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Sample records for ag nano wires

  1. Plasmonic ultra-broadband polarizers based on Ag nano wire-slit arrays

    NASA Astrophysics Data System (ADS)

    Han, Chunrui; Tam, Wing Yim

    2015-02-01

    We propose ultra-broadband reflective and absorptive polarizers in the visible range using multi-scaled Ag nano wire-slit arrays. The nano arrays can be tuned from reflective to absorptive by incorporating Ag wires/strips with different lengths/widths. The ultra-broadband nature of the absorptive array, with averaged absorption as high as ˜80%, is due to collective excitations of plasmonic resonances in the Ag wires/strips with different length scales. The nano arrays are realized experimentally by using a simple two-times shadowing vapor deposition method. They exhibit broadband transmission difference, in good agreement with simulations. Our multi-scaled nano array design has potential applications as broadband linear polarizers and anti-reflective materials in both optics and photovoltaics.

  2. Thermal Behavior of Ag Micro/Nano Wires Formed by Low-Temperature Sintering of Ag Nanoparticles

    NASA Astrophysics Data System (ADS)

    Wang, Wen; Zhong, Yinghui; Li, Dongxue; Wang, Pan; Cai, Yuwei; Duan, Zhiyong

    2015-12-01

    Ag nanoparticles of 30 nm size were deposited onto a Si substrate to form Ag microwires. The nanoparticles were transformed into continuous Ag wires with low-temperature heat treatment at temperatures not higher than 200°C. The morphology, electrical properties, and interface of the sintered Ag nanoparticle wires are described. It is shown that the neck between the nanoparticles begins to form at 150°C, and obvious metallization was found at 170°C. The changes of the crystal structure of the Ag wires at different sintering temperatures were analyzed by x-ray diffractometry. The grain boundary resistance decreased as the crystal grain size increased above 130 nm. The corresponding resistivity of the microstructure is close to that of the bulk. Through the comparison between the Mayadas-Shatzkes's model and experimental data, the range of the grain boundary reflection coefficient C at different temperatures is obtained. This research lays the foundation for the study of nanoimprint lithography with a pseudoplastic metal nanoparticle fluid.

  3. High critical current density Bi2Sr2CaCu2O x /Ag wire containing oxide precursor synthesized from nano-oxides

    NASA Astrophysics Data System (ADS)

    Zhang, Yun; Johnson, Stephen; Naderi, Golsa; Chaubal, Manasi; Hunt, Andrew; Schwartz, Justin

    2016-09-01

    Bi2Sr2CaCu2O x (Bi2212)/Ag-alloy wires are manufactured via the oxide-powder-in-tube route by filling Ag/Ag-alloy tubes with Bi2212 oxide precursor, deforming into wire, restacking and heat treating using partial-melt processing (PMP). Recent studies propose several requirements on precursor properties, including stoichiometry, chemical homogeneity, carbon content and phase purity. Here, nanosize oxides produced by nGimat’s proprietary NanoSpray CombustionTM process are used as starting materials to synthesize Bi2212 oxide precursors via solid-state calcination. Oxide powders for wire fill (precursor powder) with precisely controlled stoichiometry and chemical homogeneity containing over 99 vol% of single Bi2212-phase are synthesized. Alkaline-earth cuprate are found to be the only impurity phase in the precursor powders. Phase transformation, carbon release and grain growth during calcination are studied through a series of quench studies. Effects of particle size, surface area, stoichiometry, chemical homogeneity and microstructures of the starting materials on Bi2212 formation and wire transport properties are discussed. Small particle size, high surface area and short diffusion length of the starting materials result in a rapid and homogeneous phase transformation to Bi2212, along with an early and rapid carbon release. The residual carbon in the precursor powder is between 50 and 90 ppm. The strong dependence of transport J c on precursor stoichiometry indicates that compositional variations within precursor powders should be less than 1.5 mol%. Two Bi-rich and Ca-deficient stoichiometries give higher wire transport critical current density, with the highest being 2520 A mm‑2 (4.2 K, 5 T) after 1 bar PMP and 4560 A mm‑2 (4.2 K, 5 T) after 100 bar overpressure (OP) processing. The low residual carbon content results in smaller and fewer voids within an OP-processed wire filament. Bi-rich and Ca-deficient stoichiometries and small compositional variations

  4. A FLYING WIRE SYSTEM IN THE AGS.

    SciTech Connect

    HUANG,H.; BUXTON,W.; MAHLER,G.; MARUSIC,A.; ROSER,T.; SMITH,G.; SYPHERS,M.; WILLIAMS,N.; WITKOVER,R.

    1999-03-29

    As the AGS prepares to serve as the injector for RHIC, monitoring and control of the beam transverse emittance become a major and important topic. Before the installation of the flying wire system, the emittance was measured with ionization profile monitors in the AGS, which require correction for space charge effects. It is desirable to have a second means of measuring profile that is less depend on intensity. A flying wire system has been installed in the AGS recently to perform this task. This paper discusses the hardware and software setup and the capabilities of the system.

  5. 'Chrysanthemum petal' arrangements of silver nano wires.

    PubMed

    Cui, Hui-Wang; Jiu, Jin-Ting; Sugahara, Tohru; Nagao, Shijo; Suganuma, Katsuaki; Uchida, Hiroshi

    2014-12-01

    Highly ordered 'Chrysanthemum petal' arrangements of silver nano wires were fabricated in a biodegradable polymer of polyvinyl alcohol using a simple one-step blending method without any template. The degree of the arrangement increased with the decreasing content of polyvinyl alcohol. The mechanism for the formation of these 'Chrysanthemum petal' arrangements was discussed specifically. These 'Chrysanthemum petal' arrangements will be helpful to increase the electrical conductivity of silver nano wires films. PMID:25397618

  6. Microstructural aspects of Cu-Ag produced by the Taylor wire method

    SciTech Connect

    Han, K.; Embury, J.D.; Petrovic, J.J.; Weatherly, G.C.

    1998-08-10

    The microstructure and phase transformations of Cu-16 at.% Ag fabricated by the Taylor wire technique of drawing molten metals in a glass tube have been studied. As the diameter of the wire becomes smaller and the cooling rate increases, the scale of the microstructure is refined. Nano-crystals of supersaturated solid solution with a 10 nm grain size were observed when the wire diameter was less than 10{micro}m. When the diameter of the wire was larger than 20 {micro}m, proeutectic Cu and the Cu + Ag eutectic were found. In the region where the Cu-Ag eutectic was formed, a (111) twin orientation relationship was found between Cu and Ag.

  7. A multi-wire beam profile monitor in the AGS

    SciTech Connect

    Huang, H.; Buxton, W.; Castillo, V.; Glenn, J.W.

    1997-07-01

    A multi-wire beam profile monitor which can be used to directly monitor and control the optical matching between the Booster and AGS rings has been installed and tested in the AGS. Placement of a multi-wire monitor directly in the AGS provides profile measurements taken upon injection and the first two or more revolutions of the beam. The data from such measurements can be used to determine the optical properties of the beam transport line leading into the AGS.

  8. Plasmon hybridization in parallel nano-wire systems

    SciTech Connect

    Moradi, Afshin

    2011-06-15

    We apply the plasmon hybridization method to a double-nano-wire system, providing a simple and intuitive description of the plasmon excitations in the system. We apply the two-center cylindrical coordinate system for mathematical convenience and find an explicit form of the surface plasmon oscillations, in terms of the interaction between the bare plasmon modes of the individual surfaces of the nano-wires. We present numerical results to display how the plasmon excitations of the system depend on nano-wire separation when there is no angular momentum transfer, i.e., when m = 0.

  9. ‘Chrysanthemum petal’ arrangements of silver nano wires

    NASA Astrophysics Data System (ADS)

    Cui, Hui-Wang; Jiu, Jin-Ting; Sugahara, Tohru; Nagao, Shijo; Suganuma, Katsuaki; Uchida, Hiroshi

    2014-12-01

    Highly ordered ‘Chrysanthemum petal’ arrangements of silver nano wires were fabricated in a biodegradable polymer of polyvinyl alcohol using a simple one-step blending method without any template. The degree of the arrangement increased with the decreasing content of polyvinyl alcohol. The mechanism for the formation of these ‘Chrysanthemum petal’ arrangements was discussed specifically. These ‘Chrysanthemum petal’ arrangements will be helpful to increase the electrical conductivity of silver nano wires films.

  10. Nanoparticle Ag-enhanced textured-powder Bi-2212/Ag wire technology

    NASA Astrophysics Data System (ADS)

    Kellams, J. N.; McIntyre, P.; Pogue, N.; Vandergrifft, J.

    2015-12-01

    A new approach to the preparation of cores for Bi-2212/Ag wire is being developed. Nanoparticle Ag is homogeneously dispersed in Bi-2212 fine powder, and the mixture is uniaxially compressed to form highly textured, cold-sintered core rods. The rods can be assembled in a silver matrix, drawn to form multifilament wire, and restacked and drawn to form multifilament wire. Preliminary studies using tablet geometry demonstrate that a nonmelt heat treatment produces densification, grain growth, intergrowth among grains, and macroscopic current transport. The status of the development is reported.

  11. Capacitive deionization of seawater effected by nano Ag and Ag@C on graphene.

    PubMed

    Cai, P-F; Su, C-J; Chang, W-T; Chang, F-C; Peng, C-Y; Sun, I-W; Wei, Y-L; Jou, C-J; Wang, H Paul

    2014-08-30

    Drinking water shortage has become worse in recent decades. A new capacitive deionization (CDI) method for increasing water supplies through the effective desalination of seawater has been developed. Silver as nano Ag and Ag@C which was prepared by carbonization of the Ag(+)-β-cyclodextrin complex at 573 K for 30 min can add the antimicrobial function into the CDI process. The Ag@C and Ag nanoparticles dispersed on reduced graphene oxide (Ag@C/rGO and nano Ag/rGO) were used as the CDI electrodes. The nano Ag/rGO and Ag@C/rGO electrodes can reduce the charging resistant, and enhance the electrosorption capability. Better CDI efficiencies with the nano Ag/rGO and Ag@C/rGO electrodes can therefore be obtained. When reversed the voltage, the electrodes can be recovered up to 90% within 5 min. This work presents the feasibility for the nano Ag and Ag@C on rGO electrodes applied in CDI process to produce drinking water from seawater or saline water. PMID:24928455

  12. Ferroelectric and photocatalytic behavior of bismuth ferrite nano wire

    NASA Astrophysics Data System (ADS)

    William, R. V.; Marikani, A.; Madhavan, D.

    2016-05-01

    Multiferroic bismuth ferrite nanowires are prepared through polyol method with an average diameter of 35 nm with a narrow size distribution. The band gap was determined to be 2.10 eV, indicating their potential application as visible-light-response photo catalyst. The magnificent photocatalytic behaviors of BiFeO3 nanowires are understood from the methyl violet degradation under visible light irradiation. Moreover, the nano-wire takes only a lesser time for the diffusion of electron-hole pair from the surface of the sample. Further the BiFeO3 nano-wire was characterized using XRD, SEM, and U-V. The ferroelectric studies of BiFeO3 nano-wire show a frequency dependent property and maximum coercivity of 2.7 V/cm were achieved with a remanent polarization at 0.5 µC/cm2 at the frequency 4 kHz. The coercivity of BiFeO3 nano wire changes with variation of frequency from 1 kHz to 4 kHz.

  13. Magnetization reversal modes in fourfold Co nano-wire systems

    NASA Astrophysics Data System (ADS)

    Blachowicz, T.; Ehrmann, A.

    2015-09-01

    Magnetic nano-wire systems are, as well as other patterned magnetic structures, of special interest for novel applications, such as magnetic storage media. In these systems, the coupling between neighbouring magnetic units is most important for the magnetization reversal process of the complete system, leading to a variety of magnetization reversal mechanisms. This article examines the influence of the magnetic material on hysteresis loop shape, coercive field, and magnetization reversal modes. While iron nano-wire systems exhibit flat or one-step hysteresis loops, systems consisting of cobalt nano-wires show hysteresis loops with several longitudinal steps and transverse peaks, correlated to a rich spectrum of magnetization reversal mechanisms. We show that changing the material parameters while the system geometry stays identical can lead to completely different hysteresis loops and reversal modes. Thus, especially for finding magnetic nano-systems which can be used as quaternary or even higher-order storage devices, it is rational to test several materials for the planned systems. Apparently, new materials may lead to novel and unexpected behaviour - and can thus result in novel functionalities.

  14. Comparative analysis of opto-electronic performance of aluminium and silver nano-porous and nano-wired layers.

    PubMed

    Marus, Mikita; Hubarevich, Aliaksandr; Wang, Hong; Stsiapanau, Andrei; Smirnov, Aliaksandr; Sun, Xiao Wei; Fan, Weijun

    2015-10-01

    The comparison of optical and electronic properties between squarely and hexagonally arranged nano-porous layers and uniformly arranged nano-wired layers of aluminium and silver was presented. The nano-wired configuration exhibit 20 and 10% higher average transmittance in visible wavelength range in comparison to square and hexagonal nano-porous designs, respectively. The insignificant difference of the transmittance for aluminium and silver nano-porous and nano-wired layers is observed, when interpore/interwire distance is larger than wavelengths of incoming light. This difference becomes considerable at the interpore/interwire distance less than wavelengths of incoming light: silver nano-porous and nano-wired layers possess up to 27% higher transmittance in comparison to aluminium layers. PMID:26480190

  15. Effect of Annealing Twins on Electromigration in Ag-8Au-3Pd Bonding Wires

    NASA Astrophysics Data System (ADS)

    Chuang, Tung-Han; Wang, Hsi-Ching; Chuang, Chien-Hsun; Lee, Jun-Der; Tsai, Hsing-Hua

    2013-03-01

    An innovative Ag-8Au-3Pd bonding wire with a high twin density has been produced. The grain size of this annealing-twinned wire changes moderately during electrical stressing, unlike that of the conventional grained wire, which increases drastically and even leads to a bamboo structure. In addition, the durability against electromigration of the annealing-twinned Ag-8Au-3Pd alloy wire is higher than that of the conventional grained wire. This higher durability can be ascribed to the surface reconstruction of a stepwise morphology and slow grain growth resulting from the abundance of annealing twins in this wire.

  16. Mechanism of Electromigration in Ag-Alloy Bonding Wires with Different Pd and Au Content

    NASA Astrophysics Data System (ADS)

    Chuang, Tung-Han; Lin, Hsin-Jung; Wang, Hsi-Ching; Chuang, Chien-Hsun; Tsai, Chih-Hsin

    2015-02-01

    The mechanism of electromigration in Ag-alloy wires containing different amounts of Pd and Au has been studied. Thinning and thickening accompanying grain growth were observed in worn bonding wire after current stress. The mean time-to-failure of bonding wires stressed with different current densities is highly dependent on their electrical resistivity, and wire temperature increases during current stress, owing to the Joule effect. An indirect method is proposed for in situ assessment of the temperatures of these fine wires under current stress. A mode of failure of these bonding wires was deduced by kinetic analysis. This mode can be correlated with atomic diffusion in the wire.

  17. Silicon quantum wires on Ag(1 1 0): Fermi surface and quantum well states

    NASA Astrophysics Data System (ADS)

    Valbuena, M. A.; Avila, J.; Dávila, M. E.; Leandri, C.; Aufray, B.; Le Lay, G.; Asensio, M. C.

    2007-10-01

    One-dimensional Si quantum wires have been grown on silver single crystals upon deposition of ˜0.25 monolayer of Si on Ag(1 1 0) surfaces. Scanning tunneling microscopy (STM) clearly shows parallel 1D Si chains along the [-1 1 0] Ag crystallographic direction. Low Energy Electron Diffraction (LEED) confirms the massively parallel assembly of these selforganized Nanowires (NWs). We have characterized these nano-objects by measuring the dispersion of the NWs valence band at room temperature using Angle-Resolved PhotoEmission Spectroscopy (ARPES). Also, the Fermi Surface (FS) of the Ag(1 1 0) substrate has been mapped before and after the silicon deposition, trying to put in evidence the metallic or semiconductor character of the NWs silicon's states close to the Fermi level. Our results show the existence of well-defined quantum states associated to the silicon super-structure. Both LEED and ARUPS results confirm that the NWs have typical 1D features, however their metallic or semiconductor character could not be confirmed.

  18. Nano-/micro metallic wire synthesis on Si substrate and their characterization

    SciTech Connect

    Kaur, Jaskiran Kaur, Harmanmeet Singh, Surinder; Kanjilal, Dinakar; Chakarvarti, Shiv Kumar

    2014-04-24

    Nano-/micro wires of copper are grown on semiconducting Si substrate using the template method. It involves the irradiation of 8 um thick polymeric layer coated on Si with150 MeV Ni ion beam at a fluence of 2E8. Later, by using the simple technique of electrodeposition, copper nano-/micro wires were grown via template synthesis. Synthesized wires were morphologically characterized using SEM and electrical characterization was carried out by finding I-V plot.

  19. RRR and thermal conductivity of Ag and Ag-0.2 wt.%Mg alloy in Ag/Bi-2212 wires

    NASA Astrophysics Data System (ADS)

    Li, P.; Ye, L.; Jiang, J.; Shen, T.

    2015-12-01

    Residual resistivity ratio (RRR) and thermal conductivity of metal matrix in metal/superconductor composite wires are important parameters for designing superconducting magnets. However, the resistivity of silver in reacted Ag/Bi-2212 wires has yet to be determined over temperature range from 4.2 K to 80 K because Bi-2212 filaments have a critical transition temperature Tc of ∼ 80 K, and because it is unknown whether the RRR of Ag/Bi-2212 degrades with Cu diffusing from Bi-2212 filaments into silver sheathes at elevated temperatures and to what degree it varies with heat treatment. We measured the resistivity of stand-alone Ag and AgMg (Ag-0.2 wt.% Mg) wires as well as the resistivity of Ag and Ag-0.2 wt.% Mg in Ag/Bi- 2212 round wires reacted in 1 bar oxygen at 890 °C for 1, 8, 24 and 48 hours and quickly cooled to room temperature. The heat treatment was designed to reduce the critical current Ic of Bi- 2212 wires to nearly zero while allowing Cu loss to fully manifest itself. We determined that pure silver exhibits a RRR of ∼ 220 while the oxide-dispersion strengthened Ag-Mg exhibits a RRR of ∼ 5 in stand-alone samples. A surprising result is that the RRR of silver in the composite round wires doesn't degrade with extended time at 890 °C for up to 48 hours. This surprising result may be explained by our observation that the Cu that diffuses into silver tends to form Cu2O precipitates in oxidizing atmosphere, instead of forming Ag-Cu solution alloy. We also measured the thermal conductivity and the magneto-resistivity of pure Ag and Ag-0.2 wt. % Mg from 4.2 K to 300 K in magnetic fields up to 14.8 T and summarized them using a Kohler plot.

  20. Study on thermo-mechanical treatment in fabrication of Bi2212/Ag HTS wire

    NASA Astrophysics Data System (ADS)

    Kim, S. C.; Ha, D. W.; Oh, S. S.; Han, I. Y.; Bruzek, C. E.; Oh, J. G.; Sohn, H. S.

    2007-07-01

    Round shape Bi2212/Ag wire is isotropic, while Bi2212/Ag or Bi2223/Ag tape has anisotropic characteristics or performances with respect to magnetic field orientation, which is the only HTS wires that can be used to make Rutherford cable to transport high current. In this work, two different Bi2212/Ag round wires with different Ag ratio were fabricated using powder-in-tube method and processing factor at each step was investigated. Double stacked 385 (55 × 7) filamentary wires of various final diameter were heat treated at different melting temperatures. Microstructure after pre-annealing was investigated. Wires which have Ag ratio (silver area/superconductor area) of 0.3 and 0.42 after powder filling show similar critical current density. Higher Ag ratio wire at 0.74 mm diameter heat treated at melting temperature 890 °C shows critical current density of 2750 A/mm 2 at 4.2 K, 0 T.

  1. Glycothermal Growth of Silver Core/TiO2 Shell Nano-Wires on FTO Substrate.

    PubMed

    Song, Duck-Hyun; Hirato, Tetsuji

    2015-01-01

    Silver core/TiO2 shell nano-wires have been successfully prepared on fluorine doped tin oxide coated glass substrate via a glycothermal process assisted by a photochemical process. The morphology, diameter, length, and density of synthesized core/shell nano-wires could be varied by photochemical reaction time. The fabricated samples were characterized with X-ray diffraction, scanning electron microscopy, and energy dispersive X-ray. We suggested a mechanism to explain the growth of the silver core/TiO2 shell nano-wires. PMID:26328391

  2. Second quantization model for surface plasmon polariton in metallic nano wires

    NASA Astrophysics Data System (ADS)

    Thi Phuong Lan, Nguyen; Thi Nga, Do; Viet, Nguyen Ai

    2016-06-01

    A model of effective Hamiltonian is proposed in second quantization representation for system of surface plasmons and photon (polariton) in metallic nano wires. The dispersion relation curves of surface plasmon polariton was calculated by mean of the Bogoliubov diagonalization method. The surface plasmon photon vertexes are considered. The conditions for excitation surface plasmon, existence plasmon radiate modes, and a possible application of metallic nano wires were also discussed.

  3. Lattice-Directed Formation of Covalent and Organometallic Molecular Wires by Terminal Alkynes on Ag Surfaces.

    PubMed

    Liu, Jing; Chen, Qiwei; Xiao, Lianghong; Shang, Jian; Zhou, Xiong; Zhang, Yajie; Wang, Yongfeng; Shao, Xiang; Li, Jianlong; Chen, Wei; Xu, Guo Qin; Tang, Hao; Zhao, Dahui; Wu, Kai

    2015-06-23

    Surface reactions of 2,5-diethynyl-1,4-bis(phenylethynyl)benzene on Ag(111), Ag(110), and Ag(100) were systematically explored and scrutinized by scanning tunneling microscopy, molecular mechanics simulations, and density functional theory calculations. On Ag(111), Glaser coupling reaction became dominant, yielding one-dimensional molecular wires formed by covalent bonds. On Ag(110) and Ag(100), however, the terminal alkynes reacted with surface metal atoms, leading to one-dimensional organometallic nanostructures. Detailed experimental and theoretical analyses revealed that such a lattice dependence of the terminal alkyne reaction at surfaces originated from the matching degree between the periodicities of the produced molecular wires and the substrate lattice structures. PMID:25990647

  4. Fabrication of capillary-force-induced DNA-templated Ag wires assisted by enzymatic etching

    NASA Astrophysics Data System (ADS)

    Periasamy, Vengadesh; Ciniciato, Gustavo P. M. K.; Yunus, Kamran; Fisher, Adrian C.

    2015-02-01

    We report a novel scribing or “writing” method for fabricating micro- to nanoscale silver (Ag) wires on a silicon (Si) wafer using natural capillary force. The coffee-ring drying effect fueled by the capillary force allows the diffusion of Ag-loaded DNA molecules towards the edge of the scribing region, resulting in deposition along the scribed patterns. This is followed by the removal of DNA scaffolding by enzyme-assisted etching, leaving behind the Ag wire on the wafer. This technique is expected to improve the current DNA-assisted formation of metallic nanopatterns and nanostructures towards potential applications in nanoelectronics.

  5. Effects of Annealing Twins on the Grain Growth and Mechanical Properties of Ag-8Au-3Pd Bonding Wires

    NASA Astrophysics Data System (ADS)

    Chuang, Tung-Han; Tsai, Chih-Hsin; Wang, Hsi-Ching; Chang, Che-Cheng; Chuang, Chien-Hsun; Lee, Jun-Der; Tsai, Hsing-Hua

    2012-11-01

    An innovative Ag-8Au-3Pd bonding wire containing a large amount of annealing twins has been produced. In contrast to the apparent grain growth in a conventional Ag-8Au-3Pd wire during aging at 600°C, the grain size of this annealing-twinned Ag alloy wire remains almost unchanged. The high thermal stability of the grain structure leads to a smaller heat-affected zone near the free air ball of this twinned wire. The annealing twins in this material also result in the dual merits of increased tensile strength and elongation with aging time, which is beneficial for the reliability of wire-bonded packages.

  6. Au-Ag-Cu nano-alloys: tailoring of permittivity

    NASA Astrophysics Data System (ADS)

    Hashimoto, Yoshikazu; Seniutinas, Gediminas; Balčytis, Armandas; Juodkazis, Saulius; Nishijima, Yoshiaki

    2016-04-01

    Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective.

  7. Au-Ag-Cu nano-alloys: tailoring of permittivity

    PubMed Central

    Hashimoto, Yoshikazu; Seniutinas, Gediminas; Balčytis, Armandas; Juodkazis, Saulius; Nishijima, Yoshiaki

    2016-01-01

    Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective. PMID:27118459

  8. Au-Ag-Cu nano-alloys: tailoring of permittivity.

    PubMed

    Hashimoto, Yoshikazu; Seniutinas, Gediminas; Balčytis, Armandas; Juodkazis, Saulius; Nishijima, Yoshiaki

    2016-01-01

    Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective. PMID:27118459

  9. RRR and thermal conductivity of Ag and Ag0.2wt%Mg alloy in Ag/Bi-2212 wires

    SciTech Connect

    Li, Pei; Ye, L.; Jiang. J., Jiang. J.; Shen, T.

    2015-08-19

    The residual resistivity ratio (RRR) and thermal conductivity of metal matrix in metal/superconductor composite wires are important parameters for designing superconducting magnets. However, the resistivity of silver in reacted Ag/Bi-2212 wires has yet to be determined over temperature range from 4.2 K to 80 K because Bi-2212 filaments have a critical transition temperature Tc of ~ 80 K, and because it is unknown whether the RRR of Ag/Bi-2212 degrades with Cu diffusing from Bi-2212 filaments into silver sheathes at elevated temperatures and to what degree it varies with heat treatment. We measured the resistivity of stand-alone Ag and AgMg (Ag-0.2wt%Mg) wires as well as the resistivity of Ag and Ag- 0.2wt%Mg in the state-of-the-art Ag/Bi-2212 round wires reacted in 1 bar oxygen at 890 °C for 1, 8, 24 and 48 hours and quickly cooled to room temperature. The heat treatment was designed to reduce the critical current Ic of Bi-2212 wires to nearly zero while allowing Cu loss to fully manifest itself. We determined that pure silver exhibits a RRR of ~ 220 while the oxide-dispersion strengthened AgMg exhibits a RRR of ~ 5 in stand-alone samples. A surprising result is that the RRR of silver in the composite round wires doesn’t degrade with extended time at 890 °C for up to 48 hours. This surprising result may be explained by our observation that the Cu that diffuses into the silver tends to form Cu2O precipitates in oxidizing atmosphere, instead of forming Ag-Cu solution alloy. We also measured the thermal conductivity and the magneto-resistivity of pure Ag and Ag-0.2 wt%Mg from 4.2 K to 300 K in magnetic fields up to 14.8 T and summarized them using a Kohler plot.

  10. Formation and properties of hyaluronan/nano Ag and hyaluronan-lecithin/nano Ag films.

    PubMed

    Khachatryan, Gohar; Khachatryan, Karen; Grzyb, Jacek; Fiedorowicz, Maciej

    2016-10-20

    A facile and environmentally friendly method of the preparation of silver nanoparticles embedded in hyaluronan (Hyal/Ag) and hyaluronan-lecithin (Hyal-L/Ag) matrix was developed. Thin, elastic foils were prepared from gels by an in situ synthesis of Ag in an aqueous solution of sodium hyaluronate (Hyal), using aq. d-(+)-xylose solution as a reducing agent. The gels were applied to a clean, smooth, defatted Teflon surface and left for drying in the air. The dry foils were stored in a closed container. UV-vis spectroscopy, transmission electron microscopy (TEM) and Fourier transform infrared (FTIR) spectra confirmed formation of about 10nm ball-shaped Ag nanoparticles situated within the polysaccharide template. Thermal properties of the composites were characterized involving differential scanning calorimetry (DSC) and thermogravimetric (TGA) analyses, whereas molecular weights of polysaccharide chains of the matrix were estimated with the size exclusion chromatography coupled with multiangle laser light scattering and refractometric detectors (HPSEC-MALLS-RI). An increase in the molecular weight of the hyaluronate after generation of Ag nanoparticles was observed. The foils showed specific properties. The study confirmed that silver nanoparticles can be successfully prepared with environmentally friendly method, using hyaluronan as a stabilizing template. Hyaluronan and hyaluronan-lecithin matrices provide nanocrystals uniform in size and shape. The composites demonstrated a bacteriostatic activity. PMID:27474588

  11. Effect of composition on critical current density of Bi2212/Ag round wires

    NASA Astrophysics Data System (ADS)

    Kim, S. C.; Ha, D. W.; Oh, S. S.; Sohn, H. S.

    2009-06-01

    We have fabricated Bi2212/Ag round wires using three kinds of precursor to study the effect of a narrow variation of composition. Slightly different compositions - Bi 2.17Sr 1.94Ca 0.89Cu 2.0O x(N13), Bi 2.15Sr 1.94Ca 0.89Cu 2.0O x(N14), and Bi 2.17Sr 1.98Ca 0.89Cu 2.0O x(N15) - were used and Sr/Ca ratio of them were 2.18, 2.18, and 2.22, respectively. The Ag ratios of the wires were 2.7-2.8 and average filament diameter was 19-21 μm. DTA analysis of the wire showed the peritectic temperature of three wires was very similar value of the range of 880-881 °C. The best engineering critical current density ( Je) of three wires at 4.2 K and 0 T was 414-448 A/mm 2 at the maximum process temperature range of 884-892 °C. The n-value of N14 showed 13.6, whereas other two wires showed lower n-value, estimating the existence of micro-cracks. Although Bi2212/Ag round wires fabricated by three kinds of composition showed similar Je value, n-value was quite different. It is likely that the fabrication process such as the drawing as well as the composition of precursor will affect on Je of Bi2212/Ag round wire.

  12. A model of optical trapping cold atoms using a metallic nano wire with surface plasmon effect

    NASA Astrophysics Data System (ADS)

    Thi Phuong Lan, Nguyen; Thi Nga, Do; Viet, Nguyen Ai

    2016-06-01

    In this work, we construct a new model of optical trapping cold atoms with a metallic nano wire by using surface plasmon effect generated by strong field of laser beams. Using the skin effect, we send a strong oscillated electromagnetic filed through the surface of a metallic nano wire. The local field generated by evanescent effect creates an effective attractive potential near the surface of metallic nano wires. The consideration of some possible boundary and frequency conditions might lead to non-trivial bound state solution for a cold atom. We discus also the case of the laser reflection optical trap with shell-core design, and compare our model with another recent schemes of cold atom optical traps using optical fibers and carbon nanotubes.

  13. Hydrostatic extrusion of BSCCO/Ag composite wire

    SciTech Connect

    Bingert, J.F.; Bingham, B.L.; Sebring, R.J.; Kelly, A.M.

    1995-03-01

    The application of hydrostatic extrusion processing to composite wire fabrication offers several advantages over conventional reduction techniques. These include enhanced uniformity, increased reduction capability, and successful extrusion of normally brittle materials. Specifically, this work involved an experiment to screen the effects of seven extrusion process parameters on the uniformity and density of as-extruded BSCCO-core wire, and the required extrusion pressure. Results suggest the following factors to be potentially significant: (1) back pressure, extrusion ratio, and die angle on core uniformity, (2) packing method, extrusion ratio, silver powder additions, and temperature on density, and (3) extrusion ratio and temperature on extrusion pressure.

  14. Micro-PIXE study of Ag in digestive glands of a nano-Ag fed arthropod ( Porcellio scaber, Isopoda, Crustacea)

    NASA Astrophysics Data System (ADS)

    Tkalec, Živa Pipan; Drobne, Damjana; Vogel-Mikuš, Katarina; Pongrac, Paula; Regvar, Marjana; Štrus, Jasna; Pelicon, Primož; Vavpetič, Primož; Grlj, Nataša; Remškar, Maja

    2011-10-01

    Micro-proton induced X-ray emission (micro-PIXE) method was applied to study the micro-localization of silver (Ag) in digestive glands of a terrestrial arthropod (Porcellio scaber) after feeding on silver nanoparticles (nano-Ag) dosed food. The aim of our work was to assess whether feeding on nano-Ag results in the assimilation of silver (Ag) in digestive gland cells. To study micro-localization and elemental distribution of Ag, the animals were fed on food dosed with nanoparticles for 14 days under controlled laboratory conditions. At the end of the feeding exposure, the animals were dissected and digestive glands prepared for micro-PIXE analyses and TEM investigation. The results obtained by micro-PIXE documented high amounts of Ag inside S-cells of the digestive gland epithelium; however, TEM investigation did not show particle aggregates inside digestive gland cells. Also no adverse effect on feeding behavior was recorded what is a measure of toxic effects. We explain the presence of Ag inside the cells as a result of the assimilation of dissoluted Ag ions from ingested nano-Ag particles. Assimilation of excessive amounts of ingested metal ions in S-cells is a well known metal detoxification mechanism in isopods. We discuss the advantages of using micro-PIXE for the micro-localization of elements in biological tissue in studies of interactions between nanoparticles and biological systems.

  15. Plasmon-optical phonon hybridization in polar semiconductor nano-wires

    NASA Astrophysics Data System (ADS)

    Moradi, Afshin

    2013-12-01

    The hybridization of the plasmon oscillations with the optical phonon waves in cylindrical polar semiconductor nano-wires is investigated. A simple model based on the hydrodynamic theory in conjunction with the Poisson's equation is proposed. An explicit form of the dispersion relation for hybridized surface plasmon-optical phonon modes of the system is derived.

  16. Preparation and photocatalytic properties of AgI–SnO{sub 2} nano-composites

    SciTech Connect

    Wen, Biao; Wang, Xiao-Hui; Lu, Juan; Cao, Jia-Lei; Wang, Zuo-Shan

    2013-05-15

    Highlights: ► AgI–SnO{sub 2} nano-composites have been successfully synthesized. ► As-prepared AgI–SnO{sub 2} nano-composites own the excellent visible light photocatalytic activity. ► As-prepared AgI–SnO{sub 2} nano-composites own the excellent stability. - Abstract: AgI doped SnO{sub 2} nano-composites were prepared by the chemical coprecipitation method and were characterized by the X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Results showed that main of the I{sup −} ions remained in the AgI lattice which is highly dispersed in the system. The photo-catalytic experiments performed under visible light irradiation using methylene blue as the pollutant revealed that not only the photo-catalytic activity but also the stability of SnO{sub 2} based photocatalyst could be improved by introduction of an appropriate amount of AgI, and the result was further supported by the UV–Vis diffuse reflection spectra and the electron spin-resonance spectra. Among all of the samples, AgI–SnO{sub 2} nano-composite with 2At% AgI exhibited the best catalytic efficiency and stability.

  17. Generation and characterization of nano tungsten oxide particles by wire explosion process

    SciTech Connect

    Aravinth, S.; Sankar, Binu; Chakravarthi, S.R.; Sarathi, R.

    2011-02-15

    Nano tungsten oxide particles are produced by wire explosion process. It is realized that by exploding tungsten conductor in lower pressure of oxygen, unreacted phase of tungsten was present and it could be reduced by increasing the operating pressure and increasing the amount of energy deposited to the exploding conductor. It is realized that the nucleation rate of the particle could be high only at the point of maximum saturation ratio, irrespective of the pressure of the oxygen. The size of the critical nucleus formed is low when the saturation ratio and the nucleation rate are at maximum. The nano metal oxide particle formation by wire explosion process allows one to conclude that the second stage annealing process has a major impact on the final grain size formed. The high speed camera photographs of wire explosion process were used to understand the dynamics of particle formation by wire explosion process. The Transmission Electron Microscopy (TEM) analysis indicates that the nano tungsten oxide (WO{sub 3}) particles are of spherical shape and the analysis of particle size indicates that it follows log normal distribution. - Graphical Abstract: Nano tungsten oxide (WO{sub 3}) particles are produced by wire explosion process. Theoretical analysis indicates that the size of the critical nucleus formed is low when the saturation ratio and the nucleation rate are at maximum. High speed camera photographs of wire explosion process were used to understand the dynamics of particles formed. Research Highlights: {yields}Lower particle size is possible with lower pressure. {yields}Particle size is increased with reduced energy ratio. {yields}Unreacted tungsten content reduces when oxygen pressure increases.

  18. Investigation on the interaction of nanoAg with Cu-Zn SOD.

    PubMed

    Zhang, Bin; Yu, Lei; Zhang, Ruijing; Liu, Yang; Liu, Rutao

    2015-12-01

    Silver nanoparticles (nanoAg) are used more and more widely, particularly because of their antimicrobial properties. The effect of exposure to nanoAg on the structure of superoxide dismutase (SOD) was thoroughly investigated using fluorescence measurements, synchronous fluorescence spectroscopy, steady-state and time-resolved fluorescence quenching measurements, UV/Vis absorption spectroscopy, resonance light scattering (RLS), circular dichroism (CD), isothermal titration calorimetry (ITC) and high-resolution transmission electron microscopy (HRTEM). Through van der Waal's force, nanoAg interacted with Cu-Zn SOD and influenced the active site by inducing structural changes, which influenced the function of SOD. The fluorescence studies show that both static and dynamic quenching processes occur. This paper provides reference data for toxicological studies of nanoAg, which are important in the future development of nanotechnology. PMID:25754791

  19. Toxic effects and bioaccumulation of nano-, micron- and ionic-Ag in the polychaete, Nereis diversicolor.

    PubMed

    Cong, Yi; Banta, Gary T; Selck, Henriette; Berhanu, Deborah; Valsami-Jones, Eugenia; Forbes, Valery E

    2011-10-01

    There is increasing concern about the toxicities and potential risks, both still poorly understood, of silver nanoparticles for the aquatic environment after their eventual release via wastewater discharges. In this study, the toxicities of sediment associated nano (<100 nm)-, micron (2-3.5 μm)- and ionic (AgNO(3))-Ag on the sediment-dwelling polychaete, Nereis diversicolor, were compared after 10 days of sediment exposure, using survival, DNA damage (comet assay) and bioaccumulation as endpoints. The nominal concentrations used in all exposure scenarios were 0, 1, 5, 10, 25, and 50 μg Ag/g dry weight (dw) sediment. Our results showed that Ag was able to cause DNA damage in Nereis coelomocytes, and that this effect was both concentration- and Ag form-related. There was significantly greater genotoxicity (higher tail moment and tail DNA intensities) at 25 and 50 μg/g dw in nano- and micron-Ag treatments and at 50 μg/g dw in the ionic-Ag treatment compared to the controls (0μg/g dw). The nano-Ag treatment had the greatest genotoxic effect of the three tested Ag forms, and the ionic-Ag treatment was the least genotoxic. N. diversicolor did accumulate sediment-associated Ag from all three forms. Ag body burdens at the highest exposure concentration were 8.56 ± 6.63, 6.92 ± 5.86 and 9.86 ± 4.94 μg/g dw for worms in nano-, micron- and ionic-Ag treatments, respectively, but there was no significant difference in Ag bioaccumulation among the three treatments. PMID:21831346

  20. Dispensing of high concentration Ag nano-particles ink for ultra-low resistivity paper-based writing electronics.

    PubMed

    Wang, Fuliang; Mao, Peng; He, Hu

    2016-01-01

    Paper-based writing electronics has received a lot of interest recently due to its potential applications in flexible electronics. To obtain ultra-low resistivity paper-based writing electronics, we developed a kind of ink with high concentration of Ag Nano-particles (up to 80 wt%), as well as a related dispensing writing system consisting an air compressor machine and a dispenser. Additionally, we also demonstrated the writability and practical application of our proposed ink and writing system. Based on the study on the effect of sintering time and pressure, we found the optimal sintering time and pressure to obtain high quality Ag NPs wires. The electrical conductivity of nano-silver paper-based electronics has been tested using the calculated resistivity. After hot-pressure sintering at 120 °C, 25 MPa pressure for 20 minutes, the resistivity of silver NPs conductive tracks was 3.92 × 10(-8) (Ωm), only 2.45 times of bulk silver. The mechanical flexibility of nano-silver paper-based electronics also has been tested. After 1000 bending cycles, the resistivity slightly increased from the initial 4.01 × 10(-8) to 5.08 × 10(-8) (Ωm). With this proposed ink preparation and writing system, a kind of paper-based writing electronics with ultra-low resistivity and good mechanical flexibility was achieved. PMID:26883558

  1. Dispensing of high concentration Ag nano-particles ink for ultra-low resistivity paper-based writing electronics

    NASA Astrophysics Data System (ADS)

    Wang, Fuliang; Mao, Peng; He, Hu

    2016-02-01

    Paper-based writing electronics has received a lot of interest recently due to its potential applications in flexible electronics. To obtain ultra-low resistivity paper-based writing electronics, we developed a kind of ink with high concentration of Ag Nano-particles (up to 80 wt%), as well as a related dispensing writing system consisting an air compressor machine and a dispenser. Additionally, we also demonstrated the writability and practical application of our proposed ink and writing system. Based on the study on the effect of sintering time and pressure, we found the optimal sintering time and pressure to obtain high quality Ag NPs wires. The electrical conductivity of nano-silver paper-based electronics has been tested using the calculated resistivity. After hot-pressure sintering at 120 °C, 25 MPa pressure for 20 minutes, the resistivity of silver NPs conductive tracks was 3.92 × 10-8 (Ωm), only 2.45 times of bulk silver. The mechanical flexibility of nano-silver paper-based electronics also has been tested. After 1000 bending cycles, the resistivity slightly increased from the initial 4.01 × 10-8 to 5.08 × 10-8 (Ωm). With this proposed ink preparation and writing system, a kind of paper-based writing electronics with ultra-low resistivity and good mechanical flexibility was achieved.

  2. Electrical wire explosion process of copper/silver hybrid nano-particle ink and its sintering via flash white light to achieve high electrical conductivity.

    PubMed

    Chung, Wan-Ho; Hwang, Yeon-Taek; Lee, Seung-Hyun; Kim, Hak-Sung

    2016-05-20

    In this work, combined silver/copper nanoparticles were fabricated by the electrical explosion of a metal wire. In this method, a high electrical current passes through the metal wire with a high voltage. Consequently, the metal wire evaporates and metal nanoparticles are formed. The diameters of the silver and copper nanoparticles were controlled by changing the voltage conditions. The fabricated silver and copper nano-inks were printed on a flexible polyimide (PI) substrate and sintered at room temperature via a flash light process, using a xenon lamp and varying the light energy. The microstructures of the sintered silver and copper films were observed using a scanning electron microscope (SEM) and a transmission electron microscope (TEM). To investigate the crystal phases of the flash-light-sintered silver and copper films, x-ray diffraction (XRD) was performed. The absorption wavelengths of the silver and copper nano-inks were measured using ultraviolet-visible spectroscopy (UV-vis). Furthermore, the resistivity of the sintered silver and copper films was measured using the four-point probe method and an alpha step. As a result, the fabricated Cu/Ag film shows a high electrical conductivity (4.06 μΩcm), which is comparable to the resistivity of bulk copper (1.68 μΩcm). In addition, the fabricated Cu/Ag nanoparticle film shows superior oxidation stability compared to the Cu nanoparticle film. PMID:27070756

  3. Electrical wire explosion process of copper/silver hybrid nano-particle ink and its sintering via flash white light to achieve high electrical conductivity

    NASA Astrophysics Data System (ADS)

    Chung, Wan-Ho; Hwang, Yeon-Taek; Lee, Seung-Hyun; Kim, Hak-Sung

    2016-05-01

    In this work, combined silver/copper nanoparticles were fabricated by the electrical explosion of a metal wire. In this method, a high electrical current passes through the metal wire with a high voltage. Consequently, the metal wire evaporates and metal nanoparticles are formed. The diameters of the silver and copper nanoparticles were controlled by changing the voltage conditions. The fabricated silver and copper nano-inks were printed on a flexible polyimide (PI) substrate and sintered at room temperature via a flash light process, using a xenon lamp and varying the light energy. The microstructures of the sintered silver and copper films were observed using a scanning electron microscope (SEM) and a transmission electron microscope (TEM). To investigate the crystal phases of the flash-light-sintered silver and copper films, x-ray diffraction (XRD) was performed. The absorption wavelengths of the silver and copper nano-inks were measured using ultraviolet–visible spectroscopy (UV–vis). Furthermore, the resistivity of the sintered silver and copper films was measured using the four-point probe method and an alpha step. As a result, the fabricated Cu/Ag film shows a high electrical conductivity (4.06 μΩcm), which is comparable to the resistivity of bulk copper (1.68 μΩcm). In addition, the fabricated Cu/Ag nanoparticle film shows superior oxidation stability compared to the Cu nanoparticle film.

  4. Pool boiling of water on nano-structured micro wires at sub-atmospheric conditions

    NASA Astrophysics Data System (ADS)

    Arya, Mahendra; Khandekar, Sameer; Pratap, Dheeraj; Ramakrishna, S. Anantha

    2015-10-01

    Past decades have seen active research in enhancement of boiling heat transfer by surface modifications. Favorable surface modifications are expected to enhance boiling efficiency. Several interrelated mechanisms such as capillarity, surface energy alteration, wettability, cavity geometry, wetting transitions, geometrical features of surface morphology, etc., are responsible for change in the boiling behavior of modified surfaces. Not much work is available on pool boiling at low pressures on microscale/nanoscale geometries; low pressure boiling is attractive in many applications wherein low operating temperatures are desired for a particular working fluid. In this background, an experimental setup was designed and developed to investigate the pool boiling performance of water on (a) plain aluminum micro wire (99.999 % pure) and, (b) nano-porous alumina structured aluminum micro wire, both having diameter of 250 µm, under sub-atmospheric pressure. Nano-structuring on the plain wire surface was achieved via anodization. Two samples, A and B of anodized wires, differing by the degree of anodization were tested. The heater length scale (wire diameter) was much smaller than the capillary length scale. Pool boiling characteristics of water were investigated at three different sub-atmospheric pressures of 73, 123 and 199 mbar (corresponding to T sat = 40, 50 and 60 °C). First, the boiling characteristics of plain wire were measured. It was noticed that at sub-atmospheric pressures, boiling heat transfer performance for plain wire was quite low due to the increased bubble sizes and low nucleation site density. Subsequently, boiling performance of nano-structured wires (both Sample A and Sample B) was compared with plain wire and it was noted that boiling heat transfer for the former was considerably enhanced as compared to the plain wire. This enhancement is attributed to increased nucleation site density, change in wettability and possibly due to enhanced pore scale

  5. Synthesis and characterization of nano Cdo/NiO, nano Ag/ZnO composites & Ag/Zno embedded polymer nanocomposites

    NASA Astrophysics Data System (ADS)

    Godasu, Rahul

    Nanoparticles are finest structures whose size composition is within nanometer range. Thus nanoparticles are a collection of atoms bonded together with structural radius less than 100 nm. Nanocomposites are multiphase solid materials where one of the phases has one, two or three dimensions of less than 100 mn. Nano composites are prepared to improve mechanical, electrical, thermal, optical, electrochemical, catalytic properties from its parent materials. For instance, blend of nanoparticles with a polymer are called polymer nanocomposites. Nanostructured composites like Cadmium oxide/Nickel oxide (CdO/NiO) and silver/zinc oxide (Ag/ZnO) were prepared. Characterization of these prepared nanocomposites were carried out using X-ray powder diffraction, Differential scanning calorimetry, Scanning electron microscopy and the average sizes were determined using zeta sizer. Results obtained using characterization methods were in agreement stating that we were successful in synthesizing composites. The prepared Ag/ZnO nano composite was embedded in PCL polymer and we made films of PCL embedded with nano composite. The SEM image of the 5% Ag/ZnO embedded film clearly shows two regions, which indicates that Ag/ZnO nano composite was successfully embedded into the polymer using a non insitu method. SEM results also showed that the Zinc Oxide nano particles were successfully embedded into the polymer .

  6. Antibacterial Ag/a-C nanocomposite coatings: The influence of nano-galvanic a-C and Ag couples on Ag ionization rates

    NASA Astrophysics Data System (ADS)

    Manninen, N. K.; Calderon, S.; Carvalho, I.; Henriques, M.; Cavaleiro, A.; Carvalho, S.

    2016-07-01

    Biofilm formation has been pointed as a major concern in different industrial applications, namely on biomedical implants and surgical instruments, which has prompted the development of new strategies for production of efficient antimicrobial surfaces. In this work, nano-galvanic couples were created to enhance the antibacterial properties of silver, by embedding it into amorphous carbon (a-C) matrix. The developed Ag/a-C nanocomposite coatings, deposited by magnetron sputtering, revealed an outstanding antibacterial activity against Staphylococcus epidermidis, promoting a total reduction in biofilm formation with no bacteria counts in all dilution. The open circuit potential (OCP) tests in 0.9% NaCl confirmed that a-C shows a positive OCP value, in contrast to Ag coating, thus enhancing the ionization of biocidal Ag+ due to the nano-galvanic couple activation. This result was confirmed by the inductively coupled plasma-optical emission spectroscopy (ICP-OES), which revealed a higher Ag ionization rate in the nanocomposite coating in comparison with the Ag coating. The surface of Ag/a-C and Ag coatings immersed in 0.9% NaCl were monitored by scanning electron microscopy (SEM) over a period of 24 h, being found that the Ag ionization determined by ICP-OES was accompanied by an Ag nanoparticles coalescence and agglomeration in Ag/a-C coating.

  7. Self-Assembled DNA Templated Nano-wires and Circuits

    NASA Astrophysics Data System (ADS)

    Braun, Erez

    2000-03-01

    The realization that conventional microelectronics is approaching its miniaturization limits has motivated the search for an alternative route based on self-assembled nanometer-scale electronics. We have recently proposed a new approach based on the hybridization of biological and electronic materials (Braun E., Eichen Y., Sivan U. and Ben-Yoseph G., Nature 391, 775 (1998)). The concept relies on a two-step self-assembly process. The inherent molecular recognition capabilities of DNA molecules are first utilized to construct a network that serves as a template for the subsequent assembly of electronic materials into a circuit. The utilization of DNA and its associated enzymatic machinery enables: (a) self-assembly of complex substrates, (b) specific molecular addresses for the localization of electronic materials (e.g., gold colloids) by standard molecular biology techniques, (c) interdevice wiring and (d) bridging the microscopic structures to the macroscopic world. The self-assembly of nanometer scale electronics relies on two complementary developments. First, the ability to convert DNA molecules into thin conductive wires and second, the self-assembly of complex extended DNA templates. Our progress in these two directions will be presented. Regarding the first issue, a physical process resulting in condensation of gold colloids onto DNA molecules enables the assembly of thin gold wires (around 100-200 A wide) having, in principle, unlimited extensions. The second issue is developed in the context of recombinant DNA which allows the self-assembly of precise molecular junctions and networks. Specifically, we use RecA protein, which is the main protein responsible for genetic recombination in E. Coli bacteria, to construct DNA junctions at pre-designed addresses (sequences) on the molecules. The integration of these processes allows advancing nanometer-scale electronics. A realistic fabrication scheme for a room-temperature single-electron transistor

  8. Nano-Welding of Ag Nanowires Using Rapid Thermal Annealing for Transparent Conductive Films.

    PubMed

    Oh, Jong Sik; Oh, Ji Soo; Shin, Jae Hee; Yeom, Geun Young; Kim, Kyong Nam

    2015-11-01

    Ag nanowire (NW) films obtained by the spraying the Ag NWs on the substrates were nano-welded by rapid thermal annealing (RTA) process and the effect of RTA process on the change of sheet resistance and optical transmittance of the Ag NW films was investigated. The increased number of Ag NW sprays on the substrate decreased the sheet resistance but also decreased the optical transmittance. By the annealing for 60 sec in a nitrogen environment to 225-250 degrees C, the sheet resistance of Ag NW film could be decreased to about 50%, even though it was accompanied by the slight decrease of optical transmittance less than 5%. The decrease of sheet resistance was related to the nano-welding of the Ag NW junctions and the slight decrease of optical transmittance was related local melting of the Ag NWs and spreading on the substrate surface. Through the nano-welding by RTA process, the Ag NW film with the sheet resistance of -20 Ω/sq. and the optical transmittance of 93% could be obtained. PMID:26726568

  9. Growth of periodic nano-layers of nano-crystals of Au, Ag, Cu by ion beam

    NASA Technical Reports Server (NTRS)

    Smith, Cydale C.; Zheng, B.; Muntele, C. I.; Muntele, I. C.; Ila, D.

    2005-01-01

    Multilayered thin films of SiO2/AU+ SiO2/, SiO2/Ag+ SiO2/, and SiO2/Cu+ SiO2/, were grown by deposition. We have previously shown that MeV ion Bombardment of multi-nano-layers of SiO2/AU+ SiO2/ produces Au nanocrystals in the AU+ SiO2 layers. An increased number of nano-layers followed by MeV ion bombardment produces a wide optical absorption band, of which its FWHM depends on the number of nano-layers of SiO2/AU+ SiO2/. We have successfully repeated this process for nano-layers of SiO2/Ag+ SiO2/, and SiO2/Cu+ SiO2/. In this work we used 5 MeV Si as the post deposition bombardment ion and monitored the location as well as the optical absorption's FWHM for each layered structure using Optical Absorption Photospectrometry. The concentration and location of the metal nano-crystals were measured by Rutherford Backscattering Spectrometry. We will report on the results obtained for nano-layered structures produced by post deposition bombardment of SiO2/AU+ SiO2/, SiO2/Ag+ SiO2/, and SiO2/Cu+ SiO2/ layered systems as well as the results obtained from a system containing a periodic combination of SiO2/AU+ SiO2/, SiO2/Ag+ SiO2/, and SiO2/Cu+ SiO2/.

  10. Role of internal gases and creep of Ag in controlling the critical current density of Ag-sheathed Bi2Sr2CaCu2Ox wires

    NASA Astrophysics Data System (ADS)

    Shen, T.; Ghosh, A.; Cooley, L.; Jiang, J.

    2013-06-01

    High engineering critical current density JE of > 500 A/mm2 at 20 T and 4.2 K can be regularly achieved in Ag-sheathed multifilamentary Bi2Sr2CaCu2Ox (Bi-2212) round wire when the sample length is several centimeters. However, JE(20 T) in Bi-2212 wires of several meters length, as well as longer pieces wound in coils, rarely exceeds 200 A/mm2. Moreover, long-length wires often exhibit signs of Bi-2212 leakage after melt processing that are rarely found in short, open-end samples. We studied the length dependence of JE of state-of-the-art powder-in-tube (PIT) Bi-2212 wires and gases released by them during melt processing using mass spectroscopy, confirming that JE degradation with length is due to wire swelling produced by high internal gas pressures at elevated temperatures [A. Malagoli et al. Supercond. Sci. Technol. 24, 075016 (2011) and A. Malagoli et al. Supercond. Sci. Technol. 26, 055018 (2013)]. We further modeled the gas transport in Bi-2212 wires and examined the wire expansion at critical stages of the melt processing of as-drawn PIT wires and the wires that received a degassing treatment or a cold-densification treatment before melt processing. These investigations showed that internal gas pressure in long-length wires drives creep of the Ag sheath during the heat treatment, causing wire to expand, lowering the density of Bi-2212 filaments, and therefore degrading the wire JE; the creep rupture of silver sheath naturally leads to the leakage of Bi-2212 liquid. Our work shows that proper control of such creep is the key to preventing Bi-2212 leakage and achieving high JE in long-length Bi-2212 conductors and coils.

  11. Inverter Surge Voltage Endurance with Various Surge Voltage Waveforms of Organic / Inorganic Nano-composite Enameled Wire

    NASA Astrophysics Data System (ADS)

    Kikuchi, Hideyuki; Hanawa, Hidehito

    We developed the new power supply that is able to output various kinds of surge voltage waveform and investigated partial discharge resistance of the nano-composite enameled wires using colloid solution mixing method. Experimental results revealed the relationship between surge voltage waveform and failure time of voltage endurance, as well as the difference in the strength and frequency of the partial discharge under the various kinds of surge voltage waveform. In addition, the developed nano-composite enameled wires have been verified to contribute to the improvement of the motor quality until the present time because long lifetime was confirmed in voltage endurance test with the damaged enameled wire and actual motor.

  12. Fabrication of composite high temperature superconductor wires from Ag/YBa2Cu3O(sub x) powder produced by AgNO3 decomposition

    NASA Astrophysics Data System (ADS)

    Ferrando, William A.

    1990-03-01

    A brief discussion of the history and generic properties of superconductors is given. Arguments favoring the use of microscopically uniform silver additions to the high temperature superconducting ceramic oxide powders are made. After treating some conventional Ag deposition methods and their shortcomings in this application, a novel, inexpensive method involving the decomposition of AgNO3 is presented. Conventional wire fabrication methods, as adapted to processing the high temperature superconductor materials, are discussed. Test equipment for measurement of the important superconducting properties of critical temperature (Tc) and critical current (Jc) is described. Finally, some early results on wire segments fabricated at the Naval Surface Warfare Center (NSWC) are given.

  13. Synthesis and characterization of Ag@Cu nano/microstructure ordered arrays as SERS-active substrates

    NASA Astrophysics Data System (ADS)

    Zhang, Pinhua; Cui, Guangliang; Xiao, Chuanhai; Zhang, Mingzhe; Chen, Li; Shi, Changmin

    2016-06-01

    We fabricated an Ag decorated Cu (Ag@Cu) nano/microstructure ordered array by facile template-free 2D electrodeposition combined with a galvanic reduction method for SERS applications. The Cu nano/microstructure ordered arrays were first synthesized by a 2D electrodeposition method, then Ag nanocubes were decorated on the arrays by galvanic reduction without any capping agent. The pollution-free surface and edge-to-face heterostructure of Ag nanocubes and Cu nano/microstructure arrays provide the powerful field-enhancements for SERS performance. The results verified that the Ag@Cu nano/microstructure ordered arrays have excellent activity for 4-Mercaptopyridine, and the sensitivity limit is as low as 10‑8 M. Therefore, this facile route provides a useful platform for the fabrication of a SERS substrate based on nano/microstructure ordered arrays.

  14. Dispensing of high concentration Ag nano-particles ink for ultra-low resistivity paper-based writing electronics

    PubMed Central

    Wang, Fuliang; Mao, Peng; He, Hu

    2016-01-01

    Paper-based writing electronics has received a lot of interest recently due to its potential applications in flexible electronics. To obtain ultra-low resistivity paper-based writing electronics, we developed a kind of ink with high concentration of Ag Nano-particles (up to 80 wt%), as well as a related dispensing writing system consisting an air compressor machine and a dispenser. Additionally, we also demonstrated the writability and practical application of our proposed ink and writing system. Based on the study on the effect of sintering time and pressure, we found the optimal sintering time and pressure to obtain high quality Ag NPs wires. The electrical conductivity of nano-silver paper-based electronics has been tested using the calculated resistivity. After hot-pressure sintering at 120 °C, 25 MPa pressure for 20 minutes, the resistivity of silver NPs conductive tracks was 3.92 × 10−8 (Ωm), only 2.45 times of bulk silver. The mechanical flexibility of nano-silver paper-based electronics also has been tested. After 1000 bending cycles, the resistivity slightly increased from the initial 4.01 × 10−8 to 5.08 × 10−8 (Ωm). With this proposed ink preparation and writing system, a kind of paper-based writing electronics with ultra-low resistivity and good mechanical flexibility was achieved. PMID:26883558

  15. CDSEM AFM hybrid metrology for the characterization of gate-all-around silicon nano wires

    NASA Astrophysics Data System (ADS)

    Levi, Shimon; Schwarzband, Ishai; Weinberg, Yakov; Cornell, Roger; Adan, Ofer; Cohen, Guy M.; Gignac, Lynne; Bangsaruntip, Sarunya; Hand, Sean; Osborne, Jason; Feinstein, Adam

    2014-04-01

    In an ongoing study of the physical characterization of Gate-All-Around Silicon Nano Wires (GAASiNW), we found that the thin, suspended wires are prone to buckling as a function of their length and diameter. This buckling takes place between the fixed source and drain regions of the suspended wire, and can affect the device performance and therefore must be studied and controlled. For cylindrical SiNW, theory predicts that buckling has no directional preference. However, 3D CDSEM measurement results indicated that cylindrical wires prefer to buckle towards the wafer. To validate these results and to determine if the electron beam or charging is affecting our observations, we used 3D-AFM measurements to evaluate the buckling. To assure that the CDSEM and 3D-AFM measure the exact same locations, we developed a design based recipe generation approach to match the 3D-AFM and CDSEM coordinate systems. Measuring the exact same sites enables us to compare results and use 3D-AFM data to optimize CDSEM models. In this paper we will present a hybrid metrology approach to the characterization of GAASiNW for sub-nanometer variations, validating experimental results, and proposing methods to improve metrology capabilities.

