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Sample records for aerosol extinction product

  1. Recent Improvements to CALIOP Level 3 Aerosol Profile Product for Global 3-D Aerosol Extinction Characterization

    NASA Astrophysics Data System (ADS)

    Tackett, J. L.; Getzewich, B. J.; Winker, D. M.; Vaughan, M. A.

    2015-12-01

    With nine years of retrievals, the CALIOP level 3 aerosol profile product provides an unprecedented synopsis of aerosol extinction in three dimensions and the potential to quantify changes in aerosol distributions over time. The CALIOP level 3 aerosol profile product, initially released as a beta product in 2011, reports monthly averages of quality-screened aerosol extinction profiles on a uniform latitude/longitude grid for different cloud-cover scenarios, called "sky conditions". This presentation demonstrates improvements to the second version of the product which will be released in September 2015. The largest improvements are the new sky condition definitions which parse the atmosphere into "cloud-free" views accessible to passive remote sensors, "all-sky" views accessible to active remote sensors and "cloudy-sky" views for opaque and transparent clouds which were previously inaccessible to passive remote sensors. Taken together, the new sky conditions comprehensively summarize CALIOP aerosol extinction profiles for a broad range of scientific queries. In addition to dust-only extinction profiles, the new version will include polluted-dust and smoke-only extinction averages. A new method is adopted for averaging dust-only extinction profiles to reduce high biases which exist in the beta version of the level 3 aerosol profile product. This presentation justifies the new averaging methodology and demonstrates vertical profiles of dust and smoke extinction over Africa during the biomass burning season. Another crucial advancement demonstrated in this presentation is a new approach for computing monthly mean aerosol optical depth which removes low biases reported in the beta version - a scenario unique to lidar datasets.

  2. Aerosol extinction measurements with CO2-lidar

    NASA Technical Reports Server (NTRS)

    Hagard, Arne; Persson, Rolf

    1992-01-01

    With the aim to develop a model for infrared extinction due to aerosols in slant paths in the lower atmosphere we perform measurements with a CO2-lidar. Earlier measurements with a transmissometer along horizontal paths have been used to develop relations between aerosol extinction and meteorological parameters. With the lidar measurements we hope to develop corresponding relations for altitude profiles of the aerosol extinction in the infrared. An important application is prediction of detection range for infrared imaging systems.

  3. Study of MPLNET-Derived Aerosol Climatology over Kanpur, India, and Validation of CALIPSO Level 2 Version 3 Backscatter and Extinction Products

    NASA Technical Reports Server (NTRS)

    Misra, Amit; Tripathi, S. N.; Kaul, D. S.; Welton, Ellsworth J.

    2012-01-01

    The level 2 aerosol backscatter and extinction profiles from the NASA Micropulse Lidar Network (MPLNET) at Kanpur, India, have been studied from May 2009 to September 2010. Monthly averaged extinction profiles from MPLNET shows high extinction values near the surface during October March. Higher extinction values at altitudes of 24 km are observed from April to June, a period marked by frequent dust episodes. Version 3 level 2 Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) aerosol profile products have been compared with corresponding data from MPLNET over Kanpur for the above-mentioned period. Out of the available backscatter profiles, the16 profiles used in this study have time differences less than 3 h and distances less than 130 km. Among these profiles, four cases show good comparison above 400 m with R2 greater than 0.7. Comparison with AERONET data shows that the aerosol type is properly identified by the CALIOP algorithm. Cloud contamination is a possible source of error in the remaining cases of poor comparison. Another source of error is the improper backscatter-to-extinction ratio, which further affects the accuracy of extinction coefficient retrieval.

  4. An Accuracy Assessment of the CALIOP/CALIPSO Version 2/Version 3 Daytime Aerosol Extinction Product Based on a Detailed Multi-Sensor, Multi-Platform Case Study

    NASA Technical Reports Server (NTRS)

    Kacenelenbogen, M.; Vaughan, M. A.; Redemann, J.; Hoff, R. M.; Rogers, R. R.; Ferrare, R. A.; Russell, P. B.; Hostetler, C. A.; Hair, J. W.; Holben, B. N.

    2011-01-01

    The Cloud Aerosol LIdar with Orthogonal Polarization (CALIOP), on board the CALIPSO platform, has measured profiles of total attenuated backscatter coefficient (level 1 products) since June 2006. CALIOP s level 2 products, such as the aerosol backscatter and extinction coefficient profiles, are retrieved using a complex succession of automated algorithms. The goal of this study is to help identify potential shortcomings in the CALIOP version 2 level 2 aerosol extinction product and to illustrate some of the motivation for the changes that have been introduced in the next version of CALIOP data (version 3, released in June 2010). To help illustrate the potential factors contributing to the uncertainty of the CALIOP aerosol extinction retrieval, we focus on a one-day, multi-instrument, multiplatform comparison study during the CALIPSO and Twilight Zone (CATZ) validation campaign on 4 August 2007. On that day, we observe a consistency in the Aerosol Optical Depth (AOD) values recorded by four different instruments (i.e. spaceborne MODerate Imaging Spectroradiometer, MODIS: 0.67 and POLarization and Directionality of Earth s Reflectances, POLDER: 0.58, airborne High Spectral Resolution Lidar, HSRL: 0.52 and ground-based AErosol RObotic NETwork, AERONET: 0.48 to 0.73) while CALIOP AOD is a factor of two lower (0.32 at 532 nm). This case study illustrates the following potential sources of uncertainty in the CALIOP AOD: (i) CALIOP s low signal-to-noise ratio (SNR) leading to the misclassification and/or lack of aerosol layer identification, especially close to the Earth s surface; (ii) the cloud contamination of CALIOP version 2 aerosol backscatter and extinction profiles; (iii) potentially erroneous assumptions of the aerosol extinction-to-backscatter ratio (Sa) used in CALIOP s extinction retrievals; and (iv) calibration coefficient biases in the CALIOP daytime attenuated backscatter coefficient profiles. The use of version 3 CALIOP extinction retrieval for our case

  5. Wavelength dependence of aerosol extinction coefficient for stratospheric aerosols

    NASA Technical Reports Server (NTRS)

    Yue, Glenn K.

    1986-01-01

    A simple empirical formula for the wavelength dependence of the aerosol extinction coefficient is proposed. The relationship between the constants in the formula and the variable parameter in the aerosol size distribution is explicitly expressed. Good agreement is found between the extinction coefficients calculated from the proposed formula and that calculated from Mie theory. The proposed expression is shown to be better than the Angstroem formula commonly used by atmospheric scientists.

  6. In Situ Measurement of Aerosol Extinction

    NASA Technical Reports Server (NTRS)

    Strawa, Anthony W.; Castaneda, R.; Owano, T. G.; Bear, D.; Gore, Warren J. (Technical Monitor)

    2001-01-01

    Aerosols are important contributors to the radiative forcing in the atmosphere. Much of the uncertainty in our knowledge of climate forcing is due to uncertainties in the radiative forcing due to aerosols as illustrated in the IPCC reports of the last ten years. Improved measurement of aerosol optical properties, therefore, is critical to an improved understanding of atmospheric radiative forcing. Additionally, attempts to reconcile in situ and remote measurements of aerosol radiative properties have generally not been successful. This is due in part to the fact that it has been impossible to measure aerosol extinction in situ in the past. In this presentation we introduce a new instrument that employs the techniques used in cavity ringdown spectroscopy to measure the aerosol extinction and scattering coefficients in situ. A prototype instrument has been designed and tested in the lab and the field. It is capable of measuring aerosol extinction coefficient to 2x10(exp -6) per meter. This prototype instrument is described and results are presented.

  7. Humidity Dependent Extinction of Clay Aerosols

    NASA Astrophysics Data System (ADS)

    Greenslade, M. E.; Attwood, A. R.

    2010-12-01

    Aerosols play an important role in the Earth’s radiative balance by directly scattering and absorbing radiation. The magnitude of aerosol forcing can be altered by changes in relative humidity which cause aerosol size, shape and refractive index to vary. To quantify these effects, a custom cavity ring down instrument operated at 532 nm with two sample channels measures aerosols extinction under dry conditions and at elevated humidity. The optical growth, fRH(ext), is determined as a ratio of the extinction cross section at high relative humidity to that under dry conditions. Three key clay components of mineral dust and mixtures of clay components with ammonium sulfate are investigated using this method. Experimentally obtained optical growth is compared with physical growth factors from the literature and our work determined using several different techniques. Further, Mie theory calculations based on published optical constants are compared with experimental results. Differences between theory and experiment will be discussed.

  8. Aerosol transport in the coastal environment and effects on extinction

    NASA Astrophysics Data System (ADS)

    Vignati, Elizabetta; de Leeuw, Gerrit; Berkowicz, Ruwim

    1998-11-01

    The aerosol in the coastal environment consists of a complicated mixture of anthropogenic and rural aerosol generated over land, and sea spray aerosol. Also, particles are generate dover sea by physical and chemical processes and the chemical composition may change due to condensation/evaporation of gaseous materials. The actual composition is a function of air mass history and fetch. At the land-sea transition the continental sources cease to exist, and thus the concentrations of land-based particles and gases will gradually decrease. At the same time, sea spray is generated due to the interaction between wind and waves in a developing wave field. A very intense source for sea spray aerosol is the surf zone. Consequently, the aerosol transported over sea in off-shore winds will abruptly charge at the land-sea transition and then gradually loose its continental character, while also the contribution of the surf-generated aerosol will decrease. The latter will be compensated, at least in part, by the production of sea spray aerosol. A Coastal Aerosol Transport model is being developed describing the evolution of the aerosol size distribution in an air column advected from the coast line over sea in off-shore winds. Both removal and production are taken into account. The result are applied to estimate the effect of the changing size distribution on the extinction coefficients. In this contribution, preliminary results are presented from a study of the effects of the surf-generated aerosol and the surface production.

  9. Infrared Extinction Spectra of Mineral Dust Aerosol

    NASA Astrophysics Data System (ADS)

    Kleiber, P.; Laskina, O.; Alexander, J. M.; Young, M.; Grassian, V. H.

    2012-12-01

    Mineral dust aerosol affects the atmosphere by absorbing and scattering radiation and plays an important role in the Earth's radiative budget. The effect of atmospheric dust on climate is studied by various remote sensing techniques that use measurements from narrow band IR channels of satellites to determine key atmospheric properties. Therefore, it is essential to take radiative effects of mineral dust aerosol into account to correctly process remote sensing data. As aerosols are transported through the atmosphere they undergo aging and heterogeneous chemistry. This leads to changes in their optical properties and their effects on climate. In this study we carried out spectral simulations using both Mie theory and solutions derived in the Rayleigh regime for authentic dust samples and several processed components of mineral dust. Simulations of the extinction based on Mie theory shows that it does not accurately reproduce the peak position and band shape of the prominent IR resonance features. Errors in the simulated peak position and the line shape associated with Mie theory can adversely affect determination of mineral composition based on IR satellite data. Analytic solutions for various shapes derived from Rayleigh theory offer a better fit to the major band features of the spectra, therefore the accuracy of modeling atmospheric dust properties can be improved by using these analytic solutions. It is also important to take aging of mineral dust into account. We investigated the effect of chemical processing on the optical properties. It was shown that interactions of components of mineral dust (calcite, quartz and kaolinite) with humic and organic acids cause a shift of the IR resonance bands of these minerals. It may indicate changes in shape of the particles as well as changes in hygroscopicity and, as the result, the water content in these samples. Therefore, care should be taken when modeling optical properties of aged mineral dust.

  10. Toward a Combined SAGE II-HALOE Aerosol Climatology: An Evaluation of HALOE Version 19 Stratospheric Aerosol Extinction Coefficient Observations

    NASA Technical Reports Server (NTRS)

    Thomason, L. W.

    2012-01-01

    Herein, the Halogen Occultation Experiment (HALOE) aerosol extinction coefficient data is evaluated in the low aerosol loading period after 1996 as the first necessary step in a process that will eventually allow the production of a combined HALOE/SAGE II (Stratospheric Aerosol and Gas Experiment) aerosol climatology of derived aerosol products including surface area density. Based on these analyses, it is demonstrated that HALOE's 3.46 microns is of good quality above 19 km and suitable for scientific applications above that altitude. However, it is increasingly suspect at lower altitudes and should not be used below 17 km under any circumstances after 1996. The 3.40 microns is biased by about 10% throughout the lower stratosphere due to the failure to clear NO2 but otherwise appears to be a high quality product down to 15 km. The 2.45 and 5.26 micron aerosol extinction coefficient measurements are clearly biased and should not be used for scientific applications after the most intense parts of the Pinatubo period. Many of the issues in the aerosol data appear to be related to either the failure to clear some interfering gas species or doing so poorly. For instance, it is clear that the 3.40micronaerosol extinction coefficient measurements can be improved through the inclusion of an NO2 correction and could, in fact, end up as the highest quality overall HALOE aerosol extinction coefficient measurement. It also appears that the 2.45 and 5.26 micron channels may be improved by updating the Upper Atmosphere Pilot Database which is used as a resource for the removal of gas species otherwise not available from direct HALOE measurements. Finally, a simple model to demonstrate the promise of mixed visible/infrared aerosol extinction coefficient ensembles for the retrieval of bulk aerosol properties demonstrates that a combined HALOE/SAGE II aerosol climatology is feasible and may represent a substantial improvement over independently derived data sets.

  11. Mount St. Helens related aerosol properties from solar extinction measurements

    SciTech Connect

    Michalsky, J.J.; Kleckner, E.W.; Stokes, G.M.

    1980-11-01

    The optical extinction due to the introduction of aerosols and aerosol-precursors into the troposphere and stratosphere during the major eruptive phase of Mount St. Helens, Washington, is quantified. The concentration is on the two-week period centered on the major eruption of 22 July 1980. (ACR)

  12. Optical extinction of highly porous aerosol following atmospheric freeze drying

    NASA Astrophysics Data System (ADS)

    Adler, Gabriela; Haspel, Carynelisa; Moise, Tamar; Rudich, Yinon

    2014-06-01

    Porous glassy particles are a potentially significant but unexplored component of atmospheric aerosol that can form by aerosol processing through the ice phase of high convective clouds. The optical properties of porous glassy aerosols formed from a freeze-dry cycle simulating freezing and sublimation of ice particles were measured using a cavity ring down aerosol spectrometer (CRD-AS) at 532 nm and 355 nm wavelength. The measured extinction efficiency was significantly reduced for porous organic and mixed organic-ammonium sulfate particles as compared to the extinction efficiency of the homogeneous aerosol of the same composition prior to the freeze-drying process. A number of theoretical approaches for modeling the optical extinction of porous aerosols were explored. These include effective medium approximations, extended effective medium approximations, multilayer concentric sphere models, Rayleigh-Debye-Gans theory, and the discrete dipole approximation. Though such approaches are commonly used to describe porous particles in astrophysical and atmospheric contexts, in the current study, these approaches predicted an even lower extinction than the measured one. Rather, the best representation of the measured extinction was obtained with an effective refractive index retrieved from a fit to Mie scattering theory assuming spherical particles with a fixed void content. The single-scattering albedo of the porous glassy aerosols was derived using this effective refractive index and was found to be lower than that of the corresponding homogeneous aerosol, indicating stronger relative absorption at the wavelengths measured. The reduced extinction and increased absorption may be of significance in assessing direct, indirect, and semidirect forcing in regions where porous aerosols are expected to be prevalent.

  13. Broadband measurements of aerosol extinction in the ultraviolet spectral region

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Flores, J. M.; Brock, C. A.; Brown, S. S.; Rudich, Y.

    2013-01-01

    Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross-sections and complex refractive indices. We describe a new laboratory instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We determined aerosol extinction cross-sections and directly observed Mie scattering resonances for aerosols that are purely scattering (polystyrene latex spheres and ammonium sulfate), slightly absorbing (Suwannee River fulvic acid), and strongly absorbing (nigrosin dye). We describe an approach for retrieving refractive indices as a function of wavelength from the measured extinction cross-sections over the 360-420 nm wavelength region. The retrieved refractive indices for PSL and ammonium sulfate agree within uncertainty with literature values for this spectral region. The refractive index determined for nigrosin is 1.78 (±0.03) + 0.19 (±0.08) i at 360 nm and 1.53 (±0.03) + 0.21 (±0.05) i at 420 nm. The refractive index determined for Suwannee River fulvic acid is 1.71 (±0.02) + 0.07 (±0.06) i at 360 nm and 1.66 (±0.02) + 0.06 (±0.04) i at 420 nm. These laboratory results support the potential for a field instrument capable of determining ambient aerosol optical extinction, average aerosol extinction cross-section, and complex refractive index as a function of wavelength.

  14. Broadband measurements of aerosol extinction in the ultraviolet spectral region

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Flores, J. M.; Brock, C. A.; Brown, S. S.; Rudich, Y.

    2013-04-01

    Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross sections and complex refractive indices. We describe a new laboratory instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We determined aerosol extinction cross sections and directly observed Mie scattering resonances for aerosols that are purely scattering (polystyrene latex spheres and ammonium sulfate), slightly absorbing (Suwannee River fulvic acid), and strongly absorbing (nigrosin dye). We describe an approach for retrieving refractive indices as a function of wavelength from the measured extinction cross sections over the 360-420 nm wavelength region. The retrieved refractive indices for PSL and ammonium sulfate agree within uncertainty with the literature values for this spectral region. The refractive index determined for nigrosin is 1.78 (± 0.03) + 0.19 (± 0.08)i at 360 nm and 1.63 (± 0.03) + 0.21 (± 0.05)i at 420 nm. The refractive index determined for Suwannee River fulvic acid is 1.71 (± 0.02) + 0.07 (± 0.06)i at 360 nm and 1.66 (± 0.02) + 0.06 (± 0.04)i at 420 nm. These laboratory results support the potential for a field instrument capable of determining ambient aerosol optical extinction, average aerosol extinction cross section, and complex refractive index as a function of wavelength.

  15. In Situ Aerosol Profile Measurements and Comparisons with SAGE 3 Aerosol Extinction and Surface Area Profiles at 68 deg North

    NASA Technical Reports Server (NTRS)

    2005-01-01

    Under funding from this proposal three in situ profile measurements of stratospheric sulfate aerosol and ozone were completed from balloon-borne platforms. The measured quantities are aerosol size resolved number concentration and ozone. The one derived product is aerosol size distribution, from which aerosol moments, such as surface area, volume, and extinction can be calculated for comparison with SAGE III measurements and SAGE III derived products, such as surface area. The analysis of these profiles and comparison with SAGE III extinction measurements and SAGE III derived surface areas are provided in Yongxiao (2005), which comprised the research thesis component of Mr. Jian Yongxiao's M.S. degree in Atmospheric Science at the University of Wyoming. In addition analysis continues on using principal component analysis (PCA) to derive aerosol surface area from the 9 wavelength extinction measurements available from SAGE III. Ths paper will present PCA components to calculate surface area from SAGE III measurements and compare these derived surface areas with those available directly from in situ size distribution measurements, as well as surface areas which would be derived from PCA and Thomason's algorithm applied to the four wavelength SAGE II extinction measurements.

  16. Contributions of dust and smoke to aerosol extinction coefficient

    NASA Astrophysics Data System (ADS)

    Kavouras, I. G.; Xu, J.; Etyemezian, V.; Dubois, D.; Green, M.; Pitchford, M.

    2006-12-01

    Estimating scattering and absorption of light by atmospheric particles is critical for evaluating effects on regional and global climate. The magnitude of the interaction between aerosol and light is strongly related to the aerosol chemical composition among other factors. Dust and smoke are major sources of atmospheric aerosol, especially in the western United States. The importance of those sources has increased in recent decades due to the extensive man-made disturbance of natural ecosystems and land management practices. The objectives of this study were to specifically estimate the impact of dust and smoke on aerosol extinction coefficient measured in the Class I areas of the western states and identify the major causes of dust and types of smoke by using: (i) positive matrix factorization (PMF) to apportion ambient aerosols by source type; (ii) air mass backward trajectory analyses; (iii) land use/soil properties and; (iv) wildlife/prescribed fire data. The study included sites from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network located in western United States. For days with the worst reconstructed light extinction when dust was the major component, contributions from transcontinental transport from Asia, windblown dust from local sources and regional transport from upwind sources were identified. Based on the analysis for days with smoke being the major component of aerosol visibility extinction, the contributions of the following types of fires were determined: (a) wildfires near the site ("hot" emissions); (b) wildfires upwind of the site (aged smoke); (c) agricultural burn emissions; (d) rangeland fires.

  17. Improvement of Raman lidar algorithm for quantifying aerosol extinction

    NASA Technical Reports Server (NTRS)

    Russo, Felicita; Whiteman, David; Demoz, Belay; Hoff, Raymond

    2005-01-01

    Aerosols are particles of different composition and origin and influence the formation of clouds which are important in atmospheric radiative balance. At the present there is high uncertainty on the effect of aerosols on climate and this is mainly due to the fact that aerosol presence in the atmosphere can be highly variable in space and time. Monitoring of the aerosols in the atmosphere is necessary to better understanding many of these uncertainties. A lidar (an instrument that uses light to detect the extent of atmospheric aerosol loading) can be particularly useful to monitor aerosols in the atmosphere since it is capable to record the scattered intensity as a function of altitude from molecules and aerosols. One lidar method (the Raman lidar) makes use of the different wavelength changes that occur when light interacts with the varying chemistry and structure of atmospheric aerosols. One quantity that is indicative of aerosol presence is the aerosol extinction which quantifies the amount of attenuation (removal of photons), due to scattering, that light undergoes when propagating in the atmosphere. It can be directly measured with a Raman lidar using the wavelength dependence of the received signal. In order to calculate aerosol extinction from Raman scattering data it is necessary to evaluate the rate of change (derivative) of a Raman signal with respect to altitude. Since derivatives are defined for continuous functions, they cannot be performed directly on the experimental data which are not continuous. The most popular technique to find the functional behavior of experimental data is the least-square fit. This procedure allows finding a polynomial function which better approximate the experimental data. The typical approach in the lidar community is to make an a priori assumption about the functional behavior of the data in order to calculate the derivative. It has been shown in previous work that the use of the chi-square technique to determine the most

  18. Applications of Sunphotometry to Aerosol Extinction and Surface Anisotropy

    SciTech Connect

    Tsay, S.

    2002-09-30

    Support cost-sharing of a newly developed sunphotometer in field deployment for aerosol studies. This is a cost-sharing research to deploy a newly developed sun-sky-surface photometer for studying aerosol extinction and surface anisotropy at the ARM SGP, TWP, and NSA-AAO CART sites and in many field campaigns. Atmospheric aerosols affect the radiative energy balance of the Earth, both directly by perturbing the incoming/outgoing radiation fields and indirectly by influencing the properties/processes of clouds and reactive greenhouse gases. The surface bidirectional reflectance distribution function (BRDF) also plays a crucial role in the radiative energy balance, since the BRDF is required to determine (i) the spectral and spectrally-averaged surface albedo, and (ii) the top-of-the-atmosphere (TOA) angular distribution of radiance field. Therefore, the CART sites provide an excellent, albeit unique, opportunity to collect long-term climatic data in characterizing aerosol properties and various types of surface anisotropy.

  19. Applications of Sunphotometry to Aerosol Extinction and Surface Anisotropy

    NASA Technical Reports Server (NTRS)

    Tsay, S. C.; Holben, B. N.; Privette, J. L.

    2005-01-01

    Support cost-sharing of a newly developed sunphotometer in field deployment for aerosol studies. This is a cost-sharing research to deploy a newly developed sun-sky-surface photometer for studying aerosol extinction and surface anisotropy at the ARM SGP, TWP, and NSA-AAO CART sites and in many field campaigns. Atmospheric aerosols affect the radiative energy balance of the Earth, both directly by perturbing the incoming/outgoing radiation fields and indirectly by influencing the properties/processes of clouds and reactive greenhouse gases. The surface bidirectional reflectance distribution function (BRDF) also plays a crucial role in the radiative energy balance, since the BRDF is required to determine (1) the spectral and spectrally-averaged surface albedo, and (2) the top-of-the-atmosphere (TOA) angular distribution of radiance field. Therefore, the CART sites provide an excellent, albeit unique, opportunity to collect long-term climatic data in characterizing aerosol properties and various types of surface anisotropy.

  20. [Ultraviolet Mie lidar observations of aerosol extinction in a dust storm case over Macao].

    PubMed

    Liu, Qiao-jun; Cheng, A Y S; Zhu, Jian-hua; Fong, S K; Chang, S W; Tam, K S; Viseu, A

    2012-03-01

    Atmospheric aerosol over Macao was monitored by using a 355 nm Mie scattering lidar during the dust event on March 22nd, 2010. Vertical profiles of aerosol extinction coefficients were obtained and correlated with local PM10 concentration. The near-surface aerosol extinction coefficients have good agreement with PM10 concentration values. The aerosol extinction vertical profiles showed that there were distinct layers of dust aerosol concentration. The source and tracks of dust aerosol were analyzed by back-trajectory simulation. Observations showed that this lidar could run well even in dust storm episode, and it would help to further the study on aerosol properties over Macao. PMID:22582620

  1. Infrared extinction spectra of some common liquid aerosols.

    PubMed

    Carlon, H R; Anderson, D H; Milham, M E; Tarnove, T L; Frickel, R H; Sindoni, I

    1977-06-01

    Infrared extinction spectra in the 3-5-microm and 7-13-microm atmospheric window regions have been obtained for smokes of petroleum oil, sulfuric acid, and phosphoric acid of varying droplet concentration and for water fogs. Spectra were also obtained at 0.36-2.35microm for petroleum oil and sulfuric acid smokes. Experimental results were compared, for sulfuric acid and water aerosols, to calculated values obtained from the Mie theory. Agreement was as good as +/-10%. When absorbing smoke droplets are small compared to wavelength, very useful approximations apply, and droplet clouds may be spectrally simulated by thin liquid films. In such cases, the imaginary component of refractive index may be approximated directly from aerosol spectra. At 12.5-microm wavelength, water fog extinction is nearly independent of droplet size distribution, suggesting a simple scheme for measurement of total liquid water content of an optical path. PMID:20168760

  2. Retrieval of Aerosol Properties from Multi-Spectral Extinction Measurements

    NASA Technical Reports Server (NTRS)

    Lacis, Andrew A.

    1999-01-01

    The direct-beam spectral extinction of solar radiation contains information on atmospheric composition in a form that is essentially free from the data analysis complexities that often arise from multiple scattering. Ground based Multi-Filter Shadowband Radiometer (MFRSR) measurements provide such information for the vertical atmospheric column path, while solar occultation measurements from a satellite platform provide horizontal slices through the atmosphere. We describe application of a Multi-Spectral Atmospheric Column Extinction (MACE) analysis technique used to analyze MFRSR data also to occultation measurements made by SAGE II. For analysis, we select the 1985 Nevado del Ruiz volcanic eruption period to retrieve atmospheric profiles of ozone and NO2, and changes in the stratospheric aerosol size and optical depth. The time evolution of volcanic aerosol serves as a passive tracer to study stratospheric dynamics, and changes in particle size put constraints on the sulfur chemistry modeling of volcanic aerosols. Paper presented at The '99 Kyoto Aerosol-Cloud Workshop, held Dec 1-3, 1999, Kyoto, Japan

  3. Comparison of aerosol extinction profiles from lidar and SAGE II data at a tropical station

    NASA Technical Reports Server (NTRS)

    Parameswaran, K.; Rose, K. O.; Murthy, B. V. K.; Osborn, M. T.; Mcmaster, L. R.

    1991-01-01

    Aerosol extinction profiles obtained from lidar data at Trivandrum (8.6 deg N, 77 deg E) are compared with corresponding Stratospheric Aerosol and Gas Experiment II extinction profiles. The agreement between the two is found to be satisfactory. The extinction profiles obtained by both the experiments showed a prominent peak at 23-24 km altitude in the stratosphere. The study revealed large variability in upper tropospheric extinction with location (latitude).

  4. Importance of Raman Lidar Aerosol Extinction Measurements for Aerosol-Cloud Interaction Studies

    NASA Astrophysics Data System (ADS)

    Han, Zaw; Wu, Yonghua; Moshary, Fred; Gross, Barry; Gilerson, Alex

    2016-06-01

    Using a UV Raman Lidar for aerosol extinction, and combining Microwave Radiometer derived Liquid Water Path (LWP) with Multifilter Rotating Shadowband Radiometer derived Cloud Optical depth, to get cloud effective radius (Reff), we observe under certain specialized conditions, clear signatures of the Twomey Aerosol Indirect effect on cloud droplet properties which are consistent with the theoretical bounds. We also show that the measurement is very sensitive to how far the aerosol layer is from the cloud base and demonstrate that surface PM25 is far less useful. Measurements from both the DOE ARM site and new results at CCNY are presented.

  5. In situ measurements of light extinction of stratospheric aerosols

    NASA Technical Reports Server (NTRS)

    Metzig, Gunthard

    1991-01-01

    The extinction coefficient of ambient aerosol particles was measured using a multiple transverse cell (White Cell) with an effective path length of 100 m. Measurements were performed at seven fixed wavelengths in the visible region using a white light source and an interference filter set with 2 nm bandwidth and center wavelengths of 405.5, 450, 500, 550, 600, 650, and 692.5 nm. The total air flow in the system was 16.7 1/min; the volume of the chamber is close to 10 liters. It takes about one minute to fill the chamber with particles homogeneously, but it needs up to five minutes to get the chamber particle-free. Before measuring the aerosol, the transmission of the particle-free air is determined; then the aerosol passes through the chamber for a period of ten minutes; after this the transmission of particle-free ambient air is measured again for eight minutes. All times are subject to change. At present the measurements are done with a frequency of 1 Hz, but an increase of up to 30 Hz is possible. The lower detection limit of the used White Cell is 3.4 by 10(exp -06) per m. This is sufficient for measuring the extinction coefficient during most tropospheric and some stratospheric conditions. It will be necessary to increase the sensitivity by a factor of ten when measurements under the clearest stratospheric conditions take place.

  6. A comparative study of aerosol extinction measurements made by the SAM II and SAGE satellite experiments

    NASA Technical Reports Server (NTRS)

    Yue, G. K.; Mccormick, M. P.; Chu, W. P.

    1984-01-01

    SAM II and SAGE are two satellite experiments designed to measure stratospheric aerosol extinction using the technique of solar occultation or limb extinction. Although each sensor is mounted aboard a different satellite, there are occasions when their measurement locations are nearly coincident, thereby providing opportunities for a measurement comparison. In this paper, the aerosol extinction profiles and daily contour plots for some of these events in 1979 are reported. The comparisons shown in this paper demonstrate that SAM II and SAGE are producing similar aerosol extinction profiles within their measurement errors and that since SAM II has been previously validated, these results show the validity of the SAGE aerosol measurements.

  7. Stratospheric Aerosol and Gas Experiment (SAGE) II and III Aerosol Extinction Measurements in the Arctic Middle and Upper Troposphere

    NASA Technical Reports Server (NTRS)

    Treffeisen, R. E.; Thomason, L. W.; Strom, J.; Herber, A. B.; Burton, S. P.; Yamanouchi, T.

    2006-01-01

    In recent years, substantial effort has been expended toward understanding the impact of tropospheric aerosols on Arctic climate and chemistry. A significant part of this effort has been the collection and documentation of extensive aerosol physical and optical property data sets. However, the data sets present significant interpretive challenges because of the diverse nature of these measurements. Among the longest continuous records is that by the spaceborne Stratospheric Aerosol and Gas Experiment (SAGE) II. Although SAGE tropospheric measurements are restricted to the middle and upper troposphere, they may be able to provide significant insight into the nature and variability of tropospheric aerosol, particularly when combined with ground and airborne observations. This paper demonstrates the capacity of aerosol products from SAGE II and its follow-on experiment SAGE III to describe the temporal and vertical variations of Arctic aerosol characteristics. We find that the measurements from both instruments are consistent enough to be combined. Using this combined data set, we detect a clear annual cycle in the aerosol extinction for the middle and upper Arctic troposphere.

  8. The impacts of aerosol loading, composition, and water uptake on aerosol extinction variability in the Baltimore-Washington, D.C. region

    NASA Astrophysics Data System (ADS)

    Beyersdorf, A. J.; Ziemba, L. D.; Chen, G.; Corr, C. A.; Crawford, J. H.; Diskin, G. S.; Moore, R. H.; Thornhill, K. L.; Winstead, E. L.; Anderson, B. E.

    2016-01-01

    3 km). Routine airborne sampling over six locations was used to evaluate the relative contributions of aerosol loading, composition, and relative humidity (the amount of water available for uptake onto aerosols) to variability in mixed-layer aerosol extinction. Aerosol loading (dry extinction) was found to be the predominant source, accounting for 88 % on average of the measured spatial variability in ambient extinction, with lesser contributions from variability in relative humidity (10 %) and aerosol composition (1.3 %). On average, changes in aerosol loading also caused 82 % of the diurnal variability in ambient aerosol extinction. However on days with relative humidity above 60 %, variability in RH was found to cause up to 62 % of the spatial variability and 95 % of the diurnal variability in ambient extinction. This work shows that extinction is driven to first order by aerosol mass loadings; however, humidity-driven hydration effects play an important secondary role. This motivates combined satellite-modeling assimilation products that are able to capture these components of the aerosol optical depth (AOD)-PM2.5 link. Conversely, aerosol hygroscopicity and SSA play a minor role in driving variations both spatially and throughout the day in aerosol extinction and therefore AOD. However, changes in aerosol hygroscopicity from day to day were large and could cause a bias of up to 27 % if not accounted for. Thus it appears that a single daily measurement of aerosol hygroscopicity can be used for AOD-to-PM2.5 conversions over the study region (on the order of 1400 km2). This is complimentary to the results of Chu et al. (2015), who determined that the aerosol vertical distribution from "a single lidar is feasible to cover the range of 100 km" in the same region.

  9. Miniature instruments for aerosol extinction at ambient conditions

    NASA Astrophysics Data System (ADS)

    Murphy, D. M.

    2015-12-01

    Aerosol extinction is a fundamental parameter for the direct forcing of climate, visibility, and comparisons to remote sensing. Bringing air into an instrument "box" almost always changes the relative humidity and loses some dust or other large particles. I will show two techniques for miniature instruments that measure extinction at ambient conditions. One is a miniature sun photometer for vertical profiles. In the last year it has successfully gathered data on test flights with excellent performance and signal to noise. The second instrument is a miniature cavity ring down instrument open to the air. In both cases, small instruments require decisions about just what is necessary for the measurement rather than just scaling down larger designs. I will explore the rationale for some of these design choices.

  10. Airborne Cavity Ring-Down Measurement of Aerosol Extinction and Scattering During the Aerosol IOP

    NASA Technical Reports Server (NTRS)

    Strawa, A. W.; Ricci, K.; Provencal, R.; Schmid, B.; Covert, D.; Elleman, R.; Arnott, P.

    2003-01-01

    Large uncertainties in the effects of aerosols on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This paper describes preliminary results from Cadenza, a new continuous wave cavity ring-down (CW-CRD) instrument designed to address these uncertainties. Cadenza measures the aerosol extinction coefficient for 675 nm and 1550 nm light, and simultaneously measures the scattering coefficient at 675 nm. In the past year Cadenza was deployed in the Asian Dust Above Monterey (ADAM) and DOE Aerosol Intensive Operating Period (IOP) field projects. During these flights Cadenza produced measurements of aerosol extinction in the range from 0.2 to 300 Mm-1 with an estimated precision of 0.1 Min-1 for 1550 nm light and 0.2 Mm-1 for 675 nm light. Cadenza data from the ADAM and Aerosol IOP missions compared favorably with data from the other instruments aboard the CIRPAS Twin Otter aircraft and participating in those projects.= We present comparisons between the Cadenza measurements and those friom a TSI nephelometer, Particle Soot Absorption Photometer (PSAP), and the AATS 14 sun-photometer. Measurements of the optical properties of smoke and dust plumes sampled during these campaigns are presented and estimates of heating rates due to these plumes are made.

  11. Comparative studies of aerosol extinction measurements made by the SAM II and SAGE II satellite experiments

    NASA Technical Reports Server (NTRS)

    Yue, Glenn K.; Mccormick, M. P.; Chu, W. P.; Wang, P.; Osborn, M. T.

    1989-01-01

    Results from the Stratospheric Aerosol Measurement (SAM) II and Stratospheric Aerosol and Gas Experiment (SAGE) II are compared for measurement locations which are coincident in time and space. At 1.0 micron, the SAM II and SAGE II aerosol extinction profiles are similar within their measurement errors. In addition, sunrise and sunset aerosol extinction data at four different wavelengths are compared for occasions when the SAGE II and SAM II measurements are nearly coincident in space and about 12 hours apart.

  12. Photoacoustic determination of optical absorption to extinction ratio in aerosols.

    PubMed

    Roessler, D M; Faxvog, F R

    1980-02-15

    The photoacoustic technique has been used in conjunction with an optical transmission measurement to determine the fraction of light absorbed in cigarette and acetylene smoke aerosols. At 0.5145-microm wavelength,the absorption-to-extinction fraction is 0.01 +/- 0.003 for cigarette smoke and is in excellent agreement with predictions from Mie theory for smoke particles having a refractive index of 1.45-0.00133i and a median diameter in the 0.15-0.65-microm range. For acetylene smoke the absorbed fraction was 0.85 +/- 0.05. PMID:20216896

  13. Comparison of aerosol extinction between lidar and SAGE II over Gadanki, a tropical station in India

    NASA Astrophysics Data System (ADS)

    Kulkarni, P.; Ramachandran, S.

    2015-03-01

    An extensive comparison of aerosol extinction has been performed using lidar and Stratospheric Aerosol and Gas Experiment (SAGE) II data over Gadanki (13.5° N, 79.2° E), a tropical station in India, following coincident criteria during volcanically quiescent conditions from 1998 to 2005. The aerosol extinctions derived from lidar are higher than SAGE II during all seasons in the upper troposphere (UT), while in the lower-stratosphere (LS) values are closer. The seasonal mean percent differences between lidar and SAGE II aerosol extinctions are > 100% in the UT and < 50% above 25 km. Different techniques (point and limb observations) played the major role in producing the observed differences. SAGE II aerosol extinction in the UT increases as the longitudinal coverage is increased as the spatial aerosol extent increases, while similar extinction values in LS confirm the zonal homogeneity of LS aerosols. The study strongly emphasized that the best meteorological parameters close to the lidar measurement site in terms of space and time and Ba (sr-1), the ratio between aerosol backscattering and extinction, are needed for the tropics for a more accurate derivation of aerosol extinction.

  14. Mass extinctions: Ecological selectivity and primary production

    NASA Astrophysics Data System (ADS)

    Rhodes, Melissa Clark; Thayer, Charles W.

    1991-09-01

    If mass extinctions were caused by reduced primary productivity, then extinctions should be concentrated among animals with starvation-susceptible feeding modes, active lifestyles, and high-energy budgets. The stratigraphic ranges (by stage) of 424 genera of bivalves and 309 genera of articulate brachiopods suggest that there was an unusual reduction of primary productivity at the Cretaceous/Tertiary (K/T) boundary extinction. For bivalves at the K/T, there were (1) selective extinction of suspension feeders and other susceptible trophic categories relative to deposit feeders and other resistant categories, and (2) among suspension feed-ers, selective extinction of bivalves with active locomotion. During the Permian-Triassic (P/Tr) extinction and Jurassic background time, extinction rates among suspension feeders were greater for articulate brachiopods than for bivalves. But during the K/T event, extinction rates of articulates and suspension-feeding bivalves equalized, possibly because the low-energy budgets of articulates gave them an advantage when food was scarce.

  15. Retrieving Stratospheric Aerosol Extinction from SCIAMACHY Measurements in Limb Geometry

    NASA Astrophysics Data System (ADS)

    Dörner, Steffen; Penning de Vries, Marloes; Pukite, Janis; Beirle, Steffen; Wagner, Thomas

    2015-04-01

    Techniques for retrieving height resolved information on stratospheric aerosol improved significantly in the past decade with the availability of satellite measurements in limb geometry. Instruments like OMPS, OSIRIS and SCIAMACHY provide height resolved radiance spectra with global coverage. Long term data sets of stratospheric aerosol extinction profiles are important for a detailed investigation of spatial and temporal variation and formation processes (e.g. after volcanic eruptions or in polar stratospheric clouds). Resulting data sets contain vital information for climate models (radiative effect) or chemistry models (reaction surface for heterogeneous chemistry). This study focuses on the SCIAMACHY instrument which measured scattered sunlight in the ultra-violet, visible and near infra-red spectral range since the launch on EnviSat in 2002 until an instrumental error occurred in April 2012. SCIAMACHY's unique method of alternating measurements in limb and nadir geometry provides co-located profile and column information respectively that can be used to characterize plumes with small horizontal extents. The covered wavelength range potentially provides information on effective micro-physical properties of the aerosol particles. However, scattering on background aerosol constitutes only a small fraction of detected radiance and assumptions on particle characteristics (e.g. size distribution) have to be made which results in large uncertainties especially for wavelengths below 700nm and for measurements in backscatter geometry. Methods to reduce these uncertainties are investigated and applied to our newly developed retrieval algorithm. In addition, so called spatial straylight contamination of the measured signal was identified as a significant error source and an empirical correction scheme was developed. A large scale comparison study with SAGE II for the temporal overlap of both instruments (2002 to 2005) shows promising results.

  16. Extinction spectra of mineral dust aerosol components in an environmental aerosol chamber: IR resonance studies

    NASA Astrophysics Data System (ADS)

    Mogili, Praveen K.; Yang, K. H.; Young, Mark A.; Kleiber, Paul D.; Grassian, Vicki H.

    Mineral dust aerosol plays an important role in determining the physical and chemical equilibrium of the atmosphere. To better understand the impact that mineral dust aerosol may have on climate forcing and on remote sensing, we have initiated a study of the optical properties of important components of mineral dust aerosol including silicate clays (illite, kaolinite, and montmorillonite), quartz, anhydrite, and calcite. The extinction spectra are measured in an environmental simulation chamber over a broad wavelength range, which includes both the IR (650-5000 cm -1) and UV-vis (12,500-40,000 cm -1) spectral regions. In this paper, we focus on the IR region from 800 to 1500 cm -1, where many of these mineral dust constituents have characteristic vibrational resonance features. Experimental spectra are compared with Mie theory simulations based on published mineral optical constants. We find that Mie theory generally does a poor job in fitting the IR resonance peak positions and band profiles for nonspherical aerosols in the accumulation mode size range ( D˜0.1-2.5 μm). We explore particle shape effects on the IR resonance line profiles by considering analytic models for extinction of particles with characteristic shapes (i.e. disks, needles, and ellipsoids). Interestingly, Mie theory often appears to give more accurate results for the absorption line profiles of larger particles that fall in the coarse mode size range.

  17. Intercomparison of aerosol extinction profiles retrieved from MAX-DOAS measurements

    NASA Astrophysics Data System (ADS)

    Frieß, U.; Klein Baltink, H.; Beirle, S.; Clémer, K.; Hendrick, F.; Henzing, B.; Irie, H.; de Leeuw, G.; Li, A.; Moerman, M. M.; van Roozendael, M.; Shaiganfar, R.; Wagner, T.; Wang, Y.; Xie, P.; Yilmaz, S.; Zieger, P.

    2016-07-01

    A first direct intercomparison of aerosol vertical profiles from Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations, performed during the Cabauw Intercomparison Campaign of Nitrogen Dioxide measuring Instruments (CINDI) in summer 2009, is presented. Five out of 14 participants of the CINDI campaign reported aerosol extinction profiles and aerosol optical thickness (AOT) as deduced from observations of differential slant column densities of the oxygen collision complex (O4) at different elevation angles. Aerosol extinction vertical profiles and AOT are compared to backscatter profiles from a ceilometer instrument and to sun photometer measurements, respectively. Furthermore, the near-surface aerosol extinction coefficient is compared to in situ measurements of a humidity-controlled nephelometer and dry aerosol absorption measurements. The participants of this intercomparison exercise use different approaches for the retrieval of aerosol information, including the retrieval of the full vertical profile using optimal estimation and a parametrised approach with a prescribed profile shape. Despite these large conceptual differences, and also differences in the wavelength of the observed O4 absorption band, good agreement in terms of the vertical structure of aerosols within the boundary layer is achieved between the aerosol extinction profiles retrieved by the different groups and the backscatter profiles observed by the ceilometer instrument. AOTs from MAX-DOAS and sun photometer show a good correlation (R>0.8), but all participants systematically underestimate the AOT. Substantial differences between the near-surface aerosol extinction from MAX-DOAS and from the humidified nephelometer remain largely unresolved.

  18. Aerosol Best Estimate Value-Added Product

    SciTech Connect

    Flynn, C; Turner, D; Koontz, A; Chand, D; Sivaraman, C

    2012-07-19

    The objective of the Aerosol Best Estimate (AEROSOLBE) value-added product (VAP) is to provide vertical profiles of aerosol extinction, single scatter albedo, asymmetry parameter, and Angstroem exponents for the atmospheric column above the Central Facility at the ARM Southern Great Plains (SGP) site. We expect that AEROSOLBE will provide nearly continuous estimates of aerosol optical properties under a range of conditions (clear, broken clouds, overcast clouds, etc.). The primary requirement of this VAP was to provide an aerosol data set as continuous as possible in both time and height for the Broadband Heating Rate Profile (BBHRP) VAP in order to provide a structure for the comprehensive assessment of our ability to model atmospheric radiative transfer for all conditions. Even though BBHRP has been completed, AEROSOLBE results are very valuable for environmental, atmospheric, and climate research.

  19. Determination of aerosol extinction coefficient profiles from LIDAR data using the optical depth solution method

    NASA Astrophysics Data System (ADS)

    Aparna, John; Satheesh, S. K.; Mahadevan Pillai, V. P.

    2006-12-01

    The LIDAR equation contains four unknown variables in a two-component atmosphere where the effects caused by both molecules and aerosols have to be considered. The inversion of LIDAR returns to retrieve aerosol extinction profiles, thus, calls for some functional relationship to be assumed between these two. The Klett's method, assumes a functional relationship between the extinction and backscatter. In this paper, we apply a different technique, called the optical depth solution, where we made use of the total optical depth or transmittance of the atmosphere along the LIDAR-measurement range. This method provides a stable solution to the LIDAR equation. In this study, we apply this technique to the data obtained using a micro pulse LIDAR (MPL, model 1000, Science and Engineering Services Inc) to retrieve the vertical distribution of aerosol extinction coefficient. The LIDAR is equipped with Nd-YLF laser at an operating wavelength of 523.5 nm and the data were collected over Bangalore. The LIDAR data are analyzed to get to weighted extinction coefficient profiles or the weighted sum of aerosol and molecular extinction coefficient profiles. Simultaneous measurements of aerosol column optical depth (at 500 nm) using a Microtops sun photometer were used in the retrievals. The molecular extinction coefficient is determined assuming standard atmospheric conditions. The aerosol extinction coefficient profiles are determined by subtracting the molecular part from the weighted extinction coefficient profiles. The details of the method and the results obtained are presented.

  20. Can we predict aerosol extinction in a coastal environment?

    NASA Astrophysics Data System (ADS)

    Tsintikidis, Dimitri; Kichura, Dan; Hammel, Steve

    2007-09-01

    We have been engaged in a long-term test to determine the beam extinction effects of aerosols. During four test periods of one month duration each, we propagated a beam over a 7-km path near the ocean surface, and measured the received intensity in two near-infrared wavebands (1.061 μm and at 1.622 μm). In each test period, meteorological measurements were obtained from a meteorological buoy located at the mid-point of the propagation path. These meteorological data were used as input for the Advanced Navy Aerosol Model (ANAM). In this paper we will describe the comparison between the ANAM predictions and the measured transmission. We found that there are significant and sustained discrepancies between the ANAM model predictions and the optical transmission data. We will focus on two particular problems that have emerged from our comparison: first, the ANAM dependence on local wind speed can cause errors, and second, the local relative humidity is not optimally coupled in the ANAM. We will present the analysis we used to support these claims, and we will present recommendations for modifications to the model.

  1. Optical modeling of aerosol extinction for remote sensing in the marine environment

    NASA Astrophysics Data System (ADS)

    Kaloshin, G. A.

    2013-05-01

    A microphysical model is presented for the surface layer marine and coastal atmospheric aerosols that is based on long-term observations of size distributions for 0.01-100 μm particles in different geographic sites. The fundamental feature of the model is a parameterization of amplitudes and widths for aerosol modes of the aerosol size distribution function (ASDF) as functions of fetch and wind speed. The shape of the ASDF and its dependence on meteorological parameters, altitudes above sea level (H), fetch (X), wind speed (U) and relative humidity (RH) are investigated. The spectral profiles of the aerosol extinction coefficients calculated by MaexPro (Marine Aerosol Extinction Profiles) are in good agreement with observational data and the numerical results obtained from the Navy Aerosol Model (NAM) and the Advanced Navy Aerosol Model (ANAM). Moreover, MaexPro was found to be an accurate and reliable tool for investigation of the optical properties of atmospheric aerosols.

  2. Airborne high spectral resolution lidar for measuring aerosol extinction and backscatter coefficients.

    PubMed

    Esselborn, Michael; Wirth, Martin; Fix, Andreas; Tesche, Matthias; Ehret, Gerhard

    2008-01-20

    An airborne high spectral resolution lidar (HSRL) based on an iodine absorption filter and a high-power frequency-doubled Nd:YAG laser has been developed to measure backscatter and extinction coefficients of aerosols and clouds. The instrument was operated aboard the Falcon 20 research aircraft of the German Aerospace Center (DLR) during the Saharan Mineral Dust Experiment in May-June 2006 to measure optical properties of Saharan dust. A detailed description of the lidar system, the analysis of its data products, and measurements of backscatter and extinction coefficients of Saharan dust are presented. The system errors are discussed and airborne HSRL results are compared to ground-based Raman lidar and sunphotometer measurements. PMID:18204721

  3. Spectrally-resolved measurements of aerosol extinction at ultraviolet and visible wavelengths

    NASA Astrophysics Data System (ADS)

    Flores, M.; Washenfelder, R. A.; Brock, C. A.; Brown, S. S.; Rudich, Y.

    2012-12-01

    Aerosols play an important role in the Earth's radiative budget. Aerosol extinction includes both the scattering and absorption of light, and these vary with wavelength, aerosol diameter, and aerosol composition. Historically, aerosol absorption has been measured using filter-based or extraction methods that are prone to artifacts. There have been few investigations of ambient aerosol optical properties at the blue end of the visible spectrum and into the ultraviolet. Brown carbon is particularly important in this spectral region, because it both absorbs and scatters light, and encompasses a large and variable group of organic compounds from biomass burning and secondary organic aerosol. We have developed a laboratory instrument that combines new, high-power LED light sources with high-finesse optical cavities to achieve sensitive measurements of aerosol optical extinction. This instrument contains two broadband channels, with spectral coverage from 360 - 390 nm and 385 - 420 nm. Using this instrument, we report aerosol extinction in the ultraviolet and near-visible spectral region as a function of chemical composition and structure. We have measured the extinction cross-sections between 360 - 420 nm with 0.5 nm resolution using different sizes and concentrations of polystyrene latex spheres, ammonium sulfate, and Suwannee River fulvic acid. Fitting the real and imaginary part of the refractive index allows the absorption and scattering to be determined.

  4. Mid-infrared extinction by sulfate aerosols from the Mt. Pinatubo eruption

    NASA Technical Reports Server (NTRS)

    Rinsland, C. P.; Yue, G. K.; Gunson, M. R.; Zander, R.; Abrams, M. C.

    1994-01-01

    Quantitative measurements of the wavelength dependence of aerosol extinction in the 750-3400/cm spectral region have been derived from 0.01/cm resolution stratospheric solar occultation spectra recorded by the ATMOS (Atmospheric Trace Molecule Spectroscopy) Fourier transform spectrometer about 9 1/2 months after the Mt Pinatubo volcanic eruption. Strong, broad aerosol features have been identified near 900, 1060, 1190, 1720, and 2900/cm below a tangent height of approximately 30 km. Aerosol extinction measurements derived from approximately 0.05/cm wide microwindows nearly free of telluric line absorption in the ATMOS spectra are compared with transmission calculations derived from aerosol size distribution profiles retrieved from correlative SAGE (Stratospheric Aerosol and Gas Experiment) II visible and near i.r. extinction measurements, seasonal and zonally averaged H2SO4 aerosol weight percentage profiles, and published sulfuric acid optical constants derived from room temperature laboratory measurements. The calculated shapes and positions of the aerosol features are generally consistent with the observations, thereby confirming that the aerosols are predominantly concentrated H2SO4-H2O droplets, but there are significant differences between the measured and calculated wavelength dependences of the aerosol extinction. We attribute these differences as primarily the result of errors in the calculated low temperature H2SO4-H2O optical constants. Errors in both the published room temperature optical constants and the limitations of the Lorentz-Lorenz relation are likely to be important.

  5. Spectral Aerosol Extinction (SpEx): a new instrument for in situ ambient aerosol extinction measurements across the UV/visible wavelength range

    NASA Astrophysics Data System (ADS)

    Jordan, C. E.; Anderson, B. E.; Beyersdorf, A. J.; Corr, C. A.; Dibb, J. E.; Greenslade, M. E.; Martin, R. F.; Moore, R. H.; Scheuer, E.; Shook, M. A.; Thornhill, K. L.; Troop, D.; Winstead, E. L.; Ziemba, L. D.

    2015-06-01

    We introduce a new instrument for the measurement of in situ ambient aerosol extinction over the 300-700 nm wavelength range, the Spectral Aerosol Extinction (SpEx) instrument. This measurement capability is envisioned to complement existing in situ instrumentation, allowing for simultaneous measurement of the evolution of aerosol optical, chemical, and physical characteristics in the ambient environment. In this work, a detailed description of the instrument is provided along with characterization tests performed in the laboratory. Measured spectra of NO2 and polystyrene latex spheres (PSLs) agreed well with theoretical calculations. Good agreement was also found with simultaneous aerosol extinction measurements at 450, 530, and 630 nm using CAPS PMex instruments in a series of 22 tests including non-absorbing compounds, dusts, soot, and black and brown carbon analogs. SpEx can more accurately distinguish the presence of brown carbon from other absorbing aerosol due to its 300 nm lower wavelength limit compared to measurements limited to visible wavelengths. Extinction spectra obtained with SpEx contain more information than can be conveyed by a simple power law fit (typically represented by Ångström Exponents). Planned future improvements aim to lower detection limits and ruggedize the instrument for mobile operation.

  6. Light extinction by secondary organic aerosol: an intercomparison of three broadband cavity spectrometers

    NASA Astrophysics Data System (ADS)

    Varma, R. M.; Ball, S. M.; Brauers, T.; Dorn, H.-P.; Heitmann, U.; Jones, R. L.; Platt, U.; Pöhler, D.; Ruth, A. A.; Shillings, A. J. L.; Thieser, J.; Wahner, A.; Venables, D. S.

    2013-11-01

    Broadband optical cavity spectrometers are maturing as a technology for trace-gas detection, but only recently have they been used to retrieve the extinction coefficient of aerosols. Sensitive broadband extinction measurements allow explicit separation of gas and particle phase spectral contributions, as well as continuous spectral measurements of aerosol extinction in favourable cases. In this work, we report an intercomparison study of the aerosol extinction coefficients measured by three such instruments: a broadband cavity ring-down spectrometer (BBCRDS), a cavity-enhanced differential optical absorption spectrometer (CE-DOAS), and an incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS). Experiments were carried out in the SAPHIR atmospheric simulation chamber as part of the NO3Comp campaign to compare the measurement capabilities of NO3 and N2O5 instrumentation. Aerosol extinction coefficients between 655 and 690 nm are reported for secondary organic aerosols (SOA) formed by the NO3 oxidation of β-pinene under dry and humid conditions. Despite different measurement approaches and spectral analysis procedures, the three instruments retrieved aerosol extinction coefficients that were in close agreement. The refractive index of SOA formed from the β-pinene + NO3 reaction was 1.61, and was not measurably affected by the chamber humidity or by aging of the aerosol over several hours. This refractive index is significantly larger than SOA refractive indices observed in other studies of OH and ozone-initiated terpene oxidations, and may be caused by the large proportion of organic nitrates in the particle phase. In an experiment involving ammonium sulfate particles, the aerosol extinction coefficients as measured by IBBCEAS were found to be in reasonable agreement with those calculated using the Mie theory. The results of the study demonstrate the potential of broadband cavity spectrometers for determining the optical properties of aerosols.

  7. Light extinction by Secondary Organic Aerosol: an intercomparison of three broadband cavity spectrometers

    NASA Astrophysics Data System (ADS)

    Varma, R. M.; Ball, S. M.; Brauers, T.; Dorn, H.-P.; Heitmann, U.; Jones, R. L.; Platt, U.; Pöhler, D.; Ruth, A. A.; Shillings, A. J. L.; Thieser, J.; Wahner, A.; Venables, D. S.

    2013-07-01

    Broadband optical cavity spectrometers are maturing as a technology for trace gas detection, but only recently have they been used to retrieve the extinction coefficient of aerosols. Sensitive broadband extinction measurements allow explicit separation of gas and particle phase spectral contributions, as well as continuous spectral measurements of aerosol extinction in favourable cases. In this work, we report an intercomparison study of the aerosol extinction coefficients measured by three such instruments: a broadband cavity ring-down spectrometer (BBCRDS), a cavity-enhanced differential optical absorption spectrometer (CE-DOAS), and an incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS). Experiments were carried out in the SAPHIR atmospheric simulation chamber as part of the NO3Comp campaign to compare the measurement capabilities of NO3 and N2O5 instrumentation. Aerosol extinction coefficients between 655 and 690 nm are reported for secondary organic aerosols (SOA) formed by the NO3 oxidation of β-pinene under dry and humid conditions. Despite different measurement approaches and spectral analysis procedures, the three instruments retrieved aerosol extinction coefficients that were in close agreement. The refractive index of SOA formed from the β-pinene + NO3 reaction was 1.61, and was not measurably affected by the chamber humidity or by aging of the aerosol over several hours. This refractive index is significantly larger than SOA refractive indices observed in other studies of OH and ozone-initiated terpene oxidations, and may be caused by the large proportion of organic nitrates in the particle phase. In an experiment involving ammonium sulphate particles the aerosol extinction coefficients as measured by IBBCEAS were found to be in reasonable agreement with those calculated using Mie theory. The results of the study demonstrate the potential of broadband cavity spectrometers for determining the optical properties of aerosols.

  8. Raman Lidar Measurements of Aerosol Extinction and Backscattering. Report 1; Methods and Comparisons

    NASA Technical Reports Server (NTRS)

    Ferrare, R. A.; Melfi, S. H.; Whiteman, D. N.; Evans, K. D.; Leifer, R.

    1998-01-01

    This paper examines the aerosol backscattering and extinction profiles measured at night by the NASA Goddard Space Flight Center Scanning Raman Lidar (SRL) during the remote cloud sensing (RCS) intensive operations period (IOP) at the Department of Energy Atmospheric Radiation Measurement (ARM) southern Great Plains (SGP) site in April 1994. These lidar data are used to derive aerosol profiles for altitudes between 0.0 1 5 and 5 km. Since this lidar detects Raman scattering from nitrogen and oxygen molecules as well as the elastic scattering from molecules and aerosols, it measures both aerosol backscattering and extinction simultaneously. The aerosol extinction/backscattering ratio varied between approximately 30 sr and 75 sr at 351 nm. Aerosol optical thicknesses derived by integrating the lidar profiles of aerosol extinction measured at night between 0. I and 5 km are found to be about 10-40% lower than those measured by a Sun photometer during the day. This difference is attributed to the contribution by stratospheric aerosols not included in the lidar estimates as well as to diurnal differences in aerosol properties and concentrations. Aerosol profiles close to the surface were acquired by pointing the lidar nearly horizontally. Measurements of aerosol scattering from a tower-mounted nephelometer are found to be 40% lower than lidar measurements of aerosol extinction over a wide range of relative humidities even after accounting for the difference in wavelengths. The reasons for this difference are not clear but may be due to the inability of the nephelometer to accurately measure scattering by large particles.

  9. Raman lidar measurements of aerosol extinction and backscattering: 1. Methods and comparisons

    NASA Astrophysics Data System (ADS)

    Ferrare, R. A.; Melfi, S. H.; Whiteman, D. N.; Evans, K. D.; Leifer, R.

    1998-08-01

    This paper examines the aerosol backscattering and extinction profiles measured at night by the NASA Goddard Space Flight Center Scanning Raman Lidar (SRL) during the remote cloud sensing (RCS) intensive operations period (IOP) at the Department of Energy Atmospheric Radiation Measurement (ARM) southern Great Plains (SGP) site in April 1994. These lidar data are used to derive aerosol profiles for altitudes between 0.015 and 5 km. Since this lidar detects Raman scattering from nitrogen and oxygen molecules as well as the elastic scattering from molecules and aerosols, it measures both aerosol backscattering and extinction simultaneously. The aerosol extinction/backscattering ratio varied between approximately 30 sr and 75 sr at 351 nm. Aerosol optical thicknesses derived by integrating the lidar profiles of aerosol extinction measured at night between 0.1 and 5 km are found to be about 10-40% lower than those measured by a Sun photometer during the day. This difference is attributed to the contribution by stratospheric aerosols not included in the lidar estimates as well as to diurnal differences in aerosol properties and concentrations. Aerosol profiles close to the surface were acquired by pointing the lidar nearly horizontally. Measurements of aerosol scattering from a tower-mounted nephelometer are found to be 40% lower than lidar measurements of aerosol extinction over a wide range of relative humidities even after accounting for the difference in wavelengths. The reasons for this difference are not clear but may be due to the inability of the nephelometer to accurately measure scattering by large particles.

  10. Accuracy of near-surface aerosol extinction determined from columnar aerosol optical depth measurements in Reno, NV, USA

    NASA Astrophysics Data System (ADS)

    Loría-Salazar, S. Marcela; Arnott, W. Patrick; Moosmüller, Hans

    2014-10-01

    The aim of the present work is a detailed analysis of aerosol columnar optical depth as a tool to determine near-surface aerosol extinction in Reno, Nevada, USA, during the summer of 2012. Ground and columnar aerosol optical properties were obtained by use of in situ Photoacoustic and Integrated Nephelometer and Cimel CE-318 Sun photometer instruments, respectively. Both techniques showed that seasonal weather changes and fire plumes had enormous influence on local aerosol optics. The apparent optical height followed the shape but not magnitude of the development of the convective boundary layer when fire conditions were not present. Back trajectory analysis demonstrated that a local flow known as the Washoe Zephyr circulation often induced aerosol transport from Northern California over the Sierra Nevada Mountains that increased the aerosol optical depth at 500 nm during afternoons when compared with mornings. Aerosol fine mode fraction indicated that afternoon aerosols in June and July and fire plumes in August were dominated by submicron particles, suggesting upwind urban plume biogenically enhanced evolution toward substantial secondary aerosol formation. This fine particle optical depth was inferred to be beyond the surface, thereby complicating use of remote sensing measurements for near-ground aerosol extinction measurements. It is likely that coarse mode depletes fine mode aerosol near the surface by coagulation and condensation of precursor gases.

  11. An Aerosol Extinction-to-Backscatter Ratio Database Derived from the NASA Micro-Pulse Lidar Network: Applications for Space-based Lidar Observations

    NASA Technical Reports Server (NTRS)

    Welton, Ellsworth J.; Campbell, James R.; Spinhime, James D.; Berkoff, Timothy A.; Holben, Brent; Tsay, Si-Chee; Bucholtz, Anthony

    2004-01-01

    Backscatter lidar signals are a function of both backscatter and extinction. Hence, these lidar observations alone cannot separate the two quantities. The aerosol extinction-to-backscatter ratio, S, is the key parameter required to accurately retrieve extinction and optical depth from backscatter lidar observations of aerosol layers. S is commonly defined as 4*pi divided by the product of the single scatter albedo and the phase function at 180-degree scattering angle. Values of S for different aerosol types are not well known, and are even more difficult to determine when aerosols become mixed. Here we present a new lidar-sunphotometer S database derived from Observations of the NASA Micro-Pulse Lidar Network (MPLNET). MPLNET is a growing worldwide network of eye-safe backscatter lidars co-located with sunphotometers in the NASA Aerosol Robotic Network (AERONET). Values of S for different aerosol species and geographic regions will be presented. A framework for constructing an S look-up table will be shown. Look-up tables of S are needed to calculate aerosol extinction and optical depth from space-based lidar observations in the absence of co-located AOD data. Applications for using the new S look-up table to reprocess aerosol products from NASA's Geoscience Laser Altimeter System (GLAS) will be discussed.

  12. Statistical Characteristics of Aerosol Extinction Coefficient Profile in East Asia from CALIPSO

    NASA Astrophysics Data System (ADS)

    Sun, Xuejin; Zhou, Junhao; Zhou, Yongbo

    2016-06-01

    Aerosol extinction coefficient profile (ECP) is important in radiative transfer modeling, however, knowledge of ECP in some area has not been clearly recognized. To get a full understanding of statistical characteristics of ECP in three Asian regions: the Mongolian Plateau, the North China Plain and the Yellow Sea, CALIPSO aerosol product in 2012 is processed by conventional statistical methods. Orbit averaged ECP turns out to be mainly exponential and Gaussian patterns. Curve fitting shows that the two ECP patterns account for more than 50 percent of all the samples, especially in the Yellow Sea where the frequency of occurrence even reaches over 80 percent. Parameters determining fitting curves are provided consequently. To be specific, Gaussian pattern is the main ECP distribution in the Mongolian Plateau and the Yellow Sea, and exponential pattern predominates in the North China Plain. Besides, aerosol scale height reaches its maximum in summer and in the Mongolian Plateau. Meanwhile, the uplifting and deposition of dust during transportation are potentially explanations to the occurrence of Gaussian ECP. The results have certain representativeness, and contribute to reducing uncertainties of aerosol model in relevant researches.

  13. Field Studies of Broadband Aerosol Optical Extinction in the Ultraviolet Spectral Region

    NASA Astrophysics Data System (ADS)

    Washenfelder, R. A.; Attwood, A.; Brock, C. A.; Brown, S. S.

    2013-12-01

    Aerosols influence the Earth's radiative budget by scattering and absorbing incoming solar radiation. The optical properties of aerosols vary as a function of wavelength, but few measurements have reported the wavelength dependence of aerosol extinction cross sections and complex refractive indices. In the case of brown carbon, its wavelength-dependent absorption in the ultraviolet spectral region has been suggested as an important component of aerosol radiative forcing. We describe a new field instrument to measure aerosol optical extinction as a function of wavelength, using cavity enhanced spectroscopy with a broadband light source. The instrument consists of two broadband channels which span the 360-390 and 385-420 nm spectral regions using two light emitting diodes (LED) and a grating spectrometer with charge-coupled device (CCD) detector. We deployed this instrument during the Fire Lab at Missoula Experiment during Fall 2012 to measure biomass burning aerosol, and again during the Southern Oxidant and Aerosol Study in summer 2013 to measure organic aerosol in the Southeastern U.S. In both field experiments, we determined aerosol optical extinction as a function of wavelength and can interpret this together with size distribution and composition measurements to characterize the aerosol optical properties and radiative forcing.

  14. The code MaexPro for calculation of aerosol extinction in the marine and coastal environment

    NASA Astrophysics Data System (ADS)

    Kaloshin, G. A.

    2010-04-01

    In the paper the description of the last version of code MaexPro (Marine aerosol extinction Profile) for calculation spectral and vertical profiles of aerosol extinction coefficient α(λ), aerosol sizes distribution, area distribution, volumes distribution, modes aerosol extinction spectra is submitted. Code MaexPro is a computer program under constant development to estimate of EO systems signal power at a location place in which a fetch is key entrance parameter. The program carries out calculation α(λ), as functions of atmospheric effects using standard meteorological parameters, aerosol microphysical structure, a spectral band and a height of the sensor location. Spectral behavior α(λ) can be submitted as graphically, and as tables. Commands overplot for superposition or change of figures; profiles extrapolation; a lens; all kinds of possible copying; the data presentation, convenient for an input in code MODTRAN, and etc. are stipulated. The code MaexPro is a completely mouse-driven PC Windows program with a user-friendly interface. Calculation time of spectral and vertical profiles of α(λ) depends on the necessary wave length resolution, radius of aerosol particles and the location place height, and does not exceed tens seconds for each new meteorological condition. Other calculations characteristics, such as aerosol sizes distribution, area distribution, volumes distribution, modes aerosol extinction spectra, are performed in a few seconds.

  15. Comparison of LIDAR and Cavity Ring-Down Measurements of Aerosol Extinction and Study of Inferred Aerosol Gradients

    NASA Astrophysics Data System (ADS)

    Eberhard, W. L.; Massoli, P.; McCarty, B. J.; Machol, J. L.; Tucker, S. C.

    2007-12-01

    A LIDAR and a Cavity Ring-Down Aerosol Extinction Spectrometer (CRD) instrument simultaneously measured aerosol extinction at 355-nm wavelength from aboard the Research Vessel Ronald H. Brown during the Texas Air Quality Study II campaign. The CRD measured air sampled from the top of the common mast used by several in situ aerosol optical and chemical instruments. The LIDAR's scan sequence included near-horizontal stares (2° elevation angle) with pointing corrected for ship's roll. Aerosol extinction was retrieved using a variant of the slope method. The LIDAR therefore sampled air over a short vertical extent with midpoint higher above the surface than the CRD intake and at a horizontal distance of as much as a few kilometers. The CRD measured aerosol extinction at dry and at high (near-ambient) relative humidity (RH) levels, which were used to scale the measurements to ambient RH for the comparisons. Data from the two instruments for well-mixed conditions (supported by turbulence and atmospheric stability data) are compared to evaluate the degree of agreement between the two methods and reasons for differences. For instances of larger differences, the aerosol gradient below approximately 100 m altitude is inferred and examined in context of low-level meteorological parameters and LIDAR measurements at higher angles.

  16. Spectral aerosol extinction (SpEx): a new instrument for in situ ambient aerosol extinction measurements across the UV/visible wavelength range

    NASA Astrophysics Data System (ADS)

    Jordan, C. E.; Anderson, B. E.; Beyersdorf, A. J.; Corr, C. A.; Dibb, J. E.; Greenslade, M. E.; Martin, R. F.; Moore, R. H.; Scheuer, E.; Shook, M. A.; Thornhill, K. L.; Troop, D.; Winstead, E. L.; Ziemba, L. D.

    2015-11-01

    We introduce a new instrument for the measurement of in situ ambient aerosol extinction over the 300-700 nm wavelength range, the spectral aerosol extinction (SpEx) instrument. This measurement capability is envisioned to complement existing in situ instrumentation, allowing for simultaneous measurement of the evolution of aerosol optical, chemical, and physical characteristics in the ambient environment. In this work, a detailed description of the instrument is provided along with characterization tests performed in the laboratory. Measured spectra of NO2 and polystyrene latex spheres (PSLs) agreed well with theoretical calculations. Good agreement was also found with simultaneous aerosol extinction measurements at 450, 530, and 630 nm using CAPS PMex instruments in a series of 22 tests including nonabsorbing compounds, dusts, soot, and black and brown carbon analogs. SpEx measurements are expected to help identify the presence of ambient brown carbon due to its 300 nm lower wavelength limit compared to measurements limited to longer UV and visible wavelengths. Extinction spectra obtained with SpEx contain more information than can be conveyed by a simple power law fit (typically represented by Ångström exponents). Planned future improvements aim to lower detection limits and ruggedize the instrument for mobile operation.

  17. Aerosol extinction models based on measurements at two sites in Sweden.

    PubMed

    Kaurila, Timo; Hågård, Arne; Persson, Rolf

    2006-09-10

    Two aerosol extinction models have been developed using statistical analysis of long-term optical transmission measurements in Sweden performed at two locations from July 1977 to June 1982. The aerosol volume extinction coefficient for infrared (IR) radiation is calculated by the models with visibility, temperature, and air pressure as input parameters. As in the MODTRAN model, the IR extinction coefficient is proportional to the coefficient at 550 nm, which depends on the visibility. In the new models, the wavelength dependence of the extinction also depends on the visibility. The models predict significantly higher attenuation in the IR than does the Rural aerosol model from MODTRAN, which is commonly used. Comparison with the Maritime model shows that the new models predict lower extinction values in the 3-5 microm region and higher values in the 8-12 microm region. The uncertainties in terms of variance levels are calculated by the models. The properties of aerosols, and thereby the extinction coefficient, are partly correlated to local meteorological parameters, which enables the calculation of a mean predicted value. A substantial part of the variation is, however, caused by conditions in the source area and along the trajectory path of the aerosols. They are not correlated to the local meteorological parameters and therefore cause the variance in the models. PMID:16926909

  18. Retrieval of aerosol backscatter and extinction from airborne coherent Doppler wind lidar measurements

    NASA Astrophysics Data System (ADS)

    Chouza, F.; Reitebuch, O.; Groß, S.; Rahm, S.; Freudenthaler, V.; Toledano, C.; Weinzierl, B.

    2015-07-01

    A novel method for calibration and quantitative aerosol optical property retrieval from Doppler wind lidars (DWLs) is presented in this work. Due to the strong wavelength dependence of the atmospheric molecular backscatter and the low sensitivity of the coherent DWLs to spectrally broad signals, calibration methods for aerosol lidars cannot be applied to coherent DWLs usually operating at wavelengths between 1.5 and 2 μm. Instead, concurrent measurements of an airborne DWL at 2 μm and the POLIS ground-based aerosol lidar at 532 nm are used in this work, in combination with sun photometer measurements, for the calibration and retrieval of aerosol backscatter and extinction profiles at 532 nm. The proposed method was applied to measurements from the SALTRACE experiment in June-July 2013, which aimed at quantifying the aerosol transport and change in aerosol properties from the Sahara desert to the Caribbean. The retrieved backscatter and extinction coefficient profiles from the airborne DWL are within 20 % of POLIS aerosol lidar and CALIPSO satellite measurements. Thus the proposed method extends the capabilities of coherent DWLs to measure profiles of the horizontal and vertical wind towards aerosol backscatter and extinction profiles, which is of high benefit for aerosol transport studies.

