manipulation is of particular interest. However, optical forces are relatively small and cannot significantly modify diffusion properties. Here we show that the effectiveness of microparticle transport can be dramatically enhanced by recycling the optical energy through an effective optical advection process. We demonstrate theoretically and experimentally that this new advection mechanism permits an efficient control of collective and directional mass transport in colloidal systems. The cooperative long-range interaction between large numbers of particles can be optically manipulated to create complex flow patterns, enabling efficient and tunable transport in microfluidic lab-on-chip platforms. PMID:26440069
NASA Astrophysics Data System (ADS)
Gillibrand, P. A.; Herzfeld, M.
2016-05-01
We present a flux-form semi-Lagrangian (FFSL) advection scheme designed for offline scalar transport simulation with coastal ocean models using curvilinear horizontal coordinates. The scheme conserves mass, overcoming problems of mass conservation typically experienced with offline transport models, and permits long time steps (relative to the Courant number) to be used by the offline model. These attributes make the method attractive for offline simulation of tracers in biogeochemical or sediment transport models using archived flow fields from hydrodynamic models. We describe the FFSL scheme, and test it on two idealised domains and one real domain, the Great Barrier Reef in Australia. For comparison, we also include simulations using a traditional semi-Lagrangian advection scheme for the offline simulations. We compare tracer distributions predicted by the offline FFSL transport scheme with those predicted by the original hydrodynamic model, assess the conservation of mass in all cases and contrast the computational efficiency of the schemes. We find that the FFSL scheme produced very good agreement with the distributions of tracer predicted by the hydrodynamic model, and conserved mass with an error of a fraction of one percent. In terms of computational speed, the FFSL scheme was comparable with the semi-Lagrangian method and an order of magnitude faster than the full hydrodynamic model, even when the latter ran in parallel on multiple cores. The FFSL scheme presented here therefore offers a viable mass-conserving and computationally-efficient alternative to traditional semi-Lagrangian schemes for offline scalar transport simulation in coastal models.
NASA Astrophysics Data System (ADS)
Comolli, Alessandro; Moussey, Charlie; Dentz, Marco
2016-04-01
Transport processes in groundwater systems are strongly affected by the presence of heterogeneity. The heterogeneity leads to non-Fickian features, that manifest themselves in the heavy-tailed breakthrough curves, as well as in the non-linear growth of the mean squared displacement and in the non-Gaussian plumes of solute particles. The causes of non-Fickian transport can be the heterogeneity in the flow fields and the processes of mass exchange between mobile and immobile phases, such as sorption/desorption reactions and diffusive mass transfer. Here, we present a Continuous Time Random Walk (CTRW) model that describes the transport of solutes in d-dimensional systems by taking into account both heterogeneous advection and mobile-immobile mass transfer. In order to account for these processes in the CTRW, the heterogeneities are mapped onto a distribution of transition times, which can be decomposed into advective transition times and trapping times, the latter being treated as a compound Poisson process. While advective transition times are related to the Eulerian flow velocities and, thus, to the conductivity distribution, trapping times depend on the sorption/desorption time scale, in case of reactive problems, or on the distribution of diffusion times in the immobile zones. Since the trapping time scale is typically much larger than the advective time scale, we observe the existence of two temporal regimes. The pre-asymptotic regime is defined by a characteristic time scale at which the properties of transport are fully determined by the heterogeneity of the advective field. On the other hand, in the asymptotic regime both the heterogeneity and the mass exchange processes play a role in conditioning the behaviour of transport. We consider different scenarios to discuss the relative importance of the advective heterogeneity and the mass transfer for the occurrence of non-Fickian transport. For each case we calculate analytically the scalings of the breakthrough
Advection dispersion mass transport associated with a non-aqueous-phase liquid pool
NASA Astrophysics Data System (ADS)
Fyrillas, Marios M.
2000-06-01
The two-dimensional problem of advection dispersion associated with a non-aqueous-phase liquid (NAPL) pool is addressed using the boundary element method. The problem is appropriately posed with an inhomogeneous boundary condition taking into consideration the presence of the pool and the impermeable layer. We derive a Fredholm integral equation of the first kind for the concentration gradient along the pool location and compute the average mass transfer coefficient numerically using the boundary-element method. Numerical results are in agreement with asymptotic analytical solutions obtained for the cases of small and large Péclet number (Pex). The asymptotic solution for small Pex, which is obtained by applying a novel perturbation technique to the integral equation, is used to de-singularize the integral equation. Results predicted by this analysis are in good agreement with experimentally determined overall mass transfer coefficients.
High-resolution two dimensional advective transport
Smith, P.E.; Larock, B.E.
1989-01-01
The paper describes a two-dimensional high-resolution scheme for advective transport that is based on a Eulerian-Lagrangian method with a flux limiter. The scheme is applied to the problem of pure-advection of a rotated Gaussian hill and shown to preserve the monotonicity property of the governing conservation law.
Advective turbulent transport in the fluid plasma
NASA Astrophysics Data System (ADS)
Min, Byung-Hoon; An, Chan-Yong; Kim, Chang-Bae
2013-10-01
The Hasegawa-Wakatani model (HWM) has been employed in pedagogical analyses of the physics behind the behavior of the tokamak plasmas. In addition to the geometric simplicity HWM has an appealing feature of sustaining autonomous quasi-steady state, unstable modes providing the power that is being transported by the nonlinear interactions and is eventually dissipated by the collisional damping at small scales. Emergence of the zonal flow out of the turbulence is a main candidate to cause the transition from the low plasma confinement to the high mode. In the study of such LH transition with the HWM, the adiabaticity parameter has been shown to play an important role in forcing the zonal flow that results in the regulation of the drift-wave turbulence. Instead of concentrating on the physics of the feedback loop between the turbulence and the zonal flow the present study focuses on the presence of the advective transport of the energy. Numerical simulations of HWM are performed and the connections between the advective transport and the zonal flow will be presented. This work was supported by the Supercpmputing Center/Korea Institute of Science and Technology Information with supercomputing resources including technical support (KSC-2013-C1-009).
Coupling of active motion and advection shapes intracellular cargo transport.
Khuc Trong, Philipp; Guck, Jochen; Goldstein, Raymond E
2012-07-13
Intracellular cargo transport can arise from passive diffusion, active motor-driven transport along cytoskeletal filament networks, and passive advection by fluid flows entrained by such cargo-motor motion. Active and advective transport are thus intrinsically coupled as related, yet different representations of the same underlying network structure. A reaction-advection-diffusion system is used here to show that this coupling affects the transport and localization of a passive tracer in a confined geometry. For sufficiently low diffusion, cargo localization to a target zone is optimized either by low reaction kinetics and decoupling of bound and unbound states, or by a mostly disordered cytoskeletal network with only weak directional bias. These generic results may help to rationalize subtle features of cytoskeletal networks, for example as observed for microtubules in fly oocytes.
Advective transport in heterogeneous aquifers: Are proxy models predictive?
NASA Astrophysics Data System (ADS)
Fiori, A.; Zarlenga, A.; Gotovac, H.; Jankovic, I.; Volpi, E.; Cvetkovic, V.; Dagan, G.
2015-12-01
We examine the prediction capability of two approximate models (Multi-Rate Mass Transfer (MRMT) and Continuous Time Random Walk (CTRW)) of non-Fickian transport, by comparison with accurate 2-D and 3-D numerical simulations. Both nonlocal in time approaches circumvent the need to solve the flow and transport equations by using proxy models to advection, providing the breakthrough curves (BTC) at control planes at any x, depending on a vector of five unknown parameters. Although underlain by different mechanisms, the two models have an identical structure in the Laplace Transform domain and have the Markovian property of independent transitions. We show that also the numerical BTCs enjoy the Markovian property. Following the procedure recommended in the literature, along a practitioner perspective, we first calibrate the parameters values by a best fit with the numerical BTC at a control plane at x1, close to the injection plane, and subsequently use it for prediction at further control planes for a few values of σY2≤8. Due to a similar structure and Markovian property, the two methods perform equally well in matching the numerical BTC. The identified parameters are generally not unique, making their identification somewhat arbitrary. The inverse Gaussian model and the recently developed Multi-Indicator Model (MIM), which does not require any fitting as it relates the BTC to the permeability structure, are also discussed. The application of the proxy models for prediction requires carrying out transport field tests of large plumes for a long duration.
Garges, J.A.; Baehr, A.L.
1998-01-01
The relative importance of advection and dispersion for both solute and vapor transport can be determined from type curves or concentration, flux, or cumulative flux. The dimensionless form of the type curves provides a means to directly evaluate the importance of mass transport by advection relative to that of mass transport by diffusion and dispersion. Type curves based on an analytical solution to the advection-dispersion equation are plotted in terms of dimensionless time and Peclet number. Flux and cumulative flux type curves provide additional rationale for transport regime determination in addition to the traditional concentration type curves. The extension of type curves to include vapor transport with phase partitioning in the unsaturated zone is a new development. Type curves for negative Peclet numbers also are presented. A negative Peclet number characterizes a problem in which one direction of flow is toward the contamination source, and thereby diffusion and advection can act in opposite directions. Examples are the diffusion of solutes away from the downgradient edge of a pump-and-treat capture zone, the upward diffusion of vapors through the unsaturated zone with recharge, and the diffusion of solutes through a low hydraulic conductivity cutoff wall with an inward advective gradient.
Advective-diffusive mass transfer in fractured porous media with variable rock matrix block size.
Sharifi Haddad, Amin; Hassanzadeh, Hassan; Abedi, Jalal
2012-05-15
Traditional dual porosity models do not take into account the effect of matrix block size distribution on the mass transfer between matrix and fracture. In this study, we introduce the matrix block size distributions into an advective-diffusive solute transport model of a divergent radial system to evaluate the mass transfer shape factor, which is considered as a first-order exchange coefficient between the fracture and matrix. The results obtained lead to a better understanding of the advective-diffusive mass transport in fractured porous media by identifying two early and late time periods of mass transfer. Results show that fractured rock matrix block size distribution has a great impact on mass transfer during early time period. In addition, two dimensionless shape factors are obtained for the late time, which depend on the injection flow rate and the distance of the rock matrix from the injection point.
Advective and diffusive cosmic ray transport in galactic haloes
NASA Astrophysics Data System (ADS)
Heesen, Volker; Dettmar, Ralf-Jürgen; Krause, Marita; Beck, Rainer; Stein, Yelena
2016-05-01
We present 1D cosmic ray transport models, numerically solving equations of pure advection and diffusion for the electrons and calculating synchrotron emission spectra. We find that for exponential halo magnetic field distributions advection leads to approximately exponential radio continuum intensity profiles, whereas diffusion leads to profiles that can be better approximated by a Gaussian function. Accordingly, the vertical radio spectral profiles for advection are approximately linear, whereas for diffusion they are of `parabolic' shape. We compare our models with deep Australia Telescope Compact Array observations of two edge-on galaxies, NGC 7090 and 7462, at λλ 22 and 6 cm. Our result is that the cosmic ray transport in NGC 7090 is advection dominated with V=150^{+80}_{-30} km s^{-1}, and that the one in NGC 7462 is diffusion dominated with D=3.0± 1.0 × 10^{28}E_GeV^{0.5} cm^2 s^{-1}. NGC 7090 has both a thin and thick radio disc with respective magnetic field scale heights of hB1 = 0.8 ± 0.1 kpc and hB2 = 4.7 ± 1.0 kpc. NGC 7462 has only a thick radio disc with hB2 = 3.8 ± 1.0 kpc. In both galaxies, the magnetic field scale heights are significantly smaller than what estimates from energy equipartition would suggest. A non-negligible fraction of cosmic ray electrons can escape from NGC 7090, so that this galaxy is not an electron calorimeter.
Anomalous transport and chaotic advection in homogeneous porous media.
Lester, D R; Metcalfe, G; Trefry, M G
2014-12-01
The topological complexity inherent to all porous media imparts persistent chaotic advection under steady flow conditions, which, in concert with the no-slip boundary condition, generates anomalous transport. We explore the impact of this mechanism upon longitudinal dispersion via a model random porous network and develop a continuous-time random walk that predicts both preasymptotic and asymptotic transport. In the absence of diffusion, the ergodicity of chaotic fluid orbits acts to suppress longitudinal dispersion from ballistic to superdiffusive transport, with asymptotic variance scaling as σ(L)(2)(t)∼t(2)/(ln t)(3). These results demonstrate that anomalous transport is inherent to homogeneous porous media and has significant implications for macrodispersion.
Anomalous transport and chaotic advection in homogeneous porous media.
Lester, D R; Metcalfe, G; Trefry, M G
2014-12-01
The topological complexity inherent to all porous media imparts persistent chaotic advection under steady flow conditions, which, in concert with the no-slip boundary condition, generates anomalous transport. We explore the impact of this mechanism upon longitudinal dispersion via a model random porous network and develop a continuous-time random walk that predicts both preasymptotic and asymptotic transport. In the absence of diffusion, the ergodicity of chaotic fluid orbits acts to suppress longitudinal dispersion from ballistic to superdiffusive transport, with asymptotic variance scaling as σ(L)(2)(t)∼t(2)/(ln t)(3). These results demonstrate that anomalous transport is inherent to homogeneous porous media and has significant implications for macrodispersion. PMID:25615192
Technology Transfer Automated Retrieval System (TEKTRAN)
Mathematical models describing contaminant transport in heterogeneous porous media are often formulated as an advection-dispersion transport equation with distance-dependent transport coefficients. In this work, a general analytical solution is presented for the linear, one-dimensional advection-di...
Fractional Advective-Dispersive Equation as a Model of Solute Transport in Porous Media
Technology Transfer Automated Retrieval System (TEKTRAN)
Understanding and modeling transport of solutes in porous media is a critical issue in the environmental protection. The common model is the advective-dispersive equation (ADE) describing the superposition of the advective transport and the Brownian motion in water-filled pore space. Deviations from...
NASA Astrophysics Data System (ADS)
Ancey, Christophe; Bohorquez, Patricio; Heyman, Joris
2016-04-01
The advection-diffusion equation arises quite often in the context of sediment transport, e.g., for describing time and space variations in the particle activity (the solid volume of particles in motion per unit streambed area). Stochastic models can also be used to derive this equation, with the significant advantage that they provide information on the statistical properties of particle activity. Stochastic models are quite useful when sediment transport exhibits large fluctuations (typically at low transport rates), making the measurement of mean values difficult. We develop an approach based on birth-death Markov processes, which involves monitoring the evolution of the number of particles moving within an array of cells of finite length. While the topic has been explored in detail for diffusion-reaction systems, the treatment of advection has received little attention. We show that particle advection produces nonlocal effects, which are more or less significant depending on the cell size and particle velocity. Albeit nonlocal, these effects look like (local) diffusion and add to the intrinsic particle diffusion (dispersal due to velocity fluctuations), with the important consequence that local measurements depend on both the intrinsic properties of particle displacement and the dimensions of the measurement system.
Thermally driven advection for radioxenon transport from an underground nuclear explosion
NASA Astrophysics Data System (ADS)
Sun, Yunwei; Carrigan, Charles R.
2016-05-01
Barometric pumping is a ubiquitous process resulting in migration of gases in the subsurface that has been studied as the primary mechanism for noble gas transport from an underground nuclear explosion (UNE). However, at early times following a UNE, advection driven by explosion residual heat is relevant to noble gas transport. A rigorous measure is needed for demonstrating how, when, and where advection is important. In this paper three physical processes of uncertain magnitude (oscillatory advection, matrix diffusion, and thermally driven advection) are parameterized by using boundary conditions, system properties, and source term strength. Sobol' sensitivity analysis is conducted to evaluate the importance of all physical processes influencing the xenon signals. This study indicates that thermally driven advection plays a more important role in producing xenon signals than oscillatory advection and matrix diffusion at early times following a UNE, and xenon isotopic ratios are observed to have both time and spatial dependence.
Analytical solution for the advection-dispersion transport equation in layered media
Technology Transfer Automated Retrieval System (TEKTRAN)
The advection-dispersion transport equation with first-order decay was solved analytically for multi-layered media using the classic integral transform technique (CITT). The solution procedure used an associated non-self-adjoint advection-diffusion eigenvalue problem that had the same form and coef...
Theory of advection-driven long range biotic transport
Technology Transfer Automated Retrieval System (TEKTRAN)
We propose a simple mechanistic model to examine the effects of advective flow on the spread of fungal diseases spread by wind-blown spores. The model is defined by a set of two coupled non-linear partial differential equations for spore densities. One equation describes the long-distance advectiv...
An exact peak capturing and essentially oscillation-free (EPCOF) algorithm, consisting of advection-dispersion decoupling, backward method of characteristics, forward node tracking, and adaptive local grid refinement, is developed to solve transport equations. This algorithm repr...
Perko, Janez; Patel, Ravi A
2014-05-01
The paper presents an approach that extends the flexibility of the standard lattice Boltzmann single relaxation time scheme in terms of spatial variation of dissipative terms (e.g., diffusion coefficient) and stability for high Péclet mass transfer problems. Spatial variability of diffusion coefficient in SRT is typically accommodated through the variation of relaxation time during the collision step. This method is effective but cannot deal with large diffusion coefficient variations, which can span over several orders of magnitude in some natural systems. The approach explores an alternative way of dealing with large diffusion coefficient variations in advection-diffusion transport systems by introducing so-called diffusion velocity. The diffusion velocity is essentially an additional convective term that replaces variations in diffusion coefficients vis-à-vis a chosen reference diffusion coefficient which defines the simulation time step. Special attention is paid to the main idea behind the diffusion velocity formulation and its implementation into the lattice Boltzmann framework. Finally, the performance, stability, and accuracy of the diffusion velocity formulation are discussed via several advection-diffusion transport benchmark examples. These examples demonstrate improved stability and flexibility of the proposed scheme with marginal consequences on the numerical performance.
Lewis, F.M.; Voss, C.I.; Rubin, Jacob
1986-01-01
A model was developed that can simulate the effect of certain chemical and sorption reactions simultaneously among solutes involved in advective-dispersive transport through porous media. The model is based on a methodology that utilizes physical-chemical relationships in the development of the basic solute mass-balance equations; however, the form of these equations allows their solution to be obtained by methods that do not depend on the chemical processes. The chemical environment is governed by the condition of local chemical equilibrium, and may be defined either by the linear sorption of a single species and two soluble complexation reactions which also involve that species, or binary ion exchange and one complexation reaction involving a common ion. Partial differential equations that describe solute mass balance entirely in the liquid phase are developed for each tenad (a chemical entity whose total mass is independent of the reaction process) in terms of their total dissolved concentration. These equations are solved numerically in two dimensions through the modification of an existing groundwater flow/transport computer code. (Author 's abstract)
NASA Astrophysics Data System (ADS)
Beisman, J. J., III; Maxwell, R. M.; Navarre-Sitchler, A.; Steefel, C. I.
2014-12-01
Understanding the interactions between physical, geochemical, and biological processes in the shallow subsurface is prerequisite to the development of effective contamination remediation techniques, or the accurate quantification of nutrient fluxes and biogeochemical cycling. Here we present recent developments to the massively parallel reactive transport code ParCrunchFlow. This model, previously applicable only to steady-state, saturated subsurface flows, has been extended to transient, surface-subsurface systems. Proof-of-concept simulations detailing reactive transport processes in hillslope and floodplain settings will be presented. In order to reduce the numerical dispersion inherent in grid based advection schemes, which can lead to an over prediction of reaction rates, a weighted, essentially non-oscillatory (WENO) advection scheme has been implemented, providing formal fifth-order spatial and third-order temporal accuracy. We use a mass-conservative, positivity-preserving flux limiter while advecting solute concentrations to prevent non-physical solutions. The effects of advection schemes and their associated numerical dispersion on reaction rates are evaluated by comparing our scheme to a monotonic lower order scheme in a transverse mixing scenario. The work presented here allows a better understanding of nutrient cycling dynamics in watershed systems.
Analytical Advection-Dispersion Model for Transport and Plant Uptake of Solutes in the Root Zone
Technology Transfer Automated Retrieval System (TEKTRAN)
We develop an advective-dispersive solute transport equation that includes plant uptake of water and solute, and present an analytical solution. Assumptions underlying the transport model include linear solute sorption, first-order plant uptake, and a uniform soil water content. We examine the lat...
Two-Dimensional Advective Transport in Ground-Water Flow Parameter Estimation
Anderman, E.R.; Hill, M.C.; Poeter, E.P.
1996-01-01
Nonlinear regression is useful in ground-water flow parameter estimation, but problems of parameter insensitivity and correlation often exist given commonly available hydraulic-head and head-dependent flow (for example, stream and lake gain or loss) observations. To address this problem, advective-transport observations are added to the ground-water flow, parameter-estimation model MODFLOWP using particle-tracking methods. The resulting model is used to investigate the importance of advective-transport observations relative to head-dependent flow observations when either or both are used in conjunction with hydraulic-head observations in a simulation of the sewage-discharge plume at Otis Air Force Base, Cape Cod, Massachusetts, USA. The analysis procedure for evaluating the probable effect of new observations on the regression results consists of two steps: (1) parameter sensitivities and correlations calculated at initial parameter values are used to assess the model parameterization and expected relative contributions of different types of observations to the regression; and (2) optimal parameter values are estimated by nonlinear regression and evaluated. In the Cape Cod parameter-estimation model, advective-transport observations did not significantly increase the overall parameter sensitivity; however: (1) inclusion of advective-transport observations decreased parameter correlation enough for more unique parameter values to be estimated by the regression; (2) realistic uncertainties in advective-transport observations had a small effect on parameter estimates relative to the precision with which the parameters were estimated; and (3) the regression results and sensitivity analysis provided insight into the dynamics of the ground-water flow system, especially the importance of accurate boundary conditions. In this work, advective-transport observations improved the calibration of the model and the estimation of ground-water flow parameters, and use of
Warm-air advection, air mass transformation and fog causes rapid ice melt
NASA Astrophysics Data System (ADS)
Tjernström, Michael; Shupe, Matthew D.; Brooks, Ian M.; Persson, P. Ola G.; Prytherch, John; Salisbury, Dominic J.; Sedlar, Joseph; Achtert, Peggy; Brooks, Barbara J.; Johnston, Paul E.; Sotiropoulou, Georgia; Wolfe, Dan
2015-07-01
Direct observations during intense warm-air advection over the East Siberian Sea reveal a period of rapid sea-ice melt. A semistationary, high-pressure system north of the Bering Strait forced northward advection of warm, moist air from the continent. Air-mass transformation over melting sea ice formed a strong, surface-based temperature inversion in which dense fog formed. This induced a positive net longwave radiation at the surface while reducing net solar radiation only marginally; the inversion also resulted in downward turbulent heat flux. The sum of these processes enhanced the surface energy flux by an average of ~15 W m-2 for a week. Satellite images before and after the episode show sea-ice concentrations decreasing from > 90% to ~50% over a large area affected by the air-mass transformation. We argue that this rapid melt was triggered by the increased heat flux from the atmosphere due to the warm-air advection.
Scaling of geochemical reaction rates via advective solute transport.
Hunt, A G; Ghanbarian, B; Skinner, T E; Ewing, R P
2015-07-01
Transport in porous media is quite complex, and still yields occasional surprises. In geological porous media, the rate at which chemical reactions (e.g., weathering and dissolution) occur is found to diminish by orders of magnitude with increasing time or distance. The temporal rates of laboratory experiments and field observations differ, and extrapolating from laboratory experiments (in months) to field rates (in millions of years) can lead to order-of-magnitude errors. The reactions are transport-limited, but characterizing them using standard solute transport expressions can yield results in agreement with experiment only if spurious assumptions and parameters are introduced. We previously developed a theory of non-reactive solute transport based on applying critical path analysis to the cluster statistics of percolation. The fractal structure of the clusters can be used to generate solute distributions in both time and space. Solute velocities calculated from the temporal evolution of that distribution have the same time dependence as reaction-rate scaling in a wide range of field studies and laboratory experiments, covering some 10 decades in time. The present theory thus both explains a wide range of experiments, and also predicts changes in the scaling behavior in individual systems with increasing time and/or length scales. No other theory captures these variations in scaling by invoking a single physical mechanism. Because the successfully predicted chemical reactions include known results for silicate weathering rates, our theory provides a framework for understanding changes in the global carbon cycle, including its effects on extinctions, climate change, soil production, and denudation rates. It further provides a basis for understanding the fundamental time scales of hydrology and shallow geochemistry, as well as the basis of industrial agriculture. PMID:26232976
Technology Transfer Automated Retrieval System (TEKTRAN)
Analytical solutions of the advection-dispersion equation and related models are indispensable for predicting or analyzing contaminant transport processes in streams and rivers, as well as in other surface water bodies. Many useful analytical solutions originated in disciplines other than surface-w...
Removing volatile contaminants from the unsaturated zone by inducing advective air-phase transport
Baehr, A.L.; Hoag, G.E.; Marley, M.C.
1989-01-01
Organic liquids inadvertently spilled and then distributed in the unsaturated zone can pose a long-term threat to ground water. Many of these substances have significant volatility, and thereby establish a premise for contaminant removal from the unsaturated zone by inducing advective air-phase transport with wells screened in the unsaturated zone. In order to focus attention on the rates of mass transfer from liquid to vapour phases, sand columns were partially saturated with gasoline and vented under steady air-flow conditions. The ability of an equilibrium-based transport model to predict the hydrocarbon vapor flux from the columns implies an efficient rate of local phase transfer for reasonably high air-phase velocities. Thus the success of venting remediations will depend primarily on the ability to induce an air-flow field in a heterogeneous unsaturated zone that will intersect the distributed contaminant. To analyze this aspect of the technique, a mathematical model was developed to predict radially symmetric air flow induced by venting from a single well. This model allows for in-situ determinations of air-phase permeability, which is the fundamental design parameter, and for the analysis of the limitations of a single well design. A successful application of the technique at a site once contaminated by gasoline supports the optimism derived from the experimental and modeliing phases of this study, and illustrates the well construction and field methods used to document the volatile contaminant recovery. ?? 1989.
Seirin Lee, Sungrim; Shibata, Tatsuo
2015-10-01
Anterior-Posterior (AP) polarity formation of cell membrane proteins plays a crucial role in determining cell asymmetry, which depends not only on the several genetic process but also biochemical and biophysical interactions. The mechanism of AP formation of Caenorhabditis elegans embryo is characterized into the three processes: (i) membrane association and dissociation of posterior and anterior proteins, (ii) diffusion into the membrane and cytosol, and (iii) active cortical and cytoplasmic flows induced by the contraction of the acto-myosin cortex. We explored the mechanism of symmetry breaking and AP polarity formation using self-recruitment model of posterior proteins. We found that the AP polarity pattern is established over wide range in the total mass of polarity proteins and the diffusion ratio in the cytosol to the membrane. We also showed that the advective transport in both membrane and cytosol during the establishment phase affects optimal time interval of establishment and positioning of the posterior domain, and plays a role to increase the robustness in the AP polarity formation by reducing the number of posterior domains for the sensitivity of initial conditions. We also demonstrated that a proper ratio of the total mass to cell size robustly regulate the length scale of the posterior domain.
Technology Transfer Automated Retrieval System (TEKTRAN)
Analytical solutions of the advection-dispersion solute transport equation remain useful for a large number of applications in science and engineering. In this paper we extend the Duhamel theorem, originally established for diffusion type problems, to the case of advective-dispersive transport subj...
It is well known that the fate and transport of contaminants in the subsurface are controlled by complex processes including advection, dispersion-diffusion, and chemical reactions. However, the interplay between the physical transport processes and chemical reactions, and their...
NASA Astrophysics Data System (ADS)
Chauhan, R. P.; Kumar, Amit
The present work is aimed that out of diffusive and advective transport which is dominant process for indoor radon entry under normal room conditions. For this purpose the radon diffusion coefficient and permeability of concrete were measured by specially designed experimental set up. The radon diffusion coefficient of concrete was measured by continuous radon monitor. The measured value was (3.78 ± 0.39)×10-8 m2/s and found independent of the radon gas concentration in source chamber. The radon permeability of concrete varied between 1.85×10-17 to 1.36×10-15 m2 for the bulk pressure difference fewer than 20 Pa to 73.3 kPa. From the measured diffusion coefficient and absolute permeability, the radon flux from the concrete surface having concentrations gradient 12-40 kBq/m3 and typical floor thickness 0.1 m was calculated by the application of Fick and Darcy laws. Using the measured flux attributable to diffusive and advective transport, the indoor radon concentration for a typical Indian model room having dimension (5×6×7) m3 was calculated under average room ventilation (0.63 h-1). The results showed that the contribution of diffusive transport through intact concrete is dominant over the advective transport, as expected from the low values of concrete permeability.
McKone, Thomas E.
2009-03-01
with three major horizons, the saturated zone can be further divided into other zones based on hydraulic and geologic conditions. Wetland soils are a special and important class in which near-saturation conditions exist most of the time. When a contaminant is added to or formed in a soil column, there are several mechanisms by which it can be dispersed, transported out of the soil column to other parts of the environment, destroyed, or transformed into some other species. Thus, to evaluate or manage any contaminant introduced to the soil column, one must determine whether and how that substance will (1) remain or accumulate within the soil column, (2) be transported by dispersion or advection within the soil column, (3) be physically, chemically, or biologically transformed within the soil (i.e., by hydrolysis, oxidation, etc.), or (4) be transported out of the soil column to another part of the environment through a cross-media transfer (i.e., volatilization, runoff, ground water infiltration, etc.). These competing processes impact the fate of physical, chemical, or biological contaminants found in soils. In order to capture these mechanisms in mass transfer models, we must develop mass-transfer coefficients (MTCs) specific to soil layers. That is the goal of this chapter. The reader is referred to other chapters in this Handbook that address related transport processes, namely Chapter 13 on bioturbation, Chapter 15 on transport in near-surface geological formations, and Chapter 17 on soil resuspention. This chapter addresses the following issues: the nature of soil pollution, composition of soil, transport processes and transport parameters in soil, transformation processes in soil, mass-balance models, and MTCs in soils. We show that to address vertical heterogeneity in soils in is necessary to define a characteristic scaling depth and use this to establish process-based expressions for soil MTCs. The scaling depth in soil and the corresponding MTCs depend strongly
NASA Astrophysics Data System (ADS)
Klammler, Harald; Hatfield, Kirk; Mohamed, Mohamed M.; Perminova, Irina V.; Perlmutter, Mike
2014-07-01
The problem of permeable reactive barrier (PRB) capture and release behavior is investigated by means of an approximate analytical approach exploring the invariance of steady-state solutions of the advection-dispersion equation to conformal mapping. PRB configurations considered are doubly-symmetric funnel-and-gate as well as less frequent drain-and-gate systems. The effect of aquifer heterogeneity on contaminant plume spreading is hereby incorporated through an effective transverse macro-dispersion coefficient, which has to be known. Results are normalized and graphically represented in terms of a relative capture efficiency M of contaminant mass or groundwater passing a control plane (transect) at a sufficient distance up-stream of a PRB as to comply with underlying assumptions. Factors of safety FS are given as the ratios of required capture width under advective-dispersive and purely advective transport for achieving equal capture efficiency M. It is found that M also applies to the release behavior down-stream of a PRB, i.e., it describes the spreading and dilution of PRB treated groundwater possibly containing incompletely remediated contamination and/or remediation reaction products. Hypothetical examples are given to demonstrate results.
Technology Transfer Automated Retrieval System (TEKTRAN)
This paper presents a formal exact solution of the linear advection-diffusion transport equation with constant coefficients for both transient and steady-state regimes. A classical mathematical substitution transforms the original advection-diffusion equation into an exclusively diffusive equation. ...
Numerical advection algorithms and their role in atmospheric transport and chemistry models
NASA Technical Reports Server (NTRS)
Rood, Richard B.
1987-01-01
During the last 35 years, well over 100 algorithms for modeling advection processes have been described and tested. This review summarizes the development and improvements that have taken place. The nature of the errors caused by numerical approximation to the advection equation are highlighted. Then the particular devices that have been proposed to remedy these errors are discussed. The extensive literature comparing transport algorithms is reviewed. Although there is no clear cut 'best' algorithm, several conclusions can be made. Spectral and pseudospectral techniques consistently provide the highest degree of accuracy, but expense and difficulties assuring positive mixing ratios are serious drawbacks. Schemes which consider fluid slabs bounded by grid points (volume schemes), rather than the simple specification of constituent values at the grid points, provide accurate positive definite results.
NASA Astrophysics Data System (ADS)
Huhn, F.; von Kameke, A.; Pérez-Muñuzuri, V.; Olascoaga, M. J.; Beron-Vera, F. J.
2012-03-01
Based on ten years (1998-2007) of satellite ocean color data we analyze the spatiotemporal patterns in the seasonal Madagascar plankton bloom with respect to the advection of the recently discovered Southern Indian Ocean Countercurrent (SICC). In maps of Finite-time Lyapunov Exponents (FTLE) and Finite-Time Zonal Drift (FTZD) computed from altimetry derived velocities we observe a narrow zonal jet that starts at ˜25°S at the southern tip of Madagascar, an important upwelling region, and extends to the east further than the largest plankton blooms (˜2500 km). In bloom years, the jet coincides with large parts of the northern boundary of the plankton bloom, acting as a barrier to meridional transport. Our findings suggest that advection is an important and so far underestimated mechanism for the eastward propagation and the extent of the plankton bloom. This supports the hypothesis of a single nutrient source south of Madagascar.
Numerical advection algorithms and their role in atmospheric transport and chemistry models
NASA Astrophysics Data System (ADS)
Rood, Richard B.
1987-02-01
During the last 35 years, well over 100 algorithms for modeling advection processes have been described and tested. This review summarizes the development and improvements that have taken place. The nature of the errors caused by numerical approximation to the advection equation are highlighted. Then the particular devices that have been proposed to remedy these errors are discussed. The extensive literature comparing transport algorithms is reviewed. Although there is no clear cut 'best' algorithm, several conclusions can be made. Spectral and pseudospectral techniques consistently provide the highest degree of accuracy, but expense and difficulties assuring positive mixing ratios are serious drawbacks. Schemes which consider fluid slabs bounded by grid points (volume schemes), rather than the simple specification of constituent values at the grid points, provide accurate positive definite results.
Advective transport observations with MODPATH-OBS--documentation of the MODPATH observation process
Hanson, R.T.; Kauffman, L.K.; Hill, M.C.; Dickinson, J.E.; Mehl, S.W.
2013-01-01
The MODPATH-OBS computer program described in this report is designed to calculate simulated equivalents for observations related to advective groundwater transport that can be represented in a quantitative way by using simulated particle-tracking data. The simulated equivalents supported by MODPATH-OBS are (1) distance from a source location at a defined time, or proximity to an observed location; (2) time of travel from an initial location to defined locations, areas, or volumes of the simulated system; (3) concentrations used to simulate groundwater age; and (4) percentages of water derived from contributing source areas. Although particle tracking only simulates the advective component of conservative transport, effects of non-conservative processes such as retardation can be approximated through manipulation of the effective-porosity value used to calculate velocity based on the properties of selected conservative tracers. This program can also account for simple decay or production, but it cannot account for diffusion. Dispersion can be represented through direct simulation of subsurface heterogeneity and the use of many particles. MODPATH-OBS acts as a postprocessor to MODPATH, so that the sequence of model runs generally required is MODFLOW, MODPATH, and MODPATH-OBS. The version of MODFLOW and MODPATH that support the version of MODPATH-OBS presented in this report are MODFLOW-2005 or MODFLOW-LGR, and MODPATH-LGR. MODFLOW-LGR is derived from MODFLOW-2005, MODPATH 5, and MODPATH 6 and supports local grid refinement. MODPATH-LGR is derived from MODPATH 5. It supports the forward and backward tracking of particles through locally refined grids and provides the output needed for MODPATH_OBS. For a single grid and no observations, MODPATH-LGR results are equivalent to MODPATH 5. MODPATH-LGR and MODPATH-OBS simulations can use nearly all of the capabilities of MODFLOW-2005 and MODFLOW-LGR; for example, simulations may be steady-state, transient, or a combination
NASA Astrophysics Data System (ADS)
Ancey, C.; Bohorquez, P.; Heyman, J.
2015-12-01
The advection-diffusion equation is one of the most widespread equations in physics. It arises quite often in the context of sediment transport, e.g., for describing time and space variations in the particle activity (the solid volume of particles in motion per unit streambed area). Phenomenological laws are usually sufficient to derive this equation and interpret its terms. Stochastic models can also be used to derive it, with the significant advantage that they provide information on the statistical properties of particle activity. These models are quite useful when sediment transport exhibits large fluctuations (typically at low transport rates), making the measurement of mean values difficult. Among these stochastic models, the most common approach consists of random walk models. For instance, they have been used to model the random displacement of tracers in rivers. Here we explore an alternative approach, which involves monitoring the evolution of the number of particles moving within an array of cells of finite length. Birth-death Markov processes are well suited to this objective. While the topic has been explored in detail for diffusion-reaction systems, the treatment of advection has received no attention. We therefore look into the possibility of deriving the advection-diffusion equation (with a source term) within the framework of birth-death Markov processes. We show that in the continuum limit (when the cell size becomes vanishingly small), we can derive an advection-diffusion equation for particle activity. Yet while this derivation is formally valid in the continuum limit, it runs into difficulty in practical applications involving cells or meshes of finite length. Indeed, within our stochastic framework, particle advection produces nonlocal effects, which are more or less significant depending on the cell size and particle velocity. Albeit nonlocal, these effects look like (local) diffusion and add to the intrinsic particle diffusion (dispersal due
NASA Technical Reports Server (NTRS)
Leonard, B. P.
1988-01-01
A fresh approach is taken to the embarrassingly difficult problem of adequately modeling simple pure advection. An explicit conservative control-volume formation makes use of a universal limiter for transient interpolation modeling of the advective transport equations. This ULTIMATE conservative difference scheme is applied to unsteady, one-dimensional scalar pure advection at constant velocity, using three critical test profiles: an isolated sine-squared wave, a discontinuous step, and a semi-ellipse. The goal, of course, is to devise a single robust scheme which achieves sharp monotonic resolution of the step without corrupting the other profiles. The semi-ellipse is particularly challenging because of its combination of sudden and gradual changes in gradient. The ULTIMATE strategy can be applied to explicit conservation schemes of any order of accuracy. Second-order schemes are unsatisfactory, showing steepening and clipping typical of currently popular so-called high resolution shock-capturing of TVD schemes. The ULTIMATE third-order upwind scheme is highly satisfactory for most flows of practical importance. Higher order methods give predictably better step resolution, although even-order schemes generate a (monotonic) waviness in the difficult semi-ellipse simulation. Little is to be gained above ULTIMATE fifth-order upwinding which gives results close to the ultimate for which one might hope.
Advective transport and decomposition of chain-forming planktonic diatoms in permeable sediments
NASA Astrophysics Data System (ADS)
Ehrenhauss, Sandra; Huettel, Markus
2004-09-01
In laboratory chamber experiments we demonstrate that permeable sediments (>7×10 -12 m 2) exposed to boundary flows filter chain-forming coastal bloom diatoms ( Skeletonema costatum and Thalassiosira rotula) from the water column, causing rapid transfer of fresh organic particulate matter into sediment layers as deep as 5 cm within 72 h. The penetration depth of the diatoms depends on the permeability of the bed and the length of the chains. Long chains were not transported as deep into the sediment as short chains or single cells. The fast advective transfer of phytoplankton cells into sandy sediments may be an important process facilitating organic matter uptake and preventing resuspension of deposited organic material in high-energy coastal environments. High advective flushing rates in medium- and coarse-grained sandy sediments enhanced the mineralisation of the trapped diatoms (2300 to 3200 μmol C m -2 d -1), stimulated benthic oxygen consumption (2300 to 3000 μmol O 2 m -2 d -1), as well as nitrification (up to 20 μmol NO 3- m -2 d -1), relative to sediment where diffusion dominated the solute exchange. Advective solute exchange rates that increase with increasing permeability prevent the accumulation of Si(OH) 4 near the dissolving frustules and in the pore water, leading to an effective recycling of dissolved silica to the production process in the water column (95 to 101 μmol Si(OH) 4 m -2 d -1). This process may also enhance dissolution rates of the deposited opal in coarse-grained sands by maintaining higher degrees of undersaturation than in fine-grained sediments. Our results suggest that advective filtration of planktonic diatoms into permeable sediments increases mineralisation and recycling of Si(OH) 4 and organic matter in high energetic shelf areas.
Really TVD advection schemes for the depth-integrated transport equation
NASA Astrophysics Data System (ADS)
Mercier, Ch.; Delhez, E. J. M.
This paper explores the use of TVD advection schemes to solve the depth-integrated transport equation for tracers in finite volume marine models. Numerical experiments show that the blind application of the usual TVD schemes and associated flux limiters can lead to non-TVD solutions when applied in complex geometries. Spatial and/or temporal variations of the local bathymetry can indeed break the TVD property of the usual schemes. Really TVD schemes can be recovered by taking into account the local depth and its variations in the formulation of the flux limiters. Using this approach, a generalized superbee limiter is introduced and validated.
Analytical Solutions of a Fractional Diffusion-advection Equation for Solar Cosmic-Ray Transport
NASA Astrophysics Data System (ADS)
Litvinenko, Yuri E.; Effenberger, Frederic
2014-12-01
Motivated by recent applications of superdiffusive transport models to shock-accelerated particle distributions in the heliosphere, we analytically solve a one-dimensional fractional diffusion-advection equation for the particle density. We derive an exact Fourier transform solution, simplify it in a weak diffusion approximation, and compare the new solution with previously available analytical results and with a semi-numerical solution based on a Fourier series expansion. We apply the results to the problem of describing the transport of energetic particles, accelerated at a traveling heliospheric shock. Our analysis shows that significant errors may result from assuming an infinite initial distance between the shock and the observer. We argue that the shock travel time should be a parameter of a realistic superdiffusive transport model.
Analytical solutions of a fractional diffusion-advection equation for solar cosmic-ray transport
Litvinenko, Yuri E.; Effenberger, Frederic
2014-12-01
Motivated by recent applications of superdiffusive transport models to shock-accelerated particle distributions in the heliosphere, we analytically solve a one-dimensional fractional diffusion-advection equation for the particle density. We derive an exact Fourier transform solution, simplify it in a weak diffusion approximation, and compare the new solution with previously available analytical results and with a semi-numerical solution based on a Fourier series expansion. We apply the results to the problem of describing the transport of energetic particles, accelerated at a traveling heliospheric shock. Our analysis shows that significant errors may result from assuming an infinite initial distance between the shock and the observer. We argue that the shock travel time should be a parameter of a realistic superdiffusive transport model.
Modeling of advection-diffusion-reaction processes using transport dissipative particle dynamics
NASA Astrophysics Data System (ADS)
Li, Zhen; Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em
2015-11-01
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. In particular, the transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of Lagrangian particles. To validate the proposed tDPD model and the boundary conditions, three benchmark simulations of one-dimensional diffusion with different boundary conditions are performed, and the results show excellent agreement with the theoretical solutions. Also, two-dimensional simulations of ADR systems are performed and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, an application of tDPD to the spatio-temporal dynamics of blood coagulation involving twenty-five reacting species is performed to demonstrate the promising biological applications of the tDPD model. Supported by the DOE Center on Mathematics for Mesoscopic Modeling of Materials (CM4) and an INCITE grant.
Simulation of the advective methane transport and AOM in Shenhu area, the Northern South China Sea
NASA Astrophysics Data System (ADS)
Liu, L.; Wu, N.
2012-04-01
Anaerobic Oxidation of Methane (AOM) occurs in the transition zone between the presence of sulfate and methane. This reaction is an important process for methane and the global carbon cycle. Methane gas hydrates bearing sediments were recovered in Shenhu Area, the Northern South China Sea, and methane advective transport was detected in this area as well. A one dimension numerical simulation tool was implemented to study the AOM process combined with the advective methane transport in Shenhu Area according to the local drilling data and geochemical information. The modeled results suggest that local methane flux will be consumed in the sediment column via dissolution, sorption and AOM reaction. A portion of methane will enter water column and possibly atmosphere if the methane flux was one order of magnitude higher than current level. Furthermore, the calculated rates of AOM in Shenhu area range similar to that of gas hydrate mounds in Mexico Golf. However, AOM is ability to consume more methane than that in Golf of Mexico due to the lower permeable sediment associated with a deeper sulfate methane transition layer.
Lichtner, P.C.; Helgeson, H.C.
1986-06-20
A general formulation of multi-phase fluid flow coupled to chemical reactions was developed based on a continuum description of porous media. A preliminary version of the computer code MCCTM was constructed which implemented the general equations for a single phase fluid. The computer code MCCTM incorporates mass transport by advection-diffusion/dispersion in a one-dimensional porous medium coupled to reversible and irreversible, homogeneous and heterogeneous chemical reactions. These reactions include aqueous complexing, oxidation/reduction reactions, ion exchange, and hydrolysis reactions of stoichiometric minerals. The code MCCTM uses a fully implicit finite difference algorithm. The code was tested against analytical calculations. Applications of the code included investigation of the propagation of sharp chemical reaction fronts, metasomatic alteration of microcline at elevated temperatures and pressures, and ion-exchange in a porous column. Finally numerical calculations describing fluid flow in crystalline rock in the presence of a temperature gradient were compared with experimental results for quartzite.
NASA Technical Reports Server (NTRS)
Zhou, YE; Vahala, George
1993-01-01
The advection of a passive scalar by incompressible turbulence is considered using recursive renormalization group procedures in the differential sub grid shell thickness limit. It is shown explicitly that the higher order nonlinearities induced by the recursive renormalization group procedure preserve Galilean invariance. Differential equations, valid for the entire resolvable wave number k range, are determined for the eddy viscosity and eddy diffusivity coefficients, and it is shown that higher order nonlinearities do not contribute as k goes to 0, but have an essential role as k goes to k(sub c) the cutoff wave number separating the resolvable scales from the sub grid scales. The recursive renormalization transport coefficients and the associated eddy Prandtl number are in good agreement with the k-dependent transport coefficients derived from closure theories and experiments.
Exact PDF equations and closure approximations for advective-reactive transport
Venturi, D.; Tartakovsky, Daniel M.; Tartakovsky, Alexandre M.; Karniadakis, George E.
2013-06-01
Mathematical models of advection–reaction phenomena rely on advective flow velocity and (bio) chemical reaction rates that are notoriously random. By using functional integral methods, we derive exact evolution equations for the probability density function (PDF) of the state variables of the advection–reaction system in the presence of random transport velocity and random reaction rates with rather arbitrary distributions. These PDF equations are solved analytically for transport with deterministic flow velocity and a linear reaction rate represented mathematically by a heterog eneous and strongly-correlated random field. Our analytical solution is then used to investigate the accuracy and robustness of the recently proposed large-eddy diffusivity (LED) closure approximation [1]. We find that the solution to the LED-based PDF equation, which is exact for uncorrelated reaction rates, is accurate even in the presence of strong correlations and it provides an upper bound of predictive uncertainty.
Pavese, G; Lettino, A; Calvello, M; Esposito, F; Fiore, S
2016-04-01
Aerosol composition and properties variation under the advection of different air masses were investigated, as case studies, by contemporary measurements over the atmospheric column and at the ground in a semi-rural site in South Italy. The absence of local strong sources in this area allowed to characterize background aerosol and to compare particle mixing effects under various atmospheric circulation conditions. Aerosol optical depth (AOD) and Ǻngström parameters from radiometric measurements allowed the detection and identification of polluted, dust, and volcanic atmospheric conditions. AODs were the input for a suitable model to evaluate the columnar aerosol composition, according to six main atmospheric components (water-soluble, soot, sea salt accumulation, sea salt coarse, mineral dus,t and biological). Scanning electron microscope (SEM) analysis of particulate sampled with a 13-stage impactor at the ground showed not only fingerprints typical of the different air masses but also the effects of transport and aging on atmospheric particles, suggesting processes that changed their chemical and optical properties. Background columnar aerosol was characterized by 72% of water-soluble and soot, in agreement with ground-based findings that highlighted 60% of contribution from anthropogenic carbonate particles and soot. In general, a good agreement between ground-based and columnar results was observed. Under the advection of trans-boundary air masses, water-soluble and soot were always present in columnar aerosol, whereas, in variable percentages, sea salt and mineral particles characterized both dust and volcanic conditions. At the ground, sulfates characterized the amorphous matrix produced in finer stages by the evaporation of solutions of organic and inorganic aerosols. Sulfates were also one of the key players involved in heterogeneous chemical reactions, producing complex secondary aerosol, as such clay-sulfate internally mixed particle externally mixed
NASA Astrophysics Data System (ADS)
Ojha, Richa; Prakash, A.; Govindaraju, Rao S.
2014-08-01
Description of field-scale solute transport in unsaturated soils is essential for assessing the degree of contamination, estimating fluxes past a control plane and for designing remedial measures. The flow field is usually described by numerical solution of the Richards equation followed by numerical solution of the advection-dispersion equation to describe contaminant movement. These numerical solutions are highly complex, and do not provide the insights that are possible from simpler analytical representations. In this study, analytical solutions at the local scale are developed to describe purely advective vertical transport of a conservative solute along the principle characteristic of the flow field. Local-scale model development is simplified by using a sharp-front approximation for water movement. These local solutions are then upscaled to field-scale solute transport by adopting a lognormally distributed horizontal hydraulic conductivity field to represent the natural heterogeneity observed in field soils. Analytical expressions are developed for the mean behavior of solute transport at the field scale. Comparisons with experimental observations find that trends of field-scale solute behavior are reasonably reproduced by the model. The accuracy of the proposed solution improves with increasing spatial variability in the hydraulic conductivity as revealed by further comparisons with numerical results of the Richards equation-based field-scale solute movement. In some cases, the sharp-front approximation may lead to anomalous field-scale behavior depending on the role of pre and postponded conditions in the field, and this limitation is discussed. The proposed method shows promise for describing field-scale solute movement in loamy sand and sandy loam soils.
NASA Technical Reports Server (NTRS)
Waugh, Darryn W.; Plumb, R. Alan
1994-01-01
We present a trajectory technique, contour advection with surgery (CAS), for tracing the evolution of material contours in a specified (including observed) evolving flow. CAS uses the algorithms developed by Dritschel for contour dynamics/surgery to trace the evolution of specified contours. The contours are represented by a series of particles, which are advected by a specified, gridded, wind distribution. The resolution of the contours is preserved by continually adjusting the number of particles, and finescale features are produced that are not present in the input data (and cannot easily be generated using standard trajectory techniques). The reliability, and dependence on the spatial and temporal resolution of the wind field, of the CAS procedure is examined by comparisons with high-resolution numerical data (from contour dynamics calculations and from a general circulation model), and with routine stratospheric analyses. These comparisons show that the large-scale motions dominate the deformation field and that CAS can accurately reproduce small scales from low-resolution wind fields. The CAS technique therefore enables examination of atmospheric tracer transport at previously unattainable resolution.
Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems
NASA Astrophysics Data System (ADS)
Li, Zhen; Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em
2015-07-01
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers.
Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems.
Li, Zhen; Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em
2015-07-01
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers.
Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems
Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em
2015-01-01
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers. PMID:26156459
Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems.
Li, Zhen; Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em
2015-07-01
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers. PMID:26156459
A subordinated advection model for uniform bed load transport from local to regional scales
NASA Astrophysics Data System (ADS)
Zhang, Yong; Martin, Raleigh L.; Chen, Dong; Baeumer, Boris; Sun, Hongguang; Chen, Li
2014-12-01
Sediment tracers moving as bed load can exhibit anomalous dispersion behavior deviating from Fickian diffusion. The presence of heavy-tailed resting time distributions and thin-tailed step length distributions motivate adoption of fractional-derivative models (FDMs) to describe sediment dispersion, but these models require many parameters that are difficult to quantify. Here we propose a considerably simplified FDM for anomalous transport of uniformly sized grains along straight channels, the subordinated advection equation (SAE), which is based on the concept of time subordination. Unlike previous FDM models with time index γ between 0 and 1, our SAE model adopts a value of γ between 1 and 2. This γ describes random velocities deviating significantly from the mean velocity and models both long resting periods and relatively fast displacements. We show that the model quantifies the dynamics of four bed load transport experiments recorded in the literature. In addition to γ, SAE model parameters—velocity and capacity coefficient—are related to the mean and variance of particle velocities, respectively. Successful application of the SAE model also implies a universal probability density for the heavy-tailed waiting time distribution (with finite mean) and a relatively lighter tailed step length distribution for uniform bed load transport from local to regional scales.
Bioreactor Mass Transport Studies
NASA Technical Reports Server (NTRS)
Kleis, Stanley J.; Begley, Cynthia M.
1997-01-01
The objectives of the proposed research efforts were to develop both a simulation tool and a series of experiments to provide a quantitative assessment of mass transport in the NASA rotating wall perfused vessel (RWPV) bioreactor to be flown on EDU#2. This effort consisted of a literature review of bioreactor mass transport studies, the extension of an existing scalar transport computer simulation to include production and utilization of the scalar, and the evaluation of experimental techniques for determining mass transport in these vessels. Since mass transport at the cell surface is determined primarily by the relative motion of the cell assemblage and the surrounding fluid, a detailed assessment of the relative motion was conducted. Results of the simulations of the motion of spheres in the RWPV under microgravity conditions are compared with flight data from EDU#1 flown on STS-70. The mass transport across the cell membrane depends upon the environment, the cell type, and the biological state of the cell. Results from a literature review of cell requirements of several scalars are presented. As a first approximation, a model with a uniform spatial distribution of utilization or production was developed and results from these simulations are presented. There were two candidate processes considered for the experimental mass transport evaluations. The first was to measure the dissolution rate of solid or gel beads. The second was to measure the induced fluorescence of beads as a stimulant (for example hydrogen peroxide) is infused into the vessel. Either technique would use video taped images of the process for recording the quantitative results. Results of preliminary tests of these techniques are discussed.
Transport and Recruitment of Blue Crab Larvae:a Model with Advection and Mortality
NASA Astrophysics Data System (ADS)
Garvine, R. W.; Epifanio, C. E.; Epifanio, C. C.; Wong, K.-C.
1997-07-01
The present paper develops a mathematical model for the transport and recruitment of blue crab (Callinectes sapidus) larvae, and applies it to the inner continental shelf of the Middle Atlantic Bight near Delaware Bay, U.S.A. Blue crab larvae develop through seven or eight planktonic zoeal stages to a megalopa stage suitable for recruitment to adult populations of east coast estuaries. The larvae are concentrated near the surface, and the currents are primarily forced by alongshelf winds and river discharge through major estuaries. Model currents are prescribed based on a realistic synthesis of their observed relationship to wind and river discharge. Besides the resulting advection, particle diffusion and biological mortality are added to determine the fate of larvae released from their parent estuary. Groups of particles were released across the source region of the outflowing buoyancy-driven current in the model estuary mouth. Most larvae were swept alongshelf to the south with the buoyancy-driven coastal current, and thus were lost as recruits to the population of their parent estuary. However, some larvae released close to the seaward edge of the emerging coastal current were able to cross the coastal current front and move seaward into inner shelf water during upwelling-favorable (northward) wind events. Some of these, in turn, were suitably placed near the parent estuary mouth so that they could be advected landward as megalopae into the estuary during a subsequent downwelling-favorable (southward) wind event and thus join the adult population. The model results for megalopae returns were computed from consecutive daily release of 1000 particles, and were compared with 4 years of blue crab megalopa settlement data for Delaware Bay. The model results for 1989 and 1990 matched the observed data remarkably well, with both years showing dominance by a single return event of a few days duration. For 1991 and 1992, the observed results showed multiple return events
NASA Astrophysics Data System (ADS)
Fan, Niannian; Singh, Arvind; Guala, Michele; Foufoula-Georgiou, Efi; Wu, Baosheng
2016-04-01
Bed load transport is a highly stochastic, multiscale process, where particle advection and diffusion regimes are governed by the dynamics of each sediment grain during its motion and resting states. Having a quantitative understanding of the macroscale behavior emerging from the microscale interactions is important for proper model selection in the absence of individual grain-scale observations. Here we develop a semimechanistic sediment transport model based on individual particle dynamics, which incorporates the episodic movement (steps separated by rests) of sediment particles and study their macroscale behavior. By incorporating different types of probability distribution functions (PDFs) of particle resting times Tr, under the assumption of thin-tailed PDF of particle velocities, we study the emergent behavior of particle advection and diffusion regimes across a wide range of spatial and temporal scales. For exponential PDFs of resting times Tr, we observe normal advection and diffusion at long time scales. For a power-law PDF of resting times (i.e., f>(Tr>)˜Tr-ν), the tail thickness parameter ν is observed to affect the advection regimes (both sub and normal advective), and the diffusion regimes (both subdiffusive and superdiffusive). By comparing our semimechanistic model with two random walk models in the literature, we further suggest that in order to reproduce accurately the emerging diffusive regimes, the resting time model has to be coupled with a particle motion model able to produce finite particle velocities during steps, as the episodic model discussed here.
Automated transportable mass spectrometer
NASA Astrophysics Data System (ADS)
Echo, M. W.
1981-09-01
The need was identified for a mass spectrometer (MS) which can be conveniently transported among several facilities for rapid verification of the isotopic composition of special nuclear material. This requirement for a light weight, transportable MS for U and Pu mass analysis was met by deleting the gas chromograph (GC) portions of a Hewlett-Packard Model 5992 Quadrupole GCMS and substituting a vacuum lock sample entry system. A programmable power supply and vacuum gauge were added and circuitry modifications were made to enable use of the supplied software.
Technology Transfer Automated Retrieval System (TEKTRAN)
The classical model to describe solute transport in soil is based on the advective-dispersive equation where Fick’s law is used to explain dispersion. From the microscopic point of view this is equivalent to consider that the motion of the particles of solute may be simulated by the Brownian motion....
The predictability of advection-dominated flux-transport solar dynamo models
Sanchez, Sabrina; Fournier, Alexandre; Aubert, Julien
2014-01-20
Space weather is a matter of practical importance in our modern society. Predictions of forecoming solar cycles mean amplitude and duration are currently being made based on flux-transport numerical models of the solar dynamo. Interested in the forecast horizon of such studies, we quantify the predictability window of a representative, advection-dominated, flux-transport dynamo model by investigating its sensitivity to initial conditions and control parameters through a perturbation analysis. We measure the rate associated with the exponential growth of an initial perturbation of the model trajectory, which yields a characteristic timescale known as the e-folding time τ {sub e}. The e-folding time is shown to decrease with the strength of the α-effect, and to increase with the magnitude of the imposed meridional circulation. Comparing the e-folding time with the solar cycle periodicity, we obtain an average estimate for τ {sub e} equal to 2.76 solar cycle durations. From a practical point of view, the perturbations analyzed in this work can be interpreted as uncertainties affecting either the observations or the physical model itself. After reviewing these, we discuss their implications for solar cycle prediction.
Transport dissipative particle dynamics model for mesoscopic advection- diffusion-reaction problems
Zhen, Li; Yazdani, Alireza; Tartakovsky, Alexandre M.; Karniadakis, George E.
2015-07-07
We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic DPD framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between particles, and an analytical formula is proposed to relate the mesoscopic concentration friction to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers.
NASA Astrophysics Data System (ADS)
Maghrebi, M.; Jankovic, I.; Rabideau, A. J.; Allen-King, R. M.; Weissmann, G. S.
2011-12-01
Effects of three key transport mechanisms (advection, diffusion and sorption) on transport and contaminant tailing of chlorinated solvents have been investigated using a numerical model. Thousands of model simulations have been conducted for various combinations of transport parameters that govern three key mechanisms in order to quantify tailing and relative importance of each mechanism. Hydraulic conductivity model contains a single inclusion of constant conductivity K embedded in a homogeneous anisotropic background of conductivity Kh,Kv. The inclusion is shaped as an oblate ellipsoid and subject to uniform flow. The background represents "average" conductivity of a heterogeneous formation while inclusion is used to represent geologic units that are more or less conductive than the background. The ratio of long to short semi-axis of the inclusion (a/b) models the ratio of horizontal to vertical integral scales (Ih/Iv) of different geologic units, where integral scales can be obtained, for example, using indicator variograms. The flow solution for present problem is obtained analytically as a closed form solution with exact expressions for Darcy velocity valid both inside and outside the inclusion. Sorption is modeled as an equilibrium process governed by a linear isotherm. The effects on transport and tailing are accounted for using retardation factors. Sorption heterogeneity is created by allowing different values of retardation factor for the interior (Ri) and the exterior of the inclusion (Rb). Diffusive displacements have been added to retarded advective displacements using random walk method. Peclet number, defined as Pe=U Ih/D (U is the groundwater velocity, D is the molecular diffusion coefficient for chlorinated solvents), is used to quantify the diffusion process. Very large numbers of particles (hundreds of thousands) have been tracked using very small time steps (as small as a/10,000) to provide sufficient resolution to breakthrough curves and to
Parkhurst, D.L.
1995-01-01
PHREEQC is a computer program written in the C pwgranuning language that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC is based on an ion-association aqueous model and has capabilities for (1) speciation and saturation-index calculations, (2) reaction-path and advective-transport calculations involving specified irreversible reactions, mixing of solutions, mineral and gas equilibria surface-complex-ation reactions, and ion-exchange reactions, and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for composition differences between waters, within specified compositional uncertainties. PHREEQC is derived from the Fortran program PHREEQE, but it has been completely rewritten in C with the addition many new capabilities. New features include the capabilities to use redox couples to distribute redox elements among their valence states in speciation calculations; to model ion-exchange and surface-compiexation reactions; to model reactions with a fixed-pressure, multicomponent gas phase (that is, a gas bubble); to calculate the mass of water in the aqueous phase during reaction and transport calculations; to keep track of the moles of minerals present in the solid phases and determine antomaticaHy the thermodynamically stable phase assemblage; to simulate advective transport in combination with PHREEQC's reaction-modeling capability; and to make inverse modeling calculations that allow for uncertainties in the analytical data. The user interface is improved through the use of a simplified approach to redox reactions, which includes explicit mole-balance equations for hydrogen and oxygen; the use of a revised input that is modular and completely free format; and the use of mineral names and standard chemical symbolism rather than index numbers. The use of (2 eliminates nearly all limitations on army sizes, including numbers of elements, aqueous species, solutions, phases, and lengths of character
McGraw R.
2012-03-01
Moment methods are finding increasing usage for simulations of particle population balance in box models and in more complex flows including two-phase flows. These highly efficient methods have nevertheless had little impact to date for multi-moment representation of aerosols and clouds in atmospheric models. There are evidently two reasons for this: First, atmospheric models, especially if the goal is to simulate climate, tend to be extremely complex and take many man-years to develop. Thus there is considerable inertia to the implementation of novel approaches. Second, and more fundamental, the nonlinear transport algorithms designed to reduce numerical diffusion during advection of various species (tracers) from cell to cell, in the typically coarse grid arrays of these models, can and occasionally do fail to preserve correlations between the moments. Other correlated tracers such as isotopic abundances, composition of aerosol mixtures, hydrometeor phase, etc., are subject to this same fate. In the case of moments, this loss of correlation can and occasionally does give rise to unphysical moment sets. When this happens the simulation can come to a halt. Following a brief description and review of moment methods, the goal of this paper is to present two new approaches that both test moment sequences for validity and correct them when they fail. The new approaches work on individual grid cells without requiring stored information from previous time-steps or neighboring cells.
NASA Astrophysics Data System (ADS)
Guihéneuf, N.; Boisson, A.; Bour, O.; Le Borgne, T.; Marechal, J.; Nigon, B.; Wajiddudin, M.; Ahmed, S.
