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Sample records for ag hirrlingen germany

  1. Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany

    USGS Publications Warehouse

    Pfaff, Katharina; Hildebrandt, Ludwig H.; Leach, David L.; Jacob, Dorrit E.; Markl, Gregor

    2010-01-01

    The Mississippi Valley-type (MVT) Zn-Pb-Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb-Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Reocin, Northern Spain; Treves, Southern France; and Cracow-Silesia, Poland), which show notable

  2. Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany

    NASA Astrophysics Data System (ADS)

    Pfaff, Katharina; Hildebrandt, Ludwig H.; Leach, David L.; Jacob, Dorrit E.; Markl, Gregor

    2010-10-01

    The Mississippi Valley-type (MVT) Zn-Pb-Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb-Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Réocin, Northern Spain; Trèves, Southern France; and Cracow-Silesia, Poland), which show notable

  3. [Regional aging in Germany].

    PubMed

    Bucher, H

    1996-01-01

    Elderly people in Germany have a specific regional distribution. Recent regional population projections show that these patterns will change. The most dynamic process of aging will take place in the suburban parts of the large western Germany agglomerations, whereas in eastern Germany aging concentrates in regions with a lower density. There will be a regional deconcentration of elderly people with consequences for the planning of infrastructure.

  4. Accuracy Assessment for AG500, Electromagnetic Articulograph

    ERIC Educational Resources Information Center

    Yunusova, Yana; Green, Jordan R.; Mefferd, Antje

    2009-01-01

    Purpose: The goal of this article was to evaluate the accuracy and reliability of the AG500 (Carstens Medizinelectronik, Lenglern, Germany), an electromagnetic device developed recently to register articulatory movements in three dimensions. This technology seems to have unprecedented capabilities to provide rich information about time-varying…

  5. Germany and NATO

    SciTech Connect

    Reed, J.A.

    1987-01-01

    This work includes the following topics: Road to NATO Germany in NATO, Germany and NATO Defense Policy, Evolution of NATO, German Security in NATO-Domestic Considerations, Toward the Future, The Brussels Treaty, The North Atlantic Treaty, The Future Tasks of Alliance (Harmel Report).

  6. AGS II

    SciTech Connect

    Palmer, R.B.

    1984-01-01

    Interest in rare K decays, neutrino oscillations and other fields have generated an increasing demand for running, and improved intensity and duty cycle, at the AGS. Current projects include acceleration of polarized protons and light ions (up to mass 32). Future plans are for a booster to increase intensity and allow heavy ions (up to mass 200), and a stretcher to give 100% duty cycle. A later upgrade could yield an average current of 32 ..mu.. amps. 6 figures, 2 tables.

  7. Global update: Germany.

    PubMed

    Lauter, Frank-Roman; Wirsching, Sandra

    2011-11-01

    Researchers are working on key issues in regenerative medicine in many of the over 280 academic institutions in Germany. Moreover, nonuniversity research institutions such as Helmholtz-, Max-Planck-, Fraunhofer- and Leibniz-Centers provide important contributions to the field of regenerative medicine in Germany. Research on stem cells is conducted in the area of pluripotent stem cells (in particular basic research on induced pluripotent stem [iPS] cells, but also embryonic stem cells) and adult (tissue-specific) stem and progenitor cells, as well as cancer stem cells (both on basic science and translational levels).

  8. Leishmaniasis in Germany.

    PubMed

    Harms, Gundel; Schönian, Gabriele; Feldmeier, Hermann

    2003-07-01

    In 2000, a reference center was created to systematically record leishmaniases in Germany. We analyzed 58 cases of leishmaniases imported during a 2-year period. These findings will serve as a baseline for the sandfly vector's anticipated northward move because of global warming and as an advisory for immunocompromised persons traveling to leishmaniasis-endemic areas.

  9. Teacher Education in Germany.

    ERIC Educational Resources Information Center

    Viebahn, Peter

    2003-01-01

    Applies the concepts of idealism, individualism, and pragmatism from the Association for Teacher Education in Europe's scenario model to Germany's teacher education. Discusses the current German teacher training system's scholarly approach to idealism; notes organizational problems; examines the special psychological demands on students made by…

  10. Germany's Guest Workers.

    ERIC Educational Resources Information Center

    Gupte, Pranay

    1984-01-01

    In wake of a recent recession, Turkish "guest workers" are beginning to feel less welcome in West Germany. Many have accepted government cash incentives to return to Turkey, but others have prospered and wish to stay. The Germans themselves are split over whether the Turks threaten job opportunities for native workers or provide crucial support to…

  11. Career Development in Germany.

    ERIC Educational Resources Information Center

    Hass, Hubert

    In Germany, after elementary school, the school system splits into three branches, with students either preparing for an apprenticeship or continuing in school. A second system exists, parallel to this education system, which combines general education with basic professional training. The first key career decision point is in Grade 4, when…

  12. Germany in Europe 1963.

    ERIC Educational Resources Information Center

    Stanford Univ., CA.

    The results of the 10-week National Defense Education Act (NDEA) Third-Level Institute for Secondary School Teachers of German, conducted by Stanford University in Bad Boll, Germany, are compiled in individual reports written in both German and English by the 25 participants. Emphasizing close contact with the residents in their working and home…

  13. Germany's power potential

    SciTech Connect

    Ruddy, T.

    1992-01-01

    This article examines the potential market for independent power projects in Germany after the reunification. The topics discussed in the article include legal questions, pricing regulations, pollution regulations, energy efficiency regulations, the carbon tax, the market for modernization of power plants and construction of new capacity, and the future outlook.

  14. Germany: The Search for Unity.

    ERIC Educational Resources Information Center

    Blankenship, Glen, Ed.

    The 12 lessons in this collection are designed so that they may be used individually, integrated into the curriculum at appropriate places, or used as a complete unit. The lessons are entitled: (1) Impressions of Germany and Germans; (2) The Location and Population of Germany; (3) Pollution in Germany: A Complex Problems; (4) German Political…

  15. [Tularemia in Germany].

    PubMed

    Kohlmann, R; Geis, G; Gatermann, S G

    2014-07-01

    The bacterium Francisella tularensis is known for more than 100 years by now as the etiological agent of the disease tularemia, a zoonotic infection with a worldwide distribution in the Northern Hemisphere. The prevalence of tularemia shows a wide geographic variation, being comparably infrequent in Germany. Tularemia can present itself with multiple clinical manifestations including ulceroglandular, glandular, oropharyngeal, oculoglandular, respiratory and typhoidal forms. Due to the low prevalence and the unspecific symptomatology, a rapid diagnosis and early start of an effective therapy are rarely obtained. Thus, in this article we summarize important aspects concerning etiology, ecology and routes of transmission, recent epidemiologic situation, clinical picture, diagnostics and treatment of tularemia, focusing on the situation in Germany.

  16. Germany knows mining

    SciTech Connect

    2006-11-15

    Whether it is the nuance of precision or robust rock breaking strength, German suppliers have the expertise. Germany has about 120 companies in the mining equipment industry, employing some 16,000 people. The article describes some recent developments of the following companies: DBT, Liebherr, Atlas Copco, BASF, Boart Longyear, Eickhoff, IBS, Maschinenfabrik Glueckauf, Komatsu, TAKRA, Terex O & R, Thyssen Krupp Foerdertechnik and Wirtgen. 7 photos.

  17. Preparation, characterization, and photocatalytic activity of porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts

    NASA Astrophysics Data System (ADS)

    Yang, Fan; Tian, Baozhu; Zhang, Jinlong; Xiong, Tianqing; Wang, Tingting

    2014-02-01

    Porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts were synthesized by a multistep route, including a dealloying method to prepare porous Ag, a transformation from Ag to AgBr and AgBrI, and a photo-reduction process to form Ag nanoparticles on the surface of AgBr and AgBrI. It was found that the porous structure kept unchanged during Ag was transferred into AgBr, AgBrI, AgBr@Ag, and AgBrI@Ag. Both porous AgBr@Ag and porous AgBrI@Ag showed much higher visible-light photocatalytic activity than cubic AgBr@Ag for the degradation of methyl orange, which is because the interconnected pore channels not only provide more reactive sites but also favor the transportation of photo-generated electrons and holes. For AgBrI@Ag, AgBrI solid solution formed at the interface of AgBr and AgI, and the phase junction can effectively separate the photo-generated electrons and holes, favorable to the improvement of photocatalytic activity. The optimal I content for obtaining the highest activity is ∼10 at.%.

  18. Cardiac rehabilitation in Germany.

    PubMed

    Karoff, Marthin; Held, Klaus; Bjarnason-Wehrens, Birna

    2007-02-01

    The purpose of this review is to give an overview of the rehabilitation measures provided for cardiac patients in Germany and to outline its legal basis and outcomes. In Germany the cardiac rehabilitation system is different from rehabilitation measures in other European countries. Cardiac rehabilitation in Germany since 1885 is based on specific laws and the regulations of insurance providers. Cardiac rehabilitation has predominantly been offered as an inpatient service, but has recently been complemented by outpatient services. A general agreement on the different indications for offering these two services has yet to be reached. Cardiac rehabilitation is mainly offered after an acute cardiac event and bypass surgery. It is also indicated in severe heart failure and special cases of percutaneous coronary intervention. Most patients are men (>65%) and the age at which events occur is increasing. The benefits obtained during the 3-4 weeks after an acute event, and confirmed in numerous studies, are often later lost under 'usual care' conditions. Many attempts have been made by rehabilitation institutions to improve this deficit by providing intensive aftercare. One instrument set up to achieve this is the nationwide institution currently comprising more than 6000 heart groups with approximately 120000 outpatients. After coronary artery bypass grafting or acute coronary syndrome cardiac rehabilitation can usually be started within 10 days. The multidisciplinary rehabilitation team consists of cardiologists, psychologists, exercise therapists, social workers, nutritionists and nurses. The positive effects of cardiac rehabilitation are also important economically, for example, for the improvement of secondary prevention and vocational integration. PMID:17301623

  19. Liver transplantation in Germany.

    PubMed

    Tacke, Frank; Kroy, Daniela C; Barreiros, Ana Paula; Neumann, Ulf P

    2016-08-01

    Liver transplantation (LT) is a well-accepted procedure for end-stage liver disease in Germany. In 2015, 1489 patients were admitted to the waiting list (including 1308 new admissions), with the leading etiologies being fibrosis and cirrhosis (n = 349), alcoholic liver disease (n = 302), and hepatobiliary malignancies (n = 220). Organ allocation in Germany is regulated within the Eurotransplant system based on urgency as expressed by the Model for End-Stage Liver Disease score. In 2015, only 894 LTs (n = 48 from living donors) were performed at 23 German transplant centers, reflecting a shortage of organs. Several factors may contribute to the low number of organ donations. The German transplant legislation only accepts donation after brain death (not cardiac death), whereas advances in neurosurgery and a more frequently requested "palliative care" approach render fewer patients suitable as potential donors. The legislation further requires the active consent of the donor or first-degree relatives before donation. Ongoing debates within the German transplant field address the optimal management of patients with alcoholic liver cirrhosis, hepatocellular carcinoma (HCC), and cholangiocarcinoma and measures to increase living donor transplantations. As a result of irregularities at mainly 4 German transplant centers that were exposed in 2012, guiding principles updated by the German authorities have since implemented strict rules (including internal and external auditing, the 8-eyes principle, mandatory repeated testing for alcohol consumption) to prohibit any manipulations in organ allocation. In conclusion, we will summarize important aspects on the management of LT in Germany, discuss legal and organizational aspects, and highlight challenges mainly related to the relative lack of organ donations, increasing numbers of extended criteria donors, and the peculiarities of the recipient patients. Liver Transplantation 22 1136-1142 2016 AASLD.

  20. Liver transplantation in Germany.

    PubMed

    Tacke, Frank; Kroy, Daniela C; Barreiros, Ana Paula; Neumann, Ulf P

    2016-08-01

    Liver transplantation (LT) is a well-accepted procedure for end-stage liver disease in Germany. In 2015, 1489 patients were admitted to the waiting list (including 1308 new admissions), with the leading etiologies being fibrosis and cirrhosis (n = 349), alcoholic liver disease (n = 302), and hepatobiliary malignancies (n = 220). Organ allocation in Germany is regulated within the Eurotransplant system based on urgency as expressed by the Model for End-Stage Liver Disease score. In 2015, only 894 LTs (n = 48 from living donors) were performed at 23 German transplant centers, reflecting a shortage of organs. Several factors may contribute to the low number of organ donations. The German transplant legislation only accepts donation after brain death (not cardiac death), whereas advances in neurosurgery and a more frequently requested "palliative care" approach render fewer patients suitable as potential donors. The legislation further requires the active consent of the donor or first-degree relatives before donation. Ongoing debates within the German transplant field address the optimal management of patients with alcoholic liver cirrhosis, hepatocellular carcinoma (HCC), and cholangiocarcinoma and measures to increase living donor transplantations. As a result of irregularities at mainly 4 German transplant centers that were exposed in 2012, guiding principles updated by the German authorities have since implemented strict rules (including internal and external auditing, the 8-eyes principle, mandatory repeated testing for alcohol consumption) to prohibit any manipulations in organ allocation. In conclusion, we will summarize important aspects on the management of LT in Germany, discuss legal and organizational aspects, and highlight challenges mainly related to the relative lack of organ donations, increasing numbers of extended criteria donors, and the peculiarities of the recipient patients. Liver Transplantation 22 1136-1142 2016 AASLD. PMID:27082951

  1. Seismicity in Northern Germany

    NASA Astrophysics Data System (ADS)

    Bischoff, Monika; Gestermann, Nicolai; Plenefisch, Thomas; Bönnemann, Christian

    2013-04-01

    Northern Germany is a region of low tectonic activity, where only few and low-magnitude earthquakes occur. The driving tectonic processes are not well-understood up to now. In addition, seismic events during the last decade concentrated at the borders of the natural gas fields. The source depths of these events are shallow and in the depth range of the gas reservoirs. Based on these observations a causal relationship between seismicity near gas fields and the gas production is likely. The strongest of these earthquake had a magnitude of 4.5 and occurred near Rotenburg in 2004. Also smaller seismic events were considerably felt by the public and stimulated the discussion on the underlying processes. The latest seismic event occurred near Langwedel on 22nd November 2012 and had a magnitude of 2.8. Understanding the causes of the seismicity in Northern Germany is crucial for a thorough evaluation. Therefore the Seismological Service of Lower Saxony (NED) was established at the State Office for Mining, Energy and Geology (LBEG) of Lower Saxony in January 2013. Its main task is the monitoring and evaluation of the seismicity in Lower Saxony and adjacent areas. Scientific and technical questions are addressed in close cooperation with the Seismological Central Observatory (SZO) at the Federal Institute for Geosciences and Natural Resources (BGR). The seismological situation of Northern Germany will be presented. Possible causes of seismicity are introduced. Rare seismic events at greater depths are distributed over the whole region and probably are purely tectonic whereas events in the vicinity of natural gas fields are probably related to gas production. Improving the detection threshold of seismic events in Northern Germany is necessary for providing a better statistical basis for further analyses answering these questions. As a first step the existing seismic network will be densified over the next few years. The first borehole station was installed near Rethem by BGR

  2. Medical education in Germany.

    PubMed

    Nikendei, Christoph; Weyrich, Peter; Jünger, Jana; Schrauth, Markus

    2009-07-01

    Following the changes made to the medical licensing regulations of 2002, medical education in Germany has been subject to radical modification, especially at undergraduate level. The implementation of the Bologna Process is still a matter of intense political debate, whilst positive movement has occurred in developing the professionalisation of teaching staff through a Masters Degree in Medical Education. In the area of postgraduate medical education, major restructuring of programmes is occurring, whilst the debate in continuing medical education is related to the amount of practical clinical education that is required.

  3. Forensic entomology in Germany.

    PubMed

    Amendt, J; Krettek, R; Niess, C; Zehner, R; Bratzke, H

    2000-09-11

    Forensic entomology (FE) is increasingly gaining international recognition. In Germany, however, the development of FE has been stagnating, mainly because of the lack of cooperation between police, forensic medicine and entomology. In 1997 a co-operative research project 'Forensic Entomology' was started in Frankfurt/Main at the Center of Legal Medicine and the Research Institute Senckenberg. The aim of this project is to establish FE in Germany as a firmly integrated component of the securing of evidence from human cadavers in cases of suspected homicide. For this purpose we developed a forensic insect collecting kit, and policemen are educated for greater acceptance and better application of FE. The scientific programme focuses on the investigation of the insect succession on cadavers in urban and rural habitats. This also includes new indicator groups (e.g. parasitic wasps) for a more precise calculation of the late post mortem interval. Recently a DNA-based reliable and fast identification method especially for the immature stages of necrophagous insects became part of the project. Preliminary results are reported and two case studies presented.

  4. Immigrant Languages in Federal Germany.

    ERIC Educational Resources Information Center

    Gogolin, Ingrid; Reich, Hans

    About 10 million inhabitants of Germany are of non-German origin and use German and one or more other languages in their everyday life. The number of foreign students in German schools is constantly growing. About 25 percent of Germany's foreign population are citizens of other European Union states. The largest group of minority language speakers…

  5. Mass Media in East Germany.

    ERIC Educational Resources Information Center

    Berlin, Antje

    This paper focuses on media politics, guidance and control mechanisms, journalism education, various modes of media in use, and coverage of important news in East Germany. The paper gives special consideration to the influence of West German broadcasting in East Germany. The need for such information is that it will give insight into Eastern bloc…

  6. Phytomedicine research in Germany.

    PubMed Central

    Wagner, H

    1999-01-01

    In Germany since 1980, more than 300 clinical studies have been carried out with standardized phytopharmaceuticals, including Crataegus, Silybum, Ginkgo, Hypericum, Sabal, Urtica, Kava-Kava, Allium sativum, Valeriana, Aesculus, Echinacea, and Viscum drugs. These studies assessed the efficacy of phytopharmaceuticals for the treatment of moderate or moderately severe diseases and prevention. Several comparative clinical trials showed that these phytopharmaceuticals had full therapeutic equivalence with chemotherapeutics and had the simultaneous advantage of being devoid of any adverse effects. The mechanism of action of herbal drugs and their extract preparations, which differ in many respects from that of synthetic drugs or mono substances, can be characterized as a polyvalent action and interpreted as additive or, in some cases, potentiating. Currently, a rationale for the observed reversal effects and optimal effects with very low doses after a long-term application has not been developed, but is under investigation by systematic research at the molecular level. PMID:10504142

  7. Germany: Health system review.

    PubMed

    Busse, Reinhard; Blümel, Miriam

    2014-01-01

    This analysis of the German health system reviews recent developments in organization and governance, health financing, health care provision, health reforms and health system performance. In the German health care system, decision-making powers are traditionally shared between national (federal) and state (Land) levels, with much power delegated to self-governing bodies. It provides universal coverage for a wide range of benefits. Since 2009, health insurance has been mandatory for all citizens and permanent residents, through either statutory or private health insurance. A total of 70 million people or 85% of the population are covered by statutory health insurance in one of 132 sickness funds in early 2014. Another 11% are covered by substitutive private health insurance. Characteristics of the system are free choice of providers and unrestricted access to all care levels. A key feature of the health care delivery system in Germany is the clear institutional separation between public health services, ambulatory care and hospital (inpatient) care. This has increasingly been perceived as a barrier to change and so provisions for integrated care are being introduced with the aim of improving cooperation between ambulatory physicians and hospitals. Germany invests a substantial amount of its resources on health care: 11.4% of gross domestic product in 2012, which is one of the highest levels in the European Union. In international terms, the German health care system has a generous benefit basket, one of the highest levels of capacity as well as relatively low cost-sharing. However, the German health care system still needs improvement in some areas, such as the quality of care. In addition, the division into statutory and private health insurance remains one of the largest challenges for the German health care system, as it leads to inequalities. PMID:25115137

  8. Occupational cancer in Germany.

    PubMed Central

    Brüske-Hohlfeld, I

    1999-01-01

    As in probably mostly all other European countries, the incidence of occupational cancer in Germany increased steadily after World War II. In 1994 about 1,600 cases of occupational cancer were compensated--more than ever before. More than half of these cases were lung cancer, most caused either by asbestos (n=545) or by ionizing radiation ((italic)n(/italic)=306). Other frequent target organs of asbestos were the pleura and the peritoneum with 495 cases of mesotheliomas. Asbestos was the single most important risk factor for occupational cancer, causing more than 1000 deaths per year. All other malignant diseases, such as bladder cancer, leukemia, angiosarcoma of the liver, adenocarcinoma of the nose or nasal sinuses, and skin cancer, were comparatively rare. Although primary exposure to ionizing radiation in uranium ore mining occurred in the 1950s and attributable lung cancers seem to be on the decline, this is not true for asbestos, where the peak incidence in lung cancer and mesothelioma has not been reached yet. Images Figure 2 PMID:10350508

  9. Cardiac rehabilitation in Germany.

    PubMed

    Cantwell, J D

    1976-09-01

    The concept of cardiac reconditioning centers for the prevention and rehabilitation of coronary patients has been tremendously successful in Germany over the past 20 years. At least 40 such centers are located throughout the country. Physicians, nurses, and physical therapists work closely together in the various facets of the rehabilitation process. The financial backing for these facilities is primarily through governmental and regional insurance companies, whose officials are apparently convinced that in the long run supporting preventive measures is financially sound. Objective data supporting their convictions come from studies such as that of Brusis, who showed that such as that of 1,500 employees was diminished by nearly 70 percent during a two-year period after cardiac reconditioning, as compared to a similar time period before the rehabilitation experience. Subjective benefits, which are extremely difficult to quantitate in meaningful terms, were nonetheless expressed by nearly all the patients with whom I conversed. Perhaps they have experienced the same feelings that Mark Twain did when he observed that "all frets and worries and chafings sank to sleep in the presence of the benignant serenity of the Alps; the Great Spirit of the Mountains breathed his own peace upon their hurt minds and sore hearts and healed them." PMID:959329

  10. [Stroke management in Germany].

    PubMed

    Fritze, J

    2001-12-01

    Stroke is a leading cause of morbidity and mortality (rank 3) and thus a mass disease. Therefore, immediate access for everybody to stroke treatment services is indispensible. Therapeutic efficacy has been shown for lysis therapy and early rehabilitation in stroke units, respectively. The British-Scandinavian stroke unit concept focusses on immediately starting rehabilitation over 4-6 weeks by a specifically trained and motivated team. Since 1995, so-called stroke units are established in Germany adhering to a specific concept of the German Society for Neurology (DGN). Although referring to the British-Scandinavian concept in terms of efficacy the German concept differs fundamentally by focussing on monitoring as well as lysis therapy and neuroprotection in a short (3-5 days) stay. This is an intensive care unit approach for which scientific evidence is lacking. More essential are reasonable doubts that this concept can ever expand sufficiently to ensure comprehensive care. At least presently, stroke care is provided unevenly, thus contravening legislation (section 70 Social Security Act Vol. V). Acknowledging the restrictions the DGN adapted its concept, now advocating a two-step model comprising intensive care stroke units plus rehabilitative stroke units. PMID:11761782

  11. AGS experiments - 1994, 1995, 1996

    SciTech Connect

    Depken, J.C.

    1997-01-01

    This report contains the following information on the Brookhaven AGS Accelerator complex: FY 1996 AGS schedule as run; FY 1997 AGS schedule (working copy); AGS beams 1997; AGS experimental area FY 1994 physics program; AGS experimental area FY 1995 physics program; AGS experimental area FY 1996 physics program; AGS experimental area FY 1997 physics program (in progress); a listing of experiments by number; two-phage summaries of each experiment begin here, also ordered by number; listing of publications of AGS experiments begins here; and listing of AGS experimenters begins here.

  12. AgRISTARS

    NASA Technical Reports Server (NTRS)

    1984-01-01

    An introduction to the overall AgRISTARS program, a general statement on progress, and separate summaries of the activities of each project, with emphasis on the technical highlights are presented. Organizational and management information on AgRISTARS is included in the appendices, as is a complete bibliography of publication and reports.

  13. AGS experiments: 1993 - 1994 - 1995

    SciTech Connect

    Depken, J.C.

    1996-04-01

    This report contains: FY 1995 AGS Schedule as Run; FY 1996-97 AGE Schedule (working copy); AGS Beams 1995; AGS Experimental Area FY 1993 Physics Program; AGS Experimental Area FY 1994 Physics Program; AGS Experimental Area FY 1995 Physics Program; AGS Experimental Area FY 1996 Physics Program (In progress); A listing of experiments by number; Two-page summaries of each experiment begin here, also ordered by number; Listing of publications of AGS experiments begins here; and Listing of AGS experimenters begins here. This is the twelfth edition.

  14. Lise Meitner's escape from Germany

    NASA Astrophysics Data System (ADS)

    Sime, Ruth Lewin

    1990-03-01

    Lise Meitner (1878-1968) achieved prominence as a nuclear physicist in Germany; although of Jewish origin, her Austrian citizenship exempted her from Nazi racial laws until the annexation of Austria in 1938 precipitated her dismissal. Forbidden to emigrate, she narrowly escaped to the Netherlands with the help of concerned friends in the international physics community.

  15. The Volkshochschulen: Germany's Community College

    ERIC Educational Resources Information Center

    Meinhardt, Harry

    1978-01-01

    Compares the Volkshochschulen (VHS) or "People's Universities" of Germany with the community college system in the United States. Discusses enrollment policies, job-related instructional programs, functions of the national association of the VHS, and the advancement of adult education in developing nations. (TP)

  16. Adult Education in Western Germany.

    ERIC Educational Resources Information Center

    Knoll, Joachim H.; And Others

    Here are abstracts of three books on adult education in Western Germany, where the institutions and methods of continuing education have been nearly unknown. The first, ERWACHSENENBILDUNG IN DER BUNDESREPUBLIK (ADULT EDUCATION IN THE FEDERAL REPUBLIC), 167 pages, justifies regarding adult education today as a complete changeover from its forms in…

  17. Impedance studies of the cell Ag/AgI/Ag beta alumina/AgI/Ag. Technical report No. 15, August 1987-August 1988

    SciTech Connect

    Breiter, M.W.; Drstak, H.; Maly-Schreiber, M.

    1988-07-01

    The construction of the cell Ag/AgI/Ag beta alumina/AgI/Ag is described. The impedance of this cell was measured between .001 and 10000 Hz at temperatures between 20 and 550 C. At temperatures below 100 C the cell impedance is determined to a large extent by the bulk resistance of the AgI layer and to a smaller extent by the impedance of the interface Ag/Agi. At temperatures between 160 and 350 C the impedance is controlled by the bulk resistance of the Ag beta alumina and an impedance due to contact problems between Ag and AgI. The bulk resistance of the beta' alumina becomes predominant between 350 and 550 C. A hindrance due to the transfer of silver ions from AgI to Ag beta' alumina was not observable in the whole temperature range.

  18. Sexually transmitted diseases in Germany.

    PubMed

    Petzoldt, D; Jappe, U; Hartmann, M; Hamouda, O

    2002-04-01

    In the former West Germany, in specific venereal diseases legislation passed in 1953, only syphilis, gonorrhoea, ulcus molle, and lymphogranuloma venereum were defined as venereal diseases and subject to mandatory notification. The proportion of unreported cases was as high as 75% for syphilis and up to 90% for gonorrhoea. Epidemiological data for the past 10 years exist only on selected populations from research studies and are summarized in this article. In the former East Germany reporting of sexually transmitted infections (STIs) was mandatory and, due to the centralized organization, underreporting was considered to be low, although no specific studies have examined this. After the unification in 1990 of the two German states the West German laws were adopted in East Germany. Since 1982 - when the first AIDS case was reported in Germany - information on AIDS cases has voluntarily been collected at the national register at the AIDS Centre of the Robert Koch Institute in Berlin. The law governing the reporting of infectious diseases has recently been revised. Under the new Protection against Infection Act, which became effective on 1 January 2001, clinical diagnoses of STIs (with the exception of hepatitis B) are no longer notifiable diseases. Laboratory reporting of positive test results for Treponema pallidum has been introduced. With T. pallidum and HIV notifications, additional disaggregated data are collected. Since T. pallidum and HIV remain the only notifiable STIs, all other STIs have to be monitored through sentinel surveillance systems. These surveillance systems are currently being established. Under the new legislation, local health authorities have to provide adequate counselling and testing services for STIs, which may be provided free of charge if necessary.

  19. Nutritional behaviour differences in Germany.

    PubMed

    Thiel, C; Heinemann, L

    1996-01-01

    East- and west-German health inequalities that emerged in the 1960s and 1970s centered not only on cardiovascular mortality but also on lifestyle-dependent risk factors, thus a question that should be addressed is whether different dietary behaviours existed in the two sections of Germany. To answer this question, we examined two random-sample population surveys--MONICA in the east and VERA in the west--that were carried out during the late 1980s. In the eastern section of Germany, the consumption of milk, vegetable oil and fat, fresh vegetables and tropical fruits was much lower than that in the west, whereas the intake of sausages and butter was much higher. Consequently, the calorie intake in the east was higher for fat and lower for carbohydrates before reunification. Changes in dietary habits were anticipated in East Germany after reunification because of important changes in the food supply. Analysis of an east-German dietary survey that was carried out after the wall came down revealed that the improved food supply to the east, with more choices for planning a healthy diet, led to a favourable development in both macro- and micro-nutrient intake, more carbohydrates, vitamins, calcium, and potassium were consumed.

  20. Incidence of Narcolepsy in Germany

    PubMed Central

    Oberle, Doris; Drechsel-Bäuerle, Ursula; Schmidtmann, Irene; Mayer, Geert; Keller-Stanislawski, Brigitte

    2015-01-01

    Study Objectives: Following the 2009 pandemic, reports of an association between an AS03 adjuvanted H1N1 pandemic influenza vaccine and narcolepsy were published. Besides determining background incidence rates for narcolepsy in Germany this study aimed at investigating whether there was a change in incidence rates of narcolepsy between the pre-pandemic, pandemic, and the post-pandemic period on the population level. Design: Retrospective epidemiological study on the incidence of narcolepsy with additional capture-recapture analysis. Setting: German sleep centers. Patients or Participants: Eligible were patients with an initial diagnosis of narcolepsy (ICD10 Code G47.4) within the period from January 1, 2007 to December 31, 2011. Interventions: None; observational study. Measurements and Results: A total of 342 sleep centers were invited to participate in the study. Adequate and suitable data were provided by 233 sleep centers (68.1%). A total of 1,198 patients with an initial diagnosis of narcolepsy within the observed period were included, of whom 106 (8.8%) were children and adolescents under the age of 18 years and 1,092 (91.2%) were adults. In children and adolescents, the age-standardized adjusted incidence rate significantly increased from 0.14/100,000 person-years in the pre-pandemic period to 0.50/100,000 person-years in the post-pandemic period (incidence density ratio, IDR 3.57; 95% CI 1.94–7.00). In adults, no significant change was detectable. This increase started in spring 2009. Conclusions: For the years 2007–2011, valid estimates for the incidence of narcolepsy in Germany were provided. In individuals under 18, the incidence rates continuously increased from spring 2009. Citation: Oberle D, Drechsel-Bäuerle U, Schmidtmann I, Mayer G, Keller-Stanislawski B. Incidence of narcolepsy in Germany. SLEEP 2015;38(10):1619–1628. PMID:25902804

  1. Recycling of plastics in Germany

    SciTech Connect

    Thienen, N. von; Patel, M.

    1999-07-01

    This article deals with the waste management of post-consumer plastics in Germany and its potential to save fossil fuels and reduce CO{sub 2} emissions. Since most experience is available for packaging, the paper first gives an overview of the legislative background and the material flows for this sector. Then recycling and recovery processes for plastics waste from all sectors are assessed in terms of their contribution to energy saving and CO{sub 2} abatement. Practically all the options studied show a better performance than waste treatment in an average incinerator which has been chosen as the reference case. High ecological benefits can be achieved by mechanical recycling if virgin polymers are substituted. The paper then presents different scenarios for managing plastic waste in Germany in 1995: considerable savings can be made by strongly enhancing the efficiency of waste incinerators. Under these conditions the distribution of plastics waste among mechanical recycling, feedstock recycling and energy recovery has a comparatively mall impact on the overall results. The maximum savings amount to 74 PJ of energy, i.e, 9% of the chemical sector energy demand in 1995 and 7.0 Mt CO{sub 2}, representing 13% of the sector's emissions. The assessment does not support a general recommendation of energy recovery due to the large difference between the German average and the best available municipal waste-to-energy facilities and also due to new technological developments in the field of mechanical recycling.

  2. The Mother Centers in Germany--Empowerment Strategies for Community Women in Germany.

    ERIC Educational Resources Information Center

    Jaeckel, Monika

    Mother Centers are a grassroots self-help movement in Germany that help stay-at-home mothers break through the isolation they experience in German society when they have children and are not available for full-time employment. There are about 300 mother center projects currently in Germany, including 40 in the former East Germany. The programs…

  3. Update on Germany: Now Eastern Germany Gets a Free Press. Special Report SO 8, 1991.

    ERIC Educational Resources Information Center

    Meyn, Hermann

    Since the former East German Communist State--the German Democratic Republic (GDR)--was incorporated into the Federal Republic of Germany, the federal constitution has been valid throughout the whole of Germany, guaranteeing press freedom and ending press censorship in eastern Germany. In October 1989, the GDR had 39 daily newspapers (many…

  4. [Epidemiology of malignant melanoma in East Germany and West Germany].

    PubMed

    Jung, H D

    1982-12-01

    Data are given on the incidence of the malignant melanoma in the German Democratic Republic. The latter steadily increased from 1955 to 1975, i.e., from 1.55/100,000 (male) and 1.80/100,000 (female) to 3.1/100,000 (male) and 4.3/100,000 (female). A genuine increase of the incidence can be proven by age standardization from 1968 to 1975. Between 1955 and 1975 the incidence in men and women doubled in the German Democratic Republic. The death rate from malignant melanomas is about stationary. The survival rate in men lies about 50%, that in women is higher. In the Federal Republic of Germany about 1,674 incidences in 1969, about 1,825 in 1974, and more than 2,000 incidences of malignant melanomas in 1975 were to be expected. UV radiation and chemical carcinogens influence the incidence of the malignant melanoma in our area.

  5. Ag Division States Philosophy

    ERIC Educational Resources Information Center

    American Vocational Journal, 1976

    1976-01-01

    The discussion which took place during the American Vocational Association's (AVA) Agriculture Division meeting at the 1975 AVA Convention is summarized, and the statement of vo-ag education philosophy (including 13 key concepts), which was passed during the convention, is presented. (AJ)

  6. History of anesthesia in Germany.

    PubMed

    Wawersik, J

    1991-01-01

    The first ether anesthetic was administered in Germany by J.F. Heyfelder (1798-1869) at the Erlangen University Hospital on January 24, 1847. Thereafter, famous discoveries occurred in the field of pharmacology. Albert Niemann isolated cocaine from the coca shrub in 1860; Emil Fischer synthesized the first barbiturate, Veronal, in 1902; and Helmut Weese promoted the first ultra-short-acting barbiturate, hexobarbital (Evipan), in 1932. The local anesthetic effect of cocaine was reported by Koller at the Congress of the German Society for Ophthalmology on September 15, 1884, in Heidelberg. Many new techniques were tried first in German hospitals. Friedrich Trendelenburg carried out, by tracheotomy, the first operation with endotracheal intubation in 1869, and Franz Kuhn promoted and clinically practiced endotracheal intubation in Heidelberg beginning in 1900. August Bier performed the first operation under spinal anesthesia at the Kiel University Hospital on August 16, 1898. Carl Ludwig Schleich (1859-1922) standardized the methods of infiltration anesthesia by using a cocaine solution in sufficient dilution. The development of anesthesia machines was greatly influenced by Heinrich Dräger (1847-1917) and his son Bernhard Dräger (1870-1928). The Dräger Company in Lübeck built the first anesthesia machine with a carbon dioxide (CO2) absorber and circle system in 1925. Paul Sudeck and Helmut Schmidt worked with this system at the Hamburg University Hospital and reported their results in 1926. The first Dräger anesthesia machine was produced in 1902 and introduced into clinical use by Otto Roth (1863-1944) in Lübeck. Before the Second World War, three universities in Germany carried out research in the field of anesthesia: the University of Freiburg with H. Killian, the University of Hamburg with P. Sudeck and H. Schmidt, and the University of Würzburg with C.G. Gauss. Killian and Gauss established the first journals, Der Schmerz and Narkose und Anaesthesie, in

  7. The Corporate University Landscape in Germany

    ERIC Educational Resources Information Center

    Andresen, Maike; Lichtenberger, Bianka

    2007-01-01

    Purpose: The paper seeks first to present an overview of the corporate university landscape in Germany contrasting it with the US-American corporate university market and, second, to outline the development in Germany during the last 15 years and to have a look at future trends such as learning alliances. Design/methodology/approach: The…

  8. The Economic Development of Postwar Germany.

    ERIC Educational Resources Information Center

    Dinan, Desmond

    1993-01-01

    Reviews the economic restoration of West Germany through the Marshall Plan following World War II. Traces the development of the European Community from the Schuman Declaration of 1950 to the present. Contends that Germany's economy must remain closely tied to a united Europe in the post-Cold War international system. (CFR)

  9. 2 x Germany; 2 x Political Education.

    ERIC Educational Resources Information Center

    Moldenhauer, Gebhard

    1991-01-01

    Describes textbooks of both East and West Germany from 1949-56, 1957-62, 1963-69, and 1970 on. Discusses a shift in West German texts from intense antagonism during the Cold War to a more critical comparison by the 1980s. Compares East German text development that increased in hostility over time, viewing West Germany as a negative alternative to…

  10. Germany since 1945: A Focus on Berlin.

    ERIC Educational Resources Information Center

    Blankenship, Glen; Smith, Lindsey

    This lesson accompanies a videotape which examines some of the forces, personalities and events which shaped Berlin and the rest of Germany between 1945 and 1994. The lesson is introduced by using the videotape and uses references from the videotape for further classroom work. Worksheets for student use include "Events in Germany, 1945-1994" and…

  11. Transforming Higher Education in East Germany.

    ERIC Educational Resources Information Center

    de Rudder, Helmut

    1993-01-01

    A discussion of higher education in the former German Democratic Republic looks at the common historical roots of central European universities, the different directions higher education took in East and West Germany after 1945, and the current turbulent transformation of higher education in East Germany during German unification. (Author/MSE)

  12. OSL Dating of Maar Lake Sediments (Eifel/Germany)

    NASA Astrophysics Data System (ADS)

    Schmidt, E. D.; Sirocko, F.; Frechen, M.; Tsukamoto, S.

    2009-04-01

    OSL Dating of Maar Lake Sediments (Eifel/Germany) Esther D. Schmidt1, Frank Sirocko2, Manfred Frechen1 and Sumiko Tsukamoto1 1Leibniz Institute for Applied Geosciences, Department for Geochronology and Isotope Hydrology Hannover/ Germany - esther.schmidt@gga-hannover.de 2University of Mainz/Germany, Institute for Geoscience Keywords: Maar lake sediments, luminescence dating, Eifel/Germany. Sediment cores have been drilled by the ELSA project (Eifel Laminated Sediment Archive) in Eifel dry maar lakes to reconstruct the palaeoclimatic and palaeoenvironmental conditions as well as the history of the volcanism in the Eifel/Central Europe during the last glacial cycles (Sirocko et al. 2005). Lake sediments accumulating in relict volcanic craters have undergone continuous deposition since the eruption of the maar volcano, and hence contain unique continuous local records of climate change. The aim of this study is to test the applicability of luminescence dating techniques for the temporal successions of dust storm events. Luminescence dating has been has been significantly improved over recent years and is widely used to establish confident chronologies of glacial/interglacial cycles (Schmidt et al. submitted). Equivalent doses (De) were determined applying the Single Aliquot Regenerative dose (SAR) protocol (Murray and Wintle 2000) using infra red light stimulation for feldspar and blue light stimulation for quartz. In further work other luminescence techniques like thermal transferred OSL (TT-OSL) and Infrared Radiofluorescence (IR-RF) will also be tested on the dust storm events of the maar lake sediments. References Murray, A.S., Wintle, A.G., 2000. Luminescence dating of quartz using an improved single-aliquot regenerative-dose protocol. Radiation Measurements, 32: 57-73. Schmidt, E.D., Machalett, B., Marković, S.B., Tsukamoto, S., Frechen, M., submitted. Luminescence chronology of the upper part of the Stari Slankamen loess sequence (Vojvodina, Serbia

  13. Freeze-dried PVP-Ag+ precursors to novel AgBr/AgCl-Ag hybrid nanocrystals for visible-light-driven photodegradation of organic pollutants

    NASA Astrophysics Data System (ADS)

    Chen, Deliang; Chen, Qianqian; Zhang, Wenjie; Ge, Lianfang; Shao, Gang; Fan, Bingbing; Lu, Hongxia; Zhang, Rui; Yang, Daoyuan; Shao, Guosheng

    2015-04-01

    AgBr/AgCl-Ag nanocrystals with various molar Br-to-Ag ratios (RBr/Ag = 0, 1/3, 1/2, 2/3, 1) and different photoreduction times (0-20 min) were synthesized via stepwise liquid-solid reactions using the freeze-dried PVP-Ag+ hybrid as the Ag source, followed by a photoreduction reaction. The AgBr/AgCl-Ag7.5(1:2) nanocrystals obtained take on a spherical morphology with a particle-size range of 58 ± 15 nm. The photocatalytic performance of AgBr/AgCl-Ag nanocrystals was evaluated by photodegrading organic dyes, 4-chlorophenol and isopropanol under artificial visible light (λ ⩾ 420 nm, 100 mW cm-2). For the decomposition of rhodamine B, the AgBr/AgCl-Ag7.5(1:2) nanocrystals has a photodegradation rate of ∼0.87 min-1, ∼159 times higher than that (∼0.0054 min-1) of TiO2 (P25), whereas the AgCl-Ag and AgBr-Ag nanocrystals have photodegradation rates of 0.35 min-1 and 0.45 min-1, respectively. The efficient separation of photogenerated electron-hole pairs in the ternary system consisting of AgBr, AgCl and Ag species plays a key role in the enhancement of photocatalytic performance.

  14. [Health and justice in Germany].

    PubMed

    Rosenbrock, R

    2007-12-01

    "What do we owe each other?" Variously grounded postulates and theories of social justice try to answer this question with regard to health. Equality of opportunity is widely acclaimed and in Germany also anchored in social security laws. From the perspective of equal opportunity, the author examines the state of affairs and the perspectives of equity in health. Although the deficiencies with regard to access and quality of health care are significant, but relatively moderate, they present serious threats to equity and fairness for the future. Regarding non-medical primary prevention, the reduction of inequality in health has barely begun. The largest obstacles to equity in health are to be found in the distribution and dynamics of opportunities for education, work and income. One of the tasks of public health professionals is to place the health consequences of existing policies on the political agenda.

  15. Children's "euthanasia" in Nazi Germany.

    PubMed

    Benedict, Susan; Shields, Linda; O'Donnell, Alison J

    2009-12-01

    Children with disabilities were killed during the Nazi era, often by nurses. Some nurses killed children, saying that they were under orders. Propaganda about the need for "racial purity" was all pervasive and influenced much of the population, including nurses. The German people accepted the "mercy" killing of children with disabilities. We describe the children's "euthanasia" program, explore the influence of propaganda, ask why it was acceptable to kill children, and provide historical context demonstrating "slippery slopes" which can lead to abrogation of ethical principles. Discussion of such history is essential as the ethical principles which were breached are still the cornerstone of nursing practice today. Only by openly discussing past wrongs can we attempt to ensure that they do not happen again. Archival documents from Germany and Israel, including trial depositions and transcripts, provided material, supplemented by secondary classic sources.

  16. AGS experiments -- 1995, 1996 and 1997

    SciTech Connect

    Depken, J.C.; Presti, P.L.

    1997-12-01

    This report contains (1) FY 1995 AGS schedule as run; (2) FY 1996 AGS schedule as run; (3) FY 1997 AGS schedule as run; (4) FY 1998--1999 AGS schedule (proposed); (5) AGS beams 1997; (6) AGS experimental area FY 1995 physics program; (7) AGS experimental area FY 1996 physics program; (8) AGS experimental area FY 1997 physics program; (9) AGS experimental area FY 1998--1999 physics program (proposed); (10) a listing of experiments by number; (11) two-page summaries of each experiment, in order by number; and (12) listing of publications of AGS experiments.

  17. AGS experiments -- 1991, 1992, 1993. Tenth edition

    SciTech Connect

    Depken, J.C.

    1994-04-01

    This report contains: (1) FY 1993 AGS schedule as run; (2) FY 1994--95 AGS schedule; (3) AGS experiments {ge} FY 1993 (as of 30 March 1994); (4) AGS beams 1993; (5) AGS experimental area FY 1991 physics program; (6) AGS experimental area FY 1992 physics program; (7) AGS experimental area FY 1993 physics program; (8) AGS experimental area FY 1994 physics program (planned); (9) a listing of experiments by number; (10) two-page summaries of each experiment; (11) listing of publications of AGS experiments; and (12) listing of AGS experiments.

  18. Destabilization of Ag nanoislands on Ag(100) by adsorbed sulfur

    SciTech Connect

    Shen, Mingmin; Russell, Selena M.; Liu, Da-Jiang; Thiel, Patricia A.

    2011-10-17

    Sulfur accelerates coarsening of Ag nanoislands on Ag(100) at 300 K, and this effect is enhanced with increasing sulfur coverage over a range spanning a few hundredths of a monolayer, to nearly 0.25 monolayers. We propose that acceleration of coarsening in this system is tied to the formation of AgS{sub 2} clusters primarily at step edges. These clusters can transport Ag more efficiently than can Ag adatoms (due to a lower diffusion barrier and comparable formation energy). The mobility of isolated sulfur on Ag(100) is very low so that formation of the complex is kinetically limited at low sulfur coverages, and thus enhancement is minimal. However, higher sulfur coverages force the population of sites adjacent to step edges, so that formation of the cluster is no longer limited by diffusion of sulfur across terraces. Sulfur exerts a much weaker effect on the rate of coarsening on Ag(100) than it does on Ag(111). This is consistent with theory, which shows that the difference between the total energy barrier for coarsening with and without sulfur is also much smaller on Ag(100) than on Ag(111).

  19. AGS preinjector improvement

    SciTech Connect

    Alessi, J.G.; Brennan, J.M.; Brown, H.N.; Brodowski, J.; Gough, R.; Kponou, A.; Prelec, K.; Staples, J.; Tanabe, J.; Witkover, R.

    1987-01-01

    In 1984, a polarized H/sup -/ source was installed to permit the acceleration of polarized protons in the AGS, using a low current, 750 keV RFQ Linear Accelerator as the preinjector. This RFQ was designed by LANL and has proved to be quite satisfactory and reliable. In order to improve the reliability and simplify maintenance of the overall AGS operations, it has been decided to replace one of the two 750 keV Cockcroft-Waltons (C-W) with an RFQ. The design of a new high current RFQ has been carried out by LBL and is also being constructed there. This paper describes the preinjector improvement project, centered around that RFQ, which is underway at BNL.

  20. Imported furuncular myiasis in Germany.

    PubMed

    Robert, Leon; Yelton, John

    2002-12-01

    Furuncular myiasis is a parasitic infestation of human and other vertebrate tissues by fly larvae of primarily two species: Dermatobia hominis (human botfly, t6rsalo, or berne) in Mexico and South and Central America and Cordylobia anthropophaga (tumbu fly or mango fly) in Africa. Cuterebra species (rabbit and rodent botflies) are also rarely reported to cause furuncular myiasis only within the United States. Although these species inhabit different geographic regions and have different life cycles, their clinical presentations can be similar. We describe a case of "imported" human botfly (D. hominis) furuncular myiasis in a U.S. Army soldier stationed in Germany. We review the life cycles of human botflies and key aspects of their clinical presentation, differential diagnosis, and various therapeutic modalities. Most physicians may never encounter myiasis and attribute a patient's complaints to an insect bite or skin infection that will heal without treatment. However, the diagnosis of furuncular myiasis should be considered by remembering the basic elements of this condition: recent travel history to the tropics and a sterile, persistent furuncle with sensations of movement and pain.

  1. Management of plasmapheresis in Germany.

    PubMed

    Müller, N

    1996-05-01

    In Germany, plasmapheresis is carried out for many years in a "mixed" system by private and non-profit organisation. Most of the institutions and blood transfusion service, active in the field of plasmapheresis are members of the "Association for the Establishment, Co-ordination and Working Methods of the Plasmapheresis Centres". All centres are authorized by governmental bodies for manufacturing of pharmaceutical products with regulatory controls regarding licensing and accreditation of blood collection establishment. All parties concerned agree that self-sufficiency of plasma has to be achieved. For this purpose there is a shortage of about 400,000 1 of plasma. In 1994, about 240,000 1 of plasma were collected by plasmapheresis, 91% for fractionation and 8.7% for direct clinical uses. In addition about 970,000 1 of plasma were derived from whole blood donations. The dualism of non-profit making and commercial organisations should be regarded as a chance for diversification in the collection and processing of plasma. A long term increase in plasmapheresis plasma can be achieved by initiating plasmapheresis programmes and co-operation using the existing infrastructures and supports the aim for self-sufficiency.

  2. Preparation and antibacterial activities of Ag/Ag+/Ag3+ nanoparticle composites made by pomegranate (Punica granatum) rind extract

    NASA Astrophysics Data System (ADS)

    Yang, Hui; Ren, Yan-yu; Wang, Tao; Wang, Chuang

    Nano-silver and its composite materials are widely used in medicine, food and other industries due to their strong conductivity, size effect and other special performances. So far, more microbial researches have been applied, but a plant method is rarely reported. In order to open up a new way to prepare AgNP composites, pomegranate peel extract was used in this work to reduce Ag+ to prepare Ag/Ag+/Ag3+ nanoparticle composites. UV-Vis was employed to detect and track the reduction of Ag+ and the forming process of AgNPs. The composition, structure and size of the crystal were analyzed by XRD and TEM. Results showed that, under mild conditions, pomegranate peel extract reacted with dilute AgNO3 solution to produce Ag/Ag+/Ag3+ nanoparticle composites. At pH = 8 and 10 mmol/L of AgNO3 concentration, the size of the achieved composites ranged between 15 and 35 nm with spherical shapes and good crystallinity. The bactericidal experiment indicated that the prepared Ag/Ag+/Ag3+ nanoparticles had strong antibacterial activity against gram positive bacteria and gram negative bacteria. FTIR analysis revealed that biological macromolecules with groups of sbnd NH2, sbnd OH, and others were distributed on the surface of the newly synthesized Ag/Ag+/Ag3+ nanoparticles. This provided a useful clue to further study the AgNP biosynthesis mechanism.

  3. TUM Critical Zone Observatory, Germany

    NASA Astrophysics Data System (ADS)

    Völkel, Jörg; Eden, Marie

    2014-05-01

    Founded 2011 the TUM Critical Zone Observatory run by the Technische Universität München and partners abroad is the first CZO within Germany. TUM CZO is both, a scientific as well as an education project. It is a watershed based observatory, but moving behind this focus. In fact, two mountainous areas are integrated: (1) The Ammer Catchment area as an alpine and pre alpine research area in the northern limestone Alps and forelands south of Munich; (2) the Otter Creek Catchment in the Bavarian Forest with a crystalline setting (Granite, Gneiss) as a mid mountainous area near Regensburg; and partly the mountainous Bavarian Forest National Park. The Ammer Catchment is a high energy system as well as a sensitive climate system with past glacial elements. The lithology shows mostly carbonates from Tertiary and Mesozoic times (e.g. Flysch). Source-to-sink processes are characteristic for the Ammer Catchment down to the last glacial Ammer Lake as the regional erosion and deposition base. The consideration of distal depositional environments, the integration of upstream and downstream landscape effects are characteristic for the Ammer Catchment as well. Long term datasets exist in many regards. The Otter Creek catchment area is developed in a granitic environment, rich in saprolites. As a mid mountainous catchment the energy system is facing lower stage. Hence, it is ideal comparing both of them. Both TUM CZO Catchments: The selected catchments capture the depositional environment. Both catchment areas include historical impacts and rapid land use change. Crosscutting themes across both sites are inbuilt. Questions of ability to capture such gradients along climosequence, chronosequence, anthroposequence are essential.

  4. Ag-Air Service

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Econ, Inc.'s agricultural aerial application, "ag-air," involves more than 10,000 aircraft spreading insecticides, herbicides, fertilizer, seed and other materials over millions of acres of farmland. Difficult for an operator to estimate costs accurately and decide what to charge or which airplane can handle which assignment most efficiently. Computerized service was designed to improve business efficiency in choice of aircraft and determination of charge rates based on realistic operating cost data. Each subscriber fills out a detailed form which pertains to his needs and then receives a custom-tailored computer printout best suited to his particular business mix.

  5. Communication: Structure, formation, and equilibration of ensembles of Ag-S complexes on an Ag surface

    SciTech Connect

    Russell, Selena M.; Kim, Yousoo; Liu, Da-Jiang; Evans, J. W.; Thiel, P. A.

    2013-02-15

    We have utilized conditions of very low temperature (4.7 K) and very low sulfur coverage to isolate and identify Ag-S complexes that exist on the Ag(111) surface. The experimental conditions are such that the complexes form at temperatures above the temperature of observation. These complexes can be regarded as polymeric chains of varying length, with an Ag4S pyramid at the core of each monomeric unit. Steps may catalyze the formation of the chains and this mechanism may be reflected in the chain length distribution.

  6. AGS Experiments: 1989, 1990, 1991

    SciTech Connect

    Depken, J.C.

    1992-02-01

    This report contains: Experimental areas layout; table of beam parameters and fluxes; experiment schedule as run''; proposed 1992 schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS Experiments begin here; and list of AGS Experimenters begins here.

  7. AGS Experiments: 1989, 1990, 1991

    SciTech Connect

    Depken, J.C.

    1992-02-01

    This report contains: Experimental areas layout; table of beam parameters and fluxes; experiment schedule ``as run``; proposed 1992 schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS Experiments begin here; and list of AGS Experimenters begins here.

  8. One Germany, Two Identities? Challenges to Political Education in Germany Following Unification.

    ERIC Educational Resources Information Center

    Sussmuth, Hans

    After a discussion of the circumstances that led to the unification of the two German states, this paper then evaluates the challenges to political education in Germany after unification. Beginning with the focus by the media and politics on the effects of East German political changes on the two German states, the revolution in East Germany and…

  9. Left heart bypass support with the Rotaflow Centrifugal Pump® as a bridge to decision and recovery in an adult.

    PubMed

    Kashiwa, Koichi; Nishimura, Takashi; Saito, Aya; Kubo, Hitoshi; Fukaya, Aoi; Tamai, Hisayoshi; Yambe, Tomoyuki; Kyo, Shunei; Ono, Minoru

    2012-06-01

    Since left heart bypass or biventricular circulatory assist with an extracorporeal centrifugal pump as a bridge to decision or recovery sometimes requires long-time support, the long-term durability of extracorporeal centrifugal pumps is crucial. The Rotaflow Centrifugal Pump(®) (MAQUET Cardiopulmonary AG, Hirrlingen, Germany) is one of the centrifugal pumps available for long-term use in Japan. However, there have been few reports of left heart bypass or biventricular circulatory support over the mid-term. This is a case report of left heart bypass support with the Rotaflow Centrifugal Pump(®) as a bridge to decision and recovery for an adult patient who could not be weaned from cardiopulmonary bypass and percutaneous cardiopulmonary support after cardiac surgery. We could confirm that the patient's consciousness level was normal; however, the patient could not be weaned from the left heart bypass support lasting 1 month. Therefore, the circulatory assist device was switched to the extracorporeal Nipro ventricular assist device (VAD). This time, left heart bypass support could be maintained for 30 days using a single Rotaflow Centrifugal Pump(®). There were no signs of hemolysis during left heart bypass support. The Rotaflow Centrifugal Pump(®) itself may be used as a device for a bridge to decision or recovery before using a VAD in cardiogenic shock patients.

  10. Paleomagnetism of Jurassic Carbonates from Germany

    NASA Astrophysics Data System (ADS)

    Bachtadse, V.; Settles, E. K.; Soffel, H.

    2014-12-01

    Although the distribution of paleomagnetic data for the Jurassic of stable Europe is notorious for its wide spread and lack of any recognizable age control of pole positions it was only recently that the Jurassic has moved closer to the focus of paleomagnetic research (Kent and Irving, 2010; Muttoni et al. 2013). Here we present paleomagnetic data for carbonate rocks of early and late Jurassic age from southern (Franconia and Swabia) and northern Germany. A total of 406 samples from 37 localities in northern Germany and 180 samples from 19 localities in southern Germany were collected and subjected to detailed demagnetization experiments. All localities are dated biostratigraphically covering the Oxfordian to Tithonian (northern Germany) and the Pliensbachian (southern Germany) in time. After removal of a component of magnetization of secondary origin, stable magnetizations could be identified in 176 samples from 17 sites in northern Germany (D=003.2°, I=53.2°, k=79.4, α95=4.5°). Similar directions (D=001.2°, I=43.3°, k=18.6, α95=13.2°) were isolated in 108 sampled from 8 sites of coeval rocks from southern Germany. Positive fold and reversal tests support our interpretation that the resulting mean direction of is of primary origin e.g. late Jurassic in age. Unfortunately, however, the situation for the early Jurassic of southern Germany is less favourable. Here, only 15 samples from 2 sites yielded magnetizations which were interpreted to be of primary origin (D=025.3°, I=59.4°, k=51.0, α95=11.2°) . The resulting paleo north pole positions for the Lower and Upper Jurassic of Germany plot at comparable latitudes (70°N) but are separated in longitude by roughly 60°. This is compatible with the apparent polar wander path proposed by Kent and Irving (2010). Taking into consideration that the only reliable paleopole for the middle Jurassic of stable Europe is indistinguishable from the late Jurassic paleopole lends additional support to the proposed late

  11. Provisions for containment venting in Germany

    SciTech Connect

    Wilhelm, J.G.

    1997-08-01

    In this short paper an overlook is given of the systems developed in Germany for filtered containment venting and their implementation in nuclear power plants. More information on the development can be found in the Proceedings of the DOE/NRC Aircleaning Conferences. In Germany, 28.8 % of the electric energy is produced by 19 nuclear power reactors. No new power reactor is expected to be built at least within the next ten years, but France and Germany cooperate in the development of a future European Power Reactor (ERP). This reactor type will be fitted with a core catcher and passive cooling in order to avoid serious consequences of a hypothetical core meltdown accident so that provisions for containment venting are not required. 3 refs., 6 figs., 1 tab.

  12. Checklist of earthworms (Oligochaeta: Lumbricidae) from Germany.

    PubMed

    Lehmitz, Ricarda; Römbke, Jörg; Jänsch, Stephan; Krück, Stefanie; Beylich, Anneke; Graefe, Ulfert

    2014-09-23

    A checklist of the German earthworm fauna (Oligochaeta: Lumbricidae) is presented, including published data, data from reports, diploma- and PhD- theses as well as unpublished data from museum collections, research institutions and private persons. Overall, 16,000 datasets were analyzed to produce the first German checklist of Lumbricidae. The checklist comprises 46 earthworm species from 15 genera and provides ecological information, zoogeographical distribution type and information on the species distribution in Germany. Only one species, Lumbricus badensis Michaelsen, 1907, is endemic to Germany, whereas 41% are peregrine. As there are 14 species occurring exclusively in the southern or eastern part of Germany, the species numbers in German regions increase from north to south.

  13. Privacy Laws and Biobanking in Germany.

    PubMed

    Hoppe, Nils

    2016-03-01

    While the possibility of enacting a sui generis Biobank Act has been debated in Germany at great length, as of yet the country has not implemented any biobankspecific legislation. Instead, oversight is available via a network of research and privacy laws, including those of the European Union. The Nationale Kohorte, Germany's large-scale, population-based epidemiological research biobank, is funded by the Federal Ministry of Education and Research, and there are currently 108 registered bio-banks throughout Germany. The current system, including the structure and study design of the Nationale Kohorte, privileges the protection of personal information even at the cost of socially desirable research; it remains to be seen if forthcoming legislation will shift this balance.

  14. The AGS-Booster lattice

    SciTech Connect

    Lee, Y.Y.; Barton, D.S.; Claus, J.; Cottingham, J.G.; Courant, E.D.; Danby, G.T.; Dell, G.F.; Forsyth, E.B.; Gupta, R.C.; Kats, J.

