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Sample records for ag nw networks

  1. Si NW network by Ag nanoparticle assisted etching and TiO2/Si NWs as photodetector

    NASA Astrophysics Data System (ADS)

    Bhowmik, Kishan; Mondal, Aniruddha

    2015-03-01

    Glancing angle deposited silver (Ag) nanoparticles (NPs) were employed to fabricate the silicon (Si) nanowire (NW) network on p-type Si substrate. The Si NWs were characterized by X-ray diffraction, which shows the (311) oriented single crystalline nature. The FEG-SEM images show that the nanowire diameters are in the order of 60-180 nm. The photoluminescence emission at 525 nm was recognized from the Si NWs. The Ag-TiO2 contacts exhibit Schottky behavior and higher photoconduction was observed for TiO2-Si NW detector than that of TiO2 Thin film under illumination up to 2.5 V applied potential. A threefold enhanced photodetection for the Silicon nanowire device was observed compared to the TiO2 thin film device, under applied voltages of 0.4-1.5 V. [Figure not available: see fulltext.

  2. Ag@Ni core-shell nanowire network for robust transparent electrodes against oxidation and sulfurization.

    PubMed

    Eom, Hyeonjin; Lee, Jaemin; Pichitpajongkit, Aekachan; Amjadi, Morteza; Jeong, Jun-Ho; Lee, Eungsug; Lee, Jung-Yong; Park, Inkyu

    2014-10-29

    Silver nanowire (Ag NW) based transparent electrodes are inherently unstable to moist and chemically reactive environment. A remarkable stability improvement of the Ag NW network film against oxidizing and sulfurizing environment by local electrodeposition of Ni along Ag NWs is reported. The optical transmittance and electrical resistance of the Ni deposited Ag NW network film can be easily controlled by adjusting the morphology and thickness of the Ni shell layer. The electrical conductivity of the Ag NW network film is increased by the Ni coating via welding between Ag NWs as well as additional conductive area for the electron transport by electrodeposited Ni layer. Moreover, the chemical resistance of Ag NWs against oxidation and sulfurization can be dramatically enhanced by the Ni shell layer electrodeposited along the Ag NWs, which provides the physical barrier against chemical reaction and diffusion as well as the cathodic protection from galvanic corrosion. PMID:24961495

  3. Transparent and conductive PEDOT:PSS/Ag NW/PEDOT:PSS hybrid films prepared by spin-coating at room temperature

    NASA Astrophysics Data System (ADS)

    Qingqing, Yue; Jinliang, Yan; Delan, Meng

    2015-12-01

    PEDOT:PSS/Ag NW/PEDOT:PSS hybrid films were deposited on PET substrates by the spin coating technique at room temperature. The optical transmittance, sheet resistance, crystallization and surface morphology were characterized by using the double beam spectrophotometer, Hall effect system, X-ray diffractometer and field emission scanning electron microscopy. XRD patterns of the hybrid films display characteristic diffraction peaks of Ag (111) and Ag (200), and the Ag NW networks have a polycrystalline structure with a Ag (111) preferred orientation. A high transmittance of 83.95% at the 550 nm wavelength and a low sheet resistance of 21.98 Ω/□ are achieved for 3-PEDOT:PSS/5-Ag NW/3-PEDOT:PSS hybrid films. Project supported by the National Natural Science Foundation of China (No. 10974077), and the Innovation Project of Shandong Graduate Education, China (No. SDYY13093).

  4. Flexible transparent conducting composite films using a monolithically embedded AgNW electrode with robust performance stability

    NASA Astrophysics Data System (ADS)

    Im, Hyeon-Gyun; Jin, Jungho; Ko, Ji-Hoon; Lee, Jaemin; Lee, Jung-Yong; Bae, Byeong-Soo

    2013-12-01

    We report on the performance of an all-in-one flexible hybrid conducting film employing a monolithically embedded AgNW transparent electrode and a high-performance glass-fabric reinforced composite substrate (AgNW-GFRHybrimer film). Specifically, we perform in-depth investigations on the stability of the AgNW-GFRHybrimer film against heat, thermal oxidation, and wet chemicals to demonstrate the potential of the hybrid conducting film as a robust electrode platform for thin-film optoelectronic devices. With the ease of large-area processability, smooth surface topography, and robust performance stability, the AgNW-GFRHybrimer film can be a promising platform for high-performance optoelectronic devices.We report on the performance of an all-in-one flexible hybrid conducting film employing a monolithically embedded AgNW transparent electrode and a high-performance glass-fabric reinforced composite substrate (AgNW-GFRHybrimer film). Specifically, we perform in-depth investigations on the stability of the AgNW-GFRHybrimer film against heat, thermal oxidation, and wet chemicals to demonstrate the potential of the hybrid conducting film as a robust electrode platform for thin-film optoelectronic devices. With the ease of large-area processability, smooth surface topography, and robust performance stability, the AgNW-GFRHybrimer film can be a promising platform for high-performance optoelectronic devices. Electronic supplementary information (ESI) available: Further characteristics of AgNW-GFRHybrimer films and thermal oxidation of AgNW on glass. See DOI: 10.1039/c3nr05348b

  5. Reversibly Stretchable, Optically Transparent Radio-Frequency Antennas Based on Wavy Ag Nanowire Networks.

    PubMed

    Kim, Byoung Soo; Shin, Keun-Young; Pyo, Jun Beom; Lee, Jonghwi; Son, Jeong Gon; Lee, Sang-Soo; Park, Jong Hyuk

    2016-02-01

    We report a facile approach for producing reversibly stretchable, optically transparent radio-frequency antennas based on wavy Ag nanowire (NW) networks. The wavy configuration of Ag NWs is obtained by floating the NW networks on the surface of water, followed by compression. Stretchable antennas are prepared by transferring the compressed NW networks onto elastomeric substrates. The resulting antennas show excellent performance under mechanical deformation due to the wavy configuration, which allows the release of stress applied to the NWs and an increase in the contact area between NWs. The antennas formed from the wavy NW networks exhibit a smaller return loss and a higher radiation efficiency when strained than the antennas formed from the straight NW networks, as well as an improved stability in cyclic deformation tests. Moreover, the wavy NW antennas require a relatively small quantity of NWs, which leads to low production costs and provides an optical transparency. These results demonstrate the potential of these wavy Ag NW antennas in applications of wireless communications for wearable systems. PMID:26760896

  6. Application of patterned Ag-nanowire networks to transparent thin-film heaters and electrodes for organic light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Kim, Seung-Rok; Triambulo, Ross E.; Kim, Jin-Hoon; Park, Jaeyoon; Jeong, Unyong; Park, Jin-Woo

    2016-06-01

    We present patterned Ag-nanowire (AgNW) networks for their application to transparent electrodes in flexible devices. Using capillary-force-based soft lithography (CFL), we formed 25- to 30-µm-wide line patterns of AgNWs on flexible polymer substrates. Organic light-emitting diodes (OLEDs) and transparent thin-film heaters (TFHs) were successfully fabricated on the patterned substrates, which verified the potential of AgNW patterns formed by CFL as interconnects in flexible devices.

  7. Flexible transparent conducting composite films using a monolithically embedded AgNW electrode with robust performance stability.

    PubMed

    Im, Hyeon-Gyun; Jin, Jungho; Ko, Ji-Hoon; Lee, Jaemin; Lee, Jung-Yong; Bae, Byeong-Soo

    2014-01-21

    We report on the performance of an all-in-one flexible hybrid conducting film employing a monolithically embedded AgNW transparent electrode and a high-performance glass-fabric reinforced composite substrate (AgNW-GFRHybrimer film). Specifically, we perform in-depth investigations on the stability of the AgNW-GFRHybrimer film against heat, thermal oxidation, and wet chemicals to demonstrate the potential of the hybrid conducting film as a robust electrode platform for thin-film optoelectronic devices. With the ease of large-area processability, smooth surface topography, and robust performance stability, the AgNW-GFRHybrimer film can be a promising platform for high-performance optoelectronic devices. PMID:24284890

  8. Large-scale fabrication and application of magnetite coated Ag NW-core water-dispersible hybrid nanomaterials.

    PubMed

    Wang, Baoyu; Zhang, Min; Li, Weizhen; Wang, Linlin; Zheng, Jing; Gan, Wenjun; Xu, Jingli

    2015-05-01

    In this work, we report a large scale synthetic procedure that allows attachment of magnetite nanoparticles onto Ag NWs in situ, which was conducted in a triethylene glycol (TREG) solution with iron acetylacetonate and Ag NWs as starting materials. The as-prepared Ag NW/Fe3O4 NP composites are well characterized by SEM, TEM, XRD, XPS, FT-IR, and VSM techniques. It was found that the mass ratio of iron acetylacetonate to Ag NWs plays a crucial role in controlling the amount of magnetite nanoparticles decorated on the Ag NWs. The resulting Ag NW/Fe3O4 NP composites exhibit superparamagnetic properties at room temperature, and can be well dispersed in aqueous and organic solutions, which is greatly beneficial for their application and functionality. Thus, the as-prepared magnetic silver nanowires show good catalytic activity, using the catalytic reduction of methylene blue (MB) as a model reaction. Furthermore, the Ag NW/Fe3O4 NP composites can be functionalized with polydopamine (Pdop), resorcinol-formaldehyde resin (PFR), and SiO2, respectively, in aqueous/ethanol solution. Meanwhile they can also be coated with polyphosphazene (PZS) in organic solution, resulting in a unique nanocable with well-defined core shell structures. Besides, taking Ag NW/Fe3O4@SiO2 as an example, a hollow magnetic silica nanotube can be obtained with the use of Ag NWs as physical templates and a solution of ammonium and H2O2. These can greatly improve the application of the Ag NW/Fe3O4 NP composites. The as-synthesized above nanocomposites have high potential for applications in the fields of polymers, wastewater treatment, sensors, and biomaterials. PMID:25815705

  9. Atmospheric-Pressure Processed Silver Nanowire (Ag-NW)/ZnO Composite Transparent Conducting Contacts

    SciTech Connect

    Perkins, John D.; Aggarwal, Shruti; van Hest, Maikel F. A. M.; Ginley, David S.

    2015-06-14

    Composite transparent contacts (TCs) based on metal nanowires and metal oxide matrix materials hold great promise for high performance transparent contacts for photovoltaics and opto-electronic technologies with the potential of all-atmospheric pressure processing. The metal nanowire mesh can provide both electrical conductivity and mechanical robustness against bending while the matrix material can both control the electrical interface and protect the metal nanowires. Here, we demonstrate all atmospheric pressure processed Ag-NW/ZnO composite TCs that are 90% transparent in the visible with sheet resistance Rs ~= 10 Ohms/sq. In addition, the composite TCs have higher infrared transmission than conventional TCO films with the same sheet resistance.

  10. Large-scale uniform Ag-NW tip array with enriched sub-10-nm gaps as SERS substrate for rapid determination of trace PCB77

    NASA Astrophysics Data System (ADS)

    Xu, Wei; Meng, Guowen; Huang, Qing; Hu, Xiaoye; Huang, Zhulin; Tang, Haibin; Zhang, Junxi

    2013-04-01

    Ag-nanowire (Ag-NW) tip arrays with high density sub-10-nm gaps have been achieved via anodic aluminum oxide (AAO) template-assistant approach, and exhibit superior surface enhanced Raman scattering (SERS) performance. The Ag-NW tip arrays were fabricated via the following procedures. Firstly, the pore walls of the AAO were thinned to the sub-10-nm scale, and then a layer of Ag thin film was deposited on the AAO via silver mirror reaction. Subsequently, a layer of gold (Au) film was coated on the Ag film via ion-beam evaporation to serve as the electrode for the electrodeposition growth of Ag-NWs. Finally, the Ag-NW tip arrays with sub-10-nm gaps were exposed from the AAO template by physical milling and a subsequent chemical etching. The SERS activity of the as-fabricated substrate is verified by measuring the probe molecules of R6G and polychlorinated biphenyls (PCBs). To further improve the detection sensitivity for PCBs, the substrate was modified with β-cyclodextrin to increase its efficiency of capturing PCBs molecules. As a result, the as-fabricated SERS substrate can be utilized to measure trace 3,3',4,4'-tetrachlorinated biphenyls (PCB77) with a concentration as low as 1 × 10-10 M.

  11. Solution-processed highly conductive PEDOT:PSS/AgNW/GO transparent film for efficient organic-Si hybrid solar cells.

    PubMed

    Xu, Qiaojing; Song, Tao; Cui, Wei; Liu, Yuqiang; Xu, Weidong; Lee, Shuit-Tong; Sun, Baoquan

    2015-02-11

    Hybrid solar cells based on n-Si/poly(3,4-ethylenedioxythiophene):poly(styrene- sulfonate) (PEDOT:PSS) heterojunction promise to be a low cost photovoltaic technology by using simple device structure and easy fabrication process. However, due to the low conductivity of PEDOT:PSS, a metal grid deposited by vacuum evaporation method is still required to enhance the charge collection efficiency, which complicates the device fabrication process. Here, a solution-processed graphene oxide (GO)-welded silver nanowires (AgNWs) transparent conductive electrode (TCE) was employed to replace the vacuum deposited metal grid. A unique "sandwich" structure was developed by embedding an AgNW network between PEDOT:PSS and GO with a figure-of-merit of 8.6×10(-3) Ω(-1), which was even higher than that of sputtered indium tin oxide electrode (6.6×10(-3) Ω(-1)). A champion power conversion efficiency of 13.3% was achieved, because of the decreased series resistance of the TCEs as well as the enhanced built-in potential (Vbi) in the hybrid solar cells. The TCEs were obtained by facile low-temperature solution process method, which was compatible with cost-effective mass production technology. PMID:25599588

  12. Outer synchronization investigation between WS and NW small-world networks with different node numbers

    NASA Astrophysics Data System (ADS)

    Zhou, Guangye; Li, Chengren; Li, Tingting; Yang, Yi; Wang, Chen; He, Fangjun; Sun, Jingchang

    2016-09-01

    Some typical dual-ring erbium-doped fiber lasers with hyperchaos behaviors are taken as nodes to construct two kinds of small-world networks-NW and WS networks. Based on Lyapunov stability theorem, the appropriate controllers are designed and the outer synchronization between the small-world networks with diverse structures and different node numbers is further investigated. The simulation results show that the perfect synchronization between the complex small-world networks is realized, which is of potential application for all optical communication network.

  13. Facile control of C₂H₅OH sensing characteristics by decorating discrete Ag nanoclusters on SnO₂ nanowire networks.

    PubMed

    Hwang, In-Sung; Choi, Joong-Ki; Woo, Hyung-Sik; Kim, Sun-Jung; Jung, Se-Yeon; Seong, Tae-Yeon; Kim, Il-Doo; Lee, Jong-Heun

    2011-08-01

    The effect of Ag decoration on the gas sensing characteristics of SnO(2) nanowire (NW) networks was investigated. The Ag layers with thicknesses of 5-50 nm were uniformly coated on the surface of SnO(2) NWs via e-beam evaporation, which were converted into isolated or continuous configurations of Ag islands by heat treatment at 450 °C for 2 h. The SnO(2) NWs decorated by isolated Ag nano-islands displayed a 3.7-fold enhancement in gas response to 100 ppm C(2)H(5)OH at 450 °C compared to pristine SnO(2) NWs. In contrast, as the Ag decoration layers became continuous, the response to C(2)H(5)OH decreased significantly. The enhancement and deterioration of the C(2)H(5)OH sensing characteristics by the introduction of the Ag decoration layer were strongly governed by the morphological configurations of the Ag catalysts on SnO(2) NWs and their sensitization mechanism. PMID:21744869

  14. Fracture network heterogeneity in continental lithosphere: An example from the Lewisian Gneiss Complex, NW Scotland

    NASA Astrophysics Data System (ADS)

    Martin, J. C.; Holdsworth, R. E.; McCaffrey, K.; Conway, A.; Krabendam, M.

    2009-12-01

    Pre-existing ductile and brittle structures in continental lithosphere are thought to influence the orientation and spatial characteristics of subsequent deformation sets. By using quantitative techniques to describe fracture attributes it should be possible to determine whether these pre-existing weaknesses affect fracture network development. To test this hypothesis, the mainland Lewisian Gneiss Complex (LGC), in NW Scotland is being used as an example. The Late Archaean - Early Proterozoic LGC comprises TTG gneisses, mafic and ultramafic dykes and meta-volcanic and meta-sedimentary sequences that were accreted as a series of terranes during the Precambrian. Three regional fracture trends are recognised (from oldest to youngest); (1) steeply-dipping NW-SE Paleoproterozoic faults (mainly sinistral oblique) that are preferentially developed as foliation-parallel structures in pre-existing ductile shear zones (2) N-S to ENE-WSW trending, hematite stained normal fault ‘ladder fractures’ associated with the deposition of the overlying Neoproterozoic (1.2 Ga.) Stoer Group rift-related sediments. (3) NE-SW trending younger (likely Mesozoic) faults. Each fault set is associated with characteristic fault rock and mineral assemblages. The present project focuses on characterising these fracture sets on the regional to outcrop scale, using a variety of remote and fieldwork analysis techniques. Regional data comprises 2D lineament maps created from high resolution NEXTMap® digital elevation models. Outcrop data consists of 1D sample lines and 2D photo-mosaics which have allowed fracture attribute characterisations to be made. This project centres on the Assynt and Rhiconich terranes to assess the heterogeneity in fracture networks due to variations in lithology and metamorphic grade. Results from statistical analysis of outcrop and regional orientation data show that the tonalitic and granulite-facies Assynt terrane shows a correlation between intense foliation and

  15. Ag-bridged Ag2O nanowire network/TiO2 nanotube array p-n heterojunction as a highly efficient and stable visible light photocatalyst.

    PubMed

    Liu, Chengbin; Cao, Chenghao; Luo, Xubiao; Luo, Shenglian

    2015-03-21

    A unique Ag-bridged Ag2O nanowire network/TiO2 nanotube array p-n heterojunction (Ag-Ag2O/TiO2 NT) was fabricated by simple electrochemical method. Ag nanoparticles were firstly electrochemically deposited onto the surface of TiO2 NT and then were partly oxidized to Ag2O nanowires while the rest of Ag mother nanoparticles were located at the junctions of Ag2O nanowire network. The Ag-Ag2O/TiO2 NT heterostructure exhibited strong visible-light response, effective separation of photogenerated carriers, and high adsorption capacity. The integration of Ag-Ag2O self-stability structure and p-n heterojunction permitted high and stable photocatalytic activity of Ag-Ag2O/TiO2 NT heterostructure photocatalyst. Under 140-min visible light irradiation, the photocatalytic removal efficiency of both dye acid orange 7 (AO7) and industrial chemical p-nitrophenol (PNP) over Ag-Ag2O/TiO2 NT reached nearly 100% much higher than 17% for AO7 or 13% for PNP over bare TiO2 NT. After 5 successive cycles under 600-min simulated solar light irradiation, Ag-Ag2O/TiO2 NT remained highly stable photocatalytic activity. PMID:25528230

  16. Electrically Robust Metal Nanowire Network Formation by In-Situ Interconnection with Single-Walled Carbon Nanotubes

    PubMed Central

    Woo, Jong Seok; Han, Joong Tark; Jung, Sunshin; Jang, Jeong In; Kim, Ho Young; Jeong, Hee Jin; Jeong, Seung Yol; Baeg, Kang-Jun; Lee, Geon-Woong

    2014-01-01

    Modulation of the junction resistance between metallic nanowires is a crucial factor for high performance of the network-structured conducting film. Here, we show that under current flow, silver nanowire (AgNW) network films can be stabilised by minimizing the Joule heating at the NW-NW junction assisted by in-situ interconnection with a small amount (less than 3 wt%) of single-walled carbon nanotubes (SWCNTs). This was achieved by direct deposition of AgNW suspension containing SWCNTs functionalised with quadruple hydrogen bonding moieties excluding dispersant molecules. The electrical stabilisation mechanism of AgNW networks involves the modulation of the electrical transportation pathway by the SWCNTs through the SWCNT-AgNW junctions, which results in a relatively lower junction resistance than the NW-NW junction in the network film. In addition, we propose that good contact and Fermi level matching between AgNWs and modified SWCNTs lead to the modulation of the current pathway. The SWCNT-induced stabilisation of the AgNW networks was also demonstrated by irradiating the film with microwaves. The development of the high-throughput fabrication technology provides a robust and scalable strategy for realizing high-performance flexible transparent conductor films. PMID:24763208

  17. Bipolar resistive switching behaviors of ITO nanowire networks

    NASA Astrophysics Data System (ADS)

    Li, Qiang; Gong, Zhina; Wang, Shuai; Wang, Jiangteng; Zhang, Ye; Yun, Feng

    2016-02-01

    We have fabricated indium tin oxide (ITO) nanowire (NW) networks on aluminum electrodes using electron beam evaporation. The Ag/ITO-NW networks/Al capacitor exhibits bipolar resistive switching behavior. The resistive switching characteristics of ITO-NW networks are related to the morphology of NWs. The x-ray photoelectron spectroscopy was used to obtain the chemical nature from the NWs surface, investigating the oxygen vacancy state. A stable switching voltages and a clear memory window were observed in needle-shaped NWs. The ITO-NW networks can be used as a new two-dimensional metal oxide material for the fabrication of high-density memory devices.

  18. Facile Patterning of Ag Nanowires Network by Micro-Contact Printing of Siloxane.

    PubMed

    Yoon, Sung-Soo; Khang, Dahl-Young

    2016-09-01

    A simple, low-cost, scalable patterning method has been demonstrated for chemically welded Ag nanowires (AgNWs) network. The chemically welded network of AgNWs on substrates has been patterned by modified microcontact printing (μCP). As an ink for the μCP, uncured high-viscosity siloxane polymer has been applied. Using elastomeric polydimethylsiloxane (PDMS) stamp that has been replicated from micromachined Si master mold by metal-assisted chemical etching, the printed siloxane ink materials have been cured by simple UV/ozone exposure for 3 min, which acts as an etch barrier in ensuing wet-removal of exposed AgNWs network. The proposed patterning technique has no limitation in the choice of substrates and pattern shape, in addition to high resolution. The patterned AgNWs network electrodes have shown excellent optical, electrical, and mechanical performances, such as high flexibility (up to ∼10%) and stretchability (up to 40%). Finally, the patterned AgNWs network electrodes have been applied as a transparent heater, which can be used for rapid raindrop removal or deicing of car windows and outside mirrors. This can be a valuable help for driving safety under harsh weather conditions. PMID:27548278

  19. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel

    NASA Astrophysics Data System (ADS)

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-01

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs.

  20. Low-haze, annealing-free, very long Ag nanowire synthesis and its application in a flexible transparent touch panel.

    PubMed

    Moon, Hyunjin; Won, Phillip; Lee, Jinhwan; Ko, Seung Hwan

    2016-07-22

    Since transparent conducting films based on silver nanowires (AgNWs) have shown higher transmittance and electrical conductivity compared to those of indium tin oxide (ITO) films, the electronics industry has recognized them as promising substitutes. However, due to the higher haze value of AgNW transparent conducting films compared to ITO films, the clarity is decreased when AgNW films are applied to optoelectronic devices. In this study, we develop a highly transparent, low-haze, very long AgNW percolation network. Moreover, we confirm that analyzed chemical roles can easily be applied to different AgNW synthesis methods, and that they have a direct impact on the nanowire shape. Consequently, the lengths of the wires are increased up to 200 μm and the diameters of the wires are decreased up to 45 nm. Using these results, we fabricate highly transparent (96%) conductors (100 Ω/sq) with low-haze (2%) without any annealing process. This electrode shows enhanced clarity compared to previous results due to the decreased diffusive transmittance and scattering. In addition, a flexible touchscreen using a AgNW network is demonstrated to show the performance of modified AgNWs. PMID:27276174

  1. Contact-enhanced transparent silver nanowire network for all solution-based top-contact metal-oxide thin-film transistors.

    PubMed

    Kim, Yong-Hoon; Kim, Tae-Hyoung; Lee, Yeji; Kim, Jong-Woong; Kim, Jaekyun; Park, Sung Kyu

    2014-11-01

    In this paper, we investigate contact-enhanced transparent silver nanowire (Ag NW) network for solution-processed metal-oxide thin-film transistors (TFTs). Mechanical roll pressing was applied to a bar-coated Ag NW film to enhance the inter-nanowire connectivity. As a result, the sheet resistance of the Ag NW film was decreased from 119.5 ψ/square to 92.4 ψ/square, and more stable and enhanced TFT characteristics were achieved when the roll-pressed Ag NW was employed as source/drain electrodes. In addition, a non-acidic wet etching method was developed to pattern the Ag NW electrodes to construct top-contact geometry indium-gallium-zinc oxide TFTs. From the results, it is believed that the mechanical roll pressing and non-acidic wet etching method may be utilized in realizing all solution-based transparent metal-oxide TFTs. PMID:25958491

  2. Modeling of ionosphere time series using wavelet neural networks (case study: N-W of Iran)

    NASA Astrophysics Data System (ADS)

    Ghaffari Razin, Mir Reza; Voosoghi, Behzad

    2016-07-01

    Wavelet neural networks (WNNs) are important tools for analyzing time series especially when it is non-linear and non-stationary. It takes advantage of high resolution of wavelets and feed forward nature of neural networks (NNs). Therefore, in this paper, WNNs is used for modeling of ionosphere time series in Iran. To apply the method, observations collected at 22 GPS stations in 12 successive days of 2012 (DOY# 219-230) from Azerbaijan local GPS network are used. For training of WNN, back-propagation (BP) algorithm is used. The results of WNN compared with results of international reference ionosphere 2012 (IRI-2012) and international GNSS service (IGS) products. To assess the error of WNN, statistical indicators, relative and absolute errors are used. Minimum relative error for WNN compared with GPS TEC is 6.37% and maximum relative error is 12.94%. Also the maximum and minimum absolute error computed 6.32 and 0.13 TECU, respectively. Comparison of diurnal predicted TEC values from the WNN model and the IRI-2012 with GPS TEC revealed that the WNN provides more accurate predictions than the IRI-2012 model and IGS products in the test area.

  3. Effects of fracture reactivation and diagenesis on fracture network evolution: Cambrian Eriboll Formation, NW Scotland

    NASA Astrophysics Data System (ADS)

    Hooker, J. N.; Eichhubl, P.; Xu, G.; Ahn, H.; Fall, A.; Hargrove, P.; Laubach, S.; Ukar, E.

    2011-12-01

    The Cambrian Eriboll Formation quartzarenites contain abundant fractures with varying degrees of quartz cement infill. Fractures exist that are entirely sealed; are locally sealed by bridging cements but preserve pore space among bridges; are mostly open but lined with veneers of cement; or are devoid of cement. Fracture propagation in the Eriboll Formation is highly sensitive to the presence of pre-existing fractures. Fracture reactivation occurs in opening mode as individual fractures repeatedly open and are filled or bridged by syn-kinematic cements. As well, reactivation occurs in shear as opening of one fracture orientation coincides with shear displacement along pre-existing fractures of different orientations. The tendency for pre-existing fractures to slip varies in part by the extent of cement infill, yet we observe shear and opening-mode reactivation even among sealed fractures. Paleotemperature analysis of fluid inclusions within fracture cements suggests some fractures now in outcrop formed deep in the subsurface. Fractures within the Eriboll Formation may therefore affect later fracture propagation throughout geologic time. With progressive strain, fault zones develop within fracture networks by a sequence of opening-mode fracture formation, fracture reactivation and linkage, fragmentation, cataclasis, and the formation of slip surfaces. Cataclasite within fault zones is commonly more thoroughly cemented than fractures in the damage zone or outside the fault zone. This variance of cement abundance is likely the result of (1) continued exposure of freshly broken quartz surfaces within cataclasite, promoting quartz precipitation, and (2) possibly more interconnected pathways for mass transfer within the fault zone. Enhanced cementation of cataclasite results in strengthening or diagenetic strain hardening of the evolving fault zone. Further slip is accommodated by shear localization along discrete slip surfaces. With further linkage of fault segments

  4. Temperature-controlled metal/ligand stoichiometric ratio in Ag-TCNE coordination networks

    SciTech Connect

    Rodríguez-Fernández, Jonathan; Lauwaet, Koen; Herranz, Maria Ángeles; Miranda, Rodolfo; Otero, Roberto

    2015-03-14

    The deposition of tetracyanoethylene (TCNE) on Ag(111), both at Room Temperature (RT, 300 K) and low temperatures (150 K), leads to the formation of coordination networks involving silver adatoms, as revealed by Variable-Temperature Scanning Tunneling Microscopy. Our results indicate that TCNE molecules etch away material from the step edges and possibly also from the terraces, which facilitates the formation of the observed coordination networks. Moreover, such process is temperature dependent, which allows for different stoichiometric ratios between Ag and TCNE just by adjusting the deposition temperature. X-ray Photoelectron Spectroscopy and Density Functional Theory calculations reveal that charge-transfer from the surface to the molecule and the concomitant geometrical distortions at both sides of the organic/inorganic interface might facilitate the extraction of silver atoms from the step-edges and, thus, its incorporation into the observed TCNE coordination networks.

  5. Temperature-controlled metal/ligand stoichiometric ratio in Ag-TCNE coordination networks.

    PubMed

    Rodríguez-Fernández, Jonathan; Lauwaet, Koen; Herranz, Maria Ángeles; Martín, Nazario; Gallego, José María; Miranda, Rodolfo; Otero, Roberto

    2015-03-14

    The deposition of tetracyanoethylene (TCNE) on Ag(111), both at Room Temperature (RT, 300 K) and low temperatures (150 K), leads to the formation of coordination networks involving silver adatoms, as revealed by Variable-Temperature Scanning Tunneling Microscopy. Our results indicate that TCNE molecules etch away material from the step edges and possibly also from the terraces, which facilitates the formation of the observed coordination networks. Moreover, such process is temperature dependent, which allows for different stoichiometric ratios between Ag and TCNE just by adjusting the deposition temperature. X-ray Photoelectron Spectroscopy and Density Functional Theory calculations reveal that charge-transfer from the surface to the molecule and the concomitant geometrical distortions at both sides of the organic/inorganic interface might facilitate the extraction of silver atoms from the step-edges and, thus, its incorporation into the observed TCNE coordination networks. PMID:25770519

  6. Distribution of deformation on an active normal fault network, NW Corinth Rift

    NASA Astrophysics Data System (ADS)

    Ford, Mary; Meyer, Nicolas; Boiselet, Aurélien; Lambotte, Sophie; Scotti, Oona; Lyon-Caen, Hélène; Briole, Pierre; Caumon, Guillaume; Bernard, Pascal

    2013-04-01

    Over the last 20-25 years, geodetic measurements across the Gulf of Corinth have recorded high extension rates varying from 1.1 cm/a in the east to a maximum of 1.6 cm/a in the west. Geodetic studies also show that current deformation is confined between two relatively rigid blocks defined as Central Greece (to the north) and the Peloponnesus to the south. Active north dipping faults (<1 Ma) define the south coast of the subsiding Gulf, while high seismicity (major earthquakes and micro-seismicity) is concentrated at depth below and to the north of the westernmost Gulf. How is this intense deformation distributed in the upper crust? Our objectives here are (1) to propose two models for the distribution of deformation in the upper crust in the westernmost rift since 1 Ma, and (2) to place the tectonic behaviour of the western Gulf in the context of longer term rift evolution. Over 20 major active normal faults have been identified in the CRL area based specific characteristics (capable of generating earthquakes M> 5.5, active in the last 1 M yrs, slip rate >0.5 mm/a). Because of the uncertainty related to fault geometry at depth two models for 3D fault network geometry in the western rift down to 10 km were constructed using all available geophysical and geological data. The first model assumes planar fault geometries while the second uses listric geometries for major faults. A model for the distribution of geodetically-defined extension on faults is constructed along five NNE-SSW cross sections using a variety of data and timescales. We assume that the role of smaller faults in accommodating deformation is negligible so that extension is fully accommodated on the identified major faults. Uncertainties and implications are discussed. These models provide estimates of slip rate for each fault that can be used in seismic hazard models. A compilation of onshore and offshore data shows that the western Gulf is the youngest part of the Corinth rift having initiated

  7. Bio-lnspired dielectric elastomer actuator with AgNWs coated on carbon black electrode.

    PubMed

    Jun, K W; Lee, J M; Lee, J Y; Ohl, I K

    2014-10-01

    Bio-inspired dielectric elastomer actuators with AgNW-coated carbon black electrodes were developed in this study. The novel elastomer actuators show large in-plane deformations by electrical stimulation through the both electrodes. When a certain input voltage is applied to the elastomer electrode, the electrostatic force between cathode and anode electrodes compress the dielectric elastomer film, resulting large in in-plane direction deformation. The expanded area of the circular actuation device under 70 mV/m electric field was measured up to 50% due to a synergistic effect of highly conductive AgNW network and ultrahigh capacitance of carbon black electrodes. PMID:25942813

  8. Self-assembled Ag nanoparticle network passivated by a nano-sized ZnO layer for transparent and flexible film heaters

    SciTech Connect

    Seo, Ki-Won; Kim, Han-Ki; Kim, Min-Yi; Chang, Hyo-Sik

    2015-12-15

    We investigated a self-assembled Ag nanoparticle network electrode passivated by a nano-sized ZnO layer for use in high-performance transparent and flexible film heaters (TFFHs). The low temperature atomic layer deposition of a nano-sized ZnO layer effectively filled the uncovered area of Ag network and improved the current spreading in the self-assembled Ag network without a change in the sheet resistance and optical transmittance as well as mechanical flexibility. The time-temperature profiles and heat distribution analysis demonstrate that the performance of the TFTH with the ZnO/Ag network is superior to that of a TFFH with Ag nanowire electrodes. In addition, the TFTHs with ZnO/Ag network exhibited better stability than the TFFH with a bare Ag network due to the effective current spreading through the nano-sized ZnO layer.

  9. Silver nanowire percolation network soldered with graphene oxide at room temperature and its application for fully stretchable polymer light-emitting diodes.

    PubMed

    Liang, Jiajie; Li, Lu; Tong, Kwing; Ren, Zhi; Hu, Wei; Niu, Xiaofan; Chen, Yongsheng; Pei, Qibing

    2014-02-25

    Transparent conductive electrodes with high surface conductivity, high transmittance in the visible wavelength range, and mechanical compliance are one of the major challenges in the fabrication of stretchable optoelectronic devices. We report the preparation of a transparent conductive electrode (TCE) based on a silver nanowire (AgNW) percolation network modified with graphene oxide (GO). The monatomic thickness, mechanical flexibility, and strong bonding with AgNWs enable the GO sheets to wrap around and solder the AgNW junctions and thus dramatically reduce the inter-nanowire contact resistance without heat treatment or high force pressing. The GO-soldered AgNW network has a figure-of-merit sheet resistance of 14 ohm/sq with 88% transmittance at 550 nm. Its storage stability is improved compared to a conventional high-temperature annealed AgNW network. The GO-soldered AgNW network on polyethylene terephthalate films was processed from solutions using a drawdown machine at room temperature. When bent to 4 mm radius, its sheet resistance was increased by only 2-3% after 12,000 bending cycles. GO solder can also improve the stretchability of the AgNW network. Composite TCE fabricated by inlaying a GO-soldered AgNW network in the surface layer of polyurethane acrylate films is stretchable, by greater than 100% linear strain without losing electrical conductivity. Fully stretchable white polymer light-emitting diodes (PLEDs) were fabricated for the first time, employing the stretchable TCE as both the anode and cathode. The PLED can survive after 100 stretching cycles between 0 and 40% strain and can be stretched up to 130% linear strain at room temperature. PMID:24471886

  10. Metal dispersion and mobility in soils from the Lik Zn-Pb-Ag massive sulphide deposit, NW Alaska: Environmental and exploration implications

    USGS Publications Warehouse

    Kelley, K.D.; Kelley, D.L.

    2003-01-01

    The Lik deposit in northern Alaska is a largely unexposed shale-hosted Zn-Pb-Ag massive sulphide deposit that is underlain by continuous permafrost. Residual soils overlying the mineralized zone have element enrichments that are two to six times greater than baseline values. The most prominent elements are Ag, Mo, P, Se, Sr, V by total 4-acid digestion and Tl by a weak partial digestion (Enzyme Leach or EL) because they show multi-point anomalies that extend across the entire mineralized zone, concentration ranges are 0.5-2.6 ppm Ag, 4-26 ppm Mo, 0.1-0.3% P, 3-22 ppm Se, 90-230 ppm Sr, 170-406 ppm V, and 1.6-30 ppb Tl. Lead, Sb, and Hg are also anomalous (up to 178 ppm, 30 ppm, and 1.9 ppm, respectively), but all are characterized by single point anomalies directly over the mineralized zone, with only slightly elevated concentrations over the lower mineralized section. Zinc (total) has a consistent baseline response of 200 ppm, but it is not elevated in soils overlying the mineralized zone. However, Zn by EL shows a distinct single-point anomaly over the ore zone that suggests it was highly mobile and partly adsorbed on oxides or other secondary phases during weathering. In situ analyses (by laser ablation ICP-MS) of pyrite and sphalerite from drill core suggest that sphalerite is the primary residence for Ag, Cd, and Hg in addition to Zn, and pyrite contains As, Fe, Sb, and Tl. The level and degree of oxidation, and the proportion of reacting pyrite and carbonate minerals are two factors that affected the mobility and transport of metals. In oxidizing conditions, Zn is highly mobile relative to Hg and Ag, perhaps explaining the decoupling of Zn from the other sphalerite-hosted elements in the soils. Soils are acidic (to 3.9 pH) directly over the deposit due to the presence of acid-producing pyrite, but acid-neutralizing carbonate away from the mineralized zone yield soils that are near neutral. The soils therefore formed in a complex system involving oxidation and

  11. Effects of alkali treatments on Ag nanowire transparent conductive films

    NASA Astrophysics Data System (ADS)

    Kim, Sunho; Kang, Jun-gu; Eom, Tae-yil; Moon, Bongjin; Lee, Hoo-Jeong

    2016-06-01

    In this study, we employ various alkali materials (alkali metals with different base strengths, and ammonia gas and solution) to improve the conductivity of silver nanowire (Ag NW)-networked films. The alkali treatment appears to remove the surface oxide and improve the conductivity. When applied with TiO2 nanoparticles, the treatment appears more effective as the alkalis gather around wire junctions and help them weld to each other via heat emitted from the reduction reaction. The ammonia solution treatment is found to be quick and aggressive, damaging the wires severely in the case of excessive treatment. On the other hand, the ammonia gas treatment seems much less aggressive and does not damage the wires even after a long exposure. The results of this study highlight the effectiveness of the alkali treatment in improving of the conductivity of Ag NW-networked transparent conductive films.

  12. From hydrogen bonding to metal coordination and back: Porphyrin-based networks on Ag(111)

    SciTech Connect

    Studener, F. Müller, K.; Stöhr, M.; Marets, N.; Bulach, V. Hosseini, M. W.

    2015-03-14

    The self-assembly of a metal-free porphyrin bearing two pyridyl coordinating sites and two pentyl chains at trans meso positions was investigated under ultrahigh vacuum on a Ag(111) surface by scanning tunneling microscopy (STM). The STM measurements revealed a well-ordered close-packed structure with a rhombic unit cell for coverages ≤1 monolayer with their molecular plane parallel to the surface. The growth direction of the molecular islands is aligned along the step edges, which are restructured due to molecule-substrate interactions. The shorter unit cell vector of the molecular superstructure follows the 〈1-10〉 direction of the Ag(111) substrate. Hydrogen bonds between pyridyl and pyrrole groups of neighboring molecules as well as weak van der Waals forces between the pentyl chains stabilize the superstructure. Deposition of cobalt atoms onto the close-packed structure at room temperature leads to the formation of a hexagonal porous network stabilized by metal-ligand bonding between the pyridyl ligands and the cobalt atoms. Thermal annealing of the Co-coordination network at temperatures >450 K results in the transformation of the hexagonal network into a second close-packed structure. Changes in the molecule-substrate interactions due to metalation of the porphyrin core with Co as well as intermolecular interactions can explain the observed structural transformations.

  13. From hydrogen bonding to metal coordination and back: Porphyrin-based networks on Ag(111).

    PubMed

    Studener, F; Müller, K; Marets, N; Bulach, V; Hosseini, M W; Stöhr, M

    2015-03-14

    The self-assembly of a metal-free porphyrin bearing two pyridyl coordinating sites and two pentyl chains at trans meso positions was investigated under ultrahigh vacuum on a Ag(111) surface by scanning tunneling microscopy (STM). The STM measurements revealed a well-ordered close-packed structure with a rhombic unit cell for coverages ≤1 monolayer with their molecular plane parallel to the surface. The growth direction of the molecular islands is aligned along the step edges, which are restructured due to molecule-substrate interactions. The shorter unit cell vector of the molecular superstructure follows the〈1-10〉direction of the Ag(111) substrate. Hydrogen bonds between pyridyl and pyrrole groups of neighboring molecules as well as weak van der Waals forces between the pentyl chains stabilize the superstructure. Deposition of cobalt atoms onto the close-packed structure at room temperature leads to the formation of a hexagonal porous network stabilized by metal-ligand bonding between the pyridyl ligands and the cobalt atoms. Thermal annealing of the Co-coordination network at temperatures >450 K results in the transformation of the hexagonal network into a second close-packed structure. Changes in the molecule-substrate interactions due to metalation of the porphyrin core with Co as well as intermolecular interactions can explain the observed structural transformations. PMID:25770515

  14. Highly Stretchable and Transparent Supercapacitor by Ag-Au Core-Shell Nanowire Network with High Electrochemical Stability.

    PubMed

    Lee, Habeom; Hong, Sukjoon; Lee, Jinhwan; Suh, Young Duk; Kwon, Jinhyeong; Moon, Hyunjin; Kim, Hyeonseok; Yeo, Junyeob; Ko, Seung Hwan

    2016-06-22

    Stretchable and transparent electronics have steadily attracted huge attention in wearable devices. Although Ag nanowire is the one of the most promising candidates for transparent and stretchable electronics, its electrochemical instability has forbidden its application to the development of electrochemical energy devices such as supercapacitors. Here, we introduce a highly stretchable and transparent supercapacitor based on electrochemically stable Ag-Au core-shell nanowire percolation network electrode. We developed a simple solution process to synthesize the Ag-Au core-shell nanowire with excellent electrical conductivity as well as greatly enhanced chemical and electrochemical stabilities compared to pristine Ag nanowire. The proposed core-shell nanowire-based supercapacitor still possesses fine optical transmittance and outstanding mechanical stability up to 60% strain. The Ag-Au core-shell nanowire can be a strong candidate for future wearable electrochemical energy devices. PMID:27285849

  15. Neural network analysis of crosshole tomographic images: The seismic signature of gas hydrate bearing sediments in the Mackenzie Delta (NW Canada)

    NASA Astrophysics Data System (ADS)

    Bauer, K.; Pratt, R. G.; Haberland, C.; Weber, M.

    2008-10-01

    Crosshole seismic experiments were conducted to study the in-situ properties of gas hydrate bearing sediments (GHBS) in the Mackenzie Delta (NW Canada). Seismic tomography provided images of P velocity, anisotropy, and attenuation. Self-organizing maps (SOM) are powerful neural network techniques to classify and interpret multi-attribute data sets. The coincident tomographic images are translated to a set of data vectors in order to train a Kohonen layer. The total gradient of the model vectors is determined for the trained SOM and a watershed segmentation algorithm is used to visualize and map the lithological clusters with well-defined seismic signatures. Application to the Mallik data reveals four major litho-types: (1) GHBS, (2) sands, (3) shale/coal interlayering, and (4) silt. The signature of seismic P wave characteristics distinguished for the GHBS (high velocities, strong anisotropy and attenuation) is new and can be used for new exploration strategies to map and quantify gas hydrates.

  16. Constructing one-dimensional silver nanowire-doped reduced graphene oxide integrated with CdS nanowire network hybrid structures toward artificial photosynthesis

    NASA Astrophysics Data System (ADS)

    Liu, Siqi; Weng, Bo; Tang, Zi-Rong; Xu, Yi-Jun

    2014-12-01

    A ternary hybrid structure of one-dimensional (1D) silver nanowire-doped reduced graphene oxide (RGO) integrated with a CdS nanowire (NW) network has been fabricated via a simple electrostatic self-assembly method followed by a hydrothermal reduction process. The electrical conductivity of RGO can be significantly enhanced by opening up new conduction channels by bridging the high resistance grain-boundaries (HGBs) with 1D Ag nanowires, which results in a prolonged lifetime of photo-generated charge carriers excited from the CdS NW network, thus making Ag NW-RGO an efficient co-catalyst with the CdS NW network toward artificial photosynthesis.A ternary hybrid structure of one-dimensional (1D) silver nanowire-doped reduced graphene oxide (RGO) integrated with a CdS nanowire (NW) network has been fabricated via a simple electrostatic self-assembly method followed by a hydrothermal reduction process. The electrical conductivity of RGO can be significantly enhanced by opening up new conduction channels by bridging the high resistance grain-boundaries (HGBs) with 1D Ag nanowires, which results in a prolonged lifetime of photo-generated charge carriers excited from the CdS NW network, thus making Ag NW-RGO an efficient co-catalyst with the CdS NW network toward artificial photosynthesis. Electronic supplementary information (ESI) available: Experimental details, photographs of the experimental setups for photocatalytic activity testing, SEM images of Ag NWs and CdS NWs, Zeta potential, Raman spectra, DRS spectra, PL spectra and PL decay time evolution, and photocatalytic performances of samples for reduction of 4-NA and recycling test. See DOI: 10.1039/c4nr04229h

  17. Two-dimensional pentacene:3,4,9,10-perylenetetracarboxylic dianhydride supramolecular chiral networks on Ag(111).

    PubMed

    Chen, Wei; Li, Hui; Huang, Han; Fu, Yuanxi; Zhang, Hong Liang; Ma, Jing; Wee, Andrew Thye Shen

    2008-09-17

    Self-assembly of the binary molecular system of pentacene and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) on Ag(111) has been investigated by low-temperature scanning tunneling microscopy, molecular dynamics (MD), and density functional theory (DFT) calculations. Well-ordered two-dimensional (2D) pentacene:PTCDA supramolecular chiral networks are observed to form on Ag(111). The 2D chiral network formation is controlled by the strong interfacial interaction between adsorbed molecules and the underlying Ag(111), as revealed by MD and DFT calculations. The registry effect locks the adsorbed pentacene and PTCDA molecules into specific adsorption sites due to the corrugation of the potential energy surface. The 2D supramolecular networks are further constrained through the directional CO...H-C multiple intermolecular hydrogen bonding between the anhydride groups of PTCDA and the peripheral aromatic hydrogen atoms of the neighboring pentacene molecules. PMID:18722423

  18. Fluid inclusion and sulfur isotope thermometry of the Inkaya (Simav-Kütahya) Cu-Pb-Zn-(Ag) mineralization, NW TURKEY

    NASA Astrophysics Data System (ADS)

    Özen, Yeşim; Arik, Fetullah

    2013-09-01

    The Inkaya Cu-Pb-Zn-(Ag) mineralization, located about 20 km west of the Simav (Kütahya-Turkey), is situated in the northern part of the Menderes Massif Metamorphics. The mineralization is located along an E-W trending fault in the Cambrian Simav metamorphics consisting of quartz-muscovite schist, quartz-biotite schist, muscovite schist, biotite schist and the Arıkayası formation composed of marbles. Mineralized veins are 30-35 cm in width. The primary mineralization is represented by abundant galena, sphalerite, chalcopyrite, pyrite, fahlore and minor amounts of cerussite, anglesite, digenite, enargite, chalcocite, covellite, bornite, limonite, hematite and goethite with gangue quartz. Fluid inclusion studies on the quartz samples collected from the mineralized veins indicate that the temperature range of the fluids is 235°C to 340°C and the salinities are 0.7 to 4.49 wt. % NaCl equivalent. The wide range of homogenization temperatures indicates that two different fluid generations were trapped in quartz. Sulfur isotope studies of the sulfide minerals showed that all of the δ 34S values are between -2.1 and 2.6 per mil. These values are a typical range for hydrothermal sulfide minerals that have sulfur derived from a magmatic source. Pyrite-galena and pyrite-chalcopyrite sulfur isotope fractionation is consistent with an approach to isotopic equilibrium, and calculated temperatures are 254.6 and 277.4°C for pyrite-galena and 274.7°C for pyrite-chalcopyrite. The microthermometric data and sulfur isotope thermometry indicate the existence of a hydrothermal fluid that circulated along the fault crossing the Simav metamorphics and Arıkayası formation. Fluid inclusion and sulfur isotope thermometry can be used in combination with ore petrographical and geological information to provide site-specific targets for meso-hypothermal metal concentrations.

  19. Influence of structural position on fracture networks in the Torridon Group, Achnashellach fold and thrust belt, NW Scotland

    NASA Astrophysics Data System (ADS)

    Watkins, Hannah; Butler, Robert W. H.; Bond, Clare E.; Healy, Dave

    2015-05-01

    In fold-and-thrust belts rocks undergo deformation as fold geometries evolve. Deformation may be accommodated by brittle fracturing, which can vary depending on structural position. We use 2D forward modelling and 3D restorations to determine strain distributions throughout folds of the Achnashellach Culmination, Moine Thrust Belt, NW Scotland. Fracture data is taken from the Torridon Group; a thick, coarse grained fluviatile sandstone deposited during the Proterozoic. Modelling infers a correlation between strain and simple curvature; we use simple curvature to infer how structural position and strain control fracture attribute variations in a fold and thrust belt. In high curvature regions, such as forelimbs, fracture intensities are high and fractures are short and oriented parallel to fold hinges. In low curvature regions fractures have variable intensities and are longer. Fracture orientations in these regions are scattered and vary over short distances. These variations do not relate to strain; data suggests lithology may influence fracturing. The strain history of fold structures also influences fracturing; structures with longer deformation histories exhibit consistent fracture attributes due to moderate-high strain during folding, despite present day low curvature. This is in contrast to younger folds with similar curvatures but shorter deformation histories. We suggest in high strain regions fracturing is influenced by structural controls, whereas in low strain regions lithology becomes more important in influencing fracturing.

  20. Graphene-like Networks in the lattice of Ag, Cu and Al metals

    NASA Astrophysics Data System (ADS)

    Salamanca-Riba, Lourdes; Ge, Xiaoxiao; Isaacs, Romaine; Jaim, Hm Iftekar; Wuttig, Manfred; Rashkeev, Sergey; Kuklja, Maija; Hu, Lianbing; Covetics Team Team

    Graphene-like networks form in the lattice of metals such as silver, copper and aluminum via an electrocharging assisted process. In this process a high current of >80A is applied to the liquid metal containing particles of activated carbon. The resulting material is called M covetic (M =Al, Ag Cu). We have previously reported that this process gives rise to carbon nanostructures with sp2 bonding embedded in the lattice of the metal. The carbon bonds to the metal as evidenced by Raman scattering and first principles simulation of the phonon density of states. With this process we have observed that graphene nanoribbons form along preferential crystalline directions and form 3D epitaxial structures with Al and Ag hosts. Bulk Cu covetic was used to deposit films by e-beam deposition and PLD. The PLD films contain higher C content and show higher transmittance (~90%) and resistance to oxidation than pure copper films of the same thickness. We compare the electrical and mechanical properties of covetics containing C in the 0 to 10 wt % and the transmittance of Cu covetic films compared to pure Cu films of the same thickness. Supported by ONR Grant N000141410042

  1. Dynamics of Spatially Confined Bisphenol A Trimers in a Unimolecular Network on Ag(111).

    PubMed

    Lloyd, Julian A; Papageorgiou, Anthoula C; Fischer, Sybille; Oh, Seung Cheol; Saǧlam, Özge; Diller, Katharina; Duncan, David A; Allegretti, Francesco; Klappenberger, Florian; Stöhr, Martin; Maurer, Reinhard J; Reuter, Karsten; Reichert, Joachim; Barth, Johannes V

    2016-03-01

    Bisphenol A (BPA) aggregates on Ag(111) shows a polymorphism between two supramolecular motifs leading to formation of distinct networks depending on thermal energy. With rising temperature a dimeric pairing scheme reversibly converts into a trimeric motif, which forms a hexagonal superstructure with complex dynamic characteristics. The trimeric arrangements notably organize spontaneously into a self-assembled one-component array with supramolecular BPA rotors embedded in a two-dimensional stator sublattice. By varying the temperature, the speed of the rotors can be controlled as monitored by direct visualization. A combination of scanning tunneling microscopy and dispersion-corrected density-functional tight-binding (DFTB-vdW(surf)) based molecular modeling reveals the exact atomistic position of each molecule within the assembly as well as the driving force for the formation of the supramolecular rotors. PMID:26849384

  2. Large scale silver nanowires network fabricated by MeV hydrogen (H+) ion beam irradiation

    NASA Astrophysics Data System (ADS)

    Honey, S.; Naseem, S.; Ishaq, A.; Maaza, M.; Bhatti, M. T.; Wan, D.

    2016-04-01

    A random two-dimensional large scale nano-network of silver nanowires (Ag-NWs) is fabricated by MeV hydrogen (H+) ion beam irradiation. Ag-NWs are irradiated under H+ ion beam at different ion fluences at room temperature. The Ag-NW network is fabricated by H+ ion beam-induced welding of Ag-NWs at intersecting positions. H+ ion beam induced welding is confirmed by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Moreover, the structure of Ag NWs remains stable under H+ ion beam, and networks are optically transparent. Morphology also remains stable under H+ ion beam irradiation. No slicings or cuttings of Ag-NWs are observed under MeV H+ ion beam irradiation. The results exhibit that the formation of Ag-NW network proceeds through three steps: ion beam induced thermal spikes lead to the local heating of Ag-NWs, the formation of simple junctions on small scale, and the formation of a large scale network. This observation is useful for using Ag-NWs based devices in upper space where protons are abandoned in an energy range from MeV to GeV. This high-quality Ag-NW network can also be used as a transparent electrode for optoelectronics devices. Project supported by the National Research Foundation of South Africa (NRF), the French Centre National pour la Recherche Scientifique, iThemba-LABS, the UNESCO-UNISA Africa Chair in Nanosciences & Nanotechnology, the Third World Academy of Science (TWAS), Organization of Women in Science for the Developing World (OWSDW), the Abdus Salam ICTP via the Nanosciences African Network (NANOAFNET), and the Higher Education Commission (HEC) of Pakistan.

  3. Ag Nanowire Based Transparent Conductor for CIGS PV

    SciTech Connect

    Woods, L. M.; Wolk, J.; Smith, M.; Davande, H.; Ribelin, R. M.; Perkins, C. L.

    2011-01-01

    Coated silver nanowires (AgNW) have been considered as a replacement for transparent conducting oxides (TCOs) in CIGS based photovoltaic devices. The advantages of AgNW over TCOs are discussed, and optical and electrical characteristics of AgNWs on glass are presented. Similarly fabricated AgNWs with varying sheet resistance on CIGS devices were tested against ITO transparent conductor controls. The CIGS was produced using a roll-to-roll technique on a flexible polymer substrate. Variations in the ZnO layer resistivity that are adjacent to the AgNW layer in the CIGS device were also tested. Device results indicate similar Jsc, but a reduced FF for cells made with the AgNWs, and Voc dependence on the resistivity of the coated AgNW and ZnO window layers. FF and Voc losses associated with the use of AgNWs are discussed.

  4. Using AGNESS (A Generalized Network-based Expert System Shell) for matching images

    NASA Technical Reports Server (NTRS)

    Pong, Ting-Chuen; Lee, Chung-Mong; Slagle, James

    1988-01-01

    The image correspondence problem is considered the most difficult step in both stereo and motion analysis. Stereo vision is useful in determining the 3-D positions of points on visible surface in a scene. Motion analysis is useful in determining the spatial and temporal relationships of objects in an environment. Besides stereo and motion analysis, there is the image correspondence problem. Most of this work is based on point or local area properties of the observed gray level values in 2-D images. A global and general approach to this problem is described by using a knowledge-based system. The knowledge it uses consists of both physical properties and spatial relationships of the edges and regions extracted from the given images. The physical component depends on features of the edge or region) in isolation. The spatial component involves the set of edges and regions adjacent to a given edge (or region) of the first image and the set of edges and regions adjacent to each potentially matching edge (or region) of the second image; thus the spatial context of each edge or region is considered. A computational network is used to represent this knowledge, it allows the computation of the likelihood of matching two edges or regions with logical and heuristic operators. An expert system shell called AGNESS (A Generalized Network-based Expert System Shell) is used to build a prototype system.

  5. 3D hierarchical MnO2 nanorod/welded Ag-nanowire-network composites for high-performance supercapacitor electrodes.

    PubMed

    Qiao, Zhensong; Yang, Xiaopeng; Yang, Shuhua; Zhang, Liqiang; Cao, Bingqiang

    2016-06-28

    3D MnO2 nanorod/welded Ag-nanowire-network supercapacitor electrodes were prepared. Welding treatment of the Ag nanowire-network leads to low resistance and long lifetime. Galvanostatic charge/discharge (GCD) induces an ever-lasting morphology changing from flower-like to honeycomb-like for MnO2, which manifests as increasing specific capacitance to 663.4 F g(-1) after 7000 GCD cycles. PMID:27263832

  6. An artificial neural network application to produce debris source areas of Barla, Besparmak, and Kapi Mountains (NW Taurids, Turkey)

    NASA Astrophysics Data System (ADS)

    Tunusluoglu, M. C.; Gokceoglu, C.; Sonmez, H.; Nefeslioglu, H. A.

    2007-10-01

    Various statistical, mathematical and artificial intelligence techniques have been used in the areas of engineering geology, rock engineering and geomorphology for many years. However, among the techniques, artificial neural networks are relatively new approach used in engineering geology in particular. The attractiveness of ANN for the engineering geological problems comes from the information processing characteristics of the system, such as non-linearity, high parallelism, robustness, fault and failure tolerance, learning, ability to handle imprecise and fuzzy information, and their capability to generalize. For this reason, the purposes of the present study are to perform an application of ANN to a engineering geology problem having a very large database and to introduce a new approach to accelerate convergence. For these purposes, an ANN architecture having 5 neurons in one hidden layer was constructed. During the training stages, total 40 000 training cycles were performed and the minimum RMSE values were obtained at approximately 10 000th cycle. At this cycle, the obtained minimum RMSE value is 0.22 for the second training set, while that of value is calculated as 0.064 again for the second test set. Using the trained ANN model at 10 000th cycle for the second random sampling, the debris source area susceptibility map was produced and adjusted. Finally, a potential debris source susceptibility map for the study area was produced. When considering the field observations and existing inventory map, the produced map has a high prediction capacity and it can be used when assessing debris flow hazard mitigation efforts.

  7. Nano-morphology induced additional surface plasmon resonance enhancement of SERS sensitivity in Ag/GaN nanowall network

    NASA Astrophysics Data System (ADS)

    Sharvani, S.; Upadhayaya, Kishor; Kumari, Gayatri; Narayana, Chandrabhas; Shivaprasad, S. M.

    2015-11-01

    The GaN nanowall network, formed by opening the screw dislocations by kinetically controlled MBE growth, possesses a large surface and high conductivity. Sharp apexed nanowalls show higher surface electron concentration in the band-tail states, in comparison to blunt apexed nanowalls. Uncapped silver nanoparticles are vapor deposited on the blunt and sharp GaN nanowall networks to study the morphological dependence of band-edge plasmon-coupling. Surface enhanced Raman spectroscopy studies performed with a rhodamine 6G analyte on these two configurations clearly show that the sharp nanowall morphology with smaller Ag nanoparticles shows higher enhancement of the Raman signal. A very large enhancement factor of 2.8 × 107 and a very low limit of detection of 10-10 M is observed, which is attributed to the surface plasmon resonance owing to the high surface electron concentration on the GaN nanowall in addition to that of the Ag nanoparticles. The significantly higher sensitivity with same-sized Ag nanoparticles confirms the unconventional role of morphology-dependent surface charge carrier concentration of GaN nanowalls in the enhancement of Raman signals.

  8. Nano-morphology induced additional surface plasmon resonance enhancement of SERS sensitivity in Ag/GaN nanowall network.

    PubMed

    Sharvani, S; Upadhayaya, Kishor; Kumari, Gayatri; Narayana, Chandrabhas; Shivaprasad, S M

    2015-11-20

    The GaN nanowall network, formed by opening the screw dislocations by kinetically controlled MBE growth, possesses a large surface and high conductivity. Sharp apexed nanowalls show higher surface electron concentration in the band-tail states, in comparison to blunt apexed nanowalls. Uncapped silver nanoparticles are vapor deposited on the blunt and sharp GaN nanowall networks to study the morphological dependence of band-edge plasmon-coupling. Surface enhanced Raman spectroscopy studies performed with a rhodamine 6G analyte on these two configurations clearly show that the sharp nanowall morphology with smaller Ag nanoparticles shows higher enhancement of the Raman signal. A very large enhancement factor of 2.8 × 10(7) and a very low limit of detection of 10(-10) M is observed, which is attributed to the surface plasmon resonance owing to the high surface electron concentration on the GaN nanowall in addition to that of the Ag nanoparticles. The significantly higher sensitivity with same-sized Ag nanoparticles confirms the unconventional role of morphology-dependent surface charge carrier concentration of GaN nanowalls in the enhancement of Raman signals. PMID:26502004

  9. Self-organized metal networks at ion-etched Cu/Si and Ag/Si interfaces

    SciTech Connect

    Stepanova, M.; Dew, S.K.; Karpuzov, D.S.

    2005-04-15

    We report self-organized metal nanopatterns on Si substrates produced by ion beam etching. We have deposited thin layers of metal such as Cu or Ag on Si substrates and then etched the deposited layers by a 1-5 keV Ar{sup +} ion beam at room temperature. At the stage when the metal-Si interface is reached, we have observed networks of metal clusters on the Si substrate with the characteristic size of 30-60 nm for Cu and 100-200 nm for Ag. The Cu patterns are sensitive to the ion energy. At 1 keV energy, we observe a well-defined Cu network, whereas at 3-5 keV energy, the Cu pattern becomes fuzzy without clear boundaries. To systematize and explain our results, we have suggested a kinetic model that combines ion etching and coarsening of the metal clusters on Si substrates. From our kinetic Monte Carlo simulations, we have found that the cooperative effect of coarsening and etching has a regime when the size of metal clusters can be approximated by the expression a(4D/aR){sup 1/3}, where D is the surface diffusivity of metal adatoms on the Si substrate, R is the etch rate, and a is the interatomic distance. Our synergistic model of coarsening and sputtering explains the observed difference in Cu and Ag cluster sizes and predicts the fuzzy Cu patterns at elevated ion energies.

  10. Polymer-facilitated low temperature fusing of spray-coated silver nanowire networks as transparent top and bottom electrodes in small molecule organic photovoltaics (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Selzer, Franz; Weiß, Nelli; Kneppe, David; Bormann, Ludwig; Sachse, Christoph; Gaponik, Nikolai; Eychmüller, Alexander; Leo, Karl; Müller-Meskamp, Lars

    2015-10-01

    Networks of silver nanowires (AgNWs) are promising candidates for transparent conducting electrodes in organic photovoltaics (OPV), as they achieve similar performance as the commonly used indium tin oxide (ITO) at lower cost and increased flexibility. The initial sheet resistance (Rs) of AgNW electrodes typically needs to be reduced by a post-annealing step (90 min@200 °C), being detrimental for processing on polymeric substrates. We present novel low temperature-based methods to integrate AgNWs in organic small molecule-based photovoltaics, either as transparent and highly conductive bottom-electrode or, for the first time, as spray-coated AgNW top-electrode. The bottom-electrodes are prepared by organic matrix assisted low-temperature fusing. Here, selected polymers are coated below the AgNWs to increase the interaction between NWs and substrate. In comparison to networks without these polymeric sublayers, the Rs is reduced by two orders of magnitude. AgNW top-electrodes are realized by dispersing modified high-quality AgNWs in inert solvents, which do not damage small molecule layers. Accordingly, our AgNW dispersion can be spray-coated onto all kind of OPV devices. Both bottom- and top-electrodes show a Rs of <11 Ω/ at >87 % transparency directly after spray-coating at very low substrate temperatures of <80 °C. We also demonstrate the implementation of our AgNW electrodes in organic solar cells. The corresponding devices show almost identical performance compared to organic solar cells exploiting ITO as bottom or thermally evaporated thin-metal as top-electrode.

  11. Piezoresistive Sensor with High Elasticity Based on 3D Hybrid Network of Sponge@CNTs@Ag NPs.

    PubMed

    Zhang, Hui; Liu, Nishuang; Shi, Yuling; Liu, Weijie; Yue, Yang; Wang, Siliang; Ma, Yanan; Wen, Li; Li, Luying; Long, Fei; Zou, Zhengguang; Gao, Yihua

    2016-08-31

    Pressure sensors with high elasticity are in great demand for the realization of intelligent sensing, but there is a need to develope a simple, inexpensive, and scalable method for the manufacture of the sensors. Here, we reported an efficient, simple, facile, and repeatable "dipping and coating" process to manufacture a piezoresistive sensor with high elasticity, based on homogeneous 3D hybrid network of carbon nanotubes@silver nanoparticles (CNTs@Ag NPs) anchored on a skeleton sponge. Highly elastic, sensitive, and wearable sensors are obtained using the porous structure of sponge and the synergy effect of CNTs/Ag NPs. Our sensor was also tested for over 2000 compression-release cycles, exhibiting excellent elasticity and cycling stability. Sensors with high performance and a simple fabrication process are promising devices for commercial production in various electronic devices, for example, sport performance monitoring and man-machine interfaces. PMID:27482721

  12. Transparent conductive PVP/AgNWs films for flexible organic light emitting diodes by spraying method

    NASA Astrophysics Data System (ADS)

    Hu, Jun-tao; Mei, Wen-juan; Ye, Kang-li; Wei, Qing-qing; Hu, Sheng

    2016-05-01

    In this study, a simple spraying method is used to prepare the transparent conductive films (TCFs) based on Ag nanowires (AgNWs). Polyvinylpyrrolidone (PVP) is introduced to modify the interface of substrate. The transmittance and bending performance are improved by optimizing the number of spraying times and the solution concentration and controlling the annealing time. The spraying times of 20, the concentration of 2 mg/mL and the annealing time of 10 min are chosen to fabricate the PVP/AgNWs films. The transmittance of PVP/AgNWs films is 53.4%—67.9% at 380—780 nm, and the sheet resistance is 30 Ω/□ which is equivalent to that of commercial indium tin oxide (ITO). During cyclic bending tests to 500 cycles with bending radius of 5 mm, the changes of resistivity are negligible. The performance of PVP/AgNW transparent electrodes has little change after being exposed to the normal environment for 1 000 h. The adhesion to polymeric substrate and the ability to endure bending stress in AgNWs network films are both significantly improved by introducing PVP. Spraying method makes AgNWs form a stratified structure on large-area polymer substrates, and the vacuum annealing method is used to weld the AgNWs together at junctions and substrates, which can improve the electrical conductivity. The experimental results indicate that PVP/AgNW transparent electrodes can be used as transparent conductive electrodes in flexible organic light emitting diodes (OLEDs).

  13. Nanoscale Chemical and Electrical Stabilities of Graphene-covered Silver Nanowire Networks for Transparent Conducting Electrodes.

    PubMed

    Kim, Seong Heon; Choi, Woon Ih; Kim, Kwang Hee; Yang, Dae Jin; Heo, Sung; Yun, Dong-Jin

    2016-01-01

    The hybrid structure of Ag nanowires (AgNWs) covered with graphene (Gr) shows synergetic effects on the performance of transparent conducting electrodes (TCEs). However, these effects have been mainly observed via large-scale characterization, and precise analysis at the nanoscale level remains inadequate. Here, we present the nanoscale verification and visualization of the improved chemical and electrical stabilities of Gr-covered AgNW networks using conductive atomic force microscopy (C-AFM), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS) combined with the gas cluster ion beam (GCIB) sputtering technique. Specifically by transferring island Gr on top of the AgNW network, we were able to create samples in which both covered and uncovered AgNWs are simultaneously accessible to various surface-characterization techniques. Furthermore, our ab initio molecular dynamics (AIMD) simulation elucidated the specific mechanistic pathway and a strong propensity for AgNW sulfidation, even in the presence of ambient oxidant gases. PMID:27620453

  14. Surface-enhanced Raman scattering of a Ag/oligo(phenyleneethynylene)/Ag sandwich

    NASA Astrophysics Data System (ADS)

    Fletcher, Melissa; Alexson, D. M.; Prokes, Sharka; Glembocki, Orest; Vivoni, Alberto; Hosten, Charles

    2011-02-01

    α,ω-Dithiols are a useful class of compounds in molecular electronics because of their ability to easily adsorb to two metal surfaces, producing a molecular junction. We have prepared Ag nanosphere/oligo(phenyleneethynylene)/Ag sol (AgNS/OPE/Ag sol) and Ag nanowire/oligo(phenyleneethynylene)/Ag sol (AgNW/OPE/Ag sol) sandwiches to simulate the architecture of a molecular electronic device. This was achieved by self-assembly of OPE on the silver nanosurface, deprotection of the terminal sulfur, and deposition of Ag sol atop the monolayer. These sandwiches were then characterized by surface-enhanced Raman scattering (SERS) spectroscopy. The resulting spectra were compared to the bulk spectrum of the dimer and to the Ag nanosurface/OPE SERS spectra. The intensities of the SERS spectra in both systems exhibit a strong dependence on Ag deposition time and the results are also suggestive of intense interparticle coupling of the electromagnetic fields in both the AgNW/OPE/Ag and the AgNS/OPE/Ag systems. Three previously unobserved bands (1219, 1234, 2037 cm -1) arose in the SER spectra of the sandwiches and their presence is attributed to the strong enhancement of the electromagnetic field which is predicted from the COSMOL computational package. The 544 cm -1 disulfide bond which is observed in the spectrum of solid OPE but is absent in the AgNS/OPE/Ag and AgNW/OPE/Ag spectra is indicative of chemisorption of OPE to the nanoparticles through oxidative dissociation of the disulfide bond.

  15. ZnO-(Cu/Ag)TCNQ heterostructure network over flexible platform for enhanced cold cathode application

    NASA Astrophysics Data System (ADS)

    Pal, Shreyasi; Maiti, Soumen; Narayan Maiti, Uday; Chattopadhyay, Kalyan Kumar

    2016-07-01

    Multistage field emitters consisting of organic/inorganic hybrid nanostructures with branched geometry are designed via a two-step protocol: a simple wet chemical method followed by a vapor-solid-phase technique. (Cu/Ag)TCNQ (copper/silver-7,7,8,8-tetracyanoquinodimethane) nanowires (NWs) were grown hierarchically on zinc oxide (ZnO) nanorods (NRs) to form ZnO-(Cu/Ag)TCNQ heterostructure assemblies. By monitoring the metallic Cu and Ag coating thickness on ZnO NRs, precise control over the morphology and orientations of the secondary organic NWs is achieved. In-depth analysis of electron field emission (FE) behavior of the ZnO-(Cu/Ag)TCNQ-based hierarchy suggests highest emission performance with low turn-on as well as threshold fields of 1.15 and 3.75 V μm‑1 respectively from the morphology-optimized hierarchy. Beneficial orientation of the branched organic NWs ensures sequential electric field enhancement in the consecutive stem and branches whereas its low work function eases electron emission; these aspects combined together render an overall enhancement in the emission behavior of the hybrid system. As compared to individual building units, the heterostructures show improved field electron emission. Additionally, successful construction of this novel hybrid over a fabric platform displays great potential in opening up new pathways in the highly-anticipated field of flexible electronics.

  16. ZnO-(Cu/Ag)TCNQ heterostructure network over flexible platform for enhanced cold cathode application.

    PubMed

    Pal, Shreyasi; Maiti, Soumen; Maiti, Uday Narayan; Chattopadhyay, Kalyan Kumar

    2016-07-01

    Multistage field emitters consisting of organic/inorganic hybrid nanostructures with branched geometry are designed via a two-step protocol: a simple wet chemical method followed by a vapor-solid-phase technique. (Cu/Ag)TCNQ (copper/silver-7,7,8,8-tetracyanoquinodimethane) nanowires (NWs) were grown hierarchically on zinc oxide (ZnO) nanorods (NRs) to form ZnO-(Cu/Ag)TCNQ heterostructure assemblies. By monitoring the metallic Cu and Ag coating thickness on ZnO NRs, precise control over the morphology and orientations of the secondary organic NWs is achieved. In-depth analysis of electron field emission (FE) behavior of the ZnO-(Cu/Ag)TCNQ-based hierarchy suggests highest emission performance with low turn-on as well as threshold fields of 1.15 and 3.75 V μm(-1) respectively from the morphology-optimized hierarchy. Beneficial orientation of the branched organic NWs ensures sequential electric field enhancement in the consecutive stem and branches whereas its low work function eases electron emission; these aspects combined together render an overall enhancement in the emission behavior of the hybrid system. As compared to individual building units, the heterostructures show improved field electron emission. Additionally, successful construction of this novel hybrid over a fabric platform displays great potential in opening up new pathways in the highly-anticipated field of flexible electronics. PMID:27188388

  17. Oxidation of ethyl acetate by a high performance nanostructure (Ni, Mn)-Ag/ZSM-5 bimetallic catalysts and development of an artificial neural networks predictive modeling.

    PubMed

    Jodaei, Azadeh; Salari, Darush; Niaei, Ali; Khatamian, Masumeh; Hosseini, Seyed Ali

    2011-01-01

    The catalytic oxidation of ethyl acetate in low concentration was investigated over mono-metallic Ag/ZSM5 and bimetallic (Ni, Mn)-Ag/ZSM-5 catalysts. Catalytic studies were carried out in a catalytic fixed bed reactor under atmospheric pressure. The sequence of catalytic activity was as follows: Ni-Ag-ZSM-5 > Mn-Ag-ZSM-5 > Ag-ZSM-5 > H-ZSM-5. The catalysts were characterized by ICP-AES, X-ray diffraction (XRD), low temperature nitrogen adsorption, NH(3)-TPD, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and diffuse reflectance UV-vis spectra (UV-vis). An artificial neural networks (ANN) model was developed to predict the performance of catalytic oxidation process over bimetallic Ni-Ag/ZSM-5 catalyst based on experimental data. For this purpose the standard feed forward back propagation algorithm was employed to train the model by using laboratory experimental data. A good agreement was resulted between experimental results and those obtained by ANN. Following order for variables effects on conversion yield of ethyl acetate was predicted by ANN model: reaction temperature (32.99%) > Ag loading (27.38%) > initial ethyl acetate concentration (23.58%) > Ni loading (16.05%). PMID:21104495

  18. Large Pulsed Electron Beam Welded Percolation Networks of Silver Nanowires for Transparent and Flexible Electrodes.

    PubMed

    Kim, Jisoo; Nam, Yun Seok; Song, Myoung Hoon; Park, Hyung Wook

    2016-08-17

    Mechanical properties of transparent electrodes, including flexibility, are important in flexible electronics for sustaining electrical conductivity under bending with small radius of curvature. Low contact resistance of junctions in metal nanowire percolation networks is the most important factor to produce electrodes with excellent optical, electrical and mechanical performance. Here, we report the fabrication of welded silver nanowire percolation networks using large pulsed electron beam (LPEB) irradiation as a welding process of silver nanowires (AgNWs). It results in modification of electrical and mechanical properties because of the low contact resistance at welded junctions. Consequently, the flexible and transparent AgNW electrodes fabricated by LPEB irradiation showed lower sheet resistance of 12.63 Ω sq(-1) at high transmittance of 93% (at 550 nm), and superb mechanical flexibility, compared with other AgNW electrodes prepared by thermal treatement and without any treatment. Polymer light-emitting diodes (PLEDs) using AgNWs by LPEB irradiation were fabricated to confirm that the AgNW electrode by LPEB irradiation was able to become alternative to indium tin oxide (ITO) and they showed good device performance as a maximum luminous efficiency of 7.37 cd A(-1), and excellent mechanical flexibility under bending with small radius of curvature. PMID:27463783

  19. Resistance of Single Ag Nanowire Junctions and Their Role in the Conductivity of Nanowire Networks.

    PubMed

    Bellew, Allen T; Manning, Hugh G; Gomes da Rocha, Claudia; Ferreira, Mauro S; Boland, John J

    2015-11-24

    Networks of silver nanowires appear set to replace expensive indium tin oxide as the transparent conducting electrode material in next generation devices. The success of this approach depends on optimizing the material conductivity, which until now has largely focused on minimizing the junction resistance between wires. However, there have been no detailed reports on what the junction resistance is, nor is there a known benchmark for the minimum attainable sheet resistance of an optimized network. In this paper, we present junction resistance measurements of individual silver nanowire junctions, producing for the first time a distribution of junction resistance values and conclusively demonstrating that the junction contribution to the overall resistance can be reduced beyond that of the wires through standard processing techniques. We find that this distribution shows the presence of a small percentage (6%) of high-resistance junctions, and we show how these may impact the performance of network-based materials. Finally, through combining experiment with a rigorous model, we demonstrate the important role played by the network skeleton and the specific connectivity of the network in determining network performance. PMID:26448205

  20. Nano-Welding of Ag Nanowires Using Rapid Thermal Annealing for Transparent Conductive Films.

    PubMed

    Oh, Jong Sik; Oh, Ji Soo; Shin, Jae Hee; Yeom, Geun Young; Kim, Kyong Nam

    2015-11-01

    Ag nanowire (NW) films obtained by the spraying the Ag NWs on the substrates were nano-welded by rapid thermal annealing (RTA) process and the effect of RTA process on the change of sheet resistance and optical transmittance of the Ag NW films was investigated. The increased number of Ag NW sprays on the substrate decreased the sheet resistance but also decreased the optical transmittance. By the annealing for 60 sec in a nitrogen environment to 225-250 degrees C, the sheet resistance of Ag NW film could be decreased to about 50%, even though it was accompanied by the slight decrease of optical transmittance less than 5%. The decrease of sheet resistance was related to the nano-welding of the Ag NW junctions and the slight decrease of optical transmittance was related local melting of the Ag NWs and spreading on the substrate surface. Through the nano-welding by RTA process, the Ag NW film with the sheet resistance of -20 Ω/sq. and the optical transmittance of 93% could be obtained. PMID:26726568

  1. Enhanced transparent conducting networks on plastic substrates modified with highly oxidized graphene oxide nanosheets

    NASA Astrophysics Data System (ADS)

    Woo, Jong Seok; Sin, Dong Hun; Kim, Haena; Jang, Jeong In; Kim, Ho Young; Lee, Geon-Woong; Cho, Kilwon; Park, Soo-Young; Han, Joong Tark

    2016-03-01

    Atomically thin and two-dimensional graphene oxide (GO) is a very fascinating material because of its functional groups, high transparency, and solution processability. Here we show that highly oxidized GO (HOGO) nanosheets serve as an effective interfacial modifier of transparent conducting films with one-dimensional (1D) silver nanowires (AgNWs) and single-walled carbon nanotubes (SWCNTs). Optically transparent and small-sized GO nanosheets, with minimal sp2 domains, were successfully fabricated by step-wise oxidation and exfoliation of graphite. We demonstrated that under-coated HOGO further decreases the sheet resistance of the SWCNT film top-coated with HOGO by increasing the contact area between the SWCNTs and HOGO nanosheets by generating hole carriers in the SWCNT as a result of charge transfer. Moreover, HOGO nanosheets with AgNWs contribute to the efficient thermal joining of AgNW networks on plastic substrates by limiting the thermal embedding of AgNWs into the plastic surface, resulting in efficient decrease of the sheet resistance. Furthermore, flexible organic photovoltaic cells with GO-modified AgNW anodes on a flexible substrate were successfully demonstrated.Atomically thin and two-dimensional graphene oxide (GO) is a very fascinating material because of its functional groups, high transparency, and solution processability. Here we show that highly oxidized GO (HOGO) nanosheets serve as an effective interfacial modifier of transparent conducting films with one-dimensional (1D) silver nanowires (AgNWs) and single-walled carbon nanotubes (SWCNTs). Optically transparent and small-sized GO nanosheets, with minimal sp2 domains, were successfully fabricated by step-wise oxidation and exfoliation of graphite. We demonstrated that under-coated HOGO further decreases the sheet resistance of the SWCNT film top-coated with HOGO by increasing the contact area between the SWCNTs and HOGO nanosheets by generating hole carriers in the SWCNT as a result of charge

  2. Single-Crystal to Single-Crystal Phase Transition and Segmented Thermochromic Luminescence in a Dynamic 3D Interpenetrated Ag(I) Coordination Network.

