Science.gov

Sample records for advective mass transport

  1. Efficient mass transport by optical advection

    PubMed Central

    Kajorndejnukul, Veerachart; Sukhov, Sergey; Dogariu, Aristide

    2015-01-01

    Advection is critical for efficient mass transport. For instance, bare diffusion cannot explain the spatial and temporal scales of some of the cellular processes. The regulation of intracellular functions is strongly influenced by the transport of mass at low Reynolds numbers where viscous drag dominates inertia. Mimicking the efficacy and specificity of the cellular machinery has been a long time pursuit and, due to inherent flexibility, optical manipulation is of particular interest. However, optical forces are relatively small and cannot significantly modify diffusion properties. Here we show that the effectiveness of microparticle transport can be dramatically enhanced by recycling the optical energy through an effective optical advection process. We demonstrate theoretically and experimentally that this new advection mechanism permits an efficient control of collective and directional mass transport in colloidal systems. The cooperative long-range interaction between large numbers of particles can be optically manipulated to create complex flow patterns, enabling efficient and tunable transport in microfluidic lab-on-chip platforms. PMID:26440069

  2. Pathways for Advective Transport

    DTIC Science & Technology

    2001-01-19

    the approach is given and an application to the Gulf of Mexico is described where the analysis precisely identifies the boundaries of coherent vortical structures as well as pathways for advective transport.

  3. A mass-conserving advection scheme for offline simulation of scalar transport in coastal ocean models

    NASA Astrophysics Data System (ADS)

    Gillibrand, P. A.; Herzfeld, M.

    2016-05-01

    We present a flux-form semi-Lagrangian (FFSL) advection scheme designed for offline scalar transport simulation with coastal ocean models using curvilinear horizontal coordinates. The scheme conserves mass, overcoming problems of mass conservation typically experienced with offline transport models, and permits long time steps (relative to the Courant number) to be used by the offline model. These attributes make the method attractive for offline simulation of tracers in biogeochemical or sediment transport models using archived flow fields from hydrodynamic models. We describe the FFSL scheme, and test it on two idealised domains and one real domain, the Great Barrier Reef in Australia. For comparison, we also include simulations using a traditional semi-Lagrangian advection scheme for the offline simulations. We compare tracer distributions predicted by the offline FFSL transport scheme with those predicted by the original hydrodynamic model, assess the conservation of mass in all cases and contrast the computational efficiency of the schemes. We find that the FFSL scheme produced very good agreement with the distributions of tracer predicted by the hydrodynamic model, and conserved mass with an error of a fraction of one percent. In terms of computational speed, the FFSL scheme was comparable with the semi-Lagrangian method and an order of magnitude faster than the full hydrodynamic model, even when the latter ran in parallel on multiple cores. The FFSL scheme presented here therefore offers a viable mass-conserving and computationally-efficient alternative to traditional semi-Lagrangian schemes for offline scalar transport simulation in coastal models.

  4. Thermal advection and stratification effects on surface winds and the low level meridional mass transport

    NASA Technical Reports Server (NTRS)

    Levy, Gad; Tiu, Felice S.

    1990-01-01

    Statistical tests are performed on the Seasat scatterometer observations to examine if and to what degree thermal advection and stratification effects manifest themselves in these remotely sensed measurements of mean wind and wind stress over the ocean. On the basis of a two layer baroclinic boundary layer model which is presented, it is shown that the thermal advection and stratification of the entire boundary layer as well as the geostrophic forcing influence the modeled near surface wind and wind stress profiles. Evidence of diurnal variation in the stratification under barotropic conditions is found in the data, with the daytime marine boundary layer being more convective than its nighttime counterpart. The temporal and spacial sampling pattern of the satellite makes it impossible to recover the full diurnal cycle, however. The observed effects of the thermal advection are shown to be statistically significant during the day (and presumed more convective) hours, causing a systematic increase in the poleward transport of mass and heat. The statistical results are in a qualitative agreement with the model simulations and cannot be reproduced in randomized control tests.

  5. High-resolution two dimensional advective transport

    USGS Publications Warehouse

    Smith, P.E.; Larock, B.E.

    1989-01-01

    The paper describes a two-dimensional high-resolution scheme for advective transport that is based on a Eulerian-Lagrangian method with a flux limiter. The scheme is applied to the problem of pure-advection of a rotated Gaussian hill and shown to preserve the monotonicity property of the governing conservation law.

  6. A convexity preserving scheme for conservative advection transport

    NASA Astrophysics Data System (ADS)

    Xiao, Feng; Peng, Xindong

    2004-08-01

    A simple and practical scheme for advection transport equation is presented. The scheme, namely piecewise rational method (PRM), is a variant of the existing piecewise parabolic method (PPM) of Colella and Woodward (1984). Instead of the parabolic function, a rational function is used for the reconstruction. Making use of the convexity preserving nature of the rational function enables us to obtain oscillation-less numerical solutions, but avoids the adjustments of the cell-interface values to enforce the monotonicity in PPM. The PRM is very simple and computationally efficient. Our numerical results show that PRM is competitive to the PPM in many aspects, such as numerical accuracy and shape-preserving property.

  7. Assessment of advective porewater movement affecting mass transfer of hydrophobic organic contaminants in marine intertidal sediment.

    PubMed

    Cho, Yeo-Myoung; Werner, David; Moffett, Kevan B; Luthy, Richard G

    2010-08-01

    Advective porewater movement and molecular diffusion are important factors affecting the mass transfer of hydrophobic organic compounds (HOCs) in marsh and mudflat sediments. This study assessed porewater movement in an intertidal mudflat in South Basin adjacent to Hunters Point Shipyard, San Francisco, CA, where a pilot-scale test of sorbent amendment assessed the in situ stabilization of polychlorinated biphenyls (PCBs). To quantify advective porewater movement within the top 0-60 cm sediment layer, we used temperature as a tracer and conducted heat transport analysis using 14-day data from multidepth sediment temperature logging stations and one-dimensional heat transport simulations. The best-fit conditions gave an average Darcy velocity of 3.8cm/d in the downward vertical direction for sorbent-amended sediment with a plausible range of 0 cm/d to 8 cm/d. In a limiting case with no net advection, the best-fit depth-averaged mechanical dispersion coefficient was 2.2x10(-7) m2/s with a range of 0.9x10(-7) m2/s to 5.6x10(-7) m2/s. The Peclet number for PCB mobilization showed that molecular diffusion would control PCB mass transfer from sediment to sorbent particles for the case of uniform distribution of sorbent. However, the advective flow and mechanical dispersion in the test site would significantly benefit the stabilization effect of heterogeneously distributed sorbent by acting to smooth out the heterogeneities and homogenizing pollutant concentrations across the entire bioactive zone. These measurements and modeling techniques on intertidal sediment porewater transport could be useful for the development of more reliable mass transfer models for the prediction of contaminant release within the sediment bed, the movement of HOCs in the intertidal aquatic environment, and in situ sequestration by sorbent addition.

  8. Thermally driven advection for radioxenon transport from an underground nuclear explosion

    NASA Astrophysics Data System (ADS)

    Sun, Yunwei; Carrigan, Charles R.

    2016-05-01

    Barometric pumping is a ubiquitous process resulting in migration of gases in the subsurface that has been studied as the primary mechanism for noble gas transport from an underground nuclear explosion (UNE). However, at early times following a UNE, advection driven by explosion residual heat is relevant to noble gas transport. A rigorous measure is needed for demonstrating how, when, and where advection is important. In this paper three physical processes of uncertain magnitude (oscillatory advection, matrix diffusion, and thermally driven advection) are parameterized by using boundary conditions, system properties, and source term strength. Sobol' sensitivity analysis is conducted to evaluate the importance of all physical processes influencing the xenon signals. This study indicates that thermally driven advection plays a more important role in producing xenon signals than oscillatory advection and matrix diffusion at early times following a UNE, and xenon isotopic ratios are observed to have both time and spatial dependence.

  9. Analytical solution for the advection-dispersion transport equation in layered media

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The advection-dispersion transport equation with first-order decay was solved analytically for multi-layered media using the classic integral transform technique (CITT). The solution procedure used an associated non-self-adjoint advection-diffusion eigenvalue problem that had the same form and coef...

  10. Theory of advection-driven long range biotic transport

    Technology Transfer Automated Retrieval System (TEKTRAN)

    We propose a simple mechanistic model to examine the effects of advective flow on the spread of fungal diseases spread by wind-blown spores. The model is defined by a set of two coupled non-linear partial differential equations for spore densities. One equation describes the long-distance advectiv...

  11. Rigorous upper bounds for fluid and plasma transport due to passive advection

    SciTech Connect

    Krommes, J.A.; Smith, R.A.; Kim, C.B.

    1987-07-01

    The formulation of variational principles for transport due to passive advection is described. A detailed account of the work has been published elsewhere. In the present paper, the motivations, philosophy, and implications of the method are briefly discussed. 15 refs.

  12. AN EXACT PEAK CAPTURING AND OSCILLATION-FREE SCHEME TO SOLVE ADVECTION-DISPERSION TRANSPORT EQUATIONS

    EPA Science Inventory

    An exact peak capturing and essentially oscillation-free (EPCOF) algorithm, consisting of advection-dispersion decoupling, backward method of characteristics, forward node tracking, and adaptive local grid refinement, is developed to solve transport equations. This algorithm repr...

  13. Single-relaxation-time lattice Boltzmann scheme for advection-diffusion problems with large diffusion-coefficient heterogeneities and high-advection transport.

    PubMed

    Perko, Janez; Patel, Ravi A

    2014-05-01

    The paper presents an approach that extends the flexibility of the standard lattice Boltzmann single relaxation time scheme in terms of spatial variation of dissipative terms (e.g., diffusion coefficient) and stability for high Péclet mass transfer problems. Spatial variability of diffusion coefficient in SRT is typically accommodated through the variation of relaxation time during the collision step. This method is effective but cannot deal with large diffusion coefficient variations, which can span over several orders of magnitude in some natural systems. The approach explores an alternative way of dealing with large diffusion coefficient variations in advection-diffusion transport systems by introducing so-called diffusion velocity. The diffusion velocity is essentially an additional convective term that replaces variations in diffusion coefficients vis-à-vis a chosen reference diffusion coefficient which defines the simulation time step. Special attention is paid to the main idea behind the diffusion velocity formulation and its implementation into the lattice Boltzmann framework. Finally, the performance, stability, and accuracy of the diffusion velocity formulation are discussed via several advection-diffusion transport benchmark examples. These examples demonstrate improved stability and flexibility of the proposed scheme with marginal consequences on the numerical performance.

  14. Diffusion related isotopic fractionation effects with one-dimensional advective-dispersive transport.

    PubMed

    Xu, Bruce S; Lollar, Barbara Sherwood; Passeport, Elodie; Sleep, Brent E

    2016-04-15

    Aqueous phase diffusion-related isotope fractionation (DRIF) for carbon isotopes was investigated for common groundwater contaminants in systems in which transport could be considered to be one-dimensional. This paper focuses not only on theoretically observable DRIF effects in these systems but introduces the important concept of constraining "observable" DRIF based on constraints imposed by the scale of measurements in the field, and on standard limits of detection and analytical uncertainty. Specifically, constraints for the detection of DRIF were determined in terms of the diffusive fractionation factor, the initial concentration of contaminants (C0), the method detection limit (MDL) for isotopic analysis, the transport time, and the ratio of the longitudinal mechanical dispersion coefficient to effective molecular diffusion coefficient (Dmech/Deff). The results allow a determination of field conditions under which DRIF may be an important factor in the use of stable carbon isotope measurements for evaluation of contaminant transport and transformation for one-dimensional advective-dispersive transport. This study demonstrates that for diffusion-dominated transport of BTEX, MTBE, and chlorinated ethenes, DRIF effects are only detectable for the smaller molar mass compounds such as vinyl chloride for C0/MDL ratios of 50 or higher. Much larger C0/MDL ratios, corresponding to higher source concentrations or lower detection limits, are necessary for DRIF to be detectable for the higher molar mass compounds. The distance over which DRIF is observable for VC is small (less than 1m) for a relatively young diffusive plume (<100years), and DRIF will not easily be detected by using the conventional sampling approach with "typical" well spacing (at least several meters). With contaminant transport by advection, mechanical dispersion, and molecular diffusion this study suggests that in field sites where Dmech/Deff is larger than 10, DRIF effects will likely not be

  15. Numerical simulation of advective-dispersive multisolute transport with sorption, ion exchange and equilibrium chemistry

    USGS Publications Warehouse

    Lewis, F.M.; Voss, C.I.; Rubin, Jacob

    1986-01-01

    A model was developed that can simulate the effect of certain chemical and sorption reactions simultaneously among solutes involved in advective-dispersive transport through porous media. The model is based on a methodology that utilizes physical-chemical relationships in the development of the basic solute mass-balance equations; however, the form of these equations allows their solution to be obtained by methods that do not depend on the chemical processes. The chemical environment is governed by the condition of local chemical equilibrium, and may be defined either by the linear sorption of a single species and two soluble complexation reactions which also involve that species, or binary ion exchange and one complexation reaction involving a common ion. Partial differential equations that describe solute mass balance entirely in the liquid phase are developed for each tenad (a chemical entity whose total mass is independent of the reaction process) in terms of their total dissolved concentration. These equations are solved numerically in two dimensions through the modification of an existing groundwater flow/transport computer code. (Author 's abstract)

  16. Jet-dominated advective systems of all mass scales

    NASA Astrophysics Data System (ADS)

    Körding, Elmar; Fender, R.

    We show that the radio emission of black hole (BH) and neutron star (NS) X-ray binaries (XRBs) follows the analytical prediction of a jet model where the jet carries a constant fraction of the accretion power. The radio emission can therefore be used as a tracer of the accretion rate. This measure is normalised with efficiently radiating objects. As it is independent of the X-ray fluxes, the measure allows us to compare the accretion rate dependency of the bolometric X-ray lumi- nosity of BHs and NSs. For NSs, it scales linearly with accretion rate while the scaling for BHs is quadratic - as expected for inefficient accretion flows. We find the same behaviour in AGN. This new approach uses the jet power to obtain the accretion rate. Thus, we know both the jet power and the radiated power of an accreting BH. This allows us to show that some accretion power is likely to be advected into the black hole, while the jet power dominates over the bolometric luminosity of a hard state BH.

  17. In situ measurements of advective solute transport in permeable shelf sands

    NASA Astrophysics Data System (ADS)

    Reimers, Clare E.; Stecher, Hilmar A.; Taghon, Gary L.; Fuller, Charlotte M.; Huettel, Markus; Rusch, Antje; Ryckelynck, Natacha; Wild, Christian

    2004-01-01

    Solute transport rates within the uppermost 2 cm of a rippled continental shelf sand deposit, with a mean grain size of 400-500 μm and permeabilities of 2.0-2.4×10 -11 m 2, have been measured in situ by detecting the breakthrough of a pulse of iodide after its injection into the bottom water. These tracer experiments were conducted on the USA Middle Atlantic Bight shelf at a water depth of ˜13 m using a small tethered tripod that carried a close-up video camera, acoustic current meter, motorized 1.5 liter "syringe", and a microprofiling system for positioning and operating a solid-state voltammetric microelectrode. When triggered on shipboard, the syringe delivered a 0.21 M solution of potassium iodide and red dye through five nozzles positioned around and above the buried tip of the voltammetric sensor for 0.65-5 min. Bottom turbulence rapidly mixed and dispersed the tracer, which then was carried into the bed by interfacial water flows associated with ripple topography. The advective downward transport to the sensor tip was timed by a sequence of repetitive voltammetric scans. The distance-averaged vertical velocity, expressed as the depth of the sensor tip in the sand divided by the time to iodide breakthrough, was found to vary from 6 to 53 cm h -1 and generally to decrease with sediment depth. Because of episodic pumping and dispersion associated with the greatest 5% of wave heights and current speeds recorded, some concentration vs. time responses showed evidence of uneven solute migration. For reasons of mass balance, the advective flow field in the surface layers of permeable beds includes regions of water intrusion, horizontal pore-water flow and upwelling which also may explain some of the observed uneven migration. Pore-water advection was also evident in oxygen profiles measured before and after tracer injection with the voltammetric sensor. These profiles showed irregular distributions and oxygen penetration depths of 4-4.5 cm. Sand cores from the

  18. Diffusion or advection? Mass transfer and complex boundary layer landscapes of the brown alga Fucus vesiculosus.

    PubMed

    Lichtenberg, Mads; Nørregaard, Rasmus Dyrmose; Kühl, Michael

    2017-03-01

    The role of hyaline hairs on the thallus of brown algae in the genus Fucus is long debated and several functions have been proposed. We used a novel motorized set-up for two-dimensional and three-dimensional mapping with O2 microsensors to investigate the spatial heterogeneity of the diffusive boundary layer (DBL) and O2 flux around single and multiple tufts of hyaline hairs on the thallus of Fucus vesiculosus. Flow was a major determinant of DBL thickness, where higher flow decreased DBL thickness and increased O2 flux between the algal thallus and the surrounding seawater. However, the topography of the DBL varied and did not directly follow the contour of the underlying thallus. Areas around single tufts of hyaline hairs exhibited a more complex mass-transfer boundary layer, showing both increased and decreased thickness when compared with areas over smooth thallus surfaces. Over thallus areas with several hyaline hair tufts, the overall effect was an apparent increase in the boundary layer thickness. We also found indications for advective O2 transport driven by pressure gradients or vortex shedding downstream from dense tufts of hyaline hairs that could alleviate local mass-transfer resistances. Mass-transfer dynamics around hyaline hair tufts are thus more complex than hitherto assumed and may have important implications for algal physiology and plant-microbe interactions.

  19. Exact analytical solutions for contaminant transport in rivers 1. The equilibrium advection-dispersion equation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Analytical solutions of the advection-dispersion equation and related models are indispensable for predicting or analyzing contaminant transport processes in streams and rivers, as well as in other surface water bodies. Many useful analytical solutions originated in disciplines other than surface-w...

  20. Scaling of geochemical reaction rates via advective solute transport

    NASA Astrophysics Data System (ADS)

    Hunt, A. G.; Ghanbarian, B.; Skinner, T. E.; Ewing, R. P.

    2015-07-01

    Transport in porous media is quite complex, and still yields occasional surprises. In geological porous media, the rate at which chemical reactions (e.g., weathering and dissolution) occur is found to diminish by orders of magnitude with increasing time or distance. The temporal rates of laboratory experiments and field observations differ, and extrapolating from laboratory experiments (in months) to field rates (in millions of years) can lead to order-of-magnitude errors. The reactions are transport-limited, but characterizing them using standard solute transport expressions can yield results in agreement with experiment only if spurious assumptions and parameters are introduced. We previously developed a theory of non-reactive solute transport based on applying critical path analysis to the cluster statistics of percolation. The fractal structure of the clusters can be used to generate solute distributions in both time and space. Solute velocities calculated from the temporal evolution of that distribution have the same time dependence as reaction-rate scaling in a wide range of field studies and laboratory experiments, covering some 10 decades in time. The present theory thus both explains a wide range of experiments, and also predicts changes in the scaling behavior in individual systems with increasing time and/or length scales. No other theory captures these variations in scaling by invoking a single physical mechanism. Because the successfully predicted chemical reactions include known results for silicate weathering rates, our theory provides a framework for understanding changes in the global carbon cycle, including its effects on extinctions, climate change, soil production, and denudation rates. It further provides a basis for understanding the fundamental time scales of hydrology and shallow geochemistry, as well as the basis of industrial agriculture.

  1. The role of advection and dispersion in the rock matrix on the transport of leaking CO2-saturated brine along a fractured zone

    NASA Astrophysics Data System (ADS)

    Ahmad, Nawaz; Wörman, Anders; Sanchez-Vila, Xavier; Bottacin-Busolin, Andrea

    2016-12-01

    CO2 that is injected into a geological storage reservoir can leak in dissolved form because of brine displacement from the reservoir, which is caused by large-scale groundwater motion. Simulations of the reactive transport of leaking CO2aq along a conducting fracture in a clay-rich caprock are conducted to analyze the effect of various physical and geochemical processes. Whilst several modeling transport studies along rock fractures have considered diffusion as the only transport process in the surrounding rock matrix (diffusive transport), this study analyzes the combined role of advection and dispersion in the rock matrix in addition to diffusion (advection-dominated transport) on the migration of CO2aq along a leakage pathway and its conversion in geochemical reactions. A sensitivity analysis is performed to quantify the effect of fluid velocity and dispersivity. Variations in the porosity and permeability of the medium are found in response to calcite dissolution and precipitation along the leakage pathway. We observe that advection and dispersion in the rock matrix play a significant role in the overall transport process. For the parameters that were used in this study, advection-dominated transport increased the leakage of CO2aq from the reservoir by nearly 305%, caused faster transport and increased the mass conversion of CO2aq in geochemical reactions along the transport pathway by approximately 12.20% compared to diffusive transport.

  2. Removing volatile contaminants from the unsaturated zone by inducing advective air-phase transport

    USGS Publications Warehouse

    Baehr, A.L.; Hoag, G.E.; Marley, M.C.

    1989-01-01

    Organic liquids inadvertently spilled and then distributed in the unsaturated zone can pose a long-term threat to ground water. Many of these substances have significant volatility, and thereby establish a premise for contaminant removal from the unsaturated zone by inducing advective air-phase transport with wells screened in the unsaturated zone. In order to focus attention on the rates of mass transfer from liquid to vapour phases, sand columns were partially saturated with gasoline and vented under steady air-flow conditions. The ability of an equilibrium-based transport model to predict the hydrocarbon vapor flux from the columns implies an efficient rate of local phase transfer for reasonably high air-phase velocities. Thus the success of venting remediations will depend primarily on the ability to induce an air-flow field in a heterogeneous unsaturated zone that will intersect the distributed contaminant. To analyze this aspect of the technique, a mathematical model was developed to predict radially symmetric air flow induced by venting from a single well. This model allows for in-situ determinations of air-phase permeability, which is the fundamental design parameter, and for the analysis of the limitations of a single well design. A successful application of the technique at a site once contaminated by gasoline supports the optimism derived from the experimental and modeliing phases of this study, and illustrates the well construction and field methods used to document the volatile contaminant recovery. ?? 1989.

  3. Self-organization and advective transport in the cell polarity formation for asymmetric cell division.

    PubMed

    Seirin Lee, Sungrim; Shibata, Tatsuo

    2015-10-07

    Anterior-Posterior (AP) polarity formation of cell membrane proteins plays a crucial role in determining cell asymmetry, which depends not only on the several genetic process but also biochemical and biophysical interactions. The mechanism of AP formation of Caenorhabditis elegans embryo is characterized into the three processes: (i) membrane association and dissociation of posterior and anterior proteins, (ii) diffusion into the membrane and cytosol, and (iii) active cortical and cytoplasmic flows induced by the contraction of the acto-myosin cortex. We explored the mechanism of symmetry breaking and AP polarity formation using self-recruitment model of posterior proteins. We found that the AP polarity pattern is established over wide range in the total mass of polarity proteins and the diffusion ratio in the cytosol to the membrane. We also showed that the advective transport in both membrane and cytosol during the establishment phase affects optimal time interval of establishment and positioning of the posterior domain, and plays a role to increase the robustness in the AP polarity formation by reducing the number of posterior domains for the sensitivity of initial conditions. We also demonstrated that a proper ratio of the total mass to cell size robustly regulate the length scale of the posterior domain.

  4. Analytical solutions of the one-dimensional advection-dispersion solute transport equation subject to time-dependent boundary conditions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Analytical solutions of the advection-dispersion solute transport equation remain useful for a large number of applications in science and engineering. In this paper we extend the Duhamel theorem, originally established for diffusion type problems, to the case of advective-dispersive transport subj...

  5. The impact of air mass advection on aerosol optical properties over Gotland (Baltic Sea)

    NASA Astrophysics Data System (ADS)

    Zdun, Agnieszka; Rozwadowska, Anna; Kratzer, Susanne

    2016-12-01

    In the present paper, measurements of aerosol optical properties from the Gotland station of the AERONET network, combined with a two-stage cluster analysis of back trajectories of air masses moving over Gotland, were used to identify the main paths of air mass advection to the Baltic Sea and to relate them to aerosol optical properties, i.e. the aerosol optical thickness at the wavelength λ = 500 nm, AOT (500) and the Ångström exponent for the spectral range from 440 to 870 nm, α(440,870). One- to six-day long back trajectories ending at 300, 500 and 3000 m above the station were computed using the HYSPLIT model. The study shows that in the Gotland region, variability in aerosol optical thickness AOT(500) is more strongly related to advections in the boundary layer than to those in the free troposphere. The observed variability in AOT(500) was best explained by the advection speeds and directions given by clustering of 4-day backward trajectories of air arriving in the boundary layer at 500 m above the station. 17 clusters of 4-day trajectories arriving at altitude 500 m above the Gotland station (sea level) derived using two-stage cluster analysis differ from each other with respect to trajectory length, the speed of air mass movement and the direction of advection. They also show different cluster means of AOT(500) and α(440,870). The cluster mean AOT(500) ranges from 0.342 ± 0.012 for the continental clusters M2 (east-southeast advection with moderate speed) and 0.294 ± 0.025 for S5 (slow south-southeast advection) to 0.064 ± 0.002 and 0.069 ± 0.002 for the respective marine clusters L3 (fast west-northwest advection) and M3 (north-northwest advection with moderate speed). The cluster mean α(440,870) varies from 1.65-1.70 for the short-trajectory clusters to 0.98 ± 0.03 and 1.06 ± 0.03 for the Arctic marine cluster L4 (fast inflow from the north) and marine cluster L5 (fast inflow from the west) respectively.

  6. THE INTERPLAY BETWEEN GEOCHEMICAL REACTIONS AND ADVECTION-DISPERSION IN CONTAMINANT TRANSPORT AT A URANIUM MILL TAILINGS SITE

    EPA Science Inventory

    It is well known that the fate and transport of contaminants in the subsurface are controlled by complex processes including advection, dispersion-diffusion, and chemical reactions. However, the interplay between the physical transport processes and chemical reactions, and their...

  7. Mass Transport within Soils

    SciTech Connect

    McKone, Thomas E.

    2009-03-01

    with three major horizons, the saturated zone can be further divided into other zones based on hydraulic and geologic conditions. Wetland soils are a special and important class in which near-saturation conditions exist most of the time. When a contaminant is added to or formed in a soil column, there are several mechanisms by which it can be dispersed, transported out of the soil column to other parts of the environment, destroyed, or transformed into some other species. Thus, to evaluate or manage any contaminant introduced to the soil column, one must determine whether and how that substance will (1) remain or accumulate within the soil column, (2) be transported by dispersion or advection within the soil column, (3) be physically, chemically, or biologically transformed within the soil (i.e., by hydrolysis, oxidation, etc.), or (4) be transported out of the soil column to another part of the environment through a cross-media transfer (i.e., volatilization, runoff, ground water infiltration, etc.). These competing processes impact the fate of physical, chemical, or biological contaminants found in soils. In order to capture these mechanisms in mass transfer models, we must develop mass-transfer coefficients (MTCs) specific to soil layers. That is the goal of this chapter. The reader is referred to other chapters in this Handbook that address related transport processes, namely Chapter 13 on bioturbation, Chapter 15 on transport in near-surface geological formations, and Chapter 17 on soil resuspention. This chapter addresses the following issues: the nature of soil pollution, composition of soil, transport processes and transport parameters in soil, transformation processes in soil, mass-balance models, and MTCs in soils. We show that to address vertical heterogeneity in soils in is necessary to define a characteristic scaling depth and use this to establish process-based expressions for soil MTCs. The scaling depth in soil and the corresponding MTCs depend strongly

  8. A Comparative Study of Indoor Radon Contributed by Diffusive and Advective Transport through Intact Concrete

    NASA Astrophysics Data System (ADS)

    Chauhan, R. P.; Kumar, Amit

    The present work is aimed that out of diffusive and advective transport which is dominant process for indoor radon entry under normal room conditions. For this purpose the radon diffusion coefficient and permeability of concrete were measured by specially designed experimental set up. The radon diffusion coefficient of concrete was measured by continuous radon monitor. The measured value was (3.78 ± 0.39)×10-8 m2/s and found independent of the radon gas concentration in source chamber. The radon permeability of concrete varied between 1.85×10-17 to 1.36×10-15 m2 for the bulk pressure difference fewer than 20 Pa to 73.3 kPa. From the measured diffusion coefficient and absolute permeability, the radon flux from the concrete surface having concentrations gradient 12-40 kBq/m3 and typical floor thickness 0.1 m was calculated by the application of Fick and Darcy laws. Using the measured flux attributable to diffusive and advective transport, the indoor radon concentration for a typical Indian model room having dimension (5×6×7) m3 was calculated under average room ventilation (0.63 h-1). The results showed that the contribution of diffusive transport through intact concrete is dominant over the advective transport, as expected from the low values of concrete permeability.

  9. New Solution of Diffusion-Advection Equation for Cosmic-Ray Transport Using Ultradistributions

    NASA Astrophysics Data System (ADS)

    Rocca, M. C.; Plastino, A. R.; Plastino, A.; Ferri, G. L.; de Paoli, A.

    2015-11-01

    In this paper we exactly solve the diffusion-advection equation (DAE) for cosmic-ray transport. For such a purpose we use the Theory of Ultradistributions of J. Sebastiao e Silva, to give a general solution for the DAE. From the ensuing solution, we obtain several approximations as limiting cases of various situations of physical and astrophysical interest. One of them involves Solar cosmic-rays' diffusion.

  10. Analytical solution for one-dimensional advection-dispersion transport equation with distance-dependent coefficients

    NASA Astrophysics Data System (ADS)

    Pérez Guerrero, J. S.; Skaggs, T. H.

    2010-08-01

    SummaryMathematical models describing contaminant transport in heterogeneous porous media are often formulated as an advection-dispersion transport equation with distance-dependent transport coefficients. In this work, a general analytical solution is presented for the linear, one-dimensional advection-dispersion equation with distance-dependent coefficients. An integrating factor is employed to obtain a transport equation that has a self-adjoint differential operator, and a solution is found using the generalized integral transform technique (GITT). It is demonstrated that an analytical expression for the integrating factor exists for several transport equation formulations of practical importance in groundwater transport modeling. Unlike nearly all solutions available in the literature, the current solution is developed for a finite spatial domain. As an illustration, solutions for the particular case of a linearly increasing dispersivity are developed in detail and results are compared with solutions from the literature. Among other applications, the current analytical solution will be particularly useful for testing or benchmarking numerical transport codes because of the incorporation of a finite spatial domain.

  11. Numerical Experiments on Advective Transport in Large Three-Dimensional Discrete Fracture Networks

    NASA Astrophysics Data System (ADS)

    Makedonska, N.; Painter, S. L.; Karra, S.; Gable, C. W.

    2013-12-01

    Modeling of flow and solute transport in discrete fracture networks is an important approach for understanding the migration of contaminants in impermeable hard rocks such as granite, where fractures provide dominant flow and transport pathways. The discrete fracture network (DFN) model attempts to mimic discrete pathways for fluid flow through a fractured low-permeable rock mass, and may be combined with particle tracking simulations to address solute transport. However, experience has shown that it is challenging to obtain accurate transport results in three-dimensional DFNs because of the high computational burden and difficulty in constructing a high-quality unstructured computational mesh on simulated fractures. An integrated DFN meshing [1], flow, and particle tracking [2] simulation capability that enables accurate flow and particle tracking simulation on large DFNs has recently been developed. The new capability has been used in numerical experiments on advective transport in large DFNs with tens of thousands of fractures and millions of computational cells. The modeling procedure starts from the fracture network generation using a stochastic model derived from site data. A high-quality computational mesh is then generated [1]. Flow is then solved using the highly parallel PFLOTRAN [3] code. PFLOTRAN uses the finite volume approach, which is locally mass conserving and thus eliminates mass balance problems during particle tracking. The flow solver provides the scalar fluxes on each control volume face. From the obtained fluxes the Darcy velocity is reconstructed for each node in the network [4]. Velocities can then be continuously interpolated to any point in the domain of interest, thus enabling random walk particle tracking. In order to describe the flow field on fractures intersections, the control volume cells on intersections are split into four planar polygons, where each polygon corresponds to a piece of a fracture near the intersection line. Thus

  12. Advective transport observations with MODPATH-OBS--documentation of the MODPATH observation process

    USGS Publications Warehouse

    Hanson, R.T.; Kauffman, L.K.; Hill, M.C.; Dickinson, J.E.; Mehl, S.W.

    2013-01-01

    The MODPATH-OBS computer program described in this report is designed to calculate simulated equivalents for observations related to advective groundwater transport that can be represented in a quantitative way by using simulated particle-tracking data. The simulated equivalents supported by MODPATH-OBS are (1) distance from a source location at a defined time, or proximity to an observed location; (2) time of travel from an initial location to defined locations, areas, or volumes of the simulated system; (3) concentrations used to simulate groundwater age; and (4) percentages of water derived from contributing source areas. Although particle tracking only simulates the advective component of conservative transport, effects of non-conservative processes such as retardation can be approximated through manipulation of the effective-porosity value used to calculate velocity based on the properties of selected conservative tracers. This program can also account for simple decay or production, but it cannot account for diffusion. Dispersion can be represented through direct simulation of subsurface heterogeneity and the use of many particles. MODPATH-OBS acts as a postprocessor to MODPATH, so that the sequence of model runs generally required is MODFLOW, MODPATH, and MODPATH-OBS. The version of MODFLOW and MODPATH that support the version of MODPATH-OBS presented in this report are MODFLOW-2005 or MODFLOW-LGR, and MODPATH-LGR. MODFLOW-LGR is derived from MODFLOW-2005, MODPATH 5, and MODPATH 6 and supports local grid refinement. MODPATH-LGR is derived from MODPATH 5. It supports the forward and backward tracking of particles through locally refined grids and provides the output needed for MODPATH_OBS. For a single grid and no observations, MODPATH-LGR results are equivalent to MODPATH 5. MODPATH-LGR and MODPATH-OBS simulations can use nearly all of the capabilities of MODFLOW-2005 and MODFLOW-LGR; for example, simulations may be steady-state, transient, or a combination

  13. An approximate calculation of advective gas-phase transport of 14C at Yucca Mountain, Nevada

    NASA Astrophysics Data System (ADS)

    Knapp, R. B.

    1990-01-01

    A quasilinear partial differential equation, which describes gas-phase transport of a 14C kinematic wave through a porous medium, is derived, its sensitivity to system variables is analyzed and it is applied to one possible release scenarion at the porposed Yucca Mountain, Nevada high-level radioactive waste repository. Advection, isotope exchange between CO 2 in a flowing gas phase and HCO 3- in a static aqueous phase, and radioactive decay are incorporated. The governing equation is solved analytically by the method of characteristics. The mass fraction of 14C in the gas phase,X 14g, is controlled by radioactive decay. The relatively long half-line of 14C, about 5720 years, and the relatively shallow proposed burial depth of the radioactive waste, about 350m, requires significant retardation of the 14C wave velocity for significant reduction in X 14g. 14C wave velocity is most sensitive to temperature and pH which control the distribution of total carbon between gas and liquid phase; the greater the partitioning of carbon into the liquid phase, the greater the retardation of the 14C wave velocity and the greater the ultimate reduction in X 14g from initial conditions. Partitioning of total carbon into the liquid phase is greatest at low temperatures, < 100° C, and high pH values, > 8. Increasing water saturation also tends to retard 14C wave velocity but to a lesser extent. The governing equation has been applied using conditions that may possibly occur at the proposed Yucca Mountain repository. Calculations indicate that the 14C wave takes about 5900 years to reach the surface with a X 14g equal to 25 ppm. Diffusion and dispersion are not of major importance for these conditions. These calculations are approximate due to the number of assumptions involved. Discharge of 14C into the gas before the selected time would accelerate wave arrival and increase the amount of 14C reaching the surface.

  14. Controlling the column spacing in isothermal magnetic advection to enable tunable heat and mass transfer.

    DOE PAGES

    Solis, Kyle Jameson; Martin, James E.

    2012-11-01

    Isothermal magnetic advection is a recently discovered method of inducing highly organized, non-contact flow lattices in suspensions of magnetic particles, using only uniform ac magnetic fields of modest strength. The initiation of these vigorous flows requires neither a thermal gradient nor a gravitational field and so can be used to transfer heat and mass in circumstances where natural convection does not occur. These advection lattices are comprised of a square lattice of antiparallel flow columns. If the column spacing is sufficiently large compared to the column length, and the flow rate within the columns is sufficiently large, then one wouldmore » expect efficient transfer of both heat and mass. Otherwise, the flow lattice could act as a countercurrent heat exchanger and only mass will be efficiently transferred. Although this latter case might be useful for feeding a reaction front without extracting heat, it is likely that most interest will be focused on using IMA for heat transfer. In this paper we explore the various experimental parameters of IMA to determine which of these can be used to control the column spacing. These parameters include the field frequency, strength, and phase relation between the two field components, the liquid viscosity and particle volume fraction. We find that the column spacing can easily be tuned over a wide range, to enable the careful control of heat and mass transfer.« less

  15. Controlling the column spacing in isothermal magnetic advection to enable tunable heat and mass transfer.

    SciTech Connect

    Solis, Kyle Jameson; Martin, James E.

    2012-11-01

    Isothermal magnetic advection is a recently discovered method of inducing highly organized, non-contact flow lattices in suspensions of magnetic particles, using only uniform ac magnetic fields of modest strength. The initiation of these vigorous flows requires neither a thermal gradient nor a gravitational field and so can be used to transfer heat and mass in circumstances where natural convection does not occur. These advection lattices are comprised of a square lattice of antiparallel flow columns. If the column spacing is sufficiently large compared to the column length, and the flow rate within the columns is sufficiently large, then one would expect efficient transfer of both heat and mass. Otherwise, the flow lattice could act as a countercurrent heat exchanger and only mass will be efficiently transferred. Although this latter case might be useful for feeding a reaction front without extracting heat, it is likely that most interest will be focused on using IMA for heat transfer. In this paper we explore the various experimental parameters of IMA to determine which of these can be used to control the column spacing. These parameters include the field frequency, strength, and phase relation between the two field components, the liquid viscosity and particle volume fraction. We find that the column spacing can easily be tuned over a wide range, to enable the careful control of heat and mass transfer.

  16. An advection-diffusion model for cross-field runaway electron transport in perturbed magnetic fields

    NASA Astrophysics Data System (ADS)

    Särkimäki, Konsta; Hirvijoki, Eero; Decker, Joan; Varje, Jari; Kurki-Suonio, Taina

    2016-12-01

    Disruption-generated runaway electrons (RE) present an outstanding issue for ITER. The predictive computational studies of RE generation rely on orbit-averaged computations and, as such, they lack the effects from the magnetic field stochasticity. Since stochasticity is naturally present in post-disruption plasma, and externally induced stochastization offers a prominent mechanism to mitigate RE avalanche, we present an advection-diffusion model that can be used to couple an orbit-following code to an orbit-averaged tool in order to capture the cross-field transport and to overcome the latter’s limitation. The transport coefficients are evaluated via a Monte Carlo method. We show that the diffusion coefficient differs significantly from the well-known Rechester-Rosenbluth result. We also demonstrate the importance of including the advection: it has a two-fold role both in modelling transport barriers created by magnetic islands and in amplifying losses in regions where the islands are not present.

  17. Analytical solutions of a fractional diffusion-advection equation for solar cosmic-ray transport

    SciTech Connect

    Litvinenko, Yuri E.; Effenberger, Frederic

    2014-12-01

    Motivated by recent applications of superdiffusive transport models to shock-accelerated particle distributions in the heliosphere, we analytically solve a one-dimensional fractional diffusion-advection equation for the particle density. We derive an exact Fourier transform solution, simplify it in a weak diffusion approximation, and compare the new solution with previously available analytical results and with a semi-numerical solution based on a Fourier series expansion. We apply the results to the problem of describing the transport of energetic particles, accelerated at a traveling heliospheric shock. Our analysis shows that significant errors may result from assuming an infinite initial distance between the shock and the observer. We argue that the shock travel time should be a parameter of a realistic superdiffusive transport model.

  18. Analytical Solutions of a Fractional Diffusion-advection Equation for Solar Cosmic-Ray Transport

    NASA Astrophysics Data System (ADS)

    Litvinenko, Yuri E.; Effenberger, Frederic

    2014-12-01

    Motivated by recent applications of superdiffusive transport models to shock-accelerated particle distributions in the heliosphere, we analytically solve a one-dimensional fractional diffusion-advection equation for the particle density. We derive an exact Fourier transform solution, simplify it in a weak diffusion approximation, and compare the new solution with previously available analytical results and with a semi-numerical solution based on a Fourier series expansion. We apply the results to the problem of describing the transport of energetic particles, accelerated at a traveling heliospheric shock. Our analysis shows that significant errors may result from assuming an infinite initial distance between the shock and the observer. We argue that the shock travel time should be a parameter of a realistic superdiffusive transport model.

  19. Simulation of the advective methane transport and AOM in Shenhu area, the Northern South China Sea

    NASA Astrophysics Data System (ADS)

    Liu, L.; Wu, N.

    2012-04-01

    Anaerobic Oxidation of Methane (AOM) occurs in the transition zone between the presence of sulfate and methane. This reaction is an important process for methane and the global carbon cycle. Methane gas hydrates bearing sediments were recovered in Shenhu Area, the Northern South China Sea, and methane advective transport was detected in this area as well. A one dimension numerical simulation tool was implemented to study the AOM process combined with the advective methane transport in Shenhu Area according to the local drilling data and geochemical information. The modeled results suggest that local methane flux will be consumed in the sediment column via dissolution, sorption and AOM reaction. A portion of methane will enter water column and possibly atmosphere if the methane flux was one order of magnitude higher than current level. Furthermore, the calculated rates of AOM in Shenhu area range similar to that of gas hydrate mounds in Mexico Golf. However, AOM is ability to consume more methane than that in Golf of Mexico due to the lower permeable sediment associated with a deeper sulfate methane transition layer.

  20. Advective-diffusive/dispersive transport of chemically reacting species in hydrothermal systems. Final report, FY83-85

    SciTech Connect

    Lichtner, P.C.; Helgeson, H.C.

    1986-06-20

    A general formulation of multi-phase fluid flow coupled to chemical reactions was developed based on a continuum description of porous media. A preliminary version of the computer code MCCTM was constructed which implemented the general equations for a single phase fluid. The computer code MCCTM incorporates mass transport by advection-diffusion/dispersion in a one-dimensional porous medium coupled to reversible and irreversible, homogeneous and heterogeneous chemical reactions. These reactions include aqueous complexing, oxidation/reduction reactions, ion exchange, and hydrolysis reactions of stoichiometric minerals. The code MCCTM uses a fully implicit finite difference algorithm. The code was tested against analytical calculations. Applications of the code included investigation of the propagation of sharp chemical reaction fronts, metasomatic alteration of microcline at elevated temperatures and pressures, and ion-exchange in a porous column. Finally numerical calculations describing fluid flow in crystalline rock in the presence of a temperature gradient were compared with experimental results for quartzite.

  1. Renormalization group estimates of transport coefficients in the advection of a passive scalar by incompressible turbulence

    NASA Technical Reports Server (NTRS)

    Zhou, YE; Vahala, George

    1993-01-01

    The advection of a passive scalar by incompressible turbulence is considered using recursive renormalization group procedures in the differential sub grid shell thickness limit. It is shown explicitly that the higher order nonlinearities induced by the recursive renormalization group procedure preserve Galilean invariance. Differential equations, valid for the entire resolvable wave number k range, are determined for the eddy viscosity and eddy diffusivity coefficients, and it is shown that higher order nonlinearities do not contribute as k goes to 0, but have an essential role as k goes to k(sub c) the cutoff wave number separating the resolvable scales from the sub grid scales. The recursive renormalization transport coefficients and the associated eddy Prandtl number are in good agreement with the k-dependent transport coefficients derived from closure theories and experiments.

  2. Space shuttle exhaust plumes in the lower thermosphere: Advective transport and diffusive spreading

    NASA Astrophysics Data System (ADS)

    Stevens, Michael H.; Lossow, Stefan; Siskind, David E.; Meier, R. R.; Randall, Cora E.; Russell, James M.; Urban, Jo; Murtagh, Donal

    2014-02-01

    The space shuttle main engine plume deposited between 100 and 115 km altitude is a valuable tracer for global-scale dynamical processes. Several studies have shown that this plume can reach the Arctic or Antarctic to form bursts of polar mesospheric clouds (PMCs) within a few days. The rapid transport of the shuttle plume is currently not reproduced by general circulation models and is not well understood. To help delineate the issues, we present the complete satellite datasets of shuttle plume observations by the Sounding of the Atmosphere using Broadband Emission Radiometry instrument and the Sub-Millimeter Radiometer instrument. From 2002 to 2011 these two instruments observed 27 shuttle plumes in over 600 limb scans of water vapor emission, from which we derive both advective meridional transport and diffusive spreading. Each plume is deposited at virtually the same place off the United States east coast so our results are relevant to northern mid-latitudes. We find that the advective transport for the first 6-18 h following deposition depends on the local time (LT) of launch: shuttle plumes deposited later in the day (~13-22 LT) typically move south whereas they otherwise typically move north. For these younger plumes rapid transport is most favorable for launches at 6 and 18 LT, when the displacement is 10° in latitude corresponding to an average wind speed of 30 m/s. For plumes between 18 and 30 h old some show average sustained meridional speeds of 30 m/s. For plumes between 30 and 54 h old the observations suggest a seasonal dependence to the meridional transport, peaking near the beginning of year at 24 m/s. The diffusive spreading of the plume superimposed on the transport is on average 23 m/s in 24 h. The plume observations show large variations in both meridional transport and diffusive spreading so that accurate modeling requires knowledge of the winds specific to each case. The combination of transport and spreading from the STS-118 plume in August

  3. Contour advection with surgery: A technique for investigating finescale structure in tracer transport

    NASA Technical Reports Server (NTRS)

    Waugh, Darryn W.; Plumb, R. Alan

    1994-01-01

    We present a trajectory technique, contour advection with surgery (CAS), for tracing the evolution of material contours in a specified (including observed) evolving flow. CAS uses the algorithms developed by Dritschel for contour dynamics/surgery to trace the evolution of specified contours. The contours are represented by a series of particles, which are advected by a specified, gridded, wind distribution. The resolution of the contours is preserved by continually adjusting the number of particles, and finescale features are produced that are not present in the input data (and cannot easily be generated using standard trajectory techniques). The reliability, and dependence on the spatial and temporal resolution of the wind field, of the CAS procedure is examined by comparisons with high-resolution numerical data (from contour dynamics calculations and from a general circulation model), and with routine stratospheric analyses. These comparisons show that the large-scale motions dominate the deformation field and that CAS can accurately reproduce small scales from low-resolution wind fields. The CAS technique therefore enables examination of atmospheric tracer transport at previously unattainable resolution.

  4. Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems

    NASA Astrophysics Data System (ADS)

    Li, Zhen; Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em

    2015-07-01

    We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers.

  5. Transport dissipative particle dynamics model for mesoscopic advection-diffusion-reaction problems

    PubMed Central

    Yazdani, Alireza; Tartakovsky, Alexandre; Karniadakis, George Em

    2015-01-01

    We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic dissipative particle dynamics (DPD) framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between tDPD particles, and the advection is implicitly considered by the movements of these Lagrangian particles. An analytical formula is proposed to relate the tDPD parameters to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the conventional DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers. PMID:26156459

  6. A subordinated advection model for uniform bed load transport from local to regional scales

    NASA Astrophysics Data System (ADS)

    Zhang, Yong; Martin, Raleigh L.; Chen, Dong; Baeumer, Boris; Sun, Hongguang; Chen, Li

    2014-12-01

    Sediment tracers moving as bed load can exhibit anomalous dispersion behavior deviating from Fickian diffusion. The presence of heavy-tailed resting time distributions and thin-tailed step length distributions motivate adoption of fractional-derivative models (FDMs) to describe sediment dispersion, but these models require many parameters that are difficult to quantify. Here we propose a considerably simplified FDM for anomalous transport of uniformly sized grains along straight channels, the subordinated advection equation (SAE), which is based on the concept of time subordination. Unlike previous FDM models with time index γ between 0 and 1, our SAE model adopts a value of γ between 1 and 2. This γ describes random velocities deviating significantly from the mean velocity and models both long resting periods and relatively fast displacements. We show that the model quantifies the dynamics of four bed load transport experiments recorded in the literature. In addition to γ, SAE model parameters—velocity and capacity coefficient—are related to the mean and variance of particle velocities, respectively. Successful application of the SAE model also implies a universal probability density for the heavy-tailed waiting time distribution (with finite mean) and a relatively lighter tailed step length distribution for uniform bed load transport from local to regional scales.

  7. Transport and Recruitment of Blue Crab Larvae:a Model with Advection and Mortality

    NASA Astrophysics Data System (ADS)

    Garvine, R. W.; Epifanio, C. E.; Epifanio, C. C.; Wong, K.-C.

    1997-07-01

    The present paper develops a mathematical model for the transport and recruitment of blue crab (Callinectes sapidus) larvae, and applies it to the inner continental shelf of the Middle Atlantic Bight near Delaware Bay, U.S.A. Blue crab larvae develop through seven or eight planktonic zoeal stages to a megalopa stage suitable for recruitment to adult populations of east coast estuaries. The larvae are concentrated near the surface, and the currents are primarily forced by alongshelf winds and river discharge through major estuaries. Model currents are prescribed based on a realistic synthesis of their observed relationship to wind and river discharge. Besides the resulting advection, particle diffusion and biological mortality are added to determine the fate of larvae released from their parent estuary. Groups of particles were released across the source region of the outflowing buoyancy-driven current in the model estuary mouth. Most larvae were swept alongshelf to the south with the buoyancy-driven coastal current, and thus were lost as recruits to the population of their parent estuary. However, some larvae released close to the seaward edge of the emerging coastal current were able to cross the coastal current front and move seaward into inner shelf water during upwelling-favorable (northward) wind events. Some of these, in turn, were suitably placed near the parent estuary mouth so that they could be advected landward as megalopae into the estuary during a subsequent downwelling-favorable (southward) wind event and thus join the adult population. The model results for megalopae returns were computed from consecutive daily release of 1000 particles, and were compared with 4 years of blue crab megalopa settlement data for Delaware Bay. The model results for 1989 and 1990 matched the observed data remarkably well, with both years showing dominance by a single return event of a few days duration. For 1991 and 1992, the observed results showed multiple return events

  8. Transport dissipative particle dynamics model for mesoscopic advection- diffusion-reaction problems

    SciTech Connect

    Zhen, Li; Yazdani, Alireza; Tartakovsky, Alexandre M.; Karniadakis, George E.

    2015-07-07

    We present a transport dissipative particle dynamics (tDPD) model for simulating mesoscopic problems involving advection-diffusion-reaction (ADR) processes, along with a methodology for implementation of the correct Dirichlet and Neumann boundary conditions in tDPD simulations. tDPD is an extension of the classic DPD framework with extra variables for describing the evolution of concentration fields. The transport of concentration is modeled by a Fickian flux and a random flux between particles, and an analytical formula is proposed to relate the mesoscopic concentration friction to the effective diffusion coefficient. To validate the present tDPD model and the boundary conditions, we perform three tDPD simulations of one-dimensional diffusion with different boundary conditions, and the results show excellent agreement with the theoretical solutions. We also performed two-dimensional simulations of ADR systems and the tDPD simulations agree well with the results obtained by the spectral element method. Finally, we present an application of the tDPD model to the dynamic process of blood coagulation involving 25 reacting species in order to demonstrate the potential of tDPD in simulating biological dynamics at the mesoscale. We find that the tDPD solution of this comprehensive 25-species coagulation model is only twice as computationally expensive as the DPD simulation of the hydrodynamics only, which is a significant advantage over available continuum solvers.

  9. The predictability of advection-dominated flux-transport solar dynamo models

    SciTech Connect

    Sanchez, Sabrina; Fournier, Alexandre; Aubert, Julien

    2014-01-20

    Space weather is a matter of practical importance in our modern society. Predictions of forecoming solar cycles mean amplitude and duration are currently being made based on flux-transport numerical models of the solar dynamo. Interested in the forecast horizon of such studies, we quantify the predictability window of a representative, advection-dominated, flux-transport dynamo model by investigating its sensitivity to initial conditions and control parameters through a perturbation analysis. We measure the rate associated with the exponential growth of an initial perturbation of the model trajectory, which yields a characteristic timescale known as the e-folding time τ {sub e}. The e-folding time is shown to decrease with the strength of the α-effect, and to increase with the magnitude of the imposed meridional circulation. Comparing the e-folding time with the solar cycle periodicity, we obtain an average estimate for τ {sub e} equal to 2.76 solar cycle durations. From a practical point of view, the perturbations analyzed in this work can be interpreted as uncertainties affecting either the observations or the physical model itself. After reviewing these, we discuss their implications for solar cycle prediction.

  10. In situ experiment to determine advective-diffusive controls on solute transport in a clay-rich aquitard.

    PubMed

    Barbour, S Lee; Hendry, M Jim; Wassenaar, Leonard I

    2012-04-01

    Solute transport in clay-rich aquitards is characterized as molecular diffusion- or advection-dominated based on the Péclet number (P(e)). However, few field-based measurements of the coefficient of molecular diffusion (D(e)) exist, and none with a range of advection- or diffusion-dominated conditions in the same aquitard. In this long-term field experiment, standing water in a recovering well was spiked with deuterium ((2)H), then water-level recovery and δ(2)H values were monitored as the well returned to static conditions over 1054 days. After a second (2)H spike, water levels and δ(2)H values were monitored to day 1644 while under near static conditions. Modeling of the second spike was used to define the D(e) of (2)H as (3-4)× 10(-10)m(2)s(-1) for an accessible porosity of 0.31. Reservoir concentrations from the initial spike were modeled to define the transition from advection- to diffusion-dominated transport. This occurred after 200 days, consistent with a transition in P(e) from <1 to >1 when the length term is taken as the radial extent of the tracer plume (normalized concentration <0.05). This study verifies plume extent as the characteristic length term in the calculation of P(e) and demonstrates the transition from advection- to diffusion-dominated transport as the value of P(e) decreases below unity.

  11. User's guide to PHREEQC, a computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations

    USGS Publications Warehouse

    Parkhurst, D.L.

    1995-01-01

    PHREEQC is a computer program written in the C pwgranuning language that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC is based on an ion-association aqueous model and has capabilities for (1) speciation and saturation-index calculations, (2) reaction-path and advective-transport calculations involving specified irreversible reactions, mixing of solutions, mineral and gas equilibria surface-complex-ation reactions, and ion-exchange reactions, and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for composition differences between waters, within specified compositional uncertainties. PHREEQC is derived from the Fortran program PHREEQE, but it has been completely rewritten in C with the addition many new capabilities. New features include the capabilities to use redox couples to distribute redox elements among their valence states in speciation calculations; to model ion-exchange and surface-compiexation reactions; to model reactions with a fixed-pressure, multicomponent gas phase (that is, a gas bubble); to calculate the mass of water in the aqueous phase during reaction and transport calculations; to keep track of the moles of minerals present in the solid phases and determine antomaticaHy the thermodynamically stable phase assemblage; to simulate advective transport in combination with PHREEQC's reaction-modeling capability; and to make inverse modeling calculations that allow for uncertainties in the analytical data. The user interface is improved through the use of a simplified approach to redox reactions, which includes explicit mole-balance equations for hydrogen and oxygen; the use of a revised input that is modular and completely free format; and the use of mineral names and standard chemical symbolism rather than index numbers. The use of (2 eliminates nearly all limitations on army sizes, including numbers of elements, aqueous species, solutions, phases, and lengths of character

  12. Assessment of nitrate transport parameters using the advection-diffusion cell.

    PubMed

    Aljazzar, Taiseer; Al-Qinna, Mohammed

    2016-11-01

    This study aimed to better understand nitrate transport in the soil system in a part of the state of North Rhine-Westphalia, in Germany, and to aid in the development of groundwater protection plans. An advection-diffusion (AD) cell was used in a miscible displacement experiment setup to characterize nitrate transport in 12 different soil samples from the study area. The three nitrate sorption isotherms were tested to define the exact nitrate interaction with the soil matrix. Soils varied in their properties which in its turn explain the variations in nitrate transport rates. Soil texture and organic matter content showed to have the most important effect on nitrate recovery and retardation. The miscible displacement experiment indicated a decrease in retardation by increasing sand fraction, and an increase in retardation by increasing soil organic matter content. Soil samples with high sand fractions (up to 94 %) exhibited low nitrate sorption capacity of less than 10 %, while soils with high organic matter content showed higher sorption of about 30 %. Based on parameterization for nitrate transport equation, the pore water velocity for both sandy and loamy soils were significantly different (P < 0.001). Pore water velocity in sandy soil (about 4 × 10(-3) m/s) was about 100 to 1000 larger than in loamy soils (8.7 × 10(-5) m/s). On the other hand, the reduction in nitrate transport in soils associated with high organic matter was due to fine pore pathways clogged by fine organic colloids. It is expected that the existing micro-phobicity increased the nitrate recovery from 9 to 32 % resulting in maximum diffusion rates of about 3.5 × 10(-5) m/s(2) in sandy soils (sample number CS-04) and about 1.4 × 10(-7) m/s(2) in silt loam soils (sample number FS-02).

  13. Investigating the impact of advective and diffusive controls in solute transport on geoelectrical data

    NASA Astrophysics Data System (ADS)

    Wheaton, Daniel D.; Singha, Kamini

    2010-09-01

    Multiple types of physical heterogeneity have been suggested to explain anomalous solute transport behavior, yet determining exactly what controls transport at a given site is difficult from concentration histories alone. Differences in timing between co-located fluid and bulk apparent electrical conductivity data have previously been used to estimate solute mass transfer rates between mobile and less-mobile domains; here, we consider if this behavior can arise from other types of heterogeneity. Numerical models are used to investigate the electrical signatures associated with large-scale hydraulic conductivity heterogeneity and small-scale dual-domain mass transfer, and address issues regarding the scale of the geophysical measurement. We examine the transport behavior of solutes with and without dual-domain mass transfer, in: 1) a homogeneous medium, 2) a discretely fractured medium, and 3) a hydraulic conductivity field generated with sequential Gaussian simulation. We use the finite-element code COMSOL Multiphysics to construct two-dimensional cross-sectional models and solve the coupled flow, transport, and electrical conduction equations. Our results show that both large-scale heterogeneity and subscale heterogeneity described by dual-domain mass transfer produce a measurable hysteresis between fluid and bulk apparent electrical conductivity, indicating a lag between electrical conductivity changes in the mobile and less-mobile domains of an aquifer, or mass transfer processes, at some scale. The shape and magnitude of the observed hysteresis is controlled by the spatial distribution of hydraulic heterogeneity, mass transfer rate between domains, and the ratio of mobile to immobile porosity. Because the rate of mass transfer is related to the inverse square of a diffusion length scale, our results suggest that the shape of the hysteresis curve is indicative of the length scale over which mass transfer is occurring. We also demonstrate that the difference in

  14. Mass-loss from advective accretion disc around rotating black holes

    NASA Astrophysics Data System (ADS)

    Aktar, Ramiz; Das, Santabrata; Nandi, Anuj

    2015-11-01

    We examine the properties of the outflowing matter from an advective accretion disc around a spinning black hole. During accretion, rotating matter experiences centrifugal pressure-supported shock transition that effectively produces a virtual barrier around the black hole in the form of post-shock corona (hereafter PSC). Due to shock compression, PSC becomes hot and dense that eventually deflects a part of the inflowing matter as bipolar outflows because of the presence of extra thermal gradient force. In our approach, we study the outflow properties in terms of the inflow parameters, namely specific energy (E) and specific angular momentum (λ) considering the realistic outflow geometry around the rotating black holes. We find that spin of the black hole (ak) plays an important role in deciding the outflow rate R_{dot{m}} (ratio of mass flux of outflow to inflow); in particular, R_{dot{m}} is directly correlated with ak for the same set of inflow parameters. It is found that a large range of the inflow parameters allows global accretion-ejection solutions, and the effective area of the parameter space (E, λ) with and without outflow decreases with black hole spin (ak). We compute the maximum outflow rate (R^{max}_{dot{m}}) as a function of black hole spin (ak) and observe that R^{max}_{dot{m}} weakly depends on ak that lies in the range ˜10-18 per cent of the inflow rate for the adiabatic index (γ) with 1.5 ≥ γ ≥ 4/3. We present the observational implication of our approach while studying the steady/persistent jet activities based on the accretion states of black holes. We discuss that our formalism seems to have the potential to explain the observed jet kinetic power for several Galactic black hole sources and active galactic nuclei.

  15. Pathogen and chemical transport in the karst limestone of the Biscayne aquifer: 2. Chemical retention from diffusion and slow advection

    USGS Publications Warehouse

    Shapiro, A.M.; Renken, R.A.; Harvey, R.W.; Zygnerski, M.R.; Metge, D.W.

    2008-01-01

    A tracer experiment, using a nonreactive tracer, was conducted as part of an investigation of the potential for chemical and pathogen migration to public supply wells that draw groundwater from the highly transmissive karst limestone of the Biscayne aquifer in southeastern Florida. The tracer was injected into the formation over approximately 1 h, and its recovery was monitored at a pumping well approximately 100 m from the injection well. The first detection of the tracer occurred after approximately 5 h, and the peak concentration occurred at about 8 h after the injection. The tracer was still detected in the production well more than 6 days after injection, and only 42% of the tracer mass was recovered. It is hypothesized that a combination of chemical diffusion and slow advection resulted in significant retention of the tracer in the formation, despite the high transmissivity of the karst limestone. The tail of the breakthrough curve exhibited a straight-line behavior with a slope of -2 on a log-log plot of concentration versus time. The -2 slope is hypothesized to be a function of slow advection, where the velocities of flow paths are hypothesized to range over several orders of magnitude. The flow paths having the slowest velocities result in a response similar to chemical diffusion. Chemical diffusion, due to chemical gradients, is still ongoing during the declining limb of the breakthrough curve, but this process is dwarfed by the magnitude of the mass flux by slow advection.

  16. Two-dimensional atmospheric transport and chemistry model - Numerical experiments with a new advection algorithm

    NASA Technical Reports Server (NTRS)

    Shia, Run-Lie; Ha, Yuk Lung; Wen, Jun-Shan; Yung, Yuk L.

    1990-01-01

    Extensive testing of the advective scheme proposed by Prather (1986) has been carried out in support of the California Institute of Technology-Jet Propulsion Laboratory two-dimensional model of the middle atmosphere. The original scheme is generalized to include higher-order moments. In addition, it is shown how well the scheme works in the presence of chemistry as well as eddy diffusion. Six types of numerical experiments including simple clock motion and pure advection in two dimensions have been investigated in detail. By comparison with analytic solutions, it is shown that the new algorithm can faithfully preserve concentration profiles, has essentially no numerical diffusion, and is superior to a typical fourth-order finite difference scheme.

  17. Temporal signatures of advective versus diffusive radon transport at a geothermal zone in Central Nepal.

    PubMed

    Richon, Patrick; Perrier, Frédéric; Koirala, Bharat Prasad; Girault, Frédéric; Bhattarai, Mukunda; Sapkota, Soma Nath

    2011-02-01

    Temporal variation of radon-222 concentration was studied at the Syabru-Bensi hot springs, located on the Main Central Thrust zone in Central Nepal. This site is characterized by several carbon dioxide discharges having maximum fluxes larger than 10 kg m(-2) d(-1). Radon concentration was monitored with autonomous Barasol™ probes between January 2008 and November 2009 in two small natural cavities with high CO(2) concentration and at six locations in the soil: four points having a high flux, and two background reference points. At the reference points, dominated by radon diffusion, radon concentration was stable from January to May, with mean values of 22 ± 6.9 and 37 ± 5.5 kBq m(-3), but was affected by a large increase, of about a factor of 2 and 1.6, respectively, during the monsoon season from June to September. At the points dominated by CO(2) advection, by contrast, radon concentration showed higher mean values 39.0 ± 2.6 to 78 ± 1.4 kBq m(-3), remarkably stable throughout the year with small long-term variation, including a possible modulation of period around 6 months. A significant difference between the diffusion dominated reference points and the advection-dominated points also emerged when studying the diurnal S(1) and semi-diurnal S(2) periodic components. At the advection-dominated points, radon concentration did not exhibit S(1) or S(2) components. At the reference points, however, the S(2) component, associated with barometric tide, could be identified during the dry season, but only when the probe was installed at shallow depth. The S(1) component, associated with thermal and possibly barometric diurnal forcing, was systematically observed, especially during monsoon season. The remarkable short-term and long-term temporal stability of the radon concentration at the advection-dominated points, which suggests a strong pressure source at depth, may be an important asset to detect possible temporal variations associated with the

  18. Non-Fickian mass transport in fractured porous media

    NASA Astrophysics Data System (ADS)

    Fomin, Sergei A.; Chugunov, Vladimir A.; Hashida, Toshiyuki

    2011-02-01

    The paper provides an introduction to fundamental concepts of mathematical modeling of mass transport in fractured porous heterogeneous rocks. Keeping aside many important factors that can affect mass transport in subsurface, our main concern is the multi-scale character of the rock formation, which is constituted by porous domains dissected by the network of fractures. Taking into account the well-documented fact that porous rocks can be considered as a fractal medium and assuming that sizes of pores vary significantly (i.e. have different characteristic scales), the fractional-order differential equations that model the anomalous diffusive mass transport in such type of domains are derived and justified analytically. Analytical solutions of some particular problems of anomalous diffusion in the fractal media of various geometries are obtained. Extending this approach to more complex situation when diffusion is accompanied by advection, solute transport in a fractured porous medium is modeled by the advection-dispersion equation with fractional time derivative. In the case of confined fractured porous aquifer, accounting for anomalous non-Fickian diffusion in the surrounding rock mass, the adopted approach leads to introduction of an additional fractional time derivative in the equation for solute transport. The closed-form solutions for concentrations in the aquifer and surrounding rocks are obtained for the arbitrary time-dependent source of contamination located in the inlet of the aquifer. Based on these solutions, different regimes of contamination of the aquifers with different physical properties can be readily modeled and analyzed.

  19. Chaotic advection at the pore scale: Mechanisms, upscaling and implications for macroscopic transport

    NASA Astrophysics Data System (ADS)

    Lester, D. R.; Trefry, M. G.; Metcalfe, G.

    2016-11-01

    The macroscopic spreading and mixing of solute plumes in saturated porous media is ultimately controlled by processes operating at the pore scale. Whilst the conventional picture of pore-scale mechanical dispersion and molecular diffusion leading to persistent hydrodynamic dispersion is well accepted, this paradigm is inherently two-dimensional (2D) in nature and neglects important three-dimensional (3D) phenomena. We discuss how the kinematics of steady 3D flow at the pore scale generate chaotic advection-involving exponential stretching and folding of fluid elements-the mechanisms by which it arises and implications of microscopic chaos for macroscopic dispersion and mixing. Prohibited in steady 2D flow due to topological constraints, these phenomena are ubiquitous due to the topological complexity inherent to all 3D porous media. Consequently 3D porous media flows generate profoundly different fluid deformation and mixing processes to those of 2D flow. The interplay of chaotic advection and broad transit time distributions can be incorporated into a continuous-time random walk (CTRW) framework to predict macroscopic solute mixing and spreading. We show how these results may be generalised to real porous architectures via a CTRW model of fluid deformation, leading to stochastic models of macroscopic dispersion and mixing which both honour the pore-scale kinematics and are directly conditioned on the pore-scale architecture.