    1987-01-01

    The AGS Booster has three objectives. They are to increase the space charge limit of the AGS, to increase the intensity of the polarized proton beam by accumulating many linac pulses (since the intensity is limited by the polarized ion source), and to reaccelerate heavy ions from the BNL Tandem Van de Graaff before injection into the AGS. The machine is capable of accelerating protons at 7.5 Hertz from 200 MeV to 1.5 GeV or to lower final energies at faster repetition rates. The machine will also be able to accelerate heavy ions from as low as 1 MeV/nucleon to a magnetic rigidity as high as 17.6 Tesla-meters with a one second repetition rate. As an accumulator for polarized protons, the Booster should be able to store the protons at 200 MeV for several seconds. We expect that the Booster will increase the AGS proton intensity by a factor of four, polarized proton intensity by a factor of twenty to thirty, and will also enable the AGS to accelerate all species of heavy ions (at present the AGS heavy ion program is limited to the elements lighter than sulfur because it can only accelerate fully stripped ions). The construction project started in FY 1985 and is expected to be completed in 1989. The purpose of this paper is to provide a future reference for the AGS Booster lattice.

  15. Imported tropical virus infections in Germany.

    PubMed

    Schmitz, H; Emmerich, P; ter Meulen, J

    1996-01-01

    Our routine tests for tropical viruses document that several hundreds of Dengue fever cases are imported into Germany every year. In contrast, hemorrhagic fever cases are rarely diagnosed in Germany. Our investigations suggest that this low number is due to the different living conditions of the local population in the tropics compared with that of travellers from Europe or North America. Improved methods for detecting Dengue virus infections, e.g. three different antibody tests and the reverse transcriptase-polymerase chain reaction (RT-PCR) for detection of viral RNA, have been developed.

  16. AQUABOX 50 AND MARABU PACKED BIOLOGICAL REACTOR SYSTEM TECHNOLOGY EVALUATION, STADTWERKE DUESSELDORF AG SITE, DUESSELDORF, GERMANY

    EPA Science Inventory

    This ITER summarizes the results of an evaluation of the AQUABOX 50 and MARABU Packed Biological Reactor technologies. The evaluation was conducted under a bilateral agreement between the United States (U.S.) Environmental Protection Agency (EPA) Superfund Innovative Technology ...

  17. Spin dynamics simulations at AGS

    SciTech Connect

    Huang, H.; MacKay, W.W.; Meot, F.; Roser, T.

    2010-05-23

    To preserve proton polarization through acceleration, it is important to have a correct model of the process. It has been known that with the insertion of the two helical partial Siberian snakes in the Alternating Gradient Synchrotron (AGS), the MAD model of AGS can not deal with a field map with offset orbit. The stepwise ray-tracing code Zgoubi provides a tool to represent the real electromagnetic fields in the modeling of the optics and spin dynamics for the AGS. Numerical experiments of resonance crossing, including spin dynamics in presence of the snakes and Q-jump, have been performed in AGS lattice models, using Zgoubi. This contribution reports on various results so obtained.

  18. Vocational Training in Germany: Modernisation and Responsiveness.

    ERIC Educational Resources Information Center

    Organisation for Economic Cooperation and Development, Paris (France).

    This volume presents a report on recent developments and current policy objectives in vocational education and training in Germany. The study is based on a conceptual and analytical framework jointly elaborated by the Organisation for Economic Cooperation and Development Secretariat and representatives of member countries. Part I is "The…

  19. Estimated burden of fungal infections in Germany.

    PubMed

    Ruhnke, Markus; Groll, Andreas H; Mayser, Peter; Ullmann, Andrew J; Mendling, Werner; Hof, Herbert; Denning, David W

    2015-10-01

    In the late 1980's, the incidence of invasive fungal diseases (IFDs) in Germany was estimated with 36.000 IFDs per year. The current number of fungal infections (FI) occurring each year in Germany is still not known. In the actual analysis, data on incidence of fungal infections in various patients groups at risk for FI were calculated and mostly estimated from various (mostly national) resources. According to the very heterogenous data resources robust data or statistics could not be obtained but preliminary estimations could be made and compared with data from other areas in the world using a deterministic model that has consistently been applied in many countries by the LIFE program ( www.LIFE-worldwide.org). In 2012, of the 80.52 million population (adults 64.47 million; 41.14 million female, 39.38 million male), 20% are children (0-14 years) and 16% of population are ≥65 years old. Using local data and literature estimates of the incidence or prevalence of fungal infections, about 9.6 million (12%) people in Germany suffer from a fungal infection each year. These figures are dominated (95%) by fungal skin disease and recurrent vulvo-vaginal candidosis. In general, considerable uncertainty surrounds the total numbers because IFDs do not belong to the list of reportable infectious diseases in Germany and most patients were not hospitalised because of the IFD but a distinct underlying disease.

  20. "Spiegeldorf": Nazi Appeals in Weimar Germany.

    ERIC Educational Resources Information Center

    Sprague, Gregory A.

    The paper discusses rationales for simulation gaming and describes "Spiegeldorf," a socio-historical game which simulates socioeconomic conditions in early 1930 Germany and Nazi party tactics used to gain mass support. Objectives are to identify characteristic Nazi tactics and points of political ideology, describe German social classes and their…

  1. Higher Education in Germany: Problems and Perspectives

    ERIC Educational Resources Information Center

    Kehm, Barbara

    2004-01-01

    The contribution focuses on the process of merging the East German system of higher education with that of West Germany in the context of German unification in 1990/91. The impact of German unification on East German higher education is described as consisting of five basic measures: (a) de-politicisation; (b) reorganisation and evaluation of…

  2. Germany Provides Higher Education without the Frills

    ERIC Educational Resources Information Center

    Labi, Aisha

    2009-01-01

    In Germany, tuition is low because state governments shoulder a much higher percentage of university budgets than in the United States. As a result, most German universities provide far fewer amenities and services, and require their professors to teach longer hours to larger numbers of students than their American counterparts. Because they are…

  3. The Scope of Sexual Victimization in Germany

    ERIC Educational Resources Information Center

    Kury, Helmut; Chouaf, Silvia; Obergfell-Fuchs, Joachim; Woessner, Gunda

    2004-01-01

    This study examined the sexual victimization of 309 female students in Germany. The results indicate that the majority of the subjects have been victims of minor offenses and that a minority of subjects was severely victimized. As to the relation of victim and perpetrator, the milder offenses are more likely to be committed by strangers. In…

  4. Playscapes of Germany--A Quick Tour

    ERIC Educational Resources Information Center

    Keeler, Rusty

    2006-01-01

    While playgrounds in many parts of the world are limited to "fixed" equipment and surfacing, certain progressive countries have made a point to rise above this dull standard and create playscapes filled with sculpture, gardens, and wild elements of the natural world. This article talks about the playscapes of Germany as leader in the world of…

  5. Language Science and Orientalism in Imperial Germany

    ERIC Educational Resources Information Center

    Kaplan, Judith R. H.

    2012-01-01

    This dissertation addresses a significant gap in the historiography of science: the nature of the language sciences as "science." Focusing on disciplinary and intellectual developments in the context of Imperial Germany (1871-1918), the project anticipates, complicates, and helps to explain a widely recognized theoretical shift, namely,…

  6. Perspectives of Financing Higher Education in Germany.

    ERIC Educational Resources Information Center

    Frackmann, Edgar

    1991-01-01

    The general structure of higher education finance in Germany and current and possible future developments in German higher education financing are analyzed. A shift from input budgeting to a more output-oriented steering of higher education is identified. Methods of dealing with the problems introduced by new mechanisms of decision making and fund…

  7. Mapping Music Education Research in Germany

    ERIC Educational Resources Information Center

    Gruhn, Wilfried

    2004-01-01

    This article presents a very general survey of tracks and trends in music education research in Germany and its roots in the 19th century, where the beginning of empirical music psychology can be traced back to "Tonpsychologie" and perception research of scholars such as Helmholtz, Stumpf, Wundt, and Wellek. Focus areas that are addressed in the…

  8. Is Germany a model for managers?

    PubMed

    Wever, K S; Allen, C S

    1992-01-01

    Most American managers have a hard time making sense of Germany. The country has a fraction of the resources and less than one-third the population of the United States. Labor costs are substantially higher, paid vacations are at least three times as long, and strong unions are deeply involved at all levels of business, from the local plant to the corporate boardroom. Yet German companies manage to produce internationally competitive products in key manufacturing sectors, making Germany the greatest competitive threat to the United States after Japan. The seemingly paradoxical nature of the German economy typically evokes one of two diametrically opposed responses. The first is to celebrate the German economy as a "model" worth emulating--indeed, as the answer to declining U.S. competitiveness. The alternative, more skeptical response is to question Germany's staying power in a new, more competitive global economy. According to Kirsten Wever and Christopher Allen, the problem with both points of view is that they miss the forest for the trees. Observers are so preoccupied with praising--or blaming--individual components of the German economy that they fail to see the dynamic logic that ties these components together into a coherent system. In their review of recent research on the German business system, Wever and Allen argue that managers can learn an important lesson from Germany. In the global economy, competition isn't just between companies but between entire socioeconomic systems. Germany's ability to design a cohesive economic and social system that adapts continuously to changing requirements goes a long way toward explaining that country's competitive success.

  9. Is Germany a model for managers?

    PubMed

    Wever, K S; Allen, C S

    1992-01-01

    Most American managers have a hard time making sense of Germany. The country has a fraction of the resources and less than one-third the population of the United States. Labor costs are substantially higher, paid vacations are at least three times as long, and strong unions are deeply involved at all levels of business, from the local plant to the corporate boardroom. Yet German companies manage to produce internationally competitive products in key manufacturing sectors, making Germany the greatest competitive threat to the United States after Japan. The seemingly paradoxical nature of the German economy typically evokes one of two diametrically opposed responses. The first is to celebrate the German economy as a "model" worth emulating--indeed, as the answer to declining U.S. competitiveness. The alternative, more skeptical response is to question Germany's staying power in a new, more competitive global economy. According to Kirsten Wever and Christopher Allen, the problem with both points of view is that they miss the forest for the trees. Observers are so preoccupied with praising--or blaming--individual components of the German economy that they fail to see the dynamic logic that ties these components together into a coherent system. In their review of recent research on the German business system, Wever and Allen argue that managers can learn an important lesson from Germany. In the global economy, competition isn't just between companies but between entire socioeconomic systems. Germany's ability to design a cohesive economic and social system that adapts continuously to changing requirements goes a long way toward explaining that country's competitive success. PMID:10121315

  10. Synthesis of Ag(2) S-Ag nanoprisms and their use as DNA hybridization probes.

    PubMed

    Liu, Bing; Ma, Zhanfang

    2011-06-01

    A simple synthetic route to prepare Ag(2) S-Ag nanoprisms consists of the facile addition of Na(2) S to a solution of triangular Ag nanoprisms. The resulting Ag(2) S-Ag nanoparticles are more stable in solution than the original Ag nanoprisms, and two surface plasmon resonance (SPR) bands of the original Ag nanoprisms still remain. In addition, the SPR bands of the Ag(2) S-Ag nanoprisms are tunable over a wide range. The Ag(2) S-Ag nanoprisms can be directly bioconjugated via well-established stable Ag(2) S surface chemistry with readily available sulfur coupling agents. The nanoprisms are used in the hybridization of functionalized oligonucleotides, and show promise as probes for future biosensing applications. PMID:21538868

  11. 48 CFR 252.229-7002 - Customs exemptions (Germany).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... (Germany). 252.229-7002 Section 252.229-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.229-7002 Customs exemptions (Germany). As prescribed in 229.402-70(b), use the following clause: Customs Exemptions (Germany) (JUN 1997) Imported products required for...

  12. 48 CFR 252.229-7002 - Customs exemptions (Germany).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... (Germany). 252.229-7002 Section 252.229-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.229-7002 Customs exemptions (Germany). As prescribed in 229.402-70(b), use the following clause: Customs Exemptions (Germany) (JUN 1997) Imported products required for...

  13. 48 CFR 252.229-7002 - Customs exemptions (Germany).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... (Germany). 252.229-7002 Section 252.229-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.229-7002 Customs exemptions (Germany). As prescribed in 229.402-70(b), use the following clause: Customs Exemptions (Germany) (JUN 1997) Imported products required for...

  14. 48 CFR 252.246-7002 - Warranty of construction (Germany).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... (Germany). 252.246-7002 Section 252.246-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.246-7002 Warranty of construction (Germany). As prescribed in 246.710(4), use the following clause: Warranty of Construction (Germany) (JUN 1997) (a) In addition to any...

  15. 48 CFR 252.246-7002 - Warranty of construction (Germany).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... (Germany). 252.246-7002 Section 252.246-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.246-7002 Warranty of construction (Germany). As prescribed in 246.710(2), use the following clause: Warranty of Construction (Germany) (JUN 1997) (a) In addition to any...

  16. 48 CFR 252.246-7002 - Warranty of construction (Germany).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... (Germany). 252.246-7002 Section 252.246-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.246-7002 Warranty of construction (Germany). As prescribed in 246.710(4), use the following clause: Warranty of Construction (Germany) (JUN 1997) (a) In addition to any...

  17. 48 CFR 252.246-7002 - Warranty of construction (Germany).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... (Germany). 252.246-7002 Section 252.246-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.246-7002 Warranty of construction (Germany). As prescribed in 246.710(4), use the following clause: Warranty of Construction (Germany) (JUN 1997) (a) In addition to any...

  18. 48 CFR 252.229-7002 - Customs exemptions (Germany).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... (Germany). 252.229-7002 Section 252.229-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.229-7002 Customs exemptions (Germany). As prescribed in 229.402-70(b), use the following clause: Customs Exemptions (Germany) (JUN 1997) Imported products required for...

  19. 48 CFR 252.246-7002 - Warranty of construction (Germany).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... (Germany). 252.246-7002 Section 252.246-7002 Federal Acquisition Regulations System DEFENSE ACQUISITION... of Provisions And Clauses 252.246-7002 Warranty of construction (Germany). As prescribed in 246.710(4), use the following clause: Warranty of Construction (Germany) (JUN 1997) (a) In addition to any...

  20. Education in Germany: A Bibliography of English Language Publications.

    ERIC Educational Resources Information Center

    Max-Planck-Institut fuer Bildungsforschung, Berlin (West Germany).

    This bibliography cites bibliographies, journals, books, essays, journal articles, and monographs on education in Germany. All publications cited are in English. The three major sections of the bibliography are education in Germany up to 1945, education in the Federal Republic of Germany, and education in the German Democratic Republic. Topics…

  1. Comprehensive Schools in Germany: Concepts, Developments and Issues.

    ERIC Educational Resources Information Center

    Mitter, Wolfgang

    1991-01-01

    A discussion of the status of the comprehensive secondary school in Germany looks at its history within the overall educational system, curriculum design, the relatively traditional approach taken by West Germany in comparison to other European countries, and the chances for comprehensive schools in a united Germany. (MSE)

  2. The Definition of Vocational Diplomas in Germany and France.

    ERIC Educational Resources Information Center

    Mobus, Martine; Verdier, Eric

    1997-01-01

    In both France and Germany, the government, employers' organizations, and unions all participate in defining vocational diplomas based on a national framework of procedures of elaborating and standardizing titles. Important differences between the diploma definition processes in France and Germany may be identified. In Germany, the issue is…

  3. Study of the oxygen transport through Ag (110), Ag (poly), and Ag 2.0 Zr

    NASA Technical Reports Server (NTRS)

    Outlaw, R. A.; Wu, D.; Davidson, M. R.; Hoflund, Gar B.

    1992-01-01

    The transport of oxygen through high-purity membranes of Ag (110), Ag (poly), Ag (nano), and Ag 2.0 Zr has been studied by an ultrahigh vacuum permeation method over the temperature range of 400-800 C. The data show that there are substantial deviations from ordinary diffusion-controlled transport. A surface limitation has been confirmed by glow-discharge studies where the upstream O2 supply has been partially converted to atoms, which, for the same temperature and pressure, gave rise to over an order of magnitude increase in transport flux. Further, the addition of 2.0 wt percent Zr to the Ag has provided increased dissociative adsorption rates, which, in turn, increased the transport flux by a factor of 2. It was also observed that below a temperature of 630 C, the diffusivity exhibits an increase in activation energy of over 4 kcal/mol, which has been attributed to trapping of the atomic oxygen and/or kinetic barriers at the surface and subsurface of the vacuum interface. Above 630 C, the activation barrier decreases to the accepted value of about 11 kcal/mol for Ag (poly), consistent with zero concentration at the vacuum interface.

  4. [Future supply of tuberculin in Germany].

    PubMed

    Sagebiel, D; Hauer, B; Haas, W; Magdorf, K; Priwitzer, M; Loddenkemper, R

    2005-04-01

    The manufacturers of the only tuberculin available up to now in Germany for intradermal TB tests according to Mantoux, Chiron Vaccines Behring, in 2004 unexpectedly stopped the production of the tuberculin Behring GT (GT="gereinigtes Tuberkulin"-purified protein derivative tuberculin). Only residual stocks were sold during the preceding months. The stocks of GT 10 were already depleted at the beginning of 2005, while there are small supplies left of GT 100 and GT 1000. As a temporary solution, Chiron Vaccines Behring is offering to import the Italian tuberculin Biocine PPD 5 IE lyophil produced by Chiron S.r.l. in Siena. As this is not licensed for sale in Germany, it is necessary to obtain an exceptional prescription (Einzelverordnung) according to section sign 73 (3) of the Federal Law Relating to the Manufacture and Distribution of Medicine (Arzneimittelgesetz, AMG). In the long term, Chiron Vaccines Behring plan to secure the supply of tuberculin in Germany by importing, starting in the summer of 2006, the tuberculin produced by Chiron Vaccines Evans in the UK (PPD Evans). However, these plans involve changing over to a different type of tuberculin twice within a very short period of time. Another problem is the unresolved issue of bioequivalence. Besides the above-mentioned tuberculins produced by Chiron Vaccines, a further possibility would be the import of the tuberculin PPD RT23 SSI of the Statens Serums Institute (Copenhagen/Denmark), which is recommended by the World Health Organization (WHO) as the standard tuberculin and which has already been introduced in several European countries, or of other tuberculins such as Tubersol (PPD CT68), which is used in the US. Together with the Robert Koch Institute (RKI) and the Paul Ehrlich Institute (PEI), the German Central Committee against Tuberculosis (DZK) is striving to find a solution, in view of the urgent need for an uninterrupted supply of tuberculin in Germany for diagnostic purposes and contact tracing

  5. AGS slow extracted beam improvement

    SciTech Connect

    Marneris, I.; Danowski, G.; Sandberg, J.; Soukas, A.

    1997-07-01

    The Brookhaven AGS is a strong focusing accelerator which is used to accelerate protons and various heavy ion species to an equivalent proton energy of 29 GeV. Since the late 1960`s it has been serving high energy physics (HEP - proton beam) users of both slow and fast extracted beams. The AGS fixed target program presently uses primary proton and heavy ion beams (HIP) in slowly extracted fashion over spill lengths of 1.5 to 4.0 seconds. Extraction is accomplished by flattoping the main and extraction magnets and exciting a third integer resonance in the AGS. Over the long spill times, control of the subharmonic amplitude components up to a frequency of 1 kilohertz is very crucial. One of the most critical contributions to spill modulation is due to the AGS MMPS. An active filter was developed to reduce these frequencies and it`s operation is described in a previous paper. However there are still frequency components in the 60-720 Hz sub-harmonic ripple range, modulating the spill structure due to extraction power supplies and any remaining structures on the AGS MMPS. A recent scheme is being developed to use the existing tune-trim control horizontal quadrupole magnets and power supply to further reduce these troublesome noise sources. Feedback from an external beam sensor and overcoming the limitations of the quadrupole system by lead/lag compensation techniques will be described.

  6. [Migrants of high social status in Germany].

    PubMed

    Glebe, G

    1997-01-01

    "The accelerating economic globalization has created a growing demand for highly skilled labourers. As a result, there has been an increase in highly skilled and high-status migrants to Germany, especially to the urban agglomerations with global city functions. This migration process is carried mostly by the internal labour and job movement of multinational companies. In the urban centres these groups of migrants follow specific patterns of spatial organization and segregation with regard to their place of residence. But they also have other distinctive difference to the migrants with a lower social status, such as higher social acceptance in their host country, the transitory character of their stay in Germany, and their intentions to return to their home countries." (EXCERPT) PMID:12294167

  7. [The reception of Heinz Kohut in Germany].

    PubMed

    Milch, Wolfgang

    2016-01-01

    First the discussion of Kohut's new ideas in the United States is sketched as a background. The response to these ideas was divided: on the one hand they were hailed as important innovations of psychoanalytic theory, and a circle of colleagues formed around their author; on the other hand they were violently rejected, and old friends distanced themselves from him. In Germany Kuhut's ideas were initially well received. His visits, lectures and supervisions resulted in a lively exchange and a number of friendships. When the differences between Kohutian and classical theory became evident this led increasingly to disillusionment and retreat. De-emphasizing drive and ego psychology had considerable consequences for psychoanalytic technique as well as for the analyst's Menschenbild, his relationship to the patient and his critical self-reflection. In Germany, too, a circle of colleagues emerged, following and elaborating the ideas of Kohut. PMID:27281981

  8. Salt fluoridation in Germany since 1991.

    PubMed

    Schulte, Andreas G

    2005-01-01

    Since 1991, fluoridated salt has been on sale in household-size packages in Germany. Potassium or sodium fluoride is added to iodized salt until the fluoride concentration reaches 250 mg/kg. The use of fluoridated salt to prevent caries is officially recommended by the Deutsche Gesellschaft für Zahn-, Mund- und Kieferheilkunde (DGZMK) and several other associations and groups interested in public health. In the course of the past thirteen years, the market share of fluoridated and iodized domestic salt rose to 63.1% in Germany. However, this positive development must not obscure the fact that fluoridated and iodized salt is still not allowed to be used in restaurant or cafeteria kitchens. This restriction now needs to be revoked in view of the fact that many children, adolescents and adults take their main meals in cafeterias or restaurants. Scientific studies have demonstrated beyond doubt that using fluoridated and iodized salt in cafeteria kitchens poses no problem whatever.

  9. Prevention among immigrants: the example of Germany

    PubMed Central

    2010-01-01

    Background A large and increasing part of the European population has a history of migration. Germany, for example, is home to about 15 million people with migrant background, which amounts to 19% of its population. Migrants may have differences in their lifestyle, health beliefs and risk factors compared to the autochthonous populations. Discussion As for example studies on children's participation in routine prevention activities have shown, these differences can have a relevant impact on the access of migrants to the health care system and are likely to lower their participation in prevention programs compared to the autochthonous population. To increase the uptake of prevention programs, barriers to access must be identified and approaches to reduce them must be developed. Summary Taking the example of Germany, a need exists for prevention programs that include (migrant sensitive) and specifically address (migrant specific) migrants. These should be of sufficient scale, evidence-based, sustainable and evaluated at regular intervals. PMID:20181232

  10. Ebola risk perception in Germany, 2014.

    PubMed

    Rübsamen, Nicole; Castell, Stefanie; Horn, Johannes; Karch, André; Ott, Jördis J; Raupach-Rosin, Heike; Zoch, Beate; Krause, Gérard; Mikolajczyk, Rafael T

    2015-06-01

    Ebola virus disease (EVD) outbreaks have occurred during the past 5 decades, but none has affected European countries like the 2014 epidemic in West Africa. We used an online questionnaire to investigate risk perceptions in Germany during this epidemic peak. Our questionnaire covered risk perceptions, knowledge about transmission routes, media use, reactions to the outbreak, attitudes toward measures to prevent the spread of EVD and vaccination against EVD, and willingness to volunteer for aid missions. Of 974 participants, 29% indicated that they worried about EVD, 4% correctly stated virus transmission routes, and 75% incorrectly rated airborne transmission and transmission by asymptomatic patients as possible. Many indicated that if a patient were flown to Germany for treatment in a nearby hospital, they would adapt preventive behavior. Although most participants were not worried about EVD at the current stage of the epidemic, misperceptions regarding transmission were common and could trigger inappropriate behavior changes.

  11. Topographies of forensic practice in Imperial Germany.

    PubMed

    Engstrom, Eric J

    2014-01-01

    This article examines the topography and "cultural machinery" of forensic jurisdictions in Imperial Germany. It locates the sites at which boundary disputes between psychiatric and legal professionals arose and explores the strategies and practices that governed the division of expert labor between them. It argues that the over-determined paradigms of 'medicalization' and 'biologization' have lost much of their explanatory force and that historians need to refocus their attention on the institutional and administrative configuration of forensic practices in Germany. After first sketching the statutory context of those practices, the article explores how contentious jurisdictional negotiations pitted various administrative, financial, public security, and scientific interests against one another. The article also assesses the contested status of psychiatric expertise in the courtroom, as well as post-graduate forensic psychiatric training courses and joint professional organizations, which drew the two professional communities closer together and mediated their jurisdictional disputes.

  12. Leptospirosis in Germany, 1962–2003

    PubMed Central

    Schöneberg, Irene; Frank, Christina; Alpers, Katharina; Schneider, Thomas; Stark, Klaus

    2005-01-01

    Epidemiologic trends of human leptospirosis in Germany were investigated by analyzing national surveillance data from 1962 to 2003 and by conducting a questionnaire-based survey from 1997 to 2000. After a steady decrease of leptospirosis incidence from 1962 to 1997, surveillance data indicate an increase in disease incidence to 0.06 per 100,000 (1998–2003). Of 102 laboratory-confirmed cases in humans from 1997 to 2000, 30% were related to occupational exposures. Recreational exposures were reported in 30% (including traveling abroad in 16%), whereas residential exposure accounted for 37% of the cases. Direct contact with animals, mostly rats and dogs, was observed in 31% of the cases. We conclude that recent changes in transmission patterns of leptospirosis, partially caused by an expanding rat population and the resurgence of canine leptospirosis, may facilitate the spread of the disease in temperate countries like Germany. Preventive measures should be adapted to the changing epidemiology of leptospirosis. PMID:16022779

  13. Epidemiology of Bluetongue Virus Serotype 8, Germany

    PubMed Central

    Gethmann, Jörn M.; Staubach, Christoph; Mettenleiter, Thomas C.; Beer, Martin; Hoffmann, Bernd

    2009-01-01

    In Germany, bluetongue disease had not been reported before 2006. During August 2006–August 2008, >24,000 bluetongue virus serotype 8 infections were reported, most (20,635) in 2007. In 2006 and 2007, respectively, case-fatality rates were 6.4% and 13.1% for cattle and 37.5% and 41.5% for sheep. Vaccination in 2008 decreased cases. PMID:19239757

  14. [Health conferences in Germany: an overview].

    PubMed

    Hollederer, A

    2015-03-01

    Health conferences are a special management instrument of health policy. Less is known about the distribution. There is a lack of systematic evaluation methods.This overview is based on comprehensive literature, data base and internet searches about health conferences in Germany.The establishment of structured conferences is derived from funding projects of the federal states or local initiatives which began in different phases and with various emphases. The strategies varied from individual actions to an implementation in the whole state. Currently there are altogether 130 health conferences in Germany for approximately one third of the county and city districts in 13 federal states. The federal states assist health conferences by providing financial support, health policy, support by health authorities and regulations in the law. In the majority of the cases the office is located within the public health service. There is a great diversity in the composition of the stakeholders and in the contents. A systematic monitoring and outcome evaluation was conducted only in a few cases. Those studies predominantly report positive results but also promoting and inhibiting factors. They referred to restrictions.Health conferences are broadly disseminated, especially in west Germany. They offer opportunities for a community health management. There is a need for more intensive exchange and evaluation to improve their development. PMID:24420647

  15. Regional Adaptation Strategies in Central Germany

    NASA Astrophysics Data System (ADS)

    Marx, Andreas

    2013-04-01

    Climate change presents a major challenge on international, national, and regional scale. It affects the scientific world as well as policymakers, representatives of economy, and the public. Consequently, the need for a dialogue between experts in climate change and the people affected is needed. However, structuring and communicating climate change information on the various scales is challenging and demands coordination. Within the Helmholtz community in Germany, four regional Helmholtz climate offices are founded. One of their major goals is to encourage the communication between science and public. Primarily, this is done by close cooperation to the Helmholtz research centers at which each climate office is hosted. Second, a continuous exchange is supported beyond the Helmholtz research centers towards universities and authorities at state and federal level. Each regional Helmholtz climate office represents regional aspects of climate related research based on the scientific expertise from the hosting Helmholtz research institutes. In the Climate Office for central Germany, Land use changes are among the most important factors of climate change driven environmental changes which have to be managed by the society in the next years. Since 1991 UFZ scientists research the causes and consequences of far-reaching environmental changes. The Climate Office offers information about climate change effects on the environmental compartments, land use strategies as well as regional strategies of adaptation. The three federal states in Central Germany (Saxony, Saxony-Anhalt and Thuringia) handle adaptation to climate change very differently. The presentation focusses on alikeness and differences in the adaptation process.

  16. Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors

    SciTech Connect

    Berkowitz, J.; Batson, C.H.; Goodman, G.L.

    1980-06-01

    He I photoelectron spectra of AgCl, AgBr and AgI vapors have been obtained which differ significantly from earlier work. In each instance, the characteristic features of the diatomic molecule are prominent. The spectral features separate into a valence region, predominantly halogen p-like, and a deeper region, predominantly of Ag 4d character. The latter is split by spin--orbit and ligand field interactions, which are parametrized from the experimental data. Relativistic calculations of the X/sub ..cap alpha../--DVM--SCC type have been performed for these species. At the transition state level, they agree very well with the experimental peak positions. Nonrelativistic calculations of this type have been performed for CuCl and cyclic Cu/sub 3/Cl/sub 3/. Unlike the AgX species, the CuCl and Cu/sub 3/Cl/sub 3/ exhibit strong mixing of metal d and halogen p orbitals for the uppermost occupied orbital, and other Cu 3d-like orbitals above the Cl 3p-like orbitals. It is suggested that the occurrence of Cu 3d orbitals in the valence region may play a role in the anomalous diagmagnetic signal and large conductivity changes of CuCl condensed from the vapor.

  17. The AGS Booster control system

    SciTech Connect

    Frankel, R.; Auerbach, E.; Culwick, B.; Clifford, T.; Mandell, S.; Mariotti, R.; Salwen, C.; Schumburg, N.

    1988-01-01

    Although moderate in size, the Booster construction project requires a comprehensive control system. There are three operational modes: as a high intensity proton injector for the AGS, as a heavy ion accelerator and injector supporting a wide range of ions and as a polarized proton storage injector. These requirements are met using a workstation based extension of the existing AGS control system. Since the Booster is joining a complex of existing accelerators, the new system will be capable of supporting multiuser operational scenarios. A short discussion of this system is discussed in this paper.

  18. AG Draconis - a symbiotic mystery

    NASA Astrophysics Data System (ADS)

    Galis, R.; Hric, L.; Smelcer, L.

    2015-02-01

    Symbiotic system AG Draconis regularly undergoes quiescent and active stages which consist of the series of individual outbursts. The period analysis of new and historical photometric data, as well as radial velocities, confirmed the presence of the two periods. The longer one (~550 d) is related to the orbital motion and the shorter one (~355 d) could be due to pulsation of the cool component of AG Dra. In addition, the active stages change distinctively, but the outbursts are repeated with periods from 359 - 375 d.

  19. Energy R and D in Germany

    SciTech Connect

    Runci, PJ

    1999-11-01

    Germany's total national (i.e., combined public and private sector) funding for R&D stood at $42 billion in 1997. The private sector accounted for nearly 62% ($24 billion) of the total, while the public sector accounted for approximately 38%. Since the late 1970s, when the public and private sectors each funded roughly half of Germany's R&D, the private sector has steadily assumed a larger and larger role as the dominant supporter of R&D activity, while overall government funding has remained essentially flat for much of the past two decades. In addition to declining relative to private R&D expenditures, public R&D expenditures in Germany declined by 4% in real terms between 1991 and 1997, to approximately $15 billion. The reduction in R&D investments in the public sector can be attributed in large part to the financial challenges associated with German reunification and related shifts in social priorities including efforts to address high unemployment and to rebuild basic infrastructure in the eastern states. R&D expenditures have also declined as a percentage of the total public budget, from a peak of 3.4% in 1985 to 2.7% in 1996. Energy R&D has been the hardest hit of all major socioeconomic areas of R&D expenditure funded by the German government. Between 1981 and 1997, public energy R&D fell from approximately $1.6 billion to $400 million--a 75% real decline. The $850 million reduction in Germany's fission R&D budget (which constituted two-thirds of government R&D investment in 1985) explains some 90% of the funding decline. Negative public perceptions regarding the safety and environmental impacts of nuclear energy have reduced nuclear power's viability as a long-term energy option for Germany. Discussions of a complete nuclear phaseout are now under way. At the same time, the German government has slashed its investments in fossil energy R&D by more than 90%. While energy efficiency and renewable energy technologies have fared relatively well in comparison

  20. Ag-Ag2S Hybrid Nanoprisms: Structural versus Plasmonic Evolution.

    PubMed

    Shahjamali, Mohammad M; Zhou, Yong; Zaraee, Negin; Xue, Can; Wu, Jinsong; Large, Nicolas; McGuirk, C Michael; Boey, Freddy; Dravid, Vinayak; Cui, Zhifeng; Schatz, George C; Mirkin, Chad A

    2016-05-24

    Recently, Ag-Ag2S hybrid nanostructures have attracted a great deal of attention due to their enhanced chemical and thermal stability, in addition to their morphology- and composition-dependent tunable local surface plasmon resonances. Although Ag-Ag2S nanostructures can be synthesized via sulfidation of as-prepared anisotropic Ag nanoparticles, this process is poorly understood, often leading to materials with anomalous compositions, sizes, and shapes and, consequently, optical properties. In this work, we use theory and experiment to investigate the structural and plasmonic evolution of Ag-Ag2S nanoprisms during the sulfidation of Ag precursors. The previously observed red-shifted extinction of the Ag-Ag2S hybrid nanoprism as sulfidation occurs contradicts theoretical predictions, indicating that the reaction does not just occur at the prism tips as previously speculated. Our experiments show that sulfidation can induce either blue or red shifts in the extinction of the dipole plasmon mode, depending on reaction conditions. By elucidating the correlation with the final structure and morphology of the synthesized Ag-Ag2S nanoprisms, we find that, depending on the reaction conditions, sulfidation occurs on the prism tips and/or the (111) surfaces, leading to a core(Ag)-anisotropic shell(Ag2S) prism nanostructure. Additionally, we demonstrate that the direction of the shift in the dipole plasmon is a function of the relative amounts of Ag2S at the prism tips and Ag2S shell thickness around the prism.

  1. Ag nanotubes and Ag/AgCl electrodes in nanoporous membranes

    NASA Astrophysics Data System (ADS)

    Davenport, Matthew; Healy, Ken; Siwy, Zuzanna S.

    2011-04-01

    Miniaturization of the entire experimental setup is a key requirement for widespread application of nanodevices. For nanopore biosensing, integrating electrodes onto the nanopore membrane and controlling the pore length is important for reducing the complexity and improving the sensitivity of the system. Here we present a method to achieve these goals, which relies on electroless plating to produce Ag nanotubes in track-etched polymer nanopore templates. By plating from one side only, we create a conductive nanotube that does not span the full length of the pore, and thus can act as a nanoelectrode located inside the nanopore. To give optimal electrochemical behavior for sensing, we coat the Ag nanotube with a layer of AgCl. We characterize the behavior of this nanoelectrode by measuring its current-voltage response and find that, in most cases, the response is asymmetric. The plated nanopores have initial diameters between 100 and 300 nm, thus a range suitable for detection of viruses.

  2. Photoreduction of Ag+ in Ag/Ag2S/Au memristor

    NASA Astrophysics Data System (ADS)

    Mou, N. I.; Tabib-Azar, M.

    2015-06-01

    Silver halides and chalcogenides are excellent memristor materials that have been extensively used in the past as photosensitive layers in photography. Here we examine the effect of illumination on the operating voltages and switching speed of Ag/Ag2S/Au memristors using a green laser (473-523 nm). Our results indicate that illumination decreases the average switching time from high to low resistance states by ∼19% and decreases the turn-off voltages dramatically from -0.8 V to -0.25 V that we attribute to the change in sulfur valency and a photo-induced change in its oxidation/reduction potential. Photo-induced reduction of silver in Ag2S may be used in three dimensional optical memories that can be electronically read and reset.

  3. Ag-Ag dispersive interaction and physical properties of Ag3Co(CN)6

    NASA Astrophysics Data System (ADS)

    Fang, Hong; Dove, Martin T.; Refson, Keith

    2014-08-01

    We report a density functional theory (DFT) study of Ag3Co(CN)6, a material noted for its colossal positive and negative thermal expansion, and its giant negative linear compressibility. Here, we explicitly include the dispersive interaction within the DFT calculation, and find that it is essential to reproduce the ground state, the high-pressure phase, and the phonons of this material, and hence essential to understand this material's remarkable physical properties. New exotic properties are predicted. These include heat enhancement of the negative linear compressibility, a large reduction in the coefficient of thermal expansion on compression with change of sign of the mode Grüneisen parameters under pressure, and large softening of the material on heating. Our results suggest that these are associated with the weak Ag-Ag dispersive interactions acting with an efficient hinging mechanism in the framework structure.

  4. Laser-based synthesis of core Ag-shell AgI nanoparticles

    NASA Astrophysics Data System (ADS)

    Tan, Hua; Fan, Wai Yip

    2005-05-01

    A laser-controlled synthesis of silver iodide (AgI) nanoparticles with isolable AgI shell-Ag core stable intermediates is achieved via molecular iodine photodissociation in the presence of pure Ag nanoparticles dispersed in water. Ag nanoparticles were introduced into the solution containing sodium dodecylsulphate surfactants and iodine by ablating a piece of silver foil with a 532 nm pulsed Nd-YAG laser. Transmission electron microscopy images showed that different AgI shell-Ag core sizes could be achieved by controlling the photolysis of I 2 in solution. These nanoparticles were also found to catalyse an atom-economy Grignard-Barbier organic reaction.

  5. AGS experiments: 1990, 1991, 1992. Ninth edition

    SciTech Connect

    Depken, J.C.

    1993-04-01

    This report contains a description of the following: AGS Experimental Area - High Energy Physics FY 1993 and Heavy Ion Physics FY 1993; Table of Beam Parameters and Fluxes; Experiment Schedule ``as run``; Proposed 1993 Schedule; A listing of experiments by number; Two-page summaries of each experiment begin here, also ordered by number; Publications of AGS Experiments; and List of AGS Experimenters.

  6. West Germany's first North Sea production due

    SciTech Connect

    Bleakley, W.B.

    1986-05-01

    Deutsche Texaco A.G. will be the first operator on behalf of itself and Wintershall A.G. to produce oil from the German sector of the North Sea, with its first oil due end of 1986 from the Mittelplate pilot project. Texaco also was the first to produce oil from the Baltic Sea when Schwedeneck-See field, near Kiel Bay, went on production last year. The pilot project at Mittelplate will yield more data on the reservoirs confirmed by four wells drilled in 1980-1981, and will be carried out in spite of adverse operating conditions. Problems facing Texaco engineers in their project design include: A mud-flat location dry at low tide but submerged at high tide. Efforts to convince environmental groups that no permanent harm would result from company activities. Shipment of low-gravity crude containing asphaltenes. Logistics of transporting equipment and supplies on a schedule dictated by tides.

  7. An efficient photocatalyst for degradation of various organic dyes: Ag@Ag2MoO4-AgBr composite.

    PubMed

    Bai, Yu-Yang; Lu, Yi; Liu, Jin-Ku

    2016-04-15

    The Ag2MoO4-AgBr composite was prepared by a facile in-situ anion-exchange method, then the Ag nanoparticles were coated on this composite through photodeposition route to form a novel Ag@Ag2MoO4-AgBr composite. The in-situ Br(-) replacement in a crystal lattice node position of Ag2MoO4 crystal allows for overcoming the resistance of electron transition effectively. Meanwhile silver nano-particles on the surface of Ag@Ag2MoO4-AgBr composite could act as electron traps to intensify the photogeneration electron-hole separation and the subsequent transfer of the trapped electron to the adsorbed O2 as an electron acceptor. As an efficient visible light catalyst, the Ag@Ag2MoO4-AgBr composite exhibited superior photocatalytic activity for the degradation of various organic dyes. The experimental results demonstrated superior photocatalytic rate of Ag@Ag2MoO4-AgBr composite compared to pure AgBr and Ag2MoO4 crystals (37.6% and 348.4% enhancement respectively). The Ag@Ag2MoO4-AgBr composite cloud degraded Rhodamin B, bromophenol blue, and amino black 10b completed in 7min. PMID:26775100

  8. An efficient photocatalyst for degradation of various organic dyes: Ag@Ag2MoO4-AgBr composite.

    PubMed

    Bai, Yu-Yang; Lu, Yi; Liu, Jin-Ku

    2016-04-15

    The Ag2MoO4-AgBr composite was prepared by a facile in-situ anion-exchange method, then the Ag nanoparticles were coated on this composite through photodeposition route to form a novel Ag@Ag2MoO4-AgBr composite. The in-situ Br(-) replacement in a crystal lattice node position of Ag2MoO4 crystal allows for overcoming the resistance of electron transition effectively. Meanwhile silver nano-particles on the surface of Ag@Ag2MoO4-AgBr composite could act as electron traps to intensify the photogeneration electron-hole separation and the subsequent transfer of the trapped electron to the adsorbed O2 as an electron acceptor. As an efficient visible light catalyst, the Ag@Ag2MoO4-AgBr composite exhibited superior photocatalytic activity for the degradation of various organic dyes. The experimental results demonstrated superior photocatalytic rate of Ag@Ag2MoO4-AgBr composite compared to pure AgBr and Ag2MoO4 crystals (37.6% and 348.4% enhancement respectively). The Ag@Ag2MoO4-AgBr composite cloud degraded Rhodamin B, bromophenol blue, and amino black 10b completed in 7min.

  9. AGS 20th anniversary celebration

    SciTech Connect

    Baggett, N.V.

    1980-05-22

    On May 22, 1980, a symposium was held at Brookhaven to celebrate the 20th birthday of the AGS, to recall its beginnings, and to review major discoveries that have been made with its beams. The talks at the symposium are recorded in this volume.

  10. AGS experiments: 1985, 1986, 1987

    SciTech Connect

    Depken, J.C.

    1987-01-01

    This report contains: Experimental areas layout, table of beam parameters and fluxes, experiment schedule ''as run,'' experiment long range schedule, a listing of experiments by number, two-page summaries of each experiment, also ordered by number, and publications of AGS experiments, 1982-1987.

  11. Correcting the AGS depolarizing resonances

    SciTech Connect

    Ratner, L.G.

    1986-01-01

    For the 1986 AGS run, the technique of correcting an imperfection resonance using a beat harmonic instead of the direct harmonic was applied and found to be useful in achieving a 22 GeV/c polarized beam. Both conventional and modified techniques are explained. (LEW)

  12. What Is Ag-Ed?

    ERIC Educational Resources Information Center

    Linley, Judy; Mylne, Lee

    1998-01-01

    Ag-Ed, an agricultural education project for upper elementary students, was held in conjunction with the Toowoomba Show in Queensland, Australia. Agriculture industry representatives provided 20 interactive agricultural presentations for class groups, which were supplemented with a teacher resource-package containing a directory and 13 sections of…

  13. AGS experiments, 1988, 1989, 1990

    SciTech Connect

    Depken, J.C.

    1991-04-01

    This report contains: experimental areas layout; table of beam parameters and fluxes; experiment schedule as run''; experiment long range schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS experiments; and list of experimenters.

  14. Antibacterial activity and reusability of CNT-Ag and GO-Ag nanocomposites

    NASA Astrophysics Data System (ADS)

    Kim, Ji Dang; Yun, Hyosuk; Kim, Gwui Cheol; Lee, Chul Won; Choi, Hyun Chul

    2013-10-01

    A facile approach to the synthesis of novel CNT-Ag and GO-Ag antibacterial materials, in which thiol groups are utilized as linkers to secure silver (Ag) nanoparticles to the CNT and GO surfaces without agglomeration, is reported. The resulting CNT-Ag and GO-Ag samples were characterized by performing TEM, XRD, Auger, XPS, and Raman measurements, which revealed that in these antibacterial materials size-similar and quasi-spherical Ag nanoparticles are anchored to the CNT and GO surfaces. The Ag nanoparticles in CNT-Ag and GO-Ag have narrow size distributions with average diameters of 2.6 and 3.5 nm respectively. The antibacterial activities of CNT-Ag and GO-Ag against Escherichia coli were assessed with the paper-disk diffusion method and by determining the minimal inhibitory concentrations (MICs). CNT-Ag was found to have higher antibacterial activity than the reference Ag colloid. Moreover, both CNT-Ag and GO-Ag retain more than 50% of their original antibacterial activities after 20 washes with detergent, which indicates their potential as antibacterial materials for laboratory and medical purposes.

  15. Comparative Study of Antimicrobial Activity of AgBr and Ag Nanoparticles (NPs)

    PubMed Central

    Suchomel, Petr; Kvitek, Libor; Panacek, Ales; Prucek, Robert; Hrbac, Jan; Vecerova, Renata; Zboril, Radek

    2015-01-01

    The diverse mechanism of antimicrobial activity of Ag and AgBr nanoparticles against gram-positive and gram-negative bacteria and also against several strains of candida was explored in this study. The AgBr nanoparticles (NPs) were prepared by simple precipitation of silver nitrate by potassium bromide in the presence of stabilizing polymers. The used polymers (PEG, PVP, PVA, and HEC) influence significantly the size of the prepared AgBr NPs dependently on the mode of interaction of polymer with Ag+ ions. Small NPs (diameter of about 60–70 nm) were formed in the presence of the polymer with low interaction as are PEG and HEC, the polymers which interact with Ag+ strongly produce nearly two times bigger NPs (120–130 nm). The prepared AgBr NPs were transformed to Ag NPs by the reduction using NaBH4. The sizes of the produced Ag NPs followed the same trends – the smallest NPs were produced in the presence of PEG and HEC polymers. Prepared AgBr and Ag NPs dispersions were tested for their biological activity. The obtained results of antimicrobial activity of AgBr and Ag NPs are discussed in terms of possible mechanism of the action of these NPs against tested microbial strains. The AgBr NPs are more effective against gram-negative bacteria and tested yeast strains while Ag NPs show the best antibacterial action against gram-positive bacteria strains. PMID:25781988

  16. Ethics-committee authorization in Germany.

    PubMed Central

    Graf, H P; Cole, D

    1995-01-01

    On 9 August 1994 the German legislature revised the German Drug Law (AMG). Included in the revision is a passage requiring, for the first time, that the sponsors and investigators of clinical studies involving human subjects first obtain the approval of an ethics committee before carrying out such studies. According to the legislation, which takes effect on 17 August 1995, approval is to come from 'an independent ethics committee, set up and administered according to state law [emphasis added]' (1). Although it is clear according to the text that the 16 federal states have been empowered to establish ethics committees within their jurisdictions, this does not mean that the state governments are free to transfer exclusive authority in the matter to their respective medical associations, a step that would effectively abolish Germany's private ethics committees. First, the legislation does not rule out the authorization of private ethics committees. Second, as legal scholars attest, the exclusive control of ethics committees by the medical associations would constitute an illegal monopoly. Third, it is arguable that medical-association ethics committees fail to meet the one prior federal requirement, that of independence. There is a great deal of confusion in Germany today about which kinds of ethics committees (public and/or private) the states will sanction before 17 August 1995. In an attempt to sort things out we present a brief explanation of how ther came to be two kinds of ethics committees in Germany, review the legal battle between the two over the issue of authorization, point out how the German legislature, in passing the recent bill, has missed an opportunity to clarify the issue and, finally suggest why the administration of ethics committees by the medical associations may be incompatible with the requirement that ethics committees be independent. PMID:7473643

  17. [Postoperative pain therapy in Germany. Status quo].

    PubMed

    Pogatzki-Zahn, E M; Meissner, W

    2015-10-01

    A great deal of progress has been made in the field of postoperative pain therapy in the last 20 years. Beginning from clinical trials on the effectiveness of individual procedures, such as epidural anesthesia and patient-controlled analgesia, a wide range of healthcare services research as well as basic research with human and animal experiments has been established. Whereas health services research in the 1980s and 1990s focused more on the implementation of acute pain services, outcome-oriented research approaches are nowadays the center of attention. Acute pain registries and pain certification projects initiated in Germany have to be mentioned particularly in this respect. Basic research papers from recent years increasingly address specific aspects of acute postoperative pain and have provided translational approaches that are applied around the world for studying neurobiological mechanisms of postoperative pain. At the same time, interdisciplinary cooperation in research projects has led to a better understanding of complex correlations regarding predictors and mechanisms (including psychosocial aspects) of acute and in recent times also chronic pain after surgery. In parallel, evidence-based medicine has found its way into acute pain medicine in Germany. In 2007, clinical acute pain therapy in Germany was enhanced by S3 level guidelines for the first time; however, the implementation is still incomplete. In future, questions concerning mechanism-based therapy of acute pain need to be equally in the center of attention of research, such as prevention of persisting pain after surgery and acute pain of different origins. PMID:26289394

  18. Decrease in major amputations in Germany.

    PubMed

    Santosa, Frans; Moysidis, Theodoros; Kanya, Susanne; Babadagi-Hardt, Zeynep; Luther, Bernd; Kröger, Knut

    2015-06-01

    A decrease in rate of amputation has been reported from many countries. This study aims to study the trends in amputation rates in Germany. On the basis of DRG-system, detailed lists of all amputations coded as minor amputations (OPS 5-864) and major amputations (OPS 5-865) performed between 2005 and 2010 were provided by the Federal Statistical Office. There was a significant decrease in age-adjusted major amputation rates per 100 000 population in Germany from 27·0 in 2005 to 22·9 in 2010 (15·2%, P ≪ 0·001) in males and from 19·7 in 2005 to 14·4 in 2010 (26·9%, P ≪ 0·001) in females. Overall, minor amputation rates did not show such a decrease but increased in males (from 47·4 in 2005 to 57·8 in 2010, 21·9%, P ≪ 0·001) and remained almost unchanged in females (23·1 in 2005 and 23·9 in 2010, not significant). Reduction in major amputation rates were even more pronounced in people above 80 years, especially in males from 216 to 150 (30·5%) and in females from 168 to 117 (30·4%). The present data demonstrate an increasing overall burden of foot lesions as indicated by an increase in incidence of minor amputations but an ongoing success in the fight against amputation, resulting in a significant decrease in major amputation rates in Germany, in the 6-year period from 2005 to 2010.

  19. Modeling closure of the Pd-Ag system in iron meteorites

    NASA Astrophysics Data System (ADS)

    Van Orman, J.; Matthes, M.; Fischer-Gödde, M.; Krawczynski, M. J.; Kleine, T.

    2015-12-01

    J.A. Van Orman1, M. Matthes2, M. Fischer-Godde2, M.J. Krawczynski3, T. Kleine21 Case Western Reserve University, Cleveland, OH 44106 (james.vanorman@case.edu) 2 Westfalische Wilhelms-Universitat Muenster, 48149 Muenster, Germany 3 Washington University, St. Louis, MO 63130 The short-lived Pd-107/Ag-107 system can provide constraints on the timing of assembly and cooling of iron meteorite parent bodies, but to interpret the dates derived from this system it is necessary to understand the closure conditions. Palladium is strongly enriched in the metal phases, and sulphide (troilite) is the primary sink for radiogenic silver. Closure of the system hence depends primarily on the transfer of Ag-107 from metal to troilite. Because cation diffusion in troilite is extremely rapid, Ag-107 transfer is likely to be controlled by diffusion through the metal. Sugiura and Hoshino (2003) estimated a closure temperature of ~1100 K for the Pd/Ag system in iron meteorites under the assumption that the diffusion rate of Ag in the metal is similar to that of Ni diffusion in taenite. Here we consider the problem in more detail, utilizing constraints on Ag diffusion in taenite and kamacite from the metallurgical literature to numerically model diffusive exchange between metal and troilite with simultaneous radiogenic ingrowth. The process is complicated by exsolution of the metal into bcc kamacite and fcc taenite phases during cooling. We will discuss approaches to the treatment of this issue and their influence on the derived closure temperatures. Sugiura N., Hoshino H. (2003) Meteorit. Planet. Sci. 38, 117-143.

  20. [Jewish veterinarians in Germany, 1918-1945].

    PubMed

    Möllers, G; Schaffer, J

    2005-10-01

    In 1998 there were only twelve Jewish veterinarians known who practised in Germany between 1918 and 1945. 133 of them have now been found. Most of the Jewish veterinarians had their roots in merchant families and were general practitioners in the countryside. To be "Jewish" did not concern until 1933. Compared with the other medical professionals like human medical professionals (10,9 %), in 1933 the number of Jewish veterinarians was low (1,6 %, whole German Jewish population 0,77 %). Right with the beginning of the National Socialistic rule Jewish veterinarians were exposed to different forms of harassment. Soon after, on April 7th 1933, with the so-called Gesetz zur Wiederherstellung des Berufsbeamtentums (BBG; law for the restoration of civil service), the prosecution took on an official quality. The Reichstierärztekammer (Chamber of veterinary service) was very eager to Aryanize the German veterinary service. The BBG made the Jewish veterinarians who worked in public positions lose their jobs with the single exception of those who had the status of a so-called "Frontkämpfer" (a soldier who fought at the frontline during World War I). Many of the Jewish veterinarians who were still in Germany in November 1938 were arrested after the pogrom of November 9/10th and kept in concentration camps and prisons for about one month. The few students of veterinary medicine who already had started their studies in 1933 still could make their exams in Germany, but they did not get a licence. On January 31st 1939 all Jewish veterinarians in Germany lost their licence. 55 Jewish vets managed to emigrate in time. Nineteen German Jewish Veterinarians died in concentration camps and ghettos. Two are known to have committed suicide. Until 1997, there was no act of appreciation or rehabilitation of German Jewish veterinarians. In 2003 the degrees of two Jewish veterinarians, Hermann Cussel and Paul Stern, were renewed posthumously by the Hanover School of Veterinary Medicine

  1. Ontogeny recapitulates phylogeny: comparative immunology in Germany.

    PubMed

    Cooper, E L; Bosch, T C

    2000-01-01

    The innate immune system is in the spot light of modern immunology. Whenever protists, invertebrates and vertebrates are threatened by pathogens, they rapidly activate highly effective antimicrobial defense reactions. Because this young field develops very dynamically, it is important to ask what we really know about the mechanisms governing the innate immune defense system. This was the topic of a recent meeting entitled 'The Evolution of the Immune System', held at the Friedrich Schiller University in Jena, Germany. Leading scientists in the field of innate immunity presented their latest data in a historical and friendly setting.

  2. Fatal dengue hemorrhagic fever imported into Germany.

    PubMed

    Schmidt-Chanasit, J; Tenner-Racz, K; Poppert, D; Emmerich, P; Frank, C; Dinges, C; Penning, R; Nerlich, A; Racz, P; Günther, S

    2012-08-01

    Dengue virus (DENV) is an arthropod-borne virus (family Flaviviridae) causing dengue fever or dengue hemorrhagic fever. Here, we report the first fatal DENV infection imported into Germany. A female traveler was hospitalized with fever and abdominal pain after returning from Ecuador. Due to a suspected acute acalculous cholecystitis, cholecystectomy was performed. After cholecystectomy, severe spontaneous bleeding from the abdominal wound occurred and the patient died. Postmortem analysis of transudate and tissue demonstrated a DENV secondary infection of the patient and a gallbladder wall thickening (GBWT) due to an extensive edema.

  3. Photostimulated Luminescence and Dynamics of AgI and Ag Nanoclusters in Zeolites

    SciTech Connect

    Chen, Wei; Joly, Alan G.; Roark, Joel

    2002-06-15

    The photoluminescence and photostimulated luminescence of Ag and AgI nanoclusters formed in zeolite-Y are studied using fluorescence spectroscopy. The photoluminescence spectra of AgI nanoclusters show emission from both AgI and Ag nanoclusters, while the in the photostimulated luminescence, only the emission of Ag clusters is observed. While the photoluminescence from both Ag and AgI particles displays both sub-nanosecond and microsecond lifetimes, the emission from photostimulated luminescence shows very short, picosecond lifetimes. A model which ascribes the photostimulated luminescence to recombination of electrons trapped in the zeolite with Ag in close proximity to the trap site is proposed. The appearance of strong photostimulated luminescence with short decays in these systems demonstrates that nanoparticles have potential for digital storage and medical radiology applications.

  4. Chemically-inactive interfaces in thin film Ag/AgI systems for resistive switching memories

    PubMed Central

    Cho, Deok-Yong; Tappertzhofen, Stefan; Waser, Rainer; Valov, Ilia

    2013-01-01

    AgI nanoionics-based resistive switching memories were studied in respect to chemical stability of the Ag/AgI interface using x-ray absorption spectroscopy. The apparent dissolution of Ag films of thickness below some tens of nanometers and the loss of electrode/electrolyte contact was critically addressed. The results evidently show that there are no chemical interactions at the interface despite the high ionic mobility of Ag ions. Simulation results further show that Ag metal clusters can form in the AgI layer with intermediate-range order at least up to next-next nearest neighbors, suggesting that Ag can permeate into the AgI only in an aggregated form of metal crystallite. PMID:23378904

  5. Environmental medicine in Germany--a review.

    PubMed Central

    Seidel, Hans Joachim

    2002-01-01

    In this review I describe the development of environmental medicine as a specialized field of clinical medicine in Germany. New scientific societies were founded, based on traditions of public hygiene and occupational medicine, as a reaction to environmental issues concerning human health. Environmental medicine issues were also addressed by independent "critical" physicians. The first institutions to accept patients were centers for environmental medicine affiliated with research institutions and/or with the public health service. Medical professional organizations, particularly the German General Medical Council, described the need for and formulated conditions for additional qualification for doctors in environmental medicine, including a 200-hr course. This course and a qualifying exam were passed by about 3,000 doctors, mainly from the public health service and from occupational medicine. Unfortunately, few general physicians in primary outpatient care were similarly trained. To date, no representative study has been conducted on environmental patients, but I include in this review a typical list of patients' complaints. I also summarize research activities typical for environmental medicine in Germany. Present problems concern accounting systems and, for example, diagnosis and treatment of patients with multiple chemical sensitivities (MCS). A coordinated research program on MCS has been started. PMID:11834469

  6. [Children-orientated tobacco advertising in Germany].

    PubMed

    Pumpe, K

    2002-04-01

    Since 1990 the percentage of smokers among the 12 to 17-year-olds in Germany has risen from 21 % to about 28 %. Most of them start between the age of 11 and 13. 85 % favour a certain brand by the age of 18. Despite the prohibition of tobacco commercials on radio and TV the cigarette industry has continually increased their budget for advertising aimed more and more at women and children. According to the author's knowledge, this report describes for the first time the strategies most frequently applied in Germany to incite children and teenagers to smoking. The publicity campaigns are not restricted to billboards and the printed press, but use the internet also. Indirect conditioning to a certain brand by music videos, movies and merchandising of attractive clothes and trips as well as the sponsoring of special music and sports events are also shown.The report analyses and evaluates examples of messages in printed advertisements aimed at children. With psychological skill interest in smoking is created with teenagers and a conditioning for smoking in certain situations is promoted. PMID:11951159

  7. [Children-orientated tobacco advertising in Germany].

    PubMed

    Pumpe, K

    2002-04-01

    Since 1990 the percentage of smokers among the 12 to 17-year-olds in Germany has risen from 21 % to about 28 %. Most of them start between the age of 11 and 13. 85 % favour a certain brand by the age of 18. Despite the prohibition of tobacco commercials on radio and TV the cigarette industry has continually increased their budget for advertising aimed more and more at women and children. According to the author's knowledge, this report describes for the first time the strategies most frequently applied in Germany to incite children and teenagers to smoking. The publicity campaigns are not restricted to billboards and the printed press, but use the internet also. Indirect conditioning to a certain brand by music videos, movies and merchandising of attractive clothes and trips as well as the sponsoring of special music and sports events are also shown.The report analyses and evaluates examples of messages in printed advertisements aimed at children. With psychological skill interest in smoking is created with teenagers and a conditioning for smoking in certain situations is promoted.