  16. Arc spraying of nano-structured wire on carbon steel: examination of coating microstructures

    SciTech Connect

    Al Askandarani, A.; Hashmi, M. S. J.; Yilbas, B. S.

    2011-01-17

    Arc spraying of nano-structured wire (TAFA 95MX) onto carbon steel is carried out. The workpieces coated were heat treated at temperature similar to the operating temperature of the hot-path components of power gas turbines. The morphological and microstructural changes in the coating are examined using optical and Scanning Electron Microscope (SEM). The surface roughness and microhardness of the resulting coatings are measured. It is found that the formation of dimples like structure at surface increased the surface roughness of the coating. The microhardness of the resulting coating is significantly higher than the base material hardness. Heat treatment does not alter the microstructure and microhardness of the coating.

  17. Synthesis of AgInS2 semiconductor nano crystals by solvothermal method

    NASA Astrophysics Data System (ADS)

    Sugan, S.; Dhanasekaran, R.

    2015-02-01

    A solvothermal route was proposed to synthesis nanocrystalline silver indium sulfide (AgInS2) using ethylenediamine as a solvent. The reaction was carried out in an autoclave in the temperature of 200 °C with AgCl, Indium (In) and sulfur (S) as reactants. Powder X-ray diffraction studies show that the synthesized nano crystals belongs to orthorhombic phase AgInS2 with cell parameters a= 7.001 Å, b= 8.278 Å, and c= 6.698 Å. High resolution scanning electron microscope (HR-SEM) and Energy Dispersive X-ray (EDX) analyses have been carried out for the synthesized nano crystals to find the surface morphology and composition respectively. The band gap of the synthesized nano crystals was determined from UV-Vis spectrum and photoluminescence spectrum. The melting point of the AgInS2 nano crystals was found to be 956°C using differential thermal analysis (DTA).

  18. Micro/nano-particle decorated metal wire for cutting soft matter

    NASA Astrophysics Data System (ADS)

    Zhang, Wei; Feng, Liang-liang; Wu, Fan; Zhang, Run-run; Wu, Cheng-wei

    2016-09-01

    To cut soft materials such as biological tissues with minimal damage and reduced positional error is highly desired in medical surgery and biomechanics. After years of natural selection and evolution, mosquitoes have acquired the ability to insert their proboscises into human skin with astonishingly tiny forces. This can be associated with the unique structure of their proboscises, with micro/nano sawteeth, and the distinctive insertion manner: high frequency reciprocating saw cutting. Inspired by these, this communication describes the successful implantation of metal oxide particles onto molybdenum wire surfaces through a sol-calcination process, to form a biomimetic sawblade with a high density of micro/nano saw teeth, where the acidification is essential in terms of generating active anchoring sites on the wire. When used as a sawblade in conjunction with reciprocating action to cut the viscoelastic gel, both the cut-in force and cut-in displacement could be decreased substantially. The cutting speed and frequency of reciprocating action are important operating parameters influencing cut-in force.

  19. Micro/nano-particle decorated metal wire for cutting soft matter.

    PubMed

    Zhang, Wei; Feng, Liang-Liang; Wu, Fan; Zhang, Run-Run; Wu, Cheng-Wei

    2016-09-01

    To cut soft materials such as biological tissues with minimal damage and reduced positional error is highly desired in medical surgery and biomechanics. After years of natural selection and evolution, mosquitoes have acquired the ability to insert their proboscises into human skin with astonishingly tiny forces. This can be associated with the unique structure of their proboscises, with micro/nano sawteeth, and the distinctive insertion manner: high frequency reciprocating saw cutting. Inspired by these, this communication describes the successful implantation of metal oxide particles onto molybdenum wire surfaces through a sol-calcination process, to form a biomimetic sawblade with a high density of micro/nano saw teeth, where the acidification is essential in terms of generating active anchoring sites on the wire. When used as a sawblade in conjunction with reciprocating action to cut the viscoelastic gel, both the cut-in force and cut-in displacement could be decreased substantially. The cutting speed and frequency of reciprocating action are important operating parameters influencing cut-in force. PMID:27456430

  20. Nano Ag@AgBr surface-sensitized Bi2WO6 photocatalyst: oil-in-water synthesis and enhanced photocatalytic degradation

    NASA Astrophysics Data System (ADS)

    Lin, Shuanglong; Liu, Li; Hu, Jinshan; Liang, Yinghua; Cui, Wenquan

    2015-01-01

    Nano Ag@AgBr decorated on the surface of flower-like Bi2WO6 (hereafter designated Ag@AgBr/Bi2WO6) were prepared via a facile oil-in-water self-assembly method. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectroscopy (DRS), etc. The characterization results indicated that nano Ag@AgBr was observed to be evenly dispersed on the surface of Bi2WO6, and was approximately 20 nm in size. Ag@AgBr/Bi2WO6 composites exhibited excellent UV-vis absorption, due to quantum dimension effect of Ag@AgBr, the surface plasmonic resonance (SPR) of Ag nanoparticles and the special flower-like structure of Bi2WO6. The photoelectrochemical measurement verified that the suitable band potential of Ag@AgBr and Bi2WO6 and the existence of metal Ag resulted in the high efficiency in charge separation of the composite. The photocatalytic activities of the Ag@AgBr/Bi2WO6 samples were examined under visible-light irradiation for the degradation of methylene blue (MB). The composite presented excellent photocatalytic activity due to the synergetic effect of Bi2WO6, AgBr, and Ag nanoparticles. The Ag@AgBr(20 wt.%)/Bi2WO6 sample exhibited the best photocatalytic activity, degrading 95.03% MB after irradiation for 2 h, which was respectively 1.29 times and 1.28 times higher than that of Ag@AgBr and Bi2WO6 photocatalyst. Meanwhile, phenol and salicylic acid were degraded to further prove the degradation ability of Ag@AgBr/Bi2WO6. Additionally, studies performed using radical scavengers indicated that O2-•, •OH and Br0 acted as the main reactive species. Based on above, a photocatalytic mechanism for organics degradation over Ag@AgBr/Bi2WO6 was proposed.

  1. Nano-Nucleation Characteristic of Cu-Ag Alloy Directly Electrodeposited on W Diffusion Barrier for Microelectronic Device Interconnect.

    PubMed

    Kim, Kang O; Kim, Sunjung

    2016-05-01

    Cu-Ag alloy interconnect is promising for ultra-large-scale integration (ULSI) microelectronic system of which device dimension keeps shrinking. In this study, seedless electrodeposition of Cu-Ag alloy directly on W diffusion barrier as interconnect technology is presented in respect of nano-nucleation control. Chemical equilibrium state of electrolyte was fundamentally investigated according to the pH of electrolyte because direct nano-nucleation of Cu-Ag alloy on W surface is challenging. Chelation behavior of Cu2+ and Ag+ ions with citrate (Cit) and ammonia ligands was dependent on the pH of electrolyte. The amount and kind of Cu- and Ag-based complexes determine the deposition rate, size, elemental composition, and surface morphology of Cu-Ag alloy nano-nuclei formed on W surface. PMID:27483895

  2. Improvements of a nano-scale crossed hot-wire for high Reynolds number measurements

    NASA Astrophysics Data System (ADS)

    Fan, Yuyang; Hultmark, Marcus

    2015-11-01

    Hot-wire anemometry, despite its limited spatial and temporal resolution, is still the preferred tool for high Reynolds number flow measurements, mainly due to the continuous signal. To address the resolution issues, the Nano-Scale Thermal Anemometry Probe (NSTAP) was developed at Princeton University. The NSTAP has a sensing volume more than one order of magnitude smaller than conventional hot-wires, and it has displayed superior performance. However, the NSTAP can only measure a single component of the velocity. Using a novel combining method, a probe that enables two-component velocity measurements has been created (the x-NSTAP). The measurement volume is approximately 50 × 50 × 50 μ m, more than one order of magnitude smaller in all directions compared to conventional crossed hot-wires. The x-NSTAP has been further improved to allow more accurate measurements with the help of flow visualization using a scaled model but matching Reynolds number. Results from turbulent flow measurements with the new x-NSTAP are also presented. Supported under NSF grant CBET-1510100 (program manager Dimitrios Papavassiliou).

  3. Nano-Resolution X-ray Tomography for Deciphering Wiring Diagram of Mammalian Brain

    NASA Astrophysics Data System (ADS)

    Mizutani, H.; Sagara, H.; Takeuchi, A.; Ohigashi, T.; Yashiro, W.; Uesugi, K.; Suzuki, Y.; Momose, A.; Takagi, T.

    2011-09-01

    Neural circuits in the central nervous system are the substrate of various high-order brain functions. However, little is known about the mechanisms underlying neuronal information processing in the brain. Anatomical and functional graph structures of neural networks with actual connections will provide us with perspectives to elucidate the brain complexity. Here, we aim to develop a three-dimensional mouse brain atlas of neural circuits using nano-resolution x-ray tomography by synchrotron radiation. In addition to identifying a large number of synapses, our research will also clarify the structure of neuronal networks for understanding the most complex organ in the body. In this study, we observed metal-stained biological tissues of the mouse brain using hard x-ray Zernike-type phase-contrast microscopy with 60-nm resolution at SPring-8. As a result, the nano-resolution hard x-ray phase-contrast microscope revealed nerve fibers and organelles including mitochondria and synapses in the neural tissue. In the near future, this information will be utilized to begin deciphering the wiring diagram of the brain by using nano-resolution x-ray tomography.

  4. Optical and Electrical Investigation of ZnO Nano-Wire Array to Micro-Flower from Hierarchical Nano-Rose Structures.

    PubMed

    Pal, Kaushik; Zhan, Bihong; Ma, Xiao; Wang, Guoping; Schirhagl, Romana; Murgasen, Priya

    2016-01-01

    We have demonstrated a simple solvo-chemical and solvo-thermal route to design various nano-structures growth of zinc oxide (ZnO). The shapes and morphologies can be easily controlled by using different ambient conditions. We successfully fabricated ZnO nano-wires array on ITO substrate. Those nano-wire array center gradually formed micro-flower like structure evolved in this solvo-chemical route. This novel synthesis happened under cationic surfactant CTAB in the solution helps to form hierarchical structures of ZnO. The length of nano-wire is around 2.0 µm, which formed micro-flower diameter 5.0 µm. Micro-flowers were scratched out from ITO substrate thin film and annealed at 650 °C in electric oven for 1 hour, eventually this micro-flower transformed to novel nano-rose structure confirmed by electron microscopic study. Synthesized nano-rose diameter was around 730 nm. Moreover, we found a drastic change of dielectric behavior and DC conductivity of ZnO nanostructures depending on geometry regulated by the duration of preparation. Interestingly enough, optical and electrical properties also changed due to different crystalline structure formation. The dielectric constant is higher at 7.5 also high threshold voltages at 4 V, corresponds to nano-wires array with micro-flower system. A detail dielectric analysis of one step behavior of broad single relaxation peak was obtained only shows the normal dispersion in this system from 1000 kHz to 10 MHz. While less dielectric constant 1.7 and low threshold voltage 1 V, investigated nano-wires with micro-flower, then nano-rose transition appeared in two step behaviors of double relaxations phenomenon appeared one at low frequency and other at higher frequency region. Besides, I~V response characteristics is new idea about different breakdown voltages and bi-stable DC switching capability. Our work demonstrates the possibility of a fast novel synthesis route using a Solvo-chemical process for this type of nanomaterials

  5. Fabrication of one-dimensional Ag/multiwalled carbon nanotube nano-composite

    PubMed Central

    2012-01-01

    Composite made of multiwalled carbon nanotubes coated with silver was fabricated by an electroless deposition process. The thickness of silver layer is about 40 to 60 nm, characterized as nano-crystalline with (111) crystal orientation along the nanotube's axial direction. The characterization of silver/carbon nanotube [Ag/CNT] nanowire has shown the large current carrying capability, and the electric conductivity is similar to the pure silver nanowires that Ag/CNT would be promising as building blocks for integrated circuits. PACS: 81.05.uj, carbon nanotubes, carbon-based materials, diamond/nanocarbon composites. PMID:22444640

  6. Dwell-time effect on the synthesis of a nano-structured material in water by using Ni wire explosion

    NASA Astrophysics Data System (ADS)

    Eom, Gyu Sub; Kwon, Hyeok Jung; Cho, Yong Sub; Paek, Kwang-Hyun; Joo, Won-Tae

    2014-10-01

    Nickel nano-structured materials are synthesized by using a wire explosion in water. Based on an analysis of each step of the wire explosion, we propose insufficient energy deposition before a plasma restrike as the cause for the inclusion of coarse particles in the wire-explosion product. We confirmed that more energy, in excess of 30%, could be deposited by increasing the dwell time, which resulted from a compression of vapor by the surrounding water and from suppression of plasma restrikes. Because of an increased energy loss into the surrounding water, the specific energy increased by two-fold compared to a gas atmosphere. The synthesized nano-structured nickel showed a uniform particle size of 20 nm with a few coarse particles that were mainly metallic nickel with a little oxide and hydroxide phases. The possibility for large-volume production through a continuous explosion of 300 shots was confirmed.

  7. Fabrication and characterization of gold nano-wires templated on virus-like arrays of tobacco mosaic virus coat proteins

    PubMed Central

    Wnęk, M; Górzny, M Ł; Ward, M B; Wälti, C; Davies, A G; Brydson, R; Evans, S D; Stockley, P G

    2016-01-01

    The rod-shaped plant virus tobacco mosaic virus (TMV) is widely used as a nano-fabrication template, and chimeric peptide expression on its major coat protein has extended its potential applications. Here we describe a simple bacterial expression system for production and rapid purification of recombinant chimeric TMV coat protein carrying C-terminal peptide tags. These proteins do not bind TMV RNA or form disks at pH 7. However, they retain the ability to self-assemble into virus-like arrays at acidic pH. C-terminal peptide tags in such arrays are exposed on the protein surface, allowing interaction with target species. We have utilized a C-terminal His-tag to create virus coat protein-templated nano-rods able to bind gold nanoparticles uniformly. These can be transformed into gold nano-wires by deposition of additional gold atoms from solution, followed by thermal annealing. The resistivity of a typical annealed wire created by this approach is significantly less than values reported for other nano-wires made using different bio-templates. This expression construct is therefore a useful additional tool for the creation of chimeric TMV-like nano-rods for bio-templating. PMID:23220929

  8. Probabilistic environmental risk assessment of five nanomaterials (nano-TiO2, nano-Ag, nano-ZnO, CNT, and fullerenes).

    PubMed

    Coll, Claudia; Notter, Dominic; Gottschalk, Fadri; Sun, Tianyin; Som, Claudia; Nowack, Bernd

    2016-01-01

    The environmental risks of five engineered nanomaterials (nano-TiO2, nano-Ag, nano-ZnO, CNT, and fullerenes) were quantified in water, soils, and sediments using probabilistic Species Sensitivity Distributions (pSSDs) and probabilistic predicted environmental concentrations (PECs). For water and soil, enough ecotoxicological endpoints were found for a full risk characterization (between 17 and 73 data points per nanomaterial for water and between 4 and 20 for soil) whereas for sediments, the data availability was not sufficient. Predicted No Effect Concentrations (PNECs) were obtained from the pSSD and used to calculate risk characterization ratios (PEC/PNEC). For most materials and environmental compartments, exposure and effect concentrations were separated by several orders of magnitude. Nano-ZnO in freshwaters and nano-TiO2 in soils were the combinations where the risk characterization ratio was closest to one, meaning that these are compartment/ENM combinations to be studied in more depth with the highest priority. The probabilistic risk quantification allows us to consider the large variability of observed effects in different ecotoxicological studies and the uncertainty in modeled exposure concentrations. The risk characterization results presented in this work allows for a more focused investigation of environmental risks of nanomaterials by consideration of material/compartment combinations where the highest probability for effects with predicted environmental concentrations is likely. PMID:26554717

  9. Controlled Growth of Copper Oxide Nano-Wires through Direct Oxidation

    NASA Astrophysics Data System (ADS)

    Hilman, Joann; Neupane, Ravi; Yost, Andrew J.; Chien, Teyu

    Copper oxides, both Cu2O and CuO, have many applications in solar cells, sensors, and nano-electronics. The properties of the copper oxides are further influenced by the dimension of the materials, especially when made in nanoscale. In particular, the properties of the copper oxide nanowires could be tuned by their structures, lengths, and widths. While several methods have been reported to grow nanowires, direct oxidation is arguably the most economical one. This research examines the effects of oxidization duration and temperature in dry air environment on the development of copper oxide nanowires in order to achieve cost effective controllable growth. Using the direct oxidation method in dry air we have demonstrated growth of CuO nano-wires at temperatures as low as 300 °C and as short as 1hr. Furthermore we have observed that the lengths and diameters of the CuO NWs can be controlled by the duration and temperature of the oxidation process. WY NASA Space Grant Consortium.

  10. Ag-clad Bi-Sr-Ca-Cu-O wires I. Phase study of fully processed 2:2:1:2 wires

    NASA Astrophysics Data System (ADS)

    Ray, R. D.; Hellstrom, E. E.

    1991-01-01

    We have studied the composition of phases in fully processed Ag-clad wires containing Bi-Sr-Ca-Cu-O with a starting cation ratio of 2:2:1:2 using electron probe microanalysis. Wires that were processed at temperatures not exceeding 850°C contained two phases: the two-CuO 2 layer superconductor (“2212”) and Bi 0.06Sr 8.87Ca 4.87Cu 24O x, which is a member of the “ {14}/{24}” solid solution that is in equilibrium with “2212” at 850°C. Phases identified in wires melt processed at temperatures up to 920°C then annealed at 830-840°C were “2212”, (Sr 1- xCa x)CuO 2, and Ag particles. This appears to be a nonequilibrium phase assemblage as the superconductor is not reported to be in equilibrium with (Sr 1- xCa x)CuO 2 at 800-850°C.

  11. [Study on the development of Ag-nano-hydroxyapatite/polyamide66 porous scaffolds with surface mineralization].

    PubMed

    Fan, Jianbo; Chang, Shan; Dong, Mina; Huang, Di; Li, Jidong; Jiang, Dianming

    2012-12-01

    Bacterial infection after implantation of bone tissue engineering scaffolds is still a serious clinical problem. Ag-nano-hydroxyapatite/polyamide66 (Ag-nHA/PA66) antibacterial composite scaffold were prepared with phase-inversion method in this study. The scaffolds were mineralized in saturated calcium phosphate solution at 37 degrees C for 1 day. The microstructure and the newly formed nano-apatite deposition on the scaffolds before and after mineralization were observed using scanning electron microscopy (SEM). In order to investigate the release behaviors of Ag+, the Ag-nHA/PA66 scaffolds were immersed into 5 ml PBS at 37 degrees C for a different period between 3 h and 168 h before and after mineralization. Then the samples were cultured with E. coli (8099) to test the antibacterial effect of the scaffolds. The results showed that, after mineralization, Ag-nHA/PA66 porous scaffolds still possessed a good inter-connection and a new apatite layer was formed on the surface of the scaffolds. The average macropore size was 626.61 +/- 141.94 microm, the porosity was 76.89 +/- 8.21% and the compressive strength was 2.94 +/- 1.12 MPa. All these physical parameters had no significant difference from those of the un-mineralized scaffolds. The Ag+ release of the scaffolds with and without mineralization was fast within 1 day and then kept slow and stable after 1 day. The antibacterial test confirmed that after mineralization the scaffolds had good antibacterial effects on E. coli. PMID:23469542

  12. Quench degradation limit of multifilamentary Ag/Bi2Sr2CaCu2O x round wires

    NASA Astrophysics Data System (ADS)

    Ye, Liyang; Li, Pei; Shen, Tengming; Schwartz, Justin

    2016-03-01

    Understanding safe operating limits of composite superconducting wires is important for the design of superconducting magnets. Here we report measurements of quench-induced critical current density J c degradation in commercial Ag/Bi2Sr2CaCu2O x (Bi-2212) round wires using heater-induced quenches at 4.2 K in self magnetic field that reveal a general degradation behavior. J c degradation strongly depends on the local hot spot temperature T max, and is nearly independent of operating current, the temperature gradient along the conductor dT max/dx, and the temperature rising rate dT max/dt. Both J c and n value (where n is an index of the sharpness of the superconductor-to-normal transition) exhibit small but irreversible degradation when T max exceeds 400-450 K, and large degradation occurs when T max exceeds 550 K. This behavior was consistently found for a series of Bi-2212 wires with widely variable wire architectures and porosity levels in the Bi-2212 filaments, including a wire processed using a standard partial melt process and in which Bi-2212 filaments are porous, an overpressure processed wire in which Bi-2212 filaments are nearly porosity-free and that has a J c(4.2 K, self field) exceeding 8000 A mm-2, and a wire that has nearly no filament to filament bridges after reaction. Microstructural observations of degraded wires reveal cracks in the Bi-2212 filaments perpendicular to the wire axis, indicating that the quench-induced I c degradation is primarily driven by strain. These results further suggest that the quench degradation temperature limit depends on the strain state of Bi-2212 filaments and this dependence shall be carefully considered when engineering a high-field Bi-2212 magnet.

  13. Quench degradation limit of multifilamentary AgBi2Sr2CaCu2Ox round wires

    DOE PAGESBeta

    Ye, Liyang; Li, Pei; Shen, Tengming; Schwartz, Justin

    2016-02-02

    Understanding safe operating limits of composite superconducting wires is important for the design of superconducting magnets. Here we report measurements of quench-induced critical current density Jc degradation in commercial Ag/Bi2Sr2CaCu2Ox (Bi-2212) round wires using heater-induced quenches at 4.2 K in self magnetic field that reveal a general degradation behavior. Jc degradation strongly depends on the local hot spot temperature Tmax, and is nearly independent of operating current, the temperature gradient along the conductor dTmax/dx, and the temperature rising rate dTmax/dt. Both Jc and n value (where n is an index of the sharpness of the superconductor-to-normal transition) exhibit small butmore » irreversible degradation when Tmax exceeds 400-450 K, and large degradation occurs when Tmax exceeds 550 K. This behavior was consistently found for a series of Bi-2212 wires with widely variable wire architectures and porosity levels in the Bi-2212 filaments, including a wire processed using a standard partial melt processing and in which Bi-2212 filaments are porous, an overpressure processed wire in which Bi-2212 filaments are nearly porosity-free and that has a Jc(4.2 K, self field) exceeding 8000 A/mm2, and a wire that has nearly no filament to filament bridges after reaction. Microstructural observations of degraded wires reveal cracks in the Bi-2212 filaments perpendicular to the wire axis, indicating that the quench-induced Ic degradation is primarily driven by strain. These results further suggest that the quench degradation temperature limit depends on the strain state of Bi-2212 filaments and this dependence shall be carefully considered when engineering a high-field Bi-2212 magnet.« less

  14. Synthesis and characterization of nano ZnO, nano Ag/ZnO composite & nano-particles embedded polymers

    NASA Astrophysics Data System (ADS)

    Are, Thilak Reddy

    Zinc oxide and silver/zinc oxide nano particles were synthesized by a simple precipitation method in the presence of polyvinylpyrrolidone (PVP). The presence of polyvinylpyrrolidone prevents agglomeration and allows the formation of nano sized particles. Characterization of synthesized nano particles were carried out using X-ray powder diffraction, differential scanning calorimetry, scanning electron microscopy, and the average sizes were determined by zeta seizer. The X-ray diffraction shows that the prepared particles were poorly crystalline. The DSC results show that the prepared particles are highly stable and no phase changes were observed when heated from room temperature to 500°C. Scanning electron microscopic observation shows that the particles are uniformly distributed with similar shape. Zeta seizer results show that the prepared particles are nano-particles with average size of about 100 nm. The prepared Zinc oxide nano particles were embedded into the polycaprolactone (PCL) polymer to study the effect of embedding zinc oxide nanoparticle on PCL crystallinity and mechanical properties. ZnO nano particles were successfully embedded into the polymer using in-situ and non-in-situ embedding processes. Characterization of PCL embedded with ZnO nanoparticles was performed by X-ray diffraction technique and scanning electron microscope. Crystallinity studies were done by using differential scanning calorimetry and the results show that the polymer embedded using an in situ process showed a decrease in crystallinity compared to the polymer embedded using a non-insitu process.

  15. Nano-Structured Mesoporous Silica Wires with Intra-Wire Lamellae via Evaporation-Induced Self-Assembly in Space-Confined Channels

    SciTech Connect

    Hu, Michael Z.; Shi, Donglu; Blom, Douglas Allen

    2014-04-06

    Evaporation-induced self-assembly (EISA) of silica sol-gel ethanol-water solution mixtures with block-copolymer were studied inside uniform micro/nano channels. Nano-structured mesoporous silica wires, with various intra-wire self-assembly structures including lamellae, were prepared via EISA process but in space-confined channels with the diameter ranging from 50 nm to 200 nm. Membranes made of anodized aluminum oxide (AAO) and track-etched polycarbonate (EPC) were utilized as the arrays of space-confined channels (i.e., 50, 100, and 200-nm EPC and 200-nm AAO) for infiltration and drying of mixture solutions; these substrate membranes were submerged in mixture solutions consisting of a silica precursor, a structure-directing agent, ethanol, and water. After the substrate channels were filled with the solution under vacuum impregnation, the membrane was removed from the solution and dried in air. The silica precursor used was tetra-ethyl othosilicate (TEOS), and the structure-directing agent employed was triblock copolymer Pluronic-123 (P123). It was found that the formation of the mesoporous nanostructures in silica wires within uniform channels were significantly affected by the synthesis conditions including (1) pre-assemble TEOS aging time, (2) the evaporation rate during the vacuum impregnation, and (3) the air-dry temperature. The obtained intra-wire structures, including 2D-hexagonal rods and lamellae, were studied by scanning transmission electron microscopy (STEM). A steric hindrance effect seems to explain well the observed polymer-silica mesophase formation tailored by TEOS aging time. The evaporation effect, air-drying effect, and AAO-vs-EPC substrate effect on the mesoporous structure of the formed silica wires were also presented and discussed.

  16. Irreversibility behavior in Ag-sheathed Bi-based superconducting wires

    SciTech Connect

    Dou, S.X.; Liu, H.K.; Guo, Y.C.; Wang, J.; Jin, X.J.; Hu, Q.Y.; Shi, D.L.; Salem-Sugui, S.; Wang, Z.

    1992-04-01

    Irreversibility lines for Ag/(Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub y}(2223) wires prepared through a phase formation- decomposition-recovery (PFDR) process and normal annealing process were determined using both AC susceptibility measurements under DC fields and magnetisation measurements. It was found that flux pinning was enhanced in the PFDR processed samples over the normal processed samples, in particular at temperature above 77 K. The PFDR process results in high mass density, grain alignment, uniform distribution of impurity precipitates and high density of defects. The irreversibility temperatures scaled with the applied field according to H{sup 1/3}, which is in contrast to H{sup 2/3} law for YBa{sub 2}Cu{sub 3}O{sub 7-x} and conventional superconductors. The irreversibility lines for PFDR processed tapes showed a crossover with those for normal processed tapes at temperature below {Tc} of the (Bi,Pb){sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+x} (2212), suggesting that at temperature above {Tc} of the 2212 phase, the 2212 as nonsuperconducting region, may serve as effective pinning sites for fluxoids.

  17. Traceable calibration of a fibre-coupled superconducting nano-wire single photon detector using characterized synchrotron radiation

    NASA Astrophysics Data System (ADS)

    Müller, Ingmar; Klein, Roman M.; Werner, Lutz

    2014-12-01

    Radiometric calibrations of fibre-coupled single photon detectors are experiencing growing demand, especially at the telecommunication wavelengths. In this paper, the radiometric calibration of a fibre-coupled superconducting nano-wire single photon detector at the telecom wavelength 1.55 µm by means of well-characterized synchrotron radiation is described. This substitution method is based on the unique properties of synchrotron radiation and the Metrology Light Source, the dedicated electron storage ring of the Physikalisch-Technische Bundesanstalt, and is suitable for fibre-coupled single photon detectors. The Metrology Light Source is used as a light source with a high dynamic range of the radiant power to bridge the radiometric gap occurring in the transition from radiant power measurements and the counting of photons with single photon detectors. Very low uncertainties below 2% have been achieved in the measurement of the detection efficiency of a fibre-coupled superconducting nano-wire single photon detector.

  18. A new structural powder/wire-in-tube (PWIT) Ag-sheathed multifilamentary Bi-2223 tape and its superconducting properties

    NASA Astrophysics Data System (ADS)

    Zeng, R.; Liu, H. K.; Dou, S. X.

    1998-05-01

    A new design of macrostructural multifilamentary tapes has been developed by parking powder and composite wires into the silver tube (PWIT) at the second stage of the powder-in-tube (PIT) process. The critical current Jc and the strain tolerance for this PWIT multifilamentary tape were significantly improved in comparison with the PIT multifilamentary tapes. The enhancement of both Jc and the strain tolerance are attributable to the increased interface between Ag and oxide superconductor. We have introduced a simple concept of the periphery length of the Ag/superconductor interface per unit area in the cross-section of tapes ( E) and have compared its properties in PWIT and PIT tapes. Both Jc and the strain tolerance were improved with increasing E. This was attributed to the improved grain alignment and crack elimination at the Ag/superconductor interface. The Jc- B properties and the Jc-strain characteristic of two tapes have been compared.

  19. Nano-Storage Wires for the Controlled Release of Biochemical Materials

    NASA Astrophysics Data System (ADS)

    Yoo, Haneul; Lee, Dongjun; Kim, Eunji; Kim, Daesan; Park, Juhun; Hong, Seunghun

    2015-03-01

    We herein report ``nano-storage wires'' (NSWs) that can store chemical species and release them at a desired moment by electrical stimulations. Here, we utilized the electrodeposition process through an anodized aluminium oxide template to fabricate multi-segmented nanowires which consisted of a polypyrrole (PPy) segment containing adenosine triphosphate (ATP) molecules, a ferromagnetic nickel segment, and a conductive gold segment. We could drive and deposit the NSWs onto desired positions on electrode surfaces via external magnetic fields. When the external electric potential was applied from the electrodes, the NSWs released ATPs from the PPy segments, and the released ATPs could change the activities of motor proteins near the NSWs. Furthermore, through direct writing or magnetic manipulation strategies, we could print NSWs onto various substrates such as flexible or three-dimensional structured substrates to build versatile chemical storage devices. Since our strategy enables the controllable storage and release of chemicals, our development should open up various applications such as drug delivery systems, biosensors and biochips for the controlled release of chemicals to biosystems.

  20. Ag-doped ZnO nanorods coated metal wire meshes as hierarchical photocatalysts with high visible-light driven photoactivity and photostability.

    PubMed

    Hsu, Mu-Hsiang; Chang, Chi-Jung

    2014-08-15

    Ag-doped ZnO nanorods were grown on stainless-steel wire meshes to fabricate the hierarchical photocatalysts with excellent visible light driven activity and anti-photocorrosion property. Effects of Ag doping and the surface structure on the surface chemistry, surface wetting properties, absorption band shift, photoelectrochemical response, and photocatalytic decolorization properties of the hierarchical photocatalysts, together with the stability of photocatalytic activity for recycled photocatalysts were investigated. Ag doping leads to red-shift in the absorption band and increased visible light absorption. Nanorods coated wire meshes hierarchical structure not only increases the surface area of photocatalysts but also makes the surface hydrophilic. The photocatalytic activity enhancement and reduced photocorrosion can be achieved because of increased surface area, enhanced hydrophilicity, and the interaction between the metal wire/ZnO and Ag/ZnO heterostructure interface which can improve the charge separation of photogenerated charge carriers. PMID:24997260

  1. Syntheses and characterization of AgI nano-structures by ultrasonic method: Different morphologies under different conditions.

    PubMed

    Abbasi, Amir Reza; Morsali, Ali

    2010-03-01

    Nano-structures of AgI have been prepared by reaction between AgNO(3) and KI under ultrasound irradiation. Some of parameters such as effect of stirring, temperature, sonicating time in growth and morphology of the nano-structures have been studied. The sizes distributions depend slighter on reaction conditions. But, morphology of nano-structure depends strongly on reaction parameters. With change of solvent concentration and sonicating time, nanoparticles structures changed to nanowires. An increasing of temperature results in an increasing of solubility. As a result, nuclei with small sizes become unstable and dissolve back into the solution. Attendance or non-attendance of stirring is another parameter that effects on morphology of nano-structures. In some conditions, non-attendance of stirring led to nanowires structure and in the other conditions, nanoparticles structures were prepared. The samples were characterized with powder X-ray diffraction (XRD), scanning electron microscopy (SEM). PMID:19959390

  2. Superconducting properties and magneto-optical imaging of Ba0.6K0.4Fe2As2 PIT wires with Ag addition

    NASA Astrophysics Data System (ADS)

    Ding, Qing-Ping; Prombood, Trirat; Tsuchiya, Yuji; Nakajima, Yasuyuki; Tamegai, Tsuyoshi

    2012-03-01

    We have fabricated (Ba,K)Fe2As2 superconducting wires through an ex situ powder-in-tube method. Silver was used as a chemical addition to improve the performance of these superconducting wires. The transport critical current densities (Jc) have reached 1.3 × 104 A cm-2 and 1.0 × 104 A cm-2 at 4.2 K under self-field in the wires with and without Ag addition. We used a magneto-optical (MO) imaging technique to investigate the properties of grain boundaries in the (Ba,K)Fe2As2 superconducting wire with Ag addition. MO images show the weak links in the Fe-based superconducting wires for the first time. An intragranular Jc of 6.0 × 104 A cm-2 at 20 K is obtained from the MO image, which is consistent with the estimation from M-H measurement.

  3. The structure, morphology, and the metal-enhanced fluorescence of nano-Ag/ZnO core-shell structure

    NASA Astrophysics Data System (ADS)

    Zhao, Yue; Ding, Yanli; Peng, Xiang; Zhou, Mingtao; Liang, Xiaoyan; Min, Jiahua; Wang, Linjun; Shi, Weimin

    2015-06-01

    Nano-polyc rystalline silver (Ag) particles with the diameter of 60 nm were synthesized by the reducing agent sodium citrate. An amorphous zinc oxide (ZnO) shell layer was then coated on the surface of silver particles using wet chemical method. The Ag/ZnO core-shell structure was characterized by scanning electron microscope, transmission electron microscopy, ultraviolet-visible spectroscopy and fluorescence (FL) measurement. The results showed that nano-Ag/ZnO core-shell particles with an average diameter of ~100 nm were prepared successfully, and the FL intensity of Rhodamine 6G (R6G) mixed with Ag/ZnO nanoparticle was 53 % greater than that of the same amount of R6G without any nanoparticles, which may be related to the effect of surface plasmon resonance.

  4. The structure, morphology, and the metal-enhanced fluorescence of nano-Ag/ZnO core-shell structure

    NASA Astrophysics Data System (ADS)

    Zhao, Yue; Ding, Yanli; Peng, Xiang; Zhou, Mingtao; Liang, Xiaoyan; Min, Jiahua; Wang, Linjun; Shi, Weimin

    2014-09-01

    Nano-polyc rystalline silver (Ag) particles with the diameter of 60 nm were synthesized by the reducing agent sodium citrate. An amorphous zinc oxide (ZnO) shell layer was then coated on the surface of silver particles using wet chemical method. The Ag/ZnO core-shell structure was characterized by scanning electron microscope, transmission electron microscopy, ultraviolet-visible spectroscopy and fluorescence (FL) measurement. The results showed that nano-Ag/ZnO core-shell particles with an average diameter of ~100 nm were prepared successfully, and the FL intensity of Rhodamine 6G (R6G) mixed with Ag/ZnO nanoparticle was 53 % greater than that of the same amount of R6G without any nanoparticles, which may be related to the effect of surface plasmon resonance.

  5. Preparation and investigation of nano-thick FTO/Ag/FTO multilayer transparent electrodes with high figure of merit

    NASA Astrophysics Data System (ADS)

    Yu, Shihui; Li, Lingxia; Lyu, Xiaosong; Zhang, Weifeng

    2016-02-01

    In order to improve the conductivity of the single-layered nano-thick F doped SnO2 (FTO) thin films, an Ag mid-layer is embedded between the FTO layers. In our work, the effects of mid-layer Ag and top FTO layer on the structural, electrical and optical properties of FTO/Ag/FTO multilayered composite structures deposited on quartz glass substrates by magnetron sputtering at 100 °C have been investigated. As the thickness of Ag mid-layer increases, the resistivity decreases. As the top FTO layer thickness increases, the resistivity increases. The highest value of figure of merit φTC is 7.8 × 10-2 Ω-1 for the FTO (20 nm)/Ag (7 nm)/FTO (30 nm) multilayers, while the average optical transmittance is 95.5% in the visible range of wavelengths and the resistivity is 8.8 × 10-5 Ω·cm. In addition, we also describe the influence of Ag and top FTO layer thickness on structural, electrical and optical properties of the nano-thick FTO (20 nm)/Ag/FTO multilayers and the mechanism of the changes of electrical and optical properties at different Ag and top FTO layer thicknesses.

  6. Preparation and investigation of nano-thick FTO/Ag/FTO multilayer transparent electrodes with high figure of merit

    PubMed Central

    Yu, Shihui; Li, Lingxia; Lyu, Xiaosong; Zhang, Weifeng

    2016-01-01

    In order to improve the conductivity of the single–layered nano-thick F doped SnO2 (FTO) thin films, an Ag mid–layer is embedded between the FTO layers. In our work, the effects of mid–layer Ag and top FTO layer on the structural, electrical and optical properties of FTO/Ag/FTO multilayered composite structures deposited on quartz glass substrates by magnetron sputtering at 100 °C have been investigated. As the thickness of Ag mid–layer increases, the resistivity decreases. As the top FTO layer thickness increases, the resistivity increases. The highest value of figure of merit φTC is 7.8 × 10−2 Ω−1 for the FTO (20 nm)/Ag (7 nm)/FTO (30 nm) multilayers, while the average optical transmittance is 95.5% in the visible range of wavelengths and the resistivity is 8.8 × 10−5 Ω·cm. In addition, we also describe the influence of Ag and top FTO layer thickness on structural, electrical and optical properties of the nano-thick FTO (20 nm)/Ag/FTO multilayers and the mechanism of the changes of electrical and optical properties at different Ag and top FTO layer thicknesses. PMID:26833398

  7. Preparation and investigation of nano-thick FTO/Ag/FTO multilayer transparent electrodes with high figure of merit.

    PubMed

    Yu, Shihui; Li, Lingxia; Lyu, Xiaosong; Zhang, Weifeng

    2016-01-01

    In order to improve the conductivity of the single-layered nano-thick F doped SnO2 (FTO) thin films, an Ag mid-layer is embedded between the FTO layers. In our work, the effects of mid-layer Ag and top FTO layer on the structural, electrical and optical properties of FTO/Ag/FTO multilayered composite structures deposited on quartz glass substrates by magnetron sputtering at 100 °C have been investigated. As the thickness of Ag mid-layer increases, the resistivity decreases. As the top FTO layer thickness increases, the resistivity increases. The highest value of figure of merit φTC is 7.8 × 10(-2 ) Ω(-1) for the FTO (20 nm)/Ag (7 nm)/FTO (30 nm) multilayers, while the average optical transmittance is 95.5% in the visible range of wavelengths and the resistivity is 8.8 × 10(-5 ) Ω·cm. In addition, we also describe the influence of Ag and top FTO layer thickness on structural, electrical and optical properties of the nano-thick FTO (20 nm)/Ag/FTO multilayers and the mechanism of the changes of electrical and optical properties at different Ag and top FTO layer thicknesses. PMID:26833398

  8. Bi2Sr2CaCu2O8 + x round wires with Ag/Al oxide dispersion strengthened sheaths: microstructure-properties relationships, enhanced mechanical behavior and reduced Cu depletion

    NASA Astrophysics Data System (ADS)

    Kajbafvala, Amir; Nachtrab, William; Wong, Terence; Schwartz, Justin

    2014-09-01

    Ag/Al alloys with various Al content (0.50 wt%, 0.75 wt%, 1.00 wt%, and 1.25 wt%) are made by powder metallurgy and used as the outer sheath material for Bi2Sr2CaCu2O8 + x (Bi2212)/Ag/AgAl multifilamentary round wires (RW). Bi2212/Ag/AgAl RW microstructural, mechanical and electrical properties are studied in various conditions, including as-drawn, after internal oxidation, and after partial melt processing (PMP). The results are compared with the behavior of a Bi2212/Ag/Ag0.20Mg wire of the same geometry. The grains in as-drawn Ag/Al alloys are found to be ˜25% smaller than those in the corresponding Ag/0.20 wt%Mg, but after PMP, the Ag/Al and Ag/0.20 wt%Mg grain sizes are comparable. Tensile tests show that Bi2212/Ag/AgAl green wires have yield strength (YS) of ˜115 MPa, nearly 65% higher than that of Bi2212/Ag/Ag0.20Mg. After PMP, the Bi2212/Ag/AgAl YS is about 35% greater than that of Bi2212/Ag/Ag0.20Mg. Furthermore, Bi2212/Ag/AgAl wires exhibit higher ultimate tensile strength and modulus and twice the elongation-to-failure. Atomic resolution high-angle annular dark-field scanning transmission electron microscopy, high resolution transmission electron microscopy and energy dispersive spectroscopy demonstrate the formation of nanosize MgO and Al2O3 precipitates via internal oxidation. Large spherical MgO precipitates are observed on the Ag grain boundaries of Ag/0.20 wt%Mg alloy, whereas the Al2O3 precipitates are distributed homogenously in the dispersion-strengthened (DS) Ag/Al alloy. Furthermore, it is found that less Cu diffused from the Bi2212 filaments in the Bi2212/Ag/Ag0.75Al wire during PMP than from the filaments in the Bi2212/Ag/Ag0.20Mg wire. These results show that DS Ag/Al alloy is a strong candidate for improved Bi2212 wire.

  9. Self-assembled Ag nanoparticle network passivated by a nano-sized ZnO layer for transparent and flexible film heaters

    SciTech Connect

    Seo, Ki-Won; Kim, Han-Ki; Kim, Min-Yi; Chang, Hyo-Sik

    2015-12-15

    We investigated a self-assembled Ag nanoparticle network electrode passivated by a nano-sized ZnO layer for use in high-performance transparent and flexible film heaters (TFFHs). The low temperature atomic layer deposition of a nano-sized ZnO layer effectively filled the uncovered area of Ag network and improved the current spreading in the self-assembled Ag network without a change in the sheet resistance and optical transmittance as well as mechanical flexibility. The time-temperature profiles and heat distribution analysis demonstrate that the performance of the TFTH with the ZnO/Ag network is superior to that of a TFFH with Ag nanowire electrodes. In addition, the TFTHs with ZnO/Ag network exhibited better stability than the TFFH with a bare Ag network due to the effective current spreading through the nano-sized ZnO layer.

  10. The optimization of Ag/Ag2S electrode using carrier electroplating of nano silver particles and its preliminary application to offshore Kueishan Tao, Taiwan

    NASA Astrophysics Data System (ADS)

    Ding, Qian; Pan, Yi-wen; Huang, Yuan-feng; Chen, Chen-Tung Arthur; Ye, Ying

    2015-12-01

    Eutrophication-induced ocean acidification is causing a dramatic ecologic change in the coastal ocean. A more acidic ocean would lead to more volatile H2S in the coastal ocean, especially in the area where shallow hydrothermal vents exist. Therefore, the early detection of H2S and its associates is needed. In this study, the preparation method for and the detection limit of an Ag/Ag2S electrode were optimized by coating the electrode with micro-scale to nano-scale silver particles. The size of the silver particles was dependent on the electroplating power used to produce them: (1) direct current power made micrometer scale silver particles, and (2) direct current carrier power made nano-scale silver particles. As a result, the detection limits of [S2-] of the Ag/Ag2S electrode made using direct current and direct carrier current were improved to 1×10-5 mol L-1 and 1×10-7 mol L-1, respectively. Such improvements were mostly due to the fact that nano silver particles have larger surface area and higher surface energy. The Ag/Ag2S electrode made by direct carrier current method was then mounted to a multi-parameter sensor (including a pH and an Eh electrode) used to search of new hydrothermal vents near the Kueishan Tao in May, 2011. A new hydrothermal vent was discovered based on pH, Eh and H2S anomalies at three depths. A clear [S2-] signal anomaly was observed from the top sensor indicating the dispersive pattern of the hot fluid near this shallow vent site. This could also provide additional information on the dispersion pattern of anthropogenic pollutants in the coastal ocean.

  11. Quench Behavior and Degradation Limit of Ag-sheathed Bi 2Sr2CaCu2Ox Round Wires

    NASA Astrophysics Data System (ADS)

    Ye, Liyang

    High field superconducting magnets are important for scientific research in a variety of disciplines. With nearly field-independent critical current density over a wide range of magnetic field at 4.2 K up to 50 T, Ag-sheathed Bi2Sr2CaCu2Ox (Bi-2212) round wires offer the possibility to generate magnetic fields of 30 T and above. One of the key issues in high field Bi-2212 magnet development is the quench detection and protection. A quench occurs when a part of a superconducting winding, after receiving a small disturbance, enters into the normal (resistive) state, and the event follows with significant temperature rise due to joule heating. An unprotected quench may degrade or even destruct an entire superconducting magnet system. This thesis focuses on experimentally investigating the quench behavior and degradation limit of the state-of-the-art multifilamentary Ag/Bi-2212 round wires to guide the development of Bi-2212 high field magnet, especially the quench detection and protection system. (Abstract shortened by ProQuest.).

  12. Stimulated and spontaneous four-wave mixing in silicon-on-insulator coupled photonic wire nano-cavities

    NASA Astrophysics Data System (ADS)

    Azzini, Stefano; Grassani, Davide; Galli, Matteo; Gerace, Dario; Patrini, Maddalena; Liscidini, Marco; Velha, Philippe; Bajoni, Daniele

    2013-07-01

    We report on four-wave mixing in coupled photonic crystal nano-cavities on a silicon-on-insulator platform. Three photonic wire cavities are side-coupled to obtain three modes equally separated in energy. The structure is designed to be self-filtering, and we show that the pump is rejected by almost two orders of magnitude. We study both the stimulated and the spontaneous four-wave mixing processes: owing to the small modal volume, we find that signal and idler photons are generated with a hundred-fold increase in efficiency as compared to silicon micro-ring resonators.

  13. Phonon-engineered thermal transport in Si wires with constant and periodically modulated cross-sections: A crossover between nano- and microscale regimes

    NASA Astrophysics Data System (ADS)

    Cocemasov, A. I.; Nika, D. L.; Fomin, V. M.; Grimm, D.; Schmidt, O. G.

    2015-07-01

    The transition between nanoscale and microscale thermal transport regime at room temperature in silicon wires with constant and periodically modulated cross-section is theoretically investigated. Extrapolating the calculated thermal conductivity from the nano- to micrometer range, we find the characteristic dimensions of the wires where a crossover between nanoscale and microscale thermal transport occurs. This crossover is observed in both generic (smooth) and cross-section-modulated wires. In case of smooth silicon wires, we reveal a strong dependence of the crossing point position on the boundary roughness. For silicon wires with weak boundary roughness, the crossover occurs at cross-sections ˜60 nm × 300 nm, while for very rough boundaries it occurs at cross-sections ˜150 nm × 750 nm. In case of the periodically modulated wires, the crossover between nano- and microscale regimes occurs at typical cross-sections ˜120 nm × 120 nm of the narrow segment, and it is almost independent of boundary roughness. A strong distinction from the case of smooth wires is attributed (i) to the different trends at the nanometer scale, wherefrom the extrapolation was performed, and (ii) to the different phonon-boundary scattering due to the specific geometry. For modulated silicon wires, the influence of modulation thickness, modulation length, and cross-sectional area on the phonon thermal conductivity at the room temperature is analyzed. A possibility of thermal transport engineering in cross-section-modulated wires by resizing them is revealed in both nano- and microscale regimes. The presented results pave the way towards a better understanding of thermal transport reduction in Si nanowires with engineered diameter modulations and shed light on the crossover between nano- and microscale regimes of thermal transport.

  14. Understanding Processing, Microstructure and Transport Relationships of Bi2Sr2CaCu2Ox/Ag Round Wires

    NASA Astrophysics Data System (ADS)

    Naderi, Golsa

    Superconducting magnets generating magnetic fields above 25 T are needed for many scientific applications. Due to fundamental limitations to NbTi and Nb3Sn, such high-field superconducting magnets require alternative high-field conductors. One candidate conductor is round wire composites of Bi2Sr2CaCu2Ox sheathed in an Ag-alloy matrix (Bi2212/Ag). The performance of such wires is sensitive to the heat treatment, so improvements in the critical current density (Jc) require a thorough understanding of the processing-structureproperties relationships. Due to the complex microstructure-transport relationships, their performance is far from optimized, and the potential for further increase in Jc remains. In this research a new heat treatment approach, saw-tooth processing (STP) is introduced based upon previous results showing that Bi2212 nucleation is site-saturation limited. STP increases Jc by 120% and 70% relative to partial-melt processing at 5 T and self-field respectively. The effects of STP heat treatment parameters on the microstructure and transport properties are discussed. It is shown that wires with the highest transport critical current densities primarily have filaments with two types of microstructures, one comprised primarily highly textured Bi2212 grains, and another with a noticeable amount of Bi2Sr2CuOX with the Bi2212. After processing, multifilamentary Bi2212 round wires have complex microstructures. In melt processed Bi2212/Ag wires the primary impurity is Bi2Sr 2CuOx (Bi2201), which forms as mesoscopic grains and nanoscopic intergrowths. Microstructureproperties relationship studies are performed based on the hypothesis that Bi2201 plays critical roles in transport depending on the micron-size length scale. Mesoscopic microstructures are analyzed quantitatively using a statistical approach in which filaments are categorized based on the predominant phases observed by scanning electron microscope (SEM). A Matlab program is created to analyze the

  15. Role of plant growth promoting rhizobacteria and Ag-nano particle in the bioremediation of heavy metals and maize growth under municipal wastewater irrigation.

    PubMed

    Khan, Naeem; Bano, Asghari

    2016-01-01

    The investigation evaluated the role of plant growth promoting rhizobacteria (PGPR) and Ag-nano particle on the growth and metabolism of maize irrigated with municipal wastewater (MW). Three PGPR isolated from MW were identified on the basis of 16S-rRNA gene sequence analyses as Pseudomonas sp., Pseudomonas fluorescence, and Bacillus cereus. The municipal waste water was used to irrigate the maize seeds inoculated with 3 isolated PGPR. The isolated PGPR had catalase and oxidase enzymes, solubilize insoluble bound phosphate and exhibit antifungal and antibacterial activities. The colony forming unit (cfu) of the PGPR was inhibited by Ag-nano particle, but was stimulated by the municipal wastewater. The Ag-nano particles augmented the PGPR induced increase in root area and root length. The root-shoot ratio was also changed with the Ag-nano particles. The plants irrigated with municipal wastewater had higher activities of peroxidase and catalase which were further augmented by Ag-nano particle. The Ag- nano particle application modulated level of ABA (34%), IAA (55%), and GA (82%), increased proline production (70%) and encountered oxidative stress and augmented the bioremediation potential of PGPR for Pb, Cd, and Ni. Municipal wastewater needs to be treated with PGPR and Ag nano particle prior to be used for irrigation. This aims for the better growth of the plant and enhanced bioremediation of toxic heavy metals. PMID:26507686

  16. Ag-SHEATHED Bi2Sr2CaCu2O8 Square Wire Insulated with Oxidized Hastelloy Fiber Braid

    NASA Astrophysics Data System (ADS)

    Watanabe, K.; Nishijima, G.; Awaji, S.; Hikichi, Y.; Hasegawa, T.

    2008-03-01

    Oxidized Hastelloy X (Hx) fiber braid has been demonstrated to work well as a good electric insulation of Ag-sheathed Bi2Sr2CaCu2O8 (Ag/Bi2212) wires. In order to develop a wind-and-react processed Ag/Bi2212 superconducting magnet with a high coil current density, we fabricated a test coil employing 45 m long Ag/Bi2212 square shape wire with 50 μm Hx fiber braid. A test coil, whose size is 73 mm outer diameter, 64.5 mm inner diameter, and 74 mm coil winding height, consisted of 4 layers and 210 turns, and was heat-treated at around 890 °C in oxygen gas. The critical current Ic of the test coil was 245 A at 4.2 K in a self-field, corresponding to a 67% value of the short sample Ic heat-treated at the same time for comparison. Coil inductance was calculated to be 1.9 mH, and as a result, the same inductance value was obtained in the test coil. It was found that a Hx cloth knitting method enables us to insulate sufficiently between wires in Ag/Bi2212 square shape wire.

  17. Photocatalytic Properties of Silver Core/Titania Shell Nano-Wires Grown on a Glass Substrate Using a Glycothermal Process Assisted by a Photochemical Reaction.

    PubMed

    Song, Duck-Hyun; Hirato, Tetsuji

    2015-07-01

    A silver core/titania shell nano-wire film was successfully prepared on a glass substrate via a glycothermal process that was assisted by a photochemical reaction using tetra-n-butyl titanate as the titanium source and silver nitrate as the silver source in an autoclave with ethylene glycol as a solvent. The morphology, diameter, length, and density of the core/shell nano-wires that were synthesized could be varied by changing the silver/titanium molar ratio of the starting materials. The samples produced were characterized by X-ray diffraction and scanning electron microscopy. The photocatalytic activity of the silver core/titania shell nano-wire film was investigated by measuring the photodegradation rate of rhodamine B in aqueous solution. PMID:26373082

  18. Recent Progress in High Performance Ag-Sheathed Bi2223 Wire (DI-BSCCO®)

    NASA Astrophysics Data System (ADS)

    Kagiyama, T.; Yamazaki, K.; Kikuchi, M.; Yamade, S.; Nakashima, T.; Kobayashi, S.; Hayashi, K.; Sato, K.; Shimoyama, J.; Inoue, M.; Higashikawa, K.; Kiss, T.; Kitaguchi, H.; Kumakura, H.

    2011-10-01

    Sumitomo Electric has been developing the silver-sheathed Bi2223 multi-filamentary wires since the discovery of Bi-based superconductors. DI-BSCCO is the high performance wires produced using the controlled-overpressure (CT-OP) sintering technique. The present commercial DI-BSCCO can provide the uniform high critical current, Ic, up to 180 A with length over 2000 m, and recently 200 A were succeeded to be obtained by the same kind of 1000 m length wires, resulting from the improvement and control of the microstructure in Bi2223 multi-filaments. The short trial wires of several meters have exhibited the highest Ic over 240 A at 77K in self-field (corresponding to 580 A per 1 cm-width). Besides, the optimization of carrier density after CT-OP led to further enhancement of Ic, reached 250 A. All the derivative products also have uniform critical current properties over entire length even after lamination with the reinforcing metals. The performances of DI-BSCCO can meet the growing needs for various application of high temperature superconductor like high in-field applications, such as magnets and motors. The recent progress in transport properties of commercial DI-BSCCO and R&D short trial wires is shown.

  19. Measurement of the Mutual Coherence Function of an Incoherent Infrared Field with a Gold Nano-wire Dipole Antenna Array

    NASA Astrophysics Data System (ADS)

    Middlebrook, Christopher; Roggemann, Michael; Boreman, Glenn; Subotic, Nikola; Cooper, Kyle; Buller, William; Yang, Weidong; Alda, Javier

    2008-02-01

    The first direct measurement of the mutual coherence function of a spatially incoherent infrared beam was performed at 10.6 μm using a pair of infrared dipole nano-wire antennas that were connected to a common bolometer in the center of the pair by short lengths of coplanar strip transmission line. A spatially incoherent source was constructed by dithering a BaF2 diffuser near the focus of a CO2 laser beam. The distance from the diffuser to the nano-wire antenna pair was held constant while the distance from the focus of the laser beam to the diffuser was varied to control the effective diameter of the source. The measured bolometer signal was proportional to the magnitude of the mutual coherence function at the plane of the antennas. The experimental results were found to match the predicted performance closely. If this technology can be extended to large arrays, a form of synthetic aperture optical imaging based on the Van Cittert-Zernike theorem is possible, similar to that performed at microwave frequencies now by astronomers. This has the potential to greatly increase the angular resolution attainable with optical instruments.

  20. Phase constitution and interface structure of nano-sized Ag-Cu/AlN multilayers: Experiment and ab initio modeling

    SciTech Connect

    Pigozzi, Giancarlo; Janczak-Rusch, Jolanta; Passerone, Daniele; Antonio Pignedoli, Carlo; Patscheider, Joerg; Jeurgens, Lars P. H.; Antusek, Andrej; Parlinska-Wojtan, Magdalena; Bissig, Vinzenz

    2012-10-29

    Nano-sized Ag-Cu{sub 8nm}/AlN{sub 10nm} multilayers were deposited by reactive DC sputtering on {alpha}-Al{sub 2}O{sub 3}(0001) substrates. Investigation of the phase constitution and interface structure of the multilayers evidences a phase separation of the alloy sublayers into nanosized grains of Ag and Cu. The interfaces between the Ag grains and the quasi-single-crystalline AlN sublayers are semi-coherent, whereas the corresponding Cu/AlN interfaces are incoherent. The orientation relationship between Ag and AlN is constant throughout the entire multilayer stack. These observations are consistent with atomistic models of the interfaces as obtained by ab initio calculations.

  1. Nano-crystalline Ag-PbTe thermoelectric thin films by a multi-target PLD system

    NASA Astrophysics Data System (ADS)

    Cappelli, E.; Bellucci, A.; Medici, L.; Mezzi, A.; Kaciulis, S.; Fumagalli, F.; Di Fonzo, F.; Trucchi, D. M.

    2015-05-01

    It has been evaluated the ability of ArF pulsed laser ablation to grow nano-crystalline thin films of high temperature PbTe thermoelectric material, and to obtain a uniform and controlled Ag blending, through the entire thickness of the film, using a multi-target system in vacuum. The substrate used was a mirror polished technical alumina slab. The increasing atomic percentage of Ag effect on physical-chemical and electronic properties was evaluated in the range 300-575 K. The stoichiometry and the distribution of the Ag component, over the whole thickness of the samples deposited, have been studied by XPS (X-ray photoelectron spectroscopy) and corresponding depth profiles. The crystallographic structure of the film was analyzed by grazing incidence X-ray diffraction (GI-XRD) system. Scherrer analysis for crystallite size shows the presence of nano-structures, of the order of 30-35 nm. Electrical resistivity of the samples, studied by the four point probe method, as a function of increasing Ag content, shows a typical semi-conductor behavior. From conductivity values, carrier concentration and Seebeck parameter determination, the power factor of deposited films was calculated. Both XPS, Hall mobility and Seebeck analysis seem to indicate a limit value to the Ag solubility of the order of 5%, for thin films of ∼200 nm thickness, deposited at 350 °C. These data resulted to be comparable to theoretical evaluation for thin films but order of magnitude lower than the corresponding bulk materials.

  2. Optimization, Yield Studies and Morphology of WO3Nano-Wires Synthesized by Laser Pyrolysis in C2H2and O2Ambients—Validation of a New Growth Mechanism

    PubMed Central

    2008-01-01

    Laser pyrolysis has been used to synthesize WO3nanostructures. Spherical nano-particles were obtained when acetylene was used to carry the precursor droplet, whereas thin films were obtained at high flow-rates of oxygen carrier gas. In both environments WO3nano-wires appear only after thermal annealing of the as-deposited powders and films. Samples produced under oxygen carrier gas in the laser pyrolysis system gave a higher yield of WO3nano-wires after annealing than the samples which were run under acetylene carrier gas. Alongside the targeted nano-wires, the acetylene-ran samples showed trace amounts of multi-walled carbon nano-tubes; such carbon nano-tubes are not seen in the oxygen-processed WO3nano-wires. The solid–vapour–solid (SVS) mechanism [B. Mwakikunga et al., J. Nanosci. Nanotechnol., 2008] was found to be the possible mechanism that explains the manner of growth of the nano-wires. This model, based on the theory from basic statistical mechanics has herein been validated by length-diameter data for the produced WO3nano-wires.

  3. Copper Nano- and Micro Wires Electrodeposited in Etched Cellulose Nitrate and Makrofol KG Nuclear Track Detector

    NASA Astrophysics Data System (ADS)

    Jooybari, B. Shakeri; Afarideh, H.; Lamehi-Racti, M.; Moghimi, R.; Ghergherehchi, M.