  20. Demonstration of microbial transport into the capillary fringe via advection from below the water table

    NASA Astrophysics Data System (ADS)

    Dunn, Andrea M.; Silliman, Stephen E.; Dhamwichukorn, Srisuda; Kulpa, Charles F.

    2005-05-01

    A laboratory experiment is used to provide preliminary evidence that microbes can be advected into the capillary fringe from the region below the water table under steady flow conditions. A flow cell was packed so as to contain both a region for which pore-water pressure was greater than atmospheric pressure (termed 'below the water table') and a region, where the pore-water pressure was less than atmospheric with the pores essentially saturated with water (termed the 'capillary fringe'). Steady flow was then established through maintaining a hydraulic gradient across the medium. Green fluorescent protein (GFP) transformed bacteria ( E. coli JM109) were used to visualize migration of bacteria from below the water table into the capillary fringe. These transformed bacteria fluoresce brightly and readily when excited by standard UV light (395 nm) in 100 mL LB medium with 100 μg/mL ampicillin. The concentrations of bacterial inoculum and oxygen were adjusted to ensure GFPuv expression at a large scale. Results demonstrated that microbes can move into the capillary fringe from below the water table under horizontal hydraulic gradients. Motion from the capillary fringe into the region below the water table was also observed as was the absence of advection through regions of entrapped air below the water table.

  1. Using a Gas-Phase Tracer Test to Characterize the Impact of Landfill Gas Generation on Advective-Dispersive Transport of VOCs in the Vadose Zone

    PubMed Central

    Monger, Gregg R.; Duncan, Candice Morrison; Brusseau, Mark L.

    2015-01-01

    A gas-phase tracer test (GTT) was conducted at a landfill in Tucson, AZ, to help elucidate the impact of landfill gas generation on the transport and fate of chlorinated aliphatic volatile organic contaminants (VOCs). Sulfur hexafluoride (SF6) was used as the non-reactive gas tracer. Gas samples were collected from a multiport monitoring well located 15.2 m from the injection well, and analyzed for SF6, CH4, CO2, and VOCs. The travel times determined for SF6 from the tracer test are approximately two to ten times smaller than estimated travel times that incorporate transport by only gas-phase diffusion. In addition, significant concentrations of CH4 and CO2 were measured, indicating production of landfill gas. Based on these results, it is hypothesized that the enhanced rates of transport observed for SF6 are caused by advective transport associated with landfill gas generation. The rates of transport varied vertically, which is attributed to multiple factors including spatial variability of water content, refuse mass, refuse permeability, and gas generation. PMID:26380532

  2. Using a Gas-Phase Tracer Test to Characterize the Impact of Landfill Gas Generation on Advective-Dispersive Transport of VOCs in the Vadose Zone.

    PubMed

    Monger, Gregg R; Duncan, Candice Morrison; Brusseau, Mark L

    2014-12-01

    A gas-phase tracer test (GTT) was conducted at a landfill in Tucson, AZ, to help elucidate the impact of landfill gas generation on the transport and fate of chlorinated aliphatic volatile organic contaminants (VOCs). Sulfur hexafluoride (SF6) was used as the non-reactive gas tracer. Gas samples were collected from a multiport monitoring well located 15.2 m from the injection well, and analyzed for SF6, CH4, CO2, and VOCs. The travel times determined for SF6 from the tracer test are approximately two to ten times smaller than estimated travel times that incorporate transport by only gas-phase diffusion. In addition, significant concentrations of CH4 and CO2 were measured, indicating production of landfill gas. Based on these results, it is hypothesized that the enhanced rates of transport observed for SF6 are caused by advective transport associated with landfill gas generation. The rates of transport varied vertically, which is attributed to multiple factors including spatial variability of water content, refuse mass, refuse permeability, and gas generation.

  3. Advective heat transport associated with regional Earth degassing in central Apennine (Italy)

    NASA Astrophysics Data System (ADS)

    Chiodini, G.; Cardellini, C.; Caliro, S.; Chiarabba, C.; Frondini, F.

    2013-07-01

    In this work we show that the main springs of the central Apennine transport a total amount of heat of ˜2.2×109 J s-1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values >300 mW m-2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.

  4. Urban Mass Transportation.

    ERIC Educational Resources Information Center

    Mervine, K. E.

    This bibliography is part of a series of Environmental Resource Packets prepared under a grant from EXXON Education Foundation. The most authoritative and accessible references in the urban transportation field are reviewed. The authors, publisher, point of view, level, and summary are given for each reference. The references are categorized…

  5. Mass transport contamination study

    NASA Technical Reports Server (NTRS)

    Robertson, S. J.

    1972-01-01

    A theoretical analysis was performed to determine the effects of outgassing and waste dumping on the contamination field around an orbiting spacecraft. The spacecraft was assumed to be spherical in shape with the mass flow emitting uniformly from the spherical surface at a constant rate and in a D'Lambertian spatial distribution. The outflow of gases were assumed to be neutrally charged and of a single species with a molecular weight characteristic of a composite of the actual species involved in the mass flow. The theoretical analysis showed that, for outgassing only, less than 1.5 percent of the outgas products will return to the Skylab spacecraft as a result of intermolecular collisions. When the total mass flow from the spacecraft, including waste dumps and reaction control motor firings, was considered, it was estimated that about 30 percent will return to the spacecraft.

  6. Advective excess Ba transport as shown from sediment and trap geochemical signatures

    SciTech Connect

    Fagel, N.; Andre, L.; Dehairs, F.

    1999-08-01

    The authors report the results of a geochemical study of sediment and trap material. Major and trace elements (Zr, Ba, rare earth elements, and Th) were analyzed on bulk sedimentary material collected along the NE Atlantic margin. The aim is to test the widespread use of Ba-barite as a proxy for paleoproductivity in a continental margin area. This environment is of great interest because atmospheric-oceanic exchanges are important. In sediments, the geochemical signatures remain close to an upper crust reference, with flat shale-normalized rare earth elements patterns and constant elementary ratios. The calculated biogenic fraction of Ba or excess Ba (20--45%) remains lower than the excess Ba record in trap material (80--99%). The evolution of the geochemical signature along the margin reflects variable dilution of a detrital Post Archean Australian Shale-like component by a biogenic carbonaceous seawater-derived component. The trap material displays a wide range of variation in its trace element content (e.g., Ba {approximately}150--3,000 ppm, Zr {approximately}2--100 ppm), except for the abyssal site, which is characterized by constant signature. In the two other sites, all of the trace element contents increase with water depth and present pronounced seasonal changes at each sampled water depth. The amount of excess Ba also increases in the deepest traps, and its evolution throughout the year mimics the change of the other analyzed trace elements. In contrast, its relationships with particulate organic carbon are not obvious. In terms of fluxes, two periods of enhanced excess Ba fluxes are observed: (1) excess Ba flux increases with the detrital-like elements like Th especially during winter, and (2) excess Ba flux is enhanced without any change for the other trace elements during spring. To explain the first case, a supply through lateral advection is proposed. Such transient input of significant excess Ba flux will have a great impact on the yearly averaged

  7. Overcoming diffusion-limited processes using enhanced advective fields

    SciTech Connect

    Rasmussen, T.C.

    1995-12-31

    Many subsurface cleanup activities focus on the remediation of organic contaminants using induced advective fields. Subsurface heterogeneities cause most advective transport to occur in more permeable zones, with transport from the lower permeability units being limited by diffusion to the higher permeable units. While diffusion rates can be enhanced using thermal sources, many of the treatment strategies, including pump and treat, vapor extraction and bioremediation, are limited by mass exchange rates between the higher and lower permeability sand and clay mixtures. Instead of relying on the enhancement of diffusion rates, it is proposed that remediation strategies should focus on the enhancement of induced advective transport rates through the lower permeability units. Injection-extraction strategies using crosshole and huff-and-puff methods are presented for maximizing advective transport through lower permeability units. Optimization of the design can incorporate diffusion-enhancement technologies, bionourishment, capillary confinement in the unsaturated zone, and DNAPL slurping.

  8. Thermodynamically coupled mass transport processes in a saturated clay

    SciTech Connect

    Carnahan, C.L.

    1984-11-01

    Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.

  9. ADVECTIVE TRANSPORT OF INTERSTELLAR PLASMA INTO THE HELIOSPHERE ACROSS THE RECONNECTING HELIOPAUSE

    SciTech Connect

    Strumik, M.; Grzedzielski, S.; Czechowski, A.; Macek, W. M.; Ratkiewicz, R.

    2014-02-10

    We discuss results of magnetohydrodynamical model simulations of plasma dynamics in the proximity of the heliopause (HP). The model is shown to fit details of the magnetic field variations observed by the Voyager 1 spacecraft during the transition from the heliosphere to the local interstellar medium (LISM). We propose an interpretation of magnetic field structures observed by Voyager 1 in terms of fine-scale physical processes. Our simulations reveal an effective transport mechanism of relatively dense LISM plasma across the reconnecting HP into the heliosphere. The mechanism is associated with annihilation of magnetic sectors in the heliospheric plasma near the HP.

  10. Comparison of transport and attachment behaviors of Cryptosporidium parvum oocysts and oocyst-sized microspheres being advected through three minerologically different granular porous media

    USGS Publications Warehouse

    Mohanram, A.; Ray, C.; Harvey, R.W.; Metge, D.W.; Ryan, J.N.; Chorover, J.; Eberl, D.D.

    2010-01-01

    In order to gain more information about the fate of Cryptosporidium parvum oocysts in tropical volcanic soils, the transport and attachment behaviors of oocysts and oocyst-sized polystyrene microspheres were studied in the presence of two soils. These soils were chosen because of their differing chemical and physical properties, i.e., an organic-rich (43-46% by mass) volcanic ash-derived soil from the island of Hawaii, and a red, iron (22-29% by mass), aluminum (29-45% by mass), and clay-rich (68-76% by mass) volcanic soil from the island of Oahu. A third agricultural soil, an organic- (13% by mass) and quartz-rich (40% by mass) soil from Illinois, was included for reference. In 10-cm long flow-through columns, oocysts and microspheres advecting through the red volcanic soil were almost completely (98% and 99%) immobilized. The modest breakthrough resulted from preferential flow-path structure inadvertently created by soil-particle aggregation during the re-wetting process. Although a high (99%) removal of oocysts and microsphere within the volcanic ash soil occurred initially, further examination revealed that transport was merely retarded because of highly reversible interactions with grain surfaces. Judging from the slope of the substantive and protracted tail of the breakthrough curve for the 1.8-??m microspheres, almost all (>99%) predictably would be recovered within ~4000 pore volumes. This suggests that once contaminated, the volcanic ash soil could serve as a reservoir for subsequent contamination of groundwater, at least for pathogens of similar size or smaller. Because of the highly reversible nature of organic colloid immobilization in this soil type, C. parvum could contaminate surface water should overland flow during heavy precipitation events pick up near-surface grains to which they are attached. Surprisingly, oocyst and microsphere attachment to the reference soil from Illinois appeared to be at least as sensitive to changes in pH as was observed

  11. Dynamic characterization of external and internal mass transport in heterotrophic biofilms from microsensors measurements.

    PubMed

    Guimerà, Xavier; Dorado, Antonio David; Bonsfills, Anna; Gabriel, Gemma; Gabriel, David; Gamisans, Xavier

    2016-10-01

    Knowledge of mass transport mechanisms in biofilm-based technologies such as biofilters is essential to improve bioreactors performance by preventing mass transport limitation. External and internal mass transport in biofilms was characterized in heterotrophic biofilms grown on a flat plate bioreactor. Mass transport resistance through the liquid-biofilm interphase and diffusion within biofilms were quantified by in situ measurements using microsensors with a high spatial resolution (<50 μm). Experimental conditions were selected using a mathematical procedure based on the Fisher Information Matrix to increase the reliability of experimental data and minimize confidence intervals of estimated mass transport coefficients. The sensitivity of external and internal mass transport resistances to flow conditions within the range of typical fluid velocities over biofilms (Reynolds numbers between 0.5 and 7) was assessed. Estimated external mass transfer coefficients at different liquid phase flow velocities showed discrepancies with studies considering laminar conditions in the diffusive boundary layer near the liquid-biofilm interphase. The correlation of effective diffusivity with flow velocities showed that the heterogeneous structure of biofilms defines the transport mechanisms inside biofilms. Internal mass transport was driven by diffusion through cell clusters and aggregates at Re below 2.8. Conversely, mass transport was driven by advection within pores, voids and water channels at Re above 5.6. Between both flow velocities, mass transport occurred by a combination of advection and diffusion. Effective diffusivities estimated at different biofilm densities showed a linear increase of mass transport resistance due to a porosity decrease up to biofilm densities of 50 g VSS·L(-1). Mass transport was strongly limited at higher biofilm densities. Internal mass transport results were used to propose an empirical correlation to assess the effective diffusivity

  12. The effects of temperature and motility on the advective transport of a deep subsurface bacteria through saturated sediment

    SciTech Connect

    McCaulou, Douglas Ray

    1993-01-01

    Replicate column experiments were done to quantify the effects of temperature and bacterial motility on advective transport through repacked, but otherwise unaltered, natural aquifer sediment. The bacteria used in this study, A0500, was a flagellated, spore-forming rod isolated from the deep subsurface at DOE`s Savannah River Laboratory. Motility was controlled by turning on flagellar metabolism at 18°C but off at 40°α), estimated using a steady-state filtration model. The observed greater microsphere removal at the higher temperature agreed with the physical-chemical model, but bacteria removal at 18{degrees}C was only half that at 4°C. The sticking efficiency for non-motile A0500 (4°C) was over three times that of the motile A0500 (18°C), 0.073 versus 0.022 respectively. Analysis of complete breakthrough curves using a non-steady, kinetically limited, transport model to estimate the time scales of attachment and detachment suggested that motile A 0500 bacteria traveled twice as far as non-motile A 0500 bacteria before becoming attached. Once attached, non-motile colloids detached on the time scale of 9 to 17 days. The time scale for detachment of motile A0500 bacteria was shorter, 4 to 5 days. Results indicate that bacterial attachment was reversible and detachment was enhanced by bacterial motifity. The kinetic energy of bacterial motility changed the attachment-detachment kinetics in favor of the detached state. The chemical factors responsible for the enhanced transport are not known. However, motility may have caused weakly held bacteria to detach from the secondary minimum, and possibly from the primary minimum, as described by DLVO theory.

  13. Mechanisms of mass transport during coalescence-induced microfluidic drop dilution

    NASA Astrophysics Data System (ADS)

    Wang, William S.; Vanapalli, Siva A.

    2016-10-01

    Confinement-guided coalescence of drops in microfluidic devices is an effective means to manipulate the composition of individual droplets. Recently, Sun et al. [Lab Chip 11, 3949 (2011), 10.1039/c1lc20709a] have shown that coalescence between a long moving plug and an array of parked droplets in a microfluidic network can be used to flexibly manipulate the composition of the static droplet arrays. However, the transport mechanisms underlying this complex dilution process have not been elucidated. In this study, we develop phenomenological models and perform particle-based numerical simulations to identify the key mass transfer mechanisms influencing the concentration profiles of drops during coalescence-induced drop dilution. Motivated by experimental observations, in the simulations we consider (i) advection within the moving plug, (ii) diffusion in the moving plug and parked droplets, (iii) fluid advection due to initiation of coalescence, and (iv) advection in the coalesced plug due to the continuous phase flowing through the gutters in noncircular microchannels. We find that the dilution process is dominated by diffusion, recirculation in the moving plug, and gutter-flow-induced advection, but is only weakly affected by coalescence-induced advection. We show that the control parameters regulating dilution can be divided into those influencing the duration of mass transfer (e.g., plug length and velocity) and those affecting the rate of mass transfer (e.g., diffusion and gutter-flow-induced advection). Finally, we demonstrate that our simulations are able to predict droplet concentration profiles in experiments. The results from this study will allow better design of drop dilution microfluidic devices. Furthermore, the identification of gutter-flow-induced advection as an alternative mass transfer mechanism in two-phase flows could potentially lead to more efficient means of oil recovery from droplets trapped in porous media.

  14. Analysis of steady-state flow and advective transport in the eastern Snake River Plain aquifer system, Idaho

    USGS Publications Warehouse

    Ackerman, D.J.

    1995-01-01

    Quantitative estimates of ground-water flow directions and traveltimes for advective flow were developed for the regional aquifer system of the eastern Snake River Plain, Idaho. The work included: (1) descriptions of compartments in the aquifer that function as intermediate and regional flow systems, (2) descriptions of pathlines for flow originating at or near the water table, and (3) quantitative estimates of traveltimes for advective transport originating at or near the water table. A particle-tracking postprocessing program was used to compute pathlines on the basis of output from an existing three-dimensional steady-state flow model. The flow model uses 1980 conditions to approximate average annual conditions for 1950-80. The advective transport model required additional information about the nature of flow across model boundaries, aquifer thickness, and porosity. Porosity of two types of basalt strata has been reported for more than 1,500 individual cores from test holes, wells, and outcrops near the south side of the Idaho National Engineering Laboratory. The central 80 percent of samples had porosities of 0.08 to 0.25, the central 50 percent of samples, O. 11 to 0.21. Calibration of the model involved choosing a value for porosity that yielded the best solution. Two radiologic contaminants, iodine-129 and tritium, both introduced to the flow system about 40 years ago, are relatively conservative tracers. Iodine- 129 was considered to be more useful because of a lower analytical detection limit, longer half-life, and longer flow path. The calibration value for porosity was 0.21. Most flow in the aquifer is contained within a regional-scale compartment and follows paths that discharge to the Snake River downstream from Milner Dam. Two intermediate-scale compartments exist along the southeast side of the aquifer and near Mud Lake.One intermediate-scale compartment along the southeast side of the aquifer discharges to the Snake River near American Fails

  15. Analytical solutions for benchmarking cold regions subsurface water flow and energy transport models: one-dimensional soil thaw with conduction and advection

    USGS Publications Warehouse

    Kurylyk, Barret L.; McKenzie, Jeffrey M; MacQuarrie, Kerry T. B.; Voss, Clifford I.

    2014-01-01

    Numerous cold regions water flow and energy transport models have emerged in recent years. Dissimilarities often exist in their mathematical formulations and/or numerical solution techniques, but few analytical solutions exist for benchmarking flow and energy transport models that include pore water phase change. This paper presents a detailed derivation of the Lunardini solution, an approximate analytical solution for predicting soil thawing subject to conduction, advection, and phase change. Fifteen thawing scenarios are examined by considering differences in porosity, surface temperature, Darcy velocity, and initial temperature. The accuracy of the Lunardini solution is shown to be proportional to the Stefan number. The analytical solution results obtained for soil thawing scenarios with water flow and advection are compared to those obtained from the finite element model SUTRA. Three problems, two involving the Lunardini solution and one involving the classic Neumann solution, are recommended as standard benchmarks for future model development and testing.

  16. Advection and dispersion heat transport mechanisms in the quantification of shallow geothermal resources and associated environmental impacts.

    PubMed

    Alcaraz, Mar; García-Gil, Alejandro; Vázquez-Suñé, Enric; Velasco, Violeta

    2016-02-01

    Borehole Heat Exchangers (BHEs) are increasingly being used to exploit shallow geothermal energy. This paper presents a new methodology to provide a response to the need for a regional quantification of the geothermal potential that can be extracted by BHEs and the associated environmental impacts. A set of analytical solutions facilitates accurate calculation of the heat exchange of BHEs with the ground and its environmental impacts. For the first time, advection and dispersion heat transport mechanisms and the temporal evolution from the start of operation of the BHE are taken into account in the regional estimation of shallow geothermal resources. This methodology is integrated in a GIS environment, which facilitates the management of input and output data at a regional scale. An example of the methodology's application is presented for Barcelona, in Spain. As a result of the application, it is possible to show the strengths and improvements of this methodology in the development of potential maps of low temperature geothermal energy as well as maps of environmental impacts. The minimum and maximum energy potential values for the study site are 50 and 1800 W/m(2) for a drilled depth of 100 m, proportionally to Darcy velocity. Regarding to thermal impacts, the higher the groundwater velocity and the energy potential, the higher the size of the thermal plume after 6 months of exploitation, whose length ranges from 10 to 27 m long. A sensitivity analysis was carried out in the calculation of heat exchange rate and its impacts for different scenarios and for a wide range of Darcy velocities. The results of this analysis lead to the conclusion that the consideration of dispersion effects and temporal evolution of the exploitation prevent significant differences up to a factor 2.5 in the heat exchange rate accuracy and up to several orders of magnitude in the impacts generated.

  17. Global mass fixer algorithms for conservative tracer transport in the ECMWF model

    NASA Astrophysics Data System (ADS)

    Diamantakis, M.; Flemming, J.

    2014-01-01

    Various mass fixer algorithms (MFA) have been implemented in the Integrated Forecasting System (IFS) of ECMWF to ensure mass conservation of atmospheric tracers within the Semi-Lagrangian (SL) advection scheme. Emphasis has been placed in implementing schemes that despite being primarily global in nature adjust the solution mostly in regions where the advected field has large gradients and therefore interpolation (transport) error is assumed larger. The MFA have been tested in weather forecast, idealised and atmospheric dispersion cases. Applying these fixers to specific humidity and cloud fields did not change the accuracy of 10 day forecasts. In other words, global mass tracer conservation is achieved without deteriorating the solution accuracy. However, for longer forecast timescales or for forecasts in which correlated species are transported, experiments suggest that MFA may improve IFS forecasts.

  18. Global mass fixer algorithms for conservative tracer transport in the ECMWF model

    NASA Astrophysics Data System (ADS)

    Diamantakis, M.; Flemming, J.

    2014-05-01

    Various mass fixer algorithms (MFAs) have been implemented in the Integrated Forecasting System (IFS) of the European Centre for Medium-Range Weather Forecasts (ECMWF) to ensure mass conservation of atmospheric tracers within the semi-Lagrangian (SL) advection scheme. Emphasis has been placed in implementing schemes that despite being primarily global in nature adjust the solution mostly in regions where the advected field has large gradients and therefore interpolation (transport) error is assumed larger. The MFAs have been tested in weather forecast, idealised and atmospheric dispersion cases. Applying these fixers to specific humidity and cloud fields did not change the accuracy of 10-day forecasts. In other words, global mass tracer conservation is achieved without deteriorating the solution accuracy. However, for longer forecast timescales or for forecasts in which correlated species are transported, experiments suggest that MFAs may improve IFS forecasts.

  19. Thermally-driven advections of aerosol-rich air masses to an Alpine valley: Theoretical considerations and experimental evidences

    NASA Astrophysics Data System (ADS)

    Diémoz, Henri; Magri, Tiziana; Pession, Giordano; Zublena, Manuela; Campanelli, Monica; Gobbi, Gian Paolo; Barnaba, Francesca; Di Liberto, Luca; Dionisi, Davide

    2016-04-01

    A CHM-15k laser radar (lidar) was installed in April 2015 at the solar observatory of the Environmental Protection Agency (ARPA) of the Aosta Valley (Northern Italy, 45.74N, 7.36E, 560 m a.s.l.). The instrument operates at 1064 nm, is capable of mapping the vertical profile of aerosols and clouds up to the tropopause and is part of the Alice-net ceilometers network (www.alice-net.eu). The site is in a large Alpine valley floor, in a semi-rural context. Among the most interesting cases observed in the first months of operation, several days characterised by weak synoptic circulation and well-developed, thermally-driven up-valley winds are accompanied by the appearance of a thick aerosol layer in the afternoon. The phenomenon is frequent in Spring and Summer and is likely to be related to easterly airmass advections from polluted sites (e.g., the Po basin) rather than to local emissions. To test this hypothesis, the following method was adopted. First, some case studies were selected and the respective meteorological fields were analysed based on both observations at ground and the high-resolution output of the nonhydrostatic limited-area atmospheric prediction model maintained by the COnsortium for Small-scale MOdelling (COSMO) over the complex orography of the domain. Then, to evaluate the dynamics of the aerosol diffusion in the valley, the chemical transport 2D/3D eulerian Flexible Air quality Regional Model (FARM) was run. Finally, the three-dimensional output of the model was compared to the vertically-resolved aerosol field derived from the lidar-ceilometer soundings. The effects of up-slope winds, and the resulting subsidence along the main axis of the valley, is hypothesised to break up the aerosol layer close to the ground in the middle of the day and to drag the residual layer down into the mixing layer. The measurements by a co-located sun/sky photometer operating in the framework of the EuroSkyRad (ESR) network were additionally analysed to detect any

  20. MODFLOW-2000 : the U.S. Geological Survey modular ground-water model--documentation of the Advective-Transport Observation (ADV2) Package

    USGS Publications Warehouse

    Anderman, Evan R.; Hill, Mary Catherine

    2001-01-01

    Observations of the advective component of contaminant transport in steady-state flow fields can provide important information for the calibration of ground-water flow models. This report documents the Advective-Transport Observation (ADV2) Package, version 2, which allows advective-transport observations to be used in the three-dimensional ground-water flow parameter-estimation model MODFLOW-2000. The ADV2 Package is compatible with some of the features in the Layer-Property Flow and Hydrogeologic-Unit Flow Packages, but is not compatible with the Block-Centered Flow or Generalized Finite-Difference Packages. The particle-tracking routine used in the ADV2 Package duplicates the semi-analytical method of MODPATH, as shown in a sample problem. Particles can be tracked in a forward or backward direction, and effects such as retardation can be simulated through manipulation of the effective-porosity value used to calculate velocity. Particles can be discharged at cells that are considered to be weak sinks, in which the sink applied does not capture all the water flowing into the cell, using one of two criteria: (1) if there is any outflow to a boundary condition such as a well or surface-water feature, or (2) if the outflow exceeds a user specified fraction of the cell budget. Although effective porosity could be included as a parameter in the regression, this capability is not included in this package. The weighted sum-of-squares objective function, which is minimized in the Parameter-Estimation Process, was augmented to include the square of the weighted x-, y-, and z-components of the differences between the simulated and observed advective-front locations at defined times, thereby including the direction of travel as well as the overall travel distance in the calibration process. The sensitivities of the particle movement to the parameters needed to minimize the objective function are calculated for any particle location using the exact sensitivity

  1. The security of mass transport ticketing systems

    NASA Astrophysics Data System (ADS)

    Sel, Marc; Seys, Stefaan; Verheul, Eric

    Mass transport ticketing systems in most developed countries are making a rapid transition from ‘traditional’ paper or carton-based ticketing systems towards a contactless ‘smart card‘ based approach. This article discusses the main IT security aspects of mass transport ticketing systems (metro, bus, etc).

  2. Wind tunnel measurements of scale-by-scale energy transfer, dissipation, advection and production/transport in equilibrium and nonequilibrium decaying turbulence

    NASA Astrophysics Data System (ADS)

    Valente, Pedro; Vassilicos, Christos

    2012-11-01

    The cornerstone assumption that Cɛ ≡ ɛL /u3 ~ constant was found to breakdown in certain nonequilibrium regions of decaying grid-generated turbulence with wide power-law near -5/3 spectra where the behaviour of Cɛ is, instead, very close to Cɛ ~ ReL- 1 (Valente & Vassilicos, 2012 [Phys. Rev. Lett. 108, 214503]). We investigate nonequilibrium turbulence by measuring with two cross wire anemometers the downstream evolution of the scale-by-scale energy transfer, dissipation, advection, production and transport in the lee of a square-mesh grid and compare with a region of equilibrium turbulence. For the nonequilibrium case it is shown that the production and transport terms are negligible for scales smaller than about a third of L. For both cases it is shown that the peak of the scale-by-scale energy transfer scales as u3 / L which is the expected behaviour for equilibrium turbulence. However, for the nonequilibrium case this implies an imbalance between the energy transfer to the small scales and the dissipation. This imbalance is reflected on the small-scale advection which becomes larger in proportion to the maximum energy transfer as the turbulence decays whereas it stays proportionally constant in the equilibrium case. P. V. acknowledges the financial support from Fundação para a Ciência e a Tecnologia (SFRH/BD/61223/2009, cofinanced by POPH/FSE).

  3. Preliminary evaluation of the importance of existing hydraulic-head observation locations to advective-transport predictions, Death Valley regional flow system, California and Nevada

    SciTech Connect

    Hill, M.C.; Ely, D.M.; Tiedeman, C.R.; O'Brien, G.M.; D'Agnese, F.A.; Faunt, C.C.

    2001-08-01

    When a model is calibrated by nonlinear regression, calculated diagnostic statistics and measures of uncertainty provide a wealth of information about many aspects of the system. This report presents a method of ranking the likely importance of existing observation locations using measures of prediction uncertainty. It is suggested that continued monitoring is warranted at more important locations, and unwarranted or less warranted at less important locations. The report develops the methodology and then demonstrates it using the hydraulic-head observation locations of a three-layer model of the Death Valley regional flow system (DVRFS). The predictions of interest are subsurface transport from beneath Yucca Mountain and 14 underground Test Area (UGTA) sites. The advective component of transport is considered because it is the component most affected by the system dynamics represented by the regional-scale model being used. The problem is addressed using the capabilities of the U.S. Geological Survey computer program MODFLOW-2000, with its ADVective-Travel Observation (ADV) Package, and an additional computer program developed for this work.

  4. Mass Transport in Global Geophysical Fluids

    NASA Technical Reports Server (NTRS)

    Chao, B. F.

    1999-01-01

    Mass transports occurring in the atmosphere-hydrosphere-solid Earth-core system (the "global geophysical fluids") are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, tides, hydrological water redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. With only a few exceptions on the Earth surface, the temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have the capability of monitoring certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. These techniques include the very-long-baseline interferometry, satellite laser ranging and Doppler tracking, and the Global Positioning System, all entail global observational networks. While considerable advances have been made in observing and understanding of the dynamics of Earth's rotation, only the lowest-degree gravitational variations have been observed and limited knowledge of geocenter motion obtained. New space missions, projects and initiatives promise to further improve the measurements and hence our knowledge about the global mass transports. The latter contributes to our understanding and modeling capability of the geophysical processes that produce and regulate the mass transports, as well as the solid Earth's response to such changes in constraining the modeling of Earth's mechanical properties.

  5. Preliminary evaluation of the importance of existing hydraulic-head observation locations to advective-transport predictions, Death Valley regional flow system, California and Nevada

    USGS Publications Warehouse

    Hill, Mary C.; Ely, D. Matthew; Tiedeman, Claire R.; O'Brien, Grady M.; D'Agnese, Frank A.; Faunt, Claudia C.

    2001-01-01

    When a model is calibrated by nonlinear regression, calculated diagnostic statistics and measures of uncertainty provide a wealth of information about many aspects of the system. This report presents a method of ranking the likely importance of existing observation locations using measures of prediction uncertainty. It is suggested that continued monitoring is warranted at more important locations, and unwarranted or less warranted at less important locations. The report develops the methodology and then demonstrates it using the hydraulic-head observation locations of a three-layer model of the Death Valley regional flow system. The predictions of interest are subsurface transport from beneath Yucca Mountain and 14 Underground Test Areas. The advective component of transport is considered because it is the component most affected by the system dynamics represented by the scale model being used. The problem is addressed using the capabilities of the U.S. Geological Survey computer program MODFLOW-2000, with its ADVective-Travel Observation (ADV) Package, and an additional computer program developed for this work. The methods presented in this report are used in three ways. (1) The ratings for individual observations are obtained by manipulating the measures of prediction uncertainty, and do not involve recalibrating the model. In this analysis, observation locations are each omitted individually and the resulting increase in uncertainty in the predictions is calculated. The uncertainty is quantified as standard deviations on the simulated advective transport. The increase in uncertainty is quantified as the percent increase in the standard deviations caused by omitting the one observation location from the calculation of standard deviations. In general, observation locations associated with larger increases are rated as more important. (2) Ratings for largely geographically based groups are obtained using a straightforward extension of the method used for

  6. Mass and Momentum Turbulent Transport Experiments

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Roback, R.

    1984-01-01

    An experimental study of mixing downstream of axial and swirling coaxial jets is being conducted to obtain data for the evaluation and improvement of turbulent transport models currently employed in a variety of computational procedures used throughout the propulsion community. Effort was directed toward the acquisition of length scale and dissipation rate data that will provide more accurate inlet boundary conditions for the computational procedures and a data base to evaluate the turbulent transport models in the near jet region where recirculation does not occur. Mass and momentum turbulent transport data with a blunt inner-jet inlet configuration will also be acquired.

  7. Oceanic mass transport by mesoscale eddies.

    PubMed

    Zhang, Zhengguang; Wang, Wei; Qiu, Bo

    2014-07-18

    Oceanic transports of heat, salt, fresh water, dissolved CO2, and other tracers regulate global climate change and the distribution of natural marine resources. The time-mean ocean circulation transports fluid as a conveyor belt, but fluid parcels can also be trapped and transported discretely by migrating mesoscale eddies. By combining available satellite altimetry and Argo profiling float data, we showed that the eddy-induced zonal mass transport can reach a total meridionally integrated value of up to 30 to 40 sverdrups (Sv) (1 Sv = 10(6) cubic meters per second), and it occurs mainly in subtropical regions, where the background flows are weak. This transport is comparable in magnitude to that of the large-scale wind- and thermohaline-driven circulation.

  8. STATISTICAL METHODOLOGY FOR ESTIMATING TRANSPORT PARAMETERS: THEORY AND APPLICATIONS TO ONE-DOMENSIONAL ADVECTIVE-DISPERSIVE SYSTEMS.

    USGS Publications Warehouse

    Wagner, Brian J.; Gorelick, Steven M.

    1986-01-01

    A simulation nonlinear multiple-regression methodology for estimating parameters that characterize the transport of contaminants is developed and demonstrated. Finite difference containment transport simulation is combined with a nonlinear weighted least squares multiple-regression procedure. The technique provides optimal parameter estimates and gives statistics for assessing the reliability of these estimates under certain general assumptions about the distributions of the random measurement errors. Monte Carlo analysis is used to estimate parameter reliability for a hypothetical homogeneous soil column for which concentration data contain large random measurement errors. The value of data collected spatially versus data collected temporally was investigated for estimation of velocity, dispersion coefficient, effective porosity, first-order decay rate, and zero-order production. The use of spatial data gave estimates that were 2-3 times more reliable than estimates based on temporal data for all parameters except velocity. (Estimated author abstract) Refs.

  9. Aspects of numerical and representational methods related to the finite-difference simulation of advective and dispersive transport of freshwater in a thin brackish aquifer

    USGS Publications Warehouse

    Merritt, M.L.

    1993-01-01

    The simulation of the transport of injected freshwater in a thin brackish aquifer, overlain and underlain by confining layers containing more saline water, is shown to be influenced by the choice of the finite-difference approximation method, the algorithm for representing vertical advective and dispersive fluxes, and the values assigned to parametric coefficients that specify the degree of vertical dispersion and molecular diffusion that occurs. Computed potable water recovery efficiencies will differ depending upon the choice of algorithm and approximation method, as will dispersion coefficients estimated based on the calibration of simulations to match measured data. A comparison of centered and backward finite-difference approximation methods shows that substantially different transition zones between injected and native waters are depicted by the different methods, and computed recovery efficiencies vary greatly. Standard and experimental algorithms and a variety of values for molecular diffusivity, transverse dispersivity, and vertical scaling factor were compared in simulations of freshwater storage in a thin brackish aquifer. Computed recovery efficiencies vary considerably, and appreciable differences are observed in the distribution of injected freshwater in the various cases tested. The results demonstrate both a qualitatively different description of transport using the experimental algorithms and the interrelated influences of molecular diffusion and transverse dispersion on simulated recovery efficiency. When simulating natural aquifer flow in cross-section, flushing of the aquifer occurred for all tested coefficient choices using both standard and experimental algorithms. ?? 1993.

  10. Delft Mass Transport model DMT-2

    NASA Astrophysics Data System (ADS)

    Ditmar, Pavel; Hashemi Farahani, Hassan; Inacio, Pedro; Klees, Roland; Zhao, Qile; Guo, Jing; Liu, Xianglin; Sun, Yu; Riva, Ricardo; Ran, Jiangjun

    2013-04-01

    Gravity Recovery And Climate Experiment (GRACE) satellite mission has enormously extended our knowledge of the Earth's system by allowing natural mass transport of various origin to be quantified. This concerns, in particular, the depletion and replenishment of continental water stocks; shrinking of polar ice sheets; deformation of the Earth's crust triggered by large earthquakes, and isostatic adjustment processes. A number of research centers compute models of temporal gravity field variations and mass transport, using GRACE data as input. One of such models - Delft Mass Transport model - is being produced at the Delft University of Technology in collaboration with the GNSS Research Center of Wuhan University. A new release of this model, DMT-2, has been produced on the basis of a new (second) release of GRACE level-1b data. This model consists of a time-series of monthly solutions spanning a time interval of more than 8 years, starting from Feb. 2003. Each solution consists of spherical harmonic coefficients up to degree 120. Both unconstrained and optimally filtered solutions are obtained. The most essential improvements of the DMT-2 model, as compared to its predecessors (DMT-1 and DMT-1b), are as follows: (i) improved estimation and elimination of low-frequency noise in GRACE data, so that strong mass transport signals are not damped; (ii) computation of accurate stochastic models of data noise for each month individually with a subsequent application of frequency-dependent data weighting, which allows statistically optimal solutions to be compiled even if data noise is colored and gradually changes in time; (iii) optimized estimation of accelerometer calibration parameters; (iv) incorporation of degree 1 coefficients estimated with independent techniques; (v) usage of state-of-the-art background models to de-alias GRACE data from rapid mass transport signals (this includes the EOT11a model of ocean tides and the latest release of the AOD1B product describing

  11. Lattice Boltzmann method for the fractional advection-diffusion equation.

    PubMed

    Zhou, J G; Haygarth, P M; Withers, P J A; Macleod, C J A; Falloon, P D; Beven, K J; Ockenden, M C; Forber, K J; Hollaway, M J; Evans, R; Collins, A L; Hiscock, K M; Wearing, C; Kahana, R; Villamizar Velez, M L

    2016-04-01

    Mass transport, such as movement of phosphorus in soils and solutes in rivers, is a natural phenomenon and its study plays an important role in science and engineering. It is found that there are numerous practical diffusion phenomena that do not obey the classical advection-diffusion equation (ADE). Such diffusion is called abnormal or superdiffusion, and it is well described using a fractional advection-diffusion equation (FADE). The FADE finds a wide range of applications in various areas with great potential for studying complex mass transport in real hydrological systems. However, solution to the FADE is difficult, and the existing numerical methods are complicated and inefficient. In this study, a fresh lattice Boltzmann method is developed for solving the fractional advection-diffusion equation (LabFADE). The FADE is transformed into an equation similar to an advection-diffusion equation and solved using the lattice Boltzmann method. The LabFADE has all the advantages of the conventional lattice Boltzmann method and avoids a complex solution procedure, unlike other existing numerical methods. The method has been validated through simulations of several benchmark tests: a point-source diffusion, a boundary-value problem of steady diffusion, and an initial-boundary-value problem of unsteady diffusion with the coexistence of source and sink terms. In addition, by including the effects of the skewness β, the fractional order α, and the single relaxation time τ, the accuracy and convergence of the method have been assessed. The numerical predictions are compared with the analytical solutions, and they indicate that the method is second-order accurate. The method presented will allow the FADE to be more widely applied to complex mass transport problems in science and engineering.

  12. Lattice Boltzmann method for the fractional advection-diffusion equation

    NASA Astrophysics Data System (ADS)

    Zhou, J. G.; Haygarth, P. M.; Withers, P. J. A.; Macleod, C. J. A.; Falloon, P. D.; Beven, K. J.; Ockenden, M. C.; Forber, K. J.; Hollaway, M. J.; Evans, R.; Collins, A. L.; Hiscock, K. M.; Wearing, C.; Kahana, R.; Villamizar Velez, M. L.

    2016-04-01

    Mass transport, such as movement of phosphorus in soils and solutes in rivers, is a natural phenomenon and its study plays an important role in science and engineering. It is found that there are numerous practical diffusion phenomena that do not obey the classical advection-diffusion equation (ADE). Such diffusion is called abnormal or superdiffusion, and it is well described using a fractional advection-diffusion equation (FADE). The FADE finds a wide range of applications in various areas with great potential for studying complex mass transport in real hydrological systems. However, solution to the FADE is difficult, and the existing numerical methods are complicated and inefficient. In this study, a fresh lattice Boltzmann method is developed for solving the fractional advection-diffusion equation (LabFADE). The FADE is transformed into an equation similar to an advection-diffusion equation and solved using the lattice Boltzmann method. The LabFADE has all the advantages of the conventional lattice Boltzmann method and avoids a complex solution procedure, unlike other existing numerical methods. The method has been validated through simulations of several benchmark tests: a point-source diffusion, a boundary-value problem of steady diffusion, and an initial-boundary-value problem of unsteady diffusion with the coexistence of source and sink terms. In addition, by including the effects of the skewness β , the fractional order α , and the single relaxation time τ , the accuracy and convergence of the method have been assessed. The numerical predictions are compared with the analytical solutions, and they indicate that the method is second-order accurate. The method presented will allow the FADE to be more widely applied to complex mass transport problems in science and engineering.

  13. Modelling coupled chemico-osmotic and advective-diffusive transport of nitrate salts in the Callovo-Oxfordian Clay

    NASA Astrophysics Data System (ADS)

    Baechler, S.; Croisé, J.; Altmann, S.

    2012-12-01

    Chemico-osmosis is a recognized phenomenon taking place in clay mineral-rich sedimentary formations and a number of questions have been raised concerning its potential effects on pressure fields in and around underground radioactive waste repositories installed in such formations. Certain radioactive waste packages contain large quantities of nitrate salts whose release might result in the presence of highly concentrated salt solutions in the disposal cells, during their resaturation after closure of the facility. This would lead to large solute concentration gradients within the formation's porewater which could then potentially induce significant chemico-osmotic fluxes. In this paper, we assess the impact of chemico-osmotic fluxes on the water pressure during the post-closure period of a typical disposal cell for intermediate-level, long-lived bituminised radioactive waste in the Callovo-Oxfordian Clay formation. A numerical model of chemico-osmotic water flow and solute transport has been developed based on the work of Bader and Kooi (2005) [5], and including Bresler's dependence of osmotic efficiency on concentration and compaction state [9]. Model validity has been extended to highly concentrated solutions by incorporating a concentration-dependent activity coefficient, based on the Pitzer's equations. Results show that due to the strong dependence of the osmotic coefficient on concentration, the impact of chemico-osmosis on water flow and on the pressure field around the disposal cell is relatively low. A maximum overpressure of the order of 1 MPa was obtained. No difference in the simulation results were noticed for disposal cell solutions having concentrations higher than 1 M NaNO3. Differences between simulations were found to be almost entirely due to Bresler's relationship i.e., the model of the dependence between osmotic efficiency and concentration, and only slightly on the activity coefficient correction. Questions remain regarding the appropriate

  14. Photoinduced mass transport in azo compounds

    NASA Astrophysics Data System (ADS)

    Klismeta, K.; Teteris, J.; Aleksejeva, J.

    2013-12-01

    The photoinduced changes of optical properties in azobenzene containing compound thin films were studied under influence of polarized and non-polarized 532 nm laser light. Under influence of light azo compounds experience trans-cis isomerisation process, that can be observed in the absorbance spectrum of the sample. If the light is linearly polarized, molecules align perpendicularly to the electric field vector and as a result photoinduced dichroism and birefringence is obtained. If a known lateral polarization modulation of the light beam is present, mass transport of the azobenzene containing compound occurs. By measuring the surface relief with a profilometer the direction of mass transport can be determined. The studies of this work show that direct holographic recording of surface relief gratings can be used in optoelectronics, telecommunications and data storage.

  15. Numerical Computation of Mass Transport in Low Reynolds Number Flows and the Concentration Boundary Layer

    NASA Astrophysics Data System (ADS)

    Licata, Nicholas A.; Fuller, Nathaniel J.

    Understanding the physical mechanisms by which an individual cell interacts with its environment often requires detailed information about the fluid in which the cell is immersed. Mass transport between the interior of the cell and the external environment is influenced by the flow of the extracellular fluid and the molecular diffusivity. Analytical calculations of the flow field are challenging in simple geometries, and not generally available in more realistic cases with irregular domain boundaries. Motivated by these problems, we discuss the numerical solution of Stokes equation by implementing a Gauss-Seidel algorithm on a staggered computational grid. The computed velocity profile is used as input to numerically solve the advection-diffusion equation for mass transport. Special attention is paid to the case of two-dimensional flows at large Péclet number. The numerical results are compared with a perturbative analytical treatment of the concentration boundary layer.

  16. Tracer Transport by Deep Convection: Implications of the Connection Between Convective Mass Fluxes and Large-Scale Circulations

    NASA Astrophysics Data System (ADS)

    Lawrence, M. G.; Salzmann, M.; Tost, H.; Joeckel, P.; Lelieveld, J.

    2007-12-01

    Global chemistry-transport models (CTMs) generally simulate vertical tracer transport by deep convection separately from the advective transport due to large-scale mean winds, even though a component of the large-scale transport, for instance in the Hadley and Walker cells, occurs in deep convective updrafts. This split treatment of vertical transport can have several significant implications for CTM simulations, such as numerical diffusion, misinterpretation of the transport characteristics in convectively active regions, and underestimation of the effects of convective tracer transport on ozone and other gases. Here we show that there is a significant overlap between the convective and large-scale advective vertical transport fluxes in the CTM MATCH, and discuss the main implications for tracer transport studies which can be expected due to this. We also give an outlook to the next step of this study, in which we are examining the connection between diagnosed convective mass fluxes and the vertical fluxes in the tropical Hadley and Walker Cells using the ECHAM5/MESSy GCM, which is set up with a flexible framework allowing the use of several different convection parameterizations. From the direct comparison of multiple deep convection parameterizations within the same model we expect to gain a better sense of the relationship between parameterized deep convection and large-scale circulations, as well as of the present uncertainty due to differences in convection parameterizations. This work is anticipated to contribute to the objectives of Activity 2 (vertical tracer distributions) of AC&C.

  17. A Comparison of Mass Transport Models for Evaluating U(VI) Desorption at the Decimeter Scale

    NASA Astrophysics Data System (ADS)

    Kannappan, R.; Hay, M. B.; Miller, A. W.; Kohler, M.; Rodriguez, D.; Curtis, G. P.

    2013-12-01

    Uranium (VI) is a contaminant of concern in aquifers at many former uranium mills and processing facilities. Estimating the time-scale for desorption is important for addressing the long term risk of groundwater contamination. Determination of the rate limiting processes in desorption requires the evaluation of hydrodynamic and chemical conditions at a site along with the nature of the processes themselves. This research compares different mass transport models against the results of a decimeter scale laboratory desorption experiment. Different grain size fractions of contaminated sediments from the Naturita Uranium Mill Tailings Remediation Act site were used to create porous media systems with known physical and chemical heterogeneity. The goal is to better understand the mass transport limitations associated with uranium desorption. Two dimensional reactive transport models with no immobile zones, a single immobile zone and multiple immobile zones with a distribution of rate coefficients were compared with observations at selected monitoring locations in the domain and with the flux-averaged concentrations in the effluent. The artificial heterogeneity provided regions with a contrast of desorption rates relative to the adjacent advective rates; flow interruption events showed variable extents of the commonly observed concentration rebound indicative of mass transfer out of immobile zones which were generally reproduced by the model. A comparison of the alternative model results will be used to determine the level of complexity necessary to accurately represent mass transport in the individual breakthrough curves at sampling ports and in the integrated breakthrough curve for the entire experiment.

  18. Advection, diffusion, and delivery over a network.

    PubMed

    Heaton, Luke L M; López, Eduardo; Maini, Philip K; Fricker, Mark D; Jones, Nick S

    2012-08-01

    Many biological, geophysical, and technological systems involve the transport of a resource over a network. In this paper, we present an efficient method for calculating the exact quantity of the resource in each part of an arbitrary network, where the resource is lost or delivered out of the network at a given rate, while being subject to advection and diffusion. The key conceptual step is to partition the resource into material that does or does not reach a node over a given time step. As an example application, we consider resource allocation within fungal networks, and analyze the spatial distribution of the resource that emerges as such networks grow over time. Fungal growth involves the expansion of fluid filled vessels, and such growth necessarily involves the movement of fluid. We develop a model of delivery in growing fungal networks, and find good empirical agreement between our model and experimental data gathered using radio-labeled tracers. Our results lead us to suggest that in foraging fungi, growth-induced mass flow is sufficient to account for long-distance transport, if the system is well insulated. We conclude that active transport mechanisms may only be required at the very end of the transport pathway, near the growing tips.

  19. Physics-based agent to simulant correlations for vapor phase mass transport.

    PubMed

    Willis, Matthew P; Varady, Mark J; Pearl, Thomas P; Fouse, Janet C; Riley, Patrick C; Mantooth, Brent A; Lalain, Teri A

    2013-12-15

    Chemical warfare agent simulants are often used as an agent surrogate to perform environmental testing, mitigating exposure hazards. This work specifically addresses the assessment of downwind agent vapor concentration resulting from an evaporating simulant droplet. A previously developed methodology was used to estimate the mass diffusivities of the chemical warfare agent simulants methyl salicylate, 2-chloroethyl ethyl sulfide, di-ethyl malonate, and chloroethyl phenyl sulfide. Along with the diffusivity of the chemical warfare agent bis(2-chloroethyl) sulfide, the simulant diffusivities were used in an advection-diffusion model to predict the vapor concentrations downwind from an evaporating droplet of each chemical at various wind velocities and temperatures. The results demonstrate that the simulant-to-agent concentration ratio and the corresponding vapor pressure ratio are equivalent under certain conditions. Specifically, the relationship is valid within ranges of measurement locations relative to the evaporating droplet and observation times. The valid ranges depend on the relative transport properties of the agent and simulant, and whether vapor transport is diffusion or advection dominant.

  20. Diffuse mass transport in a porous medium

    NASA Astrophysics Data System (ADS)

    Ho, F. G.

    1981-08-01

    Variational methods are used to investigate the problems of diffusive mass transport in a porous medium. Calculations of the effective diffusivities are performed for a model pore structure generated by randomly placed, freely overlapping solid spheres all of the same radius. Effects of the tortuosity of the diffusion paths are considered. Numerical evaluations are used to test some approximate engineering models. For gaseous transition region diffusion the mean free path kinetic theory is used to derive a variational upper bound on the effective transition region diffusivity. For the simultaneous liquid or gas phase Fickian bulk diffusion in the void and Fickian surface diffusion on the pore wall surface, an analytical expression for effective diffusion coefficient is obtained and compared with the usual engineering model of parallel surface and void diffusion. The simultaneous gaseous transition region diffusion in the void and the Fickian surface diffusion on the pore wall surface are examined numerically.

  1. HEMP advection model

    SciTech Connect

    Sharp, R.W. Jr.; Barton, R.T.

    1981-01-21

    A continuous rezoning procedure has been implemented in the computational cycle of a version of the HEMP two-dimensional, Lagrange, fluid dynamics code. The rezoning problem is divided into two steps. The first step requires the solving of ordinary Lagrange equations of motion; the second step consists of adding equipotential grid relaxation along with an advective remapping scheme.

  2. Resonance wave pumping: wave mass transport pumping

    NASA Astrophysics Data System (ADS)

    Carmigniani, Remi; Violeau, Damien; Gharib, Morteza

    2016-11-01

    It has been previously reported that pinching at intrinsic resonance frequencies a valveless pump (or Liebau pump) results in a strong pulsating flow. A free-surface version of the Liebau pump is presented. The experiment consists of a closed tank with a submerged plate separating the water into a free-surface and a recirculation section connected through two openings at each end of the tank. A paddle is placed at an off-centre position at the free-surface and controlled in a heaving motion with different frequencies and amplitudes. Near certain frequencies identified as resonance frequencies through a linear potential theory analysis, the system behaves like a pump. Particle Image Velocimetry (PIV) is performed in the near free surface region and compared with simulations using Volume of Fluid (VOF) method. The mean eulerian mass flux field (ρ) is extracted. It is observed that the flow is located in the vicinity of the surface layer suggesting Stokes Drift (or Wave Mass Transport) is the source of the pumping. A model is developped to extend the linear potential theory to the second order to take into account these observations. The authors would like to acknowledge the Gordon and Betty Moore Foundation for their generous support.

  3. Final Technical Report - Stochastic Analysis of Advection-Diffusion-reaction Systems with Applications to Reactive Transport in Porous Media - DE-FG02-07ER24818

    SciTech Connect

    Karniadakis, George Em

    2014-03-11

    The main objective of this project is to develop new computational tools for uncertainty quantifica- tion (UQ) of systems governed by stochastic partial differential equations (SPDEs) with applications to advection-diffusion-reaction systems. We pursue two complementary approaches: (1) generalized polynomial chaos and its extensions and (2) a new theory on deriving PDF equations for systems subject to color noise. The focus of the current work is on high-dimensional systems involving tens or hundreds of uncertain parameters.

  4. Steady-State and Transient Groundwater Flow and Advective Transport, Eastern Snake River Plain Aquifer, Idaho National Laboratory and Vicinity, Idaho

    NASA Astrophysics Data System (ADS)

    Fisher, J. C.; Ackerman, D. J.; Rousseau, J. P.; Rattray, G. W.

    2009-12-01

    Three-dimensional steady-state and transient models of groundwater flow and advective transport through the fractured basalts and interbedded sediments of the Eastern Snake River Plain (ESRP) aquifer were developed by the U.S. Geological Survey in cooperation with the U.S. Department of Energy. The model domain covers an area of 1,940 square miles that includes most of the Idaho National Laboratory (INL). A 50-year history of waste disposal at the INL has resulted in measurable concentrations of waste contaminants in the aquifer. Numerical models simulated 1980 steady-state conditions and transient flow for 1980-95. In the transient model, streamflow infiltration was the major stress. The models were calibrated using the parameter-estimation program incorporated in MODFLOW-2000. The steady-state model reasonably simulated the observed water-table altitude and gradients. Simulation of transient conditions reproduced changes in the flow system resulting from episodic infiltration from the Big Lost River. Analysis of simulations shows that flow is (1) dominantly horizontal through interflow zones in basalt, vertical anisotropy resulting from contrasts in hydraulic conductivity of different types of basalt and the interbedded sediments, (2) temporally variable due to streamflow infiltration from the Big Lost River, and (3) moving downward downgradient of the INL. Particle-tracking simulations were used to evaluate how simulated groundwater flow paths and travel times differ between the steady-state and transient flow models, and how well model-derived groundwater flow directions and velocities compare to independently-derived estimates. Particle tracking also was used to simulate the growth of tritium plumes originating at two INL facilities over a 16 year period under steady-state and transient flow conditions (1953-68). The shape, dimensions, and areal extent of these plumes were compared to a map of the plumes for 1968 from tritium releases beginning in 1952

  5. Steady-state and transient models of groundwater flow and advective transport, Eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, Idaho

    USGS Publications Warehouse

    Ackerman, Daniel J.; Rousseau, Joseph P.; Rattray, Gordon W.; Fisher, Jason C.

    2010-01-01

    Three-dimensional steady-state and transient models of groundwater flow and advective transport in the eastern Snake River Plain aquifer were developed by the U.S. Geological Survey in cooperation with the U.S. Department of Energy. The steady-state and transient flow models cover an area of 1,940 square miles that includes most of the 890 square miles of the Idaho National Laboratory (INL). A 50-year history of waste disposal at the INL has resulted in measurable concentrations of waste contaminants in the eastern Snake River Plain aquifer. Model results can be used in numerical simulations to evaluate the movement of contaminants in the aquifer. Saturated flow in the eastern Snake River Plain aquifer was simulated using the MODFLOW-2000 groundwater flow model. Steady-state flow was simulated to represent conditions in 1980 with average streamflow infiltration from 1966-80 for the Big Lost River, the major variable inflow to the system. The transient flow model simulates groundwater flow between 1980 and 1995, a period that included a 5-year wet cycle (1982-86) followed by an 8-year dry cycle (1987-94). Specified flows into or out of the active model grid define the conditions on all boundaries except the southwest (outflow) boundary, which is simulated with head-dependent flow. In the transient flow model, streamflow infiltration was the major stress, and was variable in time and location. The models were calibrated by adjusting aquifer hydraulic properties to match simulated and observed heads or head differences using the parameter-estimation program incorporated in MODFLOW-2000. Various summary, regression, and inferential statistics, in addition to comparisons of model properties and simulated head to measured properties and head, were used to evaluate the model calibration. Model parameters estimated for the steady-state calibration included hydraulic conductivity for seven of nine hydrogeologic zones and a global value of vertical anisotropy. Parameters

  6. How to Find a Bug in Ten Thousand Lines Transport Solver? Outline of Experiences from AN Advection-Diffusion Code Verification

    NASA Astrophysics Data System (ADS)

    Zamani, K.; Bombardelli, F.

    2011-12-01

    Almost all natural phenomena on Earth are highly nonlinear. Even simplifications to the equations describing nature usually end up being nonlinear partial differential equations. Transport (ADR) equation is a pivotal equation in atmospheric sciences and water quality. This nonlinear equation needs to be solved numerically for practical purposes so academicians and engineers thoroughly rely on the assistance of numerical codes. Thus, numerical codes require verification before they are utilized for multiple applications in science and engineering. Model verification is a mathematical procedure whereby a numerical code is checked to assure the governing equation is properly solved as it is described in the design document. CFD verification is not a straightforward and well-defined course. Only a complete test suite can uncover all the limitations and bugs. Results are needed to be assessed to make a distinction between bug-induced-defect and innate limitation of a numerical scheme. As Roache (2009) said, numerical verification is a state-of-the-art procedure. Sometimes novel tricks work out. This study conveys the synopsis of the experiences we gained during a comprehensive verification process which was done for a transport solver. A test suite was designed including unit tests and algorithmic tests. Tests were layered in complexity in several dimensions from simple to complex. Acceptance criteria defined for the desirable capabilities of the transport code such as order of accuracy, mass conservation, handling stiff source term, spurious oscillation, and initial shape preservation. At the begining, mesh convergence study which is the main craft of the verification is performed. To that end, analytical solution of ADR equation gathered. Also a new solution was derived. In the more general cases, lack of analytical solution could be overcome through Richardson Extrapolation and Manufactured Solution. Then, two bugs which were concealed during the mesh convergence

  7. Isotopic and trace element sensors for fluid flow, heat- and mass transport in fractured rocks

    NASA Astrophysics Data System (ADS)

    DePaolo, D. J.

    2012-12-01

    The flow of fluids through fractured rocks is critically important in hydrothermal systems associated with geothermal energy production, base metal ore deposits, and global geochemical cycles through the enormous volumes of fluids in mid-ocean ridge systems. The nature of heat and mass transport in hydrothermal systems is determined by the spacing and volume of fractures, the nature of chemical transport in matrix blocks between fractures, the dissolution and precipitation rates of minerals in the matrix blocks, and the rates of fluid flow. Directly measuring these properties in active systems is extremely difficult, but the chemical and isotopic composition of fluids, where they can be adequately sampled, provides this information in coded form. Deciphering the signals requires appropriate models for the mineral-fluid chemical reactions and transport in the inter-fracture rock matrix. Ultimately, numerical reactive transport models are required to properly account for coupling between mineral reaction kinetics and fluid phase transport, but it is surprisingly difficult to adequately represent isotopic exchange in these models. The difficulty comes partly from the additional bookkeeping that is necessary, but more fundamentally from limitations in the detailed molecular dynamics of the mineral-fluid interfaces and how they control isotopic exchange and partitioning. Nevertheless, relatively simple analytical models illustrate how the isotopic and trace element composition of fluids relates to fracture aperture and spacing, mineral dissolution kinetics, competition between diffusive and advective transport, and competition between chemical exchange and heat exchange. The large number of geochemical parameters that can be measured potentially allows for detailed characterization of the effective mass transport and system characteristics like average fracture spacing and mineral dissolution rates. Examples of useful analytical models and applications to available data

  8. Groundwater contamination: identification of source signal by time-reverse mass transport computation and filtering

    NASA Astrophysics Data System (ADS)

    Koussis, A. S.; Mazi, K.; Lykoudis, S.; Argyriou, A.

    2003-04-01

    Source signal identification is a forensic task, within regulatory and legal activities. Estimation of the contaminant's release history by reverse-solution (stepping back in time) of the mass transport equation, partialC/partialt + u partialC/partialx = D partial^2C/ partialx^2, is an ill-posed problem (its solution is non-unique and unstable). For this reason we propose the recovery of the source signal from measured concentration profile data through a numerical technique that is based on the premise of advection-dominated transport. We derive an explicit numerical scheme by discretising the pure advection equation, partialC/ partialt + u partial C/partialx = 0, such that it also models gradient-transport by matching numerical diffusion (leading truncation error term) to physical dispersion. The match is achieved by appropriate choice of the scheme’s spatial weighting coefficient q as function of the grid Peclet number P = u Δx/D: θ = 0.5 - P-1. This is a novel and efficient direct solution approach for the signal identification problem at hand that can accommodate space-variable transport parameters as well. First, we perform numerical experiments to define proper grids (in terms of Courant {bf C} = uΔt/Δx and grid Peclet P numbers) for control of spurious oscillations (instability). We then assess recovery of source signals, from perfect as well as from error-seeded field data, considering field data resulting from single- and double-peaked source signals. With perfect data, the scheme recovers source signals with very good accuracy. With imperfect data, however, additional data conditioning is required for control of signal noise. Alternating reverse profile computation with Savitzky-Golay low-pass filtering allows the recovery of well-timed and smooth source signals that satisfy mass conservation very well. Current research focuses on: a) optimising the performance of Savitzky-Golay filters, through selection of appropriate parameters (order of least

  9. Magnetic method for stimulating transport in fluids

    DOEpatents

    Martin, James E.; Solis, Kyle J.

    2016-10-18

    A method for producing mass and heat transport in fluids, wherein the method does not rely on conventional convection, that is, it does not require gravity, a thermal gradient, or a magnetic field gradient. This method gives rise to a unique class of vigorous, field-controllable flow patterns termed advection lattices. The advection lattices can be used to transport heat and/or mass in any desired direction using only magnetic fields.

  10. Coping with model error in variational data assimilation using optimal mass transport

    NASA Astrophysics Data System (ADS)

    Ning, Lipeng; Carli, Francesca P.; Ebtehaj, Ardeshir Mohammad; Foufoula-Georgiou, Efi; Georgiou, Tryphon T.

    2014-07-01

    Classical variational data assimilation methods address the problem of optimally combining model predictions with observations in the presence of zero-mean Gaussian random errors. However, in many natural systems, uncertainty in model structure and/or model parameters often results in systematic errors or biases. Prior knowledge about such systematic model error for parametric removal is not always feasible in practice, limiting the efficient use of observations for improved prediction. The main contribution of this work is to advocate the relevance of transportation metrics for quantifying nonrandom model error in variational data assimilation for nonnegative natural states and fluxes. Transportation metrics (also known as Wasserstein metrics) originate in the theory of Optimal Mass Transport (OMT) and provide a nonparametric way to compare distributions which is natural in the sense that it penalizes mismatch in the values and relative position of "masses" in the two distributions. We demonstrate the promise of the proposed methodology using 1-D and 2-D advection-diffusion dynamics with systematic error in the velocity and diffusivity parameters. Moreover, we combine this methodology with additional regularization functionals, such as the ℓ1-norm of the state in a properly chosen domain, to incorporate both model error and potential prior information in the presence of sparsity or sharp fronts in the underlying state of interest.

  11. Thermal /Soret/ diffusion effects on interfacial mass transport rates

    NASA Technical Reports Server (NTRS)

    Rosner, D. E.

    1980-01-01

    It is shown that thermal (Soret) diffusion significantly alters convective mass transport rates and important transition temperatures in highly nonisothermal flow systems involving the transport of 'heavy' species (vapors or particles). Introduction of the Soret transport term is shown to result in mass transfer effects similar to those of 'suction' and a homogeneous chemical 'sink'. It is pointed out that this analogy provides a simple method of correlating and predicting thermal diffusion effects in the abovementioned systems.

  12. Terminology for mass transport and exchange

    PubMed Central

    BASSINGTHWAIGHTE, J. B.; CHINARD, F. P.; CRONE, C.; GORESKY, C. A.; LASSEN, N. A.; RENEMAN, R. S.; ZIERLER, K. L.

    2010-01-01

    Virtually all fields of physiological research now encompass various aspects of solute transport by convection, diffusion, and permeation across membranes. Accordingly, this set of terms, symbols, definitions, and units is proposed as a means of clear communication among workers in the physiological, engineering, and physical sciences. The goal is to provide a setting for quantitative descriptions of physiological transport phenomena. PMID:3963211

  13. Wave-induced mass transport affects daily Escherichia coli fluctuations in nearshore water

    USGS Publications Warehouse

    Ge, Zhongfu; Whitman, Richard L.; Nevers, Meredith B.; Phanikumar, Mantha S.

    2012-01-01

    Characterization of diel variability of fecal indicator bacteria concentration in nearshore waters is of particular importance for development of water sampling standards and protection of public health. Significant nighttime increase in Escherichia coli (E. coli) concentration in beach water, previously observed at marine sites, has also been identified in summer 2000 from fixed locations in waist- and knee-deep waters at Chicago 63rd Street Beach, an embayed, tideless, freshwater beach with low currents at night (approximately 0.015 m s–1). A theoretical model using wave-induced mass transport velocity for advection was developed to assess the contribution of surface waves to the observed nighttime E. coli replenishment in the nearshore water. Using average wave conditions for the summer season of year 2000, the model predicted an amount of E. coli transported from water of intermediate depth, where sediment resuspension occurred intermittently, that would be sufficient to have elevated E. coli concentration in the surf and swash zones as observed. The nighttime replenishment of E. coli in the surf and swash zones revealed here is an important phase in the cycle of diel variations of E. coli concentration in nearshore water. According to previous findings in Ge et al. (Environ. Sci. Technol. 2010, 44, 6731–6737), enhanced current circulation in the embayment during the day tends to displace and deposit material offshore, which partially sets up the system by the early evening for a new period of nighttime onshore movement. This wave-induced mass transport effect, although facilitating a significant base supply of material shoreward, can be perturbed or significantly influenced by high currents (orders of magnitude larger than a typical wave-induced mass transport velocity), current-induced turbulence, and tidal forcing.

  14. Wave-induced mass transport affects daily Escherichia coli fluctuations in nearshore water.

    PubMed

    Ge, Zhongfu; Whitman, Richard L; Nevers, Meredith B; Phanikumar, Mantha S

    2012-02-21

    Characterization of diel variability of fecal indicator bacteria concentration in nearshore waters is of particular importance for development of water sampling standards and protection of public health. Significant nighttime increase in Escherichia coli (E. coli) concentration in beach water, previously observed at marine sites, has also been identified in summer 2000 from fixed locations in waist- and knee-deep waters at Chicago 63rd Street Beach, an embayed, tideless, freshwater beach with low currents at night (approximately 0.015 m s(-1)). A theoretical model using wave-induced mass transport velocity for advection was developed to assess the contribution of surface waves to the observed nighttime E. coli replenishment in the nearshore water. Using average wave conditions for the summer season of year 2000, the model predicted an amount of E. coli transported from water of intermediate depth, where sediment resuspension occurred intermittently, that would be sufficient to have elevated E. coli concentration in the surf and swash zones as observed. The nighttime replenishment of E. coli in the surf and swash zones revealed here is an important phase in the cycle of diel variations of E. coli concentration in nearshore water. According to previous findings in Ge et al. (Environ. Sci. Technol. 2010, 44, 6731-6737), enhanced current circulation in the embayment during the day tends to displace and deposit material offshore, which partially sets up the system by the early evening for a new period of nighttime onshore movement. This wave-induced mass transport effect, although facilitating a significant base supply of material shoreward, can be perturbed or significantly influenced by high currents (orders of magnitude larger than a typical wave-induced mass transport velocity), current-induced turbulence, and tidal forcing.