    PubMed

    Yan, Zhi-Hao; Li, Xiao-Yu; Liu, Li-Wei; Yu, Si-Qi; Wang, Xing-Po; Sun, Di

    2016-02-01

    A new 3D Ag(I)-based coordination network, [Ag2(pz)(bdc)·H2O]n (1; pz = pyrazine and H2bdc = benzene-1,3-dicarboxylic acid), was constructed by one-pot assembly and structurally established by single-crystal X-ray diffraction at different temperatures. Upon cooling from 298 to 93 K, 1 undergo an interesting single-crystal to single-crystal phase transition from orthorhombic Ibca (Z = 16) to Pccn (Z = 32) at around 148 K. Both phases show a rare 2-fold-interpenetrated 4-connected lvt network but incorporate different [Ag2(COO)2] dimeric secondary building units. It is worth mentioning that complex 1 shows red- and blue-shifted luminescences in the 290-170 and 140-80 K temperature ranges, respectively. The variable-temperature single-crystal X-ray crystallographic studies suggest that the argentophilic interactions and rigidity of the structure dominated the luminescence chromism trends at the respective temperature ranges. Upon being mechanically ground, 1 exhibits a slight mechanoluminescence red shift from 589 to 604 nm at 298 K. PMID:26828950

  3. Crystalline Nanojoining Silver Nanowire Percolated Networks on Flexible Substrate.

    PubMed

    Nian, Qiong; Saei, Mojib; Xu, Yang; Sabyasachi, Ganguli; Deng, Biwei; Chen, Yong P; Cheng, Gary J

    2015-10-27

    Optoelectronic performance of metal nanowire networks are dominated by junction microstructure and network configuration. Although metal nanowire printings, such as silver nanowires (AgNWs) or AgNWs/semiconductor oxide bilayer, have great potential to replace traditional ITO, efficient and selective nanoscale integration of nanowires is still challenging owing to high cross nanowire junction resistance. Herein, pulsed laser irradiation under controlled conditions is used to generate local crystalline nanojoining of AgNWs without affecting other regions of the network, resulting in significantly improved optoelectronic performance. The method, laser-induced plasmonic welding (LPW), can be applied to roll-to-roll printed AgNWs percolating networks on PET substrate. First principle simulations and experimental characterizations reveal the mechanism of crystalline nanojoining originated from thermal activated isolated metal atom flow over nanowire junctions. Molecular dynamic simulation results show an angle-dependent recrystallization process during LPW. The excellent optoelectronic performance of AgNW/PET has achieved Rs ∼ 5 Ω/sq at high transparency (91% @λ = 550 nm). PMID:26390281

  4. Improvement of polypyrrole nanowire devices by plasmonic space charge generation: high photocurrent and wide spectral response by Ag nanoparticle decoration

    NASA Astrophysics Data System (ADS)

    Lee, S.-H.; Bae, J.; Lee, S. W.; Jang, J.-W.

    2015-10-01

    In this study, improvement of the opto-electronic properties of non-single crystallized nanowire devices with space charges generated by localized surface plasmon resonance (LSPR) is demonstrated. The photocurrent and spectral response of single polypyrrole (PPy) nanowire (NW) devices are increased by electrostatically attached Ag nanoparticles (Ag NPs). To take advantage of plasmon-exciton coupling in the photocurrent of the device, 80 nm of Ag NPs (454 nm = λmax) were chosen for matching the maximum absorption with PPy NWs (442 nm = λmax). The photocurrent density is remarkably improved, up to 25.3 times (2530%), by the Ag NP decoration onto the PPy NW (PPyAgNPs NW) under blue light (λ = 425-475 nm) illumination. In addition, the PPyAgNPs NW shows a photocurrent decay time twice that of PPy NW, as well as an improved spectral response of the photocurrent. The improved photocurrent efficiency, decay time, and spectral response resulted from the space charges generated by the LSPR of Ag NPs. Furthermore, the increasing exponent (m) of the photocurrent (JPC ~ Vm) and finite-differential time domain (FDTD) simulation straightforwardly indicate relatively large plasmonic space charge generation under blue light illumination. These results prove that the performance of non-single crystallized polymer nanowire devices can also be improved by plasmonic enhancement.In this study, improvement of the opto-electronic properties of non-single crystallized nanowire devices with space charges generated by localized surface plasmon resonance (LSPR) is demonstrated. The photocurrent and spectral response of single polypyrrole (PPy) nanowire (NW) devices are increased by electrostatically attached Ag nanoparticles (Ag NPs). To take advantage of plasmon-exciton coupling in the photocurrent of the device, 80 nm of Ag NPs (454 nm = λmax) were chosen for matching the maximum absorption with PPy NWs (442 nm = λmax). The photocurrent density is remarkably improved, up to 25.3 times

  5. Structure and stability of acrolein and allyl alcohol networks on Ag(111) from density functional theory based calculations with dispersion corrections

    NASA Astrophysics Data System (ADS)

    Ferullo, Ricardo M.; Branda, Maria Marta; Illas, Francesc

    2013-11-01

    The interaction of acrolein and allyl alcohol with the Ag(111) surface has been studied by means of periodic density functional theory based calculations including explicitly dispersion terms. Different coverage values have been explored going from isolated adsorbed molecules to isolated dimers, interacting dimers or ordered overlayers. The inclusion of the dispersion terms largely affects the calculated values of the adsorption energy and also the distance between adsorbed molecule and the metallic surface but much less the adsorbate-adsorbate interactions. Owing to the large dipole moment of acrolein, the present calculations predict that at high coverage this molecule forms a stable extensive two-dimensional network on the surface, caused by the alignment of the adsorbate dipoles. For the case of allyl alcohol, dimers and complex networks exhibit similar stability.

  6. Enhanced transparent conducting networks on plastic substrates modified with highly oxidized graphene oxide nanosheets.

    PubMed

    Woo, Jong Seok; Sin, Dong Hun; Kim, Haena; Jang, Jeong In; Kim, Ho Young; Lee, Geon-Woong; Cho, Kilwon; Park, Soo-Young; Han, Joong Tark

    2016-03-28

    Atomically thin and two-dimensional graphene oxide (GO) is a very fascinating material because of its functional groups, high transparency, and solution processability. Here we show that highly oxidized GO (HOGO) nanosheets serve as an effective interfacial modifier of transparent conducting films with one-dimensional (1D) silver nanowires (AgNWs) and single-walled carbon nanotubes (SWCNTs). Optically transparent and small-sized GO nanosheets, with minimal sp(2) domains, were successfully fabricated by step-wise oxidation and exfoliation of graphite. We demonstrated that under-coated HOGO further decreases the sheet resistance of the SWCNT film top-coated with HOGO by increasing the contact area between the SWCNTs and HOGO nanosheets by generating hole carriers in the SWCNT as a result of charge transfer. Moreover, HOGO nanosheets with AgNWs contribute to the efficient thermal joining of AgNW networks on plastic substrates by limiting the thermal embedding of AgNWs into the plastic surface, resulting in efficient decrease of the sheet resistance. Furthermore, flexible organic photovoltaic cells with GO-modified AgNW anodes on a flexible substrate were successfully demonstrated. PMID:26946993

  7. Silver nanowire networks embedded in urethane acrylate for flexible capacitive touch sensor

    NASA Astrophysics Data System (ADS)

    Kim, Youngmin; Kim, Jong-Woong

    2016-02-01

    Flexible electrodes based on a percolated network of silver nanowires (AgNWs) and polymer are considered one of the best candidates for fabrication of flexible and even rollable touch sensors. A general approach to make the AgNW transparent electrode is based on an overcoating of AgNW dispersion onto a pre-formed transparent film. However, in that case, the nanowires could be easily detached from the film, because of the poor adhesion between them. Herein an inverted layer processing method has been employed to bury the AgNWs into the surface of a transparent polymer to enhance the adhesion. For this, a highly stiff and transparent polyurethane acrylate (PUA) was newly designed and synthesized by adding a cross-linker to the pre-polymer, with AgNWs patterned for a capacitive sensor then being successfully embedded in its surface to produce. By this unique structure with the PUA, highly transparent, conductive and mechanically more reliable capacitive touch sensor could be fabricated. The sensing capability and mechanical stability were confirmed by cyclic bend testing to a curvature radius of 0.5 mm.

  8. Spatial and temporal variation of surface-enhanced Raman scattering at Ag nanowires in aqueous solution

    SciTech Connect

    Clayton, Daniel A.; McPherson, Tyler; Pan, Shanlin; Chen, Mingyang; Dixon, David A.; Hu, Dehong

    2012-12-13

    We present surface enhanced Raman spectroscopy (SERS) and Raman imaging of small organic molecules at well-defined nanostructures formed by single silver nanowires (NWs). We show that SERS can be obtained at single, crossed, and bundled Ag NWs for mercaptopyridine, adenine, cytosine, guanine, and thymine. Crossed wires and parallel Ag NWs have SERS enhancement factors much higher than single Ag NWs. New additional junctions formed by a silver nanoparticle and a single Ag NW, and bundled NWs provide SERS intensity higher than a single Ag NW. The SERS signal of single Ag NWs can be further enhanced by decorating the Ag NW surface with gold nanoparticles using electroless deposition. Single Ag NW Raman imaging with a 10 ms time resolution when compared with photoluminescence (PL) imaging results reveal a different dynamic response of SERS and PL under steady state laser excitation. Dynamic photoluminescence blinking activities are suppressed in the presence of the surface coating of Raman active molecules (e.g., mercaptopyridine) and the SERS signal is quite stable in a wide field excitation configuration. The Discrete Dipole Approximation (DDA) method was used to calculate the local field intensity that can be applied to help understand the enhanced PL and SERS at the junction of Ag NWs

  9. Electrically and mechanically enhanced Ag nanowires-colorless polyimide composite electrode for flexible capacitive sensor

    NASA Astrophysics Data System (ADS)

    Kim, Dae-Gon; Kim, Jiwan; Jung, Seung-Boo; Kim, Young-Sung; Kim, Jong-Woong

    2016-09-01

    Silver nanowire (AgNW) network is known for its low percolation threshold, high conductivity and good flexibility, therefore, considered one of the best candidates for fabrication of flexible and transparent electrodes. However, a general approach to make the AgNWs-based electrodes, an overcoating of nanowire dispersion onto a transparent polymer, should make an issue of poor mechanical stability, mainly caused by low adhesion between the nanowires and polymer. In addition, a thin insulating layer of polyvinylpyrrolidone (PVP) formed on the surface of AgNWs deteriorates the conductivity of their network, which means that a post-processing such as high temperature annealing is essentially needed. Here we employed a plasma treatment with an inert gas to remove the residual PVP layer, so that the conductivity could be enhanced without employing any high temperature processing. Interestingly, the optical transmittance in the wavelength near 400 nm was also increased, resulting in more neutral coloration of the electrode. An inverted layer processing made the nanowires to be partially buried at the surface of colorless polyimide (cPI), so that the enhancement of mechanical stability and connectivity with overlying materials were simultaneously achieved.

  10. Pollen-inferred quantitative reconstructions of Holocene land-cover in NW Europe for the evaluation of past climate-vegetation feedbacks - The Swedish LANDCLIM project and the NordForsk LANDCLIM network

    NASA Astrophysics Data System (ADS)

    Gaillard, Marie-Jose; Sugita, Shinya; Rundgren, Mats; Smith, Benjamin; Mazier, Florence; Trondman, Anna-Kari; Fyfe, Ralph; Kokfelt, Ulla; Nielsen, Anne-Birgitte; Strandberg, Gustav

    2010-05-01

    Reliable predictive models are needed to describe potential future climate changes and their impacts. Land surface-atmosphere feedbacks and their impacts on climate are a current priority in the climate modelling community, but reliable records of long-term land use and vegetation change required for model evaluation are limited. Palaeoecological and palaeo-climatic data provide a unique record of the past changes in vegetation, land use and climate on time scales relevant to vegetation processes and global change projections. The application of a new technique (the REVEALS model (Sugita 2007) to landscape reconstruction using fossil pollen data makes robust comparisons with vegetation model output possible . The model corrects for biases caused by e.g. inter-taxonomic differences in pollen productivity and dispersal. Our results show that pollen percentages, a traditional indicator of land cover changes, generally underestimate the unforested areas and certain broad-leaved trees such as Corylus and Tilia, while they often overestimate Betula and Pinus (see Cui et al. BG 6.2). Climate models use simplified land-surface classifications (plant functional types (PFTs)), such as grass (i.e. open land), deciduous trees, and conifers. Therefore, the observed large discrepancies in past land cover between the REVEALS estimates and pollen percentages are expected to influence model outcomes of the Holocene regional climate in NW Europe. The LANDCLIM project and research network (sponsored by the Swedish [VR] and Nordic [NordForsk] Research Councils) aim to quantify human-induced changes in regional vegetation/land-cover in NW Europe during the Holocene, and to evaluate the effects of these changes on the regional climate through altered feedbacks. We use the REVEALS model, theoretically derived and empirically tested, to estimate the percentage cover of taxa and groups of taxa (PFTs) from fossil pollen data for selected time windows of the Holocene, at a spatial resolution

  11. BaFe12O19-chitosan Schiff-base Ag (I) complexes embedded in carbon nanotube networks for high-performance electromagnetic materials

    NASA Astrophysics Data System (ADS)

    Zhao, Jie; Xie, Yu; Guan, Dongsheng; Hua, Helin; Zhong, Rong; Qin, Yuancheng; Fang, Jing; Liu, Huilong; Chen, Junhong

    2015-07-01

    The multiwalled carbon nanotubes/BaFe12O19-chitosan (MCNTs/BF-CS) Schiff base Ag (I) complex composites were synthesized successfully by a chemical bonding method. The morphology and structures of the composites were characterized with electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques. Their conductive properties were measured using a four-probe conductivity tester at room temperature, and their magnetic properties were tested by a vibrating sample magnetometer. The results show that the BF-CS Schiff base Ag (I) complexes are embedded into MCNT networks. When the mass ratio of MCNTs and BF-CS Schiff base is 0.95:1, the conductivity, Ms (saturation magnetization), Mr (residual magnetization), and Hc (coercivity) of the BF-CS Schiff base composites reach 1.908 S cm-1, 28.20 emu g-1, 16.66 emu g-1 and 3604.79 Oe, respectively. Finally, a possible magnetic mechanism of the composites has also been proposed.

  12. BaFe12O19-chitosan Schiff-base Ag (I) complexes embedded in carbon nanotube networks for high-performance electromagnetic materials

    PubMed Central

    Zhao, Jie; Xie, Yu; Guan, Dongsheng; Hua, Helin; Zhong, Rong; Qin, Yuancheng; Fang, Jing; Liu, Huilong; Chen, Junhong

    2015-01-01

    The multiwalled carbon nanotubes/BaFe12O19-chitosan (MCNTs/BF-CS) Schiff base Ag (I) complex composites were synthesized successfully by a chemical bonding method. The morphology and structures of the composites were characterized with electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques. Their conductive properties were measured using a four-probe conductivity tester at room temperature, and their magnetic properties were tested by a vibrating sample magnetometer. The results show that the BF-CS Schiff base Ag (I) complexes are embedded into MCNT networks. When the mass ratio of MCNTs and BF-CS Schiff base is 0.95:1, the conductivity, Ms (saturation magnetization), Mr (residual magnetization), and Hc (coercivity) of the BF-CS Schiff base composites reach 1.908 S cm−1, 28.20 emu g−1, 16.66 emu g−1 and 3604.79 Oe, respectively. Finally, a possible magnetic mechanism of the composites has also been proposed. PMID:26218269

  13. Flexible prototype thermoelectric devices based on Ag2Te and PEDOT:PSS coated nylon fibre

    NASA Astrophysics Data System (ADS)

    Finefrock, Scott W.; Zhu, Xiaoqin; Sun, Yanming; Wu, Yue

    2015-03-01

    p- and n-type Ag2Te nanocrystals are coated separately onto nylon fibres to create flexible composites. A prototype thermoelectric device made using such fibres produces ~0.8 nW in a 20 K temperature difference. This is improved to over 5 nW by using a conducting polymer as the p-type material.p- and n-type Ag2Te nanocrystals are coated separately onto nylon fibres to create flexible composites. A prototype thermoelectric device made using such fibres produces ~0.8 nW in a 20 K temperature difference. This is improved to over 5 nW by using a conducting polymer as the p-type material. Electronic supplementary information (ESI) available: Sheet resistance of Ag2Te nanocrystal coated nylon fibre mesh made using nanocrystals of various sizes. Details of MMR Seebeck coefficient measurements. See DOI: 10.1039/c5nr00058k

  14. Chemiluminescent lateral-flow immunoassays by using in-situ synthesis of CdS NW photosensor.

    PubMed

    An, Byoung-Gi; Kim, Hong-Rae; Kang, Min-Jung; Park, Jae-Gwan; Chang, Young Wook; Pyun, Jae-Chul

    2016-07-13

    A hypersensitive CdS nanowire (NW) photosensor was fabricated by an in-situ synthesis process that involved the direct synthesis of CdS NWs on an interdigitated electrode (IDE). Analysis of the photoresponse properties showed that the newly synthesized photosensor had enhanced sensitivity and a highly reproducible photoresponse compared to photosensors prepared from CdS NW suspensions. The NW photosensor was applied to measure the chemiluminescence of luminol, and the sensitivity was compared to a commercial photosensing system. Finally, the feasibility of the CdS NW photosensor for the application to the medical diagnosis of the human hepatitis B surface antigen (hHBsAg) was demonstrated using a lateral-flow immunoassay with a chemiluminescent signal band. PMID:27237842

  15. Spatial biostratigraphy of NW Pakistan

    NASA Astrophysics Data System (ADS)

    Shafique, Naseer Ahmed

    2001-07-01

    Mesozoic to Cenozoic biostratigraphy of NW Pakistan has been conducted in order to document the temporal and spatial relationship between different marine strata with the help of remote sensing and Geographic Information Systems (GIS). These relationships were then used to help distinguish different tectonostratigraphic units in the Waziristan and the Kurram areas located at the northwestern margin of the Indo-Pakistani craton. Extensive biostratigraphic work in the Waziristan and Kurram areas enabled to distinguish five tectonostratigraphic units and two significant unconformities in the study area. Different foraminiferal zones from Early Jurassic to Middle Eocenewere developed, although due to random samples these zones are not continuous in the sedimentary record. However continuous biozonation from the Late Paleocene P4 to the Early Eocene P9 (Bolli, 1985) biozone was observed. It is observed that the Santonian stage is generally missing in the sedimentary sequence, and it is only found in the olistoliths. This implies that during the Campanian stage there was instability in the shelf due to ophiolite obduction, which caused the displacement of the Santonian strata. The absence of Early Paleocene (Zone P1--P3) microfauna is suggested by rapid subsidence of the NW Indian shelf beginning in the early Paleocene. Moreover, index fossils for the Palpha, P1a, b, c, d, P2 and P3 biozones are absent in the melange of the Thal area suggesting regional uplift during the Paleocene. The presence of Planorotalites pseudomenardii P4 zone microfauna above the unconformable Upper Cretaceous Kahi melange strata suggest the India-Asia collision age between 58 Ma--56 Ma. Foraminiferal biostratigraphy of upper Cretaceous olistoliths was conducted from the Mughal Kot gorge, Baluchistan, Pakistan in order to reveal the depositional history of Late Santonian aged (Dicarinella asymmetrica zone) olistoliths and associated upper Cretaceous to early Tertiary Indo-Pakistani shelf strata

  16. Fabrication of Ag nanowire and Al-doped ZnO hybrid transparent electrodes

    NASA Astrophysics Data System (ADS)

    You, Sslimsearom; Park, Yong Seo; Choi, Hyung Wook; Kim, Kyung Hwan

    2016-01-01

    Among the materials used as transparent electrodes, silver nanowires (AgNWs) have attracted attention because of their high transmittance and excellent conductivity. However, AgNWs have shortcomings, including their poor adhesion, oxidation by atmospheric oxygen, and unstable characteristics at high temperature. To overcome these shortcomings, multi-layer thin films with an aluminum-doped zinc oxide (AZO)/AgNW/AZO structure were fabricated using facing targets sputtering. The samples heated to 350 °C exhibited stable electrical characteristics. In addition, the adhesion to the substrate was improved compared with AgNWs layer. The AZO/AgNW/AZO thin films with multilayer structure overcame the shortcomings of AgNWs, and we propose their use as transparent electrodes with excellent properties for optoelectronic applications.

  17. Increased spectral sensitivity of Si photodetector by surface plasmon effect of Ag nanowires

    NASA Astrophysics Data System (ADS)

    Kim, Hong-Sik; Kumar, Melvin David; Kim, Hyunki; Kim, Joondong

    2016-05-01

    Highly-sensitive Si photodetectors were prepared by using Ag nanowires (AgNWs). A transparent indium-tin-oxide (ITO) coating was coated on a Si substrate followed by spin-coating of AgNWs-containing solution. AgNWs having average length of 5-20 μm with a diameter of about 40-60 nm were observed in FESEM images. The haze effect of AgNWs was totally avoided because of the optimum value of diameter. The transmittance of above 85% was shown by AgNWs over a broad spectral range due to surface plasmon resonance effect. The AgNW-coated device showed an excellent rectifying ratio of 288. Under light illumination, AgNWs-coated device exhibited a significant photoresponse ratio of 5373. This advanced feature of AgNWs-templated method would be applied in broadband wavelength photodetection devices.

  18. Transparent capacitors with hybrid ZnO:Al and Ag nanowires as electrodes.

    PubMed

    Zhang, Guozhen; Wu, Hao; Wang, Xiao; Wang, Ti; Liu, Chang

    2016-03-11

    Transparent conducting films with a composite structure of AlZnO-Ag nanowires (AgNWs) have been prepared by atomic layer deposition. The sheet resistance was reduced from 120 to 9 Ω when the AgNW networks were involved. Transparent capacitors with Al2O3-TiO2-Al2O3 dielectrics were fabricated on the composite electrodes and demonstrated a capacitance density of 10.1 fF μm(-2), which was significantly higher than that of capacitors with AlZnO electrodes (8.8 fF μm(-1)). The capacitance density remained almost unchanged in a broad frequency range from 3 kHz to 1 MHz. Moreover, a low leakage current density of 2.4 × 10(-7) A cm(-2) at 1 V was achieved. Transparent and flexible capacitors were also fabricated using the composite electrodes, and demonstrated an improved bendability. The transparent capacitors showed an average optical transmittance over 70% in the visible range, and thus open the door to practical applications in transparent integrated circuits. PMID:26866788

  19. Improvement of polypyrrole nanowire devices by plasmonic space charge generation: high photocurrent and wide spectral response by Ag nanoparticle decoration.

    PubMed

    Lee, S-H; Bae, J; Lee, S W; Jang, J-W

    2015-11-01

    In this study, improvement of the opto-electronic properties of non-single crystallized nanowire devices with space charges generated by localized surface plasmon resonance (LSPR) is demonstrated. The photocurrent and spectral response of single polypyrrole (PPy) nanowire (NW) devices are increased by electrostatically attached Ag nanoparticles (Ag NPs). To take advantage of plasmon-exciton coupling in the photocurrent of the device, 80 nm of Ag NPs (454 nm = λmax) were chosen for matching the maximum absorption with PPy NWs (442 nm = λmax). The photocurrent density is remarkably improved, up to 25.3 times (2530%), by the Ag NP decoration onto the PPy NW (PPyAgNPs NW) under blue light (λ = 425-475 nm) illumination. In addition, the PPyAgNPs NW shows a photocurrent decay time twice that of PPy NW, as well as an improved spectral response of the photocurrent. The improved photocurrent efficiency, decay time, and spectral response resulted from the space charges generated by the LSPR of Ag NPs. Furthermore, the increasing exponent (m) of the photocurrent (JPC ∼ V(m)) and finite-differential time domain (FDTD) simulation straightforwardly indicate relatively large plasmonic space charge generation under blue light illumination. These results prove that the performance of non-single crystallized polymer nanowire devices can also be improved by plasmonic enhancement. PMID:26413791

  20. Discrete hexamer water clusters and 2D water layer trapped in three luminescent Ag/tetramethylpyrazine/benzene-dicarboxylate hosts: 1D chain, 2D layer and 3D network

    NASA Astrophysics Data System (ADS)

    Mei, Hong-Xin; Zhang, Ting; Huang, Hua-Qi; Huang, Rong-Bin; Zheng, Lan-Sun

    2016-03-01

    Three mix-ligand Ag(I) coordination compounds, namely, {[Ag10(tpyz) 5(L1) 5(H2 O)2].(H2 O)4}n (1, tpyz = 2,3,4,5-tetramethylpyrazine, H2 L1 = phthalic acid), [Ag4(tpyz) 2(L2) 2(H2 O)].(H2 O)5}n (2, H2 L2 = isophthalic acid) {[Ag2(tpyz) 2(L3) (H2 O)4].(H2 O)8}n (3, H2 L3 = terephthalic acid), have been synthesized and characterized by elemental analysis, IR, PXRD and X-ray single-crystal diffraction. 1 exhibits a 2D layer which can be simplified as a (4,4) net. 2 is a 3D network which can be simplified as a (3,3)-connected 2-nodal net with a point symbol of {102.12}{102}. 3 consists of linear [Ag(tpyz) (H2 O)2]n chain. Of particular interest, discrete hexamer water clusters were observed in 1 and 2, while a 2D L10(6) water layer exists in 3. The results suggest that the benzene dicarboxylates play pivotal roles in the formation of the different host architectures as well as different water aggregations. Moreover, thermogravimetric analysis (TGA) and emissive behaviors of these compounds were investigated.

  1. Improvement of polypyrrole nanowire devices by plasmonic space charge generation: high photocurrent and wide spectral response by Ag nanoparticle decoration

    NASA Astrophysics Data System (ADS)

    Lee, Seung-Hoon; Lee, Seung Woo; Jang, Jaw-Won

    In this study, improvement of the opto-electronic properties of non-single crystallized nanowire devices with space charges generated by localized surface plasmon resonance (LSPR) is demonstrated. The photocurrent and spectral response of single polypyrrole (PPy) nanowire (NW) devices are increased by electrostatically attached Ag nanoparticles (Ag NPs). The photocurrent density is remarkably improved, up to 25.3 times, by the Ag NP decoration onto the PPy NW (PPyAgNPs NW) under blue light illumination. In addition, the PPyAgNPs NW shows a photocurrent decay time twice that of PPy NW, as well as an improved spectral response of the photocurrent. The improved photocurrent efficiency, decay time, and spectral response resulted from the space charges generated by the LSPR of Ag NPs. Furthermore, the increasing exponent (m) of the photocurrent (JPC ~Vm) and finite-differential time domain (FDTD) simulation straightforwardly indicate relatively large plasmonic space charge generation. Supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (no. 2013K1A3A1A32035429 and 2015R1A1A1A05027681).

  2. Development of Au-Ag nanowire mesh fabrication by UV-induced approach

    SciTech Connect

    Saggar, Siddhartha; Predeep, Padmanabhan

    2014-10-15

    In an attempt to overcome the limitations of the presently prevailing transparent conducting electrode (TCE) - indium tin oxide (ITO) - many materials have been considered for replacing ITO. Recently, a novel method has been reported for the synthesis of Au-Ag nanowire (NW) mesh, and tested successfully for organic-light-emitting-diodes (OLEDs). It employs UV-induced reduction of gold- and silver- precursors to form Au-Ag NW mesh. In this report, Au-Ag NW mesh thin films are synthesized on glass substrates with an objective for use as facing-electrode for Organic Photovoltaics. Various issues and factors affecting the fabrication-process have been improved, and are also discussed here. The electrode showed good transmitivity, of around 95% (excluding that of glass substrate). The advantage of the technique is its simple processing method and cost-effectiveness.

  3. AGS II

    SciTech Connect

    Palmer, R.B.

    1984-01-01

    Interest in rare K decays, neutrino oscillations and other fields have generated an increasing demand for running, and improved intensity and duty cycle, at the AGS. Current projects include acceleration of polarized protons and light ions (up to mass 32). Future plans are for a booster to increase intensity and allow heavy ions (up to mass 200), and a stretcher to give 100% duty cycle. A later upgrade could yield an average current of 32 ..mu.. amps. 6 figures, 2 tables.

  4. Silicon nanowire arrays coated with electroless Ag for increased surface-enhanced Raman scattering

    NASA Astrophysics Data System (ADS)

    Bai, Fan; Li, Meicheng; Fu, Pengfei; Li, Ruike; Gu, Tiansheng; Huang, Rui; Chen, Zhao; Jiang, Bing; Li, Yingfeng

    2015-05-01

    The ordered Ag nanorod (AgNR) arrays are fabricated through a simple electroless deposition technique using the isolated Si nanowire (SiNW) arrays as the Ag-grown scaffold. The AgNR arrays have the single-crystallized structure and the plasmonic crystal feature. It is found that the formation of the AgNR arrays is strongly dependent on the filling ratio of SiNWs. A mechanism is proposed based on the selective nucleation and the synergistic growth of Ag nanoparticles on the top of the SiNWs. Moreover, the special AgNR arrays grown on the substrate of SiNWs exhibit a detection sensitivity of 10-15M for rhodamine 6G molecules, which have the potential application to the highly sensitive surface-enhanced Raman scattering sensors.

  5. BiPO4 photocatalyst employing synergistic action of Ag/Ag3PO4 nanostructure and graphene nanosheets

    NASA Astrophysics Data System (ADS)

    Mohaghegh, N.; Rahimi, E.

    2016-06-01

    Graphene-supported BiPO4/Ag/Ag3PO4 photocatalyst has been fabricated by simple hydrothermal and impregnation reaction. In BiPO4/Ag/Ag3PO4 based on Reduced Graphene Oxide (RGO), this network renders numerous pathways for rapid mass transport, strong adsorption and multireflection of incident light; meanwhile, the interface between BiPO4/Ag/Ag3PO4 and RGO increases the active sites and electron transfer rate. BiPO4/Ag/Ag3PO4 based on RGO noticeably exhibited high photocatalytic activity than that of BiPO4/Ag/Ag3PO4 and P25 under visible light irradiation for cationic dye (Rhodamine B), anionic dye (methyl orange) and 4-chlorophenol (4-CP) as a neutral pollutant, which are usually difficult to be degraded over the other catalysts. This enhanced photocatalytic activity of Graphene-supported BiPO4/Ag/Ag3PO4 for all pollutants could be mainly ascribed to the reinforced charge transfer from BiPO4/Ag/Ag3PO4 to RGO, which suppresses the recombination of electron/hole pairs. Besides that, this photocatalyst can be used repetitively with a high photocatalytic activity and no apparent loss of activity occurs. The results reveal that the RGO nanosheets work as a photocatalyst promoter during the photocatalytic reaction, leading to an improved photocatalytic activity.

  6. Preparation, characterization, and photocatalytic activity of porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts

    NASA Astrophysics Data System (ADS)

    Yang, Fan; Tian, Baozhu; Zhang, Jinlong; Xiong, Tianqing; Wang, Tingting

    2014-02-01

    Porous AgBr@Ag and AgBrI@Ag plasmonic photocatalysts were synthesized by a multistep route, including a dealloying method to prepare porous Ag, a transformation from Ag to AgBr and AgBrI, and a photo-reduction process to form Ag nanoparticles on the surface of AgBr and AgBrI. It was found that the porous structure kept unchanged during Ag was transferred into AgBr, AgBrI, AgBr@Ag, and AgBrI@Ag. Both porous AgBr@Ag and porous AgBrI@Ag showed much higher visible-light photocatalytic activity than cubic AgBr@Ag for the degradation of methyl orange, which is because the interconnected pore channels not only provide more reactive sites but also favor the transportation of photo-generated electrons and holes. For AgBrI@Ag, AgBrI solid solution formed at the interface of AgBr and AgI, and the phase junction can effectively separate the photo-generated electrons and holes, favorable to the improvement of photocatalytic activity. The optimal I content for obtaining the highest activity is ∼10 at.%.

  7. Polymorphism in Cs[AgZn(NCS)4].

    PubMed

    Güneş, Minna; Valkonen, Jussi

    2002-12-01

    The title compound, caesium silver zinc tetrathiocyanate, crystallizes in two polymorphic forms, in space groups P2(1)/n and C2/c. Both structures form a continuous three-dimensional network. The structure in C2/c contains a delocalized Ag atom in a binuclear-like anion, where two [Ag(NCS)(4)] units (delocalized Ag as an average) share two common NCS(-) ligands. PMID:12466595

  8. 9. LOOKING NW FROM EAST BANK OF SCHUYLKILL RIVER. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. LOOKING NW FROM EAST BANK OF SCHUYLKILL RIVER. - Philadelphia & Reading Railroad, Schuylkill River Viaduct, Spanning Schuylkill River, southeast of Roosevelt Boulevard Bridge, Philadelphia, Philadelphia County, PA

  9. AGS experiments - 1994, 1995, 1996

    SciTech Connect

    Depken, J.C.

    1997-01-01

    This report contains the following information on the Brookhaven AGS Accelerator complex: FY 1996 AGS schedule as run; FY 1997 AGS schedule (working copy); AGS beams 1997; AGS experimental area FY 1994 physics program; AGS experimental area FY 1995 physics program; AGS experimental area FY 1996 physics program; AGS experimental area FY 1997 physics program (in progress); a listing of experiments by number; two-phage summaries of each experiment begin here, also ordered by number; listing of publications of AGS experiments begins here; and listing of AGS experimenters begins here.

  10. Networks.

    ERIC Educational Resources Information Center

    Maughan, George R.; Petitto, Karen R.; McLaughlin, Don

    2001-01-01

    Describes the connectivity features and options of modern campus communication and information system networks, including signal transmission (wire-based and wireless), signal switching, convergence of networks, and network assessment variables, to enable campus leaders to make sound future-oriented decisions. (EV)

  11. Extreme precipitation events in NW Greece

    NASA Astrophysics Data System (ADS)

    Houssos, E. E.; Bartzokas, A.

    2006-02-01

    In this work, the extreme precipitation events in NW Greece are studied. The data used are daily precipitation totals recorded at the meteorological station of Ioannina University for the period 1970-2002. 156 days with precipitation totals above 35 mm (5% upper limit) are only considered. It is seen that, a minimum frequency of extreme precipitation events appears in the period 1986-1991, which is characterized by a high positive NAO index. For each of the 156 extreme precipitation days, at first, the mean sea level pressure pattern over Europe is constructed by using 273 grid point values. Using Factor Analysis, the dimensionality of the 156×273 data matrix is reduced to 156×5 (84% of the total variance) and then, Cluster Analysis is applied on the results of Factor Analysis. Thus, the 156 cases are grouped objectively to 11 clusters, revealing the main pressure patterns, which favour extreme precipitation in NW Greece. Seven of the patterns are encountered in winter and autumn, while three of them cover a period from autumn to spring and one appears mainly in summer. In all of them the cause of the extreme precipitation event is a low pressure system centred west of Greece or a low pressure trough extended eastwards or southwards up to Greece. In some cases the depression is so strong and extended that it covers the whole Europe and the Mediterranean. In the single summer pattern, rainfall is caused by an extension of the SW Asia thermal low up to the central Mediterranean.

  12. High-Performance Fully Nanostructured Photodetector with Single-Crystalline CdS Nanotubes as Active Layer and Very Long Ag Nanowires as Transparent Electrodes.

    PubMed

    An, Qinwei; Meng, Xianquan; Sun, Pan

    2015-10-21

    Long and single-crystalline CdS nanotubes (NTs) have been prepared via a physical evaporation process. A metal-semiconductor-metal full-nanostructured photodetector with CdS NTs as active layer and Ag nanowires (NWs) of low resistivity and high transmissivity as electrodes has been fabricated and characterized. The CdS NTs-based photodetectors exhibit high performance, such as lowest dark currents (0.19 nA) and high photoresponse ratio (Ilight/Idark ≈ 4016) (among CdS nanostructure network photodetectors and NTs netwok photodetectors reported so far) and very low operation voltages (0.5 V). The photoconduction mechanism, including the formation of a Schottky barrier at the interface of Ag NW and CdS NTs and the effect of oxygen adsorption process on the Schottky barrier has also been provided in detail based on the studies of CdS NTs photodetector in air and vacuum. Furthermore, CdS NTs photodetector exhibits an enhanced photosensitivity as compared with CdS NWs photodetector. The enhancement in performance is dependent on the larger surface area of NTs adsorbing more oxygen in air and the microcavity structure of NTs with higher light absorption efficiency and external quantum efficiency. It is believed that CdS NTs can potentially be useful in the designs of 1D CdS-based optoelectronic devices and solar cells. PMID:26457660

  13. Networking.

    ERIC Educational Resources Information Center

    Duvall, Betty

    Networking is an information giving and receiving system, a support system, and a means whereby women can get ahead in careers--either in new jobs or in current positions. Networking information can create many opportunities: women can talk about how other women handle situations and tasks, and previously established contacts can be used in…

  14. The AgNORs.

    PubMed

    Derenzini, M

    2000-04-01

    The structure and the function of interphase AgNORs and the importance of the "AgNOR" parameter in tumor pathology have been reviewed. Interphase AgNORs are structural-functional units of the nucleolus in which all the components necessary for ribosomal RNA synthesis are located. Two argyrophilic proteins involved in rRNA transcription and processing, nucleolin and nucleophosmin, are associated with interphase AgNORs and are responsible for their stainability with silver methods, thus allowing interphase AgNORs to be visulaized at light microscopic level, also in routine cyto-histopathological preparations. The number of interphase AgNORs is strictly related to rRNA transcriptional activity and, in continuously proliferating cells, to the rapidity of cell proliferation. Evaluation of the quantitative distribution of interphase AgNORs has been applied in tumor pathology both for diagnostic and prognostic purposes. The "AgNOR" parameter has been proved to represent a reliable tool for defining the clinical outcome of cancer disease, being an independent prognostic factor in many types of tumors. PMID:10588056

  15. AgRISTARS

    NASA Technical Reports Server (NTRS)

    1984-01-01

    An introduction to the overall AgRISTARS program, a general statement on progress, and separate summaries of the activities of each project, with emphasis on the technical highlights are presented. Organizational and management information on AgRISTARS is included in the appendices, as is a complete bibliography of publication and reports.

  16. AGS experiments: 1993 - 1994 - 1995

    SciTech Connect

    Depken, J.C.

    1996-04-01

    This report contains: FY 1995 AGS Schedule as Run; FY 1996-97 AGE Schedule (working copy); AGS Beams 1995; AGS Experimental Area FY 1993 Physics Program; AGS Experimental Area FY 1994 Physics Program; AGS Experimental Area FY 1995 Physics Program; AGS Experimental Area FY 1996 Physics Program (In progress); A listing of experiments by number; Two-page summaries of each experiment begin here, also ordered by number; Listing of publications of AGS experiments begins here; and Listing of AGS experimenters begins here. This is the twelfth edition.

  17. Ultrasmooth, extremely deformable and shape recoverable Ag nanowire embedded transparent electrode

    PubMed Central

    Nam, Sanggil; Song, Myungkwan; Kim, Dong-Ho; Cho, Byungjin; Lee, Hye Moon; Kwon, Jung-Dae; Park, Sung-Gyu; Nam, Kee-Seok; Jeong, Yongsoo; Kwon, Se-Hun; Park, Yun Chang; Jin, Sung-Ho; Kang, Jae-Wook; Jo, Sungjin; Kim, Chang Su

    2014-01-01

    Transparent electrodes have been widely used in electronic devices such as solar cells, displays, and touch screens. Highly flexible transparent electrodes are especially desired for the development of next generation flexible electronic devices. Although indium tin oxide (ITO) is the most commonly used material for the fabrication of transparent electrodes, its brittleness and growing cost limit its utility for flexible electronic devices. Therefore, the need for new transparent conductive materials with superior mechanical properties is clear and urgent. Ag nanowire (AgNW) has been attracting increasing attention because of its effective combination of electrical and optical properties. However, it still suffers from several drawbacks, including large surface roughness, instability against oxidation and moisture, and poor adhesion to substrates. These issues need to be addressed before wide spread use of metallic NW as transparent electrodes can be realized. In this study, we demonstrated the fabrication of a flexible transparent electrode with superior mechanical, electrical and optical properties by embedding a AgNW film into a transparent polymer matrix. This technique can produce electrodes with an ultrasmooth and extremely deformable transparent electrode that have sheet resistance and transmittance comparable to those of an ITO electrode. PMID:24763248

  18. Ultrasmooth, extremely deformable and shape recoverable Ag nanowire embedded transparent electrode.

    PubMed

    Nam, Sanggil; Song, Myungkwan; Kim, Dong-Ho; Cho, Byungjin; Lee, Hye Moon; Kwon, Jung-Dae; Park, Sung-Gyu; Nam, Kee-Seok; Jeong, Yongsoo; Kwon, Se-Hun; Park, Yun Chang; Jin, Sung-Ho; Kang, Jae-Wook; Jo, Sungjin; Kim, Chang Su

    2014-01-01

    Transparent electrodes have been widely used in electronic devices such as solar cells, displays, and touch screens. Highly flexible transparent electrodes are especially desired for the development of next generation flexible electronic devices. Although indium tin oxide (ITO) is the most commonly used material for the fabrication of transparent electrodes, its brittleness and growing cost limit its utility for flexible electronic devices. Therefore, the need for new transparent conductive materials with superior mechanical properties is clear and urgent. Ag nanowire (AgNW) has been attracting increasing attention because of its effective combination of electrical and optical properties. However, it still suffers from several drawbacks, including large surface roughness, instability against oxidation and moisture, and poor adhesion to substrates. These issues need to be addressed before wide spread use of metallic NW as transparent electrodes can be realized. In this study, we demonstrated the fabrication of a flexible transparent electrode with superior mechanical, electrical and optical properties by embedding a AgNW film into a transparent polymer matrix. This technique can produce electrodes with an ultrasmooth and extremely deformable transparent electrode that have sheet resistance and transmittance comparable to those of an ITO electrode. PMID:24763248

  19. 3. Top surface of dock including railroad tracks; looking NW ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Top surface of dock including railroad tracks; looking NW from shore end. Paving block mill location is partially visible on right one half of photo. - Pacific Creosoting Plant, West Dock, 5350 Creosote Place, Northeast, Bremerton, Kitsap County, WA

  20. 10. Side view of cane mill looking NW with steam ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. Side view of cane mill looking NW with steam engine in background. - Hacienda Azucarera La Esperanza, Steam Engine & Mill, 2.65 Mi. N of PR Rt. 2 Bridge over Manati River, Manati, Manati Municipio, PR

  1. 35. PRATER GRADE ROAD VIEW, FACING NW. NOTE WEATHERING STEEL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    35. PRATER GRADE ROAD VIEW, FACING NW. NOTE WEATHERING STEEL RAIL AND ROAD CUT IN DISTANCE. MONTEZUMA VALLEY OVERLOOK IS JUST TO RIGHT OF DISTANT ROAD CUT. - Mesa Verde National Park Main Entrance Road, Cortez, Montezuma County, CO

  2. 2. Photocopy of c. 1906 photograph looking NW at water ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Photocopy of c. 1906 photograph looking NW at water tower with mill pond and pump house in right center foreground; fuel oil storage tank in right background. - Laurel Valley Sugar Plantation, State Route 308, Thibodaux, Lafourche Parish, LA

  3. 8. August, 1971. SECOND FLOOR LOOKING NW. EVAPORATOR UNITS USED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. August, 1971. SECOND FLOOR LOOKING NW. EVAPORATOR UNITS USED IN SEQUENCE TO REDUCE OR CONCENTRATE BEET JUICE. - Utah Sugar Company, Garland Beet Sugar Refinery, Factory Street, Garland, Box Elder County, UT

  4. Elevation of deck truss span over creek, looking NW along ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Elevation of deck truss span over creek, looking NW along U.S. route 322. - Pennsylvania Railroad, Brandywine Valley Viaduct, Spanning Brandywine Creek & U.S. Route 322, Downingtown, Chester County, PA

  5. 4. Water treatment plant, view to NW, berm in foreground ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. Water treatment plant, view to NW, berm in foreground - Fort Benton Water Treatment Plant, Filtration Plant, Lots 9-13 of Block 7, Fort Benton Original Townsite at Missouri River, Fort Benton, Chouteau County, MT

  6. Perspective view NW by 310. Note the concrete pier extending ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Perspective view NW by 310. Note the concrete pier extending from the bridge in the foreground. This way to allow maximum water flow during floods and rainy periods. - Weaverland Bridge, Quarry Road spanning Conestoga Creek, Terre Hill, Lancaster County, PA

  7. Detail of third span from east end, looking NW. Note ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Detail of third span from east end, looking NW. Note that skew of pier is taken up in first panel of truss. - Pennsylvania Railroad, Selinsgrove Bridge, Spanning Susquehanna River, south of Cherry Island, Selinsgrove, Snyder County, PA

  8. 1. Barn 3. NW corner. Border shed (Barn A) in ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Barn 3. NW corner. Border shed (Barn A) in distance marks southern boundary of the original north barn area. Camera pointed SE. - Longacres, Barn 3, 1621 Southwest Sixteenth Street, Renton, King County, WA

  9. Herringbone and triangular patterns of dislocations in Ag, Au, and AgAu alloy films on Ru(0001).

    SciTech Connect

    Thayer, Gayle Echo; de la Figuera, Juan; Bartelt, Norman Charles; Carter, C. Barrington; Hwang, R. Q.; Thurmer, Konrad; Ling, W. L.; Hamilton, John C.; McCarty, Kevin F.

    2008-10-01

    We have studied the dislocation structures that occur in films of Ag, Au, and Ag{sub 0.5}Au{sub 0.5} alloy on a Ru(0001) substrate. Monolayer (ML) films form herringbone phases while films two or more layers thick contain triangular patterns of dislocations. We use scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) to determine how the film composition affects the structure and periodicity of these ordered structures. One layer of Ag forms two different herringbone phases depending on the exact Ag coverage and temperature. Low-energy electron microscopy (LEEM) establishes that a reversible, first-order phase transition occurs between these two phases at a certain temperature. We critically compare our 1 ML Ag structures to conflicting results from an X-ray scattering study [H. Zajonz et al., Phys. Rev. B 67 (2003) 155417]. Unlike Ag, the herringbone phases of Au and AgAu alloy are independent of the exact film coverage. For two layer films in all three systems, none of the dislocations in the triangular networks thread into the second film layer. In all three systems, the in-plane atomic spacing of the second film layer is nearly the same as in the bulk. Film composition does, however, affect the details of the two layer structures. Ag and Au films form interconnected networks of dislocations, which we refer to as 'trigons.' In 2 ML AgAu alloy, the dislocations form a different triangular network that shares features of both trigon and moire structures. Yet another well-ordered structure, with square symmetry, forms at the boundaries of translational trigon domains in 2 ML Ag films but not in Au films.

  10. Infection by Paramphistomidae trematodes in cattle from two agricultural regions in NW Uruguay and NW Spain.

    PubMed

    Sanchís, J; Sánchez-Andrade, R; Macchi, M I; Piñeiro, P; Suárez, J L; Cazapal-Monteiro, C; Maldini, G; Venzal, J M; Paz-Silva, A; Arias, M S

    2013-01-16

    The analysis of infection by Paramphistomidae trematodes was conducted in two agricultural regions with different knowledge on this parasitosis. Faecal and blood samples were collected from 374 cattle in Salto (NW Uruguay) where there is a lack of information about paramphistomosis. A total of 429 cattle from Galicia (NW Spain), an area with previous records of infection by gastric flukes, were sampled. Diagnostics of trematodosis was developed by using a copromicroscopic probe and an ELISA with excretory/secretory antigens collected from adult Calicophoron daubneyi (Paramphistomidae) specimens. Results were evaluated according intrinsic and extrinsic factors. In the Uruguay, the percentage of cattle passing Paramphistomidae-eggs by faeces was 7% (95% Confidence Interval 5, 10). A significantly higher prevalence of paramphistomosis in the Hereford × Angus cattle (OR=3.5) was recorded, as observed for the oldest ruminants (>3.5 years). An overall seroprevalence of 29% (25, 34) was obtained by ELISA, with the highest values in the Friesians (OR=3), the youngest bovines (<2.5 years) and dairy cattle (Friesians). Twenty-six percent (22, 30) of the cattle from Spain passed eggs by faeces, and cattle aged 2.5-7 years reached significant highest prevalences. By means of the ELISA, a percentage of 55 cattle (50, 59) had antibodies against the gastric fluke, and the highest seroprevalence was observed among the bovines under 6 years. It is concluded that paramphistomosis is on the increase in cattle from NW Spain, partly due to the absence of an effective treatment against the trematode. There is a need for reducing the risk of infection by Paramhistomidae spp. in cattle from Uruguay, especially by improving their management to avoid exposure to the gastric trematode. Further studies are in progress for identifying the species of Paramphistomidae affecting ruminants in Uruguay. PMID:22902261

  11. An Operational Coastal Forecasting System in Galicia (NW Spain)

    NASA Astrophysics Data System (ADS)

    Balseiro, C. F.; Carracedo, P.; Pérez, E.; Pérez, V.; Taboada, J.; Venacio, A.; Vilasa, L.

    2009-09-01

    The Galician coast (NW Iberian Peninsula coast) and mainly the Rias Baixas (southern Galician rias) are one of the most productive ecosystems in the world, supporting a very active fishing and aquiculture industry. This high productivity lives together with a high human pressure and an intense maritime traffic, which means an important environmental risk. Besides that, Harmful Algae Blooms (HAB) are common in this area, producing important economical losses in aquiculture. In this context, the development of an Operational Hydrodynamic Ocean Forecast System is the first step to the development of a more sophisticated Ocean Integrated Decision Support Tool. A regional oceanographic forecasting system in the Galician Coast has been developed by MeteoGalicia (the Galician regional meteorological agency) inside ESEOO project to provide forecasts on currents, sea level, water temperature and salinity. This system is based on hydrodynamic model MOHID, forced with the operational meteorological model WRF, supported daily at MeteoGalicia . Two grid meshes are running nested at different scales, one of ~2km at the shelf scale and the other one with a resolution of 500 m at the rias scale. ESEOAT (Puertos del Estado) model provide salinity and temperature fields which are relaxed at all depth along the open boundary of the regional model (~6km). Temperature and salinity initial fields are also obtained from this application. Freshwater input from main rivers are included as forcing in MOHID model. Monthly mean discharge data from gauge station have been provided by Aguas de Galicia. Nowadays a coupling between an hydrological model (SWAT) and the hydrodynamic one are in development with the aim to verify the impact of the rivers discharges. The system runs operationally daily, providing two days of forecast. First model verifications had been performed against Puertos del Estado buoys and Xunta de Galicia buoys network along the Galician coast. High resolution model results

  12. Low temperature preparation of Ag-doped ZnO nanowire arrays for sensor and light-emitting diode applications

    NASA Astrophysics Data System (ADS)

    Lupan, O.; Viana, B.; Cretu, V.; Postica, V.; Adelung, R.; Pauporté, T.

    2016-02-01

    Transition metal doped-oxide semiconductor nanostructures are important to achieve enhanced and new properties for advanced applications. We describe the low temperature preparation of ZnO:Ag nanowire/nanorod (NW/NR) arrays by electrodeposition at 90 °C. The NWs have been characterized by SEM, EDX, transmittance and photoluminescence (PL) measurements. The integration of Ag in the crystal is shown. Single nanowire/nanorod of ZnO:Ag was integrated in a nanosensor structure leading to new and enhanced properties. The ultraviolet (UV) response of the nanosensor was investigated at room temperature. Experimental results indicate that ZnO:Ag (0.75 μM) nanosensor possesses faster response/recovery time and better response to UV light than those reported in literature. The sensor structure has been also shown to give a fast response for the hydrogen detection with improved performances compared to pristine ZnO NWs. ZnO:Ag nanowire/nanorod arrays electrochemically grown on p-type GaN single crystal layer is also shown to act as light emitter in LED structures. The emission wavelength is red-shifted compared to pristine ZnO NW array. At low Ag concentration a single UV-blue emission is found whereas at higher concentration of dopant the emission is broadened and extends up to the red wavelength range. Our study indicates that high quality ZnO:Ag NW/NR prepared at low temperature by electrodeposition can serve as building nanomaterials for new sensors and light emitting diodes (LEDs) structures with low-power consumption.

  13. NW-MILO Acoustic Data Collection

    SciTech Connect

    Matzner, Shari; Myers, Joshua R.; Maxwell, Adam R.; Jones, Mark E.

    2010-02-17

    There is an enduring requirement to improve our ability to detect potential threats and discriminate these from the legitimate commercial and recreational activity ongoing in the nearshore/littoral portion of the maritime domain. The Northwest Maritime Information and Littoral Operations (NW-MILO) Program at PNNL’s Coastal Security Institute in Sequim, Washington is establishing a methodology to detect and classify these threats - in part through developing a better understanding of acoustic signatures in a near-shore environment. The purpose of the acoustic data collection described here is to investigate the acoustic signatures of small vessels. The data is being recorded continuously, 24 hours a day, along with radar track data and imagery. The recording began in August 2008, and to date the data contains tens of thousands of signals from small vessels recorded in a variety of environmental conditions. The quantity and variety of this data collection, with the supporting imagery and radar track data, makes it particularly useful for the development of robust acoustic signature models and advanced algorithms for signal classification and information extraction. The underwater acoustic sensing system is part of a multi-modal sensing system that is operating near the mouth of Sequim Bay. Sequim Bay opens onto the Straight of Juan de Fuca, which contains part of the border between the U.S. and Canada. Table 1 lists the specific components used for the NW-MILO system. The acoustic sensor is a hydrophone permanently deployed at a mean depth of about 3 meters. In addition to a hydrophone, the other sensors in the system are a marine radar, an electro-optical (EO) camera and an infra-red (IR) camera. The radar is integrated with a vessel tracking system (VTS) that provides position, speed and heading information. The data from all the sensors is recorded and saved to a central server. The data has been validated in terms of its usability for characterizing the

  14. Cysteine-Ag Cluster Hydrogel Confirmed by Experimental and Numerical Studies.

    PubMed

    Cui, Yanyan; Wang, Yaling; Zhao, Lina

    2015-10-01

    The native cysteine (Cys)-Ag3 cluster hydrogel is approved for the first time by both experimental and theoretical studies. From the detailed molecular structure and energy information, three factors are found to ensure the self-assembly of Cys and Ag3 , and result in the hydrogel. First, the Ag-S bonds make Cys and Ag3 form Cys-Ag3 -Cys monomer. Second, intermolecular hydrogen bonds between carboxyl groups of adjacent monomer push them self-assembled. Third, more monomer precisely self-assemble to produce the -[Cys-Ag3 -Cys]n multimer, e.g., a single molecular chain with the left-handed helix conformation, via a benign thermodynamic process. These multimers entangle together to form micro-network to trap water and produce hydorgel in situ. The hydrogen bonds of hydrogel are sensitive to thermal and proton stimuli, and the hydrogel presents lysosome targeting properties via fluorescent imaging with biocompatibility. PMID:26248576

  15. Quo vadis NW Black Sea benthic ecosystems?

    NASA Astrophysics Data System (ADS)

    Traian Gomoiu, Marian

    2016-04-01

    / thalasoterapy. Black Sea ecosystem restoration - Certainties and Uncertainties: Pressure on the Danube and other rivers has decreased, chemical discharges have decreased obviously, and yet there appear phenomena of water flowering - "red waters", hypoxia is still present at times and there is mass mortality of fish and other benthic organisms. Why? Signs of recovery should be considered cautiously and uncertainties may be resolved only in a longer time by increasing our scientific efforts. The results of the EU FP7 Project PERSEUS led to the identification of three important issues that should be resolved in order to achieve good environmental status: • Applying an adaptive management to increase the resilience of the ecosystems and to diminish the vulnerability of biodiversity; • Necessity of participative approach by stakeholders; • Identifying and obtaining adequate financial support for new R-D-I projects. Who are the actors in addressing and implementing the actions? • Academic educational and research institutions for adequate working condition; • More specialists trained for taxonomic groups; • Reasonable diversity of coordinating specialists, capable team leaders / satisfactory work packages; • Attracting NGO members towards nature conservation issues; • Resonable stakeholders committed to environmental issues. Studying the results of researches carried out by GeoEcoMar on the Romanian Black Sea coast in recent years, the author concluded that the major problems hampering progress towards a good ecosystem in NW Bent Black Sea are: • lack of diversity in the fields of research, both in theoretical and applied realms; • structural and functional consequences of ecological pressures and the disordered state of the ecosystems in the periods of paroxysmal eutrophication / pollution at the end of the 20th Century; • scarcity of data and knowledge on the Social-Economic System; • high costs of the new marine technology used directly in the sea and

  16. View south up 27th Street rightofway NW (formerly Lyons Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View south up 27th Street right-of-way NW (formerly Lyons Mill Road) along western edge of Female Union Band Cemetery. Vegetation obscures the cemetery's terraces. - Mount Zion Cemetery/ Female Union Band Cemetery, Bounded by 27th Street right-of-way N.W. (formerly Lyons Mill Road), Q Street N.W., & Mill Road N.W., Washington, District of Columbia, DC

  17. Fully and partially Li-stuffed diamond polytypes with Ag-Ge structures: Li2AgGe and Li2.53AgGe2.

    PubMed

    Henze, Alexander; Hlukhyy, Viktor; Fässler, Thomas F

    2015-02-01

    In view of the search for and understanding of new materials for energy storage, the Li-Ag-Ge phase diagram has been investigated. High-temperature syntheses of Li with reguli of premelted Ag and Ge led to the two new compounds Li(2)AgGe and Li(2.80-x)AgGe(2) (x = 0.27). The compounds were characterized by single-crystal X-ray diffraction. Both compounds show diamond-polytype-like polyanionic substructures with tetrahedrally coordinated Ag and Ge atoms. The Li ions are located in the channels provided by the network. The compound Li(2)AgGe crystallizes in the space group R3̅m (No. 166) with lattice parameters of a = 4.4424(6) Å and c = 42.7104(6) Å. All atomic positions are fully occupied and ordered. Li(2.80-x)AgGe(2) crystallizes in the space group I4(1)/a (No. 88) with lattice parameters of a = 9.7606(2) Å and c = 18.4399(8) Å. The Ge substructure consists of unique (1)(∞)[Ge(10)] chains that are interconnected by Ag atoms to build a three-dimensional network. In the channels of this diamond-like network, not all of the possible positions are occupied by Li ions. Li atoms in the neighborhood of the vacancies show considerably enlarged displacement vectors. The occurrence of the vacancy is traced back to short Li-Li distances in the case of the occupation of the vacancy with Li. Both compounds are not electron-precise Zintl phases. The density of states, band structure, and crystal orbital Hamilton population analyses of Li(2.80-x)AgGe(2 )reveal metallic properties, whereas a full occupation of all Li sites leads to an electron-precise Zintl compound within a rigid-band model. Li(2)AgGe reveals metallic character in the ab plane and is a semiconductor with a small band gap along the c direction. PMID:25521213

  18. 14. LOOKING NW FROM EASTERN ABUTMENT, WITH SWING SPAN IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. LOOKING NW FROM EASTERN ABUTMENT, WITH SWING SPAN IN OPEN POSITION. NOTE BUMPER ON CURVED RACK AT BOTTOM LEFT OF FRAME. - Chicago, Milwaukee & St. Paul Railway, Bridge No. Z-6, Spanning North Branch of Chicago River, South of Cortland Street, Chicago, Cook County, IL

  19. MARINA & MAINE STREETS FACING NW. DARKER COLORED HOME ON ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    MARINA & MAINE STREETS FACING NW. DARKER COLORED HOME ON SE CORNER. NYSTROM VILLAGE, LIKE ATCHISON VILLAGE (HAER CA-326-N), HOUSED WORKERS DURING WORLD WAR II - Rosie the Riveter National Historical Park, Nystrom Village, Marina & Maine Streets, Richmond, Contra Costa County, CA

  20. 34. GENERAL VIEW LOOKING NW SHOWING (LEFT TO RIGHT), WIRE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    34. GENERAL VIEW LOOKING NW SHOWING (LEFT TO RIGHT), WIRE MILL NO. 1, WIRE MILL NO. 2, SCALE HOUSE, BUILDING NO. 69B. (ABUTS NJ-122E-33). - John A. Roebling's Sons Company, Kinkora Works, Support Systems, Roebling, Burlington County, NJ

  1. 25. Stereo view version of Southeast Light looking NW with ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    25. Stereo view version of Southeast Light looking NW with picket fence ca. 1890. From a contact print of a glass negative from the Mansfield Collection. - Block Island Southeast Light, Spring Street & Mohegan Trail at Mohegan Bluffs, New Shoreham, Washington County, RI

  2. VIEW LOOKING NW FROM CATWALK OF SE TOWER, SHOWING INTERIOR ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING NW FROM CATWALK OF SE TOWER, SHOWING INTERIOR ELEVATION OF TOWER OPPOSITE. NOTE THAT CONCRETE PIERS DO NOT MATCH FOOTINGS PROJECTING SLIGHTLY ABOVE WATER. - Lake Shore & Michigan Southern Railway, Bridge No. 6, Spanning Calumet River, east of Chicago Skyway (I-90), Chicago, Cook County, IL

  3. 17. Detail of base of 'Flying Ram' in NW corner ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    17. Detail of base of 'Flying Ram' in NW corner of foyer. Camera is looking SW. First doorway beyond fountain leads to basement and men's lounge seen in WA-197-44. Second doorway leads to storefront corner at Seventh Ave. and Olive Way. (Aug. 1991) - Fox Theater, Seventh Avenue & Olive Way, Seattle, King County, WA

  4. Freeze-dried PVP-Ag+ precursors to novel AgBr/AgCl-Ag hybrid nanocrystals for visible-light-driven photodegradation of organic pollutants

    NASA Astrophysics Data System (ADS)

    Chen, Deliang; Chen, Qianqian; Zhang, Wenjie; Ge, Lianfang; Shao, Gang; Fan, Bingbing; Lu, Hongxia; Zhang, Rui; Yang, Daoyuan; Shao, Guosheng

    2015-04-01

    AgBr/AgCl-Ag nanocrystals with various molar Br-to-Ag ratios (RBr/Ag = 0, 1/3, 1/2, 2/3, 1) and different photoreduction times (0-20 min) were synthesized via stepwise liquid-solid reactions using the freeze-dried PVP-Ag+ hybrid as the Ag source, followed by a photoreduction reaction. The AgBr/AgCl-Ag7.5(1:2) nanocrystals obtained take on a spherical morphology with a particle-size range of 58 ± 15 nm. The photocatalytic performance of AgBr/AgCl-Ag nanocrystals was evaluated by photodegrading organic dyes, 4-chlorophenol and isopropanol under artificial visible light (λ ⩾ 420 nm, 100 mW cm-2). For the decomposition of rhodamine B, the AgBr/AgCl-Ag7.5(1:2) nanocrystals has a photodegradation rate of ∼0.87 min-1, ∼159 times higher than that (∼0.0054 min-1) of TiO2 (P25), whereas the AgCl-Ag and AgBr-Ag nanocrystals have photodegradation rates of 0.35 min-1 and 0.45 min-1, respectively. The efficient separation of photogenerated electron-hole pairs in the ternary system consisting of AgBr, AgCl and Ag species plays a key role in the enhancement of photocatalytic performance.

  5. Evidence for volcanism in NW Ishtar Terra, Venus

    NASA Technical Reports Server (NTRS)

    Gaddis, L.; Greeley, Ronald

    1989-01-01

    Venera 15/16 radar data for an area in NW Ishtar Terra, Venus, show an area with moderate radar return and a smooth textured surface which embays low lying areas of the surrounding mountainous terrain. Although this unit may be an extension of the lava plains of Lakshmi Planum to the southeast, detailed study suggests a separate volcanic center in NW Ishtar Terra. Lakshmi Planum, on the Ishtar Terra highland, exhibits major volcanic and tectonic features. On the Venera radar image radar brightness is influenced by slope and roughness; radar-facing slopes (east-facing) and rough surfaces (approx. 8 cm average relief) are bright, while west-facing slopes and smooth surfaces are dark. A series of semi-circular features, apparently topographic depressions, do not conform in orientation to major structural trends in this region of NW Ishtar Terra. The large depression in NW Ishtar Terra is similar to the calderas of Colette and Sacajawea Paterae, as all three structures are large irregular depressions. NW Ishtar Terra appears to be the site of a volcanic center with a complex caldera structure, possibly more than one eruptive vent, and associated lobed flows at lower elevations. The morphologic similarity between this volcanic center and those of Colette and Sacajawea suggests that centralized eruptions have been the dominant form of volcanism in Ishtar. The location of this volcanic center at the intersection of two major compressional mountain belts and the large size of the calders (with an inferred larg/deep magma source) support a crustal thickening/melting rather than a hot-spot origin for these magmas.

  6. 3D [Ag-Mg] polyanionic frameworks in the La{sub 4}Ag{sub 10}Mg{sub 3} and La{sub 4}Ag{sub 10.3}Mg{sub 12} new ternary compounds

    SciTech Connect

    Solokha, Pavlo; De Negri, Serena; Pavlyuk, Volodymyr; Saccone, Adriana

    2010-12-15

    The crystal structures of two new ternary phases, La{sub 4}Ag{sub 10}Mg{sub 3} and La{sub 4}Ag{sub 10.3}Mg{sub 12}, were refined from X-ray single crystal diffraction data. La{sub 4}Ag{sub 10}Mg{sub 3} crystallizes in the Ca{sub 4}Au{sub 10}In{sub 3} structure type, an ordered variant of the binary Zr{sub 7}Ni{sub 10} compound: orthorhombic, Cmce, oS68, a=14.173(5), b=10.266(3), c=10.354(3) A, Z=4, wR{sub 2}=0.0826, 676 F{sup 2} values, 50 variables. La{sub 4}Ag{sub 10.3}Mg{sub 12} represents a new structure type: orthorhombic, Cmmm, oS116-10.32, a=9.6130(3), b=24.9663(8), c=9.6333(2) A, Z=4, wR{sub 2}=0.0403, 1185 F{sup 2} values, 101 variables. The structural analysis of both compounds, highlighting a significant contraction of the Ag-Mg distances, suggests the existence of three-dimensional [Ag-Mg] networks hosting La atoms. LMTO calculations applied to La{sub 4}Ag{sub 10}Mg{sub 3} indicate that the strongest bonds occur for Ag-Ag and Ag-Mg interactions, and confirm the presence of a 3D{sub {infinity}}[Ag{sub 10}Mg{sub 3}]{sup {delta}}{sup -} polyanionic framework balanced by positively charged La atoms. -- Graphical abstract: An independent fragment of the 3D [Ag-Mg] framework in La{sub 4}Ag{sub 10}Mg{sub 3} together with an ELF section (1/2 0 0 basal plane). Display Omitted

  7. Ag K- and L3-edge XAFS study on Ag species in Ag/Ga2O3 photocatalysts

    NASA Astrophysics Data System (ADS)

    Yamamoto, M.; Yoshida, T.; Yamamoto, N.; Nomoto, T.; Yamamoto, A.; Yoshida, H.; Yagi, S.

    2016-05-01

    Ag loaded Ga2O3 (Ag/Ga2O3) shows photocatalytic activity for reduction of CO2 with water. Ag L3-edge XANES and K-edge EXAFS spectra were measured for various Ag/Ga2O3 samples, which suggested that structural and chemical states of Ag species varied with the loading amount of Ag and the preparation method. The Ag species were metallic Ag particles with an AgGaO2-like interface structure in the sample with high loading amount of Ag while predominantly Ag metal clusters in the sample with low loading amount of Ag. The XANES feature just above the edge represented the interaction between the Ag species and the Ga2O3 surface, showing that the Ag metal clusters had more electrons in the d-orbitals by interacting with the Ga2O3 surface, which would contribute the high photocatalytic activity.

  8. Nanocap array of Au:Ag composite for surface-enhanced Raman scattering

    NASA Astrophysics Data System (ADS)

    Zhang, Yongjun; Wang, Cong; Wang, Jinpeng; Chen, Lei; Li, Jia; Liu, Yang; Zhao, Xiaoyu; Wang, Yaxin; Yang, Jinghai

    2016-01-01

    We fabricated Au:Ag nanocap arrays by co-sputtering Au and Ag onto two-dimensional polystyrene (PS) colloidal sphere templates in a magnetron sputtering system for the surface-enhanced Raman scattering (SERS) substrate. In contrast to the bilayer Au/Ag, the co-sputtering Au:Ag bimetal array formed the protrusion network of Ag and Au nanoparticles, which contributed to Raman enhancement in the waxberry-like structure. The metal protrusions formed waxberry-like shell in which the PS beads were encapsulated. At the same time, the Au:Ag bimetal arrays exhibit 4-fold more enhancement in the SERS signal intensity of Rhodamine 6G at the 1649 cm-1 than Au/Ag bilayer array, which is ascribed to the plasmon coupling between the nanoparticles of Au and Ag on the sample. When the PS colloidal particle templates were etched by O2-plasma before sputtering process, the nanogaps affected the surface plasmon resonance (SPR), and the optimal gaps between adjacent Au:Ag nanocaps generated even stronger SERS enhancements. This SERS substrate of Au:Ag showed high sensitivity and reproducibility. The EF of Au:Ag nanocap array substrate onto which Rhodamine 6G (R6G) were adsorbed was evaluated as 6.72 × 1010.

  9. Nanocap array of Au:Ag composite for surface-enhanced Raman scattering.

    PubMed

    Zhang, Yongjun; Wang, Cong; Wang, Jinpeng; Chen, Lei; Li, Jia; Liu, Yang; Zhao, Xiaoyu; Wang, Yaxin; Yang, Jinghai

    2016-01-01

    We fabricated Au:Ag nanocap arrays by co-sputtering Au and Ag onto two-dimensional polystyrene (PS) colloidal sphere templates in a magnetron sputtering system for the surface-enhanced Raman scattering (SERS) substrate. In contrast to the bilayer Au/Ag, the co-sputtering Au:Ag bimetal array formed the protrusion network of Ag and Au nanoparticles, which contributed to Raman enhancement in the waxberry-like structure. The metal protrusions formed waxberry-like shell in which the PS beads were encapsulated. At the same time, the Au:Ag bimetal arrays exhibit 4-fold more enhancement in the SERS signal intensity of Rhodamine 6G at the 1649cm(-1) than Au/Ag bilayer array, which is ascribed to the plasmon coupling between the nanoparticles of Au and Ag on the sample. When the PS colloidal particle templates were etched by O2-plasma before sputtering process, the nanogaps affected the surface plasmon resonance (SPR), and the optimal gaps between adjacent Au:Ag nanocaps generated even stronger SERS enhancements. This SERS substrate of Au:Ag showed high sensitivity and reproducibility. The EF of Au:Ag nanocap array substrate onto which Rhodamine 6G (R6G) were adsorbed was evaluated as 6.72×10(10). PMID:26253437

  10. AGS experiments -- 1995, 1996 and 1997

    SciTech Connect

    Depken, J.C.; Presti, P.L.

    1997-12-01

    This report contains (1) FY 1995 AGS schedule as run; (2) FY 1996 AGS schedule as run; (3) FY 1997 AGS schedule as run; (4) FY 1998--1999 AGS schedule (proposed); (5) AGS beams 1997; (6) AGS experimental area FY 1995 physics program; (7) AGS experimental area FY 1996 physics program; (8) AGS experimental area FY 1997 physics program; (9) AGS experimental area FY 1998--1999 physics program (proposed); (10) a listing of experiments by number; (11) two-page summaries of each experiment, in order by number; and (12) listing of publications of AGS experiments.

  11. AGS experiments -- 1991, 1992, 1993. Tenth edition

    SciTech Connect

    Depken, J.C.

    1994-04-01

    This report contains: (1) FY 1993 AGS schedule as run; (2) FY 1994--95 AGS schedule; (3) AGS experiments {ge} FY 1993 (as of 30 March 1994); (4) AGS beams 1993; (5) AGS experimental area FY 1991 physics program; (6) AGS experimental area FY 1992 physics program; (7) AGS experimental area FY 1993 physics program; (8) AGS experimental area FY 1994 physics program (planned); (9) a listing of experiments by number; (10) two-page summaries of each experiment; (11) listing of publications of AGS experiments; and (12) listing of AGS experiments.

  12. Destabilization of Ag nanoislands on Ag(100) by adsorbed sulfur

    SciTech Connect

    Shen, Mingmin; Russell, Selena M.; Liu, Da-Jiang; Thiel, Patricia A.

    2011-10-17

    Sulfur accelerates coarsening of Ag nanoislands on Ag(100) at 300 K, and this effect is enhanced with increasing sulfur coverage over a range spanning a few hundredths of a monolayer, to nearly 0.25 monolayers. We propose that acceleration of coarsening in this system is tied to the formation of AgS{sub 2} clusters primarily at step edges. These clusters can transport Ag more efficiently than can Ag adatoms (due to a lower diffusion barrier and comparable formation energy). The mobility of isolated sulfur on Ag(100) is very low so that formation of the complex is kinetically limited at low sulfur coverages, and thus enhancement is minimal. However, higher sulfur coverages force the population of sites adjacent to step edges, so that formation of the cluster is no longer limited by diffusion of sulfur across terraces. Sulfur exerts a much weaker effect on the rate of coarsening on Ag(100) than it does on Ag(111). This is consistent with theory, which shows that the difference between the total energy barrier for coarsening with and without sulfur is also much smaller on Ag(100) than on Ag(111).

  13. High-performance flexible Ag nanowire electrode with low-temperature atomic-layer-deposition fabrication of conductive-bridging ZnO film.