2013-12-01
The prediction of transport in weathered and fractured rocks is critical as it represents the primary control of contaminant transfer from the subsurface in many parts of the world. This is the case in Southern India, where the subsurface is composed mainly of weathered and fractured granite and where the overexploitation of the groundwater resource since the 70's has led to high water table depletion and strong groundwater quality deterioration. One key issue for modelling transport in such systems is to quantify the respective role of advective heterogeneities and matrix diffusion, which can both lead to strongly non Fickian transport properties. We investigate this question by analysing tracer test experiments performed under different flow configurations at a fractured granite experimental site located in Andhra Pradesh (India). We performed both convergent and push-pull tracer tests within the same fracture and at different scales. Three convergent tracer tests were performed with a solution of fluorescein for different pumping rate and for different distances between injection and pumping boreholes: 6, 30 and 41 meters. To evaluate diffusive process, we performed two long-duration push-pull tests (push time of 3 hours) with a solution of two conservative tracers of different diffusion coefficient (fluorescein and sodium chloride). We performed also six others push-pull tests with only fluorescein but for a variable push times of 14 min and 55 min with or without resting time of about 60 min. The late-time behaviour on the breakthrough curves (BTCs) obtained for all convergent tracer tests showed a power-law slope of -2. Two of them showed an inflexion in the BTCs suggesting the existence of two independent flow paths and thus a highly channelized flow. The long-duration push-pull tests showed similar late-time behaviour with a power-law slope of -2.2 for both tracers. The six others push-pull tests showed a variation of power-law exponent from -3 to -2
Mass-loss from advective accretion disc around rotating black holes
NASA Astrophysics Data System (ADS)
Aktar, Ramiz; Das, Santabrata; Nandi, Anuj
2015-11-01
We examine the properties of the outflowing matter from an advective accretion disc around a spinning black hole. During accretion, rotating matter experiences centrifugal pressure-supported shock transition that effectively produces a virtual barrier around the black hole in the form of post-shock corona (hereafter PSC). Due to shock compression, PSC becomes hot and dense that eventually deflects a part of the inflowing matter as bipolar outflows because of the presence of extra thermal gradient force. In our approach, we study the outflow properties in terms of the inflow parameters, namely specific energy (E) and specific angular momentum (λ) considering the realistic outflow geometry around the rotating black holes. We find that spin of the black hole (ak) plays an important role in deciding the outflow rate R_{dot{m}} (ratio of mass flux of outflow to inflow); in particular, R_{dot{m}} is directly correlated with ak for the same set of inflow parameters. It is found that a large range of the inflow parameters allows global accretion-ejection solutions, and the effective area of the parameter space (E, λ) with and without outflow decreases with black hole spin (ak). We compute the maximum outflow rate (R^{max}_{dot{m}}) as a function of black hole spin (ak) and observe that R^{max}_{dot{m}} weakly depends on ak that lies in the range ˜10-18 per cent of the inflow rate for the adiabatic index (γ) with 1.5 ≥ γ ≥ 4/3. We present the observational implication of our approach while studying the steady/persistent jet activities based on the accretion states of black holes. We discuss that our formalism seems to have the potential to explain the observed jet kinetic power for several Galactic black hole sources and active galactic nuclei.
Rigorous upper bounds for transport due to passive advection by inhomogeneous turbulence
Krommes, J.A.; Smith, R.A.
1987-05-01
A variational procedure, due originally to Howard and explored by Busse and others for self-consistent turbulence problems, is employed to determine rigorous upper bounds for the advection of a passive scalar through an inhomogeneous turbulent slab with arbitrary generalized Reynolds number R and Kubo number K. In the basic version of the method, the steady-state energy balance is used as a constraint; the resulting bound, though rigorous, is independent of K. A pedagogical reference model (one dimension, K = infinity) is described in detail; the bound compares favorably with the exact solution. The direct-interaction approximation is also worked out for this model; it is somewhat more accurate than the bound, but requires considerably more labor to solve. For the basic bound, a general formalism is presented for several dimensions, finite correlation length, and reasonably general boundary conditions. Part of the general method, in which a Green's function technique is employed, applies to self-consistent as well as to passive problems, and thereby generalizes previous results in the fluid literature. The formalism is extended for the first time to include time-dependent constraints, and a bound is deduced which explicitly depends on K and has the correct physical scalings in all regimes of R and K. Two applications from the theory of turbulent plasmas ae described: flux in velocity space, and test particle transport in stochastic magnetic fields. For the velocity space problem the simplest bound reproduces Dupree's original scaling for the strong turbulence diffusion coefficient. For the case of stochastic magnetic fields, the scaling of the bounds is described for the magnetic diffusion coefficient as well as for the particle diffusion coefficient in the so-called collisionless, fluid, and double-streaming regimes.
Shapiro, A.M.; Renken, R.A.; Harvey, R.W.; Zygnerski, M.R.; Metge, D.W.
2008-01-01
A tracer experiment, using a nonreactive tracer, was conducted as part of an investigation of the potential for chemical and pathogen migration to public supply wells that draw groundwater from the highly transmissive karst limestone of the Biscayne aquifer in southeastern Florida. The tracer was injected into the formation over approximately 1 h, and its recovery was monitored at a pumping well approximately 100 m from the injection well. The first detection of the tracer occurred after approximately 5 h, and the peak concentration occurred at about 8 h after the injection. The tracer was still detected in the production well more than 6 days after injection, and only 42% of the tracer mass was recovered. It is hypothesized that a combination of chemical diffusion and slow advection resulted in significant retention of the tracer in the formation, despite the high transmissivity of the karst limestone. The tail of the breakthrough curve exhibited a straight-line behavior with a slope of -2 on a log-log plot of concentration versus time. The -2 slope is hypothesized to be a function of slow advection, where the velocities of flow paths are hypothesized to range over several orders of magnitude. The flow paths having the slowest velocities result in a response similar to chemical diffusion. Chemical diffusion, due to chemical gradients, is still ongoing during the declining limb of the breakthrough curve, but this process is dwarfed by the magnitude of the mass flux by slow advection.
NASA Technical Reports Server (NTRS)
Shia, Run-Lie; Ha, Yuk Lung; Wen, Jun-Shan; Yung, Yuk L.
1990-01-01
Extensive testing of the advective scheme proposed by Prather (1986) has been carried out in support of the California Institute of Technology-Jet Propulsion Laboratory two-dimensional model of the middle atmosphere. The original scheme is generalized to include higher-order moments. In addition, it is shown how well the scheme works in the presence of chemistry as well as eddy diffusion. Six types of numerical experiments including simple clock motion and pure advection in two dimensions have been investigated in detail. By comparison with analytic solutions, it is shown that the new algorithm can faithfully preserve concentration profiles, has essentially no numerical diffusion, and is superior to a typical fourth-order finite difference scheme.
A study of turbulent transport of an advective nature in a fluid plasma
NASA Astrophysics Data System (ADS)
Min, Byunghoon; An, Chan-Yong; Kim, Chang-Bae
2014-08-01
The advective nature of the electrostatic turbulent flux of plasma energy in Fourier space is studied numerically in a nearly adiabatic state. Such a state is represented by the Hasegawa-Mima equation, which is driven by a noise that may model the destabilization due to the phase mismatch of the plasma density and the electric potential. The noise is assumed to be Gaussian and not to be invariant under reflection along a direction ŝ. The flux density induced by such noise is found to be anisotropic: While it is random along ŝ, it is not along the perpendicular direction ŝ ⊥, and the flux is not diffusive. The renormalized response may be approximated as advective, with the velocity being proportional to ( kρ s )2, in the Fourier space.
Shia, R L; Ha, Y L; Wen, J S; Yung, Y L
1990-05-20
Extensive testing of the advective scheme, proposed by Prather (1986), has been carried out in support of the California Institute of Technology-Jet Propulsion Laboratory two-dimensional model of the middle atmosphere. We generalize the original scheme to include higher-order moments. In addition, we show how well the scheme works in the presence of chemistry as well as eddy diffusion. Six types of numerical experiments including simple clock motion and pure advection in two dimensions have been investigated in detail. By comparison with analytic solutions it is shown that the new algorithm can faithfully preserve concentration profiles, has essentially no numerical diffusion, and is superior to a typical fourth-order finite difference scheme.
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Grimm, S.; Steen-Larsen, H. C.; Schneebeli, M.; Steinfeld, A.
2014-12-01
The metamorphism of snow under advective air flow, with and without temperature gradient, was never experimentally investigated. We developed a new sample holder where metamorphism under advective conditions can be observed and measured using time-lapse micro-tomography [1]. Long-term experiments were performed and direct pore-level simulation (DPLS) [2,3] was directly applied on the extracted 3D digital geometry of the snow to calculate the effective transport properties by solving the governing fluid flow equations. The results showed no effect of isothermal advection, compared to rates typical for isothermal metamorphism. Appling a temperature gradient, the results showed increased snow metamorphism compared to rates typical for temperature gradient metamorphism. However, for both cases a change in the isotopic composition in the air as well as in the snow sample could be observed. These measurements could be influential to better understand snow-air exchange processes relevant for atmospheric chemistry and isotopic composition. REFERENCES[1] Ebner P. P., Grimm S., Schneebeli M., and Steinfeld A.: An instrumented sample holder for time-lapse micro-tomography measurements of snow under advective airflow. Geoscientific Instrumentation, Methods and Data Systems 4(2014), 353-373. [2] Zermatten E., Haussener S., Schneebeli M., and Steinfeld A.: Tomography-based determination of permeability and Dupuit-Forchheimer coefficient of characteristic snow samples. Journal of Glaciology 57(2011), 811-816. [3] Zermatten E., Schneebeli M., Arakawa H., and Steinfeld A.: Tomography-based determination of porosity, specific area and permeability of snow and comparison with measurements. Cold Regions Science and Technology 97 (2014), 33-40. Fig. 1: 3-D surface rendering of a refrozen wet snow sample with fluid flow streamline.
Richon, Patrick; Perrier, Frédéric; Koirala, Bharat Prasad; Girault, Frédéric; Bhattarai, Mukunda; Sapkota, Soma Nath
2011-02-01
Temporal variation of radon-222 concentration was studied at the Syabru-Bensi hot springs, located on the Main Central Thrust zone in Central Nepal. This site is characterized by several carbon dioxide discharges having maximum fluxes larger than 10 kg m(-2) d(-1). Radon concentration was monitored with autonomous Barasol™ probes between January 2008 and November 2009 in two small natural cavities with high CO(2) concentration and at six locations in the soil: four points having a high flux, and two background reference points. At the reference points, dominated by radon diffusion, radon concentration was stable from January to May, with mean values of 22 ± 6.9 and 37 ± 5.5 kBq m(-3), but was affected by a large increase, of about a factor of 2 and 1.6, respectively, during the monsoon season from June to September. At the points dominated by CO(2) advection, by contrast, radon concentration showed higher mean values 39.0 ± 2.6 to 78 ± 1.4 kBq m(-3), remarkably stable throughout the year with small long-term variation, including a possible modulation of period around 6 months. A significant difference between the diffusion dominated reference points and the advection-dominated points also emerged when studying the diurnal S(1) and semi-diurnal S(2) periodic components. At the advection-dominated points, radon concentration did not exhibit S(1) or S(2) components. At the reference points, however, the S(2) component, associated with barometric tide, could be identified during the dry season, but only when the probe was installed at shallow depth. The S(1) component, associated with thermal and possibly barometric diurnal forcing, was systematically observed, especially during monsoon season. The remarkable short-term and long-term temporal stability of the radon concentration at the advection-dominated points, which suggests a strong pressure source at depth, may be an important asset to detect possible temporal variations associated with the
Novak, C.F.
1993-12-31
The Fracture-Matrix Transport (FMT) code couples saturated porous media advection and diffusion with mechanistic chemical models for speciation and interphase reactions. FMT is being developed to support actinide solubility and retardation studies for the Waste Isolation Pilot Plant (WIPP), USDOE facility for demonstrating safe disposal of transuranic waste. Hydrologic studies of water-bearing units above the WIPP indicate double-porosity transport behavior in some locations, with groundwater concentrations ranging which potable to highly concentrated. Previously, FMT simulated such systems in two-dimensions on the continuum from advection- to diffusion-dominated, with a user-specified velocity field that allows double-porosity transport. However, aqueous density was assumed constant, and reactive minerals were assumed to occupy negligible volume. Both of these assumptions can be considered poor for evaporite systems, where large changes in porosity and aqueous density can result from high mineral solubilities. Therefore, further development of FMT has relaxed these restrictions, allowing aqueous density to vary with phase composition, and allowing void volume to change as minerals dissolve and precipitate. This paper describes the additional mathematical complexity required to simulate such systems. The sensitivity of advection-dominated transport to these variables is explored through an extended example.
NASA Astrophysics Data System (ADS)
Lester, D. R.; Trefry, M. G.; Metcalfe, G.
2016-11-01
The macroscopic spreading and mixing of solute plumes in saturated porous media is ultimately controlled by processes operating at the pore scale. Whilst the conventional picture of pore-scale mechanical dispersion and molecular diffusion leading to persistent hydrodynamic dispersion is well accepted, this paradigm is inherently two-dimensional (2D) in nature and neglects important three-dimensional (3D) phenomena. We discuss how the kinematics of steady 3D flow at the pore scale generate chaotic advection-involving exponential stretching and folding of fluid elements-the mechanisms by which it arises and implications of microscopic chaos for macroscopic dispersion and mixing. Prohibited in steady 2D flow due to topological constraints, these phenomena are ubiquitous due to the topological complexity inherent to all 3D porous media. Consequently 3D porous media flows generate profoundly different fluid deformation and mixing processes to those of 2D flow. The interplay of chaotic advection and broad transit time distributions can be incorporated into a continuous-time random walk (CTRW) framework to predict macroscopic solute mixing and spreading. We show how these results may be generalised to real porous architectures via a CTRW model of fluid deformation, leading to stochastic models of macroscopic dispersion and mixing which both honour the pore-scale kinematics and are directly conditioned on the pore-scale architecture.
Monger, Gregg R.; Duncan, Candice Morrison; Brusseau, Mark L.
2015-01-01
A gas-phase tracer test (GTT) was conducted at a landfill in Tucson, AZ, to help elucidate the impact of landfill gas generation on the transport and fate of chlorinated aliphatic volatile organic contaminants (VOCs). Sulfur hexafluoride (SF6) was used as the non-reactive gas tracer. Gas samples were collected from a multiport monitoring well located 15.2 m from the injection well, and analyzed for SF6, CH4, CO2, and VOCs. The travel times determined for SF6 from the tracer test are approximately two to ten times smaller than estimated travel times that incorporate transport by only gas-phase diffusion. In addition, significant concentrations of CH4 and CO2 were measured, indicating production of landfill gas. Based on these results, it is hypothesized that the enhanced rates of transport observed for SF6 are caused by advective transport associated with landfill gas generation. The rates of transport varied vertically, which is attributed to multiple factors including spatial variability of water content, refuse mass, refuse permeability, and gas generation. PMID:26380532
NASA Astrophysics Data System (ADS)
Neuman, Shlomo P.
2016-07-01
Fiori et al. (2015) examine the predictive capabilities of (among others) two "proxy" non-Fickian transport models, MRMT (Multi-Rate Mass Transfer) and CTRW (Continuous-Time Random Walk). In particular, they compare proxy model predictions of mean breakthrough curves (BTCs) at a sequence of control planes with near-ergodic BTCs generated through two- and three-dimensional simulations of nonreactive, mean-uniform advective transport in single realizations of stationary, randomly heterogeneous porous media. The authors find fitted proxy model parameters to be nonunique and devoid of clear physical meaning. This notwithstanding, they conclude optimistically that "i. Fitting the proxy models to match the BTC at [one control plane] automatically ensures prediction at downstream control planes [and thus] ii. … the measured BTC can be used directly for prediction, with no need to use models underlain by fitting." I show that (a) the authors' findings follow directly from (and thus confirm) theoretical considerations discussed earlier by Neuman and Tartakovsky (2009), which (b) additionally demonstrate that proxy models will lack similar predictive capabilities under more realistic, non-Markovian flow and transport conditions that prevail under flow through nonstationary (e.g., multiscale) media in the presence of boundaries and/or nonuniformly distributed sources, and/or when flow/transport are conditioned on measurements.
Advective excess Ba transport as shown from sediment and trap geochemical signatures
Fagel, N.; Andre, L.; Dehairs, F.
1999-08-01
The authors report the results of a geochemical study of sediment and trap material. Major and trace elements (Zr, Ba, rare earth elements, and Th) were analyzed on bulk sedimentary material collected along the NE Atlantic margin. The aim is to test the widespread use of Ba-barite as a proxy for paleoproductivity in a continental margin area. This environment is of great interest because atmospheric-oceanic exchanges are important. In sediments, the geochemical signatures remain close to an upper crust reference, with flat shale-normalized rare earth elements patterns and constant elementary ratios. The calculated biogenic fraction of Ba or excess Ba (20--45%) remains lower than the excess Ba record in trap material (80--99%). The evolution of the geochemical signature along the margin reflects variable dilution of a detrital Post Archean Australian Shale-like component by a biogenic carbonaceous seawater-derived component. The trap material displays a wide range of variation in its trace element content (e.g., Ba {approximately}150--3,000 ppm, Zr {approximately}2--100 ppm), except for the abyssal site, which is characterized by constant signature. In the two other sites, all of the trace element contents increase with water depth and present pronounced seasonal changes at each sampled water depth. The amount of excess Ba also increases in the deepest traps, and its evolution throughout the year mimics the change of the other analyzed trace elements. In contrast, its relationships with particulate organic carbon are not obvious. In terms of fluxes, two periods of enhanced excess Ba fluxes are observed: (1) excess Ba flux increases with the detrital-like elements like Th especially during winter, and (2) excess Ba flux is enhanced without any change for the other trace elements during spring. To explain the first case, a supply through lateral advection is proposed. Such transient input of significant excess Ba flux will have a great impact on the yearly averaged
ERIC Educational Resources Information Center
Mervine, K. E.
This bibliography is part of a series of Environmental Resource Packets prepared under a grant from EXXON Education Foundation. The most authoritative and accessible references in the urban transportation field are reviewed. The authors, publisher, point of view, level, and summary are given for each reference. The references are categorized…
Zhou, Quanlin; Birkholzer, Jens T.; Javandel, Iraj; Jordan, Preston D.
2004-01-14
A calibrated groundwater flow model for a contaminated site can provide substantial information for assessing and improving hydraulic measures implemented for remediation. A three-dimensional transient groundwater flow model was developed for a contaminated mountainous site, at which interim corrective measures were initiated to limit further spreading of contaminants. This flow model accounts for complex geologic units that vary considerably in thickness, slope, and hydrogeologic properties, as well as large seasonal fluctuations of the groundwater table and flow rates. Other significant factors are local recharge from leaking underground storm drains and recharge from steep uphill areas. The zonation method was employed to account for the clustering of high and low hydraulic conductivities measured in a geologic unit. A composite model was used to represent the bulk effect of thin layers of relatively high hydraulic conductivity found within bedrock of otherwise low conductivity. The inverse simulator ITOUGH2 was used to calibrate the model for the distribution of rock properties. The model was initially calibrated using data collected between 1994 and 1996. To check the validity of the model, it was subsequently applied to predicting groundwater level fluctuation and groundwater flux between 1996 and 1998. Comparison of simulated and measured data demonstrated that the model is capable of predicting the complex flow reasonably well. Advective transport was approximated using pathways of particles originating from source areas of the plumes. The advective transport approximation was in good agreement with the trend of contaminant plumes observed over the years. The validated model was then refined to focus on a subsection of the large system. The refined model was subsequently used to assess the efficiency of hydraulic measures implemented for remediation.
Kim, Chang-Bae; Krommes, J.A.
1988-08-01
The work of Krommes and Smith on rigorous upper bounds for the turbulent transport of a passively advected scalar (/ital Ann. Phys./ 177:246 (1987)) is extended in two directions: (1) For their ''reference model,'' improved upper bounds are obtained by utilizing more sophisticated two-time constraints which include the effects of cross-correlations up to fourth order. Numerical solutions of the model stochastic differential equation are also obtained; they show that the new bounds compare quite favorably with the exact results, even at large Reynolds and Kubo numbers. (2) The theory is extended to take account of a finite spatial autocorrelation length L/sub c/. As a reasonably generic example, the problem of particle transport due to statistically specified stochastic magnetic fields in a collisionless turbulent plasma is revisited. A bound is obtained which reduces for small L/sub c/ to the quasilinear limit and for large L/sub c/ to the strong turbulence limit, and which provides a reasonable and rigorous interpolation for intermediate values of L/sub c/. 18 refs., 6 figs.
ADVECTIVE TRANSPORT OF INTERSTELLAR PLASMA INTO THE HELIOSPHERE ACROSS THE RECONNECTING HELIOPAUSE
Strumik, M.; Grzedzielski, S.; Czechowski, A.; Macek, W. M.; Ratkiewicz, R.
2014-02-10
We discuss results of magnetohydrodynamical model simulations of plasma dynamics in the proximity of the heliopause (HP). The model is shown to fit details of the magnetic field variations observed by the Voyager 1 spacecraft during the transition from the heliosphere to the local interstellar medium (LISM). We propose an interpretation of magnetic field structures observed by Voyager 1 in terms of fine-scale physical processes. Our simulations reveal an effective transport mechanism of relatively dense LISM plasma across the reconnecting HP into the heliosphere. The mechanism is associated with annihilation of magnetic sectors in the heliospheric plasma near the HP.
Mohanram, Arvind; Ray, Chittaranjan; Harvey, Ronald W; Metge, David W; Ryan, Joseph N; Chorover, Jon; Eberl, D D
2010-10-01
In order to gain more information about the fate of Cryptosporidium parvum oocysts in tropical volcanic soils, the transport and attachment behaviors of oocysts and oocyst-sized polystyrene microspheres were studied in the presence of two soils. These soils were chosen because of their differing chemical and physical properties, i.e., an organic-rich (43-46% by mass) volcanic ash-derived soil from the island of Hawaii, and a red, iron (22-29% by mass), aluminum (29-45% by mass), and clay-rich (68-76% by mass) volcanic soil from the island of Oahu. A third agricultural soil, an organic- (13% by mass) and quartz-rich (40% by mass) soil from Illinois, was included for reference. In 10-cm long flow-through columns, oocysts and microspheres advecting through the red volcanic soil were almost completely (98% and 99%) immobilized. The modest breakthrough resulted from preferential flow-path structure inadvertently created by soil-particle aggregation during the re-wetting process. Although a high (99%) removal of oocysts and microsphere within the volcanic ash soil occurred initially, further examination revealed that transport was merely retarded because of highly reversible interactions with grain surfaces. Judging from the slope of the substantive and protracted tail of the breakthrough curve for the 1.8-μm microspheres, almost all (>99%) predictably would be recovered within ∼4000 pore volumes. This suggests that once contaminated, the volcanic ash soil could serve as a reservoir for subsequent contamination of groundwater, at least for pathogens of similar size or smaller. Because of the highly reversible nature of organic colloid immobilization in this soil type, C. parvum could contaminate surface water should overland flow during heavy precipitation events pick up near-surface grains to which they are attached. Surprisingly, oocyst and microsphere attachment to the reference soil from Illinois appeared to be at least as sensitive to changes in pH as was
Mohanram, A.; Ray, C.; Harvey, R.W.; Metge, D.W.; Ryan, J.N.; Chorover, J.; Eberl, D.D.
2010-01-01
In order to gain more information about the fate of Cryptosporidium parvum oocysts in tropical volcanic soils, the transport and attachment behaviors of oocysts and oocyst-sized polystyrene microspheres were studied in the presence of two soils. These soils were chosen because of their differing chemical and physical properties, i.e., an organic-rich (43-46% by mass) volcanic ash-derived soil from the island of Hawaii, and a red, iron (22-29% by mass), aluminum (29-45% by mass), and clay-rich (68-76% by mass) volcanic soil from the island of Oahu. A third agricultural soil, an organic- (13% by mass) and quartz-rich (40% by mass) soil from Illinois, was included for reference. In 10-cm long flow-through columns, oocysts and microspheres advecting through the red volcanic soil were almost completely (98% and 99%) immobilized. The modest breakthrough resulted from preferential flow-path structure inadvertently created by soil-particle aggregation during the re-wetting process. Although a high (99%) removal of oocysts and microsphere within the volcanic ash soil occurred initially, further examination revealed that transport was merely retarded because of highly reversible interactions with grain surfaces. Judging from the slope of the substantive and protracted tail of the breakthrough curve for the 1.8-??m microspheres, almost all (>99%) predictably would be recovered within ~4000 pore volumes. This suggests that once contaminated, the volcanic ash soil could serve as a reservoir for subsequent contamination of groundwater, at least for pathogens of similar size or smaller. Because of the highly reversible nature of organic colloid immobilization in this soil type, C. parvum could contaminate surface water should overland flow during heavy precipitation events pick up near-surface grains to which they are attached. Surprisingly, oocyst and microsphere attachment to the reference soil from Illinois appeared to be at least as sensitive to changes in pH as was observed
Mohanram, Arvind; Ray, Chittaranjan; Harvey, Ronald W; Metge, David W; Ryan, Joseph N; Chorover, Jon; Eberl, D D
2010-10-01
In order to gain more information about the fate of Cryptosporidium parvum oocysts in tropical volcanic soils, the transport and attachment behaviors of oocysts and oocyst-sized polystyrene microspheres were studied in the presence of two soils. These soils were chosen because of their differing chemical and physical properties, i.e., an organic-rich (43-46% by mass) volcanic ash-derived soil from the island of Hawaii, and a red, iron (22-29% by mass), aluminum (29-45% by mass), and clay-rich (68-76% by mass) volcanic soil from the island of Oahu. A third agricultural soil, an organic- (13% by mass) and quartz-rich (40% by mass) soil from Illinois, was included for reference. In 10-cm long flow-through columns, oocysts and microspheres advecting through the red volcanic soil were almost completely (98% and 99%) immobilized. The modest breakthrough resulted from preferential flow-path structure inadvertently created by soil-particle aggregation during the re-wetting process. Although a high (99%) removal of oocysts and microsphere within the volcanic ash soil occurred initially, further examination revealed that transport was merely retarded because of highly reversible interactions with grain surfaces. Judging from the slope of the substantive and protracted tail of the breakthrough curve for the 1.8-μm microspheres, almost all (>99%) predictably would be recovered within ∼4000 pore volumes. This suggests that once contaminated, the volcanic ash soil could serve as a reservoir for subsequent contamination of groundwater, at least for pathogens of similar size or smaller. Because of the highly reversible nature of organic colloid immobilization in this soil type, C. parvum could contaminate surface water should overland flow during heavy precipitation events pick up near-surface grains to which they are attached. Surprisingly, oocyst and microsphere attachment to the reference soil from Illinois appeared to be at least as sensitive to changes in pH as was
McCaulou, D.R.
1993-10-01
Replicate column experiments were done to quantify the effects of temperature and bacterial motility on advective transport through repacked, but otherwise unaltered, natural aquifer sediment. The bacteria used in this study, A0500, was a flagellated, spore-forming rod isolated from the deep subsurface at DOE`s Savannah River Laboratory. Motility was controlled by turning on flagellar metabolism at 18{degrees}C but off at 40{degrees}C. Microspheres were used to independently quantify the effects of temperature on the sticking efficiency ({alpha}), estimated using a steady-state filtration model. The observed greater microsphere removal at the higher temperature agreed with the physical-chemical model, but bacteria removal at 18{degrees}C was only half that at 4{degrees}C. The sticking efficiency for non-motile A0500 (4{degrees}C) was over three times that of the motile A0500 (18{degrees}C), 0.073 versus 0.022 respectively. Analysis of complete breakthrough curves using a non-steady, kinetically limited, transport model to estimate the time scales of attachment and detachment suggested that motile A 0500 bacteria traveled twice as far as non-motile A 0500 bacteria before becoming attached. Once attached, non-motile colloids detached on the time scale of 9 to 17 days. The time scale for detachment of motile A0500 bacteria was shorter, 4 to 5 days. Results indicate that bacterial attachment was reversible and detachment was enhanced by bacterial motifity. The kinetic energy of bacterial motility changed the attachment-detachment kinetics in favor of the detached state. The chemical factors responsible for the enhanced transport are not known. However, motility may have caused weakly held bacteria to detach from the secondary minimum, and possibly from the primary minimum, as described by DLVO theory.
Thermodynamically coupled mass transport processes in a saturated clay
Carnahan, C.L.
1984-11-01
Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.
NASA Astrophysics Data System (ADS)
Sedlar, J.
2015-12-01
Atmospheric advection of heat and moisture from lower latitudes to the high-latitude Arctic is a critical component of Earth's energy cycle. Large-scale advective events have been shown to make up a significant portion of the moist static energy budget of the Arctic atmosphere, even though such events are typically infrequent. The transport of heat and moisture over surfaces covered by ice and snow results in dynamic changes to the boundary layer structure, stability and turbulence, as well as to diabatic processes such as cloud distribution, microphysics and subsequent radiative effects. Recent studies have identified advection into the Arctic as a key mechanism for modulating the melt and freeze of snow and sea ice, via modification to all-sky longwave radiation. This paper examines the radiative impact during summer of such Arctic advective events at the top of the atmosphere (TOA), considering also the important role they play for the surface energy budget. Using infrared sounder measurements from the AIRS satellite, the summer frequency of significantly stable and moist advective events from 2003-2014 are characterized; justification of AIRS profiles over the Arctic are made using radiosoundings during a 3-month transect (ACSE) across the Eastern Arctic basin. One such event was observed within the East Siberian Sea in August 2014 during ACSE, providing in situ verification on the robustness and capability of AIRS to monitor advective cases. Results will highlight the important surface warming aspect of stable, moist instrusions. However a paradox emerges as such events also result in a cooling at the TOA evident on monthly mean TOA radiation. Thus such events have a climatic importance over ice and snow covered surfaces across the Arctic. ERA-Interim reanalyses are examined to provide a longer term perspective on the frequency of such events as well as providing capability to estimate meridional fluxes of moist static energy.
Guimerà, Xavier; Dorado, Antonio David; Bonsfills, Anna; Gabriel, Gemma; Gabriel, David; Gamisans, Xavier
2016-10-01
Knowledge of mass transport mechanisms in biofilm-based technologies such as biofilters is essential to improve bioreactors performance by preventing mass transport limitation. External and internal mass transport in biofilms was characterized in heterotrophic biofilms grown on a flat plate bioreactor. Mass transport resistance through the liquid-biofilm interphase and diffusion within biofilms were quantified by in situ measurements using microsensors with a high spatial resolution (<50 μm). Experimental conditions were selected using a mathematical procedure based on the Fisher Information Matrix to increase the reliability of experimental data and minimize confidence intervals of estimated mass transport coefficients. The sensitivity of external and internal mass transport resistances to flow conditions within the range of typical fluid velocities over biofilms (Reynolds numbers between 0.5 and 7) was assessed. Estimated external mass transfer coefficients at different liquid phase flow velocities showed discrepancies with studies considering laminar conditions in the diffusive boundary layer near the liquid-biofilm interphase. The correlation of effective diffusivity with flow velocities showed that the heterogeneous structure of biofilms defines the transport mechanisms inside biofilms. Internal mass transport was driven by diffusion through cell clusters and aggregates at Re below 2.8. Conversely, mass transport was driven by advection within pores, voids and water channels at Re above 5.6. Between both flow velocities, mass transport occurred by a combination of advection and diffusion. Effective diffusivities estimated at different biofilm densities showed a linear increase of mass transport resistance due to a porosity decrease up to biofilm densities of 50 g VSS·L(-1). Mass transport was strongly limited at higher biofilm densities. Internal mass transport results were used to propose an empirical correlation to assess the effective diffusivity
Guimerà, Xavier; Dorado, Antonio David; Bonsfills, Anna; Gabriel, Gemma; Gabriel, David; Gamisans, Xavier
2016-10-01
Knowledge of mass transport mechanisms in biofilm-based technologies such as biofilters is essential to improve bioreactors performance by preventing mass transport limitation. External and internal mass transport in biofilms was characterized in heterotrophic biofilms grown on a flat plate bioreactor. Mass transport resistance through the liquid-biofilm interphase and diffusion within biofilms were quantified by in situ measurements using microsensors with a high spatial resolution (<50 μm). Experimental conditions were selected using a mathematical procedure based on the Fisher Information Matrix to increase the reliability of experimental data and minimize confidence intervals of estimated mass transport coefficients. The sensitivity of external and internal mass transport resistances to flow conditions within the range of typical fluid velocities over biofilms (Reynolds numbers between 0.5 and 7) was assessed. Estimated external mass transfer coefficients at different liquid phase flow velocities showed discrepancies with studies considering laminar conditions in the diffusive boundary layer near the liquid-biofilm interphase. The correlation of effective diffusivity with flow velocities showed that the heterogeneous structure of biofilms defines the transport mechanisms inside biofilms. Internal mass transport was driven by diffusion through cell clusters and aggregates at Re below 2.8. Conversely, mass transport was driven by advection within pores, voids and water channels at Re above 5.6. Between both flow velocities, mass transport occurred by a combination of advection and diffusion. Effective diffusivities estimated at different biofilm densities showed a linear increase of mass transport resistance due to a porosity decrease up to biofilm densities of 50 g VSS·L(-1). Mass transport was strongly limited at higher biofilm densities. Internal mass transport results were used to propose an empirical correlation to assess the effective diffusivity
Ackerman, D.J.
1995-01-01
Quantitative estimates of ground-water flow directions and traveltimes for advective flow were developed for the regional aquifer system of the eastern Snake River Plain, Idaho. The work included: (1) descriptions of compartments in the aquifer that function as intermediate and regional flow systems, (2) descriptions of pathlines for flow originating at or near the water table, and (3) quantitative estimates of traveltimes for advective transport originating at or near the water table. A particle-tracking postprocessing program was used to compute pathlines on the basis of output from an existing three-dimensional steady-state flow model. The flow model uses 1980 conditions to approximate average annual conditions for 1950-80. The advective transport model required additional information about the nature of flow across model boundaries, aquifer thickness, and porosity. Porosity of two types of basalt strata has been reported for more than 1,500 individual cores from test holes, wells, and outcrops near the south side of the Idaho National Engineering Laboratory. The central 80 percent of samples had porosities of 0.08 to 0.25, the central 50 percent of samples, O. 11 to 0.21. Calibration of the model involved choosing a value for porosity that yielded the best solution. Two radiologic contaminants, iodine-129 and tritium, both introduced to the flow system about 40 years ago, are relatively conservative tracers. Iodine- 129 was considered to be more useful because of a lower analytical detection limit, longer half-life, and longer flow path. The calibration value for porosity was 0.21. Most flow in the aquifer is contained within a regional-scale compartment and follows paths that discharge to the Snake River downstream from Milner Dam. Two intermediate-scale compartments exist along the southeast side of the aquifer and near Mud Lake.One intermediate-scale compartment along the southeast side of the aquifer discharges to the Snake River near American Fails
Mass transport in an anatomically realistic human right coronary artery.
Kaazempur-Mofrad, M R; Ethier, C R
2001-02-01
The coronary arteries are a common site of atherosclerotic plaque formation, which has been putatively linked to hemodynamic and mass transport patterns. The purpose of this paper was to study mass transport patterns in a human right coronary artery (RCA) model, focusing on the effects of local geometric features on mass transfer from blood to artery walls. Using a previously developed characteristic/finite element scheme for solving advection-dominated transport problems, mass transfer calculations were performed in a rigid, anatomically realistic model of a human RCA. A qualitative and quantitative examination of the RCA geometry was also carried out. The concentration field within the RCA was seen to closely follow primary and secondary flow features. Local variations in mass transfer patterns due to geometric features were significant and much larger in magnitude than local variations in wall shear stress. We conclude that the complex secondary flows in a realistic arterial model can produce very substantial local variations in blood-wall mass transfer rates, and may be important in atherogenesis. Further, RCA mass transfer patterns are more sensitive to local geometric features than are wall shear stress patterns. PMID:11284666
Alcaraz, Mar; García-Gil, Alejandro; Vázquez-Suñé, Enric; Velasco, Violeta
2016-02-01
Borehole Heat Exchangers (BHEs) are increasingly being used to exploit shallow geothermal energy. This paper presents a new methodology to provide a response to the need for a regional quantification of the geothermal potential that can be extracted by BHEs and the associated environmental impacts. A set of analytical solutions facilitates accurate calculation of the heat exchange of BHEs with the ground and its environmental impacts. For the first time, advection and dispersion heat transport mechanisms and the temporal evolution from the start of operation of the BHE are taken into account in the regional estimation of shallow geothermal resources. This methodology is integrated in a GIS environment, which facilitates the management of input and output data at a regional scale. An example of the methodology's application is presented for Barcelona, in Spain. As a result of the application, it is possible to show the strengths and improvements of this methodology in the development of potential maps of low temperature geothermal energy as well as maps of environmental impacts. The minimum and maximum energy potential values for the study site are 50 and 1800 W/m(2) for a drilled depth of 100 m, proportionally to Darcy velocity. Regarding to thermal impacts, the higher the groundwater velocity and the energy potential, the higher the size of the thermal plume after 6 months of exploitation, whose length ranges from 10 to 27 m long. A sensitivity analysis was carried out in the calculation of heat exchange rate and its impacts for different scenarios and for a wide range of Darcy velocities. The results of this analysis lead to the conclusion that the consideration of dispersion effects and temporal evolution of the exploitation prevent significant differences up to a factor 2.5 in the heat exchange rate accuracy and up to several orders of magnitude in the impacts generated.
Alcaraz, Mar; García-Gil, Alejandro; Vázquez-Suñé, Enric; Velasco, Violeta
2016-02-01
Borehole Heat Exchangers (BHEs) are increasingly being used to exploit shallow geothermal energy. This paper presents a new methodology to provide a response to the need for a regional quantification of the geothermal potential that can be extracted by BHEs and the associated environmental impacts. A set of analytical solutions facilitates accurate calculation of the heat exchange of BHEs with the ground and its environmental impacts. For the first time, advection and dispersion heat transport mechanisms and the temporal evolution from the start of operation of the BHE are taken into account in the regional estimation of shallow geothermal resources. This methodology is integrated in a GIS environment, which facilitates the management of input and output data at a regional scale. An example of the methodology's application is presented for Barcelona, in Spain. As a result of the application, it is possible to show the strengths and improvements of this methodology in the development of potential maps of low temperature geothermal energy as well as maps of environmental impacts. The minimum and maximum energy potential values for the study site are 50 and 1800 W/m(2) for a drilled depth of 100 m, proportionally to Darcy velocity. Regarding to thermal impacts, the higher the groundwater velocity and the energy potential, the higher the size of the thermal plume after 6 months of exploitation, whose length ranges from 10 to 27 m long. A sensitivity analysis was carried out in the calculation of heat exchange rate and its impacts for different scenarios and for a wide range of Darcy velocities. The results of this analysis lead to the conclusion that the consideration of dispersion effects and temporal evolution of the exploitation prevent significant differences up to a factor 2.5 in the heat exchange rate accuracy and up to several orders of magnitude in the impacts generated. PMID:26605833
Kurylyk, Barret L.; McKenzie, Jeffrey M; MacQuarrie, Kerry T. B.; Voss, Clifford I.
2014-01-01
Numerous cold regions water flow and energy transport models have emerged in recent years. Dissimilarities often exist in their mathematical formulations and/or numerical solution techniques, but few analytical solutions exist for benchmarking flow and energy transport models that include pore water phase change. This paper presents a detailed derivation of the Lunardini solution, an approximate analytical solution for predicting soil thawing subject to conduction, advection, and phase change. Fifteen thawing scenarios are examined by considering differences in porosity, surface temperature, Darcy velocity, and initial temperature. The accuracy of the Lunardini solution is shown to be proportional to the Stefan number. The analytical solution results obtained for soil thawing scenarios with water flow and advection are compared to those obtained from the finite element model SUTRA. Three problems, two involving the Lunardini solution and one involving the classic Neumann solution, are recommended as standard benchmarks for future model development and testing.
NASA Astrophysics Data System (ADS)
Diémoz, Henri; Magri, Tiziana; Pession, Giordano; Zublena, Manuela; Campanelli, Monica; Gobbi, Gian Paolo; Barnaba, Francesca; Di Liberto, Luca; Dionisi, Davide
2016-04-01
A CHM-15k laser radar (lidar) was installed in April 2015 at the solar observatory of the Environmental Protection Agency (ARPA) of the Aosta Valley (Northern Italy, 45.74N, 7.36E, 560 m a.s.l.). The instrument operates at 1064 nm, is capable of mapping the vertical profile of aerosols and clouds up to the tropopause and is part of the Alice-net ceilometers network (www.alice-net.eu). The site is in a large Alpine valley floor, in a semi-rural context. Among the most interesting cases observed in the first months of operation, several days characterised by weak synoptic circulation and well-developed, thermally-driven up-valley winds are accompanied by the appearance of a thick aerosol layer in the afternoon. The phenomenon is frequent in Spring and Summer and is likely to be related to easterly airmass advections from polluted sites (e.g., the Po basin) rather than to local emissions. To test this hypothesis, the following method was adopted. First, some case studies were selected and the respective meteorological fields were analysed based on both observations at ground and the high-resolution output of the nonhydrostatic limited-area atmospheric prediction model maintained by the COnsortium for Small-scale MOdelling (COSMO) over the complex orography of the domain. Then, to evaluate the dynamics of the aerosol diffusion in the valley, the chemical transport 2D/3D eulerian Flexible Air quality Regional Model (FARM) was run. Finally, the three-dimensional output of the model was compared to the vertically-resolved aerosol field derived from the lidar-ceilometer soundings. The effects of up-slope winds, and the resulting subsidence along the main axis of the valley, is hypothesised to break up the aerosol layer close to the ground in the middle of the day and to drag the residual layer down into the mixing layer. The measurements by a co-located sun/sky photometer operating in the framework of the EuroSkyRad (ESR) network were additionally analysed to detect any
Anderman, Evan R.; Hill, Mary Catherine
2001-01-01
Observations of the advective component of contaminant transport in steady-state flow fields can provide important information for the calibration of ground-water flow models. This report documents the Advective-Transport Observation (ADV2) Package, version 2, which allows advective-transport observations to be used in the three-dimensional ground-water flow parameter-estimation model MODFLOW-2000. The ADV2 Package is compatible with some of the features in the Layer-Property Flow and Hydrogeologic-Unit Flow Packages, but is not compatible with the Block-Centered Flow or Generalized Finite-Difference Packages. The particle-tracking routine used in the ADV2 Package duplicates the semi-analytical method of MODPATH, as shown in a sample problem. Particles can be tracked in a forward or backward direction, and effects such as retardation can be simulated through manipulation of the effective-porosity value used to calculate velocity. Particles can be discharged at cells that are considered to be weak sinks, in which the sink applied does not capture all the water flowing into the cell, using one of two criteria: (1) if there is any outflow to a boundary condition such as a well or surface-water feature, or (2) if the outflow exceeds a user specified fraction of the cell budget. Although effective porosity could be included as a parameter in the regression, this capability is not included in this package. The weighted sum-of-squares objective function, which is minimized in the Parameter-Estimation Process, was augmented to include the square of the weighted x-, y-, and z-components of the differences between the simulated and observed advective-front locations at defined times, thereby including the direction of travel as well as the overall travel distance in the calibration process. The sensitivities of the particle movement to the parameters needed to minimize the objective function are calculated for any particle location using the exact sensitivity
On the tensorial nature of advective porosity
NASA Astrophysics Data System (ADS)
Neuman, Shlomo P.
2005-02-01
Field tracer tests indicate that advective porosity, the quantity relating advective velocity to Darcy flux, may exhibit directional dependence. Hydraulic anisotropy explains some but not all of the reported directional results. The present paper shows mathematically that directional variations in advective porosity may arise simply from incomplete mixing of an inert tracer between directional flow channels within a sampling (or support) volume ω of soil or rock that may be hydraulically isotropic or anisotropic. In the traditional fully homogenized case, our theory yields trivially a scalar advective porosity equal to the interconnected porosity ϕ, thus explaining neither the observed directional effects nor the widely reported experimental finding that advective porosity is generally smaller than ϕ. We consider incomplete mixing under conditions in which the characteristic time tD of longitudinal diffusion along channels across ω is much shorter than the characteristic time tH required for homogenization through transverse diffusion between channels. This may happen where flow takes place preferentially through relatively conductive channels and/or fractures of variable orientation separated by material that forms a partial barrier to diffusive transport. Our solution is valid for arbitrary channel Peclet numbers on a correspondingly wide range of time scales tD ⩽ t ≪ tH. It shows that the tracer center of mass is advected at a macroscopic velocity which is generally not collinear with the macroscopic Darcy flux and exceeds it in magnitude. These two vectors are related through a second-rank symmetric advective dispersivity tensor Φ. If the permeability k of ω is a symmetric positive-definite tensor, so is Φ. However, the principal directions and values of these two tensors are generally not the same; whereas those of k are a fixed property of the medium and the length-scale of ω, those of Φ depend additionally on the direction and magnitude of the
Hill, M.C.; Ely, D.M.; Tiedeman, C.R.; O'Brien, G.M.; D'Agnese, F.A.; Faunt, C.C.
2001-08-01
When a model is calibrated by nonlinear regression, calculated diagnostic statistics and measures of uncertainty provide a wealth of information about many aspects of the system. This report presents a method of ranking the likely importance of existing observation locations using measures of prediction uncertainty. It is suggested that continued monitoring is warranted at more important locations, and unwarranted or less warranted at less important locations. The report develops the methodology and then demonstrates it using the hydraulic-head observation locations of a three-layer model of the Death Valley regional flow system (DVRFS). The predictions of interest are subsurface transport from beneath Yucca Mountain and 14 underground Test Area (UGTA) sites. The advective component of transport is considered because it is the component most affected by the system dynamics represented by the regional-scale model being used. The problem is addressed using the capabilities of the U.S. Geological Survey computer program MODFLOW-2000, with its ADVective-Travel Observation (ADV) Package, and an additional computer program developed for this work.
Mass partitioning effects in diffusion transport.
Kojic, Milos; Milosevic, Miljan; Wu, Suhong; Blanco, Elvin; Ferrari, Mauro; Ziemys, Arturas
2015-08-28
Frequent mass exchange takes place in a heterogeneous environment among several phases, where mass partitioning may occur at the interface of phases. Analytical and computational methods for diffusion do not usually incorporate molecule partitioning masking the true picture of mass transport. Here we present a computational finite element methodology to calculate diffusion mass transport with a partitioning phenomenon included and the analysis of the effects of partitioning. Our numerical results showed that partitioning controls equilibrated mass distribution as expected from analytical solutions. The experimental validation of mass release from drug-loaded nanoparticles showed that partitioning might even dominate in some cases with respect to diffusion itself. The analysis of diffusion kinetics in the parameter space of partitioning and diffusivity showed that partitioning is an extremely important parameter in systems, where mass diffusivity is fast and that the concentration of nanoparticles can control payload retention inside nanoparticles. The computational and experimental results suggest that partitioning and physiochemical properties of phases play an important, if not crucial, role in diffusion transport and should be included in the studies of mass transport processes.
Mass partitioning effects in diffusion transport.
Kojic, Milos; Milosevic, Miljan; Wu, Suhong; Blanco, Elvin; Ferrari, Mauro; Ziemys, Arturas
2015-08-28
Frequent mass exchange takes place in a heterogeneous environment among several phases, where mass partitioning may occur at the interface of phases. Analytical and computational methods for diffusion do not usually incorporate molecule partitioning masking the true picture of mass transport. Here we present a computational finite element methodology to calculate diffusion mass transport with a partitioning phenomenon included and the analysis of the effects of partitioning. Our numerical results showed that partitioning controls equilibrated mass distribution as expected from analytical solutions. The experimental validation of mass release from drug-loaded nanoparticles showed that partitioning might even dominate in some cases with respect to diffusion itself. The analysis of diffusion kinetics in the parameter space of partitioning and diffusivity showed that partitioning is an extremely important parameter in systems, where mass diffusivity is fast and that the concentration of nanoparticles can control payload retention inside nanoparticles. The computational and experimental results suggest that partitioning and physiochemical properties of phases play an important, if not crucial, role in diffusion transport and should be included in the studies of mass transport processes. PMID:26204522
Mass Transport in Global Geophysical Fluids
NASA Technical Reports Server (NTRS)
Chao, B. F.
1999-01-01
Mass transports occurring in the atmosphere-hydrosphere-solid Earth-core system (the "global geophysical fluids") are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, tides, hydrological water redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. With only a few exceptions on the Earth surface, the temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have the capability of monitoring certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. These techniques include the very-long-baseline interferometry, satellite laser ranging and Doppler tracking, and the Global Positioning System, all entail global observational networks. While considerable advances have been made in observing and understanding of the dynamics of Earth's rotation, only the lowest-degree gravitational variations have been observed and limited knowledge of geocenter motion obtained. New space missions, projects and initiatives promise to further improve the measurements and hence our knowledge about the global mass transports. The latter contributes to our understanding and modeling capability of the geophysical processes that produce and regulate the mass transports, as well as the solid Earth's response to such changes in constraining the modeling of Earth's mechanical properties.
Hill, Mary C.; Ely, D. Matthew; Tiedeman, Claire R.; O'Brien, Grady M.; D'Agnese, Frank A.; Faunt, Claudia C.
2001-01-01
When a model is calibrated by nonlinear regression, calculated diagnostic statistics and measures of uncertainty provide a wealth of information about many aspects of the system. This report presents a method of ranking the likely importance of existing observation locations using measures of prediction uncertainty. It is suggested that continued monitoring is warranted at more important locations, and unwarranted or less warranted at less important locations. The report develops the methodology and then demonstrates it using the hydraulic-head observation locations of a three-layer model of the Death Valley regional flow system. The predictions of interest are subsurface transport from beneath Yucca Mountain and 14 Underground Test Areas. The advective component of transport is considered because it is the component most affected by the system dynamics represented by the scale model being used. The problem is addressed using the capabilities of the U.S. Geological Survey computer program MODFLOW-2000, with its ADVective-Travel Observation (ADV) Package, and an additional computer program developed for this work. The methods presented in this report are used in three ways. (1) The ratings for individual observations are obtained by manipulating the measures of prediction uncertainty, and do not involve recalibrating the model. In this analysis, observation locations are each omitted individually and the resulting increase in uncertainty in the predictions is calculated. The uncertainty is quantified as standard deviations on the simulated advective transport. The increase in uncertainty is quantified as the percent increase in the standard deviations caused by omitting the one observation location from the calculation of standard deviations. In general, observation locations associated with larger increases are rated as more important. (2) Ratings for largely geographically based groups are obtained using a straightforward extension of the method used for
Wagner, Brian J.; Gorelick, Steven M.
1986-01-01
A simulation nonlinear multiple-regression methodology for estimating parameters that characterize the transport of contaminants is developed and demonstrated. Finite difference containment transport simulation is combined with a nonlinear weighted least squares multiple-regression procedure. The technique provides optimal parameter estimates and gives statistics for assessing the reliability of these estimates under certain general assumptions about the distributions of the random measurement errors. Monte Carlo analysis is used to estimate parameter reliability for a hypothetical homogeneous soil column for which concentration data contain large random measurement errors. The value of data collected spatially versus data collected temporally was investigated for estimation of velocity, dispersion coefficient, effective porosity, first-order decay rate, and zero-order production. The use of spatial data gave estimates that were 2-3 times more reliable than estimates based on temporal data for all parameters except velocity. (Estimated author abstract) Refs.
Merritt, M.L.
1993-01-01
The simulation of the transport of injected freshwater in a thin brackish aquifer, overlain and underlain by confining layers containing more saline water, is shown to be influenced by the choice of the finite-difference approximation method, the algorithm for representing vertical advective and dispersive fluxes, and the values assigned to parametric coefficients that specify the degree of vertical dispersion and molecular diffusion that occurs. Computed potable water recovery efficiencies will differ depending upon the choice of algorithm and approximation method, as will dispersion coefficients estimated based on the calibration of simulations to match measured data. A comparison of centered and backward finite-difference approximation methods shows that substantially different transition zones between injected and native waters are depicted by the different methods, and computed recovery efficiencies vary greatly. Standard and experimental algorithms and a variety of values for molecular diffusivity, transverse dispersivity, and vertical scaling factor were compared in simulations of freshwater storage in a thin brackish aquifer. Computed recovery efficiencies vary considerably, and appreciable differences are observed in the distribution of injected freshwater in the various cases tested. The results demonstrate both a qualitatively different description of transport using the experimental algorithms and the interrelated influences of molecular diffusion and transverse dispersion on simulated recovery efficiency. When simulating natural aquifer flow in cross-section, flushing of the aquifer occurred for all tested coefficient choices using both standard and experimental algorithms. ?? 1993.
Texture Mapping via Optimal Mass Transport
Dominitz, Ayelet; Tannenbaum, Allen
2010-01-01
In this paper, we present a novel method for texture mapping of closed surfaces. Our method is based on the technique of optimal mass transport (also known as the “earth-mover’s metric”). This is a classical problem that concerns determining the optimal way, in the sense of minimal transportation cost, of moving a pile of soil from one site to another. In our context, the resulting mapping is area preserving and minimizes angle distortion in the optimal mass sense. Indeed, we first begin with an angle-preserving mapping (which may greatly distort area) and then correct it using the mass transport procedure derived via a certain gradient flow. In order to obtain fast convergence to the optimal mapping, we incorporate a multiresolution scheme into our flow. We also use ideas from discrete exterior calculus in our computations. PMID:20224137
Controlling Mass Transport in Microfluidic Devices
NASA Astrophysics Data System (ADS)
Kuo, Jason S.; Chiu, Daniel T.
2011-07-01
Microfluidic platforms offer exquisite capabilities in controlling mass transport for biological studies. In this review, we focus on recent developments in manipulating chemical concentrations at the microscale. Some techniques prevent or accelerate mixing, whereas others shape the concentration gradients of chemical and biological molecules. We also highlight several in vitro biological studies in the areas of organ engineering, cancer, and blood coagulation that have benefited from accurate control of mass transfer.
Oceanic mass transport by mesoscale eddies.
Zhang, Zhengguang; Wang, Wei; Qiu, Bo
2014-07-18
Oceanic transports of heat, salt, fresh water, dissolved CO2, and other tracers regulate global climate change and the distribution of natural marine resources. The time-mean ocean circulation transports fluid as a conveyor belt, but fluid parcels can also be trapped and transported discretely by migrating mesoscale eddies. By combining available satellite altimetry and Argo profiling float data, we showed that the eddy-induced zonal mass transport can reach a total meridionally integrated value of up to 30 to 40 sverdrups (Sv) (1 Sv = 10(6) cubic meters per second), and it occurs mainly in subtropical regions, where the background flows are weak. This transport is comparable in magnitude to that of the large-scale wind- and thermohaline-driven circulation. PMID:25035491
Oceanic mass transport by mesoscale eddies.
Zhang, Zhengguang; Wang, Wei; Qiu, Bo
2014-07-18
Oceanic transports of heat, salt, fresh water, dissolved CO2, and other tracers regulate global climate change and the distribution of natural marine resources. The time-mean ocean circulation transports fluid as a conveyor belt, but fluid parcels can also be trapped and transported discretely by migrating mesoscale eddies. By combining available satellite altimetry and Argo profiling float data, we showed that the eddy-induced zonal mass transport can reach a total meridionally integrated value of up to 30 to 40 sverdrups (Sv) (1 Sv = 10(6) cubic meters per second), and it occurs mainly in subtropical regions, where the background flows are weak. This transport is comparable in magnitude to that of the large-scale wind- and thermohaline-driven circulation.
Lattice Boltzmann method for the fractional advection-diffusion equation.
Zhou, J G; Haygarth, P M; Withers, P J A; Macleod, C J A; Falloon, P D; Beven, K J; Ockenden, M C; Forber, K J; Hollaway, M J; Evans, R; Collins, A L; Hiscock, K M; Wearing, C; Kahana, R; Villamizar Velez, M L
2016-04-01
Mass transport, such as movement of phosphorus in soils and solutes in rivers, is a natural phenomenon and its study plays an important role in science and engineering. It is found that there are numerous practical diffusion phenomena that do not obey the classical advection-diffusion equation (ADE). Such diffusion is called abnormal or superdiffusion, and it is well described using a fractional advection-diffusion equation (FADE). The FADE finds a wide range of applications in various areas with great potential for studying complex mass transport in real hydrological systems. However, solution to the FADE is difficult, and the existing numerical methods are complicated and inefficient. In this study, a fresh lattice Boltzmann method is developed for solving the fractional advection-diffusion equation (LabFADE). The FADE is transformed into an equation similar to an advection-diffusion equation and solved using the lattice Boltzmann method. The LabFADE has all the advantages of the conventional lattice Boltzmann method and avoids a complex solution procedure, unlike other existing numerical methods. The method has been validated through simulations of several benchmark tests: a point-source diffusion, a boundary-value problem of steady diffusion, and an initial-boundary-value problem of unsteady diffusion with the coexistence of source and sink terms. In addition, by including the effects of the skewness β, the fractional order α, and the single relaxation time τ, the accuracy and convergence of the method have been assessed. The numerical predictions are compared with the analytical solutions, and they indicate that the method is second-order accurate. The method presented will allow the FADE to be more widely applied to complex mass transport problems in science and engineering.
Lattice Boltzmann method for the fractional advection-diffusion equation
NASA Astrophysics Data System (ADS)
Zhou, J. G.; Haygarth, P. M.; Withers, P. J. A.; Macleod, C. J. A.; Falloon, P. D.; Beven, K. J.; Ockenden, M. C.; Forber, K. J.; Hollaway, M. J.; Evans, R.; Collins, A. L.; Hiscock, K. M.; Wearing, C.; Kahana, R.; Villamizar Velez, M. L.
2016-04-01
Mass transport, such as movement of phosphorus in soils and solutes in rivers, is a natural phenomenon and its study plays an important role in science and engineering. It is found that there are numerous practical diffusion phenomena that do not obey the classical advection-diffusion equation (ADE). Such diffusion is called abnormal or superdiffusion, and it is well described using a fractional advection-diffusion equation (FADE). The FADE finds a wide range of applications in various areas with great potential for studying complex mass transport in real hydrological systems. However, solution to the FADE is difficult, and the existing numerical methods are complicated and inefficient. In this study, a fresh lattice Boltzmann method is developed for solving the fractional advection-diffusion equation (LabFADE). The FADE is transformed into an equation similar to an advection-diffusion equation and solved using the lattice Boltzmann method. The LabFADE has all the advantages of the conventional lattice Boltzmann method and avoids a complex solution procedure, unlike other existing numerical methods. The method has been validated through simulations of several benchmark tests: a point-source diffusion, a boundary-value problem of steady diffusion, and an initial-boundary-value problem of unsteady diffusion with the coexistence of source and sink terms. In addition, by including the effects of the skewness β , the fractional order α , and the single relaxation time τ , the accuracy and convergence of the method have been assessed. The numerical predictions are compared with the analytical solutions, and they indicate that the method is second-order accurate. The method presented will allow the FADE to be more widely applied to complex mass transport problems in science and engineering.
Lattice Boltzmann method for the fractional advection-diffusion equation.
Zhou, J G; Haygarth, P M; Withers, P J A; Macleod, C J A; Falloon, P D; Beven, K J; Ockenden, M C; Forber, K J; Hollaway, M J; Evans, R; Collins, A L; Hiscock, K M; Wearing, C; Kahana, R; Villamizar Velez, M L
2016-04-01
Mass transport, such as movement of phosphorus in soils and solutes in rivers, is a natural phenomenon and its study plays an important role in science and engineering. It is found that there are numerous practical diffusion phenomena that do not obey the classical advection-diffusion equation (ADE). Such diffusion is called abnormal or superdiffusion, and it is well described using a fractional advection-diffusion equation (FADE). The FADE finds a wide range of applications in various areas with great potential for studying complex mass transport in real hydrological systems. However, solution to the FADE is difficult, and the existing numerical methods are complicated and inefficient. In this study, a fresh lattice Boltzmann method is developed for solving the fractional advection-diffusion equation (LabFADE). The FADE is transformed into an equation similar to an advection-diffusion equation and solved using the lattice Boltzmann method. The LabFADE has all the advantages of the conventional lattice Boltzmann method and avoids a complex solution procedure, unlike other existing numerical methods. The method has been validated through simulations of several benchmark tests: a point-source diffusion, a boundary-value problem of steady diffusion, and an initial-boundary-value problem of unsteady diffusion with the coexistence of source and sink terms. In addition, by including the effects of the skewness β, the fractional order α, and the single relaxation time τ, the accuracy and convergence of the method have been assessed. The numerical predictions are compared with the analytical solutions, and they indicate that the method is second-order accurate. The method presented will allow the FADE to be more widely applied to complex mass transport problems in science and engineering. PMID:27176431
NASA Astrophysics Data System (ADS)
Baechler, S.; Croisé, J.; Altmann, S.
2012-12-01
Chemico-osmosis is a recognized phenomenon taking place in clay mineral-rich sedimentary formations and a number of questions have been raised concerning its potential effects on pressure fields in and around underground radioactive waste repositories installed in such formations. Certain radioactive waste packages contain large quantities of nitrate salts whose release might result in the presence of highly concentrated salt solutions in the disposal cells, during their resaturation after closure of the facility. This would lead to large solute concentration gradients within the formation's porewater which could then potentially induce significant chemico-osmotic fluxes. In this paper, we assess the impact of chemico-osmotic fluxes on the water pressure during the post-closure period of a typical disposal cell for intermediate-level, long-lived bituminised radioactive waste in the Callovo-Oxfordian Clay formation. A numerical model of chemico-osmotic water flow and solute transport has been developed based on the work of Bader and Kooi (2005) [5], and including Bresler's dependence of osmotic efficiency on concentration and compaction state [9]. Model validity has been extended to highly concentrated solutions by incorporating a concentration-dependent activity coefficient, based on the Pitzer's equations. Results show that due to the strong dependence of the osmotic coefficient on concentration, the impact of chemico-osmosis on water flow and on the pressure field around the disposal cell is relatively low. A maximum overpressure of the order of 1 MPa was obtained. No difference in the simulation results were noticed for disposal cell solutions having concentrations higher than 1 M NaNO3. Differences between simulations were found to be almost entirely due to Bresler's relationship i.e., the model of the dependence between osmotic efficiency and concentration, and only slightly on the activity coefficient correction. Questions remain regarding the appropriate
Delft Mass Transport model DMT-2
NASA Astrophysics Data System (ADS)
Ditmar, Pavel; Hashemi Farahani, Hassan; Inacio, Pedro; Klees, Roland; Zhao, Qile; Guo, Jing; Liu, Xianglin; Sun, Yu; Riva, Ricardo; Ran, Jiangjun
2013-04-01
Gravity Recovery And Climate Experiment (GRACE) satellite mission has enormously extended our knowledge of the Earth's system by allowing natural mass transport of various origin to be quantified. This concerns, in particular, the depletion and replenishment of continental water stocks; shrinking of polar ice sheets; deformation of the Earth's crust triggered by large earthquakes, and isostatic adjustment processes. A number of research centers compute models of temporal gravity field variations and mass transport, using GRACE data as input. One of such models - Delft Mass Transport model - is being produced at the Delft University of Technology in collaboration with the GNSS Research Center of Wuhan University. A new release of this model, DMT-2, has been produced on the basis of a new (second) release of GRACE level-1b data. This model consists of a time-series of monthly solutions spanning a time interval of more than 8 years, starting from Feb. 2003. Each solution consists of spherical harmonic coefficients up to degree 120. Both unconstrained and optimally filtered solutions are obtained. The most essential improvements of the DMT-2 model, as compared to its predecessors (DMT-1 and DMT-1b), are as follows: (i) improved estimation and elimination of low-frequency noise in GRACE data, so that strong mass transport signals are not damped; (ii) computation of accurate stochastic models of data noise for each month individually with a subsequent application of frequency-dependent data weighting, which allows statistically optimal solutions to be compiled even if data noise is colored and gradually changes in time; (iii) optimized estimation of accelerometer calibration parameters; (iv) incorporation of degree 1 coefficients estimated with independent techniques; (v) usage of state-of-the-art background models to de-alias GRACE data from rapid mass transport signals (this includes the EOT11a model of ocean tides and the latest release of the AOD1B product describing
NASA Astrophysics Data System (ADS)
Licata, Nicholas A.; Fuller, Nathaniel J.
Understanding the physical mechanisms by which an individual cell interacts with its environment often requires detailed information about the fluid in which the cell is immersed. Mass transport between the interior of the cell and the external environment is influenced by the flow of the extracellular fluid and the molecular diffusivity. Analytical calculations of the flow field are challenging in simple geometries, and not generally available in more realistic cases with irregular domain boundaries. Motivated by these problems, we discuss the numerical solution of Stokes equation by implementing a Gauss-Seidel algorithm on a staggered computational grid. The computed velocity profile is used as input to numerically solve the advection-diffusion equation for mass transport. Special attention is paid to the case of two-dimensional flows at large Péclet number. The numerical results are compared with a perturbative analytical treatment of the concentration boundary layer.
Oxygen Mass Transport in Stented Coronary Arteries.