    Cellulose Nitrate and Makrofol KG nuclear track detector foils of 96 μm and 20 μm thicknesses were irradiated with 238U ions (kinetic energy 17.7 MeV/u, fluence 105 ion/cm2) and 208Pd (kinetic energy 14.0MeV/u, fluence 105 ion/cm2), respectively. By etching of damage trail caused by the ion, templates containing conical pore were prepared. By electrochemical deposition of copper in homemade design electrolytic cell, conical wires were obtained. The electric current recorded during electrodeposition reflects the geometry of the pore. The lengths of wires were 96 μm and 20 μm, corresponding to the thickness of membranes. X-Ray Diffraction analysis indicated that texture and orientation of Cu wire were polycrystalline.

  4. Effect of addition of Ag nano powder on mechanical properties of epoxy/polyaminoamide adduct coatings filled with conducting polymer

    SciTech Connect

    Samad, Ubair Abdus; Khan, Rawaiz; Alam, Mohammad Asif; Al-Othman, Othman Y.; Al-Zahrani, Saeed M.

    2015-05-22

    In this study the effect of Ag Nano powder on mechanical properties of epoxy coatings filled with optimized ratio of conducting polymers (Polyaniline and Polyppyrole) was evaluated. Bisphenol A diglycidyl ether epoxy resin (DGEBA) along with polyaminoamide adduct (ARADUR 3282-1 BD) is used as curing agent under optimized stoichiometry values. Curing is performed at room temperature with different percentages of Nano filler. Glass and steel panels were used as coating substrate. Bird applicator was used to coat the samples in order to obtain thin film with wet film thickness (WFT) of about 70-90 µm. The samples were kept in dust free environment for about 7 days at room temperature for complete curing. The coated steel panels were used to evaluate the mechanical properties of coating such as hardness, scratch and impact tests whereas coated glass panels were used for measuring pendulum hardness of the coatings. To check the dispersion and morphology of Nano filler in epoxy matrix scanning electron microscopy (SEM) was used in addition Nano indentation was also performed to observe the effect of Nano filler on modulus of elasticity and hardness at Nano scale.

  5. Effect of addition of Ag nano powder on mechanical properties of epoxy/polyaminoamide adduct coatings filled with conducting polymer

    NASA Astrophysics Data System (ADS)

    Samad, Ubair Abdus; Khan, Rawaiz; Alam, Mohammad Asif; Al-Othman, Othman Y.; Al-Zahrani, Saeed M.

    2015-05-01

    In this study the effect of Ag Nano powder on mechanical properties of epoxy coatings filled with optimized ratio of conducting polymers (Polyaniline and Polyppyrole) was evaluated. Bisphenol A diglycidyl ether epoxy resin (DGEBA) along with polyaminoamide adduct (ARADUR 3282-1 BD) is used as curing agent under optimized stoichiometry values. Curing is performed at room temperature with different percentages of Nano filler. Glass and steel panels were used as coating substrate. Bird applicator was used to coat the samples in order to obtain thin film with wet film thickness (WFT) of about 70-90 µm. The samples were kept in dust free environment for about 7 days at room temperature for complete curing. The coated steel panels were used to evaluate the mechanical properties of coating such as hardness, scratch and impact tests whereas coated glass panels were used for measuring pendulum hardness of the coatings. To check the dispersion and morphology of Nano filler in epoxy matrix scanning electron microscopy (SEM) was used in addition Nano indentation was also performed to observe the effect of Nano filler on modulus of elasticity and hardness at Nano scale.

  6. Enhancement in biological response of Ag-nano composite polymer membranes using plasma treatment for fabrication of efficient bio materials

    NASA Astrophysics Data System (ADS)

    Agrawal, Narendra Kumar; Sharma, Tamanna Kumari; Chauhan, Manish; Agarwal, Ravi; Vijay, Y. K.; Swami, K. C.

    2016-05-01

    Biomaterials are nonviable material used in medical devices, intended to interact with biological systems, which are becoming necessary for the development of artificial material for biological systems such as artificial skin diaphragm, valves for heart and kidney, lenses for eye etc. Polymers having novel properties like antibacterial, antimicrobial, high adhesion, blood compatibility and wettability are most suitable for synthesis of biomaterial, but all of these properties does not exist in any natural or artificial polymeric material. Nano particles and plasma treatment can offer these properties to the polymers. Hence a new nano-biomaterial has been developed by modifying the surface and chemical properties of Ag nanocomposite polymer membranes (NCPM) by Argon ion plasma treatment. These membranes were characterized using different techniques for surface and chemical modifications occurred. Bacterial adhesion and wettability were also tested for these membranes, to show direct use of this new class of nano-biomaterial for biomedical applications.

  7. Laser flash-Raman spectroscopy method for the measurement of the thermal properties of micro/nano wires.

    PubMed

    Liu, Jinhui; Wang, Haidong; Hu, Yudong; Ma, Weigang; Zhang, Xing

    2015-01-01

    This paper introduces a new method for measuring the thermal diffusivity and thermal conductivity of individual micro/nano wires using Raman spectroscopy. This method uses a focused short pulsed laser and a continuous-wave laser in a Raman spectroscopy system as the local heater, Raman signal excitation source, and temperature sensor. Unsteady and steady thermal conduction models are used to get two independent equations for the thermal diffusivity (α) and laser absorptivity (η). This new method is verified by comparing experimental results for graphite carbon fiber with measurement using the 3ω method. The method was then used to measure the temperature dependent thermal diffusivity and thermal conductivity of individual carbon nanotubes. PMID:25638107

  8. Frequency dependent electrical properties of nano-CdS/Ag junctions

    NASA Astrophysics Data System (ADS)

    Mohanta, D.; Choudhury, A.

    2005-05-01

    Polymer embedded cadmium sulfide nanoparticles/quantum dots were synthesized by a chemical route using polyvinyl alcohol (lmw) as the desired matrix. In an attempt to measure the electrical properties of nano-CdS/Ag samples, we propose that contribution from surface traps are mainly responsible in determining the I˜ V and C˜ V characteristics in high frequency ranges. To be specific, beyond 1.2 MHz, the carrier injection from the trap centers of the embedded quantum dots is ensured by large current establishment even at negative biasing condition of the junction. The unexpected nonlinear signature of C˜ V response is believed to be due to the fact that while trying to follow very high signal frequency (at least 10-3 of recombination frequency), there is complete abruptness in carrier trapping (charging) or/and detrapping (decay) in a given CdS nanoparticle assembly. The frequency dependent unique role of the trap carriers certainly find application in nanoelectronic devices at a desirable frequency of operation.

  9. Morphology-controlled synthesis of Ag{sub 3}PO{sub 4} nano/microcrystals and their antibacterial properties

    SciTech Connect

    Wu, Aiping; Tian, Chungui; Chang, Wei; Hong, Yu; Zhang, Qi; Qu, Yang; Fu, Honggang

    2013-09-01

    Graphical abstract: The Ag{sub 3}PO{sub 4} with rhombic dodecahedral, spherical and small size particles were controllable fabricated just by changing the types of the solvent. The materials possess good antibacterial properties toward different kinds of bacteria. - Highlights: • The Ag{sub 3}PO{sub 4} with three morphologies were controllable fabricated. • The Ag{sub 3}PO{sub 4} as-prepared possess obvious antibacterial properties in the dark. • The antibacterial ability of Ag{sub 3}PO{sub 4} could be greatly improved under the visible light irradiation. - Abstract: We reported the controllable fabrication of Ag{sub 3}PO{sub 4} nano/microcrystals through a simple solution-based precipitation reaction. The samples were characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The results indicated that the Ag{sub 3}PO{sub 4} crystals with three different morphology, including the rhombic dodecahedron of 500 nm, the sphere of 100 nm and the particles with small-size of 20 nm, could be obtained in the solvents of water, ethylene glycol (EG) and dimethyl sulfoxide (DMSO). The antibacterial assay showed that all samples possess obvious antibacterial properties. In addition, the Ag{sub 3}PO{sub 4} with small size of 20 nm showed better activity due to their high specific surface areas. Notably, we have found that the antibacterial ability of Ag{sub 3}PO{sub 4} could be greatly improved under the visible light irradiation, which are superior to that in the dark and commercial streptomycin.

  10. An oil-in-water self-assembly synthesis, characterization and photocatalytic properties of nano Ag@AgCl surface-sensitized K{sub 2}Ti{sub 4}O{sub 9}

    SciTech Connect

    Liang, Yinghua; Lin, Shuanglong; Liu, Li Hu, Jinshan; Cui, Wenquan

    2014-12-15

    Highlights: • The plasmatic Ag@AgCl surface-sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts. • Ag@AgCl greatly increased visible light absorption for K{sub 2}Ti{sub 4}O{sub 9}. • The photocatalysts exhibited enhanced photocatalytic dye degradation. - Abstract: Nano-sized plasmonic Ag@AgCl surface-sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts (hereafter designated as Ag@AgCl/K{sub 2}Ti{sub 4}O{sub 9}) was synthesized via a facile oil-in-water self-assembly method. The photocatalytic activity of the prepared materials for RhB (Rhodamine B) degradation was examined under visible light irradiation. The results reveal that the size of Ag@AgCl, which evenly dispersed on the surface of K{sub 2}Ti{sub 4}O{sub 9}, distributes about 20–50 nm. The UV–vis diffuse reflectance spectra indicate that Ag@AgCl/K{sub 2}Ti{sub 4}O{sub 9} samples have a significantly enhanced optical absorption in 380–700 nm. The photocatalytic activities of the Ag@AgCl/K{sub 2}Ti{sub 4}O{sub 9} samples increase first and then decrease with increasing amount of loading Ag@AgCl and the Ag@AgCl(20 wt.%)/K{sub 2}Ti{sub 4}O{sub 9} sample exhibits the best photocatalytic activity and 94.47% RhB was degraded after irradiation for 2 h. Additionally, studies performed using radical scavengers indicated that O{sub 2}·{sup −} and Cl{sup 0} acted as the main reactive species. The electronic interaction was systematically studied and confirmed by the photo-electrochemical measurements.

  11. Ferrocene-1,1'-dithiol as molecular wire between Ag electrodes: The role of surface defects

    NASA Astrophysics Data System (ADS)

    Bredow, T.; Tegenkamp, C.; Pfnür, H.; Meyer, J.; Maslyuk, V. V.; Mertig, I.

    2008-02-01

    The interaction of ferrocene-1,1'-dithiol (FDT) with two parallel Ag(111) surfaces has been theoretically studied at density-functional level. The effect of surface defects on the energetic and electronic structure was investigated. The electronic transport properties are studied with the nonequilibrium Green's function approach. The adsorption geometry has a strong effect on the electronic levels and conductivity. The presence of point defects strongly enhances the molecule-surface interaction but has a surprisingly small effect on the density of states near the Fermi energy. The FDT-surface bond is particularly strong near terraces or steps and leads to significant shifts of the molecular orbitals relative to the gas phase. For all considered defect types except the single adatom the electronic conductivity through the FDT molecule is decreased compared to adsorption on perfect surfaces.

  12. Magnetic properties and irreversibility behavior in Ag-sheathed Bi-based superconducting wires fabricated using a controlled melt procedure

    SciTech Connect

    Dou, S.X.; Liu, H.K.; Guo, Y.C.; Shi, D.L.; Sumption, M.D.; Collings, E.W.

    1992-12-01

    A significant enhancement of the in-field J{sub c} of Ag-clad (Bi,Pb)-Sr-Ca-Cu-0 (BPSCCO:2223) wires has been achieved using a controlled melt procedure. The greatly reduced weak linking has resulted in an extended plateau regime in the J{sub c}-H curve. J{sub c}s of 40,000 A/cm{sup 2} at 77 K (self field) and 9,000 A/cm{sup 2} at 77 K (1 T) have been achieved. The improved J. H characteristics may be attributed to microstructures consisting of uniform grain alignment throughout the entire cross section, intimate connection between grains, impurities within the grains, and an optimal level of dispersed 2212 phase. Irreversibility line measurements using both AC susceptibility in DC fields (reported elsewhere), and magnetization measurements, have indicated that flux pinning can be enhanced in the melt-processed samples over the results of normal solid-state processing with its less-than optimal 2212-phase content. But sufficiently long annealing times during the ``normal`` route may achieve 2212-phase content and J{sub c}s which are comparable to those of melt-processed samples.

  13. Magnetic properties and irreversibility behavior in Ag-sheathed Bi-based superconducting wires fabricated using a controlled melt procedure

    SciTech Connect

    Dou, S.X.; Liu, H.K.; Guo, Y.C. . School of Materials Science and Engineering); Shi, D.L. ); Sumption, M.D.; Collings, E.W. )

    1992-12-01

    A significant enhancement of the in-field J[sub c] of Ag-clad (Bi,Pb)-Sr-Ca-Cu-0 (BPSCCO:2223) wires has been achieved using a controlled melt procedure. The greatly reduced weak linking has resulted in an extended plateau regime in the J[sub c]-H curve. J[sub c]s of 40,000 A/cm[sup 2] at 77 K (self field) and 9,000 A/cm[sup 2] at 77 K (1 T) have been achieved. The improved J. H characteristics may be attributed to microstructures consisting of uniform grain alignment throughout the entire cross section, intimate connection between grains, impurities within the grains, and an optimal level of dispersed 2212 phase. Irreversibility line measurements using both AC susceptibility in DC fields (reported elsewhere), and magnetization measurements, have indicated that flux pinning can be enhanced in the melt-processed samples over the results of normal solid-state processing with its less-than optimal 2212-phase content. But sufficiently long annealing times during the normal'' route may achieve 2212-phase content and J[sub c]s which are comparable to those of melt-processed samples.

  14. Micro- and nano- second time scale, high power electrical wire explosions in water.

    NASA Astrophysics Data System (ADS)

    Grinenko, Alon; Efimov, Sergey; Sayapin, Arkadii; Fedotov, Alexander; Gurovich, Viktor; Krasik, Yakov

    2006-10-01

    Experimental and magneto-hydro-dynamic simulation results of micro- and nanosecond time scale underwater electrical Al, Cu and W wires explosions are presented. A capacitor bank with stored energy up to 6 kJ (discharge current up to 80 kA with 2.5 μs quarter period) was used in microsecond time scale experiments and water forming line generator with current amplitude up to 100 kA and pulse duration of 100 ns were used in nanosecond time scale experiments. Extremely high energy deposition of up to 60 times the atomization enthalpy was registered in nanosecond time scale explosions. A discharge channel evolution and surface temperature were analyzed by streak shadow imaging and using fast photo-diode with a set of interference filters, respectively. Microsecond time scale electrical explosion of cylindrical wire array showed extremely high pressure of converging shock waves at the axis, up to 0.2 MBar. A 1D and 2D magneto-hydro-dynamic simulation demonstrated good agreement with such experimental parameters as discharge channel current, voltage, radius, and temperature.

  15. Highly sensitive, localized surface plasmon resonance fiber device for environmental sensing, based upon a structured bi-metal array of nano-wires.

    PubMed

    Allsop, Thomas; Neal, Ron; Chengbo, Mou; Kalli, Kyriacos; Webb, David

    2014-10-15

    We demonstrate a bi-metal coated (platinum and gold or silver), localized surface plasmon resonance fiber sensor with an index sensitivity exceeding 11,900 nm/RIU, yielding an index resolution of 2×10⁻⁵ in the aqueous index regime. This is one of the highest index sensitivities achieved with an optical fiber sensor. The coatings consist of arrays of bi-metal nano-wires (typically 36 nm in radius and 20 μm in length), supported by a silicon dioxide thin film on a thin substrate of germanium, the nano-wires being perpendicular to the longitudinal axis of the D-shaped fiber. PMID:25361088

  16. All-optical switching in silicon-on-insulator photonic wire nano-cavities.

    PubMed

    Belotti, Michele; Galli, Matteo; Gerace, Dario; Andreani, Lucio Claudio; Guizzetti, Giorgio; Md Zain, Ahmad R; Johnson, Nigel P; Sorel, Marc; De La Rue, Richard M

    2010-01-18

    We report on experimental demonstration of all-optical switching in a silicon-on-insulator photonic wire nanocavity operating at telecom wavelengths. The switching is performed with a control pulse energy as low as approximately 0.1 pJ on a cavity device that presents very high signal transmission, an ultra-high quality-factor, almost diffraction-limited modal volume and a footprint of only 5 microm(2). High-speed modulation of the cavity mode is achieved by means of optical injection of free carriers using a nanosecond pulsed laser. Experimental results are interpreted by means of finite-difference time-domain simulations. The possibility of using this device as a logic gate is also demonstrated. PMID:20173973

  17. Nano-Ag-loaded hydroxyapatite coatings on titanium surfaces by electrochemical deposition

    PubMed Central

    Lu, Xiong; Zhang, Bailin; Wang, Yingbo; Zhou, Xianli; Weng, Jie; Qu, Shuxin; Feng, Bo; Watari, Fumio; Ding, Yonghui; Leng, Yang

    2011-01-01

    Hydroxyapatite (HA) coatings on titanium (Ti) substrates have attracted much attention owing to the combination of good mechanical properties of Ti and superior biocompatibility of HA. Incorporating silver (Ag) into HA coatings is an effective method to impart the coatings with antibacterial properties. However, the uniform distribution of Ag is still a challenge and Ag particles in the coatings are easy to agglomerate, which in turn affects the applications of the coatings. In this study, we employed pulsed electrochemical deposition to co-deposit HA and Ag simultaneously, which realized the uniform distribution of Ag particles in the coatings. This method was based on the use of a well-designed electrolyte containing Ag ions, calcium ions and l-cysteine, in which cysteine acted as the coordination agent to stabilize Ag ions. The antibacterial and cell culture tests were used to evaluate the antibacterial properties and biocompatibility of HA/Ag composite coatings, respectively. The results indicated the as-prepared coatings had good antibacterial properties and biocompatibility. However, an appropriate silver content should be chosen to balance the biocompatibility and antibacterial properties. Heat treatments promoted the adhesive strength and enhanced the biocompatibility without sacrificing the antibacterial properties of the HA/Ag coatings. In summary, this study provided an alternative method to prepare bioactive surfaces with bactericidal ability for biomedical devices. PMID:20880853

  18. A Visible-Light-Induced α-H Chlorination of Alkylarenes with Inorganic Chloride under NanoAg@AgCl.

    PubMed

    Liu, Shouxin; Zhang, Qi; Li, Huiying; Yang, Yihua; Tian, Xia; Whiting, Andrew

    2015-06-26

    An efficient, photocatalytic chlorination of alkylarene α-H groups using NaCl/HCl as a chlorine source has been developed, which involves a radical mechanism under visible-light (including sunlight) conditions. A chlorine radical is proposed to be formed by an electron transfer from chloride ion to O2 in air through the bandgap hole of the semiconductor AgCl. The chlorination protocol is characterized by its use of natural sunlight or other visible light, mild conditions, cheap source of chlorine, green solvent, and high selectivity. The yield of benzylchloride is 95% with a toluene conversion as high as 40%, which rivals traditional chlorination methods. PMID:26061749

  19. Omnidirectional color filters capitalizing on a nano-resonator of Ag-TiO2-Ag integrated with a phase compensating dielectric overlay.

    PubMed

    Park, Chul-Soon; Shrestha, Vivek Raj; Lee, Sang-Shin; Kim, Eun-Soo; Choi, Duk-Yong

    2015-01-01

    We present a highly efficient omnidirectional color filter that takes advantage of an Ag-TiO2-Ag nano-resonator integrated with a phase-compensating TiO2 overlay. The dielectric overlay substantially improves the angular sensitivity by appropriately compensating for the phase pertaining to the structure and suppresses unwanted optical reflection so as to elevate the transmission efficiency. The filter is thoroughly designed, and it is analyzed in terms of its reflection, optical admittance, and phase shift, thereby highlighting the origin of the omnidirectional resonance leading to angle-invariant characteristics. The polarization dependence of the filter is explored, specifically with respect to the incident angle, by performing experiments as well as by providing the relevant theoretical explanation. We could succeed in demonstrating the omnidirectional resonance for the incident angles ranging to up to 70°, over which the center wavelength is shifted by below 3.5% and the peak transmission efficiency is slightly degraded from 69%. The proposed filters incorporate a simple multi-layered structure and are expected to be utilized as tri-color pixels for applications that include image sensors and display devices. These devices are expected to allow good scalability, not requiring complex lithographic processes. PMID:25683162

  20. Omnidirectional color filters capitalizing on a nano-resonator of Ag-TiO2-Ag integrated with a phase compensating dielectric overlay

    PubMed Central

    Park, Chul-Soon; Shrestha, Vivek Raj; Lee, Sang-Shin; Kim, Eun-Soo; Choi, Duk-Yong

    2015-01-01

    We present a highly efficient omnidirectional color filter that takes advantage of an Ag-TiO2-Ag nano-resonator integrated with a phase-compensating TiO2 overlay. The dielectric overlay substantially improves the angular sensitivity by appropriately compensating for the phase pertaining to the structure and suppresses unwanted optical reflection so as to elevate the transmission efficiency. The filter is thoroughly designed, and it is analyzed in terms of its reflection, optical admittance, and phase shift, thereby highlighting the origin of the omnidirectional resonance leading to angle-invariant characteristics. The polarization dependence of the filter is explored, specifically with respect to the incident angle, by performing experiments as well as by providing the relevant theoretical explanation. We could succeed in demonstrating the omnidirectional resonance for the incident angles ranging to up to 70°, over which the center wavelength is shifted by below 3.5% and the peak transmission efficiency is slightly degraded from 69%. The proposed filters incorporate a simple multi-layered structure and are expected to be utilized as tri-color pixels for applications that include image sensors and display devices. These devices are expected to allow good scalability, not requiring complex lithographic processes. PMID:25683162

  1. Nano Ag-enhanced energy conversion efficiency in standard commercial pc-Si solar cells and numerical simulations with finite difference time domain method

    NASA Astrophysics Data System (ADS)

    Yu, Jing; Shao, Weijia; Zhou, Yao; Wang, Huijie; Liu, Xiao; Xu, Xiaoliang

    2013-11-01

    Nano Ag-enhanced energy conversion efficiency (ECE) in one standard commercial pc-Si solar cell utilizing the forward scattering by Ag nanoparticles on surface has been researched experimentally and simulatively in this paper. Directly assembling Ag nanoparticles (with size about 100 nm) on the surface, it is found when the particle surface coverage is 10%, the ECE and the short circuit current density are increased by 2.8% and 1.4%, respectively. Without changing any existing structure of the ready-made solar cell, this facile and efficient method has huger applications than other methods.

  2. Electronic structure of Ag-induced atomic wires on Si(5 5 7) investigated by STS and angle-resolved photoemission

    NASA Astrophysics Data System (ADS)

    Morikawa, Harumo; Kang, Pil Gyu; Yeom, Han Woong

    2008-12-01

    One-dimensional (1D) superstructures on the Si(5 5 7) surface induced by Ag adsorption have been investigated by scanning tunneling microscopy/spectroscopy (STM/STS) and angle-resolved photoemission. The deposition of ˜0.3 ML of Ag at 450-620 °C yields three different kinds of 1D structures along step edges. These structures form domains of different morphology, whose areal ratio depends on the growth temperature. They commonly share a characteristic atomic-scale wire structure with a ×2 periodicity. These structures are insulating with a band gap of about 0.5 eV as revealed by STS and confirmed consistently by angle-resolved photoemission, in clear contrast to the very recent inverse photoemission result (Phys. Rev. B 77 (2008) 125419).

  3. Dual layer hollow fiber PVDF ultra-filtration membranes containing Ag nano-particle loaded zeolite with longer term anti-bacterial capacity in salt water.

    PubMed

    Shi, Huyan; Xue, Lixin; Gao, Ailin; Zhou, Qingbo

    2016-01-01

    Dual layer polyvinylidene fluoride (PVDF), antibacterial, hollow fiber, ultra-filtration composite membranes with antibacterial particles (silver (Ag) nano-particles loaded zeolite (Z-Ag)) in the outer layer were prepared with high water flux and desired pore sizes. The amounts of Ag(+) released from the composite membranes, freshly made and stored in water and salt solution, were measured. The result indicated that dual layer PVDF antibacterial hollow fiber containing Z-Ag (M-1-Ag) still possessed the ability of continuous release of Ag(+) even after exposure to water with high ionic content, showing a longer term resistance to bacterial adhesion and antibacterial activity than membrane doped with Z-Ag(+) (M-1). Results from an anti-adhesion and bacteria killing test with Escherichia coli supported that the antibacterial efficiency of dual hollow fiber PVDF membranes with Z-Ag was much higher than those with Z-Ag(+) after long time storage in water or exposure to phosphate buffered saline (PBS) solution. This novel hollow fiber membrane may find applications in constructing sea water pretreatment devices with long term antifouling capability for the desalination processes. PMID:27148717

  4. A facile approach to prepare silicon-based Pt-Ag tubular dendritic nano-forests (tDNFs) for solar-light-enhanced methanol oxidation reaction.

    PubMed

    Lin, Chun-Ting; Shiao, Ming-Hua; Chang, Mao-Nan; Chu, Nancy; Chen, Yu-Wei; Peng, Yu-Hsuan; Liao, Bo-Huei; Huang, Hung Ji; Hsiao, Chien-Nan; Tseng, Fan-Gang

    2015-01-01

    In this paper, a facile two-step Galvanic replacement reaction (GRR) is proposed to prepare Pt-Ag tubular dendritic nano-forests (tDNFs) in ambient condition for enhancing methanol oxidation reaction (MOR) under solar illumination. In the first GRR, a homogeneous layer of silver dendritic nano-forests (DNFs) with 10 μm in thickness was grown on Si wafer in 5 min in silver nitride (AgNO3) and buffer oxide etchant (BOE) solution. In the second GRR, we utilized chloroplatinic acid (H2PtCl6) as the precursor for platinum (Pt) deposition to further transform the prepared Ag DNFs into Pt-Ag tDNFs. The catalytic performance and solar response of the Pt-Ag tDNFs toward methanol electro-oxidation are also studied by cyclic voltammetry (CV) and chronoamperometry (CA). The methanol oxidation current was boosted by 6.4% under solar illumination on the Pt-Ag tDNFs due to the induced localized surface plasmon resonance (LSPR) on the dendritic structure. Current results provide a cost-effective and facile approach to prepare solar-driven metallic electrodes potentially applicable to photo-electro-chemical fuel cells. PMID:25852370

  5. A facile approach to prepare silicon-based Pt-Ag tubular dendritic nano-forests (tDNFs) for solar-light-enhanced methanol oxidation reaction

    NASA Astrophysics Data System (ADS)

    Lin, Chun-Ting; Shiao, Ming-Hua; Chang, Mao-Nan; Chu, Nancy; Chen, Yu-Wei; Peng, Yu-Hsuan; Liao, Bo-Huei; Huang, Hung Ji; Hsiao, Chien-Nan; Tseng, Fan-Gang

    2015-02-01

    In this paper, a facile two-step Galvanic replacement reaction (GRR) is proposed to prepare Pt-Ag tubular dendritic nano-forests (tDNFs) in ambient condition for enhancing methanol oxidation reaction (MOR) under solar illumination. In the first GRR, a homogeneous layer of silver dendritic nano-forests (DNFs) with 10 μm in thickness was grown on Si wafer in 5 min in silver nitride (AgNO3) and buffer oxide etchant (BOE) solution. In the second GRR, we utilized chloroplatinic acid (H2PtCl6) as the precursor for platinum (Pt) deposition to further transform the prepared Ag DNFs into Pt-Ag tDNFs. The catalytic performance and solar response of the Pt-Ag tDNFs toward methanol electro-oxidation are also studied by cyclic voltammetry (CV) and chronoamperometry (CA). The methanol oxidation current was boosted by 6.4% under solar illumination on the Pt-Ag tDNFs due to the induced localized surface plasmon resonance (LSPR) on the dendritic structure. Current results provide a cost-effective and facile approach to prepare solar-driven metallic electrodes potentially applicable to photo-electro-chemical fuel cells.

  6. Enhancement of photo-response via surface plasmon resonance induced by Ag nano-particles embedded in ZnO

    NASA Astrophysics Data System (ADS)

    Li, Gaoming; Zhang, Jingwen; Chen, Guangde; Ye, Honggang; Duan, Xiangyang; Hou, Xun

    2016-09-01

    Surface plasmon resonance can be exploited to improve the performance of the photodetectors. However, it may cause the increase of dark current as a side effect. The enhancement of responsivity is highly dependent on the device structure involving SPR and the situations of the metal nano-particles. In this paper, we reported the responsivity enhancement of the ZnO UV detectors with SPR based on a structure in which Ag nano-particles are embedded in ZnO film, without the apparent increase of dark current. We found that the characteristic wavelength for SPR absorption is 380 nm, well predicted by Mie theory. And the spectral responsivity peak value increases from 472 mA/W to 10.522 A/W, by 22.3 times. The good matching between enhancement spectra and SPR absorption spectra confirms that the responsivity enhancement is resulted from SPR. Our results are of great importance in improving the photodetectors based on SPR effects, which may be widely used in light detection.

  7. Nano-Ag on vanadium dioxide. II. Thermal tuning of surface plasmon resonance

    NASA Astrophysics Data System (ADS)

    Xu, Gang; Huang, Chun-Ming; Tazawa, Masato; Jin, Ping; Chen, De-Ming

    2008-09-01

    Thermal tuning of the localized surface plasmon resonance (LSPR) of Ag nanoparticles on a thermochromic thin film of VO2 was studied experimentally. The tuning is strongly temperature dependent and thermally reversible. The LSPR wavelength λSPR shifts to the blue with increasing temperature from 30 to 80 °C, and shifts back to the red as temperature decreases. A smart tuning is achievable on condition that the temperature is controlled in a stepwise manner. The tunable wavelength range depends on the particle size or the mass thickness of the metal nanoparticle film. Further, the tunability was found to be enhanced significantly when a layer of TiO2 was introduced to overcoat the Ag nanoparticles, yielding a marked sensitivity factor ΔλSPR/Δn, of as large as 480 nm per refractive index unit (n) at the semiconductor phase of VO2.

  8. Pinning characteristics of domain wall in giant magnetoresistance spin valve stripe, consisting of a nano-wire and a circular ring.

    PubMed

    Yoon, Seungha; Jang, Youngman; Lee, Seungkyo; Cho, B K

    2011-07-01

    We investigated a technique for proving the pinning behaviors of a domain wall (DW) in spin-valve stripes with artificial configurations, which consist of a nano-wire, a large pad and sharp tip at the ends of the wire, and a circular ring at the center. It was found from the GMR measurement at various positions that a DW was pinned at a ring during DW's propagation from the side of pad to the side of tip. Micromagnetic simulation revealed that the initial onion magnetic states of the ring changes continuously to final reverse onion state via counterclockwise vortex state when a counterclockwise tail-to-tail DW pass through the ring. In addition, the simulation results indicated that the magnetic states at a circular ring were determined by the type and chirality of DW. We also studied the characteristics of domain wall motion in the same configuration, when the nano-ring was replaced with square and diamond structures. PMID:22121740

  9. Effect of temperature on the nano/microstructure and mechanical behavior of nanotwinned Ag films

    DOE PAGESBeta

    Zhang, Huan; Geng, Jie; Ott, Ryan T.; Besser, Matthew F.; Kramer, Matthew J.

    2015-06-24

    In situ and ex situ annealed nanotwinned (NT) Ag thin films have been investigated by TEM and tensile testing to reveal the thermal stability of the twin boundaries, grain boundaries, dislocation densities, and their respective influence of the macroscopic yield stress. The NT Ag films synthesized by magnetron sputtering form both coherent (CTB, Σ3{111}) and incoherent (ITB, Σ3{112}) twin boundaries that are thermally stable up to 473 K (200 Celsius), i.e., no obvious changes in grain size, twin spacing, and yield stress. In situ TEM observations show the dislocations become mobile at 453 K (180 Celsius) resulting in dislocation annihilationmore » primarily at twin and grain boundaries. Rotation of grains with low-angle grain boundaries was observed during in situ heating, resulting in the growth of columnar grains above 453 K (180 Celsius). However, no noticeable changes in the spacings of CTBs were observed during the entire in situ and ex situ annealing [up to 873 K (600 Celsius)]. The increase in grain size and concomitant decrease in yield stress following annealing at various temperatures can be described by the Hall-Petch relationship, demonstrating that grain size rather than twin spacing is most sensitive to thermal annealing and plays a dominant role in the deformation of NT Ag films.« less

  10. Effect of temperature on the nano/microstructure and mechanical behavior of nanotwinned Ag films

    SciTech Connect

    Zhang, Huan; Geng, Jie; Ott, Ryan T.; Besser, Matthew F.; Kramer, Matthew J.

    2015-06-24

    In situ and ex situ annealed nanotwinned (NT) Ag thin films have been investigated by TEM and tensile testing to reveal the thermal stability of the twin boundaries, grain boundaries, dislocation densities, and their respective influence of the macroscopic yield stress. The NT Ag films synthesized by magnetron sputtering form both coherent (CTB, Σ3{111}) and incoherent (ITB, Σ3{112}) twin boundaries that are thermally stable up to 473 K (200 Celsius), i.e., no obvious changes in grain size, twin spacing, and yield stress. In situ TEM observations show the dislocations become mobile at 453 K (180 Celsius) resulting in dislocation annihilation primarily at twin and grain boundaries. Rotation of grains with low-angle grain boundaries was observed during in situ heating, resulting in the growth of columnar grains above 453 K (180 Celsius). However, no noticeable changes in the spacings of CTBs were observed during the entire in situ and ex situ annealing [up to 873 K (600 Celsius)]. The increase in grain size and concomitant decrease in yield stress following annealing at various temperatures can be described by the Hall-Petch relationship, demonstrating that grain size rather than twin spacing is most sensitive to thermal annealing and plays a dominant role in the deformation of NT Ag films.

  11. Fabrication of an organic field effect transistor using nano imprinting of Ag inks and semiconducting polymers

    NASA Astrophysics Data System (ADS)

    Hu, PingAn; Li, Kun; Chen, Weilin; Peng, Li; Chu, Daping; O'Neill, William

    2010-07-01

    A simple and cheap procedure for flexible electronics fabrication was demonstrated by imprinting metallic nanoparticles (NPs) on flexible substrates. Silver NPs with an average diameter of 10 nm were prepared via an improved chemical approach and Ag Np ink was produced in α-terpineol with a concentration up to 15%. Silver micro/nanostructures with a dimension varying from nanometres to microns were produced on a flexible substrate (polyimide) by imprinting the as-prepared silver ink. The fine fluidic properties of an Ag NP/α-terpineol solution and low melting temperatures of silver nanoparticles render a low pressure and low temperature procedure, which is well suited for flexible electronics fabrication. The effects of sintering and mechanical bending on the conductivity of imprinted silver contacts were also investigated. Large area organic field effect transistors (OFET) on flexible substrates were fabricated using an imprinted silver electrode and semiconducting polymer. The OFET with silver electrodes imprinted from our prepared oleic acid stabilized Ag nanoparticle ink show an ideal ohmic contact; therefore, the OFET exhibit high performance (Ion/Ioff ratio: 1 × 103; mobility: 0.071 cm2 V-1 s-1).

  12. A micro-scale hot wire anemometer based on low stress (Ni/W) multi-layers deposited on nano-crystalline diamond for air flow sensing

    NASA Astrophysics Data System (ADS)

    Talbi, A.; Gimeno, L.; Gerbedoen, J.-C.; Viard, R.; Soltani, A.; Mortet, V.; Preobrazhensky, V.; Merlen, A.; Pernod, P.

    2015-12-01

    A linear array of microscale thermal anemometers has been designed, fabricated and characterized. The sensitive element consists of a self-compensated-stress multilayer (Ni/W) patterned to form a wire with length, width, and thickness close to 200 μm, 5 μm and 2 μm respectively. The wire is deposited and supported by prongs made of nano-crystalline diamond (NCD) of about 2 μm in thickness. Due to its high Young’s modulus, NCD allows a very high mechanical toughness without the need for thicker support for the hot wire. Also, depending on grain size, the NCD is able to present thermal conductivity smaller than 10 W mK-1, providing good thermal insulation from the substrate and less conductive end losses to the prongs. The sensor was characterized experimentally. Its electrical and thermal properties were obtained first in the absence of fluid flow. The results confirm the effectiveness of thermal insulation and the mechanical robustness of the structure. The fluidic characterizations were performed and analysed in the case of an airflow with velocities of up to 30 m s-1.

  13. A twin-free single-crystal Ag nanoplate plasmonic platform: hybridization of the optical nano-antenna and surface plasmon active surface

    NASA Astrophysics Data System (ADS)

    Lee, Hyoban; Jeong, Kwang-Yong; Kang, Taejoon; Seo, Min-Kyo; Kim, Bongsoo

    2013-12-01

    Surface plasmons based on metallic nanostructures enable light manipulation beyond the optical diffraction limit. We have epitaxially synthesized twin-free single-crystal Ag nanoplates on SrTiO3 substrates. Unlike the nanoplates synthesized in a solution phase, these nanoplates have perfectly clean surfaces as well as a quite large size of tens of micrometers. As-synthesized defect-free single-crystal Ag nanoplates have an atomically flat surface and sides with well-defined angles, allowing long distance propagation of surface plasmons and highly reliable plasmonic integration. By spatially separating receiving and transmitting antennas and plasmonically interfacing them, the signal quality of transmission/reception can be largely improved. Furthermore, by combining sub-dimensional nanostructures onto the two-dimensional space effective hierarchical plasmonic nano-complexes can be built up. Theoretical simulations well reproduced unique experimental results of coupling between SPPs and free-space radiation by the nanoplate antenna sides, low-loss long-range SPP propagation, and tunneling or scattering of SPPs at a nano-gap as well as a nano-structure introduced on the nanoplate. The single-crystal Ag nanoplate will find superb applications in plasmonic nano-circuitry and lab-on-a-chip for biochemical sensing.Surface plasmons based on metallic nanostructures enable light manipulation beyond the optical diffraction limit. We have epitaxially synthesized twin-free single-crystal Ag nanoplates on SrTiO3 substrates. Unlike the nanoplates synthesized in a solution phase, these nanoplates have perfectly clean surfaces as well as a quite large size of tens of micrometers. As-synthesized defect-free single-crystal Ag nanoplates have an atomically flat surface and sides with well-defined angles, allowing long distance propagation of surface plasmons and highly reliable plasmonic integration. By spatially separating receiving and transmitting antennas and plasmonically

  14. Si/Ag composite with bimodal micro-nano porous structure as a high-performance anode for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Hao, Qin; Zhao, Dianyun; Duan, Huimei; Zhou, Qiuxia; Xu, Caixia

    2015-03-01

    A one-step dealloying method is employed to conveniently fabricate a bimodal porous (BP) Si/Ag composite in high throughput under mild conditions. Upon dealloying the carefully designed SiAgAl ternary alloy in HCl solution at room temperature, the obtained Si/Ag composite has a uniform bicontinuous porous structure in three dimensions with micro-nano bimodal pore size distribution. Compared with the traditional preparation methods for porous Si and Si-based composites, this dealloying route is easily operated and environmentally benign. More importantly, it is convenient to realize the controllable components and uniform distribution of Si and Ag in the product. Owing to the rich porosity of the unique BP structure and the incorporation of highly conductive Ag, the as-made Si/Ag composite possesses the improved conductivity and alleviated volume changes of the Si network during repeated charging and discharging. As expected, the BP Si/Ag anode exhibits high capacity, excellent cycling reversibility, long cycling life and good rate capability for lithium storage. When the current rate is up to 1 A g-1, BP Si/Ag can deliver a stable reversible capacity above 1000 mA h g-1, and exhibits a capacity retention of up to 89.2% against the highest capacity after 200 cycles. With the advantages of unique performance and easy preparation, the BP Si/Ag composite holds great application potential as an advanced anode material for Li-ion batteries.A one-step dealloying method is employed to conveniently fabricate a bimodal porous (BP) Si/Ag composite in high throughput under mild conditions. Upon dealloying the carefully designed SiAgAl ternary alloy in HCl solution at room temperature, the obtained Si/Ag composite has a uniform bicontinuous porous structure in three dimensions with micro-nano bimodal pore size distribution. Compared with the traditional preparation methods for porous Si and Si-based composites, this dealloying route is easily operated and environmentally benign

  15. A density functional study of silver clusters on a stepped graphite surface: formation of self-assembled nano-wires.

    PubMed

    Singh, Akansha; Sen, Prasenjit

    2015-05-21

    Adsorption and diffusion of silver adatoms and clusters containing up to eight atoms on an HOPG substrate with an armchair step are studied using density functional methods. Step edges act as attractive sinks for adatoms and clusters. The diffusion barrier of an Ag adatom along the step edge is much larger than that on a clean terrace. At zero temperature, Ag clusters either distort or dissociate by forming covalent bonds with the edge C atoms. At 600 K, Ag5 and Ag8 clusters diffuse to the step edges, and then break up so as to maximize Ag-C bonds. The Ag atoms try to form a nanowire structure along the step edge. At such high temperatures, diffusion of clusters along the step edge involves diffusion of individual Ag atoms not bonded to the edge C atoms. Assumption of complete immobility of clusters trapped at step edges in the Gates-Robins model is not valid at high temperatures in this particular system. PMID:25903308

  16. Plasmon-enhanced photocatalytic properties of nano Ag@AgBr on single-crystalline octahedral Cu2O (1 1 1) microcrystals composite photocatalyst

    NASA Astrophysics Data System (ADS)

    Liu, Li; Lin, Shuanglong; Hu, Jinshan; Liang, Yinghua; Cui, Wenquan

    2015-03-01

    A new composite photocatalyst Ag@AgBr/Cu2O was prepared by loading Ag@AgBr on (1 1 1) facts of octahedral Cu2O substrate via a facile precipitation in situ photoreduction method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis), nitrogen sorption and the photoelectrochemical measurements. The results show that Ag@AgBr nanoparticles are well-dispersed on Cu2O nanoparticles with narrow size distributions and controllable sizes from 10 to 30 nm. TEM results of the as-synthesized Ag@AgBr/Cu2O nanocomposite revealed that Ag@AgBr nanoparticles were attached to the surface of octahedral Cu2O. Photocatalytic degradation of methylene blue (MB) was carried out to evaluate the photocatalytic activity of Ag@AgBr/Cu2O under visible-light irradiation. The Ag@AgBr/Cu2O composite showed stronger visible light absorption capacity and higher photocatalytic activity than pure Cu2O. The Ag@AgBr (15 wt.%)/Cu2O sample presented the best photocatalytic activity, degrading 93.28% MB after irradiation for 90 min, due to their high surface area (18.499 m2 g-1), the Crystal effect of Cu2O and surface plasmon resonance of Ag NPs. Meanwhile, phenol was degraded to further prove the degradation ability of Ag@AgBr/Cu2O. In addition, the quenching effect was examined in the photocatalytic reaction process of MB. Active h+, Br0 and the resulting rad O2- played the major roles for the dye degradation, while rad OH was verified to be insignificant. Based on the experimental results, a photocatalytic mechanism for organics degradation over Ag@AgBr/Cu2O photocatalysts was proposed. The electronic interactions were systematically studied and confirmed by the photoelectrochemical measurements.

  17. Assessment of modulated hot wire method for thermophysical characterization of fluid and solid matrices charged with (nano)particle inclusions

    NASA Astrophysics Data System (ADS)

    Chirtoc, M.; Henry, J. F.; Turgut, A.; Tavman, I.; Hadjov, K.; Schuchmann, H. P.; Sauter, C.; Antoniow, J. S.; Fudym, O.; Tavman, S.

    2010-03-01

    Recently we reported on simultaneous thermal conductivity k and thermal diffusivity a measurement of liquids and in particular of nanofluids in a configuration using an ac excited hot wire combined with lock-in detection of the third harmonic (3ω method) [1]. The conductive wire is used as both heater and sensor. The requirements for the asymptotic validity of the line heat source model are fulfilled at low modulation frequencies below a few Hz. The study of the relative sensitivity of signal amplitude and phase to changes in k and a indicates that there is an optimum frequency range for accurate and stable results. We extend by up to two decades the feasible frequency range for 3ω measurements by considering various more elaborate models for the heat transfer between the wire and the fluid. Finally we show that the same ac hot wire method can be applied to soft solid, composite materials. We measured the k enhancement of a poly(ethylene vinyl acetate) EVA polymer matrix charged with various fractions of graphite.

  18. Synthesis of silver nanoparticles deposited on silica by γ-irradiation and preparation of PE/Ag nano compound masterbatches

    NASA Astrophysics Data System (ADS)

    Nguyen, Thi Kim Lan; Trinh Nguyen, Thuy Ai; Phu Dang, Van; Duy Nguyen, Ngoc; Le, Anh Quoc; Hien Nguyen, Quoc

    2013-12-01

    Silver nanoparticles (AgNPs) deposited on silica were synthesized by gamma Co-60 irradiation of Ag+ dispersion in silica/ethanol/water mixture (9/80/20:w/v/v). The reduction of Ag+ is occurred by hydrated electron (e-aq) and hydrogen atom (H•) generated during radiolysis of ethanol/water. The conversion doses (Ag+ → Ag0) were determined by UV-Vis spectroscopy. The synthesized AgNPs/silica were characterized by transmission electron microscopy (TEM) and x-ray diffraction (XRD), which showed the size of AgNPs to be in the range of 5-40 nm for Ag+ concentrations from 5 to 20 mM. Masterbatches of PE/AgNPs/silica compound with silver content from 250 to 1000 mg kg-1 were also prepared. These masterbatches can be suitably used for various applications such as antimicrobial food containers and packing films, etc.

  19. Silver-sheathed multifilament wires

    NASA Astrophysics Data System (ADS)

    Wu, C. T.; Goretta, K. C.; Shi, D.; Lanagan, M. T.; Poeppel, R. B.

    1991-01-01

    The process for manufacturing Ag-sheathed multifilament superconducting wires was investigated. Bi2Sr(1.7)CaCu2O(x), Pb-doped Bi2Sr2Ca2Cu3O(x), or YBa2Cu3O(x) powders were packed into Ag tubes and swaged into long wires. Pieces were cut from each wire, packed into a second Ag tube and swaged or rolled into multifilament wires. Each wire was then sintered to produce a superconductor. Processing considerations included the sheath workability, effects of compacting and residual stresses, and heat treatment schedules. The superconducting properties of the Bi-based wires were superior to those of the YBa2Cu3O(x) wires at 4.2 K, but not at 77 K.

  20. Wire-like nano-polyaniline deposited electrochemically in a reverse micelle electrolyte as a pH sensor

    NASA Astrophysics Data System (ADS)

    Zhao, Fei; Jiao, Han-dong; Zhao, Shi-qiang

    2015-10-01

    Wire-like polyaniline (PANI) films were successfully electrodeposited onto an indium tin oxide (ITO) substrate using a pulse galvanostatic method (PGM) in a reverse micelle electrolyte. The as-prepared PANI films were electrochemically analyzed by cyclic voltammetry and electrochemical impedance spectroscopy in 1 mol·L-1 HClO4 solution. It is found that the as-prepared PANI films are highly porous, exhibit the diameters of approximately 100 nm and the lengths exceeding 3 μm, and have favorable electrochemical activities. Furthermore, the as-prepared wire-like PANI films show a good linear relationship of the potentiometric response curve over the pH value range of 3-10 with a slope of 74.13 mV·pH-1 in 0.5 mol·L-1 K2HPO4 basal solutions. The results demonstrate that the prepared wire-like PANI films are promising pH sensors.

  1. Nano-biosensor development for bacterial detection during human kidney infection: use of glycoconjugate-specific antibody-bound gold NanoWire arrays (GNWA).

    PubMed

    Basu, Manju; Seggerson, Sara; Henshaw, Joshua; Jiang, Juan; del A Cordona, Rocio; Lefave, Clare; Boyle, Patrick J; Miller, Albert; Pugia, Michael; Basu, Subhash

    2004-01-01

    Infectious disease, commonly caused by bacterial pathogens, is now the world's leading cause of premature death and third overall cause behind cardiovascular disease and cancer. Urinary Tract Infection (UTI), caused by E. coli bacteria, is a very common bacterial infection, a majority in women (85%) and may result in severe kidney failure if not detected quickly. Among hundreds of strains the bacteria, E. coli 0157:H7, is emerging as the most aggressive one because of its capability to produce a toxin causing hemolytic uremic syndrome (HUS) resulting in death, especially in children. In the present study, a project has been undertaken for developing a rapid method for UTI detection in very low bacteria concentration, applying current knowledge of nano-technology. Experiments have been designed for the development of biosensors using nano-fabricated structures coated with elements such as gold that have affinity for biomolecules. A biosensor is a device in which a biological sensing element is either intimately connected to or integrated within a transducer. The basic principle for the detection procedure of the infection is partly based on the enzyme-linked immunosorbent assay system. Anti-E. coli antibody-bound Gold Nanowire Arrays (GNWA) prepared on anodized porous alumina template is used for the primary step followed by binding of the bacteria containing specimen. An alkaline phosphatase-conjugated second antibody is then added to the system and the resultant binding determined by both electrochemical and optical measurements. Various kinds of GNWA templates were used in order to determine the one with the best affinity for antibody binding. In addition, an efficient method for enhanced antibody binding has been developed with the covalent immobilization of an organic linker Dithiobissuccinimidylundecanoate (DSU) on the GNWA surface. Studies have also been conducted to optimize the antibody-binding conditions to the linker-attached GNWA surfaces for their

  2. Development of coated-wire silver ion selective electrodes on paper using conductive films of silver nanoparticles.

    PubMed

    Janrungroatsakul, Wanwisa; Lertvachirapaiboon, Chutiparn; Ngeontae, Wittaya; Aeungmaitrepirom, Wanlapa; Chailapakul, Orawon; Ekgasit, Sanong; Tuntulani, Thawatchai

    2013-11-21

    Films of silver nanoparticles are used for the first time as an electrical conductor and ion-to-electron transducer to fabricate coated-wire ion selective electrodes (ISEs) on paper. The film of nano silver ink (nano silver film), synthesized from the reduction of AgNO3 by NaBH4, was screen printed on paper. Transmission electron microscopy showed that the synthesized silver nanoparticles (AgNPs) possessed a spherical shape with diameter ca. 5 nm. Energy-dispersive X-ray spectroscopy supported the purity and good stability of the synthesized AgNPs. Nano silver films were sintered at room temperature, 100 °C and 200 °C. Upon increasing the sintering temperature, atomic force microscopy showed that the size of AgNPs of nano silver films increased, but the sheet resistivity decreased. Silver ISEs were then fabricated from nano silver films and o-NPOE-plasticized polymeric membranes containing benzothiazolyl calix[4]arene () as ionophore and KTpClPB as anionic site. The performance of the developed Ag-ISEs was investigated by potentiometric measurements, potentiometric water layer tests, current reversal chronopotentiometry and electrochemical impedance spectroscopy. The coated-wire electrode fabricated from the nano silver film sintering at room temperature showed the best characteristics of Ag-ISEs giving a near Nernstian response slope of 59.7 ± 1.0 mV per decade, 10(-6) to 10(-2) M linear range, detection limit of 4.5 × 10(-7) M, long-term potential stability and good reversibility. PMID:24071789

  3. Study on Electro-polymerization Nano-micro Wiring System Imitating Axonal Growth of Artificial Neurons towards Machine Learning

    NASA Astrophysics Data System (ADS)

    Dang, Nguyen Tuan; Akai-Kasada, Megumi; Asai, Tetsuya; Saito, Akira; Kuwahara, Yuji; Hokkaido University Collaboration

    2015-03-01

    Machine learning using the artificial neuron network research is supposed to be the best way to understand how the human brain trains itself to process information. In this study, we have successfully developed the programs using supervised machine learning algorithm. However, these supervised learning processes for the neuron network required the very strong computing configuration. Derivation from the necessity of increasing in computing ability and in reduction of power consumption, accelerator circuits become critical. To develop such accelerator circuits using supervised machine learning algorithm, conducting polymer micro/nanowires growing process was realized and applied as a synaptic weigh controller. In this work, high conductivity Polypyrrole (PPy) and Poly (3, 4 - ethylenedioxythiophene) PEDOT wires were potentiostatically grown crosslinking the designated electrodes, which were prefabricated by lithography, when appropriate square wave AC voltage and appropriate frequency were applied. Micro/nanowire growing process emulated the neurotransmitter release process of synapses inside a biological neuron and wire's resistance variation during the growing process was preferred to as the variation of synaptic weigh in machine learning algorithm. In a cooperation with Graduate School of Information Science and Technology, Hokkaido University.

  4. International round robin test of the retained critical current after double bending at room temperature of Ag-sheathed Bi-2223 superconducting wires

    NASA Astrophysics Data System (ADS)

    Yamada, Y.; Nishijima, G.; Osamura, K.; Shin, H. S.; Goldacker, W.; Breschi, M.; Ribani, P.

    2016-02-01

    An international round robin test was carried out in order to establish a test method for retained critical current after double bending at room temperature of Ag-sheathed Bi-2223 superconducting wires. Tests for commercial Bi-2223 tape were conducted by six laboratories using the same guidelines. The standard uncertainties (SUs) of measurands were evaluated for these four quantities: I C0, I C/I C080, I C/I C060, I C/I C050, where, I C0 is initial critical current and I C /I C0XX is critical current after XX mm bending. Using an F test to determine where the most scatter was generated in the test results it was found that the greatest scatter in the normalized critical current measurements came from inter-laboratory scatter. In a type-B uncertainty evaluation, the major contribution was from the bending diameter and measuring temperature. The relative SU tended to increase as the bending diameter decreased. A specific mandrel diameter corresponding to a retained critical current of 95% could be determined with a relative SU of 1.3%. In order to reduce the overall scatter, the temperature difference between the critical current measurements before and after bending should be small.

  5. Wire frame to MOVIE. BYU transfer program

    SciTech Connect

    Robbins, D.; Byers, L.D.; Benner, M.S.

    1982-12-01

    At SNLA, the primary computer-aided drafting tool is the Applicon Graphics System (AGS). The data base for mechanical parts on the AGS is a wire frame model. This report summarizes a method of adding surface information to the wire frame and passing this information up stream to MOVIE.BYU which is on a VAX computer and is used to produce shaded graphics pictures of the AGS wire frame model on a RAMTEK 9400 display terminal.

  6. ALTERNATING CURRENT LOSSES IN AG-SHEATHED BSCCO (2212 AND 2223) TAPES AND WIRES AND YBCO (123) COATED CONDUCTORS

    SciTech Connect

    Dr. John S. Hurley

    2000-01-01

    In this study, we focus on the examination of ac losses in conductors utilizing Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O [BSCCO (2223)] high TC superconductors (HTS). In addition, we seek to assist other facilities such as the University of Wisconsin-Madison Applied Superconductivity Center (UW-ASC), Brookhaven National Laboratory, and other DoE facilities investigating the use of HTS in electric power applications (e.g., generators, motors, and transformers). To accomplish this we will develop an ac losses capability at Clark Atlanta University to complement the established ac losses efforts at Brookhaven National Laboratory (BSCCO) on BSCCO/Ag and various material characterization efforts taking place at the UW-ASC. Our goal is through this effort to gain a greater understanding of the effects on ac losses due to parameters such as ac/dc current, J{sub c}, tape geometry, voltage tap placement, field orientation, material anisotropy, surface irregularities, percolations and filament coupling effects. As a result, we expect to better understand how to minimize ac losses in applications requiring real or practical conductors. HTS conductors based on BSCCO-2223 are now being routinely produced in industrial lengths of high quality. Vendors such as Southwire and ASC are producing multi-filamentary tapes in lengths of 6 km or more carrying critical current densities of up to 3 kA/cm**2 at 77 K. While this is approaching the level of performance where some large-scale applications are considered to be economically viable, a number of problems remain to be solved. The remaining issues include: rapid reduction in JC in magnetic fields; and power dissipation due to varying magnetic fields or currents (ac losses).

  7. Fabrication and integration of micro/nano-scale optical wire circuit arrays and devices for high-speed and compact optical printed circuit board (O-PCB) and VLSI photonic applications

    NASA Astrophysics Data System (ADS)

    Lee, El-Hang; Lee, S. G.; O, B. H.; Park, S. G.; Kim, K. H.; Kang, J. K.; Choi, Y. W.; Song, S. H.

    2005-09-01

    We report on the design, fabrication and integration of micro/nano-scale optical wire circuit arrays and devices for high-speed, compact, light-weight, low power optical printed circuit boards (O-PCBs) and VLSI photonic applications. The optical wires are formed in the form of waveguides by thermal embossing and ultraviolet (UV) radiated embossing of polymer materials. The photonic devices include vertically coupled surface emitting laser (VCSEL) microlasers, microlenses, 45-degree reflection couplers, directional couplers, arrayed waveguide grating structures, multimode interference (MMI) devices and photodetectors. These devices are optically interconnected and integrated for O-PCB assembly and VLSI micro/nano-photonics. The O-PCBs are to perform the functions of transporting, switching, routing and distributing optical signals on flat modular boards or substrates. We report on the result of the optical transmission performances of these assembled O-PCBs. For the design, fabrication, and VLSI integration of nano-scale photonic devices, we used photonic crystal structures and plasmonic metallic waveguide structures. We examined the bandwidth, power dissipation, thermal stability, weight, and the miniaturization and density of optical wires and the O-PCB module. Characteristics of these devices are also described.

  8. Structural and physical properties of antibacterial Ag-doped nano-hydroxyapatite synthesized at 100°C

    PubMed Central

    2011-01-01

    Synthesis of nanosized particle of Ag-doped hydroxyapatite with antibacterial properties is in the great interest in the development of new biomedical applications. In this article, we propose a method for synthesized the Ag-doped nanocrystalline hydroxyapatite. A silver-doped nanocrystalline hydroxyapatite was synthesized at 100°C in deionized water. Other phase or impurities were not observed. Silver-doped hydroxyapatite nanoparticles (Ag:HAp) were performed by setting the atomic ratio of Ag/[Ag + Ca] at 20% and [Ca + Ag]/P as 1.67. The X-ray diffraction studies demonstrate that powders made by co-precipitation at 100°C exhibit the apatite characteristics with good crystal structure and no new phase or impurity is found. The scanning electron microscopy (SEM) observations suggest that these materials present a little different morphology, which reveals a homogeneous aspect of the synthesized particles for all samples. The presence of calcium (Ca), phosphor (P), oxygen (O), and silver (Ag) in the Ag:HAp is confirmed by energy dispersive X-ray (EDAX) analysis. FT-IR and FT-Raman spectroscopies revealed that the presence of the various vibrational modes corresponds to phosphates and hydroxyl groups. The strain of Staphylococcus aureus was used to evaluate the antibacterial activity of the Ca10-xAgx(PO4)6(OH)2 (x = 0 and 0.2). In vitro bacterial adhesion study indicated a significant difference between HAp (x = 0) and Ag:HAp (x = 0.2). The Ag:Hap nanopowder showed higher inhibition. PMID:22136671

  9. Cu/Nb nano-composite wires processed by severe plastic deformation for applications in high pulsed magnets: effects of the multi-scale microstructure on the mechanical properties

    SciTech Connect

    Dubois, J. B.; Thilly, L.; Renault, P.O.; Lecouturier, F.; Olier, P.

    2012-06-15

    Copper-based high strength and high electrical conductivity nano-composite wires reinforced by Nb nano-tubes are prepared by severe plastic deformation, applied with an Accumulative Drawing and Bundling process (ADB), for the windings of high pulsed magnets. The ADB process leads to a multi-scale Cu matrix containing up to N = 85{sub 4} (52.2.10{sup 6}) continuous parallel Nb tubes with diameter down to few tens nano-meters. After heavy strain, the Nb nano-tubes exhibit a homogeneous microstructure with grain size below 100 nm. The Cu matrix presents a multi-scale microstructure with multi-modal grain size distribution from the micrometer to the nano-meter range. The use of complementary characterization techniques at the microscopic and macroscopic level (in-situ tensile tests in the TEM, nano-indentation, in-situ tensile tests under high energy synchrotron beam) shed light on the interest of the multi-scale nature of the microstructure to achieve extreme mechanical properties, therefore allowing for design guidelines to further improve these properties. (authors)

  10. Nano-photo active cellulosic fabric through in situ phytosynthesis of star-like Ag/ZnO nanocomposites: Investigation and optimization of attributes associated with photocatalytic activity.