  19. Spectral Aerosol Extinction (SpEx): A New Instrument for In situ Ambient Aerosol Extinction Measurements Across the UV/Visible Wavelength Range

    NASA Technical Reports Server (NTRS)

    Jordan, C. E.; Anderson, B. E.; Beyersdorf, A. J.; Corr, C. A.; Dibb, J. E.; Greenslade, M. E.; Martin, R. F.; Moore, R. H.; Scheuer, E.; Shook, M. A.; Thornhill, K. L.; Troop, D.; Winstead, Edward L.; Ziemba, L. D.

    2015-01-01

    We introduce a new instrument for the measurement of in situ ambient aerosol extinction over the 300-700 nm wavelength range, the Spectral Aerosol Extinction (SpEx) instrument. This measurement capability is envisioned to complement existing in situ instrumentation, allowing for simultaneous measurement of the evolution of aerosol optical, chemical, and physical characteristics in the ambient environment. In this work, a detailed description of the instrument is provided along with characterization tests performed in the laboratory. Measured spectra of NO2 and polystyrene latex spheres agreed well with theoretical calculations. Good agreement was also found with simultaneous aerosol extinction measurements at 450, 530, and 630 nm using CAPS PMex instruments in a series of 22 tests including non-absorbing compounds, dusts, soot, and black and brown carbon analogs. SpEx can more accurately distinguish the presence of brown carbon from other absorbing aerosol due to its 300 nm lower wavelength limit compared to measurements limited to visible wavelengths. In addition, the spectra obtained by SpEx carry more information than can be conveyed by a simple power law fit that is typically defined by the use of Angstrom Exponents. Future improvements aim at lowering detection limits and ruggedizing the instrument for mobile operation.

  20. Visible and infrared extinction of atmospheric aerosol in the marine and coastal environment.

    PubMed

    Kaloshin, Gennady A

    2011-05-10

    The microphysical model Marine Aerosol Extinction Profiles (MaexPro) for surface layer marine and coastal atmospheric aerosols, which is based on long-term observations of size distributions for 0.01-100 μm particles, is presented. The fundamental feature of the model is a parameterization of amplitudes and widths for aerosol modes of the aerosol size distribution function (ASDF) as functions of fetch and wind speed. The shape of the ASDF and its dependence on meteorological parameters, altitudes above the sea level (H), fetch (X), wind speed (U), and relative humidity is investigated. The model is primarily to characterize aerosols for the near-surface layer (within 25 m). The model is also applicable to higher altitudes within the atmospheric boundary layer, where the change in the vertical profile of aerosol is not very large. In this case, it is only valid for "clean" marine environments, in the absence of air pollution or any other major sources of continental aerosols, such desert dust or smoke from biomass burning. The spectral profiles of the aerosol extinction coefficients calculated by MaexPro are in good agreement with observational data and the numerical results obtained by the well-known Navy Aerosol Model and Advanced Navy Aerosol Model codes. Moreover, MaexPro was found to be an accurate and reliable instrument for investigation of the optical properties of atmospheric aerosols. PMID:21556113

  1. Using Airborne High Spectral Resolution Lidar Data to Evaluate Combined Active Plus Passive Retrievals of Aerosol Extinction Profiles

    NASA Technical Reports Server (NTRS)

    Burton, S. P.; Ferrare, R. A.; Kittaka, C.; Hostetler, C. A.; Hair, J. W.; Obland, M. D.; Rogers, R. R.; Cook, A. L.; Haper, D. B.

    2008-01-01

    Aerosol extinction profiles are derived from backscatter data by constraining the retrieval with column aerosol optical thickness (AOT), for example from coincident MODIS observations and without reliance on a priori assumptions about aerosol type or optical properties. The backscatter data were acquired with the NASA Langley High Spectral Resolution Lidar (HSRL). The HSRL also simultaneously measures extinction independently, thereby providing an ideal data set for evaluating the constrained retrieval of extinction from backscatter. We will show constrained extinction retrievals using various sources of column AOT, and examine comparisons with the HSRL extinction measurements and with a similar retrieval using data from the CALIOP lidar on the CALIPSO satellite.

  2. SAGE I and SAM II measurements of 1 micron aerosol extinction in the free troposphere

    NASA Technical Reports Server (NTRS)

    Kent, G. S.; Farrukh, U. O.; Wang, P. H.; Deepak, A.

    1988-01-01

    The SAGE-I and SAM-II satellite sensors were designed to measure, with global coverage, the 1 micron extinction produced by the stratospheric aerosol. In the absence of high altitude clouds, similar measurements may be made for the free tropospheric aerosol. Median extinction values at middle and high latitudes in the Northern Hemisphere, for altitudes between 5 and 10 km, are found to be one-half to one order of magnitude greater than values at corresponding latitudes in the Southern Hemisphere. In addition, a seasonal increase by a factor of 1.5-2 was observed in both hemispheres, in 1979-80, in local spring and summer. Following major volcanic eruptions, a long-lived enhancement of the aerosol extinction is observed for altitudes above 5 km.

  3. Enhanced extinction of visible radiation due to hydrated aerosols in mist and fog

    NASA Astrophysics Data System (ADS)

    Elias, T.; Dupont, J.-C.; Hammer, E.; Hoyle, C. R.; Haeffelin, M.; Burnet, F.; Jolivet, D.

    2015-06-01

    The study assesses the contribution of aerosols to the extinction of visible radiation in the mist-fog-mist cycle. Relative humidity is large in the mist-fog-mist cycle, and aerosols most efficient in interacting with visible radiation are hydrated and compose the accumulation mode. Measurements of the microphysical and optical properties of these hydrated aerosols with diameters larger than 0.4 μm were carried out near Paris, during November 2011, under ambient conditions. Eleven mist-fog-mist cycles were observed, with a cumulated fog duration of 96 h, and a cumulated mist-fog-mist cycle duration of 240 h. In mist, aerosols grew by taking up water at relative humidities larger than 93%, causing a visibility decrease below 5 km. While visibility decreased down from 5 to a few kilometres, the mean size of the hydrated aerosols increased, and their number concentration (Nha) increased from approximately 160 to approximately 600 cm-3. When fog formed, droplets became the strongest contributors to visible radiation extinction, and liquid water content (LWC) increased beyond 7 mg m-3. Hydrated aerosols of the accumulation mode co-existed with droplets, as interstitial non-activated aerosols. Their size continued to increase, and some aerosols achieved diameters larger than 2.5 μm. The mean transition diameter between the aerosol accumulation mode and the small droplet mode was 4.0 ± 1.1 μm. Nha also increased on average by 60 % after fog formation. Consequently, the mean contribution to extinction in fog was 20 ± 15% from hydrated aerosols smaller than 2.5 μm and 6 ± 7% from larger aerosols. The standard deviation was large because of the large variability of Nha in fog, which could be smaller than in mist or 3 times larger. The particle extinction coefficient in fog can be computed as the sum of a droplet component and an aerosol component, which can be approximated by 3.5 Nha (Nha in cm-3 and particle extinction coefficient in Mm-1. We observed an influence of

  4. Improved stratospheric aerosol extinction profiles from SCIAMACHY: validation and sample results

    NASA Astrophysics Data System (ADS)

    von Savigny, C.; Ernst, F.; Rozanov, A.; Hommel, R.; Eichmann, K.-U.; Rozanov, V.; Burrows, J. P.; Thomason, L. W.

    2015-12-01

    Stratospheric aerosol extinction profiles have been retrieved from SCIAMACHY/Envisat measurements of limb-scattered solar radiation. The retrieval is an improved version of an algorithm presented earlier. The retrieved aerosol extinction profiles are compared to co-located aerosol profile measurements from the SAGE II solar occultation instrument at a wavelength of 525 nm. Comparisons were carried out with two versions of the SAGE II data set (version 6.2 and the new version 7.0). In a global average sense the SCIAMACHY and the SAGE II version 7.0 extinction profiles agree to within about 10 % for altitudes above 15 km. Larger relative differences (up to 40 %) are observed at specific latitudes and altitudes. We also find differences between the two SAGE II data versions of up to 40 % for specific latitudes and altitudes, consistent with earlier reports. Sample results on the latitudinal and temporal variability of stratospheric aerosol extinction and optical depth during the SCIAMACHY mission period are presented. The results confirm earlier reports that a series of volcanic eruptions is responsible for the increase in stratospheric aerosol optical depth from 2002 to 2012. Above about an altitude of 28 km, volcanic eruptions are found to have negligible impact in the period 2002-2012.

  5. Improved stratospheric aerosol extinction profiles from SCIAMACHY: validation and sample results

    NASA Astrophysics Data System (ADS)

    von Savigny, C.; Ernst, F.; Rozanov, A.; Hommel, R.; Eichmann, K.-U.; Rozanov, V.; Burrows, J. P.; Thomason, L. W.

    2015-08-01

    Stratospheric aerosol extinction profiles have been retrieved from SCIAMACHY/Envisat measurements of limb-scattered solar radiation. The retrieval is an improved version of an algorithm presented earlier. The retrieved aerosol extinction profiles are compared to co-located aerosol profile measurements with the SAGE II solar occultation instrument at a wavelength of 525 nm. Comparisons were carried out with two versions of the SAGE II data set (version 6.2 and the new version 7.0). In a global average sense the SCIAMACHY and the SAGE II version 7.0 extinction profiles agree to within about 10 % for altitudes above 15 km. Larger relative differences (up to 40 %) are observed at specific latitudes and altitudes. We also find differences between the two SAGE II data versions of up to 40 % for specific latitudes and altitudes. Sample results on the latitudinal and temporal variability of stratospheric aerosol extinction and optical depth during the SCIAMACHY mission period are presented. The results indicate that a series of volcanic eruptions is responsible for the increase in stratospheric aerosol optical depth from 2002 to 2012. Above about 28 km altitude volcanic eruptions are found to have negligible impact in the period 2002 to 2012.

  6. Verification and application of the extended spectral deconvolution algorithm (SDA+) methodology to estimate aerosol fine and coarse mode extinction coefficients in the marine boundary layer

    NASA Astrophysics Data System (ADS)

    Kaku, K. C.; Reid, J. S.; O'Neill, N. T.; Quinn, P. K.; Coffman, D. J.; Eck, T. F.

    2014-10-01

    The spectral deconvolution algorithm (SDA) and SDA+ (extended SDA) methodologies can be employed to separate the fine and coarse mode extinction coefficients from measured total aerosol extinction coefficients, but their common use is currently limited to AERONET (AErosol RObotic NETwork) aerosol optical depth (AOD). Here we provide the verification of the SDA+ methodology on a non-AERONET aerosol product, by applying it to fine and coarse mode nephelometer and particle soot absorption photometer (PSAP) data sets collected in the marine boundary layer. Using data sets collected on research vessels by NOAA-PMEL(National Oceanic and Atmospheric Administration - Pacific Marine Environmental Laboratory), we demonstrate that with accurate input, SDA+ is able to predict the fine and coarse mode scattering and extinction coefficient partition in global data sets representing a range of aerosol regimes. However, in low-extinction regimes commonly found in the clean marine boundary layer, SDA+ output accuracy is sensitive to instrumental calibration errors. This work was extended to the calculation of coarse and fine mode scattering coefficients with similar success. This effort not only verifies the application of the SDA+ method to in situ data, but by inference verifies the method as a whole for a host of applications, including AERONET. Study results open the door to much more extensive use of nephelometers and PSAPs, with the ability to calculate fine and coarse mode scattering and extinction coefficients in field campaigns that do not have the resources to explicitly measure these values.

  7. Microphysical Modeling and POAM III Observations of Aerosol Extinction in the 1998-2003 Antarctic Stratosphere

    NASA Astrophysics Data System (ADS)

    Benson, C. M.; Drdla, K.; Nedoluha, G. E.; Shettle, E. P.; Alfred, J.; Hoppel, K. W.

    2005-12-01

    The Integrated Microphysics and Chemistry on Trajectories (IMPACT) model is used to study Polar stratospheric cloud formation and evolution in the Southern Polar vortex during the 1998-2003 winters. The model is applied to individual air parcels which are advected through the vortex on UKMO wind and temperature fields. The parcel temperature and pressure histories are used by IMPACT to calculate the formation and sedimentation of ice, NAT, SAT, and STS aerosols. Model results are validated by the Polar Ozone and Aerosol Measurement (POAM) III solar occultation instrument. Comparisons of POAM data to the model results help to constrain the microphysical parameters influencing aerosol formation and growth. Measurements of the water vapor mixing ratio are of limited use in clarifying the model microphysics; however, POAM measurements of aerosol extinction prove to be valuable in differentiating model runs. Specifically, the relationship of aerosol extinction to temperature arises from the different temperatures at which the various particle types form and grow. Comparisons of IMPACT calculations of this relationship to POAM measurements constrain the initial fraction of nuclei available for heterogeneous NAT freezing to 0.02% of all aerosols. Constraints are also placed on the ice accommodation coefficient and the NAT-ice lattice compatibility factor. However, these two parameters have similar effects on the extinction-temperature relationship, and thus a range of values are permissible for each.

  8. Measurements of Stratospheric Pinatubo Aerosol Extinction Profiles by a Raman Lidar

    NASA Technical Reports Server (NTRS)

    Abo, Makoto; Nagasawa, Chikao

    1992-01-01

    The Raman lidar has been used for remote measurements of water vapor, ozone and atmospheric temperature in the lower troposphere because the Raman cross section is three orders smaller than the Rayleigh cross section. We estimated the extinction coefficients of the Pinatubo volcanic aerosol in the stratosphere using a Raman lidar. If the precise aerosol extinction coefficients are derived, the backscatter coefficient of a Mie scattering lidar will be more accurately estimated. The Raman lidar has performed to measure density profiles of some species using Raman scattering. Here we used a frequency-doubled Nd:YAG laser for transmitter and received nitrogen vibrational Q-branch Raman scattering signal. Ansmann et al. (1990) derived tropospherical aerosol extinction profiles with a Raman lidar. We think that this method can apply to dense stratospheric aerosols such as Pinatubo volcanic aerosols. As dense aerosols are now accumulated in the stratosphere by Pinatubo volcanic eruption, the error of Ramen lidar signal regarding the fluctuation of air density can be ignored.

  9. Enhanced extinction of visible radiation due to hydrated aerosols in mist and fog

    NASA Astrophysics Data System (ADS)

    Elias, T.; Dupont, J.-C.; Hammer, E.; Hoyle, C. R.; Haeffelin, M.; Burnet, F.; Jolivet, D.

    2015-01-01

    The study assesses the contribution of aerosols to the extinction of visible radiation in the mist-fog-mist cycle. Measurements of the microphysical and optical properties of hydrated aerosols with diameters larger than 400 nm, composing the accumulation mode, which are the most efficient to interact with visible radiation, were carried out near Paris, during November 2011, in ambient conditions. Eleven mist-fog-mist cycles were observed, with cumulated fog duration of 95 h, and cumulated mist-fog-mist duration of 240 h. In mist, aerosols grew up by taking up water at relative humidities larger than 93%, causing a visibility decrease below 5 km. While visibility decreased down to few km, the mean size of the hydrated aerosols increased, and their number concentration (Nha) increased from approximately 160 to approximately 600 cm-3. When fog formed, droplets became the strongest contributors to visible radiation extinction, and liquid water content (LWC) increased beyond 7 mg m-3. Hydrated aerosols of the accumulation mode co-existed with droplets, as interstitial non-activated aerosols. Their size continued to increase, and a significant proportion of aerosols achieved diameters larger than 2.5 μm. The mean transition diameter between the accumulation mode and the small droplet mode was 4.0 ± 1.1 μm. Moreover Nha increased on average by 60% after fog formation. Consequently the mean aerosol contribution to extinction in fog was 20 ± 15% for diameter smaller than 2.5 μm and 6 ± 7% beyond. The standard deviation is large because of the large variability of Nha in fog, which could be smaller than in mist or three times larger. The particle extinction coefficient in fog can be computed as the sum of a droplet component and an aerosol component, which can be approximated by 3.5 Nha (Nha in cm-3 and particle extinction coefficient in Mm-1). We observed an influence of the main formation process on Nha, but not on the contribution to fog extinction by aerosols

  10. Light extinction by aerosols during summer air pollution

    NASA Technical Reports Server (NTRS)

    Kaufman, Y. J.; Fraser, R. S.

    1983-01-01

    In order to utilize satellite measurements of optical thickness over land for estimating aerosol properties during air pollution episodes, the optical thickness was measured from the surface and investigated. Aerosol optical thicknesses have been derived from solar transmission measurements in eight spectral bands within the band lambda 440-870 nm during the summers of 1980 and 1981 near Washington, DC. The optical thicknesses for the eight bands are strongly correlated. It was found that first eigenvalue of the covariance matrix of all observations accounts for 99 percent of the trace of the matrix. Since the measured aerosol optical thickness was closely proportional to the wavelength raised to a power, the aerosol size distribution derived from it is proportional to the diameter (d) raised to a power for the range of diameters between 0.1 to 1.0 micron. This power is insensitive to the total optical thickness. Changes in the aerosol optical thickness depend on several aerosol parameters, but it is difficult to identify the dominant one. The effects of relative humidity and accumulation mode concentration on the optical thickness are analyzed theoretically, and compared with the measurements.

  11. In situ vertical profiles of aerosol extinction, mass, and composition over the SEUS during the SENEX and SEAC4RS studies

    NASA Astrophysics Data System (ADS)

    Wagner, N. L.; Brock, C. A.; Day, D. A.; Diskin, G. S.; Gordon, T. D.; Graus, M.; Holloway, J. S.; Huey, L. G.; Jimenez, J. L.; Lack, D.; Liao, J.; Liu, X.; Markovic, M. Z.; Middlebrook, A. M.; Perring, A. E.; Richardson, M.; Schwarz, J. P.; Warneke, C.; Welti, A.; Wisthaler, A.; Ziemba, L. D.; Murphy, D. M.; Campuzano Jost, P.

    2014-12-01

    Shallow cumulus convection enhances vertical transport of trace gases and aerosol and creates a cloudy transition layer on top of the sub-cloud mixed layer. Two recent studies have proposed that an elevated layer of enhanced organic aerosol over the southeastern United States (SEUS) could explain the discrepancy in the summertime enhancement of aerosol optical depth (AOD) and summertime enhancement of surface measurements of aerosol mass. We investigate the vertical profile of aerosol over the SEUS during the summertime using in situ aircraft-based measurements of aerosol from the SENEX and SEAC4RS studies. During shallow cumulus convection over the SEUS, we found that aerosol and trace gas concentration in the transition layer are diluted by cleaner air from the free troposphere, and the absolute aerosol loading decreases with altitude in the transition layer. However, after normalizing the vertical profiles to the CO boundary layer enhancement to correct for the dilution, the aerosol mass, volume, and extinction relative to the boundary layer CO enhancement is ~20% greater in the transition layer than in the mixed layer. The enhancement of aerosol loading suggests production of aerosol mass in the transition layer, although biomass burning could also be the source of the enhancement. The median composition of the aerosol in the mixed layer is ~70% organics and ~18% sulfate, while it is 65% organics and 23% sulfate in the transition layer. The composition of the aerosol enhancement in the transition layer is roughly equal parts sulfate and organics by mass. The enhancement of aerosol extinction in the transition layer is not sufficient to explain the summertime enhancement of AOD over SEUS.

  12. A new high spectral resolution lidar technique for direct retrievals of cloud and aerosol extinction

    NASA Astrophysics Data System (ADS)

    Yorks, J. E.; McGill, M. J.; Hlavka, D. L.

    2014-12-01

    The Airborne Cloud-Aerosol Transport System (ACATS) is a Doppler lidar system and high spectral resolution lidar (HSRL) recently developed at NASA Goddard Space Flight Center (GSFC). ACATS passes the returned atmospheric backscatter through a single etalon and divides the transmitted signal into several channels (wavelength intervals), which are measured simultaneously and independently (Figure 1). Both the particulate and molecular scattered signal can be directly and unambiguously measured, allowing for direct retrievals of particle extinction. The broad Rayleigh-scattered spectrum is imaged as a nearly flat background, illustrated in Figure 1c. The integral of the particulate backscattered spectrum is analogous to the aerosol measurement from the typical absorption filter HSRL technique in that the molecular and particulate backscatter components can be separated (Figure 1c and 1d). The main difference between HSRL systems that use the iodine filter technique and the multichannel etalon technique used in the ACATS instrument is that the latter directly measures the spectral broadening of the particulate backscatter using the etalon to filter out all backscattered light with the exception of a narrow wavelength interval (1.5 picometers for ACATS) that contains the particulate spectrum (grey, Figure 1a). This study outlines the method and retrieval algorithms for ACATS data products, focusing on the HSRL derived cloud and aerosol properties. While previous ground-based multi-channel etalon systems have been built and operated for wind retrievals, there has been no airborne demonstration of the technique and the method has not been used to derive HSRL cloud and aerosol properties. ACATS has flown on the NASA ER-2 during flights over Alaska in July 2014 and as part of the Wallops Airborne Vegetation Experiment (WAVE) in September 2012. This study will focus on the HSRL aspect of the ACATS instrument, since the method and retrieval algorithms have direct application

  13. Simultaneous measurement of optical scattering and extinction on dispersed aerosol samples.

    PubMed

    Dial, Kathy D; Hiemstra, Scott; Thompson, Jonathan E

    2010-10-01

    Accurate and precise measurements of light scattering and extinction by atmospheric particulate matter aid understanding of tropospheric photochemistry and are required for estimates of the direct climate effects of aerosols. In this work, we report on a second generation instrument to simultaneously measure light scattering (b(scat)) and extinction (b(ext)) coefficient by dispersed aerosols. The ratio of scattering to extinction is known as the single scatter albedo (SSA); thus, the instrument is referred to as the albedometer. Extinction is measured with the well-established cavity ring-down (CRD) technique, and the scattering coefficient is determined through collection of light scattered from the CRD beam. The improved instrument allows reduction in sample volume to <1% of the original design, and a reduction in response time by a factor of >30. Through using a commercially available condensation particle counter (CPC), we have measured scattering (σ(scat)) and extinction (σ(ext)) cross sections for size-selected ammonium sulfate and nigrosin aerosols. In most cases, the measured scattering and extinction cross section were within 1 standard deviation of the accepted values generated from Mie theory suggesting accurate measurements are made. While measurement standard deviations for b(ext) and b(scat) were generally <1 Mm(-1) when the measurement cell was sealed or purged with filtered air, relative standard deviations >0.1 for these variables were observed when the particle number density was low. It is inferred that statistical fluctuations of the absolute number of particles within the probe beam leads to this effect. However, measured relative precision in albedo is always superior to that which would be mathematically propagated assuming independent measurements of b(scat) and b(ext). Thus, this report characterizes the measurement precision achieved, evaluates the potential for systematic error to be introduced through light absorption by gases

  14. Inter-Comparison of ILAS-II Version 1.4 Aerosol Extinction Coefficient at 780 nm with SAGE II, SAGE III, and POAM III Aerosol Data

    NASA Technical Reports Server (NTRS)

    Saitoh, Naoko; Hayashida, S.; Sugita, T.; Nakajima, H.; Yokota, T.; Hayashi, M.; Shiraishi, K.; Kanzawa, H.; Ejiri, M. K.; Irie, H.; Tanaka, T.; Terao, Y.; Kobayashi, H.; Sasano, Y.; Bevilacqua, R.; Randall, C.; Thomason, L.; Taha, G.

    2006-01-01

    The Improved Limb Atmospheric Spectrometer (ILAS) II on board the Advanced Earth Observing Satellite (ADEOS) II observed stratospheric aerosol in visible/near-infrared/infrared spectra over high latitudes in the Northern and Southern Hemispheres. Observations were taken intermittently from January to March, and continuously from April through October, 2003. We assessed the data quality of ILAS-II version 1.4 aerosol extinction coefficients at 780 nm from comparisons with the Stratospheric Aerosol and Gas Experiment (SAGE) II, SAGE III, and the Polar Ozone and Aerosol Measurement (POAM) III aerosol data. At heights below 20 km in the Northern Hemisphere, aerosol extinction coefficients from ILAS-II agreed with those from SAGE II and SAGE III within 10%, and with those from POAM III within 15%. From 20 to 26 km, ILAS-II aerosol extinction coefficients were smaller than extinction coefficients from the other sensors; differences between ILAS-II and SAGE II ranged from 10% at 20 km to 34% at 26 km. ILAS-II aerosol extinction coefficients from 20 to 25 km in February over the Southern Hemisphere had a negative bias (12-66%) relative to SAGE II aerosol data. The bias increased with increasing altitude. Comparisons between ILAS-II and POAM III aerosol extinction coefficients from January to May in the Southern Hemisphere (defined as the non-Polar Stratospheric Cloud (PSC) season ) yielded qualitatively similar results. From June to October (defined as the PSC season ), aerosol extinction coefficients from ILAS-II were smaller than those from POAM III above 17 km, as in the case of the non-PSC season; however, ILAS-II and POAM III aerosol data were within 15% of each other from 12 to 17 km.

  15. Influence of the aerosol solar extinction on photochemistry during the 2010 Russian wildfires episode

    NASA Astrophysics Data System (ADS)

    Péré, J. C.; Bessagnet, B.; Pont, V.; Mallet, M.; Minvielle, F.

    2015-10-01

    In this work, impact of aerosol solar extinction on the photochemistry over eastern Europe during the 2010 wildfires episode is discussed for the period from 5 to 12 August 2010, which coincides to the peak of fire activity. The methodology is based on an online coupling between the chemistry-transport model CHIMERE (extended by an aerosol optical module) and the radiative transfer code TUV. Results of simulations indicate an important influence of the aerosol solar extinction, in terms of intensity and spatial extent, with a reduction of the photolysis rates of NO2 and O3 up to 50 % (in daytime average) along the aerosol plume transport. At a regional scale, these changes in photolysis rates lead to a 3-15 % increase in the NO2 daytime concentration and to an ozone reduction near the surface of 1-12 %. The ozone reduction is shown to occur over the entire boundary layer, where aerosols are located. Also, the total aerosol mass concentration (PM10) is shown to be decreased by 1-2 %, on average during the studied period, caused by a reduced formation of secondary aerosols such as sulfates and secondary organics (4-10 %) when aerosol impact on photolysis rates is included. In terms of model performance, comparisons of simulations with air quality measurements at Moscow indicate that an explicit representation of aerosols interaction with photolysis rates tend to improve the estimation of the near-surface concentration of ozone and nitrogen dioxide as well as the formation of inorganic aerosol species such as ammonium, nitrates and sulfates.

  16. Radiative properties of the background aerosol: absorption component of extinction.

    PubMed

    Clarke, A D; Charlson, R J

    1985-07-19

    The light-scattering and light-absorption coefficients of the global background aerosol define its single-scatter albedo. Continuous, simultaneous measurements of these optical coefficients were made on a daily basis for the remote marine mid-troposphere; such measurements are essential for assessment of the effects of aerosol on atmospheric radiative transfer. Measurements of light-absorption coefficients made at the Mauna Loa Observatory in Hawaii were higher than expected, and the single-scatter albedo was lower than the value often used in radiative transfer models. Soot appears to be the most likely primary absorber, and hemispheric dispersal of this combustion-derived material is suggested. PMID:17759145

  17. Selection Algorithm for the CALIPSO Lidar Aerosol Extinction-to-Backscatter Ratio

    NASA Technical Reports Server (NTRS)

    Omar, Ali H.; Winker, David M.; Vaughan, Mark A.

    2006-01-01

    The extinction-to-backscatter ratio (S(sub a)) is an important parameter used in the determination of the aerosol extinction and subsequently the optical depth from lidar backscatter measurements. We outline the algorithm used to determine Sa for the Cloud and Aerosol Lidar and Infrared Pathfinder Spaceborne Observations (CALIPSO) lidar. S(sub a) for the CALIPSO lidar will either be selected from a look-up table or calculated using the lidar measurements depending on the characteristics of aerosol layer. Whenever suitable lofted layers are encountered, S(sub a) is computed directly from the integrated backscatter and transmittance. In all other cases, the CALIPSO observables: the depolarization ratio, delta, the layer integrated attenuated backscatter, beta, and the mean layer total attenuated color ratio, gamma, together with the surface type, are used to aid in aerosol typing. Once the type is identified, a look-up-table developed primarily from worldwide observations, is used to determine the S(sub a) value. The CALIPSO aerosol models include desert dust, biomass burning, background, polluted continental, polluted dust, and marine aerosols.

  18. Comparison of Aerosol Backscatter and Extinction Profiles Based on the Earlinet Database and the Single Calculus Chain for Thessaloniki Greece (2001-2014)

    NASA Astrophysics Data System (ADS)

    Voudouri, K.; Siomos, N.; Giannakaki, E.; Amiridis, V.; d'Amico, G.; Balis, D. S.

    2016-06-01

    Aerosol backscatter and extinction coefficient profiles derived by the Single Calculus Chain (SCC) algorithm, which was developed within the European Aerosol Research Lidar Network (EARLINET) are compared with profiles derived by the operational inversion algorithm of Thessaloniki. Measurements performed during the period 2001-2014, that have already been uploaded in the EARLINET database, are considered in this study. The objective of this study is to verify, for the case of Thessaloniki, the consistency of the climatology of the aerosol profiles based on SCC and the EARLINET database data respectively. In this paper we show example comparisons for each lidar product submitted in the official database.

  19. Mount St. Helens related aerosol properties from solar extinction measurements

    NASA Technical Reports Server (NTRS)

    Michalsky, J. J.; Kleckner, E. W.; Stokes, G. M.

    1982-01-01

    A network of solar radiometers, operated on the North American Continent for an average of 2 years before the first major eruption of Mount St. Helens, Washington, continues to collect direct solar data through the eruptive phase of this volcano. The radiometers collect spectral data through 12 interference filters spanning the sensitivity of the photodiode used as detector. The data are collected every 5 minutes in seven filters and every 15 minutes in five additional filters. A variant of the classical Langley method has been used to measure the optical depth of the aerosols as a function of wavelength. The network, which is the nearest station, is located some 180 kilometers east of the volcano, well within range of noticeable effects during much of the minor as well as major activity. The wavelength dependence of the aerosol-optical depth before and after the 22 July 1980 major eruption, which was well characterized because of favorable meteorological conditions is discussed.

  20. Using high time resolution aerosol and number size distribution measurements to estimate atmospheric extinction.

    PubMed

    Malm, William C; McMeeking, Gavin R; Kreidenweis, Sonia M; Levin, Ezra; Carrico, Christian M; Day, Derek E; Collett, Jeffrey L; Lee, Taehyoung; Sullivan, Amy P; Raja, Suresh

    2009-09-01

    Rocky Mountain National Park is experiencing reduced visibility and changes in ecosystem function due to increasing levels of oxidized and reduced nitrogen. The Rocky Mountain Atmospheric Nitrogen and Sulfur (RoMANS) study was initiated to better understand the origins of sulfur and nitrogen species as well as the complex chemistry occurring during transport from source to receptor. As part of the study, a monitoring program was initiated for two 1-month time periods--one during the spring and the other during late summer/fall. The monitoring program included intensive high time resolution concentration measurements of aerosol number size distribution, inorganic anions, and cations, and 24-hr time resolution of PM2.5 and PM10 mass, sulfate, nitrate, carbon, and soil-related elements concentrations. These data are combined to estimate high time resolution concentrations of PM2.5 and PM10 aerosol mass and fine mass species estimates of ammoniated sulfate, nitrate, and organic and elemental carbon. Hour-by-hour extinction budgets are calculated by using these species concentration estimates and measurements of size distribution and assuming internal and external particle mixtures. Summer extinction was on average about 3 times higher than spring extinction. During spring months, sulfates, nitrates, carbon mass, and PM10 - PM2.5 mass contributed approximately equal amounts of extinction, whereas during the summer months, carbonaceous material extinction was 2-3 times higher than other species. PMID:19785272

  1. Measurement of wavelength-dependent extinction to distinguish between absorbing and nonabsorbing aerosol particulates

    NASA Technical Reports Server (NTRS)

    Portscht, R.

    1977-01-01

    Measurements of spectral transmission factors in smoky optical transmission paths reveal a difference between wavelength exponents of the extinction cross section of high absorption capacity and those of low absorption capacity. A theoretical explanation of this behavior is presented. In certain cases, it is possible to obtain data on the absorption index of aerosol particles in the optical path by measuring the spectral decadic extinction coefficient at, at least, two wavelengths. In this manner it is possible, for instance, to distinguish smoke containing soot from water vapor.

  2. CART and GSFC raman lidar measurements of atmospheric aerosol backscattering and extinction profiles for EOS validation and ARM radiation studies

    NASA Technical Reports Server (NTRS)

    Ferrare, R. A.; Turner, D. D.; Melfi, S. H.; Whiteman, D. N.; Schwenner, G.; Evans, K. D.; Goldsmith, J. E. M.; Tooman, T.

    1998-01-01

    The aerosol retrieval algorithms used by the Moderate-Resolution Imaging Spectroradiometer (MODIS) and Multi-Angle Imaging SpectroRadiometer (MISR) sensors on the Earth Observing Satellite (EOS) AM-1 platform operate by comparing measured radiances with tabulated radiances that have been computed for specific aerosol models. These aerosol models are based almost entirely on surface and/or column averaged measurements and so may not accurately represent the ambient aerosol properties. Therefore, to validate these EOS algorithms and to determine the effects of aerosols on the clear-sky radiative flux, we have begun to evaluate the vertical variability of ambient aerosol properties using the aerosol backscattering and extinction profiles measured by the Cloud and Radiation Testbed (CART) and NASA Goddard Space Flight Center (GSFC) Raman Lidars. Using the procedures developed for the GSFC Scanning Raman Lidar (SRL), we have developed and have begun to implement algorithms for the CART Raman Lidar to routinely provide profiles of aerosol extinction and backscattering during both nighttime and ,daytime operations. Aerosol backscattering and extinction profiles are computed for both lidar systems using data acquired during the 1996 and 1997 Water Vapor Intensive Operating Periods (IOPs). By integrating these aerosol extinction profiles, we derive measurements of aerosol optical thickness and compare these with coincident sun photometer measurements. We also use these measurements to measure the aerosol extinction/backscatter ratio S(sub a) (i.e. 'lidar ratio'). Furthermore, we use the simultaneous water vapor measurements acquired by these Raman lidars to investigate the effects of water vapor on aerosol optical properties.

  3. Modified cavity attenuated phase shift (CAPS) method for airborne aerosol light extinction measurement

    NASA Astrophysics Data System (ADS)

    Perim de Faria, Julia; Bundke, Ulrich; Freedman, Andrew; Petzold, Andreas

    2015-04-01

    Monitoring the direct impact of aerosol particles on climate requires the consideration of at least two major factors: the aerosol single-scattering albedo, defined as the relation between the amount of energy scattered and extinguished by an ensemble of aerosol particles; and the aerosol optical depth, calculated from the integral of the particle extinction coefficient over the thickness of the measured aerosol layer. Remote sensing networks for measuring these aerosol parameters on a regular basis are well in place (e.g., AERONET, ACTRIS), whereas the regular in situ measurement of vertical profiles of atmospheric aerosol optical properties remains still an important challenge in quantifying climate change. The European Research Infrastructure IAGOS (In-service Aircraft for a Global Observing System; www.iagos.org) responds to the increasing requests for long-term, routine in situ observational data by using commercial passenger aircraft as measurement platform. However, scientific instrumentation for the measurement of atmospheric constituents requires major modifications before being deployable aboard in-service passenger aircraft. Recently, a compact and robust family of optical instruments based on the cavity attenuated phase shift (CAPS) technique has become available for measuring aerosol light extinction. In particular, the CAPS PMex particle optical extinction monitor has demonstrated sensitivity of less than 2 Mm-1 in 1 second sampling period; with a 60 s averaging time, a detection limit of less than 0.3 Mm-1 can be achieved. While this technique was successfully deployed for ground-based atmospheric measurements under various conditions, its suitability for operation aboard aircraft in the free and upper free troposphere still has to be demonstrated. Here, we report on the modifications of a CAPS PMex instrument for measuring aerosol light extinction on aircraft, and subsequent laboratory tests for evaluating the modified instrument prototype: (1) In a

  4. Comparison of vertical aerosol extinction coefficients from in-situ and LIDAR measurements

    NASA Astrophysics Data System (ADS)

    Rosati, B.; Herrmann, E.; Bucci, S.; Fierli, F.; Cairo, F.; Gysel, M.; Tillmann, R.; Größ, J.; Gobbi, G. P.; Di Liberto, L.; Di Donfrancesco, G.; Wiedensohler, A.; Weingartner, E.; Virtanen, A.; Mentel, T. F.; Baltensperger, U.

    2015-07-01

    Vertical profiles of aerosol optical properties were explored in a case study near the San Pietro Capofiume (SPC) ground station during the PEGASOS Po Valley campaign in the summer of 2012. A Zeppelin NT airship was employed to investigate the effect of the dynamics of the planetary boundary layer at altitudes between ~ 50-800 m above ground. Determined properties included the aerosol size distribution, the hygroscopic growth factor, the effective index of refraction and the light absorption coefficient. The first three parameters were used to retrieve the light scattering coefficient. Simultaneously, direct measurements of both the scattering and absorption coefficient were carried out at the SPC ground station. Additionally, a LIDAR system provided aerosol extinction coefficients for a vertically resolved comparison between in-situ and remote sensing results. First, the airborne results at low altitudes were validated with the ground measurements. Agreement within approximately ±25 and ±20% was found for the dry scattering and absorption coefficient, respectively. The single scattering albedo, ranged between 0.83 to 0.95, indicating the importance of the absorbing particles in the Po Valley region. A clear layering of the atmosphere was observed during the beginning of the flight (until ~ 10 local time) before the mixed layer (ML) was fully developed. Highest extinction coefficients were found at low altitudes, in the new ML, while values in the residual layer, which could be probed at the beginning of the flight at elevated altitudes, were lower. At the end of the flight (after ~ 12 local time) the ML was fully developed, resulting in constant extinction coefficients at all altitudes measured on the Zeppelin NT. LIDAR results captured these dynamic features well and good agreement was found for the extinction coefficients compared to the in-situ results, using fixed LIDAR ratios (LR) between 30 and 70 sr for the altitudes probed with the Zeppelin. These LR are

  5. Effect of coagulation on extinction in an aerosol plume propagating in the atmosphere.

    PubMed

    Tsang, T H; Brock, J R

    1982-05-01

    Model studies based on the K-theory diffusion assumption have been carried out on aerosol plumes issuing from a crosswind line source in which advection, vertical diffusion, coagulation, sedimentation, and dry deposition are occurring. Procedures are described and a few typical results are presented. It is shown that in appropriate conditions coagulation can play an important role in altering extinction in the plume. An important coupling effect between coagulation and sedimentation/deposition has been demonstrated. In a coagulating plume it is found that total particle mass concentration cannot be inferred from measurements of extinction without a detailed consideration of the effects of coagulation. In realistic atmospheric simulations isopleths of extinction in the plume cross section show complex forms resulting from the wind gradient and its interactions with vertical diffusion and the coagulation and sedimentation/deposition processes. PMID:20389900

  6. Use of Lidar Derived Optical Extinction and Backscattering Coefficients Near Cloud Base to Explore Aerosol-Cloud Interactions

    NASA Astrophysics Data System (ADS)

    Han, Zaw; Wu, Yonhgua; Gross, Barry; Moshary, Fred

    2016-06-01

    Combination of microwave radiometer (MWR) and mutlifilter rotating shadowband radiometer (MFRSR) measurement data together with SBDART radiative transfer model to compute cloud optical depth (COD) and cloud droplet effective radius (Reff). Quantify the first aerosol indirect effect using calculated Reff and aerosol extinction from Raman lidar measurement in urban coastal region. Illustrate comparison between ground-based and satellite retrievals. Demonstrate relationship between surface aerosol (PM2.5) loading and Reff. We also explain the sensitivity of aerosol-cloud-index (ACI) depend on the aerosol layer from cloud base height. Potential used of less noisy elastic backscattering to calculate the ACI instead of using Raman extinction. We also present comparison of elastic backscattering and Raman extinction correlation to Reff.

  7. SAGE III Aerosol Extinction Validation in the Arctic Winter: Comparisons with SAGE II and POAM III

    NASA Technical Reports Server (NTRS)

    Thomason, L. W.; Poole, L. R.; Randall, C. E.

    2007-01-01

    The use of SAGE III multiwavelength aerosol extinction coefficient measurements to infer PSC type is contingent on the robustness of both the extinction magnitude and its spectral variation. Past validation with SAGE II and other similar measurements has shown that the SAGE III extinction coefficient measurements are reliable though the comparisons have been greatly weighted toward measurements made at mid-latitudes. Some aerosol comparisons made in the Arctic winter as a part of SOLVE II suggested that SAGE III values, particularly at longer wavelengths, are too small with the implication that both the magnitude and the wavelength dependence are not reliable. Comparisons with POAM III have also suggested a similar discrepancy. Herein, we use SAGE II data as a common standard for comparison of SAGE III and POAM III measurements in the Arctic winters of 2002/2003 through 2004/2005. During the winter, SAGE II measurements are made infrequently at the same latitudes as these instruments. We have mitigated this problem through the use potential vorticity as a spatial coordinate and thus greatly increased the number of coincident events. We find that SAGE II and III extinction coefficient measurements show a high degree of compatibility at both 1020 nm and 450 nm except a 10-20% bias at both wavelengths. In addition, the 452 to 1020-nm extinction ratio shows a consistent bias of approx. 30% throughout the lower stratosphere. We also find that SAGE II and POAM III are on average consistent though the comparisons show a much higher variability and larger bias than SAGE II/III comparisons. In addition, we find that the two data sets are not well correlated below 18 km. Overall, we find both the extinction values and the spectral dependence from SAGE III are robust and we find no evidence of a significant defect within the Arctic vortex.

  8. Forecasting of aerosol extinction of the sea and coastal atmosphere surface layer

    NASA Astrophysics Data System (ADS)

    Kaloshin, G. A.

    2010-04-01

    The focus of our study is the extinction and optical effects due to aerosol in a specific coastal region. The aerosol microphysical model of the marine and coastal atmosphere surface layer is considered. The model is made on the basis of the long-term experimental data received at researches of aerosol sizes distribution function (dN/dr) in the band particles sizes in 0.01 - 100 μk. The model is developed by present time for the band of heights is 0 - 25 m. Bands of wind speed is 3 - 18 km/s, sizes fetch is up to 120 km, RH = 40 - 98 %. Key feature of model is parameterization of amplitude and width of the modes as functions of fetch and wind speed. In the paper the dN/dr behavior depending at change meteorological parameters, heights above sea level, fetch (X), wind speed (U) and RH is show. On the basis of the developed model with usage of Mie theory for spheres the description of last version of developed code MaexPro (Marine Aerosol Extinction Profiles) for spectral profiles of aerosol extinction coefficients α(λ) calculations in the wavelength band, equal λ = 0.2 - 12 μm is presented. The received results are compared models NAN and ANAM. Also α(λ) profiles for various wind modes (combinations X and U) calculated by MaexPro code are given. The calculated spectrums of α(λ) profiles are compared with experimental data of α(λ) received by a transmission method in various geographical areas.

  9. Airborne DOAS measurements in Arctic: vertical distributions of aerosol extinction coefficient and NO2 concentration

    NASA Astrophysics Data System (ADS)

    Merlaud, A.; van Roozendael, M.; Theys, N.; Fayt, C.; Hermans, C.; Quennehen, B.; Schwarzenboeck, A.; Ancellet, G.; Pommier, M.; Pelon, J.; Burkhart, J.; Stohl, A.; de Mazière, M.

    2011-05-01

    We report airborne differential optical absorption spectroscopy (DOAS) measurements of aerosol extinction and NO2 tropospheric profiles performed off the North coast of Norway in April 2008. The DOAS instrument was installed on the Safire ATR-42 aircraft during the POLARCAT-France spring campaign and recorded scattered light spectra in near-limb geometry using a scanning telescope. We use O4 slant column measurements to derive the aerosol extinction at 360 nm. Regularization is based on the maximum a posteriori solution, for which we compare a linear and a logarithmic approach. The latter inherently constrains the solution to positive values and yields aerosol extinction profiles more consistent with independently measured size distributions. Two soundings are presented, performed on 8 April 2008 above 71° N, 22° E and on 9 April 2008 above 70° N, 17.8° E. The first profile shows aerosol extinction and NO2 in the marine boundary layer with respective values of 0.04±0.005 km-1 and 1.9±0.3 × 109 molec cm-3. A second extinction layer of 0.01±0.003 km-1 is found at 4 km altitude. During the second sounding, clouds prevented us to retrieve profile parts under 3 km altitude but a layer with enhanced extinction (0.025±0.005 km-1) and NO2 (1.95±0.2 × 109 molec cm-3) is clearly detected at 4 km altitude. From CO and ozone in-situ measurements complemented by back-trajectories, we interpret the measurements in the free troposphere as, for the first sounding, a mix between stratospheric and polluted air from Northern Europe and for the second sounding, polluted air from Central Europe containing NO2. Considering the boundary layer measurements of the first flight, modeled source regions indicate closer sources, especially the Kola Peninsula smelters, which can explain the NO2 enhancement not correlated with a CO increase at the same altitude.

  10. Airborne DOAS measurements in Arctic: vertical distributions of aerosol extinction coefficient and NO2 concentration

    NASA Astrophysics Data System (ADS)

    Merlaud, A.; van Roozendael, M.; Theys, N.; Fayt, C.; Hermans, C.; Quennehen, B.; Schwarzenboeck, A.; Ancellet, G.; Pommier, M.; Pelon, J.; Burkhart, J.; Stohl, A.; de Mazière, M.

    2011-09-01

    We report on airborne Differential Optical Absorption Spectroscopy (DOAS) measurements of aerosol extinction and NO2 tropospheric profiles performed off the North coast of Norway in April 2008. The DOAS instrument was installed on the Safire ATR-42 aircraft during the POLARCAT-France spring campaign and recorded scattered light spectra in near-limb geometry using a scanning telescope. We use O4 slant column measurements to derive the aerosol extinction at 360 nm. Regularization is based on the maximum a posteriori solution, for which we compare a linear and a logarithmic approach. The latter inherently constrains the solution to positive values and yields aerosol extinction profiles more consistent with independently measured size distributions. We present results from two soundings performed on 8 April 2008 above 71° N, 22° E and on 9 April 2008 above 70° N, 17.8° E. The first profile shows aerosol extinction and NO2 in the marine boundary layer with respective values of 0.04 ± 0.005 km-1 and 1.9 ± 0.3 × 109 molec cm-3. A second extinction layer of 0.01 ± 0.003 km-1 is found at 4 km altitude where the NO2 concentration is 0.32 ± 0.2 × 109 molec cm-3. During the second sounding, clouds prevent retrieval of profile parts under 3 km altitude but a layer with enhanced extinction (0.025 ± 0.005 km-1) and NO2 (1.95 ± 0.2 × 109 molec cm-3) is clearly detected at 4 km altitude. From CO and ozone in-situ measurements complemented by back-trajectories, we interpret the measurements in the free troposphere as, for the first sounding, a mix between stratospheric and polluted air from Northern Europe and for the second sounding, polluted air from Central Europe containing NO2. Considering the boundary layer measurements of the first flight, modeled source regions indicate closer sources, especially the Kola Peninsula smelters, which can explain the NO2 enhancement not correlated with a CO increase at the same altitude.

  11. Aerosol Backscatter and Extinction Retrieval from Airborne Coherent Doppler Wind Lidar Measurements

    NASA Astrophysics Data System (ADS)

    Chouza, F.; Reitebuch, O.; Groß, S.; Rahm, S.; Freudenthaler, V.; Toledano, C.; Weinzierl, B.

    2016-06-01

    A novel method for coherent Doppler wind lidars (DWLs) calibration is shown in this work. Concurrent measurements of a ground based aerosol lidar operating at 532 nm and an airborne DWL at 2 μm are used in combination with sun photometer measurements for the retrieval of backscatter and extinction profiles. The presented method was successfully applied to the measurements obtained during the Saharan Aerosol Long-range Transport and Aerosol-Cloud-Interaction Experiment (SALTRACE: http://www.pa.op.dlr.de/saltrace), which aimed to characterize the Saharan dust long range transport between Africa and the Caribbean.

  12. Analysis of Antarctic stratospheric aerosol properties using SAGE II extinction measurements

    NASA Technical Reports Server (NTRS)

    Thomason, Larry W.; Poole, Lamont R.

    1992-01-01

    Multispectra aerosol extinction data for the fall and spring of 1987 measured by the SAGE II sensor are employed to determine the physical characteristics of aerosols within the springtime Antarctic polar vortex. Attention is given to the physical processes that give rise to the apparent springtime 'cleansing' of the Antarctic stratosphere. The inferred vertical and radial structure compare favorably with in situ measurements but yield a previously unavailable 2D structure to the distribution of aerosols within the polar vortex. The springtime 'cleansing' of the Antarctic stratosphere is found to be a result of both large-scale subsidence and the preferential removal of large particles by the nucleation and subsequent sedimentation of polar stratospheric clouds.

  13. Development of the code MaexPro for calculation atmospheric aerosol extinction in the marine and coastal surface layer

    NASA Astrophysics Data System (ADS)

    Kaloshin, Gennady A.; Shishkin, Sergey A.; Serov, Sergey A.

    2006-11-01

    In the paper the description of the last version of the code MaexPro (Marine aerosol extinction Profile) for calculation spectral and vertical profiles of aerosol extinction coefficient α( λ), aerosol sizes distribution, area distribution, volumes distribution, modes aerosol extinction spectra using standard meteorological parameters, aerosol microphysical structure, a spectral band and a height of the sensor location place is submitted. The code MaexPro is the computer program under constantly development to estimate of EO systems signal power at a location place in which a fetch is key entrance parameter. Spectral behavior α( λ) can be submitted as graphically, and as tables. Commands overplot for superposition or change of figures; profiles extrapolation; a lens; all kinds of possible copying; the data presentation, convenient for an input in code MODTRAN, and etc. are stipulated. The code MaexPro is a completely mouse-driven PC Windows program with a user-friendly interface. Calculation time of spectral and vertical profiles of α( λ) depends on the necessary wave length resolution, radius of aerosol particles and the location place height, and does not exceed tens seconds for each new meteorological condition. Other calculations characteristics, such as aerosol sizes distribution, area distribution, volumes distribution, modes aerosol extinction spectra, are performed in a few seconds.

  14. Statistical analysis of the spatial-temporal distribution of aerosol extinction retrieved by micro-pulse lidar in Kashgar, China.

    PubMed

    Zhu, Wenyue; Xu, Chidong; Qian, Xianmei; Wei, Heli

    2013-02-11

    The spatial-temporal distribution of dust aerosol is important in climate model and ecological environment. An observation experiment of the aerosol vertical distribution in the low troposphere was made using the micro-pulse lidar system from Sept. 2008 to Aug. 2009 at the oasis city Kashgar, China, which is near the major dust source area of the Taklimakan desert. The monthly averaged temporal variation of aerosol extinction profiles are given in the paper. The profile of aerosol extinction coefficient suggested that the dust aerosol could be vertically transported from the ground level to the higher altitude of above 5 km around the source region, and the temporal distribution showed that the dust aerosol layer of a few hundred meters thick appeared in the seasons of early spring and summer near the ground surface. PMID:23481711

  15. Relationships between Optical Extinction, Backscatter and Aerosol Surface and Volume in the Stratosphere following the Eruption of Mt. Pinatubo

    NASA Technical Reports Server (NTRS)

    Brock, Charles A.; Jonsson, Haflidi H.; Wilson, James C.; Dye, James E.; Baumgardner, Darrel; Borrmann, Stephan; Pitts, Mike C.; Osborn, Mary T.; DeCoursey, Robert J.; Woods, David C.

    1993-01-01

    The eruption of the Mt. Pinatubo volcano in the Philippines in June 1991 has resulted in increases in the surface and mass concentrations of aerosol particles in the lower stratosphere. Airborne measurements made at midlatitudes between 15 and 21 km from August 1991 to March 1992 show that, prior to December 1991, the Pinatubo aerosol cloud varied widely in microphysical properties such as size distribution, number, surface and volume concentrations and was also spatially variable. Aerosol surface area concentration was found to be highly correlated to extinction at visible and near-infrared wavelengths throughout the measurement period. Similarly, backscatter at common lidar wavelengths was a good predictor of aerosol volume concentrations. These results support the use of satellite extinction measurements to estimate aerosol surface and of lidar measurements to estimate aerosol volume or mass if temporal changes in the relationships between the variables are considered.

  16. Cavity Attenuated Phase Shift (CAPS) Method for Airborne Aerosol Light Extinction Measurement: Instrument Validation and First Results from Field Deployment

    NASA Astrophysics Data System (ADS)

    Petzold, A.; Perim de Faria, J.; Berg, M.; Bundke, U.; Freedman, A.

    2015-12-01

    Monitoring the direct impact of aerosol particles on climate requires the continuous measurement of aerosol optical parameters like the aerosol extinction coefficient on a regular basis. Remote sensing and ground-based networks are well in place (e.g., AERONET, ACTRIS), whereas the regular in situ measurement of vertical profiles of atmospheric aerosol optical properties remains still an important challenge in quantifying climate change. The European Research Infrastructure IAGOS (In-service Aircraft for a Global Observing System; www.iagos.org) responds to the increasing requests for long-term, routine in situ observational data by using commercial passenger aircraft as measurement platform. However, scientific instrumentation for the measurement of atmospheric constituents requires major modifications before being deployable aboard in-service passenger aircraft. Recently, a compact and robust family of optical instruments based on the cavity attenuated phase shift (CAPS) technique has become available for measuring aerosol light extinction. While this technique was successfully deployed for ground-based atmospheric measurements under various conditions, its suitability for operation aboard aircraft in the free and upper free troposphere still has to be demonstrated. In this work, the modifications of a CAPS PMex instrument for measuring aerosol light extinction on aircraft, the results from subsequent laboratory tests for evaluating the modified instrument prototype, and first results from a field deployment aboard a research aircraft will be covered. In laboratory studies, the instrument showed excellent agreement (deviation < 5%) with theoretical values calculated from Rayleigh scattering cross-sections, when operated on pressurized air and CO2 at ambient and low pressure (~200 hPa). For monodisperse and polydisperse aerosols, reference aerosol extinction coefficients were calculated from measured size distributions and agreed with the CAPS PMex instrument

  17. Using Airborne High Spectral Resolution Lidar Data to Evaluate Combined Active Plus Passive Retrievals of Aerosol Extinction Profiles

    NASA Technical Reports Server (NTRS)

    Burton, S. P.; Ferrare, R. A.; Hostetler, C. A.; Hair, J. W.; Kittaka, C.; Vaughn, M. A.; Remer, L. A.

    2010-01-01

    We derive aerosol extinction profiles from airborne and space-based lidar backscatter signals by constraining the retrieval with column aerosol optical thickness (AOT), with no need to rely on assumptions about aerosol type or lidar ratio. The backscatter data were acquired by the NASA Langley Research Center airborne High Spectral Resolution Lidar (HSRL) and by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite. The HSRL also simultaneously measures aerosol extinction coefficients independently using the high spectral resolution lidar technique, thereby providing an ideal data set for evaluating the retrieval. We retrieve aerosol extinction profiles from both HSRL and CALIOP attenuated backscatter data constrained with HSRL, Moderate-Resolution Imaging Spectroradiometer (MODIS), and Multiangle Imaging Spectroradiometer column AOT. The resulting profiles are compared with the aerosol extinction measured by HSRL. Retrievals are limited to cases where the column aerosol thickness is greater than 0.2 over land and 0.15 over water. In the case of large AOT, the results using the Aqua MODIS constraint over water are poorer than Aqua MODIS over land or Terra MODIS. The poorer results relate to an apparent bias in Aqua MODIS AOT over water observed in August 2007. This apparent bias is still under investigation. Finally, aerosol extinction coefficients are derived from CALIPSO backscatter data using AOT from Aqua MODIS for 28 profiles over land and 9 over water. They agree with coincident measurements by the airborne HSRL to within +/-0.016/km +/- 20% for at least two-thirds of land points and within +/-0.028/km +/- 20% for at least two-thirds of ocean points.

  18. Analysis of DIAL/HSRL aerosol backscatter and extinction profiles during the SEAC4RS campaign with an aerosol assimilation system

    NASA Astrophysics Data System (ADS)

    Weaver, C. J.; da Silva, A. M., Jr.; Colarco, P. R.; Randles, C. A.

    2015-12-01

    We retrieve aerosol concentrations and optical information from vertical profiles of airborne 532 nm extinction and 532 and 1064 nm backscatter measurements made during the SEAC4RS summer 2013 campaign. The observations are from the High Spectral Resolution Lidar (HSRL) Airborne Differential Absorption Lidar (DIAL) on board the NASA DC-8. Instead of retrieving information about aerosol microphysical properties such as indexes of refraction, we seek information more directly applicable to an aerosol transport model - in our case the Goddard Chemistry Aerosol Radiation and Transport (GOCART) module used in the GEOS-5 Earth modeling system. A joint atmosphere/aerosol mini-reanalysis was performed for the SEAC4RS period using GEOS-5. The meteorological reanalysis followed the MERRA-2 atmospheric reanalysis protocol, and aerosol information from MODIS, MISR, and AERONET provided a constraint on the simulated aerosol optical depth (i.e., total column loading of aerosols). We focus on the simulated concentrations of 10 relevant aerosol species simulated by the GOCART module: dust, sulfate, and organic and black carbon. Our first retrieval algorithm starts with the SEAC4RS mini-reanalysis and adjusts the concentration of each GOCART aerosol species so that differences between the observed and simulated backscatter and extinction measurements are minimized. In this case, too often we are unable to simulate the observations by simple adjustment of the aerosol concentrations. A second retrieval approach adjusts both the aerosol concentrations and the optical parameters (i.e., assigned mass extinction efficiency) associated with each GOCART species. We present results from DC-8 flights over smoke from forest fires over the western US using both retrieval approaches. Finally, we compare our retrieved quantities with in-situ observations of aerosol absorption, scattering, and mass concentrations at flight altitude.

  19. An effective inversion algorithm for retrieving bimodal aerosol particle size distribution from spectral extinction data

    NASA Astrophysics Data System (ADS)

    He, Zhenzong; Qi, Hong; Yao, Yuchen; Ruan, Liming

    2014-12-01

    The Ant Colony Optimization algorithm based on the probability density function (PDF-ACO) is applied to estimate the bimodal aerosol particle size distribution (PSD). The direct problem is solved by the modified Anomalous Diffraction Approximation (ADA, as an approximation for optically large and soft spheres, i.e., χ≫1 and |m-1|≪1) and the Beer-Lambert law. First, a popular bimodal aerosol PSD and three other bimodal PSDs are retrieved in the dependent model by the multi-wavelength extinction technique. All the results reveal that the PDF-ACO algorithm can be used as an effective technique to investigate the bimodal PSD. Then, the Johnson's SB (J-SB) function and the modified beta (M-β) function are employed as the general distribution function to retrieve the bimodal PSDs under the independent model. Finally, the J-SB and M-β functions are applied to recover actual measurement aerosol PSDs over Beijing and Shanghai obtained from the aerosol robotic network (AERONET). The numerical simulation and experimental results demonstrate that these two general functions, especially the J-SB function, can be used as a versatile distribution function to retrieve the bimodal aerosol PSD when no priori information about the PSD is available.

  20. Aerosol extinction properties over coastal West Bengal Gangetic plain under inter-seasonal and sea breeze influenced transport processes

    NASA Astrophysics Data System (ADS)

    Verma, S.; Priyadharshini, B.; Pani, S. K.; Bharath Kumar, D.; Faruqi, A. R.; Bhanja, S. N.; Mandal, M.

    2016-01-01

    We analysed the atmospheric aerosol extinction properties under an influence of inter-seasonal and sea breeze (SB) transport processes over coastal West Bengal (WB) Gangetic plain (WBGP). The predominant frequency of airmass back trajectory path was through the Arabian Sea (AS) during southwest monsoon (SWmon) and that through the Indo-Gangetic plain (IGP) during transition to winter (Twin) season and the Bay of Bengal during transition to summer (Tsumm) season. Aerosol surface concentration (Sconc) and aerosol extinction exhibited heterogeneity in the seasonal variability over coastal WBGP with their highest seasonal mean being during winter and summer seasons respectively. Seasonal mean extinction was respectively 17% and 30% higher during winter and summer seasons than that during SWmon. While angstrom exponent (AE) was less than one during SWmon, Tsumm, and summer seasons, it was near to one during Twin and winter monsoon (Wmon), and was more than one during winter season. Relative contribution (%) of upper (at altitude above 1 km) aerosol layer (UAL) to aerosol extinction during summer was four times of that during winter. Seasonally distinct vertical distribution of aerosol extinction associated with meteorological and SB influenced transport and that due to influence of high rise open burning emissions was inferred. Possible aerosol subtypes extracted during days in Tsumm were inferred to be mostly constituted of dust and polluted dust during daytime, in addition to polluted continental and smoke in UAL during nighttime. In contrast to that at nearby urban location (Kolkata, KOL), intensity of updraft of airmass evaluated during evening/SB activity hour (1730 local time, (LT)) at study site (Kharagpur, KGP) was as high as 3.5 times the intensity during near to noon hour (1130 LT); this intensity was the highest along coast of westBengal-Orissa. Enhanced Sconc and relative contribution of UAL to aerosol extinction (58% compared to 36% only at nearby urban

  1. Simulation of improved daytime capabilities to retrieve aerosol extinction coefficient using Rotational Raman lidars

    NASA Astrophysics Data System (ADS)

    Madonna, Fabio; Amodeo, Aldo

    2015-04-01

    So far, most of the multi-wavelength Raman lidar observations of aerosols are performed at night, because Raman signals are weak compared to daylight background. Different techniques have been developed to improve Raman lidar daytime capabilities in the past years. Indeed, the retrieval of aerosol extinction during daytime is feasible through the detection of backscattered radiation due to the pure Rotational Raman Spectrum (PRRS) of molecular nitrogen or oxygen, much brighter than the vibration-rotation spectrum. The existing techniques for the measure of PRRS are based on small-bandwidth emitter and receiver systems and on a small receiver field of view to suppress the daylight background. They have been successfully tested and implemented in a few systems which are already in operational use within EARLINET (European Aerosol research Lidar NETwork). In this work, several different configurations used as receiver for a lidar system detecting the PRRS in daytime conditions are compared by means of numerical simulations. The configurations are mainly differentiated by the design of the spectral selection unit implemented in the receiver of each lidar system, based on a narrow-bandwidth filters, broad-band filters, grating spectrometers, and hybrid solutions. The research of configurations able to be more easily implemented on a large number of lidar systems within ACTRIS are explored. To show the performances of the investigated lidar configurations, a blind test has been carried out to get the simulated performances in the retrieval of the aerosol extinction profile during night-time and daytime starting from a known scenario. The atmospheric scenario used as the reference profile is represented by one of the night-time measurements with MUSA (MUlti-wavelength system for Aerosol) lidar at CNR-IMAA Atmospheric Observatory - CIAO (15.72E, 40.60N , 760 m a.s.l., Potenza, Italy). Though all the configuration considered in the blind test proved to be solid to

  2. Modeling of growth and evaporation effects on the extinction of 1.0-micron solar radiation traversing stratospheric sulfuric acid aerosols

    NASA Technical Reports Server (NTRS)

    Yue, G. K.; Deepak, A.

    1981-01-01

    The effects of growth and evaporation of stratospheric sulfuric acid aerosols on the extinction of solar radiation traversing such an aerosol medium are reported for the case of 1.0-micron solar radiation. Modeling results show that aerosol extinction is not very sensitive to the change of ambient water vapor concentration, but is sensitive to ambient temperature changes, especially at low ambient temperatures and high ambient water vapor concentration. A clarification is given of the effects of initial aerosol size distribution and composition on the change of aerosol extinction due to growth and evaporation processes. It is shown that experiments designed to observe solar radiation extinction of aerosols may also be applied to the determination of observed changes in aerosol optical properties, environmental parameters, or the physical and optical characteristics of sulfate aerosols.

  3. Relationships between optical extinction, backscatter and aerosol surface and volume in the stratosphere following the eruption of Mt. Pinatubo

    NASA Technical Reports Server (NTRS)

    Brock, Charles A.; Jonsson, Haflidi H.; Wilson, James C.; Dye, James E.; Baumgardner, Darrel; Borrmann, Stephan; Pitts, Mike C.; Osborn, Mary T.; Decoursey, Robert J.; Woods, David C.

    1993-01-01

    The eruption of the Mt. Pinatubo volcano in the Philippines in June 1991 has resulted in increases in the surface and mass concentrations of aerosol particles in the lower stratosphere. Airborne measurements made at midlatitudes between 15 and 21 km from August 1991 to March 1992 show that, prior to December 1991, the Pinatubo aerosol cloud varied widely in microphysical properties such as size distribution, number, surface and volume concentrations and was also spatially variable. Aerosol surface area concentration was found to be highly correlated to extinction at visible and near-infrared wavelenghts throughout the measurement period. Similarly, backscatter at common lidar wavelengths was a good predictor of aerosol volume concentrations. These results support the use of satellite extinction measurements to estimate aerosol volume or mass if temporal changes in the relationships between the variables are considered.

  4. Antarctic springtime measurements of ozone, nitrogen dioxide, and aerosol extinction by SAM II, SAGE, and SAGE II

    NASA Technical Reports Server (NTRS)

    Mccormick, M. P.; Larsen, J. C.

    1986-01-01

    Simultaneous vertical profiles of O3, NO2, and aerosol extinction obtained with the Stratospheric Aerosol Measurement II, Stratospheric Aerosol and Gas Experiment (SAGE), and SAGE II satellite instruments across the southern polar vortex show that significant differences exist at all altitudes. Both gaseous species display lower concentrations within the vortex over measurement altitudes ranging from the tropopause to 60 km and 20 to 40 km for O3 and NO2, respectively. Aerosol extinction above 15-18 km and total aerosol stratospheric column are also lower inside the vortex than outside. Total column amounts of O3 and NO2 are found to be strongly coupled to spatial location within the vortex, with minimum total values located around the vortex center. Vertical profiles selected to emphasize the observed difference across the circumpolar vortex are presented for October 13, 1981, and October 13, 1985, near 70 and 68 deg S latitude, respectively.

  5. Use of rotational Raman measurements in multiwavelength aerosol lidar for evaluation of particle backscattering and extinction

    NASA Astrophysics Data System (ADS)

    Veselovskii, I.; Whiteman, D. N.; Korenskiy, M.; Suvorina, A.; Pérez-Ramírez, D.

    2015-10-01

    Vibrational Raman scattering from nitrogen is commonly used in aerosol lidars for evaluation of particle backscattering (β) and extinction (α) coefficients. However, at mid-visible wavelengths, particularly in the daytime, previous measurements have possessed low signal-to-noise ratio. Also, vibrational scattering is characterized by a significant frequency shift of the Raman component, so for the calculation of α and β information about the extinction Ångström exponent is needed. Simulation results presented in this study demonstrate that ambiguity in the choice of Ångström exponent can be the a significant source of uncertainty in the calculation of backscattering coefficients when optically thick aerosol layers are considered. Both of these issues are addressed by the use of pure-rotational Raman (RR) scattering, which is characterized by a higher cross section compared to nitrogen vibrational scattering, and by a much smaller frequency shift, which essentially removes the sensitivity to changes in the Ångström exponent. We describe a practical implementation of rotational Raman measurements in an existing Mie-Raman lidar to obtain aerosol extinction and backscattering at 532 nm. A 2.3 nm width interference filter was used to select a spectral range characterized by low temperature sensitivity within the anti-Stokes branch of the RR spectrum. Simulations demonstrate that the temperature dependence of the scattering cross section does not exceed 1.5 % in the 230-300 K range, making correction for this dependence quite easy. With this upgrade, the NASA GSFC multiwavelength Raman lidar has demonstrated useful α532 measurements and was used for regular observations. Examples of lidar measurements and inversion of optical data to the particle microphysics are given.

  6. Studying the vertical aerosol extinction coefficient by comparing in situ airborne data and elastic backscatter lidar

    NASA Astrophysics Data System (ADS)

    Rosati, Bernadette; Herrmann, Erik; Bucci, Silvia; Fierli, Federico; Cairo, Francesco; Gysel, Martin; Tillmann, Ralf; Größ, Johannes; Gobbi, Gian Paolo; Di Liberto, Luca; Di Donfrancesco, Guido; Wiedensohler, Alfred; Weingartner, Ernest; Virtanen, Annele; Mentel, Thomas F.; Baltensperger, Urs

    2016-04-01

    Vertical profiles of aerosol particle optical properties were explored in a case study near the San Pietro Capofiume (SPC) ground station during the PEGASOS Po Valley campaign in the summer of 2012. A Zeppelin NT airship was employed to investigate the effect of the dynamics of the planetary boundary layer at altitudes between ˜ 50 and 800 m above ground. Determined properties included the aerosol particle size distribution, the hygroscopic growth factor, the effective index of refraction and the light absorption coefficient. The first three parameters were used to retrieve the light scattering coefficient. Simultaneously, direct measurements of both the scattering and absorption coefficient were carried out at the SPC ground station. Additionally, a single wavelength polarization diversity elastic lidar system provided estimates of aerosol extinction coefficients using the Klett method to accomplish the inversion of the signal, for a vertically resolved comparison between in situ and remote-sensing results. Note, however, that the comparison was for the most part done in the altitude range where the overlap function is incomplete and accordingly uncertainties are larger. First, the airborne results at low altitudes were validated with the ground measurements. Agreement within approximately ±25 and ±20 % was found for the dry scattering and absorption coefficient, respectively. The single scattering albedo, ranged between 0.83 and 0.95, indicating the importance of the absorbing particles in the Po Valley region. A clear layering of the atmosphere was observed during the beginning of the flight (until ˜ 10:00 LT - local time) before the mixing layer (ML) was fully developed. Highest extinction coefficients were found at low altitudes, in the new ML, while values in the residual layer, which could be probed at the beginning of the flight at elevated altitudes, were lower. At the end of the flight (after ˜ 12:00 LT) the ML was fully developed, resulting in

  7. Optical and Physicochemical Properties of Brown Carbon Aerosol: Light Scattering, FTIR Extinction Spectroscopy, and Hygroscopic Growth.

    PubMed

    Tang, Mingjin; Alexander, Jennifer M; Kwon, Deokhyeon; Estillore, Armando D; Laskina, Olga; Young, Mark A; Kleiber, Paul D; Grassian, Vicki H

    2016-06-23

    A great deal of attention has been paid to brown carbon aerosol in the troposphere because it can both scatter and absorb solar radiation, thus affecting the Earth's climate. However, knowledge of the optical and chemical properties of brown carbon aerosol is still limited. In this study, we have investigated different aspects of the optical properties of brown carbon aerosol that have not been previously explored. These properties include extinction spectroscopy in the mid-infrared region and light scattering at two different visible wavelengths, 532 and 402 nm. A proxy for atmospheric brown carbon aerosol was formed from the aqueous reaction of ammonium sulfate with methylglyoxal. The different optical properties were measured as a function of reaction time for a period of up to 19 days. UV/vis absorption experiments of bulk solutions showed that the optical absorption of aqueous brown carbon solution significantly increases as a function of reaction time in the spectral range from 200 to 700 nm. The analysis of the light scattering data, however, showed no significant differences between ammonium sulfate and brown carbon aerosol particles in the measured scattering phase functions, linear polarization profiles, or the derived real parts of the refractive indices at either 532 or 402 nm, even for the longest reaction times with greatest visible extinction. The light scattering experiments are relatively insensitive to the imaginary part of the refractive index, and it was only possible to place an upper limit of k ≤ 0.01 on the imaginary index values. These results suggest that after the reaction with methylglyoxal the single scattering albedo of ammonium sulfate aerosol is significantly reduced but that the light scattering properties including the scattering asymmetry parameter, which is a measure of the relative amount of forward-to-backward scattering, remain essentially unchanged from that of unprocessed ammonium sulfate. The optical extinction properties

  8. How well can we Measure the Vertical Profile of Tropospheric Aerosol Extinction?

    NASA Technical Reports Server (NTRS)

    Schmid, Beat; Ferrare, R.; Flynn, C.; Elleman, R.; Covert, D.; Strawa, A.; Welton, E.; Turner, D.; Jonsson, H.; Redemann, J.

    2005-01-01

    The recent Department of Energy Atmospheric Radiation Measurement (ARM) Aerosol Intensive Operations Period (MOP, May 2003) yielded one of the best measurement sets obtained to-date to assess our ability to measure the vertical profile of ambient aerosol extinction sigma(sub ep)(lambda) in the lower troposphere. During one month, a heavily instrumented aircraft with well characterized aerosol sampling ability carrying well proven and new aerosol instrumentation, devoted most of the 60 available flight hours to flying vertical profiles over the heavily instrumented ARM Southern Great Plains (SGP) Climate Research Facility (CRF). This allowed us to compare vertical extinction profiles obtained from 6 different instuments: airborne Sun photometer (AATS-14), airborne nephelometer/absorption photometer, airborne cavity ring-down system, ground-based Raman lidar and 2 ground-based elastic backscatter lidars. We find the in-situ measured sigma(sub ep)(lambda) to be lower than the AATS-14 derived values. Bias differences are 0.002 - 0.004 K/m equivalent to 12-17% in the visible, or 45% in the near-infrared. On the other hand, we find that with respect to AATS-14, the lidar sigma(sub ep)(lambda) are higher. An unnoticed loss of sensitivity of the Raman lidar had occurred leading up to AIOP and we expect better agreement from the recently restored system looking at the collective results from 6 field campaigns conducted since 1996, airborne in situ measurements of sigma(sub ep)(lambda) tend to be biased slightly low (17% at visible wavelengths) when compared to airborne Sun photometer sigma(sub ep)(lambda). On the other hand, sigma(sub ep)(lambda) values derived from lidars tend to have no or positive biases. From the bias differences we conclude that the typical systematic error associated with measuring the tropospheric vertical profile of the ambient aerosol extinction with current state of-the art instrumentation is 15-20% at visible wavelengths and potentially larger in

  9. Chemical composition of aerosol particles and light extinction apportionment before and during the heating season in Beijing, China

    NASA Astrophysics Data System (ADS)

    Wang, Qingqing; Sun, Yele; Jiang, Qi; Du, Wei; Sun, Chengzhu; Fu, Pingqing; Wang, Zifa

    2015-12-01

    Despite extensive efforts into characterization of the sources and formation mechanisms of severe haze pollution in the megacity of Beijing, the response of aerosol composition and optical properties to coal combustion emissions in the heating season remain poorly understood. Here we conducted a 3 month real-time measurement of submicron aerosol (PM1) composition by an Aerosol Chemical Speciation Monitor and particle light extinction by a Cavity Attenuated Phase Shift extinction monitor in Beijing, China, from 1 October to 31 December 2012. The average (±σ) PM1 concentration was 82.4 (±73.1) µg/m3 during the heating period (HP, 15 November to 31 December), which was nearly 50% higher than that before HP (1 October to 14 November). While nitrate and secondary organic aerosol (SOA) showed relatively small changes, organics, sulfate, and chloride were observed to have significant increases during HP, indicating the dominant impacts of coal combustion sources on these three species. The relative humidity-dependent composition further illustrated an important role of aqueous-phase processing for the sulfate enhancement during HP. We also observed great increases of hydrocarbon-like OA (HOA) and coal combustion OA (CCOA) during HP, which was attributed to higher emissions at lower temperatures and coal combustion emissions, respectively. The relationship between light extinction and chemical composition was investigated using a multiple linear regression model. Our results showed that the largest contributors to particle extinction were ammonium nitrate (32%) and ammonium sulfate (28%) before and during HP, respectively. In addition, the contributions of SOA and primary OA to particle light extinction were quantified. The results showed that the OA extinction was mainly caused by SOA before HP and by SOA and CCOA during HP, yet with small contributions from HOA and cooking aerosol for the entire study period. Our results elucidate substantial changes of aerosol

  10. Infrared extinction spectra of mineral dust aerosol: Single components and complex mixtures

    NASA Astrophysics Data System (ADS)

    Laskina, Olga; Young, Mark A.; Kleiber, Paul D.; Grassian, Vicki H.