Murphy, Eoin A; Dunne, Adrian S; Martin, David M; Boyle, Fergal J
2016-02-01
Oxygen deficiency, known as hypoxia, in arterial walls has been linked to increased intimal hyperplasia, which is the main adverse biological process causing in-stent restenosis. Stent implantation has significant effects on the oxygen transport into the arterial wall. Elucidating these effects is critical to optimizing future stent designs. In this study the most advanced oxygen transport model developed to date was assessed in two test cases and used to compare three coronary stent designs. Additionally, the predicted results from four simplified blood oxygen transport models are compared in the two test cases. The advanced model showed good agreement with experimental measurements within the mass-transfer boundary layer and at the luminal surface; however, more work is needed in predicting the oxygen transport within the arterial wall. Simplifying the oxygen transport model within the blood flow produces significant errors in predicting the oxygen transport in arteries. This study can be used as a guide for all future numerical studies in this area and the advanced model could provide a powerful tool in aiding design of stents and other cardiovascular devices.
Advection, diffusion, and delivery over a network
NASA Astrophysics Data System (ADS)
Heaton, Luke L. M.; López, Eduardo; Maini, Philip K.; Fricker, Mark D.; Jones, Nick S.
2012-08-01
Many biological, geophysical, and technological systems involve the transport of a resource over a network. In this paper, we present an efficient method for calculating the exact quantity of the resource in each part of an arbitrary network, where the resource is lost or delivered out of the network at a given rate, while being subject to advection and diffusion. The key conceptual step is to partition the resource into material that does or does not reach a node over a given time step. As an example application, we consider resource allocation within fungal networks, and analyze the spatial distribution of the resource that emerges as such networks grow over time. Fungal growth involves the expansion of fluid filled vessels, and such growth necessarily involves the movement of fluid. We develop a model of delivery in growing fungal networks, and find good empirical agreement between our model and experimental data gathered using radio-labeled tracers. Our results lead us to suggest that in foraging fungi, growth-induced mass flow is sufficient to account for long-distance transport, if the system is well insulated. We conclude that active transport mechanisms may only be required at the very end of the transport pathway, near the growing tips.
Energy and mass transport in the thermosphere
NASA Technical Reports Server (NTRS)
Mayr, H. G.; Harris, I.; Spencer, N. W.
1979-01-01
Examples illustrating the effects of large scale energy and mass transport in the thermosphere discussed include: (1) The seasonal variations reveal temperature, composition, and ionospheric anomalies involving energy exchange between the thermosphere and mesosphere. (2) The midnight temperature maximum in the thermosphere is interpreted as a signature of tidal waves emanating from the mesosphere and momentum coupling associated with ion drag. (3) The ionospheric storm in the F region illustrates the intricate effects of large scale atmospheric winds driven by magnetospheric energization processes. (4) Atmospheric signatures of Joule heating and electric field momentum coupling are markedly different.
Mass transport in annular spherical system
NASA Astrophysics Data System (ADS)
Bauer, Helmut F.
The mass transport between two concentric spheres with inlet and outlet at the poles was determined for ideal liquid flow (plug flow) and laminar flow for constant concentration at the spherical walls and constant concentration at the inlet. Velocity distribution and local concentration profiles were determined analytically for various widths of the annular spherical conduit and various diffusive flow parameters. It is found that with the increase of this parameter, the decay becomes quite rapid and that the same effect occurs for increasing diameter ratio of the spheres. This configuration may possibly be used as a basic element of an artificial kidney.
Sharp, R.W. Jr.; Barton, R.T.
1981-01-21
A continuous rezoning procedure has been implemented in the computational cycle of a version of the HEMP two-dimensional, Lagrange, fluid dynamics code. The rezoning problem is divided into two steps. The first step requires the solving of ordinary Lagrange equations of motion; the second step consists of adding equipotential grid relaxation along with an advective remapping scheme.
Lagrangian analysis of mixing and transport of water masses in the marine bays
NASA Astrophysics Data System (ADS)
Prants, S. V.; Ponomarev, V. I.; Budyansky, M. V.; Uleysky, M. Yu.; Fayman, P. A.
2013-01-01
The Lagrangian approach to studying the mixing and transport of a passive admixture in marine bays and gulfs based on the methods of a theory of dynamic systems is developed. This approach is employed to investigate the lateral mixing and transport of waters in the Peter the Great Bay, Japan Sea, using a velocity field of the predictive numerical hydrodynamic circulation model of a synoptic scale. It is shown that the Lagrangian characteristics, such as the maximum accumulated Lyapunov exponent, the time of particle stay in the bay, particle relative displacements, and the number of cyclonic and anticyclonic rotations, allow us to describe the movement of water masses, the character of mixing, and chaos in the Bay. In integrating the advection equations forward and backward in time, maps showing a number of particle arrivals to different regions of the Bay make it possible to establish corridors through which particles leave and enter the Bay.
Physics-based agent to simulant correlations for vapor phase mass transport.
Willis, Matthew P; Varady, Mark J; Pearl, Thomas P; Fouse, Janet C; Riley, Patrick C; Mantooth, Brent A; Lalain, Teri A
2013-12-15
Chemical warfare agent simulants are often used as an agent surrogate to perform environmental testing, mitigating exposure hazards. This work specifically addresses the assessment of downwind agent vapor concentration resulting from an evaporating simulant droplet. A previously developed methodology was used to estimate the mass diffusivities of the chemical warfare agent simulants methyl salicylate, 2-chloroethyl ethyl sulfide, di-ethyl malonate, and chloroethyl phenyl sulfide. Along with the diffusivity of the chemical warfare agent bis(2-chloroethyl) sulfide, the simulant diffusivities were used in an advection-diffusion model to predict the vapor concentrations downwind from an evaporating droplet of each chemical at various wind velocities and temperatures. The results demonstrate that the simulant-to-agent concentration ratio and the corresponding vapor pressure ratio are equivalent under certain conditions. Specifically, the relationship is valid within ranges of measurement locations relative to the evaporating droplet and observation times. The valid ranges depend on the relative transport properties of the agent and simulant, and whether vapor transport is diffusion or advection dominant.
Mass transfer and transport in salt repositories
Pigford, T.H.; Chambre, P.L.; Lee, W.W.L.
1989-02-01
Salt is a unique rock isolation of nuclear waste because it is dry'' and nearly impermeable. In this paper we summarize some mass-transfer and transport analyses of salt repositories. First we analyses brine migration. Heating by high-level waste can cause brine in grain boundaries to move due to pressure-gradients. We analyze brine migration treating salt as a thermoelastic solid and found that brine migration is transient and localized. We use previously developed techniques to estimate release rates from waste packages by diffusion. Interbeds exist in salt and may be conduits for radionuclide migration. We analyze steady-state migration due to brine flow in the interbed, as a function of the Peclet number. Then we analyze transient mass transfer, both into the interbed and directly to salt, due only to diffusion. Finally we compare mass transfer rates of a waste cylinder in granite facing a fracture and in salt facing an interbed. In all cases, numerical illustrations of the analytic solution are given. 10 refs., 4 figs., 3 tabs.
Karniadakis, George Em
2014-03-11
The main objective of this project is to develop new computational tools for uncertainty quantifica- tion (UQ) of systems governed by stochastic partial differential equations (SPDEs) with applications to advection-diffusion-reaction systems. We pursue two complementary approaches: (1) generalized polynomial chaos and its extensions and (2) a new theory on deriving PDF equations for systems subject to color noise. The focus of the current work is on high-dimensional systems involving tens or hundreds of uncertain parameters.
Laser speckle contrast imaging is sensitive to advective flux
NASA Astrophysics Data System (ADS)
Khaksari, Kosar; Kirkpatrick, Sean J.
2016-07-01
Unlike laser Doppler flowmetry, there has yet to be presented a clear description of the physical variables that laser speckle contrast imaging (LSCI) is sensitive to. Herein, we present a theoretical basis for demonstrating that LSCI is sensitive to total flux and, in particular, the summation of diffusive flux and advective flux. We view LSCI from the perspective of mass transport and briefly derive the diffusion with drift equation in terms of an LSCI experiment. This equation reveals the relative sensitivity of LSCI to both diffusive flux and advective flux and, thereby, to both concentration and the ordered velocity of the scattering particles. We demonstrate this dependence through a short series of flow experiments that yield relationships between the calculated speckle contrast and the concentration of the scatterers (manifesting as changes in scattering coefficient), between speckle contrast and the velocity of the scattering fluid, and ultimately between speckle contrast and advective flux. Finally, we argue that the diffusion with drift equation can be used to support both Lorentzian and Gaussian correlation models that relate observed contrast to the movement of the scattering particles and that a weighted linear combination of these two models is likely the most appropriate model for relating speckle contrast to particle motion.
Metamorphism during temperature gradient with undersaturated advective airflow in a snow sample
NASA Astrophysics Data System (ADS)
Ebner, Pirmin Philipp; Schneebeli, Martin; Steinfeld, Aldo
2016-04-01
Snow at or close to the surface commonly undergoes temperature gradient metamorphism under advective flow, which alters its microstructure and physical properties. Time-lapse X-ray microtomography is applied to investigate the structural dynamics of temperature gradient snow metamorphism exposed to an advective airflow in controlled laboratory conditions. Cold saturated air at the inlet was blown into the snow samples and warmed up while flowing across the sample with a temperature gradient of around 50 K m-1. Changes of the porous ice structure were observed at mid-height of the snow sample. Sublimation occurred due to the slight undersaturation of the incoming air into the warmer ice matrix. Diffusion of water vapor opposite to the direction of the temperature gradient counteracted the mass transport of advection. Therefore, the total net ice change was negligible leading to a constant porosity profile. However, the strong recrystallization of water molecules in snow may impact its isotopic or chemical content.
Ackerman, Daniel J.; Rousseau, Joseph P.; Rattray, Gordon W.; Fisher, Jason C.
2010-01-01
Three-dimensional steady-state and transient models of groundwater flow and advective transport in the eastern Snake River Plain aquifer were developed by the U.S. Geological Survey in cooperation with the U.S. Department of Energy. The steady-state and transient flow models cover an area of 1,940 square miles that includes most of the 890 square miles of the Idaho National Laboratory (INL). A 50-year history of waste disposal at the INL has resulted in measurable concentrations of waste contaminants in the eastern Snake River Plain aquifer. Model results can be used in numerical simulations to evaluate the movement of contaminants in the aquifer. Saturated flow in the eastern Snake River Plain aquifer was simulated using the MODFLOW-2000 groundwater flow model. Steady-state flow was simulated to represent conditions in 1980 with average streamflow infiltration from 1966-80 for the Big Lost River, the major variable inflow to the system. The transient flow model simulates groundwater flow between 1980 and 1995, a period that included a 5-year wet cycle (1982-86) followed by an 8-year dry cycle (1987-94). Specified flows into or out of the active model grid define the conditions on all boundaries except the southwest (outflow) boundary, which is simulated with head-dependent flow. In the transient flow model, streamflow infiltration was the major stress, and was variable in time and location. The models were calibrated by adjusting aquifer hydraulic properties to match simulated and observed heads or head differences using the parameter-estimation program incorporated in MODFLOW-2000. Various summary, regression, and inferential statistics, in addition to comparisons of model properties and simulated head to measured properties and head, were used to evaluate the model calibration. Model parameters estimated for the steady-state calibration included hydraulic conductivity for seven of nine hydrogeologic zones and a global value of vertical anisotropy. Parameters
NASA Astrophysics Data System (ADS)
Zamani, K.; Bombardelli, F.
2011-12-01
Almost all natural phenomena on Earth are highly nonlinear. Even simplifications to the equations describing nature usually end up being nonlinear partial differential equations. Transport (ADR) equation is a pivotal equation in atmospheric sciences and water quality. This nonlinear equation needs to be solved numerically for practical purposes so academicians and engineers thoroughly rely on the assistance of numerical codes. Thus, numerical codes require verification before they are utilized for multiple applications in science and engineering. Model verification is a mathematical procedure whereby a numerical code is checked to assure the governing equation is properly solved as it is described in the design document. CFD verification is not a straightforward and well-defined course. Only a complete test suite can uncover all the limitations and bugs. Results are needed to be assessed to make a distinction between bug-induced-defect and innate limitation of a numerical scheme. As Roache (2009) said, numerical verification is a state-of-the-art procedure. Sometimes novel tricks work out. This study conveys the synopsis of the experiences we gained during a comprehensive verification process which was done for a transport solver. A test suite was designed including unit tests and algorithmic tests. Tests were layered in complexity in several dimensions from simple to complex. Acceptance criteria defined for the desirable capabilities of the transport code such as order of accuracy, mass conservation, handling stiff source term, spurious oscillation, and initial shape preservation. At the begining, mesh convergence study which is the main craft of the verification is performed. To that end, analytical solution of ADR equation gathered. Also a new solution was derived. In the more general cases, lack of analytical solution could be overcome through Richardson Extrapolation and Manufactured Solution. Then, two bugs which were concealed during the mesh convergence
Mass transport enhancement in modified supercritical fluid
Abaroudi, K.; Trabelsi, F.; Calloud-Gabriel, B.; Recasens, F.
1999-09-01
In this paper, the supercritical-fluid extraction (SCFE) of a packed bed of {beta}-naphthol-impregnated porous pellets was studied. An increasing number of industrial SCFE processes involve the extraction of a solute retained within a porous matrix, usually in the form of seeds or irregular grains. The interest in high-pressure extraction is due to certain advantages of dense gases and near-critical solvents over conventional liquid solvents. In this study, modified carbon dioxide was the fluid studied. The effects of temperature, pressure, fluid velocity, particle size, and gravity were experimentally studied using carbon dioxide, pure or mixed with varying amounts of toluene (6%, and 10%). For the solute, {beta}-naphthol, the solubilities in SC carbon dioxide mixtures (from 0 to 10% toluene) were available from separate experiments. The dispersed plug-flow model was used to describe the nonideal flow. Fitting the experimental data with the model solution allowed the measurements of the fluid-to-particle mass transfer coefficient, the intraparticle diffusivity, and the axial dispersion coefficient (the latter in terms of the axial Peclet number). The influence of cosolvent concentration on the three transport parameters, which were not available so far, is presented.
Mass transport in physical and biological BTEX removal in a sandy aquifer
Sturman, P.J.; Cunningham, A.B.; Niehaus, S.L.; Wolfram, J.H.
1995-12-31
Injection of oxygen and nutrient-amended water facilitated alkylbenzene biodegradation in a sandy aquifer. Pumping recovery wells and air-stripping groundwater further hastened contaminant removal downgradient from the source area. High monitoring well density allowed calculation of a contaminant mass balance using contour plots developed with Surfer{reg_sign} software. Physical removal (air-stripping) and in situ attenuation appear equally responsible for contaminant removal within this aquifer. Dissolved oxygen data implicate biodegradation as the responsible in situ mechanism with a good stoichiometric fit to BTEX attenuation data. Selective plating confirmed the presence of hydrocarbon-degrading bacteria. Calculations indicate desorption is a major source for recontamination of site groundwater. Contaminant reduction is most pronounced immediately downgradient from reinjection wells. Advective transport and mixing of oxygen in the contaminated zone, rather than microbial kinetics, appears to limit in situ contaminant attenuation.
Kang, Chulhyung.
1989-01-01
Analytical models for the mass transfer and transport of radionuclides through waste package backfill material are developed and their numerical illustrations are demonstrated. These models can aid in the performance assessment of the waste package in nuclear waste repositories. The following analyses are considered to study the performance of the backfill barrier in a geologic nuclear waste repository. (1) The analysis for time and space dependent mass transfer and mass transport of a radioactive decay chain for a congruent release with the matrix species is studied. Non-recursive analytical solutions are derived for a semi-infinite medium and a finite medium. The theory is illustrated with the important decay chain {sup 234}U {yields} {sup 230}Th {yields} {sup 226}Ra. (2) The time and space dependent mass transport for high solubility nuclides, such as iodine or cesium, is analyzed. The approximate solution that is valid for all times is developed, and validated by comparison with an asymptotic solution and the solution obtained by the numerical inversion of a Laplace transform covering the entire time span. From this model one can determine the thickness of the backfill to satisfy a prescribed release rate limit for high soluble radionuclides. (3) The analysis of the transient radionuclide migration through the backfill into a fracture intersecting the waste form is developed. The nuclides are advected by water flowing in the fracture. The numerical illustrations show that the species transport for the short half-life nuclide can be stopped effectively within the backfill, but the backfill can no longer retard the migration for stable nuclides or long half-life nuclides after some initial time period. (4) The steady state mass transfer from a cylindrical waste form with flow through the backfill layer is examined.
NASA Astrophysics Data System (ADS)
Koussis, A. S.; Mazi, K.; Lykoudis, S.; Argyriou, A.
2003-04-01
Source signal identification is a forensic task, within regulatory and legal activities. Estimation of the contaminant's release history by reverse-solution (stepping back in time) of the mass transport equation, partialC/partialt + u partialC/partialx = D partial^2C/ partialx^2, is an ill-posed problem (its solution is non-unique and unstable). For this reason we propose the recovery of the source signal from measured concentration profile data through a numerical technique that is based on the premise of advection-dominated transport. We derive an explicit numerical scheme by discretising the pure advection equation, partialC/ partialt + u partial C/partialx = 0, such that it also models gradient-transport by matching numerical diffusion (leading truncation error term) to physical dispersion. The match is achieved by appropriate choice of the scheme’s spatial weighting coefficient q as function of the grid Peclet number P = u Δx/D: θ = 0.5 - P-1. This is a novel and efficient direct solution approach for the signal identification problem at hand that can accommodate space-variable transport parameters as well. First, we perform numerical experiments to define proper grids (in terms of Courant {bf C} = uΔt/Δx and grid Peclet P numbers) for control of spurious oscillations (instability). We then assess recovery of source signals, from perfect as well as from error-seeded field data, considering field data resulting from single- and double-peaked source signals. With perfect data, the scheme recovers source signals with very good accuracy. With imperfect data, however, additional data conditioning is required for control of signal noise. Alternating reverse profile computation with Savitzky-Golay low-pass filtering allows the recovery of well-timed and smooth source signals that satisfy mass conservation very well. Current research focuses on: a) optimising the performance of Savitzky-Golay filters, through selection of appropriate parameters (order of least
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Grimm, S. A.; Schneebeli, M.; Steinfeld, A.
2014-09-01
An instrumented sample holder was developed for time-lapse microtomography of snow samples to enable in situ nondestructive spatial and temporal measurements under controlled advective airflows, temperature gradients, and air humidities. The design was aided by computational fluid dynamics simulations to evaluate the airflow uniformity across the snow sample. Morphological and mass transport properties were evaluated during a 4-day test run. This instrument allows the experimental characterization of metamorphism of snow undergoing structural changes with time.
Magnetic method for stimulating transport in fluids
Martin, James E.; Solis, Kyle J.
2016-10-18
A method for producing mass and heat transport in fluids, wherein the method does not rely on conventional convection, that is, it does not require gravity, a thermal gradient, or a magnetic field gradient. This method gives rise to a unique class of vigorous, field-controllable flow patterns termed advection lattices. The advection lattices can be used to transport heat and/or mass in any desired direction using only magnetic fields.
Romero-González, J; Walton, J C; Peralta-Videa, J R; Rodríguez, E; Romero, J; Gardea-Torresdey, J L
2009-01-15
The biosorption of Cr(III) onto packed columns of Agave lechuguilla was analyzed using an advective-dispersive (AD) model and its analytical solution. Characteristic parameters such as axial dispersion coefficients, retardation factors, and distribution coefficients were predicted as functions of inlet ion metal concentration, time, flow rate, bed density, cross-sectional column area, and bed length. The root-mean-square-error (RMSE) values 0.122, 0.232, and 0.285 corresponding to the flow rates of 1, 2, and 3 (10(-3))dm3min(-1), respectively, indicated that the AD model provides an excellent approximation of the simulation of lumped breakthrough curves for the adsorption of Cr(III) by lechuguilla biomass. Therefore, the model can be used for design purposes to predict the effect of varying operational conditions. PMID:18462882
Thermal /Soret/ diffusion effects on interfacial mass transport rates
NASA Technical Reports Server (NTRS)
Rosner, D. E.
1980-01-01
It is shown that thermal (Soret) diffusion significantly alters convective mass transport rates and important transition temperatures in highly nonisothermal flow systems involving the transport of 'heavy' species (vapors or particles). Introduction of the Soret transport term is shown to result in mass transfer effects similar to those of 'suction' and a homogeneous chemical 'sink'. It is pointed out that this analogy provides a simple method of correlating and predicting thermal diffusion effects in the abovementioned systems.
NASA Astrophysics Data System (ADS)
Moltyaner, G. L.
1993-10-01
In situ sensing technology, used in a series of natural-gradient tracer tests at the Chalk River Laboratories in Ontario, leads to the introduction of a conceptually new approach to the study of groundwater motion in porous media. As opposed to the conventional approach, based on the consideration of a fictitious fluid continuum with fluid properties distributed over both voids and solids, in the new approach the actual groundwater motion in the void space of a porous medium is considered and described at the local scale by the statistical characterization of the propagation of gamma-radiation energy associated with the moving water as a tracer. The essential feature of the new approach is that the mean free path of a gamma-energy photon instead of the porosity is used as a scaling factor in transferring information associated with pore-scale fluid motion to the local scale. This scaling factor is employed for reintroducing the familiar particle model of fluid motion but at the local scale. It is shown that when the local-scale dispersion is neglected, the evolution of local-scale fluid particles making up the tracer plume can be described by the advection equation; its equation of characteristics describes trajectories of local-scale particles. A simple analytical solution to the advection equation is then used to produce three-dimensional images of the spatial distribution of local-scale particles observed in the Twin Lake test. It is also shown that the spatial averaging procedure with regard to the weighting function for a spherical averaging volume of one mean free path radius may be used to introduce the three-dimensional field of local-scale concentration. The averaging procedure is then used to illustrate that the concept of the three-dimensional field of plume-scale concentration does not make physical sense and only the one-dimensional plume-scale concentration field may be introduced in shallow aquifers.
Ramanan, B.; Holmes, W. M.; Sloan, W. T.; Phoenix, V. R.
2010-01-01
Molecules become readily visible by magnetic resonance imaging (MRI) when labeled with a paramagnetic tag. Consequently, MRI can be used to image their transport through porous media. In this study, we demonstrated that this method could be applied to image mass transport processes in biofilms. The transport of a complex of gadolinium and diethylenetriamine pentaacetic acid (Gd-DTPA), a commercially available paramagnetic molecule, was imaged both in agar (as a homogeneous test system) and in a phototrophic biofilm. The images collected were T1 weighted, where T1 is an MRI property of the biofilm and is dependent on Gd-DTPA concentration. A calibration protocol was applied to convert T1 parameter maps into concentration maps, thus revealing the spatially resolved concentrations of this tracer at different time intervals. Comparing the data obtained from the agar experiment with data from a one-dimensional diffusion model revealed that transport of Gd-DTPA in agar was purely via diffusion, with a diffusion coefficient of 7.2 × 10−10 m2 s−1. In contrast, comparison of data from the phototrophic biofilm experiment with data from a two-dimensional diffusion model revealed that transport of Gd-DTPA inside the biofilm was by both diffusion and advection, equivalent to a diffusion coefficient of 1.04 × 10−9 m2 s−1. This technology can be used to further explore mass transport processes in biofilms, either by using the wide range of commercially available paramagnetically tagged molecules and nanoparticles or by using bespoke tagged molecules. PMID:20435773
Wave-induced mass transport affects daily Escherichia coli fluctuations in nearshore water
Ge, Zhongfu; Whitman, Richard L.; Nevers, Meredith B.; Phanikumar, Mantha S.
2012-01-01
Characterization of diel variability of fecal indicator bacteria concentration in nearshore waters is of particular importance for development of water sampling standards and protection of public health. Significant nighttime increase in Escherichia coli (E. coli) concentration in beach water, previously observed at marine sites, has also been identified in summer 2000 from fixed locations in waist- and knee-deep waters at Chicago 63rd Street Beach, an embayed, tideless, freshwater beach with low currents at night (approximately 0.015 m s–1). A theoretical model using wave-induced mass transport velocity for advection was developed to assess the contribution of surface waves to the observed nighttime E. coli replenishment in the nearshore water. Using average wave conditions for the summer season of year 2000, the model predicted an amount of E. coli transported from water of intermediate depth, where sediment resuspension occurred intermittently, that would be sufficient to have elevated E. coli concentration in the surf and swash zones as observed. The nighttime replenishment of E. coli in the surf and swash zones revealed here is an important phase in the cycle of diel variations of E. coli concentration in nearshore water. According to previous findings in Ge et al. (Environ. Sci. Technol. 2010, 44, 6731–6737), enhanced current circulation in the embayment during the day tends to displace and deposit material offshore, which partially sets up the system by the early evening for a new period of nighttime onshore movement. This wave-induced mass transport effect, although facilitating a significant base supply of material shoreward, can be perturbed or significantly influenced by high currents (orders of magnitude larger than a typical wave-induced mass transport velocity), current-induced turbulence, and tidal forcing.
Mass-conservative reconstruction of Galerkin velocity fields for transport simulations
NASA Astrophysics Data System (ADS)
Scudeler, C.; Putti, M.; Paniconi, C.
2016-08-01
Accurate calculation of mass-conservative velocity fields from numerical solutions of Richards' equation is central to reliable surface-subsurface flow and transport modeling, for example in long-term tracer simulations to determine catchment residence time distributions. In this study we assess the performance of a local Larson-Niklasson (LN) post-processing procedure for reconstructing mass-conservative velocities from a linear (P1) Galerkin finite element solution of Richards' equation. This approach, originally proposed for a-posteriori error estimation, modifies the standard finite element velocities by imposing local conservation on element patches. The resulting reconstructed flow field is characterized by continuous fluxes on element edges that can be efficiently used to drive a second order finite volume advective transport model. Through a series of tests of increasing complexity that compare results from the LN scheme to those using velocity fields derived directly from the P1 Galerkin solution, we show that a locally mass-conservative velocity field is necessary to obtain accurate transport results. We also show that the accuracy of the LN reconstruction procedure is comparable to that of the inherently conservative mixed finite element approach, taken as a reference solution, but that the LN scheme has much lower computational costs. The numerical tests examine steady and unsteady, saturated and variably saturated, and homogeneous and heterogeneous cases along with initial and boundary conditions that include dry soil infiltration, alternating solute and water injection, and seepage face outflow. Typical problems that arise with velocities derived from P1 Galerkin solutions include outgoing solute flux from no-flow boundaries, solute entrapment in zones of low hydraulic conductivity, and occurrences of anomalous sources and sinks. In addition to inducing significant mass balance errors, such manifestations often lead to oscillations in concentration
LAYER DEPENDENT ADVECTION IN CMAQ
The advection methods used in CMAQ require that the Courant-Friedrichs-Lewy (CFL) condition be satisfied for numerical stability and accuracy. In CMAQ prior to version 4.3, the ADVSTEP algorithm established CFL-safe synchronization and advection timesteps that were uniform throu...
Pediatric and neonatal interfacility transport medicine after mass casualty incidents.
Lowe, Calvin G
2009-08-01
Pediatric and neonatal interfacility transport medicine is a relatively young but a rapidly evolving specialty. Transport teams are essential for the safe interfacility movement of critically ill patients. A mass casualty incident (MCI) can present major challenges for a critical care transport team. This article will examine the capabilities and limitations of pediatric and neonatal critical care transport teams. The predicaments brought about by Hurricane Katrina that hindered the evacuation of pediatric and neonatal patients out of ravaged hospitals are also reviewed. From these experiences, recommendations to improve the efficiency and efficacy of interfacility transport of pediatric patients will be presented.
Mass transport by mode-2 internal solitary-like waves
NASA Astrophysics Data System (ADS)
Deepwell, David; Stastna, Marek
2016-05-01
We present the first three-dimensional numerical simulations of the mass transport capabilities of mode-2 waves formed by a lock-release mechanism with both single and double pycnocline stratifications. Single pycnoclines and double pycnoclines with a small spacing between the pycnocline centres were found to exhibit large Lee instabilities which formed during the collapse of the intermediate density region. These instabilities led to the generation of vorticity dipoles across the mid-depth, and thereby contributed to the reduction in the mass transported by the wave. A double pycnocline with a separation of approximately 12% of the depth between the two pycnocline centres was found to transport a passive tracer optimally for the longest time-period. Increasing Schmidt number correlated with increasing mass transport, while decreasing the tracer diffusivity led to increasing mass transport, but only when a trapped core existed. Contrasted two-dimensional simulations reveal that in certain cases, most noticeably the optimal transport case, the mass transport is significantly different from the corresponding three-dimensional simulation.
Mass Transportation Operators' Beliefs about Visual Impairment.
ERIC Educational Resources Information Center
Almon, Pamela A.
2001-01-01
A study investigated 171 mass transit operators' beliefs about blindness and the factors that may influence their beliefs. There were statistically significant differences among transit operators' beliefs on the basis of the operators' ethnicity. White participants had significantly fewer irrational beliefs about blindness than Hispanic and…
Pangolin v1.0, a conservative 2-D advection model towards large-scale parallel calculation
NASA Astrophysics Data System (ADS)
Praga, A.; Cariolle, D.; Giraud, L.
2015-02-01
To exploit the possibilities of parallel computers, we designed a large-scale bidimensional atmospheric advection model named Pangolin. As the basis for a future chemistry-transport model, a finite-volume approach for advection was chosen to ensure mass preservation and to ease parallelization. To overcome the pole restriction on time steps for a regular latitude-longitude grid, Pangolin uses a quasi-area-preserving reduced latitude-longitude grid. The features of the regular grid are exploited to reduce the memory footprint and enable effective parallel performances. In addition, a custom domain decomposition algorithm is presented. To assess the validity of the advection scheme, its results are compared with state-of-the-art models on algebraic test cases. Finally, parallel performances are shown in terms of strong scaling and confirm the efficient scalability up to a few hundred cores.
Parker, Jack C; Kim, Ungtae
2015-11-01
The mono-continuum advection-dispersion equation (mADE) is commonly regarded as unsuitable for application to media that exhibit rapid breakthrough and extended tailing associated with diffusion between high and low permeability regions. This paper demonstrates that the mADE can be successfully used to model such conditions if certain issues are addressed. First, since hydrodynamic dispersion, unlike molecular diffusion, cannot occur upstream of the contaminant source, models must be formulated to prevent "back-dispersion." Second, large variations in aquifer permeability will result in differences between volume-weighted average concentration (resident concentration) and flow-weighted average concentration (flux concentration). Water samples taken from wells may be regarded as flux concentrations, while soil samples may be analyzed to determine resident concentrations. While the mADE is usually derived in terms of resident concentration, it is known that a mADE of the same mathematical form may be written in terms of flux concentration. However, when solving the latter, the mathematical transformation of a flux boundary condition applied to the resident mADE becomes a concentration type boundary condition for the flux mADE. Initial conditions must also be consistent with the form of the mADE that is to be solved. Thus, careful attention must be given to the type of concentration data that is available, whether resident or flux concentrations are to be simulated, and to boundary and initial conditions. We present 3-D analytical solutions for resident and flux concentrations, discuss methods of solving numerical models to obtain resident and flux concentrations, and compare results for hypothetical problems. We also present an upscaling method for computing "effective" dispersivities and other mADE model parameters in terms of physically meaningful parameters in a diffusion-limited mobile-immobile model. Application of the latter to previously published studies of
Parker, Jack C; Kim, Ungtae
2015-11-01
The mono-continuum advection-dispersion equation (mADE) is commonly regarded as unsuitable for application to media that exhibit rapid breakthrough and extended tailing associated with diffusion between high and low permeability regions. This paper demonstrates that the mADE can be successfully used to model such conditions if certain issues are addressed. First, since hydrodynamic dispersion, unlike molecular diffusion, cannot occur upstream of the contaminant source, models must be formulated to prevent "back-dispersion." Second, large variations in aquifer permeability will result in differences between volume-weighted average concentration (resident concentration) and flow-weighted average concentration (flux concentration). Water samples taken from wells may be regarded as flux concentrations, while soil samples may be analyzed to determine resident concentrations. While the mADE is usually derived in terms of resident concentration, it is known that a mADE of the same mathematical form may be written in terms of flux concentration. However, when solving the latter, the mathematical transformation of a flux boundary condition applied to the resident mADE becomes a concentration type boundary condition for the flux mADE. Initial conditions must also be consistent with the form of the mADE that is to be solved. Thus, careful attention must be given to the type of concentration data that is available, whether resident or flux concentrations are to be simulated, and to boundary and initial conditions. We present 3-D analytical solutions for resident and flux concentrations, discuss methods of solving numerical models to obtain resident and flux concentrations, and compare results for hypothetical problems. We also present an upscaling method for computing "effective" dispersivities and other mADE model parameters in terms of physically meaningful parameters in a diffusion-limited mobile-immobile model. Application of the latter to previously published studies of
Advection around ventilated U-shaped burrows: A model study
NASA Astrophysics Data System (ADS)
Brand, Andreas; Lewandowski, JöRg; Hamann, Enrico; Nützmann, Gunnar
2013-05-01
Advective transport in the porous matrix of sediments surrounding burrows formed by fauna such as Chironomus plumosus has been generally neglected. A positron emission tomography study recently revealed that the pumping activity of the midge larvae can indeed induce fluid flow in the sediment. We present a numerical model study which explores the conditions at which advective transport in the sediment becomes relevant. A 0.15 m deep U-shaped burrow with a diameter of 0.002 m within the sediment was represented in a 3-D domain. Fluid flow in the burrow was calculated using the Navier-Stokes equation for incompressible laminar flow in the burrow, and flow in the sediment was described by Darcy's law. Nonreactive and reactive transport scenarios were simulated considering diffusion and advection. The pumping activity of the model larva results in considerable advective flow in the sediment at reasonable high permeabilities with flow velocities of up to 7.0 × 10-6 m s-1 close to the larva for a permeability of 3 × 10-12 m2. At permeabilities below 7 × 10-13 m2 advection is negligible compared to diffusion. Reactive transport simulations using first-order kinetics for oxygen revealed that advective flux into the sediment downstream of the pumping larva enhances sedimentary uptake, while the advective flux into the burrow upstream of the larvae inhibits diffusive sedimentary uptake. Despite the fact that both effects cancel each other with respect to total solute uptake, the advection-induced asymmetry in concentration distribution can lead to a heterogeneous solute and redox distribution in the sediment relevant to complex reaction networks.
Space Geodesy Monitoring Mass Transport in Global Geophysical Fluids
NASA Technical Reports Server (NTRS)
Chao, Benjamin F.
2004-01-01
Mass transports occurring in the atmosphere-hydrosphere-cryosphere-solid Earth-core system (the 'global geophysical fluids') are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, oceanic and solid tides, hydrological water and idsnow redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. The temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have proven to be an effective tool in monitorihg certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. Considerable advances have been made in recent years in observing and understanding of these geodynamic effects. This paper will use several prominent examples to illustrate the triumphs in research over the past years under a 'Moore's law' in space geodesy. New space missions and projects promise to further advance our knowledge about the global mass transports. The latter contributes to our understanding of the geophysical processes that produce and regulate the mass transports, as well as of the solid Earth's response to such changes in terms of Earth's mechanical properties.
Synoptic patterns and air mass transport during ozone episodes in northwestern Iberia.
Saavedra, S; Rodríguez, A; Taboada, J J; Souto, J A; Casares, J J
2012-12-15
High levels of ozone are frequently measured at the Galicia (NW Iberian Peninsula) air quality monitoring stations from March to October. However, there have been very few studies on surface ozone in the northwestern Iberian Peninsula, most likely because the climate of this region is not favourable to photochemical ozone generation. The occurrence of these episodes may be related to either local-scale photochemical pollution or regional-scale transport from other polluted regions. In addition, high ozone episodes usually are developed under specific synoptic conditions. The main purposes of this study are to characterise the atmospheric conditions that lead to the ozone episodes in this region and to identify possible advection paths of ozone and precursors. A surface hourly ozone dataset (2002-2007) measured at rural sites in Galicia was analysed to identify high ozone episodes together with their associated synoptic patterns using a subjective classification with 23 different synoptic types. The synoptic weather patterns revealed that most of the episodes occur with high surface pressures centred over the British Isles and/or Central Europe while a high-altitude anticyclonic ridge crosses the Peninsula from North Africa, causing easterly or southeasterly winds. This analysis was completed with 3-day backward air mass trajectories obtained with HYSPLIT to assess the contribution of long-range transport, resulting in the following main routes: Mediterranean-Peninsular, South Atlantic-Portuguese, local and French-Cantabric.
Mass transport limitation in implantable defibrillator batteries
NASA Astrophysics Data System (ADS)
Schmidt, C.; Tam, G.; Scott, E.; Norton, J.; Chen, K.
Using cells with lithium reference electrodes, the power-limiting behavior in the lithium-SVO cell was shown to be due to a rapid voltage transition at the anode. A novel test cell was developed to explore the influence of current density, bulk LiAsF 6 concentration, separator type and separator proximity to the anode on the time to onset ( τ) of the anode polarization. The results were found to follow a relationship, iτ1/2∝ Cbulk, consistent with the Sand equation. This relationship also predicts that the critical concentration of LiAsF 6, at which onset of the anode polarization occurs, is near the solubility limit of LiAsF 6 in our system (around 3.5-4.0 M). This general phenomenon was found to be quantitatively similar for two dissimilar separator types, and the anode polarization could also be induced in the absence of separator at high concentration and current density. However, it appears that τ decreases with closer proximity of the separator to the anode surface (i.e. cell stack pressure), suggesting that the effect of separator is to inhibit convective transport to and from the Li surface.
NASA Technical Reports Server (NTRS)
Kritz, Mark A.; Le Roulley, Jean-Claude; Danielsen, Edwin F.
1990-01-01
A series of upper tropospheric radon concentration measurements made over the eastern Pacific and west coast of the U.S. during the summers of 1983 and 1984 has revealed the occurrence of unexpectedly high radon concentrations for 9 of the 61 measurements. A frequency distribution plot of the set of 61 observations shows a distinct bimodal distribution, with approximately 2/5 of the observations falling close to 1 pCi/SCM, and 3/5 falling in a high concentration mode centered at about 11 pCi/SCM. Trajectory and synoptic analyses for two of the flights on which such high radon concentrations were observed indicate that this radon-rich air originated in the Asian boundary layer, ascended in cumulus updrafts, and was carried eastward in the fast moving air on the anticyclonic side of the upper tropospheric jet. The results suggest that the combination of rapid vertical transport from the surface boundary layer to the upper troposphere, followed by rapid horizontal transport eastward represents an efficient mode of long-transport for other, chemically reactive atmospheric trace constituents.
Frontiers in Cancer Nanomedicine: Directing Mass Transport through Biological Barriers
Ferrari, Mauro
2010-01-01
The physics of mass transport within body compartments and across biological barriers differentiates cancers from healthy tissues. Variants of nanoparticles can be manufactured in combinatorially large sets, varying only one transport-affecting design parameter at a time. Nanoparticles can also be used as building blocks for systems that perform sequences of coordinated actions, in accordance to a prescribed logic. These are referred to as Logic-Embedded Vectors “(LEV)” in the following. Nanoparticles and LEVs are ideal probes for the determination of mass transport laws in tumors, acting as imaging contrast enhancers, and can be employed for the lesion-selective delivery of therapy. Their size, shape, density and surface chemistry dominate convective transport in the blood stream, margination, cell adhesion, selective cellular uptake, as well as sub-cellular trafficking and localization. As argued here, the understanding of transport differentials in cancer, termed ‘transport oncophysics’ unveils a new promising frontier in oncology: the development of lesion-specific delivery particulates that exploit mass transport differentials to deploy treatment of greater efficacy and reduced side effects. PMID:20079548
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Grimm, S. A.; Schneebeli, M.; Steinfeld, A.
2014-06-01
An instrumented sample holder was developed for time-lapse micro-tomography of snow samples to enable in-situ nondestructive spatial and temporal measurements under controlled advective airflows, temperature gradients, and air humidities. The design was aided by computational fluid dynamics simulations to evaluate the airflow uniformity across the snow sample. Morphological and mass transport properties were evaluated during a 4 day test run. This instrument allows the experimental characterization of metamorphism of snow undergoing structural changes with time.
Advection and diffusion in shoreline change prediction
NASA Astrophysics Data System (ADS)
Anderson, T. R.; Frazer, L. N.
2010-12-01
We added longshore advection and diffusion to the simple cross-shore rate calculation method, as used widely by the USGS and others, to model historic shorelines and to predict future shoreline positions; and applied this to Hawaiian Island beach data. Aerial photographs, sporadically taken throughout the past century, yield usable, albeit limited, historic shoreline data. These photographs provide excellent spatial coverage, but poor temporal resolution, of the shoreline. Due to the sparse historic shoreline data, and the many natural and anthropogenic events influencing coastlines, we constructed a simplistic shoreline change model that can identify long-term behavior of a beach. Our new, two-dimensional model combines the simple rate method to accommodate for cross-shore sediment transport with the classic Pelnard-Considère model for diffusion, as well as a longshore advection speed term. Inverse methods identify cross-shore rate, longshore advection speed, and longshore diffusivity down a sandy coastline. A spatial averaging technique then identifies shoreline segments where one parameter can reasonably account for the cross-shore and longshore transport rates in that area. This produces model results with spatial resolution more appropriate to the temporal spacing of the data. Because changes in historic data can be accounted for by varying degrees of cross-shore and longshore sediment transport - for example, beach erosion can equally be explained by sand moving either off-shore or laterally - we tested several different model scenarios on the data: allowing only cross-shore sediment movement, only longshore movement, and a combination of the two. We used statistical information criteria to determine both the optimal spatial resolution and best-fitting scenario. Finally, we employed a voting method predicting the relaxed shoreline position over time.
Mass transportation mechanism in electric-biased carbon nanotubes.
Zhao, Jiong; Huang, Jia-Qi; Wei, Fei; Zhu, Jing
2010-11-10
The mass transportation mechanism in electric-biased carbon nanotubes (CNTs) is investigated experimentally. Except for the widely accepted electromigration mechanism, we find out the thermal effect can also induce the mass transportation in the form of thermomigration or thermal evaporation. Moreover, the convincing in situ transmission electron microscope experiment results show the thermal gradient force overrides the electromigration force in most conditions, according to specific parameters of the CNTs and "cargos". A full analysis on the thermal gradient force and electromigration force imposed on the cargos is given, thus our experimental results are well explained and understood.
Mass and Momentum Turbulent Transport Experiments with Confined Coaxial Jets
NASA Technical Reports Server (NTRS)
Johnson, B. V.; Bennett, J. C.
1981-01-01
Downstream mixing of coaxial jets discharging in an expanded duct was studied to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the propulsion community for combustor flow modeling. Flow visualization studies showed four major shear regions occurring; a wake region immediately downstream of the inlet jet inlet duct; a shear region further downstream between the inner and annular jets; a recirculation zone; and a reattachment zone. A combination of turbulent momentum transport rate and two velocity component data were obtained from simultaneous measurements with a two color laser velocimeter (LV) system. Axial, radial and azimuthal velocities and turbulent momentum transport rate measurements in the r-z and r-theta planes were used to determine the mean value, second central moment (or rms fluctuation from mean), skewness and kurtosis for each data set probability density function (p.d.f.). A combination of turbulent mass transport rate, concentration and velocity data were obtained system. Velocity and mass transport in all three directions as well as concentration distributions were used to obtain the mean, second central moments, skewness and kurtosis for each p.d.f. These LV/LIF measurements also exposed the existence of a large region of countergradient turbulent axial mass transport in the region where the annular jet fluid was accelerating the inner jet fluid.
A deterministic Lagrangian particle separation-based method for advective-diffusion problems
NASA Astrophysics Data System (ADS)
Wong, Ken T. M.; Lee, Joseph H. W.; Choi, K. W.
2008-12-01
A simple and robust Lagrangian particle scheme is proposed to solve the advective-diffusion transport problem. The scheme is based on relative diffusion concepts and simulates diffusion by regulating particle separation. This new approach generates a deterministic result and requires far less number of particles than the random walk method. For the advection process, particles are simply moved according to their velocity. The general scheme is mass conservative and is free from numerical diffusion. It can be applied to a wide variety of advective-diffusion problems, but is particularly suited for ecological and water quality modelling when definition of particle attributes (e.g., cell status for modelling algal blooms or red tides) is a necessity. The basic derivation, numerical stability and practical implementation of the NEighborhood Separation Technique (NEST) are presented. The accuracy of the method is demonstrated through a series of test cases which embrace realistic features of coastal environmental transport problems. Two field application examples on the tidal flushing of a fish farm and the dynamics of vertically migrating marine algae are also presented.
Mass transport mechanism in porous fuel cell electrodes
NASA Technical Reports Server (NTRS)
Jonsson, I.; Lindholm, I.
1969-01-01
Results of experiments on hydrogen-oxygen fuel cells show that higher current densities are obtained with cell anodes having a 100 micron thin active layer of porous nickel containing silver electrocatalyst. Increase in current density is attributed to a convective mass transport mechanism.
Mass Transport Through Carbon Nanotube-Polystyrene Bundles
NASA Astrophysics Data System (ADS)
Lin, Rongzhou; Tran, Tuan
2016-05-01
Carbon nanotubes have been widely used as test channels to study nanofluidic transport, which has been found to have distinctive properties compared to transport of fluids in macroscopic channels. A long-standing challenge in the study of mass transport through carbon nanotubes (CNTs) is the determination of flow enhancement. Various experimental investigations have been conducted to measure the flow rate through CNTs, mainly based on either vertically aligned CNT membranes or individual CNTs. Here, we proposed an alternative approach that can be used to quantify the mass transport through CNTs. This is a simple method relying on the use of carbon nanotube-polystyrene bundles, which are made of CNTs pulled out from a vertically aligned CNT array and glued together by polystyrene. We experimentally showed by using fluorescent tagging that the composite bundles allowed measureable and selective mass transport through CNTs. This type of composite bundle may be useful in various CNT research areas as they are simple to fabricate, less likely to form macroscopic cracks, and offer a high density of CNT pores while maintaining the aligned morphology of CNTs.
Optimal Mass Transport for Shape Matching and Comparison
Su, Zhengyu; Wang, Yalin; Shi, Rui; Zeng, Wei; Sun, Jian; Luo, Feng; Gu, Xianfeng
2015-01-01
Surface based 3D shape analysis plays a fundamental role in computer vision and medical imaging. This work proposes to use optimal mass transport map for shape matching and comparison, focusing on two important applications including surface registration and shape space. The computation of the optimal mass transport map is based on Monge-Brenier theory, in comparison to the conventional method based on Monge-Kantorovich theory, this method significantly improves the efficiency by reducing computational complexity from O(n2) to O(n). For surface registration problem, one commonly used approach is to use conformal map to convert the shapes into some canonical space. Although conformal mappings have small angle distortions, they may introduce large area distortions which are likely to cause numerical instability thus resulting failures of shape analysis. This work proposes to compose the conformal map with the optimal mass transport map to get the unique area-preserving map, which is intrinsic to the Riemannian metric, unique, and diffeomorphic. For shape space study, this work introduces a novel Riemannian framework, Conformal Wasserstein Shape Space, by combing conformal geometry and optimal mass transport theory. In our work, all metric surfaces with the disk topology are mapped to the unit planar disk by a conformal mapping, which pushes the area element on the surface to a probability measure on the disk. The optimal mass transport provides a map from the shape space of all topological disks with metrics to the Wasserstein space of the disk and the pullback Wasserstein metric equips the shape space with a Riemannian metric. We validate our work by numerous experiments and comparisons with prior approaches and the experimental results demonstrate the efficiency and efficacy of our proposed approach. PMID:26440265
Mass transport theory for the Toda lattices, dispersive and dissipative
NASA Astrophysics Data System (ADS)
Horii, Zene
2005-05-01
To establish mass transport theory on nonlinear lattices, we formulate the Korteweg-deVries (KdV) equation and the Burgers equation using the flow variable representation so as to facilitate comparison with the Boltzmann equation and with the Cahn-Hilliard equation in classical statistical mechanics. We also study Toda lattice microdynamics using the Flaschka representation, and compare with the Liouville equation. Like the linear diffusion equation, the Boltzmann equation and the Liouville equation are to be solved for a distribution function, which is intrinsically probabilistic. Transport theory in linear systems is governed by the isotropic motions of the kinetic equations. In contrast, the KdV perturbation equation derived from the Toda lattice microdynamics expresses hydrodynamic mass transport. The KdV equation in hydrodynamics and the Burgers equation in thermodynamics do not involve a probability distribution function. The nonlinear lattices do not retain isotropy of the mass transport equations. In consequence, it is proposed that in the presence of hydrodynamic flows to the left, KdV wave propagation proceeds to the right. This basic property of the KdV system is extended to thermodynamics in the Burgers system. These features arise because linear systems are driven towards an equilibrium by molecular collisions, whereas the inhomogeneities of the nonlinear lattices are generated by the potential energy of interaction. Diffusion as expressed by the Burgers equation is governed not only by a chemical potential, but also by the Toda lattice potential energy.
Concentration polarization, surface currents, and bulk advection in a microchannel
NASA Astrophysics Data System (ADS)
Nielsen, Christoffer P.; Bruus, Henrik
2014-10-01
We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behavior of the system. A remarkable outcome of the investigations is the discovery of strong couplings between bulk advection and the surface current; without a surface current, bulk advection is strongly suppressed. The numerical simulations are supplemented by analytical models valid in the long channel limit as well as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction.
Concentration polarization, surface currents, and bulk advection in a microchannel.
Nielsen, Christoffer P; Bruus, Henrik
2014-10-01
We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behavior of the system. A remarkable outcome of the investigations is the discovery of strong couplings between bulk advection and the surface current; without a surface current, bulk advection is strongly suppressed. The numerical simulations are supplemented by analytical models valid in the long channel limit as well as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction. PMID:25375606
Shipley, Rebecca J; Waters, Sarah L
2012-12-01
A model for fluid and mass transport in a single module of a tissue engineering hollow fibre bioreactor (HFB) is developed. Cells are seeded in alginate throughout the extra-capillary space (ECS), and fluid is pumped through a central lumen to feed the cells and remove waste products. Fluid transport is described using Navier-Stokes or Darcy equations as appropriate; this is overlaid with models of mass transport in the form of advection-diffusion-reaction equations that describe the distribution and uptake/production of nutrients/waste products. The small aspect ratio of a module is exploited and the option of opening an ECS port is explored. By proceeding analytically, operating equations are determined that enable a tissue engineer to prescribe the geometry and operation of the HFB by ensuring the nutrient and waste product concentrations are consistent with a functional cell population. Finally, results for chondrocyte and cardiomyocyte cell populations are presented, typifying two extremes of oxygen uptake rates.
The role of mass transport in protein crystallization.
García-Ruiz, Juan Manuel; Otálora, Fermín; García-Caballero, Alfonso
2016-02-01
Mass transport takes place within the mesoscopic to macroscopic scale range and plays a key role in crystal growth that may affect the result of the crystallization experiment. The influence of mass transport is different depending on the crystallization technique employed, essentially because each technique reaches supersaturation in its own unique way. In the case of batch experiments, there are some complex phenomena that take place at the interface between solutions upon mixing. These transport instabilities may drastically affect the reproducibility of crystallization experiments, and different outcomes may be obtained depending on whether or not the drop is homogenized. In diffusion experiments with aqueous solutions, evaporation leads to fascinating transport phenomena. When a drop starts to evaporate, there is an increase in concentration near the interface between the drop and the air until a nucleation event eventually takes place. Upon growth, the weight of the floating crystal overcomes the surface tension and the crystal falls to the bottom of the drop. The very growth of the crystal then triggers convective flow and inhomogeneities in supersaturation values in the drop owing to buoyancy of the lighter concentration-depleted solution surrounding the crystal. Finally, the counter-diffusion technique works if, and only if, diffusive mass transport is assured. The technique relies on the propagation of a supersaturation wave that moves across the elongated protein chamber and is the result of the coupling of reaction (crystallization) and diffusion. The goal of this review is to convince protein crystal growers that in spite of the small volume of the typical protein crystallization setup, transport plays a key role in the crystal quality, size and phase in both screening and optimization experiments.
The role of mass transport in protein crystallization.
García-Ruiz, Juan Manuel; Otálora, Fermín; García-Caballero, Alfonso
2016-02-01
Mass transport takes place within the mesoscopic to macroscopic scale range and plays a key role in crystal growth that may affect the result of the crystallization experiment. The influence of mass transport is different depending on the crystallization technique employed, essentially because each technique reaches supersaturation in its own unique way. In the case of batch experiments, there are some complex phenomena that take place at the interface between solutions upon mixing. These transport instabilities may drastically affect the reproducibility of crystallization experiments, and different outcomes may be obtained depending on whether or not the drop is homogenized. In diffusion experiments with aqueous solutions, evaporation leads to fascinating transport phenomena. When a drop starts to evaporate, there is an increase in concentration near the interface between the drop and the air until a nucleation event eventually takes place. Upon growth, the weight of the floating crystal overcomes the surface tension and the crystal falls to the bottom of the drop. The very growth of the crystal then triggers convective flow and inhomogeneities in supersaturation values in the drop owing to buoyancy of the lighter concentration-depleted solution surrounding the crystal. Finally, the counter-diffusion technique works if, and only if, diffusive mass transport is assured. The technique relies on the propagation of a supersaturation wave that moves across the elongated protein chamber and is the result of the coupling of reaction (crystallization) and diffusion. The goal of this review is to convince protein crystal growers that in spite of the small volume of the typical protein crystallization setup, transport plays a key role in the crystal quality, size and phase in both screening and optimization experiments. PMID:26841759
The negative role of turbulence in estuarine mass transport
NASA Astrophysics Data System (ADS)
Nunes Vaz, Richard A.; Lennon, Geoffrey W.; de Silva Samarasinghe, Jayantha R.
1989-04-01
It is competition between the various stratifying and mixing influences which determines the character of stratification in an estuary. Borrowing concepts which have been successfully applied to the discussion of stratification in shelf seas, a quantitative basis for determining the potential energy associated with vertical structure in estuaries is derived. The formulation, along similar lines to that of Bowden (1981), provides a simple but comprehensive method of incorporating many relevant stratifying and mixing influences in a given problem, and is also shown to be capable of rearrangement into forms akin to the estuarine Richardson number which is commonly found in discussions of estuarine statification. The paper argues, based on a survey of the literature, that in wide, relatively well-mixed estuaries, the greatest longitudinal mass flux occurs at times when stratification is most developed, that is, when the turbulent kinetic energy in the water column is at a minimum. Modulation of turbulence, principally at various tidal frequencies, causes a pulsing of the mass flux in which the contribution of each pulse increases non-linearly as the period of the modulation increases. Some, possibly significant, changes to the state of stratification and to the corresponding mass transport may occur in association with slack water periods. However, the spring-neap cycle is proposed to have a far greater influence on stratification, mass transport and the long-term mass balance in estuaries, and recent observational studies lend support to this position.
Mass transfer model of nanoparticle-facilitated contaminant transport in saturated porous media.
Johari, Wan Lutfi Wan; Diamessis, Peter J; Lion, Leonard W
2010-02-01
A one-dimensional model has been evaluated for transport of hydrophobic contaminants, such as polycyclic aromatic hydrocarbon (PAH) compounds, facilitated by synthetic amphiphilic polyurethane (APU) nanoparticles in porous media. APU particles synthesized from poly(ethylene glycol)-modified urethane acrylate (PMUA) precursor chains have been shown to enhance the desorption rate and mobility of phenanthrene (PHEN) in soil. A reversible process governed by attachment and detachment rates was considered to describe the PMUA binding in soil in addition to PMUA transport through advection and dispersion. Ultimately, an irreversible second-order PMUA attachment rate in which the fractional soil saturation capacity with PMUA was a rate control was found to be adequate to describe the retention of PMUA particles. A gamma-distributed site model (GS) was used to describe the spectrum of physical/chemical constraints for PHEN transfer from solid to aqueous phases. Instantaneous equilibrium was assumed for PMUA-PHEN interactions. The coupled model for PMUA and PHEN behavior successfully described the enhanced elution profile of PHEN by PMUA. Sensitivity analysis was performed to analyze the significance of model parameters on model predictions. The adjustable parameter alpha in the gamma-distribution shapes the contaminant desorption distribution profile as well as elution and breakthrough curves. Model simulations show the use of PMUA can be also expected to improve the release rate of PHEN in soils with higher organic carbon content. The percentage removal of PHEN mass over time is shown to be influenced by the concentration of PMUA added and this information can be used to optimize cost and time require to accomplish a desired remediation goal. PMID:19406449
Mass transfer model of nanoparticle-facilitated contaminant transport in saturated porous media.
Johari, Wan Lutfi Wan; Diamessis, Peter J; Lion, Leonard W
2010-02-01
A one-dimensional model has been evaluated for transport of hydrophobic contaminants, such as polycyclic aromatic hydrocarbon (PAH) compounds, facilitated by synthetic amphiphilic polyurethane (APU) nanoparticles in porous media. APU particles synthesized from poly(ethylene glycol)-modified urethane acrylate (PMUA) precursor chains have been shown to enhance the desorption rate and mobility of phenanthrene (PHEN) in soil. A reversible process governed by attachment and detachment rates was considered to describe the PMUA binding in soil in addition to PMUA transport through advection and dispersion. Ultimately, an irreversible second-order PMUA attachment rate in which the fractional soil saturation capacity with PMUA was a rate control was found to be adequate to describe the retention of PMUA particles. A gamma-distributed site model (GS) was used to describe the spectrum of physical/chemical constraints for PHEN transfer from solid to aqueous phases. Instantaneous equilibrium was assumed for PMUA-PHEN interactions. The coupled model for PMUA and PHEN behavior successfully described the enhanced elution profile of PHEN by PMUA. Sensitivity analysis was performed to analyze the significance of model parameters on model predictions. The adjustable parameter alpha in the gamma-distribution shapes the contaminant desorption distribution profile as well as elution and breakthrough curves. Model simulations show the use of PMUA can be also expected to improve the release rate of PHEN in soils with higher organic carbon content. The percentage removal of PHEN mass over time is shown to be influenced by the concentration of PMUA added and this information can be used to optimize cost and time require to accomplish a desired remediation goal.
Coping with model uncertainty in data assimilation using optimal mass transport
NASA Astrophysics Data System (ADS)
Ning, L.; Carli, F. P.; Ebtehaj, M.; Foufoula-Georgiou, E.; Georgiou, T.
2013-12-01
Most data assimilation methods address the problem of optimally combining model predictions with observations in the presence of zero-mean Gaussian random errors. However, in many hydro-meteorological applications uncertainty in model parameters and/or model structure often result in systematic errors (bias). Examples include the prediction of precipitation or land surface fluxes at the wrong location and/or timing due to a drift in the model, unknown initial conditions, or non-additive error amplification. Existing bias-aware data assimilation methods require characterization of the bias in terms of a well-defined set of parameters or removal of bias, which is not always feasible. Here we present a new variational data assimilation framework to cope with model bias in a non-parametric fashion via an appropriate 'regularization' of the state evolution dynamics. In the context of weak-constraint 4D-VAR, our method can be seen as enforcing a minimum nonlinear distance (regularization or correction) in the evolution of the state so as to reconcile measurements with errors in the model dynamics. While a quadratic functional is typically sufficient to quantify errors in measurements, errors in state evolution is most naturally quantified by a transportation metric (Wasserstein metric) originating in the theory of Optimal Mass Transport (OMT). The proposed framework allows the use of additional regularization functionals, such as the L1-norm regularization of the state in an appropriately chosen domain, as recently introduced by the authors for states that exhibit sparsity and non-Gaussian priors, such as precipitation and soil moisture. We demonstrate the performance of the proposed method using as an example the 1-D and 2-D advection diffusion equation with systematic errors in the velocity and diffusivity parameters. Extension to real world data assimilation settings is currently under way.
Optimum periodicity of repeated contractile actions applied in mass transport
NASA Astrophysics Data System (ADS)
Ahn, Sungsook; Lee, Sang Joon
2015-01-01
Dynamically repeated periodic patterns are abundant in natural and artificial systems, such as tides, heart beats, stock prices, and the like. The characteristic repeatability and periodicity are expected to be optimized in effective system-specific functions. In this study, such optimum periodicity is experimentally evaluated in terms of effective mass transport using one-valve and multi-valve systems working in contractile fluid flows. A set of nanoscale gating functions is utilized, operating in nanocomposite networks through which permeates selectively pass under characteristic contractile actions. Optimized contractile periodicity exists for effective energy impartment to flow in a one-valve system. In the sequential contractile actions for a multi-valve system, synchronization with the fluid flow is critical for effective mass transport. This study provides fundamental understanding on the various repeated periodic patterns and dynamic repeatability occurring in nature and mechanical systems, which are useful for broad applications.
Optimum periodicity of repeated contractile actions applied in mass transport
Ahn, Sungsook; Lee, Sang Joon
2015-01-01
Dynamically repeated periodic patterns are abundant in natural and artificial systems, such as tides, heart beats, stock prices, and the like. The characteristic repeatability and periodicity are expected to be optimized in effective system-specific functions. In this study, such optimum periodicity is experimentally evaluated in terms of effective mass transport using one-valve and multi-valve systems working in contractile fluid flows. A set of nanoscale gating functions is utilized, operating in nanocomposite networks through which permeates selectively pass under characteristic contractile actions. Optimized contractile periodicity exists for effective energy impartment to flow in a one-valve system. In the sequential contractile actions for a multi-valve system, synchronization with the fluid flow is critical for effective mass transport. This study provides fundamental understanding on the various repeated periodic patterns and dynamic repeatability occurring in nature and mechanical systems, which are useful for broad applications. PMID:25622949
Mass transport in bedded salt and salt interbeds
Hwang, Y.; Pigford, T.H.; Chambre, P.L.; Lee, W.W.L.
1989-08-01
Salt is the proposed host rock for geologic repositories of nuclear waste in several nations because it is nearly dry and probably impermeable. Although experiments and experience at potential salt sites indicate that salt may contain brine, the low porosity, creep, and permeability of salt make it still a good choice for geologic isolation. In this paper we summarize several mass-transfer and transport analyses of salt repositories. The mathematical details are given in our technical reports.
Miocene mass-transport sediments, Troodos Massif, Cyprus
Lord, A.R.; Harrison, R.W.; BouDagher-Fadel, M.; Stone, B.D.; Varol, O.
2009-01-01
Sediment mass-transport layers of submarine origin on the northern and southern flanks of the Troodos ophiolitic massif are dated biostratigraphically as early Miocene and late Miocene, respectively and therefore represent different seismogenic events in the uplift and erosional history of the Troodos terrane. Analysis of such events has potential for documenting Miocene seismic and uplift events regionally in the context of changing stress field directions and plate vectors through time. ?? 2009 The Geologists' Association.
Membranes for nanometer-scale mass fast transport
Bakajin, Olgica; Holt, Jason; Noy, Aleksandr; Park, Hyung Gyu
2011-10-18
Nanoporous membranes comprising single walled, double walled, and multiwalled carbon nanotubes embedded in a matrix material were fabricated for fluid mechanics and mass transfer studies on the nanometer scale and commercial applications. Average pore size can be 2 nm to 20 nm, or seven nm or less, or two nanometers or less. The membrane can be free of large voids spanning the membrane such that transport of material such as gas or liquid occurs exclusively through the tubes. Fast fluid, vapor, and liquid transport are observed. Versatile micromachining methods can be used for membrane fabrication. A single chip can comprise multiple membranes. These membranes are a robust platform for the study of confined molecular transport, with applications in liquid and gas separations and chemical sensing including desalination, dialysis, and fabric formation.
Vortical ciliary flows actively enhance mass transport in reef corals.
Shapiro, Orr H; Fernandez, Vicente I; Garren, Melissa; Guasto, Jeffrey S; Debaillon-Vesque, François P; Kramarsky-Winter, Esti; Vardi, Assaf; Stocker, Roman
2014-09-16
The exchange of nutrients and dissolved gasses between corals and their environment is a critical determinant of the growth of coral colonies and the productivity of coral reefs. To date, this exchange has been assumed to be limited by molecular diffusion through an unstirred boundary layer extending 1-2 mm from the coral surface, with corals relying solely on external flow to overcome this limitation. Here, we present direct microscopic evidence that, instead, corals can actively enhance mass transport through strong vortical flows driven by motile epidermal cilia covering their entire surface. Ciliary beating produces quasi-steady arrays of counterrotating vortices that vigorously stir a layer of water extending up to 2 mm from the coral surface. We show that, under low ambient flow velocities, these vortices, rather than molecular diffusion, control the exchange of nutrients and oxygen between the coral and its environment, enhancing mass transfer rates by up to 400%. This ability of corals to stir their boundary layer changes the way that we perceive the microenvironment of coral surfaces, revealing an active mechanism complementing the passive enhancement of transport by ambient flow. These findings extend our understanding of mass transport processes in reef corals and may shed new light on the evolutionary success of corals and coral reefs.