    PubMed

    Aladpoosh, Razieh; Montazer, Majid

    2016-05-01

    In this study, nano-photo active cellulosic fabric was prepared through in situ phytosynthesis of star-like Ag/ZnO nanocomposites using the ashes of Seidlitzia rosmarinus plants so-called Keliab. This is provided alkali media as a vital condition for synthesis of nanocomposites, further increasing the reduce-ability of cellulosic chains by activation of hydroxyl groups. The intermolecular dehydrolysis of intermediates ions under thermal and alkaline conditions leads to formation of Ag/ZnO heterostructure. Various analytical techniques were employed to confirm Ag/ZnO nanocomposites on the cotton fabric. The surface morphology, crystal phase and chemical structure of the treated fabrics were characterized by field emission and scanning electron microscopy (FE-SEM and SEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDX). Moreover, influence of precursors: silver nitrate, zinc acetate and Keliab solution on attributes associated with photocatalytic activities including self-cleaning, whiteness and wettability was investigated via central composite design (CCD). The treated cotton samples exhibited self-cleaning activities through methylene blue degradation under day-light exposure along with improved wettability and whiteness. The prepared sample in optimized conditions showed good antibacterial activities against Staphylococcus aureus and Escherichia coli with enhanced fabric tensile strength. PMID:26877003

  11. Vertically p-n-junctioned GaN nano-wire array diode fabricated on Si(111) using MOCVD.

    PubMed

    Park, Ji-Hyeon; Kim, Min-Hee; Kissinger, Suthan; Lee, Cheul-Ro

    2013-04-01

    We demonstrate the fabrication of n-GaN:Si/p-GaN:Mg nanowire arrays on (111) silicon substrate by metal organic chemical vapor deposition (MOCVD) method .The nanowires were grown by a newly developed two-step growth process. The diameter of as-grown nanowires ranges from 300-400 nm with a density of 6-7 × 10(7) cm(-2). The p- and n-type doping of the nanowires is achieved with Mg and Si dopant species. Structural characterization by X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) indicates that the nanowires are relatively defect-free. The room-temperature photoluminescence emission with a strong peak at 370 nm indicates that the n-GaN:Si/p-GaN:Mg nanowire arrays have potential application in light-emitting nanodevices. The cathodoluminscence (CL) spectrum clearly shows a distinct optical transition of GaN nanodiodes. The nano-n-GaN:Si/p-GaN:Mg diodes were further completed using a sputter coating approach to deposit Au/Ni metal contacts. The polysilazane filler has been etched by a wet chemical etching process. The n-GaN:Si/p-GaN:Mg nanowire diode was fabricated for different Mg source flow rates. The current-voltage (I-V) measurements reveal excellent rectifying properties with an obvious turn-on voltage at 1.6 V for a Mg flow rate of 5 sccm (standard cubic centimeters per minute). PMID:23455517

  12. Au@Ag/Au nanoparticles assembled with activatable aptamer probes as smart ``nano-doctors'' for image-guided cancer thermotherapy

    NASA Astrophysics Data System (ADS)

    Shi, Hui; Ye, Xiaosheng; He, Xiaoxiao; Wang, Kemin; Cui, Wensi; He, Dinggeng; Li, Duo; Jia, Xuekun

    2014-07-01

    Although nanomaterial-based theranostics have increased positive expectations from cancer treatment, it remains challenging to develop in vivo ``nano-doctors'' that provide high-contrast image-guided site-specific therapy. Here we designed an activatable theranostic nanoprobe (ATNP) via self-assembly of activatable aptamer probes (AAPs) on Au@Ag/Au nanoparticles (NPs). As both quenchers and heaters, novel Au@Ag/Au NPs were prepared, showing excellent fluorescence quenching and more effective near-infrared photothermal therapy than Au nanorods. The AAP comprised a thiolated aptamer and a fluorophore-labeled complementary DNA; thus, the ATNP with quenched fluorescence in the free state could realize signal activation through target binding-induced conformational change of the AAP, and then achieve on-demand treatment under image-guided irradiation. By using S6 aptamer as the model, in vitro and in vivo studies of A549 lung cancer verified that the ATNP greatly improved imaging contrast and specific destruction, suggesting a robust and versatile theranostic strategy for personalized medicine in future.Although nanomaterial-based theranostics have increased positive expectations from cancer treatment, it remains challenging to develop in vivo ``nano-doctors'' that provide high-contrast image-guided site-specific therapy. Here we designed an activatable theranostic nanoprobe (ATNP) via self-assembly of activatable aptamer probes (AAPs) on Au@Ag/Au nanoparticles (NPs). As both quenchers and heaters, novel Au@Ag/Au NPs were prepared, showing excellent fluorescence quenching and more effective near-infrared photothermal therapy than Au nanorods. The AAP comprised a thiolated aptamer and a fluorophore-labeled complementary DNA; thus, the ATNP with quenched fluorescence in the free state could realize signal activation through target binding-induced conformational change of the AAP, and then achieve on-demand treatment under image-guided irradiation. By using S6 aptamer as

  13. Thickness Dispersion of Surface Plasmon of Ag Nano-thin Films: Determination by Ellipsometry Iterated with Transmittance Method

    PubMed Central

    Gong, Junbo; Dai, Rucheng; Wang, Zhongping; Zhang, Zengming

    2015-01-01

    Effective optical constants of Ag thin films are precisely determined with effective thickness simultaneously by using an ellipsometry iterated with transmittance method. Unlike the bulk optical constants in Palik's database the effective optical constants of ultrathin Ag films are found to strongly depend on the thickness. According to the optical data two branches of thickness dispersion of surface plasmon energy are derived and agreed with theoretical predication. The thickness dispersion of bulk plasmon is also observed. The influence of substrate on surface plasmon is verified for the first time by using ellipsometry. The thickness dependent effective energy loss function is thus obtained based on this optical method for Ag ultrathin films. This method is also applicable to other ultrathin films and can be used to establish an effective optical database for ultrathin films. PMID:25797217

  14. Properties of nano structured Ag-TiO{sub 2} composite coating on stainless steel using RF sputtering method

    SciTech Connect

    Bakar, S. Abu; Jamuna-Thevi, K.; Abu, N.; Mohd Toff, M. R.

    2012-07-02

    RF Sputtering system is one of the Physical Vapour Deposition (PVD) methods that have been widely used to produce hard coating. This technique is used to deposit thin layers of metallic substrates such as stainless steel (SS). From this process, a good adhesiveness and wear resistance coating can be produced for biomedical applications. In this study, RF sputtering method was used to deposit TiO{sub 2}-Ag composite coatings via various deposition parameters. The parameters are RF power of 350W, gas composition (Ar: O{sub 2}) 50:5 and deposition time at 1, 2, 4 and 6 hours. Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and Raman spectroscopy were used to characterize surface area of coated samples. The formation of nanocrystalline thin film and the surface morphology were examined using SEM. The crystallite size of TiO{sub 2}-Ag composite coatings were estimated between 20-60 nm based on XRD analysis using Scherer equation and SEM evaluation. The Raman and XRD results suggested that the structure of the TiO{sub 2}-Ag consist of anatase and rutile phases. It also showed that the intensity of anatase peaks increased after samples undergone annealing process at 500 Degree-Sign C.

  15. Nano-morphology induced additional surface plasmon resonance enhancement of SERS sensitivity in Ag/GaN nanowall network

    NASA Astrophysics Data System (ADS)

    Sharvani, S.; Upadhayaya, Kishor; Kumari, Gayatri; Narayana, Chandrabhas; Shivaprasad, S. M.

    2015-11-01

    The GaN nanowall network, formed by opening the screw dislocations by kinetically controlled MBE growth, possesses a large surface and high conductivity. Sharp apexed nanowalls show higher surface electron concentration in the band-tail states, in comparison to blunt apexed nanowalls. Uncapped silver nanoparticles are vapor deposited on the blunt and sharp GaN nanowall networks to study the morphological dependence of band-edge plasmon-coupling. Surface enhanced Raman spectroscopy studies performed with a rhodamine 6G analyte on these two configurations clearly show that the sharp nanowall morphology with smaller Ag nanoparticles shows higher enhancement of the Raman signal. A very large enhancement factor of 2.8 × 107 and a very low limit of detection of 10-10 M is observed, which is attributed to the surface plasmon resonance owing to the high surface electron concentration on the GaN nanowall in addition to that of the Ag nanoparticles. The significantly higher sensitivity with same-sized Ag nanoparticles confirms the unconventional role of morphology-dependent surface charge carrier concentration of GaN nanowalls in the enhancement of Raman signals.

  16. Nano-morphology induced additional surface plasmon resonance enhancement of SERS sensitivity in Ag/GaN nanowall network.

    PubMed

    Sharvani, S; Upadhayaya, Kishor; Kumari, Gayatri; Narayana, Chandrabhas; Shivaprasad, S M

    2015-11-20

    The GaN nanowall network, formed by opening the screw dislocations by kinetically controlled MBE growth, possesses a large surface and high conductivity. Sharp apexed nanowalls show higher surface electron concentration in the band-tail states, in comparison to blunt apexed nanowalls. Uncapped silver nanoparticles are vapor deposited on the blunt and sharp GaN nanowall networks to study the morphological dependence of band-edge plasmon-coupling. Surface enhanced Raman spectroscopy studies performed with a rhodamine 6G analyte on these two configurations clearly show that the sharp nanowall morphology with smaller Ag nanoparticles shows higher enhancement of the Raman signal. A very large enhancement factor of 2.8 × 10(7) and a very low limit of detection of 10(-10) M is observed, which is attributed to the surface plasmon resonance owing to the high surface electron concentration on the GaN nanowall in addition to that of the Ag nanoparticles. The significantly higher sensitivity with same-sized Ag nanoparticles confirms the unconventional role of morphology-dependent surface charge carrier concentration of GaN nanowalls in the enhancement of Raman signals. PMID:26502004

  17. Properties of nano structured Ag-TiO2 composite coating on stainless steel using RF sputtering method

    NASA Astrophysics Data System (ADS)

    Bakar, S. Abu; Jamuna-Thevi, K.; Abu, N.; Mohd Toff, M. R.

    2012-07-01

    RF Sputtering system is one of the Physical Vapour Deposition (PVD) methods that have been widely used to produce hard coating. This technique is used to deposit thin layers of metallic substrates such as stainless steel (SS). From this process, a good adhesiveness and wear resistance coating can be produced for biomedical applications. In this study, RF sputtering method was used to deposit TiO2-Ag composite coatings via various deposition parameters. The parameters are RF power of 350W, gas composition (Ar: O2) 50:5 and deposition time at 1, 2, 4 and 6 hours. Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and Raman spectroscopy were used to characterize surface area of coated samples. The formation of nanocrystalline thin film and the surface morphology were examined using SEM. The crystallite size of TiO2-Ag composite coatings were estimated between 20-60 nm based on XRD analysis using Scherer equation and SEM evaluation. The Raman and XRD results suggested that the structure of the TiO2-Ag consist of anatase and rutile phases. It also showed that the intensity of anatase peaks increased after samples undergone annealing process at 500 °C.

  18. Modeling effects of gas bubbles on the mechanical behaviors of Ag/Bi-2212 round wires using a double cantilever beam bridge model

    NASA Astrophysics Data System (ADS)

    Lu, Yurong; Wang, Zhongtong; Yong, Huadong; Zhou, Youhe

    2016-07-01

    Due to the larger current-carrying property, Bi2Sr2CaCu2Ox (Bi2212) superconductors have a great potential application in high field magnet. Bi2212 superconducting material can be fabricated as an isotropic round wire. However, there is 30% void space in the wire, such as gas bubbles. The void space has a larger influence on the property of the wire. In this paper, we will study the effect of gas bubble on the fracture behavior. Based on the double cantilever beam model and critical state theory, the mechanical behavior of Bi2212 wire is studied for decreasing field. Two different damage mechanisms are discussed using the strain energy release rate and strain of bridge. The results show that the large gas bubble can increase the strain of bridge. The central filaments with gas bubble are easier to be damaged than the edge filaments with gas bubble.

  19. Wire Array Photovoltaics

    NASA Astrophysics Data System (ADS)

    Turner-Evans, Dan

    Over the past five years, the cost of solar panels has dropped drastically and, in concert, the number of installed modules has risen exponentially. However, solar electricity is still more than twice as expensive as electricity from a natural gas plant. Fortunately, wire array solar cells have emerged as a promising technology for further lowering the cost of solar. Si wire array solar cells are formed with a unique, low cost growth method and use 100 times less material than conventional Si cells. The wires can be embedded in a transparent, flexible polymer to create a free-standing array that can be rolled up for easy installation in a variety of form factors. Furthermore, by incorporating multijunctions into the wire morphology, higher efficiencies can be achieved while taking advantage of the unique defect relaxation pathways afforded by the 3D wire geometry. The work in this thesis shepherded Si wires from undoped arrays to flexible, functional large area devices and laid the groundwork for multijunction wire array cells. Fabrication techniques were developed to turn intrinsic Si wires into full p-n junctions and the wires were passivated with a-Si:H and a-SiNx:H. Single wire devices yielded open circuit voltages of 600 mV and efficiencies of 9%. The arrays were then embedded in a polymer and contacted with a transparent, flexible, Ni nanoparticle and Ag nanowire top contact. The contact connected >99% of the wires in parallel and yielded flexible, substrate free solar cells featuring hundreds of thousands of wires. Building on the success of the Si wire arrays, GaP was epitaxially grown on the material to create heterostructures for photoelectrochemistry. These cells were limited by low absorption in the GaP due to its indirect bandgap, and poor current collection due to a diffusion length of only 80 nm. However, GaAsP on SiGe offers a superior combination of materials, and wire architectures based on these semiconductors were investigated for multijunction

  20. Nano-Crystal Formation and Growth from High-Fluence Ion Implantation of Au, Ag or Cu in Silica

    NASA Astrophysics Data System (ADS)

    Ila, D.; Baglin, J. E. E.; Zimmerman, R. L.

    The linear and non-linear optical properties of silica may be tailored by the introduction of a random distribution of nanocrystallites of an immiscible metal within a near-surface region. The size, size distribution, and spatial distribution of these crystallites must be controllable in order to optimize the functional properties for device applications. In this paper, we present a novel fabrication technique that offers such control. Energetic metal ions are implanted in silica at room temperature. Subsequent heat treatment leads to diffusion of the implanted atoms, nucleation and growth of metal crystallites, and Ostwald ripening of the resulting clusters. We have observed the kinetics and effective activation energies describing the multiple processes involved, for the cases of Au, Ag or Cu implanted at MeV energies, at various fluences, and then annealed at fixed temperatures in the range 500 °C-1000 °C. Effective activation energies found for nanocrystal nucleation and growth at temperatures below 800 °C (e.g. 64 meV for Ag) are replaced above this temperature range by much higher activation energies (e.g. 400 meV for Ag). We may attribute this to the depletion of un-attached mobile metal atoms (so that ripening of clusters will be limited by energy barriers for escape of such mobile atoms from small crystallites), and/or the annealing of implant-caused stress in the silica structure at high temperatures, that creates new channels for thermal diffusion of metal atoms within the silica host.

  1. Basic Wiring.

    ERIC Educational Resources Information Center

    Kaltwasser, Stan; And Others

    This module is the first in a series of three wiring publications; it serves as the foundation for students enrolled in a wiring program. It is a prerequisite to either "Residential Wiring" or "Commercial and Industrial Wiring." The module contains 16 instructional units that cover the following topics: occupational introduction; general safety;…

  2. High Tc superconductors - Composite wire fabrication

    NASA Astrophysics Data System (ADS)

    Jin, S.; Sherwood, R. C.; van Dover, R. B.; Tiefel, T. H.; Johnson, D. W., Jr.

    1987-07-01

    The fabrication of fine-wire, composite superconductors consisting of a high-conductivity normal metal shell, such as Ag or Cu/Ni/Au, and a superconducting core of Ba2YCu3O oxide is described. The functions of the normal metal shell and the importance of using the proper diffusion barrier metals are discussed. A resistivity-temperature curve for the composite wire Ag/Ba2YCu3O7 is examined, and the compound inside the finished wire is analyzed using X-ray diffraction. It is observed that the zero-field critical current density of the wire at 77 K is about 175 A/sq cm and the superconducting core is continuous and retains phase composition after wire drawing and heat treatment. The supplying of oxygen to the core of the long wire during heat treatments is studied. The data reveal that it is possible to process ceramic superconductors into a desirable composite wire form.

  3. Micro/nano-scale fabrication of integrated polymer optical wire circuit arrays for optical printed circuit board (O-PCB) application

    NASA Astrophysics Data System (ADS)

    Lee, El-Hang; Lee, Seung G.; Park, Se G.; Kim, Kyong H.; Kang, Jin K.; Chin, In J.; Kwon, Y. K.; Choi, Young W.

    2005-02-01

    We report on the results of our study on the micro/nano-scale design, fabrication and integration of waveguide arrays for optical printed circuit boards (O-PCBs) and VLSI micro/nano-photonic applications. The O-PCBs are designed to perform the functions of transporting, switching, routing and distributing optical signals on flat modular boards or substrates. We have assembled O-PCBs using optical waveguide arrays and circuits made of polymer materials and have examined information handling performances. We also designed power beam splitters and waveguide filters, using nano-scale photonic band-gap crystals, for VLSI photonic integration application. We discuss potential applications of polymer optical waveguide devices and arrays for O-PCB and VLSI micro/nano-photonics for computers, telecommunications, and transportation systems.

  4. Behavioral response of pyrite structured Co0.2Fe0.8S2 nano-wires under high-pressure up to 8 GPa - Mössbauer spectroscopic and electrical resistivity studies

    NASA Astrophysics Data System (ADS)

    Chandra, U.; Sharma, P.; Parthasarathy, G.; Sreedhar, B.

    2016-02-01

    Pyrite-structured Co0.2Fe0.8S2 nano wires with aspect ratio 45:1, synthesized using solution colloid method were studied under high pressure up to 8 GPa using 57Fe Mössbauer spectroscopy (using diamond anvil cell) and electrical resistivity (using tungsten carbide cell) techniques. Room temperature S K-edge XANES studies at INFN-LNF synchrotron beam line signified the changes in the electronic structure owing to Co substitution. Magnetic measurements at 5 K demonstrated disordered ferromagnetic behavior similar to Griffith phase. The value of isomer shift identified Fe in divalent, low spin state corresponding to pyrite structure. Higher value of quadrupole splitting observed at ambient condition was due to large lattice strain and electric field gradient generated by large surface to volume ratio of the nano size of the system. With applied pressure, the value followed the expected trend of increase up to 4.3 GPa, then to decrease till 6.4 GPa. Such change in the trend suggested a phase transition. On decompression to ambient pressure, the system seemed to retain high pressure phase and nano structure. The pressure coefficient of electrical resistivity varying from -0.0454 to -0.166 Ω-cm/GPa across the transition pressure of ~4.5 GPa was sluggish suggesting second order phase transition. The pressure-dependent variations by Mössbauer parameters and electrical resistivity showed identical result. This is the first report of pressure effect on nano sized Co0.2Fe0.8S2. Effect of particle size on transition pressure could not be evaluated due to lack of available reports on bulk system.

  5. A first principle study of encapsulated and functionalized silicon nanotube of chirality (6,6) with monoatomically thin metal wires of Ag, Au and Cu

    NASA Astrophysics Data System (ADS)

    Kumar Chandel, Surjeet; Kumar, Arun; Ahluwalia, P. K.; Sharma, Raman

    2015-04-01

    First principle calculations have been performed to study the influence of interaction of monoatomically thin metal nanowires of Ag, Au and Cu placed inside (encapsulation) and outside (functionalization) the silicon nanotube having armchair conformation with chirality (6,6). The cohesive energy for all the encapsulated and functionalized systems under study was found to be almost same. In comparison to the pristine silicon nanotube (SiNT) which is found to be semiconducting in nature, all the encapsulated and functionalized systems of SiNT are found to be metallic in nature. The calculated electronic band structures show that the conductance in case of Ag, Au and Cu nanowires encapsulation is 2G0. However, its value for functionalized Ag, Au and Cu nanowires is found to be 1G0, 2G0 and 4G0 for the outside positioning of nanowires respectively. Optical properties of all the encapsulated and functionalized SiNTs have been studied. All the systems under study show reflectivity in the infrared (IR) region and behave as non-absorbing transparent conductors in the visible region.

  6. E-beam deposited Ag-nanoparticles plasmonic organic solar cell and its absorption enhancement analysis using FDTD-based cylindrical nano-particle optical model.

    PubMed

    Kim, Richard S; Zhu, Jinfeng; Park, Jeung Hun; Li, Lu; Yu, Zhibin; Shen, Huajun; Xue, Mei; Wang, Kang L; Park, Gyechoon; Anderson, Timothy J; Pei, Qibing

    2012-06-01

    We report the plasmon-assisted photocurrent enhancement in Ag-nanoparticles (Ag-NPs) embedded PEDOT:PSS/P3HT:PCBM organic solar cells, and systematically investigate the causes of the improved optical absorption based on a cylindrical Ag-NPs optical model which is simulated with a 3-Dimensional finite difference time domain (FDTD) method. The proposed cylindrical Ag-NPs optical model is able to explain the optical absorption enhancement by the localized surface plasmon resonance (LSPR) modes, and to provide a further understanding of Ag-NPs shape parameters which play an important role to determine the broadband absorption phenomena in plasmonic organic solar cells. A significant increase in the power conversion efficiency (PCE) of the plasmonic solar cell was experimentally observed and compared with that of the solar cells without Ag-NPs. Finally, our conclusion was made after briefly discussing the electrical effects of the fabricated plasmonic organic solar cells. PMID:22714293

  7. Control of coupling in 1D photonic crystal coupled-cavity nano-wire structures via hole diameter and position variation

    NASA Astrophysics Data System (ADS)

    Zain, A. R. Md; De La Rue, R. M.

    2015-12-01

    We have successfully demonstrated close experimental control of the resonance splitting/free spectral range of a coupled micro-cavity one-dimensional photonic crystal/photonic wire device structure based on silicon-on-insulator. Clear splitting of the resonances, with FSR values ranging from 8 nm to 48 nm, was obtained through the use of different hole arrangements within the middle section of the device structures, between the coupled cavities. The results show good agreement with calculations obtained using a finite-difference time-domain simulation approach.

  8. Residential Wiring.

    ERIC Educational Resources Information Center

    Taylor, Mark

    The second in a series of three curriculum packages on wiring, these materials for a five-unit course were developed to prepare postsecondary students for entry-level employment in the residential wiring trade. The five units are: (1) blueprint reading and load calculations; (2) rough-in; (3) service; (4) trim out and troubleshooting; and (5) load…

  9. Wire chamber

    DOEpatents

    Atac, Muzaffer

    1989-01-01

    A wire chamber or proportional counter device, such as Geiger-Mueller tube or drift chamber, improved with a gas mixture providing a stable drift velocity while eliminating wire aging caused by prior art gas mixtures. The new gas mixture is comprised of equal parts argon and ethane gas and having approximately 0.25% isopropyl alcohol vapor.

  10. Doping nano-Co3O4 surface with bigger nanosized Ag and its photocatalytic properties for visible light photodegradation of organic dyes

    NASA Astrophysics Data System (ADS)

    Chen, Guangliang; Si, Xiaolei; Yu, Jinsong; Bai, Huiyu; Zhang, Xianhui

    2015-03-01

    This paper reports the synthesis of nanosized Ag/Co3O4 composite catalysts using a silver-mirror reaction and the calibration of their catalytic activities towards methyl blue (MB) dye degradation with peroxymonosulfate (PMS) under visible light. The nanosized Ag/Co3O4 composites were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV-vis spectroscopy. The experimental evidence indicated that the hydrothermal synthesis approach lead to the exposure of the {1 1 2} facets of the Co3O4 nanoflakes. Compared to Co3O4 nanoflakes, Co3O4 doped with Ag nanoparticle (average diameters of 10-15 nm) presented lower band gap energy and photoluminescent (PL) intensity. Meanwhile, the Ag/Co3O4 exhibited high stability and excellent dispersion property in dye solution. Experimental data suggested that 3.06 wt% Ag nanoparticle-doped Ag/Co3O4 nanocomposite catalyst possessed the highest catalytic activity towards MB degradation in aqueous solution at the tested concentration level of 15 mg/L, about 2.4 times higher than that of pure Co3O4. Complete decolorization of the 15 mg/L MB solution can be achieved by 3.06 wt% Ag-doped Ag/Co3O4 nanocomposite within 20 min of visible light irradiation.

  11. Depth-dependent crystallinity of nano-crystalline silicon induced by step-wise variation of hydrogen dilution during hot-wire CVD

    NASA Astrophysics Data System (ADS)

    Arendse, C. J.; van Heerden, B. A.; Muller, T. F. G.; Cummings, F. R.; Oliphant, C. J.; Malgas, G. F.; Motaung, D. E.

    2015-06-01

    To induce an amorphous surface in a nano-crystalline silicon (nc-Si:H) thin film, the hydrogen dilution was reduced step-wise at fixed time intervals from 90 - 50% during the hotwire chemical vapour deposition process. This contribution reports on the structural properties of the resultant nc-Si:H thin film as a function of the deposition time. Raman spectroscopy, confirmed by high resolution transmission spectroscopy, indicates crystalline uniformity in the growth direction, accompanied by the progression of an amorphous surface layer as the deposition time is increased. The silicon- and oxygen bonding configurations were probed using infrared spectroscopy and electron energy loss spectroscopy. The growth mechanism is ascribed to the improved etching rate by atomic hydrogen in nano-crystalline silicon towards the film/substrate interface region. The optical properties were calculated by applying the effective medium approximation theory, where the existence of bulk and interfacial layers, as inferred from cross-sectional microscopy, were taken into account.

  12. Tailoring of silver wires and their performance as transparent conductive coatings.

    PubMed

    Lu, Y C; Chou, K S

    2010-05-28

    A feasible way to manipulate the scales of Ag wires through the polyol process is presented. By adjusting the amounts of either Pd or Ag precursor used in this process, we demonstrated the ability to control the scale of the wires. The presence of Pd ultrafine particles reduced by EG in advance served as the nuclei for inducing the subsequent formation of Ag wires, and the diameter of the resulting wires was observed to be inversely proportional to the quantity of Pd added. Further, the wire length was demonstrated to be proportional to and highly correlated with the total amount of Ag added, by a linear relationship. A glass plate coated with Ag wire film by the spray method is shown to be both transparent and conductive. The effect of scaling the wires on their performance is also discussed. PMID:20431210

  13. Designing potentials by sculpturing wires

    SciTech Connect

    Della Pietra, Leonardo; Aigner, Simon; Groth, Soenke; Hagen, Christoph von; Schmiedmayer, Joerg; Bar-Joseph, Israel; Lezec, Henri J.

    2007-06-15

    Magnetic trapping potentials for atoms on atom chips are determined by the current flow in the chip wires. By modifying the shape of the conductor we can realize specialized current flow patterns and therefore microdesign the trapping potentials. We have demonstrated this by nano-machining an atom chip using the focused ion beam technique. We built a trap, a barrier, and using a Bose-Einstein Condensate as a probe we showed that by polishing the conductor edge the potential roughness on the selected wire can be reduced. Furthermore, we give different other designs and discuss the creation of a one-dimensional magnetic lattice on an atom chip.

  14. Wire Wise.

    ERIC Educational Resources Information Center

    Swanquist, Barry

    1998-01-01

    Discusses how today's technology is encouraging schools to invest in furnishings that are adaptable to computer use and telecommunications access. Explores issues concerning modularity, wiring management, ergonomics, durability, price, and aesthetics. (GR)

  15. Preparation and antibacterial activities of Ag/Ag+/Ag3+ nanoparticle composites made by pomegranate (Punica granatum) rind extract

    NASA Astrophysics Data System (ADS)

    Yang, Hui; Ren, Yan-yu; Wang, Tao; Wang, Chuang

    Nano-silver and its composite materials are widely used in medicine, food and other industries due to their strong conductivity, size effect and other special performances. So far, more microbial researches have been applied, but a plant method is rarely reported. In order to open up a new way to prepare AgNP composites, pomegranate peel extract was used in this work to reduce Ag+ to prepare Ag/Ag+/Ag3+ nanoparticle composites. UV-Vis was employed to detect and track the reduction of Ag+ and the forming process of AgNPs. The composition, structure and size of the crystal were analyzed by XRD and TEM. Results showed that, under mild conditions, pomegranate peel extract reacted with dilute AgNO3 solution to produce Ag/Ag+/Ag3+ nanoparticle composites. At pH = 8 and 10 mmol/L of AgNO3 concentration, the size of the achieved composites ranged between 15 and 35 nm with spherical shapes and good crystallinity. The bactericidal experiment indicated that the prepared Ag/Ag+/Ag3+ nanoparticles had strong antibacterial activity against gram positive bacteria and gram negative bacteria. FTIR analysis revealed that biological macromolecules with groups of sbnd NH2, sbnd OH, and others were distributed on the surface of the newly synthesized Ag/Ag+/Ag3+ nanoparticles. This provided a useful clue to further study the AgNP biosynthesis mechanism.

  16. Development of Polyamide-imide / Silica Nanocomposite Enameled Wire

    NASA Astrophysics Data System (ADS)

    Kikuchi, Hideyuki; Hanawa, Hidehito; Honda, Yuki

    The nanocomposite material based on polyamide-imide was not able to prevent nano-particles from aggregating up to now, therefore the development of this material was extremely difficult. However we prevented aggregation of nano-particles by developing the hygroscopicity solvent and copolyamide-imide, and commercialized the new partial discharge resistant enameled wire with nanocomposite polyamide-imide insulating material in 2010. The lifetime of newly developed partial discharge resistant nanocomposite polyamide-imide enameled wire has 1000 or more times compared to general organic enameled wire. Moreover lifetime of new wire is also extremely excellent in the high temperature atmosphere.

  17. Effect of Ag Templates on the Formation of Au-Ag Hollow/Core-Shell Nanostructures

    NASA Astrophysics Data System (ADS)

    Tsai, Chi-Hang; Chen, Shih-Yun; Song, Jenn-Ming; Haruta, Mitsutaka; Kurata, Hiroki

    2015-11-01

    Au-Ag alloy nanostructures with various shapes were synthesized using a successive reduction method in this study. By means of galvanic replacement, twined Ag nanoparticles (NPs) and single-crystalline Ag nanowires (NWs) were adopted as templates, respectively, and alloyed with the same amount of Au+ ions. High angle annular dark field-scanning TEM (HAADF-STEM) images observed from different rotation angles confirm that Ag NPs turned into AuAg alloy rings with an Au/Ag ratio of 1. The shifts of surface plasmon resonance and chemical composition reveal the evolution of the alloy ring formation. On the other hand, single-crystalline Ag NWs became Ag@AuAg core-shell wires instead of hollow nanostructure through a process of galvanic replacement. It is proposed that in addition to the ratio of Ag templates and Au ion additives, the twin boundaries of the Ag templates were the dominating factor causing hollow alloy nanostructures.

  18. Effect of Ag Templates on the Formation of Au-Ag Hollow/Core-Shell Nanostructures.

    PubMed

    Tsai, Chi-Hang; Chen, Shih-Yun; Song, Jenn-Ming; Haruta, Mitsutaka; Kurata, Hiroki

    2015-12-01

    Au-Ag alloy nanostructures with various shapes were synthesized using a successive reduction method in this study. By means of galvanic replacement, twined Ag nanoparticles (NPs) and single-crystalline Ag nanowires (NWs) were adopted as templates, respectively, and alloyed with the same amount of Au(+) ions. High angle annular dark field-scanning TEM (HAADF-STEM) images observed from different rotation angles confirm that Ag NPs turned into AuAg alloy rings with an Au/Ag ratio of 1. The shifts of surface plasmon resonance and chemical composition reveal the evolution of the alloy ring formation. On the other hand, single-crystalline Ag NWs became Ag@AuAg core-shell wires instead of hollow nanostructure through a process of galvanic replacement. It is proposed that in addition to the ratio of Ag templates and Au ion additives, the twin boundaries of the Ag templates were the dominating factor causing hollow alloy nanostructures. PMID:26563266

  19. Visible light activity of Ag-loaded and guanidine nitrate-doped nano-TiO2: Degradation of dichlorophenol and antibacterial properties

    EPA Science Inventory

    To utilize visible light, co-doped nano-TiO2 was prepared via “one pot” synthesis using mild reaction conditions and benign precursors. Synthesis was optimized using an appropriate experimental design taking into account silver content and calcination temperature. The optimized ...

  20. Speciation and Lability of Ag-, AgCl- and Ag2S-Nanoparticles in Soil Determined by X-ray Absorption Spectroscopy and Diffusive Gradients in Thin Films

    EPA Science Inventory

    Long-term speciation and lability of silver (Ag-), silver chloride (AgCl-) and silver sulfide nanoparticles (Ag2S-NPs) in soil were studied by X-ray absorption spectroscopy (XAS), and newly developed "nano" Diffusive Gradients in Thin Films (DGT) devices. These nano-D...

  1. No Wires.

    ERIC Educational Resources Information Center

    DeLoughry, Thomas J.

    1995-01-01

    The University of California at Santa Cruz has completed a successful test of a wireless computer network that would enable students and professors to get on line from anywhere on campus. The network, linked by radio waves, could save millions of dollars in campus wiring costs and would better meet student and faculty information needs. (MSE)

  2. Migration of Ag- and TiO2-(Nano)particles from textiles into artificial sweat under physical stress: experiments and exposure modeling.

    PubMed

    von Goetz, N; Lorenz, C; Windler, L; Nowack, B; Heuberger, M; Hungerbühler, K

    2013-09-01

    Engineered nanoparticles (ENP) are increasingly used to functionalize textiles taking advantage, e.g., of the antimicrobial activity of silver (Ag)-ENP or the UV-absorption of titania (TiO2)-ENP. Mobilization and migration of ENPs from the textile into human sweat can result in dermal exposure to these nanoobjects and their aggregates and agglomerates (NOAA). In this study we assessed exposure to NOAA migrating from commercially available textiles to artificial sweat by an experimental setup that simulates wear-and-tear during physical activity. By combining physical stress with incubation in alkaline and acidic artificial sweat solutions we experimentally realized a worst case scenario for wearing functionalized textiles during sports activities. This experimental approach is not limited to NOAA, but can be used for any other textile additive. Out of four investigated textiles, one T-shirt and one pair of trousers with claimed antimicrobial properties were found to release Ag <450 nm in detectable amounts (23-74 μg/g/L). Textiles containing TiO2 for UV protection did not release significant amounts of TiO2 <450 nm, but the antimicrobial T-shirt released both TiO2 and Ag <450 nm. The silver was present in dissolved and particulate form, whereas TiO2 was mainly found as particulate. On the basis of our experimental results we calculated external dermal exposure to Ag and TiO2 for male and female adults per use. For silver, maximal amounts of 17.1 and 8.2 μg/kg body weight were calculated for total and particulate Ag <450 nm, respectively. For TiO2, the exposure levels amount to maximal 11.6 μg/kg body weight for total (mainly particulate) TiO2. In comparison with other human exposure pathways, dermal exposure to NOAA from textiles can be considered comparably minor for TiO2-NOAA, but not for Ag-NOAA. PMID:23786648

  3. First-principles study of the geometry of Ag nanowires growing on a self-assembled Bi nanoline

    NASA Astrophysics Data System (ADS)

    Koga, H.; Ohno, T.

    2007-09-01

    Epitaxial Ag nanowires on a self-assembled Bi nanoline on the Si(001) surface are examined for their geometry and energetic stability at the level of the generalized-gradient approximation. The orientations examined are Ag(001)[100], Ag(110)[100], Ag(111)[110], and Ag(001)[110], where the indices refer to the plane and the direction parallel to the Si(001) surface and the Bi nanoline, respectively. The wires are found to have mostly bulklike structure, except that Ag(001) monolayers undergo extensive reconstruction. The calculated electronic band structure indicates that the Ag wires are metallic wires. Particularly stable among the wires are the Ag(111) wires, having a coincident site lattice interface with the Bi nanoline. The energetic stability generally improves with thickness, indicating that Ag grows through three-dimensional nucleation on the Bi nanoline.

  4. An efficient photocatalyst for degradation of various organic dyes: Ag@Ag2MoO4-AgBr composite.

    PubMed

    Bai, Yu-Yang; Lu, Yi; Liu, Jin-Ku

    2016-04-15

    The Ag2MoO4-AgBr composite was prepared by a facile in-situ anion-exchange method, then the Ag nanoparticles were coated on this composite through photodeposition route to form a novel Ag@Ag2MoO4-AgBr composite. The in-situ Br(-) replacement in a crystal lattice node position of Ag2MoO4 crystal allows for overcoming the resistance of electron transition effectively. Meanwhile silver nano-particles on the surface of Ag@Ag2MoO4-AgBr composite could act as electron traps to intensify the photogeneration electron-hole separation and the subsequent transfer of the trapped electron to the adsorbed O2 as an electron acceptor. As an efficient visible light catalyst, the Ag@Ag2MoO4-AgBr composite exhibited superior photocatalytic activity for the degradation of various organic dyes. The experimental results demonstrated superior photocatalytic rate of Ag@Ag2MoO4-AgBr composite compared to pure AgBr and Ag2MoO4 crystals (37.6% and 348.4% enhancement respectively). The Ag@Ag2MoO4-AgBr composite cloud degraded Rhodamin B, bromophenol blue, and amino black 10b completed in 7min. PMID:26775100

  5. Californium Recovery from Palladium Wire

    SciTech Connect

    Burns, Jon D.

    2014-08-01

    The recovery of 252Cf from palladium-252Cf cermet wires was investigated to determine the feasibility of implementing it into the cermet wire production operation at Oak Ridge National Laboratory’s Radiochemical Engineering Development Center. The dissolution of Pd wire in 8 M HNO3 and trace amounts of HCl was studied at both ambient and elevated temperatures. These studies showed that it took days to dissolve the wire at ambient temperature and only 2 hours at 60°C. Adjusting the ratio of the volume of solvent to the mass of the wire segment showed little change in the kinetics of dissolution, which ranged from 0.176 mL/mg down to 0.019 mL/mg. A successful chromatographic separation of 153Gd, a surrogate for 252Cf, from Pd was demonstrated using AG 50x8 cation exchange resin with a bed volume of 0.5 mL and an internal diameter of 0.8 cm.

  6. Bimetallic Pt-Ag and Pd-Ag nanoparticles

    SciTech Connect

    Lahiri, Debdutta; Bunker, Bruce; Mishra, Bhoopesh; Zhang, Zhenyuan; Meisel, Dan; Doudna, C. M.; Bertino, M. F.; Blum, Frank D.; Tokuhiro, A. T.; Chattopadhyay, Soma; Shibata, Tomohiro; Terry, Jeff

    2005-04-19

    We report studies of bimetallic nanoparticles with 15%–16% atomic crystal parameters size mismatch. The degree of alloying was also probed in a 2-nm Pt core ssmallest attainable core sized of Pt–Ag nanoparticles scompletely immiscible in bulkd and 20-nm-diameter Pd–Ag nanowires scompletely miscible in bulkd. Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical snanowired morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Also, Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd–Ag nanowires alloy similar to previously reported spherical Pd–Ag particles of similar diameter and composition

  7. Bimetallic Pt-Ag and Pd-Ag nanoparticles

    SciTech Connect

    Lahiri, Debdutta; Bunker, Bruce; Mishra, Bhoopesh; Zhang, Zhenyuan; Meisel, Dan; Doudna, C.M.; Bertino, M. F.; Blum, Frank D.; Tokuhiro, A.T.; Chattopadhyay, Soma; Shibata, Tomohiro; Terry, Jeff

    2005-05-01

    We report studies of bimetallic nanoparticles with 15%-16% atomic crystal parameters size mismatch. The degree of alloying was probed in a 2-nm Pt core (smallest attainable core size) of Pt-Ag nanoparticles (completely immiscible in bulk) and 20-nm-diameter Pd-Ag nanowires (completely miscible in bulk). Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical (nanowire) morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd-Ag nanowires alloy similar to previously reported spherical Pd-Ag particles of similar diameter and composition.

  8. Precision wire feeder for small diameter wire

    DOEpatents

    Brandon, E.D.; Hooper, F.M.; Reichenbach, M.L.

    1992-08-11

    A device for feeding small diameter wire having a diameter less than 0.04 mm (16 mil) to a welding station includes a driving wheel for controllably applying a non-deforming driving force to the wire to move the free end of the wire towards the welding station; and a tension device such as a torque motor for constantly applying a reverse force to the wire in opposition to the driving force to keep the wire taut. 1 figure.

  9. Precision wire feeder for small diameter wire

    DOEpatents

    Brandon, Eldon D.; Hooper, Frederick M.; Reichenbach, Marvin L.

    1992-01-01

    A device for feeding small diameter wire having a diameter less than 0.04 mm (16 mil) to a welding station includes a driving wheel for controllably applying a non-deforming driving force to the wire to move the free end of the wire towards the welding station; and a tension device such as a torque motor for constantly applying a reverse force to the wire in opposition to the driving force to keep the wire taut.

  10. SERS activity of Ag decorated nanodiamond and nano-β-SiC, diamond-like-carbon and thermally annealed diamond thin film surfaces.

    PubMed

    Kuntumalla, Mohan Kumar; Srikanth, Vadali Venkata Satya Siva; Ravulapalli, Satyavathi; Gangadharini, Upender; Ojha, Harish; Desai, Narayana Rao; Bansal, Chandrahas

    2015-09-01

    In the recent past surface enhanced Raman scattering (SERS) based bio-sensing has gained prominence owing to the simplicity and efficiency of the SERS technique. Dedicated and continuous research efforts have been made to develop SERS substrates that are not only stable, durable and reproducible but also facilitate real-time bio-sensing. In this context diamond, β-SiC and diamond-like-carbon (DLC) and other related thin films have been promoted as excellent candidates for bio-technological applications including real time bio-sensing. In this work, SERS activities of nanodiamond, nano-β-SiC, DLC, thermally annealed diamond thin film surfaces were examined. DLC and thermally annealed diamond thin films were found to show SERS activity without any metal nanostructures on their surfaces. The observed SERS activities of the considered surfaces are explained in terms of the electromagnetic enhancement mechanism and charge transfer resonance process. PMID:25691097

  11. Quantum stability and magic lengths of metal atom wires

    NASA Astrophysics Data System (ADS)

    Cui, Ping; Choi, Jin-Ho; Lan, Haiping; Cho, Jun-Hyung; Niu, Qian; Yang, Jinlong; Zhang, Zhenyu

    2016-06-01

    Metal atom wires represent an important class of nanomaterials in the development of future electronic devices and other functional applications. Using first-principles calculations within density functional theory, we carry out a systematic study of the quantum stability of freestanding atom wires consisting of prototypical metal elements with s -, s p -, and s d -valence electrons. We explore how the quantum mechanically confined motion and local bonding of the valence electrons in these different wire systems can dictate their overall structural stability and find that the formation energy of essentially all the wires oscillates with respect to their length measured by the number n of atoms contained in the wires, establishing the existence of highly preferred (or magic) lengths. Furthermore, different wire classes exhibit distinctively different oscillatory characteristics and quantum stabilities. Alkali metal wires possessing an unpaired s valence electron per atom exhibit simple damped even-odd oscillations. In contrast, Al and Ga wires containing three s2p1 valence electrons per atom generally display much larger and undamped even-odd energy oscillations due to stronger local bonding of the p orbitals. Among the noble metals, the s -dominant Ag wires behave similarly to the linear alkali metal wires, while Au and Pt wires distinctly prefer to be structurally zigzagged due to strong relativistic effects. These findings are discussed in connection with existing experiments and should also be instrumental in future experimental realization of different metal atom wires in freestanding or supported environments with desirable functionalities.

  12. THE AGS ELECTROSTATIC SEPTUM.

    SciTech Connect

    HOCK,J.RUSSO,T.GLEN,J.BROWN,K.

    2003-05-12

    The previous slow beam extraction electro static septum in the AGS was designed in 1981. Research documented at the Fermi Laboratory was used as the base line for this design. The septum consisted of a ground plane of .002 inch diameter wire tungsten-rhenium alloy (75%W 25%Re) with a hollow welded titanium cathode assembly. The vacuum chamber is stationary and the septum is moved with a pair of high vacuum linear feed throughs. After years of beam time, the frequency of failures increased. The vacuum system design was poor by today's standards and resulted in long pump down times after repairs. The failures ranged from broken septum wires to a twisted cathode. In addition to the failures, the mechanical drive system had too much backlash, making the operating position difficult to repeat. The new septum needed to address all of these issues in order to become a more reliable septum.

  13. Windows: Life after Wire.

    ERIC Educational Resources Information Center

    Razwick, Jerry

    2003-01-01

    Although wired glass is extremely common in school buildings, the International Building Code adopted new standards that eliminate the use of traditional wired glass in K-12 schools, daycare centers, and athletic facilities. Wired glass breaks easily, and the wires can cause significant injuries by forming dangerous snags when the glass breaks.…

  14. Stretched Wire Mechanics

    SciTech Connect

    Bowden, Gordon; /SLAC

    2005-09-06

    Stretched wires are beginning to play an important role in the alignment of accelerators and synchrotron light sources. Stretched wires are proposed for the alignment of the 130 meter long LCLS undulator. Wire position technology has reached sub-micron resolution yet analyses of perturbations to wire straightness are hard to find. This paper considers possible deviations of stretched wire from the simple 2-dimensional catenary form.

  15. Concealed wire tracing apparatus

    DOEpatents

    Kronberg, James W.

    1994-01-01

    An apparatus and method that combines a signal generator and a passive signal receiver to detect and record the path of partially or completely concealed electrical wiring without disturbing the concealing surface. The signal generator applies a series of electrical pulses to the selected wiring of interest. The applied pulses create a magnetic field about the wiring that can be detected by a coil contained within the signal receiver. An audible output connected to the receiver and driven by the coil reflects the receivers position with respect to the wiring. The receivers audible signal is strongest when the receiver is directly above the wiring and the long axis of the receivers coil is parallel to the wiring. A marking means is mounted on the receiver to mark the location of the wiring as the receiver is directed over the wiring's concealing surface. Numerous marks made on various locations of the concealing surface will trace the path of the wiring of interest.

  16. Wire Test Grip Fixture

    NASA Technical Reports Server (NTRS)

    Burke, Christopher S.

    2011-01-01

    Wire-testing issues, such as the gripping strains imposed on the wire, play a critical role in obtaining clean data. In a standard test frame fitted with flat wedge grips, the gripping action alone creates stresses on the wire specimen that cause the wire to fail at the grip location. A new test frame, which is outfitted with a vacuum chamber, negated the use of any conventional commercially available wire test fixtures, as only 7 in. (17.8 cm) existed between the grip faces. An innovative grip fixture was designed to test thin gauge wire for a variety of applications in an existing Instron test frame outfitted with a vacuum chamber.

  17. Flexible and insulative Plasmalene wire coatings for biomedical applications.

    PubMed

    Nichols, M F

    1993-01-01

    A novel polymeric material, Plasmalene, was synthesized and tested as a functional hermetic polymer coating on Gold, Platinum, and MP35N wire substrates. The flexible Plasmalene polymer coatings were synthesized onto wire substrates by vacuum processes which included radio frequency (RF) initiated plasma polymerization and thermal vapor deposition of methane and xylylene monomers. Mechanical and electrical tests were performed on 75 micron wires coated with either Plasmalene, Parylene, or Teflon polymers. The coated wire substrates were mounted on a flex testing machine that was submerged in a saline bath. A +5VDC electrical bias was continuously applied between the wire substrates and the bath. The flex testing machine mechanically stressed the coatings for 50,000 cycles with tensile and compressive loadings of up to 11% strain. The cyclic strain was applied through a total flexural arc of 170 degrees. Electrical leakage currents were measured through the polymer films to the saline bath at +5VDC versus a Ag/AgCl reference electrode. Analysis of the leakage current data for the Parylene and Teflon coated wires indicated that there was a significant (alpha = 0.05) increase, up to microampere levels, in leakage currents through the films as a result of repeated cyclic stressing. Plasmalene coated wires showed no significant increase in initial picoampere leakage currents with cycling and therefore, demonstrated that a superior insulative and mechanically durable film can be synthesized as a wire encapsulant. PMID:8329639

  18. Magnetic and electronic structure of Mn nanostructures on Ag(111) and Au(111)

    NASA Astrophysics Data System (ADS)

    Cardias, R.; Bezerra-Neto, M. M.; Ribeiro, M. S.; Bergman, A.; Szilva, A.; Eriksson, O.; Klautau, A. B.

    2016-01-01

    We present results of the electronic and magnetic structure of Mn nanowires adsorbed on Ag(111) and Au(111) surfaces. For finite Mn nanowires on Ag(111) and Au(111) surfaces, our ab initio results show that the large difference between the spin-orbit splitting of these two surfaces leads to completely different magnetic configurations. The magnetic ordering for Mn nanowires adsorbed on Ag(111) is governed by the strong exchange interaction between Mn adatoms. For Mn nano-chains on Au(111), the competition between Heisenberg and Dzyaloshinskii-Moriya interactions leads to a complex magnetic structure of the clusters considered here. Among the more conspicuous results we note a spin-spiral helical type for the nanowire with seven atoms, and a complex magnetic configuration incommensurate with the substrate lattice for a double-sized Mn wire. The effect of the structural relaxation is also investigated, showing sensitivity of the exchange interactions to the bond distance to the substrate. We also demonstrate that small changes in the band filling of these Mn chains results in drastically different changes of the interatomic exchange. Finally, we show that dispersion of the electronic energy spectrum is possible even in nanostructures with bounded spatial extension.

  19. Cable Bundle Wire Derating

    NASA Technical Reports Server (NTRS)

    Lundquist, Ray A.; Leidecker, Henning

    1998-01-01

    The allowable operating currents of electrical wiring when used in the space vacuum environment is predominantly determined by the maximum operating temperature of the wire insulation. For Kapton insulated wire this value is 200 C. Guidelines provided in the Goddard Space Flight Center (GSFC) Preferred Parts List (PPL) limit the operating current of wire within vacuum to ensure the maximum insulation temperature is not exceeded. For 20 AWG wire, these operating parameters are: 3.7 amps per wire, bundle of 15 or more wires, 70 C environment, and vacuum of 10(exp -5) torr or less. To determine the behavior and temperature of electrical wire at different operating conditions, a thermal vacuum test was performed on a representative electrical harness of the Hubble Space Telescope (HST) power distribution system. This paper describes the test and the results.

  20. Cable Bundle Wire Derating

    NASA Technical Reports Server (NTRS)

    Lundquist, Ray A.; Leidecker, Henning

    1998-01-01

    The allowable operating currents of electrical wiring when used in the space vacuum environment is predominantly determined by the maximum operating temperature of the wire insulation. For Kapton insulated wire this value is 200 C. Guidelines provided in the Goddard Space Flight Center (GSFC) Preferred Parts List (PPL) limit the operating current of wire within vacuum to ensure the maximum insulation temperature is not exceeded. For 20 AWG wire, these operating parameters are: (1) 3.7 amps per wire; (2) bundle of 15 or more wires; (3) 70 C environment: and (4) vacuum of 10(exp -5) torr or less. To determine the behavior and temperature of electrical wire at different operating conditions, a thermal vacuum test was performed on a representative electrical harness of the Hubble Space Telescope (HST) power distribution system. This paper describes the test and the results.

  1. Cable Bundle Wire Derating

    NASA Technical Reports Server (NTRS)

    Lundquist, Ray A.; Leidecker, Henning

    1999-01-01

    The allowable operating currents of electrical wiring when used in the space vacuum environment is predominantly determined by the maximum operating temperature of the wire insulation. For Kapton insulated wire this value is 200 degree C. Guidelines provided in the Goddard Space Flight Center (GSFC) Preferred Parts List (PPL) limit the operating current of wire within vacuum to ensure the maximum insulation temperature is not exceeded. For 20 AWG wire, these operating parameters are: (1) 3.7 amps per wire (2) bundle of 15 or more wires (3) 70 C environment (4) vacuum of 10(exp -5) torr or less To determine the behavior and temperature of electrical wire at different operating conditions, a thermal vacuum test was performed on a representative electrical harness of the Hubble Space Telescope (HST) power distribution system. This paper describes the test and the results.

  2. Synthesis and characterization of nanostructured Ag on porous titania

    NASA Astrophysics Data System (ADS)

    Wen, Ming; Li, Yanqiong; Zhang, Junmin; Guan, Weiming; Li, Yuncang; Wen, Cui'e.; Hodgson, Peter

    2011-03-01

    In this work, porous titania was prepared on bulk Ti by chemical oxidation, and then nanostructured silver (Ag) was deposited on titania surface by ion beam sputtering. After annealing treatment, Ag/TiO 2 composites were characterized using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results indicated that a nano-porous titania layer with mean pore size of 150 nm and thickness of 1 μm was formed by chemical oxidation at 80 °C for 45 min. There were three Ag species (Ag (0), Ag (1+), and Ag (2+)) on composites surface after annealing treatment, and metallic Ag content achieved maximum value with annealing temperature of 500 °C in air. Ag showed high thermal stability being partly attributed to the inhibiting the diffusion of Ag by the underlying porous titania.

  3. Laser Wire Stripper

    NASA Technical Reports Server (NTRS)

    1983-01-01

    NASA-developed space shuttle technology is used in a laser wire stripper designed by Raytheon Company. Laser beams cut through insulation on a wire without damaging conductive metal, because laser radiation that melts plastic insulation is reflected by the metal. The laser process is fast, clean, precise and repeatable. It eliminates quality control problems and the expense of rejected wiring.

  4. Ohmic contact effect of Ag-nanodots on quantum efficiency of Si solar cell.

    PubMed

    Choi, Jaeho; Parida, Bhaskar; Ji, Hyung Yong; Park, Seungil; Kim, Keunjoo

    2012-07-01

    The authors investigated Si solar cell with the inclusion of nano-Ag dots using the ink-jet printer. These nano-Ag dots were used for the Ohmic contact layer on phospho-silicate glass layer, which was not removed after the formation of Si emitter layer by phosphorus diffusion process. The SiNx layer deposited on the nano-Ag dots shows the catalyst selective growth and so the layer formed beneath of nano-Ag dots. The photoreflectances show that the long wavelength from 360 nm to 1200 nm tends to be increased as the density of the nano-Ag is increased. In case of short wavelength from 294 nm to 367 nm, it shows the opposite trend, indicating the plasmon effect of the nano-Ag. As embedding the nano-Ag dots on the phospho-silicate glass layer, the blocked Ohmic contact was opened and the quantum efficiency of 14.4% was achieved, which is higher than the reference sample of 12.72% without the glass layer. The nano-Ag dots form the good Ohmic contact and also enhance the light conversion efficiency with the formation of surface plasmon. PMID:22966609

  5. Thermoelectric Mechanism and Interface Characteristics of Cyanide-Free Nanogold-Coated Silver Wire

    NASA Astrophysics Data System (ADS)

    Tseng, Yi-Wei; Hung, Fei-Yi; Lui, Truan-Sheng

    2016-01-01

    Traditional bath-plated gold contains a cyanide complex, which is an environmental hazard. In response, our study used a green plating process to produce cyanide-free gold-coated silver (cyanide-free ACA) bonding wire that has been proven to be a feasible alternative to gold bonding wire in semiconductor packaging. In this work, ACA wire annealed at 550°C was found to have stable microstructure and superior mechanical properties. Intermetallic compounds Ag2Al and AuAl2 grew from Ag-Au balls and Al pads after aging at 175°C for 500 h. After current testing, ACA wire was found to have improved electrical properties due to equiaxed grain growth. The gold nanolayer on the Ag surface increased the oxidation resistance. These results provide insights regarding the reliability of ACA wire in advanced bonding processes.

  6. Fabrication Routes for High Strength High Conductivity Wires

    SciTech Connect

    Han, K.; Embury, J.D.; Sims, J.R.; Pantsyrnyi, V.I.; Shikov, A.; Bochvar, A.A.

    1998-10-01

    The development of suitable wires for magnet windings requires both the attainment of suitable combinations of properties (electrical conductivity and strength), the development of a production route capable of fabricating suitable quantity of wire of required dimension (5.2x7.6mm{sup 2} cross-section and 120 m in length) and a product with acceptable fabricability, joinability and service life. In this survey, the authors consider methods of producing suitable wire products by the codeformation of in-situ composites. This will include details of the quality control of the processing of Cu-Ag and Cu-Nb and the assessment of their detailed mechanical properties.

  7. WO3 nano-spheres into W18O49 one-dimensional nano-structures through thermal annealing.

    PubMed

    Mwakikunga, B W; Sideras-Haddad, E; Arendse, C; Witcomb, M J; Forbes, A

    2009-05-01

    We elaborate the size controlled synthesis of nano-spheres and nano-crystals of WO3 by ultrasonic spray pyrolysis. The as-deposited particles are predominantly spherical in shape and tend to exhibit less agglomeration and a decrease in diameter as the process temperature is increased. Characterization was carried out using transmission (TEM) and scanning (SEM) electron microscopy, energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). One-dimensional nano-structures with the highest yield of WOx nano-wires were observed in a sample synthesized at 500 degrees C but only after thermal annealing of this sample at 500 degrees C for 17 hour in flowing argon. XRD revealed a high deficiency in oxygen in all samples suggesting that the nano-structures are transformed to sub-oxides of tungsten. Micro-diffraction patterns of a typical nano-wire reveal the monoclinic phase of W18O49. PMID:19453005

  8. Study of the oxygen transport through Ag (110), Ag (poly), and Ag 2.0 Zr

    NASA Technical Reports Server (NTRS)

    Outlaw, R. A.; Wu, D.; Davidson, M. R.; Hoflund, Gar B.

    1992-01-01

    The transport of oxygen through high-purity membranes of Ag (110), Ag (poly), Ag (nano), and Ag 2.0 Zr has been studied by an ultrahigh vacuum permeation method over the temperature range of 400-800 C. The data show that there are substantial deviations from ordinary diffusion-controlled transport. A surface limitation has been confirmed by glow-discharge studies where the upstream O2 supply has been partially converted to atoms, which, for the same temperature and pressure, gave rise to over an order of magnitude increase in transport flux. Further, the addition of 2.0 wt percent Zr to the Ag has provided increased dissociative adsorption rates, which, in turn, increased the transport flux by a factor of 2. It was also observed that below a temperature of 630 C, the diffusivity exhibits an increase in activation energy of over 4 kcal/mol, which has been attributed to trapping of the atomic oxygen and/or kinetic barriers at the surface and subsurface of the vacuum interface. Above 630 C, the activation barrier decreases to the accepted value of about 11 kcal/mol for Ag (poly), consistent with zero concentration at the vacuum interface.

  9. Depositing High-T(sub c) Superconductors On Normal-Conductor Wires

    NASA Technical Reports Server (NTRS)

    Kirlin, Peter S.

    1994-01-01

    Experiments have demonstrated feasibility of depositing thin layers of high-T(sub c) superconductor on normally electrically conductive wires. Superconductivity evident at and below critical temperature (T{sub c}) of 71 K. OMCVD, organometallic vapor deposition, apparatus coats Ag wire with layer high-T(sub c) superconductor. Superconductive phase of this material formed subsequently by annealing under controlled conditions.

  10. Growth of Ag nanowires on Au-pre-facetted 4° vicinal Si(0 0 1)

    NASA Astrophysics Data System (ADS)

    Meyer zu Heringdorf, Frank-J.; Roos, Kimberly L.; Wiethoff, Christian; Horn-von Hoegen, Michael; Roos, Kelly R.

    2008-05-01

    We studied the self-assembly of wire-shaped Ag islands at high temperature with low energy electron microscopy and photoemission electron microscopy. A Au-faceted vicinal Si(0 0 1) surface was used as a substrate. The initial Ag deposit at 600-620 °C induces a surface phase change from the (5 × 3.2) reconstruction of the Au-covered (0 0 1) terraces, to a (3 × 2) reconstruction, but leaves the structure of the Au-induced step bunches intact. Subsequent Ag growth produces two distinct types of 3D crystalline islands: compact and wire-like. The total Ag deposit is comprised mostly of compact islands, with only a small minority of wire-like islands. We attribute the wire formation to local step bunches that create the proper quasi-one-dimensional diffusion environment for the Ag islands to grow with a high aspect ratio.

  11. 30 CFR 77.1802 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 77.1802 Section 77.1802... Wires and Trolley Feeder Wires § 77.1802 Insulation of trolley wires, trolley feeder wires and...

  12. 30 CFR 75.1003 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 75.1003 Section 75.1003... Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires...

  13. 30 CFR 75.1003 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 75.1003 Section 75.1003... Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires...

  14. 30 CFR 77.1802 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 77.1802 Section 77.1802... Wires and Trolley Feeder Wires § 77.1802 Insulation of trolley wires, trolley feeder wires and...

  15. 30 CFR 77.1802 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 77.1802 Section 77.1802... Wires and Trolley Feeder Wires § 77.1802 Insulation of trolley wires, trolley feeder wires and...