  8. Status of wind energy in Germany

    SciTech Connect

    Gerdes, G.; Molly, J.P.; Rehfeldt, K.

    1996-12-31

    By the end of 1995 in total 3655 wind turbines (WT`s) were installed in Germany with a total capacity of 1,136 MW. In the year 1995 alone the WT installations grew by 1,070 units with 505 MW. About 40% of the 1995 installations were sold to inland states of Germany with their lower wind speed potential. This fast development occurred in parallel to continuously reduced local state and federal subsidies. The further development is based mainly on the guaranteed reimbursement due to the Electricity Feed Law. But since some time the electricity utilities fight back on all legal and political levels to get cancelled the unloved Electricity Feed Law and since two years the building construction law with the foreseen privilege for WT`s is discussed without any result. All these difficulties affect investors and credit giving banks in such a negative way, that the further annual increase in wind power installation for 1996 could be 10 to 20% less than in 1995. Many of the new commercial Megawatt WT`s have pitch control and variable rotor speed which cause better electrical power quality and lower life time loads. From statistical evaluations on technical data of WT`s a good overview of the further development is derived. 8 refs., 10 figs.

  9. [Cervical cancer screening in Germany. Current status].

    PubMed

    Schneider, V

    2012-07-01

    Cervical cancer screening was introduced in Germany 40 years ago and the incidence of cancer of the cervix has subsequently decreased by close to 70%. The remaining incidence of 5,600 cases per year represents only 2.8% of all newly occurring cases of cancer in women and these cases occur mainly in patients who do not participate in regular screening. Thus, cervical cancer screening by cytological smears has been proven to be successful. The structure of the German cancer screening program is characterized by decentralized organization, exclusive involvement of medical specialists such as gynecologists and pathologists and strict quality assurance. The recruitment is 50% on a yearly basis and the cumulative participation over 3 years reaches 79%. Since 2008 all laboratories are required to report complete data sets to local quality control agencies.The Joint Federal Committee in charge of evaluating new technologies in Germany mandated an inquiry into the possible role of screening by human papillomavirus (HPV) testing. According to this report published by the Institute for Quality Assurance and Efficiency in Healthcare there are indications for advantages. There are, however, no data in the literature as to possible disadvantages of HPV testing. A similar study for the US Preventive Services Task Force was published in May 2011 with almost identical conclusions.

  10. Performance evaluation of on-site oral fluid drug screening devices in normal police procedure in Germany.

    PubMed

    Musshoff, Frank; Hokamp, Eva Große; Bott, Ulrich; Madea, Burkhard

    2014-05-01

    There is a need for quick and reliable methods for rapid screening of drug-influenced drivers on the roadside by police. Because the window of detection in oral fluid is more similar to blood than to urine, this matrix should therefore be appropriate for screening procedures. The performance of the Rapid STAT(®) (Mavand Solution GmbH, Mössingen, Germany), DrugWipe5/5+(®) (Securetec Detektions-Systeme AG, Brunnthal, Germany) and Dräger DrugTest(®) 5000 (Draeger Safety AG & Co. KGaA, Luebeck, Germany) on-site oral fluid devices was evaluated with random oral fluid specimens from car drivers in North Rhine-Westphalia (Germany). Additionally, some drivers were checked using an on-site urine device (DrugScreen(®), NAL von Minden, Regensburg, Germany). During a 11-month period, 1.212 drivers were tested. Both OF and urine on-site tests were compared to serum results. The following sensitivities were obtained by the oral fluid devices: THC 71% (DrugWipe(®)), 87% (Dräger), 91% (RapidSTAT); opiates 95% (Dräger), 100% (DrugWipe(®), RapidSTAT(®)); amphetamine 84% (DrugTest(®) 5000), 90% (RapidSTAT(®)), 100% (DrugTest(®) 5000); methamphetamine 50% (DrugTest(®) 5000), 100% (RapidSTAT(®)); cocaine 76% (DrugTest(®) 5000), 100% (DrugWipe(®), RapidSTAT(®)); methadone 33-63%, and benzodiazepines 0-33% (both with a low number of positives). THC specificity was especially low (29% [DrugWipe(®)] and 47% [DrugTest(®) 5000]) due to low cut-off concentrations. These data were similar to those obtained from the literature (e.g., DRUID project). The urine screening device showed a good sensitivity (THC 93%, opiate 94%, amphetamine 94%, methamphetamine 75% (low number of positives), cocaine 100%) and also an acceptable specificity (39%, 86%, 63%, 77%, 47%, respectively). Although oral fluid may be a useful matrix for on-site testing of drugged drivers, it is evident that oral fluid devices still show a lack of sensitivity (methamphetamine, benzodiazepines) and

  11. Substitution treatment for opioid addicts in Germany

    PubMed Central

    Michels, Ingo Ilja; Stöver, Heino; Gerlach, Ralf

    2007-01-01

    Background After a long and controversial debate methadone maintenance treatment (MMT) was first introduced in Germany in 1987. The number of patients in MMT – first low because of strict admission criteria – increased considerably since the 1990s up to some 65,000 at the end of 2006. In Germany each general practitioner (GP), who has completed an additional training in addiction medicine, is allowed to prescribe substitution drugs to opioid dependent patients. Currently 2,700 GPs prescribe substitution drugs. Psychosocial care should be made available to all MMT patients. Results The results of research studies and practical experiences clearly indicate that patients benefit substantially from MMT with improvements in physical and psychological health. MMT proves successful in attaining high retention rates (65 % to 85 % in the first years, up to 50 % after more than seven years) and plays a major role in accessing and maintaining ongoing medical treatment for HIV and hepatitis. MMT is also seen as a vital factor in the process of social re-integration and it contributes to the reduction of drug related harms such as mortality and morbidity and to the prevention of infectious diseases. Some 10 % of MMT patients become drug-free in the long run. Methadone is the most commonly prescribed substitution medication in Germany, although buprenorphine is attaining rising importance. Access to MMT in rural areas is very patchy and still constitutes a problem. There are only few employment opportunities for patients participating in MMT, although regular employment is considered unanimously as a positive factor of treatment success. Substitution treatment in German prisons is heterogeneous in access and treatment modalities. Access is very patchy and the number of inmates in treatment is limited. Nevertheless, substitution treatment plays a substantial part in the health care system provided to drug users in Germany. Conclusion In Germany, a history of substitution

  12. Ag diffusion in cubic silicon carbide

    NASA Astrophysics Data System (ADS)

    Shrader, David; Khalil, Sarah M.; Gerczak, Tyler; Allen, Todd R.; Heim, Andrew J.; Szlufarska, Izabela; Morgan, Dane

    2011-01-01

    The diffusion of Ag impurities in bulk 3C-SiC is studied using ab initio methods based on density functional theory. This work is motivated by the desire to reduce transport of radioactive Ag isotopes through the SiC boundary layer in the Tristructural-Isotropic (TRISO) fuel pellet, which is a significant concern for the Very High Temperature Reactor (VHTR) nuclear reactor concept. The structure and stability of charged Ag and Ag-vacancy clusters in SiC are calculated. Relevant intrinsic SiC defect energies are also determined. The most stable state for the Ag impurity in SiC is found to be a Ag atom substituting on the Si sub-lattice and bound to a C vacancy. Bulk diffusion coefficients are estimated for different impurity states and values are all found to have very high activation energy. The impurity state with the lowest activation energy for diffusion is found to be the Ag interstitial, with an activation energy of approximately 7.9 eV. The high activation energies for Ag diffusion in bulk 3C-SiC cause Ag transport to be very slow in the bulk and suggests that observed Ag transport in this material is due to an alternative mechanism (e.g., grain boundary diffusion).

  13. Establishment of the Certification System "Gynaecological Dysplasia" in Germany.

    PubMed

    Beckmann, M W; Quaas, J; Bischofberger, A; Kämmerle, A; Lux, M P; Wesselmann, S

    2014-09-01

    Gynaecological cancer centres have been established nationwide in Germany since 2008 according to the certification system of the German Cancer Society (Deutsche Krebsgesellschaft e. V. [DKG]) and the German Society for Gynaecology and Obstetrics (Deutsche Gesellschaft für Gynäkologie und Geburtshilfe e. V. [DGGG]). However, patient access to the certified gynaecological cancer centres is currently only possible through direct referrals. A longitudinal structure with the corresponding long-term documentation of both the high-grade precursors as well as the cancers does not exist as yet. According to the aims of the National Cancer Plan, a corresponding structure for the cancer entity "cervix carcinoma" should be established. The foundations for such a structure are appropriate diagnostic units that are responsible, after nationwide screening, for clarification according to guideline-conform principles. On the basis of the vote of the certification commission for gynaecological cancer centres under the chairmanship of the DKG, the Working Group for Gynaecological Oncology (Arbeitsgemeinschaft Gynäkologische Onkologie e. V. [AGO]), the Committee on Cervical Pathology and Colposcopy (Arbeitsgemeinschaft Zervixpathologie & Kolposkopie [AG-CPC]) and the DGGG the certification system for gynaecological dysplasia has been established. As a general principle, a distinction is made between the certification of a consulting practice for gynaecological dysplasia and a gynaecological dysplasia facility in order to integrate both outpatient and inpatient health-care facilities into the certification system. In analogy to the further catalogue of requirements from the DKG, quantitative and qualitative minimum numbers are demanded. Furthermore, the requirements of the certification process include a summary of patient information, the applied guidelines, continuing and further training, interdisciplinary cooperation in tumour boards, contents or, respectively, procedure

  14. Capacitive deionization of seawater effected by nano Ag and Ag@C on graphene.

    PubMed

    Cai, P-F; Su, C-J; Chang, W-T; Chang, F-C; Peng, C-Y; Sun, I-W; Wei, Y-L; Jou, C-J; Wang, H Paul

    2014-08-30

    Drinking water shortage has become worse in recent decades. A new capacitive deionization (CDI) method for increasing water supplies through the effective desalination of seawater has been developed. Silver as nano Ag and Ag@C which was prepared by carbonization of the Ag(+)-β-cyclodextrin complex at 573 K for 30 min can add the antimicrobial function into the CDI process. The Ag@C and Ag nanoparticles dispersed on reduced graphene oxide (Ag@C/rGO and nano Ag/rGO) were used as the CDI electrodes. The nano Ag/rGO and Ag@C/rGO electrodes can reduce the charging resistant, and enhance the electrosorption capability. Better CDI efficiencies with the nano Ag/rGO and Ag@C/rGO electrodes can therefore be obtained. When reversed the voltage, the electrodes can be recovered up to 90% within 5 min. This work presents the feasibility for the nano Ag and Ag@C on rGO electrodes applied in CDI process to produce drinking water from seawater or saline water.

  15. Ag/AgBr/TiO2 visible light photocatalyst for destruction of azodyes and bacteria.

    PubMed

    Hu, Chun; Lan, Yongqing; Qu, Jiuhui; Hu, Xuexiang; Wang, Aimin

    2006-03-01

    Ag/AgBr/TiO2 was prepared by the deposition-precipitation method and was found to be a novel visible light driven photocatalyst. The catalyst showed high efficiency for the degradation of nonbiodegradable azodyes and the killing of Escherichia coli under visible light irradiation (lambda>420 nm). The catalyst activity was maintained effectively after successive cyclic experiments under UV or visible light irradiation without the destruction of AgBr. On the basis of the characterization of X-ray diffraction, X-ray photoelectron spectroscopy, and Auger electron spectroscopy, the surface Ag species mainly exist as Ag0 in the structure of all samples before and after reaction, and Ag0 species scavenged hVB+ and then trapped eCB- in the process of photocatalytic reaction, inhibiting the decomposition of AgBr. The studies of ESR and H2O2 formation revealed that *OH and O2*- were formed in visible light irradiated aqueous Ag/AgBr/TiO2 suspension, while there was no reactive oxygen species in the visible light irradiated Ag0/TiO2 system. The results indicate that AgBr is the main photoactive species for the destruction of azodyes and bacteria under visible light. In addition, the bactericidal efficiency and killing mechanism of Ag/AgBr/TiO2 under visible light irradiation are illustrated and discussed. PMID:16509698

  16. Capacitive deionization of seawater effected by nano Ag and Ag@C on graphene.

    PubMed

    Cai, P-F; Su, C-J; Chang, W-T; Chang, F-C; Peng, C-Y; Sun, I-W; Wei, Y-L; Jou, C-J; Wang, H Paul

    2014-08-30

    Drinking water shortage has become worse in recent decades. A new capacitive deionization (CDI) method for increasing water supplies through the effective desalination of seawater has been developed. Silver as nano Ag and Ag@C which was prepared by carbonization of the Ag(+)-β-cyclodextrin complex at 573 K for 30 min can add the antimicrobial function into the CDI process. The Ag@C and Ag nanoparticles dispersed on reduced graphene oxide (Ag@C/rGO and nano Ag/rGO) were used as the CDI electrodes. The nano Ag/rGO and Ag@C/rGO electrodes can reduce the charging resistant, and enhance the electrosorption capability. Better CDI efficiencies with the nano Ag/rGO and Ag@C/rGO electrodes can therefore be obtained. When reversed the voltage, the electrodes can be recovered up to 90% within 5 min. This work presents the feasibility for the nano Ag and Ag@C on rGO electrodes applied in CDI process to produce drinking water from seawater or saline water. PMID:24928455

  17. Muslim-Turkish Children in Germany: Sociocultural Problems.

    ERIC Educational Resources Information Center

    Onder, Zehra

    1996-01-01

    The sociocultural problems of Turkish children living in Germany are explored. Turkish immigrant children in Germany must be socialized in two societies, the traditional Turkish culture of their parents and that of German society. Religion and the Islamic-value system are often at odds with German values. (SLD)

  18. The paradigm shift in cervical cancer screening in Germany.

    PubMed

    Hillemanns, Peter

    2016-01-01

    With the adoption of the Cancer Screening and Registration Law (KFRG, 2013) based on the National Cancer Plan, the so far opportunistic cervical cancer screening in Germany is to be converted to an organized screening program. This decision in Germany is consistent with the new EU Guidelines and, in anticipation of the upcoming German S3 guideline for cervical cancer screening.

  19. Educational Systems and Rising Inequality: Eastern Germany after Unification

    ERIC Educational Resources Information Center

    von Below, Susanne; Powell, Justin J. W.; Roberts, Lance W.

    2013-01-01

    Educational systems considerably influence educational opportunities and the resulting social inequalities. Contrasting institutional regulations of both structures and contents, the authors present a typology of educational system types in Germany to analyze their effects on social inequality in eastern Germany after unification. After 1990, the…

  20. National Student Governance in Germany: The Case of fzs

    ERIC Educational Resources Information Center

    Jungblut, Jens; Weber, Regina

    2012-01-01

    This article analyzes the organizational development of freier zusammenschluss von studentInnenschaften (fzs), the national union of students in Germany from its foundation until 2010. It situates it within the variety of student organizations acting on behalf of students within the multi-level system of higher education governance in Germany.…

  1. Labor, Business, and Change in Germany and the United States.

    ERIC Educational Resources Information Center

    Wever, Kirsten S., Ed.

    This book explores how two nations with widely divergent political economies, Germany and the United States (U.S.), embraced change in four contemporary settings. "Mutual Learning with Trade-Offs" (Kirsten Wever) discusses mutual learning and the distinguishing characteristics of the political economies of Germany and the U.S. "Deregulation and…

  2. Training and Further Training in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Pakleppa, Hans

    The Federal Republic of Germany uses its development aid policy to support the growth of manpower resources in developing countries by means of a broad spectrum of training and further training programs of foreign specialists. In planning these programs and arranging scholarships, Germany tries to orient itself toward the educational policy…

  3. An American Social Worker in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Hill, Paul, Jr.

    This report resulted from a 14-day Study Tour for American Experts in Youth Work arranged and financed by the Federal Republic of Germany Ministry for Youth, Family and Health which provided American youth workers with an opportunity to study the youth services structure and culture of West Germany. The structure of the West German Ministry for…

  4. 48 CFR 252.229-7002 - Customs exemptions (Germany).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... direct benefit of the United States Forces are authorized to be acquired duty-free by the Contractor in accordance with the provisions of the Agreement Between the United States of America and Germany Concerning Tax Relief to be Accorded by Germany to United States Expenditures in the Interest of Common...

  5. Multidrug-Resistant Acinetobacter baumannii in Veterinary Clinics, Germany

    PubMed Central

    Prenger-Berninghoff, Ellen; Weiss, Reinhard; van der Reijden, Tanny; van den Broek, Peterhans; Baljer, Georg; Dijkshoorn, Lenie

    2011-01-01

    An increase in prevalence of multidrug-resistant Acinetobacter spp. in hospitalized animals was observed at the Justus-Liebig-University (Germany). Genotypic analysis of 56 isolates during 2000–2008 showed 3 clusters that corresponded to European clones I–III. Results indicate spread of genotypically related strains within and among veterinary clinics in Germany. PMID:21888812

  6. Bullying Involvement of Korean Children in Germany and in Korea

    ERIC Educational Resources Information Center

    Bae, Hwa-ok

    2016-01-01

    This study compared bullying involvement of Korean or Korean-German children living in Germany with children in Korea, and examined children's perceptions of school environment associated with bullying involvement of the children. This study included 105 Korean or Korean-German children living in the Bayern State of Germany as the study sample and…

  7. The Search for Specialists and Managers. Staff Shortage in Germany.

    ERIC Educational Resources Information Center

    Stahl, Klaus, Ed.

    1999-01-01

    Despite its high unemployment level, Germany is experiencing a shortage of specialists and managers. Germany's need for highly qualified information technology (IT) workers and engineers is particularly great. Approximately 10,000 posts for computer scientists and IT specialists remained vacant in 1998. Because of the shortage of such specialists,…

  8. Racialised Norms in Apprenticeship Systems in England and Germany

    ERIC Educational Resources Information Center

    Chadderton, Charlotte; Wischmann, Anke

    2014-01-01

    In this paper, we consider the issue of the under-representation of young people from minority ethnic/migrant backgrounds in apprenticeships in England and Germany. Whilst there are many studies on apprenticeships in England and Germany, few focus on under-representation or discrimination, even fewer on ethnic under-representation, and there are…

  9. An Active Old Age--Senior Citizens in Germany.

    ERIC Educational Resources Information Center

    Metzler, Birgit

    1998-01-01

    Life expectancies are rising all over the world, leading to higher proportions of older adults in the population. This is especially true in Japan and Germany. In Germany today, "old" no longer means necessarily "poor and frail." Through volunteer work, lifelong learning, study tours, and participation in sports, older Germans are changing the…

  10. The Great Drama: Germany and the French Revolution.

    ERIC Educational Resources Information Center

    Kurz, Gerhard

    Revolution did not spread to Germany from France at the end of the 18th century, yet the German and other European states were forced to come to terms with the principles of the French Revolution such as political and legal freedoms and national unity. Germany was affected by the French Revolution particularly by the reactions of German…

  11. OECD Review of Career Guidance Policies. Germany: Country Note.

    ERIC Educational Resources Information Center

    Organisation for Economic Cooperation and Development, Paris (France).

    Germany's career guidance system and policies were evaluated. Data were collected through meetings with policymakers and guidance practitioners in the public and private sectors, an analysis of data from a national questionnaire, and a review of pertinent documentation. The evaluation focused on the following areas: reviewing the role of Germany's…

  12. Facile synthesis of S-Ag nanocomposites and Ag2S short nanorods by the interaction of sulfur with AgNO3 in PEG400

    NASA Astrophysics Data System (ADS)

    Zhang, Yan-Li; Xie, Xin-Yuan; Liang, Ming; Xie, Shu-Ming; Chen, Jie-Mei; Zheng, Wen-Jie

    2016-06-01

    A facile, eco-friendly and inexpensive method to prepare Ag2S short nanorods and S-Ag nanocomposites using sublimed sulfur, AgNO3, PVP and PEG400 was studied. According to x-ray diffraction and scanning electron microscopy of the Ag2S, the products are highly crystalline and pure Ag2S nanorods with diameters of 70-160 nm and lengths of 200-360 nm. X-ray diffraction of the S-Ag nanocomposites shows that we obtained cubic Ag and S nanoparticles. Transmission electron microscopy shows that the molar ratio of PVP to Ag+ plays an important role in controlling the size and morphology of the S-Ag nanocomposites. When the molar ratio of PVP to Ag+ was 10:1, smaller sizes, better dispersibility and narrower distribution of S-Ag nanocomposites with diameters of 10-40 nm were obtained. The formation mechanism of the S-Ag nanocomposites was studied by designing a series of experiments using ultraviolet-visible measurement, and it was found that S nanoparticles are produced first and act as seed crystals; then Ag+ becomes Ag nanocrystals on the surfaces of the S nanoparticles by the reduction of PVP. PEG400 acts as a catalyzer, accelerating the reaction rate, and protects the S-Ag nanocomposites from reacting to produce Ag2S. The antimicrobial experiments show that the S-Ag nanocomposites have greater antimicrobial activity on Staphylococcus aureus, Aspergillus niger and blue mold than Ag nanoparticles.

  13. Facile synthesis of S–Ag nanocomposites and Ag2S short nanorods by the interaction of sulfur with AgNO3 in PEG400

    NASA Astrophysics Data System (ADS)

    Zhang, Yan-Li; Xie, Xin-Yuan; Liang, Ming; Xie, Shu-Ming; Chen, Jie-Mei; Zheng, Wen-Jie

    2016-06-01

    A facile, eco-friendly and inexpensive method to prepare Ag2S short nanorods and S–Ag nanocomposites using sublimed sulfur, AgNO3, PVP and PEG400 was studied. According to x-ray diffraction and scanning electron microscopy of the Ag2S, the products are highly crystalline and pure Ag2S nanorods with diameters of 70–160 nm and lengths of 200–360 nm. X-ray diffraction of the S–Ag nanocomposites shows that we obtained cubic Ag and S nanoparticles. Transmission electron microscopy shows that the molar ratio of PVP to Ag+ plays an important role in controlling the size and morphology of the S–Ag nanocomposites. When the molar ratio of PVP to Ag+ was 10:1, smaller sizes, better dispersibility and narrower distribution of S–Ag nanocomposites with diameters of 10–40 nm were obtained. The formation mechanism of the S–Ag nanocomposites was studied by designing a series of experiments using ultraviolet–visible measurement, and it was found that S nanoparticles are produced first and act as seed crystals; then Ag+ becomes Ag nanocrystals on the surfaces of the S nanoparticles by the reduction of PVP. PEG400 acts as a catalyzer, accelerating the reaction rate, and protects the S–Ag nanocomposites from reacting to produce Ag2S. The antimicrobial experiments show that the S–Ag nanocomposites have greater antimicrobial activity on Staphylococcus aureus, Aspergillus niger and blue mold than Ag nanoparticles.

  14. Dow agrees on pipeline in eastern Germany

    SciTech Connect

    Thomas, N.

    1996-05-01

    The often fragile relationship between Dow Europe and eastern Germany strengthened this week with an agreement to build a feedstock pipeline from the Baltic Sea to the Buna BSL petrochemical complex at Boehlen. Dow recently agreed to go ahead with its 80% investment in the BSL venture following fears it might withdraw from the project because of European Commission cuts in the amount of state aid available. The multi-feedstock liquid pipeline is expected to transport naphtha, crude oil, and, possibly, liquid petroleum gas from Rostock on the Baltic to the Boehlen site. Besides Dow, the participants are BSL Olefinverbund and Elf subsidiary Mider. Dow is expected to contribute DM450 million toward the investment.

  15. West Germany: science and animal protection.

    PubMed

    Lorenz, W

    1985-01-26

    West Germany's animal welfare movement is unusual in its emphasis on "protection" based on the religious concept of "Mitgeschöpflichkeit," which holds that "animals like man, are God's creatures and must all be treated with responsibility." At a hearing on amending the 1972 animal welfare law, protectionists, represented by nine organizations, asked for explicit restrictions on the purposes of research, approval of protocols by ethics committees, and the setting of qualifications for researchers. Their demands were challenged by representatives of major medical disciplines, scientific research societies, zoo directors, pharmaceutical companies, and the farmers' association. Lorenz comments that researchers ought to increase scrutiny of their work, avoid duplication, and give attention to pain relief, while protectionists must guard against "misanthropy" and "enmity to research per se." PMID:11644362

  16. [Population developments in Germany until 2050].

    PubMed

    Osterkamp, R

    2005-01-01

    While the total population in Germany is expected to diminish until 2050, the proportion of old and very old persons will rise considerably. The annual frequency of sicknesses, clinic days, and fatalities of old persons will likewise strongly increase. This raises difficult problems for the future design of the German public health care system. In any case, reforms will contain elements of rationing which will lead to a less expansion of the field of activity for geriatric physicians and surgeons than the purely demographic development would suggest. This dampening effect of rationing reforms on geriatric medical treatment and surgery, however, might possibly be least when done in an age-specific way and combined with long-term individual provisions through savings and health insurance. PMID:15551009

  17. AgI/Ag{sub 3}PO{sub 4} hybrids with highly efficient visible-light driven photocatalytic activity

    SciTech Connect

    Katsumata, Hideyuki; Hayashi, Takahiro; Taniguchi, Masanao; Suzuki, Tohru; Kaneco, Satoshi

    2015-03-15

    Highlights: • AgI/Ag{sub 3}PO{sub 4} hybrid was prepared via an in situ anion-exchange method. • AgI/Ag{sub 3}PO{sub 4} displays the excellent photocatalytic activity under visible light. • AgI/Ag{sub 3}PO{sub 4} readily transforms to be Ag@AgI/Ag{sub 3}PO{sub 4} system. • h{sup +} and O{sub 2}{sup ·−} play the major role in the AO 7 decolorization over AgI/Ag{sub 3}PO{sub 4}. • The activity enhancement is ascribed to a Z-scheme system composed of Ag{sub 3}PO{sub 4}, Ag and AgI. - Abstract: Highly efficient visible-light-driven AgI/Ag{sub 3}PO{sub 4} hybrid photocatalysts with different mole ratios of AgI were prepared via an in situ anion-exchange method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) technique. Under visible light irradiation (>420 nm), the AgI/Ag{sub 3}PO{sub 4} photocatalysts displayed the higher photocatalytic activity than pure Ag{sub 3}PO{sub 4} and AgI for the decolorization of acid orange 7 (AO 7). Among the hybrid photocatalysts, AgI/Ag{sub 3}PO{sub 4} with 80% of AgI exhibited the highest photocatalytic activity for the decolorization of AO 7. X-ray photoelectron spectroscopy (XPS) results revealed that AgI/Ag{sub 3}PO{sub 4} readily transformed to be Ag@AgI/Ag{sub 3}PO{sub 4} system while the photocatalytic activity of AgI/Ag{sub 3}PO{sub 4} remained after 5 recycling runs. In addition, the quenching effects of different scavengers displayed that the reactive h{sup +} and O{sub 2}{sup ·−} play the major role in the AO 7 decolorization. The photocatalytic activity enhancement of AgI/Ag{sub 3}PO{sub 4} hybrids can be ascribed to the efficient separation of electron–hole pairs through a Z-scheme system composed of Ag{sub 3}PO{sub 4}, Ag and AgI, in which Ag nanoparticles act as the charge separation center.

  18. Registers for Networked Medical Research in Germany

    PubMed Central

    Stausberg, J.; Altmann, U.; Antony, G.; Drepper, J.; Sax, U.; Schütt, A.

    2010-01-01

    Background Several disease specific registers are operated by members of the ‘TMF – Technology, Methods, and Infrastructure for Networked Medical Research’, an umbrella organization of research networks in Germany. Objective To describe the coverage and the current state as well as financial and organizational issues of registers operated by member networks of the TMF, to identify their requirements and needs, and to recommend best practice models. Methods A survey with a self-completion questionnaire including all 55 TMF member networks was carried out in winter 2007/2008. Interviews focusing on technological issues were conducted and analyzed in summer 2009 with a convenience sample of 10 registers. Results From 55 TMF member networks, 11 provided information about 14 registers. Six registers address diseases of the circulatory system with more than 150,000 registered patients. The interviews revealed a typical setting of “research registers”. Research registers are an important mean to generate hypotheses for clinical research, to identify eligible patients, and to share data with clinical trials. Concerning technical solutions, we found a remarkable heterogeneity. The analysis of the most efficient registers revealed a structure with five levels as best practice model of register management: executive, operations, IT-management, software, hardware. Conclusion In the last ten years, the TMF member networks established disease specific registers in Germany mainly to support clinical research. The heterogeneity of organizational and technical solutions as well as deficits in register planning motivated the development of respective recommendations. The TMF will continue to assist the registers in quality improvement. PMID:23616850

  19. Visible-light-driven photocatalysts Ag/AgCl dispersed on mesoporous Al2O3 with enhanced photocatalytic performance.

    PubMed

    Feng, Zhouzhou; Yu, Jiajie; Sun, Dongping; Wang, Tianhe

    2016-10-15

    In this paper, Ag/AgCl and Ag/AgCl/Al2O3 photocatalysts were synthesized via a precipitation reaction between NaCl and CH3COOAg or Ag(NH3)2NO3, wherein Ag/AgCl was immobilized into mesoporous Al2O3 medium. The Ag/AgCl-based nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectra, and so on. The photocatalysts displayed excellent photocatalytic activity for the degradations of methyl orange (MO) and methylene blue (MB) pollutants under visible light irradiation. The Ag/AgCl(CH3COOAg)/Al2O3 sample exhibited the best photocatalytic performance, degrading 99% MO after 9min of irradiation, which was 1.1 times, 1.22 times and 1.65 times higher than that of Ag/AgCl(Ag(NH3)2NO3)/Al2O3, Ag/AgCl(CH3COOAg) and Ag/AgCl(Ag(NH3)2NO3) photocatalyst, respectively. Meanwhile, Ag/AgCl(CH3COOAg)/Al2O3 also showed excellent capability of MB degradation. Compared to the data reported for Ag/AgCl/TiO2, the Ag/AgCl/Al2O3 prepared in this work exhibited a good performance for the degradation of methyl orange (MO). The results suggest that the dispersion of Ag/AgCl on mesoporous Al2O3 strongly affected their photocatalytic activities. O2(-), OH radicals and Cl(0) atoms are main active species during photocatalysis. PMID:27442145

  20. Excitons in AgI-BASED-GLASSES and -

    NASA Astrophysics Data System (ADS)

    Fujishiro, Fumito; Mochizuki, Shosuke

    2007-01-01

    We summarize our recent optical studies on different pristine AgI films, different AgI-based glasses and different AgI-oxide fine particle composites. The exciton spectra of these specimens give useful information about the ionic and electronic structures at the AgI/glass and AgI/oxide particle interfaces.

  1. Interrelationships between mortality and fertility in Germany: rural and urban Prussia and modern Germany.

    PubMed

    Entorf, H; Zimmermann, K F

    1990-01-01

    "The paper investigates the interrelationship between fertility and infant mortality and its economic determinants by time-series methods for historical and modern Germany. It is studied whether the causal effects of infant mortality on fertility have to be considered as hoarding or replacement, and whether the costs of nutrition have an influence on family decision making about demographic variables. Results show that there are indications for replacement motives, and that economic factors matter." (SUMMARY IN FRE AND ITA)

  2. The cardiovascular response to the AGS

    NASA Technical Reports Server (NTRS)

    Cardus, David; Mctaggart, Wesley G.

    1993-01-01

    This paper reports the preliminary results of experiments on human subjects conducted to study the cardiovascular response to various g-levels and exposure times using an artificial gravity simulator (AGS). The AGS is a short arm centrifuge consisting of a turntable, a traction system, a platform and four beds. Data collection hardware is part of the communication system. The AGS provides a steep acceleration gradient in subjects in the supine position.

  3. AgRP Neurons Regulate Bone Mass.

    PubMed

    Kim, Jae Geun; Sun, Ben-Hua; Dietrich, Marcelo O; Koch, Marco; Yao, Gang-Qing; Diano, Sabrina; Insogna, Karl; Horvath, Tamas L

    2015-10-01

    The hypothalamus has been implicated in skeletal metabolism. Whether hunger-promoting neurons of the arcuate nucleus impact the bone is not known. We generated multiple lines of mice to affect AgRP neuronal circuit integrity. We found that mice with Ucp2 gene deletion, in which AgRP neuronal function was impaired, were osteopenic. This phenotype was rescued by cell-selective reactivation of Ucp2 in AgRP neurons. When the AgRP circuitry was impaired by early postnatal deletion of AgRP neurons or by cell autonomous deletion of Sirt1 (AgRP-Sirt1(-/-)), mice also developed reduced bone mass. No impact of leptin receptor deletion in AgRP neurons was found on bone homeostasis. Suppression of sympathetic tone in AgRP-Sirt1(-/-) mice reversed osteopenia in transgenic animals. Taken together, these observations establish a significant regulatory role for AgRP neurons in skeletal bone metabolism independent of leptin action. PMID:26411686

  4. Multiple Partial Siberian Snakes in the AGS

    SciTech Connect

    Takano, J.; Ahrens, L. A.; Bai, M.; Brown, K.; Courant, E. D.; Gardner, C. J.; Glenn, J. W.; Huang, H.; Luccio, A. U.; MacKay, W. W.; Okamura, M.; Roser, T.; Tepikian, S.; Tsoupas, N.; Yip, K.; Zelenski, A.; Zeno, K.; Hattori, T.; Lin, F.

    2007-06-13

    Polarized protons are accelerated up to 24.3 GeV in the Alternating Gradient Synchrotron (AGS) at Brookhaven National Laboratory (BNL). To accelerate the beam with preserving the polarization, two different types of helical dipole partial Siberian snake have been installed to the AGS. One is a superconducting magnet (Cold Snake, CSNK), and the other is a normal conducting one (Warm Snake, WSNK). With these snake magnets, the polarization at the AGS extraction achieved 65%. However, the AGS has spin mismatches at the injection and extraction. This description shows calculated results to have better spin matching with using two or three snakes.

  5. Toxicokinetics of Ag in the terrestrial isopod Porcellionides pruinosus exposed to Ag NPs and AgNO₃ via soil and food.

    PubMed

    Tourinho, Paula S; van Gestel, Cornelis A M; Morgan, A John; Kille, Peter; Svendsen, Claus; Jurkschat, Kerstin; Mosselmans, J Fred W; Soares, Amadeu M V M; Loureiro, Susana

    2016-03-01

    Silver nanoparticles (Ag NPs) have been used in numerous consumer products and may enter the soil through the land application of biosolids. However, little is known about the relationship between Ag NP exposure and their bioavailability for soil organisms. This study aims at comparing the uptake and elimination kinetics of Ag upon exposures to different Ag forms (NPs and ionic Ag (as AgNO3)) in the isopod Porcellionides pruinosus. Isopods were exposed to contaminated Lufa 2.2 soil or alder leaves as food. Uptake and elimination rate constants for soil exposure did not significantly differ between Ag NPs and ionic Ag at 30 and 60 mg Ag/kg. For dietary exposure, the uptake rate constant was up to 5 times higher for Ag NPs than for AgNO3, but this was related to feeding activity and exposure concentrations, while no difference in the elimination rate constants was found. When comparing both routes, dietary exposure resulted in lower Ag uptake rate constants but elimination rate constants did not differ. A fast Ag uptake was observed from both routes and most of the Ag taken up seemed not to be eliminated. Synchrotron X-ray fluorescence showed Ag in the S-cells of the hepatopancreas, thus supporting the observations from the kinetic experiment (i.e. low elimination). In addition, our results show that isopods have an extremely high Ag accumulation capacity, suggesting the presence of an efficient Ag storage compartment. PMID:26581474

  6. Characterization of the intermediate-range order in new superionic conducting AgI-Ag2S-AgPO3 glasses by neutron diffraction

    NASA Astrophysics Data System (ADS)

    Kartini, E.; Kennedy, S. J.; Itoh, K.; Fukunaga, T.; Suminta, S.; Kamiyama, T.

    Superionic conducting glasses are of considerable technological interest because of their use in batteries, sensors, and displays. We have investigated the new ternary systems AgI-Ag2S-AgPO3 where the ratio AgI:Ag2S is 1:1. The system (AgI)x(Ag2S)x(AgPO3)1-2x, for a AgI+Ag2S fraction less than 82mol%, yields glasses. We have used a neutron-diffraction technique to obtain the total scattering structure factor S(Q) of this system at room temperature by using the HIT spectrometer at the High Energy Accelerator (KEK), Tsukuba, Japan. As for AgI-AgPO3 glasses, S(Q) shows a peak at anomalously low Q in the range from 0.6 to 0.9 Å-1. This peak is not observed in the corresponding glass Ag2S-AgPO3 or pure AgPO3. The peak depends strongly on the dopant salt. Its intensity increases as the amount of (AgI+Ag2S) increases and its position shifts to lower Q, while the number density of the glasses decreases with x. This peak can be associated with an intermediate structure of particles lying inside a continuous host with the characteristic length between 5 and 10 Å [1].

  7. Toxicokinetics of Ag in the terrestrial isopod Porcellionides pruinosus exposed to Ag NPs and AgNO₃ via soil and food.

    PubMed

    Tourinho, Paula S; van Gestel, Cornelis A M; Morgan, A John; Kille, Peter; Svendsen, Claus; Jurkschat, Kerstin; Mosselmans, J Fred W; Soares, Amadeu M V M; Loureiro, Susana

    2016-03-01

    Silver nanoparticles (Ag NPs) have been used in numerous consumer products and may enter the soil through the land application of biosolids. However, little is known about the relationship between Ag NP exposure and their bioavailability for soil organisms. This study aims at comparing the uptake and elimination kinetics of Ag upon exposures to different Ag forms (NPs and ionic Ag (as AgNO3)) in the isopod Porcellionides pruinosus. Isopods were exposed to contaminated Lufa 2.2 soil or alder leaves as food. Uptake and elimination rate constants for soil exposure did not significantly differ between Ag NPs and ionic Ag at 30 and 60 mg Ag/kg. For dietary exposure, the uptake rate constant was up to 5 times higher for Ag NPs than for AgNO3, but this was related to feeding activity and exposure concentrations, while no difference in the elimination rate constants was found. When comparing both routes, dietary exposure resulted in lower Ag uptake rate constants but elimination rate constants did not differ. A fast Ag uptake was observed from both routes and most of the Ag taken up seemed not to be eliminated. Synchrotron X-ray fluorescence showed Ag in the S-cells of the hepatopancreas, thus supporting the observations from the kinetic experiment (i.e. low elimination). In addition, our results show that isopods have an extremely high Ag accumulation capacity, suggesting the presence of an efficient Ag storage compartment.

  8. Evidence for surface Ag + complexes as the SERS-active sites on Ag electrodes

    NASA Astrophysics Data System (ADS)

    Watanabe, T.; Kawanami, O.; Honda, K.; Pettinger, B.

    1983-12-01

    Evidence is given that SERS-active sites at Ag electrodes are associated with Ag + ions, forming sparingly soluble surface complexes with ligands such as pyridine molecules and halide ions. Such surface Ag + complexes contribute a factor of >800 to the overall (10 7-fold) enhancement, possibly via a resonance Raman effect.

  9. Single step electrochemical synthesis of hydrophilic/hydrophobic Ag5 and Ag6 blue luminescent clusters.

    PubMed

    Santiago González, Beatriz; Blanco, M C; López-Quintela, M Arturo

    2012-12-21

    Well-defined Ag(5) and Ag(6) dodecanethiol/tetrabutyl ammonium-protected clusters were prepared by a one-pot electrochemical method. Ag clusters show bright and photostable emissions. The presence of a dual capping renders the silver clusters soluble in both organic and aqueous solvents.

  10. 78 FR 30965 - AG Valley Railroad, LLC-Operation Exemption-Ag Valley Holdings, LLC

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-23

    ... Surface Transportation Board AG Valley Railroad, LLC--Operation Exemption--Ag Valley Holdings, LLC AG... original and 10 copies of all pleadings, referring to Docket No. FD 35736, must be filed with the Surface.... Board decisions and notices are available on our Web site at www.stb.dot.gov . Decided: May 20, 2013....

  11. Standards of nutrition for athletes in Germany.

    PubMed

    Diel, F; Khanferyan, R A

    2013-01-01

    The Deutscher Olympische Sportbund (DOSB) founded recently an advisory board for German elite athlete nutrition, the 'Arbeitsgruppe (AG) Ernahrungsberatung an den Olympiastutzpunkten'. The 'Performance codex and quality criteria for the food supply in facilities of German elite sports' have been established since 1997. The biochemical equivalent (ATP) for the energy demand is calculated using the DLW (Double Labeled Water)-method on the basis of RMR (Resting Metabolic Rate) and BMR (Basic Metabolic Rate) at sport type specific exercises and performances. Certain nutraceutical ingredients for dietary supplements can be recommended. However, quality criteria for nutrition, cooking and food supply are defined on the basis of Health Food and the individual physiological/social-psychological status of the athlete. Especially food supplements and instant food have to be avoided for young athletes. The German advisory board for elite athlete nutrition publishes 'colour lists' for highly recommended (green), acceptable (yellow), and less recommended (red) food stuff.

  12. Progress with the AGS Booster

    SciTech Connect

    Weng, W.T.

    1988-01-01

    Rare K-decay, neutrino and heavy ion physics demands that a rapid- cycling high vacuum and high intensity Booster be built for the AGS at Brookhaven. For each mode of operation there are corresponding accelerator physics and design issues needing special attention. Problems pertinent to any single mode of operation have been encountered and solved before, but putting high intensity proton requirements and high vacuum heavy ion requirements into one machine demands careful design considerations and decisions. The lattice design and magnet characteristics will be briefly reviewed. Major design issues will be discussed and design choices explained. Finally, the construction status and schedule will be presented. 6 refs., 6 figs.

  13. Hypernuclear research at the AGS

    SciTech Connect

    Chrien, R.E.

    1984-01-01

    Although the field of hypernuclear research is over 30 years old, progress in exploring the detailed behavior of hypernuclei has been slow. This fact is due mainly to the technical problems of producing and studying these strange objects. Indeed each step in the improvement of technique has been accompanied by a breakthrough in our understanding of this fascinating subject. In this paper, the aim is to describe the evolution of hypernuclear research, stressing especially the contributions of the program based on the Brookhaven AGS. 23 references, 17 figures, 1 table.

  14. Shale gas characteristics of the Lower Toarcian Posidonia Shale in Germany: from basin to nanometre scale

    NASA Astrophysics Data System (ADS)

    Schulz, Hans-Martin; Bernard, Sylvain; Horsfield, Brian; Krüger, Martin; Littke, Ralf; di primio, Rolando

    2013-04-01

    thermal maturities beyond the oil window, intra-mineral and intra-organic pores develop. In such overmature samples, nanopores occur within pyrobitumen masses. Important for gas storage and transport, they likely result from exsolution of gaseous hydrocarbon. References Bernard S., Wirth R., Schreiber A., Bowen L., Aplin A.C., Mathia E.J., Schulz H-M., & Horsfield B.: FIB-SEM and TEM investigations of an organic-rich shale maturation series (Lower Toarcian Posidonia Shale): Nanoscale pore system and fluid-rock interactions. AAPG Bulletin Special Issue "Electron Microscopy of Shale Hydrocarbon Reservoirs" (in press). Bernard, S., Horsfield, B., Schulz, H-M., Wirth, R., Schreiber, A., & Sherwood, N., 2012, Geochemical evolution of organic-rich shales with increasing maturity: A STXM and TEM study of the Posidonia Shale (Lower Toarcian, northern Germany): Marine and Petroleum Geology 31 (1) 70-89. Lott, G.K., Wong, T.E., Dusar, M., Andsbjerg, J., Mönnig, E., Feldman-Olszewska, A. & Verreussel, R.M.C.H., 2010. Jurassic. In: Doornenbal, J.C. and Stevenson, A.G. (editors): Petroleum Geological Atlas of the Southern Permian Basin Area. EAGE Publications b.v. (Houten): 175-193.

  15. Synthesis and Optical Responses of Ag@Au/Ag@Au Double Shells

    NASA Astrophysics Data System (ADS)

    Li, Ying-Ying; Liu, Xiao-Li; Yang, Da-Jie; Hao, Zhong-Hua; Wang, Qu-Quan

    2015-02-01

    We synthesize hollow-structured Ag@Au nanoparticles with single porous shell and Ag@Au/Ag@Au double shells by using the galvanic replacement reaction and investigate their linear and nonlinear optical properties. Our results show that the surface plasmon resonance wavelength of the hollow porous nanoparticles could be easily tuned in a wide range in the visible and near infrared region by controlling the volume of HAuCl4. The nonlinear optical refraction of the double-shelled Ag@Au/Ag@Au nanoparticles is prominently enhanced by the plasmon resonance. Our findings may find applications in biosensors and nonlinear optical nanodevices.

  16. Photon emission intensities in the decay of 108mAg and 110mAg.

    PubMed

    Ferreux, L; Lépy, M-C; Bé, M-M; Isnard, H; Lourenço, V

    2014-05-01

    This study focuses on two radioisotopes of silver, (108m)Ag and (110m)Ag, characterized by a complex decay scheme. Each isotope has two disintegration modes, the isomeric transition leading to the daughter isotope ((108)Ag and (110)Ag, respectively) with a short half-life. The radioactive solution was obtained by neutron activation on silver powder enriched in (109)Ag. Gamma-spectrometry was carried out using a calibrated high purity germanium detector. The main relative photon emission intensities for both radionuclides were obtained and compared with previously published values.

  17. Visible light driven photocatalysis and antibacterial activity of AgVO{sub 3} and Ag/AgVO{sub 3} nanowires

    SciTech Connect

    Singh, Anamika; Dutta, Dimple P.; Ballal, A.; Tyagi, A.K.; Fulekar, M.H.

    2014-03-01

    Graphical abstract: - Highlights: • Ag/AgVO{sub 3} and pure AgVO{sub 3} nanowires synthesized by sonochemical process. • Characterization done using XRD, SEM, TEM, EDX and BET analysis. • Visible light degradation of RhB by Ag/AgVO{sub 3} within 45 min. • Antibacterial activity of Ag/AgVO{sub 3} demonstrated. - Abstract: Ag/AgVO{sub 3} nanowires and AgVO{sub 3} nanorods were synthesized in aqueous media via a facile sonochemical route. The as-synthesized products were characterized by X-ray diffraction, Brunauer–Emmett–Teller surface area analysis, scanning electron microscopy together with an energy dispersion X-ray spectrum analysis, transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The results revealed that inert atmosphere promotes the formation of Ag/AgVO{sub 3} nanowires. The photocatalytic studies revealed that the Ag/AgVO{sub 3} nanowires exhibited complete photocatalytic degradation of Rhodamine B within 45 min under visible light irradiation. The antibacterial activity of Ag/AgVO{sub 3} nanowires was tested against Escherechia coli and Bacillus subtilis. The minimum growth inhibitory concentration value was found to be 50 and 10 folds lower than for the antibiotic ciprofloxacin for E. coli and B. subtilis, respectively. The antibacterial properties of the β-AgVO{sub 3} nanorods prove that in case of the Ag dispersed Ag/AgVO{sub 3} nanowires, the enhanced antibacterial action is also due to contribution from the AgVO{sub 3} support.

  18. Effects of soil and dietary exposures to Ag nanoparticles and AgNO₃ in the terrestrial isopod Porcellionides pruinosus.

    PubMed

    Tourinho, Paula S; van Gestel, Cornelis A M; Jurkschat, Kerstin; Soares, Amadeu M V M; Loureiro, Susana

    2015-10-01

    The effects of Ag-NPs and AgNO3 on the isopod Porcellionides pruinosus were determined upon soil and dietary exposures. Isopods avoided Ag in soil, with EC50 values of ∼16.0 and 14.0 mg Ag/kg for Ag-NPs and AgNO3, respectively. Feeding inhibition tests in soil showed EC50s for effects on consumption ratio of 127 and 56.7 mg Ag/kg, respectively. Although similar EC50s for effects on biomass were observed for nanoparticulate and ionic Ag (114 and 120 mg Ag/kg dry soil, respectively), at higher concentrations greater biomass loss was found for AgNO3. Upon dietary exposure, AgNO3 was more toxic, with EC50 for effects on biomass change being >1500 and 233 mg Ag/kg for Ag-NPs and AgNO3, respectively. The difference in toxicity between Ag-NPs and AgNO3 could not be explained from Ag body concentrations. This suggests that the relation between toxicity and bioavailability of Ag-NPs differs from that of ionic Ag in soils.

  19. Tribological properties of ag-based amphiphiles

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Most ag-based materials are amphiphilic because they comprise polar and non-polar groups within the same molecule. One of the major categories of amphiphilic ag-based materials are seed oils, which are actively investigated as substitutes for petroleum in a wide variety of consumer and industrial a...

  20. AgRISTARS documents tracking list report

    NASA Technical Reports Server (NTRS)

    Hawkins, J. L.

    1983-01-01

    A quarterly listing of documents issued and placed in the AgRISTARS tracking system is provided. The technical publications are arranged by type of documents. The reference AgRISTARS document number, title and date of publication, the issuing organization, and the National Technical Information Service reference number is given.

  1. The AGS synchrotron with four helical magnets

    SciTech Connect

    Tsoupas N.; Huang, H.; Roser, T.; MacKay, W.W.; Trbojevic, D.

    2012-05-20

    The idea of using two partial helical magnets was applied successfully to the AGS synchrotron to preserve the proton beam polarization. In this paper we explore in details the idea of using four helical magnets placed symmetrically in the AGS ring. The placement of four helical magnets in the AGS ring provides many advantages over the present setup of the AGS which uses two partial helical magnets. First, the symmetric placement of the four helical magnets allows for a better control of the AGS optics with reduced values of the beta functions especially near beam injection, second, the vertical spin direction during beam injection and extraction is closer to vertical, and third, it provides for a larger 'spin tune gap', which allows the vertical and horizontal tunes to be placed, and prevent the horizontal and vertical intrinsic spin resonances of the AGS to occur during the acceleration cycle. Although the same spin gap can be obtained with a single or two partial helices, the required high field strength of a single helix makes its use impractical, and that of the double helix rather difficult. In this paper we will provide results on the spin tune and on the optics of the AGS with four partial helical magnets, and compare these results with the present setup of the AGS that uses two partial helical magnets.

  2. Recent hypernuclear research at the Brookhaven AGS

    SciTech Connect

    Chrien, R.E.

    1985-01-01

    Recent AGS experiments contributing to our knowledge of hypernuclei are reviewed. These experiments have suggested new areas of research on hypernuclei. With the proper beam line facilities, the AGS will be able to perform experiments in these areas and provide a transition to the future era of ''kaon factories''. 20 refs., 14 figs.

  3. Synthesis and visible-light-induced catalytic activity of Ag2S-coupled TiO2 nanoparticles and nanowires

    NASA Astrophysics Data System (ADS)

    Xie, Yi; Heo, Sung Hwan; Kim, Yong Nam; Yoo, Seung Hwa; Cho, Sung Oh

    2010-01-01

    We present the synthesis and visible-light-induced catalytic activity of Ag2S-coupled TiO2 nanoparticles (NPs) and TiO2 nanowires (NWs). Through a simple wet chemical process from a mixture of peroxo titanic acid (PTA) solution, thiourea and AgAc, a composite of Ag2S NPs and TiO2 NPs with sizes of less than 7 nm was formed. When the NP composite was further treated with NaOH solution followed by annealing at ambient conditions, a new nanocomposite material comprising Ag2S NPs on TiO2 NWs was created. Due to the coupling with such a low bandgap material as Ag2S, the TiO2 nanocomposites could have a visible-light absorption capability much higher than that of pure TiO2. As a result, the synthesized Ag2S/TiO2 nanocomposites exhibited much higher catalytic efficiency for the decomposition of methyl orange than commercial TiO2 (Degussa P25, Germany) under visible light.

  4. Label-Free Detection of Ag+ Based on Gold Nanoparticles and Ag+-Specific DNA.

    PubMed

    Pu, Wendan; Zhao, Zhao; Wu, Liping; Liu, Yue; Zhao, Huawen

    2015-08-01

    A sensitive label-free method was presented for the determination of silver ion (Ag+) in this paper. Cytosine-rich DNA (C-DNA) was used as Ag+ specific DNA. Without Ag+ in the solution, fluorescence of fluorescein (FAM) is quenched by C-DNA stabilized gold nanoparticles (AuNPs) in high salt environment. When Ag+ is present in the solution, however, Ag+-mediated cytosine-Ag+-cytosine (C-Ag+-C) base pairs induced the C-DNA folding into a hairpin structure, which can not stabilize AuNPs in high salt environment, thus causing AuNPs aggregation. After centrifugation to remove the aggregated AuNPs, the quenching ability of the supernatant for FAM is decreased and the fluorescence intensity of solution increases with increasing the Ag+ concentration. Due to the highly specific interaction of the C-DNA towards Ag+ and the strong fluorescent quenching ability of AuNPs for FAM, the method has high selectivity and sensitivity for Ag+. Under the optimal conditions, the fluorescence intensity at 515 nm increased linearly with the concentration of Ag+ ranging from 15 nM to 700 nM, and the detection limit was determined as 6 nM based on 3 σ/slope. This method is simple, sensitive, and may be applied to other detection systems by selecting the appropriate DNA sequences. PMID:26369112

  5. Raman scattering enhanced within the plasmonic gap between an isolated Ag triangular nanoplate and Ag film

    NASA Astrophysics Data System (ADS)

    Li, Kuanguo; Jiang, Kang; Zhang, Lan; Wang, Yong; Mao, Lei; Zeng, Jie; Lu, Yonghua; Wang, Pei

    2016-04-01

    Enhanced electromagnetic field in the tiny gaps between metallic nanostructures holds great promise in optical applications. Herein, we report novel out-of-plane nanogaps composed of micrometer-sized Ag triangular nanoplates (AgTN) on Ag films. Notably, the new coupled plasmonic structure can dramatically enhance the surface-enhanced Raman scattering (SERS) by visible laser excitation, although the micrometer-sized AgTN has localized plasmon resonance at infrared wavelength. This enhancement is derived from the gap plasmon polariton between the AgTN and Ag film, which is excited via the antenna effect of the corner and edge of the AgTN. Systematic SERS studies indicated that the plasmon enhancement was on the order of corner > edge > face. These results were further verified by theoretical simulations. Our device paves the way for rational design of sensitive SERS substrates by judiciously choosing appropriate nanoparticles and optimizing the gap distance.

  6. Atomic-level observation of Ag-ion hopping motion in AgI

    NASA Astrophysics Data System (ADS)

    Sato, W.; Komatsuda, S.; Mizuuchi, R.; Irioka, N.; Kawata, S.; Ohkubo, Y.

    2015-04-01

    Applicability of the 111mCd(→111Cd) and 111In(→111Cd) probes to the study of dynamics in polycrystalline silver iodide (AgI) was examined by means of the time-differential perturbed angular correlation technique. It was found that the 111mCd(→111Cd) probe occupies a unique site in γ-AgI and exhibits nuclear relaxation caused by dynamic perturbation arising from Ag + hopping motion in α-AgI; while the residential sites of 111In(→111Cd) vary, suggesting that 111In ions can not settle themselves in a fixed site in the AgI crystal structure. We here demonstrate that 111mCd(→111Cd) can be a potential nucleus to probe the Ag +-ion dynamic motion in α-AgI.

  7. AgPO2F2 and Ag9(PO2F2)14: the first Ag(i) and Ag(i)/Ag(ii) difluorophosphates with complex crystal structures.

    PubMed

    Malinowski, Przemysław J; Kurzydłowski, Dominik; Grochala, Wojciech

    2015-12-01

    The reaction of AgF2 with P2O3F4 yields a mixed valence Ag(I)/Ag(II) difluorophosphate salt with AgAg(PO2F2)14 stoichiometry - the first Ag(ii)-PO2F2 system known. This highly moisture sensitive brown solid is thermally stable up to 120 °C, which points at further feasible extension of the chemistry of Ag(ii)-PO2F2 systems. The crystal structure shows a very complex bonding pattern, comprising of polymeric Ag(PO2F2)14(4-) anions and two types of Ag(I) cations. One particular Ag(II) site present in the crystal structure of Ag9(PO2F2)14 is the first known example of square pyramidal penta-coordinated Ag(ii) in an oxo-ligand environment. Ag(i)PO2F2 - the product of the thermal decomposition of Ag9(PO2F2)14 - has also been characterized by thermal analysis, IR spectroscopy and X-ray powder diffraction. It has a complicated crystal structure as well, which consists of infinite 1D [Ag(I)O4/2] chains which are linked to more complex 3D structures via OPO bridges. The PO2F2(-) anions bind to cations in both compounds as bidentate oxo-ligands. The terminal F atoms tend to point inside the van der Waals cavities in the crystal structure of both compounds. All important structural details of both title compounds were corroborated by DFT calculations. PMID:26200921

  8. [The situation of emergency psychiatry in Germany].

    PubMed

    Pajonk, F-G B

    2015-09-01

    The impact of psychiatric emergencies for the care of patients in preclinical emergency medicine, in emergency departments and in psychiatric hospitals has been underestimated for a long time. There is still insufficient knowledge and a need for further research. There are, however, sufficient reasons to assume that annually approximately 500,000 patients with a psychiatric emergency receive treatment from a preclinical emergency physician and another 1.5 million in emergency departments in Germany. Further, approximately 500,000 patients are admitted to psychiatric hospitals as an emergency. The most frequent reasons are intoxication, agitation, aggressiveness and suicidal ideation, posing a threat of self-harm to the patient or to other persons and evoking other life-threatening conditions. Emergency psychiatry also plays a role in collective injuries, such as mass disasters, catastrophes and rampage situations. There is some evidence that the number of psychiatric emergencies is increasing. Reasons are, among others, changes in the services provided for inpatient and outpatient treatment, a reduction in stabilizing psychosocial factors and a general increase in the utilization of emergency healthcare services. PMID:26099496

  9. [The quality of chronic care in Germany].

    PubMed

    Fullerton, Birgit; Nolte, Ellen; Erler, Antje

    2011-01-01

    Over the last ten years changes in the legal framework of the German health care system have promoted the development of new health service models to improve chronic care. Recent innovations include the nation-wide introduction of disease management programmes (DMPs), integrated care contracts, community nurse programmes, the introduction of General Practitioner (GP)-centred care contracts, and new opportunities to offer interdisciplinary outpatient care in polyclinics. The aim of this article is to describe the recent developments regarding both the implementation of new health care models by statutory health insurance companies and their evaluation. As part of a European project on the development and validation of disease management evaluation methods (DISMEVAL), we carried out a selective literature search to identify relevant models and evaluation studies. However, on the basis of the currently available evaluation and study results it is difficult to judge whether these developments have actually led to an improvement in the quality of chronic care in Germany. Only for DMPs, evaluation is legally mandatory; its methods are inappropriate, though, for studying the effectiveness of DMPs. Further study results on the effectiveness of DMPs mostly focus on the DMP Diabetes mellitus type II and show consistent improvements regarding process parameters such as regular routine examinations, adherence to treatment guidelines, and quality of life. More research will be needed to determine whether DMPs can also help reduce the incidence of secondary disease and mortality in the long term. PMID:22142877

  10. Women in Physics in Germany, 2008

    NASA Astrophysics Data System (ADS)

    Kluge, Hanna

    2009-04-01

    The status of women in physics in Germany has not changed dramatically in the three years since the last IUPAP Women in Physics Conference was held in 2005. The salary of a woman remains approximately 25% lower than that of a man in a comparable professional position. The number of female professors is growing slowly. The number of young women beginning to study physics is around 20%. There is, however, a noticeable increase in organization and societal acceptance of female physicists, and an increasing amount of men taking part in this process. There is also increased acceptance and support of dual-career couples. The Helmholtz Alliance for "Physics at the Terascale" founded a dual-career option program. In 2008, the annual Conference of German Female Physicists (DPT) held in Muenster became an official conference of the DPG (German Physical Society). Various scientific groups working for equal opportunity have formed a "network of networks." At the DESY (German Electron Synchrotron), a group of women led by an equal opportunity officer is involved in the entire process of hiring new staff members in all positions, including directors.