Vortical ciliary flows actively enhance mass transport in reef corals
Shapiro, Orr H.; Fernandez, Vicente I.; Garren, Melissa; Guasto, Jeffrey S.; Debaillon-Vesque, François P.; Kramarsky-Winter, Esti; Vardi, Assaf; Stocker, Roman
2014-01-01
The exchange of nutrients and dissolved gasses between corals and their environment is a critical determinant of the growth of coral colonies and the productivity of coral reefs. To date, this exchange has been assumed to be limited by molecular diffusion through an unstirred boundary layer extending 1–2 mm from the coral surface, with corals relying solely on external flow to overcome this limitation. Here, we present direct microscopic evidence that, instead, corals can actively enhance mass transport through strong vortical flows driven by motile epidermal cilia covering their entire surface. Ciliary beating produces quasi-steady arrays of counterrotating vortices that vigorously stir a layer of water extending up to 2 mm from the coral surface. We show that, under low ambient flow velocities, these vortices, rather than molecular diffusion, control the exchange of nutrients and oxygen between the coral and its environment, enhancing mass transfer rates by up to 400%. This ability of corals to stir their boundary layer changes the way that we perceive the microenvironment of coral surfaces, revealing an active mechanism complementing the passive enhancement of transport by ambient flow. These findings extend our understanding of mass transport processes in reef corals and may shed new light on the evolutionary success of corals and coral reefs. PMID:25192936
RWPV bioreactor mass transport: earth-based and in microgravity
NASA Technical Reports Server (NTRS)
Begley, Cynthia M.; Kleis, Stanley J.
2002-01-01
Mass transport and mixing of perfused scalar quantities in the NASA Rotating Wall Perfused Vessel bioreactor are studied using numerical models of the flow field and scalar concentration field. Operating conditions typical of both microgravity and ground-based cell cultures are studied to determine the expected vessel performance for both flight and ground-based control experiments. Results are presented for the transport of oxygen with cell densities and consumption rates typical of colon cancer cells cultured in the RWPV. The transport and mixing characteristics are first investigated with a step change in the perfusion inlet concentration by computing the time histories of the time to exceed 10% inlet concentration. The effects of a uniform cell utilization rate are then investigated with time histories of the outlet concentration, volume average concentration, and volume fraction starved. It is found that the operating conditions used in microgravity produce results that are quite different then those for ground-based conditions. Mixing times for microgravity conditions are significantly shorter than those for ground-based operation. Increasing the differential rotation rates (microgravity) increases the mixing and transport, while increasing the mean rotation rate (ground-based) suppresses both. Increasing perfusion rates enhances mass transport for both microgravity and ground-based cases, however, for the present range of operating conditions, above 5-10 cc/min there are diminishing returns as much of the inlet fluid is transported directly to the perfusion exit. The results show that exit concentration is not a good indicator of the concentration distributions in the vessel. In microgravity conditions, the NASA RWPV bioreactor with the viscous pump has been shown to provide an environment that is well mixed. Even when operated near the theoretical minimum perfusion rates, only a small fraction of the volume provides less than the required oxygen levels
RWPV bioreactor mass transport: earth-based and in microgravity.
Begley, Cynthia M; Kleis, Stanley J
2002-11-20
Mass transport and mixing of perfused scalar quantities in the NASA Rotating Wall Perfused Vessel bioreactor are studied using numerical models of the flow field and scalar concentration field. Operating conditions typical of both microgravity and ground-based cell cultures are studied to determine the expected vessel performance for both flight and ground-based control experiments. Results are presented for the transport of oxygen with cell densities and consumption rates typical of colon cancer cells cultured in the RWPV. The transport and mixing characteristics are first investigated with a step change in the perfusion inlet concentration by computing the time histories of the time to exceed 10% inlet concentration. The effects of a uniform cell utilization rate are then investigated with time histories of the outlet concentration, volume average concentration, and volume fraction starved. It is found that the operating conditions used in microgravity produce results that are quite different then those for ground-based conditions. Mixing times for microgravity conditions are significantly shorter than those for ground-based operation. Increasing the differential rotation rates (microgravity) increases the mixing and transport, while increasing the mean rotation rate (ground-based) suppresses both. Increasing perfusion rates enhances mass transport for both microgravity and ground-based cases, however, for the present range of operating conditions, above 5-10 cc/min there are diminishing returns as much of the inlet fluid is transported directly to the perfusion exit. The results show that exit concentration is not a good indicator of the concentration distributions in the vessel. In microgravity conditions, the NASA RWPV bioreactor with the viscous pump has been shown to provide an environment that is well mixed. Even when operated near the theoretical minimum perfusion rates, only a small fraction of the volume provides less than the required oxygen levels.
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Schneebeli, M.; Steinfeld, A.
2015-09-01
Snow at or close to the surface commonly undergoes temperature gradient metamorphism under advective flow, which alters its microstructure and physical properties. Time-lapse X-ray micro-tomography is applied to investigate the structural dynamics of temperature gradient snow metamorphism exposed to an advective airflow in controlled laboratory conditions. The sublimation of water vapor for saturated air flowing across the snow sample was experimentally determined via variations of the porous ice structure. The results showed that the exothermic gas-to-solid phase change is favorable vis-a-vis the endothermic solid-to-gas phase change, thus leading to more ice deposition than ice sublimation. Sublimation has a marked effect on the structural change of the ice matrix but diffusion of water vapor in the direction of the temperature gradient counteracted the mass transport of advection. Therefore, the total net ice change was negligible leading to a constant porosity profile. However, the strong reposition process of water molecules on the ice grains is relevant for atmospheric chemistry.
Transport phenomena of crystal growth—heat and mass transfer
NASA Astrophysics Data System (ADS)
Rudolph, Peter
2010-07-01
Selected fundamentals of transport processes and their importance for crystal growth are given. First, principal parameters and equations of heat and mass transfer, like thermal flux, radiation and diffusion are introduced. The heat- and mass- balanced melt-solid and solution-solid interface velocities are derived, respectively. The today's significance of global numeric simulation for analysis of thermo-mechanical stress and related dislocation dynamics within the growing crystal is shown. The relation between diffusion and kinetic regime is discussed. Then, thermal and solutal buoyancy-driven and Marangoni convections are introduced. Their important interplay with the diffusion boundary layer, component and particle incorporation as well as morphological interface stability is demonstrated. Non-steady crystallization phenomena (striations) caused by convective fluctuations are considered. Selected results of global 3D numeric modeling are shown. Finally, advanced methods to control heat and mass transfer by external forces, such as accelerated container rotation, ultrasonic vibration and magnetic fields are discussed.
A global assessment of accelerations in surface mass transport
NASA Astrophysics Data System (ADS)
Wu, Xiaoping; Heflin, Michael B.
2015-08-01
Water mass transport in the Earth's dynamic surface layer of atmosphere, cryosphere, and hydrosphere driven by various global change processes has complex spatiotemporal patterns. Here we determine global patterns and regional mean values of accelerations in surface mass variations during the Gravity Recovery and Climate Experiment (GRACE) mission's data span from 2002.2 to 2015.0. GRACE gravity data are supplemented by surface deformation from 607 Global Navigation Satellite System stations, an ocean bottom pressure model, satellite laser ranging, and loose a priori knowledge on mass variation regimes incorporating high-resolution geographic boundaries. While Greenland and West Antarctica have strong negative accelerations, Alaska and the Arctic Ocean show significant positive accelerations. In addition, the accelerations are not constant in time with some regions showing considerable variability due to irregular interannual changes. No evidence of significant nonsteric mean sea level acceleration has been found, but the uncertainty is quite large.
Black Hole Advective Accretion Disks with Optical Depth Transition
Artemove, Y.V.; Bisnovatyi-Kogan, G.S.; Igumenshchev, I.V.; Novikov, I.D.
2006-02-01
We have constructed numerically global solutions of advective accretion disks around black holes that describe a continuous transition between the effectively optically thick outer and optically thin inner disk regions. We have concentrated on models of accretion flows with large mass accretion rates, and we have employed a bridging formula for radiative losses at high and low effective optical depths.
Updated Delft Mass Transport model DMT-2: computation and validation
NASA Astrophysics Data System (ADS)
Hashemi Farahani, Hassan; Ditmar, Pavel; Inacio, Pedro; Klees, Roland; Guo, Jing; Guo, Xiang; Liu, Xianglin; Zhao, Qile; Didova, Olga; Ran, Jiangjun; Sun, Yu; Tangdamrongsub, Natthachet; Gunter, Brian; Riva, Ricardo; Steele-Dunne, Susan
2014-05-01
A number of research centers compute models of mass transport in the Earth's system using primarily K-Band Ranging (KBR) data from the Gravity Recovery And Climate Experiment (GRACE) satellite mission. These models typically consist of a time series of monthly solutions, each of which is defined in terms of a set of spherical harmonic coefficients up to degree 60-120. One of such models, the Delft Mass Transport, release 2 (DMT-2), is computed at the Delft University of Technology (The Netherlands) in collaboration with Wuhan University. An updated variant of this model has been produced recently. A unique feature of the computational scheme designed to compute DMT-2 is the preparation of an accurate stochastic description of data noise in the frequency domain using an Auto-Regressive Moving-Average (ARMA) model, which is derived for each particular month. The benefits of such an approach are a proper frequency-dependent data weighting in the data inversion and an accurate variance-covariance matrix of noise in the estimated spherical harmonic coefficients. Furthermore, the data prior to the inversion are subject to an advanced high-pass filtering, which makes use of a spatially-dependent weighting scheme, so that noise is primarily estimated on the basis of data collected over areas with minor mass transport signals (e.g., oceans). On the one hand, this procedure efficiently suppresses noise, which are caused by inaccuracies in satellite orbits and, on the other hand, preserves mass transport signals in the data. Finally, the unconstrained monthly solutions are filtered using a Wiener filter, which is based on estimates of the signal and noise variance-covariance matrices. In combination with a proper data weighting, this noticeably improves the spatial resolution of the monthly gravity models and the associated mass transport models.. For instance, the computed solutions allow long-term negative trends to be clearly seen in sufficiently small regions notorious
A positive finite-difference advection scheme
Hundsdorfer, W.; Koren, B.; Loon, M. van
1995-03-01
This paper examines a class of explicit finite-difference advection schemes derived along the method of lines. An important application field is large-scale atmospheric transport. The paper therefore focuses on the demand of positivity. For the spatial discretization, attention is confined to conservative schemes using five points per direction. The fourth-order central scheme and the family of {kappa}-schemes, comprising the second-order central, the second-order upwind, and the third-order upwind biased, are studied. Positivity is enforced through flux limiting. It is concluded that the limited third-order upwind discretization is the best candidate from the four examined. For the time integration attention is confined to a number of explicit Runge-Kutta methods of orders two to four. With regard to the demand of positivity, these integration methods turn out to behave almost equally and no best method could be identified. 16 refs., 4 figs., 4 tabs.
Metal intercalation-induced selective adatom mass transport on graphene
Liu, Xiaojie; Wang, Cai -Zhuang; Hupalo, Myron; Lin, Hai -Qing; Ho, Kai -Ming; Thiel, Patricia A.; Tringides, Michael C.
2016-03-29
Recent experiments indicate that metal intercalation is a very effective method to manipulate the graphene-adatom interaction and control metal nanostructure formation on graphene. A key question is mass transport, i.e., how atoms deposited uniformly on graphene populate different areas depending on the local intercalation. Using first-principles calculations, we show that partially intercalated graphene, with a mixture of intercalated and pristine areas, can induce an alternating electric field because of the spatial variations in electron doping, and thus, an oscillatory electrostatic potential. As a result, this alternating field can change normal stochastic adatom diffusion to biased diffusion, leading to selective massmore » transport and consequent nucleation, on either the intercalated or pristine areas, depending on the charge state of the adatoms.« less
Engineering Synergy: Energy and Mass Transport in Hybrid Nanomaterials.
Cho, Eun Seon; Coates, Nelson E; Forster, Jason D; Ruminski, Anne M; Russ, Boris; Sahu, Ayaskanta; Su, Norman C; Yang, Fan; Urban, Jeffrey J
2015-10-14
An emerging class of materials that are hybrid in nature is propelling a technological revolution in energy, touching many fundamental aspects of energy-generation, storage, and conservation. Hybrid materials combine classical inorganic and organic components to yield materials that manifest new functionalities unattainable in traditional composites or other related multicomponent materials, which have additive function only. This Research News article highlights the exciting materials design innovations that hybrid materials enable, with an eye toward energy-relevant applications involving charge, heat, and mass transport. PMID:25754355
NASA Astrophysics Data System (ADS)
Seo, Kyong-Hwan
2001-10-01
Particle dispersion in the stratosphere and mass exchange between the stratosphere and troposphere are investigated in a Lagrangian framework using the United Kingdom Meteorological Office assimilated winds. In the winter stratosphere, isentropic dispersion can be characterized as chaotic advection. Parcel trajectories intermittently alternate between flying in jets and trapping in coherent quasi-stationary vortices. We show that these trajectories are described by a power-law probability density function (PDF) with a decay exponent of less than 3. For these PDFs mean square displacement per flight step is divergent and the trajectories correspond to Lévy flights (random walk processes with divergent second moment). The variance of the zonal displacement grows faster than linearly with time, corresponding to superdiffusive dispersion. The self- similarity in the trajectories is revealed by the convergence of the scaled PDFs of displacement and the saturation of the normalized third and fourth moments with time. Stratosphere-troposphere exchange (STE), calculated by a Lagrangian method, exhibits a pronounced annual cycle. The northern hemisphere net flux of stratospheric air into the troposphere across the extratropical tropopause has a primary peak in late spring or early summer, which is consistent with observation. The southern hemisphere net flux of stratospheric air into the troposphere shows a maximum in winter. The preferred locations for stratosphere-to-troposphere transport are identified as the regions with the highest frequency of Rossby wave breaking events and with the storm tracks. This suggests that tropopause folding and baroclinic eddy activity are a primary mechanism for STE. The greatest diabatic injection of tropospheric air into the tropical stratosphere takes place following the annual variation of the Hadley circulation. The tropical upward transport occurs in association with the monsoon anticyclones. The interannual change of total column
Reactive Transport in Porous Media: Pore-scale Mass Exchange between Aqueous Phase and Biofilms
NASA Astrophysics Data System (ADS)
Hassanizadeh, S.; Qin, C.
2013-12-01
In the presence of water and necessary nutrients, biofilms can grow on soil grain surfaces. They occupy void pore spaces blocking water flow. As a result, some hydrodynamic properties of porous media like porosity and permeability will be reduced. This ultimately leads to a condition known as bioclogging. Also, biofilms can degrade certain compounds. So, the features of bioclogging and biodegradation in porous media with biofilms have given rise to a broad range of environmental and engineering applications, such as bioremediation, biobarriers, microbial enhanced oil recovery, and protection of steel corrosion. To date, a number of macroscale and pore-scale models for describing biodegradation in porous media with biofilms are available in the literature. At the macro scale, to simplify numerical implementation, a ';one-equation' model is normally preferred. In this approach, only the solute concentration in aqueous phase is modeled associated with the consumption of solute in biofilms. Because the solute concentration in biofilms is different from that in aqueous phase, an effectiveness factor may be used in Monod kinetics for relating reaction rate within biofilms to the solute concentration in aqueous phase. Notice that this approach has its validity domains like local equilibrium and reaction-rate limited consumption. Another approach to modeling biodegradation is referred to as a ';two-equation' model, in which one needs to simultaneously track the solute concentrations in both aqueous phase and biofilms. In addition, the two concentrations may be related by a first-order kinetic mass exchange model. This first-rate exchange model is normally represented by a constant mas exchange coefficient multiplied by the concentration difference in the two domains. Here, one may question if complex advection-diffusion-reaction processes can be represented just by a constant mass exchange coefficient. In addition, the kinetic model of mass exchange between aqueous phase
Mass Flux of ZnSe by Physical Vapor Transport
NASA Technical Reports Server (NTRS)
Sha, Yi-Gao; Su, Ching-Hua; Palosz, W.; Volz, M. P.; Gillies, D. C.; Szofran, F. R.; Lehoczky, S. L.; Liu, Hao-Chieh; Brebrick, R. F.
1995-01-01
Mass fluxes of ZnSe by physical vapor transport (PVT) were measured in the temperature range of 1050 to 1160 C using an in-situ dynamic technique. The starting materials were either baked out or distilled under vacuum to obtain near-congruently subliming compositions. Using an optical absorption technique Zn and Se, were found to be the dominant vapor species. Partial pressures of Zn and Se, over the starting materials at temperatures between 960 and 1140 C were obtained by measuring the optical densities of the vapor phase at the wavelengths of 2138, 3405, 3508, 3613, and 3792 A. The amount and composition of the residual gas inside the experimental ampoules were measured after the run using a total pressure gauge. For the first time, the experimentally determined partial pressures of Zn and Se, and the amount and composition of the residual gas were used in a one-dimensional diffusion limited analysis of the mass transport rates for a PVT system. Reasonable agreement between the experimental and theoretical results was observed.
Angular momentum transport within evolved low-mass stars
Cantiello, Matteo; Bildsten, Lars; Paxton, Bill; Mankovich, Christopher; Christensen-Dalsgaard, Jørgen
2014-06-10
Asteroseismology of 1.0-2.0 M {sub ☉} red giants by the Kepler satellite has enabled the first definitive measurements of interior rotation in both first ascent red giant branch (RGB) stars and those on the helium burning clump. The inferred rotation rates are 10-30 days for the ≈0.2 M {sub ☉} He degenerate cores on the RGB and 30-100 days for the He burning core in a clump star. Using the Modules for Experiments in Stellar Evolution code, we calculate state-of-the-art stellar evolution models of low mass rotating stars from the zero-age main sequence to the cooling white dwarf (WD) stage. We include transport of angular momentum due to rotationally induced instabilities and circulations, as well as magnetic fields in radiative zones (generated by the Tayler-Spruit dynamo). We find that all models fail to predict core rotation as slow as observed on the RGB and during core He burning, implying that an unmodeled angular momentum transport process must be operating on the early RGB of low mass stars. Later evolution of the star from the He burning clump to the cooling WD phase appears to be at nearly constant core angular momentum. We also incorporate the adiabatic pulsation code, ADIPLS, to explicitly highlight this shortfall when applied to a specific Kepler asteroseismic target, KIC8366239.
Experimental Studies on Mass Transport of Cadmium-Zinc Telluride by Physical Vapor Transport
NASA Technical Reports Server (NTRS)
Palosz, W.; Szofran, F. R.; Lehoczky, S. L.
1995-01-01
Experimental studies on mass transport of ternary compound, Cd(1-x)Zn(x)Te by physical vapor transport (PVT) for source compositions up to X = 0.21 are presented. The effect of thermochemical (temperatures, vapor composition) and other factors (preparation of the source, crystal growth rate, temperature gradient) on composition and composition profiles of the grown crystals were investigated. A steep decrease in the mass flux with an increase in X(crystal) for X less than 0.1, and a difference in composition between the source and the deposited material have been observed. The composition profiles of the crystals were found to depend on the density and pretreatment of the source, and on the temperature gradient in the source zone. The homogeneity of the crystals improves at low undercoolings and/or when an appropriate excess of metal constituents is present in the vapor phase. The experimental results are in good agreement with our thermochemical model of this system.
AN EULERIAN-LAGRANGIAN LOCALIZED ADJOINT METHOD FOR THE ADVECTION-DIFFUSION EQUATION
Many numerical methods use characteristic analysis to accommodate the advective component of transport. Such characteristic methods include Eulerian-Lagrangian methods (ELM), modified method of characteristics (MMOC), and operator splitting methods. A generalization of characteri...
Advective coalescence in chaotic flows.
Nishikawa, T; Toroczkai, Z; Grebogi, C
2001-07-16
We investigate the reaction kinetics of small spherical particles with inertia, obeying coalescence type of reaction, B+B-->B, and being advected by hydrodynamical flows with time-periodic forcing. In contrast to passive tracers, the particle dynamics is governed by the strongly nonlinear Maxey-Riley equations, which typically create chaos in the spatial component of the particle dynamics, appearing as filamental structures in the distribution of the reactants. Defining a stochastic description supported on the natural measure of the attractor, we show that, in the limit of slow reaction, the reaction kinetics assumes a universal behavior exhibiting a t(-1) decay in the amount of reagents, which become distributed on a subset of dimension D2, where D2 is the correlation dimension of the chaotic flow. PMID:11461595
Chaotic advection of immiscible fluids
NASA Astrophysics Data System (ADS)
Vollmayr-Lee, Benjamin; Beller, Daniel; Yasuda, Sohei
2012-02-01
We consider a system of two immiscible fluids advected by a chaotic flow field. A nonequilibrium steady state arises from the competition between the coarsening of the immiscible fluids and the domain bursting caused by the chaotic flow. It has been established that the average domain size in this steady state scales as a inverse power of the Lyapunov exponent. We examine the issue of local structure and look for correlations between the local domain size and the finite-time Lyapunov exponent (FTLE) field. For a variety of chaotic flows, we consistently find the domains to be smallest in regions where the FTLE field is maximal. This raises the possibility of making universal predictions of steady-state characteristics based on Lyapunov analysis of the flow field.
Bigham, S; Yu, DZ; Chugh, D; Moghaddam, S
2014-02-01
The slow diffusion of an absorbate molecule into an absorbent often makes the absorption process a rate-limiting step in many applications. In cases involving an absorbate with a high heat of phase change, such as water absorption into a LiBr (lithium bromide) solution, the absorption rate is further slowed due to significant heating of the absorbent. Recently, it has been demonstrated that constraining a LiBr solution film by a hydrophobic porous structure enables manipulation of the solution flow thermohydraulic characteristics. Here, it is shown that mass transport mode in a constrained laminar solution flow can be changed from diffusive to advective. This change in mode is accomplished through stretching and folding the laminar streamlines within the solution film via the implementation of micro-scale features on the flow channel surface. The process induces vortices within the solution film, which continuously bring concentrated solution from the bottom and middle of the solution channel to its interface with the vapor phase, thus leading to a significant enhancement in the absorption rate. The detailed physics of the involved transport processes is elucidated using the LBM (Lattice Boltzmann Method). Published by Elsevier Ltd.
Tomography-based monitoring of isothermal snow metamorphism under advective conditions
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Schneebeli, M.; Steinfeld, A.
2015-02-01
Time-lapse X-ray micro-tomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. Diffusion and advection across the snow pores were analysed in controlled laboratory experiments. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective transport properties. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Diffusion originating in the Kelvin effect between snow structures dominates and is the main transport process in isothermal snow packs.
Chemistry and mass transport of iodine in containment
Beahm, E.C.; Weber, C.F.; Kress, T.S.; Shockley, W.E.; Daish, S.R.
1988-01-01
TRENDS is a computer code for modeling behavior of iodine in containment. It tracks both chemical and physical changes and features such as calculation of radiation dose rates in water pools , radiolysis effects, hydrolysis, and deposition/revaporization on aerosols and structural surfaces. Every attempt has been made to account for all significant processes. Reaction rate constants for iodine hydrolysis and radiolysis were obtained by a variable algorithm that gives values closely modeling experimental data. TRENDS output provides the distribution of iodine in containment and release from containment as a function of time during a severe accident sequence. Initial calculations with TRENDS have shown that the amount of volatile iodine released from containment is sensitive to the value of the liquid-gas (evaporation) mass transport coefficient for I/sub 2/. 7 refs., 4 figs., 3 tabs.
Mass transport measurements and modeling for chemical vapor infiltration
Starr, T.L.; Chiang, D.Y.; Fiadzo, O.G.; Hablutzel, N.
1997-12-01
This project involves experimental and modeling investigation of densification behavior and mass transport in fiber preforms and partially densified composites, and application of these results to chemical vapor infiltration (CVI) process modeling. This supports work on-going at ORNL in process development for fabrication of ceramic matrix composite (CMC) tubes. Tube-shaped composite preforms are fabricated at ORNL with Nextel{trademark} 312 fiber (3M Corporation, St. Paul, MN) by placing and compressing several layers of braided sleeve on a tubular mandrel. In terms of fiber architecture these preforms are significantly different than those made previously with Nicalon{trademark} fiber (Nippon Carbon Corp., Tokyo, Japan) square weave cloth. The authors have made microstructure and permeability measurements on several of these preforms and a few partially densified composites so as to better understand their densification behavior during CVI.
Density Functional Theory Calculations of Mass Transport in UO2
Andersson, Anders D.; Dorado, Boris; Uberuaga, Blas P.; Stanek, Christopher R.
2012-06-26
In this talk we present results of density functional theory (DFT) calculations of U, O and fission gas diffusion in UO{sub 2}. These processes all impact nuclear fuel performance. For example, the formation and retention of fission gas bubbles induce fuel swelling, which leads to mechanical interaction with the clad thereby increasing the probability for clad breach. Alternatively, fission gas can be released from the fuel to the plenum, which increases the pressure on the clad walls and decreases the gap thermal conductivity. The evolution of fuel microstructure features is strongly coupled to diffusion of U vacancies. Since both U and fission gas transport rates vary strongly with the O stoichiometry, it is also important to understand O diffusion. In order to better understand bulk Xe behavior in UO{sub 2{+-}x} we first calculate the relevant activation energies using DFT techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next we investigate species transport on the (111) UO{sub 2} surface, which is motivated by the formation of small voids partially filled with fission gas atoms (bubbles) in UO{sub 2} under irradiation. Surface diffusion could be the rate-limiting step for diffusion of such bubbles, which is an alternative mechanism for mass transport in these materials. As expected, the activation energy for surface diffusion is significantly lower than for bulk transport. These results are further discussed in terms of engineering-scale fission gas release models
Dynamic typology of hydrothermal systems: competing effects of advection, dispersion and reactivity
NASA Astrophysics Data System (ADS)
Dolejs, David
2016-04-01
Genetic interpretation hydrothermal systems relies on recognition of (i) hydrothermal fluid source, (ii) fluid migration pathways, and (iii) deposition site identified by hydrothermal alteration and/or mineralization. Frequently, only the last object is of interest or accessible to direct observation, but constraints on the fluid source (volume) and pathways can be obtained from evaluation of the time-integrated fluid flux during hydrothermal event. Successful interpretation of the petrological record, that is, progress of alteration reactions, relies on identification of individual contributions arising from solute advection (to the deposition site), its lateral dispersion, and reaction efficiency. Although these terms are all applicable in a mass-conservation relationship within the framework of the transport theory, they are rarely considered simultaneously and their relative magnitudes evaluated. These phenomena operate on variable length and time scales, and may in turn provide insight into the system dynamics such as flow, diffusion and reaction rates, or continuous vs. episodic behavior of hydrothermal events. In addition, here we demonstrate that they also affect estimate of the net fluid flux, frequently by several orders of magnitude. The extent of alteration and mineralization reactions between the hydrothermal fluid and the host environment is determined by: (i) temperature, pressure or any other gradients across the mineralization site, (ii) magnitude of disequilibrium at inflow to the mineralization site, which is related to physico-chemical gradient between the fluid source and the mineralization site, and (iii) chemical redistribution (dispersion) within the mineralization site. We introduce quantitative mass-transport descriptors - Péclet and Damköhler II numbers - to introduce division into dispersion-dominated, advection-dominated and reaction-constrained systems. Dispersive systems are characterized by lateral solute redistribution, driven by
NASA Astrophysics Data System (ADS)
Wagenbrenner, N. S.; Edburg, S. L.; Lamb, B.; Forthofer, J.
2012-12-01
In areas of complex terrain, fine-scale changes in topography or vegetation substantially alter the flow field, and in turn, the transport and dispersion of air pollutants, pheromones, or other scalars. Thus, accurate modeling of scalar transport in complex topography requires accurate prediction of the flow field at a high spatial resolution. Mesoscale weather models typically operate on horizontal grids of 4 km or larger and are not capable of handling the effects of sub-grid complex terrain, such as wind speed-up over ridges, flow channeling in valleys, flow separation around terrain obstacles, and enhanced surface roughness from vegetation. In this paper we describe a scalar transport algorithm (advection and turbulent diffusion) used with WindNinja, a high-resolution mass-consistent wind model. WindNinja operates on a terrain-following coordinate system with a hexahedral cell mesh that grows in vertical size with height above the ground. A variational calculus approach is used in WindNinja that results in fast run times on the order of one minute for a 50 km x 50 km domain and 100 m horizontal resolution. The advection-diffusion algorithm uses a first order closure scheme for turbulent diffusion, where diffusivities are parameterized based on mixing length theory and modified as a function of atmospheric stability. We initialize WindNinja simulations with output from mesoscale weather forecasts using the Weather Research and Forecasting (WRF) model to capture the large-scale atmospheric flows and stability conditions. Model performance is evaluated against field data collected under a range of conditions at different locations including a multi-day continuous tracer gas dispersion experiment in an orchard located on rolling terrain in eastern Washington and a post-wildfire PM10 monitoring campaign in SE Idaho. The combination of fast run times, low computational demands, and explicit treatment of terrain and vegetation at a high spatial resolution are expected
Multigrid optimal mass transport for image registration and morphing
NASA Astrophysics Data System (ADS)
Rehman, Tauseef ur; Tannenbaum, Allen
2007-02-01
In this paper we present a computationally efficient Optimal Mass Transport algorithm. This method is based on the Monge-Kantorovich theory and is used for computing elastic registration and warping maps in image registration and morphing applications. This is a parameter free method which utilizes all of the grayscale data in an image pair in a symmetric fashion. No landmarks need to be specified for correspondence. In our work, we demonstrate significant improvement in computation time when our algorithm is applied as compared to the originally proposed method by Haker et al [1]. The original algorithm was based on a gradient descent method for removing the curl from an initial mass preserving map regarded as 2D vector field. This involves inverting the Laplacian in each iteration which is now computed using full multigrid technique resulting in an improvement in computational time by a factor of two. Greater improvement is achieved by decimating the curl in a multi-resolutional framework. The algorithm was applied to 2D short axis cardiac MRI images and brain MRI images for testing and comparison.
Mass and charge transport in IPMC actuators with fractal interfaces
NASA Astrophysics Data System (ADS)
Chang, Longfei; Wu, Yucheng; Zhu, Zicai; Li, Heng
2016-04-01
Ionic Polymer-Metal Composite (IPMC) actuators have been attracting a growing interest in extensive applications, which consequently raises the demands on the accuracy of its theoretical modeling. For the last few years, rough landscape of the interface between the electrode and the ionic membrane of IPMC has been well-documented as one of the key elements to ensure a satisfied performance. However, in most of the available work, the interface morphology of IPMC was simplified with structural idealization, which lead to perplexity in the physical interpretation on its interface mechanism. In this paper, the quasi-random rough interface of IPMC was described with fractal dimension and scaling parameters. And the electro-chemical field was modeled by Poisson equation and a properly simplified Nernst-Planck equation set. Then, by simulation with Finite Element Method, a comprehensive analysis on he inner mass and charge transportation in IPMC actuators with different fractal interfaces was provided, which may be further adopted to instruct the performance-oriented interface design for ionic electro-active actuators. The results also verified that rough interface can impact the electrical and mechanical response of IPMC, not only from the respect of the real surface increase, but also from mass distribution difference caused by the complexity of the micro profile.
Mass transport and element mobilisation during large-scale metasomatism
NASA Astrophysics Data System (ADS)
Putnis, C. V.; Austrheim, H.; Jamtveit, B.; Engvik, A. K.; Putnis, A.
2009-04-01
Replacement textures commonly occur in relation to fluid-driven large scale metasomatism and metamorphism and these processes are often related to mineralisation. For example, the albitisation of gabbroic rocks in the Bamble District, southern Norway is associated with ore deposits. Similar albitised rocks are also characteristic of the Curnamona Province, Australia, which includes large areas of mineralisation such as the Pb, Zn, Ag of the Broken Hill deposits as well as Cu, Au and U deposits. The main question addressed here is the mechanism of mass transport and hence element mobilisation. An indication of the former presence of fluids within a rock can be seen in mineral textures, such as porosity, replacement rims, replacement induced fracturing and crystallographic continuity across sharp compositional boundaries. Such textural observations from natural rocks as well as experimental products show that during mineral-fluid interaction, the crystallographic relations between parent and product phases control the nucleation of the product, and hence a coupling between dissolution and reprecipitation. If the rate of nucleation and growth of the product equals the dissolution rate, a pseudomorphic replacement takes place. The degree of epitaxy (or lattice misfit) at the interface, the relative solubility of parent and product phases and the molar volume changes control the microstructure of the product phase. The key observation is that these factors control the generation of porosity as well as reaction induced fracturing ahead of the main reaction interface. Porosity is generated whenever the amount of parent dissolved is greater than the amount of product reprecipitated, irrespective of the molar volume changes of the solid reactants and products. This porosity is occupied by the fluid phase during the reaction, and provides a mechanism of mass transport and fluid movement between reaction interface and the surrounding phases. The reaction-induced fracturing
Numerical experiments for advection equation
Sun, Wen-Yih )
1993-10-01
We propose to combine the Crowley fourth-order scheme and the Gadd scheme for solving the linear advection equation. Two new schemes will be presented: the first is to integrate the Crowley scheme and the Gadd scheme alternately (referred to as New1); the second is to integrate the Crowley scheme twice before we apply the Gadd scheme once (referred to as New2). The new schemes are designed such that no additional restriction is placed on the CFL criterion in an integration. The performance of the new schemes is better than that of the original Crowley or Gadd schemes. It is noted that the amplitude obtained from New2 is more accurate than that from New1 for long waves, but less accurate for short waves. The phase speed calculated from New2 is very close to the real phase speed in most cases tested here, but the phase speed of New 1 is faster than the real phase speed. Hence, New2 is a better choice, especially for a model that includes horizontal smoothing to dampen the short waves. 9 refs., 5 figs., 8 tabs.
A Mercury Transport and Fate Model for Mass Budget Assessment of Mercury Cycling in Lake Michigan
A mercury mass balance model was developed to describe and evaluate the fate, transport, and biogeochemical transformations of mercury in Lake Michigan. Coupling with total suspendable solids (TSS) and dissolved organic carbon (DOC), the mercury transport and fate model simulates...
NASA Astrophysics Data System (ADS)
Fischer, G.; Reuter, C.; Karakas, G.; Nowald, N.; Wefer, G.
2009-12-01
This article will review major features of the ‘giant’ Cape Blanc filament off Mauritania with regard to the transport of chlorophyll and organic carbon from the shelf to the open ocean. Within the filament, chlorophyll is transported about 400 km offshore. Modelled particle distributions along a zonal transect at 21°N showed that particles with a sinking velocity of 5 m d -1 are advected offshore by up to 600 km in subsurface particle clouds generally located between 400 m and 800 m water depth, forming an Intermediate Nepheloid Layer (INL). It corresponds to the depth of the oxygen minimum zone. Heavier particles with a sinking velocity of 30 m d -1 are transported from the shelf within the Bottom Layer (BL) of more than 1000 m thickness, largely following the topography of the bottom slope. The particles advected within the BL contribute to the enhanced winter-spring mass fluxes collected at the open-ocean mesotrophic sediment trap site CB-13 (∼200 nm offshore), due to a long distance advection in deeper waters. The lateral contribution to the deep sediment trap in winter-spring is estimated to be 63% and 72% for organic carbon and total mass, respectively, whereas the lateral input for both components on an annual basis is estimated to be in the order of 15%. Biogenic opal increases almost fivefold from the upper to the lower mesotrophic CB-13 trap, also pointing to an additional source for biogenic silica from eutrophic coastal waters. Blooms obviously sink in smaller, probably mesoscale-sized patches with variable settling rates, depending on the type of aggregated particles and their ballast content. Generally, particle sinking rates are exceptionally high off NW Africa. Very high chlorophyll values and a large size of the Cape Blanc filament in 1998-1999 are also documented in enhanced total mass and organic carbon fluxes. An increasing trend in satellite chlorophyll concentrations and the size of the Cape Blanc filament between 1997 and 2008 as
Lewis-Brown, Jean C.; Carleton, Glen B.; Imbrigiotta, Thomas E.
2006-01-01
Volatile organic compounds, predominantly trichloroethylene and its degradation products, have been detected in ground water at the Naval Air Warfare Center (NAWC), West Trenton, New Jersey. An air-stripping pump-and-treat system has been in operation at the NAWC since 1998. An existing ground-water-flow model was used to evaluate the effect of a change in the configuration of the network of recovery wells in the pump-and-treat system on flow paths of contaminated ground water. The NAWC is underlain by a fractured-rock aquifer composed of dipping layers of sedimentary rocks of the Lockatong and Stockton Formations. Hydraulic and solute-transport properties of the part of the aquifer composed of the Lockatong Formation were measured using aquifer tests and tracer tests. The heterogeneity of the rocks causes a wide range of values of each parameter measured. Transmissivity ranges from 95 to 1,300 feet squared per day; the storage coefficient ranges from 9 x 10-5 to 5 x 10-3; and the effective porosity ranges from 0.0003 to 0.002. The average linear velocity of contaminated ground water was determined for ambient conditions (when no wells at the site are pumped) using an existing ground-water-flow model, particle-tracking techniques, and the porosity values determined in this study. The average linear velocity of flow paths beginning at each contaminated well and ending at the streams where the flow paths terminate ranges from 0.08 to 130 feet per day. As a result of a change in the pump-and-treat system (adding a 165-foot-deep well pumped at 5 gallons per minute and reducing the pumping rate at a nearby 41-foot-deep well by the same amount), water in the vicinity of three 100- to 165-foot-deep wells flows to the deep well rather than the shallower well.
Mass transport, faceting and behavior of dislocations in GaN
Nitta, S.; Kashima, T.; Kariya, M.; Yukawa, Y.; Yamaguchi, S.; Amano, H.; Akasaki, I.
2000-07-01
The behavior of threading dislocations during mass transport of GaN was investigated in detail by transmission electron microscopy. Mass transport occurred at the surface. Therefore, growing species are supplied from the in-plane direction. The behavior of threading dislocations was found to be strongly affected by the mass transport process as well as the high crystallographic anisotropy of the surface energy of the facets particular to GaN.
The latent fingerprint in mass transport of polycrystalline materials
NASA Astrophysics Data System (ADS)
Thirunavukarasu, Gopinath; Kundu, Sukumar; Chatterjee, Subrata
2016-02-01
Herein, a systematic investigation was carried out to reach a rational understanding and to provide information concerning the possible causes for a significant influence of pressure variation in the underlying processes of mass transport in polycrystalline materials. The authors focused their research in solid-state diffusion, a part of the subject "Mass Transport in Solids". Theories on diffusion are the subject by itself which exists as a latent fingerprint in every text of higher learning in interdisciplinary science. In this research, authors prepared sandwich samples of titanium alloy and stainless steel using nickel as an intermediate metal. The samples were processed at three different levels of bonding pressure (3, 4 and 5 MPa) while bonding temperature and bonding time was maintained at 750 °C and 1 h, respectively, throughout the experiments. It was observed that the net flux of atomic diffusion of nickel atoms into Ti-alloy at TiA/Ni interface increased by ~63 % with the rise in the bonding pressure from 3 to 4 MPa, but decreased by ~40 % with the rise in the bonding pressure from 4 to 5 MPa. At the same time, the net flux of atomic diffusion of nickel atoms into stainless steel at Ni/SS interface increased by ~19 % with the rise in the bonding pressure from 3 to 4 MPa, but increased by ~17 % with the rise in the bonding pressure from 4 to 5 MPa. Here authors showed that the pressure variations have different effects at the TiA/Ni interface and Ni/SS interface, and tried to explain the explicit mechanisms operating behind them. In general for sandwich samples processed irrespective of bonding pressure chosen, the net flux of Ni-atoms diffused into SS is greater than that of the net flux of Ni-atoms diffused in Ti-alloy matrix by four orders of magnitude. The calculated diffusivity of Ni-atoms into Ti-alloy reaches its highest value of ~5.083 × 10-19 m2/s for the sandwich sample processed using 4-MPa bonding-pressure, whereas the diffusivity of Ni
Conception for enhanced mass transport in binary nanofluids
NASA Astrophysics Data System (ADS)
Xuan, Yimin
2009-12-01
Besides their application in enhancing heat transfer, suspended nanoparticles have been found to improve mass transfer process inside binary nanofluids. The concepts of enhanced mass transfer in binary nanofluids are involved. By means of the heat and mass transfer analogy, the approaches for determining the mass diffusivity and mass transfer coefficient are proposed and discussed.
Healy, R.W.; Russell, T.F.
1993-01-01
Test results demonstrate that the finite-volume Eulerian-Lagrangian localized adjoint method (FVELLAM) outperforms standard finite-difference methods for solute transport problems that are dominated by advection. FVELLAM systematically conserves mass globally with all types of boundary conditions. Integrated finite differences, instead of finite elements, are used to approximate the governing equation. This approach, in conjunction with a forward tracking scheme, greatly facilitates mass conservation. The mass storage integral is numerically evaluated at the current time level, and quadrature points are then tracked forward in time to the next level. Forward tracking permits straightforward treatment of inflow boundaries, thus avoiding the inherent problem in backtracking of characteristic lines intersecting inflow boundaries. FVELLAM extends previous results by obtaining mass conservation locally on Lagrangian space-time elements. -from Authors
NASA Astrophysics Data System (ADS)
Landel, Julien R.; Thomas, Amalia; McEvoy, Harry; Dalziel, Stuart B.
2015-11-01
We investigate the convective mass transfer of dilute passive tracers contained in small viscous drops into a submerging falling film. This problem has applications in industrial cleaning, domestic dishwashers, and decontamination of hazardous material. The film Peclet number is very high, whereas the drop Peclet number varies from 0.1 to 1. The characteristic transport time in the drop is much larger than in the film. We model the mass transfer using an analogy with Newton's law of cooling. This empirical model is supported by an analytical model solving the quasi-steady two-dimensional advection-diffusion equation in the film that is coupled with a time-dependent one-dimensional diffusion equation in the drop. We find excellent agreement between our experimental data and the two models, which predict an exponential decrease in time of the drop concentration. The transport characteristic time is related to the drop diffusion time scale, as diffusion within the drop is the limiting process. Our theoretical model not only predicts the well-known relationship between the Sherwood number and the external Reynolds number in the case of a well-mixed drop Sh ~ Re1/3, it also predicts a correction in the case of a non-uniform drop concentration. The correction depends on Re, the film Schmidt number, the drop aspect ratio and the diffusivity ratio between the two phases. This prediction is in good agreement with experimental data. This material is based upon work supported by the Defense Threat Reduction Agency under Contract No. HDTRA1-12-D-0003-0001.
An operator splitting algorithm for the three-dimensional advection-diffusion equation
NASA Astrophysics Data System (ADS)
Khan, Liaqat Ali; Liu, Philip L.-F.
1998-09-01
Operator splitting algorithms are frequently used for solving the advection-diffusion equation, especially to deal with advection dominated transport problems. In this paper an operator splitting algorithm for the three-dimensional advection-diffusion equation is presented. The algorithm represents a second-order-accurate adaptation of the Holly and Preissmann scheme for three-dimensional problems. The governing equation is split into an advection equation and a diffusion equation, and they are solved by a backward method of characteristics and a finite element method, respectively. The Hermite interpolation function is used for interpolation of concentration in the advection step. The spatial gradients of concentration in the Hermite interpolation are obtained by solving equations for concentration gradients in the advection step. To make the composite algorithm efficient, only three equations for first-order concentration derivatives are solved in the diffusion step of computation. The higher-order spatial concentration gradients, necessary to advance the solution in a computational cycle, are obtained by numerical differentiations based on the available information. The simulation characteristics and accuracy of the proposed algorithm are demonstrated by several advection dominated transport problems.
Mass and Momentum Transport in Microcavities for Diffusion-Dominant Cell Culture Applications
NASA Technical Reports Server (NTRS)
Yew, Alvin G.; Pinero, Daniel; Hsieh, Adam H.; Atencia, Javier
2012-01-01
For the informed design of microfluidic devices, it is important to understand transport phenomena at the microscale. This letter outlines an analytically-driven approach to the design of rectangular microcavities extending perpendicular to a perfusion microchannel for microfluidic cell culture devices. We present equations to estimate the spatial transition from advection- to diffusion-dominant transport inside cavities as a function of the geometry and flow conditions. We also estimate the time required for molecules, such as nutrients or drugs to travel from the microchannel to a given depth into the cavity. These analytical predictions can facilitate the rational design of microfluidic devices to optimize and maintain long-term, physiologically-based culture conditions with low fluid shear stress.
Mass transport model through the skin by microencapsulation system.
Carreras, Núria; Alonso, Cristina; Martí, Meritxell; Lis, Manel J
2015-01-01
Skin drug delivery can be subdivided into topical and transdermal administration. Transdermal administration can take advantage of chemical and physical strategies that can improve skin permeability and allow drug penetration. In this study, the development of a skin penetration profile was carried out by an in vitro technique for a microencapsulated system of ibuprofen. Release experiments were performed using percutaneous absorption tests to determine the evolution of the principle present in each of the different skin compartments as a function of time. A general kinetic model for a microencapsulated structure as a mass transport system through the skin was applied: [Formula: see text] This model could predict the penetration profile of encapsulated substances through skin from biofunctional textiles as well as estimate the dosage profile of the active principle. The apparent diffusion coefficients found were 1.20 × 10(-7 )cm/s for the stratum corneum and higher for the rest of the skin 6.67 × 10(-6 )cm/s. PMID:26004367
Utilizing Kernelized Advection Schemes in Ocean Models
NASA Astrophysics Data System (ADS)
Zadeh, N.; Balaji, V.
2008-12-01
There has been a recent effort in the ocean model community to use a set of generic FORTRAN library routines for advection of scalar tracers in the ocean. In a collaborative project called Hybrid Ocean Model Environement (HOME), vastly different advection schemes (space-differencing schemes for advection equation) become available to modelers in the form of subroutine calls (kernels). In this talk we explore the possibility of utilizing ESMF data structures in wrapping these kernels so that they can be readily used in ESMF gridded components.
NASA Astrophysics Data System (ADS)
Rubbab, Qammar; Mirza, Itrat Abbas; Qureshi, M. Zubair Akbar
2016-07-01
The time-fractional advection-diffusion equation with Caputo-Fabrizio fractional derivatives (fractional derivatives without singular kernel) is considered under the time-dependent emissions on the boundary and the first order chemical reaction. The non-dimensional problem is formulated by using suitable dimensionless variables and the fundamental solutions to the Dirichlet problem for the fractional advection-diffusion equation are determined using the integral transforms technique. The fundamental solutions for the ordinary advection-diffusion equation, fractional and ordinary diffusion equation are obtained as limiting cases of the previous model. Using Duhamel's principle, the analytical solutions to the Dirichlet problem with time-dependent boundary pulses have been obtained. The influence of the fractional parameter and of the drift parameter on the solute concentration in various spatial positions was analyzed by numerical calculations. It is found that the variation of the fractional parameter has a significant effect on the solute concentration, namely, the memory effects lead to the retardation of the mass transport.
NASA Astrophysics Data System (ADS)
Dompierre, Kathryn A.; Barbour, S. Lee
2016-06-01
Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.
Dompierre, Kathryn A; Barbour, S Lee
2016-06-01
Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.
Dompierre, Kathryn A; Barbour, S Lee
2016-06-01
Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy. PMID:27061245
NASA Technical Reports Server (NTRS)
Talay, T. A.
1975-01-01
Wave-induced mass-transport current theories with both zero and nonzero net mass (or volume) transport of the water column are reviewed. A relationship based on the Longuet-Higgens theory is derived for wave-induced, nonzero mass-transport currents in intermediate water depths for a viscous fluid. The relationship is in a form useful for experimental applications; therefore, some design criteria for experimental wave-tank tests are also presented. Sample parametric cases for typical wave-tank conditions and a typical ocean swell were assessed by using the relation in conjunction with an equation developed by Unluata and Mei for the maximum wave-induced volume transport. Calculations indicate that substantial changes in the wave-induced mass-transport current profiles may exist dependent upon the assumed net volume transport. A maximum volume transport, corresponding to an infinite channel or idealized ocean condition, produces the largest wave-induced mass-transport currents. These calculations suggest that wave-induced mass-transport currents may have considerable effects on pollution and suspended-sediments transport as well as buoy drift, the surface and midlayer water-column currents caused by waves increasing with increasing net volume transports. Some of these effects are discussed.
A high order characteristic discontinuous Galerkin scheme for advection on unstructured meshes
NASA Astrophysics Data System (ADS)
Lee, D.; Lowrie, R.; Petersen, M.; Ringler, T.; Hecht, M.
2016-11-01
A new characteristic discontinuous Galerkin (CDG) advection scheme is presented. In contrast to standard discontinuous Galerkin schemes, the test functions themselves follow characteristics in order to ensure conservation and the edges of each element are also traced backwards along characteristics in order to create a swept region, which is integrated in order to determine the mass flux across the edge. Both the accuracy and performance of the scheme are greatly improved by the use of large Courant-Friedrichs-Lewy numbers for a shear flow test case and the scheme is shown to scale sublinearly with the number of tracers being advected, outperforming a standard flux corrected transport scheme for 10 or more tracers with a linear basis. Moreover the CDG scheme may be run to arbitrarily high order spatial accuracy and on unstructured grids, and is shown to give the correct order of error convergence for piecewise linear and quadratic bases on regular quadrilateral and hexahedral planar grids. Using a modal Taylor series basis, the scheme may be made monotone while preserving conservation with the use of a standard slope limiter, although this reduces the formal accuracy of the scheme to first order. The second order scheme is roughly as accurate as the incremental remap scheme with nonlocal gradient reconstruction at half the horizontal resolution. The scheme is being developed for implementation within the Model for Prediction Across Scales (MPAS) Ocean model, an unstructured grid finite volume ocean model.
Technology and human purpose: the problem of solids transport on the Earth's surface
NASA Astrophysics Data System (ADS)
Haff, P. K.
2012-11-01
Displacement of mass of limited deformability ("solids") on the Earth's surface is opposed by friction and (the analog of) form resistance - impediments relaxed by rotational motion, self-powering of mass units, and transport infrastructure. These features of solids transport first evolved in the biosphere prior to the emergence of technology, allowing slope-independent, diffusion-like motion of discrete objects as massive as several tons, as illustrated by animal foraging and movement along game trails. However, high-energy-consumption technology powered by fossil fuels required a mechanism that could support fast advective transport of solids, i.e., long-distance, high-volume, high-speed, unidirectional, slope-independent transport across the land surface of materials like coal, containerized fluids, minerals, and economic goods. Pre-technology nature was able to sustain regional- and global-scale advection only in the limited form of piggybacking on geophysical flows of water (river sediment) and air (dust). The appearance of a mechanism for sustained advection of solids independent of fluid flows and gravity appeared only upon the emergence of human purpose. Purpose enables solids advection by, in effect, simulating a continuous potential gradient, otherwise lacking, between discrete and widely separated fossil-fuel energy sources and sinks. Invoking purpose as a mechanism in solids advection is an example of the need to import anthropic principles and concepts into the language and methodology of modern Earth system dynamics. As part of the emergence of a generalized solids advection mechanism, several additional transport requirements necessary to the function of modern large-scale technological systems were also satisfied. These include spatially accurate delivery of advected payload, targetability to essentially arbitrarily located destinations (such as cities), and independence of structure of advected payload from transport mechanism. The latter property
Technology and human purpose: the problem of solids transport on the earth's surface
NASA Astrophysics Data System (ADS)
Haff, P. K.
2012-05-01
Displacement of mass of limited deformability ("solids") on the Earth's surface is opposed by friction and (the analog of) form resistance - impediments relaxed by rotational motion, self-powering of mass units, and transport infrastructure. These features of solids transport first evolved in the biosphere prior to the emergence of technology, allowing slope-independent, diffusion-like motion of discrete objects as massive as several tons, as illustrated by animal foraging and movement along game trails. However, high-energy-consumption technology powered by fossil fuels required a mechanism that could support advective transport of solids, i.e., long-distance, high-volume, high-speed, unidirectional, slope independent transport across the land surface of materials like coal, containerized fluids, and minerals. Pre-technology nature was able to sustain large-scale, long-distance solids advection only in the limited form of piggybacking on geophysical flows of water (river sediment) and air (dust). The appearance of a generalized mechanism for advection of solids independent of fluid flows and gravity appeared only upon the emergence of human purpose. Purpose enables solids advection by, in effect, enabling a simulated continuous potential gradient, otherwise lacking, between discrete and widely separated fossil-fuel energy sources and sinks. Invoking purpose as a mechanism in solids advection is an example of the need to import anthropic principles and concepts into the language and methodology of modern Earth system dynamics. As part of the emergence of a generalized solids advection mechanism, several additional transport requirements necessary to the function of modern large-scale technological systems were also satisfied. These include spatially accurate delivery of advected payload, targetability to essentially arbitrarily located destinations (such as cities), and independence of structure of advected payload from transport mechanism. The latter property
MASS TRANSPORT EFFECTS ON THE KINETICS OF NITROBENZENE REDUCTION BY IRON METAL. (R827117)
To evaluate the importance of external mass transport on the overall rates of
contaminant reduction by iron metal (Fe^{0}), we have compared measured
rates of surface reaction for nitrobenzene (ArNO_{2}) to estimated rates
of external mass transport...
NASA Technical Reports Server (NTRS)
Thornton, D. C.; Niazy, N.
1983-01-01
A technique is developed to measure the effective mass transport parameter for the electrochemical concentration cell (ECC) ozonesonde in order to determine the mass transport rate constant for the ECC as a function of pressure. It is shown that a pressure dependent factor in the background current originates in a convective mass transport parameter. It is determined that for atmospheric pressures greater than 100 mb the mass transport parameter is a constant, while at pressures less than 100 mb it decreases logarithmically with pressure. It is suggested that the background current correction is directly correlated to the mass transport parameter pressure dependence. The presently used background current correction, which is based on the partial pressure of oxygen, is found to lead to an overestimation of the integrated ozone value in the troposphere for the ECC ozonesonde data.
Integrated mass transportation system study/definition/implementation program definition
NASA Technical Reports Server (NTRS)
Ransone, R. K.; Deptula, D. A.; Yorke, G. G.
1975-01-01
Specific actions needed to plan and effect transportation system improvements are identified within the constraints of limited financial, energy and land use resources, and diverse community requirements. A specific program is described which would develop the necessary generalized methodology for devising improved transportation systems and evaluate them against specific criteria for intermodal and intramodal optimization. A consistent, generalized method is provided for study and evaluation of transportation system improvements.
Drift by drift: effective population size is limited by advection
2008-01-01
Background Genetic estimates of effective population size often generate surprising results, including dramatically low ratios of effective population size to census size. This is particularly true for many marine species, and this effect has been associated with hypotheses of "sweepstakes" reproduction and selective hitchhiking. Results Here we show that in advective environments such as oceans and rivers, the mean asymmetric transport of passively dispersed reproductive propagules will act to limit the effective population size in species with a drifting developmental stage. As advection increases, effective population size becomes decoupled from census size as the persistence of novel genetic lineages is restricted to those that arise in a small upstream portion of the species domain. Conclusion This result leads to predictions about the maintenance of diversity in advective systems, and complements the "sweepstakes" hypothesis and other hypotheses proposed to explain cases of low allelic diversity in species with high fecundity. We describe the spatial extent of the species domain in which novel allelic diversity will be retained, thus determining how large an appropriately placed marine reserve must be to allow the persistence of endemic allelic diversity. PMID:18710549
Healy, R.W.; Russell, T.F.
1992-01-01
A finite-volume Eulerian-Lagrangian local adjoint method for solution of the advection-dispersion equation is developed and discussed. The method is mass conservative and can solve advection-dominated ground-water solute-transport problems accurately and efficiently. An integrated finite-difference approach is used in the method. A key component of the method is that the integral representing the mass-storage term is evaluated numerically at the current time level. Integration points, and the mass associated with these points, are then forward tracked up to the next time level. The number of integration points required to reach a specified level of accuracy is problem dependent and increases as the sharpness of the simulated solute front increases. Integration points are generally equally spaced within each grid cell. For problems involving variable coefficients it has been found to be advantageous to include additional integration points at strategic locations in each well. These locations are determined by backtracking. Forward tracking of boundary fluxes by the method alleviates problems that are encountered in the backtracking approaches of most characteristic methods. A test problem is used to illustrate that the new method offers substantial advantages over other numerical methods for a wide range of problems.
Distinguishing resuspension and advection signals in a hypertidal estuary
NASA Astrophysics Data System (ADS)
Todd, David; Souza, Alex; Jago, Colin
2015-04-01
Terrestrial material is supplied to an estuary system by the river, while marine material is supplied by the sea. Whether the estuary acts as a trap or a bypass zone for SPM (suspended particulate matter) depends upon the properties and dynamics of both the estuary, including the tidal and residual behaviour of the currents, and the SPM, including particle sizes and settling velocities and concentration gradients, which together control the dynamics, such as the trapping efficiency, of the estuary. Whether an SPM signal is regarded as being one of resuspension or advection depends upon the area of interest, and therefore distinguishing between resuspension and advection can be complex. Material that is resuspended within the area of study is regarded as resuspension, while that which is resuspended outside, but passes through, the area of interest, is regarded as advection. The results of a measurement campaign undertaken in a hypertidal UK estuary during the pre-spring bloom February-March and post-spring bloom May-June are presented utilising a combination of acoustic and optical instruments, moorings, and CTD stations. A characteristic asymmetric "twin peak" signal is present during both time periods, implying the presence of both resuspension and advection. This is confirmed through the use of harmonic analysis. A seasonal variation in the relative importance of the resuspension and advection components is seen between the two observation periods, with the small (<122µm) and large (>122µm) particles displaying different behaviours and providing a strong indication of the presence of flocculation. Approximate point flux calculations showed a reduction in the horizontal gradient of concentration, and subsequently the flood dominance of sediment transport, between May-June and February-March. This has been attributed to changes in biological activity and atmospheric forcing between the two observational periods. Ebb-dominant concentrations brought about by the
The contiguous domains of Arctic Ocean advection: Trails of life and death
NASA Astrophysics Data System (ADS)
Wassmann, P.; Kosobokova, K. N.; Slagstad, D.; Drinkwater, K. F.; Hopcroft, R. R.; Moore, S. E.; Ellingsen, I.; Nelson, R. J.; Carmack, E.; Popova, E.; Berge, J.
2015-12-01
The central Arctic Ocean is not isolated, but tightly connected to the northern Pacific and Atlantic Oceans. Advection of nutrient-, detritus- and plankton-rich waters into the Arctic Ocean forms lengthy contiguous domains that connect subarctic with the arctic biota, supporting both primary production and higher trophic level consumers. In turn, the Arctic influences the physical, chemical and biological oceanography of adjacent subarctic waters through southward fluxes. However, exports of biomass out of the Arctic Ocean into both the Pacific and Atlantic Oceans are thought to be far smaller than the northward influx. Thus, Arctic Ocean ecosystems are net biomass beneficiaries through advection. The biotic impact of Atlantic- and Pacific-origin taxa in arctic waters depends on the total supply of allochthonously-produced biomass, their ability to survive as adults and their (unsuccessful) reproduction in the new environment. Thus, advective transport can be thought of as trails of life and death in the Arctic Ocean. Through direct and indirect (mammal stomachs, models) observations this overview presents information about the advection and fate of zooplankton in the Arctic Ocean, now and in the future. The main zooplankton organisms subjected to advection into and inside the Arctic Ocean are (a) oceanic expatriates of boreal Atlantic and Pacific origin, (b) oceanic Arctic residents and (c) neritic Arctic expatriates. As compared to the Pacific gateway the advective supply of zooplankton biomass through the Atlantic gateways is 2-3 times higher. Advection characterises how the main planktonic organisms interact along the contiguous domains and shows how the subarctic production regimes fuel life in the Arctic Ocean. The main differences in the advective regimes through the Pacific and Atlantic gateways are presented. The Arctic Ocean is, at least in some regions, a net heterotrophic ocean that - during the foreseeable global warming trend - will more and more rely
Surfzone alongshore advective accelerations: observations and modeling
NASA Astrophysics Data System (ADS)
Hansen, J.; Raubenheimer, B.; Elgar, S.
2014-12-01
The sources, magnitudes, and impacts of non-linear advective accelerations on alongshore surfzone currents are investigated with observations and a numerical model. Previous numerical modeling results have indicated that advective accelerations are an important contribution to the alongshore force balance, and are required to understand spatial variations in alongshore currents (which may result in spatially variable morphological change). However, most prior observational studies have neglected advective accelerations in the alongshore force balance. Using a numerical model (Delft3D) to predict optimal sensor locations, a dense array of 26 colocated current meters and pressure sensors was deployed between the shoreline and 3-m water depth over a 200 by 115 m region near Duck, NC in fall 2013. The array included 7 cross- and 3 alongshore transects. Here, observational and numerical estimates of the dominant forcing terms in the alongshore balance (pressure and radiation-stress gradients) and the advective acceleration terms will be compared with each other. In addition, the numerical model will be used to examine the force balance, including sources of velocity gradients, at a higher spatial resolution than possible with the instrument array. Preliminary numerical results indicate that at O(10-100 m) alongshore scales, bathymetric variations and the ensuing alongshore variations in the wave field and subsequent forcing are the dominant sources of the modeled velocity gradients and advective accelerations. Additional simulations and analysis of the observations will be presented. Funded by NSF and ASDR&E.
Pfeuffer, Kevin P; Ray, Steven J; Hieftje, Gary M
2014-05-01
Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last 9 years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification because of the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet.
Update on Advection-Diffusion Purge Flow Model
NASA Technical Reports Server (NTRS)
Brieda, Lubos
2015-01-01
Gaseous purge is commonly used in sensitive spacecraft optical or electronic instruments to prevent infiltration of contaminants and/or water vapor. Typically, purge is sized using simplistic zero-dimensional models that do not take into account instrument geometry, surface effects, and the dependence of diffusive flux on the concentration gradient. For this reason, an axisymmetric computational fluid dynamics (CFD) simulation was recently developed to model contaminant infiltration and removal by purge. The solver uses a combined Navier-Stokes and Advection-Diffusion approach. In this talk, we report on updates in the model, namely inclusion of a particulate transport model.
Subsurface barrier design alternatives for confinement and controlled advection flow
Phillips, S.J.; Stewart, W.E.; Alexander, R.G.; Cantrell, K.J.; McLaughlin, T.J.
1994-02-01
Various technologies and designs are being considered to serve as subsurface barriers to confine or control contaminant migration from underground waste storage or disposal structures containing radioactive and hazardous wastes. Alternatives including direct-coupled flood and controlled advection designs are described as preconceptual examples. Prototype geotechnical equipment for testing and demonstration of these alternative designs tested at the Hanford Geotechnical Development and Test Facility and the Hanford Small-Tube Lysimeter Facility include mobile high-pressure injectors and pumps, mobile transport and pumping units, vibratory and impact pile drivers, and mobile batching systems. Preliminary laboratory testing of barrier materials and additive sequestering agents have been completed and are described.
Application of a Particle Method to the Advection-Diffusion-Reaction Equation
NASA Astrophysics Data System (ADS)
Paster, A.; Bolster, D.; Benson, D. A.
2012-12-01
A reaction between two chemical species can only happen if molecules collide and react. Thus, the mixing of a system can become a limiting factor in the onset of reaction. Solving for reaction rate in a well-mixed system is typically a straightforward task. However, when incomplete mixing kicks in, obtaining a solution becomes more challenging. Since reaction can only happen in regions where both reactants co-exist, the incomplete mixing may slow down the reaction rate, when compared to a well-mixed system. The effect of incomplete mixing upon reaction is a highly important aspect of various processes in natural and engineered systems, ranging from mineral precipitation in geological formations to groundwater remediation in aquifers. We study a relatively simple system with a bi-molecular irreversible kinetic reaction A+B → Ø where the underlying transport of reactants is governed by an advection-diffusion equation, and the initial concentrations are given in terms of an average and a perturbation. Such a system does not have an analytical solution to date, even for the zero advection case. We model the system by a Monte Carlo particle tracking method, where particles represent some reactant mass. In this method, diffusion is modeled by a random walk of the particles, and reaction is modeled by annihilation of particles. The probability of the annihilation is proportional to the reaction rate constant and the probability density associated with particle co-location. We study the numerical method in depth, characterizing typical numerical errors and time step restrictions. In particular, we show that the numerical method converges to the advection-diffusion-reaction equation at the limit Δt →0. We also rigorously derive the relationship between the initial number of particles in the system and the initial concentrations perturbations represented by that number. We then use the particle simulations of zero-advection system to demonstrate the well
A boundary element-Random walk model of mass transport in groundwater
Kemblowski, M.