    2012-09-01

    Simultaneous Fourier transform infrared (FTIR) extinction spectra and aerosol size distributions have been measured for some components of mineral dust aerosol including feldspars (albite, oligoclase) and diatomaceous earth, as well as more complex authentic dust samples that include Iowa loess and Saharan sand. Spectral simulations for single-component samples, derived from Rayleigh-theory models for characteristic particle shapes, better reproduce the experimental spectra including the peak position and band shape compared to Mie theory. The mineralogy of the authentic dust samples was inferred using analysis of FTIR spectra. This approach allows for analysis of the mineralogy of complex multicomponent dust samples. Extinction spectra for the authentic dust samples were simulated from the derived sample mineralogy using published optical constant data for the individual mineral constituents and assuming an external mixture. Nonspherical particle shape effects were also included in the simulations and were shown to have a significant effect on the results. The results show that the position of the peak and the shape of the band of the IR characteristic features in the 800 to 1400 cm-1 spectral range are not well simulated by Mie theory. The resonance peaks are consistently shifted by more than +40 cm-1 relative to the experimental spectrum in the Mie simulation. Rayleigh model solutions for different particle shapes better predict the peak position and band shape of experimental spectra, even though the Rayleigh condition may not be strictly obeyed in these experiments.

  11. Aerosol optical depth over a remote semi-arid region of South Africa from spectral measurements of the daytime solar extinction and the nighttime stellar extinction

    NASA Astrophysics Data System (ADS)

    Formenti, P.; Winkler, H.; Fourie, P.; Piketh, S.; Makgopa, B.; Helas, G.; Andreae, M. O.

    Spectral daytime aerosol optical depths have been measured at Sutherland, South Africa (32°22'S, 20°48'E), from January 1998 to November 1999. Sutherland is located in the semi-arid Karoo desert, approximately 400-km northeast from Cape Town. The site, remote from major sources of aerosols, hosts the South African Astronomical Observatory (SAAO), where nighttime stellar extinction is being measured. The comparison of daytime and nighttime measurements for the years 1998-1999 makes it possible to validate the astronomical dataset of aerosol optical depth ( τa) dating back to 1991. The 1998 and 1999 annually averaged daytime τa at 500 nm are 0.04±0.04 and 0.06±0.06, respectively. Half-day averages vary between 0.03 and 0.44, with peak values in August-September. This pronounced seasonality is linked to the biomass-burning season in the Southern Hemisphere. Smoke haze layers transported to Sutherland originated primarily on the African landmass at latitudes between 10° and 20°S and passed over Namibia and Angola. On one occasion, aerosols from fires in Brazil transported across the Atlantic Ocean were likely detected. The haze layers reaching Sutherland are therefore at least 2-3 days old. The spectral dependence of the aerosol optical depth for the smoke layers supports the bimodality of the volume size distribution for biomass burning aerosols. The accumulation mode has a volume modal diameter of 0.32 μm, consistent with the hypothesis of aged haze. The stellar measurements (1991-2001) show that, due to the eruption of Mt. Pinatubo, the atmospheric extinction depth at 550 nm in the years 1991-1993 increased by 33% with respect to the average value (0.14±0.03) for the period 1994-2001. Outside the Pinatubo event, extinction is largest in the period 1997-1999.

  12. The MODIS Aerosol Algorithm, Products and Validation

    NASA Technical Reports Server (NTRS)

    Remer, L. A.; Kaufman, Y. J.; Tanre, D.; Mattoo, S.; Chu, D. A.; Martins, J. V.; Li, R.-R.; Ichoku, C.; Levy, R. C.; Kleidman, R. G.

    2003-01-01

    The MODerate resolution Imaging Spectroradiometer (MODIS) aboard both NASA's Terra and Aqua satellites is making near global daily observations of the earth in a wide spectral range. These measurements are used to derive spectral aerosol optical thickness and aerosol size parameters over both land and ocean. The aerosol products available over land include aerosol optical thickness at three visible wavelengths, a measure of the fraction of aerosol optical thickness attributed to the fine mode and several derived parameters including reflected spectral solar flux at top of atmosphere. Over ocean, the aerosol optical thickness is provided in seven wavelengths from 0.47 microns to 2.13 microns. In addition, quantitative aerosol size information includes effective radius of the aerosol and quantitative fraction of optical thickness attributed to the fine mode. Spectral aerosol flux, mass concentration and number of cloud condensation nuclei round out the list of available aerosol products over the ocean. The spectral optical thickness and effective radius of the aerosol over the ocean are validated by comparison with two years of AERONET data gleaned from 133 AERONET stations. 8000 MODIS aerosol retrievals colocated with AERONET measurements confirm that one-standard deviation of MODIS optical thickness retrievals fall within the predicted uncertainty of delta tauapproximately equal to plus or minus 0.03 plus or minus 0.05 tau over ocean and delta tay equal to plus or minus 0.05 plus or minus 0.15 tau over land. 271 MODIS aerosol retrievals co-located with AERONET inversions at island and coastal sites suggest that one-standard deviation of MODIS effective radius retrievals falls within delta r_eff approximately equal to 0.11 microns. The accuracy of the MODIS retrievals suggests that the product can be used to help narrow the uncertainties associated with aerosol radiative forcing of global climate.

  13. A New Stratospheric Aerosol Product from CALIPSO Lidar Measurements

    NASA Astrophysics Data System (ADS)

    Kar, J.; Vaughan, M.; Trepte, C. R.; Winker, D. M.; Vernier, J. P.; Pitts, M. C.; Young, S. A.; Liu, Z.; Lucker, P.; Tackett, J. L.; Omar, A. H.

    2014-12-01

    Stratospheric aerosols are derived from precursor SO2 and OCS gases transported from the lower troposphere. Volcanic injections can also enhance aerosol loadings far above background levels. The latter can exert a significant influence on the Earth's radiation budget for major and even minor eruptions. Careful measurements are needed, therefore, to monitor the distribution and evolution of stratospheric aerosols for climate related studies. The Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) mission has been acquiring profile measurements of clouds and aerosols since 2006, leading to major advances in our understanding of tropospheric aerosol and cloud properties and the processes that control them. The CALIPSO products have also enabled new insights into polar stratospheric clouds and stratospheric aerosols. Vernier et al (2009,JGR,114,D00H10) reported on the construction of a modified CALIPSO lidar product that corrected minor artifacts with the original lidar calibration that affected stratospheric aerosol investigations. A significantly improved CALIPSO Lidar Version 4 Level 1 product has been recently released addressing these calibration issues and has resulted in enhanced signal levels and a highly stable record over the span of the mission. Based on this product, a new 3D gridded stratospheric CALIPSO data product is under development and being targeted for release in 2015. A key emphasis of this new product is to bridge the measurement gap between the SAGE II and SAGE III data record (1984-2005) and the start of measurements from the new SAGE III instrument to be deployed on the International Space Station in 2016. The primary parameters delivered in the CALIPSO stratospheric data products will be attenuated scattering ratio and aerosol extinction profiles, both averaged over one month intervals and binned into an equal angle grid of constant latitude and longitude with a vertical resolution of 900m. We will present the overall

  14. Aerosol extinction in a remote continental region of the Iberian Peninsula during summer

    NASA Astrophysics Data System (ADS)

    Elias, Thierry; Silva, Ana Maria; Belo, Nuno; Pereira, Sergio; Formenti, Paola; Helas, Günter; Wagner, Frank

    2006-07-01

    Summer in Évora (38°34'N, 7°54'W), Portugal, is described in terms of aerosol properties of extinction of the solar radiation. We create a data set composed of (1) cloud-screened half-day averaged values of aerosol optical thickness (AOT) measured at 7 wavelengths by both a CIMEL Sun/sky-photometer and a YES shadowband radiometer and (2) half day averaged values of aerosol scattering coefficient (ASC) measured at the surface level at two wavelengths by a TSI nephelometer. Spectral dependence of both AOT and ASC gives the column and the surface Ångström exponents, αC and αS, respectively. Measurements are acquired in both 2002 and 2003 summers. Back trajectories are computed. A statistical study of the data set provides thresholds in AOT and αC for a classification of the days. The classification is applied with success to the case study of the 2003 summer heat wave episode and is generalized to the whole data set. In 23% of the cases, the turbidity in Évora is very low, with AOT441 < 0.12 and AOT873 < 0.04. The air mass origin is the North Atlantic Ocean at 700 and 970 hPa. In 31% of the cases, the turbidity is high. Increase of AOT is due to forest fire emissions, originating in the Iberian Peninsula, with 0.30 < AOT441 < 1.10 and αC > 1.2, and to desert dust plumes transported from North Africa within 72 to 120 hours at 700 hPa, with 0.10 < AOT873 < 1.10 and 0.1 < αC < 1.0. The vertical profile is highly variable, and several cases of aerosol mixing in the column are identified. The duration of the aerosol episode during the 2003 summer heat wave is 16 days, which is exceptionally long.

  15. Antarctic measurements of ozone, water vapor, and aerosol extinction by Sage 2 in the spring of 1987

    NASA Technical Reports Server (NTRS)

    Larsen, J. C.; Mccormick, M. Patrick

    1988-01-01

    Recent measurements of ozone, water vapor, and aerosol extinction from the spring of 1987 are presented and compared to 1985 and 1986. The observed changes to variations in meteorological conditions in the vortex for these three years are noted. March ozone data at similar latitudes for these three years will be used to investigate coupling between severity of the springtime depletion and early fall values. Researchers also investigate correlations between the measured species of water vapor, ozone, and aerosols throughout the vortex region.

  16. Multi-Sensor Aerosol Products Sampling System

    NASA Technical Reports Server (NTRS)

    Petrenko, M.; Ichoku, C.; Leptoukh, G.

    2011-01-01

    Global and local properties of atmospheric aerosols have been extensively observed and measured using both spaceborne and ground-based instruments, especially during the last decade. Unique properties retrieved by the different instruments contribute to an unprecedented availability of the most complete set of complimentary aerosol measurements ever acquired. However, some of these measurements remain underutilized, largely due to the complexities involved in analyzing them synergistically. To characterize the inconsistencies and bridge the gap that exists between the sensors, we have established a Multi-sensor Aerosol Products Sampling System (MAPSS), which consistently samples and generates the spatial statistics (mean, standard deviation, direction and rate of spatial variation, and spatial correlation coefficient) of aerosol products from multiple spacebome sensors, including MODIS (on Terra and Aqua), MISR, OMI, POLDER, CALIOP, and SeaWiFS. Samples of satellite aerosol products are extracted over Aerosol Robotic Network (AERONET) locations as well as over other locations of interest such as those with available ground-based aerosol observations. In this way, MAPSS enables a direct cross-characterization and data integration between Level-2 aerosol observations from multiple sensors. In addition, the available well-characterized co-located ground-based data provides the basis for the integrated validation of these products. This paper explains the sampling methodology and concepts used in MAPSS, and demonstrates specific examples of using MAPSS for an integrated analysis of multiple aerosol products.

  17. Characterization and source apportionment of aerosol light extinction with a coupled model of CMB-IMPROVE in Hangzhou, Yangtze River Delta of China

    NASA Astrophysics Data System (ADS)

    Wang, Jiao; Zhang, Yu-fen; Feng, Yin-chang; Zheng, Xian-jue; Jiao, Li; Hong, Sheng-mao; Shen, Jian-dong; Zhu, Tan; Ding, Jing; Zhang, Qi

    2016-09-01

    To investigate the characteristics and sources of aerosol light extinction in the Yangtze River Delta of China, a campaign was carried out in Hangzhou from December 2013 to November 2014. Hourly data for air pollutants including PM2.5, SO2, NO2, O3 and CO, and aerosol optical properties including aerosol scattering coefficient and aerosol absorbing coefficient was obtained in the environmental air quality automatic monitoring station. Meteorological parameters were measured synchronously in the automated meteorology monitoring station. Additionally, around seven sets of ambient PM2.5 samples per month were collected and analyzed during the campaign. The annual mean aerosol scattering coefficient, aerosol absorbing coefficient and aerosol single scattering albedo measured in this study was 514 ± 284 Mm- 1, 35 ± 20 Mm- 1 and 94% respectively. The aerosol extinction coefficient reconstructed using the modified IMPROVE (Interagency Monitoring of Protected Visual Environment) formula was compared to the measured extinction coefficient. Better correlations could be found between the measured and reconstructed extinction coefficient when RH was under 90%. A coupled model of CMB (chemical mass balance) and modified IMPROVE was used to apportion the sources of aerosol light extinction in Hangzhou. Vehicle exhaust, secondary nitrate and secondary sulfate were identified as the most significant sources for aerosol light extinction, accounted for 30.2%, 24.1% and 15.8% respectively.

  18. Towards an improved aerosol product from SCIAMACHY limb measurements

    NASA Astrophysics Data System (ADS)

    Rozanov, Alexei; Burrows, John; Hommel, Rene

    2015-04-01

    Stratospheric aerosols are of a great scientific interest because of their crucial role in the Earth's radiative budget as well as their contribution to chemical processes resulting in ozone depletion. While the permanent aerosol background in the stratosphere is determined by the tropical injection of SO2, COS and sulphate particles from the troposphere, major perturbations of the stratospheric aerosol layer result form an uplift of SO2 after strong volcanic eruptions. Satellite measurements in the visible spectral range represent one of the most important sources of information about the vertical distribution of the stratospheric aerosol on the global scale. This study employs measurements of the scattered solar light performed in the limb viewing geometry from the space borne spectrometer SCIAMACHY, which operated onboard the ENVISAT satellite from August 2002 to April 2012. A progress in the development of SCIAMACHY aerosol data product within the ROSA/ROMIC project including the improvements in the extinction coefficient data base and steps towards the retrieval of particle size distribution parameters is reported.

  19. The CU Airborne MAX-DOAS instrument: vertical profiling of aerosol extinction and trace gases

    NASA Astrophysics Data System (ADS)

    Baidar, S.; Oetjen, H.; Coburn, S.; Dix, B.; Ortega, I.; Sinreich, R.; Volkamer, R.

    2013-03-01

    The University of Colorado Airborne Multi-Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS) instrument uses solar stray light to detect and quantify multiple trace gases, including nitrogen dioxide (NO2), glyoxal (CHOCHO), formaldehyde (HCHO), water vapor (H2O), nitrous acid (HONO), iodine monoxide (IO), bromine monoxide (BrO), and oxygen dimers (O4) at multiple wavelengths (absorption bands at 360, 477, 577, 632 nm) simultaneously in the open atmosphere. The instrument is unique as it (1) features a motion compensation system that decouples the telescope field of view from aircraft movements in real time (<0.35° accuracy), and (2) includes measurements of solar stray light photons from nadir, zenith, and multiple elevation angles forward and below the plane by the same spectrometer/detector system. Sets of solar stray light spectra collected from nadir to zenith scans provide some vertical profile information within 2 km above and below the aircraft altitude, and the vertical column density (VCD) below the aircraft is measured in nadir view. Maximum information about vertical profiles is derived simultaneously for trace gas concentrations and aerosol extinction coefficients over similar spatial scales and with a vertical resolution of typically 250 m during aircraft ascent/descent. The instrument is described, and data from flights over California during the CalNex (California Research at the Nexus of Air Quality and Climate Change) and CARES (Carbonaceous Aerosols and Radiative Effects Study) air quality field campaigns is presented. Horizontal distributions of NO2 VCD (below the aircraft) maps are sampled with typically 1 km resolution, and show good agreement with two ground-based MAX-DOAS instruments (slope = 0.95 ± 0.09, R2 = 0.86). As a case study vertical profiles of NO2, CHOCHO, HCHO, and H2O concentrations and aerosol extinction coefficients, ɛ, at 477 nm calculated from O4 measurements from a low approach at Brackett airfield inside the

  20. Extinction-to-Backscatter Ratios of Lofted Aerosol Layers Observed During the First Three Months of CALIPSO Measurements

    NASA Technical Reports Server (NTRS)

    Omar, Ali H.; Vaughan, Mark A.; Liu, Zhaoyan; Hu, Yongxiang; Reagan, John A.; Winker, David M.

    2007-01-01

    Case studies from the first three months of the Cloud and Aerosol Lidar and Infrared Pathfinder Spaceborne Observations (CALIPSO) measurements of lofted aerosol layers are analyzed using transmittance [Young, 1995] and two-wavelength algorithms [Vaughan et al., 2004] to determine the aerosol extinction-to-backscatter ratios at 532 and 1064 nm. The transmittance method requires clear air below the layer so that the transmittance through the layer can be determined. Suitable scenes are selected from the browse images and clear air below features is identified by low 532 nm backscatter signal and confirmed by low depolarization and color ratios. The transmittance and two-wavelength techniques are applied to a number of lofted layers and the extinction-to-backscatter ratios are compared with values obtained from the CALIPSO aerosol models [Omar et al., 2004]. The results obtained from these studies are used to adjust the aerosol models and develop observations based extinction-to-backscatter ratio look-up tables and phase functions. Values obtained by these techniques are compared to Sa determinations using other independent methods with a goal of developing probability distribution functions of aerosol type-specific extinction to backscatter ratios. In particular, the results are compared to values determined directly by the High Spectral Resolution Lidar (HSRL) during the CALIPSO CloudSat Validation Experiments (CCVEX) and Sa determined by the application of the two-wavelength lidar Constrained Ratio Aerosol Model-fit (CRAM) retrieval approach [Cattrall et al., 2005; Reagan et al., 2004] to the HSRL data. The results are also compared to values derived using the empirical relationship between the multiple-scattering fraction and the linear depolarization ratio by using Monte Carlo simulations of water clouds [Hu et al., 2006].

  1. In situ vertical profiles of aerosol extinction, mass, and composition over the southeast United States during SENEX and SEAC4RS: observations of a modest aerosol enhancement aloft

    NASA Astrophysics Data System (ADS)

    Wagner, N. L.; Brock, C. A.; Angevine, W. M.; Beyersdorf, A.; Campuzano-Jost, P.; Day, D. A.; de Gouw, J. A.; Diskin, G. S.; Gordon, T. D.; Graus, M. G.; Huey, G.; Jimenez, J. L.; Lack, D. A.; Liao, J.; Liu, X.; Markovic, M. Z.; Middlebrook, A. M.; Mikoviny, T.; Peischl, J.; Perring, A. E.; Richardson, M. S.; Ryerson, T. B.; Schwarz, J. P.; Warneke, C.; Welti, A.; Wisthaler, A.; Ziemba, L. D.; Murphy, D. M.

    2015-02-01

    Vertical profiles of submicron aerosol over the southeastern United States (SEUS) during the summertime from in situ aircraft-based measurements were used to construct aggregate profiles of chemical, microphysical, and optical properties. Shallow cumulus convection was observed during many profiles. These conditions enhance vertical transport of trace gases and aerosol and create a cloudy transition layer on top of the sub-cloud mixed layer. The trace gas and aerosol concentrations in the transition layer were modeled as a mixture with contributions from the mixed layer below and the free troposphere above. The amount of vertical mixing, or entrainment of air from the free troposphere, was quantified using the observed mixing ratio of carbon monoxide (CO). Although the median aerosol mass, extinction, and volume decreased with altitude in the transition layer, they were ~10% larger than expected from vertical mixing alone. This enhancement was likely due to secondary aerosol formation in the transition layer. Although the transition layer enhancements of the particulate sulfate and organic aerosol (OA) were both similar in magnitude, only the enhancement of sulfate was statistically significant. The column integrated extinction, or aerosol optical depth (AOD), was calculated for each individual profile, and the transition layer enhancement of extinction typically contributed less than 10% to the total AOD. Our measurements and analysis were motivated by two recent studies that have hypothesized an enhanced layer of secondary organic aerosol (SOA) aloft to explain the summertime enhancement of AOD (2-3 times greater than winter) over the southeastern United States. In contrast to this hypothesis, the modest enhancement we observed in the transition layer was not dominated by OA and was not a large fraction of the summertime AOD.

  2. On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

    NASA Astrophysics Data System (ADS)

    Kovilakam, Mahesh; Deshler, Terry

    2015-08-01

    In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997-2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPC measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15-30% (30-50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. This disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the ± 40% precision of the OPC moment calculations.

  3. On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

    DOE PAGESBeta

    Kovilakam, Mahesh; Deshler, Terry

    2015-08-26

    In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997 2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with themore » OPC measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15 30% (30 50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. This disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the 40% precision of the OPC moment calculations.« less

  4. On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

    SciTech Connect

    Kovilakam, Mahesh; Deshler, Terry

    2015-08-26

    In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997 2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPC measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15 30% (30 50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. This disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the 40% precision of the OPC moment calculations.

  5. Modeling study on seasonal variation in aerosol extinction properties over China.

    PubMed

    Gao, Yi; Zhang, Meigen

    2014-01-01

    To investigate the seasonal variation of aerosol optical depth (AOD), extinction coefficient (EXT), single scattering albedo (SSA) and the decomposed impacts from sulfate (SO4(2-)) and black carbon (BC) over China, numerical experiments are conducted from November 2007 to December 2008 by using WRF-Chem. Comparison of model results with measurements shows that model can reproduce the spatial distribution and seasonal variation of AOD and SSA. Over south China, AOD is largest in spring (0.6-1.2) and lowest in summer (0.2-0.6). Over north, northeast and east China, AOD is highest in summer while lowest in winter. The high value of EXT under 850 hPa which is the reflection of low visibility ranges from 0.4-0.8 km(-1) and the high value area shifts to north during winter, spring and summer, then back to south in autumn. SSA is 0.92-0.94 in winter and 0.94-0.96 for the other three seasons because of highest BC concentration in winter over south China. Over east China, SSA is highest (0.92-0.96) in summer, and 0.88-0.92 during winter, spring and autumn as the concentration of scattering aerosol is highest while BC concentration is lowest in summer over this region. Over north China, SSA is highest (0.9-0.94) in summer and lowest (0.82-0.86) in winter due to the significant variation of aerosol concentration. The SO4(2-) induced EXT increases about 5%-55% and the impacts of BC on EXT is much smaller (2%-10%). The SO4(2-)-induced increase in SSA is 0.01-0.08 and the BC-induced SSA decreases 0.02-0.18. PMID:24649695

  6. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE PAGESBeta

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2016-01-18

    In this study, aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD andmore » extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to –0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are

  7. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    NASA Astrophysics Data System (ADS)

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2016-01-01

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ˜ 2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day-1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently

  8. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    SciTech Connect

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-06-19

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond

  9. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE PAGESBeta

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2016-01-18

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below  ∼  2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over Southmore » Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to −0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and

  10. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE PAGESBeta

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-06-19

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore » and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond

  11. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    SciTech Connect

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2016-01-01

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to

  12. Assessment of 10-Year Global Record of Aerosol Products from the OMI Near-UV Algorithm

    NASA Astrophysics Data System (ADS)

    Ahn, C.; Torres, O.; Jethva, H. T.

    2014-12-01

    Global observations of aerosol properties from space are critical for understanding climate change and air quality applications. The Ozone Monitoring Instrument (OMI) onboard the EOS-Aura satellite provides information on aerosol optical properties by making use of the large sensitivity to aerosol absorption and dark surface albedo in the UV spectral region. These unique features enable us to retrieve both aerosol extinction optical depth (AOD) and single scattering albedo (SSA) successfully from radiance measurements at 354 and 388 nm by the OMI near UV aerosol algorithm (OMAERUV). Recent improvements to algorithms in conjunction with the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and Atmospheric Infrared Sounder (AIRS) carbon monoxide data also reduce uncertainties due to aerosol layer heights and types significantly in retrieved products. We present validation results of OMI AOD against space and time collocated Aerosol Robotic Network (AERONET) measured AOD values over multiple stations representing major aerosol episodes and regimes. We also compare the OMI SSA against the inversion made by AERONET as well as an independent network of ground-based radiometer called SKYNET in Japan, China, South-East Asia, India, and Europe. The outcome of the evaluation analysis indicates that in spite of the "row anomaly" problem, affecting the sensor since mid-2007, the long-term aerosol record shows remarkable sensor stability. The OMAERUV 10-year global aerosol record is publicly available at the NASA data service center web site (http://disc.sci.gsfc.nasa.gov/Aura/data-holdings/OMI/omaeruv_v003.shtml).

  13. A study on the aerosol extinction-to-backscatter ratio with combination of micro-pulse LIDAR and MODIS over Hong Kong

    NASA Astrophysics Data System (ADS)

    He, Q. S.; Li, C. C.; Mao, J. T.; Lau, A. K. H.; Li, P. R.

    2006-08-01

    The aerosol extinction-to-backscatter ratio is an important parameter for inverting LIDAR signals in the LIDAR equation. It is a complicated function of the aerosol microphysical characteristics. In this paper, a method to retrieve the column-averaged aerosol extinction-to-backscatter ratio by constraining the aerosol optical depths (AOD) from a Micro-pulse LIDAR (MPL) by the AOD measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS) is presented. Both measurements were taken on cloud free days between 1 May 2003 and 30 June 2004 over Hong Kong, a coastal city in south China. Simultaneous measurements of aerosol scattering coefficients with a forward scattering visibility sensor are compared with the LIDAR retrieval of aerosol extinction coefficients. The data are then analyzed to determine seasonal trends of the aetrosol extinction-to-backscatter ratio. In addition, the relationships between the extinction-to-backscatter ratio and wind conditions as well as other aerosol microphysical parameters are presented. The mean aerosol extinction-to-backscatter ratio for the whole period was found to be 29.1±5.8 sr, with a minimum of 18 sr in July 2003 and a maximum of 44 sr in March 2004. The ratio is lower in summer because of the dominance of oceanic aerosols in association with the prevailing southwesterly monsoon. In contrast, relatively larger ratios are noted in spring and winter because of the increased impact of local and regional industrial pollutants associated with the northerly monsoon. The extended LIDAR measurements over Hong Kong provide not only a more accurate retrieval of aerosol extinction coefficient profiles, but also significant substantial information for air pollution and climate studies in the region.

  14. Inversion of solar extinction data from the Apollo-Soyuz Test Project Stratospheric Aerosol Measurement (ASTP/SAM) experiment

    NASA Technical Reports Server (NTRS)

    Pepin, T. J.

    1977-01-01

    The inversion methods are reported that have been used to determine the vertical profile of the extinction coefficient due to the stratospheric aerosols from data measured during the ASTP/SAM solar occultation experiment. Inversion methods include the onion skin peel technique and methods of solving the Fredholm equation for the problem subject to smoothing constraints. The latter of these approaches involves a double inversion scheme. Comparisons are made between the inverted results from the SAM experiment and near simultaneous measurements made by lidar and balloon born dustsonde. The results are used to demonstrate the assumptions required to perform the inversions for aerosols.

  15. Evaluating Nighttime CALIOP 0.532 micron Aerosol Optical Depth and Extinction Coefficient Retrievals

    NASA Technical Reports Server (NTRS)

    Campbell, J. R.; Tackett, J. L.; Reid, J. S.; Zhang, J.; Curtis, C. A.; Hyer, E. J.; Sessions, W. R.; Westphal, D. L.; Prospero, J. M.; Welton, E. J.; Omar, A. H.; Vaughan, M. A.; Winker, D. M.

    2012-01-01

    NASA Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) Version 3.01 5-km nighttime 0.532 micron aerosol optical depth (AOD) datasets from 2007 are screened, averaged and evaluated at 1 deg X 1 deg resolution versus corresponding/co-incident 0.550 micron AOD derived using the US Navy Aerosol Analysis and Prediction System (NAAPS), featuring two-dimensional variational assimilation of quality-assured NASA Moderate Resolution Imaging Spectroradiometer (MODIS) and Multi-angle Imaging Spectroradiometer (MISR) AOD. In the absence of sunlight, since passive radiometric AOD retrievals rely overwhelmingly on scattered radiances, the model represents one of the few practical global estimates available from which to attempt such a validation. Daytime comparisons, though, provide useful context. Regional-mean CALIOP vertical profiles of night/day 0.532 micron extinction coefficient are compared with 0.523/0.532 micron ground-based lidar measurements to investigate representativeness and diurnal variability. In this analysis, mean nighttime CALIOP AOD are mostly lower than daytime (0.121 vs. 0.126 for all aggregated data points, and 0.099 vs. 0.102 when averaged globally per normalised 1 deg. X 1 deg. bin), though the relationship is reversed over land and coastal regions when the data are averaged per normalised bin (0.134/0.108 vs. 0140/0.112, respectively). Offsets assessed within single bins alone approach +/- 20 %. CALIOP AOD, both day and night, are higher than NAAPS over land (0.137 vs. 0.124) and equal over water (0.082 vs. 0.083) when averaged globally per normalised bin. However, for all data points inclusive, NAAPS exceeds CALIOP over land, coast and ocean, both day and night. Again, differences assessed within single bins approach 50% in extreme cases. Correlation between CALIOP and NAAPS AOD is comparable during both day and night. Higher correlation is found nearest the equator, both as a function of sample size and relative signal magnitudes inherent at

  16. In situ vertical profiles of aerosol extinction, mass, and composition over the southeast United States during SENEX and SEAC4RS: observations of a modest aerosol enhancement aloft

    NASA Astrophysics Data System (ADS)

    Wagner, N. L.; Brock, C. A.; Angevine, W. M.; Beyersdorf, A.; Campuzano-Jost, P.; Day, D.; de Gouw, J. A.; Diskin, G. S.; Gordon, T. D.; Graus, M. G.; Holloway, J. S.; Huey, G.; Jimenez, J. L.; Lack, D. A.; Liao, J.; Liu, X.; Markovic, M. Z.; Middlebrook, A. M.; Mikoviny, T.; Peischl, J.; Perring, A. E.; Richardson, M. S.; Ryerson, T. B.; Schwarz, J. P.; Warneke, C.; Welti, A.; Wisthaler, A.; Ziemba, L. D.; Murphy, D. M.

    2015-06-01

    Vertical profiles of submicron aerosol from in situ aircraft-based measurements were used to construct aggregate profiles of chemical, microphysical, and optical properties. These vertical profiles were collected over the southeastern United States (SEUS) during the summer of 2013 as part of two separate field studies: the Southeast Nexus (SENEX) study and the Study of Emissions and Atmospheric Composition, Clouds, and Climate Coupling by Regional Surveys (SEAC4RS). Shallow cumulus convection was observed during many profiles. These conditions enhance vertical transport of trace gases and aerosol and create a cloudy transition layer on top of the sub-cloud mixed layer. The trace gas and aerosol concentrations in the transition layer were modeled as a mixture with contributions from the mixed layer below and the free troposphere above. The amount of vertical mixing, or entrainment of air from the free troposphere, was quantified using the observed mixing ratio of carbon monoxide (CO). Although the median aerosol mass, extinction, and volume decreased with altitude in the transition layer, they were ~10 % larger than expected from vertical mixing alone. This enhancement was likely due to secondary aerosol formation in the transition layer. Although the transition layer enhancements of the particulate sulfate and organic aerosol (OA) were both similar in magnitude, only the enhancement of sulfate was statistically significant. The column integrated extinction, or aerosol optical depth (AOD), was calculated for each individual profile, and the transition layer enhancement of extinction typically contributed less than 10 % to the total AOD. Our measurements and analysis were motivated by two recent studies that have hypothesized an enhanced layer of secondary aerosol aloft to explain the summertime enhancement of AOD (2-3 times greater than winter) over the southeastern United States. The first study attributes the layer aloft to secondary organic aerosol (SOA) while

  17. Critical evaluation of cloud contamination in MISR aerosol product using collocated MODIS aerosol and cloud products

    NASA Astrophysics Data System (ADS)

    Shi, Y.; Zhang, J.; Reid, J. S.; Liu, B.; Deshmukh, R.

    2012-12-01

    Unique in its ability of observing the atmospheric state in nine angles nearly simultaneously, the Multi-angle Imaging Spectroradiometer (MISR) instrument has been successfully used for various applications including remote sensing of aerosol properties. However, MISR has limited spectral channels compared with other multi-spectral sensors such as the Moderate Resolution Imaging Spectroradiometer (MODIS), which poses a challenge to cloud screening for applications using MISR. This is particularly important for aerosol property retrievals as cloud contamination and cloud artifacts are one of the larger error sources in satellite aerosol products. Using collocated MODIS and MISR data sets, the potential effects of cloud contamination on the MISR aerosol product are studied. Over global oceans, for non-glint regions, the cloud mask from the level 2 MODIS aerosol products (MOD04) is used. Over ocean glint regions as well as land, the level 2 MODIS cloud mask products (MOD35) are used. The relations between cloud coverage and the bias of MISR AOD are examined using collocated the MODIS cloud information and MISR AOD data. In particular, the suspicious high AOD loading band reported by the MISR aerosol product over high latitude southern oceans is investigated. Finally, a level 3 MISR aerosol product with a new cloud screening method is developed and the potential usage of such a product in satellite aerosol data assimilation is explored.

  18. Introducing... The MODIS Collection 6 Aerosol Products

    NASA Astrophysics Data System (ADS)

    Levy, R. C.; Remer, L. A.; Mattoo, S.; Kleidman, R. G.

    2010-12-01

    As evidenced by more than 1000 publications to date, the MODIS aerosol products are indispensable to research as well as operational applications. The products are used independently, but also in conjunction with other remote sensing instruments and serve as the basis for intercomparisons with models of all scales. In collaboration with our data users, we have made a number of changes to the algorithm and product list, and expect to begin processing “Collection 6” (C006) beginning in early 2011. In addition to more robust means of dealing with degraded or missing reflectance observations, and new protocol for Quality Assurance (QA) characterization and reporting structure, C006 offers new scientific products. C006 will explicitly identify clouds within the aerosol scene, determine distance to nearest cloud for each non-cloudy pixel and provide statistics to help quantify cloud/aerosol interactions. In addition to the traditional retrieval at 10 km resolution focused on climate applications, C006 will provide a 3 km product aimed at characterizing regional and local air quality. The range of valid solar zenith is increased from 72° to 84°, thus increasing retrieval coverage in mid and high latitudes over both land and ocean. Over land, C006 will provide a merged “Dark-target” and “Deep-blue” aerosol product. As for the retrieval over traditional dark targets (land and ocean), the C006 product will benefit from better physical constraints. The lookup tables (central wavelengths, Rayleigh optical depth) are more consistent in C006, and the over-ocean retrieval now includes dependence on wind speed. The dark-land retrieval is improved with adjusted aerosol map boundaries. Finally, the entire C006 archive will be produced utilizing collective knowledge of the MODIS instrument behavior over time. Impacts from calibration drifts and instrument response will be minimized such that C006 will be ever closer to characterizing a global aerosol climate data record.

  19. Four-year long-path monitoring of ambient aerosol extinction at a central European urban site: dependence on relative humidity

    NASA Astrophysics Data System (ADS)

    Skupin, A.; Ansmann, A.; Engelmann, R.; Seifert, P.; Müller, T.

    2016-02-01

    The ambient aerosol particle extinction coefficient is measured with the Spectral Aerosol Extinction Monitoring System (SÆMS) along a 2.84 km horizontal path at 30-50 m height above ground in the urban environment of Leipzig (51.3° N, 12.4° E), Germany, since 2009. The dependence of the particle extinction coefficient (wavelength range from 300 to 1000 nm) on relative humidity up to almost 100 % was investigated. The main results are presented. For the wavelength of 550 nm, the mean extinction enhancement factor was found to be 1.75 ± 0.4 for an increase of relative humidity from 40 to 80 %. The respective 4-year mean extinction enhancement factor is 2.8 ± 0.6 for a relative-humidity increase from 40 to 95 %. A parameterization of the dependency of the urban particle extinction coefficient on relative humidity is presented. A mean hygroscopic exponent of 0.46 for the 2009-2012 period was determined. Based on a backward trajectory cluster analysis, the dependence of several aerosol optical properties for eight air flow regimes was investigated. Large differences were not found, indicating that local pollution sources widely control the aerosol conditions over the urban site. The comparison of the SÆMS extinction coefficient statistics with respective statistics from ambient AERONET sun photometer observations yields good agreement. Also, time series of the particle extinction coefficient computed from in situ-measured dry particle size distributions and humidity-corrected SÆMS extinction values (for 40 % relative humidity) were found in good overall consistency, which verifies the applicability of the developed humidity parameterization scheme. The analysis of the spectral dependence of particle extinction (Ångström exponent) revealed an increase of the 390-881 nm Ångström exponent from, on average, 0.3 (at 30 % relative humidity) to 1.3 (at 95 % relative humidity) for the 4-year period.

  20. In situ measurement of the infrared absorption and extinction of chemical and biologically derived aerosols using flow-through photoacoustics.

    PubMed

    Gurton, Kristan P; Dahmani, Rachid; Ligon, David; Bronk, Burt V

    2005-07-01

    In an effort to establish a more reliable set of optical cross sections for a variety of chemical and biological aerosol simulants, we have developed a flow-through photoacoustic system that is capable of measuring absolute, mass-normalized extinction and absorption cross sections. By employing a flow-through design we avoid issues associated with closed aerosol photoacoustic systems and improve sensitivity. Although the results shown here were obtained for the tunable CO2 laser waveband region, i.e., 9.20-10.80 microm, application to other wavelengths is easily achievable. The aerosols considered are categorized as biological, chemical, and inorganic in origin, i.e., Bacillus atrophaeus endospores, dimethicone silicone oil (SF-96 grade 50), and kaolin clay powder (alumina and silicate), respectively. Results compare well with spectral extinction measured previously by Fourier-transform infrared spectroscopy. Comparisons with Mie theory calculations based on previously published complex indices of refraction and measured size distributions are also presented. PMID:16004057

  1. Three-dimensional dust aerosol distribution and extinction climatology over northern Africa simulated with the ALADIN numerical prediction model from 2006 to 2010

    NASA Astrophysics Data System (ADS)

    Mokhtari, M.; Tulet, P.; Fischer, C.; Bouteloup, Y.; Bouyssel, F.; Brachemi, O.

    2015-08-01

    The seasonal cycle and optical properties of mineral dust aerosols in northern Africa were simulated for the period from 2006 to 2010 using the numerical atmospheric model ALADIN (Aire Limitée Adaptation dynamique Développement InterNational) coupled to the surface scheme SURFEX (SURFace EXternalisée). The particularity of the simulations is that the major physical processes responsible for dust emission and transport, as well as radiative effects, are taken into account on short timescales and at mesoscale resolution. The aim of these simulations is to quantify the dust emission and deposition, locate the major areas of dust emission and establish a climatology of aerosol optical properties in northern Africa. The mean monthly aerosol optical thickness (AOT) simulated by ALADIN is compared with the AOTs derived from the standard Dark Target (DT) and Deep Blue (DB) algorithms of the Aqua-MODIS (MODerate resolution Imaging Spectroradiometer) products over northern Africa and with a set of sun photometer measurements located at Banizoumbou, Cinzana, Soroa, Mbour and Cape Verde. The vertical distribution of dust aerosol represented by extinction profiles is also analysed using CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) observations. The annual dust emission simulated by ALADIN over northern Africa is 878 Tg year-1. The Bodélé Depression appears to be the main area of dust emission in northern Africa, with an average estimate of about 21.6 Tg year-1. The simulated AOTs are in good agreement with satellite and sun photometer observations. The positions of the maxima of the modelled AOTs over northern Africa match the observed positions, and the ALADIN simulations satisfactorily reproduce the various dust events over the 2006-2010 period. The AOT climatology proposed in this paper provides a solid database of optical properties and consolidates the existing climatology over this region derived from satellites, the AERONET network and regional climate

  2. Production of satellite-derived aerosol climate data records: current status of the ESA Aerosol_cci project

    NASA Astrophysics Data System (ADS)

    de Leeuw, Gerrit; Holzer-Popp, Thomas; Pinnock, Simon

    2015-04-01

    and the Aerosol_cci team Within the ESA Climate Change Initiative (CCI) project Aerosol_cci (Phase 1: 2010 -2014; Phase 2: 2014-2017) intensive work has been conducted to improve algorithms for the retrieval of aerosol information from European sensors ATSR (3 algorithms), PARASOL, MERIS (3 algorithms), synergetic AATSR/SCIAMACHY, OMI and GOMOS. Whereas OMI and GOMOS were used to derive absorbing aerosol index and stratospheric extinction profiles, respectively, Aerosol Optical Depth (AOD) and Ångström coefficient were retrieved from the other sensors. The cooperation between the project partners, including both the retrieval teams and independent validation teams, has resulted in a strong improvement of most algorithms. In particular the AATSR retrieved AOD is qualitatively similar to that from MODIS, usually taken as the standard, MISR and SeaWiFS. This conclusion has been reached form several different ways of validation of the L2 and L3 products, using AERONET sun photometer data as the common ground-truth for the application of both 'traditional' statistical techniques and a 'scoring' technique using spatial and temporal correlations. Quantitatively, the limited AATSR swath width of 500km results in a smaller amount of data. Nevertheless, the assimilation of AATSR-retrieved AOD, together with MODIS data, contributes to improving the in the ECMWF climate model results. In addition to the multi-spectral AOD, and thus the Ångström Exponent, also a per-pixel uncertainty is provided and validated. By the end of Aerosol_cci Phase 1 the ATSR algorithms have been applied to both ATSR-2 and AATSR resulting in an AOD time series of 17 years. In phase 2 this work is continued with a focus on the further improvement of the ATSR algorithms as well as those for the other instruments and algorithms, mentioned above, which in phase 1 were considered less mature. The first efforts are on the further characterization of the uncertainties and on better understanding of the

  3. Wavelength-resolved optical extinction measurements of aerosols using broad-band cavity-enhanced absorption spectroscopy over the spectral range of 445-480 nm.

    PubMed

    Zhao, Weixiong; Dong, Meili; Chen, Weidong; Gu, Xuejun; Hu, Changjin; Gao, Xiaoming; Huang, Wei; Zhang, Weijun

    2013-02-19

    Despite the significant progress in the measurements of aerosol extinction and absorption using spectroscopy approaches such as cavity ring-down spectroscopy (CRDS) and photoacoustic spectroscopy (PAS), the widely used single-wavelength instruments may suffer from the interferences of gases absorption present in the real environment. A second instrument for simultaneous measurement of absorbing gases is required to characterize the effect of light extinction resulted from gases absorption. We present in this paper the development of a blue light-emitting diode (LED)-based incoherent broad-band cavity-enhanced spectroscopy (IBBCEAS) approach for broad-band measurements of wavelength-resolved aerosol extinction over the spectral range of 445-480 nm. This method also allows for simultaneous measurement of trace gases absorption present in the air sample using the same instrument. On the basis of the measured wavelength-dependent aerosol extinction cross section, the real part of the refractive index (RI) can be directly retrieved in a case where the RI does not vary strongly with the wavelength over the relevant spectral region. Laboratory-generated monodispersed aerosols, polystyrene latex spheres (PSL) and ammonium sulfate (AS), were employed for validation of the RI determination by IBBCEAS measurements. On the basis of a Mie scattering model, the real parts of the aerosol RI were retrieved from the measured wavelength-resolved extinction cross sections for both aerosol samples, which are in good agreement with the reported values. The developed IBBCEAS instrument was deployed for simultaneous measurements of aerosol extinction coefficient and NO(2) concentration in ambient air in a suburban site during two representative days. PMID:23320530

  4. A broadband cavity-enhanced spectrometer for measuring the extinction of aerosols at blue and near-UV wavelengths

    NASA Astrophysics Data System (ADS)

    Venables, Dean; Fullam, Donovan; Hoa Le, Phuoc; Chen, Jun; Böge, Olaf; Herrmann, Hartmut

    2016-04-01

    We describe a new broadband cavity-enhanced absorption spectrometer for sensitive extinction measurements of aerosols. The instrument is distinguished by its broad and continuous spectral coverage from the near-UV to blue wavelengths (ca. 320 to 450 nm). The short wavelength region has been little explored compared to visible wavelengths, but is important because (1) brown carbon (BrC) absorbs strongly in this wavelength region, and (2) absorption of near-UV radiation in the atmosphere alters the photolysis rate of the key atmospheric species O3, NO2, and HONO, with implications for air quality and atmospheric oxidation capacity. The instrument performance and the effect of a switchable in-line filter are characterised. Early results using the instrument in the TROPOS atmospheric simulation chamber are presented. These experiments include studies of secondary organic aerosol formation (SOA), and biomass burning experiments of rice and wheat straw, followed by experiments simulating particle aging under daytime and nighttime conditions.

  5. How Well do State-of-the-Art Techniques Measuring the Vertical Profile of Tropospheric Aerosol Extinction Compare?

    NASA Technical Reports Server (NTRS)

    Schmid, B.; Ferrare, R.; Flynn, C.; Elleman, R.; Covert, D.; Strawa, A.; Welton, E.; Turner, D.; Jonsson, H.; Redemann, J.; Eilers, J.; Ricci, K.; Hallar, A. G.; Clayton, M.; Michalsky, J.; Smirnov, A.; Holben, B.; Barnard, J.

    2006-01-01

    The recent Department of Energy Atmospheric Radiation Measurement (ARM) Aerosol Intensive Operations Period (AIOP, May 2003) yielded one of the best measurement sets obtained to date to assess our ability to measure the vertical profile of ambient aerosol extinction sigma(ep)(lambda) in the lower troposphere. During one month, a heavily instrumented aircraft with well-characterized aerosol sampling ability carrying well-proven and new aerosol instrumentation devoted most of the 60 available flight hours to flying vertical profiles over the heavily instrumented ARM Southern Great Plains (SGP) Climate Research Facility (CRF). This allowed us to compare vertical extinction profiles obtained from six different instruments: airborne Sun photometer (AATS-14), airborne nephelometer/absorption photometer, airborne cavity ring-down system, groundbased Raman lidar, and two ground-based elastic backscatter lidars. We find the in situ measured sigma(ep)(lambda) to be lower than the AATS-14 derived values. Bias differences are 0.002-0.004 Km!1 equivalent to 13-17% in the visible, or 45% in the near-infrared. On the other hand, we find that with respect to AATS-14, the lidar sigma(ep)(lambda) are higher: Bias differences are 0.004 Km(-1) (13%) and 0.007 Km(-1) (24%) for the two elastic backscatter lidars (MPLNET and MPLARM, lambda = 523 nm) and 0.029 Km(-1) (54%) for the Raman lidar (lambda = 355 nm). An unnoticed loss of sensitivity of the Raman lidar had occurred leading up to AIOP, and we expect better agreement from the recently restored system. Looking at the collective results from six field campaigns conducted since 1996, airborne in situ measurements of sigma(ep)(lambda) tend to be biased slightly low (17% at visible wavelengths) when compared to airborne Sun photometer sigma(ep)(lambda). On the other hand, sigma(ep)(lambda) values derived from lidars tend to have no or positive biases. From the bias differences we conclude that the typical systematic error associated

  6. A study on aerosol extinction-to-backscatter ratio with combination of micro-pulse lidar and MODIS over Hong Kong

    NASA Astrophysics Data System (ADS)

    He, Q. S.; Li, C. C.; Mao, J. T.; Lau, A. K. H.

    2006-04-01

    The aerosol extinction-to-backscatter ratio is an important parameter for inverting LIDAR signals in the LIDAR equation. It is also a complicated function of aerosol microphysical characteristics depending on geographical and meteorological conditions. In this paper, a method to retrieve the column-averaged aerosol extinction-to-backscatter ratio by constraining the aerosol optical depths (AOD) recorded by the Moderate Resolution Imaging Spectroradiometer (MODIS) to the ones measured by a Micro-pulse LIDAR (MPL) is presented. Both measurements were taken between 1 May 2003 and 30 June 2004 over Hong Kong, a coastal city in south China. Simultaneous scattering coefficients measured by a forward scattering visibility sensor are compared with the LIDAR retrieval. The data are then analyzed in terms of monthly and seasonal trends. In addition, the relationships between the extinction-to-backscatter ratio and wind conditions as well as other aerosol microphysical parameters are also presented. The mean aerosol extinction-to-backscatter ratio for the whole period is found to be 28.9±6.1 sr, with the minimum of 12 sr in August 2003 and the maximum of 44 sr in March 2004. The ratio is lower in the summer because of the dominance of oceanic aerosols in association with the prevailing southwesterly monsoon. In contrast, relatively larger ratios are noted in spring and winter because of the increased impact of local and regional industrial pollutants associated with the northerly monsoon. The extended LIDAR measurements over Hong Kong provide not only a more accurate retrieval of aerosol extinction coefficient profiles, but also significant information for air pollution and climate studies in the region.

  7. Silicon production in an aerosol reactor

    NASA Technical Reports Server (NTRS)

    Wu, J. J.; Flagan, R. C.

    1986-01-01

    An aerosol reactor system was developed in which large particles of silicon can be grown by silane pyrolysis. To grow particles to sizes larger than one micron, vapor deposition must be used to grow a relatively small number of seed particles. Suppression of nucleation is achieved by limiting the rate of gas phase chemical reactions such that the condensible products of the gas phase chemical reactions diffuse to the surface of the seed particles as rapidly as they are produced. This prevents high degrees of supersaturation and runaway nucleation during the growth process. Particles on the order of 10 microns were grown repeatedly with the present aersol reactor. The nucleation controlled aerosol reactor is, therefore, a suitable system for the production of powders that can readily be separated from the gas by aerodynamic means.

  8. Phase function, backscatter, extinction, and absorption for standard radiation atmosphere and El Chichon aerosol models at visible and near-infrared wavelengths

    NASA Technical Reports Server (NTRS)

    Whitlock, C. H.; Suttles, J. T.; Lecroy, S. R.

    1985-01-01

    Tabular values of phase function, Legendre polynominal coefficients, 180 deg backscatter, and extinction cross section are given for eight wavelengths in the atmospheric windows between 0.4 and 2.2 microns. Also included are single scattering albedo, asymmetry factor, and refractive indices. These values are based on Mie theory calculations for the standard rediation atmospheres (continental, maritime, urban, unperturbed stratospheric, volcanic, upper atmospheric, soot, oceanic, dust, and water-soluble) assest measured volcanic aerosols at several time intervals following the El Chichon eruption. Comparisons of extinction to 180 deg backscatter for different aerosol models are presented and related to lidar data.

  9. Analysis of Venus Express optical extinction due to aerosols in the upper haze of Venus

    NASA Astrophysics Data System (ADS)

    Parkinson, Christopher; Bougher, Stephen; Mahieux, Arnaud; Tellmann, Silvia; Pätzold, Martin; Vandaele, Ann C.; Wilquet, Valérie; Schulte, Rick; Yung, Yuk; Gao, Peter; Bardeen, Charles

    Observations by the SPICAV/SOIR instruments aboard Venus Express (VEx) have revealed that the Upper Haze of Venus is populated by two particle modes, as reported by Wilquet et al. (J. Geophys. Res., 114, E00B42, 2009; Icarus 217, 2012). Gao et al. (In press, Icarus, 2013) posit that the large mode is made up of cloud particles that have diffused upwards from the cloud deck below, while the smaller mode is generated by the in situ nucleation of meteoric dust. They tested this hypothesis by using version 3.0 of the Community Aerosol and Radiation Model for Atmospheres, first developed by Turco et al. (J. Atmos. Sci., 36, 699-717, 1979) and upgraded to version 3.0 by Bardeen et al. (The CARMA 3.0 microphysics package in CESM, Whole Atmosphere Working Group Meeting, 2011). Using the meteoric dust production profile of Kalashnikova et al. (Geophys. Res. Lett., 27, 3293-3296, 2000), the sulfur/sulfate condensation nuclei production profile of Imamura and Hashimoto (J. Atmos. Sci., 58, 3597-3612, 2001), and sulfuric acid vapor production profile of Zhang et al. (Icarus, 217, 714-739, 2012), they numerically simulate a column of the Venus atmosphere from 40 to 100 km above the surface. Their aerosol number density results agree well with Pioneer Venus Orbiter (PVO) data from Knollenberg and Hunten (J. Geophys. Res., 85, 8039-8058, 1980), while their gas distribution results match that of Kolodner and Steffes below 55 km (Icarus, 132, 151-169, 1998). The resulting size distribution of cloud particles shows two distinct modes, qualitatively matching the observations of PVO. They also observe a third mode in their results with a size of a few microns at 48 km altitude, which appears to support the existence of the controversial third mode in the PVO data. This mode disappears if coagulation is not included in the simulation. The Upper Haze size distribution shows two lognormal-like distributions overlapping each other, possibly indicating the presence of the two distinct

  10. EXTINCTION STUDIES OF PROPANE/AIR COUNTERFLOW DIFFUSION FLAMES: THE EFFECTIVENESS OF AEROSOLS

    EPA Science Inventory

    The fire suppression effectiveness of solid aerosols as suitable halon replacements has examined. Experiments were performed in a counterflow diffusion burner, consisting of two 1 cm i.d. tubes separated by 1 cm. Aerosols were delivered to propane/air flames in the air flow. Both...

  11. Design Of A Novel Open-Path Aerosol Extinction Cavity Ringdown Spectrometer And Initial Data From Deployment At NOAA's Atmospheric Observatory

    NASA Astrophysics Data System (ADS)

    Gordon, T. D.; Wagner, N. L.; Richardson, M.; Law, D. C.; Wolfe, D. E.; Brock, C. A.; Erdesz, F.; Murphy, D. M.

    2014-12-01

    The ability to frame effective climate change policy depends strongly on reducing the uncertainty in aerosol radiative forcing, which is currently nearly as great as best estimates of its magnitude. Achieving this goal will require significant progress in measuring aerosol properties, including aerosol optical depth, single scattering albedo and the effect of relative humidity on these properties for both fine and coarse particles. However both ground- and space-based instruments fail or are highly biased in the presence of clouds, severely limiting quantitative estimates of the radiative effects of aerosols where they are advected over low-level clouds. Moreover, many in situ aerosol measurements exclude the coarse fraction, which can be very important in and downwind of desert regions. By measuring the decay rate of a pulsed laser in an optically resonant cavity, cavity ringdown spectrometers (CRDSs) have been employed successfully in measuring aerosol extinction for particles in relative humidities below 90%. At very high humidities (as found in and near clouds), however, existing CRDSs perform poorly, diverging significantly from theoretical extinction values as humidities approach 100%. The new open-path aerosol extinction CRDS described in this poster measures extinction as aerosol is drawn through the sample cavity directly without inlets or tubing for channeling the flow, which cause particle losses, condensation at high RH and other artifacts. This poster presents the key elements of the new open-path CRDS design as well as comparisons with an earlier generation closed-path CRDS and preliminary data obtained during a field study at the 300 meter tower at NOAA's Boulder Atmospheric Observatory (BAO) in Colorado.

  12. Comparison of one-parameter and two-parameter models of aerosol extinction for experimental data of the arid zone of Kazakhstan

    NASA Astrophysics Data System (ADS)

    Shchelkanov, N. N.

    2015-11-01

    Comparison of four aerosol models is carried out: two one-parameter models for a ground layer of the arid zone of Kazakhstan, two-parameter model for horizontal paths and two-parameter model for horizontal and slant paths. It is shown that the models obtained using the new methods for construction of linear regression and separation of the components allow physically correct retrieval of not only the values of the aerosol extinction coefficients, but also their root mean square deviations.

  13. Combined Laboratory and Modeling Study of the IR Extinction and Visible Light Scattering Properties of Mineral Dust Aerosol

    NASA Astrophysics Data System (ADS)

    Alexander, J. M.; Laskina, O.; Meland, B. S.; Parker, A.; Grassian, V. H.; Young, M. A.; Kleiber, P.

    2011-12-01

    Mineral dust aerosol plays a significant role in the Earth's climate system through the scattering and absorption of both incoming solar radiation in the UV-Visible range and outgoing IR terrestrial radiation. Atmospheric dust particles also serve as sites for cloud nucleation indirectly affecting albedo, and as reactive surfaces for heterogeneous chemistry. Correctly modeling the direct and indirect effects of dust requires accurate information about dust loading, dust composition, size, and shape (CSS) distributions, and aerosol optical (scattering and absorption) properties. The optical properties, however, are strongly dependent on both particle shape and composition, and mineral dust aerosol samples are often complex, inhomogeneous mixtures of particles that may be highly irregular in shape. In this work IR extinction and visible light scattering and polarization profiles are measured for a series of authentic and model dust mixtures including samples of Iowa loess, Arizona road dust, and diatomaceous earth. Laboratory measurements also include particle CSS distributions determined through real-time particle sizing, and various ex situ characterization methods. The experimental data are compared with T-Matrix model simulations based on the measured particle size distributions. Different methods used to infer particle shape and composition distributions are explored and evaluated.

  14. Application of the CALIOP Layer Product to Evaluate the Vertical Distribution of Aerosols Estimated by Global Models: AeroCom Phase I Results

    SciTech Connect

    Koffi, Brigitte; Schultz, Michael; Breon, Francois-Marie; Griesfeller, Jan; Winker, D.; Balkanski, Y.; Bauer, Susanne E.; Berntsen, T.; Chin, Mian; Collins, William D.; Dentener, Frank; Diehl, Thomas; Easter, Richard C.; Ghan, Steven J.; Ginoux, P.; Gong, S.; Horowitz, L.; Iversen, T.; Kirkevag, A.; Koch, Dorothy; Krol, Maarten; Myhre, G.; Stier, P.; Takemura, T.

    2012-05-19

    The CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) layer product is used for a multimodel evaluation of the vertical distribution of aerosols. Annual and seasonal aerosol extinction profiles are analyzed over 13 sub-continental regions representative of industrial, dust, and biomass burning pollution, from CALIOP 2007-2009 observations and from AeroCom (Aerosol Comparisons between Observations and Models) 2000 simulations. An extinction mean height diagnostic (Z{sub a}) is defined to quantitatively assess the models performance. It is calculated over the 0-6 km and 0-10 km altitude ranges by weighting the altitude of each 100 m altitude layer by its aerosol extinction coefficient. The mean extinction profiles derived from CALIOP layer products provide consistent regional and seasonal specificities and a low inter-annual variability. While the outputs from most models are significantly correlated with the observed Z{sub a} climatologies, some do better than others, and 2 of the 12 models perform particularly well in all seasons. Over industrial and maritime regions, most models show higher Z{sub a} than observed by CALIOP, whereas over the African and Chinese dust source regions, Z{sub a} is underestimated during Northern Hemisphere Spring and Summer. The positive model bias in Z{sub a} is mainly due to an overestimate of the extinction above 6 km. Potential CALIOP and model limitations, and methodological factors that might contribute to the differences are discussed.

  15. Application of the CALIOP Layer Product to Evaluate the Vertical Distribution of Aerosols Estimated by Global Models: AeroCom Phase I Results

    NASA Technical Reports Server (NTRS)

    Koffi, Brigitte; Schulz, Michael; Breon, Francois-Marie; Griesfeller, Jan; Winker, David; Balkanski, Yves; Bauer, Susanne; Berntsen, Terje; Chin, Mian; Collins, William D.; Dentener, Frank; Diehl, Thomas; Easter, Richard; Ghan, Steven; Gimoux, Paul; Gong, Sunling; Horowitz, Larry W.; Iversen, Trond; Kirkevag, Alf; Koch, Dorothy; Krol, Maarten; Myhre, Gunnar; Stier, Philip; Takemura, Toshihiko

    2012-01-01

    The CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) layer product is used for a multimodel evaluation of the vertical distribution of aerosols. Annual and seasonal aerosol extinction profiles are analyzed over 13 sub-continental regions representative of industrial, dust, and biomass burning pollution, from CALIOP 2007-2009 observations and from AeroCom (Aerosol Comparisons between Observations and Models) 2000 simulations. An extinction mean height diagnostic (Z-alpha) is defined to quantitatively assess the models' performance. It is calculated over the 0-6 km and 0-10 km altitude ranges by weighting the altitude of each 100 m altitude layer by its aerosol extinction coefficient. The mean extinction profiles derived from CALIOP layer products provide consistent regional and seasonal specificities and a low inter-annual variability. While the outputs from most models are significantly correlated with the observed Z-alpha climatologies, some do better than others, and 2 of the 12 models perform particularly well in all seasons. Over industrial and maritime regions, most models show higher Z-alpha than observed by CALIOP, whereas over the African and Chinese dust source regions, Z-alpha is underestimated during Northern Hemisphere Spring and Summer. The positive model bias in Z-alpha is mainly due to an overestimate of the extinction above 6 km. Potential CALIOP and model limitations, and methodological factors that might contribute to the differences are discussed.

  16. Production flux of sea spray aerosol

    SciTech Connect

    de Leeuw, G.; Lewis, E.; Andreas, E. L.; Anguelova, M. D.; Fairall, C. W.; O’Dowd, C.; Schulz, M.; Schwartz, S. E.

    2011-05-07

    Knowledge of the size- and composition-dependent production flux of primary sea spray aerosol (SSA) particles and its dependence on environmental variables is required for modeling cloud microphysical properties and aerosol radiative influences, interpreting measurements of particulate matter in coastal areas and its relation to air quality, and evaluating rates of uptake and reactions of gases in sea spray drops. This review examines recent research pertinent to SSA production flux, which deals mainly with production of particles with r{sub 80} (equilibrium radius at 80% relative humidity) less than 1 {micro}m and as small as 0.01 {micro}m. Production of sea spray particles and its dependence on controlling factors has been investigated in laboratory studies that have examined the dependences on water temperature, salinity, and the presence of organics and in field measurements with micrometeorological techniques that use newly developed fast optical particle sizers. Extensive measurements show that water-insoluble organic matter contributes substantially to the composition of SSA particles with r{sub 80} < 0.25 {micro}m and, in locations with high biological activity, can be the dominant constituent. Order-of-magnitude variation remains in estimates of the size-dependent production flux per white area, the quantity central to formulations of the production flux based on the whitecap method. This variation indicates that the production flux may depend on quantities such as the volume flux of air bubbles to the surface that are not accounted for in current models. Variation in estimates of the whitecap fraction as a function of wind speed contributes additional, comparable uncertainty to production flux estimates.

  17. Imaginary refractive-index effects on desert-aerosol extinction versus backscatter relationships at 351 nm: numerical computations and comparison with Raman lidar measurements.

    PubMed

    Perrone, Maria Rita; Barnaba, Francesca; De Tomasi, Ferdinando; Gobbi, Gian Paolo; Tafuro, Anna Maria

    2004-10-10

    A numerical model is used to investigate the dependence at 351 nm of desert-aerosol extinction and backscatter coefficients on particle imaginary refractive index (mi). Three ranges (-0.005 < or = mi < or = -0.001, -0.01 < or = mi < or = -0.001, and -0.02 < or = mi < or = -0.001) are considered, showing that backscatter coefficients are reduced as /mi/ increases, whereas extinction coefficients are weakly dependent on mi. Numerical results are compared with extinction and backscatter coefficients retrieved by elastic Raman lidar measurements performed during Saharan dust storms over the Mediterranean Sea. The comparison indicates that a range of -0.01 to -0.001 can be representative of Saharan dust aerosols and that the nonsphericity of mineral particles must be considered. PMID:15508611

  18. Validation of aerosol extinction and water vapor profiles from routine Atmospheric Radiation Measurement Climate Research Facility measurements

    SciTech Connect

    Schmid, Beat; Flynn, Connor J.; Newsom, Rob K.; Turner, David D.; Ferrare, Richard; Clayton, Marian F.; Ogren, John A.; Russell, P. B.; Gore, W.; Dominguez, Roseanne

    2009-11-26

    The accuracy with which vertical profiles of aerosol extinction σep(λ) can be retrieved from ARM Climate Research Facility (ACRF) routine measurements was assessed using data from two airborne field campaigns, the ARM Aerosol Intensive Operation Period (AIOP, May 2003), and the Aerosol Lidar Validation Experiment (ALIVE, September 2005). This assessment pertains to the aerosol at its ambient concentration and thermodynamic state (i.e. σep(λ) either free of or corrected for sampling artifacts) and includes the following ACRF routine methods: Raman Lidar, Micro Pulse Lidar (MPL) and in-situ aerosol profiles (IAP) with a small aircraft. Profiles of aerosol optical depth τp(λ), from which the profiles of σep(λ)are derived through vertical differentiation, were measured by the NASA Ames Airborne Tracking 14-channel Sunphotometer (AATS-14); these data were used as truth in this evaluation. The ACRF IAP σep(550 nm) were lower by 16% (during AIOP) and higher by 10% (during ALIVE) when compared to AATS-14. The ACRF MPL σep(523 nm) were higher by 24% (AIOP) and 19%-21% (ALIVE) compared to AATS-14 but the correlation improved significantly during ALIVE. In the AIOP a second MPL operated by NASA showed a smaller positive bias (13%) with respect to AATS-14. The ACRF Raman Lidar σep(355 nm) were higher by 54% (AIOP) and higher by 6% (ALIVE) compared to AATS-14. The large bias in AIOP stemmed from a gradual loss of the sensitivity of the Raman Lidar starting about the end of 2001 going unnoticed until after AIOP. A major refurbishment and upgrade of the instrument and improvements to a data-processing algorithm led to the significant improvement and very small bias in ALIVE. Finally we find that during ALIVE the Raman Lidar water vapor densities ρw are higher by 8% when compared to AATS-14, whereas comparisons between AATS-14 and in-situ measured ρw aboard two different aircraft showed small negative biases (0 to

  19. Implementation of Rotational Raman Channel in Multiwavelength Aerosol Lidar to Improve Measurements of Particle Extinction and Backscattering at 532 NM

    NASA Astrophysics Data System (ADS)

    Veselovskii, Igor; Whiteman, David N.; Korenskiy, Michael; Suvorina, A.; Perez-Ramirez, Daniel

    2016-06-01

    We describe a practical implementation of rotational Raman (RR) measurements in an existing Mie-Raman lidar to obtain measurements of aerosol extinction and backscattering at 532 nm. A 2.3 nm width interference filter was used to select a spectral range characterized by low temperature sensitivity within the anti-Stokes branch of the RR spectrum. Simulations demonstrate that the temperature dependence of the scattering cross section does not exceed 1.0% in the 230-300K range making accurate correction for this dependence quite easy. With this upgrade, the NASA/GSFC multiwavelength Raman lidar has demonstrated useful α532 measurements and was used for regular observations. Examples of lidar measurements and inversion of optical data to the particle microphysics will be given in presentation.

  20. Altitude Differentiated Aerosol Extinction Over Tenerife (North Atlantic Coast) During ACE-2 by Means of Ground and Airborne Photometry and Lidar Measurements

    NASA Technical Reports Server (NTRS)

    Formenti, P.; Elias, T.; Welton, J.; Diaz, J. P.; Exposito, F.; Schmid, B.; Powell, D.; Holben, B. N.; Smirnov, A.; Andreae, M. O.; Devaux, C.; Voss, K.; Lelieveld, J.; Livingston, J. M.; Russell, P. B.; Durkee, P. A.

    2000-01-01

    Retrievals of spectral aerosol optical depths (tau(sub a)) by means of sun photometers have been undertaken in Tenerife (28 deg 16' N, 16 deg 36' W) during ACE-2 (June-July 1997). Five ground-based sites were located at four different altitudes in the marine boundary layer and in the free troposphere, from 0 to 3570 m asl. The goal of the investigation was to provide estimates of the vertical aerosol extinction over the island, both under clean and turbid conditions. Inversion of spectral tau(sub a) allowed to retrieve size distributions, from which the single scattering albedo omega(sub 0) and the asymmetry factor g could be estimated as a function of altitude. These parameters were combined to calculate aerosol forcing in the column. Emphasis is put on episodes of increased turbidity, which were observed at different locations simultaneously, and attributed to outbreaks of mineral dust from North Africa. Differentiation of tau(sub a) as a function of altitude provided the vertical profile of the extinction coefficient sigma(sub e). For dust outbreaks, aerosol extinction is concentrated in two distinct layers above and below the strong subsidence inversion around 1200 m asl. Vertical profiles of tau(sub a) and sigma(sub e) are shown for July 8. In some occasions, vertical profiles are compared to LIDAR observations, performed both at sea level and in the low free troposphere, and to airborne measurements of aerosol optical depths.

  1. Optical extinction due to aerosols in the upper haze of Venus: Four years of SOIR/VEX observations from 2006 to 2010

    NASA Astrophysics Data System (ADS)

    Wilquet, Valérie; Drummond, Rachel; Mahieux, Arnaud; Robert, Séverine; Vandaele, Ann Carine; Bertaux, Jean-Loup

    2012-02-01

    The variability of the aerosol loading in the mesosphere of Venus is investigated from a large data set obtained with SOIR, a channel of the SPICAV instrument suite onboard Venus Express. Vertical profiles of the extinction due to light absorption by aerosols are retrieved from a spectral window around 3.0 μm recorded in many solar occultations (˜200) from September 2006 to September 2010. For this period, the continuum of light absorption is analyzed in terms of spatial and temporal variations of the upper haze of Venus. It is shown that there is a high short-term (a few Earth days) and a long-term (˜80 Earth days) variability of the extinction profiles within the data set. Latitudinal dependency of the aerosol loading is presented for the entire period considered and for shorter periods of time as well.

  2. AMS Measurements in National Parks of Aerosol Mass, Size and Composition, Comparison with Filter Samples and Correlation with Particle Hygroscopicity and Optical Extinction Properties

    NASA Astrophysics Data System (ADS)

    Alexander, M.; Taylor, N. F.; Collins, D. R.; Kumar, N.; Allen, J.; Newburn, M.; Lowenthal, D. H.; Zielinska, B.

    2011-12-01

    We report a comparison of results from aerosol studies at Great Smoky Mountain National Park (2006), Mt. Rainier National Park (2009) and Acadia National Park (2011), all class I visibility areas associated with IMPROVE (Interagency Monitoring of Protected Visual Environments) sites. This collaborative study was sponsored by the Electric Power Research Institute (EPRI) and was done with the cooperation of the National Park Service and the EPA. The atmospheric aerosol composition in these sites is influenced by a number of anthropogenic as well as biogenic sources, providing a rich environment for fundamental aerosol studies. The primary purpose of these studies was to add state-of-the-art aerosol instrumentation to the standard light extinction and aerosol measurements at the site, used to determine parameters for the IMPROVE light extinction reconstruction equation, adopted by the EPA to estimate light extinction from atmospheric aerosol concentrations and Rayleigh scattering. The combination of these diverse measurements also provides significant insight into fundamental aerosol properties such as aging and radiative forcing. New instrumentation included a quadrupole aerosol mass spectrometer (Aerodyne Q-AMS-Smoky Mountain Study), a high resolution aerosol time-of-flight mass spectrometer (Aerodyne HR-ToF-AMS - Mt. Rainier and Acadia studies) for real time measurements that directly address the relationship between sulfate, nitrate, and OC size and concentration, which is related to cloud and dry gas-to-particle conversion as air masses age during transport, the relationship between WSOC hygroscopic growth and oxygenated organic (OOA) composition, the OCM/OC ratio, and the chemical composition that determines the ambient hygroscopic state. The OCM/OC ratio and organic water uptake was addressed with high-volume and medium volume PM2.5 aerosol samples. Aerosols were collected daily on Teflon coated glass fiber filters (TGFF) in four high-volume PM2.5 samplers

  3. The optical, physical and chemical properties of the products of glyoxal uptake on ammonium sulfate seed aerosols

    NASA Astrophysics Data System (ADS)

    Trainic, M.; Riziq, A. A.; Lavi, A.; Flores, J. M.; Rudich, Y.

    2011-07-01

    The heterogeneous reaction between gas phase glyoxal and ammonium sulfate (AS) aerosols, a proxy for inorganic atmospheric aerosol, was studied in terms of the dependence of the optical, physical and chemical properties of the product aerosols on initial particle size and ambient RH. The reactions were studied under different relative humidity (RH) conditions, varying from dry conditions (~20 % RH) and up to 90 % RH, covering conditions prevalent in many atmospheric environments. At λ = 355 nm, the reacted aerosols demonstrate a substantial growth in optical extinction cross section, as well as in mobility diameter under a broad range of RH values (35-90 %). The ratio of the product aerosol to seed aerosol geometric cross section reached up to ~3.5, and the optical extinction cross-section up to ~250. The reactions show a trend of increasing physical and optical growth with decreasing seed aerosol size, from 100nm to 300 nm, as well as with decreasing RH values from 90 % to ~40 %. Optically inactive aerosols, at the limit of the Mie range (100 nm diameter) become optically active as they grow due to the reaction. AMS analyses of the reaction of 300 nm AS at RH values of 50 %, 75 % and 90 % show that the main products of the reaction are glyoxal oligomers, formed by acetal formation in the presence of AS. In addition, imidazole formation, which is a minor channel, is observed for all reactions, yielding a product which absorbs at λ = 290 nm, with possible implications on the radiative properties of the product aerosols. The ratio of absorbing substances (C-N compounds, including imidazoles) increases with increasing RH value. A core/shell model used for the investigation of the optical properties of the reaction products of AS 300nm with gas phase glyoxal, shows that the refractive index (RI) of the reaction products are in the range between 1.57-1.71 for the real part and between 0-0.02 for the imaginary part of the RI at 355 nm. The observed increase in the

  4. Hygroscopic properties and extinction of aerosol particles at ambient relative humidity in South-Eastern China

    NASA Astrophysics Data System (ADS)

    Eichler, H.; Cheng, Y. F.; Birmili, W.; Nowak, A.; Wiedensohler, A.; Brüggemann, E.; Gnauk, T.; Herrmann, H.; Althausen, D.; Ansmann, A.; Engelmann, R.; Tesche, M.; Wendisch, M.; Zhang, Y. H.; Hu, M.; Liu, S.; Zeng, L. M.