  11. Mosquitoes (Diptera: Culicidae) of metropolitan Hamburg, Germany.

    PubMed

    Krüger, A; Börstler, J; Badusche, M; Lühken, R; Garms, R; Tannich, E

    2014-08-01

    In Europe, mosquito-related public health concerns are growing due to the increasing spread of invasive mosquito species and the recent emergence of mosquito-borne arboviruses. A vital backbone in the assessment of these issues is detailed knowledge of the mosquito fauna, i.e. regional mosquito inventories. It was therefore decided to intensify nationwide investigations on the occurrence and distribution of mosquitoes in Germany in order to update old records and to detect possible faunal changes. This paper is focussing on a densely populated metropolitan region, the federal state of Hamburg and its adjacent environs, taking two historical baseline inventories into consideration, spanning almost 100 years of mosquito research in Hamburg. In the period between 2010 and 2014, more than 10,000 juvenile, neonate and adult mosquito specimens were sampled and trapped at 105 sites in Hamburg and its environs, of which about 60% have been identified to species level, resulting in a total of 33 recorded species. Of these, Anopheles algeriensis, Culex modestus, Ochlerotatus caspius, Ochlerotatus nigrinus and Ochlerotatus sticticus are new to the area. The most common species in Hamburg are Culex pipiens/torrentium and Ochlerotatus annulipes/cantans. In contrast, two previously common species, Anopheles atroparvus and Ochlerotatus excrucians, were not detected. Despite substantial environmental changes due to reconstruction, urbanisation and renaturation in the Hamburg metropolitan region in recent decades, there has been remarkably little change within the mosquito fauna during the last century. PMID:24870250

  12. Blood parasites in reptiles imported to Germany.

    PubMed

    Halla, Ursula; Ursula, Halla; Korbel, Rüdiger; Rüdiger, Korbel; Mutschmann, Frank; Frank, Mutschmann; Rinder, Monika; Monika, Rinder

    2014-12-01

    Though international trade is increasing, the significance of imported reptiles as carriers of pathogens with relevance to animal and human health is largely unknown. Reptiles imported to Germany were therefore investigated for blood parasites using light microscopy, and the detected parasites were morphologically characterized. Four hundred ten reptiles belonging to 17 species originating from 11 Asian, South American and African countries were included. Parasites were detected in 117 (29%) of individual reptiles and in 12 species. Haemococcidea (Haemogregarina, Hepatozoon, Schellackia) were found in 84% of snakes (Python regius, Corallus caninus), 20% of lizards (Acanthocercus atricollis, Agama agama, Kinyongia fischeri, Gekko gecko) and 50% of turtles (Pelusios castaneus). Infections with Hematozoea (Plasmodium, Sauroplasma) were detected in 14% of lizards (Acanthocercus atricollis, Agama agama, Agama mwanzae, K. fischeri, Furcifer pardalis, Xenagama batillifera, Acanthosaura capra, Physignathus cocincinus), while those with Kinetoplastea (Trypanosoma) were found in 9% of snakes (Python regius, Corallus caninus) and 25 % of lizards (K. fischeri, Acanthosaura capra, G. gecko). Nematoda including filarial larvae parasitized in 10% of lizards (Agama agama, Agama mwanzae, K. fischeri, Fu. pardalis, Physignathus cocincinus). Light microscopy mostly allowed diagnosis of the parasites' genus, while species identification was not possible because of limited morphological characteristics available for parasitic developmental stages. The investigation revealed a high percentage of imported reptiles being carriers of parasites while possible vectors and pathogenicity are largely unknown so far. The spreading of haemoparasites thus represents an incalculable risk for pet reptiles, native herpetofauna and even human beings.

  13. Space Radar Image of Munich, Germany

    NASA Technical Reports Server (NTRS)

    1994-01-01

    This spaceborne radar image of Munich, Germany illustrates the capability of a multi-frequency radar system to highlight different land use patterns in the area surrounding Bavaria's largest city. Central Munich is the white area at the middle of the image, on the banks of the Isar River. Pink areas are forested, while green areas indicate clear-cut and agricultural terrain. The Munich region served as a primary 'supersite' for studies in ecology, hydrology and radar calibration during the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) missions. Scientists were able to use these data to map patterns of forest damage from storms and areas affected by bark beetle infestation. The image was acquired by SIR-C/X-SAR onboard the space shuttle Endeavour on April 18, 1994. The image is 37 kilometers by 32 kilometers (23 miles by 20 miles) and is centered at 48.2 degrees North latitude, 11.5 degrees East longitude. North is toward the upper right. The colors are assigned to different radar frequencies and polarizations of the radar as follows: red is L-band, vertically transmitted and horizontally received; green is C-band, vertically transmitted and horizontally received; and blue is C-band vertically transmitted and received. SIR-C/X-SAR, a joint mission of the German, Italian, and United States space agencies, is part of NASA's Mission to Planet Earth.

  14. [The state of outpatient psychotherapy in Germany].

    PubMed

    Zepf, Siegfried; Mengele, Ute; Hartmann, Sebastian

    2003-01-01

    This paper presents the results of a study of the state of adult outpatient psychotherapy in Germany after the PTG came into force. 1042 psychotherapists were questioned on certain issues. One result was that patients have to wait 4.6 months for psychotherapy and that every second patient asking for a diagnostic interview and possible treatment was refused. Of those who were given a diagnostic interview 35 % were not taken into treatment, although disturbances were diagnosed--such as tinnitus, pain, organic disturbances with psychic complications, suicidal tendencies, anorexia nervosa, addiction, psychosomatic illnesses, personality disorders, psychotic disorders--would normally demand psychotherapeutic treatment. Furthermore only 56 % of those patients who Löcherbach et al. considered needing and wanting psychotherapeutic treatment were actually in a G IV psychotherapy. Apart from this the possibility of getting psychotherapy as well as the kind of psychotherapy proved to be dependent on the kind of medical insurance. Different payments by the insurance companies caused longer waiting times for patients and determined the choice of psychotherapy by the psychotherapists. PMID:12649759

  15. [The situation of complementary medicine in Germany].

    PubMed

    Albrecht, Henning

    2013-01-01

    With the amendment of the German Medicinal Products Act in 1976 and the inclusion of naturopathy and homeopathy into the German Medical Licensure Act from 1988, the German government set up a comparatively favorable framework for Complementary and Alternative Medicine (CAM). But no comprehensive integration into the academic operating systems followed, because the universities as well as the legislative body seemed to have no further interest in CAM. Therefore, research projects in the field and suitable professorships had and still have to be financed by third-party funds. Notwithstanding the success of several CAM-projects, no sustainable development could be established: When the third-party funding runs off and the protagonists retire the institutional structures are supposed to vanish as well. Although the public demand for CAM is high in Germany, the administration detached homeopathy as a compulsory subject from the German Medical Licensure Act in 2002 and restricted severely the refunding of naturopathic medicines by the statutory health insurance in 2004. Moreover, the trend for CAM bashing takes root in the media. Unfortunately the CAM scene does not close ranks and is incapable to implement fundamental data collection processes into daily clinical routine: A wide range of data could justify further efforts to the government as well as to the scientific community. To say something positive, it must be mentioned that the scientific standard of CAM research is high for the most part and that third-party funded projects deliver remarkable results ever and on.

  16. Blood parasites in reptiles imported to Germany.

    PubMed

    Halla, Ursula; Ursula, Halla; Korbel, Rüdiger; Rüdiger, Korbel; Mutschmann, Frank; Frank, Mutschmann; Rinder, Monika; Monika, Rinder

    2014-12-01

    Though international trade is increasing, the significance of imported reptiles as carriers of pathogens with relevance to animal and human health is largely unknown. Reptiles imported to Germany were therefore investigated for blood parasites using light microscopy, and the detected parasites were morphologically characterized. Four hundred ten reptiles belonging to 17 species originating from 11 Asian, South American and African countries were included. Parasites were detected in 117 (29%) of individual reptiles and in 12 species. Haemococcidea (Haemogregarina, Hepatozoon, Schellackia) were found in 84% of snakes (Python regius, Corallus caninus), 20% of lizards (Acanthocercus atricollis, Agama agama, Kinyongia fischeri, Gekko gecko) and 50% of turtles (Pelusios castaneus). Infections with Hematozoea (Plasmodium, Sauroplasma) were detected in 14% of lizards (Acanthocercus atricollis, Agama agama, Agama mwanzae, K. fischeri, Furcifer pardalis, Xenagama batillifera, Acanthosaura capra, Physignathus cocincinus), while those with Kinetoplastea (Trypanosoma) were found in 9% of snakes (Python regius, Corallus caninus) and 25 % of lizards (K. fischeri, Acanthosaura capra, G. gecko). Nematoda including filarial larvae parasitized in 10% of lizards (Agama agama, Agama mwanzae, K. fischeri, Fu. pardalis, Physignathus cocincinus). Light microscopy mostly allowed diagnosis of the parasites' genus, while species identification was not possible because of limited morphological characteristics available for parasitic developmental stages. The investigation revealed a high percentage of imported reptiles being carriers of parasites while possible vectors and pathogenicity are largely unknown so far. The spreading of haemoparasites thus represents an incalculable risk for pet reptiles, native herpetofauna and even human beings. PMID:25324132

  17. Antibacterial biodegradable Mg-Ag alloys.

    PubMed

    Tie, D; Feyerabend, F; Müller, W D; Schade, R; Liefeith, K; Kainer, K U; Willumeit, R

    2013-06-16

    The use of magnesium alloys as degradable metals for biomedical applications is a topic of ongoing research and the demand for multifunctional materials is increasing. Hence, binary Mg-Ag alloys were designed as implant materials to combine the favourable properties of magnesium with the well-known antibacterial property of silver. In this study, three Mg-Ag alloys, Mg2Ag, Mg4Ag and Mg6Ag that contain 1.87 %, 3.82 % and 6.00 % silver by weight, respectively, were cast and processed with solution (T4) and aging (T6) heat treatment. The metallurgical analysis and phase identification showed that all alloys contained Mg4Ag as the dominant β phase. After heat treatment, the mechanical properties of all Mg-Ag alloys were significantly improved and the corrosion rate was also significantly reduced, due to presence of silver. Mg(OH)₂ and MgO present the main magnesium corrosion products, while AgCl was found as the corresponding primary silver corrosion product. Immersion tests, under cell culture conditions, demonstrated that the silver content did not significantly shift the pH and magnesium ion release. In vitro tests, with both primary osteoblasts and cell lines (MG63, RAW 264.7), revealed that Mg-Ag alloys show negligible cytotoxicity and sound cytocompatibility. Antibacterial assays, performed in a dynamic bioreactor system, proved that the alloys reduce the viability of two common pathogenic bacteria, Staphylococcus aureus (DSMZ 20231) and Staphylococcus epidermidis (DSMZ 3269), and the results showed that the killing rate of the alloys against tested bacteria exceeded 90%. In summary, biodegradable Mg-Ag alloys are cytocompatible materials with adjustable mechanical and corrosion properties and show promising antibacterial activity, which indicates their potential as antibacterial biodegradable implant materials.

  18. Factors affecting the transfer of radiocaesium from soil to roe deer in forest ecosystems of southern Germany.

    PubMed

    Kiefer, P; Pröhl, G; Müller, H; Lindner, G; Drissner, J; Zibold, G

    1996-11-29

    Since 1987, in Southern Germany, as a consequence of the Chernobyl accident, the 137Cs activity concentration in roe deer (Capreolus capreolus) has been intensively monitored. A large data set is now available with approximately 5000 samples, with information about the location of the animal, the time of slaughtering, soil characteristics and distance to intensively managed agricultural land. Both the roe deer 137Cs activity concentrations and aggregated transfer coefficients soil-roe deer (T(ag,r)) show a considerable variability with geometric mean and geometric standard deviation in meat of 270.3.5 +/- 1 Bq.kg-1 and 0.01.3.5 +/- 1 m2.kg-1, respectively. From 1987 to 1991, T(ag,r) values exhibited a decline with an ecological half-life of about 3 years. Since 1991, no further decrease of the roe deer contamination level was observed. This general trend is superimposed by an increase in T(ag,r) in autumn that has occurred in almost every year, which is probably due to consumption of mushrooms. This hypothesis is supported by a significant positive correlation between the precipitation during July and August, stimulating the fungi's growth and the height of the maximum in T(ag,r) in autumn. Animals are less contaminated when living in parts of the forest from where they have access to intensively managed agricultural land. A small, but significant correlation is observed between the T(ag,r) and soil parameters; the total potassium content of the soil and the pH of the organic soil layer. The highest transfer coefficients soil-roe deer were found on a peat bog, where most values ranged from 0.01-0.1 m2.kg-1, and neither a pronounced seasonal variation, nor a long-term decrease was observed. On sites with coniferous forests, most T(ag,r) values range from 0.005 to 0.05 m2.kg-1, on sites with a mixture of coniferous and deciduous trees, the transfer coefficients range mostly from 0.002 to 0.02 m2.kg-1. This is a further indication of the importance of the uppermost

  19. The development of human genetics in Germany; a personal view.

    PubMed

    Vogel, F

    2005-07-01

    A personal account is given of the reconstruction and development of human genetics in Germany during the years following World War 2. An important stimulus was funding, as a result of the recognition of the genetic hazards of atomic radiation. Starting from 1960, human genetics institutes were progressively established throughout West Germany; comparable development was later in East Germany because of political factors. The first genetic counselling units were formed in 1972, but molecular biology only became an integral part of human genetics institutes at a relatively late stage. Close international links have characterised post-war human genetics in Germany from the outset and a tradition of close links with developing countries has also been established.

  20. North portal of Culvert No. 1308, High Germany Road Culvert, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    North portal of Culvert No. 1308, High Germany Road Culvert, seen from Bill's Place in Little Orleans, MD, looking southeast. - Western Maryland Railway, Cumberland Extension, Pearre to North Branch, from WM milepost 125 to 160, Pearre, Washington County, MD

  1. Extraterrestrial research in the Federal Republic of Germany

    NASA Technical Reports Server (NTRS)

    1986-01-01

    This German program for basic extraterrestrial research is an essential, successful, and worldwide recognized part of the space program and has the same attributes for basic research in the Federal Republic of Germany. It covers all major scientific disciplines.

  2. [Suicides and Suicid Rates in Germany, Bavaria and Upper Frankonia

    PubMed

    Mauerer, Christian; Wolfersdorf, Manfred; Keller, Ferdinand

    2003-05-01

    The authors give an actual survey about suicides and suicide rates in Germany, Bavaria and Upper Frankonia. Their special interest are significant trends in the last years. These trends will be shown and shortly described.

  3. Recruitment of Civil Engineering Students in Germany: Shortage or Overflow?

    ERIC Educational Resources Information Center

    Rothert, Heinrich

    1990-01-01

    Discussed is the recruitment and demand for civil engineering students in Germany. Described is the German engineering education system and the possibility of a joint-venture building industry between the two German states. (KR)

  4. Arms control and the Federal Republic of Germany

    SciTech Connect

    Hanrieder, W.F.

    1987-01-01

    These essays explore the implications of arms control negotiations for the FRG and consider why Germany has traditionally found it impossible to divorce considerations of arms control from their larger political context.

  5. Springer--Germany's Most Remorselessly Criticized Publishing Giants.

    ERIC Educational Resources Information Center

    Hollstein, Milton

    1982-01-01

    Argues that the success of West Germany's publishing giant, Axel Springer Verlag, can be attributed to the technical excellence of its products and to the fact that these products reflect the mainstream of German thought. (FL)

  6. Albedo neutron dosimetry in Germany: regulations and performance.

    PubMed

    Luszik-Bhadra, M; Zimbal, A; Busch, F; Eichelberger, A; Engelhardt, J; Figel, M; Frasch, G; Günther, K; Jordan, M; Martini, E; Haninger, T; Rimpler, A; Seifert, R

    2014-12-01

    Personal neutron dosimetry has been performed in Germany using albedo dosemeters for >20 y. This paper describes the main principles, the national standards, regulations and recommendations, the quality management and the overall performance, giving some examples. PMID:24639589

  7. Culvert No. 1308, High Germany Road Culvert in Little Orleans, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Culvert No. 1308, High Germany Road Culvert in Little Orleans, Maryland. Bill's Place in foreground, looking east. - Western Maryland Railway, Cumberland Extension, Pearre to North Branch, from WM milepost 125 to 160, Pearre, Washington County, MD

  8. Comparisons in good and bad: criminality in Japan and Germany.

    PubMed

    Kühne, H H

    1994-12-16

    In the field of criminological comparison, Japan and Germany are very suitable subjects. A nearly identical penal law and a social structure of highly developed industrial societies after a complete destruction at the end of World War War II give a good match. At first sight, Japan's crime rate is less than 1/4 of that in Germany. The impact of organised crime on the reduction of general crime is discussed.

  9. Ag(I)-binding to phytochelatins.

    PubMed

    Mehra, R K; Tran, K; Scott, G W; Mulchandani, P; Saini, S S

    1996-02-01

    Phytochelatins (PCs) are glutathione-derived peptides with the general structure (gamma-Glu-Cys)nGly, where n varies from 2 to 11. A variety of metal ions such as Cu(II), Cd(II), Pb(II), Zn(II), and Ag(I) induce PC synthesis in plants and some yeasts. It has generally been assumed that the inducer metals also bind PCs. However, very little information is available on the binding of metals other than Cu(I) and Cd(II) to PCs. In this paper, we describe the Ag(I)-binding characteristics of PCs with the structure (gamma-Glu-Cys)2Gly, (gamma-Glu-Cys)3Gly, and (gamma-Glu-Cys)4Gly. The Ag(I)-binding stoichiometries of these three peptides were determined by (i) UV/VIS spectrophotometry, (ii) luminescence spectroscopy at 77 K, and (iii) reverse-phase HPLC. The three techniques yielded similar results. ApoPCs exhibit featureless absorption in the 220-340 nm range. The binding of Ag(I) to PCs induced the appearance of specific absorption shoulders. The titration end point was indicated by the flattening of the characteristic absorption shoulders. Similarly, luminescence at 77 K due to Ag(I)-thiolate clusters increased with the addition of graded Ag(I) equivalents. The luminescence declined when Ag(I) equivalents in excess of the saturating amounts were added to the peptides. At neutral pH, (gamma-Glu-Cys)2Gly, (gamma-Glu-Cys)3Gly, and (gamma-Glu-Cys)4Gly bind 1.0, 1.5, and 4.0 equivalents of Ag(I), respectively. The Ag(I)-binding capacity of (gamma-Glu-Cys)2Gly and (gamma-Glu-Cys)3Gly was increased at pH 5.0 and below so that Ag(I)/-SH ratio approached 1.0. A similar pH-dependent binding of Ag(I) to glutathione was also observed. The increased Ag(I)-binding to PCs at lower pH is of physiological significance as these peptides accumulate in acidic vacuoles. We also report lifetime data on Ag(I)-PCs. The relatively long decay-times (approximately 0.1-0.3 msec) accompanied with a large Stokes shift in the emission band are indicative of spin-forbidden phosphorescence. PMID

  10. Sport in Germany. Basis-Info: Social Policy. In-Press.

    ERIC Educational Resources Information Center

    Beitz, Steffen

    This report describes sports in Germany, explaining that sport is part of Germany's culture. Popular sports are enjoyed by both the public and private sector. Germany has a well-developed club and association sector. One in three Germans belongs to a sports organization. A major feature of sport in Germany is its autonomy. Popular sports begin in…

  11. Spectroscopic Study on Eu3+ Doped Borate Glasses Containing Ag Nanoparticles and Ag Aggregates.

    PubMed

    Fu, Shaobo; Zheng, Hui; Zhang, Jinsu; Li, Xiangping; Sun, Jiashi; Hua, Ruinian; Dong, Bin; Xia, Haiping; Chen, Baojiu

    2015-01-01

    Transparent Eu(3+)-doped borate glasses containing Ag nanoparticles and Ag aggregates with composition (40 - x) CaO-59.5B2O3-0.5Eu2O3-xAgNO3 were prepared by a simple one-step melt-quenching technique. The X-ray diffraction (XRD) patterns of the glasses reveal amorphous structural properties and no diffraction peaks belonging to metal Ag particles. Ag particles and Ag aggregates were observed from the absorption spectra. Effective energy transfers from the Ag aggregates to the Eu3+ ions were observed in the excitation spectra from monitoring the intrinsic emission of Eu3+x .5D0 --> 7F2. The glasses with higher Ag content can be effectively excited by light in a wide wavelength region, indicating that these glasses have potential application in the solid state lighting driven by semiconductor light emitting diodes (LEDs). The emission spectra of the samples with higher Ag contents exhibit plenteous spectral components covering the full visible region from violet to red, thus indicating that these glass materials possess an excellent and tunable color rendering index. The color coordinates for all the glass samples were calculated by using the intensity-corrected emission spectra and the standard data issued by the CIE (Commission International de l' Eclairage) in 1931. It was found that the color coordinates for most samples with higher Ag contents fall into the white region in the color space. PMID:26328363

  12. Study of antibacterial activity of Ag and Ag2CO3 nanoparticles stabilized over montmorillonite

    NASA Astrophysics Data System (ADS)

    Sohrabnezhad, Sh.; Pourahmad, A.; Mehdipour Moghaddam, M. J.; Sadeghi, A.

    2015-02-01

    Silver carbonate and silver nanoparticles (NPs) over of stabilizer montmorillonite (MMT) have been synthesized in aqueous and polyol solvent, respectively. Dispersions of silver nanoparticles have been prepared by the reduction of silver nitrate over of MMT in presence and absence of Na2CO3 compound in ethylene glycol. It was observed that montmorillonite was capable of stabilizing formed Ag nanoparticles through the reduction of Ag+ ions in ethylene glycol. Na2CO3 was used as carbonate source in synthesis of Ag2CO3 NPs in water solvent and also for controlling of Ag nanoparticles size in ethylene glycol medium. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and ultraviolet-visible diffuse reflectance spectroscopy (DRS). The TEM images showed that Ag NPs size in presence Na2CO3 salts was smaller than without that. The results indicated intercalation of Ag and Ag2CO3 nanoparticles into the montmorillonite clay layers. The diffuse reflectance spectra exhibited a strong surface plasmon resonance (SPR) adsorption peak in the visible region, resulting from Ag nanoparticles. The antibacterial testing results showed that the Ag2CO3-MMT nanocomposite exhibited an antibacterial activity higher than Ag-MMT sample against Escherichia coli.

  13. Monitoring of climate change in Germany - data, products and services of Germany's National Climate Data Centre

    NASA Astrophysics Data System (ADS)

    Kaspar, F.; Müller-Westermeier, G.; Penda, E.; Mächel, H.; Zimmermann, K.; Kaiser-Weiss, A.; Deutschländer, T.

    2013-08-01

    Germany's national meteorological service (Deutscher Wetterdienst, DWD) is the responsible authority for monitoring climate change in Germany. To fulfill this task it operates the National Climate Data Centre ("Nationales KlimaDatenZentrum, NKDZ"). The historical and current instrumental measurements and visual observations of DWD's station network are archived, quality-controlled and used to provide aggregated products, as for example daily and monthly means or climate normals. Gridded data are generated and used to derive time series of national and regional averages. Phenological observations and radiosonde data are also part of the data base. In recent years, additional historical data have been digitized to expand the data base. The products are used for informing the public, e.g. as an element of the German climate atlas (http://www.deutscher-klimaatlas.de). One major recent activity was the provision of information for the new climatological reference interval 1981-2010 and an updated climatological analysis based on the newly digitized data.

  14. Evaluation of two new automated assays for hepatitis B virus surface antigen (HBsAg) detection: IMMULITE HBsAg and IMMULITE 2000 HBsAg.

    PubMed

    Weber, Bernard; Dengler, Thomas; Berger, Annemarie; Doerr, Hans Wilhelm; Rabenau, Holger

    2003-01-01

    In recent years the diagnostic industry has developed new automated immunoassays for the qualitative detection of hepatitis B virus (HBV) surface antigen (HBsAg) in serum and plasma samples that are performed on analyzers that permit a high-speed throughput, random access, and primary tube sampling. The aim of the present study was the evaluation of two new automated HBsAg screening assays, IMMULITE HBsAg and IMMULITE 2000 HBsAg, from Diagnostic Products Corporation. The new HBsAg assays were compared to well-established tests (Auszyme Monoclonal [overnight incubation, version B], IMx HBsAg, AxSYM HBsAg, and Prism HBsAg [all from Abbott] and Elecsys HBsAg [Roche Diagnostics]). In the evaluation were included seroconversion panels, sera from the acute and chronic phases of infection, dilution series of various HBsAg standards, HBV subtypes and S gene mutants. To challenge the specificity of the new assays, sera from HBsAg-negative blood donors, pregnant women, and dialysis and hospitalized patients and potentially cross-reactive samples were investigated. IMMULITE HBsAg and IMMULITE 2000 HBsAg, although not as sensitive as the Elecsys HBsAg assay, were equivalent to the AxSYM HBsAg assay and showed a higher sensitivity than the Auszyme Monoclonal B and IMx HBsAg systems for detection of acute infection in seroconversion panels. The specificities (100%) of both IMMULITE assays on unselected blood donors and potentially interfering samples were comparable to those of the alternative assays after repeated testing. In conclusion, the new IMMULITE HBsAg and IMMULITE 2000 HBsAg assays show a good sensitivity for HBsAg detection compared to other well-established tests. The specificity on repeatedly tested samples was equivalent to that of the alternative assays. The rapid turnaround time, primary tube sampling, and on-board dilution make it an interesting assay system for clinical laboratory diagnosis.

  15. Germany's Option for a Moon Satellite

    NASA Astrophysics Data System (ADS)

    Quantius, Dominik

    The German non-profit amateur satellite organisation AMSAT-Deutschland successfully de-signed, built and launched four HEO satellites in the last three decades. Now they are going to build a satellite to leave the Earth orbit based on their flight-proven P3-D satellite design. Due to energetic constraints the most suitable launch date for the planned P5-A satellite to Mars will be in 2018. To efficiently use the relatively long time gap until launch a possible prior Moon mission came into mind. In co-operation with the DLR-Institute of Space Systems in Bremen, Germany, two studies on systems level for a first P5 satellite towards Moon and a following one towards Mars have been performed. By using the DLR's Concurrent Engineering Facility (CEF) two consistent satellite concepts were designed including mission analysis, configuration, propulsion, subsystem dimensioning, payload selection, budgeting and cost. The present paper gives an insight in the accomplished design process and the results of the performed study towards Moon. The developed Moon orbiter is designed to carry the following four main instruments besides flexible communication abilities: • slewable HDTV camera combined with a high gain antenna that allows receiving lunar television using a commercially available satellite TV dish on Earth • sensor imaging infrared spectrometer for mineralogy of lunar silicates and lunar surface temperature measurements • camera for detection and monitoring of impact flashes in visible light (VIS) on lunar night side caused by meteoroid impact events • camera technology test for interplanetary navigation and planetary approach navigation. This study presents a non-industrial satellite concept that could be launched as piggyback load on Ariane 5 into GTO. Due to the fact, that the satellite would be built by the private sector, the mission costs would remain low. Otherwise the scientific and public output would be high using that satellite bus for the instruments

  16. Demonstration and partial characterization of 22-nm HBsAg and Dane particles of subtype HBsAg/ady.

    PubMed

    Hess, G; Shih, J W; Arnold, W; Gerin, J L; zum Büschenfelde, K H

    1979-09-01

    The present paper describes the demonstration of d, y, w, and r HBsAg determinants in one serum. It was shown that there are two populations of HBsAg particles: HBsAg/ad and HBsAg/ady. All complete Dane particles were of subtype HBsAg/ady. Further characterization of HBsAg/ady particles did not reveal morphologic differences when they were compared with HBsAg/ad and HBsAg/ay particles. An HBsAg/ady phenotype may be the result of a double infection with hepatitis B viruses or exchanges of DNA sequences that determine HBsAg/ay and HBsAg/ad to form a new genotype. PMID:89163

  17. Demonstration and partial characterization of 22-nm HBsAg and Dane particles of subtype HBsAg/ady.

    PubMed

    Hess, G; Shih, J W; Arnold, W; Gerin, J L; zum Büschenfelde, K H

    1979-09-01

    The present paper describes the demonstration of d, y, w, and r HBsAg determinants in one serum. It was shown that there are two populations of HBsAg particles: HBsAg/ad and HBsAg/ady. All complete Dane particles were of subtype HBsAg/ady. Further characterization of HBsAg/ady particles did not reveal morphologic differences when they were compared with HBsAg/ad and HBsAg/ay particles. An HBsAg/ady phenotype may be the result of a double infection with hepatitis B viruses or exchanges of DNA sequences that determine HBsAg/ay and HBsAg/ad to form a new genotype.

  18. Hepatitis B outbreak in a nursing home associated with reusable lancet devices for blood glucose monitoring, Northern Germany 2010.

    PubMed

    Diercke, Michaela; Monazahian, Masyar; Petermann, Holger; Gerlich, Wolfram H; Schüttler, Christian G; Wend, Ulrike; Dehnert, Manuel; Dreesman, Johannes

    2015-04-01

    In September 2010, an outbreak of acute hepatitis B virus (HBV) infections in a nursing home was notified to public health authorities in Northern Germany. To identify the route of transmission and prevent further cases a retrospective cohort study was conducted. Blood samples of residents were tested for serologic markers of HBV infection and HBV subgenotypes and sequences were analyzed. Outbreak-related cases were defined as residents of the nursing home with detection of hepatitis B surface antigen (HBsAg) and the HBV DNA sequence of the outbreak strain in 2010. Information on possible risk factors as patient care, invasive diagnostic, and therapeutical procedures was collected using a standardized questionnaire. Risk ratios (RR) and 95% confidence intervals (CI) were estimated with exact Poisson regression and binomial regression. Sixty-four residents were included in the study, 5 of them were outbreak-related cases, 12 had a past HBV infection. The outbreak strain belonged to HBV genotype D2 (HBsAg subtype ayw3, Ala118) which is not prevalent in Germany but in Eastern Europe. All cases (median age 81) were female, had diabetes, blood glucose monitoring, and chiropody. In multivariable analysis only blood glucose monitoring was associated with HBV infection (RR = 22, 95%CI 3.0-∞). Blood glucose monitoring was reported to be done by nursing home staff with patient-based reusable lancet devices. In nursing home settings the use of single use lancets for blood glucose monitoring is recommended strongly to prevent transmission. National guidelines on the handling of point-of-care devices and reusable equipment in long-term care facilities should be developed.

  19. Modified Surface Coatings and their Effect on Drug Adsorption within the Extracorporeal Life Support Circuit

    PubMed Central

    Preston, Thomas J.; Ratliff, Todd M.; Gomez, Daniel; Olshove, Vincent F.; Nicol, Kathleen K.; Sargel, Cheryl L.; Chicoine, Louis G.

    2010-01-01

    Abstract: A recently completed study quantified the percent of fentanyl or morphine sulfate lost to uncoated polyvinylchloride (PVC) tubing or to one of two hollow fiber oxygenators within the extracorporeal life support (ECLS) circuit. The results demonstrated the majority of drug loss was due to adsorption by the PVC tubing. The purpose of this study was to determine if a tubing coating process affects fentanyl or morphine Sulfate adsorption. The goal was to quantify fentanyl or morphine sulfate lost due to adhesion within surface modified tubing. The following surface modifications were studied: 1) Maquet Safeline® (synthetic immobilized albumin); 2) Maquet Softline® (a heparin free biopassive polymer); 3) Maquet Bioline® (recombinant human albumin + heparin) (Maquet Cardiopulmonary AG, Hirrlingen, Germany); 4) Terumo X Coating™ (poly2methoxylacrylate)) (Terumo Cardiovascular Systems Corporation, Ann Arbor, MI); 5) Medtronic Carmeda® (covalently bonded heparin); and 6) Medtronic Trillium® (covalently bonded heparin) (Medtronic, Minneapolis, MN). A total of 36 individual circuits were built from the above six available modified surface coatings, for a total of six individual circuits of each coating type. Blood samples were drawn at 5 minutes, 120 minutes, and 360 minutes followed by High-Performance Liquid Chromatography to determine available circulating levels of either fentanyl or morphine sulfate. Fentanyl concentrations decreased to an average final available concentration of 35% (±5%) within the 18 circuits. Morphine sulfate however, decreased to a final available concentration of 57% (±1%) in all Maquet tubing and the Medtronic Trillium tubing, while it decreased to a final concentration of 35% (±1%) in the Medtronic Carmeda coated tubing and in the Terumo X Coating tubing. Biocompatible ECLS circuit surface coatings affected drug-adsorption and availability. Further evaluation is necessary to understand the adsorptive loss of other drugs

  20. Agent planning in AgScala

    NASA Astrophysics Data System (ADS)

    Tošić, Saša; Mitrović, Dejan; Ivanović, Mirjana

    2013-10-01

    Agent-oriented programming languages are designed to simplify the development of software agents, especially those that exhibit complex, intelligent behavior. This paper presents recent improvements of AgScala, an agent-oriented programming language based on Scala. AgScala includes declarative constructs for managing beliefs, actions and goals of intelligent agents. Combined with object-oriented and functional programming paradigms offered by Scala, it aims to be an efficient framework for developing both purely reactive, and more complex, deliberate agents. Instead of the Prolog back-end used initially, the new version of AgScala relies on Agent Planning Package, a more advanced system for automated planning and reasoning.

  1. A FLYING WIRE SYSTEM IN THE AGS.

    SciTech Connect

    HUANG,H.; BUXTON,W.; MAHLER,G.; MARUSIC,A.; ROSER,T.; SMITH,G.; SYPHERS,M.; WILLIAMS,N.; WITKOVER,R.

    1999-03-29

    As the AGS prepares to serve as the injector for RHIC, monitoring and control of the beam transverse emittance become a major and important topic. Before the installation of the flying wire system, the emittance was measured with ionization profile monitors in the AGS, which require correction for space charge effects. It is desirable to have a second means of measuring profile that is less depend on intensity. A flying wire system has been installed in the AGS recently to perform this task. This paper discusses the hardware and software setup and the capabilities of the system.

  2. Crystallization kinetics of {alpha}-AgI in AgI-based silver orthoborate glasses

    SciTech Connect

    Taniguchi, Akihiro; Tatsumisago, Masahiro; Minami, Tsutomu

    1995-02-01

    Kinetics for nucleation and growth of {alpha}-AgI crystals in AgI-based silver orthoborate glasses, in which only {alpha}-AgI crystals were found to crystallize in the heating process of the glasses, were studied by isothermal and nonisothermal measurements using differential scanning calorimetry and by observations of the microstructure of the glasses using scanning electron microscopy. The values of both n and m, dependent on the crystallization mechanism, were found to be 3, indicating that a constant number of nuclei of {alpha}-AgI precipitated in a glass matrix grew three-dimensionally. The preannealing of the glasses at temperatures between glass transition and crystallization did not affect the DSC isothermal curves in the crystal growth process, which suggested that the number of {alpha}-AgI nuclei would have been saturated in the glass when the glasses were prepared by quenching the AgI-based melts.

  3. Extranuclear dynamics of 111Ag(→111Cd) doped in AgI nanoparticles

    NASA Astrophysics Data System (ADS)

    Sato, W.; Mizuuchi, R.; Irioka, N.; Komatsuda, S.; Kawata, S.; Taoka, A.; Ohkubo, Y.

    2014-08-01

    Dynamic behavior of the extranuclear field relative to the 111Ag(→111Cd) probe nucleus introduced in a superionic conductor silver iodide (AgI) was investigated by means of the time-differential perturbed angular correlation technique. For poly-N-vinyl-2-pyrrolidone (PVP)-coated AgI nanoparticles, we observed nuclear spin relaxation of the probe at room temperature. This result signifies that Ag+ ions in the polymer-coated sample make hopping motion from site to site at this low temperature. The activation energy for the dynamic motion was successfully estimated to be 46(10) meV. The first atomic-level observation of the temperature-dependent dynamic behavior of Ag+ ions in the polymer-coated AgI is reported.

  4. Ag induced electromagnetic interference shielding of Ag-graphite/PVDF flexible nanocomposites thinfilms

    NASA Astrophysics Data System (ADS)

    Kumaran, R.; Alagar, M.; Dinesh Kumar, S.; Subramanian, V.; Dinakaran, K.

    2015-09-01

    We report Ag nanoparticle induced Electromagnetic Interference (EMI) shielding in a flexible composite films of Ag nanoparticles incorporated graphite/poly-vinylidene difluoride (PVDF). PVDF nanocomposite thin-films were synthesized by intercalating Ag in Graphite (GIC) followed by dispersing GIC in PVDF. The X-ray diffraction analysis and the high-resolution transmission electron microscope clearly dictate the microstructure of silver nanoparticles in graphite intercalated composite of PVDF matrix. The conductivity values of nanocomposites are increased upto 2.5 times when compared to neat PVDF having a value of 2.70 S/cm at 1 MHz. The presence of Ag broadly enhanced the dielectric constant and lowers the dielectric loss of PVDF matrix proportional to Ag content. The EMI shielding effectiveness of the composites is 29.1 dB at 12.4 GHz for the sample having 5 wt. % Ag and 10 wt. % graphite in PVDF.

  5. Control and performance of the AGS and AGS Booster Main Magnet Power Supplies

    SciTech Connect

    Reece, R.K.; Casella, R.; Culwick, B.; Geller, J.; Marneris, I.; Sandberg, J.; Soukas, A.; Zhang, S.Y.

    1993-01-01

    Techniques for precision control of the main magnet power supplies for the AGS and AGS Booster synchrotron will be discussed. Both synchrotrons are designed to operate in a Pulse-to-Pulse Modulation (PPM) environment with a Supercycle Generator defining and distributing global timing events for the AGS Facility. Details of modelling, real-time feedback and feedforward systems, generation and distribution of real time field data, operational parameters and an overview of performance for both machines are included.

  6. Control and performance of the AGS and AGS Booster Main Magnet Power Supplies

    SciTech Connect

    Reece, R.K.; Casella, R.; Culwick, B.; Geller, J.; Marneris, I.; Sandberg, J.; Soukas, A.; Zhang, S.Y.

    1993-06-01

    Techniques for precision control of the main magnet power supplies for the AGS and AGS Booster synchrotron will be discussed. Both synchrotrons are designed to operate in a Pulse-to-Pulse Modulation (PPM) environment with a Supercycle Generator defining and distributing global timing events for the AGS Facility. Details of modelling, real-time feedback and feedforward systems, generation and distribution of real time field data, operational parameters and an overview of performance for both machines are included.

  7. [The hospital at Hillersleben Germany, April 1945].

    PubMed

    Weisskopf, Varda

    2014-01-01

    On 6th April 1945, nine days before the liberation of the Bergen Belsen Concentration Camp, about 2,500 Jewish prisoners were ordered to prepare to leave the camp on the next day. On 7th April, the prisoners left through the gates of the camp and began to walk about 10 kilometers to the train station near the city of Celle. There they were ordered to board a train that would take them to the Theresienstadt Concentration Camp. After six days of travel, the train stopped near the village of Farsleben, Germany, where it was liberated by the 743rd Tank Battalion of the 30th Infantry Division, of the U.S. 9th Army, on 13th April 1945. The 105th Medical Battalion of the same Division was the primary care provider for the survivors, who were then taken in vehicles available from the 30th Infantry Division, and organized into a convoy by the Division's Liaison Officer, Lt. Frank W. Towers, to the town of Hillersleben. A former German Air Force Base was located at Hillersleben with a small hospital that could not provide medical attention to all the survivors. On 21st April, Company C of the 95th Medical Battalion, received an order to go to Hillersleben. Colonel Dr. William W. Hurteau, the Commanding Officer of this Battalion, determined that the biggest task given to the Battalion during World War II, was establishing another hospital in the town of Hillersleben and providing additional beds in the existing hospital, which was a structure that had served as a boarding school. Furthermore, they needed to acquire hospital equipment which was obtained from German equipment and supplies that had been captured by the U.S. MiLitary. Also, they took care of obtaining food supplies from German warehouses, and meat and milk from local dairy farms. The lives of the prisoners on this train were saved by the heroism and dedicated work of those brave soldiers of the 30th Infantry Division and the 95th Medical Battalion. PMID:24791569

  8. Intake of intense sweeteners in Germany.

    PubMed

    Bär, A; Biermann, C

    1992-03-01

    The dietary intake of aspartame, cyclamate, and saccharin was evaluated in Germany (FRG) in 1988/89. In the first part of the study the sweetener intake was evaluated in a representative sample of the population. Complete 24-h records of the amount and type of all foods and drinks consumed were obtained from 2,291 individuals. The total daily intake was calculated for each person from the sweetener content of each product and was expressed in mg/kg body weight (bw). 35.9% of the participants ingested one or more sweeteners on the examination day. Cyclamate and saccharin were the prominent sweeteners because aspartame was at that time permitted only under special regulatory exemption, and products containing acesulfame were not yet available. For users of intense sweeteners the mean intakes of aspartame, cyclamate, and saccharin were 0.15, 2.62, and 0.250 mg/kg bw/day, respectively. At the 90th percentile of intake, i.e., for the heavy consumer, the ingestion of cyclamate and saccharin was about 2.5 times higher. Persons who adhered to a diet (diabetes, weight control) did not ingest sweeteners in substantially higher amounts. Tabletop sweeteners and beverages were the most important sources of sweeteners, and they contributed more than 80% of the total intake. Consumption of sweeteners in excess of the Acceptable Daily Intake (ADI) was rarely observed (saccharin: one person, cyclamate: 16 persons). In the second part of the study, the sweetener intake was further evaluated during a 7-day period in those subjects who in the 1-day study ingested any of the sweeteners in excess of 75% of the ADI. Complete 7-day food records were available from 40 out of the 41 subjects who fulfilled this criterium. In this selected subgroup in which 19 subjects were less than 19 years old, the mean daily intakes of aspartame, cyclamate, and saccharin were 0.13, 4.53, and 0.42 mg/kg body weight (bw), respectively. These levels correspond to 0.33, 41 and 17% of the corresponding ADI

  9. Nanoporous Ag prepared from the melt-spun Cu-Ag alloys

    NASA Astrophysics Data System (ADS)

    Li, Guijing; Song, Xiaoping; Sun, Zhanbo; Yang, Shengchun; Ding, Bingjun; Yang, Sen; Yang, Zhimao; Wang, Fei

    2011-07-01

    Nanoporous Ag ribbons with different morphology and porosity were achieved by the electrochemical corrosion of the melt-spun Cu-Ag alloys. The Cu-rich phase in the alloys was removed, resulting in the formation of the nanopores distributed across the whole ribbon. It is found that the structures, morphology and porosity of the nanoporous Ag ribbons were dependent on the microstructures of the parent alloys. The most of ligaments presented a rod-like shape due to the formation of pseudoeutectic microstructure in the melt-spun Cu 55Ag 45 and Cu 70Ag 30 alloys. For nanoporous Ag prepared from Cu 85Ag 15 alloys, the ligaments were camber-like because of the appearance of the divorced microstructures. Especially, a novel bamboo-grove-like structure could be observed at the cross-section of the nanoporous Ag ribbons. The experiment reveals that nanoporous Ag ribbons exhibited excellent enhancement of surface-enhanced Raman scattering (SERS) effect, but a slight difference existed due to the discrepancy of their morphology.

  10. Near-infrared emitting AgInTe2 and Zn-Ag-In-Te colloidal nanocrystals

    NASA Astrophysics Data System (ADS)

    Langevin, Marc-Antoine; Pons, Thomas; Ritcey, Anna M.; Nì. Allen, Claudine

    2015-06-01

    The synthesis of AgInTe2 nanocrystals emitting between 1095 nm and 1160 nm is presented. Evolution of the Ag:In:Te ratio shows progressive incorporation of In3+ in Ag2Te, leading to the formation of orthorhombic AgInTe2. When zinc is added to the synthesis, the photoluminescence quantum yield reaches 3.4 %.

  11. Redetermination of AgPO3

    PubMed Central

    Terebilenko, Katherina V.; Zatovsky, Igor V.; Ogorodnyk, Ivan V.; Baumer, Vyacheslav N.; Slobodyanik, Nikolay S.

    2011-01-01

    Single crystals of silver(I) polyphosphate(V), AgPO3, were prepared via a phospho­ric acid melt method using a solution of Ag3PO4 in H3PO4. In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779–784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO5] polyhedra, giving rise to multidirectional ribbons, and from two types of PO4 tetra­hedra linked into meandering chains (PO3)n spreading parallel to the b axis with a repeat unit of four tetra­hedra. The calculated bond-valence sum value of one of the two AgI ions indicates a significant strain of the structure. PMID:21522230

  12. Redetermination of AgPO(3).

    PubMed

    Terebilenko, Katherina V; Zatovsky, Igor V; Ogorodnyk, Ivan V; Baumer, Vyacheslav N; Slobodyanik, Nikolay S

    2011-02-09

    Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhedra, giving rise to multidirectional ribbons, and from two types of PO(4) tetra-hedra linked into meandering chains (PO(3))(n) spreading parallel to the b axis with a repeat unit of four tetra-hedra. The calculated bond-valence sum value of one of the two Ag(I) ions indicates a significant strain of the structure.

  13. Redetermination of AgPO(3).

    PubMed

    Terebilenko, Katherina V; Zatovsky, Igor V; Ogorodnyk, Ivan V; Baumer, Vyacheslav N; Slobodyanik, Nikolay S

    2011-01-01

    Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhedra, giving rise to multidirectional ribbons, and from two types of PO(4) tetra-hedra linked into meandering chains (PO(3))(n) spreading parallel to the b axis with a repeat unit of four tetra-hedra. The calculated bond-valence sum value of one of the two Ag(I) ions indicates a significant strain of the structure. PMID:21522230

  14. Exposure-dependent Ag+ release from silver nanoparticles and its complexation in AgS2 sites in primary murine macrophages

    NASA Astrophysics Data System (ADS)

    Veronesi, G.; Aude-Garcia, C.; Kieffer, I.; Gallon, T.; Delangle, P.; Herlin-Boime, N.; Rabilloud, T.; Carrière, M.

    2015-04-01

    Silver nanoparticle (AgNP) toxicity is related to their dissolution in biological environments and to the binding of the released Ag+ ions in cellulo; the chemical environment of recombined Ag+ ions is responsible for their toxicological outcome, moreover it is indicative of the cellular response to AgNP exposure, and can therefore shed light on the mechanisms governing AgNP toxicity. This study probes the chemistry of Ag species in primary murine macrophages exposed to AgNPs by making use of X-ray Absorption Fine Structure spectroscopy under cryogenic conditions: the linear combination analysis of the near-edge region of the spectra provides the fraction of Ag+ ions released from the AgNPs under a given exposure condition and highlights their complexation with thiolate groups; the ab initio modelling of the extended spectra allows measuring the Ag-S bond length in cellulo. Dissolution rates depend on the exposure scenario, chronicity leading to higher Ag+ release than acute exposure; Ag-S bond lengths are 2.41 +/- 0.03 Å and 2.38 +/- 0.01 Å in acute and chronic exposure respectively, compatible with digonal AgS2 coordination. Glutathione is identified as the most likely putative ligand for Ag+. The proposed method offers a scope for the investigation of metallic nanoparticle dissolution and recombination in cellular models.Silver nanoparticle (AgNP) toxicity is related to their dissolution in biological environments and to the binding of the released Ag+ ions in cellulo; the chemical environment of recombined Ag+ ions is responsible for their toxicological outcome, moreover it is indicative of the cellular response to AgNP exposure, and can therefore shed light on the mechanisms governing AgNP toxicity. This study probes the chemistry of Ag species in primary murine macrophages exposed to AgNPs by making use of X-ray Absorption Fine Structure spectroscopy under cryogenic conditions: the linear combination analysis of the near-edge region of the spectra provides

  15. AgRISTARS documents tracking list report

    NASA Technical Reports Server (NTRS)

    Hawkins, J. L.

    1982-01-01

    A quarterly listing of those documents and related publications that have been issued and placed in the AgRISTARS tracking system is presented. The Tracking List Report provides a catalog, by project, of technical publications arranged by type of document and gives the reference AgRISTARS document numbers, title and date of publication, the issuing organization, and the National Technical Information Service reference number.

  16. 20% PARTIAL SIBERIAN SNAKE IN THE AGS.

    SciTech Connect

    Huang, H; Bai, M; Brown, K A; Glenn, W; Luccio, A U; Mackay, W W; Montag, C; Ptitsyn, V; Roser, T; Tsoupas, N; Zeno, K; Ranjbar, V; Spinka, H; Underwood, D

    2002-11-06

    An 11.4% partial Siberian snake was used to successfully accelerate polarized proton through a strong intrinsic depolarizing spin resonance in the AGS. No noticeable depolarization was observed. This opens up the possibility of using a 20% to 30% partial Siberian snake in the AGS to overcome all weak and strong depolarizing spin resonances. Some design and operation issues of the new partial Siberian snake are discussed.

  17. Acceleration of polarized protons in the AGS

    SciTech Connect

    Tsoupas, N.; Ahrens, L.; Bai, M.; Brown, K.; Courant, E.; Glenn, J.W.; Huang, H.; Luccio, A.; MacKay, W.W.; Roser, T.; Schoefer, V.; Zeno, K.

    2010-02-25

    The high energy (s{sup 1/2} = 500 GeV) polarized proton beam experiments performed in RHIC, require high polarization of the proton beam. With the AGS used as the pre-injector to RHIC, one of the main tasks is to preserve the polarization of the proton beam, during the beam acceleration in the AGS. The polarization preservation is accomplished by the two partial helical magnets [1,2,3,4,5,6,7] which have been installed in AGS, and help overcome the imperfection and the intrinsic spin resonances which occur during the acceleration of protons. This elimination of the intrinsic resonances is accomplished by placing the vertical tune Q{sub y} at a value close to 8.98, within the spin-tune stop-band created by the snake. At this near integer tune the perturbations caused by the partial helical magnets is large resulting in large beta and dispersion waves. To mitigate the adverse effect of the partial helices on the optics of the AGS, we have introduced compensation quads[2] in the AGS. In this paper we present the beam optics of the AGS which ameliorates this effect of the partial helices.

  18. A visible-light-driven core-shell like Ag2S@Ag2CO3 composite photocatalyst with high performance in pollutants degradation.

    PubMed

    Yu, Changlin; Wei, Longfu; Zhou, Wanqin; Dionysiou, Dionysios D; Zhu, Lihua; Shu, Qing; Liu, Hong

    2016-08-01

    A series of Ag2S-Ag2CO3 (4%, 8%, 16%, 32% and 40% Ag2S), Ag2CO3@Ag2S (32%Ag2S) and Ag2S@Ag2CO3 (32%Ag2S) composite photocatalysts were fabricated by coprecipitation or successive precipitation reaction. The obtained catalysts were analyzed by N2 physical adsorption, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, UV-vis diffuse reflectance spectroscopy and photocurrent test. Under visible light irradiation, the influences of Ag2S content and core-shell property on photocatalytic activity and stability were evaluated in studies focused on the degradation of methyl orange (MO) dye, phenol, and bisphenol A. Results showed that excellent photocatalytic performance was obtained over Ag2S/Ag2CO3 composite photocatalysts with respect to Ag2S and Ag2CO3. With optimal content of Ag2S (32 wt%), the Ag2S-Ag2CO3 showed the highest photocatalytic degradation efficiency. Moreover, the structured property of Ag2S/Ag2CO3 greatly influenced the activity. Compared with Ag2S-Ag2CO3 and Ag2CO3@Ag2S, core-shell like Ag2S@Ag2CO3 demonstrated the highest activity and stability. The main reason for the boosting of photocatalytic performance was due to the formation of Ag2S/Ag2CO3 well contacted interface and unique electron structures. Ag2S/Ag2CO3 interface could significantly increase the separation efficiency of the photo-generated electrons (e(-)) and holes (h(+)), and production of OH radicals. More importantly, the low solubility of Ag2S shell could effectively protect the core of Ag2CO3, which further guarantees the stability of Ag2CO3. PMID:27236845

  19. Investigation of the structure of a Ag/Pd/Ag( 1 1 1 ) trilayer by means of electronic spectroscopies

    NASA Astrophysics Data System (ADS)

    Dumont, J.; Ghijsen, J.; Sporken, R.

    2002-06-01

    The growth of the Ag/Pd/Ag system has been studied by X-ray photoelectron spectroscopy and low energy electron diffraction. No chemical reaction or interdiffusion was observed between the Pd and Ag layers. The growth of the Pd interlayer follows the Frank Van der Merwe mode but is not pseudomorphic on the Ag(1 1 1) substrate. The growth of the top Ag layer on the Pd interlayer is pseudomorphic and layer by layer but contains around 12% of voids.

  20. Space Radar Image of North Sea, Germany

    NASA Technical Reports Server (NTRS)

    1994-01-01

    This is an X-band image of an oil slick experiment conducted in the North Sea, Germany. The image is centered at 54.58 degrees north latitude and 7.48 degrees east longitude. This image was acquired by the Spaceborne Imaging Radar-C and X-band Synthetic Aperture Radar (SIR-C/X-SAR) aboard the space shuttle Endeavour on October 6, 1994, during the second flight of the spaceborne radar. The experiment was designed to differentiate between petroleum oil spills and natural slicks floating on the sea surface. Two types of petroleum oil and six types of oils resembling natural sea surface slicks were poured on the sea surface from ships and a helicopter just before the space shuttle flew over the region. At the bottom of the image is the Sylt peninsula, a famous holiday resort. Twenty-six gallons (100 liters) of diesel oil was dissipated due to wave action before the shuttle reached the site. The oil spill seen at the uppermost part of the image is about 105 gallons (400 liters) of heavy heating oil and the largest spill is about 58 gallons (220 liters) of oleyl alcohol, resembling a 'natural oil' like the remaining five spills used to imitate natural slicks that have occurred offshore from various states. The volume of these other oils spilled on the ocean surface during the five experimental spills varied from 16 gallons to 21 gallons (60 liters to 80 liters). The distance between neighboring spills was about half a mile (800 meters) at the most. The largest slick later thinned out to monomolecular sheets of about 10 microns, which is the dimension of a molecule. Oceanographers found that SIR-C/X-SAR was able to clearly distinguish the oil slicks from algae products dumped nearby. Preliminary indications are that various types of slicks may be distinguished, especially when other radar wavelengths are included in the analysis. Radar imaging of the world's oceans on a continuing basis may allow oceanographers in the future to detect and clean up oil spills much more

  1. Regional climate service in Southern Germany

    NASA Astrophysics Data System (ADS)

    Schipper, Janus; Hackenbruch, Julia

    2013-04-01

    Climate change challenges science, politics, business and society at the international, national and regional level. The South German Climate Office at the Karlsruhe Institute of Technology (KIT) is a contact for the structuring and dissemination of information on climate and climate change in the South German region. It provides scientifically based and user-oriented climate information. Thereby it builds a bridge between the climate sciences and society and provides scientific information on climate change in an understandable way. The expertise of KIT, in which several institutions operate on fundamental and applied climate research, and of partner institutions is the basis for the work in the climate office. The regional focus is on the south of Germany. Thematic focuses are e.g. regional climate modeling, trends in extreme weather events such as heavy rain and hail event, and issues for energy and water management. The South German Climate Office is one of four Regional Helmholtz Climate Offices, of which each has a regional and thematic focus. The users of the Climate Office can be summarized into three categories. First, there is the general public. This category consists mainly of non-professionals. Here, special attention is on an understandable translation of climate information. Attention is paid to application-related aspects, because each individual is affected in a different way by climate change. Typical examples of this category are school groups, citizens and the media. The second category consists of experts of other disciplines. Unlike the first category they are mainly interested in the exchange of results and data. It is important to the climate office to provide support for the use of climatological results. Typical representatives of this category are ministries, state offices, and companies. In the third and final category are scientists. In addition to the climatologists, this category also holds representatives from other scientific

  2. Space Radar Image of Oberpfaffenhofen, Germany

    NASA Technical Reports Server (NTRS)

    1999-01-01

    This is a false-color, three-frequency image of the Oberpfaffenhofen supersite, southwest of Munich in southern Germany, which shows the differences in what the three radar bands can see on the ground. The image covers a 27- by 36-kilometer (17- by 22-mile) area. The center of the site is 48.09 degrees north and 11.29 degrees east. The image was acquired by the Spaceborne Imaging Radar C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) onboard space shuttle Endeavour on April 13, 1994, just after a heavy storm which covered the all area with 20 centimeters (8 inches) of snow. The dark area in the center of the image is Lake Ammersee. The two smaller lakes above the Ammersee are the Worthsee and the Pilsensee. On the right of the image is the tip of the Starnbergersee. The outskirt of the city of Munich can be seen at the top of the image. The Oberpfaffenhofen supersite is the major test site for X-SAR calibration and scientific experiments such as ecology, hydrology and geology. This color composite image is a three-frequency overlay. L-band total power was assigned red, the C-band total power is shown in green and the X-band VV polarization appears blue. The colors on the image stress the differences between the L-band, C-band and X-band images. If the three frequencies were seeing the same thing, the image will appear in black and white. For example, the blue areas corresponds to area for which the X-band backscatter is relatively higher than the backscatter at L-and C-band; this behavior is characteristic of clear cuts or shorter vegetation. Similarly, the forested areas have a reddish tint. Finally, the green areas seen at the southern tip of both the Ammersee and the Pilsensee lakes indicate a marshy area. Spaceborne Imaging Radar-C and X-Synthetic Aperture Radar (SIR-C/X-SAR) is part of NASA's Mission to Planet Earth. The radars illuminate Earth with microwaves allowing detailed observations at any time, regardless of weather or sunlight conditions. SIR

  3. The Integrated Carbon Observation System in Germany

    NASA Astrophysics Data System (ADS)

    Kutsch, Werner Leo

    2013-04-01

    will enable the researchers to calculate the European carbon fluxes with a resolution of 10 km. The ICOS-D Atmospheric Observational Network for Germany, when fully established, will comprise 9 atmospheric sites. In the Ocean Program, volunteer observing ships (VOS) plying regular routes in the Atlantic Ocean and the Baltic Sea will be instrumented to make autonomous observations of physical and biochemical parameters (temperature, salinity) and sea surface fugacity of CO2 (fCO2). In addition, two ocean observatories at the Cape Verde Islands and Svalbard ('Hausgarten') will be part of the long-term research infrastructure. The Terrestrial Ecosystem Program will provide continuous measurements of trace gas fluxes between ecosystems and the atmosphere. The measurements will be conducted in forests, grasslands, croplands and wetlands and will partly build on sites that have been run for a decade or more in the framework of EU-projects such as CarboEuropeIP. The Terrestrial Ecosystem Program will be designed in 5 - 6 clusters. A cluster is a group of sites at close range but under different land use. This will ensure high representativeness for climate, soils properties and regional land use criteria. The CAL will provide calibration gases for the entire network in order to minimize offsets and calibration uncertainties between the measurements at different stations. It will further provide a centralized analysis of grab samples taken within the whole ICOS RI network for additional trace gases and isotope ratios, including radiocarbon which provides an independent method to quantify regional fossil fuel emissions.

  4. Facile synthesis of sunlight-driven AgCI:Ag plasmonic nanophotocatalyst.

    SciTech Connect

    An, C.; Peng, S.; Sun, Y.; Center for Nanoscale Materials; Univ. of Illinois

    2010-06-18

    Highly efficient plasmonic photocatalysts of AgCl:Ag hybrid nanoparticles are successfully synthesized via a one-pot synthetic approach involving a precipitation reaction followed by polyol reduction. The as-synthesized nanoparticles exhibit high catalytic performance under visible light and sunlight for decomposing organics, such as methylene blue.

  5. Beet Juice-Induced Green Fabrication of Plasmonic AgCl/Ag Nanoparticles

    EPA Science Inventory

    A simple, green, and fast approach (complete within 5 min) was explored for the fabrication of hybrid AgCl/Ag plasmonic nanoparticles under microwave (MW) irradiation. In this method, beet juice served as a reducing reagent, which is an abundant sugar-rich agricultural produce. I...

  6. Ultra-Fast Synthesis for Ag2Se and CuAgSe Thermoelectric Materials

    NASA Astrophysics Data System (ADS)

    DUAN, H. Z.; LI, Y. L.; ZHAO, K. P.; QIU, P. F.; SHI, X.; CHEN, L. D.

    2016-10-01

    Ag2Se and CuAgSe have been recently reported as promising thermoelectric materials at room temperature. The traditional melting-annealing-sintering processes are used to grow Ag2Se and CuAgSe materials with the disadvantages of high costs of energy and time. In this work, phase-pure polycrystalline Ag2Se and CuAgSe compounds were synthesized from raw elemental powders directly by manual mixing followed by spark plasma sintering (MM-SPS) in a few minutes. The influence of SPS heating rate on the phase composition, microstructure, and thermoelectric properties, including Seebeck coefficient, electrical conductivity, and thermal conductivity, were investigated. The zTs of 0.8 at 390 K and 0.6 at 450 K are obtained for Ag2Se and CuAgSe, respectively, which is comparable with the values in the materials prepared by the traditional method. Furthermore, this ultrafast sample synthesis can significantly save material synthesis time and thus has the obvious advantage for large-scale production.