1986-01-01
A boundary element solution to the convective mass transport in groundwater is presented. This solution produces a continuous velocity field and reduces the amount of data preparation time and bookkeeping. By combining this solution and the random walk procedure, a convective-dispersive mass transport model is obtained. This model may be easily used to simulate groundwater contamination problems. The accuracy of the boundary element model has been verified by reproducing the analytical solution to a two-dimensional convective mass transport problem. The method was also used to simulate a convective-dispersive problem. ?? 1986.
Prickett, T.A.
1980-04-01
Specifications are given which are necessary to develop a three-dimensional numerical model capable of simulating regional mass transport of radionuclides from a deep waste repository. The model to be developed will include all of the significant mass transport processes including flow, chemical, and thermal advection, mechanical dispersion, molecular diffusion, ion exchange reactions, and radioactive decay. The model specifications also include that density and viscosity fluid properties be functions of pressure, temperature, and concentration and take into account fluid and geologic heterogenieties by allowing possible assignment of individual values to every block of the model. The model specifications furthermore include the repository shape, input/output information, boundary conditions, and the need for documentation and a user's manual. Model code validation can be accomplished with the included known analytical or laboratory solutions. It is recommended that an existing finite-difference model (developed by INTERCOMP and INTERA, Inc.) be used as a starting point either as an acceptable basic code for modification or as a pattern for the development of a completely different numerical scheme. A ten-step plan is given to outline the general procedure for development of the code.
Chaotic advection in 2D anisotropic porous media
NASA Astrophysics Data System (ADS)
Varghese, Stephen; Speetjens, Michel; Trieling, Ruben; Toschi, Federico
2015-11-01
Traditional methods for heat recovery from underground geothermal reservoirs employ a static system of injector-producer wells. Recent studies in literature have shown that using a well-devised pumping scheme, through actuation of multiple injector-producer wells, can dramatically enhance production rates due to the increased scalar / heat transport by means of chaotic advection. However the effect of reservoir anisotropy on kinematic mixing and heat transport is unknown and has to be incorporated and studied for practical deployment in the field. As a first step, we numerically investigate the effect of anisotropy (both magnitude and direction) on (chaotic) advection of passive tracers in a time-periodic Darcy flow within a 2D circular domain driven by periodically reoriented diametrically opposite source-sink pairs. Preliminary results indicate that anisotropy has a significant impact on the location, shape and size of coherent structures in the Poincare sections. This implies that the optimal operating parameters (well spacing, time period of well actuation) may vary strongly and must be carefully chosen so as to enhance subsurface transport. This work is part of the research program of the Foundation for Fundamental Research on Matter (FOM), which is part of Netherlands Organisation for Scientific Research (NWO). This research program is co-financed by Shell Global Solutions International B.V.
Subcontinuum mass transport of condensed hydrocarbons in nanoporous media
Falk, Kerstin; Coasne, Benoit; Pellenq, Roland; Ulm, Franz-Josef; Bocquet, Lydéric
2015-01-01
Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to account for their ultra-low permeability and complexity. Here, we use molecular simulation and statistical mechanics to show that continuum description—Darcy's law—fails to predict transport in shales nanoporous matrix (kerogen). The non-Darcy behaviour arises from strong adsorption in kerogen and the breakdown of hydrodynamics at the nanoscale, which contradict the assumption of viscous flow. Despite this complexity, all permeances collapse on a master curve with an unexpected dependence on alkane length. We rationalize this non-hydrodynamic behaviour using a molecular description capturing the scaling of permeance with alkane length and density. These results, which stress the need for a change of paradigm from classical descriptions to nanofluidic transport, have implications for shale gas but more generally for transport in nanoporous media. PMID:25901931
Bachand, P.A.M.; S. Bachand,; Fleck, Jacob A.; Anderson, Frank E.; Windham-Myers, Lisamarie
2014-01-01
The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flowrates and tracer concentrations atwetland inflows and outflows. We used two ideal reactormodel solutions, a continuous flowstirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these nonideal agricultural wetlands in which check ponds are in series. Using a fluxmodel, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment–water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemicalmechanisms affecting dissolved constituent cycling in the root zone. In addition,our understanding of internal
Bachand, P A M; Bachand, S; Fleck, J; Anderson, F; Windham-Myers, L
2014-06-15
The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flow rates and tracer concentrations at wetland inflows and outflows. We used two ideal reactor model solutions, a continuous flow stirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these non-ideal agricultural wetlands in which check ponds are in series. Using a flux model, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment-water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemical mechanisms affecting dissolved constituent cycling in the root zone. In addition, our understanding of
Measurements of the transport efficiency of the fragment mass analyzer
Back, B.B.; Blumenthal, D.J.; Davids, C.N.
1995-08-01
Extensive calculations of the transport of reaction products were carried out during the design phase of the instrument using the computer code GIOS. These show that the energy acceptance depends strongly on the angular deviation from the optical axis of the instrument. In order to reliably measure cross sections using this instrument it is therefore necessary to verify these calculations empirically.
Mass transfer and transport of radionuclides in fractured porous rock
Ahn, Joonhong
1988-04-01
Analytical studies are made to predict space-time dependent concentrations of radionuclides transported through water-saturated fractured porous rock. A basic model, which is expected to generate conservative results when used in long-term safety assessment of geologic repositories for radioactive waste, is established. Applicability and limitations of the model are investigated. 67 refs., 54 figs., 3 tabs.
Mass transport in salt repositories: Steady-state transport through interbeds
Hwang, Y.; Lee, W.W.-L.; Chambre, P.L.; Pigford, T.H. . Dept. of Nuclear Engineering)
1989-03-01
Salt has long been a candidate for geologic disposal of nuclear waste. Because salt is extremely soluble in water, the existence of rock salt in the ground atest to the long-term stability of the salt. Both bedded salt and salt domes have been considered for nuclear waste disposal in the United States and Europe. While the salt is known to be quite pure in salt domes, bedded salt is interlaced with beds of sediments. Traditionally rock salt has not been considered water-conducting, but sediments layers would be classical porous media, capable of conducting water. Therefore there is interest in determining whether interbeds in bedded salt constitute pathway for radionuclide migration. In this report we consider steady-state migration of radionuclides from a single waste cylinder into a single interbed. Two approaches are used. In 1982 Neretnieks proposed an approach for calculating the steady-state transport of oxidants to a copper container. We have adapted that approach for calculating steady-state radionuclide migration away from the waste package, as a first approximation. We have also analyzed the problem of time-dependent radionuclide diffusion from a container through a backfill layer into a fracture, and we used the steady-state solution from that problem for comparison. Section 2 gives a brief summary of the geology of interbeds in bedded salt. Section 3 presents the mass transfer resistances approach of Neretnieks, summarizing the formulation and giving numerical illustrations of the steady-state two-dimensional diffusion analysis. Section 4 gives a brief statement of the steady-state result from a related analysis. Conclusions are stated in Section 5. 13 refs., 5 figs., 2 tabs.
3D Flow Visualization Using Texture Advection
NASA Technical Reports Server (NTRS)
Kao, David; Zhang, Bing; Kim, Kwansik; Pang, Alex; Moran, Pat (Technical Monitor)
2001-01-01
Texture advection is an effective tool for animating and investigating 2D flows. In this paper, we discuss how this technique can be extended to 3D flows. In particular, we examine the use of 3D and 4D textures on 3D synthetic and computational fluid dynamics flow fields.
How Hydrate Saturation Anomalies are Diffusively Constructed and Advectively Smoothed
NASA Astrophysics Data System (ADS)
Rempel, A. W.; Irizarry, J. T.; VanderBeek, B. P.; Handwerger, A. L.
2015-12-01
The physical processes that control the bulk characteristics of hydrate reservoirs are captured reasonably well by long-established model formulations that are rooted in laboratory-verified phase equilibrium parameterizations and field-based estimates of in situ conditions. More detailed assessments of hydrate distribution, especially involving the occurrence of high-saturation hydrate anomalies have been more difficult to obtain. Spatial variations in sediment properties are of central importance for modifying the phase behavior and promoting focussed fluid flow. However, quantitative predictions of hydrate anomaly development cannot be made rigorously without also addressing the changes in phase behavior and mechanical balances that accompany changes in hydrate saturation level. We demonstrate how pore-scale geometrical controls on hydrate phase stability can be parameterized for incorporation in simulations of hydrate anomaly development along dipping coarse-grained layers embedded in a more fine-grained background that is less amenable to fluid transport. Model simulations demonstrate how hydrate anomaly growth along coarse-layer boundaries is promoted by diffusive gas transport from the adjacent fine-grained matrix, while advective transport favors more distributed growth within the coarse-grained material and so effectively limits the difference between saturation peaks and background levels. Further analysis demonstrates how sediment contacts are unloaded once hydrate saturation reaches sufficient levels to form a load-bearing skeleton that can evolve to produce segregated nodules and lenses. Decomposition of such growth forms poses a significant geohazard that is expected to be particularly sensitive to perturbations induced by gas extraction. The figure illustrates the predicted evolution of hydrate saturation Sh in a coarse-grained dipping layer showing how prominent bounding hydrate anomalies (spikes) supplied by diffusive gas transport at early times
Mass and heat transport in direct methanol fuel cells
NASA Astrophysics Data System (ADS)
Ismail, A.; Kamarudin, S. K.; Daud, W. R. W.; Masdar, S.; Yosfiah, M. R.
The direct methanol fuel cell (DMFC) is a better alternative to the conventional battery. The DMFC offers several advantages, namely, faster building of potential and longer-lasting fuel, however, there are still several issues that need to be addressed to design a better DMFC system. This article is a wide-ranging review of the most up-to-date studies on mass and heat transfer in the DMFC. The discussion will be focused on the critical problems limiting the performance of DMFCs. In addition, a technique for upgrading the DMFC with an integrated system will be presented, along with existing numerical models for modeling mass and heat transfer as well as cell performance.
NASA Astrophysics Data System (ADS)
Henri, Christopher V.; Fernàndez-Garcia, Daniel
2015-12-01
The interplay between the spatial variability of the aquifer hydraulic properties, mass transfer due to sub-grid heterogeneity and chemical reactions often complicates reactive transport simulations. It is well documented that hydro-biochemical properties are ubiquitously heterogeneous and that diffusion and slow advection at the sub-grid scale typically leads to the conceptualization of an aquifer as a multi-porosity system. Within this context, chemical reactions taking place in mobile/immobile water regions can be substantially different between each other. This paper presents a particle-based method that can efficiently simulate heterogeneity, network reactions and multi-rate mass transfer. The approach is based on the development of transition probabilities that describe the likelihood that particles belonging to a given species and mobile/immobile domain at a given time will be transformed into another species and mobile/immobile domain afterwards. The joint effect of mass transfer and sequential degradation is shown to be non-trivial. A characteristic rebound of degradation products can be observed. This late rebound of concentrations is not driven by any change in the flow regime (e.g., pumping ceases in the pump-and-treat remediation strategy) but due to the natural interplay between mass transfer and chemical reactions. To illustrate that the method can simultaneously represent mass transfer, spatially varying properties and network reactions without numerical problems, we have simulated the degradation of tetrachloroethylene (PCE) in a three-dimensional fully heterogeneous aquifer subjected to rate-limited mass transfer. Two types of degradation modes were considered to compare the effect of an active biofilm with that of clay pods present in the aquifer. Results of the two scenarios display significantly differences. Biofilms that promote the degradation of compounds in an immobile region are shown to significantly enhance degradation, rapidly producing
Pfeuffer, Kevin P.; Ray, Steven J.; Hieftje, Gary M.
2014-01-01
Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last nine years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification due to the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass-spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet. PMID:24658804
On the optimum fields and bounds for heat and mass transport in two turbulent flows
NASA Astrophysics Data System (ADS)
Vitanov, Nikolay
2011-12-01
The optimum theory of turbulence is one of the few tools for obtaining analytical results for transport of heat, mass or momentum by turbulent flows. This is achieved by asymptotic theory which is valid for large values of the characteristic numbers of the investigated fluid system. For small and intermediate values of the Reynolds, Rayleigh or Taylor numbers we have to solve numerically the Euler-Lagrange equations of the corresponding variational problems. Below we discuss numerical results from the application of the Howard-Busse method of the optimum theory of turbulence to two problems: convective heat transport in non-rotating and rotating fluid layer and mass transport in pipe flow. We obtain profiles of the optimum fields and discuss the evolution of the thickness of the boundary layers as well as present our first results about the lower bound on the mass transport in a pipe flow.
New mass transport elements and components for the NIST IAQ Model
Axley, J.W.
1995-07-01
This report presents new mass transport elements for the next generation of the NIST IAQ Model that may be used to model (1) homogenous (bulk-air) chemistry within well-mixed chamber, (2) aerosol mass transport within well-mixed chambers and fractional particle filtration in building filtration devices, and (3) heterogeneous (surface-related) physical processes and chemical transformations including those governing the behavior of gas-phase air cleaning devices. In an effort to maintain rigor, generality, and flexibility, each transport process is formulated in terms of the elemental mass transport step that together govern the overall process. In this way, the more complex processes may be represented as component equations that are assembled from fundamental element equations.
Transport of magnetic flux and mass in Saturn's inner magnetosphere
NASA Astrophysics Data System (ADS)
Lai, H. R.; Russell, C. T.; Jia, Y. D.; Wei, H. Y.; Dougherty, M. K.
2016-04-01
It is well accepted that cold plasma sourced by Enceladus is ultimately lost to the solar wind, while the magnetic flux convecting outward with the plasma must return to the inner magnetosphere. However, whether the interchange or reconnection, or a combination of the two processes is the dominant mechanism in returning the magnetic flux is still under debate. Initial Cassini observations have shown that the magnetic flux returns in the form of flux tubes in the inner magnetosphere. Here we investigate those events with 10 year Cassini magnetometer data and confirm that their magnetic signatures are determined by the background plasma environments: inside (outside) the plasma disk, the returning magnetic field is enhanced (depressed) in strength. The distribution, temporal variation, shape, and transportation rate of the flux tubes are also characterized. The flux tubes break into smaller ones as they convect in. The shape of their cross section is closer to circular than fingerlike as produced in the simulations based on the interchange mechanism. In addition, no sudden changes in any flux tube properties can be found at the "boundary" which has been claimed to separate the reconnection and interchange-dominant regions. On the other hand, reasonable cold plasma loss rate and outflow velocity can be obtained if the transport rate of the magnetic flux matches the reconnection rate, which supports reconnection alone as the dominant mechanism in unloading the cold plasma from the inner magnetosphere and returning the magnetic flux from the tail.
A Global Assessment of Accelerations in Mass Transport of Surface Geophysical Fluid
NASA Astrophysics Data System (ADS)
Wu, X.; Heflin, M. B.
2015-12-01
Mass transport in the Earth's surface geophysical fluid layer has complex spatiotemporal patterns. The GRACE gravity mission provides an unprecedented global capability to monitor this important process with high accuracy and resolution. Accurate assessments of global mass transport patterns and budget also depend critically on changes in degree-1 coefficients (geocenter motion) and in Earth's dynamic oblateness coefficient J2. We combine GRACE measurements, time series of GNSS data, JPL's ECCO ocean bottom pressure model, and high-resolution loose a priori models of mass variation regimes to derive complete spherical harmonic spectra of detrended mass variations up to degree and order 180. Mass accelerations are estimated along with linear, annual, semiannual, and the 161-day tidal aliasing components from coefficient time series. The appropriateness of a priori information and estimate uncertainties are further evaluated by variance component estimation and residual statistics of fitting the time series. During the GRACE data period of 2002.2-2015.0, accelerations in mass transport are geographically uneven with significant positive or negative accelerations in various parts of the world. While Greenland and West Antarctica show strong accelerated mass losses, Alaska and the Arctic Ocean have significant positive accelerations with reversals of earlier mass loss trends. No evidence of non-Arctic global mean sea level acceleration due to mass has been found. Depending on region, some estimated accelerations are also not steady over time due to large irregular and interannual variations.
Analytical solution of two-dimensional solute transport in an aquifer-aquitard system.
Zhan, Hongbin; Wen, Zhang; Huang, Guanhua; Sun, Dongmin
2009-07-21
This study deals with two-dimensional solute transport in an aquifer-aquitard system by maintaining rigorous mass conservation at the aquifer-aquitard interface. Advection, longitudinal dispersion, and transverse vertical dispersion are considered in the aquifer. Vertical advection and diffusion are considered in the aquitards. The first-type and the third-type boundary conditions are considered in the aquifer. This study differs from the commonly used averaged approximation (AA) method that treats the mass flux between the aquifer and aquitard as an averaged volumetric source/sink term in the governing equation of transport in the aquifer. Analytical solutions of concentrations in the aquitards and aquifer and mass transported between the aquifer and upper or lower aquitard are obtained in the Laplace domain, and are subsequently inverted numerically to yield results in the real time domain (the Zhan method). The breakthrough curves (BTCs) and distribution profiles in the aquifer obtained in this study are drastically different from those obtained using the AA method. Comparison of the numerical simulation using the model MT3DMS and the Zhan method indicates that the numerical result differs from that of the Zhan method for an asymmetric case when aquitard advections are at the same direction. The AA method overestimates the mass transported into the upper aquitard when an upward advection exists in the upper aquitard. The mass transported between the aquifer and the aquitard is sensitive to the aquitard Peclet number, but less sensitive to the aquitard diffusion coefficient. PMID:19477033
Healy, R.W.; Russell, T.F.
1998-01-01
We extend the finite-volume Eulerian-Lagrangian localized adjoint method (FVELLAM) for solution of the advection-dispersion equation to two dimensions. The method can conserve mass globally and is not limited by restrictions on the size of the grid Peclet or Courant number. Therefore, it is well suited for solution of advection-dominated ground-water solute transport problems. In test problem comparisons with standard finite differences, FVELLAM is able to attain accurate solutions on much coarser space and time grids. On fine grids, the accuracy of the two methods is comparable. A critical aspect of FVELLAM (and all other ELLAMs) is evaluation of the mass storage integral from the preceding time level. In FVELLAM this may be accomplished with either a forward or backtracking approach. The forward tracking approach conserves mass globally and is the preferred approach. The backtracking approach is less computationally intensive, but not globally mass conservative. Boundary terms are systematically represented as integrals in space and time which are evaluated by a common integration scheme in conjunction with forward tracking through time. Unlike the one-dimensional case, local mass conservation cannot be guaranteed, so slight oscillations in concentration can develop, particularly in the vicinity of inflow or outflow boundaries. Published by Elsevier Science Ltd.
Modeling Transport of Secondary Ion Fragments into a Mass Spectrometer
NASA Astrophysics Data System (ADS)
Warmenhoven, J.; Demarche, J.; Palitsin, V.; Kirkby, K. J.; Webb, R. P.
The Surrey Ion Beam Centre was awarded the Engineering and Physical Sciences Research Council (EPSRC) grant for "Promoting Cross Disciplinary Research: Engineering and Physical Sciences and Social Sciences" allowing continued research into the characteristics of desorption of secondary ions by the impact of fast primary ions in the ambient pressure at the sub-micron scale. To carry out this research a new beamline has been constructed consisting of a time-of-flight secondary ion mass spectrometer combined with the current 2MV Tandem accelerator. This research has already returned many significant results such as the first simultaneous SIMS, PIXE and RBS measurement preformed on an organic sample in vacuum. However, further optimization and validation of the new beamline is still being worked on. This work focuses on the optimization of the end station geometry to allow for high sensitivity ambient pressure measurements. It is concluded that a common geometry can be adopted for a wide variety of smooth samples to ensure optimum sensitivity provided a hard edge of the sample can be found to place the mass spectrometer capillary near.
Distributed Parallel Particle Advection using Work Requesting
Muller, Cornelius; Camp, David; Hentschel, Bernd; Garth, Christoph
2013-09-30
Particle advection is an important vector field visualization technique that is difficult to apply to very large data sets in a distributed setting due to scalability limitations in existing algorithms. In this paper, we report on several experiments using work requesting dynamic scheduling which achieves balanced work distribution on arbitrary problems with minimal communication overhead. We present a corresponding prototype implementation, provide and analyze benchmark results, and compare our results to an existing algorithm.
DEVELOPMENT AND DEMONSTRATION OF A BIDIRECTIONAL ADVECTIVE FLUX METER FOR SEDIMENT-WATER INTERFACE
A bidirectional advective flux meter for measuring water transport across the sediment-water interface has been successfully developed and field tested. The flow sensor employs a heat-pulse technique combined with a flow collection funnel for the flow measurement. Because the dir...
NASA Astrophysics Data System (ADS)
Ng, Chiu-On
2000-01-01
In this paper, an analytical study on the advective-dispersive transport of a chemical contaminant resulting from the discharge of contaminated fine solid particles into a two-dimensional, steady and uniform turbulent open-channel flow is presented. Because of sorptive exchange, the transport of the chemical cloud is affected by that of the suspended particulates. Such a relationship has so far not been explicitly established by intuitive arguments. The effective transport equations are formally derived by an extended method of homogenization. It is found that over a long time scale the fall velocity will delay the sediment advection, and the advection velocity and dispersion coefficient for the chemical transport will change with space and time according to the local sediment concentration. Numerical results confirm that the centers of mass of the sediment and dissolved phase clouds are not advancing at the same speed, and the dispersion of the chemical is enhanced by the local retardation factor.
High Order Semi-Lagrangian Advection Scheme
NASA Astrophysics Data System (ADS)
Malaga, Carlos; Mandujano, Francisco; Becerra, Julian
2014-11-01
In most fluid phenomena, advection plays an important roll. A numerical scheme capable of making quantitative predictions and simulations must compute correctly the advection terms appearing in the equations governing fluid flow. Here we present a high order forward semi-Lagrangian numerical scheme specifically tailored to compute material derivatives. The scheme relies on the geometrical interpretation of material derivatives to compute the time evolution of fields on grids that deform with the material fluid domain, an interpolating procedure of arbitrary order that preserves the moments of the interpolated distributions, and a nonlinear mapping strategy to perform interpolations between undeformed and deformed grids. Additionally, a discontinuity criterion was implemented to deal with discontinuous fields and shocks. Tests of pure advection, shock formation and nonlinear phenomena are presented to show performance and convergence of the scheme. The high computational cost is considerably reduced when implemented on massively parallel architectures found in graphic cards. The authors acknowledge funding from Fondo Sectorial CONACYT-SENER Grant Number 42536 (DGAJ-SPI-34-170412-217).
NASA Astrophysics Data System (ADS)
Ballester, Joan; Bordoni, Simona; Petrova, Desislava; Rodó, Xavier
2016-06-01
The oscillatory nature of El Niño-Southern Oscillation results from an intricate superposition of near-equilibrium balances and out-of-phase disequilibrium processes between the ocean and the atmosphere. The main objective of the present work is to perform an exhaustive spatiotemporal analysis of the upper ocean heat budget in an ensemble of state-of-the-art ocean assimilation products. We put specific emphasis on the ocean heat advection mechanisms, and their representation in individual ensemble members and in the different stages of the ENSO oscillation leading to EN events. Our analyses consistently show that the initial subsurface warming in the western equatorial Pacific is advected to the central Pacific by the equatorial undercurrent, which, together with the equatorward advection associated with anomalies in both the meridional temperature gradient and circulation at the level of the thermocline, explains the heat buildup in the central Pacific during the recharge phase. We also find that the recharge phase is characterized by an increase of meridional tilting of the thermocline, as well as a southward upper-ocean cross-equatorial mass transport resulting from Ekman-induced anomalous vertical motion in the off-equatorial regions. Although differences between data sets are generally small, and anomalies tend to have the same sign, the differences in the magnitude of the meridional term are seen to be key for explaining the different propagation speed of the subsurface warming tendency along the thermocline. The only exception is GECCO, which does not produce the patterns of meridional surface Ekman divergence (subsurface Sverdrup convergence) in the western and central equatorial Pacific.
NASA Astrophysics Data System (ADS)
Ebner, Pirmin Philipp; Andreoli, Christian; Schneebeli, Martin; Steinfeld, Aldo
2015-12-01
Snow at or close to the surface commonly undergoes temperature gradient metamorphism under advective flow, which alters its microstructure and physical properties. A functional understanding of this process is essential for many disciplines, from modeling the effects of snow on regional and global climate to assessing avalanche formation. Time-lapse X-ray microtomography was applied to investigate the structural dynamics of temperature gradient snow metamorphism exposed to an advective airflow in controlled laboratory conditions. Experiments specifically analyzed sublimation and deposition of water vapor on the ice structure. In addition, an analysis of the ice-air interface dynamics was carried out using a macroscopic equivalent model of heat and water vapor transport through a snow layer. The results indicate that sublimation of the ice matrix dominated for flow rates < 10-6 m3 s-1 while during increased mass flow rates the water vapor deposition supplied by the advective flow counteracted sublimation. A flow rate dependence of water vapor deposition at the ice interface was observed, asymptotically approaching an average estimated maximum deposition rate on the whole sample of 1.05 · 10-4 kg m-3 s-1. The growth of microsized whisker-like crystals on larger ice crystals was detected on microscope photographs, leading to an increase of the specific surface area and thus suggest a change of the physical and optical properties of the snow. The estimated values of the curvature effect of the ice crystals and the interface kinetic coefficient are in good agreement with previously published values.
Numerical modeling of DNA-chip hybridization with chaotic advection
Raynal, Florence; Beuf, Aurélien; Carrière, Philippe
2013-01-01
We present numerical simulations of DNA-chip hybridization, both in the “static” and “dynamical” cases. In the static case, transport of free targets is limited by molecular diffusion; in the dynamical case, an efficient mixing is achieved by chaotic advection, with a periodic protocol using pumps in a rectangular chamber. This protocol has been shown to achieve rapid and homogeneous mixing. We suppose in our model that all free targets are identical; the chip has different spots on which the probes are fixed, also all identical, and complementary to the targets. The reaction model is an infinite sink potential of width dh, i.e., a target is captured as soon as it comes close enough to a probe, at a distance lower than dh. Our results prove that mixing with chaotic advection enables much more rapid hybridization than the static case. We show and explain why the potential width dh does not play an important role in the final results, and we discuss the role of molecular diffusion. We also recover realistic reaction rates in the static case. PMID:24404027
Backward fractional advection dispersion model for contaminant source prediction
NASA Astrophysics Data System (ADS)
Zhang, Yong; Meerschaert, Mark M.; Neupauer, Roseanna M.
2016-04-01
The forward Fractional Advection Dispersion Equation (FADE) provides a useful model for non-Fickian transport in heterogeneous porous media. The space FADE captures the long leading tail, skewness, and fast spreading typically seen in concentration profiles from field data. This paper develops the corresponding backward FADE model, to identify source location and release time. The backward method is developed from the theory of inverse problems, and then explained from a stochastic point of view. The resultant backward FADE differs significantly from the traditional backward Advection Dispersion Equation (ADE) because the fractional derivative is not self-adjoint and the probability density function for backward locations is highly skewed. Finally, the method is validated using tracer data from a well-known field experiment, where the peak of the backward FADE curve predicts source release time, while the median or a range of percentiles can be used to determine the most likely source location for the observed plume. The backward ADE cannot reliably identify the source in this application, since the forward ADE does not provide an adequate fit to the concentration data.
NASA Astrophysics Data System (ADS)
Mertia, R. S.; Santra, Priyabrata; Kandpal, B. K.; Prasad, R.
2010-11-01
Wind erosion is an active land degradation process in the Indian Thar Desert and severe dust storm events during hot summer months in the region are very common. Assessment of soil loss due to dust storm events from major land use systems of the Indian Thar Desert is highly essential for proper environmental planning. Characterization of the mass-height profile of wind eroded aeolian sediment is an important step to compute soil loss/mass transport but was not previously studied in the region. In the present study, aeolian mass fluxes (kg m -2) at different heights from soil surface were measured at two major rangelands in the Indian Thar Desert: Overgrazing rangeland at Jaisalmer (26°55'N and 70°57'E), and controlled grazing rangeland at Chandan (27°01'N and 71°01'E). Evaluation of several mass-height profile models revealed that a power decay function [ q( z) = az-b, where q( z) is the measured mass flux at an height of z (m) from soil surface; a and b are parameters of the equation] was best to characterize the mass-height relationship of aeolian sediments from the Indian Thar Desert. The average mass transport rate (kg m -1 day -1) or the total soil loss during hot summer months was significantly higher at the overgrazed rangeland site than at the controlled grazing rangeland site. Therefore, protection of existing rangelands, which comprise about 80% geographical area of the Indian Thar Desert may check the land degradation process due to wind erosion.
Temporal variability of mass transport across Canary Islands Channels
NASA Astrophysics Data System (ADS)
Marrero-Díaz, Ángeles; Rodríguez-Santana, Ángel; José Machín, Francisco; García-Weil, Luis; Sangrà, Pablo; Vélez-Belchí, Pedro; Fraile-Nuez, Eugenio
2014-05-01
The equatorward flowing Canary Current (CC) is the main feature of the circulation in the Canary Islands region. The CC flow perturbation by the Canary Islands originate the Canary Eddy Corridor which is the major pathway for long lived eddies in the subtropical North Atlantic (Sangrà et al., 2009, DSR). Therefore the variability of the CC passing through the Canary Archipelago will have both local and regional importance. Past studies on the CC variability trough the Canary Islands point out a clearly seasonal variability (Fraile-Nuez et al, 2010 (JGR); Hernández-Guerra et al, 2002 (DSR)). However those studies where focused on the eastern islands channels missing the variability through the western island channels which are the main source of long lived eddies. In order to fill this gap from November 2012 until September 2013 we conducted trimonthly surveys crossing the whole islands channels using opportunity ships (Naviera Armas Ferries). XBT and XCTD where launched along the cross channels transects. Additionally a closed box circling the Archipelago was performed on October 2013 as part of the cruise RAPROCAN-2013 (IEO) using also XBT and XCTD. Dynamical variables where derived inferring salinity from S(T,p) analytical relationships for the region updated with new XCTD data. High resolution, vertical sections of temperature, potential density, geostrophic velocity and transport where obtained. Our preliminary results suggest that the CC suffer a noticeable acceleration in those islands channels where eddy shedding is more frequent. They also indicate a clearly seasonal variability of the flows passing the islands channels. With this regard we observed significant differences on the obtained seasonal variability with respect the cited past studies on the eastern islands channel (Lanzarote / Fuerteventura - Africa coast). This work was co-funded by Canary Government (TRAMIC project: PROID20100092) and the European Union (FEDER).
NASA Astrophysics Data System (ADS)
Marnela, Marika; Rudels, Bert; Goszczko, Ilona; Beszczynska-Möller, Agnieszka; Schauer, Ursula
2016-04-01
The exchanges between the Nordic Seas and the Arctic Ocean are important for the ocean circulation and climate. Transports are here estimated using summer hydrographic data from the Greenland Sea and the Fram Strait. Geostrophic transports are computed from hydrographic sections at 75°N in the Greenland Sea and at about 79°N in the Fram Strait. Geostrophic velocities are adjusted with summer velocities derived from Argo floats, and four conservation constraints are applied to a box closed by the two sections. The estimated net volume transports are 0.8 ± 1.5 Sv southward. Net freshwater transports through the Greenland Sea section are estimated at 54 ± 20 mSv and through the Fram Strait section at 66 ± 9 mSv. Heat loss in the area between the two sections is estimated at 9 ± 12 TW. Convection depths in the Greenland Sea are estimated from observations and vary between about 200 and 2000 dbar showing no trend. Water mass properties in the Greenland Sea are affected both by convection and lateral mixing. Vertical mixing is estimated from hydrography and based on it about 1 Sv of diluted Arctic Ocean waters are estimated to enter the Greenland Sea. The properties of Atlantic, intermediate, and deep waters are studied. Deep water properties are defined using water mass triangles and are subject to decadal changes.
Sun, Pengzhan; Wang, Kunlin; Zhu, Hongwei
2016-03-23
Significant achievements have been made on the development of next-generation filtration and separation membranes using graphene materials, as graphene-based membranes can afford numerous novel mass-transport properties that are not possible in state-of-art commercial membranes, making them promising in areas such as membrane separation, water desalination, proton conductors, energy storage and conversion, etc. The latest developments on understanding mass transport through graphene-based membranes, including perfect graphene lattice, nanoporous graphene and graphene oxide membranes are reviewed here in relation to their potential applications. A summary and outlook is further provided on the opportunities and challenges in this arising field. The aspects discussed may enable researchers to better understand the mass-transport mechanism and to optimize the synthesis of graphene-based membranes toward large-scale production for a wide range of applications.
Sun, Pengzhan; Wang, Kunlin; Zhu, Hongwei
2016-03-23
Significant achievements have been made on the development of next-generation filtration and separation membranes using graphene materials, as graphene-based membranes can afford numerous novel mass-transport properties that are not possible in state-of-art commercial membranes, making them promising in areas such as membrane separation, water desalination, proton conductors, energy storage and conversion, etc. The latest developments on understanding mass transport through graphene-based membranes, including perfect graphene lattice, nanoporous graphene and graphene oxide membranes are reviewed here in relation to their potential applications. A summary and outlook is further provided on the opportunities and challenges in this arising field. The aspects discussed may enable researchers to better understand the mass-transport mechanism and to optimize the synthesis of graphene-based membranes toward large-scale production for a wide range of applications. PMID:26797529
A PERFECT MATCH CONDITION FOR POINT-SET MATCHING PROBLEMS USING THE OPTIMAL MASS TRANSPORT APPROACH
CHEN, PENGWEN; LIN, CHING-LONG; CHERN, I-LIANG
2013-01-01
We study the performance of optimal mass transport-based methods applied to point-set matching problems. The present study, which is based on the L2 mass transport cost, states that perfect matches always occur when the product of the point-set cardinality and the norm of the curl of the non-rigid deformation field does not exceed some constant. This analytic result is justified by a numerical study of matching two sets of pulmonary vascular tree branch points whose displacement is caused by the lung volume changes in the same human subject. The nearly perfect match performance verifies the effectiveness of this mass transport-based approach. PMID:23687536
Pebay, Cécile; Sella, Catherine; Thouin, Laurent; Amatore, Christian
2013-12-17
Mass transport at infinite regular arrays of microband electrodes was investigated theoretically and experimentally in unstirred solutions. Even in the absence of forced hydrodynamics, natural convection limits the convection-free domain up to which diffusion layers may expand. Hence, several regimes of mass transport may take place according to the electrode size, gap between electrodes, time scale of the experiment, and amplitude of natural convection. They were identified through simulation by establishing zone diagrams that allowed all relative contributions to mass transport to be delineated. Dynamic and steady-state regimes were compared to those achieved at single microband electrodes. These results were validated experimentally by monitoring the chronoamperometric responses of arrays with different ratios of electrode width to gap distance and by mapping steady-state concentration profiles above their surface through scanning electrochemical microscopy. PMID:24283775
NASA Astrophysics Data System (ADS)
Santos, Isaac R.; Eyre, Bradley D.; Glud, Ronnie N.
2012-11-01
Porewater flow enhances mineralization rates in organic-poor permeable sands. Here, a series of sediment column experiments were undertaken to assess the potential effect of advective porewater transport on denitrification in permeable carbonate sands collected from Heron Island (Great Barrier Reef). Experimental conditions (flow path length, advection rate, and temperature) were manipulated to represent conditions similar to near shore tropical environments. HgCl2-poisoned controls were used to assess whether reactions were microbially mediated. Overall, significant correlations were found between oxygen consumption and N2 production. The N:O2 slope of 0.114 implied that about 75% of all the nitrogen mineralized was denitrified. A 4-fold increase in sediment column length (from 10 to 40 cm) resulted in an overall increase in oxygen consumption (1.6-fold), TCO2 production (1.8-fold), and denitrification (1.9-fold). Oxic respiration increased quickly until advection reached 80 L m-2 h-1 and then plateaued at higher advection rates. Interestingly, denitrification peaked (up to 336 μmol N2 m-2 h-1) at intermediate advection rates (30-80 L m-2 h-1). We speculate that intermediate advection rates enhance the development of microniches (i.e., steep oxygen gradients) within porous carbonate sands, perhaps providing optimum conditions for denitrification. The denitrification peak fell within the broad range of advection rates (often on scales of 1-100 L m-2 h-1) typically found on continental shelves implying that carbonate sands may play a major, but as yet unquantified, role in oceanic nitrogen budgets.
What controls the mass transport by mode-2 internal solitary-like waves?
NASA Astrophysics Data System (ADS)
Deepwell, David; Stastna, Marek
2016-04-01
Horizontally propagating internal waves are a regular occurrence in the coastal ocean. Their most commonly observed vertical structure is mode-1 in which isopycnals rise and fall in concert at all depths. Second mode waves, where isopycnals expand from and contract toward the pycnocline centre, have been found in recent observations to occur more frequently than previously thought. For the more common convex configuration, these waves mix the pycnocline, and under certain conditions form recirculating cores which efficiently transport material. In the laboratory, mode-2 waves are easily formed by releasing a mixed region into an ambient stratification. Using high resolution, three dimensional, direct numerical simulations of a laboratory configuration we describe the mass transport efficiency of mode-2 waves under a variety of different parameter regimes and initializations. We identify pycnocline configurations for which transport is especially efficient, and explore the structure of recirculating cores during their formation, propagation and disintegration and its implications on mass transport.
Dense-gas dispersion advection-diffusion model
Ermak, D.L.
1992-07-01
A dense-gas version of the ADPIC particle-in-cell, advection- diffusion model was developed to simulate the atmospheric dispersion of denser-than-air releases. In developing the model, it was assumed that the dense-gas effects could be described in terms of the vertically-averaged thermodynamic properties and the local height of the cloud. The dense-gas effects were treated as a perturbation to the ambient thermodynamic properties (density and temperature), ground level heat flux, turbulence level (diffusivity), and windfield (gravity flow) within the local region of the dense-gas cloud. These perturbations were calculated from conservation of energy and conservation of momentum principles along with the ideal gas law equation of state for a mixture of gases. ADPIC, which is generally run in conjunction with a mass-conserving wind flow model to provide the advection field, contains all the dense-gas modifications within it. This feature provides the versatility of coupling the new dense-gas ADPIC with alternative wind flow models. The new dense-gas ADPIC has been used to simulate the atmospheric dispersion of ground-level, colder-than-ambient, denser-than-air releases and has compared favorably with the results of field-scale experiments.
Aerosols in Polluted versus Nonpolluted Air Masses: Long-Range Transport and Effects on Clouds.
NASA Astrophysics Data System (ADS)
Pueschel, R. F.; van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.
1986-12-01
To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United State, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, New York, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types-background continental, polluted continental, and maritime-that were advected to the sampling site. The results are the following (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds to thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (ii) A significant fraction of anthropogenic sulfur aerosols appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (iii) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (iv) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.
NASA Astrophysics Data System (ADS)
Goldbaum, Nathan J.; Krumholz, Mark R.; Forbes, John C.
2016-08-01
Self-gravity and stellar feedback are capable of driving turbulence and transporting mass and angular momentum in disk galaxies, but the balance between them is not well understood. In the previous paper in this series, we showed that gravity alone can drive turbulence in galactic disks, regulate their Toomre Q parameters to ˜1, and transport mass inwards at a rate sufficient to fuel star formation in the centers of present-day galaxies. In this paper we extend our models to include the effects of star formation feedback. We show that feedback suppresses galaxies’ star formation rates by a factor of ˜5 and leads to the formation of a multi-phase atomic and molecular interstellar medium. Both the star formation rate and the phase balance produced in our simulations agree well with observations of nearby spirals. After our galaxies reach steady state, we find that the inclusion of feedback actually lowers the gas velocity dispersion slightly compared to the case of pure self-gravity, and also slightly reduces the rate of inward mass transport. Nevertheless, we find that, even with feedback included, our galactic disks self-regulate to Q ˜ 1, and transport mass inwards at a rate sufficient to supply a substantial fraction of the inner disk star formation. We argue that gravitational instability is therefore likely to be the dominant source of turbulence and transport in galactic disks, and that it is responsible for fueling star formation in the inner parts of galactic disks over cosmological times.
NASA Astrophysics Data System (ADS)
Pinet, Nicolas; Brake, Virginia; Campbell, Calvin; Duchesne, Mathieu J.
2015-01-01
Recently acquired multibeam bathymetry data are used to investigate seafloor instability features along a 310 km-long segment of the St. Lawrence River Estuary. The analysis of this dataset indicates that submarine slides occur over a much larger area than previously recognized and that Holocene sediments are reworked by mass-transport along significant portions of both the northwest and southeast margins of the Laurentian Channel. In the surveyed area, 96 individual mass-transport complexes (MTCs) were identified representing 13% of the seabed. MTCs vary in area from less than 1 km2 to more than 40 km2 and exhibit various geomorphological signatures. Qualitative observation reveals an apparent disparity between MTCs that remain coherent and those that disintegrate during downslope transport evolving into a blocky morphological signature. For all MTCs, morphological parameters have been measured (area, length, and height) or calculated (slope and roughness). This quantitative analysis provides a unique opportunity to study these parameters in a statistically significant and homogeneous dataset located in a relatively small area that experienced a similar Quaternary history. In many cases, mass transport events appear to initiate in the vicinity of steep bedrock walls located along some segments of the estuary. The timing of mass-transport events was not constrained during this study. However, the fact that the region hosts the Charlevoix seismic zone, the most tectonically active area in eastern Canada, strongly suggests that earthquakes acted as a trigger for submarine landsliding.
Mass and momentum turbulent transport experiments with confined swirling coaxial jets
NASA Technical Reports Server (NTRS)
Roback, R.; Johnson, B. V.
1983-01-01
Swirling coaxial jets mixing downstream, discharging into an expanded duct was conducted to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the combustion community. A combination of laser velocimeter (LV) and laser induced fluorescence (LIF) techniques was employed to obtain mean and fluctuating velocity and concentration distributions which were used to derive mass and momentum turbulent transport parameters currently incorporated into various combustor flow models. Flow visualization techniques were also employed to determine qualitatively the time dependent characteristics of the flow and the scale of turbulence. The results of these measurements indicated that the largest momentum turbulent transport was in the r-z plane. Peak momentum turbulent transport rates were approximately the same as those for the nonswirling flow condition. The mass turbulent transport process for swirling flow was complicated. Mixing occurred in several steps of axial and radial mass transport and was coupled with a large radial mean convective flux. Mixing for swirling flow was completed in one-third the length required for nonswirling flow.
Tomography-based monitoring of isothermal snow metamorphism under advective conditions
NASA Astrophysics Data System (ADS)
Ebner, P. P.; Schneebeli, M.; Steinfeld, A.
2015-07-01
Time-lapse X-ray microtomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. The effect of diffusion and advection across the snow pores on the snow microstructure were analysed in controlled laboratory experiments and possible effects on natural snowpacks discussed. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective permeability. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Isothermal snow metamorphism is driven by sublimation deposition caused by the Kelvin effect and is the limiting factor independently of the transport regime in the pores.
Mass transport properties of Pu/DT mixtures from orbital free molecular dynamics simulations
Kress, Joel David; Ticknor, Christopher; Collins, Lee A.
2015-09-16
Mass transport properties (shear viscosity and diffusion coefficients) for Pu/DT mixtures were calculated with Orbital Free Molecular Dynamics (OFMD). The results were fitted to simple functions of mass density (for ρ=10.4 to 62.4 g/cm^{3}) and temperature (for T=100 up to 3,000 eV) for Pu/DT mixtures consisting of 100/0, 25/75, 50/50, and 75/25 by number.
The water mass structure and transports in the Atlantic Subpolar Gyre
NASA Astrophysics Data System (ADS)
García-Ibáñez, Maribel I.; Pardo, Paula C.; Carracedo, Lidia I.; Mercier, Herlé; Lherminier, Pascale; Ríos, Aida F.; Pérez, Fiz F.
2014-05-01
The water mass structure, mixing and spreading in the North Atlantic Subpolar Gyre (SPG) were analyzed by means of an extended Optimum MultiParameter (eOMP) approach over the six repeats of the WOCE A25 hydrographic line located at the southern boundary of this gyre. The data includes the Fourex (4x) line taken in 1997 and the five repeat sections of the OVIDE line taken every other year from 2002 to 2010. We proposed 10 water masses, defined by their thermohaline properties (potential temperature and salinity), oxygen and nutrients (nitrate, phosphate and silicate), to resolve the water mass structure of the SPG. The eOMP enables to decompose the transports by water mass quantitatively. Our model provides water mass distributions that are able to reproduce the input data of potential temperature, salinity and silicate with r2>0.997 and of oxygen, nitrate and phosphate with r2>0.96. By combining the velocity field and the water mass structure across each section we provide the relative contribution of each water mass to the Meridional Overturning Circulation (MOC) and we evaluate the water mass transformation in the North Atlantic. The MOC upper limb during OVIDE (2002-2010) is constituted by the northward transports of the central waters (9.4 Sv; 1 Sv = 106 m3 s-1), the Subarctic Intermediate Water (SAIW, 2.8 Sv) and the Subpolar Mode Water (SPMW) of the Iceland Basin (2.1 Sv). The MOC lower limb is constituted by the southward transports of the Iceland-Scotland Overflow Water (ISOW, 2.9 Sv), the Denmark Strait Overflow Water (DSOW, 2.5 Sv), the Polar Intermediate Water (PIW, 0.8 Sv), the Labrador Sea Water (LSW, 3.6 Sv) and the SPMW of the Irminger Sea (4.7 Sv). These results contrast with those obtained for the 1997, cruise developed after a period of high NAO index. The greater MOC strength in 1997 resulted in greater northward transports of central waters (17.5 Sv), while the SAIW transports remained approximately unchanged. The increase of the northward
Experiments in Advective and Turbulent Hyporheic Pumping
NASA Astrophysics Data System (ADS)
Mccluskey, A. H.; Grant, S.; Stewardson, M. J.
2014-12-01
Hyporheic exchange (HE) is the mixing of stream and subsurface waters beneath the sediment-water interface (SWI). At the patch and reach scales, HE is dominated by periodic upwelling and downwelling zones, induced by pressure variation and processes within the turbulent boundary layer (TBL). This can be caused by (1) the geometry of the stream, imposing a stationary wave at the SWI or (2) by a travelling wave associated with the propagation of turbulent pressure waves generated from the TBL. Case (1) has generally been the favoured model of hyporheic exchange and has been referred to as hyporheic 'pumping' by Elliott and Brooks, and subsequently others. Case (2) can be termed turbulent pumping, and has been proposed as a mechanism to model the combined effects of turbulent dispersion alongside steady-state advection. While this has been represented numerically and analytically, conjecture remains about the physical representation of these combined processes. We present initial results from experiments undertaken to classify the spatial and temporal characteristics of pressure variation at and beneath the SWI, with a periodic sinusoidal geometry of wavelength 0.28m and height 0.02m. As an initial characterisation, the advective flow profile has been examined using time-lapse photography of dyes released across the span of a periodic downwelling zone. These tracer tests confirmed delineation of isolated upwelling and downwelling cells as noted by previous authors in modelling studies. However, their distribution deviates from the typical pumping pattern with increased discharge and stream gradient. Empirical orthogonal function (EOF) analysis of high frequency (250Hz) pressure measurements, sampled at an array along the centroid of the flume underneath one wavelength gave further insight into the spatial distribution of turbulent signatures arising from roughness-generated turbulence. A turbulent frequency of 6-10Hz dominates, however the penetration depth appears to
The effect of advection at luminosities close to Eddington: The ULX in M 31
NASA Astrophysics Data System (ADS)
Straub, O.; Done, C.; Middleton, M.
2013-05-01
The transient, ultra-luminous X-ray source CXOM31 J004253.1+411422 in the Andromeda galaxy is most likely a 10 solar mass black hole, with super-Eddington luminosity at its peak. The XMM-Newton spectra taken during the decline then trace luminosities of 0.86-0.27 LEdd. These spectra are all dominated by a hot disc component, which roughly follows a constant inner radius track in luminosity and temperature as the source declines. At the highest luminosity the disc structure should change due to advection of radiation through the disc. This advected flux can be partly released at lower radii thus modifying the spectral shape. To study the effect of advection at luminosities close to Eddington we employ a fully relativistic slim disc model, SLIMBH, that includes advective cooling and full radiative transfer through the photosphere based on tlusty. The model also incorporates relativistic photon ray-tracing from the proper location of the disc photosphere rather than the mid-plane as the slim disc is no longer geometrically thin. We find that these new models differ only slightly from the non-advective (standard) BHSPEC models even at the highest luminosities considered here. While both discs can fit the highest luminosity data, neither is a very good fit to the lower luminosities. This could indicate a missing physical process that acts in low luminosity discs and subsides as the disc luminosity approaches the Eddington limit.
NASA Technical Reports Server (NTRS)
Lang, Steve; Tao, W.-K.; Simpson, J.; Ferrier, B.; Einaudi, Franco (Technical Monitor)
2001-01-01
Six different convective-stratiform separation techniques, including a new technique that utilizes the ratio of vertical and terminal velocities, are compared and evaluated using two-dimensional numerical simulations of a tropical [Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA COARE)] and midlatitude continental [Preliminary Regional Experiment for STORM-Central (PRESTORM)] squall line. The simulations are made using two different numerical advection schemes: 4th order and positive definite advection. Comparisons are made in terms of rainfall, cloud coverage, mass fluxes, apparent heating and moistening, mean hydrometeor profiles, CFADs (Contoured Frequency with Altitude Diagrams), microphysics, and latent heating retrieval. Overall, it was found that the different separation techniques produced results that qualitatively agreed. However, the quantitative differences were significant. Observational comparisons were unable to conclusively evaluate the performance of the techniques. Latent heating retrieval was shown to be sensitive to the use of separation technique mainly due to the stratiform region for methods that found very little stratiform rain. The midlatitude PRESTORM simulation was found to be nearly invariant with respect to advection type for most quantities while for TOGA COARE fourth order advection produced numerous shallow convective cores and positive definite advection fewer cells that were both broader and deeper penetrating above the freezing level.
NASA Astrophysics Data System (ADS)
Tertre, E.; Hubert, F.; Bruzac, S.; Pacreau, M.; Ferrage, E.; Prêt, D.
2013-07-01
The present study aims at testing the validity of using an Na+/Ca2+ ion-exchange model, derived from batch data to interpret experimental Ca2+-for-Na+ exchange breakthrough curves obtained on vermiculite (a common swelling clay mineral in surface environments). The ion-exchange model was constructed considering the multi-site nature of the vermiculite surface as well as the exchange of all aqueous species (Mg2+ derived from the dissolution of the solid and H+). The proposed ion-exchange model was then coupled with a transport model, and the predicted breakthrough curves were compared with the experimental ones obtained using a well stirred flow-through reactor. For a given solute residence time in the reactor (typically 50 min), our thermodynamic model based on instantaneous equilibrium was found to accurately reproduce several of the experimental breakthrough curves, depending on the Na+ and Ca2+ concentrations of the influents pumped through the reactor. However the model failed to reproduce experimental breakthrough curves obtained at high flow rates and low chemical gradient between the exchanger phase and the solution. An alternative model based on a hybrid equilibrium/kinetic approach was thus used and allowed predicting experimental data. Based on these results, we show that a simple parameter can be used to differentiate between thermodynamic and kinetic control of the exchange reaction with water flow. The results of this study are relevant for natural systems where two aquatic environments having contrasted chemistries interact. Indeed, the question regarding the attainment of a full equilibrium in such a system during the contact time of the aqueous phase with the particle/colloid remains most often open. In this context, we show that when a river (a flow of fresh water) encounters marine colloids, a systematic full equilibrium can be assumed (i.e., the absence of kinetic effects) when the residence time of the solute in 1 m3 of the system is ⩾6200 h.
Conceptual model for transport processes in the Culebra Dolomite Member, Rustler Formation
Holt, R.M.
1997-08-01
The Culebra Dolomite Member of the Rustler Formation represents a possible pathway for contaminants from the Waste Isolation Pilot Plant underground repository to the accessible environment. The geologic character of the Culebra is consistent with a double-porosity, multiple-rate model for transport in which the medium is conceptualized as consisting of advective porosity, where solutes are carried by the groundwater flow, and fracture-bounded zones of diffusive porosity, where solutes move through slow advection or diffusion. As the advective travel length or travel time increases, the nature of transport within a double-porosity medium changes. This behavior is important for chemical sorption, because the specific surface area per unit mass of the diffusive porosity is much greater than in the advective porosity. Culebra transport experiments conducted at two different length scales show behavior consistent with a multiple-rate, double-porosity conceptual model for Culebra transport. Tracer tests conducted on intact core samples from the Culebra show no evidence of significant diffusion, suggesting that at the core scale the Culebra can be modeled as a single-porosity medium where only the advective porosity participates in transport. Field tracer tests conducted in the Culebra show strong double-porosity behavior that is best explained using a multiple-rate model.
NASA Astrophysics Data System (ADS)
Henry, David; Sastre-Gomez, Silvia
2016-04-01
In this paper we present an analysis of the mean flow velocities, and related mass transport, which are induced by certain equatorially-trapped water waves. In particular, we examine a recently-derived exact and explicit solution to the geophysical governing equations in the {β} -plane approximation at the equator which incorporates a constant underlying current.
Measurements of Combined Axial Mass and Heat Transport in He II.
ERIC Educational Resources Information Center
Johnson, Warren W.; Jones, Michael C.
An experiment was performed that allowed measurements of both axial mass and heat transport of He-II (the superfluid phase of helium 4) in a long tube. The apparatus allowed the pressure difference and the temperature difference across the flow tube to each be independently adjusted, and the resulting steady-state values of net fluid velocity and…
NASA Astrophysics Data System (ADS)
Tsai, Peichun Amy; Haase, A. Sander; Karatay, Elif; Lammertink, Rob; Soft Matter, Fluidics; Interfaces Group Team
2013-11-01
We numerically investigate the influence of interface geometry on momentum and mass transport on a partially slippery bubble mattress. The bubble mattress, forming a superhydrophobic substrate, consists of an array of slippery (shear-free) gas bubbles with (no-slip) solids walls in between. We consider steady pressure-driven laminar flow over the bubble mattress, with a solute being supplied from the gas bubbles. The results show that solute transport can be enhanced significantly due to effective slippage, compared to a fully saturated no-slip wall. The enhancement depends on the interface geometry of the bubble mattress, i.e. on the bubble size, protrusion angle, and surface porosity. In addition, we demonstrate that the mass transfer enhancement disappears below a critical bubble size. The effective slip vanishes for very small bubbles, whereby interfacial transport becomes diffusion dominated. For large bubbles, solute transport near the interface is greatly enhanced by convection. The results provide insight into the optimal design of ultra-hydrophobic bubble mattresses to enhance both momentum and mass transport.
NASA Astrophysics Data System (ADS)
Lenhard, R. J.; Oostrom, M.; Simmons, C. S.; White, M. D.
1995-07-01
An experiment was conducted to evaluate whether vapor-density effects are significant in transporting volatile organic compounds (VOC's) with high vapor pressure and molecular mass through the subsurface. Trichloroethylene (TCE) was chosen for the investigation because it is a common VOC contaminant with high vapor pressure and molecular mass. For the investigation, a 2-m-long by 1-m-high by 7.5-cm-thick flow cell was constructed with a network of sampling ports. The flow cell was packed with sand, and a water table was established near the lower boundary. Liquid TCE was placed near the upper boundary of the flow cell in a chamber from which vapors could enter and migrate through the sand. TCE concentrations in the gas phase were measured by extracting 25-μl gas samples with an air-tight syringe and analyzing them with a gas chromatograph. The evolution of the TCE gas plume in the sand was investigated by examining plots of TCE concentrations over the domain for specific times and for particular locations as a function of time. To help in this analysis, a numerical model was developed that can predict the simultaneous movements of a gas, a nonaqueous liquid and water in porous media. The model also considers interphase mass transfer by employing the phase equilibrium assumption. The model was tested with one- and two-dimensional analytical solutions of fluid flow before it was used to simulate the experiment. Comparisons between experimental data and simulation results when vapor-density effects are considered were very good. When vapor-density effects were ignored, agreement was poor. These analyses suggest that vapor-density effects should be considered and that density-driven vapor advection may be an important mechanism for moving VOC's with high vapor pressures and molecular mass through the subsurface.
Bilayer mass transport model for determining swelling and diffusion in coated, ultrathin membranes.
Nadermann, Nichole K; Chan, Edwin P; Stafford, Christopher M
2015-02-18
Water transport and swelling properties of an ultrathin, selective polyamide layer with a hydrophilic polymer coating, i.e., a polymer bilayer, are studied using quartz crystal microbalance with dissipation (QCM-D). Specifically, QCM-D is used to measure the dynamic and equilibrium change in mass in a series of differential sorption experiments to determine the dependence of the apparent diffusion coefficient and equilibrium swelling of the bilayer as a function of the water vapor activity. To determine transport properties specific to the polyamide layer, sorption kinetics of the bilayer was modeled with a bilayer mass transport model. The swelling and water diffusion coefficients are interpreted according to the Painter-Shenoy polymer network swelling model and the solution-diffusion model, respectively.
NASA Technical Reports Server (NTRS)
Tan, L. C.; Mason, G. M.; Lee, M. A.; Klecker, B.; Ipavich, F. M.
1992-01-01
Evidence is presented for focused transport of energetic particles along magnetic field lines draped around a coronal mass ejection. This evidence was obtained with the University of Maryland/Max-Planck-Institute experiment on the ISEE-3 spacecraft during the decay phase of the June 6, 1979, solar particle event. During the early portion of the decay phase of this event, interplanetary magnetic field lines were apparently draped around a coronal mass ejection, leading to a small focusing length on the western flank where ISEE 3 was located. A period of very slow decrease of particle intensity was observed, along with large sunward anisotropy in the solar wind frame, which is inconsistent with predictions of the standard Fokker-Planck equation models for diffusive transport. It was found possible to fit the observations, assuming that focused transport dominates and that the particle pitch angle scattering is isotropic.
Model simulation and experiments of flow and mass transport through a nano-material gas filter
Yang, Xiaofan; Zheng, Zhongquan C.; Winecki, Slawomir; Eckels, Steve
2013-11-01
A computational model for evaluating the performance of nano-material packed-bed filters was developed. The porous effects of the momentum and mass transport within the filter bed were simulated. For the momentum transport, an extended Ergun-type model was employed and the energy loss (pressure drop) along the packed-bed was simulated and compared with measurement. For the mass transport, a bulk dsorption model was developed to study the adsorption process (breakthrough behavior). Various types of porous materials and gas flows were tested in the filter system where the mathematical models used in the porous substrate were implemented and validated by comparing with experimental data and analytical solutions under similar conditions. Good agreements were obtained between experiments and model predictions.
Waves, advection, and cloud patterns on Venus
NASA Technical Reports Server (NTRS)
Schinder, Paul J.; Gierasch, Peter J.; Leroy, Stephen S.; Smith, Michael D.
1990-01-01
The stable layers adjacent to the nearly neutral layer within the Venus clouds are found to be capable of supporting vertically trapped, horizontally propagating waves with horizontal wavelengths of about 10 km and speeds of a few meters per second relative to the mean wind in the neutral layer. These waves may possibly be excited by turbulence within the neutral layer. Here, the properties of the waves, and the patterns which they might produce within the visible clouds if excited near the subsolar point are examined. The patterns can be in agreement with many features in images. The waves are capable of transferring momentum latitudinally to help maintain the general atmospheric spin, but at present we are not able to evaluate wave amplitudes. We also examine an alternative possibility that the cloud patterns are produced by advection and shearing by the mean zonal and meridional flow of blobs formed near the equator. It is concluded that advection and shearing by the mean flow is the most likely explanation for the general pattern of small scale striations.
Mittal, Ashutosh; Pilath, Heid M.; Parent, Yves; Chatterjee, Siddharth G.; Donohoe, Bryon S.; Yarbrough, John M.; Himmel, Michael E.; Nimlos, Mark R.; Johnson, David K.
2014-04-28
Mass transport limitations could be an impediment to achieving high sugar yields during biomass pretreatment and thus be a critical factor in the economics of biofuels production. The objective of this work was to study the mass transfer restrictions imposed by the structure of biomass on the hydrolysis of xylan during dilute acid pretreatment of biomass. Mass transfer effects were studied by pretreating poplar wood at particle sizes ranging from 10 micrometers to 10 mm. This work showed a significant reduction in the rate of xylan hydrolysis in poplar when compared to the intrinsic rate of hydrolysis for isolated xylan that is possible in the absence of mass transfer. In poplar samples we observed no significant difference in the rates of xylan hydrolysis over more than two orders of magnitude in particle size. It appears that no additional mass transport restrictions are introduced by increasing particle size from 10 micrometers to 10 mm. This work suggests that the rates of xylan hydrolysis in biomass particles are limited primarily by the diffusion of hydrolysis products out of plant cell walls. A mathematical description is presented to describe the kinetics of xylan hydrolysis that includes transport of the hydrolysis products through biomass into the bulk solution. The modeling results show that the effective diffusion coefficient of the hydrolysis products in the cell wall is several orders of magnitude smaller than typical values in other applications signifying the role of plant cell walls in offering resistance to diffusion of the hydrolysis products.
Mass transport in a porous microchannel for non-Newtonian fluid with electrokinetic effects.
Mondal, Sourav; De, Sirshendu
2013-03-01
Quantification of mass transfer in porous microchannel is of paramount importance in several applications. Transport of neutral solute in presence of convective-diffusive EOF having non-Newtonian rheology, in a porous microchannel was presented in this article. The governing mass transfer equation coupled with velocity field was solved along with associated boundary conditions using a similarity solution method. An analytical solution of mass transfer coefficient and hence, Sherwood number were derived from first principles. The corresponding effects of assisting and opposing pressure-driven flow and EOF were also analyzed. The influence of wall permeation, double-layer thickness, rheology, etc. on the mass transfer was also investigated. Permeation at the wall enhanced the mass transfer coefficient more than five times compared to impervious conduit in case of pressure-driven flow assisting the EOF at higher values of κh. Shear thinning fluid exhibited more enhancement of Sherwood number in presence of permeation compared to shear thickening one. The phenomenon of stagnation was observed at a particular κh (∼2.5) in case of EOF opposing the pressure-driven flow. This study provided a direct quantification of transport of a neutral solute in case of transdermal drug delivery, transport of drugs from blood to target region, etc. PMID:23192435
Mass transport in a porous microchannel for non-Newtonian fluid with electrokinetic effects.
Mondal, Sourav; De, Sirshendu
2013-03-01
Quantification of mass transfer in porous microchannel is of paramount importance in several applications. Transport of neutral solute in presence of convective-diffusive EOF having non-Newtonian rheology, in a porous microchannel was presented in this article. The governing mass transfer equation coupled with velocity field was solved along with associated boundary conditions using a similarity solution method. An analytical solution of mass transfer coefficient and hence, Sherwood number were derived from first principles. The corresponding effects of assisting and opposing pressure-driven flow and EOF were also analyzed. The influence of wall permeation, double-layer thickness, rheology, etc. on the mass transfer was also investigated. Permeation at the wall enhanced the mass transfer coefficient more than five times compared to impervious conduit in case of pressure-driven flow assisting the EOF at higher values of κh. Shear thinning fluid exhibited more enhancement of Sherwood number in presence of permeation compared to shear thickening one. The phenomenon of stagnation was observed at a particular κh (∼2.5) in case of EOF opposing the pressure-driven flow. This study provided a direct quantification of transport of a neutral solute in case of transdermal drug delivery, transport of drugs from blood to target region, etc.
Air Mass Origin as a Diagnostic of Seasonally-Varying Transport into the Arctic
NASA Astrophysics Data System (ADS)
Orbe, C.; Waugh, D. W.; Holzer, M. B.; Newman, P. A.; Polvani, L. M.; Oman, L.; Li, F.