  15. Mass-conservative reconstruction of Galerkin velocity fields for transport simulations

    NASA Astrophysics Data System (ADS)

    Scudeler, C.; Putti, M.; Paniconi, C.

    2016-08-01

    Accurate calculation of mass-conservative velocity fields from numerical solutions of Richards' equation is central to reliable surface-subsurface flow and transport modeling, for example in long-term tracer simulations to determine catchment residence time distributions. In this study we assess the performance of a local Larson-Niklasson (LN) post-processing procedure for reconstructing mass-conservative velocities from a linear (P1) Galerkin finite element solution of Richards' equation. This approach, originally proposed for a-posteriori error estimation, modifies the standard finite element velocities by imposing local conservation on element patches. The resulting reconstructed flow field is characterized by continuous fluxes on element edges that can be efficiently used to drive a second order finite volume advective transport model. Through a series of tests of increasing complexity that compare results from the LN scheme to those using velocity fields derived directly from the P1 Galerkin solution, we show that a locally mass-conservative velocity field is necessary to obtain accurate transport results. We also show that the accuracy of the LN reconstruction procedure is comparable to that of the inherently conservative mixed finite element approach, taken as a reference solution, but that the LN scheme has much lower computational costs. The numerical tests examine steady and unsteady, saturated and variably saturated, and homogeneous and heterogeneous cases along with initial and boundary conditions that include dry soil infiltration, alternating solute and water injection, and seepage face outflow. Typical problems that arise with velocities derived from P1 Galerkin solutions include outgoing solute flux from no-flow boundaries, solute entrapment in zones of low hydraulic conductivity, and occurrences of anomalous sources and sinks. In addition to inducing significant mass balance errors, such manifestations often lead to oscillations in concentration

  16. Interannual variability of water masses transports across A25-OVIDE section (subpolar atlantic gyre)

    NASA Astrophysics Data System (ADS)

    Carracedo, L. I.; García, M.; Mercier, H.; Conde, P.; Lherminier, P.; Pérez, F. F.; Gilcoto, M.

    2012-04-01

    The Ovide (Observatoire de la Variabilité Interannuelle à DEcennale) project has consisted on repeated trans-oceanic hydrographic section from Greenland to Portugal every other year (from 2002 to 2010). This project is part of the CLIVAR (Climate Variability and Predictability) and CARBOOCEAN international programs, both focused on ocean climate variability. The section crosses the main currents implicated in the North Atlantic Meridional Overturning Circulation (MOC), and is very close to the previous A25 section ("Fourex") of the WOCE (World Ocean Circulation Experiment) performed in 1997. The North Atlantic Ocean plays a crucial role in the global thermohaline circulation as can be considered the departure point of the MOC, where the warm salty waters are transformed by deep winter convection into deep waters. The water mass distribution in the section is derived by means of OMP method for every cruise, and then combined with absolute velocity fields to provide the relative contribution from each water mass to the final transport values. The water mass circulation pattern across the section is then discussed within the context of interannual variability of the main MOC components, in terms of the different water mass components. The mean transport for each of these water masses results in 11.7 ± 2.6 Sv (1 Sv = 106 m3 s-1) for central waters, 2.0 ± 0.69 Sv for SubArtic Intermediate Water, 0.58 ± 0.51 Sv for Antartic Intermediate water and MW 0.15 ± 1.3 Sv, all of them flowing northward and contributing to the upper branch of the MOC. On other hand, the lower MOC branch transports southward -8.5 ± 2.0 Sv of LSW, -3.3 ± 0.33 Sv of Iceland-Scotland Overflow Water and -1.3 ± 0.92 Sv of Denmark Strait Overflow Water, with an almost zero net transport of North East Atlantic Deep Water of 0.17 ± 1.0 Sv. The knowledge of the variability and contribution of each water mass itself will allow a better understanding of the global circulation mechanisms in the

  17. Mass and momentum turbulent transport experiments with confined coaxial jets

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Bennett, J. C.

    1984-01-01

    An experimental study of mixing downstream of coaxial jets discharging into an expanded circular duct was conducted to obtain data for the evaluation and improvement of turbulent transport models. A combination of turbulent momentum transport rate and two components of velocity data were obtained from simultaneous measurements with a two-color LV system. A combination of turbulent mass transport rate, concentration and velocity data were obtained from simultaneous measurements with laser velocimeter (LV) and laser induced fluorescence (LIF) systems.

  18. Mass and Momentum Turbulent Transport Experiments

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.

    1983-01-01

    The downstream mixing of coaxial jets discharging in an expanded duct was studied to improve turbulent transport models which are used in computational procedures throughout the propulsion community for combustor flow modeling. Laser velocimeter (LV) and laser induced fluorescence (LIF) techniques were used to measure velocities and concentration and flow visualization techniques to determine the time dependent characteristics of the flow and the scale of the turbulent structure.

  19. Mass Transportation Operators' Beliefs about Visual Impairment.

    ERIC Educational Resources Information Center

    Almon, Pamela A.

    2001-01-01

    A study investigated 171 mass transit operators' beliefs about blindness and the factors that may influence their beliefs. There were statistically significant differences among transit operators' beliefs on the basis of the operators' ethnicity. White participants had significantly fewer irrational beliefs about blindness than Hispanic and…

  20. LAYER DEPENDENT ADVECTION IN CMAQ

    EPA Science Inventory

    The advection methods used in CMAQ require that the Courant-Friedrichs-Lewy (CFL) condition be satisfied for numerical stability and accuracy. In CMAQ prior to version 4.3, the ADVSTEP algorithm established CFL-safe synchronization and advection timesteps that were uniform throu...

  1. Space Geodesy Monitoring Mass Transport in Global Geophysical Fluids

    NASA Technical Reports Server (NTRS)

    Chao, Benjamin F.

    2004-01-01

    Mass transports occurring in the atmosphere-hydrosphere-cryosphere-solid Earth-core system (the 'global geophysical fluids') are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, oceanic and solid tides, hydrological water and idsnow redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. The temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have proven to be an effective tool in monitorihg certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. Considerable advances have been made in recent years in observing and understanding of these geodynamic effects. This paper will use several prominent examples to illustrate the triumphs in research over the past years under a 'Moore's law' in space geodesy. New space missions and projects promise to further advance our knowledge about the global mass transports. The latter contributes to our understanding of the geophysical processes that produce and regulate the mass transports, as well as of the solid Earth's response to such changes in terms of Earth's mechanical properties.

  2. Pangolin v1.0, a conservative 2-D advection model towards large-scale parallel calculation

    NASA Astrophysics Data System (ADS)

    Praga, A.; Cariolle, D.; Giraud, L.

    2015-02-01

    To exploit the possibilities of parallel computers, we designed a large-scale bidimensional atmospheric advection model named Pangolin. As the basis for a future chemistry-transport model, a finite-volume approach for advection was chosen to ensure mass preservation and to ease parallelization. To overcome the pole restriction on time steps for a regular latitude-longitude grid, Pangolin uses a quasi-area-preserving reduced latitude-longitude grid. The features of the regular grid are exploited to reduce the memory footprint and enable effective parallel performances. In addition, a custom domain decomposition algorithm is presented. To assess the validity of the advection scheme, its results are compared with state-of-the-art models on algebraic test cases. Finally, parallel performances are shown in terms of strong scaling and confirm the efficient scalability up to a few hundred cores.

  3. An upscaled approach for transport in media with extended tailing due to back-diffusion using analytical and numerical solutions of the advection dispersion equation.

    PubMed

    Parker, Jack C; Kim, Ungtae

    2015-11-01

    The mono-continuum advection-dispersion equation (mADE) is commonly regarded as unsuitable for application to media that exhibit rapid breakthrough and extended tailing associated with diffusion between high and low permeability regions. This paper demonstrates that the mADE can be successfully used to model such conditions if certain issues are addressed. First, since hydrodynamic dispersion, unlike molecular diffusion, cannot occur upstream of the contaminant source, models must be formulated to prevent "back-dispersion." Second, large variations in aquifer permeability will result in differences between volume-weighted average concentration (resident concentration) and flow-weighted average concentration (flux concentration). Water samples taken from wells may be regarded as flux concentrations, while soil samples may be analyzed to determine resident concentrations. While the mADE is usually derived in terms of resident concentration, it is known that a mADE of the same mathematical form may be written in terms of flux concentration. However, when solving the latter, the mathematical transformation of a flux boundary condition applied to the resident mADE becomes a concentration type boundary condition for the flux mADE. Initial conditions must also be consistent with the form of the mADE that is to be solved. Thus, careful attention must be given to the type of concentration data that is available, whether resident or flux concentrations are to be simulated, and to boundary and initial conditions. We present 3-D analytical solutions for resident and flux concentrations, discuss methods of solving numerical models to obtain resident and flux concentrations, and compare results for hypothetical problems. We also present an upscaling method for computing "effective" dispersivities and other mADE model parameters in terms of physically meaningful parameters in a diffusion-limited mobile-immobile model. Application of the latter to previously published studies of

  4. Capillary deposition of advected floating particles

    NASA Astrophysics Data System (ADS)

    Dressaire, Emilie; Debaisieux, Aymeric; Gregori, Federico

    2016-11-01

    The deposition and aggregation of particles flowing through a confined environment can dramatically hinder the transport of suspensions. Yet, the mechanisms responsible for the deposition of particles in shear flow are not fully understood. Here, we use an experimental model system in which floating particles are advected on the surface of a water channel and deposited on fixed obstacles through attractive capillary effects. By varying the flow rate of the liquid, the wetting properties and size of the particles and obstacles, we can tune the magnitude of the capillary and hydrodynamic forces that determine the probability of deposition and the equilibrium position on the substrate. We show that arrays of obstacles can be designed to efficiently capture the floating particles advected by the flow.

  5. Advection around ventilated U-shaped burrows: A model study

    NASA Astrophysics Data System (ADS)

    Brand, Andreas; Lewandowski, JöRg; Hamann, Enrico; Nützmann, Gunnar

    2013-05-01

    Advective transport in the porous matrix of sediments surrounding burrows formed by fauna such as Chironomus plumosus has been generally neglected. A positron emission tomography study recently revealed that the pumping activity of the midge larvae can indeed induce fluid flow in the sediment. We present a numerical model study which explores the conditions at which advective transport in the sediment becomes relevant. A 0.15 m deep U-shaped burrow with a diameter of 0.002 m within the sediment was represented in a 3-D domain. Fluid flow in the burrow was calculated using the Navier-Stokes equation for incompressible laminar flow in the burrow, and flow in the sediment was described by Darcy's law. Nonreactive and reactive transport scenarios were simulated considering diffusion and advection. The pumping activity of the model larva results in considerable advective flow in the sediment at reasonable high permeabilities with flow velocities of up to 7.0 × 10-6 m s-1 close to the larva for a permeability of 3 × 10-12 m2. At permeabilities below 7 × 10-13 m2 advection is negligible compared to diffusion. Reactive transport simulations using first-order kinetics for oxygen revealed that advective flux into the sediment downstream of the pumping larva enhances sedimentary uptake, while the advective flux into the burrow upstream of the larvae inhibits diffusive sedimentary uptake. Despite the fact that both effects cancel each other with respect to total solute uptake, the advection-induced asymmetry in concentration distribution can lead to a heterogeneous solute and redox distribution in the sediment relevant to complex reaction networks.

  6. Optical Field-Induced Mass Transport in Soft Materials

    NASA Astrophysics Data System (ADS)

    Teteris, J.; Reinfelde, M.; Aleksejeva, J.; Gertners, U.

    The dependence of the surface relief formation in amorphous chalcogenide (As2S3 and As-S-Se) and Disperse Red 1 dye grafted polyurethane polymer films on the polarization state of holographic recording light beams was studied. It is shown that the direction of lateral mass transport on the film surface is determined by the direction of light electric vector and photoinduced anisotropy in the film. We propose a photoinduced dielectropfhoretic model to explain the photoinduced mass transport in amorphous films. Model is based on the photoinduced softening of the matrix, formation of defects with enhanced or decreased polarizability, and their drift under the electrical field gradient of light.

  7. Mass and Momentum Turbulent Transport Experiments with Confined Coaxial Jets

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Bennett, J. C.

    1981-01-01

    Downstream mixing of coaxial jets discharging in an expanded duct was studied to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the propulsion community for combustor flow modeling. Flow visualization studies showed four major shear regions occurring; a wake region immediately downstream of the inlet jet inlet duct; a shear region further downstream between the inner and annular jets; a recirculation zone; and a reattachment zone. A combination of turbulent momentum transport rate and two velocity component data were obtained from simultaneous measurements with a two color laser velocimeter (LV) system. Axial, radial and azimuthal velocities and turbulent momentum transport rate measurements in the r-z and r-theta planes were used to determine the mean value, second central moment (or rms fluctuation from mean), skewness and kurtosis for each data set probability density function (p.d.f.). A combination of turbulent mass transport rate, concentration and velocity data were obtained system. Velocity and mass transport in all three directions as well as concentration distributions were used to obtain the mean, second central moments, skewness and kurtosis for each p.d.f. These LV/LIF measurements also exposed the existence of a large region of countergradient turbulent axial mass transport in the region where the annular jet fluid was accelerating the inner jet fluid.

  8. The China Clipper - Fast advective transport of radon-rich air from the Asian boundary layer to the upper troposphere near California

    NASA Technical Reports Server (NTRS)

    Kritz, Mark A.; Le Roulley, Jean-Claude; Danielsen, Edwin F.

    1990-01-01

    A series of upper tropospheric radon concentration measurements made over the eastern Pacific and west coast of the U.S. during the summers of 1983 and 1984 has revealed the occurrence of unexpectedly high radon concentrations for 9 of the 61 measurements. A frequency distribution plot of the set of 61 observations shows a distinct bimodal distribution, with approximately 2/5 of the observations falling close to 1 pCi/SCM, and 3/5 falling in a high concentration mode centered at about 11 pCi/SCM. Trajectory and synoptic analyses for two of the flights on which such high radon concentrations were observed indicate that this radon-rich air originated in the Asian boundary layer, ascended in cumulus updrafts, and was carried eastward in the fast moving air on the anticyclonic side of the upper tropospheric jet. The results suggest that the combination of rapid vertical transport from the surface boundary layer to the upper troposphere, followed by rapid horizontal transport eastward represents an efficient mode of long-transport for other, chemically reactive atmospheric trace constituents.

  9. A multi-resolution approach for optimal mass transport

    NASA Astrophysics Data System (ADS)

    Dominitz, Ayelet; Angenent, Sigurd; Tannenbaum, Allen

    2007-09-01

    Optimal mass transport is an important technique with numerous applications in econometrics, fluid dynamics, automatic control, statistical physics, shape optimization, expert systems, and meteorology. Motivated by certain problems in image registration and medical image visualization, in this note, we describe a simple gradient descent methodology for computing the optimal L2 transport mapping which may be easily implemented using a multiresolution scheme. We also indicate how the optimal transport map may be computed on the sphere. A numerical example is presented illustrating our ideas.

  10. Mass transfer and transport in a geologic environment

    SciTech Connect

    Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.; Ahn, J.; Kajiwara, S.; Kim, C.L.; Kimura, H.; Lung, H.; Williams, W.J.; Zavoshy, S.J.

    1985-04-01

    This report is in a continuing series of reports that present analytic solutions for the dissolution and hydrogeologic transport of radionuclides from geologic repositories of nuclear waste. Previous reports have dealt mainly with radionuclide transport in the far-field, away from the effects of the repository. In the present report, the emphasis is on near-field processes, the transfer and transport of radionuclides in the vicinity of the waste packages. The primary tool used in these analyses is mass transfer theory from chemical engineering. The thrust of our work is to develop methods for predicting the performance of geologic repositories. The subjects treated in the present report are: radionuclide transport from a spherical-equivalent waste form through a backfill; analysis of radionuclide transport through a backfill using a non-linear sorption isotherm; radionuclide transport from a prolate spheroid-equivalent waste form with a backfill; radionuclide transport from a spherical-equivalent waste form through a backfill, where the solubility, diffusivity and retardation coefficients are temperature dependent; a coupled near-field, far-field analysis where dissolution and migration rates are temperature dependent; transport of radionuclides from a point source in a three-dimensional flow field; and a general solution for the transport of radioactive chains in geologic media. There are several important results from the numerical evaluations. First, radioactive decay, higher sorption in the rock and the backfill steepens the gradient for mass transfer, and lead to higher dissolution rates. This is contrary to what was expected by some other workers, but is shown clearly in the analytical solutions. Second, the backfill serves to provide sorption sites so that there is a delay in the arrival of radionuclides in the rock, although this effect is not so important for the steady-state transport of long-lived radionuclides.

  11. Degree-1 Surface Mass Transport and Geocenter Motion

    NASA Astrophysics Data System (ADS)

    Wu, X.

    2015-12-01

    The longest-wavelength and hemisphere asymmetric surface mass transport is characterized by three degree-one spherical harmonic components. Such mass transport modes cause geocenter motion between the center-of-mass of the total Earth system (CM) and the center-of-figure of the solid Earth surface (CF), and deforms the solid Earth. GRACE's K-band ranging data system is not sensitive to these three variation modes. For a complete spherical harmonic spectral coverage of mass transport, degree-1 surface mass changes estimated through geocenter motion or degree-1 mass/deformation signatures from other space geodetic techniques should be combined with GRACE's time-variable gravity data. The degree-1 coefficients are critically important for mass variation assessments over large regions. For example, 1 mm error in geocenter motion can result in an error of 190 gigatons of global oceanic water mass change or, equivalently, an error of 0.5 mm of global mean sea level change when the geocenter motion is converted to degree-1 mass and combined with GRACE data. Yet, several different methods of geocenter motion estimation differ in results by more than 1 mm in annual amplitude. These differences have to be resolved after 13 years of successful GRACE operation. Recently, the difference between results from direct satellite laser ranging (SLR) determination and from a global inversion of Global Navigation Satellite System (GNSS) deformation measurements, GRACE, and an ocean bottom pressure (OBP) model has been largely reconciled as due to SLR's sparse station distribution. This result and our current efforts to examine possible systematic errors in GNSS data and the OBP model will be discussed along with a future perspective.

  12. Mass Transport Through Carbon Nanotube-Polystyrene Bundles

    NASA Astrophysics Data System (ADS)

    Lin, Rongzhou; Tran, Tuan

    2016-05-01

    Carbon nanotubes have been widely used as test channels to study nanofluidic transport, which has been found to have distinctive properties compared to transport of fluids in macroscopic channels. A long-standing challenge in the study of mass transport through carbon nanotubes (CNTs) is the determination of flow enhancement. Various experimental investigations have been conducted to measure the flow rate through CNTs, mainly based on either vertically aligned CNT membranes or individual CNTs. Here, we proposed an alternative approach that can be used to quantify the mass transport through CNTs. This is a simple method relying on the use of carbon nanotube-polystyrene bundles, which are made of CNTs pulled out from a vertically aligned CNT array and glued together by polystyrene. We experimentally showed by using fluorescent tagging that the composite bundles allowed measureable and selective mass transport through CNTs. This type of composite bundle may be useful in various CNT research areas as they are simple to fabricate, less likely to form macroscopic cracks, and offer a high density of CNT pores while maintaining the aligned morphology of CNTs.

  13. Mass transport mechanism in porous fuel cell electrodes

    NASA Technical Reports Server (NTRS)

    Jonsson, I.; Lindholm, I.

    1969-01-01

    Results of experiments on hydrogen-oxygen fuel cells show that higher current densities are obtained with cell anodes having a 100 micron thin active layer of porous nickel containing silver electrocatalyst. Increase in current density is attributed to a convective mass transport mechanism.

  14. Optimal Mass Transport for Shape Matching and Comparison

    PubMed Central

    Su, Zhengyu; Wang, Yalin; Shi, Rui; Zeng, Wei; Sun, Jian; Luo, Feng; Gu, Xianfeng

    2015-01-01

    Surface based 3D shape analysis plays a fundamental role in computer vision and medical imaging. This work proposes to use optimal mass transport map for shape matching and comparison, focusing on two important applications including surface registration and shape space. The computation of the optimal mass transport map is based on Monge-Brenier theory, in comparison to the conventional method based on Monge-Kantorovich theory, this method significantly improves the efficiency by reducing computational complexity from O(n2) to O(n). For surface registration problem, one commonly used approach is to use conformal map to convert the shapes into some canonical space. Although conformal mappings have small angle distortions, they may introduce large area distortions which are likely to cause numerical instability thus resulting failures of shape analysis. This work proposes to compose the conformal map with the optimal mass transport map to get the unique area-preserving map, which is intrinsic to the Riemannian metric, unique, and diffeomorphic. For shape space study, this work introduces a novel Riemannian framework, Conformal Wasserstein Shape Space, by combing conformal geometry and optimal mass transport theory. In our work, all metric surfaces with the disk topology are mapped to the unit planar disk by a conformal mapping, which pushes the area element on the surface to a probability measure on the disk. The optimal mass transport provides a map from the shape space of all topological disks with metrics to the Wasserstein space of the disk and the pullback Wasserstein metric equips the shape space with a Riemannian metric. We validate our work by numerous experiments and comparisons with prior approaches and the experimental results demonstrate the efficiency and efficacy of our proposed approach. PMID:26440265

  15. Optimal mass transport for shape matching and comparison.

    PubMed

    Su, Zhengyu; Wang, Yalin; Shi, Rui; Zeng, Wei; Sun, Jian; Luo, Feng; Gu, Xianfeng

    2015-11-01

    Surface based 3D shape analysis plays a fundamental role in computer vision and medical imaging. This work proposes to use optimal mass transport map for shape matching and comparison, focusing on two important applications including surface registration and shape space. The computation of the optimal mass transport map is based on Monge-Brenier theory, in comparison to the conventional method based on Monge-Kantorovich theory, this method significantly improves the efficiency by reducing computational complexity from O(n(2)) to O(n) . For surface registration problem, one commonly used approach is to use conformal map to convert the shapes into some canonical space. Although conformal mappings have small angle distortions, they may introduce large area distortions which are likely to cause numerical instability thus resulting failures of shape analysis. This work proposes to compose the conformal map with the optimal mass transport map to get the unique area-preserving map, which is intrinsic to the Riemannian metric, unique, and diffeomorphic. For shape space study, this work introduces a novel Riemannian framework, Conformal Wasserstein Shape Space, by combing conformal geometry and optimal mass transport theory. In our work, all metric surfaces with the disk topology are mapped to the unit planar disk by a conformal mapping, which pushes the area element on the surface to a probability measure on the disk. The optimal mass transport provides a map from the shape space of all topological disks with metrics to the Wasserstein space of the disk and the pullback Wasserstein metric equips the shape space with a Riemannian metric. We validate our work by numerous experiments and comparisons with prior approaches and the experimental results demonstrate the efficiency and efficacy of our proposed approach.

  16. An advection scheme based on the combination of particle mesh method and pure Lagrangian approach

    NASA Astrophysics Data System (ADS)

    Arsenic, Ilija; Mihailovic, Dragutin T.; Kapor, Darko

    2011-11-01

    Possibility of using pure Lagrangian approach in modeling transport phenomena is described in this paper. The application of pure Lagrangian approach in real atmospheric field induces highly irregular spatial distribution of grid points, after only a few time steps. In order to avoid problems caused by that irregularity, a quasi interpolation procedure is proposed. Proposed interpolation procedure is similar to the radial basis functions interpolation and does not impose any demands about spatial distribution of the grid points or about continuity and differentiability of the field that needs to be interpolated. Besides that, proposed procedure is explicitly mass conserving. Combination of particle mesh method and pure Lagrangian approach creates efficient transport scheme that does not produce any new local maxima and minima in advected field. In proposed advection scheme motion of points are performed in Lagrangian manner while spatial derivatives are evaluated on the basis of values interpolated onto regular grid. Applicability of proposed advection scheme in an unambiguous way is proved by performing "standard" numerical tests with (i) the slotted cylinder under solid body rotation, (ii) the test with Doswell's idealized cyclogenesis as well as (iii) integration of shallow water equations.

  17. Area-preservation mapping using optimal mass transport.

    PubMed

    Zhao, Xin; Su, Zhengyu; Gu, Xianfeng David; Kaufman, Arie; Sun, Jian; Gao, Jie; Luo, Feng

    2013-12-01

    We present a novel area-preservation mapping/flattening method using the optimal mass transport technique, based on the Monge-Brenier theory. Our optimal transport map approach is rigorous and solid in theory, efficient and parallel in computation, yet general for various applications. By comparison with the conventional Monge-Kantorovich approach, our method reduces the number of variables from O(n2) to O(n), and converts the optimal mass transport problem to a convex optimization problem, which can now be efficiently carried out by Newton's method. Furthermore, our framework includes the area weighting strategy that enables users to completely control and adjust the size of areas everywhere in an accurate and quantitative way. Our method significantly reduces the complexity of the problem, and improves the efficiency, flexibility and scalability during visualization. Our framework, by combining conformal mapping and optimal mass transport mapping, serves as a powerful tool for a broad range of applications in visualization and graphics, especially for medical imaging. We provide a variety of experimental results to demonstrate the efficiency, robustness and efficacy of our novel framework.

  18. Demonstrating the influence of compression on artery wall mass transport.

    PubMed

    O'Connell, Barry M; Walsh, Michael T

    2010-04-01

    The development of restenosis within the coronary arteries after a stenting procedure has been addressed with the development of the drug eluting stent device. However, in recent times the superiority of the drug eluting stent over bare metal stents has been brought into question. A lack of knowledge regarding the behavior of drug transport from the drug eluting devices contributes to this uncertainty. Questions arise as to whether drug eluting stents deliver sufficient amounts of therapeutic agents into the artery wall to suppress restenosis. Published investigations in this area have focused primarily on trends associated with how variations in stenting conditions affect mass transport behavior. However, experimentally validated numerical models that simulate mass transport within the artery wall are lacking. A novel experimental model was developed to validate computational predictions of species diffusion into a porous medium and an investigation into how stent strut compression influences mass transport was conducted. The study revealed that increased compressive forces on a porous media reduced the ability of species to diffuse through that media, and in relation to drug eluting stents will contribute to a reduction in therapeutic levels of drugs within the wall.

  19. Optimal Filtering in Mass Transport Modeling From Satellite Gravimetry Data

    NASA Astrophysics Data System (ADS)

    Ditmar, P.; Hashemi Farahani, H.; Klees, R.

    2011-12-01

    Monitoring natural mass transport in the Earth's system, which has marked a new era in Earth observation, is largely based on the data collected by the GRACE satellite mission. Unfortunately, this mission is not free from certain limitations, two of which are especially critical. Firstly, its sensitivity is strongly anisotropic: it senses the north-south component of the mass re-distribution gradient much better than the east-west component. Secondly, it suffers from a trade-off between temporal and spatial resolution: a high (e.g., daily) temporal resolution is only possible if the spatial resolution is sacrificed. To make things even worse, the GRACE satellites enter occasionally a phase when their orbit is characterized by a short repeat period, which makes it impossible to reach a high spatial resolution at all. A way to mitigate limitations of GRACE measurements is to design optimal data processing procedures, so that all available information is fully exploited when modeling mass transport. This implies, in particular, that an unconstrained model directly derived from satellite gravimetry data needs to be optimally filtered. In principle, this can be realized with a Wiener filter, which is built on the basis of covariance matrices of noise and signal. In practice, however, a compilation of both matrices (and, therefore, of the filter itself) is not a trivial task. To build the covariance matrix of noise in a mass transport model, it is necessary to start from a realistic model of noise in the level-1B data. Furthermore, a routine satellite gravimetry data processing includes, in particular, the subtraction of nuisance signals (for instance, associated with atmosphere and ocean), for which appropriate background models are used. Such models are not error-free, which has to be taken into account when the noise covariance matrix is constructed. In addition, both signal and noise covariance matrices depend on the type of mass transport processes under

  20. Mass Transport and Shear Stress in the Carotid Artery Bifurcation

    NASA Astrophysics Data System (ADS)

    Gorder, Riley; Aliseda, Alberto

    2010-11-01

    The carotid artery bifurcation (CAB) is one of the leading sites for atherosclerosis, a major cause of death and disability in the developed world. The specific processes by which the complex flow found at the bifurcation and carotid sinus promotes plaque formation and growth are not fully understood. Shear stress, mass transport, and flow residence times are considered key factors. Although the governing equations closely link shear stress and mass transfer, the pulsatile, transitional, and detached flow found at the CAB can lead to differences between regions of WSS and mass transfer statistics. In this study, CAB geometries are reconstructed from patient specific 3D ultrasound medical imaging. Using ANSYS FLUENT, the fluid flow and scalar transport was solved using realistic flow conditions and various mass transfer boundary conditions. The spatial and temporal resolution was validated against the analytical solution of the Graetz-Nusselt problem with constant wall flux to ensure the scalar transport is resolved for a Peclet number up to 100,000. High residence time regions are investigated by determining the number of cardiac cycles required to flush out the carotid sinus. The correlations between regions of low WSS, high OSI, and scalar concentration are computed and interpreted in the context of atherosclerotic plaque origin and progression.

  1. Modelling aeolian sand transport using a dynamic mass balancing approach

    NASA Astrophysics Data System (ADS)

    Mayaud, Jerome R.; Bailey, Richard M.; Wiggs, Giles F. S.; Weaver, Corinne M.

    2017-03-01

    Knowledge of the changing rate of sediment flux in space and time is essential for quantifying surface erosion and deposition in desert landscapes. Whilst many aeolian studies have relied on time-averaged parameters such as wind velocity (U) and wind shear velocity (u*) to determine sediment flux, there is increasing field evidence that high-frequency turbulence is an important driving force behind the entrainment and transport of sand. At this scale of analysis, inertia in the saltation system causes changes in sediment transport to lag behind de/accelerations in flow. However, saltation inertia has yet to be incorporated into a functional sand transport model that can be used for predictive purposes. In this study, we present a new transport model that dynamically balances the sand mass being transported in the wind flow. The 'dynamic mass balance' (DMB) model we present accounts for high-frequency variations in the horizontal (u) component of wind flow, as saltation is most strongly associated with the positive u component of the wind. The performance of the DMB model is tested by fitting it to two field-derived (Namibia's Skeleton Coast) datasets of wind velocity and sediment transport: (i) a 10-min (10 Hz measurement resolution) dataset; (ii) a 2-h (1 Hz measurement resolution) dataset. The DMB model is shown to outperform two existing models that rely on time-averaged wind velocity data (e.g. Radok, 1977; Dong et al., 2003), when predicting sand transport over the two experiments. For all measurement averaging intervals presented in this study (10 Hz-10 min), the DMB model predicted total saltation count to within at least 0.48%, whereas the Radok and Dong models over- or underestimated total count by up to 5.50% and 20.53% respectively. The DMB model also produced more realistic (less 'peaky') time series of sand flux than the other two models, and a more accurate distribution of sand flux data. The best predictions of total sand transport are achieved using

  2. Optimum periodicity of repeated contractile actions applied in mass transport

    PubMed Central

    Ahn, Sungsook; Lee, Sang Joon

    2015-01-01

    Dynamically repeated periodic patterns are abundant in natural and artificial systems, such as tides, heart beats, stock prices, and the like. The characteristic repeatability and periodicity are expected to be optimized in effective system-specific functions. In this study, such optimum periodicity is experimentally evaluated in terms of effective mass transport using one-valve and multi-valve systems working in contractile fluid flows. A set of nanoscale gating functions is utilized, operating in nanocomposite networks through which permeates selectively pass under characteristic contractile actions. Optimized contractile periodicity exists for effective energy impartment to flow in a one-valve system. In the sequential contractile actions for a multi-valve system, synchronization with the fluid flow is critical for effective mass transport. This study provides fundamental understanding on the various repeated periodic patterns and dynamic repeatability occurring in nature and mechanical systems, which are useful for broad applications. PMID:25622949

  3. Metal intercalation-induced selective adatom mass transport on graphene

    SciTech Connect

    Liu, Xiaojie; Wang, Cai -Zhuang; Hupalo, Myron; Lin, Hai -Qing; Ho, Kai -Ming; Thiel, Patricia A.; Tringides, Michael C.

    2016-03-29

    Recent experiments indicate that metal intercalation is a very effective method to manipulate the graphene-adatom interaction and control metal nanostructure formation on graphene. A key question is mass transport, i.e., how atoms deposited uniformly on graphene populate different areas depending on the local intercalation. Using first-principles calculations, we show that partially intercalated graphene, with a mixture of intercalated and pristine areas, can induce an alternating electric field because of the spatial variations in electron doping, and thus, an oscillatory electrostatic potential. As a result, this alternating field can change normal stochastic adatom diffusion to biased diffusion, leading to selective mass transport and consequent nucleation, on either the intercalated or pristine areas, depending on the charge state of the adatoms.

  4. Miocene mass-transport sediments, Troodos Massif, Cyprus

    USGS Publications Warehouse

    Lord, A.R.; Harrison, R.W.; BouDagher-Fadel, M.; Stone, B.D.; Varol, O.

    2009-01-01

    Sediment mass-transport layers of submarine origin on the northern and southern flanks of the Troodos ophiolitic massif are dated biostratigraphically as early Miocene and late Miocene, respectively and therefore represent different seismogenic events in the uplift and erosional history of the Troodos terrane. Analysis of such events has potential for documenting Miocene seismic and uplift events regionally in the context of changing stress field directions and plate vectors through time. ?? 2009 The Geologists' Association.

  5. A computational method for sharp interface advection

    PubMed Central

    Bredmose, Henrik; Jasak, Hrvoje

    2016-01-01

    We devise a numerical method for passive advection of a surface, such as the interface between two incompressible fluids, across a computational mesh. The method is called isoAdvector, and is developed for general meshes consisting of arbitrary polyhedral cells. The algorithm is based on the volume of fluid (VOF) idea of calculating the volume of one of the fluids transported across the mesh faces during a time step. The novelty of the isoAdvector concept consists of two parts. First, we exploit an isosurface concept for modelling the interface inside cells in a geometric surface reconstruction step. Second, from the reconstructed surface, we model the motion of the face–interface intersection line for a general polygonal face to obtain the time evolution within a time step of the submerged face area. Integrating this submerged area over the time step leads to an accurate estimate for the total volume of fluid transported across the face. The method was tested on simple two-dimensional and three-dimensional interface advection problems on both structured and unstructured meshes. The results are very satisfactory in terms of volume conservation, boundedness, surface sharpness and efficiency. The isoAdvector method was implemented as an OpenFOAM® extension and is published as open source. PMID:28018619

  6. Membranes for nanometer-scale mass fast transport

    DOEpatents

    Bakajin, Olgica; Holt, Jason; Noy, Aleksandr; Park, Hyung Gyu

    2011-10-18

    Nanoporous membranes comprising single walled, double walled, and multiwalled carbon nanotubes embedded in a matrix material were fabricated for fluid mechanics and mass transfer studies on the nanometer scale and commercial applications. Average pore size can be 2 nm to 20 nm, or seven nm or less, or two nanometers or less. The membrane can be free of large voids spanning the membrane such that transport of material such as gas or liquid occurs exclusively through the tubes. Fast fluid, vapor, and liquid transport are observed. Versatile micromachining methods can be used for membrane fabrication. A single chip can comprise multiple membranes. These membranes are a robust platform for the study of confined molecular transport, with applications in liquid and gas separations and chemical sensing including desalination, dialysis, and fabric formation.

  7. Concentration polarization, surface currents, and bulk advection in a microchannel

    NASA Astrophysics Data System (ADS)

    Nielsen, Christoffer P.; Bruus, Henrik

    2014-10-01

    We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behavior of the system. A remarkable outcome of the investigations is the discovery of strong couplings between bulk advection and the surface current; without a surface current, bulk advection is strongly suppressed. The numerical simulations are supplemented by analytical models valid in the long channel limit as well as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction.

  8. Photo-induced Mass Transport through Polymer Networks

    NASA Astrophysics Data System (ADS)

    Meng, Yuan; Anthamatten, Mitchell

    2014-03-01

    Among adaptable materials, photo-responsive polymers are especially attractive as they allow for spatiotemporal stimuli and response. We have recently developed a macromolecular network capable of photo-induced mass transport of covalently bound species. The system comprises of crosslinked chains that form an elastic network and photosensitive fluorescent arms that become mobile upon irradiation. We form loosely crosslinked polymer networks by Michael-Addition between multifunctional thiols and small molecule containing acrylate end-groups. The arms are connected to the network by allyl sulfide, that undergoes addition-fragmentation chain transfer (AFCT) in the presence of free radicals, releasing diffusible fluorophore. The networks are loaded with photoinitiator to allow for spatial modulation of the AFCT reactions. FRAP experiments within bulk elastomers are conducted to establish correlations between the fluorophore's diffusion coefficient and experimental variables such as network architecture, temperature and UV intensity. Photo-induced mass transport between two contacted films is demonstrated, and release of fluorophore into a solvent is investigated. Spatial and temporal control of mass transport could benefit drug release, printing, and sensing applications.

  9. STM tip-mediated mass transport on Cu surfaces

    NASA Astrophysics Data System (ADS)

    Sun, Y. S. N.; Huang, R. Z.; Gao, T. F.; Zhang, R. J.; Wang, Y. M.

    2015-02-01

    Atomic-scale simulations are performed to study atomic motion on Cu surfaces to illustrate the effect of the scanning tunneling microscopy tip on mass transport (MT) in the surfaces and on top of the Co island in heteroepitaxial Co/Cu(0 0 1) and Co/Cu(1 1 1) systems. First we investigate tip-induced atomic motion of Co atoms embedded in the Cu(0 0 1) surface at zero bias voltage. With the help of the tip, the Co atom in the surface can freely diffuse toward its nearby vacancy site. So-called vacancy mechanism is used to interpret this phenomenon. Then tip-mediated atomic motion of Co adatoms on the Co islands supported by a Cu(1 1 1) surface is studied. It is revealed that the tip has a significant effect on the diffusion of adatoms on the islands and interlayer mass transport at the island edge. Interlayer mass transport at the island edge is found to depend strongly on the tip height and the lateral distance from the tip. By calculating the diffusion barriers, it is found that the jumping diffusion barrier on the island can be zero by the tip vertical manipulation while the Ehrlich-Schwoebel diffusion barrier at the island edge can be reduced by the tip lateral manipulation. Thus, the quality of thin films can be improved by controlling MT in and/or on the surface.

  10. RWPV bioreactor mass transport: earth-based and in microgravity

    NASA Technical Reports Server (NTRS)

    Begley, Cynthia M.; Kleis, Stanley J.

    2002-01-01

    Mass transport and mixing of perfused scalar quantities in the NASA Rotating Wall Perfused Vessel bioreactor are studied using numerical models of the flow field and scalar concentration field. Operating conditions typical of both microgravity and ground-based cell cultures are studied to determine the expected vessel performance for both flight and ground-based control experiments. Results are presented for the transport of oxygen with cell densities and consumption rates typical of colon cancer cells cultured in the RWPV. The transport and mixing characteristics are first investigated with a step change in the perfusion inlet concentration by computing the time histories of the time to exceed 10% inlet concentration. The effects of a uniform cell utilization rate are then investigated with time histories of the outlet concentration, volume average concentration, and volume fraction starved. It is found that the operating conditions used in microgravity produce results that are quite different then those for ground-based conditions. Mixing times for microgravity conditions are significantly shorter than those for ground-based operation. Increasing the differential rotation rates (microgravity) increases the mixing and transport, while increasing the mean rotation rate (ground-based) suppresses both. Increasing perfusion rates enhances mass transport for both microgravity and ground-based cases, however, for the present range of operating conditions, above 5-10 cc/min there are diminishing returns as much of the inlet fluid is transported directly to the perfusion exit. The results show that exit concentration is not a good indicator of the concentration distributions in the vessel. In microgravity conditions, the NASA RWPV bioreactor with the viscous pump has been shown to provide an environment that is well mixed. Even when operated near the theoretical minimum perfusion rates, only a small fraction of the volume provides less than the required oxygen levels

  11. Transport phenomena of crystal growth—heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Rudolph, Peter

    2010-07-01

    Selected fundamentals of transport processes and their importance for crystal growth are given. First, principal parameters and equations of heat and mass transfer, like thermal flux, radiation and diffusion are introduced. The heat- and mass- balanced melt-solid and solution-solid interface velocities are derived, respectively. The today's significance of global numeric simulation for analysis of thermo-mechanical stress and related dislocation dynamics within the growing crystal is shown. The relation between diffusion and kinetic regime is discussed. Then, thermal and solutal buoyancy-driven and Marangoni convections are introduced. Their important interplay with the diffusion boundary layer, component and particle incorporation as well as morphological interface stability is demonstrated. Non-steady crystallization phenomena (striations) caused by convective fluctuations are considered. Selected results of global 3D numeric modeling are shown. Finally, advanced methods to control heat and mass transfer by external forces, such as accelerated container rotation, ultrasonic vibration and magnetic fields are discussed.

  12. BUOYANT ADVECTION OF GASES IN UNSATURATED SOIL

    PubMed Central

    Seely, Gregory E.; Falta, Ronald W.; Hunt, James R.

    2010-01-01

    In unsaturated soil, methane and volatile organic compounds can significantly alter the density of soil gas and induce buoyant gas flow. A series of laboratory experiments was conducted in a two-dimensional, homogeneous sand pack with gas permeabilities ranging from 110 to 3,000 darcy. Pure methane gas was injected horizontally into the sand and steady-state methane profiles were measured. Experimental results are in close agreement with a numerical model that represents the advective and diffusive components of methane transport. Comparison of simulations with and without gravitational acceleration permits identification of conditions where buoyancy dominates methane transport. Significant buoyant flow requires a Rayleigh number greater than 10 and an injected gas velocity sufficient to overcome dilution by molecular diffusion near the source. These criteria allow the extension of laboratory results to idealized field conditions for methane as well as denser-than-air vapors produced by volatilizing nonaqueous phase liquids trapped in unsaturated soil. PMID:20396624

  13. On Matrix-Valued Monge–Kantorovich Optimal Mass Transport

    PubMed Central

    Ning, Lipeng; Georgiou, Tryphon T.; Tannenbaum, Allen

    2016-01-01

    We present a particular formulation of optimal transport for matrix-valued density functions. Our aim is to devise a geometry which is suitable for comparing power spectral densities of multivariable time series. More specifically, the value of a power spectral density at a given frequency, which in the matricial case encodes power as well as directionality, is thought of as a proxy for a “matrix-valued mass density.” Optimal transport aims at establishing a natural metric in the space of such matrix-valued densities which takes into account differences between power across frequencies as well as misalignment of the corresponding principle axes. Thus, our transportation cost includes a cost of transference of power between frequencies together with a cost of rotating the principle directions of matrix densities. The two endpoint matrix-valued densities can be thought of as marginals of a joint matrix-valued density on a tensor product space. This joint density, very much as in the classical Monge–Kantorovich setting, can be thought to specify the transportation plan. Contrary to the classical setting, the optimal transport plan for matrices is no longer supported on a thin zero-measure set. PMID:26997667

  14. Updated Delft Mass Transport model DMT-2: computation and validation

    NASA Astrophysics Data System (ADS)

    Hashemi Farahani, Hassan; Ditmar, Pavel; Inacio, Pedro; Klees, Roland; Guo, Jing; Guo, Xiang; Liu, Xianglin; Zhao, Qile; Didova, Olga; Ran, Jiangjun; Sun, Yu; Tangdamrongsub, Natthachet; Gunter, Brian; Riva, Ricardo; Steele-Dunne, Susan

    2014-05-01

    A number of research centers compute models of mass transport in the Earth's system using primarily K-Band Ranging (KBR) data from the Gravity Recovery And Climate Experiment (GRACE) satellite mission. These models typically consist of a time series of monthly solutions, each of which is defined in terms of a set of spherical harmonic coefficients up to degree 60-120. One of such models, the Delft Mass Transport, release 2 (DMT-2), is computed at the Delft University of Technology (The Netherlands) in collaboration with Wuhan University. An updated variant of this model has been produced recently. A unique feature of the computational scheme designed to compute DMT-2 is the preparation of an accurate stochastic description of data noise in the frequency domain using an Auto-Regressive Moving-Average (ARMA) model, which is derived for each particular month. The benefits of such an approach are a proper frequency-dependent data weighting in the data inversion and an accurate variance-covariance matrix of noise in the estimated spherical harmonic coefficients. Furthermore, the data prior to the inversion are subject to an advanced high-pass filtering, which makes use of a spatially-dependent weighting scheme, so that noise is primarily estimated on the basis of data collected over areas with minor mass transport signals (e.g., oceans). On the one hand, this procedure efficiently suppresses noise, which are caused by inaccuracies in satellite orbits and, on the other hand, preserves mass transport signals in the data. Finally, the unconstrained monthly solutions are filtered using a Wiener filter, which is based on estimates of the signal and noise variance-covariance matrices. In combination with a proper data weighting, this noticeably improves the spatial resolution of the monthly gravity models and the associated mass transport models.. For instance, the computed solutions allow long-term negative trends to be clearly seen in sufficiently small regions notorious

  15. Mass-transport processes at the steel-enamel interface

    NASA Astrophysics Data System (ADS)

    Yang, X.; Jha, A.; Cochrane, R. C.; Ali, S.

    2006-02-01

    Mass-transport processes at the enamel-steel interface were investigated by studying the rheological properties of the enamel and the microstructure of the enamel-steel interface. The thermophysical properties, e.g., the viscosity and spreading behavior of enamel were measured using the rotating bob and the sessile drop techniques, respectively. The results show that the viscosity of the enamel decreases sharply as the FeO concentration increases from 0 to 25 wt pct, while the contact angle changes with the increasing thickness of the NiO precoat. Microstructural characterization also revealed evidence for the presence of an interfacial gradient force (more specifically referred to as the Marangoni convection) confined within the 0- to 80-µm thickness at the enamel-steel interface. This force is responsible for a convective flow, which determines the formation of flow striae at the interface. The striae act as a sink for evolved gases and provide transport away from the enamel-steel interface. In addition, experimental simulation of Marangoni convection (interfacial-gradient force) was carried out by selectively doping the steel surface with excess Fe2O3 powder. The presence of convection flow was confirmed by analyzing the pattern of iron oxide particles dispersed across the surrounding enamel layers. Based on the microstructural characterization and the thermophysical data, we propose a mechanism for mass transport at the glass-steel interface.

  16. Seasonal variability of water masses and transport on the Antarctic continental shelf and slope in the southeastern Weddell Sea

    NASA Astrophysics Data System (ADS)

    Graham, Jennifer A.; Heywood, Karen J.; Chavanne, Cédric P.; Holland, Paul R.

    2013-04-01

    An array of five moorings was deployed from February 2009 to February 2010 across the Antarctic shelf and slope in the southeastern Weddell Sea (~18°W). Observations demonstrate the key processes responsible for variability in water masses and transport in the region. Rapid fluctuations in temperature and salinity throughout the year are linked with variability in wind stress over the array. This causes the deepening or shoaling of the pycnocline, past the depth of the moorings. In the upper 500 m, the seasonal cycle in salinity shows freshening in autumn, with the strongest freshening at the shallowest mooring (~250 m), furthest on-shelf. The sea ice concentration over the array exceeds 90% during this period and contributes a positive salt flux into the ocean during autumn. Freshening begins during strong along-shore (easterly) winds in late April 2009. This demonstrates that variations in Ekman transport and wind-driven mixing play a key role in determining the salinity of shelf waters around Antarctica. Transport of the Antarctic Slope Current also shows a seasonal cycle with a maximum during late April. Model simulations show the importance of along-shore advection, as the arrival of a fresh anomaly from upstream determines the timing of the salinity minimum at the array. These processes are likely to be important for other regions around the Antarctic continent.

  17. The effect of flow and mass transport in thrombogenesis.

    PubMed

    Basmadjian, D

    1990-01-01

    The paper presents a mathematical analysis of the contributions of flow and mass transport to a single reactive event at a blood vessel wall. The intent is to prepare the ground for a comprehensive study of the intertwining of these contributions with the reaction network of the coagulation cascade. We show that in all vessels with local mural activity, or in "large" vessels (d greater than 0.1 mm) with global reactivity, events at the tubular wall can be rigorously described by algebraic equations under steady conditions, or by ordinary differential forms (ODEs) during transient conditions. This opens up important ways for analyzing the combined roles of flow, transport, and coagulation reactions in thrombosis, a task hitherto considered to be completely intractable. We report extensively on the dependence of transport coefficient kL and mural coagulant concentration Cw on flow, vessel geometry, and reaction kinetics. It is shown that for protein transport, kL varies only weakly with shear rate gamma in large vessels, and not at all in the smaller tubes (d less than 10(-2) mm). For a typical protein, kL approximately 10(-3) cm s-1 within a factor of 3 in most geometries, irrespective of the mural reaction kinetics. Significant reductions in kL (1/10-1/1,000) leading to high-coagulant accumulation are seen mainly in stagnant zones vicinal to abrupt expansions and in small elliptical tubules. This is in accord with known physical observations. More unexpected are the dramatic increases in accumulation which can come about through the intervention of an autocatalytic reaction step, with Cw rising sharply toward infinity as the ratio of reaction to transport coefficient approaches unity. Such self-catalyzed reactions have the ability to act as powerful amplifiers of an otherwise modest influence of flow and transport on coagulant concentration. The paper considers as well the effect on mass transport of transient conditions occasioned by coagulation initiation or

  18. Interface area transport of monodispersed spherical particulates

    SciTech Connect

    Chang, Chong H.

    2016-08-05

    We present an interface area transport model required in tracking of mass, momentum, and energy exchange between dispersed and background materials. The basic transport equation has been rigorously derived from the volume fraction evolution equation. Interface area changes due to mass transport and local compression/expansion are included. The model is then simplified for the case in which the dispersed phase is composed of spheres of locally uniform size. A procedure for calculating advective flux with interface reconstruction has been suggested.

  19. Metal intercalation-induced selective adatom mass transport on graphene

    DOE PAGES

    Liu, Xiaojie; Wang, Cai -Zhuang; Hupalo, Myron; ...

    2016-03-29

    Recent experiments indicate that metal intercalation is a very effective method to manipulate the graphene-adatom interaction and control metal nanostructure formation on graphene. A key question is mass transport, i.e., how atoms deposited uniformly on graphene populate different areas depending on the local intercalation. Using first-principles calculations, we show that partially intercalated graphene, with a mixture of intercalated and pristine areas, can induce an alternating electric field because of the spatial variations in electron doping, and thus, an oscillatory electrostatic potential. As a result, this alternating field can change normal stochastic adatom diffusion to biased diffusion, leading to selective massmore » transport and consequent nucleation, on either the intercalated or pristine areas, depending on the charge state of the adatoms.« less

  20. Engineering Synergy: Energy and Mass Transport in Hybrid Nanomaterials.

    PubMed

    Cho, Eun Seon; Coates, Nelson E; Forster, Jason D; Ruminski, Anne M; Russ, Boris; Sahu, Ayaskanta; Su, Norman C; Yang, Fan; Urban, Jeffrey J

    2015-10-14

    An emerging class of materials that are hybrid in nature is propelling a technological revolution in energy, touching many fundamental aspects of energy-generation, storage, and conservation. Hybrid materials combine classical inorganic and organic components to yield materials that manifest new functionalities unattainable in traditional composites or other related multicomponent materials, which have additive function only. This Research News article highlights the exciting materials design innovations that hybrid materials enable, with an eye toward energy-relevant applications involving charge, heat, and mass transport.

  1. Mass transport of adsorbates near a discontinuous structural phase transition

    NASA Astrophysics Data System (ADS)

    Granato, E.; Ying, S. C.; Elder, K. R.; Ala-Nissila, T.

    2016-12-01

    We study the mass transport dynamics of an adsorbed layer near a discontinuous incommensurate striped-honeycomb phase transition via numerical simulations of a coarse-grained model focusing on the motion of domain walls rather than individual atoms. Following an initial step profile created in the incommensurate striped phase, an intermediate hexagonal incommensurate phase nucleates and grows, leading to a bifurcation into two sharp profiles propagating in opposite directions as opposed to broad profiles induced by atomic diffusive motion. Our results are in agreement with recent numerical simulations of a microscopic model as well as experimental observations for the Pb/Si(111) adsorbate system.

  2. Black Hole Advective Accretion Disks with Optical Depth Transition

    SciTech Connect

    Artemove, Y.V.; Bisnovatyi-Kogan, G.S.; Igumenshchev, I.V.; Novikov, I.D.

    2006-02-01

    We have constructed numerically global solutions of advective accretion disks around black holes that describe a continuous transition between the effectively optically thick outer and optically thin inner disk regions. We have concentrated on models of accretion flows with large mass accretion rates, and we have employed a bridging formula for radiative losses at high and low effective optical depths.

  3. Experimental Studies on Mass Transport of Cadmium-Zinc Telluride by Physical Vapor Transport

    NASA Technical Reports Server (NTRS)

    Palosz, W.; Szofran, F. R.; Lehoczky, S. L.

    1995-01-01

    Experimental studies on mass transport of ternary compound, Cd(1-x)Zn(x)Te by physical vapor transport (PVT) for source compositions up to X = 0.21 are presented. The effect of thermochemical (temperatures, vapor composition) and other factors (preparation of the source, crystal growth rate, temperature gradient) on composition and composition profiles of the grown crystals were investigated. A steep decrease in the mass flux with an increase in X(crystal) for X less than 0.1, and a difference in composition between the source and the deposited material have been observed. The composition profiles of the crystals were found to depend on the density and pretreatment of the source, and on the temperature gradient in the source zone. The homogeneity of the crystals improves at low undercoolings and/or when an appropriate excess of metal constituents is present in the vapor phase. The experimental results are in good agreement with our thermochemical model of this system.

  4. Angular momentum transport within evolved low-mass stars

    SciTech Connect

    Cantiello, Matteo; Bildsten, Lars; Paxton, Bill; Mankovich, Christopher; Christensen-Dalsgaard, Jørgen

    2014-06-10

    Asteroseismology of 1.0-2.0 M {sub ☉} red giants by the Kepler satellite has enabled the first definitive measurements of interior rotation in both first ascent red giant branch (RGB) stars and those on the helium burning clump. The inferred rotation rates are 10-30 days for the ≈0.2 M {sub ☉} He degenerate cores on the RGB and 30-100 days for the He burning core in a clump star. Using the Modules for Experiments in Stellar Evolution code, we calculate state-of-the-art stellar evolution models of low mass rotating stars from the zero-age main sequence to the cooling white dwarf (WD) stage. We include transport of angular momentum due to rotationally induced instabilities and circulations, as well as magnetic fields in radiative zones (generated by the Tayler-Spruit dynamo). We find that all models fail to predict core rotation as slow as observed on the RGB and during core He burning, implying that an unmodeled angular momentum transport process must be operating on the early RGB of low mass stars. Later evolution of the star from the He burning clump to the cooling WD phase appears to be at nearly constant core angular momentum. We also incorporate the adiabatic pulsation code, ADIPLS, to explicitly highlight this shortfall when applied to a specific Kepler asteroseismic target, KIC8366239.

  5. Mass Flux of ZnSe by Physical Vapor Transport

    NASA Technical Reports Server (NTRS)

    Sha, Yi-Gao; Su, Ching-Hua; Palosz, W.; Volz, M. P.; Gillies, D. C.; Szofran, F. R.; Lehoczky, S. L.; Liu, Hao-Chieh; Brebrick, R. F.

    1995-01-01

    Mass fluxes of ZnSe by physical vapor transport (PVT) were measured in the temperature range of 1050 to 1160 C using an in-situ dynamic technique. The starting materials were either baked out or distilled under vacuum to obtain near-congruently subliming compositions. Using an optical absorption technique Zn and Se, were found to be the dominant vapor species. Partial pressures of Zn and Se, over the starting materials at temperatures between 960 and 1140 C were obtained by measuring the optical densities of the vapor phase at the wavelengths of 2138, 3405, 3508, 3613, and 3792 A. The amount and composition of the residual gas inside the experimental ampoules were measured after the run using a total pressure gauge. For the first time, the experimentally determined partial pressures of Zn and Se, and the amount and composition of the residual gas were used in a one-dimensional diffusion limited analysis of the mass transport rates for a PVT system. Reasonable agreement between the experimental and theoretical results was observed.

  6. Self-oscillating surface of gel for autonomous mass transport.

    PubMed

    Yoshida, Ryo; Murase, Yoko

    2012-11-01

    As a novel biomimetic gels deffering from conventonal stimuli-responsive polymer gels, we have developed a "self-oscillating" gel that swells and deswells periodically under constant condition without on-off switching of external stimuli. The gel is composed of poly(N-isopropylacrylamide) to which the catalyst of the oscillating chemical reaction, called Belousov-Zhabotinsky reaction, is covalently immobilized. The chemical oscillation is converted to the mechanical oscillation of the gel through the change in hydrophilicity of polymer chains with the redox changes of the immobilized catalyst. By utilizing the self-oscillating gel, several kinds of functional material systems such as biomimetic actuators, etc. are expected. Here we review a potential application to functional surface to realize autonomous mass-transport by utilizing the peristaltic motion of the gel. With the propagation of the chemical wave, the loaded cargo is autonomously transported on the surface. In order to fabricate the self-driven gel conveyer for a wider use including biomedical applications, the interactions between the self-oscillating gel and the loaded gel cargo were investigated and their influence on the transport phenomena were evaluated.

  7. Mu2e Transport Solenoid Cold-Mass Alignment Issues

    DOE PAGES

    Lopes, M.; Ambrosio, G.; Badgley, K.; ...

    2017-01-05

    The Muon-to-electron conversion experiment (Mu2e) at Fermilab is designed to explore charged lepton flavor violation. It is composed of three large superconducting solenoids: the Production Solenoid (PS), the Transport Solenoid (TS) and the Detector Solenoid (DS). The TS is formed by two magnets: TS upstream (TSu) and downstream (TSd). Each has its own cryostat and power supply. Tolerance sensitivity studies of the position and angular alignment of each coil in this magnet system were performed in the past with the objective to demonstrate that the magnet design meets all the field requirements. Furthermore, the alignment of the cold-masses is criticalmore » to maximize the transmission of muons and to avoid possible backgrounds that would reduce the sensitivity of the experiment. Each TS magnet cold-mass can be individually aligned. Here, we discuss implications of the alignment of the TS cold-masses in terms of the displacement of the magnetic center. Consideration of the practical mechanical limits are also presented.« less

  8. Chaotic Advection in a Bounded 3-Dimensional Potential Flow

    NASA Astrophysics Data System (ADS)

    Metcalfe, Guy; Smith, Lachlan; Lester, Daniel

    2012-11-01

    3-dimensional potential, or Darcy flows, are central to understanding and designing laminar transport in porous media; however, chaotic advection in 3-dimensional, volume-preserving flows is still not well understood. We show results of advecting passive scalars in a transient 3-dimensional potential flow that consists of a steady dipole flow and periodic reorientation. Even for the most symmetric reorientation protocol, neither of the two invarients of the motion are conserved; however, one invarient is closely shadowed by a surface of revolution constructed from particle paths of the steady flow, creating in practice an adiabatic surface. A consequence is that chaotic regions cover 3-dimensional space, though tubular regular regions are still transport barriers. This appears to be a new mechanism generating 3-dimensional chaotic orbits. These results contast with the experimental and theoretical results for chaotic scalar transport in 2-dimensional Darcy flows. Wiggins, J. Fluid Mech. 654 (2010).

  9. AN EULERIAN-LAGRANGIAN LOCALIZED ADJOINT METHOD FOR THE ADVECTION-DIFFUSION EQUATION

    EPA Science Inventory

    Many numerical methods use characteristic analysis to accommodate the advective component of transport. Such characteristic methods include Eulerian-Lagrangian methods (ELM), modified method of characteristics (MMOC), and operator splitting methods. A generalization of characteri...

  10. Chemistry and mass transport of iodine in containment

    SciTech Connect

    Beahm, E.C.; Weber, C.F.; Kress, T.S.; Shockley, W.E.; Daish, S.R.

    1988-01-01

    TRENDS is a computer code for modeling behavior of iodine in containment. It tracks both chemical and physical changes and features such as calculation of radiation dose rates in water pools , radiolysis effects, hydrolysis, and deposition/revaporization on aerosols and structural surfaces. Every attempt has been made to account for all significant processes. Reaction rate constants for iodine hydrolysis and radiolysis were obtained by a variable algorithm that gives values closely modeling experimental data. TRENDS output provides the distribution of iodine in containment and release from containment as a function of time during a severe accident sequence. Initial calculations with TRENDS have shown that the amount of volatile iodine released from containment is sensitive to the value of the liquid-gas (evaporation) mass transport coefficient for I/sub 2/. 7 refs., 4 figs., 3 tabs.

  11. Mass transport measurements and modeling for chemical vapor infiltration

    SciTech Connect

    Starr, T.L.; Chiang, D.Y.; Fiadzo, O.G.; Hablutzel, N.

    1997-12-01

    This project involves experimental and modeling investigation of densification behavior and mass transport in fiber preforms and partially densified composites, and application of these results to chemical vapor infiltration (CVI) process modeling. This supports work on-going at ORNL in process development for fabrication of ceramic matrix composite (CMC) tubes. Tube-shaped composite preforms are fabricated at ORNL with Nextel{trademark} 312 fiber (3M Corporation, St. Paul, MN) by placing and compressing several layers of braided sleeve on a tubular mandrel. In terms of fiber architecture these preforms are significantly different than those made previously with Nicalon{trademark} fiber (Nippon Carbon Corp., Tokyo, Japan) square weave cloth. The authors have made microstructure and permeability measurements on several of these preforms and a few partially densified composites so as to better understand their densification behavior during CVI.

  12. Fractional-step method for two-dimensional estuarine transport

    USGS Publications Warehouse

    Bales, Jerad D.; Holley, Edward R.

    1988-01-01

    The fractional-step method was used in this study to split the longitudinal advective transport term from the other terms in the two-dimensional, laterally-averaged equation for estuarine mass transport. The method of characteristics with spline interpolations was used to approximate the longitudinal advective transport. A general discussion of the fractional-step method, the specific algorithm developed in this investigation, and results of numerical tests are presented. Application of the fractional-step method in conjunction with the characteristic-spline scheme offers the potential for improved simulations of transport for situations in which concentration gradients are steep.

  13. Density Functional Theory Calculations of Mass Transport in UO2

    SciTech Connect

    Andersson, Anders D.; Dorado, Boris; Uberuaga, Blas P.; Stanek, Christopher R.

    2012-06-26

    In this talk we present results of density functional theory (DFT) calculations of U, O and fission gas diffusion in UO{sub 2}. These processes all impact nuclear fuel performance. For example, the formation and retention of fission gas bubbles induce fuel swelling, which leads to mechanical interaction with the clad thereby increasing the probability for clad breach. Alternatively, fission gas can be released from the fuel to the plenum, which increases the pressure on the clad walls and decreases the gap thermal conductivity. The evolution of fuel microstructure features is strongly coupled to diffusion of U vacancies. Since both U and fission gas transport rates vary strongly with the O stoichiometry, it is also important to understand O diffusion. In order to better understand bulk Xe behavior in UO{sub 2{+-}x} we first calculate the relevant activation energies using DFT techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next we investigate species transport on the (111) UO{sub 2} surface, which is motivated by the formation of small voids partially filled with fission gas atoms (bubbles) in UO{sub 2} under irradiation. Surface diffusion could be the rate-limiting step for diffusion of such bubbles, which is an alternative mechanism for mass transport in these materials. As expected, the activation energy for surface diffusion is significantly lower than for bulk transport. These results are further discussed in terms of engineering-scale fission gas release models

  14. Restricted mass transport effects on free radical reactions

    SciTech Connect

    Buchanan, A.C. III; Britt, P.F.; Thomas, K.B.

    1994-09-01

    Coal possesses a complex chemical and physical structure. The cross-linked, network structure can lead to alterations in normal thermally-induced, free-radical decay pathways as a consequence of restrictions on mass transport. Moreover, in coal liquefaction, access of an external hydrogen donor to a reactive radical site can be hindered by the substantial domains of microporosity present in coals. However, previous work indicates that diffusion effects do not appear to be playing an important role in this coal conversion chemistry. Several possible explanations for this phenomenon were advanced including the potential involvement of a hydrogen hopping/radical relay mechanism recently discovered model systems in the authors laboratories. The authors have employed silica-anchored compounds to explore the effects of restricted mass transport on the pyrolysis mechanisms of coal model compounds. In studies of two-component systems, cases have been discovered where radical centers can be rapidly relocated in the diffusionally constrained environment as a consequence of rapid serial hydrogen atom transfers. This chemistry can have substantial effects on thermal decomposition rates and on product selectivities. In this study, the authors examine additional surfaces to systematically investigate the impact of molecular structure on the hydrogen atom transfer promoted radical relay mechanism. Silica-attached 1,3-diphenylpropane ({approx}Ph(CH{sub 2}){sub 3}Ph, or {approx}DPP) was chosen as the thermally reactive component, since it can be considered prototypical of linkages in coal that do not contain weak bonds easily cleaved at coal liquefaction temperatures (ca. 4000 {degrees}C), but which crack at reasonable rates if benzylic radicals can be generated by hydrogen abstraction. The rate of such hydrogen transfers under restricted diffusion will be highly dependent on the structure and proximity of neighboring molecules.

  15. Triple bioaffinity mass spectrometry concept for thyroid transporter ligands.

    PubMed

    Aqai, Payam; Fryganas, Christos; Mizuguchi, Mineyuki; Haasnoot, Willem; Nielen, Michel W F

    2012-08-07

    For the analysis of thyroid transporter ligands, a triple bioaffinity mass spectrometry (BioMS) concept was developed, with the aim at three different analytical objectives: rapid screening of any ligand, confirmation of known ligands in accordance with legislative requirements, and identification of emerging yet unknown ligands. These three purposes share the same biorecognition element, recombinant thyroid transport protein transthyretin (rTTR), and dedicated modes of liquid chromatography-mass spectrometry (LC-MS). For screening, a rapid and radiolabel-free competitive inhibition MS binding assay was developed with fast ultrahigh performance-liquid chromatography-electrospray ionization-triple-quadrupole-MS (UPLC-QqQ-MS) as the readout system. It uses the nonradioactive stable isotopic thyroid hormone (13)C(6)-L-thyroxine as the label of which the binding to rTTR is inhibited by any ligand such as thyroid drugs and thyroid endocrine disrupting chemicals (EDCs). To this end, rTTR is either used in solution or immobilized on paramagnetic microbeads. The concentration-dependent inhibition of the label by the natural thyroid hormone l-thyroxine (T4), as a model analyte, is demonstrated in water at part-per-trillion and in urine at part-per-billion level. For confirmation of identity of known ligands, rTTR was used for bioaffinity purification for confirmation of naturally present free T4 in urine. As a demonstrator for identification of unknown ligands, the same rTTR was used again but in combination with nano-UPLC-quadrupole time-of-flight-MS (nLC-Q-TOF-MS) and urine samples spiked with the model "unknown" EDCs triclosan and tetrabromobisphenol-A. This study highlights the potential of BioMS using one affinity system, both for rapid screening and for confirmation and identification of known and unknown emerging thyroid EDCs.

  16. Restricted mass transport effects on free radical reactions

    NASA Astrophysics Data System (ADS)

    Buchanan, A. C., III; Britt, P. F.; Thomas, K. B.