  7. EXAFS Studies of Bimetallic Ag-Pt and Ag-Pd Nanorods

    SciTech Connect

    Lahiri, D.; Chattopadhyay, S.; Bunker, B.A.; Doudna, C.M.; Bertino, M.F.; Blum, F.; Tokuhiro, A.; Terry, J.

    2008-10-30

    Nanoparticles of Ag-Pt and Ag-Pd with high aspect ratios were synthesized using a radiolysis method. Gamma rays at dose rates below 0.5 kGy/h were used for irradiation. The nanoparticles were characterized by transmission electron microscopy (TEM), optical absorption spectroscopy and x-ray Absorption Fine Structure (XAFS) spectroscopy. Bright field micrographs show that Ag-Pt nanowires are composed of large particles with diameters ranging from 20-30 nm and joined by filaments of diameter between 2-5 nm. The Ag-Pd nanowires have diameters of 20-25 nm and lengths of 1.5 {micro}m. For XAFS measurements, the Pt L3 edge (11.564 keV), Ag K-edge (25.514 keV) and Pd K-edge (24.350 keV) were excited to determine the local structure around the respective atoms in the cluster. The Ag-Pt particles were found to possess a distinct core-shell structure with Pt in the core surrounded by Ag shell, with no indication of alloy formation. However, nanorods of Ag-Pd have formed an alloy for all the alloy compositions.

  8. Ultra-Fast Synthesis for Ag2Se and CuAgSe Thermoelectric Materials

    NASA Astrophysics Data System (ADS)

    DUAN, H. Z.; LI, Y. L.; ZHAO, K. P.; QIU, P. F.; SHI, X.; CHEN, L. D.

    2016-06-01

    Ag2Se and CuAgSe have been recently reported as promising thermoelectric materials at room temperature. The traditional melting-annealing-sintering processes are used to grow Ag2Se and CuAgSe materials with the disadvantages of high costs of energy and time. In this work, phase-pure polycrystalline Ag2Se and CuAgSe compounds were synthesized from raw elemental powders directly by manual mixing followed by spark plasma sintering (MM-SPS) in a few minutes. The influence of SPS heating rate on the phase composition, microstructure, and thermoelectric properties, including Seebeck coefficient, electrical conductivity, and thermal conductivity, were investigated. The zTs of 0.8 at 390 K and 0.6 at 450 K are obtained for Ag2Se and CuAgSe, respectively, which is comparable with the values in the materials prepared by the traditional method. Furthermore, this ultrafast sample synthesis can significantly save material synthesis time and thus has the obvious advantage for large-scale production.

  9. Ultra-sensitive detection of Ag+ ions based on Ag+-assisted isothermal exponential degradation reaction.

    PubMed

    Zhao, Jing; Fan, Qi; Zhu, Sha; Duan, Aiping; Yin, Yongmei; Li, Genxi

    2013-01-15

    Ag(+) ions are greatly toxic to a lot of algae, fungi, viruses and bacteria, which can also induce harmful side-effects to environments and human health. Herein we report an ultra-sensitive method for the selective detection of Ag(+) ions with electrochemical technique based on Ag(+)-assisted isothermal exponential degradation reaction. In the presence of Ag(+), mismatched trigger DNA can transiently bind to template DNA immobilized on an electrode surface through the formation of C-Ag(+)-C base pair, which then initiates the isothermal exponential degradation reaction. As a result, the mismatched trigger DNA may melt off the cleaved template DNA to trigger rounds of elongation and cutting. After the cyclic degradation reactions, removal of the template DNA immobilized on the electrode surface can be efficiently monitored by using electrochemical technique to show the status of the electrode surface, which can be then used to determine the presence of Ag(+). Further studies reveal that the proposed method can be ultra-sensitive to detect Ag(+) at a picomolar level. The selectivity of the detection can also be satisfactory, thus the proposed method for the Ag(+) ions detection may be potentially useful in the future. PMID:22921090

  10. Ag on Si(111) from basic science to application

    SciTech Connect

    Belianinov, Aleksey

    2012-01-01

    In our work we revisit Ag and Au adsorbates on Si(111)-7x7, as well as experiment with a ternary system of Pentacene, Ag and Si(111). Of particular interest to us is the Si(111)-(√3x√3)R30°}–Ag (Ag-Si-√3 hereafter). In this thesis I systematically explore effects of Ag deposition on the Ag-Si-√3 at different temperatures, film thicknesses and deposition fluxes. The generated insight of the Ag system on the Si(111) is then applied to generate novel methods of nanostructuring and nanowire growth. I then extend our expertise to the Au system on the Ag-Si(111) to gain insight into Au-Si eutectic silicide formation. Finally we explore behavior and growth modes of an organic molecule on the Ag-Si interface.

  11. Enhanced thermoelectric performance of CdO : Ag nanocomposites.

    PubMed

    Gao, Linjie; Wang, Shufang; Liu, Ran; Zha, Xinyu; Sun, Niefeng; Wang, Shujie; Wang, Jianglong; Fu, Guangsheng

    2016-07-26

    CdO : Ag nanocomposites with metallic Ag nanoparticles embedded in the polycrystalline CdO matrix were synthesized by the solid-state reaction method. The addition of Ag led to increased grain boundaries of CdO and created numerous CdO/Ag interfaces. By incorporating Ag into the CdO matrix, the power factor was increased which was probably due to the carrier energy filtering effect induced by the enhanced energy-dependent scattering of electrons. In addition, reduced thermal conductivity was also achieved by stronger phonon scattering from grain boundaries, CdO/Ag interfaces and Ag nanoparticles. These concomitant effects resulted in enhanced ZT values for all CdO : Ag nanocomposites, demonstrating that the strategy of introducing metallic Ag nanoparticles into the CdO host was very effective in optimizing the thermoelectric performance. PMID:27411573

  12. Anomalous evolution of interfaces in Fe/Ag magnetic multilayer

    NASA Astrophysics Data System (ADS)

    Sharma, Gagan; Gupta, Ranjeeta; Kumar, Dileep; Gupta, Ajay

    2013-12-01

    Interfaces greatly influence the magnetic properties of multilayer nanostructures. In the present work, the x-ray standing wave (XSW) technique along with conversion electron Mössbauer spectroscopy have been used to study the evolution of interfaces in Fe/Ag system as a function of thermal annealing. The XSW technique has sufficient depth resolution so as to determine the concentration profiles of Fe across the two interfaces, namely Fe-on-Ag and Ag-on-Fe independently. In as-deposited Ag/Fe/Ag trilayer, Fe-on-Ag interface has a substantially higher roughness of 1.3 nm as compared to 0.9 nm of Ag-on-Fe interface. It is shown that the observed difference in the roughness of the two interfaces is due to a substantial intermixing between Fe and Ag occurring preferentially at Fe-on-Ag interface. With thermal annealing, the two interfaces exhibit opposite behaviour; while Fe-on-Ag interface exhibits an initial sharpening, Ag-on-Fe interface exhibits a monotonous broadening. Two competing processes occur at the interfaces, (i) interface sharpening as a result of de-mixing, driven by a large positive heat of mixing between Fe and Ag and (ii) increase in topological roughness due to increased thermal agitation. This results in a non-monotonous variation in the roughness of Fe-on-Ag interface. At sufficiently high temperature the layered structure is completely destroyed, leading to formation of Fe and Ag nanoparticles.

  13. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum

    NASA Astrophysics Data System (ADS)

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-01

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10-5 Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains.

  14. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum

    NASA Astrophysics Data System (ADS)

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-01

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10‑5 Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains.

  15. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum.

    PubMed

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-16

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10(-5) Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains.

  16. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum.

    PubMed

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-16

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10(-5) Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains. PMID:27487089

  17. Coal Bed Methane Production in the Münsterland Basin, Germany - Past and Future

    NASA Astrophysics Data System (ADS)

    Mösle, B.; Kukla, P.; Stollhofen, H.; Preuße, A.

    2009-04-01

    Growing demands on energy and high energy prices have lead to a re-evaluation of the coal bed methane (CBM) potential in Germany. For research reasons the Technical University of Aachen is holding a concession area in NW Germany, located in the Münsterland Basin. This concession covers an area of about 3460 km2. The southern part of the concession area involves one of the most developed, densely populated mining districts in Western Europe, the Ruhr Area. The Upper Carboniferous coal measures there are covered by northward thickening Cretaceous strata which not only limits the coal mining activity to the south of the basin but also represents a challenge to CBM production technology. This is currently restricted to a depth of about 1200 m. Mine gas has been successfully produced in the Ruhr Area for decades. With the successive closure of coal mines, gas production rates will decrease and consequently production of CBM will become more important. The Münsterland Basin contains a large portion of known Carboniferous coals in western Germany and the production of mine gas proofs that there is a significant resource of natural gas in place. Estimates of the amount of gas in place are at about 3 Trillion m3 in Germany's mining districts of which 2 Trillion m3 are expected to occur in the Ruhr Area alone. First exploration efforts on CBM were made by a consortium of Ruhrgas AG and Conoco-Phillips Inc. in the 1990s. Because of low production rates, relatively high exploration and production costs, and the low gas prices at that time this project was stopped. The present study investigates the reservoir quality and geometry in order to better estimate the potential gas content for a general economic benefit assessment. The structural inventory of the study area comprises NE-SW trending folds and thrusts which are crossed obliquely by faults. Potential gas accumulations may be found in anticlinal structures paired with thrusts. However, these gas accumulations will add

  18. Synthesis, characterization and antimycobacterial activity of Ag(I)-aspartame, Ag(I)-saccharin and Ag(I)-cyclamate complexes.

    PubMed

    Cavicchioli, Maurício; Leite, Clarice Q F; Sato, Daisy N; Massabni, Antonio C

    2007-10-01

    The present work describes the synthesis and antimycobacterial activity of three Ag(I)-complexes with the sweeteners aspartame, saccharin, and cyclamate as ligands, with the aim of finding new candidate substances for fighting tuberculosis and other mycobacterial infections. The minimal inhibitory concentration of these three complexes was investigated in order to determine their in-vitro antimycobacterial activity against Mycobacterium tuberculosis, Mycobacterium avium, Mycobacterium intracellulare, Mycobacterium malmoense, and Mycobacterium kansasii. The MIC values were determined using the Microplate Alamar Blue Assay. The best MIC values found for the complexes were 9.75 microM for Ag(I)-aspartame against M. kansasii and 15.7 microM for Ag(I)-cyclamate against M. tuberculosis.

  19. Spin coating of Ag nanoparticles: Effect of reduction

    SciTech Connect

    Ansari, A. A. Sartale, S. D.

    2014-04-24

    A surfactant free method for the growth of Ag nanoparticles on glass substrate by spin coating of Ag ions solution followed by chemical reduction in aqueous hydrazine hydrate (HyH) solution has been presented. Appearance of surface plasmon resonance confirms the formation of Ag nanoparticles. Morphology and absorbance spectra of Ag nanoparticles films are used to examine effect of hydrazine concentration on the growth of Ag nanoparticles. SEM images show uniformly distributed Ag nanoparticles. Rate constant was found to be dependent on HyH concentration as a consequence influence particle size.

  20. BiPO4 photocatalyst employing synergistic action of Ag/Ag3PO4 nanostructure and graphene nanosheets

    NASA Astrophysics Data System (ADS)

    Mohaghegh, N.; Rahimi, E.

    2016-06-01

    Graphene-supported BiPO4/Ag/Ag3PO4 photocatalyst has been fabricated by simple hydrothermal and impregnation reaction. In BiPO4/Ag/Ag3PO4 based on Reduced Graphene Oxide (RGO), this network renders numerous pathways for rapid mass transport, strong adsorption and multireflection of incident light; meanwhile, the interface between BiPO4/Ag/Ag3PO4 and RGO increases the active sites and electron transfer rate. BiPO4/Ag/Ag3PO4 based on RGO noticeably exhibited high photocatalytic activity than that of BiPO4/Ag/Ag3PO4 and P25 under visible light irradiation for cationic dye (Rhodamine B), anionic dye (methyl orange) and 4-chlorophenol (4-CP) as a neutral pollutant, which are usually difficult to be degraded over the other catalysts. This enhanced photocatalytic activity of Graphene-supported BiPO4/Ag/Ag3PO4 for all pollutants could be mainly ascribed to the reinforced charge transfer from BiPO4/Ag/Ag3PO4 to RGO, which suppresses the recombination of electron/hole pairs. Besides that, this photocatalyst can be used repetitively with a high photocatalytic activity and no apparent loss of activity occurs. The results reveal that the RGO nanosheets work as a photocatalyst promoter during the photocatalytic reaction, leading to an improved photocatalytic activity.

  1. Template synthesis of Ag/AgCl microrods and their efficient visible light-driven photocatalytic performance

    SciTech Connect

    Chen, Hua; Xiao, Liang; Huang, Jianhua

    2014-09-15

    Highlights: • Preparation ofAg/AgCl microrods by reaction of Ag{sub 2}WO{sub 4} microrods with NaCl solution. • Generation of metallic Ag is induced by the ambient light in the synthesis process. • Ag/AgCl shows excellent visible light-driven photodegradation of organic dyes. - Abstract: Ag/AgCl microrods, aggregated by nanoparticles with a diameter ranging from 100 nm to 2 μm, were prepared by an ion-exchange reaction at 80 °C between Ag{sub 2}WO{sub 4} template and NaCl solution. The existence of metallic Ag species was confirmed by XRD, DRS and XPS measurements. Ag/AgCl microrods showed excellent photocatalytic activity for the degradation of rhodamine B and methylene blue under visible light irradiation. The degradation rate constants of rhodamine B and methylene blue are 0.176 and 0.114 min{sup −1}, respectively. The cycling photodegradation experiments suggest that Ag/AgCl microds could be employed as stable plasmonic photocatalysts for the degradation of organic dyes under visible light irradiation.

  2. Size distributions of chemically synthesized Ag nanocrystals

    NASA Astrophysics Data System (ADS)

    Thøgersen, Annett; Bonsak, Jack; Fosli, Carl Huseby; Muntingh, Georg

    2011-08-01

    Silver nanocrystals made by a chemical reduction of silver salts (AgNO3) by sodium borohydride (NaBH4) were studied using transmission electron microscopy and light scattering simulations. For various AgNO3/NaBH4 molar ratios, the size distributions of the nanocrystals were found to be approximately log-normal. In addition, a linear relation was found between the mean nanocrystal size and the molar ratio. In order to relate the size distribution of Ag nanocrystals of the various molar ratios to the scattering properties of Ag nanocrystals in solar cell devices, light scattering simulations of Ag nanocrystals in Si, SiO2, SiN, and Al2O3 matrices were carried out using MiePlot. These light scattering spectra for the individual nanocrystal sizes were combined into light scattering spectra for the fitted size distributions. The evolution of these scattering spectra with respect to an increasing mean nanocrystal size was then studied. From these findings, it is possible to find the molar ratio for which the corresponding nanocrystal size distribution has maximum scattering at a particular wavelength in the desired matrix.

  3. Mussel-inspired green synthesis of polydopamine-Ag-AgCl composites with efficient visible-light-driven photocatalytic activity.

    PubMed

    Cai, Aijun; Wang, Xiuping; Guo, Aiying; Chang, Yongfang

    2016-09-01

    Polydopamine-Ag-AgCl composites (PDA-Ag-AgCl) were synthesized using a mussel-inspired method at room temperature, where PDA acts as a reducing agent to obtain the noble Ag nanoparticles from a precursor. The morphologies and structures of the as-prepared PDA-Ag-AgCl were characterized by several techniques including field emission scanning electron microscopy (FESEM), transmission electron microscopy (SEM), Raman spectra, and X-Ray photoelectron spectrum (XPS). The morphological observation depicts formation of nanoparticles with various micrometer size diameters and surface XPS analysis shows presence of various elements including Ag, N, Cl, and O. The enhanced absorbance of the PDA-Ag-AgCl particles in the visible light region is confirmed through UV-Vis diffuse reflectance spectra (DRS), and the charge transfer is demonstrated by photoluminescence (PL) and photocurrent response. The synthesized PDA-Ag-AgCl composites could be used as visible-light-driven photocatalysts for the degradation of Rhodamine B. The elevated photocatalytic activity is ascribed to the effective charge transfer from plasmon-excited Ag to AgCl that can improve the efficiency of the charge separation during the photocatalytic reaction. Furthermore, differences in the photocatalytic performance among the different PDA-Ag-AgCl composites are noticed that could be attributed to the Brunauer-Emmett-Teller (BET) specific surface area, which benefits to capture the visible light efficiently. The PDA-Ag-AgCl exhibits excellent stability without a significant loss in activity after 5cycles. The proposed method is low-cost and environmentally friendly, hence a promising new way to fabricate plasmon photocatalysts. PMID:27450302

  4. Effect of cysteine and humic acids on bioavailability of Ag from Ag nanoparticles to a freshwater snail

    USGS Publications Warehouse

    Luoma, Samuel N.; Tasha Stoiber,; Croteau, Marie-Noele; Isabelle Romer,; Ruth Merrifeild,; Jamie Lead,

    2016-01-01

    Metal-based engineered nanoparticles (NPs) will undergo transformations that will affect their bioavailability, toxicity and ecological risk when released to the environment, including interactions with dissolved organic material. The purpose of this paper is to determine how interactions with two different types of organic material affect the bioavailability of silver nanoparticles (AgNPs). Silver uptake rates by the pond snail Lymnaea stagnalis were determined after exposure to 25 nmol l-1 of Ag as PVP AgNPs, PEG AgNPs or AgNO3, in the presence of either Suwannee River humic acid or cysteine, a high-affinity thiol-rich organic ligand. Total uptake rate of Ag from the two NPs was either increased or not strongly affected in the presence of 1 – 10 mg 1-1 humic acid. Humic substances contain relatively few strong ligands for Ag explaining their limited effects on Ag uptake rate. In contrast, Ag uptake rate was substantially reduced by cysteine. Three components of uptake from the AgNPs were quantified in the presence of cysteine using a biodynamic modeling approach: uptake of dissolved Ag released by the AgNPs, uptake of a polymer or large (>3kD) Ag-cysteine complex and uptake of the nanoparticle itself. Addition of 1:1 Ag:cysteine reduced concentrations of dissolved Ag, which contributed to, but did not fully explain the reductions in uptake. A bioavailable Ag-cysteine complex (> 3kD) appeared to be the dominant avenue of uptake from both PVP AgNPs and PEG AgNPs in the presence of cysteine. Quantifying the different avenues of uptake sets the stage for studies to assess toxicity unique to NPs.

  5. Mussel-inspired green synthesis of polydopamine-Ag-AgCl composites with efficient visible-light-driven photocatalytic activity.

    PubMed

    Cai, Aijun; Wang, Xiuping; Guo, Aiying; Chang, Yongfang

    2016-09-01

    Polydopamine-Ag-AgCl composites (PDA-Ag-AgCl) were synthesized using a mussel-inspired method at room temperature, where PDA acts as a reducing agent to obtain the noble Ag nanoparticles from a precursor. The morphologies and structures of the as-prepared PDA-Ag-AgCl were characterized by several techniques including field emission scanning electron microscopy (FESEM), transmission electron microscopy (SEM), Raman spectra, and X-Ray photoelectron spectrum (XPS). The morphological observation depicts formation of nanoparticles with various micrometer size diameters and surface XPS analysis shows presence of various elements including Ag, N, Cl, and O. The enhanced absorbance of the PDA-Ag-AgCl particles in the visible light region is confirmed through UV-Vis diffuse reflectance spectra (DRS), and the charge transfer is demonstrated by photoluminescence (PL) and photocurrent response. The synthesized PDA-Ag-AgCl composites could be used as visible-light-driven photocatalysts for the degradation of Rhodamine B. The elevated photocatalytic activity is ascribed to the effective charge transfer from plasmon-excited Ag to AgCl that can improve the efficiency of the charge separation during the photocatalytic reaction. Furthermore, differences in the photocatalytic performance among the different PDA-Ag-AgCl composites are noticed that could be attributed to the Brunauer-Emmett-Teller (BET) specific surface area, which benefits to capture the visible light efficiently. The PDA-Ag-AgCl exhibits excellent stability without a significant loss in activity after 5cycles. The proposed method is low-cost and environmentally friendly, hence a promising new way to fabricate plasmon photocatalysts.

  6. Electrical conductivity of a system of Ag2SO4:AgI eutectic added to 30Li2SO4:70Ag2SO4

    NASA Astrophysics Data System (ADS)

    Chandrayan, V. R.; Tejpal, A.; Singh, K.

    1989-10-01

    The electrical conductivity of rapidly quenched specimens of 48Ag2SO4:52AgI eutectic added to 30Li2SO4:70Ag2SO4 has been measured as a function of frequency and temperature. The results show a significant enhancement in the conductivity of the 30Li2SO4:70Ag2SO4 system with a maximum value at 12.5 mol. pct eutectic. This phenomenon is explained in terms of the dispersive nature of the fine eutectic crystallites in the crystalline matrix of the Li2SO4:Ag2SO4 system.

  7. A Model for Intercultural Training for Study Abroad in Germany

    ERIC Educational Resources Information Center

    Henze, Yvonne A.

    2007-01-01

    This article describes an intercultural workshop designed for American students from the University of Rhode Island's International Engineering Program who are going to Germany to work and to study. The activities and goals of the workshop are explained. The outcomes and findings show that participation in the pre-departure intercultural workshop…

  8. Adult Education in Germany from the Middle Ages to 1980.

    ERIC Educational Resources Information Center

    Textor, Martin R.

    1986-01-01

    The history of adult education in Germany is examined, including the power of the Church during the Middle Ages, self-instruction in informal groups during the Renaissance, Lutheran influence during the Reformation, emphasis on reason and science during the Enlightenment period, industrialization, the Weimar Republic, the Third Reich, and post-war…

  9. Germany and Europe Since World War II: Resources for Teachers.

    ERIC Educational Resources Information Center

    Harris, James F., Ed.; Metcalf, Fay, Ed.

    Designed as a resource for teachers to help high school students understand the new Germany, six background papers and nine lessons provide information on the difficult transition from the Third Reich to defeat and military occupation, on the establishment of two successor states, and on revolution and reunification. The six background papers…

  10. The Kolumbus-Kids Project in Germany for Gifted Children

    ERIC Educational Resources Information Center

    Wegner, Claas; Minnaert, Lea; Strehlke, Friederike

    2013-01-01

    Since 2006, the Kolumbus-Kids project in Germany has been supporting gifted learners between the ages 9 and 12. Selected children from regional schools are invited to participate in courses dealing with biological problems and phenomena at university. In order to attend these sessions, they first have to pass a special performance test and a test…

  11. Bluetongue Virus Serotype 8 Reemergence in Germany, 2007 and 2008

    PubMed Central

    Hoffmann, Bernd; Saßerath, Michael; Thalheim, Sabine; Bunzenthal, Claudia; Strebelow, Günter

    2008-01-01

    Reemerging bluetongue virus serotype 8 (BTV-8) in Germany was detected first in May 2007 in a sentinel cow and in February 2008 in an export heifer. Reemergence was confirmed by retesting the samples, experimental inoculation, fingerprinting analysis, and virus isolation. Overwintering of BTV-8 and continuous low-level infections are assumed. PMID:18760009

  12. Prevalence of Nontuberculous Mycobacterial Pulmonary Disease, Germany, 2009–2014

    PubMed Central

    Wagner, Dirk; de Roux, Andrés; Diel, Roland; Hohmann, David; Hickstein, Lennart; Welte, Tobias; Rademacher, Jessica

    2016-01-01

    We analyzed routine statutory health insurance claim data to determine prevalence of nontuberculous mycobacterial pulmonary disease in Germany. Documented prevalence rates of this nonnotifiable disease increased from 2.3 to 3.3 cases/100,000 population from 2009 to 2014. Prevalence showed a strong association with advanced age and chronic obstructive pulmonary disease. PMID:27191473

  13. Renewable Electricity Policy in Germany, 1974 to 2005

    ERIC Educational Resources Information Center

    Lauber, Volkmar; Mez, Lutz

    2006-01-01

    Of the large industrial countries, Germany is clearly leading with regard to new renewable energy sources, occupying first rank in terms of installed capacity for wind energy and second for photovoltaics. This is not because of an exceptional natural resource base but because of public policy in this area, despite the fact that this policy was…

  14. Responses of England, Germany and Switzerland to Declining School Enrolments.

    ERIC Educational Resources Information Center

    Michalski, Catherine

    Results of interviews with educators in England, Germany, and Switzerland are combined with statistical data in this study of the effects of declining enrollment and the development of multicultural programs in those countries. In all three countries, the author encountered a prevailing resistance to program change in the face of declining…

  15. Sport in Germany. Basis-Info 3-1996.

    ERIC Educational Resources Information Center

    Beitz, Steffen

    This paper explores the importance and impact of sport in Germany from a variety of perspectives. Topics include: (1) the social function of sport; (2) popular sport, focusing on exercise and self-development rather than competition; (3) sport's role in the leisure activities of the handicapped; (4) top sport performers; (5) drugs and sport; (6)…

  16. Social Policy and Immigrant Joblessness in Britain, Germany and Sweden

    ERIC Educational Resources Information Center

    Kesler, Christel

    2006-01-01

    I examine patterns of joblessness among immigrant men and women from 33 countries of origin now living in Britain, Germany and Sweden. Access to welfare, access to the labor market, job segregation and institutional support for women's employment define distinct policy configurations in these three destinations. Findings show that gaps in…

  17. Mass Media Use by Children and Media Education in Germany.

    ERIC Educational Resources Information Center

    Wilke, Jurgen; Eschenauer, Barbara

    Efforts to include the mass media in school instruction in Germany date back almost as far as the modern mass media themselves. However, the latter were, at best, nearly always used as an instrumental means and not as a subject of education in their own right. The basic findings of a representative survey of teachers in the Federal Republic of…

  18. Home Education in Germany: An Overview of the Contemporary Situation

    ERIC Educational Resources Information Center

    Spiegler, Thomas

    2003-01-01

    This paper gives an overview of the situation of home education in Germany. The first results from a predominantly qualitative research project are presented. This combines participant observation, content analysis and qualitative interviews for a thorough sociological analysis of the German home education movement. Compulsory school attendance…

  19. Library Research in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Koch, Hans-Albrecht

    1984-01-01

    Report on current state of research in academic and research librarianship in Federal Republic of Germany highlights projects concerning acquisition of books; work procedure investigations; personnel requirements; cost accounting; investigations of library use (user research, user education); public relations work; librarianship; and subject…

  20. Germany's ECEC Workforce: A Difficult Path to Professionalisation

    ERIC Educational Resources Information Center

    Rauschenbach, Thomas; Riedel, Birgit

    2016-01-01

    In a European comparison, the childcare profession in Germany has taken a distinct path of development which is closely interwoven with the history of early childhood education and care (ECEC) in general. Institutional choices critical to this path are the assignment of childcare as part of social welfare, the pursuit of a maternalist tradition in…

  1. Innovative energy technologies and climate policy in Germany

    SciTech Connect

    Schumacher, Katja; Sands, Ronald D.

    2006-12-01

    Due to the size and structure of its economy, Germany is one of the largest carbon emitters in the European Union. However, Germany is facing a major renewal and restructuring process in electricity generation. Within the next two decades, up to 50% of current electricity generation capacity may retire because of end-of-plant lifetime and the nuclear phase-out pact of 1998. Substantial opportunities therefore exist for deployment of advanced electricity generating technologies in both a projected baseline and in alternative carbon policy scenarios. We simulate the potential role of coal integrated gasification combined cycle (IGCC), natural gas combined cycle (NGCC), carbon dioxide capture and storage (CCS), and wind power within a computable general equilibrium of Germany from the present through 2050. These advanced technologies and their role within a future German electricity system are the focus of this paper. We model the response of greenhouse gas emissions in Germany to various technology and carbon policy assumptions over the next few decades. In our baseline scenario, all of the advanced technologies except CCS provide substantial contributions to electricity generation. We also calculate the carbon price where each fossil technology, combined with CCS, becomes competitive. Constant carbon price experiments are used to characterize the model response to a carbon policy. This provides an estimate of the cost of meeting an emissions target, and the share of emissions reductions available from the electricity generation sector.

  2. The Young Generation Takes Root--Foreigners in Germany II.

    ERIC Educational Resources Information Center

    Herrmann, Helga

    1998-01-01

    Although there is no single measure of the degree of integration of the children of immigrants, individual trends and indicators can be interpreted to depict the status and opportunities of young foreigners residing in Germany. Although the standard of school-leaving certificates rose, the number of young foreigners is still disproportionately…

  3. Educational Research in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Mitter, Wolfgang

    The Federal Republic of Germany's educational system became a matter of major national concern in the early 1960's, drawing new attention to the need for educational research. Sociological and economic questions joined the pedagogical and psychological concerns previously central to research; the character of the educational system was added to…

  4. Teacher Education in Italy, Germany, England, Sweden and Finland

    ERIC Educational Resources Information Center

    Ostinelli, Giorgio

    2009-01-01

    This article presents a brief analysis of teacher education in five European countries: Italy, Germany, England, Sweden and Finland. In the post-industrial world, the sense of teaching has profoundly changed, influenced by a rapidly evolving socio-economic context. The responses given by each country are different, but two tendencies emerge: on…

  5. Increase in Imported Dengue, Germany, 2001–2002

    PubMed Central

    Schöneberg, Irene; Krause, Gérard; Claus, Hermann; Ammon, Andrea; Stark, Klaus

    2004-01-01

    Dengue fever is a reportable disease in Germany. Surveillance data from 2001 and 2002 were analyzed and compared to travel patterns. Imported dengue fever increased strongly in this time. Most infections were acquired in Southeast Asia, specifically Thailand. The 2002 epidemic in Brazil was also reflected in these data. PMID:15200827

  6. Restructuring Schools for Democracy in the Former East Germany.

    ERIC Educational Resources Information Center

    Dumas, Wayne; Dumas, Alesia; Lee, William B.

    1996-01-01

    Discusses the contentious relationship between educators within the former East Germany and their West German cohorts following reunification. The problems have stemmed from conflicting ideologies and traditions (Marxist versus Christian Democrat and Social Democrat) as well as differences concerning school organization and educational objectives.…

  7. The Division of Household Labor in Germany and Israel

    ERIC Educational Resources Information Center

    Lewin-Epstein, Noah; Stier, Haya; Braun, Michael

    2006-01-01

    We compare the patterns of household division of labor in Germany and Israel--two countries that share key elements of the corporatist welfare regime but differ in their gender regimes--and evaluate several hypotheses using data from the 2002 International Social Survey Program. Although time constraints and relative resources affect the division…

  8. Novel Lyssavirus in Natterer’s Bat, Germany

    PubMed Central

    Beer, Martin; Conraths, Franz J.; Finke, Stefan; Hoffmann, Bernd; Keller, Barbara; Kliemt, Jeannette; Mettenleiter, Thomas C.; Mühlbach, Elke; Teifke, Jens P.; Wohlsein, Peter; Müller, Thomas

    2011-01-01

    A virus isolated from a Natterer’s bat (Myotis nattererii) in Germany was differentiated from other lyssaviruses on the basis of the reaction pattern of a panel of monoclonal antibodies. Phylogenetic analysis supported the assumption that the isolated virus, Bokeloh bat lyssavirus, may represent a new member of the genus Lyssavirus. PMID:21801640

  9. Cowpox Virus Transmission from Pet Rats to Humans, Germany

    PubMed Central

    Campe, Hartmut; Zimmermann, Pia; Glos, Katharina; Bayer, Margot; Bergemann, Hans; Dreweck, Caroline; Graf, Petra; Weber, Bianca Kim; Meyer, Hermann; Büttner, Mathias; Busch, Ulrich

    2009-01-01

    We describe a cluster of cowpox virus (CPXV) infections in humans that occurred near Munich, Germany, around the beginning of 2009. Previously, only sporadic reports of CPXV infections in humans after direct contact with various animals had been published. This outbreak involved pet rats from the same litter. PMID:19402967

  10. Climate Change: A "Green" Approach to Teaching Contemporary Germany

    ERIC Educational Resources Information Center

    Melin, Charlotte

    2013-01-01

    This article describes a newly designed upper division German language course, "Contemporary Germany: Food, Energy Politics," and two sampling methods of assessment for measuring parallel gains in German skills and sustainable development (SD) thinking. Second Language Acquisition (SLA) informed course design, key assignments, and…

  11. Searching for Their Own Identity: Young People in Germany.

    ERIC Educational Resources Information Center

    Beitz, Steffen; Stahl, Klaus, Ed.

    1995-01-01

    This paper examines the definition of "young people" and asserts there is no clear-cut social description of this group with societal expectations differing from culture to culture. The article analyzes the changes affecting the lives of "youth" in Germany and assesses their social attitudes and values. The contents include seven sections: (1)…

  12. Migration and Marginality: Guestworkers in Germany and France.

    ERIC Educational Resources Information Center

    Rist, Ray C.

    1979-01-01

    Examines migratory movements in Europe since 1954, with particular emphasis on the 13 to 14 million immigrants to the industrial countries of northern Europe. Concludes that the movement of manpower has been critical in sustaining the post-World War II economies of industrialized nations such as Germany and France. (Author/DB)

  13. Education in Germany since Unification. Oxford Studies in Comparative Education.

    ERIC Educational Resources Information Center

    Phillips, David, Ed.

    This collection of papers discusses issues related to education in Germany since its unification. The papers include: "The Legacy of Unification" (David Phillips); "Change and Continuity in Education After the 'Wende'" (E. J. Neather); "A Study of Teachers' Perceptions in Brandenburg 'Gesamtschulen'" (Stephanie Wilde); "Memory and Judgement: How…

  14. [Living kidney transplantation. A comparison of Scandinavian countries and Germany].

    PubMed

    Lück, R; Schrem, H; Neipp, M; Nashan, B; Klempnauer, J

    2003-06-01

    The discussion of compensating for shortages of cadaveric donation with increased living donation often reveals differences between the Scandinavian countries and Germany. Possible adoption of Scandinavian structures to improve the rate of living donations in Germany warrants analysis of the actual differences between these two regions. Close examination reveals that significantly higher rates of living donation are achieved only in Sweden and Norway. In Norway, a frequently postulated negative effect on cadaveric donation due to very high rates of living donation could not be confirmed. In contrast to Germany and as a consequence of Norwegian geography, kidney transplantation has been regarded in Norway as the first-line therapy for endstage renal disease for more than 35 years. Living donation has since been actively pursued and is traditionally the transplantation of first choice. In Germany, living donation is still regarded as the second choice after cadaveric donation, due to legal regulations. Significant improvements in living donation frequencies could be achieved there by adopting the active Norwegian approach to living donor identification.

  15. Das Deutschlandspiegelvideo (The View-of-Germany-Videos).

    ERIC Educational Resources Information Center

    Pentecost, Gislind E.

    1993-01-01

    Describes View-of-Germany-Videos, published by the Goethe Institute. The videos are authentic, entertaining, and very versatile in usefulness. In addition they are short, thus easily incorporated into a lesson plan, and free of charge, making them accessible to any educational establishment. (AB)

  16. Germany: The Search for Unity. Guide for Workshop Leaders.

    ERIC Educational Resources Information Center

    Blankenship, Glen

    This document is designed to support teachers in the use of instructional materials related to contemporary Germany. The materials in this guide provide the basis for a one-day, 5 hour inservice session. The workshop agenda begins the guide and sets out the schedule of times for different activities and instruction. The suggested format can be…

  17. Space Research in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Preuss, Karl-Heinz, Ed.; Simen, Rolf H., Ed.

    The Federal Republic of Germany's space policy is designed to promote basic research, contribute to the development of space technology, and apply the findings in the public and private sectors. It is also aimed at enhancing the competitiveness of the West German space industry and helping countries of the Third World to solve their development…

  18. Environmental Education in Germany: Concepts, History, Projects, Visions.

    ERIC Educational Resources Information Center

    Tapia, Ivan, Ed.; Blochmann, Georg, Ed.

    2000-01-01

    This document presents the history of environmental education in Germany and reports on the diversions and solutions in the search for sustainable education. Five sections include: (1) "Environmental Education: Learning with All One's Senses"; (2) "Sustainability as the New Model: Knowledge of a New Quality"; (3) "Tomorrow's Education in…

  19. Right-Wing Extremist Violence among Adolescents in Germany

    ERIC Educational Resources Information Center

    Sitzer, Peter; Heitmeyer, Wilhelm

    2008-01-01

    What are the preconditions for right-wing extremist violence among German youths? For several years, the rate of this violence has been increasing in Germany, and the same can be observed for right-wing extremist orientations characterized by the coming together of ideologies of unequal worth and the acceptance of violence as a mode of action. And…

  20. The Life Expectancy of People with Intellectual Disabilities in Germany

    ERIC Educational Resources Information Center

    Dieckmann, Friedrich; Giovis, Christos; Offergeld, Jana

    2015-01-01

    Background: This study presents age group-specific mortality rates and the average life expectancy of people with intellectual disabilities in Germany. Method: For two samples from Westphalia-Lippe and Baden-Wuerttemberg, person-related data for the years 2007-2009 were analysed. Age group-specific mortality rates were estimated by exponential…

  1. Influences on Political Education in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    Shafer, Susanne M.

    1991-01-01

    Discusses political education in the postwar Federal Republic of Germany. Describes a U.S. led reeducation program founded upon principles of denazification and democracy and examines German responses. Identifies the influence of the Soviet Union upon West German education. Analyzes the growth of political education in the 1960s, its maturation,…

  2. School Improvement through Inspections? First Empirical Insights from Germany

    ERIC Educational Resources Information Center

    Dedering, Kathrin; Muller, Sabine

    2011-01-01

    Since the late 1990s, broad discussions on education and educational quality have given impetus to the implementation of many new measures aimed at the improvement of schools in Germany. In this context, school inspections have been introduced in all 16 German federal states during the last 6 years. In the meantime, scientific research into the…

  3. Useless Eaters: Disability as Genocidal Marker in Nazi Germany.

    ERIC Educational Resources Information Center

    Mostert, Mark P.

    2002-01-01

    This article describes historical attitudes toward people with disabilities in Germany and how this context produced mass murder of people with disabilities prior to and during World War II. Key marker variables are examined, including the rise of Darwinism and eugenics. Resistance to disability as a genocidal marker is discussed. (Contains…

  4. Increase in imported dengue, Germany, 2001-2002.

    PubMed

    Frank, Christina; Schöneberg, Irene; Krause, Gérard; Claus, Hermann; Ammon, Andrea; Stark, Klaus

    2004-05-01

    Dengue fever is a reportable disease in Germany. Surveillance data from 2001 and 2002 were analyzed and compared to travel patterns. Imported dengue fever increased strongly in this time. Most infections were acquired in Southeast Asia, specifically Thailand. The 2002 epidemic in Brazil was also reflected in these data.

  5. 22. HISTORIC VIEW OF EARLY TEST STAND IN GERMANY PERHAPS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. HISTORIC VIEW OF EARLY TEST STAND IN GERMANY PERHAPS THE ENGINE IS FOR THE VFR'S (VEREIN FUER RAUMSCHIFFAHRT) 4 STICK REPULSOR. ENGINE IN PHOTOS IS BEING TANKED WITH LOX (NOTICE THE FROST FORMING AT THE BOTTOM OF THE TANK BEHIND THE LADDER. - Marshall Space Flight Center, Redstone Rocket (Missile) Test Stand, Dodd Road, Huntsville, Madison County, AL

  6. Hammer and Compass: Introducing East Germany. An Anthology with Interpretations.

    ERIC Educational Resources Information Center

    Mayer, Elizabeth M.

    This anthology introduces students of German to the life of the people of East Germany. The three-part text describes interrelated cultural and political activities which are characteristic of the republic. Part One explores basic communistic philosophy, "a new myth", particularly through commentary on Walter Ulbricht's "Universe, Earth, and Man."…

  7. Greywater recycling systems in Germany--results, experiences and guidelines.

    PubMed

    Nolde, E

    2005-01-01

    Although Germany is not considered a water-poor country, there exist regional differences in water supply and consumption. During the past 15 years, the greywater aspect has been dealt with in Germany with a greater interest and variable success. In addition to an increased environmental awareness, water costs also play an important role in increasing the demand for advanced greywater treatment plants nstalled in buildings. Under favourable conditions, the amortisation costs usually lie between 5 and 7 years. Systems that have been extensively tried and tested and have been shown to be most reliable are those employing an advanced biological treatment followed by an UV disinfection. Systems based on membrane technology are being developed and researched intensively in Germany for municipal wastewater treatment. However, so far they play no role in greywater recycling. Greywater systems operating under low energy and maintenance requirements without the use of chemicals are mostly favoured. In Germany, greywater recycling systems should be registered at the Health Office in order to guarantee that no cross-connections exist with the drinking water network and that pipes are labelled according to regulations. The hygienic requirements for recycled greywater, which is primarily used for toilet flushing, are oriented towards the EU-Guidelines for Bathing Waters. The use of recycled greywater for irrigation purposes is minor. As to the use of recycled water for laundry, the first promising investigation results are now available.

  8. A survey of environmental needs and innovative technologies in Germany

    SciTech Connect

    Voss, C.F.; Roberds, W.J.

    1995-05-01

    The International Technology Program (IT?), formerly the international Technology Exchange Program (ITEP), of the Department of Energy`s (DOE`s) Office of Environmental Restoration and Waste Management (EM) is responsible for promoting: (1) the import of innovative technologies to better address EM`s needs; and (2) the export of US services into foreign markets to enhance US competitiveness. Under this program: (1) the environmental restoration market in Germany was evaluated, including the description of the general types of environmental problems, the environmental regulations, and specific selected contaminated sites; and (2) potentially innovative environmental restoration technologies, either commercially available or under development in Germany, were identified, described and evaluated. It was found that: (1) the environmental restoration market in Germany is very large, on the order of several billion US dollars per year, with a significant portion possibly available to US businesses; and (2) a large number (54) of innovative environmental restoration technologies, which are either commercially available or under development in Germany, may have some benefit to the DOE EM program and should be considered for transfer to the US.

  9. The Educational System in the Federal Republic of Germany.

    ERIC Educational Resources Information Center

    College Entrance Examination Board, New York, NY.

    The overview of West Germany's educational system emphasizes administration, organization, admission criteria, objectives, and career training programs. The document is presented in five chapters. Chapter I focuses on various aspects of planning for and administering elementary, secondary, and higher education, with particular attention to (1)…

  10. Casting a University-Wide Net: Teaching "Sustainability in Germany"

    ERIC Educational Resources Information Center

    Ducate, Lara

    2016-01-01

    Due to the connection between Germany and sustainability studies, German Programs are well poised to offer a course on German history, culture, and sustainability to meet the needs of the next generation of students. Interdisciplinary humanities courses that incorporate critical thinking, problem solving, and collaborative learning will help to…

  11. [Presence and future of emergency medicine in Germany].

    PubMed

    Christ, Michael; Dodt, Christoph; Geldner, Götz; Hortmann, Marcus; Stadelmeyer, Uwe; Wulf, Hinnerk

    2010-10-01

    Health care policy has changed duties and responsibilities of hospitals in Germany. The transition zone of in- and outpatient care has been recognized as a critical gateway for the success of hospitals, subsequently leading to the appreciation of the value of professionalized emergency departments. Currently, hospital-based emergency medicine in Germany is organized in a very heterogeneous manner. Due to the key function of emergency departments for the medical and economic success of hospitals, professional expertise in clinical emergency medicine has to be strengthened: We discuss possible models of hospital-based emergency care and present first data that professionalisation of hospital-based emergency medicine in Germany improves treatment quality and outcome of patients presenting with chest-pain or community-acquired pneumonia to the emergency department. Furthermore, those strategies are accompanied with the improvement of economic characteristics. Summing up, professionalisation of hospital-based emergency medicine in Germany is urgently needed and may improve medical and economic success of hospital-based patient care.

  12. One-pot synthesis of ternary Ag₂CO₃/Ag/AgCl photocatalyst in natural geothermal water with enhanced photocatalytic activity under visible light irradiation.

    PubMed

    Yao, Xiaxi; Liu, Xiaoheng

    2014-09-15

    Geothermal water is a clean, cheap and renewable resource and it is widely distributed all over the world. In this work, ternary Ag2CO3/Ag/AgCl photocatalyst has been successfully synthesized via a one-pot precipitation method in natural geothermal water at room temperature, wherein the geothermal water serves as the source of chlorine and carbonate. The results suggest that the Ag/AgCl nanoparticles are anchored on the surface of Ag2CO3 and Ag2CO3/Ag/AgCl composite shows strong absorption ability in the visible light region. The evaluation of the photocatalytic activity indicates that the as-synthesized Ag2CO3/Ag/AgCl photocatalyst exhibits higher photocatalytic performance for the degradation of methylene blue (MB) aqueous solution under visible light irradiation than one-component (Ag2CO3), two-component (Ag/AgCl, Ag2CO3/AgCl) and the mechanical mixture of Ag2CO3 and Ag/AgCl. The trapping experiments confirmed that holes (h(+)) and (•)O2(-) were the two main active species in the photocatalytic process. Finally, a possible Z-scheme photocatalytic mechanism of the charge transfer was proposed for the enhanced photocatalytic performance. This work may open up new insights into the application of cheap geothermal water resources in the word and provide new opportunities for facile fabrication of Ag/AgCl-based photocatalysts.

  13. Bipolar Ag-Zn battery

    NASA Technical Reports Server (NTRS)

    Giltner, L. John

    1994-01-01

    The silver-zinc (AgZn) battery system has been unique in its ability to safely satisfy high power demand applications with low mass and volume. However, a new generation of defense, aerospace, and commercial applications will impose even higher power demands. These new power demands can be satisfied by the development of a bipolar battery design. In this configuration the power consuming, interelectrode current conductors are eliminated while the current is then conducted via the large cross-section electrode substrate. Negative and positive active materials are applied to opposite sides of a solid silver foil substrate. In addition to reducing the weight and volume required for a specified power level, the output voltage performance is also improved as follows. Reduced weight through: elimination of the plastic cell container; elimination of plate leads and intercell connector; and elimination of internal plate current collector. Increased voltage through: elimination of resistance of current collector; elimination of resistance of plate lead; and elimination of resistance of intercell connector. EPI worked previously on development of a secondary bipolar silver zinc battery. This development demonstrated the electrical capability of the system and manufacturing techniques. One difficulty with this development was mechanical problems with the seals. However, recent improvements in plastics and adhesives should eliminate the major problem of maintaining a seal around the periphery of the bipolar module. The seal problem is not as significant for a primary battery application or for a requirement for only a few discharge cycles. A second difficulty encountered was with activation (introducing electrolyte into the cell) and with venting gas from the cell without loss of electrolyte. During previous work, the following projections for energy density were made from test data for a high power system which demonstrated in excess of 50 discharge/charge cycles. Projected

  14. Prevalence of weather sensitivity in Germany and Canada

    NASA Astrophysics Data System (ADS)

    Mackensen, Sylvia; Hoeppe, Peter; Maarouf, Abdel; Tourigny, Pierre; Nowak, Dennis

    2005-01-01

    Several studies have shown that atmospheric conditions can affect well-being or disease, and that some individuals seem to be more sensitive to weather than others. Since epidemiological data on the prevalence of weather-related health effects are lacking, two representative weather sensitivity (WS) surveys were conducted independently in Germany and Canada. The objectives of this paper are: (1) to identify the prevalence of WS in Germany and Canada, (2) to describe weather-related symptoms and the corresponding weather conditions, and (3) to compare the findings in the two countries. In Germany 1,064 citizens (age >16 years) were interviewed in January 2001, and in Canada 1,506 persons (age >18 years) were interviewed in January 1994. The results showed that 19.2% of the German population thought that weather affected their health “to a strong degree,” 35.3% that weather had “some influence on their health” (sum of both = 54.5% weather sensitive), whereas the remaining 45.5% did not consider that weather had an effect on their health status. In Canada 61% of the respondents considered themselves to be sensitive to the weather. The highest prevalence of WS (high + some influence) in Germans was found in the age group older than 60 years (68%), which was almost identical in the Canadian population (69%). The highest frequencies of weather-related symptoms were reported in Germany for stormy weather (30%) and when it became colder (29%). In Canada mainly cold weather (46%), dampness (21%) and rain (20%) were considered to affect health more than other weather types. The most frequent symptoms reported in Germany were headache/migraine (61%), lethargy (47%), sleep disturbances (46%), fatigue (42%), joint pain (40%), irritation (31%), depression (27%), vertigo (26%), concentration problems (26%) and scar pain (23%). Canadian weather-sensitive persons reported colds (29%), psychological effects (28%) and painful joints, muscles or arthritis (10%). In Germany 32

  15. New isomeric state in {sup 116}Ag

    SciTech Connect

    Batchelder, J.C.; Carter, H.K.; Spejewski, E.H.; Bingham, C.R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Ramayya, A.V.; Garrett, P.E.; Hartley, D.J.; Krolas, W.; Kulp, W.D.; Wood, J.L.; Larochelle, Y.; Tantawy, M.N.; Piechaczek, A.

    2005-10-01

    A new isomer in {sup 116}Ag with a half-life of 20(1) s has been discovered through the use of conversion electron, {beta}, and {gamma} spectroscopy of on-line mass-separated radioactivities at the Holifield Radioactive Ion Beam Facility at ORNL. The observed electron peaks at 22.5, 44.42, and 47.33 keV were interpreted as the K,L, and M conversion electron lines resulting from a 47.9-keV E3 transition associated with the decay of a second isomeric level in {sup 116}Ag. A new level structure of {sup 116}Ag is proposed, with the levels identified as the 0{sup -} ground-state and isomers at 47.9 and 128.8 keV having spin/parities of 3{sup +} and 6{sup -} respectively.

  16. Adsorption of sulfur on Ag(100)

    SciTech Connect

    Russell, Selena M.; Shen, Mingmin; Liu, Da-Jiang; Thiel, Patricia A.

    2010-12-17

    We have used scanning tunneling microscopy and density Functional theory to investigate the structures formed by sulfur on Ag(100). As indicated by previous low-energy electron diffraction studies, the main phases have unit cells of p(2 x 2) and ({radical}17 x {radical}17)R14{sup o}. We show that the latter is a reconstruction. The favored structural model is one in which 5 Ag atoms are missing from the (100) surface plane per unit cell. The ejected Ag atoms combine with sulfur to form islands of the reconstructed phase on the terraces. The ({radical}17 x {radical}17)R14{sup o} phase coexists with the p(2 x 2), at sulfur coverages slightly above 0.25 monolayers. In addition, chain-like structures are observed in STM, both at room temperature (where they are dynamic) and below (where they are not). These results are compared with relevant literature for copper surfaces.

  17. Nonequilibrium microstructures for Ag-Ni nanowires.

    PubMed

    Rai, Rajesh K; Srivastava, Chandan

    2015-04-01

    This work illustrates that a variety of nanowire microstructures can be obtained either by controlling the nanowire formation kinetics or by suitable thermal processing of as-deposited nanowires with nonequilibrium metastable microstructure. In the present work, 200-nm diameter Ag-Ni nanowires with similar compositions, but with significantly different microstructures, were electrodeposited. A 15 mA deposition current produced nanowires in which Ag-rich crystalline nanoparticles were embedded in a Ni-rich amorphous matrix. A 3 mA deposition current produced nanowires in which an Ag-rich crystalline phase formed a backbone-like configuration in the axial region of the nanowire, whereas the peripheral region contained Ni-rich nanocrystalline and amorphous phases. Isothermal annealing of the nanowires illustrated a phase evolution pathway that was extremely sensitive to the initial nanowire microstructure.

  18. Spectrophotometry of the shell around AG Carinae

    NASA Technical Reports Server (NTRS)

    Mitra, P. Mila; Dufour, Reginald J.

    1990-01-01

    Spatially-resolved long-slit spectrophotometry are presented for two regions of the shell nebula around the P-Cygni variable star AG Carinae. The spectra cover the 3700-6800 A wavelength range. Emission-line diagnostics are used to derive extinction, electron temperatures, and densities for various positions in the nebula. The chemical abundances and ionization structure are calculated and compared with other types of planetary nebulae and shells around other luminous stars. It is found that the N/O and N/S ratios of Ag Car are high compared to solar neighborhood ISM values. The O/H depletion found for the AG Car shell approaches that found in the condensations of the Eta Car system.

  19. The situation of space education in the unified Germany

    NASA Astrophysics Data System (ADS)

    von Muldau, Hans H.

    Because of the unique situation of the unified Germany it is worth discussing the state of the art and the future aspects of space education in this country. Two different social and educational systems of the F.R.G. (Federal Republic of Germany) and the G.D.R. (German Democratic Republic) have to be synchronized. The increase of the population by the unification affected the space science related people. So the majorities change. At the moment the severe unemployment situation in eastern Germany hides this fact. But we have to be prepared for this in years to come. The different relation to the space science programs of the U.S.A. and Russia for the German scientist gives a chance for more international understanding and cooperation. This becomes a subject of educational approach to the international cooperation problem. The start of DARA (the German national space administration) in 1989 accompanied by dramatic concentration of space knowledge in DASA (the cooperation of the German national space industry) in the late eighties, shows that Germany has begun to concentrate its capabilities. On such a background, space education for the majority of the population becomes understandable and desirable. European commercial unification on an open market at the beginning of 1993 helps to concentrate the Germans on their historical part and task in the European market. Therefore, many solutions to establish effective space education becomes visible which were hidden behind walls of emotions and prejudices in the past. So the forecast for space education in Germany for the nineties has never been better. The only remaining problem—funding—has to be solved by unconventional ways, e.g. a foundation by the industry as in other countries.

  20. The axisymmetric stellar wind of AG Carinae

    NASA Technical Reports Server (NTRS)

    Schulte-Ladbeck, Regina E.; Clayton, Geoffrey C.; Hillier, D. John; Harries, Tim J.; Howarth, Ian D.

    1994-01-01

    We present optical linear spectropolarimetry of the Luminous Blue Variable AG Carinae obtained after a recent visual brightness increase. The absence of He II lambda 4686 emission, together with the weakening of the He I spectrum and the appearance of Fe lines in the region around 5300 A, confirm that AG Car has started a new excursion across the HR diagram. The H alpha line profile exhibits very extended line wings that are polarized differently in both amount and position angle from either the continuum or the line core. The polarization changes across H alpha, together with variable continuum polarization, indicate the presence of intrinsic polarization. Coexistence of the line-wing polarization with extended flux-line wings evidences that both are formed by electron scattering in a dense wind. The position angle rotates across the line profiles, in a way that presently available models suggest is due to rotation and expansion of the scattering material. AG Car displays very large variations of its linear polarization with time, Delta P approximately 1.2%, indicating significant variations in envelope opacity. We find that the polarization varies along a preferred position angle of approximately 145 deg (with a scatter of +/- 10 deg) which we interpret as a symmetry axis of the stellar wind (with an ambiguity of 90 deg). This position angle is co-aligned with the major axis of the AG Car ring nebula and perpendicular to the AG Car jet. Our observations thus suggest that the axisymmetric geometry seen in the resolved circumstellar environment at various distances already exists within a few stellar radii of AG Car. From the H alpha polarization profile we deduce an interstellar polarization of Q = 0.31%, U = -1.15% at H alpha. The inferred interstellar polarization implies that the intrinsic polarization is not always of the same sign. This indicates either significant temporal changes in the envelope geometry, or it may arise from effects of multiple scattering

  1. Facile synthesis of ternary Ag/AgBr-Ag2CO3 hybrids with enhanced photocatalytic removal of elemental mercury driven by visible light.

    PubMed

    Zhang, Anchao; Zhang, Lixiang; Lu, Hao; Chen, Guoyan; Liu, Zhichao; Xiang, Jun; Sun, Lushi

    2016-08-15

    A novel technique for photocatalytic removal of elemental mercury (Hg(0)) using visible-light-driven Ag/AgBr-Ag2CO3 hybrids was proposed. The ternary Ag/AgBr-Ag2CO3 hybrids were synthesized by a simple modified co-precipitation method and characterized by N2 adsorption-desorption, scanning electron microscope (SEM), X-ray diffraction (XRD), UV-vis diffused reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) techniques. The effects of AgBr content, fluorescent lamp (FSL) irradiation, solution temperature, SO2 and NO on Hg(0) removal were investigated in detail. Furthermore, a possible reaction mechanism for higher Hg(0) removal was proposed, and the simultaneous removal of Hg(0), SO2 and NO was studied. The results showed that a high efficiency of Hg(0) removal was obtained by using Ag/AgBr-Ag2CO3 hybrids under fluorescent lamp irradiation. The AgBr content, FSL irradiation, solution temperature, and SO2 all exhibited significant effects on Hg(0) removal, while NO had slight effect on Hg(0) removal. The addition of Ca(OH)2 demonstrated a little impact on Hg(0) removal and could significantly improve the SO2-resistance performance of Ag/AgBr(0.7)-Ag2CO3 hybrid. The characterization results exhibited that hydroxyl radical (OH), superoxide radical (O2(-)), hole (h(+)), and Br(0), were reactive species responsible for removing Hg(0), and the h(+) played a key role in Hg(0) removal. PMID:27135702

  2. Polarized proton acceleration program at the AGS

    SciTech Connect

    Lee, Y.Y.

    1981-01-01

    The unexpected importance of high energy spin effects and the success of the ZGS in correcting many intrinsic and imperfection depolarizing resonances led us to attempt to accelerate polarized protons in the AGS. A multi-university/laboratory collaborative effort involving Argonne, Brookhaven, Michigan, Rice and Yale is underway to improve and modify to accelerate polarized protons. From the experience at the ZGS and careful studies made us confident of the feasibility of achieving a polarization of over 60 percent up to 26 GeV/c with an intensity of 10/sup 11/ approx. 10/sup 12/ per pulse. The first polarized proton acceleration at the AGS is expected in 1983.

  3. RESONANT EXTRACTION PARAMETERS FOR THE AGS BOOSTER.

    SciTech Connect

    BROWN,K.A.; CULLEN,J.; GLENN,J.W.; MAPES,M.; MARNERIS,I.; TSOUPAS,N.; SNYDSTRUP,L.; VAN ASSELT,W.

    2001-06-18

    Brookhaven's AGS Booster is the injector for the AGS. It is being modified to send resonant extracted heavy ions to a new beam line, the Booster Applications Facility (BAF). The design of the resonant extraction system for BAF was described in [1]. This note will give a more detailed description of the system and describe the predicted resonant beam time structure. We will describe tune space manipulations necessary to extract the resonant beam at the maximum Booster rigidity, schemes for performing resonant extraction, and describe the modifications required to perform bunched beam extraction to the BAF facility.

  4. Reducing Strength Prevailing at Root Surface of Plants Promotes Reduction of Ag+ and Generation of Ag0/Ag2O Nanoparticles Exogenously in Aqueous Phase

    PubMed Central

    Pardha-Saradhi, Peddisetty; Yamal, Gupta; Peddisetty, Tanuj; Sharmila, Peddisetty; Nagar, Shilpi; Singh, Jyoti; Nagarajan, Rajamani; Rao, Kottapalli S.

    2014-01-01

    Potential of root system of plants from wide range of families to effectively reduce membrane impermeable ferricyanide to ferrocyanide and blue coloured 2,6-dichlorophenol indophenol (DCPIP) to colourless DCPIPH2 both under non-sterile and sterile conditions, revealed prevalence of immense reducing strength at root surface. As generation of silver nanoparticles (NPs) from Ag+ involves reduction, present investigations were carried to evaluate if reducing strength prevailing at surface of root system can be exploited for reduction of Ag+ and exogenous generation of silver-NPs. Root system of intact plants of 16 species from 11 diverse families of angiosperms turned clear colorless AgNO3 solutions, turbid brown. Absorption spectra of these turbid brown solutions showed silver-NPs specific surface plasmon resonance peak. Transmission electron microscope coupled with energy dispersive X-ray confirmed the presence of distinct NPs in the range of 5–50 nm containing Ag. Selected area electron diffraction and powder X-ray diffraction patterns of the silver NPs showed Bragg reflections, characteristic of crystalline face-centered cubic structure of Ag0 and cubic structure of Ag2O. Root system of intact plants raised under sterile conditions also generated Ag0/Ag2O-NPs under strict sterile conditions in a manner similar to that recorded under non-sterile conditions. This revealed the inbuilt potential of root system to generate Ag0/Ag2O-NPs independent of any microorganism. Roots of intact plants reduced triphenyltetrazolium to triphenylformazon and impermeable ferricyanide to ferrocyanide, suggesting involvement of plasma membrane bound dehydrogenases in reduction of Ag+ and formation of Ag0/Ag2O-NPs. Root enzyme extract reduced triphenyltetrazolium to triphenylformazon and Ag+ to Ag0 in presence of NADH, clearly establishing potential of dehydrogenases to reduce Ag+ to Ag0, which generate Ag0/Ag2O-NPs. Findings presented in this manuscript put forth a novel, simple

  5. Germany Since Unification. Workshop Leader's Manual. An Introduction to Social Studies Instructional Resource Materials for Teaching about Germany Since Unification.