    PubMed

    Duan, Ya-Hui; Duan, Yu; Chen, Ping; Tao, Ye; Yang, Yong-Qiang; Zhao, Yi

    2015-01-01

    As material for flexible transparent electrodes for organic photoelectric devices, the silver nanowires (AgNWs) have been widely studied. In this work, we propose a hybrid flexible anode with photopolymer substrate, which is composed of spin-coating-processed AgNW meshes and of zinc oxide (ZnO) prepared by low-temperature (60°C) atomic layer deposition. ZnO effectively fills in the voids of the AgNW mesh electrode, which is thus able to contact to the device all over the active area, to allow for efficient charge extraction/injection. Furthermore, ZnO grown by low temperature mainly relies on hole conduction to make the anode play a better role. Hole-only devices are fabricated to certify the functionality of the low-temperature ZnO film. Finally, we confirm that the ZnO film grown at a low temperature bring a significant contribution to the performance of the modified AgNW anode. PMID:25852386

  14. High-performance flexible Ag nanowire electrode with low-temperature atomic-layer-deposition fabrication of conductive-bridging ZnO film

    NASA Astrophysics Data System (ADS)

    Duan, Ya-Hui; Duan, Yu; Chen, Ping; Tao, Ye; Yang, Yong-Qiang; Zhao, Yi

    2015-02-01

    As material for flexible transparent electrodes for organic photoelectric devices, the silver nanowires (AgNWs) have been widely studied. In this work, we propose a hybrid flexible anode with photopolymer substrate, which is composed of spin-coating-processed AgNW meshes and of zinc oxide (ZnO) prepared by low-temperature (60°C) atomic layer deposition. ZnO effectively fills in the voids of the AgNW mesh electrode, which is thus able to contact to the device all over the active area, to allow for efficient charge extraction/injection. Furthermore, ZnO grown by low temperature mainly relies on hole conduction to make the anode play a better role. Hole-only devices are fabricated to certify the functionality of the low-temperature ZnO film. Finally, we confirm that the ZnO film grown at a low temperature bring a significant contribution to the performance of the modified AgNW anode.

  15. AGS preinjector improvement

    SciTech Connect

    Alessi, J.G.; Brennan, J.M.; Brown, H.N.; Brodowski, J.; Gough, R.; Kponou, A.; Prelec, K.; Staples, J.; Tanabe, J.; Witkover, R.

    1987-01-01

    In 1984, a polarized H/sup -/ source was installed to permit the acceleration of polarized protons in the AGS, using a low current, 750 keV RFQ Linear Accelerator as the preinjector. This RFQ was designed by LANL and has proved to be quite satisfactory and reliable. In order to improve the reliability and simplify maintenance of the overall AGS operations, it has been decided to replace one of the two 750 keV Cockcroft-Waltons (C-W) with an RFQ. The design of a new high current RFQ has been carried out by LBL and is also being constructed there. This paper describes the preinjector improvement project, centered around that RFQ, which is underway at BNL.

  16. 3D Full Seismic Waveform Tomography of NW Turkey and Surroundings

    NASA Astrophysics Data System (ADS)

    Cubuk, Yesim; Fichtner, Andreas; Taymaz, Tuncay

    2015-04-01

    Northward collision of the Arabian plate with the Eurasian plate, and interaction of the motion between dynamic processes originated from the subduction of the African plate beneath the Aegean generated very complex tectonic structures in the study region. Western Turkey is among one of the most active extensional regions in the world and the study area is mainly located where the extensional Aegean and the right-lateral strike-slip North Anatolian Fault Zone (NAFZ) intersects. Therefore, the tectonic framework of the NW Turkey and the Marmara region is mainly characterized by the transition between the strike-slip tectonics to the extensional tectonics. The Sea of Marmara region has been subjected to several active and passive seismic investigations, nevertheless the accurate knowledge on the heterogeneity in the crust and upper mantle beneath the study area still remains enigmatic. On small-scale tomography problems, seismograms strongly reflect the effects of heterogeneities and the scattering properties of the Earth. Thus, the knowledge of high-resolution seismic imaging with an improved 3D radially anisotropic crustal model of the NW Turkey will enable better localization of earthquakes, identification of faults as well as the improvement of the seismic hazard assessment. For this purpose, we aim to develop 3D radially anisotropic subsurface structure of the Sea of Marmara and NW Turkey crust based on full waveform adjoint tomography method. The earthquake data were principally obtained from the Kandilli Observatory and Earthquake Research Institute (KOERI) and Earthquake Research Center (AFAD-DAD) database. In addition to this, some of the seismic waveform data extracted from the Hellenic Unified Seismic Network (HUSN) stations that are located within our study region were also used in this study. We have selected and simulated waveforms of earthquakes with magnitudes 4.0 ≤ Mw ≤ 6.7 occurred in the period between 2007-2014 to determine the 3D velocity

  17. MD simulation of nanoindentation on (001) and (111) surfaces of Ag-Ni multilayers

    NASA Astrophysics Data System (ADS)

    Zhao, Yinbo; Peng, Xianghe; Fu, Tao; Sun, Rong; Feng, Chao; Wang, Zhongchang

    2015-11-01

    We perform MD simulations of the nanoindentation on (001) and (111) surfaces of Ag-Ni multilayers with different modulation periods, and find that both the hardness and maximum force increase with the increase of modulation period, in agreement with the inverse Hall-Petch relation. A prismatic partial dislocation loop is observed in the Ni(111)/Ag(111) sample when the modulation period is relatively large. We also find that misfit dislocation network shows a square shape for the Ni(111)/Ag(111) interface, while a triangle shape for the Ni(001)/Ag(001) interface. The pyramidal defect zones are also observed in Ni(001)/Ag(001) sample, while the intersecting stacking faults are observed in Ni(111)/Ag(111) sample after dislocation traversing interface. The results offer insights into the nanoindentation behaviors in metallic multilayers, which should be important for clarifying strengthening mechanism in many other multilayers.

  18. Preparation and antibacterial activities of Ag/Ag+/Ag3+ nanoparticle composites made by pomegranate (Punica granatum) rind extract

    NASA Astrophysics Data System (ADS)

    Yang, Hui; Ren, Yan-yu; Wang, Tao; Wang, Chuang

    Nano-silver and its composite materials are widely used in medicine, food and other industries due to their strong conductivity, size effect and other special performances. So far, more microbial researches have been applied, but a plant method is rarely reported. In order to open up a new way to prepare AgNP composites, pomegranate peel extract was used in this work to reduce Ag+ to prepare Ag/Ag+/Ag3+ nanoparticle composites. UV-Vis was employed to detect and track the reduction of Ag+ and the forming process of AgNPs. The composition, structure and size of the crystal were analyzed by XRD and TEM. Results showed that, under mild conditions, pomegranate peel extract reacted with dilute AgNO3 solution to produce Ag/Ag+/Ag3+ nanoparticle composites. At pH = 8 and 10 mmol/L of AgNO3 concentration, the size of the achieved composites ranged between 15 and 35 nm with spherical shapes and good crystallinity. The bactericidal experiment indicated that the prepared Ag/Ag+/Ag3+ nanoparticles had strong antibacterial activity against gram positive bacteria and gram negative bacteria. FTIR analysis revealed that biological macromolecules with groups of sbnd NH2, sbnd OH, and others were distributed on the surface of the newly synthesized Ag/Ag+/Ag3+ nanoparticles. This provided a useful clue to further study the AgNP biosynthesis mechanism.

  19. Ag-Air Service

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Econ, Inc.'s agricultural aerial application, "ag-air," involves more than 10,000 aircraft spreading insecticides, herbicides, fertilizer, seed and other materials over millions of acres of farmland. Difficult for an operator to estimate costs accurately and decide what to charge or which airplane can handle which assignment most efficiently. Computerized service was designed to improve business efficiency in choice of aircraft and determination of charge rates based on realistic operating cost data. Each subscriber fills out a detailed form which pertains to his needs and then receives a custom-tailored computer printout best suited to his particular business mix.

  20. Bimetallic Pt-Ag and Pd-Ag nanoparticles

    SciTech Connect

    Lahiri, Debdutta; Bunker, Bruce; Mishra, Bhoopesh; Zhang, Zhenyuan; Meisel, Dan; Doudna, C. M.; Bertino, M. F.; Blum, Frank D.; Tokuhiro, A. T.; Chattopadhyay, Soma; Shibata, Tomohiro; Terry, Jeff

    2005-04-19

    We report studies of bimetallic nanoparticles with 15%–16% atomic crystal parameters size mismatch. The degree of alloying was also probed in a 2-nm Pt core ssmallest attainable core sized of Pt–Ag nanoparticles scompletely immiscible in bulkd and 20-nm-diameter Pd–Ag nanowires scompletely miscible in bulkd. Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical snanowired morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Also, Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd–Ag nanowires alloy similar to previously reported spherical Pd–Ag particles of similar diameter and composition

  1. Bimetallic Pt-Ag and Pd-Ag nanoparticles

    SciTech Connect

    Lahiri, Debdutta; Bunker, Bruce; Mishra, Bhoopesh; Zhang, Zhenyuan; Meisel, Dan; Doudna, C.M.; Bertino, M. F.; Blum, Frank D.; Tokuhiro, A.T.; Chattopadhyay, Soma; Shibata, Tomohiro; Terry, Jeff

    2005-05-01

    We report studies of bimetallic nanoparticles with 15%-16% atomic crystal parameters size mismatch. The degree of alloying was probed in a 2-nm Pt core (smallest attainable core size) of Pt-Ag nanoparticles (completely immiscible in bulk) and 20-nm-diameter Pd-Ag nanowires (completely miscible in bulk). Particles were synthesized radiolytically, and depending on the initial parameters, they assume spherical or cylindrical (nanowire) morphologies. In all cases, the metals are seen to follow their bulk alloying characteristics. Pt and Ag segregate in both spherical and wire forms, which indicates that strain due to crystallographic mismatch overcomes the excess surface free energy in the small particles. The Pd-Ag nanowires alloy similar to previously reported spherical Pd-Ag particles of similar diameter and composition.

  2. High efficiency single Ag nanowire/p-GaN substrate Schottky junction-based ultraviolet light emitting diodes

    SciTech Connect

    Wu, Y.; Li, X.; Xu, P.; Wang, Y.; Shen, X.; Liu, X.; Yang, Q.; Hasan, T.

    2015-02-02

    We report a high efficiency single Ag nanowire (NW)/p-GaN substrate Schottky junction-based ultraviolet light emitting diode (UV-LED). The device demonstrates deep UV free exciton electroluminescence at 362.5 nm. The dominant emission, detectable at ultralow (<1 μA) forward current, does not exhibit any shifts when the forward current is increased. External quantum efficiency (EQE) as high as 0.9% is achieved at 25 μA current at room temperature. Experiments and simulation analysis show that devices fabricated with thinner Ag NWs have higher EQE. However, for very thin Ag NWs (diameter < 250 nm), this trend breaks down due to heat accumulation in the NWs. Our simple device architecture offers a potentially cost-effective scheme to fabricate high efficiency Schottky junction-based UV-LEDs.

  3. ZnO/Ag nanowires composite film ultraviolet photoconductive detector

    NASA Astrophysics Data System (ADS)

    Guodong, Yan; Minqiang, Wang; Zhi, Yang

    2015-08-01

    ZnO/Ag nanowires (NWs) film ultraviolet (UV) detector was fabricated by a simple and low-cost solution-processed method. In order to prepare this device, Ag NWs network was first spin-coated on glass substrate as a transparent conducting electrode, then ZnO NWs arrays were grown vertically on the Ag NWs network based on the hydrothermal method. This UV detector exhibited an excellent detection performance with large on/off ratio and short response time. Several process and working parameters were particularly investigated to analyze the relationship between structure and performance, which include growth time of ZnO NWs array, spin speed of Ag NWs network and working temperature. This UV photoconductive detector is based on two kinds of one-dimension nanomaterials, and it was regarded as a compromise between high performance with large area, low voltage and low cost. Project supported by the National Natural Science Foundation of China (Nos. 61176056, 91323303, 91123019), the 111 Program (No. B14040), and the Open Projects from the Institute of Photonics and Photo-Technology, Provincial Key Laboratory of Photoelectronic Technology, Northwest University, China.

  4. What Is Ag-Ed?

    ERIC Educational Resources Information Center

    Lindley, Judy

    Ag-Ed is an agricultural education project aimed at upper primary students, held in conjunction with the Toowoomba Show (similar to a county fair) in Queensland, Australia. The program achieves its purpose of helping children understand the impact and relevance that agriculture has on their everyday lives through two components, an Ag-Ed day and a…

  5. AGS Experiments: 1989, 1990, 1991

    SciTech Connect

    Depken, J.C.

    1992-02-01

    This report contains: Experimental areas layout; table of beam parameters and fluxes; experiment schedule ``as run``; proposed 1992 schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS Experiments begin here; and list of AGS Experimenters begins here.

  6. AGS Experiments: 1989, 1990, 1991

    SciTech Connect

    Depken, J.C.

    1992-02-01

    This report contains: Experimental areas layout; table of beam parameters and fluxes; experiment schedule as run''; proposed 1992 schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS Experiments begin here; and list of AGS Experimenters begins here.

  7. Ag-modified silicon nanowires substrate for ultrasensitive surface-enhanced raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Shao, Ming-Wang; Zhang, Ming-Liang; Wong, Ning-Bew; Ma, Dorothy Duo-duo; Wang, Hui; Chen, Weiwei; Lee, Shuit-Tong

    2008-12-01

    We report a unique substrate for surface-enhanced raman spectroscopy (SERS) based on silver nanoparticles-embedded silicon nanowires (SiNWs). The SiNWs were prepared by thermal evaporation of SiO powder via oxide-assisted growth, oxide removed with HF, and then used to reduce silver ions to form a highly decorated Ag-embedded surface. Such modified SiNWs substrates yielded ultrahigh SERS sensitivity, which could detect 25μl of 1×10-16M Rhodamine 6G, 1×10-16M crystal violet, and 1×10-14M nicotine in methanol solutions. An Ag-modified SiNW strand could also enable SERS detection of 25μl of 1×10-8mg/ml calf thymus DNA. The possible mechanisms for the ultrahigh SERS sensitivity were discussed.

  8. Surface Modification of Silver Nanowires for Morphology and Processing Control in Composite Transparent Electrodes.

    PubMed

    Liang, Zhiming; Graham, Kenneth R

    2015-10-01

    Silver nanowires are attractive components for a number of materials and applications, including silver nanowire (AgNW)-polymer composites, electrically conductive coatings, and transparent electrodes. In this manuscript, the ability of thiols with hydrophobic to ionic end groups to bind to AgNW surfaces is investigated, followed by how the polarity of the surface modifying thiol influences the morphological and electrical properties of both AgNW/PEDOT:PSS blend films and pure AgNW networks. Utilizing surface modification of AgNWs with sodium 3-mercapto-1-propanesulfonate (MPS), morphologically homogeneous AgNW/PEDOT:PSS thin films with an order of magnitude lower sheet resistance at similar transmittance values than unmodified AgNWs are obtained with a one-step processing method. Brief optimization of MPS-AgNW/PEDOT:PSS blends yields a sheet resistance of 22.6 Ω/□ at 81.4% transmittance. PMID:26389535

  9. Microwave-assisted hydrothermal synthesis of Ag2(W1 -xMox)O4 heterostructures: Nucleation of Ag, morphology, and photoluminescence properties

    NASA Astrophysics Data System (ADS)

    Silva, M. D. P.; Gonçalves, R. F.; Nogueira, I. C.; Longo, V. M.; Mondoni, L.; Moron, M. G.; Santana, Y. V.; Longo, E.

    2016-01-01

    Ag2W1 -xMoxO4 (x = 0.0 and 0.50) powders were synthesized by the co-precipitation (drop-by-drop) method and processed using a microwave-assisted hydrothermal method. We report the real-time in situ formation and growth of Ag filaments on the Ag2W1 -xMoxO4 crystals using an accelerated electron beam under high vacuum. Various techniques were used to evaluate the influence of the network-former substitution on the structural and optical properties, including photoluminescence (PL) emission, of these materials. X-ray diffraction results confirmed the phases obtained by the synthesis methods. Raman spectroscopy revealed significant changes in local order-disorder as a function of the network-former substitution. Field-emission scanning electron microscopy was used to determine the shape as well as dimensions of the Ag2W1 -xMoxO4 heterostructures. The PL spectra showed that the PL-emission intensities of Ag2W1 -xMoxO4 were greater than those of pure Ag2WO4, probably because of the increase of intermediary energy levels within the band gap of the Ag2W1 -xMoxO4 heterostructures, as evidenced by the decrease in the band-gap values measured by ultraviolet-visible spectroscopy.

  10. The effect of size and size distribution on the oxidation kinetics and plasmonics of nanoscale Ag particles.

    PubMed

    Qi, Hua; Alexson, Dimitri; Glembocki, Orest; Prokes, S M

    2010-05-28

    We employed a simple and effective electroless (EL) plating approach to produce silver nanoparticles (NPs) on bare silicon, on dielectric ZnO nanowires (NWs) and on Si NWs, respectively. The surface stability of the homogeneous Ag NPs formed on the ZnO NW surfaces was investigated by surface enhanced Raman spectroscopy (SERS), which show that the attachment of thiol to the Ag surface can slow down the oxidation process, and the SERS signal remains strong for more than ten days. To further examine the Ag NP oxidation process in air, the oxygen content in the silicon nanowire core/Ag sheath composites was monitored by the energy dispersive x-ray (EDX) method. The amount of oxygen in the system increases with time, indicating the silver NPs were continuously oxidized, and it is not clear if saturation is reached in this time period. To investigate the influence of the Ag NPs size distribution on the oxidation process, the oxygen amount in the NPs formed by EL deposition and e-beam (EB) evaporation on a bare silicon surface was compared. Results indicate a faster oxidation process in the EL formed Ag NPs than those produced by EB evaporation. We attribute this observation to the small diameter of the EL produced silver particles, which results in a higher surface energy. PMID:20431201

  11. The effect of size and size distribution on the oxidation kinetics and plasmonics of nanoscale Ag particles

    NASA Astrophysics Data System (ADS)

    Qi, Hua; Alexson, Dimitri; Glembocki, Orest; Prokes, S. M.

    2010-05-01

    We employed a simple and effective electroless (EL) plating approach to produce silver nanoparticles (NPs) on bare silicon, on dielectric ZnO nanowires (NWs) and on Si NWs, respectively. The surface stability of the homogeneous Ag NPs formed on the ZnO NW surfaces was investigated by surface enhanced Raman spectroscopy (SERS), which show that the attachment of thiol to the Ag surface can slow down the oxidation process, and the SERS signal remains strong for more than ten days. To further examine the Ag NP oxidation process in air, the oxygen content in the silicon nanowire core/Ag sheath composites was monitored by the energy dispersive x-ray (EDX) method. The amount of oxygen in the system increases with time, indicating the silver NPs were continuously oxidized, and it is not clear if saturation is reached in this time period. To investigate the influence of the Ag NPs size distribution on the oxidation process, the oxygen amount in the NPs formed by EL deposition and e-beam (EB) evaporation on a bare silicon surface was compared. Results indicate a faster oxidation process in the EL formed Ag NPs than those produced by EB evaporation. We attribute this observation to the small diameter of the EL produced silver particles, which results in a higher surface energy.

  12. THE AGS ELECTROSTATIC SEPTUM.

    SciTech Connect

    HOCK,J.RUSSO,T.GLEN,J.BROWN,K.

    2003-05-12

    The previous slow beam extraction electro static septum in the AGS was designed in 1981. Research documented at the Fermi Laboratory was used as the base line for this design. The septum consisted of a ground plane of .002 inch diameter wire tungsten-rhenium alloy (75%W 25%Re) with a hollow welded titanium cathode assembly. The vacuum chamber is stationary and the septum is moved with a pair of high vacuum linear feed throughs. After years of beam time, the frequency of failures increased. The vacuum system design was poor by today's standards and resulted in long pump down times after repairs. The failures ranged from broken septum wires to a twisted cathode. In addition to the failures, the mechanical drive system had too much backlash, making the operating position difficult to repeat. The new septum needed to address all of these issues in order to become a more reliable septum.

  13. EPIDAUROS Biotechnologie AG.

    PubMed

    Arnold, Hans-Peter; Kluge, Peter; Mauch, Simon

    2005-07-01

    EPIDAUROS Biotechnologie AG is a leading provider of pharmacogenetic consulting, genotyping and research services to the international pharmaceutical and biotechnology industries, contract research organizations and healthcare providers. The company's mission is to improve safety, efficacy and predictability in drug development and drug therapy. EPIDAUROS determines its customers' needs in the field of pharmacogenetics using an in-depth consultancy process. The development and conduct of genotyping assays for drug-metabolizing enzymes, drug transporters and drug targets (for example, receptors)--all performed under stringent quality standards--are a major activity at EPIDAUROS. The company offers its research services to academic and industrial partners for the development of innovative diagnostic solutions by using its intellectual property. PMID:16014003

  14. Potential for Great Thrust Earthquakes in NE Colombia & NW Venezuela

    NASA Astrophysics Data System (ADS)

    Bilham, R. G.; Mencin, D.

    2013-05-01

    Sixty-five percent of the ≈19 mm/yr eastward velocity of the Caribbean Plate north of Aruba and the Guajira peninsula relative to the South American plate is accommodated by dextral slip on the Bocono Fault system in NW Venezuela at 12±1 mm/yr, the remaining ~3 mm/yr of shear apparently distributed to the NW of the fault (Perez et al., 2011). The N40E strike of the Bocono fault system, however, requires that 10.6±1 mm/yr of convergence should accompany this partitioned dextral shear, but GPS measurements reveal that less than 25% of this convergence occurs across the Venezuelan Andes. The remaining 6-8 mm of convergence is presumably accommodated by incipient subduction between the Bocono fault and a trench 300 km NW of the northern coast of Colombia. Hence NW Venezuela and NE Colombia may occasionally host great earthquakes. Our current poor understanding of the geometry of the plate interface permits the plate to be locked 300 km down-dip and possibly 600 km along-strike, and if the plate slips in 10 m ruptures it could do so every 1200 years in a M~9 earthquake. No great earthquake has occurred since 1492, since when ~4 m of potential slip has developed, but should slip occur on just 10% of the hypothesized décollement (100x150 km) it could do so now in an Mw=8.2 earthquake. In that a potential Mw>8 earthquake poses a future seismic and tsunami threat to the Caribbean it is important to examine whether great earthquakes have occurred previously near the NW Venezuela coast. It is possible that creep accommodates the entire convergence signal, since there is no suggestion from microseismicity for an abrupt locked-to-sliding transition, as, for example, signifies its location in the Himalaya. An alternative measure of future potential seismic energy release is to identify the locus and rate of present-day strain contraction. To this end, Venezuelan, Colombian and US (CU and UNAVCO) investigators are installing an array of more than a dozen continuous operating

  15. The new silver borate Ag3B5O9

    NASA Astrophysics Data System (ADS)

    Sohr, Gerhard; Falkowski, Viktoria; Huppertz, Hubert

    2015-05-01

    Single crystals of Ag3B5O9 were obtained via high-pressure synthesis at 3 GPa and 600 °C, using a Walker-type multianvil high-pressure device. Ag3B5O9 crystalizes with a=674.7(2), b=943.5(2), c=1103.5(2) pm, V=0.7025(2) nm3, and Z=4 in the noncentrosymmetric space group P212121 (no. 19). The orthorhombic structure was refined from 3740 independent reflections with R1=0.0496 and wR2=0.587 (all data). It is built up from infinite corner-sharing chains of BO4 tetrahedra along the a axis, which are interconnected by BO3 groups to form a network. In the structure, three crystallographically independent sites are occupied with Ag+ cations exhibiting argentophillic interactions. The synthetic conditions as well as the results of the single crystal structure analysis are presented.

  16. Elucidating the localized plasmonic enhancement effects from a single Ag nanowire in organic solar cells.

    PubMed

    Liu, Xinfeng; Wu, Bo; Zhang, Qing; Yip, Jing Ngei; Yu, Guannan; Xiong, Qihua; Mathews, Nripan; Sum, Tze Chien

    2014-10-28

    The origins of performance enhancement in hybrid plasmonic organic photovoltaic devices are often embroiled in a complex interaction of light scattering, localized surface plasmon resonances, exciton-plasmon energy transfer and even nonplasmonic effects. To clearly deconvolve the plasmonic contributions from a single nanostructure, we herein investigate the influence of a single silver nanowire (NW) on the charge carriers in bulk heterojunction polymer solar cells using spatially resolved optical spectroscopy, and correlate to electrical device characterization. Polarization-dependent photocurrent enhancements with a maximum of ∼ 36% over the reference are observed when the transverse mode of the plasmonic excitations in the Ag NW is activated. The ensuing higher absorbance and light scattering induced by the electronic motion perpendicular to the NW long axis lead to increased exciton and polaron densities instead of direct surface plasmon-exciton energy transfer. Finite-difference time-domain simulations also validate these findings. Importantly, our study at the single nanostructure level explores the fundamental limits of plasmonic enhancement achievable in organic solar cells with a single plasmonic nanostructure. PMID:25198060

  17. AgH, Ag/sub 2/, and AgO revisited: Basis set extensions

    SciTech Connect

    Martin, R.L.

    1987-05-01

    An extended basis set has been developed for Ag which significantly improves the agreement between theoretical and experimental spectroscopic parameters for AgH, AgO, and Ag/sub 2/. The major improvement comes about as a result of the improved treatment of electron correlation in the Ag d shell upon the introduction of f functions. Their inclusion produces very slight differences at the SCF level, but significant reductions in r/sub e/ and increases in ..omega../sub e/ and D/sub e/ in the Mo-dash-barller--Plesset perturbation theory expansion. At the MP4(SDTQ) level, typical results are 0.02 A too long for r/sub e/, 4% too low for ..omega../sub e/, and 10 kcal too small for D/sub e/. From a pragmatic standpoint, MP2 give results very similar to this at a much reduced level of effort.

  18. 14. Stairs in far NW corner of the North Section, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. Stairs in far NW corner of the North Section, as viewed from atop pier. This photo, along with phot WA-116-E-1, are the only photographs of the North Section of Drydock 3 that were approved by the U.S. Navy for inclusion in this HAER report. The brick building in center distance is the Building 59, the Pattern Shop, which has been documented in the HAER report No. WA-116-A. - Puget Sound Naval Shipyard, Drydock No. 3, Farragut Avenue, Bremerton, Kitsap County, WA

  19. The AGS-Booster lattice

    SciTech Connect

    Lee, Y.Y.; Barton, D.S.; Claus, J.; Cottingham, J.G.; Courant, E.D.; Danby, G.T.; Dell, G.F.; Forsyth, E.B.; Gupta, R.C.; Kats, J.

    1987-01-01

    The AGS Booster has three objectives. They are to increase the space charge limit of the AGS, to increase the intensity of the polarized proton beam by accumulating many linac pulses (since the intensity is limited by the polarized ion source), and to reaccelerate heavy ions from the BNL Tandem Van de Graaff before injection into the AGS. The machine is capable of accelerating protons at 7.5 Hertz from 200 MeV to 1.5 GeV or to lower final energies at faster repetition rates. The machine will also be able to accelerate heavy ions from as low as 1 MeV/nucleon to a magnetic rigidity as high as 17.6 Tesla-meters with a one second repetition rate. As an accumulator for polarized protons, the Booster should be able to store the protons at 200 MeV for several seconds. We expect that the Booster will increase the AGS proton intensity by a factor of four, polarized proton intensity by a factor of twenty to thirty, and will also enable the AGS to accelerate all species of heavy ions (at present the AGS heavy ion program is limited to the elements lighter than sulfur because it can only accelerate fully stripped ions). The construction project started in FY 1985 and is expected to be completed in 1989. The purpose of this paper is to provide a future reference for the AGS Booster lattice.

  20. Silver indium diphosphate, AgInP(2)O(7).

    PubMed

    Zouihri, Hafid; Saadi, Mohamed; Jaber, Boujemaa; El Ammari, Lehcen

    2010-01-01

    Polycrystalline material of the title compound, AgInP(2)O(7), was synthesized by traditional high-temperature solid-state methods and single crystals were grown from the melt of a mixture of AgInP(2)O(7) and B(2)O(3) as flux in a platinium crucible. The structure consists of InO(6) octa-hedra, which are corner-shared to PO(4) tetra-hedra into a three-dimensional network with hexa-gonal channels running parallel to the c axis. The silver cation, located in the channel, is bonded to seven O atoms of the [InP(2)O(7)] framework with Ag-O distances ranging from 2.370 (2) to 3.015 (2) Å. The P(2)O(7) diphosphate anion is characterized by a P-O-P angle of 137.27 (9) and a nearly eclipsed conformation. AgInP(2)O(7) is isotypic with the M(I)FeP(2)O(7) (M(I) = Na, K, Rb, Cs and Ag) diphosphate family. PMID:21522510

  1. Facile synthesis of PdAgTe nanowires with superior electrocatalytic activity

    NASA Astrophysics Data System (ADS)

    Hong, Wei; Wang, Jin; Wang, Erkang

    2014-12-01

    In this work, ultrathin Te nanowires (NWs) with high-aspect-ratio are prepared by a simple hydrothermal method. By using Te NWs as the sacrificial template, we demonstrate a facile and efficient method for the synthesis of PdAgTe NWs with high-quality through the partly galvanic replacement between Te NWs and the corresponding noble metal salts precursors in an aqueous solution. The compositions of PdAgTe NWs can be tuned by simply altering the concentration of the precursors. After cyclic voltammetry treatment, multi-component PdAgTe NW with a highly active and stable surface can be obtained. The structure and composition of the as-prepared nanomaterials are analyzed by transmission electron microscope, X-ray diffraction, energy dispersive X-ray spectroscopy, inductively coupled plasma-mass spectroscopy and X-ray photoelectron spectroscopy. Electrochemical catalytic measurement results prove that the as synthesized PdAgTe NWs present superior catalytic activity toward ethanol electrooxidation in alkaline solution than the commercial Pd/C catalyst, which making them can be used as effective catalysts for the direct ethanol fuel cells.

  2. Paleofloods and ancient fishing weirs in NW Iberian rivers

    NASA Astrophysics Data System (ADS)

    Viveen, Willem; Sanjurjo-Sanchez, Jorge; Goy-Diz, Ana; Veldkamp, Antonie; Schoorl, Jeroen M.

    2014-07-01

    A 15-m-thick, fluvial sedimentary record of the NW Iberian lower Miño River was studied. Grain-size analyses were performed and twelve samples were dated using optically stimulated luminescence dating techniques, documenting a 1300-yr-old reconstructed fluvial record that does not match with known climate fluctuations in the area, but is linked instead to the construction of a series of ancient fishing weirs (pesqueiras). The sedimentation phases are in agreement with known episodes of increased population density, which suggests active use of the pesqueiras. A number of sedimentation hiatuses in the fluvial record point towards damage to the pesqueiras during large-scale flooding in the Miño River basin, and a sudden drop in population probably due to the arrival of the plague in the 13th century AD. The oldest sedimentation phases started just after 700 AD, and we infer that the first pesqueiras were constructed around this time. This timing coincides with the transition of the NW Iberian landscape towards a more intensively used agricultural landscape, as evidenced from other geo-archeological investigations. The results demonstrate that the pesqueiras are several hundreds of years older than known from historical records, but not so old as to date back to the Roman occupation.

  3. Crystal structure of Ag2(μ-SCN)2(NH3)4.

    PubMed

    Müller, Thomas G; Kraus, Florian

    2016-07-01

    Di-μ-thio-cyanato-bis-[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear mol-ecule, the Ag(I) atom is coordinated by two ammine ligands and the S atom of one thio-cyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thio-cyanate anions at longer distances, leading to a dimer with point group symmetry C 2. The distance between the Ag(I) atoms in the dimer is at 3.0927 (6) Å within the range of argentophilic inter-actions. The crystal structure displays N-H⋯N and N-H⋯S hydrogen-bonding inter-actions that build up a three-dimensional network. PMID:27555922

  4. Ag-silica composite nanotube with controlled wall structures for biomedical applications.

    PubMed

    He, Haiyan; Wang, Juan; Gao, Qian; Chang, Mingwei; Ren, Zhaohui; Zhang, Xiwen; Li, Xiang; Weng, Wenjian; Han, Gaorong

    2013-11-01

    A range of Ag-silica composite nanotubes with tailored wall structures were successfully synthesized in situ by single-nozzle electrospinning. By increasing AgNO3 concentration, the wall structure of Ag-silica tubes changes from dense to porous, and eventually turns into a 'lace-like' structure. This is attributed to Ag ions doping into the SiOSi network of precursors, as illustrated in FTIR study. More importantly, Ag-silica composite nanotubes show robust antibacterial activity against both Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli microorganisms. Therefore, it is a breakthrough of the nanostructure biomaterial research for future medical applications that require strong antibacterial properties. PMID:23907057

  5. Crystal structure of Ag2(μ-SCN)2(NH3)4

    PubMed Central

    Müller, Thomas G.; Kraus, Florian

    2016-01-01

    Di-μ-thio­cyanato-bis­[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear mol­ecule, the AgI atom is coordinated by two ammine ligands and the S atom of one thio­cyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thio­cyanate anions at longer distances, leading to a dimer with point group symmetry C 2. The distance between the AgI atoms in the dimer is at 3.0927 (6) Å within the range of argentophilic inter­actions. The crystal structure displays N—H⋯N and N—H⋯S hydrogen-bonding inter­actions that build up a three-dimensional network. PMID:27555922

  6. Spin dynamics simulations at AGS

    SciTech Connect

    Huang, H.; MacKay, W.W.; Meot, F.; Roser, T.

    2010-05-23

    To preserve proton polarization through acceleration, it is important to have a correct model of the process. It has been known that with the insertion of the two helical partial Siberian snakes in the Alternating Gradient Synchrotron (AGS), the MAD model of AGS can not deal with a field map with offset orbit. The stepwise ray-tracing code Zgoubi provides a tool to represent the real electromagnetic fields in the modeling of the optics and spin dynamics for the AGS. Numerical experiments of resonance crossing, including spin dynamics in presence of the snakes and Q-jump, have been performed in AGS lattice models, using Zgoubi. This contribution reports on various results so obtained.

  7. NMR investigation of Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Son, Kwanghyo; Jang, Zeehoon

    2013-01-01

    109Ag nuclear magnetic resonance (NMR) and relaxation measurements have been performed on two powder samples of Ag nanoparticles with average sizes of 20 nm and 80 nm. The measurements have been done in an external field of 9.4 T and in the temperature range 10 K < T < 280 K. The 109Ag NMR spectra for both samples have close to Lorentzian shapes and turn out to be mixtures of homogeneous and inhomogeneous lines. The linewidth Δ ν at room temperature is 1.3 kHz for both samples and gradually increases with decreasing temperature. Both the Knight shift ( K) and the nuclear spin-lattice relaxation rate (1/ T 1) are observed to be almost identical to the values reported for the bulk Ag metal, whereby the Korringa ratio R(= K 2 T 1 T/S) is found to be 2.0 for both samples in the investigated temperature range.

  8. Fast plasmonic laser nanowelding for a Cu-nanowire percolation network for flexible transparent conductors and stretchable electronics.

    PubMed

    Han, Seungyong; Hong, Sukjoon; Ham, Jooyeun; Yeo, Junyeob; Lee, Jinhwan; Kang, Bongchul; Lee, Phillip; Kwon, Jinhyeong; Lee, Seung S; Yang, Min-Yang; Ko, Seung Hwan

    2014-09-01

    A facile fast laser nanoscale welding process uses the plasmonic effect at a nanowire (NW) junction to suppress oxidation and successfully fabricate a Cu-NW-based percolation-network conductor. The "nanowelding" process does not require an inert or vacuum environment. Due to the low-temperature and fast-process nature, plasmonic laser nanowelding may form Cu-nanowire networks on heat-sensitive, flexible or even stretchable substrates. PMID:24913621

  9. Geomorphometric mapping of spatio-temporal changes in Plio-Quaternary uplift in the NW European Alpine foreland

    NASA Astrophysics Data System (ADS)

    Demoulin, Alain; Bourdon, Hadrien

    2016-04-01

    A way to explore the causes of Plio-Quaternary uplift in NW Europe consists in identifying the distribution of uplifted areas and evaluating relative uplift ages. Here we use the composite metric R of fluvial landscapes, which involves three different hypsometric integrals (catchment, drainage network, and trunk stream), in order to get time information (Demoulin, 2011). Main controls on R are catchment size A and uplift age. To isolate the latter information, we use the derived SR index, which is the slope of the linear fit between R and ln(A). We calculate R for more than 7000 basins larger than 15 km2 and determine SR values for 60-km-wide regions in five N- to NW-trending zones of alternating Paleozoic massifs (Massif central-Brittany; Rhenish shield; Bohemian massif) and Meso-Cenozoic basins (Paris basin; Franconian basin) covering the whole NW European platform in front of the alpine arc. The resulting 350- to 750-km-long SR profiles seem to provide the most meaningful time information, better than that obtained with noisier higher-resolution SR maps. Preliminary results of the study especially evidence a systematic increase in SR from south to north across the Paris basin and Rhenish shield zones that suggests northward propagation of an uplift wave that started from ~200 km north of the alpine collision front in Pliocene times and travelled across this part of the European platform. The Bohemian Massif and the Massif central-Brittany zone show more complex SR patterns that might be linked to interferences between the uplift wave and more local phenomena (related, e.g., to WNW-oriented compression in front of the Carpathian arc). Surprisingly, the Franconian basin displays fairly uniform low to moderate SR values suggesting that no tectonic perturbation occurred there since at least the late Early Pleistocene. In conclusion, this new geomorphometric approach of uplift chronology provides a wealth of data, whose careful analysis will help get fresh insight

  10. Strong magnetization damping induced by Ag nanostructures in Ag/NiFe/Ag trilayers

    NASA Astrophysics Data System (ADS)

    Ley Domínguez, D.; da Silva, G. L.; Rodríguez-Suárez, R. L.; Rezende, S. M.; Azevedo, A.

    2013-07-01

    Ferromagnetic resonance has been used to investigate the magnetization relaxation in trilayers of Ag(t)/NiFe(10 nm)/Ag(t), sputter deposited on Si(001) where the thickness of the Ag layer varied from 0 nm to 24 nm. In the first stages of formation, the Ag layers form islands that work as mold to imprint defects or inhomogeneities on the NiFe film surface. The magnetic inhomogeneities and defects imprinted on the surface of the NiFe film act as extrinsic sources of magnetization relaxation in addition to the intrinsic Gilbert damping mechanism. Weak inhomogeneities are associated to the two-magnon scattering source and the strong inhomogeneities are associated to the fluctuations of the local magnetization. By adding the three different sources of magnetization damping, we were able to explain the azimuthal dependence of the ferromagnetic resonance linewidth.

  11. Holocene monsoon variability inferred from palaeolake sediments in NW India.

    NASA Astrophysics Data System (ADS)

    Dixit, Y.; Hodell, D. A.; Petrie, C. A.

    2012-04-01

    The plains of NW India encompasses arid, semi-arid to sub-humid zones and are characterized by numerous palaeolakes and playas. The sedimentary records from these water bodies provide a rich source of paleoclimatic information. We present a high-resolution, Holocene monsoon-variation record inferred from three palaeolakes lying across the precipitation gradient in NW India; palaeolake Karsandi in arid Rajasthan and palaeolake Riwasa, palaeolake Kotla Dahar in semi-arid and sub-humid regions, respectively, in Haryana plains. Laminated and massive gypsum deposits characterize Palaeolake Karsandi in the arid region. Oxygen isotopes are being measured on the gastropod shells and gypsum hydration of water (Hodell et al 2011) for a continuous isotopic record from Rajasthan. The oxygen isotope record from palaeolake Riwasa in the semi-arid region indicates the inception of a wet period at 9700-9500 cal yr (BP) with the establishment of a deep, permanent lake coinciding with the early Holocene maximum in the Indian monsoon. The deep, permanent-lake phase ended with a desiccation event at approximately 8200 BP coinciding with the '8.2kyr' weakening of the monsoon. In contrast, palaeolake Kotla Dahar, lying further east of Riwasa in the sub-humid region, receives 500-700mm annual rainfall. At Kotla Dahar, bulk CaCO3 (%), gastropod abundance and isotope data indicate that the deep lacustrine sequence ends at c.185 cm. Extrapolating from the AMS radio-carbon dated sediments at 135cm (4870-4650 BP) and 230cm (2000-1870 BP), places the 185 cm horizon at c.3970-3720 BP. Our results so far indicate that the Riwasa paleolake lying west of Kotla Dahar dries earlier than Kotla Dahar during the mid-Holocene. The precise date of the transition from a deep-lake water phase to an ephemeral lake in Kotla Dahar is pending, but the projected date suggests that the event coincides with the decline of the urban phase of the Indus Civilization at c. 3900 BP. These three lakes lying across

  12. Synthesis of Ag(2) S-Ag nanoprisms and their use as DNA hybridization probes.

    PubMed

    Liu, Bing; Ma, Zhanfang

    2011-06-01

    A simple synthetic route to prepare Ag(2) S-Ag nanoprisms consists of the facile addition of Na(2) S to a solution of triangular Ag nanoprisms. The resulting Ag(2) S-Ag nanoparticles are more stable in solution than the original Ag nanoprisms, and two surface plasmon resonance (SPR) bands of the original Ag nanoprisms still remain. In addition, the SPR bands of the Ag(2) S-Ag nanoprisms are tunable over a wide range. The Ag(2) S-Ag nanoprisms can be directly bioconjugated via well-established stable Ag(2) S surface chemistry with readily available sulfur coupling agents. The nanoprisms are used in the hybridization of functionalized oligonucleotides, and show promise as probes for future biosensing applications. PMID:21538868

  13. Study of the oxygen transport through Ag (110), Ag (poly), and Ag 2.0 Zr

    NASA Technical Reports Server (NTRS)

    Outlaw, R. A.; Wu, D.; Davidson, M. R.; Hoflund, Gar B.

    1992-01-01

    The transport of oxygen through high-purity membranes of Ag (110), Ag (poly), Ag (nano), and Ag 2.0 Zr has been studied by an ultrahigh vacuum permeation method over the temperature range of 400-800 C. The data show that there are substantial deviations from ordinary diffusion-controlled transport. A surface limitation has been confirmed by glow-discharge studies where the upstream O2 supply has been partially converted to atoms, which, for the same temperature and pressure, gave rise to over an order of magnitude increase in transport flux. Further, the addition of 2.0 wt percent Zr to the Ag has provided increased dissociative adsorption rates, which, in turn, increased the transport flux by a factor of 2. It was also observed that below a temperature of 630 C, the diffusivity exhibits an increase in activation energy of over 4 kcal/mol, which has been attributed to trapping of the atomic oxygen and/or kinetic barriers at the surface and subsurface of the vacuum interface. Above 630 C, the activation barrier decreases to the accepted value of about 11 kcal/mol for Ag (poly), consistent with zero concentration at the vacuum interface.

  14. Resolution experiments for NW Pacific subduction zone tomography

    NASA Technical Reports Server (NTRS)

    Spakman, Wim; Van Der Hilst, Rob; Wortel, Rinus; Stein, Seth

    1989-01-01

    Results are reported from an investigation of the resolving power of ISC/NEIC P travel-time data in tomographic inversions for the geometry of the subduction zones in the NW Pacific. From thermal models for the Kurile, Janan, Izu-Bonin, Mariana, and Ryukyu slabs, three-dimensional synthetic velocity anomalies for subducting slabs are generated and projected onto a cell model for the uppermost 1400 km of the mantle. These synthetic models are used to compute synthetic delay times for ray paths corresponding to the source and receiver locations used for the actual data, add Gaussian noise, invert the synthetic data, and compare the resulting velocity structure to the initial synthetic models. This comparison is illustrated for sections through the Kuriles and the Mariana arcs. A variety of resolution artifacts are observed, which in many cases resemble features visible in the tomographic results obtained from inverting the actual ISC/NEIC data.

  15. The photometric variability of the Be star NW Serpentis

    NASA Astrophysics Data System (ADS)

    Percy, J. R.; Marinova, M. M.; BožiĆ , H.; Harmanec, P.

    1999-08-01

    {NW Ser} is a bright (V = 6.1 - 6.2) active Be star which is known to vary photometrically on a time scale of hours to days. Using both Hipparcos and ground-based photometry, and using light curve, autocorrelation, power spectrum analysis and phase dispersion minimalization techniques, we have concluded that the period is close to 0.46d - a period typical of stars of this type, and in good agreement with the value of 0.488d, recently determined by Hubert & Floquet from Hipparcos data. It is possible that the period is near twice this value, but the evidence is not strong. We also find a period of about 5d. from both the ground-based and Hipparcos data.

  16. 51. (Credit JTL) Interior view (looking NW) of new pumping ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    51. (Credit JTL) Interior view (looking NW) of new pumping room built in 1921. In the right foreground is #1 low service pump built in 1897. Installed at McNeil in 1898, it was not moved during the building of this room in 1921. Beyond is a 5 mgd capacity Worthington-Snow cross-compound, duplex crank-and-fly-wheel engine built in 1920. Behind the worthington is an 8 mgd Allis-Chalmers engine of the same configuration. it was built in 1911, but not installed at McNeil until 1927. Both engines have condensers. - McNeil Street Pumping Station, McNeil Street & Cross Bayou, Shreveport, Caddo Parish, LA

  17. An Integrated 3S and Historical Materials Analysis of the Keriya Paleoriver, NW China

    NASA Astrophysics Data System (ADS)

    Luo, Lei; Wang, Xinyuan; Cai, Heng

    2014-03-01

    Combining analysis of 3S (RS, GIS and GPS) and historical materials (historical records, ancient map and academic and literary writings) allows mapping of the Keriya Paleoriver of Southern Xinjiang, NW China. Keriya Paleoriver, one of the ancient Four Green Corridors which passes through the Taklimakan Desert from south to north in the Tarim Basin, recorded changes of the climate-environment in the ancient Silk Road of the region. According to the archaeological data, historical materials and paleoclimates information, its eco-environment and climate have had great changes since the 1.09Ma B.P., especially during the last 2,000 years, which has led to many famous ancient cities to be abandoned and the route of the ancient Silk Road to be moved southward. Using RS (optical and radar imagery), GIS (mapping and spatial analysis) and GPS (study area investigation), we mapped a major paleodrainage system of Keriya River, which have linked the Kunlun Mountains to the Tienshan Mountains through the Taklimakan Desert, possibly as far back as the early Pleistocene. This study illustrates the capability of the 3S and historical materials, in mapping the Keriya Paleoriver drainage networks and archaeological study on the ancient Silk Road.

  18. Spatiotemporal analysis of vehicle collisions involving wild boar and roe deer in NW Spain.

    PubMed

    Rodríguez-Morales, Beatriz; Díaz-Varela, Emilio Rafael; Marey-Pérez, Manuel Francisco

    2013-11-01

    Ungulate-vehicle collisions pose a serious traffic safety hazard in the North of Spain. The understanding of underlying temporal and spatial structure of these non-random events is imperative to develop appropriate mitigation measures. This study analyses the temporal, spatial and spatiotemporal patterns of car crashes involving wild boar and roe deer in the province of Lugo (NW Spain) in the period 2006-2010 using geographic information systems (GIS) and spatial statistics. The temporal analysis--conducted at three scales: daily, weekly and seasonal--revealed that accidents are related to specific animal's life cycles and to interactions with human activities. The localization of collision points with GIS discovered the sections of the autonomic road network where accidents with the two studied species concentrate. Besides, the spatial arrangement of significant hotspots was mapped through kernel density estimation over two time scales (daily and seasonal), distinguishing among 41 sets, sequentially arranged to facilitate clustering comparison and determination of spatiotemporal risky areas. This work is of valuable help for road managers to design the appropriate mitigation measures that will improve traffic safety and animal welfare. PMID:24056283

  19. Structural Analysis of Active North Bozgush Fault Zone (NW Iran)

    NASA Astrophysics Data System (ADS)

    Saber, R.; Isik, V.; Caglayan, A.

    2013-12-01

    NW Iran is one of the seismically active regions between Zagros Thrust Belt at the south and Caucasus at the north. Not only large magnitude historical earthquakes (Ms>7), but also 1987 Bozgush, 1997 Ardebil (Mw 6.1) and 2012 Ahar-Varzagan (Mw 6.4) earthquakes reveal that the region is seismically active. The North Bozgush Fault Zone (NBFZ) in this region has tens of kilometers in length and hundreds of meters in width. The zone has produced some large and destructive earthquakes (1593 M:6.1 and 1883 M:6.2). The NBFZ affects the Cenozoic units and along this zone Eocene units thrusted over Miocene and/or Plio-Quaternary sedimentary units. Together with morphologic features (stream offsets and alluvial fan movements) affecting the young unites reveal that the zone is active. The zone is mainly characterized by strike-slip faults with reverse component and reverse faults. Reverse faults striking N55°-85°E and dip of 40°-50° to the SW while strike-slip faults show right lateral slip with N60°-85°W and N60°-80°E directions. Our structural data analysis in NBFZ indicates that the axis direction of σ2 principal stress is vertical and the stress ratio (R) is 0.12. These results suggest that the tectonic regime along the North Bozgush Fault Zone is transpressive. Obtained other principal stresses (σ1, σ3) results are compatible with stress directions and GPS velocity suggested for NW Iran.

  20. Projected future wave climate in the NW Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Casas-Prat, M.; Sierra, J. P.

    2013-07-01

    Projected future regional wave climate scenarios at a high temporal-spatial scale were obtained for the NW Mediterranean Sea, using five combinations of regional-global circulation models. Changes in wave variables were analyzed and related to the variations of the forcing wind projections, while also evaluating the evolution of the presence of the different types of sea states. To assess the significance of the changes produced, a bootstrap-based method was proposed, which accounts for the autocorrelation of data and correctly reproduces the extremes. For the mean climate, relative changes of Hs up to ±10% were obtained, whereas they were around ±20% for the extreme climate. In mean terms, variations of Hs are similar to those associated with wind speed but are enhanced/attenuated, respectively, when fetch conditions are favorable/unfavorable. In general, most notable alterations are not in the Hs magnitude but rather in its direction. In this regard, during the winter season, it is interesting to note that the significant deviations between the results derived from the two global circulation models are larger than those between regional models. ECHAM5 simulated an enhanced west wind flow that is translated into more frequent W-NW waves, whereas the HadCM3Q3 global model gives rise to the east component, which contributes to a higher intensity and number of storms coming from such a direction and directly affects the wind-sea/swell distribution of coastal stretches that face east, like the Catalan coast. Different patterns of change were obtained during the summer when a common rise of NE-E waves was found.

  1. A Holocene climate record from palaeolakes in NW India

    NASA Astrophysics Data System (ADS)

    Dixit, Y.; Hodell, D. A.; Petrie, C.

    2011-12-01

    The plains of NW India encompasses arid, semi-arid to sub-humid zones and archaeological research indicate this region was intensively settled by the Indus Valley Civilization. The precise climatological and environmental history of this region during the Holocene period remain largely unknown. We present high-resolution isotope proxy records of local palaeoclimate change from lacustrine deposits in two different climatic zones from west to east; Palaeo-lake Riwasa in the semi-arid and paleo-lake Kotla Dahar in the sub-humid region in Haryana plains, India. The oxygen isotope record from palaeolake Riwasa indicates the inception of wet climate conditions and establishment of a deep, permanent lake in the basin at ~8870 14C yr BP, coinciding approximately with the early Holocene maximum in the Indian monsoon. A major desiccation event occurs after ~7000 14C yr BP. Our results from palaeolake Riwasa indicate that the permanent deep-water lake and major desiccation event in semi-arid region pre-dated the urban phase of the Indus Civilization. Palaeolake Kotla Dahar is located further east than Riwasa in the sub-humid zone, and receives 500-700mm rainfall. Calcium carbonate percent of bulk sediments from Kotla Dahar increases down section to a maximum of 72%, indicating the presence of a deep carbonate marl lake. Oxygen isotopes are currently being measured on gastropod and ostracod shells and radiocarbon dates are being obtained from this section. We speculate that the oxygen isotope record from Kotla Dahar may provide critical climate data for the period between 5000-3500 BP, the period of Harappan Urbanism. Our study of palaeo-lakes Riwasa and Kotla Dahar constitute the first oxygen isotope records from the plains of NW India to interpret the palaeoclimate history of this region.

  2. A time series deformation estimation in the NW Himalayas using SBAS InSAR technique

    NASA Astrophysics Data System (ADS)

    Kumar, V.; Venkataraman, G.

    2012-12-01

    A time series land deformation studies in north western Himalayan region has been presented in this study. Synthetic aperture radar (SAR) interferometry (InSAR) is an important tool for measuring the land displacement caused by different geological processes [1]. Frequent spatial and temporal decorrelation in the Himalayan region is a strong impediment in precise deformation estimation using conventional interferometric SAR approach. In such cases, advanced DInSAR approaches PSInSAR as well as Small base line subset (SBAS) can be used to estimate earth surface deformation. The SBAS technique [2] is a DInSAR approach which uses a twelve or more number of repeat SAR acquisitions in different combinations of a properly chosen data (subsets) for generation of DInSAR interferograms using two pass interferometric approach. Finally it leads to the generation of mean deformation velocity maps and displacement time series. Herein, SBAS algorithm has been used for time series deformation estimation in the NW Himalayan region. ENVISAT ASAR IS2 swath data from 2003 to 2008 have been used for quantifying slow deformation. Himalayan region is a very active tectonic belt and active orogeny play a significant role in land deformation process [3]. Geomorphology in the region is unique and reacts to the climate change adversely bringing with land slides and subsidence. Settlements on the hill slopes are prone to land slides, landslips, rockslides and soil creep. These hazardous features have hampered the over all progress of the region as they obstruct the roads and flow of traffic, break communication, block flowing water in stream and create temporary reservoirs and also bring down lot of soil cover and thus add enormous silt and gravel to the streams. It has been observed that average deformation varies from -30.0 mm/year to 10 mm/year in the NW Himalayan region . References [1] Massonnet, D., Feigl, K.L.,Rossi, M. and Adragna, F. (1994) Radar interferometry mapping of

  3. Effect of Ag Templates on the Formation of Au-Ag Hollow/Core-Shell Nanostructures

    NASA Astrophysics Data System (ADS)

    Tsai, Chi-Hang; Chen, Shih-Yun; Song, Jenn-Ming; Haruta, Mitsutaka; Kurata, Hiroki

    2015-11-01

    Au-Ag alloy nanostructures with various shapes were synthesized using a successive reduction method in this study. By means of galvanic replacement, twined Ag nanoparticles (NPs) and single-crystalline Ag nanowires (NWs) were adopted as templates, respectively, and alloyed with the same amount of Au+ ions. High angle annular dark field-scanning TEM (HAADF-STEM) images observed from different rotation angles confirm that Ag NPs turned into AuAg alloy rings with an Au/Ag ratio of 1. The shifts of surface plasmon resonance and chemical composition reveal the evolution of the alloy ring formation. On the other hand, single-crystalline Ag NWs became Ag@AuAg core-shell wires instead of hollow nanostructure through a process of galvanic replacement. It is proposed that in addition to the ratio of Ag templates and Au ion additives, the twin boundaries of the Ag templates were the dominating factor causing hollow alloy nanostructures.

  4. Effect of Ag Templates on the Formation of Au-Ag Hollow/Core-Shell Nanostructures.

    PubMed

    Tsai, Chi-Hang; Chen, Shih-Yun; Song, Jenn-Ming; Haruta, Mitsutaka; Kurata, Hiroki

    2015-12-01

    Au-Ag alloy nanostructures with various shapes were synthesized using a successive reduction method in this study. By means of galvanic replacement, twined Ag nanoparticles (NPs) and single-crystalline Ag nanowires (NWs) were adopted as templates, respectively, and alloyed with the same amount of Au(+) ions. High angle annular dark field-scanning TEM (HAADF-STEM) images observed from different rotation angles confirm that Ag NPs turned into AuAg alloy rings with an Au/Ag ratio of 1. The shifts of surface plasmon resonance and chemical composition reveal the evolution of the alloy ring formation. On the other hand, single-crystalline Ag NWs became Ag@AuAg core-shell wires instead of hollow nanostructure through a process of galvanic replacement. It is proposed that in addition to the ratio of Ag templates and Au ion additives, the twin boundaries of the Ag templates were the dominating factor causing hollow alloy nanostructures. PMID:26563266

  5. Solution-processed assembly of ultrathin transparent conductive cellulose nanopaper embedding AgNWs

    NASA Astrophysics Data System (ADS)

    Song, Yuanyuan; Jiang, Yaoquan; Shi, Liyi; Cao, Shaomei; Feng, Xin; Miao, Miao; Fang, Jianhui

    2015-08-01

    Natural biomass based cellulose nanopaper is becoming a promising transparent substrate to supersede traditional petroleum based polymer films in realizing future flexible paper-electronics. Here, ultrathin, highly transparent, outstanding conductive hybrid nanopaper with excellent mechanical flexibility was synthesized by the assembly of nanofibrillated cellulose (NFC) and silver nanowires (AgNWs) using a pressured extrusion paper-making technique. The hybrid nanopaper with a thickness of 4.5 μm has a good combination of transparent conductive performance and mechanical stability using bamboo/hemp NFC and AgNWs cross-linked by hydroxypropylmethyl cellulose (HPMC). The heterogeneous fibrous structure of BNFC/HNFC/AgNWs endows a uniform distribution and an enhanced forward light scattering, resulting in high electrical conductivity and optical transmittance. The hybrid nanopaper with an optimal weight ratio of BNFC/HNFC to AgNWs shows outstanding synergistic properties with a transmittance of 86.41% at 550 nm and a sheet resistance of 1.90 ohm sq-1, equal to the electronic conductivity, which is about 500 S cm-1. The BNFC/HNFC/AgNW hybrid nanopaper maintains a stable electrical conductivity after the peeling test and bending at 135° for 1000 cycles, indicating remarkably strong adhesion and mechanical flexibility. Of importance here is that the high-performance and low-cost hybrid nanopaper shows promising potential for electronics application in solar cells, flexible displays and other high-technology products.Natural biomass based cellulose nanopaper is becoming a promising transparent substrate to supersede traditional petroleum based polymer films in realizing future flexible paper-electronics. Here, ultrathin, highly transparent, outstanding conductive hybrid nanopaper with excellent mechanical flexibility was synthesized by the assembly of nanofibrillated cellulose (NFC) and silver nanowires (AgNWs) using a pressured extrusion paper-making technique. The

  6. Probing the rupture of a Ag atomic junction in a Ag-Au mixed electrode

    NASA Astrophysics Data System (ADS)

    Kim, Taekyeong

    2015-09-01

    We probed that the atomic junction in Ag part ruptures during stretching of atomic sized contacts of Ag-Au mixed electrodes, resulting in Ag-Ag electrodes through a scanning tunneling microscope breaking junction (STM-BJ) technique. We observed that the conductance and tunneling decay constant for a series of amine-terminated oligophenyl molecular junctions are essentially the same for the Ag-Au mixed and the Ag-Ag electrodes. We also found the molecular plateau length and the evolution patterns with the Ag-Au mixed electrodes are similar to those with Ag-Ag electrodes rather than the Au-Au electrodes in the molecular junction elongation. This result is attributed to the smaller binding energy of Ag atoms compared to that of Au atoms, so the Ag junction part is more easily broken than that of Au part in stretching of Ag-Au mixed electrodes. Furthermore, we successfully observed that the rupture force of the atomic junction for the Ag-Au mixed electrodes was identical to that for the Ag-Ag electrodes and smaller than that for the Au-Au electrodes. This study may advance the understanding of the electrical and the mechanical properties in molecular devices with Ag and Au electrodes in future.

  7. The AGS Booster control system

    SciTech Connect

    Frankel, R.; Auerbach, E.; Culwick, B.; Clifford, T.; Mandell, S.; Mariotti, R.; Salwen, C.; Schumburg, N.

    1988-01-01

    Although moderate in size, the Booster construction project requires a comprehensive control system. There are three operational modes: as a high intensity proton injector for the AGS, as a heavy ion accelerator and injector supporting a wide range of ions and as a polarized proton storage injector. These requirements are met using a workstation based extension of the existing AGS control system. Since the Booster is joining a complex of existing accelerators, the new system will be capable of supporting multiuser operational scenarios. A short discussion of this system is discussed in this paper.

  8. Photoreduction of Ag+ in Ag/Ag2S/Au memristor

    NASA Astrophysics Data System (ADS)

    Mou, N. I.; Tabib-Azar, M.

    2015-06-01

    Silver halides and chalcogenides are excellent memristor materials that have been extensively used in the past as photosensitive layers in photography. Here we examine the effect of illumination on the operating voltages and switching speed of Ag/Ag2S/Au memristors using a green laser (473-523 nm). Our results indicate that illumination decreases the average switching time from high to low resistance states by ∼19% and decreases the turn-off voltages dramatically from -0.8 V to -0.25 V that we attribute to the change in sulfur valency and a photo-induced change in its oxidation/reduction potential. Photo-induced reduction of silver in Ag2S may be used in three dimensional optical memories that can be electronically read and reset.

  9. Ag nanotubes and Ag/AgCl electrodes in nanoporous membranes

    NASA Astrophysics Data System (ADS)

    Davenport, Matthew; Healy, Ken; Siwy, Zuzanna S.

    2011-04-01

    Miniaturization of the entire experimental setup is a key requirement for widespread application of nanodevices. For nanopore biosensing, integrating electrodes onto the nanopore membrane and controlling the pore length is important for reducing the complexity and improving the sensitivity of the system. Here we present a method to achieve these goals, which relies on electroless plating to produce Ag nanotubes in track-etched polymer nanopore templates. By plating from one side only, we create a conductive nanotube that does not span the full length of the pore, and thus can act as a nanoelectrode located inside the nanopore. To give optimal electrochemical behavior for sensing, we coat the Ag nanotube with a layer of AgCl. We characterize the behavior of this nanoelectrode by measuring its current-voltage response and find that, in most cases, the response is asymmetric. The plated nanopores have initial diameters between 100 and 300 nm, thus a range suitable for detection of viruses.

  10. [Effect of Eu ions on the Ag nanoparticles precipitation and their optical properties in borate glasses].

    PubMed

    Liu, Zhi-liang; Jiao, Qing; Qiu, Jian-bei

    2014-08-01

    Eu-Ag co-doped borate glasses were prepared by the high temperature solid method in the present work. Absorption and emission spectra were employed to investigate the precipitation of Ag nanoparticles, which is influenced by the network form B2O3 and the co-doped Eu ions. It was found in the absorption spectra of Eu-Ag co-doped sample that a broad band centered at about 410 nm emerged and their intensity decreased with the increase in the BZ 03 concentration. Meanwhile, under the excitation of 340 nm, a broad emission band was observed in the wavelength range of 350-600 nm, which belongs to the blue-green light of Ag aggregates. The intensity of the Ag aggregates presented an increasing tendency with the increase in the B2O3 contents. The weak characteristic emission of Ag aggregates and Eu3+ was observed respectively in their singly doped samples. It is concluded that both their emissions get significant enhancement when Eu ions and Ag ions are used for co-doping the sample. In addition, the increased absorption of Ag nanoparticles was detected with the increase in the Eu ions concentration. Herein, the mechanism behind Eu3+ contribution to the precipitation of Ag nanoparticles is discussed in detail. The luminescence properties of borate glasses can be controlled by the microstructure of the borate glasses. Therefore, the white emission can be realized by the adjustment of glass structure and Eu ions concentration, owing to the red light from Eu3+ : (5)D0-->(7)Fj electronic transition and the blue-green light form the broad emission of Ag aggregates. The borate glasses are expected to be the candidates for the light-emission diode (LED) luminescent materials. PMID:25508714

  11. [Effect of Eu ions on the Ag nanoparticles precipitation and their optical properties in borate glasses].

    PubMed

    Liu, Zhi-liang; Jiao, Qing; Qiu, Jian-bei

    2014-08-01

    Eu-Ag co-doped borate glasses were prepared by the high temperature solid method in the present work. Absorption and emission spectra were employed to investigate the precipitation of Ag nanoparticles, which is influenced by the network form B2O3 and the co-doped Eu ions. It was found in the absorption spectra of Eu-Ag co-doped sample that a broad band centered at about 410 nm emerged and their intensity decreased with the increase in the BZ 03 concentration. Meanwhile, under the excitation of 340 nm, a broad emission band was observed in the wavelength range of 350-600 nm, which belongs to the blue-green light of Ag aggregates. The intensity of the Ag aggregates presented an increasing tendency with the increase in the B2O3 contents. The weak characteristic emission of Ag aggregates and Eu3+ was observed respectively in their singly doped samples. It is concluded that both their emissions get significant enhancement when Eu ions and Ag ions are used for co-doping the sample. In addition, the increased absorption of Ag nanoparticles was detected with the increase in the Eu ions concentration. Herein, the mechanism behind Eu3+ contribution to the precipitation of Ag nanoparticles is discussed in detail. The luminescence properties of borate glasses can be controlled by the microstructure of the borate glasses. Therefore, the white emission can be realized by the adjustment of glass structure and Eu ions concentration, owing to the red light from Eu3+ : (5)D0-->(7)Fj electronic transition and the blue-green light form the broad emission of Ag aggregates. The borate glasses are expected to be the candidates for the light-emission diode (LED) luminescent materials. PMID:25474935

  12. Ag-Ag2S Hybrid Nanoprisms: Structural versus Plasmonic Evolution.

    PubMed

    Shahjamali, Mohammad M; Zhou, Yong; Zaraee, Negin; Xue, Can; Wu, Jinsong; Large, Nicolas; McGuirk, C Michael; Boey, Freddy; Dravid, Vinayak; Cui, Zhifeng; Schatz, George C; Mirkin, Chad A

    2016-05-24

    Recently, Ag-Ag2S hybrid nanostructures have attracted a great deal of attention due to their enhanced chemical and thermal stability, in addition to their morphology- and composition-dependent tunable local surface plasmon resonances. Although Ag-Ag2S nanostructures can be synthesized via sulfidation of as-prepared anisotropic Ag nanoparticles, this process is poorly understood, often leading to materials with anomalous compositions, sizes, and shapes and, consequently, optical properties. In this work, we use theory and experiment to investigate the structural and plasmonic evolution of Ag-Ag2S nanoprisms during the sulfidation of Ag precursors. The previously observed red-shifted extinction of the Ag-Ag2S hybrid nanoprism as sulfidation occurs contradicts theoretical predictions, indicating that the reaction does not just occur at the prism tips as previously speculated. Our experiments show that sulfidation can induce either blue or red shifts in the extinction of the dipole plasmon mode, depending on reaction conditions. By elucidating the correlation with the final structure and morphology of the synthesized Ag-Ag2S nanoprisms, we find that, depending on the reaction conditions, sulfidation occurs on the prism tips and/or the (111) surfaces, leading to a core(Ag)-anisotropic shell(Ag2S) prism nanostructure. Additionally, we demonstrate that the direction of the shift in the dipole plasmon is a function of the relative amounts of Ag2S at the prism tips and Ag2S shell thickness around the prism. PMID:27148792

  13. A Holocene speleothem record from Morocco, NW Africa

    NASA Astrophysics Data System (ADS)

    Wassenburg, Jasper; Fietzke, Jan; Richter, Detlev; Immenhauser, Adrian

    2010-05-01

    A well dated Holocene speleothem (stalagmite) from the Middle Atlas Mountains in Morocco has been investigated for its continental climate record. The aim is to compile an improved understanding of the climatically complex triple point of the North Atlantic, Mediterranean and Saharan / Monsoonal climate realms in NW Africa. At present, only few studies concerning continental climate reconstructions from NW Africa have been published (Lamb et al. 1995, Cheddadi et al. 1998, Genty et al. 2006). Given the significance of this region, this lack of data forms a strong motivation for additional, well dated climate records. The speleothem (GP2) was sampled in the 'Grotte de Piste' (ca 800 m above sea level), mean annual precipitation is about 930 mm (mainly falling in the winter season) and the mean annual temperature is about 13° C. GP2 is 60 cm tall and grew - based on U/Th MC-ICP-MS data - continuously between 11.5 kyr BP (early Holocene) and 2.9 kyr BP (late Holocene). X-Ray Diffraction data indicate a mainly aragonitic mineralogy. 'Hendy tests' suggest that CaCO3 precipitation was close to isotopic equilibrium with respect to oxygen isotopes, however kinetic effects might have influenced carbon isotopes. Carbon and oxygen isotope data have been measured along a transect with increments of approximately 1 mm representing a resolution of about 15 yrs. Highly covariant oscillations in δ13C and δ18O with an average cyclicity of about 410 yrs. are observed. These oscillations coincide with macroscopically visible high density and low density layers, possibly reflecting a higher or lower amount of inclusions and perhaps higher and lower growth rates. Geochemical analysis of speloan aragonite is accompanied by cave monitoring that has started in November 2009. Parameters quantified include: drip water parameters, cave air humidity, pCO2 and cave air temperature. Precipitation experiments using watch glasses will also be performed. References Cheddadi, R., Lamb, H. F

  14. Brittle reactivation of ductile shear zones in NW Namibia

    NASA Astrophysics Data System (ADS)

    Salomon, Eric; Koehn, Daniel; Passchier, Cees

    2014-05-01

    Existing structural elements, such as shear zones, are regarded to have a significant influence on the orientation and extent of younger structures. Thus, shear zones are seen as a primary controlling factor on the development of rift zones (e.g. Piqué & Laville, 1996). Indeed, reactivation of such structures is observed in numerous areas. However, information on the amount of offset associated with a reactivation is often lacking. Reactivation of shear zones is also reported of in NW Namibia in relation to the South Atlantic Rifting (Marsh et al., 2001; Stanistreet & Charlesworth, 2001). Here, we present the results of a quantitative study on this reactivation. NW Namibia is characterized by the ~N-S trending Kaoko Belt which developed during the assemblage of Gondwana in the Neo-Proterozoic and incorporates a number of shear zones, e.g. the Purros Shear Zone and Three Palms Shear Zone, which run sub-parallel to the present-day continental margin. The shear zones are partly covered by the extrusives of the Paraná-Etendeka Large Igneous Province (~133 Ma) which extruded shortly before or during the onset of the Atlantic rifting (e.g. Blaich et al., 2011). Combining the analysis of satellite imagery and digital elevation models with extensive field work, we identified numerous faults tracing the old shear zones along which the Etendeka basalts were down-faulted. Listric faults developed along the shear zones and accumulated vertical offsets up to 900 m. The faults developed in areas where the foliation along the shear zones is steepest, indicating that a dip of >65° is necessary for normal reactivation. A basin developed along the section where the shear zone is supposedly widest. Our results contribute to the view that the basement inheritance plays a significant role on rifting processes and that the reactivation of shear zones can accumulate significant amounts of displacement. References: Blaich, O.A. et al. (2011). Journal of Geophysical Research - Solid

  15. Late Cenozoic stress field distribution in Biga Peninsula, NW Turkey

    NASA Astrophysics Data System (ADS)

    Ozden, S.; Bekler, T.; Tutkun, S. Z.; Kurcer, A.; Ates, O.; Bekler, F. N.; Kalafat, D.

    2009-04-01

    Biga Peninsula is a seismically active region both in instrumental and historical period in NW Turkey. In this part, middle and southern branches of North Anatolian Fault are represented by Etili, Can-Biga, Yenice-Gonen, Manyas-Danisment, Lapseki, Sinekci, Terzialan, Dogruca, Uluabat, Edincik, Pazarkoy-Hamdibey-Kalkim, Edremit, Yigitler, Sarikoy-Inova, Troia and Karabiga Faults. All of these faults are responsible of the seismic activity in Biga Peninsula. Historical earthquakes happened in 29, 155, 170, 543, 620, 1440, 1737, 1855, 1865 and 1875. Furthermore, as for instrumental period, Saros Gulf-Murefte earthquakes (M:7.3 and M:6.3) in 1912, Erdek Gulf (M:6.4) and Can-Biga (M:6.3) in 1935, Edremit Gulf-Ayvaci k (M:6.8) in 1944, Yenice-Gonen (M:7.2) in 1953, Gonen (M:5.8) in 1964, Edremit-Baki rcay (M:5.5) in 1971, Biga (M:5.8) in 1983, Kusgolu-Manyas (M:5.2) and Bandirma (M:5.0) in 2006. In this study, we determined the Late Cenozoic stress field distribution and present-day tectonic regimes both fault-slip data (by 253 fault planes) and earthquake focal mechanism solutions (by 58 earthquakes) were investigated by the inversion methods. The results indicate that a transtensional stress regime is dominant with a NW-SE to WNW-ESE directed compression (1) and NE-SW to ENE-WSW directed extension (3), which yielded a NE-SW, ENE-WSW and also E-W trending strike-slip faulting faults with a normal component. While a transtensional tectonic regime has an active component in Biga Peninsula, a local and consistent transpressional tectonic regime were determined along an E-W trending narrow zone in the northern part of the Biga Peninsula also. The tectonic regime and stress field is resulted from interactions both continental collision of Eurasian/Anatolian/Arabian plate in the east and subduction processes (roll back and/or slab-pull) of the African plate along the Cyprus and Hellenic arc in the Mediterranean region.

  16. Geology and mineralogy of the Santo Nino Ag-Pb-Zn vein, Fresnillo District, Mexico

    SciTech Connect

    Gemmell, J.B.; Zantop, H.; Birnie, R.W.

    1985-01-01

    The Santo Nino Ag-Pb-Zn vein is the major producer of the Fresnillo District, located 750 km NW of Mexico City. It is over 2.4 km long, more than 480 m in vertical extent, more than 2.5 m wide overall, and has average grades of >600 gm/t Ag and <2% combined Pb and Zn. The vein is hosted by a tilted sequence of Cretaceous graywackes, shales and andesitic volcanics and extends upward into a Lower Tertiary conglomerate. Up to 5 separate opening events occurred along the vein, resulting in discontinuous stages of brecciation and crustiform banding. Ore mineral zonation is well developed both vertically and laterally and closely reflects metal and metal ratio distributions. Ore minerals are sphalerite, galena, pyrite, chalcopyrite, arsenopyrite, marcasite, pyrrhotite, acanthite, native silver, and three coexisting solid solution series, pyrargyrite-proustite, polybasite-arsenopolybasite, and tetrahedrite-tennantite in a gangue of quartz, calcite, clay, sericite,and chlorite. A 5-stage paragenetic sequence can be established: 1) pyrite, arsenopyrite, quartz, 2) sphalerite, galena, chalcopyrite, quartz, 3) tetrahedrite, pyrargyrite, polybasite, quartz, 4) acanthite, native silver, calcite, quartz, and 5) calcite. Preliminary microprobe analyses indicate that the Ag-rich solid solution series are Sb-rich in the central and upper portions of the vein and As-rich at deeper levels.

  17. AGS experiments: 1990, 1991, 1992. Ninth edition

    SciTech Connect

    Depken, J.C.

    1993-04-01

    This report contains a description of the following: AGS Experimental Area - High Energy Physics FY 1993 and Heavy Ion Physics FY 1993; Table of Beam Parameters and Fluxes; Experiment Schedule ``as run``; Proposed 1993 Schedule; A listing of experiments by number; Two-page summaries of each experiment begin here, also ordered by number; Publications of AGS Experiments; and List of AGS Experimenters.

  18. What Is Ag-Ed?

    ERIC Educational Resources Information Center

    Linley, Judy; Mylne, Lee

    1998-01-01

    Ag-Ed, an agricultural education project for upper elementary students, was held in conjunction with the Toowoomba Show in Queensland, Australia. Agriculture industry representatives provided 20 interactive agricultural presentations for class groups, which were supplemented with a teacher resource-package containing a directory and 13 sections of…

  19. AGS experiments, 1988, 1989, 1990

    SciTech Connect

    Depken, J.C.

    1991-04-01

    This report contains: experimental areas layout; table of beam parameters and fluxes; experiment schedule as run''; experiment long range schedule; a listing of experiments by number; two-page summaries of each experiment begin here, also ordered by number; publications of AGS experiments; and list of experimenters.

  20. AGS experiments: 1985, 1986, 1987

    SciTech Connect

    Depken, J.C.

    1987-01-01

    This report contains: Experimental areas layout, table of beam parameters and fluxes, experiment schedule ''as run,'' experiment long range schedule, a listing of experiments by number, two-page summaries of each experiment, also ordered by number, and publications of AGS experiments, 1982-1987.

  1. AGS 20th anniversary celebration

    SciTech Connect

    Baggett, N.V.

    1980-05-22

    On May 22, 1980, a symposium was held at Brookhaven to celebrate the 20th birthday of the AGS, to recall its beginnings, and to review major discoveries that have been made with its beams. The talks at the symposium are recorded in this volume.