    During the "Program of Regional Integrated Experiments of Air Quality over Pearl River Delta 2004 (PRIDE-PRD2004)" hygroscopic properties of particles in the diameter range 22 nm to 10μm were determined. For that purpose, a Humidifying Differential Mobility Particle Sizer (H-DMPS) and a Micro-Orifice Uniform Deposition Impactor (MOUDI) were operated. The derived size-dependent particle hygroscopic growth factors were interpolated to ambient relative humidity (RH) and used to calculate the particle number size distributions (PNSDs) at ambient conditions. A comparison between the modeled particle extinction coefficients (σ) and those observed with a Raman lidar was made. It is shown that the particle extinction coefficient ( σext) at ambient RH can be properly estimated with Mie-model calculations based on the in situ physico-chemical measurements of dry and humidified PNSD and chemical composition.

  5. Aerosol extinction and absorption in Evora, Portugal, during the European 2003 summer heat wave

    NASA Astrophysics Data System (ADS)

    Elias, Thierry G.; Silva, Ana M.; Figueira, Maria J.; Belo, Nuno; Pereira, Sergio; Formenti, Paola; Helas, Gunter

    2004-11-01

    Aerosol optical properties are retrieved from measurements acquired during the 2003 summer at the new AERONET station of Evora, Portugal, with a sun/sky photometer, a fluxmeter and a nephelometer. Aerosol optical thickness (aot) derived at several wavelengths shows that an exceptionally long turbid event occurred in July-August. Desert dust particles transported from North Africa increased aot at 873 nm (aot873) to the value of 0.27 with an Ångstrom exponent αC=0.5. Emissions from forest fires in The Iberic peninsula affected Evora since the end of the dust episode, with aot441 reaching 0.81 and aC=1.8. The aerosol scattering coefficient measured at surface level shows that desert dust does not reach the surface level at Evora while the forest fire emissions were uniformly distributed over the atmospheric column. Sky-radiance and flux measurements agree in retrieval of the aerosol single scattering albedo (assa) at several wavelengths. A large absorption rate is found with a high spectral dependence for desert dust particles (assa441=0.86 and ass873=0.93) and with a flat spectral dependence during the forest fires emission episode (assa441=0.88 and assa873=0.87). All measurements as well as back-trajectory calculations indicate mixture of particles during the desert dust.

  6. The MODIS Aerosol Algorithm, Products, Validation and Applications

    NASA Technical Reports Server (NTRS)

    Remer, L. A.; Kaufman, Y. J.; Tanre, D.

    2003-01-01

    The MODerate resolution Imaging Spectroradiometer (MODIS) currently aboard both the Terra and Aqua satellites produces a suite of products designed to characterize global aerosol distribution, optical thickness and particle size. Never before has a space-borne instrument been able to provide such detailed information, complementing field and modeling efforts to produce a comprehensive picture of aerosol characteristics. The three years of Terra-MODIS data have been validated by comparing with co-located AERONET observations of aerosol optical thickness and derivations of aerosol size parameters. Some 8000 comparison points located at 133 AERONET sites around the globe show that the MODIS aerosol optical thickness retrievals are accurate to within the pre-launch expectations. MODIS-derived size parameters are also compared with AERONET retrievals and found to agree well for fine-mode dominated aerosol regimes. Aerosol regimes dominated by dust aerosol are less accurate, attributed to what is thought to be nonsphericity. Errors due to nonsphericity will be reduced by introducing a new set of empirical phase functions, derived without any assumptions of particle shape. The major innovation that MODIS bring to the field of remote sensing of aerosol is the measure of particle size and the separation of finemode and coarsemode dominated aerosol regimes. Particle size can separate finemode man-made aerosols created during combustion, from larger natural aerosols originating from salt spray or wind erosion. This separation allows for the calculation of aerosol radiative effect and the estimation of the man-made aerosol radiative forcing. MODIS can also be used in regional studies of aerosol-cloud interaction that affect the global radiative and hydrological cycles.

  7. End-Cretaceous marine mass extinction not caused by productivity collapse

    PubMed Central

    Alegret, Laia; Thomas, Ellen; Lohmann, Kyger C

    2012-01-01

    An asteroid impact at the end of the Cretaceous caused mass extinction, but extinction mechanisms are not well-understood. The collapse of sea surface to sea floor carbon isotope gradients has been interpreted as reflecting a global collapse of primary productivity (Strangelove Ocean) or export productivity (Living Ocean), which caused mass extinction higher in the marine food chain. Phytoplankton-dependent benthic foraminifera on the deep-sea floor, however, did not suffer significant extinction, suggesting that export productivity persisted at a level sufficient to support their populations. We compare benthic foraminiferal records with benthic and bulk stable carbon isotope records from the Pacific, Southeast Atlantic, and Southern Oceans. We conclude that end-Cretaceous decrease in export productivity was moderate, regional, and insufficient to explain marine mass extinction. A transient episode of surface ocean acidification may have been the main cause of extinction of calcifying plankton and ammonites, and recovery of productivity may have been as fast in the oceans as on land. PMID:22207626

  8. Field test of a new instrument to measure UV/Vis (300-700 nm) ambient aerosol extinction spectra in Colorado during DISCOVER-AQ

    NASA Astrophysics Data System (ADS)

    Jordan, C. E.; Anderson, B. E.; Beyersdorf, A. J.; Dibb, J. E.; Greenslade, M. E.; Martin, R.; Scheuer, E. M.; Shook, M.; Thornhill, K. L., II; Troop, D.; Winstead, E.; Ziemba, L. D.

    2014-12-01

    An optical instrument has been developed to investigate aerosol extinction spectra in the ambient atmosphere. Based on a White-type cell design and using a differential optical approach, aerosol extinction spectra over the 300-700 nm ultraviolet and visible (UV/Vis) wavelength range are obtained. Laboratory tests conducted at NASA Langley Research Center (NASA LaRC) in March 2014 showed good agreement with Cavity Attenuated Phase Shift (CAPS PMex, Aerodyne Research) extinction measurements (at 450, 530, and 630 nm) for a variety of aerosols, e.g., scatterers such as polystyrene latex spheres and ammonium sulfate; absorbers such as dust (including pigmented minerals), smoke (generated in a miniCAST burning propane) and laboratory smoke analogs (e.g., fullerene soot and aquadag). The instrument was field tested in Colorado in July and August 2014 aboard the NASA mobile laboratory at various ground sites during the DISCOVER-AQ (Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality) field campaign. A description of the instrument, results from the laboratory tests, and summer field data will be presented. The instrument provides a new tool for probing in situ aerosol optical properties that may help inform remote sensing approaches well into the UV range.

  9. Characterizing the Vertical Profile of Aerosol Particle Extinction and Linear Depolarization over Southeast Asia and the Maritime Continent: The 2007-2009 View from CALIOP

    NASA Technical Reports Server (NTRS)

    Campbell, James R.; Reid, Jeffrey S.; Westphal, Douglas L.; Zhang, Jianglong; Tackett, Jason L.; Chew, Boon Ning; Welton, Ellsworth J.; Shimizu, Atsushi; Sugimoto, Nobuo; Aoki, Kazuma; Winker, David M.

    2012-01-01

    Vertical profiles of 0.532 µm aerosol particle extinction coefficient and linear volume depolarization ratio are described for Southeast Asia and the Maritime Continent. Quality-screened and cloud-cleared Version 3.01 Level 2 NASA Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) 5-km Aerosol Profile datasets are analyzed from 2007 to 2009. Numerical simulations from the U.S. Naval Aerosol Analysis and Predictive System (NAAPS), featuring two-dimensional variational assimilation of NASA Moderate Resolution Imaging Spectroradiometer and Multi-angle Imaging Spectro- Radiometer quality-assured datasets, combined with regional ground-based lidar measurements, are considered for assessing CALIOP retrieval performance, identifying bias, and evaluating regional representativeness. CALIOP retrievals of aerosol particle extinction coefficient and aerosol optical depth (AOD) are high over land and low over open waters relative to NAAPS (0.412/0.312 over land for all data points inclusive, 0.310/0.235 when the per bin average is used and each is treated as single data points; 0.102/0.151 and 0.086/0.124, respectively, over ocean). Regional means, however, are very similar (0.180/0.193 for all data points and 0.155/0.159 when averaged per normalized bin), as the two factors offset one another. The land/ocean offset is investigated, and discrepancies attributed to interpretation of particle composition and a-priori assignment of the extinction-to-backscatter ratio ("lidar ratio") necessary for retrieving the extinction coefficient from CALIOP signals. Over land, NAAPS indicates more dust present than CALIOP algorithms are identifying, indicating a likely assignment of a higher lidar ratio representative of more absorptive particles. NAAPS resolvesmore smoke overwater than identified with CALIOP, indicating likely usage of a lidar ratio characteristic of less absorptive particles to be applied that biases low AOD there. Over open waters except within the Bay of Bengal

  10. Susceptibility of stored-product psocids to aerosol insecticides

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The efficacies of commercial methoprene and esfenvalerate aerosols for control of stored-product psocid pests were evaluated in simulated field studies. The efficacies of methoprene, esfenvalerate EC, the carrier Isopar-M™, and a combination of methoprene and esfenvalerate aerosols for control of Li...

  11. MODIS 3km Aerosol Product: Algorithm and Global Perspective

    NASA Technical Reports Server (NTRS)

    Remer, L. A.; Mattoo, S.; Levy, R. C.; Munchak, L.

    2013-01-01

    After more than a decade of producing a nominal 10 km aerosol product based on the dark target method, the MODIS aerosol team will be releasing a nominal 3 km product as part of their Collection 6 release. The new product differs from the original 10 km product only in the manner in which reflectance pixels are ingested, organized and selected by the aerosol algorithm. Overall, the 3 km product closely mirrors the 10 km product. However, the finer resolution product is able to retrieve over ocean closer to islands and coastlines, and is better able to resolve fine aerosol features such as smoke plumes over both ocean and land. In some situations, it provides retrievals over entire regions that the 10 km product barely samples. In situations traditionally difficult for the dark target algorithm, such as over bright or urban surfaces the 3 km product introduces isolated spikes of artificially high aerosol optical depth (AOD) that the 10 km algorithm avoids. Over land, globally, the 3 km product appears to be 0.01 to 0.02 higher than the 10 km product, while over ocean, the 3 km algorithm is retrieving a proportionally greater number of very low aerosol loading situations. Based on collocations with ground-based observations for only six months, expected errors associated with the 3 km land product are determined to be greater than for the 10 km product: 0.05 0.25 AOD. Over ocean, the suggestion is for expected errors to be the same as the 10 km product: 0.03 0.05 AOD. The advantage of the product is on the local scale, which will require continued evaluation not addressed here. Nevertheless, the new 3 km product is expected to provide important information complementary to existing satellite-derived products and become an important tool for the aerosol community.

  12. Aerosol Products from The Future Space Lidar AEOLUS

    NASA Astrophysics Data System (ADS)

    Martinet, Pauline; Dabas, Alain; Lever, Vincent; Flamant, Pierre; Huber, Dorit

    2016-06-01

    Ready for launch by the end of 2016, the Doppler lidar mission AEOLUS from the European Space Agency (ESA) will be the first High-Spectral Resolution Lidar (HSRL) in space. Operating in the UV, it implements two detection channels for aerosol and molecular backscatter. The system is primarily designed for the measurement of winds, but the HSRL capability enables the measurement of the particulate backscatter and extinction coefficients without any a priori assumption on the aerosol type. The level-2A (L2A) processor has been developed for these measurements and tested with synthetic data. The results show good aerosol backscatter profiles can be retrieved. Extinction coefficients are reasonable but do not reach the quality of backscatter coefficients. A precise, full, radiometric calibration of the lidar is required. A major limitation of the system is a single polarization component of the light is detected leading to an underestimation of backscatter coefficients when the atmospheric particles are depolarizing. The vertical resolution goes from 250 meters in the lowest part of the atmosphere, to 2 km in the lower stratosphere. The maximum altitude can reach above 20km. The basic horizontal averaging is 90km. Averaging on shorter distances (down to a few km) are possible but require a sufficient signal to noise ratio.

  13. 1984-1995 Evolution of Stratospheric Aerosol Size, Surface Area, and Volume Derived by Combining SAGE II and CLAES Extinction Measurements

    NASA Technical Reports Server (NTRS)

    Russell, Philip B.; Bauman, Jill J.

    2000-01-01

    This SAGE II Science Team task focuses on the development of a multi-wavelength, multi- sensor Look-Up-Table (LUT) algorithm for retrieving information about stratospheric aerosols from global satellite-based observations of particulate extinction. The LUT algorithm combines the 4-wavelength SAGE II extinction measurements (0.385 <= lambda <= 1.02 microns) with the 7.96 micron and 12.82 micron extinction measurements from the Cryogenic Limb Array Etalon Spectrometer (CLAES) instrument, thus increasing the information content available from either sensor alone. The algorithm uses the SAGE II/CLAES composite spectra in month-latitude-altitude bins to retrieve values and uncertainties of particle effective radius R(sub eff), surface area S, volume V and size distribution width sigma(sub g).

  14. Use of In Situ Cloud Condensation Nuclei, Extinction, and Aerosol Size Distribution Measurements to Test a Method for Retrieving Cloud Condensation Nuclei Profiles From Surface Measurements

    NASA Technical Reports Server (NTRS)

    Ghan, Stephen J.; Rissman, Tracey A.; Ellman, Robert; Ferrare, Richard A.; Turner, David; Flynn, Connor; Wang, Jian; Ogren, John; Hudson, James; Jonsson, Haflidi H.; VanReken, Timothy; Flagan, Richard C.; Seinfeld, John H.

    2006-01-01

    If the aerosol composition and size distribution below cloud are uniform, the vertical profile of cloud condensation nuclei (CCN) concentration can be retrieved entirely from surface measurements of CCN concentration and particle humidification function and surface-based retrievals of relative humidity and aerosol extinction or backscatter. This provides the potential for long-term measurements of CCN concentrations near cloud base. We have used a combination of aircraft, surface in situ, and surface remote sensing measurements to test various aspects of the retrieval scheme. Our analysis leads us to the following conclusions. The retrieval works better for supersaturations of 0.1% than for 1% because CCN concentrations at 0.1% are controlled by the same particles that control extinction and backscatter. If in situ measurements of extinction are used, the retrieval explains a majority of the CCN variance at high supersaturation for at least two and perhaps five of the eight flights examined. The retrieval of the vertical profile of the humidification factor is not the major limitation of the CCN retrieval scheme. Vertical structure in the aerosol size distribution and composition is the dominant source of error in the CCN retrieval, but this vertical structure is difficult to measure from remote sensing at visible wavelengths.

  15. Development of synthetic GOES-R ABI aerosol products

    NASA Astrophysics Data System (ADS)

    Hoff, R. M.; Kondragunta, S.; Ciren, P.; Xu, C.; Zhang, H.; Huff, A.

    2014-09-01

    An Observing Systems Simulation Experiment (OSSE) for GOES-R Advanced Baseline Imager (ABI) aerosol products has been carried out. The generation of simulated data involves prediction of aerosol chemical composition fields at one-hour resolution and 12 km × 12 km spacing. These data are then fed to a radiative transfer model to simulate the on-orbit radiances that the GOES-R ABI will see in six channels. This allows the ABI aerosol algorithm to be tested to produce products that will be available after launch. In cooperation with a user group of 40+ state and local air quality forecasters, the system has been tested in real-time experiments where the results mimic what the forecasters will see after 2016 when GOES-R launches. Feedback from this group has allowed refinement of the web display system for the ABI aerosol products and has creatively called for new products that were not envisaged by the satellite team.

  16. Aerosol Production in a Mixed Deciduous/Coniferous Forest

    NASA Astrophysics Data System (ADS)

    Slade, N.; Mielke, L.; Alaghmand, M.; Galloway, M.; Kammrath, A.; Keutsch, F.; Hansen, R.; Griffith, S.; Dusanter, S.; Stevens, P.; Carroll, M.; Bertman, S.; Shepson, P.

    2008-12-01

    Aerosols are of fundamental concern because of their impacts on air quality, human health and radiative forcing. Recent studies have focused on secondary organic aerosol (SOA) production due to oxidation of volatile organic compounds (VOCs), and more importantly biogenic-VOCs (BVOCs), in particular, isoprene. However, the SOA precursors are not well understood because the mechanisms have shown that isoprene oxidation can contribute to aerosol production through multiple generation oxidation products. For terpenes, it is more likely that primary or secondary oxidation products lead to particle formation. In the present study, we measured the aerosol size distribution, along with O3, HOx, NOx, NOy and BVOCs, in a mixed deciduous forest that is undergoing successional transition to a conifer-dominated species mix. This study was conducted in a rural forest environment in northern Michigan as a part of the summer 2008 PROPHET campaign at the University of Michigan Biological Station (UMBS). We examine here the potential BVOC contribution to aerosol formation. A TSI, inc. Scanning Mobility Particle Sizer (SMPS) was used to measure aerosol number density in the size range, 15 nm < x < 711 nm and a Proton Transfer Reaction - Linear Ion Trap (PTR-LIT) mass spectrometer for quantifying isoprene and other BVOCs, including methyl vinyl ketone and methacrolein, and total monoterpenes. Preliminary results show periods of new particle production. Here we use a unique set of BVOC, HOx, NOx, NOy, O3 and meteorological data to examine conditions leading to new particle production.

  17. Aerosol Optical Extinction during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE) 2014 Summertime Field Campaign, Colorado U.S.A.

    NASA Astrophysics Data System (ADS)

    Dingle, J. H.; Vu, K. K. T.; Bahreini, R.; Apel, E. C.; Campos, T. L.; Cantrell, C. A.; Cohen, R. C.; Ebben, C. J.; Flocke, F. M.; Fried, A.; Herndon, S. C.; Hills, A. J.; Hornbrook, R. S.; Huey, L. G.; Kaser, L.; Mauldin, L.; Montzka, D. D.; Nowak, J. B.; Richter, D.; Roscioli, J. R.; Shertz, S.; Stell, M. H.; Tanner, D.; Tyndall, G. S.; Walega, J.; Weibring, P.; Weinheimer, A. J.

    2015-12-01

    Aerosol optical extinction (βext) was measured in the Colorado Front Range Denver Metropolitan Area as part of the summertime air quality airborne field campaign to characterize the influence of sources, photochemical processing, and transport of pollution on local air quality. An Aerodyne Cavity Attenuated Phase Shift particle light extinction monitor (CAPS-PMex) was deployed to measure dry βext at λ=632 nm at 1 Hz. Data from a suite of gas-phase instrumentation were used to interpret the βext under various categories of aged air masses and sources. Extinction enhancement ratios of Δβext/ΔCO were evaluated under 3 differently aged air mass categories (fresh, intermediately aged, and aged) to investigate impacts of photochemistry on βext. Δβext/ΔCO was significantly increased in heavily aged air masses compared to fresh air masses (0.17 Mm-1/ppbv and 0.094 Mm-1/ppbv respectively). The resulting increase in Δβext/ΔCO under heavily aged air masses was represented by secondary organic aerosols (SOA) formation. Aerosol composition and sources from urban, natural oil and gas wells (OG), and agriculture and livestock operations were also evaluated for their impacts on βext. Linear regression fits to βext vs. organic aerosol mass showed higher correlation coefficients under the urban and OG plumes (r=0.55 and r=0.71 respectively) and weakest under agricultural and livestock plumes (r=0.28). The correlation between βext and nitrate aerosol mass however was best under the agriculture and livestock plumes (r=0.81), followed by OG plumes (r=0.74), suggesting co-location of aerosol nitrate precursor sources with OG emissions. Finally, non-refractory mass extinction efficiency (MEE) was analyzed. MEE was observed to be 1.37 g/m2 and 1.30 g/m2 in OG and urban+OG plumes, respectively.

  18. Analysis of Venus Express optical extinction due to aerosols in the upper haze of Venus

    NASA Astrophysics Data System (ADS)

    Parkinson, C. D.; Bougher, S. W.; Schulte, R.; Gao, P.; Yung, Y. L.; Vandaele, A.; Wilquet, V.; Mahieux, A.; Tellmann, S.

    2013-12-01

    Observations by the SPICAV/SOIR instruments aboard the Venus Express (VEx) spacecraft have revealed that the upper haze (UH) of Venus, between 70 and 90 km, is variable on the order of days to weeks and that it is populated by two particle modes. Gao et al. (submitted, Icarus, 2013) posit that one mode is made up of cloud particles that have diffused upwards from the main sulfuric acid cloud deck below, while the other mode is generated in situ by nucleation of sulfuric acid droplets on meteoric dust. They also propose that the observed variability in the UH is caused in part by vertical transient winds. They test this hypothesis by simulating a column of the Venus atmosphere from 40 to 100 km above the surface using a model based upon the Community Aerosol and Radiation Model for Atmospheres (CARMA). In this work, we significantly extend the analysis using the new more detailed SOIR/VeRa VEx temperature profiles which better constrain the observed strong CO2 15-micron cooling emission and 4.3-μm near-IR heating in Venus' atmosphere (and consistent with Venus Thermospheric General Circulation Model (VTGCM) simulations of Brecht et al. (2011)). We discuss our new results in context of the recent VEx observations (Wilquet et al., Icarus 217, 2012) with an intercomparison with the PVO data. We will also discuss similarities and differences arising from the PVO and VEx epochs where they exist. Additionally we report on our efforts self-consistently applying the VTGCM to constrain the degree to which effects due to vertical transient wind simulations can establish variability timescales and number density profiles that match VEx observations.

  19. Silicon production in an aerosol reactor

    NASA Technical Reports Server (NTRS)

    Wu, J. J.; Alam, M. K.; Johnson, B. E.; Flagan, R. C.

    1984-01-01

    An aerosol reactor for the growth of large silicon particles by silane pyrolysis was shown to demonstrate the following properties: (1) generate seed particles by pyrolysis of a small amount of silane; (2) mix seed aerosol with primary silane flow, limiting number concentration such that the amount of silane is sufficient to grow the desired size of particles from the seed; and (3) react the silane at a rate which is controlled such that the seed particles scavenge the condensible vapors rapidly enough to inhibit further nucleation.

  20. Organic Aerosol Component (OACOMP) Value-Added Product Report

    SciTech Connect

    Fast, J; Zhang, Q; Tilp, A; Shippert, T; Parworth, C; Mei, F

    2013-08-23

    Significantly improved returns in their aerosol chemistry data can be achieved via the development of a value-added product (VAP) of deriving OA components, called Organic Aerosol Components (OACOMP). OACOMP is primarily based on multivariate analysis of the measured organic mass spectral matrix. The key outputs of OACOMP are the concentration time series and the mass spectra of OA factors that are associated with distinct sources, formation and evolution processes, and physicochemical properties.

  1. Transmission of 10 micron radiation over coastal waters: comparison of point-source image intensities with aerosol extinction and MODTRAN calculations

    NASA Astrophysics Data System (ADS)

    Schwering, Piet B.; de Leeuw, Gerrit; van Eijk, Alexander M.

    1996-10-01

    During the MAPTIP experiments in the Dutch coastal waters, 11 October - 5 November 1993, transmission curves were determined from the intensities of the image of a point source suspended from a helicopter at ranges between 0.5 and 6 NMi. The images were recorded with a 10 micrometer USFA 9092 camera from the MeetPost Noordwijk, a research tower in the North Sea at 9 km from the Dutch coast. The transmission determined from the point source intensities at several ranges is compared with calculated values. The transmission is determined by extinction due to aerosols and molecular species in the propagation path. Both contributions can be determined using code using measured size distributions. Also effects of path radiance and background on the image intensity are considered. In this coastal area, and the off- shore winds that were usually encountered during MAPTIP, the aerosol size distributions are known to be a complicated mixture of continental and marine aerosols. Hence the common aerosol models, that usually work well over the open ocean, are often not so reliable in a coastal environment. An attempt is made to assess the influence of marine and anthropogenic contributions to the aerosol on the detection range of point targets in a coastal atmosphere.

  2. Production of Highly Charged Pharmaceutical Aerosols Using a New Aerosol Induction Charger

    PubMed Central

    Golshahi, Laleh; Longest, P. Worth; Holbrook, Landon; Snead, Jessica; Hindle, Michael

    2015-01-01

    Purpose Properly charged particles can be used for effective lung targeting of pharmaceutical aerosols. The objective of this study was to characterize the performance of a new induction charger that operates with a mesh nebulizer for the production of highly charged submicrometer aerosols to bypass the mouth-throat and deliver clinically relevant doses of medications to the lungs. Methods Variables of interest included combinations of model drug (i.e. albuterol sulfate) and charging excipient (NaCl) as well as strength of the charging field (1–5 kV/cm). Aerosol charge and size were measured using a modified electrical low pressure impactor system combined with high performance liquid chromatography. Results At the approximate mass median aerodynamic diameter (MMAD) of the aerosol (~ 0.4 μm), the induction charge on the particles was an order of magnitude above the field and diffusion charge limit. The nebulization rate was 439.3 ± 42.9 μl/min, which with a 0.1 % w/v solution delivered 419.5 ± 34.2 μg of medication per minute. A new correlation was developed to predict particle charge produced by the induction charger. Conclusions The combination of the aerosol induction charger and predictive correlations will allow for the practical generation and control of charged submicrometer aerosols for targeting deposition within the lungs. PMID:25823649

  3. A Chronology of Annual-Mean Effective Radii of Stratospheric Aerosols from Volcanic Eruptions During the Twentieth Century as Derived From Ground-based Spectral Extinction Measurements

    NASA Technical Reports Server (NTRS)

    Strothers, Richard B.; Hansen, James E. (Technical Monitor)

    2001-01-01

    Stratospheric extinction can be derived from ground-based spectral photometric observations of the Sun and other stars (as well as from satellite and aircraft measurements, available since 1979), and is found to increase after large volcanic eruptions. This increased extinction shows a characteristic wavelength dependence that gives information about the chemical composition and the effective (or area weighted mean) radius of the particles responsible for it. Known to be tiny aerosols constituted of sulfuric acid in a water solution, the stratospheric particles at midlatitudes exhibit a remarkable uniformity of their column-averaged effective radii r(sub eff) in the first few months after the eruption. Considering the seven largest eruptions of the twentieth century, r(sub eff) at this phase of peak aerosol abundance is approx. 0.3 micrometers in all cases. A year later, r(sub eff) either has remained about the same size (almost certainly in the case of the Katmai eruption of 1912) or has increased to approx. 0.5 micrometers (definitely so for the Pinatubo eruption of 1991). The reasons for this divergence in aerosol growth are unknown.

  4. MISR Aerosol Product Attributes and Statistical Comparisons with MODIS

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.; Nelson, David L.; Garay, Michael J.; Levy, Robert C.; Bull, Michael A.; Diner, David J.; Martonchik, John V.; Paradise, Susan R.; Hansen, Earl G.; Remer, Lorraine A.

    2009-01-01

    In this paper, Multi-angle Imaging SpectroRadiometer (MISR) aerosol product attributes are described, including geometry and algorithm performance flags. Actual retrieval coverage is mapped and explained in detail using representative global monthly data. Statistical comparisons are made with coincident aerosol optical depth (AOD) and Angstrom exponent (ANG) retrieval results from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The relationship between these results and the ones previously obtained for MISR and MODIS individually, based on comparisons with coincident ground-truth observations, is established. For the data examined, MISR and MODIS each obtain successful aerosol retrievals about 15% of the time, and coincident MISR-MODIS aerosol retrievals are obtained for about 6%-7% of the total overlap region. Cloud avoidance, glint and oblique-Sun exclusions, and other algorithm physical limitations account for these results. For both MISR and MODIS, successful retrievals are obtained for over 75% of locations where attempts are made. Where coincident AOD retrievals are obtained over ocean, the MISR-MODIS correlation coefficient is about 0.9; over land, the correlation coefficient is about 0.7. Differences are traced to specific known algorithm issues or conditions. Over-ocean ANG comparisons yield a correlation of 0.67, showing consistency in distinguishing aerosol air masses dominated by coarse-mode versus fine-mode particles. Sampling considerations imply that care must be taken when assessing monthly global aerosol direct radiative forcing and AOD trends with these products, but they can be used directly for many other applications, such as regional AOD gradient and aerosol air mass type mapping and aerosol transport model validation. Users are urged to take seriously the published product data-quality statements.

  5. MISR Global Aerosol Product Assessment by Comparison with AERONET

    NASA Astrophysics Data System (ADS)

    Gaitley, B. J.; Kahn, R. A.

    2010-12-01

    Barbara J. Gaitley1, Ralph Kahn2, 1Jet Propulsion Laboratory, California Institute of Technology, Pasadena CA 91109; 818-354-0552; 2NASA Goddard Space Flight Center; e-mail: barbara.gaitley@jpl.nasa.gov As a further step in validating the NASA Earth Observing System Terra satellite’s Multi-angle Imaging SpectroRadiometer (MISR) aerosol products, an extensive statistical comparison between MISR optical depth and Angstrom exponent and Aerosol Robotic Network (AERONET) retrievals has been completed. Angstrom exponent was interpreted in terms of components and mixtures used by the retrieval algorithm. Specific examples illustrating the analysis approach will be shown. Eight years of data from 81 geographically diverse sites having good long-term measurement records were first stratified based on locations where six broad aerosol air mass type categories are likely to occur: maritime, biomass burning, desert dust, urban pollution, continental and mixed dust+smoke aerosols. The number of actual coincident measurements was constrained by requiring that the AERONET direct sun aerosol optical depth (AOD) data was obtained within a two-hour window centered on the MISR overpass time. 5156 coincident observations are included in this AOD data set. AERONET direct sun data were averaged over the measurements obtained within this window, and were then interpolated to the MISR characteristic wavelengths to facilitate comparison. All AERONET measurements are Level 2.0, Version 2 data. A previous, systematic comparison of MISR and AERONET aerosol optical depth data [Kahn, Gaitley et al., JGR 110, 2005] identified specific, suggested improvements to the early post-launch MISR Standard Aerosol retrieval algorithms. Most of these suggestions were implemented in the uniformly reprocessed MISR Version 22 aerosol products used in the current study. We documented the performance of the current MISR products based on the comparison statistics. For example, agreement between AERONET and

  6. Susceptibility of Stored-Product Psocids to Aerosol Insecticides

    PubMed Central

    Opit, George P.; Arthur, Frank H.; Throne, James E.; Payton, Mark E.

    2012-01-01

    The efficacies of commercial methoprene and esfenvalerate aerosols for control of stored-product psocid pests were evaluated in simulated field studies. The efficacies of methoprene, esfenvalerate EC, the carrier Isopar-M™, and a combination of methoprene and esfenvalerate aerosols for control of Liposcelis decolor (Pearman) (Psocoptera: Liposcelididae) and Liposcelis entomophila (Enderlein) nymphs were assessed, and the effects of direct and indirect exposure of Liposcelis bostrychophila Badonnel, L. decolor, and Liposcelis paeta Pearman adults to esfenvalerate EC aerosol were evaluated. The greatest nymphal mortality attained was 76%, indicating that the four aerosols tested were ineffective against L. decolor and L. entomophila nymphs. In the direct and indirect exposure studies, the greatest adult mortalities attained for the three psocid species were 62 and 32%, respectively. Based on these data, esfenvalerate aerosol is ineffective for control of L. bostrychophila, L. decolor, L. entomophila, and L. paeta psocid species. This study shows that methoprene, esfenvalerate EC, and a combination of methoprene and esfenvalerate aerosols were ineffective against the four psocid species tested when applied at rates that are usually effective against other stored-product insect pests. PMID:23463916

  7. Susceptibility of stored-product psocids to aerosol insecticides.

    PubMed

    Opit, George P; Arthur, Frank H; Throne, James E; Payton, Mark E

    2012-01-01

    The efficacies of commercial methoprene and esfenvalerate aerosols for control of stored-product psocid pests were evaluated in simulated field studies. The efficacies of methoprene, esfenvalerate EC, the carrier Isopar-M™, and a combination of methoprene and esfenvalerate aerosols for control of Liposcelis decolor (Pearman) (Psocoptera: Liposcelididae) and Liposcelis entomophila (Enderlein) nymphs were assessed, and the effects of direct and indirect exposure of Liposcelis bostrychophila Badonnel, L. decolor, and Liposcelis paeta Pearman adults to esfenvalerate EC aerosol were evaluated. The greatest nymphal mortality attained was 76%, indicating that the four aerosols tested were ineffective against L. decolor and L. entomophila nymphs. In the direct and indirect exposure studies, the greatest adult mortalities attained for the three psocid species were 62 and 32%, respectively. Based on these data, esfenvalerate aerosol is ineffective for control of L. bostrychophila, L. decolor, L. entomophila, and L. paeta psocid species. This study shows that methoprene, esfenvalerate EC, and a combination of methoprene and esfenvalerate aerosols were ineffective against the four psocid species tested when applied at rates that are usually effective against other stored-product insect pests. PMID:23463916

  8. Lidar Ratios for Dust Aerosols Derived From Retrievals of CALIPSO Visible Extinction Profiles Constrained by Optical Depths from MODIS-Aqua and CALIPSO/CloudSat Ocean Surface Reflectance Measurements

    NASA Technical Reports Server (NTRS)

    Young, Stuart A.; Josset, Damien B.; Vaughan, Mark A.

    2010-01-01

    CALIPSO's (Cloud Aerosol Lidar Infrared Pathfinder Satellite Observations) analysis algorithms generally require the use of tabulated values of the lidar ratio in order to retrieve aerosol extinction and optical depth from measured profiles of attenuated backscatter. However, for any given time or location, the lidar ratio for a given aerosol type can differ from the tabulated value. To gain some insight as to the extent of the variability, we here calculate the lidar ratio for dust aerosols using aerosol optical depth constraints from two sources. Daytime measurements are constrained using Level 2, Collection 5, 550-nm aerosol optical depth measurements made over the ocean by the MODIS (Moderate Resolution Imaging Spectroradiometer) on board the Aqua satellite, which flies in formation with CALIPSO. We also retrieve lidar ratios from night-time profiles constrained by aerosol column optical depths obtained by analysis of CALIPSO and CloudSat backscatter signals from the ocean surface.

  9. The optical, physical and chemical properties of the products of glyoxal uptake on ammonium sulfate seed aerosols

    NASA Astrophysics Data System (ADS)

    Trainic, M.; Abo Riziq, A.; Lavi, A.; Flores, J. M.; Rudich, Y.

    2011-09-01

    The heterogeneous reaction between gas phase glyoxal and ammonium sulfate (AS) aerosols, a proxy for inorganic atmospheric aerosol, was studied in terms of the dependence of the optical, physical and chemical properties of the product aerosols on initial particle size and ambient relative humidity (RH). Our experiments imitate an atmospheric scenario of a dry particle hydration at ambient RH conditions in the presence of glyoxal gas followed by efflorescence due to decrease of the ambient RH. The reactions were studied under different RH conditions, starting from dry conditions (~20% RH) and up to 90% RH, covering conditions prevalent in many atmospheric environments, and followed by consequent drying of the reacted particles before their analysis by the aerosol mass spectrometer (AMS), cavity ring down (CRD) and scanning mobility particle sizer (SMPS) systems. At λ = 355 nm, the reacted aerosols demonstrate a substantial growth in optical extinction cross section, as well as in mobility diameter under a broad range of RH values (35-90%). The ratio of the product aerosol to seed aerosol geometric cross section reached up to ~3.5, and the optical extinction cross-section up to ~250. The reactions show a trend of increasing physical and optical growth with decreasing seed aerosol size, from 100 nm to 300 nm, as well as with decreasing RH values from 90% to ~40%. Optically inactive aerosols, at the limit of the Mie range (100 nm diameter) become optically active as they grow due to the reaction. AMS analyses of the reaction of 300 nm AS at RH values of 50%, 75% and 90% show that the main products of the reaction are glyoxal oligomers, formed by acetal formation in the presence of AS. In addition, imidazole formation, which is a minor channel, is observed for all reactions, yielding a product which absorbs at λ = 290 nm, with possible implications on the radiative properties of the product aerosols. The ratio of absorbing substances (C-N compounds, including

  10. Organic Aerosol Component (OACOMP) Value-Added Product

    SciTech Connect

    Fast, J; Zhang, Q; tilp, A; Shippert, T; Parworth, C; Mei, F

    2013-08-23

    Organic aerosol (OA, i.e., the organic fraction of particles) accounts for 10–90% of the fine aerosol mass globally and is a key determinant of aerosol radiative forcing. But atmospheric OA is poorly characterized and its life cycle insufficiently represented in models. As a result, current models are unable to simulate OA concentrations and properties accurately. This deficiency represents a large source of uncertainty in quantification of aerosol effects and prediction of future climate change. Evaluation and development of aerosol models require data products generated from field observations. Real-time, quantitative data acquired with aerosol mass spectrometers (AMS) (Canagaratna et al. 2007) are critical to this need. The AMS determines size-resolved concentrations of non-refractory (NR) species in submicrometer particles (PM1) with fast time resolution suitable for both ground-based and aircraft deployments. The high-resolution AMS (HR-AMS), which is equipped with a high mass resolution time-of-flight mass spectrometer, can be used to determine the elemental composition and oxidation degrees of OA (DeCarlo et al. 2006).

  11. Current Status of Suomi NPP VIIRS Aerosol Products

    NASA Astrophysics Data System (ADS)

    Kondragunta, S.; Laszlo, I.; Liu, H.; Zhang, H.; Huang, J.; Remer, L. A.; Ciren, P.; Huang, H.

    2013-12-01

    The Suomi National Polar-orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) instrument was launched on October 28, 2011. It provides Aerosol Optical Thickness (AOT) at two different spatial resolutions: a pixel level (~750 m at nadir) product called the Intermediate Product (IP) and an aggregated (~6 km at nadir) product called the Environmental Data Record (EDR). The VIIRS AOT is expected to provide continuity to the 10-km Aqua and Terra MODIS (Moderate resolution Imaging Spectroradiometer) AOT products that the air quality and public health community has been using. The VIIRS aerosol product suite also includes less mature products such as Suspended Matter (SM) and Aerosol Particle Size Parameter (APSP). An extensive validation of VIIRS best quality aerosol products with ground based L1.5 AERONET data shows that the AOT EDR product has an accuracy/precision of -0.01/0.11 and 0.01/0.08 over land and ocean respectively. Globally, VIIRS mean AOT EDR (0.20) is similar to Aqua MODIS (0.16) with some important regional and seasonal differences. Analysis of SM shows that the algorithm predominantly picks smoke both over land and ocean which is not in agreement with retrievals from Multi-angle Imaging SpectroRadiometer (MISR) and Cloud Aerosol Lidar and Infrared Pathfinder Space Observations (CALIPSO). Similarly, the Angstrom Exponent (AE) retrieval used as a proxy for particle size has no skill over land and only a marginal skill over ocean when compared to AERONET; although a bias of ~0.2 for over ocean retrievals meets specification (0.3), the correlation is low and the standard deviation is ~0.6 and does not meet specification (0.3). This evaluation places the VIIRS AOT product at the provisional maturity level (product is validated, may contain some errors, and ready for operational evaluation). However, several algorithm updates which include a better approach to retrieve surface reflectance are forthcoming. Current status of the aerosol

  12. PRODUCTION OF SECONDARY ORGANIC AEROSOL FROM MULTIPHASE TERPENE PHOTOOXIDATION

    EPA Science Inventory

    This project involves a field and laboratory study of the production of aerosol from the atmospheric photooxidation of biogenic volatile organic compounds (BVOCs), specifically the terpenes α- and β-pinene, using a unique combination of approaches that rely on produ...

  13. Validation of MODIS aerosol product with in-situ AERONET data (a study case in Hermosillo, Sonora, Mexico)

    NASA Astrophysics Data System (ADS)

    Valdes, M.; Leyva-Contreras, A.; Bonifaz, R.; Llamas, R.

    2009-12-01

    The aerosol optical thickness (AOT) is known as blocking particles which avoid the transmission of solar radiation coming from the Sun, and is defined as the integral of the coefficient of extinction over a vertical column of the Atmosphere. This coefficient of extinction is also defined as the limited fraction of the irradiance over the trajectory at a specific wavelength. The MODIS (Moderate Resolution Imaging Spectroradiometer) sensor provides aerosol data products all over the planet. However this data requires constant evaluation and validation using in-situ data such as the provided by the network of photometers managed by AERONET (Aerosol Robotic Network). In this work, the procedure of validation of the MODIS AOT data using AERONET data in the wavelengths of 660 and 675 nm is presented. It is expected that using validate remote sensing data which provides spatial and temporal information about the AOT will help to a better understanding of the behavior of the complex atmospheric conditions which characterize the NW of Mexico and SW of the US such as the Mexican monsoon.

  14. Raman Lidar Measurements of Aerosol Extinction and Backscattering. Report 2; Derivation of Aerosol Real Refractive Index, Single-Scattering Albedo, and Humidification Factor using Raman Lidar and Aircraft Size Distribution

    NASA Technical Reports Server (NTRS)

    Ferrare, R. A.; Melfi, S. H.; Whiteman, D. N.; Evans, K. D.; Poellot, M.; Kaufman, Y. J.

    1998-01-01

    Aerosol backscattering and extinction profiles measured by the NASA Goddard Space Flight Center Scanning Raman Lidar (SRL) during the remote cloud sensing (RCS) intensive operations period (IOP) at the Department of Energy Atmospheric Radiation Measurement (ARM) southern Great Plains (SGP) site during two nights in April 1994 are discussed. These profiles are shown to be consistent with the simultaneous aerosol size distribution measurements made by a PCASP (Passive Cavity Aerosol Spectrometer Probe) optical particle counter flown on the University of North Dakota Citation aircraft. We describe a technique which uses both lidar and PCASP measurements to derive the dependence of particle size on relative humidity, the aerosol real refractive index n, and estimate the effective single-scattering albedo Omega(sub 0). Values of n ranged between 1.4-1.5 (dry) and 1.37-1.47 (wet); Omega(sub 0) varied between 0.7 and 1.0. The single-scattering albedo derived from this technique is sensitive to the manner in which absorbing particles are represented in the aerosol mixture; representing the absorbing particles as an internal mixture rather than the external mixture assumed here results in generally higher values of Omega(sub 0). The lidar measurements indicate that the change in particle size with relative humidity as measured by the PCASP can be represented in the form discussed by Hattel with the exponent gamma = 0.3 + or - 0.05. The variations in aerosol optical and physical characteristics captured in the lidar and aircraft size distribution measurements are discussed in the context of the meteorological conditions observed during the experiment.

  15. Validation of GOMOS-Envisat vertical profiles of O3, NO2, NO3, and aerosol extinction using balloon-borne instruments and analysis of the retrievals

    NASA Astrophysics Data System (ADS)

    Renard, Jean-Baptiste; Berthet, Gwenaël; Brogniez, Colette; Catoire, Valery; Fussen, Didier; Goutail, Florence; Oelhaf, Hermann; Pommereau, Jean-Pierre; Roscoe, Howard K.; Wetzel, Gerald; Chartier, Michel; Robert, Claude; Balois, Jean-Yves; Verwaerde, Christian; Auriol, Frédérique; François, Philippe; Gaubicher, Bertrand; Wursteisen, Patrick

    2008-02-01

    The UV-visible Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument onboard Envisat performs nighttime measurements of ozone, NO2, NO3 and of the aerosol extinction, using the stellar occultation method. We have conducted a validation exercise using various balloon-borne instruments in different geophysical conditions from 2002 to 2006, using GOMOS measurements performed with stars of different magnitudes. GOMOS and balloon-borne vertical columns in the middle stratosphere are in excellent agreement for ozone and NO2. Some discrepancies can appear between GOMOS and balloon-borne vertical profiles for the altitude and the amplitude of the concentration maximum. These discrepancies are randomly distributed, and no bias is detected. The accuracy of individual profiles in the middle stratosphere is 10 % for ozone and 25 % for NO2. On the other hand, the GOMOS NO3 retrieval is difficult and no direct validation can be conducted. The GOMOS aerosol content is also well estimated, but the wavelength dependence can be better estimated if the aerosol retrieval is performed only in the visible domain. We can conclude that the GOMOS operational retrieval algorithm works well and that GOMOS has fully respected its primary objective for the study of the trends of species in the middle stratosphere, using the profiles in a statistical manner. Some individual profiles can be partly inaccurate, in particular in the lower stratosphere. Improvements could be obtained by reprocessing some GOMOS transmissions in case of specific studies in the middle and lower stratosphere when using the individual profiles.

  16. 21 CFR 700.16 - Use of aerosol cosmetic products containing zirconium.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 7 2010-04-01 2010-04-01 false Use of aerosol cosmetic products containing... SERVICES (CONTINUED) COSMETICS GENERAL Requirements for Specific Cosmetic Products § 700.16 Use of aerosol... in cosmetics and/or cosmetics that are also drugs, as, for example, aerosol antiperspirants....

  17. The Collection 6 MODIS aerosol products over land and ocean

    NASA Astrophysics Data System (ADS)

    Levy, R. C.; Mattoo, S.; Munchak, L. A.; Remer, L. A.; Sayer, A. M.; Hsu, N. C.

    2013-01-01

    The twin Moderate Imaging resolution Spectroradiometer (MODIS) sensors have been flying on Terra since 2000 and Aqua since 2002, creating an incredible dataset of global Earth observations. Here, we introduce the Collection 6 (C6) algorithm to retrieve aerosol optical depth (AOD) and aerosol size parameters from MODIS-observed spectral reflectance. While not a major overhaul from the previous Collection 5 (C5) version, there are enough changes that there is significant impact on the products and their interpretation. The C6 algorithm is comprised of three sub-algorithms for retrieving aerosol properties (1) over ocean (dark in visible and near-IR wavelengths), (2) over vegetated/dark-soiled land (dark in the visible) and (3) over desert/arid land (bright in the visible). Here, we focus on the changes to both "dark target" algorithms (#1 and #2; DT-ocean and DT-land). Affecting both DT algorithms, we have updated assumptions for central wavelengths, Rayleigh optical depths and gas (H2O, O3, CO2, etc.) absorption corrections, and relaxed the solar zenith angle limit (up to ≤ 84°) to increase pole-ward coverage. For DT-land, we have updated the cloud mask to allow heavy smoke retrievals, fine-tuned the assignments for aerosol type as function of season/location, corrected bugs in the Quality Assurance (QA) logic, and added diagnostic parameters such topographic altitude. For DT-ocean, improvements include a revised cloud mask for thin-cirrus detection, inclusion of wind speed dependence in the retrieval, updates to logic of QA Confidence flag (QAC) assignment, and additions of important diagnostic information. All together, the changes to the DT algorithms result in reduced global AOD (by 0.02) over ocean and increased AOD (by 0.01) over land, along with some changes in spatial coverage. Preliminary validation shows that compared to surface-based sunphotometer data, the C6 DT-products should compare at least as well as those from C5. However, at the same time as we

  18. The Collection 6 'dark-target' MODIS Aerosol Products

    NASA Technical Reports Server (NTRS)

    Levy, Robert C.; Mattoo, Shana; Munchak, Leigh A.; Kleidman, Richard G.; Patadia, Falguni; Gupta, Pawan; Remer, Lorraine

    2013-01-01

    Aerosol retrieval algorithms are applied to Moderate resolution Imaging Spectroradiometer (MODIS) sensors on both Terra and Aqua, creating two streams of decade-plus aerosol information. Products of aerosol optical depth (AOD) and aerosol size are used for many applications, but the primary concern is that these global products are comprehensive and consistent enough for use in climate studies. One of our major customers is the international modeling comparison study known as AEROCOM, which relies on the MODIS data as a benchmark. In order to keep up with the needs of AEROCOM and other MODIS data users, while utilizing new science and tools, we have improved the algorithms and products. The code, and the associated products, will be known as Collection 6 (C6). While not a major overhaul from the previous Collection 5 (C5) version, there are enough changes that there are significant impacts to the products and their interpretation. In its entirety, the C6 algorithm is comprised of three sub-algorithms for retrieving aerosol properties over different surfaces: These include the dark-target DT algorithms to retrieve over (1) ocean and (2) vegetated-dark-soiled land, plus the (3) Deep Blue (DB) algorithm, originally developed to retrieve over desert-arid land. Focusing on the two DT algorithms, we have updated assumptions for central wavelengths, Rayleigh optical depths and gas (H2O, O3, CO2, etc.) absorption corrections, while relaxing the solar zenith angle limit (up to 84) to increase pole-ward coverage. For DT-land, we have updated the cloud mask to allow heavy smoke retrievals, fine-tuned the assignments for aerosol type as function of season location, corrected bugs in the Quality Assurance (QA) logic, and added diagnostic parameters such as topographic altitude. For DT-ocean, improvements include a revised cloud mask for thin-cirrus detection, inclusion of wind speed dependence in the retrieval, updates to logic of QA Confidence flag (QAC) assignment, and

  19. An investigation of a potential low bias in the MODIS aerosol products over Asia

    NASA Astrophysics Data System (ADS)

    McHardy, T. M.; Shi, Y.; Zhang, J.; Reid, J. S.; Campbell, J. R.; Hsu, N. Y. C.

    2015-12-01

    Heavy aerosol plumes can be misidentified as clouds in passive satellite-based aerosol retrievals due to their relatively high visible reflectivity. Thus, over regions such as China, where a higher frequency of heavy aerosol plumes is expected, regional aerosol optical depth analyses reported from passive satellite-based aerosol products may biased low. This fundamental error can be suppressed under certain conditions. In this study, with a synergistic use of satellite observations from MODIS, OMI and CALIOP, a low bias in the MODIS Dark Target (DT) and Deep Blue (DB) aerosol products is studied over Asia for the influence of dense aerosol plume undersampling. A new scheme has been developed for detecting heavy aerosol plumes by coupling OMI aerosol index retrievals with available CALIOP level 1B and cloud and aerosol profile data. Collocated CALIOP, MODIS and OMI data are then used to further investigate the potential low bias in the MODIS DT and DB aerosol products, in an attempt to quantify the measure of undersampling in the regional DT and DB archive. Our preliminary results show that DT and DB aerosol algorithms detect about half heavy aerosol loading when CALIPSO and OMI AI believe there are heavy absorbing aerosols.

  20. The Collection 6 MODIS aerosol products over land and ocean

    NASA Astrophysics Data System (ADS)

    Levy, R. C.; Mattoo, S.; Munchak, L. A.; Remer, L. A.; Sayer, A. M.; Patadia, F.; Hsu, N. C.

    2013-11-01

    The twin Moderate resolution Imaging Spectroradiometer (MODIS) sensors have been flying on Terra since 2000 and Aqua since 2002, creating an extensive data set of global Earth observations. Here, we introduce the Collection 6 (C6) algorithm to retrieve aerosol optical depth (AOD) and aerosol size parameters from MODIS-observed spectral reflectance. While not a major overhaul from the previous Collection 5 (C5) version, there are enough changes that there are significant impacts to the products and their interpretation. The C6 aerosol data set will be created from three separate retrieval algorithms that operate over different surface types. These are the two "Dark Target" (DT) algorithms for retrieving (1) over ocean (dark in visible and longer wavelengths) and (2) over vegetated/dark-soiled land (dark in the visible), plus the "Deep Blue" (DB) algorithm developed originally for retrieving (3) over desert/arid land (bright in the visible). Here, we focus on DT-ocean and DT-land (#1 and #2). We have updated assumptions for central wavelengths, Rayleigh optical depths and gas (H2O, O3, CO2, etc.) absorption corrections, while relaxing the solar zenith angle limit (up to ≤ 84°) to increase poleward coverage. For DT-land, we have updated the cloud mask to allow heavy smoke retrievals, fine-tuned the assignments for aerosol type as function of season/location, corrected bugs in the Quality Assurance (QA) logic, and added diagnostic parameters such topographic altitude. For DT-ocean, improvements include a revised cloud mask for thin-cirrus detection, inclusion of wind speed dependence on the surface reflectance, updates to logic of QA Confidence flag (QAC) assignment, and additions of important diagnostic information. At the same time, we quantified how "upstream" changes to instrument calibration, land/sea masking and cloud masking will also impact the statistics of global AOD, and affect Terra and Aqua differently. For Aqua, all changes will result in reduced

  1. Simultaneous measurement of atmospheric temperature, humidity, and aerosol extinction and backscatter coefficients by a combined vibrational pure-rotational Raman lidar

    NASA Astrophysics Data System (ADS)

    Balin, I.; Serikov, I.; Bobrovnikov, S.; Simeonov, V.; Calpini, B.; Arshinov, Y.; van den Bergh, H.

    2004-10-01

    Implementation of the pure-rotational Raman (PRR) lidar method for simultaneous measurement of atmospheric temperature, humidity, and aerosol extinction and backscatter coefficients is reported. The isolation of two wavelength domains of the PRR spectrum and the suppression of the elastically scattered light is carried out by a double-grating polychromator. Experiments involving elastic backscatter from dense clouds and a solid target confirm the high level of suppression of the elastic light in the corresponding acquisition channels of the two selected PRR domains. Calibration of the temperature channel was done both by comparison with an experimentally verified atmospheric temperature model profile and by inter-comparison with radiosondes. Night-time temperature profiles with high vertical resolution were obtained up to the lower stratosphere. The PRR temperature profile combined with the water vapor mixing ratio obtained from the ro-vibrational Raman channel is used to estimate the relative humidity.

  2. Condensation nuclei and aerosol-scattering extinction measurements at Mauna Loa Observatory: 1974-1985. Data report

    SciTech Connect

    Massey, D.M.; Quakenbush, T.K.; Bodhaine, B.A.

    1987-07-01

    The observatory at Mauna Loa, Hawaii measures the characteristics of surface aerosols under background conditions. The instruments provide data that are representative of the background-aerosol climatology at Mauna Loa. These data can also be used to identify potential local contamination periods. The nephelometer's light-scattering measurements show an annual cycle: a maximum in April and a minimum in November, with a variation of a factor of 5.5. The Condensation Nucleus (CN) counter shows a much smaller annual cycle: a maximum in September and a minimum in March, with a variation of a factor of 1.5. A local decrease in CN concentration occurs in August. The Angstrom exponent minimum occurs in May. This indicates larger aerosol particles within the month as compared with the remainder of the year.

  3. What is the "Clim-Likely" aerosol product?

    Atmospheric Science Data Center

    2014-12-08

    The "Clim-Likely" aerosol climatology data set was developed as an initial step in identifying a range of ... mixtures for the MISR Standard Aerosol Retrieval Algorithm climatology, and as one standard against which to compare MISR aerosol air mass ...

  4. MISR Global Aerosol Product Assessment by Comparison with AERONET

    NASA Technical Reports Server (NTRS)

    Kahn, Ralph A.; Gaitley, Barbara J.; Garay, Michael J.; Diner, David J.; Eck, Thomas F.; Smirnov, Alexander; Holben, Brent N.

    2010-01-01

    A statistical approach is used to assess the quality of the MISR Version 22 (V22) aerosol products. Aerosol Optical Depth (AOD) retrieval results are improved relative to the early post- launch values reported by Kahn et al. [2005a], varying with particle type category. Overall, about 70% to 75% of MISR AOD retrievals fall within 0.05 or 20% AOD of the paired validation data, and about 50% to 55% are within 0.03 or 10% AOD, except at sites where dust, or mixed dust and smoke, are commonly found. Retrieved particle microphysical properties amount to categorical values, such as three groupings in size: "small," "medium," and "large." For particle size, ground-based AERONET sun photometer Angstrom Exponents are used to assess statistically the corresponding MISR values, which are interpreted in terms of retrieved size categories. Coincident Single-Scattering Albedo (SSA) and fraction AOD spherical data are too limited for statistical validation. V22 distinguishes two or three size bins, depending on aerosol type, and about two bins in SSA (absorbing vs. non-absorbing), as well as spherical vs. non-spherical particles, under good retrieval conditions. Particle type sensitivity varies considerably with conditions, and is diminished for mid-visible AOD below about 0.15 or 0.2. Based on these results, specific algorithm upgrades are proposed, and are being investigated by the MISR team for possible implementation in future versions of the product.

  5. CU AMAX-DOAS applications in cloud-free and cloudy atmospheres: innovative Scattered Sun Light observations of trace gases and aerosol extinction

    NASA Astrophysics Data System (ADS)

    Volkamer, R.; Baidar, S.; Coburn, S.; Dix, B. K.; Oetjen, H.; Ortega, I.; Sinreich, R.; Atmospeclab

    2011-12-01

    An innovative airborne scanning multi-axis differential optical absorption spectroscopy (CU AMAX-DOAS) instrument has been developed at the University of Colorado, Boulder. The instrument collects scattered sunlight spectra in a sequence of discrete viewing angles, and employs the DOAS method (inherently calibrated, and selective) to simultaneously retrieve multiple trace gases, e.g., nitrogen dioxide (NO2), nitrous acid (HONO), formaldehyde (HCHO), glyoxal (CHOCHO), bromine oxide (BrO), iodine oxide (IO), chlorine dioxide (OClO), water vapor (H2O), and oxygen dimers (O4, at 360nm, 477nm, and 632nm) differential slant column densities (dSCD). Vertical profiles of these gases and multi-spectral aerosol extinction are inferred by combining Monte-Carlo Radiative Transfer Modelling (RTM) and optimal estimation techniques to construct a model atmosphere that can in principle represent 3D clouds and aerosols. The atmospheric state of this model atmosphere is constrained by observations of O4 dSCDs, Raman Scattering Probability (RSP), and intensity ratios, i.e., quantities that depend solely on relative intensity changes, without need for a direct sun view, or absolute radiance calibration. We show results from ongoing validation efforts (NOAA TwinOtter aircraft during CalNex and CARES), and demonstrate vertical profile retrievals (NSF/NCAR GV over the tropical Pacific Ocean) in both cloud-free and cloudy atmospheres.

  6. A merged aerosol dataset based on MODIS and MISR Aerosol Optical Depth products

    NASA Astrophysics Data System (ADS)

    Singh, Manoj K.; Gautam, Ritesh; Venkatachalam, Parvatham

    2016-05-01

    Aerosol Optical Depth (AOD) products available from MODIS and MISR observations are widely used for aerosol characterization, and global/environmental change studies. These products are based on different retrieval-algorithms, resolutions, sampling, and cloud-screening schemes, which have led to global/regional biases. Thus a merged product is desirable which bridges this gap by utilizing strengths from each of the sensors. In view of this, we have developed a "merged" AOD product based on MODIS and MISR AOD datasets, using Bayesian principles which takes error distributions from ground-based AOD measurements (from AERONET). Our methodology and resulting dataset are especially relevant in the scenario of combining multi-sensor retrievals for satellite-based climate data records; particularly for long-term studies involving AOD. Specifically for MISR AOD product, we also developed a methodology to produce a gap-filled dataset, using geostatistical methods (e.g. Kriging), taking advantage of available MODIS data. Merged and spatially-complete AOD datasets are inter-compared with other satellite products and with AERONET data at three stations- Kanpur, Jaipur and Gandhi College, in the Indo-Gangetic Plains. The RMSE of merged AOD (0.08-0.09) is lower than MISR (0.11-0.20) and MODIS (0.15-0.27). It is found that merged AOD has higher correlation with AERONET data (r within 0.92-0.95), compared to MISR (0.74-0.86) and MODIS (0.69-0.84) data. In terms of Expected Error, the accuracy of valid merged AOD is found to be superior as percent of merged AOD within error envelope are larger (71-92%), compared to MISR (43-61%) and MODIS (50-70%).

  7. Classification of Dust Days by Satellite Remotely Sensed Aerosol Products

    NASA Technical Reports Server (NTRS)

    Sorek-Hammer, M.; Cohen, A.; Levy, Robert C.; Ziv, B.; Broday, D. M.

    2013-01-01

    Considerable progress in satellite remote sensing (SRS) of dust particles has been seen in the last decade. From an environmental health perspective, such an event detection, after linking it to ground particulate matter (PM) concentrations, can proxy acute exposure to respirable particles of certain properties (i.e. size, composition, and toxicity). Being affected considerably by atmospheric dust, previous studies in the Eastern Mediterranean, and in Israel in particular, have focused on mechanistic and synoptic prediction, classification, and characterization of dust events. In particular, a scheme for identifying dust days (DD) in Israel based on ground PM10 (particulate matter of size smaller than 10 nm) measurements has been suggested, which has been validated by compositional analysis. This scheme requires information regarding ground PM10 levels, which is naturally limited in places with sparse ground-monitoring coverage. In such cases, SRS may be an efficient and cost-effective alternative to ground measurements. This work demonstrates a new model for identifying DD and non-DD (NDD) over Israel based on an integration of aerosol products from different satellite platforms (Moderate Resolution Imaging Spectroradiometer (MODIS) and Ozone Monitoring Instrument (OMI)). Analysis of ground-monitoring data from 2007 to 2008 in southern Israel revealed 67 DD, with more than 88 percent occurring during winter and spring. A Classification and Regression Tree (CART) model that was applied to a database containing ground monitoring (the dependent variable) and SRS aerosol product (the independent variables) records revealed an optimal set of binary variables for the identification of DD. These variables are combinations of the following primary variables: the calendar month, ground-level relative humidity (RH), the aerosol optical depth (AOD) from MODIS, and the aerosol absorbing index (AAI) from OMI. A logistic regression that uses these variables, coded as binary

  8. Light-enhanced primary marine aerosol production from biologically productive seawater

    NASA Astrophysics Data System (ADS)

    Long, M. S.; Keene, W. C.; Kieber, D. J.; Frossard, A. A.; Russell, L. M.; Maben, J. R.; Kinsey, J. D.; Quinn, P. K.; Bates, T. S.

    2014-04-01

    Physical and biogeochemical processes in seawater controlling primary marine aerosol (PMA) production and composition are poorly understood and associated with large uncertainties in estimated fluxes into the atmosphere. PMA production was investigated in the biologically productive NE Pacific Ocean and in biologically productive and oligotrophic regions of the NW Atlantic Ocean. Physicochemical properties of model PMA, produced by aeration of fresh seawater under controlled conditions, were quantified. Diel variability in model PMA mass and number fluxes was observed in biologically productive waters, increasing following sunrise and decreasing to predawn levels overnight. Such variability was not seen in oligotrophic waters. During daytime, surfactant scavenging by aeration in the aerosol generator without replenishing the seawater in the reservoir reduced the model PMA production in productive waters to nighttime levels but had no influence on production from oligotrophic waters. Results suggest bubble plume interactions with sunlight-mediated biogenic surfactants in productive seawater significantly enhanced model PMA production.

  9. The Multi-Sensor Aerosol Products Sampling System (MAPSS) for Integrated Analysis of Satellite Retrieval Uncertainties

    NASA Technical Reports Server (NTRS)

    Ichoku, Charles; Petrenko, Maksym; Leptoukh, Gregory

    2010-01-01

    Among the known atmospheric constituents, aerosols represent the greatest uncertainty in climate research. Although satellite-based aerosol retrieval has practically become routine, especially during the last decade, there is often disagreement between similar aerosol parameters retrieved from different sensors, leaving users confused as to which sensors to trust for answering important science questions about the distribution, properties, and impacts of aerosols. As long as there is no consensus and the inconsistencies are not well characterized and understood ', there will be no way of developing reliable climate data records from satellite aerosol measurements. Fortunately, the most globally representative well-calibrated ground-based aerosol measurements corresponding to the satellite-retrieved products are available from the Aerosol Robotic Network (AERONET). To adequately utilize the advantages offered by this vital resource,., an online Multi-sensor Aerosol Products Sampling System (MAPSS) was recently developed. The aim of MAPSS is to facilitate detailed comparative analysis of satellite aerosol measurements from different sensors (Terra-MODIS, Aqua-MODIS, Terra-MISR, Aura-OMI, Parasol-POLDER, and Calipso-CALIOP) based on the collocation of these data products over AERONET stations. In this presentation, we will describe the strategy of the MAPSS system, its potential advantages for the aerosol community, and the preliminary results of an integrated comparative uncertainty analysis of aerosol products from multiple satellite sensors.

  10. Toward a Coherent Detailed Evaluation of Aerosol Data Products from Multiple Satellite Sensors

    NASA Technical Reports Server (NTRS)

    Ichoku, Charles; Petrenko, Maksym; Leptoukh, Gregory

    2011-01-01

    Atmospheric aerosols represent one of the greatest uncertainties in climate research. Although satellite-based aerosol retrieval has practically become routine, especially during the last decade, there is often disagreement between similar aerosol parameters retrieved from different sensors, leaving users confused as to which sensors to trust for answering important science questions about the distribution, properties, and impacts of aerosols. As long as there is no consensus and the inconsistencies are not well characterized and understood, there will be no way of developing reliable climate data records from satellite aerosol measurements. Fortunately, the most globally representative well-calibrated ground-based aerosol measurements corresponding to the satellite-retrieved products are available from the Aerosol Robotic Network (AERONET). To adequately utilize the advantages offered by this vital resource, an online Multi-sensor Aerosol Products Sampling System (MAPSS) was recently developed. The aim of MAPSS is to facilitate detailed comparative analysis of satellite aerosol measurements from different sensors (Terra-MODIS, Aqua-MODIS, TerraMISR, Aura-OMI, Parasol-POLDER, and Calipso-CALIOP) based on the collocation of these data products over AERONET stations. In this presentation, we will describe the strategy of the MASS system, its potential advantages for the aerosol community, and the preliminary results of an integrated comparative uncertainly analysis of aerosol products from multiple satellite sensors.

  11. Kinetics, products, and mechanisms of secondary organic aerosol formation.

    PubMed

    Ziemann, Paul J; Atkinson, Roger

    2012-10-01

    Secondary organic aerosol (SOA) is formed in the atmosphere when volatile organic compounds (VOCs) emitted from anthropogenic and biogenic sources are oxidized by reactions with OH radicals, O(3), NO(3) radicals, or Cl atoms to form less volatile products that subsequently partition into aerosol particles. Once in particles, these organic compounds can undergo heterogenous/multiphase reactions to form more highly oxidized or oligomeric products. SOA comprises a large fraction of atmospheric aerosol mass and can have significant effects on atmospheric chemistry, visibility, human health, and climate. Previous articles have reviewed the kinetics, products, and mechanisms of atmospheric VOC reactions and the general chemistry and physics involved in SOA formation. In this article we present a detailed review of VOC and heterogeneous/multiphase chemistry as they apply to SOA formation, with a focus on the effects of VOC molecular structure on the kinetics of initial reactions with the major atmospheric oxidants, the subsequent reactions of alkyl, alkyl peroxy, and alkoxy radical intermediates, and the composition of the resulting products. Structural features of reactants and products discussed include compound carbon number; linear, branched, and cyclic configurations; the presence of C[double bond, length as m-dash]C bonds and aromatic rings; and functional groups such as carbonyl, hydroxyl, ester, hydroxperoxy, carboxyl, peroxycarboxyl, nitrate, and peroxynitrate. The intention of this review is to provide atmospheric chemists with sufficient information to understand the dominant pathways by which the major classes of atmospheric VOCs react to form SOA products, and the further reactions of these products in particles. This will allow reasonable predictions to be made, based on molecular structure, about the kinetics, products, and mechanisms of VOC and heterogeneous/multiphase reactions, including the effects of important variables such as VOC, oxidant, and NO

  12. Species-range size distributions: products of speciation, extinction and transformation

    PubMed Central

    Gaston, K. J.

    1998-01-01

    One basic summary of the spatial pattern of biodiversity across the surface of the Earth is provided by a species-range size distribution, the frequency distribution of the numbers of species exhibiting geographic ranges of different sizes. Although widely considered to be approximately lognormal, increasingly it appears that across a variety of groups of organisms this distribution systematically departs from such a form. Whatever its detailed shape, however, the distribution must arise as a product of three processes, speciation, extinction and transformation (the temporal dynamics of the range sizes of species during their life times). Considering the role potentially played by each of these processes necessitates drawing on information from a diverse array of research fields, and highlights the possible role of geographic range size as a common currency uniting them.

  13. 21 CFR 700.16 - Use of aerosol cosmetic products containing zirconium.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 7 2011-04-01 2010-04-01 true Use of aerosol cosmetic products containing... SERVICES (CONTINUED) COSMETICS GENERAL Requirements for Specific Cosmetic Products § 700.16 Use of aerosol cosmetic products containing zirconium. (a) Zirconium-containing complexes have been used as an...

  14. 21 CFR 700.16 - Use of aerosol cosmetic products containing zirconium.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 7 2012-04-01 2012-04-01 false Use of aerosol cosmetic products containing... SERVICES (CONTINUED) COSMETICS GENERAL Requirements for Specific Cosmetic Products § 700.16 Use of aerosol cosmetic products containing zirconium. (a) Zirconium-containing complexes have been used as an...

  15. 21 CFR 700.16 - Use of aerosol cosmetic products containing zirconium.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 7 2014-04-01 2014-04-01 false Use of aerosol cosmetic products containing... SERVICES (CONTINUED) COSMETICS GENERAL Requirements for Specific Cosmetic Products § 700.16 Use of aerosol cosmetic products containing zirconium. (a) Zirconium-containing complexes have been used as an...

  16. Evaluating MODIS Collection 6 Dark Target Over Water Aerosol Products for Multi-sensor Data Fusion

    NASA Astrophysics Data System (ADS)

    Shi, Y.; Zhang, J.; Reid, J. S.; Hyer, E. J.; McHardy, T. M.; Lee, L.

    2014-12-01

    The Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol products have been widely used in aerosol related climate, visibility, and air quality studies for more than a decade. Recently, the MODIS collection 6 (c6) aerosol products from MODIS-Aqua have been released. The reported changes between Collection 5 and Collection 6 include updates in the retrieving algorithms and a new cloud filtering process for the over-ocean products. Thus it is necessary to fully evaluate the collection 6 products for applications that require high quality MODIS aerosol optical depth data, such as operational aerosol data assimilation. The uncertainties in the MODIS c6 DT over ocean products are studied through both inter-comparing with the Multi-angle Imaging Spectroradiometer (MISR) aerosol products and by evaluation against ground truth. Special attention is given to the low bias in MODIS DT products due to the misclassifications of heavy aerosol plumes as clouds. Finally, a quality assured data assimilation grade aerosol optical product is constructed for aerosol data assimilation related applications.

  17. Secondary organic material formed by methylglyoxal in aqueous aerosol mimics - Part 2: Product identification using Aerosol-CIMS

    NASA Astrophysics Data System (ADS)

    Sareen, N.; Shapiro, E. L.; Schwier, A. N.; McNeill, V. F.

    2009-07-01

    We used chemical ionization mass spectrometry with a volatilization flow tube inlet (Aerosol-CIMS) to characterize secondary organic material formed by methylglyoxal with ammonium sulfate in aqueous aerosol mimics. Bulk reaction mixtures were diluted and atomized to form submicron aerosol particles. Organics were detected using Aerosol-CIMS in positive and negative ion mode using I- and H3O+·(H2O)n as reagent ions. The results are consistent with aldol condensation products, carbon-nitrogen species, sulfur-containing compounds, and oligomeric species up to 759 amu. These results support previous observations by us and others that ammonium sulfate plays a critical role in the SOA formation chemistry of dicarbonyl compounds.

  18. Oxygenated products of sesquiterpenes in secondary organic aerosol

    NASA Astrophysics Data System (ADS)

    van Eijck, A.; Kampf, C.; Hoffmann, T.

    2012-04-01

    Secondary organic aerosol (SOA) has a huge impact on air quality and climate change. It influences the Earth radiative budget through absorbing, scattering and reflecting radiation as well as the formation of clouds because the particulates can act as cloud condensation nuclei (CCN). Furthermore, it plays an important role for human health. SOA is formed from gaseous precursors which get oxidized by ozone, OH- and NO3-radicals in the atmosphere. Due to their low vapor pressure these degradation products can nucleate to form new particles or they can condense on existing aerosol particles. Despite the major progress in research during the last few years the actual chemical composition as well as the contribution of various volatile organic compounds (VOCs) to the formation of secondary organic aerosol is still partially unknown. Recent studies indicate that sesquiterpenes play an important role in the formation of SOA because of the low volatility of their oxygenated products (Lee et al., 2006). Their emission is estimated to be about 14,8 Tg per year (Henze et al., 2008), however, these emission rates remain highly uncertain due to the lack of quantitative emission rate measurements. In addition, the knowledge about the actual atmospheric degradation mechanism and the main oxidation products of sesquiterpenes is quite limited. β-Caryophyllene, α-humulene, α-farnesene and β-farnesene are the most abundant sequiterpenes in many sesquiterpene emission profiles. But also aromadendren, α-bergamotene and δ-cadinene and germacrene-D can contribute significantly to some emission profiles (Duhl et al., 2008). To determine the major oxygenated products of sesquiterpenes in SOA, reaction chamber experiments with different sesquiterpenes and ozone were performed in a 100 L reaction chamber. To measure the time dependent formation of initial oxidation products, an APCI-IT-MS was directly connected to the reaction chamber. After 2 hours the APCI-IT-MS was replaced by a

  19. Resolution and Content Improvements to MISR Aerosol and Land Surface Products

    NASA Astrophysics Data System (ADS)

    Garay, M. J.; Bull, M. A.; Diner, D. J.; Hansen, E. G.; Kalashnikova, O. V.