    ERIC Educational Resources Information Center

    Blankenship, Glen

    This manual is designed to offer support for the instructional resources guides on "Germany since Unification." It provides the basis for a full-day inservice training session on the use of those materials. The format can be modified to meet the needs of leaders, audiences, and time frames. Using the materials developed by teachers and sponsored…

  6. Facile synthesis of novel Ag/AgI/BiOI composites with highly enhanced visible light photocatalytic performances

    SciTech Connect

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Novel Ag/AgI/BiOI composites were controllably synthesized via a facile ion-exchange followed by photoreduction strategy by using hierarchical BiOI microflower as substrate. The as-prepared Ag/AgI/BiOI composites were studied by X-ray powder diffractometer (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) surface area analyzer and UV–vis diffuse reflectance spectroscopy (DRS). Under visible light (λ>420 nm), Ag/AgI/BiOI displayed highly enhanced photocatalytic activities for degradation of methyl orange (MO) compared to the pure hierarchical BiOI, which was mainly ascribed to the highly efficient separation of electrons and holes through the closely contacted interfaces in the Ag/AgI/BiOI ternary system. - Graphical abstract: Ag/AgI/BiOI displayed excellent photocatalytic activities for methyl orange degradation under visible light, which was mainly ascribed to the highly efficient separation of electrons and holes through Z-scheme pathway. Display Omitted - Highlights: • Novel Ag/AgI/BiOI composites were successfully synthesized. • Ag/AgI/BiOI displayed higher visible light activities than those of pure BiOI and AgI. • ·O{sub 2}{sup −} and h{sup +}, especially ·O{sub 2}{sup −}, dominated the photodegradation process of MO. • A Z-scheme pattern was adopted for Ag/AgI/BiOI activity enhancement.

  7. The AGS (alternating gradient synchrotron): Performance and potential

    SciTech Connect

    Ratner, L.G.

    1989-01-01

    This report discusses the following topics on the Brookhaven AGS: basic parameters, description of the accelerator complex and proton operation; operation with heavy ions and polarized protons; AGS upgrades and expanded potential. (LSP)

  8. Opinion-Makers or Enlighteners? Training and Further Training of Journalists in Germany.

    ERIC Educational Resources Information Center

    Meyn, Hermann

    1992-01-01

    This special report discusses journalism in Germany, focusing especially on the training of journalists. The report is presented under the following headings: In retrospect (a brief description of journalism in the former East Germany); The media range in the Federal Republic of Germany; Journalist--a dream profession?; Freedom of the press and…

  9. Ubersichten: Overview of the Federal Republic of Germany and the Federal States. Social Studies Lessons.

    ERIC Educational Resources Information Center

    Blankenship, Glen; Tinkler, D. William

    This series of lesson plans provides an overview of the Federal Republic of Germany. Transparencies and instructions are provided for each of the four lessons. Lesson 1 looks at "Culture and Perspective Taking on the Federal Republic of Germany" with five activities relating to: (1) "Impressions of Germany and Germans"; (2) "German National…

  10. Germany's Persistent Balance-of-Payments Disequilibrium Revisited. German Studies Notes.

    ERIC Educational Resources Information Center

    Kindleberger, Charles P.

    This essay compares Germany's persistent financial disequilibrium with the balance of payments situation in the United States. Delivered at a Symposium on German Economic Growth and Stability, the author concentrates on Germany's balance of payments surplus and presents U.S. figures mainly as a point of comparison. The material on Germany has been…

  11. Time Line: An Annotated Chronology of Events in Postwar Germany and the European Community.

    ERIC Educational Resources Information Center

    Kraemer, Dagmar

    1993-01-01

    Presents a selective chronology of three aspects of German history since World War II: the origins of the postwar division of Germany; the effects of two major policy decisions by West Germany after 1949; and the unification process after 1989. Contends that France and Germany will remain the core nations in the evolution of the European…

  12. Germany's Armed Forces in the Second World War: Manpower, Armaments, and Supply.

    ERIC Educational Resources Information Center

    Balsamo, Larry T.

    1991-01-01

    Discusses the state of Germany's armed forces in World War II. Describes Germany's progress from inferior weaponry and unprepared military at the beginning of the war to superior weapons and fighting. Stresses heavy German dependence on horse drawn supply. Credits Germany's defeat to human attrition accelerated by Hitler's operational leadership.…

  13. Learning for the Working World: Vocational Training in the Federal Republic of Germany. [Revised.

    ERIC Educational Resources Information Center

    Schlicht, Michael

    1995-01-01

    This document presents an overview of the past, present, and future of vocational training (VT) in the Federal Republic of Germany. The following topics are discussed: place of VT among the various institutions constituting Germany's education system; Germany's dual system of on-the-job and school VT (historical development, training regulations,…

  14. Study of structural modification of PVA by incorporating Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Saini, Isha; Sharma, Annu; Rozra, Jyoti; Aggarwal, Sanjeev; Dhiman, Rajnish; Sharma, Pawan K.

    2016-05-01

    Nanocomposites of PVA with Ag nanoparticles dispersed in it were synthesized using solution casting method. The morphology and size distribution of Ag nanoparticles embedded in PVA matrix were obtained by transmission electron microscopy (TEM) and Field emission scanning electron microscopy (FE-SEM). Raman spectroscopy was used to examine structural changes taking place inside polyvinyl alcohol (PVA) matrix due to incorporation of Ag nanoparticle. Raman analysis indicates that Ag nanoparticles interact with PVA through H-bonding.

  15. A multi-wire beam profile monitor in the AGS

    SciTech Connect

    Huang, H.; Buxton, W.; Castillo, V.; Glenn, J.W.

    1997-07-01

    A multi-wire beam profile monitor which can be used to directly monitor and control the optical matching between the Booster and AGS rings has been installed and tested in the AGS. Placement of a multi-wire monitor directly in the AGS provides profile measurements taken upon injection and the first two or more revolutions of the beam. The data from such measurements can be used to determine the optical properties of the beam transport line leading into the AGS.

  16. Development of a Rhizoctonia solani AG1-IB Specific Gene Model Enables Comparative Genome Analyses between Phytopathogenic R. solani AG1-IA, AG1-IB, AG3 and AG8 Isolates.

    PubMed

    Wibberg, Daniel; Rupp, Oliver; Blom, Jochen; Jelonek, Lukas; Kröber, Magdalena; Verwaaijen, Bart; Goesmann, Alexander; Albaum, Stefan; Grosch, Rita; Pühler, Alfred; Schlüter, Andreas

    2015-01-01

    Rhizoctonia solani, a soil-born plant pathogenic basidiomycetous fungus, affects various economically important agricultural and horticultural crops. The draft genome sequence for the R. solani AG1-IB isolate 7/3/14 as well as a corresponding transcriptome dataset (Expressed Sequence Tags--ESTs) were established previously. Development of a specific R. solani AG1-IB gene model based on GMAP transcript mapping within the eukaryotic gene prediction platform AUGUSTUS allowed detection of new genes and provided insights into the gene structure of this fungus. In total, 12,616 genes were recognized in the genome of the AG1-IB isolate. Analysis of predicted genes by means of different bioinformatics tools revealed new genes whose products potentially are involved in degradation of plant cell wall components, melanin formation and synthesis of secondary metabolites. Comparative genome analyses between members of different R. solani anastomosis groups, namely AG1-IA, AG3 and AG8 and the newly annotated R. solani AG1-IB genome were performed within the comparative genomics platform EDGAR. It appeared that only 21 to 28% of all genes encoded in the draft genomes of the different strains were identified as core genes. Based on Average Nucleotide Identity (ANI) and Average Amino-acid Identity (AAI) analyses, considerable sequence differences between isolates representing different anastomosis groups were identified. However, R. solani isolates form a distinct cluster in relation to other fungi of the phylum Basidiomycota. The isolate representing AG1-IB encodes significant more genes featuring predictable functions in secondary metabolite production compared to other completely sequenced R. solani strains. The newly established R. solani AG1-IB 7/3/14 gene layout now provides a reliable basis for post-genomics studies.

  17. The electron paramagnetic resonance spectrum of Ag2 3

    NASA Astrophysics Data System (ADS)

    van der Pol, A.; Reijersen, E. J.; de Boer, E.; Wasowicz, T.; Michalik, J.

    A highly resolved EPR spectrum of the silver trimer 109Ag2+3, present in 109Ag1-NaA zeolite, has been measured. The spectrum is characterized by an axially symmetric spin Hamiltonian having and for each of the 109Ag nuclei tMPH0037_images.

  18. AGS experiments -- 1996, 1997, 1998, 1999. Fifteenth edition

    SciTech Connect

    Lo Presti, P.

    1999-03-01

    This report is a compilation of two-page summaries for AGS experiments for FY 1996, FY 1997, FY 1998, FY 1999. The bulk of the experiments are for high energy physics and nuclear physics programs. Also included are the run schedules for the AGS for each of those years and a listing of publications of AGS experiments for 1982--1999.

  19. Effect of Ag+ and PO43‑ ratios on the microstructure and photocatalytic activity of Ag3PO4

    NASA Astrophysics Data System (ADS)

    Qin, Jiaqian; Zhang, Xinyu; Yang, Chengwu; Song, Aijun; Zhang, Bing; Rajendran, Saravanan; Ma, Mingzhen; Liu, Riping

    2016-09-01

    In this work, the catalyst silver phosphate (Ag3PO4) with different initial ratios of Ag+ and PO43‑ in aqueous solution was synthesized by a simple precipitation method from AgNO3 and NH4H2PO4 which were used as the precursor. After that, the prepared samples were characterized by different techniques such as field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), UV-visible diffuse reflectance spectroscopy (UV-DRS) and decomposition evolution of rhodamine B (RhB) solution. The results indicate that the initial ratios of Ag+/PO43‑ in aqueous solution can modify the morphology and also it can significantly affect the photocatalytic performance. During photocatalytic process, the rich Ag+ ion Ag3PO4 can form the surface plasmon resonance (SPR) of Ag nanoparticles, which inhibit the reduction of Ag3PO4 resulting in higher photocatalytic activity and stability.

  20. Comparison of drug abuse in Germany and China.

    PubMed

    Michels, Ingo Ilja; Fang, Yu-Xia; Zhao, Dong; Zhao, Li-Yan; Lu, Lin

    2007-10-01

    Drug abuse has a long, but also different history in Germany and China. The Opium War largely influenced the history of China in 19th century; however, China was once recognized as a drug-free nation for 3 decades from the 1950s to the 1980s. Drug abuse has spread quickly since re-emerging as a national problem in China in the late 1980s. The number of registered drug abusers increased from 70 000 in 1990 to more than 1 million by the end of 2005. In past decades, illicit drug trafficking and production have swept most provinces in China, and drug abuse has caused many problems for both abusers and the community. One major drug-related problem is the spread of HIV, which has caused major social and economic damage in China. Germany, the largest developed European country, also faces the drug and addiction problem. Germany has about 150 000 heroin addicts, for whom HIV/AIDS has become a serious threat since the mid 1980s. To control the drug problem, the German Government adopted the pAction Plan on Drugs and Addictionq in 2003; the China Central Government approved a similar regulation in the antidrug campaign in 2005. Germany has experience in reducing drug-related harm. The methadone maintenance treatment (MMT) program has run for more than 20 years and the public has become more tolerant of addicts. In 2003, China began the MMT program for controlling the spread of HIV/AIDS. It is necessary for China to learn from developed countries to acquire success in its antidrug campaign. In this review, we will go over the differences and similarities in drug abuse between Germany and China. The differences are related to history, population and economics, drug policy context, drug laws, HIV/hepatitis C virus infection, the MMT program and so on. These 2 nations have drug abuse problems with different histories and currently use different approaches to handle illicit drug marketing and use. The legal penalties for illicit drug offences reflect the social differences of

  1. Comparison of drug abuse in Germany and China.

    PubMed

    Michels, Ingo Ilja; Fang, Yu-Xia; Zhao, Dong; Zhao, Li-Yan; Lu, Lin

    2007-10-01

    Drug abuse has a long, but also different history in Germany and China. The Opium War largely influenced the history of China in 19th century; however, China was once recognized as a drug-free nation for 3 decades from the 1950s to the 1980s. Drug abuse has spread quickly since re-emerging as a national problem in China in the late 1980s. The number of registered drug abusers increased from 70 000 in 1990 to more than 1 million by the end of 2005. In past decades, illicit drug trafficking and production have swept most provinces in China, and drug abuse has caused many problems for both abusers and the community. One major drug-related problem is the spread of HIV, which has caused major social and economic damage in China. Germany, the largest developed European country, also faces the drug and addiction problem. Germany has about 150 000 heroin addicts, for whom HIV/AIDS has become a serious threat since the mid 1980s. To control the drug problem, the German Government adopted the pAction Plan on Drugs and Addictionq in 2003; the China Central Government approved a similar regulation in the antidrug campaign in 2005. Germany has experience in reducing drug-related harm. The methadone maintenance treatment (MMT) program has run for more than 20 years and the public has become more tolerant of addicts. In 2003, China began the MMT program for controlling the spread of HIV/AIDS. It is necessary for China to learn from developed countries to acquire success in its antidrug campaign. In this review, we will go over the differences and similarities in drug abuse between Germany and China. The differences are related to history, population and economics, drug policy context, drug laws, HIV/hepatitis C virus infection, the MMT program and so on. These 2 nations have drug abuse problems with different histories and currently use different approaches to handle illicit drug marketing and use. The legal penalties for illicit drug offences reflect the social differences of

  2. Fabrication of Sn-3.5Ag Eutectic Alloy Powder by Annealing Sub-Micrometer Sn@Ag Powder Prepared by Citric Acid-Assisted Ag Immersion Plating.

    PubMed

    Chee, Sang-Soo; Choi, Eun Byeol; Lee, Jong-Hyun

    2015-11-01

    A Sn-3.5Ag eutectic alloy powder has been developed by chemically synthesizing sub-micrometer Sn@Ag powder at room temperature. This synthesis was achieved by first obtaining a sub-micrometer Sn powder for the core using a modified variant of the polyol method, and then coating this with a uniformly thin and continuous Ag layer through immersion plating in 5.20 mM citric acid. The citric acid was found to play multiple roles in the Ag coating process, acting as a chelating agent, a reducing agent and a stabilizer to ensure coating uniformity; and as such, the amount used has an immense influence on the coating quality of the Ag shells. It was later verified by transmission electron microscopy and X-ray diffraction analysis that the coated Ag layer transfers to the Sn core via diffusion to form an Ag3Sn phase at room temperature. Differential scanning calorimetry also revealed that the synthesized Sn@Ag powder is nearly transformed into Sn-3.5Ag eutectic alloy powder upon annealing three times at a temperature of up to 250 degrees C, as evidenced by a single melting peak at 220.5 degrees C. It was inferred from this that Sn-3.5Ag eutectic alloy powder can be successfully prepared through the synthesis of core Sn powders by a modified polyol method, immersion plating using citric acid, and annealing, in that order.

  3. Antibacterial Ag/a-C nanocomposite coatings: The influence of nano-galvanic a-C and Ag couples on Ag ionization rates

    NASA Astrophysics Data System (ADS)

    Manninen, N. K.; Calderon, S.; Carvalho, I.; Henriques, M.; Cavaleiro, A.; Carvalho, S.

    2016-07-01

    Biofilm formation has been pointed as a major concern in different industrial applications, namely on biomedical implants and surgical instruments, which has prompted the development of new strategies for production of efficient antimicrobial surfaces. In this work, nano-galvanic couples were created to enhance the antibacterial properties of silver, by embedding it into amorphous carbon (a-C) matrix. The developed Ag/a-C nanocomposite coatings, deposited by magnetron sputtering, revealed an outstanding antibacterial activity against Staphylococcus epidermidis, promoting a total reduction in biofilm formation with no bacteria counts in all dilution. The open circuit potential (OCP) tests in 0.9% NaCl confirmed that a-C shows a positive OCP value, in contrast to Ag coating, thus enhancing the ionization of biocidal Ag+ due to the nano-galvanic couple activation. This result was confirmed by the inductively coupled plasma-optical emission spectroscopy (ICP-OES), which revealed a higher Ag ionization rate in the nanocomposite coating in comparison with the Ag coating. The surface of Ag/a-C and Ag coatings immersed in 0.9% NaCl were monitored by scanning electron microscopy (SEM) over a period of 24 h, being found that the Ag ionization determined by ICP-OES was accompanied by an Ag nanoparticles coalescence and agglomeration in Ag/a-C coating.

  4. Communication: Kinetics of chemical ordering in Ag-Au and Ag-Ni nanoalloys

    NASA Astrophysics Data System (ADS)

    Calvo, F.; Fortunelli, A.; Negreiros, F.; Wales, D. J.

    2013-09-01

    The energy landscape and kinetics of medium-sized Ag-Au and Ag-Ni nanoalloy particles are explored via a discrete path sampling approach, focusing on rearrangements connecting regions differing in chemical order. The highly miscible Ag27Au28 supports a large number of nearly degenerate icosahedral homotops. The transformation from reverse core-shell to core-shell involves large displacements away from the icosahedron through elementary steps corresponding to surface diffusion and vacancy formation. The immiscible Ag42Ni13 naturally forms an asymmetric core-shell structure, and about 10 eV is required to extrude the nickel core to the surface. The corresponding transformation occurs via a long and smooth sequence of surface displacements. For both systems the rearrangement kinetics exhibit Arrhenius behavior. These results are discussed in the light of experimental observations.

  5. Geometry optimization and structural distribution of silver clusters from Ag 170 to Ag 310

    NASA Astrophysics Data System (ADS)

    Shao, Xueguang; Yang, Xiaoli; Cai, Wensheng

    2008-07-01

    Silver clusters in the size range of 170-310 were optimized with a modified dynamic lattice search (DLS) method. Considering the computational complexity, only 21 clusters of several tens and magic numbers of atoms were investigated. The interaction of silver atoms is modeled by the Gupta potential. Results show that, between the 21 clusters, nine fcc and twelve m-Dh structures are obtained. Compared with the structures adopted by Ag 13 to Ag 160, the main motif is still m-Dh in the range of Ag 170-Ag 310, but the ratio of fcc structures obviously increases. It can, therefore, be deduced that the fcc motif is more stable for larger size silver clusters.

  6. High Resolution PDF Measurements on Ag Nanoparticles

    SciTech Connect

    Rocha, Tulio C. R.; Martin, Chris; Kycia, Stefan; Zanchet, Daniela

    2009-01-29

    The quantitative analysis of structural defects in Ag nanoparticles was addressed in this work. We performed atomic scale structural characterization by a combination of x-ray diffraction (XRD) using the Pair Distribution Function analysis (PDF) and High Resolution Transmission Electron Microscopy (HRTEM). The XRD measurements were performed using an innovative instrumentation setup to provide high resolution PDF patterns.

  7. Normal-incidence steering effect in crystal growth: Ag/Ag(100)

    SciTech Connect

    Montalenti, F.; Voter, A. F.

    2001-08-15

    During crystal growth by vapor deposition, normal incident atoms are deflected toward three-dimensional surface structures. The effect becomes strong when the atoms are deposited with a low initial kinetic energy. At low T this steering effect induces an instability in the growth process, causing a perfectly flat surface to become rough after a few monolayers are deposited. Quantitative results for the initial stages of growth of Ag/Ag(100) at T{approx}0 K are presented.

  8. Surface-enhanced Raman scattering from AgNP-graphene-AgNP sandwiched nanostructures

    NASA Astrophysics Data System (ADS)

    Wu, Jian; Xu, Yijun; Xu, Pengyu; Pan, Zhenghui; Chen, Sheng; Shen, Qishen; Zhan, Li; Zhang, Yuegang; Ni, Weihai

    2015-10-01

    We developed a facile approach toward hybrid AgNP-graphene-AgNP sandwiched structures using self-organized monolayered AgNPs from wet chemical synthesis for the optimized enhancement of the Raman response of monolayer graphene. We demonstrate that the Raman scattering of graphene can be enhanced 530 fold in the hybrid structure. The Raman enhancement is sensitively dependent on the hybrid structure, incident angle, and excitation wavelength. A systematic simulation is performed, which well explains the enhancement mechanism. Our study indicates that the enhancement resulted from the plasmonic coupling between the AgNPs on the opposite sides of graphene. Our approach towards ideal substrates offers great potential to produce a ``hot surface'' for enhancing the Raman response of two-dimensional materials.We developed a facile approach toward hybrid AgNP-graphene-AgNP sandwiched structures using self-organized monolayered AgNPs from wet chemical synthesis for the optimized enhancement of the Raman response of monolayer graphene. We demonstrate that the Raman scattering of graphene can be enhanced 530 fold in the hybrid structure. The Raman enhancement is sensitively dependent on the hybrid structure, incident angle, and excitation wavelength. A systematic simulation is performed, which well explains the enhancement mechanism. Our study indicates that the enhancement resulted from the plasmonic coupling between the AgNPs on the opposite sides of graphene. Our approach towards ideal substrates offers great potential to produce a ``hot surface'' for enhancing the Raman response of two-dimensional materials. Electronic supplementary information (ESI) available: Additional SEM images, electric field enhancement profiles, Raman scattering spectra, and structure-dependent peak ratios. See DOI: 10.1039/c5nr04500b

  9. A dry method to synthesize dendritic Ag2Se nanostructures utilizing CdSe quantum dots and Ag thin films.

    PubMed

    Hu, Lian; Zhang, Bingpo; Xu, Tianning; Li, Ruifeng; Wu, Huizhen

    2015-01-01

    Dendritic Ag2Se nanostructures are synthesized in a dry environment by UV irradiating the hybrids composed of CdSe quantum dots (QDs) and silver (Ag). UV irradiation on CdSe QDs induces a photooxidation effect on the QD surface and leads to the formation of SeO2 components. Then SeO2 reacts with the Ag atoms in either Ag film or QD layer to produce the Ag2Se. The growth mechanism of Ag2Se dendrites on solid Ag films is explored and explained by a diffusion limited aggregation model in which the QD layer provides enough freedom for Ag2Se motion. Since the oxidation of the CdSe QDs is the critical step for the Ag2Se dendrites formation this dry chemical interaction between QDs and Ag film can be applied in the study of the QD surface chemical properties. With this dry synthesis method, the Ag2Se dendrites can also be facilely formed at the designed area on Ag substrates. PMID:25483981

  10. A dry method to synthesize dendritic Ag2Se nanostructures utilizing CdSe quantum dots and Ag thin films

    NASA Astrophysics Data System (ADS)

    Hu, Lian; Zhang, Bingpo; Xu, Tianning; Li, Ruifeng; Wu, Huizhen

    2015-01-01

    Dendritic Ag2Se nanostructures are synthesized in a dry environment by UV irradiating the hybrids composed of CdSe quantum dots (QDs) and silver (Ag). UV irradiation on CdSe QDs induces a photooxidation effect on the QD surface and leads to the formation of SeO2 components. Then SeO2 reacts with the Ag atoms in either Ag film or QD layer to produce the Ag2Se. The growth mechanism of Ag2Se dendrites on solid Ag films is explored and explained by a diffusion limited aggregation model in which the QD layer provides enough freedom for Ag2Se motion. Since the oxidation of the CdSe QDs is the critical step for the Ag2Se dendrites formation this dry chemical interaction between QDs and Ag film can be applied in the study of the QD surface chemical properties. With this dry synthesis method, the Ag2Se dendrites can also be facilely formed at the designed area on Ag substrates.

  11. New insight into daylight photocatalysis of AgBr@Ag: synergistic effect between semiconductor photocatalysis and plasmonic photocatalysis.

    PubMed

    Jiang, Jing; Li, Hao; Zhang, Lizhi

    2012-05-14

    Noble metal nanoparticles (NPs) are often used as electron scavengers in conventional semiconductor photocatalysis to suppress electron-hole (e(-)-h(+) ) recombination and promote interfacial charge transfer, and thus enhance photocatalytic activity of semiconductors. In this contribution, it is demonstrated that noble metal NPs such as Ag NPs function as visible-light harvesting and electron-generating centers during the daylight photocatalysis of AgBr@Ag. Novel Ag plasmonic photocatalysis could cooperate with the conventional AgBr semiconductor photocatalysis to enhance the overall daylight activity of AgBr@Ag greatly because of an interesting synergistic effect. After a systematic investigation of the daylight photocatalysis mechanism of AgBr@Ag, the synergistic effect was attributed to surface plasmon resonance induced local electric field enhancement on Ag, which can accelerate the generation of e(-)-h(+) pairs in AgBr, so that more electrons are produced in the conduction band of AgBr under daylight irradiation. This study provides new insight into the photocatalytic mechanism of noble metal/semiconductor systems as well as the design and fabrication of novel plasmonic photocatalysts.

  12. A comparative study about electronic structures at rubrene/Ag and Ag/rubrene interfaces

    SciTech Connect

    Sinha, Sumona Mukherjee, M.

    2015-10-15

    The contact between the electrode and the organic semiconductor is one of the most crucial factors in determining the organic device performance. The development and production technology of different organic devices require the understanding of different types of metal/organic semiconducting thin film interfaces. Comparisons about the electronic structures at Rubrene/Ag and Ag/Rubrene interfaces have been studied using photoemission spectroscopy. The Ag on rubrene interfaces is found to show more interesting and complex natures than its counterpart. The vacuum level (VL) was shifted about 0.51 eV from push back effect for deposition of 5 Å rubrene onto Ag film whereas the electronic features of silver was only suppressed and no energy shift was resulted. While the deposition of 5 Å Ag onto rubrene film leads to the diffusion of the Ag atoms, as a cluster with quantum size effect, inside the film. Angle dependent XPS measurement indicates that diffused metal clusters were present at entire probed depth of the film. Moreover these clusters dope the uppermost surface of the rubrene film which consequences a shift of the electronic states of thick organic film towards higher binding energy. The VL was found to shift about 0.31 eV toward higher binding energy whereas the shift was around 0.21 eV for the electronic states of rubrene layer.

  13. Enhancement of ferromagnetism by Ag doping in Ni-Mn-In-Ag Heusler alloys

    NASA Astrophysics Data System (ADS)

    Pandey, Sudip; Quetz, Abdiel; Aryal, Anil; Dubenko, Igor; Mazumdar, Dipanjan; Stadler, Shane; Ali, Naushad

    The effect of Ag on the structural, magnetocaloric, and thermomagnetic properties of Ni50Mn35In15-xAgx (x = 0.1, 0.2, 0.5, and 1) Heusler alloys was studied. The magnitude of the magnetization change at martensitic transition temperature (TM) decreases with increasing Ag concentration A smaller magnetic entropy changes (ΔSM) for the alloys with higher Ag concentration is observed. A shift of TM by about 25 K to a higher temperature was detected for P = 6.6 kbar with respect to ambient pressure. Large drop of resistivity is observed with the increase of Ag concentration. The magnetoresistance is dramatically suppressed with increasing Ag concentration due to the weakening of the antiferromagnetic interactions in the martensitic phase. The experimental results demonstrate that Ag substitution in Ni50Mn35In15-xAgx Heusler alloys suppresses the AFM interactions and enhances the FM interactions in the alloys. The possible mechanisms responsible for the observed behavior are discussed. Acknowledgement: This work was supported by the Office of Basic Energy Sciences, Material Science Division of the U.S. Department of Energy (DOE Grant No. DE-FG02-06ER46291 and DE-FG02-13ER46946).

  14. The Effect of Ag and Ag+N Ion Implantation on Cell Attachment Properties

    SciTech Connect

    Urkac, Emel Sokullu; Oztarhan, Ahmet; Gurhan, Ismet Deliloglu; Iz, Sultan Gulce; Tihminlioglu, Funda; Oks, Efim; Nikolaev, Alexey; Ila, Daryush

    2009-03-10

    Implanted biomedical prosthetic devices are intended to perform safely, reliably and effectively in the human body thus the materials used for orthopedic devices should have good biocompatibility. Ultra High Molecular Weight Poly Ethylene (UHMWPE) has been commonly used for total hip joint replacement because of its very good properties. In this work, UHMWPE samples were Ag and Ag+N ion implanted by using the Metal-Vapor Vacuum Arc (MEVVA) ion implantation technique. Samples were implanted with a fluency of 1017 ion/cm2 and extraction voltage of 30 kV. Rutherford Backscattering Spectrometry (RBS) was used for surface studies. RBS showed the presence of Ag and N on the surface. Cell attachment properties investigated with model cell lines (L929 mouse fibroblasts) to demonstrate that the effect of Ag and Ag+N ion implantation can favorably influence the surface of UHMWPE for biomedical applications. Scanning electron microscopy (SEM) was used to demonstrate the cell attachment on the surface. Study has shown that Ag+N ion implantation represents more effective cell attachment properties on the UHMWPE surfaces.

  15. Ag induced electromagnetic interference shielding of Ag-graphite/PVDF flexible nanocomposites thinfilms

    SciTech Connect

    Kumaran, R.; Alagar, M.; Dinesh Kumar, S.; Subramanian, V.; Dinakaran, K.

    2015-09-14

    We report Ag nanoparticle induced Electromagnetic Interference (EMI) shielding in a flexible composite films of Ag nanoparticles incorporated graphite/poly-vinylidene difluoride (PVDF). PVDF nanocomposite thin-films were synthesized by intercalating Ag in Graphite (GIC) followed by dispersing GIC in PVDF. The X-ray diffraction analysis and the high-resolution transmission electron microscope clearly dictate the microstructure of silver nanoparticles in graphite intercalated composite of PVDF matrix. The conductivity values of nanocomposites are increased upto 2.5 times when compared to neat PVDF having a value of 2.70 S/cm at 1 MHz. The presence of Ag broadly enhanced the dielectric constant and lowers the dielectric loss of PVDF matrix proportional to Ag content. The EMI shielding effectiveness of the composites is 29.1 dB at 12.4 GHz for the sample having 5 wt. % Ag and 10 wt. % graphite in PVDF.

  16. The Effect of Ag and Ag+N Ion Implantation on Cell Attachment Properties

    NASA Astrophysics Data System (ADS)

    Urkac, Emel Sokullu; Oztarhan, Ahmet; Tihminlioglu, Funda; Gurhan, Ismet Deliloglu; Iz, Sultan Gulce; Oks, Efim; Nikolaev, Alexey; Ila, Daryush

    2009-03-01

    Implanted biomedical prosthetic devices are intended to perform safely, reliably and effectively in the human body thus the materials used for orthopedic devices should have good biocompatibility. Ultra High Molecular Weight Poly Ethylene (UHMWPE) has been commonly used for total hip joint replacement because of its very good properties. In this work, UHMWPE samples were Ag and Ag+N ion implanted by using the Metal-Vapor Vacuum Arc (MEVVA) ion implantation technique. Samples were implanted with a fluency of 1017 ion/cm2 and extraction voltage of 30 kV. Rutherford Backscattering Spectrometry (RBS) was used for surface studies. RBS showed the presence of Ag and N on the surface. Cell attachment properties investigated with model cell lines (L929 mouse fibroblasts) to demonstrate that the effect of Ag and Ag+N ion implantation can favorably influence the surface of UHMWPE for biomedical applications. Scanning electron microscopy (SEM) was used to demonstrate the cell attachment on the surface. Study has shown that Ag+N ion implantation represents more effective cell attachment properties on the UHMWPE surfaces.

  17. A comparative study about electronic structures at rubrene/Ag and Ag/rubrene interfaces

    NASA Astrophysics Data System (ADS)

    Sinha, Sumona; Mukherjee, M.

    2015-10-01

    The contact between the electrode and the organic semiconductor is one of the most crucial factors in determining the organic device performance. The development and production technology of different organic devices require the understanding of different types of metal/organic semiconducting thin film interfaces. Comparisons about the electronic structures at Rubrene/Ag and Ag/Rubrene interfaces have been studied using photoemission spectroscopy. The Ag on rubrene interfaces is found to show more interesting and complex natures than its counterpart. The vacuum level (VL) was shifted about 0.51 eV from push back effect for deposition of 5 Å rubrene onto Ag film whereas the electronic features of silver was only suppressed and no energy shift was resulted. While the deposition of 5 Å Ag onto rubrene film leads to the diffusion of the Ag atoms, as a cluster with quantum size effect, inside the film. Angle dependent XPS measurement indicates that diffused metal clusters were present at entire probed depth of the film. Moreover these clusters dope the uppermost surface of the rubrene film which consequences a shift of the electronic states of thick organic film towards higher binding energy. The VL was found to shift about 0.31 eV toward higher binding energy whereas the shift was around 0.21 eV for the electronic states of rubrene layer.

  18. Physician payment in Canada, Germany, and the United States.

    PubMed

    Galvin, R S

    1993-01-01

    As the debate about reforming the U.S. health care system intensifies, interest has focused on three alternative delivery systems: the predominantly private-sector model in the United States, the provincial-government health insurance model of Canada, and the social insurance model of Germany. The organization of physician payment is an important part of all these health care systems. To maintain an affordable system that delivers high-quality care, payment to physicians must be sufficient to attract and maintain an able group of doctors, while not exceeding an amount that the country can afford. In this article, these three systems will be examined, and an attempt will be made to apply the lessons learned from Germany and Canada to the direction of physician payment reform in the United States.

  19. [Intentions to return home of foreigners living in Germany].

    PubMed

    Waldorf, B

    1997-01-01

    "This article provides a comparison between intentions to return home and observable return migration behaviour of Italians and Turks living in Germany. It is argued that external factors (economic and legal conditions) and internal factors (assimilation in the host country and ties to home) influence the discrepancies between return intentions and behaviours. Using micro-data from the MARPLAN surveys and macro-data published by the German government for the 1970s and 1980s, the analysis reveals that the return migration behaviour of Italians is by and large consistent with their expressed intentions. In contrast, Turks are less prone to translate their intentions into behaviour. Specifically, Turks are more likely to postpone their intended return and extend their sojourn in Germany." (EXCERPT)

  20. Continuity and change in Germany's treatment of non-Germans.

    PubMed

    O'brien, P

    1988-01-01

    This essay criticizes 2 conventional approaches to migrants in Germany. 1 focuses on racism in German history while the 2nd examines the tradition of repressive laws which exploit and dominate foreigners. This essay finds these approaches appropriate until the 1970s. From that point, German governments tend to accept foreigners and develop new programs of integration. The essay concludes with ways future research can uncover new and subtle forms of control and domination; the goal of integration itself may become a form of control. Future research can investigate 1) the extent to which integration is rhetorical rather than substantial, 2) the extent to which policies create restrictive forms of integration, and 3) how integration forces migrants to make choices they might not choose to make, such as the choice forced by the current debate over which group of Moslems should rule Islam in Germany.

  1. Nitrous oxide emissions from rapeseed cultivation in Germany

    NASA Astrophysics Data System (ADS)

    Fuß, Roland; Andres, Monique; Hegewald, Hannes; Kesenheimer, Katharina; Koebke, Sarah; Räbiger, Thomas; Suárez Quiñones, Teresa; Walter, Katja; Stichnothe, Heinz; Flessa, Heinz

    2016-04-01

    About 12 % of Germany's agricultural area is used for rapeseed cultivation and two third of the harvest is converted to biodiesel. Due to requirements of the EU Renewables Directive the greenhouse gas (GHG) balance of rapeseed cultivation must be reported and sustainability criteria and GHG savings compared to fossil fuel must be achieved and certified. Current certified methodology estimates N2O field emissions from rapeseed cultivation using the IPCC Tier 1 approach based on a global emission factor (N2O emission per unit nitrogen fertilizer input) of 1 %, which is not specific for the crop. We present results from three years of measurements (2013 - 2015) on five field trials in Germany, which combined with data from a meta-analysis suggest that GHG emission factors of German rapeseed cultivation are lower than thought previously. Furthermore, results suggest that substitution of mineral fertilizers with organic fertilizers is a valid mitigation option since it avoids GHG emissions during production of mineral fertilizers.

  2. Implications of structural deficits for patient education in Germany.

    PubMed

    Keller, S; Basler, H

    2001-07-01

    Several changes in health politics and legal settings in recent years have affected the structure and practice of health promotion and patient education in Germany. The current legal background and its implications for patient education are discussed. Based on examples from four selected areas (cardiovascular diseases, diabetes mellitus, chronic pain, and asthma) the current practice of patient education in Germany is summarized. While many well-structured programs exist that are based on state-of-the-art guidelines, there is a lack of high quality research that documents the long-term effectiveness and cost-effectiveness of such approaches. Structural problems and an insufficient number of highly trained personnel result in the fact that many patients do not have access to standardized programs. Persisting compliance problems indicate that there is still room for improvement of patient education interventions. As important for the future, necessary changes in the legal settings and possible implications for the education of the educators are discussed.

  3. Synopsis of freshwater aquaculture legislation in Germany since national reunification.

    PubMed

    Schlotfeldt, H J

    1996-06-01

    Under German law, federal ministries are responsible for preparing legislation, while federal states (Länder) are responsible for applying the legislation. The author describes the system, contrasting it with the situation in former East Germany, where preparation and application of legislation were controlled centrally. The author also describes the various inland water fisheries Acts and regulations of the federal states of former West Germany which apply to aquaculture. There is a discussion of the impact on German freshwater aquaculture of the Federal Water Act, the Waste Water Levies Act, the Nature Conservation and Protection Act, the Conservation of Species Regulation, the Animal Welfare Act, the Fisheries Acts of the Länder, the Drug Act, the Animal Epidemic Act and the Fish Epidemics Regulation. The impact of this legislation varies considerably, and the extent of application is discussed. The economic changes in freshwater fish production are briefly summarised and their causes analysed. PMID:8890388

  4. Results from power quality measurements in Germany - An overview

    SciTech Connect

    Gerdes, G.J.; Santjer, F.

    1996-12-31

    Grid interferences caused by wind turbines (WT) are getting a severe problem in Germany with the fast increasing number of installed turbines. The wind energy capacity was doubled annually in the past three years. The actual situation and the plannings for the next years will lead to a situation, where high wind energy penetration will exercise a big influence on the power and voltage quality of local utility networks. Measurements performed in Germany according to a national guideline show a big variety in power quality performance of WT`s, which does affect the requirements for grid connection and thus the economical situation of wind energy projects to a large extent. The results from more than 25 power quality measurements will be discussed in this paper. 5 refs., 5 figs., 1 tab.

  5. [Interdisciplinary management of a large Legionella outbreak in Germany].

    PubMed

    Freudenmann, M; Kurz, S; von Baum, H; Reick, D; Schreff, A M; Essig, A; Lück, C; Gonser, T; Brockmann, S O; Härter, G; Eberhardt, B; Embacher, A; Höller, C

    2011-11-01

    Between December 2009 and the end of January 2010, the largest hitherto known outbreak of Legionella in Germany took place in the cities of Ulm and Neu-Ulm. Of a total of 64 patients involved, 60 patients had to be hospitalized, and 5 patients died from the infection. This event was caused by a wet cooling tower of a large air conditioning system in the city center of Ulm. The search for the source of the Legionella emission was extremely difficult, since these plants are neither notifiable nor subject to authorization in Germany. We report about the search for the source and the measures to control the outbreak. We also discuss communication and coordination during these investigations. Regulatory measures as proposed by the World Health Organization (WHO) and the European Network for Legionellosis (EWGLI) and already implemented in numerous other European countries would be desirable to prevent such outbreaks in the future. PMID:22015788

  6. Enhanced thermal stability of Ag nanorods through capping

    SciTech Connect

    Bachenheimer, Lou; Elliott, Paul; Stagon, Stephen; Huang, Hanchen

    2014-11-24

    Ag nanorods may serve as sensors in the detection of trace amounts of chemical agents, even single molecules, through surface enhanced Raman spectroscopy (SERS). However, thermal coarsening of Ag nanorods near room temperature limits their applications. This letter proposes the use of a thin oxide capping layer to enhance the thermal stability of Ag nanorods beyond 100 °C. Using electron microscopy characterization and SERS tests, the authors show that the proposed method is effective in stabilizing both morphology and sensitivity of Ag nanorods. The results of this work extend the applicability of Ag nanorods as chemical sensors to higher temperatures.

  7. High intensity proton operation at the Brookhaven AGS accelerator complex

    SciTech Connect

    Ahrens, L.A.; Blaskiewicz, M.; Bleser, E.; Brennan, J.M.; Gardner, C.; Glenn, J.W.; Onillon, E.; Reece, R.K.; Roser, T.; Soukas, A.

    1994-08-01

    With the completion of the AGS rf upgrade, and the implementation of a transition {open_quotes}jump{close_quotes}, all of accelerator systems were in place in 1994 to allow acceleration of the proton intensity available from the AGS Booster injector to AGS extraction energy and delivery to the high energy users. Beam commissioning results with these new systems are presented. Progress in identifying and overcoming other obstacles to higher intensity are given. These include a careful exploration of the stopband strengths present on the AGS injection magnetic porch, and implementation of the AGS single bunch transverse dampers throughout the acceleration cycle.

  8. Monitoring of West Nile virus infections in Germany.

    PubMed

    Ziegler, U; Seidowski, D; Angenvoort, J; Eiden, M; Müller, K; Nowotny, N; Groschup, M H

    2012-09-01

    West Nile virus (WNV) is a flavivirus that is maintained in an enzootic cycle between ornithophilic mosquitoes, mainly of the Culex genus, and certain wild bird species. Other bird species like ravens, jays and raptors are highly susceptible to the infection and may develop deadly encephalitis, while further species of birds are only going through subclinical infection. The objective of this study was to continue in years 2009-2011 the serological and molecular surveillance in wild birds in Germany (see Vector Borne Zoonotic Dis. 10, 639) and to expand these investigations for the first time also to sera from domestic poultry and horses collected between 2005 and 2009. All three cohorts function as indicators for the endemic circulation of WNV. The presence of WNV-specific antibodies was detected in all samples by virus neutralization test (VNT), indirect immunofluorescence test (IFT) and/or enzyme-linked immunosorbent assay (ELISA). The presence of WNV genomes was monitored in relevant sera using two qRT-PCRs that amplify lineage 1 and 2 strains. A total of 364 migratory and resident wild bird serum samples (with emphasis on Passeriformes and Falconiformes) as well as 1119 serum samples from domestic poultry and 1282 sera from horses were analysed. With the exception of one hooded crow, antibody carriers were exclusively found in migratory birds, but not in resident birds/domestic poultry or in local horses. Crows are facultative, short-distance winter migrants in Germany. WNV-specific nucleic acids could not be demonstrated in any of the samples. According to these data, there is no convincing evidence for indigenous WNV infections in equines and in wild/domestic birds in Germany. However, since a few years, WNV infections are endemic in other European countries such as Austria, Hungary, Greece and Italy, a state-of-the-art surveillance system for the detection of incursions of WNV into Germany deems mandatory.

  9. Historical perspective on neurosurgery in Germany after World War II.

    PubMed

    Collmann, Hartmut; Vitzthum, Hans-Ekkehart

    2008-11-01

    AFTER THE COLLAPSE of the Third Reich, the specialty of neurosurgery in Germany, although well developed in the late 1930s, had to start anew, and for decades to come, had to deal with the physical and political consequences of World War II. Because of the division of the country, neurosurgery developed separately in the two independent states. In West Germany, the evolution was promoted by a few personalities who represented different schools according to their own training: these "surgical neurologists" emphasized the neurological basis of neurosurgery and were represented by Traugott Riechert and the students of Otfrid Foerster, such as Arist Stender and Hans Kuhlendahl. In contrast, the "neurological surgeons" stressed their origins in general surgery. Their main proponent was Wilhelm Tönnis, who gained particular merit for promoting neurosurgical teaching, the development of new neurosurgical units, and the recognition of neurosurgery as an autonomous specialty. In East Germany, progress was delayed by a weak economy and a repressive political system. Yet several excellent neurosurgeons won international recognition, predominantly Georg Merrem, who came from the school of Fedor Krause. Following a worldwide trend, the number of neurosurgical units in West Germany increased dramatically from 18 in 1950 to 85 in 1988. In 2006, in the unified nation, 1200 certified neurosurgeons in 138 hospital departments and 75 private practices served 82 million people. Since its founding in 1949, the German Neurosurgical Society has promoted the idea of reconciliation and has focused on international collaboration in both science and education. This idea, shared by other European nations, eventually gave rise to the European Association of Neurosurgical Societies. At present, escalating costs in the health sector pose a problem to neurosurgical services and have led to reconsiderations about their structure and financing.

  10. Sexual transmission of Zika virus in Germany, April 2016.

    PubMed

    Frank, Christina; Cadar, Daniel; Schlaphof, Alexander; Neddersen, Neele; Günther, Stephan; Schmidt-Chanasit, Jonas; Tappe, Dennis

    2016-06-01

    Zika virus (ZIKV), an emerging mosquito-borne flavivirus, causes a mild dengue fever-like illness but has recently been associated with neurological disease and severe birth defects. The virus is currently causing a large epidemic in the Americas. Here, we report a male-to-female sexual transmission of ZIKV in Germany in April 2016, following travel to Puerto Rico of the male patient, demonstrated by subsequent seroconversions and molecular identification of identical virus sequences from both patients. PMID:27311329

  11. Solar technology in the Federal Republic of Germany

    NASA Technical Reports Server (NTRS)

    1979-01-01

    A series of papers dealing with the status of solar research and development in the Federal Republic of Germany are presented at a conference in Greece with the object of promoting international cooperation in solar energy utilization. The reports focus on solar collector designs, solar systems, heat pumps, solar homes, solar cooling and refrigeration, desalination and electric power generation. Numerous examples of systems produced by German manufacturers are illustrated and described, and performance data are presented.

  12. Sexual transmission of Zika virus in Germany, April 2016.

    PubMed

    Frank, Christina; Cadar, Daniel; Schlaphof, Alexander; Neddersen, Neele; Günther, Stephan; Schmidt-Chanasit, Jonas; Tappe, Dennis

    2016-06-01

    Zika virus (ZIKV), an emerging mosquito-borne flavivirus, causes a mild dengue fever-like illness but has recently been associated with neurological disease and severe birth defects. The virus is currently causing a large epidemic in the Americas. Here, we report a male-to-female sexual transmission of ZIKV in Germany in April 2016, following travel to Puerto Rico of the male patient, demonstrated by subsequent seroconversions and molecular identification of identical virus sequences from both patients.

  13. [Choosing wisely--against overuse in healthcare systems--activities in Germany and Austria in geriatric medicine].

    PubMed

    Gogol, Manfred; Siebenhofer, Andrea

    2016-04-01

    In 2012, the American Board of Internal Medicine (ABIM) Foundation initiated the Choosing Wisely campaign to promote discussion between physicians and patients (or proxies) on decision-making in medicine, and to reduce the use of procedures and therapies which are not necessary, or harmful to patients. The American Geriatrics Society (AGS), the American Medical Directors Association and the Society of Post-Acute and Long-Term Medicine (AMDA) participated in this initiative and both published 10 recommendations on procedures that should be discussed and avoided. Furthermore, some scientific societies have also published recommendations concerning elderly patients. As the campaign attracted considerable international attention, an International Roundtable was established in 2014. In Germany a similar initiative to address overuse and underuse was established by the German Society of Internal Medicine (DGIM) in 2015. The German Society of Geriatrics (DGG) was invited to address subjects affecting elderly patients that are of relevance to the German health care system. As a member of the Commission of the Association of the Scientific Medical Societies in Germany (AWMF), it also participated actively in the development of a methods paper on how to prepare recommendations. The German College of General Practitioners and Family Physicians (DEGAM) has developed a new guideline on this topic and in Austria preliminary activities are already underway. A clear, transparent, structured and evidence-based approach may help avoid some of the methodological weaknesses to be found in the development of the U.S. recommendations. Whereas the U.S. campaign only addresses overuse, the German campaign will also address underuse and misuse. PMID:26811241

  14. Germany wide seasonal flood risk analysis for agricultural crops

    NASA Astrophysics Data System (ADS)

    Klaus, Stefan; Kreibich, Heidi; Kuhlmann, Bernd; Merz, Bruno; Schröter, Kai

    2016-04-01

    In recent years, large-scale flood risk analysis and mapping has gained attention. Regional to national risk assessments are needed, for example, for national risk policy developments, for large-scale disaster management planning and in the (re-)insurance industry. Despite increasing requests for comprehensive risk assessments some sectors have not received much scientific attention, one of these is the agricultural sector. In contrast to other sectors, agricultural crop losses depend strongly on the season. Also flood probability shows seasonal variation. Thus, the temporal superposition of high flood susceptibility of crops and high flood probability plays an important role for agricultural flood risk. To investigate this interrelation and provide a large-scale overview of agricultural flood risk in Germany, an agricultural crop loss model is used for crop susceptibility analyses and Germany wide seasonal flood-frequency analyses are undertaken to derive seasonal flood patterns. As a result, a Germany wide map of agricultural flood risk is shown as well as the crop type most at risk in a specific region. The risk maps may provide guidance for federal state-wide coordinated designation of retention areas.

  15. [WINHO quality indicators for outpatient oncology care in Germany].

    PubMed

    Hermes-Moll, Kerstin; Klein, Gudrun; Buschmann-Maiworm, Regina E; Baumann, Walter; Otremba, Burkhard; Lebahn, Herbert; Steinmetz, H Tilmann; Geraedts, Max; Kleeberg, Ulrich R; Schmitz, Stephan

    2013-01-01

    The aim of the WINHO indicators project is to describe and enhance the quality of outpatient oncology care in Germany with indicators. This paper deals with the development of a set of evidence- and consensus-based meaningful indicators to assess the quality of outpatient oncology care in Germany. These indicators are intended to be applied in assessments of quality of patient care in oncology practices, in quality reports and in peer-to-peer benchmarking. A set of 272 already existing indicators was identified through internet and literature searches. After redundancy reduction and addition of newly developed indicators for areas of ambulatory oncology care that were not yet covered, a preliminary set of 67 indicators was established. The further development of the indicator set was based on a modified version of the two-step RAND/UCLA expert evaluation method, which has been internationally established for developing quality indicator sets. The indicators were modified after the first round of ratings. After completing and assessing the second round of ratings, a set of 46 homogeneously positively rated quality indicators is now available for outpatient oncology care in Germany.

  16. Alaria alata mesocercariae in raccoons (Procyon lotor) in Germany.

    PubMed

    Rentería-Solís, Zaida Melina; Hamedy, Ahmad; Michler, Frank-Uwe; Michler, Berit Annika; Lücker, Ernst; Stier, Norman; Wibbelt, Gudrun; Riehn, Katharina

    2013-10-01

    Alaria alata is a trematode of carnivores from Europe. The mesocercarial stage was recently identified in wild boar meat from Europe. Previous histopathologic studies showed the presence of unidentified parasitic cysts within the tongues of raccoons from northern Germany. For identification of the parasite species, tissue samples of 105 raccoons originating from a National Park in northern Germany and from Berlin metropolitan area were collected. Histological examination of cryotome sections of frozen as well as paraffin-embedded tongues were used to identify parasite cysts. These were located in the connective and adipose tissue and in close proximity to small arterioles, suggesting a hematogenous spread of the parasite. Often, cysts were surrounded with mild infiltration by inflammatory cells. Additionally, mesocercariae were isolated from defrosted tongue samples of 11 raccoons. Molecular-biology assays confirmed the parasite species as A. alata. Except for one positive raccoon from Berlin City, all other positive raccoons originated from the sylvan Müritz National park, indicating an abundance of intermediate hosts in this area. Our results show that raccoons can act as paratenic hosts for A. alata and extend the broad host range of this parasite to a species introduced into Germany.

  17. Post-diagnostic abortion in Germany: reproduction gone awry, again?

    PubMed

    Erikson, Susan L

    2003-05-01

    Routine use of prenatal diagnostic technologies (PDTs) such as ultrasound and amniocentesis result in the detection of a small percentage of fetal anomalies. For those women faced with the diagnosis of fetal disability, a decision must be made to continue or terminate the pregnancy. When the diagnosis is merely hypothetical, the discursive specter of post-diagnostic abortion is shaped by social and historical contexts in which interested discourses (regional, political, ethical, and religious) weigh in with varying degrees of authority and influence. However, when the diagnosis is actual, in this sample population of women, an estimated minimum of 90% opt to terminate their pregnancies. Data collected at two German hospitals-one in former East Germany, one in former West Germany-illuminate rates of PDT use and provide data with which to discuss the specter of post-diagnostic abortion in relation to mainstream medical discourses, Germany's divided history, abortion politics, feminism, disability activism, and religion. These data demonstrate how reproductive discourses are shaped by ideological and historical contingencies, even when women's ultimate reproductive decisions are not. PMID:12650734

  18. Evidence for an independent third Usutu virus introduction into Germany.

    PubMed

    Ziegler, Ute; Fast, Christine; Eiden, Martin; Bock, Sabine; Schulze, Christoph; Hoeper, Dirk; Ochs, Andreas; Schlieben, Patricia; Keller, Markus; Zielke, Dorothee E; Luehken, Renke; Cadar, Daniel; Walther, Doreen; Schmidt-Chanasit, Jonas; Groschup, Martin H

    2016-08-30

    Usutu virus (USUV) is an arbovirus within the genus flavivirus, which was first introduced to Southern Europe approximately twenty years ago causing epizootics among wild and captive birds. In Germany USUV was initially discovered in wild birds, mainly Common blackbirds (Turdus merula), in the Upper Rhine valley in southwest of the country in 2011 and has not spread much northwards since. Phylogenetic analyses revealed that the still ongoing USUV epidemic is caused by two different USUV strains, USUV-Germany belonging to the USUV Europe 3 lineage and USUV-Bonn belonging to the USUV Africa 3 lineage. The two strains were introduced independently. In August 2015 a new USUV strain, named USUV-Berlin, was isolated in Vero cells from two carcasses of juvenile Great grey owls (Strix nebulosa) kept in the Zoological Garden Berlin, which had suffered from a hyperacute fatal systemic infection. Both owls carried high USUV genome loads. Full-length USUV genomes sequences were determined and phylogenetic analysis demonstrated a close relationship with a Spanish mosquito-derived sequence from 2006. Immunohistochemical antigen detection in organ samples of the owls showed the typical USUV infection patterns. According to the phylogenetic analysis, USUV-Berlin belongs to the Africa 2 lineage, and can thus be distinguished from the other strains circulating in Germany. Repeated findings of different USUV strains suggest more frequent introductions into Central Europe and a higher mobility of this virus than assumed to date. PMID:27527765

  19. Anaerobic waste digestion in Germany--status and recent developments.

    PubMed

    Weiland, P

    2000-01-01

    Anaerobic treatment processes are especially suited for the utilization of wet organic wastes from agriculture and industry as well as for the organic part of source-separated household wastes. Anaerobic degradation is a very cost-effective method for treating biogenic wastes because the formed biogas can be used for heat and electricity production and the digester residues can be recycled to agriculture as a secondary fertilizer. Anaerobic technology will also be used for the common treatment of wastes together with renewable energy crops in order to reduce the CO2-emissions according the Kyoto protocol. Various process types are applied in Germany which differ in material, reaction conditions and in the form of the used reactor systems. The widespread introduction of anaerobic digestion in Germany has shown that biogenic organic wastes are a valuable source for energy and nutrients. Anaerobic waste treatment is done today in approx. 850 biogas plants on small farm scale as well as on large industrial scale with the best beneficial and economic outcome. Due to some new environmental protection acts which promote the recycling of wastes and their utilization for renewable energy formation it can be expected that several hundreds new biogas plants will be built per year in Germany. In order to use the synergetic effects of a combined fermentation of wastes and energy crops new process types must be developed in order to optimize the substrate combinations and the process conditions for maximum biodegradation.

  20. Post-diagnostic abortion in Germany: reproduction gone awry, again?

    PubMed

    Erikson, Susan L

    2003-05-01

    Routine use of prenatal diagnostic technologies (PDTs) such as ultrasound and amniocentesis result in the detection of a small percentage of fetal anomalies. For those women faced with the diagnosis of fetal disability, a decision must be made to continue or terminate the pregnancy. When the diagnosis is merely hypothetical, the discursive specter of post-diagnostic abortion is shaped by social and historical contexts in which interested discourses (regional, political, ethical, and religious) weigh in with varying degrees of authority and influence. However, when the diagnosis is actual, in this sample population of women, an estimated minimum of 90% opt to terminate their pregnancies. Data collected at two German hospitals-one in former East Germany, one in former West Germany-illuminate rates of PDT use and provide data with which to discuss the specter of post-diagnostic abortion in relation to mainstream medical discourses, Germany's divided history, abortion politics, feminism, disability activism, and religion. These data demonstrate how reproductive discourses are shaped by ideological and historical contingencies, even when women's ultimate reproductive decisions are not.

  1. Ag@Ag8W4O16 nanoroasted rice beads with photocatalytic, antibacterial and anticancer activity.

    PubMed

    Selvamani, Muthamizh; Krishnamoorthy, Giribabu; Ramadoss, Manigandan; Sivakumar, Praveen Kumar; Settu, Munusamy; Ranganathan, Suresh; Vengidusamy, Narayanan

    2016-03-01

    Increasing resistance of pathogens and cancer cell line towards antibiotics and anticancer agents has caused serious health problems in the past decades. Due to these problems in recent years, researchers have tried to combine nanotechnology with material science to have intrinsic antimicrobial and anticancer activity. The metals and metal oxides were investigated with respect to their antimicrobial and anticancer effects towards bacteria and cancer cell line. In the present work metal@metal tungstate (Ag@Ag8W4O16 nanoroasted rice beads) is investigated for antibacterial activity against Escherichia coli and Staphylococcus aureus using Mueller-Hinton broth and the anticancer activity against B16F10 cell line was studied. Silver decorated silver tungstate (Ag@Ag8W4O16) was synthesized by the microwave irradiation method using Cetyl Trimethyl Ammonium Bromide (CTAB). Ag@Ag8W4O16 was characterized by using various spectroscopic techniques. The phase and crystalline nature were analyzed by using XRD. The morphological analysis was carried out using Field Emission Scanning Electron Microscopy (FE-SEM), and High Resolution Transmission Electron Microscopy (HR-TEM). Further, Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectral analysis were carried out in order to ascertain the presence of functional groups in Ag@Ag8W4O16. The optical property was investigated using Diffuse Reflectance Ultraviolet-Visible Spectroscopy (DRS-UV-Vis) and the band gap was found to be 3.08eV. Surface area of the synthesized Ag@Ag8W4O16 wasanalyzed by BET analysis and Ag@Ag8W4O16 was utilized for the degradation of organic dyes methylene blue and rhodamine B. The morphology of the Ag@Ag8W4O16 resembles roasted rice beads with breath and length in nm range. The oxidation state of tungsten (W) and silver (Ag) was investigated using X-ray photoelectron spectroscopy (XPS).

  2. Temperature dependent effects during Ag deposition on Cu(110)

    SciTech Connect

    Taylor, T.N.; Muenchausen, R.E.; Hoffbauer, M.A.; Denier van der Gon, A.W.; van der Veen, J.F.; FOM-Instituut voor Atoom-en Molecuulfysica, Amsterdam )

    1989-01-01

    The composition, structure, and morphology of ultrathin films grown by Ag deposition on Cu(110) were monitored as a function of temperature using low-energy electron diffraction (LEED), Auger electron spectroscopy (AES), and medium energy ion scattering (MEIS). Aligned backscattering measurements with 150 keV He ions indicate that the Ag resides on top of the Cu and there is no significant surface compound formation. Measurements with LEED show that the Ag is initially confined to the substrate troughs. Further deposition forces the Ag out of the troughs and results in a split c(2 {times} 4) LEED pattern, which is characteristic of a distorted Ag(111) monolayer template. As verified by both AES and MEIS measurements, postmonolayer deposition of Ag on Cu(110) at 300K leads to a pronounced 3-dimensional clustering. Ion blocking analysis of the Ag clusters show that the crystallites have a (110)-like growth orientation, implying that the Ag monolayer template undergoes a rearrangement. These data are confirmed by low temperature LEED results in the absence of clusters, which indicate that Ag multilayers grow from a Ag--Cu interface where the Ag is captured in the troughs. Changes observed in the film structure and morphology are consistent with a film growth mechanism that is driven by overlayer strain response to the substrate corrugation. 16 refs., 4 figs.