  2. 14. ENTRANCE AT FIFTEENTH AND W STREETS, N.W., NOTE MOLDED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. ENTRANCE AT FIFTEENTH AND W STREETS, N.W., NOTE MOLDED CONCRETE FORMS, August 1976 - Meridian Hill Park, Bounded by Fifteenth, Sixteenth, Euclid & W Streets, Northwest, Washington, District of Columbia, DC

  3. 11. Building H9; 3/4 view, looking NW; showing relationship of ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. Building H-9; 3/4 view, looking NW; showing relationship of wheeling ramp to building. (Ryan and Harms) - Holston Army Ammunition Plant, RDX-and-Composition-B Manufacturing Line 9, Kingsport, Sullivan County, TN

  4. 52. VIEW LOOKING N.W. AT THE AUTOCLAVE BUILDING, PIPING FOR ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    52. VIEW LOOKING N.W. AT THE AUTOCLAVE BUILDING, PIPING FOR THE AMMONIA DISTILLATE IN FOREGROUND. MAY 21, 1919. - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL

  5. Nanomolar detection of dopamine at multi-walled carbon nanotube grafted silica network/gold nanoparticle functionalised nanocomposite electrodes.

    PubMed

    Komathi, Shanmugasundaram; Gopalan, Anantha Iyengar; Lee, Kwang-Pill

    2010-02-01

    This is the first report on ultrahigh sensitive and selective electrochemical detection of nanomolar concentrations of dopamine (DA) in the presence of ascorbic acid (AA) at a modified electrode fabricated with a new functional nanocomposite, comprising of multi-walled carbon nanotube (MWNT) grafted silica network (silica NW) and gold nanoparticles (Au NPs) (MWNT-g-silica NW/Au NPs). The fabrication of MWNT-g-silica NW/Au NPs modified electrodes involves two steps: covalent functionaliztion of MWNT with silica NW and deposition of Au NP. Cyclic voltammetry and differential pulse voltammetry experiments were performed for the individual and simultaneous electrochemical detection of DA (in nanomolar concentrations) and AA. Differential pulse voltammograms at ITO/MWNT-g-silica NW/Au NPs modified electrode (ME) revealed that the current response is linear for DA in the concentration range of 0.1 nM-30 nM with a detection limit of 0.1 nM. This is the lowest detection limit reported for DA. A plausible mechanism is presented for the excellent performance of ITO/MWNT-g-silica NW/Au NPs-ME towards nanomolar detection of DA. The results revealed that MWNT, silica NW and Au NPs in ITO/MWNT-g-silica NW/Au NPs-ME synergistically contribute to the ultrasensitivity and selectivity for the electrochemical detection of nanomolar concentrations of DA in the presence of coexisting species. PMID:20098776

  6. An efficient photocatalyst for degradation of various organic dyes: Ag@Ag2MoO4-AgBr composite.

    PubMed

    Bai, Yu-Yang; Lu, Yi; Liu, Jin-Ku

    2016-04-15

    The Ag2MoO4-AgBr composite was prepared by a facile in-situ anion-exchange method, then the Ag nanoparticles were coated on this composite through photodeposition route to form a novel Ag@Ag2MoO4-AgBr composite. The in-situ Br(-) replacement in a crystal lattice node position of Ag2MoO4 crystal allows for overcoming the resistance of electron transition effectively. Meanwhile silver nano-particles on the surface of Ag@Ag2MoO4-AgBr composite could act as electron traps to intensify the photogeneration electron-hole separation and the subsequent transfer of the trapped electron to the adsorbed O2 as an electron acceptor. As an efficient visible light catalyst, the Ag@Ag2MoO4-AgBr composite exhibited superior photocatalytic activity for the degradation of various organic dyes. The experimental results demonstrated superior photocatalytic rate of Ag@Ag2MoO4-AgBr composite compared to pure AgBr and Ag2MoO4 crystals (37.6% and 348.4% enhancement respectively). The Ag@Ag2MoO4-AgBr composite cloud degraded Rhodamin B, bromophenol blue, and amino black 10b completed in 7min. PMID:26775100

  7. Preparation and characterization of BC/PAM-AgNPs nanocomposites for antibacterial applications.

    PubMed

    Yang, Guang; Wang, Caixia; Hong, Feng; Yang, Xuexia; Cao, Zhangjun

    2015-01-22

    In this work, a bacterial cellulose/polyacrylamide (BC/PAM) double network composite was prepared to act as the template for in situ synthesis of silver nanoparticles (AgNPs). Effects of reaction conditions of the BC/PAM composite were investigated on its microstructure, mechanical properties and thermal stabilities. Both the BC/PAM composite and pure BC were utilized to prepare the corresponding silver impregnated nanocomposites, i.e., BC/PAM-AgNPs and BC-AgNPs, by an environmental friendly method, UV irradiation. The influences of the templates were investigated on the AgNPs formation and the antibacterial activities of the nanocomposites by both the zone of inhibition and dynamic shake flask methods. It was shown that the BC/PAM composite displayed a denser microstructure and higher thermal stabilities than pure BC. The BC/PAM-AgNPs nanocomposite exhibited a bigger particle size and lower mass content of AgNPs than the BC-AgNPs one. For the antibacterial test, two nanocomposites exhibited a close antibacterial effect, with a high log reduction above 3 and killing ratio above 99.9%, respectively. PMID:25439942

  8. Thermoelectric properties of semiconductor nanowire networks

    DOE PAGESBeta

    Roslyak, Oleksiy; Piryatinski, Andrei

    2016-03-28

    To examine the thermoelectric (TE) properties of a semiconductor nanowire (NW) network, we propose a theoretical approach mapping the TE network on a two-port network. In contrast to a conventional single-port (i.e., resistor)network model, our model allows for large scale calculations showing convergence of TE figure of merit, ZT, with an increasing number of junctions. Using this model, numerical simulations are performed for the Bi2Te3 branched nanowire (BNW) and Cayley tree NW (CTNW) network. We find that the phonon scattering at the network junctions plays a dominant role in enhancing the network ZT. Specifically, disordered BNW and CTNW demonstrate anmore » order of magnitude higher ZT enhancement compared to their ordered counterparts. Formation of preferential TE pathways in CTNW makes the network effectively behave as its BNW counterpart. In conclusion, we provide formalism for simulating large scale nanowire networks hinged upon experimentally measurable TE parameters of a single T-junction.« less

  9. Tectonic deformations of the NW Novaya Zemlya Archipelago

    NASA Astrophysics Data System (ADS)

    Prokopiev, Andrei; Ershova, Victoria; Khudoley, Andrey; Sobolev, Nikolay; Petrov, Eugeniy

    2016-04-01

    The Novaya Zemlya archipelago comprises two main islands (Northern and Southern). Structural studies were conducted in the northwestern part of Northern Island, composed mainly of Upper Proterozoic-Carboniferous rocks. The structural style is dominated by NW-striking folds, clearly recognized on geological maps. The folds are typically overturned to the northwest. Southeast-dipping axial-plane cleavage is widely distributed. Tectonic transportation in Mesozoic time was directed from southeast to northwest. The bedding-cleavage intersection lineation plunges to southeast and southwest, parallel to the axes of large and small folds. The dip angle of the lineation is high, ranging up to 30o or, rarely even more. Dip angle of the intersection lineation is highly variable over a short distance, pointing to occurrence of several stages of deformation. The intersection lineation plunge angels are likely close to dip angles of bedding on the early-stage fold limbs, most of which were gentle to open ones. The early folding is presumably related to Caledonian or Ellesmerian orogenies.

  10. Assessment of Quercus flowering trends in NW Spain

    NASA Astrophysics Data System (ADS)

    Jato, V.; Rodríguez-Rajo, F. J.; Fernandez-González, M.; Aira, M. J.

    2015-05-01

    This paper sought to chart airborne Quercus pollen counts over the last 20 years in the region of Galicia (NW Spain) with a view to detecting the possible influence of climate change on the Quercus airborne pollen season (APS). Pollen data from Ourense, Santiago de Compostela, Vigo and Lugo were used. The Quercus airborne pollen season was characterized in terms of the following parameters: pollen season start and end dates, peak pollen count, pollen season length and pollen index. Several methods, dates and threshold temperatures for determining the chill and heat requirements needed to trigger flowering were applied. A diverse APS onset timing sequence was observed for the four cities as Quercus flowers few days in advance in Vigo. The variations observed could be related to differences in the meteorological conditions or the thermal requirements needed for flowering. Thermal requirements differed depending on local climate conditions in the study cities: the lowest values for chilling accumulation were recorded in Vigo and the highest in Lugo, whereas the lowest heat accumulation was achieved in Vigo. Differences in APS trends between cities may reflect variations in weather-related trends. A significant trend towards rising Quercus pollen indices and higher maximum daily mean pollen counts was observed in Ourense, linked to the more marked temperature increase across southern Galicia. A non-uniform trend towards increased temperatures was noted over the study period, particularly in late summer and early autumn in all four study cities. Additionally, an increase in spring temperatures was observed in south-western Galicia.

  11. Chemical approaches to therapeutically target the metabolism and signaling of the endocannabinoid 2-AG and eicosanoids.

    PubMed

    Kohnz, Rebecca A; Nomura, Daniel K

    2014-10-01

    The endocannabinoid system, most popularly known as the target of the psychoactive component of marijuana, Δ(9)-tetrahydrocannabinol (THC), is a signaling network that modulates a diverse range of physiological processes including nociception, behavior, cognitive function, appetite, metabolism, motor control, memory formation, and inflammation. While THC and its derivatives have garnered notoriety in the eyes of the public, the endocannabinoid system consists of two endogenous signaling lipids, 2-arachidonoylglycerol (2-AG) and N-arachidonoylethanolamine (anandamide), which activate cannabinoid receptors CB1 and CB2 in the nervous system and peripheral tissues. This review will focus on the recent efforts to chemically manipulate 2-AG signaling through the development of inhibitors of the 2-AG-synthesizing enzyme diacylglycerol lipase (DAGL) or the 2-AG-degrading enzyme monoacylglycerol lipase (MAGL), and assessing the therapeutic potential of DAGL and MAGL inhibitors in pain, inflammation, degenerative diseases, tissue injury, and cancer. PMID:24676249

  12. Antibacterial activity and reusability of CNT-Ag and GO-Ag nanocomposites

    NASA Astrophysics Data System (ADS)

    Kim, Ji Dang; Yun, Hyosuk; Kim, Gwui Cheol; Lee, Chul Won; Choi, Hyun Chul

    2013-10-01

    A facile approach to the synthesis of novel CNT-Ag and GO-Ag antibacterial materials, in which thiol groups are utilized as linkers to secure silver (Ag) nanoparticles to the CNT and GO surfaces without agglomeration, is reported. The resulting CNT-Ag and GO-Ag samples were characterized by performing TEM, XRD, Auger, XPS, and Raman measurements, which revealed that in these antibacterial materials size-similar and quasi-spherical Ag nanoparticles are anchored to the CNT and GO surfaces. The Ag nanoparticles in CNT-Ag and GO-Ag have narrow size distributions with average diameters of 2.6 and 3.5 nm respectively. The antibacterial activities of CNT-Ag and GO-Ag against Escherichia coli were assessed with the paper-disk diffusion method and by determining the minimal inhibitory concentrations (MICs). CNT-Ag was found to have higher antibacterial activity than the reference Ag colloid. Moreover, both CNT-Ag and GO-Ag retain more than 50% of their original antibacterial activities after 20 washes with detergent, which indicates their potential as antibacterial materials for laboratory and medical purposes.

  13. Comparative Study of Antimicrobial Activity of AgBr and Ag Nanoparticles (NPs)

    PubMed Central

    Suchomel, Petr; Kvitek, Libor; Panacek, Ales; Prucek, Robert; Hrbac, Jan; Vecerova, Renata; Zboril, Radek

    2015-01-01

    The diverse mechanism of antimicrobial activity of Ag and AgBr nanoparticles against gram-positive and gram-negative bacteria and also against several strains of candida was explored in this study. The AgBr nanoparticles (NPs) were prepared by simple precipitation of silver nitrate by potassium bromide in the presence of stabilizing polymers. The used polymers (PEG, PVP, PVA, and HEC) influence significantly the size of the prepared AgBr NPs dependently on the mode of interaction of polymer with Ag+ ions. Small NPs (diameter of about 60–70 nm) were formed in the presence of the polymer with low interaction as are PEG and HEC, the polymers which interact with Ag+ strongly produce nearly two times bigger NPs (120–130 nm). The prepared AgBr NPs were transformed to Ag NPs by the reduction using NaBH4. The sizes of the produced Ag NPs followed the same trends – the smallest NPs were produced in the presence of PEG and HEC polymers. Prepared AgBr and Ag NPs dispersions were tested for their biological activity. The obtained results of antimicrobial activity of AgBr and Ag NPs are discussed in terms of possible mechanism of the action of these NPs against tested microbial strains. The AgBr NPs are more effective against gram-negative bacteria and tested yeast strains while Ag NPs show the best antibacterial action against gram-positive bacteria strains. PMID:25781988

  14. Synthesis, structures and properties of Ag+ complexes containing polyphosphine ligands with extended Ag⋯C, N-O⋯π and C-H⋯π interactions

    NASA Astrophysics Data System (ADS)

    Huang, Ting-Hong; Yang, Hu; Yang, Guo; Li, Yanfen; Huang, Li-Li

    2016-08-01

    Based on ligands of N,N-bis((diphenylphosphino)methyl)benzenamine (pba), 4-(4-(bis((diphenylphosphino)methyl)amino)benzyl)-N-((diphenylphosphino)methyl)benzenamine (dptp) and N,N,N‧,N‧-tetrakis((diphenylphosphino)methyl)benzene-1,4-diamine (pbaa), three new silver(I) complexes [Ag(pba)2]ClO4 (1), [Ag2(dptp)2](ClO4)2·2DMF (2) and [Ag4(pbaa)(NO3)4]n (3), have been synthesized and characterized. Structural analysis reveals that all of these complexes contain the 1D infinite chains, with different variations in the weak interactions. Complexes 1 and 2 are interconnected by intermolecular C-H⋯π interactions to form 1D infinite chains and 2D networks, and the ordered-layer-lattic ClO4- and DMF in 2 are between 2D networks. For 3, the pbaa ligand adopts a tetradentate coordination mode to link two adjacent stair-like [Ag4O4] cores resulting in a 1D chain, respectively, with Ag⋯C, N-O⋯π and C-H⋯π interactions. All these show that phosphine ligands play an important role in the construction of interesting topological structures with different types of the weak interactions.

  15. Shifts in the architecture of the Nationwide Health Information Network

    PubMed Central

    Sundwall, David; Lenert, Michael Edward

    2012-01-01

    In the midst of a US $30 billion USD investment in the Nationwide Health Information Network (NwHIN) and electronic health records systems, a significant change in the architecture of the NwHIN is taking place. Prior to 2010, the focus of information exchange in the NwHIN was the Regional Health Information Organization (RHIO). Since 2010, the Office of the National Coordinator (ONC) has been sponsoring policies that promote an internet-like architecture that encourages point to-point information exchange and private health information exchange networks. The net effect of these activities is to undercut the limited business model for RHIOs, decreasing the likelihood of their success, while making the NwHIN dependent on nascent technologies for community level functions such as record locator services. These changes may impact the health of patients and communities. Independent, scientifically focused debate is needed on the wisdom of ONC's proposed changes in its strategy for the NwHIN. PMID:22268218

  16. The Late Miocene Quaternary Antofalla volcanic complex, southern Puna, NW Argentina: Protracted history, diverse petrology, and economic potential

    NASA Astrophysics Data System (ADS)

    Richards, Jeremy P.; Ullrich, Thomas; Kerrich, Robert

    2006-04-01

    The Antofalla volcanic complex (AVC) is located on the southern Puna plateau of NW Argentina, ˜100 km east of the main axis of the Cordillera Occidental volcanic arc. It lies on the NW-SE Archibarca lineament, one of several transverse structures that cut across the Andes from Chile, and divert arc magmatism in SE-trending fingers across the Puna. 40Ar/ 39Ar dating of volcanic products from the AVC reveals a protracted magmatic history from 10.9 to ≤ 1.6 Ma. Initial volcanism was characterized by eruption of voluminous rhyolitic ignimbrites, deposited directly onto exposed crystalline basement and supracrustal sedimentary rocks. These rhyolites record significant geochemical evidence for crustal contamination, or derivation by crustal melting, which decreases upwards through the pyroclastic sequence. They were followed by extrusion of potassic lavas of the shoshonite-latite-trachydacite suite from 10.1 to 9.5 Ma. Subsequent magmatism (9.1-1.6 Ma) was of basaltic andesite-andesite-dacite composition, with localized, smaller volume, dacitic and rhyolitic ignimbrites. Monogenetic basaltic andesite cinder cones and lava flows were erupted in the Quaternary in response to a change to transtensional tectonics in the Puna. The volcanic sequence is interpreted to record the early development of a lower crustal MASH zone at ˜11 Ma, where mantle-derived arc magmas interacted extensively with felsic lower crustal rocks to produce evolved shoshonitic compositions, and crustal melts that erupted to form rhyolitic ignimbrites (common at this time throughout the Puna). After establishment of a steady-state MASH zone by ˜9 Ma, subsequent basaltic andesite-andesite magmas show less evidence of felsic crustal contamination, and may have developed largely by interaction with previous ultramafic-mafic fractionates of early magmas in the lower crust. More felsic dacitic magmas appear to have evolved largely by fractional crystallization from basaltic andesites and andesites, with

  17. Capillary Printing of Highly Aligned Silver Nanowire Transparent Electrodes for High-Performance Optoelectronic Devices.

    PubMed

    Kang, Saewon; Kim, Taehyo; Cho, Seungse; Lee, Youngoh; Choe, Ayoung; Walker, Bright; Ko, Seo-Jin; Kim, Jin Young; Ko, Hyunhyub

    2015-12-01

    Percolation networks of silver nanowires (AgNWs) are commonly used as transparent conductive electrodes (TCEs) for a variety of optoelectronic applications, but there have been no attempts to precisely control the percolation networks of AgNWs that critically affect the performances of TCEs. Here, we introduce a capillary printing technique to precisely control the NW alignment and the percolation behavior of AgNW networks. Notably, partially aligned AgNW networks exhibit a greatly lower percolation threshold, which leads to the substantial improvement of optical transmittance (96.7%) at a similar sheet resistance (19.5 Ω sq(-1)) as compared to random AgNW networks (92.9%, 20 Ω sq(-1)). Polymer light-emitting diodes (PLEDs) using aligned AgNW electrodes show a 30% enhanced maximum luminance (33068 cd m(-2)) compared to that with random AgNWs and a high luminance efficiency (14.25 cd A(-1)), which is the highest value reported so far using indium-free transparent electrodes for fluorescent PLEDs. In addition, polymer solar cells (PSCs) using aligned AgNW electrodes exhibit a power conversion efficiency (PCE) of 8.57%, the highest value ever reported to date for PSCs using AgNW electrodes. PMID:26540011

  18. Microseismicity at the North Anatolian Fault in the Sea of Marmara offshore Istanbul, NW Turkey

    USGS Publications Warehouse

    Bulut, Fatih; Bohnhoff, Marco; Ellsworth, William L.; Aktar, Mustafa; Dresen, Georg

    2009-01-01

    The North Anatolian Fault Zone (NAFZ) below the Sea of Marmara forms a “seismic gap” where a major earthquake is expected to occur in the near future. This segment of the fault lies between the 1912 Ganos and 1999 İzmit ruptures and is the only NAFZ segment that has not ruptured since 1766. To monitor the microseismic activity at the main fault branch offshore of Istanbul below the Çınarcık Basin, a permanent seismic array (PIRES) was installed on the two outermost Prince Islands, Yassiada and Sivriada, at a few kilometers distance to the fault. In addition, a temporary network of ocean bottom seismometers was deployed throughout the Çınarcık Basin. Slowness vectors are determined combining waveform cross correlation and P wave polarization. We jointly invert azimuth and traveltime observations for hypocenter determination and apply a bootstrap resampling technique to quantify the location precision. We observe seismicity rates of 20 events per month for M < 2.5 along the basin. The spatial distribution of hypocenters suggests that the two major fault branches bounding the depocenter below the Çınarcık Basin merge to one single master fault below ∼17 km depth. On the basis of a cross-correlation technique we group closely spaced earthquakes and determine composite focal mechanisms implementing recordings of surrounding permanent land stations. Fault plane solutions have a predominant right-lateral strike-slip mechanism, indicating that normal faulting along this part of the NAFZ plays a minor role. Toward the west we observe increasing components of thrust faulting. This supports the model of NW trending, dextral strike-slip motion along the northern and main branch of the NAFZ below the eastern Sea of Marmara.

  19. Visualizing Redox Dynamics of a Single Ag/AgCl Heterogeneous Nanocatalyst at Atomic Resolution.

    PubMed

    Wu, Yimin A; Li, Liang; Li, Zheng; Kinaci, Alper; Chan, Maria K Y; Sun, Yugang; Guest, Jeffrey R; McNulty, Ian; Rajh, Tijana; Liu, Yuzi

    2016-03-22

    Operando characterization of gas-solid reactions at the atomic scale is of great importance for determining the mechanism of catalysis. This is especially true in the study of heterostructures because of structural correlation between the different parts. However, such experiments are challenging and have rarely been accomplished. In this work, atomic scale redox dynamics of Ag/AgCl heterostructures have been studied using in situ environmental transmission electron microscopy (ETEM) in combination with density function theory (DFT) calculations. The reduction of Ag/AgCl to Ag is likely a result of the formation of Cl vacancies while Ag(+) ions accept electrons. The oxidation process of Ag/AgCl has been observed: rather than direct replacement of Cl by O, the Ag/AgCl nanocatalyst was first reduced to Ag, and then Ag was oxidized to different phases of silver oxide under different O2 partial pressures. Ag2O formed at low O2 partial pressure, whereas AgO formed at atmospheric pressure. By combining in situ ETEM observation and DFT calculations, this structural evolution is characterized in a distinct nanoscale environment. PMID:26937679

  20. A study of petroleum system in Chuhuangkeng anticline, NW Taiwan

    NASA Astrophysics Data System (ADS)

    Yiang, S.; Tsai, L. Y.

    2015-12-01

    Since energy demand is still increasing in the world, the exploration of unconventional fossil fuel becomes more and more important today. Miaoli area of the NW Western Foothill Belt, Taiwan, had been a major oil and gas producing field in the past, important oil/gas producing structures include Tiechenshen, Chinshui and Chuhuangkeng anticline. The reservoir rocks of unconventional resources need to be examined to illustrate the remaining hydrocarbon potential of Chuhuangkeng anticline. A standard evaluation procedure for assessing integrated geochemical parameters can thus be established. In this study, we combine various geochemical parameters including TOC, porosity, Rock-Eval pyrolysis, vitrinite reflectance measurement to assess the HC potential of shale gas reservoirs. The results show that Wuchishan and Mushan Formations possess the best hydrocarbon potential in Chuhuangkeng anticline. The maturation of Wuchishan and Mushan Formations are both in oil window (Ro of Wuchishan formation =1.7% , Ro of Mushan =1.01~1.53% ). The maturation of Shitih Formation barely reached oil window, however the shallower depth and less exploration cost are the advantages of Shitih Formation. Moreover, Wuchishan Formation is a dry gas field and Mushan Formation is a condensate gas field. The results of porosity show that there are secondary porosity existed in Mushan Formation which provides the extra storage space for hydrocarbon. Additionally, Piling Shale is a good cap rock on top of Mushan formation, it further benefits the conservation of oil and gas in Mushan Formation. In conclude, Mushan Formation is the most potential HC target in future shale gas exploration.

  1. Late Cenozoic Deformation in the Western Tarim Basin, NW China

    NASA Astrophysics Data System (ADS)

    Thompson, J. A.; Burbank, D. W.; Chen, J.; Li, T.

    2009-12-01

    The Tian Shan in NW China is one of the most active regions of intracontinental deformation in the world, accommodating a large fraction (~40%) of the shortening from the Indo-Eurasian collision. The western Tarim Basin, situated between the southern Tian Shan and Pamir Mountains, manifests this deformation through a series of east-west trending fault-related folds that have formed during the late Cenozoic. Previous studies in this region have focused on the kinematics, style, and timing of detachment folds related to folding within the foreland basin of the southern Tian Shan. In contrast, this study focuses on the deformation caused by fault-propagation folding resulting from the northward movement of the Pamir. The rates of deformation are calculated using a combination of optically stimulated luminescence (OSL) ages, structural mapping and differential GPS surveys of fault scarps and deformed terrace surfaces crossing active folds. OSL dating provides the time since the sediment was last exposed to daylight, i.e., time since burial. Consequently, OSL is useful for dating the abandonment of terrace surfaces due to tectonic (fold growth) or climatic events. OSL quartz samples were collected from silt lenses within gravel topping the terraces. Most of the quartz OSL signals are weak, thus several grain sizes (silt (4-11 µm, 8-15 µm) and sand (90-125 µm)) were analyzed and different integrations of the shine-down curves were explored to calculate equivalent doses. The implications for different equivalent doses and ages on the calculation of rates of deformation are also addressed.

  2. Shear zone reactivation during South Atlantic rifting in NW Namibia

    NASA Astrophysics Data System (ADS)

    Koehn, D.; Passchier, C. W.; Salomon, E.

    2013-12-01

    Reactivation of inherited structures during rifting as well as an influence of inherited structures on the orientation of a developing rift has long been discussed (e.g. Piqué & Laville, 1996; Younes & McClay, 2002). Here, we present a qualitative and quantitative study of shear zone reactivation during the South Atlantic opening in NW Namibia. The study area comprises the Neo-Proterozoic rocks of the Kaoko Belt which was formed during the amalgamation of Gondwana. The Kaoko Belt encompasses the prominent ~500 km long ductile Purros shear zone and the Three Palms shear zone, both running sub-parallel to the present continental margin. The Kaoko Belt is partly overlain by the basalts of the Paraná-Etendeka Large Igneous Province, which with an age of ~133 Ma were emplaced just before or during the onset of the Atlantic rifting at this latitude. Combining the analysis of satellite imagery and digital elevation models with extensive field work, we identified numerous faults tracing the old shear zones along which the Etendeka basalts were down-faulted. The faults are often listric, yet we also found evidence for a regional scale basin formation. Our analysis allowed for constructing the geometry of three of these faults and we could thus estimate the vertical offsets to ~150 m, ~500 m, and ~1100 m, respectively. Our results contribute to the view that the basement inheritance plays a significant role on rifting processes and that the reactivation of shear zones can accumulate significant amounts of displacement. References: Pique, A. and E. Laville (1996). The Central Atlantic rifting: Reactivation of Paleozoic structures?. J. Geodynamics, 21, 235-255. Younes, I.A. and K. McClay (2002). Development of accommodation zones in the Gulf of Suez-Red Sea rift, Egypt. AAPG Bulletin, 86, 1003-1026.

  3. Petrography, palynology and depositional environment of Gelibolu coals, NW Turkey

    NASA Astrophysics Data System (ADS)

    Demirtaş, Ferdi; Bozcu, Mustafa; Koşun, Erdal

    2014-05-01

    Upper Oligocene and Miocene coal samples collected from two outcrops in the Gelibolu Peninsula, NW Turkey were analyzed petrographically and palynologically to determine the depositional environment of the coals. Microscopic studies reveal that the studied coal samples from both locations are characterized by high amount of huminite group macerals, ranging from 46 to 78% (mineral-included basis). The prevailing maceral from this group is gelinite (31-65%), it can be easily seen on all studied samples, indicative of high gelification degree of organic matter. Relatively low amount of liptinite (does not exceed 9%) and inertinite (does not exceed 8%) are also observed in the coals. The mineral matter content is variable but generally high, varying from 5 to 37%, as in other Turkish coals and consists mostly of clay minerals, quartz, calcite and pyrite. The mean reflectance values range from 0.502 to 0.564% suggesting that rank of coal is subbituminous (ASTM). The chemical properties of coal including calorific value, volatile matter and fixed carbon content are also in accordance with rank of coal. Facies indices based on maceral ratios (Tissue Preservation Index vs. Gelification Index and ABC ternary diagrams) were used to interpret to depositional environment of coals. Low tissue preservation index (TPI) and high gelification index (GI) values are observed. These indices indicate that the coals deposited in limnic environment. High pH and strongly reducing conditions inferred from the presence of framboidal pyrite and also evidenced by low TPI values. The palynological assembly of the coals dominated by angiosperm pollen and spore, however, gymnosperms were rarely seen. Herbaceous/sedge plants are common in Miocene coal samples.

  4. The Pliocene-Pleistocene sedimentary tectonic history of NW California

    SciTech Connect

    Stone, L.; Moley, K.; Aalto, K.R. . Dept. of Geology); Renne, P.R. . Berkeley Geochronology Center)

    1993-04-01

    A thick sequence of Late Miocene to Pleistocene sediments thought to represent deposition in a Neogene forearc basin are preserved in the structural basin referred to as the Eel River basin' located offshore of NW California and SE Oregon. The southern portion of this structural basin comes on land in the vicinity of Eureka where the marine and fluvial Wildcat Group is exposed. Basal Wildcat Group sediments are fluvial and littorial. Marine sandstones of the Wildcat Group contain K-spar concentrations of 5.5% and are believed to represent a fresh source. [sup 40]Ar/[sup 39]Ar laser probe analyses of Wildcat Group micas yield dates of 52--57, 66--75, 128.5 and 299--303 Ma. The presence of Idaho detritus throughout the Neogene Wildcat Group indicates that the Klamath Mountains remained low during the Pliocene and early Pleistocene. Younger fluvial sediments in this region contain primarily locally derived detritus indicating local uplift of the Klamath Mountains. To the north, at Crescent City, thin remnants of the near-shore Saint George Formation and the eastern estuarine and fluvial Wimer Formation are lowermost Pliocene in age (5 ma). The presence of the highly erodible Wilmer Formation on uplifted plateaus in an area of extreme rainfall suggest that these sediments represent only the lowermost portion of an originally much thicker sequence. Consequently, the sediments confined to the present day Eel River basin do not represent the lateral extent of the original forearc basin. Sandstones and conglomerates of the Saint George and Wimer Formation indicate a local Klamath provenance derivation.

  5. Assessment of Quercus flowering trends in NW Spain.

    PubMed

    Jato, V; Rodríguez-Rajo, F J; Fernandez-González, M; Aira, M J

    2015-05-01

    This paper sought to chart airborne Quercus pollen counts over the last 20 years in the region of Galicia (NW Spain) with a view to detecting the possible influence of climate change on the Quercus airborne pollen season (APS). Pollen data from Ourense, Santiago de Compostela, Vigo and Lugo were used. The Quercus airborne pollen season was characterized in terms of the following parameters: pollen season start and end dates, peak pollen count, pollen season length and pollen index. Several methods, dates and threshold temperatures for determining the chill and heat requirements needed to trigger flowering were applied. A diverse APS onset timing sequence was observed for the four cities as Quercus flowers few days in advance in Vigo. The variations observed could be related to differences in the meteorological conditions or the thermal requirements needed for flowering. Thermal requirements differed depending on local climate conditions in the study cities: the lowest values for chilling accumulation were recorded in Vigo and the highest in Lugo, whereas the lowest heat accumulation was achieved in Vigo. Differences in APS trends between cities may reflect variations in weather-related trends. A significant trend towards rising Quercus pollen indices and higher maximum daily mean pollen counts was observed in Ourense, linked to the more marked temperature increase across southern Galicia. A non-uniform trend towards increased temperatures was noted over the study period, particularly in late summer and early autumn in all four study cities. Additionally, an increase in spring temperatures was observed in south-western Galicia. PMID:25108375

  6. Timing and Spatial Distribution of Loess in Xinjiang, NW China

    PubMed Central

    Li, Yun; Song, Yougui; Yan, Libin; Chen, Tao; An, Zhisheng

    2015-01-01

    Central Asia is one of the most significant loess regions on Earth, with an important role in understanding Quaternary climate and environmental change. However, in contrast to the widely investigated loess deposits in the Chinese Loess Plateau, the Central Asian loess–paleosol sequences are still insufficiently known and poorly understood. Through field investigation and review of the previous literature, the authors have investigated the distribution, thickness and age of the Xinjiang loess, and analyzed factors that control these parameters in the Xinjiang in northwest China, Central Asia. The loess sediments cover river terraces, low uplands, the margins of deserts and the slopes of the Tianshan Mountains and Kunlun Mountains and are also present in the Ili Basin. The thickness of the Xinjiang loess deposits varies from several meters to 670 m. The variation trend of the sand fraction (>63 μm) grain-size contour can indicate the local major wind directions, so we conclude that the NW and NE winds are the main wind directions in the North and South Xinjiang, and the westerly wind mainly transport dust into the Ili basin. We consider persistent drying, adequate regional wind energy and well-developed river terraces to be the main factors controlling the distribution, thickness and formation age of the Xinjiang loess. The well-outcropped loess sections have mainly developed since the middle Pleistocene in Xinjiang, reflecting the appearance of the persistent drying and the present air circulation system. However, the oldest loess deposits are as old as the beginning of the Pliocene in the Tarim Basin, which suggests that earlier aridification occurred in the Tarim Basin rather than in the Ili Basin and the Junggar Basin. PMID:25970617

  7. Timing and Spatial Distribution of Loess in Xinjiang, NW China.

    PubMed

    Li, Yun; Song, Yougui; Yan, Libin; Chen, Tao; An, Zhisheng

    2015-01-01

    Central Asia is one of the most significant loess regions on Earth, with an important role in understanding Quaternary climate and environmental change. However, in contrast to the widely investigated loess deposits in the Chinese Loess Plateau, the Central Asian loess-paleosol sequences are still insufficiently known and poorly understood. Through field investigation and review of the previous literature, the authors have investigated the distribution, thickness and age of the Xinjiang loess, and analyzed factors that control these parameters in the Xinjiang in northwest China, Central Asia. The loess sediments cover river terraces, low uplands, the margins of deserts and the slopes of the Tianshan Mountains and Kunlun Mountains and are also present in the Ili Basin. The thickness of the Xinjiang loess deposits varies from several meters to 670 m. The variation trend of the sand fraction (>63 μm) grain-size contour can indicate the local major wind directions, so we conclude that the NW and NE winds are the main wind directions in the North and South Xinjiang, and the westerly wind mainly transport dust into the Ili basin. We consider persistent drying, adequate regional wind energy and well-developed river terraces to be the main factors controlling the distribution, thickness and formation age of the Xinjiang loess. The well-outcropped loess sections have mainly developed since the middle Pleistocene in Xinjiang, reflecting the appearance of the persistent drying and the present air circulation system. However, the oldest loess deposits are as old as the beginning of the Pliocene in the Tarim Basin, which suggests that earlier aridification occurred in the Tarim Basin rather than in the Ili Basin and the Junggar Basin. PMID:25970617

  8. Mesozooplankton metabolism and feeding in the NW Iberian upwelling

    NASA Astrophysics Data System (ADS)

    Isla, José Alejandro; Ceballos, Sara; Anadón, Ricardo

    2004-09-01

    Mesozooplankton size-fractionated biomass, feeding, and metabolic rates were investigated during a cruise conducted off NW Spain in August 1998. Based on different hydrographic conditions observed throughout the study area (upwelling events nearshore and stratified waters offshore), the sampling area was divided into coastal and oceanic zones. Both phytoplankton and mesozooplankton biomass were higher in the coastal upwelling than in the offshore zone. Size structure analysis shows that the small fraction (200-500 μm) of mesozooplankton was more important than the larger fractions (500-1000 μm and >1000 μm) in the open ocean in terms of both biomass and grazing activity. The relationship between copepod ingestion rate and the concentration of chlorophyll a >5 μm resembled a type II functional response. Saturation occurred at the coastal stations, where copepod gut contents were highest. The grazing impact on both phytoplankton biomass and primary production seemed to be higher offshore (5.7 and 12.9%, respectively) than in upwelled waters (5.2 and 5.2%), although the differences were not statistically significant. Phytoplankton ingestion was enough to fulfil the basal metabolism of mesozooplankton in the upwelling area (102.1% of the minimum carbon requirements met) but not in the offshore (45.9%). Feeding activity and metabolic measurements on mesozooplankton point to a herbivorous food web in the coastal upwelling zone and a multivorous food web in the stratified open oceanic waters. The amount of metabolic end products released by mesozooplankton was higher in the coastal zone, but mesozooplankton played a more important role as nutrient regenerators in the multivorous food web (30.3 and 21.7% of the nitrogen and phosphorus phytoplankton demand accounted for ammonium and phosphate excretion, respectively) than in the herbivorous one (3.8% for ammonium and 2.6% for phosphate).

  9. Safinamide: FCE 26743, NW 1015, PNU 151774, PNU 151774E.

    PubMed

    2004-01-01

    Safinamide [NW 1015, PNU 151774E; FCE 26743] is a potent anticonvulsant and antiparkinsonian compound that is being developed by Newron Pharmaceuticals in Europe. It has been shown to antagonise the calcium and sodium channels, as well as inhibit monoamine oxidase type-B (MAO-B). Phase III trials for the treatment of Parkinson's disease are underway in Germany and Europe, while phase II trials in patients with epilepsy are ongoing in Italy. Newron Pharmaceuticals was founded at the end of 1998 after Pharmacia & Upjohn announced its worldwide restructuring programme. Newron obtained the rights to safinamide, which Pharmacia Corporation (now Pfizer) had been developing as PNU 151774E. Safinamide was originated by Farmitalia-CarloErba in Italy. Newron now owns all intellectual property associated with the drug.A multinational phase II trial for Parkinson's disease in Europe has shown positive results in slowing the progression of the disease; however, due to the placebo-effect seen in this study, a longer (6-month) phase IIb study is planned for the second quarter of 2003. In July 2003, Newron received an IND from the US FDA authorising a phase I trial to confirm that no dietary restrictions are needed in patients while being treated with safinamide. This study is be conducted in 12 healthy volunteers at the University of Vienna, Austria, and will be followed by efficacy studies in Parkinson's disease in the US. Five phase I trials were completed in April 2001 in Switzerland. Safinamide combines sodium and calcium channel modulatory activity with monoamine oxidase B inhibition. PMID:15563241

  10. Grounding zone wedges, Kveithola Trough (NW Barents Sea)

    NASA Astrophysics Data System (ADS)

    Rebesco, Michele; Urgeles, Roger; Özmaral, Asli; Hanebuth, Till; Caburlotto, Andrea; Hörner, Tanja; Lantzsch, Hendrik; LLopart, Juame; Lucchi, Renata; Skøtt Nicolaisen, Line; Giacomo, Osti; Sabbatini, Anna; Camerlenghi, Angelo

    2014-05-01

    Swath bathymetry within Kveithola Trough (NW Barents Sea) shows a seafloor characterized by E-W trending megascale glacial lineations (MSGLs) overprinted by transverse Grounding Zone Wedges (GZWs), which give the trough a stair profile (Rebesco et al., 2011). GZWs are formed by deposition of subglacial till at temporarily stable ice-stream fronts in between successive episodic retreats (Rüther et al., 2012; Bjarnadóttir et al., 2012). Sub-bottom data show that present-day morphology is largely inherited from palaeo-seafloor topography of GZWs, which is draped by a deglacial to early Holocene glaciomarine sediments (about 15 m thick). The ice stream that produced such subglacial morphology was flowing from East to West inside Kveithola Trough during Last Glacial Maximum. Its rapid retreat was likely associated with progressive lift-offs, and successive rapid melting of the grounded ice, induced by the eustatic sea-level rise (Lucchi et al., 2013). References: Bjarnadóttir, L.R., Rüther, D.C., Winsborrow, M.C.M., Andreassen, K., 2012. Grounding-line dynamics during the last deglaciation of Kveithola, W Barents Sea, as revealed by seabed geomorphology and shallow seismic stratigraphy. Boreas, 42, 84-107. Lucchi R.G., et al. 2013. Postglacial sedimentary processes on the Storfjorden and Kveithola TMFs: impact of extreme glacimarine sedimentation. Global and Planetary Change, 111, 309-326. Rebesco, M., et al. 2011. Deglaciation of the Barents Sea Ice Sheet - a swath bathymetric and subbottom seismic study from the Kveitehola Trough. Marine Geology, 279, 141-14. Rüther, D.C., Bjarnadóttir, L.R., Junttila, J., Husum, K., Rasmussen, T.L., Lucchi, R.G., Andreassen, K., 2012. Pattern and timing of the north-western Barents Sea Ice Sheet deglaciation and indications of episodic Holocene deposition. Boreas 41, 494-512.

  11. DENSITY VARIATIONS IN THE NW STAR STREAM OF M31

    SciTech Connect

    Carlberg, R. G.; Richer, Harvey B.; McConnachie, Alan W. E-mail: richer@astro.ubc.ca

    2011-04-20

    The Pan Andromeda Archeological Survey (PAndAS) CFHT Megaprime survey of the M31-M33 system has found a star stream which extends about 120 kpc NW from the center of M31. The great length of the stream, and the likelihood that it does not significantly intersect the disk of M31, means that it is unusually well suited for a measurement of stream gaps and clumps along its length as a test for the predicted thousands of dark matter sub-halos. The main result of this paper is that the density of the stream varies between zero and about three times the mean along its length on scales of 2-20 kpc. The probability that the variations are random fluctuations in the star density is less than 10{sup -5}. As a control sample, we search for density variations at precisely the same location in stars with metallicity higher than the stream [Fe/H] = [0, -0.5] and find no variations above the expected shot noise. The lumpiness of the stream is not compatible with a low mass star stream in a smooth galactic potential, nor is it readily compatible with the disturbance caused by the visible M31 satellite galaxies. The stream's density variations appear to be consistent with the effects of a large population of steep mass function dark matter sub-halos, such as found in LCDM simulations, acting on an approximately 10 Gyr old star stream. The effects of a single set of halo substructure realizations are shown for illustration, reserving a statistical comparison for another study.

  12. Visible emission from Ag+ exchanged SOD zeolites

    NASA Astrophysics Data System (ADS)

    Lin, H.; Imakita, K.; Fujii, M.; Prokof'ev, V. Yu.; Gordina, N. E.; Saïd, B.; Galarneau, A.

    2015-09-01

    Broad visible emissions dominant at green or red have been observed for the thermally-treated Ag+ exchanged SOD zeolites, determined by the Ag+ loading contents and the excitation wavelengths. Contrary to the notable reversible green/red dominant emission evolution in the Ag+ exchanged LTA zeolites upon hydration/dehydration in air (or water vapor)/vacuum, emission spectra of the Ag+ exchanged SOD zeolites are insensitive to the environmental change. This is most probably due to the difficult H2O permeation in SOD zeolites in comparison with LTA zeolites. By combining the environment dependent emission spectra of the Ag+ exchanged LTA and SOD zeolites, we proposed the following emission mechanisms for Ag+ exchanged LTA and SOD zeolites: the green emission is due to the transition from ligand-to-metal (framework O2- --> Ag+) charge transfer state to the ground state and the red emission is due to the transition from the metal-metal (Ag+-Ag+) charge transfer state to the ground state. The insensitive environment dependent emission characteristics of Ag+ exchanged SOD zeolites may have potential applications as robust phosphors.

  13. The new silver borate Ag{sub 3}B{sub 5}O{sub 9}

    SciTech Connect

    Sohr, Gerhard; Falkowski, Viktoria; Huppertz, Hubert

    2015-05-15

    Single crystals of Ag{sub 3}B{sub 5}O{sub 9} were obtained via high-pressure synthesis at 3 GPa and 600 °C, using a Walker-type multianvil high-pressure device. Ag{sub 3}B{sub 5}O{sub 9} crystalizes with a=674.7(2), b=943.5(2), c=1103.5(2) pm, V=0.7025(2) nm{sup 3}, and Z=4 in the noncentrosymmetric space group P2{sub 1}2{sub 1}2{sub 1} (no. 19). The orthorhombic structure was refined from 3740 independent reflections with R1=0.0496 and wR2=0.587 (all data). It is built up from infinite corner-sharing chains of BO{sub 4} tetrahedra along the a axis, which are interconnected by BO{sub 3} groups to form a network. In the structure, three crystallographically independent sites are occupied with Ag{sup +} cations exhibiting argentophillic interactions. The synthetic conditions as well as the results of the single crystal structure analysis are presented. - Graphical abstract: Noncentrosymmetric silver borate: During investigations in the system Ag–B–O, a new noncentrosymmetric silver borate Ag{sub 3}B{sub 5}O{sub 9} was discovered. The new structure type is built up from corner-sharing BO{sub 3} and BO{sub 4} groups, forming a network. Argentophillic interactions are clearly indicated by the Ag{sup +}⋯Ag{sup +} distances present in the structure. - Highlights: • A noncentrosymmetric borate Ag{sub 3}B{sub 5}O{sub 9} is accessible via high-pressure synthesis. • Ag{sub 3}B{sub 5}O{sub 9} is the second high-pressure silver borate. • Ag{sup +}⋯Ag{sup +} distances in Ag3B5O9 clearly indicate the presence of argentophillic interactions.

  14. Structural, elastic, electronic, and thermodynamic properties of MgAgSb investigated by density functional theory

    NASA Astrophysics Data System (ADS)

    Wang, Jun-Fei; Fu, Xiao-Nan; Zhang, Xiao-Dong; Wang, Jun-Tao; Li, Xiao-Dong; Jiang, Zhen-Yi

    2016-08-01

    The structural, elastic, electronic, and thermodynamic properties of thermoelectric material MgAgSb in γ,β,α phases are studied with first-principles calculations based on density functional theory. The optimized lattice constants accord well with the experimental data. According to the calculated total energy of the three phases, the phase transition order is determined from α to γ phase with cooling, which is in agreement with the experimental result. The physical properties such as elastic constants, bulk modulus, shear modulus, Young’s modulus, Poisson’s ratio, and anisotropy factor are also discussed and analyzed, which indicates that the three structures are mechanically stable and each has a ductile feature. The Debye temperature is deduced from the elastic properties. The total density of states (TDOS) and partial density of states (PDOS) of the three phases are investigated. The TDOS results show that the γ phase is most stable with a pseudogap near the Fermi level, and the PDOS analysis indicates that the conduction band of the three phases is composed mostly of Mg-3s, Ag-4d, and Sb-5p. In addition, the changes of the free energy, entropy, specific heat, thermal expansion of γ-MgAgSb with temperature are obtained successfully. The obtained results above are important parameters for further experimental and theoretical tuning of doped MgAgSb as a thermoelectric material at high temperature. Project supported by the National Natural Science Foundation of China (Grant No. 11504088), the Fund from Henan University of Technology, China (Grant Nos. 2014YWQN08 and 2013JCYJ12), the Natural Science Fund from the Henan Provincial Education Department, China (Grant No. 16A140027), the Natural Science Foundation of Shaanxi Province of China (Grant Nos. 2013JQ1018 and 15JK1759), and the Science Foundation of Northwest University of China (Grant No. 14NW23).

  15. Capacitive deionization of seawater effected by nano Ag and Ag@C on graphene.

    PubMed

    Cai, P-F; Su, C-J; Chang, W-T; Chang, F-C; Peng, C-Y; Sun, I-W; Wei, Y-L; Jou, C-J; Wang, H Paul

    2014-08-30

    Drinking water shortage has become worse in recent decades. A new capacitive deionization (CDI) method for increasing water supplies through the effective desalination of seawater has been developed. Silver as nano Ag and Ag@C which was prepared by carbonization of the Ag(+)-β-cyclodextrin complex at 573 K for 30 min can add the antimicrobial function into the CDI process. The Ag@C and Ag nanoparticles dispersed on reduced graphene oxide (Ag@C/rGO and nano Ag/rGO) were used as the CDI electrodes. The nano Ag/rGO and Ag@C/rGO electrodes can reduce the charging resistant, and enhance the electrosorption capability. Better CDI efficiencies with the nano Ag/rGO and Ag@C/rGO electrodes can therefore be obtained. When reversed the voltage, the electrodes can be recovered up to 90% within 5 min. This work presents the feasibility for the nano Ag and Ag@C on rGO electrodes applied in CDI process to produce drinking water from seawater or saline water. PMID:24928455

  16. Ag nanotubes and Ag/AgCl electrodes in nanoporous membranes.

    PubMed

    Davenport, Matthew; Healy, Ken; Siwy, Zuzanna S

    2011-04-15

    Miniaturization of the entire experimental setup is a key requirement for widespread application of nanodevices. For nanopore biosensing, integrating electrodes onto the nanopore membrane and controlling the pore length is important for reducing the complexity and improving the sensitivity of the system. Here we present a method to achieve these goals, which relies on electroless plating to produce Ag nanotubes in track-etched polymer nanopore templates. By plating from one side only, we create a conductive nanotube that does not span the full length of the pore, and thus can act as a nanoelectrode located inside the nanopore. To give optimal electrochemical behavior for sensing, we coat the Ag nanotube with a layer of AgCl. We characterize the behavior of this nanoelectrode by measuring its current-voltage response and find that, in most cases, the response is asymmetric. The plated nanopores have initial diameters between 100 and 300 nm, thus a range suitable for detection of viruses. PMID:21389573

  17. Facile synthesis of S–Ag nanocomposites and Ag2S short nanorods by the interaction of sulfur with AgNO3 in PEG400

    NASA Astrophysics Data System (ADS)

    Zhang, Yan-Li; Xie, Xin-Yuan; Liang, Ming; Xie, Shu-Ming; Chen, Jie-Mei; Zheng, Wen-Jie

    2016-06-01

    A facile, eco-friendly and inexpensive method to prepare Ag2S short nanorods and S–Ag nanocomposites using sublimed sulfur, AgNO3, PVP and PEG400 was studied. According to x-ray diffraction and scanning electron microscopy of the Ag2S, the products are highly crystalline and pure Ag2S nanorods with diameters of 70–160 nm and lengths of 200–360 nm. X-ray diffraction of the S–Ag nanocomposites shows that we obtained cubic Ag and S nanoparticles. Transmission electron microscopy shows that the molar ratio of PVP to Ag+ plays an important role in controlling the size and morphology of the S–Ag nanocomposites. When the molar ratio of PVP to Ag+ was 10:1, smaller sizes, better dispersibility and narrower distribution of S–Ag nanocomposites with diameters of 10–40 nm were obtained. The formation mechanism of the S–Ag nanocomposites was studied by designing a series of experiments using ultraviolet–visible measurement, and it was found that S nanoparticles are produced first and act as seed crystals; then Ag+ becomes Ag nanocrystals on the surfaces of the S nanoparticles by the reduction of PVP. PEG400 acts as a catalyzer, accelerating the reaction rate, and protects the S–Ag nanocomposites from reacting to produce Ag2S. The antimicrobial experiments show that the S–Ag nanocomposites have greater antimicrobial activity on Staphylococcus aureus, Aspergillus niger and blue mold than Ag nanoparticles.

  18. Silver nanowire-carbon fiber cloth nanocomposites synthesized by UV curing adhesive for electrochemical point-of-use water disinfection.

    PubMed

    Hong, Xuesen; Wen, Junjie; Xiong, Xuhua; Hu, Yongyou

    2016-07-01

    Novel silver nanowire (AgNW) - carbon fiber cloth (CC) nanocomposites were synthesized by a rapid and facile method. Acting as filter in an electrical gravity filtration device, the AgNW-CC nanocomposites were applied to electrochemical point-of-use water disinfection. AgNW-CC nanocomposites were characterized by FESEM, XRD, and FTIR. Their disinfection performance toward Escherichia coli and bacteriophage MS2 was evaluated by inhibition zone tests, optical density growth curve tests, and flow tests. The results showed that complex 3D AgNW networks with controllable silver release (<100 ppb) were fabricated on CC by using UV curing adhesive. AgNW-CC nanocomposites exhibited excellent intrinsic antibacterial activities against E. coli. The concentration of AgNWs and UV adhesive controlled the released silver and hence led to the change in antibacterial activity. The external electric field significantly enhanced the disinfection efficiency of AgNW-CC nanocomposites. Over 99.999% removal of E. coli and MS2 could be achieved. More complex AgNW networks contributed to higher disinfection efficiency under 10 V and 10(6) CFU (PFU) mL(-1) of microorganism. UV adhesive could keep the disinfection performance from being affected by flow rate. The convenient synthesis and outstanding disinfection performance offer AgNW-CC nanocomposites opportunities in the application of electrochemical point-of-use drinking water disinfection. PMID:27085313

  19. Easy deposition of Ag onto polystyrene beads for developing surface-enhanced-Raman-scattering-based molecular sensors.

    PubMed

    Kim, Kwan; Lee, Hyang Bong; Park, Hyoung Kun; Shin, Kuan Soo

    2008-02-15

    We describe a very simple electroless plating method that can be used to prepare Ag-coated polystyrene beads. Robust Ag nanostructures are reproducibly fabricated by soaking polystyrene beads in ethanolic solutions of AgNO(3) and butylamine. When the molar ratio of butylamine to AgNO(3) is far below 1.0, distinct nanosized Ag particles are formed on the polystyrene beads, but by increasing the amount of butylamine, network-like Ag nanostructures are formed that possess very broad UV/vis absorption characteristics extending from the near-UV to near-infrared regions. In conformity with the UV/vis absorption characteristics, the Ag-deposited polystyrene beads were highly efficient surface-enhanced Raman scattering (SERS) substrates, with an enhancement factor estimated using 4-aminobenzenethiol (4-ABT) as a model adsorbate to be larger than 1.1x10(6). On the basis of the nature of the SERS peaks of 4-ABT, those Ag-deposited polystyrene beads were confirmed, after attaching biotin groups over 4-ABT, to selectively recognize streptavidin molecules down to concentrations of 10(-11) g mL(-1) (i.e., approximately 0.2 pM). Since a number of different molecules can be used as SERS-marker molecules (such as 4-ABT), multiple bioassays are readily accomplished via SERS after attaching appropriate host or guest molecules onto them. PMID:18001760

  20. UV irradiated PVA-Ag nanocomposites for optical applications

    NASA Astrophysics Data System (ADS)

    Chahal, Rishi Pal; Mahendia, Suman; Tomar, A. K.; Kumar, Shyam

    2015-07-01

    The present paper is focused on the in-situ prepared Poly (vinyl alcohol)-Silver (PVA-Ag) nanocomposites and tailoring their optical properties by means of UV irradiation in such a way that these can be used for anti-reflective coatings and bandpass filters. The reflectance from these irradiated nanocomposites has been found to decrease leading to the increase in refractive index (RI), with increasing UV exposure time, in the entire visible region. Decrease in optical energy gap of PVA film from 4.92 to 4.57 eV on doping with Ag nanoparticles has been observed which reduces further to 4.1 eV on exposure to UV radiations for 300 min. This decrease in optical energy gap can be correlated to the formation of charge transfer complexes within the base polymer network on embedding Ag nanoparticles, which further enhances with increasing exposure time. Such complexes may also be responsible for increased molecular density of the composite films which corresponds to decrease in reflectance corroborating the observed results.

  1. Acceleration of polarized proton at the AGS

    SciTech Connect

    Lee, Y Y

    1980-01-01

    The unexpected importance of high energy spin effects and the success of the ZGS in correcting many intrinsic and imperfection depolarizing resonances led us to attempt to accelerate polarized protons in the AGS. A collaborative effort is underway by the groups in Argonne, Michigan, Rice, Yale and Brookhaven to improve and modify the AGS to accelerate polarized protons. With the appropriate funding the first polarized proton acceleration at the AGS should be possible by 1983.

  2. The cardiovascular response to the AGS

    NASA Technical Reports Server (NTRS)

    Cardus, David; Mctaggart, Wesley G.

    1993-01-01

    This paper reports the preliminary results of experiments on human subjects conducted to study the cardiovascular response to various g-levels and exposure times using an artificial gravity simulator (AGS). The AGS is a short arm centrifuge consisting of a turntable, a traction system, a platform and four beds. Data collection hardware is part of the communication system. The AGS provides a steep acceleration gradient in subjects in the supine position.

  3. AgI/Ag{sub 3}PO{sub 4} hybrids with highly efficient visible-light driven photocatalytic activity

    SciTech Connect

    Katsumata, Hideyuki; Hayashi, Takahiro; Taniguchi, Masanao; Suzuki, Tohru; Kaneco, Satoshi

    2015-03-15

    Highlights: • AgI/Ag{sub 3}PO{sub 4} hybrid was prepared via an in situ anion-exchange method. • AgI/Ag{sub 3}PO{sub 4} displays the excellent photocatalytic activity under visible light. • AgI/Ag{sub 3}PO{sub 4} readily transforms to be Ag@AgI/Ag{sub 3}PO{sub 4} system. • h{sup +} and O{sub 2}{sup ·−} play the major role in the AO 7 decolorization over AgI/Ag{sub 3}PO{sub 4}. • The activity enhancement is ascribed to a Z-scheme system composed of Ag{sub 3}PO{sub 4}, Ag and AgI. - Abstract: Highly efficient visible-light-driven AgI/Ag{sub 3}PO{sub 4} hybrid photocatalysts with different mole ratios of AgI were prepared via an in situ anion-exchange method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) technique. Under visible light irradiation (>420 nm), the AgI/Ag{sub 3}PO{sub 4} photocatalysts displayed the higher photocatalytic activity than pure Ag{sub 3}PO{sub 4} and AgI for the decolorization of acid orange 7 (AO 7). Among the hybrid photocatalysts, AgI/Ag{sub 3}PO{sub 4} with 80% of AgI exhibited the highest photocatalytic activity for the decolorization of AO 7. X-ray photoelectron spectroscopy (XPS) results revealed that AgI/Ag{sub 3}PO{sub 4} readily transformed to be Ag@AgI/Ag{sub 3}PO{sub 4} system while the photocatalytic activity of AgI/Ag{sub 3}PO{sub 4} remained after 5 recycling runs. In addition, the quenching effects of different scavengers displayed that the reactive h{sup +} and O{sub 2}{sup ·−} play the major role in the AO 7 decolorization. The photocatalytic activity enhancement of AgI/Ag{sub 3}PO{sub 4} hybrids can be ascribed to the efficient separation of electron–hole pairs through a Z-scheme system composed of Ag{sub 3}PO{sub 4}, Ag and AgI, in which Ag nanoparticles act as the charge separation center.

  4. Active Structures in the Georgia Basin, NW Washington State, USA, and SW British Columbia, Canada

    NASA Astrophysics Data System (ADS)

    Polivka, P.; Riedel, M.; Pratt, T. L.

    2013-12-01

    interpreted from regional bedrock fault trends and shallow sediment deformation imaged on the 2002 SHIPS lines. (2) Kelsey et al. (2012, JGR) identified three subparallel NW-striking faults in NW Washington. We use the industry lines to constrain the subsurface geometries of these faults to >4 km depth. (3) Interpreting on-shore mapping, bathymetric bedrock ridges, and intersecting deep seismic profiles, we conclude that the E-K boundary is an angular unconformity across and along the length of the basin. (4) We correlate kinks in bathymetric bedrock ridges with bedrock folds on the intersecting SHIPS 1998 profile to re-interpret previously identified NE-trending 'secondary faults' as blind and broken-through fault-propagation folds. These faults are orthogonal to the subduction margin and collectively deemed the Vancouver Fold and Thrust Belt. The Gabriola Island earthquake indicates that the fault system is active, and likely accommodates at least part of the strain measured on GPS networks but not accounted for in previous tectonic models.

  5. SAR measurements of coastal features in the NW Mediterranean

    NASA Astrophysics Data System (ADS)

    Redondo, Jose M.; Martinez Benjamin, Juan Jose; Diez, Margarita; Lopez Gonzalez-Nieto, Pilar

    2013-04-01

    The Synthetic Aperture Radar (SAR) is a useful tool to study both marine water dynamics and its pollution, this is relevant near the coastline, where river pollution may be also important. Oil spills and natural slicks are detected with SAR [1-3] to reveal river and vessel pollution as well as the complex eddy and current interaction in the ocean surface near the coastline. In the framework of the ESA and European Union contracts, more than 1000 SAR images of the North-west Mediterranean Sea area taken between December 1996 and December 2008 are presented using self-similar traces that may be used to parametrize mixing at both limits of the Rossby Deformation Radius scale. Results show the ability to identify different SAR signatures and at the same time provide calibrations for the different local configurations of vortices, spirals, oil spills and tensioactive slicks that eventually allow predicting the behaviour of different tracers and pollutants in the NW Mediterranean Sea. Thanks to different polarization and intensity levels in satellite imagery can be used to distinguish between natural and man-made sea surface features due to their distinct self-similar as a function of spill parameters, environmental conditions and history of both oil release and weather conditions. (Environmental factors determine [4] spreading, drift and weathering of oil on the sea surface - see: Behaviour oil at sea). Detecting the low contrast patches depends also on the speckle noise which always presents in the image. Application of different filters (available for example in several image processing software (Matlab, Envi, IDL) to the radar data decreases noise level and improves the feature detecting in the image [1] Bezerra, M.O., Diez, M., Medeiros, C., Rodriguez, A., Bahia, E., Sanchez-Arcilla, A. and Redondo, J.M. 1998. Study on the influence of waves on coastal diffusion using image analysis. Applied Scientific Research 59, pp.191-204. [2] Carrillo, A., A., Sanchez,, M

  6. Submarine Explosive Eruptions: Physical Volcanology of NW Rota-1, Marianas

    NASA Astrophysics Data System (ADS)

    Deardorff, N. D.; Chadwick, W. W.; Embley, R. W.; Cashman, K. V.

    2006-12-01

    The discovery of an actively erupting submarine arc volcano is a scientific breakthrough that greatly extends our understanding of submarine volcanism. NW Rota-1, located at 14¢X40'N in the Mariana volcanic arc, is a conical basaltic andesite volcano with a summit at 517 m b.s.l, a base at 2700 m, and a diameter of 16- km. In April 2006, on the most recent cruise of the "Submarine Ring of Fire" (SROF) expeditions, violently explosive submarine eruptions were observed and sampled at the active vent, Brimstone Pit (550 m depth), through the use of JASON II remotely operated vehicle (ROV). During six dives repeated observations made at close range over a week documented a diverse and increasingly energetic range of activity that culminated in explosive bursts of glowing red lava propelled by violently expanding gases. Preliminary work shows erupted clasts to vary greatly in density (vesicularity) and crystallinity. Densities of representative larger clasts are moderately high (1700-1900 kg/m3, or ~ 30-40% vesicularity assuming a solid density of 2800 kg/m3; Fig 5b), although the more vigorous activity clearly produced some lower density (< 1000 kg/m3;> 66% vesicularity) material. Grain sizes were measured in 1.0 intervals from -5 to 3 using dry sieving techniques. The grain size distribution is approximately log normal with a mode at -1 (2 mm). Clast morphology consists of three components: (1) very glassy juveniles ranging from light to dark brown (sideromelane), often fluidal and irregularly shaped with obvious vesicle stretching, (2) phenocryst-rich blocky juveniles ranging from dark brown to black (tachylite), (3) non-juvenile lithics are equant, often rounded, ranging from light grey to dark grey and are often coated with altered material. Initial FTIR analyses show a lack of CO2 and a range of H20 from 0.3-1.15wt%, with the average approximately in equilibrium for 550 m water depth. The high vesicularity of the samples collected directly from Brimstone Pit and

  7. Short Communication: Reassessing the Origin of the HIV-1 CRF02_AG Lineages Circulating in Brazil.

    PubMed

    Delatorre, Edson; Velasco-De-Castro, Carlos A; Pilotto, José H; Couto-Fernandez, José Carlos; Bello, Gonzalo; Morgado, Mariza G

    2015-12-01

    HIV-1 CRF02_AG is responsible for at least 8% of the HIV-1 infections worldwide and is distributed mainly in West Africa. CRF02_AG has recently been reported in countries where it is not native, including Brazil. In a previous study including 10 CRF02_AG Brazilian samples, we found at least four independent introductions and two autochthonous transmission networks of this clade in Brazil. As more CRF02_AG samples have been identified in Brazil, we performed a new phylogeographic analysis using a larger dataset than before. A total of 20 Brazilian (18 from Rio de Janeiro and two from São Paulo) and 1,485 African HIV-1 CRF02_AG pol sequences were analyzed using maximum likelihood (ML). The ML tree showed that the Brazilian sequences were distributed in five different lineages. The Bayesian phylogeographic analysis of the Brazilian and their most closely related African sequences (n = 212) placed the origin of all Brazilian lineages in West Africa, probably Ghana, Senegal, and Nigeria. Two monophyletic clades were identified, comprising only sequences from Rio de Janeiro, and their date of origin was estimated at around 1985 (95% highest posterior density: 1979-1992). These results support the existence of at least five independent introductions of the CRF02_AG lineage from West Africa into Brazil and further indicate that at least two of these lineages have been locally disseminated in the Rio de Janeiro state over the past 30 years. PMID:26353079

  8. Visible-light-driven photocatalysts Ag/AgCl dispersed on mesoporous Al2O3 with enhanced photocatalytic performance.

    PubMed

    Feng, Zhouzhou; Yu, Jiajie; Sun, Dongping; Wang, Tianhe

    2016-10-15

    In this paper, Ag/AgCl and Ag/AgCl/Al2O3 photocatalysts were synthesized via a precipitation reaction between NaCl and CH3COOAg or Ag(NH3)2NO3, wherein Ag/AgCl was immobilized into mesoporous Al2O3 medium. The Ag/AgCl-based nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectra, and so on. The photocatalysts displayed excellent photocatalytic activity for the degradations of methyl orange (MO) and methylene blue (MB) pollutants under visible light irradiation. The Ag/AgCl(CH3COOAg)/Al2O3 sample exhibited the best photocatalytic performance, degrading 99% MO after 9min of irradiation, which was 1.1 times, 1.22 times and 1.65 times higher than that of Ag/AgCl(Ag(NH3)2NO3)/Al2O3, Ag/AgCl(CH3COOAg) and Ag/AgCl(Ag(NH3)2NO3) photocatalyst, respectively. Meanwhile, Ag/AgCl(CH3COOAg)/Al2O3 also showed excellent capability of MB degradation. Compared to the data reported for Ag/AgCl/TiO2, the Ag/AgCl/Al2O3 prepared in this work exhibited a good performance for the degradation of methyl orange (MO). The results suggest that the dispersion of Ag/AgCl on mesoporous Al2O3 strongly affected their photocatalytic activities. O2(-), OH radicals and Cl(0) atoms are main active species during photocatalysis. PMID:27442145

  9. Au-Ag polymetallic mineralization within tectonically weak zones along the southwestern edge of the Colorado Plateau

    SciTech Connect

    Wenrich, K.J.; Silberman, M.L. )

    1993-04-01

    The Music Mountain mining district lies at the base of the Grand Wash Cliffs, a major fault-line scarp along the Grand Wash fault, which marks the SW margin of the Colorado Plateau. Nearly vertical Au-Ag polymetallic quartz veins parallel, and are in contact with, altered diabase and granite porphyry dikes that cut Proterozoic granite, schist, and gneiss. The gold-bearing veins range in thickness from an inch to several feet and contain significant amounts of sulfide minerals. Diabase dikes and quartz veins in the district and to the north consistently strike N42[degree]W to N57[degree]W, which is one of the most prevalent fracture orientation throughout NW Arizona. In the Gold Basin-Lost Basin districts to the north, the Au occurs in such pegmatite-quartz veins that strike NE. Thirty miles east along Diamond Creek, quartz veins and diabase dikes strike N45[degree]E and are associated with Au and Ag anomalies in stream-sediments and panned concentrates. To the west major Au-Ag polymetallic quartz veins of the Wallapai mining district show consistent strikes from N30[degree] to 60[degree]W. K-Ar ages of hydrothermal alterations of 4 NW oriented diabase dikes that have quartz veins along them, range from 935 [+-] 35 to 755 [+-] 21 Ma. Sericite from altered granite porphyry, adjacent to a mineralized vein, gave a K-Ar age of 72 [+-]2 Ma. All geochemical sites (within a 1,000 mi[sup 2] area) determined to be anomalous in Au lie within 2 mi of either the Grand Wash or Hurricane faults. The Hurricane and Grand Wash faults, major Precambrian fault zones that were reactivated in the Phanerozoic, appear to be good exploration targets for Au-rich quartz veins associated with pegmatite or diabase dikes, many of which may be buried beneath the thick alluvium of Hualapai Valley.

  10. Multiple Partial Siberian Snakes in the AGS

    SciTech Connect

    Takano, J.; Ahrens, L. A.; Bai, M.; Brown, K.; Courant, E. D.; Gardner, C. J.; Glenn, J. W.; Huang, H.; Luccio, A. U.; MacKay, W. W.; Okamura, M.; Roser, T.; Tepikian, S.; Tsoupas, N.; Yip, K.; Zelenski, A.; Zeno, K.; Hattori, T.; Lin, F.

    2007-06-13

    Polarized protons are accelerated up to 24.3 GeV in the Alternating Gradient Synchrotron (AGS) at Brookhaven National Laboratory (BNL). To accelerate the beam with preserving the polarization, two different types of helical dipole partial Siberian snake have been installed to the AGS. One is a superconducting magnet (Cold Snake, CSNK), and the other is a normal conducting one (Warm Snake, WSNK). With these snake magnets, the polarization at the AGS extraction achieved 65%. However, the AGS has spin mismatches at the injection and extraction. This description shows calculated results to have better spin matching with using two or three snakes.

  11. Synthesis of Cu-Ag@Ag particles using hyperbranched polyester as template

    NASA Astrophysics Data System (ADS)

    Han, Wen-Song

    2015-07-01

    In this manuscript, the third-generation hyperbranched polyester was synthesized with 2, 2-dimethylol propionic acid as AB2 monomer and pentaerythrite as core molecule by using step by step polymerization process at first. Then, the Cu-Ag particles were prepared by co-reduction of silver nitrate and copper nitrate with ascorbic acid in the aqueous solution using hyperbranched polyester as template. Finally, the Cu-Ag@Ag particles were prepared by coating silver on the surface of Cu-Ag particles by reduction of silver nitrate. The synthesized hyperbranched polyester and Cu-Ag@Ag particles were characterized by Fourier transform infrared (FT-IR) spectroscopy, UV-vis spectra, x-ray diffraction, Laser light scattering, thermogravimetric analysis (TGA) and SEM. UV-vis spectra results showed that the Cu-Ag@Ag particles had a strong absorption band at around 420 nm. Laser light scattering and SEM studies confirmed that the most frequent particle sizes of Cu-Ag@Ag particles were 1.2 um. TGA results indicated that the Cu-Ag@Ag particles had good thermal stability. [Figure not available: see fulltext.

  12. Antibacterial action of Ag-containing MFI zeolite at low Ag loadings.

    PubMed

    Lalueza, Patricia; Monzón, Marta; Arruebo, Manuel; Santamaria, Jesus

    2011-01-14

    We show that Ag-containing zeolites are highly effective against Staphylococcus aureus (SA) bacteria even at low Ag loadings and in the presence of high (10(9) CFU per mL) bacterial concentrations. At short contact times the bactericidal efficiency correlates strongly with Ag(+) release. At longer times data dispersion is higher, probably as a consequence of bacterial metabolism. PMID:21103583

  13. 78 FR 30965 - AG Valley Railroad, LLC-Operation Exemption-Ag Valley Holdings, LLC

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-23

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF TRANSPORTATION Surface Transportation Board AG Valley Railroad, LLC--Operation Exemption--Ag Valley Holdings, LLC AG... original and 10 copies of all pleadings, referring to Docket No. FD 35736, must be filed with the...

  14. Progress with the AGS Booster

    SciTech Connect

    Weng, W.T.

    1988-01-01

    Rare K-decay, neutrino and heavy ion physics demands that a rapid- cycling high vacuum and high intensity Booster be built for the AGS at Brookhaven. For each mode of operation there are corresponding accelerator physics and design issues needing special attention. Problems pertinent to any single mode of operation have been encountered and solved before, but putting high intensity proton requirements and high vacuum heavy ion requirements into one machine demands careful design considerations and decisions. The lattice design and magnet characteristics will be briefly reviewed. Major design issues will be discussed and design choices explained. Finally, the construction status and schedule will be presented. 6 refs., 6 figs.

  15. Polarization preservation in the AGS

    SciTech Connect

    Ratner, L.G.

    1983-01-01

    The successful operation of a high energy polarized beam at the Argonne Zero Gradient Synchrotron (ZGS) with the concommitant development of depolarizing resonance correction techniques has led to the present project of commissioning such a beam at the Brookhaven Alternating Gradient Synchrotron (AGS). A description of the project was presented at the 1981 National Accelerator Conference. I would like to now present a more detailed description of how we plan to preserve the polarization during acceleration, and to present our game plan for tuning through some 50 resonances and reaching our goal of a 26 GeV polarized proton beam with greater than 60% polarization.

  16. Hypernuclear research at the AGS

    SciTech Connect

    Chrien, R.E.

    1984-01-01

    Although the field of hypernuclear research is over 30 years old, progress in exploring the detailed behavior of hypernuclei has been slow. This fact is due mainly to the technical problems of producing and studying these strange objects. Indeed each step in the improvement of technique has been accompanied by a breakthrough in our understanding of this fascinating subject. In this paper, the aim is to describe the evolution of hypernuclear research, stressing especially the contributions of the program based on the Brookhaven AGS. 23 references, 17 figures, 1 table.

  17. New AGS fast extraction system

    SciTech Connect

    Weng, W.T.

    1980-09-01

    Both the high energy physics program and ISA injection require an improved fast extraction system from the AGS. The proposed new system consists of a fast kicker at H5 and an ejector magnet at H10. The H5 kicker is capable of producing 1.2 mrad deflection and rising up to 99% strength in 150 nsec with flat top ripple within +- 1%. It is found that the focusing strengths and positions of UQ3-UQ7 have to be modified to achieve an achromatic condition at the end of 8/sup 0/-bend. Also, the conceptual design of the H5 magnet and the pulser system are discussed.

  18. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer

    2013-07-15

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with μ{sub eff}=7.87(1) μ{sub B}/Eu atom and θ{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of −9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  19. Toxicokinetics of Ag in the terrestrial isopod Porcellionides pruinosus exposed to Ag NPs and AgNO₃ via soil and food.

    PubMed

    Tourinho, Paula S; van Gestel, Cornelis A M; Morgan, A John; Kille, Peter; Svendsen, Claus; Jurkschat, Kerstin; Mosselmans, J Fred W; Soares, Amadeu M V M; Loureiro, Susana

    2016-03-01

    Silver nanoparticles (Ag NPs) have been used in numerous consumer products and may enter the soil through the land application of biosolids. However, little is known about the relationship between Ag NP exposure and their bioavailability for soil organisms. This study aims at comparing the uptake and elimination kinetics of Ag upon exposures to different Ag forms (NPs and ionic Ag (as AgNO3)) in the isopod Porcellionides pruinosus. Isopods were exposed to contaminated Lufa 2.2 soil or alder leaves as food. Uptake and elimination rate constants for soil exposure did not significantly differ between Ag NPs and ionic Ag at 30 and 60 mg Ag/kg. For dietary exposure, the uptake rate constant was up to 5 times higher for Ag NPs than for AgNO3, but this was related to feeding activity and exposure concentrations, while no difference in the elimination rate constants was found. When comparing both routes, dietary exposure resulted in lower Ag uptake rate constants but elimination rate constants did not differ. A fast Ag uptake was observed from both routes and most of the Ag taken up seemed not to be eliminated. Synchrotron X-ray fluorescence showed Ag in the S-cells of the hepatopancreas, thus supporting the observations from the kinetic experiment (i.e. low elimination). In addition, our results show that isopods have an extremely high Ag accumulation capacity, suggesting the presence of an efficient Ag storage compartment. PMID:26581474

  20. Negligible shift of 3Ag- potential in longer-chain carotenoids as revealed by a single persistent peak of 3Ag-→1Ag- stimulated emission followed by 3Ag-←1Ag- transient-absorption

    NASA Astrophysics Data System (ADS)

    Li, Chunyong; Miki, Takeshi; Kakitani, Yoshinori; Koyama, Yasushi; Nagae, Hiroyoshi

    2007-12-01

    Upon excitation of lycopene, anhydrorhodovibrin or spirilloxanthin to the 1Bu+(0) state, stimulated emission followed by transient-absorption was observed as a single peak with the 3Ag-(0) energy that had been determined by measurement of resonance-Raman excitation profiles. This observation was explained in terms of negligible shift of the 3Ag- potential, in reference to the 1Ag- potential, where only the 3Ag-(υ)→1Ag-(υ) emission and the 3Ag-(υ)←1Ag-(υ) absorption become allowed during the vibrational relaxation of υ = 2 → 1 → 0, starting from the 3Ag-(2) level generated by diabatic internal conversion from the 1Bu+(0) level, in anhydrorhodovibrin, for example.

  1. Late Miocene Rise of C4 Vegetation in NW Africa from Leaf Wax Biomarkers

    NASA Astrophysics Data System (ADS)

    Rose, C. A.; deMenocal, P. B.; Polissar, P. J.