2013-12-01
While the signatures of the seasonal cycle on basic state variables such as temperature, winds and on chemical composition have been explored in depth, its signature on air mass composition has received relatively little attention. To this end, we present the first analysis of the seasonally varying transport from the northern hemisphere (NH) midlatitudes into the Arctic using rigorously defined air masses. The fractional contribution from each air mass partitions Arctic air according to where it was last in the planetary boundary layer (PBL) at midlatitudes over the Pacific and Atlantic oceans, North America, Europe, and Asia. Air mass fractions are computed using the coupled climate-chemistry model GEOSCCM subject to fixed present-day climate forcings. We find that during DJF 48% of the air in the free troposphere poleward of 60N was last at midlatitudes primarily at the Pacific and Atlantic oceans, at 20% and 10% respectively. During JJA, however, the largest contributions to Arctic air come from Asian and North American source regions, revealing that transport from the industrialized midlatitude regions dominates during boreal summer. Preliminary calculations of future air masses for a model integration subject to A1B greenhouse gases also reveal the model's climate change response in arctic air mass composition. In concert with weakened tropospheric eddy kinetic energy and a weakened Hadley cell, we find that changes in annual mean arctic air mass fractions are of the order 10%, with increased contributions from air that was last in contact with the PBL over North America and over the Atlantic and Pacific oceans. Air-mass fractions, and their changes, thus help to isolate the role of transport to changes in composition, which are not only driven by changes in chemistry and emissions but also crucially by changes in atmospheric flow.
Mass-conserving tracer transport modelling on a reduced latitude-longitude grid
NASA Astrophysics Data System (ADS)
Belikov, D.; Maksyutov, S.; Miyasaka, T.; Saeki, T.; Zhuravlev, R.; Kiryushov, B.
2010-10-01
The need to perform long-term simulations with reasonable accuracy has led to the development of mass-conservative and efficient numerical methods for solving the transport equation in forward and inverse models. We designed and implemented a flux-form (Eulerian) tracer transport algorithm in the National Institute for Environmental Studies Transport Model (NIES TM), which is used for simulating diurnal and synoptic-scale variations of tropospheric long-lived constituents, as well as their seasonal and inter-annual variability. Implementation of the flux-form method requires the mass conservative wind fields. However, the model is off-line and is driven by datasets from a global atmospheric model or data assimilation system, in which vertically integrated mass changes are not in balance with the surface pressure tendency and mass conservation is not achieved. To rectify the mass-imbalance, a flux-correction method is employed. To avoid singularity near the poles caused by the small grid size arising from the meridional convergence problem, the proposed model uses a reduced latitude-longitude grid scheme, in which the grid size is doubled several times approaching the poles. This approach overcomes the Courant condition in the Polar Regions, maintains a reasonably high integration time-step and ensures adequate model performance during simulations. To assess the model performance, we performed global transport simulations for SF6, 222Rn and CO2. The results were compared with observations available from the World Data Centre for Greenhouse Gases, GLOBALVIEW and the Hateruma monitoring station, Japan. Overall, the results show that the proposed flux-form version of NIES TM can produce tropospheric tracer transport more realistically than previously possible. The reasons for this improvement are discussed.
Multiscale mass transport in z ˜6 galactic discs: fuelling black holes
NASA Astrophysics Data System (ADS)
Prieto, Joaquin; Escala, Andrés
2016-08-01
By using Adaptive Mesh Refinement cosmological hydrodynamic N-body zoom-in simulations, with the RAMSES code, we studied the mass transport processes on to galactic nuclei from high redshift up to z ˜6. Due to the large dynamical range of the simulations, we were able to study the mass accretion process on scales from ˜50 kpc to ˜few 1 pc. We studied the black hole (BH) growth on to the Galactic Centre in relation with the mass transport processes associated to both the Reynolds stress and the gravitational stress on the disc. Such methodology allowed us to identify the main mass transport process as a function of the scales of the problem. We found that in simulations that include radiative cooling and supernovae feedback, the supermassive black hole (SMBH) grows at the Eddington limit for some periods of time presenting
Converted charter plane for mass transport of patients after a tsunami.
Björnsson, Hjalti Már; Kristjánsson, Már; Möller, Alma D
2008-01-01
After a tsunami in the Indian Ocean in December 2004, thousands of injured tourists were stranded far away from home. To transport injured Scandinavians and their relatives back to Sweden, a standard Icelandic charter plane was altered for the mission in 2 days. Orthopedic injuries and aspirations were the predominant injuries among patients transported, but all had received advanced care in Thailand. The transport to Sweden was uneventful. The possibility of including charter planes in plans for mass transport of injured patients in disaster preparedness is stressed. For a given incident, a detailed checklist can facilitate gathering vital information to ensure adequate equipment and patient care. The lessons from the preparation of the plane and the mission are reported.
Converted charter plane for mass transport of patients after a tsunami.
Björnsson, Hjalti Már; Kristjánsson, Már; Möller, Alma D
2008-01-01
After a tsunami in the Indian Ocean in December 2004, thousands of injured tourists were stranded far away from home. To transport injured Scandinavians and their relatives back to Sweden, a standard Icelandic charter plane was altered for the mission in 2 days. Orthopedic injuries and aspirations were the predominant injuries among patients transported, but all had received advanced care in Thailand. The transport to Sweden was uneventful. The possibility of including charter planes in plans for mass transport of injured patients in disaster preparedness is stressed. For a given incident, a detailed checklist can facilitate gathering vital information to ensure adequate equipment and patient care. The lessons from the preparation of the plane and the mission are reported. PMID:18992689
NASA Astrophysics Data System (ADS)
Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon
2016-04-01
The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.
Picioreanu, C; van Loosdrecht, M C; Heijnen, J J
2000-05-20
This modeling study evaluates the influence of biofilm geometrical characteristics on substrate mass transfer and conversion rates. A spatially two-dimensional model was used to compute laminar fluid flow, substrate mass transport, and conversion in irregularly shaped biofilms. The flow velocity above the biofilm surface was varied over 3 orders of magnitude. Numerical results show that increased biofilm roughness does not necessarily lead to an enhancement of either conversion rates or external mass transfer. The average mass transfer coefficient and Sherwood numbers were found to decrease almost linearly with biofilm area enlargement in the flow regime tested. The influence of flow, biofilm geometry and biofilm activity on external mass transfer could be quantified by Sh-Re correlations. The effect of biofilm surface roughness was incorporated in this correlation via area enlargement. Conversion rates could be best correlated to biofilm compactness. The more compact the biofilm, the higher the global conversion rate of substrate. Although an increase of bulk fluid velocity showed a large effect on mass transfer coefficients, the global substrate conversion rate per carrier area was less affected. If only diffusion occurs in pores and channels, then rough biofilms behave as if they were compact but having less biomass activity. In spite of the fact that the real biofilm area is increased due to roughness, the effective mass transfer area is actually decreased because only biofilm peaks receive substrate. This can be explained by the fact that in the absence of normal convection in the biofilm valleys, the substrate gradients are still largely perpendicular to the carrier. Even in the cases where convective transport dominates the external mass transfer process, roughness could lead to decreased conversion rates. The results of this study clearly indicate that only evaluation of overall conversion rates or mass fluxes can describe the correct biofilm conversion
Lateral advection of organic matter in cascading-dominated submarine canyons
NASA Astrophysics Data System (ADS)
Tesi, T.; Puig, P.; Palanques, A.; Goñi, M. A.
2010-03-01
In the Gulf of Lions (GoL), dense water overflowing off the shelf occurs seasonally and represents the main mechanism affecting the shelf-slope exchange of particulate organic matter (OM). Most of the dense water export takes place in the south-western GoL and in particular through Cap de Creus (CdC) submarine canyon. Here, benthic instruments were deployed to collect down-canyon particulate fluxes whereas surface sediments were taken after the cascading event along the sediment dispersal system on the shelf, in CdC canyon and in the nearby Lacaze-Duthiers (LD) canyon. The chemical composition of the suspended material and surface sediments were investigated using several proxies including organic and inorganic carbon, total nitrogen, biogenic silica, δ 13C, Δ 14C, and alkaline CuO oxidation products. Thermohaline anomalies and high current speed events were measured in CdC canyon since December 2004 until mid-April 2005 indicating a marked off-shelf export of dense water trough the canyon. During the cascading, mud and relatively coarse shelf and upper canyon sediments were the major component of the mass flux. Conversely, advection of fine material via nepheloid layers dominated down-slope fluxes during pre- and post-cascading. The resulting change in grain-size affected the flux of mineral-bound terrigenous OC, indicating that the down-canyon transport of land-derived OM did not occur as bulk but rather its composition is driven by sediment sorting associated with different transport mechanisms. Both surface sediments and sediment trap samples indicated that CdC canyon is well connected to the GoL terrigenous dispersal system. Conversely, our results suggest an overall limited influence of land-derived OM in LD canyon. In spite of the reduced fluvial nutrient supply, a significant pulsed input of modern marine OM was observed in April 2005 at the end of the cascading period. Both intense mixing and lack of strong water column stratification likely played a key
Varank, Gamze; Demir, Ahmet; Yetilmezsoy, Kaan; Bilgili, M. Sinan; Top, Selin; Sekman, Elif
2011-11-15
Highlights: > We conduct 1D advection-dispersion modeling to estimate transport parameters. > We examine fourteen phenolic compounds and three inorganic contaminants. > 2-MP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,3,4,6-TeCP have the highest coefficients. > Dispersion coefficients of Cu are determined to be higher than Zn and Fe. > Transport of phenolics can be prevented by zeolite and bentonite in landfill liners. - Abstract: One-dimensional (1D) advection-dispersion transport modeling was conducted as a conceptual approach for the estimation of the transport parameters of fourteen different phenolic compounds (phenol, 2-CP, 2-MP, 3-MP, 4-MP, 2-NP, 4-NP, 2,4-DNP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,4,6-TCP, 2,3,4,6-TeCP, PCP) and three different inorganic contaminants (Cu, Zn, Fe) migrating downward through the several liner systems. Four identical pilot-scale landfill reactors (0.25 m{sup 3}) with different composite liners (R1: 0.10 + 0.10 m of compacted clay liner (CCL), L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R2: 0.002-m-thick damaged high-density polyethylene (HDPE) geomembrane overlying 0.10 + 0.10 m of CCL, L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R3: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick bentonite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 1 x 10{sup -8} m/s, R4: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick zeolite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 4.24 x 10{sup -7} m/s) were simultaneously run for a period of about 540 days to investigate the nature of diffusive and advective transport of the selected organic and inorganic contaminants. The results of 1D transport model showed that the highest molecular diffusion coefficients, ranging from 4.77 x 10{sup -10} to 10.67 x 10{sup -10} m{sup 2}/s, were estimated for phenol (R4), 2-MP (R1), 2,4-DNP (R2), 2,4-DCP (R1), 2,6-DCP (R2), 2,4,5-TCP (R2) and 2,3,4,6-TeCP (R1). For all reactors
Specific features of defect and mass transport in concentrated fcc alloys
Osetsky, Yuri N.; Béland, Laurent K.; Stoller, Roger E.
2016-06-15
We report that diffusion and mass transport are basic properties that control materials performance, such as phase stability, solute decomposition and radiation tolerance. While understanding diffusion in dilute alloys is a mature field, concentrated alloys are much less studied. Here, atomic-scale diffusion and mass transport via vacancies and interstitial atoms are compared in fcc Ni, Fe and equiatomic Ni-Fe alloy. High temperature properties were determined using conventional molecular dynamics on the microsecond timescale, whereas the kinetic activation-relaxation (k-ART) approach was applied at low temperatures. The k-ART was also used to calculate transition states in the alloy and defect transport coefficients.more » The calculations reveal several specific features. For example, vacancy and interstitial defects migrate via different alloy components, diffusion is more sluggish in the alloy and, notably, mass transport in the concentrated alloy cannot be predicted on the basis of diffusion in its pure metal counterparts. Lastly, the percolation threshold for the defect diffusion in the alloy is discussed and it is suggested that this phenomenon depends on the properties and diffusion mechanisms of specific defects.« less
NASA Astrophysics Data System (ADS)
Young, D. L.; Coutts, T. J.; Kaydanov, V. I.
2000-02-01
A novel machine has been developed to measure transport coefficients in the temperature range of 50-350 K of thin films deposited on electrically insulating substrates. The measured coefficients—resistivity, Hall, Seebeck, and Nernst—are applied to solutions of the Boltzmann transport equation to give information about the film's density-of-states effective mass, the Fermi energy level, and an energy-dependent scattering parameter. The machine is designed to eliminate or compensate for simultaneously occurring transport phenomena that would interfere with the desired measured quantity, while allowing for all four coefficients to be measured on the same sample. An average density-of-states effective mass value of 0.29±0.04me was measured on the transparent conductive oxide, cadmium stannate (CTO), over a carrier concentration range of 2-7×1020cm-3. This effective mass value matched previous results obtained by optical and thermoelectric modeling. The measured scattering parameter indicates that neutral impurities or a mixture of scattering mechanisms may inhibit the transport of carriers in CTO.
On the potential importance of transient air flow in advective radon entry into buildings
Narasimhan, T.N.; Tsang, Y.W.; Holman, H.Y. )
1990-05-01
The authors have investigated, using a mathematical model, the temporal variations of air flux within the soil mass surrounding a basement in the presence of time dependent periodic variations of barometric pressure and a persistent under-pressure at the basement. The results of transient air flow show that for a homogeneous soil medium, the effects of barometric fluctuations are most significant in the cases where soil permeability to air is low and the fluctuation frequency is high. In these cases, the barometric fluctuation can greatly enhance the magnitude of fluxes as well as introduce flow direction reversals from surrounding soil into the basement. These large fluxes with direction reversals have strong implications in regard to advective transport of radon. The results suggest that the transient oscillations have to be accounted for in quantifying radon entry into buildings. In the actual field set up, the transient behavior will be further influenced by soil permeability heterogeneity, by soil moisture variations, and by the effects of multiple periodic components in the barometric pressure fluctuations.
Laboratory experiments of fine-scale mixing and mass transport within a coral canopy
NASA Astrophysics Data System (ADS)
Reidenbach, Matthew A.; Koseff, Jeffrey R.; Monismith, Stephen G.
2007-07-01
Laboratory experiments obtained fine scale measurements of turbulent shear stresses and rates of mixing and mass transfer over a nonliving bed of the coral, Porites compressa, the dominant species found in Kaneohe Bay, Hawaii. A reef canopy was placed in a recirculating wave-current flume and flow was generated that simulated the flow characteristics of the reef flat of Kaneohe Bay. Turbulence and velocity structure under both unidirectional and wave-dominated currents were measured using a two-dimensional laser Doppler anemometer. Mass transport measurements were made using a planar laser-induced fluorescence technique in which the scalar transport of Rhodamine 6G dye, fluxed from the surfaces of the coral, was quantified. Results show that the action of surface waves, interacting with the structure of the reef, can increase instantaneous shear and mixing up to six times compared to that of unidirectional currents. Maximum shear and mass transport events coincided with flow separation within the wave-current boundary layer and the ejection of vortices into the flow. Wave action also acted to increase the vertical flux of water from within the coral structure. The combined effects of increased turbulent stress and fluid exchange from the interior of the canopy increased mass flux due to wave action 2.3±0.5 times that measured for comparable unidirectional currents.
NASA Astrophysics Data System (ADS)
Gorder, Riley; Aliseda, Alberto
2009-11-01
The carotid artery bifurcation (CAB) is one of the leading site for atherosclerosis, a major cause of mortality and morbidity in the developed world. The specific mechanisms by which perturbed flow at the bifurcation and in the carotid bulge promotes plaque formation and growth are not fully understood. Shear stress, mass transport, and flow residence times are considered dominant factors. Shear stress causes restructuring of endothelial cells at the arterial wall which changes the wall's permeability. Long residence times are associated with enhanced mass transport through increased diffusion of lipids and white blood cells into the arterial wall. Although momentum and mass transfer are traditionally coupled by correlations similar to Reynolds Analogy, the complex flow patterns present in this region due to the pulsatile, transitional, detached flow associated with the complex geometry makes the validity of commonly accepted assumptions uncertain. We create solid models of the CAB from MRI or ultrasound medical images, build flow phantoms on clear polyester resin and use an IOR matching, blood mimicking, working fluid. Using PIV and dye injection techniques the shear stress and scalar transport are experimentally investigated. Our goal is to establish a quantitative relationship between momentum and mass transfer under a wide range of physiologically normal and pathological conditions.
Implications of anthropogenic river stage fluctuations on mass transport in a valley fill aquifer
Boutt, D.F.; Fleming, B.J.
2009-01-01
In humid regions a strong coupling between surface water features and groundwater systems may exist. In these environments the exchange of water and solute depends primarily on the hydraulic gradient between the reservoirs. We hypothesize that daily changes in river stage associated with anthropogenic water releases (such as those from a hydroelectric dam) cause anomalous mixing in the near-stream environment by creating large hydraulic head gradients between the stream and adjacent aquifer. We present field observations of hydraulic gradient reversals in a shallow aquifer. Important physical processes observed in the field are explicitly reproduced in a physically based two-dimensional numerical model of groundwater flow coupled to a simplistic surface water boundary condition. Mass transport simulations of a conservative solute introduced into the surface water are performed and examined relative to a stream condition without stage fluctuations. Simulations of 20 d for both fluctuating river stage and fixed high river stage show that more mass is introduced into the aquifer from the stream in the oscillating case even though the net water flux is zero. Enhanced transport by mechanical dispersion leads to mass being driven away from the hydraulic zone of influence of the river. The modification of local hydraulic gradients is likely to be important for understanding dissolved mass transport in near-stream aquifer environments and can influence exchange zone processes under conditions of high-frequency stream stage changes. Copyright 2009 by the American Geophysical Union.
2010-01-01
Background The finite volume solver Fluent (Lebanon, NH, USA) is a computational fluid dynamics software employed to analyse biological mass-transport in the vasculature. A principal consideration for computational modelling of blood-side mass-transport is convection-diffusion discretisation scheme selection. Due to numerous discretisation schemes available when developing a mass-transport numerical model, the results obtained should either be validated against benchmark theoretical solutions or experimentally obtained results. Methods An idealised aneurysm model was selected for the experimental and computational mass-transport analysis of species concentration due to its well-defined recirculation region within the aneurysmal sac, allowing species concentration to vary slowly with time. The experimental results were obtained from fluid samples extracted from a glass aneurysm model, using the direct spectrophometric concentration measurement technique. The computational analysis was conducted using the four convection-diffusion discretisation schemes available to the Fluent user, including the First-Order Upwind, the Power Law, the Second-Order Upwind and the Quadratic Upstream Interpolation for Convective Kinetics (QUICK) schemes. The fluid has a diffusivity of 3.125 × 10-10 m2/s in water, resulting in a Peclet number of 2,560,000, indicating strongly convection-dominated flow. Results The discretisation scheme applied to the solution of the convection-diffusion equation, for blood-side mass-transport within the vasculature, has a significant influence on the resultant species concentration field. The First-Order Upwind and the Power Law schemes produce similar results. The Second-Order Upwind and QUICK schemes also correlate well but differ considerably from the concentration contour plots of the First-Order Upwind and Power Law schemes. The computational results were then compared to the experimental findings. An average error of 140% and 116% was demonstrated
Mass spectroscopic characterization of the GeSe:GeI4 vapor transport system
NASA Technical Reports Server (NTRS)
Buchan, Nicholas I.; Rosenberger, Franz
1987-01-01
The GeSe:GeI4 vapor crystal growth system was characterized mass spectroscopically. A steady-state Knudsen effusion technique was developed to simulate the equilibrium conditions at one end of a vapor transport ampoule. It was found that the previously neglected equilibrium GeSe2(s) = GeSe(v) + 1/2Se2(v) reduces the Se2(v) concentration to an extent that sublimation/condensation of GeSe becomes the dominant transport mechanism. At total pressures near 1 atm the concentration of an additional Ge-Se-I vapor species becomes comparable to that of GeSe(v).
Leung, Juliana Y; Srinivasan, Sanjay
2016-09-01
Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It
NASA Astrophysics Data System (ADS)
Leung, Juliana Y.; Srinivasan, Sanjay
2016-09-01
Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It
Leung, Juliana Y; Srinivasan, Sanjay
2016-09-01
Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It
NASA Astrophysics Data System (ADS)
Anderson, B. E.; Jordan, C. E.; Grant, W. B.; Browell, E. V.; Hudgins, C. H.; Winstead, E. L.; Thornhill, K. L.
2002-12-01
The 2001, NASA Transport and Chemical Evolution over the Pacific (TRACE-P) experiment was conducted during late winter and early spring, the time of year when eastward transport of dust and pollution from southern and central Asia reaches a maximum. From bases of operation in Hong Kong, Japan, and Hawaii, extensive measurements of trace species concentrations and characteristics were made from aboard a P-3B and DC-8 aircraft as they flew coordinated sampling missions within air masses at varying distances from the Asian coast and at altitudes ranging from near surface to over 12 km. Data recorded aboard the DC-8 included total condensation nuclei (CN) number densities and fractional volatility; aerosol size distributions, composition and optical properties; and multi-wavelength profiles of polarized, aerosol backscatter. Examining these data in light of simultaneous meteorological and chemical species measurements, we have calculated the advective flux and mean values of aerosol mass and physical properties at various locations within the Western Pacific Basin. At distances >100 km offshore, we find that the highest fluxes of sub-micron particles occurred below 2 km in the region downwind of Shanghai. These air masses exhibited CN concentrations approaching 50,000 cm-3 and visible scattering coefficients in excess of 200 Mm-1. For near-shore sampling between 26° and 36°N within this height range, these parameters averaged ~8,000 cm-3 and 130 Mm-, respectively, . As a result of dilution, surface deposition, and precipitation scavenging, these values rapidly diminished during eastward transport so that parcels sampled at low altitudes >1500 km from land typically contained ~1000 cm-3 CN and exhibited scattering coefficients <30 Mm-1. Because of the decreased strength of loss processes and greater atmospheric stability, parcels sampled in the 2- to 7-km height range were more apt to maintain their initial aerosol signatures during long-range transport.
Advances in Studies of Electrode Kinetics and Mass Transport in AMTEC Cells (abstract)
NASA Technical Reports Server (NTRS)
Williams, R. M.; Jeffries-Nakamura, B.; Ryan, M. A.; Underwood, M. L.; Kisor, A.; O'Connor, D.; Kikkert, S.
1993-01-01
Previous work reported from JPL has included characterization of electrode kinetics and alkali atom transport from electrodes including Mo, W, WRh(sub x), WPt(sub x)(Mn), in sodium AMTEC cells and vapor exposure cells, and Mo in potassium vapor exposure cells. These studies were generally performed in cells with small area electrodes (about 1 to 5 cm(sup 2)), and device geometry had little effect on transport. Alkali diffusion coefficients through these electrodes have been characterized, and approximate surface diffusion coefficients derived in cases of activated transport. A basic model of electrode kinetic at the alkali metal vapor/porous metal electrode/alkali beta'-alumina solid electrolyte three phase boundary has been proposed which accounts for electrochemical reaction rates with a collision frequency near the three phase boundary and tunneling from the porous electrode partially covered with adsorbed alkali metal atoms. The small electrode effect in AMTEC cells has been discussed in several papers, but quantitative investigations have described only the overall effect and the important contribution of electrolyte resistance. The quantitative characterization of transport losses in cells with large area electrodes has been limited to simulations of large area electrode effects, or characterization of transport losses from large area electrodes with significant longitudinal temperature gradients. This paper describes new investigations of electrochemical kinetics and transport, particularily with WPt(sub 3.5) electrodes, including the influence of electrode size on the mass transport loss in the AMTEC cell. These electrodes possess excellent sodium transport properties making verification of device limitations on transport much more readily attained.
Diapycnal advection by double diffusion and turbulence in the ocean
NASA Astrophysics Data System (ADS)
St. Laurent, Louis Christopher
1999-11-01
Observations of diapycnal mixing rates are examined and related to diapycnal advection for both double-diffusive and turbulent regimes. The role of double-diffusive mixing at the site of the North Atlantic Tracer Release Experiment is considered. The strength of salt-finger mixing is analyzed in terms of the stability parameters for shear and double- diffusive convection, and a nondimensional ratio of the thermal and energy dissipation rates. While the model for turbulence describes most dissipation occurring in high shear, dissipation in low shear is better described by the salt-finger model, and a method for estimating the salt-finger enhancement of the diapycnal haline diffusivity over the thermal diffusivity is proposed. Best agreement between tracer-inferred mixing rates and microstructure based estimates is achieved when the salt- finger enhancement of haline flux is taken into account. The role of turbulence occurring above rough bathymetry in the abyssal Brazil Basin is also considered. The mixing levels along sloping bathymetry exceed the levels observed on ridge crests and canyon floors. Additionally, mixing levels modulate in phase with the spring-neap tidal cycle. A model of the dissipation rate is derived and used to specify the turbulent mixing rate and constrain the diapycnal advection in an inverse model for the steady circulation. The inverse model solution reveals the presence of a secondary circulation with zonal character. These results suggest that mixing in abyssal canyons plays an important role in the mass budget of Antarctic Bottom Water. (Copies available exclusively from MIT Libraries, Rm. 14-0551, Cambridge, MA 02139-4307. Ph. 617-253-5668; Fax 617-253-1690.)
Gluon transport equation with effective mass and dynamical onset of Bose–Einstein condensation
Blaizot, Jean-Paul; Jiang, Yin; Liao, Jinfeng
2016-05-01
In this paper we study the transport equation describing a dense system of gluons, in the small scattering angle approximation, taking into account medium-generated effective masses of the gluons. We focus on the case of overpopulated systems that are driven to Bose–Einstein condensation on their way to thermalization. Lastly, the presence of a mass modifies the dispersion relation of the gluon, as compared to the massless case, but it is shown that this does not change qualitatively the scaling behavior in the vicinity of the onset.
LETTER: Construction of the factorized steady state distribution in models of mass transport
NASA Astrophysics Data System (ADS)
Zia, R. K. P.; Evans, M. R.; Majumdar, Satya N.
2004-10-01
For a class of one-dimensional mass transport models we present a simple and direct test on the chipping functions, which define the probabilities for mass to be transferred to neighbouring sites, to determine whether the stationary distribution is factorized. In cases where the answer is affirmative, we provide an explicit method for constructing the single-site weight function. As an illustration of the power of this approach, previously known results on the zero-range process and asymmetric random average process are recovered in a few lines. We also construct new models, namely a generalized zero-range process and a binomial chipping model, which have factorized steady states.
Technologies involved in configuring an advanced earth-to-orbit transport for low structural mass
NASA Technical Reports Server (NTRS)
Macconochie, I. O.; Klich, P. J.
1980-01-01
A tradeoff study for a single-stage, earth-to-orbit transport spacecraft configured with low structural mass as the prime objective is presented. Among the major design elements affecting vehicle mass are: maneuverability and re-entry heating, the compatibility of an irregular cargo bay geometry to future mission requirements, the fabrication and assembly of large honeycomb structure fuselage sections, and the development of LOX/LH2 engine extendable nozzles and dual-propulsion schemes. It is shown that vehicle geometry and materials and structural technologies will be the critical areas in the development of such a system.
A Twophase Multirate-Mass Transfer Model for Flow and Transport in Porous Media
NASA Astrophysics Data System (ADS)
Dentz, M.; Tecklenburg, J.; Neuweiler, I.; Carrera, J.
2015-12-01
We present an upscaled non-local model for two-phase flow and transport in highly heterogeneous porous media. The media under consideration are characterized by sharp contrasts in the hydraulic properties typical for fractured porous media, for example. A two-scale expansion gives an upscaled flow and transport formulation that models multiratemass transfer between mobile (fracture) and immobile (matrix) medium portions. The evolution of saturation due to viscous dominated flow in the mobile domain and mass exchange with the immobile zones through capillary countercurrent flow. The medium heterogeneity is mapped onto the mass transfer parameters, which are encoded in a memory functionthat describes the non-local flux between mobile and immobile zones. The upscaled model is parameterized by the medium heterogeneity and the distribution of hydraulic parameters. Breakthrough of the displaced fluidshows characteristic heavy tails due to fluid retention in immobile zones.
Heat and mass transport resistances in vacuum membrane distillation per drop
Bandini, S.; Sarti, G.C.
1999-07-01
Vacuum membrane distillation (VMD) is a separation process based on the use of microporous hydrophobic membranes. The membrane is located between an aqueous phase and a permeate, which is kept under vacuum at pressure values below the equilibrium vapor pressure of the feed. The liquid stream vaporizes at one side of the membrane, and the vapors diffuse through the gas phase inside the membrane pores. The process rate and performance are affected highly by the transport phenomena both in the liquid phase and through the membrane. Heat- and mass-transfer resistance in the liquid phase, as well as mass-transfer resistance through the membrane, play an important role in determining the process performance. Based on VMD experimental data for several binary aqueous mixtures containing volatile organic compounds, a simple criterion to investigate the role of each transport resistance on the separation efficiency is discussed.
NASA Astrophysics Data System (ADS)
Zhang, Jiaping; Zhao, Xuanhe; Suo, Zhigang; Jiang, Hanqing
2009-05-01
A gel is an aggregate of polymers and solvent molecules. The polymers crosslink into a three-dimensional network by strong chemical bonds and enable the gel to retain its shape after a large deformation. The solvent molecules, however, interact among themselves and with the network by weak physical bonds and enable the gel to be a conduit of mass transport. The time-dependent concurrent process of large deformation and mass transport is studied by developing a finite element method. We combine the kinematics of large deformation, the conservation of the solvent molecules, the conditions of local equilibrium, and the kinetics of migration to evolve simultaneously two fields: the displacement of the network and the chemical potential of the solvent. The finite element method is demonstrated by analyzing several phenomena, such as swelling, draining and buckling. This work builds a platform to study diverse phenomena in gels with spatial and temporal complexity.
Performance of intact and partially degraded concrete barriers in limiting mass transport
Walton, J.C. )
1992-06-01
Mass transport through concrete barriers and release rate from concrete vaults are quantitatively evaluated. The thorny issue of appropriate diffusion coefficients for use in performance assessment calculations is covered, with no ultimate solution found. Release from monolithic concrete vaults composed of concrete waste forms is estimated with a semi-analytical solution. A parametric study illustrates the importance of different parameters on release. A second situation of importance is the role of a concrete shell or vault placed around typical waste forms in limiting mass transport. In both situations, the primary factor controlling concrete performance is cracks. The implications of leaching behavior on likely groundwater concentrations is examined. Frequently, lower groundwater concentrations can be expected in the absence of engineered covers that reduce infiltration.
Upscaling momentum and mass transport under Knudsen and binary diffusion gas slip conditions
NASA Astrophysics Data System (ADS)
Valdes-Parada, F. J.; Lasseux, D.
2015-12-01
Modeling of gas phase flow in porous media is relevant as it is present in a wide variety of applications ranging from nanofluidic systems to subsurface contaminant transport. In this work, we derive a macroscopic model to study slightly compressible gas flow in porous media for conditions in which the tangential fluid velocity undergoes a slip at the solid interface due to Knudsen effects and to mass diffusion in binary conditions. To this end, we use the method of volume averaging to derive the governing equations at the Darcy scale for both mass and momentum transport. The momentum transport model consists on a modification to Darcy's law due to mass dispersion and to total density gradients. For mass transport, the resulting model is the conventional convection-dispersion equation with two correction terms, one affecting convective transport and the second one affecting mass dispersion due to gas compressibility. The macroscopic model reduces to the one reported by Altevogt et al. (2003) for the case in which gas slip is only due to a concentration gradient and to the one by Lasseux et al. (2014) under Knudsen slip conditions. The model is written in terms of effective-medium coefficients that can be predicted from solving the associated closure problems in representative unit cells. For conditions in which the Péclet number is much greater than one and when the Knudsen number is not exceedingly small compared to the unity, our computations show that the predictions of the longitudinal dispersion may reach an error as high as 60% compared to the predictions obtained by ignoring gas slip. Altevogt A.S., Rolston D.E., Whitaker S. New equations for binary gas transport in porous media, Part 1: equation development. Advances in Water Resources, Vol. 26, 695-715, 2003. Lasseux D., Valdés-Parada F.J., Ochoa-Tapia J.A., Goyeau B. A macroscopic model for slightly compressible gas slip-flow in homogeneous porous media. Physics of Fluids, Vol. 26, 053102, 2014.
On dynamical formulations of a tethered satellite system with mass transport
NASA Astrophysics Data System (ADS)
Liu, F. C.
1985-01-01
Two satellites connected by a long flexible tether along the earth radial direction comprise a stable equilibrium state. This paper deals with formulations of in-plane motion of the tether connected satellites with a third mass transporting from one satellite to the other. Systems of equations of motion formulated by two methods, Lagrange equations and D'Alembert's Principle, are presented and methods for numerical solutions are proposed. Initial conditions for inward and outward transfers are derived.
NASA Astrophysics Data System (ADS)
Favier, J. J.; Garandet, J. P.; Rouzaud, A.; Camel, D.
1994-06-01
The MEPHISTO space facility flew on the Columbia space shuttle in October 1992. The preliminary scientific results, mainly based on the analysis of the Seebeck signal, are presented in this paper. Valuable information was obtained for both planar and cellular solidification regimes. It is shown that mass transfer in the melt during the flight was principally diffusive; however, even in microgravity, slow growth rates may result in significant convective transport. A tentative interpretation of the Seebeck signal for destabilized interfaces is also proposed.
Final Report - Ion Production and Transport in Atmospheric Pressure Ion Source Mass Spectrometers
Farnsworth, Paul B.; Spencer, Ross L.
2014-05-14
This document is the final report on a project that focused in the general theme of atmospheric-pressure ion production and transport for mass spectrometry. Within that general theme there were two main projects: the fundamental study of the transport of elemental ions through the vacuum interface of an inductively coupled plasma mass spectrometer (ICPMS), and fundamental studies of the ionization mechanisms in ambient desorption/ionization (ADI) sources for molecular mass spectrometry. In both cases the goal was to generate fundamental understanding of key instrumental processes that would lead to the development of instruments that were more sensitive and more consistent in their performance. The emphasis on consistency derives from the need for instruments that have the same sensitivity, regardless of sample type. In the jargon of analytical chemistry, such instruments are said to be free from matrix effects. In the ICPMS work each stage of ion production and of ion transport from the atmospheric pressure to the high-vacuum mass analyzer was studied. Factors controlling ion transport efficiency and consistency were identified at each stage of pressure reduction. In the ADI work the interactions between an electrospray plume and a fluorescent sample on a surface were examined microscopically. A new mechanism for analyte ion production in desorption electrospray ionization (DESI) was proposed. Optical spectroscopy was used to track the production of reactive species in plasmas used as ADI sources. Experiments with mixed-gas plasmas demonstrated that the addition of a small amount of hydrogen to a helium ADI plasma could boost the sensitivity for some analytes by over an order of magnitude.
Ovtchinnikov, Mikhail; Easter, Richard C.
2009-02-01
Monotonicity constraints and gradient preserving flux corrections employed by many advection algorithms used in atmospheric models make these algorithms non-linear. Consequently, any relations among model variables transported separately are not necessarily preserved in such models. These errors cannot be revealed by traditional algorithm testing based on advection of a single tracer. New type of tests are developed and conducted to evaluate the preservation of a sum of several number mixing ratios advected independently of each other, as is the case, for example, in models using bin or sectional representation of aerosol or cloud particle size distribution. The tests show that when three tracers are advected in 1D uniform constant velocity flow, local errors in the sum can be on the order of 10%. When cloud-like interactions are allowed among the tracers, errors in total sum of three mixing ratios can reach up to 30%. Several approaches to eliminate the error are suggested, all based on advecting the sum as a separate variable and then normalizing mixing ratios for individual tracers to match the total sum. A simple scalar normalization preserves the total number mixing ratio and positive definiteness of the variables but the monotonicity constraint for individual tracers is no longer maintained. More involved flux normalization procedures are developed for the flux based advection algorithms to maintain the monotonicity for individual scalars and their sum.
NASA Astrophysics Data System (ADS)
Matiatos, Ioannis; Varouhakis, Emmanouil A.; Papadopoulou, Maria P.
2015-04-01
As the sustainable use of groundwater resources is a great challenge for many countries in the world, groundwater modeling has become a very useful and well established tool for studying groundwater management problems. Based on various methods used to numerically solve algebraic equations representing groundwater flow and contaminant mass transport, numerical models are mainly divided into Finite Difference-based and Finite Element-based models. The present study aims at evaluating the performance of a finite difference-based (MODFLOW-MT3DMS), a finite element-based (FEFLOW) and a hybrid finite element and finite difference (Princeton Transport Code-PTC) groundwater numerical models simulating groundwater flow and nitrate mass transport in the alluvial aquifer of Trizina region in NE Peloponnese, Greece. The calibration of groundwater flow in all models was performed using groundwater hydraulic head data from seven stress periods and the validation was based on a series of hydraulic head data for two stress periods in sufficient numbers of observation locations. The same periods were used for the calibration of nitrate mass transport. The calibration and validation of the three models revealed that the simulated values of hydraulic heads and nitrate mass concentrations coincide well with the observed ones. The models' performance was assessed by performing a statistical analysis of these different types of numerical algorithms. A number of metrics, such as Mean Absolute Error (MAE), Root Mean Square Error (RMSE), Bias, Nash Sutcliffe Model Efficiency (NSE) and Reliability Index (RI) were used allowing the direct comparison of models' performance. Spatiotemporal Kriging (STRK) was also applied using separable and non-separable spatiotemporal variograms to predict water table level and nitrate concentration at each sampling station for two selected hydrological stress periods. The predictions were validated using the respective measured values. Maps of water table
Advection-Dominated Accretion Disks: Geometrically Slim or Thick?
NASA Astrophysics Data System (ADS)
Gu, Wei-Min; Xue, Li; Liu, Tong; Lu, Ju-Fu
2009-12-01
We revisit the vertical structure of black-hole accretion disks in spherical coordinates. By comparing the advective cooling with the viscous heating, we show that advection-dominated disks are geometrically thick, i.e., with a half-opening angle of Δθ > 2π/5, rather than being slim, as supposed previously in the literature.
Glassman, Erik S; Parrillo, Steven J
2010-01-01
The purpose of this discussion is to review the use of destinations other than the hospital emergency department, to transport patients injured as a result of a mass-casualty incident (MCI). A MCI has the ability to overwhelm traditional hospital resources normally thought of as appropriate destinations for the transport of injured patients. As a result, those with less severe injuries often are required to wait before they can receive definitive treatment. This waiting period, either at the scene of the incident or in the emergency department, can increase morbidity and drain resources that can be better directed toward the transport and care of those more severely injured. Potential alternate transport destinations include physician office buildings, ambulatory care centers, ambulatory surgery centers, and urgent care centers. By allowing for transport to alternate locations, these less severely injured patients can be removed rapidly from the scene, treated, and potentially released. This effort can decrease the strain on traditional resources within the system, better allowing these resources to treat more seriously injured patients.
Generalized Fourier Analyses of Semi-Discretizations of the Advection-Diffusion Equation
CHRISTON, MARK A.; VOTH, THOMAS E.; MARTINEZ, MARIO J.
2002-11-01
This report presents a detailed multi-methods comparison of the spatial errors associated with finite difference, finite element and finite volume semi-discretizations of the scalar advection-diffusion equation. The errors are reported in terms of non-dimensional phase and group speeds, discrete diffusivity, artificial diffusivity, and grid-induced anisotropy. It is demonstrated that Fourier analysis (aka von Neumann analysis) provides an automatic process for separating the spectral behavior of the discrete advective operator into its symmetric dissipative and skew-symmetric advective components. Further it is demonstrated that streamline upwind Petrov-Galerkin and its control-volume finite element analogue, streamline upwind control-volume, produce both an artificial diffusivity and an artificial phase speed in addition to the usual semi-discrete artifacts observed in the discrete phase speed, group speed and diffusivity. For each of the numerical methods considered, asymptotic truncation error and resolution estimates are presented for the limiting cases of pure advection and pure diffusion. The Galerkin finite element method and its streamline upwind derivatives are shown to exhibit super-convergent behavior in terms of phase and group speed when a consistent mass matrix is used in the formulation. In contrast, the CVFEM method and its streamline upwind derivatives yield strictly second-order behavior. While this work can only be considered a first step in a comprehensive multi-methods analysis and comparison, it serves to identify some of the relative strengths and weaknesses of multiple numerical methods in a common mathematical framework.
NASA Astrophysics Data System (ADS)
Schelenz, Sophie; Dietrich, Peter; Vienken, Thomas
2016-04-01
A sustainable thermal exploitation of the shallow subsurface requires a precise understanding of all relevant heat transport processes. Currently, planning practice of shallow geothermal systems (especially for systems < 30 kW) focuses on conductive heat transport as the main energy source while the impact of groundwater flow as the driver for advective heat transport is neglected or strongly simplified. The presented study proves that those simplifications of complex geological and hydrogeological subsurface characteristics are insufficient for a precise evaluation of site-specific energy extraction rates. Based on synthetic model scenarios with varying subsurface conditions (groundwater flow velocity and aquifer thickness) the impact of advection on induced long term temperature changes in 5 and 10 m distance of the borehole heat exchanger is presented. Extending known investigations, this study enhances the evaluation of shallow geothermal energy extraction rates by considering conductive and advective heat transport under varying aquifer thicknesses. Further, it evaluates the impact of advection on installation lengths of the borehole heat exchanger to optimize the initial financial investment. Finally, an evaluation approach is presented that classifies relevant heat transport processes according to their Péclet number to enable a first quantitative assessment of the subsurface energy regime and recommend further investigation and planning procedures.
Analysis of moisture advection during explosive cyclogenesis over North Atlantic Ocean
NASA Astrophysics Data System (ADS)
Ordóñez, Paulina; Liberato, Margarida L. R.; Pinto, Joaquim G.; Trigo, Ricardo M.
2013-04-01
The development of a mid-latitude cyclone may strongly be amplified by the presence of a very warm and moist air mass within its warm sector through enhanced latent heat release. In this work, a lagrangian approach is applied to examine the contribution of moisture advection to the deepening of cyclones over the North Atlantic Ocean. The warm sector is represented by a 5°x5° longitude/latitude moving box comprising the centre of the cyclone and its south-eastern area is defined for the tracks of different cyclones computed at 6-hourly intervals. Using the lagrangian particle model FLEXPART we evaluated the fresh water flux (E - P) along 2-days back-trajectories of the particles residing on the total column over the defined boxes for case studies occurring during winter months from 1980 to 2000. FLEXPART simulations were performed using one degree resolution and 60 model vertical levels available in ERA40 Reanalyses at 00, 06, 12, 18 UTC for each case. Sensitivity studies on the dimensions of the target area - chosen boxes representing the warm sector -, and on its relative position to the center, were performed. We have applied this methodology to several case studies of independent North Atlantic cyclones with notorious characteristics (e.g. deepening rate, wind speed, surface damages). Results indicate that the moisture transport is particularly relevant in what concerns the fast/explosive development stage of these extratropical cyclones. In particular, the advection of moist air from the subtropics towards the cyclone core is clearly associated with the warm conveyor belt of the cyclone. This methodology can be generalized to a much larger number of mid-latitude cyclones, providing a unique opportunity to analyze the moisture behavior associated with the explosive development. Acknowledgments: This work was partially supported by FEDER (Fundo Europeu de Desenvolvimento Regional) funds through the COMPETE (Programa Operacional Factores de Competitividade
A micro-mapping strategy to investigate mechanical and chemical mass transport in migmatite
NASA Astrophysics Data System (ADS)
Lanari, Pierre; Riel, Nicolas
2016-04-01
Migmatites are fantastic objects to study both mechanical and chemical mass transport occurring at mm to cm-scale. However, migmatitic outcrops are the result of complex space and time interactions between (i) melt producing reactions, (ii) melt gain/loss and (iii) retrograde reactions. This succession of events is recorded in the minerals and microstructures of migmatites, and accounts for their apparent complexity. In order to explore the controlling parameters of these chemico-mechanical mass transport, it is thus necessary to characterize in great details the compositional changes between the different migmatitic domains, such as between leucosome and residuum. In this contribution we show how suitable local effective bulk (LEB) compositions can be derived by means of standardized microprobe X-ray images, using the program XMapTools. For chemically heterogeneous samples, such as migmatites, these LEB allow to forward model the stable mineral assemblages for each domain. Those thermodynamic models are used to investigate the conditions of leucosome-residuum separation. The studied sample is a metapelite embedded within a metasedimentary xenolith in the Marcabeli pluton, El Oro Complex, Ecuador. The sample exhibits complex mineral patterns due to local melt redistribution (at mm to cm-scale). Such physical mass transport involves major changes that affect the local chemical composition observed today. At the same time gradients in chemical potential can be established between adjacent domains such as residuum and leucosome, thus triggering chemical interaction. Diffusive transport between domains aims to reduce such chemical potential gradients. Along a modelled P-T path the chemical and mineralogical evolution of micro-domains can be reconstructed for (at least the reactive parts of) the crystallization history.
NASA Astrophysics Data System (ADS)
Ciarletta, P.; Ambrosi, D.; Maugin, G. A.
2012-03-01
In this work, we derive a novel thermo-mechanical theory for growth and remodeling of biological materials in morphogenetic processes. This second gradient hyperelastic theory is the first attempt to describe both volumetric growth and mass transport phenomena in a single-phase continuum model, where both stress- and shape-dependent growth regulations can be investigated. The diffusion of biochemical species (e.g. morphogens, growth factors, migration signals) inside the material is driven by configurational forces, enforced in the balance equations and in the set of constitutive relations. Mass transport is found to depend both on first- and on second-order material connections, possibly withstanding a chemotactic behavior with respect to diffusing molecules. We find that the driving forces of mass diffusion can be written in terms of covariant material derivatives reflecting, in a purely geometrical manner, the presence of a (first-order) torsion and a (second-order) curvature. Thermodynamical arguments show that the Eshelby stress and hyperstress tensors drive the rearrangement of the first- and second-order material inhomogeneities, respectively. In particular, an evolution law is proposed for the first-order transplant, extending a well-known result for inelastic materials. Moreover, we define the first stress-driven evolution law of the second-order transplant in function of the completely material Eshelby hyperstress. The theory is applied to two biomechanical examples, showing how an Eshelbian coupling can coordinate volumetric growth, mass transport and internal stress state, both in physiological and pathological conditions. Finally, possible applications of the proposed model are discussed for studying the unknown regulation mechanisms in morphogenetic processes, as well as for optimizing scaffold architecture in regenerative medicine and tissue engineering.
A tracer-based inversion method for diagnosing eddy-induced diffusivity and advection
NASA Astrophysics Data System (ADS)
Bachman, S. D.; Fox-Kemper, B.; Bryan, F. O.
2015-02-01
A diagnosis method is presented which inverts a set of tracer flux statistics into an eddy-induced transport intended to apply for all tracers. The underlying assumption is that a linear flux-gradient relationship describes eddy-induced tracer transport, but a full tensor coefficient is assumed rather than a scalar coefficient which allows for down-gradient and skew transports. Thus, Lagrangian advection and anisotropic diffusion not necessarily aligned with the tracer gradient can be diagnosed. In this method, multiple passive tracers are initialized in an eddy-resolving flow simulation. Their spatially-averaged gradients form a matrix, where the gradient of each tracer is assumed to satisfy an identical flux-gradient relationship. The resulting linear system, which is overdetermined when using more than three tracers, is then solved to obtain an eddy transport tensor R which describes the eddy advection (antisymmetric part of R) and potentially anisotropic diffusion (symmetric part of R) in terms of coarse-grained variables. The mathematical basis for this inversion method is presented here, along with practical guidelines for its implementation. We present recommendations for initialization of the passive tracers, maintaining the required misalignment of the tracer gradients, correcting for nonconservative effects, and quantifying the error in the diagnosed transport tensor. A method is proposed to find unique, tracer-independent, distinct rotational and divergent Lagrangian transport operators, but the results indicate that these operators are not meaningfully relatable to tracer-independent eddy advection or diffusion. With the optimal method of diagnosis, the diagnosed transport tensor is capable of predicting the fluxes of other tracers that are withheld from the diagnosis, including even active tracers such as buoyancy, such that relative errors of 14% or less are found.
Vande Geest, Jonathan P; Simon, B R; Rigby, Paul H; Newberg, Tyler P
2011-04-01
Finite element models (FEMs) including characteristic large deformations in highly nonlinear materials (hyperelasticity and coupled diffusive/convective transport of neutral mobile species) will allow quantitative study of in vivo tissues. Such FEMs will provide basic understanding of normal and pathological tissue responses and lead to optimization of local drug delivery strategies. We present a coupled porohyperelastic mass transport (PHEXPT) finite element approach developed using a commercially available ABAQUS finite element software. The PHEXPT transient simulations are based on sequential solution of the porohyperelastic (PHE) and mass transport (XPT) problems where an Eulerian PHE FEM is coupled to a Lagrangian XPT FEM using a custom-written FORTRAN program. The PHEXPT theoretical background is derived in the context of porous media transport theory and extended to ABAQUS finite element formulations. The essential assumptions needed in order to use ABAQUS are clearly identified in the derivation. Representative benchmark finite element simulations are provided along with analytical solutions (when appropriate). These simulations demonstrate the differences in transient and steady state responses including finite deformations, total stress, fluid pressure, relative fluid, and mobile species flux. A detailed description of important model considerations (e.g., material property functions and jump discontinuities at material interfaces) is also presented in the context of finite deformations. The ABAQUS-based PHEXPT approach enables the use of the available ABAQUS capabilities (interactive FEM mesh generation, finite element libraries, nonlinear material laws, pre- and postprocessing, etc.). PHEXPT FEMs can be used to simulate the transport of a relatively large neutral species (negligible osmotic fluid flux) in highly deformable hydrated soft tissues and tissue-engineered materials. PMID:21428686
1. Transport of Mass, Momentum and Energy in Planetary Magnetodisc Regions
NASA Astrophysics Data System (ADS)
Achilleos, Nicholas; André, Nicolas; Blanco-Cano, Xochitl; Brandt, Pontus C.; Delamere, Peter A.; Winglee, Robert
2015-04-01
The rapid rotation of the gas giant planets, Jupiter and Saturn, leads to the formation of magnetodisc regions in their magnetospheric environments. In these regions, relatively cold plasma is confined towards the equatorial regions, and the magnetic field generated by the azimuthal (ring) current adds to the planetary dipole, forming radially distended field lines near the equatorial plane. The ensuing force balance in the equatorial magnetodisc is strongly influenced by centrifugal stress and by the thermal pressure of hot ion populations, whose thermal energy is large compared to the magnitude of their centrifugal potential energy. The sources of plasma for the Jovian and Kronian magnetospheres are the respective satellites Io (a volcanic moon) and Enceladus (an icy moon). The plasma produced by these sources is globally transported outwards through the respective magnetosphere, and ultimately lost from the system. One of the most studied mechanisms for this transport is flux tube interchange, a plasma instability which displaces mass but does not displace magnetic flux—an important observational constraint for any transport process. Pressure anisotropy is likely to play a role in the loss of plasma from these magnetospheres. This is especially the case for the Jovian system, which can harbour strong parallel pressures at the equatorial segments of rotating, expanding flux tubes, leading to these regions becoming unstable, blowing open and releasing their plasma. Plasma mass loss is also associated with magnetic reconnection events in the magnetotail regions. In this overview, we summarise some important observational and theoretical concepts associated with the production and transport of plasma in giant planet magnetodiscs. We begin by considering aspects of force balance in these systems, and their coupling with the ionospheres of their parent planets. We then describe the role of the interaction between neutral and ionized species, and how it determines
Modelling mass transport through a porous partition: Effect of pore size distribution
NASA Astrophysics Data System (ADS)
Khayet, Mohamed; Velázquez, Armando; Mengual, Juan I.
2004-09-01
Direct contact membrane distillation process has been studied using microporous polytetrafluoroethylene and polyvinylidene fluoride membranes. The membranes were characterized in terms of their non-wettability, pore size distribution and porosity. The mean pore sizes and pore size distributions were obtained by means of wet/dry flow method. The mean pore size and the effective porosity of the membranes were also determined from the gas permeation test. A theoretical model that considers the pore size distribution together with the gas transport mechanisms through the membrane pores was developed for this process. The contribution of each mass transport mechanism was analyzed. It was found that both membranes have pore size distributions in the Knudsen region and in the transition between Knudsen and ordinary diffusion region. The transition region was the major contribution to mass transport. The predicted water vapor permeability of the membranes were compared with the experimental ones. The effect of considering pore size distribution instead of mean pore size to predict the water vapor permeability of the membranes was investigated.
Analysis of hemodynamic fluid phase mass transport in a separated flow region.
Lutostansky, Elizabeth M; Karner, Gerhard; Rappitsch, Gerhard; Ku, David N; Perktold, Karl
2003-04-01
The mass transfer behavior in the recirculation region downstream of an axisymmetric sudden expansion was examined. The Reynolds number, 500, and Schmidt number, 3200, were selected to model the mass transfer of molecules, such as ADP, in the arterial system. In a first step the transient mass transport applying zero diffusive flux at the wall was analyzed using experiments and two computational codes. The two codes were FLUENT, a commercially available finite volume method, and FTSP, a finite element code developed at Graz University of Technology. The comparison of the transient wall concentration values determined by the three methods was excellent and provides a measure of confidence for computational mass transfer calculations in convection dominated, separated flows. In a second step the effect of the flow separation on the stationary mass transport applying a permeability boundary condition at the water-permeable wall was analyzed using the finite element code FTSP. The results show an increase of luminal ADP surface concentration in the upstream and in the downstream tube of the sudden expansion geometry in the range of six and twelve percent of the bulk flow concentration. The effect of flow separation in the downstream tube on the wall concentration is a decrease of about ten percent of the difference between wall concentration and bulk concentration occurring at nearly fully developed flow at the downstream region at a distance of 66 downstream tube diameters from the expansion. The decrease of ADP flux into the wall is in the range of three percent of the flux at the downstream region. PMID:12751280
Mass-corrections for the conservative coupling of flow and transport on collocated meshes
NASA Astrophysics Data System (ADS)
Waluga, Christian; Wohlmuth, Barbara; Rüde, Ulrich
2016-01-01
Buoyancy-driven flow models demand a careful treatment of the mass-balance equation to avoid spurious source and sink terms in the non-linear coupling between flow and transport. In the context of finite-elements, it is therefore commonly proposed to employ sufficiently rich pressure spaces, containing piecewise constant shape functions to obtain local or even strong mass-conservation. In three-dimensional computations, this usually requires nonconforming approaches, special meshes or higher order velocities, which make these schemes prohibitively expensive for some applications and complicate the implementation into legacy code. In this paper, we therefore propose a lean and conservatively coupled scheme based on standard stabilized linear equal-order finite elements for the Stokes part and vertex-centered finite volumes for the energy equation. We show that in a weak mass-balance it is possible to recover exact conservation properties by a local flux-correction which can be computed efficiently on the control volume boundaries of the transport mesh. We discuss implementation aspects and demonstrate the effectiveness of the flux-correction by different two- and three-dimensional examples which are motivated by geophysical applications.
Electrohydrodynamically Driven Chaotic Advection in Drops
NASA Astrophysics Data System (ADS)
Ward, Thomas; Homsy, G. M.
2002-11-01
When a liquid drop of given dielectric constant, resistivity and viscosity is translating in a liquid of different dielectric constant, resistivity and viscosity under Stokes flow conditions in the presence of an electric field, the resulting internal circulation is a superposition of the Hadamard-Rybcynski circulation and the circulation first described theoretically by G. I. Taylor. For sufficiently strong electric field strengths, the quadrapole structure of the Taylor circulation can cause an internal stagnation disk to occur. Our interest is in the situation where a modulation of the electric field causes the stagnation disk to modulate its position, potentially leading to chaotic flows within the drop. The dimensionless electric field strength is characterized by W = 4V(1+lambda)/U where V is the maximum interfacial velocity of the Taylor circulation, U the translational velocity, and lambda the viscosity ratio. The streamfunction for the flow is: 1) psi = (r4-r2) sin2)(theta + W(t) (r3 - r5) sin2 (theta) cos(theta) 2) W(t) = W1 + W2 cos ((epsilon)t) where epsilon is the dimensionless frequency, and W1, W2 are the amplitudes of the DC and AC components, respectively. We have found it useful to replace these parameters by a secondary set, epsilon, Wmax and delta = (1 / W1 - 1 / W2) - (1 / W1 + 1 / W2). As shown in Figure 1a, delta is the dimensionless distance the stagnation disk moves over one period of modulation. The advection equations corresponding to the flow were integrated by standard techniques, and it was found that the trajectories were chaotic over a wide range of parameters. Experiments were conducted to test the predictions of rapid mixing on convective time scales. Drops of silicon oil were suspended in a small 60 mm x 120 mm x 120 mm test cell filled with castor oil, and subject to time-modulated axial electric fields with a wave form corresponding to eq(2). The drops were typically 5 mm in diameter and settled with typical speeds of O(10-1 mm
Oligomers Modulate Interfibril Branching and Mass Transport Properties of Collagen Matrices
Whittington, Catherine F.; Brandner, Eric; Teo, Ka Yaw; Han, Bumsoo; Nauman, Eric; Voytik-Harbin, Sherry L.
2013-01-01
Mass transport within collagen-based matrices is critical to tissue development, repair, and pathogenesis as well as the design of next generation tissue engineering strategies. This work shows how collagen precursors, specified by intermolecular cross-link composition, provide independent control of collagen matrix mechanical and transport properties. Collagen matrices were prepared from tissue-extracted monomers or oligomers. Viscoelastic behavior was measured in oscillatory shear and unconfined compression. Matrix permeability and diffusivity were measured using gravity-driven permeametry and integrated optical imaging, respectively. Both collagen types showed an increase in stiffness and permeability hindrance with increasing collagen concentration (fibril density); however, different physical property-concentration relationships were noted. Diffusivity wasn’t affected by concentration for either collagen type over the range tested. In general, oligomer matrices exhibited a substantial increase in stiffness and only a modest decrease in transport properties when compared to monomer matrices prepared at the same concentration. The observed differences in viscoelastic and transport properties were largely attributed to increased levels of interfibril branching within oligomer matrices. The ability to relate physical properties to relevant microstructure parameters, including fibril density and interfibril branching, is expected to advance the understanding of cell-matrix signaling as well as facilitate model-based prediction and design of matrix-based therapeutic strategies. PMID:23842082
Particulate export vs lateral advection in the Antarctic Polar Front (Southern Pacific Ocean)
NASA Astrophysics Data System (ADS)
Tesi, T.; Langone, L.; Ravaioli, M.; Capotondi, L.; Giglio, F.
2012-04-01
The overarching goal of our study was to describe and quantify the influence of lateral advection relative to the vertical export in the Antarctic Polar Front (Southern Pacific Ocean). In areas where lateral advection of particulate material is significant, budgets of bioactive elements can be inaccurate if fluxes through the water column and to the seabed are exclusively interpreted as passive sinking of particles. However, detailed information on the influence of lateral advection in the water column in the southern ocean is lacking. With this in mind, our study focused between the twilight zone (i.e. mesopelagic) and the benthic nepheloid layer to understand the relative importance of lateral flux with increasing water depth. Measurements were performed south of the Antarctic Polar Front for 1 year (January 10th 1999-January 3rd 2000) at 900, 1300, 2400, and 3700 m from the sea surface. The study was carried out using a 3.5 km long mooring line instrumented with sediment traps, current meters and sensors of temperature and conductivity. Sediment trap samples were characterized via several parameters including total mass flux, elemental composition (organic carbon, total nitrogen, biogenic silica, and calcium carbonate), concentration of metals (aluminum, iron, barium, and manganese), 210Pb activity, and foraminifera taxonomy. High fluxes of biogenic particles were observed in both summer 1999 and 2000 as a result of seasonal algal blooms associated with sea ice retreat and water column stratification. During no-productive periods, several high energy events occurred and resulted in advecting resuspended biogenic particles from flat-topped summits of the Pacific Antarctic Ridge. Whereas the distance between seabed and uppermost sediment traps was sufficient to avoid lateral advection processes, resuspension was significant in the lowermost sediment traps accounting for ~60 and ~90% of the material caught at 2400 and 3700 m, respectively. Samples collected during
Oscillatory Mass Transport in Vapor-Liquid-Solid Growth of Sapphire Nanowires
Oh, Sang Ho; Chisholm, Matthew F; Kauffmann, Yaron; Kaplan, Prof. Wayne D.; Luo, Weidong; Ruhle, M.; Scheu, Christina
2010-01-01
In vapor-liquid-solid (VLS) growth, the liquid phase plays a pivotal role in mediating mass transport from the vapor source to the growth front of a nanowire. Such transport often takes place through the liquid phase. However, we observed by in situ transmission electron microscopy a different behavior for self-catalytic VLS growth of sapphire nanowires. The growth occurs in a layer-by-layer fashion and is accomplished by interfacial diffusion of oxygen through the ordered liquid aluminum atoms. Oscillatory growth and dissolution reactions at the top rim of the nanowires occur and supply the oxygen required to grow a new (0006) sapphire layer. A periodic modulation of the VLS triple-junction configuration accompanies these oscillatory reactions.
Comparison of Flamelet Models with the Transported Mass Fraction Approach for Supersonic Combustion
NASA Astrophysics Data System (ADS)
Li, Wenhai; Alabi, Ken; Ladeinde, Foluso
2015-11-01
In this study, two fully compressible RANS, LES, and combined RANS/LES flow solvers - AEROFLO and VULCAN, both of which were originally developed by the United States Department of Defense but have since been significantly enhanced and commercialized by our organization, are used to investigate the accuracy of flamelet-based approach when employed to model supersonic combustion. The flamelet results from both codes are assessed relative to solutions obtained by solving the transport equations for the mass fractions - which is also supported by one of the codes, and making familiar assumptions about the closure of the reaction rate. The studies are carried out in the flamelet regime, and the numerical procedures are based on high-order schemes, which are also used to solve the level-set and mixture fraction transport equations used to study, respectively, premixed and non-premixed combustion. The effects of supersonic Mach numbers on the results are discussed.
Numerical investigation of mass transport through patient-specific deformed aortae.
Chen, Jie; Gutmark, Ephraim; Mylavarapu, Goutham; Backeljauw, Philippe F; Gutmark-Little, Iris
2014-01-22
Blood flow in human arteries has been investigated using computational fluid dynamics tools. This paper considers flow modeling through three aorta models reconstructed from cross-sectional magnetic resonance scans of female patients. One has the normal control configuration, the second has elongation of the transverse aorta, and the third has tortuosity of the aorta with stenosis. The objective of this study is to determine the impact of aortic abnormal geometries on the wall shear stress (WSS), luminal surface low-density lipoproteins (LDLs) concentration, and oxygen flux along the arterial wall. The results show that the curvature of the aortic arch and the stenosis have significant effects on the blood flow, and in turn, the mass transport. The location of hypoxia areas can be predicted well by ignoring the effect of hemoglobin on the oxygen transport. However, this simplification indeed alters the absolute value of Sherwood number on the wall. PMID:24210472
Horizontal Advection and Mixing of Pollutants in the Urban Atmospheric Environment
NASA Astrophysics Data System (ADS)
Magnusson, S. P.; Entekhabi, D.; Britter, R.; Norford, L.; Fernando, H. J.
2013-12-01
Although urban air quality and its impacts on the public health have long been studied, the increasing urbanization is raising concerns on how to better control and mitigate these health impacts. A necessary element in predicting exposure levels is fundamental understanding of flow and dispersion in urban canyons. The complex topology of building structures and roads requires the resolution of turbulence phenomena within urban canyons. The use of dense and low porosity construction material can lead to rapid heating in response to direct solar exposure due to large thermal mass. Hence thermal and buoyancy effects may be as important as mechanically-forced or shear-induced flows. In this study, the transport of pollutants within the urban environment, as well as the thermal and advection effects, are investigated. The focus is on the horizontal transport or the advection effects within the urban environment. With increased urbanization and larger and more spread cities, concern about how the upstream air quality situation can affect downstream areas. The study also examines the release and the dispersion of hazardous material. Due to the variety and complexity of urban areas around the world, the urban environment is simplified into adjacent two-dimensional urban street canyons. Pollutants are released inside each canyon. Computational Fluid Dynamics (CFD) simulations are applied to evaluate and quantify the flow rate out of each canyon and also the exchange of pollutants between the canyons. Imagine a row of ten adjacent urban street canyons of aspect ratio 1 with horizontal flow perpendicular to it as shown in the attached figure. C is the concentration of pollutants. The first digit indicates in what canyon the pollutant is released and the second digit indicates the location of that pollutant. For example, C3,4 is the concentration of pollutant released inside canyon 3 measured in canyon 4. The same amount of pollution is released inside the ten street canyons
LM2-Mercury, a mercury mass balance model, was developed to simulate and evaluate the transport, fate, and biogeochemical transformations of mercury in Lake Michigan. The model simulates total suspended solids (TSS), disolved organic carbon (DOC), and total, elemental, divalent, ...