    Coal possesses a complex chemical and physical structure. The cross-linked, network structure can lead to alterations in normal thermally-induced, free-radical decay pathways as a consequence of restrictions on mass transport. Moreover, in coal liquefaction, access of an external hydrogen donor to a reactive radical site can be hindered by the substantial domains of microporosity present in coals. However, previous work indicates that diffusion effects do not appear to be playing an important role in this coal conversion chemistry. Several possible explanations for this phenomenon were advanced including the potential involvement of a hydrogen hopping/radical relay mechanism recently discovered model systems in the authors' laboratories. The authors have employed silica-anchored compounds to explore the effects of restricted mass transport on the pyrolysis mechanisms of coal model compounds. In studies of two-component systems, cases have been discovered where radical centers can be rapidly relocated in the diffusionally constrained environment as a consequence of rapid serial hydrogen atom transfers. This chemistry can have substantial effects on thermal decomposition rates and on product selectivities. In this study, the authors examine additional surfaces to systematically investigate the impact of molecular structure on the hydrogen atom transfer promoted radical relay mechanism. Silica-attached 1,3-diphenylpropane (approximately Ph(CH2)3Ph, or approximately DPP) was chosen as the thermally reactive component, since it can be considered prototypical of linkages in coal that do not contain weak bonds easily cleaved at coal liquefaction temperatures (ca. 4000 C), but which crack at reasonable rates if benzylic radicals can be generated by hydrogen abstraction. The rate of such hydrogen transfers under restricted diffusion will be highly dependent on the structure and proximity of neighboring molecules.

  17. Materials with engineered mesoporosity for programmed mass transport

    NASA Astrophysics Data System (ADS)

    Gough, Dara V.

    Transport in nanostructured materials is of great interest for scientists in various fields, including molecular sequestration, catalysis, artificial photosynthesis and energy storage. This thesis will present work on the transport of molecular and ionic species in mesoporous materials (materials with pore sizes between 2 and 50 nm). Initially, discussion will focus on the synthesis of mesoporous ZnS nanorattles and the size selected mass transport of small molecules through the mesopores. Discussion will then shift of exploration of cation exchange and electroless plating of metals to alter the mesoporous hollow sphere (MHS) materials and properties. The focus of discussion will then shift to the transport of ions into and out of a hierarchically structured gold electrode. Finally, a model gamma-bactiophage was developed to study the electromigration of charged molecules into and out of a confined geometry. A catalytically active biomolecular species was encapsulated within the central cavity of ZnS MHS. Both the activity of the encapsulated enzyme and the size-selective transport through the wall of the MHS were verified through the use of a common fluorogen, hydrogen peroxide, and sodium azide. Additionally, the protection of the enzyme was shown through size-selected blocking of a protease. The mesoporous hollow sphere system introduces size-selectivity to catalyzed chemical reactions; future work may include variations in pore sizes, and pore wall chemical functionalization. The pore size in ZnS mesoporous hollow spheres is controlled between 2.5 and 4.1 nm through swelling of the lyotropic liquid crystal template. The incorporation of a swelling agent is shown to linearly vary the hexagonal lyotropic liquid crystalline phase, which templates the mesopores, while allowing the high fidelity synthesis of mesoporous hollow spheres. Fluorescnently labeled ssDNA was utilized as a probe to explore the change in mesopore permeability afforded by the swollen template

  18. Mass and charge transport in arbitrarily shaped microchannels

    NASA Astrophysics Data System (ADS)

    Bruus, Henrik; Asger Mortensen, Niels; Okkels, Fridolin; Hoejgaard Olesen, Laurits

    2006-11-01

    We consider laminar flow of incompressible electrolytes in long, straight channels driven by pressure and electro-osmosis. We use a Hilbert space eigenfunction expansion to address the problem of arbitrarily shaped cross sections and obtain general results in linear-response theory for the mass and charge transport coefficients which satisfy Onsager relations [1,2]. In the limit of non-overlapping Debye layers the transport coefficients are simply expressed in terms of parameters of the electrolyte as well as half the hydraulic diameter R=2 A/P with A and P being the cross- sectional area and perimeter, respectively. In particular, we consider the limits of thin non-overlapping as well as strongly overlapping Debye layers, respectively, and calculate the corrections to the hydraulic resistance due to electro- hydrodynamic interactions.[1] N. A. Mortensen, F. Okkels, and H. Bruus, Phys. Rev. E 71, 057301 (2005) [2] N. A. Mortensen, L. H. Olesen, and H. Bruus, New J. Phys. 8, 37 (2006)

  19. Advective hydrogel membrane chromatography for monoclonal antibody purification in bioprocessing.

    PubMed

    Hou, Ying; Brower, Mark; Pollard, David; Kanani, Dharmesh; Jacquemart, Renaud; Kachuik, Bradley; Stout, James

    2015-01-01

    Protein A chromatography is widely employed for the capture and purification of monoclonal antibodies (mAbs). Because of the high cost of protein A resins, there is a significant economic driving force to seek new downstream processing strategies. Membrane chromatography has emerged as a promising alternative to conventional resin based column chromatography. However, to date, the application has been limited to mostly ion exchange flow through (FT) mode. Recently, significant advances in Natrix hydrogel membrane has resulted in increased dynamic binding capacities for proteins, which makes membrane chromatography much more attractive for bind/elute operations. The dominantly advective mass transport property of the hydrogel membrane has also enabled Natrix membrane to be run at faster volumetric flow rates with high dynamic binding capacities. In this work, the potential of using Natrix weak cation exchange membrane as a mAb capture step is assessed. A series of cycle studies was also performed in the pilot scale device (> 30 cycles) with good reproducibility in terms of yield and product purities, suggesting potential for improved manufacturing flexibility and productivity. In addition, anion exchange (AEX) hydrogel membranes were also evaluated with multiple mAb programs in FT mode. Significantly higher binding capacity for impurities (support mAb loads up to 10Kg/L) and 40X faster processing speed were observed compared with traditional AEX column chromatography. A proposed protein A free mAb purification process platform could meet the demand of a downstream purification process with high purity, yield, and throughput.

  20. Pulsatile flow and mass transport past a circular cylinder

    NASA Astrophysics Data System (ADS)

    Zierenberg, Jennifer R.; Fujioka, Hideki; Suresh, Vinod; Bartlett, Robert H.; Hirschl, Ronald B.; Grotberg, James B.

    2006-01-01

    The mass transport of a pulsatile free-stream flow past a single circular cylinder is investigated as a building block for an artificial lung device. The free stream far from the cylinder is represented by a time-periodic (sinusoidal) component superimposed on a steady velocity. The dimensionless parameters of interest are the steady Reynolds number (Re), Womersley parameter (α), sinusoidal amplitude (A), and the Schmidt number (Sc). The ranges investigated in this study are 5⩽Re⩽40, 0.25⩽α⩽4, 0.25⩽A⩽0.75, and Sc =1000. A pair of vortices downstream of the cylinder is observed in almost all cases investigated. These vortices oscillate in size and strength as α and A are varied. For α <αc, where αc=0.005A-1.13Re1.33, the vortex is always attached to the cylinder (persistent); while for α >αc, the vortex is attached to the cylinder only during part of a time cycle (intermittent). The time-averaged Sherwood number, Sh̿, is found to be largely influenced by the steady Reynolds number, increasing approximately as Re1/2. For α =0.25, Sh̿ is less than the steady (α =0, A =0) value and decreases with increasing A. For α =2 and α =4, Sh̿ is greater than the steady value and increases with increasing A. These qualitatively opposite effects of pulsatility are discussed in terms of quasisteady versus unsteady transport. The maximum increase over steady transport due to pulsatility varies between 14.4% and 20.9% for Re =10-40, α =4, and A =0.75.

  1. Cerebrospinal and interstitial fluid transport via the glymphatic pathway modeled by optimal mass transport.

    PubMed

    Ratner, Vadim; Gao, Yi; Lee, Hedok; Elkin, Rena; Nedergaard, Maiken; Benveniste, Helene; Tannenbaum, Allen

    2017-03-18

    The glymphatic pathway is a system which facilitates continuous cerebrospinal fluid (CSF) and interstitial fluid (ISF) exchange and plays a key role in removing waste products from the rodent brain. Dysfunction of the glymphatic pathway may be implicated in the pathophysiology of Alzheimer's disease. Intriguingly, the glymphatic system is most active during deep wave sleep general anesthesia. By using paramagnetic tracers administered into CSF of rodents, we previously showed the utility of MRI in characterizing a macroscopic whole brain view of glymphatic transport but we have yet to define and visualize the specific flow patterns. Here we have applied an alternative mathematical analysis approach to a dynamic time series of MRI images acquired every 4min over ∼3h in anesthetized rats, following administration of a small molecular weight paramagnetic tracer into the CSF reservoir of the cisterna magna. We use Optimal Mass Transport (OMT) to model the glymphatic flow vector field, and then analyze the flow to find the network of CSF-ISF flow channels. We use 3D visualization computational tools to visualize the OMT defined network of CSF-ISF flow channels in relation to anatomical and vascular key landmarks from the live rodent brain. The resulting OMT model of the glymphatic transport network agrees largely with the current understanding of the glymphatic transport patterns defined by dynamic contrast-enhanced MRI revealing key CSF transport pathways along the ventral surface of the brain with a trajectory towards the pineal gland, cerebellum, hypothalamus and olfactory bulb. In addition, the OMT analysis also revealed some interesting previously unnoticed behaviors regarding CSF transport involving parenchymal streamlines moving from ventral reservoirs towards the surface of the brain, olfactory bulb and large central veins.

  2. Scalar Transport and Dispersion in Complex Terrain within a High Resolution Mass-Consistent Wind Modeling Framework

    NASA Astrophysics Data System (ADS)

    Wagenbrenner, N. S.; Edburg, S. L.; Lamb, B.; Forthofer, J.

    2012-12-01

    In areas of complex terrain, fine-scale changes in topography or vegetation substantially alter the flow field, and in turn, the transport and dispersion of air pollutants, pheromones, or other scalars. Thus, accurate modeling of scalar transport in complex topography requires accurate prediction of the flow field at a high spatial resolution. Mesoscale weather models typically operate on horizontal grids of 4 km or larger and are not capable of handling the effects of sub-grid complex terrain, such as wind speed-up over ridges, flow channeling in valleys, flow separation around terrain obstacles, and enhanced surface roughness from vegetation. In this paper we describe a scalar transport algorithm (advection and turbulent diffusion) used with WindNinja, a high-resolution mass-consistent wind model. WindNinja operates on a terrain-following coordinate system with a hexahedral cell mesh that grows in vertical size with height above the ground. A variational calculus approach is used in WindNinja that results in fast run times on the order of one minute for a 50 km x 50 km domain and 100 m horizontal resolution. The advection-diffusion algorithm uses a first order closure scheme for turbulent diffusion, where diffusivities are parameterized based on mixing length theory and modified as a function of atmospheric stability. We initialize WindNinja simulations with output from mesoscale weather forecasts using the Weather Research and Forecasting (WRF) model to capture the large-scale atmospheric flows and stability conditions. Model performance is evaluated against field data collected under a range of conditions at different locations including a multi-day continuous tracer gas dispersion experiment in an orchard located on rolling terrain in eastern Washington and a post-wildfire PM10 monitoring campaign in SE Idaho. The combination of fast run times, low computational demands, and explicit treatment of terrain and vegetation at a high spatial resolution are expected

  3. Pesticide transport with runoff from creeping bentgrass turf: Relationship of pesticide properties to mass transport.

    PubMed

    Rice, Pamela J; Horgan, Brian P; Rittenhouse, Jennifer L

    2010-06-01

    The off-site transport of pesticides with runoff is both an agronomic and environmental concern, resulting from reduced control of target pests in the area of application and contamination of surrounding ecosystems. Experiments were designed to measure the quantity of pesticides in runoff from creeping bentgrass (Agrostis palustris) turf managed as golf course fairway to gain a better understanding of factors that influence chemical availability and mass transport. Less than 1 to 23% of applied chloropyrifos, flutolanil, mecoprop-p (MCPP), dimethylamine salt of 2,4-dichlorophenoxyacetic acid (2,4-D), or dicamba was measured in edge-of-plot runoff when commercially available pesticide formulations were applied at label rates 23 +/- 9 h prior to simulated precipitation (62 +/- 13 mm). Time differential between hollow tine core cultivation and runoff did not significantly influence runoff volumes or the percentage of applied chemicals transported in the runoff. With the exception of chlorpyrifos, all chemicals of interest were detected in the initial runoff samples and throughout the runoff events. Chemographs of the five pesticides followed trends in agreement with mobility classifications associated with their soil organic carbon partition coefficient (K(OC).) Data collected from the present study provides information on the transport of chemicals with runoff from turf, which can be used in model simulations to predict nonpoint source pollution potentials and estimate ecological risks.

  4. Mass and charge transport in IPMC actuators with fractal interfaces

    NASA Astrophysics Data System (ADS)

    Chang, Longfei; Wu, Yucheng; Zhu, Zicai; Li, Heng

    2016-04-01

    Ionic Polymer-Metal Composite (IPMC) actuators have been attracting a growing interest in extensive applications, which consequently raises the demands on the accuracy of its theoretical modeling. For the last few years, rough landscape of the interface between the electrode and the ionic membrane of IPMC has been well-documented as one of the key elements to ensure a satisfied performance. However, in most of the available work, the interface morphology of IPMC was simplified with structural idealization, which lead to perplexity in the physical interpretation on its interface mechanism. In this paper, the quasi-random rough interface of IPMC was described with fractal dimension and scaling parameters. And the electro-chemical field was modeled by Poisson equation and a properly simplified Nernst-Planck equation set. Then, by simulation with Finite Element Method, a comprehensive analysis on he inner mass and charge transportation in IPMC actuators with different fractal interfaces was provided, which may be further adopted to instruct the performance-oriented interface design for ionic electro-active actuators. The results also verified that rough interface can impact the electrical and mechanical response of IPMC, not only from the respect of the real surface increase, but also from mass distribution difference caused by the complexity of the micro profile.

  5. Turbulence and mass-transports in stratocumulus clouds

    NASA Astrophysics Data System (ADS)

    Ghate, Virendra P.

    Boundary layer (BL) stratocumulus clouds are an important factor in the earth's radiation budget due to their high albedo and low cloud top heights. Continental BL stratocumulus clouds are closely coupled to the diurnal cycle and the turbulence in the BL affecting the surface energy and moisture budgets. In this study the turbulence and mass-transport structures in continental BL stratocumulus clouds are studied using data from the Atmospheric Radiation Measurements (ARM)'s Southern Great Plains (SGP) observing facility located at Lamont, Oklahoma. High temporal (4 sec) and spatial (45 m) resolution observations from a vertically pointing 35 GHz cloud Doppler radar were used to obtain the in-cloud vertical velocity probability density function (pdf) in the absence of precipitation size hydrometeors. A total of 70 hours of radar data were analyzed to report half-hourly statistics of vertical velocity variance, skewness, updraft fraction, downdraft and velocity binned mass-flux at five cloud depth normalized levels. The variance showed a general decrease with increase in height in the cloud layer while the skewness is weakly positive in the cloud layer and negative near cloud top. The updraft fraction decreases with height with the decrease mainly occurring in the upper half of the cloud layer. The downdraft fraction increases with decrease in height with the increase being almost linear. The velocity of eddies responsible for maximum mass-transport decreases from of 0.4 ms-1 near cloud base to 0.2 ms-1 near cloud top. The half-hour periods were then classified based on the surface buoyancy flux as stable or unstable and it was found that the variance near cloud top is higher during the stable periods as compared to the unstable periods. Classification was also made based on the cloud depth to BL depth ratio (CBR) being greater or less than 0.3. The variance profile was similar for the classification while the skewness was almost zero during periods with CBR less 0

  6. An evaluation and intercomparison of four new advection schemes for use in global chemistry models

    NASA Astrophysics Data System (ADS)

    Petersen, Arthur C.; Spee, Edwin J.; van Dop, Han; Hundsdorfer, Willem

    1998-08-01

    The need to use a higher spatial resolution and to include more chemical species in global atmospheric chemistry models has led to a demand for efficient advection schemes with high accuracy. We test four newly developed three-dimensional advection schemes named Mol-rg, Split-u, Split-us, and Split-rg. We compare the new schemes with the existing schemes Slopes and Second Moments, both implemented on a uniform grid. Mol-rg and Split-rg make use of a reduced grid. Split-us is an unconditionally stable scheme on a uniform grid. Two tests are performed with all schemes: a solid-body rotation test and a radon transport test. The radon transport test is performed with the off-line global tracer model TM2. The solid-body rotation test shows that none of the new schemes generates undershoot and overshoot and that all of them are mass conservative. Slopes and Second Moments both generate small undershoot and overshoot at all resolutions. The accuracy of the new and old schemes for rotation of a smooth profile is similar for the horizontal resolutions studied. Since the new schemes are slightly more diffusive than the old schemes, they perform worse for rotation of a cone. The radon test shows that the errors related to the numerical schemes are much smaller than other model errors. The main advantage of the new schemes is that they use 75% and 90% less memory than Slopes and Second Moments, respectively. At horizontal resolutions higher than 5° × 5° Split-us and Split-rg are the most efficient of the schemes in terms of cpu time. The new advection schemes are available through Internet.

  7. Ballistic transport in Saturn's rings - An analytic theory

    NASA Technical Reports Server (NTRS)

    Lissauer, J. J.

    1984-01-01

    Ejecta from impacts of micrometeoroids on Saturn's ring particles will, in most cases, remain in orbit about Saturn and eventually be reaccreted by the rings, possibly at a different radial location. The resulting mass transport has been suggested as the cause of some of the features observed in Saturn's rings. Previous attempts to model this transport have used numerical simulations which have not included the effects of the angular momentum transport coincident with mass transport. An analytical model for ballistic mass transport in Saturn's rings is developed. The model includes the effects of angular momentum advection and shows that the net material movement due to angular momentum advection is comparable to that caused by direct ballistic mass transport.

  8. Dynamic typology of hydrothermal systems: competing effects of advection, dispersion and reactivity

    NASA Astrophysics Data System (ADS)

    Dolejs, David

    2016-04-01

    Genetic interpretation hydrothermal systems relies on recognition of (i) hydrothermal fluid source, (ii) fluid migration pathways, and (iii) deposition site identified by hydrothermal alteration and/or mineralization. Frequently, only the last object is of interest or accessible to direct observation, but constraints on the fluid source (volume) and pathways can be obtained from evaluation of the time-integrated fluid flux during hydrothermal event. Successful interpretation of the petrological record, that is, progress of alteration reactions, relies on identification of individual contributions arising from solute advection (to the deposition site), its lateral dispersion, and reaction efficiency. Although these terms are all applicable in a mass-conservation relationship within the framework of the transport theory, they are rarely considered simultaneously and their relative magnitudes evaluated. These phenomena operate on variable length and time scales, and may in turn provide insight into the system dynamics such as flow, diffusion and reaction rates, or continuous vs. episodic behavior of hydrothermal events. In addition, here we demonstrate that they also affect estimate of the net fluid flux, frequently by several orders of magnitude. The extent of alteration and mineralization reactions between the hydrothermal fluid and the host environment is determined by: (i) temperature, pressure or any other gradients across the mineralization site, (ii) magnitude of disequilibrium at inflow to the mineralization site, which is related to physico-chemical gradient between the fluid source and the mineralization site, and (iii) chemical redistribution (dispersion) within the mineralization site. We introduce quantitative mass-transport descriptors - Péclet and Damköhler II numbers - to introduce division into dispersion-dominated, advection-dominated and reaction-constrained systems. Dispersive systems are characterized by lateral solute redistribution, driven by

  9. Advective-diffusive contaminant migration in unsaturated sand and gravel

    SciTech Connect

    Rowe, R.K.; Badv, K.

    1996-12-01

    A method is presented for estimating the diffusion coefficients for chloride and sodium in unsaturated coarse sand and fine gravel based on parameters obtained from saturated diffusion tests conducted for similar material. The method is tested by comparing the observed and predicted diffusion profiles through unsaturated soil. The method is shown to work well for predicting the advective-diffusive migration of chloride and sodium through a two-layer soil system consisting of a compacted clayey silt underlain by an unsaturated fine gravel. Over the range of conditions examined, it is concluded that existing solute transport theory along with the proposed procedure for estimating the unsaturated diffusion coefficients can adequately predict chloride and sodium diffusion through both unsaturated coarse sand and fine gravel as well as predict advective-diffusive transport through a compacted clayey layer and underlying unsaturated fine gravel.

  10. Mass transport, faceting and behavior of dislocations in GaN

    SciTech Connect

    Nitta, S.; Kashima, T.; Kariya, M.; Yukawa, Y.; Yamaguchi, S.; Amano, H.; Akasaki, I.

    2000-07-01

    The behavior of threading dislocations during mass transport of GaN was investigated in detail by transmission electron microscopy. Mass transport occurred at the surface. Therefore, growing species are supplied from the in-plane direction. The behavior of threading dislocations was found to be strongly affected by the mass transport process as well as the high crystallographic anisotropy of the surface energy of the facets particular to GaN.

  11. A Quasi-Conservative Adaptive Semi-Lagrangian Advection-Diffusion Scheme

    NASA Astrophysics Data System (ADS)

    Behrens, Joern

    2014-05-01

    Many processes in atmospheric or oceanic tracer transport are conveniently represented by advection-diffusion type equations. Depending on the magnitudes of both components, the mathematical representation and consequently the discretization is a non-trivial problem. We will focus on advection-dominated situations and will introduce a semi-Lagrangian scheme with adaptive mesh refinement for high local resolution. This scheme is well suited for pollutant transport from point sources, or transport processes featuring fine filamentation with corresponding local concentration maxima. In order to achieve stability, accuracy and conservation, we combine an adaptive mesh refinement quasi-conservative semi-Lagrangian scheme, based on an integral formulation of the underlying advective conservation law (Behrens, 2006), with an advection diffusion scheme as described by Spiegelman and Katz (2006). The resulting scheme proves to be conservative and stable, while maintaining high computational efficiency and accuracy.

  12. Promising approaches to crystallization of macromolecules suppressing the convective mass transport to the growing crystal

    NASA Astrophysics Data System (ADS)

    Boyko, K. M.; Popov, V. O.; Kovalchuk, M. V.

    2015-08-01

    Conditions of mass transport to growing crystals are important factors that have an impact on the size and quality of macromolecular crystals. The mass transport occurs via two mechanisms — by diffusion and convection. The crystal quality can be influenced by changing (either suppressing or enhancing) the convective mass transport. The review gives an overview and analysis of the published data on different methods of macromolecular crystallization providing the suppression of convective mass transport to growing crystals in order to improve the crystal quality. The bibliography includes 91 references.

  13. Impact of internal transport on the convective mass transfer from a droplet into a submerging falling film

    NASA Astrophysics Data System (ADS)

    Landel, Julien R.; Thomas, Amalia; McEvoy, Harry; Dalziel, Stuart B.

    2015-11-01

    We investigate the convective mass transfer of dilute passive tracers contained in small viscous drops into a submerging falling film. This problem has applications in industrial cleaning, domestic dishwashers, and decontamination of hazardous material. The film Peclet number is very high, whereas the drop Peclet number varies from 0.1 to 1. The characteristic transport time in the drop is much larger than in the film. We model the mass transfer using an analogy with Newton's law of cooling. This empirical model is supported by an analytical model solving the quasi-steady two-dimensional advection-diffusion equation in the film that is coupled with a time-dependent one-dimensional diffusion equation in the drop. We find excellent agreement between our experimental data and the two models, which predict an exponential decrease in time of the drop concentration. The transport characteristic time is related to the drop diffusion time scale, as diffusion within the drop is the limiting process. Our theoretical model not only predicts the well-known relationship between the Sherwood number and the external Reynolds number in the case of a well-mixed drop Sh ~ Re1/3, it also predicts a correction in the case of a non-uniform drop concentration. The correction depends on Re, the film Schmidt number, the drop aspect ratio and the diffusivity ratio between the two phases. This prediction is in good agreement with experimental data. This material is based upon work supported by the Defense Threat Reduction Agency under Contract No. HDTRA1-12-D-0003-0001.

  14. Mass and Momentum Transport in Microcavities for Diffusion-Dominant Cell Culture Applications

    NASA Technical Reports Server (NTRS)

    Yew, Alvin G.; Pinero, Daniel; Hsieh, Adam H.; Atencia, Javier

    2012-01-01

    For the informed design of microfluidic devices, it is important to understand transport phenomena at the microscale. This letter outlines an analytically-driven approach to the design of rectangular microcavities extending perpendicular to a perfusion microchannel for microfluidic cell culture devices. We present equations to estimate the spatial transition from advection- to diffusion-dominant transport inside cavities as a function of the geometry and flow conditions. We also estimate the time required for molecules, such as nutrients or drugs to travel from the microchannel to a given depth into the cavity. These analytical predictions can facilitate the rational design of microfluidic devices to optimize and maintain long-term, physiologically-based culture conditions with low fluid shear stress.

  15. Mass Transport Phenomena in Lipid Oxidation and Antioxidation.

    PubMed

    Laguerre, Mickaël; Bily, Antoine; Roller, Marc; Birtić, Simona

    2017-02-28

    In lipid dispersions, the ability of reactants to move from one lipid particle to another is an important, yet often ignored, determinant of lipid oxidation and its inhibition by antioxidants. This review describes three putative interparticle transfer mechanisms for oxidants and antioxidants: (a) diffusion, (b) collision-exchange-separation, and (c) micelle-assisted transfer. Mechanism a involves the diffusion of molecules from one particle to another through the intervening aqueous phase. Mechanism b involves the transfer of molecules from one particle to another when the particles collide with each other. Mechanism c involves the solubilization of molecules in micelles within the aqueous phase and then their transfer between particles. During lipid oxidation, the accumulation of surface-active lipid hydroperoxides (LOOHs) beyond their critical micelle concentration may shift their mass transport from the collision-exchange-separation pathway (slow transfer) to the micelle-assisted mechanism (fast transfer), which may account for the transition from the initiation to the propagation phase. Similarly, the cut-off effect governing antioxidant activity in lipid dispersions may be due to the fact that above a certain hydrophobicity, the transfer mechanism for antioxidants changes from diffusion to collision-exchange-separation. This hypothesis provides a simple model to rationalize the design and formulation of antioxidants and dispersed lipids.

  16. Water mass structure and transport in the Tourbillon eddy

    NASA Astrophysics Data System (ADS)

    Harvey, John; Glynn, Simon

    1985-06-01

    CTD data collected during the Tourbillon Experiment have been used to identify the water masses present in a mesoscale eddy in the eastern North Atlantic, and their transports during the 50-day period of the Experiment. The core of the eddy was found to comprise North Atlantic Central Water within the temperature range 10 to 11°C, and evidence of downward movement of this water between 150 and 700 db and upward movement between 750 and 820 db is presented. Mediterranean Water (MW) was drawn around the eddy in a tongue which broke into separate patches during the Experiment. There is evidence of this MW having a dynamical role in the eddy: whilst it was present as a continuous tongue it did not progress around the eddy as fast as other water. There is also an indication of upward movement of this MW. The distribution of Labrador Sea Water showed some positive relationship to the location of the eddy centre, whilst low concentrations were noted beneath the MW tongue. Both θ-S analysis and charts of the planetary component of potential vorticity are used in an attempt to identify the source region of the eddy; it is concluded that the eddy had not moved far (perhaps 200 km) from its place of origin, and that the homogeneous water in its core may have been formed by deep winter convection somewhere between north and west of the area where the Experiment was conducted.

  17. Uncluttering graph layouts using anisotropic diffusion and mass transport.

    PubMed

    Frishman, Yaniv; Tal, Ayellet

    2009-01-01

    Many graph layouts include very dense areas, making the layout difficult to understand. In this paper, we propose a technique for modifying an existing layout in order to reduce the clutter in dense areas. A physically inspired evolution process based on a modified heat equation is used to create an improved layout density image, making better use of available screen space. Using results from optimal mass transport problems, a warp to the improved density image is computed. The graph nodes are displaced according to the warp. The warp maintains the overall structure of the graph, thus limiting disturbances to the mental map, while reducing the clutter in dense areas of the layout. The complexity of the algorithm depends mainly on the resolution of the image visualizing the graph and is linear in the size of the graph. This allows scaling the computation according to required running times. It is demonstrated how the algorithm can be significantly accelerated using a graphics processing unit (GPU), resulting in the ability to handle large graphs in a matter of seconds. Results on several layout algorithms and applications are demonstrated.

  18. Evolution and advection of solar mesogranulation

    NASA Technical Reports Server (NTRS)

    Muller, Richard; Auffret, Herve; Roudier, Thierry; Vigneau, Jean; Simon, George W.; Frank, Zoe; Shine, Richard A.; Title, Alan M.

    1992-01-01

    A three-hour sequence of observations at the Pic du Midi observatory has been obtained which shows the evolution of solar mesogranules from appearance to disappearance with unprecedented clarity. It is seen that the supergranules, which are known to advect the granules with their convective motion, also advect the mesogranules to their boundaries. This process controls the evolution and disappearance of mesogranules.

  19. Magnetic resonance imaging of mass transport and structure inside a phototrophic biofilm.

    PubMed

    Ramanan, Baheerathan; Holmes, William M; Sloan, William T; Phoenix, Vernon R

    2013-05-01

    The aim of this study was to utilize magnetic resonance imaging (MRI) to image structural heterogeneity and mass transport inside a biofilm which was too thick for photon based imaging. MRI was used to map water diffusion and image the transport of the paramagnetically tagged macromolecule, Gd-DTPA, inside a 2.5 mm thick cyanobacterial biofilm. The structural heterogeneity of the biofilm was imaged at resolutions down to 22 × 22 μm, enabling the impact of biofilm architecture on the mass transport of both water and Gd-DTPA to be investigated. Higher density areas of the biofilm correlated with areas exhibiting lower relative water diffusion coefficients and slower transport of Gd-DTPA, highlighting the impact of biofilm structure on mass transport phenomena. This approach has potential for shedding light on heterogeneous mass transport of a range of molecular mass molecules in biofilms.

  20. Statistical characteristics of velocity, concentration, mass transport, and momentum transport for coaxial jet mixing in a confined duct

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Bennett, J. C.

    1983-01-01

    An experimental study of mixing downstream of coaxial jets discharging into an expanded circular duct was conducted to obtain data for the evaluation and improvement of turbulent transport models currently used for combustor flow modeling. A combination of turbulent momentum transport rate and two velocity component data was obtained from simultaneous measurements with a two-color LV system. A combination of turbulent mass transport rate, concentration and velocity data was obtained from simultaneous measurements with laser velocimeter (LV) and laser induced fluorescence (LIF) systems. These measurements were used to obtain mean, second central moment, skewness and kurtosis values for three velocity components and the concentration. These measurements showed the existence of countergradient turbulent axial mass transport where the annular jet fluid was accelerating the inner jet fluid. Results from the study are related to the assumptions employed in the current mass and momentum turbulent transport models.

  1. Hydraulic and solute-transport properties and simulated advective transport of contaminated ground water in a fractured rock aquifer at the Naval Air Warfare Center, West Trenton, New Jersey, 2003

    USGS Publications Warehouse

    Lewis-Brown, Jean C.; Carleton, Glen B.; Imbrigiotta, Thomas E.

    2006-01-01

    Volatile organic compounds, predominantly trichloroethylene and its degradation products, have been detected in ground water at the Naval Air Warfare Center (NAWC), West Trenton, New Jersey. An air-stripping pump-and-treat system has been in operation at the NAWC since 1998. An existing ground-water-flow model was used to evaluate the effect of a change in the configuration of the network of recovery wells in the pump-and-treat system on flow paths of contaminated ground water. The NAWC is underlain by a fractured-rock aquifer composed of dipping layers of sedimentary rocks of the Lockatong and Stockton Formations. Hydraulic and solute-transport properties of the part of the aquifer composed of the Lockatong Formation were measured using aquifer tests and tracer tests. The heterogeneity of the rocks causes a wide range of values of each parameter measured. Transmissivity ranges from 95 to 1,300 feet squared per day; the storage coefficient ranges from 9 x 10-5 to 5 x 10-3; and the effective porosity ranges from 0.0003 to 0.002. The average linear velocity of contaminated ground water was determined for ambient conditions (when no wells at the site are pumped) using an existing ground-water-flow model, particle-tracking techniques, and the porosity values determined in this study. The average linear velocity of flow paths beginning at each contaminated well and ending at the streams where the flow paths terminate ranges from 0.08 to 130 feet per day. As a result of a change in the pump-and-treat system (adding a 165-foot-deep well pumped at 5 gallons per minute and reducing the pumping rate at a nearby 41-foot-deep well by the same amount), water in the vicinity of three 100- to 165-foot-deep wells flows to the deep well rather than the shallower well.

  2. Aerosol particles and the formation of advection fog

    NASA Technical Reports Server (NTRS)

    Hung, R. J.; Liaw, G. S.; Vaughan, O. H., Jr.

    1979-01-01

    A study of numerical simulation of the effects of concentration, particle size, mass of nuclei, and chemical composition on the dynamics of warm fog formation, particularly the formation of advection fog, is presented. This formation is associated with the aerosol particle characteristics, and both macrophysical and microphysical processes are considered. In the macrophysical model, the evolution of wind components, water vapor content, liquid water content, and potential temperature under the influences of vertical turbulent diffusion, turbulent momentum, and turbulent energy transfers are taken into account. In the microphysical model, the supersaturation effect is incorporated with the surface tension and hygroscopic material solution. It is shown that the aerosol particles with the higher number density, larger size nuclei, the heavier nuclei mass, and the higher ratio of the Van't Hoff factor to the molecular weight favor the formation of the lower visibility advection fogs with stronger vertical energy transfer during the nucleation and condensation time period.

  3. Theoretical monochromatic-wave-induced currents in intermediate water with viscosity and nonzero mass transport

    NASA Technical Reports Server (NTRS)

    Talay, T. A.

    1975-01-01

    Wave-induced mass-transport current theories with both zero and nonzero net mass (or volume) transport of the water column are reviewed. A relationship based on the Longuet-Higgens theory is derived for wave-induced, nonzero mass-transport currents in intermediate water depths for a viscous fluid. The relationship is in a form useful for experimental applications; therefore, some design criteria for experimental wave-tank tests are also presented. Sample parametric cases for typical wave-tank conditions and a typical ocean swell were assessed by using the relation in conjunction with an equation developed by Unluata and Mei for the maximum wave-induced volume transport. Calculations indicate that substantial changes in the wave-induced mass-transport current profiles may exist dependent upon the assumed net volume transport. A maximum volume transport, corresponding to an infinite channel or idealized ocean condition, produces the largest wave-induced mass-transport currents. These calculations suggest that wave-induced mass-transport currents may have considerable effects on pollution and suspended-sediments transport as well as buoy drift, the surface and midlayer water-column currents caused by waves increasing with increasing net volume transports. Some of these effects are discussed.

  4. A finite-volume Eulerian-Lagrangian localized adjoint method for solution of the advection-dispersion equation

    USGS Publications Warehouse

    Healy, R.W.; Russell, T.F.

    1993-01-01

    Test results demonstrate that the finite-volume Eulerian-Lagrangian localized adjoint method (FVELLAM) outperforms standard finite-difference methods for solute transport problems that are dominated by advection. FVELLAM systematically conserves mass globally with all types of boundary conditions. Integrated finite differences, instead of finite elements, are used to approximate the governing equation. This approach, in conjunction with a forward tracking scheme, greatly facilitates mass conservation. The mass storage integral is numerically evaluated at the current time level, and quadrature points are then tracked forward in time to the next level. Forward tracking permits straightforward treatment of inflow boundaries, thus avoiding the inherent problem in backtracking of characteristic lines intersecting inflow boundaries. FVELLAM extends previous results by obtaining mass conservation locally on Lagrangian space-time elements. -from Authors

  5. Characterization of physical mass transport through oil sands fluid fine tailings in an end pit lake: a multi-tracer study.

    PubMed

    Dompierre, Kathryn A; Barbour, S Lee

    2016-06-01

    Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.

  6. Characterization of physical mass transport through oil sands fluid fine tailings in an end pit lake: a multi-tracer study

    NASA Astrophysics Data System (ADS)

    Dompierre, Kathryn A.; Barbour, S. Lee

    2016-06-01

    Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.

  7. Advective velocity and energy dissipation rate in an oscillatory flow.

    PubMed

    Haider, Ziaul; Hondzo, Miki; Porte-Agel, Fernando

    2005-07-01

    Characterizing the transport processes at the sediment-water interface along sloping boundaries in lakes and reservoirs is of fundamental interest in lake and reservoir water quality management. The turbulent bottom boundary layer (TBBL) along a slope, induced by the breaking of internal waves in a linearly stratified fluid, was investigated through laboratory measurements. Fast response micro-scale conductivity and temperature probes in conjunction with laser-Doppler velocimetry were used to measure the time series of salinity, temperature, and velocity along a sloping boundary. Turbulent energy spectra were computed from the velocity data using a time-dependent advective velocity and Taylor's hypothesis. The energy spectra were used to estimate the energy dissipation rate at different positions in the TBBL. The advective velocity in this near-zero mean shear flow is based on an integral time scale (T(int)). The integral time scale is related to the average frequency of the spectral energy density of the flow velocity. The energy dissipation rate estimated from the variable advective velocity with an averaging time window equal to the integral time scale (T=T(int)) was 43% higher than the energy dissipation rate estimated from a constant advective velocity. The estimated dissipation rates with T=T(int) were comparable to values obtained by curve-fitting a theoretical Batchelor spectrum for the temperature gradient spectra. This study proposes the integral time scale to be used for the oscillatory flows as (a) a time-averaging window to estimate the advective velocity and associated energy dissipation level, and (b) a normalizing parameter in the energy spectrum.

  8. An operator splitting algorithm for the three-dimensional advection-diffusion equation

    NASA Astrophysics Data System (ADS)

    Khan, Liaqat Ali; Liu, Philip L.-F.

    1998-09-01

    Operator splitting algorithms are frequently used for solving the advection-diffusion equation, especially to deal with advection dominated transport problems. In this paper an operator splitting algorithm for the three-dimensional advection-diffusion equation is presented. The algorithm represents a second-order-accurate adaptation of the Holly and Preissmann scheme for three-dimensional problems. The governing equation is split into an advection equation and a diffusion equation, and they are solved by a backward method of characteristics and a finite element method, respectively. The Hermite interpolation function is used for interpolation of concentration in the advection step. The spatial gradients of concentration in the Hermite interpolation are obtained by solving equations for concentration gradients in the advection step. To make the composite algorithm efficient, only three equations for first-order concentration derivatives are solved in the diffusion step of computation. The higher-order spatial concentration gradients, necessary to advance the solution in a computational cycle, are obtained by numerical differentiations based on the available information. The simulation characteristics and accuracy of the proposed algorithm are demonstrated by several advection dominated transport problems.

  9. Channeling, channel density and mass recovery in aquifer transport, with application to the MADE experiment

    NASA Astrophysics Data System (ADS)

    Fiori, A.

    2014-12-01

    Channeling effects in heterogeneous formations are studied through a new quantity denoted as channel density a(x,t). Focusing on advection only, a(x,t) is defined as the relative number of streamtubes (or channels) containing solute between x and x + dx at a given time t, regardless of the mass that they carry. The channel density generally differs from the widely employed longitudinal mass distribution m(x,t), and their difference increases with time and the degree of heterogeneity. The difference between a and m reflects the nonuniformity of mass distribution relative to the plume geometry. In particular, the "fast" channels typically carry a larger fraction of mass than their share in their relative volume, which in turn can be rather small. Detecting such channels by a network of monitoring wells may be a challenging task, which might explain the poor solute recovery of some field experiments at increasing times. After application of the proposed concepts to the simple case of stratified formations, we model the channel density and mass distribution pertaining to the MADE experiment, which exhibited poor mass recovery at large times. The results presented in this study emphasize the possible channeling effects at MADE and the general difficulty in sampling the leading edge of the plume, which in turn may contain a significant fraction of the plume mass.

  10. Technology and human purpose: the problem of solids transport on the Earth's surface

    NASA Astrophysics Data System (ADS)

    Haff, P. K.

    2012-11-01

    Displacement of mass of limited deformability ("solids") on the Earth's surface is opposed by friction and (the analog of) form resistance - impediments relaxed by rotational motion, self-powering of mass units, and transport infrastructure. These features of solids transport first evolved in the biosphere prior to the emergence of technology, allowing slope-independent, diffusion-like motion of discrete objects as massive as several tons, as illustrated by animal foraging and movement along game trails. However, high-energy-consumption technology powered by fossil fuels required a mechanism that could support fast advective transport of solids, i.e., long-distance, high-volume, high-speed, unidirectional, slope-independent transport across the land surface of materials like coal, containerized fluids, minerals, and economic goods. Pre-technology nature was able to sustain regional- and global-scale advection only in the limited form of piggybacking on geophysical flows of water (river sediment) and air (dust). The appearance of a mechanism for sustained advection of solids independent of fluid flows and gravity appeared only upon the emergence of human purpose. Purpose enables solids advection by, in effect, simulating a continuous potential gradient, otherwise lacking, between discrete and widely separated fossil-fuel energy sources and sinks. Invoking purpose as a mechanism in solids advection is an example of the need to import anthropic principles and concepts into the language and methodology of modern Earth system dynamics. As part of the emergence of a generalized solids advection mechanism, several additional transport requirements necessary to the function of modern large-scale technological systems were also satisfied. These include spatially accurate delivery of advected payload, targetability to essentially arbitrarily located destinations (such as cities), and independence of structure of advected payload from transport mechanism. The latter property

  11. Technology and human purpose: the problem of solids transport on the earth's surface

    NASA Astrophysics Data System (ADS)

    Haff, P. K.

    2012-05-01

    Displacement of mass of limited deformability ("solids") on the Earth's surface is opposed by friction and (the analog of) form resistance - impediments relaxed by rotational motion, self-powering of mass units, and transport infrastructure. These features of solids transport first evolved in the biosphere prior to the emergence of technology, allowing slope-independent, diffusion-like motion of discrete objects as massive as several tons, as illustrated by animal foraging and movement along game trails. However, high-energy-consumption technology powered by fossil fuels required a mechanism that could support advective transport of solids, i.e., long-distance, high-volume, high-speed, unidirectional, slope independent transport across the land surface of materials like coal, containerized fluids, and minerals. Pre-technology nature was able to sustain large-scale, long-distance solids advection only in the limited form of piggybacking on geophysical flows of water (river sediment) and air (dust). The appearance of a generalized mechanism for advection of solids independent of fluid flows and gravity appeared only upon the emergence of human purpose. Purpose enables solids advection by, in effect, enabling a simulated continuous potential gradient, otherwise lacking, between discrete and widely separated fossil-fuel energy sources and sinks. Invoking purpose as a mechanism in solids advection is an example of the need to import anthropic principles and concepts into the language and methodology of modern Earth system dynamics. As part of the emergence of a generalized solids advection mechanism, several additional transport requirements necessary to the function of modern large-scale technological systems were also satisfied. These include spatially accurate delivery of advected payload, targetability to essentially arbitrarily located destinations (such as cities), and independence of structure of advected payload from transport mechanism. The latter property

  12. MASS TRANSPORT EFFECTS ON THE KINETICS OF NITROBENZENE REDUCTION BY IRON METAL. (R827117)

    EPA Science Inventory

    To evaluate the importance of external mass transport on the overall rates of
    contaminant reduction by iron metal (Fe0), we have compared measured
    rates of surface reaction for nitrobenzene (ArNO2) to estimated rates
    of external mass transport...

  13. Effects of solution mass transport on the ECC ozonesonde background current. [Electrochemical Concentration Cell

    NASA Technical Reports Server (NTRS)

    Thornton, D. C.; Niazy, N.

    1983-01-01

    A technique is developed to measure the effective mass transport parameter for the electrochemical concentration cell (ECC) ozonesonde in order to determine the mass transport rate constant for the ECC as a function of pressure. It is shown that a pressure dependent factor in the background current originates in a convective mass transport parameter. It is determined that for atmospheric pressures greater than 100 mb the mass transport parameter is a constant, while at pressures less than 100 mb it decreases logarithmically with pressure. It is suggested that the background current correction is directly correlated to the mass transport parameter pressure dependence. The presently used background current correction, which is based on the partial pressure of oxygen, is found to lead to an overestimation of the integrated ozone value in the troposphere for the ECC ozonesonde data.

  14. Integrated mass transportation system study/definition/implementation program definition

    NASA Technical Reports Server (NTRS)

    Ransone, R. K.; Deptula, D. A.; Yorke, G. G.

    1975-01-01

    Specific actions needed to plan and effect transportation system improvements are identified within the constraints of limited financial, energy and land use resources, and diverse community requirements. A specific program is described which would develop the necessary generalized methodology for devising improved transportation systems and evaluate them against specific criteria for intermodal and intramodal optimization. A consistent, generalized method is provided for study and evaluation of transportation system improvements.

  15. A high order characteristic discontinuous Galerkin scheme for advection on unstructured meshes

    NASA Astrophysics Data System (ADS)

    Lee, D.; Lowrie, R.; Petersen, M.; Ringler, T.; Hecht, M.

    2016-11-01

    A new characteristic discontinuous Galerkin (CDG) advection scheme is presented. In contrast to standard discontinuous Galerkin schemes, the test functions themselves follow characteristics in order to ensure conservation and the edges of each element are also traced backwards along characteristics in order to create a swept region, which is integrated in order to determine the mass flux across the edge. Both the accuracy and performance of the scheme are greatly improved by the use of large Courant-Friedrichs-Lewy numbers for a shear flow test case and the scheme is shown to scale sublinearly with the number of tracers being advected, outperforming a standard flux corrected transport scheme for 10 or more tracers with a linear basis. Moreover the CDG scheme may be run to arbitrarily high order spatial accuracy and on unstructured grids, and is shown to give the correct order of error convergence for piecewise linear and quadratic bases on regular quadrilateral and hexahedral planar grids. Using a modal Taylor series basis, the scheme may be made monotone while preserving conservation with the use of a standard slope limiter, although this reduces the formal accuracy of the scheme to first order. The second order scheme is roughly as accurate as the incremental remap scheme with nonlocal gradient reconstruction at half the horizontal resolution. The scheme is being developed for implementation within the Model for Prediction Across Scales (MPAS) Ocean model, an unstructured grid finite volume ocean model.

  16. An advective volume-balance model for flow in porous media

    NASA Astrophysics Data System (ADS)

    Malaga, Carlos; Mandujano, Francisco; Becerra, Julian

    2016-11-01

    Volume-balance models are used by petroleum engineers to simulate multiphase and multicomponent flow phenomena in porous media and the extraction process in oil reservoirs. In these models, mass conservation equations and Darcy's law are supplemented by a balance condition for the pore and fluid volumes. This provides a pressure equation suitable for simulating a compressible flow within a compressible solid matrix. Here we present an alternative interpretation of the volume-balance condition that includes the advective transport within a consolidated porous media. We obtain a modified equation for the time evolution of the pressure field. Preliminary numerical tests of phase separation due to gravity suggest the model reproduces qualitatively the physical phenomena. Fondo Sectorial CONACYT-SENER Grant Number 42536 (DGAJ-SPI-34-170412-217).

  17. Evolution and Advection of Solar Mesogranulation

    DTIC Science & Technology

    1992-03-01

    unprecedented clarity. We see that the supergranules, which are known to carry along (advect) the granules with their convective motion, also advect...I Solar mesogranulation, Solar observations, Solar super- 2 granulation 16. PRICE COCE 1i7. SECJ-3T LSiIATO 8 EUITY CLASSIFICA ION 19. SECURITY CLAS...mo~iesý sho~ed that granules are adl~ectedl b• Richard Muller*, Hers& Auffret*, Thierry Roudiert, the larger-scale consectie flowss. and thu, could

  18. Hybrid Multiscale Finite Volume Method for Advection-Diffusion Equations Subject to Heterogeneous Reactive Boundary Conditions

    SciTech Connect

    Barajas-Solano, David A.; Tartakovsky, A. M.

    2016-10-13

    We present a hybrid scheme for the coupling of macro and microscale continuum models for reactive contaminant transport in fractured and porous media. The transport model considered is the advection-dispersion equation, subject to linear heterogeneous reactive boundary conditions. The Multiscale Finite Volume method (MsFV) is employed to define an approximation to the microscale concentration field defined in terms of macroscopic or \\emph{global} degrees of freedom, together with local interpolator and corrector functions capturing microscopic spatial variability. The macroscopic mass balance relations for the MsFV global degrees of freedom are coupled with the macroscopic model, resulting in a global problem for the simultaneous time-stepping of all macroscopic degrees of freedom throughout the domain. In order to perform the hybrid coupling, the micro and macroscale models are applied over overlapping subdomains of the simulation domain, with the overlap denoted as the handshake subdomain $\\Omega^{hs}$, over which continuity of concentration and transport fluxes between models is enforced. Continuity of concentration is enforced by posing a restriction relation between models over $\\Omega^{hs}$. Continuity of fluxes is enforced by prolongating the macroscopic model fluxes across the boundary of $\\Omega^{hs}$ to microscopic resolution. The microscopic interpolator and corrector functions are solutions to local microscopic advection-diffusion problems decoupled from the global degrees of freedom and from each other by virtue of the MsFV decoupling ansatz. The error introduced by the decoupling ansatz is reduced iteratively by the preconditioned GMRES algorithm, with the hybrid MsFV operator serving as the preconditioner.

  19. Measurement and Visualization of Mass Transport for the Flowing Atmospheric Pressure Afterglow (FAPA) Ambient Mass-Spectrometry Source

    NASA Astrophysics Data System (ADS)

    Pfeuffer, Kevin P.; Ray, Steven J.; Hieftje, Gary M.

    2014-05-01

    Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last 9 years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification because of the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet.

  20. Measurement and visualization of mass transport for the flowing atmospheric pressure afterglow (FAPA) ambient mass-spectrometry source.

    PubMed

    Pfeuffer, Kevin P; Ray, Steven J; Hieftje, Gary M

    2014-05-01

    Ambient desorption/ionization mass spectrometry (ADI-MS) has developed into an important analytical field over the last 9 years. The ability to analyze samples under ambient conditions while retaining the sensitivity and specificity of mass spectrometry has led to numerous applications and a corresponding jump in the popularity of this field. Despite the great potential of ADI-MS, problems remain in the areas of ion identification and quantification. Difficulties with ion identification can be solved through modified instrumentation, including accurate-mass or MS/MS capabilities for analyte identification. More difficult problems include quantification because of the ambient nature of the sampling process. To characterize and improve sample volatilization, ionization, and introduction into the mass spectrometer interface, a method of visualizing mass transport into the mass spectrometer is needed. Schlieren imaging is a well-established technique that renders small changes in refractive index visible. Here, schlieren imaging was used to visualize helium flow from a plasma-based ADI-MS source into a mass spectrometer while ion signals were recorded. Optimal sample positions for melting-point capillary and transmission-mode (stainless steel mesh) introduction were found to be near (within 1 mm of) the mass spectrometer inlet. Additionally, the orientation of the sampled surface plays a significant role. More efficient mass transport resulted for analyte deposits directly facing the MS inlet. Different surfaces (glass slide and rough surface) were also examined; for both it was found that the optimal position is immediately beneath the MS inlet.

  1. Specifications for the development of a fully three-dimensional numerical groundwater model for regional mass transport of radionuclides from a deep waste repository

    SciTech Connect

    Prickett, T.A.

    1980-04-01

    Specifications are given which are necessary to develop a three-dimensional numerical model capable of simulating regional mass transport of radionuclides from a deep waste repository. The model to be developed will include all of the significant mass transport processes including flow, chemical, and thermal advection, mechanical dispersion, molecular diffusion, ion exchange reactions, and radioactive decay. The model specifications also include that density and viscosity fluid properties be functions of pressure, temperature, and concentration and take into account fluid and geologic heterogenieties by allowing possible assignment of individual values to every block of the model. The model specifications furthermore include the repository shape, input/output information, boundary conditions, and the need for documentation and a user's manual. Model code validation can be accomplished with the included known analytical or laboratory solutions. It is recommended that an existing finite-difference model (developed by INTERCOMP and INTERA, Inc.) be used as a starting point either as an acceptable basic code for modification or as a pattern for the development of a completely different numerical scheme. A ten-step plan is given to outline the general procedure for development of the code.

  2. Fold and thrust systems in Mass Transport Deposits

    NASA Astrophysics Data System (ADS)

    Alsop, G. I.; Marco, S.; Levi, T.; Weinberger, R.

    2017-01-01

    Improvements in seismic reflection data from gravity-driven fold and thrust systems developed in offshore Mass Transport Deposits (MTDs) reveal a number of significant features relating to displacement along thrusts. However, the data are still limited by the resolution of the seismic method, and are unable to provide detail of local fold and thrust processes. Investigation of exceptional gravity-driven contractional structures forming part of MTDs in lacustrine deposits of the Dead Sea Basin, enables us to present the first detailed outcrop analysis of fold and thrust systems cutting unlithified 'soft' sediments. We employ a range of established geometric techniques to our case study, including dip isogons, fault-propagation fold charts and displacement-distance diagrams previously developed for investigation of thrusts and folds in lithified rocks. Fault-propagation folds in unlithified sediments display tighter interlimb angles compared to models developed for lithified sequences. Values of stretch, which compares the relative thickness of equivalent hangingwall and footwall sequences measured along the fault plane, may be as low as only 0.3, which is significantly less than the minimum 0.5 values reported from thrusts cutting lithified rocks, and reflects the extreme variation in stratigraphic thickness around thrust-related folds. We suggest that the simple shear component of deformation in unlithified sediments may modify the forelimb thickness and interlimb angles to a greater extent than in lithified rocks. The average spacing of thrust ramps and the thickness of the thrust sequence display an approximate 5:1 ratio across a range of scales in MTDs. In general, thicker hangingwall and footwall sequences occur with larger thrust displacements, although displacement patterns on thrusts cutting unlithified (yet cohesive) sediments are more variable than those in lithified rocks. Line-length restoration of thrust systems in MTDs reveals 42% shortening, which

  3. Thermo-chemical convection in planetary mantles: advection methods and magma ocean overturn simulations

    NASA Astrophysics Data System (ADS)

    Plesa, A.-C.; Tosi, N.; Hüttig, C.

    2012-04-01

    Thermal and chemical convection in planetary mantles are the most dominant dynamical processes influencing the thermal and geological evolution of a planet. After the planetary formation, convection in the interior is one of the most prominent processes being responsible for the heat transport efficiency, the interior structure, the magnetic field generation and the geological structures at the surface of a planet such as volcanoes, rifts and others. The slow creep of the silicate materials that make up the mantle of terrestrial planets (i.e. Mercury, Venus, the Earth and Mars) is driven by a combination of thermal and compositional buoyancy. On the one hand, the primordial heat accumulated after accretion and core formation and the heat released by the decay of radiogenic isotopes are transported from the interior to the surface by thermal convection. This process involves the transfer of heat both via diffusion, which occurs mainly across thermal boundary layers, and advection due to fluid motion in the bulk of the mantle. On the other hand, density anomalies of non-thermal origin associated with chemical (i.e. compositional) heterogeneities provide an additional source of buoyancy that actively contributes to the transport of energy and mass. In the present work we discuss the modeling of active compositional fields in the framework of solid-state mantle convection using the 3D spherical/2D cylindrical code Gaia [1, 2]. Numerical methods for the advection of active compositional fields fall in two main categories [3, 4]. They are based either on a fixed computational grid (Eulerian methods) or on evolving grids or moving particles (Lagrangian methods). We compare an Eulerian method based on double-diffusive convection against a Lagrangian, particle-based method. Though straightforward, the first method generally suffers from non-negligible numerical diffusion and demands then the use of grids with a high resolution. Moreover, its accuracy can substantially

  4. The contiguous domains of Arctic Ocean advection: Trails of life and death

    NASA Astrophysics Data System (ADS)

    Wassmann, P.; Kosobokova, K. N.; Slagstad, D.; Drinkwater, K. F.; Hopcroft, R. R.; Moore, S. E.; Ellingsen, I.; Nelson, R. J.; Carmack, E.; Popova, E.; Berge, J.

    2015-12-01

    The central Arctic Ocean is not isolated, but tightly connected to the northern Pacific and Atlantic Oceans. Advection of nutrient-, detritus- and plankton-rich waters into the Arctic Ocean forms lengthy contiguous domains that connect subarctic with the arctic biota, supporting both primary production and higher trophic level consumers. In turn, the Arctic influences the physical, chemical and biological oceanography of adjacent subarctic waters through southward fluxes. However, exports of biomass out of the Arctic Ocean into both the Pacific and Atlantic Oceans are thought to be far smaller than the northward influx. Thus, Arctic Ocean ecosystems are net biomass beneficiaries through advection. The biotic impact of Atlantic- and Pacific-origin taxa in arctic waters depends on the total supply of allochthonously-produced biomass, their ability to survive as adults and their (unsuccessful) reproduction in the new environment. Thus, advective transport can be thought of as trails of life and death in the Arctic Ocean. Through direct and indirect (mammal stomachs, models) observations this overview presents information about the advection and fate of zooplankton in the Arctic Ocean, now and in the future. The main zooplankton organisms subjected to advection into and inside the Arctic Ocean are (a) oceanic expatriates of boreal Atlantic and Pacific origin, (b) oceanic Arctic residents and (c) neritic Arctic expatriates. As compared to the Pacific gateway the advective supply of zooplankton biomass through the Atlantic gateways is 2-3 times higher. Advection characterises how the main planktonic organisms interact along the contiguous domains and shows how the subarctic production regimes fuel life in the Arctic Ocean. The main differences in the advective regimes through the Pacific and Atlantic gateways are presented. The Arctic Ocean is, at least in some regions, a net heterotrophic ocean that - during the foreseeable global warming trend - will more and more rely

  5. Mass Transport Separation via Grace: Anthropogenic and Natural Change

    NASA Astrophysics Data System (ADS)

    Dickey, J. O.; de Viron, O.

    2011-12-01

    The GRACE satellite has been monitoring the change in the mass distribution at the Earth surface for nearly 10 years. This becomes enough to study long-term mass change, and to separate interannual variations from trends. Up to now, many studies have shown a fast (and non-linear) loss of mass in many glaciers and ice sheets. They all have been attributed to global warming, though part of the mass variation is also associated with the classical long-term climate variation. Using climatic data as well as the GRACE mascon solution, we can separate the part associated to the anthropogenic part from the non-anthropogenic part, in order to better estimate those contributions. Results and implications from our analyses will be presented.

  6. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media

    PubMed Central

    Falk, Kerstin; Coasne, Benoit; Pellenq, Roland; Ulm, Franz-Josef; Bocquet, Lydéric

    2015-01-01

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to account for their ultra-low permeability and complexity. Here, we use molecular simulation and statistical mechanics to show that continuum description—Darcy's law—fails to predict transport in shales nanoporous matrix (kerogen). The non-Darcy behaviour arises from strong adsorption in kerogen and the breakdown of hydrodynamics at the nanoscale, which contradict the assumption of viscous flow. Despite this complexity, all permeances collapse on a master curve with an unexpected dependence on alkane length. We rationalize this non-hydrodynamic behaviour using a molecular description capturing the scaling of permeance with alkane length and density. These results, which stress the need for a change of paradigm from classical descriptions to nanofluidic transport, have implications for shale gas but more generally for transport in nanoporous media. PMID:25901931

  7. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media.

    PubMed

    Falk, Kerstin; Coasne, Benoit; Pellenq, Roland; Ulm, Franz-Josef; Bocquet, Lydéric

    2015-04-22

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to account for their ultra-low permeability and complexity. Here, we use molecular simulation and statistical mechanics to show that continuum description--Darcy's law--fails to predict transport in shales nanoporous matrix (kerogen). The non-Darcy behaviour arises from strong adsorption in kerogen and the breakdown of hydrodynamics at the nanoscale, which contradict the assumption of viscous flow. Despite this complexity, all permeances collapse on a master curve with an unexpected dependence on alkane length. We rationalize this non-hydrodynamic behaviour using a molecular description capturing the scaling of permeance with alkane length and density. These results, which stress the need for a change of paradigm from classical descriptions to nanofluidic transport, have implications for shale gas but more generally for transport in nanoporous media.

  8. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media

    NASA Astrophysics Data System (ADS)

    Falk, Kerstin; Coasne, Benoit; Pellenq, Roland; Ulm, Franz-Josef; Bocquet, Lydéric

    2015-04-01

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to account for their ultra-low permeability and complexity. Here, we use molecular simulation and statistical mechanics to show that continuum description--Darcy's law--fails to predict transport in shales nanoporous matrix (kerogen). The non-Darcy behaviour arises from strong adsorption in kerogen and the breakdown of hydrodynamics at the nanoscale, which contradict the assumption of viscous flow. Despite this complexity, all permeances collapse on a master curve with an unexpected dependence on alkane length. We rationalize this non-hydrodynamic behaviour using a molecular description capturing the scaling of permeance with alkane length and density. These results, which stress the need for a change of paradigm from classical descriptions to nanofluidic transport, have implications for shale gas but more generally for transport in nanoporous media.

  9. Mass transport in salt repositories: Steady-state transport through interbeds

    SciTech Connect

    Hwang, Y.; Lee, W.W.-L.; Chambre, P.L.; Pigford, T.H. . Dept. of Nuclear Engineering)

    1989-03-01

    Salt has long been a candidate for geologic disposal of nuclear waste. Because salt is extremely soluble in water, the existence of rock salt in the ground atest to the long-term stability of the salt. Both bedded salt and salt domes have been considered for nuclear waste disposal in the United States and Europe. While the salt is known to be quite pure in salt domes, bedded salt is interlaced with beds of sediments. Traditionally rock salt has not been considered water-conducting, but sediments layers would be classical porous media, capable of conducting water. Therefore there is interest in determining whether interbeds in bedded salt constitute pathway for radionuclide migration. In this report we consider steady-state migration of radionuclides from a single waste cylinder into a single interbed. Two approaches are used. In 1982 Neretnieks proposed an approach for calculating the steady-state transport of oxidants to a copper container. We have adapted that approach for calculating steady-state radionuclide migration away from the waste package, as a first approximation. We have also analyzed the problem of time-dependent radionuclide diffusion from a container through a backfill layer into a fracture, and we used the steady-state solution from that problem for comparison. Section 2 gives a brief summary of the geology of interbeds in bedded salt. Section 3 presents the mass transfer resistances approach of Neretnieks, summarizing the formulation and giving numerical illustrations of the steady-state two-dimensional diffusion analysis. Section 4 gives a brief statement of the steady-state result from a related analysis. Conclusions are stated in Section 5. 13 refs., 5 figs., 2 tabs.

  10. Hydrodynamic and Mass Transport Properties of Microfluidic Geometries

    DTIC Science & Technology

    2013-12-01

    Bioanalytical Chemistry, 391:2453–2467, 2008. 18 [34] D. Mark, S. Haeberle, G. Roth , F. Von Setten, and R. Zengerle. Microfluidic lab-on-a-chip platforms...Biophysical Journal, 75:583–594, 1998. 23 [81] T. Mason , A. Pineda, C. Wofsy, and B. Goldstein. Effec- tive Rate Models for the Analysis of Transport

  11. Measurements of the transport efficiency of the fragment mass analyzer

    SciTech Connect

    Back, B.B.; Blumenthal, D.J.; Davids, C.N.

    1995-08-01

    Extensive calculations of the transport of reaction products were carried out during the design phase of the instrument using the computer code GIOS. These show that the energy acceptance depends strongly on the angular deviation from the optical axis of the instrument. In order to reliably measure cross sections using this instrument it is therefore necessary to verify these calculations empirically.

  12. Application of a Particle Method to the Advection-Diffusion-Reaction Equation

    NASA Astrophysics Data System (ADS)

    Paster, A.; Bolster, D.; Benson, D. A.

    2012-12-01

    A reaction between two chemical species can only happen if molecules collide and react. Thus, the mixing of a system can become a limiting factor in the onset of reaction. Solving for reaction rate in a well-mixed system is typically a straightforward task. However, when incomplete mixing kicks in, obtaining a solution becomes more challenging. Since reaction can only happen in regions where both reactants co-exist, the incomplete mixing may slow down the reaction rate, when compared to a well-mixed system. The effect of incomplete mixing upon reaction is a highly important aspect of various processes in natural and engineered systems, ranging from mineral precipitation in geological formations to groundwater remediation in aquifers. We study a relatively simple system with a bi-molecular irreversible kinetic reaction A+B → Ø where the underlying transport of reactants is governed by an advection-diffusion equation, and the initial concentrations are given in terms of an average and a perturbation. Such a system does not have an analytical solution to date, even for the zero advection case. We model the system by a Monte Carlo particle tracking method, where particles represent some reactant mass. In this method, diffusion is modeled by a random walk of the particles, and reaction is modeled by annihilation of particles. The probability of the annihilation is proportional to the reaction rate constant and the probability density associated with particle co-location. We study the numerical method in depth, characterizing typical numerical errors and time step restrictions. In particular, we show that the numerical method converges to the advection-diffusion-reaction equation at the limit Δt →0. We also rigorously derive the relationship between the initial number of particles in the system and the initial concentrations perturbations represented by that number. We then use the particle simulations of zero-advection system to demonstrate the well

  13. Update on Advection-Diffusion Purge Flow Model

    NASA Technical Reports Server (NTRS)

    Brieda, Lubos

    2015-01-01

    Gaseous purge is commonly used in sensitive spacecraft optical or electronic instruments to prevent infiltration of contaminants and/or water vapor. Typically, purge is sized using simplistic zero-dimensional models that do not take into account instrument geometry, surface effects, and the dependence of diffusive flux on the concentration gradient. For this reason, an axisymmetric computational fluid dynamics (CFD) simulation was recently developed to model contaminant infiltration and removal by purge. The solver uses a combined Navier-Stokes and Advection-Diffusion approach. In this talk, we report on updates in the model, namely inclusion of a particulate transport model.

  14. Subsurface barrier design alternatives for confinement and controlled advection flow

    SciTech Connect

    Phillips, S.J.; Stewart, W.E.; Alexander, R.G.; Cantrell, K.J.; McLaughlin, T.J.

    1994-02-01

    Various technologies and designs are being considered to serve as subsurface barriers to confine or control contaminant migration from underground waste storage or disposal structures containing radioactive and hazardous wastes. Alternatives including direct-coupled flood and controlled advection designs are described as preconceptual examples. Prototype geotechnical equipment for testing and demonstration of these alternative designs tested at the Hanford Geotechnical Development and Test Facility and the Hanford Small-Tube Lysimeter Facility include mobile high-pressure injectors and pumps, mobile transport and pumping units, vibratory and impact pile drivers, and mobile batching systems. Preliminary laboratory testing of barrier materials and additive sequestering agents have been completed and are described.

  15. Is Chaotic Advection Inherent to Porous Media Flow?

    NASA Astrophysics Data System (ADS)

    Lester, Daniel; Metcalfe, Guy; Trefry, Mike

    2013-11-01

    All porous media, including granular and packed media, fractured and open networks, are typified by the inherent topological complexity of the pore-space. This topological complexity admits a large number density of stagnation points under steady Stokes flow, which in turn generates a 3D fluid mechanical analouge of the Bakers map, termed the Baker's flow. We demonstrate that via this mechanism, chaotic advection at the pore-scale is inherent to almost all porous media under reasonable conditions, and such dynamics have significant implications for a range of fluid-borne processes including transport and mixing, chemical reactions and biological activity.

  16. Surfzone alongshore advective accelerations: observations and modeling

    NASA Astrophysics Data System (ADS)

    Hansen, J.; Raubenheimer, B.; Elgar, S.