    2014-12-01

    When and why did NW Africa become dry? The answers to these important questions have proven elusive. Strong climate controls on African vegetation today make knowledge of past changes a valuable proxy for understanding NW Africa's climate evolution. Various lines of geologic and paleobotanical evidence indicate that NW African landscapes changed from more humid conditions in the late Oligocene/early Miocene to arid/hyper-arid environments by the late Pliocene. As proxies for the paleohydrological and paleovegetation signatures of this event, we analyzed leaf wax n-alkane stable isotopes (δDwax and δ13Cwax) at Ocean Drilling Program Site 659 (20°N), offshore West Africa, from 0 - 25 Ma. Between 25 to 10 Ma, n-alkane δ13Cwax values were persistently very low (-31‰) suggesting that C3 vegetation dominated NW African landscapes over this interval. Between 10-7 Ma there is a marked, positive secular δ13Cwax shift (in excess of 4‰) suggesting the initial growth and establishment of C4 Sahel grasslands. δ13Cwax shows a sustained positive trend (>7‰ total) until 1 Ma. The 10-7 Ma date for the establishment of NW African C4 grasslands is earlier than comparable records from South Africa and South Asia. We will also present low-resolution isotope data from equatorial ODP Site 959 (3°N) and compare these data with Site 659 (20°N) to reconstruct the development of the modern vegetation and hydrological gradients in NW Africa over this time span.

  2. Fate of zinc and silver engineered nanoparticles in sewerage networks.

    PubMed

    Brunetti, Gianluca; Donner, Erica; Laera, Giuseppe; Sekine, Ryo; Scheckel, Kirk G; Khaksar, Maryam; Vasilev, Krasimir; De Mastro, Giuseppe; Lombi, Enzo

    2015-06-15

    Engineered zinc oxide (ZnO) and silver (Ag) nanoparticles (NPs) used in consumer products are largely released into the environment through the wastewater stream. Limited information is available regarding the transformations they undergo during their transit through sewerage systems before reaching wastewater treatment plants. To address this knowledge gap, laboratory-scale systems fed with raw wastewater were used to evaluate the transformation of ZnO- and Ag-NPs within sewerage transfer networks. Two experimental systems were established and spiked with either Ag- and ZnO-NPs or with their dissolved salts, and the wastewater influent and effluent samples from both systems were thoroughly characterised. X-ray absorption spectroscopy (XAS) was used to assess the extent of the chemical transformation of both forms of Zn and Ag during transport through the model systems. The results indicated that both ZnO- and Ag-NPs underwent significant transformation during their transport through the sewerage network. Reduced sulphur species represented the most important endpoint for these NPs in the sewer with slight differences in terms of speciation; ZnO converted largely to Zn sulfide, while Ag was also sorbed to cysteine and histidine. Importantly, both ionic Ag and Ag-NPs formed secondary Ag sulfide nanoparticles in the sewerage network as revealed by TEM analysis. Ag-cysteine was also shown to be a major species in biofilms. These results were verified in the field using recently developed nanoparticle in situ deployment devices (nIDDs) which were exposed directly to sewerage network conditions by immersing them into a municipal wastewater network trunk sewer and then retrieving them for XAS analysis. PMID:25841090

  3. Zero-bias photocurrents in highly-disordered networks of Ge and Si nanowires

    NASA Astrophysics Data System (ADS)

    Rabbani, M. Golam; Patil, Sunil R.; Verma, Amit; Villarreal, Julian E.; Korgel, Brian A.; Nekovei, Reza; Khader, Mahmoud M.; Darling, R. B.; Anantram, M. P.

    2016-01-01

    Semiconducting nanowire (NW) devices have garnered attention in self-powered electronic and optoelectronic applications. This work explores and exhibits, for the first time for visible light, clear evidence of the zero-biased optoelectronic switching in randomly dispersed Ge and Si NW networks. The test bench, on which the NWs were dispersed for optoelectronic characterization, was fabricated using a standard CMOS fabrication process, and utilized metal contacts with dissimilar work functions—Al and Ni. The randomly dispersed NWs respond to light by exhibiting substantial photocurrents and, most remarkably, demonstrate zero-bias photo-switching. The magnitude of the photocurrent is dependent on the NW material, as well as the channel length. The photocurrent in randomly dispersed GeNWs was found to be higher by orders of magnitude compared to SiNWs. In both of these material systems, when the length of the NWs was comparable to the channel length, the currents in sparse NW networks were found to be higher than those in dense NW networks, which can be explained by considering various possible arrangements of NWs in these devices.

  4. Groundwater hydrochemistry evolution in cyclone driven hydrological regimes, NW Australia

    NASA Astrophysics Data System (ADS)

    Skrzypek, G.; Dogramaci, S.; Grierson, P.

    2013-12-01

    Groundwater reserves supply the water needs of many arid regions around the world. Aquifer recharge in these regions is primarily depended on the amount and distribution of rainfall, coupled with exceedingly high rates of evaporation and interactions with both local and regional geomorphology and geology. In semi-arid northwest Australia, the majority of rainfall is delivered by large but infrequent cyclonic events and relatively more frequent but low intensity frontal systems. Changes to rainfall patterns due to global climate change may impact hydrological regimes, recharge rates and groundwater hydrochemistry. These changes may significantly restrict freshwater resources in the future. Between 2008 and 2012, we analysed >400 groundwater, surface and rainwater samples for stable isotope composition (δ2H and δ18O) and major ion chemistry. We then developed conceptual geochemical models of groundwater evolution for the Hamersley Basin (>100,000 km2) and a salt inventory for the Fortescue Marsh (the largest wetland in NW Australia) [1,2]. Fresh groundwater from the alluvium (-8.02 × 0.83‰) and fractured aquifers (-8.22 × 0.70‰) were hydrochemically similar and characterised by a very narrow range of δ18O [1]. In contrast, δ18O of saline and brine groundwater (TDS >10 g L-1) varies in wide range from +2.5 to -7.2‰ [2]. Most of the fresh and brackish groundwater reflects modern recharge and is evaporated by <20% prior to recharge. In contrast, highly saline and brine groundwater reflects mixing between modern rainfall, brackish water and older deep groundwater. The Fortescue Marsh primarily acts as a terminal basin for surface water from the upper Fortescue River catchment [2]. The stable isotope composition of the deep brine groundwater under the Marsh suggests a complex evolution, which cannot be explained by evaporation under current climatic conditions. The observed salinity and δ18O values may result from progressive evaporation from highly saline

  5. Fluvial sensitivity to Late Quaternary climate changes in NW Romania

    NASA Astrophysics Data System (ADS)

    Perşoiu, Ioana; Rădoane, Maria; Robu, Delia; Tanţău, Ioan

    2013-04-01

    Fluvial archives became increasingly important for the reconstruction of past environments, as they record a sum of climate, vegetation, hydrologic and anthropic changes. This is especially important for the Late Quaternary, when climate and human activities had recorded large spatial and temporal variations. Here we present a tale of fluvial behavior during the last ca. 24.000 years in NW Romania, based on 1) absolute ages and fluvial architecture of sediments exposed in 8 openings located along the Someşu Mic River, and 2) depth-age models, grain size, LOI and gastropods assemblage analysis on 2 cores located upstream from Ştiucilor Lake, a natural lake along a small tributary of the Someşu Mic River, formed by salt disolution on top of a narrow diapiric anticline. During the Late Glacial (LG), Ştiucilor Lake was more extended then is today, with a high input of coarse materials (sands) from the slopes; and dramatically reducing its size in the Early Holocene, a transition marked by the abrupt occurrence of Holocene gyttja on top of LG sands, 1 km upstream from the present lake. Further upstream, at ca. 4 km from the present day edge of the lake, clays and sandy clays were deposited during the Bolling - Allerod (BA), followed by fine - medium sands of Younger Dryas (YD) age. On top of these sands, clays, sandy clays and gyttja occur, suggesting a returning to a less energetic sedimentary environment in the Holocene. In both cores, the sediments become lacustrine, with clays and fine sands, attesting the expansion of the lake's surface, followed by large fluctuations during the Holocene. The river fed by this stream - Someşu Mic, was a coarse gravel, shallow braided river before the Last Glacial Maximum and until the YD. The channel metamorphosis into a narrow, incised, meandering one, occurred ca. 1500 years after the beginning of the Holocene. However, sedimentological evidences suggest that this transition from braided to meandering channel was not a

  6. Visible light driven photocatalysis and antibacterial activity of AgVO{sub 3} and Ag/AgVO{sub 3} nanowires

    SciTech Connect

    Singh, Anamika; Dutta, Dimple P.; Ballal, A.; Tyagi, A.K.; Fulekar, M.H.

    2014-03-01

    Graphical abstract: - Highlights: • Ag/AgVO{sub 3} and pure AgVO{sub 3} nanowires synthesized by sonochemical process. • Characterization done using XRD, SEM, TEM, EDX and BET analysis. • Visible light degradation of RhB by Ag/AgVO{sub 3} within 45 min. • Antibacterial activity of Ag/AgVO{sub 3} demonstrated. - Abstract: Ag/AgVO{sub 3} nanowires and AgVO{sub 3} nanorods were synthesized in aqueous media via a facile sonochemical route. The as-synthesized products were characterized by X-ray diffraction, Brunauer–Emmett–Teller surface area analysis, scanning electron microscopy together with an energy dispersion X-ray spectrum analysis, transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The results revealed that inert atmosphere promotes the formation of Ag/AgVO{sub 3} nanowires. The photocatalytic studies revealed that the Ag/AgVO{sub 3} nanowires exhibited complete photocatalytic degradation of Rhodamine B within 45 min under visible light irradiation. The antibacterial activity of Ag/AgVO{sub 3} nanowires was tested against Escherechia coli and Bacillus subtilis. The minimum growth inhibitory concentration value was found to be 50 and 10 folds lower than for the antibiotic ciprofloxacin for E. coli and B. subtilis, respectively. The antibacterial properties of the β-AgVO{sub 3} nanorods prove that in case of the Ag dispersed Ag/AgVO{sub 3} nanowires, the enhanced antibacterial action is also due to contribution from the AgVO{sub 3} support.

  7. The AGS synchrotron with four helical magnets

    SciTech Connect

    Tsoupas N.; Huang, H.; Roser, T.; MacKay, W.W.; Trbojevic, D.

    2012-05-20

    The idea of using two partial helical magnets was applied successfully to the AGS synchrotron to preserve the proton beam polarization. In this paper we explore in details the idea of using four helical magnets placed symmetrically in the AGS ring. The placement of four helical magnets in the AGS ring provides many advantages over the present setup of the AGS which uses two partial helical magnets. First, the symmetric placement of the four helical magnets allows for a better control of the AGS optics with reduced values of the beta functions especially near beam injection, second, the vertical spin direction during beam injection and extraction is closer to vertical, and third, it provides for a larger 'spin tune gap', which allows the vertical and horizontal tunes to be placed, and prevent the horizontal and vertical intrinsic spin resonances of the AGS to occur during the acceleration cycle. Although the same spin gap can be obtained with a single or two partial helices, the required high field strength of a single helix makes its use impractical, and that of the double helix rather difficult. In this paper we will provide results on the spin tune and on the optics of the AGS with four partial helical magnets, and compare these results with the present setup of the AGS that uses two partial helical magnets.

  8. Acceleration of heavy ions in the AGS

    SciTech Connect

    Barton, M.Q.

    1983-01-01

    It is possible to use the Brookhaven AGS as a heavy ion machine by adding a cyclotron to the Tandem and using this combination as injector. An intermediate step for lighter ions might consist of injecting the Tandem beam directly into the AGS. In either case, quite high intensities should be possible.

  9. Tribological properties of ag-based amphiphiles

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Most ag-based materials are amphiphilic because they comprise polar and non-polar groups within the same molecule. One of the major categories of amphiphilic ag-based materials are seed oils, which are actively investigated as substitutes for petroleum in a wide variety of consumer and industrial a...

  10. AgRISTARS documents tracking list report

    NASA Technical Reports Server (NTRS)

    Hawkins, J. L.

    1983-01-01

    A quarterly listing of documents issued and placed in the AgRISTARS tracking system is provided. The technical publications are arranged by type of documents. The reference AgRISTARS document number, title and date of publication, the issuing organization, and the National Technical Information Service reference number is given.

  11. Recent hypernuclear research at the Brookhaven AGS

    SciTech Connect

    Chrien, R.E.

    1985-01-01

    Recent AGS experiments contributing to our knowledge of hypernuclei are reviewed. These experiments have suggested new areas of research on hypernuclei. With the proper beam line facilities, the AGS will be able to perform experiments in these areas and provide a transition to the future era of ''kaon factories''. 20 refs., 14 figs.

  12. Effects of soil and dietary exposures to Ag nanoparticles and AgNO₃ in the terrestrial isopod Porcellionides pruinosus.

    PubMed

    Tourinho, Paula S; van Gestel, Cornelis A M; Jurkschat, Kerstin; Soares, Amadeu M V M; Loureiro, Susana

    2015-10-01

    The effects of Ag-NPs and AgNO3 on the isopod Porcellionides pruinosus were determined upon soil and dietary exposures. Isopods avoided Ag in soil, with EC50 values of ∼16.0 and 14.0 mg Ag/kg for Ag-NPs and AgNO3, respectively. Feeding inhibition tests in soil showed EC50s for effects on consumption ratio of 127 and 56.7 mg Ag/kg, respectively. Although similar EC50s for effects on biomass were observed for nanoparticulate and ionic Ag (114 and 120 mg Ag/kg dry soil, respectively), at higher concentrations greater biomass loss was found for AgNO3. Upon dietary exposure, AgNO3 was more toxic, with EC50 for effects on biomass change being >1500 and 233 mg Ag/kg for Ag-NPs and AgNO3, respectively. The difference in toxicity between Ag-NPs and AgNO3 could not be explained from Ag body concentrations. This suggests that the relation between toxicity and bioavailability of Ag-NPs differs from that of ionic Ag in soils. PMID:26071943

  13. Laser generated Ag and Ag-Au composite nanoparticles for refractive index sensor

    NASA Astrophysics Data System (ADS)

    Navas, M. P.; Soni, R. K.

    2014-09-01

    Localized surface plasmon resonance (LSPR) wavelength of metal nanoparticles (NPs) is highly sensitive to size, shape and the surrounding medium. Metal targets were laser ablated in liquid for preparation of spherical Ag and Ag@Au core-shell NP colloidal solution for refractive index sensing. The LSPR peak wavelength and broadening of the NPs were monitored in different refractive index liquid. Quasi-static Mie theory simulation results show that refractive index sensitivity of Ag, Ag-Au alloy and Ag@Au core-shell NPs increases nearly linearly with size and shell thickness. However, the increased broadening of the LSPR peak with size, alloy concentration and Au shell thickness restricts the sensing resolution of these NPs. Figure-of-merit (FOM) was calculated to optimize the size of Ag NPs, concentration of Ag-Au alloy NPs and Au shell thickness of Ag@Au core-shell NPs. The refractive index sensitivity (RIS) and FOM were optimum in the size range 20-40 nm for Ag NPs. Laser generated Ag@Au NPs of Au shell thickness in the range of 1-2 nm showed optimum FOM, where thin layer of Au coating can improve the stability of Ag NPs.

  14. A multidisciplinary geomatics approach to morphometric and morphotectonic analysis of the Cannobino Basin (Piemonte Region, NW-Italy).

    NASA Astrophysics Data System (ADS)

    Bacenetti, Marco; Ghiraldi, Luca; Giardino, Marco

    2014-05-01

    The paper presents an integrated multidisciplinary approach to the morphometric and morphotectonic characterization of the Cannobino Basin (Piemonte Region, NW-Italy). The basin is drained by the Cannobino river; in its first 8 km, it flows SE to NW along a wide valley characterized by glacial landforms; thereafter it suddenly turns South assuming a W to E direction, by flowing in a deeply entrenched valley to the intermontane basin of the Maggiore Lake. This area belongs to the Lepontine Alps, which from the geological point of view belong to the Southern Alps. His Hercynian basement is divided in two units: Ivrea-Verbano Zone (IVZ) and Serie dei Laghi (SDL). The IVZ outcrops in the northern sector of the basin, while the SDL outcrops in the southern and central sector. They separated by the Cossato-Mergozzo-Brissago (CMB) and Pogallo lines (PL). These major discontinuities and the neoctonic activity of their shear zones possibly control Quaternary evolution of the alpine relief. Detailed studies of the area are needed for understanding possible interactions of neotectonic activity, fluvial/glacial erosional/depositional processes and slope dynamics. Our focus is on drainage basin characteristics and its evolutionary stages in response to local and regional base level changes and to differential rock uplift. GIS methodologies combined with DEMs analyses are among the most common geomatics approaches to geomorphology. Based on this framework, an evaluation of the geomorphometric characteristic of the Cannobino Basin has been carried out by using an aerial LIDAR DEM (5x5 meters, Regione Piemonte, 2009). The workflow followed for calculating the geomorphic indexes can be summarized in different steps: i) drainage network extraction and hierarchization; ii) lineament features digitalization and interpretation; iii) azimuthal distribution of drainage pattern; iv) DEM analysis and evaluation of linear, areal indexes and SWAT profile. The multidisciplinary and innovative

  15. Raman scattering enhanced within the plasmonic gap between an isolated Ag triangular nanoplate and Ag film.

    PubMed

    Li, Kuanguo; Jiang, Kang; Zhang, Lan; Wang, Yong; Mao, Lei; Zeng, Jie; Lu, Yonghua; Wang, Pei

    2016-04-22

    Enhanced electromagnetic field in the tiny gaps between metallic nanostructures holds great promise in optical applications. Herein, we report novel out-of-plane nanogaps composed of micrometer-sized Ag triangular nanoplates (AgTN) on Ag films. Notably, the new coupled plasmonic structure can dramatically enhance the surface-enhanced Raman scattering (SERS) by visible laser excitation, although the micrometer-sized AgTN has localized plasmon resonance at infrared wavelength. This enhancement is derived from the gap plasmon polariton between the AgTN and Ag film, which is excited via the antenna effect of the corner and edge of the AgTN. Systematic SERS studies indicated that the plasmon enhancement was on the order of corner > edge > face. These results were further verified by theoretical simulations. Our device paves the way for rational design of sensitive SERS substrates by judiciously choosing appropriate nanoparticles and optimizing the gap distance. PMID:26939539

  16. Raman scattering enhanced within the plasmonic gap between an isolated Ag triangular nanoplate and Ag film

    NASA Astrophysics Data System (ADS)

    Li, Kuanguo; Jiang, Kang; Zhang, Lan; Wang, Yong; Mao, Lei; Zeng, Jie; Lu, Yonghua; Wang, Pei

    2016-04-01

    Enhanced electromagnetic field in the tiny gaps between metallic nanostructures holds great promise in optical applications. Herein, we report novel out-of-plane nanogaps composed of micrometer-sized Ag triangular nanoplates (AgTN) on Ag films. Notably, the new coupled plasmonic structure can dramatically enhance the surface-enhanced Raman scattering (SERS) by visible laser excitation, although the micrometer-sized AgTN has localized plasmon resonance at infrared wavelength. This enhancement is derived from the gap plasmon polariton between the AgTN and Ag film, which is excited via the antenna effect of the corner and edge of the AgTN. Systematic SERS studies indicated that the plasmon enhancement was on the order of corner > edge > face. These results were further verified by theoretical simulations. Our device paves the way for rational design of sensitive SERS substrates by judiciously choosing appropriate nanoparticles and optimizing the gap distance.

  17. Fabrication and characterization of AgI/Ag hollow fibers for near-infrared lasers

    NASA Astrophysics Data System (ADS)

    Zeng, Xuan; Liu, Bing-Hong; He, Yu-Jing; Sun, Bang-Shan; Iwai, Katsumasa; Miyagi, Mitsunobu; Shi, Yi-Wei

    2013-07-01

    AgI/Ag hollow fibers have found applications in mid- and far-infrared regions owing to the properties of low loss and high power capability. It has been a challenge to fabricate low-loss AgI/Ag hollow fiber in the near-infrared laser light. In this paper, we report on improvements of the fabrication technology. In order to coat a thin and smooth AgI film, ethanol was used as the solvent of iodine and the iodination process is carried out in low temperatures with high flow-rate of iodine solution. Low-loss AgI/Ag hollow fibers with various inner diameters were firstly obtained for 1 μm wavelength band. Fabrication parameters were discussed in detail and transmission properties were characterized.

  18. Atomic-level observation of Ag-ion hopping motion in AgI

    NASA Astrophysics Data System (ADS)

    Sato, W.; Komatsuda, S.; Mizuuchi, R.; Irioka, N.; Kawata, S.; Ohkubo, Y.

    2015-04-01

    Applicability of the 111mCd(→111Cd) and 111In(→111Cd) probes to the study of dynamics in polycrystalline silver iodide (AgI) was examined by means of the time-differential perturbed angular correlation technique. It was found that the 111mCd(→111Cd) probe occupies a unique site in γ-AgI and exhibits nuclear relaxation caused by dynamic perturbation arising from Ag + hopping motion in α-AgI; while the residential sites of 111In(→111Cd) vary, suggesting that 111In ions can not settle themselves in a fixed site in the AgI crystal structure. We here demonstrate that 111mCd(→111Cd) can be a potential nucleus to probe the Ag +-ion dynamic motion in α-AgI.

  19. Studies on electronic structure of interfaces between Ag and gelatin for stabilization of Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Tani, Tadaaki; Uchida, Takayuki

    2015-06-01

    Extremely high stability of Ag nanoparticles in photographic materials has forced us to study the electronic structures of the interfaces between thin layers of Ag, Au, and Pt and their surface membranes in ambient atmosphere by photoelectron yield spectroscopy in air and Kelvin probe method. Owing to the Fermi level equalization between a metal layer and a membrane coming from air, the electron transfer took place from the membrane to Pt and Au layers and from an Ag layer to the membrane, giving the reason for poor stability of Ag nanoparticles in air. The control of the Fermi level of an Ag layer with respect to that of a gelatin membrane in air could be widely made according to Nernst’s equation by changing the pH and pAg values of an aqueous gelatin solution used to form the membrane, and thus available to stabilize Ag nanoparticles in a gelatin matrix.

  20. AgPO2F2 and Ag9(PO2F2)14: the first Ag(i) and Ag(i)/Ag(ii) difluorophosphates with complex crystal structures.

    PubMed

    Malinowski, Przemysław J; Kurzydłowski, Dominik; Grochala, Wojciech

    2015-12-01

    The reaction of AgF2 with P2O3F4 yields a mixed valence Ag(I)/Ag(II) difluorophosphate salt with AgAg(PO2F2)14 stoichiometry - the first Ag(ii)-PO2F2 system known. This highly moisture sensitive brown solid is thermally stable up to 120 °C, which points at further feasible extension of the chemistry of Ag(ii)-PO2F2 systems. The crystal structure shows a very complex bonding pattern, comprising of polymeric Ag(PO2F2)14(4-) anions and two types of Ag(I) cations. One particular Ag(II) site present in the crystal structure of Ag9(PO2F2)14 is the first known example of square pyramidal penta-coordinated Ag(ii) in an oxo-ligand environment. Ag(i)PO2F2 - the product of the thermal decomposition of Ag9(PO2F2)14 - has also been characterized by thermal analysis, IR spectroscopy and X-ray powder diffraction. It has a complicated crystal structure as well, which consists of infinite 1D [Ag(I)O4/2] chains which are linked to more complex 3D structures via OPO bridges. The PO2F2(-) anions bind to cations in both compounds as bidentate oxo-ligands. The terminal F atoms tend to point inside the van der Waals cavities in the crystal structure of both compounds. All important structural details of both title compounds were corroborated by DFT calculations. PMID:26200921

  1. Manipulation resolves non-trivial structure of corrole monolayer on Ag(111).

    PubMed

    Tebi, Stefano; Aldahhak, Hazem; Serrano, Giulia; Schöfberger, Wolfgang; Rauls, Eva; Schmidt, Wolf Gero; Koch, Reinhold; Müllegger, Stefan

    2016-01-15

    Non-trivial arrangement of molecules within a molecular network complicates structure determination due to interdigitation, partial overlap, or stacking. We demonstrate that combined imaging and lateral manipulation with a scanning tunneling microscope resolves the intricate structure of a molecular network in two-dimensions in a straightforward manner. The network, formed by a monolayer of 5,10,15-tris(pentafluorophenyl)-corrole molecules on Ag(111), is manipulated for the first time with single-molecule precision. Our results reveal a shingle-like packing of partially overlapping corrole molecules. Density functional theory calculations support our findings. PMID:26629708

  2. Manipulation resolves non-trivial structure of corrole monolayer on Ag(111)

    NASA Astrophysics Data System (ADS)

    Tebi, Stefano; Aldahhak, Hazem; Serrano, Giulia; Schöfberger, Wolfgang; Rauls, Eva; Gero Schmidt, Wolf; Koch, Reinhold; Müllegger, Stefan

    2016-01-01

    Non-trivial arrangement of molecules within a molecular network complicates structure determination due to interdigitation, partial overlap, or stacking. We demonstrate that combined imaging and lateral manipulation with a scanning tunneling microscope resolves the intricate structure of a molecular network in two-dimensions in a straightforward manner. The network, formed by a monolayer of 5,10,15-tris(pentafluorophenyl)-corrole molecules on Ag(111), is manipulated for the first time with single-molecule precision. Our results reveal a shingle-like packing of partially overlapping corrole molecules. Density functional theory calculations support our findings.

  3. Antibacterial biodegradable Mg-Ag alloys.

    PubMed

    Tie, D; Feyerabend, F; Müller, W D; Schade, R; Liefeith, K; Kainer, K U; Willumeit, R

    2013-01-01

    The use of magnesium alloys as degradable metals for biomedical applications is a topic of ongoing research and the demand for multifunctional materials is increasing. Hence, binary Mg-Ag alloys were designed as implant materials to combine the favourable properties of magnesium with the well-known antibacterial property of silver. In this study, three Mg-Ag alloys, Mg2Ag, Mg4Ag and Mg6Ag that contain 1.87 %, 3.82 % and 6.00 % silver by weight, respectively, were cast and processed with solution (T4) and aging (T6) heat treatment. The metallurgical analysis and phase identification showed that all alloys contained Mg4Ag as the dominant β phase. After heat treatment, the mechanical properties of all Mg-Ag alloys were significantly improved and the corrosion rate was also significantly reduced, due to presence of silver. Mg(OH)₂ and MgO present the main magnesium corrosion products, while AgCl was found as the corresponding primary silver corrosion product. Immersion tests, under cell culture conditions, demonstrated that the silver content did not significantly shift the pH and magnesium ion release. In vitro tests, with both primary osteoblasts and cell lines (MG63, RAW 264.7), revealed that Mg-Ag alloys show negligible cytotoxicity and sound cytocompatibility. Antibacterial assays, performed in a dynamic bioreactor system, proved that the alloys reduce the viability of two common pathogenic bacteria, Staphylococcus aureus (DSMZ 20231) and Staphylococcus epidermidis (DSMZ 3269), and the results showed that the killing rate of the alloys against tested bacteria exceeded 90%. In summary, biodegradable Mg-Ag alloys are cytocompatible materials with adjustable mechanical and corrosion properties and show promising antibacterial activity, which indicates their potential as antibacterial biodegradable implant materials. PMID:23771512

  4. Geology and geochemistry of the shear-hosted Julie gold deposit, NW Ghana

    NASA Astrophysics Data System (ADS)

    Amponsah, Prince Ofori; Salvi, Stefano; Béziat, Didier; Siebenaller, Luc; Baratoux, Lenka; Jessell, Mark W.

    2015-12-01

    The Leo Man Craton in West Africa is host to numerous economic gold deposits. If some regions, such as the SW of Ghana, are well known for world-class mineralizations and have been extensively studied, gold occurrences elsewhere in the craton have been discovered only in the last half a century or so, and very little is known about them. The Julie gold deposit, located in the Paleoproterozoic Birimian terrane of NW Ghana, is one such case. This deposit is hosted in a series of granitoid intrusives of TTG composition, and consists of a network of deformed, boudinaged quartz lodes (A-type veins) contained within an early DJ1 E-W trending shear zone with dextral characteristics. A conjugate set of veins (C-type) perpendicular to the A-type veins contains low grade mineralization. The main ore zone defines a lenticular corridor about 20-50 m in width and about 3.5 km along strike, trending E-W and dipping between 30 and 60°N. The corridor is strongly altered, by an assemblage of sericite + quartz + ankerite + calcite + tourmaline + pyrite. This is surrounded by a second alteration assemblage, consisting of albite + sericite + calcite + chlorite + pyrite + rutile, which marks a lateral alteration that fades into the unaltered rock. Mass balance calculations show that during alteration overall mass was conserved and elemental transfer is generally consistent with sulfidation, sericitization and carbonatization of the host TTG. Gold is closely associated with pyrite, which occurs as disseminated grains in the veins and in the host rock, within the mineralized corridor. SEM imagery and LA-ICP-MS analyses of pyrites indicate that in A-type veins gold is associated with bismuth, tellurium, lead and silver, while in C-type veins it is mostly associated with silver. Pyrites in A-type veins contain gold as inclusions and as free gold on its edges and fractures, while pyrites from C-type veins contains mostly free gold. Primary and pseudosecondary fluid inclusions from both

  5. Ethnoveterinary plant remedies used by Nu people in NW Yunnan of China

    PubMed Central

    2010-01-01

    Background Nu people are the least populous ethnic group in Yunnan Province of China and most are distributed in Gongshan County, NW Yunnan. Animal production plays an important role in Nu livelihoods and the Nu people have abundant traditional knowledge of animal management and ethnoveterinary practices. This study documents the animal diseases, ethnoveterinary plant remedies and related traditional knowledge in three Nu villages of Gongshan County. Methods This study was carried out in three Nu villages of Gongshan County between July 2009 and February 2010. Data was obtained through the use of semi-structured questionnaires, field observation and PRA tools. A total of 60 Nu respondents (34 men and 26 women) provided information on animal ailments and ethnoveterinary plant medicines used for Nu livestock production. Information on traditional ethnoveterinary medicine knowledge and choice of treatment providers was also obtained. Results Thirty-five animal conditions were identified in the surveyed area. The major and most common animal diseases among livestock were skin conditions, diarrhea, heat, fevers, colds, and parasites. Most ailments occurred between June and August. The ethnoveterinary medicinal use of 45 plant species was documented. Most medicinal species (86.7%) were collected from the wild. The most frequently used plant parts were whole plants (35.6%), followed by roots (22.2%). The most important medicinal plant species were Saussurea costus (Falc.) Lipech. (UV = 0.67), Senecio scandens Buch.-Ham.ex D.Don (UV = 0.67), Plantago depressa Willd. (UV = 0.63), Rubus corchorifolius L. f. (UV = 0.62), Bupleurum yunnanense Franch. (UV = 0.60), and Polygonum paleaceum Wall. (UV = 0.60). Animal diseases treated with the highest number of ethnoveterinary plant remedies were diarrhea (16 plant species), heat, fever, colds (11 plant species), retained afterbirth (11 plant species), and skin conditions and sores (11 plant species). Many Nu villagers (52

  6. The Structure and Electrical Properties of the Ag2Se + Ga2Se3 + GeSe2 Glass System

    NASA Astrophysics Data System (ADS)

    Marple, Maxwell Adam Thomas

    Silver containing homogeneous chalcogenide glasses in the ternary system Ag2Se-Ga2Se3-GeSe2 (AGGS) are synthesized and their atomic structure-property relationships are investigated. Structural studies are carried out using Raman, 77Se, 71Ga, 69Ga, and 109Ag nuclear magnetic resonance (NMR) spectroscopy. The structure of these glasses consists primarily of a network of corner sharing (Ga/Ge)Se4/2 tetrahedra with a small fraction of homopolar Se-Se bonds. Compositional modification of the atomic structure follows the charge compensated network model developed in the literature for aluminosilicate glasses. Ag2Se acts as a network modifier, forming non-bridging Se in glasses with Ag/Ga >1, while Ga 2Se3 plays the role of a network intermediate similar to Al2O3 in oxide glasses. The network favors the formation of homopolar Ge-Ge bonding in glasses with Ag/Ga <1, to accommodate the Se deficiency brought by the incorporation of Ga2Se3 with Ga being tetrahedrally coordinated to Se. This structural model is consistent with the variation in the glass transition temperatures and molar volume. Electrical Impedance Spectroscopy (EIS) reveals the ionic conductivity of the AGGS glasses to be quite high at ambient temperature, reaching up to 10 --4 S/cm for glasses with the highest Ag content. Increasing Se deficiency with respect to stoichiometry can enhance the conductivity further to ˜3x10--4 S/cm . Transference number measurements using the electromotive force (EMF) method as well as variable temperature 109Ag NMR line shape studies indicate that the conductivity is predominantly ionic in nature and results from fast hopping dynamics of Ag ions. The high ionic conductivity can be related to a heavily modified structural network that results in a potential energy landscape with many suitable hopping sites for the Ag ions. These structural characteristics and electrical properties of the glasses in the AGGS system may guide in the development of next generation fast ion

  7. Airborne radioactivity Survey of part of Saratoga NW quadrangle, Carbon County, Wyoming

    USGS Publications Warehouse

    Henderson, J.R.

    1954-01-01

    The accompanying map shows the results of an airborne radioactivity survey in 133 square miles of Saratoga NW quadrangle, Wyoming. This area is part of a larger survey made in southern Carbon and Sweetwater Counties by the U. S. Geological Survey, November 9-24, 1953. The work was undertaken as part of a cooperative program with the U.S. Atomic Energy Commission.

  8. 23. Building N9; 3/4 view, looking NW at loading dock. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    23. Building N-9; 3/4 view, looking NW at loading dock. The view also shows the relationship of the blast barricades to the building. (Ryan) - Holston Army Ammunition Plant, RDX-and-Composition-B Manufacturing Line 9, Kingsport, Sullivan County, TN

  9. 13. RAILROAD BRIDGE MISSISSIPPI, MONROE CO., ABERDEEN 1.5 mi. NW ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. RAILROAD BRIDGE MISSISSIPPI, MONROE CO., ABERDEEN 1.5 mi. NW of Amory. St. Louis and San Francisco RR bridge. Steam locomotive and coal train cross bridge on 10 August 1921. Credit: Owned by Jack Donnell, Columbus, Ms., photographer. Copied by Sarcone Photography, Columbus, Ms. - Bridges of the Upper Tombigbee River Valley, Columbus, Lowndes County, MS

  10. 4. DETAIL VIEW OF NW CORNER OF BUILDING 1'S W ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. DETAIL VIEW OF NW CORNER OF BUILDING 1'S W WING, SHOWING THE PILASTERS, TERRA COTTA PANELS, AND THE EGYPTIAN MOTIF DECORATIVE CORNICE ELEMENTS; LOOKING ENE. (Harms) - Veterans Administration Medical Center, Building No. 1, Old State Route 13 West, Marion, Williamson County, IL

  11. Ag(I)-binding to phytochelatins.

    PubMed

    Mehra, R K; Tran, K; Scott, G W; Mulchandani, P; Saini, S S

    1996-02-01

    Phytochelatins (PCs) are glutathione-derived peptides with the general structure (gamma-Glu-Cys)nGly, where n varies from 2 to 11. A variety of metal ions such as Cu(II), Cd(II), Pb(II), Zn(II), and Ag(I) induce PC synthesis in plants and some yeasts. It has generally been assumed that the inducer metals also bind PCs. However, very little information is available on the binding of metals other than Cu(I) and Cd(II) to PCs. In this paper, we describe the Ag(I)-binding characteristics of PCs with the structure (gamma-Glu-Cys)2Gly, (gamma-Glu-Cys)3Gly, and (gamma-Glu-Cys)4Gly. The Ag(I)-binding stoichiometries of these three peptides were determined by (i) UV/VIS spectrophotometry, (ii) luminescence spectroscopy at 77 K, and (iii) reverse-phase HPLC. The three techniques yielded similar results. ApoPCs exhibit featureless absorption in the 220-340 nm range. The binding of Ag(I) to PCs induced the appearance of specific absorption shoulders. The titration end point was indicated by the flattening of the characteristic absorption shoulders. Similarly, luminescence at 77 K due to Ag(I)-thiolate clusters increased with the addition of graded Ag(I) equivalents. The luminescence declined when Ag(I) equivalents in excess of the saturating amounts were added to the peptides. At neutral pH, (gamma-Glu-Cys)2Gly, (gamma-Glu-Cys)3Gly, and (gamma-Glu-Cys)4Gly bind 1.0, 1.5, and 4.0 equivalents of Ag(I), respectively. The Ag(I)-binding capacity of (gamma-Glu-Cys)2Gly and (gamma-Glu-Cys)3Gly was increased at pH 5.0 and below so that Ag(I)/-SH ratio approached 1.0. A similar pH-dependent binding of Ag(I) to glutathione was also observed. The increased Ag(I)-binding to PCs at lower pH is of physiological significance as these peptides accumulate in acidic vacuoles. We also report lifetime data on Ag(I)-PCs. The relatively long decay-times (approximately 0.1-0.3 msec) accompanied with a large Stokes shift in the emission band are indicative of spin-forbidden phosphorescence. PMID

  12. Focal mechanisms of the 2000 swarm in NW-Bohemia/Vogtland anything new in the seismotectonic picture of the area?

    NASA Astrophysics Data System (ADS)

    Horalek, J.; Šílený, J.; Fischer, T.

    2003-04-01

    The Nový Kostel area witnessed the most intensive earthquake swarms of the whole NW-Bohemia/Vogtland swarm region. The Ml = 4.6 swarm of 1985/86, which was the most intensive swarm in the area, showed focal mechanisms compatible with the main fault orientation. By contrast, the recent results of the analysis of the 1997 swarm (Ml = 3) have shown that two types of faulting took place. One of them beards a significant isotropic component in its moment tensors, what may indicate activity of fluids during the rupture process. The events of the most recent 2000 swarm (ML=3.2) lasting for three months were confined to a thin, almost planar, and steeply dipping focal area. The existing, preliminary focal mechanisms of the 2000 swarm show a simple pattern, which is again compatible with the main fault orientation. We made a detailed analysis of swarm seismograms recorded by WEBNET and other local networks in the area to determine precisely the focal mechanisms of all larger events (ML>1.8). We try to find any regularities in the occurrence of different fault mechanisms during the swarm development and across the fault volume. Full moment tensors have been determined for selected events and the rate of shear and non-shear components was critically evaluated. The results are interpreted according to focal mechanisms of the previous swarms occurring in the area and to its seismotectonic regime.

  13. Extraction of morphotectonic features from DEMs: Development and applications for study areas in Hungary and NW Greece

    NASA Astrophysics Data System (ADS)

    Jordan, G.; Meijninger, B. M. L.; Hinsbergen, D. J. J. van; Meulenkamp, J. E.; Dijk, P. M. van

    2005-11-01

    A procedure for the consistent application of digital terrain analysis methods to identify tectonic phenomena from geomorphology is developed and presented through two case studies. Based on the study of landforms related to faults, geomorphological characteristics are translated into mathematical and numerical algorithms. Topographic features represented by digital elevation models of the test areas were extracted, described and interpreted in terms of structural geology and geomorphology. Digital terrain modelling was carried out by means of the combined use of: (1) numerical differential geometry methods, (2) digital drainage network analysis, (3) digital geomorphometry, (4) digital image processing, (5) lineament extraction and analysis, (6) spatial and statistical analysis and (7) digital elevation model-specific digital methods, such as shaded relief models, digital cross-sections and 3D surface modelling. A sequential modelling scheme was developed and implemented to analyse two selected study sites, in Hungary and NW Greece on local and regional scales. Structural information from other sources, such as geological and geophysical maps, remotely sensed images and field observations were analysed with geographic information system techniques. Digital terrain analysis methods applied in the proposed way in this study could extract morphotectonic features from DEMs along known faults and they contributed to the tectonic interpretation of the study areas.

  14. Flexible membranes of Ag-nanosheet-grafted polyamide-nanofibers as effective 3D SERS substrates

    NASA Astrophysics Data System (ADS)

    Qian, Yiwu; Meng, Guowen; Huang, Qing; Zhu, Chuhong; Huang, Zhulin; Sun, Kexi; Chen, Bin

    2014-04-01

    We report on a synthetic approach to produce self-supported flexible surface-enhanced Raman scattering (SERS) active membranes consisting of polyamide (PA) nanofibers grafted with vertical Ag-nanosheets, via a combinatorial process of electrospinning PA-nanofiber membranes, assembling Au-nanoparticles on the PA-nanofibers as seeds for subsequent growth of Ag-nanosheets, and electrodepositing Ag-nanosheets on the electrospun PA-nanofibers. As a high density of Ag-nanosheets are vertically grown around each PA-nanofiber in the three-dimensional (3D) networked PA-nanofiber membranes, homogeneous nano-scaled gaps between the neighboring Ag-nanosheets are formed, leading to a high density of 3D SERS ``hot spots'' within the Ag-nanosheet-grafted PA-nanofiber membranes. The Ag-nanosheet-grafted PA-nanofiber membranes demonstrate high SERS activity with excellent Raman signal reproducibility for rhodamine 6G over the whole membrane. For a SERS-based trial analysis of polychlorinated biphenyls (PCBs, a kind of global environmental hazard), the 3D SERS substrate membranes are modified with mono-6-β-cychlodextrin to effectively capture PCB molecules. As a result, not only a low concentration down to 10-6 M is reached, but also two congeners of PCBs in their mixed solution are identified, showing promising potential in SERS-based rapid detection of trace organic pollutants such as PCBs in the environment.We report on a synthetic approach to produce self-supported flexible surface-enhanced Raman scattering (SERS) active membranes consisting of polyamide (PA) nanofibers grafted with vertical Ag-nanosheets, via a combinatorial process of electrospinning PA-nanofiber membranes, assembling Au-nanoparticles on the PA-nanofibers as seeds for subsequent growth of Ag-nanosheets, and electrodepositing Ag-nanosheets on the electrospun PA-nanofibers. As a high density of Ag-nanosheets are vertically grown around each PA-nanofiber in the three-dimensional (3D) networked PA

  15. Study of antibacterial activity of Ag and Ag2CO3 nanoparticles stabilized over montmorillonite

    NASA Astrophysics Data System (ADS)

    Sohrabnezhad, Sh.; Pourahmad, A.; Mehdipour Moghaddam, M. J.; Sadeghi, A.

    2015-02-01

    Silver carbonate and silver nanoparticles (NPs) over of stabilizer montmorillonite (MMT) have been synthesized in aqueous and polyol solvent, respectively. Dispersions of silver nanoparticles have been prepared by the reduction of silver nitrate over of MMT in presence and absence of Na2CO3 compound in ethylene glycol. It was observed that montmorillonite was capable of stabilizing formed Ag nanoparticles through the reduction of Ag+ ions in ethylene glycol. Na2CO3 was used as carbonate source in synthesis of Ag2CO3 NPs in water solvent and also for controlling of Ag nanoparticles size in ethylene glycol medium. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and ultraviolet-visible diffuse reflectance spectroscopy (DRS). The TEM images showed that Ag NPs size in presence Na2CO3 salts was smaller than without that. The results indicated intercalation of Ag and Ag2CO3 nanoparticles into the montmorillonite clay layers. The diffuse reflectance spectra exhibited a strong surface plasmon resonance (SPR) adsorption peak in the visible region, resulting from Ag nanoparticles. The antibacterial testing results showed that the Ag2CO3-MMT nanocomposite exhibited an antibacterial activity higher than Ag-MMT sample against Escherichia coli.

  16. Spectroscopic Study on Eu3+ Doped Borate Glasses Containing Ag Nanoparticles and Ag Aggregates.

    PubMed

    Fu, Shaobo; Zheng, Hui; Zhang, Jinsu; Li, Xiangping; Sun, Jiashi; Hua, Ruinian; Dong, Bin; Xia, Haiping; Chen, Baojiu

    2015-01-01

    Transparent Eu(3+)-doped borate glasses containing Ag nanoparticles and Ag aggregates with composition (40 - x) CaO-59.5B2O3-0.5Eu2O3-xAgNO3 were prepared by a simple one-step melt-quenching technique. The X-ray diffraction (XRD) patterns of the glasses reveal amorphous structural properties and no diffraction peaks belonging to metal Ag particles. Ag particles and Ag aggregates were observed from the absorption spectra. Effective energy transfers from the Ag aggregates to the Eu3+ ions were observed in the excitation spectra from monitoring the intrinsic emission of Eu3+x .5D0 --> 7F2. The glasses with higher Ag content can be effectively excited by light in a wide wavelength region, indicating that these glasses have potential application in the solid state lighting driven by semiconductor light emitting diodes (LEDs). The emission spectra of the samples with higher Ag contents exhibit plenteous spectral components covering the full visible region from violet to red, thus indicating that these glass materials possess an excellent and tunable color rendering index. The color coordinates for all the glass samples were calculated by using the intensity-corrected emission spectra and the standard data issued by the CIE (Commission International de l' Eclairage) in 1931. It was found that the color coordinates for most samples with higher Ag contents fall into the white region in the color space. PMID:26328363

  17. The AGS with four helical magnets

    SciTech Connect

    Tsoupas, N.; Huang, H.; MacKay, W.W.; Roser, T.; Trbojevic, D.

    2010-02-25

    The idea of using multiple partial helical magnets was applied successfully to the AGS synchrotron, to preserve the proton beam polarization. In this paper we explore in details the idea of using four helical magnets placed symmetrically in the AGS ring. This modification provides many advantages over the present setup of the AGS that uses two partial helical magnets. First, it provides a larger 'spin tune gap' for the placement of the vertical betatron tune of the AGS during acceleration, second, the vertical spin direction during the beam injection and extraction is closer to vertical, third, the symmetric placement of the snakes allows for a better control of the AGS optics, and for reduced values of the beta and eta functions, especially near injection, fourth, the optical properties of the helical magnets also favor the placement of the horizontal betatron tune in the 'spin tune gap', thus eliminating the horizontal spin resonances. In this paper we provide results on the spin tune and on the optics of the AGS with four partial helical magnets, and we compare these results with the present setup of the AGS that uses two partial helical magnets.

  18. Synthesis and electromagnetic absorption properties of Ag-coated reduced graphene oxide with MnFe2O4 particles

    NASA Astrophysics Data System (ADS)

    Wang, Yan; Wu, Xinming; Zhang, Wenzhi; Huang, Shuo

    2016-04-01

    A ternary composite of Ag/MnFe2O4/reduced graphene oxide (RGO) was synthesized by a facile hydrothermal method. The morphology, microstructure, magnetic and electromagnetic properties of as-prepared Ag/MnFe2O4/RGO composite were characterized by means of XRD, TEM, XPS, VSM and vector network analyzer. The maximum reflection loss (RL) of Ag/ MnFe2O4/RGO composite shows maximum absorption of -38 dB at 6 GHz with the thickness of 3.5 mm, and the absorption bandwidth with the RL below -10 dB is up to 3.5 GHz (from 3.7 to 7.2 GHz). The result demonstrates that the introduction of Ag significantly leads to the multiple absorbing mechanisms. It is believed that such composite could serve as a powerful candidate for microwave absorber.

  19. Enhancement of the visible light activity and stability of Ag2CO3 by formation of AgI/Ag2CO3 heterojunction

    NASA Astrophysics Data System (ADS)

    Yu, Changlin; Wei, Longfu; Zhou, Wanqin; Chen, Jianchai; Fan, Qizhe; Liu, Hong

    2014-11-01

    An insurmountable problem for silver-based semiconductor photocatalysts is their poor stability. Here, at room temperature, AgI with different concentrations (5%, 10%, 20% and 30%) were coupled into Ag2CO3, producing a series of novel AgI/Ag2CO3 composite photocatalysts. The effects of AgI addition on the Ag2CO3 catalyst for photocatalytic degradation of methyl orange (MO) under visible light irradiation have been investigated. Some physicochemical technologies like N2 physical adsorption/desorption, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX) spectroscopy, X-ray photoelectron spectroscopy (XPS), and UV-vis diffuse reflectance spectroscopy (UV-vis DRS) were applied to characterize these products. Results show that the photocatalytic degradation activity of AgI/Ag2CO3 photocatalyst is much higher than that of pure AgI and Ag2CO3. With the optimal content of AgI (20 wt%), the AgI/Ag2CO3 exhibits the highest photocatalytic degradation efficiency. Its first order reaction rate constant (0.54 h-1) is 20 times of that of AgI (0.026 h-1) and 3.6 times of that of Ag2CO3 (0.15 h-1). The characterizations and theory calculation show that AgI and Ag2CO3 have suitably matched band gap structures. The formation of AgI/Ag2CO3 heterojunction with intimate interface could effectively increase the separation efficiency of the e-/h+ pairs and promote the production of •OH and O2•- radicals, which brings about the fast degradation rate of the dye and an increase in photocatalytic stability.

  20. Demonstration and partial characterization of 22-nm HBsAg and Dane particles of subtype HBsAg/ady.

    PubMed

    Hess, G; Shih, J W; Arnold, W; Gerin, J L; zum Büschenfelde, K H

    1979-09-01

    The present paper describes the demonstration of d, y, w, and r HBsAg determinants in one serum. It was shown that there are two populations of HBsAg particles: HBsAg/ad and HBsAg/ady. All complete Dane particles were of subtype HBsAg/ady. Further characterization of HBsAg/ady particles did not reveal morphologic differences when they were compared with HBsAg/ad and HBsAg/ay particles. An HBsAg/ady phenotype may be the result of a double infection with hepatitis B viruses or exchanges of DNA sequences that determine HBsAg/ay and HBsAg/ad to form a new genotype. PMID:89163

  1. Hierarchically plasmonic photocatalysts of Ag/AgCl nanocrystals coupled with single-crystalline WO3 nanoplates

    NASA Astrophysics Data System (ADS)

    Chen, Deliang; Li, Tao; Chen, Qianqian; Gao, Jiabing; Fan, Bingbing; Li, Jian; Li, Xinjian; Zhang, Rui; Sun, Jing; Gao, Lian

    2012-08-01

    The hierarchical photocatalysts of Ag/AgCl@plate-WO3 have been synthesized by anchoring Ag/AgCl nanocrystals on the surfaces of single-crystalline WO3 nanoplates that were obtained via an intercalation and topochemical approach. The heterogeneous precipitation process of the PVP-Ag+-WO3 suspensions with a Cl- solution added drop-wise was developed to synthesize AgCl@WO3 composites, which were then photoreduced to form Ag/AgCl@WO3 nanostructures in situ. WO3 nanocrystals with various shapes (i.e., nanoplates, nanorods, and nanoparticles) were used as the substrates to synthesize Ag/AgCl@WO3 photocatalysts, and the effects of the WO3 contents and photoreduction times on their visible-light-driven photocatalytic performance were investigated. The techniques of TEM, SEM, XPS, EDS, XRD, N2 adsorption-desorption and UV-vis DR spectra were used to characterize the compositions, phases and microstructures of the samples. The RhB aqueous solutions were used as the model system to estimate the photocatalytic performance of the as-obtained Ag/AgCl@WO3 nanostructures under visible light (λ >= 420 nm) and sunlight. The results indicated that the hierarchical Ag/AgCl@plate-WO3 photocatalyst has a higher photodegradation rate than Ag/AgCl, AgCl, AgCl@WO3 and TiO2 (P25). The contents and morphologies of the WO3 substrates in the Ag/AgCl@plate-WO3 photocatalysts have important effects on their photocatalytic performance. The related mechanisms for the enhancement in visible-light-driven photodegradation of RhB molecules were analyzed.The hierarchical photocatalysts of Ag/AgCl@plate-WO3 have been synthesized by anchoring Ag/AgCl nanocrystals on the surfaces of single-crystalline WO3 nanoplates that were obtained via an intercalation and topochemical approach. The heterogeneous precipitation process of the PVP-Ag+-WO3 suspensions with a Cl- solution added drop-wise was developed to synthesize AgCl@WO3 composites, which were then photoreduced to form Ag/AgCl@WO3 nanostructures in

  2. A 300-mV 220-nW event-driven ADC with real-time QRS detection for wearable ECG sensors.

    PubMed

    Zhang, Xiaoyang; Lian, Yong

    2014-12-01

    This paper presents an ultra-low-power event-driven analog-to-digital converter (ADC) with real-time QRS detection for wearable electrocardiogram (ECG) sensors in wireless body sensor network (WBSN) applications. Two QRS detection algorithms, pulse-triggered (PUT) and time-assisted PUT (t-PUT), are proposed based on the level-crossing events generated from the ADC. The PUT detector achieves 97.63% sensitivity and 97.33% positive prediction in simulation on the MIT-BIH Arrhythmia Database. The t-PUT improves the sensitivity and positive prediction to 97.76% and 98.59% respectively. Fabricated in 0.13 μm CMOS technology, the ADC with QRS detector consumes only 220 nW measured under 300 mV power supply, making it the first nanoWatt compact analog-to-information (A2I) converter with embedded QRS detector. PMID:25608283

  3. Agent planning in AgScala

    NASA Astrophysics Data System (ADS)

    Tošić, Saša; Mitrović, Dejan; Ivanović, Mirjana

    2013-10-01

    Agent-oriented programming languages are designed to simplify the development of software agents, especially those that exhibit complex, intelligent behavior. This paper presents recent improvements of AgScala, an agent-oriented programming language based on Scala. AgScala includes declarative constructs for managing beliefs, actions and goals of intelligent agents. Combined with object-oriented and functional programming paradigms offered by Scala, it aims to be an efficient framework for developing both purely reactive, and more complex, deliberate agents. Instead of the Prolog back-end used initially, the new version of AgScala relies on Agent Planning Package, a more advanced system for automated planning and reasoning.

  4. A FLYING WIRE SYSTEM IN THE AGS.

    SciTech Connect

    HUANG,H.; BUXTON,W.; MAHLER,G.; MARUSIC,A.; ROSER,T.; SMITH,G.; SYPHERS,M.; WILLIAMS,N.; WITKOVER,R.

    1999-03-29

    As the AGS prepares to serve as the injector for RHIC, monitoring and control of the beam transverse emittance become a major and important topic. Before the installation of the flying wire system, the emittance was measured with ionization profile monitors in the AGS, which require correction for space charge effects. It is desirable to have a second means of measuring profile that is less depend on intensity. A flying wire system has been installed in the AGS recently to perform this task. This paper discusses the hardware and software setup and the capabilities of the system.

  5. Ag induced enhancement of perpendicular magnetic anisotropy

    NASA Astrophysics Data System (ADS)

    Shern, C. S.; Su, C. W.; Wu, Y. E.; Chen, S. H.

    2001-12-01

    Some interesting magnetic properties were observed after Ag ultrathin films were deposited on Co/Pt(1 1 1). The spin reversal of Co can be prevented when Ag atoms cap Co on Pt(1 1 1). The out-of-plane magnetization has a significant enhancement after annealing at high temperature. The Curie temperature increases from 625 to 710 K as 1 ML of Ag is deposited on 1 ML Co/Pt(1 1 1). The change of surface anisotropy and the formation of a Co-Pt alloy are possible mechanisms for the magnetization enhancement.

  6. Extranuclear dynamics of 111Ag(→111Cd) doped in AgI nanoparticles

    NASA Astrophysics Data System (ADS)

    Sato, W.; Mizuuchi, R.; Irioka, N.; Komatsuda, S.; Kawata, S.; Taoka, A.; Ohkubo, Y.

    2014-08-01

    Dynamic behavior of the extranuclear field relative to the 111Ag(→111Cd) probe nucleus introduced in a superionic conductor silver iodide (AgI) was investigated by means of the time-differential perturbed angular correlation technique. For poly-N-vinyl-2-pyrrolidone (PVP)-coated AgI nanoparticles, we observed nuclear spin relaxation of the probe at room temperature. This result signifies that Ag+ ions in the polymer-coated sample make hopping motion from site to site at this low temperature. The activation energy for the dynamic motion was successfully estimated to be 46(10) meV. The first atomic-level observation of the temperature-dependent dynamic behavior of Ag+ ions in the polymer-coated AgI is reported.

  7. Ag induced electromagnetic interference shielding of Ag-graphite/PVDF flexible nanocomposites thinfilms

    NASA Astrophysics Data System (ADS)

    Kumaran, R.; Alagar, M.; Dinesh Kumar, S.; Subramanian, V.; Dinakaran, K.

    2015-09-01

    We report Ag nanoparticle induced Electromagnetic Interference (EMI) shielding in a flexible composite films of Ag nanoparticles incorporated graphite/poly-vinylidene difluoride (PVDF). PVDF nanocomposite thin-films were synthesized by intercalating Ag in Graphite (GIC) followed by dispersing GIC in PVDF. The X-ray diffraction analysis and the high-resolution transmission electron microscope clearly dictate the microstructure of silver nanoparticles in graphite intercalated composite of PVDF matrix. The conductivity values of nanocomposites are increased upto 2.5 times when compared to neat PVDF having a value of 2.70 S/cm at 1 MHz. The presence of Ag broadly enhanced the dielectric constant and lowers the dielectric loss of PVDF matrix proportional to Ag content. The EMI shielding effectiveness of the composites is 29.1 dB at 12.4 GHz for the sample having 5 wt. % Ag and 10 wt. % graphite in PVDF.

  8. Nanoscale current spreading analysis in solution-processed graphene oxide/silver nanowire transparent electrodes via conductive atomic force microscopy

    NASA Astrophysics Data System (ADS)

    Shaw, Joseph E.; Perumal, Ajay; Bradley, Donal D. C.; Stavrinou, Paul N.; Anthopoulos, Thomas D.

    2016-05-01

    We use conductive atomic force microscopy (CAFM) to study the origin of long-range conductivity in model transparent conductive electrodes composed of networks of reduced graphene oxide (rGOX) and silver nanowires (AgNWs), with nanoscale spatial resolution. Pristine networks of rGOX (1-3 monolayers-thick) and AgNWs exhibit sheet resistances of ˜100-1000 kΩ/□ and 100-900 Ω/□, respectively. When the materials are deposited sequentially to form bilayer rGOX/AgNW electrodes and thermally annealed at 200 °C, the sheet resistance reduces by up to 36% as compared to pristine AgNW networks. CAFM was used to analyze the current spreading in both systems in order to identify the nanoscale phenomena responsible for this effect. For rGOX networks, the low intra-flake conductivity and the inter-flake contact resistance is found to dominate the macroscopic sheet resistance, while for AgNW networks the latter is determined by the density of the inter-AgNW junctions and their associated resistance. In the case of the bilayer rGOX/AgNWs' networks, rGOX flakes are found to form conductive "bridges" between AgNWs. We show that these additional nanoscopic electrical connections are responsible for the enhanced macroscopic conductivity of the bilayer rGOX/AgNW electrodes. Finally, the critical role of thermal annealing on the formation of these nanoscopic connections is discussed.

  9. Highly luminescent Ag+ nanoclusters for Hg2+ ion detection

    NASA Astrophysics Data System (ADS)

    Yuan, Xun; Yeow, Teik Jin; Zhang, Qingbo; Lee, Jim Yang; Xie, Jianping

    2012-03-01

    A simple, low-cost and label-free Hg2+ ion sensor has been developed by using novel luminescent Ag+ nanoclusters (NCs) with an excellent optical property (quantum yield = 15%), an ultra-high ratio of active Ag+ species in the NC surface (~100%), and an ultra-short diffusion path length of Hg2+ ions to access the NC surface (~0.5 nm).A simple, low-cost and label-free Hg2+ ion sensor has been developed by using novel luminescent Ag+ nanoclusters (NCs) with an excellent optical property (quantum yield = 15%), an ultra-high ratio of active Ag+ species in the NC surface (~100%), and an ultra-short diffusion path length of Hg2+ ions to access the NC surface (~0.5 nm). Electronic supplementary information (ESI) available: Experimental details of the synthesis of b-Ag NCs; time-resolved evolution of photoemission spectra of the b-Ag NCs in toluene; photoexcitation spectrum of the b-Ag NCs in toluene; comparison of the luminescence of b-Ag NCs at different temperatures (4 and 25 °C) TEM image of the b-Ag NCs in toluene; optical properties of r-Ag NCs obtained by the reduction of b-Ag NCs in toluene; XPS spectra of b-Ag NCs, thiolate-Ag+ complexes, r-Ag NCs, and large Ag nanoparticles; TEM image of the Hg2+-Ag NCs; photostability of the b-Ag NCs; tolerance studies of the b-Ag NCs over other metal ions; tolerance studies of the b-Ag NCs over common thiol ligands (e.g., GSH) and anions; relative luminescence of the b-Ag NCs in different real water samples in the presence of Hg2+ ions; and relative luminescence of the b-Ag NCs in NaCl solution with different concentrations. See DOI: 10.1039/c2nr11999d

  10. Facile synthesis of S-Ag nanocomposites and Ag2S short nanorods by the interaction of sulfur with AgNO3 in PEG400.

    PubMed

    Zhang, Yan-Li; Xie, Xin-Yuan; Liang, Ming; Xie, Shu-Ming; Chen, Jie-Mei; Zheng, Wen-Jie

    2016-06-01

    A facile, eco-friendly and inexpensive method to prepare Ag2S short nanorods and S-Ag nanocomposites using sublimed sulfur, AgNO3, PVP and PEG400 was studied. According to x-ray diffraction and scanning electron microscopy of the Ag2S, the products are highly crystalline and pure Ag2S nanorods with diameters of 70-160 nm and lengths of 200-360 nm. X-ray diffraction of the S-Ag nanocomposites shows that we obtained cubic Ag and S nanoparticles. Transmission electron microscopy shows that the molar ratio of PVP to Ag(+) plays an important role in controlling the size and morphology of the S-Ag nanocomposites. When the molar ratio of PVP to Ag(+) was 10:1, smaller sizes, better dispersibility and narrower distribution of S-Ag nanocomposites with diameters of 10-40 nm were obtained. The formation mechanism of the S-Ag nanocomposites was studied by designing a series of experiments using ultraviolet-visible measurement, and it was found that S nanoparticles are produced first and act as seed crystals; then Ag(+) becomes Ag nanocrystals on the surfaces of the S nanoparticles by the reduction of PVP. PEG400 acts as a catalyzer, accelerating the reaction rate, and protects the S-Ag nanocomposites from reacting to produce Ag2S. The antimicrobial experiments show that the S-Ag nanocomposites have greater antimicrobial activity on Staphylococcus aureus, Aspergillus niger and blue mold than Ag nanoparticles. PMID:27109417

  11. Long term monitoring system integrated in an elevational gradient in NW Argentina

    NASA Astrophysics Data System (ADS)

    Carilla, J.; Malizia, A.; Osinaga, O.; Blundo, C.; Grau, R.; Malizia, L.; Aráoz, E.

    2013-05-01

    Ecological trends and ranges of variability are poorly known in the tropical and subtropical Andes. Long term studies are powerful tools to detect the response of vegetation dynamics, biodiversity and hydrological cycle to these trends. We present a long term monitoring system in NW Argentinean mountains, including forest permanent plots at different elevations and high elevation grasslands, encompassing more than 3.000 m elevation range. Long term studies include: 1) 66 ha of mountain forest permanent plots along the Yungas elevational gradient from c. 400 to 2500 masl , and latitudinal gradient (22-28S) with 45 plots in mature forests and 28 in secondary forests originated in grazing, agriculture and selective logging. Some of these permanent plots have achieved 20 years of monitoring and all of them are included in the "Red de Bosques Andinos" a network created recently, together with c. 10 institutions and more than 130 (c. 120 ha) forest permanent plots from Argentina to Colombia Andes. 2) Two GLORIA (Global Observation Research Initiative in Alpine Environments) sites, above 4000 masl with more than 170 species recorded, including one re-measurement. This system is included in GLORIA network (www.gloria.ac.at) and in GLORIA Andes (http://www.condesan.org/gloria), and 3) more than 15 satellite monitored high Andean lakes and a wide extension of vegas (75800 ha in Argentinean puna). A digital database is being implemented to organize and provide access to the information generated by these three systems coordinated by the Instituto de Ecología Regional (http://www.iecologia.com.ar). These monitoring data are analyzed together with instrumental and dendrochronological data to describe the dynamics of these ecosystems over an area of 20 million hectares distributed between 22 and 28°S. Some of the most significant results to date include: 1) secondary mountain forests are expanding over grasslands and agriculture lands, and tend to converge toward mature forest

  12. Control and performance of the AGS and AGS Booster Main Magnet Power Supplies

    SciTech Connect

    Reece, R.K.; Casella, R.; Culwick, B.; Geller, J.; Marneris, I.; Sandberg, J.; Soukas, A.; Zhang, S.Y.

    1993-06-01

    Techniques for precision control of the main magnet power supplies for the AGS and AGS Booster synchrotron will be discussed. Both synchrotrons are designed to operate in a Pulse-to-Pulse Modulation (PPM) environment with a Supercycle Generator defining and distributing global timing events for the AGS Facility. Details of modelling, real-time feedback and feedforward systems, generation and distribution of real time field data, operational parameters and an overview of performance for both machines are included.

  13. Control and performance of the AGS and AGS Booster Main Magnet Power Supplies

    SciTech Connect

    Reece, R.K.; Casella, R.; Culwick, B.; Geller, J.; Marneris, I.; Sandberg, J.; Soukas, A.; Zhang, S.Y.

    1993-01-01

    Techniques for precision control of the main magnet power supplies for the AGS and AGS Booster synchrotron will be discussed. Both synchrotrons are designed to operate in a Pulse-to-Pulse Modulation (PPM) environment with a Supercycle Generator defining and distributing global timing events for the AGS Facility. Details of modelling, real-time feedback and feedforward systems, generation and distribution of real time field data, operational parameters and an overview of performance for both machines are included.

  14. Indium Tin Oxide Nanowire Networks as Effective UV/Vis Photodetection Platforms

    PubMed Central

    2015-01-01

    We demonstrate that indium tin oxide nanowires (ITO NWs) and cationic polymer-modified ITO NWs configured in a network format can be used as high performing UV/vis photodetectors. The photovoltage response of ITO NWs is much higher than similarly constructed devices made from tin oxide, zinc tin oxide, and zinc oxide nanostructures. The ITO NW mesh-based devices exhibit a substantial photovoltage (31–100 mV under illumination with a 1.14 mW 543 nm laser) and photocurrent (225–325 μA at 3 V). The response time of the devices is fast with a rise time of 20–30 μs and a decay time of 1.5–3.7 ms when probed with a 355 nm pulsed laser. The photoresponsivity of the ITO NW devices ranges from 0.07 to 0.2 A/W at a 3 V bias, whose values are in the performance range of most commercial UV/vis photodetectors. Such useful photodetector characteristics from our ITO NW mesh devices are attained straightforwardly without the need for complicated fabrication procedures involving highly specialized lithographic tools. Therefore, our approach of ITO NW network-based photodetectors can serve as a convenient alternative to commercial or single NW-based devices. PMID:26167237

  15. Disease Registries on the Nationwide Health Information Network

    PubMed Central

    Russler, Daniel

    2011-01-01

    Background: Donation by individuals of their protected health information (PHI) for evidence-based research potentially benefits all individuals with disease through improved understandings of disease patterns. In the future, a better understanding of how disease features combine into unique patterns of disease will generate new disease classifications, supporting greater specificity in health management techniques. However, without large numbers of people who donate their PHI to disease registries designed for research, it is difficult for researchers to discover the existence of complex patterns or to create more specific evidence-based management techniques. In order to identify new opportunities in disease registry design, an analysis of the current stage of maturity of the newly created U.S. Nationwide Health Information Network (NwHIN) related to large-scale consumer donation of PHI is presented. Methods: Utilizing a use–case analysis methodology, the consumer-centric designs of the policies and technologies created for the NwHIN were examined for the potential to support consumer donations of PHI to research. Results: The NwHIN design has placed the enforcement point for the policy-based release of PHI over the Internet into a specialized gateway accessible to consumer authorization. However, current NwHIN policies leave the final decision regarding release of PHI for research to the health care providers rather than to the consumers themselves. Conclusions: Should disease registries designed for research be established on the NwHIN, consumers might then directly authorize the donation of their PHI to these disease registries. However, under current NwHIN policies, consumer authorization does not guarantee release of PHI by health providers. PMID:21722569

  16. Redetermination of AgPO(3).

    PubMed

    Terebilenko, Katherina V; Zatovsky, Igor V; Ogorodnyk, Ivan V; Baumer, Vyacheslav N; Slobodyanik, Nikolay S

    2011-01-01

    Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhedra, giving rise to multidirectional ribbons, and from two types of PO(4) tetra-hedra linked into meandering chains (PO(3))(n) spreading parallel to the b axis with a repeat unit of four tetra-hedra. The calculated bond-valence sum value of one of the two Ag(I) ions indicates a significant strain of the structure. PMID:21522230

  17. Nanoporous Ag prepared from the melt-spun Cu-Ag alloys

    NASA Astrophysics Data System (ADS)

    Li, Guijing; Song, Xiaoping; Sun, Zhanbo; Yang, Shengchun; Ding, Bingjun; Yang, Sen; Yang, Zhimao; Wang, Fei

    2011-07-01

    Nanoporous Ag ribbons with different morphology and porosity were achieved by the electrochemical corrosion of the melt-spun Cu-Ag alloys. The Cu-rich phase in the alloys was removed, resulting in the formation of the nanopores distributed across the whole ribbon. It is found that the structures, morphology and porosity of the nanoporous Ag ribbons were dependent on the microstructures of the parent alloys. The most of ligaments presented a rod-like shape due to the formation of pseudoeutectic microstructure in the melt-spun Cu 55Ag 45 and Cu 70Ag 30 alloys. For nanoporous Ag prepared from Cu 85Ag 15 alloys, the ligaments were camber-like because of the appearance of the divorced microstructures. Especially, a novel bamboo-grove-like structure could be observed at the cross-section of the nanoporous Ag ribbons. The experiment reveals that nanoporous Ag ribbons exhibited excellent enhancement of surface-enhanced Raman scattering (SERS) effect, but a slight difference existed due to the discrepancy of their morphology.

  18. Surface migration and volume diffusion in the AgGaSe2-Ag2Se system

    NASA Technical Reports Server (NTRS)

    Kim, N.-H.; Feigelson, R. S.; Route, R. K.

    1992-01-01

    Surface migration and volume diffusion in the Ag2Se-AgGaSe2 system were investigated using reactive diffusion couples which were analyzed by X-ray diffraction, optical microscopy, and electron probe microanalysis. The surface diffusivities of all mobile species are found to be much larger than volume diffusivities. The results of the study suggest that Se moves together with Ag and Ga to maintain binary (Ag2Se and Ga2Se3) stoichiometry and electroneutrality. The dominance of surface migration kinetics can account for the uniform annihilation of second-phase precipitates during heat treatments.

  19. A surface plasmon model for laser ablation of Ag sup + ions from a roughened Ag surface

    SciTech Connect

    Ritchie, R.H. Tennessee Univ., Knoxville, TN . Dept. of Physics); Manson, J.R. . Dept. of Physics); Echenique, P.M. . Faculdad de Quimica)

    1991-01-01

    Experimental work by Shea and Compton suggests that Ag{sup +} ions emitted from a roughened Ag surface irradiated by a nanosecond or picosecond laser beam may absorb the full energy of the Ag surface plasmon. We have modeled this process under the assumption that it proceeds through an inverse bremsstrahlung-type absorption of the SP quantum by Ag{sup +} ion which also undergoes a small-impact parameter collision with another ion or atom in the vicinity of the surface. We give a quantitative estimate of the absorption probability and find reasonable agreement with the Shea-Compton results. 8 refs., 2 figs.

  20. Mechanical and electrical properties of ZnO/Ag nanocomposites.

    SciTech Connect

    Hayashi, Y.

    1998-08-27

    Effects of Ag particle dispersions on microstructural development and some properties were investigated for ZnO/Ag nanocomposites. They were fabricated by Pulse Electric Current Sintering (PECS) Process to achieve finer and densified microstructure. ZnO/Ag nanocomposites with novel microstructure which were prepared by a reduction process using Ag{sub 2}O fine powders were compared with microcomposites prepared by mixing of Ag and ZnO powders. SEM observation indicated that fine Ag particles were homogeneously dispersed within the ZnO matrix grains and at the grain boundaries for ZnO/Ag nanocomposites prepared by the reduction process using Ag{sub 2}O fine powder. Hardness and fracture toughness increased with increasing the Ag volume fraction. Linear resistivity was decreased with increasing Ag volume fraction. However, the mechanical and electrical properties appeared to the significantly different for composites prepared by two different powder processes.

  1. Plasmonic TiO2/AgBr/Ag ternary composite nanosphere with heterojunction structure for advanced visible light photocatalyst

    NASA Astrophysics Data System (ADS)

    Dai, Kai; Li, Dongpei; Lu, Luhua; Liu, Qi; Liang, Changhao; Lv, Jiali; Zhu, Guangping

    2014-09-01

    In this work, TiO2/AgBr/Ag ternary composite nanosphere photocatalyst has been synthesized by in situ deposition of AgBr onto hollow spherical TiO2 template and followed by sun light reduction of AgBr into AgBr/Ag. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images have shown that the diameter of hollow TiO2 nanospheres is 250-350 nm and AgBr/Ag nanoparticles are well dispersed on the outer surface of TiO2 nanosphere. UV-vis spectrum analysis has shown largely improved visible light absorption of this ternary composite, in comparison to pure TiO2 and AgBr. The building-in AgBr/Ag, TiO2/AgBr and TiO2/Ag junctions within the ternary composite enhanced the visible light absorption because of plasmonic resonance and narrow bandgap. The pseudo-first-order rate constant kapp of the TiO2/AgBr/Ag ternary composite for methylene blue photodegradation displays 24.5 times and 3.3 times than the pure TiO2 nanosphere and AgBr/Ag nanoparticles, respectively. Furthermore, the stability of TiO2/AgBr/Ag ternary composite is characterized through cyclic photocatalytic test. Results indicate that 92.7% of photocatalytic degradation can be achieved by TiO2/AgBr/Ag ternary composite even after five recycles.

  2. 20% PARTIAL SIBERIAN SNAKE IN THE AGS.

    SciTech Connect

    Huang, H; Bai, M; Brown, K A; Glenn, W; Luccio, A U; Mackay, W W; Montag, C; Ptitsyn, V; Roser, T; Tsoupas, N; Zeno, K; Ranjbar, V; Spinka, H; Underwood, D

    2002-11-06

    An 11.4% partial Siberian snake was used to successfully accelerate polarized proton through a strong intrinsic depolarizing spin resonance in the AGS. No noticeable depolarization was observed. This opens up the possibility of using a 20% to 30% partial Siberian snake in the AGS to overcome all weak and strong depolarizing spin resonances. Some design and operation issues of the new partial Siberian snake are discussed.

  3. AgRISTARS documents tracking list report

    NASA Technical Reports Server (NTRS)

    Hawkins, J. L.

    1982-01-01

    A quarterly listing of those documents and related publications that have been issued and placed in the AgRISTARS tracking system is presented. The Tracking List Report provides a catalog, by project, of technical publications arranged by type of document and gives the reference AgRISTARS document numbers, title and date of publication, the issuing organization, and the National Technical Information Service reference number.

  4. AGS polarized proton operation in run 8.

    SciTech Connect

    Huang,H.; Ahrens, L.; Bai, M.; Brown, K.A.; Gardner, C.; Glenn, J.W.; Lin, F.; Luccio, A.U.; MacKay, W.W.; Roser, T.; Tepikian, S.; Tsoupas, N.; Yip, K.; Zeno, K.

    2008-06-23

    Dual partial snake scheme has been used for the Brookhaven AGS (Alternating Gradient Synchrotron) polarized proton operation for several years. It has provided polarized proton beams with 1.5 x 10{sup 11} intensity and 65% polarization for RHIC spin program. There is still residual polarization loss. Several schemes such as putting horizontal tune into the spin tune gap, and injection-on-the-fly were tested in the AGS to mitigate the loss. This paper presents the experiment results and analysis.

  5. Agricultural terraces and slope instability at Cinque Terre (NW Italy)

    NASA Astrophysics Data System (ADS)

    Brandolini, Pierluigi; Cevasco, Andrea

    2015-04-01

    Cinque Terre, located in the eastern Liguria, are one of the most representative examples of terraced coastal landscape within the Mediterranean region. They are the result of a century-old agricultural practice and constitute an outstanding example of human integration with the natural landscape. For this highly unusual man-made coastal landscape, the Cinque Terre have been recognized as a World Heritage Site by UNESCO since 1997 and became National Park in 1999. The complex network of retaining dry stone walls and drainage networks ensured through times the control of shallow water erosion and therefore, indirectly, favoured debris cover stability. The lack of maintenance of terracing due to farmer abandonment since the 1950s led to widespread slope erosion phenomena. The effects of such phenomena culminated during the 25 October 2011 storm rainfall event, when slope debris materials charged by streams gave rise to debris floods affecting both Monterosso and Vernazza villages. As the analysis of the relationships between geo-hydrological processes and land use in the Vernazza catchment highlighted, abandoned and not well maintained terraces were the most susceptible areas to shallow landsliding and erosion triggered by intense rainfall. As a consequence, the thousands of kilometres of dry stone walls retaining millions of cubic metres of debris cover at Cinque Terre currently constitute a potential menace for both villages, that are mainly located at the floor of deep cut valleys, and tourists. Given the increasing human pressure due to tourist activities, geo-hydrological risk mitigation measures are urgently needed. At the same time, restoration policies are necessary to preserve this extraordinary example of terraced coastal landscape. In this framework, the detailed knowledge of the response of terraced areas to intense rainfall in terms of slope instability is a topic issue in order to identify adequate land planning strategies as well as the areas where

  6. Exposure-dependent Ag+ release from silver nanoparticles and its complexation in AgS2 sites in primary murine macrophages

    NASA Astrophysics Data System (ADS)

    Veronesi, G.; Aude-Garcia, C.; Kieffer, I.; Gallon, T.; Delangle, P.; Herlin-Boime, N.; Rabilloud, T.; Carrière, M.