  16. 30 CFR 75.1003 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 75.1003 Section 75.1003... Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires...

  17. 30 CFR 75.1003 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 75.1003 Section 75.1003... Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires...

  18. 30 CFR 77.1802 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 77.1802 Section 77.1802... Wires and Trolley Feeder Wires § 77.1802 Insulation of trolley wires, trolley feeder wires and...

  19. 30 CFR 77.1802 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 77.1802 Section 77.1802... Wires and Trolley Feeder Wires § 77.1802 Insulation of trolley wires, trolley feeder wires and...

  20. 30 CFR 75.1003 - Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires and trolley feeder wires. 75.1003 Section 75.1003... Insulation of trolley wires, trolley feeder wires and bare signal wires; guarding of trolley wires...

  1. Thin wire pointing method

    NASA Technical Reports Server (NTRS)

    Green, G.; Mattauch, R. J. (Inventor)

    1983-01-01

    A method is described for forming sharp tips on thin wires, in particular phosphor bronze wires of diameters such as one-thousandth inch used to contact micron size Schottky barrier diodes, which enables close control of tip shape and which avoids the use of highly toxic solutions. The method includes dipping an end of a phosphor bronze wire into a dilute solution of sulfamic acid and applying a current through the wire to electrochemically etch it. The humidity in the room is controlled to a level of less than 50%, and the voltage applied between the wire and another electrode in the solutions is a half wave rectified voltage. The current through the wire is monitored, and the process is stopped when the current falls to a predetermined low level.

  2. Sintered wire annode

    DOEpatents

    Falce, Louis R.; Ives, R. Lawrence

    2007-12-25

    A plurality of high atomic number wires are sintered together to form a porous rod that is parted into porous disks which will be used as x-ray targets. A thermally conductive material is introduced into the pores of the rod, and when a stream of electrons impinges on the sintered wire target and generates x-rays, the heat generated by the impinging x-rays is removed by the thermally conductive material interspersed in the pores of the wires.

  3. Zinc wired rebar

    SciTech Connect

    Zhang, X.G.; Hwang, J.

    1997-02-01

    A novel method for corrosion protection of rebar in concrete is reported wherein it is galvanically protected by attaching a zinc wire along its length. The self-corrosion and galvanic-corrosion loss of the zinc wire is dependent on the water/cement ratio, the size of the cathode, and the concrete cover thickness. The wire acts as a sacrificial anode when the rebar embedded in concrete is exposed to corrosive environments.

  4. Concealed wire tracing apparatus

    DOEpatents

    Kronberg, J.W.

    1994-05-31

    An apparatus and method that combines a signal generator and a passive signal receiver to detect and record the path of partially or completely concealed electrical wiring without disturbing the concealing surface is disclosed. The signal generator applies a series of electrical pulses to the selected wiring of interest. The applied pulses create a magnetic field about the wiring that can be detected by a coil contained within the signal receiver. An audible output connected to the receiver and driven by the coil reflects the receivers position with respect to the wiring. The receivers audible signal is strongest when the receiver is directly above the wiring and the long axis of the receivers coil is parallel to the wiring. A marking means is mounted on the receiver to mark the location of the wiring as the receiver is directed over the wiring's concealing surface. Numerous marks made on various locations of the concealing surface will trace the path of the wiring of interest. 4 figs.

  5. Weld Wire Investigation Summary

    SciTech Connect

    Cunningham, M.A.

    1999-03-22

    After GTA welding reservoir A production/process prove-in assemblies, X-ray examination detected a lack of sidewall fusion. After examining several possible causes, it was determined that the weld wire filler metal was responsible, particularly the wire cleaning process. The final conclusion was that the filler wire must be abrasively cleaned in a particular manner to perform as required. The abrasive process was incorporated into the wire material specification, ensuring consistency for all reservoir GTA welding at AlliedSignal Federal Manufacturing and Technologies (FM and T).

  6. Wire-inhomogeneity detector

    DOEpatents

    Gibson, G.H.; Smits, R.G.; Eberhard, P.H.

    1982-08-31

    A device for uncovering imperfections in electrical conducting wire, particularly superconducting wire, by detecting variations in eddy currents. Eddy currents effect the magnetic field in a gap of an inductor, contained in a modified commercial ferrite core, through which the wire being tested is passed. A small increase or decrease in the amount of conductive material, such as copper, in a fixed cross section of wire will unbalance a bridge used to measure the impedance of the inductor, tripping a detector and sounding an alarm.

  7. 1998 wire development workshop proceedings

    SciTech Connect

    1998-04-01

    This report consists of vugraphs of the presentations at the conference. The conference was divided into the following sessions: (1) First Generation Wire Development: Status and Issues; (2) First Generation Wire in Pre-Commercial Prototypes; (3) Second Generation Wire Development: Private Sector Progress and Issues; (4) Second Generation Wire Development: Federal Laboratories; and (5) Fundamental Research Issues for HTS Wire Development.

  8. VIEW SOUTHEASTBUILDING 4 NO. 1 WIRE MILL (1871) WIRE DRAWING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW SOUTHEAST-BUILDING 4 NO. 1 WIRE MILL (1871) WIRE DRAWING MACHINE - John A. Roebling's Sons Company & American Steel & Wire Company, South Broad, Clark, Elmer, Mott & Hudson Streets, Trenton, Mercer County, NJ

  9. Recent development of drastically innovative BSCCO wire (DI-BISCCO)

    NASA Astrophysics Data System (ADS)

    Kikuchi, M.; Kato, T.; Ohkura, K.; Ayai, N.; Fujikami, J.; Fujino, K.; Kobayashi, S.; Ueno, E.; Yamazaki, K.; Yamade, S.; Hayashi, K.; Sato, K.; Nagai, T.; Matsui, Y.

    2006-10-01

    Up to this day, Ag-sheathed Bi2223 superconducting wires have been widely investigated and the long wires about 1000 m have been produced by using powder-in-tube (PIT) method on a commercial basis in the various facilities or companies. Although the wires are used for some applications such as HTS cables, magnets, motor and so on, the Bi2223 wires not only require much more improvements of the superconducting properties such as critical current, mechanical properties, but also longer and more uniform wires. Recently, the performances of Bi2223 wires have been drastically improved by using Controlled Over Pressure (CT-OP) sintering process. CT-OP process increased critical current (Ic) by more than 60% at 77 K and self field and improved the mechanical strength by more than 70%. The maximum Ic was increased up to 166 A. These drastic improvements were caused by the higher density of Bi2223 filament up to almost 100% and better connectivity of the Bi2223 grains. The dense structure of the Bi2223 filaments prevents the ballooning phenomenon which is caused by the gasification of the trapped liquid nitrogen during temperature rise. Additionally, higher uniformity and higher production yield of long length wire were also achieved by exterminating defects during sintering. These high performance levels in CT-OP wires have contributed commercial level applications. We call as Drastically Innovative BSCCO (DI-BSCCO).

  10. On the influence of magnetic field processing on the texture, phase assemblage and properties of low aspect ratio Bi2 Sr2 CaCu2 Ox /AgMg wire

    NASA Astrophysics Data System (ADS)

    Liu, Xiaotao; Schwartz, Justin

    2009-01-01

    Bi2 Sr2 CaCu2 Ox /AgMg conductors are potentially important for many applications up to 20 K, including magnets for cryogen-free magnetic resonance imaging and high field nuclear magnetic resonance research. One promising approach to increased critical current density is partial-melt processing in the presence of a magnetic field which has been shown to enhance c-axis texturing of wide, thin tape conductors. Here, we report on low aspect ratio rectangular conductors processed in an 8 T magnetic field. The magnetic field is applied during different stages of the heat treatment process. The conductors are electrically characterized using four-point critical current measurements as a function of magnetic field and magnetic field orientation relative to the conductor. The superconductive transition and magnetization hysteresis are measured using a SQUID magnetometer. The microstructures are characterized using scanning electron microscopy and energy dispersive spectroscopy and analyzed using digital image processing. It is found that the presence of a magnetic field during split melt processing enhances the electrical transport and magnetic behavior, but that the anisotropy is not consistently affected. The magnetic field also affects development of interfilamentary Bi2212 bridges, and that this depends on the initial shape of the Bi2212 filament. At least two behaviors are identified; one impacts the oxide phase assemblage and the other impacts textured growth.

  11. Commercial and Industrial Wiring.

    ERIC Educational Resources Information Center

    Kaltwasser, Stan; Flowers, Gary

    This module is the third in a series of three wiring publications, includes additional technical knowledge and applications required for job entry in the commercial and industrial wiring trade. The module contains 15 instructional units that cover the following topics: blueprint reading and load calculations; tools and equipment; service;…

  12. 2016 MOST WIRED.

    PubMed

    Barr, Paul; Butcher, Lola; Hoppszallern, Suzanna

    2016-07-01

    This year's IT survey shows that hospitals are aggressively fighting cyber crime and looking for ways to use data to help in the transition to value-based care. Find out who made the 2016 lists of Most Wired, Most Advanced, Most Improved and Most Wired-Small and Rural. PMID:27526506

  13. The exploding wire phenomenon

    NASA Astrophysics Data System (ADS)

    Aspden, H.

    1985-02-01

    Graneau's recent interpretation of the exploding wire phenomenon as an electrodynamic effect verifying Ampère's classical formulation is questioned. Instead, it is shown that the rupturing force arising from the imbalance of the self-induced electromotive force and the ohmic potential during an explosive current surge will account for the wire breaking into several segments, as is observed.

  14. Water Desalination with Wires.

    PubMed

    Porada, S; Sales, B B; Hamelers, H V M; Biesheuvel, P M

    2012-06-21

    We show the significant potential of water desalination using a novel capacitive wire-based technology in which anode/cathode wire pairs are constructed from coating a thin porous carbon electrode layer on top of electrically conducting rods (or wires). By alternately dipping an array of electrode pairs in freshwater with and in brine without an applied cell voltage, we create an ion adsorption/desorption cycle. We show experimentally how in six subsequent cycles we can reduce the salinity of 20 mM feed (brackish) water by a factor of 3, while application of a cation exchange membrane on the cathode wires makes the desalination factor increase to 4. Theoretical modeling rationalizes the experimental findings, and predicts that system performance can be significantly enhanced by material modifications. To treat large volumes of water, multiple stacks of wire pairs can be used simultaneously in a "merry-go-round" operational mode. PMID:26285717

  15. International space station wire program

    NASA Technical Reports Server (NTRS)

    May, Todd

    1995-01-01

    Hardware provider wire systems and current wire insulation issues for the International Space Station (ISS) program are discussed in this viewgraph presentation. Wire insulation issues include silicone wire contamination, Tefzel cold temperature flexibility, and Russian polyimide wire insulation. ISS is a complex program with hardware developed and managed by many countries and hundreds of contractors. Most of the obvious wire insulation issues are known by contractors and have been precluded by proper selection.

  16. Superhydrophobic Ag decorated ZnO nanostructured thin film as effective surface enhanced Raman scattering substrates

    NASA Astrophysics Data System (ADS)

    Jayram, Naidu Dhanpal; Sonia, S.; Poongodi, S.; Kumar, P. Suresh; Masuda, Yoshitake; Mangalaraj, D.; Ponpandian, N.; Viswanathan, C.

    2015-11-01

    The present work is an attempt to overcome the challenges in the fabrication of super hydrophobic silver decorated zinc oxide (ZnO) nanostructure thin films via thermal evaporation process. The ZnO nanowire thin films are prepared without any surface modification and show super hydrophobic nature with a contact angle of 163°. Silver is further deposited onto the ZnO nanowire to obtain nanoworm morphology. Silver decorated ZnO (Ag@ZnO) thin films are used as substrates for surface enhanced Raman spectroscopy (SERS) studies. The formation of randomly arranged nanowire and silver decorated nanoworm structure is confirmed using FESEM, HR-TEM and AFM analysis. Crystallinity and existence of Ag on ZnO are confirmed using XRD and XPS studies. A detailed growth mechanism is discussed for the formation of the nanowires from nanobeads based on various deposition times. The prepared SERS substrate reveals a reproducible enhancement of 3.082 × 107 M for Rhodamine 6G dye (R6G) for 10-10 molar concentration per liter. A higher order of SERS spectra is obtained for a contact angle of 155°. Thus the obtained thin films show the superhydrophobic nature with a highly enhanced Raman spectrum and act as SERS substrates. The present nanoworm morphology shows a new pathway for the construction of semiconductor thin films for plasmonic studies and challenges the orderly arranged ZnO nanorods, wires and other nano structure substrates used in SERS studies.

  17. Superconducting and Mechanical Properties of Bi-2223/Metal Alloy Wires Composite Bulk

    NASA Astrophysics Data System (ADS)

    Yoshizawa, S.; Hirano, S.; Oya-Seimiya, Y.; Hishinuma, Y.; Nishimura, A.

    2006-03-01

    Bi-2223 sintered bulk samples with addition of AgMg wires or Ag-plated Ni wires have been prepared to improve both the superconducting and the mechanical properties, simultaneously. When 24 AgMg wires of 0.4 mm in diameter were added into Bi-2223 bulk composite sample, the critical current density (Jc) at 77 K increased from 2 A/mm2 to 7 A/mm2. The mechanical properties have been estimated by a three-point bending test. The maximum bending stress of 70 - 90 MPa at the rupture was obtained for Bi-2223/metal wires composite bulk, regardless of the number of the wires. After the maximum bending stress, Bi-2223 bulk without metal wires fractured separately, while the composite did not fracture but fine cracks were induced only. The Jc values of the composites just after the fracture were about half of the Jc value in the composites without bending. It has been observed that the superconducting current flows even after cracking, in Bi-2223 bulk with metal wires. This is due to the fact that metal wires suppress progress of fine cracks just after the fracture, while the superconducting current flows in the uncracked region. This current still remaining after the fracture is a very important feature for the applications.

  18. Investigation of optimal silver nanowires film as conductive wires for LED

    NASA Astrophysics Data System (ADS)

    Wu, I. C.; Yang, T. L.; Pan, C. T.; Chen, Y. C.; Hung, K. H.

    2015-03-01

    In the study, the Polyol reduction process was used to fabricate silver nanowires (AgNWs). In the experiment, the ratio of PVP/Ag, silver seed, AgNO3 and the amount of ethylene glycol (EG) were adopted to design orthogonal array with a constant temperature and heating time and the synthesis parameters of AgNWs were obtained. Therefore, the optimal AgNWs solution was obtained, followed by centrifuging to obtain AgNWs which were used to fabricate AgNWs film. The scanning electron microscope (SEM), Fourier Transform Infrared Spectroscope (FTIR), Energy Dispersive Spectrometer (EDS) and four-point probe were used to measure the sheet resistant and transmittance of AgNWs film. Moreover, the AgNWs film was adopted to be the conductive wires of LED. From the experiment results, the synthesis parameter of 15ml EG, 0.01g AgCl, ratio 2 of PVP/Ag and 0.22g AgNO3 could be used to fabricate optimal AgNWs with 45nm average diameter, 5μm average length and aspect ratio of 110. The sheet resistance and transmittance of film fabricated by centrifuged AgNWs was 0.1252 Ω/sq and 70%, respectively. Furthermore, the luminance of LED with conductive wires made of AgNWs film was better than that made of commercial silver plastic. In the future, the AgNWs film can be broadly applied to the conductive films of touch electric products, LCD display and solar panels.

  19. Stability of magnetic nano-structures against erroneous shape modifications

    NASA Astrophysics Data System (ADS)

    Blachowicz, T.; Ehrmann, A.

    2016-04-01

    Magnetic nano-structures can be used in various applications. Due to their possible utilization in data storage media, examinations of nano-structured systems often aim at decreasing the pattern size, in order to enhance the possible information density in a given area. Since this scaling process is limited by the resolution of the lithography process which is used to produce the nano-particles, it is important to determine the influence of erroneous shape modifications on the magnetic properties, such as magnetization reversal processes and coercive fields. For this, a square nano-wire system from permalloy has been simulated using Magpar. In a former work, changes of the wire diameter have been shown to result in different magnetization reversal mechanisms and significantly altered coercive fields. In a new project, the intersections of the wires - which are most susceptible to undesired shape modifications - have been changed by adding or subtracting parts. Additionally, the wire intersections have been separated step by step, resulting in a qualitatively changed angular dependence of the coercive fields. Similar experiments have been performed for nano-squares with walls of rectangular cross-section. This study allows for estimation of the reliability of magnetic properties of nano-structures with respect to undesired shape modifications in the lithography process.

  20. Nb3Sn multifilamentary superconductors fabricated through a diffusion reaction between Nb and Ag-Sn alloys

    NASA Astrophysics Data System (ADS)

    Matsumoto, G.; Inoue, K.; Kikuchi, A.; Takeuchi, T.; Kiyoshi, T.

    2006-06-01

    Ag-Sn alloy is very attractive for fabricating Nb3Sn wires through diffusion reaction, because Ag-based alloy including a large amount of Sn is ductile. Therefore we investigated the Nb3Sn formation through the diffusion reaction between Nb and Ag-Sn alloys. With using Ag-9 at% Sn fcc phase, Ag-12 at% Sn ζ phase, and Ag-24at% Sn epsilon phase alloys, we fabricated single-core, 200-core, and 40000-core composite wires with Nb matrix and Ag-Sn alloy cores. With increase of Sn content in Ag-Sn alloys, the obtained superconducting properties of heat treated composite wires were improved. Tc and Bc2(4.2 K) for the Nb/Ag-Sn are similar to those for the Nb/Cu-Sn. However, the Ic values are relatively small, due to the formed very thin Nb3Sn layers. Ag is apparently not so effective to increase the formation rate of Nb3Sn layer as Cu. We obtained very interesting results by making the 200-core and 40000-core wires, which show the improved Tc and Bc2(4.2 K) by 0.5-1 K and 2-5 T, respectively. From 10 to 500 times larger Ic(4.2 K) were also obtained for the multifilamentary wires.

  1. Next Generation Wiring

    NASA Technical Reports Server (NTRS)

    Medelius, Petro; Jolley, Scott; Fitzpatrick, Lilliana; Vinje, Rubiela; Williams, Martha; Clayton, LaNetra; Roberson, Luke; Smith, Trent; Santiago-Maldonado, Edgardo

    2007-01-01

    Wiring is a major operational component on aerospace hardware that accounts for substantial weight and volumetric space. Over time wire insulation can age and fail, often leading to catastrophic events such as system failure or fire. The next generation of wiring must be reliable and sustainable over long periods of time. These features will be achieved by the development of a wire insulation capable of autonomous self-healing that mitigates failure before it reaches a catastrophic level. In order to develop a self-healing insulation material, three steps must occur. First, methods of bonding similar materials must be developed that are capable of being initiated autonomously. This process will lead to the development of a manual repair system for polyimide wire insulation. Second, ways to initiate these bonding methods that lead to materials that are similar to the primary insulation must be developed. Finally, steps one and two must be integrated to produce a material that has no residues from the process that degrades the insulating properties of the final repaired insulation. The self-healing technology, teamed with the ability to identify and locate damage, will greatly improve reliability and safety of electrical wiring of critical systems. This paper will address these topics, discuss the results of preliminary testing, and remaining development issues related to self-healing wire insulation.

  2. Effect of Ozone Treatment on Nano-Sized Silver Sulfide in Wastewater Effluent.

    PubMed

    Thalmann, Basilius; Voegelin, Andreas; von Gunten, Urs; Behra, Renata; Morgenroth, Eberhard; Kaegi, Ralf

    2015-09-15

    Silver nanoparticles used in consumer products are likely to be released into municipal wastewater. Transformation reactions, most importantly sulfidation, lead to the formation of nanoscale silver sulfide (nano-Ag2S) particles. In wastewater treatment plants (WWTP), ozonation can enhance the effluent quality by eliminating organic micropollutants. The effect of ozonation on the fate of nano-Ag2S, however, is currently unknown. In this study, we investigate the interaction of ozone with nano-Ag2S and evaluate the effect of ozonation on the short-term toxicity of WWTP effluent spiked with nano-Ag2S. The oxidation of nano-Ag2S by ozone resulted in a stoichiometric factor (number of moles of ozone required to oxidize one mole of sulfide to sulfate) of 2.91, which is comparable to the results obtained for the reaction of bisulfide (HS(-)) with ozone. The second-order rate constant for the reaction of nano-Ag2S with ozone (k = 3.1 × 10(4) M(-1) s(-1)) is comparable to the rate constant of fast-reacting micropollutants. Analysis of the ozonation products of nano-Ag2S by transmission electron microscopy (TEM) and X-ray absorption spectroscopy (XAS) revealed that ozonation dominantly led to the formation of silver chloride in WWTP effluent. After ozonation of the Ag2S-spiked effluent, the short-term toxicity for the green algae Chlamydomonas reinhardtii increased and reached EC50 values comparable to Ag(+). This study thus reveals that ozone treatment of WWTP effluent results in the oxidation of Ag2S and, hence, an increase of the Ag toxicity in the effluent, which may become relevant at elevated Ag concentrations. PMID:26270654

  3. Orbiter Kapton wire operational requirements and experience

    NASA Technical Reports Server (NTRS)

    Peterson, R. V.

    1994-01-01

    The agenda of this presentation includes the Orbiter wire selection requirements, the Orbiter wire usage, fabrication and test requirements, typical wiring installations, Kapton wire experience, NASA Kapton wire testing, summary, and backup data.

  4. AGS II

    SciTech Connect

    Palmer, R.B.

    1984-01-01

    Interest in rare K decays, neutrino oscillations and other fields have generated an increasing demand for running, and improved intensity and duty cycle, at the AGS. Current projects include acceleration of polarized protons and light ions (up to mass 32). Future plans are for a booster to increase intensity and allow heavy ions (up to mass 200), and a stretcher to give 100% duty cycle. A later upgrade could yield an average current of 32 ..mu.. amps. 6 figures, 2 tables.

  5. Composite ceramic superconducting wires for electric motor applications

    NASA Astrophysics Data System (ADS)

    Halloran, John W.

    1990-07-01

    Several types of HTSC wire have been produced and two types of HTSC motors are being built. Hundreds of meters of Ag- clad wire were fabricated from YBa2Cu3O(7-x) (Y-123) and Bi2Ca2Sr2Cu3O10 (BiSCCO). The dc homopolar motor coils are not yet completed, but multiple turns of wire have been wound on the coil bobbins to characterize the superconducting properties of coiled wire. Multifilamentary conductors were fabricated as cables and coils. The sintered polycrystalline wire has self-field critical current densities (Jc) as high as 2800 A/sq cm, but the Jc falls rapidly with magnetic field. To improve Jc, sintered YBCO wire is melt textured with a continuous process which has produced textures wire up to 0.5 meters long with 77K transport Jc above 11, 770 A/sq cm2 in self field and 2100 A/sq cm2 at 1 telsa. The Emerson Electric dc homopolar HTSC motor has been fabricated and run with conventional copper coils. A novel class of potential very powerful superconducting motors have been designed to use trapped flux in melt textures Y-123 as magnet replicas in an new type of permanent magnet motor. The stator element and part of the rotor of the first prototype machine exist, and the HTSC magnet replica segments are being fabricated.

  6. Effects of Nano Silver Oxide and Silver Ions on Growth of Vigna radiata.

    PubMed

    Singh, Divya; Kumar, Arun

    2015-09-01

    Transformation of silver oxide nanoparticles (nano-Ag2O) to silver nanoparticles (nano-Ag) and silver ions in environment is possible which might pose toxicity to plants and other species. The objective of this study was to study effects of nano-Ag2O and silver ions on growth of Mung bean (Vigna radiata) seedlings. V. radiata seeds were exposed to nano-Ag2O and silver ions (concentration range: 4.3 × 10(-7), 4.3 × 10(-6), 4.3 × 10(-5), 4.3 × 10(-4), and 4.3 × 10(-3) mol/L) for 6 days. Root length, shoot length and dry weight of seedlings were found to decrease due to exposure of nano-Ag2O and silver ions. These findings indicate silver ions to be more toxic to V. radiata seeds than nano-Ag2O. Silver content in seedlings was found to increase with increasing concentrations of nano-Ag2O and silver ions. Overall, findings of the present study add to the existing knowledge of phytotoxicity of silver-based nanoparticles of different chemical compositions to V. radiata seeds and need to be considered during use of nanoparticles-contaminated water for irrigation purposes. PMID:26155963

  7. Photochemical synthesis of Ag nanobars and their potential application as catalyst

    NASA Astrophysics Data System (ADS)

    Pyne, Santanu; Samanta, Sadhan; Misra, Ajay

    2013-12-01

    Monodispersed sodium alginate (SA) stabilized silver nano bar and hydroxyl propyl methyl cellulose (HPMC) stabilized silver nano bar have been synthesized by photochemical method. The nanoparticles are characterized by UV-VIS-NIR spectroscopy, transmission electron microscopy (TEM) and selected area electron diffraction (SAED) study. Catalytic reduction of 4-nitrophenol (4-NP) by sodium borohydride in presence of nanoparticles is also evaluated. The kinetic data obtained by monitoring the change in UV-Vis absorption spectra of 4-NP are explained by Langmuir-Hinshelwood model. It is observed that the rate of reduction is higher in SA stabilized Ag nano bar than the HPMC stabilized Ag nano bar.

  8. Fabrication of high-performance (Ba,K)Fe2As2 superconducting wires by powder-in-tube method

    NASA Astrophysics Data System (ADS)

    Ding, Q. P.; Prombood, T.; Mohan, S.; Y. Tsuchiya; Nakajima, Y.; Tamegai, T.

    (Ba,K)Fe2As2 superconducting wires have been fabricated by ex-situ powder-in-tube method. In addition to the pure (Ba,K)Fe2As2 wires, silver powder was also used as a chemical addition to improve the performance of these superconducting wires. The transport critical current density (Jc) has reached 1.3×104 A/cm2 at 4.2 K under self field in the wire with Ag addition. The self-field Jc is the highest among all the reported Fe-based superconducting wires so far. We have also performed magneto-optical imaging to this (Ba,K)Fe2As2 superconducting wire with Ag addition, and intragranular Jc of 6.0×104 A/cm2 at 20 K is obtained, which is similar to the estimation from M-H measurement.

  9. Dual wire weld feed proportioner

    NASA Technical Reports Server (NTRS)

    Nugent, R. E.

    1968-01-01

    Dual feed mechanism enables proportioning of two different weld feed wires during automated TIG welding to produce a weld alloy deposit of the desired composition. The wires are fed into the weld simultaneously. The relative feed rates of the wires and the wire diameters determine the weld deposit composition.

  10. Splicing Wires Permanently With Explosives

    NASA Technical Reports Server (NTRS)

    Bement, Laurence J.; Kushnick, Anne C.

    1990-01-01

    Explosive joining process developed to splice wires by enclosing and metallurgically bonding wires within copper sheets. Joints exhibit many desirable characteristics, 100-percent conductivity and strength, no heat-induced annealing, no susceptibility to corrosion in contacts between dissimilar metals, and stability at high temperature. Used to join wires to terminals, as well as to splice wires. Applicable to telecommunications industry, in which millions of small wires spliced annually.

  11. Wafer-scale aluminum nano-plasmonics

    NASA Astrophysics Data System (ADS)

    George, Matthew C.; Nielson, Stew; Petrova, Rumyana; Frasier, James; Gardner, Eric

    2014-09-01

    The design, characterization, and optical modeling of aluminum nano-hole arrays are discussed for potential applications in surface plasmon resonance (SPR) sensing, surface-enhanced Raman scattering (SERS), and surface-enhanced fluorescence spectroscopy (SEFS). In addition, recently-commercialized work on narrow-band, cloaked wire grid polarizers composed of nano-stacked metal and dielectric layers patterned over 200 mm diameter wafers for projection display applications is reviewed. The stacked sub-wavelength nanowire grid results in a narrow-band reduction in reflectance by 1-2 orders of magnitude, which can be tuned throughout the visible spectrum for stray light control.

  12. Low-cost spray-processed Ag{sub 1−x}Cu{sub x}InS{sub 2} nano-films: Structural and functional investigation within the Lattice Compatibility Theory framework

    SciTech Connect

    Gherouel, D.; Yumak, A.; Znaidi, M.; Bouzidi, A.; Boubaker, K.; Yacoubi, N.; Amlouk, M.

    2015-08-15

    Highlights: • Cu{sub x}Ag{sub 1−x}InS{sub 2} with a minimal lattice mismatch between absorbers and buffers. • The lattice compatibility for understanding silver–copper kinetics. • Controlled and enhanced spray pyrolisis method as a low-cost synthesis protocol. - Abstract: This work deals with some structural and optical investigations about Cu{sub x}Ag{sub 1−x}InS{sub 2} alloys sprayed films and the beneficial effect of copper incorporation in AgInS{sub 2} ternary matrices. The main purpose of this work is to obtain the band gap energy E{sub g} as well as different lattice parameters. The studied properties led to reaching minimum of lattice mismatch between absorber and buffer layers within solar cell devices. As a principal and original finding, the lattice compatibility between both silver and copper indium disulfide structures has been proposed as a guide for understanding kinetics of these materials crystallization.

  13. Embrittlement phenomenon of Ag core MP35N cable as lead conductor in medical device.

    PubMed

    Wang, Ling; Li, Bernie; Zhang, Haitao

    2013-02-01

    Ag core MP35N (Ag/MP35N) wire has been used in lead electric conductor wires in the medical device industry for many years. Recently it was noticed that the combination of silver and MP35N restricts its wire drawing process. The annealing temperature in Ag/MP35N has to be lower than the melting temperature of pure Ag (960 °C), which cannot fully anneal MP35N. The lower annealing temperature results in a highly cold worked MP35N, which significantly reduces Ag/MP35N ductility. The embrittlement phenomenon of Ag/MP35N cable was observed in tension and bending deformation. The effect of the embrittlement on the wire flex fatigue life was evaluated using a newly developed flex fatigue testing method. The Ag/MP35N cable fatigue results was analyzed with a Coffin-Manson approach and compared to the MP35N cable fatigue results. The root causes of the Ag/Mp35N embrittlement phenomenon are discussed. PMID:23231759

  14. Wire brush fastening device

    SciTech Connect

    Meigs, R.A.

    1993-08-31

    A fastening device is provided which is a variation on the conventional nut and bolt. The bolt has a longitudinal axis and threading helically affixed thereon along the longitudinal axis. A nut having a bore extending therethrough is provided. The bore of the nut has a greater diameter than the diameter of the bolt so the bolt can extend through the bore. An array of wire bristles are affixed within the bore so as to form a brush. The wire bristles extend inwardly from the bore and are constructed and arranged of the correct size, length and stiffness to guide the bolt within the bore and to restrain the bolt within the bore as required. A variety of applications of the wire brush nut are disclosed, including a bolt capture device and a test rig apparatus.

  15. Wire brush fastening device

    DOEpatents

    Meigs, Richard A.

    1995-01-01

    A fastening device is provided which is a variation on the conventional nut and bolt. The bolt has a longitudinal axis and threading helically affixed thereon along the longitudinal axis. A nut having a bore extending therethrough is provided. The bore of the nut has a greater diameter than the diameter of the bolt so the bolt can extend through the bore. An array of wire bristles are affixed within the bore so as to form a brush. The wire bristles extend inwardly from the bore and are constructed and arranged of the correct size, length and stiffness to guide the bolt within the bore and to restrain the bolt within the bore as required. A variety of applications of the wire brush nut are disclosed, including a bolt capture device and a test rig apparatus.

  16. Wire brush fastening device

    DOEpatents

    Meigs, R.A.

    1995-09-19

    A fastening device is provided which is a variation on the conventional nut and bolt. The bolt has a longitudinal axis and threading helically affixed thereon along the longitudinal axis. A nut having a bore extending therethrough is provided. The bore of the nut has a greater diameter than the diameter of the bolt so the bolt can extend through the bore. An array of wire bristles are affixed within the bore so as to form a brush. The wire bristles extend inwardly from the bore and are constructed and arranged of the correct size, length and stiffness to guide the bolt within the bore and to restrain the bolt within the bore as required. A variety of applications of the wire brush nut are disclosed, including a bolt capture device and a test rig apparatus. 13 figs.

  17. Dielectric coated wire antennas

    NASA Technical Reports Server (NTRS)

    Richmond, J. H.; Newman, E. H.

    1976-01-01

    An electrically thin dielectric insulating shell on an antenna composed of electrically thin circular cylindrical wires is examined. A moment method solution is obtained, and the insulating shell is modeled by equivalent volume polarization currents. These polarization currents are related in a simple manner to the surface charge density on the wire antenna. In this way the insulating shell causes no new unknowns to be introduced, and the size of the impedance matrix is the same as for the uninsulated wires. The insulation is accounted for entirely through a modification of the symmetric impedance matrix. This modification influences the current distribution, impedance, efficiency, field patterns, and scattering properties. The theory is compared with measurement for dielectric coated antennas in air.

  18. 2. TYPICAL OVERHEAD WIRE CONSTRUCTION CURVE GUY WIRE ARRANGEMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. TYPICAL OVERHEAD WIRE CONSTRUCTION - CURVE GUY WIRE ARRANGEMENT (ABANDONED WEST LEG OF WYE AT SIXTH AVENUE AND PINE STREET) - Yakima Valley Transportation Company Interurban Railroad, Trackage, Yakima, Yakima County, WA

  19. Flying wires at Fermilab

    SciTech Connect

    Gannon, J.; Crawford, C.; Finley, D.; Flora, R.; Groves, T.; MacPherson, M.

    1989-03-01

    Transverse beam profile measurement systems called ''Flying Wires'' have been installed and made operational in the Fermilab Main Ring and Tevatron accelerators. These devices are used routinely to measure the emittance of both protons and antiprotons throughout the fill process, and for emittance growth measurements during stores. In the Tevatron, the individual transverse profiles of six proton and six antiproton bunches are obtained simultaneously, with a single pass of the wire through the beam. Essential features of the hardware, software, and system operation are explained in the rest of the paper. 3 refs., 4 figs.

  20. Wiring for space applications program

    NASA Technical Reports Server (NTRS)

    Hammoud, Ahmad

    1994-01-01

    The insulation testing and analysis consists of: identifying and prioritizing NASA wiring requirements; selecting candidate wiring constructions; developing test matrix and formulating test program; managing, coordinating, and conducting tests; and analyzing and documenting data, establishing guidelines and recommendations.

  1. NewsWire, 2002.

    ERIC Educational Resources Information Center

    Byrom, Elizabeth, Ed.; Bingham, Margaret, Ed.; Bowman, Gloria, Ed.; Shoemaker, Dan, Ed.

    2002-01-01

    This document presents the 3 2002 issues of the newsletter "NewsWire," (volume 5). Issue Number One focuses on collaborative Web projects. This issue begins with descriptions of four individual projects: "iEARN"; "Operation RubyThroat"; "Follow the Polar Huskies!"; and "Log in Your Animal Roadkill!" Features that follow include: "Bringing the…

  2. Basic Wiring. Second Edition.

    ERIC Educational Resources Information Center

    Kaltwasser, Stan; And Others

    This guide is designed to assist teachers conducting a foundation course to prepare students for additional courses of training for entry-level employment in either the residential or commercial and industrial wiring trades. Included in the guide are 17 instructional units and the following sections of information for teachers: guidelines in using…

  3. Improved wire chamber

    DOEpatents

    Atac, M.

    1987-05-12

    An improved gas mixture for use with proportional counter devices, such as Geiger-Mueller tubes and drift chambers. The improved gas mixture provides a stable drift velocity while eliminating wire aging caused by prior art gas mixtures. The new gas mixture is comprised of equal parts argon and ethane gas and having approximately 0.25% isopropyl alcohol vapor. 2 figs.

  4. Caroviologens: Towards molecular wires

    NASA Astrophysics Data System (ADS)

    Blanchard-Desce, M.; Arrhenius, T. S.; Dvolaïtzky, M.; Kugimiya, S.-I.; Lazrak, T.; Lehn, J.-M.

    1992-07-01

    Bispyridinium conjugated polyenes of different lengths and charges have been synthesized. Since they combine the features of carotenoids and of viologens, they have been termed caroviologens. Such molecules, possessing an extended conjugated chain fitted with polar electroactive endgroups, and having a length sufficient to span a lipid membrane could function as transmembrane electron channels, i.e., as molecular wires.

  5. A World without Wires

    ERIC Educational Resources Information Center

    Panettieri, Joseph C.

    2006-01-01

    The wireless bandwagon is rolling across Mississippi, picking up a fresh load of converts and turning calamity into opportunity. Traditional wired school networks, many of which unraveled during Hurricane Katrina, are giving way to advanced wireless mesh networks that frequently include voice-over-IP (VoIP) capabilities. Vendor funding is helping…

  6. Residential Wiring. Second Edition.

    ERIC Educational Resources Information Center

    Taylor, Mark; And Others

    This guide is designed to assist teachers conducting a course to prepare students for entry-level employment in the residential wiring trade. Included in the guide are six instructional units and the following sections of information for teachers: guidelines in using the unit components; academic and workplace skills classifications and…

  7. Formation of nanodots and enhancement of thermoelectric power induced by ion irradiation in PbTe:Ag composite thin films

    NASA Astrophysics Data System (ADS)

    Bala, Manju; Meena, Ramcharan; Gupta, Srashti; Pannu, Compesh; Tripathi, Tripurari S.; Varma, Shikha; Tripathi, Surya K.; Asokan, K.; Avasthi, Devesh K.

    2016-07-01

    Present study demonstrates an enhancement in thermoelectric power of 10% Ag doped PbTe (PbTe:Ag) thin films when irradiated with 200 keV Ar ion. X-ray diffraction showed an increase in crystallinity for both PbTe and PbTe:10Ag nano-composite films after Ar ion irradiation due to annealing of defects in the grain boundaries. The preferential sputtering of Pb and Te ions in comparison to Ag ions resulted in the formation of nano-dots. This was further confirmed by X-ray photoelectron spectroscopy (XPS). Such an enhancement in thermoelectric power of irradiated PbTe:10Ag films in comparison to pristine PbTe:10Ag film is attributed to the decrease in charge carrier concentration that takes part in the transport process via restricting the tunneling of carriers through the wider potential barrier formed at the interface of nano-dots.

  8. Easily-wired toggle switch

    NASA Technical Reports Server (NTRS)

    Dean, W. T.; Stringer, E. J.

    1979-01-01

    Crimp-type connectors reduce assembly and disassembly time. With design, no switch preparation is necessary and socket contracts are crimped to wires inserted in module attached to back of toggle switch engaging pins inside module to make electrical connections. Wires are easily removed with standard detachment tool. Design can accommodate wires of any gage and as many terminals can be placed on switch as wire gage and switch dimensions will allow.

  9. Wire EDM for Refractory Materials

    NASA Technical Reports Server (NTRS)

    Zellars, G. R.; Harris, F. E.; Lowell, C. E.; Pollman, W. M.; Rys, V. J.; Wills, R. J.

    1982-01-01

    In an attempt to reduce fabrication time and costs, Wire Electrical Discharge Machine (Wire EDM) method was investigated as tool for fabricating matched blade roots and disk slots. Eight high-strength nickel-base superalloys were used. Computer-controlled Wire EDM technique provided high quality surfaces with excellent dimensional tolerances. Wire EDM method offers potential for substantial reductions in fabrication costs for "hard to machine" alloys and electrically conductive materials in specific high-precision applications.

  10. Note: Buoyant-force assisted liquid membrane electrochemical etching for nano-tip preparation.

    PubMed

    Zeng, Yongbin; Wang, Yufeng; Wu, Xiujuan; Xu, Kun; Qu, Ningsong

    2014-12-01

    A liquid membrane electrochemical etching process for preparing nano-tips is proposed by the introduction of buoyant force to the lower tip, in which the lower portion of the anodic wire is immersed into a floating layer. A mathematical model of this method is derived. Both calculation and experimental results demonstrate that the introduction of buoyant force can significantly decrease the tip radius. The lubricating oil and deionized water floating layers were tested for the processing of nano-tips. Further, high-aspect-ratio nano-electrodes were prepared by applying a relative vertical movement to the anodic wire. PMID:25554341

  11. Propagating and localized surface plasmons in Ag nanostructures

    NASA Astrophysics Data System (ADS)

    Dabrowski, Maciej; Dai, Yanan; Petek, Hrvoje

    Plasmonic excitations strongly depend on the size, geometry and dielectric environment of nanoscale metals. Here, we study an epitaxially grown Ag nanostructures on Si(001) and Si(111) surfaces by Low Energy Electron Microscopy/Photoemission Electron Microscopy (LEEM/PEEM). Using the combination of LEEM and broadly tunable femtosecond laser excited multiphoton PEEM we image how single crystalline metallic nanostructures form and how plasmon excitations depend on the particle structure and laser excitation parameters. For Ag pyramids with the dimensions of few hundreds nanometers, dipolar and quadrupolar localized surface plasmons are observed. For Ag wires with several micrometer lengths, both localized and propagating surface plasmons can be excited, depending on the polarization, particle orientation and energy of the excitation. Finally, in larger Ag islands, several micrometers in size, the interference patterns are created by plasmon waves excited at the island edges. In addition to plasmonic response, light diffraction patterns around the Ag nanostrutures are discussed.

  12. Effects of alkali treatments on Ag nanowire transparent conductive films

    NASA Astrophysics Data System (ADS)

    Kim, Sunho; Kang, Jun-gu; Eom, Tae-yil; Moon, Bongjin; Lee, Hoo-Jeong

    2016-06-01

    In this study, we employ various alkali materials (alkali metals with different base strengths, and ammonia gas and solution) to improve the conductivity of silver nanowire (Ag NW)-networked films. The alkali treatment appears to remove the surface oxide and improve the conductivity. When applied with TiO2 nanoparticles, the treatment appears more effective as the alkalis gather around wire junctions and help them weld to each other via heat emitted from the reduction reaction. The ammonia solution treatment is found to be quick and aggressive, damaging the wires severely in the case of excessive treatment. On the other hand, the ammonia gas treatment seems much less aggressive and does not damage the wires even after a long exposure. The results of this study highlight the effectiveness of the alkali treatment in improving of the conductivity of Ag NW-networked transparent conductive films.

  13. 1997 wire development workshop: Proceedings

    SciTech Connect

    1997-04-01

    This conference is divided into the following sections: (1) First Generation Wires I; (2) First Generation Wires II; (3) Coated conductors I; and (4) Coated conductors II. Applications of the superconducting wires include fault current limiters, superconducting motors, transformers, and power transmission lines.

  14. Production of hot-wires

    NASA Astrophysics Data System (ADS)

    Dickinson, S. C.

    1983-04-01

    Several methods for producing hot-wire probes are described. Discussion includes the manufacture of probe bodies, soldering plated wires to the prongs etching Walaston type wires, and finishing the probe. This report is written as an instruction manual for researchers who desire to produce or repair their own sensors.

  15. Magnetism of ultrathin wires suspended in free space and adsorbed on vicinal surfaces

    NASA Astrophysics Data System (ADS)

    Spišák, D.; Hafner, J.

    2003-06-01

    On the basis of total-energy calculations within density functional theory the possibility of magnetic ordering in ultrathin, one or two atom wide nanowires is studied. Specifically, we investigate nanowires composed of fifth and sixth row elements, which are nonmagnetic in the solid phase. At first, the unsupported straight wires are discussed and then, similar to experimental conditions, the wires are placed along step ledges of vicinal surfaces of copper and silver. Free-standing wires show only a weak tendency towards magnetic ordering at the equilibrium bond length. In analogy with their 3d homologues Mo, Tc, W, Re are found to order antiferromagnetically, Ru, Rh, and Ir ferromagnetically. Surprisingly, ferromagnetism is also predicted for the early transition metals Zr and Ta and for the simple metals In and Tl. This picture is profoundly modified for supported wires, where the expansion of the bond length enforced through the epitaxial relationship with the substrate favors magnetic ordering but hybridization with the substrate electrons tends to quench magnetism. It turns out that wires on a Cu substrate prefer a ferromagnetic order, whereas on a Ag substrate most elements tend to antiferromagnetism. A second row of atoms added to the wires destroys the magnetism in wires on a Cu substrate, and reduces it in wires on a Ag substrate, except for the late transition metals (Rh, Ir) where an enhancement of magnetic moments is observed. Two possible growth modes of nanowires — a row-by-row growth and island growth — are explored. The results allow us to suggest that Ru, Rh, and Os wires on Ag stepped surfaces are the most promising systems in which magnetism could be verified experimentally.

  16. Searching for efficient X-ray radiators for wire array Z-pinch plasmas using mid-atomic-number single planar wire arrays on Zebra at UNR

    NASA Astrophysics Data System (ADS)

    Safronova, A. S.; Esaulov, A. A.; Kantsyrev, V. L.; Ouart, N. D.; Shlyaptseva, V.; Weller, M. E.; Keim, S. F.; Williamson, K. M.; Shrestha, I.; Osborne, G. C.

    2011-12-01

    We continue to search for more efficient X-ray radiators from wire array Z-pinch plasmas. The results of recent experiments with single planar wire array (SPWA) loads made from mid-atomic-number material wires such as Alumel, Cu, Mo, and Ag are presented and compared. In particular, two new efficient X-ray radiators, Alumel (95% Ni, 2% Al, and 2% Si) and Ag, are introduced, and their radiative properties are discussed in detail. The experiments were performed on the 1 MA Zebra generator at UNR. The X-ray yields from such mid-atomic-number SPWAs exceed twice those from low-atomic-number SPWAs, such as Al, and increase with the atomic number to reach more than 27-29 kJ for Ag. To consider the main contributions to the total radiation, we divided the time interval of the Z-pinch dynamic where wire ablation and implosion, stagnation, and plasma expansion occur in corresponding phases and studied the radiative and implosion characteristics within them. Theoretical tools such as non-LTE kinetics and wire ablation dynamic models were applied in the data analysis. These results and the models developed have much broader applications, not only for SPWAs on Zebra, but for other HED plasmas with mid-atomic-number ions.

  17. Preparation, characterization, and photocatalytic activity of porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts

    NASA Astrophysics Data System (ADS)

    Yang, Fan; Tian, Baozhu; Zhang, Jinlong; Xiong, Tianqing; Wang, Tingting

    2014-02-01

    Porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts were synthesized by a multistep route, including a dealloying method to prepare porous Ag, a transformation from Ag to AgBr and AgBrI, and a photo-reduction process to form Ag nanoparticles on the surface of AgBr and AgBrI. It was found that the porous structure kept unchanged during Ag was transferred into AgBr, AgBrI, AgBr@Ag, and AgBrI@Ag. Both porous AgBr@Ag and porous AgBrI@Ag showed much higher visible-light photocatalytic activity than cubic AgBr@Ag for the degradation of methyl orange, which is because the interconnected pore channels not only provide more reactive sites but also favor the transportation of photo-generated electrons and holes. For AgBrI@Ag, AgBrI solid solution formed at the interface of AgBr and AgI, and the phase junction can effectively separate the photo-generated electrons and holes, favorable to the improvement of photocatalytic activity. The optimal I content for obtaining the highest activity is ∼10 at.%.

  18. Growth of low temperature silicon nano-structures for electronic and electrical energy generation applications

    PubMed Central

    2013-01-01

    This paper represents the lowest growth temperature for silicon nano-wires (SiNWs) via a vapour-liquid–solid method, which has ever been reported in the literature. The nano-wires were grown using plasma-enhanced chemical vapour deposition technique at temperatures as low as 150°C using gallium as the catalyst. This study investigates the structure and the size of the grown silicon nano-structure as functions of growth temperature and catalyst layer thickness. Moreover, the choice of the growth temperature determines the thickness of the catalyst layer to be used. The electrical and optical characteristics of the nano-wires were tested by incorporating them in photovoltaic solar cells, two terminal bistable memory devices and Schottky diode. With further optimisation of the growth parameters, SiNWs, grown by our method, have promising future for incorporation into high performance electronic and optical devices. PMID:23413969

  19. An innovative method for joining materials at low temperature using silver (nano)particles derived from [AgO2C(CH2OCH2)3H

    NASA Astrophysics Data System (ADS)

    Oestreicher, Annerose; Röhrich, Tobias; Wilden, Johannes; Lerch, Martin; Jakob, Alexander; Lang, Heinrich

    2013-01-01

    A novel method for the manufacture of compact sintered silver layers as joining materials at low temperatures without applying pressure is described. The metal-organic silver complex [AgO2C(CH2OCH2)3H] (3) is used, which generates silver nanoparticles with heat treatment below 200 °C. Complex (3) provides the features for the formation of a molten metal-like silver phase in which silver particles in the nanometer and submicron size range, respectively, are completely miscible. Within this study, copper specimens were bonded, and the joints were evaluated by cross-sectional scanning electron microscope (SEM) images. Moreover, this approach enables the incorporation of copper. An example is given with an average amount of 20 at.% copper content in the silver layer.

  20. Pulsed Laser Deposition and Reflection High-Energy Electron Diffraction studies of epitaxial long range order, nano- and microstructured Ag thin films grown on MgO, Al2 O3 , STO and Si

    NASA Astrophysics Data System (ADS)

    Velazquez, Daniel; Seibert, Rachel; Man, Hamdi; Spentzouris, Linda; Terry, Jeff

    2015-03-01

    Pulsed Laser Deposition is a state-of-the-art technique that allows for the fine tunability of the deposition rate, highly uniform and epitaxial sample growth, the ability to introduce partial pressures of gases into the experimental chamber for growth of complex materials without interfering with the energy source (laser). An auxiliary in situ technique for growth monitoring, Reflection High-Energy Electron Diffraction, is a powerful characterization tool for predictability of the surface physical structure both, qualitatively and quantitatively. RHEED patterns during and post deposition of Ag thin films on MgO, Al2O3, Si and STO substrtates are presented and their interpretations are compared with surface imaging techniques (SEM, STM) to evidence the usefulness of the technique.

  1. π-Conjugated bis(terpyridine)metal complex molecular wires.

    PubMed

    Sakamoto, Ryota; Wu, Kuo-Hui; Matsuoka, Ryota; Maeda, Hiroaki; Nishihara, Hiroshi

    2015-11-01

    Bottom-up approaches have gained significant attention recently for the creation of nano-sized, ordered functional structures and materials. Stepwise coordination techniques, in which ligand molecules and metal sources are reacted alternatively, offer several advantages. Coordination bonds are stable, reversible, and self-assembling, and the resultant metal complex motifs may contain functionalities unique to their own characteristics. This review focuses on metal complex wire systems, specifically the bottom-up fabrication of linear and branched bis(terpyridine)metal complex wires on electrode surfaces. This system possesses distinct and characteristic electronic functionalities, intra-wire redox conduction and excellent long-range electron transport ability. This series of comprehensive studies exploited the customizability of bis(terpyridine)metal complex wires, including examining the influence of building blocks. In addition, simple yet effective electron transfer models were established for redox conduction and long-range electron transport. A fabrication technique for an ultra-long bis(terpyridine)metal complex wire is also described, along with its properties and functionalities. PMID:25864838

  2. From wires to cosmology

    NASA Astrophysics Data System (ADS)

    Amin, Mustafa A.; Baumann, Daniel

    2016-02-01

    We provide a statistical framework for characterizing stochastic particle production in the early universe via a precise correspondence to current conduction in wires with impurities. Our approach is particularly useful when the microphysics is uncertain and the dynamics are complex, but only coarse-grained information is of interest. We study scenarios with multiple interacting fields and derive the evolution of the particle occupation numbers from a Fokker-Planck equation. At late times, the typical occupation numbers grow exponentially which is the analog of Anderson localization for disordered wires. Some statistical features of the occupation numbers show hints of universality in the limit of a large number of interactions and/or a large number of fields. For test cases, excellent agreement is found between our analytic results and numerical simulations.

  3. Dental Arch Wire

    NASA Technical Reports Server (NTRS)

    1979-01-01

    Straightening teeth is an arduous process requiring months, often years, of applying corrective pressure by means of arch wires-better known as brace-which may have to be changed several times in the course of treatment. A new method has been developed by Dr. George Andreasen, orthodontist and dental scientist at the University of Iowa. The key is a new type of arch wire material, called Nitinol, with exceptional elasticity which helps reduce the required number of brace changes. An alloy of nickel and titanium, Nitinol was originally developed for aerospace applications by the Naval Ordnance Laboratory, now the Naval Surface Weapons Laboratory, White Oaks, Maryland. NASA subsequently conducted additional research on the properties of Nitinol and on procedures for processing the metal.

  4. Wire insulation defect detector

    NASA Technical Reports Server (NTRS)

    Greulich, Owen R. (Inventor)

    2004-01-01

    Wiring defects are located by detecting a reflected signal that is developed when an arc occurs through the defect to a nearby ground. The time between the generation of the signal and the return of the reflected signal provides an indication of the distance of the arc (and therefore the defect) from the signal source. To ensure arcing, a signal is repeated at gradually increasing voltages while the wire being tested and a nearby ground are immersed in a conductive medium. In order to ensure that the arcing occurs at an identifiable time, the signal whose reflection is to be detected is always made to reach the highest potential yet seen by the system.

  5. Wiring for aerospace applications

    NASA Technical Reports Server (NTRS)

    Christian, J. L., Jr.; Dickman, J. E.; Bercaw, R. W.; Myers, I. T.; Hammoud, A. N.; Stavnes, M.; Evans, J.

    1992-01-01

    In this paper, the authors summarize the current state of knowledge of arc propagation in aerospace power wiring and efforts by the National Aeronautics and Space Administration (NASA) towards the understanding of the arc tracking phenomena in space environments. Recommendations will be made for additional testing. A database of the performance of commonly used insulating materials will be developed to support the design of advanced high power missions, such as Space Station Freedom and Lunar/Mars Exploration.

  6. Plated wire memory subsystem

    NASA Technical Reports Server (NTRS)

    Reynolds, L.; Tweed, H.

    1972-01-01

    The work performed entailed the design, development, construction and testing of a 4000 word by 18 bit random access, NDRO plated wire memory for use in conjunction with a spacecraft imput/output unit and central processing unit. The primary design parameters, in order of importance, were high reliability, low power, volume and weight. A single memory unit, referred to as a qualification model, was delivered.

  7. Exposure Medium: Key in Identifying Free Ag+ as the Exclusive Species of Silver Nanoparticles with Acute Toxicity to Daphnia magna

    PubMed Central

    Shen, Mo-Hai; Zhou, Xiao-Xia; Yang, Xiao-Ya; Chao, Jing-Bo; Liu, Rui; Liu, Jing-Fu

    2015-01-01

    It is still not very clear what roles the various Ag species play in the toxicity of silver nanoparticles (AgNPs). In this study, we found that traditional exposure media result in uncontrollable but consistent physicochemical transformation of AgNPs, causing artifacts in determination of median lethal concentration (LC50) and hindering the identification of Ag species responsible for the acute toxicity of AgNPs to Daphnia magna. This obstacle was overcome by using 8 h exposure in 0.1 mmol L−1 NaNO3 medium, in which we measured the 8-h LC50 of seven AgNPs with different sizes and coatings, and determined the concentrations of various Ag species. The LC50 as free Ag+ of the seven AgNPs (0.37–0.44 μg L−1) agreed very well with that of AgNO3 (0.40 μg L−1), and showed the lowest value compared to that as total Ag, total Ag+, and dissolved Ag, demonstrating free Ag+ is exclusively responsible for the acute toxicity of AgNPs to D. magna, while other Ag species in AgNPs have no contribution to the acute toxicity. Our results demonstrated the great importance of developing appropriate exposure media for evaluating risk of nanomaterials. PMID:25858866

  8. Exposure Medium: Key in Identifying Free Ag+ as the Exclusive Species of Silver Nanoparticles with Acute Toxicity to Daphnia magna

    NASA Astrophysics Data System (ADS)

    Shen, Mo-Hai; Zhou, Xiao-Xia; Yang, Xiao-Ya; Chao, Jing-Bo; Liu, Rui; Liu, Jing-Fu

    2015-04-01

    It is still not very clear what roles the various Ag species play in the toxicity of silver nanoparticles (AgNPs). In this study, we found that traditional exposure media result in uncontrollable but consistent physicochemical transformation of AgNPs, causing artifacts in determination of median lethal concentration (LC50) and hindering the identification of Ag species responsible for the acute toxicity of AgNPs to Daphnia magna. This obstacle was overcome by using 8 h exposure in 0.1 mmol L-1 NaNO3 medium, in which we measured the 8-h LC50 of seven AgNPs with different sizes and coatings, and determined the concentrations of various Ag species. The LC50 as free Ag+ of the seven AgNPs (0.37-0.44 μg L-1) agreed very well with that of AgNO3 (0.40 μg L-1), and showed the lowest value compared to that as total Ag, total Ag+, and dissolved Ag, demonstrating free Ag+ is exclusively responsible for the acute toxicity of AgNPs to D. magna, while other Ag species in AgNPs have no contribution to the acute toxicity. Our results demonstrated the great importance of developing appropriate exposure media for evaluating risk of nanomaterials.

  9. Near-surface and bulk behavior of Ag in SiC

    SciTech Connect

    Xiao, Haiyan; Zhang, Yanwen; Snead, Lance Lewis; Shutthanandan, Vaithiyalingam; Xue, Haizhou; Weber, William J

    2012-01-01

    The diffusive release of fission products, such as Ag, from TRISO particles at high temperatures has raised concerns regarding safe and economic operation of advanced nuclear reactors. Understanding the mechanisms of Ag diffusion is thus of crucial importance for effective retention of fission products. Two mechanisms, i.e., grain boundary diffusion and vapor or surface diffusion through macroscopic structures such as nano-pores or nano-cracks, remain in debate. In the present work, an integrated computational and experimental study of the near-surface and bulk behavior of Ag in silicon carbide (SiC) has been carried out. The ab initio calculations show that Ag prefers to adsorb on the SiC surface rather than in the bulk, and the mobility of Ag on the surface is high. The energy barrier for Ag desorption from the surface is calculated to be 0.85-1.68 eV, and Ag migration into bulk SiC through equilibrium diffusion process is not favorable. Experimentally, Ag ions are implanted into SiC to produce Ag profiles buried in the bulk and peaked at the surface. High-temperature annealing leads to Ag release from the surface region instead of diffusion into the interior of SiC. It is suggested that surface diffusion through mechanical structural imperfection, such as vapor transport through cracks in SiC coatings, may be a dominating mechanism accounting for Ag release from the SiC in the nuclear reactor.

  10. Fate of Ag-NPs in Sewage Sludge after Application on Agricultural Soils.

    PubMed

    Pradas del Real, Ana E; Castillo-Michel, Hiram; Kaegi, Ralf; Sinnet, Brian; Magnin, Valérie; Findling, Nathaniel; Villanova, Julie; Carrière, Marie; Santaella, Catherine; Fernández-Martínez, Alejandro; Levard, Clément; Sarret, Géraldine

    2016-02-16

    The objective of this work was to investigate the fate of silver nanoparticles (Ag-NPs) in a sludge-amended soil cultivated with monocot (Wheat) and dicot (Rape) crop species. A pot experiment was performed with sludges produced in a pilot wastewater treatment plant containing realistic Ag concentrations (18 and 400 mg kg(-1), 14 mg kg(-1) for the control). Investigations focused on the highest dose treatment. X-ray absorption spectroscopy (XAS) showed that Ag2S was the main species in the sludge and amended soil before and after plant culture. The second most abundant species was an organic and/or amorphous Ag-S phase whose proportion slightly varied (from 24% to 36%) depending on the conditions. Micro and nano X-ray fluorescence (XRF) showed that Ag was preferentially associated with S-rich particles, including organic fragments, of the sludge and amended soils. Ag was distributed as heteroaggregates with soil components (size ranging from ≤0.5 to 1-3 μm) and as diffused zones likely corresponding to sorbed/complexed Ag species. Nano-XRF evidenced the presence of mixed metallic sulfides. Ag was weakly exchangeable and labile. However, micronutrient mobilization by plant roots and organic matter turnover may induce Ag species interconversion eventually leading to Ag release on longer time scales. Together, these data provide valuable information for risk assessment of sewage sludge application on agricultural soils. PMID:26756906

  11. Large-area multilayer infrared nano-wire grid polarizers

    NASA Astrophysics Data System (ADS)

    Gayduk, Alexey E.; Prinz, Victor Ya.; Seleznev, Vladimir A.; Rechkunov, Sergey N.

    2016-03-01

    We have developed a technology for fabricating infrared polarizers based on double- and four-layer metal-dielectric nanogratings. Due to the use of nanoimprint lithography, the size of fabricated samples with 190-nm grating period could be made exceeding 170 cm2. The fabricated polarizers are flexible, and they have high quality over the entire area of the sample. Spectrophotometric measurements and numerical simulations have showed that the polarizers exhibited a large transmission coefficient and a high extinction ratio (over 3 ṡ 104). In order to expand applications of polarizers to the bio-inspired wide field-of-view systems, technology for fabricating polarizers on curved surfaces prepared by 3D printing has been developed. The obtained results offer much promise for polarimetry purposes.