    2014-12-01

    The sources, magnitudes, and impacts of non-linear advective accelerations on alongshore surfzone currents are investigated with observations and a numerical model. Previous numerical modeling results have indicated that advective accelerations are an important contribution to the alongshore force balance, and are required to understand spatial variations in alongshore currents (which may result in spatially variable morphological change). However, most prior observational studies have neglected advective accelerations in the alongshore force balance. Using a numerical model (Delft3D) to predict optimal sensor locations, a dense array of 26 colocated current meters and pressure sensors was deployed between the shoreline and 3-m water depth over a 200 by 115 m region near Duck, NC in fall 2013. The array included 7 cross- and 3 alongshore transects. Here, observational and numerical estimates of the dominant forcing terms in the alongshore balance (pressure and radiation-stress gradients) and the advective acceleration terms will be compared with each other. In addition, the numerical model will be used to examine the force balance, including sources of velocity gradients, at a higher spatial resolution than possible with the instrument array. Preliminary numerical results indicate that at O(10-100 m) alongshore scales, bathymetric variations and the ensuing alongshore variations in the wave field and subsequent forcing are the dominant sources of the modeled velocity gradients and advective accelerations. Additional simulations and analysis of the observations will be presented. Funded by NSF and ASDR&E.

  17. Effects of demographic stochasticity on population persistence in advective media.

    PubMed

    Kolpas, Allison; Nisbet, Roger M

    2010-07-01

    Many populations live and disperse in advective media. A fundamental question, known as the "drift paradox" in stream ecology, is how a closed population can survive when it is constantly being transported downstream by the flow. Recent population-level models have focused on the role of diffusive movement in balancing the effects of advection, predicting critical conditions for persistence. Here, we formulate an individual-based stochastic analog of the model described in (Lutscher et al., SIAM Rev. 47(4):749-772, 2005) to quantify the effects of demographic stochasticity on persistence. Population dynamics are modeled as a logistic growth process and dispersal as a position-jump process on a finite domain divided into patches. When there is no correlation in the interpatch movement of residents, stochasticity simply smooths the persistence-extinction boundary. However, when individuals disperse in "packets" from one patch to another and the flow field is memoryless on the timescale of packet transport, the probability of persistence is greatly enhanced. The latter transport mechanism may be characteristic of larval dispersal in the coastal ocean or wind-dispersed seed pods.

  18. Chaotic advection in 2D anisotropic porous media

    NASA Astrophysics Data System (ADS)

    Varghese, Stephen; Speetjens, Michel; Trieling, Ruben; Toschi, Federico

    2015-11-01

    Traditional methods for heat recovery from underground geothermal reservoirs employ a static system of injector-producer wells. Recent studies in literature have shown that using a well-devised pumping scheme, through actuation of multiple injector-producer wells, can dramatically enhance production rates due to the increased scalar / heat transport by means of chaotic advection. However the effect of reservoir anisotropy on kinematic mixing and heat transport is unknown and has to be incorporated and studied for practical deployment in the field. As a first step, we numerically investigate the effect of anisotropy (both magnitude and direction) on (chaotic) advection of passive tracers in a time-periodic Darcy flow within a 2D circular domain driven by periodically reoriented diametrically opposite source-sink pairs. Preliminary results indicate that anisotropy has a significant impact on the location, shape and size of coherent structures in the Poincare sections. This implies that the optimal operating parameters (well spacing, time period of well actuation) may vary strongly and must be carefully chosen so as to enhance subsurface transport. This work is part of the research program of the Foundation for Fundamental Research on Matter (FOM), which is part of Netherlands Organisation for Scientific Research (NWO). This research program is co-financed by Shell Global Solutions International B.V.

  19. Structural design of a double-layered porous hydrogel for effective mass transport.

    PubMed

    Kim, Hyejeong; Kim, Hyeon Jeong; Huh, Hyung Kyu; Hwang, Hyung Ju; Lee, Sang Joon

    2015-03-01

    Mass transport in porous materials is universal in nature, and its worth attracts great attention in many engineering applications. Plant leaves, which work as natural hydraulic pumps for water uptake, have evolved to have the morphological structure for fast water transport to compensate large water loss by leaf transpiration. In this study, we tried to deduce the advantageous structural features of plant leaves for practical applications. Inspired by the tissue organization of the hydraulic pathways in plant leaves, analogous double-layered porous models were fabricated using agarose hydrogel. Solute transport through the hydrogel models with different thickness ratios of the two layers was experimentally observed. In addition, numerical simulation and theoretical analysis were carried out with varying porosity and thickness ratio to investigate the effect of structural factors on mass transport ability. A simple parametric study was also conducted to examine unveiled relations between structural factors. As a result, the porosity and thickness ratio of the two layers are found to govern the mass transport ability in double-layered porous materials. The hydrogel models with widely dispersed pores at a fixed porosity, i.e., close to a homogeneously porous structure, are mostly turned out to exhibit fast mass transport. The present results would provide a new framework for fundamental design of various porous structures for effective mass transport.

  20. Analysis of the contribution of sedimentation to bacterial mass transport in a parallel plate flow chamber.

    PubMed

    Li, Jiuyi; Busscher, Henk J; Norde, Willem; Sjollema, Jelmer

    2011-05-01

    In order to investigate bacterium-substratum interactions, understanding of bacterial mass transport is necessary. Comparisons of experimentally observed initial deposition rates with mass transport rates in parallel-plate-flow-chambers (PPFC) predicted by convective-diffusion yielded deposition efficiencies above unity, despite electrostatic repulsion. It is hypothesized that sedimentation is the major mass transport mechanism in a PPFC. The contribution of sedimentation to the mass transport in a PPFC was experimentally investigated by introducing a novel microscopy-based method. First, height-dependent bacterial concentrations were measured at different times and flow rates and used to calculate bacterial sedimentation velocities. For Staphylococcus aureus ATCC 12600, a sedimentation velocity of 240 μm h(-1) was obtained. Therewith, sedimentation appeared as the predominant contribution to mass transport in a PPFC. Also in the current study, deposition efficiencies of S. aureus ATCC 12600 with respect to the Smoluchowski-Levich solution of the convective-diffusion equation were four-to-five fold higher than unity. However, calculation of deposition efficiencies with respect to sedimentation were below unity and decreased from 0.78 to 0.36 when flow rates increased from 0.017 to 0.33 cm(3) s(-1). The proposed analysis of bacterial mass transport processes is simple, does not require additional equipment and yields a more reasonable interpretation of bacterial deposition in a PPFC.

  1. Smooth information flow in temperature climate network reflects mass transport

    NASA Astrophysics Data System (ADS)

    Hlinka, Jaroslav; Jajcay, Nikola; Hartman, David; Paluš, Milan

    2017-03-01

    A directed climate network is constructed by Granger causality analysis of air temperature time series from a regular grid covering the whole Earth. Using winner-takes-all network thresholding approach, a structure of a smooth information flow is revealed, hidden to previous studies. The relevance of this observation is confirmed by comparison with the air mass transfer defined by the wind field. Their close relation illustrates that although the information transferred due to the causal influence is not a physical quantity, the information transfer is tied to the transfer of mass and energy.

  2. Effect of dissolved organic carbon on the transport and attachment behaviors of Cryptosporidium parvum oocysts and carboxylate-modified microspheres advected through temperate humic and tropical volcanic agricultural soil.

    PubMed

    Mohanram, Arvind; Ray, Chittaranjan; Metge, David W; Barber, Larry B; Ryan, Joseph N; Harvey, Ronald W

    2012-02-21

    Transport of Cryptosporidium parvum oocysts and microspheres in two disparate (a clay- and Fe-rich, volcanic and a temperate, humic) agricultural soils were studied in the presence and absence of 100 mg L(-1) of sodium dodecyl benzene sulfonate (SDBS), and Suwannee River Humic Acid (SRHA) at pH 5.0-6.0. Transport of carboxylate-modified, 1.8 μm microspheres in soil columns was highly sensitive to the nature of the dissolved organic carbon (DOC), whereas oocysts transport was more affected by soil mineralogy. SDBS increased transport of microspheres from 48% to 87% through the tropical soil and from 43% to 93% in temperate soil. In contrast, SRHA reduced transport of microspheres from 48% to 28% in tropical soil and from 43% to 16% in temperate soil. SDBS also increased oocysts transport through the temperate soil 5-fold, whereas no oocyst transport was detected in tropical soil. SRHA had only a nominal effect in increasing oocysts transport in tropical soil, but caused a 6-fold increase in transport through the temperate soil. Amendments of only 4 mg L(-1) SRHA and SDBS decreased oocyst hydrophobicity from 66% to 20% and from 66% to 5%, respectively. However, SDBS increased microsphere hydrophobicity from 16% to 33%. Soil fines, which includes clays, and SRHA, both caused the oocysts zeta potential (ζ) to become more negative, but caused the highly hydrophilic microspheres to become less negatively charged. The disparate behaviors of the two colloids in the presence of an ionic surfactant and natural organic matter suggest that microspheres may not be suitable surrogates for oocysts in certain types of soils. These results indicate that whether or not DOC inhibits or promotes transport of oocysts and microspheres in agricultural soils and by how much, depends not only on the surface characteristics of the colloid, but the nature of the DOC and the soil mineralogy.

  3. Quasi-synoptic transport, budgets and water mass transformation in the Azores-Gibraltar Strait region during summer 2009

    NASA Astrophysics Data System (ADS)

    Carracedo Segade, Lidia Isabel; Gilcoto, Miguel; Mercier, Herlé; Pérez, Fiz Fernández

    2015-01-01

    We describe the circulation patterns in the Azores-Gibraltar Strait region (North-Eastern Atlantic) during the 2009 CAIBOX cruise on the basis of hydrographic and direct current velocity measurements. This study offers new data for a region where importation of central waters (subpolar and subtropical modes of Eastern North Atlantic Central Water) and exports of Mediterranean Water are strongly related to large-scale dynamics in the North Atlantic Ocean (Azores Current-Mediterranean Water system). The description is backed up quantitatively by the results of a box inverse model, which was used to obtain absolute water mass transport values consistent with thermal wind equations and with conservation of volume, salt and heat. The contributions of water masses were determined in an extended Optimum Multiparameter Analysis from a quasi-synoptic point of view, providing detail in addition to volume, salt and heat transport. The surface-subsurface large-scale current system in the region consists of the Azores Current (13.1 ± 2.5 Sverdrup [Sv], 1 Sv = 106 m3 s-1), the Azores Counter-Current (5.2 ± 2.1 Sv), the Portugal Current (4.5 ± 1.4 Sv) and the Canary Current (7.1 ± 1.1 Sv). Broadly speaking, central waters are imported into the CAIBOX region at a rate of 1.6 ± 0.9 Sv, and Mediterranean Water is exported at a rate of 1.5 ± 0.4 Sv. The downwelling of central waters west of Gibraltar Strait was quantified at 1.1 Sv. Not all this volume participates in MW formation, but 0.8 Sv of entrained central waters; of which 0.5 Sv are from central waters of subpolar origin and 0.3 Sv from subtropical central waters. Of the 4.9 Sv of subtropical central waters advected by the Azores Current, about 0.7 Sv would reach the Gulf of Cadiz region either to take part in central water entrainment or to flow across the Gibraltar Strait as part of the Atlantic inflow to the Mediterranean Sea.

  4. Mass Transport through Nanostructured Membranes: Towards a Predictive Tool

    PubMed Central

    Darvishmanesh, Siavash; Van der Bruggen, Bart

    2016-01-01

    This study proposes a new mechanism to understand the transport of solvents through nanostructured membranes from a fundamental point of view. The findings are used to develop readily applicable mathematical models to predict solvent fluxes and solute rejections through solvent resistant membranes used for nanofiltration. The new model was developed based on a pore-flow type of transport. New parameters found to be of fundamental importance were introduced to the equation, i.e., the affinity of the solute and the solvent for the membrane expressed as the hydrogen-bonding contribution of the solubility parameter for the solute, solvent and membrane. A graphical map was constructed to predict the solute rejection based on the hydrogen-bonding contribution of the solubility parameter. The model was evaluated with performance data from the literature. Both the solvent flux and the solute rejection calculated with the new approach were similar to values reported in the literature. PMID:27918434

  5. Differentiating transpiration from evaporation in seasonal agricultural wetlands and the link to advective fluxes in the root zone

    USGS Publications Warehouse

    Bachand, P.A.M.; S. Bachand,; Fleck, Jacob A.; Anderson, Frank E.; Windham-Myers, Lisamarie

    2014-01-01

    The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flowrates and tracer concentrations atwetland inflows and outflows. We used two ideal reactormodel solutions, a continuous flowstirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these nonideal agricultural wetlands in which check ponds are in series. Using a fluxmodel, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment–water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemicalmechanisms affecting dissolved constituent cycling in the root zone. In addition,our understanding of internal

  6. Differentiating transpiration from evaporation in seasonal agricultural wetlands and the link to advective fluxes in the root zone.

    PubMed

    Bachand, P A M; Bachand, S; Fleck, J; Anderson, F; Windham-Myers, L

    2014-06-15

    The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flow rates and tracer concentrations at wetland inflows and outflows. We used two ideal reactor model solutions, a continuous flow stirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these non-ideal agricultural wetlands in which check ponds are in series. Using a flux model, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment-water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemical mechanisms affecting dissolved constituent cycling in the root zone. In addition, our understanding of

  7. Mechanism and Model of Laser-Driven Mass Transport in Thin Films of Azo Polymers

    DTIC Science & Technology

    2007-11-02

    and Model of Laser-Driven Mass Transport in Thin Films of Azo Polymers by C. J. Barrett, A. Natansohn, and P. Rochon Submitted for publication in...DATE June 23, 1998 Tprhnjr.fil P^nnr I’: 4. TITLE AHO SU3TITLE Mechanism and Model of Laser-Driven Mass Transport in Thin Films of Azo Polymers...TRANSPORT IN THIN FILMS OF AZO POLYMERS Christopher J. Barrett’, Almeria L. Natansohn1, and Paul L. Rochon2. ’Dept. of Chemistry. Queen’s

  8. Mass spectrometer. [On Space Transportation System 2 Flight

    NASA Technical Reports Server (NTRS)

    Miller, E. R.; Carignan, G. R.

    1983-01-01

    The quadrupole Mass Spectrometer of the Induced Environment Contamination Monitor (IECM) operates in the range from 2 to 150 amu. It is pointed out that the Mass Spectrometer on STS-2 performed very well. It was found that the column density of H2O effluent from the Shuttle reached a maximum of 1 x 10 to the 13th per sq cm at 7 hr, 30 min and decreased by a factor of 7.5 during the subsequent 40 hrs. The count rate response of H2O could be correlated with mission-related events, taking into account the dumping of supply water, the operation of the Flash Evaporator System, and the firing of a primary reaction control system engine.

  9. Mass and Momentum Transport Experiments with Swirling Flow

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Roback, R.

    1984-01-01

    An experimental study of mixing downstream of axial and swirling coaxial jets is being conducted to obtain data for the evaluation and improvement of turbulent transport models currently employed in a variety of computational procedures used throughout the propulsion community. The axial coaxial jet study was completed under Phase 1. The swirling coaxial jet study, which is the subject of this paper, was conducted under Phase 2 of the contract. A TEACH code was acquired, checked out for several test cases, and is reported. A study to measure length scales and to obtain a limited number of measurements with a blunt trailing edge inlet is being conducted under Phase 3 of the contract.

  10. An analysis of three dimensional diffusion in a representative arterial wall mass transport model.

    PubMed

    Denny, William J; O'Connell, Barry M; Milroy, John; Walsh, Michael T

    2013-05-01

    The development and use of drug eluting stents has brought about significant improvements in reducing in-stent restenosis, however, their long term presence in the artery is still under examination due to restenosis reoccurring. Current studies focus mainly on stent design, coatings and deployment techniques but few studies address the issue of the physics of three dimensional mass transport in the artery wall. There is a dearth of adequate validated numerical mass transport models that simulate the physics of diffusion dominated drug transport in the artery wall whilst under compression. A novel experimental setup used in a previous study was adapted and an expansion of that research was carried out to validate the physics of three dimensional diffusive mass transport into a compressed porous media. This study developed a more sensitive method for measuring the concentration of the species of interest. It revalidated mass transport in the radial direction and presented results which highlight the need for an evaluation of the governing equation for transient diffusive mass transport in a porous media, in its current form, to be carried out.

  11. A Global Assessment of Accelerations in Mass Transport of Surface Geophysical Fluid

    NASA Astrophysics Data System (ADS)

    Wu, X.; Heflin, M. B.

    2015-12-01

    Mass transport in the Earth's surface geophysical fluid layer has complex spatiotemporal patterns. The GRACE gravity mission provides an unprecedented global capability to monitor this important process with high accuracy and resolution. Accurate assessments of global mass transport patterns and budget also depend critically on changes in degree-1 coefficients (geocenter motion) and in Earth's dynamic oblateness coefficient J2. We combine GRACE measurements, time series of GNSS data, JPL's ECCO ocean bottom pressure model, and high-resolution loose a priori models of mass variation regimes to derive complete spherical harmonic spectra of detrended mass variations up to degree and order 180. Mass accelerations are estimated along with linear, annual, semiannual, and the 161-day tidal aliasing components from coefficient time series. The appropriateness of a priori information and estimate uncertainties are further evaluated by variance component estimation and residual statistics of fitting the time series. During the GRACE data period of 2002.2-2015.0, accelerations in mass transport are geographically uneven with significant positive or negative accelerations in various parts of the world. While Greenland and West Antarctica show strong accelerated mass losses, Alaska and the Arctic Ocean have significant positive accelerations with reversals of earlier mass loss trends. No evidence of non-Arctic global mean sea level acceleration due to mass has been found. Depending on region, some estimated accelerations are also not steady over time due to large irregular and interannual variations.

  12. Sensitivity of solute advective travel time to porosities of hydrogeologic units.

    PubMed

    Zhu, Jianting; Pohlmann, Karl F; Chapman, Jenny B; Russell, Charles E; Carroll, Rosemary W H; Shafer, David S

    2010-01-01

    An integral approach is proposed to quantify uncertainty and sensitivity of advective travel time to the effective porosities of hydrogeologic units (HGUs) along groundwater flow paths. The approach is applicable in situations where a groundwater flow model exists, but a full solute transport model is not available. The approach can be used to: (1) determine HGUs whose porosities are influential to the solute advective travel time; and (2) apportion uncertainties of solute advective travel times to the uncertainty contributions from individual HGU porosities. A simple one-dimensional steady-state flow example is used to illustrate the approach. Advective travel times of solutes are obtained based on the one-dimensional steady-state flow results in conjunction with the HGU porosities. The approach can be easily applicable to more complex multi-dimensional cases where advective solute travel time can be calculated based on simulated flow results from groundwater flow models. This approach is particularly valuable for optimizing limited resources when designing field characterization programs for uncertainty reduction by identifying HGUs that contribute most to the estimation uncertainty of advective travel times of solutes.

  13. Systematic characterization of porosity and mass transport and mechanical properties of porous polyurethane scaffolds.

    PubMed

    Wang, Yu-Fu; Barrera, Carlos M; Dauer, Edward A; Gu, Weiyong; Andreopoulos, Fotios; Huang, C-Y Charles

    2017-01-01

    One of the key challenges in porous scaffold design is to create a porous structure with desired mechanical function and mass transport properties which support delivery of biofactors and development of function tissue substitute. In recent years, polyurethane (PU) has become one of the most popular biomaterials in various tissue engineering fields. However, there are no studies fully investigating the relations between porosity and both mass transport and mechanical properties of PU porous scaffolds. In this paper, we fabricated PU scaffolds by combining phase inversion and salt (sodium chloride) leaching methods. The tensile and compressive moduli were examined on PU scaffolds fabricated with different PU concentrations (25%, 20% and 15% w/v) and salt/PU weight ratios (9/1, 6/1, 3/1 and 0/1). The mass transport properties of PU scaffolds including hydraulic permeability and glucose diffusivity were also measured. Furthermore, the relationships between the porosity and mass transport and mechanical properties of porous PU scaffold were systemically investigated. The results demonstrated that porosity is a key parameter which governs both mass transport and mechanical properties of porous PU scaffolds. With similar pore sizes, the mass transport and mechanical properties of porous PU scaffold can be described as single functions of porosity regardless of initial PU concentration. The relationships between scaffold porosity and properties can be utilized to facilitate porous PU scaffold fabrication with specific mass transport and mechanical properties. The systematic approach established in this study can be applied to characterization of other biomaterials for scaffold design and fabrication.

  14. How Hydrate Saturation Anomalies are Diffusively Constructed and Advectively Smoothed

    NASA Astrophysics Data System (ADS)

    Rempel, A. W.; Irizarry, J. T.; VanderBeek, B. P.; Handwerger, A. L.

    2015-12-01

    The physical processes that control the bulk characteristics of hydrate reservoirs are captured reasonably well by long-established model formulations that are rooted in laboratory-verified phase equilibrium parameterizations and field-based estimates of in situ conditions. More detailed assessments of hydrate distribution, especially involving the occurrence of high-saturation hydrate anomalies have been more difficult to obtain. Spatial variations in sediment properties are of central importance for modifying the phase behavior and promoting focussed fluid flow. However, quantitative predictions of hydrate anomaly development cannot be made rigorously without also addressing the changes in phase behavior and mechanical balances that accompany changes in hydrate saturation level. We demonstrate how pore-scale geometrical controls on hydrate phase stability can be parameterized for incorporation in simulations of hydrate anomaly development along dipping coarse-grained layers embedded in a more fine-grained background that is less amenable to fluid transport. Model simulations demonstrate how hydrate anomaly growth along coarse-layer boundaries is promoted by diffusive gas transport from the adjacent fine-grained matrix, while advective transport favors more distributed growth within the coarse-grained material and so effectively limits the difference between saturation peaks and background levels. Further analysis demonstrates how sediment contacts are unloaded once hydrate saturation reaches sufficient levels to form a load-bearing skeleton that can evolve to produce segregated nodules and lenses. Decomposition of such growth forms poses a significant geohazard that is expected to be particularly sensitive to perturbations induced by gas extraction. The figure illustrates the predicted evolution of hydrate saturation Sh in a coarse-grained dipping layer showing how prominent bounding hydrate anomalies (spikes) supplied by diffusive gas transport at early times

  15. Heat- and mass-transport in aqueous silica nanofluids

    NASA Astrophysics Data System (ADS)

    Turanov, A. N.; Tolmachev, Yuriy V.

    2009-10-01

    Using the transient hot wire and pulsed field gradient nuclear magnetic resonance methods we determined the thermal conductivity and the solvent self-diffusion coefficient (SDC) in aqueous suspensions of quasi-monodisperse spherical silica nanoparticles. The thermal conductivity was found to increase at higher volume fraction of nanoparticles in accordance with the effective medium theory albeit with a smaller slope. On the other hand, the SDC was found to decrease with nanoparticle volume fraction faster than predicted by the effective medium theory. These deviations can be explained by the presence of an interfacial heat-transfer resistance and water retention by the nanoparticles, respectively. We found no evidence for anomalous enhancement in the transport properties of nanofluids reported earlier by other groups.

  16. Transport in the interplanetary medium of coronal mass ejections

    NASA Astrophysics Data System (ADS)

    Borgazzi, A.; Lara, A.; Romero-Salazar, L.; Ventura, A.

    2008-07-01

    Coronal mass ejections (CMEs) are large scale structures of plasma and magnetic field expelled from the Sun to the interplanetary medium and generally observed in white light coronagraphs. During their travel, in the interplanetary medium these structures named interplanetary coronal mass ejections (ICMEs), suffer acceleration or deceleration due to the interaction with the ambient solar wind. This process can be understood as a transference of momentum between the interplanetary CME (ICME) and the solar wind. This process seems to be fundamentally different for `slow' and `fast' ICMEs (compared with the ambient solar wind velocity). In this work, we approach the problem from the fluid dynamics point of view and consider the ICMEs - solar wind system as two interacting fluids under the action of viscous forces. We note that this interaction is a special case of interaction between low density plasmas. Using these viscous forces in the Newtons Second Law, we obtained an analytical solution for the ICME velocity as a function of time. By comparing our analytic results with empirical models found in recent literature, we suggested values for the viscosity and drag parameters in this system. In this first approximation we have neglected the magnetic field.

  17. Diffusion and Advection using Cellular Potts Model

    NASA Astrophysics Data System (ADS)

    Dan, Debasis; Glazier, James

    2005-03-01

    The Cellular Potts Model (CPM) is a robust cell level methodology for simulation of biological tissues and morphogenesis. Standard diffusion solvers in the CPM use finite difference methods on the underlying CPM lattice. These methods have difficulty in simulating local advection in the ECM due to physiology and morphogenesis. To circumvent the problem of instabilities we simulate advection-diffusion within the framework of CPM using off-lattice finite-difference methods. We define a set of generalised fluid "cells" or particles which separate advection and diffusion from the lattice. Diffusion occurs between neighboring fluid cells by local averaging rules which approximate the Laplacian. CPM movement of the cells by spin flips handles the advection. The extension allows the CPM to model viscosity explicitly by including a relative velocity constraint on the fluid. The extended CPM correctly reproduces flow profiles of viscous fluids in cylindrical tube, during Stokes flow across a sphere and in flow in concentric cylindrical shells. We illustrate various conditions for diffusion including multiple instantaneous sources, continuous sources, moving sources and different boundary geometries and conditions to validate our approximation by comparing with analytical and established numerical solutions.

  18. 3D Flow Visualization Using Texture Advection

    NASA Technical Reports Server (NTRS)

    Kao, David; Zhang, Bing; Kim, Kwansik; Pang, Alex; Moran, Pat (Technical Monitor)

    2001-01-01

    Texture advection is an effective tool for animating and investigating 2D flows. In this paper, we discuss how this technique can be extended to 3D flows. In particular, we examine the use of 3D and 4D textures on 3D synthetic and computational fluid dynamics flow fields.

  19. Modification of the finite element heat and mass transfer code (FEHMN) to model multicomponent reactive transport

    SciTech Connect

    Viswanathan, H.S.

    1995-12-31

    The finite element code FEHMN is a three-dimensional finite element heat and mass transport simulator that can handle complex stratigraphy and nonlinear processes such as vadose zone flow, heat flow and solute transport. Scientists at LANL have been developed hydrologic flow and transport models of the Yucca Mountain site using FEHMN. Previous FEHMN simulations have used an equivalent K{sub d} model to model solute transport. In this thesis, FEHMN is modified making it possible to simulate the transport of a species with a rigorous chemical model. Including the rigorous chemical equations into FEHMN simulations should provide for more representative transport models for highly reactive chemical species. A fully kinetic formulation is chosen for the FEHMN reactive transport model. Several methods are available to computationally implement a fully kinetic formulation. Different numerical algorithms are investigated in order to optimize computational efficiency and memory requirements of the reactive transport model. The best algorithm of those investigated is then incorporated into FEHMN. The algorithm chosen requires for the user to place strongly coupled species into groups which are then solved for simultaneously using FEHMN. The complete reactive transport model is verified over a wide variety of problems and is shown to be working properly. The simulations demonstrate that gas flow and carbonate chemistry can significantly affect {sup 14}C transport at Yucca Mountain. The simulations also provide that the new capabilities of FEHMN can be used to refine and buttress already existing Yucca Mountain radionuclide transport studies.

  20. A novel method for analytically solving a radial advection-dispersion equation

    NASA Astrophysics Data System (ADS)

    Lai, Keng-Hsin; Liu, Chen-Wuing; Liang, Ching-Ping; Chen, Jui-Sheng; Sie, Bing-Ruei

    2016-11-01

    An analytical solution for solute transport in a radial flow field has a variety of practical applications in the study of the transport in push-pull/divergent/convergent flow tracer tests, aquifer remediation by pumping and aquifer storage and recovery. However, an analytical solution for radial advective-dispersive transport has been proven very difficult to develop and relatively few in subsurface hydrology have made efforts to do so, because variable coefficients in the governing partial differential equations. Most of the solutions for radial advective-dispersive transport presented in the literature have generally been solved semi-analytically with the final concentration values being obtained with the help of a numerical Laplace inversion. This study presents a novel solution strategy for analytically solving the radial advective-dispersive transport problem. A Laplace transform with respect to the time variable and a generalized integral transform technique with respect to the spatial variable are first performed to convert the transient governing partial differential equations into an algebraic equation. Subsequently, the algebraic equation is solved using simple algebraic manipulations, easily yielding the solution in the transformed domain. The solution in the original domain is ultimately obtained by successive applications of the Laplace and corresponding generalized integral transform inversions. A convergent flow tracer test is used to demonstrate the robustness of the proposed method for deriving an exact analytical solution to the radial advective-dispersive transport problem. The developed analytical solution is verified against a semi-analytical solution taken from the literature. The results show perfect agreement between our exact analytical solution and the semi-analytical solution. The solution method presented in this study can be applied to create more comprehensive analytical models for a great variety of radial advective

  1. Mass Balance Implications of Wind-Transported Snow Loss From Antarctic Ice Shelves

    NASA Astrophysics Data System (ADS)

    Leonard, K. C.; Jacobs, S. S.; Cullather, R. I.

    2008-12-01

    Some fraction of the snow that falls as precipitation over the Antarctic ice sheet is transported across the coastline by the wind. This is a long-recognized but poorly constrained problem. If recent projections of increasing coastal wind speeds are correct, wind-blown snow transport will also intensify, as the relationship between mass transport and wind speed is strongly nonlinear. The large-scale importance of wind- transported snow to coastal ocean freshening or ice sheet mass balance depends on unknowns including details of the transport of snow by the wind, the net precipitation over Antarctica, and the effective length of its coastline. Prior estimates of snow loss into the ocean from Antarctica range over two orders of magnitude, from less than 2 to more than 200 Gt / year. Modeled annual snow transport based on measured winds at an automatic weather station site on the northern edge of the Ross Ice Shelf is in good agreement with measured values from Halley Station. When extrapolated around the coastline, these values fall between the reported extremes. Because most of Antarctica's coastal areas experience higher winds and greater snow supply than its ice shelves, this data provides a lower limit on the mass of snow removed from the ice sheet by the wind. From this lower bound we estimate the probable range of values for present-day wind blown snow export to the Southern Ocean, and explore the implications of projected rising winds for increases in wind-blown snow transport.

  2. Intraparticle mass transport mechanism in activated carbon adsorption of phenols

    SciTech Connect

    Furuya, E.G.; Miura, Y.; Yokomura, H.; Tajima, S.; Yamashita, S.; Chang, H.T.; Noll, K.E.

    1996-10-01

    Two parallel diffusion mechanisms, pore and surface, can control the rate of contaminant adsorption. The two mechanisms are different functions of temperature and adsorbate concentration. To develop a mechanistic design model for adsorption processes, the two mechanisms must be evaluated separately. In this paper, the authors show that the mechanisms can be separated accurately using a stepwise linearization technique. The technique can easily be incorporated in adsorption diffusion modeling. Two phenolic compounds were used in this study: p-chlorophenol (PCP) and p-nitrophenol (PNP). The application of the linearization technique is illustrated using two types of reactors: a completely mixed batch reactor and a differential reactor. The study results show that pore and surface diffusivity can be determined accurately using the linearization technique. Furthermore, the tortuosity for the absorbent can be estimated from the pore diffusivity. For PCP that is strongly adsorbed by the adsorbent, surface diffusion is the dominant mechanism controlling the intraparticle transport. For weakly adsorbed PNP, neither surface nor pore diffusion is dominant.

  3. Temporal variability of mass transport across Canary Islands Channels

    NASA Astrophysics Data System (ADS)

    Marrero-Díaz, Ángeles; Rodríguez-Santana, Ángel; José Machín, Francisco; García-Weil, Luis; Sangrà, Pablo; Vélez-Belchí, Pedro; Fraile-Nuez, Eugenio

    2014-05-01

    The equatorward flowing Canary Current (CC) is the main feature of the circulation in the Canary Islands region. The CC flow perturbation by the Canary Islands originate the Canary Eddy Corridor which is the major pathway for long lived eddies in the subtropical North Atlantic (Sangrà et al., 2009, DSR). Therefore the variability of the CC passing through the Canary Archipelago will have both local and regional importance. Past studies on the CC variability trough the Canary Islands point out a clearly seasonal variability (Fraile-Nuez et al, 2010 (JGR); Hernández-Guerra et al, 2002 (DSR)). However those studies where focused on the eastern islands channels missing the variability through the western island channels which are the main source of long lived eddies. In order to fill this gap from November 2012 until September 2013 we conducted trimonthly surveys crossing the whole islands channels using opportunity ships (Naviera Armas Ferries). XBT and XCTD where launched along the cross channels transects. Additionally a closed box circling the Archipelago was performed on October 2013 as part of the cruise RAPROCAN-2013 (IEO) using also XBT and XCTD. Dynamical variables where derived inferring salinity from S(T,p) analytical relationships for the region updated with new XCTD data. High resolution, vertical sections of temperature, potential density, geostrophic velocity and transport where obtained. Our preliminary results suggest that the CC suffer a noticeable acceleration in those islands channels where eddy shedding is more frequent. They also indicate a clearly seasonal variability of the flows passing the islands channels. With this regard we observed significant differences on the obtained seasonal variability with respect the cited past studies on the eastern islands channel (Lanzarote / Fuerteventura - Africa coast). This work was co-funded by Canary Government (TRAMIC project: PROID20100092) and the European Union (FEDER).

  4. Fram Strait and Greenland Sea transports, water masses, and water mass transformations 1999-2010 (and beyond)

    NASA Astrophysics Data System (ADS)

    Marnela, Marika; Rudels, Bert; Goszczko, Ilona; Beszczynska-Möller, Agnieszka; Schauer, Ursula

    2016-04-01

    The exchanges between the Nordic Seas and the Arctic Ocean are important for the ocean circulation and climate. Transports are here estimated using summer hydrographic data from the Greenland Sea and the Fram Strait. Geostrophic transports are computed from hydrographic sections at 75°N in the Greenland Sea and at about 79°N in the Fram Strait. Geostrophic velocities are adjusted with summer velocities derived from Argo floats, and four conservation constraints are applied to a box closed by the two sections. The estimated net volume transports are 0.8 ± 1.5 Sv southward. Net freshwater transports through the Greenland Sea section are estimated at 54 ± 20 mSv and through the Fram Strait section at 66 ± 9 mSv. Heat loss in the area between the two sections is estimated at 9 ± 12 TW. Convection depths in the Greenland Sea are estimated from observations and vary between about 200 and 2000 dbar showing no trend. Water mass properties in the Greenland Sea are affected both by convection and lateral mixing. Vertical mixing is estimated from hydrography and based on it about 1 Sv of diluted Arctic Ocean waters are estimated to enter the Greenland Sea. The properties of Atlantic, intermediate, and deep waters are studied. Deep water properties are defined using water mass triangles and are subject to decadal changes.

  5. Single-Molecule Investigations of Morphology and Mass Transport Dynamics in Nanostructured Materials

    NASA Astrophysics Data System (ADS)

    Higgins, Daniel A.; Park, Seok Chan; Tran-Ba, Khanh-Hoa; Ito, Takashi

    2015-07-01

    Nanostructured materials such as mesoporous metal oxides and phase-separated block copolymers form the basis for new monolith, membrane, and thin film technologies having applications in energy storage, chemical catalysis, and separations. Mass transport plays an integral role in governing the application-specific performance characteristics of many such materials. The majority of methods employed in their characterization provide only ensemble data, often masking the nanoscale, molecular-level details of materials morphology and mass transport. Single-molecule fluorescence methods offer direct routes to probing these characteristics on a single-molecule/single-nanostructure basis. This article provides a review of single-molecule studies focused on measurements of anisotropic diffusion, adsorption, partitioning, and confinement in nanostructured materials. Experimental methods covered include confocal and wide-field fluorescence microscopy. The results obtained promise to deepen our understanding of mass transport mechanisms in nanostructures, thus aiding in the realization of advanced materials systems.

  6. Mass transport in a thin layer of power-law mud under surface waves

    NASA Astrophysics Data System (ADS)

    Liu, Jie; Bai, Yuchuan; Xu, Dong

    2017-02-01

    The mass transport velocity in a two-layer system is studied theoretically. The wave motion is driven by a periodic pressure load on the free water surface, and mud in the lower layer is described by a power-law rheological model. Perturbation analysis is performed to the second order to find the mean Eulerian velocity. A numerical iteration method is employed to solve the non-linear governing equation at the leading order. The influence of rheological properties on fluid motion characteristics including the flow field, the surface displacement, the mass transport velocity, and the net discharge rates are investigated based on theoretical results. Theoretical analysis shows that under the action of interfacial shearing, a recirculation structure may appear near the interface in the upper water layer. A higher mass transport velocity at the interface does not necessarily mean a higher discharge rate for a pseudo-plastic fluid mud.

  7. Single-Molecule Investigations of Morphology and Mass Transport Dynamics in Nanostructured Materials.

    PubMed

    Higgins, Daniel A; Park, Seok Chan; Tran-Ba, Khanh-Hoa; Ito, Takashi

    2015-01-01

    Nanostructured materials such as mesoporous metal oxides and phase-separated block copolymers form the basis for new monolith, membrane, and thin film technologies having applications in energy storage, chemical catalysis, and separations. Mass transport plays an integral role in governing the application-specific performance characteristics of many such materials. The majority of methods employed in their characterization provide only ensemble data, often masking the nanoscale, molecular-level details of materials morphology and mass transport. Single-molecule fluorescence methods offer direct routes to probing these characteristics on a single-molecule/single-nanostructure basis. This article provides a review of single-molecule studies focused on measurements of anisotropic diffusion, adsorption, partitioning, and confinement in nanostructured materials. Experimental methods covered include confocal and wide-field fluorescence microscopy. The results obtained promise to deepen our understanding of mass transport mechanisms in nanostructures, thus aiding in the realization of advanced materials systems.

  8. Bubble-Facilitated VOC Transport from LNAPL Smear Zones and Its Potential Effect on Vapor Intrusion.

    PubMed

    Soucy, Nicole C; Mumford, Kevin G

    2017-02-10

    Most conceptual and mathematical models of soil vapor intrusion assume that the transport of volatile organic compounds (VOCs) from a source toward a building is limited by diffusion through the soil gas. Under conditions where advection occurs, transport rates are higher and can lead to higher indoor air concentrations. Advection-dominated conditions can be created by gas bubble flow in the saturated zone. A series of laboratory column experiments were conducted to measure mass flux due to bubble-facilitated VOC transport from light nonaqueous phase liquid (LNAPL) smear zones. Smear zones that contained both LNAPL residual and trapped gas, as well as those that contained only LNAPL residual, were investigated. Results showed that the VOC mass flux due to bubble-facilitated transport was orders-of-magnitude higher than under diffusion-limited conditions. Results also showed that the mass flux due to bubble-facilitated transport was intermittent, and increased with an increased supply of dissolved gases.

  9. Pore Water PAH Transport in Amended Sediment Caps

    NASA Astrophysics Data System (ADS)

    Gidley, P. T.; Kwon, S.; Ghosh, U.

    2009-05-01

    Capping is a common remediation strategy for contaminated sediments that creates a physical barrier between contaminated sediments and the water column. Diffusive flux of contaminants through a sediment cap is small. However, under certain hydrodynamic conditions such as groundwater potential and tidal pumping, groundwater advection can accelerate contaminant transport. Hydrophobic organic contaminants such as polycyclic aromatic hydrocarbons (PAHs) could be transported through the cap under advective conditions. To better understand PAH migration under these conditions, physical models of sediment caps were evaluated in the laboratory through direct measurement of pore water using solid phase micro-extraction with gas chromatography and mass spectrometry. Contaminated sediment and capping material was obtained from an existing Superfund site that was capped at Eagle Harbor, Washington. A PAH dissolution model linked to an advection-dispersion equation with retardation using published organic carbon-water partitioning coefficients (Koc) was compared to measured PAHs in the sediment and cap porewater of the physical model.

  10. Intra-tumoral heterogeneity of gemcitabine delivery and mass transport in human pancreatic cancer

    NASA Astrophysics Data System (ADS)

    Koay, Eugene J.; Baio, Flavio E.; Ondari, Alexander; Truty, Mark J.; Cristini, Vittorio; Thomas, Ryan M.; Chen, Rong; Chatterjee, Deyali; Kang, Ya'an; Zhang, Joy; Court, Laurence; Bhosale, Priya R.; Tamm, Eric P.; Qayyum, Aliya; Crane, Christopher H.; Javle, Milind; Katz, Matthew H.; Gottumukkala, Vijaya N.; Rozner, Marc A.; Shen, Haifa; Lee, Jeffrey E.; Wang, Huamin; Chen, Yuling; Plunkett, William; Abbruzzese, James L.; Wolff, Robert A.; Maitra, Anirban; Ferrari, Mauro; Varadhachary, Gauri R.; Fleming, Jason B.

    2014-12-01

    There is substantial heterogeneity in the clinical behavior of pancreatic cancer and in its response to therapy. Some of this variation may be due to differences in delivery of cytotoxic therapies between patients and within individual tumors. Indeed, in 12 patients with resectable pancreatic cancer, we previously demonstrated wide inter-patient variability in the delivery of gemcitabine as well as in the mass transport properties of tumors as measured by computed tomography (CT) scans. However, the variability of drug delivery and transport properties within pancreatic tumors is currently unknown. Here, we analyzed regional measurements of gemcitabine DNA incorporation in the tumors of the same 12 patients to understand the degree of intra-tumoral heterogeneity of drug delivery. We also developed a volumetric segmentation approach to measure mass transport properties from the CT scans of these patients and tested inter-observer agreement with this new methodology. Our results demonstrate significant heterogeneity of gemcitabine delivery within individual pancreatic tumors and across the patient cohort, with gemcitabine DNA incorporation in the inner portion of the tumors ranging from 38 to 74% of the total. Similarly, the CT-derived mass transport properties of the tumors had a high degree of heterogeneity, ranging from minimal difference to almost 200% difference between inner and outer portions of the tumor. Our quantitative method to derive transport properties from CT scans demonstrated less than 5% difference in gemcitabine prediction at the average CT-derived transport value across observers. These data illustrate significant inter-patient and intra-tumoral heterogeneity in the delivery of gemcitabine, and highlight how this variability can be reproducibly accounted for using principles of mass transport. With further validation as a biophysical marker, transport properties of tumors may be useful in patient selection for therapy and prediction of

  11. DEVELOPMENT AND DEMONSTRATION OF A BIDIRECTIONAL ADVECTIVE FLUX METER FOR SEDIMENT-WATER INTERFACE

    EPA Science Inventory

    A bidirectional advective flux meter for measuring water transport across the sediment-water interface has been successfully developed and field tested. The flow sensor employs a heat-pulse technique combined with a flow collection funnel for the flow measurement. Because the dir...

  12. Mass and momentum turbulent transport experiments with confined swirling coaxial jets

    NASA Technical Reports Server (NTRS)

    Roback, R.; Johnson, B. V.

    1983-01-01

    Swirling coaxial jets mixing downstream, discharging into an expanded duct was conducted to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the combustion community. A combination of laser velocimeter (LV) and laser induced fluorescence (LIF) techniques was employed to obtain mean and fluctuating velocity and concentration distributions which were used to derive mass and momentum turbulent transport parameters currently incorporated into various combustor flow models. Flow visualization techniques were also employed to determine qualitatively the time dependent characteristics of the flow and the scale of turbulence. The results of these measurements indicated that the largest momentum turbulent transport was in the r-z plane. Peak momentum turbulent transport rates were approximately the same as those for the nonswirling flow condition. The mass turbulent transport process for swirling flow was complicated. Mixing occurred in several steps of axial and radial mass transport and was coupled with a large radial mean convective flux. Mixing for swirling flow was completed in one-third the length required for nonswirling flow.

  13. Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

    1986-01-01

    To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

  14. Tomography-based characterization of ice-air interface dynamics of temperature gradient snow metamorphism under advective conditions

    NASA Astrophysics Data System (ADS)

    Ebner, Pirmin Philipp; Andreoli, Christian; Schneebeli, Martin; Steinfeld, Aldo

    2015-12-01

    Snow at or close to the surface commonly undergoes temperature gradient metamorphism under advective flow, which alters its microstructure and physical properties. A functional understanding of this process is essential for many disciplines, from modeling the effects of snow on regional and global climate to assessing avalanche formation. Time-lapse X-ray microtomography was applied to investigate the structural dynamics of temperature gradient snow metamorphism exposed to an advective airflow in controlled laboratory conditions. Experiments specifically analyzed sublimation and deposition of water vapor on the ice structure. In addition, an analysis of the ice-air interface dynamics was carried out using a macroscopic equivalent model of heat and water vapor transport through a snow layer. The results indicate that sublimation of the ice matrix dominated for flow rates < 10-6 m3 s-1 while during increased mass flow rates the water vapor deposition supplied by the advective flow counteracted sublimation. A flow rate dependence of water vapor deposition at the ice interface was observed, asymptotically approaching an average estimated maximum deposition rate on the whole sample of 1.05 · 10-4 kg m-3 s-1. The growth of microsized whisker-like crystals on larger ice crystals was detected on microscope photographs, leading to an increase of the specific surface area and thus suggest a change of the physical and optical properties of the snow. The estimated values of the curvature effect of the ice crystals and the interface kinetic coefficient are in good agreement with previously published values.

  15. Heat advection processes leading to El Niño events as depicted by an ensemble of ocean assimilation products

    NASA Astrophysics Data System (ADS)

    Ballester, Joan; Bordoni, Simona; Petrova, Desislava; Rodó, Xavier

    2016-06-01

    The oscillatory nature of El Niño-Southern Oscillation results from an intricate superposition of near-equilibrium balances and out-of-phase disequilibrium processes between the ocean and the atmosphere. The main objective of the present work is to perform an exhaustive spatiotemporal analysis of the upper ocean heat budget in an ensemble of state-of-the-art ocean assimilation products. We put specific emphasis on the ocean heat advection mechanisms, and their representation in individual ensemble members and in the different stages of the ENSO oscillation leading to EN events. Our analyses consistently show that the initial subsurface warming in the western equatorial Pacific is advected to the central Pacific by the equatorial undercurrent, which, together with the equatorward advection associated with anomalies in both the meridional temperature gradient and circulation at the level of the thermocline, explains the heat buildup in the central Pacific during the recharge phase. We also find that the recharge phase is characterized by an increase of meridional tilting of the thermocline, as well as a southward upper-ocean cross-equatorial mass transport resulting from Ekman-induced anomalous vertical motion in the off-equatorial regions. Although differences between data sets are generally small, and anomalies tend to have the same sign, the differences in the magnitude of the meridional term are seen to be key for explaining the different propagation speed of the subsurface warming tendency along the thermocline. The only exception is GECCO, which does not produce the patterns of meridional surface Ekman divergence (subsurface Sverdrup convergence) in the western and central equatorial Pacific.

  16. Mass transport properties of Pu/DT mixtures from orbital free molecular dynamics simulations

    SciTech Connect

    Kress, Joel David; Ticknor, Christopher; Collins, Lee A.

    2015-09-16

    Mass transport properties (shear viscosity and diffusion coefficients) for Pu/DT mixtures were calculated with Orbital Free Molecular Dynamics (OFMD). The results were fitted to simple functions of mass density (for ρ=10.4 to 62.4 g/cm3) and temperature (for T=100 up to 3,000 eV) for Pu/DT mixtures consisting of 100/0, 25/75, 50/50, and 75/25 by number.

  17. Distributed Parallel Particle Advection using Work Requesting

    SciTech Connect

    Muller, Cornelius; Camp, David; Hentschel, Bernd; Garth, Christoph

    2013-09-30

    Particle advection is an important vector field visualization technique that is difficult to apply to very large data sets in a distributed setting due to scalability limitations in existing algorithms. In this paper, we report on several experiments using work requesting dynamic scheduling which achieves balanced work distribution on arbitrary problems with minimal communication overhead. We present a corresponding prototype implementation, provide and analyze benchmark results, and compare our results to an existing algorithm.

  18. Space-fractional advection-diffusion and reflective boundary condition.

    PubMed

    Krepysheva, Natalia; Di Pietro, Liliana; Néel, Marie-Christine

    2006-02-01

    Anomalous diffusive transport arises in a large diversity of disordered media. Stochastic formulations in terms of continuous time random walks (CTRWs) with transition probability densities showing space- and/or time-diverging moments were developed to account for anomalous behaviors. A broad class of CTRWs was shown to correspond, on the macroscopic scale, to advection-diffusion equations involving derivatives of noninteger order. In particular, CTRWs with Lévy distribution of jumps and finite mean waiting time lead to a space-fractional equation that accounts for superdiffusion and involves a nonlocal integral-differential operator. Within this framework, we analyze the evolution of particles performing symmetric Lévy flights with respect to a fluid moving at uniform speed . The particles are restricted to a semi-infinite domain limited by a reflective barrier. We show that the introduction of the boundary condition induces a modification in the kernel of the nonlocal operator. Thus, the macroscopic space-fractional advection-diffusion equation obtained is different from that in an infinite medium.

  19. Effects of functional group mass variance on vibrational properties and thermal transport in graphene

    NASA Astrophysics Data System (ADS)

    Lindsay, L.; Kuang, Y.

    2017-03-01

    Intrinsic thermal resistivity critically depends on features of phonon dispersions dictated by harmonic interatomic forces and masses. Here we present the effects of functional group mass variance on vibrational properties and thermal conductivity (κ ) of functionalized graphene from first-principles calculations. We use graphane, a buckled graphene backbone with covalently bonded hydrogen atoms on both sides, as the base material and vary the mass of the hydrogen atoms to simulate the effect of mass variance from other functional groups. We find nonmonotonic behavior of κ with increasing mass of the functional group and an unusual crossover from acoustic-dominated to optic-dominated thermal transport behavior. We connect this crossover to changes in the phonon dispersion with varying mass which suppress acoustic phonon velocities, but also give unusually high velocity optic modes. Further, we show that out-of-plane acoustic vibrations contribute significantly more to thermal transport than in-plane acoustic modes despite breaking of a reflection-symmetry-based scattering selection rule responsible for their large contributions in graphene. This work demonstrates the potential for manipulation and engineering of thermal transport properties in two-dimensional materials toward targeted applications.

  20. Effects of functional group mass variance on vibrational properties and thermal transport in graphene

    DOE PAGES

    Lindsay, L.; Kuang, Y.

    2017-03-13

    Intrinsic thermal resistivity critically depends on features of phonon dispersions dictated by harmonic interatomic forces and masses. We present the effects of functional group mass variance on vibrational properties and thermal conductivity (κ ) of functionalized graphene from first principles calculations. We also use graphane, a buckled graphene backbone with covalently bonded Hydrogen atoms on both sides, as the base material and vary the mass of the Hydrogen atoms to simulate the effect of mass variance from other functional groups. We find non-monotonic behavior of κ with increasing mass of the functional group and an unusual cross-over from acoustic-dominated tomore » optic-dominated thermal transport behavior. We connect this cross-over to changes in the phonon dispersion with varying mass which suppress acoustic phonon velocities, but also give unusually high velocity optic modes. Further, we show that out-of-plane acoustic vibrations contribute significantly more to thermal transport than in-plane acoustic modes despite breaking of a reflection symmetry based scattering selection rule responsible for their large contributions in graphene. Our work demonstrates the potential for manipulation and engineering of thermal transport properties in two dimensional materials toward targeted applications.« less

  1. High Order Semi-Lagrangian Advection Scheme

    NASA Astrophysics Data System (ADS)

    Malaga, Carlos; Mandujano, Francisco; Becerra, Julian

    2014-11-01

    In most fluid phenomena, advection plays an important roll. A numerical scheme capable of making quantitative predictions and simulations must compute correctly the advection terms appearing in the equations governing fluid flow. Here we present a high order forward semi-Lagrangian numerical scheme specifically tailored to compute material derivatives. The scheme relies on the geometrical interpretation of material derivatives to compute the time evolution of fields on grids that deform with the material fluid domain, an interpolating procedure of arbitrary order that preserves the moments of the interpolated distributions, and a nonlinear mapping strategy to perform interpolations between undeformed and deformed grids. Additionally, a discontinuity criterion was implemented to deal with discontinuous fields and shocks. Tests of pure advection, shock formation and nonlinear phenomena are presented to show performance and convergence of the scheme. The high computational cost is considerably reduced when implemented on massively parallel architectures found in graphic cards. The authors acknowledge funding from Fondo Sectorial CONACYT-SENER Grant Number 42536 (DGAJ-SPI-34-170412-217).

  2. High-Schmidt-number mass transport mechanisms from a turbulent flow to absorbing sediments

    NASA Astrophysics Data System (ADS)

    Scalo, Carlo; Piomelli, Ugo; Boegman, Leon

    2012-08-01

    We have investigated the mechanisms involved in dissolved oxygen (DO) transfer from a turbulent flow to an underlying organic sediment bed populated with DO-absorbing bacteria. Our numerical study relies on a previously developed and tested computational tool that couples a bio-geochemical model for the sediment layer and large-eddy simulation for transport on the water side. Simulations have been carried out in an open channel configuration for different Reynolds numbers (Reτ = 180-1000), Schmidt numbers (Sc = 400-1000), and bacterial populations (χ* = 100-700 mg l-1). We show that the average oxygen flux across the sediment-water interface (SWI) changes with Reτ and Sc, in good agreement with classic heat-and-mass-transfer parametrizations. Time correlations at the SWI show that intermittent peaks in the wall-shear stress initiate the mass transfer and modulate its distribution in space and time. The diffusive sublayer acts as a de-noising filter with respect to the overlying turbulence; the instantaneous mass flux is not affected by low-amplitude background fluctuations in the wall-shear stress but, on the other hand, it is receptive to energetic and coherent near-wall transport events, in agreement with the surface renewal theory. The three transport processes involved in DO depletion (turbulent transport, molecular transport across the diffusive sublayer, and absorption in the organic sediment layer) exhibit distinct temporal and spatial scales. The rapidly evolving near-wall high-speed streaks transport patches of fluid to the edge of the diffusive sublayer, leaving slowly regenerating elongated patches of positive DO concentration fluctuations and mass flux at the SWI. The sediment surface retains the signature of the overlying turbulent transport over long time scales, allowed by the slow bacterial absorption.

  3. Analytical solution of advection-diffusion equation in heterogeneous infinite medium using Green's function method

    NASA Astrophysics Data System (ADS)

    Sanskrityayn, Abhishek; Kumar, Naveen

    2016-12-01

    Some analytical solutions of one-dimensional advection-diffusion equation (ADE) with variable dispersion coefficient and velocity are obtained using Green's function method (GFM). The variability attributes to the heterogeneity of hydro-geological media like river bed or aquifer in more general ways than that in the previous works. Dispersion coefficient is considered temporally dependent, while velocity is considered spatially and temporally dependent. The spatial dependence is considered to be linear and temporal dependence is considered to be of linear, exponential and asymptotic. The spatio-temporal dependence of velocity is considered in three ways. Results of previous works are also derived validating the results of the present work. To use GFM, a moving coordinate transformation is developed through which this ADE is reduced into a form, whose analytical solution is already known. Analytical solutions are obtained for the pollutant's mass dispersion from an instantaneous point source as well as from a continuous point source in a heterogeneous medium. The effect of such dependence on the mass transport is explained through the illustrations of the analytical solutions.

  4. The 8th-10 th January 2009 snowfalls: a case of Mediterranean warm advection event

    NASA Astrophysics Data System (ADS)

    Aguado, F.; Ayensa, E.; Barriga, M.; Del Hoyo, J.; Fernández, A.; Garrido, N.; Martín, A.; Martín, F.; Roa, I. Martínez, A.; Pascual, R.

    2009-09-01

    From 8 th to 10 th of January 2009, significant snowfalls were reported in many areas of the Iberian Peninsula and the Balearic Islands. This relevant event was very important from the meteorological and social impact point of views. The snow affected many zones, especially the regions of Madrid, Castilla & León and Castilla-La Mancha (Spanish central plateau) with the persistence and thickness of solid precipitation. Up to twenty-five centimetres of snow were reported in some places. On 9th of January the snowfalls caused great social and media impact due to the fact that they took place in the early hours in the Madrid metropolitan areas, affecting both air traffic and land transport. The "Madrid-Barajas" airport was closed and the city was collapsed during several hours. A study of this situation appears in the poster. The snowstorm was characterized by the previous irruption of an European continental polar air mass, that subsequently interacted with a wet and warm air mass of Mediterranean origin, all preceded by low level easterly flows. This type of snowfall is called "warm advection". These winter situations are very efficient from precipitation point of view, generating significant snowfalls and affecting a lot of areas.

  5. Peroxy radicals and ozone photochemistry in air masses undergoing long-range transport

    NASA Astrophysics Data System (ADS)

    Parker, A. E.; Monks, P. S.; Jacob, M. J.; Penkett, S. A.; Lewis, A. C.; Stewart, D. J.; Whalley, L. K.; Methven, J.; Stohl, A.

    2009-09-01

    Concentrations of peroxy radicals (HO2+ΣiRiO2) in addition to other trace gases were measured onboard the UK Meteorological Office/Natural Environment Research Council British Aerospace 146-300 atmospheric research aircraft during the Intercontinental Transport of Ozone and Precursors (ITOP) campaign based at Horta Airport, Faial, Azores (38.58° N, 28.72° W) in July/August 2004. The overall peroxy radical altitude profile displays an increase with altitude that is likely to have been impacted by the effects of long-range transport. The peroxy radical altitude profile for air classified as of marine origin shows no discernable altitude profile. A range of air-masses were intercepted with varying source signatures, including those with aged American and Asian signatures, air-masses of biomass burning origin, and those that originated from the east coast of the United States. Enhanced peroxy radical concentrations have been observed within this range of air-masses indicating that long-range transported air-masses traversing the Atlantic show significant photochemical activity. The net ozone production at clear sky limit is in general negative, and as such the summer mid-Atlantic troposphere is at limit net ozone destructive. However, there is clear evidence of positive ozone production even at clear sky limit within air masses undergoing long-range transport, and during ITOP especially between 5 and 5.5 km, which in the main corresponds to a flight that extensively sampled air with a biomass burning signature. Ozone production was NOx limited throughout ITOP, as evidenced by a good correlation (r2=0.72) between P(O3) and NO. Strong positive net ozone production has also been seen in varying source signature air-masses undergoing long-range transport, including but not limited to low-level export events, and export from the east coast of the United States.

  6. Conceptual model for transport processes in the Culebra Dolomite Member, Rustler Formation

    SciTech Connect

    Holt, R.M.

    1997-08-01

    The Culebra Dolomite Member of the Rustler Formation represents a possible pathway for contaminants from the Waste Isolation Pilot Plant underground repository to the accessible environment. The geologic character of the Culebra is consistent with a double-porosity, multiple-rate model for transport in which the medium is conceptualized as consisting of advective porosity, where solutes are carried by the groundwater flow, and fracture-bounded zones of diffusive porosity, where solutes move through slow advection or diffusion. As the advective travel length or travel time increases, the nature of transport within a double-porosity medium changes. This behavior is important for chemical sorption, because the specific surface area per unit mass of the diffusive porosity is much greater than in the advective porosity. Culebra transport experiments conducted at two different length scales show behavior consistent with a multiple-rate, double-porosity conceptual model for Culebra transport. Tracer tests conducted on intact core samples from the Culebra show no evidence of significant diffusion, suggesting that at the core scale the Culebra can be modeled as a single-porosity medium where only the advective porosity participates in transport. Field tracer tests conducted in the Culebra show strong double-porosity behavior that is best explained using a multiple-rate model.

  7. Modification of the finite element heat and mass transfer code (FEHM) to model multicomponent reactive transport

    SciTech Connect

    Viswanathan, H.S.

    1996-08-01

    The finite element code FEHMN, developed by scientists at Los Alamos National Laboratory (LANL), is a three-dimensional finite element heat and mass transport simulator that can handle complex stratigraphy and nonlinear processes such as vadose zone flow, heat flow and solute transport. Scientists at LANL have been developing hydrologic flow and transport models of the Yucca Mountain site using FEHMN. Previous FEHMN simulations have used an equivalent Kd model to model solute transport. In this thesis, FEHMN is modified making it possible to simulate the transport of a species with a rigorous chemical model. Including the rigorous chemical equations into FEHMN simulations should provide for more representative transport models for highly reactive chemical species. A fully kinetic formulation is chosen for the FEHMN reactive transport model. Several methods are available to computationally implement a fully kinetic formulation. Different numerical algorithms are investigated in order to optimize computational efficiency and memory requirements of the reactive transport model. The best algorithm of those investigated is then incorporated into FEHMN. The algorithm chosen requires for the user to place strongly coupled species into groups which are then solved for simultaneously using FEHMN. The complete reactive transport model is verified over a wide variety of problems and is shown to be working properly. The new chemical capabilities of FEHMN are illustrated by using Los Alamos National Laboratory`s site scale model of Yucca Mountain to model two-dimensional, vadose zone {sup 14}C transport. The simulations demonstrate that gas flow and carbonate chemistry can significantly affect {sup 14}C transport at Yucca Mountain. The simulations also prove that the new capabilities of FEHMN can be used to refine and buttress already existing Yucca Mountain radionuclide transport studies.

  8. Mass and heat transport in the two-phase Buckley-Leverett model

    NASA Astrophysics Data System (ADS)

    Akhmetzyanov, Atlas V.; Kushner, Alexei G.; Lychagin, Valentin V.

    2017-03-01

    In this article we study the initial boundary value problem for two-phase heat and mass transport in porous media described by the Buckley-Leverett model. We outline a method to construct asymptotic solutions of the initial boundary problem and show how to overcome singularities in solutions and shock waves.

  9. Measurements of Combined Axial Mass and Heat Transport in He II.

    ERIC Educational Resources Information Center

    Johnson, Warren W.; Jones, Michael C.

    An experiment was performed that allowed measurements of both axial mass and heat transport of He-II (the superfluid phase of helium 4) in a long tube. The apparatus allowed the pressure difference and the temperature difference across the flow tube to each be independently adjusted, and the resulting steady-state values of net fluid velocity and…

  10. Mean Flow Velocities and Mass Transport for Equatorially-Trapped Water Waves with an Underlying Current

    NASA Astrophysics Data System (ADS)

    Henry, David; Sastre-Gomez, Silvia

    2016-12-01

    In this paper we present an analysis of the mean flow velocities, and related mass transport, which are induced by certain equatorially-trapped water waves. In particular, we examine a recently-derived exact and explicit solution to the geophysical governing equations in the {β}-plane approximation at the equator which incorporates a constant underlying current.

  11. Volumetric vs Mass Velocity in Analyzing Convective-Diffusive Transport Processes in Liquids

    NASA Astrophysics Data System (ADS)

    Brenner, Howard

    2000-11-01

    Because mass rather than volume is preserved in fluid-mechanical problems involving density changes, a natural predilection exists for quantifying convective-diffusive transport phenomena in terms of a velocity field based upon mass, rather than volume. Indeed, in the classic BSL "Transport Phenomena" textbook, but a single reference exists even to the very concept of a volume velocity, and even then it is relegated to a homework assignment. However, especially when dealing with transport in fluids in which the mass density of the conserved property being transported (e.g., chemical species, internal energy, etc.) is independent of the prevailing pressure, as is largely true in the case of liquids, overwhelming advantages exist is preferring the volume velocity over the more ubiquitous and classical mass velocity. In a generalization of ideas pioneered by D. D. Joseph and co-workers, we outline the reasons for this volumetric velocity preference in a broad general context by identifying a large class of physical problems whose solutions are rendered more accessible by exploiting this unconventional velocity choice.

  12. Aerosol properties and radiative forcing for three air masses transported in Summer 2011 to Sopot, Poland

    NASA Astrophysics Data System (ADS)

    Rozwadowska, Anna; Stachlewska, Iwona S.; Makuch, P.; Markowicz, K. M.; Petelski, T.; Strzałkowska, A.; Zieliński, T.

    2013-05-01

    Properties of atmospheric aerosols and solar radiation reaching the Earth's surface were measured during Summer 2011 in Sopot, Poland. Three cloudless days, characterized by different directions of incoming air-flows, which are typical transport pathways to Sopot, were used to estimate a radiative forcing due to aerosols present in each air mass.

  13. Geoelectrical Evidence of Bicontinuum Transport in Ground Water

    NASA Astrophysics Data System (ADS)

    Singha, K.; Day-Lewis, F. D.; Lane, J. W.

    2007-12-01

    The fate and transport of chemicals in ground water is commonly described by advection and dispersion processes. In many settings, however, observed transport behavior appears inconsistent with the standard advective-dispersive model; instead, concentration histories show long tailing behavior, non-Gaussian breakthrough, and/or rebound after pumping for mass removal has ceased. These phenomena have prompted the consideration of dual-domain, rate-limited mass transfer (RLMT) as a controlling process. Determination of parameters describing mass-transfer between mobile and immobile domains - or even verifying the occurrence of RLMT - is problematic because geochemical data-collection methods preferentially sample the mobile component of the pore space. We present direct evidence of RLMT at the field scale during an aquifer storage and recovery experiment. We observe a hysteretic relation between measurements of pore-fluid conductivity (from borehole fluid samples) and bulk earth conductivity (from borehole electrical-resistivity). This hysteresis contradicts advective-dispersive transport and the standard petrophysical model relating pore-fluid and bulk conductivity, but can be explained by bicontinuum transport models that include first-order RLMT. Using a simple model, we demonstrate that geoelectrical methods can be used to bound estimates of mass transfer-rates and immobile porosity that are otherwise difficult to estimate in situ. These findings suggest that RLMT is one of the fundamental processes controlling solute transport and the efficiency of aquifer remediation, and suggest that similar analyses in other geologic settings may help evaluate the prevalence of RLMT.

  14. Tomography-based monitoring of isothermal snow metamorphism under advective conditions

    NASA Astrophysics Data System (ADS)

    Ebner, P. P.; Schneebeli, M.; Steinfeld, A.

    2015-07-01

    Time-lapse X-ray microtomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. The effect of diffusion and advection across the snow pores on the snow microstructure were analysed in controlled laboratory experiments and possible effects on natural snowpacks discussed. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective permeability. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Isothermal snow metamorphism is driven by sublimation deposition caused by the Kelvin effect and is the limiting factor independently of the transport regime in the pores.

  15. A Study of the Physical Processes of an Advection Fog Boundary Layer

    NASA Astrophysics Data System (ADS)

    Liu, Duan Yang; Yan, Wen Lian; Yang, Jun; Pu, Mei Juan; Niu, Sheng Jie; Li, Zi Hua

    2016-01-01

    A large quantity of advection fog appeared in the Yangtze River delta region between 1 and 2 December 2009. Here, we detail the fog formation and dissipation processes and the background weather conditions. The fog boundary layer and its formation and dissipation mechanisms have also been analyzed using field data recorded in a northern suburb of Nanjing. The results showed the following: (1) This advection fog was generated by interaction between advection of a north-east cold ground layer and a south-east warm upper layer. The double-inversion structure generated by this interaction between the cold and warm advections and steady south-east vapour transport was the main cause of this long-lasting fog. The double-inversion structure provided good thermal conditions for the thick fog, and the south-east vapour transport was not only conducive to maintaining the thickness of the fog but also sustained its long duration. (2) The fog-top altitude was over 600 m for most of the time, and the fog reduced visibility to less than 100 m for approximately 12 h. (3) The low-level jet near the lower inversion layer also played a role in maintaining the thick fog system by promoting heat, momentum and south-east vapour transport.