    2015-04-01

    Silver nanoparticle (AgNP) toxicity is related to their dissolution in biological environments and to the binding of the released Ag+ ions in cellulo; the chemical environment of recombined Ag+ ions is responsible for their toxicological outcome, moreover it is indicative of the cellular response to AgNP exposure, and can therefore shed light on the mechanisms governing AgNP toxicity. This study probes the chemistry of Ag species in primary murine macrophages exposed to AgNPs by making use of X-ray Absorption Fine Structure spectroscopy under cryogenic conditions: the linear combination analysis of the near-edge region of the spectra provides the fraction of Ag+ ions released from the AgNPs under a given exposure condition and highlights their complexation with thiolate groups; the ab initio modelling of the extended spectra allows measuring the Ag-S bond length in cellulo. Dissolution rates depend on the exposure scenario, chronicity leading to higher Ag+ release than acute exposure; Ag-S bond lengths are 2.41 +/- 0.03 Å and 2.38 +/- 0.01 Å in acute and chronic exposure respectively, compatible with digonal AgS2 coordination. Glutathione is identified as the most likely putative ligand for Ag+. The proposed method offers a scope for the investigation of metallic nanoparticle dissolution and recombination in cellular models.Silver nanoparticle (AgNP) toxicity is related to their dissolution in biological environments and to the binding of the released Ag+ ions in cellulo; the chemical environment of recombined Ag+ ions is responsible for their toxicological outcome, moreover it is indicative of the cellular response to AgNP exposure, and can therefore shed light on the mechanisms governing AgNP toxicity. This study probes the chemistry of Ag species in primary murine macrophages exposed to AgNPs by making use of X-ray Absorption Fine Structure spectroscopy under cryogenic conditions: the linear combination analysis of the near-edge region of the spectra provides

  7. Near-infrared emitting AgInTe2 and Zn-Ag-In-Te colloidal nanocrystals

    NASA Astrophysics Data System (ADS)

    Langevin, Marc-Antoine; Pons, Thomas; Ritcey, Anna M.; Nì. Allen, Claudine

    2015-06-01

    The synthesis of AgInTe2 nanocrystals emitting between 1095 nm and 1160 nm is presented. Evolution of the Ag:In:Te ratio shows progressive incorporation of In3+ in Ag2Te, leading to the formation of orthorhombic AgInTe2. When zinc is added to the synthesis, the photoluminescence quantum yield reaches 3.4 %.

  8. A Stretcher for the Brookhaven AGS

    SciTech Connect

    Foelsche, H.W.J.

    1989-01-01

    Brookhaven National Laboratory is proposing to add a Stretcher ring to increase the capacity and the quality of the experimental physics program at the AGS. At the present time a typical AGS cycle is about equally divided between the task of accelerating the beam to full energy and the task of distributing it on a 30 GeV flattop. The Stretcher, a 30 GeV dc storage ring, will take over from the AGS the distribution of the high energy beam with a continuous slow spill, and the AGS can then provide beam for the program at more than twice the present repetition rate. In this manner the average current delivered to the experimenters will be more than doubled, and the duty cycle of the spill will increase from the present optimum of about 40% to nearly 100%. The Stretcher proposal continues the gradual evolution of the AGS toward a high intensity hadron factory. At the present time the AGS provides about 1 ..mu..A average proton current. With the booster alone, now under construction, this is expected to increase to above 4 ..mu..A, and with the Stretcher to about 8-10 ..mu..A, an order of magnitude higher than now. 5 refs., 9 figs.

  9. Structure and vibrational modes of AgI-doped AsSe glasses: Raman scattering and ab initio calculations

    SciTech Connect

    Kostadinova, O.; Chrissanthopoulos, A.; Petkova, T.; Petkov, P.; Yannopoulos, S.N.

    2011-02-15

    We report an investigation of the structure and vibrational modes of (AgI){sub x} (AsSe){sub 100-x}, bulk glasses using Raman spectroscopy and first principles calculations. The short- and medium-range structural order of the glasses was elucidated by analyzing the reduced Raman spectra, recorded at off-resonance conditions. Three distinct local environments were revealed for the AsSe glass including stoichiometric-like and As-rich network sub-structures, and cage-like molecules (As{sub 4}Se{sub n}, n=3, 4) decoupled from the network. To facilitate the interpretation of the Raman spectra ab initio calculations are employed to study the geometric and vibrational properties of As{sub 4}Se{sub n} molecular units that are parts of the glass structure. The incorporation of AgI causes appreciable structural changes into the glass structure. AgI is responsible for the population reduction of molecular units and for the degradation of the As-rich network-like sub-structure via the introduction of As-I terminal bonds. Ab initio calculations of mixed chalcohalide pyramids AsSe{sub m}I{sub 3-m} provided useful information augmenting the interpretation of the Raman spectra. -- Graphical abstract: Raman scattering and ab initio calculations are employed to study the structure of AgI-AsSe superionic glasses. The role of mixed chalcohalide pyramidal units as illustrated in the figure is elucidated. Display Omitted Research highlights: {yields} Doping binary As-Se glasses with AgI cause dramatic changes in glass structure. {yields} Raman scattering and ab initio calculations determine changes in short- and medium-range order. {yields} Three local environments exist in AsSe glass including a network sub-structure and cage-like molecules. {yields} Mixed chalcohalide pyramids AsSe{sub m}I{sub 3-m} dominate the AgI-doped glass structure.

  10. Monitoring of Landslides using Repeated Kinematics GPS Observables in Sevketiye Town, Biga Peninsula, Çanakkale, NW Turkey

    NASA Astrophysics Data System (ADS)

    Cuneyt Erenoglu, Ramazan; Akcay, Ozgun; Karaca, Zeki; Erenoglu, Oya; Sengul Uluocak, Ebru; Yucel, Mehmet Ali

    2014-05-01

    through the Biga Peninsula. This pipeline has been damaged due to a landslide occurred in February 2006. It is essential to temporal monitoring of urban areas, transportation and infrastructure facilities against the possibility of landslides. Landslide hazards are evaluated in the earthquake and heavy rainfall processes that are the most important factors triggering landslide, and as a result the size of the hazards is estimated lower than the fact. In Çanakkale, the climate prevails in transition climates of the Mediterranean and Black Sea. So the main source of water in the project areas is meteoric water that is the most important component of the hydrological cycle. Moreover a big earthquake can trigger landslides when the ground is saturated by water in the period of between December and April. There are many landslides depending on the region's high sloping topography. It should be paid attention to aspect of movements of these landslides that could threaten residential areas the long-distance transport network and infrastructure. Conventionally, landslides are monitored by sampling of soil, rock, slope, land cover, underground water level, geology in the field and so on. The purpose of this study is to analyze the spatial and temporal behavior of the landslide located in Şevketiye Town, Çanakkale, NW Turkey. A network consisting of 16 sites has been designed surveyed three times from 2013 to 2014 using GPS. The deformation analysis has been performed in order to model the parameters of movements for the landslides based on the GPS sites using three epochs. The rates of determined deformation are summarized by strains, velocities and also displacements. Thereby, all the landslide region can be easily characterized using the GPS sites of the network. Individual GPS sites showed various statistical properties due to their relative movements. Keywords: Landslide, GPS, Deformation, Monitoring, Strain

  11. Sm3+:Ag NPs assisted modification in absorption features of magnesium tellurite glass

    NASA Astrophysics Data System (ADS)

    Yusoff, N. M.; Sahar, M. R.; Ghoshal, S. K.

    2015-01-01

    Metallic nanoparticles (NPs) assisted enhancements in absorption and emission cross-section of tellurite glass is the present challenge. The influences of samarium (Sm3+) ions and silver (Ag) NPs ratio on physical and optical absorption properties of melt quench synthesized magnesium tellurite glasses are reported. XRD patterns verify the amorphous nature of glasses. Glass density, molar volume and ionic packing fraction are discerned to be in the range of 4.92-5.0 g cm-3, 29.82-30.26 cm3 mol-1 and 0.452-0.446, respectively. Moderate reduction potential of tellurite glass converted Ag1+ to Ag0 via single step process and NPs are formed. TEM image manifest the existence of NPs of average diameter ∼16.94 nm having Gaussian size distribution. The significant changes in structural properties in the presence of Ag NPs are discussed in terms of TeO4 tetrahedra distortion and network depolymerization process. The Sm3+:Ag NPs dependent variation in physical properties are ascribed to the alteration in the number of bridging oxygen to non bridging (NB) one. Enhancement in absorption intensity due to the local field effects of Ag NPs is attributed to the changes in Sm-O bond strength. Optical energy band gap (2.81-3.18 eV) and Urbach energy (0.18-0.24 eV) are found increase and decrease, respectively with the increase of Sm3+:Ag NPs up to 1.33 then quenches and enhances, respectively thereafter which are related to the changes in cross-link and NBO numbers. The FTIR spectra reveal modification in network structures evidenced from vibrational wave-number shifts of TeO4 and TeO3 structural units. The observed notable increase in HOH vibration mode suggests its helpfulness in promoting the absorption of water and light. It is asserted that the physical, optical and structural properties of magnesium tellurite glass can be tuned by controlling Sm3+:Ag NPs.

  12. Association of hepatitis Be antigen (HBeAg) with the core of the hepatitis B virus (HBcAg).

    PubMed

    Slusarczyk, J; Hess, G; Meyer zum Büschenfelde, K H

    1985-02-01

    Three substances (pronase E, sodium dodecylsulfate (SDS) and guanidine hydrochloride) with different chemical actions partially convert HBcAg to HBeAg. This process retains the integrity of the HBcAg particle, which was not different between HBcAg subpopulations, and does not generate HBcAg or HBeAg sub-units. DNA polymerase activity was destroyed by SDS and guanidine hydrochloride, but not by pronase E. Serum HBeAg could not be converted into HBcAg, suggesting that this might be an irreversible process. The data are consistent with the assumption that HBcAg and HBeAg are coded for by the same gene (C gene of the HBV-DNA). PMID:3982243

  13. Evidence for rapid epithermal mineralization and coeval bimodal volcanism, Bruner Au-Ag property, NV USA

    NASA Astrophysics Data System (ADS)

    Baldwin, Dylan

    -ore hydrothermal system is overprinted by Au-Ag stage alteration consisting of proximal quartz + Fe-sericite + pyrite +/- adularia and distal illite-montmorillonite-chlorite (after biotite). The distribution of steam-heated alteration zones and vitrophyre units, along with prominent chemical and textural zonation of veins, suggest that a 400 m vertical section of the epithermal system is now exposed at surface. 40Ar/39Ar geochronology of 3 adularia and 4 volcanic samples identified a rhyolite unit that slightly predates ~16.34 Ma Au-Ag mineralization and mafic magmatism. The proposed timeline for deposit formation is: 21-20 Ma, eruption of locally derived rhyolitic flows; 16.62 Ma, development of new rhyolite flow-dome complex and meteoric-dominated geothermal circulation along N-S structural fabric driven by heat from rhyolite domes; ~16.34 Ma, emplacement of NW trending basalt dikes, followed by violent hydrothermal eruptions, eruption of tuffisite breccia dikes, and Au-Ag mineralization; <16.34 Ma, post-mineral rhyolitic volcanism and normal faulting; and <16 Ma to present, continued faulting and dismemberment of the mineral system. The close spatial and temporal association of veining with coeval volcanic units suggests that Au-Ag-S traveled along similar structure and may have been supplied from the same magma chamber. Deposition of Au and Ag from HS- complexes by boiling appears to have occurred rapidly following closely spaced violent magmatic/hydrothermal eruption events. On a deposit scale, a complex interplay of depth, proximity to dikes, and structural dilatency during Au-Ag stage fluid pulses controlled localization of economic mineralization, which can be highly variable over meter-scale distances. Bruner appears to belong to a small subset of mid-Miocene epithermal deposits in Nevada with low base metal contents and low to no Se, related to calc- alkaline rhyolite flow-dome complexes. Multiple lines of evidence document decoupled sourcing of Al-Si-K-O from Au-Ag

  14. Ternary Ag/epoxy adhesive with excellent overall performance.

    PubMed

    Ji, Yan-Hong; Liu, Yu; Huang, Gui-Wen; Shen, Xiao-Jun; Xiao, Hong-Mei; Fu, Shao-Yun

    2015-04-22

    Excellent electrical conductivity (EC) generally conflicts with high lap shear strength (LSS) for electrically conductive adhesives (ECAs) since EC increases while LSS decreases with increasing conductive filler content. In this work, the ECAs with the excellent overall performance are developed based on the ternary hybrid of Ag microflakes (Ag-MFs), Ag nanospheres (Ag-NSs), and Ag nanowires (Ag-NWs). First, a low silver content adhesive system is determined. Then, the effects of the relative contents of Ag fillers on the EC and the LSS are studied. It is shown that a small amount of Ag-NSs or Ag-NWs can dramatically improve the EC for the Ag-MF/epoxy adhesives. The Ag-NSs and Ag-NWs with appropriate contents have a synergistic effect in improving the EC. Meanwhile, the LSS of the as-prepared adhesive with the appropriate Ag contents reaches an optimal value. Both the EC and the LSS of the as-prepared ternary hybrid ECA with a low content of 40 wt % Ag are higher than those of the commercial ECAs filled with the Ag-MF content over 60 wt %. Finally, the ternary hybrid ECA with the optimal formulation is shown to be promising for printing the radio frequency identification tag antennas as an immediate application example. PMID:25835391

  15. An Ab Initio Study of the Low-Lying Doublet States of AgO and AgS

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Partridge, Harry; Langhoff, Stephen R.

    1990-01-01

    Spectroscopic constants (D(sub o), r(sub e), mu(sub e), T(sub e)) are determined for the doublet states of AgO and AgS below approx. = 30000/cm. Large valence basis sets are employed in conjunction with relativistic effective core potentials (RECPs). Electron correlation is included using the modified coupled-pair functional (MCPF) and multireference configuration interaction (MRCI) methods. The A(sup 2)Sigma(sup +) - X(sup 2)Pi band system is found to occur in the near infrared (approx. = 9000/cm) and to be relatively weak with a radiative lifetime of 900 microns for A(sup 2)Sigma(sup +) (upsilon = 0). The weakly bound C(sup 2)Pi state (our notation), the upper state of the blue system, is found to require high levels of theoretical treatment to determine a quantitatively accurate potential. The red system is assigned as a transition from the C(sup 2)Pi state to the previously unobserved A(sup 2)Sigma(sup +) state. Several additional transitions are identified that should be detectable experimentally. A more limited study is performed for the vertical excitation spectrum of AgS. In addition, a detailed all-electron study of the X(sup 2)Pi and A(sup 2)Sigma(sup +) states of AgO is carried out using large atomic natural orbital (ANO) basis sets. Our best calculated D(sub o) value for AgO is significantly less than the experimental value, which suggests that there may be some systematic error in the experimental determination.

  16. A visible-light-driven core-shell like Ag2S@Ag2CO3 composite photocatalyst with high performance in pollutants degradation.

    PubMed

    Yu, Changlin; Wei, Longfu; Zhou, Wanqin; Dionysiou, Dionysios D; Zhu, Lihua; Shu, Qing; Liu, Hong

    2016-08-01

    A series of Ag2S-Ag2CO3 (4%, 8%, 16%, 32% and 40% Ag2S), Ag2CO3@Ag2S (32%Ag2S) and Ag2S@Ag2CO3 (32%Ag2S) composite photocatalysts were fabricated by coprecipitation or successive precipitation reaction. The obtained catalysts were analyzed by N2 physical adsorption, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, UV-vis diffuse reflectance spectroscopy and photocurrent test. Under visible light irradiation, the influences of Ag2S content and core-shell property on photocatalytic activity and stability were evaluated in studies focused on the degradation of methyl orange (MO) dye, phenol, and bisphenol A. Results showed that excellent photocatalytic performance was obtained over Ag2S/Ag2CO3 composite photocatalysts with respect to Ag2S and Ag2CO3. With optimal content of Ag2S (32 wt%), the Ag2S-Ag2CO3 showed the highest photocatalytic degradation efficiency. Moreover, the structured property of Ag2S/Ag2CO3 greatly influenced the activity. Compared with Ag2S-Ag2CO3 and Ag2CO3@Ag2S, core-shell like Ag2S@Ag2CO3 demonstrated the highest activity and stability. The main reason for the boosting of photocatalytic performance was due to the formation of Ag2S/Ag2CO3 well contacted interface and unique electron structures. Ag2S/Ag2CO3 interface could significantly increase the separation efficiency of the photo-generated electrons (e(-)) and holes (h(+)), and production of OH radicals. More importantly, the low solubility of Ag2S shell could effectively protect the core of Ag2CO3, which further guarantees the stability of Ag2CO3. PMID:27236845

  17. Marine sedimentary record of Meltwater Pulse 1a along the NW Barents Sea continental margin

    NASA Astrophysics Data System (ADS)

    Giulia Lucchi, Renata; Sagnotti, Leonardo; Camerlenghi, Angelo; Macrì, Patrizia; Rebesco, Michele; Pedrosa, Maria Teresa; Giorgetti, Giovanna

    2016-04-01

    The upper continental slope of the Storfjorden-Kveithola Trough Mouth Fans (NW Barents Sea) contains a several m-thick late Pleistocene sequence of plumites composed of laminated mud interbedded with sand/silt layers. Radiocarbon ages revealed that deposition occurred during about 130 years at a very high sedimentation rate of 3.4 cm a-1, at about 7 km from the present shelf break. Palaeomagnetic and rock magnetic analyses confirm the existence of a prominent, short-living sedimentary event. The plumites appear laterally continuous and were correlated with the sedimentary sequences described west of Svalbard and neighbouring glacial depositional systems representing a major event at regional scale appointed to correspond to the deep-sea sedimentary record of Meltwater Pulse-1a. We also present new sedimentological and geochemical insights, and multi-beam data adding information on the palaeoenvironmental characteristics during MWP-1a and ice sheet decay in the NW Barents Sea.

  18. Preliminary Feasibility Assessment of Integrating CCHP with NW Food Processing Plant #1: Modeling Documentation

    SciTech Connect

    Hoffman, Michael G.; Srivastava, Viraj; Wagner, Anne W.; Makhmalbaf, Atefe; Thornton, John

    2014-01-01

    The Pacific Northwest National Laboratory (PNNL) has launched a project funded by the Bonneville Power Association (BPA) to identify strategies for increasing industrial energy efficiency and reducing energy costs of Northwest Food Processors Association (NWFPA) plants through deployment of novel combinations and designs of variable-output combined heat and power (CHP) distributed generation (DG), combined cooling, heating and electric power (CCHP) DG and energy storage systems. Detailed evaluations and recommendations of CHP and CCHP DG systems will be performed for several Northwest (NW) food processing sites. The objective is to reduce the overall energy use intensity of NW food processors by 25% by 2020 and by 50% by 2030, as well as reducing emissions and understanding potential congestion reduction impacts on the transmission system in the Pacific Northwest.

  19. Three-dimensional Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O heterostructures for improving photocatalytic activity

    SciTech Connect

    He, Xiaoyu; Hu, Chenguo; Xi, Yi; Zhang, Kaiyou; Hua, Hao

    2014-02-01

    Highlights: • Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O 3D network heterostructures are prepared via a simple precipitatation method. • Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O networks exhibit much enhanced photocatalytic activity. • High photocatalytic activity is attributed to its heterostructure and 3D architectures. - Abstract: Three-dimensional Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O heterostructures were fabricated by loading Ag{sub 2}O nanoparticles on WO{sub 3}·0.33H{sub 2}O 3D networks via a simple chemical precipitation method. The Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O heterostructures exhibited much enhanced photocatalytic activity for the degradation of methylene blue (MB) under simulated solar light irradiation. The optimal molar ratio of Ag{sub 2}O and WO{sub 3}·0.33H{sub 2}O is 1:2. The outstanding photocatalytic activity of the Ag{sub 2}O/WO{sub 3}·0.33H{sub 2}O can be attributed to its large surface area of the three-dimensional networks, the enhanced sunlight absorption and the prevention of electrons–holes combination from the heterostructures. The experiment result demonstrates that wide band gap semiconductor (WO{sub 3}·0.33H{sub 2}O) modified by narrow band gap metal oxide (Ag{sub 2}O) with 3D architecture will be an effective route to enhance its photocatalytic activity.

  20. Microwave-assisted hydrothermal synthesis of Ag₂(W(1-x)Mox)O₄ heterostructures: Nucleation of Ag, morphology, and photoluminescence properties.

    PubMed

    Silva, M D P; Gonçalves, R F; Nogueira, I C; Longo, V M; Mondoni, L; Moron, M G; Santana, Y V; Longo, E

    2016-01-15

    Ag2W(1-x)MoxO4 (x=0.0 and 0.50) powders were synthesized by the co-precipitation (drop-by-drop) method and processed using a microwave-assisted hydrothermal method. We report the real-time in situ formation and growth of Ag filaments on the Ag2W(1-x)MoxO4 crystals using an accelerated electron beam under high vacuum. Various techniques were used to evaluate the influence of the network-former substitution on the structural and optical properties, including photoluminescence (PL) emission, of these materials. X-ray diffraction results confirmed the phases obtained by the synthesis methods. Raman spectroscopy revealed significant changes in local order-disorder as a function of the network-former substitution. Field-emission scanning electron microscopy was used to determine the shape as well as dimensions of the Ag2W(1-x)MoxO4 heterostructures. The PL spectra showed that the PL-emission intensities of Ag2W(1-x)MoxO4 were greater than those of pure Ag2WO4, probably because of the increase of intermediary energy levels within the band gap of the Ag2W(1-x)MoxO4 heterostructures, as evidenced by the decrease in the band-gap values measured by ultraviolet-visible spectroscopy. PMID:26361214

  1. Silver(I) complexes in coordination supramolecular system with bulky acridine-based ligands: syntheses, crystal structures, and theoretical investigations on C-H...Ag close interaction.

    PubMed

    Liu, Chun-Sen; Chen, Pei-Quan; Yang, En-Cui; Tian, Jin-Lei; Bu, Xian-He; Li, Zheng-Ming; Sun, Hong-Wei; Lin, Zhenyang

    2006-07-24

    In our efforts to investigate the coordination architectures of transition metals and organic ligands with tailored structures, we have prepared two structurally related rigid bulky acridine-based ligands, 9-[3-(2-pyridyl)pyrazol-1-yl]- acridine (L(1)) and 9-(1-imidazolyl)acridine (L2), and synthesized and characterized four of their Ag(I) complexes, {[AgL1](ClO4)}2 (1), {[AgL1](NO3)}2 (2), [AgL2(2)](ClO4) (3), and {[(Ag3L2(3))(NO3)](NO3)2(H2O)}(infinity) (4). The single-crystal X-ray diffraction analysis shows that the structures of 1 and 2 are similar to each other, with the two intramolecular Ag(I) centers of each complex being encircled by two L1 ligands; this forms a unique boxlike cyclic dimer, which is further linked to form one-dimensional (1D) chains of 1 and a two-dimensional (2D) network of 2 by intermolecular face-to-face pi...pi stacking and/or weak C-H...O hydrogen-bonding interactions, respectively. 3 has a mononuclear structure, which is further assembled into a 2D network via intermolecular Ag...O and pi...pi stacking weak interactions. 4 possesses two different 1D motifs that are further interlinked through interlayer face-to-face pi...pi stacking and Ag...O weak interactions, resulting in a 2D network. It is worth noting that one of the interesting structural features of 1, 2, and 4 is the presence of obvious C-H...M hydrogen-bonding interactions between the Ag centers and some acridine ring H atoms identified by X-ray diffraction on the basis of the van der Waals radii. Furthermore, as a representative example, full geometry optimization on the basis of the experimental structure, the natural bond orbital (NBO), and topological analysis of 1 were carried out by DFT and AIM (Atoms in Molecules) calculations. The total C-H...Ag interaction energy in 1 is estimated to be about 14 kJ/mol. Therefore, this work offers three new rare examples (1, 2, and 4) that exhibit C-H...Ag weak interactions, in which the N donors of the acridine rings coordinate

  2. Double-gated Si NW FET sensors: Low-frequency noise and photoelectric properties

    NASA Astrophysics Data System (ADS)

    Gasparyan, F.; Khondkaryan, H.; Arakelyan, A.; Zadorozhnyi, I.; Pud, S.; Vitusevich, S.

    2016-08-01

    The transport, noise, and photosensitivity properties of an array of silicon nanowire (NW) p+-p-p+ field-effect transistors (FETs) are investigated. The peculiarities of photosensitivity and detectivity are analyzed over a wide spectrum range. The absorbance of p-Si NW shifts to the short wavelength region compared with bulk Si. The photocurrent and photosensitivity reach increased values in the UV range of the spectrum at 300 K. It is shown that sensitivity values can be tuned by the drain-source voltage and may reach record values of up to 2-4 A/W at a wavelength of 300 nm at room temperature. Low-frequency noise studies allow calculating the photodetectivity values, which increase with decreasing wavelength down to 300 nm. We show that the drain current of Si NW biochemical sensors substantially depends on pH value and the signal-to-noise ratio reaches the high value of 105. Increasing pH sensitivity with gate voltage is revealed for certain source-drain currents of pH-sensors based on Si NW FETs. The noise characteristic index decreases from 1.1 to 0.7 with the growth of the liquid gate voltage. Noise behavior is successfully explained in the framework of the correlated number-mobility unified fluctuation model. pH sensitivity increases as a result of the increase in liquid gate voltage, thus giving the opportunity to measure very low proton concentrations in the electrolyte medium at certain values of the liquid gate voltage.

  3. Looking for Larvae Above an Erupting Submarine Volcano, NW Rota-1, Mariana Arc

    NASA Astrophysics Data System (ADS)

    Hanson, M.; Beaulieu, S.; Tunnicliffe, V.; Chadwick, W.; Breuer, E. R.

    2015-12-01

    In 2009 the first marine protected areas for deep-sea hydrothermal vents in U.S. waters were established as part of the Volcanic Unit of the Marianas Trench Marine National Monument. In this region, hydrothermal vents are located along the Mariana Arc and back-arc spreading center. In particular hydrothermal vents are located near the summit of NW Rota-1, an active submarine volcano on the Mariana Arc which was erupting between 2003 through 2010 and ceased as of 2014. In late 2009, NW Rota-1 experienced a massive landslide decimating the habitat on the southern side of the volcano. This presented an enormous natural disturbance to the community. This project looked at zooplankton tow samples taken from the water column above NW Rota-1 in 2010, searching specifically for larvae which have the potential to recolonize the sea floor after such a major disturbance. We focused on samples for which profiles with a MAPR sensor indicated hydrothermal plumes in the water column. Samples were sorted in entirety into coarse taxa, and then larvae were removed for DNA barcoding. Overall zooplankton composition was dominated by copepods, ostracods, and chaetognaths, the majority of which are pelagic organisms. Comparatively few larvae of benthic invertebrates were found, but shrimp, gastropod, barnacle, and polychaete larvae did appear in low numbers in the samples. Species-level identification obtained via genetic barcoding will allow for these larvae to be matched to species known to inhabit the benthic communities at NW Rota-1. Identified larvae will give insight into the organisms which can re-colonize the seafloor vent communities after a disturbance such as the 2009 landslide. Communities at hydrothermal vents at other submarine volcanoes in the Monument also can act as sources for these planktonic, recolonizing larvae. As the microinvertebrate biodiversity in the Monument has yet to be fully characterized, our project also provides an opportunity to better describe both

  4. Hydrological cycles and trends in the NW Argentine Andes since 1940

    NASA Astrophysics Data System (ADS)

    Castino, Fabiana; Bookhagen, Bodo; Strecker, Manfred

    2016-04-01

    Strong spatiotemporal variability characterizes the hydrometeorological pattern in the NW Argentine Andes, draining parts of the most populated and economically important areas of South America. During the summer monsoon season (DJF), the eastern flanks of the central Andes are characterized by deep convection, exposing them to extreme hydrometeorological events. These often result in floods and landslides with disastrous effects on the local populations. Here, we analyze river discharge to explore long-term hydrological variability in NW Argentine Andes and the linked climate controlling processes. We rely on 13 daily river discharge time series relevant to drainage basins spanning several size orders (102-104 km2) starting in 1914 and define different hydro-climate indices both for the mean and the extreme hydrological events. We apply quantile regression to investigate long-term trends and spectral analysis associated with cross-correlation with SST-based climate indices to identify links to large-scale climate variability modes. River discharge presents a pronounced and coherent variability signal in South America, particularly for wide drainage basins, such as the Amazon and Paraná/La Plata rivers, strongly associated to Pacific and Atlantic Oceans Sea Surface Temperature (SST) anomalies (i.e. ENSO, PDO, AMO). Our analysis evidences that in the NW Argentine Andes, mean discharge values are characterized by statistically significant, mostly positive, long-term trends since 1940, whereas the extreme events present a more non-unidirectional trend pattern. Also, coherent multi-annual to multi-decadal cycles characterizing the discharge pattern have been identified, suggesting that processes linked to SST anomaly-modes strongly control the hydrometeorology variability in the NW Argentina Andes.

  5. Airborne radioactivity survey of parts of Savery NW and Savery NE quadrangles, Carbon County, Wyoming

    USGS Publications Warehouse

    Henderson, J.R.

    1954-01-01

    The accompanying map shows the results of an airborne radioactivity survey in 266 square miles of Savery NW and Savery NE quadrangles, Wyoming. This area is part of a larger survey made in southern Carbon and Sweetwater Counties by the U. S. Geological Survey, November 9-24, 1953. The work was undertaken as part of a cooperative program with the U.S. Atomic Energy Commission.

  6. Evidence for an Ancient Buried Landscape on the NW Rim of Hellas Basin, Mars

    NASA Technical Reports Server (NTRS)

    Crown, David A.; Bleamaster, Leslie F., III; Mest, Scott C.; Mustard, John F.; Vincendon, Mathieu

    2010-01-01

    Hellas basin is the largest (2000+ km across) well-preserved impact structure on Mars and its deepest depositional sink [e.g., 1]. The Hellas rim and adjacent highlands are of special interest given the possibility of paleolakes on the basin floor [2-4], recent studies of potential localized fluvial/lacustrine systems [2, 5-17], and evidence for phyllosilicates around and within impact craters north of the basin [18-26]. We are producing a 1:1.5M-scale geologic map of eight MTM quadrangles (-25312, -25307, -25302, -25297, -30312, -30307, -30302, -30297) along Hellas NW rim. The map region (22.5-32.5degS, 45- 65degE) includes a transect across the cratered highlands of Terra Sabaea, the degraded NW rim of Hellas, and basin interior deposits of NW Hellas Planitia. No previous mapping studies have focused on this region, although it has been included in earlier global and regional maps [27-29].

  7. Lithospheric structure beneath NW Iran using regional and teleseismic travel-time tomography

    NASA Astrophysics Data System (ADS)

    Bavali, K.; Motaghi, K.; Sobouti, F.; Ghods, A.; Abbasi, M.; Priestley, K.; Mortezanejad, G.; Rezaeian, M.

    2016-04-01

    We compute a 2-D tomogram using the P wave arrival time readings from a temporary seismic experiment to study the seismic structure of the crust and upper mantle in NW Iran. The study area includes the western margins of the South Caspian Basin (SCB), and the Sahand and Sabalan post-collisional volcanoes in NW Iran. We invert 2780 regional and teleseismic relative P wave arrival times recorded by 23 stations along the seismic profile extending from the western shoreline of the Caspian Sea to Lake Urumieh. Our tomographic results show a higher-velocity region beneath the SCB. The observed higher velocities strongly correlate with the observed positive gravity anomalies over the southwestern margins of the Caspian Sea, suggesting an oceanic like nature for the SCB lithosphere. The tomographic results also show several lower-velocity anomalies in the crust. The Sabalan volcano is underlain by a low-velocity zone in the lower crust, which is most likely thermal in nature. In the Sahand region, the lower velocities are considerably shallower in depth and might be controlled by shallow sedimentary structures, as well as an anomalously warm upper crust. The shallow low-velocity regions are connected with deeper low-velocity zones 60-100 km deep in the upper mantle. This pattern points to a possible mantle source of post-collisional volcanism in NW Iran, i.e. the melting of a subducted slab.

  8. Mercury content and their risk assessment in farmed shrimp Litopenaeus vannamei from NW Mexico.

    PubMed

    Delgado-Alvarez, C G; Ruelas-Inzunza, J; Osuna-López, J I; Voltolina, D; Frías-Espericueta, M G

    2015-01-01

    The main objective of this study was to evaluate the total mercury content in hepatopancreas and edible muscle of the whiteleg shrimp Litopenaeus vannamei cultured along the NW coast of Mexico, and to evaluate the potential human health risk due to their consumption. Samples were obtained between May and June 2010 in 26 shrimp farms from the three most important shrimp-producing states of NW Mexico, and total Hg was analyzed after reduction with SnCl2 in a mercury analyzer. The ranges of Hg concentrations of the hepatopancreas were 0.101±0.03-0.184±0.13 μg g(-1) in Sonora, 0.077±0.055-0.813±0.363 μg g(-1) in Sinaloa and 0.139±0.037-0.791±0.33 μg g(-1) in Nayarit. In the muscle, values were from 0.078±0.02 to 0.539±0.09 μg g(-1) in Sonora, 0.154±0.03-0.861±0.423 μg g(-1) in Sinaloa and 0.121±0.041-1.48±0.44 μg g(-1) in Nayarit. Considering the concentrations of Hg in the muscle and the national consumption rate, shrimp farmed in NW Mexico does not represent a risk for human health (HQ<1). PMID:25303662

  9. Facile synthesis of sunlight-driven AgCI:Ag plasmonic nanophotocatalyst.

    SciTech Connect

    An, C.; Peng, S.; Sun, Y.; Center for Nanoscale Materials; Univ. of Illinois

    2010-06-18

    Highly efficient plasmonic photocatalysts of AgCl:Ag hybrid nanoparticles are successfully synthesized via a one-pot synthetic approach involving a precipitation reaction followed by polyol reduction. The as-synthesized nanoparticles exhibit high catalytic performance under visible light and sunlight for decomposing organics, such as methylene blue.

  10. EXAFS Studies of Bimetallic Ag-Pt and Ag-Pd Nanorods

    SciTech Connect

    Lahiri, D.; Chattopadhyay, S.; Bunker, B.A.; Doudna, C.M.; Bertino, M.F.; Blum, F.; Tokuhiro, A.; Terry, J.

    2008-10-30

    Nanoparticles of Ag-Pt and Ag-Pd with high aspect ratios were synthesized using a radiolysis method. Gamma rays at dose rates below 0.5 kGy/h were used for irradiation. The nanoparticles were characterized by transmission electron microscopy (TEM), optical absorption spectroscopy and x-ray Absorption Fine Structure (XAFS) spectroscopy. Bright field micrographs show that Ag-Pt nanowires are composed of large particles with diameters ranging from 20-30 nm and joined by filaments of diameter between 2-5 nm. The Ag-Pd nanowires have diameters of 20-25 nm and lengths of 1.5 {micro}m. For XAFS measurements, the Pt L3 edge (11.564 keV), Ag K-edge (25.514 keV) and Pd K-edge (24.350 keV) were excited to determine the local structure around the respective atoms in the cluster. The Ag-Pt particles were found to possess a distinct core-shell structure with Pt in the core surrounded by Ag shell, with no indication of alloy formation. However, nanorods of Ag-Pd have formed an alloy for all the alloy compositions.

  11. Charge-transfer interactions between TCNQ and silver clusters Ag20 and Ag13.

    PubMed

    Chen, Jing; Zhang, Hanyu; Liu, Xianhu; Yuan, Chengqian; Jia, Meiye; Luo, Zhixun; Yao, Jiannian

    2016-03-14

    Interactions between tetracyanoquinodimethane (TCNQ) and two typical silver clusters Ag13 and Ag20 are studied by first-principles DFT calculations. Charge transfer (CT) from silver clusters to TCNQ molecules initiates the Ag-N bond formation at selective sites resulting in the formation of different isomers of Ag13-TCNQ and Ag20-TCNQ complexes. We show here a comprehensive spectroscopic analysis for the two CT complexes on the basis of Raman and infrared activities. Furthermore, frontier molecular orbital (FMO) and natural bond orbital (NBO) analysis of the complexes provides a vivid illustration of electron cloud overlap and interactions. The behavior of TCNQ adsorbed on the tetrahedral Ag20 cluster was even found in good agreement with the experimental measurement of TCNQ molecules on a single-crystal Ag(111) surface. This study not only endeavors to clarify the charge-transfer interactions of TCNQ with silver, but also presents a finding of enhanced charge transfer between Ag13 and TCNQ indicating potential for candidate building blocks of granular materials. PMID:26888771

  12. New data for AG haplotype frequencies in Caucasoid populations and selective neutrality of the AG polymorphism.

    PubMed

    Sanchez-Mazas, A; Bütler-Brunner, E; Excoffier, L; Ghanem, N; Ben Salem, M; Breguet, G; Dard, P; Pellegrini, B; Tikkanen, M J; Langaney, A

    1994-02-01

    We present the results of AG antigen typings of three Caucasoid population samples: Lebanese, Tunisians, and Finns. AG haplotype frequencies estimated by maximum-likelihood methods are compared with the frequencies observed in 13 world populations previously tested for AG specificities by computing a genetic distance matrix used in a multivariate analysis. A high degree of polymorphism characterizes the three samples, with 10 haplotypes detected in the Lebanese and 11 haplotypes detected in the Tunisians and Finns; high heterozygosity levels are also present in the three populations. The genetic distance analysis shows that the three populations possess a genetic structure intermediate between those observed in sub-Saharan Africans and in Caucasoids from the Near East and India. This tight correspondence between AG differentiation and geography is confirmed by a highly significant correlation coefficient found between genetic and geographic distances computed worldwide, suggesting that an isolation by distance model of evolution applies to the AG system. The Ewens-Watterson test for selective neutrality on all world populations tested for AG specificities also supports the hypothesis that the AG system behaves like a neutral polymorphism. Overall, the AG differentiation pattern appears to be close to the patterns observed for other serological polymorphisms, such as RH, GM, and HLA, whose evolutionary mechanisms are also discussed. PMID:8157263

  13. Beet Juice-Induced Green Fabrication of Plasmonic AgCl/Ag Nanoparticles

    EPA Science Inventory

    A simple, green, and fast approach (complete within 5 min) was explored for the fabrication of hybrid AgCl/Ag plasmonic nanoparticles under microwave (MW) irradiation. In this method, beet juice served as a reducing reagent, which is an abundant sugar-rich agricultural produce. I...

  14. Ultra-Fast Synthesis for Ag2Se and CuAgSe Thermoelectric Materials

    NASA Astrophysics Data System (ADS)

    DUAN, H. Z.; LI, Y. L.; ZHAO, K. P.; QIU, P. F.; SHI, X.; CHEN, L. D.

    2016-06-01

    Ag2Se and CuAgSe have been recently reported as promising thermoelectric materials at room temperature. The traditional melting-annealing-sintering processes are used to grow Ag2Se and CuAgSe materials with the disadvantages of high costs of energy and time. In this work, phase-pure polycrystalline Ag2Se and CuAgSe compounds were synthesized from raw elemental powders directly by manual mixing followed by spark plasma sintering (MM-SPS) in a few minutes. The influence of SPS heating rate on the phase composition, microstructure, and thermoelectric properties, including Seebeck coefficient, electrical conductivity, and thermal conductivity, were investigated. The zTs of 0.8 at 390 K and 0.6 at 450 K are obtained for Ag2Se and CuAgSe, respectively, which is comparable with the values in the materials prepared by the traditional method. Furthermore, this ultrafast sample synthesis can significantly save material synthesis time and thus has the obvious advantage for large-scale production.

  15. Ultra-sensitive detection of Ag+ ions based on Ag+-assisted isothermal exponential degradation reaction.

    PubMed

    Zhao, Jing; Fan, Qi; Zhu, Sha; Duan, Aiping; Yin, Yongmei; Li, Genxi

    2013-01-15

    Ag(+) ions are greatly toxic to a lot of algae, fungi, viruses and bacteria, which can also induce harmful side-effects to environments and human health. Herein we report an ultra-sensitive method for the selective detection of Ag(+) ions with electrochemical technique based on Ag(+)-assisted isothermal exponential degradation reaction. In the presence of Ag(+), mismatched trigger DNA can transiently bind to template DNA immobilized on an electrode surface through the formation of C-Ag(+)-C base pair, which then initiates the isothermal exponential degradation reaction. As a result, the mismatched trigger DNA may melt off the cleaved template DNA to trigger rounds of elongation and cutting. After the cyclic degradation reactions, removal of the template DNA immobilized on the electrode surface can be efficiently monitored by using electrochemical technique to show the status of the electrode surface, which can be then used to determine the presence of Ag(+). Further studies reveal that the proposed method can be ultra-sensitive to detect Ag(+) at a picomolar level. The selectivity of the detection can also be satisfactory, thus the proposed method for the Ag(+) ions detection may be potentially useful in the future. PMID:22921090

  16. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum

    NASA Astrophysics Data System (ADS)

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-01

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10‑5 Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains.

  17. Noble-metal Ag nanoparticle chains: annealing Ag/Bi superlattice nanowires in vacuum.

    PubMed

    Xu, Shao Hui; Fei, Guang Tao; You, Qiao; Gao, Xu Dong; Huo, Peng Cheng; De Zhang, Li

    2016-09-16

    One-dimensional noble-metal Ag nanoparticle chains have been prepared by electrodepositing Ag/Bi superlattice nanowires in a porous anodic alumina oxide (AAO) template and following an annealing process in vacuum. It is found that Bi, as a sacrificial metal, can be removed completely after annealing at 450 °C with a vacuum degree of 10(-5) Torr. The regulation of particle size, shape and interparticle spacing of Ag NP chains has been realized by adjusting the segment length of the Ag/Bi superlattice nanowires and the annealing condition. With an extension of the annealing time, it is observed that Ag particles display the transform trend from ellipsoid to sphere. Our findings could inspire further investigation on the design and fabrication of metal nanoparticle chains. PMID:27487089

  18. Effect of MWNT electroless Ag plating on field emission properties of MWNT/Ag nanocomposite cathodes

    NASA Astrophysics Data System (ADS)

    Ye, Yun; Guo, Tailiang

    2013-01-01

    Field emission properties of multiwall carbon nanotube (MWNT) electroless Ag plating nanocomposite cathodes fabricated using screen printing were studied. The MWNT was purified and electroless plated with Ag. The results of field emission scanning electron microscopy (FESEM) showed that the morphology of Ag electroless plating on the surface of MWNT depended on the temperature of electroless plating. Experiments showed that the stability of MWNT/Ag nanocomposite cathodes had no more than 10% degradation, achieving a field emission current density of 4.0 mA/cm2 at an applied electric field of 0.5 V/μm for 50 h. The proposed MWNT/Ag nanocomposite cathodes possess good field emission properties and have potential for application in field emission displays.

  19. Strongly visible-light responsive plasmonic shaped AgX:Ag (X = Cl, Br) nanoparticles for reduction of CO2 to methanol

    NASA Astrophysics Data System (ADS)

    An, Changhua; Wang, Jizhuang; Jiang, Wen; Zhang, Meiyu; Ming, Xijuan; Wang, Shutao; Zhang, Qinhui

    2012-08-01

    Plasmonic shaped AgX:Ag (X = Cl, Br) nanoparticles have been synthesized by a facile and versatile glycerol-mediated solution route. The as-prepared AgX:Ag nanoparticles exhibit regular shapes, i.e., cube-tetrapod-like AgCl:Ag nanoparticles and AgBr:Ag nanoplates. Compared with the pristine AgX, AgX:Ag nanocomposites display stronger absorption in the visible region due to the surface plasmon resonance of silver nanoparticles. The calculation of bandgaps and band positions indicates the as-achieved AgX:Ag nanoparticles can be used as a class of potential photocatalyst for the reduction of CO2. For example, reduction of CO2 under visible light irradiation with the assistance of the anisotropic AgX:Ag nanoparticles yields as much as 100 μmol methanol in the products. Furthermore, the AgX:Ag nanoparticles can maintain its structure and activity after 3 runs of reactions. Therefore, the present route opens an avenue to acquire plasmonic photocatalysts for conversion of CO2 into useful organic compounds.Plasmonic shaped AgX:Ag (X = Cl, Br) nanoparticles have been synthesized by a facile and versatile glycerol-mediated solution route. The as-prepared AgX:Ag nanoparticles exhibit regular shapes, i.e., cube-tetrapod-like AgCl:Ag nanoparticles and AgBr:Ag nanoplates. Compared with the pristine AgX, AgX:Ag nanocomposites display stronger absorption in the visible region due to the surface plasmon resonance of silver nanoparticles. The calculation of bandgaps and band positions indicates the as-achieved AgX:Ag nanoparticles can be used as a class of potential photocatalyst for the reduction of CO2. For example, reduction of CO2 under visible light irradiation with the assistance of the anisotropic AgX:Ag nanoparticles yields as much as 100 μmol methanol in the products. Furthermore, the AgX:Ag nanoparticles can maintain its structure and activity after 3 runs of reactions. Therefore, the present route opens an avenue to acquire plasmonic photocatalysts for conversion of CO2

  20. Enhanced thermoelectric performance of CdO : Ag nanocomposites.

    PubMed

    Gao, Linjie; Wang, Shufang; Liu, Ran; Zha, Xinyu; Sun, Niefeng; Wang, Shujie; Wang, Jianglong; Fu, Guangsheng

    2016-07-26

    CdO : Ag nanocomposites with metallic Ag nanoparticles embedded in the polycrystalline CdO matrix were synthesized by the solid-state reaction method. The addition of Ag led to increased grain boundaries of CdO and created numerous CdO/Ag interfaces. By incorporating Ag into the CdO matrix, the power factor was increased which was probably due to the carrier energy filtering effect induced by the enhanced energy-dependent scattering of electrons. In addition, reduced thermal conductivity was also achieved by stronger phonon scattering from grain boundaries, CdO/Ag interfaces and Ag nanoparticles. These concomitant effects resulted in enhanced ZT values for all CdO : Ag nanocomposites, demonstrating that the strategy of introducing metallic Ag nanoparticles into the CdO host was very effective in optimizing the thermoelectric performance. PMID:27411573

  1. Synthesis and characterization of nanostructured Ag on porous titania

    NASA Astrophysics Data System (ADS)

    Wen, Ming; Li, Yanqiong; Zhang, Junmin; Guan, Weiming; Li, Yuncang; Wen, Cui'e.; Hodgson, Peter

    2011-03-01

    In this work, porous titania was prepared on bulk Ti by chemical oxidation, and then nanostructured silver (Ag) was deposited on titania surface by ion beam sputtering. After annealing treatment, Ag/TiO 2 composites were characterized using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results indicated that a nano-porous titania layer with mean pore size of 150 nm and thickness of 1 μm was formed by chemical oxidation at 80 °C for 45 min. There were three Ag species (Ag (0), Ag (1+), and Ag (2+)) on composites surface after annealing treatment, and metallic Ag content achieved maximum value with annealing temperature of 500 °C in air. Ag showed high thermal stability being partly attributed to the inhibiting the diffusion of Ag by the underlying porous titania.

  2. Ag on Si(111) from basic science to application

    SciTech Connect

    Belianinov, Aleksey

    2012-01-01

    In our work we revisit Ag and Au adsorbates on Si(111)-7x7, as well as experiment with a ternary system of Pentacene, Ag and Si(111). Of particular interest to us is the Si(111)-(√3x√3)R30°}–Ag (Ag-Si-√3 hereafter). In this thesis I systematically explore effects of Ag deposition on the Ag-Si-√3 at different temperatures, film thicknesses and deposition fluxes. The generated insight of the Ag system on the Si(111) is then applied to generate novel methods of nanostructuring and nanowire growth. I then extend our expertise to the Au system on the Ag-Si(111) to gain insight into Au-Si eutectic silicide formation. Finally we explore behavior and growth modes of an organic molecule on the Ag-Si interface.

  3. Permeability enhancement during gold mineralization: Evidences from Kestanelik epithermal vein system, NW Turkey

    NASA Astrophysics Data System (ADS)

    Gulyuz, Nilay; Shipton, Zoe; Kuscu, Ilkay; Lord, Richard A.; Gladwell, David R.; Kaymakci, Nuretdin

    2016-04-01

    The most favourable and principal mineral deposition mechanism in low sulphidation epithermal systems is boiling. Mineralization in these systems occurs dominantly as veins and stockworks; therefore, structures play major role in the localization of epithermal fluid flow. Epithermal fluids rise from depth along structural conduits at high temperatures under enough pressure to prevent boiling. When the pressure drops suddenly (for instance, through faulting or any fracturing), boiling occurs, and CO2 and H2S are released to the vapour phase. Change in fluid chemistry due to the boiling causes first the base metals, and then the ore and gangue minerals to deposit in a well-recognized temporal and vertical sequence until all open spaces are filled. Vein infill in epithermal deposits indicate that mineralization is multiphase and associated with repeated and episodic fluid flow rather than a steady-state process. How can permeability enhancement be achieved after deposition of minerals in fractures and faults chokes permeable pathways and restrict fluid flow? Although geochemical aspects of LS epithermal systems are well known, limited studies exist on the permeability enhancement mechanisms in LS epithermal veins. The main aim of the study is to understand the permeability enhancement mechanisms in epithermal gold deposits by focussing on the structures and quartz textures of a well-preserved low sulphidation epithermal quartz vein/breccia system in Lapseki, NW Turkey. We revealed the kinematics of the structure-vein network by mapping the geometries of epithermal quartz veins and associated structures and collecting detailed structural data from them. In addition, we determined the different phases of fluid flow and mineralization with the cross-cutting and structural relationships among them by examining the quartz textures and breccias and mapping their spatial distribution on vein outcrops and in drill cores with the help of thin section analyses. On-going work

  4. Identification of flood events inside karst cavities: Fria Cave (Asturias - NW Spain)

    NASA Astrophysics Data System (ADS)

    Gonzalez Lemos, Saul; Stoll, Heather

    2013-04-01

    Fluvial records may be well preserved in subterranean karst drainage networks and fluvial deposits cemented in speleothems may provide good chronology of past flood events. In several karst systems in Asturias (NW. Spain), moments of extreme precipitation events produce deposits from flood events in the bed and walls of caves which we propose are also recorded in the calcium carbonate stalagmites growing in the cave. The final stretch of the studied cave (Fria Cave), with a development of 360 m in length, intersects a small perennial stream which in our observation has maintained a minimum discharge of about 0.022 m3/s but periodically overflows into the vadose cave passage. Immediately after a flood overflow event, water marks and foam detritus are visible at various levels on the cave walls and corresponding to heights of bottlenecks in overflow drainage through the cave passage. Flood events deposit sand on terraces on the cave wall and move large volumes of sand in the cave bed. These extreme events leave a long-term record in i) wall coloration or water marks on the cave walls; and ii) detrital particles preserved as inclusions inside the stalagmites. Throughout this cave, it is possible to recognize chromatic changes in the walls, such as manganese oxide stains, which coincide with one of the water marks left during a recent flood event. The most salient manganese oxide on the walls rises up to 1.5 m measured from the thalweg and we interpreted it as the result of a frequent process of wetting - drying related to frequent flooding of the cave. Since 3-4 ka, drapery flowstone has been deposited over this oxide coating in some parts of the cave and the drapery remains free of oxide coating. We interpret this as indicating a reduction in the frequency and/or duration of flooding to this height, coincident with a regional drying trend in late Holocene. Stalagmites growing in the bed of the cave appear to trap fluvial sediments like sand or silts particles, which

  5. A stretcher for the Brookhaven AGS

    SciTech Connect

    Foelsche, H.W.J.

    1989-01-01

    This paper summarizes the conceptual design of a 30 GeV Stretcher ring, which is designed to increase the capacity and the quality of the experimental physics program at the AGS. In a typical 3 second operating cycle the AGS now accomplishes two functions: accelerating the beam to full energy and then providing a slow spill on a 30 GeV flattop. These tasks consume approximately equal time. The proposed Stretcher, a dc storage ring, will take up the task of distributing the high energy beam with a continuous slow spill, making it possible for the AGS to provide beam for the program at more than twice the present repetition rate. Thus the average current delivered to the experimenters will be more than doubled, and the duty cycle of the spill will increase from the present optimum of about 40% to nearly 100%. The Stretcher will continue the gradual evolution of the AGS toward a kaon factory. At present, the AGS provides about 1 {mu}A average proton current. A Booster, now under construction, is expected to increase the current to above 4 {mu}a, and the Stretcher to about 8-10 {mu}A, an order of magnitude higher than now. 5 refs., 6 figs., 1 tab.

  6. First-principles study of electronic and dynamic properties of AgMg and AgZn

    NASA Astrophysics Data System (ADS)

    Arıkan, Nihat; Bayhan, Ülkü

    2012-05-01

    The structural, electronic, and phonon properties of AgMg and AgZn in the cesium-chloride phase have been investigated using the density functional theory (DFT) within the local density approximation (LDA). The calculated ground state properties such as lattice constant and bulk modulus agree well with the previous theoretical calculations. The electronic band structure is also presented for AgMg and AgZn. The calculated DOS at the Fermi energy are 0.49{states}/{eV cell} for AgMg and 0.43{states}/{eV cell} for AgZn. A linear-response approach to the density functional theory is used to derive phonon dispersion curves and the total and partial density of states for AgMg and AgZn. The high-frequency region of AgMg is mainly due to the vibrations of Mg atoms.

  7. Spin coating of Ag nanoparticles: Effect of reduction

    SciTech Connect

    Ansari, A. A. Sartale, S. D.

    2014-04-24

    A surfactant free method for the growth of Ag nanoparticles on glass substrate by spin coating of Ag ions solution followed by chemical reduction in aqueous hydrazine hydrate (HyH) solution has been presented. Appearance of surface plasmon resonance confirms the formation of Ag nanoparticles. Morphology and absorbance spectra of Ag nanoparticles films are used to examine effect of hydrazine concentration on the growth of Ag nanoparticles. SEM images show uniformly distributed Ag nanoparticles. Rate constant was found to be dependent on HyH concentration as a consequence influence particle size.

  8. Bipolar Ag-Zn battery

    NASA Astrophysics Data System (ADS)

    Giltner, L. John

    1994-02-01

    The silver-zinc (AgZn) battery system has been unique in its ability to safely satisfy high power demand applications with low mass and volume. However, a new generation of defense, aerospace, and commercial applications will impose even higher power demands. These new power demands can be satisfied by the development of a bipolar battery design. In this configuration the power consuming, interelectrode current conductors are eliminated while the current is then conducted via the large cross-section electrode substrate. Negative and positive active materials are applied to opposite sides of a solid silver foil substrate. In addition to reducing the weight and volume required for a specified power level, the output voltage performance is also improved as follows. Reduced weight through: elimination of the plastic cell container; elimination of plate leads and intercell connector; and elimination of internal plate current collector. Increased voltage through: elimination of resistance of current collector; elimination of resistance of plate lead; and elimination of resistance of intercell connector. EPI worked previously on development of a secondary bipolar silver zinc battery. This development demonstrated the electrical capability of the system and manufacturing techniques. One difficulty with this development was mechanical problems with the seals. However, recent improvements in plastics and adhesives should eliminate the major problem of maintaining a seal around the periphery of the bipolar module. The seal problem is not as significant for a primary battery application or for a requirement for only a few discharge cycles. A second difficulty encountered was with activation (introducing electrolyte into the cell) and with venting gas from the cell without loss of electrolyte. During previous work, the following projections for energy density were made from test data for a high power system which demonstrated in excess of 50 discharge/charge cycles. Projected

  9. Bipolar Ag-Zn battery

    NASA Technical Reports Server (NTRS)

    Giltner, L. John

    1994-01-01

    The silver-zinc (AgZn) battery system has been unique in its ability to safely satisfy high power demand applications with low mass and volume. However, a new generation of defense, aerospace, and commercial applications will impose even higher power demands. These new power demands can be satisfied by the development of a bipolar battery design. In this configuration the power consuming, interelectrode current conductors are eliminated while the current is then conducted via the large cross-section electrode substrate. Negative and positive active materials are applied to opposite sides of a solid silver foil substrate. In addition to reducing the weight and volume required for a specified power level, the output voltage performance is also improved as follows. Reduced weight through: elimination of the plastic cell container; elimination of plate leads and intercell connector; and elimination of internal plate current collector. Increased voltage through: elimination of resistance of current collector; elimination of resistance of plate lead; and elimination of resistance of intercell connector. EPI worked previously on development of a secondary bipolar silver zinc battery. This development demonstrated the electrical capability of the system and manufacturing techniques. One difficulty with this development was mechanical problems with the seals. However, recent improvements in plastics and adhesives should eliminate the major problem of maintaining a seal around the periphery of the bipolar module. The seal problem is not as significant for a primary battery application or for a requirement for only a few discharge cycles. A second difficulty encountered was with activation (introducing electrolyte into the cell) and with venting gas from the cell without loss of electrolyte. During previous work, the following projections for energy density were made from test data for a high power system which demonstrated in excess of 50 discharge/charge cycles. Projected

  10. Template synthesis of Ag/AgCl microrods and their efficient visible light-driven photocatalytic performance

    SciTech Connect

    Chen, Hua; Xiao, Liang; Huang, Jianhua

    2014-09-15

    Highlights: • Preparation ofAg/AgCl microrods by reaction of Ag{sub 2}WO{sub 4} microrods with NaCl solution. • Generation of metallic Ag is induced by the ambient light in the synthesis process. • Ag/AgCl shows excellent visible light-driven photodegradation of organic dyes. - Abstract: Ag/AgCl microrods, aggregated by nanoparticles with a diameter ranging from 100 nm to 2 μm, were prepared by an ion-exchange reaction at 80 °C between Ag{sub 2}WO{sub 4} template and NaCl solution. The existence of metallic Ag species was confirmed by XRD, DRS and XPS measurements. Ag/AgCl microrods showed excellent photocatalytic activity for the degradation of rhodamine B and methylene blue under visible light irradiation. The degradation rate constants of rhodamine B and methylene blue are 0.176 and 0.114 min{sup −1}, respectively. The cycling photodegradation experiments suggest that Ag/AgCl microds could be employed as stable plasmonic photocatalysts for the degradation of organic dyes under visible light irradiation.

  11. Preparation of Ag2O/Ag2CO3/MWNTs composite photocatalysts for enhancement of ciprofloxacin degradation

    NASA Astrophysics Data System (ADS)

    Wang, Huiqin; Li, Jinze; Huo, Pengwei; Yan, Yongsheng; Guan, Qingfeng

    2016-03-01

    The Ag2O/Ag2CO3/multi-walled carbon nanotube (MWNTs) composite photocatalysts were prepared by calcination of the obtained precipitate. The structures and morphology of as-prepared composite photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, X-ray photoelectron spectroscopy (XPS). The Ag2O/Ag2CO3/MWNTs composite photocatalysts exhibit higher degradation rate of ciprofloxacin (CIP) than the pure Ag2CO3, Ag2O/Ag2CO3 and Ag2CO3/MWNTs under visible light irradiation. The amount of loaded Ag2CO3 onto MWNTs and calcined time for Ag2CO3/MWNTs were systematically investigated, and the optimal amount of loaded Ag2CO3 and calcined time of Ag2CO3/MWNTs are 150 wt% and 10 min, respectively. The highest photocatalytic degradation rate of CIP could reach 76% under optimal conditions. The active species trapping experiments were also analyzed, the results show that the holes are main contributor for the degradation processes of CIP, furthermore the electrons, rad O2- and rad OH are also crucially influenced the photocatalytic degradation processes of CIP. The possible photocatalytic processes of CIP with Ag2O/Ag2CO3/MWNTs composite photocatalyst are also proposed.

  12. Crystal structure and properties of tetragonal EuAg{sub 4}In{sub 8} grown by metal flux technique

    SciTech Connect

    Subbarao, Udumula; Sarkar, Sumanta; Peter, Sebastian C.

    2015-03-15

    The compound EuAg{sub 4}In{sub 8} has been obtained as single crystals in high yield from reactions run in liquid indium. X-ray diffraction on single crystals suggests that EuAg{sub 4}In{sub 8} crystallizes in the CeMn{sub 4}Al{sub 8} structure type, tetragonal space group I4/mmm with lattice constants a=b=9.7937(2) Å and c=5.7492(2) Å. Crystal structure of EuAg{sub 4}In{sub 8} is composed of pseudo Frank–Kasper cages occupied by one europium atom in each ring, which are shared through the corner along the ab plane resulting in a three dimensional network. The magnetic susceptibility of EuAg{sub 4}In{sub 8} was measured in the temperature range 2–300 K, which obeyed Curie–Weiss law above 50 K. Magnetic moment value calculated from the fitting indicates the presence of divalent europium, which was confirmed by X-ray absorption near edge spectroscopy. Electrical resistivity measurements suggest that EuAg{sub 4}In{sub 8} is metallic in nature with a probable Fermi liquid behavior at low temperature. - Graphical abstract: The tetragonal EuAg{sub 4}In{sub 8} has been grown as single crystals from reactions run in liquid indium. Magnetic and XANES measurements suggest divalent nature of Eu and resistivity measurements suggest metallic nature. - Highlights: • EuAg{sub 4}In{sub 8} phase having tetragonal phase is grown by metal flux technique. • Magnetic and XANES measurements exhibit divalent nature of Eu in EuAg{sub 4}In{sub 8}. • Resistivity measurement suggests metallic nature and probable Fermi liquid behavior.

  13. Metal-Semiconductor Hybrid Aerogels: Evolution of Optoelectronic Properties in a Low-Dimensional CdSe/Ag Nanoparticle Assembly.

    PubMed

    Nahar, Lamia; Esteves, Richard J Alan; Hafiz, Shopan; Özgür, Ümit; Arachchige, Indika U

    2015-10-27

    Hybrid nanomaterials composed of metal-semiconductor components exhibit unique properties in comparison to their individual counterparts, making them of great interest for optoelectronic applications. Theoretical and experimental studies suggest that interfacial interactions of individual components are of paramount importance to produce hybrid electronic states. The direct cross-linking of nanoparticles (NPs) via controlled removal of the surfactant ligands provides a route to tune interfacial interactions in a manner that has not been thoroughly investigated. Herein, we report the synthesis of CdSe/Ag heteronanostructures (aerogels) via oxidation induced self-assembly of thiol-coated NPs and the evolution of optical properties as a function of composition. Three hybrid systems were investigated, where the first and second excitonic energies of CdSe were matched with plasmonic energy of Au or Ag NPs and Ag hollow NPs. Physical characterization of the aerogels suggests the presence of an interconnected network of hexagonal CdSe and cubic Ag NPs. The optical properties of hybrids were systematically examined through UV-vis, photoluminescence (PL), and time-resolved (TR) PL spectroscopic studies that indicate the generation of alternate radiative decay pathways. A new emission (640 nm) from CdSe/Ag aerogels emerged at Ag loading as low as 0.27%, whereas absorption band tailing and PL quenching effects were observed at higher Ag and Au loading, respectively. The TRPL decay time of the new emission (∼600 ns) is markedly different from those of the band-edge (1.83 ± 0.03 ns) and trap-state (1190 ± 120 ns) emission maxima of phase pure CdSe, supporting the existence of alternate radiative relaxation pathways in sol-gel derived CdSe/Ag hybrids. PMID:26389642

  14. Gate modulation of anodically etched gallium arsenide nanowire random network

    NASA Astrophysics Data System (ADS)

    Aikawa, Shinya; Yamada, Kohei; Asoh, Hidetaka; Ono, Sachiko

    2016-06-01

    Gallium arsenide nanowires (GaAs NWs) formed by anodic etching show an electrically semi-insulating behavior because of charge carrier depletion caused by high interface state density. Here, we demonstrate the gate modulation of an anodically etched GaAs NW random network. By applying a reverse bias voltage after anodic etching of bulk GaAs, hydrogen ion exposure of the depleted NW region occurs, and then the interface state density is possibly decreased owing to the reduction in the amount of excess As generated at the interface between the amorphous Ga2O3 and GaAs layers. Consequently, the drain current of the thin-film transistor (TFT) with the GaAs NW random network was increased and was changed by the gate voltage. In contrast, the random network film remained in the insulator in the absence of reverse electrolysis treatment. The TFT performance is still insufficient but may be improved by optimizing the hydrogen ion exposure conditions.

  15. Variations and origin of the atmospheric pollen of Cannabis detected in the province of Tetouan (NW Morocco): 2008-2010.

    PubMed

    Aboulaich, Nadia; Trigo, M Mar; Bouziane, Hassan; Cabezudo, Baltasar; Recio, Marta; El Kadiri, Mohamed; Ater, Mohammed

    2013-01-15

    Cannabis, also called marihuana or hemp, is a wind-pollinated plant that produces hundreds of flowers on large inflorescences. It is also one of the oldest psychoactive plants known to humanity. Morocco has become one of the main producers of Cannabis resin (hashish), primarily supplying the European market. The aim of this paper is to ascertain whether the atmospheric monitoring of Cannabis pollen can play a role, from a criminological point of view, in the surveillance of Cannabis cultivation in the area of Tetouan (NW Morocco) as well as to estimate pollen emission so that the sensitive population can be warned about the allergic diseases that its pollen can cause. Aerobiological samplings were made with the aid of a Hirst type volumetric trap (Hirst, 1952), which worked uninterruptedly during a 3-year period (2008-2010) according to the methodology proposed by the Spanish Aerobiology Network, the REA. Cannabis pollen was present in the atmosphere of Tetouan mainly from early April to late August, a period in which about 95% of the annual counts were registered. The highest levels were detected in June and July, with concentrations more or less evenly distributed throughout the day with slight increases of 5% between 12:00 and 16:00 h. The strong association between skin test reactivity, respiratory symptoms, and pollination period found by other authors, together with the levels registered, suggests that Cannabis pollen could be a clinically important aeroallergen for sensitive patients. On the other hand, the data obtained could serve as an indicator of the cultivation activity of this species and should be taken into account by the state authorities since they provide strong evidence of the existence of Cannabis crops in the region of Tetouan. PMID:23208276

  16. Morphometric age estimate of the last phase of accelerated uplift in the Kazdag area (Biga Peninsula, NW Turkey)

    NASA Astrophysics Data System (ADS)

    Demoulin, A.; Altin, T. Bayer; Beckers, A.

    2013-11-01

    While the Plio-Quaternary uplift of the Kazdag mountain range (Biga Peninsula, NW Turkey) is generally acknowledged, little is known about its detailed timing. Partly because of this lack of data, the cause of this uplift phase is also debated, being associated either to back-arc extension in the rear of the Hellenic subduction zone, to transpression along the northern edge of the west-moving Anatolian microplate, or to extension driven by gravitational collapse. Here, we perform a morphometric study of the fluvial landscape at the scale of the Biga Peninsula, coupling the recently developed R/SR analysis of the drainage network with concavity and steepness measures of a set of 29 rivers of all sizes. While the dependence of profile concavity on basin size confirms that the landscape of the peninsula is still in a transient state, the spatial distribution of profile steepness values characterized by higher values for streams flowing down from the Kazdag massif shows that the latter undergoes higher uplift rates than the rest of the peninsula. We obtain a SR value of 0.324 ± 0.035 that, according to the relation established by Demoulin (2012), yields an age range of 0.5-1.3 Ma and a most probable value of 0.8 Ma for the time of the last tectonic perturbation in the region. In agreement with the analysis of knickpoint migration in a subset of rivers, this suggests that a pulse of uplift occurred at that time and, corroborated by sparse published observations in the Bayramiç and Çanakkale depressions, that the peninsula was uplifted as a whole from that time. This uplift pulse might have been caused by transient compressive conditions in the Anatolian plate when the Eratosthenes seamount came to subduct beneath the Cyprus arc around the early-to-mid Pleistocene transition (Schattner, 2010).

  17. The role of bacteria in the formation of cold seep carbonates: geological evidence from Monferrato (Tertiary, NW Italy)

    NASA Astrophysics Data System (ADS)

    Cavagna, Simona; Clari, Pierangelo; Martire, Luca

    1999-07-01

    Methane-derived carbonate rocks ( Lucina limestone and Marmorito limestone) crop out in Monferrato (NW Italy) and represent one of the first described examples of rocks produced at fossil cold seeps. These rocks, of Miocene age, consist of strongly carbonate-cemented siliciclastic sediments ranging in grain size from mud to coarse sand. The methane-related origin of Monferrato carbonates is based on: (a) outcrop-scale evidence: patchiness of cementation, chemosymbiotic fossil communities, presence of a network of polyphase carbonate-filled veins not related to tectonics; (b) isotope geochemistry: very depleted δ 13C values, as low as -50‰ PDB; (c) peculiar petrographic features. Diverse microbial communities have been observed in present-day cold seeps. These communities include sulphate-reducing, sulphur-oxidizing and methane-oxidizing bacteria. The present work is focused on the identification and description of fossil evidence of such microbial activity in the Monferrato carbonates. Examples of fossilization of microbial structures are probably represented by pyritic rods and dolomite tubes referable to sulphur-oxidizing and to unspecified bacteria, respectively. Less direct but more abundant evidence has been found through petrographic and SEM studies of seep carbonates. Many features point to the presence of organic clumps or mats capable of trapping sediment and promoting carbonate precipitation: microcrystalline calcite peloids; dolomite crystals with irregular hollow cores; dolomite spheroids with dumbbell-shaped cores; laminated internal sediments lining cavities completely. All these features are interpreted to result from bacterially mediated, sedimentary and diagenetic processes and can therefore be considered as an additional evidence of ancient methane seeps.

  18. Insights on high-grade deformation in quartzo-feldspathic gneisses during the early Variscan exhumation of the Cabo Ortegal nappe, NW Iberia

    NASA Astrophysics Data System (ADS)

    José Fernández, Francisco; Llana-Fúnez, Sergio; Valverde-Vaquero, Pablo; Marcos, Alberto; Castiñeiras, Pedro

    2016-04-01

    High-grade, highly deformed gneisses crop out continuously along the Masanteo peninsula and constitute the upper part of the lower crustal section in the Cabo Ortegal nappe (NW Spain). The rock sequence formed by migmatitic quartzo-feldspathic (qz-fsp) gneisses and mafic rocks records the early Ordovician (ca. 480-488 Ma) injection of felsic dioritic/granodioritic dykes at the base of the qz-fsp gneisses, and Devonian eclogitization (ca. 390.4 ± 1.2 Ma), prior to its exhumation. A SE-vergent ductile thrust constitutes the base of quartzo-feldspathic gneissic unit, incorporating mafic eclogite blocks within migmatitic gneisses. A NW-vergent detachment displaced metasedimentary qz-fsp gneisses over the migmatites. A difference in metamorphic pressure of ca. 0.5 GPa is estimated between both gneissic units. The tectono-metamorphic relationships of the basal ductile thrust and the normal detachment bounding the top of the migmatites indicate that both discrete mechanical contacts were active before the recumbent folding affecting the sequence of gneisses during their final emplacement. The progressive tectonic exhumation from eclogite to greenschist facies conditions occurred over ca. 10 Ma and involved bulk thinning of the high-grade rock sequence in the high pressure and high temperature (HP-HT) Cabo Ortegal nappe. The necessary strain was accommodated by the development of a widespread main foliation, dominated by flattening, that subsequently localized to a network of anastomosing shear bands that evolved to planar shear zones. Qz-fsp gneisses and neighbouring mafic granulites were exhumed at > 3 mm yr-1, and the exhumation path involved a cooling of ˜ 20 °C/100 MPa, These figures are comparable to currently active subduction zones, although exhumation P-T trajectory and ascent rates are at the hotter and slower end in comparison with currently active similar settings, suggesting an extremely ductile deformation environment during the exhumation of qz

  19. Mussel-inspired green synthesis of polydopamine-Ag-AgCl composites with efficient visible-light-driven photocatalytic activity.

    PubMed

    Cai, Aijun; Wang, Xiuping; Guo, Aiying; Chang, Yongfang

    2016-09-01

    Polydopamine-Ag-AgCl composites (PDA-Ag-AgCl) were synthesized using a mussel-inspired method at room temperature, where PDA acts as a reducing agent to obtain the noble Ag nanoparticles from a precursor. The morphologies and structures of the as-prepared PDA-Ag-AgCl were characterized by several techniques including field emission scanning electron microscopy (FESEM), transmission electron microscopy (SEM), Raman spectra, and X-Ray photoelectron spectrum (XPS). The morphological observation depicts formation of nanoparticles with various micrometer size diameters and surface XPS analysis shows presence of various elements including Ag, N, Cl, and O. The enhanced absorbance of the PDA-Ag-AgCl particles in the visible light region is confirmed through UV-Vis diffuse reflectance spectra (DRS), and the charge transfer is demonstrated by photoluminescence (PL) and photocurrent response. The synthesized PDA-Ag-AgCl composites could be used as visible-light-driven photocatalysts for the degradation of Rhodamine B. The elevated photocatalytic activity is ascribed to the effective charge transfer from plasmon-excited Ag to AgCl that can improve the efficiency of the charge separation during the photocatalytic reaction. Furthermore, differences in the photocatalytic performance among the different PDA-Ag-AgCl composites are noticed that could be attributed to the Brunauer-Emmett-Teller (BET) specific surface area, which benefits to capture the visible light efficiently. The PDA-Ag-AgCl exhibits excellent stability without a significant loss in activity after 5cycles. The proposed method is low-cost and environmentally friendly, hence a promising new way to fabricate plasmon photocatalysts. PMID:27450302

  20. Effect of cysteine and humic acids on bioavailability of Ag from Ag nanoparticles to a freshwater snail

    USGS Publications Warehouse

    Luoma, Samuel N.; Tasha Stoiber; Croteau, Marie-Noele; Isabelle Romer; Ruth Merrifeild; Jamie Lead

    2016-01-01

    Metal-based engineered nanoparticles (NPs) will undergo transformations that will affect their bioavailability, toxicity and ecological risk when released to the environment, including interactions with dissolved organic material. The purpose of this paper is to determine how interactions with two different types of organic material affect the bioavailability of silver nanoparticles (AgNPs). Silver uptake rates by the pond snail Lymnaea stagnalis were determined after exposure to 25 nmol l-1 of Ag as PVP AgNPs, PEG AgNPs or AgNO3, in the presence of either Suwannee River humic acid or cysteine, a high-affinity thiol-rich organic ligand. Total uptake rate of Ag from the two NPs was either increased or not strongly affected in the presence of 1 – 10 mg 1-1 humic acid. Humic substances contain relatively few strong ligands for Ag explaining their limited effects on Ag uptake rate. In contrast, Ag uptake rate was substantially reduced by cysteine. Three components of uptake from the AgNPs were quantified in the presence of cysteine using a biodynamic modeling approach: uptake of dissolved Ag released by the AgNPs, uptake of a polymer or large (>3kD) Ag-cysteine complex and uptake of the nanoparticle itself. Addition of 1:1 Ag:cysteine reduced concentrations of dissolved Ag, which contributed to, but did not fully explain the reductions in uptake. A bioavailable Ag-cysteine complex (> 3kD) appeared to be the dominant avenue of uptake from both PVP AgNPs and PEG AgNPs in the presence of cysteine. Quantifying the different avenues of uptake sets the stage for studies to assess toxicity unique to NPs.

  1. Sonosynthesis of an Ag/AgBr/Graphene-oxide nanocomposite as a solar photocatalyst for efficient degradation of methyl orange.