  12. Stability of Ag nanoparticles dispersed in amphiphilic organic matrix

    NASA Astrophysics Data System (ADS)

    Suvorova, Elena I.; Klechkovskaya, Vera V.; Kopeikin, Victor V.; Buffat, Philippe A.

    2005-02-01

    Nano- and thin-film technologies based on novel systems associating metals particles to polymer matrix open a broad range of different applications. Such composites were found to be more efficient and safe, for instance, in biomedical needs. The Ag/poly(N-vinyl-2-pyrrolidone) (Ag/PVP) composite investigated in the present work is a new bactericide mean applied in complicated cases of infected burns and purulent wounds. High-resolution transmission electron microscopy (HRTEM) and X-ray energy-dispersive (EDS) microanalysis were used to bring chemical and structural information in a study of the properties and stability of thin-film nanocomposite whih consisted of Ag nanoparticles dispersed in water-soluble organic matrix poly(N-vinyl-2-pyrrolidone). The nanostructural investigation of Ag/PVP composite by HRTEM and EDS exposed to SO 2 and H 2S from the atmosphere and some traces of S-containing substances explains the limited stability of this system by a structural modification associated with a phase change and formation of Ag 2S and Ag 2SO 3. However, formation of the hardly water-soluble Ag 2S and Ag 2SO 3 salts may play an important role in the suppression of bacterial growth. On the one hand, silver could block S-H groups in vital proteins and conduced to their destruction, in that way revealing the antibacterial power. On the other hand, antiseptic properties of Ag consist in binding the products of the protein decay.

  13. Dual wire welding torch and method

    DOEpatents

    Diez, Fernando Martinez; Stump, Kevin S.; Ludewig, Howard W.; Kilty, Alan L.; Robinson, Matthew M.; Egland, Keith M.

    2009-04-28

    A welding torch includes a nozzle with a first welding wire guide configured to orient a first welding wire in a first welding wire orientation, and a second welding wire guide configured to orient a second welding wire in a second welding wire orientation that is non-coplanar and divergent with respect to the first welding wire orientation. A method of welding includes moving a welding torch with respect to a workpiece joint to be welded. During moving the welding torch, a first welding wire is fed through a first welding wire guide defining a first welding wire orientation and a second welding wire is fed through a second welding wire guide defining a second welding wire orientation that is divergent and non-coplanar with respect to the first welding wire orientation.

  14. Wire detecting apparatus and method

    SciTech Connect

    Kronberg, J.W.

    1991-12-31

    This invention is comprised of an apparatus and method that combines a signal generator and a passive signal receiver to detect and record the path of partially or completely concealed electrical wiring without disturbing the concealing surface. The signal generator applies a series of electrical pulses to the selected wiring of interest. The applied pulses create a magnetic field about the wiring that can be detected by a coil contained within the signal receiver. An audible output connected to the receiver and driven by the coil reflects the receiver`s position with respect to the wiring. The receiver`s audible signal is strongest when the receiver is directly above the wiring and the long axis of the receiver`s coil is parallel to the wiring. A marking means is mounted on the receiver to mark the location of the wiring as the receiver is directed over the wiring`s concealing surface. Numerous marks made on various locations of the concealing surface will trace the path of the wiring of interest.

  15. Manually Operated Welding Wire Feeder

    NASA Technical Reports Server (NTRS)

    Rybicki, Daniel J. (Inventor)

    2001-01-01

    A manual welding wire feeder apparatus comprising a bendable elongate metal frame with a feed roller mounted at the center thereof for rotation about an axis transverse to the longitudinal axis of the frame. The frame ends are turned up as tabs and each provided with openings in alignment with each other and the mid-width center of the roller surface. The tab openings are sized to accommodate welding wire and each extends to a side edge of the tab, both opening on the same side of the frame, whereby welding wire can be side-loaded onto the frame. On the side of the frame, opposite the roller a lock ring handle is attached tangentially and is rotatable about the attachment point and an axis perpendicular to the frame. The device is grasped in the hand normally used to hold the wire. A finger is placed through the loop ring and the frame positioned across the palm and lower fingers. The thumb is positioned atop the wire so it can be moved from the back of the frame across the roller, and towards the front. In doing so, the wire is advanced at a steady rate in axial alignment with the tab openings and roller. To accommodate different wire diameters the frame is bendable about its center in the plane of the frame axis and wire so as to keep the wire in sufficient tension against the roller and to keep the wire fixed when the frame is tilted and thumb pressure released.

  16. Ag/AgCl electrodes in the EEG/fMRI method in 3T MRI scanner

    NASA Astrophysics Data System (ADS)

    Akay, Cengiz; Kepceoğlu, Abdullah

    2013-10-01

    This study focuses on the comparison of two different types of EEG electrodes (the first B10-S-150 Ag/AgCl sintered ring electrode with 1, 5 mm touch proof safety socket and 150 cm heavy-duty lead wire and the second, B12-LS-100 Ag/AgCl sintered FE-electrode with 100 cm light-duty lead wire and 1, 5 mm touch proof safety socket with 5 kΩ resistor near sensor) used in the EEG/fMRI method in 3T MRI scanner. We compared these electrodes by their specific absorption rate (SAR) simulation values and the temperature change calculated by PRF method. The experimental setup of the study is described as follows: a phantom is prepared and the electrodes are placed on it. Then, a simulation for SAR values is realized. The temperature change is calculated by MR thermometer. As a result of this study, Ag/AgCl pin electrode is better to be use in EEG/fMRI; because the measured temperature change is expected to be low.

  17. Metering Wheel-Wire Track Wire Boom Deployment Mechanism

    NASA Technical Reports Server (NTRS)

    Granoff, Mark S.

    2014-01-01

    The NASA MMS Spin Plane Double Probe (SDP) Deployer utilizes a helical path, rotating Metering Wheel and a spring loaded Wire "Holding" Track to pay out a "fixed end" 57 meter x 1.5 mm diameter Wire Boom stored between concentric storage cylinders. Unlike rotating spool type storage devices, the storage cylinders remain stationary, and the boom wire is uncoiled along the length of the cylinder via the rotation of the Metering Wheel. This uncoiling action avoids the need for slip-ring contacts since the ends of the wire can remain stationary. Conventional fixed electrical connectors (Micro-D type) are used to terminate to operational electronics.

  18. Nano-technology and nano-toxicology

    PubMed Central

    Maynard, Robert L.

    2012-01-01

    Rapid developments in nano-technology are likely to confer significant benefits on mankind. But, as with perhaps all new technologies, these benefits are likely to be accompanied by risks, perhaps by new risks. Nano-toxicology is developing in parallel with nano-technology and seeks to define the hazards and risks associated with nano-materials: only when risks have been identified they can be controlled. This article discusses the reasons for concern about the potential effects on health of exposure to nano-materials and relates these to the evidence of the effects on health of the ambient aerosol. A number of hypotheses are proposed and the dangers of adopting unsubstantiated hypotheses are stressed. Nano-toxicology presents many challenges and will need substantial financial support if it is to develop at a rate sufficient to cope with developments in nano-technology. PMID:22662021

  19. Review of wire chamber aging

    SciTech Connect

    Va'Vra, J.

    1986-02-01

    This paper makes an overview of the wire chamber aging problems as a function of various chamber design parameters. It emphasizes the chemistry point of view and many examples are drawn from the plasma chemistry field as a guidance for a possible effort in the wire chamber field. The paper emphasizes the necessity of variable tuning, the importance of purity of the wire chamber environment, as well as it provides a practical list of presently known recommendations. In addition, several models of the wire chamber aging are qualitatively discussed. The paper is based on a summary talk given at the Wire Chamber Aging Workshop held at LBL, Berkeley on January 16-17, 1986. Presented also at Wire Chamber Conference, Vienna, February 25-28, 1986. 74 refs., 18 figs., 11 tabs.

  20. Neural wiring optimization.

    PubMed

    Cherniak, Christopher

    2012-01-01

    Combinatorial network optimization theory concerns minimization of connection costs among interconnected components in systems such as electronic circuits. As an organization principle, similar wiring minimization can be observed at various levels of nervous systems, invertebrate and vertebrate, including primate, from placement of the entire brain in the body down to the subcellular level of neuron arbor geometry. In some cases, the minimization appears either perfect, or as good as can be detected with current methods. One question such best-of-all-possible-brains results raise is, what is the map of such optimization, does it have a distinct neural domain? PMID:22230636

  1. Plated wire memory subsystem

    NASA Technical Reports Server (NTRS)

    Carpenter, K. H.

    1974-01-01

    The design, construction, and test history of a 4096 word by 18 bit random access NDRO Plated Wire Memory for use in conjunction with a spacecraft input/output and central processing unit is reported. A technical and functional description is given along with diagrams illustrating layout and systems operation. Test data is shown on the procedures and results of system level and memory stack testing, and hybrid circuit screening. A comparison of the most significant physical and performance characteristics of the memory unit versus the specified requirements is also included.

  2. Texture development in Galfenol wire

    NASA Astrophysics Data System (ADS)

    Boesenberg, A. J.; Restorff, J. B.; Wun-Fogle, M.; Sailsbury, H.; Summers, E.

    2013-05-01

    Galfenol (Fe-Ga alloy) wire fabrication provides a low cost alternative to directional solidification methods. This work evaluates the compositional dependence of the wire drawing suitability of Fe-Ga and characterizes the microstructural and magnetic properties of these wires. Wire has been produced with Ga contents between 10 at. % and 17 at. % to allow determination of the ductile to brittle transition (DTBT) in wire manufacture. Published results on chill cast bend specimens indicated that a DTBT occurs at roughly 15 at. % Ga. This DTBT was observed under tensile loading with a corresponding change in fracture behavior from transverse fracture to intergranular fracture. For improved magnetostrictive performance, higher Ga contents are desired, closer to the 17 at. % Ga evaluated in this work. Electron backscattered diffraction B-H loop and resonance measurements as a function of magnetic field (to determine modulus and coupling factor) are presented for as-drawn, furnace, and direct current (DC) annealed wire. Galfenol wire produced via traditional drawing methods is found to have a strong <110> (α) texture parallel to the drawing direction. As-drawn wire was observed to have a lower magnetic permeability and larger hysteresis than DC annealed wire. This is attributed to the presence of a large volume of crystalline defects; such as vacancies and dislocations.

  3. 49 CFR 236.74 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... underground wire. 236.74 Section 236.74 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION RULES, STANDARDS, AND INSTRUCTIONS GOVERNING... wire; splice in underground wire. Insulated wire shall be protected from mechanical injury....

  4. 49 CFR 236.74 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... underground wire. 236.74 Section 236.74 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION RULES, STANDARDS, AND INSTRUCTIONS GOVERNING... wire; splice in underground wire. Insulated wire shall be protected from mechanical injury....

  5. 49 CFR 234.241 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... underground wire. 234.241 Section 234.241 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION GRADE CROSSING SIGNAL SYSTEM SAFETY... of insulated wire; splice in underground wire. Insulated wire shall be protected from...

  6. 49 CFR 236.74 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... underground wire. 236.74 Section 236.74 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION RULES, STANDARDS, AND INSTRUCTIONS GOVERNING... wire; splice in underground wire. Insulated wire shall be protected from mechanical injury....

  7. 49 CFR 236.74 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... underground wire. 236.74 Section 236.74 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION RULES, STANDARDS, AND INSTRUCTIONS GOVERNING... wire; splice in underground wire. Insulated wire shall be protected from mechanical injury....

  8. 49 CFR 234.241 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... underground wire. 234.241 Section 234.241 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION GRADE CROSSING SIGNAL SYSTEM SAFETY... of insulated wire; splice in underground wire. Insulated wire shall be protected from...

  9. 49 CFR 236.74 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... underground wire. 236.74 Section 236.74 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION RULES, STANDARDS, AND INSTRUCTIONS GOVERNING... wire; splice in underground wire. Insulated wire shall be protected from mechanical injury....

  10. Modeled environmental concentrations of engineered nanomaterials (TiO(2), ZnO, Ag, CNT, Fullerenes) for different regions.

    PubMed

    Gottschalk, Fadri; Sonderer, Tobias; Scholz, Roland W; Nowack, Bernd

    2009-12-15

    Engineered nanomaterials (ENM) are already used in many products and consequently released into environmental compartments. In this study, we calculated predicted environmental concentrations (PEC) based on a probabilistic material flow analysis from a life-cycle perspective of ENM-containing products. We modeled nano-TiO(2), nano-ZnO, nano-Ag, carbon nanotubes (CNT), and fullerenes for the U.S., Europe and Switzerland. The environmental concentrations were calculated as probabilistic density functions and were compared to data from ecotoxicological studies. The simulated modes (most frequent values) range from 0.003 ng L(-1) (fullerenes) to 21 ng L(-1) (nano-TiO(2)) for surface waters and from 4 ng L(-1) (fullerenes) to 4 microg L(-1) (nano-TiO(2)) for sewage treatment effluents. For Europe and the U.S., the annual increase of ENMs on sludge-treated soil ranges from 1 ng kg(-1) for fullerenes to 89 microg kg(-1) for nano-TiO(2). The results of this study indicate that risks to aquatic organisms may currently emanate from nano-Ag, nano-TiO(2), and nano-ZnO in sewage treatment effluents for all considered regions and for nano-Ag in surface waters. For the other environmental compartments for which ecotoxicological data were available, no risks to organisms are presently expected. PMID:20000512

  11. Aspects of SiC diode assembly using Ag technology

    NASA Astrophysics Data System (ADS)

    Mysliwiec, Marcin; Guziewicz, Marek; Kisiel, Ryszard

    2013-07-01

    The aim of our paper is to consider the possibility of applying pure Ag technology for assembly of SiC Schottky diode into a ceramic package able to work at temperatures up to 350°C. Ag micropowder was used for assembly SiC structure to DBC interposer of the ceramic package. Ag wire bonds as well as flip-chip technology using Ag balls were used as material for interconnection systems. The parameters of I-V characteristics were used as a quality factor to determine the Schottky diode after hermetization into ceramic package as well as after ageing in air at 350°C in comparison with characteristics of bare SiC diode.

  12. Study of tribological behavior of Cu-MoS2 and Ag-MoS2 nanocomposite lubricants.

    PubMed

    An, V; Anisimov, E; Druzyanova, V; Burtsev, N; Shulepov, I; Khaskelberg, M

    2016-01-01

    Tribological behavior of Cu-MoS2 and Ag-MoS2 nanocomposite lubricant was studied. Cu nanoparticles produced by electrical explosion of copper wires and Ag nanoparticles prepared by electrospark erosion were employed as metal cladding modifiers of MoS2 nanolamellar particles. The tribological tests showed Cu-MoS2 and Ag-MoS2 nanocomposite lubricants changed the friction coefficient of the initial grease and essentially improved its wear resistance. PMID:26837277

  13. Two-Wire to Four-Wire Audio Converter

    NASA Technical Reports Server (NTRS)

    Talley, G. L., Jr; Seale, B. L.

    1983-01-01

    Simple circuit provides interface between normally incompatible voicecommunication lines. Circuit maintains 40 dB of isolation between input and output halves of four-wire line permitting two-wire line to be connected. Balancing potentiometer, Rg, adjusts gain of IC2 to null feed through from input to output. Adjustment is done on workbench just after assembly.

  14. Single-wire dye-sensitized solar cells wrapped by carbon nanotube film electrodes.

    PubMed

    Zhang, Sen; Ji, Chunyan; Bian, Zhuqiang; Liu, Runhua; Xia, Xinyuan; Yun, Daqin; Zhang, Luhui; Huang, Chunhui; Cao, Anyuan

    2011-08-10

    Conventional fiber-shaped polymeric or dye-sensitized solar cells (DSSCs) are usually made into a double-wire structure, in which a secondary electrode wire (e.g., Pt) was twisted along the primary core wire consisting of active layers. Here, we report highly flexible DSSCs based on a single wire, by wrapping a carbon nanotube film around Ti wire-supported TiO(2) tube arrays as the transparent electrode. Unlike a twisted Pt electrode, the CNT film ensures full contact with the underlying active layer, as well as uniform illumination along circumference through the entire DSSC. The single-wire DSSC shows a power conversion efficiency of 1.6% under standard illumination (AM 1.5, 100 mW/cm(2)), which is further improved to more than 2.6% assisted by a second conventional metal wire (Ag or Cu). Our DSSC wires are stable and can be bent to large angles up to 90° reversibly without performance degradation. PMID:21766836

  15. Soft magnetic wires

    NASA Astrophysics Data System (ADS)

    Vázquez, M.

    2001-06-01

    An overview of the present state of the art on the preparation techniques, outstanding magnetic properties and applications of soft magnetic micro and nanowires is presented. Rapid solidification techniques (in-rotating-water quenching and drawing methods) to fabricate amorphous microwires with diameter in the range from 100 down to 1 μm are first described. Electrodeposition is also employed to prepare composite microtubes (magnetic coatings) and to fill porous membranes (diameter of the order of 0.1 μm). Magnetic behaviours of interest are related to the different hysteresis loops of samples: square-shaped loops typical of bistable behaviour, and nearly non-hysteretic loop with well-defined transverse anisotropy field. The role played by magnetic dipolar interactions in the magnetic behaviour of arrays of micro and nanowires is described. A particular analysis is done on the giant magnetoimpedance (GMI) effect in the radio and microwave frequency ranges exhibited by ultrasoft microwires. Finally, a few examples of applications are introduced for magnetostrictive and non-magnetostrictive wires, they are: “magnetoelastic pens”, micromotors; DC current-sensors based on GMI, and sharpened amorphous wire tips in spin polarised scanning tunneling microscopy.

  16. Improved superconducting magnet wire

    DOEpatents

    Schuller, I.K.; Ketterson, J.B.

    1983-08-16

    This invention is directed to a superconducting tape or wire composed of alternating layers of copper and a niobium-containing superconductor such as niobium of NbTi, Nb/sub 3/Sn or Nb/sub 3/Ge. In general, each layer of the niobium-containing superconductor has a thickness in the range of about 0.05 to 1.5 times its coherence length (which for Nb/sub 3/Si is 41 A) with each copper layer having a thickness in the range of about 170 to 600 A. With the use of very thin layers of the niobium composition having a thickness within the desired range, the critical field (H/sub c/) may be increased by factors of 2 to 4. Also, the thin layers of the superconductor permit the resulting tape or wire to exhibit suitable ductility for winding on a magnet core. These compositions are also characterized by relatively high values of critical temperature and therefore will exhibit a combination of useful properties as superconductors.

  17. A Binder-Free Ag Paste Using a Chemically Adsorbed Monolayer

    NASA Astrophysics Data System (ADS)

    Onishi, Shogo; Ohkubo, Yuji; Soejima, Kazuhiro; Ogawa, Kazufumi

    2009-06-01

    We developed a binder-free Ag paste using reactive chemically absorbed monolayers (CAMs), such as epoxy-terminated CAMs. Ag paste was prepared by forming an epoxy-terminated CAM with 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane (ECHxES) on the surface of Ag particles, followed by adding 2-methyl-imidazole (2-MeIm) as a cross-linker into a suspension of dispersed Ag particles modified with ECHxES. To increase electrical conductivity, a mixture of large (average diameter D = 1.0 µm) and small (D = 0.5 µm) Ag particles was used. When the ratio in the mixture of large: small was 7:3, the best conductivity, 4.0 ×104 S/cm, was obtained. To prepare rigid wires from Ag paste, a cross-linker of a copper imidazole complex, instead of 2-MeIm, was added to the mixture of the Ag particles covered with ECHxES CAMs. The best pencil hardness and the best electrical conductivity obtained with the Ag paste wire were F and 2.5 ×105 S/cm, respectively, which exceeded the values of commercially available Ag pastes.

  18. Preparation of silver nano-particles immobilized onto chitin nano-crystals and their application to cellulose paper for imparting antimicrobial activity.

    PubMed

    Li, Zhihan; Zhang, Ming; Cheng, Dong; Yang, Rendang

    2016-10-20

    Immobilized silver nano-particles (Ag NPs) possess excellent antimicrobial properties due to their unique surface characteristics. In this paper, immobilized silver nano-particles were synthesized in the presence of chitin nano-crystals (CNC) based on the Tollens mechanism (reduction of silver ion by aldehydes in the chitosan oligosaccharides (COS)) under microwave-assisted conditions. The prepared Ag NPs-loaded CNC nano-composites were then applied onto the paper surface via coating for the preparation of antibacterial paper. Fourier transform infrared (FT-IR) and X-ray diffraction (XRD) results confirmed that the Ag NPs were immobilized onto the CNC. The transmission electron microscope (TEM) and scanning electron microscopy (SEM) results further revealed that the spherical Ag NPs (5-12nm) were well dispersed on the surface of CNC. The coated paper made from the Ag NPs-loaded CNC nano-composites exhibited a high effectiveness of the antibacterial activity against E. coli or S. aureus. PMID:27474631

  19. A Novel Sensor for Sensitive and Selective Detection of Iodide Using Turn-on Fluorescence Graphene Quantum Dots/Ag Nanocomposite.

    PubMed

    Xu, Xianghong; Wang, Yanhui

    2015-01-01

    Based on the principle of fluorescence enhancing, by the strong and specific interreaction between iodide (I(-)) ions and nanoAg on the surface of graphene quantum dots/Ag (GQDs/Ag) nanocomposite, we propose a simple label-free and turn-on method for the detection of I(-) ions with high selectivity and sensitivity by using fluorescent GQDs/Ag nanocomposite in aqueous media. PMID:26256602

  20. High temperature self-assembly of Ag nanowires on vicinal Si(001)

    NASA Astrophysics Data System (ADS)

    Roos, K. R.; Roos, K. L.; Horn-von Hoegen, M.; Heringdorf, F.-J. Meyer zu

    2005-04-01

    We have used low energy electron microscopy (LEEM) and photo emission electron microscopy (PEEM) to study the high temperature (620 °C) self-assembly of Ag nanowires on vicinal Si(001), miscut 4° in the [110] direction. After formation of an initial wetting layer, growth of wire-like structures proceeds with subsequent deposition. Simultaneously, compact islands form and the nanowires comprise only a minority of the total Ag deposit. The wires display quasi-one-dimensional behaviour as their length is observed to increase while their width remains constant. The lengths of the wires can be controlled and we have routinely grown wires longer than 100 µm. A kinetically limiting process, wherein mass transport is suppressed in the direction normal to the direction of elongation, is identified as a contributor to the growth of the nanowires.

  1. AGS experiments - 1994, 1995, 1996

    SciTech Connect

    Depken, J.C.

    1997-01-01

    This report contains the following information on the Brookhaven AGS Accelerator complex: FY 1996 AGS schedule as run; FY 1997 AGS schedule (working copy); AGS beams 1997; AGS experimental area FY 1994 physics program; AGS experimental area FY 1995 physics program; AGS experimental area FY 1996 physics program; AGS experimental area FY 1997 physics program (in progress); a listing of experiments by number; two-phage summaries of each experiment begin here, also ordered by number; listing of publications of AGS experiments begins here; and listing of AGS experimenters begins here.

  2. The Current in a Wire

    ERIC Educational Resources Information Center

    Thompson, Keith

    2009-01-01

    This little problem arose because I was frustrated with the standard electromagnetism texts, which show the magnetic field due to a current-bearing wire outside the wire [proportional to] 1/r and inside [proportional to] r. However, they never point out that the moving electrons must be influenced by the magnetic field created by the other moving…

  3. Aircraft wiring program status report

    NASA Technical Reports Server (NTRS)

    Beach, Rex

    1995-01-01

    In this Naval Air Warfare Center (NAWC) Aircraft Division status report, the general and wire and cable component activities, the systems engineering activities, the aircraft wiring lead maintenance activities, the NAVAIR/NASA interface activities, and the Base Realignment and Closure (BRAC) Commission recommendations are presented.

  4. First Wire-Free Pacemaker Approved

    MedlinePlus

    ... Wire-Free Pacemaker Approved Treats irregular heartbeat without wired leads To use the sharing features on this ... said in a news release. In traditional pacemakers, wired leads may malfunction and require the device to ...

  5. Wired up: interconnecting two-dimensional materials with one-dimensional atomic chains.

    PubMed

    Rong, Youmin; Warner, Jamie H

    2014-12-23

    Atomic wires are chains of atoms sequentially bonded together and epitomize the structural form of a one-dimensional (1D) material. In graphene, they form as interconnects between regions when the nanoconstriction eventually becomes so narrow that it is reduced to one atom thick. In this issue of ACS Nano, Cretu et al. extend the discovery of 1D atomic wire interconnects in two-dimensional (2D) materials to hexagonal boron nitride. We highlight recent progress in the area of 1D atomic wires within 2D materials, with a focus on their atomic-level structural analysis using aberration-corrected transmission electron microscopy. We extend this discussion to the formation of nanowires in transition metal dichalcogenides under similar electron-beam irradiation conditions. The future outlook for atomic wires is considered in the context of new 2D materials and hybrids of C, B, and N. PMID:25474120

  6. Welding wire pressure sensor assembly

    NASA Technical Reports Server (NTRS)

    Morris, Timothy B. (Inventor); Milly, Peter F., Sr. (Inventor); White, J. Kevin (Inventor)

    1994-01-01

    The present invention relates to a device which is used to monitor the position of a filler wire relative to a base material being welded as the filler wire is added to a welding pool. The device is applicable to automated welding systems wherein nonconsumable electrode arc welding processes are utilized in conjunction with a filler wire which is added to a weld pool created by the electrode arc. The invention senses pressure deviations from a predetermined pressure between the filler wire and the base material, and provides electrical signals responsive to the deviations for actuating control mechanisms in an automatic welding apparatus so as to minimize the pressure deviation and to prevent disengagement of the contact between the filler wire and the base material.

  7. Welding wire pressure sensor assembly

    NASA Astrophysics Data System (ADS)

    Morris, Timothy B.; Milly, Peter F.; White, J. Kevin

    1993-05-01

    The present invention relates to a device which is used to monitor the position of a filler wire relative to a base material being welded as the filler wire is added to a welding pool. The device is applicable to automated welding systems wherein nonconsumable electrode arc welding processes are utilized in conjunction with a filler wire which is added to a weld pool created by the electrode arc. The invention senses pressure deviations from a predetermined pressure between the filler wire and the base material, and provides electrical signals responsive to the deviations for actuating control mechanisms in an automatic welding apparatus so as to minimize the pressure deviation and to prevent disengagement of the contact between the filler wire and the base material.

  8. Welding wire pressure sensor assembly

    NASA Astrophysics Data System (ADS)

    Morris, Timothy B.; Milly, Peter F., Sr.; White, J. Kevin

    1994-04-01

    The present invention relates to a device which is used to monitor the position of a filler wire relative to a base material being welded as the filler wire is added to a welding pool. The device is applicable to automated welding systems wherein nonconsumable electrode arc welding processes are utilized in conjunction with a filler wire which is added to a weld pool created by the electrode arc. The invention senses pressure deviations from a predetermined pressure between the filler wire and the base material, and provides electrical signals responsive to the deviations for actuating control mechanisms in an automatic welding apparatus so as to minimize the pressure deviation and to prevent disengagement of the contact between the filler wire and the base material.

  9. Apollo experience report: Electrical wiring subsystem

    NASA Technical Reports Server (NTRS)

    White, L. D.

    1975-01-01

    The general requirements of the electrical wiring subsystems and the problem areas and solutions that occurred during the major part of the Apollo Program are detailed in this report. The concepts and definitions of specific requirements for electrical wiring; wire-connecting devices; and wire-harness fabrication, checkout, and installation techniques are discussed. The design and development of electrical wiring and wire-connecting devices are described. Mission performance is discussed, and conclusions and recommendations for future programs are presented.

  10. Electrode carrying wire for GTAW welding

    NASA Technical Reports Server (NTRS)

    Morgan, Gene E. (Inventor); Dyer, Gerald E. (Inventor)

    1990-01-01

    A welding torch for gas tungsten arc welding apparatus has a hollow tungsten electrode including a ceramic liner and forms the filler metal wire guide. The wire is fed through the tungsten electrode thereby reducing the size of the torch to eliminate clearance problems which exist with external wire guides. Since the wire is preheated from the tungsten more wire may be fed into the weld puddle, and the wire will not oxidize because it is always within the shielding gas.

  11. Internal wire guide for GTAW welding

    NASA Technical Reports Server (NTRS)

    Morgan, Gene E. (Inventor); Dyer, Gerald E. (Inventor)

    1989-01-01

    A welding torch for gas tungsten arc welding apparatus has a filler metal wire guide positioned within the torch, and within the shielding gas nozzle. The wire guide is adjacent to the tungsten electrode and has a ceramic liner through which the wire is fed. This reduces the size of the torch and eliminates the outside clearance problems that exit with external wire guides. Additionally, since the wire is always within the shielding gas, oxidizing of the wire is eliminated.

  12. Limiting current mechanisms of Bi2223 wires in magnetic fields

    NASA Astrophysics Data System (ADS)

    Kobayashi, S.; Yamade, S.; Kikuchi, M.; Yamazaki, K.; Fujikami, J.; Ayai, N.; Hayashi, K.; Sato, K.; Hata, R.; Kitaguti, H.

    2008-05-01

    Controlled overpressure (CT-OP) processing eliminates pores and heals cracks, which densifies the Bi2223 filaments and increases the critical current of Ag-sheathed Bi2223 wire. High current capacity wires with critical current values around 210 A at 77 K and self-field have been achieved. The enhancement of the current capacity seems to be due to reducing the weak links between Bi2223 grains and improving the flux pinning. In order to understand the mechanisms for transport critical current in Bi2223 wires, the dependence of the critical current on magnetic field and temperature has been investigated. The critical current is measured as a function of the perpendicular and parallel magnetic fields, up to 12 T, at temperatures ranging from 4.2 to 90 K. These results indicate that higher critical current is associated with highly textured and well connected Bi2223 grains. To further improve a critical current of Bi2223 wires, it is necessary to decrease the misalignment angle and reduce the fraction of Bi2212 and secondary phases.

  13. Progress in wire fabrication of iron-based superconductors

    NASA Astrophysics Data System (ADS)

    Ma, Yanwei

    2012-11-01

    Iron-based superconductors, with Tc values up to 55 K, are of great interest for applications, due to their lower anisotropies and ultrahigh upper critical fields. In the past four years, great progress has been made in the fabrication of iron-based superconducting wires and tapes using the powder-in-tube (PIT) processing method, including main three types of 122, 11, and 1111 iron-based parent compounds. In this article, an overview of the current state of development of iron-based superconducting wires and tapes is presented. We focus on the fabrication techniques used for 122 pnictide wires and tapes, with an emphasis on their meeting the critical current requirements for making high-performance conductors, such as a combination of using Ag sheath, addition element and optimized heat treatment to realize high Jc, ex situ process employed to reduce non-superconducting phases and to obtain a high relative density, and a texture control to improve grain connectivity. Of particular interest is that so far transport Jc values above 104 A cm-2 at 4.2 K and 10 T are obtained in 122 type tapes, suggesting that they are prospective candidates for high-field applications. Finally, a perspective and future development of PIT pnictide wires are also given.

  14. A study of plasmonic enhanced transmission effects in nano-optics

    SciTech Connect

    Gbur, Greg

    2012-01-24

    This project was a numerical study of the behavior of surface plasmons in nano-systems, focusing on the interaction between plasmons, light, and nano-scale structures such as nano-scale metallic wires and quantum wires/dots. The primary results of the project included: a) the demonstration of the use of surface plasmons to modify the spatial coherence of a light wave, b) the demonstration of a feasible plasmonic superresolved readout system, and c) the demonstration of a Plasmonic Zeno effect, in which the attenuation of a light wave in metal is suppressed by breaking up the metal into a collection of structured layers. The integration of quantum wire/dot effects with the plasmonic simulations proved to be harder than expected, in large part due to the lack of accurate and simple quantum dot models.

  15. Sonochemical procedures; the main synthetic method for synthesis of coinage metal ion supramolecular polymer nano structures.

    PubMed

    Shahangi Shirazi, Fatemeh; Akhbari, Kamran

    2016-07-01

    During the last two decades, supramolecular polymers have received great attention and the number of their synthesized compounds is still growing. Although people have long been interested in their crystalline network form it was only until 2005 that the first examples of nano- or microscale coordination polymers particles be demonstrated. This review tries to give an overview of all nano supramolecular compounds which were reported from coinage metal ions, their attributed synthetic procedures and to investigate the relation between the dimensions of coinage metal ions (Cu, Ag and Au) coordination and supramolecular polymers with their nano-structural morphologies and dimensions. Eleven compounds (from twenty compounds) with nano-structure morphology were prepared by sonochemical process and Ag(I) coordination and supramolecular polymer nano-structures can be easily prepared by sonochemical procedures. PMID:26964923

  16. Sintered wire cathode

    DOEpatents

    Falce, Louis R.; Ives, R. Lawrence

    2009-06-09

    A porous cathode structure is fabricated from a plurality of wires which are placed in proximity to each other in elevated temperature and pressure for a sintering time. The sintering process produces the porous cathode structure which may be divided into a plurality of individual porous cathodes, one of which may be placed into a dispenser cathode support which includes a cavity for containing a work function reduction material such as BaO, CaO, and Al.sub.2O.sub.3. The work function reduction material migrates through the pores of the porous cathode from a work replenishment surface adjacent to the cavity of the dispenser cathode support to an emitting cathode surface, thereby providing a dispenser cathode which has a uniform work function and therefore a uniform electron emission.

  17. Critical interparticle distance for the remarkably enhanced dielectric constant of BaTiO3-Ag hybrids filled polyvinylidene fluoride composites

    NASA Astrophysics Data System (ADS)

    Luo, Suibin; Yu, Shuhui; Fang, Fang; Lai, Maobai; Sun, Rong; Wong, Ching-Ping

    2014-06-01

    Discrete nano Ag-deposited BaTiO3 (BT-Ag) hybrids with varied Ag content were synthesized, and the hybrids filled polyvinylidene fluoride (PVDF) composites were prepared. The effect of Ag content on the dielectric properties of the composites were analyzed based on the diffused electrical double layer theory. Results showed that with a higher Ag content in BT-Ag hybrids, the dielectric constant of BT-Ag/PVDF composites increases fast with the filler loading, while the dielectric loss and conductivity showed a suppressed and moderate increase. The dielectric constant of BT-0.61Ag/PVDF (61 wt. % of Ag in BT-Ag hybrid) composites reached 613, with the dielectric loss of 0.29 at 1 kHz. It was deduced that remarkably enhanced dielectric constant appeared when the interparticle distance decreased to a critical value of about 20 nm.

  18. Thermal conductivity of 2G HTS wires for current lead applications

    NASA Astrophysics Data System (ADS)

    Hoffmann, C.; Strickland, N.; Pooke, D.; Gannon, J.; Carter, B.; Otto, A.

    2010-06-01

    We have studied the thermal conductivity of several 2G HTS coated conductor wires produced by AMSC's RABiTSTM/MOD processes. The measurements employed a non-steady state method in which the sample is connected to a cold head on one end and a copper block on the other end. The heat capacity of the copper block is used to determine heat flow through the sample as the cold head slowly warms up. Measurements were done at temperatures ranging from 10 K to 130 K on 2G wires made with a Ni 5at%W substrate and different lamination architectures. The focus of the investigation was on the effects of lamina material type, thickness of the silver layer and alloyed silver. The data show that 2G wires can be 3 times less thermally conductive when compared to 1G BSCCO wires with a Ag-Au matrix, making them excellent candidates for use in current lead applications.

  19. Plasma chemistry in wire chambers

    SciTech Connect

    Wise, J.

    1990-05-01

    The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to remove trace water and oxygen contaminants from the gas resulted in an increase in the average molecular weight of the products, consistent with results from low-pressure rf-discharge plasmas. It is suggested that because water and oxygen inhibit polymer growth in the gas phase that they may also reduce polymer deposition in proportional tubes and therefore retard wire aging processes. Mechanistic implications of the plasma reactions of hydrocarbons with oxygen are suggested. Unresolved issues in this work and proposals for further study are discussed.

  20. Growth and characterization of horizontal GaN wires on silicon

    SciTech Connect

    Zou, Xinbo; May Lau, Kei; Lu, Xing; Lucas, Ryan; Kuech, Thomas F.; Choi, Jonathan W.; Gopalan, Padma

    2014-06-30

    We report the growth of in-plane GaN wires on silicon by metalorganic chemical vapor deposition. Triangular-shaped GaN microwires with semi-polar sidewalls are observed to grow on top of a GaN/Si template patterned with nano-porous SiO{sub 2}. With a length-to-thickness ratio ∼200, the GaN wires are well aligned along the three equivalent 〈 112{sup ¯}0 〉 directions. Micro-Raman measurements indicate negligible stress and a low defect density inside the wires. Stacking faults were found to be the only defect type in the GaN wire by cross-sectional transmission electron microscopy. The GaN wires exhibited high conductivity, and the resistivity was 20–30 mΩ cm, regardless of the wire thickness. With proper heterostructure and doping design, these highly aligned GaN wires are promising for photonic and electronic applications monolithically integrated on silicon.

  1. Ultrafast Nonlinear Plasmonics of Single Nano-Objects

    NASA Astrophysics Data System (ADS)

    Del Fatti, Natalia

    Investigating, understanding and modeling the physical properties of nano-objects are intense fields of research. Of particular interest are metal-based nano-objects, where their morphology and environment dependent surface plasmon resonances (SPR) have been extensively exploited to design new optical systems. As a SPR is associated to electromagnetic local field enhancement in the nano-object, it also leads to enhancement of its optical nonlinearity, opening many possibilities for investigating fundamental processes at nanoscale. Most of these studies were performed on large ensembles of nano-objects, providing mean information which impedes detailed comparison between experimental data and theoretical models. With the advance of single nanoparticle spectroscopy methods, the linear and nonlinear responses of a single nano-object can now be addressed, which, associated to determination of its morphology by electron microscopy, opens the way to their quantitative modeling. In this context we discuss experimental and theoretical investigations of the ultrafast response of individual model nano-objects, either formed by a single particle (gold nanorod) or by two particles at a nanometric distance (gold-silver nano-dimer). Results obtained in gold nanorods are in excellent quantitative agreement with a model computing the change of the metal dielectric function due to ultrafast electron heating and relaxation. This shows that the nonlinear response of a metal nano-object can be fully described as that of the bulk metal enhanced by plasmonic effects. Extension of these studies to more complex nano-objects, as nano-dimers formed by two different materials, permits analysis of the impact of their interaction. We demonstrate here the existence of Fano effect in the absorption of a single Ag-Au dimer, experimentally proving previous theoretical predictions. Furthermore, we show that ultrafast pump-probe nonlinear spectroscopy permits to selectively address at nanoscale only

  2. Mechanical, Electrical, and Environmental Evaluation of Nano-Miniature Connectors

    SciTech Connect

    Hilton, J.W.

    2001-07-30

    Because of their small size (0.025-inch spacing), nano-miniature connectors have been chosen for JTA telemetry applications. At the time they were chosen, extensive testing had not been done to determine the mechanical, electrical, and environmental characteristics of these connectors at the levels required for use by weapon systems. Since nano-miniature connectors use some unique plating and wire crimping processes not used in most design agency connectors, it was decided that these properties should be tested thoroughly. This report describes the results of that testing.

  3. Requirements for printed wiring boards

    NASA Technical Reports Server (NTRS)

    1984-01-01

    In order to maintain the high standards of the NASA printed wiring programs, this publication: prescribes NASA's requirements for assuring reliable rigid printed wiring boards; describes and incorporates basic considerations necessary to assure reliable rigid printed wiring boards; establishes the supplier's responsibility to train and certify personnel; provides for supplier documentation of the fabrication and inspection procedures to be used for NASA work, including supplier innovations and changes in technology; and provides visual workmanship standards to aid those responsible for determining quality conformance to the established requirements.

  4. Demonstrating Forces between Parallel Wires.

    ERIC Educational Resources Information Center

    Baker, Blane

    2000-01-01

    Describes a physics demonstration that dramatically illustrates the mutual repulsion (attraction) between parallel conductors using insulated copper wire, wooden dowels, a high direct current power supply, electrical tape, and an overhead projector. (WRM)

  5. Method of manufacturing superconductor wire

    SciTech Connect

    Motowidlo, Leszek

    2014-09-16

    A method for forming Nb.sub.3Sn superconducting wire is provided. The method employs a powder-in-tube process using a high-tin intermetallic compound, such as MnSn.sub.2, for producing the Nb.sub.3Sn. The use of a high-tin intermetallic compound enables the process to perform hot extrusion without melting the high-tin intermetallic compound. Alternatively, the method may entail drawing the wire without hot extrusion.

  6. Smart Wire Grid: Resisting Expectations

    SciTech Connect

    Ramsay, Stewart; Lowe, DeJim

    2014-03-03

    Smart Wire Grid's DSR technology (Discrete Series Reactor) can be quickly deployed on electrical transmission lines to create intelligent mesh networks capable of quickly rerouting electricity to get power where and when it's needed the most. With their recent ARPA-E funding, Smart Wire Grid has been able to move from prototype and field testing to building out a US manufacturing operation in just under a year.

  7. Smart Wire Grid: Resisting Expectations

    ScienceCinema

    Ramsay, Stewart; Lowe, DeJim

    2014-04-09

    Smart Wire Grid's DSR technology (Discrete Series Reactor) can be quickly deployed on electrical transmission lines to create intelligent mesh networks capable of quickly rerouting electricity to get power where and when it's needed the most. With their recent ARPA-E funding, Smart Wire Grid has been able to move from prototype and field testing to building out a US manufacturing operation in just under a year.

  8. 30 CFR 75.701-4 - Grounding wires; capacity of wires.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Grounding wires; capacity of wires. 75.701-4... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Grounding § 75.701-4 Grounding wires; capacity of wires. Where grounding wires are used to ground metallic sheaths, armors, conduits,...

  9. 30 CFR 75.701-4 - Grounding wires; capacity of wires.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Grounding wires; capacity of wires. 75.701-4... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Grounding § 75.701-4 Grounding wires; capacity of wires. Where grounding wires are used to ground metallic sheaths, armors, conduits,...

  10. HTS Wire Development Workshop: Proceedings

    SciTech Connect

    Not Available

    1994-07-01

    The 1994 High-Temperature Superconducting Wire Development Workshop was held on February 16--17 at the St. Petersburg Hilton and Towers in St. Petersburg, Florida. The meeting was hosted by Florida Power Corporation and sponsored by the US Department of Energy`s Superconductivity Program for Electric Power Systems. The meeting focused on recent high-temperature superconducting wire development activities in the Department of Energy`s Superconductivity Systems program. The meeting opened with a general discussion on the needs and benefits of superconductivity from a utility perspective, the US global competitiveness position, and an outlook on the overall prospects of wire development. The meeting then focused on four important technology areas: Wire characterization: issues and needs; technology for overcoming barriers: weak links and flux pinning; manufacturing issues for long wire lengths; and physical properties of HTS coils. Following in-depth presentations, working groups were formed in each technology area to discuss the most important current research and development issues. The working groups identified research areas that have the potential for greatly enhancing the wire development effort. These areas are discussed in the summary reports from each of the working groups. This document is a compilation of the workshop proceedings including all general session presentations and summary reports from the working groups.

  11. 1 mil gold bond wire study.

    SciTech Connect

    Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

    2013-05-01

    In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

  12. The AgNORs.

    PubMed

    Derenzini, M

    2000-04-01

    The structure and the function of interphase AgNORs and the importance of the "AgNOR" parameter in tumor pathology have been reviewed. Interphase AgNORs are structural-functional units of the nucleolus in which all the components necessary for ribosomal RNA synthesis are located. Two argyrophilic proteins involved in rRNA transcription and processing, nucleolin and nucleophosmin, are associated with interphase AgNORs and are responsible for their stainability with silver methods, thus allowing interphase AgNORs to be visulaized at light microscopic level, also in routine cyto-histopathological preparations. The number of interphase AgNORs is strictly related to rRNA transcriptional activity and, in continuously proliferating cells, to the rapidity of cell proliferation. Evaluation of the quantitative distribution of interphase AgNORs has been applied in tumor pathology both for diagnostic and prognostic purposes. The "AgNOR" parameter has been proved to represent a reliable tool for defining the clinical outcome of cancer disease, being an independent prognostic factor in many types of tumors. PMID:10588056

  13. AgRISTARS

    NASA Technical Reports Server (NTRS)

    1984-01-01

    An introduction to the overall AgRISTARS program, a general statement on progress, and separate summaries of the activities of each project, with emphasis on the technical highlights are presented. Organizational and management information on AgRISTARS is included in the appendices, as is a complete bibliography of publication and reports.

  14. Fabrication of Pd-Cr wire

    NASA Technical Reports Server (NTRS)

    Diamond, Sidney; Leach, Dennen M.

    1989-01-01

    Fabrication of Pd-13 percent Cr alloy wires is described. Melting, casting, swaging and annealing processes are discussed. Drawing to reach two diameters (0.003 inch and 0.00176 inch) of wire is described. Representative micrographs of the Pd-Cr alloy at selected stages during wire fabrication are included. The resistance of the wire was somewhat lower, by about 15 to 20 percent, than comparable wire of other alloys used for strain gages.

  15. Experimental Results for Space-Wire-D

    NASA Astrophysics Data System (ADS)

    Parkes, Steve; Gibson, David; Ferrer, Albert

    2015-09-01

    SpaceWire-D is a deterministic extension to SpaceWire that uses time-division multiplexing to schedule traffic within time-slots. It allows a single SpaceWire network to be used for both time-critical avionics control applications and asynchronous payload data-handling simultaneously using existing SpaceWire technology. In this paper we describe the services of SpaceWire-D and present experimental results for each service.

  16. Connecting to Thermocouples with Fewer Lead Wires

    NASA Technical Reports Server (NTRS)

    Goldsby, Jon C.

    2003-01-01

    A simple technique has been devised to reduce the number of lead wires needed to connect an array of thermocouples to the instruments (e.g., voltmeters) used to read their output voltages. Because thermocouple wires are usually made of expensive metal alloys, reducing the number of lead wires can effect a considerable reduction in the cost of such an array. Reducing the number of wires also reduces the number of terminals and the amount of space needed to accommodate the wires.

  17. AGS experiments: 1993 - 1994 - 1995

    SciTech Connect

    Depken, J.C.

    1996-04-01

    This report contains: FY 1995 AGS Schedule as Run; FY 1996-97 AGE Schedule (working copy); AGS Beams 1995; AGS Experimental Area FY 1993 Physics Program; AGS Experimental Area FY 1994 Physics Program; AGS Experimental Area FY 1995 Physics Program; AGS Experimental Area FY 1996 Physics Program (In progress); A listing of experiments by number; Two-page summaries of each experiment begin here, also ordered by number; Listing of publications of AGS experiments begins here; and Listing of AGS experimenters begins here. This is the twelfth edition.

  18. Behavior of PET implanted by Ti, Ag, Si and C ion using MEVVA implantation

    NASA Astrophysics Data System (ADS)

    Wu, Yuguang; Zhang, Tonghe; Zhang, Yanwen; Zhang, Huixing; Zhang, Xiaoji; Zhou, Gu

    2001-01-01

    Polyethylene terephthalane (PET) has been modified with Ti, Ag, Si and C ions from a metal vapor arc source (MEVVA). Ti, Ag, Si and C ions were implanted with acceleration voltage 40 kV to fluences ranging from 1×10 16 to 2×10 17 cm -2. The surface of implanted PET darkened with increasing ion dose, when the metal ion dose was greater than 1×10 17 cm -2 the color changed to metallic bright. The surface resistance decreases by 5-6 orders of magnitude with increasing dose. The resistivity is stable after long-term storage. The depth of Ti- and Ag-implanted layer is approximately 150 and 80 nm measured by Rutherford backscattering (RBS), respectively. TEM photos revealed the presence of Ti and Ag nano-meter particles on the surface resulting from the high-dose implantation. Ti and Ag ion implantations improved conductivity and wear resistance significantly. The phase and structural changes were obtained by X-ray diffraction (XRD). It can be seen that nano-meter particles of Ti precipitation, TiO 2 and Ti-carbides have been formed in implanted layer. Nano-hardness of implanted PET has been measured by a nano-indenter. The results show that the surface hardness, modulus and wear resistance could be increased.

  19. The role of the local chemical environment of Ag on the resistive switching mechanism of conductive bridging random access memories.

    PubMed

    Souchier, E; D'Acapito, F; Noé, P; Blaise, P; Bernard, M; Jousseaume, V

    2015-10-01

    Conductive bridging random access memories (CBRAMs) are one of the most promising emerging technologies for the next generation of non-volatile memory. However, the lack of understanding of the switching mechanism at the nanoscale level prevents successful transfer to industry. In this paper, Ag/GeSx/W CBRAM devices are analyzed using depth selective X-ray Absorption Spectroscopy before and after switching. The study of the local environment around Ag atoms in such devices reveals that Ag is in two very distinct environments with short Ag-S bonds due to Ag dissolved in the GeSx matrix, and longer Ag-Ag bonds related to an Ag metallic phase. These experiments allow the conclusion that the switching process involves the formation of metallic Ag nano-filaments initiated at the Ag electrode. All these experimental features are well supported by ab initio molecular dynamics simulations showing that Ag favorably bonds to S atoms, and permit the proposal of a model at the microscopic level that can explain the instability of the conductive state in these Ag-GeSx CBRAM devices. Finally, the principle of the nondestructive method described here can be extended to other types of resistive memory concepts. PMID:26312954

  20. Single-molecule conductance in atomically precise germanium wires.

    PubMed

    Su, Timothy A; Li, Haixing; Zhang, Vivian; Neupane, Madhav; Batra, Arunabh; Klausen, Rebekka S; Kumar, Bharat; Steigerwald, Michael L; Venkataraman, Latha; Nuckolls, Colin

    2015-09-30

    While the electrical conductivity of bulk-scale group 14 materials such as diamond carbon, silicon, and germanium is well understood, there is a gap in knowledge regarding the conductivity of these materials at the nano and molecular scales. Filling this gap is important because integrated circuits have shrunk so far that their active regions, which rely so heavily on silicon and germanium, begin to resemble ornate molecules rather than extended solids. Here we unveil a new approach for synthesizing atomically discrete wires of germanium and present the first conductance measurements of molecular germanium using a scanning tunneling microscope-based break-junction (STM-BJ) technique. Our findings show that germanium and silicon wires are nearly identical in conductivity at the molecular scale, and that both are much more conductive than aliphatic carbon. We demonstrate that the strong donor ability of C-Ge σ-bonds can be used to raise the energy of the anchor lone pair and increase conductance. Furthermore, the oligogermane wires behave as conductance switches that function through stereoelectronic logic. These devices can be trained to operate with a higher switching factor by repeatedly compressing and elongating the molecular junction. PMID:26373928

  1. Mechanical properties of high-temperature superconducting wires. Ph.D. Thesis - Illinois Inst. of Tech.

    NASA Technical Reports Server (NTRS)

    Goretta, K. C.; Cluff, J. A.; Joo, J.; Lanagan, M. T.; Singh, J. P.; Vasanthamohan, N.; Xin, Y.; Wong, K. W.

    1995-01-01

    Bending strength, fracture toughness, and elastic modulus data were acquired for YBa2Cu3O(x), Bi2Sr2CaCu2O(x) (Bi,Pb)2Sr2Ca2Cu3O(x), and Tl2Ba2Ca2Cu3O(x) bars. These data and thermal expansion coefficients strongly suggest that the maximum possible tensile strain without fracture of bulk tapes or wires is approximately equals 0.2%. In Ag-clad conductors, residual stresses will be of limited benefit, but fractures produced by larger strains can be accommodated by shunting current through the Ag.

  2. The Nano-Micro Interface: Bridging the Micro and Nano Worlds

    NASA Astrophysics Data System (ADS)

    Fecht, Hans-Jörg; Werner, Matthias

    2003-09-01

    Two exciting worlds of science and technology - the nano and micro dimensions. The former is a booming new field of research, the latter the established size range for electronics, and for mutual technological benefit and future commercialization, suitable junctions need to be found. Functional nanostructures such as DNA computers, sensors, neural interfaces, nanooptics or molecular electronics need to be wired to their 'bigger' surroundings. Coming from the opposite direction, microelectronics have experienced an unprecedented miniaturization drive in the last decade, pushing ever further down through the micro size scale towards submicron circuitry. Bringing these two worlds together is a new interdisciplinary challenge for scientists and engineers alike - recognized and substantially funded by the European Commission and other major project initiators worldwide. This book offers a wide range of information from technologies to materials and devices as well as from research to administrative know-how collected by the editors from renowned key members of the nano/micro community.

  3. The Nano-Micro Interface: Bridging the Micro and Nano Worlds

    NASA Astrophysics Data System (ADS)

    Fecht, Hans-Jörg; Werner, Matthias

    2004-12-01

    Two exciting worlds of science and technology - the nano and micro dimensions. The former is a booming new field of research, the latter the established size range for electronics, and for mutual technological benefit and future commercialization, suitable junctions need to be found. Functional nanostructures such as DNA computers, sensors, neural interfaces, nanooptics or molecular electronics need to be wired to their 'bigger' surroundings. Coming from the opposite direction, microelectronics have experienced an unprecedented miniaturization drive in the last decade, pushing ever further down through the micro size scale towards submicron circuitry. Bringing these two worlds together is a new interdisciplinary challenge for scientists and engineers alike - recognized and substantially funded by the European Commission and other major project initiators worldwide. This book offers a wide range of information from technologies to materials and devices as well as from research to administrative know-how collected by the editors from renowned key members of the nano/micro community.

  4. Wire chambers revisited.

    PubMed

    Ott, R J

    1993-04-01

    Detectors used for radioisotope imaging have, historically, been based on scintillating crystal/photomultiplier combinations in various forms. From the rectilinear scanner through to modern gamma cameras and positron cameras, the basic technology has remained much the same. Efforts to overcome the limitations of this form of technology have foundered on the inability to reproduce the required sensitivity, spatial resolution and sensitive area at acceptable cost. Multiwire proportional chambers (MWPCs) have long been used as position-sensitive charged particle detectors in nuclear and high-energy physics. MWPCs are large-area gas-filled ionisation chambers in which large arrays of fine wires are used to measure the position of ionisation produced in the gas by the passage of charged particles. The important properties of MWPCs are high-spatial-resolution, large-area, high-count-rate performance at low cost. For research applications, detectors several metres square have been built and small-area detectors have a charged particle resolution of 0.4 mm at a count rate of several million per second. Modification is required to MWPCs for nuclear medicine imaging. As gamma rays or X-rays cannot be detected directly, they must be converted into photo- or Compton scatter electrons. Photon-electron conversion requires the use of high atomic number materials in the body of the chamber. Pressurised xenon is the most useful form of "gas only" photon-electron convertor and has been used successfully in a gamma camera for the detection of gamma rays at energies below 100 keV. This camera has been developed specifically for high-count-rate first-pass cardiac imaging. This high-pressure xenon gas MWPC is the key to a highly competitive system which can outperform scintillator-based systems. The count rate performance is close to a million counts per second and the intrinsic spatial resolution is better than the best scintillator-based camera. The MWPC camera produces quantitative

  5. Plasma arc torch with coaxial wire feed

    DOEpatents

    Hooper, Frederick M

    2002-01-01

    A plasma arc welding apparatus having a coaxial wire feed. The apparatus includes a plasma arc welding torch, a wire guide disposed coaxially inside of the plasma arc welding torch, and a hollow non-consumable electrode. The coaxial wire guide feeds non-electrified filler wire through the tip of the hollow non-consumable electrode during plasma arc welding. Non-electrified filler wires as small as 0.010 inches can be used. This invention allows precision control of the positioning and feeding of the filler wire during plasma arc welding. Since the non-electrified filler wire is fed coaxially through the center of the plasma arc torch's electrode and nozzle, the wire is automatically aimed at the optimum point in the weld zone. Therefore, there is no need for additional equipment to position and feed the filler wire from the side before or during welding.

  6. Morphological and electrochemical characterization of electrodeposited Zn–Ag nanoparticle composite coatings

    SciTech Connect

    Punith Kumar, M.K.; Srivastava, Chandan

    2013-11-15

    Silver nanoparticles with an average size of 23 nm were chemically synthesized and used to fabricate Zn–Ag composite coatings. The Zn–Ag composite coatings were generated by electrodeposition method using a simple sulfate plating bath dispersed with 0.5, 1 and 1.5 g/l of Ag nanoparticles. Scanning electron microscopy, X-ray diffraction and texture co-efficient calculations revealed that Ag nanoparticles appreciably influenced the morphology, micro-structure and texture of the deposit. It was also noticed that agglomerates of Ag nanoparticles, in the case of high bath load conditions, produced defects and dislocations on the deposit surface. Ag nanoparticles altered the corrosion resistance property of Zn–Ag composite coatings as observed from Tafel polarization, electrochemical impedance analysis and an immersion test. Reduction in corrosion rate with increased charge transfer resistance was observed for Zn–Ag composite coatings when compared to a pure Zn coating. However, the particle concentration in the plating bath and their agglomeration state directly influenced the surface morphology and the subsequent corrosion behavior of the deposits. - Highlights: • Synthesis of Ag nanoparticles with an average size of 23 nm • Fabrication of Zn/nano Ag composite coating on mild steel • Composite coatings showed better corrosion resistance. • Optimization of particle concentration is necessary.

  7. Ag/ZnO heterostructures and their photocatalytic activity under visible light: effect of reducing medium.

    PubMed

    Liu, Yangsi; Wei, Shanghai; Gao, Wei

    2015-04-28

    Decoration of ZnO by Ag is a promising method to improve its photocatalytic activity and extend the photoreactivity to the visible light. In this paper, Ag/ZnO heterostructures have been synthesised by photoreduction in various reducing mediums. When the Ag/ZnO nanocomposite arrays were obtained in the air, only a small amount of Ag was reduced. Ag nanosheets and nanoparticles were formed in the water and attached on the top and side surfaces of ZnO nanorods, forming Ag/ZnO heterostructures with a nano(sheet-rod-particle) multi-level structure. In the mixture of water and ethanol, a large amount of Ag nanoclusters was produced and embedded in the ZnO nanorod arrays. The influence of reducing mediums on the microstructure, morphology, quantity and dispersion of Ag nanostructures was investigated; and the effect of Ag component on the optical properties and visible light driven photocatalytic behaviour of the Ag/ZnO heterostructures was discussed. PMID:25621832

  8. Processing and properties of silver-clad Tl-Ba-Ca-Cu-O wires and tapes

    SciTech Connect

    Goretta, K.C.; Wu, C.T.; Lanagan, M.T.; Boling, M.A.; Shi, D.; Miller, D.J.; Chen, Nan; Hanewald, W.G.; Sengupta, S.; Wang, Z.; Poeppel, R.B.; Foong, F.; Liou, S.H.

    1992-03-01

    TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} and Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} powders were synthesized, loaded into Ag tubes, and worked into wires and tapes by drawing and rolling. All processing outside of furnaces was in a dry-N{sub 2} glovebox. All heat treatments were performed in O{sub 2}. The Ag-clad wires fabricated from these powders exhibited onset of superconductivity at {approx}118 K and critical current densities at 77K of 2{times}10{sup 3} to 4{times}10{sup 3} A/cm{sup 2}.

  9. Bi-2223/Ag HTS coil magnetic field properties for magnet and bias winding

    NASA Astrophysics Data System (ADS)

    Jin, J. X.; Grantham, C.; Liu, H. K.; Dou, S. X.

    1997-08-01

    Ag-clad (Bi,Pb)2Sr2Ca2Cu3O10+x high-Tc supercondicting (HTS) multifilament wire, is used to prepare a HTS coil. The magnetic field behaviour of the HTS coil is studied with respect to its critical current and magnetic field properties. The anisotropic HTS wire has strong magnetic field dependent critical current, which causes critical current degradation when used in the form of a coil. The HTS coil magnetic field is measured and its distribution is investigated. The experimental results and analysis provide basic information for the design of a magnet or bias winding with the Ag-clad (Bi,Pb)2Sr2Ca2Cu3O10+x HTS wire.