  16. Model simulation and experiments of flow and mass transport through a nano-material gas filter

    SciTech Connect

    Yang, Xiaofan; Zheng, Zhongquan C.; Winecki, Slawomir; Eckels, Steve

    2013-11-01

    A computational model for evaluating the performance of nano-material packed-bed filters was developed. The porous effects of the momentum and mass transport within the filter bed were simulated. For the momentum transport, an extended Ergun-type model was employed and the energy loss (pressure drop) along the packed-bed was simulated and compared with measurement. For the mass transport, a bulk dsorption model was developed to study the adsorption process (breakthrough behavior). Various types of porous materials and gas flows were tested in the filter system where the mathematical models used in the porous substrate were implemented and validated by comparing with experimental data and analytical solutions under similar conditions. Good agreements were obtained between experiments and model predictions.

  17. Mass transport in a porous microchannel for non-Newtonian fluid with electrokinetic effects.

    PubMed

    Mondal, Sourav; De, Sirshendu

    2013-03-01

    Quantification of mass transfer in porous microchannel is of paramount importance in several applications. Transport of neutral solute in presence of convective-diffusive EOF having non-Newtonian rheology, in a porous microchannel was presented in this article. The governing mass transfer equation coupled with velocity field was solved along with associated boundary conditions using a similarity solution method. An analytical solution of mass transfer coefficient and hence, Sherwood number were derived from first principles. The corresponding effects of assisting and opposing pressure-driven flow and EOF were also analyzed. The influence of wall permeation, double-layer thickness, rheology, etc. on the mass transfer was also investigated. Permeation at the wall enhanced the mass transfer coefficient more than five times compared to impervious conduit in case of pressure-driven flow assisting the EOF at higher values of κh. Shear thinning fluid exhibited more enhancement of Sherwood number in presence of permeation compared to shear thickening one. The phenomenon of stagnation was observed at a particular κh (∼2.5) in case of EOF opposing the pressure-driven flow. This study provided a direct quantification of transport of a neutral solute in case of transdermal drug delivery, transport of drugs from blood to target region, etc.

  18. Investigating Mass Transport Limitations on Xylan Hydrolysis During Dilute Acid Pretreatment of Poplar

    SciTech Connect

    Mittal, Ashutosh; Pilath, Heid M.; Parent, Yves; Chatterjee, Siddharth G.; Donohoe, Bryon S.; Yarbrough, John M.; Himmel, Michael E.; Nimlos, Mark R.; Johnson, David K.

    2014-04-28

    Mass transport limitations could be an impediment to achieving high sugar yields during biomass pretreatment and thus be a critical factor in the economics of biofuels production. The objective of this work was to study the mass transfer restrictions imposed by the structure of biomass on the hydrolysis of xylan during dilute acid pretreatment of biomass. Mass transfer effects were studied by pretreating poplar wood at particle sizes ranging from 10 micrometers to 10 mm. This work showed a significant reduction in the rate of xylan hydrolysis in poplar when compared to the intrinsic rate of hydrolysis for isolated xylan that is possible in the absence of mass transfer. In poplar samples we observed no significant difference in the rates of xylan hydrolysis over more than two orders of magnitude in particle size. It appears that no additional mass transport restrictions are introduced by increasing particle size from 10 micrometers to 10 mm. This work suggests that the rates of xylan hydrolysis in biomass particles are limited primarily by the diffusion of hydrolysis products out of plant cell walls. A mathematical description is presented to describe the kinetics of xylan hydrolysis that includes transport of the hydrolysis products through biomass into the bulk solution. The modeling results show that the effective diffusion coefficient of the hydrolysis products in the cell wall is several orders of magnitude smaller than typical values in other applications signifying the role of plant cell walls in offering resistance to diffusion of the hydrolysis products.

  19. Thermal debinding modeling of mass transport and deformation in powder-injection molding compact

    NASA Astrophysics Data System (ADS)

    Shengjie, Ying; Lam, Y. C.; Yu, S. C. M.; Tam, K. C.

    2002-06-01

    A two-dimensional model of mass transport and deformation in thermal debinding for the powder-injection molding (PIM) compact, based on mass and heat transfer in deformable porous media and elasticity theory, is proposed. The primary mechanisms of mass transport, i.e., liquid flow, gas flow, vapor diffusion, and convection, as well as heat transfer, polymer pyrolysis, powder-particle packing, compact deformation, and their interactions are simultaneously included in the model. A computer code, in which integrated control-volume finite-difference and finite-element methods are employed, is developed to simulate the process. The simulated results revealed that the nonuniform distribution of polymer residue, which results from the nonuniform flow of the polymer, causes the nonuniform deformation in the compact. Severe nonuniform deformation in the compact might lead to cracking, distortion, and failure of the compact during the polymer-removal process.

  20. Electrocatalytic performance of fuel cell reactions at low catalyst loading and high mass transport.

    PubMed

    Zalitis, Christopher M; Kramer, Denis; Kucernak, Anthony R

    2013-03-28

    An alternative approach to the rotating disk electrode (RDE) for characterising fuel cell electrocatalysts is presented. The approach combines high mass transport with a flat, uniform, and homogeneous catalyst deposition process, well suited for studying intrinsic catalyst properties at realistic operating conditions of a polymer electrolyte fuel cell (PEFC). Uniform catalyst layers were produced with loadings as low as 0.16 μgPt cm(-2) and thicknesses as low as 200 nm. Such ultra thin catalyst layers are considered advantageous to minimize internal resistances and mass transport limitations. Geometric current densities as high as 5.7 A cm(-2)Geo were experimentally achieved at a loading of 10.15 μgPt cm(-2) for the hydrogen oxidation reaction (HOR) at room temperature, which is three orders of magnitude higher than current densities achievable with the RDE. Modelling of the associated diffusion field suggests that such high performance is enabled by fast lateral diffusion within the electrode. The electrodes operate over a wide potential range with insignificant mass transport losses, allowing the study of the ORR at high overpotentials. Electrodes produced a specific current density of 31 ± 9 mA cm(-2)Spec at a potential of 0.65 V vs. RHE for the oxygen reduction reaction (ORR) and 600 ± 60 mA cm(-2)Spec for the peak potential of the HOR. The mass activity of a commercial 60 wt% Pt/C catalyst towards the ORR was found to exceed a range of literature PEFC mass activities across the entire potential range. The HOR also revealed fine structure in the limiting current range and an asymptotic current decay for potentials above 0.36 V. These characteristics are not visible with techniques limited by mass transport in aqueous media such as the RDE.

  1. Multiscale mass transport in z ˜6 galactic discs: fuelling black holes

    NASA Astrophysics Data System (ADS)

    Prieto, Joaquin; Escala, Andrés

    2016-08-01

    By using Adaptive Mesh Refinement cosmological hydrodynamic N-body zoom-in simulations, with the RAMSES code, we studied the mass transport processes on to galactic nuclei from high redshift up to z ˜6. Due to the large dynamical range of the simulations, we were able to study the mass accretion process on scales from ˜50 kpc to ˜few 1 pc. We studied the black hole (BH) growth on to the Galactic Centre in relation with the mass transport processes associated to both the Reynolds stress and the gravitational stress on the disc. Such methodology allowed us to identify the main mass transport process as a function of the scales of the problem. We found that in simulations that include radiative cooling and supernovae feedback, the supermassive black hole (SMBH) grows at the Eddington limit for some periods of time presenting ≈ 0.5 throughout its evolution. The α parameter is dominated by the Reynolds term, αR, with αR ≫ 1. The gravitational part of the α parameter, αG, has an increasing trend towards the Galactic Centre at higher redshifts, with values αG ˜1 at radii ≲ few 101 pc contributing to the BH fuelling. In terms of torques, we also found that gravity has an increasing contribution towards the Galactic Centre at earlier epochs with a mixed contribution above ˜100 pc. This complementary work between pressure gradients and gravitational potential gradients allows an efficient mass transport on the disc with average mass accretion rates of the order of ˜few 1 M⊙ yr-1. These levels of SMBH accretion rates found in our cosmological simulations are needed in all models of SMBH growth that attempt to explain the formation of redshift 6-7 quasars.

  2. Ion-exchange reactions on clay minerals coupled with advection/dispersion processes. Application to Na+/Ca2+ exchange on vermiculite: Reactive-transport modeling, batch and stirred flow-through reactor experiments

    NASA Astrophysics Data System (ADS)

    Tertre, E.; Hubert, F.; Bruzac, S.; Pacreau, M.; Ferrage, E.; Prêt, D.

    2013-07-01

    The present study aims at testing the validity of using an Na+/Ca2+ ion-exchange model, derived from batch data to interpret experimental Ca2+-for-Na+ exchange breakthrough curves obtained on vermiculite (a common swelling clay mineral in surface environments). The ion-exchange model was constructed considering the multi-site nature of the vermiculite surface as well as the exchange of all aqueous species (Mg2+ derived from the dissolution of the solid and H+). The proposed ion-exchange model was then coupled with a transport model, and the predicted breakthrough curves were compared with the experimental ones obtained using a well stirred flow-through reactor. For a given solute residence time in the reactor (typically 50 min), our thermodynamic model based on instantaneous equilibrium was found to accurately reproduce several of the experimental breakthrough curves, depending on the Na+ and Ca2+ concentrations of the influents pumped through the reactor. However the model failed to reproduce experimental breakthrough curves obtained at high flow rates and low chemical gradient between the exchanger phase and the solution. An alternative model based on a hybrid equilibrium/kinetic approach was thus used and allowed predicting experimental data. Based on these results, we show that a simple parameter can be used to differentiate between thermodynamic and kinetic control of the exchange reaction with water flow. The results of this study are relevant for natural systems where two aquatic environments having contrasted chemistries interact. Indeed, the question regarding the attainment of a full equilibrium in such a system during the contact time of the aqueous phase with the particle/colloid remains most often open. In this context, we show that when a river (a flow of fresh water) encounters marine colloids, a systematic full equilibrium can be assumed (i.e., the absence of kinetic effects) when the residence time of the solute in 1 m3 of the system is ⩾6200 h.

  3. Modeling of Convective-Stratiform Precipitation Processes: Sensitivity to Partitioning Methods and Numerical Advection Schemes

    NASA Technical Reports Server (NTRS)

    Lang, Steve; Tao, W.-K.; Simpson, J.; Ferrier, B.; Einaudi, Franco (Technical Monitor)

    2001-01-01

    Six different convective-stratiform separation techniques, including a new technique that utilizes the ratio of vertical and terminal velocities, are compared and evaluated using two-dimensional numerical simulations of a tropical [Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA COARE)] and midlatitude continental [Preliminary Regional Experiment for STORM-Central (PRESTORM)] squall line. The simulations are made using two different numerical advection schemes: 4th order and positive definite advection. Comparisons are made in terms of rainfall, cloud coverage, mass fluxes, apparent heating and moistening, mean hydrometeor profiles, CFADs (Contoured Frequency with Altitude Diagrams), microphysics, and latent heating retrieval. Overall, it was found that the different separation techniques produced results that qualitatively agreed. However, the quantitative differences were significant. Observational comparisons were unable to conclusively evaluate the performance of the techniques. Latent heating retrieval was shown to be sensitive to the use of separation technique mainly due to the stratiform region for methods that found very little stratiform rain. The midlatitude PRESTORM simulation was found to be nearly invariant with respect to advection type for most quantities while for TOGA COARE fourth order advection produced numerous shallow convective cores and positive definite advection fewer cells that were both broader and deeper penetrating above the freezing level.

  4. Coupled effect of flow variability and mass transfer on contaminant transport and attenuation in groundwater

    NASA Astrophysics Data System (ADS)

    Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon

    2016-04-01

    The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.

  5. Numerical modelling of shear-dependent mass transfer in large arteries

    NASA Astrophysics Data System (ADS)

    Rappitsch, Gerhard; Perktold, Karl; Pernkopf, Elisabeth

    1997-10-01

    A numerical scheme for the simulation of blood flow and transport processes in large arteries is presented. Blood flow is described by the unsteady 3D incompressible Navier-Stokes equations for Newtonian fluids; solute transport is modelled by the advection-diffusion equation. The resistance of the arterial wall to transmural transport is described by a shear-dependent wall permeability model. The finite element formulation of the Navier-Stokes equations is based on an operator-splitting method and implicit time discretization. The streamline upwind/Petrov-Galerkin (SUPG) method is applied for stabilization of the advective terms in the transport equation and in the flow equations. A numerical simulation is carried out for pulsatile mass transport in a 3D arterial bend to demonstrate the influence of arterial flow patterns on wall permeability characteristics and transmural mass transfer. The main result is a substantial wall flux reduction at the inner side of the curved region.

  6. Estimation of transport parameters of phenolic compounds and inorganic contaminants through composite landfill liners using one-dimensional mass transport model

    SciTech Connect

    Varank, Gamze; Demir, Ahmet; Yetilmezsoy, Kaan; Bilgili, M. Sinan; Top, Selin; Sekman, Elif

    2011-11-15

    Highlights: > We conduct 1D advection-dispersion modeling to estimate transport parameters. > We examine fourteen phenolic compounds and three inorganic contaminants. > 2-MP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,3,4,6-TeCP have the highest coefficients. > Dispersion coefficients of Cu are determined to be higher than Zn and Fe. > Transport of phenolics can be prevented by zeolite and bentonite in landfill liners. - Abstract: One-dimensional (1D) advection-dispersion transport modeling was conducted as a conceptual approach for the estimation of the transport parameters of fourteen different phenolic compounds (phenol, 2-CP, 2-MP, 3-MP, 4-MP, 2-NP, 4-NP, 2,4-DNP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,4,6-TCP, 2,3,4,6-TeCP, PCP) and three different inorganic contaminants (Cu, Zn, Fe) migrating downward through the several liner systems. Four identical pilot-scale landfill reactors (0.25 m{sup 3}) with different composite liners (R1: 0.10 + 0.10 m of compacted clay liner (CCL), L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R2: 0.002-m-thick damaged high-density polyethylene (HDPE) geomembrane overlying 0.10 + 0.10 m of CCL, L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R3: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick bentonite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 1 x 10{sup -8} m/s, R4: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick zeolite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 4.24 x 10{sup -7} m/s) were simultaneously run for a period of about 540 days to investigate the nature of diffusive and advective transport of the selected organic and inorganic contaminants. The results of 1D transport model showed that the highest molecular diffusion coefficients, ranging from 4.77 x 10{sup -10} to 10.67 x 10{sup -10} m{sup 2}/s, were estimated for phenol (R4), 2-MP (R1), 2,4-DNP (R2), 2,4-DCP (R1), 2,6-DCP (R2), 2,4,5-TCP (R2) and 2,3,4,6-TeCP (R1). For all reactors

  7. Density-of-states effective mass and scattering parameter measurements by transport phenomena in thin films

    NASA Astrophysics Data System (ADS)

    Young, D. L.; Coutts, T. J.; Kaydanov, V. I.

    2000-02-01

    A novel machine has been developed to measure transport coefficients in the temperature range of 50-350 K of thin films deposited on electrically insulating substrates. The measured coefficients—resistivity, Hall, Seebeck, and Nernst—are applied to solutions of the Boltzmann transport equation to give information about the film's density-of-states effective mass, the Fermi energy level, and an energy-dependent scattering parameter. The machine is designed to eliminate or compensate for simultaneously occurring transport phenomena that would interfere with the desired measured quantity, while allowing for all four coefficients to be measured on the same sample. An average density-of-states effective mass value of 0.29±0.04me was measured on the transparent conductive oxide, cadmium stannate (CTO), over a carrier concentration range of 2-7×1020cm-3. This effective mass value matched previous results obtained by optical and thermoelectric modeling. The measured scattering parameter indicates that neutral impurities or a mixture of scattering mechanisms may inhibit the transport of carriers in CTO.

  8. Specific features of defect and mass transport in concentrated fcc alloys

    SciTech Connect

    Osetsky, Yuri N.; Béland, Laurent K.; Stoller, Roger E.

    2016-06-15

    We report that diffusion and mass transport are basic properties that control materials performance, such as phase stability, solute decomposition and radiation tolerance. While understanding diffusion in dilute alloys is a mature field, concentrated alloys are much less studied. Here, atomic-scale diffusion and mass transport via vacancies and interstitial atoms are compared in fcc Ni, Fe and equiatomic Ni-Fe alloy. High temperature properties were determined using conventional molecular dynamics on the microsecond timescale, whereas the kinetic activation-relaxation (k-ART) approach was applied at low temperatures. The k-ART was also used to calculate transition states in the alloy and defect transport coefficients. The calculations reveal several specific features. For example, vacancy and interstitial defects migrate via different alloy components, diffusion is more sluggish in the alloy and, notably, mass transport in the concentrated alloy cannot be predicted on the basis of diffusion in its pure metal counterparts. Lastly, the percolation threshold for the defect diffusion in the alloy is discussed and it is suggested that this phenomenon depends on the properties and diffusion mechanisms of specific defects.

  9. Specific features of defect and mass transport in concentrated fcc alloys

    DOE PAGES

    Osetsky, Yuri N.; Béland, Laurent K.; Stoller, Roger E.

    2016-06-15

    We report that diffusion and mass transport are basic properties that control materials performance, such as phase stability, solute decomposition and radiation tolerance. While understanding diffusion in dilute alloys is a mature field, concentrated alloys are much less studied. Here, atomic-scale diffusion and mass transport via vacancies and interstitial atoms are compared in fcc Ni, Fe and equiatomic Ni-Fe alloy. High temperature properties were determined using conventional molecular dynamics on the microsecond timescale, whereas the kinetic activation-relaxation (k-ART) approach was applied at low temperatures. The k-ART was also used to calculate transition states in the alloy and defect transport coefficients.more » The calculations reveal several specific features. For example, vacancy and interstitial defects migrate via different alloy components, diffusion is more sluggish in the alloy and, notably, mass transport in the concentrated alloy cannot be predicted on the basis of diffusion in its pure metal counterparts. Lastly, the percolation threshold for the defect diffusion in the alloy is discussed and it is suggested that this phenomenon depends on the properties and diffusion mechanisms of specific defects.« less

  10. High-Schmidt-number mass transport mechanisms from a turbulent flow to absorbing sediments

    NASA Astrophysics Data System (ADS)

    Scalo, Carlo; Piomelli, Ugo; Boegman, Leon

    2012-11-01

    We have investigated the mechanisms involved in dissolved oxygen (DO) transfer from a turbulent flow to an underlying organic sediment bed, populated with DO-absorbing bacteria, relying on the coupling between the bio-geochemistry of the sediment layer and large-eddy simulation for the transport on the water side [Scalo et al., J. Geophys. Res., 117(C6), 2012]. Time correlations at the sediment-water interface (SWI) show that the diffusive sublayer acts as a de-noising filter with respect to the overlying turbulence; the mass flux is not affected by low-amplitude background fluctuations in the wall-shear stress but, rather, by energetic and coherent near-wall transport events, in agreement with the surface renewal theory. The spatial and temporal distribution of the mass flux is therefore modulated by rapidly evolving near-wall high-speed streaks (associated with intermittent peaks in the wall-shear stress) transporting patches of (rich-in-oxygen) fluid to the edge of the diffusive sublayer, leaving slowly-regenerating elongated patches of positive DO concentration fluctuation and mass flux at the SWI. The sediment surface retains the signature of the overlying turbulent transport over long time scales, allowed by the slow bacterial absorption. Currently postdoctoral fellow at Center for Turbulence Research (scalo@stanford.edu).

  11. Multicomponent mass transport model: a model for simulating migration of radionuclides in ground water

    SciTech Connect

    Washburn, J.F.; Kaszeta, F.E.; Simmons, C.S.; Cole, C.R.

    1980-07-01

    This report presents the results of the development of a one-dimensional radionuclide transport code, MMT2D (Multicomponent Mass Transport), for the AEGIS Program. Multicomponent Mass Transport is a numerical solution technique that uses the discrete-parcel-random-wald (DPRW) method to directly simulate the migration of radionuclides. MMT1D accounts for: convection;dispersion; sorption-desorption; first-order radioactive decay; and n-membered radioactive decay chains. Comparisons between MMT1D and an analytical solution for a similar problem show that: MMT1D agrees very closely with the analytical solution; MMT1D has no cumulative numerical dispersion like that associated with solution techniques such as finite differences and finite elements; for current AEGIS applications, relatively few parcels are required to produce adequate results; and the power of MMT1D is the flexibility of the code in being able to handle complex problems for which analytical solution cannot be obtained. Multicomponent Mass Transport (MMT1D) codes were developed at Pacific Northwest Laboratory to predict the movement of radiocontaminants in the saturated and unsaturated sediments of the Hanford Site. All MMT models require ground-water flow patterns that have been previously generated by a hydrologic model. This report documents the computer code and operating procedures of a third generation of the MMT series: the MMT differs from previous versions by simulating the mass transport processes in systems with radionuclide decay chains. Although MMT is a one-dimensional code, the user is referred to the documentation of the theoretical and numerical procedures of the three-dimensional MMT-DPRW code for discussion of expediency, verification, and error-sensitivity analysis.

  12. Implications of anthropogenic river stage fluctuations on mass transport in a valley fill aquifer

    USGS Publications Warehouse

    Boutt, D.F.; Fleming, B.J.

    2009-01-01

    In humid regions a strong coupling between surface water features and groundwater systems may exist. In these environments the exchange of water and solute depends primarily on the hydraulic gradient between the reservoirs. We hypothesize that daily changes in river stage associated with anthropogenic water releases (such as those from a hydroelectric dam) cause anomalous mixing in the near-stream environment by creating large hydraulic head gradients between the stream and adjacent aquifer. We present field observations of hydraulic gradient reversals in a shallow aquifer. Important physical processes observed in the field are explicitly reproduced in a physically based two-dimensional numerical model of groundwater flow coupled to a simplistic surface water boundary condition. Mass transport simulations of a conservative solute introduced into the surface water are performed and examined relative to a stream condition without stage fluctuations. Simulations of 20 d for both fluctuating river stage and fixed high river stage show that more mass is introduced into the aquifer from the stream in the oscillating case even though the net water flux is zero. Enhanced transport by mechanical dispersion leads to mass being driven away from the hydraulic zone of influence of the river. The modification of local hydraulic gradients is likely to be important for understanding dissolved mass transport in near-stream aquifer environments and can influence exchange zone processes under conditions of high-frequency stream stage changes. Copyright 2009 by the American Geophysical Union.

  13. Mass Transport and Shear Stress as Mediators of Flow Effects on Atherosclerotic Plaque Origin and Growth

    NASA Astrophysics Data System (ADS)

    Gorder, Riley; Aliseda, Alberto

    2009-11-01

    The carotid artery bifurcation (CAB) is one of the leading site for atherosclerosis, a major cause of mortality and morbidity in the developed world. The specific mechanisms by which perturbed flow at the bifurcation and in the carotid bulge promotes plaque formation and growth are not fully understood. Shear stress, mass transport, and flow residence times are considered dominant factors. Shear stress causes restructuring of endothelial cells at the arterial wall which changes the wall's permeability. Long residence times are associated with enhanced mass transport through increased diffusion of lipids and white blood cells into the arterial wall. Although momentum and mass transfer are traditionally coupled by correlations similar to Reynolds Analogy, the complex flow patterns present in this region due to the pulsatile, transitional, detached flow associated with the complex geometry makes the validity of commonly accepted assumptions uncertain. We create solid models of the CAB from MRI or ultrasound medical images, build flow phantoms on clear polyester resin and use an IOR matching, blood mimicking, working fluid. Using PIV and dye injection techniques the shear stress and scalar transport are experimentally investigated. Our goal is to establish a quantitative relationship between momentum and mass transfer under a wide range of physiologically normal and pathological conditions.

  14. Finite element modeling of mass transport in high-Péclet cardiovascular flows

    NASA Astrophysics Data System (ADS)

    Hansen, Kirk; Arzani, Amirhossein; Shadden, Shawn

    2016-11-01

    Mass transport plays an important role in many important cardiovascular processes, including thrombus formation and atherosclerosis. These mass transport problems are characterized by Péclet numbers of up to 108, leading to several numerical difficulties. The presence of thin near-wall concentration boundary layers requires very fine mesh resolution in these regions, while large concentration gradients within the flow cause numerical stabilization issues. In this work, we will discuss some guidelines for solving mass transport problems in cardiovascular flows using a stabilized Galerkin finite element method. First, we perform mesh convergence studies in a series of idealized and patient-specific geometries to determine the required near-wall mesh resolution for these types of problems, using both first- and second-order tetrahedral finite elements. Second, we investigate the use of several boundary condition types at outflow boundaries where backflow during some parts of the cardiac cycle can lead to convergence issues. Finally, we evaluate the effect of reducing Péclet number by increasing mass diffusivity as has been proposed by some researchers. This work was supported by the NSF GRFP and NSF Career Award #1354541.

  15. Guidance and trajectory considerations in lunar mass transportation. [to space colonies at libration points

    NASA Technical Reports Server (NTRS)

    Heppenheimer, T. A.; Kaplan, D.

    1977-01-01

    Flight-mechanics problems associated with large-scale transport of lunar mass to a space colony or manufacturing facility are discussed. The proposed transport method involves launch of payloads from a mass-driver on the lunar surface, onto ballistic trajectories to a passive mass-catcher located near the L2 libration point, with the caught mass subsequently being transported to the colony. Arrival velocities at L2, sensitivities in arrival dispersion due to launch errors, and effects of launch site location are treated, via numerically integrated orbits in the restricted three-body problem. From any launch site it is possible to define a target point reached with zero dispersion due to errors in a selected component of launch velocity. Effects of lunar geometrical librations and of obliquity, as well as the conditions for biasing a trajectory away from L2 so as to reduce stationkeeping costs, are dealt with along with transfer orbits from L2 to the colony. The theory of capture and the theory of resonance lead to a colony orbit, with period approximately two weeks, reached from L2 with velocity increment as low as 9.02 m/sec.

  16. Mass transport disturbances in the distal graft/artery junction of a peripheral bypass graft.

    PubMed

    Devereux, P D; O'Callaghan, S M; Walsh, M T; McGloughlin, T

    2005-11-01

    Intimal hyperplasia (IH) development is a primary cause of failure of reconstructive bypass surgery. While the exact mechanism by which IH initiates and proliferates has yet to be fully elucidated, it is clear that the abnormal haemodynamics present in the downstream graft/artery junction are intrinsic in its development. Mass transport disturbances owing to abnormal haemodynamics have been associated with atherogenesis and it is for this reason that an investigation into transport of platelet-derived growth factor (PDGF), a known promoter of the intimal hyperplastic response, at the downstream graft/artery junction was carried out. A steady flow analysis in a three-dimensional, idealized, downstream graft/artery junction was carried out using commercial computational fluid dynamics software. It was found that there is a two-and-half fold increase in the transport of PDGF to the artery wall at the bed of the junction when compared with an idealized, healthy artery. The presence of secondary flows in the downstream arterial section also leads to large disturbances in mass transport. It was concluded that PDGF transport in the downstream graft/artery junction tends to be highly disturbed and that there may be a role of this disturbance in the initiation and subsequent development of distal anastomotic intimal hyperplasia.

  17. Advances in Studies of Electrode Kinetics and Mass Transport in AMTEC Cells (abstract)

    NASA Technical Reports Server (NTRS)

    Williams, R. M.; Jeffries-Nakamura, B.; Ryan, M. A.; Underwood, M. L.; Kisor, A.; O'Connor, D.; Kikkert, S.

    1993-01-01

    Previous work reported from JPL has included characterization of electrode kinetics and alkali atom transport from electrodes including Mo, W, WRh(sub x), WPt(sub x)(Mn), in sodium AMTEC cells and vapor exposure cells, and Mo in potassium vapor exposure cells. These studies were generally performed in cells with small area electrodes (about 1 to 5 cm(sup 2)), and device geometry had little effect on transport. Alkali diffusion coefficients through these electrodes have been characterized, and approximate surface diffusion coefficients derived in cases of activated transport. A basic model of electrode kinetic at the alkali metal vapor/porous metal electrode/alkali beta'-alumina solid electrolyte three phase boundary has been proposed which accounts for electrochemical reaction rates with a collision frequency near the three phase boundary and tunneling from the porous electrode partially covered with adsorbed alkali metal atoms. The small electrode effect in AMTEC cells has been discussed in several papers, but quantitative investigations have described only the overall effect and the important contribution of electrolyte resistance. The quantitative characterization of transport losses in cells with large area electrodes has been limited to simulations of large area electrode effects, or characterization of transport losses from large area electrodes with significant longitudinal temperature gradients. This paper describes new investigations of electrochemical kinetics and transport, particularily with WPt(sub 3.5) electrodes, including the influence of electrode size on the mass transport loss in the AMTEC cell. These electrodes possess excellent sodium transport properties making verification of device limitations on transport much more readily attained.

  18. Effects of reservoir heterogeneity on scaling of effective mass transfer coefficient for solute transport.

    PubMed

    Leung, Juliana Y; Srinivasan, Sanjay

    2016-09-01

    Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It

  19. Effects of reservoir heterogeneity on scaling of effective mass transfer coefficient for solute transport

    NASA Astrophysics Data System (ADS)

    Leung, Juliana Y.; Srinivasan, Sanjay

    2016-09-01

    Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It

  20. Striated populations in disordered environments with advection

    NASA Astrophysics Data System (ADS)

    Chotibut, Thiparat; Nelson, David R.; Succi, Sauro

    2017-01-01

    Growth in static and controlled environments such as a Petri dish can be used to study the spatial population dynamics of microorganisms. However, natural populations such as marine microbes experience fluid advection and often grow up in heterogeneous environments. We investigate a generalized Fisher-Kolmogorov-Petrovsky-Piscounov (FKPP) equation describing single species population subject to a constant flow field and quenched random spatially inhomogeneous growth rates with a fertile overall growth condition. We analytically and numerically demonstrate that the non-equilibrium steady-state population density develops a flow-driven striation pattern. The striations are highly asymmetric with a longitudinal correlation length that diverges linearly with the flow speed and a transverse correlation length that approaches a finite velocity-independent value. Linear response theory is developed to study the statistics of the steady states. Theoretical predictions show excellent agreement with the numerical steady states of the generalized FKPP equation obtained from Lattice Boltzmann simulations. These findings suggest that, although the growth disorder can be spatially uncorrelated, correlated population structures with striations emerge naturally at sufficiently strong advection.

  1. Waves, advection, and cloud patterns on Venus

    NASA Technical Reports Server (NTRS)

    Schinder, Paul J.; Gierasch, Peter J.; Leroy, Stephen S.; Smith, Michael D.

    1990-01-01

    The stable layers adjacent to the nearly neutral layer within the Venus clouds are found to be capable of supporting vertically trapped, horizontally propagating waves with horizontal wavelengths of about 10 km and speeds of a few meters per second relative to the mean wind in the neutral layer. These waves may possibly be excited by turbulence within the neutral layer. Here, the properties of the waves, and the patterns which they might produce within the visible clouds if excited near the subsolar point are examined. The patterns can be in agreement with many features in images. The waves are capable of transferring momentum latitudinally to help maintain the general atmospheric spin, but at present we are not able to evaluate wave amplitudes. We also examine an alternative possibility that the cloud patterns are produced by advection and shearing by the mean zonal and meridional flow of blobs formed near the equator. It is concluded that advection and shearing by the mean flow is the most likely explanation for the general pattern of small scale striations.

  2. Parallel algorithms for semi-lagrangian advection

    NASA Astrophysics Data System (ADS)

    Malevsky, A. V.; Thomas, S. J.

    1997-08-01

    Numerical time step limitations associated with the explicit treatment of advection-dominated problems in computational fluid dynamics are often relaxed by employing Eulerian-Lagrangian methods. These are also known as semi-Lagrangian methods in the atmospheric sciences. Such methods involve backward time integration of a characteristic equation to find the departure point of a fluid particle arriving at a Eulerian grid point. The value of the advected field at the departure point is obtained by interpolation. Both the trajectory integration and repeated interpolation influence accuracy. We compare the accuracy and performance of interpolation schemes based on piecewise cubic polynomials and cubic B-splines in the context of a distributed memory, parallel computing environment. The computational cost and interprocessor communication requirements for both methods are reported. Spline interpolation has better conservation properties but requires the solution of a global linear system, initially appearing to hinder a distributed memory implementation. The proposed parallel algorithm for multidimensional spline interpolation has almost the same communication overhead as local piecewise polynomial interpolation. We also compare various techniques for tracking trajectories given different values for the Courant number. Large Courant numbers require a high-order ODE solver involving multiple interpolations of the velocity field.

  3. Gluon transport equation with effective mass and dynamical onset of Bose–Einstein condensation

    DOE PAGES

    Blaizot, Jean-Paul; Jiang, Yin; Liao, Jinfeng

    2016-05-01

    In this paper we study the transport equation describing a dense system of gluons, in the small scattering angle approximation, taking into account medium-generated effective masses of the gluons. We focus on the case of overpopulated systems that are driven to Bose–Einstein condensation on their way to thermalization. Lastly, the presence of a mass modifies the dispersion relation of the gluon, as compared to the massless case, but it is shown that this does not change qualitatively the scaling behavior in the vicinity of the onset.

  4. Can transport peak explain the low-mass enhancement of dileptons at RHIC?

    NASA Astrophysics Data System (ADS)

    Akamatsu, Y.; Hamagaki, H.; Hatsuda, T.; Hirano, T.

    2011-12-01

    We propose a novel relation between the low-mass enhancement of dielectrons observed at PHENIX and transport coefficients of QGP such as the charge diffusion constant D and the relaxation time τJ. We parameterize the transport peak in the spectral function using the second-order relativistic dissipative hydrodynamics by Israel and Stewart. Combining the spectral function and the full (3+1)-dimensional hydrodynamical evolution with the lattice EoS, theoretical dielectron spectra and the experimental data are compared. Detailed analysis suggests that the low-mass dilepton enhancement originates mainly from the high-temperature QGP phase where there is a large electric charge fluctuation as obtained from lattice QCD simulations.

  5. A non-equilibrium thermodynamics model of multicomponent mass and heat transport in pervaporation processes

    NASA Astrophysics Data System (ADS)

    Villaluenga, Juan P. G.; Kjelstrup, Signe

    2012-12-01

    The framework of non-equilibrium thermodynamics (NET) is used to derive heat and mass transport equations for pervaporation of a binary mixture in a membrane. In this study, the assumption of equilibrium of the sorbed phase in the membrane and the adjacent phases at the feed and permeate sides of the membrane is abandoned, defining the interface properties using local equilibrium. The transport equations have been used to model the pervaporation of a water-ethanol mixture, which is typically encountered in the dehydration of organics. The water and ethanol activities and temperature profiles are calculated taking mass and heat coupling effects and surfaces into account. The NET approach is deemed good because the temperature results provided by the model are comparable to experimental results available for water-alcohol systems.

  6. An overview of polymer electrolyte membrane electrolyzer for hydrogen production: Modeling and mass transport

    NASA Astrophysics Data System (ADS)

    Abdol Rahim, A. H.; Tijani, Alhassan Salami; Kamarudin, S. K.; Hanapi, S.

    2016-03-01

    Polymer electrolyte membrane electrolyzer (PEME) is a candidate for advanced engineering technology. There are many polymer electrolyte membrane fuel cell (PEMFC) models that have been reported, but none regarding PEME. This paper presents state of the art mass transport models applied to PEME, a detailed literature review of these models and associate methods have been conducted. PEME models are typically developed using analytical, semi empirical and mechanistic techniques that are based on their state and spatial dimensions. Methods for developing the PEME models are introduced and briefly explained. Furthermore the model cell voltage of PEME, which consists of Nernst voltage, ohmic over potential, activation over potential, and diffusion over potential is discussed with focus on mass transport modeling. This paper also presents current issues encountered with PEME model.

  7. Performance of intact and partially degraded concrete barriers in limiting mass transport

    SciTech Connect

    Walton, J.C. )

    1992-06-01

    Mass transport through concrete barriers and release rate from concrete vaults are quantitatively evaluated. The thorny issue of appropriate diffusion coefficients for use in performance assessment calculations is covered, with no ultimate solution found. Release from monolithic concrete vaults composed of concrete waste forms is estimated with a semi-analytical solution. A parametric study illustrates the importance of different parameters on release. A second situation of importance is the role of a concrete shell or vault placed around typical waste forms in limiting mass transport. In both situations, the primary factor controlling concrete performance is cracks. The implications of leaching behavior on likely groundwater concentrations is examined. Frequently, lower groundwater concentrations can be expected in the absence of engineered covers that reduce infiltration.

  8. Advective loss of overwintering Calanus finmarchicus from the Faroe-Shetland Channel

    NASA Astrophysics Data System (ADS)

    Rullyanto, Arief; Jónasdóttir, Sigrún H.; Visser, André W.

    2015-04-01

    The flow of deep water from the Norwegian Sea to the North Atlantic via the Faroe-Shetland Channel is one of the critical bottlenecks in the meridional overturn circulation. It is also a flow that potentially carries with it a large number of the overwintering copepod, Calanus finmarchicus, a regionally important secondary producer. Using a high resolution hydrodynamic model, MIKE 3 FM, we simulate the overflow of deep water and estimate the associated loss rate of C. finmarchicus as a function of the water depth strata within which they reside. We estimate a net advective loss from the Norwegian Sea population of 80±10 kt carbon bound in lipids of C. finmarchicus biomass per year, a number that constitutes about 50% of the total overwintering population. Estimates of water mass characteristics and particle tracking suggest that the fate of individuals transported in the overflowing water is to be entrained into warmer waters of the North Atlantic Basin, a habitat that appears to be unsuitable for successful overwintering.

  9. On the potential importance of transient air flow in advective radon entry into buildings

    SciTech Connect

    Narasimhan, T.N.; Tsang, Y.W.; Holman, H.Y. )

    1990-05-01

    The authors have investigated, using a mathematical model, the temporal variations of air flux within the soil mass surrounding a basement in the presence of time dependent periodic variations of barometric pressure and a persistent under-pressure at the basement. The results of transient air flow show that for a homogeneous soil medium, the effects of barometric fluctuations are most significant in the cases where soil permeability to air is low and the fluctuation frequency is high. In these cases, the barometric fluctuation can greatly enhance the magnitude of fluxes as well as introduce flow direction reversals from surrounding soil into the basement. These large fluxes with direction reversals have strong implications in regard to advective transport of radon. The results suggest that the transient oscillations have to be accounted for in quantifying radon entry into buildings. In the actual field set up, the transient behavior will be further influenced by soil permeability heterogeneity, by soil moisture variations, and by the effects of multiple periodic components in the barometric pressure fluctuations.

  10. Nanoparticle traffic on helical tracks: thermophoretic mass transport through carbon nanotubes.

    PubMed

    Schoen, Philipp A E; Walther, Jens H; Arcidiacono, Salvatore; Poulikakos, Dimos; Koumoutsakos, Petros

    2006-09-01

    Using molecular dynamics simulations, we demonstrate and quantify thermophoretic motion of solid gold nanoparticles inside carbon nanotubes subject to wall temperature gradients ranging from 0.4 to 25 K/nm. For temperature gradients below 1 K/nm, we find that the particles move "on tracks" in a predictable fashion as they follow unique helical orbits depending on the geometry of the carbon nanotubes. These findings markedly advance our knowledge of mass transport mechanisms relevant to nanoscale applications.

  11. Final Report - Ion Production and Transport in Atmospheric Pressure Ion Source Mass Spectrometers

    SciTech Connect

    Farnsworth, Paul B.; Spencer, Ross L.

    2014-05-14

    This document is the final report on a project that focused in the general theme of atmospheric-pressure ion production and transport for mass spectrometry. Within that general theme there were two main projects: the fundamental study of the transport of elemental ions through the vacuum interface of an inductively coupled plasma mass spectrometer (ICPMS), and fundamental studies of the ionization mechanisms in ambient desorption/ionization (ADI) sources for molecular mass spectrometry. In both cases the goal was to generate fundamental understanding of key instrumental processes that would lead to the development of instruments that were more sensitive and more consistent in their performance. The emphasis on consistency derives from the need for instruments that have the same sensitivity, regardless of sample type. In the jargon of analytical chemistry, such instruments are said to be free from matrix effects. In the ICPMS work each stage of ion production and of ion transport from the atmospheric pressure to the high-vacuum mass analyzer was studied. Factors controlling ion transport efficiency and consistency were identified at each stage of pressure reduction. In the ADI work the interactions between an electrospray plume and a fluorescent sample on a surface were examined microscopically. A new mechanism for analyte ion production in desorption electrospray ionization (DESI) was proposed. Optical spectroscopy was used to track the production of reactive species in plasmas used as ADI sources. Experiments with mixed-gas plasmas demonstrated that the addition of a small amount of hydrogen to a helium ADI plasma could boost the sensitivity for some analytes by over an order of magnitude.

  12. Alternating photoinduced mass transport triggered by light polarization in azobenzene containing sol-gel films

    NASA Astrophysics Data System (ADS)

    Fabbri, F.; Lassailly, Y.; Lahlil, K.; Boilot, J. P.; Peretti, J.

    2010-02-01

    Combined shear-force and near-field optical microscopies are used for real-time monitoring of the formation of photoinduced surface relief gratings in photochromic thin films containing azobenzene derivatives. The correlated optical and topographical images provide evidence that the direction of the photoinduced matter migration is defined by the light polarization pattern and that, for a given light intensity pattern, modulating the polarization between two orthogonal states gives rise to alternating mass transport.

  13. Statistical Performance Evaluation of Spatiotemporal Characteristics of Groundwater Flow and Contaminant Mass Transport

    NASA Astrophysics Data System (ADS)

    Matiatos, Ioannis; Papadopoulou, Maria P.; Varouchakis, Emmanouil A.

    2016-04-01

    As groundwater remains one of the most critical natural resources worldwide, numerical models of groundwater flow and contaminant mass transport provide a reliable tool for the efficient protection, planning and sustainable management of groundwater resources. This work focuses on the evaluation of the performance of different numerical models which have been developed to simulate spatiotemporal groundwater flow and contaminant mass transport in a coastal aquifer system. The evaluation of the models' performance has been based on 9 different statistical measures and indices of goodness of fit. Overall, the simulation of groundwater level and contaminant mass concentration delivered very good calibration and validation results in all cases, quite close to the desired values. Maps of aquifer water level and contaminant mass concentrations are provided for all cases in order the differences to be discussed and assessed. The selection of the appropriate model(s) is case oriented and it should be based on the problem's characteristics in order the spatiotemporal variability of the components under study to be optimally estimated.

  14. Estimation of water table level and nitrate pollution based on geostatistical and multiple mass transport models

    NASA Astrophysics Data System (ADS)

    Matiatos, Ioannis; Varouhakis, Emmanouil A.; Papadopoulou, Maria P.

    2015-04-01

    As the sustainable use of groundwater resources is a great challenge for many countries in the world, groundwater modeling has become a very useful and well established tool for studying groundwater management problems. Based on various methods used to numerically solve algebraic equations representing groundwater flow and contaminant mass transport, numerical models are mainly divided into Finite Difference-based and Finite Element-based models. The present study aims at evaluating the performance of a finite difference-based (MODFLOW-MT3DMS), a finite element-based (FEFLOW) and a hybrid finite element and finite difference (Princeton Transport Code-PTC) groundwater numerical models simulating groundwater flow and nitrate mass transport in the alluvial aquifer of Trizina region in NE Peloponnese, Greece. The calibration of groundwater flow in all models was performed using groundwater hydraulic head data from seven stress periods and the validation was based on a series of hydraulic head data for two stress periods in sufficient numbers of observation locations. The same periods were used for the calibration of nitrate mass transport. The calibration and validation of the three models revealed that the simulated values of hydraulic heads and nitrate mass concentrations coincide well with the observed ones. The models' performance was assessed by performing a statistical analysis of these different types of numerical algorithms. A number of metrics, such as Mean Absolute Error (MAE), Root Mean Square Error (RMSE), Bias, Nash Sutcliffe Model Efficiency (NSE) and Reliability Index (RI) were used allowing the direct comparison of models' performance. Spatiotemporal Kriging (STRK) was also applied using separable and non-separable spatiotemporal variograms to predict water table level and nitrate concentration at each sampling station for two selected hydrological stress periods. The predictions were validated using the respective measured values. Maps of water table

  15. A micro-mapping strategy to investigate mechanical and chemical mass transport in migmatite

    NASA Astrophysics Data System (ADS)

    Lanari, Pierre; Riel, Nicolas

    2016-04-01

    Migmatites are fantastic objects to study both mechanical and chemical mass transport occurring at mm to cm-scale. However, migmatitic outcrops are the result of complex space and time interactions between (i) melt producing reactions, (ii) melt gain/loss and (iii) retrograde reactions. This succession of events is recorded in the minerals and microstructures of migmatites, and accounts for their apparent complexity. In order to explore the controlling parameters of these chemico-mechanical mass transport, it is thus necessary to characterize in great details the compositional changes between the different migmatitic domains, such as between leucosome and residuum. In this contribution we show how suitable local effective bulk (LEB) compositions can be derived by means of standardized microprobe X-ray images, using the program XMapTools. For chemically heterogeneous samples, such as migmatites, these LEB allow to forward model the stable mineral assemblages for each domain. Those thermodynamic models are used to investigate the conditions of leucosome-residuum separation. The studied sample is a metapelite embedded within a metasedimentary xenolith in the Marcabeli pluton, El Oro Complex, Ecuador. The sample exhibits complex mineral patterns due to local melt redistribution (at mm to cm-scale). Such physical mass transport involves major changes that affect the local chemical composition observed today. At the same time gradients in chemical potential can be established between adjacent domains such as residuum and leucosome, thus triggering chemical interaction. Diffusive transport between domains aims to reduce such chemical potential gradients. Along a modelled P-T path the chemical and mineralogical evolution of micro-domains can be reconstructed for (at least the reactive parts of) the crystallization history.

  16. Criteria for local equilibrium in a system with transport of heat and mass

    NASA Astrophysics Data System (ADS)

    Hafskjold, Bjørn; Ratkje, Signe Kjelstrup

    1995-01-01

    Nonequilibrium molecular dynamics is used to compute the coupled heat and mass transport in a binary isotope mixture of particles interacting with a Lennard-Jones/spline potential. Two different stationary states are studied, one with a fixed internal energy flux and zero mass flux, and the other with a fixed diffusive mass flux and zero temperature gradient. Computations are made for one overall temperature, T=2, and three overall number densities, n=0.1, 0.2, and 0.4. (All numerical values are given in reduced, Lennard-Jones units unless otherwise stated.) Temperature gradients are up to ∇ T=0.09 and weight-fraction gradients up to ∇ w 1=0.007. The flux-force relationships are found to be linear over the entire range. All four transport coefficients (the L-matrix) are determined and the Onsager reciprocal relationship for the off-diagonal coefficients is verified. Four different criteria are used to analyze the concept of local equilibrium in the nonequilibrium system. The local temperature fluctuation is found to be δ T≈0.03 T and of the same order as the maximum temperature difference across the control volume, except near the cold boundary. A comparison of the local potential energy, enthalpy, and pressure with the corresponding equilibrium values at the same temperature, density, and composition also verifies that local equilibrium is established, except near the boundaries of the system. The velocity contribution to the Boltzmann H-function agrees with its Maxwellian (equilibrium) value within 1%, except near the boundaries, where the deviation is up to 4%. Our results do not support the Eyring-type transport theory involving jumps across energy barriers; we find that its estimates for the heat and mass fluxes are wrong by at least one order of magnitude.

  17. Coupled porohyperelastic mass transport (PHEXPT) finite element models for soft tissues using ABAQUS.

    PubMed

    Vande Geest, Jonathan P; Simon, B R; Rigby, Paul H; Newberg, Tyler P

    2011-04-01

    Finite element models (FEMs) including characteristic large deformations in highly nonlinear materials (hyperelasticity and coupled diffusive/convective transport of neutral mobile species) will allow quantitative study of in vivo tissues. Such FEMs will provide basic understanding of normal and pathological tissue responses and lead to optimization of local drug delivery strategies. We present a coupled porohyperelastic mass transport (PHEXPT) finite element approach developed using a commercially available ABAQUS finite element software. The PHEXPT transient simulations are based on sequential solution of the porohyperelastic (PHE) and mass transport (XPT) problems where an Eulerian PHE FEM is coupled to a Lagrangian XPT FEM using a custom-written FORTRAN program. The PHEXPT theoretical background is derived in the context of porous media transport theory and extended to ABAQUS finite element formulations. The essential assumptions needed in order to use ABAQUS are clearly identified in the derivation. Representative benchmark finite element simulations are provided along with analytical solutions (when appropriate). These simulations demonstrate the differences in transient and steady state responses including finite deformations, total stress, fluid pressure, relative fluid, and mobile species flux. A detailed description of important model considerations (e.g., material property functions and jump discontinuities at material interfaces) is also presented in the context of finite deformations. The ABAQUS-based PHEXPT approach enables the use of the available ABAQUS capabilities (interactive FEM mesh generation, finite element libraries, nonlinear material laws, pre- and postprocessing, etc.). PHEXPT FEMs can be used to simulate the transport of a relatively large neutral species (negligible osmotic fluid flux) in highly deformable hydrated soft tissues and tissue-engineered materials.

  18. 1. Transport of Mass, Momentum and Energy in Planetary Magnetodisc Regions

    NASA Astrophysics Data System (ADS)

    Achilleos, Nicholas; André, Nicolas; Blanco-Cano, Xochitl; Brandt, Pontus C.; Delamere, Peter A.; Winglee, Robert

    2015-04-01

    The rapid rotation of the gas giant planets, Jupiter and Saturn, leads to the formation of magnetodisc regions in their magnetospheric environments. In these regions, relatively cold plasma is confined towards the equatorial regions, and the magnetic field generated by the azimuthal (ring) current adds to the planetary dipole, forming radially distended field lines near the equatorial plane. The ensuing force balance in the equatorial magnetodisc is strongly influenced by centrifugal stress and by the thermal pressure of hot ion populations, whose thermal energy is large compared to the magnitude of their centrifugal potential energy. The sources of plasma for the Jovian and Kronian magnetospheres are the respective satellites Io (a volcanic moon) and Enceladus (an icy moon). The plasma produced by these sources is globally transported outwards through the respective magnetosphere, and ultimately lost from the system. One of the most studied mechanisms for this transport is flux tube interchange, a plasma instability which displaces mass but does not displace magnetic flux—an important observational constraint for any transport process. Pressure anisotropy is likely to play a role in the loss of plasma from these magnetospheres. This is especially the case for the Jovian system, which can harbour strong parallel pressures at the equatorial segments of rotating, expanding flux tubes, leading to these regions becoming unstable, blowing open and releasing their plasma. Plasma mass loss is also associated with magnetic reconnection events in the magnetotail regions. In this overview, we summarise some important observational and theoretical concepts associated with the production and transport of plasma in giant planet magnetodiscs. We begin by considering aspects of force balance in these systems, and their coupling with the ionospheres of their parent planets. We then describe the role of the interaction between neutral and ionized species, and how it determines

  19. Mass and momentum turbulent transport experiments with confined swirling coaxial jets. I

    NASA Technical Reports Server (NTRS)

    Johnson, B. V.; Roback, R.

    1984-01-01

    An experimental study of mixing downstream of swirling coaxial jets discharging into an expanded duct was conducted to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the combustion community. A combination of laser velocimeter and laser induced fluorescence techniques was employed to obtain mean and fluctuating velocity and concentration distributions which were used to derive mass and momentum turbulent transport parameters currently incorporated into various combustor flow models. Flow visualization techniques were also employed to determine qualitatively the time dependent characteristics of the flow and the scale of turbulence. Mean and fluctuating velocity profiles and probability density functions were obtained at selected axial and radial locations throughout the flow field. Mixing occurred in several steps of axial and radial mass transport and was coupled with a large radial mean convective flux. Major mixing regions were observed to occur (1) at the interface between the inner stream and the centerline recirculation zone, and (2) at the interface between the inner jet and the annular jet streams. Mixing for swirling flow was completed in one-third the length required for nonswirling flow.

  20. Mass and momentum turbulent transport experiments with swirling confined coaxial jets. II

    NASA Technical Reports Server (NTRS)

    Roback, R.; Johnson, B. V.

    1986-01-01

    An experimental study of mixing downstream of swirling coaxial jets discharging into an expanded duct was conducted to obtain data for the evaluation and improvement of turbulent transport models currently used in a variety of computational procedures throughout the combustion community. A combination of laser velocimeter and laser induced fluorescence techniques was employed to obtain mean and fluctuating velocity and concentration distributions at selected axial and radial locations throughout the flow field. Flow visualization techniques were also employed to determine qualitatively the time dependent characteristics of the flow and the scale of turbulence. Simultaneous two component velocity and concentration/velocity measurements provided data which were used to determine the average momentum and mass transport rates for each of three measurement planes. Mixing for swirling flows occurred in several steps of axial and radial mean convective flow and was completed in one-third the length required for nonswirling flow. Comparison of the mass and momentum transport processes for swirling and nonswirling flows indicated that large differences existed in these processes between the two flows.

  1. Numerical advection by conservation of second-order moments. [for trace element spatial distribution and chemical interaction in atmosphere

    NASA Technical Reports Server (NTRS)

    Prather, M. J.

    1986-01-01

    A new, accurate, and nondiffusive method for three-dimensional advection of trace species is presented. The method preserves tracer structures by conserving the second-order moments of the spatial distribution of tracer during advection. Upstream transport and second-order tracer distribution are described, and the moments of the tracer distribution about the center of a grid box are formally defined and related to the polynomial distribution. Formulas are presented which describe how the moments of a grid box are decomposed into a unique set of moments centered about each subbox and how they are reassembled into new grid boxes. A one-dimensional example if tracer transport is given, and limits necessary to maintain positive tracer concentrations are derived. The accuracy and stability of this method are analytically examined, and numerical experiments testing the effective resolution are presented. The method is compared with other methods for numerical advection of tracers.

  2. Mass-corrections for the conservative coupling of flow and transport on collocated meshes

    SciTech Connect

    Waluga, Christian; Wohlmuth, Barbara; Rüde, Ulrich

    2016-01-15

    Buoyancy-driven flow models demand a careful treatment of the mass-balance equation to avoid spurious source and sink terms in the non-linear coupling between flow and transport. In the context of finite-elements, it is therefore commonly proposed to employ sufficiently rich pressure spaces, containing piecewise constant shape functions to obtain local or even strong mass-conservation. In three-dimensional computations, this usually requires nonconforming approaches, special meshes or higher order velocities, which make these schemes prohibitively expensive for some applications and complicate the implementation into legacy code. In this paper, we therefore propose a lean and conservatively coupled scheme based on standard stabilized linear equal-order finite elements for the Stokes part and vertex-centered finite volumes for the energy equation. We show that in a weak mass-balance it is possible to recover exact conservation properties by a local flux-correction which can be computed efficiently on the control volume boundaries of the transport mesh. We discuss implementation aspects and demonstrate the effectiveness of the flux-correction by different two- and three-dimensional examples which are motivated by geophysical applications.

  3. Biofilm dynamics characterization using a novel DO-MEA sensor: mass transport and biokinetics.

    PubMed

    Guimerà, Xavier; Moya, Ana; Dorado, Antonio David; Villa, Rosa; Gabriel, David; Gabriel, Gemma; Gamisans, Xavier

    2015-01-01

    Biodegradation process modeling is an essential tool for the optimization of biotechnologies related to gaseous pollutant treatment. In these technologies, the predominant role of biofilm, particularly under conditions of no mass transfer limitations, results in a need to determine what processes are occurring within the same. By measuring the interior of the biofilms, an increased knowledge of mass transport and biodegradation processes may be attained. This information is useful in order to develop more reliable models that take biofilm heterogeneity into account. In this study, a new methodology, based on a novel dissolved oxygen (DO) and mass transport microelectronic array (MEA) sensor, is presented in order to characterize a biofilm. Utilizing the MEA sensor, designed to obtain DO and diffusivity profiles with a single measurement, it was possible to obtain distributions of oxygen diffusivity and biokinetic parameters along a biofilm grown in a flat plate bioreactor (FPB). The results obtained for oxygen diffusivity, estimated from oxygenation profiles and direct measurements, revealed that changes in its distribution were reduced when increasing the liquid flow rate. It was also possible to observe the effect of biofilm heterogeneity through biokinetic parameters, estimated using the DO profiles. Biokinetic parameters, including maximum specific growth rate, the Monod half-saturation coefficient of oxygen, and the maintenance coefficient for oxygen which showed a marked variation across the biofilm, suggest that a tool that considers the heterogeneity of biofilms is essential for the optimization of biotechnologies.

  4. Mass-corrections for the conservative coupling of flow and transport on collocated meshes

    NASA Astrophysics Data System (ADS)

    Waluga, Christian; Wohlmuth, Barbara; Rüde, Ulrich

    2016-01-01

    Buoyancy-driven flow models demand a careful treatment of the mass-balance equation to avoid spurious source and sink terms in the non-linear coupling between flow and transport. In the context of finite-elements, it is therefore commonly proposed to employ sufficiently rich pressure spaces, containing piecewise constant shape functions to obtain local or even strong mass-conservation. In three-dimensional computations, this usually requires nonconforming approaches, special meshes or higher order velocities, which make these schemes prohibitively expensive for some applications and complicate the implementation into legacy code. In this paper, we therefore propose a lean and conservatively coupled scheme based on standard stabilized linear equal-order finite elements for the Stokes part and vertex-centered finite volumes for the energy equation. We show that in a weak mass-balance it is possible to recover exact conservation properties by a local flux-correction which can be computed efficiently on the control volume boundaries of the transport mesh. We discuss implementation aspects and demonstrate the effectiveness of the flux-correction by different two- and three-dimensional examples which are motivated by geophysical applications.

  5. Investigation of the influence of groundwater advection on energy extraction rates for sustainable borehole heat exchanger operation

    NASA Astrophysics Data System (ADS)

    Schelenz, Sophie; Dietrich, Peter; Vienken, Thomas

    2016-04-01

    A sustainable thermal exploitation of the shallow subsurface requires a precise understanding of all relevant heat transport processes. Currently, planning practice of shallow geothermal systems (especially for systems < 30 kW) focuses on conductive heat transport as the main energy source while the impact of groundwater flow as the driver for advective heat transport is neglected or strongly simplified. The presented study proves that those simplifications of complex geological and hydrogeological subsurface characteristics are insufficient for a precise evaluation of site-specific energy extraction rates. Based on synthetic model scenarios with varying subsurface conditions (groundwater flow velocity and aquifer thickness) the impact of advection on induced long term temperature changes in 5 and 10 m distance of the borehole heat exchanger is presented. Extending known investigations, this study enhances the evaluation of shallow geothermal energy extraction rates by considering conductive and advective heat transport under varying aquifer thicknesses. Further, it evaluates the impact of advection on installation lengths of the borehole heat exchanger to optimize the initial financial investment. Finally, an evaluation approach is presented that classifies relevant heat transport processes according to their Péclet number to enable a first quantitative assessment of the subsurface energy regime and recommend further investigation and planning procedures.

  6. Oligomers modulate interfibril branching and mass transport properties of collagen matrices.

    PubMed

    Whittington, Catherine F; Brandner, Eric; Teo, Ka Yaw; Han, Bumsoo; Nauman, Eric; Voytik-Harbin, Sherry L

    2013-10-01

    Mass transport within collagen-based matrices is critical to tissue development, repair, and pathogenesis, as well as the design of next-generation tissue engineering strategies. This work shows how collagen precursors, specified by intermolecular cross-link composition, provide independent control of collagen matrix mechanical and transport properties. Collagen matrices were prepared from tissue-extracted monomers or oligomers. Viscoelastic behavior was measured in oscillatory shear and unconfined compression. Matrix permeability and diffusivity were measured using gravity-driven permeametry and integrated optical imaging, respectively. Both collagen types showed an increase in stiffness and permeability hindrance with increasing collagen concentration (fibril density); however, different physical property–concentration relationships were noted. Diffusivity was not affected by concentration for either collagen type over the range tested. In general, oligomer matrices exhibited a substantial increase in stiffness and only a modest decrease in transport properties when compared with monomer matrices prepared at the same concentration. The observed differences in viscoelastic and transport properties were largely attributed to increased levels of interfibril branching within oligomer matrices. The ability to relate physical properties to relevant microstructure parameters, including fibril density and interfibril branching, is expected to advance the understanding of cell–matrix signaling, as well as facilitate model-based prediction and design of matrix-based therapeutic strategies.

  7. Resistance of Citrus Fruit to Mass Transport of Water Vapor and Other Gases 1

    PubMed Central

    Ben-Yehoshua, Shimshon; Burg, Stanley P.; Young, Roger

    1985-01-01

    The resistance of oranges (Citrus sinensis L. Osbeck) and grapefruit (Citrus paradisi Macf.) to ethylene, O2, CO2, and H2O mass transport was investigated anatomically with scanning electron microscope and physiologically by gas exchange measurements at steady state. The resistance of untreated fruit to water vapor is far less than to ethylene, CO2 and O2. Waxing partially or completely plugs stomatal pores and forms an intermittent cracked layer over the surface of fruit, restricting transport of ethylene, O2, and CO2, but not of water; whereas individual sealing of fruit with high density polyethylene films reduces water transport by 90% without substantially inhibiting gas exchange. Stomata of harvested citrus fruits are essentially closed. However, ethylene, O2 and CO2 still diffuse mainly through the residual stomatal opening where the relative transport resistance (approximately 6,000 seconds per centimeter) depends on the relative diffusivity of each gas in air. Water moves preferentially by a different pathway, probably through a liquid aqueous phase in the cuticle where water conductance is 60-fold greater. Other gases are constrained from using this pathway because their diffusivity in liquid water is 104-fold less than in air. Images Fig. 1 Fig. 2 Fig. 3 Fig. 4 Fig. 5 PMID:16664527

  8. Dynamo magnetic field-induced angular momentum transport in protostellar nebulae - The 'minimum mass' protosolar nebula

    NASA Technical Reports Server (NTRS)

    Stepinski, T. F.; Levy, E. H.

    1990-01-01

    Magnetic torques can produce angular momentum redistribution in protostellar nebulas. Dynamo magnetic fields can be generated in differentially rotating and turbulent nebulas and can be the source of magnetic torques that transfer angular momentum from a protostar to a disk, as well as redistribute angular momentum within a disk. A magnetic field strength of 100-1000 G is needed to transport the major part of a protostar's angular momentum into a surrounding disk in a time characteristic of star formation, thus allowing formation of a solar-system size protoplanetary nebula in the usual 'minimum-mass' model of the protosolar nebula. This paper examines the possibility that a dynamo magnetic field could have induced the needed angular momentum transport from the proto-Sun to the protoplanetary nebula.

  9. Mass balance method for estimating transcapillary protein transport in an extremity

    SciTech Connect

    Friedman, J.J.; Hing, C.T.

    1985-03-01

    A clinical procedure for applying the mass balance method to estimate transcapillary protein transport was compared with the experimental procedure of direct tissue monitoring of the rate of /sup 125/I- albumin accumulation in the dog hindlimb under conditions of venous pressure (Pv) elevation, norepinephrine infusion, and hemorrhagic hypotension. Over a wide range of venous protein flux (0.2 to 4.6 mg/min x 100 gm), the two estimates correlated well. The correlation coefficients were 0.987, 0.962, and 0.993 for Pv elevation in the control state, during norepinephrine infusion, and following hemorrhage, respectively. Since the clinical format requires only estimates of tissue blood flow, the change in tissue volume, and the change in protein concentration easily obtained with strain gauge plethysmography and venous blood sampling, it represents a relatively innocuous procedure for estimating protein transport which should be suitable for clinical application.

  10. Comparison of Flamelet Models with the Transported Mass Fraction Approach for Supersonic Combustion

    NASA Astrophysics Data System (ADS)

    Li, Wenhai; Alabi, Ken; Ladeinde, Foluso

    2015-11-01

    In this study, two fully compressible RANS, LES, and combined RANS/LES flow solvers - AEROFLO and VULCAN, both of which were originally developed by the United States Department of Defense but have since been significantly enhanced and commercialized by our organization, are used to investigate the accuracy of flamelet-based approach when employed to model supersonic combustion. The flamelet results from both codes are assessed relative to solutions obtained by solving the transport equations for the mass fractions - which is also supported by one of the codes, and making familiar assumptions about the closure of the reaction rate. The studies are carried out in the flamelet regime, and the numerical procedures are based on high-order schemes, which are also used to solve the level-set and mixture fraction transport equations used to study, respectively, premixed and non-premixed combustion. The effects of supersonic Mach numbers on the results are discussed.

  11. Mass transport and crystal growth of the mixed ZrS2-ZrSe2 system

    NASA Technical Reports Server (NTRS)

    Wiedemeier, Heribert; Goldman, Howard

    1986-01-01

    The solid solubility of the ZrS2-ZrSe2 system was reinvestigated by annealing techniques to establish the relationship between composition and lattice parameters. Mixed crystals of ZrS(2x)Se2(1-x) for selected compositions of the source material were grown by chemical vapor transport and characterized by X-ray diffraction and microscopic methods. The mass transport rates and crystal growth of ZrSSe were investigated and compared with those of other compositions. The mass fluxes of the mixed system showed an increase with increasing selenium content. The transport products were richer in ZrSe2 than the residual source materials when the ZrSe2 content of the starting materials was greater than 50 mol.-pct. The mass transport rates revealed an increasing mass flux with pressure.

  12. Neutrino Transport in Black Hole-Neutron Star Binaries: Dynamical Mass Ejection and Neutrino-Driven Wind

    NASA Astrophysics Data System (ADS)

    Kyutoku, K.; Kiuchi, K.; Sekiguchi, Y.; Shibata, M.; Taniguchi, K.

    2016-10-01

    We present our recent results of numerical-relativity simulations of black hole-neutron star binary mergers incorporating approximate neutrino transport. We in particular discuss dynamical mass ejection and neutrino-driven wind.

  13. A mercury transport and fate model (LM2-mercury) for mass budget assessment of mercury cycling in Lake Michigan

    EPA Science Inventory

    LM2-Mercury, a mercury mass balance model, was developed to simulate and evaluate the transport, fate, and biogeochemical transformations of mercury in Lake Michigan. The model simulates total suspended solids (TSS), disolved organic carbon (DOC), and total, elemental, divalent, ...

  14. A tracer-based inversion method for diagnosing eddy-induced diffusivity and advection

    NASA Astrophysics Data System (ADS)

    Bachman, S. D.; Fox-Kemper, B.; Bryan, F. O.

    2015-02-01

    A diagnosis method is presented which inverts a set of tracer flux statistics into an eddy-induced transport intended to apply for all tracers. The underlying assumption is that a linear flux-gradient relationship describes eddy-induced tracer transport, but a full tensor coefficient is assumed rather than a scalar coefficient which allows for down-gradient and skew transports. Thus, Lagrangian advection and anisotropic diffusion not necessarily aligned with the tracer gradient can be diagnosed. In this method, multiple passive tracers are initialized in an eddy-resolving flow simulation. Their spatially-averaged gradients form a matrix, where the gradient of each tracer is assumed to satisfy an identical flux-gradient relationship. The resulting linear system, which is overdetermined when using more than three tracers, is then solved to obtain an eddy transport tensor R which describes the eddy advection (antisymmetric part of R) and potentially anisotropic diffusion (symmetric part of R) in terms of coarse-grained variables. The mathematical basis for this inversion method is presented here, along with practical guidelines for its implementation. We present recommendations for initialization of the passive tracers, maintaining the required misalignment of the tracer gradients, correcting for nonconservative effects, and quantifying the error in the diagnosed transport tensor. A method is proposed to find unique, tracer-independent, distinct rotational and divergent Lagrangian transport operators, but the results indicate that these operators are not meaningfully relatable to tracer-independent eddy advection or diffusion. With the optimal method of diagnosis, the diagnosed transport tensor is capable of predicting the fluxes of other tracers that are withheld from the diagnosis, including even active tracers such as buoyancy, such that relative errors of 14% or less are found.