    PubMed

    Esmaeili, A; Entezari, M H

    2016-03-15

    In this study, a new method has developed for the synthesis of Ag/AgBr/Graphene-oxide (Ag/AgBr/GO) nanocomposite with high adsorption capacity and high photocatalytic activity in degradation of methyl orange (MO). In this method, ultrasound was applied in the synthesis and it was facilitated the process. The samples prepared under ultrasound were shown as Ag/AgBr/GO-U, and the samples under conventional method as Ag/AgBr/GO-C. The results of FT-IR, XRD, Raman, DRS and SEM confirmed the structure of the nanocomposites very well. Ultrasound played a key role in the formation of nanocomposite with smaller size of GO sheets and particles. Different amount of GO was used in the nanocomposite composition and their photocatalytic activities were compared. The MO in solution was completely degraded in 15 min, 30 min, and 45 min with Ag/AgBr/GO-U-1 that contained 1 mg mL(-1) GO, Ag/AgBr/GO-U-0.5 that contained 0.5 mg mL(-1) GO and Ag/AgBr/GO-C-0.5 that contained 0.5 mg mL(-1) GO, respectively. The chemical oxygen demand (COD) measurements displayed a complete mineralization in 30 min for Ag/AgBr/GO-U-0.5. The data obtained from the degradation experiments were fitted to the first-order kinetics and the adsorption obeyed the Langmuir model. The nanocatalyst did not exhibit significant loss of activity even after four cycles of successive uses. To determine the mechanism of photocatalytic degradation of MO, different scavengers were used. Based on the results, the superoxide radical, hydroxyl radical and hole had a key role in the degradation process. The Ag/AgBr/GO-U-1 nanocomposite exhibited the highest photocatalytic activity due to its high adsorption capacity and enhanced charge transfer. PMID:26724706

  2. Three new Ag(I) coordination architectures based on mixed ligands: Syntheses, structures and photoluminescent properties

    SciTech Connect

    Li, Yamin; Xiao, Changyu; Li, Shu; Chen, Qi; Li, Beibei; Liao, Qian; Niu, Jingyang

    2013-04-15

    Three new silver (I) coordination complexes, [Ag{sub 2}(1,2-bdc)(phdat)]{sub n} (1), [Ag{sub 2}(NO{sub 2}-bdc)(phdat)]{sub n} (2), [Ag{sub 4}(nta){sub 3}(phdat)NO{sub 3}]{sub n} (3) (1,2-bdc=phthalic acid dianion, NO{sub 2}-bdc=5-nitro-1,3-benzenedicarboxylic acid dianion, nta=nicotinic acid anion, phdat=2,4-diamine-6-phenyl-1,3,5-triazine) have been hydrothermally synthesized by the reactions of silver nitrate and phdat with the homologous ligands 1,2-H{sub 2}bdc, NO{sub 2}-H{sub 2}bdc, and Hnta, respectively, and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses thermogravimetric analyses (TGA). The compound 1 exhibits a chiral 3D network with cbs/CrB self-dual topological net, which contains two kinds of single helical chains. For compound 2, the 3D network is comprised of two kinds of similar 2D sheets with the topological symbol of sql-type packed in AABBAA mode by Ag–N/O weakly contacts. And compound 3 has 2D double layer architecture, consisting of the 2D plane with hcb-type topological symbol connected by Ag–O weakly coordinations. The photoluminescent properties associated with the crystal structures of three compounds have also been measured. - Graphical abstract: Three new silver(I) coordination complexes 1–3 have been synthesized and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses, thermogravimetric analyses (TGA) and photoluminescent spectra. Highlights: ► The compound 1 exhibits a novel chiral 3D network with two kinds of single helical chains. ► 3D or 2D new Ag coordination complexes. ► The photoluminescent properties have been measured.

  3. Environmentally friendly ultrosound synthesis and antibacterial activity of cellulose/Ag/AgCl hybrids.

    PubMed

    Dong, Yan-Yan; Deng, Fu; Zhao, Jin-Jin; He, Jing; Ma, Ming-Guo; Xu, Feng; Sun, Run-Cang

    2014-01-01

    This study aims to investigate the fabrication and property of cellulose/Ag/AgCl hybrids. In this article, preparation of cellulose/Ag/AgCl hybrids was reported using the cellulose solution, AgNO₃, AlCl₃·6H₂O with ultrasound agitation method. The cellulose solution was synthesized by the dissolution of the microcrystalline cellulose in NaOH/urea aqueous solution. Influences of the experimental parameters of ultrasound treatment time and ultrasonic intermittent on the hybrids were investigated. The phase, microstructure, thermal stability, and morphology of the hybrids were characterized by X-ray powder diffraction (XRD), Fourier transform infrared (FTIR) spectrometry, thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy (SEM). Results showed the successful synthesis of cellulose/Ag/AgCl hybrids with good thermal stability. Moreover, the hybrids displayed desirable antimicrobial activities. Compared with other conventional methods, the rapid, green, and environmentally friendly ultrasound agitation method opens a new window to the high value-added applications of biomass. PMID:24274493

  4. Ag/FeCo/Ag core/shell/shell magnetic nanoparticles with plasmonic imaging capability.

    PubMed

    Takahashi, Mari; Mohan, Priyank; Nakade, Akiko; Higashimine, Koichi; Mott, Derrick; Hamada, Tsutomu; Matsumura, Kazuaki; Taguchi, Tomohiko; Maenosono, Shinya

    2015-02-24

    Magnetic nanoparticles (NPs) have been used to separate various species such as bacteria, cells, and proteins. In this study, we synthesized Ag/FeCo/Ag core/shell/shell NPs designed for magnetic separation of subcellular components like intracellular vesicles. A benefit of these NPs is that their silver metal content allows plasmon scattering to be used as a tool to observe detection by the NPs easily and semipermanently. Therefore, these NPs are considered a potential alternative to existing fluorescent probes like dye molecules and colloidal quantum dots. In addition, the Ag core inside the NPs suppresses the oxidation of FeCo because of electron transfer from the Ag core to the FeCo shell, even though FeCo is typically susceptible to oxidation. The surfaces of the Ag/FeCo/Ag NPs were functionalized with ε-poly-L-lysine-based hydrophilic polymers to make them water-soluble and biocompatible. The imaging capability of the polymer-functionalized NPs induced by plasmon scattering from the Ag core was investigated. The response of the NPs to a magnetic field using liposomes as platforms and applying a magnetic field during observation by confocal laser scanning microscopy was assessed. The results of the magnetophoresis experiments of liposomes allowed us to calculate the magnetic force to which each liposome was subjected. PMID:25614919

  5. The axisymmetric stellar wind of AG Carinae

    NASA Technical Reports Server (NTRS)

    Schulte-Ladbeck, Regina E.; Clayton, Geoffrey C.; Hillier, D. John; Harries, Tim J.; Howarth, Ian D.

    1994-01-01

    We present optical linear spectropolarimetry of the Luminous Blue Variable AG Carinae obtained after a recent visual brightness increase. The absence of He II lambda 4686 emission, together with the weakening of the He I spectrum and the appearance of Fe lines in the region around 5300 A, confirm that AG Car has started a new excursion across the HR diagram. The H alpha line profile exhibits very extended line wings that are polarized differently in both amount and position angle from either the continuum or the line core. The polarization changes across H alpha, together with variable continuum polarization, indicate the presence of intrinsic polarization. Coexistence of the line-wing polarization with extended flux-line wings evidences that both are formed by electron scattering in a dense wind. The position angle rotates across the line profiles, in a way that presently available models suggest is due to rotation and expansion of the scattering material. AG Car displays very large variations of its linear polarization with time, Delta P approximately 1.2%, indicating significant variations in envelope opacity. We find that the polarization varies along a preferred position angle of approximately 145 deg (with a scatter of +/- 10 deg) which we interpret as a symmetry axis of the stellar wind (with an ambiguity of 90 deg). This position angle is co-aligned with the major axis of the AG Car ring nebula and perpendicular to the AG Car jet. Our observations thus suggest that the axisymmetric geometry seen in the resolved circumstellar environment at various distances already exists within a few stellar radii of AG Car. From the H alpha polarization profile we deduce an interstellar polarization of Q = 0.31%, U = -1.15% at H alpha. The inferred interstellar polarization implies that the intrinsic polarization is not always of the same sign. This indicates either significant temporal changes in the envelope geometry, or it may arise from effects of multiple scattering

  6. One-pot synthesis of ternary Ag₂CO₃/Ag/AgCl photocatalyst in natural geothermal water with enhanced photocatalytic activity under visible light irradiation.

    PubMed

    Yao, Xiaxi; Liu, Xiaoheng

    2014-09-15

    Geothermal water is a clean, cheap and renewable resource and it is widely distributed all over the world. In this work, ternary Ag2CO3/Ag/AgCl photocatalyst has been successfully synthesized via a one-pot precipitation method in natural geothermal water at room temperature, wherein the geothermal water serves as the source of chlorine and carbonate. The results suggest that the Ag/AgCl nanoparticles are anchored on the surface of Ag2CO3 and Ag2CO3/Ag/AgCl composite shows strong absorption ability in the visible light region. The evaluation of the photocatalytic activity indicates that the as-synthesized Ag2CO3/Ag/AgCl photocatalyst exhibits higher photocatalytic performance for the degradation of methylene blue (MB) aqueous solution under visible light irradiation than one-component (Ag2CO3), two-component (Ag/AgCl, Ag2CO3/AgCl) and the mechanical mixture of Ag2CO3 and Ag/AgCl. The trapping experiments confirmed that holes (h(+)) and (•)O2(-) were the two main active species in the photocatalytic process. Finally, a possible Z-scheme photocatalytic mechanism of the charge transfer was proposed for the enhanced photocatalytic performance. This work may open up new insights into the application of cheap geothermal water resources in the word and provide new opportunities for facile fabrication of Ag/AgCl-based photocatalysts. PMID:25164388

  7. Development of an Artificial Gravity Sleeper (AGS)

    NASA Technical Reports Server (NTRS)

    Cardus, David; Mctaggart, Wesley G.; Diamandis, Peter; Campbell, Scott

    1990-01-01

    The design and construction of a 2-meter radius 'human compatible' centrifuge termed the Artificial Gravity Sleeper (AGS) is considered. The centrifuge will accommodate up to four subjects at a time, operate at a broad range of speeds, and have safety features. Experiments that will be conducted on the AGS will help to investigate the quality of sleep during 100 percent gradient centrifugation. A microgravity simulation also will be studied using bed rest to assess the ability of 100 percent gradient centrifugation to function as a countermeasure to cardiovascular deconditioning.

  8. Siberian Snake solenoid for the AGS

    SciTech Connect

    Ratner, L. G.

    1991-01-01

    Recent experiments at the Indiana University Cyclotron Facility (IUCF) have demonstrated that Siberian Snakes'' can be used to preserve the polarization of an accelerated polarized beam in a circular accelerator. Retrofitting full snakes into accelerators such as the Alternating Gradient Synchrotron (AGS) at Brookhaven is almost impossible due to space limitations, but a partial snake that can correct depolarization due to imperfection resonances with 1/20 to 1/30 of a full strength snake seems to present a viable option. We describe such a device for the AGS and give the design criteria in terms of simplicity of accelerator operation and level of achievable polarization. 2 refs., 5 figs., 1 tab.

  9. Polarized proton acceleration at the Brookhaven AGS

    SciTech Connect

    Ahrens, L.A.

    1986-01-01

    At the conclusion of polarized proton commissioning in February 1986, protons with an average polarization of 45%, momentum of 21.7 GeV/c, and intensity of 2 x 10/sup 10/ protons per pulse, were extracted to an external polarimeter at the Brookhaven AGS. In order to maintain this polarization, five intrinsic and nearly forty imperfection depolarizing resonances had to be corrected. An apparent interaction between imperfection and intrinsic resonances occurring at very nearly the same energy was observed and the correction of imperfection resonances using ''beat'' magnetic harmonics discovered in the previous AGS commissioning run was further confirmed.

  10. AG Channel Measurement and Modeling Results for Over-Water and Hilly Terrain Conditions

    NASA Technical Reports Server (NTRS)

    Matolak, David W.; Sun, Ruoyu

    2015-01-01

    This report describes work completed over the past year on our project, entitled "Unmanned Aircraft Systems (UAS) Research: The AG Channel, Robust Waveforms, and Aeronautical Network Simulations." This project is funded under the NASA project "Unmanned Aircraft Systems (UAS) in the National Airspace System (NAS)." In this report we provide the following: an update on project progress; a description of the over-freshwater and hilly terrain initial results on path loss, delay spread, small-scale fading, and correlations; complete path loss models for the over-water AG channels; analysis for obtaining parameter statistics required for development of accurate wideband AG channel models; and analysis of an atypical AG channel in which the aircraft flies out of the ground site antenna main beam. We have modeled the small-scale fading of these channels with Ricean statistics, and have quantified the behavior of the Ricean K-factor. We also provide some results for correlations of signal components, both intra-band and inter-band. An updated literature review, and a summary that also describes future work, are also included.

  11. Electronic structure of crystalline phosphorus pentoxide and the effect of an Ag impurity

    NASA Astrophysics Data System (ADS)

    Abarenkov, I. V.; Tupitsyn, I. I.; Kuznetsov, V. G.; Payne, M. C.

    1999-09-01

    The phosphorus pentoxide crystal with Pnam symmetry containing four P2O5 molecules in the unit cell was calculated by ab initio density-functional theory in the local-density approximation with a plane-wave basis set using the CASTEP code. The calculated optimized geometry is in good agreement with experiment. The population analysis made in terms of Löwdin and Mulliken charges and Wiberg indexes showed that this crystal has a mixed chemical bonding, partly ionic, partly covalent. An Ag atom impurity in the phosphorus pentoxide crystal was investigated within the periodic model. The distortion of the lattice around the impurity was analyzed in terms of PO4 tetrahedra. The calculations showed that in spite of considerable deformation of the lattice, the Ag impurity does not break the P-O bonding network and changes the P-O bond order only a little. The Ag impurity atom is bound to the crystal with an almost pure ionic bond, the Ag atomic charge being 0.6 (Löwdin charge).

  12. Facile synthesis of ternary Ag/AgBr-Ag2CO3 hybrids with enhanced photocatalytic removal of elemental mercury driven by visible light.

    PubMed

    Zhang, Anchao; Zhang, Lixiang; Lu, Hao; Chen, Guoyan; Liu, Zhichao; Xiang, Jun; Sun, Lushi

    2016-08-15

    A novel technique for photocatalytic removal of elemental mercury (Hg(0)) using visible-light-driven Ag/AgBr-Ag2CO3 hybrids was proposed. The ternary Ag/AgBr-Ag2CO3 hybrids were synthesized by a simple modified co-precipitation method and characterized by N2 adsorption-desorption, scanning electron microscope (SEM), X-ray diffraction (XRD), UV-vis diffused reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) techniques. The effects of AgBr content, fluorescent lamp (FSL) irradiation, solution temperature, SO2 and NO on Hg(0) removal were investigated in detail. Furthermore, a possible reaction mechanism for higher Hg(0) removal was proposed, and the simultaneous removal of Hg(0), SO2 and NO was studied. The results showed that a high efficiency of Hg(0) removal was obtained by using Ag/AgBr-Ag2CO3 hybrids under fluorescent lamp irradiation. The AgBr content, FSL irradiation, solution temperature, and SO2 all exhibited significant effects on Hg(0) removal, while NO had slight effect on Hg(0) removal. The addition of Ca(OH)2 demonstrated a little impact on Hg(0) removal and could significantly improve the SO2-resistance performance of Ag/AgBr(0.7)-Ag2CO3 hybrid. The characterization results exhibited that hydroxyl radical (OH), superoxide radical (O2(-)), hole (h(+)), and Br(0), were reactive species responsible for removing Hg(0), and the h(+) played a key role in Hg(0) removal. PMID:27135702

  13. Reducing Strength Prevailing at Root Surface of Plants Promotes Reduction of Ag+ and Generation of Ag0/Ag2O Nanoparticles Exogenously in Aqueous Phase

    PubMed Central

    Pardha-Saradhi, Peddisetty; Yamal, Gupta; Peddisetty, Tanuj; Sharmila, Peddisetty; Nagar, Shilpi; Singh, Jyoti; Nagarajan, Rajamani; Rao, Kottapalli S.

    2014-01-01

    Potential of root system of plants from wide range of families to effectively reduce membrane impermeable ferricyanide to ferrocyanide and blue coloured 2,6-dichlorophenol indophenol (DCPIP) to colourless DCPIPH2 both under non-sterile and sterile conditions, revealed prevalence of immense reducing strength at root surface. As generation of silver nanoparticles (NPs) from Ag+ involves reduction, present investigations were carried to evaluate if reducing strength prevailing at surface of root system can be exploited for reduction of Ag+ and exogenous generation of silver-NPs. Root system of intact plants of 16 species from 11 diverse families of angiosperms turned clear colorless AgNO3 solutions, turbid brown. Absorption spectra of these turbid brown solutions showed silver-NPs specific surface plasmon resonance peak. Transmission electron microscope coupled with energy dispersive X-ray confirmed the presence of distinct NPs in the range of 5–50 nm containing Ag. Selected area electron diffraction and powder X-ray diffraction patterns of the silver NPs showed Bragg reflections, characteristic of crystalline face-centered cubic structure of Ag0 and cubic structure of Ag2O. Root system of intact plants raised under sterile conditions also generated Ag0/Ag2O-NPs under strict sterile conditions in a manner similar to that recorded under non-sterile conditions. This revealed the inbuilt potential of root system to generate Ag0/Ag2O-NPs independent of any microorganism. Roots of intact plants reduced triphenyltetrazolium to triphenylformazon and impermeable ferricyanide to ferrocyanide, suggesting involvement of plasma membrane bound dehydrogenases in reduction of Ag+ and formation of Ag0/Ag2O-NPs. Root enzyme extract reduced triphenyltetrazolium to triphenylformazon and Ag+ to Ag0 in presence of NADH, clearly establishing potential of dehydrogenases to reduce Ag+ to Ag0, which generate Ag0/Ag2O-NPs. Findings presented in this manuscript put forth a novel, simple

  14. The AGS (alternating gradient synchrotron): Performance and potential

    SciTech Connect

    Ratner, L.G.

    1989-01-01

    This report discusses the following topics on the Brookhaven AGS: basic parameters, description of the accelerator complex and proton operation; operation with heavy ions and polarized protons; AGS upgrades and expanded potential. (LSP)

  15. Facile synthesis of novel Ag/AgI/BiOI composites with highly enhanced visible light photocatalytic performances

    SciTech Connect

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Novel Ag/AgI/BiOI composites were controllably synthesized via a facile ion-exchange followed by photoreduction strategy by using hierarchical BiOI microflower as substrate. The as-prepared Ag/AgI/BiOI composites were studied by X-ray powder diffractometer (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) surface area analyzer and UV–vis diffuse reflectance spectroscopy (DRS). Under visible light (λ>420 nm), Ag/AgI/BiOI displayed highly enhanced photocatalytic activities for degradation of methyl orange (MO) compared to the pure hierarchical BiOI, which was mainly ascribed to the highly efficient separation of electrons and holes through the closely contacted interfaces in the Ag/AgI/BiOI ternary system. - Graphical abstract: Ag/AgI/BiOI displayed excellent photocatalytic activities for methyl orange degradation under visible light, which was mainly ascribed to the highly efficient separation of electrons and holes through Z-scheme pathway. Display Omitted - Highlights: • Novel Ag/AgI/BiOI composites were successfully synthesized. • Ag/AgI/BiOI displayed higher visible light activities than those of pure BiOI and AgI. • ·O{sub 2}{sup −} and h{sup +}, especially ·O{sub 2}{sup −}, dominated the photodegradation process of MO. • A Z-scheme pattern was adopted for Ag/AgI/BiOI activity enhancement.

  16. Bifunctional AgCl/Ag composites for SERS monitoring and low temperature visible light photocatalysis degradation of pollutant

    NASA Astrophysics Data System (ADS)

    Dong, Lihong; Zhu, Junyi; Xia, Guangqing

    2014-12-01

    With the assistance of Polyvinylpyrrolidone (PVP), AgCl/Ag composites were fabricated in N, N-Dimethylformamide (DMF) solvent via a photoactivated route. The size of AgCl particles was in the range of 500 nm to 1 μm and the Ag particle's diameter was about 10-20 nm. Different from those core-shell structures reported before, the Ag nanoparticles were dispersed uniformly both on the surface and in the body of AgCl particles. The generation of such kind of composites was resulted from the reducing ability of DMF and light irradiation during the formation of AgCl particles. The as-obtained AgCl/Ag composites presented great activity for both surface-enhanced Raman scattering (SERS) detection and visible light photocatalytic degradation of organic dyes. Additionally, the AgCl/Ag composites could maintain high photocatalytic activity even though the ambient temperature was as low as 15 °C and recycle photocatalysis experiments indicated that the photocatalyst exhibited higher stability. Such kind of AgCl/Ag composites holds great potential for environmental monitoring devices and pollutant treatments.

  17. Photocatalytic activity of undoped and Ag-doped TiO{sub 2}-supported zeolite for humic acid degradation and mineralization

    SciTech Connect

    Lazau, C.; Ratiu, C.; Orha, C.; Pode, R.; Manea, F.

    2011-11-15

    Highlights: {yields} Hybrid materials based on natural zeolite and TiO{sub 2} obtained by solid-state reaction. {yields} XRD proved the presence of anatase form of undoped and Ag-doped TiO{sub 2} onto zeolite. {yields} FT-IR spectra evidenced the presence on TiO{sub 2} bounded at the zeolite network. {yields} Ag-doped TiO{sub 2} onto zeolitic matrix exhibited an enhanced photocatalytic activity. -- Abstract: The hybrid materials based on natural zeolite and undoped and Ag-doped TiO{sub 2}, i.e., Z-Na-TiO{sub 2} and Z-Na-TiO{sub 2}-Ag, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO{sub 2} and Ag-doped TiO{sub 2} nanocrystals were previously synthesized by sol-gel method. The surface characterization of undoped TiO{sub 2}/Ag-doped TiO{sub 2} and natural zeolite hybrid materials has been investigated by X-ray diffraction, DRUV-VIS spectroscopy, FT-IR spectroscopy, BET analysis, SEM microscopy and EDX analysis. The results indicated that anatase TiO{sub 2} is the dominant crystalline type as spherical form onto zeolitic matrix. The presence of Ag into Z-Na-TiO{sub 2}-Ag was confirmed by EDX analysis. The DRUV-VIS spectra showed that Z-Na-TiO{sub 2}-Ag exhibited absorption within the range of 400-500 nm in comparison with Z-Na-TiO{sub 2} catalyst. The enhanced photocatalytic activity of Z-Na-TiO{sub 2}-Ag catalyst is proved through the degradation and mineralization of humic acid under ultraviolet and visible irradiation.

  18. Direct Cross-Linking of Au/Ag Alloy Nanoparticles into Monolithic Aerogels for Application in Surface-Enhanced Raman Scattering.

    PubMed

    Gao, Xiaonan; Esteves, Richard J Alan; Nahar, Lamia; Nowaczyk, Jordan; Arachchige, Indika U

    2016-05-25

    The direct cross-linking of Au/Ag alloy nanoparticles (NPs) into high surface area, mesoporous Au/Ag aerogels via chemical oxidation of the surface ligands is reported. The precursor alloy NPs with composition-tunable morphologies were produced by galvanic replacement of the preformed Ag hollow NPs. The effect of Au:Ag molar ratio on the NP morphology and surface plasmon resonance has been thoroughly investigated and resulted in smaller Au/Ag alloy NPs (4-8 nm), larger Au/Ag alloy hollow NPs (40-45 nm), and Au/Ag alloy hollow particles decorated with smaller Au NPs (2-5 nm). The oxidative removal of surfactant ligands, followed by supercritical drying, is utilized to construct large (centimeter to millimeter) self-supported Au/Ag alloy aerogels. The resultant assemblies exhibit high surface areas (67-73 m(2)/g), extremely low densities (0.051-0.055 g/cm(3)), and interconnected mesoporous (2-50 nm) networks, making them of great interest for a number of new technologies. The influence of mesoporous gel morphology on surface-enhanced Raman scattering (SERS) has been studied using Rhodamine 101 (Rd 101) as the probe molecule. The alloy aerogels exhibit SERS signal intensities that are 10-42 times higher than those achieved from the precursor Au/Ag alloy NPs. The Au/Ag alloy aerogel III exhibits SERS sensing capability down to 1 nM level. The increased signal intensities attained for alloy aerogels are attributed to highly porous gel morphology and enhanced surface roughness that can potentially generate a large number of plasmonic hot spots, creating efficient SERS substrates for future applications. PMID:27142886

  19. The BNL AGS accelerator complex status and future plans

    SciTech Connect

    Tanaka, Mitsuyoshi

    1997-05-01

    This paper describes the present performance and capability of the BNL AGS accelerator complex and possible future intensity upgrade plans. In 1995, the AGS reached its design upgrade goal of 6.0 x 10(exp 13) ppp with the Booster. The AGS with a new fast extracted beam (FEB) system is able to perform single bunch multiple extraction at 30 Hz per AGS cycle for the g-2 experiment and for RHIC injection.

  20. The BNL AGS accelerator complex status and future plans

    SciTech Connect

    Tanaka, Mitsuyoshi

    1997-05-20

    This paper describes the present performance and capability of the BNL AGS accelerator complex and possible future intensity upgrade plans. In 1995, the AGS reached its design upgrade goal of 6.0{center_dot}10{sup 13} ppp with the Booster. The AGS with a new fast extracted beam (FEB) system is able to perform single bunch multiple extraction at 30 Hz per AGS cycle for the g-2 experiment and for RHIC injection.

  1. The BNL AGS accelerator complex status and future plans

    SciTech Connect

    Tanaka, M.

    1997-05-01

    This paper describes the present performance and capability of the BNL AGS accelerator complex and possible future intensity upgrade plans. In 1995, the AGS reached its design upgrade goal of 6.0{center_dot}10{sup 13}ppp with the Booster. The AGS with a new fast extracted beam (FEB) system is able to perform single bunch multiple extraction at 30 Hz per AGS cycle for the g-2 experiment and for RHIC injection. {copyright} {ital 1997 American Institute of Physics.}

  2. Study of structural modification of PVA by incorporating Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Saini, Isha; Sharma, Annu; Rozra, Jyoti; Aggarwal, Sanjeev; Dhiman, Rajnish; Sharma, Pawan K.

    2016-05-01

    Nanocomposites of PVA with Ag nanoparticles dispersed in it were synthesized using solution casting method. The morphology and size distribution of Ag nanoparticles embedded in PVA matrix were obtained by transmission electron microscopy (TEM) and Field emission scanning electron microscopy (FE-SEM). Raman spectroscopy was used to examine structural changes taking place inside polyvinyl alcohol (PVA) matrix due to incorporation of Ag nanoparticle. Raman analysis indicates that Ag nanoparticles interact with PVA through H-bonding.

  3. A multi-wire beam profile monitor in the AGS

    SciTech Connect

    Huang, H.; Buxton, W.; Castillo, V.; Glenn, J.W.

    1997-07-01

    A multi-wire beam profile monitor which can be used to directly monitor and control the optical matching between the Booster and AGS rings has been installed and tested in the AGS. Placement of a multi-wire monitor directly in the AGS provides profile measurements taken upon injection and the first two or more revolutions of the beam. The data from such measurements can be used to determine the optical properties of the beam transport line leading into the AGS.

  4. Development of a Rhizoctonia solani AG1-IB Specific Gene Model Enables Comparative Genome Analyses between Phytopathogenic R. solani AG1-IA, AG1-IB, AG3 and AG8 Isolates.

    PubMed

    Wibberg, Daniel; Rupp, Oliver; Blom, Jochen; Jelonek, Lukas; Kröber, Magdalena; Verwaaijen, Bart; Goesmann, Alexander; Albaum, Stefan; Grosch, Rita; Pühler, Alfred; Schlüter, Andreas

    2015-01-01

    Rhizoctonia solani, a soil-born plant pathogenic basidiomycetous fungus, affects various economically important agricultural and horticultural crops. The draft genome sequence for the R. solani AG1-IB isolate 7/3/14 as well as a corresponding transcriptome dataset (Expressed Sequence Tags--ESTs) were established previously. Development of a specific R. solani AG1-IB gene model based on GMAP transcript mapping within the eukaryotic gene prediction platform AUGUSTUS allowed detection of new genes and provided insights into the gene structure of this fungus. In total, 12,616 genes were recognized in the genome of the AG1-IB isolate. Analysis of predicted genes by means of different bioinformatics tools revealed new genes whose products potentially are involved in degradation of plant cell wall components, melanin formation and synthesis of secondary metabolites. Comparative genome analyses between members of different R. solani anastomosis groups, namely AG1-IA, AG3 and AG8 and the newly annotated R. solani AG1-IB genome were performed within the comparative genomics platform EDGAR. It appeared that only 21 to 28% of all genes encoded in the draft genomes of the different strains were identified as core genes. Based on Average Nucleotide Identity (ANI) and Average Amino-acid Identity (AAI) analyses, considerable sequence differences between isolates representing different anastomosis groups were identified. However, R. solani isolates form a distinct cluster in relation to other fungi of the phylum Basidiomycota. The isolate representing AG1-IB encodes significant more genes featuring predictable functions in secondary metabolite production compared to other completely sequenced R. solani strains. The newly established R. solani AG1-IB 7/3/14 gene layout now provides a reliable basis for post-genomics studies. PMID:26690577

  5. Development of a Rhizoctonia solani AG1-IB Specific Gene Model Enables Comparative Genome Analyses between Phytopathogenic R. solani AG1-IA, AG1-IB, AG3 and AG8 Isolates

    PubMed Central

    Wibberg, Daniel; Rupp, Oliver; Blom, Jochen; Jelonek, Lukas; Kröber, Magdalena; Verwaaijen, Bart; Goesmann, Alexander; Albaum, Stefan; Grosch, Rita; Pühler, Alfred; Schlüter, Andreas

    2015-01-01

    Rhizoctonia solani, a soil-born plant pathogenic basidiomycetous fungus, affects various economically important agricultural and horticultural crops. The draft genome sequence for the R. solani AG1-IB isolate 7/3/14 as well as a corresponding transcriptome dataset (Expressed Sequence Tags—ESTs) were established previously. Development of a specific R. solani AG1-IB gene model based on GMAP transcript mapping within the eukaryotic gene prediction platform AUGUSTUS allowed detection of new genes and provided insights into the gene structure of this fungus. In total, 12,616 genes were recognized in the genome of the AG1-IB isolate. Analysis of predicted genes by means of different bioinformatics tools revealed new genes whose products potentially are involved in degradation of plant cell wall components, melanin formation and synthesis of secondary metabolites. Comparative genome analyses between members of different R. solani anastomosis groups, namely AG1-IA, AG3 and AG8 and the newly annotated R. solani AG1-IB genome were performed within the comparative genomics platform EDGAR. It appeared that only 21 to 28% of all genes encoded in the draft genomes of the different strains were identified as core genes. Based on Average Nucleotide Identity (ANI) and Average Amino-acid Identity (AAI) analyses, considerable sequence differences between isolates representing different anastomosis groups were identified. However, R. solani isolates form a distinct cluster in relation to other fungi of the phylum Basidiomycota. The isolate representing AG1-IB encodes significant more genes featuring predictable functions in secondary metabolite production compared to other completely sequenced R. solani strains. The newly established R. solani AG1-IB 7/3/14 gene layout now provides a reliable basis for post-genomics studies. PMID:26690577

  6. Insights Into the Drainage Characteristics of Pleistocene Ice Sheets in NW Europe Using 3D Seismic Reflection Data.

    NASA Astrophysics Data System (ADS)

    Lonergan, L.; Collier, J. S.; Maidment, S.

    2003-12-01

    We use commercial 3D seismic reflection data to image spectacular, cross-cutting, anastomosing valley systems formed by subglacial meltwater drainage in the Pleistocene of the North Sea, at ~58degN 1degE. Although the seismic data were collected to image deeper structures, the high resolution and quality of the data have allowed us to identify meltwater drainage systems formed at the base of different NW European Pleistocene icesheets in the top 400 ms of the data. The data volume comprises stacked, deconvolved and time migrated data, in 12.5 x 12.5 m bins sampled at 4 ms. The frequency bandwidth is 5-80 Hz (at the 20 dB point), giving a vertical resolution of ~ 8 m and lateral resolution of 12.5 m. Within the 12.5 by 8 km study area, four phases of cross-cutting valley incision can be identified. Individual valleys, which are 30-155m deep and 250-1200m wide, have the irregular longitudinal profile characteristic of meltwater incision under ice sheets. The first three phases are orientated N-S, whilst the youngest, fourth phase valleys and orientated E-W. The fourth phase valleys are also narrower and shallower than the older valleys. We speculate that the successive episodes of valley formation document a history of advance and retreat of an ice-sheet, probably during the Elsterian glaciation of northwest Europe. Detailed mapping of the valley morphology and the geometry of the infill has shown that the valleys were incised by a number of meltwater flow episodes, which were variable energy, probably high velocity and episodic. As a result the valleys were dynamic and long-lived, and they existed as depressions for long periods of time under the ice sheet. When the ice sheet retreated, they were filled with proglacial sediments. From our limited study area it appears that the first of these advances had a N-S orientated drainage network and generated a greater volume of subglacial meltwater than the second, whose drainage network was orientated in a more E

  7. Effect of Ag/Al co-doping method on optically p-type ZnO nanowires synthesized by hot-walled pulsed laser deposition

    PubMed Central

    2012-01-01

    Silver and aluminum-co-doped zinc oxide (SAZO) nanowires (NWs) of 1, 3, and 5 at.% were grown on sapphire substrates. Low-temperature photoluminescence (PL) was studied experimentally to investigate the p-type behavior observed by the exciton bound to a neutral acceptor (A0X). The A0X was not observed in the 1 at.% SAZO NWs by low-temperature PL because 1 at.% SAZO NWs do not have a Ag-O chemical bonding as confirmed by XPS measurement. The activation energies (Ea) of the A0X were calculated to be about 18.14 and 19.77 meV for 3 and 5 at.% SAZO NWs, respectively, which are lower than the activation energy of single Ag-doped NW which is about 25 meV. These results indicate that Ag/Al co-doping method is a good candidate to make optically p-type ZnO NWs. PMID:22647319

  8. AGS experiments -- 1996, 1997, 1998, 1999. Fifteenth edition

    SciTech Connect

    Lo Presti, P.

    1999-03-01

    This report is a compilation of two-page summaries for AGS experiments for FY 1996, FY 1997, FY 1998, FY 1999. The bulk of the experiments are for high energy physics and nuclear physics programs. Also included are the run schedules for the AGS for each of those years and a listing of publications of AGS experiments for 1982--1999.

  9. High Resolution PDF Measurements on Ag Nanoparticles

    SciTech Connect

    Rocha, Tulio C. R.; Martin, Chris; Kycia, Stefan; Zanchet, Daniela

    2009-01-29

    The quantitative analysis of structural defects in Ag nanoparticles was addressed in this work. We performed atomic scale structural characterization by a combination of x-ray diffraction (XRD) using the Pair Distribution Function analysis (PDF) and High Resolution Transmission Electron Microscopy (HRTEM). The XRD measurements were performed using an innovative instrumentation setup to provide high resolution PDF patterns.

  10. Accuracy Assessment for AG500, Electromagnetic Articulograph

    ERIC Educational Resources Information Center

    Yunusova, Yana; Green, Jordan R.; Mefferd, Antje

    2009-01-01

    Purpose: The goal of this article was to evaluate the accuracy and reliability of the AG500 (Carstens Medizinelectronik, Lenglern, Germany), an electromagnetic device developed recently to register articulatory movements in three dimensions. This technology seems to have unprecedented capabilities to provide rich information about time-varying…

  11. Progress in the AGS upgrade projects

    SciTech Connect

    Sluyters, T.J.

    1989-01-01

    The objectives of the AGS Upgrade Project are to prepare the AGS for Booster injection with an increase in the proton intensity to 6 {times} 10{sup 13} particles per pulse for a new generation of experiments on rare K decay, neutrino physics, the (g-2) value of the muon, and many other areas; to increase polarized proton intensity to 10{sup 12} particles per pulse for multi-target spin physics; to accelerate heavy ions up to Au for heavy ion physics; and, of course, to improve the flexibility and reliability of the AGS. High priority has been given to those projects which will reduce, at an early stage, beam losses during injection and acceleration, such as a fast electrostatic beam chopper and a high frequency dilution cavity. Other upgrade programs in progress are: a vacuum overhaul to reduce the AGS operating pressure by a factor of 100; an upgrade of the low and high field magnet correction system; automation of the Siemens main magnet power supply, etc. 3 refs., 2 figs.

  12. Communication: Kinetics of chemical ordering in Ag-Au and Ag-Ni nanoalloys

    NASA Astrophysics Data System (ADS)

    Calvo, F.; Fortunelli, A.; Negreiros, F.; Wales, D. J.

    2013-09-01

    The energy landscape and kinetics of medium-sized Ag-Au and Ag-Ni nanoalloy particles are explored via a discrete path sampling approach, focusing on rearrangements connecting regions differing in chemical order. The highly miscible Ag27Au28 supports a large number of nearly degenerate icosahedral homotops. The transformation from reverse core-shell to core-shell involves large displacements away from the icosahedron through elementary steps corresponding to surface diffusion and vacancy formation. The immiscible Ag42Ni13 naturally forms an asymmetric core-shell structure, and about 10 eV is required to extrude the nickel core to the surface. The corresponding transformation occurs via a long and smooth sequence of surface displacements. For both systems the rearrangement kinetics exhibit Arrhenius behavior. These results are discussed in the light of experimental observations.

  13. Water repellent Ag/Ag2O@bamboo cellulose fiber membrane as bioinspired cargo carriers.

    PubMed

    Wang, Yaru; Zhang, Ximu; Zhang, Xiaofang; Zhao, Jiangqi; Zhang, Wei; Lu, Canhui

    2015-11-20

    Water striders can walk on water. To mimic this function, a porous membrane consisted of bamboo cellulose fiber was hybridized with Ag/Ag2O nanoparticles through a facile in situ method to produce water repellent and well-ventilated materials. Herein, we report the sole surface roughness created by Ag/Ag2O nanoparticles could render the membrane a water contact angle (CA) of 140±3.0°. When floating on water, the hybrid membrane was able to support a heavy load more than 10 times the weight of the membrane itself. Additionally, this membrane demonstrated capabilities for oil sampling under water or oil/water separation and strong antibacterial activity against Escherichia coli. Thus we foresee that this novel hybrid membrane can be potentially utilized as drag-reducing, gas permeable and antibiotic substrates for constructing miniature aquatic devices. PMID:26344306

  14. Selectivity control of photosensitivity of Ag-GaP and Ag- AlGaN structures

    NASA Astrophysics Data System (ADS)

    Lamkin, I. A.; Tarasov, S. A.; Solomonov, A. V.; Andreev, M. Y.; Kurin, S. Yu

    2015-12-01

    Design, growth and studies of photosensitive structures based on Ag-GaP and Ag- AlxGa1-xN contacts are reported. Methods for structure selectivity control, which allow changing the sensitivity spectrum half-width in a range of 11-210 nm were worked out. By varying the metal layer thickness, a set of Ag-GaP short-wavelength photodetectors (PD) was fabricated. The set includes PDs from broadband (spectrum half-width Δλ=210 nm, sensitivity SI = 0,19 A/W) to visible-blind (Δλ=15 nm, SI = 0,034 A/W). The use of Ag-AlxGa1-xN structures provided increased sensitivity (SI = 0,071 A/W) and Δλ reduced to 11 nm due to special selection of solid solution composition.

  15. Antibacterial Ag/a-C nanocomposite coatings: The influence of nano-galvanic a-C and Ag couples on Ag ionization rates

    NASA Astrophysics Data System (ADS)

    Manninen, N. K.; Calderon, S.; Carvalho, I.; Henriques, M.; Cavaleiro, A.; Carvalho, S.

    2016-07-01

    Biofilm formation has been pointed as a major concern in different industrial applications, namely on biomedical implants and surgical instruments, which has prompted the development of new strategies for production of efficient antimicrobial surfaces. In this work, nano-galvanic couples were created to enhance the antibacterial properties of silver, by embedding it into amorphous carbon (a-C) matrix. The developed Ag/a-C nanocomposite coatings, deposited by magnetron sputtering, revealed an outstanding antibacterial activity against Staphylococcus epidermidis, promoting a total reduction in biofilm formation with no bacteria counts in all dilution. The open circuit potential (OCP) tests in 0.9% NaCl confirmed that a-C shows a positive OCP value, in contrast to Ag coating, thus enhancing the ionization of biocidal Ag+ due to the nano-galvanic couple activation. This result was confirmed by the inductively coupled plasma-optical emission spectroscopy (ICP-OES), which revealed a higher Ag ionization rate in the nanocomposite coating in comparison with the Ag coating. The surface of Ag/a-C and Ag coatings immersed in 0.9% NaCl were monitored by scanning electron microscopy (SEM) over a period of 24 h, being found that the Ag ionization determined by ICP-OES was accompanied by an Ag nanoparticles coalescence and agglomeration in Ag/a-C coating.

  16. Fabrication of Sn-3.5Ag Eutectic Alloy Powder by Annealing Sub-Micrometer Sn@Ag Powder Prepared by Citric Acid-Assisted Ag Immersion Plating.

    PubMed

    Chee, Sang-Soo; Choi, Eun Byeol; Lee, Jong-Hyun

    2015-11-01

    A Sn-3.5Ag eutectic alloy powder has been developed by chemically synthesizing sub-micrometer Sn@Ag powder at room temperature. This synthesis was achieved by first obtaining a sub-micrometer Sn powder for the core using a modified variant of the polyol method, and then coating this with a uniformly thin and continuous Ag layer through immersion plating in 5.20 mM citric acid. The citric acid was found to play multiple roles in the Ag coating process, acting as a chelating agent, a reducing agent and a stabilizer to ensure coating uniformity; and as such, the amount used has an immense influence on the coating quality of the Ag shells. It was later verified by transmission electron microscopy and X-ray diffraction analysis that the coated Ag layer transfers to the Sn core via diffusion to form an Ag3Sn phase at room temperature. Differential scanning calorimetry also revealed that the synthesized Sn@Ag powder is nearly transformed into Sn-3.5Ag eutectic alloy powder upon annealing three times at a temperature of up to 250 degrees C, as evidenced by a single melting peak at 220.5 degrees C. It was inferred from this that Sn-3.5Ag eutectic alloy powder can be successfully prepared through the synthesis of core Sn powders by a modified polyol method, immersion plating using citric acid, and annealing, in that order. PMID:26726525

  17. Na2AgF4: 1D antiferromagnet with unusually short Ag2+···Ag2+ separation.

    PubMed

    Kurzydłowski, Dominik; Mazej, Zoran; Grochala, Wojciech

    2013-02-14

    Disodium tetrafluoroargentate(II) (Na(2)AgF(4)) has been synthesized by the thermal decomposition of NaAg(III)F(4) in the presence of NaF. This novel synthetic pathway yielded a high-purity product which enabled determination of the crystal structure and magnetic properties of this compound. The crystal structure of Na(2)AgF(4) contains infinite [AgF(2+4/2)](2-) chains, in analogy to β-K(2)AgF(4), but with a different packing of chains. The unusually short Ag(2+)···Ag(2+) contact of 3.342 Å within the chain is the shortest Ag(2+)···Ag(2+) distance among all structurally characterized compounds of divalent silver. This structural feature is responsible for the 1D antiferromagnetic properties of Na(2)AgF(4) as determined from powder magnetic susceptibility measurements. These findings are rationalized with the aid of calculations of magnetic coupling constants within the framework of the Density Functional Theory including on-site Coulomb repulsion (DFT+U). PMID:23187895

  18. Pollen loads of eucalypt and other pollen types in birds in NW Spain.

    PubMed

    Calviño-Cancela, María; Neumann, Max

    2015-12-01

    Here we present the amount of pollen of eucalypt and pollen of other types for birds captured in two bird ringing stations for 14 months (March 2014 to April 2015) in NW Spain. Common and latin names of all birds species captured, together with the number of captured individuals (N), prevalence of eucalypt pollen (percentage of individuals with eucalypt pollen) and of pollen of other types and average pollen loads per individual for eucalypt and other pollen types is presented. See [1] for further information and discussion. PMID:26568978

  19. Pollen loads of eucalypt and other pollen types in birds in NW Spain

    PubMed Central

    Calviño-Cancela, María; Neumann, Max

    2015-01-01

    Here we present the amount of pollen of eucalypt and pollen of other types for birds captured in two bird ringing stations for 14 months (March 2014 to April 2015) in NW Spain. Common and latin names of all birds species captured, together with the number of captured individuals (N), prevalence of eucalypt pollen (percentage of individuals with eucalypt pollen) and of pollen of other types and average pollen loads per individual for eucalypt and other pollen types is presented. See [1] for further information and discussion. PMID:26568978

  20. The Neo-Tethyan subduction zone(s,?) in Azerbaijan, NW Iran: preliminary results

    NASA Astrophysics Data System (ADS)

    Lechmann, Anna; Burg, Jean-Pierre; Faridi, Mohammad

    2015-04-01

    Azerbaijan in NW Iran, and in particular the Khoy ophiolitic complex, require more detailed documentation to integrate them as elements of the Alpine-Himalayan orogenic belt. They are attributed to multiple accretion and collision after subduction and closure of the Tethys Ocean and related seaways. We are interested in the pre- to syn-collisional relationships between the ophiolitic, arc and other magmatic units. This work investigates to what extent single or multiple collisions and orogeny have shaped the NW Iranian Plateau. In particular, we want to understand the changes in deformation style within the collision zone and the effects of several possibly coeval events such as closure of two suture zones separated by an arc and possibly followed by slab break-off(s). Fieldwork focused on sampling the different magmatic rock units to specify the structural record and the structural relationships between the various lithological units. Cretaceous to Quaternary, regionally distributed magmatic rocks were collected to have good resolution of their changes in space and time. Petrological, geochemical and isotope studies will characterize magmatic rocks and their sources. Major and trace element geochemistry of mantle and crustal suites of the Khoy ophiolitic complex help to constrain the tectonic setting. Two complexes were defined on the basis of K-Ar dating (Khalatbari-Jafari et al., 2004). An older, probably subducted ophiolite of Triassic-Jurassic age and a younger non-metamorphic ophiolite of Late Cretaceous age. Fossil-bearing sediments provide stratigraphic ages of important contacts. Preliminary results are present in form of bulk rock and trace element chemistry of ultramafic and mafic rocks of the Khoy ophiolite(s, ?) and offer a first possibility to compare the data with already existing publications. Additionally, petrological studies of various magmatic rocks present first products for a starting discussion on the geodynamic evolution of the NW part of

  1. Three new species of Pruvotinidae (Mollusca: Solenogastres) from Antarctica and NW Spain

    NASA Astrophysics Data System (ADS)

    Zamarro, Maria; García-Álvarez, Oscar; Urgorri, Victoriano

    2013-09-01

    The family Pruvotinidae (Solenogastres, Cavibelonia) includes thirty species of fifteen genera grouped in five subfamilies. These subfamilies are defined by the combination of the presence or absence of hollow hook-shaped sclerites, the presence or absence of a dorsopharyngeal gland and the type of ventrolateral foregut glandular organs: type A, type C or circumpharyngeal. In this paper, three new species of the family Pruvotinidae are described: Pruvotina artabra n. sp. and Gephyroherpia impar n. sp. from NW Spain, and Pruvotina manifesta n. sp. from Antarctic Peninsula. These new descriptions increase the global knowledge of Solenogastres biodiversity.

  2. Origin of postcollisional intrusions in NW Anatolia, Turkey: Implications for magma chamber processes

    NASA Astrophysics Data System (ADS)

    Aysal, Namık

    2013-04-01

    Post-collisional magmatic activities of NW Anatolia are represented by a series of granitic intrusions and volcanic successions in the Biga Peninsula, NW Turkey. These plutonic rocks have distinct textures, chemical compositions and Sr-Nd isotope characteristics. They consist of coarse grained, equigranular and/or hypidiomorphic textured granite, gronodiorite, monzogranite, quartz-monzonite, pyroxene-monzonite and leucocratic alkali feldspar granites. These intrusions are composed of quartz, K-feldspar, plagioclase, hornblende, pyroxene and biotite. However, leucocratic facies rocks contain tourmaline with minor amount of mafic minerals. Accessory phases are represented by zircon, apatite, monozite, magnetite, sphene and rarely allanite. ASI values of the plutonic rocks vary between 0.7 and 1.24. These intrusive rocks are therefore classified as metaluminous-peraluminous with I-type affinity. K2O contents show that the intrusive rock samples show calc-alkaline, high K-calc-alkaline and shoshonitic character. Initial 87Sr/86Sr(t) (0.69980-0.70835), 143Nd/144Nd(t) (0.51238-0.51247) isotope ratios and negative ɛNd(t) (-4.4 - -2.6) values imply that these intrusive rocks could have been derived from enriched mantle sources. N-MORB normalized spidergrams of NW Anatolian plutonic rocks display enrichments in large ion lithophile elements (LILE), light rare earth elements (LREE) and depletion in high field strength elements (HFSE) indicating hydrous melting of a mantle wedge in a subduction zone and/or enrichment of the mantle source with an inherited subduction component from an ancient arc magmatism. Chondrite-normalized Rare Earth Element spidergrams are indicative of the importance of plagioclase and amphibole fractionation. On tectonic discrimination diagrams, all granite samples fall into the volcanic arc granite, syn and post-collisional granite fields. The geochemical data also indicate that a number of magma chamber processes involving magma mixing, fractional

  3. Groundwater composition near the nickel—copper smelting industry on the Kola Peninsula, central Barents Region (NW Russia and NE Norway)

    NASA Astrophysics Data System (ADS)

    de Caritat, Patrice; Danilova, Svetlana; Jæger, Øystein; Reimann, Clemens; Storrø, Gaute

    1998-07-01

    The chemical composition of 185 groundwater samples collected from two catchments in the extreme NE Norway and NW Russia over the period April 1994 to November 1995 is reported in terms of Ag, Al, As, B, Ba, Be, Bi, Br, Ca, Cd, Cl, Co, Cr, Cu, F, Fe, K, Li, Mg, Mn, Mo, Na, Ni, NO 3, P, Pb, PO 4,Rb, S, Sb, Se, Si, SO 4, Sr, Th, Ti, Tl, U, V and Zn concentrations (as determined by ICP-MS, ICP-AES and IC), pH and electrical conductance. One catchment (C2) is located in Russia 5 km downwind of the nickel—copper ore smelting industry in Monchegorsk, which is a major SO 2 and trace metal emission source, the other (C5) is located in Norway 30 km off-wind from the nickel-copper ore smelter in Nikel and 52 km off-wind from the nickel—copper ore roasting plant of Zapoljarniy, which are also significant emitters of inorganic atmospheric pollutants. Groundwater chemistry mostly reflects the mineralogical composition of the gabbro aquifer in C2 and the Quaternary deposits in C5, although groundwater in C2 also shows signs of incipient contamination from surface waters (heavy metals, sulphate, chloride). Groundwater in C2 appears to have been acidified by S-compounds emitted from Monchegorsk, but the groundwater's capacity to neutralise incoming acidity has not been exhausted. In C5, groundwater has not been acidified to any extent and has a high acid neutralising capacity. This study demonstrates that the geological substrate of a catchment is a fundamental control on how groundwater responds to atmospheric pollution, even if the latter is severe.

  4. A Fabrication Method for Highly Stretchable Conductors with Silver Nanowires.

    PubMed

    Chang, Chia-Wei; Chen, Shih-Pin; Liao, Ying-Chih

    2016-01-01

    Stretchable electronics are identified as a key technology for electronic applications in the next generation. One of the challenges in fabrication of stretchable electronic devices is the preparation of stretchable conductors with great mechanical stability. In this study, we developed a simple fabrication method to chemically solder the contact points between silver nanowire (AgNW) networks. AgNW nanomesh was first deposited on a glass slide via spray coating method. A reactive ink composed of silver nanoparticle (AgNPs) precursors was applied over the spray coated AgNW thin films. After heating for 40 min, AgNPs were preferentially generated over the nanowire junctions to solder the AgNW nanomesh, and reinforced the conducting network. The chemically modified AgNW thin film was then transferred to polyurethane (PU) substrates by casting method. The soldered AgNW thin films on PU exhibited no obvious change in electrical conductivity under stretching or rolling process with elongation strains up to 120%. PMID:26862843

  5. Reversible formation of Ag44 from selenolates

    NASA Astrophysics Data System (ADS)

    Chakraborty, Indranath; Pradeep, T.

    2014-11-01

    The cluster Ag44SePh30, originally prepared from silver selenolate, upon oxidative decomposition by H2O2 gives the same cluster back, in an apparently reversible synthesis. Such an unusual phenomenon was not seen for the corresponding thiolate analogues. From several characterization studies such as mass spectrometry, Raman spectroscopy, etc., it has been confirmed that the degraded and as-synthesized selenolates are the same in nature, which leads to the reversible process. The possibility of making clusters from the degraded material makes cluster synthesis economical. This observation makes one to consider cluster synthesis to be a reversible chemical process, at least for selenolates.The cluster Ag44SePh30, originally prepared from silver selenolate, upon oxidative decomposition by H2O2 gives the same cluster back, in an apparently reversible synthesis. Such an unusual phenomenon was not seen for the corresponding thiolate analogues. From several characterization studies such as mass spectrometry, Raman spectroscopy, etc., it has been confirmed that the degraded and as-synthesized selenolates are the same in nature, which leads to the reversible process. The possibility of making clusters from the degraded material makes cluster synthesis economical. This observation makes one to consider cluster synthesis to be a reversible chemical process, at least for selenolates. Electronic supplementary information (ESI) available: Details of experimental procedures; instrumentation; reversible cycles, UV/Vis spectra of thiophenol, 4-FTP, 3-FTP protected Ag44, and Ag152 cluster; UV/Vis, SEM images and Raman spectra of as-synthesized and degraded thiolates & selenolates; SEM/EDAX of degraded selenolates, UV/Vis of the Ag44(SePh)30 cluster under different selenol concentrations and temperatures. See DOI: 10.1039/c4nr03267e

  6. The Effect of Ag and Ag+N Ion Implantation on Cell Attachment Properties

    NASA Astrophysics Data System (ADS)

    Urkac, Emel Sokullu; Oztarhan, Ahmet; Tihminlioglu, Funda; Gurhan, Ismet Deliloglu; Iz, Sultan Gulce; Oks, Efim; Nikolaev, Alexey; Ila, Daryush

    2009-03-01

    Implanted biomedical prosthetic devices are intended to perform safely, reliably and effectively in the human body thus the materials used for orthopedic devices should have good biocompatibility. Ultra High Molecular Weight Poly Ethylene (UHMWPE) has been commonly used for total hip joint replacement because of its very good properties. In this work, UHMWPE samples were Ag and Ag+N ion implanted by using the Metal-Vapor Vacuum Arc (MEVVA) ion implantation technique. Samples were implanted with a fluency of 1017 ion/cm2 and extraction voltage of 30 kV. Rutherford Backscattering Spectrometry (RBS) was used for surface studies. RBS showed the presence of Ag and N on the surface. Cell attachment properties investigated with model cell lines (L929 mouse fibroblasts) to demonstrate that the effect of Ag and Ag+N ion implantation can favorably influence the surface of UHMWPE for biomedical applications. Scanning electron microscopy (SEM) was used to demonstrate the cell attachment on the surface. Study has shown that Ag+N ion implantation represents more effective cell attachment properties on the UHMWPE surfaces.

  7. Direct observation of two-electron Ag(I)/Ag(III) redox cycles in coupling catalysis.

    PubMed

    Font, Marc; Acuña-Parés, Ferran; Parella, Teodor; Serra, Jordi; Luis, Josep M; Lloret-Fillol, Julio; Costas, Miquel; Ribas, Xavi

    2014-01-01

    Silver is extensively used in homogeneous catalysis for organic synthesis owing to its Lewis acidity, and as a powerful one-electron oxidant. However, two-electron redox catalytic cycles, which are most common in noble metal organometallic reactivity, have never been considered. Here we show that a Ag(I)/Ag(III) catalytic cycle is operative in model C-O and C-C cross-coupling reactions. An aryl-Ag(III) species is unequivocally identified as an intermediate in the catalytic cycle and we provide direct evidence of aryl halide oxidative addition and C-N, C-O, C-S, C-C and C-halide bond-forming reductive elimination steps at monometallic silver centres. We anticipate our study as the starting point for expanding Ag(I)/Ag(III) redox chemistry into new methodologies for organic synthesis, resembling well-known copper or palladium cross-coupling catalysis. Furthermore, findings described herein provide unique fundamental mechanistic understanding on Ag-catalysed cross-coupling reactions and dismiss the generally accepted conception that silver redox chemistry can only arise from one-electron processes. PMID:25014317

  8. A comparative study about electronic structures at rubrene/Ag and Ag/rubrene interfaces

    SciTech Connect

    Sinha, Sumona Mukherjee, M.

    2015-10-15

    The contact between the electrode and the organic semiconductor is one of the most crucial factors in determining the organic device performance. The development and production technology of different organic devices require the understanding of different types of metal/organic semiconducting thin film interfaces. Comparisons about the electronic structures at Rubrene/Ag and Ag/Rubrene interfaces have been studied using photoemission spectroscopy. The Ag on rubrene interfaces is found to show more interesting and complex natures than its counterpart. The vacuum level (VL) was shifted about 0.51 eV from push back effect for deposition of 5 Å rubrene onto Ag film whereas the electronic features of silver was only suppressed and no energy shift was resulted. While the deposition of 5 Å Ag onto rubrene film leads to the diffusion of the Ag atoms, as a cluster with quantum size effect, inside the film. Angle dependent XPS measurement indicates that diffused metal clusters were present at entire probed depth of the film. Moreover these clusters dope the uppermost surface of the rubrene film which consequences a shift of the electronic states of thick organic film towards higher binding energy. The VL was found to shift about 0.31 eV toward higher binding energy whereas the shift was around 0.21 eV for the electronic states of rubrene layer.

  9. Ag induced electromagnetic interference shielding of Ag-graphite/PVDF flexible nanocomposites thinfilms

    SciTech Connect

    Kumaran, R.; Alagar, M.; Dinesh Kumar, S.; Subramanian, V.; Dinakaran, K.

    2015-09-14

    We report Ag nanoparticle induced Electromagnetic Interference (EMI) shielding in a flexible composite films of Ag nanoparticles incorporated graphite/poly-vinylidene difluoride (PVDF). PVDF nanocomposite thin-films were synthesized by intercalating Ag in Graphite (GIC) followed by dispersing GIC in PVDF. The X-ray diffraction analysis and the high-resolution transmission electron microscope clearly dictate the microstructure of silver nanoparticles in graphite intercalated composite of PVDF matrix. The conductivity values of nanocomposites are increased upto 2.5 times when compared to neat PVDF having a value of 2.70 S/cm at 1 MHz. The presence of Ag broadly enhanced the dielectric constant and lowers the dielectric loss of PVDF matrix proportional to Ag content. The EMI shielding effectiveness of the composites is 29.1 dB at 12.4 GHz for the sample having 5 wt. % Ag and 10 wt. % graphite in PVDF.

  10. The Effect of Ag and Ag+N Ion Implantation on Cell Attachment Properties

    SciTech Connect

    Urkac, Emel Sokullu; Oztarhan, Ahmet; Gurhan, Ismet Deliloglu; Iz, Sultan Gulce; Tihminlioglu, Funda; Oks, Efim; Nikolaev, Alexey; Ila, Daryush

    2009-03-10

    Implanted biomedical prosthetic devices are intended to perform safely, reliably and effectively in the human body thus the materials used for orthopedic devices should have good biocompatibility. Ultra High Molecular Weight Poly Ethylene (UHMWPE) has been commonly used for total hip joint replacement because of its very good properties. In this work, UHMWPE samples were Ag and Ag+N ion implanted by using the Metal-Vapor Vacuum Arc (MEVVA) ion implantation technique. Samples were implanted with a fluency of 1017 ion/cm2 and extraction voltage of 30 kV. Rutherford Backscattering Spectrometry (RBS) was used for surface studies. RBS showed the presence of Ag and N on the surface. Cell attachment properties investigated with model cell lines (L929 mouse fibroblasts) to demonstrate that the effect of Ag and Ag+N ion implantation can favorably influence the surface of UHMWPE for biomedical applications. Scanning electron microscopy (SEM) was used to demonstrate the cell attachment on the surface. Study has shown that Ag+N ion implantation represents more effective cell attachment properties on the UHMWPE surfaces.

  11. Effect of Solder-Joint Geometry on the Low-Cycle Fatigue Behavior of Sn-xAg-0.7Cu

    NASA Astrophysics Data System (ADS)

    Lee, Hwa-Teng; Huang, Kuo-Chen

    2016-07-01

    Low-cycle fatigue tests of Sn-Ag-Cu (SAC) Pb-free solder joints under fixed displacement were performed to evaluate the influence of Ag content (0-3 wt.%) and solder-joint geometry (barrel and hourglass types) on solder-joint fatigue behavior and reliability. The solder joints were composed of fine particles of Ag3Sn and Cu6Sn5, which aggregated as an eutectic constituent at grain boundaries of the primary β-Sn phase and formed a dense network structure. A decrease in the Ag content resulted in coarsening of the β-Sn and eutectic phases, which, in turn, decreased the strength of the joint and caused earlier failure. Solder joints in the hourglass form exhibited better fatigue performance with longer life than barrel-type joints. The sharp contact angle formed between the solder and the Cu substrate by the barrel-type joints concentrated stress, which compromised fatigue reliability. The addition of Ag to the solder, however, enhanced fatigue performance because of strengthening caused by Ag3Sn formation. The cracks of the barrel-type SAC solder joints originated mostly at the contact corner and propagated along the interfacial layer between the interfacial intermetallic compound (IMC) and solder matrix. Hourglass-type solder joints, however, demonstrated both crack initiation and propagation in the solder matrix (solder mode). The addition of 1.5-2.0 wt.% Ag to SAC solder appears to enhance the fatigue performance of solder joints while maintaining sufficient strength.

  12. A dry method to synthesize dendritic Ag2Se nanostructures utilizing CdSe quantum dots and Ag thin films.

    PubMed

    Hu, Lian; Zhang, Bingpo; Xu, Tianning; Li, Ruifeng; Wu, Huizhen

    2015-01-01

    Dendritic Ag2Se nanostructures are synthesized in a dry environment by UV irradiating the hybrids composed of CdSe quantum dots (QDs) and silver (Ag). UV irradiation on CdSe QDs induces a photooxidation effect on the QD surface and leads to the formation of SeO2 components. Then SeO2 reacts with the Ag atoms in either Ag film or QD layer to produce the Ag2Se. The growth mechanism of Ag2Se dendrites on solid Ag films is explored and explained by a diffusion limited aggregation model in which the QD layer provides enough freedom for Ag2Se motion. Since the oxidation of the CdSe QDs is the critical step for the Ag2Se dendrites formation this dry chemical interaction between QDs and Ag film can be applied in the study of the QD surface chemical properties. With this dry synthesis method, the Ag2Se dendrites can also be facilely formed at the designed area on Ag substrates. PMID:25483981

  13. A dry method to synthesize dendritic Ag2Se nanostructures utilizing CdSe quantum dots and Ag thin films

    NASA Astrophysics Data System (ADS)

    Hu, Lian; Zhang, Bingpo; Xu, Tianning; Li, Ruifeng; Wu, Huizhen

    2015-01-01

    Dendritic Ag2Se nanostructures are synthesized in a dry environment by UV irradiating the hybrids composed of CdSe quantum dots (QDs) and silver (Ag). UV irradiation on CdSe QDs induces a photooxidation effect on the QD surface and leads to the formation of SeO2 components. Then SeO2 reacts with the Ag atoms in either Ag film or QD layer to produce the Ag2Se. The growth mechanism of Ag2Se dendrites on solid Ag films is explored and explained by a diffusion limited aggregation model in which the QD layer provides enough freedom for Ag2Se motion. Since the oxidation of the CdSe QDs is the critical step for the Ag2Se dendrites formation this dry chemical interaction between QDs and Ag film can be applied in the study of the QD surface chemical properties. With this dry synthesis method, the Ag2Se dendrites can also be facilely formed at the designed area on Ag substrates.

  14. Investigating the properties of infrared PCFs based on AgCl-AgBr, AgBr-TlI, AgCl-AgBr-AgI(TlI) crystals theoretically and experimentally

    NASA Astrophysics Data System (ADS)

    Korsakov, A. S.; Zhukova, L. V.; Vrublevsky, D. S.; Korsakova, E. A.

    2014-12-01

    For operating at the CO2 laser wavelength (10.6 μm), we manufactured single- and double-layered infrared (IR) fibers, as well as those with an enlarged mode field diameter, obtained via extrusion from Ag(Cl) x Br1 - x (0 < x < 1), Ag1 - x Tl x Br1 - x I x (0 < x ≤ 0.08), Ag1 - x Tl x Cl y I z Br1 - y - z (0.003 ≤ x ≤ 0.040; 0.066 ≤ y ≤ 0.246; 0.004 ≤ z ≤ 0.048) crystals. We calculated their fundamental characteristics at 10.6 μm and conducted computer simulation of their structure and mode field beforehand. Optical and mechanical characteristics of IR crystals and fibers, such as transmission range, refractive indices, and durability, were also determined, with the dependence of varying monadic thallium iodide content on them being shown as well. In particular, we demonstrated that the increase of thallium iodide content in the initial silver chloride bromide widens the transparency range to 40 μm and improves the rupture strength up to 200 MPa, which is due to the decrease in average fiber grain size up to 95 nm—nanocrystalline size. Using a CCD camera for the far field investigation at 10.6 μm, we showed the single mode of the fibers obtained.

  15. Enhanced thermal stability of Ag nanorods through capping

    SciTech Connect

    Bachenheimer, Lou; Elliott, Paul; Stagon, Stephen; Huang, Hanchen

    2014-11-24

    Ag nanorods may serve as sensors in the detection of trace amounts of chemical agents, even single molecules, through surface enhanced Raman spectroscopy (SERS). However, thermal coarsening of Ag nanorods near room temperature limits their applications. This letter proposes the use of a thin oxide capping layer to enhance the thermal stability of Ag nanorods beyond 100 °C. Using electron microscopy characterization and SERS tests, the authors show that the proposed method is effective in stabilizing both morphology and sensitivity of Ag nanorods. The results of this work extend the applicability of Ag nanorods as chemical sensors to higher temperatures.

  16. Liquidus Projection and Isothermal Section of the Ag-In-Zn Ternary System

    NASA Astrophysics Data System (ADS)

    Chang, Jui-Shen; Chen, Sinn-wen

    2015-04-01

    This study experimentally determines the liquidus projection and phase equilibria isothermal section at 773.2 K (500°C) of the Ag-In-Zn ternary system. There are ten primary solidification phases of the Ag-In-Zn ternary system. In addition to the (Ag) (In) and (Zn) phases, there are seven binary compounds: β-(Ag3In), ζ-(Ag3In), γ-(Ag9In4), AgIn2, β-(AgZn), γ-(Ag5Zn8), and ɛ-(AgZn3). No ternary compounds were found. Among all these phases, the γ-(Ag9In4) primary solidification phase has the largest compositional regime. Five invariant reactions, two Class I reactions, two Class II reactions, and one Class III reaction, are determined by thermal analysis in this study. The reactions with the lowest and highest reaction temperatures are Liquid = (In) + AgIn2 + γ-(Ag5Zn8) at 413.5 K (140.3°C) and Liquid + (Ag) + β-(AgZn) = ζ-(Ag3In) at 964.9 K (691.7°C), respectively. In the isothermal section at 773.2 K, there are six tie-triangles: (Ag) + ζ-(Ag3In) + β-(AgZn), ζ-(Ag3In) + γ-(Ag9In4) + β-(AgZn), ζ-(Ag3In) + γ-(Ag9In4) + Liquid, γ-(Ag9In4) + β-(AgZn) + Liquid, β-(AgZn) + γ -(Ag5Zn8) + Liquid, and γ-(Ag5Zn8) + ɛ-(AgZn3) + Liquid.

  17. Photocurrent enhancement of SiNW-FETs by integrating protein-shelled CdSe quantum dots

    NASA Astrophysics Data System (ADS)

    Moh, Sang Hyun; Kulkarni, Atul; San, Boi Hoa; Lee, Jeong Hun; Kim, Doyoun; Park, Kwang Su; Lee, Min Ho; Kim, Taesung; Kim, Kyeong Kyu

    2016-01-01

    We proposed a new strategy to increase the photoresponsivity of silicon NW field-effect transistors (FETs) by integrating CdSe quantum dots (QDs) using protein shells (PSs). CdSe QDs were synthesized using ClpP, a bacterial protease, as protein shells to control the size and stability of QD and to facilitate the mounting of QDs on SiNWs. The photocurrent of SiNW-FETs in response to light at a wavelength of 480 nm was enhanced by a factor of 6.5 after integrating CdSe QDs because of the coupling of the optical properties of SiNWs and QDs. As a result, the photoresponsivity to 480 nm light reached up to 3.1 × 106, the highest value compared to other SiNW-based devices in the visible light range.We proposed a new strategy to increase the photoresponsivity of silicon NW field-effect transistors (FETs) by integrating CdSe quantum dots (QDs) using protein shells (PSs). CdSe QDs were synthesized using ClpP, a bacterial protease, as protein shells to control the size and stability of QD and to facilitate the mounting of QDs on SiNWs. The photocurrent of SiNW-FETs in response to light at a wavelength of 480 nm was enhanced by a factor of 6.5 after integrating CdSe QDs because of the coupling of the optical properties of SiNWs and QDs. As a result, the photoresponsivity to 480 nm light reached up to 3.1 × 106, the highest value compared to other SiNW-based devices in the visible light range. Electronic supplementary information (ESI) available: Materials and methods. See DOI: 10.1039/c5nr07901b

  18. Spatial distribution and sources of perfluorochemicals in the NW Mediterranean coastal waters (Catalonia, Spain).

    PubMed

    Sánchez-Avila, Juan; Meyer, Johan; Lacorte, Silvia

    2010-09-01

    This study provides the first evidence of the sources and loads of perfluorochemicals (PFCs) to the NW Mediterranean Sea. Five PFCs were analyzed in 45 seawater samples collected along the Catalan coast. Total PFCs ranged from 0.07 to 13.0 ng/l, being the levels higher in ports than in coastal waters. To determine the sources of PFCs, 8 wastewater treatment plants (WWTPs) effluents and 6 rivers discharging to the sea were also analyzed. WWTP effluents contained total PFCs levels ranging from 3.47 to 132 ng/l but due to the relatively low discharge flows, they contributed to 34.7 g/d to the sea. Total PFCs in rivers ranged from 2.24 to 21.9 ng/l and were the principal PFCs contributors to the sea. Overall, a total load of 190 g/d of PFCs are discharged to the NW Mediterranean coast. The effects and risk of PFCs discharges to the Mediterranean basin are discussed. PMID:20630635

  19. Kashmir Basin Fault and its tectonic significance in NW Himalaya, Jammu and Kashmir, India

    NASA Astrophysics Data System (ADS)

    Shah, A. A.

    2015-10-01

    The Kashmir Basin Fault is located in the Jammu and Kashmir region of Kashmir Basin in NW Himalaya, India. It is a classic example of an out-of-sequence thrust faulting and is tectonically active as observed from multiple geological evidences. Its geomorphology, structure and lateral extent indicate significant accommodation of stress since long, which is further supported by the absence of a large earthquake in this region. It seems this fault is actively accommodating some portion of the total India-Eurasia convergence, apart from two well-recognised active structures the Medlicott-Wadia Thrust and the Main Frontal Thrust, which are referred in Vassallo et al. (Earth Planet Sci Lett 411:241-252, 2015). This requires its quantification and inclusion into slip distribution scheme of NW Himalaya. Therefore, it should be explored extensively because this internal out-of-sequence thrust could serve major seismic hazard in KB, repeating a situation similar to Muzaffarabad earthquake of Northern Pakistan in 2005.

  20. Organic micropollutants in coastal waters from NW Mediterranean Sea: sources distribution and potential risk.

    PubMed

    Sánchez-Avila, Juan; Tauler, Romà; Lacorte, Silvia

    2012-10-01

    This study provides a first estimation on the sources, distribution and risk of organic micropollutants (OMPs) in coastal waters from NW Mediterranean Sea. Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, organochlorinated pesticides, polybrominated diphenyl ethers, phthalates and alkylphenols were analyzed by solid phase extraction and gas chromatography coupled to tandem mass spectrometry (SPE-GC-EI-MS/MS). River waters and wastewater treatment plant effluents discharging to the sea were identified as the main sources of OMPs to coastal waters, with an estimated input amount of around of 25,800 g d(-1). The concentration of ΣOMPs in coastal areas ranged from 17.4 to 8442 ng L(-1), and was the highest in port waters, followed by coastal and river mouth seawaters. A summarized overview of the patterns and sources of OMP contamination on the investigated coastal sea waters of NW Mediterranean Sea, as well as of their geographical distribution was obtained by Principal Component Analysis of the complete data set after its adequate pretreatment. Alkylphenols, bisphenol A and phthalates were the main contributors to ΣOMPs and produced an estimated significant pollution risk for fish, algae and the sensitive mysid shrimp organisms in seawater samples. The combination of GC-MS/MS, chemometrics and risk analysis is proven to be useful for a better control and management of OMP discharges. PMID:22706016

  1. The geostatistical approach for structural and stratigraphic framework analysis of offshore NW Bonaparte Basin, Australia

    NASA Astrophysics Data System (ADS)

    Wahid, Ali; Salim, Ahmed Mohamed Ahmed; Gaafar, Gamal Ragab; Yusoff, Wan Ismail Wan

    2016-02-01

    Geostatistics or statistical approach is based on the studies of temporal and spatial trend, which depend upon spatial relationships to model known information of variable(s) at unsampled locations. The statistical technique known as kriging was used for petrophycial and facies analysis, which help to assume spatial relationship to model the geological continuity between the known data and the unknown to produce a single best guess of the unknown. Kriging is also known as optimal interpolation technique, which facilitate to generate best linear unbiased estimation of each horizon. The idea is to construct a numerical model of the lithofacies and rock properties that honor available data and further integrate with interpreting seismic sections, techtonostratigraphy chart with sea level curve (short term) and regional tectonics of the study area to find the structural and stratigraphic growth history of the NW Bonaparte Basin. By using kriging technique the models were built which help to estimate different parameters like horizons, facies, and porosities in the study area. The variograms were used to determine for identification of spatial relationship between data which help to find the depositional history of the North West (NW) Bonaparte Basin.

  2. A mid-Holocene candidate tsunami deposit from the NW Cape (Western Australia)

    NASA Astrophysics Data System (ADS)

    May, Simon Matthias; Falvard, Simon; Norpoth, Maike; Pint, Anna; Brill, Dominik; Engel, Max; Scheffers, Anja; Dierick, Manuel; Paris, Raphaël; Squire, Peter; Brückner, Helmut

    2016-03-01

    Although extreme-wave events are frequent along the northwestern coast of Western Australia and tsunamis in 1994 and 2006 induced considerable coastal flooding locally, robust stratigraphical evidence of prehistoric tropical cyclones and tsunamis from this area is lacking. Based on the analyses of X-ray computed microtomography (μCT) of oriented sediment cores, multi-proxy sediment and microfaunal analyses, optically stimulated luminescence (OSL) and 14C-AMS dating, this study presents detailed investigations on an allochthonous sand layer of marine origin found in a back-barrier depression on the NW Cape Range peninsula. The event layer consists of material from the adjacent beach and dune, fines and thins inland, and was traced up to ~ 400 m onshore. Although a cyclone-induced origin cannot entirely be ruled out, the particular architecture and fabric of the sediment, rip-up clasts and three subunits point to deposition by a tsunami. As such, it represents the first stratigraphical evidence of a prehistoric, mid-Holocene tsunami in NW Western Australia. It was OSL-dated to 5400-4300 years ago, thus postdating the regional mid-Holocene sea-level highstand.

  3. Formation and distribution of coal measure-derived hydrocarbon accumulation in NW China

    SciTech Connect

    Wenxhi Zhao; Yan Zhang; Dafeng Xu; Changyi Zhao )

    1996-01-01

    This study recognizes that the following conditions are necessary for the Jurassic coal measure-derived oil and gas fields in NW China: (1) The Jurassic original basins, which were dominated by lacustrine to low-positional swamp environments, should exist to accept coal-measure related sediments, (2) the original depositional settings were characterized by low and gentle depressions and humid climate where oil-prone organic materials accumulated, (3) the development of the subsequent basins and successive sedimentation should occur on the Jurassic original basins, which are necessary to keep the coal measure source rocks progressively maturing, and, (4) a certain degree of tectonic compression took place soon after the maturation of source rocks, which provided the driving force for the effective expulsion of oil and gas from coal measures. Most of the coal measure-derived oil gas fields in NW China are horizontally distributed along the inner side of lake strandlines. They occur vertically above or below the threshold of maturation. Owing to the sharp variations of lithology and facies in coal measures, the lithologies and hydrocarbon compositions of oil and gas reservoirs play a significant role in the oil and gas accumulations of the coal measures sequences.

  4. Formation and distribution of coal measure-derived hydrocarbon accumulation in NW China

    SciTech Connect

    Wenxhi Zhao; Yan Zhang; Dafeng Xu; Changyi Zhao

    1996-12-31

    This study recognizes that the following conditions are necessary for the Jurassic coal measure-derived oil and gas fields in NW China: (1) The Jurassic original basins, which were dominated by lacustrine to low-positional swamp environments, should exist to accept coal-measure related sediments, (2) the original depositional settings were characterized by low and gentle depressions and humid climate where oil-prone organic materials accumulated, (3) the development of the subsequent basins and successive sedimentation should occur on the Jurassic original basins, which are necessary to keep the coal measure source rocks progressively maturing, and, (4) a certain degree of tectonic compression took place soon after the maturation of source rocks, which provided the driving force for the effective expulsion of oil and gas from coal measures. Most of the coal measure-derived oil & gas fields in NW China are horizontally distributed along the inner side of lake strandlines. They occur vertically above or below the threshold of maturation. Owing to the sharp variations of lithology and facies in coal measures, the lithologies and hydrocarbon compositions of oil and gas reservoirs play a significant role in the oil and gas accumulations of the coal measures sequences.

  5. The influence of atmospheric circulation types on regional patterns of precipitation in Marmara (NW Turkey)

    NASA Astrophysics Data System (ADS)

    Baltacı, H.; Kındap, T.; Ünal, A.; Karaca, M.