  3. Ag(+)-mediated assembly of 5'-guanosine monophosphate.

    PubMed

    Loo, Kristine; Degtyareva, Natalya; Park, Jihae; Sengupta, Bidisha; Reddish, Michaeal; Rogers, Christopher C; Bryant, Andrea; Petty, Jeffrey T

    2010-04-01

    Polymorphic forms of nucleic acids provide platforms for new nanomaterials, and transition metal cations give access to alternative arrangements of nucleobases by coordinating with electron-rich functional groups. Interaction of Ag(+) with 5'-guanosine monophosphate (5'-GMP) is considered in this work. Ag(+) promotes nucleotide stacking and aggregation, as indicated by the increased viscosity of 5'-GMP solutions with Ag(+), magnification of the circular dichroism response of guanine by Ag(+), and exothermic reactions between Ag(+) and guanine derivatives. Isothermal titration calorimetry studies show that the reaction is favored starting at 10 microM 5'-GMP. Utilizing the exothermic heat change associated with reaction of Ag(+) with 5'-GMP, local structure within the aggregate was assessed. On the basis of the salt dependence of the reaction and comparison with the corresponding nucleoside, the dianionic phosphate of 5'-GMP is one binding site for Ag(+), although this electrostatic interaction is not a dominant contribution to the overall heat change. Another binding site is the N7 on the nucleobase, as determined via studies with 7-deazaguanosine. Besides this binding site, Ag(+) also associates with the O6, as earlier studies deduced from the shift in the carbonyl stretching frequency associated with adduct formation. With these two binding sites on the nucleobase, the empirical stoichiometry of approximately 1 Ag(+):nucleobase derived from the calorimetry studies indicates that Ag(+) coordinates two nucleobases. The proposed structural model is a Ag(+)-mediated guanine dimer within a base stacked aggregate. PMID:20205377

  4. Metallurgical characterization of experimental Ag-based soldering alloys

    PubMed Central

    Ntasi, Argyro; Al Jabbari, Youssef S.; Silikas, Nick; Al Taweel, Sara M.; Zinelis, Spiros

    2014-01-01

    Aim To characterize microstructure, hardness and thermal properties of experimental Ag-based soldering alloys for dental applications. Materials and methods Ag12Ga (AgGa) and Ag10Ga5Sn (AgGaSn) were fabricated by induction melting. Six samples were prepared for each alloy and microstructure, hardness and their melting range were determined by, scanning electron microscopy, energy dispersive X-ray (EDX) microanalysis, X-ray diffraction (XRD), Vickers hardness testing and differential scanning calorimetry (DSC). Results Both alloys demonstrated a gross dendritic microstructure while according to XRD results both materials consisted predominately of a Ag-rich face centered cubic phase The hardness of AgGa (61 ± 2) was statistically lower than that of AgGaSn (84 ± 2) while the alloys tested showed similar melting range of 627–762 °C for AgGa and 631–756 °C for AgGaSn. Conclusion The experimental alloys tested demonstrated similar microstructures and melting ranges. Ga and Sn might be used as alternative to Cu and Zn to modify the selected properties of Ag based soldering alloys. PMID:25382945

  5. RRR and thermal conductivity of Ag and Ag-0.2 wt.%Mg alloy in Ag/Bi-2212 wires

    NASA Astrophysics Data System (ADS)

    Li, P.; Ye, L.; Jiang, J.; Shen, T.

    2015-12-01

    Residual resistivity ratio (RRR) and thermal conductivity of metal matrix in metal/superconductor composite wires are important parameters for designing superconducting magnets. However, the resistivity of silver in reacted Ag/Bi-2212 wires has yet to be determined over temperature range from 4.2 K to 80 K because Bi-2212 filaments have a critical transition temperature Tc of ∼ 80 K, and because it is unknown whether the RRR of Ag/Bi-2212 degrades with Cu diffusing from Bi-2212 filaments into silver sheathes at elevated temperatures and to what degree it varies with heat treatment. We measured the resistivity of stand-alone Ag and AgMg (Ag-0.2 wt.% Mg) wires as well as the resistivity of Ag and Ag-0.2 wt.% Mg in Ag/Bi- 2212 round wires reacted in 1 bar oxygen at 890 °C for 1, 8, 24 and 48 hours and quickly cooled to room temperature. The heat treatment was designed to reduce the critical current Ic of Bi- 2212 wires to nearly zero while allowing Cu loss to fully manifest itself. We determined that pure silver exhibits a RRR of ∼ 220 while the oxide-dispersion strengthened Ag-Mg exhibits a RRR of ∼ 5 in stand-alone samples. A surprising result is that the RRR of silver in the composite round wires doesn't degrade with extended time at 890 °C for up to 48 hours. This surprising result may be explained by our observation that the Cu that diffuses into silver tends to form Cu2O precipitates in oxidizing atmosphere, instead of forming Ag-Cu solution alloy. We also measured the thermal conductivity and the magneto-resistivity of pure Ag and Ag-0.2 wt. % Mg from 4.2 K to 300 K in magnetic fields up to 14.8 T and summarized them using a Kohler plot.

  6. Time-dependency of the 137Cs contamination of wild boar from a region in Southern Germany in the years 1998 to 2008.

    PubMed

    Semizhon, Tatiana; Putyrskaya, Victoria; Zibold, Gregor; Klemt, Eckehard

    2009-11-01

    Following the Chernobyl accident, (137)Cs contamination levels of wild boar in some districts of Southern Germany are still exceeding thousands of Bq kg(-1). While the long term (137)Cs concentration in forest plants, mushrooms, and roe deer meat has decreased significantly, for wild boar it has remained constant during the last decade. Between 1998 and 2008, we analysed the muscle meat of 656 wild boars shot in the district ("Landkreis") Ravensburg. The (137)Cs activity concentration showed considerable variability from less than 5 up to 8266 Bq kg(-1) and it followed a seasonal pattern, which is attributed to changes in dietary habits, fodder availability, meteorological conditions and specific behaviour of (137)Cs in wild boar organism. T(ag) values for wild boars from the district Ravensburg varied from 0.008 to 0.062 m(2)kg(-1) during 2000-2008.

  7. Fluoride-induced reduction of Ag(I) cation leading to formation of silver mirrors and luminescent Ag-nanoparticles.

    PubMed

    Maity, Krishnendu; Panda, Dillip K; Lochner, Eric; Saha, Sourav

    2015-03-01

    In aprotic solvents, Lewis basic F(-) anion reduces Lewis acidic Ag(I) cation to Ag(0), forming metallic silver mirrors on the inner surfaces of reaction vessels and luminescent Ag-nanoparticles (AgNPs) in supernatant solutions, which emit blue light upon UV irradiation. The F(-)-induced formation of silver mirrors and AgNPs was confirmed through X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), fluorescence spectroscopy, and mass spectrometry, whereas the Ag(I)-induced oxidation of F(-) to Ḟ radical, followed by its conversion to HF2(-) via H-abstraction and H-bonding, was evident from (19)F NMR spectroscopy. This redox reaction is deactivated in water, as the reducing power of hydrated F(-) diminishes drastically. Less Lewis basic Cl(-), Br(-), and I(-) ions do not reduce Ag(I) to Ag(0), instead they can only form Ag(I) halide precipitates irrespective of protic or aprotic solvents. The Ag-coated surfaces, luminescent AgNPs, and Ḟ radicals produced by this unprecedented redox reaction could be exploited as electrodes, light-emitting materials, and radical initiators, respectively.

  8. New frontiers in water purification: highly stable amphopolycarboxyglycinate-stabilized Ag-AgCl nanocomposite and its newly discovered potential

    NASA Astrophysics Data System (ADS)

    Krutyakov, Yurii A.; Zherebin, Pavel M.; Kudrinskiy, Alexey A.; Zubavichus, Yan V.; Presniakov, Mikhail Yu; Yapryntsev, Alexey D.; Karabtseva, Anastasia V.; Mikhaylov, Dmitry M.; Lisichkin, Georgii V.

    2016-09-01

    A simple synthetic procedure for high-stable dispersions of porous composite Ag/AgCl nanoparticles stabilized with amphoteric surfactant sodium tallow amphopolycarboxyglycinate has been proposed for the first time. The prepared samples were characterized by UV-vis spectroscopy, x-ray powder diffraction (XRD), x-ray photoelectron spectroscopy, small area electron diffraction (SAED), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and electron probe micro-analysis. In addition, measurements (carried out at the Kurchatov synchrotron radiation source stations) of the Ag K-edge extended x-ray absorption fine structure (EXAFS) and x-ray absorption near edge structure (XANES) spectra and XRD of the prepared nanoparticles have been performed. The obtained results suggest that small-sized Ag clusters are homogeneously distributed in the mass of the AgCl nanoparticle (~80 nm) formed during the synthesis. The Ag/AgCl dispersion demonstrates photocatalytic activity (with respect to methyl orange) and high bactericidal activity against E. coli. This activity is superior to the activity of both Ag and AgCl nanoparticles stabilized by the same surfactant. Thus, porous composite Ag/AgCl nanoparticles can be used as a multifunctional agent that is able to remove both pollutants and bacterium from water.

  9. High-Quality AgGaTe2 Layers on Si Substrates with Ag2Te Buffer Layers

    NASA Astrophysics Data System (ADS)

    Uruno, Aya; Kobayashi, Masakazu

    2016-09-01

    AgGaTe2 layers were successfully grown on Si substrates by the close-spaced sublimation method. The Si substrates were confirmed to be etched during AgGaTe2 layer growth when the layer was grown directly on the substrate. To eliminate melt-back etching, a buffer layer of Ag2Te was introduced. It was found that the Ag2Te buffer layer changed into the AgGaTe2 layer during the growth process, and a uniform AgGaTe2 layer with an abrupt interface was formed. Both the diffusion of Ga into Ag2Te and the growth of AgGaTe2 occurred simultaneously. It was confirmed that uniform AgGaTe2 layers could be formed without any traces of the Ag2Te layer or melt-back etching by tuning the growth parameters. A solar cell was also fabricated using the p-AgGaTe2/n-Si heterojunction. This solar cell showed conversion efficiency of approximately 3%.

  10. Superionic behavior in the xAgI-(1-x)CsAg2I3 polycrystalline system

    NASA Astrophysics Data System (ADS)

    Rodríguez, L. A.; Zapata, J.; Vargas, R. A.; Peña Lara, D.; Diosa, J. E.

    2016-06-01

    A superionic phase behavior (with DC ionic conductivities higher than 0.01 S/cm) has been observed in xAgI-(1-x)CsAg2I3 (x≈0.67) polycrystalline system grown by slow evaporation using AgI and CsI powders (molar ratio Cs/Ag=0.25) as starting salts and an aqueous solution of HI as solvent. The transition from the normal-to- the superionic state is first-order with a hysteretic behavior in temperature centered at about 116 °C as reflected by thermal (DSC) and electrical conductivity measurements. This mixture is composed of CsAg2I3 and AgI crystalline phases and an additional amorphous AgI phase that explains the glassy-type behavior observed in the superionic phase transition.

  11. Synthesis, characterization and optical properties of low nuclearity liganded silver clusters: Ag31(SG)19 and Ag15(SG)11.

    PubMed

    Bertorelle, Franck; Hamouda, Ramzi; Rayane, Driss; Broyer, Michel; Antoine, Rodolphe; Dugourd, Philippe; Gell, Lars; Kulesza, Alexander; Mitrić, Roland; Bonačić-Koutecký, Vlasta

    2013-06-21

    We report a simple synthesis of silver:glutathione (Ag:SG) clusters using a cyclic reduction under oxidative conditions. Two syntheses are described which lead to solutions containing well-defined Ag31(SG)19 and Ag15(SG)11 clusters that have been characterized by mass spectrometry. The optical properties of silver:glutathione (Ag:SG) cluster solutions have been investigated experimentally. In particular, the solution containing Ag15(SG)11 clusters shows a bright and photostable emission. For Ag31(SG)19 and Ag15(SG)11 clusters, the comparison of experimental findings with DFT and TDDFT calculations allowed us to reveal the structural and electronic properties of such low nuclearity liganded silver clusters.

  12. Mechanisms of Toxicity of Ag Nanoparticles in Comparison to Bulk and Ionic Ag on Mussel Hemocytes and Gill Cells

    PubMed Central

    Katsumiti, Alberto; Gilliland, Douglas; Arostegui, Inmaculada; Cajaraville, Miren P.

    2015-01-01

    Silver nanoparticles (Ag NPs) are increasingly used in many products and are expected to end up in the aquatic environment. Mussels have been proposed as marine model species to evaluate NP toxicity in vitro. The objective of this work was to assess the mechanisms of toxicity of Ag NPs on mussel hemocytes and gill cells, in comparison to ionic and bulk Ag. Firstly, cytotoxicity of commercial and maltose stabilized Ag NPs was screened in parallel with the ionic and bulk forms at a wide range of concentrations in isolated mussel cells using cell viability assays. Toxicity of maltose alone was also tested. LC50 values were calculated and the most toxic Ag NPs tested were selected for a second step where sublethal concentrations of each Ag form were tested using a wide array of mechanistic tests in both cell types. Maltose-stabilized Ag NPs showed size-dependent cytotoxicity, smaller (20 nm) NPs being more toxic than larger (40 and 100 nm) NPs. Maltose alone provoked minor effects on cell viability. Ionic Ag was the most cytotoxic Ag form tested whereas bulk Ag showed similar cytotoxicity to the commercial Ag NPs. Main mechanisms of action of Ag NPs involved oxidative stress and genotoxicity in the two cell types, activation of lysosomal AcP activity, disruption of actin cytoskeleton and stimulation of phagocytosis in hemocytes and increase of MXR transport activity and inhibition of Na-K-ATPase in gill cells. Similar effects were observed after exposure to ionic and bulk Ag in the two cell types, although generally effects were more marked for the ionic form. In conclusion, results suggest that most observed responses were due at least in part to dissolved Ag. PMID:26061169

  13. Stability of magic planar Ag clusters

    NASA Astrophysics Data System (ADS)

    Chiu, Y. P.; Ou, Y. S.; Chang, Y. R.; Wei, C. M.; Chang, C. S.; Tsong, Tien T.

    2007-03-01

    The spontaneous assembly of atoms and molecules in a system has attracted many research interests and created numerous potential applications. Utilizing the periodic pattern found on the Pb quantum islands, which are grown on the Si(111) surface, we have recently discovered that self-organized Ag planar clusters formed on these templates exhibit enhanced stability at some particular sizes [1]. Existence of the magic atom numbers in these clusters is mainly attributed to the electronic confinement effect. Here, we further explore the strength of these magic clusters subject to the temperature rise and oxygen exposure. Detailed calculations based on ab initio density functional theory have also been performed. The results help establish the relation between the physical and chemical stability of a magic Ag cluster and its size and shape. Ref:[1] Ya-Ping Chiu, Li-Wei Huang, Ching-Ming Wei, Chia-Seng Chang, and Tien-Tzou Tsong, Phys. Rev. Lett. 97, 165504 (2006).

  14. The instability of silicene on Ag(111)

    SciTech Connect

    Acun, A.; Poelsema, B.; Zandvliet, H. J. W.; Gastel, R. van

    2013-12-23

    We have used low energy electron microscopy to directly visualize the formation and stability of silicene layers on a Ag(111) substrate. Theoretical calculations call into question the stability of this graphene-like analog of silicon. We find that silicene layers are intrinsically unstable against the formation of an “sp{sup 3}-like” hybridized, bulk-like silicon structure. The irreversible formation of this bulk-like structure is triggered by thermal Si adatoms that are created by the silicene layer itself. To add injury to insult, this same instability prevents the formation of a fully closed silicene layer or a thicker bilayer, rendering the future large-scale fabrication of silicene layers on Ag substrates unlikely.

  15. Lake County Geo-Ag heat center

    SciTech Connect

    Not Available

    1987-07-01

    Lake County is proceeding with plans to develop a unique agricultural park called the Geo-Ag Heat Center Project. The project will combine vocational training, geothermal heat-transfer research, and commercial resources for greenhouse heating, crop drying, and other agricultural operations. The first phase of the project involved drilling wells to confirm the availability of an adequate geothermal resource. The first well, AG Park 1, drilled in January, 1986 to a depth of 1614 feet, proved noncommercial; it will be used as an injection well. Next, a geophysical program of seismic surveys was undertaken to pinpoint the more productive fracture zones. Wells AG Park 2 and 3 were drilled in these zones. Both wells were drilled in December 1986, to depths of 592 and 488 feet, respectively. In 3-day tests of continuous production, AG Park 2 and 3 yielded flowing wellhead temperatures of 143/sup 0/F and 153/sup 0/F, respectively, at flow rates exceeding 150 gpm, with minor drawdowns. The next phase of the project entails construction of a 7000 square-foot greenhouse by the end of 1987. It will be operated by the Mendocino-Lake Community College District as an educational and demonstration facility. Geothermal-fluid and irrigation water-distribution and injection-pipeline systems will also be installed in preparation for future commercial leasing on the 3-acre site. The demonstration greenhouse will allow evaluation of the effectiveness of various heat-transfer systems. This would assist commercial operators in designing the most economical system for their needs.

  16. Formation and properties of hyaluronan/nano Ag and hyaluronan-lecithin/nano Ag films.

    PubMed

    Khachatryan, Gohar; Khachatryan, Karen; Grzyb, Jacek; Fiedorowicz, Maciej

    2016-10-20

    A facile and environmentally friendly method of the preparation of silver nanoparticles embedded in hyaluronan (Hyal/Ag) and hyaluronan-lecithin (Hyal-L/Ag) matrix was developed. Thin, elastic foils were prepared from gels by an in situ synthesis of Ag in an aqueous solution of sodium hyaluronate (Hyal), using aq. d-(+)-xylose solution as a reducing agent. The gels were applied to a clean, smooth, defatted Teflon surface and left for drying in the air. The dry foils were stored in a closed container. UV-vis spectroscopy, transmission electron microscopy (TEM) and Fourier transform infrared (FTIR) spectra confirmed formation of about 10nm ball-shaped Ag nanoparticles situated within the polysaccharide template. Thermal properties of the composites were characterized involving differential scanning calorimetry (DSC) and thermogravimetric (TGA) analyses, whereas molecular weights of polysaccharide chains of the matrix were estimated with the size exclusion chromatography coupled with multiangle laser light scattering and refractometric detectors (HPSEC-MALLS-RI). An increase in the molecular weight of the hyaluronate after generation of Ag nanoparticles was observed. The foils showed specific properties. The study confirmed that silver nanoparticles can be successfully prepared with environmentally friendly method, using hyaluronan as a stabilizing template. Hyaluronan and hyaluronan-lecithin matrices provide nanocrystals uniform in size and shape. The composites demonstrated a bacteriostatic activity. PMID:27474588

  17. Electrochemical detection of aqueous Ag+ based on Ag+-assisted ligation reaction

    PubMed Central

    Miao, Peng; Han, Kun; Wang, Bidou; Luo, Gangyin; Wang, Peng; Chen, Mingli; Tang, Yuguo

    2015-01-01

    In this work, a novel strategy to fabricate a highly sensitive and selective biosensor for the detection of Ag+ is proposed. Two DNA probes are designed and modified on a gold electrode surface by gold-sulfur chemistry and hybridization. In the presence of Ag+, cytosine-Ag+-cytosine composite forms and facilitates the ligation event on the electrode surface, which can block the release of electrochemical signals labeled on one of the two DNA probes during denaturation process. Ag+ can be sensitively detected with the detection limit of 0.1 nM, which is much lower than the toxicity level defined by U.S. Environmental Protection Agency. This biosensor can easily distinguish Ag+ from other interfering ions and the performances in real water samples are also satisfactory. Moreover, the two DNA probes are designed to contain the recognition sequences of a nicking endonuclease, and the ligated DNA can thus be cleaved at the original site. Therefore, the electrode can be regenerated, which allows the biosensor to be reused for additional tests. PMID:25779347

  18. Isomorphism and solid solutions among Ag- and Au-selenides

    NASA Astrophysics Data System (ADS)

    Palyanova, Galina A.; Seryotkin, Yurii V.; Kokh, Konstantin A.; Bakakin, Vladimir V.

    2016-09-01

    Au-Ag selenides were synthesized by heating stoichiometric mixtures of elementary substances of initial compositions Ag2-xAuxSe with a step of x=0.25 (0≤x≤2) to 1050 °C and annealing at 500 °C. Scanning electron microscopy, optical microscopy, electron microprobe analysis and X-ray powder diffraction methods have been applied to study synthesized samples. Results of studies of synthesized products revealed the existence of three solid solutions with limited isomorphism Ag↔Au: naumannite Ag2Se - Ag1.94Au0.06Se, fischesserite Ag3AuSe2 - Ag3.2Au0.8Se2 and gold selenide AuSe - Au0.94Ag0.06Se. Solid solutions and AgAuSe phases were added to the phase diagram of Ag-Au-Se system. Crystal-chemical interpretation of Ag-Au isomorphism in selenides was made on the basis of structural features of fischesserite, naumannite, and AuSe.

  19. Glass formation and high conductivity in the ternary system AgI + Ag/sub 3/AsO/sub 4/ + AgPO/sub 3/: host to glassy AgI

    SciTech Connect

    Martin, S.W.; Schiraldi, A.

    1985-05-09

    Wide regions of glass formation have been found in the ternary system xAgI + yAg/sub 3/AsO/sub 4/ + (1 - x - y)AgPO/sub 3/. Glasses containing up to 75 mol % AgI can be formed in sections greater than 2 cm thick without signs of devitrification. Glass transition temperatures as high as 175/sup 0/C for glasses containing approx. 10 mol% AgI fall to approx. 45/sup 0/C at the highest AgI content. An equivalent ratio of AgI:N is defined and it is found that, for all glass-forming compositions, the electrical data as expressed in the Arrhenius form, sigma = A exp(-E/sub act/RT), log (sigma/omega cm)/sup -1/), log (A/omega cm)/sup -1/), E/sub act//(kcal mol/sup -1/), and additionally T/sub g/K, can be described as linear functions of N. These data are used to give support to the view of these glasses as being hosts to a liquidlike AgI giving rise to the high conductivity they exhibit, as high as 0.0143 (omega cm)/sup -1/ at room temperature for glasses containing the maximum AgI. Finally, from these linear relationships, functions for the mobility ..mu.. and number of the mobile Ag/sup +/ cations n are developed. 29 references, 8 figures, 2 tables.

  20. Hydrogen in Ag-doped ZnO: theoretical calculations.

    PubMed

    He, H Y; Hu, J; Pan, B C

    2009-05-28

    Based on density functional theory calculations, we systematically investigate the behaviors of a H atom in Ag-doped ZnO involving the preference sites, diffusion behaviors, the electronic structures, and vibrational properties. We find that a H atom can migrate to the doped Ag to form a Ag-H complex by overcoming energy barriers of 0.3-1.0 eV. The lowest-energy site for H location is the bond center of a Ag-O in the basal plane. Moreover, H can migrate between this site and its equivalent sites with energy cost of less than 0.5 eV. In contrast, dissociation of such a Ag-H complex needs energy of about 1.1-1.3 eV. This implies that the Ag-H complexes can commonly exist in the Ag-doped ZnO, which have a negative effect on the desirable p-type carrier concentrations of Ag-doped ZnO. In addition, based on the frozen phonon calculation, the vibrational properties of ZnO with a Ag-H complex are predicted. Some new vibrational modes associated with the Ag-H complex present in the vibrational spectrum of the system.

  1. Pressureless Bonding Using Sputtered Ag Thin Films

    NASA Astrophysics Data System (ADS)

    Oh, Chulmin; Nagao, Shijo; Suganuma, Katsuaki

    2014-12-01

    To improve the performance and reliability of power electronic devices, particularly those built around next-generation wide-bandgap semiconductors such as SiC and GaN, the bonding method used for packaging must change from soldering to solderless technology. Because traditional solders are problematic in the harsh operating conditions expected for emerging high-temperature power devices, we propose a new bonding method in this paper, namely a pressureless, low-temperature bonding process in air, using abnormal grain growth on sputtered Ag thin films to realize extremely high temperature resistance. To investigate the mechanisms of this bonding process, we characterized the microstructural changes in the Ag films over various bonding temperatures and times. We measured the bonding properties of the specimens by a die-shear strength test, as well as by x-ray diffraction measurements of the residual stress in the Ag films to show how the microstructural developments were essential to the bonding technology. Sound bonds with high die strength can be achieved only with abnormal grain growth at optimum bonding temperature and time. Pressureless bonding allows for production of reliable high-temperature power devices for a wide variety of industrial, energy, and environmental applications.

  2. Commissioning the polarized beam in the AGS

    SciTech Connect

    Ratner, L.G.; Brown, H.; Chiang, I.H.; Courant, E.; Gardner, C.; Lazarus, D.; Lee, Y.Y.; Makdisi, Y.; Sidhu, S.; Skelly, J.

    1985-01-01

    After the successful operation of a high energy polarized proton beam at the Argonne Laboratory Zero Gradient Synchrotron (ZGS) was terminated, plans were made to commission such a beam at the Brookhaven National Laboratory Alternating Gradient Synchrotron (AGS). On February 23, 1984, 2 ..mu..A of polarized H/sup -/ was accelerated through the Linac to 200 MeV with a polarization of about 65%. 1 ..mu..A was injected into the AGS and acceleration attempts began. Several relatively short runs were then made during the next three months. Dedicated commissioning began in early June, and on June 26 the AGS polarized beam reached 13.8 GeV/c to exceed the previous ZGS peak momentum of 12.75 GeV/c. Commissioning continued to the point where 10/sup 10/ polarized protons were accelerated to 16.5 GeV/c with 40% polarization. Then, two experiments had a short polarized proton run. We plan to continue commissioning efforts in the fall of this year to reach higher energy, higher intensity, and higher polarization levels. We present a brief description of the facility and of the methods used for preserving the polarization of the accelerating beam.

  3. Autologous blood donor screening indicated a lower prevalence of viral hepatitis in East vs West Germany: epidemiological benefit from established health resources.

    PubMed

    Wiegand, J; Luz, B; Mengelkamp, A-K; Moog, R; Koscielny, J; Halm-Heinrich, I; Susemihl, C; Bentzien, F; Diekmann, J; Wernet, D; Karger, R; Angert, K; Schmitt-Thomssen, A; Kiefel, V; Lutter, K; Hesse, R; Kätzel, R; Opitz, A; Luhm, J; Barz, D; Leib, U; Matthes, G; Tillmann, H L

    2009-10-01

    Prevalence data concerning viral hepatitis and human immunodeficiency virus (HIV) in the general population are usually scarce. We aimed for a large cohort representative of the general population that required little funding. Autologous blood donors are relatively representative of the general population, and are tested for viral hepatitis and HIV in many countries. However, frequently these data are not captured for epidemiologic purposes. We analysed data from well over 35,000 autologous blood donors as recorded in 21 different transfusion centres for anti-hepatitis C virus (HCV), HBsAg and anti-HIV, as well as TPHA if available. We found a lower prevalence of hepatitis B virus and HCV in East vs West Germany, 0.2%vs 0.32% and 0.16%vs 0.32% respectively, which confirms earlier data in smaller cohorts, thus supporting the value of our approach. HIV was too rare to disclose significant differences, 0.01%vs 0.02%. TPHA was higher in East (0.34%) vs West Germany (0.29%) without significant differences. HCV was more frequent in women vs men. Transfusion institutes managing autologous blood donations should be used as a resource for epidemiological data relating to viral hepatitis and HIV, if such testing is performed routinely. This approach generates data relating to the general population with special emphasis on undiagnosed cases.

  4. Highly efficient and stable Ag-AgBr/TiO2 composites for destruction of Escherichia coli under visible light irradiation.

    PubMed

    Wang, Xiaoping; Lim, Teik-Thye

    2013-08-01

    A series of Ag-AgBr/TiO2 composites were prepared by a sol-gel method followed by photoreduction. Effect of Ag-AgBr content on the physicochemical properties and antibacterial activities of the Ag-AgBr/TiO2 composites was investigated. These composites showed intrinsic antibacterial activities against Escherichia coli (E. coli) in the dark attributed to the Ag nanoparticles dispersed in the composites. Under visible light irradiation, inactivation of E. coli over these Ag-AgBr/TiO2 composites was attributed to both their photocatalytic disinfection activities and intrinsic antibacterial properties. The Ag-AgBr/TiO2 with an optimum Ti/Ag atomic ratio of 10 exhibited superior visible-light photocatalytic activities for ibuprofen degradation and mineralization as compared to the other Ag-AgBr/TiO2 composites and also Ag-AgBr/P25, Ag/TiO2 and TiO2. It is probably because of the coexistence of two visible-light active components (AgBr and Ag nanoparticles) and the most effective separation of photogenerated electrons and holes in this photocatalyst. Correspondingly, the photocatalyst achieved a much higher efficiency of E. coli destruction than Ag-AgBr/P25 and TiO2. E. coli was almost completely inactivated (7-log reduction) within 60 min by the photocatalyst with a rather low dosage of 0.05 g L(-1) under white LED irradiation. Furthermore, the Ag-AgBr/TiO2 showed high stability for photocatalytic destruction of E. coli and the dark repair and photoreactivation did not occur after the photocatalytic process. Finally, the action spectrum of this photocatalyst for E. coli inactivation and the influence of several inorganic ions present in surface water were also investigated.

  5. HBcrAg Identifies Patients Failing to Achieve HBeAg Seroconversion Treated with Pegylated Interferon Alfa-2b

    PubMed Central

    Ma, Hui; Yang, Rui-Feng; Li, Xiao-He; Jin, Qian; Wei, Lai

    2016-01-01

    Background: We aimed to evaluate the usefulness of serum hepatitis B virus core-related antigens (HBcrAg) for predicting hepatitis B e antigen (HBeAg) seroconversion in HBeAg-positive chronic hepatitis B patients treated with conventional interferon (IFN) alfa-2b or pegylated IFN. Methods: Fifty-eight patients were enrolled: 29 for the training group and 29 for the validating group. HBcrAg was measured at baseline, week 12, end of the treatment, and 12- and 24-week follow-ups. Sixteen patients in the training group were enrolled in the long-term follow-up (LTFU), during which time the dynamics of the HBcrAg was monitored. Results: The serum HBcrAg level gradually declined during treatment among the HBeAg seroconversion patients of the training group (from baseline, week 12, end of the treatment, 12-week follow-up to 24-week follow-up were 110,245 kU/ml, 3760 kU/ml, 7410 kU/ml, 715 kU/ml, 200 kU/ml, respectively). HBcrAg <19,565 kU/ml at week 24, HBcrAg <34,225 kU/ml at 12-week follow-up, and HBcrAg decrease ≥0.565 log10 kU/ml from the baseline to the end of treatment (EOT) had negative predictive values (NPVs) of 100% for HBeAg seroconversion at the end of follow-up, whereas the positive predictive values (PPVs) were 30.77%, 26.67%, and 25.00%, respectively. The patients with HBeAg seroconversion at the end of 24-week follow-up remained in seroconversion during the LTFU, during which time their serum HBcrAg levels steadily declined or even became undetectable, ranging from 0 to 2.1 kU/ml. Conclusions: Effective antiviral treatment can decrease HBcrAg levels in the serum. The NPVs of HBcrAg for predicting HBeAg seroconversion at 24-week follow-up was 100%, but the PPVs were not satisfactory (all <31%). The serum HBcrAg levels of the patients with HBeAg seroconversion at the end of the 24-week follow-up steadily declined or even became undetectable during the LTFU. PMID:27625094

  6. Effects of Ag nanomaterials (NM300K) and Ag salt (AgNO3) can be discriminated in a full life cycle long term test with Enchytraeus crypticus.

    PubMed

    Bicho, Rita C; Ribeiro, Tânia; Rodrigues, Natália P; Scott-Fordsmand, Janeck J; Amorim, Mónica J B

    2016-11-15

    Information on effects of silver nanoparticles on soil invertebrates, especially using long-term exposures, is scarce. In this study we investigated the effects of the reference Ag (NM300K) (compared to AgNO3) using the full life cycle test (FLCt) of the soil invertebrate Enchytraeus crypticus. Results showed that effects were higher compared to the standard reproduction test, which is shorter and does not cover the FLC. Both Ag forms caused a reduction on hatching success, juvenile and adult survival and reproduction with similar ECx. Differences between AgNO3 and Ag NM300K could be discriminated using the FLCt: AgNO3 decreased hatching success was shown to be a delay in the process, whereas Ag NM300K caused irreversible effects during the same time frame. These effects may have occurred during the embryo development, hatching (inhibition) or survival of hatched juveniles. Ag NM300K caused non-monotonic concentration-response effect as observed by the high effect of the lowest concentration (20mgkg-1). It is known that dispersion is higher at lower concentrations - this could explain the increased effect at low concentration. Non monotonic responses are well described in the literature, where effects of high cannot predict for low concentrations, hence special attention should be given for NMs low concentration effects. PMID:27474850

  7. A nanosized {Ag@Ag12} "molecular windmill" templated by polyoxometalates anions.

    PubMed

    Wang, Lei; Yang, Weiting; Zhu, Wei; Guan, Xingang; Xie, Zhigang; Sun, Zhong-Ming

    2014-11-01

    Reaction of multidentate 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (L) ligand with Ag(I) ions in the existence of H3PW12O40 as anionic template under hydrothermal conditions results in tridecanuclear silver cluster-polyoxometalates hybrid: {Ag13L12}{PW12O40}4·30H2O (1). X-ray single crystal diffraction analysis indicates that the main structural feature of 1 is a nanosized molecular windmill-shaped polynuclear Ag cluster with intriguing {M@M12}-type cuboctahedral topology. The as-synthesized compound exhibits effective photocatalytic activity in the photodegradation of Rhodamine-B (RhB) and antibacterial activity against Escherichia coli, respectively.

  8. Heterojunction double dumb-bell Ag2Te-Te-Ag2Te nanowires

    NASA Astrophysics Data System (ADS)

    Som, Anirban; Pradeep, T.

    2012-07-01

    Growth of isolated axial heterojunction nanowires by a solution phase growth process is reported. The dumb-bell shaped nanowires contain two silver telluride sections at the extremes joined by a tellurium section. Reaction of silver nitrate with tellurium NWs in aqueous solution at a molar ratio of 1 : 1 leads to the formation of amorphous partially silver reacted Te NWs. Low temperature (75 °C) solution phase annealing of these silver deficient NWs results in phase segregation producing crystalline Ag2Te and Te phases with clear phase boundaries along the wire axis. Structural characterization of these dumb-bell shaped NWs was performed with different microscopic and spectroscopic tools. Solution phase silver concentration over the course of annealing indicated leaching of silver into the solution during the formation of biphasic NWs. Similar Ag : Te ratios were observed in both partially silver reacted Te NWs and phase segregated Ag2Te-Te-Ag2Te NWs and this was attributed to redeposition of leached silver on the amorphous NW tips which eventually resulted in complete phase segregation. Successful integration of different chemical components in single NWs is expected to open up new application possibilities as physical and chemical properties of the heterostructure can be exploited.Growth of isolated axial heterojunction nanowires by a solution phase growth process is reported. The dumb-bell shaped nanowires contain two silver telluride sections at the extremes joined by a tellurium section. Reaction of silver nitrate with tellurium NWs in aqueous solution at a molar ratio of 1 : 1 leads to the formation of amorphous partially silver reacted Te NWs. Low temperature (75 °C) solution phase annealing of these silver deficient NWs results in phase segregation producing crystalline Ag2Te and Te phases with clear phase boundaries along the wire axis. Structural characterization of these dumb-bell shaped NWs was performed with different microscopic and spectroscopic

  9. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition

    SciTech Connect

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.

    2010-11-01

    The flux of atomic oxygen generated in a electron cyclotron resonance (ECR) microwave plasma source was quantified by two different methods. The commonly applied approach of monitoring the frequency change of a silver-coated quartz crystal microbalance (QCM) deposition rate monitor as the silver is oxidized was found to underestimate the atomic oxygen flux by an order of magnitude compared to a more direct deposition approach. In the mixed-phase Ag/Ag2O deposition method, silver films were deposited in the presence of the plasma such that the films were partially oxidized to Ag2O; x-ray photoelectron spectroscopy (XPS) was utilized for quantification of the oxidized fraction. The inaccuracy of the QCM oxidation method was tentatively attributed to efficient catalytic recombination of O atoms on the silver surface.

  10. Conversion of Ag nanowires to AgCI nanowires decorated with Au nanoparticles and their photocatalytic activity.

    SciTech Connect

    Sun, Y.; Center for Nanoscale Materials

    2010-02-11

    A two-step approach has been developed to synthesize AgCl nanowires decorated with Au nanoparticles by using Ag nanowires as chemical templates. In the first step, the Ag nanowires are oxidized with FeCl{sub 3} followed by a simultaneous precipitation reaction between Ag{sup +} and Cl{sup -} ions at room temperature, resulting in conversion of the Ag nanowires to AgCl nanowires as well as reduction of Fe{sup 3+} to Fe{sup 2+} ions. In the second step, the Fe{sup 2+} ions generated in the first step reduce Au precursors (e.g., NaAuCl{sub 4}) to deposit Au nanoparticles on the surfaces of the AgCl nanowires, resulting in the formation of AgCl:Au composite nanowires. Because of strong surface plasmon resonance and chemical inertness of Au nanoparticles, the as-synthesized AgCl:Au nanowires exhibit enhanced absorption coefficient in the visible region and enhanced chemical stability to prevent them from degradation and aggregation. These unique properties enable the AgCl:Au nanowires to be used as a class of promising plasmonic photocatalysts driven by visible light. Preliminary results demonstrate these composite nanowires can efficiently decompose organics, such as methylene blue molecules, under illumination of white light.

  11. Dissociation energies of Ag-RG (RG = Ar, Kr, Xe) and AgO molecules from velocity map imaging studies.

    PubMed

    Cooper, Graham A; Kartouzian, Aras; Gentleman, Alexander S; Iskra, Andreas; van Wijk, Robert; Mackenzie, Stuart R

    2015-09-28

    The near ultraviolet photodissociation dynamics of silver atom-rare gas dimers have been studied by velocity map imaging. Ag-RG (RG = Ar, Kr, Xe) species generated by laser ablation are excited in the region of the C ((2)Σ(+))←X ((2)Σ(+)) continuum leading to direct, near-threshold dissociation generating Ag* ((2)P3/2) + RG ((1)S0) products. Images recorded at excitation wavelengths throughout the C ((2)Σ(+))←X ((2)Σ(+)) continuum, coupled with known atomic energy levels, permit determination of the ground X ((2)Σ(+)) state dissociation energies of 85.9 ± 23.4 cm(-1) (Ag-Ar), 149.3 ± 22.4 cm(-1) (Ag-Kr), and 256.3 ± 16.0 cm(-1) (Ag-Xe). Three additional photolysis processes, each yielding Ag atom photoproducts, are observed in the same spectral region. Two of these are markedly enhanced in intensity upon seeding the molecular beam with nitrous oxide, and are assigned to photodissociation of AgO at the two-photon level. These features yield an improved ground state dissociation energy for AgO of 15 965 ± 81 cm(-1), which is in good agreement with high level calculations. The third process results in Ag atom fragments whose kinetic energy shows anomalously weak photon energy dependence and is assigned tentatively to dissociative ionization of the silver dimer Ag2.

  12. Patterns of orthopox virus wild rodent hosts in South Germany.

    PubMed

    Essbauer, Sandra; Hartnack, Sonja; Misztela, Krystian; Kiessling-Tsalos, Judith; Bäumler, Walter; Pfeffer, Martin

    2009-06-01

    Although cowpox virus (CPXV) infections in a variety of dead-end hosts have been investigated in Germany for more than 50 years, data on species and geographical distribution of CPXV in reservoir hosts are sparse. Here we present the first comprehensive study of 825 rodents that have been collected in Bavaria, Southern Germany. In summary, six different rodent species (Apodemus flavicollis, Myodes glareolus, Microtus arvalis, Apodemus sylvaticus, Microtus agrestis, and Arvicola amphibius) were trapped at three main trapping sites and investigated using a serum neutralization test (SNT). Prevalence of orthopox virus (OPV)-neutralizing antibodies was (with exception of one trapping site) highest in bank voles, ranging from 24.5% to 42.4%; often with SNT titers > or =96. Two up to 25% of yellow-necked mice were OPV sero-positive, but wood mice only at one site with 5.5%. Up to 7.7% of common voles were found to be OPV seroreactive, while M. agrestis and A. amphibius only sporadically showed seroreactivity. Further analyses of a subset of 450 bank voles and yellow-necked mice trapped at one site over a 18-month period revealed that male yellow-necked mice and female gravid yellow-necked mice had significantly more OPV-neutralizing antibodies. Mean body weight and OPV-seroreactivity were significantly negatively associated in male A. flavicollis. This was not due to shorter body length or smaller body mass index, but previously OPV-infected male A. flavicollis had dramatically reduced mean kidney weights. Seroreactivity in female bank voles was positively related to lung weights. We also found that both male yellow-necked mice and male bank voles with positive SNT titers had higher infestation rates with ectoparasites. We here show for the first time that A. flavicollis beside M. glareolus is a hypothetic host for CPXV, and that there are big geographical and spatial variations concerning the seroprevalence in rodent populations in South Germany.

  13. A review of multiple natural hazard risks in Germany

    NASA Astrophysics Data System (ADS)

    Kreibich, Heidi; Schröter, Kai; Bubeck, Philip; Parolai, Stefano; Khazai, Bijan; Daniell, James; Kunz, Michael; Mahlke, Holger; Lakes, Tobia

    2013-04-01

    Germany is experiencing various natural hazards and their impacts are expected to increase due to socio-economic and climatic changes, if an efficient risk management is not able to counteract. The international disaster database EM-DAT lists 79 events, namely earthquakes (3), extreme temperatures (9), floods (18), wet mass movement (1), storms (47) and wildfire (1) between 1950 and 2011; all together causing more than 10.000 fatalities and more than 40 billion US damage in Germany. The event with the highest human loss was the heat wave of 2003 with more than 9.000 fatalities. The event with the highest economic damage was the flood in 2002 causing €11.600 million damage. The aim of this paper is to offer a new perspective on multiple risk assessments in Germany by giving a systematic and comprehensive review on existing hazards and risk management strategies. Such a multiple risk assessment is particularly important because the potential for a natural event to cause a disaster depends on how vulnerable an exposed community is to such hazards. Human actions can reduce the damage to people and property but can at the same time increase the exposure to risks and exacerbate the impacts of hazardous events. To significantly improve risk management, i.e. decrease vulnerability and increase resilience of a region, more effort is needed than the well-established hazard-specific risk assessments. Planners and decision-makers need to be aware of and informed about all pertinent hazards in a region. Thus, to compare different hazards and to evaluate changes in risk, we propose the need of a consistent multi risk assessment.

  14. Antimicrobial susceptibility and molecular epidemiology of Neisseria gonorrhoeae in Germany.

    PubMed

    Horn, Nicole Nari; Kresken, Michael; Körber-Irrgang, Barbara; Göttig, Stephan; Wichelhaus, Cornelia; Wichelhaus, Thomas A

    2014-07-01

    Antimicrobial drug resistance in Neisseria gonorrhoeae has become an increasing public health problem. Hence, surveillance of resistance development is of crucial importance to implement adequate treatment guidelines. Data on the spread of antibiotic resistance among gonococcal isolates in Germany, however, is scarce. In a resistance surveillance study conducted by the Paul Ehrlich Society for Chemotherapy between October 2010 and December 2011, 23 laboratories all over Germany were requested to send N. gonorrhoeae isolates to the study laboratory in Frankfurt am Main. Species verification was performed biochemically using ApiNH and with Matrix-Assisted Laser Desorption Ionization-Time of Flight Mass Spectrometry (MALDI-TOF MS). Antimicrobial susceptibility testing was performed using the Etest method. For molecular epidemiological analysis, N. gonorrhoeae strains were genotyped by means of N. gonorrhoeae multi-antigen sequence typing. A total of 213 consecutive gonococcal isolates were analyzed in this nationwide study. Applying EUCAST breakpoints, high resistance rates were found for ciprofloxacin (74%) and tetracycline (41%). Penicillin non-susceptibility was detected in 80% of isolates. The rate of azithromycin resistance was 6%, while all strains were susceptible to spectinomycin, cefixime, and ceftriaxone. Molecular typing of gonococcal isolates revealed a great heterogeneity of 99 different sequence types (ST), but ST1407 predominated (n=39). This is the first comprehensive German multi-centre surveillance study on antibiotic susceptibility and molecular epidemiology of N. gonorrhoeae with implications for antibiotic choice for treatment of gonorrhoea. The World Health Organization supports the concept that an efficacious treatment of gonorrhoea results in at least 95% of infections being cured. Accordingly, as spectinomycin is not available on the German market, only the third generation cephalosporins cefixime and ceftriaxone are regarded as valuable drugs

  15. Ag surface diffusion and out-of-bulk segregation in CrN-Ag nano-composite coatings.

    PubMed

    Incerti, L; Rota, A; Ballestrazzi, A; Gualtieri, E; Valeri, S

    2011-10-01

    CrN-Ag nanocomposite coatings are deposited on Si(100) wafers and 20MnCr5 steel disks in a mixed Ar+N2 atmosphere by reactive magnetron sputtering. Structure, composition and morphology were investigated by Scanning Electron Microscopy (SEM), Auger Electron Spectroscopy (AES), X-ray Photoemission Spectroscopy (XPS), X-ray Diffraction (XRD) and Focused Ion Beam (FIB) cross sectional analysis. The as deposited film matrix is mainly composed by CrN phase (78%), but a relevant part (28%) is composed by Cr2N. Ag agglomerates in the CrN matrix forming elongated grains 200-400 nm wide and 50-100 nm high, which extends on the top of CrN columns. At the surface Ag aggregates into two different structures: large tetrahedral crystalline clusters, with typical dimension ranging from 200 to 500 nm, and smaller Ag nanoparticles with diameter of 15-25 nm. The annealing in N2 atmosphere up to 500 degrees C does not affect size and distribution of the Ag grains in the sub-surface region, while it induces a size increase of the bigger Ag clusters on the surface, mainly related to Ag surface diffusion and clusters coalescence. Annealing at higher temperature leads to an evident Ag out-of-bulk segregation, generating Ag depleted voids in the near-surface region, and further increasing of the Ag clusters size at the surface. Tribological tests on as deposited CrN-Ag film reveal a coefficient of friction against a steel ball reduced with respect to CrN film, probably related to the presence of Ag which acts as solid lubricant, but the coating is removed after a very short sliding distance. The poor mechanical properties of the realized Ag-based coatings are confirmed by lower hardness and Young modulus values with respect to pure CrN.

  16. Klimanavigator - Climate Navigator - Gateway to climate knowledge in Germany

    NASA Astrophysics Data System (ADS)

    Schuck-Zöller, Susanne

    2013-04-01

    Objective More than 50 German research institutions and networks are represented on www.klimanavigator.de, a common platform, where information about their work, and the latest findings from climate research and adaptation can be found. Thus Klimanavigator as a gateway to climate knowledge provides a information portal for those who have to respond to climate change. The internet portal gives an overview of the present state of research and is estimated as a decision support tool for appropriate mitigation and adaptation measures. Target Groups The portal collects the German climate research institutions to publish their scientific knowledge in a non-scientific language. Economists, policymakers, administration and the media are bound to find the names of scientific experts and institutions by an elaborated research tool. Methodology The chapter "Dossiers" is edited by the Klimanavigator-Coordinator CSC. It gathers information to a special issue looked upon from various points of view. Publications of outstanding German scientists are presented side by side, current knowledge is being synthesized, scientifically reviewed and disseminated. The latest news from climate and adaptation research is presented in an own chapter, dedicated to the press releases of the portal members. Via RSS-feed the press releases are collected from the different partner institutions. Thirdly, portraits of the member institutions, that are individually edited by themselves, draw a map of science in Germany and help to find appropriate cooperation partners. For the future further development is being planned. Common Management Klimanavigator is being managed by the partners in common. The main decisions concerning the concept and shape of the portal are made by the partners' assembly. An elected editorial committee decides about the content between the assemblies. The Climate Service Center (part of the Helmholtz-Zentrum Geesthacht) concentrates on facilitating the cooperation, and

  17. [Quality improvement in acute pain management in Germany].

    PubMed

    Meißner, Winfried

    2016-01-01

    In Germany, different quality management approaches in postoperative pain management have been established. In this context, quality is distinguished into structure quality (e.g. personnel and equipment resources), process quality (e. g. standardized treatment schemes) and outcome quality (e.g. pain intensity, side effects, satisfaction). While guidelines and recommendations help to set up evidence based structures and processes and offer support for decision making, benchmark projects offer insights in real life conditions. By use of feedback and benchmarking tools, they can be used for outcome-oriented quality improvement. Certification projects assess compliance with or achievement of defined quality criteria on the basis of predefined structure, process, and outcome parameter.

  18. The school-HE interface in West Germany

    NASA Astrophysics Data System (ADS)

    Schmithals, F.

    1986-09-01

    The author outlines the history of relationships between schools and higher educational institutions in Germany. He describes the problems caused by a mismatch between the number of educated teachers and the number of posts available for them. He discusses the role of the final school examination (Abitur) in university admission and in indicating general maturity for higher education (Allgemeine Hochschulreife). Attempts to improve the state of preparedness of students entering the universities, including the 1972 reform and the optional 'pre-courses', provided by some universities, are discussed.

  19. Meseritz-Obrawalde: a 'wild euthanasia' hospital of Nazi Germany.

    PubMed

    Benedict, Susan; Chelouche, Tessa

    2008-03-01

    In 1939, Hitler authorized a programme of 'euthanasia' of children and adults with physical and psychiatric disorders. Initially, gas chambers were established at six psychiatric institutions in Germany and Austria. This programme was discontinued in August 1941 but the killings continued on an individual basis. Physicians selected patients who were unable to work or who required extensive care, and ordered the nurses to administer lethal doses of sedatives. Meseritz-Obrawalde was a site for 10,000 of these killings. Using documents from the trial of one of Obrawalde's physicians, Hilde Wernicke, the era of 'wild euthanasia' is described and her rationale for participating in the killings is explored. PMID:19127829

  20. Wartime nuclear weapons research in Germany and Japan.

    PubMed

    Grunden, Walter E; Walker, Mark; Yamnazaki, Masakatsu

    2005-01-01

    This article compares military research projects during the Second World War to develop nuclear weapons in Germany and Japan, two countries who lost the war and failed to create nuclear weapons. The performance and motivations of the scientists, as well as the institutional support given the work, is examined, explaining why, in each case, the project went as far as it did-but no further. The story is carried over into the postwar period, when the two cultures and their scientists had to deal with the buildup of nuclear weapons during the cold war and the new nuclear power industry.

  1. Extreme drought events in Germany during the last 60 yrs

    NASA Astrophysics Data System (ADS)

    Samaniego, L. E.; Kumar, R.; Zink, M.

    2011-12-01

    Droughts are among the most costly natural disasters because they heavily impact on the economy of a region as well as on its social and cultural activities. Droughts do not only occur in arid or semiarid regions but also in humid ones. The year 2007, for example, was the sunniest, hottest and driest in Germany in the last two centuries. In this case, it was too dry too early. As a result, the harvest was cut by half leading to enormous losses in the primary sector. Consumer prices of some agricultural products went up 26 percent. The purpose of this study is to identify the major agricultural and hydrological droughts in Germany since 1950 based on their severity, duration and areal extend. To achieve this goal, a 60-yr retrospective hydrological simulation of the land surface water budget over Germany was carried out with the process-based distributed hydrological model mHM. The model was forced with grided daily precipitation and temperature data at 4x4 km, and the model simulations were carried out at same spatial resolutions. Point measurement data from more than 5600 raingauges and about 1120 meteorological stations (DWD) were interpolated with EDK. Land cover change was also considered during this period. Drought indices were derived as monthly quantiles of the simulated fluxes which include root zone soil moisture and total runoff. A Gaussian kernel smoother was used to estimate these quantiles at each grid cell. A spatio-temporal cluster algorithm was used to consolidate all significant drought events. Main statistics such as magnitude, areal extend, duration, and severity were estimated only on those selected clusters. The mHM model was calibrated in major river basins giving Nash-Sutcliffe efficiencies for daily discharge simulations greater than 0.8 in the evaluation period. Plausibility tests between the simulated mHM soil moisture and land surface temperature from MODIS and regional climate model reanalysis data compared well. Results indicated that

  2. Synthesis and Functions of Ag2S Nanostructures

    NASA Astrophysics Data System (ADS)

    Cui, Chunyan; Li, Xiaoru; Liu, Jixian; Hou, Yongchao; Zhao, Yuqing; Zhong, Guocheng

    2015-11-01

    The paper presents a review about synthesis and applications of Ag2S nanostructures. As the modern photoelectric and biological materials, Ag2S nanomaterials are potentially useful for both structure and function purposes. Ag2S is a direction narrow band gap semiconductor with special properties. Ag2S nanostructures have been widely researched in chemistry and biochemistry fields because of their unusual optical, electrical, and mechanical properties. It can also be used in many fields, such as photovoltaic cells and infrared detector. In the past few years, Ag2S nanostructures have been synthesized by various methods. The article mainly discusses the four types of preparation methods. Moreover, this article shows a detailed review on the new properties, fabrication, and applications of Ag2S nanocrystals.

  3. Facile tuning of superhydrophobic states with Ag nanoplates.

    SciTech Connect

    Sun, Y.; Qiao, R.; Clemson Univ.

    2008-01-01

    GaAs wafers have been decorated with Ag nanoplates through direct galvanic reaction between aqueous AgNO{sub 3} solutions and GaAs, resulting in Ag nanoplate/GaAs composite surfaces with varying hydrophobocity after the Ag nanoplates are coated with self-assembled monolayers of alkyl thiol molecules. By carefully controlling the reaction conditions, such as growth time and concentration of the AgNO{sub 3} solution, the size, thickness, and surface roughness of the individual Ag nanoplates can be tuned in order to produce different topographic structures and roughness of the composite surfaces, which in turn influences the hydrophobicity of the surfaces. The as-synthesized composite surfaces have been found to exhibit various levels of hydrophobicity and different wetting states such as the Wenzel wetting state, Cassie impregnating wetting state, and Cassie nonwetting state. The relationship between surface structure and hydrophobic state is also discussed.

  4. Double dumbbell shaped AgNi alloy by pulsed electrodeposition

    SciTech Connect

    Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy; Narayanan, V. Stephen, A.

    2014-01-28

    Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

  5. Synthesis and Functions of Ag2S Nanostructures.

    PubMed

    Cui, Chunyan; Li, Xiaoru; Liu, Jixian; Hou, Yongchao; Zhao, Yuqing; Zhong, Guocheng

    2015-12-01

    The paper presents a review about synthesis and applications of Ag2S nanostructures. As the modern photoelectric and biological materials, Ag2S nanomaterials are potentially useful for both structure and function purposes. Ag2S is a direction narrow band gap semiconductor with special properties. Ag2S nanostructures have been widely researched in chemistry and biochemistry fields because of their unusual optical, electrical, and mechanical properties. It can also be used in many fields, such as photovoltaic cells and infrared detector. In the past few years, Ag2S nanostructures have been synthesized by various methods. The article mainly discusses the four types of preparation methods. Moreover, this article shows a detailed review on the new properties, fabrication, and applications of Ag2S nanocrystals. PMID:26525702

  6. Nanoparticle Ag-enhanced textured-powder Bi-2212/Ag wire technology

    NASA Astrophysics Data System (ADS)

    Kellams, J. N.; McIntyre, P.; Pogue, N.; Vandergrifft, J.

    2015-12-01

    A new approach to the preparation of cores for Bi-2212/Ag wire is being developed. Nanoparticle Ag is homogeneously dispersed in Bi-2212 fine powder, and the mixture is uniaxially compressed to form highly textured, cold-sintered core rods. The rods can be assembled in a silver matrix, drawn to form multifilament wire, and restacked and drawn to form multifilament wire. Preliminary studies using tablet geometry demonstrate that a nonmelt heat treatment produces densification, grain growth, intergrowth among grains, and macroscopic current transport. The status of the development is reported.

  7. Oxidative Stress Mechanisms Caused by Ag Nanoparticles (NM300K) are Different from Those of AgNO3: Effects in the Soil Invertebrate Enchytraeus crypticus

    PubMed Central

    Ribeiro, Maria J.; Maria, Vera L.; Scott-Fordsmand, Janeck J.; Amorim, Mónica J. B.

    2015-01-01

    The mechanisms of toxicity of Ag nanoparticles (NPs) are unclear, in particular in the terrestrial environment. In this study the effects of AgNP (AgNM300K) were assessed in terms of oxidative stress in the soil worm Enchytraeus crypticus, using a range of biochemical markers [catalase (CAT), glutathione peroxidase (GPx), glutathione S-transferase (GST), glutathione reductase (GR), total glutathione (TG), metallothionein (MT), lipid peroxidation (LPO)]. E. crypticus were exposed during 3 and 7 days (d) to the reproduction EC20, EC50 and EC80 levels of both AgNP and AgNO3. AgNO3 induced oxidative stress earlier (3 d) than AgNP (7 d), both leading to LPO despite the activation of the anti-redox system. MT increased only for AgNP. The Correspondence Analysis showed a clear separation between AgNO3 and AgNP, with e.g., CAT being the main descriptor for AgNP for 7 d. LPO, GST and GPx were for both 3 and 7 d associated with AgNO3, whereas MT and TG were associated with AgNP. These results may reflect a delay in the effects of AgNP compared to AgNO3 due to the slower release of Ag+ ions from the AgNP, although this does not fully explain the observed differences, i.e., we can conclude that there is a nanoparticle effect. PMID:26287225

  8. Rare and forbidden kaon decays at the AGS

    SciTech Connect

    Kettell, S.

    1997-12-09

    An overview of the Rare Kaon Decay program at the AGS is presented, with particular emphasis on the three major experiments currently running and analyzing data. A brief overview of earlier kaon decay experiments and of the AGs performance improvements is also provided. This review concludes with a discussion of proposed and developing experiments planned to run in the year 2000 and beyond (AGS-2000).

  9. Positive-ion emission from a-AgI films

    SciTech Connect

    Pong, W.; Lam, W.; Tong, A.; Brandt, D.

    1981-03-01

    Positive-ion emission from evaporated films of AgI was observed when the films were heated to temperatures above 160 /sup 0/C. A slow sublimation of AgI was also found to occur with the ion emission when the temperature was sufficiently high. The activation energy for positive-ion emission from the surface of a-AgI is estimated to be 1.7 eV.

  10. Transport of silver nanoparticles (AgNPs) in soil.

    PubMed

    Sagee, Omer; Dror, Ishai; Berkowitz, Brian

    2012-07-01

    The effect of soil properties on the transport of silver nanoparticles (AgNPs) was studied in a set of laboratory column experiments, using different combinations of size fractions of a Mediterranean sandy clay soil. The AgNPs with average size of ~30nm yielded a stable suspension in water with zeta potential of -39mV. Early breakthrough of AgNPs in soil was observed in column transport experiments. AgNPs were found to have high mobility in soil with outlet relative concentrations ranging from 30% to 70%, depending on experimental conditions. AgNP mobility through the column decreased when the fraction of smaller soil aggregates was larger. The early breakthrough pattern was not observed for AgNPs in pure quartz columns nor for bromide tracer in soil columns, suggesting that early breakthrough is related to the nature of AgNP transport in natural soils. Micro-CT and image analysis used to investigate structural features of the soil, suggest that soil aggregate size strongly affects AgNP transport in natural soil. The retention of AgNPs in the soil column was reduced when humic acid was added to the leaching solution, while a lower flow rate (Darcy velocity of 0.17cm/min versus 0.66cm/min) resulted in higher retention of AgNPs in the soil. When soil residual chloride was exchanged by nitrate prior to column experiments, significantly improved mobility of AgNPs was observed in the soil column. These findings point to the importance of AgNP-soil chemical interactions as a retention mechanism, and demonstrate the need to employ natural soils rather than glass beads or quartz in representative experimental investigations.