NASA Astrophysics Data System (ADS)
Kyutoku, K.; Kiuchi, K.; Sekiguchi, Y.; Shibata, M.; Taniguchi, K.
2016-10-01
We present our recent results of numerical-relativity simulations of black hole-neutron star binary mergers incorporating approximate neutrino transport. We in particular discuss dynamical mass ejection and neutrino-driven wind.
Mass transport and crystal growth of the mixed ZrS2-ZrSe2 system
NASA Technical Reports Server (NTRS)
Wiedemeier, Heribert; Goldman, Howard
1986-01-01
The solid solubility of the ZrS2-ZrSe2 system was reinvestigated by annealing techniques to establish the relationship between composition and lattice parameters. Mixed crystals of ZrS(2x)Se2(1-x) for selected compositions of the source material were grown by chemical vapor transport and characterized by X-ray diffraction and microscopic methods. The mass transport rates and crystal growth of ZrSSe were investigated and compared with those of other compositions. The mass fluxes of the mixed system showed an increase with increasing selenium content. The transport products were richer in ZrSe2 than the residual source materials when the ZrSe2 content of the starting materials was greater than 50 mol.-pct. The mass transport rates revealed an increasing mass flux with pressure.
Steiman-Cameron, Thomas Y.; Durisen, Richard H.; Michael, Scott; McConnell, Caitlin R.; Boley, Aaron C. E-mail: durisen@astro.indiana.edu E-mail: carmccon@indiana.edu
2013-05-10
We conduct a convergence study of a protoplanetary disk subject to gravitational instabilities (GIs) at a time of approximate balance between heating produced by the GIs and radiative cooling governed by realistic dust opacities. We examine cooling times, characterize GI-driven spiral waves and their resultant gravitational torques, and evaluate how accurately mass transport can be represented by an {alpha}-disk formulation. Four simulations, identical except for azimuthal resolution, are conducted with a grid-based three-dimensional hydrodynamics code. There are two regions in which behaviors differ as resolution increases. The inner region, which contains 75% of the disk mass and is optically thick, has long cooling times and is well converged in terms of various measures of structure and mass transport for the three highest resolutions. The longest cooling times coincide with radii where the Toomre Q has its minimum value. Torques are dominated in this region by two- and three-armed spirals. The effective {alpha} arising from gravitational stresses is typically a few Multiplication-Sign 10{sup -3} and is only roughly consistent with local balance of heating and cooling when time-averaged over many dynamic times and a wide range of radii. On the other hand, the outer disk region, which is mostly optically thin, has relatively short cooling times and does not show convergence as resolution increases. Treatment of unstable disks with optical depths near unity with realistic radiative transport is a difficult numerical problem requiring further study. We discuss possible implications of our results for numerical convergence of fragmentation criteria in disk simulations.
Mass transport-dominated sedimentation in a foreland basin, the Hidaka Trough, northern Japan
NASA Astrophysics Data System (ADS)
Noda, Atsushi; TuZino, Taqumi; Joshima, Masato; Goto, Shusaku
2013-08-01
Mass transport is an important process of sediment redistribution from shallow to deep sea basins. It is vital to understand this process for disaster prevention and protection of economic interests in coastal and offshore areas. We describe mass transport-dominated sedimentation in an active foreland basin, the Hidaka Trough, which developed from collision between the northeastern Japan arc and the Kuril arc. The basin is deformed by east-west compression associated with large, frequent earthquakes. The trough is filled with thick (>4.5 km) sediments, ranging from coal-bearing Cretaceous terrestrial strata to modern diatomaceous hemipelagic mud and volcanic ash. Bottom-simulating reflectors and the distribution of mud volcanoes, pockmarks, and acoustic wipe-out zones on the seismic records suggest the presence of subsurface gases in the sediments. The basin features stacked mass transport deposits (MTDs), but no channel-levee systems have developed. The MTDs are relatively thin (<30 m) and are derived from three sides of the basin margin. Initiation of submarine slope failure in this area may be controlled by multiple factors that increase driving forces and decrease resistance of the slopes. The driving forces include oversteepening of the margin slope as a resul`t of thrusting and folding, and additional downslope gravitational acceleration caused by cyclic shaking during earthquakes. Decreased resistance in the slopes may be caused by the accumulation of excess pore-water pressure driven by a high-sedimentation rate, gas hydrate dissociation accompanying changes in sea level or seawater temperature, and liquefaction in coarse-grained beds during earthquakes.
Xiang, Chengxiang; Meng, Andrew C.; Lewis, Nathan S.
2012-01-01
Physical integration of a Ag electrical contact internally into a metal/substrate/microstructured Si wire array/oxide/Ag/electrolyte photoelectrochemical solar cell has produced structures that display relatively low ohmic resistance losses, as well as highly efficient mass transport of redox species in the absence of forced convection. Even with front-side illumination, such wire-array based photoelectrochemical solar cells do not require a transparent conducting oxide top contact. In contact with a test electrolyte that contained 50 mM/5.0 mM of the cobaltocenium+/0 redox species in CH3CN–1.0 M LiClO4, when the counterelectrode was placed in the solution and separated from the photoelectrode, mass transport restrictions of redox species in the internal volume of the Si wire array photoelectrode produced low fill factors and limited the obtainable current densities to 17.6 mA cm-2 even under high illumination. In contrast, when the physically integrated internal Ag film served as the counter electrode, the redox couple species were regenerated inside the internal volume of the photoelectrode, especially in regions where depletion of the redox species due to mass transport limitations would have otherwise occurred. This behavior allowed the integrated assembly to operate as a two-terminal, stand-alone, photoelectrochemical solar cell. The current density vs. voltage behavior of the integrated photoelectrochemical solar cell produced short-circuit current densities in excess of 80 mA cm-2 at high light intensities, and resulted in relatively low losses due to concentration overpotentials at 1 Sun illumination. The integrated wire array-based device architecture also provides design guidance for tandem photoelectrochemical cells for solar-driven water splitting. PMID:22904185
NASA Astrophysics Data System (ADS)
Llopis-Albert, Carlos; Capilla, José E.
2009-06-01
SummaryA large-scale natural-gradient tracer experiment conducted in a highly heterogeneous aquifer at the Macrodispersion Experiment (MADE-2) site on Columbus Air Force Base in Mississippi (USA) is simulated using the gradual conditioning (GC) method. This methodology allows the stochastic inversion of hydraulic conductivity data ( K), and transient piezometric ( h) and solute concentration ( c) measurements in a non-Gaussian framework, including soft and secondary data. Results show (i) that the GC method allows the reproduction of the heavy tailing of the tracer plume as observed in the field by using a dual-domain mass transfer approach together with conditioning to K, h and c data, in a non-Gaussian framework, (ii) a good agreement between data and simulated mass distribution at time 328 days, including the non-Gaussian plume behaviour, (iii) the necessity of using a dual-domain mass transfer approach - or other transport equation different to the advection-dispersion equation (ADE) - when treating with upscaled models regardless of what random function is used to generate the K distribution, (iv) the reduction of uncertainty results when conditioning to all available information and not only to K data, and (v) the importance of preferential flow paths on the anomalous tracer plume spreading at the MADE site. Besides, the viability of the GC method in a highly heterogeneous 3D aquifer is proven, and also its contribution to the state-of-the-art in stochastic inverse modelling.
NASA Astrophysics Data System (ADS)
Gupta, Ashish; Chauhan, Anuj; Kopelevich, Dmitry I.
2008-06-01
Mass transport across surfactant-covered oil-water interfaces of microemulsions plays an important role in numerous applications. In the current work, we use coarse-grained molecular dynamics simulations to investigate model systems containing flat hexadecane-water interfaces covered by monolayers of nonionic surfactants of various lengths. Several properties of the surfactant monolayers relevant to the mass transport are considered, including the monolayer microstructure, dynamics, and a free energy barrier to the solute transport. It is observed that the dominant contribution of a surfactant monolayer to the free energy barrier is a steric repulsion caused by a local density increase inside the monolayer. The local densities, and hence the free energy barriers, are larger for monolayers composed of longer surfactants. Since it is likely that the solute transport mechanism involves a sequence of jumps between short-lived pores within a monolayer, we perform a detailed analysis of structure, size, and lifetime of these pores. We demonstrate that the pore statistics is consistent with predictions of percolation theory and apply this theory to identify the characteristic length scale of the monolayer microstructure. The obtained pore structures are sensitive to minute changes of surfactant configurations occurring on the picosecond time scale. To reduce this sensitivity, the pores are averaged over short time intervals. The optimal duration of these time intervals is estimated from analysis of dynamics of pores with diameters comparable to or exceeding the characteristic percolation length scale. The developed approach allows one to filter out transient events of the pore dynamics and to focus on events leading to substantial changes of the monolayer microstructure.
Angular momentum transport efficiency in post-main sequence low-mass stars
NASA Astrophysics Data System (ADS)
Spada, F.; Gellert, M.; Arlt, R.; Deheuvels, S.
2016-05-01
Context. Using asteroseismic techniques, it has recently become possible to probe the internal rotation profile of low-mass (≈1.1-1.5 M⊙) subgiant and red giant stars. Under the assumption of local angular momentum conservation, the core contraction and envelope expansion occurring at the end of the main sequence would result in a much larger internal differential rotation than observed. This suggests that angular momentum redistribution must be taking place in the interior of these stars. Aims: We investigate the physical nature of the angular momentum redistribution mechanisms operating in stellar interiors by constraining the efficiency of post-main sequence rotational coupling. Methods: We model the rotational evolution of a 1.25M⊙ star using the Yale Rotational stellar Evolution Code. Our models take into account the magnetic wind braking occurring at the surface of the star and the angular momentum transport in the interior, with an efficiency dependent on the degree of internal differential rotation. Results: We find that models including a dependence of the angular momentum transport efficiency on the radial rotational shear reproduce very well the observations. The best fit of the data is obtained with an angular momentum transport coefficient scaling with the ratio of the rotation rate of the radiative interior over that of the convective envelope of the star as a power law of exponent ≈3. This scaling is consistent with the predictions of recent numerical simulations of the Azimuthal Magneto-Rotational Instability. Conclusions: We show that an angular momentum transport process whose efficiency varies during the stellar evolution through a dependence on the level of internal differential rotation is required to explain the observed post-main sequence rotational evolution of low-mass stars.
Clarke Stations and mercurian mass-drivers: energy for large-scale transportation systems
Jones, E.M.
1985-01-01
Three-week voyages across 1 AU could be made in large sailing craft propelled by microwaves generated at power stations operating at 0.1 AU from the sun. The power stations could be built of mercurian materials launched by mass driver to building sites in solar orbit. A Clarke Station 28 km in radius could generate 64 TW of microwaves and support the operation of a 1000-tonne, 1000-passenger vessel. The ability to build near-sun power stations of mercurian materials would not only support high-speed transport but solar system development in general.
Yao, Yijun; Wu, Yun; Wang, Yue; Verginelli, Iason; Zeng, Tian; Suuberg, Eric M; Jiang, Lin; Wen, Yuezhong; Ma, Jie
2015-10-01
At petroleum vapor intrusion (PVI) sites at which there is significant methane generation, upward advective soil gas transport may be observed. To evaluate the health and explosion risks that may exist under such scenarios, a one-dimensional analytical model describing these processes is introduced in this study. This new model accounts for both advective and diffusive transport in soil gas and couples this with a piecewise first-order aerobic biodegradation model, limited by oxygen availability. The predicted results from the new model are shown to be in good agreement with the simulation results obtained from a three-dimensional numerical model. These results suggest that this analytical model is suitable for describing cases involving open ground surface beyond the foundation edge, serving as the primary oxygen source. This new analytical model indicates that the major contribution of upward advection to indoor air concentration could be limited to the increase of soil gas entry rate, since the oxygen in soil might already be depleted owing to the associated high methane source vapor concentration.
NASA Technical Reports Server (NTRS)
Klich, P. J.; Macconochie, I. O.
1979-01-01
A study of an array of advanced earth-to-orbit space transportation systems with a focus on mass properties and technology requirements is presented. Methods of estimating weights of these vehicles differ from those used for commercial and military aircraft; the new techniques emphasizing winged horizontal and vertical takeoff advanced systems are described utilizing the space shuttle subsystem data base for the weight estimating equations. The weight equations require information on mission profile, the structural materials, the thermal protection system, and the ascent propulsion system, allowing for the type of construction and various propellant tank shapes. The overall system weights are calculated using this information and incorporated into the Systems Engineering Mass Properties Computer Program.
The photoinduced birefringence and mass transport in azo compound K-D-2
NASA Astrophysics Data System (ADS)
Klismeta, K.; Teteris, J.
2015-06-01
Azobenzene containing compounds are among light polarization sensitive materials - the moieties may align relative to the electric field vector of light, leading to anisotropy and birefringence in the sample. Another phenomenon which can be observed in azo compounds under influence of light is macroscopic movement of the material. In this work photoinduced processes in low molecular weight organic glass - bis-azobenzene containing compound K-D-2 were experimentally studied. Birefringence was induced with linearly polarized laser light (473, 532 and 635 nm) and measured at 633 nm wavelength. Polarization holography with recording beam configuration +45°/-45° was used to induce mass motion. Dependence of the surface relief depth on the recording laser wavelength in the visible spectrum (375 - 671 nm) was obtained. Formation of the SRG was observed with all used wavelengths and high birefringence values were obtained. Certain correlation between the absorption of the wavelength and photoinduced mass transport and birefringence is yet to be confirmed.
Chaotic advection, diffusion, and reactions in open flows
Tel, Tamas; Karolyi, Gyoergy; Pentek, Aron; Scheuring, Istvan; Toroczkai, Zoltan; Grebogi, Celso; Kadtke, James
2000-03-01
We review and generalize recent results on advection of particles in open time-periodic hydrodynamical flows. First, the problem of passive advection is considered, and its fractal and chaotic nature is pointed out. Next, we study the effect of weak molecular diffusion or randomness of the flow. Finally, we investigate the influence of passive advection on chemical or biological activity superimposed on open flows. The nondiffusive approach is shown to carry some features of a weak diffusion, due to the finiteness of the reaction range or reaction velocity. (c) 2000 American Institute of Physics.
Predicting salt advection in groundwater from saline aquaculture ponds
NASA Astrophysics Data System (ADS)
Verrall, D. P.; Read, W. W.; Narayan, K. A.
2009-01-01
SummaryThis paper predicts saltwater advection in groundwater from leaky aquaculture ponds. A closed form solution for the potential function, stream function and velocity field is derived via the series solutions method. Numerically integrating along different streamlines gives the location (or advection front) of saltwater throughout the domain for any predefined upper time limit. Extending this process produces a function which predicts advection front location against time. The models considered in this paper are easily modified given knowledge of the required physical parameters.
A finite-volume ELLAM for three-dimensional solute-transport modeling
Russell, T.F.; Heberton, C.I.; Konikow, L.F.; Hornberger, G.Z.
2003-01-01
A three-dimensional finite-volume ELLAM method has been developed, tested, and successfully implemented as part of the U.S. Geological Survey (USGS) MODFLOW-2000 ground water modeling package. It is included as a solver option for the Ground Water Transport process. The FVELLAM uses space-time finite volumes oriented along the streamlines of the flow field to solve an integral form of the solute-transport equation, thus combining local and global mass conservation with the advantages of Eulerian-Lagrangian characteristic methods. The USGS FVELLAM code simulates solute transport in flowing ground water for a single dissolved solute constituent and represents the processes of advective transport, hydrodynamic dispersion, mixing from fluid sources, retardation, and decay. Implicit time discretization of the dispersive and source/sink terms is combined with a Lagrangian treatment of advection, in which forward tracking moves mass to the new time level, distributing mass among destination cells using approximate indicator functions. This allows the use of large transport time increments (large Courant numbers) with accurate results, even for advection-dominated systems (large Peclet numbers). Four test cases, including comparisons with analytical solutions and benchmarking against other numerical codes, are presented that indicate that the FVELLAM can usually yield excellent results, even if relatively few transport time steps are used, although the quality of the results is problem-dependent.
Ballistic thermal transport in monolayer transition-metal dichalcogenides: Role of atomic mass
NASA Astrophysics Data System (ADS)
Ma, Jinlong; Li, Wu; Luo, Xiaobing
2016-02-01
We investigate the ballistic thermal transport of monolayer transition-metal dichalcogenides (TMDs), which is crucial for the thermal management of their potential applications in nanoelectronics. We find the thermal conductance is mainly affected by the atomic masses of TMDs. As a consequence, the temperature dependences of thermal conductances of different TMDs cross: At low temperatures below ˜50 K, the thermal conductance increases with the atomic mass, while it exhibits the opposite trend at high temperatures. The crossing behavior of temperature dependent thermal conductance is characteristic of the atomic mass effect, and TMDs provide a model system demonstrating that the thermal conductance can be effectively manipulated via the atomic mass by selecting appropriate atom. In addition, we clarify that in any two dimensional system such as monolayer TMDs and graphene, due to quadratic dispersion of the out-of-plane modes, the thermal conductance and specific heat in the low temperature limit are proportional to T3/2 and T, respectively. Mainly because of much smaller group velocities of in-plane acoustic phonons, the high temperature thermal conductances of monolayer TMDs are much smaller than graphene. However, due to comparable group velocities of out-of-plane acoustic phonons, below 100 K thermal conductances of monolayer TMDs are rather comparable to graphene if taking the same layer thickness for comparison.
Geocenter motion due to surface mass transport from GRACE satellite data
NASA Astrophysics Data System (ADS)
Riva, R. E. M.; van der Wal, W.; Lavallée, D. A.; Hashemi Farahani, H.; Ditmar, P.
2012-04-01
Measurements of mass redistribution from satellite gravimetry are insensitive to geocenter motions. However, geocenter motions can be constrained by satellite gravity data alone if we partition mass changes between land and oceans, under the assumption that the ocean is passive (i.e., in gravitational equilibrium with the land load and the solid earth). Here, we make use of 8 years (2003-2010) of optimally filtered monthly GRACE-based solutions produced at TU Delft to determine changes in the land load and the corresponding geocenter motion, through an iterative procedure. We pay particular attention to correcting for signal leakage caused by the limited spatial resolution of GRACE. We also investigate how the choice of a model of glacial isostatic adjustment (GIA) affects the estimated geocenter motion trend due to present-day surface mass transport. Finally, we separate the contribution of ice masses from that of land hydrology and show how they have a different sensitivity to the chosen GIA model and observational time-span.
Ghatak, J; Umananda Bhatta, M; Sundaravel, B; Nair, K G M; Liou, Sz-Chian; Chen, Cheng-Hsuan; Wang, Yuh-Lin; Satyam, P V
2008-08-13
We report a direct observation of dramatic mass transport due to 1.5 MeV Au(2+) ion impact on isolated Au nanostructures of average size ≈7.6 nm and height ≈6.9 nm that are deposited on Si(111) substrate under high flux (3.2 × 10(10)-6.3 × 10(12) ions cm(-2) s(-1)) conditions. The mass transport from nanostructures was found to extend up to a distance of about 60 nm into the substrate, much beyond their size. This forward mass transport is compared with the recoil implantation profiles using SRIM simulation. The observed anomalies with theory and simulations are discussed. At a given energy, the incident flux plays a major role in mass transport and its redistribution. The mass transport is explained on the basis of thermal effects and the creation of rapid diffusion paths in the nanoscale regime during the course of ion irradiation. The unusual mass transport is found to be associated with the formation of gold silicide nano-alloys at subsurfaces. The complexity of the ion-nanostructure interaction process is discussed with a direct observation of melting (in the form of spherical fragments on the surface) phenomena. Transmission electron microscopy, scanning transmission electron microscopy, and Rutherford backscattering spectroscopy methods have been used.
Advection and the Efficiency of Spectral Energy Transfer in Two-Dimensional Turbulence.
Fang, Lei; Ouellette, Nicholas T
2016-09-01
We report measurements of the geometric alignment of the small-scale turbulent stress and the large-scale rate of strain that together lead to the net flux of energy from small scales to large scales in two-dimensional turbulence. We find that the instantaneous alignment between these two tensors is weak and, thus, that the spectral transport of energy is inefficient. We show, however, that the strain rate is much better aligned with the stress at times in the past, suggesting that the differential advection of the two is responsible for the inefficient spectral transfer. We provide evidence for this conjecture by measuring the alignment statistics conditioned on weakly changing stress history. Our results give new insight into the relationship between scale-to-scale energy transfer, geometric alignment, and advection in turbulent flows.
Advection and the Efficiency of Spectral Energy Transfer in Two-Dimensional Turbulence
NASA Astrophysics Data System (ADS)
Fang, Lei; Ouellette, Nicholas T.
2016-09-01
We report measurements of the geometric alignment of the small-scale turbulent stress and the large-scale rate of strain that together lead to the net flux of energy from small scales to large scales in two-dimensional turbulence. We find that the instantaneous alignment between these two tensors is weak and, thus, that the spectral transport of energy is inefficient. We show, however, that the strain rate is much better aligned with the stress at times in the past, suggesting that the differential advection of the two is responsible for the inefficient spectral transfer. We provide evidence for this conjecture by measuring the alignment statistics conditioned on weakly changing stress history. Our results give new insight into the relationship between scale-to-scale energy transfer, geometric alignment, and advection in turbulent flows.
Advection and the Efficiency of Spectral Energy Transfer in Two-Dimensional Turbulence.
Fang, Lei; Ouellette, Nicholas T
2016-09-01
We report measurements of the geometric alignment of the small-scale turbulent stress and the large-scale rate of strain that together lead to the net flux of energy from small scales to large scales in two-dimensional turbulence. We find that the instantaneous alignment between these two tensors is weak and, thus, that the spectral transport of energy is inefficient. We show, however, that the strain rate is much better aligned with the stress at times in the past, suggesting that the differential advection of the two is responsible for the inefficient spectral transfer. We provide evidence for this conjecture by measuring the alignment statistics conditioned on weakly changing stress history. Our results give new insight into the relationship between scale-to-scale energy transfer, geometric alignment, and advection in turbulent flows. PMID:27636478
Choi, Jee-Won; Tillman, Fred D; Smith, James A
2002-07-15
It was hypothesized that atmospheric pressure changes can induce gas flow in the unsaturated zone to such an extent that the advective flux of organic vapors in unsaturated-zone soil gas can be significant relative to the gas-phase diffusion flux of these organic vapors. To test this hypothesis, a series of field measurements and computer simulations were conducted to simulate and compare diffusion and advection fluxes at a trichloroethene-contaminated field site at Picatinny Arsenal in north-central New Jersey. Moisture content temperature, and soil-gas pressure were measured at multiple depths (including at land surface) and times for three distinct sampling events in August 1996, October 1996, and August 1998. Gas pressures in the unsaturated zone changed significantly over time and followed changes measured in the atmosphere. Gas permeability of the unsaturated zone was estimated using data from a variety of sources, including laboratory gas permeability measurements made on intact soil cores from the site, a field air pump test, and calibration of a gas-flow model to the transient, one-dimensional gas pressure data. The final gas-flow model reproduced small pressure gradients as observed in the field during the three distinct sampling events. The velocities calculated from the gas-flow model were used in transient, one-dimensional transport simulations to quantify advective and diffusive fluxes of TCE vapor from the subsurface to the atmosphere as a function of time for each sampling event. Effective diffusion coefficients used for these simulations were determined from independent laboratory measurements made on intact soil cores collected from the field site. For two of the three sampling events (August 1996 and August 1998), the TCE gas-phase diffusion flux at land surface was significantly greater than the advection flux over the entire sampling period. For the second sampling event (October 1996), the advection flux was frequently larger than the
Azagury, Aharon; Khoury, Luai; Adato, Yair; Wolloch, Lior; Ariel, Ilana; Hallak, Mordechai; Kost, Joseph
2015-02-28
In our previous study we proposed the use of chemical penetration enhancers for noninvasive detection of fetus abnormalities that can also be utilized for direct fetal drug delivery. In an attempt to further increase the mass transport rate across the amniotic membrane, thus shortening the procedure and improving the applicability of the proposed procedure, the effect and mechanism of combining ultrasound exposure with chemical penetration enhancers' application were assessed. The combined effect was evaluated in vitro on post-delivery human amniotic membrane and ex vivo on rat's whole amniotic sac. Ultrasound effect has been assessed by dye experiments using a customized image analysis program. Additional insights of ultrasound effect's mechanism on biological membranes are presented. Previously we have determined that chemical penetration enhancers affect the fetal membranes via two mechanisms termed as 'extractors' and 'fluidizers'. In this study, we found that combining ultrasound with a 'fluidizer' CPE (e.g. bupivacaine) results in a synergistic enhancement (90-fold) of fetal membrane's mass transport, while combining ultrasound with 'extractors' (e.g. ethanol and NMP) results in an antagonistic effect. The combined procedure is faster and gain greater accuracy than the applications of sole chemical penetration enhancers.
Ligand-receptor interaction rates in the presence of convective mass transport.
Model, M A; Omann, G M
1995-01-01
The rate of binding of a ligand to receptors on the cell surface can be diffusion limited. We analyze the kinetics of binding, diffusion-limited in a stationary liquid, in the presence of convective mass transport. We derive a formula that expresses the reaction kinetics in terms of the mass transfer coefficient. A moderately transport-limited kinetics is not readily recognizable from the shape of the binding curve and may lead to erroneous estimates of the rate coefficients. We apply our results to practically important cases: a cell suspension in a stirred volume of liquid and a confluent cell colony under a laminar stream. Using typical numbers characterizing the ligand-receptor interactions, we show that stirring and perfusion can be important factors determining the reaction rates. With the confluent colony, the early reaction kinetics requires a different treatment, and we provide it for the case of low receptor occupancy. We show that, even with a fast perfusion, a cell monolayer can transiently generate a zone of depletion of the ligand, and that would affect the early stages of the reaction. Our results are expressed in a simple analytical form and can be used for the design and interpretation of experimental data. PMID:8580315
Conditions and processes affecting radionuclide transport
Simmons, Ardyth M.; Neymark, Leonid A.
2012-01-01
Understanding of unsaturated-zone transport is based on laboratory and field-scale experiments. Fractures provide advective transport pathways. Sorption and matrix diffusion may contribute to retardation of radionuclides. Conversely, sorption onto mobile colloids may enhance radionuclide transport.
Anomalous scaling of a scalar field advected by turbulence
Kraichnan, R.H.
1995-12-31
Recent work leading to deduction of anomalous scaling exponents for the inertial range of an advected passive field from the equations of motion is reviewed. Implications for other turbulence problems are discussed.
Technologies Involved in Configuring an Advanced Earth-to-Orbit Transport for Low Structural Mass
NASA Technical Reports Server (NTRS)
MacConochie, Ian O.; Klich, Phillip J.
1980-01-01
The current space shuttle is expected to adequately meet Government and industry needs for the transport of cargo to and from orbit well into the 1990's. However, continual study of potential follow-on shuttle systems is necessary and desirable in order to complement ongoing research in materials, structures, propulsion, aerodynamics, and other related areas. By studying alternate systems well in advance, it will be possible to explore the various technologies and develop those for which there is the greatest apparent payoff. In this paper a single-stage Earth-to-orbit transport designed for delivery of approximately 29,500 kg (65,000 lb) payload will be described. The vehicle, which takes off vertically and lands horizontally, is 60 m (197 feet) long and weighs approximately 1.8 Gg (4 M lb) at liftoff. In the interest of weight reduction, a simple body of revolution is utilized for the main body shell. In this design the main propulsion tanks serve as a primary load-carrying structure. Further, in order to minimize structural mass, the cargo bay is located between two of the main propellant tanks. The cargo volume, at 396 cu m (14,000 cu feet), exceeds that provided by the shuttle; but the bay itself is nonconforming in shape - being approximately 10 m (32 feet) in diameter by 5 m (17 feet) long. Dual-fuel propulsion is employed, since a number of studies have shown that (though lowering performance) the operation of hydrocarbon (RP) engines in parallel with LOX/LH2 engines results in a net reduction in the vehicle's physical size and structural mass. Other weight-saving features entail the extensive use of honeycomb sandwiches, advanced materials, and advanced fabrication techniques. The vehicle presented is utilized only as a means to study and identify various technologies needed in order to develop a low mass Earth-to-orbit transportation system for the future. The conclusion of this study is that vehicle geometry and structural/materials technology are
NASA Astrophysics Data System (ADS)
Yochelis, Arik; Bar-On, Tomer; Gov, Nir S.
2016-04-01
Unconventional myosins belong to a class of molecular motors that walk processively inside cellular protrusions towards the tips, on top of actin filament. Surprisingly, in addition, they also form retrograde moving self-organized aggregates. The qualitative properties of these aggregates are recapitulated by a mass conserving reaction-diffusion-advection model and admit two distinct families of modes: traveling waves and pulse trains. Unlike the traveling waves that are generated by a linear instability, pulses are nonlinear structures that propagate on top of linearly stable uniform backgrounds. Asymptotic analysis of isolated pulses via a simplified reaction-diffusion-advection variant on large periodic domains, allows to draw qualitative trends for pulse properties, such as the amplitude, width, and propagation speed. The results agree well with numerical integrations and are related to available empirical observations.
Imaging ion and molecular transport at subcellular resolution by secondary ion mass spectrometry
NASA Astrophysics Data System (ADS)
Chandra, Subhash; Morrison, George H.
1995-05-01
The transport of K+, Na+, and Ca2+ were imaged in individual cells with a Cameca IMS-3f ion microscope. Strict cryogenic frozen freeze-dry sample preparations were employed. Ion redistribution artifacts in conventional chemical preparations are discussed. Cryogenically prepared freeze-fractured freeze-dried cultured cells allowed the three-dimensional ion microscopic imaging of elements. As smaller structures in calcium images can be resolved with the 0.5 [mu]m spatial resolution, correlative techniques are needed to confirm their identity. The potentials of reflected light microscopy, scanning electron microscopy and laser scanning confocal microscopy are discussed for microfeature recognition in freeze-fractured freeze-dried cells. The feasibility of using frozen freeze-dried cells for imaging molecular transport at subcellular resolution was tested. Ion microscopy successfully imaged the transport of the isotopically tagged (13C, 15N) amino acid, -arginine. The labeled amino acid was imaged at mass 28 with a Cs+ primary ion beam as the 28(13C15N)- species. After a 4 h exposure of LLC-PK1 kidney cells to 4 mM labeled arginine, the amino acid was localized throughout the cell with a preferential incorporation into the nucleus and nucleolus. An example is also shown of the ion microscopic imaging of sodium borocaptate, an experimental therapeutic drug for brain tumors, in cryogenically prepared frozen freeze-dried Swiss 3T3 cells.
Solvent-Induced Crystallization in Poly(Ethylene Terephthalate) during Mass Transport
NASA Astrophysics Data System (ADS)
Ouyang, Hao
2001-03-01
The solvent transport in poly(ethylene terephthalate) (PET) and related phase transformation were investigated. The data of mass sorption were analyzed according to Harmon¡¦s model for Case I (Fickian), Case II (swelling) and anomalous transport. This transport process in PET is accompanied by the induced crystallization of the original amorphous state. The transformation was studied by wide angle x-ray scattering (WAXS), small angle x-ray scattering (SAXS), Differential Scanning Calorimeter (DSC), density gradient column, and Fourier Transform Infra-Red (FTIR). During this process, the matrix is under a compressive strain that causes different kinetic path of crystallization as compared to that by thermal annealing. This state of strain will assist the development of the solvent-induced crystallization. It also can be explained in terms of the principle of Le Chatelier if the local equilibrium is assumed. The model regarding the crystallization was proposed in terms of the study of long period L, the crystal thickness lc and the thickness of amorphous layer la, obtained from the linear correlation function and interface distribution function.
A heuristic simulation model of Lake Ontario circulation and mass balance transport
McKenna, J.E.; Chalupnicki, M.A.
2011-01-01
The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.
NASA Astrophysics Data System (ADS)
Whipp, David M.; Beaumont, Christopher; Braun, Jean
2014-06-01
The Nanga Parbat-Haramosh massif (NPHM; western Himalayan syntaxis) requires an influx of mass exceeding that in the adjacent Himalayan arc to sustain high topography and rapid erosional exhumation rates. What supplies this mass flux and feeds this "tectonic aneurysm?" We show, using a simple 3-D model of oblique orogen convergence, that velocity/strain partitioning results in horizontal orogen-parallel (OP) crustal transport, and the same behavior is inferred for the Himalaya, with OP transport diverting converging crust toward the syntaxis. Model results also show that the OP flow rate decreases in the syntaxis, thereby thickening the crust and forming a structure like the NPHM. The additional crustal thickening, over and above that elsewhere in the Himalayan arc, sustains the rapid exhumation of this "aneurysm." Normally, velocity/strain partitioning would be minimal for the Himalayan arc where the convergence obliquity is no greater than ~40°. However, we show analytically that the Himalayan system can act both as a critical wedge and exhibit strain partitioning if both the detachment beneath the wedge and the bounding rear shear zone, which accommodates OP transport, are very weak. Corresponding numerical results confirm this requirement and demonstrate that a Nanga Parbat-type shortening structure can develop spontaneously if the orogenic wedge and bounding rear shear zone can strain rate soften while active. These results lead us to question whether the position of NPHM aneurysm is localized by river incision, as previously suggested, or by a priori focused tectonic shortening of the crust in the syntaxis region as demonstrated by our models.
Model development and verification for mass transport to Escherichia coli cells in a turbulent flow
NASA Astrophysics Data System (ADS)
Hondzo, Miki; Al-Homoud, Amer
2007-08-01
Theoretical studies imply that fluid motion does not significantly increase the molecular diffusive mass flux toward and away from microscopic organisms. This study presents experimental and theoretical evidence that small-scale turbulence modulates enhanced mass transport to Escherichia coli cells in a turbulent flow. Using the technique of inner region and outer region expansions, a model for dissolved oxygen and glucose uptake by E. coli was developed. The mass transport to the E. coli was modeled by the Sherwood (Sh)-Péclet (Pe) number relationship with redefined characteristic length and velocity scales. The model Sh = (1 + Pe1/2 + Pe) agreed with the laboratory measurements well. The Péclet number that quantifies the role and function of small-scale turbulence on E. coli metabolism is defined by Pe = (?) where Ezz is the root mean square of fluid extension in the direction of local vorticity, ηK is the Kolmogorov length scale, Lc is the length scale of E. coli, and D is the molecular diffusion coefficient. An alternative formulation for the redefined Pe is given by Pe = (?) where ? = 0.5(ɛν)1/4 is the Kolmogorov velocity averaged over the Kolmogorov length scale, ɛ is dissipation of turbulent kinetic energy, and ν is the kinematic viscosity of fluid. The dissipation of turbulent kinetic energy was estimated directly from measured velocity gradients and was within the reported range in engineered and natural aquatic ecosytems. The specific growth of E. coli was up to 5 times larger in a turbulent flow in comparison to the still water controls. Dissolved oxygen and glucose uptake were enhanced with increased ɛ in the turbulent flow.
A spatial SIS model in advective heterogeneous environments
NASA Astrophysics Data System (ADS)
Cui, Renhao; Lou, Yuan
2016-09-01
We study the effects of diffusion and advection for a susceptible-infected-susceptible epidemic reaction-diffusion model in heterogeneous environments. The definition of the basic reproduction number R0 is given. If R0 < 1, the unique disease-free equilibrium (DFE) is globally asymptotically stable. Asymptotic behaviors of R0 for advection rate and mobility of the infected individuals (denoted by dI) are established, and the existence of the endemic equilibrium when R0 > 1 is studied. The effects of diffusion and advection rates on the stability of the DFE are further investigated. Among other things, we find that if the habitat is a low-risk domain, there may exist one critical value for the advection rate, under which the DFE changes its stability at least twice as dI varies from zero to infinity, while the DFE is unstable for any dI when the advection rate is larger than the critical value. These results are in strong contrast with the case of no advection, where the DFE changes its stability at most once as dI varies from zero to infinity.
Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan
2004-06-01
The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had
Arabian Night and Sea Story - Biomarkers from a Giant Mass Transport Deposit.
NASA Astrophysics Data System (ADS)
Bratenkov, Sophia; Kulhanek, Denise K.; Clift, Peter D.; George, Simon C.
2016-04-01
The study of mass transport deposits (MTDs) is an important field of research due to the potential insights into catastrophic events in the past and modern geohazard threats (e.g. tsunamis). Submarine mass movements are very significant processes in sculpturing the structure of continental margins, particularly in their extent and magnitude that have consequences both in the modern day, as well as in the geological past. An understanding of the complex stratigraphy of a submarine mass transport deposit (MTD) might help in reconstructing the provenance and transport pathways of sedimentary material and thus give important insights into sedimentary dynamics and processes triggering specific events. Drilling operations during International Ocean Discovery Program (IODP) Expedition 355 Arabian Sea Monsoon, which took place during April and May, 2015 cored two sites in Laxmi Basin. Site U1456 was cored to 1109.4 m below seafloor (mbsf), with the oldest recovered rock dated to ~13.5-17.7 Ma. Site U1457 was cored to 1108.6 mbsf, with the oldest rock dated to ~62 Ma. At each site, we cored through ~330 m and ~190 m of MTD material. The MTD layers mainly consist of interbedded lithologies of dark grey claystone, light greenish calcarenite and calcilutite, and conglomerate/breccia, with ages based on calcareous nannofossil and foraminifer biostratigraphy ranging from the Eocene to early Miocene (Pandey et al., 2015). This MTD, known as Nataraja Slide, is the third largest MTD known from the geological record and the second largest on a passive margin. Calvés et al. (2015) identified a potential source area offshore Sourashstra on the Indian continental margin and invoked the single step mass movement model to explain the mechanism of emplacement. Initial shipboard work demonstrated the high variability in total organic carbon and total nitrogen levels in different layers within the MTD, which raises a number of questions related to the source and composition of the organic
NASA Astrophysics Data System (ADS)
Black, Jay R.; John, Seth G.; Kavner, Abby
2014-01-01
The isotopic composition of zinc metal electrodeposited on a rotating disc electrode from a Zn-citrate aqueous solution was investigated as a function of overpotential (electrochemical driving force), temperature, and rotation rate. Zn metal was measured to be isotopically light with respect to Zn+2 in solution, with observed fractionations varying from Δ66/64Znmetal-aqueous = -1.0‰ to -3.9‰. Fractionation varies continuously as a function of a dimensionless parameter described by the ratio of observed deposition rate to calculated mass-transport limiting rate, where larger fractionations are observed at lower deposition rates, lower temperature, and at faster electrode rotation rates. Thus, the large fractionation and its rate dependence is interpreted as a competition between the two kinetic processes with different effective activation energies: mass-transport-limited (diffusion limited) kinetics with a large activation energy, which creates small fractionations close to the predicted diffusive fractionation; and electrochemical deposition kinetics, with a smaller effective activation energy, which creates large fractionations at low deposition rates and high hydrodynamic fluxes of solute to the electrode. The results provide a framework for predicting isotope fractionation in processes controlled by two competing reactions with different kinetic isotope effects. Light isotopes are electroplated. In all cases light stable isotopes of the metals are preferentially electroplated, with mass-dependent behavior evident where three or more isotopes are measured. Fractionation is time-independent, meaning that the fractionation factor does not vary with the extent of reaction. In most of our experiments, we have controlled the extent of reaction such that only a small amount of metal is deposited from the stock solution, thus avoiding significant evolution of the reservoir composition. In such experiments, the observed isotope fractionation is constant as a
Webb, S.W.
1996-05-01
Two models for gas-phase diffusion and advection in porous media, the Advective-Dispersive Model (ADM) and the Dusty-Gas Model (DGM), are reviewed. The ADM, which is more widely used, is based on a linear addition of advection calculated by Darcy`s Law and ordinary diffusion using Fick`s Law. Knudsen diffusion is often included through the use of a Klinkenberg factor for advection, while the effect of a porous medium on the diffusion process is through a porosity-tortuosity-gas saturation multiplier. Another, more comprehensive approach for gas-phase transport in porous media has been formulated by Evans and Mason, and is referred to as the Dusty- Gas Model (DGM). This model applies the kinetic theory of gases to the gaseous components and the porous media (or ``dust``) to develop an approach for combined transport due to ordinary and Knudsen diffusion and advection including porous medium effects. While these two models both consider advection and diffusion, the formulations are considerably different, especially for ordinary diffusion. The various components of flow (advection and diffusion) are compared for both models. Results from these two models are compared to isothermal experimental data for He-Ar gas diffusion in a low-permeability graphite. Air-water vapor comparisons have also been performed, although data are not available, for the low-permeability graphite system used for the helium-argon data. Radial and linear air-water heat pipes involving heat, advection, capillary transport, and diffusion under nonisothermal conditions have also been considered.
Driessen, B.J.; Dohner, J.L.
1998-08-01
In this paper a hybrid, finite element--boundary element method which can be used to solve for particle advection-diffusion in infinite domains with variable advective fields is presented. In previous work either boundary element, finite element, or difference methods have been used to solve for particle motion in advective-diffusive domains. These methods have a number of limitations. Due to the complexity of computing spatially dependent Green`s functions, the boundary element method is limited to domains containing only constant advective fields, and due to their inherent formulation, finite element and finite difference methods are limited to only domains of finite spatial extent. Thus, finite element and finite difference methods are limited to finite space problems for which the boundary element method is not, and the boundary element method is limited to constant advection field problems for which finite element and finite difference methods are not. In this paper it is proposed to split a domain into two sub-domains, and for each of these sub domains, apply the appropriate solution method; thereby, producing a method for the total infinite space, variable advective field domain.
A Method for Measuring Subcanopy CO2 Advection
NASA Astrophysics Data System (ADS)
Staebler, R. M.; Fitzjarrald, D. R.
2004-12-01
Underestimation of nocturnal CO2 respiration under calm conditions remains an unsolved problem at many forest flux stations, and several groups are currently investigating the direct measurement of horizontal advection of CO2. This presentation will describe a systematic, relatively low-cost methodology developed to determine whether horizontal mean transport of CO2 accounts for the missing CO2 at the Harvard Forest (Petersham, MA). This methodology includes the characterization of subcanopy motions, determining the appropriate size of the subcanopy network required to make the measurements, developing a method of integrating the measurements in the vertical, and determining the required averaging time. Measurements were conducted over 4 years and produced data for 310 nights covering all seasons. Subcanopy flows were decoupled from the flows aloft 75% of the time. Conditions conducive to the generation of negative buoyancy near the forest floor, necessary for drainage flows to develop, were given in 92% of all nights. The occurrence of nocturnal drainage flows correlated well with "missing flux" problems ("deficit nights"), prompting us to propose an improvement on the commonly used friction velocity criterion (which requires u* to be larger than some empirical cut-off for the eddy fluxes to be considered credible). The "negative buoyancy forcing fraction", i.e. negative buoyancy as a fraction of the sum of the dynamic driving forces, can be shown to predict deficit nights significantly better than the u* cut-off. The appropriate horizontal size of the network of wind and CO2 sensors at the Harvard Forest was shown to be on the order of 100 m, ensuring that sensors were generally observing coherent processes on this scale or larger and thus displaying some correlation. Horizontal transport of CO2 was found to be restricted to the bottom ~10 m of the forest, facilitating the development of a method of integrating the horizontal CO2 gradients in the vertical
DeSimone, L.A.; Howes, B.L.
1998-01-01
Nitrogen transport and transformations were followed over the initial 3 years of development of a plume of wastewater-contaminated groundwater in Cape Cod, Massachusetts. Ammonification and nitrification in the unsaturated zone and ammonium sorption in the saturated zone were predominant, while loss of fixed nitrogen through denitrification was minor. The major effect of transport was the oxidation of discharged organic and inorganic forms to nitrate, which was the dominant nitrogen form in transit to receiving systems. Ammonification and nitrification in the unsaturated zone transformed 16-19% and 50-70%, respectively, of the total nitrogen mass discharged to the land surface during the study but did not attenuate the nitrogen loading. Nitrification in the unsaturated zone also contributed to a pH decrease of 2 standard units and to an N2O increase (46-660 ??g N/L in the plume). Other processes in the unsaturated zone had little net effect: Ammonium sorption removed <1% of the total discharged nitrogen mass; filtering of particulate organic nitrogen was less than 3%; ammonium and nitrate assimilation was less than 6%; and ammonia volatilization was less than 0.25%. In the saturated zone a central zone of anoxic groundwater (DO ??? 0.05 mg/L) was first detected 17 months after effluent discharge to the aquifer began, which expanded at about the groundwater-flow velocity. Although nitrate was dominant at the water table, the low, carbon-limited rates of denitrification in the anoxic zone (3.0-9.6 (ng N/cm3)/d) reduced only about 2% of the recharged nitrogen mass to N2. In contrast, ammonium sorption in the saturated zone removed about 16% of the recharged nitrogen mass from the groundwater. Ammonium sorption was primarily limited to anoxic zone, where nitrification was prevented, and was best described by a Langmuir isotherm in which effluent ionic concentrations were simulated. The initial nitrogen load discharged from the groundwater system may depend largely on
Study of mass and heat transport of the tropical Atlantic Ocean using models and altimeter data
NASA Technical Reports Server (NTRS)
Merle, Jacques; Arnault, S.; Morliere, A.; Verstraete, J. M.; Menard, Yves; Gourdeau, L.
1991-01-01
The specific objectives of this proposal are: (1) to assess the quality of the TOPEX/POSEIDON surface altimeter data in regard to its use for a large, low-frequency monitoring of the surface topography of the tropical Atlantic Ocean; (2) to develop a method, on a demonstration basis, to derive from the tropical Atlantic the depth of the thermocline and the heat content changes from the surface altimeter data field; (3) to develop a method of assimilation of altimeter data into Oceanic General Circulation Models (OGCM's) for the purpose of preparing an operational, permanent, three-dimensional now casting of the tropical Atlantic Ocean (a TOGA objective); and (4) to derive from these models global circulation fields and a time series of mass and meridional heat transports across the tropical Atlantic region (a WOCE objective).
Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene
Vecera, Philipp; Holzwarth, Johannes; Edelthalhammer, Konstantin F.; Mundloch, Udo; Peterlik, Herwig; Hauke, Frank; Hirsch, Andreas
2016-01-01
Herein, we report on a significant discovery, namely, the quantitative discharging of reduced graphite forms, such as graphite intercalation compounds, graphenide dispersions and graphenides deposited on surfaces with the simple solvent benzonitrile. Because of its comparatively low reduction potential, benzonitrile is reduced during this process to the radical anion, which exhibits a red colour and serves as a reporter molecule for the quantitative determination of negative charges on the carbon sheets. Moreover, this discovery reveals a very fundamental physical–chemical phenomenon, namely a quantitative solvent reduction induced and electrostatically driven mass transport of K+ ions from the graphite intercalation compounds into the liquid. The simple treatment of dispersed graphenides suspended on silica substrates with benzonitrile leads to the clean conversion to graphene. This unprecedented procedure represents a rather mild, scalable and inexpensive method for graphene production surpassing previous wet-chemical approaches. PMID:27506380
Loss of cabin pressure in a military transport: a mass casualty with decompression illnesses.
Johnston, Mickaila J
2008-04-01
Presented here is the sudden cabin depressurization of a military C-130 aircraft carrying 66 personnel. They suffered a depressurization from 2134 to 7317 m, resulting in a potential 66-person mass casualty. The aircrew were able to descend to below 3049 m in less than 5 min. They landed in the Kingdom of Bahrain--the nearest hyperbaric recompression facility. Three cases of peripheral neurologic DCS and one case of spinal DCS were identified. Limited manning, unique host nation concerns, and limited available assets led to difficulties in triage, patient transport, and asset allocation. These led to difficult decisions regarding when and for whom to initiate ground level oxygen or hyperbaric recompression therapy.
The Sheath Transport Observer for the Redistribution of Mass (STORM) Image
NASA Technical Reports Server (NTRS)
Kuntz, Kip; Collier, Michael; Sibeck, David G.; Porter, F. Scott; Carter, J. A.; Cravens, Thomas; Omidi, N.; Robertson, Ina; Sembay, S.; Snowden, Steven L.
2008-01-01
All of the solar wind energy that powers magnetospheric processes passes through the magnetosheath and magnetopause. Global images of the magnetosheath and magnetopause boundary layers will resolve longstanding controversy surrounding fundamental phenomena that occur at the magnetopause and provide information needed to improve operational space weather models. Recent developments showing that soft X-rays (0.15-1 keV) result from high charge state solar wind ions undergoing charge exchange recombination through collisions with exospheric neutral atoms has led to the realization that soft X-ray imaging can provide global maps of the high-density shocked solar wind within the magnetosheath and cusps, regions lying between the lower density solar wind and magnetosphere. We discuss an instrument concept called the Sheath Transport Observer for the Redistribution of Mass (STORM), an X-ray imager suitable for simultaneously imaging the dayside magnetosheath, the magnetopause boundary layers, and the cusps.
Mass transport, corrosion, plugging, and their reduction in solar dish/Stirling heat pipe receivers
Adkins, D.R.; Andraka, C.E.; Bradshaw, R.W.; Goods, S.H.; Moreno, J.B.; Moss, T.A.
1996-07-01
Solar dish/Stirling systems using sodium heat pipe receivers are being developed by industry and government laboratories here and abroad. The unique demands of this application lead to heat pipe wicks with very large surface areas and complex three-dimensional flow patterns. These characteristics can enhance the mass transport and concentration of constituents of the wick material, resulting in wick corrosion and plugging. As the test times for heat pipe receivers lengthen, we are beginning to see these effects both indirectly, as they affect performance, and directly in post-test examinations. We are also beginning to develop corrective measures. In this paper, we report on our test experiences, our post-test examinations, and on our initial effort to ameliorate various problems.
Contribution of di-SIA to mass transport in Fe-Cr alloys
NASA Astrophysics Data System (ADS)
Ryabov, V. A.; Pechenkin, V. A.; Molodtsov, V. L.; Terentyev, D.
2016-04-01
Molecular dynamics simulations have been performed to study the diffusion characteristics of di-self interstitial atom (di-SIA) in BCC Fe-Cr alloys and corresponding mass transport of Fe and Cratoms in the temperature range 600-1000 K in the alloys with Cr content 5-25 at%, which is relevant for ferritic/martensitic steels. An original treatment is proposed in this work to account for a mixed migration mode composed of the diffusion of the cluster itself and break-up into a pair of independent SIAs. The ratio of self-diffusion coefficients of Cr and Fe is found to exceed unity in Fe-5Cr and Fe-10Cr alloys, which implies that under cascade-producing damage, 3D-migrating small SIA clusters will effectively contribute to the segregation of Cr to neutral and SIA-preferential sinks, eventually causing radiation induced segregation.
A biphasic hyperelastic model for the analysis of fluid and mass transport in brain tissue.
García, José Jaime; Smith, Joshua H
2009-02-01
A biphasic hyperelastic finite element model is proposed for the description of the mechanical behavior of brain tissue. The model takes into account finite deformations through an Ogden-type hyperelastic compressible function and a hydraulic conductivity dependent on deformation. The biphasic equations, implemented here for spherical symmetry using an updated Lagrangian algorithm, yielded radial coordinates and fluid velocities that were used with the convective-diffusive equation in order to predict mass transport in the brain. Results of the model were equal to those of a closed-form solution under infinitesimal deformations, however, for a wide range of material parameters, the model predicted important increments in the infusion sphere, reductions of the fluid velocities, and changes in the species content distribution. In addition, high localized deformation and stresses were obtained at the infusion sphere. Differences with the infinitesimal solution may be mainly attributed to geometrical nonlinearities related to the increment of the infusion sphere and not to material nonlinearities.
A biphasic hyperelastic model for the analysis of fluid and mass transport in brain tissue.
García, José Jaime; Smith, Joshua H
2009-02-01
A biphasic hyperelastic finite element model is proposed for the description of the mechanical behavior of brain tissue. The model takes into account finite deformations through an Ogden-type hyperelastic compressible function and a hydraulic conductivity dependent on deformation. The biphasic equations, implemented here for spherical symmetry using an updated Lagrangian algorithm, yielded radial coordinates and fluid velocities that were used with the convective-diffusive equation in order to predict mass transport in the brain. Results of the model were equal to those of a closed-form solution under infinitesimal deformations, however, for a wide range of material parameters, the model predicted important increments in the infusion sphere, reductions of the fluid velocities, and changes in the species content distribution. In addition, high localized deformation and stresses were obtained at the infusion sphere. Differences with the infinitesimal solution may be mainly attributed to geometrical nonlinearities related to the increment of the infusion sphere and not to material nonlinearities. PMID:19058008
Decay characteristics of surface mounds with contrasting interlayer mass transport channels.
Li, M; Wendelken, J F; Liu, B G; Wang, E G; Zhang, Z
2001-03-12
The decay characteristics of three-dimensional (3D) islands formed on surfaces are investigated theoretically considering two types of interlayer mass transport mechanisms. If an adatom on a given layer can easily descend from any site along the periphery of the layer, an optimal island slope and a constant terrace width will be selected during the decay. In contrast, if the adatom can descend primarily through selective (such as kinked) sites, the decay will be accompanied by a gradual increase in the island slope. These generic conclusions provide the basis for a microscopic understanding of the decay of nanostructures in fcc(111) and fcc(100) metal homoepitaxy and are applicable to other systems as well.
Decay Characteristics of Surface Mounds with Contrasting Interlayer Mass Transport Channels
Li, Maozhi; Wendelken, J. F.; Liu, Bang-Gui; Wang, E. G.; Zhang, Zhenyu
2001-03-12
The decay characteristics of three-dimensional (3D) islands formed on surfaces are investigated theoretically considering two types of interlayer mass transport mechanisms. If an adatom on a given layer can easily descend from any site along the periphery of the layer, an optimal island slope and a constant terrace width will be selected during the decay. In contrast, if the adatom can descend primarily through selective (such as kinked) sites, the decay will be accompanied by a gradual increase in the island slope. These generic conclusions provide the basis for a microscopic understanding of the decay of nanostructures in fcc(111) and fcc(100) metal homoepitaxy and are applicable to other systems as well.
The Sheath Transport Observer for the Redistribution of Mass (STORM) Imager
NASA Technical Reports Server (NTRS)
Collier, Michael R.; Sibeck, David G.; Porter, F. Scott; Burch, J.; Carter, J. A.; Cravens, Thomas; Kuntz, Kip; Omidi, N.; Read, A.; Robertson, Ina; Sembay, S.; Snowden, Steven L.
2010-01-01
All of the solar wind energy that powers magnetospheric processes passes through the magnetosheath and magnetopause. Global images of the magnetosheath and magnetopause boundary layers will resolve longstanding controversies surrounding fundamental phenomena that occur at the magnetopause and provide information needed to improve operational space weather models. Recent developments showing that soft X-rays (0.15-1 keV) result from high charge state solar wind ions undergoing charge exchange recombination through collisions with exospheric neutral atoms has led to the realization that soft X-ray imaging can provide global maps of the high-density shocked solar wind within the magnetosheath and cusps, regions lying between the lower density solar wind and magnetosphere. We discuss an instrument concept called the Sheath Transport Observer for the Redistribution of Mass (STORM), an X-ray imager suitable for simultaneously imaging the dayside magnetosheath, the magnetopause boundary layers, and the cusps.
Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene.
Vecera, Philipp; Holzwarth, Johannes; Edelthalhammer, Konstantin F; Mundloch, Udo; Peterlik, Herwig; Hauke, Frank; Hirsch, Andreas
2016-01-01
Herein, we report on a significant discovery, namely, the quantitative discharging of reduced graphite forms, such as graphite intercalation compounds, graphenide dispersions and graphenides deposited on surfaces with the simple solvent benzonitrile. Because of its comparatively low reduction potential, benzonitrile is reduced during this process to the radical anion, which exhibits a red colour and serves as a reporter molecule for the quantitative determination of negative charges on the carbon sheets. Moreover, this discovery reveals a very fundamental physical-chemical phenomenon, namely a quantitative solvent reduction induced and electrostatically driven mass transport of K(+) ions from the graphite intercalation compounds into the liquid. The simple treatment of dispersed graphenides suspended on silica substrates with benzonitrile leads to the clean conversion to graphene. This unprecedented procedure represents a rather mild, scalable and inexpensive method for graphene production surpassing previous wet-chemical approaches. PMID:27506380
Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene
NASA Astrophysics Data System (ADS)
Vecera, Philipp; Holzwarth, Johannes; Edelthalhammer, Konstantin F.; Mundloch, Udo; Peterlik, Herwig; Hauke, Frank; Hirsch, Andreas
2016-08-01
Herein, we report on a significant discovery, namely, the quantitative discharging of reduced graphite forms, such as graphite intercalation compounds, graphenide dispersions and graphenides deposited on surfaces with the simple solvent benzonitrile. Because of its comparatively low reduction potential, benzonitrile is reduced during this process to the radical anion, which exhibits a red colour and serves as a reporter molecule for the quantitative determination of negative charges on the carbon sheets. Moreover, this discovery reveals a very fundamental physical-chemical phenomenon, namely a quantitative solvent reduction induced and electrostatically driven mass transport of K+ ions from the graphite intercalation compounds into the liquid. The simple treatment of dispersed graphenides suspended on silica substrates with benzonitrile leads to the clean conversion to graphene. This unprecedented procedure represents a rather mild, scalable and inexpensive method for graphene production surpassing previous wet-chemical approaches.
Optimal-mass-transfer-based estimation of glymphatic transport in living brain
NASA Astrophysics Data System (ADS)
Ratner, Vadim; Zhu, Liangjia; Kolesov, Ivan; Nedergaard, Maiken; Benveniste, Helene; Tannenbaum, Allen
2015-03-01
It was recently shown that the brain-wide cerebrospinal fluid (CSF) and interstitial fluid exchange system designated the `glymphatic pathway' plays a key role in removing waste products from the brain, similarly to the lymphatic system in other body organs . It is therefore important to study the flow patterns of glymphatic transport through the live brain in order to better understand its functionality in normal and pathological states. Unlike blood, the CSF does not flow rapidly through a network of dedicated vessels, but rather through para-vascular channels and brain parenchyma in a slower time-domain, and thus conventional fMRI or other blood-flow sensitive MRI sequences do not provide much useful information about the desired flow patterns. We have accordingly analyzed a series of MRI images, taken at different times, of the brain of a live rat, which was injected with a paramagnetic tracer into the CSF via the lumbar intrathecal space of the spine. Our goal is twofold: (a) find glymphatic (tracer) flow directions in the live rodent brain; and (b) provide a model of a (healthy) brain that will allow the prediction of tracer concentrations given initial conditions. We model the liquid flow through the brain by the diffusion equation. We then use the Optimal Mass Transfer (OMT) approach to derive the glymphatic flow vector field, and estimate the diffusion tensors by analyzing the (changes in the) flow. Simulations show that the resulting model successfully reproduces the dominant features of the experimental data. Keywords: inverse problem, optimal mass transport, diffusion equation, cerebrospinal fluid flow in brain, optical flow, liquid flow modeling, Monge Kantorovich problem, diffusion tensor estimation
NASA Astrophysics Data System (ADS)
Ezzedine, S. M.
2010-12-01
Fractures and fracture networks are the principle pathways for migration of water, heat and mass in enhanced geothermal systems, oil and gas reservoirs, CO2 leakage from saline aquifers, and radioactive and toxic industrial wastes from underground storage repositories. A major issue to overcome when characterizing a fractured reservoir is that of data limitation due to accessibility and affordability. Moreover, the ability to map discontinuities in the rock with available geological and geophysical tools tends to decrease particularly as the scale of the discontinuity goes down. Geological characterization data include measurements of fracture density, orientation, extent, and aperture, and are based on analysis of outcrops, borehole optical and acoustic televiewer logs, aerial photographs, and core samples among others. All of these measurements are taken at the field scale through a very sparse limited number of deep boreholes. These types of data are often reduced to probability distributions function for predictive modeling and simulation in a stochastic framework such as stochastic discrete fracture network. Stochastic discrete fracture network models enable, through Monte Carlo realizations and simulations, for probabilistic assessment of flow and transport phenomena that are not adequately captured using continuum models. Despite the fundamental uncertainties inherited within the probabilistic reduction of the sparse data collected, very little work has been conducted on quantifying uncertainty on the reduced probabilistic distribution functions. In the current study, using nested Monte Carlo simulations, we present the impact of parameter uncertainties of the distribution functions that characterize discrete fracture networks on the flow, heat and mass transport. Numerical results of first, second and third moments, normalized to a base case scenario, are presented and compared to theoretical results extended from percolation theory.
A generalized mass transfer law unifying various particle transport mechanisms in dilute dispersions
NASA Astrophysics Data System (ADS)
Guha, Abhijit
2008-09-01
A generalized mass transfer law for dilute dispersion of particles (or droplets) of any sizes suspended in a fluid has been described, which can be applied to turbulent or laminar flow. The generalized law reduces to the Fick’s law of diffusion in the limit of very small particles. Thus the study shows how the well-known and much-used Fick’s law of diffusion fits into the broader context of particle transport. The general expression for particle flux comprises a diffusive flux due to Brownian motion and turbulent fluctuation, a diffusive flux due to temperature gradient (thermophoresis plus stressphoresis) and a convective flux that arises primarily due to the interaction of particle inertia and the inhomogeneity of the fluid turbulence field (turbophoresis). Shear-induced lift force, electrical force, gravity, etc. also contribute to the convective flux. The present study includes the effects of surface roughness, and the calculations show that the presence of small surface roughness even in the hydraulically smooth regime significantly enhances deposition especially of small particles. Thermophoresis can have equally strong effects, even with a modest temperature difference between the wall and the bulk fluid. For particles of the intermediate size range, turbophoresis, thermophoresis and roughness are all important contributors to the overall deposition rate. The paper includes a parametric study of the effects of electrostatic forces due to mirror charging. The present work provides a unified framework to determine the combined effect of various particle transport mechanisms on mass transfer rate and the inclusion of other mechanisms not considered in this paper is possible.
Milliken, M.D.; McJannet, G.S.; Shiflett, D.W.; Deutsch, H.A.
1996-12-31
The {open_quotes}A{close_quotes} sands of the Northwest Stevens Pool consist of six major subdivisions (A1-A6) and numerous sublayers. These sands are above the {open_quotes}N Point{close_quotes} stratigraphic marker, making them much younger than most other Stevens sands at Elk Hills. Cores show the A1-A3 sands to be possibly mass transport deposition, primarily debris flows, slumps, and sand injection bodies. The A4-A6 sands are characterized by normally graded sheet-like sand bodies Hospital of traditional outer fan turbidite lithofacies. Most current production from the A1-A2 interval comes from well 373A-7R, are completed waterflood wells that came on line in 1992 at 1400 BOPD. Well 373A-7R is an anomaly in the A1-A2 zone, where average production from the other ten wells is 200 BOPD. Other evidence for compartmentalization in the A1-A2 interval includes sporadic oil-water contacts and drawdown pressures, difficult log correlations, and rapid thickness changes. In 1973, well 362-7R penetrated 220 ft of wet Al sand. The well was redrilled updip and successfully completed in the A1, where the oil-water contact is more than 130 ft lower than the original hole and faulting is not apparent. In 1992, horizontal well 323H-7R unexpectedly encountered an entirely wet Al wedge zone. Reevaluation of the A1-A3 and other sands as mass transport origin is important for modeling initialization and production/development strategies.
Milliken, M.D.; McJannet, G.S. ); Shiflett, D.W. ); Deutsch, H.A. )
1996-01-01
The [open quotes]A[close quotes] sands of the Northwest Stevens Pool consist of six major subdivisions (A1-A6) and numerous sublayers. These sands are above the [open quotes]N Point[close quotes] stratigraphic marker, making them much younger than most other Stevens sands at Elk Hills. Cores show the A1-A3 sands to be possibly mass transport deposition, primarily debris flows, slumps, and sand injection bodies. The A4-A6 sands are characterized by normally graded sheet-like sand bodies Hospital of traditional outer fan turbidite lithofacies. Most current production from the A1-A2 interval comes from well 373A-7R, are completed waterflood wells that came on line in 1992 at 1400 BOPD. Well 373A-7R is an anomaly in the A1-A2 zone, where average production from the other ten wells is 200 BOPD. Other evidence for compartmentalization in the A1-A2 interval includes sporadic oil-water contacts and drawdown pressures, difficult log correlations, and rapid thickness changes. In 1973, well 362-7R penetrated 220 ft of wet Al sand. The well was redrilled updip and successfully completed in the A1, where the oil-water contact is more than 130 ft lower than the original hole and faulting is not apparent. In 1992, horizontal well 323H-7R unexpectedly encountered an entirely wet Al wedge zone. Reevaluation of the A1-A3 and other sands as mass transport origin is important for modeling initialization and production/development strategies.