    2015-12-01

    Since early 2000, the Multi-angle Imaging SpectroRadiometer (MISR) instrument on NASA's Terra satellite has been providing operational Level 2 (swath-based) aerosol optical depth (AOD) and particle property retrievals at 17.6 km spatial resolution and atmospherically corrected land surface products at 1.1 km resolution. The performance of the aerosol product has been validated against ground-based Aerosol Robotic Network (AERONET) observations, model comparisons, and climatological assessments. This product has played a major role in studies of the impacts of aerosols on climate and air quality. The surface product has found a variety of uses, particularly at regional scales for assessing vegetation and land surface change. A major development effort has led to the release of an update to the operational (Version 22) MISR Level 2 aerosol and land surface retrieval products, which has been in production since December 2007. The new release is designated Version 23. The resolution of the aerosol product has been increased to 4.4 km, allowing more detailed characterization of aerosol spatial variability, especially near local sources and in urban areas. The product content has been simplified and updated to include more robust measures of retrieval uncertainty and other fields to benefit users. The land surface product has also been updated to incorporate the Version 23 aerosol product as input and to improve spatial coverage, particularly over mountainous terrain and snow/ice-covered surfaces. We will describe the major upgrades incorporated in Version 23 and present validation of the aerosol product against both the standard AERONET historical database, as well as high spatial density AERONET-DRAGON deployments. Comparisons will also be shown relative to the Version 22 aerosol and land surface products. Applications enabled by these product updates will be discussed.

  20. Experimental correlations for transient soot measurement in diesel exhaust aerosol with light extinction, electrical mobility and diffusion charger sensor techniques

    NASA Astrophysics Data System (ADS)

    Bermúdez, Vicente; Pastor, José V.; López, J. Javier; Campos, Daniel

    2014-06-01

    A study of soot measurement deviation using a diffusion charger sensor with three dilution ratios was conducted in order to obtain an optimum setting that can be used to obtain accurate measurements in terms of soot mass emitted by a light-duty diesel engine under transient operating conditions. The paper includes three experimental phases: an experimental validation of the measurement settings in steady-state operating conditions; evaluation of the proposed setting under the New European Driving Cycle; and a study of correlations for different measurement techniques. These correlations provide a reliable tool for estimating soot emission from light extinction measurement or from accumulation particle mode concentration. There are several methods and correlations to estimate soot concentration in the literature but most of them were assessed for steady-state operating points. In this case, the correlations are obtained by more than 4000 points measured in transient conditions. The results of the new two correlations, with less than 4% deviation from the reference measurement, are presented in this paper.

  1. Two MODIS Aerosol Products Over Ocean on the Terra and Aqua CERES SSF Datasets

    NASA Technical Reports Server (NTRS)

    Ignatov, Alexander; Minnis, Patrick; Loeb, Norman; Wielicki, Bruce; Miller, Walter; Sun-Mack, Sunny; Tanre, Didier; Remer, Lorraine; Laszlo, Istvan; Geier, Erika

    2004-01-01

    Over ocean, two aerosol products are reported on the Terra and Aqua CERES SSFs. Both are derived from MODIS, but using different sampling and aerosol algorithms. This study briefly summarizes these products, and compares using 2 weeks of global Terra data from 15-21 December 2000, and 1-7 June 2001.

  2. The Cretaceous-Tertiary boundary marine extinction and global primary productivity collapse

    NASA Technical Reports Server (NTRS)

    Zachos, J. C.; Arthus, M. A.; Dean, W. E.

    1988-01-01

    The extinction of marine phyto-and zoo-plankton across the K-T boundary has been well documented. Such an event may have resulted in decreased photosynthetic fixation of carbon in surface waters and a collapse of the food chain in the marine biosphere. Because the vertical and horizontal distribution of the carbon isotopic composition of total dissolved carton (TDC) in the modern ocean is controlled by the transfer of organic carbon from the surface to deep reservoirs, it follows that a major disruption of the marine biosphere would have had a major effect on the distribution of carbon isotopes in the ocean. Negative carbon isotope excursions have been identified at many marine K-T boundary sequences worldwide and are interpreted as a signal of decreased oceanic primary productivity. However, the magnitude, duration and consequences of this productivity crisis have been poorly constrained. On the basis of planktonic and benthic calcareous microfossil carbon isotope and other geochemical data from DSDP Site 577 located on the Shatsky Rise in the north-central Pacific, as well as other sites, researchers have been able to provide a reasonable estimate of the duration and magnitude of this event.

  3. δ 13C evidence that high primary productivity delayed recovery from end-Permian mass extinction

    NASA Astrophysics Data System (ADS)

    Meyer, K. M.; Yu, M.; Jost, A. B.; Kelley, B. M.; Payne, J. L.

    2011-02-01

    Euxinia was widespread during and after the end-Permian mass extinction and is commonly cited as an explanation for delayed biotic recovery during Early Triassic time. This anoxic, sulfidic episode has been ascribed to both low- and high-productivity states in the marine water column, leaving the causes of euxinia and the mechanisms underlying delayed recovery poorly understood. Here we use isotopic analysis to examine the changing chemical structure of the water column through the recovery interval and thereby better constrain paleoproductivity. The δ 13C of limestones from 5 stratigraphic sections in south China displays a negative gradient of approximately 4‰ from shallow-to-deep water facies within the Lower Triassic. This intense gradient declines within Spathian and lowermost Middle Triassic strata, coincident with accelerated biotic recovery and carbon cycle stabilization. Model simulations show that high nutrient levels and a vigorous biological pump are required to sustain such a large gradient in δ 13C, indicating that Early Triassic ocean anoxia and delayed recovery of benthic animal ecosystems resulted from too much productivity rather than too little.

  4. VIIRS Aerosol Optical Depth (AOD) Products for Air Quality Applications

    NASA Astrophysics Data System (ADS)

    Huff, A. K.; Zhang, H.; Kondragunta, S.; Laszlo, I.

    2014-12-01

    The air quality community uses satellite aerosol optical depth (AOD) for a variety of applications, including daily air quality forecasting, retrospective event analysis, and justification for Exceptional Events. AOD is suitable for ambient air quality applications because is related to particulate matter (e.g., PM2.5) concentrations in the atmosphere; higher values of AOD correspond to higher concentrations of particulate matter. AOD is useful for identifying and tracking areas of high PM2.5 concentrations that correspond to air quality events, such as wildfires, dust storms, or haze episodes. Currently, the air quality community utilizes AOD from the MODIS instrument on NASA's polar-orbiting Terra and Aqua satellites and from NOAA's GOES geostationary satellites (e.g, GASP). The Visible Infrared Imaging Radiometer Suite (VIIRS) instrument on the Suomi-NPP satellite is making AOD measurements that are similar to MODIS AOD, but with higher spatial resolution. Two AOD products are available from VIIRS: the 750 m nadir resolution Intermediate Product (IP) and the 6 km resolution Environmental Data Record (EDR) product, which is aggregated from IP measurements. These VIIRS AOD products offer a substantial increase in spatial resolution compared to the MODIS AOD 3 km and 10 km AOD products, respectively. True color (RGB) imagery is also available from VIIRS as a decision aid for air quality applications. It serves as a complement to AOD measurements by providing visible information about areas of smoke, haze, and blowing dust in the atmosphere. Case studies of VIIRS AOD and RGB data for recent air quality events will be presented, with a focus on wildfires, and the relative pros and cons of the VIIRS AOD IP and EDR for air quality applications will be discussed in comparison to MODIS AOD products. Improvements to VIIRS aerosol products based on user feedback as part of the NOAA Satellite Air Quality Proving Ground (AQPG) will be outlined, and an overview of future

  5. Influence of anthropogenic aerosol deposition on the relationship between oceanic productivity and warming

    NASA Astrophysics Data System (ADS)

    Wang, Rong; Balkanski, Yves; Bopp, Laurent; Aumont, Olivier; Boucher, Olivier; Ciais, Philippe; Gehlen, Marion; Peñuelas, Josep; Ethé, Christian; Hauglustaine, Didier; Li, Bengang; Liu, Junfeng; Zhou, Feng; Tao, Shu

    2015-12-01

    Satellite data and models suggest that oceanic productivity is reduced in response to less nutrient supply under warming. In contrast, anthropogenic aerosols provide nutrients and exert a fertilizing effect, but its contribution to evolution of oceanic productivity is unknown. We simulate the response of oceanic biogeochemistry to anthropogenic aerosols deposition under varying climate from 1850 to 2010. We find a positive response of observed chlorophyll to deposition of anthropogenic aerosols. Our results suggest that anthropogenic aerosols reduce the sensitivity of oceanic productivity to warming from -15.2 ± 1.8 to -13.3 ± 1.6 Pg C yr-1 °C-1 in global stratified oceans during 1948-2007. The reducing percentage over the North Atlantic, North Pacific, and Indian Oceans reaches 40, 24, and 25%, respectively. We hypothesize that inevitable reduction of aerosol emissions in response to higher air quality standards in the future might accelerate the decline of oceanic productivity per unit warming.

  6. Effect of the composition of the hot product stream in the quasi-steady extinction of strained premixed flames

    SciTech Connect

    Coriton, Bruno; Smooke, Mitchell D.; Gomez, Alessandro

    2010-11-15

    The extinction of premixed CH{sub 4}/O{sub 2}/N{sub 2} flames counterflowing against a jet of combustion products in chemical equilibrium was investigated numerically using detailed chemistry and transport mechanisms. Such a problem is of relevance to combustion systems with non-homogeneous air/fuel mixtures or recirculation of the burnt gases. Contrary to similar studies that were focused on heat loss/gain, depending on the degree of non-adiabaticity of the system, the emphasis here was on the yet unexplored role of the composition of counterflowing burnt gases in the extinction of lean-to-stoichiometric premixed flames. For a given temperature of the counterflowing products of combustion, it was found that the decrease of heat release with increase in strain rate could be either monotonic or non-monotonic, depending on the equivalence ratio {phi}{sub b} of the flame feeding the hot combustion product stream. Two distinct extinction modes were observed: an abrupt one, when the hot counterflowing stream consists of either inert gas or equilibrium products of a stoichiometric premixed flame, and a smooth extinction, when there is an excess of oxidizing species in the combustion product stream. In the latter case four burning regimes can be distinguished as the strain rate is progressively increased while the heat release decreases smoothly: an adiabatic propagating flame regime, a non-adiabatic propagating flame regime, the so-called partially-extinguished flame regime, in which the location of the peak of heat release crosses the stagnation plane, and a frozen flow regime. The flame structure was analyzed in detail in the different burning regimes. Abrupt extinction was attributed to the quenching of the oxidation layer with the entire H-OH-O radical pool being comparably reduced. Under conditions of smooth extinction, the behavior is different and the concentration of the H radical decreases the most with increasing strain rate, whereas OH and O remain

  7. Inversion of tropospheric profiles of aerosol extinction and HCHO and NO2 mixing ratios from MAX-DOAS observations in Milano during the summer of 2003 and comparison with independent data sets

    NASA Astrophysics Data System (ADS)

    Wagner, T.; Beirle, S.; Brauers, T.; Deutschmann, T.; Frieß, U.; Hak, C.; Halla, J. D.; Heue, K. P.; Junkermann, W.; Li, X.; Platt, U.; Pundt-Gruber, I.

    2011-12-01

    We present aerosol and trace gas profiles derived from MAX-DOAS observations. Our inversion scheme is based on simple profile parameterisations used as input for an atmospheric radiative transfer model (forward model). From a least squares fit of the forward model to the MAX-DOAS measurements, two profile parameters are retrieved including integrated quantities (aerosol optical depth or trace gas vertical column density), and parameters describing the height and shape of the respective profiles. From these results, the aerosol extinction and trace gas mixing ratios can also be calculated. We apply the profile inversion to MAX-DOAS observations during a measurement campaign in Milano, Italy, September 2003, which allowed simultaneous observations from three telescopes (directed to north, west, south). Profile inversions for aerosols and trace gases were possible on 23 days. Especially in the middle of the campaign (17-20 September 2003), enhanced values of aerosol optical depth and NO2 and HCHO mixing ratios were found. The retrieved layer heights were typically similar for HCHO and aerosols. For NO2, lower layer heights were found, which increased during the day. The MAX-DOAS inversion results are compared to independent measurements: (1) aerosol optical depth measured at an AERONET station at Ispra; (2) near-surface NO2 and HCHO (formaldehyde) mixing ratios measured by long path DOAS and Hantzsch instruments at Bresso; (3) vertical profiles of HCHO and aerosols measured by an ultra light aircraft. Depending on the viewing direction, the aerosol optical depths from MAX-DOAS are either smaller or larger than those from AERONET observations. Similar comparison results are found for the MAX-DOAS NO2 mixing ratios versus long path DOAS measurements. In contrast, the MAX-DOAS HCHO mixing ratios are generally higher than those from long path DOAS or Hantzsch instruments. The comparison of the HCHO and aerosol profiles from the aircraft showed reasonable agreement with

  8. Inversion of tropospheric profiles of aerosol extinction and HCHO and NO2 mixing ratios from MAX-DOAS observations in Milano during the summer of 2003 and comparison with independent data sets

    NASA Astrophysics Data System (ADS)

    Wagner, T.; Beirle, S.; Brauers, T.; Deutschmann, T.; Frieß, U.; Hak, C.; Halla, J. D.; Heue, K. P.; Junkermann, W.; Li, X.; Platt, U.; Pundt-Gruber, I.

    2011-06-01

    We present aerosol and trace gas profiles derived from MAX-DOAS observations. Our inversion scheme is based on simple profile parameterisations used as input for an atmospheric radiative transfer model (forward model). From a least squares fit of the forward model to the MAX-DOAS measurements, two profile parameters are retrieved including integrated quantities (aerosol optical depth or trace gas vertical column density), and parameters describing the height and shape of the respective profiles. From these results, the aerosol extinction and trace gas mixing ratios can also be calculated. We apply the profile inversion to MAX-DOAS observations during a measurement campaign in Milano, Italy, September 2003, which allowed simultaneous observations from three telescopes (directed to north, west, south). Profile inversions for aerosols and trace gases were possible on 23 days. Especially in the middle of the campaign (17-20 September 2003), enhanced values of aerosol optical depth and NO2 and HCHO mixing ratios were found. The retrieved layer heights were typically similar for HCHO and aerosols. For NO2, lower layer heights were found, which increased during the day. The MAX-DOAS inversion results are compared to independent measurements: (1) aerosol optical depth measured at an AERONET station at Ispra; (2) near-surface NO2 and HCHO (formaldehyde) mixing ratios measured by long path DOAS and Hantzsch instruments at Bresso; (3) vertical profiles of HCHO and aerosols measured by an ultra light aircraft. Depending on the viewing direction, the aerosol optical depths from MAX-DOAS are either smaller or larger than those from AERONET observations. Similar comparison results are found for the MAX-DOAS NO2 mixing ratios versus long path DOAS measurements. In contrast, the MAX-DOAS HCHO mixing ratios are generally higher than those from long path DOAS or Hantzsch instruments. The comparison of the HCHO and aerosol profiles from the aircraft showed reasonable agreement with

  9. A model for the separation of cloud and aerosol in SAGE II occultation data

    NASA Technical Reports Server (NTRS)

    Kent, G. S.; Winker, D. M.; Osborn, M. T.; Skeens, K. M.

    1993-01-01

    The Stratospheric Aerosol and Gas Experiment (SAGE) II satellite experiment measures the extinction due to aerosols and thin cloud, at wavelengths of 0.525 and 1.02 micrometers, down to an altitude of 6 km. The wavelength dependence of the extinction due to aerosols differs from that of the extinction due to cloud and is used as the basis of a model for separating these two components. The model is presented and its validation using airborne lidar data, obtained coincident with SAGE II observations, is described. This comparison shows that smaller SAGE II cloud extinction values correspond to the presence of subvisible cirrus cloud in the lidar record. Examples of aerosol and cloud data products obtained using this model to interpret SAGE II upper tropospheric and lower stratospheric data are also shown.

  10. Bryozoan paleoecology indicates mid-Phanerozoic extinctions were the product of long-term environmental stress

    NASA Astrophysics Data System (ADS)

    Powers, Catherine M.; Bottjer, David J.

    2007-11-01

    We compiled the global onshore-offshore distribution of marine bryozoans within 396 Permian-Early Jurassic bryozoan assemblages and show that bryozoan assemblage generic richness declined significantly in advance of the end-Permian and end-Triassic mass extinctions, starting as early as the Capitanian prior to the end-Permian and the Norian prior to the end-Triassic. We also show that offshore settings were affected first, prior to both extinctions, suggesting that environmental stress resulted from the gradual encroachment of some deep-water phenomenon onto the shelves. These patterns support long-term oceanographic, rather than extraterrestrial, extinction mechanisms, such as widespread euxinia triggered by massive volcanism and global warming. Tracking the onshore-offshore environmental distribution of these marine invertebrates provides a unique approach to assessing prolonged environmentally induced stress through this ˜120 m.y. time interval.

  11. [Characteristics and Parameterization for Atmospheric Extinction Coefficient in Beijing].

    PubMed

    Chen, Yi-na; Zhao, Pu-sheng; He, Di; Dong, Fan; Zhao, Xiu-juan; Zhang, Xiao-ling

    2015-10-01

    In order to study the characteristics of atmospheric extinction coefficient in Beijing, systematic measurements had been carried out for atmospheric visibility, PM2.5 concentration, scattering coefficient, black carbon, reactive gases, and meteorological parameters from 2013 to 2014. Based on these data, we compared some published fitting schemes of aerosol light scattering enhancement factor [ f(RH)], and discussed the characteristics and the key influence factors for atmospheric extinction coefficient. Then a set of parameterization models of atmospheric extinction coefficient for different seasons and different polluted levels had been established. The results showed that aerosol scattering accounted for more than 94% of total light extinction. In the summer and autumn, the aerosol hygroscopic growth caused by high relative humidity had increased the aerosol scattering coefficient by 70 to 80 percent. The parameterization models could reflect the influencing mechanism of aerosol and relative humidity upon ambient light extinction, and describe the seasonal variations of aerosol light extinction ability. PMID:26841588

  12. Comparison of Aerosol Classification from Airborne High Spectral Resolution Lidar and the CALIPSO Vertical Feature Mask

    NASA Astrophysics Data System (ADS)

    Burton, S. P.; Ferrare, R. A.; Omar, A. H.; Hostetler, C. A.; Hair, J. W.; Rogers, R.; Obland, M. D.; Butler, C. F.; Cook, A. L.; Harper, D. B.

    2012-12-01

    The NASA Langley Research Center (LaRC) airborne High Spectral Resolution Lidar (HSRL-1) on the NASA B200 aircraft has acquired large datasets of aerosol extinction (532nm), backscatter (532 and 1064nm), and depolarization (532 and 1064nm) profiles during 349 science flights in 19 field missions across North America since 2006. The extinction-to-backscatter ratio ("lidar ratio"), aerosol depolarization ratios, and backscatter color ratio measurements from HSRL-1 are scale-invariant parameters that depend on aerosol type but not concentration. These four aerosol intensive parameters are combined to qualitatively classify HSRL aerosol measurements into eight separate composition types. The classification methodology uses models formed from "training cases" with known aerosol type. The remaining measurements are then compared with these models using the Mahalanobis distance. Aerosol products from the CALIPSO satellite include aerosol type information as well, which is used as input to the CALIPSO aerosol retrieval. CALIPSO aerosol types are inferred using a mix of aerosol loading-dependent parameters, estimated aerosol depolarization, and location, altitude, and surface type information. The HSRL instrument flies beneath the CALIPSO satellite orbit track, presenting the opportunity for comparisons between the HSRL aerosol typing and the CALIPSO Vertical Feature Mask Aerosol Subtype product, giving insight into the performance of the CALIPSO aerosol type algorithm. We find that the aerosol classification from the two instruments frequently agree for marine aerosols and pure dust, and somewhat less frequently for pollution and smoke. In addition, the comparison suggests that the CALIPSO polluted dust type is overly inclusive, encompassing cases of dust combined with marine aerosol as well as cases without much evidence of dust. Qualitative classification of aerosol type combined with quantitative profile measurements of aerosol backscatter and extinction has many useful

  13. Occupational exposure to inhalable and total aerosol in the primary nickel production industry.

    PubMed Central

    Tsai, P J; Vincent, J H; Wahl, G; Maldonado, G

    1995-01-01

    OBJECTIVES--This paper describes a study that was carried out in the primary nickel production industry to investigate the levels of personal exposure to aerosols containing nickel and the impact on exposure assessment of introducing new personal sampling techniques with performance consistent with the latest particle size-selective criteria. METHODS--Experiments were carried out at workplaces in mining, milling, smelting, and refining works to investigate the effect of changing from the current method of total aerosol (with the widely used 37 mm filter holder) to the new method of measuring inhalable aerosol (with the Institute of Occupational Medicine (IOM) inhalable aerosol sampler). RESULTS--The results show that inhalable aerosol exposure concentrations--for both overall aerosol and for total nickel--were consistently and significantly higher than the corresponding total aerosol concentrations. Weighted least squares linear regression yielded IOM/37 mm factors ranging from about 1.2 to 4.0. The exposure data for each company process were found to be log-normally distributed. CONCLUSIONS--The results suggest the possibility of generating a single pragmatic factor for each company process for converting current total aerosol exposures to new exposures based on the inhalability concept contained in the latest particle size-selective criteria for aerosol exposure assessment. Such data may be important in determining new occupational exposure limits for nickel. PMID:8563841

  14. MODIS 3 Km Aerosol Product: Applications over Land in an Urban/suburban Region

    NASA Technical Reports Server (NTRS)

    Munchak, L. A.; Levy, R. C.; Mattoo, S.; Remer, L. A.; Holben, B. N.; Schafer, J. S.; Hostetler, C. A.; Ferrare, R. A.

    2013-01-01

    MODerate resolution Imaging Spectroradiometer (MODIS) instruments aboard the Terra and Aqua satellites have provided a rich dataset of aerosol information at a 10 km spatial scale. Although originally intended for climate applications, the air quality community quickly became interested in using the MODIS aerosol data. However, 10 km resolution is not sufficient to resolve local scale aerosol features. With this in mind, MODIS Collection 6 is including a global aerosol product with a 3 km resolution. Here, we evaluate the 3 km product over the Baltimore/Washington D.C., USA, corridor during the summer of 2011, by comparing with spatially dense data collected as part of the DISCOVER-AQ campaign these data were measured by the NASA Langley Research Center airborne High Spectral Resolution Lidar (HSRL) and a network of 44 sun photometers (SP) spaced approximately 10 km apart. The HSRL instrument shows that AOD can vary by up to 0.2 within a single 10 km MODIS pixel, meaning that higher resolution satellite retrievals may help to characterize aerosol spatial distributions in this region. Different techniques for validating a high-resolution aerosol product against SP measurements are considered. Although the 10 km product is more statistically reliable than the 3 km product, the 3 km product still performs acceptably, with more than two-thirds of MODIS/SP collocations falling within the expected error envelope with high correlation (R > 0.90). The 3 km product can better resolve aerosol gradients and retrieve closer to clouds and shorelines than the 10 km product, but tends to show more significant noise especially in urban areas. This urban degradation is quantified using ancillary land cover data. Overall, we show that the MODIS 3 km product adds new information to the existing set of satellite derived aerosol products and validates well over the region, but due to noise and problems in urban areas, should be treated with some degree of caution.

  15. The global 3-D distribution of tropospheric aerosols as characterized by CALIOP

    NASA Astrophysics Data System (ADS)

    Winker, D. M.; Tackett, J. L.; Getzewich, B. J.; Liu, Z.; Vaughan, M. A.; Rogers, R. R.

    2013-03-01

    The CALIOP lidar, carried on the CALIPSO satellite, has been acquiring global atmospheric profiles since June 2006. This dataset now offers the opportunity to characterize the global 3-D distribution of aerosol as well as seasonal and interannual variations, and confront aerosol models with observations in a way that has not been possible before. With that goal in mind, a monthly global gridded dataset of daytime and nighttime aerosol extinction profiles has been constructed, available as a Level 3 aerosol product. Averaged aerosol profiles for cloud-free and all-sky conditions are reported separately. This 6-yr dataset characterizes the global 3-dimensional distribution of tropospheric aerosol. Vertical distributions are seen to vary with season, as both source strengths and transport mechanisms vary. In most regions, clear-sky and all-sky mean aerosol profiles are found to be quite similar, implying a lack of correlation between high semi-transparent cloud and aerosol in the lower troposphere. An initial evaluation of the accuracy of the aerosol extinction profiles is presented. Detection limitations and the representivity of aerosol profiles in the upper troposphere are of particular concern. While results are preliminary, we present evidence that the monthly-mean CALIOP aerosol profiles provide quantitative characterization of elevated aerosol layers in major transport pathways. Aerosol extinction in the free troposphere in clean conditions, where the true aerosol extinction is typically 0.001 km-1 or less, is generally underestimated, however. The work described here forms an initial global 3-D aerosol climatology which we plan to extend and improve over time.

  16. Aerosols and their influence on radiation partitioning and savanna productivity in northern Australia

    SciTech Connect

    Kanniah, K. D.; Beringer, J.; Tapper, N. J.; Long, Charles N.

    2010-05-01

    We investigated the effect of aerosols and clouds on the Net Ecosystem Productivity (NEP) of savannas in northern Australia using aerosol optical depth, clouds and radiation data from the Atmospheric Radiation Measurement (ARM) site in Darwin and carbon flux data measured from eddy covariance techniques from a site at Howard Springs, 35km southeast of Darwin. Generally we found that the concentration of aerosols in this region was relatively low than observed at other sites, therefore the proportion of diffuse radiation reaching the earths surface was only ~ 30%. As a result, we observed only a modest change in carbon uptake under aerosol laden skies and there was no significant difference for dry season Radiation Use Efficiency (RUE) between clear sky, aerosols or thin clouds. On the other hand thick clouds in the wet season produce much more diffuse radiation than aerosols or thin clouds and therefore the initial canopy quantum efficiency was seen to increase 45 and 2.5 times more than under thin clouds and aerosols respectively. The normalized carbon uptake under thick clouds is 57% and 50% higher than under aerosols and thin clouds respectively even though the total irradiance received under thick clouds was reduced 59% and 50% than under aerosols and thin clouds respectively. However, reduction in total irradiance decreases the mean absolute carbon uptake as much as 22% under heavy cloud cover compared to thin clouds or aerosols. Thus, any increase in aerosol concentration or cloud cover that can enhance the diffuse component may have large impacts on productivity in this region.

  17. Inter-comparison of MAX-DOAS Retrieved Vertical Profiles of Aerosol Extinction, SO2 and NO2 in the Alberta Oil Sands with LIDAR Data and GEM-MACH Air Quality Model.

    NASA Astrophysics Data System (ADS)

    Davis, Zoe; Friess, Udo; Strawbridge, Kevin; Whiteway, James; Aggarwal, Monika; Makar, Paul; Li, Shao-Meng; O'Brien, Jason; Baray, Sabour; Schnitzler, Elijah; Olfert, Jason S.; Osthoff, Hans D.; Lobo, Akshay; McLaren, Robert

    2016-04-01

    Understanding industrial emissions of trace gas pollutants in the Alberta oil sands is essential to maintaining air quality standards and informing public policy. Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of trace gases can improve knowledge of pollutant levels, vertical distribution and chemical transformation. During an intensive air measurement campaign to study emissions, transport, transformation and deposition of oil sands air pollutants from August to September of 2013, a MAX-DOAS instrument was deployed at a site north of Fort McMurray, Alberta to determine the vertical profiles of aerosol extinction, NO2 and SO2 through retrieval from the MAX-DOAS spectral measurements using an optimal estimation method. The large complement of data collected from multiple instruments deployed during this field campaign provides a unique opportunity to validate and characterize the performance of the MAX-DOAS vertical profile retrievals. Aerosol extinction profiles determined from two Light Detection and Ranging (LIDAR) instruments, one collocated and the other on a Twin Otter aircraft that flew over the site during the study, will be compared to the MAX-DOAS aerosol extinction profile retrievals. Vertical profiles of NO2 and SO2 retrieved from the MAX-DOAS measurements will be further compared with the composite vertical profiles measured from the flights of a second aircraft, the NRC-Convair 580, over the field site during the same measurement period. Finally, the MAX-DOAS retrieved tropospheric vertical column densities (VCDs) of SO2 and NO2 will be compared to the predicted VCDs from Environment and Climate Change Canada's Global Environmental Multi-scale - Modelling Air quality and Chemistry (GEM-MACH) air quality model over the grid cell containing the field site. Emission estimates of SO2 from the major oil mining facility Syncrude Mildred Lake using the MAX-DOAS VCD results, validated through the detailed characterization above

  18. Aerosol Optical Depth Value-Added Product Report

    SciTech Connect

    Koontz, A; Hodges, G; Barnard, J; Flynn, C; Michalsky, J

    2013-03-17

    This document describes the process applied to retrieve aerosol optical depth (AOD) from multifilter rotating shadowband radiometers (MFRSR) and normal incidence multifilter radiometers (NIMFR) operated at the ARM Climate Research Facility’s ground-based facilities.

  19. Controls on aerosol wet deposition from satellite-based (re-)analysis products

    NASA Astrophysics Data System (ADS)

    Chuang, P. Y.

    2015-12-01

    Aerosol wet deposition is the key aerosol loss mechanism globally, yet is not well-understood relative to aerosol sources and transformations. The difficulty in generating appropriate observational data sets is one important barrier to the study of aerosol wet removal. In this study, we combine two independent products based on satellite measurements. Aerosol optical depth (AOD) is obtained from the ECMWF Monitoring Atmospheric Composition and Climate (MACC) project, which is a re-analysis product that assimilates MODIS-retrieved aerosol optical depth. Rainfall is obtained from the Tropical Rainfall Measurement Mission (TRMM) Multi-satellite Precipitation Analysis version 7 (TMPA-7). The latter product is available only from 50°N to 50°S, which sets our region of study. The data used is from 2011-12, is averaged to 6-hr intervals and has a horizontal resolution of 0.25°x0.25°. Our approach involves constructing a Lagrangian advection scheme that predicts aerosol AOD at the next time step (i.e. 6 hr in the future) based on current time step AOD and winds, and neglecting all aerosol sources and sinks. Predicted AOD is then compared with MACC reanalysis AOD conditioned on Lagrangian parcels that experienced rainfall during that interval, with AOD decreases attributed to wet deposition. Aerosol wet deposition is often parameterized in models as a function of rainfall rate using a power law. We evaluate the validity of such a power law relationship, and, when valid, compute the power law exponent globally, and by region (including continental and maritime locations) to reveal seasonal and geographic variability. Assuming precipitation is modulated by aerosol, at least in some regimes, then it follows that wet deposition also depends on AOD, and we quantify the strength of this coupling. This same approach could be used to study wet deposition of trace gases such as CO and ozone, as these are also available from the MACC re-analysis.

  20. Characterization of particulate products for aging of ethylbenzene secondary organic aerosol in the presence of ammonium sulfate seed aerosol.

    PubMed

    Huang, Mingqiang; Zhang, Jiahui; Cai, Shunyou; Liao, Yingmin; Zhao, Weixiong; Hu, Changjin; Gu, Xuejun; Fang, Li; Zhang, Weijun

    2016-09-01

    Aging of secondary organic aerosol (SOA) particles formed from OH- initiated oxidation of ethylbenzene in the presence of high mass (100-300μg/m(3)) concentrations of (NH4)2SO4 seed aerosol was investigated in a home-made smog chamber in this study. The chemical composition of aged ethylbenzene SOA particles was measured using an aerosol laser time-of-flight mass spectrometer (ALTOFMS) coupled with a Fuzzy C-Means (FCM) clustering algorithm. Experimental results showed that nitrophenol, ethyl-nitrophenol, 2,4-dinitrophenol, methyl glyoxylic acid, 5-ethyl-6-oxo-2,4-hexadienoic acid, 2-ethyl-2,4-hexadiendioic acid, 2,3-dihydroxy-5-ethyl-6-oxo-4-hexenoic acid, 1H-imidazole, hydrated N-glyoxal substituted 1H-imidazole, hydrated glyoxal dimer substituted imidazole, 1H-imidazole-2-carbaldehyde, N-glyoxal substituted hydrated 1H-imidazole-2-carbaldehyde and high-molecular-weight (HMW) components were the predominant products in the aged particles. Compared to the previous aromatic SOA aging studies, imidazole compounds, which can absorb solar radiation effectively, were newly detected in aged ethylbenzene SOA in the presence of high concentrations of (NH4)2SO4 seed aerosol. These findings provide new information for discussing aromatic SOA aging mechanisms. PMID:27593289

  1. Air Quality Monitoring and Forecasting Applications of Suomi NPP VIIRS Aerosol Products

    NASA Astrophysics Data System (ADS)

    Kondragunta, Shobha

    The Suomi National Polar-orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) instrument was launched on October 28, 2011. It provides Aerosol Optical Thickness (AOT) at two different spatial resolutions: a pixel level (~750 m at nadir) product called the Intermediate Product (IP) and an aggregated (~6 km at nadir) product called the Environmental Data Record (EDR), and a Suspended Matter (SM) EDR that provides aerosol type (dust, smoke, sea salt, and volcanic ash) information. An extensive validation of VIIRS best quality aerosol products with ground based L1.5 Aerosol Robotic NETwork (AERONET) data shows that the AOT EDR product has an accuracy/precision of -0.01/0.11 and 0.01/0.08 over land and ocean respectively. Globally, VIIRS mean AOT EDR (0.20) is similar to Aqua MODIS (0.16) with some important regional and seasonal differences. The accuracy of the SM product, however, is found to be very low (20 percent) when compared to Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) and AERONET. Several algorithm updates which include a better approach to retrieve surface reflectance have been developed for AOT retrieval. For dust aerosol type retrieval, a new approach that takes advantage of spectral dependence of Rayleigh scattering, surface reflectance, dust absorption in the deep blue (412 nm), blue (440 nm), and mid-IR (2.2 um) has been developed that detects dust with an accuracy of ~80 percent. For smoke plume identification, a source apportionment algorithm that combines fire hot spots with AOT imagery has been developed that provides smoke plume extent with an accuracy of ~70 percent. The VIIRS aerosol products will provide continuity to the current operational use of aerosol products from Aqua and Terra MODIS. These include aerosol data assimilation in Naval Research Laboratory (NRL) global aerosol model, verification of National Weather Service (NWS) dust and smoke forecasts, exceptional events monitoring by different states

  2. MODIS aerosol products in Collection 6:Moving towards multisensor fusion and interdisciplinary studies

    NASA Astrophysics Data System (ADS)

    Mattoo, S.; Levy, R. C.; Remer, L. A.

    2009-12-01

    As the Terra satellite turns 10, so do the MODIS aerosol products. During the past ten years the MODIS products have evolved and expanded to include opportunities and capabilities nonexistent in the at-launch version. We are anticipating the next step, Collection 6, becoming available in late 2010. The new products in the Collection 6 MODIS aerosol suite of products will include: 1) Fine mode aerosol optical depth over land from the PARASOL POLDER data set, merged into the MODIS data product. This is a direct capture of the PARASOL product that will be placed in the MODIS data files. It is not a separate derivation using PARASOL radiances and polarization. The incorporation of the PARASOL product over land is collocated to the MODIS 10 km product pixel, and is provided as a convenience to MODIS users. 2) Aerosol optical depth over land at 3 km resolution for Air Quality monitoring. 3) Cloud mask and distance to the nearest cloud calculated and presented for every 500 m “cloud-free” pixel that allows better control of cloud contamination in the basic aerosol products. This information is also summarized statistically at the 10 km product resolution, and will be available for both land and ocean. 4) A Quality Assurance (QA) flag in simple plain integers that does not require a binary reader to decode.

  3. Fission product partitioning in aerosol release from simulated spent nuclear fuel

    NASA Astrophysics Data System (ADS)

    Di Lemma, F. G.; Colle, J. Y.; Rasmussen, G.; Konings, R. J. M.

    2015-10-01

    Aerosols created by the vaporization of simulated spent nuclear fuel (simfuel) were produced by laser heating techniques and characterised by a wide range of post-analyses. In particular attention has been focused on determining the fission product behaviour in the aerosols, in order to improve the evaluation of the source term and consequently the risk associated with release from spent fuel sabotage or accidents. Different simulated spent fuels were tested with burn-up up to 8 at. %. The results from the aerosol characterisation were compared with studies of the vaporization process by Knudsen Effusion Mass Spectrometry and thermochemical equilibrium calculations. These studies permit an understanding of the aerosol gaseous precursors and the gaseous reactions taking place during the aerosol formation process.

  4. The Remote Sensing of Mineral Aerosols and their Impact on Phytoplankton Productivity

    NASA Technical Reports Server (NTRS)

    Tindale, Neil W.

    1997-01-01

    The overall objective of this experiment was to test the iron hypothesis does the addition of iron to nutrient rich surface waters enhance productivity? Our specific objectives in this experiment included sampling and studying the marine aerosol size and type (which are related to chemical reactivity) during the PlumEx cruise to determine the importance of local (Galapagos Islands) versus long-range sources of atmospheric material. Detailed results of single particle analysis of our samples are being prepared for publication in two papers. We collect aerosol samples and they have been analyzed for trace metals and other elements. We are mapped aerosol distribution and the desert source areas around the Arabian Sea region. We did record a clear relationship between the aerosol radiance and synoptic weather patterns with distinct signals over the ocean northwest and southwest of Australia. While the interpretation was limited an aerosol climatology pattern was presented.

  5. Series cell light extinction monitor

    DOEpatents

    Novick, Vincent J.

    1990-01-01

    A method and apparatus for using the light extinction measurements from two or more light cells positioned along a gasflow chamber in which the gas volumetric rate is known to determine particle number concentration and mass concentration of an aerosol independent of extinction coefficient and to determine estimates for particle size and mass concentrations. The invention is independent of particle size. This invention has application to measurements made during a severe nuclear reactor fuel damage test.

  6. SAGE II Measurements of Stratospheric Aerosol Properties at Non-Volcanic Levels

    NASA Technical Reports Server (NTRS)

    Thomason, Larry W.; Burton, Sharon P.; Luo, Bei-Ping; Peter, Thomas

    2008-01-01

    Since 2000, stratospheric aerosol levels have been relatively stable and at the lowest levels observed in the historical record. Given the challenges of making satellite measurements of aerosol properties at these levels, we have performed a study of the sensitivity of the product to the major components of the processing algorithm used in the production of SAGE II aerosol extinction measurements and the retrieval process that produces the operational surface area density (SAD) product. We find that the aerosol extinction measurements, particularly at 1020 nm, remain robust and reliable at the observed aerosol levels. On the other hand, during background periods, the SAD operational product has an uncertainty of at least a factor of 2 during due to the lack of sensitivity to particles with radii less than 100 nm.

  7. Development and Applications of a New, High-Resolution, Operational MISR Aerosol Product

    NASA Astrophysics Data System (ADS)

    Garay, M. J.; Diner, D. J.; Kalashnikova, O.

    2014-12-01

    Since early 2000, the Multi-angle Imaging SpectroRadiometer (MISR) instrument on NASA's Terra satellite has been providing aerosol optical depth (AOD) and particle property retrievals at 17.6 km spatial resolution. Capitalizing on the capabilities provided by multi-angle viewing, the operational MISR algorithm performs well, with about 75% of MISR AOD retrievals falling within 0.05 or 20% × AOD of the paired validation data from the ground-based Aerosol Robotic Network (AERONET), and is able to distinguish aerosol particles by size and sphericity, over both land and water. These attributes enable a variety of applications, including aerosol transport model validation and global air quality assessment. Motivated by the adverse impacts of aerosols on human health at the local level, and taking advantage of computational speed advances that have occurred since the launch of Terra, we have implemented an operational MISR aerosol product with 4.4 km spatial resolution that maintains, and sometimes improves upon, the quality of the 17.6 km resolution product. We will describe the performance of this product relative to the heritage 17.6 km product, the global AERONET validation network, and high spatial density AERONET-DRAGON sites. Other changes that simplify product content, and make working with the data much easier for users, will also be discussed. Examples of how the new product demonstrates finer spatial variability of aerosol fields than previously retrieved, and ways this new dataset can be used for studies of local aerosol effects, will be shown.

  8. Products of BVOC oxidation: ozone and organic aerosols

    NASA Astrophysics Data System (ADS)

    Wildt, Jürgen; Andres, Stefanie; Carriero, Giulia; Ehn, Mikael; Fares, Silvano; Hoffmann, Thorsten; Hacker, Lina; Kiendler-Scharr, Astrid; Kleist, Einhard; Paoletti, Elena; Pullinen, Iida; Rohrer, Franz; Rudich, Yinon; Springer, Monika; Tillmann, Ralf; Wahner, Andreas; Wu, Cheng; Mentel, Thomas

    2015-04-01

    Biogenic Volatile Organic Compounds (BVOC) are important precursors in photochemical O3 and secondary organic aerosol (SOA) formation. We conducted a series of laboratory experiments with OH-induced oxidation of monoterpenes to elucidate pathways and efficiencies of O3 and SOA formation. At high NOx conditions ([BVOC] / [NOx] < 7 ppbC / ppb) photochemical ozone formation was observed. For -pinene as individual BVOC as well as for the monoterpene mixes emitted from different plant species we observed increasing ozone formation with increasing [NOX]. Between 2 and 3 O3-molecules were formed from 1 monoterpene when ozone formation was BVOC limited. Under such high NOX conditions, new particle formation was suppressed. Increasing [BVOC] / [NOX] ratios caused increasing efficiency of new particle formation indicating that peroxy radicals are the key intermediates in both, photochemical ozone- and new particle formation. The classical chemistry of peroxy radicals is well established (e.g. Master Chemical Mechanism). Peroxy radicals are produced by addition of molecular oxygen to the alkyl radical formed after OH attack at the BVOC. They either react with NO which leads to ozone formation or they react with other peroxy radicals and form chemically stable products (hydroperoxides, alkoholes and ketones). Much less knowledge exists on such reactions for Highly Oxidized Peroxy Radicals, (HOPR). Such HOPR were observed during ozonolysis of several volatiles and, in case of monoterpenes as precursors, they can contain more than 12 Oxygen atoms (Mentel et al., 2015). Although the OH-initiated formation of HOPR is yet not fully understood, their basic gas phase reactions seem to follow classical photochemical rules. In reactions with NO they can act as precursor for O3 and in reactions with other HOPR or with classical less oxidized peroxy radicals they can form highly oxidized stable products and alkoxy radicals. In addition, HOPR-HOPR reactions lead to the formation of

  9. Aerosol Production from Charbroiled and Wet-Fried Meats

    NASA Astrophysics Data System (ADS)

    Niedziela, R. F.; Blanc, L. E.

    2012-12-01

    Previous work in our laboratory focused on the chemical and optical characterization of aerosols produced during the dry-frying of different meat samples. This method yielded a complex ensemble of particles composed of water and long-chain fatty acids with the latter dominated by oleic, stearic, and palmitic acids. The present study examines how wet-frying and charbroiling cooking methods affect the physical and chemical properties of their derived aerosols. Samples of ground beef, salmon, chicken, and pork were subject to both cooking methods in the laboratory, with their respective aerosols swept into a laminar flow cell where they were optically analyzed in the mid-infrared and collected through a gas chromatography probe for chemical characterization. This presentation will compare and contrast the nature of the aerosols generated in each cooking method, particularly those produced during charbroiling which exposes the samples, and their drippings, to significantly higher temperatures. Characterization of such cooking-related aerosols is important because of the potential impact of these particles on air quality, particularly in urban areas.

  10. Rethinking Extinction.

    PubMed

    Dunsmoor, Joseph E; Niv, Yael; Daw, Nathaniel; Phelps, Elizabeth A

    2015-10-01

    Extinction serves as the leading theoretical framework and experimental model to describe how learned behaviors diminish through absence of anticipated reinforcement. In the past decade, extinction has moved beyond the realm of associative learning theory and behavioral experimentation in animals and has become a topic of considerable interest in the neuroscience of learning, memory, and emotion. Here, we review research and theories of extinction, both as a learning process and as a behavioral technique, and consider whether traditional understandings warrant a re-examination. We discuss the neurobiology, cognitive factors, and major computational theories, and revisit the predominant view that extinction results in new learning that interferes with expression of the original memory. Additionally, we reconsider the limitations of extinction as a technique to prevent the relapse of maladaptive behavior and discuss novel approaches, informed by contemporary theoretical advances, that augment traditional extinction methods to target and potentially alter maladaptive memories. PMID:26447572

  11. Production Mechanism, Number Concentration, Size Distribution, Chemical Composition, and Optical Properties of Sea Spray Aerosols Workshop, Summer 2012

    SciTech Connect

    Meskhidze, Nicholas

    2013-10-21

    The objective of this workshop was to address the most urgent open science questions for improved quantification of sea spray aerosol-radiation-climate interactions. Sea spray emission and its influence on global climate remains one of the most uncertain components of the aerosol-radiation-climate problem, but has received less attention than other aerosol processes (e.g. production of terrestrial secondary organic aerosols). Thus, the special emphasis was placed on the production flux of sea spray aerosol particles, their number concentration and chemical composition and properties.

  12. Validation of the NOAA/NESDIS satellite aerosol product over the North Atlantic in 1989

    NASA Astrophysics Data System (ADS)

    Ignatov, Aleksandr M.; Stowe, Larry L.; Sakerin, Sergey M.; Korotaev, Gennady K.

    1995-03-01

    A validation experiment and resulting potential improvements to the operational satellite optical thickness product at the National Oceanic and Atmospheric Administration/National Environmental Satellite Data and Information Service (NOAA/NESDIS) are presented. An earlier paper described a set of Sun photometer measurements collected from the Soviet R/V Akademik Vernadsky during its cruise in the Atlantic Ocean and Mediterranean Sea from September to December 1989. The accuracy of the Sun photometer aerosol optical thickness was proven acceptable of use as a ground truth standard for validation of the NOAA product. This paper describes the validation methodology and the results of its application to the NOAA 11 satellite product. A systematic underestimation in the operational values by about 35%, relative to the ship truth, is found. Causes for this discrepancy are examined, emphasizing the importance of careful satellite instrument calibration, and a revision of the oceanic reflectance model used in the retrieval algorithm. It is shown that the remaining systematic underestimate in satellite aerosol optical thickness can be attributed only to the aerosol model used in the retrieval. Additional checks of this conclusion using independent data sets are underway. If confirmed, a fundamental revision of the presently used aerosol model would be required. An example of a simple adjustment to the present aerosol model which successfully removes the bias is given, based on the assumption of an absorbing aerosol.

  13. Characterization of potential impurities and degradation products in electronic cigarette formulations and aerosols.

    PubMed

    Flora, Jason W; Meruva, Naren; Huang, Chorng B; Wilkinson, Celeste T; Ballentine, Regina; Smith, Donna C; Werley, Michael S; McKinney, Willie J

    2016-02-01

    E-cigarettes are gaining popularity in the U.S. as well as in other global markets. Currently, limited published analytical data characterizing e-cigarette formulations (e-liquids) and aerosols exist. While FDA has not published a harmful and potentially harmful constituent (HPHC) list for e-cigarettes, the HPHC list for currently regulated tobacco products may be useful to analytically characterize e-cigarette aerosols. For example, most e-cigarette formulations contain propylene glycol and glycerin, which may produce aldehydes when heated. In addition, nicotine-related chemicals have been previously reported as potential e-cigarette formulation impurities. This study determined e-liquid formulation impurities and potentially harmful chemicals in aerosols of select commercial MarkTen(®) e-cigarettes manufactured by NuMark LLC. The potential hazard of the identified formulation impurities and aerosol chemicals was also estimated. E-cigarettes were machine puffed (4-s duration, 55-mL volume, 30-s intervals) to battery exhaustion to maximize aerosol collection. Aerosols analyzed for carbonyls were collected in 20-puff increments to account for analyte instability. Tobacco specific nitrosamines were measured at levels observed in pharmaceutical grade nicotine. Nicotine-related impurities in the e-cigarette formulations were below the identification and qualification thresholds proposed in ICH Guideline Q3B(R2). Levels of potentially harmful chemicals detected in the aerosols were determined to be below published occupational exposure limits. PMID:26617410

  14. If the MODIS Aerosol Product is so Infested with Cloud Contamination, Why Does Everybody Use the Product?

    NASA Technical Reports Server (NTRS)

    Remeer, Lorraine A.

    2011-01-01

    The MODIS aerosol cloud mask is based on a spatial variability test, using the assumption that aerosols are more homogeneous than clouds. On top of this first line of defense are a series of additional tests based on threshold values and ratios of various MODIS channels. The goal is to eliminate clouds and keep the aerosol. How well have we succeeded? There have been several studies showing cloud contamination in the MODIS aerosol product and several alternative cloud masks proposed. There are even "competing" MODIS aerosol products that offer an alternative "cloud free" world. Are these alternative products an improvement to the old standard product? We find there is a trade-off between retrieval availability and cloud contamination, and for many applications it is better to have a little bit of cloud in the product than to not have enough product. I will review the decisions that led us to the present MODIS cloud mask, and show how it is simultaneously too liberal and too conservative, some ideas on how to make it better and why in the end it doesn't matter. I hope to inspire a spirited discussion and will be very willing to take your complaints and suggestions.

  15. The uncertainty of MODIS C6 aerosol optical depth product over land

    NASA Astrophysics Data System (ADS)

    Wu, Yerong; de Graaf, Martin; Menenti, Massimo

    2015-04-01

    Aerosol Optical Depth (AOD) has an important impact on climate change and air quality. A number of AOD satellite data products have been released, like Moderate Resolution Imaging Spectroradiometer (MODIS) AOD product, which are further applied for monitoring PM2.5, for long-term aerosol trend analysis, and for estimating aerosol radiative forcing. However, the accuracy of MODIS AOD product with ±0.03 or 15-20% of global mean value over land is still low for extensive scientific research. To investigate the accuracy of the product, a synthetic experiment was designed where the errors introduced by both radiometry and algorithm, e.g. instrument calibration, gas correction and cloud mask, and some assumptions on aerosol properties can be removed. Through analysis of the mean value of retrieved AOD over 1520 observational configurations, the algorithm performs very well with small errors (up to 0.2%) for most cases, while for some extreme cases (eg., AOD=5.0), it performs less accurately (> 3%). The uncertainty also shows a trend related to the geometry of observations (e.g., scattering angle). The results suggest higher accuracy at large scattering angles, and lower accuracy at small scattering angles. The main reason for the uncertainty is an inappropriate assumption on surface reflectance, where surface reflectance is regarded as a function of aerosol loading and mixing ratio. Therefore, a more accurate representation of the surface reflectance will increase the accuracy of the MODIS AOD product.

  16. ALTERNATIVE FORMULATIONS TO REDUCE CFC USE IN U.S. EXEMPTED AND EXCLUSED AEROSOL PRODUCTS

    EPA Science Inventory

    The report examines products exempted and excluded from those affected by the 1978 ban on the use of chlorofluorocarbons (CFCs) as aerosol propellants, the present consumption of CFCs still utilized for these products in the U.S., and alternative formulations which may be used to...

  17. ALTERNATIVE FORMULATIONS TO REDUCE CFC USE IN U.S. EXEMPTED AND EXCLUDED AEROSOL PRODUCTS

    EPA Science Inventory

    The report examines products exempted and excluded from those affected by the 1978 ban on the use of chlorofluorocarbons (CFCs) as aerosol propellants, the present consumption of CFCs still utilized for these products in the U.S., and alternative formulations which may be used to...

  18. Evidence of Aerosols as a Media for Rapid Daytime HONO Production over China

    SciTech Connect

    Liu, Zhen; Wang, Yuhang; Costabile, Francesa; Amoroso, Antonio; Zhao, Chun; Huey, L. G.; Stickel, Robert; Liao, Jin; Zhu, Tong

    2014-12-16

    Current knowledge of daytime HONO sources remains incomplete. A large missing daytime HONO source has been found in many places around the world, including polluted regions in China. Conventional understanding and recent studies attributed this missing source mainly to ground surface processes or gas-phase chemistry, while assuming aerosols to be an insignificant media for HONO production. We analyze in situ observations of HONO and its precursors at an urban site in Beijing, China, and report an apparent dependence of the missing HONO source strength on aerosol surface area and solar ultraviolet radiation. Based on extensive correlation analysis and process-modeling, we propose that the rapid daytime HONO production in Beijing can be explained by enhanced hydrolytic disproportionation of NO2 on aqueous aerosol surfaces due to catalysis by dicarboxylic acid anions. The combination of high abundance of NO2, aromatic hydrocarbons, and aerosols over broad regions in China likely leads to elevated HONO levels, rapid OH production, and enhanced oxidizing capacity on a regional basis. Our findings call for attention to aerosols as a media for daytime heterogeneous HONO production in polluted regions like Beijing. This study also highlights the complex and uncertain heterogeneous chemistry in China, which merits future efforts of reconciling regional modeling and laboratory experiments, in order to understand and mitigate the regional particulate and O3 pollutions over China.

  19. On direct passive microwave remote sensing of sea spray aerosol production

    NASA Astrophysics Data System (ADS)

    Savelyev, I. B.; Anguelova, M. D.; Frick, G. M.; Dowgiallo, D. J.; Hwang, P. A.; Caffrey, P. F.; Bobak, J. P.

    2014-11-01

    This study addresses and attempts to mitigate persistent uncertainty and scatter among existing approaches for determining the rate of sea spray aerosol production by breaking waves in the open ocean. The new approach proposed here utilizes passive microwave emissions from the ocean surface, which are known to be sensitive to surface roughness and foam. Direct, simultaneous, and collocated measurements of the aerosol production and microwave emissions were collected aboard the FLoating Instrument Platform (FLIP) in deep water ~ 150 km off the coast of California over a period of ~ 4 days. Vertical profiles of coarse-mode aerosol (0.25-23.5 μm) concentrations were measured with a forward-scattering spectrometer and converted to surface flux using dry deposition and vertical gradient methods. Back-trajectory analysis of eastern North Pacific meteorology verified the clean marine origin of the sampled air mass over at least 5 days prior to measurements. Vertical and horizontal polarization surface brightness temperature were measured with a microwave radiometer at 10.7 GHz frequency. Data analysis revealed a strong sensitivity of the brightness temperature polarization difference to the rate of aerosol production. An existing model of microwave emission from the ocean surface was used to determine the empirical relationship and to attribute its underlying physical basis to microwave emissions from surface roughness and foam within active and passive phases of breaking waves. A possibility of and initial steps towards satellite retrievals of the sea spray aerosol production are briefly discussed in concluding remarks.

  20. On direct passive microwave remote sensing of sea spray aerosol production

    NASA Astrophysics Data System (ADS)

    Savelyev, I. B.; Anguelova, M. D.; Frick, G. M.; Dowgiallo, D. J.; Hwang, P. A.; Caffrey, P. F.; Bobak, J. P.

    2014-06-01

    This study addresses and attempts to mitigate persistent uncertainty and scatter among existing approaches for determining the rate of sea spray aerosol production by breaking waves in the open ocean. The new approach proposed here utilizes passive microwave emissions from the ocean surface, which are known to be sensitive to surface roughness and foam. Direct, simultaneous, and collocated measurements of the aerosol production and microwave emissions were collected on-board FLoating Instrument Platform (FLIP) in deep water ∼150 km off the coast of California over a period of ∼4 days. Vertical profiles of coarse-mode aerosol (0.25-23.5 μm) concentrations were measured with a forward scattering spectrometer and converted to surface flux using dry deposition and vertical gradient methods. Back trajectory analysis of Northeast Pacific meteorology verified the clean marine origin of the sampled air mass over at least 5 days prior to measurements. Vertical and horizontal polarization surface brightness temperatures were measured with a microwave radiometer at 10.7 GHz frequency. Data analysis revealed a strong sensitivity of the brightness temperature polarization difference to the rate of aerosol production. An existing model of microwave emission from the ocean surface was used to determine the empirical relationship and to attribute its underlying physical basis to microwave emissions from surface roughness and foam within active and passive phases of breaking waves. A possibility of and initial steps towards satellite retrievals of the sea spray aerosol production are briefly discussed in concluding remarks.

  1. Bioequivalence for locally acting nasal spray and nasal aerosol products: standard development and generic approval.

    PubMed

    Li, Bing V; Jin, Feiyan; Lee, Sau L; Bai, Tao; Chowdhury, Badrul; Caramenico, Hoainhon T; Conner, Dale P

    2013-07-01

    Demonstrating bioequivalence (BE) for nasal spray/aerosol products for local action has been very challenging because the relationship between the drug in systemic circulation and the drug reaching the nasal site of action has not been well established. Thus, the current BE standard for these drug/device combination products is based on a weight-of-evidence approach, which contains three major elements: equivalent in vitro performance, equivalent systemic exposure, and equivalent local delivery. In addition, formulation sameness and device similarity are evidences to support BE. This paper presents a comprehensive review of the scientific rationale of the current BE standard and their development history for nasal spray/aerosol products, as well as the Food and Drug Administration's review and approval status of generic nasal sprays/aerosols with the application of these BE standard. PMID:23686396

  2. Analysis of reversibility and reaction products of glyoxal uptake onto ammonium sulfate aerosol

    NASA Astrophysics Data System (ADS)

    Galloway, M. M.; Chhabra, P. S.; Chan, A. W.; Surratt, J. D.; Kwan, A. J.; Wennberg, P. O.; Flagan, R. C.; Seinfeld, J. H.; Keutsch, F. N.

    2009-04-01

    Glyoxal, the smallest alpha-dicarbonyl, is an oxidation product of both biogenic and anthropogenic volatile organic compounds (Fu et al. JGR 113, D15303, 2008). Despite its low molecular weight, its role in secondary organic aerosol (SOA) formation has gained interest and a recent study suggested that it accounts for more than 15% of SOA in Mexico City (Volkamer et al. GRL 34, L19807, 2007). Despite numerous previous studies, questions remain regarding the processes controlling glyoxal uptake onto aerosol, including the role of acid catalysis, degree of reversibility, and identity of aerosol phase reaction products. We present results of chamber aerosol studies (Galloway et al. ACPD 8, 20799, 2008) and laboratory studies of bulk samples aimed at improving the understanding of these processes, in particular formation of oligomers and organosulfates of glyoxal, as well as the formation of imidazoles (carbon-nitrogen containing heterocyclic aromatic compounds) under dark and irradiated conditions. The relevance of these classes of reaction products extends beyond glyoxal, as evidence of oligomers and organosulfates other than those of glyoxal have been found in ambient aerosol (Surratt et al. JPCA 112, 8345, 2008; Denkenberger et al. Environ. Sci. Technol. 41, 5439, 2007). Experiments in which a chamber air mass was diluted after equilibration of glyoxal uptake onto ammonium sulfate seed aerosol (relative humidity 60% and glyoxal mixing ratios of 25-200 ppbv) shows that under these conditions uptake is reversible. The most important condensed phase products are hydrated oligomers of glyoxal, which are also formed reversibly under these conditions. Our studies show that organosulfates were not formed under dark conditions for neutral or acidified aerosol; similarly, Minerath et al. have recently shown that formation of a different class of organosulfates (alkyl sulfates) also proceeds very slowly even under acidic conditions (Environ. Sci. Technol. 42, 4410, 2008). The

  3. Forecasting Plant Productivity and Health Using Diffuse-to-Global Irradiance Ratios Extracted from the OMI Aerosol Product

    NASA Technical Reports Server (NTRS)

    Knowlton, Kelly; Andrews, Jane C.; Ryan, Robert E.

    2007-01-01

    Atmospheric aerosols are a major contributor to diffuse irradiance. This Candidate Solution suggests using the OMI (Ozone Monitoring Instrument) aerosol product as input into a radiative transfer model, which would calculate the ratio of diffuse to global irradiance at the Earth s surface. This ratio can significantly influence the rate of photosynthesis in plants; increasing the ratio of diffuse to global irradiance can accelerate photosynthesis, resulting in greater plant productivity. Accurate values of this ratio could be useful in predicting crop productivity, thereby improving forecasts of regional food resources. However, disagreements exist between diffuse-to-global irradiance values measured by different satellites and ground sensors. OMI, with its unique combination of spectral bands, high resolution, and daily global coverage, may be able to provide more accurate aerosol measurements than other comparable sensors.

  4. Aerosol Extinction and Single Scattering Albedo Downwind of the Summer 2008 California Wildfires Measured With Photoacoustic Spectrometers and Sunphotometers From 355 nm to 1047 nm.

    NASA Astrophysics Data System (ADS)

    Arnott, W. P.; Gyawali, M. S.; Arnold, I. J.

    2008-12-01

    Hundreds of wildfires in Northern California were sparked by lightning during the summer of 2008, resulting in downwind smoke for much of June and July associated with the flaming and smoldering stages of the fires. These fires are consistent with a growing trend towards increasing biomass burning worldwide. Climate impacts from the smoke depend critically on the smoke amount and aerosol optical properties. We report comparison of aerosol optics measurements in Reno Nevada made during the very smoky summer month of July with the relatively clean, average month of August. Photoacoustic instruments equipped with integrating nephelometers were used to measure aerosol light scattering and absorption at wavelengths of 355 nm, 405 nm, 532 nm, 870 nm, and 1047 nm. Total aerosol optical depth was measured with a sun photometer operating at 430nm, 470nm, 530nm, 660nm, 870nm and 950nm. A spectrometer based sun photometer with an operating range from 390nm to 880 nm was also used for a few days as well. These measurements document the intensity of the smoke optical impacts downwind. They are processed further to reveal a strong variation of the aerosol light absorption on wavelength, indicating the presence of light absorbing organic material and perhaps wavelength dependent absorption caused by black carbon particles coated with organic and inorganic particulate matter. On the day with most smoke in Reno (July 10, 2008) Angstrom coefficients for absorption as high as 3.6 were found for wavelengths of 405 nm and 870 nm, with the corresponding single scattering albedo near 0.92 at 405 nm. Aerosol optical depths of 3.5 were found for 430 nm on July 10th from the sun photometer measurements. A roughly fourfold increase in aerosol optical quantities was observed between the months of July and August 2008, attesting to the large average effects of biomass aerosols from the California wildfires.

  5. Near-Cloud Aerosol Properties from the 1 Km Resolution MODIS Ocean Product

    NASA Technical Reports Server (NTRS)

    Varnai, Tamas; Marshak, Alexander

    2014-01-01

    This study examines aerosol properties in the vicinity of clouds by analyzing high-resolution atmospheric correction parameters provided in the MODIS (Moderate Resolution Imaging Spectroradiometer) ocean color product. The study analyzes data from a 2 week long period of September in 10 years, covering a large area in the northeast Atlantic Ocean. The results indicate that on the one hand, the Quality Assessment (QA) flags of the ocean color product successfully eliminate cloud-related uncertainties in ocean parameters such as chlorophyll content, but on the other hand, using the flags introduces a sampling bias in atmospheric products such as aerosol optical thickness (AOT) and Angstrom exponent. Therefore, researchers need to select QA flags by balancing the risks of increased retrieval uncertainties and sampling biases. Using an optimal set of QA flags, the results reveal substantial increases in optical thickness near clouds-on average the increase is 50% for the roughly half of pixels within 5 km from clouds and is accompanied by a roughly matching increase in particle size. Theoretical simulations show that the 50% increase in 550nm AOT changes instantaneous direct aerosol radiative forcing by up to 8W/m2 and that the radiative impact is significantly larger if observed near-cloud changes are attributed to aerosol particles as opposed to undetected cloud particles. These results underline that accounting for near-cloud areas and understanding the causes of near-cloud particle changes are critical for accurate calculations of direct aerosol radiative forcing.

  6. Contribution of airborne microbes to bacterial production and N2 fixation in seawater upon aerosol deposition

    NASA Astrophysics Data System (ADS)

    Rahav, Eyal; Ovadia, Galit; Paytan, Adina; Herut, Barak

    2016-01-01

    Aerosol deposition may supply a high diversity of airborne microbes, which can affect surface microbial composition and biological production. This study reports a diverse microbial community associated with dust and other aerosol particles, which differed significantly according to their geographical air mass origin. Microcosm bioassay experiments, in which aerosols were added to sterile (0.2 µm filtered and autoclaved) SE Mediterranean Sea (SEMS) water, were performed to assess the potential impact of airborne bacteria on bacterial abundance, production, and N2 fixation. Significant increase was observed in all parameters within a few hours, and calculations suggest that airborne microbes can account for one third in bacterial abundance and 50-100% in bacterial production and N2-fixation rates following dust/aerosol amendments in the surface SEMS. We show that dust/aerosol deposition can be a potential source of a wide array of microorganisms, which may impact microbial composition and food web dynamics in oligotrophic marine systems such as the SEMS.

  7. Capabilities and Limitations of MISR Aerosol Products in Dust-Laden Regions

    NASA Technical Reports Server (NTRS)

    Kalashnikova, Olga V.; Garay, Michael J.; Sokolik, Irina N.; Diner, David J.; Kahn, Ralph A.; Martonchcik, John V.; Lee, Jae N.; Torres, Omar; Yang, Weidong; Marshak, Alexander; Kassabian, Sero; Chodas, Mark

    2011-01-01

    Atmospheric mineral dust particles have significant effects on climate and the environment, and despite notable advances in modeling and satellite and ground-based measurements, remain one of the major factors contributing to large uncertainty in aerosol radiative forcing. We examine the Multi-angle Imaging SpectroRadiometer (MISR) 11+ year aerosol data record to demonstrate MISR's unique strengths and assess potential biases of MISR products for dust study applications. In particular, we examine MISR's unique capabilities to 1) distinguish dust aerosol from spherical aerosol types, 2) provide aerosol optical depths over bright desert source regions, and 3) provide high-resolution retrievals of dust plume heights and associated winds. We show examples of regional and global MISR data products in dusty regions together with quantitative evaluations of product accuracies through comparisons with independent data sources, and demonstrate applications of MISR data to dust regional and climatological studies, such as dust property evolution during transport, dust source climatology in relation to climatic factors, and dust source dynamics. The potential use of MISR radiance data to study dust properties is also discussed.

  8. Laser Remote Sensing from ISS: CATS Cloud and Aerosol Level 2 Data Products (Heritage Edition)

    NASA Astrophysics Data System (ADS)

    Rodier, Sharon; Palm, Steve; Vaughan, Mark; Yorks, John; McGill, Matt; Jensen, Mike; Murray, Tim; Trepte, Chip

    2016-06-01

    With the recent launch of the Cloud-Aerosol Transport System (CATS) we have the opportunity to acquire a continuous record of space based lidar measurements spanning from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) era to the start of the EarthCARE mission. Utilizing existing well-validated science algorithms from the CALIPSO mission, we will ingest the CATS data stream and deliver high-quality lidar data sets to the user community at the earliest possible opportunity. In this paper we present an overview of procedures necessary to generate CALIPSO-like lidar level 2 data products from the CATS level 1 data products.

  9. Aerosol Precursor Emissions, Secondary Aerosol Production, and Climate-Forcing Gas Exchange in the Midwestern United States

    NASA Astrophysics Data System (ADS)

    Doskey, P. V.

    2009-12-01

    Aerosol precursors in the Midwest are generated from a myriad of sources including biogenic emissions of terpenes from the Ozarks region, anthropogenic emissions of volatile and semivolatile aliphatic and aromatic hydrocarbons from the St. Louis airshed, and agricultural emissions of ammonia (NH3), amines, and nitrogen oxides (NOx) from animal husbandry and cropping systems of the Midwest Corn Belt. The deciduous and coniferous forests of the Ozarks region are significant sources of isoprene, monoterpenes, and sesquiterpenes that are sensitive to rising CO2 levels and temperature and generate light-scattering, secondary organic aerosol (SOA). Application of nitrogen fertilizers stimulates emissions of ammonia (NH3), nitric oxide (NO), and nitrous oxide (N2O) from agricultural soils and crops. Nitric acid, generated through photooxidation of NO emissions from fossil fuel combustion in urban air and from soil emissions in agroecosystems, reacts rapidly with NH3 to generate light-scattering, secondary inorganic aerosol (SIA). The atmospheric lifetime of N2O is about 120 years, making the substance a potent greenhouse gas with a global warming potential of 290 for a time horizon of 20 years relative to CO2. Emissions of CO2, N2O, and SIA precursors from the Midwest Corn Belt and surrounding areas are likely to increase in the near future as pastureland and prairie is converted to grow corn and other biofuel crops to meet the demand for renewable fuels. Several large river systems transport nutrients from fertilized fields of the Midwest agroecosystem to the Gulf of Mexico where plankton growth is accelerated. Microbial decomposition of plankton detritus consumes oxygen and creates a hypoxic zone, which might be a significant source of N2O.The presentation will discuss gaps in our knowledge of the production of climate-forcing species in the Midwestern United States.

  10. Determination of a refractive index and an extinction coefficient of standard production of CVD-graphene

    NASA Astrophysics Data System (ADS)

    Ochoa-Martínez, Efraín; Gabás, Mercedes; Barrutia, Laura; Pesquera, Amaia; Centeno, Alba; Palanco, Santiago; Zurutuza, Amaia; Algora, Carlos

    2015-01-01

    The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical properties of the stacked structure is noticeable both in the visible and the ultraviolet spectral regions, thus masking the graphene optical response. Finally, the use of heat treatment under a nitrogen atmosphere of the graphene-based stacked structures, as a method to reduce the water content of the sample, and its effect on the optical response of both graphene and the residual debris layer are presented. The Lorentz-Drude model proposed for the optical response of graphene fits fairly well the experimental ellipsometric data for all the analysed graphene-based stacked structures.The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical

  11. Uncertainty Analysis And Synergy Of Aerosol Products From Multiple Satellite Sensors For Advanced Atmospheric Research

    NASA Astrophysics Data System (ADS)

    Ichoku, C. M.; Petrenko, M.

    2013-05-01

    Aerosols are tiny particles suspended in the air, and can be made up of wind-blown dust, smoke from fires, and particulate emissions from automobiles, industries, and other natural and man-made sources. Aerosols can have significant impacts on the air quality, and can interact with clouds and solar radiation in such a way as to affect the water cycle and climate. However, the extent and scale of these impacts are still poorly understood, and this represents one of the greatest uncertainties in climate research to date. To fill this gap in our knowledge, the global and local properties of atmospheric aerosols are being extensively observed and measured, especially during the last decade, using both satellite and ground-based instruments, including such spaceborne sensors as MODIS on the Terra and Aqua satellites, MISR on Terra, OMI on Aura, POLDER on PARASOL, CALIOP on CALIPSO, SeaWiFS on SeaStar, and the ground-based Aerosol Robotic Network (AERONET) of sunphotometers. The aerosol measurements collected by these instruments over the last decade contribute to an unprecedented availability of the most complete set of complimentary aerosol measurements ever acquired. Still, to be able to utilize these measurements synergistically, they have to be carefully and uniformly analyzed and inter-compared, in order to understand the uncertainties and limitations of the products - a process that is greatly complicated by the diversity of differences that exist among them. In this presentation, we will show results of a coherent comparative uncertainty analysis of aerosol measurements from the above-named satellite sensors relative to AERONET. We use these results to demonstrate how these sensors perform in different parts of the world over different landcover types as well as their performance relative to one another, thereby facilitating product selection and integration for specific research and applications needs.

  12. Aerus-GEO: newly available satellite-derived aerosol optical depth product over Europe and Africa

    NASA Astrophysics Data System (ADS)

    Carrer, D.; Roujean, J. L.; Ceamanos, X.; Six, B.; Suman, S.

    2015-12-01

    The major difficulty in detecting the aerosol signal from visible and near-infrared remote sensing observations is to reach the proper separation of the components related to the atmosphere and the surface. A method is proposed to circumvent this issue by exploiting the directional and temporal dimensions of the satellite signal through the use of a semi-empirical kernel-driven model for the surface/atmosphere coupled system. This algorithm was implemented by the ICARE Data Center (http://www.icare.univ-lille1.fr), which operationally disseminates a daily AOD product at 670 nm over the MSG disk since 2014. The proposed method referred to as AERUS-GEO (Aerosol and surface albEdo Retrieval Using a directional Splitting method - application to GEO data) is applied to three spectral bands (0.6 mm, 0.8 mm, and 1.6 mm) of MSG (Meteosat Second Generation) observations, which scan Europe, Africa, and the Eastern part of South America every 15 minutes. The daily AOD estimates at 0.63μm has been extensively validated. In contrast, the Angstrom coefficient is still going through validation and we will show the differences between the MSG derived Angstrom exponent with that of CAMS (Copernicus Atmosphere Monitoring Service) near-real time aerosol product. The impact of aerosol type on the aerosol radiative forcing will be presented as a part of future development plan.

  13. Tropical and Midlatitude Cirrus Cloud Extinction and Backscatter From Multiyear Raman Lidar Measurements.

    NASA Astrophysics Data System (ADS)

    Thorsen, T. J.; Fu, Q.

    2014-12-01

    Lidars have the capability to provide unparalleled range-resolved observations of particulate extinction. However, lidars fundamentally measure backscattered energy, not extinction, and for widely prevalent single-channel elastic backscatter lidars extinction must be obtained by assuming a backscatter-extinction relationship. Our knowledge of this relationship, known as the lidar ratio, mainly consists values determined via the transmission-loss method: which can only provide layer-averaged values and is only applicable to a subset of all cloud layers. Directly-retrieved, vertically resolved extinction coefficients and lidar ratios are obtainable through the use of more advance high spectral resolution lidars (HSRL) or Raman lidars (RL). However, the complexity of operating a HSRL or RL has limited their use for cloud observations to very limited time periods: typical only a few months or less. In this work, we present a newly developed retrieval for the Atmospheric Radiation Measurement (ARM) program's Raman lidars for Feature detection and EXtinction retrieval (FEX). FEX improves upon existing ARM products by using multiple, complimentary quantities to identify both clouds and aerosols and retrieve their extinction and backscatter profiles. Multiple years of data are examined at both the Lamont, Oklahoma and Darwin, Australia ARM sites; providing the most comprehensive climatology to date of cirrus extinction and lidar ratios. Variations in these optical properties with classification of the synoptic state and their relationship with microphysical parameters (temperature, relative humidity and depolarization) are examined.

  14. A Marine Aerosol Reference Tank system as a breaking wave analogue for the production of foam and sea-spray aerosols

    NASA Astrophysics Data System (ADS)

    Stokes, M. D.; Deane, G. B.; Prather, K.; Bertram, T. H.; Ruppel, M. J.; Ryder, O. S.; Brady, J. M.; Zhao, D.