    2015-10-01

    In this study, regional patterns of precipitation in Marmara are described for the first time by means of Ward's hierarchical cluster analysis. Daily values of winter precipitation data based on 19 meteorological stations were used for the period from 1960 to 2012. Five clusters of coherent zones were determined, namely Black Sea-Marmara, Black Sea, Marmara, Thrace, and Aegean sub-regions. To investigate the prevailing atmospheric circulation types (CTs) that cause precipitation occurrence and intensity in these five different rainfall sub-basins, objective Lamb weather type (LWT) methodology was applied to National Centers of Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR) reanalysis of daily mean sea level pressure (MSLP) data. Precipitation occurrence suggested that wet CTs (i.e. N, NE, NW, and C) offer a high chance of precipitation in all sub-regions. For the eastern (western) part of the region, the high probability of rainfall occurrence is shown under the influence of E (SE, S, SW) atmospheric CTs. In terms of precipitation intensity, N and C CTs had the highest positive gradients in all the sub-basins of the Marmara. In addition, although Marmara and Black Sea sub-regions have the highest daily rainfall potential during NE types, high daily rainfall totals are recorded in all sub-regions except the Black Sea during NW types.

  6. Dyking Mechanism and Melting transfer, Misho granitoid Pluton (NW of Iran)

    NASA Astrophysics Data System (ADS)

    Mehri, M.; Mohssen, M.

    2009-04-01

    Misho granitoid pluton are exposed in NW of Misho elevation and SW of Marand depression (Nw of Iran). Mineralogical paragenesis of pluton contain unhedral to sub-hedral quartz, alkaline feldspar (microcline and sub-hedral to unhedral orthoclase), two type biotites, subhedral to euhedral plagioclase (oligoclase to albite), two type zircon, magmatic epidote, sphene and apatite. Pluton, samples show geochemical characteristic of syn - to post - collisional environment, s-type granite and allocktonous. Pluton located in faulted area with Paleozoic respect dating. Source rocks of Pluton are meta - graywake and meta - pelite mixed. One type of zircon and biotite are restitic. Pluton samples have textures that indicate the effect and evidence of pressure syn - crystallization. Field geological, mineralogical and geochemical characteristic of samples from this pluton associated with enclaves riched in mica and shapes of pluton suggest quick arising and dyking mechanism as main mechanism for melt transfer. This caused restitic zircon and biotite remained, there for main mechanism of arising and generation of this pluton are dyking with propagation of fractures so that diaprism process and mechanism have very low role and effect in emplacement and melt transfer of Misho granitoid. Key Words: Misho Pluton, Restitic biotite, Arising mechanism, Dyking

  7. Decadal changes in the distribution of common intertidal seaweeds in Galicia (NW Iberia).

    PubMed

    Piñeiro-Corbeira, Cristina; Barreiro, Rodolfo; Cremades, Javier

    2016-02-01

    Seaweed assemblages in Atlantic Europe are been distorted by global change, but the intricate coastal profile of the area suggests that susceptibility may differ between regions. In particular, NW Iberia is an important omission because no study has systematically assessed long-term changes in a large number of species. Using intertidal surveys for 33 common perennial seaweeds, we show that the average number of species per site declined significantly from 1998-99 to 2014 in NW Iberia. The largest drops in site occupancy were detected in kelps, fucoids, and carrageenan-producing Rhodophyta. Parallel analyses revealed significant upward trends in SST, air temperature, and strong waves; meanwhile, nutrients decreased slightly except in areas affected by local inputs. Similar changes reported for subtidal assemblages in other parts of Atlantic Europe suggest that the drivers may be ubiquitous. Nonetheless, a more proper assessment of both global and local impacts, will require further surveys, and the regular monitoring of intertidal perennial seaweeds appears as a cost-effective alternative to discriminate genuine long-term trends from transitory fluctuations. PMID:26707882

  8. Paleomagnetic investigation of the Early Permian Panjal Traps of NW India; regional tectonic implications

    NASA Astrophysics Data System (ADS)

    Stojanovic, Denis; Aitchison, Jonathan C.; Ali, Jason R.; Ahmad, Talat; Dar, Reyaz Ahmad

    2016-01-01

    The ∼289 Ma Panjal Traps of NW India (Kashmir) are part of a series of rift-related mafic suites (Abor, Sikkim etc.) that were erupted onto northern India (present-day coordinates) around the same time as separation of the Cimmerian blocks of Qiangtang and Sibumasu. We report new data from only the second paleomagnetic investigation of this unit. Standard alternating field and thermal demagnetization methods were used to isolate characteristic magnetizations from seven outcrops at three locations within the Kashmir Valley, NW India. Analysis of four sections (14 individual cooling units) from close to Srinagar, that together form a tectonically coherent sequence spanning ∼3 km of stratigraphy, yield a single-component, primary magnetization with a mean direction of Dec: 134.8°, Inc: 55.3° (α95 = 8.9°, k = 21.0). An inclination-only mean of 52.5° (α95 = 8.9°, k = 47.2) gives a paleolatitude of ∼33°S (±5°). A paleopole of 110.5°E 8.4°S (A95 = 10.7) is also calculated. Assuming the magnetization records a portion of the reverse polarity Kiaman Superchron, the new result indicates extrusion of the Panjal Traps basalts at mid-latitudes in the southern hemisphere. By inference this constrains the location of central Gondwana, and informs debates related to Cimmeria's detachment from Gondwana.

  9. Post-rift unroofing of the NW Africa passive continental margin during the Central Atlantic opening

    NASA Astrophysics Data System (ADS)

    Ghorbal, B.; Bertotti, G.; Andriessen, P. A. M.

    2009-04-01

    Many passive margins considered as being stable for long times, show however late uplift and exhumation at regional scale as assessed by low temperature geochronometry. A large amount of Lower Cretaceous terrigeneous sediments laid down in most of basins along the NW Africa continental margins indicate that a major episode of erosion occurred during early post-rift period in the Central Atlantic. AFT and (U-Th)/He dating performed, along a roughly >500 km N-S transect, on pre-Mesozoic basement rocks from Western Meseta to the Anti-Atlas (Morocco, NW Africa) document a fully unexpected widespread unroofing during the Middle-Late Jurassic to early Late Cretaceous, with AFT and (U-Th)/He ages ranging respectively between 120-170Ma and 115-165Ma. A well documented age cluster of 140±20Ma measured for the Moroccan Meseta, Atlas domains and Anti-Atlas belt designates those domains as potentially being the source areas of the detritic sediments considering the proximity of the depositional basins. Absence of major fault separating the Anti-Atlas from the rest of the Western African Craton during the Mesozoic suggests the unroofing region to extend further in Morocco, as far south as the Reguibat (Mauritania) or even New Guinea, documented by our investigation, and perhaps even further when confirmed by additional AFT and AHe data.

  10. RRR and thermal conductivity of Ag and Ag-0.2 wt.%Mg alloy in Ag/Bi-2212 wires

    NASA Astrophysics Data System (ADS)

    Li, P.; Ye, L.; Jiang, J.; Shen, T.

    2015-12-01

    Residual resistivity ratio (RRR) and thermal conductivity of metal matrix in metal/superconductor composite wires are important parameters for designing superconducting magnets. However, the resistivity of silver in reacted Ag/Bi-2212 wires has yet to be determined over temperature range from 4.2 K to 80 K because Bi-2212 filaments have a critical transition temperature Tc of ∼ 80 K, and because it is unknown whether the RRR of Ag/Bi-2212 degrades with Cu diffusing from Bi-2212 filaments into silver sheathes at elevated temperatures and to what degree it varies with heat treatment. We measured the resistivity of stand-alone Ag and AgMg (Ag-0.2 wt.% Mg) wires as well as the resistivity of Ag and Ag-0.2 wt.% Mg in Ag/Bi- 2212 round wires reacted in 1 bar oxygen at 890 °C for 1, 8, 24 and 48 hours and quickly cooled to room temperature. The heat treatment was designed to reduce the critical current Ic of Bi- 2212 wires to nearly zero while allowing Cu loss to fully manifest itself. We determined that pure silver exhibits a RRR of ∼ 220 while the oxide-dispersion strengthened Ag-Mg exhibits a RRR of ∼ 5 in stand-alone samples. A surprising result is that the RRR of silver in the composite round wires doesn't degrade with extended time at 890 °C for up to 48 hours. This surprising result may be explained by our observation that the Cu that diffuses into silver tends to form Cu2O precipitates in oxidizing atmosphere, instead of forming Ag-Cu solution alloy. We also measured the thermal conductivity and the magneto-resistivity of pure Ag and Ag-0.2 wt. % Mg from 4.2 K to 300 K in magnetic fields up to 14.8 T and summarized them using a Kohler plot.

  11. Metallurgical characterization of experimental Ag-based soldering alloys

    PubMed Central

    Ntasi, Argyro; Al Jabbari, Youssef S.; Silikas, Nick; Al Taweel, Sara M.; Zinelis, Spiros

    2014-01-01

    Aim To characterize microstructure, hardness and thermal properties of experimental Ag-based soldering alloys for dental applications. Materials and methods Ag12Ga (AgGa) and Ag10Ga5Sn (AgGaSn) were fabricated by induction melting. Six samples were prepared for each alloy and microstructure, hardness and their melting range were determined by, scanning electron microscopy, energy dispersive X-ray (EDX) microanalysis, X-ray diffraction (XRD), Vickers hardness testing and differential scanning calorimetry (DSC). Results Both alloys demonstrated a gross dendritic microstructure while according to XRD results both materials consisted predominately of a Ag-rich face centered cubic phase The hardness of AgGa (61 ± 2) was statistically lower than that of AgGaSn (84 ± 2) while the alloys tested showed similar melting range of 627–762 °C for AgGa and 631–756 °C for AgGaSn. Conclusion The experimental alloys tested demonstrated similar microstructures and melting ranges. Ga and Sn might be used as alternative to Cu and Zn to modify the selected properties of Ag based soldering alloys. PMID:25382945

  12. Temperature dependent effects during Ag deposition on Cu(110)

    SciTech Connect

    Taylor, T.N.; Muenchausen, R.E.; Hoffbauer, M.A.; Denier van der Gon, A.W.; van der Veen, J.F.; FOM-Instituut voor Atoom-en Molecuulfysica, Amsterdam )

    1989-01-01

    The composition, structure, and morphology of ultrathin films grown by Ag deposition on Cu(110) were monitored as a function of temperature using low-energy electron diffraction (LEED), Auger electron spectroscopy (AES), and medium energy ion scattering (MEIS). Aligned backscattering measurements with 150 keV He ions indicate that the Ag resides on top of the Cu and there is no significant surface compound formation. Measurements with LEED show that the Ag is initially confined to the substrate troughs. Further deposition forces the Ag out of the troughs and results in a split c(2 {times} 4) LEED pattern, which is characteristic of a distorted Ag(111) monolayer template. As verified by both AES and MEIS measurements, postmonolayer deposition of Ag on Cu(110) at 300K leads to a pronounced 3-dimensional clustering. Ion blocking analysis of the Ag clusters show that the crystallites have a (110)-like growth orientation, implying that the Ag monolayer template undergoes a rearrangement. These data are confirmed by low temperature LEED results in the absence of clusters, which indicate that Ag multilayers grow from a Ag--Cu interface where the Ag is captured in the troughs. Changes observed in the film structure and morphology are consistent with a film growth mechanism that is driven by overlayer strain response to the substrate corrugation. 16 refs., 4 figs.

  13. Ag(+)-mediated assembly of 5'-guanosine monophosphate.

    PubMed

    Loo, Kristine; Degtyareva, Natalya; Park, Jihae; Sengupta, Bidisha; Reddish, Michaeal; Rogers, Christopher C; Bryant, Andrea; Petty, Jeffrey T

    2010-04-01

    Polymorphic forms of nucleic acids provide platforms for new nanomaterials, and transition metal cations give access to alternative arrangements of nucleobases by coordinating with electron-rich functional groups. Interaction of Ag(+) with 5'-guanosine monophosphate (5'-GMP) is considered in this work. Ag(+) promotes nucleotide stacking and aggregation, as indicated by the increased viscosity of 5'-GMP solutions with Ag(+), magnification of the circular dichroism response of guanine by Ag(+), and exothermic reactions between Ag(+) and guanine derivatives. Isothermal titration calorimetry studies show that the reaction is favored starting at 10 microM 5'-GMP. Utilizing the exothermic heat change associated with reaction of Ag(+) with 5'-GMP, local structure within the aggregate was assessed. On the basis of the salt dependence of the reaction and comparison with the corresponding nucleoside, the dianionic phosphate of 5'-GMP is one binding site for Ag(+), although this electrostatic interaction is not a dominant contribution to the overall heat change. Another binding site is the N7 on the nucleobase, as determined via studies with 7-deazaguanosine. Besides this binding site, Ag(+) also associates with the O6, as earlier studies deduced from the shift in the carbonyl stretching frequency associated with adduct formation. With these two binding sites on the nucleobase, the empirical stoichiometry of approximately 1 Ag(+):nucleobase derived from the calorimetry studies indicates that Ag(+) coordinates two nucleobases. The proposed structural model is a Ag(+)-mediated guanine dimer within a base stacked aggregate. PMID:20205377

  14. Preparation of the CNC/Ag/beeswax composites for enhancing antibacterial and water resistance properties of paper.

    PubMed

    Liu, Kai; Liang, Hunan; Nasrallah, Joseph; Chen, Lihui; Huang, Liulian; Ni, Yonghao

    2016-05-20

    An effective method of preparing composites containing inorganic (Ag) and organic (beeswax) particles was established in this study. Ag nanoparticles were first immobilized on the cellulose nanocrystals (CNC) during the reduction of AgNO3 in the presence of CNC, then mixed with beeswax by high speed stirring. Scanning transmission electron microscopy (STEM) images indicated that Ag and beeswax particles were uniformly dispersed and stable in the network structure formed by CNC. Upon coating on a paper surface, a layer of beeswax film was evident based on scanning electron microscopy (SEM) images. The dynamic contact angle and antibacterial activity tests indicated that the contact angle of coated paper reached 113.06° and the growth inhibition of Escherichia coli increased to 99.96%, respectively, at a coating amount of 21.53 g/m(2). When applied onto paper surface by coating, the CNC/Ag/beeswax composites can impact paper with antibacterial property and improved water resistance. PMID:26917389

  15. Anomalous photoelectric emission from Ag on zinc-phthalocyanine film

    NASA Astrophysics Data System (ADS)

    Tanaka, Senku; Otani, Tomohiro; Fukuzawa, Ken; Ogawa, Koji; Azuma, Junpei; Yamamoto, Isamu; Takahashi, Kazutoshi; Kamada, Masao; Hiromitsu, Ichiro

    2014-05-01

    Photoelectric emission from organic and metal thin films is generally observed with irradiation of photon energy larger than 4 eV. In this paper, however, we report photoelectric emission from Ag on a zinc-phthalocyanine (ZnPc) layer at a photon energy of 3.4 eV. The threshold energy for this photoelectric emission is much smaller than the work function of Ag estimated by conventional photoelectron spectroscopy. The photoelectric emission by low-energy photons is significant for Ag thicknesses of less than 1 nm. Photoelectron spectroscopy and morphological study of the Ag/ZnPc suggest that the anomalous photoelectric emission from the Ag surface is caused by a vacuum level shift at the Ag/ZnPc interface and by surface plasmons of the Ag nanoparticles.

  16. Anomalous photoelectric emission from Ag on zinc-phthalocyanine film

    SciTech Connect

    Tanaka, Senku; Otani, Tomohiro; Fukuzawa, Ken; Hiromitsu, Ichiro; Ogawa, Koji; Azuma, Junpei; Yamamoto, Isamu; Takahashi, Kazutoshi; Kamada, Masao

    2014-05-12

    Photoelectric emission from organic and metal thin films is generally observed with irradiation of photon energy larger than 4 eV. In this paper, however, we report photoelectric emission from Ag on a zinc-phthalocyanine (ZnPc) layer at a photon energy of 3.4 eV. The threshold energy for this photoelectric emission is much smaller than the work function of Ag estimated by conventional photoelectron spectroscopy. The photoelectric emission by low-energy photons is significant for Ag thicknesses of less than 1 nm. Photoelectron spectroscopy and morphological study of the Ag/ZnPc suggest that the anomalous photoelectric emission from the Ag surface is caused by a vacuum level shift at the Ag/ZnPc interface and by surface plasmons of the Ag nanoparticles.

  17. Highly Effective Electromagnetic Interference Shielding Materials based on Silver Nanowire/Cellulose Papers.

    PubMed

    Lee, Tae-Won; Lee, Sang-Eui; Jeong, Young Gyu

    2016-05-25

    We fabricated silver nanowire (AgNW)-coated cellulose papers with a hierarchical structure by an efficient and facile dip-coating process, and investigated their microstructures, electrical conductivity and electromagnetic interference (EMI) shielding effectiveness. SEM images confirm that AgNWs are coated dominantly on the paper surfaces, although they exist partially in the inner parts of the cellulose papers, which demonstrates that the AgNW density gradually decreases in thickness direction of the AgNW/cellulose papers. This result is supported by the anisotropic apparent electrical conductivity of the AgNW/cellulose papers depending on in-plane or thickness direction. Even for a AgNW/cellulose paper obtained by a single dip-coating cycle, the apparent electrical conductivity in the in-plane direction of 0.34 S/cm is achieved, which is far higher than the neat cellulose paper with ∼10(-11) S/cm. In addition, the apparent electrical conductivity of the papers in the in-plane direction increases significantly from 0.34 to 67.51 S/cm with increasing the number of dip-coating cycle. Moreover, although the AgNW/cellulose paper with 67.51 S/cm possesses 0.53 vol % AgNW only, it exhibits high EMI shielding performance of ∼48.6 dB at 1 GHz. This indicates that the cellulose paper structure is highly effective to form a conductive AgNW network. Overall, it can be concluded that the AgNW/cellulose papers with high flexibility and low density can be used as electrically conductive components and EMI shielding elements in advanced application areas. PMID:27156577

  18. Si/Ag composite with bimodal micro-nano porous structure as a high-performance anode for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Hao, Qin; Zhao, Dianyun; Duan, Huimei; Zhou, Qiuxia; Xu, Caixia

    2015-03-01

    A one-step dealloying method is employed to conveniently fabricate a bimodal porous (BP) Si/Ag composite in high throughput under mild conditions. Upon dealloying the carefully designed SiAgAl ternary alloy in HCl solution at room temperature, the obtained Si/Ag composite has a uniform bicontinuous porous structure in three dimensions with micro-nano bimodal pore size distribution. Compared with the traditional preparation methods for porous Si and Si-based composites, this dealloying route is easily operated and environmentally benign. More importantly, it is convenient to realize the controllable components and uniform distribution of Si and Ag in the product. Owing to the rich porosity of the unique BP structure and the incorporation of highly conductive Ag, the as-made Si/Ag composite possesses the improved conductivity and alleviated volume changes of the Si network during repeated charging and discharging. As expected, the BP Si/Ag anode exhibits high capacity, excellent cycling reversibility, long cycling life and good rate capability for lithium storage. When the current rate is up to 1 A g-1, BP Si/Ag can deliver a stable reversible capacity above 1000 mA h g-1, and exhibits a capacity retention of up to 89.2% against the highest capacity after 200 cycles. With the advantages of unique performance and easy preparation, the BP Si/Ag composite holds great application potential as an advanced anode material for Li-ion batteries.A one-step dealloying method is employed to conveniently fabricate a bimodal porous (BP) Si/Ag composite in high throughput under mild conditions. Upon dealloying the carefully designed SiAgAl ternary alloy in HCl solution at room temperature, the obtained Si/Ag composite has a uniform bicontinuous porous structure in three dimensions with micro-nano bimodal pore size distribution. Compared with the traditional preparation methods for porous Si and Si-based composites, this dealloying route is easily operated and environmentally benign

  19. Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance.

    PubMed

    Lu, Lei-Lei; Ge, Jin; Yang, Jun-Nan; Chen, Si-Ming; Yao, Hong-Bin; Zhou, Fei; Yu, Shu-Hong

    2016-07-13

    Lithium metal is one of the most attractive anode materials for next-generation lithium batteries due to its high specific capacity and low electrochemical potential. However, the poor cycling performance and serious safety hazards, caused by the growth of dendritic and mossy lithium, has long hindered the application of lithium metal based batteries. Herein, we reported a rational design of free-standing Cu nanowire (CuNW) network to suppress the growth of dendritic lithium via accommodating the lithium metal in three-dimensional (3D) nanostructures. We demonstrated that as high as 7.5 mA h cm(-2) of lithium can be plated into the free-standing copper nanowire (CuNW) current collector without the growth of dendritic lithium. The lithium metal anode based on the CuNW exhibited high Coulombic efficiency (average 98.6% during 200 cycles) and outstanding rate performance owing to the suppression of lithium dendrite growth and high conductivity of CuNW network. Our results demonstrate that the rational nanostructural design of current collector could be a promising strategy to improve the performance of lithium metal anode enabling its application in next-generation lithium-metal based batteries. PMID:27253417

  20. A spray-coating process for highly conductive silver nanowire networks as the transparent top-electrode for small molecule organic photovoltaics.

    PubMed

    Selzer, Franz; Weiss, Nelli; Kneppe, David; Bormann, Ludwig; Sachse, Christoph; Gaponik, Nikolai; Eychmüller, Alexander; Leo, Karl; Müller-Meskamp, Lars

    2015-02-14

    We present a novel top-electrode spray-coating process for the solution-based deposition of silver nanowires (AgNWs) onto vacuum-processed small molecule organic electronic solar cells. The process is compatible with organic light emitting diodes (OLEDs) and organic light emitting thin film transistors (OLETs) as well. By modifying commonly synthesized AgNWs with a perfluorinated methacrylate, we are able to disperse these wires in a highly fluorinated solvent. This solvent does not dissolve most organic materials, enabling a top spray-coating process for sensitive small molecule and polymer-based devices. The optimized preparation of the novel AgNW dispersion and spray-coating at only 30 °C leads to high performance electrodes directly after the deposition, exhibiting a sheet resistance of 10.0 Ω □(-1) at 87.4% transparency (80.0% with substrate). By spraying our novel AgNW dispersion in air onto the vacuum-processed organic p-i-n type solar cells, we obtain working solar cells with a power conversion efficiency (PCE) of 1.23%, compared to the air exposed reference devices employing thermally evaporated thin metal layers as the top-electrode. PMID:25584968

  1. Hydrodynamic characterization of the bottom boundary layer in a coastal upwelling system (Ría de Vigo, NW Spain)

    NASA Astrophysics Data System (ADS)

    Villacieros-Robineau, N.; Herrera, J. L.; Castro, C. G.; Piedracoba, S.; Roson, G.

    2013-10-01

    The hydrodynamics of the bottom boundary layer (BBL) in the Ría de Vigo (NW Iberian Peninsula) are studied for the first time, identifying their possible forcing factors and filling a previous lack of knowledge about the coastal upwelling system of NW Iberian Peninsula. For tackling this subject, high resolution time series of bottom currents by means of a downwards looking Acoustic Doppler Current Profiler (3 m above the bottom) were recorded in the inner part of the Ría de Vigo covering the four seasons of the climate year 2004-2005.

  2. The magmatic plumbing of the submarine Hachijo NW volcanic chain, Hachijojima, Japan: long distance lateral magma transport?

    NASA Astrophysics Data System (ADS)

    Ishizuka, O.; Geshi, N.; Itoh, J.; Kawanabe, Y.; Tsujino, T.

    2005-12-01

    Recent geophysical observations on basaltic composite volcanoes in Izu-Bonin arc reveal the process of long distance lateral magma transport within the shallow middle crust. Such intrusion events sometimes caused flank fissure eruption and also triggered a formation of collapsed caldera (Miyakejima 2000). To clarify a long-distance magma transport system of the basaltic composite volcano in volcanic arc from geological and petrological aspects, we investigated a submarine volcanic chain (Hachijo NW chain) nested Hachijo Nishiyama volcano, a frontal composite volcano in the northern Izu arc. The volcanic chain extends 15 km from Hachijo-Nishiyama volcano and is composed of ridges and many small cones with basal diameters generally less than 2km. Dredge sampling recovered basaltic lavas and spatters. A diving survey using a ROV (Hyper Dolphin) revealed pillow lava flows on steep slopes and accumulation of spatters and agglutinates near the eruption center. Basalts from the Hachijo NW chain generally have more primitive composition (up to nearly 7% of MgO) compared to the basaltic rocks from the Nishiyama. The bulk magma composition of Hachijo NW chain is controlled by fractionation of clinopyroxene, olivine and plagioclase while plagioclase accumulation was indicated by aluminum-rich character of the Nishiyama volcano and its subaerial satellite cones. Trace element ratios unaffected by melting or crystal fractionation (e.g., Nb/Zr) are not significantly different between the Nishiyama and the Hachijo NW chain. This implies that the sources of magma for these volcanic systems are basically identical. However, ratios affected by melting process are significantly different between the two. Hachijo NW chain shows lower LREE/HREE and Zr/Y, implying difference in degree of partial melting of the source. Other possible processes for producing these differences in trace element characteristics include crustal assimilation. These results obtained so far appear to

  3. Effects of Ag addition on FePt L10 ordering transition: A direct observation of ordering transition and Ag segregation in FePtAg alloy films

    NASA Astrophysics Data System (ADS)

    Wang, Lei; Gao, Tenghua; Yu, Youxing

    2015-12-01

    FePt and (FePt)91.2Ag8.8 alloy films were deposited by magnetron sputtering. The average coercivity of (FePt)91.2Ag8.8 films reaches 8.51 × 105 A/m, which is 0.63 × 105 A/m higher than that of the corresponding FePt films. Ag addition effectively promotes the FePt L10 ordering transition at a relatively low annealing temperature of 400 °C. The promotion mechanism was investigated by using in situ high-resolution transmission electron microscopy (HRTEM) and ex situ X-ray absorption fine structure (XAFS). The concurrence of ordering transition and Ag segregation in FePtAg alloy films was first observed by using in situ heating HRTEM. The time-resolved evolution reveals more details on the role of Ag addition in FePt low-temperature ordering. Ex situ XAFS results further confirm that Ag replaces Fe sites in the as-deposited films and segregates from FePt-Ag solid solution phase through annealing at elevated temperatures. The segregation of Ag atoms leaves vacancies in the grain. The vacancy formation is believed to accelerate the diffusion of Fe and Pt atoms, which is critical for the L10 ordering transition.

  4. Structural evolution of Ag nanoparticles during electron driven synthesis of Ag filaments on Ag2WO4: In situ observation and theoretical supporting evidence

    NASA Astrophysics Data System (ADS)

    da Silva, Edison Z.; da Silva Pereira, Wyllamanney; Andrés, Juan; Gracia, Lourdes; San-Miguel, Miguel; Longo, Elson; Longo, Valeria M.

    2015-03-01

    α - Ag2WO4 crystals irradiated by an electron beam from an electron microscope under high vacuum, nucleate metallic Ag, and form Ag metallic nanowires on the α crystals surface. In order to understand this interesting and complex behavior of the formation and growth of Ag nanowires on α-Ag2WO4 we investigated by detailed in situ transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM) studies, density functional theory calculations and ab initio molecular dynamics (MD) simulations. First principle calculations point out that Ag-3 and Ag-4 atoms, located on the (100) surface, are the most energetically favorable to undergo the diffusion process to form metallic Ag. Ab initio MD simulations and nudged elastic band (NEB) method were used to investigate the minimum energy pathways for diffusion of Ag atoms to outward sites on the (100) surface. The results point out that the injection of electrons decreases the activation barrier for this diffusion step and this unusual behavior results from the presence of a lower energy barrier process. Financial support FAPESP, Project 2010/16970-0, grant (2013/02032-7), calculations performed at CENAPAD-SP.

  5. Post-Synthetic Decoupling of On-Surface-Synthesized Covalent Nanostructures from Ag(111).

    PubMed

    Rastgoo-Lahrood, Atena; Björk, Jonas; Lischka, Matthias; Eichhorn, Johanna; Kloft, Stephan; Fritton, Massimo; Strunskus, Thomas; Samanta, Debabrata; Schmittel, Michael; Heckl, Wolfgang M; Lackinger, Markus

    2016-06-27

    The on-surface synthesis of covalent organic nanosheets driven by reactive metal surfaces leads to strongly adsorbed organic nanostructures, which conceals their intrinsic properties. Hence, reducing the electronic coupling between the organic networks and commonly used metal surfaces is an important step towards characterization of the true material. We demonstrate that post-synthetic exposure to iodine vapor leads to the intercalation of an iodine monolayer between covalent polyphenylene networks and Ag(111) surfaces. The experimentally observed changes from surface-bound to detached nanosheets are reproduced by DFT simulations. These findings suggest that the intercalation of iodine provides a material that shows geometric and electronic properties substantially closer to those of the freestanding network. PMID:27125328

  6. Corrosion of Ti-STS dissimilar joints brazed by a Ag interlayer and Ag-Cu-(Pd) alloy fillers

    NASA Astrophysics Data System (ADS)

    Lee, M. K.; Park, J. J.; Lee, G. J.; Lee, J. G.; Kim, D. W.; Lim, C. H.; Rhee, C. K.; Lee, Y. B.; Lee, J. K.; Hong, S. J.

    2011-02-01

    Corrosion behavior of dissimilar brazed joints between titanium Gr. 2 (Ti) and S31254 stainless steel (STS) was investigated. For the study, a Ag interlayer and two Ag-base eutectic alloys, 72Ag-28Cu and 66.2Ag-25.8Cu-8Pd (wt.%), were introduced as a diffusion control layer and fillers, respectively, between the base materials. The joints commonly had a layered structure of Ti(base)/TiAg/Ag solid solution/STS(base), but the one brazed by the Ag-Cu-Pd filler was slightly alloyed with the noble Pd elements over the Ag-rich solid solution region. A series of corrosion test experiments in a sea water revealed that a corrosion of TiAg layer and a stress-induced cracking at the TiAg/Ag solid solution interface were dominant due to a galvanic attack, but notably the Ti-STS dissimilar joint's resistance to corrosion was significantly improved by alloying the Pd in the joint. The corrosion behavior of such dissimilar metal joints was discussed based on galvanic corrosion effect.

  7. High-Quality AgGaTe2 Layers on Si Substrates with Ag2Te Buffer Layers

    NASA Astrophysics Data System (ADS)

    Uruno, Aya; Kobayashi, Masakazu

    2016-05-01

    AgGaTe2 layers were successfully grown on Si substrates by the close-spaced sublimation method. The Si substrates were confirmed to be etched during AgGaTe2 layer growth when the layer was grown directly on the substrate. To eliminate melt-back etching, a buffer layer of Ag2Te was introduced. It was found that the Ag2Te buffer layer changed into the AgGaTe2 layer during the growth process, and a uniform AgGaTe2 layer with an abrupt interface was formed. Both the diffusion of Ga into Ag2Te and the growth of AgGaTe2 occurred simultaneously. It was confirmed that uniform AgGaTe2 layers could be formed without any traces of the Ag2Te layer or melt-back etching by tuning the growth parameters. A solar cell was also fabricated using the p-AgGaTe2/n-Si heterojunction. This solar cell showed conversion efficiency of approximately 3%.

  8. High-Quality AgGaTe2 Layers on Si Substrates with Ag2Te Buffer Layers

    NASA Astrophysics Data System (ADS)

    Uruno, Aya; Kobayashi, Masakazu

    2016-09-01

    AgGaTe2 layers were successfully grown on Si substrates by the close-spaced sublimation method. The Si substrates were confirmed to be etched during AgGaTe2 layer growth when the layer was grown directly on the substrate. To eliminate melt-back etching, a buffer layer of Ag2Te was introduced. It was found that the Ag2Te buffer layer changed into the AgGaTe2 layer during the growth process, and a uniform AgGaTe2 layer with an abrupt interface was formed. Both the diffusion of Ga into Ag2Te and the growth of AgGaTe2 occurred simultaneously. It was confirmed that uniform AgGaTe2 layers could be formed without any traces of the Ag2Te layer or melt-back etching by tuning the growth parameters. A solar cell was also fabricated using the p-AgGaTe2/n-Si heterojunction. This solar cell showed conversion efficiency of approximately 3%.

  9. Superionic behavior in the xAgI-(1-x)CsAg2I3 polycrystalline system

    NASA Astrophysics Data System (ADS)

    Rodríguez, L. A.; Zapata, J.; Vargas, R. A.; Peña Lara, D.; Diosa, J. E.

    2016-06-01

    A superionic phase behavior (with DC ionic conductivities higher than 0.01 S/cm) has been observed in xAgI-(1-x)CsAg2I3 (x≈0.67) polycrystalline system grown by slow evaporation using AgI and CsI powders (molar ratio Cs/Ag=0.25) as starting salts and an aqueous solution of HI as solvent. The transition from the normal-to- the superionic state is first-order with a hysteretic behavior in temperature centered at about 116 °C as reflected by thermal (DSC) and electrical conductivity measurements. This mixture is composed of CsAg2I3 and AgI crystalline phases and an additional amorphous AgI phase that explains the glassy-type behavior observed in the superionic phase transition.

  10. The instability of silicene on Ag(111)

    SciTech Connect

    Acun, A.; Poelsema, B.; Zandvliet, H. J. W.; Gastel, R. van

    2013-12-23

    We have used low energy electron microscopy to directly visualize the formation and stability of silicene layers on a Ag(111) substrate. Theoretical calculations call into question the stability of this graphene-like analog of silicon. We find that silicene layers are intrinsically unstable against the formation of an “sp{sup 3}-like” hybridized, bulk-like silicon structure. The irreversible formation of this bulk-like structure is triggered by thermal Si adatoms that are created by the silicene layer itself. To add injury to insult, this same instability prevents the formation of a fully closed silicene layer or a thicker bilayer, rendering the future large-scale fabrication of silicene layers on Ag substrates unlikely.

  11. PERFORMANCE OF THE AGS TRANSITION JUMP SYSTEM.

    SciTech Connect

    AHRENS,L.A.; BRENNAN,J.M.; GLENN,J.W.; ROSER,T.; VAN ASSELT,W.K.

    1999-03-29

    The transition jump system has been indispensable to the high intensity proton operation of the AGS complex. Nevertheless, transition crossing remains one of the major hurdles as the accelerator complex intensity is pushed upward. To enhance the performance of the system ''quadrupole pumping'' in the Booster is used to minimize the necessary longitudinal dilution of the beam on the AGS injection porch. During the transition jump sextupole correctors at strategic locations are pulsed to minimize the effects of the chromatic non-linearity of the jump system. The available instrumentation for diagnosing the performance of the system will be described, along with installed hardware to counter the non-linear effects of the transition jump system.

  12. Lake County Geo-Ag heat center

    SciTech Connect

    Not Available

    1987-07-01

    Lake County is proceeding with plans to develop a unique agricultural park called the Geo-Ag Heat Center Project. The project will combine vocational training, geothermal heat-transfer research, and commercial resources for greenhouse heating, crop drying, and other agricultural operations. The first phase of the project involved drilling wells to confirm the availability of an adequate geothermal resource. The first well, AG Park 1, drilled in January, 1986 to a depth of 1614 feet, proved noncommercial; it will be used as an injection well. Next, a geophysical program of seismic surveys was undertaken to pinpoint the more productive fracture zones. Wells AG Park 2 and 3 were drilled in these zones. Both wells were drilled in December 1986, to depths of 592 and 488 feet, respectively. In 3-day tests of continuous production, AG Park 2 and 3 yielded flowing wellhead temperatures of 143/sup 0/F and 153/sup 0/F, respectively, at flow rates exceeding 150 gpm, with minor drawdowns. The next phase of the project entails construction of a 7000 square-foot greenhouse by the end of 1987. It will be operated by the Mendocino-Lake Community College District as an educational and demonstration facility. Geothermal-fluid and irrigation water-distribution and injection-pipeline systems will also be installed in preparation for future commercial leasing on the 3-acre site. The demonstration greenhouse will allow evaluation of the effectiveness of various heat-transfer systems. This would assist commercial operators in designing the most economical system for their needs.

  13. Results from the AGS Booster transverse damper

    SciTech Connect

    Russo, D.; Brennan, M.; Meth, M.; Roser, T.

    1993-01-01

    To reach the design intensity of 1.5 [times] 10[sup 13] protons per pulse in the AGS Booster, transverse coupled bunch instabilities with an estimated growth rate of 1500s[sup [minus]1] have to be dampened. A prototype transverse damper has been tested successfully using a one turn digital delay and closed orbit suppression implemented in a programmable gate array. An updated damper, which includes an algorithm to optimize damping for a changing betatron rune, will also be presented.

  14. Results from the AGS Booster transverse damper

    SciTech Connect

    Russo, D.; Brennan, M.; Meth, M.; Roser, T.

    1993-06-01

    To reach the design intensity of 1.5 {times} 10{sup 13} protons per pulse in the AGS Booster, transverse coupled bunch instabilities with an estimated growth rate of 1500s{sup {minus}1} have to be dampened. A prototype transverse damper has been tested successfully using a one turn digital delay and closed orbit suppression implemented in a programmable gate array. An updated damper, which includes an algorithm to optimize damping for a changing betatron rune, will also be presented.

  15. Rotational structures in {sup 107}Ag

    SciTech Connect

    Espinoza-Quinones, F.R.; Cybulska, E.W.; Oliveira, J.R.; Ribas, R.V.; Medina, N.H.; Rao, M.N.; Rizzutto, M.A.; Emediato, L.G.; Seale, W.A.; Botelho, S.

    1997-03-01

    The {sup 107}Ag nucleus has been investigated with the {sup 100}Mo({sup 11}B,4n{gamma}) reaction at 39 MeV beam energy. Gamma-gamma coincidences and angular correlations were measured. The ground state band has been extended to higher spins and a three-quasiparticle rotational band has been established. The results were interpreted within the cranked shell model and total Routhian surface predictions. {copyright} {ital 1997} {ital The American Physical Society}

  16. SNS RING STUDY AT THE AGS BOOSTER.

    SciTech Connect

    ZHANG, S.Y.; AHRENS, L.; BEEBE-WANG, J.; BLASKIEWICZ, M.; FEDOTOV, A.; GARDNER, C.; LEE, Y.Y.; LUCCIO, A.; MALITSKY, N.; ROSER, T.; WENG, W.T.; WEI, J.; ZENO, K.; REECE, K.; WANG, J.G.

    2000-06-30

    During the g-2 run at the BNL AGS in early 2000, a 200 MeV storage-ring-like magnetic cycle has been set-up and tuned at the Booster in preparing for the Spallation Neutron Source (SNS) accumulator ring study. In this article, we report the progress of the machine set-up, tuning, some preliminary studies, and the future plan.

  17. Mechanisms of Toxicity of Ag Nanoparticles in Comparison to Bulk and Ionic Ag on Mussel Hemocytes and Gill Cells

    PubMed Central

    Katsumiti, Alberto; Gilliland, Douglas; Arostegui, Inmaculada; Cajaraville, Miren P.

    2015-01-01

    Silver nanoparticles (Ag NPs) are increasingly used in many products and are expected to end up in the aquatic environment. Mussels have been proposed as marine model species to evaluate NP toxicity in vitro. The objective of this work was to assess the mechanisms of toxicity of Ag NPs on mussel hemocytes and gill cells, in comparison to ionic and bulk Ag. Firstly, cytotoxicity of commercial and maltose stabilized Ag NPs was screened in parallel with the ionic and bulk forms at a wide range of concentrations in isolated mussel cells using cell viability assays. Toxicity of maltose alone was also tested. LC50 values were calculated and the most toxic Ag NPs tested were selected for a second step where sublethal concentrations of each Ag form were tested using a wide array of mechanistic tests in both cell types. Maltose-stabilized Ag NPs showed size-dependent cytotoxicity, smaller (20 nm) NPs being more toxic than larger (40 and 100 nm) NPs. Maltose alone provoked minor effects on cell viability. Ionic Ag was the most cytotoxic Ag form tested whereas bulk Ag showed similar cytotoxicity to the commercial Ag NPs. Main mechanisms of action of Ag NPs involved oxidative stress and genotoxicity in the two cell types, activation of lysosomal AcP activity, disruption of actin cytoskeleton and stimulation of phagocytosis in hemocytes and increase of MXR transport activity and inhibition of Na-K-ATPase in gill cells. Similar effects were observed after exposure to ionic and bulk Ag in the two cell types, although generally effects were more marked for the ionic form. In conclusion, results suggest that most observed responses were due at least in part to dissolved Ag. PMID:26061169

  18. Formation and properties of hyaluronan/nano Ag and hyaluronan-lecithin/nano Ag films.

    PubMed

    Khachatryan, Gohar; Khachatryan, Karen; Grzyb, Jacek; Fiedorowicz, Maciej

    2016-10-20

    A facile and environmentally friendly method of the preparation of silver nanoparticles embedded in hyaluronan (Hyal/Ag) and hyaluronan-lecithin (Hyal-L/Ag) matrix was developed. Thin, elastic foils were prepared from gels by an in situ synthesis of Ag in an aqueous solution of sodium hyaluronate (Hyal), using aq. d-(+)-xylose solution as a reducing agent. The gels were applied to a clean, smooth, defatted Teflon surface and left for drying in the air. The dry foils were stored in a closed container. UV-vis spectroscopy, transmission electron microscopy (TEM) and Fourier transform infrared (FTIR) spectra confirmed formation of about 10nm ball-shaped Ag nanoparticles situated within the polysaccharide template. Thermal properties of the composites were characterized involving differential scanning calorimetry (DSC) and thermogravimetric (TGA) analyses, whereas molecular weights of polysaccharide chains of the matrix were estimated with the size exclusion chromatography coupled with multiangle laser light scattering and refractometric detectors (HPSEC-MALLS-RI). An increase in the molecular weight of the hyaluronate after generation of Ag nanoparticles was observed. The foils showed specific properties. The study confirmed that silver nanoparticles can be successfully prepared with environmentally friendly method, using hyaluronan as a stabilizing template. Hyaluronan and hyaluronan-lecithin matrices provide nanocrystals uniform in size and shape. The composites demonstrated a bacteriostatic activity. PMID:27474588

  19. Electrochemical detection of aqueous Ag+ based on Ag+-assisted ligation reaction

    NASA Astrophysics Data System (ADS)

    Miao, Peng; Han, Kun; Wang, Bidou; Luo, Gangyin; Wang, Peng; Chen, Mingli; Tang, Yuguo

    2015-03-01

    In this work, a novel strategy to fabricate a highly sensitive and selective biosensor for the detection of Ag+ is proposed. Two DNA probes are designed and modified on a gold electrode surface by gold-sulfur chemistry and hybridization. In the presence of Ag+, cytosine-Ag+-cytosine composite forms and facilitates the ligation event on the electrode surface, which can block the release of electrochemical signals labeled on one of the two DNA probes during denaturation process. Ag+ can be sensitively detected with the detection limit of 0.1 nM, which is much lower than the toxicity level defined by U.S. Environmental Protection Agency. This biosensor can easily distinguish Ag+ from other interfering ions and the performances in real water samples are also satisfactory. Moreover, the two DNA probes are designed to contain the recognition sequences of a nicking endonuclease, and the ligated DNA can thus be cleaved at the original site. Therefore, the electrode can be regenerated, which allows the biosensor to be reused for additional tests.

  20. Electrochemical detection of aqueous Ag+ based on Ag+-assisted ligation reaction

    PubMed Central

    Miao, Peng; Han, Kun; Wang, Bidou; Luo, Gangyin; Wang, Peng; Chen, Mingli; Tang, Yuguo

    2015-01-01

    In this work, a novel strategy to fabricate a highly sensitive and selective biosensor for the detection of Ag+ is proposed. Two DNA probes are designed and modified on a gold electrode surface by gold-sulfur chemistry and hybridization. In the presence of Ag+, cytosine-Ag+-cytosine composite forms and facilitates the ligation event on the electrode surface, which can block the release of electrochemical signals labeled on one of the two DNA probes during denaturation process. Ag+ can be sensitively detected with the detection limit of 0.1 nM, which is much lower than the toxicity level defined by U.S. Environmental Protection Agency. This biosensor can easily distinguish Ag+ from other interfering ions and the performances in real water samples are also satisfactory. Moreover, the two DNA probes are designed to contain the recognition sequences of a nicking endonuclease, and the ligated DNA can thus be cleaved at the original site. Therefore, the electrode can be regenerated, which allows the biosensor to be reused for additional tests. PMID:25779347

  1. Commissioning the polarized beam in the AGS

    SciTech Connect

    Ratner, L.G.; Brown, H.; Chiang, I.H.; Courant, E.; Gardner, C.; Lazarus, D.; Lee, Y.Y.; Makdisi, Y.; Sidhu, S.; Skelly, J.

    1985-01-01

    After the successful operation of a high energy polarized proton beam at the Argonne Laboratory Zero Gradient Synchrotron (ZGS) was terminated, plans were made to commission such a beam at the Brookhaven National Laboratory Alternating Gradient Synchrotron (AGS). On February 23, 1984, 2 ..mu..A of polarized H/sup -/ was accelerated through the Linac to 200 MeV with a polarization of about 65%. 1 ..mu..A was injected into the AGS and acceleration attempts began. Several relatively short runs were then made during the next three months. Dedicated commissioning began in early June, and on June 26 the AGS polarized beam reached 13.8 GeV/c to exceed the previous ZGS peak momentum of 12.75 GeV/c. Commissioning continued to the point where 10/sup 10/ polarized protons were accelerated to 16.5 GeV/c with 40% polarization. Then, two experiments had a short polarized proton run. We plan to continue commissioning efforts in the fall of this year to reach higher energy, higher intensity, and higher polarization levels. We present a brief description of the facility and of the methods used for preserving the polarization of the accelerating beam.

  2. AGS RESONANT EXTRACTION WITH HIGH INTENSITY BEAMS.

    SciTech Connect

    AHRENS,L.; BROWN,K.; GLENN,J.W.; ROSER,T.; TSOUPAS,N.; VANASSELT,W.

    1999-03-29

    The Brookhaven AGS third integer resonant extraction system allows the AGS to provide high quality, high intensity 25.5 GeV/c proton beams simultaneously to four target stations and as many as 8 experiments. With the increasing intensities (over 7 x 10{sup 13} protons/pulse) and associated longer spill periods (2.4 to 3 seconds long), we continue to run with low losses and high quality low modulation continuous current beams.[1] Learning to extract and transport these higher intensity beams has required a process of careful modeling and experimentation. We have had to learn how to correct for various instabilities and how to better match extraction and the transport lines to the higher emittance beams being accelerated in the AGS. Techniques employed include ''RF'' methods to smooth out momentum distributions and fine structure. We will present results of detailed multi-particle tracking modeling studies which enabled us to develop a clear understanding of beam loss mechanisms in the transport and extraction process. We will report on our status, experiences, and the present understanding of the intensity limitations imposed by resonant extraction and transport to fixed target stations.

  3. Pressureless Bonding Using Sputtered Ag Thin Films

    NASA Astrophysics Data System (ADS)

    Oh, Chulmin; Nagao, Shijo; Suganuma, Katsuaki

    2014-12-01

    To improve the performance and reliability of power electronic devices, particularly those built around next-generation wide-bandgap semiconductors such as SiC and GaN, the bonding method used for packaging must change from soldering to solderless technology. Because traditional solders are problematic in the harsh operating conditions expected for emerging high-temperature power devices, we propose a new bonding method in this paper, namely a pressureless, low-temperature bonding process in air, using abnormal grain growth on sputtered Ag thin films to realize extremely high temperature resistance. To investigate the mechanisms of this bonding process, we characterized the microstructural changes in the Ag films over various bonding temperatures and times. We measured the bonding properties of the specimens by a die-shear strength test, as well as by x-ray diffraction measurements of the residual stress in the Ag films to show how the microstructural developments were essential to the bonding technology. Sound bonds with high die strength can be achieved only with abnormal grain growth at optimum bonding temperature and time. Pressureless bonding allows for production of reliable high-temperature power devices for a wide variety of industrial, energy, and environmental applications.

  4. Isomorphism and solid solutions among Ag- and Au-selenides

    NASA Astrophysics Data System (ADS)

    Palyanova, Galina A.; Seryotkin, Yurii V.; Kokh, Konstantin A.; Bakakin, Vladimir V.

    2016-09-01

    Au-Ag selenides were synthesized by heating stoichiometric mixtures of elementary substances of initial compositions Ag2-xAuxSe with a step of x=0.25 (0≤x≤2) to 1050 °C and annealing at 500 °C. Scanning electron microscopy, optical microscopy, electron microprobe analysis and X-ray powder diffraction methods have been applied to study synthesized samples. Results of studies of synthesized products revealed the existence of three solid solutions with limited isomorphism Ag↔Au: naumannite Ag2Se - Ag1.94Au0.06Se, fischesserite Ag3AuSe2 - Ag3.2Au0.8Se2 and gold selenide AuSe - Au0.94Ag0.06Se. Solid solutions and AgAuSe phases were added to the phase diagram of Ag-Au-Se system. Crystal-chemical interpretation of Ag-Au isomorphism in selenides was made on the basis of structural features of fischesserite, naumannite, and AuSe.

  5. Seafloor morphology: nature of the seabed and the cold water corals of the Levante Canyon (eastern Ligurian Sea, NW Mediterranean)

    NASA Astrophysics Data System (ADS)

    Delbono, Ivana; Ivaldi, Roberta; Pratellesi, Marta; Fanelli, Emanuela; Peirano, Andrea; Cocito, Silvia; Dialti, Lorenzo; Delfanti, Roberta

    2014-05-01

    The Levante Canyon, located approximately in the offshore area of Cinque Terre (eastern Ligurian Sea, NW Mediterranean), was investigated in autumn 2013 onboard Italian Navy Ships through high resolution multibeam (MB), side scan sonar (SSS) and image data acquired by a Remotely Operating Vehicle (ROV) in order to study the seafloor features and ecological characters. First data allow us to product a seabed mapping of the study area with high detail of seafloor shapes, to be extended to other similar sectors of the canyon catchment area, constituted by a dendritic pattern of each individual gully network. The highest values of slope (17°) can be found in the steep canyon heads and flanks. Slope values up to 10° can be seen depicting sea-bed mounds on the northernmost and central interfluve. MB and SSS data show higher acoustic backscatter in the deepest sections of the canyon than interfluve and the changes in the sea-bed nature over the mounds are highlighted as areas of variable intensity. ROV images were recorded from 510 m depth up to 370 m and suggested the presence of biological communities, mainly typical of deep muddy bottom, and small cold water coral colonies, possibly identified as Madrepora oculata. This survey provides not only a detailed mapping of the variable morphology of the proximal area of the Levante Canyon, but it also investigates the seabed nature and biological communities within the canyon system for the assessment of a potential Site of Community Importance (SCI) under the European Commission Habitats Directive (92/43/EEC). In particular cold water corals (CWC) provide a complex structural marine habitat hosting high levels of biological diversity, which are in the reef habitat three times higher compared to the surrounding seabed. For this reason they fall within the habitats that deserve protection (EU-Habitat 1170 "Reefs"). Preliminary observations and data interpretations suggest that the Levante Canyon shows interesting

  6. Linking the field to the stream: soil erosion and sediment yield in a rural catchment, NW Spain

    NASA Astrophysics Data System (ADS)

    Rodriguez-Blanco, M. L.; Taboada-Castro, M. M.; Palleiro-Suarez, L.; Taboada-Castro, M. T.

    2009-04-01

    Quantifying the linkages between field erosion, fluvial response and catchment sediment yield remains problematic, among other reasons, because of the re-deposition of eroded sediment within the catchment, which is controlled by the spatial organization of the land use and the connectivity between sediment sources and the stream network. This paper presents the results of an integrated study that considered the relationship between erosion and stream sediment yield in an agroforestry catchment (16 km2) in NW Spain. The geology consists of basic metamorphic schist. The relieve of the area is steeper, the mean slope is approximately 19%. Main soil types are classified as Umbrisol and Cambisol. Soils are acidic and rich in organic matter. The soil texture is silt and silt-loam. Land cover consists of a mixture of forest (65%) and agricultural fields (mainly grassland, pasture and maize). The study combined measurements of soil erosion by concentrate flow and sediment deposition at field scale with sediment yield measured at the catchment outlet. The hydrological data and water samples were obtained at the catchment outlet. Stream water level was monitored continuously and converted to discharge using a rating curve. The sampling for suspended sediments was supplemented by an automatic sampler. Suspended sediment load was calculated from the suspended sediment concentrations and discharge data. Eroded volume was calculated from cross-sections (measured at specific points, where the section changed abruptly) and length of the channel segments. The total sediment delivered to stream was determined as the difference between all erosion features (rills and gullies) and the sediment volumes that were deposited on the fields. The results showed that in the catchment during the period winter 2007/08 soil erosion by concentrate flow, i.e. rills and ephemeral gullies, occurred on unprotected crop field. Erosion by concentrate flow was highly discontinuous within the catchment

  7. Combining double difference and amplitude ratio approaches for Q estimates at the NW Bohemia earthquake swarm region

    NASA Astrophysics Data System (ADS)

    Kriegerowski, Marius; Cesca, Simone; Krüger, Frank; Dahm, Torsten; Horálek, Josef

    2016-04-01

    Aside from the propagation velocity of seismic waves, their attenuation can provide a direct measure of rock properties in the sampled subspace. We present a new attenuation tomography approach exploiting relative amplitude spectral ratios of earthquake pairs. We focus our investigation on North West Bohemia - a region characterized by intense earthquake swarm activity in a confined source region. The inter-event distances are small compared to the epicentral distances to the receivers meeting a fundamental requirement of the method. Due to the similar event locations also the ray paths are very similar. Consequently, the relative spectral ratio is affected mostly by rock properties along the path of the vector distance and thus representative of the focal region. In order to exclude effects of the seismic source spectra, only the high frequency content beyond the corner frequency is taken into consideration. This requires high quality as well as high sampling records. Future improvements in that respect can be expected from the ICDP proposal "Eger rift", which includes plans to install borehole monitoring in the investigated region. 1D and 3D synthetic tests show the feasibility of the presented method. Furthermore, we demonstrate influences of perturbations in source locations and travel time estimates on the determination of Q. Errors in Q scale linearly with errors in the differential travel times. These sources of errors can be attributed to the complex velocity structure of the investigated region. A critical aspect is the signal-to-noise ratio, which imposes a strong limitation and emphasizes the demand for high quality recordings. Hence, the presented method is expected to benefit from bore hole installations. Since we focus our analysis on the NW Bohemia case study example, a synthetic earthquake catalog incorporating source characteristics deduced from preceding moment tensor inversions coupled with a realistic velocity model provides us with a realistic

  8. Rapid hydrological response to central Andean Plateau uplift, NW-Argentina

    NASA Astrophysics Data System (ADS)

    Rohrmann, Alexander; Sachse, Dirk; Strecker, Manfred R.; Mulch, Andreas; Pingel, Heiko; Alonso, Ricardo N.

    2015-04-01

    The response of the regional and global hydrological cycle, vegetation and erosion to tectonic surface uplift and topographic growth of the world's largest orogenic plateaus and their flanking ranges is subject to ongoing debate. During the last decade reconstructions of paleo-environmental conditions and the topographic evolution of mountain belts have increasingly relied on stable isotope proxies retaining the oxygen (δ18O) or hydrogen (δD) isotopic composition of ancient meteoric waters or carbon (δ13C) of vegetation. Intermontane basin sediments along the Puna of NW Argentina, the southern extension of the Altiplano-Puna Plateau and the world's second largest plateau, record the eastward-directed lateral growth of the central Andes and the spatiotemporal impact of tectonism on hydrologic, sedimentary, and ecological changes through time. Here we reconstructed paleo-hydrological changes during a phase of major Andean uplift and orographic barrier formation (10-2 Ma) along the eastern flank of the Puna Plateau from a sedimentary sequence within the intermontane Angastaco basin of NW Argentina (25°45 S, 66 W). We use a unique array of stable water-isotope proxies in leafwaxes, pedogenic carbonates and hydrated volcanic glass. In addition we use vegetation-cover proxies based on stable C isotopes obtained from leaf-waxes and pedogenic carbonates. Lipid biomarker leafwax δD values range between -95 and -160 ‰ (VSMOW), and δ13C values from -23 to -36 ‰ (PDB). Pedogenic carbonate δ18O values range from 18 to 31 ‰ (VSMOW) and δ13C values vary between -4 to -17 ‰ (PDB), whereas volcanic glass δD values range from -71 to -95 ‰ (VSMOW). In combination, these proxies provide a precipitation - evapotranspiration record, which reveals the onset of the South American Low Level-Jet in NW Argentina at ~ 9 Ma and the presence of seasonally humid foreland conditions until 7 Ma, followed by orographic barrier formation upwind of the basin and rapid creation of

  9. Middle Miocene coralline algal facies from the NW Transylvanian Basin (Romania)

    NASA Astrophysics Data System (ADS)

    Chelaru, Ramona; Bucur, Ioan I.; Sǎsǎran, Emanoil; Bǎlc, Ramona; Tǎmas, Tudor

    2016-04-01

    The current study focus on the coralline algae from the Middle Miocene limestones in NW Transylvania to provide an outline for their systematics and palaeoecology. The investigated samples were collected from three carbonate outcrops: Vǎlenii Șomcutei, Ciolt 1 and Ciolt 2, named after the respective localities situated in the vicinity of the Țicǎu-Preluca Mountains (NW Romania). The microfacies analysis suggest shallowing upward tendency in middle to proximal shelf environments. The coralline algae are present in the carbonate successions as detritus, branches, crusts and rhodoliths. The Vǎlenii Șomcutei section shows a depositional model where large and spheroidal rhodoliths develop in high energy conditions, most probably generated by storm waves. The sections from the Ciolt area are distinguished by the presence of green algae in association with the encrusting and geniculate coralline specimens. The identified species belong to Ord. Corallinales (Hydrolithon, Spongites, Lithophyllum, Jania), Hapalidales (Lithothamnion and Mesophyllum) and Sporolithales (Sporolithon). In the taxonomic identification of coralline red algae we used as many diagnostic features as possible, known from the description of present - day species, such as: shape of epithallial cells and roof morphology for melobesioids; presence/absence of a layer of elongated cells below sporangial compartments and number of cells in paraphyses for sporolithoids. The identified coralline algal assemblages are discussed according to different paleoenvironmental conditions (paleo-depth, hydrodynamic energy) and then compared with similar fossil assemblages and recent analogs like modern maërl and rhodolith pavements. The study of the calcareous nannoplankton assemblages from the Vǎlenii Șomcutei section [1] and the presence of previously dated tuffite intercalations of Dej Tuff [2] in the two sections near the Ciolt village confirm the Badenian age (NN5) of these deposits. [1] Chelaru R., S

  10. Arctic passages: liminality, Iñupiat Eskimo mothers and NW Alaska communities in transition

    PubMed Central

    Schwarzburg, Lisa Llewellyn

    2013-01-01

    Background While the primary goal of the NW Alaska Native maternal transport is safe deliveries for mothers from remote villages, little has been done to question the impact of transport on the mothers and communities involved. This study explores how presence of Iñupiat values influences the desire of indigenous women of differing eras and NW Alaska villages to participate in biomedical birth, largely made available by a tribal health-sponsored transport system. Objective This paper portrays how important it is (and why) for Alaska Native families and women of different generations from various areas of Iñupiat villages of NW Alaska to get to the hospital to give birth. This research asks: How does a community's presence of Iñupiat values influence women of different eras and locations to participate in a more biomedical mode of birth? Design Theoretical frameworks of medical anthropology and maternal identity work are used to track the differences in regard to the maternal transport operation for Iñupiat mothers of the area. Presence of Iñupiat values in each of the communities is compared by birth era and location for each village. Content analysis is conducted to determine common themes in an inductive, recursive fashion. Results A connection is shown between a community's manifestation of Iñupiat cultural expression and mothers’ acceptance of maternal transport in this study. For this group of Iñupiat Eskimo mothers, there is interplay between community expression of Iñupiat values and desire and lengths gone to by women of different eras and locations. Conclusions The more openly manifested the Iñupiat values of the community, the more likely alternative birthing practices sought, lessening the reliance on the existing transport policy. Conversely, the more openly western values are manifested in the village of origin, the less likely alternative measures are sought. For this study group, mothers from study villages with openly manifested western

  11. Synthetic Studies of Local Travel Time Tomography In The Earthquake Swarm Region Vogtland/nw-bohemia

    NASA Astrophysics Data System (ADS)

    Roessler, D.; Korn, M.

    The Vogtland/NW-Bohemia region is characterized by periodic occurence of earth- quake swarms at upper crustal depths along deep-reaching neotectonic faults and other geophysical phenomena. As one source of these phenomena the existence of a deep- seated magma reservoir at the mantle-crust transition has been postulated. Seismic traveltime tomography making use of local seismic sources can image the 3-dimensional structure of the vp- and vp/vs-distribution in the earth's crust including the mantle-crust transition and thus might give explanations for the observed phenom- ena as aimed by the seismic experiment BOHEMA starting in 2002. The synthetic study presented here deals with the feasability to resolve given synthetic velocity anomalies embedded in a realistic background model of the Vogtland/NW- Bohemia region using realistic velocity background model derived from a refraction seismic experiment. A low velocity zone was included below 7 km representing a worst case scenario concerning ray path coverage. Synthetic travel times were com- puted for a receiver distribution consisting of 54 presently existing permanent seismic stations and 64 additional temporary stations as planned for for BOHEMA experi- ment. As for the sources, 12 epicentres of frequently recorded tectonic earthquakes and 138 sites of known quarry blasts were used guaranteeing sufficiant ray distri- bution in the crust. Applying the SIMULPS software, the tomographic inversion for P-velocity was carried out for a volume of 220 km x 180 km in horizontal and 50 km in vertical direction having increased grid density in the Vogtland/NW-Bohemia re- gion. Results of the inversion as well as considerations of their reliability are presented. The usage of a high number of quarry blasts enables high spatial resolution in the upper crust whereas reproduction of velocity patterns at Moho depth is strongly dependent on well distributed earthquake sources. Due to the existence of a low velocity zone tomographic

  12. The Solarya Volcano-Plutonic Complex (NW Turkey): Petrography, Petrogenesis and Tectonic Implications

    NASA Astrophysics Data System (ADS)

    Ünal, Alp; Kamacı, Ömer; Altunkaynak, Şafak

    2014-05-01

    The post collisional magmatic activity produced several volcano-plutonic complexes in NW Anatolia (Turkey) during the late Oligocene- Middle Miocene. One of the major volcano-plutonic complexes, the Solarya volcano-plutonic complex is remarkable for its coeval and cogenetic plutonic (Solarya pluton), hypabysal and volcanic rocks of Early Miocene (24-21 Ma) age. Solarya pluton is an epizonal pluton which discordantly intruded into metamorphic and nonmetamorphic basement rocks of Triassic age. It is a N-S trending magmatic body covering an area of 220 km2,approximatelly 20 km in length and 10 km in width. Based on the field and petrographic studies, three main rock groups distinguished in Solarya pluton; K-feldspar megacrystalline granodiorite, microgranite-granodiorite and haplogranite. Porphyritic and graphic-granophyric textures are common in these three rock groups. Pluton contains magmatic enclaves and syn-plutonic dykes of dioritic composition. Hypabyssal rocks are represented by porphyritic microdiorite and porphyritic quartz-diorite. They form porphyry plugs, sheet inrusions and dykes around the pluton. Porphyrites have microcrystalline-cryptocrystalline groundmass displaying micrographic and granophyric textures. Petrographically similar to the hypabyssal rocks, volcanic rocks are formed from andesitic and dasitic lavas and pyroclastic rocks. Plutonic, hypabyssal and volcanic rocks of Solarya volcano-plutonic complex show similar major-trace element and Sr-Nd-Pb isotopic compositions, indicating common magmatic evolution and multicomponent melt sources including mantle and crustal components. They are mainly metaluminous, medium to high-K calc alkaline rocks and display enrichment in LILE and depletion in Nb, Ta, P and Ti. They have initial 87Sr/86Sr values of 0.70701- 0.70818 and 143Nd/144Nd values of 0.51241-0.51250. These geochemical characteristics and isotopic signatures are considered to reflect the composition of the magmas derived from a

  13. Cave-dwelling invertebrates of the NW Mediterranean: silent victims of global warming?

    NASA Astrophysics Data System (ADS)

    Lejeusne, C.; Chevaldonné, P.

    2003-04-01

    Dark submarine caves constitute an extreme and fragmented habitat of the littoral zone. They present environmental conditions characterised by a complete absence of light and a strong oligotrophy, and then are inhabited by endemic and specialised species. However, the extremely fragmented and poorly resilient characteristics of these communities imply that they are more sensitive than any other littoral community to large-scale perturbations such as global warming. Global change induces a long term increase in water temperatures, but also shorter and more acute events such as those recorded in the NW Mediterranean during summers 1997 and 1999. During these two thermal anomalies, water temperatures of up to 24^oC reached 40m depth and below, during several weeks. Many sessile invertebrate species such as sponges, cnidarians and bivalves, were heavily affected. Consequences on NW Mediterranean caves were studied through mysids (Crustacea: Peracarida), especially Hemimysis genus. Since its discover, Hemimysis speluncola Ledoyer, 1963 had been the dominant endemic mysid in those caves, where it formed large and high-density swarms. However, consequently to the thermal anomalies, swarm density declined rapidly, leading to an almost complete disappearance of the species. This phenomenon was first recorded in the Marseille (France) area, but we show that it happened in most other NW Mediterranean regions. At the same time, another mysid Hemimysis margalefi Alcaraz, Riera &Gili, 1986 replaced H. speluncola in the caves. Comparative thermotolerance experiments between the two species revealed more eurythermal characteristics in H. margalefi and a better resistance to acute thermal stress. Because of the Mediterranean geography, the endemic H. speluncola, with distant fragmented populations and a low thermal tolerance cannot migrate to northern (colder) regions. It may therefore be doomed to disappear in the context of global change, with replacement by the more thermophile

  14. GPR Surveys for Archaeological Investigation in a Bronze Age site from NW Portugal

    NASA Astrophysics Data System (ADS)

    Gonçalves, L.; Sampaio, H. A.; Bettencourt, A. M. S.; Alves, M. I. C.

    2012-04-01

    This work describes the use of Ground-penetrating Radar (GPR) surveys in the identification and mapping of subtle cultural remains, from Pego Late Bronze Age settlement, located near the city of Braga, in NW Portugal. Bronze Age settlements from NW Portugal are characterized by the presence archaeological structures such as storage pits, postholes and trenches. These subtle structures have a very low dielectric contrast, making them quite difficult to detect in GPR surveys. In the case of Pego Site, previous investigations using conventional archaeological techniques, during a rescue excavation, partially revealed a residential area, a necropolis, and a stockade foundation trench that encircle the whole settlement. Different GPR prospection approaches were performed using GSSI Sir 3000 System, with 400 MHz antennae, with the objective of identify and define the borders between the different areas of human occupation inside the settlement. For the GPR survey, a grid-based approach with closely spaced parallels transects was defined, covering different areas inside the site. A first survey was conducted with a pseudo-3D methodology, with 50 cm profile separation, followed by a second survey with a dense data acquisition methodology, with 10 cm profile separation. Processed two-dimensional GPR profiles and constructed amplituded-slice maps were produced and analysed. Wave velocities were determined by reflected wave methods and by Hyperbola-Fitting method. The background analysis of the archaeological and geological features of the site, integrated with the preliminary interpretation of GPR data (profiles and amplitude slice-maps) suggest the presence of flat graves, in the west part of the site, and storage pits, post holes and some small trenches, in the centre and north area of the settlement. This interpretation indicates that the settlement is individualized in two different areas, a necropolis and a residential area, such as the first archaeological study

  15. Structural Setting of Western Monferrato (Alps-Apennines Junction Zone, NW Italy)

    NASA Astrophysics Data System (ADS)

    Piana, Fabrizio

    2000-10-01

    New data on the structural setting of the Torino Hill and Western Monferrato domains provide a clearer picture of the kinematic evolution of the Alps-Apennines junction zone. In the Alps-Apennines junction, left-lateral underthrusting of Ligurian units below Alpine crust has often been invoked to explain the underthrusting of the Insubric domain and the NW-ward movement of the Adriatic indenter. A transpressive fault system (Rio Freddo Fault Zone) developed in the Monferrato epi-Ligurian succession is here understood as the surficial expression of a deep-seated thrust along which the Alpine metamorphic basement of the Torino Hill has overridden the Apenninic Ligurian nappes since the Paleogene up to Burdigalian. In the Western Monferrato the regional sinistral transpression differentiated separated crustal blocks during the Oligocene-early Miocene, and kilometer-thick successions were steepened by NNW-SSE faults that acted as reverse and/or left-lateral faults. Double-vergent (SE-NW) low-angle shear zones then cut the Rio Freddo Fault Zone in post-Langhian times. They have been here related with the eastward tectonic transport of the Torino Hill and relative Alpine crust toward the Monferrato domain, which occurred before the seismic line scale middle Miocene unconformity was established. This poses the problem of the exact age of this regional unconformity, which in our case should be at least Serravallian. Finally, the Monferrato and Torino Hill domains were coupled, and both were NW-ward translated by the Padan Thrust Front in the Pliocene. The youngest strike-slip and reverse faults of the Western Monferrato may be tear or compartmental faults that partitioned the Padan Thrust motion, whose propagation could be controlled by pre-middle-Miocene tectonic structures. The structural complexity of the study area is here understood as the inheritance of deep crosscutting regional structures that forced the convergent structural units of the Alpine and Insubric

  16. Is There any Relationship Between Active Tabriz Fault Zone and Bozkush Fault Zones, NW Iran?

    NASA Astrophysics Data System (ADS)

    ISIK, V.; Saber, R.; Caglayan, A.

    2012-12-01

    Tectonic plate motions and consequent earthquakes can be actively observed along the northwestern Iran. The Tabriz fault zone (TFZ), also called the North Tabriz fault, active right-lateral strike-slip fault zone with slip rates estimated as ~8 mm/yr, has been vigorously deforming much of northwestern Iran for over the past several million years. Historical earthquakes on the TFZ consist of large magnitude, complimentary rupture length and changed the landscape of regions surrounding the fault zone. The TFZ in the city of Bostanabad is more segmented with several strands and joined by a series of WNW-ESE trending faults, called the Bozkush fault zones. The Bozkush fault zones (BFZ's) (south and north), bounding arch-shaped Bozkush mountains, generates not only hundreds of small earthquakes each year but also has provided significant earthquakes that have been historically documented. The rock units deformed within the BFZ's include Eocene-Oligocene volcanic rocks with intercalation limestone, Oligo-Miocene clastic rocks with intercalation gypsiferous marl and Plio-Quaternary volcano-sedimentary rocks, travertine and alluvium. The North and South Bozkush fault zones are characterized by development of structures typically associated with transpression. These include right-lateral strike-slip faults, thrust faults and foldings. Our field studies indicate that these zones include step to sub-vertical fault surfaces trending NW and NE with slickenlines. Slickensides preserve brittle kinematic indicators (e.g., Riedel shear patterns, slickenside marks) suggesting both dextral displacements and top-to-the-NE/NW and-SE/SW sense of shearing. Besides, mesoscopic and microscopic ductile kinematic indicators (e.g., asymmetric porphyroclasts, C/S fabrics) within Miocene gypsum marl show dextral displacements. Fault rocks along most of these faults consist of incohesive fault breccia and gauge. Adjacent to the fault contact evidence of bedding in Oligo-Miocene and Plio

  17. Lithospheric strength across the ocean-continent transition in the NW of the Iberian Peninsula

    NASA Astrophysics Data System (ADS)

    Martín-Velázquez, Silvia; Martín-González, Fidel

    2014-05-01

    The main objective of this work is to investigate the relation between the strength of the lithosphere and the observed pattern of seismicity across the ocean-continent transition in the NW margin of the Iberian Peninsula. The seismicity is diffuse in this intraplate area, far from the seismically active margin of the plate: the Eurasia-African plate boundary, where convergence occurs at a rate of 4-5mm/year. The earthquake epicentres are mainly limited to an E-W trending zone (onshore seismicity is more abundant than offshore), and most earthquakes occur at depths less than 30 km, however, offshore depths are up to 150 km). Moreover, one of the problems to unravel in this area is that the seismotectonic interpretations of the anomalous seismicity in the NW peninsular are contradictory. The temperature and strength profiles have been modelled in three domains along the non-volcanic rifted West Iberian Margin: 1) the oceanic lithosphere of the Iberian Abyssal Plain, 2) the oceanic lithosphere near the ocean-continent transition of the Galicia Bank, and 3) the continental lithosphere of the NW Iberian Massif. The average bathymetry and topography have been used to fit the thermal structures of the three types of lithospheres, given that the heat flow and heat production values show a varied range. The geotherms, together with the brittle and ductile rheological laws, have been used to calculate the strength envelopes in different stress regimes (compression, shear and tensile). The continental lithosphere-asthenosphere boundary is located at 123 km and several brittle-ductile transitions appear in the crust and the mantle. However, the oceanic lithospheres are thinner (110 km near the Galicia Bank and 87 km in the Iberian Abbysal Plain) and more simple (brittle behaviour in the crust and upper mantle). The earthquake distribution is best explained by lithospheres with dry compositions and shear or tensile stress regimes. These results are similar can be compared to

  18. Effect of Ag/Au bilayer assisted etching on the strongly enhanced photoluminescence and visible light photocatalysis by Si nanowire arrays.

    PubMed

    Ghosh, Ramesh; Imakita, Kenji; Fujii, Minoru; Giri, P K

    2016-03-01

    We report on the strongly enhanced photoluminescence (PL) and visible light photocatalysis by arrays of vertically aligned single crystalline Si nanowires (NWs) grown by Ag/Au bilayer assisted etching. High resolution FESEM and TEM imaging reveals that the Si NWs are decorated with ultra-small size arbitrary shaped Si nanocrystals (NCs) due to the lateral etching of the NWs. A strong broad band and tunable visible to near-infrared (NIR) photoluminescence (PL) in the range 1.3-2.4 eV are observed for these Si NWs/NCs at room temperature, depending on the etching conditions. Our studies reveal that the visible-NIR PL intensity is about two orders of magnitude higher and it exhibits faster decay dynamics in the bilayer assisted etching case as compared to the Ag or Au single layer etching case. The enhanced PL in the bimetal case is attributed to the longer length and higher density of the Si NWs/NCs, surface plasmon resonance enhanced absorption by residual bimetal NPs and the enhanced radiative recombination rate. Studies on the time evolution of PL spectral features with laser exposure under ambient conditions and laser power dependence reveal that both the quantum confinement of carriers in Si NCs and the nonbridging oxygen hole defects in the SiOx layer contribute to the tunable PL. Interestingly, Si NWs grown by Ag/Au bilayer assisted etching exhibit enhanced photocatalytic degradation of methylene blue in comparison to Si NWs grown by single layer Ag or Au assisted etching. The Schottky barrier present between bimetallic NPs and nanoporous Si NWs with Si-H bonds facilitates the photocatalytic activity by efficient separation of photogenerated e-h pairs. Our results demonstrate the superiority of the Si NW array grown by bilayer assisted etching for their cutting edge applications in optoelectronics and environmental cleaning. PMID:26907170

  19. Formation of surface oxides and Ag2O thin films with atomic oxygen on Ag(111)

    NASA Astrophysics Data System (ADS)

    Derouin, Jonathan; Farber, Rachael G.; Heslop, Stacy L.; Killelea, Daniel R.

    2015-11-01

    The nature of the oxygen species adsorbed to silver surfaces is a key component of the heterogeneously catalyzed epoxidation of ethylene and partial oxidation of methanol over silver catalysts. We report the formation of two different silver-oxygen species depending on the flux and energy of incident gas-phase oxygen atoms on an Ag(111) surface. A combination of surface science techniques was used to characterize the oxidized surfaces. Atomic oxygen was generated with an Ir filament; lower temperatures created surface oxides previously reported. When O was deposited with a higher filament temperature, the surface became highly corrugated, little subsurface oxygen was observed, and thin layers of Ag2O were likely formed. These results show that the energy and flux of oxygen are important parameters in the chemical identity and abundance of oxygen on silver surfaces and suggest that formation of the Ag2O thin film hinders formation of subsurface oxygen.

  20. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition

    SciTech Connect

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.

    2010-11-01

    The flux of atomic oxygen generated in a electron cyclotron resonance (ECR) microwave plasma source was quantified by two different methods. The commonly applied approach of monitoring the frequency change of a silver-coated quartz crystal microbalance (QCM) deposition rate monitor as the silver is oxidized was found to underestimate the atomic oxygen flux by an order of magnitude compared to a more direct deposition approach. In the mixed-phase Ag/Ag2O deposition method, silver films were deposited in the presence of the plasma such that the films were partially oxidized to Ag2O; x-ray photoelectron spectroscopy (XPS) was utilized for quantification of the oxidized fraction. The inaccuracy of the QCM oxidation method was tentatively attributed to efficient catalytic recombination of O atoms on the silver surface.