NASA Astrophysics Data System (ADS)
Abdelaziz, Ramadan; Sussumu Komori, Fabio
2015-04-01
Recently, Lattice Boltzmann Modelling (LBM) techniques attract many scientists in various fields of research. This work shows the capability for LBM to simulate the fluid flow and solute transport in porous and fracture media, additionally, how to study behavior of nanofluids submitted to a temperature gradient, which it is an important process in natural aquatic environments, water treatment, and other water related technologies. LBSim is used in this work as Lattice Boltzmann Model simulator software. In this article, a series of cases using the lattice Boltzmann method are presented, showing the capability of the method in simulating phenomena with fluid flow and heat transfer in porous media. Results show that the lattice Boltzmann method delivers reliable and helpful simulations for the analyses of processes in water related technologies. Thus, LBSim is a recommended tool for simulating fluid flow at laminar and turbulent condition, and heat and mass transport under complex geometry and boundary condition. parameter values. Keywords: Lattice Boltzmann Model, LBSim, Fractures Media, Porous Media, nanofluids
Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations
Vold, E. L.; Molvig, K.; Joglekar, A. S.; Ortega, M. I.; Moll, R.; Fenn, D.
2015-11-15
The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.
Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations
NASA Astrophysics Data System (ADS)
Vold, E. L.; Joglekar, A. S.; Ortega, M. I.; Moll, R.; Fenn, D.; Molvig, K.
2015-11-01
The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.
3D nonrigid registration via optimal mass transport on the GPU
Rehman, Tauseef ur; Haber, Eldad; Pryor, Gallagher; Melonakos, John; Tannenbaum, Allen
2009-01-01
In this paper, we present a new computationally efficient numerical scheme for the minimizing flow approach for optimal mass transport (OMT) with applications to non-rigid 3D image registration. The approach utilizes all of the gray-scale data in both images, and the optimal mapping from image A to image B is the inverse of the optimal mapping from B to A. Further, no landmarks need to be specified, and the minimizer of the distance functional involved is unique. Our implementation also employs multigrid, and parallel methodologies on a consumer graphics processing unit (GPU) for fast computation. Although computing the optimal map has been shown to be computationally expensive in the past, we show that our approach is orders of magnitude faster then previous work and is capable of finding transport maps with optimality measures (mean curl) previously unattainable by other works (which directly influences the accuracy of registration). We give results where the algorithm was used to compute non-rigid registrations of 3D synthetic data as well as intra-patient pre-operative and post-operative 3D brain MRI datasets. PMID:19135403
Energy and Mass Transport of Magnetospheric Plasmas during the November 2003 Magnetic Storm
NASA Technical Reports Server (NTRS)
Fok, Mei-Chging; Moore, Thomas
2008-01-01
Intensive energy and mass transport from the solar wind across the magnetosphere boundary is a trigger of magnetic storms. The storm on 20-21 November 2003 was elicited by a high-speed solar wind and strong southward component of interplanetary magnetic field. This storm attained a minimum Dst of -422 nT. During the storm, some of the solar wind particles enter the magnetosphere and eventually become part of the ring current. At the same time, the fierce solar wind powers strong outflow of H+ and O+ from the ionosphere, as well as from the plasmasphere. We examine the contribution of plasmas from the solar wind, ionosphere and plasmasphere to the storm-time ring current. Our simulation shows, for this particular storm, ionospheric O+ and solar wind ions are the major sources of the ring current particles. The polar wind and plasmaspheric H+ have only minor impacts. In the storm main phase, the strong penetration of solar wind electric field pushes ions from the geosynchronous orbit to L shells of 2 and below. Ring current is greatly intensified during the earthward transport and produces a large magnetic depression in the surface field. When the convection subsides, the deep penetrating ions experience strong charge exchange loss, causing rapid decay of the ring current and fast initial storm recovery. Our simulation reproduces very well the storm development indicated by the Dst index.
Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations
Vold, Erik Lehman; Joglekar, Archis S.; Ortega, Mario I.; Moll, Ryan; Fenn, Daniel; Molvig, Kim
2015-11-20
The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion(ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. In this paper, we have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasmaviscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasmaviscosity andmore » to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasmaviscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Finally, plasmaviscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.« less
Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations
Vold, Erik Lehman; Joglekar, Archis S.; Ortega, Mario I.; Moll, Ryan; Fenn, Daniel; Molvig, Kim
2015-11-20
The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion(ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. In this paper, we have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasmaviscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasmaviscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasmaviscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Finally, plasmaviscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.
Mass transport around comets and its impact on the seasonal differences in water production rates
Rubin, M.; Altwegg, K.; Thomas, N.; Fougere, N.; Combi, M. R.; Tenishev, V. M.; Le Roy, L.
2014-06-20
Comets are surrounded by a thin expanding atmosphere, and although the nucleus' gravity is small, some molecules and grains, possibly with the inclusion of ices, can get transported around the nucleus through scattering (atoms/molecules) and gravitational pull (grains). Based on the obliquity of the comet, it is also possible that volatile material and icy grains get trapped in regions, which are in shadow until the comet passes its equinox. When the Sun rises above the horizon and the surface starts to heat up, this condensed material starts to desorb and icy grains will sublimate off the surface, possibly increasing the comet's neutral gas production rate on the outbound path. In this paper we investigate the mass transport around the nucleus, and based on a simplified model, we derive the possible contribution to the asymmetry in the seasonal gas production rate that could arise from trapped material released from cold areas once they come into sunlight. We conclude that the total amount of volatiles retained by this effect can only contribute up to a few percent of the asymmetry observed in some comets.
NASA Technical Reports Server (NTRS)
Marshall, Jochen; Milos, Frank; Fredrich, Joanne; Rasky, Daniel J. (Technical Monitor)
1997-01-01
Laser Scanning Confocal Microscopy (LSCM) has been used to obtain digital images of the complicated 3-D (three-dimensional) microstructures of rigid, fibrous thermal protection system (TPS) materials. These orthotropic materials are comprised of refractory ceramic fibers with diameters in the range of 1 to 10 microns and have open porosities of 0.8 or more. Algorithms are being constructed to extract quantitative microstructural information from the digital data so that it may be applied to specific heat and mass transport modeling efforts; such information includes, for example, the solid and pore volume fractions, the internal surface area per volume, fiber diameter distributions, and fiber orientation distributions. This type of information is difficult to obtain in general, yet it is directly relevant to many computational efforts which seek to model macroscopic thermophysical phenomena in terms of microscopic mechanisms or interactions. Two such computational efforts for fibrous TPS materials are: i) the calculation of radiative transport properties; ii) the modeling of gas permeabilities.
The effects of advection solvers on the performance of air quality models
Tanrikulu, S.; Odman, M.T.
1996-12-31
The available numerical solvers for the advection term in the chemical species conservation equation have different properties, and consequently introduce different types of errors. These errors can affect the performance of air quality models and lead to biases in model results. In this study, a large number of advection solvers have been studied and six of them were identified as having potential for use in photochemical models. The identified solvers were evaluated extensively using various numerical tests that are relevant to air quality simulations. Among the solvers evaluated, three of them showed better performance in terms of accuracy and some other characteristics such as conservation of mass and positivity. They are the solvers by Bott, Yuamartino, and Dabdub and Seinfeld. These three solvers were incorporated into the SARMAP Air Quality Model (SAQM) and the August 3-6, 1990 ozone episode in the San Joaquin Valley of California was simulated with each. A model performance analysis was conducted for each simulation using the rich air quality database of the 1990 San Joaquin Valley Air Quality Study. The results of the simulations were compared with each other and the effects of advection solvers on the performance of the model are discussed.
Constraints on the Magnitude of Vertical and Lateral Mass Transport on the Moon
NASA Technical Reports Server (NTRS)
Mustard, John F.
1997-01-01
The role of vertical and lateral mass transport of crustal materials on the observed patterns of lunar surface composition, and the effects on our understanding of the geologic evolution of the planet, have been the subject of much debate in the lunar science community. The primary consensus that emerged from analyses of these processes in the 1970's and 1980's was that vertical and lateral mixing through impact gardening was a relatively inefficient process, and not likely to have contributed significantly to compositional units and variations on the Moon. The supporting evidence for this view is that unit boundaries (e.g. mare-highland contacts, contacts between mare color units) are still apparently quite distinct and sharp despite several aeons of impact activity, and cores from the Apollo landing sites did not show any evidence of widespread homogenization of the surface composition, nor distinct compositional gradients across geologic boundaries. In addition, modeling of vertical and lateral transport generally showed that the effects on composition should be confined to horizontal scales of about a kilometer and vertical scales of a meter. The problem with this consensus is that there is ample contradictory evidence. The fundamental discovery of Wood et al. (1970) was made possible by significant horizontal transport of highland material to the center of Mare Tranquillitatis. The continuous and discontinuous ejecta from the crater Copernicus has clearly influenced the surface composition of a large area of the lunar maria, while rays and ejecta from many highland craters are easily recognized in and around the nearside maria. Despite this contrary evidence, there have been few detailed studies to quantify the amount and rate of material redistribution through impact processes (a notable exception is reported in the paper by Pieters et al, 1985), largely because data adequate to critically analyze this process were lacking. However, the multispectral images
NASA Astrophysics Data System (ADS)
Shrestha, Binaya Kumar
This thesis focuses on understanding implications of nanomaterial quality control and mass transport through internally etched silica coated nanoparticles for direct and quantitative molecular detection using surface enhanced Raman scattering (SERS). Prior to use, bare nanoparticles (partially or uncoated with silica) are removal using column chromatography to improve the quality of these nanomaterials and their SERS reproducibility. Separation of silica coated nanoparticles with two different diameters is achieved using Surfactant-free size exclusion chromatography with modest fractionation. Next, selective molecular transport is modeled and monitored using SERS and evaluated as a function of solution ionic strength, pH, and polarity. Molecular detection is achieved when the analytes first partition through the silica membrane then interact with the metal surface at short distances (i.e., less than 2 nm). The SERS intensities of unique molecular vibrational modes for a given molecule increases as the number of molecules that bind to the metal surface increases and are enhanced via both chemical and electromagnetic enhancement mechanisms as long as the vibrational mode has a component of polarizability tensor along the surface normal. SERS signals increase linearly with molecular concentration until the three-dimensional SERS-active volume is saturated with molecules. Implications of molecular orientation as well as surface selection rules on SERS intensities of molecular vibrational modes are studied to improve quantitative and reproducible SERS detection using internally etched Ag Au SiO2 nanoparticles. Using the unique vibrational modes, SERS intensities for p-aminothiophenol as a function of metal core compositions and plasmonics are studied. By understanding molecular transport mechanisms through internally etched silica matrices coated on metal nanoparticles, important experimental and materials design parameters are learned, which can be subsequently applied
Interpolation of longitudinal shape and image data via optimal mass transport
NASA Astrophysics Data System (ADS)
Gao, Yi; Zhu, Liang-Jia; Bouix, Sylvain; Tannenbaum, Allen
2014-03-01
Longitudinal analysis of medical imaging data has become central to the study of many disorders. Unfortunately, various constraints (study design, patient availability, technological limitations) restrict the acquisition of data to only a few time points, limiting the study of continuous disease/treatment progression. Having the ability to produce a sensible time interpolation of the data can lead to improved analysis, such as intuitive visualizations of anatomical changes, or the creation of more samples to improve statistical analysis. In this work, we model interpolation of medical image data, in particular shape data, using the theory of optimal mass transport (OMT), which can construct a continuous transition from two time points while preserving "mass" (e.g., image intensity, shape volume) during the transition. The theory even allows a short extrapolation in time and may help predict short-term treatment impact or disease progression on anatomical structure. We apply the proposed method to the hippocampus-amygdala complex in schizophrenia, the heart in atrial fibrillation, and full head MR images in traumatic brain injury.
Back to the primordial universe by a monge-ampere-kantorovich mass transportation method
NASA Astrophysics Data System (ADS)
Frisch, U.
2003-04-01
The Monge-Kantorovich mass transportation problem dates back to work by Monge in 1781 on how to optimally move earth from one place to another, knowing only the initial and final landscapes, the cost being a prescribed function of the distance travelled by "molecules" of earth. We solve the cosmological reconstruction problem of mapping the present locations of (mostly dark) matter, to their primordial locations, knowing only the current field of mass density, e.g. from a full-sky galaxy catalogue or a numerical simulation. Under the assumption that the map is close to potential, we reduce the problem to solving a nonlinear partial differential equation, originally written by Ampere in 1820, now known as the Monge-Ampere equation. Thanks to recent work by Y. Brenier, this becomes a Monge-Kantorovich problem with quadratic cost function and, in discretised form, an assignment problem: find the pairing between N departure and N arrival points which minimises the sum of the squared distances between paired points. The latter can be solved very efficiently by the auction algorithm of Bertsekas. When tested against N-body cosmological simulations, excellent reconstruction is obtained above a few megaparsecs. Based on the paper Frisch-Matarrese-Mohayaee-Sobolevski Nature 417, 260-262 (16 May 2002).
Advection of Sea-Ice Meltwater and Halocline Water Along the Siberian Continental Margin
NASA Astrophysics Data System (ADS)
Bauch, D.; Torres-Valdes, S.; Polyakov, I.; Chernyavskaya, E.; Novikhin, A.; Dmitrenko, I.; McKay, J. L.; Mix, A. C.
2014-12-01
Our study is based on hydrochemical and stable oxygen isotope data at the Laptev Sea continental slope from summers 2005-2009 and reveals a general pattern in water mass distribution and potential shelf-basin exchange. Despite considerable inter-annual variations, a frontal system can be inferred between shelf, continental slope and central Eurasian Basin waters in the upper 100 m of the water column along the continental slope. Net sea-ice melt is consistently found at the continental slope. However, the sea-ice meltwater signal is independent from the local retreat of the sea-ice edge and appears to be advected from upwind locations. In addition to the along-slope frontal system at the continental shelf break, a strong gradient is identified on the Laptev Sea shelf at ~122-126°E with an eastward increase of riverine and sea-ice related brine water contents. These waters cross the shelf break at ~140°E and feed the Low Salinity Halocline Water (LSHW, salinity S<33) in the upper 50 m of the water column. High silicate concentrations in Laptev Sea bottom waters may lead to speculation about a link to the local silicate maximum found within the salinity range of ~33 to 34.5, typical for the Lower Halocline Water (LHW) at the continental slope. However brine signatures and nutrient ratios from the central Laptev Sea differ from those observed at the continental slope. Similar to the advection of the sea-ice melt signal along the Laptev Sea continental slope the nutrient signal at 50-70 m water depth within the LHW might also be fed by advection parallel to the slope. Thus, our analyses suggest that advective processes from upstream locations play a significant role in the meltwater distribution and halocline formation in the northern Laptev Sea. Inter-annual variations within the properties of LHW are further investigated.
Lakatos, I.; Bauer, K.; Lakatos-Szabo, J.; Kretzschmar, H.J.
1997-12-31
The diffusion and hydrodynamic mass transport of multivalent cations, mostly Cr(III) and Cr(VI) ions and radon in polymer/silicate gels and Montanwax emulsions were studied. It was concluded that the self-conforming gels may decrease the hydrodynamic mass transport in porous and fractured media by 4-6 orders of magnitude. In water saturated systems, however, the diffusion transport can be restricted by hydrogels only to a moderate extent. On the other hand, the high and selective retention capacity of gels towards different diffusing species may open new vistas in the sealing technologies. Similar results were obtained for transport phenomena of radon. The almost perfect quenching process of radon and its nuclides in gels and emulsions further enhances the positive effects of the encapsulation methods. The laboratory experiments provided valuable new information to design the different containment technologies.
NASA Astrophysics Data System (ADS)
Schnyder, J.
2015-12-01
Submarine slope failures are a likely cause for tsunami generation along the East U.S. coast. A possible source are the large slope failures along western Great Bahama Bank (GBB). Numerical models simulate tsunami generation and propagation through the Straits of Florida, caused by these Pleistocene mass wasting events. In order to estimate the likelihood and extent of future landslides, distribution, characteristics, and possible triggering mechanisms of previous failures and their associated mass transport deposits (MTD) have to be investigated. In 2013, the University of Hamburg acquired 2D high-resolution multichannel seismic data, multibeam data, and subbottom profiles inside the Santaren Channel, along the slopes of western GBB and Cay Sal Bank (CSB). The two platforms are different in two ways. CSB is part of the Cuban Fold and Thrust Belt while GBB is situated in a tectonically quiet zone. In addition, the slopes of western GBB are on the leeward side of the bank, while the eastern slopes of CSB are in a windward position. Differences in nature and size of mass wasting events between the Cay Sal side and the western GBB side of the dataset show how influential the tectonically active Cuban Fold and Thrust Belt is to the generation of large MTDs in this area. In the study area, the slope failures can be divided in two categories; small-scale in situ failures with high frequencies on the slopes, dominant on the western GBB side, and large landslides with a lower frequency, but higher volumes and transport distances on the toe of the slope and in the basin, dominant on the Cay Sal side. The distribution of in situ failures, such as slump and debris flow alternation, shows the interplay between high and low inner strength of the sediment, respectively. On the other hand, large MTDs caused by submarine landslides suggest movement in an unconfined manner. Internal sediment preconditions derived from sea level oscillations are suggested as triggering mechanisms
Code of Federal Regulations, 2014 CFR
2014-01-01
... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...
Code of Federal Regulations, 2013 CFR
2013-07-01
... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...
Code of Federal Regulations, 2012 CFR
2012-01-01
... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...
Code of Federal Regulations, 2011 CFR
2011-01-01
... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...
Code of Federal Regulations, 2010 CFR
2010-07-01
... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...
The role of advection and diffusion in waste disposal by sea urchin embryos
NASA Astrophysics Data System (ADS)
Clark, Aaron; Licata, Nicholas
2014-03-01
We determine the first passage probability for the absorption of waste molecules released from the microvilli of sea urchin embryos. We calculate a perturbative solution of the advection-diffusion equation for a linear shear profile similar to the fluid environment which the embryos inhabit. Rapid rotation of the embryo results in a concentration boundary layer of comparable thickness to the length of the microvilli. A comparison of the results to the regime of diffusion limited transport indicates that fluid flow is advantageous for efficient waste disposal.
NASA Astrophysics Data System (ADS)
Black, Jay R.; John, Seth G.; Kavner, Abby
2014-01-01
The isotopic composition of zinc metal electrodeposited on a rotating disc electrode from a Zn-citrate aqueous solution was investigated as a function of overpotential (electrochemical driving force), temperature, and rotation rate. Zn metal was measured to be isotopically light with respect to Zn+2 in solution, with observed fractionations varying from Δ66/64Znmetal-aqueous = -1.0‰ to -3.9‰. Fractionation varies continuously as a function of a dimensionless parameter described by the ratio of observed deposition rate to calculated mass-transport limiting rate, where larger fractionations are observed at lower deposition rates, lower temperature, and at faster electrode rotation rates. Thus, the large fractionation and its rate dependence is interpreted as a competition between the two kinetic processes with different effective activation energies: mass-transport-limited (diffusion limited) kinetics with a large activation energy, which creates small fractionations close to the predicted diffusive fractionation; and electrochemical deposition kinetics, with a smaller effective activation energy, which creates large fractionations at low deposition rates and high hydrodynamic fluxes of solute to the electrode. The results provide a framework for predicting isotope fractionation in processes controlled by two competing reactions with different kinetic isotope effects. Light isotopes are electroplated. In all cases light stable isotopes of the metals are preferentially electroplated, with mass-dependent behavior evident where three or more isotopes are measured. Fractionation is time-independent, meaning that the fractionation factor does not vary with the extent of reaction. In most of our experiments, we have controlled the extent of reaction such that only a small amount of metal is deposited from the stock solution, thus avoiding significant evolution of the reservoir composition. In such experiments, the observed isotope fractionation is constant as a
Clay with Desiccation Cracks is an Advection Dominated Environment
NASA Astrophysics Data System (ADS)
Baram, S.; Kurtzman, D.; Sher, Y.; Ronen, Z.; Dahan, O.
2012-04-01
Heavy clay sediments are regarded "safe" from the hydrological point of view due to their low hydraulic conductivities. However, the formation of desiccation cracks in dispersive clays may dramatically change their bulk hydraulic properties. The impact of desiccation cracks on water percolation, dissolved salts and contaminants transport and redox related reactions (microbial ammonium oxidation and denitrification) were investigated in 6 -12 m clay layer near a diary farm waste lagoon. The study implemented unique vadose-zone monitoring systems that enable in-situ measurements of the temporal variation of the sediment's water content along with frequent sampling of the sediment's pore water along the entire vadose zone (> 30 m). Results from four years of continuous measurements showed quick rises in sediment water content following rain events and temporal wastewater overflows. The percolation pattern indicated dominance of preferential flow through a desiccation-cracks network crossing the entire clay sediment layer. High water-propagation velocities (0.4 - 23.6 m h-1) were observed, indicating that the desiccation-crack network remains open and serves as a preferential flow pathway year-round, even at high sediment water content (~0.50 m3 m-3). The rapid percolation bypassed the most bio-geo-active parts of the soil, transporting even highly sorptive contaminants (testosterone and estrogen) in to the deep sections of the vadose zone, accelerating the underlying groundwater contamination. The ammonium and nitrate concentrations in the vadose zone and the high number of nitrifying and denitrifying bacteria (~108 gene copies gdry-sediemt-1, each) found in the sediment indicated that the entire vadose zone is aerated even at high water content conditions (~0.55 m3 m-3). The dissolved salts concentration in the pore-water and the δ2H-H2O and δ18O-H2O values of the pore-water substantially increased with depth (becoming less depleted) in the clay sediment
Atomistic Simulations of Mass and Thermal Transport in Oxide Nuclear Fuels
Andersson, Anders D.; Uberuaga, Blas P.; Du, Shiyu; Liu, Xiang-Yang; Nerikar, Pankaj; Stanek, Christopher R.; Tonks, Michael; Millet, Paul; Biner, Bulent
2012-06-04
In this talk we discuss simulations of the mass and thermal transport in oxide nuclear fuels. Redistribution of fission gases such as Xe is closely coupled to nuclear fuel performance. Most fission gases have low solubility in the fuel matrix, specifically the insolubility is most pronounced for large fission gas atoms such as Xe, and as a result there is a significant driving force for segregation of gas atoms to grain boundaries or dislocations and subsequently for nucleation of gas bubbles at these sinks. The first step of the fission gas redistribution is diffusion of individual gas atoms through the fuel matrix to existing sinks, which is governed by the activation energy for bulk diffusion. Fission gas bubbles are then formed by either separate nucleation events or by filling voids that were nucleated at a prior stage; in both cases their formation and latter growth is coupled to vacancy dynamics and thus linked to the production of vacancies via irradiation or thermal events. In order to better understand bulk Xe behavior (diffusion mechanisms) in UO{sub 2{+-}x} we first calculate the relevant activation energies using density functional theory (DFT) techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism, though other alternatives may exist in high irradiation fields. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next a continuum transport model for Xe and U is formulated based on the diffusion mechanisms established from DFT. After combining this model with descriptions of the interaction between Xe and grain
Wang, H.; Man, S.; Ewing, R.E.; Qin, G.; Lyons, S.L.; Al-Lawatia, M.
1999-06-10
Many difficult problems arise in the numerical simulation of fluid flow processes within porous media in petroleum reservoir simulation and in subsurface contaminant transport and remediation. The authors develop a family of Eulerian-Lagrangian localized adjoint methods for the solution of the initial-boundary value problems for first-order advection-reaction equations on general multi-dimensional domains. Different tracking algorithms, including the Euler and Runge-Kutta algorithms, are used. The derived schemes, which are full mass conservative, naturally incorporate inflow boundary conditions into their formulations and do not need any artificial outflow boundary conditions. Moreover, they have regularly structured, well-conditioned, symmetric, and positive-definite coefficient matrices, which can be efficiently solved by the conjugate gradient method in an optimal order number of iterations without any preconditioning needed. Numerical results are presented to compare the performance of the ELLAM schemes with many well studied and widely used methods, including the upwind finite difference method, the Galerkin and the Petrov-Galerkin finite element methods with backward-Euler or Crank-Nicolson temporal discretization, the streamline diffusion finite element methods, the monotonic upstream-centered scheme for conservation laws (MUSCL), and the Minmod scheme.
Mass Conservation in a Chemical Transport Model and its Effect on CO2 and SF6 Simulations
NASA Technical Reports Server (NTRS)
Zhu, Z.; Weaver, C.; Kawa, S. R.; Douglass, A. R.; Bhartia, P. K. (Technical Monitor)
2002-01-01
Chemical transport models (CTMs) must conserve mass to be useful for applications involving assessment of the effect of various pollutants on the troposphere and stratosphere. Furthermore, calculations of the evolution of constituents such as SF6 are used to evaluate overall model transport, and interpretation of such simulations is clouded if mass conservation is not assured. For realistic simulations or predictions, it is crucial that constituents are not produced or lost by transport or other processes in the CTMs. Analysis of CO2 and SF6 experiments using a CTM shows that problems with mass conservation can seriously degrade the simulations. Failure to conserve mass results from inconsistency of the surface pressure tendency and the divergence of horizontal mass flux when the model is forced by assimilated meteorological data. We have developed an effective method to eliminate the inconsistency by modifying the divergent part of the wind field. The changes in the wind fields are quite small but the impact on mass conservation is large. Parameterizations of physical processes such as convection or turbulent transport can also affect mass conservation. The lack of conservation is small but accumulates when integrations are lengthy such as required for SF6. This lack of conservation is found using winds from either a GCM or from an assimilation system. A simple adjustment removes much of the inaccuracy in the convective parameterization. A CO2 simulation using assimilated winds from the most recent version of the Goddard Earth Observing System Data Assimilation System will be used to illustrate the impact of these transport improvements.
Advecting Procedural Textures for 2D Flow Animation
NASA Technical Reports Server (NTRS)
Kao, David; Pang, Alex; Moran, Pat (Technical Monitor)
2001-01-01
This paper proposes the use of specially generated 3D procedural textures for visualizing steady state 2D flow fields. We use the flow field to advect and animate the texture over time. However, using standard texture advection techniques and arbitrary textures will introduce some undesirable effects such as: (a) expanding texture from a critical source point, (b) streaking pattern from the boundary of the flowfield, (c) crowding of advected textures near an attracting spiral or sink, and (d) absent or lack of textures in some regions of the flow. This paper proposes a number of strategies to solve these problems. We demonstrate how the technique works using both synthetic data and computational fluid dynamics data.
NASA Technical Reports Server (NTRS)
Fanale, Fraser P.; Salvail, James R.; Matson, Dennis L.; Brown, Robert H.
1990-01-01
The present quantitative modeling of convective, condensational, and sublimational effects on porous ice crust volumes subjected to solar radiation encompasses the effect of such insolation's penetration of visible bandpass-translucent light, but opaque to the IR bandpass. Quasi-steady-state temperatures, H2O mass fluxes, and ice mass-density change rates are computed as functions of time of day and ice depth. When the effects of latent heat and mass transport are included in the model, the enhancement of near-surface temperature due to the 'solid-state greenhouse effect' is substantially diminished. When latent heat, mass transport, and densification effects are considered, however, a significant solid-state greenhouse effect is shown to be compatible with both morphological evidence for high crust strengths and icy shell decoupling from the lithosphere.
NASA Astrophysics Data System (ADS)
Kotaka, Toshikazu; Tabuchi, Yuichiro; Mukherjee, Partha P.
2015-04-01
Cost reduction is a key issue for commercialization of fuel cell electric vehicles (FCEV). High current density operation is a solution pathway. In order to realize high current density operation, it is necessary to reduce mass transport resistance in the gas diffusion media commonly consisted of gas diffusion layer (GDL) and micro porous layer (MPL). However, fundamental understanding of the underlying mass transport phenomena in the porous components is not only critical but also not fully understood yet due to the inherent microstructural complexity. In this study, a comprehensive analysis of electron and oxygen transport in the GDL and MPL is conducted experimentally and numerically with three-dimensional (3D) microstructural data to reveal the structure-transport relationship. The results reveal that the mass transport in the GDL is strongly dependent on the local microstructural variations, such as local pore/solid volume fractions and connectivity. However, especially in the case of the electrical conductivity of MPL, the contact resistance between carbon particles is the dominant factor. This suggests that reducing the contact resistance between carbon particles and/or the number of contact points along the transport pathway can improve the electrical conductivity of MPL.
Continuous time random walks for non-local radial solute transport
NASA Astrophysics Data System (ADS)
Dentz, Marco; Kang, Peter K.; Le Borgne, Tanguy
2015-08-01
This study formulates and analyzes continuous time random walk (CTRW) models in radial flow geometries for the quantification of non-local solute transport induced by heterogeneous flow distributions and by mobile-immobile mass transfer processes. To this end we derive a general CTRW framework in radial coordinates starting from the random walk equations for radial particle positions and times. The particle density, or solute concentration is governed by a non-local radial advection-dispersion equation (ADE). Unlike in CTRWs for uniform flow scenarios, particle transition times here depend on the radial particle position, which renders the CTRW non-stationary. As a consequence, the memory kernel characterizing the non-local ADE, is radially dependent. Based on this general formulation, we derive radial CTRW implementations that (i) emulate non-local radial transport due to heterogeneous advection, (ii) model multirate mass transfer (MRMT) between mobile and immobile continua, and (iii) quantify both heterogeneous advection in a mobile region and mass transfer between mobile and immobile regions. The expected solute breakthrough behavior is studied using numerical random walk particle tracking simulations. This behavior is analyzed by explicit analytical expressions for the asymptotic solute breakthrough curves. We observe clear power-law tails of the solute breakthrough for broad (power-law) distributions of particle transit times (heterogeneous advection) and particle trapping times (MRMT model). The combined model displays two distinct time regimes. An intermediate regime, in which the solute breakthrough is dominated by the particle transit times in the mobile zones, and a late time regime that is governed by the distribution of particle trapping times in immobile zones. These radial CTRW formulations allow for the identification of heterogeneous advection and mobile-immobile processes as drivers of anomalous transport, under conditions relevant for field tracer
Lake Michigan Mass Balance Project (LMMBP) was initiated to directly support the development of a lakewide management plan (LaMP) for Lake Michigan. A mass balance modeling approach is proposed for the project to addrss the realtionship between sources of toxic chemicals and thei...
NASA Astrophysics Data System (ADS)
Bulmer, M. H.
1996-03-01
Evidence for slope failures exists on Mars, the Moon, Earth and Venus, but the processes involved in the transport and emplacement of large mass movements (> 10^6 m^3) remain poorly understood. The majority of models proposed to explain the long travel distances and low coefficients of friction of large mass movements are based on the concept that debris were fluidized either by internally or externally derived processes. The mass movements G1 and G2 with the longest run-outs on Venus are of particular interest since they are large and appear to have been highly mobile, tending to travel further for a given vertical drop than mass movements on Earth, Mars and the Moon. This mobility may be explained if a fluidizing agent or lubricant enhanced the locomotion of the debris, but in the absence of water on Venus another medium must be postulated. Likely influences and controls on the transport and emplacement of debris masses on Venus can be divided into those resulting from the geological and geomorphological conditions and those that result form environmental conditions. Having examined the geological and geomorphological influences on the transport and emplacement of debris masses on Venus it appears that neither the nature of the rock mass, the site of the slope failures, nor its traveled path can adequately account for the tendency for mass movements on Venus to travel further for a given vertical drop than mass movements on the other terrestrial planets. The effects of atmospheric conditions on Venus seem likely to be the important factor in explaining the apparent mobility of large rock masses over the surface of the planet.
New Satellite Laser Ranging TRF and EOP Series for Mass Transport Studies in the Earth System
NASA Astrophysics Data System (ADS)
Pavlis, E. C.
2001-12-01
The new millennium has started on the right note for geodesy. We finally see a series of gravity mapping missions materialize. What now becomes important is that well-established geodetic techniques rise to the challenge of validating and complementing the data these new missions will deliver. An area where this is likely to be important is the temporal variations in the zonal gravitational field and its very low degree and order components in general. Satellite laser ranging (SLR) has for a long time monitored the continuous redistribution of mass within the Earth system through concomitant changes in the Stokes' coefficients of the terrestrial gravity field. Secular changes in J2 due to post-glacial relaxation have been observed since many years and similar changes in J3, J4 J5, etc. are attributed to changes in the ice sheets of Greenland and Antarctica. Seasonal changes in these coefficients have also been closely correlated with mass transfer in the atmosphere and oceans. JCET's latest analysis of the 1993-present SLR data set from LAGEOS and LAGEOS 2 data for the IERS (International Earth Rotation Service) Terrestrial Reference Frame (ITRF) development, includes the weekly monitoring of such compound changes in the low degree and order harmonics. This latest solution (2001) incorporates several important changes in the modeling of SLR data with resulting improvements in the geophysical products. Along with the static parameters of the TRF we have determined a time series of variations of its origin with respect to the center of mass of the Earth system (geocenter). These estimates provide a measure of the total motion due to all sources of mass transport within the Earth system and can be used to either complement the estimates from the future missions or to validate them through comparisons with their estimates for the same quantities. The data were reduced using NASA Goddard's GEODYN/SOLVE II software, resulting to a final RMS error of ~8 mm - close to the
Fast multigrid solution of the advection problem with closed characteristics
Yavneh, I.; Venner, C.H.; Brandt, A.
1996-12-31
The numerical solution of the advection-diffusion problem in the inviscid limit with closed characteristics is studied as a prelude to an efficient high Reynolds-number flow solver. It is demonstrated by a heuristic analysis and numerical calculations that using upstream discretization with downstream relaxation-ordering and appropriate residual weighting in a simple multigrid V cycle produces an efficient solution process. We also derive upstream finite-difference approximations to the advection operator, whose truncation terms approximate {open_quotes}physical{close_quotes} (Laplacian) viscosity, thus avoiding spurious solutions to the homogeneous problem when the artificial diffusivity dominates the physical viscosity.
Quigg, Chris
2007-12-05
In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.
Mass Influx of Cosmic Dust Estimated From Vertical Transport of Meteoric Metals
NASA Astrophysics Data System (ADS)
Liu, Alan Z.; Guo, Yafang; Gardner, Chester S.
2016-04-01
The mesospheric metal layers are formed by the vaporization of high-speed cosmic dust particles in the lower thermosphere and upper mesosphere. The vaporized atoms and ions are transported downward by waves and turbulence to chemical sinks below 85 km, where they form stable compounds. These compounds condense onto meteoric smoke particles and are then transported to the winter pole where they eventually settle onto the surface. The downward fluxes of the metal atoms are directly related to their meteoric influxes and chemical loss rates. In this paper we use Doppler lidar measurements of Na and Fe fluxes made by the University of Illinois and University of Colorado groups, and a chemical ablation model (CABMOD) developed at the University of Leeds, to constrain the velocity/mass distribution of the meteoroids entering the atmosphere and to derive an improved estimate for the global influx of cosmic dust. We find that the particles responsible for injecting a large fraction of the ablated material into the Earth's upper atmosphere, enter at relatively slow speeds and originate primarily from the Jupiter Family of Comets. The global mean Na influx is 21,500±1,100 atoms/cm2/s, which equals 372±18 kg/d for the global input of Na vapor and 186±24 t/d for the global influx of cosmic dust. The global mean Fe influx is 131,000±36,000 atoms/cm2/s, which equals 5.5±1.5 t/d for the global input of Na vapor.
Jobson, Harvey E.; Keefer, Thomas N.
1979-01-01
A coupled flow-temperature model has been developed and verified for a 27.9-km reach of the Chattahoochee River between Buford Dam and Norcross, Ga. Flow in this reach of the Chattahoochee is continuous but highly regulated by Buford Dam, a flood-control and hydroelectric facility located near Buford, Ga. Calibration and verification utilized two sets of data collected under highly unsteady discharge conditions. Existing solution techniques, with certain minor improvements, were applied to verify the existing technology of flow and transport modeling. The linear, implicit finite-difference flow model was calibrated by use of a depth profile obtained at steady low flow and unsteady flow data obtained in March 1976. During the calibration period, the model was generally able to reproduce observed stages to within 0.15 m and discharges at less than 100 m 3 /s, to within 5 percent. Peak discharges of about 200 m 3 /s were under-estimated by about 20 percent. During the verification period, October 1975, the flow model reproduced observed stage changes to within about 0.15 m, and its timing and over-all performance was considered to be very good. Dye was added to the upstream end of the river reach at a constant rate while the river flow was highly unsteady. The numerical solution of either the conservative or nonconservative form of the mass-transport equation did an excellent job of simulating the observed concentrations of dye in the river. The temperature model was capable of predicting temperature changes through this reach of as large as 5.8?C with a RMS (root-mean-square) error of 0.32?C in October 1975 and 0.20?C in March 1976. Hydropulsation has a significant effect on the water temperature below Buford Dam. These effects are very complicated because they are quite dependent on the timing of the release with respect to both the time of day and past releases.
Performance Analysis of high-order remap-type advection scheme on icosahedral-hexagonal grid
NASA Astrophysics Data System (ADS)
Mittal, Rashmi; Dubey, Sarvesh; Saxena, Vaibhav; Meurdesoif, Yann
2014-05-01
A comparative performance analysis on computational cost of second order advection schemes FF-CSLAM (Flux form conservative semi-Lagrangian multi-tracer transport scheme) and it's two simplifications on Icosahedral grid has been presented. Tracer transport is one of the main building blocks in atmospheric models and hence their performance greatly determines the overall performance of the model. FF-CSLAM falls in the category of arbitrary Lagrangian Eulerian (ALE) scheme. It exploits the finite volume formulation and therefore it is inherently conservative. Flux-area through edges are approximated with great circle arcs in an upwind fashion. Bi-quadratic sub-grid scale reconstructions using weighted least-squares method is employed to approximate trace field. Area integrals on the overlapped region of flux-area and static Eulerian meshes are evaluated via line-integrals. A brief description of implementation of FF-CSLAM on icosahedral -hexagonal meshes along with and its numerical accuracy in terms of standard test cases will be presented. A comparative analysis of the computational overhead is necessary to assess the suitability of FF-CSLAM for massively parallel and multi-threading computer architectures in comparison to other advection schemes implemented on icosahedral grids. The main focus of this work is to present the implementation of the shared memory parallelization and to describe the memory access pattern of the numerical scheme. FF-CSLAM is a remap-type advection scheme, thus extra calculation are done in comparison to the other advection schemes. The additional computations are associated with the search required to find the overlap area between the area swept through the edge and the underlining grid. But the experiments shows that the associated computational overhead is minimal for multi-tracer transport. It will be shown that for the Courant Number less than one, FF-CSLAM, the computations are not expensive. Since the grid cells are arranged in
Schwartz, S.E.
1988-10-01
Although it has been recognized for some time that the rate of reactive uptake of gases in cloudwater can depend on the value of the mass-accommodation coefficient (..cap alpha..) describing interfacial mass transport (MT), definitive evaluation of such rates is only now becoming possible with the availability of measurements of ..cap alpha.. for gases of atmospheric interest at air-water interfaces. Examination of MT limitation to the rate of in-cloud aqueous-phase oxidation of SO/sub 2/ by O/sub 3/ and H/sub 2/O/sub 2/ shows that despite the low value of ..cap alpha../sub O3/ (5 /times/ 10/sup /minus/4/), interfacial MT of this species is not limiting under essentially all conditions of interest; the high values of ..cap alpha.. for SO/sub 2/ (greater than or equal to 0.2) and H/sub 2/O/sub 2/ (greater than or equal to 0.08) indicate no interfacial MT limitation for these species also. Although gas- and aqueous-phase MT can be limiting under certain extremes of conditions, treating the system as under chemical kinetic control is generally an excellent approximation. Interfacial MT limitation also is found not to hinder the rate of H/sub 2/O/sub 2/ formation by aqueous-phase disproportionation of HO/sub 2/. Finally, the rapid uptake of N/sub 2/O/sub 5/ by cloud droplets implies that the yield of aqueous HNO/sub 3/ from in-cloud gas-phase oxidation of NO/sub 2/by O/sub 3/ can be substantial even under daytime conditions. This report consists of copies of viewgraphs prepared for this presentation.
Wolf, S.C.
1970-01-01
southward except near Monterey Canyon which acts as a physiographic barrier and the extreme southern end of the bay where currents are non persistent. Some sediments are also transported offshore by rip currents and other agencies and deposited in deeper, quieter waters. Supply of sediments to the canyon head results in over-filling and steepening with subsequent mass movement of sediments seaward followed by deposition in channels and on the broad deep sea fan. ?? 1970.
Zhou, Jianzhong; Song, Lixiang; Kursan, Suncana; Liu, Yi
2015-05-01
A two-dimensional coupled water quality model is developed for modeling the flow-mass transport in shallow water. To simulate shallow flows on complex topography with wetting and drying, an unstructured grid, well-balanced, finite volume algorithm is proposed for numerical resolution of a modified formulation of two-dimensional shallow water equations. The slope-limited linear reconstruction method is used to achieve second-order accuracy in space. The algorithm adopts a HLLC-based integrated solver to compute the flow and mass transport fluxes simultaneously, and uses Hancock's predictor-corrector scheme for efficient time stepping as well as second-order temporal accuracy. The continuity and momentum equations are updated in both wet and dry cells. A new hybrid method, which can preserve the well-balanced property of the algorithm for simulations involving flooding and recession, is proposed for bed slope terms approximation. The effectiveness and robustness of the proposed algorithm are validated by the reasonable good agreement between numerical and reference results of several benchmark test cases. Results show that the proposed coupled flow-mass transport model can simulate complex flows and mass transport in shallow water.
Zhou, Jianzhong; Song, Lixiang; Kursan, Suncana; Liu, Yi
2015-05-01
A two-dimensional coupled water quality model is developed for modeling the flow-mass transport in shallow water. To simulate shallow flows on complex topography with wetting and drying, an unstructured grid, well-balanced, finite volume algorithm is proposed for numerical resolution of a modified formulation of two-dimensional shallow water equations. The slope-limited linear reconstruction method is used to achieve second-order accuracy in space. The algorithm adopts a HLLC-based integrated solver to compute the flow and mass transport fluxes simultaneously, and uses Hancock's predictor-corrector scheme for efficient time stepping as well as second-order temporal accuracy. The continuity and momentum equations are updated in both wet and dry cells. A new hybrid method, which can preserve the well-balanced property of the algorithm for simulations involving flooding and recession, is proposed for bed slope terms approximation. The effectiveness and robustness of the proposed algorithm are validated by the reasonable good agreement between numerical and reference results of several benchmark test cases. Results show that the proposed coupled flow-mass transport model can simulate complex flows and mass transport in shallow water. PMID:25686488
Invasions in heterogeneous habitats in the presence of advection.
Vergni, Davide; Iannaccone, Sandro; Berti, Stefano; Cencini, Massimo
2012-05-21
We investigate invasions from a biological reservoir to an initially empty, heterogeneous habitat in the presence of advection. The habitat consists of a periodic alternation of favorable and unfavorable patches. In the latter the population dies at fixed rate. In the former it grows either with the logistic or with an Allee effect type dynamics, where the population has to overcome a threshold to grow. We study the conditions for successful invasions and the speed of the invasion process, which is numerically and analytically investigated in several limits. Generically advection enhances the downstream invasion speed but decreases the population size of the invading species, and can even inhibit the invasion process. Remarkably, however, the rate of population increase, which quantifies the invasion efficiency, is maximized by an optimal advection velocity. In models with Allee effect, differently from the logistic case, above a critical unfavorable patch size the population localizes in a favorable patch, being unable to invade the habitat. However, we show that advection, when intense enough, may activate the invasion process.
NASA Astrophysics Data System (ADS)
Sawyer, Derek E.; Flemings, Peter B.; Dugan, Brandon; Germaine, John T.
2009-10-01
Clay-rich mass transport deposits (MTDs) in the Ursa Basin, Gulf of Mexico, record failures that mobilized along extensional failure planes and transformed into long runout flows. Failure proceeded retrogressively: scarp formation unloaded adjacent sediment causing extensional failure that drove successive scarp formation updip. This model is developed from three-dimensional seismic reflection data, core and log data from Integrated Ocean Drilling Project (IODP) Expedition 308, and triaxial shear experiments. MTDs are imaged seismically as low-amplitude zones above continuous, grooved, high-amplitude basal reflections and are characterized by two seismic facies. A Chaotic facies typifies the downdip interior, and a Discontinuous Stratified facies typifies the headwalls/sidewalls. The Chaotic facies contains discontinuous, high-amplitude reflections that correspond to flow-like features in amplitude maps: it has higher bulk density, resistivity, and shear strength, than bounding sediment. In contrast, the Discontinuous Stratified facies contains relatively dim reflections that abut against intact pinnacles of parallel-stratified reflections: it has only slightly higher bulk density, resistivity, and shear strength than bounding sediment, and deformation is limited. In both facies, densification is greatest at the base, resulting in a strong basal reflection. Undrained shear tests document strain weakening (sensitivity = 3). We estimate that failure at 30 meters below seafloor will occur when overpressure = 70% of the hydrostatic effective stress: under these conditions soil will liquefy and result in long runout flows.
Numerical simulation of heat and mass transport during space crystal growth with MEPHISTO
NASA Technical Reports Server (NTRS)
Yao, Minwu; Raman, Raghu; Degroh, Henry C., III
1995-01-01
The MEPHISTO space experiments are collaborative United States and French investigations aimed at understanding the fundamentals of crystal growth. Microgravity experiments were conducted aboard the USMP-1 and -2 missions on STS-52 and 62 in October 1992 and March 1994 respectively. MEPHISTO is a French designed and built Bridgman type furnace which uses the Seebeck technique to monitor the solid/liquid interface temperature and Peltier pulsing to mark the location and shape of the solid/liquid interface. In this paper the Bridgman growth of Sn-Bi and Bi-Sn under terrestrial and microgravity conditions is modeled using the finite element code, FIDAP*. The numerical model considers fully coupled heat and mass transport, fluid motion and solid/liquid phase changes in the crystal growth process. The primary goals of this work are: to provide a quantitative study of the thermal buoyancy-induced convection in the melt for the two flight experiments; to compare the vertical and horizontal growth configurations and systematically evaluate the effects of various gravity levels on the solute segregation. Numerical results of the vertical and horizontal Bridgman growth configurations are presented.
NASA Technical Reports Server (NTRS)
Klaus, David M.; Benoit, Michael R.; Nelson, Emily S.; Hammond, Timmothy G.
2004-01-01
Conducting biological research in space requires consideration be given to isolating appropriate control parameters. For in vitro cell cultures, numerous environmental factors can adversely affect data interpretation. A biological response attributed to microgravity can, in theory, be explicitly correlated to a specific lack of weight or gravity-driven motion occurring to, within or around a cell. Weight can be broken down to include the formation of hydrostatic gradients, structural load (stress) or physical deformation (strain). Gravitationally induced motion within or near individual cells in a fluid includes sedimentation (or buoyancy) of the cell and associated shear forces, displacement of cytoskeleton or organelles, and factors associated with intra- or extracellular mass transport. Finally, and of particular importance for cell culture experiments, the collective effects of gravity must be considered for the overall system consisting of the cells, their environment and the device in which they are contained. This does not, however, rule out other confounding variables such as launch acceleration, on orbit vibration, transient acceleration impulses or radiation, which can be isolated using onboard centrifuges or vibration isolation techniques. A framework is offered for characterizing specific cause-and-effect relationships for gravity-dependent responses as a function of the above parameters.
Thermodynamics and Mass Transport in Multicomponent, Multiphase H2O Systems of Planetary Interest
NASA Astrophysics Data System (ADS)
Lu, Xinli; Kieffer, Susan W.
2009-05-01
Heat and mass transport in low-temperature, low-pressure H2O systems are important processes on Earth, and on a number of planets and moons in the Solar System. In most occurrences, these systems will contain other components, the so-called noncondensible gases, such as CO2, CO, SO2, CH4, and N2. The presence of the noncondensible components can greatly alter the thermodynamic properties of the phases and their flow properties as they move in and on the planets. We review various forms of phase diagrams that give information about pressure-temperature-volume-entropy-enthalpy-composition conditions in these complex systems. Fluid dynamic models must be coupled to the thermodynamics to accurately describe flow in gas-driven liquid and solid systems. The concepts are illustrated in detail by considering flow and flow instabilities such as geysering in modern geothermal systems on Earth, paleofluid systems on Mars, and cryogenic ice-gas systems on Mars and Enceladus. We emphasize that consideration of single-component end-member systems often leads to conclusions that exclude many qualitatively and quantitatively important phenomena.
Aqueous gradient by balancing diffusive and convective mass transport (Conference Presentation)
NASA Astrophysics Data System (ADS)
Habhab, Mohammed-Baker I.; Ismail, Tania; Lo, Joe F.; Haque, Arefa
2016-03-01
In wounds, cells secret biomolecules such as vascular endothelial growth factor (VEGF), a protein that controls many processes in healing. VEGF protein is expressed in a gradient in tissue, and its shape will be affected by the tissue injury sustained during wounding. In order to study the responses of keratinocyte cell migration to VEGF gradients and the geometric factors on wound healing, we designed a microfluidic gradient device that can generate large area gradients (1.5 cm in diameter) capable of mimicking arbitrary wound shapes. Microfluidic devices offer novel techniques to address biological and biomedical issues. Different from other gradient microfluidics, our device balances diffusion of biomolecules versus the convective clearance by a buffer flow on the opposite ends of the gradient. This allows us to create a large area gradient within shorter time scales by actively driving mass transport. In addition, the microfluidic device makes use of a porous filter membrane to create this balance as well as to deliver the resulting gradient to a culture of cells. The culture of cells are seeded above the gradient in a gasket chamber. However, Keratinocytes do not migrate effectively on filter paper. Therefore, in order to improve the motility of cells on the surface, we coated the filter paper with a 30m thick layer of gelatin type B. after observation under the microscope we found that the gelatin coated sample showed cells with more spread out morphology, with 97% viability, suggesting better adhesion than the non-coated sample.
Can a reduction in mass transport occur at invariant segmental time?
NASA Astrophysics Data System (ADS)
Napolitano, Simone; Sferrazza, Michele
2015-03-01
The glassy dynamics of polymer melts adsorbed onto solid substrates shows a peculiar confinement effect: a severe reduction in mass transport occurs without a corresponding increase in segmental relaxation time. This phenomenon provides a ``negative violation'' of the Stokes-Einstein (SE) relation, not observed in bulk melts or confined water. Explaining those findings in analogy to the large drop of thermal expansion reported in polymers under 1D confinement, we considered the presence of an interfacial dead layer where tracer diffusivity assumes negligible values. To verify this hypothesis, we performed an extensive investigation of the diffusion of styrene oligomers, acting as tracers, into matrices of high molecular weight polystyrene, irreversibly adsorbed onto aluminum oxide. We demonstrate that the reduced interfacial diffusion is due to larger residence times of the tracers inside the dead layer, tDL. In particular, we show that tDL is directly proportional to the amount of irreversibly adsorbed monomers, a quantity limiting the available space for diffusion. We thus discuss of a dynamic dead layer evolving within the adsorbed layer, and of its role on the dynamics of glassy polymers under confinement and the ``negative violation'' the SE relation.
Ring waves as a mass transport mechanism in air-driven core-annular flows.
Camassa, Roberto; Forest, M Gregory; Lee, Long; Ogrosky, H Reed; Olander, Jeffrey
2012-12-01
Air-driven core-annular fluid flows occur in many situations, from lung airways to engineering applications. Here we study, experimentally and theoretically, flows where a viscous liquid film lining the inside of a tube is forced upwards against gravity by turbulent airflow up the center of the tube. We present results on the thickness and mean speed of the film and properties of the interfacial waves that develop from an instability of the air-liquid interface. We derive a long-wave asymptotic model and compare properties of its solutions with those of the experiments. Traveling wave solutions of this long-wave model exhibit evidence of different mass transport regimes: Past a certain threshold, sufficiently large-amplitude waves begin to trap cores of fluid which propagate upward at wave speeds. This theoretical result is then confirmed by a second set of experiments that show evidence of ring waves of annular fluid propagating over the underlying creeping flow. By tuning the parameters of the experiments, the strength of this phenomenon can be adjusted in a way that is predicted qualitatively by the model.
Klaus, David M; Benoit, Michael R; Nelson, Emily S; Hammond, Timmothy G
2004-03-01
Conducting biological research in space requires consideration be given to isolating appropriate control parameters. For in vitro cell cultures, numerous environmental factors can adversely affect data interpretation. A biological response attributed to microgravity can, in theory, be explicitly correlated to a specific lack of weight or gravity-driven motion occurring to, within or around a cell. Weight can be broken down to include the formation of hydrostatic gradients, structural load (stress) or physical deformation (strain). Gravitationally induced motion within or near individual cells in a fluid includes sedimentation (or buoyancy) of the cell and associated shear forces, displacement of cytoskeleton or organelles, and factors associated with intra- or extracellular mass transport. Finally, and of particular importance for cell culture experiments, the collective effects of gravity must be considered for the overall system consisting of the cells, their environment and the device in which they are contained. This does not, however, rule out other confounding variables such as launch acceleration, on orbit vibration, transient acceleration impulses or radiation, which can be isolated using onboard centrifuges or vibration isolation techniques. A framework is offered for characterizing specific cause-and-effect relationships for gravity-dependent responses as a function of the above parameters.
Implementation of a Semi-Lagrangian scheme for water vapour and tracer advection in RegCM4
NASA Astrophysics Data System (ADS)
Tefera Diro, Gulilat; Tompkins, Adrian; Giorgi, Filippo; Bonaventura, Luca
2013-04-01
A semi-Lagrangian approach is introduced in the latest version of the ICTP regional climate model (RegCM4) for water vapor and tracer advection. A 'quasi' cubic interpolation and McGregor's third order accurate trajectory calculation are used in the advection scheme. The modified scheme is evaluated on idealized as well as realistic case studies and its results are compared against those of the Eulerian scheme originally employed in RegCM4. In the idealized test cases the semi-Lagrangian scheme appears to be superior to the Eulerian scheme in terms of the dissipative and dispersive errors, especially when large gradients are present in the advected quantity. Two realistic cases of meso-scale phenomena over the European domain were also tested in a short range mode for specific humidity transport. In both cases, the semi-Lagrangian scheme has captured better the detailed structure and improved the overall pattern of the vertically integrated humidity field. In the present preliminary implementation, the scheme is more expensive than the Eulerian one. This is because the same time step is used for tracer advection as the explicit time discretization employed by the dynamical core. However, greater computational gains are expected as the number of tracers considered increases, for instance when the gas phase chemistry is switched on.
Stevens, D.E.; Bretherton, S.
1996-12-01
This paper presents a new forward-in-time advection method for nearly incompressible flow, MU, and its application to an adaptive multilevel flow solver for atmospheric flows. MU is a modification of Leonard et al.`s UTOPIA scheme. MU, like UTOPIA, is based on third-order accurate semi-Lagrangian multidimensional upwinding for constant velocity flows. for varying velocity fields, MU is a second-order conservative method. MU has greater stability and accuracy than UTOPIA and naturally decomposes into a monotone low-order method and a higher-order accurate correction for use with flux limiting. Its stability and accuracy make it a computationally efficient alternative to current finite-difference advection methods. We present a fully second-order accurate flow solver for the anelastic equations, a prototypical low Mach number flow. The flow solver is based on MU which is used for both momentum and scalar transport equations. This flow solver can also be implemented with any forward-in-time advection scheme. The multilevel flow solver conserves discrete global integrals of advected quantities and includes adaptive mesh refinements. Its second-order accuracy is verified using a nonlinear energy conservation integral for the anelastic equations. For a typical geophysical problem in which the flow is most rapidly varying in a small part of the domain, the multilevel flow solver achieves global accuracy comparable to uniform-resolution simulation for 10% of the computational cost. 36 refs., 10 figs.
NASA Astrophysics Data System (ADS)
Bateman, Glenn; Kritz, Arnold H.; Parail, Vassili V.; Cordey, J. G.
1999-12-01
The effect of isotopic mass on heat and particle transport in Joint European Torus (JET) [P.-H. Rebut et al., Nucl. Fusion 25, 1011 (1985)] plasma discharges is studied using the Multi-Mode model in the BALDUR predictive transport code [Bateman et al., Phys. Plasmas 5, 1793 (1998)]. Temperature and density profiles from these simulations generally agree with the experimentally measured profiles for high-mode JET discharges with Edge Localized Modes in hydrogen, deuterium, and tritium discharges. It is surprising that a purely gyro-Bohm transport model, used in these simulations, correctly predicts the experimentally observed improvement in confinement as the isotope mass is increased—given the fact that gyro-Bohm diffusion coefficients increase with isotope mass when the shapes of all the plasma profiles are held fixed. However, in the JET experiment, it was found that the electron and ion temperature at the top of the edge pedestal increases systematically as the isotope mass in increased (J. G. Cordey et al., Report No. JET-P (98)53, 1998). The numerical simulations reported here show that this increase in the edge temperatures and subsequent broadening of the temperature profiles account for the improvement in confinement as the isotope mass is increased.
Toxic Alexandrium blooms in the western Gulf of Maine: The plume advection hypothesis revisited
Anderson, D.M.; Keafer, B.A.; Geyer, W.R.; Signell, R.P.; Loder, T.C.
2005-01-01
The plume advection hypothesis links blooms of the toxic dinoflagellate Alexandrium fundyense in the western Gulf of Maine (GOM) to a buoyant plume derived from river outflows. This hypothesis was examined with cruise and moored-instrument observations in 1993 when levels of paralytic shellfish poisoning (PSP) toxins were high, and in 1994 when toxicity was low. A coupled physical-biological model simulated hydrography and A. fundyense distributions. Initial A. fundyense populations were restricted to low-salinity nearshore waters near Casco Bay, but also occurred in higher salinity waters along the plume boundary. This suggests two sources of cells - those from shallow-water cyst populations and those transported to shore from offshore blooms in the eastern segment of the Maine coastal current (EMCC). Observations confirm the role of the plume in A. fundyense transport and growth. Downwelling-favorable winds in 1993 transported the plume and its cells rapidly alongshore, enhancing toxicity and propagating PSP to the south. In 1994, sustained upwelling moved the plume offshore, resulting in low toxicity in intertidal shellfish. A. fundyense blooms were likely nutrient limited, leading to low growth rates and moderate cell abundances. These observations and mechanisms were reproduced by coupled physical-biological model simulations. The plume advection hypothesis provides a viable explanation for outbreaks of PSP in the western GOM, but should be refined to include two sources for cells that populate the plume and two major pathways for transport: one within the low-salinity plume and another where A. fundyense cells originating in the EMCC are transported along the outer boundary of the plume front with the western segment of the Maine coastal current.
Huang, Y.H.; Saiers, J.E.; Harvey, J.W.; Noe, G.B.; Mylon, S.
2008-01-01
The movement of particulate matter within wetland surface waters affects nutrient cycling, contaminant mobility, and the evolution of the wetland landscape. Despite the importance of particle transport in influencing wetland form and function, there are few data sets that illuminate, in a quantitative way, the transport behavior of particulate matter within surface waters containing emergent vegetation. We report observations from experiments on the transport of 1 ??m latex microspheres at a wetland field site located in Water Conservation Area 3A of the Florida Everglades. The experiments involved line source injections of particles inside two 4.8-m-long surface water flumes constructed within a transition zone between an Eleocharis slough and Cladium jamaicense ridge and within a Cladium jamaicense ridge. We compared the measurements of particle transport to calculations of two-dimensional advection-dispersion model that accounted for a linear increase in water velocities with elevation above the ground surface. The results of this analysis revealed that particle spreading by longitudinal and vertical dispersion was substantially greater in the ridge than within the transition zone and that particle capture by aquatic vegetation lowered surface water particle concentrations and, at least for the timescale of our experiments, could be represented as an irreversible, first-order kinetics process. We found generally good agreement between our field-based estimates of particle dispersion and water velocity and estimates determined from published theory, suggesting that the advective-dispersive transport of particulate matter within complex wetland environments can be approximated on the basis of measurable properties of the flow and aquatic vegetation. Copyright 2008 by the American Geophysical Union.
Pollutant advective spreading in beach sand exposed to high-energy tides
NASA Astrophysics Data System (ADS)
Itugha, Okuroghoboye D.; Chen, Daoyi; Guo, Yakun
2016-11-01
This paper presents field measurements in which dye solute was injected into coastal sand to investigate contaminant advection in intertidal beach sand. The measurements show the pathways of a contaminated plume in the unsaturated zone during both the flood and ebb tides. A prescribed amount of dye tracer solution was directly injected through the topsoil, with average porosity 0.3521 ± 0.01, at predetermined locations of the River Mersey's outer estuarial beach during ebb-tide. The injected dye was monitored, sampled and photographed over several tidal cycles. The distinctive features of the plume (full two dimensional cross-sections), sediments and water-table depth were sampled in-situ, close to the injection point (differing from previous contaminant monitoring tests in aquifers). The advective movement is attributed to tidal impact which is different from contaminant transport in aquifers. The experimental results show that plumes have significantly large spatial variability, diverging upwards and converging downwards, with a conical geometric shape which is different from the usual spherical/elliptical shape reported in literature. The mean vertical motion of the plume reaches three times the top-width within ten tidal cycles, exceeding the narrow bottom-width by a factor of order 2. The observed transport features of the plume within the beach sand have significant relevance to saltwater intrusion, surface water and groundwater quality. The field observations are unique and can serve as a valuable benchmark database for relevant numerical studies.
Advection of surface-derived organic carbon fuels microbial reduction in Bangladesh groundwater
NASA Astrophysics Data System (ADS)
Mailloux, Brian J.; Trembath-Reichert, Elizabeth; Cheung, Jennifer; Watson, Marlena; Stute, Martin; Freyer, Greg A.; Ferguson, Andrew S.; Matin Ahmed, Kazi; Jahangir Alam, Md.; Buchholz, Bruce A.; Thomas, James; Layton, Alice C.; Zheng, Yan; Bostick, Benjamin C.; van Geen, Alexander
2013-04-01
Chronic exposure to arsenic (As) by drinking shallow groundwater causes widespread disease in Bangladesh and neighboring countries. The release of As naturally present in sediment to groundwater has been linked to the reductive dissolution of iron oxides coupled to the microbial respiration of organic carbon (OC). The source of OC driving this microbial reduction-carbon deposited with the sediments or exogenous carbon transported by groundwater-is still debated despite its importance in regulating aquifer redox status and groundwater As levels. Here, we used the radiocarbon (14C) signature of microbial DNA isolated from groundwater samples to determine the relative importance of surface and sediment-derived OC. Three DNA samples collected from the shallow, high-As aquifer and one sample from the underlying, low-As aquifer were consistently younger than the total sediment carbon, by as much as several thousand years. This difference and the dominance of heterotrophic microorganisms implies that younger, surface-derived OC is advected within the aquifer, albeit more slowly than groundwater, and represents a critical pool of OC for aquifer microbial communities. The vertical profile shows that downward transport of dissolved OC is occurring on anthropogenic timescales, but bomb 14C-labeled dissolved OC has not yet accumulated in DNA and is not fueling reduction. These results indicate that advected OC controls aquifer redox status and confirm that As release is a natural process that predates human perturbations to groundwater flow. Anthropogenic perturbations, however, could affect groundwater redox conditions and As levels in the future.
Mass-conserving tracer transport modelling on a reduced latitude-longitude grid with NIES-TM
NASA Astrophysics Data System (ADS)
Belikov, D.; Maksyutov, S.; Miyasaka, T.; Saeki, T.; Zhuravlev, R.; Kiryushov, B.
2011-03-01
The need to perform long-term simulations with reasonable accuracy has led to the development of mass-conservative and efficient numerical methods for solving the transport equation in forward and inverse models. We designed and implemented a flux-form (Eulerian) tracer transport algorithm in the National Institute for Environmental Studies Transport Model (NIES TM), which is used for simulating diurnal and synoptic-scale variations of tropospheric long-lived constituents, as well as their seasonal and inter-annual v