    2013-04-01

    In order to better understand the processes governing the production of marine aerosols a repeatable, controlled method for their generation is required. The Marine Aerosol Reference Tank (MART) has been designed to closely approximate oceanic conditions by producing an evolving bubble plume and surface foam patch. The tank utilizes an intermittently plunging sheet of water and large volume tank reservoir to simulate turbulence, plume and foam formation, and the water flow is monitored volumetrically and acoustically to ensure the repeatability of conditions.

  15. Biochemical Controls on the Production and Composition of Primary Marine Aerosol

    NASA Astrophysics Data System (ADS)

    Keene, W. C.; Kieber, D. J.; Frossard, A. A.; Long, M. S.; Russell, L. M.; Maben, J. R.; Kinsey, J. D.; Tyssebotn, I. M.; Quinn, P. K.; Bates, T. S.

    2013-12-01

    Nascent marine aerosols were produced by bursting bubbles from both flowing and fixed volumes of fresh surface seawater under controlled conditions in a high-capacity shipboard generator deployed in the eastern North Pacific Ocean during CalNex and in the western North Atlantic Ocean during the Western Atlantic Climate Study (WACS). Seawater conditions ranged from highly productive (chl a = 12 μg L-1) to oligotrophic (chl a = 0.03 μg L-1). Aerosols were also produced from fresh flowing seawater sampled at 2500 m depth (chl a = 0.00 μg L-1). Bubble sizes, bubble surface tension, and size-resolved aerosol chemical compositions and number production fluxes were quantified. Number fluxes were dominated by particles less than100-nm dry diameter that were composed primarily of organic matter (OM). Production fluxes of particulate OM corresponded to <0.01% of dissolved OM (DOC) in flowing seawater. Aerosol number fluxes from flowing productive waters were greater by factors of 2 to 3 compared to oligotrophic waters but corresponding organic enrichments (EFocs) relative to seawater were similar. Bubble scavenging from fixed-volume reservoirs of productive waters rapidly depleted dominant but small surfactants pools leading to lower bubble surface tensions and number production fluxes that converged to those for oligotrophic waters. Bubble scavenging from fixed-volume oligotrophic waters had no influence on aerosol fluxes suggesting the presence of a large background pool of surfactants. Number production fluxes and EFocs from flowing deep seawater were within the ranges of those from surface waters indicating that significant particulate OM is produced by bursting bubbles at the ocean surface in the absence of recent biological activity. Taken together, these results suggest that surfactant material associated with the large pool of recalcitrant DOC in surface seawater contributes to particulate OM in marine air.

  16. A new method of satellite-based haze aerosol monitoring over the North China Plain and a comparison with MODIS Collection 6 aerosol products

    NASA Astrophysics Data System (ADS)

    Yan, Xing; Shi, Wenzhong; Luo, Nana; Zhao, Wenji

    2016-05-01

    With worldwide urbanization, hazy weather has been increasingly frequent, especially in the North China Plain. However, haze aerosol monitoring remains a challenge. In this paper, MODerate resolution Imaging Spectroradiometer (MODIS) measurements were used to develop an enhanced haze aerosol retrieval algorithm (EHARA). This method can work not only on hazy days but also on normal weather days. Based on 12-year (2002-2014) Aerosol Robotic Network (AERONET) aerosol property data, empirical single scattering albedo (SSA) and asymmetry factor (AF) values were chosen to assist haze aerosol retrieval. For validation, EHARA aerosol optical thickness (AOT) values, along with MODIS Collection 6 (C6) dark-pixel and deep blue aerosol products, were compared with AERONET data. The results show that the EHARA can achieve greater AOT spatial coverage under hazy conditions with a high accuracy (73% within error range) and work a higher resolution (1-km). Additionally, this paper presents a comprehensive discussion of the differences between and limitations of the EHARA and the MODIS C6 DT land algorithms.

  17. Light extinction in the atmosphere

    SciTech Connect

    Laulainen, N.

    1992-06-01

    Atmospheric aerosol particles originating from natural sources, such as volcanos and sulfur-bearing gas emissions from the oceans, and from human sources, such as sulfur emissions from fossil fuel combustion and biomass burning, strongly affect visual air quality and are suspected to significantly affect radiative climate forcing of the planet. During the daytime, aerosols obscure scenic vistas, while at night they diminish our ability to observe stellar objects. Scattering of light is the main means by which aerosols attenuate and redistribute light in the atmosphere and by which aerosols can alter and reduce visibility and potentially modify the energy balance of the planet. Trends and seasonal variability of atmospheric aerosol loading, such as column-integrated light extinction or optical depth, and how they may affect potential climate change have been difficult to quantify because there have been few observations made of important aerosol optical parameters, such as optical depth, over the globe and over time and often these are of uneven quality. To address questions related to possible climate change, there is a pressing need to acquire more high-quality aerosol optical depth data. Extensive deployment of improved solar radiometers over the next few years will provide higher-quality extinction data over a wider variety of locations worldwide. An often overlooked source of turbidity data, however, is available from astronomical observations, particularly stellar photoelectric photometry observations. With the exception of the Project ASTRA articles published almost 20 years ago, few of these data ever appear in the published literature. This paper will review the current status of atmospheric extinction observations, as highlighted by the ASTRA work and augmented by more recent solar radiometry measurements.

  18. Markers of heterogeneous reaction products in α-pinene ozone secondary organic aerosol

    NASA Astrophysics Data System (ADS)

    Czoschke, Nadine M.; Jang, Myoseon

    A gas chromatograph iontrap mass spectrometer (GC-ITMS) was used to analyze the gas-and particle-phase products of α-pinene ozone oxidation in the presence of three different inorganic seed aerosols: sodium chloride, ammonium sulfate only, and ammonium sulfate with sulfuric acid. Products of α-pinene ozone oxidation common to the literature showed little difference in gas or particle-phase concentrations between seed types within the precision of the measurements even though significantly different aerosol yields were found between seed types. Small amounts of ring-opening products of four-membered cyclic oxygenates and markers of aldol condensation products were tentatively identified in the particle-phase for all seed types. These tentatively identified products are thought to be the result of acid-catalyzed heterogeneous reactions in the particle-phase or during sampling processes or analysis. The mechanisms for their formation are also proposed in this study.

  19. Photochemical production of aerosols from real plant emissions

    NASA Astrophysics Data System (ADS)

    Mentel, Th. F.; Wildt, J.; Kiendler-Scharr, A.; Kleist, E.; Tillmann, R.; Dal Maso, M.; Fisseha, R.; Hohaus, Th.; Spahn, H.; Uerlings, R.; Wegener, R.; Griffiths, P. T.; Dinar, E.; Rudich, Y.; Wahner, A.

    2009-07-01

    Emission of biogenic volatile organic compounds (VOC) which on oxidation form secondary organic aerosols (SOA) can couple the vegetation with the atmosphere and climate. Particle formation from tree emissions was investigated in a new setup: a plant chamber coupled to a reaction chamber for oxidizing the plant emissions and for forming SOA. Emissions from the boreal tree species birch, pine, and spruce were studied. In addition, α-pinene was used as reference compound. Under the employed experimental conditions, OH radicals were essential for inducing new particle formation, although O3 (≤80 ppb) was always present and a fraction of the monoterpenes and the sesquiterpenes reacted with ozone before OH was generated. Formation rates of 3 nm particles were linearly related to the VOC carbon mixing ratios, as were the maximum observed volume and the condensational growth rates. For all trees, the threshold of new particle formation was lower than for α-pinene. It was lowest for birch which emitted the largest fraction of oxygenated VOC (OVOC), suggesting that OVOC may play a role in the nucleation process. Incremental mass yields were ≍5% for pine, spruce and α-pinene, and ≍10% for birch. α-Pinene was a good model compound to describe the yield and the growth of SOA particles from coniferous emissions. The mass fractional yields agreed well with observations for boreal forests. Despite the somewhat enhanced VOC and OH concentrations our results may be up-scaled to eco-system level. Using the mass fractional yields observed for the tree emissions and weighting them with the abundance of the respective trees in boreal forests SOA mass concentration calculations agree within 6% with field observations. For a future VOC increase of 50% we predict a particle mass increase due to SOA of 19% assuming today's mass contribution of pre-existing aerosol and oxidant levels.

  20. Photochemical production of aerosols from real plant emissions

    NASA Astrophysics Data System (ADS)

    Mentel, Th. F.; Wildt, J.; Kiendler-Scharr, A.; Kleist, E.; Tillmann, R.; Dal Maso, M.; Fisseha, R.; Hohaus, Th.; Spahn, H.; Uerlings, R.; Wegener, R.; Griffiths, P. T.; Dinar, E.; Rudich, Y.; Wahner, A.

    2009-01-01

    By emission of volatile organic compounds (VOC) which on oxidation form secondary organic aerosols (SOA) the vegetation is coupled to atmosphere and climate. New particle formation from tree emissions was investigated in a new setup: a plant chamber coupled to a reaction chamber for oxidizing the plant emissions and for forming SOA. The boreal tree species birch, pine, and spruce were studied and α-pinene was used as reference compound. Under the experimental conditions OH radicals were essential for inducing new particle formation, although O3 (≤80 ppb) was always present and a part of the monoterpenes and the sesquiterpenes reacted already with ozone before OH was generated. Formation rates of 3 nm particles were linearly related to the carbon mixing ratios of the VOC, as were the maximum observed volume and the condensational growth rates. The threshold of new particle formation was lower for the tree emissions than for α-pinene. It was lowest for birch with the largest fraction of oxygenated VOC (OVOC) suggesting that OVOC may play a pivotal role in new particle formation. Incremental mass yields were ≍5% for pine, spruce and α-pinene, and ≍10% for birch. α-Pinene was a good model compound to describe the yield and the growth of SOA particles from coniferous emissions. The mass fractional yields agreed well with observations for boreal forests. Despite our somewhat enhanced VOC and OH concentrations our results may thus be up-scaled to eco-system level. Using the mass fractional yields observed for the tree emissions and weighting them with the abundance of the respective trees in boreal forests we calculate SOA mass concentrations which agree within 6% with field observations. For a future VOC increase of 50% we predict a particle mass increase due to SOA of 19% assuming today's mass contribution of pre-existing aerosol.

  1. Abiotic causes of the great mass extinction of marine biota at the Triassic-Jurassic boundary

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2015-05-01

    In the interval of the Triassic-Jurassic boundary up to 80% of marine species became extinct. The main hypotheses on the causes of this mass extinction are reviewed. The extinction was triggered by a powerful eruption of basalts in the Central Atlantic Magmatic Province. In addition, several impact craters have been found. Extraterrestrial factors resulted in two main sequences of events: terrestrial, leading to strong volcanism, and extraterrestrial (impact events). They produced similar effects: emissions of harmful chemical compounds and aerosols. Consequences included the greenhouse effect, darkening of the atmosphere (which prevented photosynthesis), stagnation of the oceans, and anoxia. Biological productivity decreased; food chains collapsed. As a result, all vital processes were disturbed, and a large portion of the biota went extinct.

  2. Observation of aerosol parameters at Saga using GOSAT product validation lidar

    NASA Astrophysics Data System (ADS)

    Takubo, Shoichiro; Okumura, Hiroshi; Kawasaki, Takeru; Abdullah, Indra Nugraha; Uchino, Osamu; Morino, Isamu; Yokota, Tatsuya; Nagai, Tomohiro; Sakai, Tetsu; Maki, Takashi; Arai, Kohei

    2012-11-01

    Greenhouse gases Observation SATellite (GOSAT) was launched to enable the precise monitoring of the density of carbon dioxide by combining global observation data sent from space with data obtained on land, and with simulation models. In addition, observation of methane, another greenhouse gas, has been considered. For validation of GOSAT data products, ground-base observation with Fourier Transform Spectrometer (FTS), aerosol lidar and ozone-DIAL (DIfferencial Absorption Lidar) at Saga University, JAPAN has been continued since March, 2011. In this article, observation results obtained from aerosol lidar are reported.

  3. On the Physics of Fizziness: How liquid properties control bursting bubble aerosol production?

    NASA Astrophysics Data System (ADS)

    Ghabache, Elisabeth; Antkowiak, Arnaud; Josserand, Christophe; Seon, Thomas

    2014-11-01

    Either in a champagne glass or at the oceanic scales, the tiny capillary bubbles rising at the surface burst in ejecting myriads of droplets. Focusing on the ejected droplets produced by a single bubble, we investigate experimentally how liquid properties and bubble size affect their characteristics: number, ejection velocities, sizes and ejection heights. These results allow us to finely tune the bursting bubble aerosol production. In the context of champagne industry, aerosols play a major role by spreading wine aroma above the glass. We demonstrate that this champagne fizz can be enhanced by selecting the wine viscosity and the bubble size, thanks to specially designed glass.

  4. A decadal regional and global trend analysis of the aerosol optical depth using a data-assimilation grade over-water MODIS and Level 2 MISR aerosol products

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Reid, J. S.

    2010-08-01

    Using the ten-year (2000-2009) DA quality Terra MODIS and MISR aerosol products, as well as 7 years of Aqua MODIS, we studied both regional and global aerosol trends over oceans. This included both natural and data assimilation grade versions of the products. Contrary to some of the previous studies that showed a decreasing trend in aerosol optical depth (AOD) over global oceans, after correcting for what appears to be aerosol signal drift from the radiometric calibration of both MODIS instruments, we found MODIS and MISR agreed on a statistically negligible global trend of 0.0003/per year. Our study also suggests that AODs over the Indian Bay of Bengal, east coast of Asia, and Arabian Sea show statistically significant increasing trends of 0.07, 0.06, and 0.06 per ten years for MODIS, respectively. Similar increasing trends were found from MISR, but with less relative magnitude. These trends reflect respective increases in the optical intensity of aerosol events in each region: anthropogenic aerosols over the east coast of China and Indian Bay of Bengal; and a stronger influence from dust events over the Arabian Sea. Negative AOD trends are found off Central America, the east coast of North America, and the west coast of Africa. However, confidence levels are low in these regions, which indicate that longer periods of observation are necessary to be conclusive.

  5. ALE: Astronomical LIDAR for Extinction

    NASA Astrophysics Data System (ADS)

    Zimmer, Peter C.; McGraw, J. T.; Gimmestad, G.; Roberts, D.; Stewart, J.; Dawsey, M.; Fitch, J.; Smith, J.; Townsend, A.; Black, B.

    2006-12-01

    The primary impediment to precision all-sky photometry is the scattering or absorption of incoming starlight by the aerosols suspended in, and the molecules of, the Earth's atmosphere. The University of New Mexico (UNM) and the Georgia Tech Research Institute (GTRI) are currently developing the Astronomical LIDAR (LIght Detection And Ranging) for Extinction (ALE), which is undergoing final integration and initial calibration at UNM. ALE is based upon a 527nm laser operated at a pulse repetition rate of 1500 pps, and rendered eyesafe by expanding its beam through a 32cm diameter transmitter. The alt-az mounted ALE will operate in multiple modes, including mapping the sky to obtain a quantitative measurement of extinction sources, measuring a monochromatic extinction coefficient by producing Langely plots, and monitoring extinction in the direction in which a telescope is observing. A primary goal is to use the Rayleigh scattered LIDAR return from air above 20km as a quasi-constant illumination source. Air above this altitude is generally free from aerosols and the variations in density are relatively constant over intervals of a few minutes. When measured at several zenith angles, the integrated line-of-sight extinction can be obtained from a simple model fit of these returns. The 69 microjoule exit pulse power and 0.6m aperture receiver will allow ALE to collect approximately one million photons per minute from above 20km, enough to enable measurements of the monochromatic vertical extinction to better than 1% under photometric conditions. Along the way, ALE will also provide a plethora of additional information about the vertical and horizontal distributions of low-lying aerosols, dust or smoke in the free troposphere, and high cirrus, as well as detect the passage of boundary layer atmospheric gravity waves. This project is funded by NSF Grant 0421087.

  6. Comparison of Aerosol Classification From Airborne High Spectral Resolution Lidar and the CALIPSO Vertical Feature Mask

    NASA Technical Reports Server (NTRS)

    Burton, Sharon P.; Ferrare, Rich A.; Omar, Ali H.; Vaughan, Mark A.; Rogers, Raymond R.; Hostetler, Chris a.; Hair, Johnathan W.; Obland, Michael D.; Butler, Carolyn F.; Cook, Anthony L.; Harper, David B.

    2012-01-01

    Knowledge of aerosol composition and vertical distribution is crucial for assessing the impact of aerosols on climate. In addition, aerosol classification is a key input to CALIOP aerosol retrievals, since CALIOP requires an inference of the lidar ratio in order to estimate the effects of aerosol extinction and backscattering. In contrast, the NASA airborne HSRL-1 directly measures both aerosol extinction and backscatter, and therefore the lidar ratio (extinction-to-backscatter ratio). Four aerosol intensive properties from HSRL-1 are combined to infer aerosol type. Aerosol classification results from HSRL-1 are used here to validate the CALIOP aerosol type inferences.

  7. Observed aerosol-induced radiative effect on plant productivity in the eastern United States

    NASA Astrophysics Data System (ADS)

    Strada, S.; Unger, N.; Yue, X.

    2015-12-01

    We apply satellite observations of aerosol optical depth (AOD) in conjunction with flux tower-derived estimates of gross primary productivity (GPP) to probe the relationship between atmospheric aerosol loading and carbon uptake rate at 10 select sites (4 deciduous broadleaf, 3 cropland, 1 evergreen needle leaf, 1 mixed forest and 1 grassland) on hourly time scales in the growing season in the eastern United States. For deciduous and mixed forests, the aerosol light scattering increases GPP with a maximum effect observed under polluted conditions (AOD >0.6), when diffuse radiation is 40-60%. During midday hours, high AOD conditions (>0.4) enhance plant productivity by ∼13% in deciduous forests. In contrast, we find that high diffuse light fraction does not increase the carbon uptake rate in croplands and grasslands; for these ecosystems, we estimate that high AOD conditions reduce GPP by ∼17% during midday hours. Our findings are consistent with previous studies that have attributed these contrasting response sensitivities to the complex and closed canopy architecture of forests versus crops and grasslands. C4 but not C3 crops may benefit from pollution-induced changes in diffuse and direct light. Further research is needed to investigate the role of local meteorology as a possible confounder in the connection between atmospheric aerosols and plant productivity.

  8. Hygroscopicity of dicarbonyl-amine secondary organic aerosol products investigated with HTDMA

    NASA Astrophysics Data System (ADS)

    Hawkins, L. N.; de Haan, D. O.

    2010-12-01

    Recent studies have shown the importance of amine-dicarbonyl chemistry as a secondary organic aerosol (SOA) formation pathway, producing imines, imidazoles, and N-containing oligomers. Preliminary work in our group has suggested that some of these products may be surface active. Therefore, the presence of these products may result in important changes to submicron particle hygroscopicity that affect aerosol scattering and cloud condensation nuclei (CCN) activity, especially in regions with significant amine-containing particles. To investigate their hygroscopicity, we have designed a hygroscopicity tandem differential mobility analyzer (HTDMA) system around a 300 L Teflon chamber that allows for longer humidification times needed for some organic aerosol components that are only slightly hygroscopic. This modification provides a range of residence times from 2.5 minutes up to 1 hour, unlike previously published systems that vary from 2-30 seconds. Using the modified hygroscopicity tandem differential mobility analyzer (HTDMA), we have measured the hygroscopic growth factor (HGF) of SOA formed from reactions of glyoxal (and methylglyoxal) with methylamine, ammonium sulfate, and several amino acids. Changes to inorganic aerosol HGF in response to the presence of SOA products are also investigated.

  9. Extinctions of life

    NASA Technical Reports Server (NTRS)

    Sepkoski, J. J. Jr; Sepkoski JJ, J. r. (Principal Investigator)

    1988-01-01

    This meeting presentation examines mass extinctions through earth's history. Extinctions are charted for marine families and marine genera. Timing of marine genera extinctions is discussed. Periodicity in extinctions during the Mesozoic and Cenozoic eras is plotted and compared with Paleozoic extinction peaks. The role of extinction in evolution and mankind's role in present extinctions are examined.

  10. Comparison of Multi-angle Imaging SpectroRadiometer (MISR) joint aerosol product with high-resolution model output

    NASA Astrophysics Data System (ADS)

    Kalashnikova, O.; Lee, H.; Suzuki, K.; Braverman, A. J.

    2014-12-01

    The Multi-angle Imaging SpectroRadiometer (MISR) Level 3 Joint Aerosol product (JOINT_AS) provides global, descriptive summary of MISR Level 2 aerosol optical thickness (AOT) for eight different types of aerosols at 5 x 5 degrees of horizontal resolution in each month between March 2000 and present. Using Version 22 JOINT_AS, this study analyzed characteristics of the observed AOT distributions and compared various statistical moments of aerosol optical thickness derived from JOINT_AS with the results from Nonhydrostatic Icosahedral Atmospheric Model (NICAM) simulation. Overall, marginal distributions of AOT show highly positive skewness at many grid points. Some of the large skewness values are related to the problems in MISR's retrieval algorithm. For example, the positive skewness in AOT for strongly absorbing aerosols at mid- and high latitudes in winter results from few outlier values is due to cloud contamination over a wide area. Combined AOT for multiple MISR aerosol types is comparable to the AOT for carbonaceous, sulfate aerosols and dust particles from the NICAM simulation implemented with aerosol transport processes. NICAM's carbonaceous aerosols in the Southwest Africa show good agreement with MISR's strongly absorbing aerosols. The AOT of dust particles in MISR and NICAM exhibit similar spatial patterns over the Sahara desert. The AOT of nonabsorbing aerosols in MISR well represents spatial distributions of the sulfate aerosols originating from industrial complex over the Shandong Peninsula in China. Our results indicate that MISR's AOT for each aerosol type may be useful for monitoring biomass burning, dust storms and air pollution and evaluating chemistry climate models.

  11. Australian Extinctions

    ERIC Educational Resources Information Center

    Science Teacher, 2005

    2005-01-01

    Massive extinctions of animals and the arrival of the first humans in ancient Australia--which occurred 45,000 to 55,000 years ago--may be linked. Researchers at the Carnegie Institution, University of Colorado, Australian National University, and Bates College believe that massive fires set by the first humans may have altered the ecosystem of…

  12. Formation and evolution of molecular products in α-pinene secondary organic aerosol.

    PubMed

    Zhang, Xuan; McVay, Renee C; Huang, Dan D; Dalleska, Nathan F; Aumont, Bernard; Flagan, Richard C; Seinfeld, John H

    2015-11-17

    Much of our understanding of atmospheric secondary organic aerosol (SOA) formation from volatile organic compounds derives from laboratory chamber measurements, including mass yield and elemental composition. These measurements alone are insufficient to identify the chemical mechanisms of SOA production. We present here a comprehensive dataset on the molecular identity, abundance, and kinetics of α-pinene SOA, a canonical system that has received much attention owing to its importance as an organic aerosol source in the pristine atmosphere. Identified organic species account for ∼58-72% of the α-pinene SOA mass, and are characterized as semivolatile/low-volatility monomers and extremely low volatility dimers, which exhibit comparable oxidation states yet different functionalities. Features of the α-pinene SOA formation process are revealed for the first time, to our knowledge, from the dynamics of individual particle-phase components. Although monomeric products dominate the overall aerosol mass, rapid production of dimers plays a key role in initiating particle growth. Continuous production of monomers is observed after the parent α-pinene is consumed, which cannot be explained solely by gas-phase photochemical production. Additionally, distinct responses of monomers and dimers to α-pinene oxidation by ozone vs. hydroxyl radicals, temperature, and relative humidity are observed. Gas-phase radical combination reactions together with condensed phase rearrangement of labile molecules potentially explain the newly characterized SOA features, thereby opening up further avenues for understanding formation and evolution mechanisms of α-pinene SOA. PMID:26578760

  13. Aircraft Measurements of BrO, IO, Glyoxal, NO2, H2O, O2-O2 and Aerosol Extinction Profiles in the Tropics: Comparison with Aircraft-/Ship-Based in Situ and Lidar Measurements

    NASA Technical Reports Server (NTRS)

    Volkamer, R.; Baidar, S.; Campos, T. L.; Coburn, S.; DiGangi, J. P.; Dix, B.; Eloranta, E. W.; Koenig, T. K.; Morley, B.; Ortega, I.; Pierce, B. R.; Reeves, M.; Sinreich, R.; Wang, S.; Zondlo, M. A.; Romashkin, P. A.

    2015-01-01

    Tropospheric chemistry of halogens and organic carbon over tropical oceans modifies ozone and atmospheric aerosols, yet atmospheric models remain largely untested for lack of vertically resolved measurements of bromine monoxide (BrO), iodine monoxide (IO) and small oxygenated hydrocarbons like glyoxal (CHOCHO) in the tropical troposphere. BrO, IO, glyoxal, nitrogen dioxide (NO2), water vapor (H2O) and O2-O2 collision complexes (O4/ were measured by the University of Colorado Airborne Multi-AXis Differential Optical Absorption Spectroscopy (CU AMAXDOAS) instrument, aerosol extinction by high spectral resolution lidar (HSRL), in situ aerosol size distributions by an ultra high sensitivity aerosol spectrometer (UHSAS) and in situ H2O by vertical-cavity surface-emitting laser (VCSEL) hygrometer. Data are presented from two research flights (RF12, RF17) aboard the National Science Foundation/ National Center for Atmospheric Research Gulfstream V aircraft over the tropical Eastern Pacific Ocean (tEPO) as part of the "Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated hydrocarbons" (TORERO) project (January/February 2012). We assess the accuracy of O4 slant column density (SCD) measurements in the presence and absence of aerosols. Our O4-inferred aerosol extinction profiles at 477 nm agree within 6% with HSRL in the boundary layer and closely resemble the renormalized profile shape of Mie calculations constrained by UHSAS at low (sub-Rayleigh) aerosol extinction in the free troposphere. CU AMAX-DOAS provides a flexible choice of geometry, which we exploit to minimize the SCD in the reference spectrum (SCDREF, maximize signal-to-noise ratio) and to test the robustness of BrO, IO and glyoxal differential SCDs. The RF12 case study was conducted in pristine marine and free tropospheric air. The RF17 case study was conducted above the NOAA RV Ka'imimoana (TORERO cruise, KA-12-01) and provides independent validation data from ship-based in situ cavity

  14. Aircraft measurements of BrO, IO, glyoxal, NO2, H2O, O2-O2 and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements

    NASA Astrophysics Data System (ADS)

    Volkamer, R.; Baidar, S.; Campos, T. L.; Coburn, S.; DiGangi, J. P.; Dix, B.; Eloranta, E. W.; Koenig, T. K.; Morley, B.; Ortega, I.; Pierce, B. R.; Reeves, M.; Sinreich, R.; Wang, S.; Zondlo, M. A.; Romashkin, P. A.

    2015-05-01

    Tropospheric chemistry of halogens and organic carbon over tropical oceans modifies ozone and atmospheric aerosols, yet atmospheric models remain largely untested for lack of vertically resolved measurements of bromine monoxide (BrO), iodine monoxide (IO) and small oxygenated hydrocarbons like glyoxal (CHOCHO) in the tropical troposphere. BrO, IO, glyoxal, nitrogen dioxide (NO2), water vapor (H2O) and O2-O2 collision complexes (O4) were measured by the University of Colorado Airborne Multi-AXis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS) instrument, aerosol extinction by high spectral resolution lidar (HSRL), in situ aerosol size distributions by an ultra high sensitivity aerosol spectrometer (UHSAS) and in situ H2O by vertical-cavity surface-emitting laser (VCSEL) hygrometer. Data are presented from two research flights (RF12, RF17) aboard the National Science Foundation/National Center for Atmospheric Research Gulfstream V aircraft over the tropical Eastern Pacific Ocean (tEPO) as part of the "Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated hydrocarbons" (TORERO) project (January/February 2012). We assess the accuracy of O4 slant column density (SCD) measurements in the presence and absence of aerosols. Our O4-inferred aerosol extinction profiles at 477 nm agree within 6% with HSRL in the boundary layer and closely resemble the renormalized profile shape of Mie calculations constrained by UHSAS at low (sub-Rayleigh) aerosol extinction in the free troposphere. CU AMAX-DOAS provides a flexible choice of geometry, which we exploit to minimize the SCD in the reference spectrum (SCDREF, maximize signal-to-noise ratio) and to test the robustness of BrO, IO and glyoxal differential SCDs. The RF12 case study was conducted in pristine marine and free tropospheric air. The RF17 case study was conducted above the NOAA RV Ka'imimoana (TORERO cruise, KA-12-01) and provides independent validation data from ship-based in situ cavity

  15. A consistent aerosol optical depth (AOD) dataset over mainland China by integration of several AOD products

    NASA Astrophysics Data System (ADS)

    Xu, H.; Guang, J.; Xue, Y.; de Leeuw, Gerrit; Che, Y. H.; Guo, Jianping; He, X. W.; Wang, T. K.

    2015-08-01

    The Moderate Resolution Imaging Spectroradiometer (MODIS), the Multiangle Imaging Spectroradiometer (MISR) and the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) provide validated aerosol optical depth (AOD) products over both land and ocean. However, the values of the AOD provided by each of these satellites may show spatial and temporal differences due to the instrument characteristics and aerosol retrieval algorithms used for each instrument. In this article we present a method to produce an AOD data set over Asia for the year 2007 based on fusion of the data provided by different instruments and/or algorithms. First, the bias of each satellite-derived AOD product was calculated by comparison with ground-based AOD data derived from the AErosol RObotic NETwork (AERONET) and the China Aerosol Remote Sensing NETwork (CARSNET) for different values of the surface albedo and the AOD. Then, these multiple AOD products were combined using the maximum likelihood estimate (MLE) method using weights derived from the root mean square error (RMSE) associated with the accuracies of the original AOD products. The original and merged AOD dataset has been validated by comparison with AOD data from the CARSNET. Results show that the mean bias error (MBE) and mean absolute error (MAE) of the merged AOD dataset are not larger than that of any of the original AOD products. In addition, for the merged AOD dataset the fraction of pixels with no data is significantly smaller than that of any of the original products, thus increasing the spatial coverage. The fraction of retrievable area is about 50% for the merged AOD dataset and between 5% and 20% for the MISR, SeaWiFS, MODIS-DT and MODIS-DB algorithms.

  16. Monoterpene oxidation products and organosulfates in aerosols during BEARPEX 2007 and 2009

    NASA Astrophysics Data System (ADS)

    Glasius, Marianne; Kristensen, Kasper; Worton, David R.; Goldstein, Allen H.

    2010-05-01

    Organosulfate esters of oxidation products of monoterpenes and isoprene have been identified in aerosols from both laboratory and field studies. While the exact route of formation of organosulfates is still ambiguous, these compounds pose an interesting coupling between anthropogenic emissions and biogenic oxidation products in secondary organic aerosols (SOA). We present measurements of monoterpene oxidation products, organosulfates and nitroxy organosulfates in aerosols collected during the Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX) in California during late summer 2007 and summer 2009. The study site was located in a Ponderosa pine plantation affected by regional transport of air pollutants. Particles (PM2.5) were collected as one night-time and two daytime samples per day using a high volume sampler. After extraction of filters, polar organic compounds were analysed by HPLC coupled through an electrospray inlet to a quadrupole time-of-flight mass spectrometer (qTOF-MS). Standards of adipic, cis-pinic and pinonic acids were used for quantification, while camphor sulphonic acid was used as a surrogate standard for organosulfate compounds. Organosulfate esters can be identified from their MS-fragments (HSO4- and SO3-) and the isotopic pattern of sulphur. Concentrations of adipic acid and the terpene oxidation products cis-pinic acid and pinonic acid (from α- and β-pinene) were quantified. The relative concentrations between samples of terpenylic acid, diterpenylic acid and 2-hydroxyterpenylic acid were also investigated. Organosulfate esters and nitroxy organosulfate esters of α-pinene, β-pinene, limonene and isoprene, as well as their oxidation products, were identified based on their molecular mass and fragmentation patterns. Concentrations of some nitroxy organosulfate esters generally increased during night compared to day-time. Their formation thus seems to be related to reactions involving nitrate radicals at night-time.

  17. A fixed frequency aerosol albedometer.

    PubMed

    Thompson, Jonathan E; Barta, Nick; Policarpio, Danielle; Duvall, Richard

    2008-02-01

    A new method for the measurement of aerosol single scatter albedo (omega) at 532 nm was developed. The method employs cavity ring-down spectroscopy (CRDS) for measurement of aerosol extinction coefficient (b(ext)) and an integrating sphere nephelometer for determination of aerosol scattering coefficient (b(scat)). A unique feature of this method is that the extinction and scattering measurements are conducted simultaneously, on the exact same sample volume. Limits of detection (3s) for the extinction and scattering channel were 0.61 Mm(-1) and 2.7 Mm(-1) respectively. PMID:18542299

  18. Hybridization and extinction.

    PubMed

    Todesco, Marco; Pascual, Mariana A; Owens, Gregory L; Ostevik, Katherine L; Moyers, Brook T; Hübner, Sariel; Heredia, Sylvia M; Hahn, Min A; Caseys, Celine; Bock, Dan G; Rieseberg, Loren H

    2016-08-01

    Hybridization may drive rare taxa to extinction through genetic swamping, where the rare form is replaced by hybrids, or by demographic swamping, where population growth rates are reduced due to the wasteful production of maladaptive hybrids. Conversely, hybridization may rescue the viability of small, inbred populations. Understanding the factors that contribute to destructive versus constructive outcomes of hybridization is key to managing conservation concerns. Here, we survey the literature for studies of hybridization and extinction to identify the ecological, evolutionary, and genetic factors that critically affect extinction risk through hybridization. We find that while extinction risk is highly situation dependent, genetic swamping is much more frequent than demographic swamping. In addition, human involvement is associated with increased risk and high reproductive isolation with reduced risk. Although climate change is predicted to increase the risk of hybridization-induced extinction, we find little empirical support for this prediction. Similarly, theoretical and experimental studies imply that genetic rescue through hybridization may be equally or more probable than demographic swamping, but our literature survey failed to support this claim. We conclude that halting the introduction of hybridization-prone exotics and restoring mature and diverse habitats that are resistant to hybrid establishment should be management priorities. PMID:27468307

  19. A decadal regional and global trend analysis of the aerosol optical depth using a data-assimilation grade over-water MODIS and Level 2 MISR aerosol products

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Reid, J. S.

    2010-11-01

    Using the ten-year (2000-2009) Data-Assimilation (DA) quality Terra MODIS and MISR aerosol products, as well as 7 years of Aqua MODIS, we studied both regional and global aerosol trends over oceans. This included both operational and data assimilation grade versions of the products. After correcting for what appears to be aerosol signal drift from the radiometric calibration of both MODIS instruments, we found MODIS and MISR agreed on a statistically negligible global trend of ±0.003/per decade. Our study also suggests that AODs over the Indian Bay of Bengal, east coast of Asia, and Arabian Sea show increasing trends of 0.07, 0.06, and 0.06 per decade for MODIS, respectively. These regional trends are considered as significant with a confidence level above 95%. Similar increasing trends were found from MISR, but with less relative magnitude. These trends reflect respective increases in the optical intensity of aerosol events in each region: anthropogenic aerosols over the east coast of China and Indian Bay of Bengal; and a stronger influence from dust events over the Arabian Sea. Negative AOD trends, low in confidence levels, are found off Central America, the east coast of North America, and the west coast of Africa, which indicate that longer periods of observation are necessary to be conclusive.

  20. Laser Remote Sensing from ISS: the CATS-CALIPSO Cloud and Aerosol Data Products

    NASA Astrophysics Data System (ADS)

    Rodier, S. D.; Palm, S. P.; Jensen, M. H.; Yorks, J. E.; McGill, M. J.; Vaughan, M.; Trepte, C. R.

    2014-12-01

    The NASA Cloud Aerosol Transport System (CATS) is a dual-beam, multi-wavelength (1064, 532 and 355 nm), polarization sensitive (1064 and 532 nm) lidar developed at NASA's Goddard Space Flight Center (GSFC) for deployment to the International Space Station (ISS) in late 2014. CATS will be mounted on the Japanese Experiment Module's Exposed Facility and will provide near-continuous, altitude-resolved measurements of clouds and aerosols in the Earth's atmosphere. The ISS orbit path provides a unique opportunity to capture the full diurnal cycle of cloud and aerosol development and transport, allowing for studies that are not possible with the lidar aboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) mission, which flies in the sun-synchronous A-Train orbit. One of the primary objectives of CATS is to continue the CALIPSO data record to provide continuity of aerosol and cloud lidar observations during the transition from CALIPSO to EarthCARE. To accomplish this, the CATS project at GSFC and the CALIPSO project at NASA's Langley Research Center are closely collaborating to develop and deliver a full suite of CALIPSO-like level 2 data products generated from the newly acquired CATS level 1B data. Now in its eighth year of on-orbit operations, the CALIPSO project has developed a robust set of mature and well-validated science algorithms to retrieve the spatial and optical properties of clouds and aerosols from multi-wavelength lidar backscatter signal. By leveraging both new and existing NASA technical resources, this joint effort by the CATS-CALIPSO team will enable rapid delivery of high-quality lidar data sets to the user community at the earliest possible opportunity. In this work we outline the development of the CALIPSO- CATS level 2 software and data products and describe the modifications made to the input CATS data stream and the CALIPSO processing algorithms in order to successfully interface two disparate data processing

  1. United role of radon decay products and nano-aerosols in radon dosimetry

    NASA Astrophysics Data System (ADS)

    Smerajec, M.; Vaupotič, J.

    2012-04-01

    The major part of human exposure to natural radiation originates from inhalation of radon (Rn) and radon short-lived decay products (RnDP: 218Po, 214Pb, 214Bi and 214Po). RnDP are formed as a result of α-transformation of radon. In the beginning they are positive ions which neutralize and form clusters with air molecules, and later partly attach to background aerosol particles in indoor air. Eventually, they appear as radioactive nano-aerosols with a bimodal size distribution in ranges of 1-10 nm (unattached RnDP) and of 200-800 nm (attached RnDP). When inhaled, they are deposited in the respiratory tract. Deposition is more efficient for smaller particles. Therefore, the fraction (fun) of the unattached RnDP, which appears to be influenced by the number concentration and size distribution of general (background) aerosols in the ambient air, has a crucial role in radon dosimetry. Radon, radon decay products and general aerosols have been monitored simultaneously in the kitchen of a typical rural house under real living conditions, also comprising four human activities generating particular matter: cooking and baking, as two typical activities in kitchen, and cigarette smoking and candle burning. In periods without any human activity, the total number concentration of general aerosol ranged from 1000 to 3000 cm-3,with the geometric mean of particle diameter in the range of 60-68 nm and with 0.1-1 % of particles smaller than 10 nm. Preparation of coffee changed the concentration to 193,000 cm-3, the geometric mean of diameter to 20 nm and fraction of particles smaller than 10 nm to 11 %. The respective changes were for baking cake: 503,000 cm-3, 17 nm and 19 %, for smoking:423,000 cm-3, 83 nm and 0.4 %, and forcandle burning: 945,000 cm-3, 8 nm and 85 %. While, as expected, a reduction of fun was observed during cooking, baking and smoking, when larger particles were emitted, fun did not increase during candle burning with mostly particles smaller than 10 nm

  2. Factors Regulating the Size-Resolved Production and Composition of Nascent Marine Aerosols (Invited)

    NASA Astrophysics Data System (ADS)

    Keene, W. C.; Frossard, A.; Long, M. S.; Maben, J. R.; Russell, L. M.; Kieber, D. J.; Kinsey, J.; Bates, T. S.; Quinn, P.

    2010-12-01

    Bursting bubbles generated by breaking wind waves at the ocean surface are a major but poorly constrained global source for aerosol mass, volume, and number and associated reactive constituents all of which significantly influence the multiphase physicochemical evolution of Earth’s troposphere and climate. During a spring 2010 cruise of the R/V Atlantis in the eastern North Pacific Ocean, marine aerosols were produced in a high-capacity glass and Teflon generator by artificially injecting zero air into fresh flowing seawater via coarse (A) and fine (D) frits at 1.2 m depth and seawater jets impinging upon the surface. Size-resolved number concentrations and organic and inorganic composition, organic functional groups, bubble-plume volumes, and near-surface bubble sizes were characterized over ranges of bubble and seawater flow rates and headspace RH. Seawater temperature, salinity, and chlorophyll a concentrations were measured in parallel. Relative to fine frits, bubble-plume volumes generated with coarse frits were three times smaller due to the higher initial rise velocity and shorting lifetimes of larger bubbles. However, bubbles produced by both coarse and fine frits evolved in response to surface tension to similar size (0.2- to 0.5-mm diameter) near the water-air interface. Consequently, the two frit sizes produced similar number fluxes of size-resolved aerosols per unit volume air flux. Production fluxes of supermicron- and submicron-diameter size fractions varied as linear functions of air detrainment. Ranges in centroids for number size distributions of aerosols produced with coarse (70- to 100-nm dry diameter) and fine frits (60- to 80-nm dry diameter) overlapped. Centroids for size distributions produced by a bubbler-type generator deployed in open seawater adjacent to the ship ranged from 55- 60-nm dry diameter. Number-size distributions produced by water jets were shifted towards larger particles with centroids of 100- to 150-nm dry diameter

  3. Measurements of extinct fission products in nuclear bomb debris: Determination of the yield of the Trinity nuclear test 70 y later.

    PubMed

    Hanson, Susan K; Pollington, Anthony D; Waidmann, Christopher R; Kinman, William S; Wende, Allison M; Miller, Jeffrey L; Berger, Jennifer A; Oldham, Warren J; Selby, Hugh D

    2016-07-19

    This paper describes an approach to measuring extinct fission products that would allow for the characterization of a nuclear test at any time. The isotopic composition of molybdenum in five samples of glassy debris from the 1945 Trinity nuclear test has been measured. Nonnatural molybdenum isotopic compositions were observed, reflecting an input from the decay of the short-lived fission products (95)Zr and (97)Zr. By measuring both the perturbation of the (95)Mo/(96)Mo and (97)Mo/(96)Mo isotopic ratios and the total amount of molybdenum in the Trinity nuclear debris samples, it is possible to calculate the original concentrations of the (95)Zr and (97)Zr isotopes formed in the nuclear detonation. Together with a determination of the amount of plutonium in the debris, these measurements of extinct fission products allow for new estimates of the efficiency and yield of the historic Trinity test. PMID:27382169

  4. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  5. Revisiting Aerosol Effects in Global Climate Models Using an Aerosol Lidar Simulator

    NASA Astrophysics Data System (ADS)

    Ma, P. L.; Chepfer, H.; Winker, D. M.; Ghan, S.; Rasch, P. J.

    2015-12-01

    Aerosol effects are considered a major source of uncertainty in global climate models and the direct and indirect radiative forcings have strong model dependency. These forcings are routinely evaluated (and calibrated) against observations, among them satellite retrievals are greatly used for their near-global coverage. However, the forcings calculated from model output are not directly comparable with those computed from satellite retrievals since sampling and algorithmic differences (such as cloud screening, noise reduction, and retrieval) between models and observations are not accounted for. It is our hypothesis that the conventional model validation procedures for comparing satellite observations and model simulations can mislead model development and introduce biases. Hence, we have developed an aerosol lidar simulator for global climate models that simulates the CALIOP lidar signal at 532nm. The simulator uses the same algorithms as those used to produce the "GCM-oriented CALIPSO Aerosol Product" to (1) objectively sample lidar signal profiles; and (2) derive aerosol fields (e.g., extinction profile, aerosol type, etc) from lidar signals. This allows us to sample and derive aerosol fields in the model and real atmosphere in identical ways. Using the Department of Energy's ACME model simulations, we found that the simulator-retrieved aerosol distribution and aerosol-cloud interactions are significantly different from those computed from conventional approaches, and that the model is much closer to satellite estimates than previously believed.

  6. DETERMINATION OF SECONDARY ORGANIC AEROSOL PRODUCTS FROM THE PHOTOOXIDATION OF TOLUENE AND THEIR IMPLICATIONS IN AMBIENT PM2.5

    EPA Science Inventory

    Laboratory study was carried out to investigate the secondary organic aerosol products from photooxidation of the aromatic hydrocarbon toluene. The laboratory experiments consisted of irradiating toluene/propylene/NOX/air mixtures in a smog chamber operated in the dynamic mode...

  7. 3. Guidelines for efficacy testing of household insecticide products - Mosquito coils, vaporizer mats, liquid vaporizers, ambient emanators and aerosols

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This document provides specific and standardized procedures and criteria for efficacy testing and evaluation of specific household insecticide products intended for indoor use against mosquitoes, namely, mosquito coils, vaporizer mats, liquid vaporizers, ambient emanators and aerosols....

  8. Reactive processing of formaldehyde and acetaldehyde in aqueous aerosol mimics: surface tension depression and secondary organic products

    NASA Astrophysics Data System (ADS)

    Li, Z.; Schwier, A. N.; Sareen, N.; McNeill, V. F.

    2011-11-01

    The reactive uptake of carbonyl-containing volatile organic compounds (cVOCs) by aqueous atmospheric aerosols is a likely source of particulate organic material. The aqueous-phase secondary organic products of some cVOCs are surface-active. Therefore, cVOC uptake can lead to organic film formation at the gas-aerosol interface and changes in aerosol surface tension. We examined the chemical reactions of two abundant cVOCs, formaldehyde and acetaldehyde, in water and aqueous ammonium sulfate (AS) solutions mimicking tropospheric aerosols. Secondary organic products were identified using Aerosol Chemical Ionization Mass Spectrometry (Aerosol-CIMS), and changes in surface tension were monitored using pendant drop tensiometry. Hemiacetal oligomers and aldol condensation products were identified using Aerosol-CIMS. Acetaldehyde depresses surface tension to 65(±2) dyn cm-1 in pure water (a 10% surface tension reduction from that of pure water) and 62(±1) dyn cm-1 in AS solutions (a 20.6% reduction from that of a 3.1 M AS solution). Surface tension depression by formaldehyde in pure water is negligible; in AS solutions, a 9% reduction in surface tension is observed. Mixtures of these species were also studied in combination with methylglyoxal in order to evaluate the influence of cross-reactions on surface tension depression and product formation in these systems. We find that surface tension depression in the solutions containing mixed cVOCs exceeds that predicted by an additive model based on the single-species isotherms.

  9. Reactive processing of formaldehyde and acetaldehyde in aqueous aerosol mimics: surface tension depression and secondary organic products

    NASA Astrophysics Data System (ADS)

    Li, Z.; Schwier, A. N.; Sareen, N.; McNeill, V. F.

    2011-07-01

    The reactive uptake of carbonyl-containing volatile organic compounds (cVOCs) by aqueous atmospheric aerosols is a likely source of particulate organic material. The aqueous-phase secondary organic products of some cVOCs are surface-active. Therefore, cVOC uptake can lead to organic film formation at the gas-aerosol interface and changes in aerosol surface tension. We examined the chemical reactions of two abundant cVOCs, formaldehyde and acetaldehyde, in water and aqueous ammonium sulfate (AS) solutions mimicking tropospheric aerosols. Secondary organic products were identified using Aerosol Chemical Ionization Mass Spectrometry (Aerosol-CIMS), and changes in surface tension were monitored using pendant drop tensiometry. Hemiacetal oligomers and aldol condensation products were identified using Aerosol-CIMS. A hemiacetal sulfate ester was tentatively identified in the formaldehyde-AS system. Acetaldehyde depresses surface tension to 65(±2) dyn cm-1 in pure water and 62(±1) dyn cm-1 in AS solutions. Surface tension depression by formaldehyde in pure water is negligible; in AS solutions, a 9 % reduction in surface tension is observed. Mixtures of these species were also studied in combination with methylglyoxal in order to evaluate the influence of cross-reactions on surface tension depression and product formation in these systems. We find that surface tension depression in the solutions containing mixed cVOCs exceeds that predicted by an additive model based on the single-species isotherms.

  10. A new operational EUMETSAT product for the retrieval of aerosol optical properties over land (PMAp v2)

    NASA Astrophysics Data System (ADS)

    Grzegorski, Michael; Munro, Rosemary; Poli, Gabriele; Holdak, Andriy; Lang, Ruediger

    2016-04-01

    The retrieval of aerosol optical properties is an important task to provide data for industry and climate forecasting. An ideal instrument should include observations with moderate spectral and high spatial resolution for a wide range of wavelengths (from the UV to the TIR), measurements of the polarization state at different wavelengths and measurements of the same scene for different observation geometries. As such an ideal instrument is currently unavailable the usage of different instruments on one satellite platform is an alternative choice. Since February 2014, the Polar Multi sensor Aerosol product (PMAp) has been delivered as an operational GOME product to our customers. The algorithm retrieves aerosol optical properties over ocean (AOD, volcanic ash, aerosol type) using a multi-sensor approach (GOME, AVHRR, IASI). The product is now extended to pixels over land using a new release of the operational PMAp processor (PMAp v2). The pre-operational data dissemination of the new PMAp v2 data to our users is scheduled for March 2016. This presentation gives an overview on the new operational product PMAp v2 with a focus on the validation of the PMAp aerosol optical depth over land. The impact of different error sources on the results (e.g. surface contribution to the TOA reflectance) is discussed. We also show first results of upcoming extensions of our PMAp processor, in particular the improvement of the cloud/aerosol discrimination of thick aerosol events (e.g. volcanic ash plumes, desert dust outbreaks).

  11. Aerosol characterization with lidar methods

    NASA Astrophysics Data System (ADS)

    Sugimoto, Nobuo; Nishizawa, Tomoaki; Shimizu, Atsushi; Matsui, Ichiro

    2014-08-01

    Aerosol component analysis methods for characterizing aerosols were developed for various types of lidars including polarization-sensitive Mie scattering lidars, multi-wavelength Raman scattering lidars, and multi-wavelength highspectral- resolution lidars. From the multi-parameter lidar data, the extinction coefficients for four aerosol components can be derived. The microphysical parameters such as single scattering albedo and effective radius can be also estimated from the derived aerosol component distributions.

  12. The influence of marine microbial activities on aerosol production: A laboratory mesocosm study

    NASA Astrophysics Data System (ADS)

    Alpert, Peter A.; Kilthau, Wendy P.; Bothe, Dylan W.; Radway, JoAnn C.; Aller, Josephine Y.; Knopf, Daniel A.

    2015-09-01

    The oceans cover most of the Earth's surface, contain nearly half the total global primary biomass productivity, and are a major source of atmospheric aerosol particles. Here we experimentally investigate links between biological activity in seawater and sea spray aerosol (SSA) flux, a relationship of potential significance for organic aerosol loading and cloud formation over the oceans and thus for climate globally. Bubbles were generated in laboratory mesocosm experiments either by recirculating impinging water jets or glass frits. Experiments were conducted with Atlantic Ocean seawater collected off the eastern end of Long Island, NY, and with artificial seawater containing cultures of bacteria and phytoplankton Thalassiosira pseudonana, Emiliania huxleyi, and Nannochloris atomus. Changes in SSA size distributions occurred during all phases of bacterial and phytoplankton growth, as characterized by cell concentrations, dissolved organic carbon, total particulate carbon, and transparent exopolymer particles (gel-forming polysaccharides representing a major component of biogenic exudate material). Over a 2 week growth period, SSA particle concentrations increased by a factor of less than 2 when only bacteria were present and by a factor of about 3 when bacteria and phytoplankton were present. Production of jet-generated SSA particles of diameter less than 200 nm increased with time, while production of all particle diameters increased with time when frits were used. The implications of a marine biological activity dependent SSA flux are discussed.

  13. Stratospheric aerosol particle size information in Odin-OSIRIS limb scatter spectra

    NASA Astrophysics Data System (ADS)

    Rieger, L. A.; Bourassa, A. E.; Degenstein, D. A.

    2014-02-01

    The Optical Spectrograph and InfraRed Imaging System (OSIRIS) onboard the Odin satellite has now taken over a decade of limb scatter measurements that have been used to retrieve the version 5 stratospheric aerosol extinction product. This product is retrieved using a representative particle size distribution to calculate scattering cross sections and scattering phase functions for the forward model calculations. In this work the information content of OSIRIS measurements with respect to stratospheric aerosol is systematically examined for the purpose of retrieving particle size information along with the extinction coefficient. The benefit of using measurements at different wavelengths and scattering angles in the retrieval is studied, and it is found that incorporation of the 1530 nm radiance measurement is key for a robust retrieval of particle size information. It is also found that using OSIRIS measurements at the different solar geometries available on the Odin orbit simultaneously provides little additional benefit. Based on these results, an improved aerosol retrieval algorithm is developed that couples the retrieval of aerosol extinction and mode radius of a log-normal particle size distribution. Comparison of these results with coincident measurements from SAGE III shows agreement in retrieved extinction to within approximately 10% over the bulk of the aerosol layer, which is comparable to version 5. The retrieved particle size, when converted to Ångström coefficient, shows good qualitative agreement with SAGE II measurements made at somewhat shorter wavelengths.

  14. Aerosol Correction for Improving OMPS/LP Ozone Retrieval

    NASA Technical Reports Server (NTRS)

    Chen, Zhong; Bhartia, Pawan K.; Loughman, Robert

    2015-01-01

    The Ozone Mapping and Profiler Suite Limb Profiler (OMPS-LP) on board the Suomi National Polar-orbiting Partnership (SNPP) satellite was launched on Oct. 28, 2011. Limb profilers measures the radiance scattered from the Earth's atmospheric in limb viewing mode from 290 to 1000 nm and infer ozone profiles from tropopause to 60 km. The recently released OMPS-LP Version 2 data product contains the first publicly released ozone profiles retrievals, and these are now available for the entire OMPS mission, which extends from April, 2012. The Version 2 data product retrievals incorporate several important improvements to the algorithm. One of the primary changes is to turn off the aerosol retrieval module. The aerosol profiles retrieved inside the ozone code was not helping the ozone retrieval and was adding noise and other artifacts. Aerosols including polar stratospheric cloud (PSC) and polar mesospheric clouds (PMC) have a detectable effect on OMPS-LP data. Our results show that ignoring the aerosol contribution would produce an ozone density bias of up to 10 percent in the region of maximum aerosol extinction. Therefore, aerosol correction is needed to improve the quality of the retrieved ozone concentration profile. We provide Aerosol Scattering Index (ASI) for detecting aerosols-PMC-PSC, defined as ln(Im-Ic) normalized at 45km, where Im is the measured radiance and Ic is the calculated radiance assuming no aerosols. Since ASI varies with wavelengths, latitude and altitude, we can start by assuming no aerosol profiles in calculating the ASIs and then use the aerosol profile to see if it significantly reduces the residuals. We also discuss the effect of aerosol size distribution on the ozone profile retrieval process. Finally, we present an aerosol-PMC-PSC correction scheme.

  15. Aerosol composition and variability in the Baltimore-Washington, DC region

    NASA Astrophysics Data System (ADS)

    Beyersdorf, A. J.; Ziemba, L. D.; Chen, G.; Corr, C. A.; Crawford, J. H.; Diskin, G. S.; Moore, R. H.; Thornhill, K. L.; Winstead, E. L.; Anderson, B. E.

    2015-08-01

    in the free troposphere (above 3 km). Routine airborne sampling over six locations was used to evaluate the relative contributions of aerosol loading, composition, and relative humidity (the amount of water available for uptake onto aerosols) to variability in mixed layer aerosol. Aerosol loading was found to be the predominant source accounting for 88 % on average of the measured spatial variability in extinction with lesser contributions from variability in relative humidity (10 %) and aerosol composition (1.3 %). On average, changes in aerosol loading also caused 82 % of the diurnal variability in ambient aerosol extinction. However on days with relative humidity above 60 %, variability in RH was found to cause up to 62 % of the spatial variability and 95 % of the diurnal variability in ambient extinction. This work shows that extinction is driven to first-order by aerosol mass loadings; however, humidity-driven hydration effects play an important secondary role. This motivates combined satellite/modelling assimilation products that are able to capture these components of the AOD-PM2.5 link. Conversely, aerosol hygroscopicity and SSA play a minor role in driving variations both spatially and throughout the day in aerosol extinction and therefore AOD. However, changes in aerosol hygroscopicity from day-to-day were large and could cause a bias of up to 27 % if not accounted for. Thus it appears that a single daily measurement of aerosol hygroscopicity can be used for AOD-to-PM2.5 conversions over the study region (on the order of 1400 km2). This is complimentary to the results of Chu et al. (2015) that determined the aerosol vertical distribution from "a single lidar is feasible to cover the range of 100 km" in the same region.

  16. Mechanism for production of secondary organic aerosols and their representation in atmospheric models. Final report

    SciTech Connect

    Seinfeld, J.H.; Flagan, R.C.

    1999-06-07

    This document contains the following: organic aerosol formation from the oxidation of biogenic hydrocarbons; gas/particle partitioning of semivolatile organic compounds to model inorganic, organic, and ambient smog aerosols; and representation of secondary organic aerosol formation in atmospheric models.

  17. Development, Application, and Transition of Aerosol and Trace Gas Products Derived from Next-Generation Satellite Observations to Operations

    NASA Technical Reports Server (NTRS)

    Berndt, Emily; Naeger, Aaron; Zavodsky, Bradley; McGrath, Kevin; LaFontaine, Frank

    2016-01-01

    NASA Short-term Prediction Research and Transition (SPoRT) Center has a history of successfully transitioning unique observations and research capabilities to the operational weather community to improve short-term forecasts. SPoRTstrives to bridge the gap between research and operations by maintaining interactive partnerships with end users to develop products that match specific forecast challenges, provide training, and assess the products in the operational environment. This presentation focuses on recent product development, application, and transition of aerosol and trace gas products to operations for specific forecasting applications. Recent activities relating to the SPoRT ozone products, aerosol optical depth composite product, sulfur dioxide, and aerosol index products are discussed.

  18. Secondary organic aerosol formation from m-xylene photooxidation: The role of the phenolic product

    NASA Astrophysics Data System (ADS)

    Nakao, S.; Qi, L.; Clark, C.; Sato, K.; Tang, P.; Cocker, D.

    2009-12-01

    Aromatic hydrocarbons comprise a significant fraction of volatile organic compounds in the urban atmosphere and their importance as precursors to secondary organic aerosols (SOA) has been widely recognized. However, SOA formation from aromatics is one of the least understood processes among all the classes of volatile organic compounds (VOCs) due to its complex multi-generation reactions. Phenolic compounds have been identified as one of the significant products from OH-initiated reaction of aromatic hydrocarbons and are suggested to have a very high potential of SOA formation (e.g., cresol isomers having SOA yield 9~42%, Henry et al., Atmos. Environ., 2008). We examined the effect of extent of oxidation of m-xylene on chemical composition and physical properties using m-xylene and xylenol as reactants in environmental chamber experiments. Chemical composition of SOA was investigated by Liquid Chromatography / Time of Flight Mass Spectrometer (LC/ToF-MS), and Aerodyne High Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS). Physical properties of SOA such as density, volatility, and hygroscopicity were investigated by Aerosol Particle Mass Analyzer - Scanning Mobility Particle Sizer (APM-SMPS), Hygroscopicity/Volatility - Tandem Differential Mobility Analyzer (H/V-TDMA), respectively. Also SOA yields were obtained to evaluate the importance of xylenol as an intermediate product.

  19. Laser Remote Sensing From ISS: CATS Cloud and Aerosol Level 2 Data Products (Heritage Edition)

    NASA Technical Reports Server (NTRS)

    Rodier, Sharon; Vaughan, Mark; Palm, Steve; Jensen, Mike; Yorks, John; McGill, Matt; Trepte, Chip; Murray, Tim; Lee, Kam-Pui

    2015-01-01

    The Cloud-Aerosol Transport System (CATS) instrument was developed at NASA's Goddard Space Flight Center (GSFC) and deployed to the International Space Station (ISS) on 10 January 2015. CATS is mounted on the Japanese Experiment Module's Exposed Facility (JEM_EF) and will provide near-continuous, altitude-resolved measurements of clouds and aerosols in the Earth's atmosphere. The CATS ISS orbit path provides a unique opportunity to capture the full diurnal cycle of cloud and aerosol development and transport, allowing for studies that are not possible with the lidar aboard the CALIPSO platform, which flies in the sun-synchronous A-Train orbit." " One of the primary science objectives of CATS is to continue the CALIPSO aerosol and cloud profile data record to provide continuity of lidar climate observations during the transition from CALIPSO to EarthCARE. To accomplish this, the CATS project at NASA's Goddard Space Flight Center (GSFC) and the CALIPSO project at NASA's Langley Research Center (LaRC) are closely collaborating to develop and deliver a full suite of CALIPSO-like level 2 data products that will be produced using the newly acquired CATS level 1B data whenever CATS is operating in science modes 1. The CALIPSO mission is now well into its ninth year of on-orbit operations, and has developed a robust set of mature and well-validated science algorithms to retrieve the spatial and optical properties of clouds and aerosols from multi-wavelength lidar backscatter signals. By leveraging both new and existing NASA technical resources, this joint effort by the CATS and CALIPSO teams will deliver validated lidar data sets to the user community at the earliest possible opportunity. The science community will have access to two sets of CATS Level 2 data products. The "Operational" data products will be produced by the GSFC CATS team utilizing the new instrument capabilities (e.g., multiple FOVs and 1064 nm depolarization), while the "Heritage" data products created

  20. A Novel Aerosol Method for the Production of Hydrogel Particles

    PubMed Central

    Guzman-Villanueva, Diana; Smyth, Hugh D. C.; Herrera-Ruiz, Dea; El-Sherbiny, Ibrahim M.

    2012-01-01

    A novel method of generating hydrogel particles for various applications including drug delivery purposes was developed. This method is based on the production of hydrogel particles from sprayed polymeric nano/microdroplets obtained by a nebulization process that is immediately followed by gelation in a crosslinking fluid. In this study, particle synthesis parameters such as type of nebulizer, type of crosslinker, air pressure, and polymer concentration were investigated for their impact on the mean particle size, swelling behavior, and morphology of the developed particles. Spherical alginate-based hydrogel particles with a mean particle size in the range from 842 to 886 nm were obtained. Using statistical analysis of the factorial design of experiment it was found that the main factors influencing the size and swelling values of the particles are the alginate concentration and the air pressure. Thus, it was demonstrated that the method described in the current study is promising for the generation of hydrogel particles and it constitutes a relatively simple and low-cost system. PMID:23687513

  1. Changes in environmental conditions as the cause of the marine biota Great Mass Extinction at the Triassic-Jurassic boundary

    NASA Astrophysics Data System (ADS)

    Barash, M. S.

    2016-02-01

    In the interval of the Triassic-Jurassic boundary, 80% of the marine species became extinct. Four main hypotheses about the causes of this mass extinction are considered: volcanism, climatic oscillations, sea level variations accompanied by anoxia, and asteroid impact events. The extinction was triggered by an extensive flooding of basalts in the Central Atlantic Magmatic Province. Furthermore, a number of meteoritic craters have been found. Under the effect of cosmic causes, two main sequences of events developed on the Earth: terrestrial ones, leading to intensive volcanism, and cosmic ones (asteroid impacts). Their aftermaths, however, were similar in terms of the chemical compounds and aerosols released. As a consequence, the greenhouse effect, dimming of the atmosphere (impeding photosynthesis), ocean stagnation, and anoxia emerged. Then, biological productivity decreased and food chains were destroyed. Thus, the entire ecosystem was disturbed and a considerable part of the biota became extinct.

  2. Photooxidation Products of Isoprene Epoxydiols (IEPOX) and IEPOX-Derived Secondary Organic Aerosol

    NASA Astrophysics Data System (ADS)

    Bates, K. H.; Nguyen, T. B.; Coggon, M. M.; Lignell, H.; Stoltz, B.; Wennberg, P. O.; Seinfeld, J.

    2014-12-01

    Isoprene epoxydiol (IEPOX) has recently been identified as a key intermediate in the photooxidation of isoprene under low-NO conditions and in the formation of isoprene-derived secondary organic aerosol (SOA). IEPOX is generally expected to react with OH in the gas phase, where it has been found to form predominantly C4O3H8 products, or undergo reactive uptake onto particles, where it is converted into 2-methyltetrols or organosulfates by acid- or ammonium-catalyzed mechanisms. The subsequent chemistry of these gas- and particle-phase products has not yet been explored. Using synthetic standards of IEPOX and its gas-phase products, we have performed environmental chamber and flow tube experiments to investigate the fate of IEPOX in both the gas and particle phases. To explore the gas-phase chemistry of IEPOX, three potential isomers of the C4O3H8 products were synthesized and photooxidized by exposure to OH. Detection with CF3O- chemical ionization mass spectrometry (CIMS) allowed for determination of their oxidation rates, fractional yields from IEPOX oxidation, and major products. To explore the photooxidation of IEPOX-derived SOA, synthetic IEPOX was reacted with various salts and atomized into a flow tube, where it was photooxidized by exposure to OH. We will present results showing changes in gas- and particle-phase chemical composition, monitored during oxidation by CIMS and aerosol mass spectrometry, including their dependence on both seed particle composition and OH concentration. Preliminary data show that the photochemical loss of IEPOX-derived SOA mass may be an important consideration for predicting aerosol loading and gas phase oxidative chemistry in isoprene-rich environments.

  3. New Global Deep Blue Aerosol Product over Land and Ocean from VIIRS, and Its comparisons with MODIS

    NASA Astrophysics Data System (ADS)

    Hsu, N. Y. C.; Bettenhausen, C.; Sayer, A. M.; Lee, J.; Tsay, S. C.; Carletta, N.

    2015-12-01

    The impacts of natural and anthropogenic sources of air pollution on climate and human health have continued to gain attention from the scientific community. In order to facilitate these effects, high quality consistent long-term global aerosol data records from satellites are essential. Several EOS-era instruments (e.g., SeaWiFS, MODIS, and MISR) are able to provide such information with a high degree of fidelity. However, with the aging MODIS sensors and the launch of the VIIRS instrument on Suomi NPP in late 2011, the continuation of long-term aerosol data records suitable for climate studies from MODIS to VIIRS is needed urgently. VIIRS was designed to have similar capabilities to MODIS, with similar visible/infrared spectral channels, and spatial/ temporal resolution. However, small but significant differences in several key channels used in aerosol retrievals between MODIS and VIIRS mean that significant effort is required to revise aerosol models and surface reflectance determination modules previously developed using MODIS data. In this study, we will show the global (land and ocean) distribution of aerosols from Version 1 of the VIIRS Deep Blue data set. The preliminary validation results of these new VIIRS Deep Blue aerosol products using data from AERONET sunphotometers over land and ocean will be discussed. We will also compare the monthly averaged Deep Blue aerosol optical thickness (AOT) from VIIRS with the MODIS C6 products to investigate if any systematic biases may exist between MODIS C6 and VIIRS AOT.

  4. Impossible Extinction

    NASA Astrophysics Data System (ADS)

    Cockell, Charles S.

    2003-03-01

    Every 225 million years the Earth, and all the life on it, completes one revolution around the Milky Way Galaxy. During this remarkable journey, life is influenced by calamitous changes. Comets and asteroids strike the surface of the Earth, stars explode, enormous volcanoes erupt, and, more recently, humans litter the planet with waste. Many animals and plants become extinct during the voyage, but humble microbes, simple creatures made of a single cell, survive this journey. This book takes a tour of the microbial world, from the coldest and deepest places on Earth to the hottest and highest, and witnesses some of the most catastrophic events that life can face. Impossible Extinction tells this remarkable story to the general reader by explaining how microbes have survived on Earth for over three billion years. Charles Cockell received his doctorate from the University of Oxford, and is currently a microbiologist with rhe Search for Extraterrestrial Intelligence Institute (SETI), based at the British Antarctic Survey in Cambridge, UK. His research focusses on astrobiology, life in the extremes and the human exploration of Mars. Cockell has been on expeditions to the Arctic, Antarctic, Mongolia, and in 1993 he piloted a modified insect-collecting ultra-light aircraft over the Indonesian rainforests. He is Chair of the Twenty-one Eleven Foundation for Exploration, a charity that supports expeditions that forge links between space exploration and environmentalism.

  5. Multiday production of condensing organic aerosol mass in urban and forest outflow

    NASA Astrophysics Data System (ADS)

    Lee-Taylor, J.; Hodzic, A.; Madronich, S.; Aumont, B.; Camredon, M.; Valorso, R.

    2015-01-01

    Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for multiple days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (~50%) and of shorter duration (1-2 days). The multiday production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction products of both aromatics and alkanes, especially those with relatively low carbon numbers (C4-15). In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions and different vapor pressure schemes, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.

  6. Multiday production of condensing organic aerosol mass in urban and forest outflow

    NASA Astrophysics Data System (ADS)

    Lee-Taylor, J.; Hodzic, A.; Madronich, S.; Aumont, B.; Camredon, M.; Valorso, R.

    2014-07-01

    Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for several days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (∼50%) and of shorter duration (1-2 days). The production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction products of both aromatics and alkanes. In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.

  7. Multiday production of condensing organic aerosol mass in urban and forest outflow

    DOE PAGESBeta

    Lee-Taylor, J.; Hodzic, A.; Madronich, S.; Aumont, B.; Camredon, M.; Valorso, R.

    2014-07-03

    Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for several days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (∼50%) and of shorter duration (1–2 days). The production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction products ofmore » both aromatics and alkanes. In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.« less

  8. Production, Organic Characterization, and Phase Transformations of Marine Particles Aerosolized from a Laboratory Mesocosm Phytoplankton Bioreactor

    NASA Astrophysics Data System (ADS)

    Alpert, P. A.; Knopf, D. A.; Aller, J. Y.; Radway, J.; Kilthau, W.

    2012-12-01

    Previous studies have shown that particles emitted from bubble bursting and wave breaking of ocean waters with high biological activity can contain sea salts associated with organic material, with smaller particles containing a larger mass fraction of organics than larger particles. This likely indicates a link between phytoplankton productivity in oceans and particulate organic material in marine air. Once aerosolized, particles with significant amount of organic material can affect cloud activation and formation of ice crystals, among other atmospheric processes, thus influencing climate. This is significant for clouds and climate particularly over nutrient rich polar seas, in which concentrations of biological organisms can reach up to 109 cells per ml during spring phytoplankton blooms. Here we present results of bubble bursting aerosol production from a seawater mesocosm containing artificial seawater, natural seawater and unialgal cultures of three representative phytoplankton species. These phytoplankton (Thalassiosira pseudonana, Emilianaia huxleyi, and Nannochloris atomus), possessed siliceous frustules, calcareous frustules and no frustules, respectively. Bubbles were generated employing recirculating impinging water jets or glass frits. Dry and humidified aerosol size distributions and bulk aerosol organic composition were measured as a function of phytoplankton growth, and chlorophyll composition and particulate and dissolved organic carbon in the water were determined. Finally, particles were collected on substrates for ice nucleation and water uptake experiments, their elemental compositions were determined using computer controlled scanning electron microscopy and energy dispersive analysis of X-rays (CCSEMEDAX), and their carbon speciation was determined using scanning transmission X-ray microscopy and near-edge X-ray absorption fine structure spectroscopy (STXM/NEXAFS). Particle size distributions exposed to dry and humidified air employing

  9. Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes

    NASA Astrophysics Data System (ADS)

    Lee, Anita; Goldstein, Allen H.; Keywood, Melita D.; Gao, Song; Varutbangkul, Varuntida; Bahreini, Roya; Ng, Nga L.; Flagan, Richard C.; Seinfeld, John H.

    2006-04-01

    The ozonolyses of six monoterpenes (α-pinene, β-pinene, 3-carene, terpinolene, α-terpinene, and myrcene), two sesquiterpenes (α-humulene and β-caryophyllene), and two oxygenated terpenes (methyl chavicol and linalool) were conducted individually in Teflon chambers to examine the gas-phase oxidation product and secondary organic aerosol (SOA) yields from these reactions. Particle size distribution and number concentration were monitored and allowed for the calculation of the SOA yield from each experiment, which ranged from 1 to 54%. A proton transfer reaction mass spectrometer (PTR-MS) was used to monitor the evolution of gas-phase products, identified by their mass to charge ratio (m/z). Several gas-phase oxidation products, formaldehyde, acetaldehyde, formic acid, acetone, acetic acid, and nopinone, were identified and calibrated. Aerosol yields, and the yields of these identified and calibrated oxidation products, as well as many higher m/z oxidation products observed with the PTR-MS, varied significantly between the different parent terpene compounds. The sum of measured oxidation products in the gas and particle phase ranged from 33 to 77% of the carbon in the reacted terpenes, suggesting there are still unmeasured products from these reactions. The observations of the higher molecular weight oxidation product ions provide evidence of previously unreported compounds and their temporal evolution in the smog chamber from multistep oxidation processes. Many of the observed ions, including m/z 111 and 113, have also been observed in ambient air above a Ponderosa pine forest canopy, and our results confirm they are consistent with products from terpene + O3 reactions. Many of these products are stable on the timescale of our experiments and can therefore be monitored in field campaigns as evidence for ozone oxidative chemistry.

  10. SAGE II aerosol data validation based on retrieved aerosol model size distribution from SAGE II aerosol measurements

    NASA Technical Reports Server (NTRS)

    Wang, Pi-Huan; Mccormick, M. P.; Mcmaster, L. R.; Chu, W. P.; Swissler, T. J.; Osborn, M. T.; Russell, P. B.; Oberbeck, V. R.; Livingston, J.; Rosen, J. M.

    1989-01-01

    Consideration is given to aerosol correlative measurements experiments for the Stratospheric Aerosol and Gas Experiment (SAGE) II, conducted between November 1984 and July 1986. The correlative measurements were taken with an impactor/laser probe, a dustsonde, and an airborne 36-cm lidar system. The primary aerosol quantities measured by the ground-based instruments are compared with those calculated from the aerosol size distributions from SAGE II aerosol extinction measurements. Good agreement is found between the two sets of measurements.