  11. The synthesis, activity, stability and the charge transfer identification of Ag:AgBr/γ-Al2O3 photocatalyst for organic pollutant decomposition in water

    NASA Astrophysics Data System (ADS)

    Huang, Shan; Si, Zhichun; Weng, Duan

    2015-12-01

    Highly stable Ag:AgBr/γ-Al2O3 photo-catalyst was obtained by dispersing AgBr sol on hollow γ-Al2O3 microsphere. Metallic Ag nanoparticles were in situ generated on AgBr crystals by a photo-reduction method. The activity of catalyst was characterized by MO and phenol decomposition. The light irradiation response, the life times of the photo-induced charges, and the charge separation and transition were determined by the UV-vis diffuse reflection spectra, open circuit voltage decay spectra and transient photocurrent responses. The as-prepared Ag:AgBr/γ-Al2O3 catalyst can response to visible light irradiation. Charge separation was clarified to correlate with electrons transferring from Ag to AgBr surface and the consequent reaction with ads-O2 to generate rad O2- species. It was found that the rad O2- rather than rad OH played a dominant role in the photocatalytic oxidation of MO and phenol in water. However, the electrons trended to transfer from AgBr to Ag intrinsically without light irradiation. Therefore, the electron transfer between Ag and AgBr reaching the dynamic equilibrium was the key factor for obtaining a high stable Ag/AgBr catalyst which can be obtained by optimizing the Ag:AgBr ratio. Loading amount of Ag:AgBr on γ-Al2O3 was optimized to 30 wt.% and the metallic Ag content was stabilized at 9 wt.% of Ag:AgBr catalyst.

  12. Ag-ZnO nanostructure for ANTA explosive molecule detection

    NASA Astrophysics Data System (ADS)

    Shaik, Ummar Pasha; Sangani, L. D. Varma; Gaur, Anshu; Mohiddon, Md. Ahamad; Krishna, M. Ghanashyam

    2016-05-01

    Ag/ZnO nanostructure for surface enhanced Raman scattering application in the detection of ANTA explosive molecule is demonstrated. A highly rough ZnO microstructure was achieved by rapid thermal annealing of metallic Zn film. Different thickness Ag nanostructures are decorated over these ZnO microstructures by ion beam sputtering technique. Surface enhanced Raman spectroscopic studies carried out over Ag/ZnO substrates have shown three orders higher enhancement compared to bare Ag nanostructure deposited on the same substrate. The reasons behind such huge enhancement are discussed based on the morphology of the sample.

  13. Molecular dynamics study of nanojoining between axially positioned Ag nanowires

    NASA Astrophysics Data System (ADS)

    Cui, Jianlei; Theogene, Barayavuga; Wang, Xuewen; Mei, Xuesong; Wang, Wenjun; Wang, Kedian

    2016-08-01

    The miniaturization of electronics devices into nanometer scale is indispensable for next-generation semiconductor technology. Ag nanowires (Ag NWs) are considered to be the promising candidates for future electronic circuit owing to the excellent electrical and thermal properties. The nanojoining of axially positioned Ag NWs was performed by molecular dynamics simulation. Through the detailed atomic evolution during the nanojoining, the results indicate that the temperature and the distance between Ag NWs in axial direction have a great impact on nanojoining effect. When the nanojoining temperature is relatively high, the atoms are disordered and the atomic queues become to distort with strong thermodynamic properties and weak effect of metal bonds. At the relatively low temperature, the Ag NWs can be well connected with good junction quality and their own morphology, which is similar to the cold welding without fusion, while the distance between Ag NWs should be controlled for interaction and diffusion of interfacial atoms at nanowires head. When the Ag NWs are placed on Si and SiO2 substrate, because the atomic species and lattice structure of substrate material can differently affect the motions of Ag atoms through the interactive force between the atoms, the nanojoining quality of Ag NWs on Si substrate is better than that on the SiO2 substrate. So, for getting effective and reliable nanojoining without nanosolders and other materials, the temperature, distance and substrate surface should be reasonably controlled and selected, providing helpful theoretical guidance for experiment and application of nanojoining.

  14. AG Pegasi - now a classical symbiotic star in outburst?

    NASA Astrophysics Data System (ADS)

    Tomov, T. V.; Stoyanov, K. A.; Zamanov, R. K.

    2016-11-01

    Optical spectroscopy study of the recent AG Pegasi (AG Peg) outburst observed during the second half of 2015 is presented. Considerable variations of the intensity and the shape of the spectral features as well as the changes of the hot component parameters, caused by the outburst, are discussed and certain similarities between the outburst of AG Peg and the outburst of a classical symbiotic stars are shown. It seems that after the end of the symbiotic nova phase, AG Peg became a member of the classical symbiotic stars group.

  15. Stability of Ag nanoparticles dispersed in amphiphilic organic matrix

    NASA Astrophysics Data System (ADS)

    Suvorova, Elena I.; Klechkovskaya, Vera V.; Kopeikin, Victor V.; Buffat, Philippe A.

    2005-02-01

    Nano- and thin-film technologies based on novel systems associating metals particles to polymer matrix open a broad range of different applications. Such composites were found to be more efficient and safe, for instance, in biomedical needs. The Ag/poly(N-vinyl-2-pyrrolidone) (Ag/PVP) composite investigated in the present work is a new bactericide mean applied in complicated cases of infected burns and purulent wounds. High-resolution transmission electron microscopy (HRTEM) and X-ray energy-dispersive (EDS) microanalysis were used to bring chemical and structural information in a study of the properties and stability of thin-film nanocomposite whih consisted of Ag nanoparticles dispersed in water-soluble organic matrix poly(N-vinyl-2-pyrrolidone). The nanostructural investigation of Ag/PVP composite by HRTEM and EDS exposed to SO 2 and H 2S from the atmosphere and some traces of S-containing substances explains the limited stability of this system by a structural modification associated with a phase change and formation of Ag 2S and Ag 2SO 3. However, formation of the hardly water-soluble Ag 2S and Ag 2SO 3 salts may play an important role in the suppression of bacterial growth. On the one hand, silver could block S-H groups in vital proteins and conduced to their destruction, in that way revealing the antibacterial power. On the other hand, antiseptic properties of Ag consist in binding the products of the protein decay.

  16. Phytotoxicity of Ag nanoparticles prepared by biogenic and chemical methods

    NASA Astrophysics Data System (ADS)

    Choudhury, Rupasree; Majumder, Manna; Roy, Dijendra Nath; Basumallick, Srijita; Misra, Tarun Kumar

    2016-06-01

    Silver nanoparticles (Ag NPs) are now widely used as antibacterial and antifungal materials in different consumer products. We report here the preparation of Ag NPs by neem leaves extract ( Azadirachta) reduction and trisodium citrate-sodium borohydride reduction methods, and study of their phytotoxicity. The nanoparticles were characterized by UV-Vis spectroscopy, FTIR, and atomic force microscopy (AFM) techniques. Both neem-coated and citrate-coated Ag NPs exhibit surface plasmon around 400 nm, and their average sizes measured by AFM are about 100 and 20 nm, respectively. Antibacterial and antifungal activities of these nanomaterials have been studied by simple pea seed germination and disk diffusion methods. It has been observed from the growth of root and shoot, citrate-coated Ag NPs significantly affect seedling growth, but neem-coated Ag NPs exhibit somehow mild toxicity toward germination process due to the nutrient supplements from neem. On the other hand, antifungal activity of neem-coated Ag NPs has been found much higher than that of citrate-coated Ag NPs due to the combined effects of antifungal activity of neem and Ag NPs. Present research primarily indicates a possible application of neem-coated Ag NPs as a potential fungicide.

  17. Contact Resistance of Ti-Si-C-Ag and Ti-Si-C-Ag-Pd Nanocomposite Coatings

    NASA Astrophysics Data System (ADS)

    Sarius, N. G.; Lauridsen, J.; Lewin, E.; Jansson, U.; Högberg, H.; Öberg, Å.; Sarova, G.; Staperfeld, G.; Leisner, P.; Eklund, P.; Hultman, L.

    2012-03-01

    Ti-Si-C-Ag-Pd and Ti-Si-C-Ag nanocomposite coatings were deposited by direct-current magnetron sputtering on Cu substrates with an electroplated Ni layer. Analytical electron microscopy, x-ray diffraction, and x-ray photoelectron spectroscopy show that the nanocomposites consist of TiC, Ag:Pd, and amorphous SiC. The contact resistance of these coatings against a spherical Au-Co surface was measured for applied contact forces up to 5 N. Ti-Si-C-Ag-Pd coatings with Ag:Pd top coating had ~10 times lower contact resistance at contact forces below 1 N (~10 mΩ at ~0.1 N), and 2 to 3 times lower for contact forces around 5 N (<1 mΩ at 5 N), compared with the Ti-Si-C-Ag coating.

  18. Cu-Ag sulfides as indicators of pre-porphyritic epithermal Au-Ag deposits in Northeastern Russia

    NASA Astrophysics Data System (ADS)

    Savva, N. E.; Sidorov, A. A.; Volkov, A. V.

    2016-08-01

    Au-Ag mineralization of the Olcha and Teploe epithermal deposits underwent thermal metamorphism due to porphyritic intrusions. The presence of Bi-bearing galena and matildite in the ores (Teploe), Cu-Te-bearing naumannite (Olcha), the occurrence of middle- and high-temperature facies of metasomatic rocks (epidote and actinolite), and temperature formation conditions are related, firstly, to the influence of granitoids on the ore process, which supplied not only Cu and Mo, but also Bi, Te, and, secondly, to the heating of host rocks containing pre-porphyritic epithermal Au-Ag mineralization. The abundance of Cu-Ag sulfides and Cu-acanthite resulted from the enrichment of later mineral phases in Cu and Ag under the substance redistribution with the formation of Ag-acanthite ores. The data considered in the paper are of practical importance for regional forecasting of metallogenic constructions, exploration, and evaluation of the epithermal Au-Ag deposits.

  19. Fabrication of a microfluidic Ag/AgCl reference electrode and its application for portable and disposable electrochemical microchips.

    PubMed

    Zhou, Jianhua; Ren, Kangning; Zheng, Yizhe; Su, Jing; Zhao, Yihua; Ryan, Declan; Wu, Hongkai

    2010-09-01

    This report describes a convenient method for the fabrication of a miniaturized, reliable Ag/AgCl reference electrode with nanofluidic channels acting as a salt bridge that can be easily integrated into microfluidic chips. The Ag/AgCl reference electrode shows high stability with millivolt variations. We demonstrated the application of this reference electrode in a portable microfluidic chip that is connected to a USB-port microelectrochemical station and to a computer for data collection and analysis. The low fabrication cost of the chip with the potential for mass production makes it disposable and an excellent candidate for real-world analysis and measurement. We used the chip to quantitatively analyze the concentrations of heavy metal ions (Cd(2+) and Pb(2+)) in sea water. We believe that the Ag/AgCl reference microelectrode and the portable electrochemical system will be of interest to people in microfluidics, environmental science, clinical diagnostics, and food research.

  20. Novel visible-light-responsive Ag/AgCl@MIL-101 hybrid materials with synergistic photocatalytic activity.

    PubMed

    Gao, Shutao; Feng, Tao; Feng, Cheng; Shang, Ningzhao; Wang, Chun

    2016-03-15

    In this paper, a novel visible-light responsive photocatalyst of Ag/AgCl@MIL-101 was synthesized via vapor diffusion-photoreduction strategy. The as-prepared composite material was characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, ultraviolet-visible diffuse reflection spectra and X-ray photoelectron spectroscopy. Due to the synergistic effect between Ag/AgCl and MIL-101, the composite photocatalyst exhibited an enhanced and stable photoactivity for the degradation of Rhodamine B under visible light irradiation. The relationship between the photocatalytic activity and the structure of Ag/AgCl@MIL-101 hybrid material was discussed and the possible reaction mechanism was proposed.

  1. [Synthesis of Cu2O-Ag-AgBr/MA visible photocatalyst and its performance in degradation of 2-chlorophenol].

    PubMed

    Wang, Ran; Zhou, Xue-feng; Hu, Xue-xiang; Hu, Chun

    2014-09-01

    Cu2O-Ag-AgBr/MA plasmon photocatalyst was prepared by the co-deposition of Cu2O and Ag-AgBr nanoparticles on mesoporous alumina (MA). The samples were characterized by means of X-ray diffraction (XRD) ,X-ray photoelectron spectroscopy (XPS) and diffuse reflectance UV-vis spectra (UV-vis DRS). The results showed that both Ag+ and Ag0 existed on the surface. The photocatalytic activity of the samples prepared were evaluated by degradation of 2-chlorophenol (2-CP) under visible light (λ >420 nm) irradiation. The results showed that the catalyst had high photocatalytic activity for the degradation of 2-CP. Meanwhile, the doping of Cu2O nanoparticles significantly inhibited the release of silver ions during the photocatalytic reaction, which improved the photostability of the catalyst. Analyses on the effects of various scavengers showed that h+ , O2- and OH radicals were the primary active species. PMID:25518659

  2. [Healthcare services research on pain in Germany. A survey].

    PubMed

    Häuser, W; Neugebauer, E; Petzke, F

    2015-10-01

    Within the last ten years healthcare services research has developed into an independent interdisciplinary field of research. A selective search of the literature was conducted in the database Google Scholar and the database on healthcare services research in Germany (http://versorgungsforschung-deutschland.de) for healthcare services research projects on pain in Germany. Healthcare services research projects were conducted by pharmaceutical companies, patient self-help organizations, scientific societies, statutory health insurance companies and university departments on acute and chronic pain. Valid data on the epidemiology, grading and treatment of chronic pain are available. There was an overuse of opioids and invasive procedures in patients with chronic low back pain, fibromyalgia syndrome and somatoform pain disorders. Databases for patients with chronic pain are currently constructed by pain societies. The fragmentation of data from health insurance companies, old age pension insurances, clinical institutions and population surveys and inconsistencies in diagnosing or encoding chronic pain impede the carrying out of significant longitudinal studies. Based on the data available, the needs of care for patients with chronic pain and the necessary care services cannot be derived. Important topics of future healthcare services research on pain are longitudinal studies on the cost efficacy and risks of inpatient and outpatient pain therapy based on routine data of health insurance companies, old age pension insurances and pain registries, longitudinal studies on "patient careers" (i.e. sequences of healthcare) and the identification of potential starting points for control of healthcare. PMID:26264899

  3. Seasonal fluctuations of head lice infestation in Germany.

    PubMed

    Bauer, Eline; Jahnke, Claudia; Feldmeier, Hermann

    2009-02-01

    Pediculosis capitis is one of the most frequent infectious diseases in childhood. If not diagnosed and treated rapidly, considerable clinical pathology may develop. The ubiquitous parasitic skin disease is characterized by a lack of sound epidemiological data, and factors which influence disease occurrence are still enigmatic. To investigate whether, in Germany, head lice infestation follows a seasonal pattern, we analyzed the weekly head lice consultations at the Health Department of Braunschweig City, Lower Saxony, for a period of 5 years, and compared the data with the units of pediculocides sold by two wholesalers to German pharmacies during a period of 2 and 3 years, respectively. The number of consultations did not show a clear seasonality, although there was a tendency of fewer consultations during school holidays, and an increase when schools opened again after Christmas, Easter, summer, and autumn holidays. In contrast, the number of packages of pediculocides sold followed a distinct seasonal rhythm with a maximum between calendar week 34 and 40, i.e., from mid September to end of October. In Germany, occurrence of pediculosis capitis varies according to the season of the year with a maximum in late summer and early autumn. PMID:19015879

  4. [Helmut Schmidt--a protagonist of modern anesthesia in Germany].

    PubMed

    Goerig, M; Schulte am Esch, J

    1996-12-01

    Helmut Schmidt, an assistant of the reputed surgeon Paul Sudeck, who headed the Surgical Department of the University in Hamburg at that time, habilitated in 1928. The title of his monograph was "Merits of nitrous oxide anaesthesia--a comparative study seeking reintroduction and increase of the use of nitrous oxide in Germany". With this paper, Schmidt qualified himself as the first lecturer for anaesthesiology in Germany. He had been eager since the mid-twenties on establishing our special medical discipline separate from surgery. Schmidt's merits also include introducing students and doctors to the practice of anaesthesiology, teaching both a practical approach towards anaesthesia at the operating room, and theory during lectures on general surgery. This method was absolutely new at that time. Due to the resistance by conservative surgeons, he failed to establish a "German Society of Anaesthesia" during the 90th meeting of the "German Society of Natural Scientists and Physicians" held in Hamburg in 1928. In fact, this was accomplished only as late as 1953. The following text recalls a number of contributions to anaesthesiology made by the honorary member of the "German Society for Anaesthesiology" Helmut Schmidt, who was born a hundred years ago and whose name and merits have fallen into oblivion during the past decades. PMID:9081419

  5. [Infectious diseases as a clinical specialty in Germany and Europe].

    PubMed

    Kern, Winfried V; Fätkenheuer, Gerd; Tacconelli, Evelina; Ullmann, Andrew

    2015-01-01

    Clinical infectious diseases have only slowly been established as a medical specialty in Germany. The density of infectious diseases (ID) specialists and the number of ID divisions in general hospitals is still limited when compared with the situation in many other European countries, and there is also a lack of hospital-based medical microbiologists and infection control doctors for many reasons. Often, there is a lack of understanding of the roles and the performance of ID specialists versus microbiologists. Experience in other countries shows that ID specialists are important as clinical experts at the bedside, can help ascertain healthcare quality and patient safety, and are perfectly suited for undertaking strategic tasks in the field of cost-effective antimicrobial therapy algorithms and antibiotic stewardship (ABS) in hospitals. ID specialists are responsible for infection control in several countries, can improve the utility of diagnostic microbiology and are key partners in translational research. We estimate that more than 1,000 additional ID specialists are needed in this country, and believe that specially trained ABS experts can take over parts of their responsibilities and tasks in smaller hospitals. More capacity and flexibility in postgraduate training in infectious diseases, antibiotic stewardship and infection control in Germany will be critical to address the problem of antimicrobial resistance. (As supplied by publisher).

  6. Acidification reversal in low mountain range streams of Germany.

    PubMed

    Sucker, Carina; von Wilpert, Klaus; Puhlmann, Heike

    2011-03-01

    This study evaluates the acidification status and trends in streams of forested mountain ranges in Germany in consequence of reduced anthropogenic deposition since the mid 1980s. The analysis is based on water quality data for 86 long-term monitored streams in the Ore Mountains, the Bavarian Forest, the Fichtelgebirge, the Harz Mountains, the Spessart, the Black Forest, the Thuringian Forest, and the Rheinisches Schiefergebirge of Germany and the Vosges of France. Within the observation period, which starts for the individual streams between 1980 and 2001 and ends between 1990 and 2009, trends in chemical water quality were calculated with the Seasonal Mann Kendall Test. About 87% of the streams show significant (p < 0.05) negative trends in sulfate. The general reduction in acid deposition resulted in increased pH values (significant for 66% of the streams) and subsequently decreased base cation concentrations in the stream water (for calcium significant in 58% and magnesium 49% of the streams). Reaction products of acidification such as aluminum (significant for 50%) or manganese (significant for 69%) also decreased. Nitrate (52% with significant decrease) and chloride (38% with significant increase) have less pronounced trends and more variable spatial patterns. For the quotient of acidification, which is the ratio of the sum of base cations and the sum of acid anions, no clear trend is observed: in 44% of the monitored streams values significantly decreased and in 23% values significantly increased. A notable observation is the increasing DOC concentration, which is significant for 55% of the observed streams.

  7. Transition in cancer patterns among Turks residing in Germany.

    PubMed

    Zeeb, H; Razum, O; Blettner, M; Stegmaier, C

    2002-03-01

    Cancer mortality among the 2.1 million Turks residing in Germany is assumed to change from a pattern typical for a developing country towards one of an industrialised country. To test this hypothesis, we compared age-standardised cancer mortality rates among Turkish residents and (West) Germans using death registration data. In addition, we assessed proportional cancer incidence ratios among Turkish cases (n=144) in a German population-based cancer registry. All-cancer mortality 1992-1997 (per 100000) was 34.8 (n=4192) among Turkish men (Germans: 72.3) and 21.5 (n=1862) among Turkish women (Germans: 52.4). Over time, gastric and lung cancer mortality increased among Turkish men, as did breast cancer mortality among Turkish women. The proportional cancer incidence (PCIR) for stomach cancer among men was 2.9 (95% Confidence Interval (CI): 1.7-4.8), and that for breast cancer among women was 0.7 (95% CI: 0.4-1.1). Turks had an increased proportional incidence ratio for non-Hodgkin's lymphoma. Our findings partly support a transition of cancer patterns among Turks in Germany.

  8. Depression risk in patients with coronary heart disease in Germany

    PubMed Central

    Konrad, Marcel; Jacob, Louis; Rapp, Michael A; Kostev, Karel

    2016-01-01

    AIM To determine the prevalence of depression and its risk factors among patients with coronary heart disease (CHD) treated in German primary care practices. METHODS Longitudinal data from nationwide general practices in Germany (n = 1072) were analyzed. Individuals initially diagnosed with CHD (2009-2013) were identified, and 59992 patients were included and matched (1:1) to 59992 controls. The primary outcome measure was an initial diagnosis of depression within five years after the index date among patients with and without CHD. Cox proportional hazards models were used to adjust for confounders. RESULTS Mean age was equal to 68.0 years (SD = 11.3). A total of 55.9% of patients were men. After a five-year follow-up, 21.8% of the CHD group and 14.2% of the control group were diagnosed with depression (P < 0.001). In the multivariate regression model, CHD was a strong risk factor for developing depression (HR = 1.54, 95%CI: 1.49-1.59, P < 0.001). Prior depressive episodes, dementia, and eight other chronic conditions were associated with a higher risk of developing depression. Interestingly, older patients and women were also more likely to be diagnosed with depression compared with younger patients and men, respectively. CONCLUSION The risk of depression is significantly increased among patients with CHD compared with patients without CHD treated in primary care practices in Germany. CHD patients should be routinely screened for depression to ensure improved treatment and management. PMID:27721937

  9. Recent data on iodine intake in Germany and Europe.

    PubMed

    Gärtner, Roland

    2016-09-01

    Iodine is essential for the synthesis of thyroid hormones. These regulate metabolism, promote growth, development and maturation of all organs, especially the brain. Most iodine is found in oceans and most continental soil and ground water is deficient in iodine. Therefore, around 2 billion individuals are estimated to have insufficient iodine intake and are at risk of iodine deficiency disorders. The best carrier for save iodine supplementation is salt, as the daily intake of salt is mainly constant. Due to the collaboration between international and national organisations and the salt industry, many developing and developed countries introduced universal salt iodization (USI) or have mandatory or voluntary fortification programs. In Germany as in most European countries the use of iodized salt is voluntary not only in household but also in the food industry. Two recent epidemiological surveys in Germany revealed that 33% of children and 32% of adults are still suffering from mild to moderate iodine deficiency. The best surrogate parameter for iodine deficiency is goitre. The goitre prevalence is around 30% in children as well as in adults which is in accordance with the documented iodine deficiency. From other European countries epidemiological derived data on iodine intake are only available from Denmark and Poland. Further efforts are under way to reveal the iodine status with proper methods in all European countries. On this background it might be possible to establish adequate iodine fortification programs in all European countries. PMID:27421794

  10. Prevalence of selected rickettsial infections in cats in Southern Germany.

    PubMed

    Bergmann, Michèle; Englert, Theresa; Stuetzer, Bianca; Hawley, Jennifer R; Lappin, Michael R; Hartmann, Katrin

    2015-10-01

    Prevalence of Anaplasma, Ehrlichia, Neorickettsia, and Wolbachia DNA in blood of 479 cats collected in different veterinary clinics in Southern Germany was determined using a previously published conventional PCR using 16S-23S intergenic spacer primers (5' CTG GGG ACT ACG GTC GCA AGA C 3' - forward; 5' CTC CAG TTT ATC ACT GGA AGT T 3' - reverse). Purified amplicons were sequenced to confirm genus and species. Associations between rickettsial infections, and feline immunodeficiency virus (FIV), as well as feline leukemia virus (FeLV) status were evaluated. Rickettsial prevalence was 0.4% (2/479; CI: 0.01-1.62%). In the two infected cats, Anaplasma phagocytophilum DNA was amplified. These cats came from different environment and had outdoor access. Both were ill with many of their problems likely related to other diseases. However, one cat had neutrophilia with left shift and the other thrombocytopenia potentially caused by their A. phagocytophilum infection. There was no significant difference in the FIV and FeLV status between A. phagocytophilum-negative and -positive cats. A. phagocytophilum can cause infection in cats in Southern Germany, and appropriate tick control is recommended. PMID:26387062

  11. Gambling market and individual patterns of gambling in Germany.

    PubMed

    Albers, N; Hübl, L

    1997-01-01

    In this paper individual patterns of gambling in Germany are estimated for the first time. The probit technique is used to test the influence of a set of individual characteristics on the probability of participating in each of the various legal games. A sample size of 1,586 adults collected for the pool of German lotteries provides a reliable set of data. All disaggregated estimations of participation are statistically significant at least at the 5 percent level. The basic findings suggest that gambling is a widespread normal (superior) consumption good because gambling participation tends to rise with income. Moreover, no demand anomaly can be found to justify assessing gambling as a social demerit. Only the participation in gaming machines is higher for younger, unemployed and less educated adults. While a moral evaluation of gambling is beyond the scope of this paper, the legislator's preference for a highly taxed state monopoly in gambling markets is to be rejected, at least for Germany. Additional statistical findings suggest distinct consumer perceptions of the characteristics of the various games and may be used for market segmentation. The paper starts with a descriptive introduction to the German gambling market.

  12. Direct costs of bovine spongiform encephalopathy control measures in Germany.

    PubMed

    Probst, C; Gethmann, J M; Heuser, R; Niemann, H; Conraths, F J

    2013-12-01

    On 26 November 2000, the first autochthonous case of bovine spongiform encephalopathy (BSE) was detected in Germany. Since then, a total of 413 BSE cases have been confirmed, resulting in the culling and destruction of 17 313 heads of cattle. In view of the possible risks for human and animal health, Germany has adopted EU regulations along with some additional requirements concerning active surveillance and response measures after detecting a BSE-positive animal. In this study, we used a stochastic model to estimate the costs incurred by the ensuing legislative amendments responding to BSE between November 2000 and December 2010. The total costs were estimated to range between 1847 and 2094 million Euros. They peaked in 2001 (about 394 million Euros) and declined since. About 54% of the costs (approximately 1000 million Euros) were incurred by the extension of the feed ban for animal protein to all farmed livestock. Active surveillance accounted for 21% (405 million Euros), the incineration of animal protein for 13% (249 million Euros) and the removal of specified risk material for 11% (225 million Euros). Only 1% of the costs was related to response measures after detecting a BSE-positive animal, including indemnity payments for culled cattle and confiscated carcasses at the slaughterhouse.

  13. Prevalence of selected rickettsial infections in cats in Southern Germany.

    PubMed

    Bergmann, Michèle; Englert, Theresa; Stuetzer, Bianca; Hawley, Jennifer R; Lappin, Michael R; Hartmann, Katrin

    2015-10-01

    Prevalence of Anaplasma, Ehrlichia, Neorickettsia, and Wolbachia DNA in blood of 479 cats collected in different veterinary clinics in Southern Germany was determined using a previously published conventional PCR using 16S-23S intergenic spacer primers (5' CTG GGG ACT ACG GTC GCA AGA C 3' - forward; 5' CTC CAG TTT ATC ACT GGA AGT T 3' - reverse). Purified amplicons were sequenced to confirm genus and species. Associations between rickettsial infections, and feline immunodeficiency virus (FIV), as well as feline leukemia virus (FeLV) status were evaluated. Rickettsial prevalence was 0.4% (2/479; CI: 0.01-1.62%). In the two infected cats, Anaplasma phagocytophilum DNA was amplified. These cats came from different environment and had outdoor access. Both were ill with many of their problems likely related to other diseases. However, one cat had neutrophilia with left shift and the other thrombocytopenia potentially caused by their A. phagocytophilum infection. There was no significant difference in the FIV and FeLV status between A. phagocytophilum-negative and -positive cats. A. phagocytophilum can cause infection in cats in Southern Germany, and appropriate tick control is recommended.

  14. [Regionalisation of Germany by data of agricultural structures].

    PubMed

    Merle, Roswitha; Busse, Marc; Rechter, Galina; Meer, Uwe

    2012-01-01

    In order to simplify the design of representative studies in animal populations the structural differences of animal husbandry (cattle, pigs and laying hens) in Germany were characterised. Several regions were defined and thus districts identified which are typical for the respective region and can be regarded as representatives for the whole region. Data on animal husbandry as well as human population per district originated from the Federal Statistical Office and were linked to the geometric data of the Federal Agency for Cartography and Geodesy. By this, data of "livestock units/square kilometre area" and "farms/square kilometre area" per district were calculated using methods of the spatial statistics Global Moran's Index, Anselin Local Moran's Index and Getis-Ord Gi*. With the help of these analyses six clusters could be identified which resulted in four large (Middle, Northwest, East, and South) and one smaller region (Northern Upper-Rhine) respecting the federal state borders. These regions differed significantly regarding animal and farm densities. The selection of typical districts was carried out with the help of the respective animal and farm data of the species pigs, dairy cattle and laying hens. The means of the selected districts (three to six per region) were within the 60%- and the 80%-percentile of at least two of the analysed variables. Concerning the region Northern Upper-Rhine no representative district was selected. This presented regionalisation including representative districts can be used for the design of scientific studies that are associated with animal husbandry in Germany.

  15. Data safety and drug safety in Germany: a closing gap?

    PubMed

    Rathmann, W

    2001-12-01

    Pharmacoepidemiology and drug utilization research are more and more involved in a fundamental conflict with data privacy regulations in Germany. In an attempt to close this gap, a working group of German data protection commissioners and representatives from epidemiologic research societies published guidelines on epidemiology and data protection, which are briefly reviewed. There are several data sources for drug utilization research and pharmacoepidemiology in Germany (national health surveys, routine data from hospitals, general practitioners, or statutory health insurance companies) allowing descriptive and analytic epidemiologic studies. Furthermore, since 1980 a random sample of all prescriptions of patients from statutory health insurances (GKV-Arzneimittelindex) is analysed to produce an annual report on prescription drug use. More intensive use of health insurance data for evaluation of medical care including drug prescriptions is in discussion. The MediPlus (IMS HEALTH) database on 400 general and internal medicine practices provides an example to close the gap between the current demand for drug safety studies and data privacy issues. Finally, large provider systems with enormous data storage and data flow are emerging. Therefore, a further development of policies to guarantee ethically correct use of personally identifiable health data in the changing health care environment is urgently required.

  16. Travel-related vector-borne virus infections in Germany.

    PubMed

    Schwarz, T F; Jäger, G; Gilch, S; Pauli, C; Eisenhut, M; Nitschko, H; Hegenscheid, B

    1996-01-01

    Laboratory diagnosis of imported, vector-borne virus diseases during a 22-month-period in Munich, Germany, is summarized. IN 13/317 Germans returning from the Mediterranean with suspected sandfly fever, acute sandfly fever, serotype Toscana, was confirmed serologically: 84.6% of the infections were acquired in Italy. Of 249 German tourists with febrile disease returning from the tropics, acute infection with dengue virus was diagnosed serologically in 26 (10.4%): most infections were acquired in Thailand (57.7%). In a seroepidemiological study of 670 German aid workers who had spent two years in the tropics, 49 (7.3%) were positive for antibodies to dengue, 9 (1.3%) to chikungunya, and 1 (0.1%) to Sindbis virus. Of 17 Middle Eastern patients with suspected viral haemorrhagic fever, genomic Crimean-Congo haemorrhagic fever virus RNA was amplified in 4 (23.5%) by semi-nested reverse transcriptase polymerase chain reaction, and confirmed by molecular characterization of nucleic acid. With the increase in travel to and from endemic areas, imported vector-borne virus infections are increasingly important in Germany.

  17. [The demographic development in Germany : challenge and chances for urology].

    PubMed

    Schneider, A W; Fichtner, J

    2014-08-01

    Urology is affected by the demographic development in Germany more than any other medical discipline. Despite a relatively stable total population, by the year 2040 there will be an absolute and relevant increase in urological diseases caused only by the demographic development in the population. This is particularly true for the increase in oncological treatment just in the field of the discipline of urology. Even now the current numbers for tumor development in Germany (RKI 2014) in the urological oncology segment of all tumor diseases show an increasing trend with more than 23 %. This significant increase in performance is in contrast to the age development of the specialists in this discipline. In total but especially due to the significantly over-aged specialist medical profession in urology, this leads to a substantial bottleneck of specialists in the discipline of urology. This deficiency of personnel resources in urology is aggravated by the requirements of Generation Y for a well-adjusted work-life balance and the associated feminization of the medical profession. This requires intelligent strategies for.

  18. Seasonal fluctuations of head lice infestation in Germany.

    PubMed

    Bauer, Eline; Jahnke, Claudia; Feldmeier, Hermann

    2009-02-01

    Pediculosis capitis is one of the most frequent infectious diseases in childhood. If not diagnosed and treated rapidly, considerable clinical pathology may develop. The ubiquitous parasitic skin disease is characterized by a lack of sound epidemiological data, and factors which influence disease occurrence are still enigmatic. To investigate whether, in Germany, head lice infestation follows a seasonal pattern, we analyzed the weekly head lice consultations at the Health Department of Braunschweig City, Lower Saxony, for a period of 5 years, and compared the data with the units of pediculocides sold by two wholesalers to German pharmacies during a period of 2 and 3 years, respectively. The number of consultations did not show a clear seasonality, although there was a tendency of fewer consultations during school holidays, and an increase when schools opened again after Christmas, Easter, summer, and autumn holidays. In contrast, the number of packages of pediculocides sold followed a distinct seasonal rhythm with a maximum between calendar week 34 and 40, i.e., from mid September to end of October. In Germany, occurrence of pediculosis capitis varies according to the season of the year with a maximum in late summer and early autumn.

  19. Green energy products in the United Kingdom, Germany and Finland

    NASA Astrophysics Data System (ADS)

    Hast, Aira; McDermott, Liisa; Järvelä, Marja; Syri, Sanna

    2014-12-01

    In liberalized electricity markets, suppliers are offering several kinds of voluntary green electricity products marketed as environmentally friendly. This paper focuses on the development of these voluntary markets at household level in the UK, Germany and Finland. Since there are already existing renewable energy policies regulating and encouraging the use of renewable energy, it is important to consider whether voluntary products offer real additional benefits above these policies. Problems such as double counting or re-marketing hydropower produced in existing plants are identified. According to our study, the demand varies between countries: in Germany the number of green electricity customers has increased and is also higher than in the UK or Finland. Typically the average additional cost to consumer from buying green electricity product instead of standard electricity product is in the range of 0-5% in all studied countries, although the level of price premium depends on several factors like electricity consumption. Case study of Finland and literature show that the impacts of green energy are not solely environmental. Renewable energy can benefit local public policy.

  20. [Rare diseases. Funding programs in Germany and Europe].

    PubMed

    Wetterauer, Birgit; Schuster, R

    2008-05-01

    Rare diseases are defined by lifetime prevalence and are a medically heterogeneous group. Treatment options and the state of knowledge about these diseases are also very heterogeneous, as well as the respective needs for research. This article provides an overview on funding programs in Germany, further examples of countries within Europe and the European Commission, and a few examples of research networks. It is one of the goals of the article to show similarities and differences between the funding programs. The funding organizations of most countries and the European Commission (FP7) fund research on rare diseases with programs in which researchers define the contents in bottom up approaches. While, in general, basic science is well established, the translation of knowledge into clinical benefit for the patients is slow. Because of the low prevalence and geographic distribution of patients and researchers, research on rare diseases suffers from infrastructural deficits. While France, Germany, Italy and Spain have implemented research programs which are specific for rare diseases and aim to support networking of scarce resources and to stimulate interdisciplinary collaborations, other countries fund research on rare diseases within the context of general programs.

  1. Component conversion from pure Au nanorods to multiblock Ag-Au-Ag nanorods assisted by Pt nanoframe templates

    NASA Astrophysics Data System (ADS)

    Lee, Sangji; Jang, Hee-Jeong; Jang, Ho Young; Kim, Seong Kyu; Park, Sungho

    2016-06-01

    We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications.We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr03484e

  2. Desorption of Ag from Grain Boundaries in Ag Film on Br and H-Passivated Si(111) Surfaces

    SciTech Connect

    Roy, Anupam; Batabyal, R.; Mahato, J. C.; Dev, B. N.; Sundaravel, B.

    2011-07-15

    Growth of Ag film on Br- and H-passivated Si(111) surfaces was examined by Rutherford backscattering spectrometry (RBS), scanning electron microscopy (SEM) and photoemission electron microscopy (PEEM) techniques. The phenomenon of thermal grooving was observed after annealing at higher temperatures. Hierarchical desorption of Ag from the grain boundaries produce a fractal structure of Ag-depleted regions. Hierarchical desorption may be used for nanopatterning of the layer.

  3. Plasmon-assisted degradation of methylene blue with Ag/AgCl/montmorillonite nanocomposite under visible light

    NASA Astrophysics Data System (ADS)

    Sohrabnezhad, Sh.; Zanjanchi, M. A.; Razavi, M.

    2014-09-01

    Metal-semiconductor compounds, such as Ag/AgX (X = Cl, Br, I), enable visible light absorption and separation of photogenerated electron-hole through surface plasmon resonance (SPR) effect. However, the electron-hole generated and separated by light are vulnerable in Ag/AgX phase because of the occurrence of secondary recombined. In order to more effectively utilize the SPR photocatalytic effect, nanoparticles are located in a matrix. In this article, Ag/AgCl nanoparticles were synthesized in montmorillonite (MMT) matrix using dispersion method and light irradiation. The structure, composition and optical properties of such material were investigated by transmission electron microscopy (TEM), UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), X-ray diffraction (XRD) and FTIR. Powder X-ray diffraction showed intercalation of Ag/AgCl nanoparticles into the clay layers. The as-prepared plasmonic photocatalyst exhibited an enhanced and stable photoactivity for the degradation of methylene blue (MB) under visible light. The high activity was attributed to the surface plasmon resonance (SPR) exhibited by Ag nanoparticles on the surface of AgCl. The detection of reactive species by radical scavengers displays that rad O2- and rad OH- are the main reactive species for the degradation of MB under visible light irradiation. The studies showed that 20 min illumination under visible light can complete degradation of methylene blue (MB), and indicate a high stability of photocatalytic degradation. The mechanism of separation of the photo-generated electrons and holes at the Ag/AgCl-MMT nanocomposite was discussed.

  4. Studies of nosocomial outbreaks of hepatitis B in nursing homes in Germany suggest a major role of hepatitis B e antigen expression in disease severity and progression.

    PubMed

    Seiz, Pia L; Slanina, Heiko; Ziebuhr, John; Gerlich, Wolfram H; Glebe, Dieter; Schüttler, Christian G

    2015-10-01

    Hepatitis B virus (HBV) causes acute or chronic hepatitis B. Local outbreaks of HBV infections in skilled nursing facilities is a matter of growing concern in developed countries. Here, we investigated two outbreaks of hepatitis B that recently occurred in nursing homes in Germany. The outbreak at location A was associated with acute fulminant hepatitis with fatal outcome in several cases, while individuals infected at location B developed asymptomatic or mild hepatitis B. Sequence analysis of viruses involved in these outbreaks revealed different, but unique HBV strains for each location. Each of the strains produced high viremia of more than 10(9) virions/mL serum. We found that the mild course of hepatitis B at location B was caused by a circulating wild-type HBV genotype A2 strain, which is commonly found in Central Europe. Complete genome sequences of isolates obtained from infected patients revealed nearly 100% sequence identity at the nucleotide level as well as expression of HBV e protein (HBeAg), a known T cell tolerogen in the incubation or chronic phases of HBV infection. By contrast, the outbreak at location A was associated with an HBV genotype D2 variant that lacked HBeAg expression, suggesting that immunopathology and selection of specific HBV variants played a major role in the severe (or even fulminant) acute hepatitis observed at location A. Importantly, all patients were diagnosed with type 2 diabetes mellitus, a known risk factor for healthcare-associated transmission of HBV. The study leads us to suggest that, besides strict adherence to hygiene standards, additional efforts are required to reduce the risk of HBV transmission and fulminant disease progression in healthcare settings and nursing homes. In this context, a general screening for HBsAg and active hepatitis B vaccination should be considered for people living in nursing homes, especially for those with diagnosed diabetes or other predisposing factors for HBV transmission.

  5. METAL MEDIA FILTERS, AG-1 SECTION FI

    SciTech Connect

    Adamson, D.

    2012-05-23

    One application of metal media filters is in various nuclear air cleaning processes including applications for protecting workers, the public and the environment from hazardous and radioactive particles. To support this application the development of the ASME AG-1 FI Standard on Metal Media has been under way for more than ten years. Development of the proposed section has required resolving several difficult issues associated with operating conditions (media velocity, pressure drop, etc.), qualification testing, and quality acceptance testing. Performance characteristics of metal media are dramatically different than the glass fiber media with respect to parameters like differential pressures, operating temperatures, media strength, etc. These differences make existing data for a glass fiber media inadequate for qualifying a metal media filter for AG-1. In the past much work has been conducted on metal media filters at facilities such as Lawrence Livermore National Laboratory (LLNL) and Savannah River National Laboratory (SRNL) to qualify the media as High Efficiency Particulate Air (HEPA) Filters. Particle retention testing has been conducted at Oak Ridge Filter Test Facility and at Air Techniques International (ATI) to prove that the metal media meets or exceeds the 99.97% particle retention required for a HEPA Filter. Even with his testing, data was lacking to complete an AG-1 FI Standard on metal media. With funding secured by Mississippi State University (MSU) from National Nuclear Security Administration (NNSA), a research test stand is being designed and fabricated at MSU's Institute for Clean Energy Technology (ICET) Facility to obtain qualification data on metal media. This in turn will support required data needed for the FI Standard. The paper will discuss in detail how the test stand at MSU will obtain the necessary data to complete the FI Standard.

  6. Adsorbate-Induced Segregation in a PdAg Membrane Model System: Pd3Ag(1 1 1)

    SciTech Connect

    Svenum, I. H.; Herron, Jeffrey A.; Mavrikakis, Manos; Venvik, H. J.

    2012-10-15

    Thin PdAg alloy membranes with 20–25% Ag are being developed for hydrogen separation technology. Despite many investigations on such membranes as well as representative experimental and theoretical model systems, unresolved issues remain concerning the effect of the alloy surface structure and composition on adsorption and vice versa. Therefore, the interaction between hydrogen, carbon monoxide or oxygen with the surface of a PdAg model alloy was studied using periodic self-consistent density functional theory (DFT-GGA) calculations. In particular, the adsorption structure, coverage dependence and possible adsorption-induced segregation phenomena were addressed using Pd3Ag(1 1 1) model surfaces with varying degrees of surface segregation. In agreement with previous experimental and theoretical investigations, we predict Ag surface termination to be energetically favorable in vacuum. The segregation of Ag is then reversed upon adsorption of H, CO or O. For these adsorbates, the binding is strongest on Pd three-fold hollow sites, and hence complete Pd termination is favored at high coverage of H or CO, while 25% Ag may remain under oxygen because of the lower O-saturation coverage. CO adsorption provides a somewhat stronger driving force for Pd segregation when compared to H, and this may have implications with respect to permeation properties of PdAg alloy surfaces. Our predictions for high coverage are particularly relevant in underlining the importance of segregation phenomena to the hydrogen transport properties of thin PdAg alloy membranes.

  7. Growth and evaluation of AgGaS2 and AgGaSe2 for infrared nonlinear applications

    NASA Technical Reports Server (NTRS)

    Byer, R. L.; Feigelson, R. S.

    1986-01-01

    Significant advances were made in the growth technology of silver thiogallate (AgGaS2) and silver selenogallate (AgGaSe2). High efficiency harmonic generation of carbon dioxide laser radiation and tunable infrared parametric oscillation were demonstrated using these materials. Nonliner frequency conversion in the infrared was limited by the optical properties and the size of the available nonlinear materials. The development of these materials has reduced some of the limitations and generated wide interest. The continued development and application of AgGaS2 and AgGaSe2 now appears assured.

  8. Spherical and sheetlike Ag/AgCl nanostructures: interesting photocatalysts with unusual facet-dependent yet substrate-sensitive reactivity.

    PubMed

    Shen, Yunfan; Chen, Penglei; Xiao, Dan; Chen, Chuncheng; Zhu, Mingshan; Li, Tiesheng; Ma, Wangong; Liu, Minghua

    2015-01-13

    We herein report that spherical and sheetlike Ag/AgCl nanostructures could be controllably synthesized by means of chemical reactions between AgNO3 and cetyltrimethylammonium chloride (CTAC) surfactant. In this synthesis system, AgNO3 works as the silver source, while CTAC serves not only as the chlorine source but also as the directing reagent for a controllable nanofabrication. We show that compared to the spherical Ag/AgCl nanostructures, the sheetlike counterparts, wherein the AgCl nanospecies are predominantly enriched with {111} facets, could exhibit superior catalytic performances toward the photodegradation of methyl orange. Interestingly, we further demonstrate that when 4-chlorophenol or phenol is used as the substrate, the sheetlike Ag/AgCl nanostructures exhibit inferior catalytic reactivity, whereas the spherical counterparts display superior catalytic performances comparatively. Our results disclose new insights on the facet-dependent catalytic performances with regard to a facet-selective but substrate-sensitive photoinduced electron-hole separation.

  9. In situ growth of Ag nanoparticles on α-Ag2WO4 under electron irradiation: probing the physical principles

    NASA Astrophysics Data System (ADS)

    San-Miguel, Miguel A.; da Silva, Edison Z.; Zannetti, Sonia M.; Cilense, Mario; Fabbro, Maria T.; Gracia, Lourdes; Andrés, Juan; Longo, Elson

    2016-06-01

    Exploiting the plasmonic behavior of Ag nanoparticles grown on α-Ag2WO4 is a widely employed strategy to produce efficient photocatalysts, ozone sensors, and bactericides. However, a description of the atomic and electronic structure of the semiconductor sites irradiated by electrons is still not available. Such a description is of great importance to understand the mechanisms underlying these physical processes and to improve the design of silver nanoparticles to enhance their activities. Motivated by this, we studied the growth of silver nanoparticles to investigate this novel class of phenomena using both transmission electron microscopy and field emission scanning electron microscopy. A theoretical framework based on density functional theory calculations (DFT), together with experimental analysis and measurements, were developed to examine the changes in the local geometrical and electronic structure of the materials. The physical principles for the formation of Ag nanoparticles on α-Ag2WO4 by electron beam irradiation are described. Quantum mechanical calculations based on DFT show that the (001) of α-Ag2WO4 displays Ag atoms with different coordination numbers. Some of them are able to diffuse out of the surface with a very low energy barrier (less than 0.1 eV), thus, initiating the growth of metallic Ag nanostructures and leaving Ag vacancies in the bulk material. These processes increase the structural disorder of α-Ag2WO4 as well as its electrical resistance as observed in the experimental measurements.

  10. First principle study of 0.75AgI:0.25AgCl: A density functional approach

    NASA Astrophysics Data System (ADS)

    Rao, B. Keshav; Verma, Mohan L.

    2016-09-01

    The first principles calculations based on norm-conserving pseudo potentials and density functional theory are performed for zincblende structured new host 0.75AgI:0.25AgCl. For comparison point of view zincblende structured β-AgI is considered. The structural analysis provides the higher cationic concentration in new host. Density of state analysis explains a weak p-d hybridization in β-AgI and strong in new host. There is decrease in forbidden energy band gap by 0.05 eV and hence large ionic concentration and conductivity is found in new host.

  11. Read-only memory disk with AgOx and AgInSbTe superresolution mask layer

    NASA Astrophysics Data System (ADS)

    Zhang, Feng; Wang, Yang; Xu, Wendong; Gan, Fuxi

    2005-06-01

    Two novel read-only memory (ROM) disks, one with an AgOx mask layer and the other with an AgInSbTe mask layer, are proposed and studied. The AgOx and the AgInSbTe films sputtered on the premastered substrates with pit depths of 50 nm and pit lengths (space) of 380 nm are studied by atomic force microscopy. Disk readout measurement is carried out using a dynamic setup with a laser wavelength of 632.8 nm and an object lens numerical aperture (NA) of 0.40. Results show that the superresolution effect happens only at a suitable oxygen flow ratio for the AgOx ROM disk. The best superresolution readout effect is achieved at an oxygen flow ratio of 0.5 with the smoothest film surface. Compared with the AgOx ROM disk, the AgInSbTe ROM disk has a much smoother film surface and better superresolution effect. A carrier-to-noise ratio (CNR) of above 40 dB can be obtained at an appropriate readout power and readout velocity. The readout CNR of both the AgOx and AgInSbTe ROM disks have a nonlinear dependence on the readout power. The superresolution readout mechanisms for these ROM disks are analyzed and compared as well.

  12. Micro-PIXE study of Ag in digestive glands of a nano-Ag fed arthropod ( Porcellio scaber, Isopoda, Crustacea)

    NASA Astrophysics Data System (ADS)

    Tkalec, Živa Pipan; Drobne, Damjana; Vogel-Mikuš, Katarina; Pongrac, Paula; Regvar, Marjana; Štrus, Jasna; Pelicon, Primož; Vavpetič, Primož; Grlj, Nataša; Remškar, Maja

    2011-10-01

    Micro-proton induced X-ray emission (micro-PIXE) method was applied to study the micro-localization of silver (Ag) in digestive glands of a terrestrial arthropod (Porcellio scaber) after feeding on silver nanoparticles (nano-Ag) dosed food. The aim of our work was to assess whether feeding on nano-Ag results in the assimilation of silver (Ag) in digestive gland cells. To study micro-localization and elemental distribution of Ag, the animals were fed on food dosed with nanoparticles for 14 days under controlled laboratory conditions. At the end of the feeding exposure, the animals were dissected and digestive glands prepared for micro-PIXE analyses and TEM investigation. The results obtained by micro-PIXE documented high amounts of Ag inside S-cells of the digestive gland epithelium; however, TEM investigation did not show particle aggregates inside digestive gland cells. Also no adverse effect on feeding behavior was recorded what is a measure of toxic effects. We explain the presence of Ag inside the cells as a result of the assimilation of dissoluted Ag ions from ingested nano-Ag particles. Assimilation of excessive amounts of ingested metal ions in S-cells is a well known metal detoxification mechanism in isopods. We discuss the advantages of using micro-PIXE for the micro-localization of elements in biological tissue in studies of interactions between nanoparticles and biological systems.

  13. In situ growth of Ag nanoparticles on α-Ag2WO4 under electron irradiation: probing the physical principles.

    PubMed

    San-Miguel, Miguel A; da Silva, Edison Z; Zannetti, Sonia M; Cilense, Mario; Fabbro, Maria T; Gracia, Lourdes; Andrés, Juan; Longo, Elson

    2016-06-01

    Exploiting the plasmonic behavior of Ag nanoparticles grown on α-Ag2WO4 is a widely employed strategy to produce efficient photocatalysts, ozone sensors, and bactericides. However, a description of the atomic and electronic structure of the semiconductor sites irradiated by electrons is still not available. Such a description is of great importance to understand the mechanisms underlying these physical processes and to improve the design of silver nanoparticles to enhance their activities. Motivated by this, we studied the growth of silver nanoparticles to investigate this novel class of phenomena using both transmission electron microscopy and field emission scanning electron microscopy. A theoretical framework based on density functional theory calculations (DFT), together with experimental analysis and measurements, were developed to examine the changes in the local geometrical and electronic structure of the materials. The physical principles for the formation of Ag nanoparticles on α-Ag2WO4 by electron beam irradiation are described. Quantum mechanical calculations based on DFT show that the (001) of α-Ag2WO4 displays Ag atoms with different coordination numbers. Some of them are able to diffuse out of the surface with a very low energy barrier (less than 0.1 eV), thus, initiating the growth of metallic Ag nanostructures and leaving Ag vacancies in the bulk material. These processes increase the structural disorder of α-Ag2WO4 as well as its electrical resistance as observed in the experimental measurements. PMID:27114472

  14. Modelling of the AGS using Zgoubi - Status

    SciTech Connect

    Meot F.; Ahrens, L.; Dutheil, Y.; Glenn, J.; Huang, H.; Roser, T.; Schoefer, V.; Tsoupas, N.

    2012-05-20

    This paper summarizes the progress achieved so far, and discusses various outcomes, regarding the development of a model of the Alternating Gradient Synchrotron at the RHIC collider. The model, based on stepwise ray-tracing methods, includes beam and polarization dynamics. This is an on-going work, and a follow-on of code developments and particle and spin dynamics simulations that have been subject to earlier publications at IPAC and PAC [1, 2, 3]. A companion paper [4] gives additional informations, regarding the use of the measured magnetic field maps of the AGS main magnets.

  15. AG Dra monitoring requested for multiwavelength campaign

    NASA Astrophysics Data System (ADS)

    Waagen, Elizabeth O.

    2013-06-01

    Dr. Andrea Dupree (Harvard-Smithsonian Center for Astrophysics) has requested AAVSO monitoring (visual and photometric) of the symbiotic variable AG Draconis from June 20 through at least September 2013 for correlation with upcoming Chandra x-ray and HST ultraviolet observations. The purpose of their observations is to determine the dynamics of the gas and the temperatures and densities in various parts of this complex system. Finder charts with sequences may be created using the AAVSO Variable Star Plotter (http://www.aavso.org/vsp). Observations should be submitted to the AAVSO International Database.

  16. Bunched beam echos in the AGS

    SciTech Connect

    Kewisch, J.; Brennan, J.M.

    1998-08-01

    Beam echos have been measured at FNAL and CERN in coasting beams. A coherent oscillation introduced by a short RF burst decoheres quickly, but a coherent echo of this oscillation can be observed if the decohered oscillation is bounced off a second RF burst. In this report the authors describe first longitudinal echo measurements of bunched beam in the AGS accelerator. They applied a method proposed by Stupakov for transverse beam echos, where the initial oscillation is produced by a dipole kick and is bounced off a quadrupole kick. In the longitudinal case the dipole and quadrupole kicks are produced by cavities operating at a 90 and 0{degree} phase shift, respectively.

  17. Structure Determination of an Ag(I) -Mediated Cytosine-Cytosine Base Pair within DNA Duplex in Solution with (1) H/(15) N/(109) Ag NMR Spectroscopy.

    PubMed

    Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Šebera, Jakub; Nakashima, Katsuyuki; Kondo, Jiro; Yamanaka, Daichi; Kondo, Yoshinori; Okamoto, Itaru; Ono, Akira; Sychrovský, Vladimír; Kojima, Chojiro; Tanaka, Yoshiyuki

    2016-09-01

    The structure of an Ag(I) -mediated cytosine-cytosine base pair, C-Ag(I) -C, was determined with NMR spectroscopy in solution. The observation of 1-bond (15) N-(109) Ag J-coupling ((1) J((15) N,(109) Ag): 83 and 84 Hz) recorded within the C-Ag(I) -C base pair evidenced the N3-Ag(I) -N3 linkage in C-Ag(I) -C. The triplet resonances of the N4 atoms in C-Ag(I) -C demonstrated that each exocyclic N4 atom exists as an amino group (-NH2 ), and any isomerization and/or N4-Ag(I) bonding can be excluded. The 3D structure of Ag(I) -DNA complex determined with NOEs was classified as a B-form conformation with a notable propeller twist of C-Ag(I) -C (-18.3±3.0°). The (109) Ag NMR chemical shift of C-Ag(I) -C was recorded for cytidine/Ag(I) complex (δ((109) Ag): 442 ppm) to completed full NMR characterization of the metal linkage. The structural interpretation of NMR data with quantum mechanical calculations corroborated the structure of the C-Ag(I) -C base pair. PMID:27505707

  18. Structure Determination of an Ag(I) -Mediated Cytosine-Cytosine Base Pair within DNA Duplex in Solution with (1) H/(15) N/(109) Ag NMR Spectroscopy.

    PubMed

    Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Šebera, Jakub; Nakashima, Katsuyuki; Kondo, Jiro; Yamanaka, Daichi; Kondo, Yoshinori; Okamoto, Itaru; Ono, Akira; Sychrovský, Vladimír; Kojima, Chojiro; Tanaka, Yoshiyuki

    2016-09-01

    The structure of an Ag(I) -mediated cytosine-cytosine base pair, C-Ag(I) -C, was determined with NMR spectroscopy in solution. The observation of 1-bond (15) N-(109) Ag J-coupling ((1) J((15) N,(109) Ag): 83 and 84 Hz) recorded within the C-Ag(I) -C base pair evidenced the N3-Ag(I) -N3 linkage in C-Ag(I) -C. The triplet resonances of the N4 atoms in C-Ag(I) -C demonstrated that each exocyclic N4 atom exists as an amino group (-NH2 ), and any isomerization and/or N4-Ag(I) bonding can be excluded. The 3D structure of Ag(I) -DNA complex determined with NOEs was classified as a B-form conformation with a notable propeller twist of C-Ag(I) -C (-18.3±3.0°). The (109) Ag NMR chemical shift of C-Ag(I) -C was recorded for cytidine/Ag(I) complex (δ((109) Ag): 442 ppm) to completed full NMR characterization of the metal linkage. The structural interpretation of NMR data with quantum mechanical calculations corroborated the structure of the C-Ag(I) -C base pair.

  19. Fluorescence switch for silver ion detection utilizing dimerization of DNA-Ag nanoclusters.

    PubMed

    Lee, Jihyun; Park, Juhee; Hee Lee, Hong; Park, Hansoo; Kim, Hugh I; Kim, Won Jong

    2015-06-15

    A fluorescence switch that consists of DNA-templated silver nanoclusters (DNA-AgNCs) triggered by silver ion (Ag(+)) is developed to detect Ag(+). The mechanism of the fluorescence switching of DNA-AgNCs is investigated by fluorescence spectroscopy, circular dichroism spectroscopy, DNA hybridization assay and mass spectrometry. Ag(+) induces a dimeric structure of Cyt12-AgNCs by forming a bridge between two Cyt12-AgNCs, where Cyt12 is cytosine 12-mer; this dimer formation causes the fluorescence change of Cyt12-AgNCs from red to green. Using this Ag(+)-triggered fluorescence switch, we successfully detected Ag(+) at concentrations as low as 10nM. Furthermore, we quantitatively detected the Ag(+) in the Silmazin(®), which is dermatological burn ointment having silver sulfadiazine. Ag(+) detection using this fluorescence switch has high selectivity and sensitivity, and short response time, and can be used successfully even in the presence of other metal ions.

  20. The role of reduction extent of graphene oxide in the photocatalytic performance of Ag/AgX (X = Cl, Br)/rGO composites and the pseudo-second-order kinetics reaction nature of the Ag/AgBr system.

    PubMed

    Gao, Weiyin; Ran, Chenxin; Wang, Minqiang; Li, Le; Sun, Zhongwang; Yao, Xi

    2016-07-21

    Although reduced graphene oxide (rGO)-based photocatalyst composites have been intensively developed during the past few years, the influence of reduction extent of rGO on the photocatalytic performance of the rGO-based composite has virtually not been investigated due to some technical limitations, such as the poor water dispersibility of rGO and low reduction selectivity of the hydrothermal method, which make it difficult to control the reduction extent of rGO in these composites. Herein, we used a facile room-temperature method to synthesize Ag/AgX (X = Cl, Br)/rGO photocatalyst composites as a model to study the effect of reduction extent of rGO on the photocatalytic performance of the photocatalyst. It was found that the photocatalytic activities of both Ag/AgCl/PrGO and Ag/AgBr/PrGO systems had an optimized threshold of the reduction extent of photoreduced GO (PrGO). More importantly, due to the different conductive band values of AgCl and AgBr, the optimized thresholds in the two systems were at different PrGO reduction extents, based on which we proposed that the favorable energy band matching between AgX and PrGO in the two systems played a crucial role in obtaining high photocatalysis performance. Besides, the photocatalytic reaction of the Ag/AgBr based system was confirmed to be a pseudo-second-order kinetics reaction rather than pseudo-first-order kinetics reaction. The new insights presented in this work provided useful information on the design and development of a more sophisticated photocatalyst, and can also be applied to many other applications. PMID:27332751