  10. Antenna coupled photonic wire lasers.

    PubMed

    Kao, Tsung-Yu; Cai, Xiaowei; Lee, Alan W M; Reno, John L; Hu, Qing

    2015-06-29

    Slope efficiency (SE) is an important performance metric for lasers. In conventional semiconductor lasers, SE can be optimized by careful designs of the facet (or the modulation for DFB lasers) dimension and surface. However, photonic wire lasers intrinsically suffer low SE due to their deep sub-wavelength emitting facets. Inspired by microwave engineering techniques, we show a novel method to extract power from wire lasers using monolithically integrated antennas. These integrated antennas significantly increase the effective radiation area, and consequently enhance the power extraction efficiency. When applied to wire lasers at THz frequency, we achieved the highest single-side slope efficiency (~450 mW/A) in pulsed mode for DFB lasers at 4 THz and a ~4x increase in output power at 3 THz compared with a similar structure without antennas. This work demonstrates the versatility of incorporating microwave engineering techniques into laser designs, enabling significant performance enhancements. PMID:26191717

  11. A nano lamella NbTi–NiTi composite with high strength

    SciTech Connect

    Jiang, Jiang; Jiang, Daqiang; Hao, Shijie; Yu, Cun; Zhang, Junsong; Ren, Yang; Lu, Deping; Xie, Shifang; Cui, Lishan

    2015-05-01

    A hypereutectic Nb60Ti24Ni16 (at%) alloy was prepared by vacuum induction melting, and a nano lamellae NbTi-NiTi composite was obtained by hot-forging and wire-drawing of the ingot Microscopic analysis showed that NbTi and NiTi nano lamellae distributed alternatively in the composite, and aligned along the wire axial direction, with a high volume fraction (similar to 70%) of NbTi nano lamellae. In situ synchrotron X-ray diffraction analysis revealed that stress induced martensitic transformation occurred upon loading, which would effectively weaken the stress concentration at the interface and avoid the introduction of defects into the nano reinforced phase. Then the embedded NbTi nano lamellae exhibited a high elastic strain up to 2.72%, 1.5 times as high as that of the Nb nanowires embedded in a conventional plastic matrix, and the corresponding stress carried by NbTi was evaluated as 2.53 GPa. The high volume fraction of NbTi nano lamellae improved the translation of high strength from the nano reinforced phase into bulk properties of the composite, with a platform stress of similar to 1.7 GPa and a fracture strength of similar to 1.9 GPa. (C) 2015 Elsevier B.V. All rights reserved.

  12. Egg White Templated Synthesis of Ag and Au@Ag Alloy Microspheres for Surface-Enhanced Raman Spectroscopy Research.

    PubMed

    Li, Min; Zhang, Ying; Wang, Xiansong; Cui, Daxiang

    2016-01-01

    Herein, we report the green synthesis of Ag and Au@Ag microspheres by using the aqueous extracts of the egg white as well as their application as substrates for surface-enhanced Raman spectroscopy (SERS) detection. Both microspheres are prepared via the green synthesis method (room temperature, in aqueous solution and a benign reducer). The as-prepared urchin-like Ag microspheres have an average diameter of 600-800 nm, which is made up of some nanopricks with an average length of 10-40 nm. Meanwhile, the Au@Ag architectures prepared by galvanic replacement keep nearly similar size, which is also composed of some compact nanoparticles with an average diameter of about 10-40 nm. These products are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electronic microscopy (TEM), and Fourier transform infrared spectrophotometer (FTIR). The study on SERS activities is also carried out for both microspheres. It is found that Au@Ag microspheres possess much higher SERS activity than Ag microspheres. Our work may shed light on the design and synthesis of self-assembled 3D micro/nano-architectures for the use of SERS, catalysis, biosensors, nanomedicine, etc. PMID:27398550

  13. Aluminum-matrix electrotechnical composite alloys hardened by endogenous nano- and microphases

    NASA Astrophysics Data System (ADS)

    Babkin, V. G.; Terent'ev, N. A.; Cherepanov, A. I.

    2014-09-01

    A method is developed to manufacture aluminum-matrix composite alloys hardened by endogenous nano- and microphases. The formation of the structure and properties of the composite materials is studied. The experimental results demonstrate that the developed alloys are promising to produce electro-technical wire rods and other electrotechnical products.

  14. Wire Detection Algorithms for Navigation

    NASA Technical Reports Server (NTRS)

    Kasturi, Rangachar; Camps, Octavia I.

    2002-01-01

    In this research we addressed the problem of obstacle detection for low altitude rotorcraft flight. In particular, the problem of detecting thin wires in the presence of image clutter and noise was studied. Wires present a serious hazard to rotorcrafts. Since they are very thin, their detection early enough so that the pilot has enough time to take evasive action is difficult, as their images can be less than one or two pixels wide. Two approaches were explored for this purpose. The first approach involved a technique for sub-pixel edge detection and subsequent post processing, in order to reduce the false alarms. After reviewing the line detection literature, an algorithm for sub-pixel edge detection proposed by Steger was identified as having good potential to solve the considered task. The algorithm was tested using a set of images synthetically generated by combining real outdoor images with computer generated wire images. The performance of the algorithm was evaluated both, at the pixel and the wire levels. It was observed that the algorithm performs well, provided that the wires are not too thin (or distant) and that some post processing is performed to remove false alarms due to clutter. The second approach involved the use of an example-based learning scheme namely, Support Vector Machines. The purpose of this approach was to explore the feasibility of an example-based learning based approach for the task of detecting wires from their images. Support Vector Machines (SVMs) have emerged as a promising pattern classification tool and have been used in various applications. It was found that this approach is not suitable for very thin wires and of course, not suitable at all for sub-pixel thick wires. High dimensionality of the data as such does not present a major problem for SVMs. However it is desirable to have a large number of training examples especially for high dimensional data. The main difficulty in using SVMs (or any other example-based learning

  15. Mechanical properties and in vitro characterization of polyvinyl alcohol-nano-silver hydrogel wound dressings

    PubMed Central

    Oliveira, R. N.; Rouzé, R.; Quilty, B.; Alves, G. G.; Soares, G. D. A.; Thiré, R. M. S. M.; McGuinness, G. B.

    2014-01-01

    Polyvinyl alcohol (PVA) hydrogels are materials for potential use in burn healing. Silver nanoparticles can be synthesized within PVA hydrogels giving antimicrobial hydrogels. Hydrogels have to be swollen prior to their application, and the common medium available for that in hospitals is saline solution, but the hydrogel could also take up some of the wound's fluid. This work developed gamma-irradiated PVA/nano-Ag hydrogels for potential use in burn dressing applications. Silver nitrate (AgNO3) was used as nano-Ag precursor agent. Saline solution, phosphate-buffered solution (PBS) pH 7.4 and solution pH 4.0 were used as swelling media. Microstructural evaluation revealed an effect of the nanoparticles on PVA crystallization. The swelling of the PVA-Ag samples in solution pH 4.0 was low, as was their silver delivery, compared with the equivalent samples swollen in the other media. The highest swelling and silver delivery were related to samples prepared with 0.50% AgNO3, and they also presented lower strength in PBS pH 7.4 and solution pH 4.0. Both PVA-Ag samples were also non-toxic and presented antimicrobial activity, confirming that 0.25% AgNO3 concentration is sufficient to establish an antimicrobial effect. Both PVA-Ag samples presented suitable mechanical and swelling properties in all media, representative of potential burn site conditions. PMID:24501677

  16. Magnetic studies of silico-phosphate glass-ceramics containing Ag and iron oxide

    NASA Astrophysics Data System (ADS)

    Sharma, K.; Prajapat, C. L.; Singh, M. R.; Kothiyal, G. P.

    2013-02-01

    The magnetic properties of 25SiO2-(50-x)CaO-15P2O5-8Fe2O3-2ZnO-xAg (where x = 0, 2 and 4 mol %) glass-ceramics have been studied. The microstructure as seen by scanning electron microscopy (SEM) exhibits formation of nano size particles. Magnetic studies revealed an increase in saturation magnetization with addition of 4 mol % Ag. Increase in Ag content also results in increase in the strength of magnetic interactions.

  17. Production of Oxidation-Resistant Cu-Based Nanoparticles by Wire Explosion

    PubMed Central

    Kawamura, Go; Alvarez, Samuel; Stewart, Ian E.; Catenacci, Matthew; Chen, Zuofeng; Ha, Yoon-Cheol

    2015-01-01

    The low performance or high cost of commercially available conductive inks limits the advancement of printed electronics. This article studies the explosion of metal wires in aqueous solutions as a simple, low-cost, and environmentally friendly method to prepare metallic nanoparticles consisting of Cu and Cu alloys for use in affordable, highly conductive inks. Addition of 0.2 M ascorbic acid to an aqueous explosion medium prevented the formation of Cu2O shells around Cu nanoparticles, and allowed for the printing of conductive lines directly from these nanoparticles with no post-treatment. Cu alloy nanoparticles were generated from metal wires that were alloyed as purchased, or from two wires of different metals that were twisted together. Cu nanoparticles alloyed with 1% Sn, 5% Ag, 5% Ni and 30% Ni had electrical conductivities similar to Cu but unlike Cu, remained conductive after 24 hrs at 85 °C and 85% RH. PMID:26669447

  18. Production of Oxidation-Resistant Cu-Based Nanoparticles by Wire Explosion

    NASA Astrophysics Data System (ADS)

    Kawamura, Go; Alvarez, Samuel; Stewart, Ian E.; Catenacci, Matthew; Chen, Zuofeng; Ha, Yoon-Cheol

    2015-12-01

    The low performance or high cost of commercially available conductive inks limits the advancement of printed electronics. This article studies the explosion of metal wires in aqueous solutions as a simple, low-cost, and environmentally friendly method to prepare metallic nanoparticles consisting of Cu and Cu alloys for use in affordable, highly conductive inks. Addition of 0.2 M ascorbic acid to an aqueous explosion medium prevented the formation of Cu2O shells around Cu nanoparticles, and allowed for the printing of conductive lines directly from these nanoparticles with no post-treatment. Cu alloy nanoparticles were generated from metal wires that were alloyed as purchased, or from two wires of different metals that were twisted together. Cu nanoparticles alloyed with 1% Sn, 5% Ag, 5% Ni and 30% Ni had electrical conductivities similar to Cu but unlike Cu, remained conductive after 24 hrs at 85 °C and 85% RH.

  19. Spatial and temporal variation of surface-enhanced Raman scattering at Ag nanowires in aqueous solution

    SciTech Connect

    Clayton, Daniel A.; McPherson, Tyler; Pan, Shanlin; Chen, Mingyang; Dixon, David A.; Hu, Dehong

    2012-12-13

    We present surface enhanced Raman spectroscopy (SERS) and Raman imaging of small organic molecules at well-defined nanostructures formed by single silver nanowires (NWs). We show that SERS can be obtained at single, crossed, and bundled Ag NWs for mercaptopyridine, adenine, cytosine, guanine, and thymine. Crossed wires and parallel Ag NWs have SERS enhancement factors much higher than single Ag NWs. New additional junctions formed by a silver nanoparticle and a single Ag NW, and bundled NWs provide SERS intensity higher than a single Ag NW. The SERS signal of single Ag NWs can be further enhanced by decorating the Ag NW surface with gold nanoparticles using electroless deposition. Single Ag NW Raman imaging with a 10 ms time resolution when compared with photoluminescence (PL) imaging results reveal a different dynamic response of SERS and PL under steady state laser excitation. Dynamic photoluminescence blinking activities are suppressed in the presence of the surface coating of Raman active molecules (e.g., mercaptopyridine) and the SERS signal is quite stable in a wide field excitation configuration. The Discrete Dipole Approximation (DDA) method was used to calculate the local field intensity that can be applied to help understand the enhanced PL and SERS at the junction of Ag NWs

  20. Anode wire aging tests with selected gases

    SciTech Connect

    Kadyk, J.; Wise, J.; Hess, D.; Williams, M. )

    1990-04-01

    As a continuation of earlier wire aging investigations, additional candidates for wire chamber gas and wire have been tested. These include the gases: argon/ethane, HRS gas, dimethyl ether, carbon dioxide/ethane, and carbon tetrafluoride/isobutane. Wires used were: gold- plated tungsten, Stablohm, Nicotin, and Stainless Steel. Measurements were made of the effects upon wire aging of impurities from plumbing materials or contamination from various types of oil. Attempts were made to induce wire aging by adding measured amounts of oxygen and halogen (methyl chloride) with negative results. In this paper, the possible role of electronegativity in the wire aging process is discussed, and measurements of electronegativity are made with several single carbon Freons, using both an electron capture detector and a wire chamber operating with dimethyl ether.

  1. Electrical wire insulation and electromagnetic coil

    DOEpatents

    Bich, George J.; Gupta, Tapan K.

    1984-01-01

    An electromagnetic coil for high temperature and high radiation application in which glass is used to insulate the electrical wire. A process for applying the insulation to the wire is disclosed which results in improved insulation properties.

  2. Quality control of microelectronic wire bonds

    NASA Technical Reports Server (NTRS)

    Thiel, R. A.; Schmidt, G. D.

    1975-01-01

    Report evaluates ultrasonic bonding of small-diameter aluminum wire joined to ceramic substrates metalized with thin-film and thick-film gold. Quick testing technique for nondestructive location of poor wire bonds is also presented.

  3. Put Your Cable Wiring to the Test.

    ERIC Educational Resources Information Center

    Day, C. William

    2001-01-01

    Discusses why schools and universities should use testing procedures in any wire bid specification for cable wiring and also know how experienced the installers are in testing and installing structured cabling systems. Key cabling terms are included. (GR)

  4. New insulation constructions for aerospace wiring applications

    NASA Technical Reports Server (NTRS)

    Slenski, George

    1994-01-01

    Outlined in this presentation is the background to insulation constructions for aerospace wiring applications, the Air Force wiring policy, the purpose and contract requirements of new insulation constructions, the test plan, and the test results.

  5. A manually set magnetic wire counter

    NASA Technical Reports Server (NTRS)

    1972-01-01

    Magnetic storage wire counter design principles are given. Magnetic storage wire was coupled with two phase propagational driver in manual set counter shift register. Time delay between magnetic counter domain insertion and corresponding output pulse provides counting functions.

  6. Technique for stripping Teflon insulated wire

    NASA Technical Reports Server (NTRS)

    Babb, B. D.

    1967-01-01

    Cryogenic stripping of Teflon insulated wire leaves no residue and produces no physical damage. After the wire is immersed in liquid nitrogen, bent slightly, and returned to room temperature, the Teflon is removed by fingernails or flat-nosed pliers.

  7. Wire Capture Programs for Macintosh and IBM.

    ERIC Educational Resources Information Center

    Wiley, Gale

    1989-01-01

    Discusses wire capture programs (computer programs which gather and process wire services such as the Associated Press or United Press) for computer labs in journalism departments. Describes details of such programs for Macintosh, IBM, and IBM clones. (SR)

  8. Electrical Wire Insulation and Electromagnetic Coil

    SciTech Connect

    Bich, G. J.; Gupta, T. K.

    1984-01-31

    An electromagnetic coil for high temperature and high radiation application in which glass is used to insulate the electrical wire. A process for applying the insulation to the wire is disclosed which results in improved insulation properties.

  9. Sustainable nano-catalysis

    EPA Science Inventory

    A novel nano-catalyst system which bridges the homogenous and heterogeneous system is described that is cheaper, easily accessible (sustainable) and requires no need of catalyst filtration during the work-up. Because of its nano-size, i.e. high surface area, the contact between r...

  10. Improved galvanic replacement growth of Ag microstructures on Cu micro-grid for enhanced SERS detection of organic molecules.

    PubMed

    Guo, Tian-Long; Li, Ji-Guang; Sun, Xudong; Sakka, Yoshio

    2016-04-01

    Galvanic growth of Ag nano/micro-structures on Cu micro-grid was systematically studied for surface-enhanced Raman scattering (SERS) applications. Detailed characterizations via FE-SEM and HR-TEM showed that processing parameters, (reaction time, Ag(+) concentration, and PVP addition) all substantially affect thermodynamics/kinetics of the replacement reaction to yield substrates of significantly different microstructures/homogeneities and thus varied SERS performances (sensitivity, enhancement factor, and reproducibility) of the Ag substrates in the detection of R6G analyte. PVP as an additive was shown to notably alter nucleation/growth behaviors of the Ag crystals and promote the deposition of dense and uniform Ag films of nearly monodisperse polyhedrons/nanoplates through suppressing dendrites crystallization. Under optimized synthesis (50mM of Ag(+), 30s of reaction, and 700 wt.% of PVP), Ag substrates exhibiting a high Raman signal enhancement factor of ~1.1 × 10(6) and a low relative standard deviation of ~0.13 in the repeated detection of 10 μM R6G were obtained. The facile deposition and excellent performance reported in this work may allow the Ag microstructures to find wider SERS applications. Moreover, growth mechanisms of the different Ag nano/micro-structures were discussed based on extensive FE-SEM and HR-TEM analysis. PMID:26838829

  11. REACH. Residential Electrical Wiring Units.

    ERIC Educational Resources Information Center

    Ansley, Jimmy; Ennis, Mike

    As a part of the REACH (Refrigeration, Electro-Mechanical, Air-Conditioning, Heating) electromechanical cluster, this student manual contains individualized instructional units in the area of residential electrical wiring. The instructional units focus on grounded outlets, service entrance, and blueprint reading. Each unit follows a typical format…

  12. Flexible substrate for printed wiring

    NASA Technical Reports Server (NTRS)

    Asakura, M.; Yabe, K.; Tanaka, H.; Soda, A.

    1982-01-01

    A very flexible substrate for printed wiring is disclosed which is composed of a blend of phenoxy resin-polyisocyanate-brominated epoxy resin in which the equivalent ration of the functional groups is hydroxyl grouped: isocyanate group: epoxy group = 1:0.2 to 2:0.5 to 3. The product has outstanding solder resistance and is applied to metal without using adhesives.

  13. Health care's 100 most wired.

    PubMed

    Solovy, A; Serb, C

    1999-02-01

    They're wired all right, and America's 100 most techno-savvy hospitals and health systems share one more thing: a commitment to using technology to link with employees, patients, suppliers, and insurers. "We want to be a health care travel agency for our community," says one chief information officer. "And we see Internet technology as a key." PMID:10081454

  14. Regeneration: New Neurons Wire Up.

    PubMed

    Raymond, Pamela A

    2016-09-12

    Functional repair of damage in the nervous system requires re-establishment of precise patterns of synaptic connectivity. A new study shows that after selective ablation, zebrafish retinal neurons regenerate and reconstruct some, although not all, of their stereotypic wiring. PMID:27623258

  15. Fabrication of tungsten wire needles

    SciTech Connect

    Roder, A.

    1983-02-01

    Fine point needles for field emissoin are conventionally produced by electrolytically or chemically etching tungsten wire. Points formed in this manner have a typical tip radius of about 0.5 microns and a cone angle of some 30 degrees. The construction of needle matrix detector chambers has created a need for tungsten needles whose specifications are: 20 mil tungsten wire, 1.5 inch total length, 3 mm-long taper (resulting in a cone angle of about 5 degrees), and 25 micron-radius point (similar to that found on sewing needles). In the process described here for producing such needles, tungsten wire, immersed in a NaOH solution and in the presence of an electrode, is connected first to an ac voltage and then to a dc supply, to form a taper and a point on the end of the wire immersed in the solution. The process parameters described here are for needles that will meet the above specifications. Possible variations will be discussed under each approprite heading.

  16. Plated wire random access memories

    NASA Technical Reports Server (NTRS)

    Gouldin, L. D.

    1975-01-01

    A program was conducted to construct 4096-work by 18-bit random access, NDRO-plated wire memory units. The memory units were subjected to comprehensive functional and environmental tests at the end-item level to verify comformance with the specified requirements. A technical description of the unit is given, along with acceptance test data sheets.

  17. Wire-Wrap Chatter Detector

    NASA Technical Reports Server (NTRS)

    Fisch, G. Z.; Borden, T. J.

    1982-01-01

    Monitoring circuit responds to changes in resistance as little as 0.1 ohm. Has been used to detect defective wire-wrap connections during thermal and vibration tests. Defect is indicated to operator by light-emitting diode and by increase in count on a two-digit display.

  18. Ultrasonic Calibration Wire Test Phantom

    SciTech Connect

    Lehman, S K; Fisher, K A; Werve, M; Chambers, D H

    2004-09-24

    We designed and built a phantom consisting of vertical wires maintained under tension to be used as an ultrasonic test, calibration, and reconstruction object for the Lawrence Livermore National Laboratory annular array scanner. We provide a description of the phantom, present example data sets, preliminary reconstructions, example metadata, and MATLAB codes to read the data.

  19. Transport Through Carbon Nanotube Wires

    NASA Technical Reports Server (NTRS)

    Anantram, M. P.; Kwak, Dochan (Technical Monitor)

    2001-01-01

    This viewgraph presentation deals with the use of carbon nanotubes as a transport system. Contact, defects, tubular bend, phonons, and mechanical deformations all contribute to reflection within the nanotube wire. Bragg reflection, however, is native to an ideal energy transport system. Transmission resistance depends primarily on the level of energy present. Finally, the details regarding coupling between carbon nanotubes and simple metals are presented.

  20. Novel Wiring Technologies for Aerospace Applications

    NASA Technical Reports Server (NTRS)

    Gibson, Tracy L.; Parrish, Lewis M.

    2014-01-01

    Because wire failure in aerospace vehicles could be catastrophic, smart wiring capabilities have been critical for NASA. Through the years, researchers at Kennedy Space Center (KSC) have developed technologies, expertise, and research facilities to meet this need. In addition to aerospace applications, NASA has applied its knowledge of smart wiring, including self-healing materials, to serve the aviation industry. This webinar will discuss the development efforts of several wiring technologies at KSC and provide insight into both current and future research objectives.

  1. Further Studies Of Hot-Wire Anemometry

    NASA Technical Reports Server (NTRS)

    Mckenzie, Robert; Logan, Pamela; Bershader, Daniel

    1990-01-01

    Report discusses factors affecting readings of hot-wire anemometer in turbulent supersonic boundary layer. Represents extension of work described in "Hot-Wire Anemometry Versus Laser-Induced Fluorescence" (ARC-11802). Presents theoretical analysis of responses of hot-wire probe to changes in flow; also compares measurements by hot-wire probe with measurements of same flows by laser-induced fluorescence (LIF).

  2. Different mechanical properties in Seldinger guide wires

    PubMed Central

    Schummer, Wolfram

    2015-01-01

    Background and Aims: Most central venous catheters are placed using Seldinger guide wires. EN ISO 11070 is the guideline for testing guide wire flexing performance and tensile strength, and we can safely assume that guide wires in use meet these requirements. Unfortunately, EN ISO 11070 guidelines do not reflect the clinical requirements and we continue to see mechanical failures and their associated complications. Material and Methods: This in vitro study was performed in an accredited laboratory. With regard to flexing, we: (1) Established the minimum flexing performance needed to meet clinical requirements, (2) developed flexing performance tests which mimic clinical requirement, and (3) evaluated the mechanical properties of various guide wires relative to these requirements. With regard to tensile strength, we used the testing method prescribed in ISO 11070, but did not end the test at 5 Newton (N). We continued until the guide wire was damaged, or we reached maximum tractive force. We then did a wire-to-wire comparison. We examined two basic wire constructions, monofil and core and coil. Results: Tensile strength: All wires tested, except one, met EN ISO 11070 requirements for 5 N tensile strength. The mean of the wire types tested ranged from 15.06 N to 257.76 N. Flexing performance: None of the wires kinked. The monofil had no evidence of bending. Two core/coil wires displayed minor bending (angle 1.5°). All other wires displayed bending angles between 22.5° and 43.0°. Conclusion: We recommend that: (1) Clinicians use guide wires with high-end mechanical properties, (2) EN ISO 11070 incorporate our flexing test into their testing method, raise the flexing requirement to kink-proof, (3) and raise the tensile strength requirement to a minimum of 30 N, and (3) all manufacturers and suppliers be required to display mechanical properties of all guide wire, and guide wire kits sold. PMID:26702209

  3. NEMA wire and cable standards development programs

    NASA Technical Reports Server (NTRS)

    Baird, Robert W.

    1994-01-01

    The National Electrical Manufacturers Association (NEMA) is the nation's largest trade association for manufacturers of electrical equipment. Its member companies produce components, end-use equipment and systems for the generation, transmission, distribution, control and use of electricity. The wire and cable division is presented in 6 sections: building wire and cable, fabricated conductors, flexible cords, high performance wire and cable, magnet wire, and power and control cable. Participating companies are listed.

  4. Antifungal Effects of Silver Nanoparticles (AgNPs) against Various Plant Pathogenic Fungi

    PubMed Central

    Kim, Sang Woo; Jung, Jin Hee; Lamsal, Kabir; Kim, Yun Seok; Min, Ji Seon

    2012-01-01

    This research is concerned with the fungicidal properties of nano-size silver colloidal solution used as an agent for antifungal treatment of various plant pathogens. We used WA-CV-WA13B, WA-AT-WB13R, and WA-PR-WB13R silver nanoparticles (AgNPs) at concentrations of 10, 25, 50, and 100 ppm. Eighteen different plant pathogenic fungi were treated with these AgNPs on potato dextrose agar (PDA), malt extract agar, and corn meal agar plates. We calculated fungal inhibition in order to evaluate the antifungal efficacy of silver nanoparticles against pathogens. The results indicated that AgNPs possess antifungal properties against these plant pathogens at various levels. Treatment with WA-CV-WB13R AgNPs resulted in maximum inhibition of most fungi. Results also showed that the most significant inhibition of plant pathogenic fungi was observed on PDA and 100 ppm of AgNPs. PMID:22783135

  5. Formation of DNA-network embedding ferromagnetic Cobalt nano-particles

    NASA Astrophysics Data System (ADS)

    Kanki, Teruo; Tanaka, Hidekazu; Shirakawa, Hideaki; Sacho, Yu; Taniguchi, Masateru; Lee, Hea-Yeon; Kawai, Tomoji; Kang, Nam-Jung; Chen, Jinwoo

    2002-03-01

    Formation of DNA-network embedding ferromagnetic Cobalt nano-particles T. Kanki, Hidekazu. Tanaka, H. Shirakawa, Y. Sacho, M. Taniguchi, H. Lee, T. Kawai The Institute of Scientific and Industrial Research, Osaka University, Japan and Nam-Jung Kang, Jinwoo Chen Korea Advanced Institute of Science and Technology (KAIST), Korea DNA can be regarded as a naturally occurring and highly specific functional biopolymer and as a fine nano-wire. Moreover, it was found that large-scale DNA networks can be fabricated on mica surfaces. By using this network structure, we can expect to construct nano-scale assembly of functional nano particle, for example ferromagnetic Co nano particles, toward nano scale spin-electronics based on DNA circuits. When we formed DNA network by 250mg/ml DNA solution of poly(dG)-poly(dC) including ferromagnetic Co nano particles (diameter of 12nm), we have conformed the DNA network structure embedding Co nano-particles (height of about 12nm) by atomic force microscopy. On the other hand, we used 100mg/ml DNA solution, DNA can not connect each other, and many Co nano-particles exist without being embedded.

  6. 30 CFR 75.906 - Trailing cables for mobile equipment, ground wires, and ground check wires.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Trailing cables for mobile equipment, ground wires, and ground check wires. 75.906 Section 75.906 Mineral Resources MINE SAFETY AND HEALTH..., ground wires, and ground check wires. Trailing cables for mobile equipment shall contain one or...

  7. 30 CFR 75.906 - Trailing cables for mobile equipment, ground wires, and ground check wires.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Trailing cables for mobile equipment, ground wires, and ground check wires. 75.906 Section 75.906 Mineral Resources MINE SAFETY AND HEALTH..., ground wires, and ground check wires. Trailing cables for mobile equipment shall contain one or...

  8. 30 CFR 75.906 - Trailing cables for mobile equipment, ground wires, and ground check wires.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Trailing cables for mobile equipment, ground wires, and ground check wires. 75.906 Section 75.906 Mineral Resources MINE SAFETY AND HEALTH..., ground wires, and ground check wires. Trailing cables for mobile equipment shall contain one or...

  9. 30 CFR 75.906 - Trailing cables for mobile equipment, ground wires, and ground check wires.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Trailing cables for mobile equipment, ground wires, and ground check wires. 75.906 Section 75.906 Mineral Resources MINE SAFETY AND HEALTH..., ground wires, and ground check wires. Trailing cables for mobile equipment shall contain one or...

  10. 30 CFR 75.906 - Trailing cables for mobile equipment, ground wires, and ground check wires.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Trailing cables for mobile equipment, ground wires, and ground check wires. 75.906 Section 75.906 Mineral Resources MINE SAFETY AND HEALTH..., ground wires, and ground check wires. Trailing cables for mobile equipment shall contain one or...

  11. 49 CFR 236.838 - Wire, shunt.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Wire, shunt. 236.838 Section 236.838 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION... Wire, shunt. A wire forming part of a shunt circuit....

  12. 30 CFR 57.12047 - Guy wires.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Guy wires. 57.12047 Section 57.12047 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Electricity Surface and Underground § 57.12047 Guy wires. Guy wires of...

  13. Getting "Wired" for McLuhan's Cyberculture.

    ERIC Educational Resources Information Center

    McMurdo, George

    1995-01-01

    Examines the introduction of the computing magazine, "Wired", into the United Kingdom's (UK) market. Presents conversations with the founder and editorial staff of the UK edition, and discusses the accessibility of "Wired" via the World Wide Web. Describes 10 articles from United States "Wired" back-issues and presents critiques of a utopian…

  14. 49 CFR 393.28 - Wiring systems.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 5 2010-10-01 2010-10-01 false Wiring systems. 393.28 Section 393.28 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL MOTOR CARRIER SAFETY... NECESSARY FOR SAFE OPERATION Lamps, Reflective Devices, and Electrical Wiring § 393.28 Wiring...

  15. Home and School Technology: Wired versus Wireless.

    ERIC Educational Resources Information Center

    Van Horn, Royal

    2001-01-01

    Presents results of informal research on smart homes and appliances, structured home wiring, whole-house audio/video distribution, hybrid cable, and wireless networks. Computer network wiring is tricky to install unless all-in-one jacketed cable is used. Wireless phones help installers avoid pre-wiring problems in homes and schools. (MLH)

  16. Synthesis of supported silver nano-spheres on zinc oxide nanorods for visible light photocatalytic applications

    SciTech Connect

    Saoud, Khaled; Alsoubaihi, Rola; Bensalah, Nasr; Bora, Tanujjal; Bertino, Massimo; Dutta, Joydeep

    2015-03-15

    Highlights: • Synthesis of supported Ag NPs on ZnO nanorods using open vessel microwave reactor. • Use of the Ag/ZnO NPs as an efficient visible light photocatalyst. • Complete degradation of methylene blue in 1 h with 0.5 g/L Ag/ZnO NPs. - Abstract: We report the synthesis of silver (Ag) nano-spheres (NS) supported on zinc oxide (ZnO) nanorods through two step mechanism, using open vessel microwave reactor. Direct reduction of ZnO from zinc nitrates was followed by deposition precipitation of the silver on the ZnO nanorods. The supported Ag/ZnO nanoparticles were then characterized by electron microscopy, X-ray diffraction, FTIR, photoluminescence and UV–vis spectroscopy. The visible light photocatalytic activity of Ag/ZnO system was investigated using a test contaminant, methylene blue (MB). Almost complete removal of MB in about 60 min for doses higher than 0.5 g/L of the Ag/ZnO photocatalyst was achieved. This significant improvement in the photocatalytic efficiency of Ag/ZnO photocatalyst under visible light irradiation can be attributed to the presence of Ag nanoparticles on the ZnO nanoparticles which greatly enhances absorption in the visible range of solar spectrum enabled by surface plasmon resonance effect from Ag nanoparticles.

  17. Study on the Synthesis and Characterization of Nano Silver Loaded ZSM-5 Zeolite for Bacterial Elimination.

    PubMed

    Nam, Le Thi Hoai; Vinh, Tran Quang; Loan, Nguyen Thi Thanh; Nhiem, Nguyen Thi; Trang, Nguyen Thi Thu; Tan, Nguyen Minh; Radnik, Jörg

    2015-09-01

    The synthesis of nano silver coated ZSM-5 zeolite (Ag/ZSM-5) by ion exchange method combined with anaerobic thermal treatment and its bacterial elimination performance were studied. The various Ag content of different samples was analysed by atomic absorption spectroscopy method. The Ag/ZSM-5 sample with 0.251 wt% Ag (denoted as ZAg3) was characterized by using atomic absorption spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and pulsed CO chemisorption methods. The results showed that silver nanoparticles with a small nano-size of 2-3 nm were formed and distributed on the surface of ZSM-5 zeolite with a dispersion value of 59%. The samples denoted as ZAg1, ZAg2, ZAg3, ZAg4 correspond to a Ag content of 0.064; 0.128; 0.251; 0.253 wt% Ag. In the evaluation series, after 10 min of contact time between bacterial and Ag/ZSM-5, over 99% of E.coli (initial concentration was 10(6) cfu/ml) could be eliminated by Ag/ZSM-5 with the Ag content of at least 0.251 wt% (ZAg3). In addition, over 99% of Coliform (initial concentration was 10(5) cfu/ml) could be eliminated by Ag/ZSM-5 with Ag content of at least 0.128 wt% (ZAg2). In a further evaluation series varying the contact time, ZAg3 sample could eliminate over 99% and 100% of Ecoli after 10 min and 60 min, respectively (initial concentrations of both E.coli and Coliform were 10(5) cfu/ml). In addition, it could eliminate 100% of Coliform in only 10 min of contact time. PMID:26716323

  18. Galvanic Corrosion of and Ion Release from Various Orthodontic Brackets and Wires in a Fluoride-containing Mouthwash

    PubMed Central

    Tahmasbi, Soodeh; Ghorbani, Mohammad; Masudrad, Mahdis

    2015-01-01

    Background and aims. This study compared the galvanic corrosion of orthodontic wires and brackets from various manufacturers following exposure to a fluoride mouthwash. Materials and methods. This study was conducted on 24 lower central incisor 0.022" Roth brackets of four different commercially available brands (Dentaurum, American Orthodontics, ORJ, Shinye). These brackets along with stainless steel (SS) or nickel-titanium (NiTi) orthodontic wires (0.016", round) were immersed in Oral-B mouthwash containing 0.05% sodium fluoride for 28 days. The electric potential (EP) difference of each bracket-wire couple was measured with a Saturated Calomel Reference Electrode (Ag/AgCl saturated with KCl) via a voltmeter. The ions released in the electrolyte weremeasured with an atomic absorption spectrometer. All the specimens were assessed under a stereomicroscope and specimens with corrosion were analyzed with scanning electron microscopy (SEM). Data were analyzed using ANOVA. Results. The copper ions released from specimens with NiTi wire were greater than those of samples containing SS wire. ORJ brackets released more Cu ions than other samples. The Ni ions released from Shinye brackets were significantly more than those of other specimens (P < 0.05). Corrosion rate of brackets coupled with NiTi wires was higher than that of brackets coupled with SS wires. Light and electron microscopic observations showed greater corrosion of ORJ brackets. Conclusion. In fluoride mouthwash, Shinye and ORJ brackets exhibited greater corrosion than Dentaurum and American Orthodontics brackets. Stainless steel brackets used with NiTi wires showed greater corrosion and thus caution is recommended when using them. PMID:26697148

  19. Galvanic Corrosion of and Ion Release from Various Orthodontic Brackets and Wires in a Fluoride-containing Mouthwash.

    PubMed

    Tahmasbi, Soodeh; Ghorbani, Mohammad; Masudrad, Mahdis

    2015-01-01

    Background and aims. This study compared the galvanic corrosion of orthodontic wires and brackets from various manufacturers following exposure to a fluoride mouthwash. Materials and methods. This study was conducted on 24 lower central incisor 0.022" Roth brackets of four different commercially available brands (Dentaurum, American Orthodontics, ORJ, Shinye). These brackets along with stainless steel (SS) or nickel-titanium (NiTi) orthodontic wires (0.016", round) were immersed in Oral-B mouthwash containing 0.05% sodium fluoride for 28 days. The electric potential (EP) difference of each bracket-wire couple was measured with a Saturated Calomel Reference Electrode (Ag/AgCl saturated with KCl) via a voltmeter. The ions released in the electrolyte weremeasured with an atomic absorption spectrometer. All the specimens were assessed under a stereomicroscope and specimens with corrosion were analyzed with scanning electron microscopy (SEM). Data were analyzed using ANOVA. Results. The copper ions released from specimens with NiTi wire were greater than those of samples containing SS wire. ORJ brackets released more Cu ions than other samples. The Ni ions released from Shinye brackets were significantly more than those of other specimens (P < 0.05). Corrosion rate of brackets coupled with NiTi wires was higher than that of brackets coupled with SS wires. Light and electron microscopic observations showed greater corrosion of ORJ brackets. Conclusion. In fluoride mouthwash, Shinye and ORJ brackets exhibited greater corrosion than Dentaurum and American Orthodontics brackets. Stainless steel brackets used with NiTi wires showed greater corrosion and thus caution is recommended when using them. PMID:26697148

  20. Surface Degradation of Ag/W Circuit Breaker Contacts During Standardized UL Testing

    NASA Astrophysics Data System (ADS)

    Yu, Haibo; Sun, Yu; Kesim, M. Tumerkan; Harmon, Jason; Potter, Jonathan; Alpay, S. Pamir; Aindow, Mark

    2015-09-01

    The near-surface microstructure of Ag/W contacts from 120 V, 30 A commercial circuit breakers in the as-manufactured condition and after standardized UL overload/temperature-rise, endurance, and short-circuit testing have been investigated using a combination of x-ray diffraction, scanning electron microscopy, energy-dispersive x-ray spectroscopy, focused ion beam milling, and transmission electron microscopy. The as-manufactured contacts comprised three constituents: sintered Ag/W composite particles with fine-grained Ag and coarse-grained W, coarse-grained pockets of Ag infiltrate, and a nano-crystalline surface Ag layer. There are also WO3 and Ag2O phases at the surface. After UL overload/temperature-rise testing, there is Ag loss giving a porous W-rich layer at the contact surface. In addition to binary oxides, we observe the formation of Ag2WO4. After UL endurance testing, material is swept across the surface by the breaker action giving a W-rich eroded porous surface on one side and a build-up of mixed oxides on the other. After UL short-circuit testing, a W crust forms due to melting and re-solidification of W and vaporization of Ag, and mid-plane cracks form due to the severe thermal gradients. There is a strong correlation between the observed microstructural features and the contact resistance measurements obtained from these samples.

  1. Frequency response in short thermocouple wires

    NASA Technical Reports Server (NTRS)

    Forney, L. J.; Meeks, E. L.; Ma, J.; Fralick, G. C.

    1992-01-01

    Theoretical expressions are derived for the steady state frequency response of a thermocouple wire. In particular, the effects of axial heat conduction are demonstrated for a nonuniform wire with unequal material properties and wire diameters across the junction. The amplitude ratio at low frequency omega approaches 0 agrees with the results of Scadron and Warshawsky (1952) for a steady state temperature distribution. Moreover, the frequency response for a nonuniform wire in the limit of infinite length l approaches infinity is shown to reduce to a simple expression that is analogous to the classic first order solution for a thermocouple wire with uniform properties. Theoretical expressions are also derived for the steady state frequency response of a supported thermocouple wire. In particular, the effects of axial heat conduction are demonstrated for both a supported one material wire and a two material wire with unequal material properties across the junction. For the case of a one material supported wire, an exact solution is derived which compares favorably with an approximate expression that only matches temperatures at the support junction. Moreover, for the case of a two material supported wire, an analytical expression is derived that closely correlates numerical results. Experimental measurements are made for the steady state frequency response of a supported thermocouple wire. In particular, the effects of axial heat conduction are demonstrated for both a supported one material wire (type K) and a two material wire (type T) with unequal material properties across the junction. The data for the amplitude ratio and phase angle are correlated to within 10 pct. with the theoretical predictions of Forney and Fralick (1991). This is accomplished by choosing a natural frequency omega sub n for the wire data to correlate the first order response at large gas temperature frequencies. It is found that a large bead size, however, will increase the amplitude ratio at

  2. The nucleation mechanism of wire explosion

    NASA Astrophysics Data System (ADS)

    Tkachenko, S. I.; Vorob'ev, V. S.; Malyshenko, S. P.

    2004-02-01

    This study deals with the nucleation mechanism of electric explosion of wires allowing estimation of wire parameters at the start of the explosion for a wide range of experimental conditions. We analyse the dependence of the limit value of the energy deposited during the initial resistive phase of heating of the wire on the parameters of the wire and circuit as well as the size distribution of metal particles formed on electrical explosion of the wire. We discuss the correspondence of these results with previously published experimental data.

  3. Heat-induced spinodal decomposition of Ag-Cu nanoparticles.

    PubMed

    Sopoušek, Jiří; Zobač, Ondřej; Buršík, Jiří; Roupcová, Pavla; Vykoukal, Vít; Brož, Pavel; Pinkas, Jiří; Vřešt'ál, Jan

    2015-11-14

    Solvothermal synthesis was used for Ag-Cu nanoparticle (NP) preparation from metallo-organic precursors. The detailed NP characterization was performed to obtain information about nanoparticle microstructure and both phase and chemical compositions. The resulting nanoparticles exhibited chemical composition inside a FCC_Ag + FCC_Cu two-phase region. The microstructure study was performed by various methods of electron microscopy including high-resolution transmission electron microscopy (HRTEM) at an atomic scale. The HRTEM and X-ray diffraction studies showed that the prepared nanoparticles form the face centred cubic (FCC) crystal lattice where the silver atoms are randomly mixed with copper. The CALPHAD approach was used for predicting the phase diagram of the Ag-Cu system in both macro- and nano-scales. The predicted spinodal decomposition of the metastable Ag-Cu nanoparticles was experimentally induced by heating on an X-ray powder diffractometer (HT XRD). The nucleation of the Cu-rich phase was detected and its growth was studied. Changes in the Ag-rich phase were observed in situ by X-ray diffraction under vacuum. The heat treatment was conducted at different maximum temperatures up to 450 °C and the resulting particle product was analysed. The experiments were complemented by differential scanning calorimetry (DSC) measurements up to liquidus temperature. The start temperatures of the spinodal phase transformation and particle aggregation were evaluated. PMID:25929324

  4. Electromagnetic scattering by a straight thin wire

    NASA Technical Reports Server (NTRS)

    Shamansky, Harry T.; Dominek, Allen K.; Peters, Leon, Jr.

    1989-01-01

    The traveling-wave energy, which multiply diffracts on a straight thin wire, is represented as a sum of terms, each with a distinct physical meaning, that can be individually examined in the time domain. Expressions for each scattering mechanism on a straight thin wire are cast in the form of four basic electromagnetic wave concepts: diffraction, attachment, launch, and reflection. Using the basic mechanisms from P. Ya. Ufimtsev (1962), each of the scattering mechanisms is included into the total scattered field for the straight thin wire. Scattering as a function of angle and frequency is then compared to the moment-method solution. These analytic expressions are then extended to a lossy wire with a simple approximate modification using the propagation velocity on the wire as derived from the Sommerfeld wave on a straight lossy wire. Both the perfectly conducting and lossy wire solutions are compared to moment-method results, and excellent agreement is found. As is common with asymptotic solutions, when the electrical length of wire is smaller than 0.2 lambda the results lose accuracy. The expressions modified to approximate the scattering for the lossy thin wire yield excellent agreement even for lossy wires where the wire radius is on the order of skin depth.

  5. SpaceWire Data Handling Demonstration System

    NASA Astrophysics Data System (ADS)

    Mills, S.; Parkes, S. M.; O'Gribin, N.

    2007-08-01

    The SpaceWire standard was published in 2003 with the aim of providing a standard for onboard communications, defining the physical and data link layers of an interconnection, in order to improve reusability, reliability and to reduce the cost of mission development. The many benefits which it provides mean that it has already been used in a number of missions, both in Europe and throughout the world. Recent work by the SpaceWire community has included the development of higher level protocols for SpaceWire, such as the Remote Memory Access Protocol (RMAP) which can be used for many purposes, including the configuration of SpaceWire devices. Although SpaceWire has become very popular, the various ways in which it can be used are still being discovered, as are the most efficient ways to use it. At the same time, some in the space industry are not even aware of SpaceWire's existence. This paper describes the SpaceWire Data Handling Demonstration System that has been developed by the University of Dundee. This system simulates an onboard data handling network based on SpaceWire. It uses RMAP for all communication, and so demonstrates how SpaceWire and standardised higher level protocols can be used onboard a spacecraft. The system is not only a good advert for those who are unfamiliar with the benefits of SpaceWire, it is also a useful tool for those using SpaceWire to test ideas.

  6. NASA wiring for space applications program

    NASA Technical Reports Server (NTRS)

    Schulze, Norman

    1995-01-01

    An overview of the NASA Wiring for Space Applications Program and its relationship to NASA's space technology enterprise is given in viewgraph format. The mission of the space technology enterprise is to pioneer, with industry, the development and use of space technology to secure national economic competitiveness, promote industrial growth, and to support space missions. The objectives of the NASA Wiring for Space Applications Program is to improve the safety, performance, and reliability of wiring systems for space applications and to develop improved wiring technologies for NASA flight programs and commercial applications. Wiring system failures in space and commercial applications have shown the need for arc track resistant wiring constructions. A matrix of tests performed versus wiring constructions is presented. Preliminary data indicate the performance of the Tensolite and Filotex hybrid constructions are the best of the various candidates.

  7. Wire Crimp Connectors Verification using Ultrasonic Inspection

    NASA Technical Reports Server (NTRS)

    Cramer, K. Elliott; Perey, Daniel F.; Yost, William T.

    2007-01-01

    The development of a new ultrasonic measurement technique to quantitatively assess wire crimp connections is discussed. The amplitude change of a compressional ultrasonic wave propagating through the junction of a crimp connector and wire is shown to correlate with the results of a destructive pull test, which previously has been used to assess crimp wire junction quality. Various crimp junction pathologies (missing wire strands, incorrect wire gauge, incomplete wire insertion in connector) are ultrasonically tested, and their results are correlated with pull tests. Results show that the ultrasonic measurement technique consistently (as evidenced with pull-testing data) predicts good crimps when ultrasonic transmission is above a certain threshold amplitude level. A physics-based model, solved by finite element analysis, describes the compressional ultrasonic wave propagation through the junction during the crimping process. This model is in agreement within 6% of the ultrasonic measurements. A prototype instrument for applying the technique while wire crimps are installed is also presented.

  8. Sintered wire cesium dispenser photocathode

    DOEpatents

    Montgomery, Eric J; Ives, R. Lawrence; Falce, Louis R

    2014-03-04

    A photoelectric cathode has a work function lowering material such as cesium placed into an enclosure which couples a thermal energy from a heater to the work function lowering material. The enclosure directs the work function lowering material in vapor form through a low diffusion layer, through a free space layer, and through a uniform porosity layer, one side of which also forms a photoelectric cathode surface. The low diffusion layer may be formed from sintered powdered metal, such as tungsten, and the uniform porosity layer may be formed from wires which are sintered together to form pores between the wires which are continuous from the a back surface to a front surface which is also the photoelectric surface.

  9. Parallel wire cable static load testing

    NASA Astrophysics Data System (ADS)

    Velasco Gil, Isabella C.

    This report is the result of two evaluations for the analysis of parallel wire cables. The purpose of the first assessment was to evaluate the stiffness and strength of parallel wire cables. For the methodology, three test setups were executed utilizing single wires, seven wire parallel cables, and 100 wire parallel cables as specimens. The parallel wire cables were connected with molted zinc to their sockets. The cables were manufactured by Wilolamb Construction. The results indicate that the single, seven, and 100 wire specimens had similar performance in yield stress, yield strain, modulus, and ultimate strain. However, the amount of strain decreased as the number of wires increased. Because the mechanical properties of the multi wires specimens had not significant difference, it is suggested that the zinc sockets had insignificant impact on their performance. Comparing these results to a previous test executed for parallel wire cables, there were significant differences on the ultimate capacity. It is assumed that the fabrication method of the cables were different. The second evaluation had two purposes. First, it was intended to compare the results of the single wire test from OSU to the single wire test results from Sherry Laboratories. From the analysis, it was found that the ultimate and yield loads were similar between both laboratories procedures, but their strength capacity and ultimate strain were different. It was observed that the Sherry Lab used a different method to compute the mechanical properties of the wire and that the measurement of the elongation was different to the procedures from OSU. Second, the secondary analysis was to evaluate if there is any significant difference between wires sanded at the mid-length of the specimen and wires that were not sanded. From this analysis it was observed that there was no difference between the sanded and non-sanded wires, which indicated that cross-section reduction should not be necessary for the

  10. Pin Wire Coating Trip Report

    SciTech Connect

    Spellman, G P

    2004-03-18

    A meeting to discuss the current pin wire coating problems was held at the Reynolds plant in Los Angeles on 2MAR04. The attendance list for Reynolds personnel is attached. there was an initial presentation which gave a brief history and the current status of pin wire coating at Reynolds. There was a presentation by Lori Primus on the requirements and issues for the coating. There was a presentation by Jim Smith of LANL on the chemistry and to some extent process development done to date. There was a long session covering what steps should be taken in the short term and, to a lesser extent, the long term. The coating currently being used is a blend of two polymers, polyethersulfone and polyparabanic acid (PPA) and some TiO2 filler. This system was accepted and put into production when the pin wire coating was outsourced to another company in 1974. When that company no longer was interested, the wire coating was brought in-house to Reynolds. At that time polyparabanic acid was actually a commercial product available from Exxon under the trade name Tradlon. However, it appears that the material used at Reynolds was synthesized locally. Also, it appears that a single large batch was synthesized in that time period and used up to 1997 when the supply ran out. The reason for the inclusion of TiO2 is not known although it does act as a rheological thickener. However, a more controlled thickening can be obtained with materials such as fumed silica. This material would have less likelihood of causing point imperfections in the coatings. Also, the mixing technique being used for all stages of the process is a relatively low shear ball mill process and the author recommends a high shear process such as a three roll paint mill, at least for the final mixing. Since solvent is added to the powder at Reynolds, it may be that they need to have the paint mill there.

  11. Reduced-Wiring Tactile Sensor

    NASA Technical Reports Server (NTRS)

    Ohm, Timothy R.

    1991-01-01

    Proposed tactile sensor on robot finger puts out multiplexed analog signals transmitted to control computer on fewer wires than needed to transmit equivalent digital signals. Analog output represents data on contact area of object being gripped, on position of object, and on direction and rate of slippage if any. Consists of chains of normally open switches and resistors on surface of finger. Each resistance double preceding resistance in each chain. Constant-current sources supply power to chains.

  12. Highly luminescent material based on Alq3:Ag nanoparticles.

    PubMed

    Salah, Numan; Habib, Sami S; Khan, Zishan H

    2013-09-01

    Tris (8-hydroxyquinoline) aluminum (Alq3) is an organic semiconductor molecule, widely used as an electron transport layer, light emitting layer in organic light-emitting diodes and a host for fluorescent and phosphorescent dyes. In this work thin films of pure and silver (Ag), cupper (Cu), terbium (Tb) doped Alq3 nanoparticles were synthesized using the physical vapor condensation method. They were fabricated on glass substrates and characterized by X-ray diffraction, scanning electron microscope (SEM), energy dispersive spectroscopy, atomic force microscope (AFM), UV-visible absorption spectra and studied for their photoluminescence (PL) properties. SEM and AFM results show spherical nanoparticles with size around 70-80 nm. These nanoparticles have almost equal sizes and a homogeneous size distribution. The maximum absorption of Alq3 nanoparticles is observed at 300 nm, while the surface plasmon resonant band of Ag doped sample appears at 450 nm. The PL emission spectra of Tb, Cu and Ag doped Alq3 nanoparticles show a single broad band at around 515 nm, which is similar to that of the pure one, but with enhanced PL intensity. The sample doped with Ag at a concentration ratio of Alq3:Ag = 1:0.8 is found to have the highest PL intensity, which is around 2 times stronger than that of the pure one. This enhancement could be attributed to the surface plasmon resonance of Ag ions that might have increased the absorption and then the quantum yield. These remarkable result suggest that Alq3 nanoparticles incorporated with Ag ions might be quite useful for future nano-optoelectronic devices. PMID:23653126

  13. The interaction of Ag with Bi-Pb-Sr-Ca-Cu-O superconductor

    NASA Astrophysics Data System (ADS)

    Dou, S. X.; Song, K. H.; Liu, H. K.; Sorrell, C. C.; Apperley, M. H.; Gouch, A. J.; Savvides, N.; Hensley, D. W.

    1989-10-01

    Bi-Pb-Sr-Ca-Cu-O superconductor compounds have been doped with up to 30 wt% Ag, sintered under variable oxygen partial pressure, and characterised in terms of the electrical and crystallographic behaviour. In contrast to previous reports that claim that Ag is the only metal non-poisoning to the superconductivity of Bi-Sr-Ca-Cu-O (BSCCO), it has been found that Ag additions to Bi-Pb-Sr-Ca-Cu-O depress Tc and Jc drastically and cause a large decrease in lattice parameters when samples are treated in air or pure oxygen. However, the lattice parameters, Tc and Jc remain unaffected by Ag additions when samples are heat treated in 0.030-0.067 atm oxygen. It is clear that the Ag reacts with and destabilises the superconducting phase when the samples are treated in air or pure oxygen while, when the samples are heat treated in low oxygen partial pressures, the Ag remains as an isolated inert metal phase that improves the weak links between the grains. This discovery clearly shows the feasibility of Ag-clad superconductor wire. For Ag-clad superconductor tape of 0.1 mm 2 cross sectional area heat treated in air, Jc was measured to be 54 A/cm 2. The same specimen sintered in 0.067 atm oxygen showed that the Jc increased to 2078 A/cm 2.

  14. Life cycle assessment of the application of nanoclays in wire coating

    NASA Astrophysics Data System (ADS)

    Tellaetxe, A.; Blázquez, M.; Arteche, A.; Egizabal, A.; Ermini, V.; Rose, J.; Chaurand, P.; Unzueta, I.

    2012-09-01

    A life cycle assessment (LCA) is carried out to compare nanoclay-reinforced polymer wire coatings with conventional ones. While the conventional wire coatings contain standard halogen free retardants, in reinforced coatings, montmorillonite (nanoclay) is incorporated into electric cable linings as a rheological agent for an increased resistance to fire. In addition, a reduced load of standard halogen free retardants is obtained. The synergistic effect of the montmorillonite on traditional flame retardant additives (by the formation of a three-dimensional char network) can lead to a revolution in wire production. The application of nanoclays contributes also to anti-dripping effect and flexibility increase [1]. Some producers have already started commercializing wire with nanotechnology-based coating; in the short term the use of nanoclay in wire coating production will probably reach a significant market share replacing traditional formulations. The main aim of this study is to compare the environmental impacts along the life cycle of a traditional wire coating (mineral flame retardants like ATH or MDH in a polymer matrix) with the nanoclay-reinforced wire coating, where the montmorillonite replaces a low percentage of the mineral flame retardant. The system boundaries of the study include the following unit processes: nanoclay production, thermoplastic material and mineral flame retardants production, cable coating manufacturing by extrusion and different end of life scenarios (recycling, incineration and landfill disposal). Whereas nanoreinforced composites have shown and increased fire retardance, the addition of nanomaterials seems to have no significant relevance in the environmental assessment. However, the lack of nano-specific characterization factors for nanomaterials and emission rates associated to the different life cycle stages -mainly in the extrusion and use phase, where accidental combustions can take place- still remains a challenge for realistic

  15. Synthesis, characterization and multifunctional properties of plasmonic Ag-TiO2 nanocomposites.

    PubMed

    Prakash, Jai; Kumar, Promod; Harris, R A; Swart, Chantel; Neethling, J H; van Vuuren, A Janse; Swart, H C

    2016-09-01

    We report on the synthesis of multifunctional Ag-TiO2 nanocomposites and their optical, physio-chemical, surface enhanced Raman scattering (SERS) and antibacterial properties. A series of Ag-TiO2 nanocomposites were synthesized by sol-gel technique and characterized by x-ray diffraction, scanning and transmission electron microscopy, energy-dispersed x-ray analysis, photoluminescence, UV-vis, x-ray photoelectron and Raman spectroscopy and Brunauer-Emmett-Teller method. The Ag nanoparticles (NPs) (7-20 nm) were found to be uniformly distributed around and strongly attached to TiO2 NPs. The novel optical responses of the nanocomposites are due to the strong electric field from the localized surface plasmon (LSP) excitation of the Ag NPs and decreased recombination of photo-induced electrons and holes at Ag-TiO2 interface providing potential materials for photocatalysis. The nanocomposites show enhancement in the SERS signals of methyl orange (MO) molecules with increasing Ag content attributed to the long-range electromagnetic enhancement from the excited LSP of the Ag NPs. To further understand the SERS activity, molecular mechanics and molecular dynamics simulations were used to study the geometries and SERS enhancement of MO adsorbed onto Ag-TiO2 respectively. Simulation results indicate that number of ligands (MO) that adsorb onto the Ag NPs as well as binding energy per ligand increases with increasing NP density and molecule-to-surface orientation is mainly flat resulting in strong bond strength between MO and Ag NP surface and enhanced SERS signals. The antimicrobial activity of the Ag-TiO2 nanocomposites was tested against the bacterium Staphylococcus aureus and enhanced antibacterial effect was observed with increasing Ag content explained by contact killing action mechanism. These results foresee promising applications of the plasmonic metal-semiconductor based nano-biocomposites for both chemical and biological samples. PMID:27456278

  16. Radiation from Ag high energy density Z-pinch plasmas and applications to lasing

    SciTech Connect

    Weller, M. E. Safronova, A. S.; Kantsyrev, V. L.; Esaulov, A. A.; Shrestha, I.; Stafford, A.; Keim, S. F.; Shlyaptseva, V. V.; Osborne, G. C.; Petkov, E. E.; Apruzese, J. P.; Giuliani, J. L.; Chuvatin, A. S.

    2014-03-15

    Silver (Ag) wire arrays were recently introduced as efficient x-ray radiators and have been shown to create L-shell plasmas that have the highest electron temperature (>1.8 keV) observed on the Zebra generator so far and upwards of 30 kJ of energy output. In this paper, results of single planar wire arrays and double planar wire arrays of Ag and mixed Ag and Al that were tested on the UNR Zebra generator are presented and compared. To further understand how L-shell Ag plasma evolves in time, a time-gated x-ray spectrometer was designed and fielded, which has a spectral range of approximately 3.5–5.0 Å. With this, L-shell Ag as well as cold L{sub α} and L{sub β} Ag lines was captured and analyzed along with photoconducting diode (PCD) signals (>0.8 keV). Along with PCD signals, other signals, such as filtered XRD (>0.2 keV) and Si-diodes (SiD) (>9 keV), are analyzed covering a broad range of energies from a few eV to greater than 53 keV. The observation and analysis of cold L{sub α} and L{sub β} lines show possible correlations with electron beams and SiD signals. Recently, an interesting issue regarding these Ag plasmas is whether lasing occurs in the Ne-like soft x-ray range, and if so, at what gains? To help answer this question, a non-local thermodynamic equilibrium (LTE) kinetic model was utilized to calculate theoretical lasing gains. It is shown that the Ag L-shell plasma conditions produced on the Zebra generator at 1.7 maximum current may be adequate to produce gains as high as 6 cm{sup −1} for various 3p → 3s transitions. Other potential lasing transitions, including higher Rydberg states, are also included in detail. The overall importance of Ag wire arrays and plasmas is discussed.

  17. Radiation from Ag high energy density Z-pinch plasmas and applications to lasing

    NASA Astrophysics Data System (ADS)

    Weller, M. E.; Safronova, A. S.; Kantsyrev, V. L.; Esaulov, A. A.; Shrestha, I.; Apruzese, J. P.; Giuliani, J. L.; Chuvatin, A. S.; Stafford, A.; Keim, S. F.; Shlyaptseva, V. V.; Osborne, G. C.; Petkov, E. E.

    2014-03-01

    Silver (Ag) wire arrays were recently introduced as efficient x-ray radiators and have been shown to create L-shell plasmas that have the highest electron temperature (>1.8 keV) observed on the Zebra generator so far and upwards of 30 kJ of energy output. In this paper, results of single planar wire arrays and double planar wire arrays of Ag and mixed Ag and Al that were tested on the UNR Zebra generator are presented and compared. To further understand how L-shell Ag plasma evolves in time, a time-gated x-ray spectrometer was designed and fielded, which has a spectral range of approximately 3.5-5.0 Å. With this, L-shell Ag as well as cold Lα and Lβ Ag lines was captured and analyzed along with photoconducting diode (PCD) signals (>0.8 keV). Along with PCD signals, other signals, such as filtered XRD (>0.2 keV) and Si-diodes (SiD) (>9 keV), are analyzed covering a broad range of energies from a few eV to greater than 53 keV. The observation and analysis of cold Lα and Lβ lines show possible correlations with electron beams and SiD signals. Recently, an interesting issue regarding these Ag plasmas is whether lasing occurs in the Ne-like soft x-ray range, and if so, at what gains? To help answer this question, a non-local thermodynamic equilibrium (LTE) kinetic model was utilized to calculate theoretical lasing gains. It is shown that the Ag L-shell plasma conditions produced on the Zebra generator at 1.7 maximum current may be adequate to produce gains as high as 6 cm-1 for various 3p → 3s transitions. Other potential lasing transitions, including higher Rydberg states, are also included in detail. The overall importance of Ag wire arrays and plasmas is discussed.