  11. N(2)O(5) reaction on submicron sea salt aerosol: kinetics, products, and the effect of surface active organics.

    PubMed

    Thornton, Joel A; Abbatt, Jonathan P D

    2005-11-10

    The reaction of N(2)O(5) on sea salt aerosol is a sink for atmospheric nitrogen oxides and a source of the Cl radical. We present room-temperature measurements of the N(2)O(5) loss rate on submicron artificial seawater (ASW) aerosol, performed with an entrained aerosol flow tube coupled to a chemical ionization mass spectrometer, as a function of aerosol phase (aqueous or partially crystalline), liquid water content, and size. We also present an analysis of the product growth kinetics showing that ClNO(2) is produced at a rate equal to N(2)O(5) loss, with an estimated lower limit yield of 50% at 50% relative humidity (RH). The reaction probability for N(2)O(5), gamma(N(2)(O)(5)), depends strongly on the particle phase, being 0.005 +/- 0.004 on partially crystalline ASW aerosol at 30% RH and 0.03 +/- 0.008 on aqueous ASW aerosol at 65% RH. At 50% RH, N(2)O(5) loss is relatively insensitive to particle size for radii greater than 100 nm, and gamma(N(2)(O)(5)) displays a statistically insignificant increase from 0.022 to approximately 0.03 for aqueous ASW aerosol over the RH range of 43-70%. We find that the presence of millimolar levels of hexanoic acid in the aerosol bulk decreases the gamma(N(2)(O)(5)) at 70% RH by a factor of 3-4 from approximately 0.025 to 0.008 +/- 0.004. This reduction is likely due to the partitioning of hexanoic acid to the gas-aerosol interface at a surface coverage that we estimate to be equivalent to a monolayer. This result is the first evidence that a monolayer coating of aqueous organic surfactant can slow the reactive uptake of atmospheric trace gases to aerosol. PMID:16838918

  12. Secondary Organic Aerosol (SOA) production from the Aqueous Reactions of Phenols and Triplet Aromatic Carbonyls

    NASA Astrophysics Data System (ADS)

    Smith, J.; Sun, Y.; Lu, Y.; Zhang, Q.; Anastasio, C.

    2010-12-01

    The phenolic compounds guaiacol, syringol and phenol have recently been shown to produce secondary organic aerosol (SOA) at high yields in the aqueous phase upon exposure to simulated sunlight and hydroxyl radical. These phenols are significant products from wood combustion that can readily enter atmospheric waters, such as aqueous aerosol particles and cloud/fog droplets. Once in the aqueous phase, phenols can react with the triplet excited states of non-phenolic aromatic carbonyls (NPCs), particle-bound organics that are also emitted from wood combustion. In this study, we examined the aqueous-phase production of SOA from the reaction of phenolic compounds with triplet excited state organics. These aqueous phase reactions were tested by illuminating solutions containing a phenolic compound and NPC under simulated sunlight at various concentrations and pH values. The phenolic compound is consumed during these reactions, following a first-order decay that varies with phenol concentration, phenol identity, and pH. The non-volatile product mass formed in our illuminated solutions was determined gravimetrically and by analysis with High Resolution Time of Flight Aerosol Mass Spectrometry (HR-AMS). The SOA mass yield was determined as the mass of non-volatile product formed per mass of phenolic consumed during illumination. We also used HR-AMS to analyze for elemental composition, carbon oxidation state, and oligomers in the SOA produced. Our results to date indicate that phenols can be rapidly oxidized by triplet excited states under environmentally relevant conditions and that the accompanying SOA mass yields are very high.

  13. Gas phase emissions from cooking processes and their secondary aerosol production potential

    NASA Astrophysics Data System (ADS)

    Klein, Felix; Platt, Stephen; Bruns, Emily; Termime-roussel, Brice; Detournay, Anais; Mohr, Claudia; Crippa, Monica; Slowik, Jay; Marchand, Nicolas; Baltensperger, Urs; Prevot, Andre; El Haddad, Imad

    2014-05-01

    Long before the industrial evolution and the era of fossil fuels, high concentrations of aerosol particles were alluded to in heavily populated areas, including ancient Rome and medieval London. Recent radiocarbon measurements (14C) conducted in modern megacities came as a surprise: carbonaceous aerosol (mainly organic aerosol, OA), a predominant fraction of particulate matter (PM), remains overwhelmingly non-fossil despite extensive fossil fuel combustion. Such particles are directly emitted (primary OA, POA) or formed in-situ in the atmosphere (secondary OA, SOA) via photochemical reactions of volatile organic compounds (VOCs). Urban levels of non-fossil OA greatly exceed the levels measured in pristine environments strongly impacted by biogenic emissions, suggesting a contribution from unidentified anthropogenic non-fossil sources to urban OA. Positive matrix factorization (PMF) techniques applied to ambient aerosol mass spectrometer (AMS, Aerodyne) data identify primary cooking emissions (COA) as one of the main sources of primary non-fossil OA in major cities like London (Allan et al., 2010), New York (Sun et al., 2011) and Beijing (Huang et al., 2010). Cooking processes can also emit VOCs that can act as SOA precursors, potentially explaining in part the high levels of oxygenated OA (OOA) identified by the AMS in urban areas. However, at present, the chemical nature of these VOCs and their secondary aerosol production potential (SAPP) remain virtually unknown. The approach adopted here involves laboratory quantification of PM and VOC emission factors from the main primary COA emitting processes and their SAPP. Primary emissions from deep-fat frying, vegetable boiling, vegetable frying and meat cooking for different oils, meats and vegetables were analysed under controlled conditions after ~100 times dilution. A high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and a high resolution proton transfer time-of-flight mass spectrometer (PTR

  14. Measuring black carbon spectral extinction in the visible and infrared

    NASA Astrophysics Data System (ADS)

    Smith, A. J. A.; Peters, D. M.; McPheat, R.; Lukanihins, S.; Grainger, R. G.

    2015-09-01

    This work presents measurements of the spectral extinction of black carbon aerosol from 400 nm to 15 μm. The aerosol was generated using a Miniature Combustion Aerosol Standard soot generator and then allowed to circulate in an aerosol cell where its extinction was measured using a grating spectrometer in the visible and a Fourier transform spectrometer in the infrared. Size distribution, number concentration, and mass extinction cross sections have also been obtained using single-particle aerosol samplers. A mean mass extinction cross section at 550 nm of 8.3 ± 1.6 m2 g-1 is found which, assuming a reasonable single scatter albedo of 0.2, corresponds to a mass absorption cross section of 6.6 ± 1.3 m2 g-1. This compares well with previously reported literature values. Computer analysis of electron microscope images of the particles provides independent confirmation of the size distribution as well as fractal parameters of the black carbon aerosol. The aerosol properties presented in this work are representative of very fresh, uncoated black carbon aerosol. After atmospheric processing of such aerosols (which could include mixing with other constituents and structural changes), different optical properties would be expected.

  15. Gas-Phase Oxidation Kinetics and Organic Aerosol Products of Ethanolamine

    NASA Astrophysics Data System (ADS)

    Borduas, N.; Abbatt, J.; Murphy, J. G.

    2012-12-01

    Ethanolamine is currently the solvent of choice in carbon capture and storage technology (CCS) which aims to reduce CO2 emissions to the atmosphere in coal powered pilot plants. CCS technology represents an unprecedented large scale application of ethanolamine and little is known of its fate if it was unintentionally released into the atmosphere. Relative kinetic experiments were conducted in a 1m3 smog chamber using online proton-transfer-reaction mass spectrometry. The kinetics of oxidation with hydroxyl radicals from light and dark sources converge to a value of (7.6 ± 1.1) x 10-11 cm3 molec-1 s-1. The reaction of ethanolamine with ozone was determined to be (1.05 ± 0.08) x 10-18 cm3 molec-1 s-1. We find that ethanolamine has a short lifetime in the atmosphere and readily deposits onto wall and particle surfaces, as observed by considerable formation of organonitrogen aerosol products. An investigation into the oxidation product formation using a combination of reagent ions with online chemical ionization mass spectrometry approaches lead to the detection of higher order products. The formation of these high molecular weight products is simultaneous with the oxidation of ethanolamine and implies substantial organic aerosol chemistry.

  16. Multiday production of condensing organic aerosol mass in urban and forest outflow

    DOE PAGESBeta

    Lee-Taylor, J.; Hodzic, A.; Madronich, S.; Aumont, B.; Camredon, M.; Valorso, R.

    2015-01-16

    Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for multiple days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (~50%) and of shorter duration (1–2 days). The multiday production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction productsmore » of both aromatics and alkanes, especially those with relatively low carbon numbers (C4–15). In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions and different vapor pressure schemes, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.« less

  17. Quantifying VOC-Reaction Tracers, Ozone Production, and Continuing Aerosol Production Rates in Urban and Far-Downwind Atmospheres

    NASA Technical Reports Server (NTRS)

    Chatfield, Robert; Ren, X.; Brune, W.; Fried, A.; Schwab, J.

    2008-01-01

    We have found a surprisingly informative decomposition of the complex question of smoggy ozone production (basically, [HO2] in a more locally determined field of [NO]) in the process of linked investigations of modestly smoggy Eastern North America (by NASA aircraft, July 2004) and rather polluted Flushing, NYC (Queens College, July, 2001). In both rural and very polluted situations, we find that a simple contour graph parameterization of the local principal ozone production rate can be estimated using only the variables [NO] and j(sub rads) [HCHO]: Po(O3) = c (j(sub rads) [HCHO])(sup a) [HCHO](sup b). Here j(sub rads) is the photolysis of HCHO to radicals, presumably capturing many harder-UV photolytic processes and the principle ozone production is that due to HO2; mechanisms suggest that ozone production due to RO2 is closely correlated, often suggesting a limited range of different proportionality factors. The method immediately suggests a local interpretation for concepts of VOC limitation and NOx limitation. We believe that the product j(sub rads) [HCHO] guages the oxidation rate of observed VOC mixtures in a way that also provides [HO2] useful for the principle ozone production rate k [HO2] [NO], and indeed, all ozone chemical production. The success of the method suggests that dominant urban primary-HCHO sources may transition to secondary plume-HCHO sources in a convenient way. Are there other, simple, near-terminal oxidized VOC's which help guage ozone production and aerosol particle formation? Regarding particles, we report on, to the extent NASA Research resources allow, on appealing relationships between far-downwind (Atlantic PBL) HCHO and very fine aerosol (including sulfate. Since j(sub rads) [HCHO] provides a time-scale, we may understand distant-plume particle production in a more quantitative manner. Additionally we report on a statistical search in the nearer field for relationships between glyoxals (important near-terminal aromatic and isoprene

  18. Secondary organic aerosol (trans)formation through aqueous phase guaiacol photonitration: chemical characterization of the products

    NASA Astrophysics Data System (ADS)

    Grgić, Irena; Kitanovski, Zoran; Kroflič, Ana; Čusak, Alen

    2014-05-01

    One of the largest primary sources of organic aerosol in the atmosphere is biomass burning (BB) (Laskin et al. 2009); in Europe its contribution to annual mean of PM10 is between 3 and 14 % (Maenhaut et al. 2012). During the process of wood burning many different products are formed via thermal degradation of wood lignin. Hardwood burning produces mainly syringol (2,6-dimetoxyphenol) derivatives, while softwood burning exclusively guaiacol (2-methoxyphenol) and its derivatives. Taking into account physical properties of methoxyphenols only, their concentrations in atmospheric waters might be underestimated. So, their aqueous phase reactions can be an additional source of SOA, especially in regions under significant influence of wood combustion. An important class of compounds formed during physical and chemical aging of the primary BBA in the atmosphere is nitrocatechols, known as strong absorbers of UV and Vis light (Claeys et al. 2012). Very recently, methyl-nitrocatechols were proposed as suitable markers for highly oxidized secondary BBA (Iinuma et al. 2010, Kitanovski et al. 2012). In the present work, the formation of SOA through aqueous phase photooxidation and nitration of guaiacol was examined. The key objective was to chemically characterize the main low-volatility products and further to check their possible presence in the urban atmospheric aerosols. The aqueous phase reactions were performed in a thermostated reactor under simulated sunlight in the presence of H2O2 and nitrite. Guaiacol reaction products were first concentrated by solid-phase extraction (SPE) and then subjected to semi-preparative liquid chromatography.The main product compounds were fractionated and isolated as pure solids and their structure was further elucidated by using nuclear magnetic resonance spectroscopy (1H, 13C and 2D NMR) and direct infusion negative ion electro-spray ionization tandem mass spectrometry (( )ESI-MS/MS). The main photonitration products of guaiacol (4

  19. Testing the limits in a greenhouse ocean: Did low nitrogen availability limit marine productivity during the end-Triassic mass extinction?

    NASA Astrophysics Data System (ADS)

    Schoepfer, Shane D.; Algeo, Thomas J.; Ward, Peter D.; Williford, Kenneth H.; Haggart, James W.

    2016-10-01

    The end-Triassic mass extinction has been characterized as a 'greenhouse extinction', related to rapid atmospheric warming and associated changes in ocean circulation and oxygenation. The response of the marine nitrogen cycle to these oceanographic changes, and the extent to which mass extinction intervals represent a deviation in nitrogen cycling from other ice-free 'greenhouse' periods of Earth history, remain poorly understood. The well-studied Kennecott Point section in Haida Gwaii, British Columbia, Canada, was deposited in the open Panthalassic Ocean, and is used here as a test case to better understand changes in the nitrogen cycle and marine productivity from the pre-crisis greenhouse of the Rhaetian to the latest-Rhaetian crisis interval. We estimated marine productivity from the late Norian to the early Hettangian using TOC- and P-based paleoproductivity transform equations, and then compared these estimates to records of sedimentary nitrogen isotopes, redox-sensitive trace elements, and biomarker data. Major negative excursions in δ15N (to ≤ 0 ‰) correspond to periods of depressed marine productivity. During these episodes, the development of a stable pycnocline below the base of the photic zone suppressed vertical mixing and limited N availability in surface waters, leading to low productivity and increased nitrogen fixation, as well as ecological stresses in the photic zone. The subsequent shoaling of euxinic waters into the ocean surface layer was fatal for most Triassic marine fauna, although the introduction of regenerated NH4+ into the photic zone may have allowed phytoplankton productivity to recover. These results indicate that the open-ocean nitrogen cycle was influenced by climatic changes during the latest Triassic, despite having existed in a greenhouse state for over 50 million years previously, and that low N availability limited marine productivity for hundreds of thousands of years during the end-Triassic crisis.

  20. SAGE II aerosol correlative observations - Profile measurements

    NASA Technical Reports Server (NTRS)

    Osborn, M. T.; Rosen, J. M.; Mccormick, M. P.; Wang, Pi-Huan; Livinfston, J. M.

    1989-01-01

    Profiles of the aerosol extinction measurements from the Stratospheric Aerosol and Gas Experiment (SAGE) II are compared with profiles from five correlative experiments between November 1984 and July 1986. The correlative profiles were derived from six-channel dustsonde measurements and two-wavelength lidar backscatter data. The correlation between the dustsonde- and lidar-derived measurements and the SAGE II data is good, validating the SAGE II lower stratospheric aerosol extinction measurements.

  1. Gradient Correlation Method for the Stabilization of Inversion Results of Aerosol Microphysical Properties Retrieved from Profiles of Optical Data

    NASA Astrophysics Data System (ADS)

    Kolgotin, Alexei; Müller, Detlef; Romanov, Anton; Chemyakin, Eduard

    2016-06-01

    Correlation relationships between aerosol microphysical parameters and optical data are investigated. The results show that surface-area concentrations and extinction coefficients are linearly correlated with a correlation coefficient above 0.99 for arbitrary particle size distribution. The correlation relationships that we obtained can be used as constraints in our inversion of optical lidar data. Simulation studies demonstrate a significant stabilization of aerosol microphysical data products if we apply the gradient correlation method in our traditional regularization technique.

  2. Spatiotemporal fusion of multiple-satellite aerosol optical depth (AOD) products using Bayesian maximum entropy method

    NASA Astrophysics Data System (ADS)

    Tang, Qingxin; Bo, Yanchen; Zhu, Yuxin

    2016-04-01

    Merging multisensor aerosol optical depth (AOD) products is an effective way to produce more spatiotemporally complete and accurate AOD products. A spatiotemporal statistical data fusion framework based on a Bayesian maximum entropy (BME) method was developed for merging satellite AOD products in East Asia. The advantages of the presented merging framework are that it not only utilizes the spatiotemporal autocorrelations but also explicitly incorporates the uncertainties of the AOD products being merged. The satellite AOD products used for merging are the Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 5.1 Level-2 AOD products (MOD04_L2) and the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Deep Blue Level 2 AOD products (SWDB_L2). The results show that the average completeness of the merged AOD data is 95.2%,which is significantly superior to the completeness of MOD04_L2 (22.9%) and SWDB_L2 (20.2%). By comparing the merged AOD to the Aerosol Robotic Network AOD records, the results show that the correlation coefficient (0.75), root-mean-square error (0.29), and mean bias (0.068) of the merged AOD are close to those (the correlation coefficient (0.82), root-mean-square error (0.19), and mean bias (0.059)) of the MODIS AOD. In the regions where both MODIS and SeaWiFS have valid observations, the accuracy of the merged AOD is higher than those of MODIS and SeaWiFS AODs. Even in regions where both MODIS and SeaWiFS AODs are missing, the accuracy of the merged AOD is also close to the accuracy of the regions where both MODIS and SeaWiFS have valid observations.

  3. Aqueous secondary organic aerosol (SOA) production from the oxidation of phenols by triplet excited state organics

    NASA Astrophysics Data System (ADS)

    Smith, J.; Yu, L.; Zhang, Q.; Anastasio, C.

    2011-12-01

    Recent literature has shown that atmospheric condensed-phase chemistry can play a significant role in the evolution of organic aerosols, including the formation of secondary organic aerosol (SOA). SOA formation from the oxidation of volatile organic compounds (VOCs) in the aqueous phase has largely focused on oxidations involving the hydroxyl radical and other oxidants, such as photochemically created triplet excited states, have not been fully investigated. Phenolic compounds are one of the primary carbon emission classes from biomass and wood combustion and have significant water solubility. Once in the aqueous phase, phenolic compounds can react with the triplet excited states of non-phenolic aromatic carbonyls (NPCs), particle-bound organics that are also emitted in large quantities from wood combustion. The oxidation of phenolic species in the condensed phase by triplet excited states can result in the production of SOA. A main goal of this study was to investigate bulk solution reaction kinetics under atmospherically relevant conditions in order to ascertain how these reactions can impact aqueous-phase SOA production. In our experiments, we studied the reactions of five phenols (phenol, guaiacol, syringol, catechol, and resorcinol) with the triplet state of 3,4-dimethoxybenzaldehyde (34-DMB) during simulated solar radiation. We have characterized the impacts of pH, ionic strength and reactant concentrations on the reaction behavior of this system. In addition, we analyzed the SOA formed using high-resolution aerosol mass spectrometry, ion chromatography, and liquid chromatography-mass spectrometry to infer the reaction mechanisms. Our evidence suggests that under atmospherically relevant conditions, triplet excited states can be the dominant oxidant of phenolics and contribute significantly to the total SOA budget.

  4. Analysis of aerosol vertical distribution and variability in Hong Kong

    NASA Astrophysics Data System (ADS)

    He, Qianshan; Li, Chengcai; Mao, Jietai; Lau, Alexis Kai-Hon; Chu, D. A.

    2008-07-01

    Aerosol vertical distribution is an important piece of information to improve aerosol retrieval from satellite remote sensing. Aerosol extinction coefficient profile and its integral form, aerosol optical depth (AOD), as well as atmospheric boundary layer (ABL) height and haze layer height can be derived using lidar measurements. In this paper, we used micropulse lidar measurements acquired from May 2003 to June 2004 to illustrate seasonal variations of AOD and ABL height in Hong Kong. On average, about 64% of monthly mean aerosol optical depths were contributed by aerosols within the mixing layer (with a maximum (˜76%) in November and a minimum (˜55%) in September) revealing the existence of large abundance of aerosols above ABL due to regional transport. The characteristics of seasonal averaged aerosol profiles over Hong Kong in the study period are presented to illustrate seasonal phenomena of aerosol transport and associated meteorological conditions. The correlation between AOD and surface extinction coefficient, as found, is generally poor (r2 ˜0.42) since elevated aerosol layers increase columnar aerosol abundance but not extinction at surface. The typical aerosol extinction profile in the ABL can be characterized by a low value near the surface and values increased with altitude reaching the top of ABL. When aerosol vertical profile is assumed, surface extinction coefficient can be derived from AOD using two algorithms, which are discussed in detail in this paper. Preliminary analysis showed that better estimates of the extinction coefficient at the ground level could be obtained using two-layer aerosol extinction profiles (r2 ˜0.78, slope ˜0.82, and intercept ˜0.15) than uniform profiles of extinction with height within the ABL (r2 ˜0.65, slope ˜0.27, and intercept ˜0.03). The improvement in correlation is promising on mapping satellite retrieved AOD to surface aerosol extinction coefficient for urban and regional environmental studies on air

  5. Estimation of surface-level PM concentration from satellite observation taking into account the aerosol vertical profiles and hygroscopicity.

    PubMed

    Kim, Kwanchul; Lee, Kwon H; Kim, Ji I; Noh, Youngmin; Shin, Dong H; Shin, Sung K; Lee, Dasom; Kim, Jhoon; Kim, Young J; Song, Chul H

    2016-01-01

    Surface-level PM10 distribution was estimated from the satellite aerosol optical depth (AOD) products, taking the account of vertical profiles and hygroscopicity of aerosols over Jeju, Korea during March 2008 and October 2009. In this study, MODIS AOD data from the Terra and Aqua satellites were corrected with aerosol extinction profiles and relative humidity data. PBLH (Planetary Boundary Layer Height) was determined from MPLNET lidar-derived aerosol extinction coefficient profiles. Through statistical analysis, better agreement in correlation (R = 0.82) between the hourly PM10 concentration and hourly average Sunphotometer AOD was the obtained when vertical fraction method (VFM) considering Haze Layer Height (HLH) and hygroscopic growth factor f(RH) was used. The validity of the derived relationship between satellite AOD and surface PM10 concentration clearly demonstrates that satellite AOD data can be utilized for remote sensing of spatial distribution of regional PM10 concentration. PMID:26421659

  6. Interpreting aerosol lidar profiles to better estimate surface PM2.5 for columnar AOD measurements

    NASA Astrophysics Data System (ADS)

    Chu, D. Allen; Tsai, Tzu-Chin; Chen, Jen-Ping; Chang, Shuenn-Chin; Jeng, Yung-Jyh; Chiang, Wei-Li; Lin, Neng-Hui

    2013-11-01

    Satellite aerosol optical depth (AOD) products have been used to estimate surface PM2.5 in different parts of the world. However, some revealed good but some relatively poorer relationship between AOD and PM2.5. The increasingly available lidar-based aerosol extinction profiles provide insights into the boundary layer as well as residual above it. Here we report a study in Taiwan using four-year (2006-2009) MPLNet data to characterize aerosol vertical distribution. We derived haze layer height (HLH) from MPLNet aerosol extinction profiles and classified profile differences by mean PBL extinction (MPE) and near-surface extinction (NSE). The former represents the mean extinction within boundary layer and the latter the closest extinction to surface. The comparison of MPE versus NSE leads to three distinct classifications of aerosol profiles to help interpret the relationship between AOD and PM2.5. The approximation of normalizing AODAERONET by HLH closely follows MPE in correlating with PM2.5 (≥0.8 with respect to season or ≥0.85 with respect to profile classification). The correlation resulted from AODMODIS/HLH is systematically lower than that derived by AODAERONET/HLH. PM2.5 values are overall better estimated by profile classification than those derived by season. Better performance of PM2.5 is obtained with the approximation (i.e., normalizing AOD by HLH) than that using AOD only. The performance metrics used in quantifying the relationship reveal improvements in uncertainty by 2.9 μg m-3 (or 20%) with AODAERONET/HLH and 2.3 μg m-3 (or 15%) with AODMODIS/HLH in comparison to using AOD only.

  7. Global Long-Term SeaWiFS Deep Blue Aerosol Products available at NASA GES DISC

    NASA Astrophysics Data System (ADS)

    Shen, S.; Sayer, A. M.; Bettenhausen, C.; Wei, J. C.; Ostrenga, D.; Vollmer, B.; Hsu, N. C.

    2012-12-01

    Long-term climate data records of aerosols are needed in order to study regional air quality and the uncertainty of aerosol radiative forcing with numerical models. Recently, global long-term (over 13 years from 1997 to 2010) SeaWiFS Deep Blue (SWDB) aerosol products have become available. The SWDB aerosol dataset has been produced by the "Consistent Long-Term Aerosol Data Records over Land and Ocean from SeaWIFS" project led by Dr. N. Christina Hsu as part of the Making Earth Science data records for Use in Research for Earth Science (MEaSUREs) program. The latest Deep Blue algorithm retrieves aerosol properties not only over bright desert surfaces, but also vegetated surfaces, oceans, and inland water bodies. Comparisons with AERONET observations have shown that the data are suitable for quantitative scientific use. The resolution of the Level 2 pixels is 13.5x13.5 km2 at the center of the swath. The Level 3 daily and monthly data are composed by using best quality level 2 pixels at resolution of both 0.5x0.5 and 1.0x1.0 degrees. This presentation, focusing over the south Asia region, will show sample higher resolution Level 2 images of dust events and the Level 3 monthly climatology at large scale. The data are compared with the widely-used MODIS (Deep Blue and Dark Target) aerosol dataset. The SWDB aerosol data are available from NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) through a number of data services, such as FTP; the data search system, Mirador; OPeNDAP; and online subsetting services. The global daily and monthly Level 3 products are also available in the innovative online visualization and analysis system, Giovanni. More information about SWBD aerosol products can be found from the project portal: http://disc.gsfc.nasa.gov/dust. Seasonal climatology of SeaWiFS Deep Blue Aerosol Optical Depth at 550nm for the period from 1997.09 to 2010.12.

  8. A Comparison of Parameterizations of Secondary Organic Aerosol Production: Global Budget and Spatiotemporal Variability

    NASA Astrophysics Data System (ADS)

    Liu, J.; Chen, Z.; Horowitz, L. W.; Carlton, A. M. G.; Fan, S.; Cheng, Y.; Ervens, B.; Fu, T. M.; He, C.; Tao, S.

    2014-12-01

    Secondary organic aerosols (SOA) have a profound influence on air quality and climate, but large uncertainties exist in modeling SOA on the global scale. In this study, five SOA parameterization schemes, including a two-product model (TPM), volatility basis-set (VBS) and three cloud SOA schemes (Ervens et al. (2008, 2014), Fu et al. (2008) , and He et al. (2013)), are implemented into the global chemical transport model (MOZART-4). For each scheme, model simulations are conducted with identical boundary and initial conditions. The VBS scheme produces the highest global annual SOA production (close to 35 Tg·y-1), followed by three cloud schemes (26-30 Tg·y-1) and TPM (23 Tg·y-1). Though sharing a similar partitioning theory to the TPM scheme, the VBS approach simulates the chemical aging of multiple generations of VOCs oxidation products, resulting in a much larger SOA source, particularly from aromatic species, over Europe, the Middle East and Eastern America. The formation of SOA in VBS, which represents the net partitioning of semi-volatile organic compounds from vapor to condensed phase, is highly sensitivity to the aging and wet removal processes of vapor-phase organic compounds. The production of SOA from cloud processes (SOAcld) is constrained by the coincidence of liquid cloud water and water-soluble organic compounds. Therefore, all cloud schemes resolve a fairly similar spatial pattern over the tropical and the mid-latitude continents. The spatiotemporal diversity among SOA parameterizations is largely driven by differences in precursor inputs. Therefore, a deeper understanding of the evolution, wet removal, and phase partitioning of semi-volatile organic compounds, particularly above remote land and oceanic areas, is critical to better constrain the global-scale distribution and related climate forcing of secondary organic aerosols.

  9. Spatial and Temporal Characteristics of Aerosols from Collection 6 Aqua and Terra MODIS e-Deep Blue Products

    NASA Astrophysics Data System (ADS)

    Bettenhausen, C.; Hsu, N. Y. C.; Sayer, A. M.; Lee, J.; Carletta, N.

    2015-12-01

    Aerosols continue to attract a significant amount of attention from researchers worldwide due to their extensive effects on Earth's climate, ecology, public health, and even energy production. In order to truly understand these effects, a long, stable, and well-calibrated data record is required. Since 2000 and 2002, the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments aboard the Terra and Aqua satellites together with the e-Deep Blue aerosol retrieval algorithm have been providing such a data record. After a multi-year development effort, the production of both Aqua and Terra MODIS Collection 6 (C6) atmosphere products successfully completed earlier this year and the data was released to the public shortly thereafter. The C6 Deep Blue products (now enhanced Deep Blue or e-Deep Blue) have been significantly improved over the previous Collection 5.1 version. In this poster we provide an overview of the latest C6 e-Deep Blue products and the improvements implemented since the previous collection including coverage over dark surfaces and updates to the Terra calibration. Validation results utilizing Aerosol Robotic Network (AERONET) data are also summarized. We then use the C6 e-Deep Blue products from both Aqua and Terra to explore the spatial characteristics in addition to the seasonal and inter-annual variability of aerosols on both regional and global scales. We also use this as an opportunity to compare these results and investigate any differences found between the two instruments.

  10. Laboratory Experiments and Instrument Intercomparison Studies of Carbonaceous Aerosol Particles

    SciTech Connect

    Davidovits, Paul

    2015-10-20

    Aerosols containing black carbon (and some specific types of organic particulate matter) directly absorb incoming light, heating the atmosphere. In addition, all aerosol particles backscatter solar light, leading to a net-cooling effect. Indirect effects involve hydrophilic aerosols, which serve as cloud condensation nuclei (CCN) that affect cloud cover and cloud stability, impacting both atmospheric radiation balance and precipitation patterns. At night, all clouds produce local warming, but overall clouds exert a net-cooling effect on the Earth. The effect of aerosol radiative forcing on climate may be as large as that of the greenhouse gases, but predominantly opposite in sign and much more uncertain. The uncertainties in the representation of aerosol interactions in climate models makes it problematic to use model projections to guide energy policy. The objective of our program is to reduce the uncertainties in the aerosol radiative forcing in the two areas highlighted in the ASR Science and Program Plan. That is, (1) addressing the direct effect by correlating particle chemistry and morphology with particle optical properties (i.e. absorption, scattering, extinction), and (2) addressing the indirect effect by correlating particle hygroscopicity and CCN activity with particle size, chemistry, and morphology. In this connection we are systematically studying particle formation, oxidation, and the effects of particle coating. The work is specifically focused on carbonaceous particles where the uncertainties in the climate relevant properties are the highest. The ongoing work consists of laboratory experiments and related instrument inter-comparison studies both coordinated with field and modeling studies, with the aim of providing reliable data to represent aerosol processes in climate models. The work is performed in the aerosol laboratory at Boston College. At the center of our laboratory setup are two main sources for the production of aerosol particles: (a

  11. Atmospheric aerosol characterization combining multi-wavelength Raman lidar and MAX-DOAS measurements in Gwanjgu

    NASA Astrophysics Data System (ADS)

    Chong, Jihyo; Shin, Dong Ho; Kim, Kwang Chul; Lee, Kwon-Ho; Shin, Sungkyun; Noh, Young M.; Müller, Detlef; Kim, Young J.

    2011-11-01

    Integrated approach has been adopted at the ADvanced Environmental Research Center (ADEMRC), Gwangju Institute of Science and Technology (GIST), Korea for effective monitoring of atmospheric aerosol. Various active and passive optical remote sensing techniques such as multi-wavelength (3β+2α+1δ) Raman LIDAR, sun-photometry, MAX-DOAS, and satellite retrieval have been utilized. This integrated monitoring system approach combined with in-situ surface measurement is to allow better characterization of physical and optical properties of atmospheric aerosol. Information on the vertical distribution and microphysical properties of atmospheric aerosol is important for understanding its transport characteristics as well as radiative effect. The GIST multi-wavelength (3β + 2α+1δ) Raman lidar system can measure vertical profiles of optical properties of atmospheric aerosols such as extinction coefficients at 355 and 532nm, particle backscatter coefficients at 355, 532 and 1064 nm, and depolarization ratio at 532nm. The incomplete overlap between the telescope field-of-view and beam divergence of the transmitting laser significantly affects lidar measurement, resulting in higher uncertainty near the surface where atmospheric aerosols of interest are concentrated. Differential Optical Absorption Spectroscopy (DOAS) technique is applied as a complementary tool for the detection of atmospheric aerosols near the surface. The passive Multi-Axis DOAS (MAX-DOAS) technique uses scattered sunlight as a light source from several viewing directions. Recently developed aerosol retrieval algorithm based on O4 slant column densities (SCDs) measured at UV and visible wavelengths has been utilized to derive aerosol information (e.g., aerosol optical depth (AOD) and aerosol extinction coefficients (AECs)) in the lower troposphere. The aerosol extinction coefficient at 356 nm was retrieved for the 0-1 and 1-2 km layers based on the MAX-DOAS measurements using the retrieval algorithm

  12. Light-absorbing aldol condensation products in acidic aerosols: Spectra, kinetics, and contribution to the absorption index

    NASA Astrophysics Data System (ADS)

    Nozière, Barbara; Esteve, William

    The radiative properties of aerosols that are transparent to light in the near-UV and visible, such as sulfate aerosols, can be dramatically modified when mixed with absorbing material such as soot. In a previous work we had shown that the aldol condensation of carbonyl compounds produces light-absorbing compounds in sulfuric acid solutions. In this work we report the spectroscopic and kinetic parameters necessary to estimate the effects of these reactions on the absorption index of sulfuric acid aerosols in the atmosphere. The absorption spectra obtained from the reactions of six different carbonyl compounds (acetaldehyde, acetone, propanal, butanal, 2-butanone, and trifluoroacetone) and their mixtures were compared over 190-1100 nm. The results indicated that most carbonyl compounds should be able to undergo aldol condensation. The products are oligomers absorbing light in the 300-500 nm region where few other compounds absorb, making them important for the radiative properties of aerosols. Kinetic experiments in 96-75 wt% H 2SO 4 solutions and between 273 and 314 K gave an activation energy for the rate constant of formation of the aldol products of acetaldehyde of -(70±15) kJ mol -1 in 96 wt% solution and showed that the effect of acid concentration was exponential. A complete expression for this rate constant is proposed where the absolute value in 96 wt% H 2SO 4 and at 298 K is scaled to the Henry's law coefficient for acetaldehyde and the absorption cross-section for the aldol products assumed in this work. The absorption index of stratospheric sulfuric acid aerosols after a 2-year residence time was estimated to 2×10 -4, optically equivalent to a content of 0.5% of soot and potentially significant for the radiative forcing of these aerosols and for satellite observations in channels where the aldol products absorb.

  13. Kinetics, Mechanism, and Secondary Organic Aerosol Yield of Aqueous Phase Photo-oxidation of α-Pinene Oxidation Products.

    PubMed

    Aljawhary, Dana; Zhao, Ran; Lee, Alex K Y; Wang, Chen; Abbatt, Jonathan P D

    2016-03-10

    Formation of secondary organic aerosol (SOA) involves atmospheric oxidation of volatile organic compounds (VOCs), the majority of which are emitted from biogenic sources. Oxidation can occur not only in the gas-phase but also in atmospheric aqueous phases such as cloudwater and aerosol liquid water. This study explores for the first time the aqueous-phase OH oxidation chemistry of oxidation products of α-pinene, a major biogenic VOC species emitted to the atmosphere. The kinetics, reaction mechanisms, and formation of SOA compounds in the aqueous phase of two model compounds, cis-pinonic acid (PIN) and tricarballylic acid (TCA), were investigated in the laboratory; TCA was used as a surrogate for 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA), a known α-pinene oxidation product. Aerosol time-of-flight chemical ionization mass spectrometry (Aerosol-ToF-CIMS) was used to follow the kinetics and reaction mechanisms at the molecular level. Room-temperature second-order rate constants of PIN and TCA were determined to be 3.3 (±0.5) × 10(9) and 3.1 (±0.2) × 10(8) M(-1) s(-1), respectively, from which were estimated their condensed-phase atmospheric lifetimes. Aerosol-ToF-CIMS detected a large number of products leading to detailed reaction mechanisms for PIN and MBTCA. By monitoring the particle size distribution after drying, the amount of SOA material remaining in the particle phase was determined. An aqueous SOA yield of 40 to 60% was determined for PIN OH oxidation. Although recent laboratory studies have focused primarily on aqueous-phase processing of isoprene-related compounds, we demonstrate that aqueous formation of SOA materials also occurs from monoterpene oxidation products, thus representing an additional source of biogenically driven aerosol formation. PMID:26299576

  14. Development the EarthCARE aerosol classification scheme

    NASA Astrophysics Data System (ADS)

    Wandinger, Ulla; Baars, Holger; Hünerbein, Anja; Donovan, Dave; van Zadelhoff, Gerd-Jan; Fischer, Jürgen; von Bismarck, Jonas; Eisinger, Michael; Lajas, Dulce; Wehr, Tobias

    2015-04-01

    The Earth Clouds, Aerosols and Radiation Explorer (EarthCARE) mission is a joint ESA/JAXA mission planned to be launched in 2018. The multi-sensor platform carries a cloud-profiling radar (CPR), a high-spectral-resolution cloud/aerosol lidar (ATLID), a cloud/aerosol multi-spectral imager (MSI), and a three-view broad-band radiometer (BBR). Three out of the four instruments (ATLID, MSI, and BBR) will be able to sense the global aerosol distribution and contribute to the overarching EarthCARE goals of sensor synergy and radiation closure with respect to aerosols. The high-spectral-resolution lidar ATLID obtains profiles of particle extinction and backscatter coefficients, lidar ratio, and linear depolarization ratio as well as the aerosol optical thickness (AOT) at 355 nm. MSI provides AOT at 670 nm (over land and ocean) and 865 nm (over ocean). Next to these primary observables the aerosol type is one of the required products to be derived from both lidar stand-alone and ATLID-MSI synergistic retrievals. ATLID measurements of the aerosol intensive properties (lidar ratio, depolarization ratio) and ATLID-MSI observations of the spectral AOT will provide the basic input for aerosol-type determination. Aerosol typing is needed for the quantification of anthropogenic versus natural aerosol loadings of the atmosphere, the investigation of aerosol-cloud interaction, assimilation purposes, and the validation of atmospheric transport models which carry components like dust, sea salt, smoke and pollution. Furthermore, aerosol classification is a prerequisite for the estimation of direct aerosol radiative forcing and radiative closure studies. With an appropriate underlying microphysical particle description, the categorization of aerosol observations into predefined aerosol types allows us to infer information needed for the calculation of shortwave radiative effects, such as mean particle size, single-scattering albedo, and spectral conversion factors. In order to ensure

  15. 76 FR 60530 - Notice Pursuant to the National Cooperative Research and Production Act of 1993-Plastic Aerosol...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-29

    ... Antitrust Division Notice Pursuant to the National Cooperative Research and Production Act of 1993--Plastic...''), Plastic Aerosol Research Group, L.L.C. (``PARG'') has filed written notifications simultaneously with the... are: Aerofil Technology Inc, Sullivan, MO; Aptar Beauty & Home, Cary, IL; Berry Plastics...

  16. Midinfrared optical properties of petroleum oil aerosols. Final report

    SciTech Connect

    Gurton, K.P.; Bruce, C.W.

    1994-08-01

    The mass normalized absorption and extinction coefficients were measured for fog oil aerosol at 3.4 micrometers with a combined photoacoustic and transmissometer system. An extinction spectral profile was determined over a range of infrared (IR) wavelengths from 2.7 to 4.0 micrometers by an IR scanning transmissometer. The extinction spectrum was mass normalized by referencing it to the photoacoustic portion of the experiment. A corresponding Mie calculation was conducted and compared with the above measurements. Agreement is good for the most recent optical coefficients. An extrapolation of this data to other similar petroleum products such as kerosene or diesel fuel that exhibit similar bulk absorption characteristics were briefly examined.

  17. Relating Aerosol Mass and Optical Depth in the Summertime Continental Boundary Layer

    NASA Astrophysics Data System (ADS)

    Brock, C. A.; Wagner, N.; Middlebrook, A. M.; Attwood, A. R.; Washenfelder, R. A.; Brown, S. S.; McComiskey, A. C.; Gordon, T. D.; Welti, A.; Carlton, A. G.; Murphy, D. M.

    2014-12-01

    Aerosol optical depth (AOD), the column-integrated ambient aerosol light extinction, is determined from satellite and ground-based remote sensing measurements. AOD is the parameter most often used to validate earth system model simulations of aerosol mass. Relating aerosol mass to AOD, however, is problematic due to issues including aerosol water uptake as a function of relative humidity (RH) and the complicated relationship between aerosol physicochemical properties and light extinction. Measurements of aerosol microphysical, chemical, and optical properties help to constrain the relationship between aerosol mass and optical depth because aerosol extinction at ambient RH is a function of the abundance, composition and size distribution of the aerosol. We use vertical profiles of humidity and dry aerosol extinction observed in the southeastern United States (U.S.) to examine the relationship between submicron aerosol mass concentration and extinction at ambient RH. We show that the κ-Köhler parameterization directly, and without additional Mie calculations, describes the change in extinction with varying RH as a function of composition for both aged aerosols typical of the polluted summertime continental boundary layer and the biomass burning aerosols we encountered. We calculate how AOD and the direct radiative effect in the eastern U.S. have likely changed due to trends in aerosol composition in recent decades. We also examine the sensitivity of AOD to the RH profile and to aerosol composition, size distribution and abundance.

  18. Secondary organic material formed by methylglyoxal in aqueous aerosol mimics - Part 1: Surface tension depression and light-absorbing products

    NASA Astrophysics Data System (ADS)

    Schwier, A. N.; Shapiro, E. L.; Sareen, N.; McNeill, V. F.

    2009-07-01

    We show that methylglyoxal forms light-absorbing secondary organic material in aqueous ammonium sulfate and ammonium nitrate solutions mimicking tropospheric aerosol particles. The light-absorbing products form on the order of minutes, and solution composition continues to change over several days. The results suggest an aldol condensation pathway involving the participation of the ammonium ion. Aqueous solutions of methylglyoxal, with and without inorganic salts, exhibit surface tension depression. Methylglyoxal uptake could potentially change the optical properties, climate effects, and heterogeneous chemistry of the seed aerosol over its lifetime.

  19. Aerosol Climate Time Series in ESA Aerosol_cci

    NASA Astrophysics Data System (ADS)

    Popp, Thomas; de Leeuw, Gerrit; Pinnock, Simon

    2016-04-01

    Within the ESA Climate Change Initiative (CCI) Aerosol_cci (2010 - 2017) conducts intensive work to improve algorithms for the retrieval of aerosol information from European sensors. Meanwhile, full mission time series of 2 GCOS-required aerosol parameters are completely validated and released: Aerosol Optical Depth (AOD) from dual view ATSR-2 / AATSR radiometers (3 algorithms, 1995 - 2012), and stratospheric extinction profiles from star occultation GOMOS spectrometer (2002 - 2012). Additionally, a 35-year multi-sensor time series of the qualitative Absorbing Aerosol Index (AAI) together with sensitivity information and an AAI model simulator is available. Complementary aerosol properties requested by GCOS are in a "round robin" phase, where various algorithms are inter-compared: fine mode AOD, mineral dust AOD (from the thermal IASI spectrometer, but also from ATSR instruments and the POLDER sensor), absorption information and aerosol layer height. As a quasi-reference for validation in few selected regions with sparse ground-based observations the multi-pixel GRASP algorithm for the POLDER instrument is used. Validation of first dataset versions (vs. AERONET, MAN) and inter-comparison to other satellite datasets (MODIS, MISR, SeaWIFS) proved the high quality of the available datasets comparable to other satellite retrievals and revealed needs for algorithm improvement (for example for higher AOD values) which were taken into account for a reprocessing. The datasets contain pixel level uncertainty estimates which were also validated and improved in the reprocessing. For the three ATSR algorithms the use of an ensemble method was tested. The paper will summarize and discuss the status of dataset reprocessing and validation. The focus will be on the ATSR, GOMOS and IASI datasets. Pixel level uncertainties validation will be summarized and discussed including unknown components and their potential usefulness and limitations. Opportunities for time series extension

  20. Impact production of CO2 by the Cretaceous/Tertiary extinction bolide and the resultant heating of the earth

    NASA Technical Reports Server (NTRS)

    O'Keefe, John D.; Ahrens, Thomas J.

    1989-01-01

    Various observations and data demonstrate that sea level at the end of the Cretaceous was 150-200 m higher than at present, suggesting the possibility that the extinction bolide struck a shallow marine carbonate-rich sedimentary section. It is shown here that the impact of such a bolide (about 5 km in radius) onto a carbonate-rich terrane would increase the CO2 content of the atmosphere by a factor of two to ten. Additional dissolution of CO2 from the ocean's photic zone could release much larger quantities of CO2. The impact-induced release of CO2, by itself, would enhance atmospheric greenhouse heating and give rise to a worldwide increase in temperature from 2 K to 10 K for periods of 10,000 to 100,000 years.

  1. Dimers and organosulfates derived from biogenic oxidation products in aerosols during the Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX) in California 2007 and 2009 (Invited)

    NASA Astrophysics Data System (ADS)

    Glasius, M.; Worton, D. R.; Kristensen, K.; Nguyen, Q.; Surratt, J.; Enggrob, K. L.; Bouvier-Brown, N. C.; Farmer, D.; Docherty, K. S.; Platt, S.; Bilde, M.; Nøjgaard, J. K.; Seinfeld, J.; Jimenez, J. L.; Goldstein, A.

    2010-12-01

    Oxidation products of biogenic volatile organic compounds, such as monoterpenes and isoprene, contribute to biogenic secondary organic aerosol (BSOA). The organosulfate derivatives of these compounds are formed through heterogeneous reactions involving sulphur compounds, with a considerable contribution from anthropogenic sources. Organosulfate derivatives of biogenic oxidation products thus belong to a new group of anthropogenic enhanced biogenic SOA (ABSOA). The Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX) during summers of 2007 and 2009 provided an excellent platform at Blodgett Forest, California (a ponderosa pine plantation) for studying ABSOA. Typically, polluted air masses were transported upslope from the California Central Valley during day, while night conditions were influenced by downslope transport of air masses, low local atmospheric mixing and formation of a shallow boundary layer. We collected particle samples (PM2.5) as one nighttime and two daytime samples per day. After extraction of filters in polar organic solvents (i.e. acetonitrile or methanol), organic aerosol constituents were analyzed by HPLC coupled through an electrospray inlet to a quadrupole time-of-flight mass spectrometer (qTOF-MS). Organosulfates and nitrooxy organosulfates derived from oxidation products of α-pinene, β-pinene, limonene and isoprene were identified based on their molecular mass and MS fragmentation patterns. Measurements by High Resolution Time of Flight Aerosol Mass Spectrometry (HR-ToF-AMS) show high mass loadings of nitrate in the night and morning samples with highest levels of the nitrooxy organosulfates with MW 295 and MW 297. This may indicate that elevated levels of nitrate and nitrooxy organosulfates are formed in the same polluted air mass, probably through nitrate radical reactions. Terpenylic acid, diterpenylic acid acetate, and methylbutane tricarboxylic acid were found at concentrations comparable to pinic acid. A dimer of

  2. Global and regional validation of the Collection 6 MODIS dark target aerosol products, and comparison to Collection 5

    NASA Astrophysics Data System (ADS)

    Munchak, L. A.; Levy, R. C.; Mattoo, S.

    2014-12-01

    The MODIS Collection 6 (C6) dark targets aerosol algorithms include several updates, including multiple wind speed look up tables over ocean and improved sensor calibration. We analyze the entirety of the MODIS-Aqua aerosol record against AERONET to characterize uncertainty in the products, and relate the new collection to the well-characterized Collection 5 (C5) products to understand specific improvements. Over land, ~70% of high quality AOD retrievals at 0.55 μm are within the C5 expected error bounds, which is comparable to C5; however, a slight overestimation of AOD at low optical depths and a slight underestimation at high optical depths that was observed in C5 has been eliminated in C6. The highest agreement with AERONET occurs in the Eastern U.S. and Europe. Regions with large surface reflectance, such as the Western U.S., or higher aerosol loading, including much of Africa and South America, remain a challenge. Over ocean, the inclusion of wind speed in the surface characterization has removed a wind speed dependant bias, and globally, ~63% of high quality AOD retrievals at 0.55 μm are within the C5 expected error bounds. The dust outflow regions off the coast of Africa show the poorest agreement with AERONET. The aerosol products validate acceptably for science, though users should be aware of some regional biases we present in this work.

  3. The Statistical Evolution of Multiple Generations of Oxidation Products in the Photochemical Aging of Chemically Reduced Organic Aerosol

    SciTech Connect

    Wilson, Kevin R.; Smith, Jared D.; Kessler, Sean; Kroll, Jesse H.

    2011-10-03

    The heterogeneous reaction of hydroxyl radicals (OH) with squalane and bis(2-ethylhexyl) sebacate (BES) particles are used as model systems to examine how distributions of reactionproducts evolve during the oxidation of chemically reduced organic aerosol. A kinetic model of multigenerational chemistry, which is compared to previously measured (squalane) and new(BES) experimental data, reveals that it is the statistical mixtures of different generations of oxidation products that control the average particle mass and elemental composition during thereaction. The model suggests that more highly oxidized reaction products, although initially formed with low probability, play a large role in the production of gas phase reaction products.In general, these results highlight the importance of considering atmospheric oxidation as a statistical process, further suggesting that the underlying distribution of molecules could playimportant roles in aerosol formation as well as in the evolution of key physicochemical properties such as volatility and hygroscopicity.

  4. Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime

    NASA Astrophysics Data System (ADS)

    Hodzic, Alma; Kasibhatla, Prasad S.; Jo, Duseong S.; Cappa, Christopher D.; Jimenez, Jose L.; Madronich, Sasha; Park, Rokjin J.

    2016-06-01

    Recent laboratory studies suggest that secondary organic aerosol (SOA) formation rates are higher than assumed in current models. There is also evidence that SOA removal by dry and wet deposition occurs more efficiently than some current models suggest and that photolysis and heterogeneous oxidation may be important (but currently ignored) SOA sinks. Here, we have updated the global GEOS-Chem model to include this new information on formation (i.e., wall-corrected yields and emissions of semi-volatile and intermediate volatility organic compounds) and on removal processes (photolysis and heterogeneous oxidation). We compare simulated SOA from various model configurations against ground, aircraft and satellite measurements to assess the extent to which these improved representations of SOA formation and removal processes are consistent with observed characteristics of the SOA distribution. The updated model presents a more dynamic picture of the life cycle of atmospheric SOA, with production rates 3.9 times higher and sinks a factor of 3.6 more efficient than in the base model. In particular, the updated model predicts larger SOA concentrations in the boundary layer and lower concentrations in the upper troposphere, leading to better agreement with surface and aircraft measurements of organic aerosol compared to the base model. Our analysis thus suggests that the long-standing discrepancy in model predictions of the vertical SOA distribution can now be resolved, at least in part, by a stronger source and stronger sinks leading to a shorter lifetime. The predicted global SOA burden in the updated model is 0.88 Tg and the corresponding direct radiative effect at top of the atmosphere is -0.33 W m-2, which is comparable to recent model estimates constrained by observations. The updated model predicts a population-weighed global mean surface SOA concentration that is a factor of 2 higher than in the base model, suggesting the need for a reanalysis of the contribution of

  5. Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime

    NASA Astrophysics Data System (ADS)

    Hodzic, A.; Kasibhatla, P. S.; Jo, D. S.; Cappa, C.; Jimenez, J. L.; Madronich, S.; Park, R. J.

    2015-11-01

    Recent laboratory studies suggest that secondary organic aerosol (SOA) formation rates are higher than assumed in current models. There is also evidence that SOA removal by dry and wet deposition occurs more efficiently than some current models suggest, and that photolysis and heterogeneous oxidation may be important (but currently ignored) SOA sinks. Here, we have updated the global GEOS-Chem model to include this new information on formation (i.e. wall-corrected yields and emissions of semi-volatile and intermediate volatility organic compounds) and on removal processes (photolysis and heterogeneous oxidation). We compare simulated SOA from various model configurations against ground, aircraft and satellite measurements to assess the extent to which these improved representations of SOA formation and removal processes are consistent with observed characteristics of the SOA distribution. The updated model presents a more dynamic picture of the lifecycle of atmospheric SOA, with production rates 4 times higher and sinks a factor of 3.7 more efficient than in the base model. In particular, the updated model predicts larger SOA concentrations in the boundary layer and lower concentrations in the upper troposphere, leading to better agreement with surface and aircraft measurements of organic aerosol compared to the base model. Our analysis thus suggests that the long-standing discrepancy in model predictions of the vertical SOA distribution can now be resolved, at least in part, by a stronger source and stronger sinks leading to a shorter lifetime. The predicted global SOA burden in the updated model is 0.95 Tg and the corresponding direct radiative forcing at top of the atmosphere is -0.35 W m-2, which is comparable to recent model estimates constrained by observations. The updated model predicts a population-weighed global mean surface SOA concentration that is a factor of 2 higher than in the base model, suggesting the need for a reanalysis of the contribution of

  6. Secondary organic aerosol from ozone-initiated reactions with terpene-rich household products

    SciTech Connect

    Coleman, Beverly; Coleman, Beverly K.; Lunden, Melissa M.; Destaillats, Hugo; Nazaroff, William W.

    2008-01-01

    We analyzed secondary organic aerosol (SOA) data from a series of small-chamber experiments in which terpene-rich vapors from household products were combined with ozone under conditions analogous to product use indoors. Reagents were introduced into a continuously ventilated 198 L chamber at steady rates. Consistently, at the time of ozone introduction, nucleation occurred exhibiting behavior similar to atmospheric events. The initial nucleation burst and growth was followed by a period in which approximately stable particle levels were established reflecting a balance between new particle formation, condensational growth, and removal by ventilation. Airborne particles were measured with a scanning mobility particle sizer (SMPS, 10 to 400 nm) in every experiment and with an optical particle counter (OPC, 0.1 to 2.0 ?m) in a subset. Parameters for a three-mode lognormal fit to the size distribution at steady state were determined for each experiment. Increasing the supply ozone level increased the steady-state mass concentration and yield of SOA from each product tested. Decreasing the air-exchange rate increased the yield. The steady-state fine-particle mass concentration (PM1.1) ranged from 10 to> 300 mu g m-3 and yields ranged from 5percent to 37percent. Steady-state nucleation rates and SOA mass formation rates were on the order of 10 cm-3 s-1 and 10 mu g m-3 min-1, respectively.

  7. Implications of extinction due to meteoritic smoke in the upper stratosphere

    NASA Astrophysics Data System (ADS)

    Neely, Ryan R., III; English, Jason M.; Toon, Owen B.; Solomon, Susan; Mills, Michael; Thayer, Jeffery P.

    2011-12-01

    Recent optical observations of aerosols in the upper stratosphere and mesosphere show significant amounts of extinction at altitudes above about 40 km where the stratospheric sulfate aerosol layer ends. Recent modeling of this region reveals that meteoritic smoke settling from the mesosphere and its interaction with the upper part of the sulfate aerosol layer is the origin of the observed extinction. Extinction in this region has major implications for the interpretation and analysis of several kinds of aerosol data (satellite and lidar). We compare observations from the SAGE II satellite and from NOAA's lidar located at Mauna Loa, Hawaii to extinction profiles derived from the Whole Atmosphere Community Climate Model (WACCM) coupled with the Community Aerosol and Radiation Model for Atmospheres (CARMA). Our results show that a major source of extinction exists in the region above about 30 km that must be addressed by all remote sensing instruments that have traditionally used the stratosphere above about 30 km as an aerosol free region to estimate the molecular component of their total extinction. It is also shown that meteoritic smoke not only contributes to but also becomes the dominant source of aerosol extinction above 35 km and poleward of 30 degrees in latitude, as well as above 40 km in the tropics. After addressing the concerns described here, current and past observations of this region could be reanalyzed to further our understanding of meteoritic dust in the upper stratosphere.

  8. Science verification of operational aerosol and cloud products for TROPOMI on Sentinel-5 precursor

    NASA Astrophysics Data System (ADS)

    Lelli, Luca; Gimeno-Garcia, Sebastian; Sanders, Abram; Sneep, Maarten; Rozanov, Vladimir V.; Kokhanvosky, Alexander A.; Loyola, Diego; Burrows, John P.

    2016-04-01

    With the approaching launch of the Sentinel-5 precursor (S-5P) satellite, scheduled by mid 2016, one preparatory task of the L2 working group (composed by the Institute of Environmental Physics IUP Bremen, the Royal Netherlands Meteorological Institute KNMI De Bilt, and the German Aerospace Center DLR Oberpfaffenhofen) has been the assessment of biases among aerosol and cloud products, that are going to be inferred by the respective algorithms from measurements of the platform's payload TROPOspheric Monitoring Instrument (TROPOMI). The instrument will measure terrestrial radiance with varying moderate spectral resolutions from the ultraviolet throughout the shortwave infrared. Specifically, all the operational and verification algorithms involved in this comparison exploit the sensitivity of molecular oxygen absorption (the A-band, 755-775 nm, with a resolution of 0.54 nm) to changes in optical and geometrical parameters of tropospheric scattering layers. Therefore, aerosol layer height (ALH) and thickness (AOT), cloud top height (CTH), thickness (COT) and albedo (CA) are the targeted properties. First, the verification of these properties has been accomplished upon synchronisation of the respective forward radiative transfer models for a variety of atmospheric scenarios. Then, biases against independent techniques have been evaluated with real measurements of selected GOME-2 orbits. Global seasonal bias assessment has been carried out for CTH, CA and COT, whereas the verification of ALH and AOT is based on the analysis of the ash plume emitted by the icelandic volcanic eruption Eyjafjallajökull in May 2010 and selected dust scenes off the Saharan west coast sensed by SCIAMACHY in year 2009.

  9. The use of MODIS data and aerosol products for air quality prediction

    NASA Astrophysics Data System (ADS)

    Hutchison, Keith D.; Smith, Solar; Faruqui, Shazia

    2004-09-01

    The Center for Space Research (CSR) is exploring new approaches to integrate data collected by the MODerate resolution Imaging Spectroradiometer (MODIS) sensor, flown on NASA's Earth Observing System (EOS) satellites, into a real-time prediction methodology to support operational air quality forecasts issued by the Monitoring Operations Division (MOD) of the Texas Commission on Environmental Quality (TCEQ). Air pollution is a widespread problem in the United States, with over 130 million individuals exposed to levels of air pollution that exceed one or more health-based standards. Texas air quality is under assault by a variety of anthropogenic sources associated with a rapidly growing population along with increases in emissions from the diesel engines that drive international trade between the US and Central America. The challenges of meeting air quality standards established by the Environmental Protection Agency are further impacted by the transport of pollution into Texas that originates from outside its borders and are cumulative with those generated by local sources. In an earlier study, CSR demonstrated the value of MODIS imagery and aerosol products for monitoring ozone-laden pollution that originated in the central US before migrating into Texas and causing TCEQ to issue a health alert for 150 counties. Now, data from this same event are re-analyzed in an attempt to predict air quality from MODIS aerosol optical thickness (AOT) observations. The results demonstrate a method to forecast air quality from remotely sensed satellite observations when the transient pollution can be isolated from local sources. These pollution sources can be separated using TCEQ's network of ground-based Continuous Air quality Monitoring (CAM) stations.

  10. Thermal Transgressions and Phanerozoic Extinctions

    NASA Astrophysics Data System (ADS)

    Worsley, T. R.; Kidder, D. L.

    2007-12-01

    A number of significant Phanerozoic extinctions are associated with marine transgressions that were probably driven by rapid ocean warming. The conditions associated with what we call thermal transgressions are extremely stressful to life on Earth. The Earth system setting associated with end-Permian extinction exemplifies an end-member case of our model. The conditions favoring extreme warmth and sea-level increases driven by thermal expansion are also conducive to changes in ocean circulation that foster widespread anoxia and sulfidic subsurface ocean waters. Equable climates are characterized by reduced wind shear and weak surface ocean circulation. Late Permian and Early Triassic thermohaline circulation differs considerably from today's world, with minimal polar sinking and intensified mid-latitude sinking that delivers sulfate from shallow evaporative areas to deeper water where it is reduced to sulfide. Reduced nutrient input to oceans from land at many of the extinction intervals results from diminished silicate weathering and weakened delivery of iron via eolian dust. The falloff in iron-bearing dust leads to minimal nitrate production, weakening food webs and rendering faunas and floras more susceptible to extinction when stressed. Factors such as heat, anoxia, ocean acidification, hypercapnia, and hydrogen sulfide poisoning would significantly affect these biotas. Intervals of tectonic quiescence set up preconditions favoring extinctions. Reductions in chemical silicate weathering lead to carbon dioxide buildup, oxygen drawdown, nutrient depletion, wind and ocean current abatement, long-term global warming, and ocean acidification. The effects of extinction triggers such as large igneous provinces, bolide impacts, and episodes of sudden methane release are more potent against the backdrop of our proposed preconditions. Extinctions that have characteristics we call for in the thermal transgressions include the Early Cambrian Sinsk event, as well as

  11. New ARM Measurements of Clouds, Aerosols, and the Atmospheric State

    NASA Astrophysics Data System (ADS)

    Mather, J.

    2012-04-01

    The DOE Atmospheric Radiation Measurement (ARM) program has recently enhanced its observational capabilities at its fixed and mobile sites as well as its aerial facility. New capabilities include scanning radars, several types of lidars, an array of aerosol instruments, and in situ cloud probes. All ARM sites have been equipped with dual frequency scanning cloud radars that will provide three-dimensional observations of cloud fields for analysis of cloud field evolution. Sites in Oklahoma, Alaska, and Papua New Guinea have also received scanning centimeter wavelength radars for observing precipitation fields. This combination of radars will provide the means to study the interaction of clouds and precipitation. New lidars include a Raman lidar in Darwin, Australia and High Spectral Resolution Lidars in Barrow and with the second ARM Mobile Facility. Each of these lidars will provide profiles of aerosol extinction while the Raman will also measure profiles of water vapor. ARM has also expanded its capabilities in the realm of aerosol observations. ARM is adding Aerosol Observing Systems to its sites in Darwin and the second mobile facility. These aerosol systems principally provided measurements of aerosol optical properties. In addition, a new Mobile Aerosol Observing System has been developed that includes a variety of instruments to provide information about aerosol chemistry and size distributions. Many of these aerosol instruments are also available for the ARM Aerial Facility. The Aerial Facility also now includes a variety of cloud probes for measuring size distribution and water content. The new array of ARM instruments is intended to build upon the existing ARM capabilities to better study the interactions among aerosol, clouds, and precipitation. Data from these instruments are now available and development of advanced data products is underway.

  12. Production of Inhalable Submicrometer Aerosols from Conventional Mesh Nebulizers for Improved Respiratory Drug Delivery

    PubMed Central

    Longest, P. Worth; Spence, Benjamin M.; Holbrook, Landon T.; Mossi, Karla M.; Son, Yoen-Ju; Hindle, Michael

    2012-01-01

    Submicrometer and nanoparticle aerosols may significantly improve the delivery efficiency, dissolution characteristics, and bioavailability of inhaled pharmaceuticals. The objective of this study was to explore the formation of submicrometer and nanometer aerosols from mesh nebulizers suitable for respiratory drug delivery using experiments and computational fluid dynamics (CFD) modeling. Mesh nebulizers were coupled with add-on devices to promote aerosol drying and the formation of submicrometer particles, as well as to control the inhaled aerosol temperature and relative humidity. Cascade impaction experiments were used to determine the initial mass median aerodynamic diameters of 0.1% albuterol aerosols produced by the AeroNeb commercial (4.69 μm) and lab (3.90 μm) nebulizers and to validate the CFD model in terms of droplet evaporation. Through an appropriate selection of flow rates, nebulizers, and model drug concentrations, submicrometer and nanometer aerosols could be formed with the three devices considered. Based on CFD simulations, a wire heated design was shown to overheat the airstream producing unsafe conditions for inhalation if the aerosol was not uniformly distributed in the tube cross-section or if the nebulizer stopped producing droplets. In comparison, a counter-flow heated design provided sufficient thermal energy to produce submicrometer particles, but also automatically limited the maximum aerosol outlet temperature based on the physics of heat transfer. With the counter-flow design, submicrometer aerosols were produced at flow rates of 5, 15, and 30 LPM, which may be suitable for various forms of oral and nasal aerosol delivery. Thermodynamic conditions of the aerosol stream exiting the counter-flow design were found be in a range of 21-45 °C with relative humidity greater than 40% in some cases, which was considered safe for direct inhalation and advantageous for condensational growth delivery. PMID:22707794

  13. Aerosol studies in mid-latitude coastal environments in Australia

    NASA Technical Reports Server (NTRS)

    Young, S. A.; Cutten, D.; Lynch, M. J.; Davies, J. E.

    1986-01-01

    The results of the evaluation of several inversion procedures that were used to select one which provides the most accurate atmospheric extinction profiles for small aerosol extinction coefficients (that often predominate in the maritime airmass) are presented. Height profiles of atmospheric extinction calculated by a two component atmospheric solution to the LIDAR equation will be compared with corresponding in-situ extinction profiles based on the size distribution profiles obtained in Western Australia. Values of the aerosol backscatter to extinction ratio obtained from multi-angle LIDAR measurements will be used in this solution.

  14. Effect of heavy haze and aerosol pollution on rice and wheat productions in China

    NASA Astrophysics Data System (ADS)

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-07-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28–49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades.

  15. Effect of heavy haze and aerosol pollution on rice and wheat productions in China.

    PubMed

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-01-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28-49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades. PMID:27388031

  16. Effect of heavy haze and aerosol pollution on rice and wheat productions in China

    PubMed Central

    Tie, Xuexi; Huang, Ru-Jin; Dai, Wenting; Cao, Junji; Long, Xin; Su, Xiaoli; Zhao, Shuyu; Wang, Qiyuan; Li, Guohui

    2016-01-01

    In China, regional haze pollution is a serious environmental problem. The impact on ecosystem, however, is not clearly understood. This study investigates the effect of regional haze pollution on the yields of rice and wheat in China. The spatial and temporal distributions of aerosol optical depth (AOD) show high particulate pollution in the North China Plain region, Yangtze River Delta region, the central eastern China, and the Si Chuan Basin, coexisted largely with crop growth in time and space. The solar irradiance reaching these regions is estimated to reduce by up to 28–49%, calculated using the AOD distributions and tropospheric ultraviolet-visible (TUV) model. Reduction of solar irradiance in these regions can depress optimal yields of about 45% of rice and 75% of wheat growth in China, leading to 2% reduction in total rice production and 8% reduction in total wheat production in China. However, there are large uncertainties of the estimate related to the diffuse solar radiation. For high diffuse radiation case, the estimate reductions of rice and wheat decrease to 1% and 4.5%, respectively. A further detailed study is needed to clearly understand this effect to meet the growing food demand in the nation in the coming decades. PMID:27388031

  17. APPLICATION OF POLLUTION PREVENTION TECHNIQUES TO REDUCE INDOOR AIR EMISSIONS FROM AEROSOL CONSUMER PRODUCTS (PROJECT SUMMARY)

    EPA Science Inventory

    report gives results of research, undertaken to develop tools and meth-odologies to measure aerosol chemical and particle dispersion through space. Georgia Tech Research Institute re-searchers built an Aerosol Mass Spec-tral Interface (AMSI), which is interfaced with a mass spect...

  18. Gas-phase products and secondary organic aerosol formation from the ozonolysis and photooxidation of myrcene

    NASA Astrophysics Data System (ADS)

    Böge, Olaf; Mutzel, Anke; Iinuma, Yoshiteru; Yli-Pirilä, Pasi; Kahnt, Ariane; Joutsensaari, Jorma; Herrmann, Hartmut

    2013-04-01

    Terrestrial vegetation releases a great variety of volatile organic compounds (VOC) into the atmosphere. Monoterpenes, like myrcene, contribute significantly to this global biogenic VOC emission. In the atmosphere, monoterpenes rapidly undergo oxidation reactions by OH radicals (mainly during the daytime), NO3 radicals (mainly during the nighttime) and O3 to form multifunctional oxidation products. The products of these reactions are likely to be of low volatility and hence might lead to secondary organic aerosol (SOA) formation. In the present study, we report results from a series of chamber experiments performed in the LEAK chamber at TROPOS in which the gas-phase products and SOA yields obtained from myrcene O3 reactions with and without an OH radical scavenger as well as from the myrcene OH radical reaction in the presence of NOx have been measured. During the experiments the consumption of myrcene as well as the formation of gas-phase products was monitored using a proton transfer reaction mass spectrometer (PTR-MS). Ozone concentration was measured by an O3 monitor and the mixing ratios of nitrogen oxides were measured by a NOx monitor. Particle size distributions between 3-900 nm were monitored every 11 min using a differential mobility particle sizer (DMPS) system. In addition to the products observed by means of the PTR-MS by their m/z values, an identification of carbonylic compounds by their DNPH derivatives was performed. Beside low molecular mass products the formation of 4-vinyl-4-pentenal with a yield of 55 % in myrcene ozonolysis has been observed. The further oxidation of this major first generation product lead to the formation of two dicarbonylic products with m/z 113 and to SOA formation. The influence of the continuing oxidation of 4-vinyl-4-pentenal on SOA formation will be discussed in detail. The emergence of the gas-phase product hydroxyacetone as direct result of the myrcene ozone reaction will be mooted, because hydroxyacetone seems to

  19. Study on particulate matter air pollution in Beijing with MODIS aerosol level 2 products

    NASA Astrophysics Data System (ADS)

    Mao, Jietai; Li, Chengcai; Lau, Alexis K.

    2004-09-01

    In the run-up to the 2008 Olympic Games in Beijing, Chinese government officials at both the central and municipal levels are keenly aware that they must transform Beijing into a world-class city. According to the Beijing Municipal Environmental Protection Bureau (BJEPB) to improve its air quality some actions are adopting, including taking steps to increase the forested area surrounding the city preventing dust storms, reducing the automotive vehicles, moving polluting factories now inside the fourth ring road ringing the inner city to locations outside of the fourth ring road, and switching the fuel of public buses and taxis from diesel to natural gas, etc. Will they eliminate most serious environmental problems in Beijing? MODIS aerosol products are helping us to answer this kind of questions. A long-term validation has been finished by sun-photometer observations, and the results proved the relative error of MODIS level 2 products was slightly larger than the estimation of Chu et al. (2002) from the results in most AERONET sites. However, the comparison between the products and moisture-corrected air pollution index (API) data, which were daily released to public by EPB, showed a high correlation coefficient. An air pollution episode in 2003 was investigated by the usage of satellite products. Our conclusion for the air pollution control strategy in Beijing is that only reducing the pollution sources from inner city can't fully solve the pollution problems in Beijing and the regional transports from the nearby southern provinces are contributing a lot to the pollution situation in Beijing.

  20. An improved whitecap timescale for sea spray aerosol production flux modeling using the discrete whitecap method

    NASA Astrophysics Data System (ADS)

    Callaghan, Adrian H.

    2013-09-01

    The discrete whitecap method (DWM) to model the sea spray aerosol (SSA) production flux explicitly requires a whitecap timescale, which up to now has only considered a whitecap decay timescale, τdecay. A reevaluation of the DWM suggests that the whitecap timescale should account for the total whitecap lifetime (τwcap), which consists of both the formation timescale (τform) and the decay timescale (timescale definitions are given in the text). Here values of τform for 552 oceanic whitecaps measured at the Martha's Vineyard Coastal Observatory on the east coast of the USA are presented, and added to the corresponding values of τdecay to form 552 whitecap timescales. For the majority of whitecaps, τform makes up about 20-25% of τwcap, but this can be as large as 70% depending on the value of τdecay. Furthermore, an area-weighted mean whitecap timescale for use in the DWM (τDWM) is defined that encompasses the variable nature of individual whitecap lifetimes within a given time period, and is calculated to be 5.3 s for this entire data set. This value is combined with previously published whitecap coverage parameterizations and estimates of SSA particle production per whitecap area to form a size-resolved SSA production flux parameterization (dF(r80)/dlog10r80). This parameterization yields integrated sea-salt mass fluxes that are largely within the range of uncertainty of recent measurements over the size range 0.029 µm < r80 < 0.580 µm. Physical factors controlling whitecap lifetime such as bubble plume lifetime and surfactant stabilization are discussed in the context of SSA production from whitecaps.

  1. Is extinction forever?

    PubMed

    Smith-Patten, Brenda D; Bridge, Eli S; Crawford, Priscilla H C; Hough, Daniel J; Kelly, Jeffrey F; Patten, Michael A

    2015-05-01

    Mistrust of science has seeped into public perception of the most fundamental aspect of conservation-extinction. The term ought to be straightforward, and yet, there is a disconnect between scientific discussion and public views. This is not a mere semantic issue, rather one of communication. Within a population dynamics context, we say that a species went locally extinct, later to document its return. Conveying our findings matters, for when we use local extinction, an essentially nonsensical phrase, rather than extirpation, which is what is meant, then we contribute to, if not create outright, a problem for public understanding of conservation, particularly as local extinction is often shortened to extinction in media sources. The public that receives the message of our research void of context and modifiers comes away with the idea that extinction is not forever or, worse for conservation as a whole, that an extinction crisis has been invented. PMID:25711479

  2. Is extinction forever?

    PubMed Central

    Bridge, Eli S.; Crawford, Priscilla H. C.; Hough, Daniel J.; Kelly, Jeffrey F.; Patten, Michael A.

    2015-01-01

    Mistrust of science has seeped into public perception of the most fundamental aspect of conservation—extinction. The term ought to be straightforward, and yet, there is a disconnect between scientific discussion and public views. This is not a mere semantic issue, rather one of communication. Within a population dynamics context, we say that a species went locally extinct, later to document its return. Conveying our findings matters, for when we use local extinction, an essentially nonsensical phrase, rather than extirpation, which is what is meant, then we contribute to, if not create outright, a problem for public understanding of conservation, particularly as local extinction is often shortened to extinction in media sources. The public that receives the message of our research void of context and modifiers comes away with the idea that extinction is not forever or, worse for conservation as a whole, that an extinction crisis has been invented. PMID:25711479

  3. Biological selectivity of extinction

    NASA Astrophysics Data System (ADS)

    Kitchell, Jennifer A.

    Selective survival across major extinction event horizons is both a bothersome puzzle and an opportunity to delimit the biologically interesting question of causality. Heritable differences in characters may have predictable consequences in terms of differential species survival. Differences in magnitude and intensity of extinction are insufficient to distinguish background from mass extinction regimes. Biological adaptations may establish links of causality between abnormal times of mass extinction and normal times of background extinction. A current hypothesis, developed from a comparison of extinction patterns among Late Cretaceous molluscs, is that biological adaptations of organisms, effective during normal times of Earth history, are ineffectual during times of crises. A counter example is provided by data from high-latitude laminated marine strata that preserve evidence of an actively exploited life-history strategy among Late Cretaceous phytoplankton. These data illustrate a causal dependency between a biological character selected for during times of background extinction and macroevolutionary survivorship during an unusual time of crisis.