  15. Evaluation and optimization of mass transport of redox species in silicon microwire-array photoelectrodes

    PubMed Central

    Xiang, Chengxiang; Meng, Andrew C.; Lewis, Nathan S.

    2012-01-01

    Physical integration of a Ag electrical contact internally into a metal/substrate/microstructured Si wire array/oxide/Ag/electrolyte photoelectrochemical solar cell has produced structures that display relatively low ohmic resistance losses, as well as highly efficient mass transport of redox species in the absence of forced convection. Even with front-side illumination, such wire-array based photoelectrochemical solar cells do not require a transparent conducting oxide top contact. In contact with a test electrolyte that contained 50 mM/5.0 mM of the cobaltocenium+/0 redox species in CH3CN–1.0 M LiClO4, when the counterelectrode was placed in the solution and separated from the photoelectrode, mass transport restrictions of redox species in the internal volume of the Si wire array photoelectrode produced low fill factors and limited the obtainable current densities to 17.6 mA cm-2 even under high illumination. In contrast, when the physically integrated internal Ag film served as the counter electrode, the redox couple species were regenerated inside the internal volume of the photoelectrode, especially in regions where depletion of the redox species due to mass transport limitations would have otherwise occurred. This behavior allowed the integrated assembly to operate as a two-terminal, stand-alone, photoelectrochemical solar cell. The current density vs. voltage behavior of the integrated photoelectrochemical solar cell produced short-circuit current densities in excess of 80 mA cm-2 at high light intensities, and resulted in relatively low losses due to concentration overpotentials at 1 Sun illumination. The integrated wire array-based device architecture also provides design guidance for tandem photoelectrochemical cells for solar-driven water splitting. PMID:22904185

  16. Evaluation and optimization of mass transport of redox species in silicon microwire-array photoelectrodes.

    PubMed

    Xiang, Chengxiang; Meng, Andrew C; Lewis, Nathan S

    2012-09-25

    Physical integration of a Ag electrical contact internally into a metal/substrate/microstructured Si wire array/oxide/Ag/electrolyte photoelectrochemical solar cell has produced structures that display relatively low ohmic resistance losses, as well as highly efficient mass transport of redox species in the absence of forced convection. Even with front-side illumination, such wire-array based photoelectrochemical solar cells do not require a transparent conducting oxide top contact. In contact with a test electrolyte that contained 50 mM/5.0 mM of the cobaltocenium(+/0) redox species in CH(3)CN-1.0 M LiClO(4), when the counterelectrode was placed in the solution and separated from the photoelectrode, mass transport restrictions of redox species in the internal volume of the Si wire array photoelectrode produced low fill factors and limited the obtainable current densities to 17.6 mA cm(-2) even under high illumination. In contrast, when the physically integrated internal Ag film served as the counter electrode, the redox couple species were regenerated inside the internal volume of the photoelectrode, especially in regions where depletion of the redox species due to mass transport limitations would have otherwise occurred. This behavior allowed the integrated assembly to operate as a two-terminal, stand-alone, photoelectrochemical solar cell. The current density vs. voltage behavior of the integrated photoelectrochemical solar cell produced short-circuit current densities in excess of 80 mA cm(-2) at high light intensities, and resulted in relatively low losses due to concentration overpotentials at 1 Sun illumination. The integrated wire array-based device architecture also provides design guidance for tandem photoelectrochemical cells for solar-driven water splitting.

  17. CONVERGENCE STUDIES OF MASS TRANSPORT IN DISKS WITH GRAVITATIONAL INSTABILITIES. II. THE RADIATIVE COOLING CASE

    SciTech Connect

    Steiman-Cameron, Thomas Y.; Durisen, Richard H.; Michael, Scott; McConnell, Caitlin R.; Boley, Aaron C. E-mail: durisen@astro.indiana.edu E-mail: carmccon@indiana.edu

    2013-05-10

    We conduct a convergence study of a protoplanetary disk subject to gravitational instabilities (GIs) at a time of approximate balance between heating produced by the GIs and radiative cooling governed by realistic dust opacities. We examine cooling times, characterize GI-driven spiral waves and their resultant gravitational torques, and evaluate how accurately mass transport can be represented by an {alpha}-disk formulation. Four simulations, identical except for azimuthal resolution, are conducted with a grid-based three-dimensional hydrodynamics code. There are two regions in which behaviors differ as resolution increases. The inner region, which contains 75% of the disk mass and is optically thick, has long cooling times and is well converged in terms of various measures of structure and mass transport for the three highest resolutions. The longest cooling times coincide with radii where the Toomre Q has its minimum value. Torques are dominated in this region by two- and three-armed spirals. The effective {alpha} arising from gravitational stresses is typically a few Multiplication-Sign 10{sup -3} and is only roughly consistent with local balance of heating and cooling when time-averaged over many dynamic times and a wide range of radii. On the other hand, the outer disk region, which is mostly optically thin, has relatively short cooling times and does not show convergence as resolution increases. Treatment of unstable disks with optical depths near unity with realistic radiative transport is a difficult numerical problem requiring further study. We discuss possible implications of our results for numerical convergence of fragmentation criteria in disk simulations.

  18. Angular momentum transport efficiency in post-main sequence low-mass stars

    NASA Astrophysics Data System (ADS)

    Spada, F.; Gellert, M.; Arlt, R.; Deheuvels, S.

    2016-05-01

    Context. Using asteroseismic techniques, it has recently become possible to probe the internal rotation profile of low-mass (≈1.1-1.5 M⊙) subgiant and red giant stars. Under the assumption of local angular momentum conservation, the core contraction and envelope expansion occurring at the end of the main sequence would result in a much larger internal differential rotation than observed. This suggests that angular momentum redistribution must be taking place in the interior of these stars. Aims: We investigate the physical nature of the angular momentum redistribution mechanisms operating in stellar interiors by constraining the efficiency of post-main sequence rotational coupling. Methods: We model the rotational evolution of a 1.25M⊙ star using the Yale Rotational stellar Evolution Code. Our models take into account the magnetic wind braking occurring at the surface of the star and the angular momentum transport in the interior, with an efficiency dependent on the degree of internal differential rotation. Results: We find that models including a dependence of the angular momentum transport efficiency on the radial rotational shear reproduce very well the observations. The best fit of the data is obtained with an angular momentum transport coefficient scaling with the ratio of the rotation rate of the radiative interior over that of the convective envelope of the star as a power law of exponent ≈3. This scaling is consistent with the predictions of recent numerical simulations of the Azimuthal Magneto-Rotational Instability. Conclusions: We show that an angular momentum transport process whose efficiency varies during the stellar evolution through a dependence on the level of internal differential rotation is required to explain the observed post-main sequence rotational evolution of low-mass stars.

  19. Observation of graphene bubbles and effective mass transport under graphene films.

    PubMed

    Stolyarova, E; Stolyarov, D; Bolotin, K; Ryu, S; Liu, L; Rim, K T; Klima, M; Hybertsen, M; Pogorelsky, I; Pavlishin, I; Kusche, K; Hone, J; Kim, P; Stormer, H L; Yakimenko, V; Flynn, G

    2009-01-01

    Mechanically exfoliated graphene mounted on a SiO2/Si substrate was subjected to HF/H(2)O etching or irradiation by energetic protons. In both cases gas was released from the SiO2 and accumulated at the graphene/SiO2 interface resulting in the formation of "bubbles" in the graphene sheet. Formation of these "bubbles" demonstrates the robust nature of single layer graphene membranes, which are capable of containing mesoscopic volumes of gas. In addition, effective mass transport at the graphene/SiO2 interface has been observed.

  20. Gradual conditioning of non-Gaussian transmissivity fields to flow and mass transport data: 1. Theory

    NASA Astrophysics Data System (ADS)

    Capilla, José E.; Llopis-Albert, Carlos

    2009-06-01

    SummaryThe paper presents a new stochastic inverse method for the simulation of transmissivity ( T) fields conditional to T measurements, secondary information obtained from expert judgement and geophysical surveys, transient piezometric and solute concentration measurements, and travel time data. The formulation of the method is simple and derived from the gradual deformation method. It basically consists of an iterative optimization procedure in which successive combinations of T fields, that honour T measurements and soft data (secondary data obtained from expert judgement and/or geophysical surveys), gradually lead to a simulated T field conditional to flow and mass transport data. Every combination of fields requires minimizing a penalty function that penalizes the difference between computed and measured conditioning data. This penalty function depends on only one parameter. Travel time conditioning data are considered by means of a backward-in-time probabilistic model, which extends the potential applications of the method to the characterization of groundwater contamination sources. In order to solve the mass transport equation, the method implements a Lagrangian approach that allows avoiding numerical problems usually found in Eulerian methods. Besides, to deal with highly heterogeneous and non-Gaussian media, being able to reproduce anomalous breakthrough curves, a dual-domain approach is implemented with a first-order mass transfer approach. To determine the particle distribution between the mobile domain and the immobile domain the method uses a Bernoulli trial on the appropriate phase transition probabilities, derived using the normalized zeroth spatial moments of the multirate transport equations. The presented method does not require assuming the classical multiGaussian hypothesis thus easing the reproduction of T spatial patterns where extreme values of T show high connectivity. This feature allows the reproduction of a property found in real

  1. A First Principles Study of Mass Transport in the Dehydrogenation of Lithium Amides and Lithium Alanates

    NASA Astrophysics Data System (ADS)

    Rolih, Biljana

    The pursuit of competitive alternatives to energy derived from the combustion of fossil fuels, has led to a great variety of new technologies. Exceptional develop- ments in electrochemical storage and production promise to lead to clean burning passenger vehicles. The high chemical density of a hydrogen fuel cell enables it to meet current standards for driving range and weight required of vehicles, making it an excellent candidate for universal application in the automotive industry. One of the biggest obstacles the fuel cell industry has yet to overcome is the means of practical hydrogen storage. Solid state metal hydrides are a class of materials that show potential for both economic and practical hydrogen storage. The search for the ideal metal hydride is defined by thermodynamic and kinetic constraints, since the requirements for a viable system are a rapid release of hydrogen in the temperature range of -40°C, to 80°C. First-principles density functional theory is an excellent method for gaining insight into the kinetics and thermodynamics of metal hydride solid state reactions. In the work presented here, density functional theory is used to explore formation energies, concentrations and migration barriers of metal hydrides. In particular, the following systems were analyzed: • Li - N - H It is well known that the reactive hydride composite LiNH 2 + LiH reversibly releases a large amount of hydrogen gas, with more favorable thermodynamics than LiNH2 alone. Kinetics of mass transport during the dehydrogenation of LiNH2 + LiH are investigated. A model is developed for determining activation energies of native defects in bulk crystals. In order to establish whether mass transport is the rate-limiting step in the dehydrogenation reaction, results are compared to experimental values. • Li - Al - H Kinetics of mass transport during the dehydrogenation of the metal hydride LiAlH2 are investigated. It is known that LiAlH4 endothermically decomposes via a two

  2. A finite-volume ELLAM for three-dimensional solute-transport modeling

    USGS Publications Warehouse

    Russell, T.F.; Heberton, C.I.; Konikow, L.F.; Hornberger, G.Z.

    2003-01-01

    A three-dimensional finite-volume ELLAM method has been developed, tested, and successfully implemented as part of the U.S. Geological Survey (USGS) MODFLOW-2000 ground water modeling package. It is included as a solver option for the Ground Water Transport process. The FVELLAM uses space-time finite volumes oriented along the streamlines of the flow field to solve an integral form of the solute-transport equation, thus combining local and global mass conservation with the advantages of Eulerian-Lagrangian characteristic methods. The USGS FVELLAM code simulates solute transport in flowing ground water for a single dissolved solute constituent and represents the processes of advective transport, hydrodynamic dispersion, mixing from fluid sources, retardation, and decay. Implicit time discretization of the dispersive and source/sink terms is combined with a Lagrangian treatment of advection, in which forward tracking moves mass to the new time level, distributing mass among destination cells using approximate indicator functions. This allows the use of large transport time increments (large Courant numbers) with accurate results, even for advection-dominated systems (large Peclet numbers). Four test cases, including comparisons with analytical solutions and benchmarking against other numerical codes, are presented that indicate that the FVELLAM can usually yield excellent results, even if relatively few transport time steps are used, although the quality of the results is problem-dependent.

  3. Mass estimating techniques for earth-to-orbit transports with various configuration factors and technologies applied

    NASA Technical Reports Server (NTRS)

    Klich, P. J.; Macconochie, I. O.

    1979-01-01

    A study of an array of advanced earth-to-orbit space transportation systems with a focus on mass properties and technology requirements is presented. Methods of estimating weights of these vehicles differ from those used for commercial and military aircraft; the new techniques emphasizing winged horizontal and vertical takeoff advanced systems are described utilizing the space shuttle subsystem data base for the weight estimating equations. The weight equations require information on mission profile, the structural materials, the thermal protection system, and the ascent propulsion system, allowing for the type of construction and various propellant tank shapes. The overall system weights are calculated using this information and incorporated into the Systems Engineering Mass Properties Computer Program.

  4. Conservative transport upscaling based on information of connectivity

    NASA Astrophysics Data System (ADS)

    Tyukhova, Alina R.; Willmann, Matthias

    2016-09-01

    Connected structures in highly heterogeneous hydraulic conductivity fields lead to channels and preferential pathways for the main fluid flux and fastest solute particles. Their spatial complement is zones of slow advection, where solutes are delayed, causing tailing of solute breakthrough curves. These delays depend on the inclusion's size and the hydraulic conductivity contrast between inclusion and channel. The interplay between channels and small-scale low conductivity inclusions leads to anomalous transport at larger scales. We test whether a simple separation of transport processes between channels and inclusions could be used to parameterize an effective transport model accounting for anomalous transport. Effective transport is represented by a multirate mass transfer model (MRMT): fast channel transport is controlled by parameters of the mobile zone, while slow advective delays are controlled by parameters of the mobile-immobile exchange. We delineate the connected channels and analyze their connectivity followed by characterizing the low conductivity inclusions. We parameterize a MRMT model using connectivity and the statistics of the low permeable inclusions. Finally, we compare the parameterized MRMT with detailed numerical simulations in heterogeneous hydraulic conductivity fields with a clear separation between connected channel network and inclusions. In intermediately connected hydraulic conductivity fields only the cut-off time of the tails is represented while early and intermediate time behavior is not reproduced. We suggest that an effective model for the latter case should account for additional processes like variability in advective velocity.

  5. Effects of Mass Fluctuation on Thermal Transport Properties in Bulk Bi2Te3

    NASA Astrophysics Data System (ADS)

    Huang, Ben; Zhai, Pengcheng; Yang, Xuqiu; Li, Guodong

    2016-10-01

    In this paper, we applied large-scale molecular dynamics and lattice dynamics to study the influence of mass fluctuation on thermal transport properties in bulk Bi2Te3, namely thermal conductivity (K), phonon density of state (PDOS), group velocity (v g), and mean free path (l). The results show that total atomic mass change can affect the relevant vibrational frequency on the micro level and heat transfer rate in the macro statistic, hence leading to the strength variation of the anharmonic phonon processes (Umklapp scattering) in the defect-free Bi2Te3 bulk. Moreover, it is interesting to find that the anharmonicity of Bi2Te3 can be also influenced by atomic differences of the structure such as the mass distribution in the primitive cell. Considering the asymmetry of the crystal structure and interatomic forces, it can be concluded by phonon frequency, lifetime, and velocity calculation that acoustic-optical phonon scattering shows the structure-sensitivity to the mass distribution and complicates the heat transfer mechanism, hence resulting in the low lattice thermal conductivity of Bi2Te3. This study is helpful for designing the material with tailored thermal conductivity via atomic substitution.

  6. Mass transport at the interface between a highly permeable porous medium and an open channel flow

    NASA Astrophysics Data System (ADS)

    Moretto, C.; Pokrajac, D.

    2012-04-01

    Hyporheic exchange has been extensively studied in the literature. The majority of papers present the results of field studies and the associated engineering simulation models. The number of laboratory studies is smaller. Most of them are focused on the bulk scale effects, since the measurements within the bed at the grain scale are difficult and therefore rare. Measurement within the pores of a permeable bed becomes possible for some idealized pore configurations. Pokrajac and Manes (2009) and Manes et al. (2009) use constant diameter spheres packed in a cubic pattern, which form straight pores (with variable cross-sectional area) in three orthogonal directions. Their results include detailed velocity measurements and the characteristics of turbulence at the fluid/porous interface, but not the mass transport. The experimental study reported here uses the same porous medium and extends this work by including grain-scale mass transport measurements. The results presented involve the hydrodynamics and the mass transport at the fluid/pore interface and within the first pore under the surface of the medium. The experiments are carried out in a 11m long and 40cm wide tilting flume. The porous medium, placed on the flume bed, is composed of 5 layers of 12mm diameter plastic spheres packed in a cubic pattern. This arrangement was chosen in order to have a regular matrix, thereby allowing measurements of the velocities and solute concentration within a pore. The measurement window covers a central section of a longitudinal pore which is visible through a lateral pore. The velocity field is measured by means of the Particle Image Velocimetry (PIV), and the concentration field is measured using the Laser Induced Fluorescence (LIF). These two techniques allow simultaneous non-intrusive measurements within a single pore. The experiments involved uniform, fully developed turbulent flow. The experimental conditions were: bed slope = 0.01, water depth = 45mm, depth

  7. Conditions and processes affecting radionuclide transport

    USGS Publications Warehouse

    Simmons, Ardyth M.; Neymark, Leonid A.

    2012-01-01

    Understanding of unsaturated-zone transport is based on laboratory and field-scale experiments. Fractures provide advective transport pathways. Sorption and matrix diffusion may contribute to retardation of radionuclides. Conversely, sorption onto mobile colloids may enhance radionuclide transport.

  8. A mass conserving and multi-tracer efficient transport scheme in the online integrated Enviro-HIRLAM model

    NASA Astrophysics Data System (ADS)

    Sørensen, B.; Kaas, E.; Korsholm, U. S.

    2012-11-01

    In this paper a new advection scheme for the online coupled chemical-weather prediction model Enviro-HIRLAM is presented. The new scheme is based on the locally mass conserving semi-Lagrangian method (LMCSL), where the original two-dimensional scheme has been extended to a fully three-dimensional version. This means that the three-dimensional semi-implicit semi-Lagrangian scheme which is currently used in Enviro-HIRLAM, is largely unchanged. The HIRLAM model is a computationally efficient hydrostatic operational short term numerical weather prediction model, which is used as the base for the online integrated Enviro-HIRLAM. The new scheme is shown to be efficient, mass conserving, and shape-preserving while only requiring minor alterations to the original code. It still retains the stability at long time steps, which the semi-Lagrangian schemes are known for, while handling the emissions of chemical species accurately. Several mass conserving filters have been tested to assess the optimal balance of accuracy vs. efficiency.

  9. A mass-conserving and multi-tracer efficient transport scheme in the online integrated Enviro-HIRLAM model

    NASA Astrophysics Data System (ADS)

    Sørensen, B.; Kaas, E.; Korsholm, U. S.

    2013-07-01

    In this paper a new advection scheme for the online coupled chemical-weather prediction model Enviro-HIRLAM is presented. The new scheme is based on the locally mass-conserving semi-Lagrangian method (LMCSL), where the original two-dimensional scheme has been extended to a fully three-dimensional version. This means that the three-dimensional semi-implicit semi-Lagrangian scheme which is currently used in Enviro-HIRLAM is largely unchanged. The HIRLAM model is a computationally efficient hydrostatic operational short-term numerical weather prediction model, which is used as the base for the online integrated Enviro-HIRLAM. The new scheme is shown to be efficient, mass conserving, and shape preserving, while only requiring minor alterations to the original code. It still retains the stability at long time steps, which the semi-Lagrangian schemes are known for, while handling the emissions of chemical species accurately. Several mass-conserving filters have been tested to assess the optimal balance of accuracy vs. efficiency.

  10. Coupled electrochemical and heat/mass transport characteristics in passive direct methanol fuel cells

    NASA Astrophysics Data System (ADS)

    Chen, Rong

    This thesis presents both experimental and theoretical investigations of coupled heat/mass transfer and electrochemical characteristics in the passive DMFC. Unlike active fuel cells, which can be operated under stabilized operating conditions, the discharging behavior of the passive DMFC usually varies with time, as the methanol concentration in the fuel reservoir decreases with time. This poses a difficulty in characterizing the performance of the passive DMFC under relatively stable operating conditions. In this work, we found that the performance of the passive DMFC became relatively stable as the cell operating temperature rose to a relatively stable value. This finding indicates that the performance of the passive DMFC can be characterized by collecting polarization data at the instance when the cell operating temperature under the open-circuit condition rises to a relatively stable value. With this proposed standard of passive DMFC performance characterization, the effects of two important parameters, including methanol concentration and cell orientation, on the passive DMFC performance were then investigated. It is found that the cell performance increased with methanol concentration. Unlike previous studies that attributed the improved performance as a result of increasing methanol concentration to the reduced anode mass transport polarization, our experimental results revealed that the improved cell performance was primarily due to the increased cell operating temperature as a result of the increased rate of methanol crossover with high methanol concentration operation. We also found that the performance was sensitive to the cell orientation. The vertical operation always yielded better performance than did the horizontal operation. This can be attributed to the increased operating temperature as a result of a higher rate of methanol crossover, which resulted from the stronger natural convection in the vertical orientation. These parametric studies

  11. Horizontal Advection and Mixing of Pollutants in the Urban Atmospheric Environment

    NASA Astrophysics Data System (ADS)

    Magnusson, S. P.; Entekhabi, D.; Britter, R.; Norford, L.; Fernando, H. J.

    2013-12-01

    Although urban air quality and its impacts on the public health have long been studied, the increasing urbanization is raising concerns on how to better control and mitigate these health impacts. A necessary element in predicting exposure levels is fundamental understanding of flow and dispersion in urban canyons. The complex topology of building structures and roads requires the resolution of turbulence phenomena within urban canyons. The use of dense and low porosity construction material can lead to rapid heating in response to direct solar exposure due to large thermal mass. Hence thermal and buoyancy effects may be as important as mechanically-forced or shear-induced flows. In this study, the transport of pollutants within the urban environment, as well as the thermal and advection effects, are investigated. The focus is on the horizontal transport or the advection effects within the urban environment. With increased urbanization and larger and more spread cities, concern about how the upstream air quality situation can affect downstream areas. The study also examines the release and the dispersion of hazardous material. Due to the variety and complexity of urban areas around the world, the urban environment is simplified into adjacent two-dimensional urban street canyons. Pollutants are released inside each canyon. Computational Fluid Dynamics (CFD) simulations are applied to evaluate and quantify the flow rate out of each canyon and also the exchange of pollutants between the canyons. Imagine a row of ten adjacent urban street canyons of aspect ratio 1 with horizontal flow perpendicular to it as shown in the attached figure. C is the concentration of pollutants. The first digit indicates in what canyon the pollutant is released and the second digit indicates the location of that pollutant. For example, C3,4 is the concentration of pollutant released inside canyon 3 measured in canyon 4. The same amount of pollution is released inside the ten street canyons

  12. The synergistic effect of ultrasound and chemical penetration enhancers on chorioamnion mass transport.

    PubMed

    Azagury, Aharon; Khoury, Luai; Adato, Yair; Wolloch, Lior; Ariel, Ilana; Hallak, Mordechai; Kost, Joseph

    2015-02-28

    In our previous study we proposed the use of chemical penetration enhancers for noninvasive detection of fetus abnormalities that can also be utilized for direct fetal drug delivery. In an attempt to further increase the mass transport rate across the amniotic membrane, thus shortening the procedure and improving the applicability of the proposed procedure, the effect and mechanism of combining ultrasound exposure with chemical penetration enhancers' application were assessed. The combined effect was evaluated in vitro on post-delivery human amniotic membrane and ex vivo on rat's whole amniotic sac. Ultrasound effect has been assessed by dye experiments using a customized image analysis program. Additional insights of ultrasound effect's mechanism on biological membranes are presented. Previously we have determined that chemical penetration enhancers affect the fetal membranes via two mechanisms termed as 'extractors' and 'fluidizers'. In this study, we found that combining ultrasound with a 'fluidizer' CPE (e.g. bupivacaine) results in a synergistic enhancement (90-fold) of fetal membrane's mass transport, while combining ultrasound with 'extractors' (e.g. ethanol and NMP) results in an antagonistic effect. The combined procedure is faster and gain greater accuracy than the applications of sole chemical penetration enhancers.

  13. Task 6.7.3 - Interfacial Mass Transport Effects in Composite Materials

    SciTech Connect

    Jan W. Nowok

    1998-02-01

    Advanced metal-matrix composites (MMCS) consisting of titanium-based alloys possess some unique mechanical, physical, and chemical characteristics that make them highly desirable for aircraft and gas turbine engines. Tailoring MMC properties is essential for advanced product design in materials processing. The main factors that affect materials processing and, further, the nature of a metal-ceramic interface, its structure, and morphological stability is liquid surface mass transport related to adhesional wetting (physical effect) and reactive wetting (chemical effect).' Surfaces and interfaces dominate many of the technologically important processes in composite materials such as liquid-solid sintering and joining. The objective of this work is threefold: 1) to get insight into the role of the nonstoichiometry of chemical composition in ceramic materials used as reinforcement components in MMC processing, 2) to extend previous energetic analysis of mass transport phenomena to wetting behavior between liquid metal and the quasi-solidlike skin resulting from the presolidification of liquid on nonstoichiometric solids on a scale of interatomic distance, and 3) to provide experimental verification of our concept.

  14. Task 6.7.3 - Interfacial Mass Transport Effects in Composite Materials

    SciTech Connect

    Jan W. Nowok

    1998-02-01

    Advanced metal-matrix composites (MMCS) consisting of titanium-based alloys possess some unique mechanical, physical, and chemical characteristics that make them highly desirable for aircraft and gas turbine engines. Tailoring MMC properties is essential for advanced product design in materials processing. The main factors that affect materials processing and, further, the nature of a metal-ceramic interface, its structure, and morphological stability is liquid surface mass transport related to adhesional wetting physical effect) and reactive wetting (chemical effect). Surfaces and interfaces dominate many of the technologically important processes in composite materials such as liquid-solid sintering and joining. The objective of this work is threefold: 1) to get insight into the role of the nonstoichiometry of chemical composition in ceramic materials used as reinforcement components in MMC processing, 2) to extend previous energetic analysis of mass transport phenomena to wetting behavior between liquid metal and the quasi-solid like skin resulting from the presolidification of liquid on nonstoichiometric solids on a scale of interatomic distance, and 3) to provide experimental verification of our concept.

  15. Numerical simulation on mass transport in a microchannel bioreactor for co-culture applications.

    PubMed

    Zeng, Yan; Lee, Thong-See; Yu, Peng; Low, Hong-Tong

    2007-06-01

    Microchannel bioreactors have applications for manipulating and investigating the fluid microenvironment on cell growth and functions in either single culture or co-culture. This study considers two different types of cells distributed randomly as a co-culture at the base of a microchannel bioreactor: absorption cells, which only consume species based on the Michaelis-Menten process, and release cells, which secrete species, assuming zeroth order reaction, to support the absorption cells. The species concentrations at the co-culture cell base are computed from a three-dimensional numerical flow-model incorporating mass transport. Combined dimensionless parameters are proposed for the co-culture system, developed from a simplified analysis under the condition of decreasing axial-concentration. The numerical results of species concentration at the co-culture cell-base are approximately correlated by the combined parameters under the condition of positive flux-parameter. Based on the correlated results, the critical value of the inlet concentration is determined, which depends on the effective microchannel length. For the flow to develop to the critical inlet concentration, an upstream length consisting only of release cells is needed; this upstream length is determined from an analytical solution. The generalized results may find applications in analyzing the mass transport requirements in a co-culture microchannel bioreactor.

  16. Facile synthesis of mesostructured ZSM-5 zeolite with enhanced mass transport and catalytic performances

    NASA Astrophysics Data System (ADS)

    Li, Chao; Ren, Yanqun; Gou, Jinsheng; Liu, Baoyu; Xi, Hongxia

    2017-01-01

    A mesostructured ZSM-5 zeolite with multilamellar structure was successfully synthesized by employing a tetra-headgroup rigid bolaform quaternary ammonium surfactant. It was characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), nitrogen adsorption/desorption isotherms, amines temperature programmed desorption (amines-TPD), and computer simulation. These results indicated that the dual-functional amphiphilic surfactants play a critical role for directing the multilamellar structure with high mesoporosity. The mass transport and catalytic performances of the zeolite were investigated by zero length column (ZLC) technique and aldol condensation reactions to evaluate the structure-property relationship. These results clearly indicated that the mass transport of selected molecules in hierarchical zeolite can be accelerated by introducing mesoporous structure with mesostructure with reduced diffusion length and an overall enhanced resistance against deactivation in reactions involving large molecules. Furthermore, the dual-functional surfactant approach of making hierarchical zeolite with MFI nanosheets framework would open up new opportunities for design and synthesis of hierarchical zeolites with controllable mesoporous structures.

  17. Particulate export vs lateral advection in the Antarctic Polar Front (Southern Pacific Ocean)

    NASA Astrophysics Data System (ADS)

    Tesi, T.; Langone, L.; Ravaioli, M.; Capotondi, L.; Giglio, F.

    2012-04-01

    The overarching goal of our study was to describe and quantify the influence of lateral advection relative to the vertical export in the Antarctic Polar Front (Southern Pacific Ocean). In areas where lateral advection of particulate material is significant, budgets of bioactive elements can be inaccurate if fluxes through the water column and to the seabed are exclusively interpreted as passive sinking of particles. However, detailed information on the influence of lateral advection in the water column in the southern ocean is lacking. With this in mind, our study focused between the twilight zone (i.e. mesopelagic) and the benthic nepheloid layer to understand the relative importance of lateral flux with increasing water depth. Measurements were performed south of the Antarctic Polar Front for 1 year (January 10th 1999-January 3rd 2000) at 900, 1300, 2400, and 3700 m from the sea surface. The study was carried out using a 3.5 km long mooring line instrumented with sediment traps, current meters and sensors of temperature and conductivity. Sediment trap samples were characterized via several parameters including total mass flux, elemental composition (organic carbon, total nitrogen, biogenic silica, and calcium carbonate), concentration of metals (aluminum, iron, barium, and manganese), 210Pb activity, and foraminifera taxonomy. High fluxes of biogenic particles were observed in both summer 1999 and 2000 as a result of seasonal algal blooms associated with sea ice retreat and water column stratification. During no-productive periods, several high energy events occurred and resulted in advecting resuspended biogenic particles from flat-topped summits of the Pacific Antarctic Ridge. Whereas the distance between seabed and uppermost sediment traps was sufficient to avoid lateral advection processes, resuspension was significant in the lowermost sediment traps accounting for ~60 and ~90% of the material caught at 2400 and 3700 m, respectively. Samples collected during

  18. Advective removal of intraparticle uranium from contaminated vadose zone sediments, Hanford, U.S.

    PubMed

    Ilton, Eugene S; Qafoku, Nikolla P; Liu, Chongxuan; Moore, Dean A; Zachara, John M

    2008-03-01

    A column study on U(VI)-contaminated vadose zone sediments from the Hanford Site, WA, was performed to investigate U(VI) release kinetics with water advection and variable geochemical conditions. The sediments were collected from an area adjacent to and below tank BX-102 that was contaminated as a result of a radioactive tank waste overfill event. The primary reservoir for U(VI) in the sediments are micrometer-size precipitates composed of nanocrystallite aggregates of a Na-U-Silicate phase, most likely Na-boltwoodite, that nucleated and grew within microfractures of the plagioclase component of sand-sized granitic clasts. Two sediment samples, with different U(VI) concentrations and intraparticle mass transfer properties, were leached with advective flows of three different solutions. The influent solutions were all calcite-saturated and in equilibrium with atmospheric CO2. One solution was prepared from DI water, the second was a synthetic groundwater (SGW) with elevated Na that mimicked groundwater at the Hanford site, and the third was the same SGW but with both elevated Na and Si. The latter two solutions were employed, in part, to test the effect of saturation state on U(VI) release. For both sediments, and all three electrolytes, there was an initial rapid release of U(VI) to the advecting solution followed by slower near steady-state release. U(VI)aq concentrations increased during subsequent stop-flow events. The electrolytes with elevated Na and Si depressed U(VL)aq concentrations in effluent solutions. Effluent U(VI)aq concentrations for both sediments and all three electrolytes were simulated reasonably well by a three domain model (the advecting fluid, fractures, and matrix) that coupled U(VI) dissolution, intraparticle U(VI)aq diffusion, and interparticle advection, where diffusion and dissolution properties were parameterized in a previous batch study.

  19. A heuristic simulation model of Lake Ontario circulation and mass balance transport

    USGS Publications Warehouse

    McKenna, J.E.; Chalupnicki, M.A.

    2011-01-01

    The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.

  20. Solvent-Induced Crystallization in Poly(Ethylene Terephthalate) during Mass Transport

    NASA Astrophysics Data System (ADS)

    Ouyang, Hao

    2001-03-01

    The solvent transport in poly(ethylene terephthalate) (PET) and related phase transformation were investigated. The data of mass sorption were analyzed according to Harmon¡¦s model for Case I (Fickian), Case II (swelling) and anomalous transport. This transport process in PET is accompanied by the induced crystallization of the original amorphous state. The transformation was studied by wide angle x-ray scattering (WAXS), small angle x-ray scattering (SAXS), Differential Scanning Calorimeter (DSC), density gradient column, and Fourier Transform Infra-Red (FTIR). During this process, the matrix is under a compressive strain that causes different kinetic path of crystallization as compared to that by thermal annealing. This state of strain will assist the development of the solvent-induced crystallization. It also can be explained in terms of the principle of Le Chatelier if the local equilibrium is assumed. The model regarding the crystallization was proposed in terms of the study of long period L, the crystal thickness lc and the thickness of amorphous layer la, obtained from the linear correlation function and interface distribution function.

  1. A Petroleum Vapor Intrusion Model Involving Upward Advective Soil Gas Flow Due to Methane Generation.

    PubMed

    Yao, Yijun; Wu, Yun; Wang, Yue; Verginelli, Iason; Zeng, Tian; Suuberg, Eric M; Jiang, Lin; Wen, Yuezhong; Ma, Jie

    2015-10-06

    At petroleum vapor intrusion (PVI) sites at which there is significant methane generation, upward advective soil gas transport may be observed. To evaluate the health and explosion risks that may exist under such scenarios, a one-dimensional analytical model describing these processes is introduced in this study. This new model accounts for both advective and diffusive transport in soil gas and couples this with a piecewise first-order aerobic biodegradation model, limited by oxygen availability. The predicted results from the new model are shown to be in good agreement with the simulation results obtained from a three-dimensional numerical model. These results suggest that this analytical model is suitable for describing cases involving open ground surface beyond the foundation edge, serving as the primary oxygen source. This new analytical model indicates that the major contribution of upward advection to indoor air concentration could be limited to the increase of soil gas entry rate, since the oxygen in soil might already be depleted owing to the associated high methane source vapor concentration.

  2. Pointwise interactions of finite element modeling of advection-diffusion equations

    SciTech Connect

    Yeh, G.T.

    1984-07-01

    Pointwise iteration techniques including successive under-relaxation (SUR), Gauss-Seidel (G-S), and successive over-relaxation (SOR) schemes, are applied to advection-diffusion equations to derive the matrix equation with finite element methods. These schemes are tested using two simple examples for which analytical solutions are available so that numerical results can be checked to ensure code consistency. Numerical experiments indicate that the iteration schemes, if convergent, produce almost identical solutions as those obtained by the direct elimination scheme. For diffusion dominant transport, all three iteration schemes generate convergent computations. However, for advection-diffusion equally dominant or advection dominant transport, only SUR and G-S schemes yield convergent calculations, the SOR scheme leads to divergent computations. Pointwise iteration schemes offer substantial savings in central process unit (CPU) memory over the direct elimination scheme, even for the small, two-dimensional verification example, without complicating the programming efforts and, in the meantime, keeps the CPU time comparable. A realistic, hypothetical problem is used to demonstrate the applicability and versatility of pointwise iterations and direct elimination schemes. The saving in CPU memory using the pointwise iterations is more than tenfold that using the direct elimination solution for this hypothetical problem. The saving in CPU time is even better, more than 40 fold.

  3. Feeding the "aneurysm": Orogen-parallel mass transport into Nanga Parbat and the western Himalayan syntaxis

    NASA Astrophysics Data System (ADS)

    Whipp, David M.; Beaumont, Christopher; Braun, Jean

    2014-06-01

    The Nanga Parbat-Haramosh massif (NPHM; western Himalayan syntaxis) requires an influx of mass exceeding that in the adjacent Himalayan arc to sustain high topography and rapid erosional exhumation rates. What supplies this mass flux and feeds this "tectonic aneurysm?" We show, using a simple 3-D model of oblique orogen convergence, that velocity/strain partitioning results in horizontal orogen-parallel (OP) crustal transport, and the same behavior is inferred for the Himalaya, with OP transport diverting converging crust toward the syntaxis. Model results also show that the OP flow rate decreases in the syntaxis, thereby thickening the crust and forming a structure like the NPHM. The additional crustal thickening, over and above that elsewhere in the Himalayan arc, sustains the rapid exhumation of this "aneurysm." Normally, velocity/strain partitioning would be minimal for the Himalayan arc where the convergence obliquity is no greater than ~40°. However, we show analytically that the Himalayan system can act both as a critical wedge and exhibit strain partitioning if both the detachment beneath the wedge and the bounding rear shear zone, which accommodates OP transport, are very weak. Corresponding numerical results confirm this requirement and demonstrate that a Nanga Parbat-type shortening structure can develop spontaneously if the orogenic wedge and bounding rear shear zone can strain rate soften while active. These results lead us to question whether the position of NPHM aneurysm is localized by river incision, as previously suggested, or by a priori focused tectonic shortening of the crust in the syntaxis region as demonstrated by our models.

  4. Mitigation of along-track artifacts in unconstrained mass transport models based on GRACE satellite data

    NASA Astrophysics Data System (ADS)

    Ditmar, Pavel; Hashemi Farahani, Hassan; Encarnação, João.

    2010-05-01

    The satellite gravity mission GRACE (Gravity Recovery And Climate Experiment), which was launched in 2002, offers a unique opportunity to monitor tiny variations of the Earth's gravity and associated mass transport from space. In particular, the redistribution of water in the Earth's system can be traced in this way, which is critical for monitoring key climate indicators such as ice-sheet mass balance, terrestrial water-storage change, sea-level rise, and ocean circulation. Unfortunately, mass transport models based on GRACE data suffer from along-track artifacts. In order to suppress these artifacts, various filtering algorithms are applied to unconstrained GRACE-based models at the post-processing stage. However, any filtering not only suppresses noise but also distorts signals. Therefore, it is important to study the precise origin of the along-track artifacts in an attempt to mitigate them already at the level of unconstrained solutions. We identify two major causes of along-track artifacts: (1) the presence of low-frequency noise in GRACE data and (2) the observation principle of the GRACE satellite mission, which results in a poor sensitivity of the collected inter-satellite ranging data to the East-West gradient of the gravity field. According to our studies, an increased level of noise at low frequencies can be mostly explained by inaccuracies in the estimated orbits of GRACE satellites. To suppress this type of noise, we propose: (i) to use more advanced orbit determination procedures that allow deficiencies of available force models to be mitigated; (ii) to apply proper data weighting in the frequency domain, so that that the influence of frequencies with a large noise level is downweighted. As far as East-West gradients are concerned, we find it important to use the statistically optimal combination of GRACE inter-satellite ranging data with other observations (particularly, absolute positions of GRACE and CHAMP satellites). The added value of each of

  5. Model development and verification for mass transport to Escherichia coli cells in a turbulent flow

    NASA Astrophysics Data System (ADS)

    Hondzo, Miki; Al-Homoud, Amer

    2007-08-01

    Theoretical studies imply that fluid motion does not significantly increase the molecular diffusive mass flux toward and away from microscopic organisms. This study presents experimental and theoretical evidence that small-scale turbulence modulates enhanced mass transport to Escherichia coli cells in a turbulent flow. Using the technique of inner region and outer region expansions, a model for dissolved oxygen and glucose uptake by E. coli was developed. The mass transport to the E. coli was modeled by the Sherwood (Sh)-Péclet (Pe) number relationship with redefined characteristic length and velocity scales. The model Sh = (1 + Pe1/2 + Pe) agreed with the laboratory measurements well. The Péclet number that quantifies the role and function of small-scale turbulence on E. coli metabolism is defined by Pe = (?) where Ezz is the root mean square of fluid extension in the direction of local vorticity, ηK is the Kolmogorov length scale, Lc is the length scale of E. coli, and D is the molecular diffusion coefficient. An alternative formulation for the redefined Pe is given by Pe = (?) where ? = 0.5(ɛν)1/4 is the Kolmogorov velocity averaged over the Kolmogorov length scale, ɛ is dissipation of turbulent kinetic energy, and ν is the kinematic viscosity of fluid. The dissipation of turbulent kinetic energy was estimated directly from measured velocity gradients and was within the reported range in engineered and natural aquatic ecosytems. The specific growth of E. coli was up to 5 times larger in a turbulent flow in comparison to the still water controls. Dissolved oxygen and glucose uptake were enhanced with increased ɛ in the turbulent flow.

  6. Analytic radiative-advective equilibrium as a model for high-latitude climate

    NASA Astrophysics Data System (ADS)

    Cronin, Timothy W.; Jansen, Malte F.

    2016-01-01

    We propose radiative-advective equilibrium as a basic-state model for the high-latitude atmosphere. Temperature profiles are determined by a competition between stabilization by atmospheric shortwave absorption and advective heat flux convergence, and destabilization by surface shortwave absorption. We derive analytic expressions for temperature profiles, assuming power law atmospheric heating profiles as a function of pressure and two-stream windowed-gray longwave radiative transfer. We discuss example profiles with and without an atmospheric window and show that the sensitivity of surface temperature to forcing depends on the nature of the forcing, with greatest sensitivity to radiative forcing by increased optical thickness and least sensitivity to increased atmospheric heat transport. These differences in sensitivity of surface temperature to forcing can be explained in terms of a forcing-dependent lapse-rate feedback.

  7. Advection and the Efficiency of Spectral Energy Transfer in Two-Dimensional Turbulence.

    PubMed

    Fang, Lei; Ouellette, Nicholas T

    2016-09-02

    We report measurements of the geometric alignment of the small-scale turbulent stress and the large-scale rate of strain that together lead to the net flux of energy from small scales to large scales in two-dimensional turbulence. We find that the instantaneous alignment between these two tensors is weak and, thus, that the spectral transport of energy is inefficient. We show, however, that the strain rate is much better aligned with the stress at times in the past, suggesting that the differential advection of the two is responsible for the inefficient spectral transfer. We provide evidence for this conjecture by measuring the alignment statistics conditioned on weakly changing stress history. Our results give new insight into the relationship between scale-to-scale energy transfer, geometric alignment, and advection in turbulent flows.

  8. Relative importance of gas-phase diffusive and advective tichloroethene (TCE) fluxes in the unsaturated zone under natural conditions.

    PubMed

    Choi, Jee-Won; Tillman, Fred D; Smith, James A

    2002-07-15

    It was hypothesized that atmospheric pressure changes can induce gas flow in the unsaturated zone to such an extent that the advective flux of organic vapors in unsaturated-zone soil gas can be significant relative to the gas-phase diffusion flux of these organic vapors. To test this hypothesis, a series of field measurements and computer simulations were conducted to simulate and compare diffusion and advection fluxes at a trichloroethene-contaminated field site at Picatinny Arsenal in north-central New Jersey. Moisture content temperature, and soil-gas pressure were measured at multiple depths (including at land surface) and times for three distinct sampling events in August 1996, October 1996, and August 1998. Gas pressures in the unsaturated zone changed significantly over time and followed changes measured in the atmosphere. Gas permeability of the unsaturated zone was estimated using data from a variety of sources, including laboratory gas permeability measurements made on intact soil cores from the site, a field air pump test, and calibration of a gas-flow model to the transient, one-dimensional gas pressure data. The final gas-flow model reproduced small pressure gradients as observed in the field during the three distinct sampling events. The velocities calculated from the gas-flow model were used in transient, one-dimensional transport simulations to quantify advective and diffusive fluxes of TCE vapor from the subsurface to the atmosphere as a function of time for each sampling event. Effective diffusion coefficients used for these simulations were determined from independent laboratory measurements made on intact soil cores collected from the field site. For two of the three sampling events (August 1996 and August 1998), the TCE gas-phase diffusion flux at land surface was significantly greater than the advection flux over the entire sampling period. For the second sampling event (October 1996), the advection flux was frequently larger than the

  9. Arabian Night and Sea Story - Biomarkers from a Giant Mass Transport Deposit.

    NASA Astrophysics Data System (ADS)

    Bratenkov, Sophia; Kulhanek, Denise K.; Clift, Peter D.; George, Simon C.

    2016-04-01

    The study of mass transport deposits (MTDs) is an important field of research due to the potential insights into catastrophic events in the past and modern geohazard threats (e.g. tsunamis). Submarine mass movements are very significant processes in sculpturing the structure of continental margins, particularly in their extent and magnitude that have consequences both in the modern day, as well as in the geological past. An understanding of the complex stratigraphy of a submarine mass transport deposit (MTD) might help in reconstructing the provenance and transport pathways of sedimentary material and thus give important insights into sedimentary dynamics and processes triggering specific events. Drilling operations during International Ocean Discovery Program (IODP) Expedition 355 Arabian Sea Monsoon, which took place during April and May, 2015 cored two sites in Laxmi Basin. Site U1456 was cored to 1109.4 m below seafloor (mbsf), with the oldest recovered rock dated to ~13.5-17.7 Ma. Site U1457 was cored to 1108.6 mbsf, with the oldest rock dated to ~62 Ma. At each site, we cored through ~330 m and ~190 m of MTD material. The MTD layers mainly consist of interbedded lithologies of dark grey claystone, light greenish calcarenite and calcilutite, and conglomerate/breccia, with ages based on calcareous nannofossil and foraminifer biostratigraphy ranging from the Eocene to early Miocene (Pandey et al., 2015). This MTD, known as Nataraja Slide, is the third largest MTD known from the geological record and the second largest on a passive margin. Calvés et al. (2015) identified a potential source area offshore Sourashstra on the Indian continental margin and invoked the single step mass movement model to explain the mechanism of emplacement. Initial shipboard work demonstrated the high variability in total organic carbon and total nitrogen levels in different layers within the MTD, which raises a number of questions related to the source and composition of the organic

  10. Designing for chaos: applications of chaotic advection at the microscale.

    PubMed

    Stremler, Mark A; Haselton, F R; Aref, Hassan

    2004-05-15

    Chaotic advection can play an important role in efficient microfluidic mixers. We discuss a design paradigm that exploits chaotic advection and illustrate by two recent examples, namely enhancing gene expression profiling and constructing an in-line microfluidic mixing channel, how application of this paradigm has led to successful micromixers. We suggest that 'designing for chaos', that is, basing practical mixer design on chaotic advection analysis, is a promising approach to adopt in this developing field which otherwise has little to guide it and is constrained by issues of scale and manufacturability.

  11. Monthly Variation of Taiwan Strait Through-flow Transports and Associated Water Masses

    NASA Astrophysics Data System (ADS)

    Jan, S.; Sheu, D.; Kuo, H.

    2005-05-01

    Through-flow transports and associated water masses are analyzed using current data measured by bottom-mounted and ship-board ADCP (1999-2001) across the central Taiwan Strait and strait-wide hydrographic data acquired from 79 CTD survey cruises (1986-2003). The East Asian monsoon, from southwest in July to August and northeast in October to March, controls the transport fluctuation which peaks in August (2.34 Sv northward), is hampered by the northeast monsoon after September and diminishes to the minimum (0.26 Sv southward) in December. The standard deviation of the calculated transport ranges from 0.56 to 1.05 Sv during northeast monsoon months and is relatively small in other months. A cluster analysis together with conventional T-S diagrams identifies the saline and warm Kuroshio Branch Water (KBW), the less saline South China Sea Surface Water (SCSSW), the brackish and cold China Coastal Water (CCW), the saline Subsurface Water (SW) (depth > 100 m) and the Diluted Coastal Water (DCW). The majority of the northward transport in summer carries the SCSSW to the East China Sea. Meanwhile, the DCW appears off the northwest bank of the strait and the SW resides in the bottom layer of a deep trench in the southeastern strait. The onset of the northeast monsoon in September drives the CCW from the Yangtze river mouth to the northern strait. In the southern strait, the northward-moving KBW replaces the SCSSW and meets the southward-intruding CCW in the middle strait during November to April.

  12. Mass transport of deposited particles by surface-to-surface contact.

    PubMed

    McDonagh, A; Sextro, R G; Byrne, M A

    2012-08-15

    The spread of particle-borne contamination by surface-to-surface contact and its implications for exposures within the indoor environment have been observed - largely qualitatively. The present study was conducted with the aim of quantifying the mass transfer efficiency (TE) of deposited aerosol particles when selected soft and hard surfaces come in contact. The surfaces used were 100% cotton, synthetic fleece, plastic laminate and brass. Contact transfer efficiencies ranging from 2 to 45% were observed; these are very significant numbers in terms of hazardous aerosol transport in the environment. Other observations include an increase in the mass transferred with increased surface roughness. An increase in the applied pressure between the two surfaces in contact leads to a step change in transfer efficiency, so that two pressure regimes can be identified, with a transition pressure between them that depends on surface type. Time of contact appears to have little to no effect on the mass transfer efficiency for the surfaces studied, while contaminant loading has some effect that is not systematic.

  13. Mass transport induced by internal Kelvin waves beneath shore-fast ice

    NASA Astrophysics Data System (ADS)

    StøYlen, Eivind; Weber, Jan Erik H.

    2010-03-01

    A one-layer reduced-gravity model is used to investigate the wave-induced mass flux in internal Kelvin waves along a straight coast beneath shore-fast ice. The waves are generated by barotropic tidal pumping at narrow sounds, and the ice lid introduces a no-slip condition for the horizontal wave motion. The mean Lagrangian fluxes to second order in wave steepness are obtained by integrating the equations of momentum and mass between the material interface and the surface. The mean flow is forced by the conventional radiation stress for internal wave motion, the mean pressure gradient due to the sloping surface, and the frictional drag at the boundaries. The equations that govern the mean fluxes are expressed in terms of mean Eulerian variables, while the wave forcing terms are given by the horizontal divergence of the Stokes flux. Analytical results show that the effect of friction induces a mean Eulerian flux along the coast that is comparable to the Stokes flux. In addition, the horizontal divergence of the total mean flux along the coast induces a small mass flux in the cross-shore direction. This flux changes the mean thickness of the upper layer outside the trapping region and may facilitate geostrophically balanced boundary currents in enclosed basins. This is indeed demonstrated by numerical solutions of the flux equations for confined areas larger than the trapping region. Application of the theory to Arctic waters is discussed, with emphasis on the transport of biological material and pollutants in nearshore regions.

  14. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    PubMed

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  15. MAST solution of advection problems in irrotational flow fields

    NASA Astrophysics Data System (ADS)

    Aricò, Costanza; Tucciarelli, Tullio

    2007-03-01

    A new numerical-analytical Eulerian procedure is proposed for the solution of convection-dominated problems in the case of existing scalar potential of the flow field. The methodology is based on the conservation inside each computational elements of the 0th and 1st order effective spatial moments of the advected variable. This leads to a set of small ODE systems solved sequentially, one element after the other over all the computational domain, according to a MArching in Space and Time technique. The proposed procedure shows the following advantages: (1) it guarantees the local and global mass balance; (2) it is unconditionally stable with respect to the Courant number, (3) the solution in each cell needs information only from the upstream cells and does not require wider and wider stencils as in most of the recently proposed higher-order methods; (4) it provides a monotone solution. Several 1D and 2D numerical test have been performed and results have been compared with analytical solutions, as well as with results provided by other recent numerical methods.

  16. Comparisons of diffusive and advective fluxes of gas phase volatile organic compounds (VOCs) in unsaturated zones under natural conditions

    NASA Astrophysics Data System (ADS)

    You, Kehua; Zhan, Hongbin

    2013-02-01

    Diffusive flux is traditionally treated as the dominant mechanism of gas transport in unsaturated zones under natural conditions, and advective flux is usually neglected. However, some researchers have found that pressure-driven and density-driven advective flux may also be significant under certain conditions. This article compares the diffusive, pressure-driven and density-driven advective fluxes of gas phase volatile organic compound (VOCs) in unsaturated zones under various natural conditions. The presence of a less or more permeable layer at ground surface in a layered unsaturated zone is investigated for its impact on the net contribution of advective and diffusive fluxes. Results show although the transient advective flux can be greater than the diffusive flux, under most of the field conditions the net contribution of the advective flux is one to three orders of magnitude less than the diffusive flux, and the influence of the density-driven flux is undetectable. The advective flux contributes comparably with the diffusive flux only when the gas-filled porosity is less than 0.05. The presence of a less permeable layer at ground surface slightly increases the total flux in the underlying layer, while the presence of a more permeable layer at ground surface significantly increases the total flux in it. When the magnitude of water table fluctuation is less than 1 cm, and the period is greater than 0.5 day, the fluctuation of the water table can be simulated by fixing the water table position and setting a fluctuating moving velocity at the water table.

  17. VOC Composition of Air Masses Transported from Asia to the U.S. West Coast

    NASA Astrophysics Data System (ADS)

    de Gouw, J.; Warneke, C.; Kuster, B.; Parrish, D.; Holloway, J.; Huebler, G.; Fehsenfeld, F.

    2002-12-01

    Airborne measurements of volatile organic compounds (VOCs) were performed using a proton-transfer-reaction mass spectrometer (PTR-MS) operated onboard a NOAA WP-3 aircraft during the Intercontinental Transport and Chemical Transformation (ITCT) experiment in 2002. Enhancements of acetone (CH3COCH3), methanol (CH3OH), acetonitrile (CH3CN) and in some cases benzene were observed in air masses that were impacted by outflow from Asia. The enhancement ratios with respect to carbon monoxide are compared to emission factors for fossil fuel combustion and biomass burning, which gives some insight into the sources responsible for the pollution. The observed mixing ratios for acetone, methanol and in particular acetonitrile were generally reduced in the marine boundary layer, suggesting the presence of an ocean uptake sink. The ocean uptake of acetonitrile was found to be particularly efficient in a zone with upwelling water off of the U.S. west coast. Reduced mixing ratios of acetone and methanol were observed in a stratospheric intrusion. This observation gives some information about the lifetime of these VOCs in the stratosphere. Enhanced concentrations of aromatic hydrocarbons were observed in air masses that were impacted by urban sources in California. The ratio between the concentrations of benzene, toluene and higher aromatics indicated the degree of photochemical oxidation. PTR-MS only gives information about the mass of the ions produced by proton-transfer reactions between H3O+ and VOCs in the instrument. The identification of VOCs was confirmed by coupling a gas-chromatographic (GC) column to the instrument and post-flight GC-PTR-MS analyses of canister samples collected during the flights.

  18. The effect of advection on the nutrient reservoir in the North Atlantic subtropical gyre.

    PubMed

    Palter, Jaime B; Lozier, M Susan; Barber, Richard T

    2005-09-29

    Though critically important in sustaining the ocean's biological pump, the cycling of nutrients in the subtropical gyres is poorly understood. The supply of nutrients to the sunlit surface layer of the ocean has traditionally been attributed solely to vertical processes. However, horizontal advection may also be important in establishing the availability of nutrients. Here we show that the production and advection of North Atlantic Subtropical Mode Water introduces spatial and temporal variability in the subsurface nutrient reservoir beneath the North Atlantic subtropical gyre. As the mode water is formed, its nutrients are depleted by biological utilization. When the depleted water mass is exported to the gyre, it injects a wedge of low-nutrient water into the upper layers of the ocean. Contrary to intuition, cold winters that promote deep convective mixing and vigorous mode water formation may diminish downstream primary productivity by altering the subsurface delivery of nutrients.

  19. Reaction-diffusion-advection approach to spatially localized treadmilling aggregates of molecular motors

    NASA Astrophysics Data System (ADS)

    Yochelis, Arik; Bar-On, Tomer; Gov, Nir S.

    2016-04-01

    Unconventional myosins belong to a class of molecular motors that walk processively inside cellular protrusions towards the tips, on top of actin filament. Surprisingly, in addition, they also form retrograde moving self-organized aggregates. The qualitative properties of these aggregates are recapitulated by a mass conserving reaction-diffusion-advection model and admit two distinct families of modes: traveling waves and pulse trains. Unlike the traveling waves that are generated by a linear instability, pulses are nonlinear structures that propagate on top of linearly stable uniform backgrounds. Asymptotic analysis of isolated pulses via a simplified reaction-diffusion-advection variant on large periodic domains, allows to draw qualitative trends for pulse properties, such as the amplitude, width, and propagation speed. The results agree well with numerical integrations and are related to available empirical observations.

  20. Anomalous scaling of a scalar field advected by turbulence

    SciTech Connect

    Kraichnan, R.H.

    1995-12-31

    Recent work leading to deduction of anomalous scaling exponents for the inertial range of an advected passive field from the equations of motion is reviewed. Implications for other turbulence problems are discussed.

  1. Nitrogen transport and transformations in a shallow aquifer receiving wastewater discharge: A mass balance approach

    USGS Publications Warehouse

    DeSimone, L.A.; Howes, B.L.

    1998-01-01

    Nitrogen transport and transformations were followed over the initial 3 years of development of a plume of wastewater-contaminated groundwater in Cape Cod, Massachusetts. Ammonification and nitrification in the unsaturated zone and ammonium sorption in the saturated zone were predominant, while loss of fixed nitrogen through denitrification was minor. The major effect of transport was the oxidation of discharged organic and inorganic forms to nitrate, which was the dominant nitrogen form in transit to receiving systems. Ammonification and nitrification in the unsaturated zone transformed 16-19% and 50-70%, respectively, of the total nitrogen mass discharged to the land surface during the study but did not attenuate the nitrogen loading. Nitrification in the unsaturated zone also contributed to a pH decrease of 2 standard units and to an N2O increase (46-660 ??g N/L in the plume). Other processes in the unsaturated zone had little net effect: Ammonium sorption removed <1% of the total discharged nitrogen mass; filtering of particulate organic nitrogen was less than 3%; ammonium and nitrate assimilation was less than 6%; and ammonia volatilization was less than 0.25%. In the saturated zone a central zone of anoxic groundwater (DO ??? 0.05 mg/L) was first detected 17 months after effluent discharge to the aquifer began, which expanded at about the groundwater-flow velocity. Although nitrate was dominant at the water table, the low, carbon-limited rates of denitrification in the anoxic zone (3.0-9.6 (ng N/cm3)/d) reduced only about 2% of the recharged nitrogen mass to N2. In contrast, ammonium sorption in the saturated zone removed about 16% of the recharged nitrogen mass from the groundwater. Ammonium sorption was primarily limited to anoxic zone, where nitrification was prevented, and was best described by a Langmuir isotherm in which effluent ionic concentrations were simulated. The initial nitrogen load discharged from the groundwater system may depend largely on

  2. New evidence for widespread mass transport on the Northeast Newfoundland Shelf revealed by Olex single-beam echo sounding

    NASA Astrophysics Data System (ADS)

    Shaw, John; Piper, David J. W.; Skulski, Thomas; Lamplugh, Michael J.; Craft, Andrew; Roy, André

    2012-02-01

    Based on Olex single-beam sounder data, multibeam sonar surveys, and sparse seismic reflection profiles, we recognize a large area of anomalous bathymetry on the Northeast Newfoundland Shelf as having formed as a result of mass-transport processes. Transported masses include (1) an arcuate ridge of deformed material with an area of 430 km2, which has moved distances of ~20 km; (2) a 70-km2 mass of deformed material displaced 50 km along a nearly horizontal track flanked by 90-m-high berms. The movement of these and other sediment bodies has created a 150-m-high headwall escarpment extending 110 km along the north flank of the Notre Dame glacial trough. In addition, a 35-km2 block of undeformed material has moved 5 km to the southeast, away from the headwall, creating a gap of the same dimensions, while a smaller block of material originating in this vicinity has been displaced 24 km in the opposite direction, creating a 20-m-deep groove on the seafloor. There is evidence for mass transport and headwall formation elsewhere on the Northeast Newfoundland Shelf. Analysis of seismic reflection data indicates that the transported material most likely consists of stacked Quaternary till sheets that overlie Cenozoic, Mesozoic and older sedimentary rocks. Given the very low gradients involved, glaciotectonism is the most likely process to account for transport and deformation of the large sediment masses. However, some mass transport may have resulted from submarine sliding away from the headwalls that were created by the glacial transport.

  3. Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene

    PubMed Central

    Vecera, Philipp; Holzwarth, Johannes; Edelthalhammer, Konstantin F.; Mundloch, Udo; Peterlik, Herwig; Hauke, Frank; Hirsch, Andreas

    2016-01-01

    Herein, we report on a significant discovery, namely, the quantitative discharging of reduced graphite forms, such as graphite intercalation compounds, graphenide dispersions and graphenides deposited on surfaces with the simple solvent benzonitrile. Because of its comparatively low reduction potential, benzonitrile is reduced during this process to the radical anion, which exhibits a red colour and serves as a reporter molecule for the quantitative determination of negative charges on the carbon sheets. Moreover, this discovery reveals a very fundamental physical–chemical phenomenon, namely a quantitative solvent reduction induced and electrostatically driven mass transport of K+ ions from the graphite intercalation compounds into the liquid. The simple treatment of dispersed graphenides suspended on silica substrates with benzonitrile leads to the clean conversion to graphene. This unprecedented procedure represents a rather mild, scalable and inexpensive method for graphene production surpassing previous wet-chemical approaches. PMID:27506380

  4. A biphasic hyperelastic model for the analysis of fluid and mass transport in brain tissue.

    PubMed

    García, José Jaime; Smith, Joshua H

    2009-02-01

    A biphasic hyperelastic finite element model is proposed for the description of the mechanical behavior of brain tissue. The model takes into account finite deformations through an Ogden-type hyperelastic compressible function and a hydraulic conductivity dependent on deformation. The biphasic equations, implemented here for spherical symmetry using an updated Lagrangian algorithm, yielded radial coordinates and fluid velocities that were used with the convective-diffusive equation in order to predict mass transport in the brain. Results of the model were equal to those of a closed-form solution under infinitesimal deformations, however, for a wide range of material parameters, the model predicted important increments in the infusion sphere, reductions of the fluid velocities, and changes in the species content distribution. In addition, high localized deformation and stresses were obtained at the infusion sphere. Differences with the infinitesimal solution may be mainly attributed to geometrical nonlinearities related to the increment of the infusion sphere and not to material nonlinearities.

  5. The Sheath Transport Observer for the Redistribution of Mass (STORM) Image

    NASA Technical Reports Server (NTRS)

    Kuntz, Kip; Collier, Michael; Sibeck, David G.; Porter, F. Scott; Carter, J. A.; Cravens, Thomas; Omidi, N.; Robertson, Ina; Sembay, S.; Snowden, Steven L.

    2008-01-01

    All of the solar wind energy that powers magnetospheric processes passes through the magnetosheath and magnetopause. Global images of the magnetosheath and magnetopause boundary layers will resolve longstanding controversy surrounding fundamental phenomena that occur at the magnetopause and provide information needed to improve operational space weather models. Recent developments showing that soft X-rays (0.15-1 keV) result from high charge state solar wind ions undergoing charge exchange recombination through collisions with exospheric neutral atoms has led to the realization that soft X-ray imaging can provide global maps of the high-density shocked solar wind within the magnetosheath and cusps, regions lying between the lower density solar wind and magnetosphere. We discuss an instrument concept called the Sheath Transport Observer for the Redistribution of Mass (STORM), an X-ray imager suitable for simultaneously imaging the dayside magnetosheath, the magnetopause boundary layers, and the cusps.

  6. Decay Characteristics of Surface Mounds with Contrasting Interlayer Mass Transport Channels

    SciTech Connect

    Li, Maozhi; Wendelken, J. F.; Liu, Bang-Gui; Wang, E. G.; Zhang, Zhenyu

    2001-03-12

    The decay characteristics of three-dimensional (3D) islands formed on surfaces are investigated theoretically considering two types of interlayer mass transport mechanisms. If an adatom on a given layer can easily descend from any site along the periphery of the layer, an optimal island slope and a constant terrace width will be selected during the decay. In contrast, if the adatom can descend primarily through selective (such as kinked) sites, the decay will be accompanied by a gradual increase in the island slope. These generic conclusions provide the basis for a microscopic understanding of the decay of nanostructures in fcc(111) and fcc(100) metal homoepitaxy and are applicable to other systems as well.

  7. Decay characteristics of surface mounds with contrasting interlayer mass transport channels.

    PubMed

    Li, M; Wendelken, J F; Liu, B G; Wang, E G; Zhang, Z

    2001-03-12

    The decay characteristics of three-dimensional (3D) islands formed on surfaces are investigated theoretically considering two types of interlayer mass transport mechanisms. If an adatom on a given layer can easily descend from any site along the periphery of the layer, an optimal island slope and a constant terrace width will be selected during the decay. In contrast, if the adatom can descend primarily through selective (such as kinked) sites, the decay will be accompanied by a gradual increase in the island slope. These generic conclusions provide the basis for a microscopic understanding of the decay of nanostructures in fcc(111) and fcc(100) metal homoepitaxy and are applicable to other systems as well.

  8. Modeling of the mass transport in porous media under laser beam irradiation

    NASA Astrophysics Data System (ADS)

    Wojtatowicz, Tomasz W.

    1995-03-01

    The vaporization of porous materials (especially internal vaporization of skeleton) has been largely ignored in studies of laser heating and processing of materials. The loss of energy associated with the vaporization process would keep the internal temperature of material from rising. In this paper the author presents the results of the computation of the heat losses for two different models of porous media: the sand and the pores' tree model. In his calculation the author uses the thermophysical parameters of gypsum slurry. In the first step a numerical simulation is carried out for the vaporization of solid skeleton and mass transport of vapor (without the viscosity of vapor), only. Then the water on the pore's wall was taken into account.

  9. Contribution of di-SIA to mass transport in Fe-Cr alloys

    NASA Astrophysics Data System (ADS)

    Ryabov, V. A.; Pechenkin, V. A.; Molodtsov, V. L.; Terentyev, D.

    2016-04-01

    Molecular dynamics simulations have been performed to study the diffusion characteristics of di-self interstitial atom (di-SIA) in BCC Fe-Cr alloys and corresponding mass transport of Fe and Cratoms in the temperature range 600-1000 K in the alloys with Cr content 5-25 at%, which is relevant for ferritic/martensitic steels. An original treatment is proposed in this work to account for a mixed migration mode composed of the diffusion of the cluster itself and break-up into a pair of independent SIAs. The ratio of self-diffusion coefficients of Cr and Fe is found to exceed unity in Fe-5Cr and Fe-10Cr alloys, which implies that under cascade-producing damage, 3D-migrating small SIA clusters will effectively contribute to the segregation of Cr to neutral and SIA-preferential sinks, eventually causing radiation induced segregation.

  10. High-speed mass-transport phenomena during carburization of aluminum alloy by laser plasma treatment

    NASA Astrophysics Data System (ADS)

    Fariaut, F.; Boulmer-Leborgne, C.; Semmar, N.; Le Menn, E.