  18. Nano-composite materials

    DOEpatents

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland

    2010-05-25

    Nano-composite materials are disclosed. An exemplary method of producing a nano-composite material may comprise co-sputtering a transition metal and a refractory metal in a reactive atmosphere. The method may also comprise co-depositing a transition metal and a refractory metal composite structure on a substrate. The method may further comprise thermally annealing the deposited transition metal and refractory metal composite structure in a reactive atmosphere.

  19. Synthesis of Ultrastable Ag Nanoplates/Polyethylenimine-Reduced Graphene Oxide and Its Application as a Versatile Electrochemical Sensor.

    PubMed

    Wang, Jindi; Zhang, Guoxin; Sun, Wanxia; Sun, Jingsong; Luo, Liang; Chang, Zheng; Sun, Xiaoming

    2016-07-25

    Investigations on Ag nanostructures/reduced graphene oxide composites have been frequently reported, yet the morphology control of those loaded Ag nanocrystals is still challenging. We herein develop a facile method to grow triangular Ag nanoplates (AgP) on polyethylenimine-modified reduced graphene oxide (AgP/PEI-rGO). The AgP/PEI-rGO hybrids show unexpected high stability against chloride ions (Cl(-) ) and hydrogen peroxide (H2 O2 ), which is possibly due to the strong interaction between surface Ag atoms with the amine groups of PEI. In the chronoamperometry measurements for detecting H2 O2 , N2 H4 , and NaNO2 , the AgP/PEI-rGO hybrid shows very wide linear ranges (usually 10(-6) -10(-2)  mol L(-1) for H2 O2 , N2 H4 , and NaNO2 ) and low detection limits (down to ≈1×10(-7)  mol L(-1) ), which demonstrate the promising electrochemical sensor applications of these metal/graphene hybrids with well-defined morphologies and facets. In addition, this strategy could be extended to the deposition of other noble metals on rGO with controlled morphologies. PMID:27362916

  20. Electron-probe quantitative energy-dispersive analysis of trace magnesium concentrations in Ag-Mg alloys

    SciTech Connect

    Marinenko, R.B.

    1996-12-31

    Internally oxidized Ag-Mg alloys are used as sheaths for high Tc superconductor wires because of their superior mechanical properties. The preparation and characteristics of these materials have been reported. Performance of the sheaths depends on the concentration of the magnesium which generally is less than 0.5 wt. percent. The purpose of this work was to determine whether electron probe microanalysis using energy dispersive spectrometry (EDS) could be used to quantitate three different Ag-Mg alloys. Quantitative EDS analysis can be difficult because the AgL escape peak occurs at the same energy (1.25 keV) as the Mg K{alpha} peak.

  1. Intermetallic compound formation at Cu-Al wire bond interface

    SciTech Connect

    Bae, In-Tae; Young Jung, Dae; Chen, William T.; Du Yong

    2012-12-15

    Intermetallic compound (IMC) formation and evolution at Cu-Al wire bond interface were studied using focused ion beam /scanning electron microscopy, transmission electron microscopy (TEM)/energy dispersive x-ray spectroscopy (EDS), nano beam electron diffraction (NBED) and structure factor (SF) calculation. It was found that discrete IMC patches were formed at the Cu/Al interface in as-packaged state and they grew toward Al pad after high temperature storage (HTS) environment at 150 Degree-Sign C. TEM/EDS and NBED results combined with SF calculation revealed the evidence of metastable {theta} Prime -CuAl{sub 2} IMC phase (tetragonal, space group: I4m2, a = 0.404 nm, c= 0.580 nm) formed at Cu/Al interfaces in both of the as-packaged and the post-HTS samples. Two feasible mechanisms for the formation of the metastable {theta} Prime -CuAl{sub 2} phase are discussed based on (1) non-equilibrium cooling of wire bond that is attributed to highly short bonding process time and (2) the epitaxial relationships between Cu and {theta} Prime -CuAl{sub 2}, which can minimize lattice mismatch for {theta} Prime -CuAl{sub 2} to grow on Cu.

  2. Method and apparatus for laying wire arrays

    DOEpatents

    Horowitz, Seymour M.; Nesbitt, Dale D.

    1986-01-01

    Wire arrays (11) having a continuous wire (12) which is formed into a predetermined pattern and adhered to a backing material or substrate (13) are fabricated by applying adhesive material (16a, 16b) along opposite edge portions (17, 18) of the substrate, positioning a row of winding spools (21) along each of the edge portions and repeatedly extending the wire between and around successive spools at the opposite edge portions. The wound wire is then traveled along each spool toward the substrate and into contact with the adhesive. The spools are then removed and a coating of hardenable material (54) is applied to secure the wound wire to the substrate. Tension in the wire is relieved prior to contact of the wire with the adhesive and a small amount of slack is introduced into the wire before the final coating step. Mechanism (32) is provided for lifting the spools away from the substrate without disturbing the wound wire. The method and apparatus enable manufacture of precisely configured wire arrays without complex or costly equipment and do not require structural alterations in the substrate for the purpose of accommodating to fabrication equipment.

  3. Analysis of Conical Wire Array Z-Pinch Stability with a Center Wire

    SciTech Connect

    Martinez, D.; Presura, R.; Wright, S.; Plechaty, C.; Neff, S.; Wanex, L.; Ampleford, D. J.

    2009-01-21

    Adding a center wire on the axis of a conical wire array produces conditions suitable for studying shear flow stabilization of the Z-pinch. The conical wire array produces and axial plasma flow while the center wire introduces a radial variation of the axial velocity. Experiments of this array configuration were preformed on the 1 MA Zebra Z-pinch generator and showed stabilization of the kink instability when a center wire was present. Comparison with equivalent cylindrical wire arrays indicates that the shear flow stabilization plays a role in the stabilization of the kink instability.

  4. Thermal energy scavenger (rotating wire modules)

    SciTech Connect

    Hochstein, P.A.; Milton, H.W.; Pringle, W.L.

    1980-11-04

    A thermal energy scavenger assembly is is described including a plurality of temperature-sensitive wires made of material which exhibits shape memory due to a thermoelastic, martensitic phase transformation. The wires are placed in tension between fixed and movable plates which are, in turn, supported by a pair of wheels which are rotatably supported by a housing for rotation about a central axis. A pair of upper and lower cams are fixed to the housing and cam followers react with the respective cams. Each cam transmits forces through a pair of hydraulic pistons. One of the pistons is connected to a movable plate to which one end of the wires are connected whereby a stress is applied to the wires to strain the wires during a first phase and whereby the cam responds to the unstraining of the wires during a second phase. A housing defines fluid compartments through which hot and cold fluid passes and flows radially through the wires whereby the wires become unstrained and shorten in length when subjected to the hot fluid for causing a reaction between the cam followers and the cams to effect rotation of the wheels about the central axis of the assembly, which rotation of the wheels is extracted through beveled gearing. The wires are grouped into a plurality of independent modules with each module having a movable plate, a fixed plate and the associated hydraulic pistons and cam follower. The hydraulic pistons and cam follower of a module are disposed at ends of the wires opposite from the ends of the wires at which the same components of the next adjacent modules are disposed so that the cam followers of alternate modules react with one of the cams and the remaining cam followers of the remaining modules react with the other cam. There is also included stress limiting means in the form of coil springs associated with alternate ends of the wires for limiting the stress or strain in the wires.

  5. Nano-nutrition of chicken embryos. The effect of silver nanoparticles and ATP on expression of chosen genes involved in myogenesis.

    PubMed

    Sawosz, Filip; Pineda, Lane; Hotowy, Anna; Jaworski, Sławomir; Prasek, Marta; Sawosz, Ewa; Chwalibog, André

    2013-01-01

    It has been suggested that the quantity and quality of nutrients stored in the egg might not be optimal for the fast rate of chicken embryo development in modern broilers, and embryos could be supplemented with nutrients by in ovo injection. Recent experiments showed that in ovo feeding reduces post-hatch mortality and skeletal disorders and increases muscle growth and breast meat yield. Adenosine triphosphate (ATP) is a "ready for use" energetic molecule, while nanoparticles of silver (Nano-Ag) may penetrate tissues as well as cells and localise inside cells. In this investigation, we hypothesised that silver nanoparticles could be used as a protective carrier for ATP as well as an active agent. ATP and/or an ATP complex with Nano-Ag would be delivered to the muscle cells as a gene expression regulator and promoter of growth and development of embryo breast muscle. A collection of 160 broiler eggs was randomly divided into a Control group without injection and injected groups with hydrocolloids of Nano-Ag, ATP or a complex of Nano-Ag and ATP (Nano-Ag/ATP). The embryos were evaluated on day 20 of incubation. The results indicate that the application of ATP to chicken embryos increases expression of fibroblast growth factor 2 (FGF2), vascular endothelial growth factor (VEGF) and Na(+)/K(+) transporting ATPase (ATP1A1), which may indicate that an extra energy source can enhance molecular mechanisms of muscle cell proliferation. Nano-Ag also up-regulated expression of FGF2, VEGF, ATP1A1 and, also up-regulated expression of myogenic differentiation 1(MyoD1), affecting cell differentiation. The results indicate that ATP and Nano-Ag may accelerate growth and maturation of muscle cells. PMID:23952606

  6. Characterization of tumor-targeting Ag2S quantum dots for cancer imaging and therapy in vivo

    NASA Astrophysics Data System (ADS)

    Chen, Haiyan; Li, Bowen; Zhang, Min; Sun, Kang; Wang, Yiran; Peng, Kerui; Ao, Mengdi; Guo, Yiran; Gu, Yueqing

    2014-10-01

    Nanomedicine platforms that have the potential to simultaneously provide the function of molecular imaging and therapeutic treatment in one system are beneficial to address the challenges of cancer heterogeneity and adaptive resistance. In this study, Cyclic RGD peptide (cRGD), a less-expensive active tumor targeting tri-peptide, and doxorubicin (DOX), a widely used chemotherapeutic drug, were covalently attached to Ag2S quantum dots (QDs) to form the nano-conjugates Ag2S-DOX-cRGD. The optical characterization of Ag2S-DOX-cRGD manifested the maintenance of QDs fluorescence, which suggested the potential of Ag2S for monitoring intracellular and systemic drug distribution. The low biotoxicity of Ag2S QDs indicated that they are promisingly safe nanoparticles for bio-applications. Furthermore, the selective imaging and favorable tumor inhibition of the nanoconjugates were demonstrated at both cell and animal levels. These results indicated a promising future for the utilization of Ag2S QDs as a kind of multi-functional nano platform to achieve imaging-visible nano-therapeutics.

  7. The Nano-filters as the tools for the management of the water imbalance in the human society

    NASA Astrophysics Data System (ADS)

    Singh, R. P.; Kontar, V.

    2011-12-01

    The imbalance of water in the human society there is some situation where the water demand is not equivalent to the water supply. We are talking now about the shortage of some clear water which suitable for human use, animals, plants, technologies etc. There are existing some various imbalances of water in the human society, but about this will be other publications. The humanity has have the millennial experience of the water imbalance management. The novelty of the matter is the new nano-materials which offer a lot of the new principles more effective management of the water imbalance in the human society. The nano-materials have typical pore size 0.001 micron (1 nano-meter). There are some metal-containing nano-particles, CNTs, fullerene, graphene, zeolites and dendrimers etc, The nano-materials have unique physicochemical properties due to their large surface areas, size and shape-dependent optical, electronic, and catalytic properties that make them very useful for separation components some various stuff and water also. They have ability to functionalize with various chemical groups to increase their affinity toward a desired compound. The silver nano-wires have established a variety of applications, including transparent conductive electrodes for solar cells and optoelectronic. The salt of silver i.e. bulk silver shows photo-catalytic properties. The gold decorated silver nano-wires film may clean the organic molecule while irradiated with either commercial bulb or sun light. The mat (membrane) papers of nano-wires may clean up spilled oil at sea and organic pollutants in water. Arsenic-poisoned drinking water is a global problem, affecting people in Asia, Africa, North America, South America and Europe. Tiny bits of iron oxide that are smaller than living cells known as nanorust, which naturally binds with arsenic, could be used as a low-cost means of removing arsenic from water. Nano-tea bag purifies water on a small scale. The sachets are made up from the

  8. Nano-biocomposite films with modified cellulose nanocrystals and synthesized silver nanoparticles.

    PubMed

    Fortunati, E; Rinaldi, S; Peltzer, M; Bloise, N; Visai, L; Armentano, I; Jiménez, A; Latterini, L; Kenny, J M

    2014-01-30

    Ternary nano-biocomposite films based on poly(lactic acid) (PLA) with modified cellulose nanocrystals (s-CNC) and synthesized silver nanoparticles (Ag) have been prepared and characterized. The functionalization of the CNC surface with an acid phosphate ester of ethoxylated nonylphenol favoured its dispersion in the PLA matrix. The positive effects of the addition of cellulose and silver on the PLA barrier properties were confirmed by reductions in the water permeability (WVP) and oxygen transmission rate (OTR) of the films tested. The migration level of all nano-biocomposites in contact with food simulants were below the permitted limits in both non-polar and polar simulants. PLA nano-biocomposites showed a significant antibacterial activity influenced by the Ag content, while composting tests showed that the materials were visibly disintegrated after 15 days with the ternary systems showing the highest rate of disintegration under composting conditions. PMID:24299883

  9. A Vibrating Wire System For Quadrupole Fiducialization

    SciTech Connect

    Wolf, Zachary

    2010-12-13

    A vibrating wire system is being developed to fiducialize the quadrupoles between undulator segments in the LCLS. This note provides a detailed analysis of the system. The LCLS will have quadrupoles between the undulator segments to keep the electron beam focused. If the quadrupoles are not centered on the beam axis, the beam will receive transverse kicks, causing it to deviate from the undulator axis. Beam based alignment will be used to move the quadrupoles onto a straight line, but an initial, conventional alignment must place the quadrupole centers on a straight line to 100 {micro}m. In the fiducialization step of the initial alignment, the position of the center of the quadrupole is measured relative to tooling balls on the outside of the quadrupole. The alignment crews then use the tooling balls to place the magnet in the tunnel. The required error on the location of the quadrupole center relative to the tooling balls must be less than 25 {micro}m. In this note, we analyze a system under construction for the quadrupole fiducialization. The system uses the vibrating wire technique to position a wire onto the quadrupole magnetic axis. The wire position is then related to tooling balls using wire position detectors. The tooling balls on the wire position detectors are finally related to tooling balls on the quadrupole to perform the fiducialization. The total 25 {micro}m fiducialization error must be divided between these three steps. The wire must be positioned onto the quadrupole magnetic axis to within 10 {micro}m, the wire position must be measured relative to tooling balls on the wire position detectors to within 15 {micro}m, and tooling balls on the wire position detectors must be related to tooling balls on the quadrupole to within 10 {micro}m. The techniques used in these three steps will be discussed. The note begins by discussing various quadrupole fiducialization techniques used in the past and discusses why the vibrating wire technique is our method

  10. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel

    NASA Astrophysics Data System (ADS)

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-01

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs.

  11. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel.

    PubMed

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-22

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs. PMID:27276174

  12. Wire ablation dynamics model and its application to imploding wire arrays of different geometries.

    PubMed

    Esaulov, A A; Kantsyrev, V L; Safronova, A S; Velikovich, A L; Shrestha, I K; Williamson, K M; Osborne, G C

    2012-10-01

    The paper presents an extended description of the amplified wire ablation dynamics model (WADM), which accounts in a single simulation for the processes of wire ablation and implosion of a wire array load of arbitrary geometry and wire material composition. To investigate the role of wire ablation effects, the implosions of cylindrical and planar wire array loads at the university based generators Cobra (Cornell University) and Zebra (University of Nevada, Reno) have been analyzed. The analysis of the experimental data shows that the wire mass ablation rate can be described as a function of the current through the wire and some coefficient defined by the wire material properties. The aluminum wires were found to ablate with the highest rate, while the copper ablation is the slowest one. The lower wire ablation rate results in a higher inward velocity of the ablated plasma, a higher rate of the energy coupling with the ablated plasma, and a more significant delay of implosion for a heavy load due to the ablation effects, which manifest the most in a cylindrical array configuration and almost vanish in a single-planar array configuration. The WADM is an efficient tool suited for wire array load design and optimization in wide parameter ranges, including the loads with specific properties needed for the inertial confinement fusion research and laboratory astrophysics experiments. The data output from the WADM simulation can be used to simplify the radiation magnetohydrodynamics modeling of the wire array plasma. PMID:23214697

  13. Wire ablation dynamics model and its application to imploding wire arrays of different geometries

    NASA Astrophysics Data System (ADS)

    Esaulov, A. A.; Kantsyrev, V. L.; Safronova, A. S.; Velikovich, A. L.; Shrestha, I. K.; Williamson, K. M.; Osborne, G. C.

    2012-10-01

    The paper presents an extended description of the amplified wire ablation dynamics model (WADM), which accounts in a single simulation for the processes of wire ablation and implosion of a wire array load of arbitrary geometry and wire material composition. To investigate the role of wire ablation effects, the implosions of cylindrical and planar wire array loads at the university based generators Cobra (Cornell University) and Zebra (University of Nevada, Reno) have been analyzed. The analysis of the experimental data shows that the wire mass ablation rate can be described as a function of the current through the wire and some coefficient defined by the wire material properties. The aluminum wires were found to ablate with the highest rate, while the copper ablation is the slowest one. The lower wire ablation rate results in a higher inward velocity of the ablated plasma, a higher rate of the energy coupling with the ablated plasma, and a more significant delay of implosion for a heavy load due to the ablation effects, which manifest the most in a cylindrical array configuration and almost vanish in a single-planar array configuration. The WADM is an efficient tool suited for wire array load design and optimization in wide parameter ranges, including the loads with specific properties needed for the inertial confinement fusion research and laboratory astrophysics experiments. The data output from the WADM simulation can be used to simplify the radiation magnetohydrodynamics modeling of the wire array plasma.

  14. Ag nanoparticles generated using bio-reduction and -coating cause microbial killing without cell lysis.

    PubMed

    Gade, Aniket; Adams, Joshua; Britt, David W; Shen, Fen-Ann; McLean, Joan E; Jacobson, Astrid; Kim, Young-Cheol; Anderson, Anne J

    2016-04-01

    Cost-effective "green" methods of producing Ag nanoparticles (NPs) are being examined because of the potential of these NPs as antimicrobials. Ag NPs were generated from Ag ions using extracellular metabolites from a soil-borne Pythium species. The NPs were variable in size, but had one dimension less than 50 nm and were biocoated; aggregation and coating changed with acetone precipitation. They had dose-dependent lethal effects on a soil pseudomonad, Pseudomonas chlororaphis O6, and were about 30-fold more effective than Ag(+) ions. A role of reactive oxygen species in cell death was demonstrated by use of fluorescent dyes responsive to superoxide anion and peroxide accumulation. Also mutants of the pseudomonad, defective in enzymes that protect against oxidative stress, were more sensitive than the wild type strain; mutant sensitivity differed between exposure to Ag NPs and Ag(+) ions demonstrating a nano-effect. Imaging of bacterial cells treated with the biocoated Ag NPs revealed no cell lysis, but there were changes in surface properties and cell height. These findings support that biocoating the NPs results in limited Ag release and yet they retained potent antimicrobial activity. PMID:26805711

  15. A long-lived external Ag/AgCl reference electrode for use in high temperature/pressure environments

    SciTech Connect

    Danielson, M.J.

    1983-05-01

    High temperature pressure Ag/AgCl electrodes resistant to the contaminating effects of H/sub 2/ and H/sub 2/S were described in 1979. But the external reference electrode suffers from a thermal liquid junction potential (TLJP) and the development of the Soret effect (thermo-diffusion of the electrolyte). This paper describes a design to improve electrode life. A silvered-tube replaces the silver wire electrode. A liquid chromatograph minipump is used to slowly inject KC1 solution into the electrode to maintain a ''front'' of fresh solution. This prevents ageing effects, and the Soret effect. Construction specifications are given for: corrosion resistant tubing, electrical gland end, zirconium yarn, titanium tubing, polyimide collar, PTFE tubing, minipumps for chromatograph, zirconia plug, and silver chloride.

  16. Freeze-dried PVP-Ag+ precursors to novel AgBr/AgCl-Ag hybrid nanocrystals for visible-light-driven photodegradation of organic pollutants

    NASA Astrophysics Data System (ADS)

    Chen, Deliang; Chen, Qianqian; Zhang, Wenjie; Ge, Lianfang; Shao, Gang; Fan, Bingbing; Lu, Hongxia; Zhang, Rui; Yang, Daoyuan; Shao, Guosheng

    2015-04-01

    AgBr/AgCl-Ag nanocrystals with various molar Br-to-Ag ratios (RBr/Ag = 0, 1/3, 1/2, 2/3, 1) and different photoreduction times (0-20 min) were synthesized via stepwise liquid-solid reactions using the freeze-dried PVP-Ag+ hybrid as the Ag source, followed by a photoreduction reaction. The AgBr/AgCl-Ag7.5(1:2) nanocrystals obtained take on a spherical morphology with a particle-size range of 58 ± 15 nm. The photocatalytic performance of AgBr/AgCl-Ag nanocrystals was evaluated by photodegrading organic dyes, 4-chlorophenol and isopropanol under artificial visible light (λ ⩾ 420 nm, 100 mW cm-2). For the decomposition of rhodamine B, the AgBr/AgCl-Ag7.5(1:2) nanocrystals has a photodegradation rate of ∼0.87 min-1, ∼159 times higher than that (∼0.0054 min-1) of TiO2 (P25), whereas the AgCl-Ag and AgBr-Ag nanocrystals have photodegradation rates of 0.35 min-1 and 0.45 min-1, respectively. The efficient separation of photogenerated electron-hole pairs in the ternary system consisting of AgBr, AgCl and Ag species plays a key role in the enhancement of photocatalytic performance.

  17. Titanium bone implants with superimposed micro/nano-scale porosity and antibacterial capability

    NASA Astrophysics Data System (ADS)

    Necula, B. S.; Apachitei, I.; Fratila-Apachitei, L. E.; van Langelaan, E. J.; Duszczyk, J.

    2013-05-01

    This study aimed at producing a multifunctional layer with micro/nano-interconnected porosity and antibacterial capability on a rough macro-porous plasma sprayed titanium surface using the plasma electrolytic oxidation process. The layers were electrochemically formed in electrolytes based on calcium acetate and calcium glycerophosphate salts bearing dispersed Ag nanoparticles. They were characterized with respect to surface morphology and chemical composition using a scanning electron microscope equipped with the energy dispersive spectroscopy and back scattering detectors. Scanning electron microscopy images showed the formation of a micro/nano-scale porous layer, comprised of TiO2 bearing Ca and P species and Ag nanoparticles, following accurately the surface topography of the plasma sprayed titanium coating. The Ca/P atomic ratio was found to be close to that of bone apatite. Ag nanoparticles were incorporated on both on top and inside the porous structure of the TiO2 layer.

  18. Contact conductance of a graphene nanoribbon with its graphene nano-electrodes

    NASA Astrophysics Data System (ADS)

    Srivastava, Saurabh; Kino, Hiori; Joachim, Christian

    2016-04-01

    Electronically contacted between two graphene nano-electrodes, the contact conductance (G0) of a graphene nanoribbon (GNR) molecular wire is calculated using mono-electronic Elastic Scattering Quantum Chemistry (ESQC) theory. Different nano-electrode contact geometries are considered ranging from a top face to face van der Waals contact to an adiabatic funnel like planar chemical bonding. The Tamm state contributions to the GNR-graphene nano-electrode electronic interactions are discussed as a function of the molecular orbital hybridization. Contrary to the common belief, the adiabatic-like triangle shaped contact nano-graphene electrode does not provide a large G0 as compared to the abrupt contact geometry. The abrupt contact geometry is even worth than a top face to face van der Waals electronic contact with a metal.

  19. Contact conductance of a graphene nanoribbon with its graphene nano-electrodes.

    PubMed

    Srivastava, Saurabh; Kino, Hiori; Joachim, Christian

    2016-04-28

    Electronically contacted between two graphene nano-electrodes, the contact conductance (G0) of a graphene nanoribbon (GNR) molecular wire is calculated using mono-electronic Elastic Scattering Quantum Chemistry (ESQC) theory. Different nano-electrode contact geometries are considered ranging from a top face to face van der Waals contact to an adiabatic funnel like planar chemical bonding. The Tamm state contributions to the GNR-graphene nano-electrode electronic interactions are discussed as a function of the molecular orbital hybridization. Contrary to the common belief, the adiabatic-like triangle shaped contact nano-graphene electrode does not provide a large G0 as compared to the abrupt contact geometry. The abrupt contact geometry is even worth than a top face to face van der Waals electronic contact with a metal. PMID:27089225

  20. Tensile deformation of NiTi wires.

    PubMed

    Gall, Ken; Tyber, Jeff; Brice, Valerie; Frick, Carl P; Maier, Hans J; Morgan, Neil

    2005-12-15

    We examine the structure and properties of cold drawn Ti-50.1 at % Ni and Ti-50.9 at % Ni shape memory alloy wires. Wires with both compositions possess a strong <111> fiber texture in the wire drawing direction, a grain size on the order of micrometers, and a high dislocation density. The more Ni rich wires contain fine second phase precipitates, while the wires with lower Ni content are relatively free of precipitates. The wire stress-strain response depends strongly on composition through operant deformation mechanisms, and cannot be explained based solely on measured differences in the transformation temperatures. We provide fundamental connections between the material structure, deformation mechanisms, and resulting stress-strain responses. The results help clarify some inconsistencies and common misconceptions in the literature. Ramifications on materials selection and design for emerging biomedical applications of NiTi shape memory alloys are discussed. PMID:16138359

  1. Fabrication of Oxidation-Resistant Metal Wire Network-Based Transparent Electrodes by a Spray-Roll Coating Process.

    PubMed

    Kiruthika, S; Gupta, Ritu; Anand, Aman; Kumar, Ankush; Kulkarni, G U

    2015-12-16

    Roll and spray coating methods have been employed for the fabrication of highly oxidation resistant transparent and conducting electrodes (TCEs) by a simple solution process using crackle lithography technique. We have spray-coated a crackle paint-based precursor to produce highly interconnected crackle network on PET roll mounted on a roll coater with web speed of 0.6 m/min. Ag TCE with a transmittance of 78% and sheet resistance of ∼20 Ω/□ was derived by spraying Ag precursor ink over the crackle template followed by lift-off and annealing under ambient conditions. The Ag wire mesh was stable toward bending and sonication tests but prone to oxidation in air. When electrolessly coated with Pd, its robustness toward harsh oxidation conditions was enhanced. A low-cost transparent electrode has also been realized by using only small amounts of Ag as seed layer and growing Cu wire mesh by electroless method. Thus, made Ag/Cu meshes are found to be highly stable for more than a year even under ambient atmosphere. PMID:26580415

  2. Ag K- and L3-edge XAFS study on Ag species in Ag/Ga2O3 photocatalysts

    NASA Astrophysics Data System (ADS)

    Yamamoto, M.; Yoshida, T.; Yamamoto, N.; Nomoto, T.; Yamamoto, A.; Yoshida, H.; Yagi, S.

    2016-05-01

    Ag loaded Ga2O3 (Ag/Ga2O3) shows photocatalytic activity for reduction of CO2 with water. Ag L3-edge XANES and K-edge EXAFS spectra were measured for various Ag/Ga2O3 samples, which suggested that structural and chemical states of Ag species varied with the loading amount of Ag and the preparation method. The Ag species were metallic Ag particles with an AgGaO2-like interface structure in the sample with high loading amount of Ag while predominantly Ag metal clusters in the sample with low loading amount of Ag. The XANES feature just above the edge represented the interaction between the Ag species and the Ga2O3 surface, showing that the Ag metal clusters had more electrons in the d-orbitals by interacting with the Ga2O3 surface, which would contribute the high photocatalytic activity.

  3. AGS experiments -- 1995, 1996 and 1997

    SciTech Connect

    Depken, J.C.; Presti, P.L.

    1997-12-01

    This report contains (1) FY 1995 AGS schedule as run; (2) FY 1996 AGS schedule as run; (3) FY 1997 AGS schedule as run; (4) FY 1998--1999 AGS schedule (proposed); (5) AGS beams 1997; (6) AGS experimental area FY 1995 physics program; (7) AGS experimental area FY 1996 physics program; (8) AGS experimental area FY 1997 physics program; (9) AGS experimental area FY 1998--1999 physics program (proposed); (10) a listing of experiments by number; (11) two-page summaries of each experiment, in order by number; and (12) listing of publications of AGS experiments.

  4. AGS experiments -- 1991, 1992, 1993. Tenth edition

    SciTech Connect

    Depken, J.C.

    1994-04-01

    This report contains: (1) FY 1993 AGS schedule as run; (2) FY 1994--95 AGS schedule; (3) AGS experiments {ge} FY 1993 (as of 30 March 1994); (4) AGS beams 1993; (5) AGS experimental area FY 1991 physics program; (6) AGS experimental area FY 1992 physics program; (7) AGS experimental area FY 1993 physics program; (8) AGS experimental area FY 1994 physics program (planned); (9) a listing of experiments by number; (10) two-page summaries of each experiment; (11) listing of publications of AGS experiments; and (12) listing of AGS experiments.

  5. Synthesis and optimization of Ag-TiO2 composite nanofibers for photocatalytic treatment of impaired water sources.

    PubMed

    Nalbandian, Michael J; Zhang, Miluo; Sanchez, Joel; Kim, Seil; Choa, Yong-Ho; Cwiertny, David M; Myung, Nosang V

    2015-12-15

    In this work, Ag-TiO2 composite nanofibers were fabricated by electrospinning, where the composition and crystallinity were tuned by controlling the precursor composition and annealing conditions. Characterization revealed that bulk-embedded Ag nanoparticles inhibited anatase-to-rutile phase transformation and a decrease in band gap from 3.2 down to 2.8 eV with increase in the Ag content. The photocatalytic activity of 0.5 at.% Ag-TiO2 nanofibers toward phenol degradation was the greatest, outperforming both unmodified TiO2 nanofibers and commercially available TiO2 Aeroxide(®) P25 by a factor of ∼3. The high reactivity of the low content Ag-TiO2 nanofibers can be attributed to the addition of electron traps, which provide efficient carrier separation and, therefore, decreased recombination. However, further increase in Ag content led to lower photoreactivity, most likely due to the growth of the Ag nanoparticles, which suggests an optimal size of 2 to 3 nm for the Ag nanoparticles at 0.5 at.% provided the greatest photoreactivity. Ag-TiO2 nanofibers show great promise as innovative and highly performing nanomaterials for future nanotechnology-based treatment systems, particularly when the photoreactivity demonstrate herein is used in synergy with the established antimicrobial activity of nano-Ag. PMID:26101968

  6. Wire Whip Keeps Spray Nozzle Clean

    NASA Technical Reports Server (NTRS)

    Carroll, H. R.

    1982-01-01

    Air-turbine-driven wire whip is clamped near spray-gun mount. When spray gun is installed, wire whip is in position to remove foam buildup from nozzle face. Two lengths of wire 1 to 2 inches long and about 0.03 inch in thickness are used. Foam spray would be prevented from accumulating on nozzle face by increasing purge flow and cutting vortex-generating grooves inside cap and on nozzle flats.

  7. Space Shuttle Columbia Aging Wiring Failure Analysis

    NASA Technical Reports Server (NTRS)

    McDaniels, Steven J.

    2005-01-01

    A Space Shuttle Columbia main engine controller 14 AWG wire short circuited during the launch of STS-93. Post-flight examination divulged that the wire had electrically arced against the head of a nearby bolt. More extensive inspection revealed additional damage to the subject wire, and to other wires as well from the mid-body of Columbia. The shorted wire was to have been constructed from nickel-plated copper conductors surrounded by the polyimide insulation Kapton, top-coated with an aromatic polyimide resin. The wires were analyzed via scanning electron microscope (SEM), energy dispersive X-Ray spectroscopy (EDX), and electron spectroscopy for chemical analysis (ESCA); differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) were performed on the polyimide. Exemplar testing under laboratory conditions was performed to replicate the mechanical damage characteristics evident on the failed wires. The exemplar testing included a step test, where, as the name implies, a person stepped on a simulated wire bundle that rested upon a bolt head. Likewise, a shear test that forced a bolt head and a torque tip against a wire was performed to attempt to damage the insulation and conductor. Additionally, a vibration test was performed to determine if a wire bundle would abrade when vibrated against the head of a bolt. Also, an abrasion test was undertaken to determine if the polyimide of the wire could be damaged by rubbing against convolex helical tubing. Finally, an impact test was performed to ascertain if the use of the tubing would protect the wire from the strike of a foreign object.

  8. Radiofrequency Wire Recanalization of Chronically Thrombosed TIPS.

    PubMed

    Majdalany, Bill S; Elliott, Eric D; Michaels, Anthony J; Hanje, A James; Saad, Wael E A

    2016-07-01

    Radiofrequency (RF) guide wires have been applied to cardiac interventions, recanalization of central venous thromboses, and to cross biliary occlusions. Herein, the use of a RF wire technique to revise chronically occluded transjugular intrahepatic portosystemic shunts (TIPS) is described. In both cases, conventional TIPS revision techniques failed to revise the chronically thrombosed TIPS. RF wire recanalization was successfully performed through each of the chronically thrombosed TIPS, demonstrating initial safety and feasibility in this application. PMID:26902703

  9. Nondestructive Evaluation of Aircraft and Spacecraft Wiring

    NASA Technical Reports Server (NTRS)

    White, John E.; Tucholski, Edward J.; Green, Robert E., Jr.

    2004-01-01

    Spacecraft, and especially aircraft, often fry well past their original design lives and, therefore, the need to develop nondestructive evaluation procedures for inspection of vital structures in these craft is extremely important. One of the more recent problems is the degradation of wiring and wiring insulation. The present paper describes several nondestructive characterization methods which afford the possibility to detect wiring and insulation degradation in-situ prior to major problems with the safety of aircraft and spacecraft.

  10. Wrapped Wire Detects Rupture Of Pressure Vessel

    NASA Technical Reports Server (NTRS)

    Hunt, James B.

    1990-01-01

    Simple, inexpensive technique helps protect against damage caused by continuing operation of equipment after rupture or burnout of pressure vessel. Wire wrapped over area on outside of vessel where breakthrough most likely. If wall breaks or burns, so does wire. Current passing through wire ceases, triggering cutoff mechanism stopping flow in vessel to prevent further damage. Applied in other situations in which pipes or vessels fail due to overpressure, overheating, or corrosion.

  11. Plasmonic excitation-assisted optical and electric enhancement in ultra-thin solar cells: the influence of nano-strip cross section

    NASA Astrophysics Data System (ADS)

    Sabaeian, Mohammad; Heydari, Mehdi; Ajamgard, Narges

    2015-08-01

    The effects of Ag nano-strips with triangle, rectangular and trapezoid cross sections on the optical absorption, generation rate, and short-circuit current density of ultra-thin solar cells were investigated. By putting the nano-strips as a grating structure on the top of the solar cells, the waveguide, surface plasmon polariton (SPP), and localized surface plasmon (LSP) modes, which are excited with the assistance of nano-strips, were evaluated in TE and TM polarizations. The results show, firstly, the TM modes are more influential than TE modes in optical and electrical properties enhancement of solar cell, because of plasmonic excitations in TM mode. Secondly, the trapezoid nano-strips reveal noticeable impact on the optical absorption, generation rate, and short-circuit current density enhancement than triangle and rectangular ones. In particular, the absorption of long wavelengths which is a challenge in ultra-thin solar cells is significantly improved by using Ag trapezoid nano-strips.

  12. Plasmonic excitation-assisted optical and electric enhancement in ultra-thin solar cells: the influence of nano-strip cross section

    SciTech Connect

    Sabaeian, Mohammad Heydari, Mehdi; Ajamgard, Narges

    2015-08-15

    The effects of Ag nano-strips with triangle, rectangular and trapezoid cross sections on the optical absorption, generation rate, and short-circuit current density of ultra-thin solar cells were investigated. By putting the nano-strips as a grating structure on the top of the solar cells, the waveguide, surface plasmon polariton (SPP), and localized surface plasmon (LSP) modes, which are excited with the assistance of nano-strips, were evaluated in TE and TM polarizations. The results show, firstly, the TM modes are more influential than TE modes in optical and electrical properties enhancement of solar cell, because of plasmonic excitations in TM mode. Secondly, the trapezoid nano-strips reveal noticeable impact on the optical absorption, generation rate, and short-circuit current density enhancement than triangle and rectangular ones. In particular, the absorption of long wavelengths which is a challenge in ultra-thin solar cells is significantly improved by using Ag trapezoid nano-strips.

  13. Development of the Axial Instability in Low Wire Number Wire Array Z-Pinches

    SciTech Connect

    Knapp, P. F.; Bell, K. S.; Blesener, I. C.; Chalenski, D. A.; Douglass, J. D.; Greenly, J. B.; Martin, M. R.; McBride, R. D.; Pikuz, S. A.; Shelkovenko, T. A.; Hammer, D. A.; Kusse, B. R.; Hall, G. N.

    2009-01-21

    We are investigating the development of the axial instability, a modulation of the size of the coronal plasma that develops around each wire in wire-array Z-pinches. The modulation is a result of nonuniform ablation of material from the relatively cold wire core. It has long been known that the wavelength of this modulation is constant late in time and, since it is unique to different materials, it has come to be known as the fundamental mode. In these experiments we imaged individual wires with laser shadowgraphy early in time primarily in low wire number, large wire diameter aluminum arrays for ease of viewing. We Observe the development of this modulation from the time of initiation of coronal plasma, obtaining its dominant wavelength and amplitude growth as a function of time. We also studied the instability on coiled wires, which modify the wire ablation mechanism and completely suppress the fundamental mode[Hall2008]. time is discussed.

  14. 49 CFR 234.241 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... underground wire. 234.241 Section 234.241 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION GRADE CROSSING SAFETY, INCLUDING... Testing Maintenance Standards § 234.241 Protection of insulated wire; splice in underground...

  15. 49 CFR 234.241 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... underground wire. 234.241 Section 234.241 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION GRADE CROSSING SAFETY, INCLUDING... Testing Maintenance Standards § 234.241 Protection of insulated wire; splice in underground...

  16. 49 CFR 234.241 - Protection of insulated wire; splice in underground wire.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... underground wire. 234.241 Section 234.241 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION GRADE CROSSING SAFETY, INCLUDING... Testing Maintenance Standards § 234.241 Protection of insulated wire; splice in underground...

  17. Destabilization of Ag nanoislands on Ag(100) by adsorbed sulfur

    SciTech Connect

    Shen, Mingmin; Russell, Selena M.; Liu, Da-Jiang; Thiel, Patricia A.

    2011-10-17

    Sulfur accelerates coarsening of Ag nanoislands on Ag(100) at 300 K, and this effect is enhanced with increasing sulfur coverage over a range spanning a few hundredths of a monolayer, to nearly 0.25 monolayers. We propose that acceleration of coarsening in this system is tied to the formation of AgS{sub 2} clusters primarily at step edges. These clusters can transport Ag more efficiently than can Ag adatoms (due to a lower diffusion barrier and comparable formation energy). The mobility of isolated sulfur on Ag(100) is very low so that formation of the complex is kinetically limited at low sulfur coverages, and thus enhancement is minimal. However, higher sulfur coverages force the population of sites adjacent to step edges, so that formation of the cluster is no longer limited by diffusion of sulfur across terraces. Sulfur exerts a much weaker effect on the rate of coarsening on Ag(100) than it does on Ag(111). This is consistent with theory, which shows that the difference between the total energy barrier for coarsening with and without sulfur is also much smaller on Ag(100) than on Ag(111).

  18. Wired

    NASA Astrophysics Data System (ADS)

    Carlowicz, Michael

    Every American grade school and library ought to have free access to the Internet, and universities and institutions ought to have better access, according to the Clinton Administration.In an October 10 speech in Knoxville, Tennessee, President Clinton proposed that all of the nation's 100,000 public schools and 9,000 libraries receive a two-tiered E-rate (education rate) for access to Internet services. All schools and libraries should receive basic connections for free, as well as deep discounts on video conferencing and highspeed connections (with prices influenced by how much the school can afford to pay). The basic connections (and part of the cost of the more sophisticated connections) would be paid from a special federal fund that currently provides below-cost phone service to households in poor and rural areas. That fund is currently drawn from fees assessed on local and long-distance telephone providers; the Clinton Administration would have cable operators and cellular service providers contribute as well. Companies that provide Internet services would be paid at the best available commercial rate.

  19. Wired.

    ERIC Educational Resources Information Center

    Conklin, Aaron R.

    1998-01-01

    Discusses technology's impact on scoreboard design: the development of the light-emitting diode (LED) display. How the LED system works is explained, as are the advantages and disadvantages of LED compared with incandescent lamp boards. Final comments address deciding on materials for scoreboard casings. (GR)

  20. Magnified fluorescence detection of silver(I) ion in aqueous solutions by using nano-graphite-DNA hybrid and DNase I.

    PubMed

    Wei, Yin; Li, Bianmiao; Wang, Xu; Duan, Yixiang

    2014-08-15

    This paper describes a novel approach utilizing nano-graphite-DNA hybrid and DNase I for the amplified detection of silver(I) ion in aqueous solutions for the first time. Nano-graphite can effectively quench the fluorescence of dye-labeled cytosine-rich single-stranded DNA due to its strong π-π stacking interactions; however, in the presence of Ag(+), C-Ag(+)-C coordination induces the probe to fold into a hairpin structure, which does not adsorb on the surface of nano-graphite and thus retains the dye fluorescence. Meanwhile, the hairpin structure can be cleaved by DNase I, and in such case Ag(+) is delivered from the complex. The released Ag(+) then binds other dye-labeled single-stranded DNA on the nano-graphite surface, and touches off another target recycling, resulting in the successive release of dye-labeled single-stranded DNA from the nano-graphite, which leads to significant amplification of the signal. The present magnification sensing system exhibits high sensitivity toward Ag(+) with a limit of detection of 0.3nM (S/N=3), which is much lower than the standard for Ag(+) in drinking water recommended by the Environmental Protection Agency (EPA). The selectivity of the sensor for Ag(+) against other biologically and environmentally related metal ions is outstanding due to the high specificity of C-Ag(+)-C formation. Moreover, the sensing system is used for the determination of Ag(+) in river water samples with satisfying results. The proposed assay is simple, cost-effective, and might open the door for the development of new assays for other metal ions or biomolecules. PMID:24657649

  1. Superconducting-wire fabrication. Final report

    SciTech Connect

    Glad, W.E.; Chase, G.G.

    1990-05-01

    Experiments were done leading to the fabrication of high-temperature superconducting composite wire. Bulk superconductor was characterized by using optical microscopy, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. The chemical compatibility of superconducting materials with a number of metal sheathing candidates was tested, with silver offering the best compatibility. Wire was fabricated by drawing 0.250-inch-diameter silver tubing packed with superconducting powder. Single core wires were drawn to 0.037-inch diameter. The best critical current performance (660 A/cm2) for leaded bismuth 2-2-2-3 material was achieved by flattening single-core wire before heat treatment.

  2. Two-stage epitaxial growth of vertically-aligned SnO2 nano-rods on(001) ceria

    DOE PAGESBeta

    Solovyov, Vyacheslav F.; Wu, Li-jun; Rupich, Martin W.; Sathyamurthy, Srivatsan; Li, Xiaoping; Li, Qiang

    2014-09-20

    Growth of high-aspect ratio oriented tin oxide, SnO2, nano-rods is complicated by a limited choice of matching substrates. We show that a (001) cerium oxide, CeO2, surface uniquely enables epitaxial growth of tin-oxide nano-rods via a two-stage process. First, (100) oriented nano-wires coat the ceria surface by lateral growth, forming a uniaxially-textured SnO2 deposit. Second, vertical SnO2nano-rods nucleate on the deposit by homoepitaxy. We demonstrate growth of vertically oriented 1-2 μm long nano-rods with an average diameter of ≈20 nm.

  3. Two-stage epitaxial growth of vertically-aligned SnO2 nano-rods on (001) ceria

    SciTech Connect

    Solovyov, VF; Wu, LJ; Rupich, MW; Sathyamurthy, S; Li, XP; Li, Q

    2014-12-15

    Growth of high-aspect ratio oriented tin oxide, SnO2, nano-rods is complicated by a limited choice of matching substrates. We show that a (001) cerium oxide, CeO2, surface uniquely enables epitaxial growth of tin-oxide nano-rods via a two-stage process. First, (100) oriented nano-wires coat the ceria surface by lateral growth, forming a uniaxially-textured SnO2 deposit. Second, vertical SnO2 nano-rods nucleate on the deposit by homoepitaxy. We demonstrate growth of vertically oriented 1-2 mu m long nano-rods with an average diameter of approximate to 20 nm. 2014 Elsevier B.V. All rights reserved.

  4. AGS preinjector improvement

    SciTech Connect

    Alessi, J.G.; Brennan, J.M.; Brown, H.N.; Brodowski, J.; Gough, R.; Kponou, A.; Prelec, K.; Staples, J.; Tanabe, J.; Witkover, R.

    1987-01-01

    In 1984, a polarized H/sup -/ source was installed to permit the acceleration of polarized protons in the AGS, using a low current, 750 keV RFQ Linear Accelerator as the preinjector. This RFQ was designed by LANL and has proved to be quite satisfactory and reliable. In order to improve the reliability and simplify maintenance of the overall AGS operations, it has been decided to replace one of the two 750 keV Cockcroft-Waltons (C-W) with an RFQ. The design of a new high current RFQ has been carried out by LBL and is also being constructed there. This paper describes the preinjector improvement project, centered around that RFQ, which is underway at BNL.

  5. Theoretical and Experimental Studies of Radiation from Z-Pinch Complex Wire Arrays and Applications

    NASA Astrophysics Data System (ADS)

    Weller, Michael Eugene

    In the research area of high energy density plasmas an ever increasing goal is searching for higher efficient radiators, particularly in z-pinch plasmas, and their applications. This goal is a major focus of this dissertation and implements both theoretical and experimental tools in the process. The theoretical tools involve the Wire Ablation Dynamics Model (WADM) to infer z-pinch implosion characteristics and various non-local thermodynamic equilibrium (LTE) kinetic models to understand the radiative properties of plasmas, including a new model for L-shell Ag. The experimental tools includes an advanced set of diagnostics, in particular a newly developed time-gated hard x-ray spectrometer to gain an understanding as to how these plasmas radiate in time, particularly in the 0.7 - 4.4 A range. The experiments predominately took place on the 1.7 MA Zebra generator at the Nevada Terawatt Facility (NTF) at the University of Nevada, Reno (UNR). Traditional nested cylindrical wire arrays with mixed materials (brass and Al, Mo and Al) were tested to understand how the inner and outer arrays implode and radiate. Novel planar wire arrays, which have been shown to be very powerful radiation sources, arranged in single, double, and triple wire array configurations were tested with Mo and Ag materials, which have both been shown to be powerful radiators, and also mixed with Al to understand opacity effects and how a mixture of two different plasmas radiate. Radiation from the extreme ultraviolet (EUV) range has also been of recent interest due the substantial contribution into total radiation yields. Therefore EUV radiation of M-shell Cu was modeled and benchmarked with spheromak and laser-produced plasma data. Lastly, lasing gain from L-shell Ag is calculated as an application of the aforementioned model to evaluate whether lasing might be occurring in wire array z-pinches. In connection to creating a uniform plasma column to measure lasing lines, the split double planar wire

  6. Effect of an Axial Wire on Conical Wire Array Z-Pinch Radiation

    SciTech Connect

    Presura, R.; Martinez, D.; Wright, S.; Plechaty, C.; Neff, S.; Wanex, L.; Ampleford, D. J.

    2009-01-21

    Adding a wire on the axis of wire arrays significantly affects the x-ray emission of the conical arrays, and much less that of the cylindrical ones. The radiation of the conical wire arrays increases with the thickness of the central wire, surpassing that of the equivalent cylindrical arrays. Significant energy is emitted early on, around the time of the conical shock formation, before the pinch stagnation.

  7. 47 CFR 76.804 - Disposition of home run wiring.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Disposition of home run wiring. 76.804 Section... MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Cable Inside Wiring § 76.804 Disposition of home run wiring. (a) Building-by-building disposition of home run wiring. (1) Where an MVPD owns the home run wiring in an...

  8. 47 CFR 76.804 - Disposition of home run wiring.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Disposition of home run wiring. 76.804 Section... MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Cable Inside Wiring § 76.804 Disposition of home run wiring. (a) Building-by-building disposition of home run wiring. (1) Where an MVPD owns the home run wiring in an...

  9. 47 CFR 76.804 - Disposition of home run wiring.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Disposition of home run wiring. 76.804 Section... MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Cable Inside Wiring § 76.804 Disposition of home run wiring. (a) Building-by-building disposition of home run wiring. (1) Where an MVPD owns the home run wiring in an...

  10. 46 CFR 129.340 - Cable and wiring.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Power Sources and Distribution Systems § 129.340 Cable and wiring. (a) If individual wires, rather than... tank, unless it supplies power to equipment in the tank; and (9) Have sheathing or wire insulation...) Cable and wire in power and lighting circuits must be #14 AWG or larger. Cable and wire in control...

  11. Processing A Printed Wiring Board By Single Bath Electrodeposition

    DOEpatents

    Meltzer, Michael P.; Steffani, Christopher P.; Gonfiotti, Ray A.

    2003-04-15

    A method of processing a printed wiring board by single bath electrodeposition. Initial processing steps are implemented on the printed wiring board. Copper is plated on the printed wiring board from a bath containing nickel and copper. Nickel is plated on the printed wiring board from the bath containing nickel and copper and final processing steps are implemented on the printed wiring board.

  12. Processing a printed wiring board by single bath electrodeposition

    DOEpatents

    Meltzer, Michael P.; Steffani, Christopher P.; Gonfiotti, Ray A.

    2010-12-07

    A method of processing a printed wiring board. Initial processing steps are implemented on the printed wiring board. Copper is plated on the printed wiring board from a bath containing nickel and copper. Nickel is plated on the printed wiring board from a bath containing nickel and copper and final processing steps are implemented on the printed wiring board.

  13. Nano-optical observation of cascade switching in a parallel superconducting nanowire single photon detector

    SciTech Connect

    Heath, Robert M. Tanner, Michael G.; Casaburi, Alessandro; Hadfield, Robert H.; Webster, Mark G.; San Emeterio Alvarez, Lara; Jiang, Weitao; Barber, Zoe H.; Warburton, Richard J.

    2014-02-10

    The device physics of parallel-wire superconducting nanowire single photon detectors is based on a cascade process. Using nano-optical techniques and a parallel wire device with spatially separate pixels, we explicitly demonstrate the single- and multi-photon triggering regimes. We develop a model for describing efficiency of a detector operating in the arm-trigger regime. We investigate the timing response of the detector when illuminating a single pixel and two pixels. We see a change in the active area of the detector between the two regimes and find the two-pixel trigger regime to have a faster timing response than the one-pixel regime.

  14. Recent progress in micro and nano-joining

    NASA Astrophysics Data System (ADS)

    Zhou, Y.; Hu, A.; Khan, M. I.; Wu, W.; Tam, B.; Yavuz, M.

    2009-05-01

    Micro and nano-joining has been identified as a key enabling technology in the construction of micromechanical and microelectronic devices. The current article reviews recent progress in micro and nano-joining. In particular, laser micro-welding (LMW) of crossed 316 LVM stainless steel (SS) wire was compared to conventional resistance micro-welding (RMW) and was successfully employed in welding a Pt-Ir /SS dissimilar combination. Welding of Au nanoparticles was realized using femtosecond laser irradiation and its application in the surface enhanced Raman spectroscopy was investigated. Brazing between carbon nanotube (CNT) bundles and Ni electrodes was attained in vacuum, resulting in the development of a novel CNT filament of incandescent lamps.

  15. Characterization and antimicrobial performance of nano silver coatings on leather materials

    PubMed Central

    Lkhagvajav, N.; Koizhaiganova, M.; Yasa, I.; Çelik, E.; Sari, Ö.

    2015-01-01

    In this study, the characterization and the antimicrobial properties of nano silver (nAg) coating on leather were investigated. For this purpose, turbidity, viscosity and pH of nAg solutions prepared by the sol-gel method were measured. The formation of films from these solutions was characterized according to temperature by Differential Thermal Analysis-Thermogravimetry (DTA-TG) equipment. The surface morphology of treated leathers was observed using Scanning Electron Microscopy (SEM). The antimicrobial performance of nAg coatings on leather materials to the test microorganisms as Escherichia coli , Staphylococcus aureus , Candida albicans and Aspergillius niger was evaluated by the application of qualitative (Agar overlay method) and quantitative (percentage of microbial reduction) tests. According to qualitative test results it was found that 20 μg/cm 2 and higher concentrations of nAg on the leather samples were effective against all microorganisms tested. Moreover, quantitative test results showed that leather samples treated with 20 μg/cm 2 of nAg demonstrated the highest antibacterial activity against E. coli with 99.25% bacterium removal, whereas a 10 μg/cm 2 concentration of nAg on leather was enough to exhibit the excellent percentage reduction against S. aureus of 99.91%. The results are promising for the use of colloidal nano silver solution on lining leather as antimicrobial coating. PMID:26221087

  16. Tuning a Tetrahertz Wire Laser

    NASA Technical Reports Server (NTRS)

    Qin, Qi; Williams, Benjamin S.; Kumar, Sushil; Reno, John L.; Hu, Qing

    2009-01-01

    Tunable terahertz lasers are desirable in applications in sensing and spectroscopy because many biochemical species have strong spectral fingerprints at terahertz frequencies. Conventionally, the frequency of a laser is tuned in a similar manner to a stringed musical instrument, in which pitch is varied by changing the length of the string (the longitudinal component of the wave vector) and/ or its tension (the refractive index). However, such methods are difficult to implement in terahertz semiconductor lasers because of their poor outcoupling efficiencies. Here, we demonstrate a novel tuning mechanism based on a unique 'wire laser' device for which the transverse dimension w is much much less than lambda. Placing a movable object close to the wire laser manipulates a large fraction of the waveguided mode propagating outside the cavity, thereby tuning its resonant frequency. Continuous single-mode redshift and blueshift tuning is demonstrated for the same device by using either a dielectric or metallic movable object. In combination, this enables a frequency tuning of approximately equal to 137 GHz (3.6%) from a single laser device at approximately equal to 3.8 THz.

  17. Preparation of visible-light nano-photocatalysts through decoration of TiO2 by silver nanoparticles in inverse miniemulsions.

    PubMed

    Cao, Zhihai; Zhu, Shudi; Qu, Hui; Qi, Dongming; Ziener, Ulrich; Yang, Liu; Yan, Yingjie; Yang, Haitang

    2014-12-01

    Ag/TiO2 nanocomposites were prepared through combination of a sol-gel process of a titanium precursor in inverse miniemulsions and in situ reduction of silver ions in the "nanoreactors". The morphological investigation shows that Ag nanoparticles are mainly located on the surface of TiO2 nano-supports because of the fast reduction rate of Ag ions by hydrazine. Ag/TiO2 nanocomposites with amorphous or anatase TiO2 phase displayed high visible-light catalytic activity for degradation of Rhodamine B. The photoactivity of Ag/anatase TiO2 nanocomposites could be influenced by the Ag content that could be conveniently tuned by the loading of silver salts. The influence of the loading of silver salts on the particle properties of the Ag/TiO2 nanocomposites was investigated systematically. PMID:25217730

  18. Ag Nanodots Emitters Embedded in a Nanocrystalline Thin Film Deposited on Crystalline Si Solar Cells.

    PubMed

    Park, Seungil; Ryu, Sel Gi; Ji, HyungYong; Kim, Myeong Jun; Peck, Jong Hyeon; Kim, Keunjoo

    2016-06-01

    We fabricated crystalline Si solar cells with the inclusion of various Ag nanodots into the additional emitters of nanocrystallite Si thin films. The fabricated process was carried out on the emitter surface of p-n junction for the textured p-type wafer. The Ag thin films were deposited on emitter surfaces and annealed at various temperatures. The amorphous Si layers were also deposited on the Ag annealed surfaces by hot-wire chemical vapor deposition and then the deposited layers were doped by the second n-type doping process to form an additional emitter. From the characterization, both the Ag nanodots and the deposited amorphous Si thin films strongly reduce photo-reflectances in a spectral region between 200-400 nm. After embedding Ag nanodots in nanocrystallite Si thin films, a conversion efficiency of the sample with added emitter was achieved to 15.1%, which is higher than the 14.1% of the reference sample and the 14.7% of the de-posited sample with a-Si:H thin film after the Ag annealing process. The additional nanocrystallite emitter on crystalline Si with Ag nanodots enhances cell properties. PMID:27427665

  19. Ag-based semiconductor photocatalysts in environmental purification

    NASA Astrophysics Data System (ADS)

    Li, Jiade; Fang, Wen; Yu, Changlin; Zhou, Wanqin; zhu, Lihua; Xie, Yu

    2015-12-01

    Over the past decades, with the fast development of global industrial development, various organic pollutants discharged in water have become a major source of environmental pollution in waste fields. Photocatalysis, as green and environmentally friendly technology, has attracted much attention in pollutants degradation due to its efficient degradation rate. However, the practical application of traditional semiconductor photocatalysts, e.g. TiO2, ZnO, is limited by their weak visible light adsorption due to their wide band gaps. Nowadays, the study in photocatalysts focuses on new and narrow band gap semiconductors. Among them, Ag-based semiconductors as promising visible light-driven photocatalysts have aroused much interesting due to their strong visible light responsibility. Most of Ag-based semiconductors could exhibit high initial photocatalytic activity. But they easy suffer from poor stability because of photochemical corrosion. Design heterojunction, increasing specific surface area, enriching pore structure, regulating morphology, controlling crystal facets, and producing plasmonic effects were considered as the effective strategies to improve the photocatalytic performance of Ag-based photocatalyts. Moreover, combining the superior properties of carbon materials (e.g. carbon quantum dots, carbon nano-tube, carbon nanofibers, graphene) with Ag-based semiconductor could produce high efficient composite photocatalyts.

  20. Homogenous BSCCO-2212 Round Wires for Very High Field Magnets

    SciTech Connect

    Dr. Scott Campbell Dr. Terry Holesinger Dr. Ybing Huang

    2012-06-30

    the very significant advantage of an extremely high H{sub c2}. For this reason, Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y} (Bi-2212, or 2212) in the form of a multifilamentary Ag alloy matrix composite is beginning to attract the interest of the magnet community for future extremely high-field magnets or magnet-insert coils for 4.2K operation. Fig. 1 shows an example of excellent JE (engineering current density) in Bi-2212 round wire at fields up to 45 T, demonstrating the potential for high field applications of this material. For comparison, the Nb{sub 3}Sn wires used in magnets in the 16-18 T range typically perform with J{sub E} in the range 200-500 A/mm{sup 2}; the Bi-2212 wire retains this level of performance to fields at least as high as 45 T, and probably significantly higher. Bi-2212 conductors have in fact been used to generate a 25 T field in a superconducting insert magnet. These two factors- the very high field critical current performance of Bi-2212, and the already demonstrated capability of this material for high field magnets up to 25 T, strongly suggest this material as a leading contender for the next generation high field superconducting (HFS) wire. This potential was recognized by the US Academy of Science's Committee on Opportunities in High Magnetic Field Science. Their report of the same name specifically calls out the high field potential for this material, and suggests that 30 T magnets appear feasible based on the performance of 2212. There are several requirements for HFS conductors. The most obvious is J{sub E} (B, T), the engineering current density at the field and temperature of operation. As shown in Fig. 1, Bi-2212 excels in this regard. Stability requirements for magnets dictate that the effective filament diameter should be less than 30 micrometers, something that Bi-2212 multifilamentary wire can uniquely satisfy among the HFS superconducting wire technologies. Additional requirements include mechanical properties that prevent stress