  4. High-time resolved measurements of biogenic and anthropogenic secondary organic aerosol precursors and products in urban air

    NASA Astrophysics Data System (ADS)

    Flores, Rosa M.; Doskey, Paul V.

    2016-04-01

    Volatile organic compounds (VOCs), which are present in the atmosphere entirely in the gas phase are directly emitted by biogenic (~1089 Tg yr-1) and anthropogenic sources (~185 Tg yr-1). However, the sources and molecular speciation of intermediate VOCs (IVOCs), which are for the most part also present almost entirely in the gas phase, are not well characterized. The VOCs and IVOCs participate in reactions that form ozone and semivolatile OC (SVOC) that partition into the aerosol phase. Formation and evolution of secondary organic aerosol (SOA) are part of a complex dynamic process that depends on the molecular speciation and concentration of VOCs, IVOCs, primary organic aerosol (POA), and the level of oxidants (NO3, OH, O3). The current lack of understanding of OA properties and their impact on radiative forcing, ecosystems, and human health is partly due to limitations of models to predict SOA production on local, regional, and global scales. More accurate forecasting of SOA production requires high-temporal resolution measurement and molecular characterization of SOA precursors and products. For the subject study, the IVOCs and aerosol-phase organic matter were collected using the high-volume sampling technique and were analyzed by multidimensional gas chromatography with time-of-flight mass spectrometry (GCxGC-ToFMS). The IVOCs included terpenes, terpenoids, n-alkanes, branched alkanes, isoprenoids, alkylbenzenes, cycloalkylbenzenes, PAH, alkyl PAH, and an unresolved complex mixture (UCM). Diurnal variations of OA species containing multiple oxygenated functionalities and selected SOA tracers of isorprene, α-pinene, toluene, cyclohexene, and n-dodecane oxidation were also quantified. The data for SOA precursor and oxidation products presented here will be useful for evaluating the ability of molecular-specific SOA models to forecast SOA production in and downwind of urban areas.

  5. Heterogeneous oxidation of saturated organic aerosols by hydroxyl radicals: uptake kinetics, condensed-phase products, and particle size change

    NASA Astrophysics Data System (ADS)

    George, I. J.; Vlasenko, A.; Slowik, J. G.; Broekhuizen, K.; Abbatt, J. P. D.

    2007-08-01

    The kinetics and reaction mechanism for the heterogeneous oxidation of saturated organic aerosols by gas-phase OH radicals were investigated under NOx-free conditions. The reaction of 150 nm diameter Bis(2-ethylhexyl) sebacate (BES) particles with OH was studied as a proxy for chemical aging of atmospheric aerosols containing saturated organic matter. An aerosol reactor flow tube combined with an Aerodyne time-of-flight aerosol mass spectrometer (ToF-AMS) and scanning mobility particle sizer (SMPS) was used to study this system. Hydroxyl radicals were produced by 254 nm photolysis of O3 in the presence of water vapour. The kinetics of the heterogeneous oxidation of the BES particles was studied by monitoring the loss of a mass fragment of BES with the ToF-AMS as a function of OH exposure. We measured an initial OH uptake coefficient of γ0=1.3 (±0.4), confirming that this reaction is highly efficient. The density of BES particles increased by up to 20% of the original BES particle density at the highest OH exposure studied, consistent with the particle becoming more oxidized. Electrospray ionization mass spectrometry analysis showed that the major particle-phase reaction products are multifunctional carbonyls and alcohols with higher molecular weights than the starting material. Volatilization of oxidation products accounted for a maximum of 17% decrease of the particle volume at the highest OH exposure studied. Tropospheric organic aerosols will become more oxidized from heterogeneous photochemical oxidation, which may affect not only their physical and chemical properties, but also their hygroscopicity and cloud nucleation activity.

  6. Comparison Between NPP-VIIRS Aerosol Data Products and the MODIS AQUA Deep Blue Collection 6 Dataset Over Land

    NASA Technical Reports Server (NTRS)

    Sayer, Andrew M.; Hsu, N. C.; Bettenhausen, C.; Lee, J.; Kondragunta, S.

    2013-01-01

    Aerosols are small particles suspended in the atmosphere and have a variety of natural and man-made sources. Knowledge of aerosol optical depth (AOD), which is a measure of the amount of aerosol in the atmosphere, and its change over time, is important for multiple reasons. These include climate change, air quality (pollution) monitoring, monitoring hazards such as dust storms and volcanic ash, monitoring smoke from biomass burning, determining potential energy yields from solar plants, determining visibility at sea, estimating fertilization of oceans and rainforests by transported mineral dust, understanding changes in weather brought upon by the interaction of aerosols and clouds, and more. The Suomi-NPP satellite was launched late in 2011. The Visible Infrared Imaging Radiometer Suite (VIIRS) aboard Suomi-NPP is being used, among other things, to determine AOD. This study compares the VIIRS dataset to ground-based measurements of AOD, along with a state-of-the-art satellite AOD dataset (the new version of the Moderate Resolution Imaging Spectrometer Deep Blue algorithm) to assess its reliability. The Suomi-NPP satellite was launched late in 2011, carrying several instruments designed to continue the biogeophysical data records of current and previous satellite sensors. The Visible Infrared Imaging Radiometer Suite (VIIRS) aboard Suomi-NPP is being used, among other things, to determine aerosol optical depth (AOD), and related activities since launch have been focused towards validating and understanding this new dataset through comparisons with other satellite and ground-based products. The operational VIIRS AOD product is compared over land with AOD derived from Moderate Resolution Imaging Spectrometer (MODIS) observations using the Deep Blue (DB) algorithm from the forthcoming Collection 6 of MODIS data

  7. High sedimentation rates in the Early Triassic after latest Permian mass extinction: Carbonate production is main factor in non-Arctic regions

    NASA Astrophysics Data System (ADS)

    Horacek, Micha; Brandner, Rainer

    2016-04-01

    A substantial change in sedimentation rates towards higher values has been documented from the Late Permian to the Lower Triassic. Although it is assumed and also has been shown that the deposition of siliciclastic material increased in the Lower Triassic due to stronger erosion because of loss of land cover and increased chemical and physical weathering with extreme climate warming, the main sediment production occurred by marine carbonate production. Still, carbonate production might have been significantly influenced by weathering and erosion in the hinterland, as the transport of dust by storms into the ocean water probably was a main nutrient source for microbial carbonate producers, because "normal" nutrient supply by ocean circulation, i. e. upwelling was strongly reduced due to the elevated temperatures resulting in water-column stratification . Sediment accumulation was also clearly influenced by the paleo-geographic and latitudinal position, with lower carbonate production and sedimentation rates in moderate latitudes. The existence of a "boundary clay" and microbial carbonate mounds and layers in the immediate aftermath of the latest Permian mass extinction points towards a development from a short-timed acid ocean water - resulting in a carbonate production gap and the deposition of the boundary clay towards the deposition of the microbial mounds and layers due to the microbial production of micro-environments with higher alkalinity allowing the production of carbonate. After the return of the ocean water to normal alkalinity planktic production of carbonate resulted in a very high sedimentation rate, especially taking into account the absence of carbonate producing eukaryotic algae and animals.

  8. Satellite assessment of sea spray aerosol productivity: Southern Ocean case study

    NASA Astrophysics Data System (ADS)

    Witek, Marcin L.; Diner, David J.; Garay, Michael J.

    2016-01-01

    Despite many years of observations by multiple sensors, there is still substantial ambiguity regarding aerosol optical depths (AOD) over remote oceans, in particular, over the pristine Southern Ocean. Passive satellite retrievals (e.g., Multiangle Imaging Spectroradiometer (MISR) and Moderate Resolution Imaging Spectroradiometer (MODIS)) and global aerosol transport models show a distinct AOD maximum around the 60°S latitude band. Sun photometer measurements performed by the Maritime Aerosol Network (MAN), on the other hand, indicate no increased AODs over the Southern Ocean. In this study elevated Southern Ocean AODs are examined from the modeling perspective. The primary aerosol component over the Southern Ocean is sea spray aerosol (SSA). Multiple simulations of SSA concentrations and optical depths are carried out using a single modeling framework, the Navy Aerosol Analysis and Prediction System (NAAPS) model. Several SSA emission functions are examined, including recently proposed formulations with sea surface temperature corrections. The differences between NAAPS simulations are primarily due to different SSA emission formulations. The results are compared against satellite-derived AODs from the MISR and MODIS instruments. MISR and MODIS AOD retrievals are further filtered to eliminate retrievals potentially affected by cloud contamination and cloud adjacency effects. The results indicate a very large impact of SSA emission parameterization on the simulated AODs. For some scenarios, the Southern Ocean AOD maximum almost completely disappears. Further MISR and MODIS AOD quality screening substantially improves model/satellite agreement. Based on these comparisons, an optimal SSA emission function for global aerosol transport models is recommended.

  9. A Spatio-Temporal Approach for Global Validation and Analysis of MODIS Aerosol Products

    NASA Technical Reports Server (NTRS)

    Ichoku, Charles; Chu, D. Allen; Mattoo, Shana; Kaufman, Yoram J.; Remer, Lorraine A.; Tanre, Didier; Slutsker, Ilya; Holben, Brent N.; Lau, William K. M. (Technical Monitor)

    2001-01-01

    With the launch of the MODIS sensor on the Terra spacecraft, new data sets of the global distribution and properties of aerosol are being retrieved, and need to be validated and analyzed. A system has been put in place to generate spatial statistics (mean, standard deviation, direction and rate of spatial variation, and spatial correlation coefficient) of the MODIS aerosol parameters over more than 100 validation sites spread around the globe. Corresponding statistics are also computed from temporal subsets of AERONET-derived aerosol data. The means and standard deviations of identical parameters from MOMS and AERONET are compared. Although, their means compare favorably, their standard deviations reveal some influence of surface effects on the MODIS aerosol retrievals over land, especially at low aerosol loading. The direction and rate of spatial variation from MODIS are used to study the spatial distribution of aerosols at various locations either individually or comparatively. This paper introduces the methodology for generating and analyzing the data sets used by the two MODIS aerosol validation papers in this issue.

  10. Aerosol Radiative Forcing Estimates from South Asian Clay Brick Production Based on Direct Emission Measurements

    NASA Astrophysics Data System (ADS)

    Weyant, C.; Athalye, V.; Ragavan, S.; Rajarathnam, U.; Kr, B.; Lalchandani, D.; Maithel, S.; Malhotra, G.; Bhanware, P.; Thoa, V.; Phuong, N.; Baum, E.; Bond, T. C.

    2012-12-01

    About 150-200 billion clay bricks are produced in India every year. Most of these bricks are fired in small-scale traditional kilns that burn coal or biomass without pollution controls. Reddy and Venkataraman (2001) estimated that 8% of fossil fuel related PM2.5 emissions and 23% of black carbon emissions in India are released from brick production. Few direct emissions measurements have been done in this industry and black carbon emissions, in particular, have not been previously measured. In this study, 9 kilns representing five common brick kiln technologies were tested for aerosol properties and gaseous pollutant emissions, including optical scattering and absorption and thermal-optical OC/EC. Simple relationships are then used to estimate the radiative-forcing impact. Kiln design and fuel quality greatly affect the overall emission profiles and relative climate warming. Batch production kilns, such as the Downdraft kiln, produce the most PM2.5 (0.97 gPM2.5/fired brick) with an OC/EC fraction of 0.3. Vertical Shaft Brick kilns using internally mixed fuels produce the least PM (0.09 gPM2.5/kg fired brick) with the least EC (OC/EC = 16.5), but these kilns are expensive to implement and their use throughout Southern Asia is minimal. The most popular kiln in India, the Bull's Trench kiln, had fewer emissions per brick than the Downdraft kiln, but an even higher EC fraction (OC/EC = 0.05). The Zig-zag kiln is similar in structure to the Bull's Trench kiln, but the emission factors are significantly lower: 50% reduction for CO, 17% for PM2.5 and 60% for black carbon. This difference in emissions suggests that converting traditional Bull's Trench kilns into less polluting Zig-zag kilns would result in reduced atmospheric warming from brick production.

  11. The Remote Sensing of Mineral Aerosols and Their Impact on Phytoplankton Productivity using Sea WiFS

    NASA Technical Reports Server (NTRS)

    Stegmann, Petra M.

    1998-01-01

    The main objective of this proposal was to use SeaWiFs data to study the relationship between aerosols found in aeollan dust and photosynthesis of phytoplankton in open ocean surface waters. This project was a collaborative effort between myself and Dr. Neil Tindale at Texas A&M University and followed on our earlier funded proposal which had been designed as a proof-of-concept study to determine if ocean color sensors such as the Coastal Zone Color Scanner (CZCS) could be used to detect and map large-scale mineral aerosol plumes. Despite the large spatial and temporal gaps inherent in the CZCS data coverage, our results from this initial study indicated that an ocean color sensor could indeed be used to detect aerosols. These encouraging results led us to propose in this proposal the use of SeaWiFS data to study mineral aerosol transport and its impact on phytoplankton production. This proposal orignally intended to make use of SeaWiFS images, but as the launch delay of SeaWiFS dragged on, we had to make do with other satellite data sets. Thus, the focus of this proposal became the CSCS image archive instead. I detail my results and accomplishments with this data set.

  12. Regional Comparison and Assimilation of GOCART and MODIS Aerosol Optical Depth across the Eastern U.S.

    NASA Technical Reports Server (NTRS)

    Matsui, Toshihisa; Kreidenweis, Sonia M.; Pielke, Roger A., Sr.; Schichtel, Bret; Yu, Hongbin; Chin, Mian; Chu, D. Allen; Niyogi, Dev

    2004-01-01

    This study compares aerosol optical depths (AOD) products from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model and their integrated products with ground measurements across the eastern U.S. from March 1, 2000 to December 31, 2001. The Terra MODIS Level-3 (collection 4) AOD at 0.55 pm has better correlation, but consistently overestimates the values of the Aerosol Robotic Network (AERONET) measurements. GOCART has small biases for a 22-month integration, and slight positive biases are appeared for the cold season. These results are also supported by the comparison with the IMPROVE (Interagency Monitoring of Protected Visual Environments) light extinction index. The optimal interpolation improves the daily-scale RMSE from either MODIS or GOCART alone. However, the regional biases in the aerosol products constitute a major constraint to the optimal estimate of AOD.

  13. Preliminary results for salt aerosol production intended for marine cloud brightening, using effervescent spray atomization.

    PubMed

    Cooper, Gary; Foster, Jack; Galbraith, Lee; Jain, Sudhanshu; Neukermans, Armand; Ormond, Bob

    2014-12-28

    The large-scale production of vast numbers of suitable salt nuclei and their upward launch is one of the main technological barriers to the experimental testing of marine cloud brightening (MCB). Very promising, though not definitive, results have been obtained using an adapted version of effervescent spray atomization. The process is simple, robust and inexpensive. This form of effervescent spraying uses only pressurized water and air sprayed from small nozzles to obtain very fine distributions. While it is far from optimized, and may not be the best method if full deployment is ever desired, we believe that even in its present form the process would lend itself well to preliminary field test investigations of MCB. Measurements obtained using standard aerosol instrumentation show approximately lognormal distributions of salt nuclei with median diameters of approximately 65 nm and geometric standard deviations slightly less than 2. However, these measurements are not in agreement with those based on scanning electron microscopy imaging of collected particles, an observation that has not yet been explained. Assuming the above distribution, 10(15) particles per second could be made with 21 kW of spray power, using approximately 200 nozzles. It is envisioned that existing snow making equipment can be adapted to launch the nuclei 60-100 m into the air, requiring approximately 20 kW of additional power. PMID:25404673

  14. Preliminary results for salt aerosol production intended for marine cloud brightening, using effervescent spray atomization

    PubMed Central

    Cooper, Gary; Foster, Jack; Galbraith, Lee; Jain, Sudhanshu; Neukermans, Armand; Ormond, Bob

    2014-01-01

    The large-scale production of vast numbers of suitable salt nuclei and their upward launch is one of the main technological barriers to the experimental testing of marine cloud brightening (MCB). Very promising, though not definitive, results have been obtained using an adapted version of effervescent spray atomization. The process is simple, robust and inexpensive. This form of effervescent spraying uses only pressurized water and air sprayed from small nozzles to obtain very fine distributions. While it is far from optimized, and may not be the best method if full deployment is ever desired, we believe that even in its present form the process would lend itself well to preliminary field test investigations of MCB. Measurements obtained using standard aerosol instrumentation show approximately lognormal distributions of salt nuclei with median diameters of approximately 65 nm and geometric standard deviations slightly less than 2. However, these measurements are not in agreement with those based on scanning electron microscopy imaging of collected particles, an observation that has not yet been explained. Assuming the above distribution, 1015 particles per second could be made with 21 kW of spray power, using approximately 200 nozzles. It is envisioned that existing snow making equipment can be adapted to launch the nuclei 60–100 m into the air, requiring approximately 20 kW of additional power. PMID:25404673

  15. Global dust sources detection using MODIS Deep Blue Collection 6 aerosol products

    NASA Astrophysics Data System (ADS)

    Pérez García-Pando, C.; Ginoux, P. A.

    2015-12-01

    Our understanding of the global dust cycle is limited by a dearth of information about dust sources, especially small-scale features which could account for a large fraction of global emissions. Remote sensing sensors are the most useful tool to locate dust sources. These sensors include microwaves, visible channels, and lidar. On the global scale, major dust source regions have been identified using polar orbiting satellite instruments. The MODIS Deep Blue algorithm has been particularly useful to detect small-scale sources such as floodplains, alluvial fans, rivers, and wadis , as well as to identify anthropogenic sources from agriculture. The recent release of Collection 6 MODIS aerosol products allows to extend dust source detection to the entire land surfaces, which is quite useful to identify mid to high latitude dust sources and detect not only dust from agriculture but fugitive dust from transport and industrial activities. This presentation will overview the advantages and drawbacks of using MODIS Deep Blue for dust detection, compare to other instruments (polar orbiting and geostationary). The results of Collection 6 with a new dust screening will be compared against AERONET. Applications to long range transport of anthropogenic dust will be presented.

  16. Aerosol and product yields from NO{sub 3} radical-initiated oxidation o/f selected monoterpenes

    SciTech Connect

    Hallquist, M.; Ljungstroem, E.; Waengberg, I.; Barnes, I.; Becker, K.H.

    1999-02-15

    Atmospheric transformation of monoterpenes gives products that may cause environmental consequences. In this work the NO{sub 3} radical-initiated oxidation of the monoterpenes {alpha}-pinene, {beta}-pinene, {Delta}{sup 3}-carene, and limonene has been investigated. All experiments were conducted in EUPHORE, the EUropean PHOto REactor facility in Valencia, Spain. The aerosol and product yields were measured in experiments with a conversion of the terpenes in the interval from 7 to 400 ppb. The lower end of the concentrations used are close to those measured in ambient pine forest air. Products were measured using long path in situ FTIR. Aerosol yields were obtained using a DMA-CPC system. The aerosol mass yields measured at low concentrations were <1, 10, 15, and 17% for {alpha}-pinene, {beta}-pinene, {Delta}{sup 3}-carene, and limonene, respectively. The total molar alkylnitrate yields were calculated to be 19, 61, 66, and 48%, and molar carbonyl compound yields were estimated to be 71, 14, 29, and 69% for {alpha}-pinene, {beta}-pinene, {Delta}{sup 3}-carene, and limonene, respectively. The aerosol yields were strongly dependent on the amounts of terpene reacted, whereas the nitrate and carbonyl yields do not depend on the amount of terpene converted. The principal carbonyl compound from {alpha}pinene oxidation was pinonaldehyde. In the case of limonene, endolim was tentatively identified and appears to be a major product. The reactions with {beta}-pinene and {Delta}{sup 3}-carene yielded 1--2% of nopinone and 2--3% caronaldehyde, respectively. The results show that it is not possible to use generalized descriptions of terpene chemistry, e.g., in mathematical models.

  17. The generation of aerosols by accidents which may occur during plant-scale production of micro-organisms.

    PubMed Central

    Ashcroft, J.; Pomeroy, N. P.

    1983-01-01

    Experiments have been performed to simulate accidents which may occur during large-scale production of micro-organisms. Four types of accident, which were considered to be the most likely to result in the greatest hazard to health, were simulated using a bacterial model. The accidents were all concerned with faults occurring in the operation of the microbial fermenter. Gross contamination of surfaces occurred in all experiments, but only three types of accident produced a measurable aerosol. PMID:6350448

  18. Chemical composition of individual aerosol particles in workplace air during production of manganese alloys.

    PubMed

    Gunst, S; Weinbruch, S; Wentzel, M; Ortner, H M; Skogstad, A; Hetland, S; Thomassen, Y

    2000-02-01

    Aerosol particle samples were collected at ELKEM ASA ferromanganese (FeMn) and silicomanganese (SiMn) smelters at Porsgrunn, Norway, during different production steps: raw material mixing, welding of protective steel casings, tapping of FeMn and slag, crane operation moving the ladles with molten metal, operation of the Metal Oxygen Refinement (MOR) reactor and casting of SiMn. Aerosol fractions were assessed for the analysis of the bulk elemental composition as well as for individual particle analysis. The bulk elemental composition was determined by inductively coupled plasma atomic emission spectrometry. For individual particle analysis, an electron microprobe was used in combination with wavelength-dispersive techniques. Most particles show a complex composition and cannot be attributed to a single phase. Therefore, the particles were divided into six groups according to their chemical composition: Group I, particles containing mainly metallic Fe and/or Mn; Group II, slag particles containing mainly Fe and/or Mn oxides; Group III, slag particles consisting predominantly of oxidized flux components such as Si, Al, Mg, Ca, Na and K; Group IV, particles consisting mainly of carbon; Group V, mixtures of particles from Groups II, III and IV; Group VI, mixtures of particles from Groups II and III. In raw material mixing, particles originating from the Mn ores were mostly found. In the welding of steel casings, most particles were assigned to Group II, Mn and Fe oxides. During the tapping of slag and metal, mostly slag particles from Group III were found (oxides of the flux components). During movement of the ladles, most particles came from Group II. At the MOR reactor, most of the particles belonged to the slag phase consisting of the flux components (Group III). The particles collected during the casting of SiMn were mainly attributed to the slag phase (Groups III and V). Due to the compositional complexity of the particles, toxicological investigations on the

  19. Global stratospheric aerosol distribution as measured by the OMPS/LP

    NASA Astrophysics Data System (ADS)

    Gorkavyi, N.; Rault, D. F.

    2012-12-01

    The Ozone Mapping and Profiler Suite (OMPS) was launched on board NPP/SUOMI in October 2011 to continue monitoring the global distribution of the Earth's middle atmosphere ozone and aerosol. The present paper will be concerned with the stratospheric aerosol product retrieved with the OMPS Limb Profiler (heritage: SOLSE/LORE, OSIRIS, SCIAMACHY, SAGE III). The retrieval algorithm will be described together with early results. The retrieved products will be compared with data of CALIPSO and OSIRIS. The vertical profile of aerosol extinction is retrieved over a range of wavelengths (typically 500-900nm), from which a moment of the size distribution (namely the Angstrom coefficient) is inferred. Results will be shown in the form of (a) curtain profiles of aerosol extinction over an altitude range covering the UTLS region ~ 10-35km (sampling rate of one measurement per km in vertical direction and one measurement per one degree latitude), (b) curtain profiles of Angstrom coefficients, (c) weekly global maps of vertical optical depth (the OMPS/LP revisit time is about 5 days). The global distribution of aerosols retrieved by the OMPS/LP in 2012 shows the presence of stable or slowly time-varying structures of stratospheric aerosol, with four distinct geographical features: - the Northern latitudes exhibit large aerosol loading distributed in 4 layers: large particles near tropopause, smaller particles around 15km, larger particles near 18km and a reservoir of small particles above 20km - the middle latitudes (~30 degrees N,S) are characterized by low aerosol loading - the equatorial region shows large aerosol loading with large particles near the tropopause - the southern region (< -30 degrees) exhibits low aerosol loading and small particles Particle size information inferred from retrieved values of the Angstrom coefficient could provide valuable information on aerosol dynamics. Early results show larger stratospheric particles over land masses than over the oceans

  20. Study of a CCP RF Dusty Plasma for the Production of Titan's Aerosols Analogues

    SciTech Connect

    Alcouffe, G.; Cernogora, G.; Ouni, F.; Correia, J. J.; Cavarroc, M.; Boufendi, L.; Szopa, C.

    2008-09-07

    The CCP-RF discharge PAMPRE experiment produces analogues of Titan's aerosols. Here are presented the plasma characteristics as a function of gas mixtures and dust formation. Electronic density, optical emission spectroscopy, and self-bias voltage measurements are presented.

  1. Operational Retrieval of aerosol optical depth over Indian subcontinent and Indian Ocean using INSAT-3D/Imager product validation

    NASA Astrophysics Data System (ADS)

    Mishra, M. K.; Rastogi, G.; Chauhan, P.

    2014-11-01

    Aerosol optical depth (AOD) over Indian subcontinent and Indian Ocean region is derived operationally for the first time from the geostationary earth orbit (GEO) satellite INSAT-3D Imager data at 0.65 μm wavelength. Single visible channel algorithm based on clear sky composites gives larger retrieval error in AOD than other multiple channel algorithms due to errors in estimating surface reflectance and atmospheric property. However, since MIR channel signal is insensitive to the presence of most aerosols, therefore in present study, AOD retrieval algorithm employs both visible (centred at 0.65 μm) and mid-infrared (MIR) band (centred at 3.9 μm) measurements, and allows us to monitor transport of aerosols at higher temporal resolution. Comparisons made between INSAT-3D derived AOD (τI) and MODIS derived AOD (τM) co-located in space (at 1° resolution) and time during January, February and March (JFM) 2014 encompasses 1165, 1052 and 900 pixels, respectively. Good agreement found between τI and τM during JFM 2014 with linear correlation coefficients (R) of 0.87, 0.81 and 0.76, respectively. The extensive validation made during JFM 2014 encompasses 215 co-located AOD in space and time derived by INSAT 3D (τI) and 10 sun-photometers (τA) that includes 9 AERONET (Aerosol Robotic Network) and 1 handheld sun-photometer site. INSAT-3D derived AOD i.e. τI, is found within the retrieval errors of τI = ±0.07 ±0.15τA with linear correlation coefficient (R) of 0.90 and root mean square error equal (RMSE) to 0.06. Present work shows that INSAT-3D aerosol products can be used quantitatively in many applications with caution for possible residual clouds, snow/ice, and water contamination.

  2. Integrated Cloud-Aerosol-Radiation Product using CERES, MODIS, CALIPSO and CloudSat Data

    NASA Technical Reports Server (NTRS)

    Sun-Mack, Sunny; Minnis, Patrick; Chen, Yan; Gibson, Sharon; Yi, Yuhong; Trepte, Qing; Wielicki, Bruce; Kato, Seiji; Winker, Dave

    2007-01-01

    This paper documents the development of the first integrated data set of global vertical profiles of clouds, aerosols, and radiation using the combined NASA A-Train data from the Aqua Clouds and Earth's Radiant Energy System (CERES) and Moderate Resolution Imaging Spectroradiometer (MODIS), Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO), and CloudSat. As part of this effort, cloud data from the CALIPSO lidar and the CloudSat radar are merged with the integrated column cloud properties from the CERES-MODIS analyses. The active and passive datasets are compared to determine commonalities and differences in order to facilitate the development of a 3- dimensional cloud and aerosol dataset that will then be integrated into the CERES broadband radiance footprint. Preliminary results from the comparisons for April 2007 reveal that the CERES-MODIS global cloud amounts are, on average, 0.14 less and 0.15 greater than those from CALIPSO and CloudSat, respectively. These new data will provide unprecedented ability to test and improve global cloud and aerosol models, to investigate aerosol direct and indirect radiative forcing, and to validate the accuracy of global aerosol, cloud, and radiation data sets especially in polar regions and for multi-layered cloud conditions.

  3. Secondary extinctions of biodiversity.

    PubMed

    Brodie, Jedediah F; Aslan, Clare E; Rogers, Haldre S; Redford, Kent H; Maron, John L; Bronstein, Judith L; Groves, Craig R

    2014-12-01

    Extinctions beget further extinctions when species lose obligate mutualists, predators, prey, or hosts. Here, we develop a conceptual model of species and community attributes affecting secondary extinction likelihood, incorporating mechanisms that buffer organisms against partner loss. Specialized interactors, including 'cryptic specialists' with diverse but nonredundant partner assemblages, incur elevated risk. Risk is also higher for species that cannot either evolve new traits following partner loss or obtain novel partners in communities reorganizing under changing environmental conditions. Partner loss occurs alongside other anthropogenic impacts; multiple stressors can circumvent ecological buffers, enhancing secondary extinction risk. Stressors can also offset each other, reducing secondary extinction risk, a hitherto unappreciated phenomenon. This synthesis suggests improved conservation planning tactics and critical directions for research on secondary extinctions. PMID:25445878

  4. Inference of stratospheric aerosol composition and size distribution from SAGE II satellite measurements

    NASA Technical Reports Server (NTRS)

    Wang, Pi-Huan; Mccormick, M. P.; Fuller, W. H.; Yue, G. K.; Swissler, T. J.; Osborn, M. T.

    1989-01-01

    A method for inferring stratospheric aerosol composition and size distribution from the water vapor concentration and aerosol extinction measurements obtained in the Stratospheric Aerosol and Gas Experiment (SAGE) II and the associated temperature from the NMC. The aerosols are assumed to be sulfuric acid-water droplets. A modified Levenberg-Marquardt algorithm is used to determine model size distribution parameters based on the SAGE II multiwavelength aerosol extinctions. It is found that the best aerosol size information is contained in the aerosol radius range between about 0.25 and 0.80 micron.

  5. Scanning tropospheric ozone and aerosol lidar with double-gated photomultipliers.

    PubMed

    Machol, Janet L; Marchbanks, Richard D; Senff, Christoph J; McCarty, Brandi J; Eberhard, Wynn L; Brewer, William A; Richter, Ronald A; Alvarez, Raul J; Law, Daniel C; Weickmann, Ann M; Sandberg, Scott P

    2009-01-20

    The Ozone Profiling Atmospheric Lidar is a scanning four-wavelength ultraviolet differential absorption lidar that measures tropospheric ozone and aerosols. Derived profiles from the lidar data include ozone concentration, aerosol extinction, and calibrated aerosol backscatter. Aerosol calibrations assume a clear air region aloft. Other products include cloud base heights, aerosol layer heights, and scans of particulate plumes from aircraft. The aerosol data range from 280 m to 12 km with 5 m range resolution, while the ozone data ranges from 280 m to about 1.2 km with 100 m resolution. In horizontally homogeneous atmospheres, data from multiple-elevation angles is combined to reduce the minimum altitude of the aerosol and ozone profiles to about 20 m. The lidar design, the characterization of the photomultiplier tubes, ozone and aerosol analysis techniques, and sample data are described. Also discussed is a double-gating technique to shorten the gated turn-on time of the photomultiplier tubes, and thereby reduce the detection of background light and the outgoing laser pulse. PMID:19151820

  6. Near Real Time Vertical Profiles of Clouds and Aerosols from the Cloud-Aerosol Transport System (CATS) on the International Space Station

    NASA Astrophysics Data System (ADS)

    Yorks, J. E.; McGill, M. J.; Nowottnick, E. P.

    2015-12-01

    Plumes from hazardous events, such as ash from volcanic eruptions and smoke from wildfires, can have a profound impact on the climate system, human health and the economy. Global aerosol transport models are very useful for tracking hazardous plumes and predicting the transport of these plumes. However aerosol vertical distributions and optical properties are a major weakness of global aerosol transport models, yet a key component of tracking and forecasting smoke and ash. The Cloud-Aerosol Transport System (CATS) is an elastic backscatter lidar designed to provide vertical profiles of clouds and aerosols while also demonstrating new in-space technologies for future Earth Science missions. CATS has been operating on the Japanese Experiment Module - Exposed Facility (JEM-EF) of the International Space Station (ISS) since early February 2015. The ISS orbit provides more comprehensive coverage of the tropics and mid-latitudes than sun-synchronous orbiting sensors, with nearly a three-day repeat cycle. The ISS orbit also provides CATS with excellent coverage over the primary aerosol transport tracks, mid-latitude storm tracks, and tropical convection. Data from CATS is used to derive properties of clouds and aerosols including: layer height, layer thickness, backscatter, optical depth, extinction, and depolarization-based discrimination of particle type. The measurements of atmospheric clouds and aerosols provided by the CATS payload have demonstrated several science benefits. CATS provides near-real-time observations of cloud and aerosol vertical distributions that can be used as inputs to global models. The infrastructure of the ISS allows CATS data to be captured, transmitted, and received at the CATS ground station within several minutes of data collection. The CATS backscatter and vertical feature mask are part of a customized near real time (NRT) product that the CATS processing team produces within 6 hours of collection. The continuous near real time CATS data

  7. Gradual extinction reduces reinstatement

    PubMed Central

    Shiban, Youssef; Wittmann, Jasmin; Weißinger, Mara; Mühlberger, Andreas

    2015-01-01

    The current study investigated whether gradually reducing the frequency of aversive stimuli during extinction can prevent the return of fear. Thirty-one participants of a three-stage procedure (acquisition, extinction and a reinstatement test on day 2) were randomly assigned to a standard extinction (SE) and gradual extinction (GE) procedure. The two groups differed only in the extinction procedure. While the SE group ran through a regular extinction process without any negative events, the frequency of the aversive stimuli during the extinction phase was gradually reduced for the GE group. The unconditioned stimulus (US) was an air blast (5 bar, 10 ms). A spider and a scorpion were used as conditioned stimuli (CS). The outcome variables were contingency ratings and physiological measures (skin conductance response, SCR and startle response). There were no differences found between the two groups for the acquisition and extinction phases concerning contingency ratings, SCR, or startle response. GE compared to SE significantly reduced the return of fear in the reinstatement test for the startle response but not for SCR or contingency ratings. This study was successful in translating the findings in rodent to humans. The results suggest that the GE process is suitable for increasing the efficacy of fear extinction. PMID:26441581

  8. Mass extinction: a commentary

    NASA Technical Reports Server (NTRS)

    Raup, D. M.

    1987-01-01

    Four neocatastrophist claims about mass extinction are currently being debated; they are that: 1, the late Cretaceous mass extinction was caused by large body impact; 2, as many as five other major extinctions were caused by impact; 3, the timing of extinction events since the Permian is uniformly periodic; and 4, the ages of impact craters on Earth are also periodic and in phase with the extinctions. Although strongly interconnected the four claims are independent in the sense that none depends on the others. Evidence for a link between impact and extinction is strong but still needs more confirmation through bed-by-bed and laboratory studies. An important area for future research is the question of whether extinction is a continuous process, with the rate increasing at times of mass extinctions, or whether it is episodic at all scales. If the latter is shown to be generally true, then species are at risk of extinction only rarely during their existence and catastrophism, in the sense of isolated events of extreme stress, is indicated. This is line of reasoning can only be considered an hypothesis for testing. In a larger context, paleontologists may benefit from a research strategy that looks to known Solar System and Galactic phenomena for predictions about environmental effects on earth. The recent success in the recognition of Milankovitch Cycles in the late Pleistocene record is an example of the potential of this research area.

  9. Impact of Stronger Production and Loss Rates of Secondary Organic Aerosols on their Global Distribution and Budget

    NASA Astrophysics Data System (ADS)

    Hodzic, A.; Kasibhatla, P. S.; Cappa, C. D.; Madronich, S.; Jo, D. S.; Park, R.; Jimenez, J. L.

    2015-12-01

    Organic aerosols are observed to be the major constituents of submicron particles worldwide, and yet their atmospheric lifecycle including formation, ageing, and removal processes is poorly understood. Recent laboratory and ambient measurements suggest that both production yields and removal rates of chemically produced secondary organic aerosols (SOA) are much stronger and more diverse than currently assumed in chemistry-climate models (which typically consider wet deposition as the major loss process). In this study, we re-assess the global SOA distribution and budget with newly proposed SOA production and loss processes derived from these recent measurements, as well as from theoretical calculations. We evaluate and discuss the relative importance of removal pathways for organic vapors and particles (e.g. dry and wet deposition, photo-dissociation, evaporation, and heterogeneous surface reactions), and their effect on the SOA vertical distribution and budget using the GEOS-Chem global chemistry-transport model. We compare simulated SOA from various model configurations against ground, aircraft and satellite measurements to assess the extent to which these new developments in our understanding of SOA formation and removal processes are consistent with observed characteristics of the SOA distribution. Our results show strong changes in predicted vertical profiles of organic aerosols with higher SOA concentrations in the boundary layer and lower concentrations in the upper troposphere, which appear to be in a better agreement with aircraft measurements.

  10. AMS+ALS: Kinetic and Product Studies of the Heterogeneous Oxidation of Organic Aerosol at the Advanced Light Source

    NASA Astrophysics Data System (ADS)

    Kroll, J. H.; Wilson, K. R.; Kessler, S. H.; Browne, E. C.; Nah, T.; Smith, J.; Worsnop, D. R.

    2014-12-01

    The atmospheric oxidation of condensed-phase organic species can have a major influence on the composition, properties, and impacts of organic aerosol (OA); however the rates and products of such "aging" reactions are poorly constrained. Here we describe a series of laboratory experiments aimed at better understanding one class of aging reactions, the heterogeneous oxidation of OA by gas-phase oxidants. Central to these experiments is the availability of vacuum ultraviolet (VUV) light at the Chemical Dynamics Beamline of the Advanced Light Source at LBNL, which enables the implementation of VUV photoionization aerosol mass spectrometry. This technique allows for the real-time, speciated measurement of OA composition, yielding molecular information that is highly complementary to ensemble data from electron-impact ionization. OA composition is measured with both ionization schemes as a function of oxidant exposure within a flow reactor, providing detailed information on the kinetics and products of heterogeneous oxidation over multiple generations of oxidation. Specific topics investigated include the branching between functionalization and fragmentation of OA components, the formation of secondary organic aerosol from photolytically-generated radical species, and the heterogeneous aging of soot-associated organic species.

  11. Radiative Effects of Aerosols

    NASA Technical Reports Server (NTRS)

    Valero, Francisco P. J.

    1996-01-01

    During the Atlantic Stratocumulus Transition Experiment (ASTEX) in June 1992, two descents in cloud-free regions allowed comparison of the change in aerosol optical depth as determined by an onboard total-direct-diffuse radiometer (TDDR) to the change calculated from measured size-resolved aerosol microphysics and chemistry. Both profiles included a pollution haze from Europe but the second also included the effect of a Saharan dust layer above the haze. The separate contributions of supermicrometer (coarse) and submicrometer (fine) aerosol were determined and thermal analysis of the pollution haze indicated that the fine aerosol was composed primarily of a sulfate/water mixture with a refractory soot-like core. The soot core increased the calculated extinction by about 10% in the most polluted drier layer relative to a pure sulfate aerosol but had significantly less effect at higher humidities. A 3 km descent through a boundary layer air mass dominated by pollutant aerosol with relative humidities (RH) 10-77% yielded a close agreement between the measured and calculated aerosol optical depths (550 nm) of 0.160 (+/- 0.07) and 0. 157 (+/- 0.034) respectively. During descent the aerosol mass scattering coefficient per unit sulfate mass varied from about 5 to 16 m(exp 2)/g and primarily dependent upon ambient RH. However, the total scattering coefficient per total fine mass was far less variable at about 4+/- 0.7 m(exp 2)/g. A subsequent descent through a Saharan dust layer located above the pollution aerosol layer revealed that both layers contributed similarly to aerosol optical depth. The scattering per unit mass of the coarse aged dust was estimated at 1.1 +/- 0.2 m(exp 2)/g. The large difference (50%) in measured and calculated optical depth for the dust layer exceeded measurements.

  12. Global distribution of stratospheric aerosols by satellite measurements

    NASA Astrophysics Data System (ADS)

    McCormick, M. P.

    1982-01-01

    A description is given of the first-ever global stratospheric aerosol climatology which is being developed by the earth-orbiting SAM II and SAGE satellite-based sensors. These sensors use the technique of solar occulation; that is, for every spacecraft sunrise and sunset, the modulation of solar intensity caused by the intervening earth-limb is measured. These data are mathematically inverted to yield vertical profiles of aerosol extinction coefficients with 1 km resolution. The data show seasonal variations which are similar in each hemisphere, with strong correlation between aerosol extinction and the corresponding temperature field. Typical values of extinction in the stratosphere are found to be about 0.0001 to 0.0002 per km at 1 micrometer; stratospheric optical depths at this wavelength are about 0.002. The peak extinction in the stratospheric aerosol layer follows the tropopause with altitude, with peak extinction ratios about 10 km above the local tropopause.

  13. Comparison of ground based indices (API and AQI) with satellite based aerosol products.

    PubMed

    Zheng, Sheng; Cao, Chun-Xiang; Singh, Ramesh P

    2014-08-01

    Air quality in mega cities is one of the major concerns due to serious health issues and its indirect impact to the climate. Among mega cities, Beijing city is considered as one of the densely populated cities with extremely poor air quality. The meteorological parameters (wind, surface temperature, air temperature and relative humidity) control the dynamics and dispersion of air pollution. China National Environmental Monitoring Centre (CNEMC) started air pollution index (API) as of 2000 to evaluate air quality, but over the years, it was felt that the air quality is not well represented by API. Recently, the Ministry of Environmental Protection (MEP) of the People's Republic of China (PRC) started using a new index "air quality index (AQI)" from January 2013. We have compared API and AQI with three different MODIS (MODIS - Moderate Resolution Imaging SpectroRadiometer, onboard the Terra/Aqua satellites) AOD (aerosol optical depth) products for ten months, January-October, 2013. The correlation between AQI and Aqua Deep Blue AOD was found to be reasonably good as compared with API, mainly due to inclusion of PM2.5 in the calculation of AQI. In addition, for every month, the correlation coefficient between AQI and Aqua Deep Blue AOD was found to be relatively higher in the month of February to May. According to the monthly average distribution of precipitation, temperature, and PM10, the air quality in the months of June-September was better as compared to those in the months of February-May. AQI and Aqua Deep Blue AOD show highly polluted days associated with dust event, representing true air quality of Beijing. PMID:24412562

  14. Validation of radiolabeling of drug formulations for aerosol deposition assessment of orally inhaled products.

    PubMed

    Devadason, Sunalene G; Chan, Hak-Kim; Haeussermann, Sabine; Kietzig, Claudius; Kuehl, Philip J; Newman, Stephen; Sommerer, Knut; Taylor, Glyn

    2012-12-01

    Radiolabeling of inhaler formulations for imaging studies is an indirect method of determining lung deposition and regional distribution of drug in human subjects. Hence, ensuring that the radiotracer and drug exhibit similar aerodynamic characteristics when aerosolized, and that addition of the radiotracer has not significantly altered the characteristics of the formulation, are critical steps in the development of a radiolabeling method. The validation phase should occur during development of the radiolabeling method, prior to commencement of in vivo studies. The validation process involves characterization of the aerodynamic particle size distribution (APSD) of drug in the reference formulation, and of both drug and radiotracer in the radiolabeled formulation, using multistage cascade impaction. We propose the adoption of acceptance criteria similar to those recommended by the EMA and ISAM/IPAC-RS for determination of therapeutic equivalence of orally inhaled products: (a) if only total lung deposition is being quantified, the fine particle fraction ratio of both radiolabeled drug and radiotracer to that of the reference drug should fall between 0.85 and 1.18, and (b) if regional lung deposition (e.g., outer and inner lung regions) is to be quantified, the ratio of both radiolabeled drug and radiotracer to reference drug on each impactor stage or group of stages should fall between 0.85 and 1.18. If impactor stages are grouped together, at least four separate groups should be provided. In addition, while conducting in vivo studies, measurement of the APSD of the inhaler used on each study day is recommended to check its suitability for use in man. PMID:23215848

  15. Airborne Aerosol Closure Studies During PRIDE

    NASA Technical Reports Server (NTRS)

    Redemann, Jens; Livingston, John M.; Russell, Philip B.; Schmid, Beat; Reid, Jeff

    2000-01-01

    The Puerto Rico Dust Experiment (PRIDE) was conducted during June/July of 2000 to study the properties of Saharan dust aerosols transported across the Atlantic Ocean to the Caribbean Islands. During PRIDE, the NASA Ames Research Center six-channel (380 - 1020 nm) airborne autotracking sunphotometer (AATS-6) was operated aboard a Piper Navajo airplane alongside a suite of in situ aerosol instruments. The in situ aerosol instrumentation relevant to this paper included a Forward Scattering Spectrometer Probe (FSSP-100) and a Passive Cavity Aerosol Spectrometer Probe (PCASP), covering the radius range of approx. 0.05 to 10 microns. The simultaneous and collocated measurement of multi-spectral aerosol optical depth and in situ particle size distribution data permits a variety of closure studies. For example, vertical profiles of aerosol optical depth obtained during local aircraft ascents and descents can be differentiated with respect to altitude and compared to extinction profiles calculated using the in situ particle size distribution data (and reasonable estimates of the aerosol index of refraction). Additionally, aerosol extinction (optical depth) spectra can be inverted to retrieve estimates of the particle size distributions, which can be compared directly to the in situ size distributions. In this paper we will report on such closure studies using data from a select number of vertical profiles at Cabras Island, Puerto Rico, including measurements in distinct Saharan Dust Layers. Preliminary results show good agreement to within 30% between mid-visible aerosol extinction derived from the AATS-6 optical depth profiles and extinction profiles forward calculated using 60s-average in situ particle size distributions and standard Saharan dust aerosol refractive indices published in the literature. In agreement with tendencies observed in previous studies, our initial results show an underestimate of aerosol extinction calculated based on the in situ size distributions

  16. Chemical characterization of the main secondary organic aerosol (SOA) products formed through aqueous-phase photonitration of guaiacol

    NASA Astrophysics Data System (ADS)

    Kitanovski, Z.; Čusak, A.; Grgić, I.; Claeys, M.

    2014-04-01

    Guaiacol (2-methoxyphenol) and its derivatives can be emitted into the atmosphere by thermal degradation (i.e. burning) of wood lignins. Due to its volatility, guaiacol is predominantly distributed in the atmospheric gaseous phase. Recent studies have shown the importance of aqueous-phase reactions in addition to the dominant gas-phase and heterogeneous reactions of guaiacol, in the formation of secondary organic aerosol (SOA) in the atmosphere. The main objectives of the present study were to chemically characterize the low-volatility SOA products of the aqueous-phase photonitration of guaiacol and examine their possible presence in urban atmospheric aerosols. The aqueous-phase reactions were carried out under simulated sunlight and in the presence of H2O2 and nitrite. The formed guaiacol reaction products were concentrated by using solid-phase extraction (SPE) and then purified by means of semi-preparative high-performance liquid chromatography (HPLC). The fractionated individual compounds were isolated as pure solids and further analyzed with liquid-state 1H, 13C and 2D nuclear magnetic resonance (NMR) spectroscopy and direct infusion negative ion electrospray ionization tandem mass spectrometry ((-)ESI-MS/MS). The NMR and product ion (MS2) spectra were used for unambiguous product structure elucidation. The main products of guaiacol photonitration are 4-nitroguaiacol (4NG), 6-nitroguaiacol (6NG), and 4,6-dinitroguaiacol (4,6DNG). Using the isolated compounds as standards, 4NG and 4,6DNG were unambiguously identified in winter PM10 aerosols from the city of Ljubljana (Slovenia) by means of HPLC/(-)ESI-MS/MS. Owing to the strong absorption of UV and visible light, 4,6DNG could be an important constituent of atmospheric "brown" carbon, especially in regions affected by biomass burning.

  17. Hyperspectral Aerosol Optical Depths from TCAP Flights

    SciTech Connect

    Shinozuka, Yohei; Johnson, Roy R.; Flynn, Connor J.; Russell, P. B.; Schmid, Beat; Redemann, Jens; Dunagan, Stephen; Kluzek, Celine D.; Hubbe, John M.; Segal-Rosenheimer, Michal; Livingston, J. M.; Eck, T.; Wagener, Richard; Gregory, L.; Chand, Duli; Berg, Larry K.; Rogers, Ray; Ferrare, R. A.; Hair, John; Hostetler, Chris A.; Burton, S. P.

    2013-11-13

    4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research), the world’s first hyperspectral airborne tracking sunphotometer, acquired aerosol optical depths (AOD) at 1 Hz during all July 2012 flights of the Two Column Aerosol Project (TCAP). Root-mean square differences from AERONET ground-based observations were 0.01 at wavelengths between 500-1020 nm, 0.02 at 380 and 1640 nm and 0.03 at 440 nm in four clear-sky fly-over events, and similar in ground side-by-side comparisons. Changes in the above-aircraft AOD across 3-km-deep spirals were typically consistent with integrals of coincident in situ (on DOE Gulfstream 1 with 4STAR) and lidar (on NASA B200) extinction measurements within 0.01, 0.03, 0.01, 0.02, 0.02, 0.02 at 355, 450, 532, 550, 700, 1064 nm, respectively, despite atmospheric variations and combined measurement uncertainties. Finer vertical differentials of the 4STAR measurements matched the in situ ambient extinction profile within 14% for one homogeneous column. For the AOD observed between 350-1660 nm, excluding strong water vapor and oxygen absorption bands, estimated uncertainties were ~0.01 and dominated by (then) unpredictable throughput changes, up to +/-0.8%, of the fiber optic rotary joint. The favorable intercomparisons herald 4STAR’s spatially-resolved high-frequency hyperspectral products as a reliable tool for climate studies and satellite validation.

  18. A High-Spatial-Resolution, Localized MODIS Aerosol Optical Depth Product for Use in Air Quality Exposure Assessment During Large Wildfire Smoke Events

    NASA Astrophysics Data System (ADS)

    McCarthy, M. C.; Raffuse, S. M.; DeWinter, J. L.; Craig, K. J.; Jumbam, L. K.; Fruin, S.; Lurmann, F.

    2011-12-01

    Aerosol optical depth (AOD) has potential use for determining the intra-urban variability of airborne particulate matter exposure during wildfire events; however, the standard Moderate Resolution Imaging Spectroradiometer (MODIS) AOD products have limitations for this application. Specifically, the 10x10 km resolution is too coarse for intra-urban population exposure assessments, the assumed aerosol optical properties are not representative of biomass burning aerosol, and the cloud masking algorithm misinterprets heavy smoke as clouds. We developed a localized MODIS AOD product at 1.5 and 2.5 km resolutions and tested the performance in northern California during the 2008 wildfires. The localized product's algorithm uses local biomass burning aerosol optical properties, local surface reflectance data, and a relaxed cloud filter. During the 2008 season, persistent heavy smoke was produced over northern California and the San Joaquin Valley for over two months. As California is both highly populated and covered with a relatively dense network of ground-based aerosol monitoring stations, this event provided an excellent opportunity to develop the AOD product and test its ability to predict aerosol concentrations on the ground to assess population exposure. We will present our methodology and discuss its potential for air quality and public health applications.

  19. An aerosol absorption remote sensing algorithm

    NASA Astrophysics Data System (ADS)

    Zhai, P.; Winker, D. M.; Hu, Y.; Trepte, C. R.; Lucker, P. L.

    2013-12-01

    Aerosol absorption plays an important role in the climate by modulating atmospheric radiative forcing processes. Unfortunately aerosol absorption is very difficult to obtain via satellite remote sensing techniques. In this work we have built an algorithm to obtain aerosol absorption optical depth using both measurements from a passive O2 A-band spectrometer and an active lidar. The instrument protocols for these two satellite instruments are the O2 A-band spectrometer onboard the Orbiting Carbon Observatory (OCO-2) and the CALIOP onboard CALIPSO. The aerosol height and typing information is obtained from the CALIOP measurement. The aerosol extinction and absorption optical depths are then retrieved by fitting the forward model simulations to the O2 A-band spectrometer measurements. The forward model simulates the scattering and absorption of solar light at high spectral resolution in the O2 A-band region. The O2 and other gas absorption coefficients near 0.76 micron are calculated by either the line-by-line code (for instance, the Atmospheric Radiative Transfer Simulator) or the OCO2 ABSCO Look-Up-Table. The line parameters used are from the HITRAN 2008 database (http://www.cfa.harvard.edu/hitran/). The multiple light scattering by molecules, aerosols, and clouds is handled by the radiative transfer model based on the successive order of scattering method (Zhai et al, JQSRT, Vol. 111, pp. 1025-1040, 2010). The code is parallelized with Message Passing Interface (MPI) for better efficiency. The aerosol model is based on Shettle and Fenn (AFGL-TR 790214, 1979) with variant relative humidity. The vertical distribution of the aerosols and clouds will be read in from the CALIPSO product (http://www-calipso.larc.nasa.gov). The surface albedo is estimated by the continuum of the three bands of OCO2 payloads. Sensitivity study shows that the Gaussian quadrature (stream) number should be at least 12 to ensure the reflectance error is within 0.5% at the top of the atmosphere

  20. A Critical Examination of Spatial Biases Between MODIS and MISR Aerosol Products - Application for Potential AERONET Deployment

    NASA Technical Reports Server (NTRS)

    Shi, Y.; Zhang, J.; Reid, J. S.; Hyer, E. J.; Eck, T. F.; Holben, B. N.; Kahn, R. A.

    2011-01-01

    AErosol RObotic NETwork (AERONET) data are the primary benchmark for evaluating satellite-retrieved aerosol properties. However, despite its extensive coverage, the representativeness of the AERONET data is rarely discussed. Indeed, many studies have shown that satellite retrieval biases have a significant degree of spatial correlation that may be problematic for higher-level processes or inverse-emissions-modeling studies. To consider these issues and evaluate relative performance in regions of few surface observations, cross-comparisons between the Aerosol Optical Depth (AOD) products of operational MODIS Collection 5.1 Dark Target (DT) and operational MODIS Collection 5.1 Deep Blue (DB) with MISR version 22 were conducted. Through such comparisons, we can observe coherent spatial features of the AOD bias while side-stepping the full analysis required for determining when or where either retrieval is more correct. We identify regions where MODIS to MISR AOD ratios were found to be above 1.4 and below 0.7. Regions where lower boundary condition uncertainty is likely to be a dominant factor include portions of Western North America, the Andes mountains, Saharan Africa, the Arabian Peninsula, and Central Asia. Similarly, microphysical biases may be an issue in South America, and specific parts of Southern Africa, India Asia, East Asia, and Indonesia. These results help identify high-priority locations for possible future deployments of both in situ and ground based remote sensing measurements. The Supplement includes a km1 file.

  1. Environmental contaminants and productivity in an extinct heronry at Charleston Harbor, South Carolina, U.S.A., 1984

    USGS Publications Warehouse

    White, D.H.; Geitner, J.G.H.

    1996-01-01

    Our objectives were to collect information on contaminant levels and productivity of wading birds at the Drum Island heronry in Charleston Harbor, South Carolina, before diversion of the Cooper River took place in 1985. The diversion was expected to reduce water flow by ~80% into the Harbor, thereby concentrating industrial effluents near the heronry with potentially harmful effects. Hatching success of white ibises (Eudocimus albus) in 1984 averaged 66% and 1.0 chick per nest survived to three weeks post-hatch. Fresh eggs collected from a sample of nests contained only background levels of DDT, DDE, and dieldrin; no PCBs, diphenyl ethers, or styrenes were detected. Pesticide residues in eggs were not correlated (P >0.05) with productivity in corresponding nests. Heavy metals and selenium in tissues of wading bird chicks were also representative of background levels. Follow-up studies after the diversion of the Cooper River were not feasible because the heronry was abandoned beginning in 1985. However, our baseline results will be useful in determining potential contaminant effects due to diversion of the Cooper River should wading birds return to Drum Island in the future.

  2. SAGE and SAM II measurements of global stratospheric aerosol optical depth and mass loading

    NASA Technical Reports Server (NTRS)

    Kent, G. S.; Mccormick, M. P.

    1984-01-01

    Several volcanic eruptions between November 1979 and April 1981 have injected material into the stratosphere. The SAGE and SAM II satellite systems have measured, with global coverage, the 1-micron extinction produced by this material, and examples of the data product are shown in the form of global maps of stratospheric optical depth and altitude-latitude plots of zonal mean extinction. These data, and that for the volcanically quiet period in early 1979, have been used to determine the changes in the total stratospheric mass loading. Estimates have also been made of the contribution to the total aerosol mass from each eruption. It has been found that between 1979 and mid-1981, the total stratospheric aerosol mass increased from a background level of approximately 570,000 metric tons to a peak of approximately 1,300,000 metric tons.

  3. Global Long-Term SeaWiFS Deep Blue Aerosol Products available at NASA GES DISC

    NASA Technical Reports Server (NTRS)

    Shen, Suhung; Sayer, A. M.; Bettenhausen, Corey; Wei, Jennifer C.; Ostrenga, Dana M.; Vollmer, Bruce E.; Hsu, Nai-Yung; Kempler, Steven J.

    2012-01-01

    Long-term climate data records about aerosols are needed in order to improve understanding of air quality, radiative forcing, and for many other applications. The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) provides a global well-calibrated 13- year (1997-2010) record of top-of-atmosphere radiance, suitable for use in retrieval of atmospheric aerosol optical depth (AOD). Recently, global aerosol products derived from SeaWiFS with Deep Blue algorithm (SWDB) have become available for the entire mission, as part of the NASA Making Earth Science data records for Use in Research for Earth Science (MEaSUREs) program. The latest Deep Blue algorithm retrieves aerosol properties not only over bright desert surfaces, but also vegetated surfaces, oceans, and inland water bodies. Comparisons with AERONET observations have shown that the data are suitable for quantitative scientific use [1],[2]. The resolution of Level 2 pixels is 13.5x13.5 km2 at the center of the swath. Level 3 daily and monthly data are composed by using best quality level 2 pixels at resolution of both 0.5ox0.5o and 1.0ox1.0o. Focusing on the southwest Asia region, this presentation shows seasonal variations of AOD, and the result of comparisons of 5-years (2003- 2007) of AOD from SWDB (Version 3) and MODIS Aqua (Version 5.1) for Dark Target (MYD-DT) and Deep Blue (MYD-DB) algorithms.

  4. Emissions of biogenic volatile organic compounds and subsequent photochemical production of secondary organic aerosol in mesocosm studies of temperate and tropical plant species

    NASA Astrophysics Data System (ADS)

    Wyche, K. P.; Ryan, A. C.; Hewitt, C. N.; Alfarra, M. R.; McFiggans, G.; Carr, T.; Monks, P. S.; Smallbone, K. L.; Capes, G.; Hamilton, J. F.; Pugh, T. A. M.; MacKenzie, A. R.

    2014-12-01

    Silver birch (Betula pendula) and three Southeast Asian tropical plant species (Ficus cyathistipula, Ficus benjamina and Caryota millis) from the pantropical fig and palm genera were grown in a purpose-built and environment-controlled whole-tree chamber. The volatile organic compounds emitted from these trees were characterised and fed into a linked photochemical reaction chamber where they underwent photo-oxidation under a range of controlled conditions (relative humidity or RH ~65-89%, volatile organic compound-to-NOx or VOC / NOx ~3-9 and NOx ~2 ppbV). Both the gas phase and the aerosol phase of the reaction chamber were monitored in detail using a comprehensive suite of on-line and off-line chemical and physical measurement techniques. Silver birch was found to be a high monoterpene and sesquiterpene but low isoprene emitter, and its emissions were observed to produce measurable amounts of secondary organic aerosol (SOA) via both nucleation and condensation onto pre-existing seed aerosol (YSOA 26-39%). In contrast, all three tropical species were found to be high isoprene emitters with trace emissions of monoterpenes and sesquiterpenes. In tropical plant experiments without seed aerosol there was no measurable SOA nucleation, but aerosol mass was shown to increase when seed aerosol was present. Although principally isoprene emitting, the aerosol mass produced from tropical fig was mostly consistent (i.e. in 78 out of 120 aerosol mass calculations using plausible parameter sets of various precursor specific yields) with condensation of photo-oxidation products of the minor volatile organic compounds (VOCs) co-emitted; no significant aerosol yield from condensation of isoprene oxidation products was required in the interpretations of the experimental results. This finding is in line with previous reports of organic aerosol loadings consistent with production from minor biogenic VOCs co-emitted with isoprene in principally isoprene-emitting landscapes in Southeast

  5. Cirrus and aerosol lidar profilometer - analysis and results

    SciTech Connect

    Spinhirne, J.D.; Scott, V.S.; Reagan, J.A.; Galbraith, A.

    1996-04-01

    A cloud and aerosol lidar set from over a year of near continuous operation of a micro pulse lidar (MPL) instrument at the Cloud and Radiation Testbed (CART) site has been established. MPL instruments are to be included in the Ames Research Center (ARC) instrument compliments for the SW Pacific and Arctic ARM sites. Operational processing algorithms are in development for the data sets. The derived products are to be cloud presence and classification, base height, cirrus thickness, cirrus optical thickness, cirrus extinction profile, aerosol optical thickness and profile, and planetary boundary layer (PBL) height. A cloud presence and base height algorithm is in use, and a data set from the CART site is available. The scientific basis for the algorithm development of the higher level data products and plans for implementation are discussed.

  6. Extinction and the fossil record

    NASA Technical Reports Server (NTRS)

    Sepkoski, J. J. Jr; Sepkoski JJ, ,. J. r. (Principal Investigator)

    1994-01-01

    The author examines evidence of mass extinctions in the fossil record and searches for reasons for such large extinctions. Five major mass extinctions eliminated at least 40 percent of animal genera in the oceans and from 65 to 95 percent of ocean species. Questions include the occurrence of gradual or catastrophic extinctions, causes, environment, the capacity of a perturbation to cause extinctions each time it happens, and the possibility and identification of complex events leading to a mass extinction.

  7. APPLICATION OF POLLUTION PREVENTION TECHNIQUES TO REDUCE INDOOR AIR EMISSONS FROM AEROSOL CONSUMER PRODUCTS

    EPA Science Inventory

    The report gives results of a research project to develop tools and methodologies to measure aerosol chemical and particle dispersion through space. These tools can be used to devise pollution prevention strategies that could reduce occupant chemical exposures and guide manufactu...

  8. Probing aerosol formation by comprehensive measurements of gas phase oxidation products

    NASA Astrophysics Data System (ADS)

    Ehn, Mikael; Kleist, Einhard; Junninen, Heikki; Sipilä, Mikko; Petäjä, Tuukka; Pullinen, Iida; Springer, Monika; Andres, Stefanie; Rissanen, Matti; Kontkanen, Jenni; Schobesberger, Siegfried; Rubach, Florian; Tillman, Ralf; Lee, Ben H.; Lopez-Hilfiker, Felipe; Kerminen, Veli-Matti; Kulmala, Markku; Worsnop, Douglas R.; Thornton, Joel; Wildt, Jürgen; Mentel, Thomas F.

    2013-05-01

    A comprehensive suite of chemical ionization mass spectrometers (CIMS) were deployed for chamber studies of monoterpene oxidation. The CIMS instruments were able to detect several different groups of compounds ranging from volatile to practically non-volatile. The compound groups showed very different behavior and correlations with aerosol number and mass. Results suggest that major gas phase contributors are not considered in current models.

  9. Influence of aerosol estimation on coastal water products retrieved from HICO images

    NASA Astrophysics Data System (ADS)

    Patterson, Karen W.; Lamela, Gia

    2011-06-01

    The Hyperspectral Imager for the Coastal Ocean (HICO) is a hyperspectral sensor which was launched to the International Space Station in September 2009. The Naval Research Laboratory (NRL) has been developing the Coastal Water Signatures Toolkit (CWST) to estimate water depth, bottom type and water column constituents such as chlorophyll, suspended sediments and chromophoric dissolved organic matter from hyperspectral imagery. The CWST uses a look-up table approach, comparing remote sensing reflectance spectra observed in an image to a database of modeled spectra for pre-determined water column constituents, depth and bottom type. In order to successfully use this approach, the remote sensing reflectances must be accurate which implies accurately correcting for the atmospheric contribution to the HICO top of the atmosphere radiances. One tool the NRL is using to atmospherically correct HICO imagery is Correction of Coastal Ocean Atmospheres (COCOA), which is based on Tafkaa 6S. One of the user input parameters to COCOA is aerosol optical depth or aerosol visibility, which can vary rapidly over short distances in coastal waters. Changes to the aerosol thickness results in changes to the magnitude of the remote sensing reflectances. As such, the CWST retrievals for water constituents, depth and bottom type can be expected to vary in like fashion. This work is an illustration of the variability in CWST retrievals due to inaccurate aerosol thickness estimation during atmospheric correction of HICO images.

  10. Aerosol typing - key information from aerosol studies

    NASA Astrophysics Data System (ADS)

    Mona, Lucia; Kahn, Ralph; Papagiannopoulos, Nikolaos; Holzer-Popp, Thomas; Pappalardo, Gelsomina

    2016-04-01

    Aerosol typing is a key source of aerosol information from ground-based and satellite-borne instruments. Depending on the specific measurement technique, aerosol typing can be used as input for retrievals or represents an output for other applications. Typically aerosol retrievals require some a priori or external aerosol type information. The accuracy of the derived aerosol products strongly depends on the reliability of these assumptions. Different sensors can make use of different aerosol type inputs. A critical review and harmonization of these procedures could significantly reduce related uncertainties. On the other hand, satellite measurements in recent years are providing valuable information about the global distribution of aerosol types, showing for example the main source regions and typical transport paths. Climatological studies of aerosol load at global and regional scales often rely on inferred aerosol type. There is still a high degree of inhomogeneity among satellite aerosol typing schemes, which makes the use different sensor datasets in a consistent way difficult. Knowledge of the 4d aerosol type distribution at these scales is essential for understanding the impact of different aerosol sources on climate, precipitation and air quality. All this information is needed for planning upcoming aerosol emissions policies. The exchange of expertise and the communication among satellite and ground-based measurement communities is fundamental for improving long-term dataset consistency, and for reducing aerosol type distribution uncertainties. Aerosol typing has been recognized as one of its high-priority activities of the AEROSAT (International Satellite Aerosol Science Network, http://aero-sat.org/) initiative. In the AEROSAT framework, a first critical review of aerosol typing procedures has been carried out. The review underlines the high heterogeneity in many aspects: approach, nomenclature, assumed number of components and parameters used for the

  11. Mexico City Aerosol Transect

    NASA Astrophysics Data System (ADS)

    Lewandowski, P. A.; Eichinger, W. E.; Prueger, J.; Holder, H. L.

    2007-12-01

    A radiative impact study was conducted in Mexico City during MILAGRO/MIRAGE campaign in March of 2006. On a day when the predominant wind was from the north to the south, authors measured radiative properties of the atmosphere in six locations across the city ranging from the city center, through the city south limits and the pass leading out of the city (causing pollutants to funnel through the area). A large change in aerosol optical properties has been noticed. The aerosol optical depth has generally increased outside of the city and angstrom coefficient has changed significantly towards smaller values. Aerosol size distribution was calculated using SkyRadPack. The total optical depths allowed coincidental lidar data to calculate total extinction profiles for all the locations for 1064nm.

  12. Monitoring Airborne Dust from Source to Sink Using the e-Deep Blue Aerosol Products from VIIRS, MODIS, and Seawifs

    NASA Astrophysics Data System (ADS)

    Carletta, N.; Hsu, N. Y. C.; Bettenhausen, C.; Sayer, A. M.; Lee, J.

    2014-12-01

    Mineral dust sources are typically located in very bright, arid desert regions across the globe. In the past, aerosol retrieval algorithms were unable to properly handle these bright surfaces which lead to large, persistent data gaps. In order to eliminate these gaps, the Deep Blue algorithm was developed and first entered into the MODIS operational stream in Collection 5.1. Since then, the Deep Blue algorithm has evolved to retrieve not only over bright surfaces, but also vegetated surfaces. This updated algorithm has been named the enhanced Deep Blue (e-Deep Blue) algorithm and has been successfully applied to reflectances from the Sea-viewing, Wide Field-of-view Sensor (SeaWiFS, 1997-2010), Moderate Resolution Imaging Spectroradiometer (MODIS, 2000/2002-present), and now the Visible Infrared Imaging Radiometer Suite (VIIRS, 2012-present) aboard the Suomi-NPP platform. This algorithm has been partnered with a new over-ocean algorithm for our SeaWiFS and VIIRS datasets. Due to the broad swath of VIIRS, daily global coverage is achieved at higher spatial resolution compared to MODIS and SeaWiFS. Thus, the evolution of dust can be tracked from source to sink, across both land and ocean using these satellite products. We introduce the basics of the e-Deep Blue algorithm along with our preliminary VIIRS e-Deep Blue products, including aerosol optical thickness at 550nm and Ǻngström exponent. Validation with AErosol RObotic NETwork (AERONET) data are also presented along with the intercomparisons between VIIRS Deep Blue and other satellite products.

  13. The Geochemistry of Mass Extinction

    NASA Astrophysics Data System (ADS)

    Kump, L. R.

    2003-12-01

    rates) and ecosystem function (guild structure, complexity of interactions, productivity). Geochemical records reflect attributes of ecosystem function, not biodiversity; low-diversity recovery faunas and floras may support pre-event productivities. Thus, geochemical and biodiversity recovery intervals are interdependent but not equivalent, and may not be of equal duration.From the biological point of view, there is an inevitable lag between peak extinction rates and peak origination rates, and the durations and underlying causes of the lags are topics of debate. Both intrinsic (e.g., the fact that ecospace is created as biodiversity increases producing positive feedback) and external (environmental) constraints are possible. Kirchner and Weil (2000) performed a time-series analysis of extinction and origination-rate data, and concluded that the lag is ˜10 Myr and independent of the magnitude of the event. Erwin (2001) raised the possibility that the 10 Myr lag may be an artifact of the coarseness of the timescales utilized, and discussed possible environmental and ecological limits on rate of recovery from mass extinction.The comparison of the geochemical records of the five major mass extinctions of the Phanerozoic reveals few commonalities. Most, but not all, exhibit sharp drops in the carbon isotopic composition (δ13C) of the surface ocean, indicating substantial disruptions to the global carbon cycle. The P-Tr and F-F events are associated with indicators of widespread anoxia and enhanced pyrite burial (positive δ34S excursions), whereas the Late Ordovician extinction occurred during a brief interlude of oxic conditions from general anoxia. Some are associated with sea-level transgressions from previous lowstands (P-Tr, Tr-J, K-T), but the Late Ordovician and F-F occurred during sea-level falls. Long-term climates change across all events, but span major coolings (Late Ordovician, F-F) to prominent warmings (P-Tr, Tr-J, K-T).Evidence for extraterrestrial

  14. Satellite remote sensing of aerosol and cloud properties over Eurasia

    NASA Astrophysics Data System (ADS)

    Sogacheva, Larisa; Kolmonen, Pekka; Saponaro, Giulia; Virtanen, Timo; Rodriguez, Edith; Sundström, Anu-Maija; Atlaskina, Ksenia; de Leeuw, Gerrit

    2015-04-01

    Satellite remote sensing provides the spatial distribution of aerosol and cloud properties over a wide area. In our studies large data sets are used for statistical studies on aerosol and cloud interaction in an area over Fennoscandia, the Baltic Sea and adjacent regions over the European mainland. This area spans several regimes with different influences on aerosol cloud interaction such as a the transition from relative clean air over Fennoscandia to more anthropogenically polluted air further south, and the influence maritime air over the Baltic and oceanic air advected from the North Atlantic. Anthropogenic pollution occurs in several parts of the study area, and in particular near densely populated areas and megacities, but also in industrialized areas and areas with dense traffic. The aerosol in such areas is quite different from that produced over the boreal forest and has different effects on air quality and climate. Studies have been made on the effects of aerosols on air quality and on the radiation balance in China. The aim of the study is to study the effect of these different regimes on aerosol-cloud interaction using a large aerosol and cloud data set retrieved with the (Advanced) Along Track Scanning Radiometer (A)ATSR Dual View algorithm (ADV) further developed at Finnish Meteorological Institute and aerosol and cloud data provided by MODIS. Retrieval algorithms for aerosol and clouds have been developed for the (A)ATSR, consisting of a series of instruments of which we use the second and third one: ATSR-2 which flew on the ERS-2 satellite (1995-2003) and AATSR which flew on the ENVISAT satellite (2002-2012) (both from the European Space Agency, ESA). The ADV algorithm provides aerosol data on a global scale with a default resolution of 10x10km2 (L2) and an aggregate product on 1x1 degree (L3). Optional, a 1x1 km2 retrieval products is available over smaller areas for specific studies. Since for the retrieval of AOD no prior knowledge is needed on

  15. Using MAIAC Aerosol Products to Estimate PM10 Concentrations in the Southeastern U.S

    NASA Astrophysics Data System (ADS)

    Jinnagara Puttaswamy, S.; Hu, X.; Lyapustin, A.; Wang, Y.; Liu, Y.

    2012-12-01

    Acute and chronic exposure to particulate matter has been linked to various adverse health effects. High PM levels including inhalable particles (PM10) and fine particles (PM2.5) are commonly found in large urban centers in the developing world. Unlike PM2.5 whose routine ground monitoring is very sparse, PM10 is regularly measured in many large cities in developing countries. In this analysis, we evaluate the potential for satellite aerosol remote sensing product to estimate PM10 levels. We chose AOD values in 2003 retrieved by the Multiangle Implementation of Atmospheric Correction (MAIAC) algorithm based on MODIS measurements, which has a high spatial resolution of 1 km. Our study area is a 600 km x 600 km region centered in Atlanta, GA. Linear mixed effect (LME) models were developed with MAIAC AOD as the primary predictor variable, meteorology, PM10 emission locations and land use variables as secondary predictor variables. Daily PM10 concentrations measured at ~70 EPA air quality monitoring stations were used as the dependent variable. Model day of year was used as the grouping factor for the random effect of MAIAC AOD. We aggregated AOD and other covariates on 1 km, 3km, 5km and 10km resolution grids and similar LME models were developed for each spatial resolution to compare their abilities to cap