    2006-04-01

    In the excimer laser carburizing process reported here, aluminum alloy samples have been treated in a propylene atmosphere, producing aluminum carbide surface layers. The layers have been characterized by nuclear reaction analysis that has shown carbon incorporation. X-ray diffraction at grazing incidence has evidenced aluminum carbide (Al4C3) phase. This study helps the understanding of the incorporation mechanisms of carbon in a surface. A micro-thermocapillary effect induced by heterogeneous surface formation has been evidenced. This original mass-transport phenomenon is very efficient in improving the carbon incorporation yield and hence in obtaining carbide layers several μm in thickness with a reduced laser pulse number. In order to obtain this micro-thermocapillary effect, the binary diagram of ceramic compounds must contain a peritectic.

  11. The Sheath Transport Observer for the Redistribution of Mass (STORM) Imager

    NASA Technical Reports Server (NTRS)

    Collier, Michael R.; Sibeck, David G.; Porter, F. Scott; Burch, J.; Carter, J. A.; Cravens, Thomas; Kuntz, Kip; Omidi, N.; Read, A.; Robertson, Ina; Sembay, S.; Snowden, Steven L.

    2010-01-01

    All of the solar wind energy that powers magnetospheric processes passes through the magnetosheath and magnetopause. Global images of the magnetosheath and magnetopause boundary layers will resolve longstanding controversies surrounding fundamental phenomena that occur at the magnetopause and provide information needed to improve operational space weather models. Recent developments showing that soft X-rays (0.15-1 keV) result from high charge state solar wind ions undergoing charge exchange recombination through collisions with exospheric neutral atoms has led to the realization that soft X-ray imaging can provide global maps of the high-density shocked solar wind within the magnetosheath and cusps, regions lying between the lower density solar wind and magnetosphere. We discuss an instrument concept called the Sheath Transport Observer for the Redistribution of Mass (STORM), an X-ray imager suitable for simultaneously imaging the dayside magnetosheath, the magnetopause boundary layers, and the cusps.

  12. Mass transport, corrosion, plugging, and their reduction in solar dish/Stirling heat pipe receivers

    SciTech Connect

    Adkins, D.R.; Andraka, C.E.; Bradshaw, R.W.; Goods, S.H.; Moreno, J.B.; Moss, T.A.

    1996-07-01

    Solar dish/Stirling systems using sodium heat pipe receivers are being developed by industry and government laboratories here and abroad. The unique demands of this application lead to heat pipe wicks with very large surface areas and complex three-dimensional flow patterns. These characteristics can enhance the mass transport and concentration of constituents of the wick material, resulting in wick corrosion and plugging. As the test times for heat pipe receivers lengthen, we are beginning to see these effects both indirectly, as they affect performance, and directly in post-test examinations. We are also beginning to develop corrective measures. In this paper, we report on our test experiences, our post-test examinations, and on our initial effort to ameliorate various problems.

  13. Comparison of one-, two-, and three-dimensional models for mass transport of radionuclides

    SciTech Connect

    Prickett, T.A.; Voorhees, M.L.; Herzog, B.L.

    1980-02-01

    This technical memorandum compares one-, two-, and three-dimensional models for studying regional mass transport of radionuclides in groundwater associated with deep repository disposal of high-level radioactive wastes. In addition, this report outlines the general conditions for which a one- or two-dimensional model could be used as an alternate to a three-dimensional model analysis. The investigation includes a review of analytical and numerical models in addition to consideration of such conditions as rock and fluid heterogeneity, anisotropy, boundary and initial conditions, and various geometric shapes of repository sources and sinks. Based upon current hydrologic practice, each review is taken separately and discussed to the extent that the researcher can match his problem conditions with the minimum number of model dimensions necessary for an accurate solution.

  14. Upward mass transport and alloying during the growth of Co on Cu(111)

    NASA Astrophysics Data System (ADS)

    Vu, Quang Huy; Morgenstern, Karina

    2017-03-01

    Co growth on Cu(111) was investigated at several temperatures between 120 K and 300 K by variable-temperature fast-scanning tunneling microscopy at submonolayer coverage. Islands nucleate heterogeneously at step edges and homogeneously on terraces. The height and area distribution difference between these two types of differently nucleated islands is attributed to a step edge alloy. Furthermore, the transformation from one-monolayer high islands to two-monolayer high islands is followed in time-lapsed sequences between 145 and 165 K. A surprising low-energy barrier for upward mass transport of Eupward≈(0.15 ±0.04 ) eV is determined for islands on terraces. At 120 and 150 K, the terrace islands are pure Cu; in contrast, at room temperature, terrace islands larger than ≈120 nm2 alloy at their border.

  15. Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene

    NASA Astrophysics Data System (ADS)

    Vecera, Philipp; Holzwarth, Johannes; Edelthalhammer, Konstantin F.; Mundloch, Udo; Peterlik, Herwig; Hauke, Frank; Hirsch, Andreas

    2016-08-01

    Herein, we report on a significant discovery, namely, the quantitative discharging of reduced graphite forms, such as graphite intercalation compounds, graphenide dispersions and graphenides deposited on surfaces with the simple solvent benzonitrile. Because of its comparatively low reduction potential, benzonitrile is reduced during this process to the radical anion, which exhibits a red colour and serves as a reporter molecule for the quantitative determination of negative charges on the carbon sheets. Moreover, this discovery reveals a very fundamental physical-chemical phenomenon, namely a quantitative solvent reduction induced and electrostatically driven mass transport of K+ ions from the graphite intercalation compounds into the liquid. The simple treatment of dispersed graphenides suspended on silica substrates with benzonitrile leads to the clean conversion to graphene. This unprecedented procedure represents a rather mild, scalable and inexpensive method for graphene production surpassing previous wet-chemical approaches.

  16. Constraints upon water advection in sediments of the Mariana Trough

    SciTech Connect

    Abbott, D.H.; Menke, W.; Morin, R.

    1983-02-10

    Thermal gradient measurements, consolidation tests, and pore water compositions from the Mariana Trough imply that water is moving through the sediments in areas with less than about 100 m of sediment cover. The maximum advection rates implied by the thermal measurements and consolidation tests may be as high as 10/sup -5/ cm s/sup -1/ but are most commonly in the range of 1 to 5 x 10/sup -6/ cm s/sup -1/. Theoretical calculations of the effect of the highest advection rates upon carbonate dissolution indicate that dissolution may be impeded or enhanced (depending upon the direction of flow) by a factor of 2 to 5 times the rate for diffusion alone. The average percentage of carbonate is consistently higher in two cores from the area with no advection or upward advection than the average percentage of carbonate in three cores from the area with downward advection. This increase in average amount of carbonate in cores with upward moving water or no movement cannot be attributed solely to differences in water depth or in amount of terrigenous dilution. If the sediment column acts as a passive boundary layer, then the water velocities necessary to affect chemical gradients of silica are in the range 10/sup -9/ to 10/sup -10/ cm s/sup -1/. However, if dissolution of silica occurs within the sediment column, then the advection velocities needed to affect chemical gradients are at least 3 x 10/sup -8/ cm s/sup -1/ and may be as high as 3 x 10/sup -6/ cm s/sup -1/. This order of magnitude increase in advection velocities when chemical reactions occur within the sediments is probably applicable to other cations in addition to silica. If so, then the advection velocities needed to affect heat flow (>10/sup -8/ cm s/sup -1/) and pore water chemical gradients are much nearer in magnitude than previously assumed.

  17. Optimal-mass-transfer-based estimation of glymphatic transport in living brain

    NASA Astrophysics Data System (ADS)

    Ratner, Vadim; Zhu, Liangjia; Kolesov, Ivan; Nedergaard, Maiken; Benveniste, Helene; Tannenbaum, Allen

    2015-03-01

    It was recently shown that the brain-wide cerebrospinal fluid (CSF) and interstitial fluid exchange system designated the `glymphatic pathway' plays a key role in removing waste products from the brain, similarly to the lymphatic system in other body organs . It is therefore important to study the flow patterns of glymphatic transport through the live brain in order to better understand its functionality in normal and pathological states. Unlike blood, the CSF does not flow rapidly through a network of dedicated vessels, but rather through para-vascular channels and brain parenchyma in a slower time-domain, and thus conventional fMRI or other blood-flow sensitive MRI sequences do not provide much useful information about the desired flow patterns. We have accordingly analyzed a series of MRI images, taken at different times, of the brain of a live rat, which was injected with a paramagnetic tracer into the CSF via the lumbar intrathecal space of the spine. Our goal is twofold: (a) find glymphatic (tracer) flow directions in the live rodent brain; and (b) provide a model of a (healthy) brain that will allow the prediction of tracer concentrations given initial conditions. We model the liquid flow through the brain by the diffusion equation. We then use the Optimal Mass Transfer (OMT) approach to derive the glymphatic flow vector field, and estimate the diffusion tensors by analyzing the (changes in the) flow. Simulations show that the resulting model successfully reproduces the dominant features of the experimental data. Keywords: inverse problem, optimal mass transport, diffusion equation, cerebrospinal fluid flow in brain, optical flow, liquid flow modeling, Monge Kantorovich problem, diffusion tensor estimation

  18. Reservoir compartmentalization caused by mass transport deposition Northwest Stevens pool, Elk Hills Naval Petroleum Reserves, California

    SciTech Connect

    Milliken, M.D.; McJannet, G.S.; Shiflett, D.W.; Deutsch, H.A.

    1996-12-31

    The {open_quotes}A{close_quotes} sands of the Northwest Stevens Pool consist of six major subdivisions (A1-A6) and numerous sublayers. These sands are above the {open_quotes}N Point{close_quotes} stratigraphic marker, making them much younger than most other Stevens sands at Elk Hills. Cores show the A1-A3 sands to be possibly mass transport deposition, primarily debris flows, slumps, and sand injection bodies. The A4-A6 sands are characterized by normally graded sheet-like sand bodies Hospital of traditional outer fan turbidite lithofacies. Most current production from the A1-A2 interval comes from well 373A-7R, are completed waterflood wells that came on line in 1992 at 1400 BOPD. Well 373A-7R is an anomaly in the A1-A2 zone, where average production from the other ten wells is 200 BOPD. Other evidence for compartmentalization in the A1-A2 interval includes sporadic oil-water contacts and drawdown pressures, difficult log correlations, and rapid thickness changes. In 1973, well 362-7R penetrated 220 ft of wet Al sand. The well was redrilled updip and successfully completed in the A1, where the oil-water contact is more than 130 ft lower than the original hole and faulting is not apparent. In 1992, horizontal well 323H-7R unexpectedly encountered an entirely wet Al wedge zone. Reevaluation of the A1-A3 and other sands as mass transport origin is important for modeling initialization and production/development strategies.

  19. Reservoir compartmentalization caused by mass transport deposition Northwest Stevens pool, Elk Hills Naval Petroleum Reserves, California

    SciTech Connect

    Milliken, M.D.; McJannet, G.S. ); Shiflett, D.W. ); Deutsch, H.A. )

    1996-01-01

    The [open quotes]A[close quotes] sands of the Northwest Stevens Pool consist of six major subdivisions (A1-A6) and numerous sublayers. These sands are above the [open quotes]N Point[close quotes] stratigraphic marker, making them much younger than most other Stevens sands at Elk Hills. Cores show the A1-A3 sands to be possibly mass transport deposition, primarily debris flows, slumps, and sand injection bodies. The A4-A6 sands are characterized by normally graded sheet-like sand bodies Hospital of traditional outer fan turbidite lithofacies. Most current production from the A1-A2 interval comes from well 373A-7R, are completed waterflood wells that came on line in 1992 at 1400 BOPD. Well 373A-7R is an anomaly in the A1-A2 zone, where average production from the other ten wells is 200 BOPD. Other evidence for compartmentalization in the A1-A2 interval includes sporadic oil-water contacts and drawdown pressures, difficult log correlations, and rapid thickness changes. In 1973, well 362-7R penetrated 220 ft of wet Al sand. The well was redrilled updip and successfully completed in the A1, where the oil-water contact is more than 130 ft lower than the original hole and faulting is not apparent. In 1992, horizontal well 323H-7R unexpectedly encountered an entirely wet Al wedge zone. Reevaluation of the A1-A3 and other sands as mass transport origin is important for modeling initialization and production/development strategies.

  20. A Comprehensive Flow, Heat and Mass Transport Uncertainty Quantification in Discrete Fracture Network Systems

    NASA Astrophysics Data System (ADS)

    Ezzedine, S. M.

    2010-12-01

    Fractures and fracture networks are the principle pathways for migration of water, heat and mass in enhanced geothermal systems, oil and gas reservoirs, CO2 leakage from saline aquifers, and radioactive and toxic industrial wastes from underground storage repositories. A major issue to overcome when characterizing a fractured reservoir is that of data limitation due to accessibility and affordability. Moreover, the ability to map discontinuities in the rock with available geological and geophysical tools tends to decrease particularly as the scale of the discontinuity goes down. Geological characterization data include measurements of fracture density, orientation, extent, and aperture, and are based on analysis of outcrops, borehole optical and acoustic televiewer logs, aerial photographs, and core samples among others. All of these measurements are taken at the field scale through a very sparse limited number of deep boreholes. These types of data are often reduced to probability distributions function for predictive modeling and simulation in a stochastic framework such as stochastic discrete fracture network. Stochastic discrete fracture network models enable, through Monte Carlo realizations and simulations, for probabilistic assessment of flow and transport phenomena that are not adequately captured using continuum models. Despite the fundamental uncertainties inherited within the probabilistic reduction of the sparse data collected, very little work has been conducted on quantifying uncertainty on the reduced probabilistic distribution functions. In the current study, using nested Monte Carlo simulations, we present the impact of parameter uncertainties of the distribution functions that characterize discrete fracture networks on the flow, heat and mass transport. Numerical results of first, second and third moments, normalized to a base case scenario, are presented and compared to theoretical results extended from percolation theory.

  1. Mass transport analysis: inhalation rfc methods framework for interspecies dosimetric adjustment.

    PubMed

    Hanna, L M; Lou, S R; Su, S; Jarabek, A M

    2001-05-01

    In 1994, the U.S. Environmental Protection Agency introduced dosimetry modeling into the methods used to derive an inhalation reference concentration (RfC). The type of dosimetric adjustment factor (DAF) applied had to span the range of physicochemical characteristics of the gases listed on the Clean Air Act Amendments in 1991 as hazardous air pollutants (HAPs) and accommodate differences in available data with respect to their toxicokinetic properties. A framework was proposed that allowed for a hierarchy of dosimetry model structures, from optimal to rudimentary, and a category scheme that provided for limiting model structures based on physicochemical and toxicokinetic properties. These limiting cases were developed from restricting consideration to specific properties relying on an understanding of the generalized system based on mass transport theory. Physiochemical characteristics included the solubility and reactivity (e.g., propensity to dissociate, oxidize, or serve as a metabolic substrate) of the gas and were used as major determinants of absorption. Dosimetric adjustments were developed to evaluate portal of entry (POE) effects as well as remote (systemic) effects relevant to the toxicokinetic properties of the gas of interest. The gas categorization scheme consisted of defining three gas categories: (1) gases that are highly soluble and/or reactive, absorbing primarily in the extrathoracic airways; (2) gases that are moderately soluble and/or reactive, absorbing throughout the airways, as well as accumulating in the bloodstream; and (3) gases that have a low water solubility and are lipid soluble such that they are primarily absorbed in the pulmonary region and likely to act systemically. This article presents the framework and the mass transport theory behind the RfC method. Comparison to compartmental approaches and considerations for future development are also discussed.

  2. Mass-transport deposits: the role of gas in their triggering and final morphology

    NASA Astrophysics Data System (ADS)

    Imbert, Patrice

    2013-04-01

    Mass failure on continental slopes occurs when and where the shear stress at a certain level below the seafloor exceeds the resistance to shear of that level. A number of processes may cause this disequilibrium, including tectonic activity, excess sedimentation, etc. In several cases that will be presented from both seismic and outcrop data, it seems that gas migration plays a crucial role in defining the morphology of the basal surface. The clearest examples come from three separate sedimentary basins. In those three examples, the basal décollement of large-scale mass-transport deposits (MTDs), follows one stratigraphic level over most of the surveyed area, but locally jumps down to a ca. 100-m deeper level. These downward shifts in the basal surface occur right above the crest of underlying structural highs. The coincidence of this morphology with the deeper structure and in some cases with the presence of seismic indications of gas just below strongly suggest that gas did play a role in the location of the anomaly. Another seismic example shows numerous bright amplitude patches at the base of an MTD. The distribution of these anomalies, below relative thins of the transported mass, may indicate degassing by pressure decrease during, and maybe for some time after the gliding. Finally, a Cretaceous outcrop in SE France shows tubular carbonate concretions with a negative anomaly of 13C, interpreted to be diagnostic of methane-derived carbonates, just below the base of a 20-m thick slump. The following processes are envisioned to account for the relationship observed or inferred between anomalies in MTD morphology and gas migration pathways, and may not be mutually exclusive: • Processes initiated by the failure: local anomalies of the décollement surface - Pressure decrease by the spreading out of a failing mass of sediment may cause gas exsolution below the failure along gas migration pathways. Exsolution would then induce local loss of shear strength, and

  3. An unusual stratospheric ozone decrease linked to isentropic air-mass transport as observed over Irene (25.5° S, 28.1° E) in mid-May 2002

    NASA Astrophysics Data System (ADS)

    Semane, N.; Bencherif, H.; Morel, B.; Hauchecorne, A.; Diab, R. D.

    2005-12-01

    A prominent ozone minimum of less than 240 Dobson Units (DU) was observed over Irene (25.5° S, 28.1° E) by the Total Ozone Mapping Spectrometer (TOMS) during May 2002 with extremely low ozone value of less than 219 DU recorded on 12 May, as compared to a climatological mean of 249 DU for May between 1999 and 2005. In this study, the vertical structure of this ozone minimum is examined using ozonesonde measurements performed over Irene on 15 May 2002, when the total ozone (as given by TOMS) was about 226 DU. Indeed, it is found that the ozone minimum is of Antarctic polar origin with a low-ozone layer in the middle stratosphere above 625 K and of tropical origin with low-ozone layer between 400-K and 450-K isentropic levels in the lower stratosphere. The upper and lower depleted parts of the ozonesonde profile for 15 May, are respectively attributed to equatorward and poleward transport of low-ozone air toward the subtropics. The tropical air moving over Irene and the polar one passing over the same area associated with enhanced planetary-wave activity are simulated successfully using a high-resolution advection contour model (MIMOSA) of Potential Vorticity. Indeed, in mid-May 2002, MIMOSA maps show a polar vortex filament in the middle stratosphere above the 625-K isentropic level and they show also tropical air-masses moving southward (over Irene) in the lower stratosphere between 400-K and 450-K isentropic levels. The winter stratospheric wave driving and its associated localized isentropic mixing leading to the ozone minimum are investigated by means of two diagnostic tools: the Eliassen-Palm flux and the effective diffusivity computed from the European Center for Medium-range Weather Forecasts (ECMWF) fields. The unusual distribution of ozone over Irene during May 2002 in the middle stratosphere is closely connected to the anomalously pre-conditioned structure of the polar vortex at that time of the year. Indeed, the perturbed vortex was typically predisposed

  4. 3D nonrigid registration via optimal mass transport on the GPU

    PubMed Central

    Rehman, Tauseef ur; Haber, Eldad; Pryor, Gallagher; Melonakos, John; Tannenbaum, Allen

    2009-01-01

    In this paper, we present a new computationally efficient numerical scheme for the minimizing flow approach for optimal mass transport (OMT) with applications to non-rigid 3D image registration. The approach utilizes all of the gray-scale data in both images, and the optimal mapping from image A to image B is the inverse of the optimal mapping from B to A. Further, no landmarks need to be specified, and the minimizer of the distance functional involved is unique. Our implementation also employs multigrid, and parallel methodologies on a consumer graphics processing unit (GPU) for fast computation. Although computing the optimal map has been shown to be computationally expensive in the past, we show that our approach is orders of magnitude faster then previous work and is capable of finding transport maps with optimality measures (mean curl) previously unattainable by other works (which directly influences the accuracy of registration). We give results where the algorithm was used to compute non-rigid registrations of 3D synthetic data as well as intra-patient pre-operative and post-operative 3D brain MRI datasets. PMID:19135403

  5. Mass transport around comets and its impact on the seasonal differences in water production rates

    SciTech Connect

    Rubin, M.; Altwegg, K.; Thomas, N.; Fougere, N.; Combi, M. R.; Tenishev, V. M.; Le Roy, L.

    2014-06-20

    Comets are surrounded by a thin expanding atmosphere, and although the nucleus' gravity is small, some molecules and grains, possibly with the inclusion of ices, can get transported around the nucleus through scattering (atoms/molecules) and gravitational pull (grains). Based on the obliquity of the comet, it is also possible that volatile material and icy grains get trapped in regions, which are in shadow until the comet passes its equinox. When the Sun rises above the horizon and the surface starts to heat up, this condensed material starts to desorb and icy grains will sublimate off the surface, possibly increasing the comet's neutral gas production rate on the outbound path. In this paper we investigate the mass transport around the nucleus, and based on a simplified model, we derive the possible contribution to the asymmetry in the seasonal gas production rate that could arise from trapped material released from cold areas once they come into sunlight. We conclude that the total amount of volatiles retained by this effect can only contribute up to a few percent of the asymmetry observed in some comets.

  6. Role of preplasma for shortpulse laser-driven electron transport in mass-limited targets

    NASA Astrophysics Data System (ADS)

    Schollmeier, M.; Sefkow, A. B.; Geissel, M.; Atherton, B.; Corwell, S. E.; Kimmel, M. W.; Rambo, P.; Schwarz, J.; Arefiev, A.; Breizman, B.; Koning, J. M.; Marinak, M. M.

    2012-10-01

    We report on experiments with the Z-Petawatt laser at Sandia National Labs using mm-sized foils and mass-limited targets of various thicknesses. Rear side accelerated proton beam measurements, in combination with simulation results, were used to infer hot electron transport in presence of preplasma. Full-scale, 3D radiation-hydrodynamics simulations of the ns to ps prepulse were performed. Preplasma properties (density profiles, temperatures, charge states) where then imported into a fully explicit and kinetic 2D particle-in-cell code to simulate, 10 ps of the main laser pulse interaction with the preplasma and target at full scale. A comparison of experimental data and numerical data shows outstanding agreement in all measured proton beam parameters, which gives confidence in the simulation results of hot electron transport. Sandia National Labs is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corp., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  7. A multi-physical model for charge and mass transport in a flexible ionic polymer sensor

    NASA Astrophysics Data System (ADS)

    Zhu, Zicai; Asaka, Kinji; Takagi, Kentaro; Aabloo, Alvo; Horiuchi, Tetsuya

    2016-04-01

    An ionic polymer material can generate electrical potential and function as a bio-sensor under a non-uniform deformation. Ionic polymer-metal composite (IPMC) is a typical flexible ionic polymer sensor material. A multi-physical sensing model is presented at first based on the same physical equations in the physical model for IPMC actuator we obtained before. Under an applied bending deformation, water and cation migrate to the direction of outside electrode immediately. Redistribution of cations causes an electrical potential difference between two electrodes. The cation migration is strongly restrained by the generated electrical potential. And the migrated cations will move back to the inner electrode under the concentration diffusion effect and lead to a relaxation of electrical potential. In the whole sensing process, transport and redistribution of charge and mass are revealed along the thickness direction by numerical analysis. The sensing process is a revised physical process of the actuation, however, the transport properties are quite different from those of the later. And the effective dielectric constant of IPMC, which is related to the morphology of the electrode-ionic polymer interface, is proved to have little relation with the sensing amplitude. All the conclusions are significant for ionic polymer sensing material design.

  8. Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

    NASA Astrophysics Data System (ADS)

    Vold, E. L.; Joglekar, A. S.; Ortega, M. I.; Moll, R.; Fenn, D.; Molvig, K.

    2015-11-01

    The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.

  9. Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

    SciTech Connect

    Vold, Erik Lehman; Joglekar, Archis S.; Ortega, Mario I.; Moll, Ryan; Fenn, Daniel; Molvig, Kim

    2015-11-20

    The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion(ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. In this paper, we have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasmaviscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasmaviscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasmaviscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Finally, plasmaviscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.

  10. Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

    DOE PAGES

    Vold, Erik Lehman; Joglekar, Archis S.; Ortega, Mario I.; ...

    2015-11-20

    The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion(ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. In this paper, we have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasmaviscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasmaviscosity andmore » to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasmaviscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Finally, plasmaviscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.« less

  11. Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

    SciTech Connect

    Vold, E. L.; Molvig, K.; Joglekar, A. S.; Ortega, M. I.; Moll, R.; Fenn, D.

    2015-11-15

    The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.

  12. Energy and Mass Transport of Magnetospheric Plasmas during the November 2003 Magnetic Storm

    NASA Technical Reports Server (NTRS)

    Fok, Mei-Chging; Moore, Thomas

    2008-01-01

    Intensive energy and mass transport from the solar wind across the magnetosphere boundary is a trigger of magnetic storms. The storm on 20-21 November 2003 was elicited by a high-speed solar wind and strong southward component of interplanetary magnetic field. This storm attained a minimum Dst of -422 nT. During the storm, some of the solar wind particles enter the magnetosphere and eventually become part of the ring current. At the same time, the fierce solar wind powers strong outflow of H+ and O+ from the ionosphere, as well as from the plasmasphere. We examine the contribution of plasmas from the solar wind, ionosphere and plasmasphere to the storm-time ring current. Our simulation shows, for this particular storm, ionospheric O+ and solar wind ions are the major sources of the ring current particles. The polar wind and plasmaspheric H+ have only minor impacts. In the storm main phase, the strong penetration of solar wind electric field pushes ions from the geosynchronous orbit to L shells of 2 and below. Ring current is greatly intensified during the earthward transport and produces a large magnetic depression in the surface field. When the convection subsides, the deep penetrating ions experience strong charge exchange loss, causing rapid decay of the ring current and fast initial storm recovery. Our simulation reproduces very well the storm development indicated by the Dst index.

  13. Numerical analysis of the diffusive mass transport in brain tissues with applications to optical sensors

    NASA Astrophysics Data System (ADS)

    Neculae, Adrian P.; Otte, Andreas; Curticapean, Dan

    2013-03-01

    In the brain-cell microenvironment, diffusion plays an important role: apart from delivering glucose and oxygen from the vascular system to brain cells, it also moves informational substances between cells. The brain is an extremely complex structure of interwoven, intercommunicating cells, but recent theoretical and experimental works showed that the classical laws of diffusion, cast in the framework of porous media theory, can deliver an accurate quantitative description of the way molecules are transported through this tissue. The mathematical modeling and the numerical simulations are successfully applied in the investigation of diffusion processes in tissues, replacing the costly laboratory investigations. Nevertheless, modeling must rely on highly accurate information regarding the main parameters (tortuosity, volume fraction) which characterize the tissue, obtained by structural and functional imaging. The usual techniques to measure the diffusion mechanism in brain tissue are the radiotracer method, the real time iontophoretic method and integrative optical imaging using fluorescence microscopy. A promising technique for obtaining the values for characteristic parameters of the transport equation is the direct optical investigation using optical fibers. The analysis of these parameters also reveals how the local geometry of the brain changes with time or under pathological conditions. This paper presents a set of computations concerning the mass transport inside the brain tissue, for different types of cells. By measuring the time evolution of the concentration profile of an injected substance and using suitable fitting procedures, the main parameters characterizing the tissue can be determined. This type of analysis could be an important tool in understanding the functional mechanisms of effective drug delivery in complex structures such as the brain tissue. It also offers possibilities to realize optical imaging methods for in vitro and in vivo

  14. Constraints on the Magnitude of Vertical and Lateral Mass Transport on the Moon

    NASA Technical Reports Server (NTRS)

    Mustard, John F.

    1997-01-01

    The role of vertical and lateral mass transport of crustal materials on the observed patterns of lunar surface composition, and the effects on our understanding of the geologic evolution of the planet, have been the subject of much debate in the lunar science community. The primary consensus that emerged from analyses of these processes in the 1970's and 1980's was that vertical and lateral mixing through impact gardening was a relatively inefficient process, and not likely to have contributed significantly to compositional units and variations on the Moon. The supporting evidence for this view is that unit boundaries (e.g. mare-highland contacts, contacts between mare color units) are still apparently quite distinct and sharp despite several aeons of impact activity, and cores from the Apollo landing sites did not show any evidence of widespread homogenization of the surface composition, nor distinct compositional gradients across geologic boundaries. In addition, modeling of vertical and lateral transport generally showed that the effects on composition should be confined to horizontal scales of about a kilometer and vertical scales of a meter. The problem with this consensus is that there is ample contradictory evidence. The fundamental discovery of Wood et al. (1970) was made possible by significant horizontal transport of highland material to the center of Mare Tranquillitatis. The continuous and discontinuous ejecta from the crater Copernicus has clearly influenced the surface composition of a large area of the lunar maria, while rays and ejecta from many highland craters are easily recognized in and around the nearside maria. Despite this contrary evidence, there have been few detailed studies to quantify the amount and rate of material redistribution through impact processes (a notable exception is reported in the paper by Pieters et al, 1985), largely because data adequate to critically analyze this process were lacking. However, the multispectral images

  15. Morphologic Variability of two Adjacent Mass-Transport Deposits: Twin Slides, Gela Basin (Sicily Channel).

    NASA Astrophysics Data System (ADS)

    Minisini, D.; Trincardi, F.; Asioli, A.; Canu, M.; Foglini, F.

    2006-12-01

    Integrating geophysical, sedimentological, structural and paleontological data, we reconstruct the age, size and internal geometry of two adjacent and recent mass-transport deposits (Twin Slides) exposed on the seafloor of Gela Basin (Sicily Channel). Twin Slides are coeval (late-Holocene), and were likely triggered by an earthquake. Twin Slides originated from the mobilization of Pleistocene slope units, are only 6 km apart from each other, have their headscarps in similar water depth (230 m), and have a comparable run out distance (ca. 10 km). Both slides suggest a multistage evolution, but differ in internal organization and morphological expression. The northern slide shows a deposit characterised by pressure ridges in the toe region suggesting a component of plastic deformation, while the southern slide is characterised by large blocks and a reduced thickness of displaced masses. We ascribe the difference in deformation style and resulting morphology to the stratigraphic architecture of the Pleistocene progradational units involved in failure. In the case of the blocky southern slide the units affected by failure are slightly older (Eemian or pre-Emian) and more consolidated; furthermore, in the area where the headscarp is located these units appear affected by shallow faulting likely resulting in the definition of large blocks. The northern slide, instead, affects progradational units of the Last Glacial Maximum in an area where these units are more than 100 m thick and, possibly, underconsolidated.

  16. Back to the primordial universe by a monge-ampere-kantorovich mass transportation method

    NASA Astrophysics Data System (ADS)

    Frisch, U.

    2003-04-01

    The Monge-Kantorovich mass transportation problem dates back to work by Monge in 1781 on how to optimally move earth from one place to another, knowing only the initial and final landscapes, the cost being a prescribed function of the distance travelled by "molecules" of earth. We solve the cosmological reconstruction problem of mapping the present locations of (mostly dark) matter, to their primordial locations, knowing only the current field of mass density, e.g. from a full-sky galaxy catalogue or a numerical simulation. Under the assumption that the map is close to potential, we reduce the problem to solving a nonlinear partial differential equation, originally written by Ampere in 1820, now known as the Monge-Ampere equation. Thanks to recent work by Y. Brenier, this becomes a Monge-Kantorovich problem with quadratic cost function and, in discretised form, an assignment problem: find the pairing between N departure and N arrival points which minimises the sum of the squared distances between paired points. The latter can be solved very efficiently by the auction algorithm of Bertsekas. When tested against N-body cosmological simulations, excellent reconstruction is obtained above a few megaparsecs. Based on the paper Frisch-Matarrese-Mohayaee-Sobolevski Nature 417, 260-262 (16 May 2002).

  17. Dynamics and mass transport of solutal convection in a closed porous media system

    NASA Astrophysics Data System (ADS)

    Wen, Baole; Akhbari, Daria; Hesse, Marc

    2016-11-01

    Most of the recent studies of CO2 sequestration are performed in open systems where the constant partial pressure of CO2 in the vapor phase results in a time-invariant saturated concentration of CO2 in the brine (Cs). However, in some closed natural CO2 reservoirs, e.g., Bravo Dome in New Mexico, the continuous dissolution of CO2 leads to a pressure drop in the gas that is accompanied by a reduction of Cs and thereby affects the dynamics and mass transport of convection in the brine. In this talk, I discuss the characteristics of convective CO2 dissolution in a closed system. The gas is assumed to be ideal and its solubility given by Henry's law. An analytical solution shows that the diffusive base state is no longer self-similar and that diffusive mass transfer declines rapidly. Scaling analysis reveals that the volume ratio of brine and gas η determines the behavior of the system. DNS show that no constant flux regime exists for η > 0 nevertheless, the quantity F /Cs2 remains constant, where F is the dissolution flux. The onset time is only affected by η when the Rayleigh number Ra is small. In this case, the drop in Cs during the initial diffusive regime significantly reduces the effective Ra and therefore delays the onset.

  18. Interpolation of longitudinal shape and image data via optimal mass transport

    NASA Astrophysics Data System (ADS)

    Gao, Yi; Zhu, Liang-Jia; Bouix, Sylvain; Tannenbaum, Allen

    2014-03-01

    Longitudinal analysis of medical imaging data has become central to the study of many disorders. Unfortunately, various constraints (study design, patient availability, technological limitations) restrict the acquisition of data to only a few time points, limiting the study of continuous disease/treatment progression. Having the ability to produce a sensible time interpolation of the data can lead to improved analysis, such as intuitive visualizations of anatomical changes, or the creation of more samples to improve statistical analysis. In this work, we model interpolation of medical image data, in particular shape data, using the theory of optimal mass transport (OMT), which can construct a continuous transition from two time points while preserving "mass" (e.g., image intensity, shape volume) during the transition. The theory even allows a short extrapolation in time and may help predict short-term treatment impact or disease progression on anatomical structure. We apply the proposed method to the hippocampus-amygdala complex in schizophrenia, the heart in atrial fibrillation, and full head MR images in traumatic brain injury.

  19. Mass transport enhancement in annular-shaped lid-driven bioreactor.

    PubMed

    Al-Shannag, Mohammad

    2012-08-01

    The current study investigated numerically the two-dimensional (2D) incompressible flow and mass transfer in a lid-driven cavity of annular geometry accompanied by enzymatic surface-reactions. The lid-driven bioreactor had a square cross-section of (H × H) and a radius of curvature of r (c). This flow configuration gives the opportunity to evaluate effects of curvature as well as operational parameters on the bioreactor performance. For forced-convection, conservation equations were solved numerically, using fourth-order finite volume schemes, to identify the 2D flow structure and concentration distribution of substrate within the bioreactor. For pure diffusion, analytical solution was obtained. Substrate transfer rates were presented in terms of Sherwood number. While, effectiveness factor was computed to evaluate the force-convection contribution over pure molecular diffusion. Mass-transfer against surface-reaction resistance was estimated via Damkohler number. Results indicate the positive role of increasing Peclet number, Reynolds number, and radius of curvature in enhancing the substrate transport process.

  20. Experimental Investigation of Mass Transport, Dynamics, and Stirring in Isolated Thermal Plumes

    NASA Astrophysics Data System (ADS)

    Newsome, William H.

    2011-12-01

    Significant differences exist between isotopic signatures of typical mid-ocean ridge basalts and those associated with many ocean islands, with ocean island basalts (OIB) generally exhibiting more variability in trace element concentrations and a bias towards enrichment in more primitive isotopes in sonic cases. Such observations coupled with other geophysical evidence have been used to suggest that. OIB's are surface manifestations of upwellings originating in the deep interior near the core-mantle boundary that interact with distinct geochemical reservoirs as material is transported from the Earth's interior to the surface. Although many have studied the chemistry and dynamics of these mantle plumes, fundamental questions remain. Lagrangian coherent structures and elements of dynamical systems theory are used to extract key material lines and surfaces in isolated laminar plumes. These structures are shown to provide a taxonomic picture of plumes operating in different regimes, to govern how the plume interacts with the ambient during its ascent, and to have a pronounced effect on the origin of mass transported by the plume. A metric is developed to provide a means of predicting the morphology of mass transported by a general flow, and the rise velocity of the starting plume is used to investigate time scales for liftoff. All investigations are conducted using a series of experiments and numerical models where laminar, thermal plumes are generated in a high Prandtl number fluid having strongly temperature dependent viscosity. Experimental data are acquired using a custom-built stereoscopic particle image velocimetry with thermochromic liquid crystals to measure the 3D flow and temperature fields within the tank. A hybrid particle image particle tracking velocimetry scheme is presented which provides improved robustness to particle pattern deformation when using PIV techniques. In agreement with others, we find starting plumes rise with an essentially constant

  1. Mass transport of heavy metal ions and radon in gels used as sealing agents in containment technologies

    SciTech Connect

    Lakatos, I.; Bauer, K.; Lakatos-Szabo, J.; Kretzschmar, H.J.

    1997-12-31

    The diffusion and hydrodynamic mass transport of multivalent cations, mostly Cr(III) and Cr(VI) ions and radon in polymer/silicate gels and Montanwax emulsions were studied. It was concluded that the self-conforming gels may decrease the hydrodynamic mass transport in porous and fractured media by 4-6 orders of magnitude. In water saturated systems, however, the diffusion transport can be restricted by hydrogels only to a moderate extent. On the other hand, the high and selective retention capacity of gels towards different diffusing species may open new vistas in the sealing technologies. Similar results were obtained for transport phenomena of radon. The almost perfect quenching process of radon and its nuclides in gels and emulsions further enhances the positive effects of the encapsulation methods. The laboratory experiments provided valuable new information to design the different containment technologies.

  2. 41 CFR 102-34.210 - May I use a Government motor vehicle for transportation between places of employment and mass...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...

  3. 41 CFR 102-34.210 - May I use a Government motor vehicle for transportation between places of employment and mass...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...

  4. 41 CFR 102-34.210 - May I use a Government motor vehicle for transportation between places of employment and mass...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...

  5. 41 CFR 102-34.210 - May I use a Government motor vehicle for transportation between places of employment and mass...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...

  6. 41 CFR 102-34.210 - May I use a Government motor vehicle for transportation between places of employment and mass...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... motor vehicle for transportation between places of employment and mass transit facilities? 102-34.210... of employment and mass transit facilities? Yes, you may use a Government motor vehicle for transportation between places of employment and mass transit facilities under the following conditions: (a)...

  7. Mass Transport Deposits in the Santaren Channel: Distribution, Characteristics, and Potential Triggering Mechanisms

    NASA Astrophysics Data System (ADS)

    Schnyder, J.

    2015-12-01

    Submarine slope failures are a likely cause for tsunami generation along the East U.S. coast. A possible source are the large slope failures along western Great Bahama Bank (GBB). Numerical models simulate tsunami generation and propagation through the Straits of Florida, caused by these Pleistocene mass wasting events. In order to estimate the likelihood and extent of future landslides, distribution, characteristics, and possible triggering mechanisms of previous failures and their associated mass transport deposits (MTD) have to be investigated. In 2013, the University of Hamburg acquired 2D high-resolution multichannel seismic data, multibeam data, and subbottom profiles inside the Santaren Channel, along the slopes of western GBB and Cay Sal Bank (CSB). The two platforms are different in two ways. CSB is part of the Cuban Fold and Thrust Belt while GBB is situated in a tectonically quiet zone. In addition, the slopes of western GBB are on the leeward side of the bank, while the eastern slopes of CSB are in a windward position. Differences in nature and size of mass wasting events between the Cay Sal side and the western GBB side of the dataset show how influential the tectonically active Cuban Fold and Thrust Belt is to the generation of large MTDs in this area. In the study area, the slope failures can be divided in two categories; small-scale in situ failures with high frequencies on the slopes, dominant on the western GBB side, and large landslides with a lower frequency, but higher volumes and transport distances on the toe of the slope and in the basin, dominant on the Cay Sal side. The distribution of in situ failures, such as slump and debris flow alternation, shows the interplay between high and low inner strength of the sediment, respectively. On the other hand, large MTDs caused by submarine landslides suggest movement in an unconfined manner. Internal sediment preconditions derived from sea level oscillations are suggested as triggering mechanisms

  8. Adriatic water masses, their rates of formation and transport through the Otranto Strait

    NASA Astrophysics Data System (ADS)

    Vilibić, Ivica; Orlić, Mirko

    2002-08-01

    The paper examines dense water formation in the South Adriatic by analysing temperature, salinity and dissolved oxygen data collected during six along-Adriatic cruises carried out from the Jabuka Pit to the Otranto Strait. The least-squares tracer analysis method is applied to distinguish the fractions of the four characteristic deep, dense water masses of the Adriatic Sea. Two types of dense water generation are considered: (1) shelf type occurring during cold and dry winters in the North Adriatic and resulting in the North Adriatic dense water (NAdDW) which partially transforms to the Middle Adriatic dense water (MAdDW) on its way along the Italian shelf to the Bari Canyon, where it interacts with topography, violently mixes and sinks; and (2) deep-convection type occurring in the centre of the South Adriatic Pit, generating dense water which reaches down to 800 m, fills the bottom and enters the Ionian Sea through the Otranto Strait. Both processes are visible in the July 1976 data, as the previous winter was cold (February) and relatively dry over the whole Adriatic basin. Both types of processes can influence the bottom layer of the Otranto Strait, where the fraction of shelf-type dense water generated in the North and Middle Adriatic was occasionally observed along with the fraction of water generated by deep convection in the South Adriatic. During the non-generative period, the cyclonic South Adriatic Gyre moved more to the northwest in general, as the Levantine intermediate water (LIW) occupied southeastern part of the South Adriatic Pit. However, such behaviour was not observed in January 1980, when LIW filled much of the Adriatic, thus diminishing density gradients in the South Adriatic. By applying a simple box model of water masses, it is estimated that the decay time of the Adriatic water masses equals 26 months, whereas transport of the Adriatic deep water (ADW) in the Otranto Strait amounted to 0.34 Sv during summer 1975. In the winter 1974/75 the

  9. Constraining the efficiency of angular momentum transport with asteroseismology of red giants: the effect of stellar mass

    NASA Astrophysics Data System (ADS)

    Eggenberger, P.; Lagarde, N.; Miglio, A.; Montalbán, J.; Ekström, S.; Georgy, C.; Meynet, G.; Salmon, S.; Ceillier, T.; García, R. A.; Mathis, S.; Deheuvels, S.; Maeder, A.; den Hartogh, J. W.; Hirschi, R.

    2017-02-01

    Context. Constraints on the internal rotation of red giants are now available thanks to asteroseismic observations. Preliminary comparisons with rotating stellar models indicate that an undetermined additional process for the internal transport of angular momentum is required in addition to purely hydrodynamic processes. Aims: We investigate how asteroseismic measurements of red giants can help us characterize the additional transport mechanism. Methods: We first determine the efficiency of the missing transport mechanism for the low-mass red giant KIC 7341231 by computing rotating models that include an additional viscosity corresponding to this process. We then discuss the change in the efficiency of this transport of angular momentum with the mass, metallicity, and evolutionary stage in the light of the corresponding viscosity determined for the more massive red giant KIC 8366239. Results: In the case of the low-mass red giant KIC 7341231, we find that the viscosity corresponding to the additional mechanism is constrained to the range νadd = 1 × 103-1.3 × 104 cm2 s-1. This constraint on the efficiency of the unknown additional transport mechanism during the post-main sequence is obtained independently of any specific assumption about the modeling of rotational effects during the pre-main sequence and the main sequence (in particular, the braking of the surface by magnetized winds and the efficiency of the internal transport of angular momentum before the post-main-sequence phase). When we assume that the additional transport mechanism is at work during the whole evolution of the star together with a solar-calibrated braking of the surface by magnetized winds, the range of νadd is reduced to 1-4 × 103 cm2 s-1. In addition to being sensitive to the evolutionary stage of the star, the efficiency of the unknown process for internal transport of angular momentum increases with the stellar mass.

  10. Coupled effects of temperature and mass transport on the isotope fractionation of zinc during electroplating

    NASA Astrophysics Data System (ADS)

    Black, Jay R.; John, Seth G.; Kavner, Abby

    2014-01-01

    The isotopic composition of zinc metal electrodeposited on a rotating disc electrode from a Zn-citrate aqueous solution was investigated as a function of overpotential (electrochemical driving force), temperature, and rotation rate. Zn metal was measured to be isotopically light with respect to Zn+2 in solution, with observed fractionations varying from Δ66/64Znmetal-aqueous = -1.0‰ to -3.9‰. Fractionation varies continuously as a function of a dimensionless parameter described by the ratio of observed deposition rate to calculated mass-transport limiting rate, where larger fractionations are observed at lower deposition rates, lower temperature, and at faster electrode rotation rates. Thus, the large fractionation and its rate dependence is interpreted as a competition between the two kinetic processes with different effective activation energies: mass-transport-limited (diffusion limited) kinetics with a large activation energy, which creates small fractionations close to the predicted diffusive fractionation; and electrochemical deposition kinetics, with a smaller effective activation energy, which creates large fractionations at low deposition rates and high hydrodynamic fluxes of solute to the electrode. The results provide a framework for predicting isotope fractionation in processes controlled by two competing reactions with different kinetic isotope effects. Light isotopes are electroplated. In all cases light stable isotopes of the metals are preferentially electroplated, with mass-dependent behavior evident where three or more isotopes are measured. Fractionation is time-independent, meaning that the fractionation factor does not vary with the extent of reaction. In most of our experiments, we have controlled the extent of reaction such that only a small amount of metal is deposited from the stock solution, thus avoiding significant evolution of the reservoir composition. In such experiments, the observed isotope fractionation is constant as a

  11. Fractures as Advective Conduits at the Earth Atmosphere Interface

    NASA Astrophysics Data System (ADS)

    Dragila, M. I.; Weisbrod, N.; Nachshon, U.; Kamai, T.

    2012-12-01

    Understanding gas exchange between the Earth's upper crust and the atmosphere is vital and necessary because this phenomenon controls to a large extent many important processes including, the water cycle, agricultural activities, greenhouse gas emissions and more. From a hydrological aspect, water vapor transport is an extremely important process related to Earth-atmosphere gas exchange because it affects above ground water vapor concentration, soil water content and soil salinity. Traditionally, diffusion was considered the main mechanism of gas exchange between the atmosphere and vadose zone, driven by gas concentration gradients. While this assumption may be correct for many porous media, our laboratory and field-scale studies have shown that advective gas transport mechanisms are governing these fluxes in fractured rocks and cracked soils. Convection driven by thermal gradients (free convection) and wind induced (forced convection) were explored and both were found to play a major role in Earth-atmosphere gas exchange. Long-term laboratory experiments using fracture simulators in a customized climate controlled laboratory have shown that thermal convection occurs when nighttime thermal conditions prevail. This convective venting significantly enhances evaporation and subsequently salt precipitation on the fracture walls. Experiment results were used to develop an empirical relationship between temperature gradients, fracture aperture and convective gas flux through the fracture. Theoretical calculations show that thermal convection is indeed likely to play a major role in evaporation from fractures and can explain enhanced salt accumulation observed in surface-exposed fractures. Long-term field measurements, carried out continuously for 5+ years in a single fracture in the Israeli Negev Desert, verified the development of air convection cycles of 10-18 hours duration on a daily basis, with a peak in both convective flux and duration during the winter. During

  12. Atomistic Simulations of Mass and Thermal Transport in Oxide Nuclear Fuels

    SciTech Connect

    Andersson, Anders D.; Uberuaga, Blas P.; Du, Shiyu; Liu, Xiang-Yang; Nerikar, Pankaj; Stanek, Christopher R.; Tonks, Michael; Millet, Paul; Biner, Bulent

    2012-06-04

    In this talk we discuss simulations of the mass and thermal transport in oxide nuclear fuels. Redistribution of fission gases such as Xe is closely coupled to nuclear fuel performance. Most fission gases have low solubility in the fuel matrix, specifically the insolubility is most pronounced for large fission gas atoms such as Xe, and as a result there is a significant driving force for segregation of gas atoms to grain boundaries or dislocations and subsequently for nucleation of gas bubbles at these sinks. The first step of the fission gas redistribution is diffusion of individual gas atoms through the fuel matrix to existing sinks, which is governed by the activation energy for bulk diffusion. Fission gas bubbles are then formed by either separate nucleation events or by filling voids that were nucleated at a prior stage; in both cases their formation and latter growth is coupled to vacancy dynamics and thus linked to the production of vacancies via irradiation or thermal events. In order to better understand bulk Xe behavior (diffusion mechanisms) in UO{sub 2{+-}x} we first calculate the relevant activation energies using density functional theory (DFT) techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism, though other alternatives may exist in high irradiation fields. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next a continuum transport model for Xe and U is formulated based on the diffusion mechanisms established from DFT. After combining this model with descriptions of the interaction between Xe and grain

  13. Mass Conservation in a Chemical Transport Model and its Effect on CO2 and SF6 Simulations

    NASA Technical Reports Server (NTRS)

    Zhu, Z.; Weaver, C.; Kawa, S. R.; Douglass, A. R.; Bhartia, P. K. (Technical Monitor)

    2002-01-01

    Chemical transport models (CTMs) must conserve mass to be useful for applications involving assessment of the effect of various pollutants on the troposphere and stratosphere. Furthermore, calculations of the evolution of constituents such as SF6 are used to evaluate overall model transport, and interpretation of such simulations is clouded if mass conservation is not assured. For realistic simulations or predictions, it is crucial that constituents are not produced or lost by transport or other processes in the CTMs. Analysis of CO2 and SF6 experiments using a CTM shows that problems with mass conservation can seriously degrade the simulations. Failure to conserve mass results from inconsistency of the surface pressure tendency and the divergence of horizontal mass flux when the model is forced by assimilated meteorological data. We have developed an effective method to eliminate the inconsistency by modifying the divergent part of the wind field. The changes in the wind fields are quite small but the impact on mass conservation is large. Parameterizations of physical processes such as convection or turbulent transport can also affect mass conservation. The lack of conservation is small but accumulates when integrations are lengthy such as required for SF6. This lack of conservation is found using winds from either a GCM or from an assimilation system. A simple adjustment removes much of the inaccuracy in the convective parameterization. A CO2 simulation using assimilated winds from the most recent version of the Goddard Earth Observing System Data Assimilation System will be used to illustrate the impact of these transport improvements.

  14. The effect of volume phase changes, mass transport, sunlight penetration, and densification on the thermal regime of icy regoliths

    NASA Technical Reports Server (NTRS)

    Fanale, Fraser P.; Salvail, James R.; Matson, Dennis L.; Brown, Robert H.

    1990-01-01

    The present quantitative modeling of convective, condensational, and sublimational effects on porous ice crust volumes subjected to solar radiation encompasses the effect of such insolation's penetration of visible bandpass-translucent light, but opaque to the IR bandpass. Quasi-steady-state temperatures, H2O mass fluxes, and ice mass-density change rates are computed as functions of time of day and ice depth. When the effects of latent heat and mass transport are included in the model, the enhancement of near-surface temperature due to the 'solid-state greenhouse effect' is substantially diminished. When latent heat, mass transport, and densification effects are considered, however, a significant solid-state greenhouse effect is shown to be compatible with both morphological evidence for high crust strengths and icy shell decoupling from the lithosphere.

  15. An advection-based model to increase the temporal resolution of PIV time series.

    PubMed

    Scarano, Fulvio; Moore, Peter

    A numerical implementation of the advection equation is proposed to increase the temporal resolution of PIV time series. The method is based on the principle that velocity fluctuations are transported passively, similar to Taylor's hypothesis of frozen turbulence. In the present work, the advection model is extended to unsteady three-dimensional flows. The main objective of the method is that of lowering the requirement on the PIV repetition rate from the Eulerian frequency toward the Lagrangian one. The local trajectory of the fluid parcel is obtained by forward projection of the instantaneous velocity at the preceding time instant and backward projection from the subsequent time step. The trajectories are approximated by the instantaneous streamlines, which yields accurate results when the amplitude of velocity fluctuations is small with respect to the convective motion. The verification is performed with two experiments conducted at temporal resolutions significantly higher than that dictated by Nyquist criterion. The flow past the trailing edge of a NACA0012 airfoil closely approximates frozen turbulence, where the largest ratio between the Lagrangian and Eulerian temporal scales is expected. An order of magnitude reduction of the needed acquisition frequency is demonstrated by the velocity spectra of super-sampled series. The application to three-dimensional data is made with time-resolved tomographic PIV measurements of a transitional jet. Here, the 3D advection equation is implemented to estimate the fluid trajectories. The reduction in the minimum sampling rate by the use of super-sampling in this case is less, due to the fact that vortices occurring in the jet shear layer are not well approximated by sole advection at large time separation. Both cases reveal that the current requirements for time-resolved PIV experiments can be revised when information is poured from space to time. An additional favorable effect is observed by the analysis in the frequency

  16. A computational Lagrangian-Eulerian advection remap for free surface flows

    NASA Astrophysics Data System (ADS)

    Ashgriz, Nasser; Barbat, Tiberiu; Wang, Gang

    2004-01-01

    A VOF-based algorithm for advecting free surfaces and interfaces across a 2-D unstructured grid is presented. This algorithm is based on a combination of a Computational Lagrangian-Eulerian Advection Remap and the Volume of the Fluid method (CLEAR-VOF). A set of geometric tools are used to remap the advected shape of the volume fraction from one cell onto the Eulerian fixed unstructured grid. The geometric remapping is used to compute the fluxes onto a group of neighbouring cells of the mesh. These fluxes are then redistributed and corrected to satisfy the conservation of mass. Here, we present methods for developing identification algorithms for surface cells and incorporating them with CLEAR-VOF. The CLEAR-VOF algorithm is then tested for translation of several geometries. It is also incorporated in a finite element based flow solver and tested in a laminar flow over a broad-crested weir and a turbulent flow over a semi-circular obstacle.

  17. STANDING SHOCK INSTABILITY IN ADVECTION-DOMINATED ACCRETION FLOWS

    SciTech Connect

    Le, Truong; Wood, Kent S.; Wolff, Michael T.; Becker, Peter A.; Putney, Joy

    2016-03-10

    Depending on the values of the energy and angular momentum per unit mass in the gas supplied at large radii, inviscid advection-dominated accretion flows can display velocity profiles with either preshock deceleration or preshock acceleration. Nakayama has shown that these two types of flow configurations are expected to have different stability properties. By employing the Chevalier and Imamura linearization method and the Nakayama instability boundary conditions, we discover that there are regions of parameter space where disks/shocks with outflows can be stable or unstable. In regions of instability, we find that preshock deceleration is always unstable to the zeroth mode with zero frequency of oscillation, but is always stable to the fundamental mode and overtones. Furthermore, we also find that preshock acceleration is always unstable to the zeroth mode and that the fundamental mode and overtones become increasingly less stable as the shock location moves away from the horizon when the disk half-height expands above ∼12 gravitational radii at the shock radius. In regions of stability, we demonstrate the zeroth mode to be stable for the velocity profiles that exhibit preshock acceleration and deceleration. Moreover, for models that are linearly unstable, our model suggests the possible existence of quasi-periodic oscillations (QPOs) with ratios 2:3 and 3:5. These ratios are believed to occur in stellar and supermassive black hole candidates, for example, in GRS 1915+105 and Sgr A*, respectively. We expect that similar QPO ratios also exist in regions of stable shocks.

  18. Modeling highly transient flow, mass, and heat transport in the Chattahoochee River near Atlanta, Georgia

    USGS Publications Warehouse

    Jobson, Harvey E.; Keefer, Thomas N.

    1979-01-01

    A coupled flow-temperature model has been developed and verified for a 27.9-km reach of the Chattahoochee River between Buford Dam and Norcross, Ga. Flow in this reach of the Chattahoochee is continuous but highly regulated by Buford Dam, a flood-control and hydroelectric facility located near Buford, Ga. Calibration and verification utilized two sets of data collected under highly unsteady discharge conditions. Existing solution techniques, with certain minor improvements, were applied to verify the existing technology of flow and transport modeling. The linear, implicit finite-difference flow model was calibrated by use of a depth profile obtained at steady low flow and unsteady flow data obtained in March 1976. During the calibration period, the model was generally able to reproduce observed stages to within 0.15 m and discharges at less than 100 m 3 /s, to within 5 percent. Peak discharges of about 200 m 3 /s were under-estimated by about 20 percent. During the verification period, October 1975, the flow model reproduced observed stage changes to within about 0.15 m, and its timing and over-all performance was considered to be very good. Dye was added to the upstream end of the river reach at a constant rate while the river flow was highly unsteady. The numerical solution of either the conservative or nonconservative form of the mass-transport equation did an excellent job of simulating the observed concentrations of dye in the river. The temperature model was capable of predicting temperature changes through this reach of as large as 5.8?C with a RMS (root-mean-square) error of 0.32?C in October 1975 and 0.20?C in March 1976. Hydropulsation has a significant effect on the water temperature below Buford Dam. These effects are very complicated because they are quite dependent on the timing of the release with respect to both the time of day and past releases.

  19. Fate, mass balance, and transport of phosphorus in the septic system drainfields.

    PubMed

    Mechtensimer, Sara; Toor, Gurpal S

    2016-09-01

    Septic systems can be a potential source of phosphorus (P) in shallow groundwater. Our objective was to investigate the fate, mass balance, and transport of P in the drainfield of a drip-dispersal septic system. Drainfields were replicated in lysimeters (152.4 cm long, 91.4 cm wide, and 91.4 cm high). Leachate and effluent samples were collected over 67 events (n = 15 daily; n = 52 weekly flow-weighted) and analyzed for total P (TP), orthophosphate (PO4P), and other P (TP - PO4P). Mean TP was 15 mg L(-1) (84% PO4P; 16% other P) in the effluent and 0.16 mg L(-1) (47% PO4P, 53% other P) in the leachate. After one year, 46.8 g of TP was added with effluent and rainfall to each drainfield, of which, <1% leached, 3.8% was taken up by St. Augustine grass, leaving >95% in the drainfield. Effluent dispersal increased water extractable P (WEP) in the drainfield from <5 to >10 mg kg(-1). Using the P sorption maxima of sand (118 mg kg(-1)) and soil (260 mg kg(-1)), we estimated that ∼18% of the drainfield P sorption capacity was saturated after one year of effluent dispersal. We conclude that despite the low leaching potential of P dispersed with effluent in the first year of drainfield operation, a growing WEP pool in the drainfield and low P sorption capacity of Florida's sandy soils may have the potential to transport P to shallow groundwater in long-running septic systems.

  20. The role of advection and diffusion in waste disposal by sea urchin embryos

    NASA Astrophysics Data System (ADS)

    Clark, Aaron; Licata, Nicholas

    2014-03-01

    We determine the first passage probability for the absorption of waste molecules released from the microvilli of sea urchin embryos. We calculate a perturbative solution of the advection-diffusion equation for a linear shear profile similar to the fluid environment which the embryos inhabit. Rapid rotation of the embryo results in a concentration boundary layer of comparable thickness to the length of the microvilli. A comparison of the results to the regime of diffusion limited transport indicates that fluid flow is advantageous for efficient waste disposal.

  1. Least-Squares Spectral Method for the solution of a fractional advection-dispersion equation

    NASA Astrophysics Data System (ADS)

    Carella, Alfredo Raúl; Dorao, Carlos Alberto

    2013-01-01

    Fractional derivatives provide a general approach for modeling transport phenomena occurring in diverse fields. This article describes a Least Squares Spectral Method for solving advection-dispersion equations using Caputo or Riemann-Liouville fractional derivatives. A Gauss-Lobatto-Jacobi quadrature is implemented to approximate the singularities in the integrands arising from the fractional derivative definition. Exponential convergence rate of the operator is verified when increasing the order of the approximation. Solutions are calculated for fractional-time and fractional-space differential equations. Comparisons with finite difference schemes are included. A significant reduction in storage space is achieved by lowering the resolution requirements in the time coordinate.

  2. Mass transport of small retained molecules in polymer-based monolithic columns.

    PubMed

    Gritti, Fabrice; Guiochon, Georges

    2014-10-03

    The mass transport properties of a non-retained (thiourea) and three retained low molecular weight compounds (acetophenone, valerophenone, and octanophenone) along a 4.6mm×45mm PROSWIFT™ RP-1S monolithic column made of rigid cross-linked poly(styrene-divinylbenzene) copolymer was investigated in depth. Accurate protocols (peak parking experiments, measurement of the first and second central moments of peak profiles by numerical integration) combined with the use of validated models of effective diffusion along monolithic structures were applied for the determination of the longitudinal diffusion, the eddy dispersion, and the skeleton-eluent mass transfer resistances due to the finite analyte diffusivity across the polymer skeleton and to the slow absorption kinetics into the polymer volume. Experimental results show by increasing order of importance evidence that the resolution performance of this short and wide polymer-based monolithic HPLC column is limited by the slow analyte diffusivity across the polymer skeleton (smaller than one tenth of the bulk diffusion coefficient for k'>1), its large eddy dispersion HETP (Heddy≃100μm), and the slow rate of absorption (≃10Hz only) in the polymer volume for retained analytes. The column performance could be improved by preparing a more homogeneous material with a rigid internal mesoporous structure. This would provide a column bed having a larger specific surface area, allowing faster analyte diffusion across the mesoporous skeleton, a smaller eddy dispersion HETP, and a faster absorption kinetics in the polymeric monolith than those observed for the currently available materials.

  3. Coastal currents and mass transport of surface sediments over the shelf regions of Monterey Bay, California

    USGS Publications Warehouse

    Wolf, S.C.

    1970-01-01

    southward except near Monterey Canyon which acts as a physiographic barrier and the extreme southern end of the bay where currents are non persistent. Some sediments are also transported offshore by rip currents and other agencies and deposited in deeper, quieter waters. Supply of sediments to the canyon head results in over-filling and steepening with subsequent mass movement of sediments seaward followed by deposition in channels and on the broad deep sea fan. ?? 1970.

  4. Mass transport and electrode accessibility through periodic self-assembled nanoporous silica thin films.

    PubMed

    Wei, Ta-Chen; Hillhouse, Hugh W

    2007-05-08

    Ordered nanoporous silica films have attracted great interest for their potential use to template nanowires for photovoltaics and thermoelectrics. However, it is crucial to develop films such that an electrode under the nanoporous film is accessible to solution species via facile mass transport through well-defined pores. Here, we quantitatively measure the electrode accessibility and the effective species diffusivity for nearly all the known nanoporous silica film structures formed by evaporation-induced self-assembly upon dip-coating or spin-coating. Grazing-angle of incidence small-angle X-ray scattering was used to verify the nanoscale structure of the films and to ensure that all films were highly ordered and oriented. Electrochemical impedance spectroscopy (EIS) was then used to assess the transport properties. A model has been developed that separates the electrode/film kinetics and the film transport properties from the film/solution interface and bulk solution effects. Accounting for this, the accessible area of the nanoporous film coated FTO electrode (1-theta) is obtained from the high-frequency data, while the effective diffusivity of the ferrocene dimethanol (D(FDM)) redox couple is obtained from intermediate frequencies. It was found that the degree of order and orientation in the film, in addition to the symmetry/topology, is a dominant factor that determines these two key parameters. The EIS data show that the (211) oriented double gyroid, (110) oriented distorted body center cubic, and (211) distorted primitive cubic silica films have significant accessibility (larger than 26% of geometric area). However, the double-gyroid films showed the highest diffusivity by over an order of magnitude. Both the (10) oriented 2D hexagonal and (111) oriented rhombohedral films were found to be highly blocking with only small accessibility due to microporosity. The impedance data were also collected to study the stability of the nanoporous silica films in aqueous

  5. Clay with Desiccation Cracks is an Advection Dominated Environment

    NASA Astrophysics Data System (ADS)

    Baram, S.; Kurtzman, D.; Sher, Y.; Ronen, Z.; Dahan, O.

    2012-04-01

    Heavy clay sediments are regarded "safe" from the hydrological point of view due to their low hydraulic conductivities. However, the formation of desiccation cracks in dispersive clays may dramatically change their bulk hydraulic properties. The impact of desiccation cracks on water percolation, dissolved salts and contaminants transport and redox related reactions (microbial ammonium oxidation and denitrification) were investigated in 6 -12 m clay layer near a diary farm waste lagoon. The study implemented unique vadose-zone monitoring systems that enable in-situ measurements of the temporal variation of the sediment's water content along with frequent sampling of the sediment's pore water along the entire vadose zone (> 30 m). Results from four years of continuous measurements showed quick rises in sediment water content following rain events and temporal wastewater overflows. The percolation pattern indicated dominance of preferential flow through a desiccation-cracks network crossing the entire clay sediment layer. High water-propagation velocities (0.4 - 23.6 m h-1) were observed, indicating that the desiccation-crack network remains open and serves as a preferential flow pathway year-round, even at high sediment water content (~0.50 m3 m-3). The rapid percolation bypassed the most bio-geo-active parts of the soil, transporting even highly sorptive contaminants (testosterone and estrogen) in to the deep sections of the vadose zone, accelerating the underlying groundwater contamination. The ammonium and nitrate concentrations in the vadose zone and the high number of nitrifying and denitrifying bacteria (~108 gene copies gdry-sediemt-1, each) found in the sediment indicated that the entire vadose zone is aerated even at high water content conditions (~0.55 m3 m-3). The dissolved salts concentration in the pore-water and the δ2H-H2O and δ18O-H2O values of the pore-water substantially increased with depth (becoming less depleted) in the clay sediment

  6. A two-dimensional coupled flow-mass transport model based on an improved unstructured finite volume algorithm.

    PubMed

    Zhou, Jianzhong; Song, Lixiang; Kursan, Suncana; Liu, Yi

    2015-05-01

    A two-dimensional coupled water quality model is developed for modeling the flow-mass transport in shallow water. To simulate shallow flows on complex topography with wetting and drying, an unstructured grid, well-balanced, finite volume algorithm is proposed for numerical resolution of a modified formulation of two-dimensional shallow water equations. The slope-limited linear reconstruction method is used to achieve second-order accuracy in space. The algorithm adopts a HLLC-based integrated solver to compute the flow and mass transport fluxes simultaneously, and uses Hancock's predictor-corrector scheme for efficient time stepping as well as second-order temporal accuracy. The continuity and momentum equations are updated in both wet and dry cells. A new hybrid method, which can preserve the well-balanced property of the algorithm for simulations involving flooding and recession, is proposed for bed slope terms approximation. The effectiveness and robustness of the proposed algorithm are validated by the reasonable good agreement between numerical and reference results of several benchmark test cases. Results show that the proposed coupled flow-mass transport model can simulate complex flows and mass transport in shallow water.

  7. Geoelectrical evidence of bicontinuum transport in groundwater

    USGS Publications Warehouse

    Singha, K.; Day-Lewis, F. D.; Lane, J.W.

    2007-01-01

    Bicontinuum models and rate-limited mass transfer (RLMT) explain complex transport behavior (e.g., long tailing and rebound) in heterogeneous geologic media, but experimental verification is problematic because geochemical samples represent the mobile component of the pore space. Here, we present geophysical evidence of RLMT at the field scale during an aquifer-storage and recovery experiment in a fractured limestone aquifer in Charleston, South Carolina. We observe a hysteretic relation between measurements of porefluid conductivity and bulk electrical conductivity; this hysteresis contradicts advective-dispersive transport and the standard petrophysical model relating pore-fluid and bulk conductivity, but can be explained by considering bicontinuum transport models that include first-order RLMT. Using a simple numerical model, we demonstrate that geoelectrical measurements are sensitive to bicontinuum transport and RLMT parameters, which are otherwise difficult to infer from direct, h